Metabolic profiling of residents in the vicinity of a petrochemical complex

Energy Technology Data Exchange (ETDEWEB)

Yuan, Tzu-Hsuen; Chung, Ming-Kei [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Lin, Ching-Yu [Institute of Environmental Health, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Chen, Shu-Ting; Wu, Kuen-Yuh [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Chan, Chang-Chuan, E-mail: ccchan@ntu.edu.tw [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China)

2016-04-01

No previous studies have simultaneously measured the biomarkers of environmental exposure and metabolome perturbation in residents affected by industrial pollutants. This study aimed to investigate the metabolic effects of environmental pollutants such as vanadium and polycyclic aromatic hydrocarbons (PAHs) on residents in the vicinity of a petrochemical complex. The study subjects were 160 residents, including 80 high-exposure subjects exposed to high levels of vanadium and PAHs and 80 age- and gender-matched low-exposure subjects living within a 40-km radius of a petrochemical complex. The exposure biomarkers vanadium and 1-hydroxypyrene and four oxidative/nitrosative stress biomarkers were measured in these subjects. Plasma samples from the study subjects were also analyzed using {sup 1}H NMR spectroscopy for metabolic profiling. The results showed that the urinary levels of vanadium and 1-hydroxypyrene in the high-exposure subjects were 40- and 20-fold higher, respectively, than those in the low-exposure subjects. Higher urinary levels of stress biomarkers, including 8-OHdG, HNE-MA, 8-isoPF2α, and 8-NO{sub 2}Gua, were also observed among the high-exposure subjects compared with the low-exposure subjects. Partial least squares discriminant analysis of the plasma metabolome demonstrated a clear separation between the high- and low-exposure subjects; the intensities of amino acids and carbohydrate metabolites were lower in the high-exposure subjects compared with the low-exposure subjects. The exposure to vanadium and PAHs may cause a reduction in the levels of amino acids and carbohydrates by elevating PPAR and insulin signaling, as well as oxidative/nitrosative stress. - Highlights: • Metabolic effects when exposure to pollutants near a petrochemical complex • V and PAHs exposure associated with elevated oxidative/nitrosative stress responses • V and PAHs exposure related to reduced amino acid and carbohydrate levels • V and PAHs affect metabolic

Cancer incidence and mortality among temporary maintenance workers in a refinery/petrochemical complex in Korea

Science.gov (United States)

Koh, Dong-Hee; Chung, Eun-Kyo; Jang, Jae-Kil; Lee, Hye-Eun; Ryu, Hyang-Woo; Yoo, Kye-Mook; Kim, Eun-A; Kim, Kyoo-Sang

2014-01-01

Background: Petrochemical plant maintenance workers are exposed to various carcinogens such as benzene and metal fumes. In Korea, maintenance operations in petrochemical plants are typically performed by temporary employees hired as contract workers. Objectives: The purpose of this retrospective study was to evaluate cancer risk in temporary maintenance workers in a refinery/petrochemical complex in Korea. Methods: Subjects consisted of 14 698 male workers registered in a regional petrochemical plant maintenance workers union during 2002–2007. Cancer mortality and incidence were identified by linking with the nationwide death and cancer registries during 2002–2007 and 2002–2005, respectively. Standardized mortality ratios (SMRs) and standardized incidence ratios (SIRs) were calculated for each cancer. Results: Increased SMR 3.61 (six cases, 95% CI: 1.32–7.87) and SIR 3.18 (five cases, 95% CI: 1.03–7.42) were observed in oral and pharyngeal cancers. Conclusion: Our findings may suggest a potential association between oral and pharyngeal cancers and temporary maintenance jobs in the petrochemical industry. Future studies should include a longer follow-up period and a quantitative exposure assessment. PMID:24999849

Waste minimization in a petrochemical company

Energy Technology Data Exchange (ETDEWEB)

Anan, Marcelo [Oxiteno S.A., Industria e Comercio, Sao Paulo, SP (Brazil)

1994-12-31

A way to manage industrial effluents consists in reducing their generation or treating them when elimination or minimization is economically unachievable. This work aims to present the modifications adopted in a petrochemical plant to adequate and, or, reduce the generation of industrial effluent. 8 refs., 3 figs.

Waste minimization in a petrochemical company

Energy Technology Data Exchange (ETDEWEB)

Anan, Marcelo [Oxiteno S.A., Industria e Comercio, Sao Paulo, SP (Brazil)

1993-12-31

A way to manage industrial effluents consists in reducing their generation or treating them when elimination or minimization is economically unachievable. This work aims to present the modifications adopted in a petrochemical plant to adequate and, or, reduce the generation of industrial effluent. 8 refs., 3 figs.

Proceedings of the 3. International conference on waste management in the chemical and petrochemical industries. Volume 1 and 2.

Energy Technology Data Exchange (ETDEWEB)

Lima, Francisco F; Pereira Filho, Francisco A; Almeida, Sergio A.S. [eds.

1994-12-31

To produce without pollution is today a mandate for the preservation of our society. To produce cleaner means to conserve energy and natural resources, to reduce the use of toxic substances, to invest in the evolution of products and production processes towards a minimum of residues. The Third International Conference on Waste Minimization in the Chemical and Petrochemical Industries addresses these challenging questions regarding waste minimization

Proceedings of the 3. International conference on waste management in the chemical and petrochemical industries. Volume 1 and 2.

Energy Technology Data Exchange (ETDEWEB)

Lima, Francisco F.; Pereira Filho, Francisco A.; Almeida, Sergio A.S. [eds.

1993-12-31

To produce without pollution is today a mandate for the preservation of our society. To produce cleaner means to conserve energy and natural resources, to reduce the use of toxic substances, to invest in the evolution of products and production processes towards a minimum of residues. The Third International Conference on Waste Minimization in the Chemical and Petrochemical Industries addresses these challenging questions regarding waste minimization

Source pollution control program at the Camacari Petrochemical Complex: overall and individual improvements

Energy Technology Data Exchange (ETDEWEB)

Freire, P A; Neto, D B; Carvalho, D M [CETREL S.A., Camacari, BA (Brazil)

1994-12-31

Along with the technical progress experienced by the Camacari Petrochemical Complex in the last few years, new policies, following new worldwide trends, in pollution control and prevention became mandatory. This work describes some of these experiences as well as future perspectives. 3 refs., 2 fig., 13 tabs.

Source pollution control program at the Camacari Petrochemical Complex: overall and individual improvements

Energy Technology Data Exchange (ETDEWEB)

Freire, P.A.; Neto, D.B.; Carvalho, D.M. [CETREL S.A., Camacari, BA (Brazil)

1993-12-31

Along with the technical progress experienced by the Camacari Petrochemical Complex in the last few years, new policies, following new worldwide trends, in pollution control and prevention became mandatory. This work describes some of these experiences as well as future perspectives. 3 refs., 2 fig., 13 tabs.

2003 assessment of PCDDs-PCDFs emissions from the Copesul/South Petrochemical complex located in southern Brazil

Energy Technology Data Exchange (ETDEWEB)

Deschamps, M.; Allard, J.L. [SNC-Lavalin Environment Inc., Montreal, PQ (Canada); Rangel, C.M.P.; Ribeiro, C.; Dos Santos, S.T.F. [Companhia Petroquimica do Sul, Triunfo (Brazil)

2004-09-15

COPESUL is the Raw Material and Utilities Central of the South Petrochemical Complex, this, being the most modern industrial facility of its type in Brazil, and the second largest naphtha cracker in the country. Responsible for more than 40% of Brazilian olefins production, it is also among the largest crackers (on the same site) in the world. The majority of COPESUL products are transformed by downstream industries of the Complex into thermoplastics resins, synthetic rubber, styrene and solvents that are widely used in the manufacturing of packing material (food, hygiene, cleaning), electronic appliances, medical and surgical supplies, toys and in the car industries, to be consumed in Brazil and foreign countries. At the request of the state of Rio Grande do Sul Environmental Protection Agency (Fundacao Estadual de Protecao Ambiental or FEPAM), an Environmental Assessment of Priority Pollutants (EAPP) was performed by Copesul at the end of the year 2003. EAPPs have been voluntarily performed at the Petrochemical Complex since 1986 on a basis of once every three year. It is now performed as a requirement which is part of the petrochemical plant operational license. Among the different (organic and inorganic) parameters tested, PCDDs-PCDFs remained a main concern to the local State Agency with regards to the Complex activities and of it's potential impact on the human health and the environment, despite the fact that the Complex does not use nor produce any organochlorinated product.

Development of refractory ceramic using waste of petrochemical catalysts

International Nuclear Information System (INIS)

Pedroso, M.A.; Mymrine, V.

2011-01-01

The manufacturing of catalytic catalysts by the company FCC SA. for the Brazilian petrochemical industry is 25,000 tons per annum, which after going through the cracking process cannot undergo regeneration any longer, being wasted with humidity near 70%. To increase the economical and environmental efficiency of the use of this rejected catalyst, without preliminary drying, a method of using it as main raw material in composition like kaolin was developed, as well as in ash and glass for the manufacturing of common (regular) and refractory ceramic. The mixture of these components were burnt at temperatures of 1100 deg C, 1200°C, 1250°C and 1300°C. The ceramics with 30% and 40% in weight of wasted catalyst, sintered in 1250 deg C or 1300 deg C have flexion of 10,8 - 12,9 MPa. After burning the mixtures, the chemical interaction of the initial components was determined by the methods of RXD, MEV and EDS, synthesizing new minerals like Diopside Ca(Mg,Al)(Si,Al) 2 O 6 , Nepheline (K,Na)AlSiO 4 , Lazurite Na 8 [Al 2 SiO 4 ] 6 [SO 4 ,S] 2 , Magnetite Fe 3 O 4 , Albite Na Al Si 3 O 8 and high content of vitreous amorphous phase. (author)

Energy saving in refineries and petrochemical complexes

Energy Technology Data Exchange (ETDEWEB)

Verde, L

1975-01-01

Possible measures applicable in the design of refineries and petrochemical complexes, to effect energy savings were investigated. This was not limited to the single process unit problems, on the contrary the attention is mainly addressed to the identification of the interrelations between different units, emphasizing possible integrations. Particularly, the optimization of the pressure levels and number of the utility networks for steam distribution inside plant facilities, is considered, in order to maximize heat recovery in the process units, and electric power production in the central steampower generation plant. A computer program of general application, based on profitability evaluation at various fuel oil prices and different project configurations, has been developed for these purposes. The general measures applicable within certain limits are then briefly examined. The task of the process engineer is discussed in the perspective of the ''energy saving'' goal.

Hygienic evaluation of repurification schemes for waste waters containing complexes for organic substances

Energy Technology Data Exchange (ETDEWEB)

Bulgakov, R G

1983-01-01

Sanitary-chemical and sanitary-toxicological methods were used to study two repurification schemes for biologically purified waste waters from a petrochemical industrial complex. These repurification schemes were, (1) filtration through quartz sand, adsorption to activated charcoal, chlorination; (2) coagulation, filtration through quartz sand, adsorption to activated charcoal, chlorination. Both repurification schemes considerably improved the composition and properties of the waste waters in terms of organoleptic and sanitary-chemical indices. Scheme 1 also considerably lowered the toxic properties of the waste waters and Scheme 2 abolished them completely. Provided that the corresponding sanitary norms are observed, the use of repurification Scheme 1 would be economically reasonable where repurified waste water is recirculated in the industrial plant. Repurification Scheme 2 is recommended where purified waste water is disposed into low-capacity reservoirs.

Qualitative Survey of the Effluent from the Olefin Unit of Bandar-e-Imam Petrochemical Complex

Directory of Open Access Journals (Sweden)

Sima Sabzalipour

2007-09-01

Full Text Available This study was conducted to determine the qualitative parameters of the wastewater from the Olefin Unit of Bandar-e-Imam Petrochemical Complex in an attempt to identify the problems and to develop solutions. All the oily wastes generated in the unit under study are directed to the CPI and DAF systems where they are deoiled, diverted into the Eastern Pond, and, finally, discharged into the sea after a primary treatment process. In this study, information was collected on the process and on the effluent contaminant spreading sources in order to determined the sampling spots. Sampling was performed over 6 months and the effluent quality parameters (pH, TDS, BOD, COD, Oil, SO4=, PO4≡, and NO− were measured. Changes in the parameters were recorded on monthly, weekly, and daily bases. Combined samples were additionally used to ensure measurement accuracy. The results showed that the concentration levels of the parameters BOD, COD, oil, and phosphate ion in the effluent from the CPI system were beyond the national standards. Pollution load estimations for the relevant parameters also confirmed these results. Investigations revealed that COD and oil removal efficiencies in the CPI system were 17% and 10%, respectively, which cannot be desirable (paired sample t-test. Another problem observed was the effluent from the caustic wash tower. This effluent, which contains considerable quantities of caustic, polymer, yellow oil, and water, is discharged into the waste neutralization pond to leave the complex without further neutralization.

Petrochemical development in Venezuela

International Nuclear Information System (INIS)

Volkenborn, A.

1997-01-01

This presentation highlighted the evolution of the petrochemical industry in Venezuela. Comparative advantages for the industry such as (1) abundant low cost energy, (2) attractive geographical position, (3) good infrastructure, (4) skilled, low cost labour force, and (5) regional integration, were reviewed. A summary of national production, refining, and marketing facts for petrochemicals, coal, orimulsion, and marine transportation were presented, along with financial information concerning revenues from sales, and profits and investments. Future plans to maximize the creation of value for the nation through increased oil production and partial privatization of state petroleum enterprises, were reviewed. The current state and future plans for focused development of fertilizers, olefins and olefin derivatives, and methanol products were outlined. Production statistics for three large petrochemical complexes, - El Tablazo, Moron and Jose - were also presented. 9 figs

The Effect of Social Trust on Citizens’ Health Risk Perception in the Context of a Petrochemical Industrial Complex

Directory of Open Access Journals (Sweden)

Vicente Tortosa-Edo

2013-01-01

Full Text Available Perceived risk of environmental threats often translates into psychological stress with a wide range of effects on health and well-being. Petrochemical industrial complexes constitute one of the sites that can cause considerable pollution and health problems. The uncertainty around emissions results in a perception of risk for citizens residing in neighboring areas, which translates into anxiety and physiological stress. In this context, social trust is a key factor in managing the perceived risk. In the case of industrial risks, it is essential to distinguish between trust in the companies that make up the industry, and trust in public institutions. In the context of a petrochemical industrial complex located in the port of Castellón (Spain, this paper primarily discusses how trust — both in the companies located in the petrochemical complex and in the public institutions — affects citizens’ health risk perception. The research findings confirm that while the trust in companies negatively affects citizens’ health risk perception, trust in public institutions does not exert a direct and significant effect. Analysis also revealed that trust in public institutions and health risk perception are essentially linked indirectly (through trust in companies.

The Effect of Social Trust on Citizens’ Health Risk Perception in the Context of a Petrochemical Industrial Complex

Science.gov (United States)

López-Navarro, Miguel Ángel; Llorens-Monzonís, Jaume; Tortosa-Edo, Vicente

2013-01-01

Perceived risk of environmental threats often translates into psychological stress with a wide range of effects on health and well-being. Petrochemical industrial complexes constitute one of the sites that can cause considerable pollution and health problems. The uncertainty around emissions results in a perception of risk for citizens residing in neighboring areas, which translates into anxiety and physiological stress. In this context, social trust is a key factor in managing the perceived risk. In the case of industrial risks, it is essential to distinguish between trust in the companies that make up the industry, and trust in public institutions. In the context of a petrochemical industrial complex located in the port of Castellón (Spain), this paper primarily discusses how trust—both in the companies located in the petrochemical complex and in the public institutions—affects citizens’ health risk perception. The research findings confirm that while the trust in companies negatively affects citizens’ health risk perception, trust in public institutions does not exert a direct and significant effect. Analysis also revealed that trust in public institutions and health risk perception are essentially linked indirectly (through trust in companies). PMID:23337129

Considerations for Planning a Monitoring Campaign at Petrochemical Complexes: Lessons Learned

Science.gov (United States)

Cuclis, A.

2010-12-01

An air quality monitoring campaign was developed for the late spring of 2009 near Houston area petrochemical facilities. The focus of the field campaign was to measure free radicals that contribute to the formation of ozone, however refinery and chemical plants monitored are also emitters of many different volatile organic compounds (vocs) and hazardous air pollutants (haps). The Houston area is home to the largest aggregation of petrochemical facilities in the U.S. Three specific geographical areas with industrial facilities were considered: Mont Belvieu, the Houston Ship Channel and the Texas City Industrial Complex. Previous experiences with field campaigns in the area led to the presumption that there would be little if any access inside the facilities. Considerations for which areas to focus on included: how close could the facility be approached, what were the directions of the prevailing winds, what kind of barriers to measurement existed (e.g. trees, buildings, highways, privately owned land, etc.), and what were the possible chemical interferences from other sources near the measurement sites? Close communications with the plant security, the local police, the Federal Bureau of Investigations (FBI), Homeland Security, the Federal Aviation Administration (FAA), and the Texas Commission on Environmental Quality (TCEQ) were required. Substantial delays can occur due to local concerns regarding homeland security and plant safety. Also, a system of communications is essential to coordinate the participating scientists operating stationary analyzers with the scientists who have analyzers mounted in ground vehicles and in aircraft. The researchers were provided with information regarding plant operations, types of equipment and potential pollutants. A wide variety of stationery and mobile ambient air monitoring techniques were used to measure formaldehyde and other volatile organic compounds. In order to identify likely formaldehyde sources the self

Energy and carbon emissions analysis and prediction of complex petrochemical systems based on an improved extreme learning machine integrated interpretative structural model

International Nuclear Information System (INIS)

Han, Yongming; Zhu, Qunxiong; Geng, Zhiqiang; Xu, Yuan

2017-01-01

Highlights: • The ELM integrated ISM (ISM-ELM) method is proposed. • The proposed method is more efficient and accurate than the ELM through the UCI data set. • Energy and carbon emissions analysis and prediction of petrochemical industries based ISM-ELM is obtained. • The proposed method is valid in improving energy efficiency and reducing carbon emissions of ethylene plants. - Abstract: Energy saving and carbon emissions reduction of the petrochemical industry are affected by many factors. Thus, it is difficult to analyze and optimize the energy of complex petrochemical systems accurately. This paper proposes an energy and carbon emissions analysis and prediction approach based on an improved extreme learning machine (ELM) integrated interpretative structural model (ISM) (ISM-ELM). ISM based the partial correlation coefficient is utilized to analyze key parameters that affect the energy and carbon emissions of the complex petrochemical system, and can denoise and reduce dimensions of data to decrease the training time and errors of the ELM prediction model. Meanwhile, in terms of the model accuracy and the training time, the robustness and effectiveness of the ISM-ELM model are better than the ELM through standard data sets from the University of California Irvine (UCI) repository. Moreover, a multi-inputs and single-output (MISO) model of energy and carbon emissions of complex ethylene systems is established based on the ISM-ELM. Finally, detailed analyses and simulations using the real ethylene plant data demonstrate the effectiveness of the ISM-ELM and can guide the improvement direction of energy saving and carbon emissions reduction in complex petrochemical systems.

Northern gas: Williams petrochemical feasibility study

Energy Technology Data Exchange (ETDEWEB)

Chappell, D. [Williams Energy Canada, Calgary, AB (Canada)

2002-07-01

Williams Energy is a company that is involved in the following fields: gas pipelines, exploration and production, midstream, refining, petrochemical, power, and marketing and trading. The author provides an overview of the global and Canadian infrastructure before proceeding to discuss Arctic gas, which is viewed by Williams Energy as necessary. It favors the Alaska Highway route with a consortium for project development. Williams performed a petrochemical study to determine the feasibility of a petrochemical complex utilizing natural gas liquid from an Arctic gas pipeline. The scope of the study encompassed facilities (extraction plant, cracker, polyolefins plant), size (world scale, approximately 2 billion pounds per year), and location (Fairbanks or Alberta). The study led to the following findings: (1) review of several scenarios for both locations, (2) complex to produce two grades of polyethylene, (3) feedstock cost favors Alaska, (4) construction costs lower in Alberta, (5) and the primary market for the Alaska complex would be northeast Asia, while the primary market for the Alberta location would be the United States. It was determined that both options would be viable, however Alberta was favored due to the polyethylene forecast. The challenges still being faced by Williams include low frac spread, market inefficiencies, empress volumes, carbon dioxide, and fuel and electricity cost. Each of these challenges is discussed separately. The author concludes by indicating that incremental ethane is available, carbon dioxide issues need resolution, and Alberta and Alaska are attractive for Arctic ethane petrochemical production. figs.

Method of burning petrochemical products

Energy Technology Data Exchange (ETDEWEB)

Sado, I

1973-01-12

This invention concerns a method of burning wastes such as polyvinyl chloride or other synthetic resin products and rubbers, in which wastes are burned in a nearly smokeless and odorless state. The method is characterized by a process by which petrochemical waste products are subjected to a spontaneous combustion in a casserole state in a closed combustion room in such a way that no air is supplied whatever, and subsequently the gas so generated is sent successively in an adequate amount into a separately installed second combustion room where it is reburnt at a high temperature of more than 1000 C by a jet flame from the oil burners mounted inside the combustion room. Usually, petrochemical products emanate black smoke of Ringelmann concentration of more than five and a strong odor, but in this method, particularly in the case of polyvinyl chloride the exhaust smoke has a Ringelmann smoke concentration of less than one and is almost odorless because the plastic is completely gasified by the spontaneous combustion and completely burned at 1300 to 1400/sup 0/C with oil and air in the second combustion room. When the exhaust smoke is passed through a neutralization tank to remove the chloride compounds in the smoke, the damaging contribution of the exhaust gas or smoke to the secondary pollution can be completely eliminated.

How will Southeast Asian petrochemicals impact the HPI?

International Nuclear Information System (INIS)

Rothman, S.N.

1997-01-01

Development of East Asia's petrochemical industry has been phenomenal, with major complexes built in numerous locations. The Southeast Asian countries of particular interest are members of the Association of Southeast Asian Nations (ASEAN): Singapore, Thailand, Malaysia, Indonesia, the Philippines, Brunei and Vietnam. As new capacity is built in this region, these large operating facilities will affect supply and demand for key petrochemical products--ethylene and polyolefins. What are the potential regional effects from this new capacity? Traditional net export countries will have to re-evaluate their future marketing strategies to remain competitive in Southeast Asia and other trading areas. As East Asia's petrochemical industry comes of age, competition will undoubtedly increase. However, this growing region offers opportunities to widen manufacturing basis. The paper discusses basic chemical demands and the outlook for the Asian petrochemical industry

Financing the petrochemical industry : a banker's perspective

International Nuclear Information System (INIS)

Weissenberger, A.T.

1998-01-01

The risks that are associated with the petrochemical industry from a lender's perspective were described. It was suggested that the petrochemical industry is facing a downturn which will be intensified by the Asian economic crisis. In the past, petrochemicals were recognized as a major requirement for economic growth and many governments encouraged joint ventures with foreign companies. However, the Asian economic crisis has significantly slowed petrochemical demand from Canada. The three major risks associated with the petrochemical industry - cyclical nature of the business, price volatility and complexity - were examined. It was shown that a typical petrochemical company accesses multiple feedstocks and produces thousands of products. This complicates cash flow analysis and market risk for lenders. Another risk pertains to environmental issues and international environmental policies which emphasize reduction of emissions, including those from chemical manufacturing. Critical success factors such as global diversification, leading process technology, low cost operation, and focusing on core competencies were also reviewed. Prediction for the next three to five years was a further slowdown of Asian demand, competition from Asian petrochemical companies, capacity driven oversupply and industry consolidation as a way to deal with depressed markets that could last for several years. Nevertheless, the emerging markets will continue to be the hotspots. Alberta, as one of the low cost feedstock areas of the world, will continue to be in a good position to take advantage of the Asian recovery which despite the current problems, is confidently expected within the next three to five years. 5 figs

Assessing vanadium and arsenic exposure of people living near a petrochemical complex with two-stage dispersion models

International Nuclear Information System (INIS)

Chio, Chia-Pin; Yuan, Tzu-Hsuen; Shie, Ruei-Hao; Chan, Chang-Chuan

2014-01-01

Highlights: • Two-stage dispersion models can estimate exposures to hazardous air pollutants. • Spatial distribution of V levels is derived for sources without known emission rates. • A distance-to-source gradient is found for V levels from a petrochemical complex. • Two-stage dispersion is useful for modeling air pollution in resource-limited areas. - Abstract: The goal of this study is to demonstrate that it is possible to construct a two-stage dispersion model empirically for the purpose of estimating air pollution levels in the vicinity of petrochemical plants. We studied oil refineries and coal-fired power plants in the No. 6 Naphtha Cracking Complex, an area of 2,603-ha situated on the central west coast of Taiwan. The pollutants targeted were vanadium (V) from oil refineries and arsenic (As) from coal-fired power plants. We applied a backward fitting method to determine emission rates of V and As, with 192 PM 10 filters originally collected between 2009 and 2012. Our first-stage model estimated emission rates of V and As (median and 95% confidence intervals at 0.0202 (0.0040–0.1063) and 0.1368 (0.0398–0.4782) g/s, respectively. In our second stage model, the predicted zone-average concentrations showed a strong correlation with V, but a poor correlation with As. Our findings show that two-stage dispersion models are relatively precise for estimating V levels at residents’ addresses near the petrochemical complex, but they did not work as well for As levels. In conclusion, our model-based approach can be widely used for modeling exposure to air pollution from industrial areas in countries with limited resources

Assessment of urinary thiodiglycolic acid exposure in school-aged children in the vicinity of a petrochemical complex in central Taiwan

Energy Technology Data Exchange (ETDEWEB)

Huang, Po-Chin, E-mail: pchuang@nhri.org.tw [National Environmental Health Research Center, National Institute of Environmental Health Sciences, National Health Research Institutes, Miaoli, Taiwan (China); Liu, Li-Hsuan [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Shie, Ruei-Hao [Green Energy and Environment Research Laboratories, Industrial Technology Research Institute, Hsinchu, Taiwan (China); Tsai, Chih-Hsin; Liang, Wei-Yen [National Environmental Health Research Center, National Institute of Environmental Health Sciences, National Health Research Institutes, Miaoli, Taiwan (China); Wang, Chih-Wen [National Environmental Health Research Center, National Institute of Environmental Health Sciences, National Health Research Institutes, Miaoli, Taiwan (China); Hepatobiliary Diversion, Department of Internal medicine, Kaohsiung Medical University Hospital, Kaohsiung, Taiwan (China); Department of Internal Medicine, Chi-Shan Hospital, Ministry of Health and Welfare, Kaohsiung, Taiwan (China); Tsai, Cheng-Hsien [Department of Pediatrics, National Taiwan University Hospital Yun-Lin Branch, Yun-Lin, Taiwan (China); Chiang, Hung-Che, E-mail: hcchiang@nhri.org.tw [National Environmental Health Research Center, National Institute of Environmental Health Sciences, National Health Research Institutes, Miaoli, Taiwan (China); Division of Environmental Health and Occupational Medicine, National Institute of Environmental Health Sciences, National Health Research Institutes, Miaoli, Taiwan (China); Chan, Chang-Chuan, E-mail: ccchan@ntu.edu.tw [Institute of Occupational Medicine and Industrial Hygiene, College of Public Health, National Taiwan University, Taipei, Taiwan (China)

2016-10-15

Background: School-aged children living in the vicinity of vinyl chloride (VCM)/polyvinyl chloride (PVC) factories may have an increased risk of exposure to hazardous air pollutants. Objectives: We aimed to evaluate the urinary thiodiglycolic acid (TDGA) level, as TDGA is a major metabolite of VCM, for students at elementary schools near a petrochemical complex in central Taiwan. Methods: We recruited 343 students from 5 elementary schools based on distance to the VCM/PVC factory. First-morning urine and blood samples were obtained from our subjects from October 2013 to September 2014. Urine samples were analyzed for urinary creatinine and TDGA using LC/MS–MS. Hepatitis virus infection were assessed using blood samples. We determined their vitamin consumption, resident location, parent’s employment, and other demographic or lifestyle characteristics using a questionnaire. Results: Median urinary TDGA levels for 316 students at 5 elementary schools from the closest (<.9 km) to the farthest (∼8.6 km) with respect to the petrochemical complex were 147.6, 95.5, 115.5, 86.8, and 17.3 μg/g creatinine, respectively. After adjusting for age, gender, hepatitis virus infection, vitamin B consumption, passive smoking, and home to source distance, we found that urinary TDGA levels for the closest students was significantly higher than those at other schools. Further, median urinary TDGA levels for students during school time were 4.1-fold higher than those during summer vacation. Conclusions: After adjusting for confounders, urinary TDGA levels for the school-aged children decreased with increasing distances between the elementary schools and the petrochemical complex. - Highlights: • We conducted a bio-monitoring survey of students nearby a petrochemical complex. • We measured thiodiglycolic acid (TDGA) as a biomarker of vinyl chloride monomer. • Increased urinary TDGA levels in students nearby a VCM factory was found. • Significantly lower urinary TDGA levels

Assessment of urinary thiodiglycolic acid exposure in school-aged children in the vicinity of a petrochemical complex in central Taiwan

International Nuclear Information System (INIS)

Huang, Po-Chin; Liu, Li-Hsuan; Shie, Ruei-Hao; Tsai, Chih-Hsin; Liang, Wei-Yen; Wang, Chih-Wen; Tsai, Cheng-Hsien; Chiang, Hung-Che; Chan, Chang-Chuan

2016-01-01

Background: School-aged children living in the vicinity of vinyl chloride (VCM)/polyvinyl chloride (PVC) factories may have an increased risk of exposure to hazardous air pollutants. Objectives: We aimed to evaluate the urinary thiodiglycolic acid (TDGA) level, as TDGA is a major metabolite of VCM, for students at elementary schools near a petrochemical complex in central Taiwan. Methods: We recruited 343 students from 5 elementary schools based on distance to the VCM/PVC factory. First-morning urine and blood samples were obtained from our subjects from October 2013 to September 2014. Urine samples were analyzed for urinary creatinine and TDGA using LC/MS–MS. Hepatitis virus infection were assessed using blood samples. We determined their vitamin consumption, resident location, parent’s employment, and other demographic or lifestyle characteristics using a questionnaire. Results: Median urinary TDGA levels for 316 students at 5 elementary schools from the closest (<.9 km) to the farthest (∼8.6 km) with respect to the petrochemical complex were 147.6, 95.5, 115.5, 86.8, and 17.3 μg/g creatinine, respectively. After adjusting for age, gender, hepatitis virus infection, vitamin B consumption, passive smoking, and home to source distance, we found that urinary TDGA levels for the closest students was significantly higher than those at other schools. Further, median urinary TDGA levels for students during school time were 4.1-fold higher than those during summer vacation. Conclusions: After adjusting for confounders, urinary TDGA levels for the school-aged children decreased with increasing distances between the elementary schools and the petrochemical complex. - Highlights: • We conducted a bio-monitoring survey of students nearby a petrochemical complex. • We measured thiodiglycolic acid (TDGA) as a biomarker of vinyl chloride monomer. • Increased urinary TDGA levels in students nearby a VCM factory was found. • Significantly lower urinary TDGA levels

The Asian petrochemical industry

International Nuclear Information System (INIS)

Selwa, Christopher.

1996-03-01

The Asian Petrochemical Industry brings you up to date with the latest developments in this dynamic region and covers all the key issues, giving detailed analysis and comment on: the general economic outlook; demand and production trends for basic petrochemicals and specialities in individual countries; political stability and how with affects growth and investment opportunities; security of supply; the import of petrochemicals and the aim of the region to become a net exporter by 2000; capacity increases - the relative merits of new plant construction versus expanding existing plants; the financing of petrochemical projects; the use of appropriate projects; the use of appropriate technology and patent provision in the Gatt treaty; increasing environmental concerns and the 'responsible care' initiative. The Asian Petrochemical Industry presents an overview of each Asian player in the petrochemical and associated industries, comparing and contrasting the countries within the region. (Author)

Effluents and Solid Waste Analysis in a Petrochemical Company- A Case Study of Eleme Petrochemical Company Ltd, Port Harcourt, Nigeria

Directory of Open Access Journals (Sweden)

A. U. Israel

2008-01-01

Full Text Available Effluents and soil samples where sediments from the treated effluents are dumped were analyzed for physicochemical properties, metallic and non-metallic ions. These parameters were compared with established international standard (FEPA. Effluents were classified as process waste water (PWW, clarified water (CW, and final discharge (FD. The petrochemical effluents contained very high concentration of TDS (284.00±014 mg/L and significant concentrations of TSS (78.89±0.01 mg/L, COD (30.10±0.02 mg/L, DO (13.20±0.01 mg/L, BOD (6.12±0.00 mg/L, PO43- (4.34±0.00 mg/L, SO42- (3.59±0.00 mg/L, Cl- (55.52±0.01 mg/L and NO3- (8.40±0.01 mg/L. Low concentrations of iron, zinc, copper, cadmium, lead, nickel and cobalt was also observed. Some heavy metals were not detected at all in some of the effluent samples analyzed. Apart from temperature and total dissolved solid TDS, all the other parameters were below FEPA effluent limitations for guidelines for Petroleum Refinery, Fuel/Gasoline oil category in Nigeria.

Components of sustainability considerations in management of petrochemical industries.

Science.gov (United States)

Aryanasl, Amir; Ghodousi, Jamal; Arjmandi, Reza; Mansouri, Nabiollah

2017-06-01

Sustainability comprises three pillars of social, environmental, and economic aspects. Petrochemical industry has a great inter-related complex impact on social and economic development of societies and adverse impact on almost all environmental aspects and resource depletion in many countries, which make sustainability a crucial issue for petrochemical industries. This study was conducted to propose components of sustainability considerations in management of petrochemical industries.A combination of exploratory study-to prepare a preliminary list of components of sustainable business in petrochemical industries based on review of literature and Delphi-to obtain experts' view on this preliminary list and provide a detailed list of components and sub-components that should be addressed to bring sustainability to petrochemical industries, were used.Two sets of components were provided. First general components, which include stakeholders (staffs, society, and environment) with four sub-components, financial resources with 11 sub-components, improvement of design and processes with nine sub-components, policy and strategy of cleaner production with seven sub-components and leadership with seven sub-components. The second operational components included raw material supply and preparation with five, synthesis with ten, product separation and refinement with nine, product handling and storage with five, emission abatement with eight, and improvement of technology and equipment with 16 sub-components.

Whether integrating refining and petrochemical business can provide opportunities for development of petrochemical industry in Serbia

Directory of Open Access Journals (Sweden)

Popović Zoran M.

2016-01-01

Full Text Available Since the beginning of 90s of last century both the petroleum industry and petrochemical industry have operated in difficult circumstances. In particularly, margins of petroleum and petrochemical industry were exacerbated during global economic crisis in 2008-2009 years. At that time, as one option that could be the solution, the global analysts had started to more intense investigate the benefits of Refining-Petrochemical Integration. Shortly afterwards, more and more petroleum refineries and petrochemical manufacturers began to see the future in this kind of operational, managerial, marketing and commercial connection. This paper evaluates, in particular, the achieved level of integration of refinery and petrochemical businesses in Central and South-Eastern Europe. And specifically, the paper identifies current capabilities and future chances of linking this kind of integration between Serbian refining and petrochemical players. The viability of integration between possible actors and benefits of every single refining-petrochemical interface in Serbia depend on many factors, and therefore each integrated system is unique and requires prior serious Cost Benefit Analysis.

Maximizing petrochemicals from refineries

Energy Technology Data Exchange (ETDEWEB)

Glover, B.; Foley, T.; Frey, S. [UOP, Des Plaines, IL (United States)

2007-07-01

New fuel quality requirements and high growth rates for petrochemicals are providing both challenges and opportunities for refineries. A key challenge in refineries today is to improve of the value of the products from the FCC unit. In particular, light FCC naphtha and LCO are prime candidates for improved utilization. Processing options have been developed focusing on new opportunities for these traditional fuel components. The Total Petrochemicals/UOP Olefin Cracking Process cracks C4-C8 olefins to produce propylene and ethylene. This process can be integrated into FCC units running at all severity levels to produce valuable light olefins while reducing the olefin content of the light FCC naphtha. Integration of the Olefin Cracking Process with an FCC unit can be accomplished to allow a range of operating modes which can accommodate changing demand for propylene, cracked naphtha and alkylate. Other processes developed by UOP allow for upgrading LCO into a range of products including petrochemical grade xylenes, benzene, high cetane diesel and low sulfur high octane gasoline. Various processing options are available which allow the products from LCO conversion to be adjusted based on the needs and opportunities of an individual refinery, as well as the external petrochemical demand cycles. This presentation will examine recent refining and petrochemical trends and highlight new process technologies that can be used to generate additional revenue from petrochemical production while addressing evolving clean fuel demands. (orig.)

A demonstration of biofiltration for VOC removal in petrochemical industries.

Science.gov (United States)

Zhao, Lan; Huang, Shaobin; Wei, Zongmin

2014-05-01

A biotrickling filter demo has been set up in a petrochemical factory in Sinopec Group for about 10 months with a maximum inlet gas flow rate of 3000 m3 h(-1). The purpose of this project is to assess the ability of the biotrickling filter to remove hardly biodegradable VOCs such as benzene, toluene and xylene which are recalcitrant and poorly water soluble and commonly found in petrochemical factories. Light-weight hollow ceramic balls (Φ 5-8 cm) were used as the packing media treated with large amounts of circulating water (2.4 m3 m(-2) h(-1)) added with bacterial species. The controlled empty bed retention time (EBRT) of 240 s is a key parameter for reaching a removal efficiency of 95% for benzene, toluene, xylene, and 90% for total hydrocarbons. The demo has been successfully adopted and practically applied in waste air treatments in many petrochemical industries for about two years. The net inlet concentrations of benzene, toluene and xylene were varied from 0.5 to 3 g m(-3). The biofiltration process is highly efficient for the removal of hydrophobic and recalcitrant VOCs with various concentrations from the petrochemical factories. The SEM analysis of the bacterial community in the BTF during VOC removal showed that Pseudomonas putida and Klebsiella sp. phylum were dominant and shutdown periods could play a role in forming the community structural differences and leading to the changes of removal efficiencies.

Long-term study of an estuarine mudflat subjected to petro-chemical discharges

International Nuclear Information System (INIS)

McLusky, D.A.; Martins, T.

1998-01-01

The Kinneil intertidal area, situated in the middle reaches of the Forth estuary, eastern Scotland, has been subject to the effects of industrial discharges, principally from petro-chemical industries (oil refinery and chemical works) since the 1920s. The intertidal fauna has been studied annually since 1976 using consistent methodology. The study continues, now providing over 20 yrs of data. During the study period the discharges from the industrial sources have been reduced substantially through a combination of plant closure and modernization and the installation of effluent treatment works. Furthermore, the River Avon which flows across the area has experienced substantial improvements in water quality, attributed to improvements in waste treatment works at localities upstream from the estuarine site. Overall, however, the clearest trends have been increases in diversity, expressed either as mean number of species per station, or as diversity indices. These increases in diversity are shown to be a clear community response to the improvements made to the petro-chemical wastes discharged to the area. (author)

More valuable as petrochemical feedstock

International Nuclear Information System (INIS)

Ramachandran, R.

2005-01-01

The problems facing the North American petrochemical industry were discussed with particular reference to the fact that high North American prices present a challenge to competitiveness in a globally traded market. A background of Dow Canada was provided, including details of its upgrading of natural gas liquids that would otherwise be combusted for electrical power generation. The value of the petrochemical industry was outlined, with details of employment, manufacturing output and exports. Alberta's relationship to the natural gas industry was reviewed. The role of petrochemicals as a nexus for bridging the resource sector with manufacturing, retail and transportation was discussed. The historic correlation between world Gross Domestic Product (GDP) and ethylene demand was presented. It was noted that the petrochemical industry currently competes with power generators for smaller volumes of natural gas liquids. As a highly energy intensive industry, inequities in gas pipeline haul charges and even small increases in gas prices has compromised the success of the petrochemical industry. It was noted that while crude oil is a globally traded commodity, natural gas liquids are generally traded at a more localized level, and factors that helped build the petrochemical industry and are now inhibiting growth. Ethane is the primary feedstock in the petrochemical industry. High natural gas prices affected the industry on two levels: volatility in a weakening industry and higher prices on primary feedstocks. It was estimated that changes in current trends were likely to take place in 5 to 10 years, following Northern gas developments. It was estimated that more than 50 per cent of new capacity investment in ethylene plants would take place in the Middle East in the next 5 years. No new plants are planned in Canada. It was concluded that low-cost feedstock advantages, as well as alternative feedstocks and the sustainment of a healthy industry are necessary for the

Chronic lymphocytic thyroiditis: could it be influenced by a petrochemical complex? Data from a cytological study in South-Eastern Sicily.

Science.gov (United States)

Arena, Salvatore; Latina, Adele; Baratta, Roberto; Burgio, Giuseppe; Gullo, Damiano; Benvenga, Salvatore

2015-04-01

In genetically predisposed individuals, exogenous factors (including pollution) influence the development of Hashimoto's thyroiditis/chronic lymphocytic thyroiditis (CLT). CLT may also be a risk factor for associated thyroid cancer. Few data are available on the role of pollution from petrochemical complexes, one of which is located in the Siracusa province (South-Eastern Sicily), in the pathogenesis of CLT. i) To study the frequency of CLT in fine-needle aspiration cytology (FNAC)-interrogated thyroid nodules from patients who were stably resident in their zones, comparing it in patients living in the petrochemical complex area (zone A) with that of patients from a control area (zone B). ii) To study the frequency of CLT in the FNAC categories of malignancy risk, comparing the two zones. We retrospectively evaluated cytologically adequate slides of 1323 nodules in 1013 outpatients who underwent ultrasound-guided FNAC from 2006 to 2012. We stratified by area of residence, gender, and FNAC categories of malignancy risk. CLT was detected with significantly greater frequency in either patients or nodules from zone A compared with zone B (32.0% vs 23.1%, P=0.002 or 28.2% vs 18.8%, P=0.0001), with a female preponderance (F=35.2% vs M=21.1% or 30.4% vs 20.4%, zone A and F=26.5% vs 12.3% or 21.6% vs 9.5%, zone B). Regardless of zone, CLT was approximately twofold more frequent in the suspiciously malignant+malignant classes (TH4+THY5=47.6%, zone A and 32.4%, zone B) compared with the benign+intermediate classes (THY2+THY3=27.3%, zone A and 18.2%, zone B), but with a clear stepwise THY2 through THY5 increase only in zone A (THY2=25.3%, THY5=66.7%; THY2=18.6%, THY5=28.6% in zone B). The petrochemical complex-related pollution is an environmental factor involved in the development of CLT and, likely, in the CLT association with thyroid neoplasms. © 2015 European Society of Endocrinology.

Health risk evaluation in a population exposed to chemical releases from a petrochemical complex in Thailand.

Science.gov (United States)

Kampeerawipakorn, Ormrat; Navasumrit, Panida; Settachan, Daam; Promvijit, Jeerawan; Hunsonti, Potchanee; Parnlob, Varabhorn; Nakngam, Netnapa; Choonvisase, Suppachai; Chotikapukana, Passaornrawan; Chanchaeamsai, Samroeng; Ruchirawat, Mathuros

2017-01-01

Emissions from petrochemical industries may contain toxic and carcinogenic compounds that can pose health risk to human populations. The scenario may be worse in developing countries where management of such exposure-health problems is typically not well-implemented and the public may not be well-informed about such health risk. In Thailand, increasing incidences of respiratory diseases and cancers have been reported for the population around a major petrochemical complex, the Map Ta Phut Industrial Estate (MTPIE). This study aimed to systematically investigate an exposure-health risk among these populations. One-hundred and twelve healthy residents living nearby MTPIE and 50 controls located approximately 40km from MTPIE were recruited. Both external and internal exposure doses to benzene and 1,3-butadiene, known to be associated with the types of cancer that are of concern, were measured because they represent exposure to industrial and/or traffic-related emissions. Health risk was assessed using the biomarkers of early biological effects for cancer and inflammatory responses, as well as biomarkers of exposure for benzene and 1,3-butadiene. The exposure levels of benzene and 1,3-butadiene were similar for both the exposed and control groups. This was confirmed by a non-significant difference in the levels of specific urinary metabolites for benzene (trans,trans-muconic acid, t,t-MA) and 1,3-butadiene (monohydroxy-butyl mercapturic acid, MHBMA). Levels of 8-hydroxydeoxyguanosine (8-OHdG) and DNA strand breaks between the two groups were not statistically significantly different. However, functional biomarkers, interleukin-8 (IL-8) expression was significantly higher (pindustrial complex could be causing these functional abnormalities. Copyright © 2016 Elsevier Inc. All rights reserved.

Transformation of the Czech refinery and petrochemical

International Nuclear Information System (INIS)

Junek, V.

1995-01-01

The petrochemical and chemical industries in former Czechoslovakia in the period after World War II was built up with a purpose to create a complex whose individual subjects would be closely interlinked from the point of view of their production programmes. The separation of Slovakia as an independent state has disrupted some of these links. In spite of that the petrochemical and chemical industries are nowadays the most prosperous branches of economy of the Czech Republic. The governmental proposal for the reorganizing of the refinery and petrochemical complex elaborated in connection with the resolution of the Governmental Privatization Commission of November 6 1994 proposed the formation of a holding company Unipetrol in the way of merging Chemopetrol and Kaucuk with a new joint stock company Unipetrol established for this purpose by the National Property Fund. The updated proposal offers formation of the holding organization Unipetrol in a substantially simpler, from the point of view of time, organization and financing less demanding manner. This proposal is based on the following principles: respecting the approved privatization projects, the solution must not have influence on the rights and position of natural and juristic persons who became shareholders in accordance with the privatization projects already approved, the influence of the state on decisions of the holding and its daughter companies will be maintained with regard to the security of the state and supplying the strategically important subjects with fuels in situation of a crisis, the share of the business subjects in the shares of the holding will be such that it would enable them from the very beginning to participate effectively and not only formally in the decisions. 2 figs

Refining and petrochemicals

International Nuclear Information System (INIS)

Benazzi, E.; Alario, F.

2004-01-01

In 2003, refining margins showed a clear improvement that continued throughout the first three quarters of 2004. Oil companies posted significantly higher earnings in 2003 compared to 2002, with the results of first quarter 2004 confirming this trend. Due to higher feedstock prices, the implementation of new capacity and more intense competition, the petrochemicals industry was not able to boost margins in 2003. In such difficult business conditions, aggravated by soaring crude prices, the petrochemicals industry is not likely to see any improvement in profitability before the second half of 2004. (author)

The prospects for using nuclear reactors to provide energy to petrochemical factories

Energy Technology Data Exchange (ETDEWEB)

Feygin, Ye.A.; Barashkov, R.Ya.; Chernovisov, G.N.; Deyneko, P.S.; Lemayev, N.V.; Raud, E.A.; Romanova, Ye.G.; Vernov, P.A.; Zlotnikov, L.Ye.

1984-01-01

The engineering level of the development of atomic rocket engineering has made it possible to consider various types of nuclear reactors as possible electricity sources to support petrochemical processes at petrochemical plants (using vapor, heat, electricity and radiation energies). The use of energy from nuclear reactors in combination with the elimination of liquid and gas fuels used in the furnaces will make it possible to improve the ecological situation in the vicinity of the plant, to accelerate petroleum processing and oil processing processes and to improve the cost effectiveness of nuclear engineering complexes to a degree related to the total capacity of the industrial complexes and the degree of comprehensive utilization of energy from the nuclear reactors.

Transformation of heavy gas oils derived from oil sands to petrochemical feedstock

Energy Technology Data Exchange (ETDEWEB)

Du Plessis, D.; Laureshen, C. [Alberta Energy Research Inst., Edmonton, AB (Canada)

2006-07-01

Alberta's petrochemical industry is primarily based on ethane. However, ethane could potentially impede future growth of Alberta's petrochemical industry because of increasing cost and diminishing supplies. Alternately, the rapidly growing oil sands production could provide abundant new feedstocks. Different integration schemes and technologies were evaluated in this study. Research on converting bitumen-derived heavy gas oil into petrochemical feedstock has resulted in the development of two novel technologies and process integration schemes, notably the NOVA heavy oil laboratory catalyst (NHC) process and the aromatic ring cleavage (ARORINCLE) process. This paper described progress to date on these two projects. The paper presented the experimental results for each scheme. For the ARORINCLE process, results were discussed in terms of the effect of process parameters on the hydrogenation step; effect of process parameters on the ring cleavage step; and integrating the upgrading and petrochemical complex. Early laboratory stage results of these two technologies were found to be encouraging. The authors recommended that work should progress to larger scale demonstration of the NHC and ARORINCLE technologies., 13 refs., 2 tabs., 5 figs.

Thai petrochemical boom on track

International Nuclear Information System (INIS)

Anon.

1992-01-01

This paper reports that Thailand continues to mark progress on the ambitious expansion of its petrochemical industry. Among recent developments: The outlook for Thailand's troubled worldscale aromatics project has improved with a major cut in its estimated cost. In addition, the project apparently has drawn the interest of other companies seeking a possible equity stake. Amoco Chemical Co., which lost a tender to build a worldscale purified terephathalic acid (PTA) complex in Thailand to Taiwan's Tuntex Co., is reviving its bid with a proposal similar to its earlier one. Amoco contends there will be enough demand to warrant a second PTA plant in Thailand. Tuntex is negotiating with several business groups to take part in its $333 million, 350,000 ton/year PTA project in Thailand. Tuntex is soliciting interest from a number of Thai companies, including Bangkok Bank and the Saha Union industrial conglomerate to acquire portions of the 51% interest in the project earmarked for Thai shareholders. The firm also is negotiating with a number of Japanese companies with whom it has long trade ties, including Mitsui and Co. and Marubeni Corp. to acquire part of the 49% foreign shareholding in the project. Thai Olefins Co. (TOC) marked further progress with feedstock contracts and financing arrangements for its proposed $720 million olefins plant, part of Thailand's second worldscale petrochemical complex (NPC II). Indian industrial giant Birla proposed a $20 million ethylene glycol (EG) project in Thailand

Proceedings of the CERI 2005 petrochemical conference: competing in a global marketplace. CD-ROM ed.

International Nuclear Information System (INIS)

2005-01-01

The focus of this conference was on the Canadian petrochemical industry's global competitiveness and potential markets. Recent advances in technology were explored, as well as issues concerning transportation and infrastructure. Capital cost requirements and feedstock availability were examined, as well as opportunities in growth and product diversification. Issues currently challenging the petrochemical industry and its relationship to the energy sector were reviewed. Alberta's place in the North American energy complex was discussed, along with issues concerning feedstock from Canadian oil sands. An overview of North America's position in the world petrochemicals market was presented, and outlooks for future trade with China were discussed. Outlines of the United States and Middle East petrochemical industries were presented, and Russia's role in global energy security was examined. The conference was divided into the following 7 sessions: (1) global conditions for the petrochemical industry; (2) energy supply outlook; (3) transportation and trade; (4) pan-Canadian synergies in petrochemicals and refining; (5) maintaining competitiveness and product and market diversity; (6) capital costs and constraints; and (7) contributions towards global leadership. Twenty-three papers were presented at the conference. refs., tabs., figs

Iran's petrochemical industry : status and prospects

International Nuclear Information System (INIS)

Jazayeri, S.

2006-01-01

This presentation provided some basic information, current status and prospects for Iran's petrochemical industry with particular reference to Iran's National Petrochemical Company (NPC), one of the fastest growing chemical producers and exporters in the world. According to Chemical Marketing Associates Inc. (CMAI), NPC will become the second largest commodity chemical producer in the world by 2015, ranking only behind Dow Chemical. Product categories include chemicals and aromatics; fertilizers; polymers; feedstocks and gas. Opportunities for cooperation with North America were also identified. Iran's domestic markets were shown to be well developed downstream petrochemical industries producing a broad range of industrial and consumer goods. Iran's foreign markets include Asia (66 per cent), Middle East (25 per cent), and Europe (9 per cent). This presentation examined Iran's comparative advantage in the further development of its petrochemical/chemical industries. Some details of NPC's organizational structure were also provided, along with production, domestic sales, exports and ongoing expansion and development projects. Remarks on the projected and potential growth in NPC's position in the world markets were included with reference to potential for foreign participation and investment into the petrochemical industry in Iran. tabs., figs

Optimization of phenol biodegradation by efficient bacteria isolated from petrochemical effluents

Directory of Open Access Journals (Sweden)

M. Shahriari Moghadam

2016-05-01

Full Text Available Phenol is an environmental pollutant present in industrial wastewaters such as refineries, coal processing and petrochemicals products. In this study three phenol degrading bacteria from Arak Petrochemical Complex effluent were isolated which consume phenol. Molecular analysis was used to identify bacteria and isolated bacteria were identified as Rhodococcus pyridinivorans (NS1, Advenella faeciporci (NS2 and Pseudomonas aeroginosa (NS3. Among the isolated strains, NS1 had the highest ability to degrade phenol. In order to observe the best yield in phenol biodegradation using NS1, optimization was performed using one factor at a time of experimental design to investigate the effect of four factors, including pH, temperature, phosphate and urea concentration. The optimal biodegradation condition through or tho pathway was pH = 8, urea = 1 g/L, temperature = 30°C and K2HPO4 = 0.5 g/L. Under the suggested condition, a biodegradation efficiency of 100% was achieved. Moreover, NS1 has shown growth and phenol degradation in concentrations between 250 to 2000 mg/L. In a nutshell, the results revealed thatphenol efficiently consumed by NS1 as the sole carbon source. Obviously, the isolate strain may be seen as an important tool in the bioremediation of wastewater effluent, petrochemical complex.

Central waste complex interim safety basis

International Nuclear Information System (INIS)

Cain, F.G.

1995-01-01

This interim safety basis provides the necessary information to conclude that hazards at the Central Waste Complex are controlled and that current and planned activities at the CWC can be conducted safely. CWC is a multi-facility complex within the Solid Waste Management Complex that receives and stores most of the solid wastes generated and received at the Hanford Site. The solid wastes that will be handled at CWC include both currently stored and newly generated low-level waste, low-level mixed waste, contact-handled transuranic, and contact-handled TRU mixed waste

Facing the petrochemical competition. Are you prepared?

International Nuclear Information System (INIS)

Baggett, P.E.

1997-01-01

The factors that impact petrochemical supply, demand and economics were discussed. Petrochemicals are the basis for most commodities consumed in today's society. The demand for these products is determined by the economy and by the population. Recent changes in the world's political structure will have an impact on the petrochemical industry. There is evidence that petrochemical activity is shifting to the developing regions of the world as a result of the fall of communism, the fall of some dictatorships and the privatization of state enterprises. In 1980, the world's economic strength was in Western Europe, North America, and Japan, with 78 per cent of the world's GDP. It was forecast that by 2010, these three areas will only account for 70 per cent of the world's GDP. Shifting population and economies will increase per capita incomes in Eastern Europe, South America, and Asia. These areas will see an increase in purchases of petrochemicals products. Demand for base petrochemicals is expected to increase by 106 million tons over the next ten years. However, to survive in a competitive market, companies will have to develop programs to reduce costs, integrate and be prepared to take advantage of opportunities created by the supply/demand cycles

Construction Management of Electromechanical Engineering Project in Petrochemical Construction

Directory of Open Access Journals (Sweden)

Xi Tao

2017-03-01

Full Text Available Petrochemical industry as a basic industry, occupies a pivotal position in the national economy, with the continuous development of science and technology, electromechanical automation in the petrochemical industry has been widely used to save a lot of labor but also greatly improve the oil Chemical industry production efficiency. Therefore, in the construction of petrochemical industry, mechanical and electrical engineering as part of it. It plays a vital role. Petrochemical industry with the production of high temperature and high pressure and flammable and explosive gas, can strengthen the construction of mechanical and electrical engineering specialization and construction management of scientific, has become the relationship between the smooth development of mechanical and electrical engineering and engineering quality of the key, A direct impact on the petrochemical construction of the overall construction quality. To this end, it is necessary for the construction of petrochemical construction of electromechanical engineering construction management to promote the construction of mechanical and electrical engineering management level gradually increased. This article on the machine Electric engineering project construction management were discussed with a view to the petrochemical construction in the relevant aspects of the need to provide reference for reference.

Health risk assessment of chemical pollutants in a petrochemical complex

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F Golbabaie

2012-12-01

Full Text Available   Background and Aims: workers in petrochemical industries are exposed to various contaminants and are facing to serious hazards, therefore a comprehensive risk assessment program for identification of hazardous chemicals that affect human health and also determination of hazardous tasks and processes is necessary.     Methods : This descriptive cross-sectional study was conducted in three stages. First stage consisted of identifying hazardous chemicals and determination of chemicals risk ratio, the second stage included the evaluation of worker's exposure to hazardous chemicals, and the third stage was estimating the relative risk of blood cancer caused by exposure to benzene through epidemiological studies.     Results: With regard to risk assessment method, 40 chemicals were identified in this Petrochemical Company. Among them, Benzene introduced as the most hazardous chemical. The results of the second stage showed that site man workers in noon shift work and in aromatic site with mean exposure 4.29 ppm had the highest exposure to benzene. The results of estimated leukemia relative risk stage in benzene exposure, the highest relative risk in workers related to site man workers in aromatic units with cumulative benzene exposure of 4.149 ppm. Years that obtained the relative risk of 2.3. The statistical test results showed that the relationship between worker's exposure to benzene and their job was significant(p<0/001     Conclusion : This study showed that benzene with a risk ratio of 4.5 -5 have 5th rank in risk levels and this indicates that preventative actions regarding to this hazardous and carcinogenic chemical must be started as soon as possible.

Malaysia: oil, gas, petrochemicals

International Nuclear Information System (INIS)

1990-01-01

Petronas or Petroliam Nasional Berhad was established on 17 August 1974 as the national petroleum corporation of Malaysia. The Petroleum Development Act, passed by the Malaysian Parliament in October of that same year, vested in Petronas the entire ownership of all oil and natural gas resources in the country. These resources are considerable and Malaysia is poised to become one of the major petrochemical producers in the region. This report outlines the extent of oil, gas and petrochemicals production in Malaysia, lists companies holding licences and contracts from Petronas and provides a directory of the Malaysian oil industry. (Author)

Modelling of rational economic proportions of the balance sheet structure of the petrochemical enterprises

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G. S. Tsvetkova

2016-01-01

Full Text Available The paper provides the assessment of the balance sheet structure of rival companies of a petrochemical complex of the Russian Federation. J. Aubert-Kriye's method is chosen as a main methodical tool. Practical demonstration of the method is offered on the example of the enterprises of petrochemical business of PJSC “Sibur”, PJSC “Nizhnekamskneftekhim” and JSC “Sterlitamak Petrochemical Plant”. The analysis of balance sheets showed that the enterprises have elements of irrational structure. “Sibur” differs in a low share of owner’s equity and a high share of long-term liabilities. “Nizhnekamskneftekhim” is characterized by the high share of owner’s equity which use for the purposes of development of the company and it is more expensive in comparison with liabilities. “Sterlitamak Petrochemical Plant” has excessive values of liquidity rates that demonstrates accumulation of a money, their derivation in receivables. At the same time, processes of ongoing investment in upgrade of the equipment and expansion of capacities require cause necessity of support of a rational balance sheet structure of the enterprises of a petrochemical complex. On the example of “Nizhnekamskneftekhim” modeling of a rational balance sheet structure of the company is carried out. The sequence of calculations included performing diagnostics of structural distribution of current assets and sources of means; determination of structure of financial and active elements of the entity; establishment of permissible limit of change of basic proportions and ratios by criterion of solvency and financial stability. Modeling of structure of a liability and current assets on the basis of the J. Aubert-Kriye's method showed a possibility of improvement of economic indicators of “Nizhnekamskneftekhim”. Further determination of range of tolerance for elements of the liabilities and current assets will allow to provide balance of economic proportions and

Refining and petrochemicals

Energy Technology Data Exchange (ETDEWEB)

Constancio, Silva

2006-07-01

In 2004, refining margins showed a clear improvement that persisted throughout the first three quarters of 2005. This enabled oil companies to post significantly higher earnings for their refining activity in 2004 compared to 2003, with the results of the first half of 2005 confirming this trend. As for petrochemicals, despite a steady rise in the naphtha price, higher cash margins enabled a turnaround in 2004 as well as a clear improvement in oil company financial performance that should continue in 2005, judging by the net income figures reported for the first half-year. Despite this favorable business environment, capital expenditure in refining and petrochemicals remained at a low level, especially investment in new capacity, but a number of projects are being planned for the next five years. (author)

Refining and petrochemicals

International Nuclear Information System (INIS)

Constancio, Silva

2006-01-01

In 2004, refining margins showed a clear improvement that persisted throughout the first three quarters of 2005. This enabled oil companies to post significantly higher earnings for their refining activity in 2004 compared to 2003, with the results of the first half of 2005 confirming this trend. As for petrochemicals, despite a steady rise in the naphtha price, higher cash margins enabled a turnaround in 2004 as well as a clear improvement in oil company financial performance that should continue in 2005, judging by the net income figures reported for the first half-year. Despite this favorable business environment, capital expenditure in refining and petrochemicals remained at a low level, especially investment in new capacity, but a number of projects are being planned for the next five years. (author)

A Study of the Unsafe Actions of Staff in the Maintenance and Overhaul Unit at a Petrochemical Complex and the Presentation of Control Strategies

Directory of Open Access Journals (Sweden)

Mousavipour

2016-02-01

Full Text Available Background Today, oil, gas, and petrochemical industries are of strategic significance in the macro-development of oil-rich countries. These industries, given the nature of the work and the technical complexity of the various processes, are hazardous and susceptible to occupational accidents. More than 90% of the accidents are related to the faults and unsafe actions of personnel, either directly or indirectly. Objectives The aim of this study is to investigate the unsafe actions of staff working in the maintenance unit of a petrochemical complex. Materials and Methods This is a descriptive and analytical study conducted on 167 morning-shift workers at the Mahshahr petrochemical complex. The data were collected based on a checklist of unsafe actions prepared through a direct observation of their activities and an analysis of work instructions, documents, and incident reports. SPSS statistical software was also used for data analysis and relevant testing. Results According to the results of this study, the mean number of unsafe actions performed by the employees was 42%. The highest number of unsafe actions achieved in the maintenance mechanical unit was 52.8%, 47.1% in repair services, and 43.8% in machinery. The highest frequency of unsafe actions were caused by indiscretion and negligence, a failure to use a face shield and goggles, and non-compliance with safety principles. Conclusions According to the findings, there has been a rise in the number of unsafe actions in machinery and maintenance service units compared to other maintenance units. As such, training courses based on the behavior-based safety principles at the beginning of employment, close monitoring of health safety environment (HSE officials on the implementation of regulations, and provision of appropriate scheduling based on weather conditions and the nature of maintenance services are recommended. In addition, a refrainment from hastiness in performing duties, enhanced

ISO 9000: The challenge of Camacari petrochemical complex, Bahia State - Northeast Brazil; ISO 9000: o desafio do polo petroquimico de Camacari, BA, Brazil

Energy Technology Data Exchange (ETDEWEB)

Oliveira, Marcos Antonio Lima de; Carvalho Neto, Jose

1993-12-31

The petrochemical complex of Camacari, BA, Brazil, involves 40 companies, responsible for 55% of brazilian production. The companies were installed using the most modern techniques related to quality available at that time, strongly centered in quality control. The new industrial policy towards reducing import taxes and allowing the entrance of foreign products at competitive prices, besides the quality exigencies of international market, induced the companies to develop new techniques for quality management based in the ISO 9000 standards. The paper shows the stage of implementation of these standards in 30 companies, corresponding to 90% of global sales of all the complex. (author)

ISO 9000: The challenge of Camacari petrochemical complex, Bahia State - Northeast Brazil; ISO 9000: o desafio do polo petroquimico de Camacari, BA, Brazil

Energy Technology Data Exchange (ETDEWEB)

Oliveira, Marcos Antonio Lima de; Carvalho Neto, Jose

1992-12-31

The petrochemical complex of Camacari, BA, Brazil, involves 40 companies, responsible for 55% of brazilian production. The companies were installed using the most modern techniques related to quality available at that time, strongly centered in quality control. The new industrial policy towards reducing import taxes and allowing the entrance of foreign products at competitive prices, besides the quality exigencies of international market, induced the companies to develop new techniques for quality management based in the ISO 9000 standards. The paper shows the stage of implementation of these standards in 30 companies, corresponding to 90% of global sales of all the complex. (author)

Cadmium complexation by solid waste leachates

DEFF Research Database (Denmark)

Xu Ze Lun; Christensen, Thomas H.

1989-01-01

A previously reported method for determination of Cd species in solid waste leachates has been applied to ten leachate samples representing five different types of solid waste: refuse compost, flyash from coal combustion, sewage sludge, refuse incineration residues and landfilled municipal waste......, slowly labile complexes and stable complexes. Leachates originating from the same type of solid waste showed different fractions of Cd, in particular with respect to free divalent Cd and stable Cd complexes. Only coal flyash showed almost identical fractions of Cd in the two leachates. The latter is due...

Hanford Central Waste Complex: Radioactive mixed waste storage facility dangerous waste permit application

International Nuclear Information System (INIS)

1991-10-01

The Hanford Site is owned by the US Government and operated by the US Department of Energy Field Office, Richland. The Hanford Site manages and produces dangerous waste and mixed waste (containing both radioactive and dangerous components). The dangerous waste is regulated in accordance with the Resource Conversation and Recovery Act of 1976 and the State of Washington Hazardous Waste Management Act of 1976. The radioactive component of mixed waste is interpreted by the US Department of Energy to be regulated under the Atomic Energy Act of 1954; the nonradioactive dangerous component of mixed waste is interpreted to be regulated under the Resource Conservation and Recovery Act of 1976 and Washington Administrative Code 173--303. Westinghouse Hanford Company is a major contractor to the US Department of Energy Field Office, Richland and serves as co-operator of the Hanford Central Waste Complex. The Hanford Central Waste Complex is an existing and planned series of treatment, storage, and/or disposal units that will centralize the management of solid waste operations at a single location on the Hanford facility. The Hanford Central Waste Complex units include the Radioactive Mixed Waste Storage Facility, the unit addressed by this permit application, and the Waste Receiving and Processing Facility. The Waste Receiving and Processing Facility is covered in a separate permit application submittal

Reducing NO(x) emissions from a nitric acid plant of domestic petrochemical complex: enhanced conversion in conventional radial-flow reactor of selective catalytic reduction process.

Science.gov (United States)

Abbasfard, Hamed; Hashemi, Seyed Hamid; Rahimpour, Mohammad Reza; Jokar, Seyyed Mohammad; Ghader, Sattar

2013-01-01

The nitric acid plant of a domestic petrochemical complex is designed to annually produce 56,400 metric tons (based on 100% nitric acid). In the present work, radial-flow spherical bed reactor (RFSBR) for selective catalytic reduction of nitric oxides (NO(x)) from the stack of this plant was modelled and compared with the conventional radial-flow reactor (CRFR). Moreover, the proficiency of a radial-flow (water or nitrogen) membrane reactor was also compared with the CRFR which was found to be inefficient at identical process conditions. In the RFSBR, the space between the two concentric spheres is filled by a catalyst. A mathematical model, including conservation of mass has been developed to investigate the performance of the configurations. The model was checked against the CRFR in a nitric acid plant located at the domestic petrochemical complex. A good agreement was observed between the modelling results and the plant data. The effects of some important parameters such as pressure and temperature on NO(x) conversion were analysed. Results show 14% decrease in NO(x) emission annually in RFSBR compared with the CRFR, which is beneficial for the prevention of NO(x) emission, global warming and acid rain.

The international petrochemical industry

International Nuclear Information System (INIS)

Chapman, K.

1991-01-01

The petrochemical industry occupies a crucial place in economic, strategic and political terms in the twentieth century. The author explains its growth and international distribution from the 1920s tot he present, relating the particular experience of petrochemicals to the processes that have shaped the long-term evolution of industry in general. The geographical coverage of this book extends from the regional to international scale, and its historical scope embraces one hundred years from the laboratory origins of polymer science and petrochemistry to the massive operations of modern industry. It represents the result of twenty years of research, and reflects the author's privileged access to company sources in both the U.S. and Europe

Application of radioactive techniques in the petrochemical plant

International Nuclear Information System (INIS)

Wei Weisheng; Wang Guorong; Yan Xiangfu

2006-01-01

Gamma scanning and neutron backscatter techniques, which are widely used in petrochemical plants, are briefly introduced. The fundamental is explained and the major applications in the petrochemical plants are given. Emphasis is placed on the industrial application of gamma scanning in tower operation and the neutron backscatter in the level detection of an industrial gas/liquid separator and a hydrogenation reactor. The application results show that radioactive techniques can play a key role in trouble shooting, optimization and predictive maintenance of the petrochemical devices. (authors)

Airborne trace elements near a petrochemical industrial complex in Thailand assessed by the lichen Parmotrema tinctorum (Despr. ex Nyl.) Hale.

Science.gov (United States)

Boonpeng, Chaiwat; Polyiam, Wetchasart; Sriviboon, Chutima; Sangiamdee, Duangkamon; Watthana, Santi; Nimis, Pier Luigi; Boonpragob, Kansri

2017-05-01

Several trace elements discharged by the petrochemical industry are toxic to humans and the ecosystem. In this study, we assessed airborne trace elements in the vicinity of the Map Ta Phut petrochemical industrial complex in Thailand by transplanting the lichen Parmotrema tinctorum to eight industrial, two rural, and one clean air sites between October 2013 and June 2014. After 242 days, the concentrations of As, Cd, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sb, Ti, V, and Zn in lichens at most industrial sites were higher than those at the rural and the control sites; in particular, As, Cu, Mo, Sb, V, and Zn were significantly higher than at the control site (p industrial sites. Principal component analysis (PCA) showed that most elements were associated with industry, with lesser contributions from traffic and agriculture. Based on the pollution load indexes (PLIs), two industrial sites were highly polluted, five were moderately polluted, and one had a low pollution level, whereas the pollution load at the rural sites was comparable to background levels. This study reinforces the utility of lichens as cost-effective biomonitors of airborne elements, suitable for use in developing countries, where adequate numbers of air monitoring instruments are unavailable due to financial, technical, and policy constraints.

DOE complex buried waste characterization assessment

International Nuclear Information System (INIS)

Kaae, P.S.; Holter, G.M.; Garrett, S.M.K.

1993-01-01

The work described in this report was conducted by Pacific Northwest Laboratory to provide information to the Buried Waste Integrated Demonstration (BWID) program. The information in this report is intended to provide a complex-wide planning base for th.e BWID to ensure that BWID activities are appropriately focused to address the range of remediation problems existing across the US Department of Energy (DOE) complex. This report contains information characterizing the 2.1 million m 3 of buried and stored wastes and their associated sites at six major DOE facilities. Approximately 85% of this waste is low-level waste, with about 12% TRU or TRU mixed waste; the remaining 3% is low-level mixed waste. In addition, the report describes soil contamination sites across the complex. Some of the details that would be useful in further characterizing the buried wastes and contaminated soil sites across the DOE complex are either unavailable or difficult to locate. Several options for accessing this information and/or improving the information that is available are identified in the report. This document is a companion to Technology Needs for Remediation: Hanford and Other DOE Sites, PNL-8328 (Stapp 1993)

Central Waste Complex (CWC) Waste Analysis Plan

International Nuclear Information System (INIS)

ELLEFSON, M.D.

2000-01-01

The purpose of this waste analysis plan (WAP) is to document the waste acceptance process, sampling methodologies, analytical techniques, and overall processes that are undertaken for waste accepted for storage at the Central Waste Complex (CWC), which is located in the 200 West Area of the Hanford Facility, Richland, Washington. Because dangerous waste does not include the source special nuclear and by-product material components of mixed waste, radionuclides are not within the scope of this document. The information on radionuclides is provided only for general knowledge. This document has been revised to meet the interim status waste analysis plan requirements of Washington Administrative Code (WAC) 173 303-300(5). When the final status permit is issued, permit conditions will be incorporated and this document will be revised accordingly

Hanford Central Waste Complex: Waste Receiving and Processing Facility dangerous waste permit application

International Nuclear Information System (INIS)

1991-10-01

The Hanford Central Waste Complex is an existing and planned series of treatment, and/or disposal (TSD) unites that will centralize the management of solid waste operations at a single location on the Hanford Facility. The Complex includes two units: the WRAP Facility and the Radioactive Mixed Wastes Storage Facility (RMW Storage Facility). This Part B permit application addresses the WRAP Facility. The Facility will be a treatment and storage unit that will provide the capability to examine, sample, characterize, treat, repackage, store, and certify radioactive and/or mixed waste. Waste treated and stored will include both radioactive and/or mixed waste received from onsite and offsite sources. Certification will be designed to ensure and demonstrate compliance with waste acceptance criteria set forth by onsite disposal units and/or offsite facilities that subsequently are to receive waste from the WRAP Facility. This permit application discusses the following: facility description and general provisions; waste characterization; process information; groundwater monitoring; procedures to prevent hazards; contingency plant; personnel training; exposure information report; waste minimization plan; closure and postclosure requirements; reporting and recordkeeping; other relevant laws; certification

Important TQM Implementation Contributors in Pakistani Petrochemical Sector

Directory of Open Access Journals (Sweden)

Yasir Latif

2014-10-01

Full Text Available This study discusses quality practices in Pakistani Petrochemical sector to understand TQM practices and their implementation in Pakistan. It helps to understand the role of leadership, vision & plan statement, employee participation and education & training as important constructs of TQM. It shows how these constructs help to speed up the TQM implementation in petrochemical sector like other constructs of TQM and finally company moves towards quality approach. The responses of executives, managerial staff and workers were received using questionnaire and online surveys which are sent through Google Drive. Data of 106 respondents was taken in this study and analyzed by SPSS18. Study shows that Total Quality Management culture is less understood by employees, thus less adopted and implemented in Pakistan. Petrochemical companies fail to adopt the TQM philosophy and processes, hence reducing productivity and profits. This research paper is very helpful for executives for TQM implementation in petrochemical sector.

Underground waters management program at Camacari petrochemical complex; Programa de gerenciamento das aguas subterraneas do Polo Petroquimico de Camacari

Energy Technology Data Exchange (ETDEWEB)

Santos, Paulo Roberto Penalva dos [Empresa de Protecao Ambiental S.A. (CETREL), Camacari, BA (Brazil); Nobre, Manoel de Melo Maia [Maia Nobre Engenharia Ltda., Maceio, AL (Brazil)

1996-12-31

The Camacari Petrochemical Complex, situated in the state of Bahia, is the largest and most important integrated industrial complex in Latin America. With the primary objective of preventing any environmental impact that could be caused by its processes, monitoring the quality of the air and water resources in the vicinity became common practice. In regard to the water resources, since 1992, the industries of the Camacari Complex, under the coordination of CETREL - Empresa de Protecao Ambiental S.A - have conducted an integrated program to monitor, protect and establish rational use of the groundwater resources at the region. This program complies with the conditions established by the Environmental Protection Board of Bahia State (CEPRAM). Several specific goals were already achieved by this program and others still under way. Some of them include: Elimination of most of the primary contaminant sources to groundwater; Evaluation of secondary sources based on plumes behavior and remediation of isolated areas with contaminated saturated and unsaturated zones; Interruption of production wells in the region to prevent contamination of deeper formations; Operations of a pump-and-treat system consisting of 12 extraction wells located down gradient of the Camacari Complex. (author) 7 refs.

Chemical and petrochemical industry

Science.gov (United States)

Staszak, Katarzyna

2018-03-01

The potential sources of various metals in chemical and petrochemical processes are discussed. Special emphasis is put on the catalysts used in the industry. Their main applications, compositions, especially metal contents are presented both for fresh and spent ones. The focus is on the main types of metals used in catalysts: the platinum-group metals, the rare-earth elements, and the variety of transition metals. The analysis suggested that chemical and petrochemical sectors can be considered as the secondary source of metals. Because the utilization of spent refinery catalysts for metal recovery is potentially viable, different methods were applied. The conventional approaches used in metal reclamation as hydrometallurgy and pyrometallurgy, as well as new methods include bioleaching, were described. Some industrial solutions for metal recovery from spent solution were also presented.

Integration of Microalgae-Based Bioenergy Production into a Petrochemical Complex: Techno-Economic Assessment

Directory of Open Access Journals (Sweden)

Ana L. Gonçalves

2016-03-01

Full Text Available The rapid development of modern society has resulted in an increased demand for energy, mainly from fossil fuels. The use of this source of energy has led to the accumulation of carbon dioxide (CO2 in the atmosphere. In this context, microalgae culturing may be an effective solution to reduce the CO2 concentration in the atmosphere, since these microorganisms can capture CO2 and, simultaneously, produce bioenergy. This work consists of a techno-economic assessment of a microalgal production facility integrated in a petrochemical complex, in which established infrastructure allows efficient material and energy transport. Seven different scenarios were considered regarding photosynthetic, lipids extraction and anaerobic digestion efficiencies. This analysis has demonstrated six economically viable scenarios able to: (i reduce CO2 emissions from a thermoelectric power plant; (ii treat domestic wastewaters (which were used as culture medium; and (iii produce lipids and electrical and thermal energy. For a 100-ha facility, considering a photosynthetic efficiency of 3%, a lipids extraction efficiency of 75% and an anaerobic digestion efficiency of 45% (scenario 3, an economically viable process was obtained (net present value of 22.6 million euros, being effective in both CO2 removal (accounting for 1.1 × 104 t per year and energy production (annual energy produced was 1.6 × 107 kWh and annual lipids productivity was 1.9 × 103 m3.

Petrochemical promoters in catalytic cracking

International Nuclear Information System (INIS)

Gomez, Maria; Vargas, Clemencia; Lizcano, Javier

2010-01-01

This study is based on the current scheme followed by a refinery with available Catalytic Cracking capacity to process new feedstocks such as Straight Run Naphtha and Naphthas from FCC. These feedstocks are of petrochemical interest to produce Ethane, Ethylene, Propylene, i-Butane, Toluene and Xylene. To evaluate the potential of these new streams versus the Cracking-charged Residues, it was performed a detailed chemical analysis on the structural groups in carbons [C1-C12] at the reactor product obtained in pilot plant. A catalyst with and without Propylene Promoter Additive was used. This study analyzes the differences in the chemical composition of the feedstocks, relating them to the yield of each petrochemical product. Straight Run Naphthas with a high content of Naphthenes, and Paraffines n[C5-C12] and i[C7-C12] are selective to the production of i-Butane and Propane, while Naphthas from FCC with a high content of n[C5-C12]Olefins, i-Olefins, and Aromatics are more selective to Propylene, Toluene, and Xylene. Concerning Catalytic Cracking of Naphthas, the Additive has similar selectivity for all the petrochemical products, their yields increase by about one point with 4%wt of Additive, while in cracking of Residues, the Additive increases in three points Propylene yield, corresponding to a selectivity of 50% (?C3= / ?LPG).

[Appraisal of occupational stressor in petrochemical industry workers].

Science.gov (United States)

Tang, Xiao-ping; Tian, Hong-er; Huang, Tong; Li, Zhi-yuan; Hu, Ke-ming; Ge, Xi-yong; Jin, Lei; Gao, Qi; Zhang, Jing-jing; Wang, Yu; Liu, Wen-he

2009-12-01

To discuss the origin of occupational stress among petrochemical industry workers and to access the main occupational stressors that impact job satisfaction and mental health of petrochemical industry workers. A survey on occupational stressor was carried out by Occupational Stress Indicator (OSI) in 532 petrochemical industry workers (345 chemical and 187 logistic workers). The environment in workplace of chemical group was worse than that of contrast. The chemical workers had less control over job and they experienced more hazards, monotonous as well as role stressors than the logistic group. The scores of job satisfaction and mental health of chemical group (36.867 +/- 0.656, 43.734 +/- 0.542, respectively) were higher than that of contrast (40.321 +/- 0.901, 46.714 +/- 0.745, respectively) (P job satisfaction and mental health with different levels.

Strategic Management of People in Organizations of Petrochemical Camaçari – Bahia: Reflections on its Strategies for Attracting, Retaining and Professional Development

Directory of Open Access Journals (Sweden)

Nildes Pitombo Leite

2012-12-01

Full Text Available The investigation object of this research, the primary objectives was to identify and analyze what changes made in people management by the petrochemical organizations, from the trajectory of diversification in the Industrial Complex of Camaçari and their reflections into strategies for attraction, retention and professional development, much in line with the justifications, as with the question asked. The subjects involved were directors, managers and / or coordinators HR, minimum 10 and maximum of 32 years, two respondents per organization, totaling twenty-one organizations. This investigation was answered in each category and gradually increased at the junction of them all. The results show that the changes made in managing people in the petrochemical investigated are not, necessarily, computed from the trajectory of diversification: Petrochemical Pole / Industrial Complex of Camaçari. These results suggest that mergers are among the main responsible. However, there is the record that this change in context was beneficial to these organizations promote the output of the comfort zone that were since deploying Pole. It reinforces the premise that such an investigation ends innovative and contributory aspect for: the area of people management, petrochemical industry and the country.

New technology for producing petrochemical feedstock from heavy oils derived from Alberta oil sands

International Nuclear Information System (INIS)

Oballa, M.; Simanzhenkov, V.; Clark, P.; Laureshen, C.; Plessis du, D.

2006-01-01

This paper presented the results of a study demonstrating the feasibility of producing petrochemical feedstock or petrochemicals from vacuum gas oils derived from oil sands. A typical bitumen upgrader flow scheme was integrated with several new technologies and coupled with an ethane/propane cracker. Technologies included steam cracking, fluid catalytic cracking (FCC); and the catalytic pyrolysis process (CPP). The scheme was then integrated with the Nova Heavy Oil Cracking (NHC) technology. The NHC process uses a reactor to perform catalytic cracking followed by a main tower that separates gas and liquid products. Aromatic ring cleavage (ARORINCLE) technology was explored as a method of catalytic treatment. Experimental runs were conducted in a laboratory scale fixed bed reactor. A stacked catalyst bed was used, followed by a zeolite-based noble metal catalyst. Examples from process run results were presented. Results indicated that the NHC technology should be used on an FCC unit technology platform. The ARORINCLE technology was considered for use on a hydrotreating unit technology platform. Once the catalysts are fully developed and demonstrated, the economics of the technologies will be enhanced through the construction of world-scale complexes integrating upgrading, refining and petrochemical plants. refs., tabs., figs

Heavy gas oils as feedstock for petrochemicals

Energy Technology Data Exchange (ETDEWEB)

Clark, P.D. [Nova Chemicals Ltd., Calgary, AB (Canada); Du Plessis, D. [Alberta Energy Research Inst., Edmonton, AB (Canada)]|[Alberta Economic Development and Trade, Edmonton, AB (Canada)

2004-07-01

This presentation reviewed the possibilities for converting heavy aromatic compounds and gas oils obtained from Alberta bitumen into competitively priced feedstock for high value refined products and petrochemicals. Upgrading bitumen beyond synthetic crude oil to refined products and petrochemicals would add value to bitumen in Alberta by expanding the petrochemical industry by providing a secure market for co-products derived from the integration of bitumen upgrading and refining. This presentation also reviewed conventional feedstocks and processes; by-products from bitumen upgrading and refining; production of light olefins by the fluid catalytic cracking (FCC) and hydrocracking process; deep catalytic cracking, catalytic pyrolysis and PetroFCC processes; technical and economic evaluations; and opportunities and challenges. Conventional feeds for steam cracking were listed along with comparative yields on feedstock. The use of synthetic gas liquids from oil sands plants was also reviewed. Current FCC type processes for paraffinic feedstocks are not suitable for Alberta's bitumen, which require better technologies based on hydrotreating and new ring opening catalysts. tabs., figs.

New deal under negotiation with petrochemical sector

Energy Technology Data Exchange (ETDEWEB)

Anon.

1997-08-04

Development of a strong petrochemicals industry is the cornerstone of Alberta`s economic diversification policy. According to the Vice-President for Business Strategy for Nova Corporation, developments have now reached the critical mass that lure new investments and employment by its sheer scale. A tall hurdle still to clear is to secure the source of raw materials from the natural gas production sector and the Alberta government. Negotiations have been underway over supplies of ethane to be extracted from gas streams for proposed new plants. These negotiations are crucial in testing whether Canadian industry can fulfill its potential. The Alliance Pipeline Project is a key component in settling this complex issue in view of the crucial importance of the proposed pipeline to Chicago for export of gas and liquid by-products, including ethane. Nova has made an offer to Alliance which represents a major change in buying methods. Nova is now ready to recognize ethane as a separate commodity that requires it to be listed with its own selling price. Nova offers prices `on a Gulf Coast-dominated basis` which is generally agreed to yield about the same economic upside to producers as if they actually exported the ethane. Nova hopes for a conclusion of negotiations by year end. Meanwhile the Alberta government also hopes for a settlement, if only to avoid the necessity of rationing ethane between Alberta petrochemical plants and exports.

Preliminary assessment of Miramar Petrochemical Harbor as PAH source to Guajará bay (Belém-PA-Brazil surface sediments

Directory of Open Access Journals (Sweden)

Silvana do Socorro Veloso Sodré

Full Text Available Abstract A preliminary study on a petrochemical harbor as a potential source of polycyclic aromatic hydrocarbons (PAH to surface sediments of Guajará bay, located in Belém City, Pará State, Brazil, over the last 10 years is presented here. The 16 priority USEPA PAH were identified and quantified. Surface sediment samples, collected at 5 sites in the bay, near Miramar Petrochemical Harbor (TEMIR, were extracted and analyzed by high performance liquid chromatography with a diode array detector. Total PAH concentration ranged from 533.0 to 3123.3 ng g-1 dry weight with a mean concentration of 1091.9 ng g-1. The most contaminated places were those where muddy sediments were found with highest concentrations of organic matter. The priority PAH with low molecular weight represented 54.4% of the total abundance and indicate that the main source of contamination of the sediments was petrogenic, indicative of the relevant contribution of the petrochemical harbor activity to the input of PAH to Guajará bay. However, pyrolytic PAH coming from fuel combustion, household waste combustion and untreated sewage discharge are also potential contamination sources to this environment.

Panorama 2012 - Petrochemicals and chemicals from biomass

International Nuclear Information System (INIS)

Alario, Fabio; Castagna, Franck

2011-12-01

Petrochemicals is a mature industry which has undergone, and continues to undergo, deep changes. The historically-important producing areas of the USA, Europe and Japan have seen their share of the market contract in favour of Asia and the Middle East. The investment choices inherent in this shift of emphasis are now beginning to impact significantly on the availability and price of some petrochemical intermediates, and producers increasingly consider basing their production processes on biomass, a renewable and abundant resource. This new channel offers a more favourable greenhouse gas (GHG) balance than the benchmark fossil fuels options. (authors)

Plan of development of the Petrochemical sector

International Nuclear Information System (INIS)

Carta Petrolera

1997-01-01

With the discoveries of gas and petroleum in Cusiana and Piedemonte Llanero, one can speak in Colombia of reactivating the interest for the petrochemical development; theme that during a lot of times was forgotten, because the main interest has been of satisfying the national demand of fuels. Now, when that demand is already supplied, for the surpluses of natural gas, ethane, LPG and natural gasoline, product of the new discoveries, it should be taken advantage of, besides the export, for the development of the petrochemical industry in the country and to produce olefins, aromatic and nitrogenates

Solid Waste Burial Grounds/Central Waste Complex hazards assessment

International Nuclear Information System (INIS)

Broz, R.E.

1994-01-01

This document establishes the technical basis in support of Emergency Planning Activities for Solid Waste Burial Grounds/Central Waste Complex on the Hanford Site. The document represents an acceptable interpretation of the implementing guidance document for DOE Order 5500.3A. Through this document, the technical basis for the development of facility specific Emergency Action Levels and the Emergency Planning Zone is documented

Petrochemical trends and the chemical company in 2010

International Nuclear Information System (INIS)

Finley, A.B.

1992-01-01

Some trends discernible in the petrochemical industry in Quebec and world-wide -- cyclicality, increasing globalization, environmental concerns, and a high degree of integration between olefins and derivative production -- were discussed. On a global basis, the incremental feedstock for ethylene production during the 1990s will likely be naphtha and propane. The challenge for Quebec lies in its distance from low-priced olefin feedstocks and its limited petrochemical infrastructure. In practice that means that despite Quebec's well-educated and productive work force, local producers will not have the feedstock advantage that would translate to low-priced natural gas liquids such as ethane, butane and propane. Against this backdrop what would be the agenda of a world-class petrochemical company in Quebec? This author's prescription called for a clear company vision that would include an appropriate business focus and downstream integration, the development of the required core competencies and strategies, with emphasis on low-cost feedstock acquisition, feedstock flexibility, maximum by-product values, and super-efficient manufacturing. 9 figs

Low-level waste characterization plan for the WSCF Laboratory Complex

International Nuclear Information System (INIS)

Morrison, J.A.

1994-01-01

The Waste Characterization Plan for the Waste Sampling and Characterization Facility (WSCF) complex describes the organization and methodology for characterization of all waste streams that are transferred from the WSCF Laboratory Complex to the Hanford Site 200 Areas Storage and Disposal Facilities. Waste generated at the WSCF complex typically originates from analytical or radiological procedures. Process knowledge is derived from these operations and should be considered an accurate description of WSCF generated waste. Sample contribution is accounted for in the laboratory waste designation process and unused or excess samples are returned to the originator for disposal. The report describes procedures and processes common to all waste streams; individual waste streams; and radionuclide characterization methodology

Accumulation of specific pollutants in various media in the area affected by a petrochemical center

International Nuclear Information System (INIS)

Oprea, C.D.; Mihul, Al.

2002-01-01

The results on monitoring of oil pollution around the town of Ploiesti (South Romania), known for its petrochemical and chemical industry complexes and crude oil activity, are reported. The distribution of heavy metals, rare earth and other microelements along the wind rose profile (the oil complex ∼ 20 km distance) was examined through the analysis of soil samples. Mosses were chosen as biomonitors of local atmospheric pollution with heavy metals and other toxic elements. The trace element content of vegetation growing near the territory of the plant was compared with that of the background one. The contamination of the river flowing in the vicinity of the plant was examined. Comparison of the spatial trends of different pollutants shows the influence of the same atmospheric transport phases on the uptake of trace elements by vegetation. A comparative evaluation of the results was carried out to find to what extent the amount of pollutants in the atmosphere or the amount deposited in the soil or transported by sediments contributes to pollution of the local ecosystem in the vicinity of a petrochemical center. (authors)

Effect of Meteorological Parameters on Accident Rates in Petrochemical Industries

International Nuclear Information System (INIS)

Mansouri, N.; Farsi, E.

2016-01-01

Background and Objective: In this research the effectiveness of weather and climate parameters in incidence of accidents in the petrochemical industry was studied and management strategies to prevent these events have been presented. Method: Two of the petrochemical companies, one of them in Assaluyeh (named Zagros, located in warm climates) and the other one in Tabriz (in cold climates) were selected for pilot study. The required data were collected by questionnaire, interview and walking through under study fields. The analyses of data have been done by Excel, SPSS software and Correlation statistical test. Findings: Climate parameters don’t have a directly impact on the petrochemical occupational accidents and there is no significant relationship between them. Discussion and Conclusion: The role of climatic parameters in the incidence of accidents in the petrochemical industry is indirect. In fact, the thermal stress in the first stage caused unsafe conditions and then unsafe behavior, and finally cause human error and occupational accidents. In this study, appropriate solutions for instance engineering or managerial measures are also suggested in order to prevent accidents and injuries.

Magnox waste storage complex

International Nuclear Information System (INIS)

Anon.

1990-01-01

This article looks at the design and construction of British Nuclear Fuel Limited's (BNFL) Magnox waste storage complex by Costain Engineering Limited. Magnox swarf from fuel decanning is stored underwater in specially designed silos. Gas processing capabilities from Costain Engineering Limited and the experience of BNFL combined in this project to provide the necessary problem-solving skills necessary for this waste storage upgrading and extension project. A retrofitted inerting facility was fitted to an existing building and a new storage extension was fitted, both without interrupting reprocessing operations at Sellafield. (UK)

Chemical and Petrochemical Sector

Energy Technology Data Exchange (ETDEWEB)

NONE

2009-07-01

This publication is a background document on the global chemical and petrochemical sector for the IEA publication Energy Technology Transitions in Industry (IEA, 2009). It provides further, more detailed information on the methodology and data issues for energy efficiency indicators for the sector. The indicators discussed offer insight regarding the energy efficiency improvement potential in the short- to medium-term (by proven technologies).

[Influencing factors for reproductive health of female workers in petrochemical industry].

Science.gov (United States)

Kou, Z X; Wang, S L; Chen, Z L; He, Y H; Yu, W L; Mei, L Y; Zhang, H D

2018-02-20

Objective: To investigate the reproductive health status of female workers in petrochemical industry, and to provide a reference for improving reproductive health status and developing preventive and control measures for female workers in petrochemical industry. Methods: A face-to-face questionnaire survey was performed from January to October, 2016. The Questionnaire on Women's Reproductive Health was used to investigate the reproductive health of female workers in petrochemical industry. The multivariate logistic regression model was used to identify the influencing factors for reproductive health of female workers in petrochemical industry. Results: Among the 7485 female workers, 1 268 (40.9%) had abnormal menstrual period, 1 437 (46.4%) had abnormal menstrual volume, 177 (28.5%) had hyperplasia of mammary glands, and 1 807 (24.6%) had gynecological inflammation. The reproductive system diseases in female workers in petrochemical industry were associated with the factors including age, marital status, education level, unhealthy living habits, abortion, overtime work, work shift, workload, video operation, occupational exposure, positive events, and negative events, and among these factors, negative events (odds ratio[ OR ]= 1.856) , unhealthy living habits ( OR =1.542) , and positive events ( OR =1.516) had greater impact on reproductive system diseases. Conclusion: Many chemical substances in the occupational environment of petrochemical industry can cause damage to the reproductive system, which not only affects the health of the female workers, but also poses potential threats to the health of their offspring. Occupational exposure, unhealthy living habits, overtime work, and work shift have great influence on reproductive system diseases in female workers.

Papers of the 1997 CERI international petrochemical conference : transformation, growth and future direction

International Nuclear Information System (INIS)

1997-06-01

A global overview of the current state of the petrochemical industry, a forecast of future developments, and Alberta's place in the petrochemical industry were the principal themes of this conference. Main topics explored included: (1) global opportunities for petrochemical producers, (2) natural gas and feedstock supplies, (3) chemical industry environment, (4) pipeline implications and transportation systems for the petrochemical industry, (5) partnerships, (6) investment cycles, and (7) forces and future directions for the Canadian industry. The Proceedings volume includes complete text of some of the papers, and speaking notes and copies of overhead slides for others, as submitted by individual speakers. refs., tabs., figs

Operational planning optimization of steam power plants considering equipment failure in petrochemical complex

International Nuclear Information System (INIS)

Luo, Xianglong; Zhang, Bingjian; Chen, Ying; Mo, Songping

2013-01-01

Highlights: ► We develop a systematic programming methodology to address equipment failure. ► We classify different operation conditions into real periods and virtual periods. ► The formulated MILP models guarantee cost reduction and enough operation safety. ► The consideration of reserving operation redundancy is effective. - Abstract: One or more interconnected steam power plants (SPPs) are constructed in a petrochemical complex to supply utility energy to the process. To avoid large economic penalties or process shutdowns, these SPPs should be flexible and reliable enough to meet the process energy requirement under varying conditions. Unexpected utility equipment failure is inevitable and difficult to be predicted. Most of the conventional methods are based on the assumption that SPPs do not experience any kind of equipment failure. Unfortunately, a process shutdown cannot be avoided when equipment fails unexpectedly. In this paper, a systematic methodology is presented to minimize the total cost under normal conditions while reserving enough flexibility and safety for unexpected equipment failure conditions. The proposed method transforms the different conditions into real periods to indicate normal scenarios and virtual periods to indicate unexpected equipment failure scenarios. The optimization strategy incorporating various operation redundancy scheduling, the transition constraints from equipment failure conditions to normal conditions, and the boiler load increase behavior modeling are presented to save cost and guarantee operation safety. A detailed industrial case study shows that the proposed systematic methodology is effective and practical in coping with equipment failure conditions with only few additional cost penalties

The use of plasticizing additives based on recycled raw materials in the petrochemical rubber mixtures

Directory of Open Access Journals (Sweden)

Z. S. Shashok

2016-01-01

Full Text Available At present, the development of alternative products for elastomers based on recycling petrochemical raw materials is a new trend of the rubber industry progress. Petrochemical raw materials include spent lubricants and motor oils are among such recycling products. In this context, the influence of the products of recycling waste engine oil (DVCH and RA in comparison with industrial oil (I-20 on the technological properties of filled elastomeric compositions was investigated. The elastomeric compositions were based on poly isoprene and divinyl rubbers. The plasticizing components were manufactured by IOOO “DVCH-Menedzhment”. They are mixture of hydro-carbons, C16–C20 and differ from each other in the content of linear and branched paraffin. Plastic-elastic properties of rubber compounds on the shear disk viscometer MV2000 in accordance with GOST 10722–76 was carried out. Kinetics of vulcanization on the rheometer ODR2000 according to GOST 12535–84 was defined. It is shown that the introduction of RA test plasticizing component provides a significant effect on Mooney viscosity, as compared to elastomeric compositions containing a plasticizer and I-20 and plasticizing additive DVCH. It revealed that the administration of all components in the studied plasticizing elastomer compositions based on a combination poly isoprene and divinyl rubbers has no significant effect on the rate of relaxation of stress of rubber compounds. It is found that elastomeric compositions containing as additives investigated processing waste oil products (DVCH and RA are characterized by a slightly smaller value of time to reach an optimal degree of vulcanization.

Environmental assessment: Solid waste retrieval complex, enhanced radioactive and mixed waste storage facility, infrastructure upgrades, and central waste support complex, Hanford Site, Richland, Washington

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-09-01

The U.S. Department of Energy (DOE) needs to take action to: retrieve transuranic (TRU) waste because interim storage waste containers have exceeded their 20-year design life and could fail causing a radioactive release to the environment provide storage capacity for retrieved and newly generated TRU, Greater-than-Category 3 (GTC3), and mixed waste before treatment and/or shipment to the Waste Isolation Pilot Project (WIPP); and upgrade the infrastructure network in the 200 West Area to enhance operational efficiencies and reduce the cost of operating the Solid Waste Operations Complex. This proposed action would initiate the retrieval activities (Retrieval) from Trench 4C-T04 in the 200 West Area including the construction of support facilities necessary to carry out the retrieval operations. In addition, the proposed action includes the construction and operation of a facility (Enhanced Radioactive Mixed Waste Storage Facility) in the 200 West Area to store newly generated and the retrieved waste while it awaits shipment to a final disposal site. Also, Infrastructure Upgrades and a Central Waste Support Complex are necessary to support the Hanford Site`s centralized waste management area in the 200 West Area. The proposed action also includes mitigation for the loss of priority shrub-steppe habitat resulting from construction. The estimated total cost of the proposed action is $66 million.

Environmental assessment: Solid waste retrieval complex, enhanced radioactive and mixed waste storage facility, infrastructure upgrades, and central waste support complex, Hanford Site, Richland, Washington

International Nuclear Information System (INIS)

1995-09-01

The U.S. Department of Energy (DOE) needs to take action to: retrieve transuranic (TRU) waste because interim storage waste containers have exceeded their 20-year design life and could fail causing a radioactive release to the environment provide storage capacity for retrieved and newly generated TRU, Greater-than-Category 3 (GTC3), and mixed waste before treatment and/or shipment to the Waste Isolation Pilot Project (WIPP); and upgrade the infrastructure network in the 200 West Area to enhance operational efficiencies and reduce the cost of operating the Solid Waste Operations Complex. This proposed action would initiate the retrieval activities (Retrieval) from Trench 4C-T04 in the 200 West Area including the construction of support facilities necessary to carry out the retrieval operations. In addition, the proposed action includes the construction and operation of a facility (Enhanced Radioactive Mixed Waste Storage Facility) in the 200 West Area to store newly generated and the retrieved waste while it awaits shipment to a final disposal site. Also, Infrastructure Upgrades and a Central Waste Support Complex are necessary to support the Hanford Site's centralized waste management area in the 200 West Area. The proposed action also includes mitigation for the loss of priority shrub-steppe habitat resulting from construction. The estimated total cost of the proposed action is $66 million

Refining and petrochemicals

International Nuclear Information System (INIS)

Benazzi, E.

2003-01-01

Down sharply in 2002, refining margins showed a clear improvement in the first half-year of 2003. As a result, the earnings reported by oil companies for financial year 2002 were significantly lower than in 2001, but the prospects are brighter for 2003. In the petrochemicals sector, slow demand and higher feedstock prices eroded margins in 2002, especially in Europe and the United States. The financial results for the first part of 2003 seem to indicate that sector profitability will not improve before 2004. (author)

Catalysts in petroleum refining and petrochemical industries 1995

Energy Technology Data Exchange (ETDEWEB)

Absi-Halabi, M.; Beshara, J.; Qabazard, H.; Stanislaus, A. [eds.] [Petroleum, Petrochemicals and Materials Division, Kuwait Institute of Scientific Research, Kuwait (Kuwait)

1996-07-01

Catalysis plays an increasingly critical role in modern petroleum refining and basic petrochemical industries. The market demands for and specifications of petroleum and petrochemical products are continuously changing. They have impacted the industry significantly over the past twenty years. Numerous new refining processes have been developed and significant improvements were made on existing technologies. Catalysts have been instrumental in enabling the industry to meet the continuous challenges posed by the market. As we enter the 21st century, new challenges for catalysis science and technology are anticipated in almost every field. Particularly, better utilization of petroleum resources and demands for cleaner transportation fuels are major items on the agenda. It is against this background that the 2nd International Conference on Catalysts in Petroleum Refining and Petrochemical Industries was organized. The papers from the conference were carefully selected from around 100 submissions. They were a mix of reviews providing an overview of selected areas, original fundamental research results, and industrial experiences. The papers in the proceedings were grouped in the following sections for quick reference: Plenary Papers; Hydroprocessing of Petroleum Residues and Distillates; Fluid Catalytic Cracking; Oxidation Catalysis; Aromatization and Polymerization Catalysis; Catalyst Characterization and Performance. The plenary papers were mostly reviews covering important topics related to the objectives of the conference. The remaining sections cover various topics of major impact on modern petroleum refining and petrochemical industries. A large number of papers dealt with hydroprocessing of petroleum distillates and residues which reflects the concern over meeting future sulfur-level specifications for diesel and fuel oils

Ethylbenzene-induced hearing loss, neurobehavioral function, and neurotransmitter alterations in petrochemical workers.

Science.gov (United States)

Zhang, Ming; Wang, Yanrang; Wang, Qian; Yang, Deyi; Zhang, Jingshu; Wang, Fengshan; Gu, Qing

2013-09-01

To estimate hearing loss, neurobehavioral function, and neurotransmitter alteration induced by ethylbenzene in petrochemical workers. From two petrochemical plants, 246 and 307 workers exposed to both ethylbenzene and noise were recruited-290 workers exposed to noise only from a power station plant and 327 office personnel as control group, respectively. Hearing and neurobehavioral functions were evaluated. Serum neurotransmitters were also determined. The prevalence of hearing loss was much higher in petrochemical groups than that in power station and control groups (P workers (P hearing loss, neurobehavioral function impairment, and imbalance of neurotransmitters.

Structure Optimization of Safety Investment of Petrochemical Port Enterprises

Directory of Open Access Journals (Sweden)

Zhiqiang Hou

2017-01-01

Full Text Available Safety investment is an essential guarantee to identify and manage potential security problems in petrochemical port enterprises. The reasonability of safety investment structure determines overall security risks in an enterprise. Based on the definition of risks, combining Cobb-Douglas production function with FTA probability model, and taking Gompertz curve model as the constraint condition, structure optimization model of safety investment is built in order to minimize risks and work out the safety investment structure of petrochemical port enterprises. According to the case study, the calculations indicate that safety investment in corporate management presents a larger growth rate than past years and that unsafe act of human being is the main factor accounting for the greatest probability of occurrence, which is consistent with previous accident investigation results as well as enterprise reality. This testifies that the model is effective and that the results can guide the allocation of safety investment of petrochemical port enterprises scientifically.

Latin America second only to Asia in petrochemical prospects

International Nuclear Information System (INIS)

Krenek, M.R.

1995-01-01

The opportunity in Asia for petrochemical companies generally is well known among global players in the industry. Conventional wisdom dictates that most companies at least consider investing in Asia, and for good reason, in most cases. The more aggressive, growth-oriented companies, however, already are attempting to discover the ''next Asia,'' if there is such a thing. Latin America has been nominated as one of the less developed regions that might inherit the Asia/Pacific region's enviable position. This nomination, however, was made before the Mexican financial crisis and the burgeoning pressure on the currencies of Brazil and Argentina. In light of current events, can Latin America still be considered the next Asia, and, if so, what opportunities will follow the devaluation of the Mexican peso? An analysis of the economic and political factors affecting the petrochemical industry in Latin America indicates that the region still hold excellent prospects for petrochemical companies

Obtaining petrochemical products from ethanol; Obtencao de produtos petroquimicos a partir do etanol

Energy Technology Data Exchange (ETDEWEB)

Silverio, Carlos Augusto N.; Oliveira, Claudia Vasconcellos R. de; Joao, Rafael Richard; Hashizume, Tulio Kenji C. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

2008-07-01

Currently, high oil prices, low availability of traditional raw material (natural gas and petrochemical naphtha), increasing recognition of the importance of the preservation of nature and reducing emissions of pollutants have been creating a great opportunity for the petrochemical industry to seek alternative materials from renewable resources. The ethanol, which obtained a virtuous journey as fuel, is a very promising alternative to be used for the production of petrochemical products. However, the use of ethanol as a raw material will require a considerable increase in its production, what can be achieved through the development of new production technologies based on biomass and the construction of integrated biorefineries. So, this study aims to identify and compare conventional petrochemical routes with routes from this renewable raw material in order to evaluate their technical and economic feasibility. A preliminary analysis was performed between four petrochemical products: acetic acid, acetaldehyde, the ethyl acetate and ethylene. From this initial analysis, acetic acid and ethylene were selected for a more comprehensive feasibility study considering their production using ethanol as raw material, what is called ethanol chemistry. (author)

Panorama 2007: Refining and Petrochemicals

International Nuclear Information System (INIS)

Silva, C.

2007-01-01

The year 2005 saw a new improvement in refining margins that continued during the first three quarters of 2006. The restoration of margins in the last three years has allowed the refining sector to regain its profitability. In this context, the oil companies reported earnings for fiscal year 2005 that were up significantly compared to 2004, and the figures for the first half-year 2006 confirm this trend. Despite this favorable business environment, investments only saw a minimal increase in 2005 and the improvement expected for 2006 should remain fairly limited. Looking to 2010-2015, it would appear that the planned investment projects with the highest probability of reaching completion will be barely adequate to cover the increase in demand. Refining sector should continue to find itself under pressure. As for petrochemicals, despite a steady up-trend in the naphtha price, the restoration of margins consolidated a comeback that started in 2005. All in all, capital expenditure remained fairly low in both the refining and petrochemicals sectors, but many projects are planned for the next ten years. (author)

Maturity In The Petrochemical Industry Features, Motives And Combating

International Nuclear Information System (INIS)

Farag, H.; El Messirie, A.

2004-01-01

Petrochemicals give the highest value from crude oil and natural gas but suffers from maturity like any other business. Petrochemicals companies are promoting their business in the direction from oil and gas commodities. Specialities and life science. Reasons of maturity are expired patents, low demand, over capacity, intense competition. Actions to combat maturity are to restructure capacity achieving mega sizes, do downstream, and restructuring business practices. Strategies followed by some companies to combat maturity include exit, focus on core business and exploit a competitive advantage

The on-going search for new technology in the petrochemical industry

Energy Technology Data Exchange (ETDEWEB)

Granson, E.

2005-09-30

This paper outlined some of the technological advancements taking place in the petrochemical sector in Western Canada, where some of the world's largest processing plants are located. It described the impact of the petroleum industry on daily life, with reference to the research and development that has taken place since the opening of the first refinery in Bulgaria in 1861, followed by the development of electricity and the internal combustion engine. Although each discovery created a new market for gasoline, distillation techniques could not keep up with demand. Thermal cracking, catalytic cracking and polymerization processes were then devised to improve production. In the 1940s, alkylation produced a higher octane gasoline and also petrochemical feedstocks which eventually led to the large-scale production of hydrocarbon molecules known as alkenes or olefins. These, along with aromatics and methane, are the foundation of the petrochemical industry. Facilities in central Alberta have been a major component of Canada's petrochemical industry for decades, producing products such as formaldehyde, acetic acid, anhydride, solvents, ammonium nitrate, styrofoam, ethylene glycol, vinyl chloride, polyvinyl, vinyl acetate, and styrene. This paper described an innovative technology developed by Edmonton-based Quantiam Technologies Inc. to improve the efficiency of manufacturing olefins, a petrochemical derivative of natural gas and oil. Olefins are widely used to produce plastics and solvents, including ethylene. This paper described the process that turns natural gas into feedstock at the Empress 2 Straddle Plant located near TransCanada's pipeline and the Foothills pipeline system. Details of the thermal cracking process were also presented with reference to catalysts that are specific to the process. Sustainable Development Technology Canada (SDTC) contributed $1.45 million to Quantiam and its partner NOVA Chemicals Corp. to construct a pilot plant that

Fracture mechanics based life assessment in petrochemical plants

International Nuclear Information System (INIS)

Norasiah Ab Kasim; Abd Nassir Ibrahim; Ab Razak Hamzah; Shukri Mohd

2004-01-01

The increasing use of thick walled pressure vessels in petrochemical plants operating at high pressure under severe service conditions could lead to catastrophic failure. In the Malaysian Institute for Nuclear Technology Research (MINT), initial efforts are underway to apply fracture mechanics approach for assessment of significance of defects detected during periodic in service inspection (ISI) of industrial plants. This paper outlines the integrity management strategy based on fracture mechanics and proposes a new procedure for life assessment of petrochemical plants based on ASME Boiler and Pressure Vessel Code, Section XI, BSI PD 6493:1991, BSI 6539:1994, BSI Standard 7910:1999 and API 579:2000. Essential relevant data required for the assessment is listed. Several methods available for determination of fracture toughness are reviewed with limitations in their application to petrochemical plants. A new non destructive method for determination of fracture toughness based on hardness testing and normalized key roughness curve is given. Results of fracture mechanics based life assessment conducted for 100 mm thick ammonia converter of Ni r o steel and 70 mm thick plat forming reactor vessel of ASTM A 38 7 grade B steel in operational fertilizer and petroleum refining plants are presented. (Author)

Corrosion problems and solutions in oil refining and petrochemical industry

CERN Document Server

Groysman, Alec

2017-01-01

This book addresses corrosion problems and their solutions at facilities in the oil refining and petrochemical industry, including cooling water and boiler feed water units. Further, it describes and analyzes corrosion control actions, corrosion monitoring, and corrosion management. Corrosion problems are a perennial issue in the oil refining and petrochemical industry, as they lead to a deterioration of the functional properties of metallic equipment and harm the environment – both of which need to be protected for the sake of current and future generations. Accordingly, this book examines and analyzes typical and atypical corrosion failure cases and their prevention at refineries and petrochemical facilities, including problems with: pipelines, tanks, furnaces, distillation columns, absorbers, heat exchangers, and pumps. In addition, it describes naphthenic acid corrosion, stress corrosion cracking, hydrogen damages, sulfidic corrosion, microbiologically induced corrosion, erosion-corrosion, and corrosion...

Fiscal 1999 basic survey report for promotion of joint implementation. Energy saving at petrochemical plant; 1999 nendo sekiyu kagaku kojo no sho energy chosa hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

A survey is conducted of energy-saving and greenhouse gas reducing measures in cooperation with the National Petrochemical Public Company Limited (NPC), Thailand. The NPC is the first petrochemical producer in that country and, after 10 years' operation, the largest such producer there. Transfer of energy-saving technologies from Japan will lead to the construction of clean development mechanism (CDM) in the future. The NPC plant surveyed is situated in a Maptaphut industrial complex, and produces ethylene propylene from natural gas and at the same time serves as a utility center to supply electricity and steam to factories and plants in the vicinity. Items examined involve waste heat power generation, power generating gas turbine efficiency improvement, ethylene plant cracking furnace heat retaining capability enhancement, steam pipe heat retaining material renewal, and replacement of obsolete air conditioners with higher-efficiency equipment. After tentative calculation a conclusion is reached that the total of energy-saving effects of the said five items will be 21,900 tons/year in terms of crude oil and that a CO2 reduction will be feasible at a rate of 45,300 tons/year. These figures are larger than the ones predicted before the survey. A total of 354.3 million bahts will have to be invested. Negotiations will continue with attention directed to the progress of NPC's preparedness to accept CDM. (NEDO)

Thanks to shale gas, the rebirth of the petrochemical industry in the USA

International Nuclear Information System (INIS)

Cornot-Gandolphe, Sylvie

2014-01-01

America's competitive advantage is a strong incentive for petrochemical companies to invest in the USA. Petrochemicals are thus one of the high energy intensity sectors to benefit the most from the shale gas revolution. (author)

Asia's new power : opportunities for Canadian petrochemicals

International Nuclear Information System (INIS)

Swanson, A.B.

2004-01-01

The structure and outlook of the Asian economy was discussed. In 2004, Japan had the largest share of the Asian gross domestic product (GDP) at 50.5 per cent followed by China at 15.7 per cent. Nexant forecasts that Asian growth will average 5 to 6 per cent inclusive of Japan's mature economy. The presentation included a graph comparing GDP on a purchasing power parity basis and exchange rate basis. It was noted that although China's strong growth is due in part to a stable currency fixed to the US$, there are some underlying concerns regarding efficiency improvements in state owned enterprises, non performing loans, and a lack of transparency in growth statistics and inflation. With consumers driving demand, China is the world's largest importer of petrochemicals and polymers, but the purchasing pattern is erratic. This presentation listed some of the major changes under the World Trade Organization (WTO) and illustrated the important role that trades play in importing polymers. It is expected that imported polymers and petrochemicals may be sold directly to end-users. A graph depicting delivered costs of monoethylene glycol (MEG), excluding tariffs, port charges and internal logistics, indicates that the Middle East is favoured. The implications for Canadian petrochemicals was discussed, given that China is Canada's prime MEG export market. tabs., figs

Idaho CERCLA Disposal Facility Complex Waste Acceptance Criteria

Energy Technology Data Exchange (ETDEWEB)

W. Mahlon Heileson

2006-10-01

The Idaho Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Disposal Facility (ICDF) has been designed to accept CERCLA waste generated within the Idaho National Laboratory. Hazardous, mixed, low-level, and Toxic Substance Control Act waste will be accepted for disposal at the ICDF. The purpose of this document is to provide criteria for the quantities of radioactive and/or hazardous constituents allowable in waste streams designated for disposal at ICDF. This ICDF Complex Waste Acceptance Criteria is divided into four section: (1) ICDF Complex; (2) Landfill; (3) Evaporation Pond: and (4) Staging, Storage, Sizing, and Treatment Facility (SSSTF). The ICDF Complex section contains the compliance details, which are the same for all areas of the ICDF. Corresponding sections contain details specific to the landfill, evaporation pond, and the SSSTF. This document specifies chemical and radiological constituent acceptance criteria for waste that will be disposed of at ICDF. Compliance with the requirements of this document ensures protection of human health and the environment, including the Snake River Plain Aquifer. Waste placed in the ICDF landfill and evaporation pond must not cause groundwater in the Snake River Plain Aquifer to exceed maximum contaminant levels, a hazard index of 1, or 10-4 cumulative risk levels. The defined waste acceptance criteria concentrations are compared to the design inventory concentrations. The purpose of this comparison is to show that there is an acceptable uncertainty margin based on the actual constituent concentrations anticipated for disposal at the ICDF. Implementation of this Waste Acceptance Criteria document will ensure compliance with the Final Report of Decision for the Idaho Nuclear Technology and Engineering Center, Operable Unit 3-13. For waste to be received, it must meet the waste acceptance criteria for the specific disposal/treatment unit (on-Site or off-Site) for which it is destined.

Toxicological evaluation of complex industrial wastes: Implications for exposure assessment

Energy Technology Data Exchange (ETDEWEB)

DeMarini, D.M.; Gallagher, J.E.; Houk, V.S.; Simmons, J.E.

1990-07-01

We evaluated a variety of short-term bioassays to construct a battery of tests that could be used for assessing the biological effects of potentially hazardous complex industrial wastes. Ten samples were studied for hepatotoxicity; these samples and an additional five were studied for mutagenicity. Although the data are limited to these samples, the results suggest that the Salmonella assay (strain TA98) or a prophage-induction assay (both in the presence of S9) in combination with determination of relative liver weight and levels of a set of serum enzymes in rats may provide a battery of tests suitable to characterize complex industrial wastes for mutagenic and hepatotoxic potential. The biological activities exhibited by the wastes were not readily predicted by the chemical profiles of the wastes, emphasizing the importance of characterizing potentially hazardous complex industrial wastes by both chemical and biological means. DNA from liver, lung, and bladder of rats exposed to some of the wastes was analyzed by the 32P-postlabeling technique for the presence of DNA adducts. A waste that produced mutagenic urine produced a DNA adduct in bladder DNA. The implications of this approach for assessment of exposure to complex hazardous waste mixtures are discussed.

The state of the petrochemical industry and how the midstream market is impacted

International Nuclear Information System (INIS)

Howard, G.

2004-01-01

The petrochemical industry is Canada's third largest manufacturing sector, exporting almost 2 thirds of production. Alberta's petrochemical advantage was outlined in this presentation. Alberta's abundant natural resources and progressive business climate have contributed to the growing interest of investors. Other advantages include proximity to natural gas resources; secure supplies of natural gas and gas liquids; and favourable government policies. It was suggested that the petrochemical industry took root in Alberta because of a distinct natural gas feedstock price advantage. However, high natural gas feedstock prices have brought the industry to a crossroads. Petrochemicals consume over half of Alberta's industrial gas use, and 75 per cent of the operating expenditures in petrochemical plants are tied up in feedstock costs. It was noted that Middle East gas is priced at one fifth of North American gas, and that volatility and maturing gas basins affect supply and increase cost. Excess natural gas pipeline capacity has tightened basis differentials. Nearly half of liquefied natural gas (LNG) terminals are strategically placed along the U.S. Gulf coast. Transportation costs and the distance of haul inequities were discussed. It was noted that the sales volume of basic chemicals and plastics fell by 2 per cent in 2003. However, chemical export revenues rose 12 per cent in 2004. Details of World and North American ethylene demand, capacity and operating rates were provided, as well as cash costs and regional averages in 2004. Various downstream integration opportunities include the use of hydrogen in refinery integration; capturing carbon dioxide rich sources for enhanced oil recovery; capitalizing on the potential for propylene derivative plants; crude butadiene; and pyrolysis gasoline. It was concluded that a sustained global recovery in the petrochemical industry must reflect a change in business strategy. Although the Alberta petrochemical industry is still at

Global petrochemical industry experiencing cyclic downturn

International Nuclear Information System (INIS)

Anon.

1993-01-01

The current deterioration of the petrochemical industry-particularly in the U.S. and Western Europe-is a cause of great concern to operators and analysts alike. Although the rapidly developing Asian market will continue to be a major factor into the next century, the immediate global outlook is for a weak market. Chem Systems Inc., Tarrytown, N.Y., discussed these issues at its annual petrochemical conference, held Jan. 13-14 in Houston. One of the few optimistic predictions of the meetings gas that the harbingers of the next industry cycle already can be seen in the U.S. economic recovery, and slow-down in new project planning, and a reduction in fixed costs. The paper describes the US market; market structure; the trend toward capacity integration; product forecasts; factors affecting the prices of propylene, aromatics, and benzene; the Asian market (Japan, Korea, Taiwan, China, Asian countries); regional trade; and the European market

Asthma, respiratory symptoms and lung function in children living near a petrochemical site.

NARCIS (Netherlands)

Rovira, E.; Cuadras, A.; Aguilar, X.; Esteban, L.; Borràs-Santos, A.; Zock, J.P.; Sunyer, J.

2014-01-01

Residential proximity to environmental hazards has been related to adverse health outcomes. Respiratory health and allergies in children living near petrochemical sites have not been extensively studied. We evaluated the association between residential proximity to the petrochemical site of

Meteorologically estimated exposure but not distance predicts asthma symptoms in schoolchildren in the environs of a petrochemical refinery: a cross-sectional study

CSIR Research Space (South Africa)

White, N

2009-09-01

Full Text Available Community concern about asthma prompted an epidemiological study of children living near a petrochemical refinery in Cape Town, South Africa. Because of resource constraints and the complexity of refinery emissions, neither direct environmental...

Process heat applications of HTR-PM600 in Chinese petrochemical industry: Preliminary study of adaptability and economy

International Nuclear Information System (INIS)

Fang, Chao; Min, Qi; Yang, Yanran; Sun, Yuliang

2017-01-01

Highlights: •High Temperature Gas Cooled Reactor (HTGR) could work as heat source for petrochemical industry. •The joint of a 600 MW modular HTGR (HTR-PM600) and petrochemical industry is achievable. •The mature technology of turbine in thermal power station could be readily adopted. •The economy of this scheme is also acceptable. -- Abstract: High Temperature Gas Cooled Reactor (HTGR) could work as heat source for petrochemical industry. In this article, the preliminary feasibility of a 600 MW modular HTGR (HTR-PM600) working as heat source for a typical hypothetical Chinese petrochemical factory is discussed and it is found that the joint of HTR-PM600 and petrochemical industry is achievable. In detail, the heat and water balance analysis of the petrochemical factory is given. Furthermore, the direct cost of heat supplied by HTR-PM600 is calculated and corresponding economy is estimated. The results show that though there are several challenges, the application of process heat of HTGR to petrochemical industry is practical in sense of both technology and economy.

The petrochemical production capacity of the Saudi Arabian Basic Industry Corporation (SABIC)

International Nuclear Information System (INIS)

Anon.

1993-01-01

This paper describes the development program of the SABIC (Saudi Arabian Basic Industry Co.) which has provided the building of new petrochemical units while retrofitting old units or developing the capacities of some of them. Statistical data on petrochemical production, sales and exports, contracts and joint ventures are also given. 2 tabs

Safety and health in the petrochemical industry in Map Ta Phut, Thailand.

Science.gov (United States)

Langkulsen, Uma; Vichit-Vadakan, Nuntavarn; Taptagaporn, Sasitorn

2011-01-01

Petrochemical industries are known as sources of many toxic chemicals. Safety and health risks of the petrochemical workers employed at Map Ta Phut Industrial Estate, located in Rayong, Thailand, are potentially high. The research materials consisted of documents emanating from statutory reports on safety in working with toxic chemicals and the results of interviews by questionnaire among 457 petrochemical workers regarding occupational health and safety issues. Most of workers who were working with toxic chemicals had knowledge and awareness of health risks and chemical hazards at work. We found that safe behavior at work through read the safety information among operational workers less than non-operational workers around 10%. Most of workers had perceived occupational health and safety management in their companies. Some companies revealed that they had not been performing biological monitoring of blood or urine for their health examination reports and that workplace exposure monitoring had not correlated well with health examination of workers. Our study suggested that occupational health and safety for petrochemical industries requires standards and guidelines for workers' health surveillance aimed at protection of workers.

Biomonitoring of genotoxicity using micronuclei assay in native population of Astyanax jacuhiensis (Characiformes: Characidae) at sites under petrochemical influence

Energy Technology Data Exchange (ETDEWEB)

Torres de Lemos, Clarice [Divisao de Biologia, Programa de Pesquisas Ambientais, Departamento de Laboratorios, Fundacao Estadual de Protecao Ambiental Henrique Luis Roessler (FEPAM), Avenida Dr. Salvador Franca, 1707, 90690-000, Porto Alegre, RS (Brazil)], E-mail: claricetl@fepam.rs.gov.br; Almeida Iranco, Fabio de; D' Avila de Oliveira, Nanci Cristina; Dornelles de Souza, Getulio [Divisao de Biologia, Programa de Pesquisas Ambientais, Departamento de Laboratorios, Fundacao Estadual de Protecao Ambiental Henrique Luis Roessler (FEPAM), Avenida Dr. Salvador Franca, 1707, 90690-000, Porto Alegre, RS (Brazil); Guimaraes Fachel, Jandyra Maria [Instituto de Matematica, Departamento de Estatistica, Universidade Federal do Rio Grande do Sul. Av. Bento Goncalves, 9500, 91509-9000, Porto Alegre, RS (Brazil)

2008-11-15

Bom Jardim brook is a small stream that flows through an area under the influence of a Petrochemical Complex, demanding control over its quality, so a genotoxic evaluation was performed. This study was conducted in situ, based on previous analysis on the same subject. These were performed both in vitro, with Salmonella typhimurium and human lymphocytes, and in vivo, using bioassays with fish exposed to water from the study area. The purpose of this research was to assess the quality of the aquatic environment and possible effects from petrochemical pollution to surrounding native populations. Micronuclei (MNE) and nuclear abnormalities (NA) frequencies in peripheral blood of Astyanax jacuhiensis, a native fish species collected from the study area, were used as biomarkers. Study period was from summer/99 to spring/2001, using samples obtained seasonally at two ponds upstream from the industrial area (BJN and BJPa) and two sites in Bom Jardim brook (BJ002 and BJ000), which are subject to Complex influence. MNE and NA frequencies found in individuals from BJ002 and BJ000 were similar, showing positive genotoxic responses related to control sites BJN and BJPa. No differential sensitivity could be verified for micronuclei induction between genders of A. jacuhiensis in the studied population. This study showed that sites subject to petrochemical influence were under higher genotoxic impact. Biomarkers adequacy to the case and the sensitivity of A. jacuhiensis for water monitoring could be also inferred.

Biomonitoring of genotoxicity using micronuclei assay in native population of Astyanax jacuhiensis (Characiformes: Characidae) at sites under petrochemical influence

International Nuclear Information System (INIS)

Torres de Lemos, Clarice; Almeida Iranco, Fabio de; D'Avila de Oliveira, Nanci Cristina; Dornelles de Souza, Getulio; Guimaraes Fachel, Jandyra Maria

2008-01-01

Bom Jardim brook is a small stream that flows through an area under the influence of a Petrochemical Complex, demanding control over its quality, so a genotoxic evaluation was performed. This study was conducted in situ, based on previous analysis on the same subject. These were performed both in vitro, with Salmonella typhimurium and human lymphocytes, and in vivo, using bioassays with fish exposed to water from the study area. The purpose of this research was to assess the quality of the aquatic environment and possible effects from petrochemical pollution to surrounding native populations. Micronuclei (MNE) and nuclear abnormalities (NA) frequencies in peripheral blood of Astyanax jacuhiensis, a native fish species collected from the study area, were used as biomarkers. Study period was from summer/99 to spring/2001, using samples obtained seasonally at two ponds upstream from the industrial area (BJN and BJPa) and two sites in Bom Jardim brook (BJ002 and BJ000), which are subject to Complex influence. MNE and NA frequencies found in individuals from BJ002 and BJ000 were similar, showing positive genotoxic responses related to control sites BJN and BJPa. No differential sensitivity could be verified for micronuclei induction between genders of A. jacuhiensis in the studied population. This study showed that sites subject to petrochemical influence were under higher genotoxic impact. Biomarkers adequacy to the case and the sensitivity of A. jacuhiensis for water monitoring could be also inferred

Petrochemicals from oil, natural gas, Ccoal and biomass: energy use, economics and innovation

NARCIS (Netherlands)

Ren, T.

2009-01-01

The petrochemical industry is faced with the dual challenges of climate change and the security of energy supply. To deal with these challenges, it is necessary to identify technologies for the production of basic petrochemicals that could potentially improve energy efficiency and/or utilizing

Remarks to the Canadian Energy Research Institute at the first international petrochemical conference

International Nuclear Information System (INIS)

West, S.C.

1997-01-01

In his opening address, the Alberta Minister of Energy outlined the role of the Alberta government in the development of the petrochemical industry in that province. A large portion of Alberta's petrochemical production is based on ethane extracted from natural gas. Several world class petrochemical plant expansions are planned for the near future in an effort to maximize the economic benefits from gas production. The goal of the Alberta government is to maximize the economic benefits from gas production and value added gas liquids upgrading within the province to benefit all Albertans. At the same time, gas producers want to sell their product at full market value, while Alberta's petrochemical industry is interested in securing an adequate supply of ethane to allow the industry to expand to its full potential in a global marketplace. According to the Minister, these goals will be best achieved through cooperation between the government, regulatory authorities, gas producers, petrochemical producers and pipeline companies. Simplification of the royalty regime, pipeline tolling issues, the jurisdictional issues yet to be resolved with the federal government regarding ways to respond to climate change challenge, and natural gas/electricity convergence were some of the other issues addressed by the Minister

B Plant complex hazardous, mixed and low level waste certification plan

International Nuclear Information System (INIS)

Beam, T.G.

1994-11-01

This plan describes the administrative steps and handling methodology for certification of hazardous waste, mixed waste, and low level waste generated at B Plant Complex. The plan also provides the applicable elements of waste reduction and pollution prevention, including up front minimization and end product reduction of volume and/or toxicity. The plan is written to satisfy requirements for Hanford Site waste generators to have a waste certification program in place at their facility. This plan, as described, applies only to waste which is generated at, or is the responsibility of, B Plant Complex. The scope of this plan is derived from the requirements found in WHC-EP-0063, Hanford Site Solid Waste Acceptance Criteria

B Plant complex hazardous, mixed and low level waste certification plan

Energy Technology Data Exchange (ETDEWEB)

Beam, T.G.

1994-11-01

This plan describes the administrative steps and handling methodology for certification of hazardous waste, mixed waste, and low level waste generated at B Plant Complex. The plan also provides the applicable elements of waste reduction and pollution prevention, including up front minimization and end product reduction of volume and/or toxicity. The plan is written to satisfy requirements for Hanford Site waste generators to have a waste certification program in place at their facility. This plan, as described, applies only to waste which is generated at, or is the responsibility of, B Plant Complex. The scope of this plan is derived from the requirements found in WHC-EP-0063, Hanford Site Solid Waste Acceptance Criteria.

Toxicological evaluation of complex industrial wastes: Implications for exposure assessment

Energy Technology Data Exchange (ETDEWEB)

DeMarini, D.M.; Gallagher, J.E.; Houk, V.S.; Simmons, J.E.

1989-01-01

A variety of short-term bioassays to construct a battery of tests that could be used for assessing the biological effects of potentially hazardous complex industrial wastes were evaluated. Ten samples were studied for hepatotoxicity: These samples and an additional five were studied for mutagenicity. Although the data are limited to these samples, the results suggest that the Salmonella assay (either TA98 or TA100) or a prophage-induction assay (both in the presence of S9) in combination with determination of relative liver weight and levels of a set of serum enzymes in rats would provide a battery of tests suitable to characterize complex industrial wastes for mutagenic and hepatotoxic potential. The biological activities exhibited by the wastes were not readily predicted by the chemical profiles of the wastes, emphasizing the importance of characterizing potentially hazardous complex industrial wastes by both chemical and biological means.

The petrochemical industry in Quebec : from yesterday to today

International Nuclear Information System (INIS)

Giard, P.

1992-01-01

A historical account of the development of the chemical industry in Quebec from the year 1800 to the present was presented. The emphasis was on the development of the petrochemical industry after 1945. The earliest signs of chemical manufacturing in Quebec appeared in 1800 with the opening of the Wadsworth and Lyman pharmaceutical laboratories followed by several manufacturers of soap, paint, sugar, rubber, cement and explosive products. In 1900 the acetylene-based carbon chemistry industry was established in the Shawinigan region. The petrochemical industry in Quebec was born in 1952 with the opening in Montreal of a cumene and phenol plant by Shawinigan Chemicals and British American Oil, peaking in 1976 with six producing refineries in east Montreal. At that time, Montreal represented the largest refining centre in Canada with a combined capacity of 600,000 barrels per year. Since then, four of these refineries have closed but the province remains an important centre particularly in the manufacturing of oil-derived plastic products. Tables and maps showing the development and distribution of petrochemical manufacturing and the location of oil pipelines in the Montreal area, at various times since 1946, are included. 11 figs

Chemodynamics of EDTA in a simulated mixed waste: the Hanford Site's complex concentrate waste

International Nuclear Information System (INIS)

Toste, A.P.; Ohnuki, Toshihiko

1999-01-01

Enormous stockpiles of mixed wastes at the USDOE's Hanford Site, the original US plutonium production facility, await permanent disposal. One mixed waste derived from reprocessing spent fuel was found to contain numerous nuclear related organics including chelating agents like EDTA and complexing agents, which have been used as decontamination agents, etc. Their presence in actual mixed wastes indicates that the organic content of nuclear wastes is dynamic and complicate waste management efforts. The subjects of this report is the chemo-degradation of EDTA degradation in a simulant Hanford's complex concentrate waste. The simulant was prepared by adding EDTA to an inorganic matrix, which was formulated based on past analyses of the actual waste. Aliquots of the EDTA simulant were withdrawn at different time points, derivatized via methylation and analyzed by gas chromatography and Gc/MS to monitor the disappearance of EDTA and the appearance of its' degradation products. This report also compares the results of EDTA's chemo-degradation to the g-radiolysis of EDTA in the simulant, the subject of a recently published article. Finally based on the results of these two studies, an assesment of the potential impact of EDTA degradation on the management of mixed wastes is offered. (J.P.N.)

Petrochemical producers gain advantage with novel business strategies

International Nuclear Information System (INIS)

Glauthier, T.; Kalkstein, H.; Williamson, R.

1997-01-01

After 50 years of gradual change in the petrochemicals industry, the rules of the game are rapidly being written. Parity among competitors has made strategies based on minimizing costs increasingly ineffectual. Some competitors are now finding new business approaches that may allow them to leave others behind. Although the recent upturn in the chemical cycle has brought with it high utilization rates and encouraging financial returns for manufacturers of both petrochemicals and other chemicals, chemical managers need to be aware that the next downturn may erase these gains. The industry has experienced periods of poor financial performance in the past, and there is little reason to expect that the future will bring improvements. Until recently, petrochemical companies have generally pursued strategies focused on optimizing particular portions of the value chain. For the purposes of this article, it is helpful to think of the value chain in terms of four main business segments: feedstocks, products, production processes, and service/distribution. Some chemical companies have managed to avoid a competitive stalemate by developing strategies that have fundamentally changed the way the game is played. Granted, it will still be necessary to pursue maximum efficiency, but the emerging strategies will allow the companies that adopt them to differentiate themselves further than they otherwise could have done. These strategies are discussed

World petrochemical outlook: Is the current weakness a trend or an aberration?

International Nuclear Information System (INIS)

Baggett, P.E.

1995-01-01

While the focus of this conference is methanol, a review of the general petrochemical industry might be enlightening and valuable to understanding the methanol market. Methanol is certainly a commodity with similarities to hydrocarbons such as gasoline and similarities to base petrochemicals such as ethylene. Methanol stands with one foot in the fuels market via MTBE and the other in the chemicals business for acetic acid and formaldehyde, among many others. Is the world petrochemical market moving into a new trend of weak prices and profits or is the strong growth seen in 1994 and 1995 continuing and the current situation an aberration? In order to determine whether the current market is a trend or aberration, the author looks at issues that he believes caused the current situation and then considers where the world's economies and petrochemical markets are heading. The issues discussed are: unusually high price increase in a short period; inventory increase/decrease because of price changes; reduction in demand caused by high prices; increase in capacity caused by high prices; changes in growth of world economies; and political/economic issues in China

Evaluation of Respiratory Protection Program in Petrochemical Industries: Application of Analytic Hierarchy Process

Directory of Open Access Journals (Sweden)

Hadi Kolahi

2018-03-01

Full Text Available Background: Respiratory protection equipment (RPE is the last resort to control exposure to workplace air pollutants. A comprehensive respiratory protection program (RPP ensures that RPE is selected, used, and cared properly. Therefore, RPP must be well integrated into the occupational health and safety requirements. In this study, we evaluated the implementation of RPP in Iranian petrochemical industries to identify the required solutions to improve the current status of respiratory protection. Methods: This cross-sectional study was conducted among 24 petrochemical industries in Iran. The survey instrument was a checklist extracted from the Occupational Safety and Health Administration respiratory protection standard. An index, Respiratory Protection Program Index (RPPI, was developed and weighted by analytic hierarchy process to determine the compliance rate (CR of provided respiratory protection measures with the RPP standard. Data analysis was performed using Excel 2010. Results: The most important element of RPP, according to experts, was respiratory hazard evaluation. The average value of RPPI in the petrochemical plants was 49 ± 15%. The highest and lowest of CR among RPP elements were RPE selection and medical evaluation, respectively. Conclusion: None of studied petrochemical industries implemented RPP completely. This can lead to employees' overexposure to hazardous workplace air contaminants. Increasing awareness of employees and employers through training is suggested by this study to improve such conditions. Keywords: analytic hierarchy process, petrochemical industries, respiratory protection program

Energy-saving at petrochemical plant

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

A potential survey was conducted of the reduction of greenhouse effect gas emissions and energy conservation in Thailand which are to be brought by the introduction of the energy conservation technology of Japan to a petrochemical company of Thailand. In the survey, study was made on the energy consumption in NPC (National Petroleum Corporation) which started operation 10 years ago, the largest petrochemical company in Thailand, and items for improvement of energy efficiency were selected and the demonstration was made using equipment. NPC's plant produces ethylene and propylene from natural gas and supplies power and vapor to plants near-by at the same time. The paper studied the power generation by recovery of exhaust heat, improvement of efficiency of power generation use gas turbine, reinforcement of thermal insulation of cracking furnace of ethylene plant, renewal of thermal insulation of vapor pipeline, change of the superannuated air conditioner to the high-efficient one, etc., and explained the specifications for improvement, expenses required and profits expected. The energy conservation amount to be brought by this improvement project will be 21,900 t/y crude oil or equivalent, and the reduction amount of greenhouse effect gas emissions 45,300 t/y CO2. (NEDO)

Energy-saving at petrochemical plant

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

A potential survey was conducted of the reduction of greenhouse effect gas emissions and energy conservation in Thailand which are to be brought by the introduction of the energy conservation technology of Japan to a petrochemical company of Thailand. In the survey, study was made on the energy consumption in NPC (National Petroleum Corporation) which started operation 10 years ago, the largest petrochemical company in Thailand, and items for improvement of energy efficiency were selected and the demonstration was made using equipment. NPC's plant produces ethylene and propylene from natural gas and supplies power and vapor to plants near-by at the same time. The paper studied the power generation by recovery of exhaust heat, improvement of efficiency of power generation use gas turbine, reinforcement of thermal insulation of cracking furnace of ethylene plant, renewal of thermal insulation of vapor pipeline, change of the superannuated air conditioner to the high-efficient one, etc., and explained the specifications for improvement, expenses required and profits expected. The energy conservation amount to be brought by this improvement project will be 21,900 t/y crude oil or equivalent, and the reduction amount of greenhouse effect gas emissions 45,300 t/y CO2. (NEDO)

High-level waste program integration within the DOE complex

International Nuclear Information System (INIS)

Valentine, J.H.; Malone, K.; Schaus, P.S.

1998-03-01

Eleven major Department of Energy (DOE) site contractors were chartered by the Assistant Secretary to use a systems engineering approach to develop and evaluate technically defensible cost savings opportunities across the complex. Known as the complex-wide Environmental Management Integration (EMI), this process evaluated all the major DOE waste streams including high level waste (HLW). Across the DOE complex, this waste stream has the highest life cycle cost and is scheduled to take until at least 2035 before all HLW is processed for disposal. Technical contract experts from the four DOE sites that manage high level waste participated in the integration analysis: Hanford, Savannah River Site (SRS), Idaho National Engineering and Environmental Laboratory (INEEL), and West Valley Demonstration Project (WVDP). In addition, subject matter experts from the Yucca Mountain Project and the Tanks Focus Area participated in the analysis. Also, departmental representatives from the US Department of Energy Headquarters (DOE-HQ) monitored the analysis and results. Workouts were held throughout the year to develop recommendations to achieve a complex-wide integrated program. From this effort, the HLW Environmental Management (EM) Team identified a set of programmatic and technical opportunities that could result in potential cost savings and avoidance in excess of $18 billion and an accelerated completion of the HLW mission by seven years. The cost savings, schedule improvements, and volume reduction are attributed to a multifaceted HLW treatment disposal strategy which involves waste pretreatment, standardized waste matrices, risk-based retrieval, early development and deployment of a shipping system for glass canisters, and reasonable, low cost tank closure

Investigation Of HDPE Plastic Waste Aggregate On The Properties Of Concrete

OpenAIRE

A. M. Mustafa Al Bakri; S. Mohammad Tamizi; A. R. Rafiza; Y. Zarina

2011-01-01

Quantities of polymer wastes have increased in recent years due to increases in industrialization and the rapid improvement in the standard of living. In Malaysia, most polymer wastes are abandoned and not recycled, causing serious problems, such as the waste of natural resources and environmental pollution. Polymer products, such as synthetic fibers, plastics, and rubber, are made from petrochemical compounds, and they degrade extremely slowly in the natural environment. Plastic materials ar...

Challenges of knowledge sharing in the petrochemical industry

Directory of Open Access Journals (Sweden)

Chin Wei Chong

2014-06-01

Full Text Available Knowledge sharing is one of the important and also challenging parts in the success of KM implementation. The objective of this paper is to find out knowledge sharing barriers in the petrochemical companies in a Middle East country. Three main categories are found to have an impact on knowledge sharing in the companies. These categories are potential individual knowledge sharing barriers, potential organizational knowledge sharing barriers and potential technological knowledge sharing barriers. Data were collected by using a convenience sampling survey method. 500 questionnaires were distributed among employees and 302 questionnaires were returned. Trust, knowledge as power, communication, organizational hierarchy and knowledge sharing technological systems are found to have relationships with knowledge sharing. However, reward and recognition system have less significant relationship with knowledge sharing in the petrochemical companies.

Opportunities and challenges at the interface between petrochemicals and refinery. The OMV view

Energy Technology Data Exchange (ETDEWEB)

Lichtscheidl, J. [OMV Refining and Marketing GmbH, Vienna (Austria)

2007-07-01

OMV's refineries have been integrated into petrochemicals since the first steam cracker came on line in 1970. The refineries in Schwechat, Burghausen and Romania, especially Arpechim, have significant petrochemical capacities. In 1998 PCD was merged with Borealis, a leading producer of high grade polymers. OMV's initial 25% stake in Borealis increased to 36 in 2007. The last years have seen major investments in Schwechat and Burghausen: Schwechat's cracker was expanded by approximately 150 KTA to a nominal 500 KTA of ethylene. And in Burghausen the revamp of the cracker has been combined with a metathesis unit in order to feed a new 330 KTA polypropylene plant. The polymer market is still growing. However, the bulk of investments to increase capacity are located in the Middle East and in the Asia-Pacific region, predominately in China. As more and more products from these regions find their way to Europe, the European petrochemicals industry faces fierce competition. The response is restructuring: the creation of Arkema (Total), the takeover of BP's petrochemical assets by INEOS, the disposal of Shell-BASF subsidiary Basell to Haldia Petrochemical and Accent Industries, and the transfer of Statoil's interest in Borealis to IPIC and OMV. And most recently, Basell's acquisition of Lyondell. Compared with competitors in the Middle East and the Asia-Pacific region, producers in Europe are burdened with serious disadvantages: fairly old, small units and high costs of labor, energy and raw materials. There is no single solution. OMV, however, will continue to follow the strategies that have been successful so far: - Ever closer integration of refining and petrochemicals; - Capturing market opportunities for profitable growth; -Remaining market orientated. (orig.)

[Application of association rule in mental health test for employees in a petrochemical enterprise].

Science.gov (United States)

Zhang, L F; Zhang, D N; Wang, Z P

2017-10-20

Objective: To investigate the occurrence ruleof common psychological abnormalities in petrochemical workers using association rule. Methods: From July to September,2014,the Symptom Checklist-90 (SCL-90)was used for the general survey of mental healthamong all employees in a petrochemical enterprise.The association rule Apriori algorithm was used to analyze the data of SCL-90 and investigate the occurrence rule of psychological abnormalities in petrochemical workers with different sexes,ages,or nationalities. Results: A total of 8 248 usable questionnaires were collected. The SCL-90 analysis showed that 1623 petrochemical workers(19.68%) had positive results,among whom 567(34.94%)had one positive factor and 1056 (65.06%)had two or more positive factors. A total of 7 strong association rules were identified and all of them included obsessive-compulsive symptom and depression. Male({obsessive-compulsive symptom,anxiety}=>{depression}) and female workers ({somatization,depression}=>{obsessive-compulsive symptom}) had their own special association rules. The workers aged 35-44 years had 17 special association rules,and ethnic minorities had 5 special association rules. Conclusion: Employeesin the petrochemical enterprise have multiple positive factors in SCL-90, and employees aged 35-44 years and ethnic minorities have a rich combination of psychological symptoms and need special attention during mental health intervention.

Evaluation of liver enzyme levels in workers exposed to vinyl chloride vapors in a petrochemical complex: a cross-sectional study

Directory of Open Access Journals (Sweden)

Dolati Mandana

2007-08-01

Full Text Available Abstract Background Polyvinyl chloride is used in production and manufacturing of many essential tools (e.g. plastic pipes, photography films, etc.. Its production is impossible without the use of vinyl chloride monomer (VCM, which can cause liver damage in long-term. In this study we intend to assess the effects of mild to moderate long term exposure to VCM on liver and to assess the importance of liver enzyme measurements as a screening tool. Methods In this study, liver enzyme levels of 52 workers were compared to 48 control workers using the T-test. The cases all worked in a PVC production unit in a petrochemical complex and the controls were randomly selected from office personnel of the same complex. A questionnaire was also filled in about information such as age, weight, work history, etc. in both groups. Results Mean comparisons for ALP and GGT using T-test showed statistically significant differences between the two groups. For AST, ALT and bilirubin (total, direct the mean was higher in the case group but this difference was not statistically significant. Discussion This study showed that mild exposure to VCM can cause mild liver cholestasis. So, using cholestasis assessment tests such as ALP and GGT should be considered in periodic assessment of liver function in PVC producing units.

Pollution and health risk assessment of industrial and residential area based on metal and metalloids contents in soil and sediment samples from and around the petrochemical industry, Serbia

Science.gov (United States)

Relic, Dubravka; Sakan, Sanja; Andjelkovic, Ivan; Djordjevic, Dragana

2017-04-01

Within this study the investigation of pollution state of metal and metalloids contamination in soils and sediments samples of the petrochemical and nearby residential area is present. The pseudo-total concentrations of Ba, Cd, Co, Cu, Cr, Mn, Ni, Pb, V, Zn, As, Hg, and Se were monitored with ICP/OES. The pollution indices applied in this work, such as the enrichment factor, the pollution load index, the total enrichment factor, and the ecological risk index showed that some of the soil and sediment samples were highly polluted by Hg, Ba, Pb, Cd, Cr Cu and Zn. The highest pollution indices were calculated for Hg in samples from the petrochemical area: chloralkali plant, electrolysis factory, mercury disposal area, and in samples from the waste channel. The pollution indices of the samples from the residential area indicated that this area is not polluted by investigated elements. Besides the pollution indices, the metal and metalloids concentrations were used in the equations for calculating the health risk criteria. We calculate no carcinogenic and carcinogenic risks for the composite worker and residential people by usage adequate equations. In analyzed samples, the no carcinogenic risks were lower than 1. The highest values of carcinogenic risk were obtained in sediment samples from the waste channel within the petrochemical industry and the metal that mostly contributes to the highest carcinogenic risk is Cr. Correlation analysis of pollution indices and carcinogenic risks calculated from the residential area samples showed good correlations while this is not the case for an industrial area.

Organic analyses of an actual and simulated mixed waste. Hanford's organic complexant waste revisited

International Nuclear Information System (INIS)

Toste, A.P.; Osborn, B.C.; Polach, K.J.; Lechner-Fish, T.J.

1995-01-01

Reanalysis of the organics in a mixed waste, an organic complexant waste, from the U.S. Department of Energy's Hanford Site, has yielded an 80.4% accounting of the waste's total organic content. In addition to several complexing and chelating agents (citrate, EDTA, HEDTA and NTA), 38 chelator/complexor fragments have been identified, compared to only 11 in the original analysis, all presumably formed via organic degradation. Moreover, a mis identification, methanetricarboxylic acid, has been re-identified as the chelator fragment N-(methylamine)imino-diacetic acid (MAIDA). A nonradioactive simulant of the actual waste, containing the parent organics (citrate, EDTA, HEDTA and NTA), was formulated and stored in the dark at ambient temperature for 90 days. Twenty chelator and complexor fragments were identified in the simulant, along with several carboxylic acids, confirming that myriad chelator and complexor fragments are formed via degradation of the parent organics. Moreover, their abundance in the simulant (60.9% of the organics identified) argues that the harsh chemistries of mixed wastes like Hanford's organic degradation, even in the absence of radiation. (author). 26 refs., 2 tabs

Anaerobic biodegradation of a petrochemical waste-water using biomass support particles

International Nuclear Information System (INIS)

Sharma, S.; Ramakrishna, C.; Desai, J.D.; Bhatt, N.M.

1994-01-01

During the anaerobic biodegradation of effluent from a dimethyl terephthalate (DMT) manufacturing plant, reduction in chemical oxygen demand (COD) degradation and biogas formation was observed after the waste-water concentration exceeded 25% of added feed COD. This condition reverted back to normal after 25-30 days when the DMT waste-water concentration in the feed was brought down to a non-toxic level. However, the above effects were observed only after the concentration of DMT waste-water reached more than 75% of added feed COD when biomass support particles (BSP) were augmented to the system. In the BSP system, a biomass concentration of up to 7000 mg/l was retained and the sludge retention time increased to >200 days compared to 2200 mg/l and 8-10 days, respectively, in the system without BSP (control). Formaldehyde in the waste-water was found to be responsible for the observed toxicity. The BSP system was found to resist formaldehyde toxicity of up to 375 mg/l as against 125 mg/l in the control system. Moreover, the BSP system recovered from the toxicity much faster (15 days) than the control (25-30 days). The advantages of the BSP system in anaerobic treatment of DMT waste-water are discussed. (orig.)

Development and validation of a new safety climate scale for petrochemical industries.

Science.gov (United States)

Jafari, Mohammad Javad; Eskandari, Davood; Valipour, Firouz; Mehrabi, Yadollah; Charkhand, Hossein; Mirghotbi, Mostafa

2017-01-01

While a considerable body of research has studied safety climate and its role as a leading indicator of organizational safety, much of this work has been conducted with Western manufacturing samples. The current study puts emphasis on the cross-validation of a safety climate model in the non-Western industrial context of Iranian petrochemical industries. The current study was performed in one petrochemical company in Iran. The scale was developed through conducting a literature review followed by a qualitative study with expert participation. After performing a screening process, the initial number of items on the scale was reduced to 68. Ten dimensions (including management commitment, workers' empowerment, communication, blame culture, safety training, job satisfaction, interpersonal relationship, supervision, continuous improvement, and reward system) together with 37 items were extracted from the exploratory factor analysis (EFA) to measure safety climate. Acceptable ranges of internal consistency statistics for the sub-scales were observed. Confirmatory factor analysis (CFA) confirmed the construct validity of the developed safety climate scale for the petrochemical industry workers. The results of reliability showed that the Cronbach's alpha coefficient for the designed scale was 0.94. The ICC was obtained 0.92. This study created a valid and reliable scale for measuring safety climate in petrochemical industries.

The impact of the petrochemical industry in the economic development framework of the Montreal region

International Nuclear Information System (INIS)

Danis, M.

1992-01-01

A brief overview of the petrochemical industry in Canada was presented. The industry, which employs approximately 100,000 Canadians, has an annual production estimated to be in excess of 20 billion dollars. Similarly, in the province of Quebec, the petrochemical industry makes a very significant contribution to the economy of the province, especially to that of the Montreal region. Recent initiatives and investments by the Canadian Government in the petrochemical sector were summarized. Among these, subsidies to Petromont to improve and modernize its plant facilities in Varennes, to Himont Canada, also of Varennes, to develop a new manufacturing process, to Gaz Metropolitain to establish a centre of gas technology, were highlighted. These and other government measures and initiatives provide a solid foundation for the petrochemical industry to continue to play a pre-eminent role in the economy of the Montreal region

Approximation of theoretical energy-saving potentials for the petrochemical industry using energy balances for 68 key processes

International Nuclear Information System (INIS)

Neelis, Maarten; Patel, Martin; Blok, Kornelis; Haije, Wim; Bach, Pieter

2007-01-01

We prepared energy and carbon balances for 68 petrochemical processes in the petrochemical industry for Western Europe, the Netherlands and the world. We analysed the process energy use in relation to the heat effects of the chemical reactions and quantified in this way the sum of all energy inputs into the processes that do not end up in the useful products of the process, but are lost as waste heat to the environment. We showed that both process energy use and heat effects of reaction contribute significantly to the overall energy loss of the processes studied and recommend addressing reaction effects explicitly in energy-efficiency studies. We estimated the energy loss in Western Europe in the year 2000 at 1620 PJ of final energy and 1936 PJ of primary energy, resulting in a total of 127 Mt CO 2 . The losses identified can be regarded as good approximations of the theoretical energy-saving potentials of the processes analysed. The processes with large energy losses in relative (per tonne of product) and absolute (in PJ per year) terms are recommended for more detailed analysis taking into account further thermodynamic, economic, and practical considerations to identify technical and economic energy-saving potentials

Risk assessment study of fire following an earthquake: a case study of petrochemical enterprises in China

Science.gov (United States)

Li, J.; Wang, Y.; Chen, H.; Lin, L.

2014-04-01

After an earthquake, the fire risk of petrochemical enterprises is higher than that of other enterprises as it involves production processes with inflammable and explosive characteristics. Using Chinese petrochemical enterprises as the research object, this paper uses a literature review and case summaries to study, amongst others, the classification of petrochemical enterprises, the proportion of daily fires, and fire loss ratio. This paper builds a fire following an earthquake risk assessment model of petrochemical enterprises based on a previous earthquake fire hazard model, and the earthquake loss prediction assessment method, calculates the expected loss of the fire following an earthquake in various counties and draws a risk map. Moreover, this research identifies high-risk areas, concentrating on the Beijing-Tianjin-Tangshan region, and Shandong, Jiangsu, and Zhejiang provinces. Differences in enterprise type produce different levels and distribution of petrochemical enterprise earthquake fire risk. Furthermore, areas at high risk of post-earthquake fires and with low levels of seismic fortification require extra attention to ensure appropriate mechanisms are in place.

Panorama 2014 - Petrochemicals and green chemistry

International Nuclear Information System (INIS)

Alario, Fabio; Marion, Pierre

2013-12-01

The petrochemical industry will experience structural and economic upheaval in the coming years, driven by the development of shale gas in the United States and increasing tensions surrounding the availability and price of certain intermediate products. A real opportunity exists to further develop a new chemical industry based on processing biomass; the basic framework is in place, but it will need several years to mature. (authors)

Radioactive Waste Management Complex low-level waste radiological performance assessment

Energy Technology Data Exchange (ETDEWEB)

Maheras, S.J.; Rood, A.S.; Magnuson, S.O.; Sussman, M.E.; Bhatt, R.N.

1994-04-01

This report documents the projected radiological dose impacts associated with the disposal of radioactive low-level waste at the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory. This radiological performance assessment was conducted to evaluate compliance with applicable radiological criteria of the US Department of Energy and the US Environmental Protection Agency for protection of the public and the environment. The calculations involved modeling the transport of radionuclides from buried waste, to surface soil and subsurface media, and eventually to members of the public via air, groundwater, and food chain pathways. Projections of doses were made for both offsite receptors and individuals inadvertently intruding onto the site after closure. In addition, uncertainty and sensitivity analyses were performed. The results of the analyses indicate compliance with established radiological criteria and provide reasonable assurance that public health and safety will be protected.

Radioactive Waste Management Complex low-level waste radiological performance assessment

International Nuclear Information System (INIS)

Maheras, S.J.; Rood, A.S.; Magnuson, S.O.; Sussman, M.E.; Bhatt, R.N.

1994-04-01

This report documents the projected radiological dose impacts associated with the disposal of radioactive low-level waste at the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory. This radiological performance assessment was conducted to evaluate compliance with applicable radiological criteria of the US Department of Energy and the US Environmental Protection Agency for protection of the public and the environment. The calculations involved modeling the transport of radionuclides from buried waste, to surface soil and subsurface media, and eventually to members of the public via air, groundwater, and food chain pathways. Projections of doses were made for both offsite receptors and individuals inadvertently intruding onto the site after closure. In addition, uncertainty and sensitivity analyses were performed. The results of the analyses indicate compliance with established radiological criteria and provide reasonable assurance that public health and safety will be protected

Quebec's petrochemical industry: prospects and challenges: proceedings of the workshop

International Nuclear Information System (INIS)

1992-01-01

A review of the present status of Quebec's petrochemical industry was presented, including an historical perspective of the development of the industry. In terms of economic importance, the petrochemical industry in the province of Quebec occupies fifth place and is primarily concentrated in the Montreal region. The industry peaked in 1976 with six producing refineries in east Montreal. At that time, Montreal represented the largest refining centre in Canada with a combined capacity of 600,000 barrels per year. Although four of these refineries have closed, the province remains an important centre particularly in the manufacturing of oil-derived plastic products. The objective of this workshop was to throw light on the challenges and the strategic economic potential of the Montreal region, to obtain the views of experienced industry insiders regarding the extent of changes that globalization of the industry has produced and the kind of conditions that would have to be created to ensure that the Montreal region can continue to compete in the global market place. Recent initiatives and investments by the Canadian Government in the petrochemical sector were also summarized. tabs., figs

Environmental indicators of the combustion of prospective coal water slurry containing petrochemicals.

Science.gov (United States)

Dmitrienko, Margarita A; Nyashina, Galina S; Strizhak, Pavel A

2017-09-15

Negative environmental impact of coal combustion has been known to humankind for a fairly long time. Sulfur and nitrogen oxides are considered the most dangerous anthropogenic emissions. A possible solution to this problem is replacing coal dust combustion with that of coal water slurry containing petrochemicals (CWSP). Coal processing wastes and used combustible liquids (oils, sludge, resins) are promising in terms of their economic and energy yield characteristics. However, no research has yet been conducted on the environmental indicators of fuels based on CWSP. The present work contains the findings of the research of CO, CO2, NOx, SOx emissions from the combustion of coals and CWSPs produced from coal processing waste (filter cakes). It is demonstrated for the first time that the concentrations of dangerous emissions from the combustion of CWSPs (carbon oxide and dioxide), even when combustible heavy liquid fractions are added, are not worse than those of coal. As for the concentration of sulfur and nitrogen oxides, it is significantly lower for CWSPs combustion as compared to coals. The presented research findings illustrate the prospects of the wide use of CWSPs as a fuel that is cheap and beneficial, in terms of both energy output and ecology, as compared to coal. Copyright © 2017 Elsevier B.V. All rights reserved.

340 waste handling complex: Deactivation project management plan

International Nuclear Information System (INIS)

Stordeur, R.T.

1998-01-01

This document provides an overview of the strategy for deactivating the 340 Waste Handling Complex within Hanford's 300 Area. The plan covers the period from the pending September 30, 1998 cessation of voluntary radioactive liquid waste (RLW) transfers to the 340 Complex, until such time that those portions of the 340 Complex that remain active beyond September 30, 1998, specifically, the Retention Process Sewer (RPS), can also be shut down and deactivated. Specific activities are detailed and divided into two phases. Phase 1 ends in 2001 after the core RLW systems have been deactivated. Phase 2 covers the subsequent interim surveillance of deactivated and stand-by components during the period of continued RPS operation, through the final transfer of the entire 340 Complex to the Environmental Restoration Contractor. One of several possible scenarios was postulated and developed as a budget and schedule planning case

Organic complexing agents in low and medium level radioactive waste

International Nuclear Information System (INIS)

Allard, B.; Persson, G.

1985-11-01

Low and medium level radioactive wastes will contain various organic agents, such as ion exchange resins (mainly in the operational wastes), plastics and cellulose (mainly in the reprocessing wastes and in the decommissioning wastes) and bitumen (mainly in the reprocessing wastes). The degradation of these organics will lead to the formation of complexing agents that possibly could affect the release of radionuclides from an underground repository and the subsequent transport of these nuclides. The solution chemistry of the actinides may be totally dominated by the presence of such organic degradation products within the repository. However, hydrolysis and formation of carbonates (and possibly humates) will most likely dominate solubility and speciation outside the immediate vicinity of the repository. The minor quantities of strong complexing agents (in the reprocessing waste), notably aminopolycarboxylic acids (EDTA, DTPA) and possibly organic phosphates (DBP) could significantly affect speciation and sorption behaviour of primarily the trivalent actinides even outside the repository. (author)

Exchange Rate Pass-through and Industry Characteristics: The Case of Taiwan's Exports of Midstream Petrochemical Products

OpenAIRE

Kuo-Liang Wang; Chung-Shu Wu

1996-01-01

Based on 1986-1992 survey data of 22 midstream petrochemical industries in Taiwan, the empirical results of the export price, the markup ratio and the price-cost margin equations in this study show that Taiwan's petrochemical firms absorb only a small portion of a given weighted exchange rate change in their export prices, markup ratios and price-cost margins. It implies that Taiwan's petrochemical firms have a weak pricing-to-market pattern. The empirical results may be explained by the vola...

USA program on the waste disposal of nuclear military complexes

International Nuclear Information System (INIS)

Vinogradova, I.

1992-01-01

The USA program on the nuclear military complex waste disposal which focuses on the problems of environment protection and recovery is briefly considered. A group of works on the updating of the existing and on the construction of new nuclear weapon undustries is chosen to be the priority direction. The problem of radioactive waste burial in the Hunford nuclear complex is discussed. Total expenses for military enterprise purification from radioactive wastes are estimated as 91.2-129 billion dollars, and expenses for realization of the whole program are estimated as 180 billion dollars for 50 years

Petrochemical plant in the desert

International Nuclear Information System (INIS)

Sunnanaa, Dag

2001-01-01

Qatar Vinyl Company Ltd. (QVC), a new production plants for raw material for PVC production, was opened in Qatar on the 20. June 2000. The design capacity is 290 000 tonne of caustic soda, 175 000 tonne of ethylene dichloride and 230 000 tonne of vinyl chloride. Major customers are well established in Australia, India, Malaysia, Indonesia and Thailand. Geographically, Qatar is favourably located with respect to the Asian markets. The company is owned by Qatar Petrochemical Company, Qatar Petroleum, Norsk Hydro and Atofina

Risk assessment study of fire following earthquake: a case study of petrochemical enterprises in China

Science.gov (United States)

Li, J.; Wang, Y.; Chen, H.; Lin, L.

2013-04-01

After an earthquake, the fire risk of petrochemistry enterprises is higher than that of other enterprises as it involves production processes with inflammable and explosive characteristics. Using Chinese petrochemical enterprises as the research object, this paper uses a literature review and case summaries to study, amongst others, the classification of petrochemical enterprises, the proportion of daily fires, and fire loss ratio. This paper builds a fire following earthquake risk assessment model of petrochemical enterprises based on a previous earthquake fire hazard model, and the earthquake loss prediction assessment method, calculates the expected loss of the fire following earthquake in various counties and draws a risk map. Moreover, this research identifies high-risk areas, concentrating on the Beijing-Tianjin-Tangshan region, and Shandong, Jiangsu, and Zhejiang provinces. Differences in enterprise type produce different levels and distribution of petrochemical enterprises earthquake fire risk. Furthermore, areas at high risk of post-earthquake fires and with low levels of seismic fortification require extra attention to ensure appropriate mechanisms are in place.

Concern About Petrochemical Health Risk Before and After a Refinery Explosion

Science.gov (United States)

Cutchin, Malcolm P.; Martin, Kathryn Remmes; Owen, Steven V.; Goodwin, James S.

2014-01-01

On March 23, 2005, a large explosion at an oil refinery in Texas City, Texas caused 15 deaths and approximately 170 injuries. Little is known about how such an industrial accident influences concern about environmental health risks. We used measures of environmental health concern about nearby petrochemical production with a sample of Texas City residents to understand patterns of concern and change in concern after an industrial accident, as well as individual and contextual factors associated with those patterns. Survey interviews with residents of Texas City, Texas (N =315) both pre- and postexplosion using a brief Concern About Petrochemical Health Risk Scale (CAPHRS) and other questions were used to collect pertinent predictor information. CAPHRS baseline, postexplosion, and change scores were compared and modeled using ordinary least squares (OLS) regression and a mixed model. Higher preexplosion CAPHRS scores were predicted by younger adults, foreign-born Hispanics, non-Hispanic blacks, lower- and middle-income groups, and those who live with someone who has worked at the petrochemical plants. Higher CAPHRS change scores are predicted by the same variables (except income), as well as proximity to, or perception of, the explosion, and reports of neighborhood damage. Findings suggest these groups’ concern scores could indicate a greater vulnerability to psychological and physical harm generated by concern and stress arising from local petrochemical activities. A clearer understanding of concern about actual environmental health risks in exposed populations may enhance the evolving theory of stress and coping and eventually enable public health professionals to develop appropriate mitigation strategies. PMID:18643817

B Plant Complex generator dangerous waste storage areas inspection plan: Revision 1

International Nuclear Information System (INIS)

Beam, T.G.

1994-01-01

This document contains the inspection plan for the <90 day dangerous/mixed waste storage areas and satellite accumulation areas at B Plant Complex. This inspection plan is designed to comply with all applicable federal, state and US Department of Energy-Richland Operations Office training requirements. In particular, the requirements of WAC 173-303 ''Dangerous Waste Regulations'' are met by this inspection plan. This inspection plan is designed to provide B Plant Complex with the records and documentation showing that the waste storage and handling program is in compliance with applicable regulations. The plan also includes the requirements for becoming a qualified inspector of waste storage areas and the responsibilities of various individuals and groups at B Plant Complex

The conversion of waste plastics/petroleum residue mixtures to transportation fuels

International Nuclear Information System (INIS)

Ali, M.F.; Siddiqui, M.N.

2005-01-01

Plastics have become the material of choice in the modern world and its applications in the industrial field are continually increasing. Presently the plastics are manufactured for various uses such as: consumer packaging, wires, pipes, containers, bottles, appliances, electrical/electronic parts, computers and automotive parts. Most of he post consumer, plastic products are discarded and end up as mixed plastic municipal waste. The disposal of his waste has become a major social concern. Mixed plastic waste (MPW) recycling is still very much in its infancy. Approximately 20 million tons of plastic waste is generated in the United States of America, while about 15 million tons is generated throughout the Europe. With existing recycle efforts, only 7% of the MPW are recycled to produce low-grade plastic products such as plastic sacks, pipes, plastic fencing, and garden furniture. The current plastic reclamation technology options are generally grouped into the following four types: (i) Primary: The processing of plastic for use comparable to the original application. (ii) Secondary: The processing of plastics waste into new products with a lower quality level. (iii) Tertiary: The chemical or thermal processing of plastic waste to their basic hydrocarbon feedstock. The resulting raw materials are then reprocessed into plastic material or other products of the oil refining process. (iv) Quaternary: The incineration of plastics waste to recover energy. This paper deals exclusively with tertiary recycling by pyrolysis and catalytic cracking of plastics waste alone and by coprocessing with petroleum residue or heavy oils to fuels and petrochemical feedstock for further processing in existing refinery and petrochemical units. (author)

System for decision analysis support on complex waste management issues

International Nuclear Information System (INIS)

Shropshire, D.E.

1997-01-01

A software system called the Waste Flow Analysis has been developed and applied to complex environmental management processes for the United States Department of Energy (US DOE). The system can evaluate proposed methods of waste retrieval, treatment, storage, transportation, and disposal. Analysts can evaluate various scenarios to see the impacts to waste slows and schedules, costs, and health and safety risks. Decision analysis capabilities have been integrated into the system to help identify preferred alternatives based on a specific objectives may be to maximize the waste moved to final disposition during a given time period, minimize health risks, minimize costs, or combinations of objectives. The decision analysis capabilities can support evaluation of large and complex problems rapidly, and under conditions of variable uncertainty. The system is being used to evaluate environmental management strategies to safely disposition wastes in the next ten years and reduce the environmental legacy resulting from nuclear material production over the past forty years

Complex processing of rubber waste through energy recovery

Directory of Open Access Journals (Sweden)

Roman Smelík

2015-12-01

Full Text Available This article deals with the applied energy recovery solutions for complex processing of rubber waste for energy recovery. It deals specifically with the solution that could maximize possible use of all rubber waste and does not create no additional waste that disposal would be expensive and dangerous for the environment. The project is economically viable and energy self-sufficient. The outputs of the process could replace natural gas and crude oil products. The other part of the process is also the separation of metals, which can be returned to the metallurgical secondary production.

The petrochemical industry and its energy use. Prospects for the Dutch energy intensive industry

International Nuclear Information System (INIS)

Gielen, D.J.; Vos, D.; Van Dril, A.W.N.

1996-04-01

The current state and the future of the Dutch petrochemical industry are discussed. First, its current energy use, technology and its markets are analysed. Competitiveness of Dutch and Western European producers compared to foreign producers is shown. Main technological developments and other key issues (e.g. environmental issues) are discussed. Based on this analysis, a future scenario is derived for petrochemical industrial energy use for the period 2000-2015. This case study can be divided into an analysis of the current situation (Chapter 2-6) and alternatives for production and energy consumption of the Dutch petrochemical industry within its Western European context (Chapter 7-11). Chapter 2 analyses the current production structure and the historical developments. Chapter 3 discusses current technologies. Chapter 4 analyses markets for Dutch petrochemical products. Chapter 5 analyses the industry economics in the Netherlands in terms of costs and revenues. Chapter 6 provides information on institutional factors that influence industrial activities. Chapter 7 discusses global competition with special emphasis on competition for the European market. Chapter 8 analyses potential technology shifts. In Chapter 9, data from the preceding chapters on markets, competition, structure and technology are combined to compare competing production options. This is followed by a sensitivity analysis in Chapter 10. Based on a production volume forecast and the development of energy intensity of production, energy consumption of the Dutch petrochemical industry is forecast in Chapter 11. Finally, Chapter 12 provides conclusions and policy recommendations. 24 figs., 48 tabs., 103 refs., 2 appendices

Mixed-waste minimization activities in the nuclear weapons complex

International Nuclear Information System (INIS)

Marchetti, J.A.; Suffern, J.S.

1991-01-01

Over the past 40 years, the US Department of Energy (DOE) and the nuclear weapons complex have successfully executed their mission of providing the country with a strong nuclear deterrent. Now, however, they must attain another mission at the same time: to eliminate or greatly reduce the environmental, safety, and health problems in the complex. Mixed-waste minimization activities have taken place in 11 of the complex production plants and laboratories: the Pinellas plant, the Mount plant, the Kansas City plant, the Y-12 plant, the Rocky Flats plant, the Savannah River Site (SRS), the Savannah River Site (SRS), the Pantex plant, the Nevada Test Site, Sandia National Laboratories, Los Alamos National Laboratory, and the Lawrence Livermore National Laboratory. The mixed-waste minimization opportunities that have been implemented to date by the production facilities are different from those that have been implemented by the laboratories. Areas of opportunity at the plants involve the following activities: (1) process design or improvement; (2) substitution of materials; (3) waste segregation; (4) recycling; and (5) administrative controls

Dynamics of the European refining and petrochemical industry. Strategies, structure and change

International Nuclear Information System (INIS)

Steenbakkers, K.

1997-01-01

The changes in the market position of producers engaged in the oil refining and basic petrochemical industry on the Western European market are the central theme of this book. Analysis of this reshuffling process among these actors is conducted on three levels. First, research is carried out at the level of world regions. In order to understand the reorganization of oil refining and basic petrochemical production in Western Europe, it is necessary to explore the recent aggregate dynamics of these activities on a global scale. Second, the differences in strategic behaviour are exanuned at the level of groups of market participants, namely the major oil companies, the chemical companies, the state-owned companies from both consumer and producer countries, and the independents. Finally, the investment/disinvestment decisions in the Western European oil refining and basic petrochemical industry are investigated at the level of the individual firm. Particular emphasis is placed upon explaining why companies active in the sectors under study have followed different strategies, although they have been confronted with similar adverse market conditions in Western Europe during the last decades. 341 refs

[Source identification of toxic wastewaters in a petrochemical industrial park].

Science.gov (United States)

Yang, Qian; Yu, Yin; Zhou, Yue-Xi; Chen, Xue-Min; Fu, Xiao-Yong; Wang, Miao

2014-12-01

Petrochemical wastewaters have toxic impacts on the microorganisms in biotreatment processes, which are prone to cause deterioration of effluent quality of the wastewater treatment plants. In this study, the inhibition effects of activated sludge's oxygen consumption were tested to evaluate the toxicity of production wastewaters in a petrochemical industrial park. The evaluation covered the wastewaters from not only different production units in the park, but also different production nodes in each unit. No direct correlation was observed between the toxicity effects and the organic contents, suggesting that the toxic properties of the effluents could not be predicted by the organic contents. In view of the variation of activated sludge sensitivity among different tests, the toxicity data were standardized according to the concentration-effect relationships of the standard toxic substance 3, 5-dichlorophenol on each day, in order to improve the comparability among the toxicity data. Furthermore, the Quality Emission Load (QEL) of corresponding standard toxic substance was calculated by multiplying the corresponding 3, 5-dichlorophenol concentration and the wastewater flow quantity, to indicate the toxicity emission contribution of each wastewater to the wastewater treatment plant. According to the rank list of the toxicity contribution of wastewater from different units and nodes, the sources of toxic wastewater in the petrochemical industrial park were clearly identified. This study provides effective guidance for source control of wastewater toxicity in the large industrial park.

Complex-wide review of DOE's management of low-level radioactive waste - progress to date

International Nuclear Information System (INIS)

Letourneau, M.J.

1995-01-01

The Defense Nuclear Facilities Safety Board (DNFSB) Recommendation 94-2 includes a recommendation that the Department of Energy (DOE) conduct a comprehensive, complex-wide review of the low-level waste issue to establish the dimensions of the low-level waste problem and to identify necessary corrective actions to address the safe disposition of past, present, and future volumes. DOE's Implementation Plan calls for the conduct of a complex-wide review of low-level radioactive waste treatment, storage, and disposal sites to identify environmental, safety, and health vulnerabilities. The complex-wide review focuses on low-level waste disposal facilities through a site evaluation survey, reviews of existing documentation, and onsite observations. Low-level waste treatment and storage facilities will be assessed for their ability to meet waste acceptance criteria for disposal. Results from the complex-wide review will be used to form the basis for an integrated and planned set of actions to correct the identified vulnerabilities and to prompt development of new requirements for managing low-level waste

Impact of petrochemicals on the photosynthesis of Halophila ovalis using chlorophyll fluorescence

International Nuclear Information System (INIS)

Ralph, P.J.; Burchett, M.D.

1998-01-01

Laboratory-cultured Halophila ovalis showed tolerance to petrochemical exposure up to 1% (w/v) solution of Bass Strait crude oil, an oil dispersant (Corexit 9527) and a mixture of crude oil and dispersant. Quantum yield, as measured by chlorophyll fluorescence, was the most sensitive measure of the photosynthetic processes affected by petrochemical. The results indicated clearly that chlorophyll fluorescence was effective at monitoring the onset and development of stress and recovery of H. ovalis when exposed to crude oil, dispersant and a mixture of the two compounds. Photosynthetic pigment content generally confirmed the chlorophyll fluorescence response; however, several anomalies occurred. (author)

Ultrasonic and Thermal Pretreatments on Anaerobic Digestion of Petrochemical Sludge: Dewaterability and Degradation of PAHs

Science.gov (United States)

Zhou, Jun; Xu, Weizhong; Wong, Jonathan W. C.; Yong, Xiaoyu; Yan, Binghua; Zhang, Xueying; Jia, Honghua

2015-01-01

Effects of different pretreatment methods on sludge dewaterability and polycyclic aromatic hydrocarbons (PAHs) degradation during petrochemical sludge anaerobic digestion were studied. Results showed that the total biogas production volume in the thermal pretreatment system was 4 and 5 times higher than that in the ultrasound pretreatment and in the control system, and the corresponding volatile solid removal efficiencies reached 28%, 15%, and 8%. Phenanthrene, paranaphthalene, fluoranthene, benzofluoranthene, and benzopyrene removal rates reached 43.3%, 55.5%, 30.6%, 42.9%, and 41.7%, respectively, in the thermal pretreatment system, which were much higher than those in the ultrasound pretreatment and in the control system. Moreover, capillary suction time (CST) of sludge increased after pretreatment, and then reduced after 20 days of anaerobic digestion, indicating that sludge dewaterability was greatly improved after anaerobic digestion. The decrease of protein and polysaccharide in the sludge could improve sludge dewaterability during petrochemical sludge anaerobic digestion. This study suggested that thermal pretreatment might be a promising enhancement method for petrochemical sludge solubilization, thus contributing to degradation of the PAHs, biogas production, and improvement of dewaterability during petrochemical sludge anaerobic digestion. PMID:26327510

The Impact of the Development of Shale Gas in the United States on Europe's Petrochemical Industries

International Nuclear Information System (INIS)

Cornot-Gandolphe, Sylvie

2013-01-01

The shale gas revolution has led to strong falls in energy prices, reducing significantly the raw material costs of the US petrochemical industry. Between 2008 and 2012, US gas prices fell by two thirds. Ethane comes from natural gas liquids (NGLs) contained in shale gas, and used by the US petrochemical industry as the raw material to make ethylene. Its price fell by 55% between 2008 and 2012. These price cuts are giving the US petrochemical industry a significant competitive advantage, and profits are exploding. The United States has become the region in the world with the second lowest energy and raw material prices, just after the Middle East. This renewed competitiveness is leading to the re-birth of American petrochemicals, whereas the sector was stagnating and even experiencing waves of closures in the middle of the 2000's. An estimated $15 billion is set to be invested in the sector by 2017, generating a 40% increase in ethylene output, the leading petrochemical product. The competitive advantage makes itself felt downstream in the sector. In particular, plastics derived from the transformation of petrochemicals are used in manufacturing in three major consumer industries: packaging, construction and the automotive industry. By 2017, the output capacity of polyethylene, the polymer most used in the production of plastics, should rise by 40%. The economic spillovers of such investments are significant. The American Chemistry Council (ACC) has conducted a study of around one hundred investment projects, identified at the end of March 2013 in the US chemical industry (excluding pharmaceuticals). These projects involved $72 billion in investment, through to 2020. They will raise the turnover of the chemical industry by $67 billion (in 2012 dollars), by 2020, and will create 1.2 million jobs during the phase of construction. By 2020, additional earnings of the US economy will run to $201 billion, with tax revenues of $14 billion. The ACC estimates that these

Semi-Quantitative Assessment of the Health Risk of Occupational Exposure to Chemicals and Evaluation of Spirometry Indices on the Staff of Petrochemical Industry

Directory of Open Access Journals (Sweden)

Hajar Dazi

2017-01-01

Full Text Available Background & Aims of the Study: Petrochemical industry is an important industry in the economic development of the country that causes employees have exposure with several kinds of contamination. The aim of this study was Semi-quantitative assessment of the health risk of occupational exposure to chemical materials and investigation of spirometry indices between employees of petrochemical industry. Material & Methods: This cross-sectional study was conducted in one of the petrochemical industry complex in a special area of Assaluyeh in Iran in 2016. Health risk assessment of exposure to harmful chemical agents was performed in all of units and during three stages (identification of harmful material, determination of hazard rate of the chemical material, exposure rate and estimate of risk rate. Spirometry indices were measured using spirometry. Results: The results of chemical materials risk assessment showed that Raffinate in Butadiene unit has identified the highest amount of risk rank among 27 chemical materials in investigated units. In comparison with spirometry indices in Olefine unit between age with FVC parameter and history work with FVC and FEV1 parameters has observed a significant and negative correlation (P<0.05. Conclusion: The results of risk assessment in all of the petrochemical units showed that 48.14% of materials were at low risk level, 29.62% medium risk, 18.51% high risk and 3.7% had very high risk level. The variables affecting on spirometry employees such as age and work experience play an important role in reducing the pulmonary function tests in exposed subjects.

An outline of the Dutch chemical industry and petrochemical industry

International Nuclear Information System (INIS)

Heesen, Th.J.; Terwoert, J.; Hoefnagels, F.

1996-03-01

An overview is given of the most important processes and products of the chemical and petrochemical industry in the Netherlands. Also attention is paid to the material balance and the energy balance of those industries. refs

Guidelines for the management of common hazardous wastes in developing countries

International Nuclear Information System (INIS)

Smith, J.E. Jr; Helmick, J.; Ozolins, G.

1991-01-01

Several United Nations organizations, including the World Health Organization (WHO), World Bank (WB), and United Nations Environment Programme (UNEP), are cooperating in the development and implementation of a technology transfer and training program for management of hazardous wastes. A number of other organizations, including the International Solid Waste and Public Cleansing Association (ISWA) and the U.S. Environmental Protection Agency (EPA), are assisting in this effort. Waste-specific guidelines are being written for administrators and technical staff in developing countries who are responsible for waste management and for public health and environmental protection in general. Guidance documents are being developed for wastes based on requests from personnel in developing countries, including: metal finishing (e.g., electroplating) wastes, pesticides, chlorinated solvents (including PCBs), petrochemicals, waste oils, tannery/fellmongering/slaughterhouse wastes, clinical wastes, lead acid batteries, asbestos, and textile industry wastes. (au)

Accumulation of specific pollutants in various media in the area affected by a petrochemical center

International Nuclear Information System (INIS)

Oprea, C.D.; Mihul, Al.

2003-01-01

The Southern part of Romania is a highly industrialized region, including oil refining, ferrous and non-ferrous, chemical and power point source categories. The results from monitoring oil pollution around the town Ploiesti (South Romania), known for its petrochemical and chemical industrial compounds and crude oil activity, are reported. The distribution of heavy metals, rare earth and other microelements along the wind rose profile (at 20 Km distance from the oil complex ) was examined through the analysis of soil samples. Mosses were chosen as biomonitors of local atmospheric pollution with heavy metals and other toxic elements. The trace elements content of vegetation growing near the plant's area was compared with that of the background one. The contamination of the river flowing in the vicinity of the plant was examined. Comparison of the spatial trends of different pollutants shows the influence of the some atmospheric transport phases on the uptake of trace elements by vegetation. A comparative evaluation of the results was carried out to indicate at which extend the amount of pollutant in the atmosphere or the amount deposited in the soil or transported by sediment contributes to pollution of the local ecosystem in the vicinity of a petrochemical compound. (authors)

Bitumen to refined products and petrochemicals : a preliminary assessment

International Nuclear Information System (INIS)

Crandall, G.

2004-01-01

Purvin and Gertz is an energy consulting firm that provides advise to the energy sector. A review of western Canadian crude oil supply suggests that oil sands production will surpass declining conventional production. Oil sands supply includes synthetic crude oil (SCO), bitumen and diluent. It is expected that oil sands will increase from 42 per cent of western supply in 2002 to 78 per cent in 2015. This presentation reviewed the potential of Alberta's oil sands and presented a recent study of refined products and petrochemicals from bitumen. Upgrading, refining and petrochemical case studies were presented. In particular, the author examined if a Canadian oil sands upgrading project with high capital costs can be competitive with competing projects in the United States and internationally. In addition to supply and demand issues, the presentation examined infrastructure capability and market potential in the United States. The economic potential and risks of preferred business cases compared to upgrading to SCO were also evaluated. tabs., figs

Air Quality Impacts of Petroleum Refining and Petrochemical Industries

Directory of Open Access Journals (Sweden)

Aiswarya Ragothaman

2017-09-01

Full Text Available Though refineries and petrochemical industries meet society’s energy demands and produce a range of useful chemicals, they can also affect air quality. The World Health Organization (WHO has identified polluted air as the single largest environmental risk, and hence it is necessary to strive for and maintain good air quality. To manage potential health impacts, it is important to implement proper air quality management by understanding the link between specific pollutant sources and resulting population exposures. These industries release pollutants such as Volatile Organic Compounds, greenhouse gases and particulate matter, from various parts of their operations. Air quality should be monitored and controlled more meticulously in developing nations where increased energy demands, industrialization and overpopulation has led to more emissions and lower air quality. This paper presents a review of findings and highlights from various studies on air quality impacts of petroleum refining and petrochemical plants in many regions in the world.

Mortality and morbidity study of petrochemical employees in a polluted site

Directory of Open Access Journals (Sweden)

Pasetto Roberto

2012-05-01

Full Text Available Abstract Background The area of Gela was included among the 57 Italian polluted sites of national interest for environmental remediation because of its widespread contamination from a petrochemical complex. The present study investigates mortality and morbidity of the cohort of Gela petrochemical workers with the aim of disentangling occupational from residential risk. Methods Mortality was assessed for 5,627 men hired from 1960, year of the plant start-up, to 1993; it was followed up for vital status in the period 1960–2002. Morbidity was analysed for 5,431 workers neither dead nor lost to follow-up from 1960 to 2001 and was based on Hospital Discharge Records in the period 2001–2006. The work experience was classified in terms of job categories such as blue collars, white collars, and both – workers who shifted from blue to white collar (95% or vice versa. An ad hoc mobility model was applied to define qualitative categories of residence in Gela, as residents and commuters. Standardized Mortality Ratios (SMRs and Mortality Rate Ratios (MRRs were computed, the latter by using a Poisson regression model. Morbidity was analyzed in terms of Hospital Discharge Odds Ratios (HDORs through a logistic regression model. While performing the internal comparisons, white collars was the reference category for the job analysis, and commuters was the reference category for the residential analysis. Results In the light of epidemiological evidence about health risk from petrochemical industries in both occupational and environmental settings, and/or on the basis of information about occupational and residential contamination and health risk in the area of Gela, noteworthy results are shown for lung cancer [MRR: 2.11 (CI 90%; 0.96-4.63 in blue collars; 1.71 (1.09-2.69 in residents], respiratory diseases [HDOR: 2.0 (1.0-3.0 in blue collars; 1.4 (0.96-2.06 in residents] and genitourinary diseases [HDOR: 1.34 (1.06-1.68 in blue collars; 1.23 (1.04-1.45 in

Petrochemical industry drivers

International Nuclear Information System (INIS)

Sedriks, W.

1995-01-01

Extensive analyses of profit-ability and pricing over the years have shown that the trends seen in the petrochemical industry have two dominant drivers, namely, industry experience curves (reflecting continuous process improvement and cost savings) and profitability cycles. Any outlook for the future must examine both of these facets. The author's algorithm for price projections has two primary terms: a cost-related one and a supply/demand-related one. Both are strong functions of experience curves; the latter is also a prime function of cyclicality. At SRI International. To arrive at medium-term quantitative projections, SRI typically creates a consistent base-case scenario that more or less mirrors the past but also incorporates observed directional changes. In this article the author examines in detail how these scenarios are used for projection. He describes experience curves, ethylene/gross domestic product (GDP) penetration levels, industry structure, and cyclicality as they apply to ethylene prices

Complex-wide review of DOE`s management of low-level radioactive waste - progress to date

Energy Technology Data Exchange (ETDEWEB)

Letourneau, M.J.

1995-12-31

The Defense Nuclear Facilities Safety Board (DNFSB) Recommendation 94-2 includes a recommendation that the Department of Energy (DOE) conduct a comprehensive, complex-wide review of the low-level waste issue to establish the dimensions of the low-level waste problem and to identify necessary corrective actions to address the safe disposition of past, present, and future volumes. DOE`s Implementation Plan calls for the conduct of a complex-wide review of low-level radioactive waste treatment, storage, and disposal sites to identify environmental, safety, and health vulnerabilities. The complex-wide review focuses on low-level waste disposal facilities through a site evaluation survey, reviews of existing documentation, and onsite observations. Low-level waste treatment and storage facilities will be assessed for their ability to meet waste acceptance criteria for disposal. Results from the complex-wide review will be used to form the basis for an integrated and planned set of actions to correct the identified vulnerabilities and to prompt development of new requirements for managing low-level waste.

Impact of the development of shale gases in the USA on the European petrochemical industry

International Nuclear Information System (INIS)

Cornot-Gandolphe, Sylvie

2013-10-01

As the massive development of shale gases and oils in the USA is often only considered in its energetic dimension, the author discusses the influence these raw materials have, not only on energy production, but as raw materials for the industry and more particularly for the petrochemical industry which is a high energy consumer and also transforms these products into products used by all types of manufacturing industries. In a first part, the author recalls this strong development of shale gas production in the USA, its main impacts on the US gas industry, notably its impact on energy prices on the American market. In a second part, the author reports the analysis of the contrasted evolutions of energy prices (gas, electricity, ethane, naphtha) in the USA and in Europe, and highlights the significant competitive advantage the USA took from the development of shale gas. A third part describes the revival of the American petrochemical industry through numerous investment projects of new ethylene and polyethylene production capacities which have been announced since the decrease of energy prices. The impact of this development on the European petrochemical industry is analysed in the next part which also describes adaptation strategies adopted by European petrochemical industries

Long-term outlook for Alberta's primary petrochemical industry : panel discussion : sustainability, feedstocks, infrastructure, transportation

International Nuclear Information System (INIS)

Lauzon, D.

1997-01-01

The long-term outlook for Dow Chemical's involvement in Alberta's petrochemical industry was discussed. Dow Chemical Canada is a company with annual sales of more than $20 billion that manufactures and supplies chemicals, plastics, energy, agricultural products, consumer goods and environmental services in 157 countries in the world. Alberta is the centre of growth and development for the Canadian petrochemical industry because of the proximity to feedstocks. Alberta is seen as a good, long-term source of ethane. Dow Chemical intends to continue being a major player in the further development of the industry in Alberta. As proof of that confidence, there are 11 capital projects in progress at Dow's Western Canada Operation, totaling $600 million. An important ingredient of the continuing success of the petrochemical industry in Alberta will be the willingness and ability of the federal and provincial governments to work in partnership with industry to develop support infrastructure and policies

Dynamic effects of tank waste aging on radionuclide-complexant interactions. 1998 annual progress report

International Nuclear Information System (INIS)

Arterburn, J.B.; Chamberlin, R.

1998-01-01

'The overall objective of this project is to provide a scientific basis for safely processing complexant-containing high-level tank wastes for disposal. The key goals are to identify a means to prepare realistic complexant-containing tank waste simulants, and to use those simulants to determine the relative importance of organic complexants and their breakdown products on the partitioning of important radionuclides. These goals will be accomplished by artificially aging complexant-containing tank waste simulants using microwave, ultrasound, and photolysis techniques. The simulants will be compared to samples of actual Hanford tank wastes to determine the most realistic aging method, on the basis of the organic fragmentation and the partitioning behavior of the important radionuclides 90 Sr, 99 Tc, and 239 Pu. Also, the authors will use their simulant aging process to investigate the relative effects of chelator degradation products on the partitioning of important radionuclides from the waste. Using NMR-active labels in the chelators, they will use a combinatorial approach of generating multiple chelator fragments in a single experiment and then determining which fragments have a negative effect on the separations chemistry. The successful completion of this goal will specifically identify the most problematic organic fragments in complexant-containing waste and provide the basis for developing successful treatment strategies for these wastes. This report summarizes work carried out at Los Alamos during the first 8 months of a 3-year project.'

Active waste disposal monitoring at the Radioactive Waste Management Complex, Idaho National Engineering Laboratory

International Nuclear Information System (INIS)

Hubbell, J.M.

1990-10-01

This report describes an active waste disposal monitoring system proposed to be installed beneath the low-level radioactive disposal site at the Radioactive Waste Management Complex (RWMC), Idaho National Engineering Laboratory, Idaho. The monitoring instruments will be installed while the waste is being disposed. Instruments will be located adjacent to and immediately beneath the disposal area within the unsaturated zone to provide early warning of contaminant movement before contaminants reach the Snake River Plain Aquifer. This study determined the optimum sampling techniques using existing monitoring equipment. Monitoring devices were chosen that provide long-term data for moisture content, movement of gamma-emitting nuclides, and gas concentrations in the waste. The devices will allow leachate collection, pore-water collection, collection of gasses, and access for drilling through and beneath the waste at a later time. The optimum monitoring design includes gas sampling devices above, within, and below the waste. Samples will be collected for methane, tritium, carbon dioxide, oxygen, and volatile organic compounds. Access tubes will be utilized to define the redistribution of radionuclides within, above, and below the waste over time and to define moisture content changes within the waste using spectral and neutron logging, respectively. Tracers will be placed within the cover material and within waste containers to estimate transport times by conservative chemical tracers. Monitoring the vadose zone below, within, and adjacent to waste while it is being buried is a viable monitoring option. 12 refs., 16 figs., 1 tab

Production of steam cracking feedstocks by mild cracking of plastic wastes

Energy Technology Data Exchange (ETDEWEB)

Angyal, Andras; Miskolczi, Norbert; Bartha, Laszlo; Tungler, Antal; Nagy, Lajos; Vida, Laszlo; Nagy, Gabor

2010-11-15

In this work the utility of new possible petrochemical feedstocks obtained by plastic waste cracking has been studied. The cracking process of polyethylene (PE), polyethylene-polypropylene (PEPP) and polyethylene-polystyrene (PEPS) has been carried out in a pilot scale tubular reactor. In this process mild reaction parameters has been applied, with the temperature of 530 C and the residence time of 15 min. The produced hydrocarbon fractions as light- and middle distillates were tested by using a laboratory steam cracking unit. It was concluded that the products of the mild cracking of plastic wastes could be applied as petrochemical feedstocks. Based on the analytical data it was determined that these liquid products contained in significant concentration (25-50 wt.%) of olefin hydrocarbons. Moreover the cracking of polystyrene containing raw material resulted in liquid products with significant amounts of aromatic hydrocarbons too. The steam cracking experiments proved that the products obtained by PE and PEPP cracking resulted in similar or better ethylene and propylene yields than the reference samples, however the aromatic content of PEPS products reduced the ethylene and propylene yields. (author)

Characteristics of Occupational Exposure to Benzene during Turnaround in the Petrochemical Industries.

Science.gov (United States)

Chung, Eun-Kyo; Shin, Jung-Ah; Lee, Byung-Kyu; Kwon, Jiwoon; Lee, Naroo; Chung, Kwang-Jae; Lee, Jong-Han; Lee, In-Seop; Kang, Seong-Kyu; Jang, Jae-Kil

2010-09-01

The level of benzene exposure in the petrochemical industry during regular operation has been well established, but not in turnaround (TA), where high exposure may occur. In this study, the characteristics of occupational exposure to benzene during TA in the petrochemical companies were investigated in order to determine the best management strategies and improve the working environment. This was accomplished by evaluating the exposure level for the workers working in environments where benzene was being produced or used as an ingredient during the unit process. From 2003 to 2008, a total of 705 workers in three petrochemical companies in Korea were studied. Long- and short-term (< 1 hr) samples were taken during TAs. TA was classified into three stages: shut-down, maintenance and start-up. All works were classified into 12 occupation categories. The long-term geometric mean (GM) benzene exposure level was 0.025 (5.82) ppm (0.005-42.120 ppm) and the short-term exposure concentration during TA was 0.020 (17.42) ppm (0.005-61.855 ppm). The proportions of TA samples exceeding the time-weighted average, occupational exposure level (TWA-OEL in Korea, 1 ppm) and the short-term exposure limit (STEL-OEL, 5 ppm) were 4.1% (20 samples of 488) and 6.0% (13 samples of 217), respectively. The results for the benzene exposure levels and the rates of exceeding the OEL were both statistically significant (p < 0.05). Among the 12 job categories of petrochemical workers, mechanical engineers, plumbers, welders, fieldman and scaffolding workers exhibited long-term samples that exceeded the OEL of benzene, and the rate of exceeding the OEL was statistically significant for the first two occupations (p < 0.05). These findings suggest that the periodic work environment must be assessed during non-routine works such as TA.

Green Chemistry, Green Engineering and Eco-Innovation Towards a More Sustainable Petrochemical Industry: Determinants of Brazilian Petrochemical Companies´ Engagement in GCE-Based Eco-Innovation Processes

NARCIS (Netherlands)

P.A. Freire da Silva (Paulo)

2014-01-01

markdownabstract__Abstract__ It is the general wisdom, within the petrochemical industrial sector, that technological changes, for the development of cleaner products, processes and services, is a basic requirement for companies to achieve advanced states of environmental and

Solid waste management complex site development plan

International Nuclear Information System (INIS)

Greager, T.M.

1994-01-01

The main purpose of this Solid Waste Management Complex Site Development Plan is to optimize the location of future solid waste treatment and storage facilities and the infrastructure required to support them. An overall site plan is recommended. Further, a series of layouts are included that depict site conditions as facilities are constructed at the SWMC site. In this respect the report serves not only as the siting basis for future projects, but provides siting guidance for Project W-112, as well. The plan is intended to function as a template for expected growth of the site over the next 30 years so that future facilities and infrastructure will be properly integrated

Solid waste management complex site development plan

Energy Technology Data Exchange (ETDEWEB)

Greager, T.M.

1994-09-30

The main purpose of this Solid Waste Management Complex Site Development Plan is to optimize the location of future solid waste treatment and storage facilities and the infrastructure required to support them. An overall site plan is recommended. Further, a series of layouts are included that depict site conditions as facilities are constructed at the SWMC site. In this respect the report serves not only as the siting basis for future projects, but provides siting guidance for Project W-112, as well. The plan is intended to function as a template for expected growth of the site over the next 30 years so that future facilities and infrastructure will be properly integrated.

Environmental surveillance report for the INEL radioactive waste management complex. Annual report, 1976

International Nuclear Information System (INIS)

Dolenc, M.R.; Janke, D.H.

1977-05-01

This report describes the environmental surveillance activities during 1976 at the two solid waste facilities of the Idaho National Engineering Laboratory. The monitoring program encompasses periodic and random sampling of air, water, and soil within and adjacent to the Radioactive Waste Management Complex and SL-1 Burial Ground. It was found that operation of the Radioactive Waste Management Complex and SL-1 during 1976 had little radiological impact on the environment and radioactivity levels were shown to be within appropriate guidelines for worker safety

Analysis of the matrix structure of the Nuclear Weapons Complex waste minimization and hazard reduction program

International Nuclear Information System (INIS)

Churnetski, S.R.

1991-01-01

Two of the primary goals of this program in waste minimization that the major waste problems facing the Nuclear Weapons Complex (NWC) are being addressed systematically and to prevent duplication of effort by forming an integrated approach across the complex. Production, disposal, and the hazards of both the wastes and the in-process chemicals used were to be studied. The eight waste streams chosen (electroplating, miscellaneous, mixed, plutonium, polymers, solvents, tritium, and uranium) were deemed to be the most serious problems facing the Nuclear Weapons Complex

The Impact of Job Stress and Job Satisfaction on Workforce Productivity in an Iranian Petrochemical Industry

OpenAIRE

Hoboubi, Naser; Choobineh, Alireza; Kamari Ghanavati, Fatemeh; Keshavarzi, Sareh; Akbar Hosseini, Ali

2016-01-01

Background: Job stress and job satisfaction are important factors affecting workforce productivity. This study was carried out to investigate the job stress, job satisfaction, and workforce productivity levels, to examine the effects of job stress and job satisfaction on workforce productivity, and to identify factors associated with productivity decrement among employees of an Iranian petrochemical industry. Methods: In this study, 125 randomly selected employees of an Iranian petrochemic...

Health effects of people living close to a petrochemical industrial estate in Thailand.

Science.gov (United States)

Kongtip, Pornpimol; Singkaew, Panawadee; Yoosook, Witaya; Chantanakul, Suttinun; Sujiratat, Dusit

2013-12-01

An acute health effect of people living near the petrochemical industrial estate in Thailand was assessed using a panel study design. The populations in communities near the petrochemical industrial estates were recruited. The daily air pollutant concentrations, daily percentage of respiratory and other health symptoms reported were collected for 63 days. The effect of air pollutants to reported symptoms of people were estimated by adjusted odds ratios and 95% confidence interval using binary logistic regression. The significant associations were found with the adjusted odds ratios of 38.01 for wheezing, 18.63 for shortness of breath, 4.30 for eye irritation and 3.58 for dizziness for total volatile organic compounds (Total VOCs). The adjusted odds ratio for carbon monoxide (CO2) was 7.71 for cough, 4.55 for eye irritation and 3.53 for weakness and the adjusted odds ratio for ozone (O3) was 1.02 for nose congestion, sore throat and 1.05 for phlegm. The results showed that the people living near petrochemical industrial estate had acute adverse health effects, shortness of breath, eye irritation, dizziness, cough, nose congestion, sore throat, phlegm and weakness from exposure to industrial air pollutants.

Radioactive waste management complex low-level waste radiological composite analysis

Energy Technology Data Exchange (ETDEWEB)

McCarthy, J.M.; Becker, B.H.; Magnuson, S.O.; Keck, K.N.; Honeycutt, T.K.

1998-05-01

The composite analysis estimates the projected cumulative impacts to future members of the public from the disposal of low-level radioactive waste (LLW) at the Idaho National Engineering and Environmental Laboratory (INEEL) Radioactive Waste Management Complex (RWMC) and all other sources of radioactive contamination at the INEEL that could interact with the LLW disposal facility to affect the radiological dose. Based upon the composite analysis evaluation, waste buried in the Subsurface Disposal Area (SDA) at the RWMC is the only source at the INEEL that will significantly interact with the LLW facility. The source term used in the composite analysis consists of all historical SDA subsurface disposals of radionuclides as well as the authorized LLW subsurface disposal inventory and projected LLW subsurface disposal inventory. Exposure scenarios evaluated in the composite analysis include all the all-pathways and groundwater protection scenarios. The projected dose of 58 mrem/yr exceeds the composite analysis guidance dose constraint of 30 mrem/yr; therefore, an options analysis was conducted to determine the feasibility of reducing the projected annual dose. Three options for creating such a reduction were considered: (1) lowering infiltration of precipitation through the waste by providing a better cover, (2) maintaining control over the RWMC and portions of the INEEL indefinitely, and (3) extending the period of institutional control beyond the 100 years assumed in the composite analysis. Of the three options investigated, maintaining control over the RWMC and a small part of the present INEEL appears to be feasible and cost effective.

Radioactive waste management complex low-level waste radiological composite analysis

International Nuclear Information System (INIS)

McCarthy, J.M.; Becker, B.H.; Magnuson, S.O.; Keck, K.N.; Honeycutt, T.K.

1998-05-01

The composite analysis estimates the projected cumulative impacts to future members of the public from the disposal of low-level radioactive waste (LLW) at the Idaho National Engineering and Environmental Laboratory (INEEL) Radioactive Waste Management Complex (RWMC) and all other sources of radioactive contamination at the INEEL that could interact with the LLW disposal facility to affect the radiological dose. Based upon the composite analysis evaluation, waste buried in the Subsurface Disposal Area (SDA) at the RWMC is the only source at the INEEL that will significantly interact with the LLW facility. The source term used in the composite analysis consists of all historical SDA subsurface disposals of radionuclides as well as the authorized LLW subsurface disposal inventory and projected LLW subsurface disposal inventory. Exposure scenarios evaluated in the composite analysis include all the all-pathways and groundwater protection scenarios. The projected dose of 58 mrem/yr exceeds the composite analysis guidance dose constraint of 30 mrem/yr; therefore, an options analysis was conducted to determine the feasibility of reducing the projected annual dose. Three options for creating such a reduction were considered: (1) lowering infiltration of precipitation through the waste by providing a better cover, (2) maintaining control over the RWMC and portions of the INEEL indefinitely, and (3) extending the period of institutional control beyond the 100 years assumed in the composite analysis. Of the three options investigated, maintaining control over the RWMC and a small part of the present INEEL appears to be feasible and cost effective

Identification, classification and management of industrial waste in Kavir steel complex according to the Bazel convention and RCRA

Directory of Open Access Journals (Sweden)

Mohammad Hasan Ehrampoush

2016-06-01

Full Text Available Introduction: Requiring industries for implementing industrial waste management programs and planning for proper waste disposal is essential in order to achieve sustainable development. Therefore, industrial waste management program was done in Kavir Steel Complex, in Aran va Bidgol region to identify and classify industrial waste and also to present solutions for improving waste management. In this complex, production process is hot rolling steel and the product is rebar. Material and Method: The preset study was conducted in Kavir Steel Complex. Following survey of production process and sources of waste, the type and volume of produced waste were identified and measured during 3 months. Then, the classification of wastes was done according to the Bazel Convention and Resource Conservation and Recovery Act (RCRA, and finally new industrial & health solid waste management program was presented. Result: Considering the volume, industrial waste of production process in Kavir Steel Complex was between 130 to 180 grams per each ton of rebar. Main industrial waste included oxide of steel billet, industrial sludge, used oil and lubricant which were classified according to the RCRA: 8 materials with T code, 1 with C code, 5 with I code and 3 materials with C code. Conclusion: The results revealed that the most amount of industrial waste in Kavir Steel Complex is the waste of steel billet and industrial sludge, and more than 90% of Kavir steel industrial waste were reused and recycled inside or outside of this complex. It is recommended that used oil to be transport and maintain in the safe containers.

Screening tests for hazard classification of complex waste materials – Selection of methods

International Nuclear Information System (INIS)

Weltens, R.; Vanermen, G.; Tirez, K.; Robbens, J.; Deprez, K.; Michiels, L.

2012-01-01

In this study we describe the development of an alternative methodology for hazard characterization of waste materials. Such an alternative methodology for hazard assessment of complex waste materials is urgently needed, because the lack of a validated instrument leads to arbitrary hazard classification of such complex waste materials. False classification can lead to human and environmental health risks and also has important financial consequences for the waste owner. The Hazardous Waste Directive (HWD) describes the methodology for hazard classification of waste materials. For mirror entries the HWD classification is based upon the hazardous properties (H1–15) of the waste which can be assessed from the hazardous properties of individual identified waste compounds or – if not all compounds are identified – from test results of hazard assessment tests performed on the waste material itself. For the latter the HWD recommends toxicity tests that were initially designed for risk assessment of chemicals in consumer products (pharmaceuticals, cosmetics, biocides, food, etc.). These tests (often using mammals) are not designed nor suitable for the hazard characterization of waste materials. With the present study we want to contribute to the development of an alternative and transparent test strategy for hazard assessment of complex wastes that is in line with the HWD principles for waste classification. It is necessary to cope with this important shortcoming in hazardous waste classification and to demonstrate that alternative methods are available that can be used for hazard assessment of waste materials. Next, by describing the pros and cons of the available methods, and by identifying the needs for additional or further development of test methods, we hope to stimulate research efforts and development in this direction. In this paper we describe promising techniques and argument on the test selection for the pilot study that we have performed on different

Central Waste Complex (CWC) essential/support drawing list

International Nuclear Information System (INIS)

WHITLOCK, R.W.

1999-01-01

Essential and supporting engineering drawings for the Central Waste Complex (CWC) are identified in this document. The purpose of the document is to describe the criteria used to identify drawings and the plan for updating and maintaining their accuracy. This document supports HNF-PRO-242 and HNF-PRO-440

Environmental compliance in the petrochemical industry in the Sarnia area

Energy Technology Data Exchange (ETDEWEB)

NONE

2005-04-01

In February 2004, the Ontario Ministry of the Environment directed its Environmental SWAT Team to conduct a comprehensive inspection sweep of Sarnia's industrial sector to ensure that all facilities in that region were brought into compliance with environmental legislation. The primary focus was to inspect areas with the potential for future spills or unlawful discharges that could pose risks to human health or the environment. Legislative and regulatory gaps that could allow environmentally unsafe practices to exist at the facilities were also revealed. The inspection sweep involved comprehensive inspections of 35 petrochemical plant's air emissions, water discharges and spill prevention plans. SWAT officers examined waste management, laboratory operations and other areas that must meet environmental legislative requirements. Nearly all of the of facilities inspected during the sweep were found to be in non-compliance with one or more legislative or regulatory requirement. Common deficiencies included: no spill contingency or spill prevention plans; not having a Certificate of Approval for wastewater collection and treatment works or air emission control equipment; altering equipment, systems, processes, or structure contrary to the existing Certificate of Approval; and improper chemical handling, storage and identification. As a result of the inspection, 6 facilities were ordered to develop both a spill prevention plan and a spill contingency plan and 2 facilities were ordered to develop a spill prevention plan. SWAT officers have followed up to ensure that companies have taken appropriate corrective actions. The inspection revealed some of the sound practices undertaken at some facilities, such as containment; monitoring; prevention of discharge of contaminants to air or water; waste water and storm water treatment; contingency planning; and process hazard analysis of all key processes. refs., tabs., figs.

An application of failure mode and effect analysis (FMEA to assess risks in petrochemical industry in Iran

Directory of Open Access Journals (Sweden)

Mehdi Kangavari

2015-06-01

Full Text Available Petrochemical industries have a high rate of accidents. Failure mode and effect analysis (FMEA is a systematic method and thus is capable of analyzing the risks of systems from concept phase to system disposal, detecting the failures in design stage, and determining the control measures and corrective actions for failures to reduce their impacts. The objectives of this research were to perform FMEA to identify risks in an Iranian petrochemical industry and determine the decrease of the risk priority number (RPN after implementation of intervention programs. This interventional study was performed at one petrochemical plant in Tehran, Iran in 2014. Relevant information about job categories and plant process was gathered using brainstorming techniques, fishbone diagram, and group decision making. The data were collected through interviews, observation, and documents investigations and was recorded in FMEA worksheets. The necessary corrective measures were performed on the basis of the results of initial FMEA. Forty eight failures were identified in welding unit by application of FMEA to assess risks. Welding processes especially working at height got the highest RPN. Obtained RPN for working at height before performing the corrective actions was 120 and the score was reduced to 96 after performing corrective measures. Calculated RPN for all processes was significantly reduced (p≤0.001 by implementing the corrective actions. Scores of RPN in all studied processes effectively decreased after performing corrective actions in a petrochemical industry. FMEA method is a useful tool for identifying risk intervention priorities and effectiveness in a studied petrochemical industry.

PROTECTIVE TREATMENT OF WOOD IMPREGNATING COMPOSITION OF PETROCHEMICAL WASTE

Directory of Open Access Journals (Sweden)

T. V. Maslakova

2015-01-01

Full Text Available The paper presents results of experimental and theoretical studies aimed at expanding the applications of the copolymers on the basis of the waste styrene production. One of the areas is used as impregnating compositions of wood materials, selection of optimal conditions modification on samples of the most widely used in the industry of wood, such as birch, aspen and other. Studies were conducted to obtain and use an impregnating compositions based on copolymers synthesized from waste products of styrene and the cubic remainder rectification of ethylbenzene (CRRE for the protective treatment of birch wood. Identified physic-chemical characteristics of physical mixtures of copolymers «CORS», «STAM», CRRE at different ratios. Studied the process of modification birch using the method of experiment planning greco-latin square of the fourth order, and the influence of such factors as the temperature of the impregnating composition, the duration of the impregnation, the temperature and duration of thermal treatment on the performance moisture resistance of wood. Were established optimal conditions modification birch wood treated impregnating compositions on the basis of physical mixtures of copolymer «CORS» with CRRE and copolymer «STAM» with CRRE is the mixing ratio 2:1, the duration and temperature of the impregnation 7 h and 95 0C, time and temperature of heat treatment 7 h and 170 0C, respectively. A sealing composition containing CRRE with copolymer «STAM» 1:2 is more preferable, as in the structure of the copolymer «STAM» contains carboxyl and anhydrite group. Thus was justified use for the modification of natural wood impregnating compositions on the basis of physical mixtures of CRRE with copolymers «CORS» and «STAM», which improve the properties of wood, increase moisture and weather resistance more than twice.

Use of Low-cost Adsorbents to Chlorophenols and Organic Matter Removal of Petrochemical Wastewater

Directory of Open Access Journals (Sweden)

Aretha Moreira de Oliveira

2013-11-01

Full Text Available The removal of 2,4 diclorophenol (2,4-DCF and 2,4,6 trichlorophenol (2,4,6 TCF present in  petrochemical wastewater was evaluated using low-cost adsorbents, such as chitin, chitosan and coconut shells. Batch studies showed that the absorption efficiency for 2,4 DCF and 2,4,6 TCF follow the order: chitosan > chitin > coconut shells. Langmuir and Freundlich models have been applied to experimental isotherms data, to better understand the adsorption mechanisms. Petrochemical wastewater treatment with fixed bed column system using chitinous adsorbents showed a removal of COD (75% , TOG (90% and turbidity (74-89%.

Using atomic energy in the oil refining and petrochemical industry

Energy Technology Data Exchange (ETDEWEB)

Feigin, E.A.; Barashkov, R.Ia.; Raud, E.A.

1982-01-01

A short description of the basic large scale processes for oil refining and petrochemistry in which nuclear reactors can be used is given. The possible industrial plans for using nuclear reactors are examined together with the problems in using the advances in atomic technology in oil refining and petrochemical processes.

[Study on the quantitative estimation method for VOCs emission from petrochemical storage tanks based on tanks 4.0.9d model].

Science.gov (United States)

Li, Jing; Wang, Min-Yan; Zhang, Jian; He, Wan-Qing; Nie, Lei; Shao, Xia

2013-12-01

VOCs emission from petrochemical storage tanks is one of the important emission sources in the petrochemical industry. In order to find out the VOCs emission amount of petrochemical storage tanks, Tanks 4.0.9d model is utilized to calculate the VOCs emission from different kinds of storage tanks. VOCs emissions from a horizontal tank, a vertical fixed roof tank, an internal floating roof tank and an external floating roof tank were calculated as an example. The consideration of the site meteorological information, the sealing information, the tank content information and unit conversion by using Tanks 4.0.9d model in China was also discussed. Tanks 4.0.9d model can be used to estimate VOCs emissions from petrochemical storage tanks in China as a simple and highly accurate method.

Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples

International Nuclear Information System (INIS)

Thorson, Megan K.; Ung, Phuc; Leaver, Franklin M.; Corbin, Teresa S.; Tuck, Kellie L.; Graham, Bim; Barrios, Amy M.

2015-01-01

A series of lanthanide-based, azide-appended complexes were investigated as hydrogen sulfide-sensitive probes. Europium complex 1 and Tb complex 3 both displayed a sulfide-dependent increase in luminescence, while Tb complex 2 displayed a decrease in luminescence upon exposure to NaHS. The utility of the complexes for monitoring sulfide levels in industrial oil and water samples was investigated. Complex 3 provided a sensitive measure of sulfide levels in petrochemical water samples (detection limit ∼ 250 nM), while complex 1 was capable of monitoring μM levels of sulfide in partially refined crude oil. - Highlights: • Lanthanide–azide based sulfide sensors were synthesized and characterized. • The probes have excitation and emission profiles compatible with sulfide-contaminated samples from the petrochemical industry. • A terbium-based probe was used to measure the sulfide concentration in oil refinery wastewater. • A europium-based probe had compatibility with partially refined crude oil samples.

Lanthanide complexes as luminogenic probes to measure sulfide levels in industrial samples

Energy Technology Data Exchange (ETDEWEB)

Thorson, Megan K. [Department of Medicinal Chemistry, University of Utah College of Pharmacy, Salt Lake City, UT 84108 (United States); Ung, Phuc [Monash Institute of Pharmaceutical Sciences, Monash University, Victoria 3052 (Australia); Leaver, Franklin M. [Water & Energy Systems Technology, Inc., Kaysville, UT 84037 (United States); Corbin, Teresa S. [Quality Services Laboratory, Tesoro Refining and Marketing, Salt Lake City, UT 84103 (United States); Tuck, Kellie L., E-mail: kellie.tuck@monash.edu [School of Chemistry, Monash University, Victoria 3800 (Australia); Graham, Bim, E-mail: bim.graham@monash.edu [Monash Institute of Pharmaceutical Sciences, Monash University, Victoria 3052 (Australia); Barrios, Amy M., E-mail: amy.barrios@utah.edu [Department of Medicinal Chemistry, University of Utah College of Pharmacy, Salt Lake City, UT 84108 (United States)

2015-10-08

A series of lanthanide-based, azide-appended complexes were investigated as hydrogen sulfide-sensitive probes. Europium complex 1 and Tb complex 3 both displayed a sulfide-dependent increase in luminescence, while Tb complex 2 displayed a decrease in luminescence upon exposure to NaHS. The utility of the complexes for monitoring sulfide levels in industrial oil and water samples was investigated. Complex 3 provided a sensitive measure of sulfide levels in petrochemical water samples (detection limit ∼ 250 nM), while complex 1 was capable of monitoring μM levels of sulfide in partially refined crude oil. - Highlights: • Lanthanide–azide based sulfide sensors were synthesized and characterized. • The probes have excitation and emission profiles compatible with sulfide-contaminated samples from the petrochemical industry. • A terbium-based probe was used to measure the sulfide concentration in oil refinery wastewater. • A europium-based probe had compatibility with partially refined crude oil samples.

Dual application of duckweed and azolla plants for wastewater treatment and renewable fuels and petrochemicals production.

Science.gov (United States)

Muradov, Nazim; Taha, Mohamed; Miranda, Ana F; Kadali, Krishna; Gujar, Amit; Rochfort, Simone; Stevenson, Trevor; Ball, Andrew S; Mouradov, Aidyn

2014-02-28

Shortages in fresh water supplies today affects more than 1 billion people worldwide. Phytoremediation strategies, based on the abilities of aquatic plants to recycle nutrients offer an attractive solution for the bioremediation of water pollution and represents one of the most globally researched issues. The subsequent application of the biomass from the remediation for the production of fuels and petrochemicals offers an ecologically friendly and cost-effective solution for water pollution problems and production of value-added products. In this paper, the feasibility of the dual application of duckweed and azolla aquatic plants for wastewater treatment and production of renewable fuels and petrochemicals is explored. The differences in absorption rates of the key wastewater nutrients, ammonium and phosphorus by these aquatic macrophytes were used as the basis for optimization of the composition of wastewater effluents. Analysis of pyrolysis products showed that azolla and algae produce a similar range of bio-oils that contain a large spectrum of petrochemicals including straight-chain C10-C21 alkanes, which can be directly used as diesel fuel supplement, or a glycerin-free component of biodiesel. Pyrolysis of duckweed produces a different range of bio-oil components that can potentially be used for the production of "green" gasoline and diesel fuel using existing techniques, such as catalytic hydrodeoxygenation. Differences in absorption rates of the key wastewater nutrients, ammonium and phosphorus by different aquatic macrophytes can be used for optimization of composition of wastewater effluents. The generated data suggest that the composition of the petrochemicals can be modified in a targeted fashion, not only by using different species, but also by changing the source plants' metabolic profile, by exposing them to different abiotic or biotic stresses. This study presents an attractive, ecologically friendly and cost-effective solution for efficient bio

Dual application of duckweed and azolla plants for wastewater treatment and renewable fuels and petrochemicals production

Science.gov (United States)

2014-01-01

Background Shortages in fresh water supplies today affects more than 1 billion people worldwide. Phytoremediation strategies, based on the abilities of aquatic plants to recycle nutrients offer an attractive solution for the bioremediation of water pollution and represents one of the most globally researched issues. The subsequent application of the biomass from the remediation for the production of fuels and petrochemicals offers an ecologically friendly and cost-effective solution for water pollution problems and production of value-added products. Results In this paper, the feasibility of the dual application of duckweed and azolla aquatic plants for wastewater treatment and production of renewable fuels and petrochemicals is explored. The differences in absorption rates of the key wastewater nutrients, ammonium and phosphorus by these aquatic macrophytes were used as the basis for optimization of the composition of wastewater effluents. Analysis of pyrolysis products showed that azolla and algae produce a similar range of bio-oils that contain a large spectrum of petrochemicals including straight-chain C10-C21 alkanes, which can be directly used as diesel fuel supplement, or a glycerin-free component of biodiesel. Pyrolysis of duckweed produces a different range of bio-oil components that can potentially be used for the production of “green” gasoline and diesel fuel using existing techniques, such as catalytic hydrodeoxygenation. Conclusions Differences in absorption rates of the key wastewater nutrients, ammonium and phosphorus by different aquatic macrophytes can be used for optimization of composition of wastewater effluents. The generated data suggest that the composition of the petrochemicals can be modified in a targeted fashion, not only by using different species, but also by changing the source plants’ metabolic profile, by exposing them to different abiotic or biotic stresses. This study presents an attractive, ecologically friendly and cost

Trends in high performance compressors for petrochemical and natural gas industry in China

Science.gov (United States)

Zhao, Yuanyang; Li, Liansheng

2015-08-01

Compressors are the key equipment in the petrochemical and natural gas industry system. The performance and reliability of them are very important for the process system. The application status of petrochemical & natural gas compressors in China is presented in this paper. The present status of design and operating technologies of compressors in China are mentioned in this paper. The turbo, reciprocating and twin screw compressors are discussed. The market demands for different structure compressors in process gas industries are analysed. This paper also introduces the research and developments for high performance compressors in China. The recent research results on efficiency improvement methods, stability improvement, online monitor and fault diagnosis will also be presented in details.

A brief analysis and description of transuranic wastes in the Subsurface Disposal Area of the radioactive waste management complex at INEL

International Nuclear Information System (INIS)

Arrenholz, D.A.; Knight, J.L.

1991-08-01

This document presents a brief summary of the wastes and waste types disposed of in the transuranic contaminated portions of the Subsurface Disposal Area of the radioactive waste management complex at Idaho National Engineering Laboratory from 1954 through 1970. Wastes included in this summary are organics, inorganics, metals, radionuclides, and atypical wastes. In addition to summarizing amounts of wastes disposed and describing the wastes, the document also provides information on disposal pit and trench dimensions and contaminated soil volumes. The report also points out discrepancies that exist in available documentation regarding waste and soil volumes and make recommendations for future efforts at waste characterization. 19 refs., 3 figs., 17 tabs

A brief analysis and description of transuranic wastes in the Subsurface Disposal Area of the radioactive waste management complex at INEL

Energy Technology Data Exchange (ETDEWEB)

Arrenholz, D.A.; Knight, J.L.

1991-08-01

This document presents a brief summary of the wastes and waste types disposed of in the transuranic contaminated portions of the Subsurface Disposal Area of the radioactive waste management complex at Idaho National Engineering Laboratory from 1954 through 1970. Wastes included in this summary are organics, inorganics, metals, radionuclides, and atypical wastes. In addition to summarizing amounts of wastes disposed and describing the wastes, the document also provides information on disposal pit and trench dimensions and contaminated soil volumes. The report also points out discrepancies that exist in available documentation regarding waste and soil volumes and make recommendations for future efforts at waste characterization. 19 refs., 3 figs., 17 tabs.

Education in petrochemical industry as prevention from chemical terrorism

International Nuclear Information System (INIS)

Mesaric, B.; Habek, R.; Loncarevic, M.

2009-01-01

Technical and technological accidents in petrochemical industry, with possible catastrophic consequences, caused by anthropogenic activity (technical or technological malfunction, terror, or war destruction ), usually accompanied by great human losses and material damage and high intensity of events in a relatively short period of time, which requires a quick action of emergency responders, process personnel and the high degree of self-organized endangered population for treatment in these kind of accidents. This implies a high qualification and skills for the treatment of accidents of all factors of rescue and protection such as: process personnel, emergency responders (fire-fighters, technical services), other workers as well as the endangered population. Managing the system of protection and rescue in communities with such risks requires maximum responsibility of local authorities and management of petrochemical plants. Petrokemija Kutina, with its many years of experience as a target for military and terrorist attacks, actively participated in the creation of laws and systems of protection and rescue in the Republic of Croatia, and also in creating standard operating procedures on local and regional level, and is also ready to share its own experiences with other similar factories using toxic substances in the production processes.(author)

Radioactive Waste Management Complex performance assessment: Draft

Energy Technology Data Exchange (ETDEWEB)

Case, M.J.; Maheras, S.J.; McKenzie-Carter, M.A.; Sussman, M.E.; Voilleque, P.

1990-06-01

A radiological performance assessment of the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory was conducted to demonstrate compliance with appropriate radiological criteria of the US Department of Energy and the US Environmental Protection Agency for protection of the general public. The calculations involved modeling the transport of radionuclides from buried waste, to surface soil and subsurface media, and eventually to members of the general public via air, ground water, and food chain pathways. Projections of doses were made for both offsite receptors and individuals intruding onto the site after closure. In addition, uncertainty analyses were performed. Results of calculations made using nominal data indicate that the radiological doses will be below appropriate radiological criteria throughout operations and after closure of the facility. Recommendations were made for future performance assessment calculations.

Radioactive Waste Management Complex performance assessment: Draft

International Nuclear Information System (INIS)

Case, M.J.; Maheras, S.J.; McKenzie-Carter, M.A.; Sussman, M.E.; Voilleque, P.

1990-06-01

A radiological performance assessment of the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory was conducted to demonstrate compliance with appropriate radiological criteria of the US Department of Energy and the US Environmental Protection Agency for protection of the general public. The calculations involved modeling the transport of radionuclides from buried waste, to surface soil and subsurface media, and eventually to members of the general public via air, ground water, and food chain pathways. Projections of doses were made for both offsite receptors and individuals intruding onto the site after closure. In addition, uncertainty analyses were performed. Results of calculations made using nominal data indicate that the radiological doses will be below appropriate radiological criteria throughout operations and after closure of the facility. Recommendations were made for future performance assessment calculations

DE based economic control chart design and application for a typical petrochemical process

Institute of Scientific and Technical Information of China (English)

Zhi LI; Feng QIAN; Wenli DU; Weimin ZHONG

2017-01-01

Petrochemical industry plays an important role in the development of the national economy.Purified terephthalic acid (PTA) is one of the most important intermediate raw materials in the petrochemical and chemical fiber industries.PTA production has two parts:p-xylene (PX) oxidation process and crude terephthalic acid (CTA) hydropurification process.The CTA hydropurification process is used to reduce impurities,such as 4-carboxybenzaldehyde,which is produced by a side reaction in the PX oxidation process and is harmful to the polyester industry.From the safety and economic viewpoints,monitoring this process is necessary.Four main faults of this process are analyzed in this study.The common process monitoring methods always use T2 and SPE statistic as control limits.However,the traditional methods do not fully consider the economic viewpoint.In this study,a new economic control chart design method based on the differential evolution (DE) algorithm is developed.The DE algorithm transforms the economic control chart design problem to an optimization problem and is an excellent solution to such problem.Case studies of the main faults of the hydropurification process indicate that the proposed method can achieve minimum profit loss.This method is useful in economic control chart design and can provide guidance for the petrochemical industry.

Corrosion Assessment by Using Risk-Based Inspection Method for Petrochemical Plant - Practical Experience

International Nuclear Information System (INIS)

Choi, Song Chun; Song, Ki Hun

2009-01-01

Corrosion assessment has a number of uses but the use considered here is as a precursor to Risk-Based Inspection (RBI) planning. Systematic methods consisting of technical modules of RBI program were used to assess the effect of specific corrosion mechanism on the probability of failure in equipment of petrochemical plants. Especially in part of the damage and corrosion assessment, screening step involved evaluating the combinations of process conditions and construction materials for each equipment item in order to determine which damage mechanisms are potentially active. For general internal corrosion, either API 510 or API 570 was applied as the damage rate in the calculation to determine the remaining life and inspection frequency. In some cases, a measured rate of corrosion may not be available. The technical modules of RBI program employ default values for corrosion, typically derived from published data or from experience with similar processes, for use until inspection results are available. This paper describes the case study of corrosion and damage assessment by using RBI methodology in petrochemical plant. Specifically, this paper reports the methodology and the results of its application to the petrochemical units using the KGS-RBI TM program, developed by the Korea Gas Safety Corporation to suit Korean situation in conformity with API 581 Codes

Wastewater quality control at Sarnia (Ontario, Canada) petrochemical industries

Energy Technology Data Exchange (ETDEWEB)

Vianna, Arlinda C [Servico Nacional de Aprendizagem Industrial (SENAI), Salvador, BA (Brazil); Souza, Eliane S; Himmelman, William [Lambton College, Sarnia, ON (Canada)

1994-12-31

Ontario industries are required by law to meet strict regulations under the provinces under MISA initiative (Municipal-Industrial Strategy for Abatement). The petroleum-petrochemical area was selected as a leader in the development of new environmental objectives, and monitoring and training programs. Sarnia has become a world leader in industrial environmental control systems and the approach toward zero emissions. 4 refs., 6 figs., 2 tabs.

Wastewater quality control at Sarnia (Ontario, Canada) petrochemical industries

Energy Technology Data Exchange (ETDEWEB)

Vianna, Arlinda C. [Servico Nacional de Aprendizagem Industrial (SENAI), Salvador, BA (Brazil); Souza, Eliane S.; Himmelman, William [Lambton College, Sarnia, ON (Canada)

1993-12-31

Ontario industries are required by law to meet strict regulations under the provinces under MISA initiative (Municipal-Industrial Strategy for Abatement). The petroleum-petrochemical area was selected as a leader in the development of new environmental objectives, and monitoring and training programs. Sarnia has become a world leader in industrial environmental control systems and the approach toward zero emissions. 4 refs., 6 figs., 2 tabs.

The Sarnia complex: synergies and strategies

International Nuclear Information System (INIS)

Heath, M.; Chan, K.S.; Renne, G.; Raggett, C.

1995-01-01

A study was conducted to examine ways in which the oil refiners and petrochemical producers in the Sarnia Complex in Ontario could become more competitive with their counterparts in the United States through joint actions. Methods by which the petroleum industry could meet the challenges posed by changing environmental regulations were proposed. Five suggestions were advanced, i. e., (1) increase pipeline capacity and reduce refining and petrochemical feedstock shipping costs to Ontario, (2) joint ventures in existing or new facilities to produce higher value products, mainly petrochemicals, (3) major joint process integrations involving investment in significant new facilities to meet demand growth and maximize value of the product slate, (4) major joint process integrations to manufacture cleaner fuels, and (5) joint services and utilities integration. Of the joint actions identified by experts, those which were judged to be most plausible and had the greatest profit potential were: further cogeneration, distillate desulfurization, hydrogen production and pipelining, cryogenic recovery of light ends, styrene production and sharing services and utilities.68 refs., 7 tabs., 9 figs

Problems of comprehensive use of waste hydrogen-containing gas in petrochemistry

Energy Technology Data Exchange (ETDEWEB)

Kulikov, V M; Grabovskiy, O G; Yevplanov, A I

1979-01-01

At enterprises of the Ministry of the Petrochemical Industry, gas wastes, containing 60-70% CH/sub 4/ and 25-30% H/sub 2/, are practically completely used as boiler and furnace fuel. The situation is different with gases with a high H/sub 2/ content. Gases containing 70-90% H/sub 2/ are not used, and are emitted into the atmosphere. The gases are not detoxified by burning in torches, and the air basin is polluted by organic compounds contained in these gases that are harmful to people's health. Emitting combustible gases into the atmosphere is the result of fears of burning gases with a high H/sub 2/ content in burners designed to burn gases at a slower flame propagation speed, as well as a low gas pressure and their uneven exit. At the Kuybyshev synthetic alcohol plant, waste gases of the following composition (rounded) are formed: H2, 76; CH4, 8; C2H4, 7; C3H8, 1; CO2, 8%. The gas also contains fractions of a percent of ethane, propane, butylene and butadiene. The lowest combustion heat of 1 cubic meter of gas under normal conditions is 3875 kcal. The gas pressure is 0.2 kg-force/square cm. About 1500 cubic meters of gas form per hour. A hearth fantail burner developed by the Kuybyshev Polytechnical Institute is suggested for burning waste gas. Using waste gases in the petrochemical industry will enable a savings of less than or equal to 60,000 tons of equivalent fuel per year.

Waste Sampling and Characterization Facility (WSCF) Complex Safety Analysis

International Nuclear Information System (INIS)

MELOY, R.T.

2003-01-01

The Waste Sampling and Characterization Facility (WSCF) is an analytical laboratory complex on the Hanford Site that was constructed to perform chemical and low-level radiological analyses on a variety of sample media in support of Hanford Site customer needs. The complex is located in the 600 area of the Hanford Site, east of the 200 West Area. Customers include effluent treatment facilities, waste disposal and storage facilities, and remediation projects. Customers primarily need analysis results for process control and to comply with federal, Washington State, and US. Department of Energy (DOE) environmental or industrial hygiene requirements. This document was prepared to analyze the facility for safety consequences and includes the following steps: Determine radionuclide and highly hazardous chemical inventories; Compare these inventories to the appropriate regulatory limits; Document the compliance status with respect to these limits; and Identify the administrative controls necessary to maintain this status

Proceedings of the CERI 2006 petrochemical conference : thinking outside the box : preparing tomorrow's North American industry

International Nuclear Information System (INIS)

2006-01-01

This conference addressed the global competitiveness of the Canadian petrochemical industry and its potential markets. Recent advances in technology were highlighted along with issues concerning transportation and infrastructure. In addition to addressing capital cost requirements and feedstock availability, the presentations addressed opportunities for growth and product diversification. Alberta's role in the North American energy markets was also discussed, along with issues concerning feedstock from Canadian oil sands. It was noted that the survival of the North American petrochemical industry depends on the price of natural gas liquids. With feedstock at two to three times the price in the Middle East, petrochemical producers, governments, and suppliers need to adopt aggressive strategies to maintain a competitive position and profitability. The sessions of the conference addressed global competitive issues; integration and mastering competitiveness; the Alberta advantage; feedstock and technologies; and, reaching international markets. The conference featured 18 presentations, of which 7 have been catalogued separately for inclusion in this database. refs., tabs., figs

Problems created on delayed supply of feedstock for the HDPE plant of Jam Petrochemical Complex (JPC) in Iran : a case study[The 1. international construction specialty conference

Energy Technology Data Exchange (ETDEWEB)

Etemadzadeh, S.; Mortaheb, M. [Sharif Univ. of Technology, Tehran (Iran, Islamic Republic of). Dept. of Civil Engineering; Beigi, H. [Jam Petrochemical Co., Assaluyeh, Bushehr (Iran, Islamic Republic of)

2006-07-01

The total loss incurred due to delays in supply of feedstock and utilities over the past 2 years during Iran's construction boom in petrochemical plants was evaluated. The problems associated with the delay of feedstock supply and its impact on the final stages of a petrochemical project were discussed and the factors that affect the financial viability of a project were identified. In particular, the paper reviewed issues regarding equipment warranty and their pre-mature expiration; unavoidable rework prior to pre-commissioning; preservation and maintenance cost of equipment in a humid and hot environment; changes in technology and market demands; and, additional fixed costs covering salaries and maintenance costs. Remedial action plans addressing these issues were proposed in order to reduce the costs and any further delays of a project. The importance of technical audits at the feasibility stage of a project was emphasized along with the need to verify the accuracy of initial data for proper design and completion of a project.

Carbonaceous materials in petrochemical wastewater before and after treatment in an aerated submerged fixed-bed biofilm reactor

OpenAIRE

Trojanowicz Karol; Wojcik Wlodzimierz

2016-01-01

Results of the studies for determining fractions of organic contaminants in a pretreated petrochemical wastewater flowing into a pilot Aerated Submerged Fixed-Bed Biofilm Reactor (ASFBBR) are presented and discussed. The method of chemical oxygen demand (COD) fractionation consisted of physical tests and biological assays. It was found that the main part of the total COD in the petrochemical, pretreated wastewater was soluble organic substance with average value of 57.6%. The fractions of par...

Treatment of the oily waste sludges through thermal plasma in absence of oxygen

International Nuclear Information System (INIS)

Castaneda J, G.; Pacheco S, J.

2001-01-01

The thermal plasma process in absence of oxygen for the degradation of oily waste sludges was evaluated. These residues are commonly generated in the petrochemical industry and are considered hazardous wastes according to the present environmental regulations. The process was operated using difference residence times and the characteristics of the gaseous by products and residual soils were determined. The efficiency of organic matter degradation was 99.99%. The attained volume reduction, under the best conditions was 95.5%. The residual soils were composed of carbon and clays. The residual gases have low molecular weight. The resulting final wastes were non-hazardous and could be disposed of in landfills. (Author)

Report: future industrial solid waste management in pars Special Economic Energy Zone (PSEEZ), Iran.

Science.gov (United States)

Mokhtarani, Babak; Moghaddam, Mohammad Reza Alavi; Mokhtarani, Nader; Khaledi, Hossein Jomeh

2006-06-01

The Pars Special Economic Energy Zone (PSEEZ) is located in the south of Iran, on the northern coastline of the Persian Gulf. This area was established in 1998 for the utilization of south Pars field oil and gas resources. This field is one of the largest gas resources in the world and contains about 6% of the total fossil fuels known. Petrochemical industries, gas refineries and downstream industries are being constructed in this area. At present there are three gas refineries in operation and five more gas refineries are under construction. In this study, different types of solid waste including municipal solid waste (MSW) and industrial wastes were investigated separately. The aim of the study was to focus on the management of the industrial wastes in order to minimize the environmental impact. In the first stage, the types and amounts of industrial waste in PSEEZ were evaluated by an inventory. The main types of industrial waste are oil products (fuel oil, light oil, lubricating oil), spent catalysts, adsorbents, resins, coke, wax and packaging materials. The waste management of PSEEZ is quite complex because of the different types of industry and the diversity of industrial residues. In some cases recycling/reuse of waste is the best option, but treatment and disposal are also necessary tools. Recently a design has been prepared for a disposal site in PSEEZ for the industrial waste that cannot be reused or recycled. The total surface area of this disposal site where the industrial waste should be tipped for the next 20 years was estimated to be about 42 000 m2.

Long-lived legacy: Managing high-level and transuranic waste at the DOE Nuclear Weapons Complex. Background paper

International Nuclear Information System (INIS)

1991-05-01

The document focuses on high-level and transuranic waste at the DOE nuclear weapons complex. Reviews some of the critical areas and aspects of the DOE waste problem in order to provide data and further analysis of important issues. Partial contents, High-Level Waste Management at the DOE Weapons Complex, are as follows: High-Level Waste Management: Present and Planned; Amount and Distribution; Current and Potential Problems; Vitrification; Calcination; Alternative Waste Forms for the Idaho National Engineering Laboratory; Technologies for Pretreatment of High-Level Waste; Waste Minimization; Regulatory Framework; Definition of High-Level Waste; Repository Delays and Contingency Planning; Urgency of High-Level Tank Waste Treatment; Technologies for High-Level Waste Treatment; Rethinking the Waste Form and Package; Waste Form for the Idaho National Engineering Laboratory; Releases to the Atmosphere; Future of the PUREX Plant at Hanford; Waste Minimization; Tritium Production; International Cooperation; Scenarios for Future HLW Production. Partial contents of Chapter 2, Managing Transuranic Waste at the DOE Nuclear Weapons Complex, are as follows: Transuranic Waste at Department of Energy Sites; Amount and Distribution; Waste Management: Present and Planned; Current and Potential Problems; Three Technologies for Treating Retrievably Stored Transuranic Waste; In Situ Vitrification; The Applied Research, Development, Demonstration, Testing, and Evaluation Plan (RDDT ampersand E); Actinide Conversion (Transmutation); Waste Minimization; The Regulatory Framework; Definition of, and Standards for, Disposal of Transuranic Waste; Repository Delays; Alternative Storage and Disposal Strategies; Remediation of Buried Waste; The Waste Isolation Pilot Plant; Waste Minimization; Scenarios for Future Transuranic Waste Production; Conditions of No-Migration Determination

B Plant Complex waste management training plan. Revision 1

International Nuclear Information System (INIS)

Beam, T.G.

1994-01-01

This training program is designed to comply with all applicable federal, state and US Department of Energy-Richland Operations Office training requirements. The training program complies with requirements contained within WAC 173-303-330 for the development of a written dangerous waste training program. The training program is designed to prepare personnel to manage and maintain waste treatment, storage and disposal (TSD) units, as well as generator units, in a safe, effective, efficient and environmentally sound manner. In addition to preparing employees to manage and maintain TSD and generator units under normal conditions, the training program ensures that employees are prepared to respond in a prompt and effective manner should an emergency occur. The training plan also identifies specific individuals holding key waste management positions at B Plant Complex

Alternative refining configurations and petrochemical integration in Brazil; Configuracoes alternativas de refino e integracao com petroquimica no Brasil

Energy Technology Data Exchange (ETDEWEB)

Gomes, Gabriel Lourenco [Coordenacao dos Programas de Pos-graduacao em Engenharia (COPPE/UFRJ), RJ (Brazil). Programa de Planejamento Energetico

2008-07-01

This paper presents the results of alternative configurations for a new refinery in Brazil, with the objective of transforming national heavy oils into low sulfur derivatives and petrochemical products, until 2020. The hypothetical refinery proposed has a processing capacity of 10.000 t/year of Marlim heavy oil, through distillation and delayed coking units. Two base cases of conversion units were considered, one with a Fluid Catalytic Cracking - FCC, and another with a Hydro-cracking - HCC. Both cases also have several hydro-treating units to be able to achieve future fuel quality specifications in Brazil and for export. The refinery-petrochemical integration was considered through the use of a petrochemical FCC instead of a conventional FCC, and through the addition of a steam cracking and aromatics separation unit, included as an option to the 3 refinery cases: FCC, HCC, and Petro FCC. All the results were compared in terms of economic return. The best return on investment is obtained in the Petro FCC case. The FCC and HCC cases present lower and similar results for 2006 prices. However, the HCC has the advantage of producing a greater amount of middle distillates, with a higher expected demand growth in Brazil. Finally, the addition of a steam cracking unit reduces the return on investment of the hypothetical refinery for all cases using 2006 prices. However, the return of the petrochemical activity on the same period could still justify this investment, depending on the petrochemicals market evolution. With the steam cracking unit, the Petro FCC and HCC cases present similar returns using 2006 prices. (author)

Dynamic Effects of Tank Waste Aging on Radionuclide-Complexant Interactions - Final Report - 10/01/1997 - 10/01/2000

Energy Technology Data Exchange (ETDEWEB)

Chamberlin, Rebecca M.; Arterburn, Jeffrey B. rmchamberlin@lanl.gov; jarterbu@nmsu.edu

2000-10-01

The long-range objective of this project is to provide a scientific basis for safely processing high-level nuclear tanks wastes for disposal. Our goals are to identify a means to prepare realistic simulant formulations for complexant-containing Hanford tank wastes, and then use those simulants to determine the relative importance of various organic complexants and their breakdown products on the partitioning of important radionuclides. The harsh chemical and radiolytic environment in high-level waste tanks alters both the organic complexants and the metal species, producing radionuclide-chelator complexes that resist standard separation methods. A detailed understanding of the complexation reactions of the key radionuclides in tank wastes would allow for reliable, science-based solutions for high-level waste processing, but a key problem is that tank waste samples are exceedingly difficult to obtain, transport and handle in the laboratory. In contrast, freshly-prepared simulated wastes are safe and readily obtained, but they do not reproduce the partitioning behavior of actual tank waste samples. For this project, we will first artificially age complexant-containing tank waste simulants using microwave, ultrasound, and photolysis techniques that can be applied in any standard laboratory. The aged samples will be compared to samples of actual Hanford tank wastes to determine the most realistic aging method, on the basis of the organic fragments present, and the oxidation states and partitioning behavior of important radionuclides such as 90Sr, 99Tc, and 239Pu. Our successful completion of this goal will make it possible for scientists in academic and industrial laboratories to address tank waste remediation problems without the enormous costs and hazards associated with handling actual tank waste samples. Later, we will use our simulant aging process to investigate the relative effects of chelator degradation products on the partitioning of important radionuclides

Dynamic Effects of Tank Waste Aging on Radionuclide-Complexant Interactions - Final Report - 10/01/1997 - 10/01/2000

International Nuclear Information System (INIS)

Chamberlin, Rebecca M.; Arterburn, Jeffrey B.

2000-01-01

The long-range objective of this project is to provide a scientific basis for safely processing high-level nuclear tanks wastes for disposal. Our goals are to identify a means to prepare realistic simulant formulations for complexant-containing Hanford tank wastes, and then use those simulants to determine the relative importance of various organic complexants and their breakdown products on the partitioning of important radionuclides. The harsh chemical and radiolytic environment in high-level waste tanks alters both the organic complexants and the metal species, producing radionuclide-chelator complexes that resist standard separation methods. A detailed understanding of the complexation reactions of the key radionuclides in tank wastes would allow for reliable, science-based solutions for high-level waste processing, but a key problem is that tank waste samples are exceedingly difficult to obtain, transport and handle in the laboratory. In contrast, freshly-prepared simulated wastes are safe and readily obtained, but they do not reproduce the partitioning behavior of actual tank waste samples. For this project, we will first artificially age complexant-containing tank waste simulants using microwave, ultrasound, and photolysis techniques that can be applied in any standard laboratory. The aged samples will be compared to samples of actual Hanford tank wastes to determine the most realistic aging method, on the basis of the organic fragments present, and the oxidation states and partitioning behavior of important radionuclides such as 90Sr, 99Tc, and 239Pu. Our successful completion of this goal will make it possible for scientists in academic and industrial laboratories to address tank waste remediation problems without the enormous costs and hazards associated with handling actual tank waste samples. Later, we will use our simulant aging process to investigate the relative effects of chelator degradation products on the partitioning of important radionuclides

Identification, classification and management of industrial waste in Kavir steel complex according to the Bazel convention and RCRA

OpenAIRE

Mohammad Hasan Ehrampoush; Mohsen Hesami Arani; Mohammad Taghi Ghaneian; Asghar Ebrahimi; Masoud Shafiee

2016-01-01

Introduction: Requiring industries for implementing industrial waste management programs and planning for proper waste disposal is essential in order to achieve sustainable development. Therefore, industrial waste management program was done in Kavir Steel Complex, in Aran va Bidgol region to identify and classify industrial waste and also to present solutions for improving waste management. In this complex, production process is hot rolling steel and the product is rebar. Material and Me...

Sampling and analysis plan for sampling of liquid waste streams generated by 222-S Laboratory Complex operations

International Nuclear Information System (INIS)

Benally, A.B.

1997-01-01

This Sampling and Analysis Plan (SAP) establishes the requirements and guidelines to be used by the Waste Management Federal Services of Hanford, Inc. personnel in characterizing liquid waste generated at the 222-S Laboratory Complex. The characterization process to verify the accuracy of process knowledge used for designation and subsequent management of wastes consists of three steps: to prepare the technical rationale and the appendix in accordance with the steps outlined in this SAP; to implement the SAP by sampling and analyzing the requested waste streams; and to compile the report and evaluate the findings to the objectives of this SAP. This SAP applies to portions of the 222-S Laboratory Complex defined as Generator under the Resource Conservation and Recovery Act (RCRA). Any portion of the 222-S Laboratory Complex that is defined or permitted under RCRA as a treatment, storage, or disposal (TSD) facility is excluded from this document. This SAP applies to the liquid waste generated in the 222-S Laboratory Complex. Because the analytical data obtained will be used to manage waste properly, including waste compatibility and waste designation, this SAP will provide directions for obtaining and maintaining the information as required by WAC173-303

Complexant Identification in Hanford Waste Simulant Sr/TRU Filtrate

International Nuclear Information System (INIS)

Bannochie, C.J.

2003-01-01

This project was designed to characterize the available multidentate ligand species and metal ion complexes of iron, strontium and manganese formed with the parent chelators, complexing agents and their fragment products. Complex identification was applied to AN-102 and AN-107 filtrate simulants for Hanford waste after an oxidation reaction with sodium permanganate to create a freshly precipitated manganese dioxide solid for adsorption of transuranic elements. Separation efficiency of different ligands was investigated based on the exchange capability of different ion exchange and ion exclusion analytical columns including Dionex IonPac AS-5A, AS-10, AS-11 and AS-6. The elution programs developed with different mobile phase concentrations were based on the change in the effective charge of the anionic species and therefore the retention on the stationary phase. In the present work, qualitative and quantitative assessments of multidentate ligands were investigated. Identification methods for the metal ion complexes responsible for solubilizing Fe, Mn and Sr were applied to aged and fresh simulant waste filtrates. Although concentration measurements of both fresh and 3-week aged filtrates showed that the degradation process occurs mainly due to the harsh chemical environment, it was found that the concentration of iron and manganese did not increase, within the error of the analytical measurements, after three weeks when compared with fresh filtrate

Maruzen Petrochemical Co., Ltd.: It sells function carbon material; Kinosei tanso zai wo kakuhan

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-02-28

Maruzen Petrochemical Co., Ltd. strengthens the sales of the function carbon material. Maruzen Petrochemical Co., Ltd. started development of demand of the new function charcoals purple material. New carbon material proceeds with the sample work to turn the lithium ion the second battery that an electric self-help car and so on is being expected demand expansion with the material for molding which made naphsa resolution child quality oil raw material, and capacitor. In the same company, the policy that laying will be fitted to this rank diffusion of the electric car in the future and a business story comic will be advanced as a high-performance capacitor material. (translated by NEDO)

Risky business : outlook for financing petrochemical projects in Asia

International Nuclear Information System (INIS)

Miyachi, M.

1998-01-01

The impact of the Asian economic crisis on the petrochemical industry was discussed. From 1985 to 1995 East Asian currencies that were pegged to the US dollar experienced a 40 per cent depreciation against other major currencies, such as the Japanese yen. This resulted in strong exports which stimulated rapid economic growth rates. However, during 1995-1997, the US dollar rebounded, appreciating by 20 per cent. For countries such as Indonesia, Thailand and Korea, the sharp appreciation of their US dollar-linked currencies effectively reversed their export advantage vis-a-vis China and Japan, and led to massive devaluation of their currencies. Tightening of the Japanese fiscal policy by increasing taxes produced disastrous results, leading to a drastic reduction in consumer demand. The solution, it was suggested, lies in loosening Japanese fiscal policy and stabilizing the Yen-Dollar rate. Another solution suggested was decisive action to strengthen the Japanese banking system. Despite the current difficulties, it was concluded that the future outlook for the Asian petrochemical market is bright and that steady economic growth can be expected in the long term. It was suggested that the main factor that will determine how quickly East Asian economies recover will be how quickly the Japanese economy emerges from recession. 6 figs

Petrochemical variation of Topopah Spring tuff matrix with depth (stratigraphic level), drill hole USW G-4, Yucca Mountain, Nevada

International Nuclear Information System (INIS)

Byers, F.M. Jr.

1985-12-01

This study describes and interprets petrochemical variation of the matrix (excluding fractures and large gas cavities) of the Topopah Spring Member of the Paintbrush Tuff. This tuff includes the candidate host rock for a high-level nuclear waste repository at Yucca Mountain on the Nevada Test Site. Cored hole USW G-4, near the site of a potential exploratory shaft at Yucca Mountain, penetrated 359.4 m (1179 ft) of the member within the unsaturated zone. This study shows that petrographic textures and chemistry of the matrix vary systematically within recognizable lithologic subunits related to crystallization (cooling) zones, welding (compaction) zones, and compositional zones (rhyolite versus quartz latite). The methods used for this study include petrographic modal thin section analysis using an automated counter and electron microprobe analysis of the groundmass. Distinctive textural categories are defined, and they can be ranked from finest to coarsest as vitrophyre (glass), cryptocrystalline groundmass, spherulites, granophyre, lithic fragments, and phenocrysts. The two main groundmass compositions are also defined: rhyolite high silica) and quartz latite. The value of these petrochemical studies lies in providing microscopic criteria for recognizing the zonal subunits where they may have greatly limited exposure, as in mined drifts and in core from horizontal drill holes. For example, the lower nonlithophysal zone can be distinguished microscopically from the middle nonlithophysal zone by (1) degree of compaction, (2) amount of quartz, and (3) amount of lithic fragments. The variability between these textural categories should also be considered in designing physical and chemical tests of the Topopah Spring

Petrochemical variation of Topopah Spring tuff matrix with depth (stratigraphic level), drill hole USW G-4, Yucca Mountain, Nevada

Energy Technology Data Exchange (ETDEWEB)

Byers, F.M. Jr.

1985-12-01

This study describes and interprets petrochemical variation of the matrix (excluding fractures and large gas cavities) of the Topopah Spring Member of the Paintbrush Tuff. This tuff includes the candidate host rock for a high-level nuclear waste repository at Yucca Mountain on the Nevada Test Site. Cored hole USW G-4, near the site of a potential exploratory shaft at Yucca Mountain, penetrated 359.4 m (1179 ft) of the member within the unsaturated zone. This study shows that petrographic textures and chemistry of the matrix vary systematically within recognizable lithologic subunits related to crystallization (cooling) zones, welding (compaction) zones, and compositional zones (rhyolite versus quartz latite). The methods used for this study include petrographic modal thin section analysis using an automated counter and electron microprobe analysis of the groundmass. Distinctive textural categories are defined, and they can be ranked from finest to coarsest as vitrophyre (glass), cryptocrystalline groundmass, spherulites, granophyre, lithic fragments, and phenocrysts. The two main groundmass compositions are also defined: rhyolite high silica) and quartz latite. The value of these petrochemical studies lies in providing microscopic criteria for recognizing the zonal subunits where they may have greatly limited exposure, as in mined drifts and in core from horizontal drill holes. For example, the lower nonlithophysal zone can be distinguished microscopically from the middle nonlithophysal zone by (1) degree of compaction, (2) amount of quartz, and (3) amount of lithic fragments. The variability between these textural categories should also be considered in designing physical and chemical tests of the Topopah Spring.

Colombia defines innovative plans for refining and petrochemicals

International Nuclear Information System (INIS)

Carta Petrolera

1998-01-01

Ecopetrol plans to increase capacity at its Cartagena refinery to 140,000 barrels per day until 2002. The new production will be for basic streams to supply and stimulate new industries in the petrochemical sector. Investment has concentrated on exploration and production and far less on the rest of the oil sector, but now Ecopetrol will be new financing plans to develop refining in keeping with government guidelines. The Ecopetrol Board approved the development plan for the Cartagena Refinery, this consist of increasing capacity

Development of biodegradation testing within a whole effluent assessment scheme: petrochemical application

NARCIS (Netherlands)

Leonards, P.E.G.; Postma, J.F.

2007-01-01

This study was performed for Concawe to obtain information on the development of an approach for assessing biodegradation of petrochemical effluents and the impact on assessing the toxicity and potential to bioaccumulate of the constituents. Whole Effluent Assessments (WEA) are being investigated as

Hanford facility dangerous waste Part A, Form 3 and Part B permit application documentation, Central Waste Complex (WA7890008967)(TSD: TS-2-4)

Energy Technology Data Exchange (ETDEWEB)

Saueressig, D.G.

1998-05-20

The Hanford Facility Dangerous Waste Permit Application is considered to be a single application organized into a General Information Portion (document number DOE/RL-91-28) and a Unit-Specific Portion. The scope of the Unit-Specific Portion is limited to Part B permit application documentation submitted for individual, operating, treatment, storage, and/or disposal units, such as the Central Waste Complex (this document, DOE/RL-91-17). Both the General Information and Unit-Specific portions of the Hanford Facility Dangerous Waste Permit Application address the content of the Part B permit application guidance prepared by the Washington State Department of Ecology (Ecology 1996) and the U.S. Environmental Protection Agency (40 Code of Federal Regulations 270), with additional information needed by the Hazardous and Solid Waste Amendments and revisions of Washington Administrative Code 173-303. For ease of reference, the Washington State Department of Ecology alpha-numeric section identifiers from the permit application guidance documentation (Ecology 1996) follow, in brackets, the chapter headings and subheadings. A checklist indicating where information is contained in the Central Waste Complex permit application documentation, in relation to the Washington State Department of Ecology guidance, is located in the Contents section. Documentation contained in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units (e.g., the glossary provided in the General Information Portion). Wherever appropriate, the Central Waste Complex permit application documentation makes cross-reference to the General Information Portion, rather than duplicating text. Information provided in this Central Waste Complex permit application documentation is current as of May 1998.

The effect of Health, Safety and Environment Management System (HSE-MS on the improvement of safety performance indices in Urea and Ammonia Kermanshah Petrochemical Company

Directory of Open Access Journals (Sweden)

M. S. Poursoleiman

2015-09-01

Full Text Available Introduction: Work-related accidents may cause damage to people, environment and lead to waste of time and money. Health, Safety and Environment Management System has been developed in order to reduce accidents. This study aimed to investigate the effect of implementation of this system on reduction of the accidents and its consequences and also on the safety performance indices in Kermanshah Petrochemical Company. Material and Method: In this study, records of accidents were collected by OSHA incident report form 301 over 4 years. Following, the mean annual accidents and its consequences and safety performance indices were calculated and reported. Then, using statistical analysis, the impacts of two years implementation of this system on the accidents and its consequences and safety performance indices were evaluated. Result: The results showed that the implementation of HSE system was significantly correlated with Frequency Severity Indicator, Accident Severity Rate, lost days, minor accidents and total incidents (P-value 0.05. Conclusion: The implementation of Health, Safety and the Environment Management System caused a reduction in accidents and its consequences and most of the safety performance indices in the entire process cycle of Kermanshah Petrochemical Company. Overall, safety condition has been improved considerably.

Nuclear waste management and sustainable development: the complexity of a decision in a controversial universe

International Nuclear Information System (INIS)

Le Dars, A.

2002-01-01

This PhD dissertation intends to demonstrate in what extent the concept of sustainable development applied to nuclear waste management requires a novel scientific approach. High-level and long-lived radioactive waste management needs to make decisions in taking into account multiple dimensions, characterised by uncertainty, irreversibility, and long term, and which are much debated. These scientific controversies often induce social conflicts due to the divergence in stakeholders point of views, values or interests. Therefore, nuclear waste management in a sustainable development constitutes a complex decision-making problem. This thesis focuses on high-level and long-lived radioactive waste management in the French context because this country is confronted with the most severe conflicts. Researches are operating in the 30 December 1991 law framework, and in 2006 a Parliament decision could be made concerning the choice of a long-term nuclear waste management solution. This survey studies in what extent economics can open to other scientific disciplines in using evaluation tools and decision-making procedures which better integrate several conflicting criteria. This work deals with the criticism of the epistemological and methodological foundations of economic evaluation, notably in questioning the realism of its hypothesis, and a qualitative survey directly made close to stakeholders goes deeper into the analysis of their complex relationships. The first part of this thesis puts in evidence the complexity of a sustainable nuclear waste management. Chapter 1 shows that sustainable nuclear waste management is a health and ecological problem irreducible to a technical solution, and Chapter 2 explains why sustainable nuclear waste management constitutes a social choice problem irreducible to an economic evaluation. The second part of this thesis shows that a concerted decision-making process seems to be a good procedure to overcome this complexity. Chapter 3 analyses

Hanford Facility Dangerous Waste Permit Application, 222-S Laboratory Complex

International Nuclear Information System (INIS)

WILLIAMS, J.F.

2000-01-01

The Hanford Facility Dangerous Waste Permit Application is considered to be a single application organized into a General Information Portion (document number DOE/RL-91-28) and a Unit-Specific Portion. The scope of the Unit-Specific Portion is limited to Part B permit application documentation submitted for individual, operating treatment, storage, and/or disposal units, such as the 222-S Laboratory Complex (this document, DOE/RL-91-27). Both the General Information and Unit-Specific portions of the Hanford Facility Dangerous Waste Permit Application address the content of the Part B permit application guidance prepared by the Washington State Department of Ecology (Ecology 1987 and 1996) and the U.S. Environmental Protection Agency (40 Code of Federal Regulations 270), with additional information needs defined by the Hazardous and Solid Waste Amendments and revisions of Washington Administrative Code 173-303. For ease of reference, the Washington State Department of Ecology alpha-numeric section identifiers from the permit application guidance documentation (Ecology 1996) follow, in brackets, the chapter headings and subheadings. Documentation contained in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units (e.g., the glossary provided in the General Information Portion). Wherever appropriate, the 222-S Laboratory Complex permit application documentation makes cross-reference to the General Information Portion, rather than duplicating text. Information provided in this 222-S Laboratory Complex permit application documentation is current as of August 2000

Environmental benefits and drawbacks of composite fuels based on industrial wastes and different ranks of coal.

Science.gov (United States)

Nyashina, G S; Vershinina, K Yu; Dmitrienko, M A; Strizhak, P A

2018-04-05

A promising solution to many problems that thermal power industry is facing today would be switching from conventional coal dust combustion to coal-water slurries containing petrochemicals (CWSP). Here, we perform an experimental study of the most hazardous anthropogenic emissions (sulfur and nitrogen oxides) from the combustion of high-potential CWSP. We identify the main benefits and potential drawbacks of using CWSP in thermal power industry. A set of components and additives to CWSP are explored that significantly affect the environmental and energy performance of fuels. The anthropogenic emissions from the combustion of CWSP made of widespread coal and oil processing wastes are no higher than those from coal dust combustion. Using specialized additives to CWSP, we can change the concentrations of NO x and SO x several times. The most appealing additives to CWSP are sawdust, straw, charcoal, limestone, and glycerol. They provide better environmental, economic, and energy performance and improve the rheological properties of CWSP. Waste oils and oil sludge added to CWSP may impair the environmental performance but boost the cost and energy efficiency. Using coal-water slurries containing petrochemicals as a fuel at thermal power plants is an environmentally friendly as well as cost- and energy-efficient way to recover industrial wastes. Copyright © 2018 Elsevier B.V. All rights reserved.

Recovery of Proteins and Chromium Complexes from Chromium – Containing Leather Waste (CCLW

Directory of Open Access Journals (Sweden)

B. Gutti

2010-08-01

Full Text Available Chromium – Containing Leather Waste (CCLW constitutes an environmental pollution problem to leather industries disposing the waste by landfill. The waste mainly consists of collagen and chromium III complexes. This work is a design of reactors to recover gelatin, polypeptides and chromium from CCLW. The results of the experiment shows that 68% of protein, based on dry weight of leather scraps, could be recovered. Three reactors with a total volume of 18 m3 was designed to handle 10,431 kg of waste generated from the tanning industries.

Characterization of radionuclide-chelating agent complexes found in low-level radioactive decontamination waste. Literature review

International Nuclear Information System (INIS)

Serne, R.J.; Felmy, A.R.; Cantrell, K.J.; Krupka, K.M.; Campbell, J.A.; Bolton, H. Jr.; Fredrickson, J.K.

1996-03-01

The US Nuclear Regulatory Commission is responsible for regulating the safe land disposal of low-level radioactive wastes that may contain organic chelating agents. Such agents include ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), picolinic acid, oxalic acid, and citric acid, and can form radionuclide-chelate complexes that may enhance the migration of radionuclides from disposal sites. Data from the available literature indicate that chelates can leach from solidified decontamination wastes in moderate concentration (1--100 ppm) and can potentially complex certain radionuclides in the leachates. In general it appears that both EDTA and DTPA have the potential to mobilize radionuclides from waste disposal sites because such chelates can leach in moderate concentration, form strong radionuclide-chelate complexes, and can be recalcitrant to biodegradation. It also appears that oxalic acid and citric acid will not greatly enhance the mobility of radionuclides from waste disposal sites because these chelates do not appear to leach in high concentration, tend to form relatively weak radionuclide-chelate complexes, and can be readily biodegraded. In the case of picolinic acid, insufficient data are available on adsorption, complexation of key radionuclides (such as the actinides), and biodegradation to make definitive predictions, although the available data indicate that picolinic acid can chelate certain radionuclides in the leachates

Characterization of radionuclide-chelating agent complexes found in low-level radioactive decontamination waste. Literature review

Energy Technology Data Exchange (ETDEWEB)

Serne, R.J.; Felmy, A.R.; Cantrell, K.J.; Krupka, K.M.; Campbell, J.A.; Bolton, H. Jr.; Fredrickson, J.K. [Pacific Northwest National Lab., Richland, WA (United States)

1996-03-01

The US Nuclear Regulatory Commission is responsible for regulating the safe land disposal of low-level radioactive wastes that may contain organic chelating agents. Such agents include ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), picolinic acid, oxalic acid, and citric acid, and can form radionuclide-chelate complexes that may enhance the migration of radionuclides from disposal sites. Data from the available literature indicate that chelates can leach from solidified decontamination wastes in moderate concentration (1--100 ppm) and can potentially complex certain radionuclides in the leachates. In general it appears that both EDTA and DTPA have the potential to mobilize radionuclides from waste disposal sites because such chelates can leach in moderate concentration, form strong radionuclide-chelate complexes, and can be recalcitrant to biodegradation. It also appears that oxalic acid and citric acid will not greatly enhance the mobility of radionuclides from waste disposal sites because these chelates do not appear to leach in high concentration, tend to form relatively weak radionuclide-chelate complexes, and can be readily biodegraded. In the case of picolinic acid, insufficient data are available on adsorption, complexation of key radionuclides (such as the actinides), and biodegradation to make definitive predictions, although the available data indicate that picolinic acid can chelate certain radionuclides in the leachates.

Training requirements and responsibilities for the Buried Waste Integrated Demonstration at the Radioactive Waste Management Complex

International Nuclear Information System (INIS)

Vega, H.G.; French, S.B.; Rick, D.L.

1992-09-01

The Buried Waste Integrated Demonstration (BWID) is scheduled to conduct intrusive (hydropunch screening tests, bore hole installation, soil sampling, etc.) and nonintrusive (geophysical surveys) studies at the Radioactive Waste Management Complex (RWMC). These studies and activities will be limited to specific locations at the RWMC. The duration of these activities will vary, but most tasks are not expected to exceed 90 days. The BWID personnel requested that the Waste Management Operational Support Group establish the training requirements and training responsibilities for BWID personnel and BWID subcontractor personnel. This document specifies these training requirements and responsibilities. While the responsibilities of BWID and the RWMC are, in general, defined in the interface agreement, the training elements are based on regulatory requirements, DOE orders, DOE-ID guidance, state law, and the nature of the work to be performed

Integrating sequencing batch reactor with bio-electrochemical treatment for augmenting remediation efficiency of complex petrochemical wastewater.

Science.gov (United States)

Yeruva, Dileep Kumar; Jukuri, Srinivas; Velvizhi, G; Naresh Kumar, A; Swamy, Y V; Venkata Mohan, S

2015-01-01

The present study evaluates the sequential integration of two advanced biological treatment methods viz., sequencing batch reactor (SBR) and bioelectrochemical treatment systems (BET) for the treatment of real-field petrochemical wastewater (PCW). Initially two SBR reactors were operated in aerobic (SBR(Ae)) and anoxic (SBR(Ax)) microenvironments with an organic loading rate (OLR) of 9.68 kg COD/m(3)-day. Relatively, SBR(Ax) showed higher substrate degradation (3.34 kg COD/m(3)-day) compared to SBR(Ae) (2.9 kg COD/m(3)-day). To further improve treatment efficiency, the effluents from SBR process were fed to BET reactors. BET(Ax) depicted higher SDR (1.92 kg COD/m(3)-day) with simultaneous power generation (17.12 mW/m(2)) followed by BET(Ae) (1.80 kg COD/m(3)-day; 14.25 mW/m(2)). Integrating both the processes documented significant improvement in COD removal efficiency due to the flexibility of combining multiple microenvironments sequentially. Results were supported with GC-MS and FTIR, which confirmed the increment in biodegradability of wastewater. Copyright © 2015 Elsevier Ltd. All rights reserved.

Toxicity assessment of carbon black waste: A by-product from oil refineries

Energy Technology Data Exchange (ETDEWEB)

Zhen, Xu; Ng, Wei Cheng [NUS Environmental Research Institute, National University of Singapore, 1 Create Way, Create Tower #15-02, 138602 (Singapore); Fendy; Tong, Yen Wah [Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 (Singapore); Dai, Yanjun [School of Mechanical Engineering, Shanghai Jiaotong University, Shanghai, 200240 (China); Neoh, Koon Gee, E-mail: chenkg@nus.edu.sg [Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 (Singapore); Wang, Chi-Hwa, E-mail: chewch@nus.edu.sg [Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585 (Singapore)

2017-01-05

Highlights: • Carbon black waste extract decreased cell viability in a dose and time-dependent manner. • Apoptosis of human cell lines was induced by carbon black waste extract. • Carbon black waste extract elicited oxidative stress by increasing intracellular ROS generation. • Carbon black waste extract impaired antioxidant enzymatic activities of human cell lines. • The high toxicity of carbon black waste extract could be attributed mainly to the effect of vanadium. - Abstract: In Singapore, approximately 30 t/day of carbon-based solid waste are produced from petrochemical processes. This carbon black waste has been shown to possess physical properties that are characteristic of a good adsorbent such as high external surface area. Therefore, there is a growing interest to reutilize and process this carbon black waste into secondary materials such as adsorbents. However, the carbon black waste obtained from petrochemical industries may contain heavy metals that are hazardous to human health and the environment, hence restricting its full potential for re-utilization. Therefore, it is important to examine the possible toxicity effects and toxicity mechanism of carbon black waste on human health. In this study, inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis showed that the heavy metals, vanadium (V), molybdenum (Mo) and nickel (Ni), were present in the carbon black waste in high concentrations. Three human cell lines (HepG2 cells, MRC-5 cells and MDA-MB-231 cells) were used to investigate the toxicity of carbon black waste extract in a variety of in vitro assays. Results from MTS assays indicated that carbon black waste extract decreased the viability of all three cell lines in a dose and time-dependent manner. Observations from confocal microscopy further confirmed this phenomenon. Flow cytometry assay also showed that carbon black waste extract induced apoptosis of human cell lines, and the level of apoptosis increased with

Toxicity assessment of carbon black waste: A by-product from oil refineries

International Nuclear Information System (INIS)

Zhen, Xu; Ng, Wei Cheng; Fendy; Tong, Yen Wah; Dai, Yanjun; Neoh, Koon Gee; Wang, Chi-Hwa

2017-01-01

Highlights: • Carbon black waste extract decreased cell viability in a dose and time-dependent manner. • Apoptosis of human cell lines was induced by carbon black waste extract. • Carbon black waste extract elicited oxidative stress by increasing intracellular ROS generation. • Carbon black waste extract impaired antioxidant enzymatic activities of human cell lines. • The high toxicity of carbon black waste extract could be attributed mainly to the effect of vanadium. - Abstract: In Singapore, approximately 30 t/day of carbon-based solid waste are produced from petrochemical processes. This carbon black waste has been shown to possess physical properties that are characteristic of a good adsorbent such as high external surface area. Therefore, there is a growing interest to reutilize and process this carbon black waste into secondary materials such as adsorbents. However, the carbon black waste obtained from petrochemical industries may contain heavy metals that are hazardous to human health and the environment, hence restricting its full potential for re-utilization. Therefore, it is important to examine the possible toxicity effects and toxicity mechanism of carbon black waste on human health. In this study, inductively coupled plasma optical emission spectroscopy (ICP-OES) analysis showed that the heavy metals, vanadium (V), molybdenum (Mo) and nickel (Ni), were present in the carbon black waste in high concentrations. Three human cell lines (HepG2 cells, MRC-5 cells and MDA-MB-231 cells) were used to investigate the toxicity of carbon black waste extract in a variety of in vitro assays. Results from MTS assays indicated that carbon black waste extract decreased the viability of all three cell lines in a dose and time-dependent manner. Observations from confocal microscopy further confirmed this phenomenon. Flow cytometry assay also showed that carbon black waste extract induced apoptosis of human cell lines, and the level of apoptosis increased with

Hurricane Harvey, Houston's Petrochemical Industry, and US Chemical Safety Policy: Impacts to Environmental Justice Communities

Science.gov (United States)

Goldman, G. T.; Johnson, C.; Gutierrez, A.; Declet-Barreto, J.; Berman, E.; Bergman, A.

2017-12-01

When Hurricane Harvey made landfall outside Houston, Texas, the storm's wind speeds and unprecedented precipitation caused significant damage to the region's petrochemical infrastructure. Most notably, the company Arkema's Crosby facility suffered a power failure that led to explosions and incineration of six of its peroxide tanks. Chemicals released into the air from the explosions sent 15 emergency responders to the hospital with severe respiratory conditions and led to the evacuation of hundreds of surrounding households. Other petrochemical facilities faced other damages that resulted in unsafe and acute chemical releases into the air and water. What impacts did such chemical disasters have on the surrounding communities and emergency responders during Harvey's aftermath? What steps might companies have taken to prevent such chemical releases? And what chemical safety policies might have ensured that such disaster risks were mitigated? In this talk we will report on a survey of the extent of damage to Houston's oil and gas infrastructure and related chemical releases and discuss the role of federal chemical safety policy in preventing and mitigating the potential for such risks for future storms and other extreme weather and climate events. We will also discuss how these chemical disasters created acute toxics exposures on environmental justice communities already overburdened with chronic exposures from the petrochemical industry.

Proceedings of the CERI 2006 petrochemical conference : thinking outside the box : preparing tomorrow's North American industry

Energy Technology Data Exchange (ETDEWEB)

NONE

2006-07-01

This conference addressed the global competitiveness of the Canadian petrochemical industry and its potential markets. Recent advances in technology were highlighted along with issues concerning transportation and infrastructure. In addition to addressing capital cost requirements and feedstock availability, the presentations addressed opportunities for growth and product diversification. Alberta's role in the North American energy markets was also discussed, along with issues concerning feedstock from Canadian oil sands. It was noted that the survival of the North American petrochemical industry depends on the price of natural gas liquids. With feedstock at two to three times the price in the Middle East, petrochemical producers, governments, and suppliers need to adopt aggressive strategies to maintain a competitive position and profitability. The sessions of the conference addressed global competitive issues; integration and mastering competitiveness; the Alberta advantage; feedstock and technologies; and, reaching international markets. The conference featured 18 presentations, of which 7 have been catalogued separately for inclusion in this database. refs., tabs., figs.

International natural gas and petrochemical opportunities

International Nuclear Information System (INIS)

Pierce, R.L.

1995-01-01

The approach of NOVA Gas International Ltd. (NGI) to locating international development opportunities was reviewed. NOVA has provided consulting expertise to more than 300 projects in 50 countries during the past 20 years. NGI is focusing its energies on five regions: Canada, the US, Mexico, the southern cone of South America and the Asia-Pacific region. To determine where to offer natural gas services and petrochemicals, the Company utilizes a multi-step analysis process which is designed to identify (1) the perfect customer, (2) the most attractive global regions, (3) the potential pitfalls, and (4) the best projects. NOVA also found out the importance of developing a solid network of local contacts and partners. Project financing must be adequate and flexible, requiring constant communications with partners and interested parties

Public health assessment for Petrochem Recycling Corporation/Ekotek, Salt Lake City, Salt Lake County, Utah, Region 8. CERCLIS No. UTD093119196. Preliminary report

International Nuclear Information System (INIS)

1993-01-01

The Petrochem/EkoTek site was operated by several owners as a refinery from 1953 until 1978 and as a hazardous waste storage/treatment facility and a petroleum recycling facility from 1978 through 1988. Removal of essentially all petroleum products and hazardous wastes in tanks and drums was accomplished from 1988 - 1991. The process that will lead to the complete clean-up of the facility is ongoing. The site was added to the National Priorities List (NPL) in October 1992. Contaminants in the soil are arsenic, barium, cadmium, chromium, lead, manganese, mercury, chlordane, dieldrin, polychlorinated biphenyls (PCBs), bis(2-ethylhexyl)phthalate, di-n-butyl phthalate, pentachlorophenol, and heptachlor epoxide. Children who ingest regularly large amounts (five grams or more a day) of soil contaminated with the highest levels of arsenic and cadmium have some risk for adverse health effects. The arsenic levels are typical for the Salt Lake City area. The maximum levels of barium could also cause health effects in children according to animal studies. There are four ways that humans may have been exposed: surface water, groundwater, soil gas, and waste materials. Surface-water runoff probably transported unknown concentrations of site contaminants to businesses west of the site. Residences and businesses within 1 mile of the site use municipal water for drinking water

Identification of efficient chelating acids responsible for Cesium, Strontium and Barium complexes solubilization in mixed wastes

International Nuclear Information System (INIS)

Borai, E.H.

2007-01-01

The present paper is focused to characterize the available multi dentate ligand species and their metal ion complexes of cesium (Cs), strontium (Sr) and barium (Ba) formed with the parent chelators, complexing agents and its fragment products in mixed waste filtrate. The developed separation programs of different ligands by different mobile phases were based on the decrease of the effective charge of the anionic species in a differentiated way hence, the retention times on the stationary phases (AS-4A and AS-12A) are changed. Ion chromatographic (IC) analysis of the metal complexes showed that the carboxylic acids that are responsible for solubilizing Cs, Sr and Ba in the waste filtrate are NTA, Citrate and PDCA, respectively. Therefore, the predominant metal complexes in the filtrate at high ph are Cs (I)-NTA, Sr (IT)-Citrate and Ba (IT)-PDCA. Identification of the metal ion complexes responsible for solubilizing Cs, Sr and Ba was applied on the fresh and aged waste filtrates, to monitor their chemical behavior, which leads to increased control of the waste treatment process. Although, concentration measurements of both fresh and aged filtrates confirmed that the degradation process has occurred mainly due to a harsh chemical environment, the concentration of Cs(I), Sr(II) and Ba(II) increased slightly in the aged filterate compared with the fresh filtrate. This is due to the decomposition and/or degradation of their metal complexes and hence leads to free metal ion species in the filtrate. These observations indicate that the organic content of mixed waste filtrate is dynamic and need continuous analytical monitoring

Carbonaceous materials in petrochemical wastewater before and after treatment in an aerated submerged fixed-bed biofilm reactor

Directory of Open Access Journals (Sweden)

Trojanowicz Karol

2016-09-01

Full Text Available Results of the studies for determining fractions of organic contaminants in a pretreated petrochemical wastewater flowing into a pilot Aerated Submerged Fixed-Bed Biofilm Reactor (ASFBBR are presented and discussed. The method of chemical oxygen demand (COD fractionation consisted of physical tests and biological assays. It was found that the main part of the total COD in the petrochemical, pretreated wastewater was soluble organic substance with average value of 57.6%. The fractions of particulate and colloidal organic matter were found to be 31.8% and 10.6%, respectively. About 40% of COD in the influent was determined as readily biodegradable COD. The inert fraction of the soluble organic matter in the petrochemical wastewater constituted about 60% of the influent colloidal and soluble COD. Determination of degree of hydrolysis (DH of the colloidal fraction of COD was also included in the paper. The estimated value of DH was about 62%. Values of the assayed COD fractions were compared with the same parameters obtained for municipal wastewater by other authors.

Supplemental design requirements document solid waste operations complex

International Nuclear Information System (INIS)

Ocampo, V.P.; Boothe, G.F.; Broz, D.R.; Eaton, H.E.; Greager, T.M.; Huckfeldt, R.A.; Kooiker, S.L.; Lamberd, D.L.; Lang, L.L.; Myers, J.B.

1994-11-01

This document provides additional and supplemental information to the WHC-SD-W112-FDC-001, WHC-SD-W113-FDC-001, and WHC-SD-W100-FDC-001. It provides additional requirements for the design and summarizes Westinghouse Hanford Company key design guidance and establishes the technical baseline agreements to be used for definitive design common to the Solid Waste Operations Complex (SWOC) Facilities (Project W-112, Project W-113, and WRAP 2A)

THE INFLUENCE OF INNOVATIONS SUSTAINABLE IN DECISION PURCHASE OF INDUSTRIES THIRD GENERATION PETROCHEMICAL

Directory of Open Access Journals (Sweden)

Luciana Madureira Domingues

2016-08-01

Full Text Available This article aims to understand how sustainable innovation influences the decision of industrial purchases. Much has been said about the organizational buying behavior, but little is said about how the industrial buyers consider sustainable innovation in their purchasing procedures. This work aims to contribute to the constructs involving this type of purchase behavior. Therefore, a qualitative survey was conducted with non-probabilistic sample , composed of six companies of different sizes , which make up the chain of the petrochemical industry , more specifically , the third generation of this chain . Data were collected via semi-structured interview guide, and studied by means of categorization by content analysis. The analysis revealed that sustainable innovations not influence the purchasing decisions of the petrochemical industry , since the companies surveyed are strongly linked to criteria such as price , time and quality and do not realize sustainable innovation as an important factor in purchasing decisions .

Bio-processing of solid wastes and secondary resources for metal extraction - A review.

Science.gov (United States)

Lee, Jae-Chun; Pandey, Banshi Dhar

2012-01-01

Metal containing wastes/byproducts of various industries, used consumer goods, and municipal waste are potential pollutants, if not treated properly. They may also be important secondary resources if processed in eco-friendly manner for secured supply of contained metals/materials. Bio-extraction of metals from such resources with microbes such as bacteria, fungi and archaea is being increasingly explored to meet the twin objectives of resource recycling and pollution mitigation. This review focuses on the bio-processing of solid wastes/byproducts of metallurgical and manufacturing industries, chemical/petrochemical plants, electroplating and tanning units, besides sewage sludge and fly ash of municipal incinerators, electronic wastes (e-wastes/PCBs), used batteries, etc. An assessment has been made to quantify the wastes generated and its compositions, microbes used, metal leaching efficiency etc. Processing of certain effluents and wastewaters comprising of metals is also included in brief. Future directions of research are highlighted. Copyright © 2011 Elsevier Ltd. All rights reserved.

Prospects of Oil, Gas and Petrochemical Industries in the Arab Region: Opportunities and Challenges, Volume 1 and Volume 2

International Nuclear Information System (INIS)

2004-01-01

The publication has been set up as proceedings of the Chemical Engineering conference, Prospects of Oil, Gas and Petrochemical Industries in The Arab Region Opportunities and Challenges., the conference contains of the following subjects: Gas Processing; Oil Refinery Engineering; Petrochemical Industry; Fuels Technologies and Transport Phenomena; Project Management Economics and Control; Materials and Corrosion Engineering; Biochemical and Environmental Engineering; Water Treatment and Pollution Control. This conference consists of two volume and 1534 pages., figs., tabs., refs

Complex-Wide Waste Flow Analysis V1.0 verification and validation report

International Nuclear Information System (INIS)

Hsu, K.M.; Lundeen, A.S.; Oswald, K.B.; Shropshire, D.E.; Robinson, J.M.; West, W.H.

1997-01-01

The complex-wide waste flow analysis model (CWWFA) was developed to assist the Department of Energy (DOE) Environmental Management (EM) Office of Science and Technology (EM-50) to evaluate waste management scenarios with emphasis on identifying and prioritizing technology development opportunities to reduce waste flows and public risk. In addition, the model was intended to support the needs of the Complex-Wide Environmental Integration (EMI) team supporting the DOE's Accelerating Cleanup: 2006 Plan. CWWFA represents an integrated environmental modeling system that covers the life cycle of waste management activities including waste generation, interim process storage, retrieval, characterization and sorting, waste preparation and processing, packaging, final interim storage, transport, and disposal at a final repository. The CWWFA shows waste flows through actual site-specific and facility-specific conditions. The system requirements for CWWFA are documented in the Technical Requirements Document (TRD). The TRD is intended to be a living document that will be modified over the course of the execution of CWWFA development. Thus, it is anticipated that CWWFA will continue to evolve as new requirements are identified (i.e., transportation, small sites, new streams, etc.). This report provides a documented basis for system verification of CWWFA requirements. System verification is accomplished through formal testing and evaluation to ensure that all performance requirements as specified in the TRD have been satisfied. A Requirement Verification Matrix (RVM) was used to map the technical requirements to the test procedures. The RVM is attached as Appendix A. Since February of 1997, substantial progress has been made toward development of the CWWFA to meet the system requirements. This system verification activity provides a baseline on system compliance to requirements and also an opportunity to reevaluate what requirements need to be satisfied in FY-98

Can we talk? Communications management for the Waste Isolation Pilot Plant, a complex nuclear waste management project

International Nuclear Information System (INIS)

Goldstein, S.A.; Pullen, G.M.; Brewer, D.R.

1995-01-01

Sandia Nuclear Waste Management Program is pursuing for DOE an option for permanently disposing radioactive waste in deep geologic repositories. Included in the Program are the Waste Isolation Pilot Plant (WIPP) Project for US defense program mixed waste the Yucca Mountain Project (YMP) for spent power reactor fuel and vitrified high-level waste, projects for other waste types, and development efforts in environmental decision support technologies. WIPP and YMP are in the public arena, of a controversial nature, and provide significant management challenges. Both projects have large project teams, multiple organization participants, large budgets, long durations, are very complex, have a high degree of programmatic risk, and operate in an extremely regulated environment requiring legal defensibility. For environmental projects like these to succeed, SNL's Program is utilizing nearly all areas in PMI's Project Management Body of Knowledge (PMBOK) to manage along multiple project dimensions such as the physical sciences (e.g., geophysics and geochemistry; performance assessment; decision analysis) management sciences (controlling the triple constraint of performance, cost and schedule), and social sciences (belief systems; public participation; institutional politics). This discussion focuses primarily on communication challenges active on WIPP. How is the WIPP team meeting the challenges of managing communications?'' and ''How are you approaching similar challenges?'' will be questions for a dialog with the audience

Hanford facility dangerous waste Part A, Form 3, and Part B permit application documentation for the Central Waste Complex (WA7890008967) (TSD: TS-2-4)

International Nuclear Information System (INIS)

Saueressig, D.G.

1998-01-01

The Hanford Facility Dangerous Waste Permit Application is considered to be a single application organized into a General Information Portion (document number DOE/RL-91-28) and a Unit-Specific Portion. The scope of the Unit-Specific Portion is limited to Part B permit application documentation submitted for individual, operating, treatment, storage, and/or disposal units, such as the Central Waste Complex (this document, DOE/RL-91-17). Both the General Information and Unit-Specific portions of the Hanford Facility Dangerous Waste Permit Application address the content of the Part B permit application guidance prepared by the Washington State Department of Ecology (Ecology 1996) and the U.S. Environmental Protection Agency (40 Code of Federal Regulations 270), with additional information needed by the Hazardous and Solid Waste Amendments and revisions of Washington Administrative Code 173-303. For ease of reference, the Washington State Department of Ecology alpha-numeric section identifiers from the permit application guidance documentation (Ecology 1996) follow, in brackets, the chapter headings and subheadings. A checklist indicating where information is contained in the Central Waste Complex permit application documentation, in relation to the Washington State Department of Ecology guidance, is located in the Contents section. Documentation contained in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units (e.g., the glossary provided in the General Information Portion). Wherever appropriate, the Central Waste Complex permit application documentation makes cross-reference to the General Information Portion, rather than duplicating text. Information provided in this Central Waste Complex permit application documentation is current as of May 1998

Radiation treatment of solid wastes

International Nuclear Information System (INIS)

Brenner, W.; Rugg, B.; Rogers, C.

1977-01-01

Solid waste is now generally recognized as both a major problem and an underutilized renewable resource for materials and energy recovery. Current methods for dealing with solid wastes are admittedly inadequate for cost effective utilization of the latest material and energy values, especially of cellulose and other organics. Processes for production of energy from organic wastes including incineration, pyrolysis and biodegradation, are receiving considerable attention even though the heating value of dried organic wastes is substantially less than that of fossil fuels. An attractive alternative approach is conversion into chemical feedstocks for use as fuels, intermediates for plastics, rubbers, fibers etc., and in the preparation of foods. Radiation treatment of solid wastes offers attractive possibilities for upgrading the value of such organic waste components as cellulose and putrescible matter. The latter can be cold sterilized by radiation treatments for the production of animal feed supplements. The wide availability of cellulosic wastes warrants their consideration as an alternate feedstock to petrochemicals for fuels, intermediates and synthesis of single cell protein. The crucial step in this developing technology is optimizing the conversion of cellulose to its monomer glucose which can be accomplished by either acid or enzymatic hydrolysis. A combination pretreatment consisting of radiation of hydropulped cellulosic wastes has shown considerable promise in improving the yields of glucose for acid hydrolysis reactions at substantially lower cost than presently used methods such as grinding. Data are presented to compare the effectiveness of this pretreatment with other techniques which have been investigated. (author)

Analysis of the low-level waste radionuclide inventory for the Radioactive Waste Management Complex performance assessment

Energy Technology Data Exchange (ETDEWEB)

Plansky, L.E.; Hoiland, S.A.

1992-02-01

This report summarizes the results of a study to improve the estimates of the radionuclides in the low-level radioactive waste (LLW) inventory which is buried in the Idaho National Engineering Laboratory (INEL) Radioactive Waste Management Complex (RWMC) Subsurface Disposal Area (SDA). The work is done to support the RWMC draft performance assessment (PA). Improved radionuclide inventory estimates are provided for the INEL LLW generators. Engineering, environmental assessment or other research areas may find use for the information in this report. It may also serve as a LLW inventory baseline for data quality assurance. The individual INEL LLW generators, their history and their activities are also described in detail.

Analysis of the low-level waste radionuclide inventory for the Radioactive Waste Management Complex performance assessment

International Nuclear Information System (INIS)

Plansky, L.E.; Hoiland, S.A.

1992-02-01

This report summarizes the results of a study to improve the estimates of the radionuclides in the low-level radioactive waste (LLW) inventory which is buried in the Idaho National Engineering Laboratory (INEL) Radioactive Waste Management Complex (RWMC) Subsurface Disposal Area (SDA). The work is done to support the RWMC draft performance assessment (PA). Improved radionuclide inventory estimates are provided for the INEL LLW generators. Engineering, environmental assessment or other research areas may find use for the information in this report. It may also serve as a LLW inventory baseline for data quality assurance. The individual INEL LLW generators, their history and their activities are also described in detail

40 CFR Appendix B to Part 414 - Complexed Metal-Bearing Waste Streams

Science.gov (United States)

2010-07-01

... 414—Complexed Metal-Bearing Waste Streams Chromium Azo dye intermediates/Substituted diazonium salts + coupling compounds Vat dyes Acid dyes Azo dyes, metallized/Azo dye + metal acetate Acid dyes, Azo...

A dynamic simulation model of the Savannah River Site high level waste complex

International Nuclear Information System (INIS)

Gregory, M.V.; Aull, J.E.; Dimenna, R.A.

1994-01-01

A detailed, dynamic simulation entire high level radioactive waste complex at the Savannah River Site has been developed using SPEEDUP(tm) software. The model represents mass transfer, evaporation, precipitation, sludge washing, effluent treatment, and vitrification unit operation processes through the solution of 7800 coupled differential and algebraic equations. Twenty-seven discrete chemical constituents are tracked through the unit operations. The simultaneous simultaneous simulation of concurrent batch and continuous processes is achieved by several novel, customized SPEEDUP(tm) algorithms. Due to the model's computational burden, a high-end work station is required: simulation of a years operation of the complex requires approximately three CPU hours on an IBM RS/6000 Model 590 processor. The model will be used to develop optimal high level waste (HLW) processing strategies over a thirty year time horizon. It will be employed to better understand the dynamic inter-relationships between different HLW unit operations, and to suggest strategies that will maximize available working tank space during the early years of operation and minimize overall waste processing cost over the long-term history of the complex. Model validation runs are currently underway with comparisons against actual plant operating data providing an excellent match

Monitoring plan for routine organic air emissions at the Radioactive Waste Management Complex Waste Storage Facilities

International Nuclear Information System (INIS)

Galloway, K.J.; Jolley, J.G.

1994-06-01

This monitoring plan provides the information necessary to perform routine organic air emissions monitoring at the Waste Storage Facilities located at the Transuranic Storage Area of the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory. The Waste Storage Facilities include both the Type I and II Waste Storage Modules. The plan implements a dual method approach where two dissimilar analytical methodologies, Open-Path Fourier Transform Infrared Spectroscopy (OP-FTIR) and ancillary SUMMA reg-sign canister sampling, following the US Environmental Protection Agency (EPA) analytical method TO-14, will be used to provide qualitative and quantitative volatile organic concentration data. The Open-Path Fourier Transform Infrared Spectroscopy will provide in situ, real time monitoring of volatile organic compound concentrations in the ambient air of the Waste Storage Facilities. To supplement the OP-FTIR data, air samples will be collected using SUMMA reg-sign, passivated, stainless steel canisters, following the EPA Method TO-14. These samples will be analyzed for volatile organic compounds with gas chromatograph/mass spectrometry analysis. The sampling strategy, procedures, and schedules are included in this monitoring plan. The development of this monitoring plan is driven by regulatory compliance to the Resource Conservation and Recovery Act, State of Idaho Toxic Air Pollutant increments, Occupational Safety and Health Administration. The various state and federal regulations address the characterization of the volatile organic compounds and the resultant ambient air emissions that may originate from facilities involved in industrial production and/or waste management activities

Proceedings of the CERI 2004 petrochemical conference : Positioning for recovery. CD-ROM ed.

International Nuclear Information System (INIS)

2004-01-01

This conference provided a networking opportunity for those involved in Canada's petrochemical industry. The conditions that affect the industry were discussed along with opportunities for maintaining a competitive position in a global context. Topics of discussion included supply shortages, high costs and major shifts in international trade. It was emphasized that innovation is the key for the industry to maintain its market in a strengthening world economy. The conference featured the following 6 sessions: (1) petrochemicals in a strengthening world economy, (2) twenty-first century natural gas, the other energy crisis, (3) electricity, (4) the feedstock future, upgrading and integration opportunities, (5) adding value to resources, and (6) innovation and opportunity, prospects for new processes. Investment growth and implications for Canada were also outlined along with the challenge of product movement, including new approaches to pipeline shipments, rail transport and maritime transport. The conference featured 23 presentations, of which 9 have been indexed separately for inclusion in this database. tabs., figs

Coal-water slurries containing petrochemicals to solve problems of air pollution by coal thermal power stations and boiler plants: An introductory review.

Science.gov (United States)

Dmitrienko, Margarita A; Strizhak, Pavel A

2018-02-01

This introductory study presents the analysis of the environmental, economic and energy performance indicators of burning high-potential coal water slurries containing petrochemicals (CWSP) instead of coal, fuel oil, and natural gas at typical thermal power stations (TPS) and a boiler plant. We focus on the most hazardous anthropogenic emissions of coal power industry: sulfur and nitrogen oxides. The research findings show that these emissions may be several times lower if coal and oil processing wastes are mixed with water as compared to the combustion of traditional pulverized coal, even of high grades. The study focuses on wastes, such as filter cakes, oil sludge, waste industrial oils, heavy coal-tar products, resins, etc., that are produced and stored in abundance. Their deep conversion is very rare due to low economic benefit. Effective ways are necessary to recover such industrial wastes. We present the cost assessment of the changes to the heat and power generation technologies that are required from typical power plants for switching from coal, fuel oil and natural gas to CWSPs based on coal and oil processing wastes. The corresponding technological changes pay off after a short time, ranging from several months to several years. The most promising components for CWSP production have been identified, which provide payback within a year. Among these are filter cakes (coal processing wastes), which are produced as a ready-made coal-water slurry fuel (a mixture of flocculants, water, and fine coal dust). These fuels have the least impact on the environment in terms of the emissions of sulfur and nitrogen oxides as well as fly ash. An important conclusion of the study is that using CWSPs based on filter cakes is worthwhile both as the main fuel for thermal power stations and boiler plants and as starting fuel. Copyright © 2017 Elsevier B.V. All rights reserved.

Waste biorefinery models towards sustainable circular bioeconomy: Critical review and future perspectives.

Science.gov (United States)

Venkata Mohan, S; Nikhil, G N; Chiranjeevi, P; Nagendranatha Reddy, C; Rohit, M V; Kumar, A Naresh; Sarkar, Omprakash

2016-09-01

Increased urbanization worldwide has resulted in a substantial increase in energy and material consumption as well as anthropogenic waste generation. The main source for our current needs is petroleum refinery, which have grave impact over energy-environment nexus. Therefore, production of bioenergy and biomaterials have significant potential to contribute and need to meet the ever increasing demand. In this perspective, a biorefinery concept visualizes negative-valued waste as a potential renewable feedstock. This review illustrates different bioprocess based technological models that will pave sustainable avenues for the development of biobased society. The proposed models hypothesize closed loop approach wherein waste is valorised through a cascade of various biotechnological processes addressing circular economy. Biorefinery offers a sustainable green option to utilize waste and to produce a gamut of marketable bioproducts and bioenergy on par to petro-chemical refinery. Copyright © 2016 Elsevier Ltd. All rights reserved.

Petrochemical activity in France. 2005-2008 data

International Nuclear Information System (INIS)

2010-01-01

About 12% of the French consumption of petroleum products is used as raw material for organic chemistry. In this case, more than 80% of the carbon content of petroleum products is not released in the atmosphere but included in products, like plastic materials, with an added-value. The inquiry carried out by the Service of observation and statistics (SOeS) shows the good health of the petrochemical activity from 2005 to 2007, and then a clear fall in 2008. This fall is explained by a double change: a strong rise of oil prices in the beginning of 2008 with a direct impact on the raw material cost, and the economic crisis which carried much weight on the demand at the end of the year. (J.S.)

Can we talk? Communications management for the Waste Isolation Pilot Plant, a complex nuclear waste management project

Energy Technology Data Exchange (ETDEWEB)

Goldstein, S.A.; Pullen, G.M.; Brewer, D.R.

1995-07-01

Sandia Nuclear Waste Management Program is pursuing for DOE an option for permanently disposing radioactive waste in deep geologic repositories. Included in the Program are the Waste Isolation Pilot Plant (WIPP) Project for US defense program mixed waste the Yucca Mountain Project (YMP) for spent power reactor fuel and vitrified high-level waste, projects for other waste types, and development efforts in environmental decision support technologies. WIPP and YMP are in the public arena, of a controversial nature, and provide significant management challenges. Both projects have large project teams, multiple organization participants, large budgets, long durations, are very complex, have a high degree of programmatic risk, and operate in an extremely regulated environment requiring legal defensibility. For environmental projects like these to succeed, SNL`s Program is utilizing nearly all areas in PMI`s Project Management Body of Knowledge (PMBOK) to manage along multiple project dimensions such as the physical sciences (e.g., geophysics and geochemistry; performance assessment; decision analysis) management sciences (controlling the triple constraint of performance, cost and schedule), and social sciences (belief systems; public participation; institutional politics). This discussion focuses primarily on communication challenges active on WIPP. How is the WIPP team meeting the challenges of managing communications?`` and ``How are you approaching similar challenges?`` will be questions for a dialog with the audience.

Biomassa, atividade microbiana e fungos micorrízicos em solo de "landfarming" de resíduos petroquímicos Biomass, microbial activity and mycorrhizal fungi in landfarming soil of petrochemical wastes

Directory of Open Access Journals (Sweden)

Alessandra M. de Paula

2006-06-01

Full Text Available Avaliaram-se, no presente trabalho, a biomassa microbiana, atividade heterotrófica e a ocorrência de fungos micorrízicos arbusculares (FMAs de um solo de área de "landfarming" de resíduo petroquímico durante 15 anos. Realizaram-se análises laboratoriais e ensaios em casa de vegetação para avaliar as condições biológicas do solo e o efeito da inoculação com FMAs (Glomus clarum e Paraglomus occultum no crescimento de seis espécies vegetais com potencial para estabelecimento nesses solos. A biomassa microbiana e os indicadores de atividade bioquímica (respiração basal, respiração induzida por substrato e qCO2 apresentaram-se em valores típicos de solos não contaminados, exceto para o qCO2, que foram bem elevados. Esses resultados indicam a presença de comunidades microbianas ativas mas se verificou baixa atividade das enzimas b-glicosidase, fosfatase ácida e urease, indicando interferências nos processos bioquímicos do solo o que poderá comprometer sua capacidade de transformar os resíduos. Verificou-se também a ocorrência abundante de FMAs em plantas espontâneas ou introduzidas. Foi notória a resposta positiva da inoculação com FMAs sobre o crescimento da alfafa, braquiária e sorgo, porém sem influência no crescimento do capim-elefante. Esses resultados apontam a existência de populações microbianas tolerantes aos componentes tóxicos dos resíduos petroquímicos aplicados continuamente ao solo estudado.In the present study the microbial biomass, heterotrophic activity and the occurrence of arbuscular mycorrhizal fungi (AMF were evaluated in soil samples from a landfarming area that has been used for petrochemical waste treatment for the last fifteen years. Laboratory analysis and greenhouse assays were conducted in order to evaluate soil biological conditions and the effects of inoculation with AMF (Glomus clarum and Paraglomus occultum on growth of six plant species with potential to establish in soil

Back to hewers of wood and drawers of water : energy, trade and the demise of petrochemicals in Alberta

International Nuclear Information System (INIS)

Turner, T.E.; Gibson, D.

2005-09-01

One of the consequences of The North American Free Trade Agreement (NAFTA) has been that Canadians no longer have the ability to manage the price and supply of natural gas or regulate exports. The rising price of oil and natural gas has had a profound impact on the petrochemicals industry, which is heavily reliant on natural gas as both an input and an energy source. This study focused on the recent closure of Celanese, one of the oldest petrochemical plants in Alberta. The closure was linked to natural gas and supply changes and placed in the context of broader trends in the petrochemicals industry as well as to the lack of energy and industrial strategies in Alberta. The study suggested that the causal factors in natural gas price and supply changes revolved around NAFTA, gas and pipeline policies and export policies. Significant changes resulting from these agreements and policies included national treatment rules; the opening of the energy sector to foreign corporations; the prohibition of preferential pricing for Canadian industries; the elimination of export taxes; impact assessment requirements for export licences; and the introduction of the proportional sharing requirement whereby current export levels are guaranteed to the United States. It was suggested that these changes had the effect of increasing exports while reserves began to decline. Recommendations were made regarding renewed export, environmental and energy strategies and policies. It was concluded that the petrochemicals industry could be supported by a more effective energy resource management strategy that prioritized Canadian consumers. 107 refs., 1 tab., 5 figs

Investigating the causes of human error-induced incidents in the maintenance operations of petrochemical industry by using HFACS

Directory of Open Access Journals (Sweden)

Mohammadreza Azhdari

2017-03-01

Full Text Available Background & Objectives: Maintenance is an important tool for the petrochemical industries to prevent of accidents and increase operational and process safety success. The purpose of this study was to identify the possible causes of incidents caused by human error in the petrochemical maintenance activities by using Human Factors Analysis and Classification System (HFACS. Methods: This study is a cross-sectional analysis that was conducted in Zagros Petrochemical Company, Asaluyeh-Iran. A checklist of human error-induced incidents was developed based on four HFACS main levels and nineteen sub-groups. Hierarchical task analysis (HTA technique was used to identify maintenance activities and tasks. The main causes of possible incidents were identified by checklist and recorded. Corrective and preventive actions were defined depending on priority.   Results: The content analysis of worksheets of 444 activities showed 37.6% of the causes at the level of unsafe actions, 27.5% at the level of unsafe supervision, 20.9% at the level of preconditions for unsafe acts and 14% of the causes at the level of organizational effects. The HFACS sub-groups showed errors (24.36% inadequate supervision (14.89% and violations (13.26% with the most frequency. Conclusion: In order to prevent and reduce the occurrence of the identified errors, reducing the rate of the detected errors is crucial. Findings of this study showed that appropriate controlling measures such as periodical training of work procedures and supervision improvement decrease the human error-induced incidents in petrochemical industry maintenance.

Basic survey project for Joint Implementation, etc. for energy conservation in ethylene production at Yangzi Petrochemical Company

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

For the purpose of reducing greenhouse effect gas emissions, a potential study was conducted of energy conservation in Yangzi Petrochemical Company in Nanking City, China. The project is aimed at realizing energy conservation and reduction in greenhouse effect gas emissions by generating power by installation of gas turbine and by using waste gas as fuel for ethylene cracking furnace. In the project, the following are carried out: introduction of 35MW gas turbine generator, and repairs of fuel burner of ethylene cracking furnace, fuel gas compressor of gas turbine, emergency use air blower, duct, etc. The construction work is to be done in 30 months from April, 2005. The initial investment is approximately 45 million US$. The energy conservation to be brought by this project is 37,958 tons/year, or 759,160 tons in the total project term. Further, the reduction amount of greenhouse effect gas emissions is 117,452 CO2 tons/year, or 2,349,040 CO2 tons in the total project term. (NEDO)

Energy Efficiency Improvement and Cost Saving Opportunities for the Petrochemical Industry - An ENERGY STAR(R) Guide for Energy and Plant Managers

Energy Technology Data Exchange (ETDEWEB)

Neelis, Maarten; Worrell, Ernst; Masanet, Eric

2008-09-01

Energy is the most important cost factor in the U.S petrochemical industry, defined in this guide as the chemical industry sectors producing large volume basic and intermediate organic chemicals as well as large volume plastics. The sector spent about $10 billion on fuels and electricity in 2004. Energy efficiency improvement is an important way to reduce these costs and to increase predictable earnings, especially in times of high energy price volatility. There are a variety of opportunities available at individual plants in the U.S. petrochemical industry to reduce energy consumption in a cost-effective manner. This Energy Guide discusses energy efficiency practices and energy efficient technologies that can be implemented at the component, process, facility, and organizational levels. A discussion of the trends, structure, and energy consumption characteristics of the petrochemical industry is provided along with a description of the major process technologies used within the industry. Next, a wide variety of energy efficiency measures are described. Many measure descriptions include expected savings in energy and energy-related costs, based on case study data from real-world applications in the petrochemical and related industries worldwide. Typical measure payback periods and references to further information in the technical literature are also provided, when available. The information in this Energy Guide is intended to help energy and plant managers in the U.S. petrochemical industry reduce energy consumption in a cost-effective manner while maintaining the quality of products manufactured. Further research on the economics of all measures--and on their applicability to different production practices--is needed to assess their cost effectiveness at individual plants.

Process Knowledge Summary Report for Materials and Fuels Complex Contact-Handled Transuranic Debris Waste

Energy Technology Data Exchange (ETDEWEB)

R. P. Grant; P. J. Crane; S. Butler; M. A. Henry

2010-02-01

This Process Knowledge Summary Report summarizes the information collected to satisfy the transportation and waste acceptance requirements for the transfer of transuranic (TRU) waste between the Materials and Fuels Complex (MFC) and the Advanced Mixed Waste Treatment Project (AMWTP). The information collected includes documentation that addresses the requirements for AMWTP and the applicable portion of their Resource Conservation and Recovery Act permits for receipt and treatment of TRU debris waste in AMWTP. This report has been prepared for contact-handled TRU debris waste generated by the Idaho National Laboratory at MFC. The TRU debris waste will be shipped to AMWTP for purposes of supercompaction. This Process Knowledge Summary Report includes information regarding, but not limited to, the generation process, the physical form, radiological characteristics, and chemical contaminants of the TRU debris waste, prohibited items, and packaging configuration. This report, along with the referenced supporting documents, will create a defensible and auditable record for waste originating from MFC.

Waste management under multiple complexities: Inexact piecewise-linearization-based fuzzy flexible programming

International Nuclear Information System (INIS)

Sun Wei; Huang, Guo H.; Lv Ying; Li Gongchen

2012-01-01

Highlights: ► Inexact piecewise-linearization-based fuzzy flexible programming is proposed. ► It’s the first application to waste management under multiple complexities. ► It tackles nonlinear economies-of-scale effects in interval-parameter constraints. ► It estimates costs more accurately than the linear-regression-based model. ► Uncertainties are decreased and more satisfactory interval solutions are obtained. - Abstract: To tackle nonlinear economies-of-scale (EOS) effects in interval-parameter constraints for a representative waste management problem, an inexact piecewise-linearization-based fuzzy flexible programming (IPFP) model is developed. In IPFP, interval parameters for waste amounts and transportation/operation costs can be quantified; aspiration levels for net system costs, as well as tolerance intervals for both capacities of waste treatment facilities and waste generation rates can be reflected; and the nonlinear EOS effects transformed from objective function to constraints can be approximated. An interactive algorithm is proposed for solving the IPFP model, which in nature is an interval-parameter mixed-integer quadratically constrained programming model. To demonstrate the IPFP’s advantages, two alternative models are developed to compare their performances. One is a conventional linear-regression-based inexact fuzzy programming model (IPFP2) and the other is an IPFP model with all right-hand-sides of fussy constraints being the corresponding interval numbers (IPFP3). The comparison results between IPFP and IPFP2 indicate that the optimized waste amounts would have the similar patterns in both models. However, when dealing with EOS effects in constraints, the IPFP2 may underestimate the net system costs while the IPFP can estimate the costs more accurately. The comparison results between IPFP and IPFP3 indicate that their solutions would be significantly different. The decreased system uncertainties in IPFP’s solutions demonstrate

Mobile loading transuranic waste at small quantity sites in the Department of Energy complex-10523

International Nuclear Information System (INIS)

Carter, Mitch; Howard, Bryan; Weyerman, Wade; Mctaggart, Jerri

2009-01-01

Los Alamos National Laboratory, Carlsbad Office (LANL-CO), operates mobile loading operations for all of the large and small quantity transuranic (TRU) waste sites in the Department of Energy (DOE) complex. The mobile loading team performs loading and unloading evolutions for both contact handled (CH) and remote handled (RH) waste. For small quantity sites, many of which have yet to remove their TRU waste, the mobile loading team will load shipments that will ship to Idaho National Laboratory, a centralization site, or ship directly to the Waste Isolation Pilot Plant (WIPP). For example, Argonne National Laboratory and General Electric Vallecitos Nuclear Center have certified programs for RH waste so they will ship their RH waste directly to WIPP. Many of the other sites will ship their waste to Idaho for characterization and certification. The Mobile Loading Units (MLU) contain all of the necessary equipment needed to load CH and RH waste into the appropriate shipping vessels. Sites are required to provide additional equipment, such as cranes, fork trucks, and office space. The sites are also required to provide personnel to assist in the shipping operations. Each site requires a site visit from the mobile loading team to ensure that all of the necessary site equipment, site requirements and space for shipping can be provided. The mobile loading team works diligently with site representatives to ensure that all safety and regulatory requirements are met. Once the waste is ready and shipping needs are met, the mobile loading team can be scheduled to ship the waste. The CH MLU is designed to support TRUPACT-II and HalfPACT loading activities wherever needed within the DOE complex. The team that performs the mobile loading operation has obtained national certification under DOE for TRUPACT-II and HalfPACT loading and shipment certification. The RH MLU is designed to support removable lid canister (RLC) and RH-72B cask loading activities wherever needed within the DOE

Evaluation of the toxicity of organic matter in marine sediments

Digital Repository Service at National Institute of Oceanography (India)

Sarkar, A.

stream_size 3 stream_content_type text/plain stream_name 2_Int_Conf_Waste_Mgmt_Chem_Petrochem_Ind_Toxic_Mgmt_1991_258.pdf.txt stream_source_info 2_Int_Conf_Waste_Mgmt_Chem_Petrochem_Ind_Toxic_Mgmt_1991_258.pdf.txt Content...

2016 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site's Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond

International Nuclear Information System (INIS)

Cafferty, Kara Grace

2017-01-01

This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (WRU-I-0160-01, Modification 1, formerly LA 000160 01), for the wastewater reuse site at the Idaho National Laboratory Site's Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond from November 1, 2015, through October 31, 2016.

Radiological and chemical source terms for Solid Waste Operations Complex

International Nuclear Information System (INIS)

Boothe, G.F.

1994-01-01

The purpose of this document is to describe the radiological and chemical source terms for the major projects of the Solid Waste Operations Complex (SWOC), including Project W-112, Project W-133 and Project W-100 (WRAP 2A). For purposes of this document, the term ''source term'' means the design basis inventory. All of the SWOC source terms involve the estimation of the radiological and chemical contents of various waste packages from different waste streams, and the inventories of these packages within facilities or within a scope of operations. The composition of some of the waste is not known precisely; consequently, conservative assumptions were made to ensure that the source term represents a bounding case (i.e., it is expected that the source term would not be exceeded). As better information is obtained on the radiological and chemical contents of waste packages and more accurate facility specific models are developed, this document should be revised as appropriate. Radiological source terms are needed to perform shielding and external dose calculations, to estimate routine airborne releases, to perform release calculations and dose estimates for safety documentation, to calculate the maximum possible fire loss and specific source terms for individual fire areas, etc. Chemical source terms (i.e., inventories of combustible, flammable, explosive or hazardous chemicals) are used to determine combustible loading, fire protection requirements, personnel exposures to hazardous chemicals from routine and accident conditions, and a wide variety of other safety and environmental requirements

Materials and Fuels Complex Facilities Radioactive Waste Management Basis and DOE Manual 435.1-1 Compliance Tables

Energy Technology Data Exchange (ETDEWEB)

Lisa Harvego; Brion Bennett

2011-09-01

Department of Energy Order 435.1, 'Radioactive Waste Management,' along with its associated manual and guidance, requires development and maintenance of a radioactive waste management basis for each radioactive waste management facility, operation, and activity. This document presents a radioactive waste management basis for Idaho National Laboratory's Materials and Fuels Complex facilities that manage radioactive waste. The radioactive waste management basis for a facility comprises existing laboratory-wide and facility-specific documents. Department of Energy Manual 435.1-1, 'Radioactive Waste Management Manual,' facility compliance tables also are presented for the facilities. The tables serve as a tool for developing the radioactive waste management basis.

Materials and Fuels Complex Facilities Radioactive Waste Management Basis and DOE Manual 435.1-1 Compliance Tables

International Nuclear Information System (INIS)

Harvego, Lisa; Bennett, Brion

2011-01-01

Department of Energy Order 435.1, 'Radioactive Waste Management,' along with its associated manual and guidance, requires development and maintenance of a radioactive waste management basis for each radioactive waste management facility, operation, and activity. This document presents a radioactive waste management basis for Idaho National Laboratory's Materials and Fuels Complex facilities that manage radioactive waste. The radioactive waste management basis for a facility comprises existing laboratory-wide and facility-specific documents. Department of Energy Manual 435.1-1, 'Radioactive Waste Management Manual,' facility compliance tables also are presented for the facilities. The tables serve as a tool for developing the radioactive waste management basis.

Toxicity Assessment of Contaminated Soils of Solid Domestic Waste Landfill

Science.gov (United States)

Pasko, O. A.; Mochalova, T. N.

2014-08-01

The paper delivers the analysis of an 18-year dynamic pattern of land pollutants concentration in the soils of a solid domestic waste landfill. It also presents the composition of the contaminated soils from different areas of the waste landfill during its operating period. The authors calculate the concentrations of the following pollutants: chrome, nickel, tin, vanadium, lead, cuprum, zinc, cobalt, beryllium, barium, yttrium, cadmium, arsenic, germanium, nitrate ions and petrochemicals and determine a consistent pattern of their spatial distribution within the waste landfill area as well as the dynamic pattern of their concentration. Test-objects are used in experiments to make an integral assessment of the polluted soil's impact on living organisms. It was discovered that the soil samples of an animal burial site are characterized by acute toxicity while the area of open waste dumping is the most dangerous in terms of a number of pollutants. This contradiction can be attributed to the synergetic effect of the polluted soil, which accounts for the regularities described by other researchers.

Safety Culture Assessment in Petrochemical Industry: A Comparative Study of Two Algerian Plants

Directory of Open Access Journals (Sweden)

Assia Boughaba

2014-06-01

Conclusion: The comparison between the two petrochemical plants of the group Sonatrach confirms these results in which Company A, the managers of which are English and Norwegian, distinguishes itself by the maturity of their safety culture has significantly higher evaluations than the company B, who is constituted of Algerian staff, in terms of safety management practices and safety performance.

Routine organic air emissions at the Radioactive Waste Management Complex Waste Storage Facilities fiscal year 1995 report

International Nuclear Information System (INIS)

Galloway, K.J.; Jolley, J.G.

1995-12-01

This report presents the data and results of the routine organic air emissions monitoring performed in the Radioactive Waste Management Complex Waste Storage Facility, WMF-628, from January 4, 1995 to September 3, 1995. The task objectives were to systematically identify and measure volatile organic compound (VOC) concentrations within WMF-628 that could be emitted into the environment. These routine measurements implemented a dual method approach using Open-Path Fourier Transform Infrared Spectroscopy (OP-FTIR) monitoring and the Environmental Protection Agency (EPA) analytical method TO-14, Summa reg-sign Canister sampling. The data collected from the routine monitoring of WNF-628 will assist in estimating the total VOC emissions from WMF-628

Two-dimensional gas chromatography-online hydrogenation for improved characterization of petrochemical samples.

Science.gov (United States)

Potgieter, H; Bekker, R; Govender, A; Rohwer, E

2016-05-06

The Fischer-Tropsch (FT) process produces a variety of hydrocarbons over a wide carbon number range and during subsequent product workup a large variety of synthetic fuels and chemicals are produced. The complexity of the product slate obtained from this process is well documented and the high temperature FT (HT-FT) process products are spread over gas, oil and water phases. The characterization of these phases is very challenging even when using comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS). Despite the increase in separation power, peak co-elution still occurs when samples containing isomeric compounds are analysed by comprehensive two dimensional GC. The separation of isomeric compounds with the same double bond equivalents is especially difficult since these compounds elute in a similar position on the GC×GC chromatogram and have identical molecular masses and similar fragmentation patterns in their electron ionization (EI) mass spectra. On-line hydrogenation after GC×GC separation is a possible way to distinguish between these isomeric compounds since the number of rings and alkene double bonds can be determined from the mass spectra of the compounds before and after hydrogenation. This paper describes development of a GC×GC method with post column hydrogenation for the determination of the backbone of cyclic/olefinic structures enabling us to differentiate between classes like dienes and cyclic olefins in complex petrochemical streams. Copyright © 2016 Elsevier B.V. All rights reserved.

SCIENTIFIC METHODOLOGICAL APPROACHES TO CREATION OF COMPLEX CONTROL SYSTEM MODEL FOR THE STREAMS OF BUILDING WASTE

Directory of Open Access Journals (Sweden)

Tskhovrebov Eduard Stanislavovich

2015-09-01

Full Text Available In 2011 in Russia a Strategy of Production Development of Construction Materials and Industrial Housing Construction for the period up to 2020 was approved as one of strategic documents in the sphere of construction. In the process of this strategy development all the needs of construction complex were taken into account in all the spheres of economy, including transport system. The strategy also underlined, that the construction industry is a great basis for use and application in secondary economic turnover of dangerous waste from different production branches. This gives possibility to produce construction products of recycled materials and at the same time to solve the problem of environmental protection. The article considers and analyzes scientific methodological approaches to creation of a model of a complex control system for the streams of building waste in frames of organizing uniform ecologically safe and economically effective complex system of waste treatment in country regions.

Fundamental chemistry, characterization, and separation of technetium complexes in Hanford waste. 1998 annual progress report

International Nuclear Information System (INIS)

Ashley, K.R.; Blanchard, D.L. Jr.; Schroeder, N.C.

1998-01-01

'The ultimate goal of this proposal is to separate technetium from Hanford tank waste. The recent work has shown that a large portion of the technetium is not pertechnetate (TcO 4 - ) and is not easily oxidized. This has serious repercussions for technetium partitioning schemes because they are designed to separate this chemical form. Rational attempts to oxidize these species to TcO 4 - for processing or to separate the non-pertechnetate species themselves would be facilitated by knowing the identity of these complexes and understanding their fundamental chemistry. Tank characterization work has not yet identified any of the non-pertechnetate species. However, based on the types of ligands available and the redox conditions in the tank, a reasonable speculation can be made about the types of species that may be present. Thus, this proposal will synthesize and characterize the relevant model complexes of Tc(III), Tc(IV), and Tc(V) that may have formed under tank waste conditions. Once synthesized, these complexes will be used as standards for developing and characterizing the non-pertechnetate species in actual waste using instrumental techniques such as capillary electrophoresis electrospray mass spectrometry (CE-MS), x-ray absorbance spectroscopy (EXAFS and XANES), and multi-nuclear NMR (including 99 Tc NMR). The authors study the redox chemistry of the technetium complexes so that more efficient and selective oxidative methods can be used to bring these species to TcO 4 - for processing purposes. They will also study their ligand substitution chemistry which could be used to develop separation methods for non-pertechnetate species. Understanding the fundamental chemistry of these technetium complexes will enable technetium to be efficiently removed from the Hanford tank waste and help DOE to fulfill its remediation mission. This report summarizes the first 8 months of a 3-year project.'

Waste analysis plan for T Plant Complex

International Nuclear Information System (INIS)

Williams, J.F.

1996-01-01

Washington Administration Code 173-303-300 requires that a waste analysis plan (WAP) be provided by a treatment, storage, and/or disposal (TSD) unit to confirm their knowledge about a dangerous and/or mixed waste to ensure that the waste is managed properly. The specific objectives of the WAP are as follows: Ensure safe management of waste during treatment and storage; Ensure that waste generated during operational activities is properly designated in accordance with regulatory requirements; Provide chemical and physical analysis of representative samples of the waste stored for characterization and/or verification before the waste is transferred to another TSD unit; Ensure compliance with land disposal restriction (LDR) requirements for treated waste; and Provide basis for work plans that describes waste analysis for development of new treatment technologies

Hydrocarbon Source Signatures in Houston, Texas: Influence of the Petrochemical Industry

Energy Technology Data Exchange (ETDEWEB)

Jobson, B Tom T; Berkowitz, Carl M; Kuster, W C; Goldan, P D; Williams, E J; Fesenfeld, F; Apel, Eric; Karl, Thomas G; Lonneman, William A; Riemer, D

2004-12-22

Observations of C1-C10 hydrocarbon mixing ratios measured by in-situ instrumentation at the La Porte super site during the TexAQS 2000 field experiment are reported. The La Porte data were compared to a roadway vehicle exhaust signature obtained from canister samples collected in the Houston Washburn tunnel during the same summer to better understand the impact of petrochemical emissions of hydrocarbons at the site. It is shown that the abundance of ethene, propene, 1-butene, C2-C4 alkanes, hexane, cyclohexane, methylcyclohexane, isopropylbenzene, and styrene at La Porte were systematically impacted by petrochemical industry emissions. Coherent power law relationships between frequency distribution widths of hydrocarbon mixing ratios and their local lifetimes clearly identify two major source groups, roadway vehicle emissions and industrial emissions. Distributions of most aromatics and long chain alkanes were consistent with roadway vehicle emissions as the dominant source. Airmass reactivity was generally dominated by C1-C3 aldehydes. Propene and ethene sometimes dominated air mass reactivity with HO loss frequencies often greater than 10 s-1. Ozone mixing ratios near 200 ppbv were observed on two separate occasions and these air masses appear to have been impacted by industrial emissions of alkenes from the Houston Ship Channel. The La Porte data provide evidence of the importance of industrial emissions of ethene and propene on air masses reactivity and ozone formation in Houston.

Mixed Waste Focus Area: Department of Energy complex needs report

International Nuclear Information System (INIS)

Roach, J.A.

1995-01-01

The Assistant Secretary for the Office of Environmental Management (EM) at the US Department of Energy (DOE) initiated a new approach in August of 1993 to environmental research and technology development. A key feature of this new approach included establishment of the Mixed Waste Characterization, Treatment, and Disposal Focus Area (MWFA). The mission of the MWFA is to identify, develop, and implement needed technologies such that the major environmental management problems related to meeting DOE's commitments for treatment of mixed wastes under the Federal Facility Compliance Act (FFCA), and in accordance with the Land Disposal Restrictions (LDR) of the Resource Conservation and Recovery Act (RCRA), can be addressed, while cost-effectively expending the funding resources. To define the deficiencies or needs of the EM customers, the MWFA analyzed Proposed Site Treatment Plans (PSTPs), as well as other applicable documents, and conducted site visits throughout the summer of 1995. Representatives from the Office of Waste Management (EM-30), the Office of Environmental Restoration (EM-40), and the Office of Facility Transition and Management (EM-60) at each site visited were requested to consult with the Focus Area to collaboratively define their technology needs. This report documents the needs, deficiencies, technology gaps, and opportunities for expedited treatment activities that were identified during the site visit process. The defined deficiencies and needs are categorized by waste type, namely Wastewaters, Combustible Organics, Sludges/Soils, Debris/Solids, and Unique Wastes, and will be prioritized based on the relative affect the deficiency has on the DOE Complex

2016 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site’s Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond

Energy Technology Data Exchange (ETDEWEB)

Cafferty, Kara Grace [Idaho National Lab. (INL), Idaho Falls, ID (United States)

2017-02-01

This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (WRU-I-0160-01, Modification 1, formerly LA 000160 01), for the wastewater reuse site at the Idaho National Laboratory Site’s Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond from November 1, 2015, through October 31, 2016.

The Effectiveness of Communication Skills Training to Increase Job Satisfaction and Job Performance of Employees in Bandar Imam Petrochemical Plant in Mahshahr

OpenAIRE

Shayesteh Khaleghi; Rezvan Homaei

2017-01-01

The aim of this study was to determine the effectiveness of communication skills training to increase job satisfaction and job performance in employees of Bandar Imam petrochemical plant in Mahshahr in 2016. The statistical population consisted of all employees of Bandar Imam petrochemical plant in Mahshahr in 2015. 30 employees who were selected by convenient sampling constituted the sample of the study and were assigned to experimental and control groups (15=experiment and 15=control).  The...

Efficient Simulation Modeling of an Integrated High-Level-Waste Processing Complex

International Nuclear Information System (INIS)

Gregory, Michael V.; Paul, Pran K.

2000-01-01

An integrated computational tool named the Production Planning Model (ProdMod) has been developed to simulate the operation of the entire high-level-waste complex (HLW) at the Savannah River Site (SRS) over its full life cycle. ProdMod is used to guide SRS management in operating the waste complex in an economically efficient and environmentally sound manner. SRS HLW operations are modeled using coupled algebraic equations. The dynamic nature of plant processes is modeled in the form of a linear construct in which the time dependence is implicit. Batch processes are modeled in discrete event-space, while continuous processes are modeled in time-space. The ProdMod methodology maps between event-space and time-space such that the inherent mathematical discontinuities in batch process simulation are avoided without sacrificing any of the necessary detail in the batch recipe steps. Modeling the processes separately in event- and time-space using linear constructs, and then coupling the two spaces, has accelerated the speed of simulation compared to a typical dynamic simulation. The ProdMod simulator models have been validated against operating data and other computer codes. Case studies have demonstrated the usefulness of the ProdMod simulator in developing strategies that demonstrate significant cost savings in operating the SRS HLW complex and in verifying the feasibility of newly proposed processes

Making and Doing Politics Through Grassroots Scientific Research on the Energy and Petrochemical Industries

Directory of Open Access Journals (Sweden)

Sara Wylie

2017-09-01

Full Text Available The high stakes of emergent environmental crises, from climate change to widespread toxic exposures, have motivated STS practitioners to innovate methodologically, including leveraging STS scholarship to actively remake environmental scientific practice and technologies. This thematic collection brings together current research that transforms how communities and academics identify, study, and collectively respond to contaminants engendered by the fossil fuel and petrochemical industries, including air contamination from hydraulic fracking, marine pollution from petroleum-derived plastics, and hydrocarbon derivatives such as formaldehyde that intoxicate our homes. These interventions make inroads into the “undone science” and “regimes of imperceptibility” of environmental health crises. Authors, most of whom are practitioners, investigate grassroots methods for collaboratively designing and developing low-cost monitoring tools, crowdsourcing data analysis, and imagining ways of redressing toxicity outside of the idioms of science. Collectively, these articles work towards remaking how knowledge is made about and across industrial systems by networking community grounded approaches for accounting for environmental health issues created by the fossil fuels and allied petrochemical industries.

Microbial surfactant activities from a petrochemical landfarm in a humid tropical region of Brazil

Energy Technology Data Exchange (ETDEWEB)

Maciel, B.M.; Dias, J.C.T.; Santos, A.C.F.; Argolo-Filho, R.C.; Fontana, R.; Loguercio, L.L.; Rezende, R.P. [Univ. Estadual de Santa Cruz, Santa Cruz (Brazil). Dept. de Ciencias Biologicas

2007-08-15

Studies have suggested that biosurfactants can enhance the biodegradation of almost insoluble organics by increasing cell uptake availability. In this study, micro-organisms were isolated from a soil sample from a Brazilian petrochemical waste landfarm and grown in petroleum as a carbon source in order to assess their surfactant potential. Isolated colonies were inoculated into tubes, and a drop-collapse method was used to select micro-organisms with surfactant activity. Surfactant activity of the isolates was assessed when the activity was detected for the first time in each culture. The supernatant of each micro-organism was then diluted. The surfactant activity of each dilution was then observed via micelles formation. DNA was then extracted from the samples. A total of 60 microbial strains were selected. Results showed that a variety of petroleum-grown micro-organisms obtained from the landfarm soil showed surfactant activity. Results showed that the micro-organisms were able to use petroleum as a sole carbon source. The production of surfactant compounds occurred during the declining stages of microbial culture curves, which suggested that the nutritional stress achieved on the fourth day of the culture induced the synthesis and secretion of biosurfactants by the isolates. It was concluded that micro-organisms derived from soils polluted with hydrocarbons can be used in bioremediation processes. 21 refs., 1 tab., 3 figs.

Recycling and recovery routes of plastic solid waste (PSW): A review

International Nuclear Information System (INIS)

Al-Salem, S.M.; Lettieri, P.; Baeyens, J.

2009-01-01

Plastic solid waste (PSW) presents challenges and opportunities to societies regardless of their sustainability awareness and technological advances. In this paper, recent progress in the recycling and recovery of PSW is reviewed. A special emphasis is paid on waste generated from polyolefinic sources, which makes up a great percentage of our daily single-life cycle plastic products. The four routes of PSW treatment are detailed and discussed covering primary (re-extrusion), secondary (mechanical), tertiary (chemical) and quaternary (energy recovery) schemes and technologies. Primary recycling, which involves the re-introduction of clean scrap of single polymer to the extrusion cycle in order to produce products of the similar material, is commonly applied in the processing line itself but rarely applied among recyclers, as recycling materials rarely possess the required quality. The various waste products, consisting of either end-of-life or production (scrap) waste, are the feedstock of secondary techniques, thereby generally reduced in size to a more desirable shape and form, such as pellets, flakes or powders, depending on the source, shape and usability. Tertiary treatment schemes have contributed greatly to the recycling status of PSW in recent years. Advanced thermo-chemical treatment methods cover a wide range of technologies and produce either fuels or petrochemical feedstock. Nowadays, non-catalytic thermal cracking (thermolysis) is receiving renewed attention, due to the fact of added value on a crude oil barrel and its very valuable yielded products. But a fact remains that advanced thermo-chemical recycling of PSW (namely polyolefins) still lacks the proper design and kinetic background to target certain desired products and/or chemicals. Energy recovery was found to be an attainable solution to PSW in general and municipal solid waste (MSW) in particular. The amount of energy produced in kilns and reactors applied in this route is sufficiently

Application of Interval Type-2 Fuzzy Logic to polypropylene business policy in a petrochemical plant in India

Directory of Open Access Journals (Sweden)

Dipak Kumar Jana

2018-01-01

Full Text Available This paper presents a new approach to predict the quality of polypropylene in petrochemical plants. The proposed approach constructs four different models, based on a large number of data collected from a renowned petrochemical plant in India and uses it to predict the polypropylene quality. The quality of polypropylene depends on the indices such as melt flow index and the xylene solubility of the product and the parameters controlling these two indices are hydrogen flow, donor flow, pressure and temperature of polymerization reactors. Mamdani Interval Type-2 Fuzzy Logic inference systems are formed for first time. The model outcomes are compared with the collected plant data and a sequence of sensitivity analysis elects the most suitable model from them. Some sensitivity analyses are provided using Fuzzy C-Means Clustering to the models.

Use of glass-reinforced plastic vessels in petrochemical production plants

International Nuclear Information System (INIS)

Makarov, V.G.; Baikin, V.G.; Perlin, S.M.

1984-01-01

At present, petrochemical plant production equipment is made of scarce high-alloy steels and alloys or carbon steel with subsequent chemical protection. Traditional methods of protection frequently do not provide reliable and safe service of equipment for the length of the normal operating life. One of the effective methods of combatting corrosion is the use of glass-reinforced plastic equipment. Glass-reinforced equipment is not subject to electrochemical corrosion and has a high chemical resistance. Weight is approximately a third of similar vessels. The paper provides recommendations and precautions for the production, installation, use and maintenance of glass-reinforced plastic vessels

COMPLEX PROCESSING OF CELLULOSE WASTE FROM POULTRY AND SUGAR PRODUCTION

Directory of Open Access Journals (Sweden)

E. V. Sklyadnev

2015-01-01

Full Text Available Summary.To solve the problem of disposing of huge volumes of cellulose waste from sugar production in the form of beet pulp and waste of poultry farms in the form of poultry manure is proposed to use the joint use of two methods of thermal processing of waste - pyrolysis and gasification. The possibility of using pyrolysis applied to the waste are confirmed by experimental results. Based on the results of laboratory studies of the properties of by-products resulting from the thermal processing of the feedstock, it is proposed complex processing to produce useful products, to be implemented in the form of marketable products, and the organization's own process energy utilization. Developed flow diagram of an integrated processing said waste comprises 3 sections, which successively carried out: pyrolytic decomposition of the feedstock to obtain a secondary product in the form of solid, liquid and gas fractions, the gasification of solids to obtain combustible gas and separating the liquid fraction by distillation to obtain valuable products. The main equipment in the first region is the pyrolysis reactor cascade condensers; the second section - gasifiers layers and stream type; the third - one or more distillation columns with the necessary strapping. Proper power supply installation is organized by the use of the heat produced during combustion of the synthesis gas for heating and gasification reactor. For the developed scheme presents calculations of the heat balance of the installation, supporting the energy efficiency of the proposed disposal process. Developments carried out in the framework of the project the winner of the Youth Prize Competition Government of Voronezh region to support youth programs in the 2014-2015.

The Properties of Polymer-Modified Asphalt Drived from Vacuum Bottom and Wastes of PE and SBR Plants

Directory of Open Access Journals (Sweden)

A. Yousefi

2008-12-01

Full Text Available The polymeric and non-polymeric petrochemical wastes are environmentally unfavorable materials. We have to found a way to reuse these wastes in a safe manner. In styrene-butadiene rubber (SBR production plant two major wastes are produced one is a fine rubber powder and the other is recycled N-methyl pyrrolidone (NMP. In high-density polyethylene (HDPE production plant also a low molecular weight polymer waste is produced which does not degrade in environment easily. On the other hand, bitumen is usually blended with thermoplastics, rubbers and an oil to produce polymermodified bitumens. Effect of SBR, PE and NMP wastes on vacuum bottom residue of crude oil distillation was investigated. The results of penetration, softening point and Frass tests revealed the advantages of SBR and PE wastes at high temperatures and suggest NMP waste as a good bitumen extender. The results of the Marshal test on the prepared polymer-modified hot-mix asphalt of the optimum formulation highlight the superiority of its strength and its lower flow as compared with those of standard 60/70 penetration grade bitumen.

Effect of organic complexants on the mobility of low-level-waste radionuclides in soils

International Nuclear Information System (INIS)

Swanson, J.L.

1982-02-01

The effect of certain organic complexants on the distribution of some radionuclides between solution and soil has been measured. The complexants and radionuclides examined are some of those most likely to be present in low-level waste disposal sites; Cs, Sr, Ni, Co, and Eu radionuclides, and EDTA, DTPA, oxalate, and citrate complexants. The effect of complexants was found to vary widely; in some systems there was no effect and in other systems there were large effects. In some cases slow rates of reaction have not allowed equilibrium measurements to be made

Assessment of the estrogenic potency of effluents from petrochemical facilities and a petroleum refinery in Ontario

International Nuclear Information System (INIS)

Sherry, J.P.; Trepanier, T.; Tinson, C.; Munro, S.

2002-01-01

Studies have shown that wastewater from refineries could induce vitellogenin (Vg) in juvenile rainbow trout. Vg is a biomarker of exposure to estrogenic chemicals. This study reassessed the estrogenic potency of the wastewater from an Ontario refinery and assessed the estrogenicity of wastewater from 3 petrochemical facilities. A 21 day static renewal test was conducted to test the effluents and in which a competitive binding ELISA detected induced Vg. Statistical testing for tank effects was performed in a replicated tank design and the St. Clair River water from upstream industrial facilities was used as a negative reference. The positive control treatment was waterborne 17β-estradiol. Wastewater from the petroleum refinery induced Vg in the treated fish, but wastewater from the petrochemical effluents did not induce detectable levels of Vg in treated trout. The information obtained through this study will be used to determine the potential for responses in feral fish

Bio-waste corn-cob cellulose supported poly(hydroxamic acid) copper complex for Huisgen reaction: Waste to wealth approach.

Science.gov (United States)

Mandal, Bablu Hira; Rahman, Md Lutfor; Yusoff, Mashitah Mohd; Chong, Kwok Feng; Sarkar, Shaheen M

2017-01-20

Corn-cob cellulose supported poly(hydroxamic acid) Cu(II) complex was prepared by the surface modification of waste corn-cob cellulose through graft copolymerization and subsequent hydroximation. The complex was characterized by IR, UV, FESEM, TEM, XPS, EDX and ICP-AES analyses. The complex has been found to be an efficient catalyst for 1,3-dipolar Huisgen cycloaddition (CuAAC) of aryl/alkyl azides with a variety of alkynes as well as one-pot three-components reaction in the presence of sodium ascorbate to give the corresponding cycloaddition products in up to 96% yield and high turn over number (TON 18,600) and turn over frequency (TOF 930h -1 ) were achieved. The complex was easy to recover from the reaction mixture and reused six times without significant loss of its catalytic activity. Copyright © 2016 Elsevier Ltd. All rights reserved.

Mobile/portable transuranic waste characterization systems at Los Alamos National Laboratory and a model for their use complex-wide

International Nuclear Information System (INIS)

Derr, E.D.; Harper, J.R.; Zygmunt, S.J.; Taggart, D.P.; Betts, S.E.

1997-01-01

Los Alamos National Laboratory has implemented mobile and portable characterization and repackaging systems to characterize TRU waste in storage for ultimate shipment and disposal at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, NM. These mobile systems are being used to characterize and repackage waste to meet the full requirements of the WIPP Waste Acceptance Criteria (WAC) and the WIPP Characterization Quality Assurance Program Plan (QAPP). Mobile and portable characterization and repackaging systems are being used to supplement the capabilities and throughputs of existing facilities. Utilization of mobile systems is a key factor that is enabling LANL to: (1) reduce its TRU waste work-off schedule from 36 years to 8.5 years; (2) eliminate the need to construct a $70M+ TRU waste characterization facility; (3) have waste certified for shipment to WIPP when WIPP opens; (4) continue to ship TRU waste to WIPP at the rate of 5000 drums per year; and, (5) reduce overall costs by more than $200M. Aggressive implementation of mobile and portable systems throughout the DOE complex through a centralized-distributed services model will result in similar advantages complex-wide

Mobile/portable transuranic waste characterization systems at Los Alamos National Laboratory and a model for their use complex-wide

International Nuclear Information System (INIS)

Derr, E.D.; Harper, J.R.; Zygmunt, S.J.; Taggart, D.P.; Betts, S.E.

1997-01-01

Los Alamos National Laboratory (LANL) has implemented mobile and portable characterization and repackaging systems to characterize transuranic (TRU) waste in storage for ultimate shipment and disposal at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, NM. These mobile systems are being used to characterize and repackage waste to meet the full requirements of the WIPP Waste Acceptance Criteria (WAC) and the WIPP Characterization Quality Assurance Program Plan (QAPP). Mobile and portable characterization and repackaging systems are being used to supplement the capabilities and throughputs of existing facilities. Utilization of mobile systems is a key factor that is enabling LANL to (1) reduce its TRU waste work-off schedule from 36 years to 8.5 years; (2) eliminate the need to construct a $70M+ TRU waste characterization facility; (3) have waste certified for shipment to WIPP when WIPP opens; (4) continue to ship TRU waste to WIPP at the rate of 5000 drums per year; and (5) reduce overall costs by more than $200M. Aggressive implementation of mobile and portable systems throughout the Department of Energy complex through a centralized-distributed services model will result in similar advantages complex-wide

Used solid catalysts from chemical and petrochemical industries; Les catalyseurs solides uses de l`industrie chimique et du raffinage petrolier

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-10-01

A comprehensive survey of the solid catalysts used in the chemical and petrochemical industries is presented; information on solid catalyst market demand prospective for 1998, the nature of solid catalysts used in the various industrial sectors and for the various chemical products production, the european catalysts manufacturers, solid catalyst poisons and inhibitors according to the various types of chemical reactions, mean compositions of used solid catalysts, an assessment of the volume of used solid catalysts generated by chemical and petrochemical industries, the various ways of solid catalyst regeneration and disposal, the potential for off-site regeneration of used catalysts, and French and European regulations, is presented

Determination of boiling point of petrochemicals by gas chromatography-mass spectrometry and multivariate regression analysis of structural activity relationship.

Science.gov (United States)

Fakayode, Sayo O; Mitchell, Breanna S; Pollard, David A

2014-08-01

Accurate understanding of analyte boiling points (BP) is of critical importance in gas chromatographic (GC) separation and crude oil refinery operation in petrochemical industries. This study reported the first combined use of GC separation and partial-least-square (PLS1) multivariate regression analysis of petrochemical structural activity relationship (SAR) for accurate BP determination of two commercially available (D3710 and MA VHP) calibration gas mix samples. The results of the BP determination using PLS1 multivariate regression were further compared with the results of traditional simulated distillation method of BP determination. The developed PLS1 regression was able to correctly predict analytes BP in D3710 and MA VHP calibration gas mix samples, with a root-mean-square-%-relative-error (RMS%RE) of 6.4%, and 10.8% respectively. In contrast, the overall RMS%RE of 32.9% and 40.4%, respectively obtained for BP determination in D3710 and MA VHP using a traditional simulated distillation method were approximately four times larger than the corresponding RMS%RE of BP prediction using MRA, demonstrating the better predictive ability of MRA. The reported method is rapid, robust, and promising, and can be potentially used routinely for fast analysis, pattern recognition, and analyte BP determination in petrochemical industries. Copyright © 2014 Elsevier B.V. All rights reserved.

PENGARUH PEMERIKSAAN INTERN TERHADAP EFEKTIVITAS PENGENDALIAN INTERN ATAS PERSEDIAAN BAHAN BAKU PADA PT. CHANDRA ASRI PETROCHEMICAL JAKARTA

Directory of Open Access Journals (Sweden)

Andi Riyanto

2016-03-01

  Keyword : Raw Material Inventory, Internal Control, Internal Auditing.   Abstrak - PT. Chandra Asri Petrochemical adalah perusahaan petrokimia terbesar dan terintegrasi secara vertikal di Indonesia. Tujuan penelitian ini adalah untuk mengetahui pengaruh pemeriksaan intern terhadap efektivitas pengendalian intern atas persediaan bahan baku pada PT. Chandra Asri Petrochemical. Metode yang digunakan adalah metode deskriptif analitis dengan pendekatan kuantitatif. Populasi berjumlah 27 pegawai dan semua populasi digunakan sebagai sampel dengan teknik sampling jenuh. Dari perhitungan uji statistik menggunakan aplikasi SPSS versi 20, diperoleh nilai thitung untuk variabel pemeriksaan intern adalah 5,799 dengan df = 24 pada signifikansi (α 0,05, diperoleh ttabel sebesar 2,064, maka keputusan uji yang diambil adalah H0 ditolak. Artinya bahwa pemeriksaan intern berpengaruh signifikan terhadap efektivitas pengendalian intern atas persediaan bahan baku.   Kata Kunci : Pemeriksaan Intern, Pengendalian Intern, Persediaan Bahan Baku.

Canadian petrochemicals - what's next. A background and planning paper on the petrochemical industry

Energy Technology Data Exchange (ETDEWEB)

1976-01-01

This report undertakes a forecast of the Canadian petrochemicals industry, based on a cross-impact computer model. This model was designed to assist in determining relevant future conditions and their corresponding impact on one another. Industry data were obtained from questionnaires sent to major corporations. Respondents were asked to give their subjective interpretation of the probability of occurrence of future events in the areas of feedstocks, production, trade and distribution, research and technology, and government/industry structure. Skeleton scenarios were developed in each of these areas. Prognoses were made on the basis of the most popular pairs of cross-impact events, or where frequencies of response were at a sufficient level where interpretation of the result would be valid. Some conclusions reached are as follows. The impact of feedstocks will be related to the growing gap between supply and demand of natural gas, e.g. increased use of gas as feedstock will lead to higher production costs and possibly the use of coal gasification and other sources. The impact of production and trade will be in the area of price competition from producers in other countries and the development of new plants in Canada. New technology will depend on licensing arrangements, investment, and informational exchanges. Government policies will have a direct effect on the industry if a requirement of Canadian equity is implemented, with implications for foreign investment and bilateral agreements with the USA. 45 tabs.

Nonradioactive Air Emissions Notice of Construction (NOC) Application for the Central Waste Complex (CSC) for Storage of Vented Waste Containers

International Nuclear Information System (INIS)

KAMBERG, L.D.

2000-01-01

This Notice of Construction (NOC) application is submitted for the storage and management of waste containers at the Central Waste Complex (CWC) stationary source. The CWC stationary source consists of multiple sources of diffuse and fugitive emissions, as described herein. This NOC is submitted in accordance with the requirements of Washington Administrative Code (WAC) 173-400-110 (criteria pollutants) and 173-460-040 (toxic air pollutants), and pursuant to guidance provided by the Washington State Department of Ecology (Ecology). Transuranic (TRU) mixed waste containers at CWC are vented to preclude the build up of hydrogen produced as a result of radionuclide decay, not as safety pressure releases. The following activities are conducted within the CWC stationary source: Storage and inspection; Transfer and staging; Packaging; Treatment; and Sampling. This NOC application is intended to cover all existing storage structures within the current CWC treatment, storage, and/or disposal (TSD) boundary, as well as any storage structures, including waste storage pads and staging areas, that might be constructed in the future within the existing CWC boundary

Prevalence and risk factors of gallbladder polypoid lesions in Chinese petrochemical employees.

Science.gov (United States)

Mao, Yu-Shan; Mai, Yi-Feng; Li, Fu-Jun; Zhang, Yan-Ming; Hu, Ke-Min; Hong, Zhong-Li; Zhu, Zhong-Wei

2013-07-21

To investigate the prevalence and risk factors of polypoid lesions of the gallbladder (PLGs) in petrochemical employees in Ningbo, Zhejiang Province, China. All active and retired employees aged 20-90 years (n = 11098) of a refinery and chemical plant in eastern China were requested to participate in a health survey. The participants were subjected to interview, physical examination, laboratory assessments and ultrasonography. All the participants were invited to have a physical examination after a face-to-face interview. Fasting blood samples were obtained from the antecubital vein, and the samples were used for the analysis of biochemical values. Abdominal ultrasonography was conducted. A total of 10461 (7331 men and 3130 women) current and former petrochemical employees attended for screening. The overall prevalence of post-cholecystectomy, gallstones and PLGs was 0.9%, 5.2% and 7.4%, respectively. Compared with the increased prevalence of either gallstones or post-cholecystectomy in older persons, PLGs were more common in the middle-aged, peaking in those aged 40-59 years. Excluding the patients with gallstones, gallstones mixed with PLGs, or those who had undergone cholecystectomy, in the remaining 9828 participants, the prevalence of PLGs in men (8.9%) was significantly higher than that in women (5.5%, P employees. Male gender, HBsAg positivity, and middle age are risk factors for developing PLGs.

Increasing a large petrochemical company efficiency by improvement of decision making process

OpenAIRE

Kirin Snežana D.; Nešić Lela G.

2010-01-01

The paper shows the results of a research conducted in a large petrochemical company, in a state under transition, with the aim to "shed light" on the decision making process from the aspect of personal characteristics of the employees, in order to use the results to improve decision making process and increase company efficiency. The research was conducted by a survey, i.e. by filling out a questionnaire specially made for this purpose, in real conditions, during working hours. The sample of...

Complex processing and utilization of waste as the basis for sustainable economic development district

Directory of Open Access Journals (Sweden)

V.М. Ilchenko

2015-06-01

Full Text Available The article describes the main environmental problems of Ukraine. The problems that are connected with complex processing and recycling, the example Dnieper economic paradise-one, which allows more detailed present environmental situation of the country at this stage. The article is used and analyzed recent environmental performance and the basic problems of on-disposal and recycling. Basic research methods: observation, analysis and comparison. The aim was to find ways to overcome the ecological crisis in Ukraine. As a result of the research, it was determined that most types of waste-tion prevail in Ukraine and found the best solutions to problems related to waste and their processing. It was possible to find the main problem that has caused serious environmental situation, and the main task for the country at this stage. The main problems and tasks Dnieper economic region. Also indicate how to save, due to complex processing waste. The article is very relevant and important because it is here that the basic problems and tasks of Ukraine concerning the ecological situation. It also focuses on eco-logical problems, which the government does not pay enough attention.

Environmental surveillance for the INEL radioactive waste management complex. Annual report, 1979

International Nuclear Information System (INIS)

Wickham, L.E.; Janke, D.H.

1980-12-01

This document is the 1979 annual environmental surveillance report for the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory. Included are tabulated data from and discussions about routine radiological monitoring of atmospheric, hydrologic, geologic, and biotic environments of the RWMC. Also included are discussions of selected nonradiological pollutants (e.g., sodium, etc.). It is concluded that (a) RWMC operations have not adversely affected local, existing environments; (b) environmental conditions within the Transuranic Storage Area are not corrosive enough to adversely affect transuranic waste storage containers, and (c) the addition of lakebed soil to pit, trench, and soil test plot areas has altered the moisture cycle characteristic of RWMC soil

Personnel reliability impact on petrochemical facilities monitoring system's failure skipping probability

Science.gov (United States)

Kostyukov, V. N.; Naumenko, A. P.

2017-08-01

The paper dwells upon urgent issues of evaluating impact of actions conducted by complex technological systems operators on their safe operation considering application of condition monitoring systems for elements and sub-systems of petrochemical production facilities. The main task for the research is to distinguish factors and criteria of monitoring system properties description, which would allow to evaluate impact of errors made by personnel on operation of real-time condition monitoring and diagnostic systems for machinery of petrochemical facilities, and find and objective criteria for monitoring system class, considering a human factor. On the basis of real-time condition monitoring concepts of sudden failure skipping risk, static and dynamic error, monitoring systems, one may solve a task of evaluation of impact that personnel's qualification has on monitoring system operation in terms of error in personnel or operators' actions while receiving information from monitoring systems and operating a technological system. Operator is considered as a part of the technological system. Although, personnel's behavior is usually a combination of the following parameters: input signal - information perceiving, reaction - decision making, response - decision implementing. Based on several researches on behavior of nuclear powers station operators in USA, Italy and other countries, as well as on researches conducted by Russian scientists, required data on operator's reliability were selected for analysis of operator's behavior at technological facilities diagnostics and monitoring systems. The calculations revealed that for the monitoring system selected as an example, the failure skipping risk for the set values of static (less than 0.01) and dynamic (less than 0.001) errors considering all related factors of data on reliability of information perception, decision-making, and reaction fulfilled is 0.037, in case when all the facilities and error probability are under

New Governance of Corporate Cybersecurity : A case study of the petrochemical industry in the port of Rotterdam

NARCIS (Netherlands)

van Erp, J.G.

The petro-chemical industry is a critical infrastructure that is vulnerable to cybercrime. In particular, industrial process control systems contain many vulnerabilities and are known targets for hackers. A cyberattack to a chemical facility can cause enormous risks to the economy, the environment,

Comparative Life Cycle Studies on Poly(3-hydroxybutyrate)-Based Composites as Potential Replacement for Conventional Petrochemical Plastics

NARCIS (Netherlands)

Pietrini, M.; Roes, A.L.; Patel, M.K.; Chiellini, E.

2007-01-01

A cradle-to-grave environmental life cycle assessment (LCA) of a few poly(3-hydroxybutyrate) (PHB) based composites has been performed and was compared to commodity petrochemical polymers. The end products studied are a cathode ray tube (CRT) monitor housing (conventionally produced from high-impact

Retrofitting refinery and petrochemical plants

Energy Technology Data Exchange (ETDEWEB)

Kesler, M.G.

1988-06-01

This article focuses on process improvements as the best way to reduce plant energy use. The emphasis on process revamp is well justified, as an energy profile for a typical refinery shows. The diagram shows that 60% of the total heat losses are in water and air cooling. Most of this heat loss results from condensing and cooling in fractionators and recycle systems, intermediate product cooling, and condensing of turbine steam. These losses, of mostly low-level heat, are tied to the basic approach previously used for the process design of existing refineries. Despite the progress to date, there is growing evidence that these heat losses can be further reduced economically by about 20-30% in most refineries and petrochemical plants. One way to reduce the losses is to increase recovery of low-level heat by improved heat exchange, which has been the subject of most publications on plant energy conservation. A better way, presented here, is to develop new process schemes that require less air/water cooling. One useful concept in developing new schemes is to concentrate on heat losses, rather than heat input, as an easier measure of proposed improvements. By an overall heat balance, eliminating a unit of energy loss is equivalent to saving a unit of heat input somewhere in the plant.

Phase V storage (Project W-112) Central Waste Complex operational readiness review, final report

International Nuclear Information System (INIS)

Wight, R.H.

1997-01-01

This document is the final report for the RFSH conducted, Contractor Operational Readiness Review (ORR) for the Central Waste Complex (CWC) Project W-112 and Interim Safety Basis implementation. As appendices, all findings, observations, lines of inquiry and the implementation plan are included

Phase 5 storage (Project W-112) Central Waste Complex operational readiness review, final report

Energy Technology Data Exchange (ETDEWEB)

Wight, R.H.

1997-05-30

This document is the final report for the RFSH conducted, Contractor Operational Readiness Review (ORR) for the Central Waste Complex (CWC) Project W-112 and Interim Safety Basis implementation. As appendices, all findings, observations, lines of inquiry and the implementation plan are included.

Organic analyses of mixed nuclear wastes

International Nuclear Information System (INIS)

Toste, A.P.; Lucke, R.B.; Lechner-Fish, T.J.; Hendren, D.J.; Myers, R.B.

1987-04-01

Analytical methods are being developed for the organic analysis of nuclear wastes. Our laboratory analyzed the organic content of three commercial wastes and an organic-rich, complex concentrate waste. The commercial wastes contained a variety of hydrophobic and hydrophilic organics, at concentrations ranging from nanomolar to micromolar. Alkyl phenols, chelating and complexing agents, as well as their degradation products, and carboxylic acids were detected in the commercial wastes. The complex concentrate waste contained chelating and complexing agents, as well as numerous degradation products, at millimolar concentrations. 75.1% of the complex concentrate waste's total organic carbon content has been identified. The presence of chelator fragments in all of the wastes analyzed, occasionally at elevated concentrations, indicates that organic diagenesis, or degradation, in nuclear wastes is both widespread and quite vigorous. 23 refs., 3 tabs

Reproductive outcomes in an area adjacent to a petrochemical plant in southern Brazil

Directory of Open Access Journals (Sweden)

Oliveira Lenice Minussi

2002-01-01

Full Text Available OBJECTIVE: To evaluate possible adverse reproductive outcomes in an area adjacent to a petrochemical plant in southern Brazil. METHODS: A review of 17,113 birth records of the main hospital of the municipality of Montenegro, southern Brazil, from 1983 to 1998 was carried out. Three groups of cases were selected: (1 newborns with major congenital malformations; (2 newborns with low birth weight (500 g. A control was assigned to each case. Controls were the first newborns weighing > or = 2,500 g without malformations and of case-matching sex. Mother's residence during pregnancy was used as an exposure parameter. Statistical analyses were performed using Chi-square test or Fisher test, odds ratio, 0.05 significance level, and 95% confidence interval. RESULTS: For unadjusted analysis, it was found a correlation between low birth weight and geographical proximity of mother's residence to the petrochemical plant (OR = 1.66; 95% CI = 1.01--2.72 or residence on the way of preferential wind direction (OR = 1.62; 95% CI = 1.03--2.56. When other covariates were added in the conditional logistic regression (maternal smoking habits, chronic disease and age, there was no association. CONCLUSIONS: Despite final results were negative, low birth weight could be a good parameter of environmental contamination and should be closely monitored in the studied area.

Appling hydrolysis acidification-anoxic–oxic process in the treatment of petrochemical wastewater: From bench scale reactor to full scale wastewater treatment plant

International Nuclear Information System (INIS)

Wu, Changyong; Zhou, Yuexi; Sun, Qingliang; Fu, Liya; Xi, Hongbo; Yu, Yin; Yu, Ruozhen

2016-01-01

Highlights: • Hydrolysis acidification-anoxic–oxic process can be used to treat petrochemical wastewater. • The toxicity and treatability changed significantly after hydrolysis acidification. • The type and concentration of organics reduced greatly after treatment. • The effluent shows low acute toxicity by luminescent bacteria assay. • Advanced treatment is recommended for the effluent. - Abstract: A hydrolysis acidification (HA)-anoxic–oxic (A/O) process was adopted to treat a petrochemical wastewater. The operation optimization was carried out firstly by a bench scale experimental reactor. Then a full scale petrochemical wastewater treatment plant (PCWWTP, 6500 m 3 h −1 ) was operated with the same parameters. The results showed that the BOD 5 /COD of the wastewater increased from 0.30 to 0.43 by HA. The effluent COD was 54.4 mg L −1 for bench scale reactor and 60.9 mg L −1 for PCWWTP when the influent COD was about 480 mg L −1 on optimized conditions. The organics measured by gas chromatography-mass spectrometry (GC–MS) reduced obviously and the total concentration of the 5 organics (1,3-dioxolane, 2-pentanone, ethylbenzene, 2-chloromethyl-1,3-dioxolane and indene) detected in the effluent was only 0.24 mg L −1 . There was no obvious toxicity of the effluent. However, low acute toxicity of the effluent could be detected by the luminescent bacteria assay, indicating the advanced treatment is needed. The clone library profiling analysis showed that the dominant bacteria in the system were Acidobacteria, Proteobacteria and Bacteriodetes. HA-A/O process is suitable for the petrochemical wastewater treatment.

Non-methane hydrocarbons (NMHCs) and their contribution to ozone formation potential in a petrochemical industrialized city, Northwest China

Science.gov (United States)

Jia, Chenhui; Mao, Xiaoxuan; Huang, Tao; Liang, Xiaoxue; Wang, Yanan; Shen, Yanjie; Jiang, Wanyanhan; Wang, Huiqin; Bai, Zhilin; Ma, Minquan; Yu, Zhousuo; Ma, Jianmin; Gao, Hong

2016-03-01

Hourly air concentrations of fifty-three non-methane hydrocarbons (NMHCs) were measured at downtown and suburb of Lanzhou, a petrochemical industrialized city, Northwest China in 2013. The measured data were used to investigate the seasonal characteristics of NMHCs air pollution and their contributions to the ozone formation in Lanzhou. Annually averaged NMHCs concentration was 38.29 ppbv in downtown Lanzhou. Among 53 NMHCs, alkanes, alkenes, and aromatics accounted for 57%, 23% and 20% of the total NMHCs air concentration, respectively. The atmospheric levels of toluene and propane with mean values of 4.62 and 4.56 ppbv were higher than other NMHCs, respectively. The ambient levels of NMHCs in downtown Lanzhou were compared with measured NMHCs data collected at a suburban site of Lanzhou, located near a large-scale petrochemical industry. Results show that the levels of alkanes, alkenes, and aromatics in downtown Lanzhou were lower by factors of 3-11 than that in west suburb of the city. O3-isopleth plots show that ozone was formed in VOCs control area in downtown Lanzhou and NOx control area at the west suburban site during the summertime. Propylene-equivalent (Prop-Equiv) concentration and the maximum incremental reactivity (MIR) in downtown Lanzhou indicate that cis-2-butene, propylene, and m/p-xylene were the first three compounds contributing to ozone formation potentials whereas in the petrochemical industrialized west suburb, ethane, propene, and trans-2-Butene played more important role in the summertime ozone formation. Principal component analysis (PCA) and multiple linear regression (MLR) were further applied to identify the dominant emission sources and examine their fractions in total NMHCs. Results suggest that vehicle emission, solvent usage, and industrial activities were major sources of NMHCs in the city, accounting for 58.34%, 22.19%, and 19.47% of the total monitored NMHCs in downtown Lanzhou, respectively. In the west suburb of the city

Oil policies and privatization strategies in Mexico: implications for the petrochemical sector and its production spaces

International Nuclear Information System (INIS)

Laguna, N.M.

2004-01-01

Through a retrospective analysis of Mexico's oil history, this work examines the privatization processes that occurred in the petrochemical sector, from the abolishment of the government's monopoly, Petroleos Mexicanos (PEMEX) during the 1980s, until the restructuring and open liberalization in the early 1990s, focusing on the areas incorporated to production processes, particularly along the Gulf coast. As a result of the industrial policies and regional development strategies promoted by the government from the sixties, oriented towards strengthening production in areas with the highest potential, attractive business investment areas were developed. These included southern Tamaulipas, a strategic region where a number of industrial factors facilitated access to raw materials at competitive prices, as well as their processing and distribution to local and international markets, all of these within a single location. The strategic nature of the petrochemical location and production have made southern Tamaulipas a key factor for the territorial shaping and industrial development linked to the behavior of transnational companies that, seeking comparative advantages, have relocated parts of their production capacity in this region

Preliminary engineering evaluation of heat and digest treatment for in-tank removal of radionuclides from complexed waste

International Nuclear Information System (INIS)

Klem, M.J.

1995-01-01

This report uses laboratory data from low temperature-ambient pressure digestion of actual complexed supernatant to evaluate digestion as a pretreatment method for waste in double-shell tanks 241-AN-102, 241-AN-107 and 241-AY-101. Digestion time requirements were developed at 100 degrees celsius to remove organic and meet NRC Class C criterion for TRU elements and NRC Class B criterion for 90Sr. The incidental waste ruling will establish the need for removal of 90Sr. Digestion pretreatment precipitates non radioactive metal ions and produces additional high-level waste solids and canisters of high level glass. This report estimates the amount of additional high-level waste produced and preliminary capital and operating costs for in-tank digestion of waste. An overview of alternative in-tank treatment methods is included

Bio-processing of solid wastes and secondary resources for metal extraction – A review

International Nuclear Information System (INIS)

Lee, Jae-chun; Pandey, Banshi Dhar

2012-01-01

Highlights: ► Review focuses on bio-extraction of metals from solid wastes of industries and consumer goods. ► Bio-processing of certain effluents/wastewaters with metals is also included in brief. ► Quantity/composition of wastes are assessed, and microbes used and leaching conditions included. ► Bio-recovery using bacteria, fungi and archaea is highlighted for resource recycling. ► Process methodology/mechanism, R and D direction and scope of large scale use are briefly included. - Abstract: Metal containing wastes/byproducts of various industries, used consumer goods, and municipal waste are potential pollutants, if not treated properly. They may also be important secondary resources if processed in eco-friendly manner for secured supply of contained metals/materials. Bio-extraction of metals from such resources with microbes such as bacteria, fungi and archaea is being increasingly explored to meet the twin objectives of resource recycling and pollution mitigation. This review focuses on the bio-processing of solid wastes/byproducts of metallurgical and manufacturing industries, chemical/petrochemical plants, electroplating and tanning units, besides sewage sludge and fly ash of municipal incinerators, electronic wastes (e-wastes/PCBs), used batteries, etc. An assessment has been made to quantify the wastes generated and its compositions, microbes used, metal leaching efficiency etc. Processing of certain effluents and wastewaters comprising of metals is also included in brief. Future directions of research are highlighted.

Perceptions of Private Sector towards the Pollutant Release and Transfer Register: A Case Study on Petrochemical Industry in the Map Ta Phut Industrial Estate, Rayong, Thailand

Directory of Open Access Journals (Sweden)

Marie Kondo

2013-01-01

Full Text Available Under the Rio Declaration and Agenda 21 from the United Nations Conference on Environment and Development in 1992 as well as other international agreements, Thailand is currently in the process of adopting the Pollutant Release and Transfer Register (PRTR through a pilot project in Rayong province with assistance from the Japan International Cooperation Agency (JICA. This research aimed to study perceptions of private sector towards the PRTR through a case study on petrochemical industry in the Map Ta Phut Industrial Estate. Through semi-structured questionnaires and in-depth interviews, the study found that the petrochemical industry viewed that benefits of the PRTR for the government and civil society is quite clear, while each petrochemical company has different understanding on such benefit for private sector to be as sustainable industrial management. Various incentive measures and concerns on the PRTR were also indicated in this study.

Isolation and characterization of an n-hexadecane degrading Acinetobacter baumannii KSS1060 from a petrochemical wastewater treatment plant

International Nuclear Information System (INIS)

Shiri, Z.; Kermanshahi, R. K.; Soudi, M. R.; Farajzadeh, D.

2015-01-01

Hydrocarbons are widespread in the environment, but because of the massive utilization of petroleum products, they are nowadays strongly involved in environmental pollution. Bioremediation is the obliging technology for the treatment of hydrocarbon-contaminated sites. Therefore, to investigate the potential of petrochemical hydrocarbon (HC)-degrading indigenous microorganisms in wastewater samples collected from Fajr petrochemical wastewater treatment plants, a strain of Acinetobacter baumannii was isolated from this hydrocarbon-contaminated wastewater and examined for its ability to utilize hexadecane. This strain was capable to grow on n-hexadecane as the sole source of carbon and energy. The ability of the isolate to degrade n-hexadecane was assessed by growth assays and gas chromatography/mass spectrometry analysis. Using GC analysis, it was shown that the strain KSS1060 was able to degrade 62 % of n-hexadecane within 6 days, which mostly (51.6 %) occurred within the first 24 h. Identification of this hexadecane-degrader bacterium was carried out using 16S rDNA sequence analysis. Additionally, characterization of chemical composition of wastewater samples by the use of gas chromatography/mass spectrometry analysis indicated the presence of Hexanal, Benzene methanol, Indanol, 1,2-benzenedicarboxylic acid diethyl ester, diisobutyl phthalate, and Phenol,4,4′-(1-methylethylidene) in the major constituents of wastewater. In conclusion, this study can focus on more cost-efficient applications of native bacterial strains for the large-scale biodegradation of wastewater samples from petrochemical plant in industry, where it causes disturbing problems due to its harmful effects on different organisms and human beings.

Air quality impacted by local pollution sources and beyond - Using a prominent petro-industrial complex as a study case.

Science.gov (United States)

Chen, Sheng-Po; Wang, Chieh-Heng; Lin, Wen-Dian; Tong, Yu-Huei; Chen, Yu-Chun; Chiu, Ching-Jui; Chiang, Hung-Chi; Fan, Chen-Lun; Wang, Jia-Lin; Chang, Julius S

2018-05-01

The present study combines high-resolution measurements at various distances from a world-class gigantic petrochemical complex with model simulations to test a method to assess industrial emissions and their effect on local air quality. Due to the complexity in wind conditions which were highly seasonal, the dominant wind flow patterns in the coastal region of interest were classified into three types, namely northeast monsoonal (NEM) flows, southwest monsoonal (SEM) flows and local circulation (LC) based on six years of monitoring data. Sulfur dioxide (SO 2 ) was chosen as an indicative pollutant for prominent industrial emissions. A high-density monitoring network of 12 air-quality stations distributed within a 20-km radius surrounding the petrochemical complex provided hourly measurements of SO 2 and wind parameters. The SO 2 emissions from major industrial sources registered by the monitoring network were then used to validate model simulations and to illustrate the transport of the SO 2 plumes under the three typical wind patterns. It was found that the coupling of observations and modeling was able to successfully explain the transport of the industrial plumes. Although the petrochemical complex was seemingly the only major source to affect local air quality, multiple prominent sources from afar also played a significant role in local air quality. As a result, we found that a more complete and balanced assessment of the local air quality can be achieved only after taking into account the wind characteristics and emission factors of a much larger spatial scale than the initial (20 km by 20 km) study domain. Copyright © 2018 Elsevier Ltd. All rights reserved.

Fundamental requirements for petrochemical development

International Nuclear Information System (INIS)

Flint, G. B.

1999-01-01

The development of NOVA Chemicals over the past 20 years is described as an illustration of how the petrochemical industry provides markets for natural gas, natural gas liquids and the products of crude oil distillation, and functions as a conduit for upgrading products which would otherwise be sold into the fuel market. Some fundamental characteristics of the business which are foundations for competitiveness are reviewed in the process. These fundamentals help to understand why the industry locates in certain geographic regions of the world, which are often remote from end-use markets. Chief among these fundamentals is access to an adequate supply of appropriately priced feedstock; this is the single most important reason why chemical companies continue to emphasize developments in areas of the world where feedstock are advantageously priced. The cost of operations is equally significant. Cost depends not so much on location but on the scale of operations, hence the tendency towards large scale plants. Plant and product rationalization, technology and product development synergies and leverage with suppliers are all opportunities for cost reduction throughout the product supply chain. The combination of lower natural gas cost in Alberta, the lower fixed cost of extraction and the economies of scale achieved by large scale operation (five billion pounds per year of polyethylene production capacity) are the crucial factors that will enable NOVA Chemicals to maintain its competitive position and to weather the highs and lows in industry price fluctuations

Supply of ethane and transportation to the petrochemical industry

International Nuclear Information System (INIS)

Moe, D.

1997-01-01

This presentation reviewed the existing infrastructure for ethane delivery and distribution from Alberta and assessed future potential. Large investments continue to be made to expand pipelines and petrochemical plants, at the same time, the sufficiency of ethane supplies for all projects to proceed are being questioned. Some current projects such as the Empress to Kerrobert pipeline expansion, the NCL Straddle Plant at Taylor, the PacRim LNG project, the new fractionation plant at Fort Saskatchewan, the Alliance Pipeline project to connect gas and ethane, and the impact of Alliance and PacRim on available ethane were reviewed. The competition for supplies is increasing and the export of ethane is expected to continue at low levels. Recent regulatory decisions about producers rights and upcoming challenges (NOVA load retention tolling, component balancing on NOVA, competitive hearings) were also outlined. 9 figs

The buried waste integrated demonstration

International Nuclear Information System (INIS)

Kostelnik, K.M.

1991-01-01

There are numerous locations throughout the Department of Energy (DOE) Complex where wastes have been buried in the ground or stored for future disposal. Much of this buried waste is contaminated with hazardous and radioactive materials. An extensive research program has been initiated at the Idaho National Engineering Laboratory (INEL) to develop and demonstrate advanced remediation techniques for DOE Complex buried waste. The purpose of the Buried Waste Integrated Demonstration (BWID), is to develop a scientifically sound and deployable remediation system consisting of advanced technologies which address the buried waste characteristics of the DOE Complex. This comprehensive remediation system win include technologies for the entire remediation cycle (cradle-to-grave). Technologies developed and demonstrated within the BWID will be transferred to the DOE Complex sites with buried waste, to private industry, and to universities. Multidirectional technology transfer is encouraged by the BWID. Identification and evaluation of plausible technological solutions are an ongoing activity of the BWID. A number of technologies are currently under development throughout the DOE Complex, private industry, and universities. Technology integration mechanisms have been established by BWID to facilitate collaborative research and demonstration of applicable remedial technologies for buried waste. Successful completion of the BWID will result in the development of a proven and deployable system at the INEL and other DOE Complex buried waste sites, thereby supporting the DOE Complex's environmental restoration objectives

IMPROVEMENTS IN CONTAINER MANAGEMENT OF TRANSURANIC (TRU) AND LOW LEVEL RADIOACTIVE WASTE STORED AT THE CENTRAL WASTE COMPLEX (CWC) AT HANFORD

International Nuclear Information System (INIS)

UYTIOCO EM

2007-01-01

The Central Waste Complex (CWC) is the interim storage facility for Resource Conservation and Recovery Act (RCRA) mixed waste, transuranic waste, transuranic mixed waste, low-level and low-level mixed radioactive waste at the Department of Energy's (DOE'S) Hanford Site. The majority of the waste stored at the facility is retrieved from the low-level burial grounds in the 200 West Area at the Site, with minor quantities of newly generated waste from on-site and off-site waste generators. The CWC comprises 18 storage buildings that house 13,000 containers. Each waste container within the facility is scanned into its location by building, module, tier and position and the information is stored in a site-wide database. As waste is retrieved from the burial grounds, a preliminary non-destructive assay is performed to determine if the waste is transuranic (TRU) or low-level waste (LLW) and subsequently shipped to the CWC. In general, the TRU and LLW waste containers are stored in separate locations within the CWC, but the final disposition of each waste container is not known upon receipt. The final disposition of each waste container is determined by the appropriate program as process knowledge is applied and characterization data becomes available. Waste containers are stored within the CWC based on their physical chemical and radiological hazards. Further segregation within each building is done by container size (55-gallon, 85-gallon, Standard Waste Box) and waste stream. Due to this waste storage scheme, assembling waste containers for shipment out of the CWC has been time consuming and labor intensive. Qualitatively, the ratio of containers moved to containers in the outgoing shipment has been excessively high, which correlates to additional worker exposure, shipment delays, and operational inefficiencies. These inefficiencies impacted the LLW Program's ability to meet commitments established by the Tri-Party Agreement, an agreement between the State of Washington

Risk Perception, Knowledge and Safety Attitude and Hearing Protector Use in Petrochemical Industry Workers

Directory of Open Access Journals (Sweden)

Mahdi Jahangiri

2008-06-01

Full Text Available Background and Aim: Hearing protectors (HP are widely employed as the only measure against noise exposure. However, it is well known that unless do workers wear HP continuously, its efficacy will be very low. The purpose of this study was to determine the influence of risk perception, knowledge and safety attitude on hearing protection use in petrochemical industry's workers.Materials and Methods: In this cross-sectional study a structural questionnaire was administrated to 236 randomly selected workers in Iranian petrochemical industry who had been to 85 dBA noise and some influencing factors including risk perception, knowledge and general attitude to safety on using of HP had been investigated.Results: This study showed that only 20.3% of employees claimed to wear hearing protection all the time when they exposed to noise. There was a significant relationship between use of hearing protector and worker's risk perception (p=0.048 and also their knowledge about hearing protection(p=0.009. Also, the relationship between general attitude of workers to safety and risk perception was statistically significant (p=0.046. Conclusion: The results of the study showed that for promoting the use of hearing protectors, two main strategy should be followed. First, removing the barriers to make hearing protectors compliant, and second enhancing the workers’ risk perception about hearing loss and proper use of ear protectors.

Statistical analysis of incidents reported in the Greek Petrochemical Industry for the period 1997-2003

International Nuclear Information System (INIS)

Konstandinidou, Myrto; Nivolianitou, Zoe; Markatos, Nikolaos; Kiranoudis, Chris

2006-01-01

This paper makes an analysis of all reported accidents and incidents in the Greek Petrochemical Industry for the period spanning from 1997 to 2003. The work performed is related to the analysis of important parameters of the incidents, their inclusion in a database adequately designed for the purposes of this analysis and an importance assessment of this reporting scheme. Indeed, various stakeholders have highlighted the importance of a reporting system for industrial accidents and incidents. The European Union has established for this purpose the Major Accident Reporting System (MARS) for the reporting of major accidents in the Member States. However, major accidents are not the only measure that can characterize the safety status of an establishment; neither are the former the only events from which important lessons can be learned. Near misses, industrial incidents without major consequences, as well as occupational accidents could equally supply with important findings the interested analyst, while statistical analysis of these incidents could give significant insight in the understanding and the prevention of similar incidents or major accidents in the future. This analysis could be more significant, if each industrial sector was separately analyzed, as the authors do for the petrochemical sector in the present article

In-depth analysis of the causal factors of incidents reported in the Greek petrochemical industry

Energy Technology Data Exchange (ETDEWEB)

Konstandinidou, Myrto [Institute of Nuclear Technology-Radiation Protection, National Center for Scientific Research ' Demokritos' , Aghia Paraskevi 15310 (Greece); Nivolianitou, Zoe, E-mail: zoe@ipta.demokritos.gr [Institute of Nuclear Technology-Radiation Protection, National Center for Scientific Research ' Demokritos' , Aghia Paraskevi 15310 (Greece); Kefalogianni, Eirini; Caroni, Chrys [School of Applied Mathematical and Physical Sciences, National Technical University of Athens, 9 Iroon Polytexneiou Str., Zografou Campus, 157 80 Athens (Greece)

2011-11-15

This paper presents a statistical analysis of all reported incidents in the Greek petrochemical industry from 1997 to 2003. A comprehensive database has been developed to include industrial accidents (fires, explosions and substance releases), occupational accidents, incidents without significant consequences and near misses. The study concentrates on identifying and analyzing the causal factors related to different consequences of incidents, in particular, injury, absence from work and material damage. Methods of analysis include logistic regression with one of these consequences as dependent variable. The causal factors that are considered cover four major categories related to organizational issues, equipment malfunctions, human errors (of commission or omission) and external causes. Further analyses aim to confirm the value of recording near misses by comparing their causal factors with those of more serious incidents. The statistical analysis highlights the connection between the human factor and the underlying causes of accidents or incidents. - Highlights: > The research work is original, based on field data collected directly from the petrochemical industry. > It deals with the in-depth statistical analysis of accident data on human-organizational causes. > It researches underlying causes of accidents and the parameters affecting them. > The causal factors that are considered cover four big taxonomies. > Near misses are worth recording for comparing their causal factors with more serious incidents.

Job insecurity, leadership empowerment behaviour, employee engagement and intention to leave in a petrochemical laboratory

Directory of Open Access Journals (Sweden)

Sonet van Schalkwyk

2010-07-01

Research purpose: The objective of this study was to investigate the relationship between job insecurity, leadership empowerment behaviour (as perceived by the employees who report to leaders, employee engagement and intention to leave their jobs in a petrochemical laboratory. Motivation for the study: Knowledge of the effects of job insecurity and leadership on employee engagement and turnover intention will contribute to improved talent management. Research design, approach and method: A correlational design was used. A total of 169 employees in a petrochemical laboratory were studied. The measuring instruments included the Job Insecurity Index, the Leadership Empowerment Behaviour Questionnaire, and the Utrecht Work Engagement Scale. Two questions were used to measure intention to leave. Main findings: The results showed that job insecurity was not statistically significantly related to employee engagement and turnover intention. Leadership empowerment behaviour contributed statistically significantly to employee engagement and low turnover intention. Employee engagement partially mediated the relationship between leadership empowerment behaviour and turnover intention. Practical implications: Leaders should be developed to show empowerment behaviour, because it affects employee engagement, which in turn affects their turnover intention Contribution: This was the first study that demonstrated the effect of empowerment behaviour of leaders on the engagement and turnover intention of employees.

The sequencing batch reactor as an excellent configuration to treat wastewater from the petrochemical industry.

Science.gov (United States)

Caluwé, Michel; Daens, Dominique; Blust, Ronny; Geuens, Luc; Dries, Jan

2017-02-01

In the present study, the influence of a changing feeding pattern from continuous to pulse feeding on the characteristics of activated sludge was investigated with a wastewater from the petrochemical industry from the harbour of Antwerp. Continuous seed sludge, adapted to the industrial wastewater, was used to start up three laboratory-scale sequencing batch reactors. After an adaptation period from the shift to pulse feeding, the effect of an increasing organic loading rate (OLR) and volume exchange ratio (VER) were investigated one after another. Remarkable changes of the specific oxygen uptake rate (sOUR), microscopic structure, sludge volume index (SVI), SVI 30 /SVI 5 ratio, and settling rate were observed during adaptation. sOUR increased two to five times and treatment time decreased 43.9% in 15 days. Stabilization of the SVI occurred after a period of 20 days and improved significantly from 300 mL·g -1 to 80 mL·g -1 . Triplication of the OLR and VER had no negative influence on sludge settling and effluent quality. Adaptation time of the microorganisms to a new feeding pattern, OLR and VER was relatively short and sludge characteristics related to aerobic granular sludge were obtained. This study indicates significant potential of the batch activated sludge system for the treatment of this industrial petrochemical wastewater.

Chicken feather hydrolysate as an inexpensive complex nitrogen source for PHA production by Cupriavidus necator on waste frying oils.

Science.gov (United States)

Benesova, P; Kucera, D; Marova, I; Obruca, S

2017-08-01

The chicken feather hydrolysate (FH) has been tested as a potential complex nitrogen source for the production of polyhydroxyalkanoates by Cupriavidus necator H16 when waste frying oil was used as a carbon source. The addition of FH into the mineral salt media with decreased inorganic nitrogen source concentration improved the yields of biomass and polyhydrohyalkanoates. The highest yields were achieved when 10 vol.% of FH prepared by microwave-assisted alkaline hydrolysis of 60 g l -1 feather was added. In this case, the poly(3-hydroxybutyrate) (PHB) yields were improved by more than about 50% as compared with control cultivation. A positive impact of FH was also observed for accumulation of copolymer poly(3-hydroxybutyrate-co-3-hydroxyvalerate) when sodium propionate was used as a precursor. The copolymer has superior processing and mechanical properties in comparison with PHB homopolymer. The application of FH eliminated the inhibitory effect of propionate and resulted in altered content of 3-hydroxyvalerate (3HV) in copolymer. Therefore, the hydrolysed feather can serve as an excellent complex source of nitrogen for the polyhydroxyalkanoates (PHA) production. Moreover, by the combination of two inexpensive types of waste, such as waste frying oil and feather hydrolysate, it is possible to produce PHA with substantially improved efficiency and sustainability. Millions of tons of feathers, important waste product of poultry-processing industry, are disposed off annually without any further benefits. Thus, there is an inevitable need for new technologies that enable ecologically and economically sensible processing of this waste. Herein, we report that alkali-hydrolysed feathers can be used as a complex nitrogen source considerably improving polyhydroxyalkanoates production on waste frying oil employing Cupriavidus necator. © 2017 The Society for Applied Microbiology.

Case studies illustrating in-situ remediation methods for soil and groundwater contaminated with petrochemicals

Energy Technology Data Exchange (ETDEWEB)

Dixon, Robert A; Lance, P E; Downs, A; Kier, Brian P [EMCON Northwest Inc., Portland, OR (United States)

1994-12-31

Four case studies of successful in-situ remediation are summarized illustrating cost-effective methods to remediate soil and groundwater contaminated with volatile and non-volatile petrochemicals. Each site is in a different geologic environment with varying soil types and with and without groundwater impact. The methods described include vadose zone vapor extraction, high-vacuum vapor extraction combined with groundwater tab.le depression, air sparging with groundwater recovery and vapor extraction, and bio remediation of saturated zone soils using inorganic nutrient and oxygen addition

Case studies illustrating in-situ remediation methods for soil and groundwater contaminated with petrochemicals

Energy Technology Data Exchange (ETDEWEB)

Dixon, Robert A.; Lance, P.E.; Downs, A.; Kier, Brian P. [EMCON Northwest Inc., Portland, OR (United States)

1993-12-31

Four case studies of successful in-situ remediation are summarized illustrating cost-effective methods to remediate soil and groundwater contaminated with volatile and non-volatile petrochemicals. Each site is in a different geologic environment with varying soil types and with and without groundwater impact. The methods described include vadose zone vapor extraction, high-vacuum vapor extraction combined with groundwater tab.le depression, air sparging with groundwater recovery and vapor extraction, and bio remediation of saturated zone soils using inorganic nutrient and oxygen addition

Environmental surveillance for the INEL Radioactive-Waste-Management complex. Annual report 1981

International Nuclear Information System (INIS)

Janke, D.H.; Zahn, T.P.

1982-09-01

The 1981 environmental surveillance report for the Radioactive Waste Management Complex of the Idaho National Engineering Laboratory contains data and discussions about routine radiological monitoring of the atmospheric, hydrologic, and geologic environments of the RWMC. Additional discussions include results of routine monitoring of two surplus facilities, the Stationary Low-Power Reactor No. 1 Surplus Area and the Organic Moderated Reactor Experiment. Each area has produced localized effects on the environment, but containment is well within the INEL site boundary

Integration of complex-wide mixed low-level waste activities for program acceleration and optimization

International Nuclear Information System (INIS)

McKenney, D.E.

1998-01-01

In July 1996, the US Department of Energy (DOE) chartered a contractor-led effort to develop a suite of technically defensible, integrated alternatives which would allow the Environmental Management program to accomplish its mission objectives in an accelerated fashion and at a reduced cost. These alternatives, or opportunities, could then be evaluated by DOE and stakeholders for possible implementation, given precursor requirements (regulatory changes, etc.) could be met and benefits to the Complex realized. This contractor effort initially focused on six waste types, one of which was Mixed Low-Level Waste (MLLW). Many opportunities were identified by the contractor team for integrating MLLW activities across the DOE Complex. These opportunities were further narrowed to six that had the most promise for implementation and savings to the DOE Complex. The opportunities include six items: (1) the consolidation of individual site analytical services procurement efforts, (2) the consolidation of individual site MLLW treatment services procurement efforts, (3) establishment of ''de minimus'' radioactivity levels, (4) standardization of characterization requirements, (5) increased utilization of existing DOE treatment facilities, and (6) using a combination of DOE and commercial MLLW disposal capacity. The results of the integration effort showed that by managing MLLW activities across the DOE Complex as a cohesive unit rather than as independent site efforts, the DOE could improve the rate of progress toward meeting its objectives and reduce its overall MLLW program costs. Savings potential for MLLW, if the identified opportunities could be implemented, could total $224 million or more. Implementation of the opportunities also could result in the acceleration of the MLLW ''work off schedule'' across the DOE Complex by five years

Corporate Social responsibility in the petrochemical industry: Exploring current trends in social and environmental disclosure

OpenAIRE

Lei, Juan

2006-01-01

Current trends indicate that we are entering a new phase of corporate responsibility reporting that more emphasis is paid on social responsibility, but significant variation still remains in the maturity of reporting content and styles in industries, and even in the same industry. This study explores the current trend of corporate social and environmental reporting in petrochemical industry. It offers a detailed review of the development of corporate social responsibility reporting, and of th...

Health Risk Assessment of Harmful Chemicals: Case Study in a Petrochemical Industry

Directory of Open Access Journals (Sweden)

M. Motovagheh

2011-01-01

Full Text Available Background and aims In the most chemical process industries, workers are exposed to various chemicals and working with these chemicals without considering safety and health considerations can lead to different harmful symptoms. For deciding about control measures and reducing risk to acceptable level , it is necessary to assess the health risk of exposing to harmful chemicals by aid of specific risk assessment techniques in the process industries. The purpose of this study was to assess the health risks arising from the exposures to chemicals in a petrochemical industry.  methods A simple and applied method was used for health risk assessment of chemicals in a petrochemical industry. Firstly job tasks and work process were determined and then different chemicals in each tasks identified and risk ranking was calculated in each job task by aid of hazard and exposure rate.   Results The result showed that workers are exposed to 10 chemicals including Methyl ethyl ketone, Epichlorohydrin, Sulfuric acid, Phenol, Chlorobenzene, Toluene, Isopropanol, Methylene chloride, Chlorideric Acid and Acetone during their work in plant. From these chemicals, the highest risk level was for Epichlorohydrin in the jobs of tank and utility operations and maintenance workers. The next high risk level was for Epichlorohydrin in technical inspecting and Methyl ethyl ketone in Tank and utility operations operator.     Conclusion Hazard information and monitoring data of chemical agents in the chemical industries can be used for assessing health risks from exposures to chemicals and ranking jobs by their risk level. These data can be used for resource allocation for control measures and reducing risk level to acceptable level.    

Fermentative Succinate Production: An Emerging Technology to Replace the Traditional Petrochemical Processes

Directory of Open Access Journals (Sweden)

Yujin Cao

2013-01-01

Full Text Available Succinate is a valuable platform chemical for multiple applications. Confronted with the exhaustion of fossil energy resources, fermentative succinate production from renewable biomass to replace the traditional petrochemical process is receiving an increasing amount of attention. During the past few years, the succinate-producing process using microbial fermentation has been made commercially available by the joint efforts of researchers in different fields. In this review, recent attempts and experiences devoted to reduce the production cost of biobased succinate are summarized, including strain improvement, fermentation engineering, and downstream processing. The key limitations and challenges faced in current microbial production systems are also proposed.

Assessing corrosion in oil refining and petrochemical processing

Directory of Open Access Journals (Sweden)

Randy C. John

2004-03-01

Full Text Available This paper summarizes the development of an information system used to manage corrosion of metals and alloys by high temperature gases found in many different oil refining, petrochemical, power generation, and chemical processes. The database currently represents about 7.9 million h of exposure time for about 5,500 tests with 89 commercial alloys for a temperature range of 200 - 1,200°C. The system manages corrosion data from well-defined exposures and determines corrosion product stabilities. New models used in the analysis of thermochemical data for the Fe-Ni-Cr-Co-C-O-S-N-H system are being compiled. All known phases based upon combinations of the elements have been analyzed to allow complete assessments of corrosion product stabilities. Use of these data allows prediction of stable corrosion products and hence identification of the possible dominant corrosion mechanisms. The system has the potential to be used in corrosion research, alloy development, failure analysis, lifetime prediction, and process operations evaluations. The corrosion mechanisms emphasized are oxidation, sulfidation, sulfidation/oxidation, and carburization.

Testing in power plant construction as well as in the petrochemical and chemical industry

International Nuclear Information System (INIS)

Riess, N.; Schittko, H.

1978-01-01

In general, the upgrading of requirements for the most different fields of engineering is also characterized by a corresponding effort in testing. In this context especially nondestructive tests of materials are of outstanding importance. In the fields of power plant construction (among others, components for nuclear power plants) as well as petrochemical and chemical industry considered here, almost all nondestructive test methods are applied. This paper discusses not so much theoretical testing problems, but rather test objects as well as specifications and testing equipment. (orig./HP) [de

The complex using of coals of Ekibastuz coal basin and wastes of their development

International Nuclear Information System (INIS)

Gorlov, E.G.; Kost, L.A.; Lebedeva, L.N.; Shpirt, M.Ya.

2013-01-01

Present article is devoted to main directions of complex using of coals of Ekibastuz coal basin and wastes of their development. It was found that gasification of Ekibastuz coals is the perspective way of their using. It is defined that coal gasification could solve the ecological problems which arise at industrial combustion of coal. Therefore, the thermodynamic and experimental researches were conducted.

Petrochemical wastewater treatment by means of clean electrochemical technologies

Energy Technology Data Exchange (ETDEWEB)

Dimoglo, A.; Akbulut, H.Y.; Cihan, F.; Karpuzcu, M. [Gebze Institute of Technology, Kocaeli (Turkey)

2004-09-01

The removal of chemical oxygen demand (COD), turbidity, phenol, hydrocarbon and grease from petrochemical wastewater (PCWW) was experimentally done by using electroflotation (EF) and electrocoagulation (EC). In the EF unit, a graphite anode and a stainless steel mesh as cathode were used. In the EC unit, iron and aluminium were used simultaneously as materials for two blocks of alternating electrodes. The reactor voltage was 12 V, current density (CD) was varied from 5 to 15 mA cm{sup -2}, and the residence time varied in the limits of 2-20 min for EF and 1-10 min for EC. The results have shown that EC removes the mentioned contaminants from PCWW more effectively than EF. Turbidity removal in the process of PCWW purification was estimated as 83% for EF and 88% for EC. The yields of phenol, hydrocarbon and grease removal by EC were examined under different values of residence time, CD, and with iron and aluminium as materials for electrodes. (orig.)

Petrochemical industries diagnosis concerning competition, quality and productivity programs; Diagnostico de industrias petroquimicas face aos programas de competitividade, produtividade e qualidade

Energy Technology Data Exchange (ETDEWEB)

Souza Antunes, Adelaide Maria de; Chamas, Claudia Ines [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia

1992-12-31

The objective of this study is to evaluate how brazilian petrochemical industries take technological and competitive strategies. New industrial policy emphasizes quality, productivity and competitiveness aspects. The sector company survival depends on fitting to competition patterns. (author) 6 refs.

Petrochemical industries diagnosis concerning competition, quality and productivity programs; Diagnostico de industrias petroquimicas face aos programas de competitividade, produtividade e qualidade

Energy Technology Data Exchange (ETDEWEB)

Souza Antunes, Adelaide Maria de; Chamas, Claudia Ines [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia

1993-12-31

The objective of this study is to evaluate how brazilian petrochemical industries take technological and competitive strategies. New industrial policy emphasizes quality, productivity and competitiveness aspects. The sector company survival depends on fitting to competition patterns. (author) 6 refs.

Volatile organic compounds (VOCs) emission characteristics and control strategies for a petrochemical industrial area in middle Taiwan.

Science.gov (United States)

Yen, Chia-Hsien; Horng, Jao-Jia

2009-11-01

This study investigated VOC emissions from the largest petrochemical industrial district in Taiwan and recommended some control measures to reduce VOC emissions. In addition to the petrochemical industry, the district encompasses a chemical and fiber industry, a plastics industry and a harbor, which together produce more than 95% of the VOC emissions in the area. The sequence of VOC emission was as follows: components (e.g., valves, flanges, and pumps) (47%) > tanks (29%) > stacks (15%) > wastewater treatment facility (6%) > loading (2%) > flares (1%). Other plants producing high-density polyethylene (HDPE), styrene, ethylene glycol (EG), gas oil, and iso-nonyl-alchol (INA) were measured to determine the VOC leaching in the district. The VOC emissions of these 35 plants (90% of all plants) were less than 100 tons/year. About 74% of the tanks were fixed-roof tanks that leached more VOCs than the other types of tanks. To reduce leaching, the components should be checked periodically, and companies should be required to follow the Taiwan EPA regulations. A VOC emission management system was developed in state implementation plans (SIPs) to inspect and reduce emissions in the industrial district.

An integrated multi attribute decision model for energy efficiency processes in petrochemical industry applying fuzzy set theory

International Nuclear Information System (INIS)

Taylan, Osman; Kaya, Durmus; Demirbas, Ayhan

2016-01-01

Graphical abstract: Evaluation of compressors by comparing the different cost parameters. - Highlights: • Fuzzy sets and systems are used for decision making in MCDM problems. • An integrated Fuzzy AHP and fuzzy TOPSIS approaches are employed for compressor selection. • Compressor selection is a highly complex and non-linear process. • This approach increases the efficiency, reliability of alternative scenarios, and reduces the pay-back period. - Abstract: Energy efficient technologies offered by the market increases productivity. However, decision making for these technologies is usually obstructed in the firms and comes up with organizational barriers. Compressor selection in petrochemical industry requires assessment of several criteria such as ‘reliability, energy consumption, initial investment, capacity, pressure, and maintenance cost.’ Therefore, air compressor selection is a multi-attribute decision making (MADM) problem. The aim of this study is to select the most eligible compressor(s) so as to avoid the high energy consumption due to the capacity and maintenance costs. It is also aimed to avoid failures due to the reliability problems and high pressure. MADM usually takes place in a vague and imprecise environment. Soft computing techniques such as fuzzy sets and system can be used for decision making where vague and imprecise knowledge is available. In this study, an integrated fuzzy analytical hierarchy process (FAHP) and fuzzy technique for order performance by similarity to ideal solution (TOPSIS) methodologies are employed for the compressor selection. Fuzzy AHP was used to determine the weights of criteria and fuzzy TOPSIS was employed to order the scenarios according to their superiority. The total effect of all criteria was determined for all alternative scenarios to make an optimal decision. Moreover, the types of compressor, carbon emission, waste heat recovery and their capacities were analyzed and compared by statistical

Identification of the non-pertechnetate species in Hanford waste tanks, Tc(I) carbonyl complexes

Energy Technology Data Exchange (ETDEWEB)

Lukens, Wayne W.; Shuh, David K.; Schroeder, Norman C.; Ashley, Kenneth R.

2003-10-16

Immobilization of the high-level nuclear waste stored at the Hanford Reservation has been complicated by the presence of soluble, lower-valent technetium species. Previous work by Schroeder and Blanchard has shown that these species cannot be removed by ion-exchange and are difficult to oxidize. The Tc-K edge XANES spectra of the species in Tanks SY-101 and SY-103 were reported by Blanchard, but they could not be assigned to any known technetium complex. We report that the XANES spectra are most likely those of Tc(I) carbonyl species, especially fac-Tc(CO){sub 3}(gluconate){sup 2-}. This is further supported by EXAFS and {sup 99}Tc-NMR studies in nonradioactive simulants of these tank wastes.

Risk factors affecting visual-motor coordination deficit among children residing near a petrochemical industrial estate.

Science.gov (United States)

Aungudornpukdee, P; Vichit-Vadakan, N

2009-12-01

Thailand has been changed to rapid urbanization and industrialization since 1980s. During 1992 through 1996, the number of industrial factories in Rayong province increased very sharply. The major types of industries are petrol-chemical and plastic production. However, after the petrochemical industry boomed, the higher demand led to an industrial area expansion. The establishment of factories in this area leads to serious environmental and health impacts. The study aims to investigate the factors that affect visual-motor coordination deficit among children, 6-13 years of age, residing near the Petrochemical Industrial Estate, Map Ta Phut, Rayong province. A population-based cross-sectional study was employed for collecting data on neurobehavioral effects using the Digit Symbol Test. The study found one-third of 2,956 children presented with visual-motor coordination deficits. Three factors were identified that caused children to have a higher risk of visual-motor coordination deficits: gender (adjusted OR 1.934), monthly parental income (range of adjusted OR 1.977 - 2.612), and household environmental tobacco smoke (adjusted OR 1.284), while age (adjusted OR 0.874) and living period (adjusted OR 0.954) in study areas were reversed effects on visual-motor coordination deficit among children. The finding indicated that children with visual-motor coordination deficit were affected by gender, monthly parental income, age of children, length of living period, and household environmental tobacco smoke.

In-depth analysis of the causal factors of incidents reported in the Greek petrochemical industry

International Nuclear Information System (INIS)

Konstandinidou, Myrto; Nivolianitou, Zoe; Kefalogianni, Eirini; Caroni, Chrys

2011-01-01

This paper presents a statistical analysis of all reported incidents in the Greek petrochemical industry from 1997 to 2003. A comprehensive database has been developed to include industrial accidents (fires, explosions and substance releases), occupational accidents, incidents without significant consequences and near misses. The study concentrates on identifying and analyzing the causal factors related to different consequences of incidents, in particular, injury, absence from work and material damage. Methods of analysis include logistic regression with one of these consequences as dependent variable. The causal factors that are considered cover four major categories related to organizational issues, equipment malfunctions, human errors (of commission or omission) and external causes. Further analyses aim to confirm the value of recording near misses by comparing their causal factors with those of more serious incidents. The statistical analysis highlights the connection between the human factor and the underlying causes of accidents or incidents. - Highlights: → The research work is original, based on field data collected directly from the petrochemical industry. → It deals with the in-depth statistical analysis of accident data on human-organizational causes. → It researches underlying causes of accidents and the parameters affecting them. → The causal factors that are considered cover four big taxonomies. → Near misses are worth recording for comparing their causal factors with more serious incidents.

Dynamic modeling of uncertainty in the planned values of investments in petrochemical and refining projects

International Nuclear Information System (INIS)

Vianello, Juliano Melquiades; Costa, Leticia; Teixeira, José Paulo

2014-01-01

There is a large gap between the planned value of investment in a project and its financial implementation. This fact creates a mismatch between the planned and effectively achieved net present value (NPV) of the project. Considering the project portfolio of a company, this could even threaten your solvency in the future. Therefore, a quantitative-risk analysis that takes into account different possible scenarios for these values of investment is extremely important to measure statistically the real value of a project. The aim of this paper is to present the reasons for this mismatch between planned and executed investments and, from this study, obtain a suitable stochastic process to generate different scenarios for these investments in the oil industry. Although the results are valid for projects in the petrochemical and refining sector, also called in the oil industry as downstream, the methodology can be applied to the upstream or even other branches of industry. - Highlights: • We measure statistically the real value of an investment project. • We present the reasons for the mismatch between planned and executed investments. • We obtain a stochastic process to generate scenarios for oil industry investments. • Results are valid for projects in the petrochemical and refining sector, downstream. • The methodology can be applied to the upstream or even other branches of industry

Effect of exposure to a mixture of organic solvents on hearing thresholds in petrochemical industry workers.

Science.gov (United States)

Loukzadeh, Ziba; Shojaoddiny-Ardekani, Ahmad; Mehrparvar, Amir Houshang; Yazdi, Zohreh; Mollasadeghi, Abolfazl

2014-10-01

Hearing loss is one of the most common occupational diseases. In most workplaces, workers are exposed to noise and solvents simultaneously, so the potential risk of hearing loss due to solvents may be attributed to noise. In this study we aimed to assess the effect of exposure to mixed aromatic solvents on hearing in the absence of exposure to hazardous noise. In a cross-sectional study, 99 workers from the petrochemical industry with exposure to a mixture of organic solvents whose noise exposure was lower than 85 dBA were compared with 100 un-exposed controls. After measuring sound pressure level and mean concentration of each solvent in the workplace, pure-tone-audiometry was performed and the two groups were compared in terms of high-frequency and low-frequency hearing loss. T-tests and Chi-square tests were used to compare the two groups. The mean hearing threshold at all frequencies among petrochemical workers was normal (below 25 dB). We did not observe any significant association between solvent exposure and high-frequency or low-frequency hearing loss. This study showed that temporary exposure (less than 4 years) to a mixture of organic solvents, without exposure to noise, does not affect workers' hearing threshold in audiometry tests.

TECHNICAL AND ECONOMIC EVALUATION OF THE SEPARATION OF LIGHT OLEFINS (ETHYLENE AND PROPYLENE) BY USING p-COMPLEXATION WITH SILVER SALTS

OpenAIRE

Salgado-Gordon, Hernando-José; Valbuena-Moreno, Gleidy

2011-01-01

ABSTRACT Conventional processes for separation of ethylene and propylene until reaching petrochemical grade are energy intensive. Therefore, alternative separation methods, such as chemical affinity based technologies, are an interesting alternative for designing more sustainable processes. p-Complexation of the silver ion (Ag+) is one of these technologies. In this study, p-complexation is compared to the conventional technologies from process and economic points of view, in order to determi...

Complex-wide review of DOE's Low-Level Waste Management ES ampersand H vulnerabilities. Volume I. Final report

International Nuclear Information System (INIS)

1996-05-01

The Department of Energy (DOE) conducted a comprehensive complex-wide review of its management of low-level waste (LLW) and the radioactive component of mixed low-level waste (MLLW). This review was conducted in response to a recommendation from the Defense Nuclear Facilities Safety Board (DNFSB) which was established and authorized by Congress to oversee DOE. The DNFSB's recommendation concerning conformance with safety standards at DOE LLW sites was issued on September 8, 1994 and is referred to as Recommendation 94-2. DOE's Implementation Plan for its response to Recommendation 94-2 was submitted to the DNFSB on March 31, 1995. The DNFSB recommended that a complex-wide review of DOE's LLW management be initiated. The goal of the complex-wide review of DOE's LLW management system was to identify both programmatic and physical vulnerabilities that could lead to unnecessary radiation exposure of workers or the public or unnecessary releases of radioactive materials to the environment. Additionally, the DNFSB stated that an objective of the complex-wide review should be to establish the dimensions of the DOE LLW problem and support the identification of corrective actions to address safe disposition of past, present, and future volumes of LLW. The complex-wide review involved an evaluation of LLW management activities at 38 DOE facilities at 36 sites that actively manage LLW and MLLW

Solid Waste Operations Complex W-113: Project cost estimate. Preliminary design report. Volume IV

International Nuclear Information System (INIS)

1995-01-01

This document contains Volume IV of the Preliminary Design Report for the Solid Waste Operations Complex W-113 which is the Project Cost Estimate and construction schedule. The estimate was developed based upon Title 1 material take-offs, budgetary equipment quotes and Raytheon historical in-house data. The W-113 project cost estimate and project construction schedule were integrated together to provide a resource loaded project network

Expert (Peer) Reviews at the Waste Isolation Pilot Plant (WIPP): Making Complex Information and Decision Making Transparent

International Nuclear Information System (INIS)

Eriksson, Leif G.

2001-01-01

On the 18th of May 1998, based on the information provided by the United Sates Department of Energy (DOE) in support of the 1996 Waste Isolation Pilot Plant (WIPP) Compliance Certification Application, the U.S. Environmental Protection Agency certified the proposed deep geological repository for disposal of long-lived, defense-generated, transuranic radioactive waste at the WIPP site in New Mexico, United States of America, was compliant with all applicable radioactive waste disposal regulations. Seven domestic and one joint international peer reviews commissioned by the DOE were instrumental in making complex scientific and engineering information, as well as the related WIPP decision-making process, both credible and transparent to the majority of affected and interested parties and, ultimately, to the regulator

Expert (Peer) Reviews at the Waste Isolation Pilot Plant (WIPP): Making Complex Information and Decision Making Transparent

Energy Technology Data Exchange (ETDEWEB)

Eriksson, Leif G. [GRAM, Inc., Albuquerque, NM (United States)

2001-07-01

On the 18th of May 1998, based on the information provided by the United Sates Department of Energy (DOE) in support of the 1996 Waste Isolation Pilot Plant (WIPP) Compliance Certification Application, the U.S. Environmental Protection Agency certified the proposed deep geological repository for disposal of long-lived, defense-generated, transuranic radioactive waste at the WIPP site in New Mexico, United States of America, was compliant with all applicable radioactive waste disposal regulations. Seven domestic and one joint international peer reviews commissioned by the DOE were instrumental in making complex scientific and engineering information, as well as the related WIPP decision-making process, both credible and transparent to the majority of affected and interested parties and, ultimately, to the regulator.

Selection of low-level radioactive waste disposal sites using screening models versus more complex methodologies

International Nuclear Information System (INIS)

Uslu, I.; Fields, D.E.

1993-01-01

The task of choosing a waste-disposal site from a set of candidate sites requires an approach capable of objectively handling many environmental variables for each site. Several computer methodologies have been developed to assist in the process of choosing a site for the disposal of low-level radioactive waste; however, most of these models are costly to apply, in terms of computer resources and the time and effort required by professional modelers, geologists, and waste-disposal experts. The authors describe how the relatively simple DRASTIC methodology (a standardized system for evaluating groundwater pollution potential using hydrogeologic settings) may be used for open-quotes pre-screeningclose quotes of sites to determine which subset of candidate sites is worthy of more detailed screening. Results of site comparisons made with DRASTIC are compared with results obtained using PRESTO-II methodology, which is representative of the more complex release-transport-human exposure methodologies. 6 refs., 1 fig., 1 tab

Ecology studies at the Idaho National Engineering Laboratory Radioactive Waste Management Complex

International Nuclear Information System (INIS)

Arthur, W.J.; Markham, O.D.

1978-01-01

In September 1977 a radioecological research program was initiated at the Idaho National Engineering Laboratory (INEL) Radioactive Waste Management Complex in the southcentral Idaho. The primary goals of the research are to: (1) determine floral and faunal composition in the area; (2) sample various ecosystem components for radionuclides; (3) determine impacts of small mammal burrowing and vegetation growth on movement of radioactive materials; (4) compare ambient radiation exposures to radiation doses received by animals inhabiting the area; and (5) understand the interrelationships between the organisms and their role in radionuclide transport

Comparing the steam and electric heat tracing solutions for petrochemical or refining facilities

Energy Technology Data Exchange (ETDEWEB)

Young, Joseph G.; McQueen, Greg [Tyco Thermal Controls, Belgie (Belgium)

2012-07-01

In this era of energy conservation and cost reduction, the ability to effectively select the optimal solution to meet the heat management system needs of petrochemical or refining facilities is becoming increasingly important. Depending on the type and location of the plant, a heat management system (HMS) can comprise a significant portion of the overall capital expenditure, as well as the ongoing operating and maintenance costs. Several important heat management system design decisions affect the financial operations of a facility, including the selection of the heat tracing technology, the utility distribution scheme, and the insulation system criteria, among others. However, most of these decisions are made early in the project life-cycle without thorough analysis of the various options available. From a high level perspective, numerous heat trace media should be considered, including electric, steam, tempered water, and glycol. These systems also have different impacts on piping systems within the plant battery limits (ISBL) and transfer lines outside of the battery limits (OSBL). This paper takes a careful look at two of the predominant heat tracing technologies - electric heat tracing and steam tracing - and compares these within the larger framework of the heat management system, and relative to petrochemical or refining facilities within the general Brazil geography. In the broader context, a heat management system is defined as the heat tracing technology itself, the utility distribution associated with that technology, the control and monitoring scheme associated with that technology, and the insulation system. We will evaluate the capital expenditure cost, operating expenditure cost, and overall reliability of the electric and steam tracing mediums in both the ISBL and OSBL environments within this broader context. (author)

A new tool for risk analysis and assessment in petrochemical plants

Directory of Open Access Journals (Sweden)

El-Arkam Mechhoud

2016-09-01

Full Text Available The aim of our work was the implementation of a new automated tool dedicated to risk analysis and assessment in petrochemical plants, based on a combination of two analysis methods: HAZOP (HAZard and OPerability and FMEA (Failure Mode and Effect Analysis. Assessment of accident scenarios is also considered. The principal advantage of the two analysis methods is to speed-up hazard identification and risk assessment and forecast the nature and impact of such accidents. Plant parameters are analyzed under a graphical interface to facilitate the exploitation of our developed approach. This automated analysis brings out the different deviations of the operating parameters of any system in the plant. Possible causes of these deviations, their consequences and preventive actions are identified. The result is risk minimization and dependability enhancement of the considered system.

Concept of ecological corridors and agroforestal systems applied for the implementation of PETROBRAS punctual and linear projects: case study of COMPERJ (Rio de Janeiro Petrochemical Complex); Conceito de corredores ecologicos e sistemas agroflorestais aplicados a implantacao de empreendimentos pontuais e lineares em ambito PETROBRAS: estudo de caso do COMPERJ (Complexo Petroquimico do Rio de Janeiro)

Energy Technology Data Exchange (ETDEWEB)

Secron, Marcelo B; Mesquita, Ivan D; Soares, Luiz Felipe R; Almeida, Ronaldo Bento G. de; Fernandes, Renato; Dellamea, Giovani S [PETROBRAS, Rio de Janeiro, RJ (Brazil); Nunes, Rodrigo T; Pereira, Junior, Edson Rodrigues [SEEBLA, Servicos de Engenharia Emilio Baumgart Ltda., Rio de Janeiro, RJ (Brazil)

2008-07-01

The land use and human occupation realized with an indiscriminate form across many parts of the world, including Brazil, have been causing destruction of great amount of forest mass and green areas. These actions results an isolation of a forest reminder fragment, and in such case, along the time, these fragments become weak and debilitated, characterizing general biodiversity loss or its extinction, in a worse case. This study presents basic concepts of ecological corridors and agroforestal systems, showing the case study that will be implemented in COMPERJ (Rio de Janeiro Petrochemical Complex), pointing the aspects that can be applied for PETROBRAS to offset impacts (biodiversity offsets concept) of punctual and linear projects. (author)

Solid waste operations complex engineering verification program plan

International Nuclear Information System (INIS)

Bergeson, C.L.

1994-01-01

This plan supersedes, but does not replace, the previous Waste Receiving and Processing/Solid Waste Engineering Development Program Plan. In doing this, it does not repeat the basic definitions of the various types or classes of development activities nor provide the rigorous written description of each facility and assign the equipment to development classes. The methodology described in the previous document is still valid and was used to determine the types of verification efforts required. This Engineering Verification Program Plan will be updated on a yearly basis. This EVPP provides programmatic definition of all engineering verification activities for the following SWOC projects: (1) Project W-026 - Waste Receiving and Processing Facility Module 1; (2) Project W-100 - Waste Receiving and Processing Facility Module 2A; (3) Project W-112 - Phase V Storage Facility; and (4) Project W-113 - Solid Waste Retrieval. No engineering verification activities are defined for Project W-112 as no verification work was identified. The Acceptance Test Procedures/Operational Test Procedures will be part of each project's Title III operation test efforts. The ATPs/OTPs are not covered by this EVPP

Complex concentrate pretreatment

International Nuclear Information System (INIS)

Lokken, R.O.; Scheele, R.D.; Strachan, D.M.; Toste, A.P.

1991-03-01

After removal of the transuranics (TRU) by the TRUEX process, complex concentrate waste will be grouted for final storage. The purpose of this project, conducted at the Pacific Northwest Laboratory, is to support a future decision to grout the complexant waste without destruction of the organic contents. It has been demonstrated that grouts with acceptable parameters for the Transportable Grout Facility can be made using actual waste. The acceptability of these grouts from a regulatory view seems to be less of a problem than previously. None of the organics found in the waste have been found on the EPA hazardous chemicals list. Two potential problems with the processing of the complex concentrate wastes were identified during the use of the TRUEX process on samples of several milliliters. One was the amount of foam that is generated during acid addition to the alkaline waste. Some of this foam appears to be of a waxy nature but does redissolve when the waste is strongly acid. The second potential problem is that noticeable amounts of NO x gases are generated. No quantitative measure of the NO x gas generation was made. The problem relates to processing the waste in B-plant where there are no facilities to handle NO x gases. 5 refs., 4 figs., 4 tabs

Aggradational and erosional history of the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory

International Nuclear Information System (INIS)

Dechert, T.V.; McDaniel, P.A.; Falen, A.L.

1994-09-01

Long-term performance of the low-level waste disposal site at the Radioactive Waste Management Complex (RWMC) is partially dependent on the stability of the land surface with respect to erosion of cover materials. This document discusses the aggradational and erosional history of the naturally occurring sediments and soils in and around the RWMC, focusing on the late-Pleistocene and Holocene epochs. Other related issues include the ages of the various deposits, the extent to which they have been altered by soil formation and other processes, their relationships to the basalt flows in the area, and the impact of human activity on the materials at the RWMC

Aggradational and erosional history of the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory

Energy Technology Data Exchange (ETDEWEB)

Dechert, T.V.; McDaniel, P.A.; Falen, A.L. [Idaho Univ., Moscow, ID (United States)

1994-09-01

Long-term performance of the low-level waste disposal site at the Radioactive Waste Management Complex (RWMC) is partially dependent on the stability of the land surface with respect to erosion of cover materials. This document discusses the aggradational and erosional history of the naturally occurring sediments and soils in and around the RWMC, focusing on the late-Pleistocene and Holocene epochs. Other related issues include the ages of the various deposits, the extent to which they have been altered by soil formation and other processes, their relationships to the basalt flows in the area, and the impact of human activity on the materials at the RWMC.

Process improvement technology for petrochemical plant; Sekiyu kagaku puranto ni okesu purosesu kaizen gijutsu

Energy Technology Data Exchange (ETDEWEB)

Yamada, Shin

1999-05-05

Before, GTC technology Co. was a manufacturer of the tray as a Greenwich technology. It is the subsidiary, which undertakes technology and licence of the engineering firm in U.S.A. at present. It carries out besides the technology licence support in the startup for the prolonged driving of technical service, operating condition of the plant of improvement and optimization and, etc. Has made separation and purification technology, which made extractive distillation to be a beginning good and has the process improvement technology to the PTA (high-pure terephthalic acid) from BTX (benzene toluene xylene) of petrochemical plant. (NEDO)

Complex-wide review of DOE's Low-Level Waste Management ES ampersand H vulnerabilities. Volume II. Final report

International Nuclear Information System (INIS)

1996-05-01

Volume I of this report presents a summary of DOE's complex-wide review of its low-level waste management system, including the assessment scope and methodology, site-specific and complex-wide vulnerabilities, and DOE's conclusions and recommendations. Volume II presents a more detailed discussion of the assessment methodology and evaluation instruments developed by the Assessment Working Group for identifying site-specific vulnerabilities, categorizing and classifying vulnerabilities, and identifying and analyzing complex-wide vulnerabilities. Attachments A and B of this volume contain, respectively, the Site Evaluation Survey and the Vulnerability Assessment Form used in those processes. Volume III contains the site-specific assessment reports for the 36 sites (38 facilities) assessed in the complex-wide review from which the complex-wide vulnerabilities were drawn

Effect of Exposure to a Mixture of Organic Solvents on Hearing Thresholds in Petrochemical Industry Workers

Directory of Open Access Journals (Sweden)

Ziba Loukzadeh

2014-10-01

Full Text Available Introduction: Hearing loss is one of the most common occupational diseases. In most workplaces, workers are exposed to noise and solvents simultaneously, so the potential risk of hearing loss due to solvents may be attributed to noise.  In this study we aimed to assess the effect of exposure to mixed aromatic solvents on hearing in the absence of exposure to hazardous noise.   Materials and Methods: In a cross-sectional study, 99 workers from the petrochemical industry with exposure to a mixture of organic solvents whose noise exposure was lower than 85 dBA were compared with 100 un-exposed controls. After measuring sound pressure level and mean concentration of each solvent in the workplace, pure-tone-audiometry was performed and the two groups were compared in terms of high-frequency and low-frequency hearing loss. T-tests and Chi-square tests were used to compare the two groups.   Results: The mean hearing threshold at all frequencies among petrochemical workers was normal (below 25 dB. We did not observe any significant association between solvent exposure and high-frequency or low-frequency hearing loss.   Conclusion:  This study showed that temporary exposure (less than 4 years to a mixture of organic solvents, without exposure to noise, does not affect workers’ hearing threshold in audiometry tests.

The Impact of Job Stress and Job Satisfaction on Workforce Productivity in an Iranian Petrochemical Industry.

Science.gov (United States)

Hoboubi, Naser; Choobineh, Alireza; Kamari Ghanavati, Fatemeh; Keshavarzi, Sareh; Akbar Hosseini, Ali

2017-03-01

Job stress and job satisfaction are important factors affecting workforce productivity. This study was carried out to investigate the job stress, job satisfaction, and workforce productivity levels, to examine the effects of job stress and job satisfaction on workforce productivity, and to identify factors associated with productivity decrement among employees of an Iranian petrochemical industry. In this study, 125 randomly selected employees of an Iranian petrochemical company participated. The data were collected using the demographic questionnaire, Osipow occupational stress questionnaire to investigate the level of job stress, Job Descriptive Index to examine job satisfaction, and Hersey and Goldsmith questionnaire to investigate productivity in the study population. The levels of employees' perceived job stress and job satisfaction were moderate-high and moderate, respectively. Also, their productivity was evaluated as moderate. Although the relationship between job stress and productivity indices was not statistically significant, the positive correlation between job satisfaction and productivity indices was statistically significant. The regression modeling demonstrated that productivity was significantly associated with shift schedule, the second and the third dimensions of job stress (role insufficiency and role ambiguity), and the second dimension of job satisfaction (supervision). Corrective measures are necessary to improve the shift work system. "Role insufficiency" and "role ambiguity" should be improved and supervisor support must be increased to reduce job stress and increase job satisfaction and productivity.

Improving societal acceptance of rad waste management policy decisions: an approach based on complex intelligence

International Nuclear Information System (INIS)

Rao, Suman

2008-01-01

In today's context elaborate public participation exercises are conducted around the world to elicit and incorporate societal risk perceptions into nuclear policy Decision-Making. However, on many occasions, such as in the case of rad waste management, the society remains unconvinced about these decisions. This naturally leads to the questions: are techniques for incorporating societal risk perceptions into the rad waste policy decision making processes sufficiently mature? How could societal risk perceptions and legal normative principles be better integrated in order to render the decisions more equitable and convincing to society? Based on guidance from socio-psychological research this paper postulates that a critical factor for gaining/improving societal acceptance is the quality and adequacy of criteria for option evaluation that are used in the policy decision making. After surveying three rad waste public participation cases, the paper identifies key lacunae in criteria abstraction processes as currently practiced. A new policy decision support model CIRDA: Complex Intelligent Risk Discourse Abstraction model that is based on the heuristic of Risk-Risk Analysis is proposed to overcome these lacunae. CIRDA's functionality of rad waste policy decision making is modelled as a policy decision-making Abstract Intelligent Agent and the agent program/abstraction mappings are presented. CIRDA is then applied to a live (U.K.) rad waste management case and the advantages of this method as compared to the Value Tree Method as practiced in the GB case are demonstrated. (author)

Monitoring of meteorology and air quality at influence area of COMPERJ (Rio de Janeiro Petrochemical Complex); Monitoramento meteorologico e da qualidade do ar na regiao de influencia do COMPERJ (Complexo Petroquimico do Rio de Janeiro)

Energy Technology Data Exchange (ETDEWEB)

Albuquerque, Edler Lins de; Villa, Felipe de Santana; Lyra, Diogenes Ganghis Pimentel de [CETREL-LUMINA Solucoes Ambientais, Salvador, BA (Brazil); Secron, Marcelo; Iorio, Patricia Freire; Mendes, Marcos Faistauer [PETROBRAS, Rio de Janeiro, RJ (Brazil)

2008-07-01

Rio de Janeiro Petrochemical Complex (COMPERJ) will be installed in the north region of Itaborai city. The start of COMPERJ operations is foreseen to 2012. Because of the intensification of industrialization and urbanization processes, the implantation of COMPERJ will bring environmental modifications for Itaborai city and neighbors areas. Thus, meteorological and air quality monitoring was initiated in February of 2007 with the intention of carrying out a characterization of air pollution in this area, before COMPERJ operations. In this work are presented the results found in campaigns performed of February of 2007 until April of 2008. The meteorological monitoring disclosed that the meteorological parameters have varied enough throughout the months, but these are representative of a global behavior of the studied area. Monitoring of air quality has shown that atmospheric levels of monitored pollutants has been generally below of Brazilian air quality standards. This fact corroborates the basic aspect of the present study: identification of the concentrations 'background' in the studied area. Throughout the period of monitoring, the primary air quality standard for ozone has been reached. Observations of meteorological parameters indicate that this fact is associated to the emissions originated from Sao Goncalo, Niteroi and Rio de Janeiro cities. (author)

2010 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site's Advanced Test Reactor Complex Cold Waste Pond

International Nuclear Information System (INIS)

Lewis, Mike

2011-01-01

This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (LA 000161 01, Modification B), for the wastewater land application site at the Idaho National Laboratory Site's Advanced Test Reactor Complex Cold Waste Pond from November 1, 2009 through October 31, 2010. The report contains the following information: (1) Facility and system description; (2) Permit required effluent monitoring data and loading rates; (3) Groundwater monitoring data; (4) Status of compliance activities; and (5) Discussion of the facility's environmental impacts. During the 2010 permit year, approximately 164 million gallons of wastewater were discharged to the Cold Waste Pond. As shown by the groundwater sampling data, sulfate and total dissolved solids concentrations are highest near the Cold Waste Pond and decrease rapidly as the distance from the Cold Waste Pond increases. Although concentrations of sulfate and total dissolved solids are elevated near the Cold Waste Pond, both parameters were below the Ground Water Quality Rule Secondary Constituent Standards in the down gradient monitoring wells.

Environmental Restoration and Waste Management manpower needs assessment: US Department of Energy complex

Energy Technology Data Exchange (ETDEWEB)

Holmes, C.W.; Lewis, R.E.; Hunt, S.T. (Pacific Northwest Lab., Richland, WA (United States)); Finn, M.G. (Oak Ridge Associated Universities, Inc., TN (United States))

1992-06-01

A study was conducted Pacific Northwest Laboratory and Oak Ridge Associated Universities, Inc. to assess the supply and demand for 53 scientific, engineering, and technical occupations relevant to the US Department of Energy's (DOE's) Office of Environmental Restoration and Waste management (EM). These assessments were made by examining budget projections and the input of program/project and human resources managers throughout the DOE complex. Quantitative projections of full-time equivalent employees slots for each occupation have been developed for the 1993--1997 time frame. Qualitative assessments of the factors that affect recruitment, staffing, and retention are also reported. The implications of the study are discussed within the likely skills mix of the future workforce and the education and organization interventions most likely to address the needs of the DOE complex.

Peripheral blood values in workers occupied in the petrochemical production

Directory of Open Access Journals (Sweden)

G.G. Badamshina

2015-06-01

Full Text Available The study is devoted to solution of the problems of the early changes detection in a body on the stages, when only the conditions for the pathology formation were created. The analysis of peripheral blood in the workers, occupied in petrochemical production, allowed us to diagnose the changes that testify the body defenses’ decrease that occurs under exposure to chemicals. It is shown that in the initial period of exposure to harmful substances the body's reaction to a toxic irritant contain both specific and nonspecific components. The first working years is characterized by the reduction of the number of red blood cells and hemoglobin. Over the next years the gradual stabilization is presented, and then the moderate and persistent increase in red blood indices occur, what indicate on the adaptive nature of the condition. It was established, that in dependence of the tropism, mechanism of action and the hazard class of hazardous substances, the diverse hematological changes in the body workers are revealed.

Certification Plan, Radioactive Mixed Waste Hazardous Waste Handling Facility

International Nuclear Information System (INIS)

Albert, R.

1992-01-01

The purpose of this plan is to describe the organization and methodology for the certification of radioactive mixed waste (RMW) handled in the Hazardous Waste Handling Facility at Lawrence Berkeley Laboratory (LBL). RMW is low-level radioactive waste (LLW) or transuranic (TRU) waste that is co-contaminated with dangerous waste as defined in the Westinghouse Hanford Company (WHC) Solid Waste Acceptance Criteria (WAC) and the Washington State Dangerous Waste Regulations, 173-303-040 (18). This waste is to be transferred to the Hanford Site Central Waste Complex and Burial Grounds in Hanford, Washington. This plan incorporates the applicable elements of waste reduction, which include both up-front minimization and end-product treatment to reduce the volume and toxicity of the waste; segregation of the waste as it applies to certification; an executive summary of the Waste Management Quality Assurance Implementing Management Plan (QAIMP) for the HWHF (Section 4); and a list of the current and planned implementing procedures used in waste certification

Solid waste handling

International Nuclear Information System (INIS)

Parazin, R.J.

1995-01-01

This study presents estimates of the solid radioactive waste quantities that will be generated in the Separations, Low-Level Waste Vitrification and High-Level Waste Vitrification facilities, collectively called the Tank Waste Remediation System Treatment Complex, over the life of these facilities. This study then considers previous estimates from other 200 Area generators and compares alternative methods of handling (segregation, packaging, assaying, shipping, etc.)

2011 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site's Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond

Energy Technology Data Exchange (ETDEWEB)

David Frederick

2012-02-01

This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (LA-000160-01), for the wastewater reuse site at the Idaho National Laboratory Site's Materials and Fuels Complex Industrial Waste Ditch and Industrial Waste Pond from November 1, 2010 through October 31, 2011. The report contains the following information: (1) Facility and system description; (2) Permit required effluent monitoring data and loading rates; (3) Groundwater monitoring data; (4) Status of special compliance conditions; and (5) Discussion of the facility's environmental impacts. During the 2011 reporting year, an estimated 6.99 million gallons of wastewater were discharged to the Industrial Waste Ditch and Pond which is well below the permit limit of 13 million gallons per year. Using the dissolved iron data, the concentrations of all permit-required analytes in the samples from the down gradient monitoring wells were below the Ground Water Quality Rule Primary and Secondary Constituent Standards.

Characterisation of metals in the electronic waste of complex mixtures of end-of-life ICT products for development of cleaner recovery technology

International Nuclear Information System (INIS)

Sun, Z.H.I.; Xiao, Y.; Sietsma, J.; Agterhuis, H.; Visser, G.; Yang, Y.

2015-01-01

Highlights: • New characterisation methodology has been established to understand an industrially processed ICT waste. • Particle size distribution, composition, thermal–chemical behaviour and occurrence of metals were considered. • The characterisation provides direct guidelines for values recovery from the waste. - Abstract: Recycling of valuable metals from electronic waste, especially complex mixtures of end-of-life information and communication technology (ICT) products, is of great difficulty due to their complexity and heterogeneity. One of the important reasons is the lack of comprehensive characterisation on such materials, i.e. accurate compositions, physical/chemical properties. In the present research, we focus on developing methodologies for the characterisation of metals in an industrially processed ICT waste. The morphology, particle size distribution, compositional distribution, occurrence, liberation as well as the thermo-chemical properties of the ICT waste were investigated with various characterisation techniques, including X-ray Fluorescence Spectrometry (XRF), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) with energy dispersed spectroscopy (EDS). Due to the high heterogeneity of the material, special sample preparation procedures were introduced to minimise the discrepancies during compositional analyses. As a result, a clearer overview of the ICT waste has been reached. This research provides better understanding of the extractability of each metal and improves the awareness of potential obstacles for extraction. It will lead to smarter decisions during further development of a clean and effective recovery process

Characterisation of metals in the electronic waste of complex mixtures of end-of-life ICT products for development of cleaner recovery technology

Energy Technology Data Exchange (ETDEWEB)

Sun, Z.H.I. [Department of Materials Science and Engineering, TU Delft, 2628 CD Delft (Netherlands); Xiao, Y. [Ironmaking Department, R and D, Tata Steel, 1970 CA IJmuiden (Netherlands); Sietsma, J. [Department of Materials Science and Engineering, TU Delft, 2628 CD Delft (Netherlands); Agterhuis, H.; Visser, G. [Business Development, Van Gansewinkel Groep BV, 5657 DH Eindhoven (Netherlands); Yang, Y. [Department of Materials Science and Engineering, TU Delft, 2628 CD Delft (Netherlands)

2015-01-15

Highlights: • New characterisation methodology has been established to understand an industrially processed ICT waste. • Particle size distribution, composition, thermal–chemical behaviour and occurrence of metals were considered. • The characterisation provides direct guidelines for values recovery from the waste. - Abstract: Recycling of valuable metals from electronic waste, especially complex mixtures of end-of-life information and communication technology (ICT) products, is of great difficulty due to their complexity and heterogeneity. One of the important reasons is the lack of comprehensive characterisation on such materials, i.e. accurate compositions, physical/chemical properties. In the present research, we focus on developing methodologies for the characterisation of metals in an industrially processed ICT waste. The morphology, particle size distribution, compositional distribution, occurrence, liberation as well as the thermo-chemical properties of the ICT waste were investigated with various characterisation techniques, including X-ray Fluorescence Spectrometry (XRF), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) with energy dispersed spectroscopy (EDS). Due to the high heterogeneity of the material, special sample preparation procedures were introduced to minimise the discrepancies during compositional analyses. As a result, a clearer overview of the ICT waste has been reached. This research provides better understanding of the extractability of each metal and improves the awareness of potential obstacles for extraction. It will lead to smarter decisions during further development of a clean and effective recovery process.

Household food waste

NARCIS (Netherlands)

Wahlen, S.; Winkel, Thomas

2017-01-01

Food waste is debated not only in the light of sustainable consumption in research and policy, but also in the broader public. This article focuses on food waste in household contexts, what is widely believed the end of the food chain. However, household food waste is far more complex and intricate

Experimental evaluation of main emissions during coal processing waste combustion.

Science.gov (United States)

Dmitrienko, Margarita A; Legros, Jean C; Strizhak, Pavel A

2018-02-01

The total volume of the coal processing wastes (filter cakes) produced by Russia, China, and India is as high as dozens of millions of tons per year. The concentrations of CO and CO 2 in the emissions from the combustion of filter cakes have been measured directly for the first time. They are the biggest volume of coal processing wastes. There have been many discussions about using these wastes as primary or secondary components of coal-water slurries (CWS) and coal-water slurries containing petrochemicals (CWSP). Boilers have already been operationally tested in Russia for the combustion of CWSP based on filter cakes. In this work, the concentrations of hazardous emissions have been measured at temperatures ranging from 500 to 1000°С. The produced CO and CO 2 concentrations are shown to be practically constant at high temperatures (over 900°С) for all the coal processing wastes under study. Experiments have shown the feasibility to lowering the combustion temperatures of coal processing wastes down to 750-850°С. This provides sustainable combustion and reduces the CO and CO 2 emissions 1.2-1.7 times. These relatively low temperatures ensure satisfactory environmental and energy performance of combustion. Using CWS and CWSP instead of conventional solid fuels significantly reduces NO x and SO x emissions but leaves CO and CO 2 emissions practically at the same level as coal powder combustion. Therefore, the environmentally friendly future (in terms of all the main atmospheric emissions: CO, CO 2 , NO x , and SO x ) of both CWS and CWSP technologies relies on low-temperature combustion. Copyright © 2017 Elsevier Ltd. All rights reserved.

ECONOMIC AND LEGAL ASPECTS OF MANAGEMENT OF WASTES AND SECONDARY MATERIAL RESOURCES (ON THE EXAMPLE OF CONSTRUCTION COMPLEX

Directory of Open Access Journals (Sweden)

Tskhovrebov Eduard Stanislavovich

2018-05-01

Full Text Available Subject: technical and economic processes and aspects of handling wastes and secondary material resources; stages of transition of anthropogenic object of environment to wastes and secondary material resources; technical possibility and economic feasibility of using secondary material resources as a secondary raw material for making products, providing energy, works, services. The problem of economy and rational use of material and power resources is relevant and significant within the limits of maintenance of a strategic course of Russia on innovative sustainable development. In this article, issues of actualization and harmonization of the regulatory and legal base in the field of management of wastes and secondary material resources are considered from the viewpoint of maintenance of minimization of waste formation and maximum use of secondary material resources in an industrial-economic cycle, provision of economic incentives for innovative activity in the given field. The actual multi-plan problem, chosen here as a topic of research, concerns regulations in management of wastes and secondary material resources in construction complex, in which economic, civil-law, ecological, social, industrial and legal relations are closely coordinated and define a subject of the present research. Production and consumption waste is a dangerous anthropogenic object of the environment but at the same time, it is a valuable secondary material resource. The non-use of wastes to be recycled as secondary raw materials for energy generation, production and, as a result, their increasing accumulation in the environment causes irreparable harm to natural objects and human health due to their dangerous properties. Research objectives: scientific and methodological substantiation of legal regulation, economic basis for formation of wastes and secondary material resources management system (on the example of construction complex and building materials industry

Bioremediation of Petrochemical Wastewater Containing BTEX Compounds by a New Immobilized Bacterium Comamonas sp. JB in Magnetic Gellan Gum.

Science.gov (United States)

Jiang, Bei; Zhou, Zunchun; Dong, Ying; Wang, Bai; Jiang, Jingwei; Guan, Xiaoyan; Gao, Shan; Yang, Aifu; Chen, Zhong; Sun, Hongjuan

2015-05-01

In this study, we investigated the bioremediation of petrochemical wastewater containing BTEX compounds by immobilized Comamonas sp. JB cells. Three kinds of magnetic nanoparticles were evaluated as immobilization supports for strain JB. After comparison with Fe3O4 and a-Fe2O3 nanoparticles, r-Fe2O3 nanoparticle was selected as the optimal immobilization support. The highest biodegradation activity of r-Fe2O3-magnetically immobilized cells was obtained when the concentration of r-Fe2O3 nanoparticle was 120 mg L(-1). Additionally, the recycling experiments demonstrated that the degradation activity of r-Fe2O3-magnetically immobilized cells was still high and led to less toxicity than untreated wastewater during the eight recycles. qPCR suggested the concentration of strain JB in r-Fe2O3-magnetically immobilized cells was evidently increased after eight cycles of degradation experiments. These results supported developing efficient biocatalysts using r-Fe2O3-magnetically immobilized cells and provided a promising technique for improving biocatalysts used in the bioremediation of not only petrochemical wastewater but also other hazardous wastewater.

Iron piano-stool complexes containing NHC ligands outfitted with pendent arms: synthesis, characterization, and screening for catalytic transfer hydrogenation

Science.gov (United States)

Parthapratim Das; Thomas Elder; William W. Brennessel; Stephen C. Chmely

2016-01-01

Catalysis is a fundamental technology that is widely used in the food, petrochemical, pharmaceutical, and agricultural sectors to produce chemical products on an industrial scale. Well-defined molecular organometallic species are a cornerstone of catalytic methodology, and the activity and selectivity of these complexes can be modulated by judicious choice of metal and...

Study of the leaching of heavy metals from waste water sludge and incinerator's ash, using coupled thermostated columns and DTPA as complex agent

International Nuclear Information System (INIS)

Vite T, J.; Vite T, M.; Guerrero D, J.; Carreno de Leon, M.C.

2000-01-01

We studied the metallic composition from waste water sludge and incinerators ashes of an incinerator located in Toluca, Mexico, the qualitative studies were made using the Activation Analysis technique, and fluorescence X-ray techniques. The quantitative analysis of heavy metals in the wastes were made using Inductively coupled plasma atomic emission spectrometry (Icp-Aes). For leaching the samples, we used four coupled thermostated columns, each one had a p H of 2,5, 7 and 10. The flux of the air was of 1600 cc/min. The temperature was maintain constant in 60 Centigrade using a thermostated system. For this study we used 100 g of wastes mixed with mineral acid or sodium hydroxide to reach p H 2,5,7 and 10. We added a reducing and tensoactive agents and finally DTPA as complex agent. With this method, we obtain a better leaching efficiency using a complex agent. However the high DTPA cost, make this process expansive that is why we recommend to work with another classes of complex agents, that be cheaper to leach metals of different chemistry matrix. (Author)

Effect of organic complexants on the mobility of low-level waste radionuclides in soils: status report

International Nuclear Information System (INIS)

Swanson, J.L.

1981-09-01

The effects of some organic complexants on the sorption by soil of some elements typical of those present in low-level wastes are being evaluated and procedures are being developed to efficiently obtain valid sorption data. Data have been obtained with Hanford soil and the elements europium, nickel, cobalt, cesium, and strontium. Complexants studied to date include ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), and humic acid. The sorption of cesium and strontium has been found to be affected very little by EDTA or DTPA, as expected. However, these complexants have been found to greatly reduce the sorption of europium, nickel, or cobalt by the soil. The Eu/EDTA system was found to be well behaved, and the effect of the complexant on the sorption by soil was quantified. With nickel and cobalt, however, kinetic problems have been encountered, and the effects of complexants on the sorption by soil have not yet been quantified. The problems encountered in the nickel and cobalt systems have further emphasized the need for the development of methods to assure the general validity of the data obtained in the experiments. Series of experimental results that looked very good within themselves were found by additional procedures to be artifacts of the conditions used. One procedure that has been of great value in identifying invalid data is that of contacting the equilibrated solution from a soil contact with a second batch of soil. Unless the sorption coefficient in the second contact is equivalent to that in the first contact, the data are likely invalid. Efforts are continuing to develop procedures that will allow generally valid data to be obtained in an efficient manner and to employ such procedures to obtain data in a variety of systems pertinent to low-level waste disposal

2011 Annual Industrial Wastewater Reuse Report for the Idaho National Laboratory Site's Advanced Test Reactor Complex Cold Waste Pond

International Nuclear Information System (INIS)

Lewis, Mike

2012-01-01

This report describes conditions, as required by the state of Idaho Industrial Wastewater Reuse Permit (LA 000161 01, Modification B), for the wastewater land application site at the Idaho National Laboratory Site's Advanced Test Reactor Complex Cold Waste Pond from November 1, 2010 through October 31, 2011. The report contains the following information: Facility and system description Permit required effluent monitoring data and loading rates Groundwater monitoring data Status of compliance activities Noncompliance and other issues Discussion of the facility's environmental impacts During the 2011 permit year, approximately 166 million gallons of wastewater were discharged to the Cold Waste Pond. This is well below the maximum annual permit limit of 375 million gallons. As shown by the groundwater sampling data, sulfate and total dissolved solids concentrations are highest near the Cold Waste Pond and decrease rapidly as the distance from the Cold Waste Pond increases. Although concentrations of sulfate and total dissolved solids are elevated near the Cold Waste Pond, both parameters were below the Ground Water Quality Rule Secondary Constituent Standards in the down gradient monitoring wells.

Buried Waste Integrated Demonstration

International Nuclear Information System (INIS)

1994-03-01

The Buried Waste Integrated Demonstration (BWID) supports the applied research, development, demonstration, and evaluation of a suite of advanced technologies that offer promising solutions to the problems associated with the remediation of buried waste. BWID addresses the difficult remediation problems associated with DOE complex-wide buried waste, particularly transuranic (TRU) contaminated buried waste. BWID has implemented a systems approach to the development and demonstration of technologies that will characterize, retrieve, treat, and dispose of DOE buried wastes. This approach encompasses the entire remediation process from characterization to post-monitoring. The development and demonstration of the technology is predicated on how a technology fits into the total remediation process. To address all of these technological issues, BWID has enlisted scientific expertise of individuals and groups from within the DOE Complex, as well as experts from universities and private industry. The BWID mission is to support development and demonstration of a suite of technologies that, when integrated with commercially-available technologies, forms a comprehensive, remediation system for the effective and efficient remediation of buried waste throughout the DOE Complex. BWID will evaluate and validate demonstrated technologies and transfer this information and equipment to private industry to support the Office of Environmental Restoration (ER), Office of Waste Management (WM), and Office of Facility Transition (FT) remediation planning and implementation activities

Haldia complex in doubt as Tata pulls out

International Nuclear Information System (INIS)

Alperowicz, N.

1993-01-01

The Tata Tea group (Calcutta) intends to pull out of Haldia Petrochemicals, casting a shadow on India's second major petrochemical project. Late last year Shell withdrew from National Organic Chemical Industries (Nocil; Bombay), throwing Nocil's plans into disarray. Tata - copromoting Halida with the West Bengal government - cites escalating costs as the main reason for its decision. The Haldia project was revised in 1990 to have annual capacities for 300,000 m.t. of ethylene, 100,000 m.t. of high-density polyethylene (HDPE), 160,000 m.t. of linear low-density polyethylene, and 150,000 m.t. of polypropylene (PP). The cost was frozen at Rs30 billion, but the exchange rate shifted and the petrochemical markets suffered a downturn. Lummus Crest has been shortlisted to supply the ethylene plant, with Mitsui for HDPE and Himont for PP

Effects of probiotics on biomarkers of oxidative stress and inflammatory factors in petrochemical workers: A randomized, double-blind, placebo-controlled trial

Directory of Open Access Journals (Sweden)

Ali Akbar Mohammadi

2015-01-01

Full Text Available Background: The aim of the current study was to determine effects of probiotic yoghurt and multispecies probiotic capsule supplementation on biomarkers of oxidative stress and inflammatory factors in petrochemical workers. Methods: This randomized, double-blind, placebo-controlled trial was done among petrochemical workers. Subjects were randomly divided into three groups to receive 100 g/day probiotic yogurt (n = 12 or one probiotic capsule daily (n = 13 or 100 g/day conventional yogurt (n = 10 for 6 weeks. The probiotic yoghurt was containing two strains of Lactobacillus acidophilus and Bifidobacterium lactis with a total of min 1 Χ 10 7 CFU. Multispecies probiotic capsule contains seven probiotic bacteria spices Actobacillus casei 3 Χ 10 3 , L. acidophilus 3 Χ 10 7 , Lactobacillus rhamnosus 7 Χ 10 9 , Lactobacillus bulgaricus 5 Χ 10 8 , Bifidobacterium breve 2 Χ 10 10 , Bifidobacterium longum 1 Χ 10 9 and Streptococcus thermophilus 3 Χ 10 8 CFU/g. Fasting blood samples were obtained at the beginning and end of the trial to quantify biomarkers of oxidative stress and inflammatory factors. Results: Although a significant within-group decrease in plasma protein carbonyl levels was seen in the probiotic capsule group (326.0 ± 308.9 vs. 251.0 ± 176.3 ng/mL, P = 0.02, the changes were similar among the three groups. In addition, significant within-group decreases in plasma iso prostaglandin were observed in the probiotic supplements group (111.9 ± 85.4 vs. 88.0 ± 71.0 pg/mL, P = 0.003 and in the probiotic yogurt group (116.3 ± 93.0 vs. 92.0 ± 66.0 pg/mL, P = 0.02, nevertheless there were no significant change among the three groups. Conclusions: Taken together, consumption of probiotic yogurt or multispecies probiotic capsule had beneficial effects on biomarkers of oxidative stress in petrochemical workers.

The petrochemical industry versus the transformers. Allays or enemies?; A industria petroquimica versus transformadores. Aliados ou inimigos?

Energy Technology Data Exchange (ETDEWEB)

Eigner, Gabriel [Girassol Industria e Comercio de Plasticos Ltda., Sao Paulo, SP (Brazil)

1993-12-31

The existing different realities between the two companies environment focused, on one side the big petrochemical plants and on the other side, the transformer ones, most of them small and middle companies produces unlike views in terms of the management of these companies. The present economical conjuncture requires an urgent alteration of this procedure, in order to favour improvements in rentability and competitivity in both segments, as well as to provide a more adjusted basis of business expansion and development. (author)

The petrochemical industry versus the transformers. Allays or enemies?; A industria petroquimica versus transformadores. Aliados ou inimigos?

Energy Technology Data Exchange (ETDEWEB)

Eigner, Gabriel [Girassol Industria e Comercio de Plasticos Ltda., Sao Paulo, SP (Brazil)

1992-12-31

The existing different realities between the two companies environment focused, on one side the big petrochemical plants and on the other side, the transformer ones, most of them small and middle companies produces unlike views in terms of the management of these companies. The present economical conjuncture requires an urgent alteration of this procedure, in order to favour improvements in rentability and competitivity in both segments, as well as to provide a more adjusted basis of business expansion and development. (author)

Annual report of waste generation and pollution prevention progress 1997

International Nuclear Information System (INIS)

1998-09-01

This sixth Annual Report presents and analyzes DOE Complex-wide waste generation and pollution prevention activities at 36 reporting sites from 1993 through 1997. In May 1996, the Secretary of Energy established a 50 percent Complex-Wide Waste Reduction Goal (relative to the 1993 baseline) for routine operations radioactive and hazardous waste generation, to be achieved by December 31, 1999. Excluding sanitary waste, routine operations waste generation increased three percent from 1996 to 1997, and decreased 61 percent overall from 1993 to 1997. DOE has achieved its Complex-Wide Waste Reduction Goals for routine operations based upon a comparison of 1997 waste generation to the 1993 baseline. However, it is important to note that increases in low-level radioactive and low-level mixed waste generation could reverse this achievement. From 1996 to 1997, low-level radioactive waste generation increased 10 percent, and low-level mixed waste generation increased slightly. It is critical that DOE sites continue to reduce routine operations waste generation for all waste types, to ensure that DOE's Complex-Wide Waste Reduction Goals are achieved by December 31, 1999

High exhaust chrome complex using chrome tanned tannery, solid wastes and common hydrocarbons as reductants and masking agents to minimize the liquid and solid wastes: tanning and environmental impact studies

International Nuclear Information System (INIS)

Nawaz, H.R.

2005-01-01

Still no alternate of chrome tanning has been found to achieve the best quality and quantity of leather. But the chrome tanning process is associated with the generation of very toxic liquid and solid wastes. Therefore we emphasized to develop an efficient process for the synthesis of high exhaust chrome complex that could minimize the both liquid and solid wastes up to very low limit. In this research, chrome shavings and raw organic compounds have beneficially utilized as a reductant as well as potential masking agents providing a comprehensive close loop. Two chrome tanning materials have been developed using leather shavings with molasses in product A and replacement of molasses by other organic compounds for chrome complex B. These materials have also been employed for the tanning of goatskins parallel to the commercial BCS from the market. The comparative studies revealed that, the quality of leather made from product B is either better or comparable with the conventional tanning material. The chrome contents in leather have been increased with the simultaneous decreased in spent chrome liquor. Hence the exhaustion rate of chrome complex B has been noted up to 95%. While the physical characteristics of resulted leather from product A and B have been found comparable to that of conventional tanned leather. Therefore this methodology would not only reduce liquid and solid wastes but also provide quality leather and economically multi benefits. (author)

Calculation of projected waste loads for transuranic waste management alternatives

International Nuclear Information System (INIS)

Hong, K.; Kotek, T.; Koebnick, B.; Wang, Y.; Kaicher, C.

1995-01-01

The level of treatment and the treatment and interim storage site configurations (decentralized, regional, or centralized) impact transuranic (TRU) waste loads at and en route to sites in the US Department of Energy (DOE) complex. Other elements that impact waste loads are the volume and characteristics of the waste and the unit operation parameters of the technologies used to treat it. Projected annual complexwide TRU waste loads under various TRU waste management alternatives were calculated using the WASTEunderscoreMGMT computational model. WASTEunderscoreMGMT accepts as input three types of data: (1) the waste stream inventory volume, mass, and contaminant characteristics by generating site and waste stream category; (2) unit operation parameters of treatment technologies; and (3) waste management alternative definitions. Results indicate that the designed capacity of the Waste Isolation Pilot Plant, identified under all waste management alternatives as the permanent disposal facility for DOE-generated TRU waste, is sufficient for the projected complexwide TRU waste load under any of the alternatives

Characterisation of metals in the electronic waste of complex mixtures of end-of-life ICT products for development of cleaner recovery technology.

Science.gov (United States)

Sun, Z H I; Xiao, Y; Sietsma, J; Agterhuis, H; Visser, G; Yang, Y

2015-01-01

Recycling of valuable metals from electronic waste, especially complex mixtures of end-of-life information and communication technology (ICT) products, is of great difficulty due to their complexity and heterogeneity. One of the important reasons is the lack of comprehensive characterisation on such materials, i.e. accurate compositions, physical/chemical properties. In the present research, we focus on developing methodologies for the characterisation of metals in an industrially processed ICT waste. The morphology, particle size distribution, compositional distribution, occurrence, liberation as well as the thermo-chemical properties of the ICT waste were investigated with various characterisation techniques, including X-ray Fluorescence Spectrometry (XRF), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) with energy dispersed spectroscopy (EDS). Due to the high heterogeneity of the material, special sample preparation procedures were introduced to minimise the discrepancies during compositional analyses. As a result, a clearer overview of the ICT waste has been reached. This research provides better understanding of the extractability of each metal and improves the awareness of potential obstacles for extraction. It will lead to smarter decisions during further development of a clean and effective recovery process. Copyright © 2014 Elsevier Ltd. All rights reserved.

Detection and reduction of diffuse liquid and gas emissions in chemical and petrochemical industries; Ermittlung und Verminderung diffuser fluessiger und gasfoermiger Emissionen in der chemischen und petrochemischen Industrie

Energy Technology Data Exchange (ETDEWEB)

Koeppke, K.E. [Witten-Herdecke Univ. gGmbH, Witten (Germany). Inst. fuer Umwelttechnik und Management; Cuhls, C. [Halle-Wittenberg Univ., Halle (Germany). Inst. fuer Umwelttechnik

2002-09-01

In order to improve environmental protection, VOC emissions from diffuse sources are of growing importance. For the first time in Germany the present research report gives a detailed presentation of: constructive measures for the avoidance and reduction of diffuse emissions, adequate assembling procedures for equipments and installations, technical possibilities of leak detection and, different methods for the estimation of total emissions from chemical and petrochemical production plants. On the basis of own investigations and monitoring measures taken at various plants of chemical and petrochemical industries different measuring techniques for leak detection as well as methods for the estimation of total emissions from diffuse sources are analysed and their limits are described. (orig.)

TSA waste stream and final waste form composition

International Nuclear Information System (INIS)

Grandy, J.D.; Eddy, T.L.; Anderson, G.L.

1993-01-01

A final vitrified waste form composition, based upon the chemical compositions of the input waste streams, is recommended for the transuranic-contaminated waste stored at the Transuranic Storage Area of the Radioactive Waste Management Complex at the Idaho National Engineering Laboratory. The quantities of waste are large with a considerable uncertainty in the distribution of various waste materials. It is therefore impractical to mix the input waste streams into an ''average'' transuranic-contaminated waste. As a result, waste stream input to a melter could vary widely in composition, with the potential of affecting the composition and properties of the final waste form. This work examines the extent of the variation in the input waste streams, as well as the final waste form under conditions of adding different amounts of soil. Five prominent Rocky Flats Plant 740 waste streams are considered, as well as nonspecial metals and the ''average'' transuranic-contaminated waste streams. The metals waste stream is the most extreme variation and results indicate that if an average of approximately 60 wt% of the mixture is soil, the final waste form will be predominantly silica, alumina, alkaline earth oxides, and iron oxide. This composition will have consistent properties in the final waste form, including high leach resistance, irrespective of the variation in waste stream. For other waste streams, much less or no soil could be required to yield a leach resistant waste form but with varying properties

Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP)

International Nuclear Information System (INIS)

Achilias, D.S.; Roupakias, C.; Megalokonomos, P.; Lappas, A.A.; Antonakou, E.V.

2007-01-01

The recycling of either model polymers or waste products based on low-density polyethylene (LDPE), high-density polyethylene (HDPE) or polypropylene (PP) is examined using the dissolution/reprecipitation method, as well as pyrolysis. In the first technique, different solvents/non-solvents were examined at different weight percent amounts and temperatures using as raw material both model polymers and commercial products (packaging film, bags, pipes, food-retail outlets). The recovery of polymer in every case was greater than 90%. FT-IR spectra and tensile mechanical properties of the samples before and after recycling were measured. Furthermore, catalytic pyrolysis was carried out in a laboratory fixed bed reactor with an FCC catalyst using again model polymers and waste products as raw materials. Analysis of the derived gases and oils showed that pyrolysis gave a mainly aliphatic composition consisting of a series of hydrocarbons (alkanes and alkenes), with a great potential to be recycled back into the petrochemical industry as a feedstock for the production of new plastics or refined fuels

Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP).

Science.gov (United States)

Achilias, D S; Roupakias, C; Megalokonomos, P; Lappas, A A; Antonakou, Epsilon V

2007-11-19

The recycling of either model polymers or waste products based on low-density polyethylene (LDPE), high-density polyethylene (HDPE) or polypropylene (PP) is examined using the dissolution/reprecipitation method, as well as pyrolysis. In the first technique, different solvents/non-solvents were examined at different weight percent amounts and temperatures using as raw material both model polymers and commercial products (packaging film, bags, pipes, food-retail outlets). The recovery of polymer in every case was greater than 90%. FT-IR spectra and tensile mechanical properties of the samples before and after recycling were measured. Furthermore, catalytic pyrolysis was carried out in a laboratory fixed bed reactor with an FCC catalyst using again model polymers and waste products as raw materials. Analysis of the derived gases and oils showed that pyrolysis gave a mainly aliphatic composition consisting of a series of hydrocarbons (alkanes and alkenes), with a great potential to be recycled back into the petrochemical industry as a feedstock for the production of new plastics or refined fuels.

The Cenelec EEx'e' concept in oil and petrochemical engineering

International Nuclear Information System (INIS)

Bennett, P.A.

1993-01-01

Although a long established practice throughout Europe initially covered by the individual standards of what is now the European community and now harmonized under Cenelec (Comite Europeen de Normalisation Electrotechnique) under standards EN 50-014-039 the EEx'e' concept for hazardous atmospheres is little known, little understood and, because of differing standards, little used on the North American Continent. This is a pity because the application of the concept can make the engineering design of an oil or petrochemical plant, oil-rig etc. simpler and more cost-effective in that zone classification can be significantly less onerous, cheaper and virtually maintenance free apparatus can be used. This means, particularly on offshore oil and gas platforms that substantial savings in cost can be effected by means of the possible top-side weight reduction achieved by its use. These factors which are to the benefit of all should no longer be ignored by the major oil producing companies and the many competent engineers, consultants and contractors who serve them. References, figures, and bibliography appear at the end of the paper

Health Risk Assessment of Xylene through Microenvironment Monitoring Data: A Case Study of the Petro-Chemical Industries, Thailand

Directory of Open Access Journals (Sweden)

Pensri Watchalayann

2009-01-01

Full Text Available In the absence of environmental health epidemiology, risk managers, policy makers and health-care authorities usually rely on estimates of human exposure level of proximity to hazardous waste site or regional ambient air quality data. Based on ambient concentrations without considering time-activity patterns, the estimation of personal exposure may be overor underestimated. Twelve villages surrounding the petro-chemical industries located in the eastern region of Thailand were randomly selected to be a representative study area. In each village, air samples were collected at thirty-one microenvironments including indoor and outdoor of a household and workplace. The time-activity patterns of the commuters were also recorded. The ambient xylene concentrations were determined by thermal desorption gas chromatograhy/mass spectrometry. The indoor samples were determined by gas chromatography flame ionization detector. Commuters living in the vicinity of the industrial areas spent most of the time indoor (93.2%, especially at home (66.8%. Individuals spent a significant fraction of the day indoors. The concentrations of xylene ranged from less than 1 μg/m3 to 291.3 μg/m3. The highest level was found at the auto repair shop (291.3 μg/m3. Given micro-environmental concentrations and activity times, the average concentrations of xylene to which commuters may be exposed daily ranged from 90.62 to 134.75 μg/m3. The long term exposure level via inhalation was found to be very low. Collectively, no hazard was indicated by the hazard quotient and the results were found to be similar in all villages.

Feasibility study on the utilization of high sulfur pet. coke as a by-product at SINOPEC Fujian Petrochemical Company Limited

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-03-01

For the purpose of conserving energy and reducing greenhouse effect gas emission, an investigational study was conducted for the project on the effective utilization of high-sulfur petroleum coke at Fujian Petrochemical Co., Fujian Province, China. In the project, IGCC (integrated gasification combined cycle) power generation facilities are introduced to the refinery of Fujian Petrochemical Co. By gasifying the residues produced from the refinery as raw material, the gas clean the same as natural gas is produced and is used as power generation use fuel. As a result of the study, the energy conservation amount was 94,300 toe/y, and was 1,414,500 toe in cumulative amount during 15 years. Further, the amount of greenhouse effect gas reduction was 291,600 t-CO2/y, and was 4,374,000 t-CO2 in cumulative amount during 15 years. The construction cost of the project is approximately 29.7 billion yen. The annual profit to be obtained from the project is approximately 8.66 billion yen, which is indicated by difference between before and after the implementation of the project. The calculated years required for return of investment were 3.4. (NEDO)

An analysis of the inter-project knowledge transfer in the petrochemical industry

Directory of Open Access Journals (Sweden)

Marcelo Müller Beuren

2015-02-01

Full Text Available This paper presents a knowledge transfer (KT analysis in an operational project management environment of the petrochemical industry. The main objective of this paper is to identify the major barriers and to suggest improvements activities aiming to foster the KT process. To this end, interviews with members of the project department were conducted by means of a questionnaire. Results were analyzed to identify the most problematic barriers and to propose improvements. The study concluded that the greatest difficulties are related to the transfer of tacit knowledge between different teams. The main contribution of this paper is that it presents an analysis of an unexplored environment and it proposes an improvement of the adapted method for KT study, by using a relationship matrix between the questionnaire and the barriers, so that problems can be identified in an easier manner.

Denitration of Savannah River Plant waste streams

International Nuclear Information System (INIS)

Orebaugh, E.G.

1976-07-01

Partial denitration of waste streams from Savannah River Plant separations processes was shown to significantly reduce the quantity of waste solids to be stored as an alkaline salt cake. The chemical processes involved in the denitration of nonradioactive simulated waste solutions were studied. Chemical and instrumental analytical techniques were used to define both the equilibrium concentrations and the variation of reactants and products in the denitration reaction. Mechanisms were proposed that account for the complicated chemical reactions observed in the simulated waste solutions. Metal nitrates can be denitrated by reaction with formic acid only by the release of nitric acid from hydrolysis or formate complexation of metal cations. However, eventual radiolysis of formate salts or complexes results in the formation of biocarbonate and makes complexation-denitration a nonproductive means of reducing waste solids. Nevertheless, destruction of nitrate associated with free acid and easily hydrolyzable cations such as iron, mercury, and zirconium can result in greater than 30 percent reduction in waste solids from five SRP waste streams

Reduction of energy cost and CO2 emission for the furnace using energy recovered from waste tail-gas

International Nuclear Information System (INIS)

Jou, Chih-Ju G.; Wu, Chung-Rung; Lee, Chien-Li

2010-01-01

In this research, the waste tail gas emitted from petrochemical processes, e.g. catalytic reforming unit, catalytic cracking unit and residue desulfurization unit, was recovered and reused as a replacement of natural gas (NG). On-site experimental results show that both the flame length and orange-yellowish brightness decrease with more proportion of waste gas fuel added to the natural gas, and that the adiabatic temperature of the mixed fuel is greater than 1800 o C. A complete replacement of natural gas by the recovered waste gas fuel will save 5.8 x 10 6 m 3 of natural gas consumption, and 3.5 x 10 4 tons of CO 2 emission annually. In addition, the reduction of residual O 2 concentration in flue gases from 4% to 3% will save 1.1 x 10 6 m 3 of natural gas consumption, reduce 43.0% of NO x emission, and 1.3 x 10 3 tons of CO 2 emission annually. Thus, from the viewpoint of the overall economics and sustainable energy policy, recovering the waste tail gas energy as an independent fuel source to replace natural gas is of great importance for saving energy, reducing CO 2 emission reduction, and lowering environmental impact.

Regulatory controls on the hydrogeological characterization of a mixed waste disposal site, Radioactive Waste Management Complex, Idaho National Engineering Laboratory

International Nuclear Information System (INIS)

Ruebelmann, K.L.

1990-01-01

Following the detection of chlorinated volatile organic compounds in the groundwater beneath the SDA in the summer of 1987, hydrogeological characterization of the Radioactive Waste Management Complex (RWMC), Idaho National Engineering Laboratory (INEL) was required by the Resource Conservation and Recovery Act (RCRA). The waste site, the Subsurface Disposal Area (SDA), is the subject of a RCRA Corrective Action Program. Regulatory requirements for the Corrective Action Program dictate a phased approach to evaluation of the SDA. In the first phase of the program, the SDA is the subject of a RCRA Facility Investigation (RIF), which will obtain information to fully characterize the physical properties of the site, determine the nature and extent of contamination, and identify pathways for migration of contaminants. If the need for corrective measures is identified during the RIF, a Corrective Measures Study (CMS) will be performed as second phase. Information generated during the RIF will be used to aid in the selection and implementation of appropriate corrective measures to correct the release. Following the CMS, the final phase is the implementation of the selected corrective measures. 4 refs., 1 fig

Efficiency Evaluation of Food Waste Materials for the Removal of Metals and Metalloids from Complex Multi-Element Solutions

Science.gov (United States)

Giuliano, Antonella; Astolfi, Maria Luisa; Congedo, Rossana; Masotti, Andrea; Canepari, Silvia

2018-01-01

Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents’ efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements’ removal efficiency which resulted to be in correlation with the specific adsorbents’ chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements. PMID:29495363

Efficiency Evaluation of Food Waste Materials for the Removal of Metals and Metalloids from Complex Multi-Element Solutions.

Science.gov (United States)

Massimi, Lorenzo; Giuliano, Antonella; Astolfi, Maria Luisa; Congedo, Rossana; Masotti, Andrea; Canepari, Silvia

2018-02-26

Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents' efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements' removal efficiency which resulted to be in correlation with the specific adsorbents' chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements.

Efficiency Evaluation of Food Waste Materials for the Removal of Metals and Metalloids from Complex Multi-Element Solutions

Directory of Open Access Journals (Sweden)

Lorenzo Massimi

2018-02-01

Full Text Available Recent studies have shown the potential of food waste materials as low cost adsorbents for the removal of heavy metals and toxic elements from wastewater. However, the adsorption experiments have been performed in heterogeneous conditions, consequently it is difficult to compare the efficiency of the individual adsorbents. In this study, the adsorption capacities of 12 food waste materials were evaluated by comparing the adsorbents’ efficiency for the removal of 23 elements from complex multi-element solutions, maintaining homogeneous experimental conditions. The examined materials resulted to be extremely efficient for the adsorption of many elements from synthetic multi-element solutions as well as from a heavy metal wastewater. The 12 adsorbent surfaces were analyzed by Fourier transform infrared spectroscopy and showed different types and amounts of functional groups, which demonstrated to act as adsorption active sites for various elements. By multivariate statistical computations of the obtained data, the 12 food waste materials were grouped in five clusters characterized by different elements’ removal efficiency which resulted to be in correlation with the specific adsorbents’ chemical structures. Banana peel, watermelon peel and grape waste resulted the least selective and the most efficient food waste materials for the removal of most of the elements.

Evaluation of co-pyrolysis petrochemical wastewater sludge with lignite in a thermogravimetric analyzer and a packed-bed reactor: Pyrolysis characteristics, kinetics, and products analysis.

Science.gov (United States)

Mu, Lin; Chen, Jianbiao; Yao, Pikai; Zhou, Dapeng; Zhao, Liang; Yin, Hongchao

2016-12-01

Co-pyrolysis characteristics of petrochemical wastewater sludge and Huolinhe lignite were investigated using thermogravimetric analyzer and packed-bed reactor coupled with Fourier transform infrared spectrometer and gas chromatography. The pyrolysis characteristics of the blends at various sludge blending ratios were compared with those of the individual materials. Thermogravimetric experiments showed that the interactions between the blends were beneficial to generate more residues. In packed-bed reactor, synergetic effects promoted the release of gas products and left less liquid and solid products than those calculated by additive manner. Fourier transform infrared spectrometer analysis showed that main functional groups in chars gradually disappeared with pyrolysis temperatures increasing, and H 2 O, CH 4 , CO, and CO 2 appeared in volatiles during pyrolysis. Gas compositions analysis indicated that, the yields of H 2 and CO clearly increased as the pyrolysis temperature and sludge blending ratio increasing, while the changes of CH 4 and CO 2 yields were relatively complex. Copyright © 2016 Elsevier Ltd. All rights reserved.

Prevalence of musculoskeletal symptoms among employees of Iranian petrochemical industries: October 2009 to December 2012.

Science.gov (United States)

Choobineh, A R; Daneshmandi, H; Aghabeigi, M; Haghayegh, A

2013-10-01

Work-related musculoskeletal disorders (WMSDs) are a common health problem throughout the world and a major cause of disability in the workplace. To determine the prevalence rate of MSDs, assessment of ergonomics working conditions and identification of major risk factors associated with MSDs symptoms among employees of Iranian petrochemical industries between October 2009 and December 2012. In this study, we studied 1184 randomly selected employees of 4 Iranian petrochemical companies with at least one year of work experience in office or operational units. For those with office jobs, data were collected using Nordic Musculoskeletal disorders Questionnaire (NMQ) and ergonomics checklist for the assessment of working conditions. For those with operational jobs, NMQ and Quick Exposure Check (QEC) method were used for data collection. The most prevalent MSD symptoms were reported in lower back (41.5%) and neck (36.5%). The prevalence of MSDs in all body regions but elbows and thighs of the office staff was significantly higher than that of operational workers. Assessment of working conditions in office staff revealed that the lowest index was attributed to workstation. QEC technique among operational workers showed that in 73.8% of the workers studied, the level of exposure to musculoskeletal risks was "high" or "very high." MSDs were associated with type of job, age, body mass index, work experience, gender, marital status, educational level and type of employment. The prevalence of MSDs in the office staff was higher than that of operational workers. Level of exposure to MSDs risk was high in operational workers. Corrective measures are thus necessary for improving working conditions for both office and operational units.

Prevalence of Musculoskeletal Symptoms among Employees of Iranian Petrochemical Industries: October 2009 to December 2012

Directory of Open Access Journals (Sweden)

AR Choobineh

2013-10-01

Full Text Available Background: Work-related musculoskeletal disorders (WMSDs are a common health problem throughout the world and a major cause of disability in the workplace. Objective: To determine the prevalence rate of MSDs, assessment of ergonomics working conditions and identification of major risk factors associated with MSDs symptoms among employees of Iranian petrochemical industries between October 2009 and December 2012. Methods: In this study, we studied 1184 randomly selected employees of 4 Iranian petrochemical companies with at least one year of work experience in office or operational units. For those with office jobs, data were collected using Nordic Musculoskeletal disorders Questionnaire (NMQ and ergonomics checklist for the assessment of working conditions. For those with operational jobs, NMQ and Quick Exposure Check (QEC method were used for data collection. Results: The most prevalent MSD symptoms were reported in lower back (41.5% and neck (36.5%. The prevalence of MSDs in all body regions but elbows and thighs of the office staff was significantly higher than that of operational workers. Assessment of working conditions in office staff revealed that the lowest index was attributed to workstation. QEC technique among operational workers showed that in 73.8% of the workers studied, the level of exposure to musculoskeletal risks was “high” or “very high.” MSDs were associated with type of job, age, body mass index, work experience, gender, marital status, educational level and type of employment. Conclusion: The prevalence of MSDs in the office staff was higher than that of operational workers. Level of exposure to MSDs risk was high in operational workers. Corrective measures are thus necessary for improving working conditions for both office and operational units.

Annual report of waste generation and pollution prevention progress 1998

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-09-01

This seventh Annual Report presents and analyzes DOE Complex-wide waste generation and pollution prevention activities at 45 reporting sites from 1993 through 1998. This section summarizes Calendar Year 1998 Complex-wide waste generation and pollution prevention accomplishments. More detailed information follows this section in the body of the Report. In May 1996, the Secretary of Energy established a 50 percent Complex-Wide Waste Reduction Goal (relative to the 1993 baseline) for routine operations radioactive, mixed, and hazardous waste generation, to be achieved by December31, 1999. DOE has achieved its Complex-Wide Waste Reduction Goals for routine operations based upon a comparison of 1998 waste generation to the 1993 baseline. Excluding sanitary waste, routine operations waste generation decreased 67 percent overall from 1993 to 1998. However, for the first time since 1994, the total amount of materials recycled by the Complex decreased from 109,600 metric tons in 1997 to 92,800 metric tons in 1998. This decrease is attributed to the fact that in 1997, several large ''one-time only'' recycling projects were conducted throughout the Complex. In order to demonstrate commitment to DOE's Complex-wide recycling goal, it is important for sites to identify all potential large-scale recycling/reuse opportunities.

The effects of probiotics on mental health and hypothalamic-pituitary-adrenal axis: A randomized, double-blind, placebo-controlled trial in petrochemical workers.

Science.gov (United States)

Mohammadi, Ali Akbar; Jazayeri, Shima; Khosravi-Darani, Kianoush; Solati, Zahra; Mohammadpour, Nakisa; Asemi, Zatollah; Adab, Zohre; Djalali, Mahmoud; Tehrani-Doost, Mehdi; Hosseini, Mostafa; Eghtesadi, Shahryar

2016-11-01

The aim of this study was to determine effects of probiotic yogurt and multispecies probiotic capsule supplementation on mental health and hypothalamic-pituitary-adrenal axis in petrochemical workers. The present randomized double-blind, placebo-controlled trial was conducted on 70 petrochemical workers. Subjects were randomly divided into three groups to receive 100 g/day probiotic yogurt + one placebo capsule (n = 25) or one probiotic capsule daily + 100 g/day conventional yogurt (n = 25) or 100 g/day conventional yogurt + one placebo capsule (n = 20) for 6 weeks. Mental health parameters including general health questionnaire (GHQ) and depression anxiety and stress scale (DASS) scores were measured. Fasting blood samples were obtained at the beginning and 6 weeks after the intervention to quantify hypothalamic-pituitary-adrenal axis. After 6 weeks of intervention, a significant improvement of GHQ was observed in the probiotic yogurt (18.0 ± 1.5 vs. 13.5 ± 1.9, P = 0.007) and in the probiotic capsule group (16.9 ± 1.8 vs. 9.8 ± 1.9, P = 0.001), as well as a significant improvement in DASS scores in the probiotic yogurt (23.3 ± 3.7 vs. 13.0 ± 3.7, P = 0.02) and the probiotic capsule group (18.9 ± 3.2 vs. 9.4 ± 4.0, P = 0.006). However, there was no significant improvement in the conventional yogurt group (P = 0.05 for GHQ and P = 0.08 for DASS). The consumption of probiotic yogurt or a multispecies probiotic capsule had beneficial effects on mental health parameters in petrochemical workers.

Implementation of Waste Minimization at a complex R ampersand D site

International Nuclear Information System (INIS)

Lang, R.E.; Thuot, J.R.; Devgun, J.S.

1995-01-01

Under the 1994 Waste Minimization/Pollution Prevention Crosscut Plan, the Department of Energy (DOE) has set a goal of 50% reduction in waste at its facilities by the end of 1999. Each DOE site is required to set site-specific goals to reduce generation of all types of waste including hazardous, radioactive, and mixed. To meet these goals, Argonne National Laboratory (ANL), Argonne, IL, has developed and implemented a comprehensive Pollution Prevention/Waste Minimization (PP/WMin) Program. The facilities and activities at the site vary from research into basic sciences and research into nuclear fuel cycle to high energy physics and decontamination and decommissioning projects. As a multidisciplinary R ampersand D facility and a multiactivity site, ANL generates waste streams that are varied, in physical form as well as in chemical constituents. This in turn presents a significant challenge to put a cohesive site-wide PP/WMin Program into action. In this paper, we will describe ANL's key activities and waste streams, the regulatory drivers for waste minimization, and the DOE goals in this area, and we will discuss ANL's strategy for waste minimization and it's implementation across the site

Processes for production of alternative waste forms

International Nuclear Information System (INIS)

Ross, W.A.; Rusin, J.M.; McElroy, J.L.

1979-01-01

During the past 20 years, numerous waste forms and processes have been proposed for solidification of high-level radioactive wastes (HLW). The number has increased significantly during the past 3 to 4 years. At least five factors must be considered in selecting the waste form and process method: 1) processing flexibility, 2) waste loading, 3) canister size and stability, 4) waste form inertness and stability, and 5) processing complexity. This paper describes various waste form processes and operations, and a simple system is proposed for making comparisons. This system suggests that one goal for processes would be to reduce the number of process steps, thereby providing less complex processing systems

Isolation and Screening of Polyhydroxyalkanoates Producing Bacteria from Pulp, Paper, and Cardboard Industry Wastes

Directory of Open Access Journals (Sweden)

Anish Kumari Bhuwal

2013-01-01

Full Text Available Background. Polyhydroxyalkanoates (PHAs are storage materials that accumulate by various bacteria as energy and carbon reserve materials. They are biodegradable, environmentally friendly, and also biocompatible bioplastics. Unlike petrochemical-based plastics that take several decades to fully degrade, PHAs can be completely degraded within a year by variety of microorganisms into CO2 and water. In the present study, we aim to utilize pulp, paper, and cardboard industry sludge and waste water for the isolation and screening of polyhydroxyalkanoates (PHAs accumulating bacteria and production of cost-effective PHB using cardboard industry waste water. Results. A total of 42 isolates showed black-blue coloration when stained with Sudan black B, a preliminary screening agent for lipophilic compounds, and a total of 15 isolates showed positive result with Nile blue A staining, a more specific dye for PHA granules. The isolates NAP11 and NAC1 showed maximum PHA production 79.27% and 77.63% with polymer concentration of 5.236 g/L and 4.042 g/L with cardboard industry waste water. Both of the selected isolates, NAP11 and NAC1, were classified up to genus level by studying their morphological and biochemical characteristics and were found to be Enterococcus sp., Brevundimonas sp. and, respectively. Conclusion. The isolates Enterococcus sp. NAP11 and Brevundimonas sp. NAC1 can be considered as good candidates for industrial production of PHB from cardboard industry waste water. We are reporting for the first time the use of cardboard industry waste water as a cultivation medium for the PHB production.

Isolation and Screening of Polyhydroxyalkanoates Producing Bacteria from Pulp, Paper, and Cardboard Industry Wastes

Science.gov (United States)

Bhuwal, Anish Kumari; Singh, Gulab; Aggarwal, Neeraj Kumar; Goyal, Varsha; Yadav, Anita

2013-01-01

Background. Polyhydroxyalkanoates (PHAs) are storage materials that accumulate by various bacteria as energy and carbon reserve materials. They are biodegradable, environmentally friendly, and also biocompatible bioplastics. Unlike petrochemical-based plastics that take several decades to fully degrade, PHAs can be completely degraded within a year by variety of microorganisms into CO2 and water. In the present study, we aim to utilize pulp, paper, and cardboard industry sludge and waste water for the isolation and screening of polyhydroxyalkanoates (PHAs) accumulating bacteria and production of cost-effective PHB using cardboard industry waste water. Results. A total of 42 isolates showed black-blue coloration when stained with Sudan black B, a preliminary screening agent for lipophilic compounds, and a total of 15 isolates showed positive result with Nile blue A staining, a more specific dye for PHA granules. The isolates NAP11 and NAC1 showed maximum PHA production 79.27% and 77.63% with polymer concentration of 5.236 g/L and 4.042 g/L with cardboard industry waste water. Both of the selected isolates, NAP11 and NAC1, were classified up to genus level by studying their morphological and biochemical characteristics and were found to be Enterococcus sp., Brevundimonas sp. and, respectively. Conclusion. The isolates Enterococcus sp. NAP11 and Brevundimonas sp. NAC1 can be considered as good candidates for industrial production of PHB from cardboard industry waste water. We are reporting for the first time the use of cardboard industry waste water as a cultivation medium for the PHB production. PMID:24288534

Liquid waste handling facilities for a conceptual LWR spent fuel reprocessing complex

International Nuclear Information System (INIS)

Witt, D.C.; Bradley, R.F.

1978-01-01

The waste evaporator systems and the methods for evaporating the liquid wastes of various radioactivity levels are discussed. After the liquid wastes are evaporated and nitric acid is recovered the high-level liquid waste is incorporated into borosilicate glass and the intermediate-level liquid waste into concrete for final disposal

Reduction of energy cost and CO{sub 2} emission for the furnace using energy recovered from waste tail-gas

Energy Technology Data Exchange (ETDEWEB)

Jou, Chih-Ju G.; Wu, Chung-Rung; Lee, Chien-Li [Department of Safety, Health and Environmental Engineering, National Kaohsiung First University of Science and Technology, No. 2, Jhuoyue Road, Nanzih District, Kaohsiung 811 (China)

2010-03-15

In this research, the waste tail gas emitted from petrochemical processes, e.g. catalytic reforming unit, catalytic cracking unit and residue desulfurization unit, was recovered and reused as a replacement of natural gas (NG). On-site experimental results show that both the flame length and orange-yellowish brightness decrease with more proportion of waste gas fuel added to the natural gas, and that the adiabatic temperature of the mixed fuel is greater than 1800 C. A complete replacement of natural gas by the recovered waste gas fuel will save 5.8 x 10{sup 6} m{sup 3} of natural gas consumption, and 3.5 x 10{sup 4} tons of CO{sub 2} emission annually. In addition, the reduction of residual O{sub 2} concentration in flue gases from 4% to 3% will save 1.1 x 10{sup 6} m{sup 3} of natural gas consumption, reduce 43.0% of NO{sub x} emission, and 1.3 x 10{sup 3} tons of CO{sub 2} emission annually. Thus, from the viewpoint of the overall economics and sustainable energy policy, recovering the waste tail gas energy as an independent fuel source to replace natural gas is of great importance for saving energy, reducing CO{sub 2} emission reduction, and lowering environmental impact. (author)

Use of Iron (II Salts and Complexes for the Production of Soil Amendments from Organic Solid Wastes

Directory of Open Access Journals (Sweden)

Amerigo Beneduci

2012-01-01

Full Text Available A method to obtain rapidly stabilized composts for crops from solid organic wastes is evaluated. Here we used a laboratory scale reaction chamber where solid waste treatment was performed under strictly controlled temperature and pressure conditions. The row organic waste was mixed with acid solutions containing iron (II ions either in the fully hydrated form or in the form of complexes with the diethylentriaminopentaacetic acid. Data from elemental analysis distribution and GC/MS analysis of the polar and non polar dissolved organic matter, clearly showed that Fe(II ions significantly enhance organic substrate oxidation of the initial solid waste, compared to a material obtained without the addition of the Fe(II ions to the raw organic matrix. These results suggest that Fe(II ions might be involved in a catalytic oxidation pathway that would be activated under the experimental conditions used. The extent of the oxidation process was evaluated by the value of the C/N ratio and, qualitatively, by the molecular composition of the dissolved organic matter. After about 6 hours of incubation, dark-brown and dry organic matrices were obtained with C/N ratio as low as 12 and a high degree of oxidative decomposition into low-molecular-weight compounds at high oxidation state.

Chemical mass balance modeling for air quality analysis near a waste-to-energy facility in a complex urban area: Program design

International Nuclear Information System (INIS)

Wells, R.; Watson, J.

1997-01-01

This paper describes the design and implementation of an ambient monitoring and receptor modeling study to evaluate air quality impacts from a state-of-the-art municipal waste management facility in a major urban area. The Robbins Resource Recovery Facility (RRRF), located in the Chicago metropolitan area, processes municipal solid waste (MSW) to recover recyclables, process the residual waste to create refuse-derived fuel (RDF), and burns the RDF to reduce the residual waste volume and recover energy. The RRRF is cooperating with the Illinois Environmental Protection Agency (IEPA) and the Illinois Office of the Attorney General (OAG) to analyze air quality and facility impacts in the plant vicinity. An ambient monitoring program began one year before plant operation and will continue for five years after startup. Because the impacts of the RRRF are projected to be very low, and because the Chicago area includes a complex mix of existing industrial, commercial, and residential activity, the ambient data will be analyzed using Version 7.0 of the USEPA s Chemical Mass Balance (CMB) model to estimate the extent of the RRRF's impact on air quality in the area. The first year of pre-operational ambient data is currently under analysis. This paper describes the study design considerations, ambient monitoring program, emission data acquisition, background source data needs, and data analysis procedures developed to conduct CMB modeling in a complex industrialized area

The effect of Health, Safety and Environment Management System (HSE-MS on the improvement of safety performance indices in Urea and Ammonia Kermanshah Petrochemical Company

Directory of Open Access Journals (Sweden)

M. S. Poursoleiman

2015-09-01

.Conclusion: The implementation of Health, Safety and the Environment Management System caused a reduction in accidents and its consequences and most of the safety performance indices in the entire process cycle of Kermanshah Petrochemical Company. Overall, safety condition has been improved considerably.

From weapons to waste: The future of the nuclear weapons complex

International Nuclear Information System (INIS)

Wasserman Goodman, Sherri

1992-01-01

This paper examines how decision-making power has shifted within the nuclear weapons complex, from the federal government operating agency, in which power was originally vested by the Atomic Energy Act, to the states and to regulatory authorities. Additionally, when the original operating agency, the Atomic Energy Commission (AEC), was abolished in the 1970s, substantial decision-making power shifted from Washington to the field sites. This paper identifies the needs for future materials and weapons production, and recommends that restart of old plants be abandoned as no longer militarily necessary. Instead, the U. S. should take advantage of what may be a unique opportunity to 'leapfrog' to new, smaller, technologically-advanced plants that will meet the needs of the nuclear arsenal in the post-Cold War world. This paper then looks at the current state of DOE's environmental restoration/waste management program, and the technological, legal and political problems it faces in trying to accomplish its mission of cleaning up all nuclear weapons sites. This paper argues that the U. S. government no longer has the exclusive authority to make and carry out critical decisions affecting a cleanup program that will cost the U. S. over $200 billion over the next 20-40 years. Moreover, there are competing theories about the principles that should guide the cleanup program. Finally, the author examines alternative futures for the DOE'S environmental restoration/waste management program. (author)

Radioactive waste management in Slovenia

International Nuclear Information System (INIS)

Fink, K.

1992-01-01

The problem of radioactive waste management is both scientifically and technically complex and also deeply emotional issue. In the last twenty years the first two aspects have been mostly resolved up to the point of safe implementation. In the Republic of Slovenia, certain fundamentalist approaches in politics and the use of radioactive waste problem as political marketing tool, make things even more complex. Public involvement in planning and development of radioactive waste management program must be perceived as essential for the success of the program. Education is a precursor to public comprehension and confidence which lead to adequate waste management decisions that will protect the public health, safety and environment without jeopardizing further progress and development. (author) [sl

Assessment of the Mechanisms for Sr-90 and TRU Removal from Complexant-Containing Tank Wastes at Hanford

International Nuclear Information System (INIS)

Hallen, Richard T.; Geeting, John GH; Lilga, Michael A.; Hart, Todd R.; Hoopes, Francis V.

2005-01-01

Small-scale tests (∼20 mL) were conducted with samples from Hanford underground storage tanks AN-102 and AN-107 to assess the mechanisms for removing Sr-90 and transuranics (TRU) from the liquid (supernatant) portion of the waste. The Sr-90 and TRU must be removed (decontaminated), in addition to Cs-137 and the entrained solids, before the supernatant can be disposed of as low-activity waste. Experiments were conducted with various reagents and modified Sr/TRU removal process conditions to more fully understand the reaction mechanisms. The optimized treatment conditions--no added hydroxide, addition of Sr (0.02M target concentration) followed by sodium permanganate (0.02M target concentration) with mixing at ambient temperature--were used as a reference for comparison. The waste was initially two orders of magnitude undersaturated with Sr; the addition of nonradioactive Sr(NO?) ? saturated the supernatant, resulting in isotopic dilution and precipitation of Sr-90 as SrCO?. The reaction chemistry of Mn species relevant to the mechanism of TRU removal by permanganate treatment was evaluated, along with the importance of various mechanisms for decontamination, such as precipitation, absorption, ligand exchange, and oxidation of organic complexants. For TRU removal, permanganate addition generally gave the highest DF. The addition of Mn of lower oxidation states (II, IV, and VI) also resulted in good TRU removal, as did complexant oxidation with periodate and addition of Zr(IV) for ligand exchange. These results suggest that permanganate treatment leads to TRU removal by multiple routes

Investigation of the subsurface environment at the Idaho National Engineering Laboratory Radioactive Waste Management Complex

International Nuclear Information System (INIS)

Russell, B.F.; Mizell, S.A.; Hull, L.C.; Smith, T.H.; Lewis, B.D.; Barraclough, J.T.; Humphrey, T.G.

1984-01-01

A comprehensive, 10-year plan to investigate radionuclide migration in the subsurface at the Radioactive Waste Management Complex (RWMC) has been prepared and initiated (in FY-84). The RWMC Subsurface Investigation is designed to address two objectives set forth by the DOE Idaho Operations Office: (1) determine the extent of radionuclide migration, if any, from the buried waste, and (2) develop and calibrate a computer model to simulate long-term radionuclide migration. At the RWMC, the Snake River Plain Aquifer underlies about 177 m of partially saturated, fractured basalts and thin sedimentary units. Three sedimentary units, accounting for no more than 20 m of the partially saturated thickness, appear to be continuous throughout the area. Thinner sedimentary units are discontinuous. Low-level waste and (prior to 1970) transuranic waste have been buried in the surficial sediments at the RWMC. The first burials took place in 1952. Due to the complicated disposal system, a comprehensive review of state-of-the-art vadose zone monitoring instrumentation and techniques, an analysis of conceptual migration pathways, and an evaluation of potential hazard from buried radionuclides were conducted to guide preparation of the investigation plan. The plan includes an overview of the RWMC facility, subsurface work conducted to date at the RWMC and other DOE laboratory facilities, an evaluation and selection of the methods and studies to be used, a radionuclide hazard evaluation, a cost analysis, and external peer review results. In addition, an Appendix contains the details for each method/study to be employed. 4 references, 5 figures, 1 table

Corrective Measures Study Modeling Results for the Southwest Plume - Burial Ground Complex/Mixed Waste Management Facility

International Nuclear Information System (INIS)

Harris, M.K.

1999-01-01

Groundwater modeling scenarios were performed to support the Corrective Measures Study and Interim Action Plan for the southwest plume of the Burial Ground Complex/Mixed Waste Management Facility. The modeling scenarios were designed to provide data for an economic analysis of alternatives, and subsequently evaluate the effectiveness of the selected remedial technologies for tritium reduction to Fourmile Branch. Modeling scenarios assessed include no action, vertical barriers, pump, treat, and reinject; and vertical recirculation wells

A business perspective on environmental risk and cost reduction

International Nuclear Information System (INIS)

Roper, U.V.

1998-01-01

The ways in which the petrochemical industry can enjoy successful business partnerships with environmental service companies was discussed. The petrochemical industry has traditionally viewed environmental service companies as an inherent cost in the context of risk management, and not in the context of business opportunity. Today, as environmental issues are integrated into business operations, there is a new potential for creating business opportunities in a number of operational areas, among them : (1) energy efficiency, (2) process efficiency, (3) waste minimization, (4) waste recycling, and (5) operational pooling. As environmental service companies became more competitive, they have become more attractive business partners. They are providing more diversified services and are better aligned with core competencies required to exploit business opportunities that are too small for major players in the oil,natural gas and petro-chemical industry. They also offer public recognition and financial upside for industry. Some examples of successful business partnerships along these lines are briefly described

Treatment and disposal of toxic wastes

Energy Technology Data Exchange (ETDEWEB)

Train, D

1983-03-01

An unparallelled expansion of material benefits to life and commerce in the '50s and '60s caused wastes to increase in variety and complexity. Amongst these some materials were particularly hazardous, being flammable, corrosive, reactive or toxic. This article presents simple guidelines for use in complex waste disposal situations.