Oxygen isotopic signature of CO2 from combustion processes

Directory of Open Access Journals (Sweden)

W. A. Brand

2011-02-01

Full Text Available For a comprehensive understanding of the global carbon cycle precise knowledge of all processes is necessary. Stable isotope (13C and 18O abundances provide information for the qualification and the quantification of the diverse source and sink processes. This study focuses on the δ18O signature of CO2 from combustion processes, which are widely present both naturally (wild fires, and human induced (fossil fuel combustion, biomass burning in the carbon cycle. All these combustion processes use atmospheric oxygen, of which the isotopic signature is assumed to be constant with time throughout the whole atmosphere. The combustion is generally presumed to take place at high temperatures, thus minimizing isotopic fractionation. Therefore it is generally supposed that the 18O signature of the produced CO2 is equal to that of the atmospheric oxygen. This study, however, reveals that the situation is much more complicated and that important fractionation effects do occur. From laboratory studies fractionation effects on the order of up to 26%permil; became obvious in the derived CO2 from combustion of different kinds of material, a clear differentiation of about 7‰ was also found in car exhausts which were sampled directly under ambient atmospheric conditions. We investigated a wide range of materials (both different raw materials and similar materials with different inherent 18O signature, sample geometries (e.g. texture and surface-volume ratios and combustion circumstances. We found that the main factor influencing the specific isotopic signatures of the combustion-derived CO2 and of the concomitantly released oxygen-containing side products, is the case-specific rate of combustion. This points firmly into the direction of (diffusive transport of oxygen to the reaction zone as the cause of the isotope fractionation. The original total 18O signature of the material appeared to have little influence, however, a contribution of specific bio

Energy balance of a wood biomass combustion process

International Nuclear Information System (INIS)

Baggio, P.; Cemin, A.; Grigiante, M.; Ragazzi, M.

2001-01-01

This article reports the results of a project developed at the University of Trent dealing with some wood biomass combustion processes. The project has been particularly dedicated to the study of the energetic analysis of the combustion processes that occur on a gasified wood stove of advanced combustion technologies. A considerable number of experimental tests has been carried out making use of different type of wood widely in use in Trentino region. The wood stove is a part of a pilot plant providing an hydraulic circuit equipped with a specific apparatus to measure all the necessary data to determine the energy balance required and specifically the thermal efficiency of the plant [it

Process for water-gas generation from degassed combustibles

Energy Technology Data Exchange (ETDEWEB)

1906-05-23

A process for water-gas generation in a continuous operation from degassed combustibles in the lower part of a vertical exterior-heated retort, whose middle part can serve to degas the combustibles, is described. It is characterized in that the water vapor employed is obtained by vaporizing water in the upper part of the retort by means of the waste heat from the heating gases, which had effected the coking of the combustibles before the water-gas recovery or after the latter.

Gas permeation process for post combustion CO2 capture

International Nuclear Information System (INIS)

Pfister, Marc

2017-01-01

CO 2 Capture and Storage (CCS) is a promising solution to separate CO 2 from flue gas, to reduce the CO 2 emissions in the atmosphere, and hence to reduce global warming. In CCS, one important constraint is the high additional energy requirement of the different capture processes. That statement is partly explained by the low CO 2 fraction in the inlet flue gas and the high output targets in terms of CO 2 capture and purity (≥90%). Gas permeation across dense membrane can be used in post combustion CO 2 capture. Gas permeation in a dense membrane is ruled by a mass transfer mechanism and separation performance in a dense membrane are characterized by component's effective permeability and selectivity. One of the newest and encouraging type of membrane in terms of separation performance is the facilitated transport membrane. Each particular type of membrane is defined by a specific mass transfer law. The most important difference to the mass transfer behavior in a dense membrane is related to the facilitated transport mechanism and the solution diffusion mechanism and its restrictions and limitations. Permeation flux modelling across a dense membrane is required to perform a post combustion CO 2 capture process simulation. A CO 2 gas permeation separation process is composed of a two-steps membrane process, one drying step and a compression unit. Simulation on the energy requirement and surface area of the different membrane modules in the global system are useful to determine the benefits of using dense membranes in a post combustion CO 2 capture technology. (author)

Internal Heterogeneous Processes in Aluminum Combustion

Science.gov (United States)

Dreizin, E. L.

1999-01-01

This paper discusses the aluminum particle combustion mechanism which has been expanded by inclusion of gas dissolution processes and ensuing internal phase transformations. This mechanism is proposed based on recent normal and microgravity experiments with particles formed and ignited in a pulsed micro-arc. Recent experimental findings on the three stages observed in Al particle combustion in air and shows the burning particle radiation, trajectory (streak), smoke cloud shapes, and quenched particle interiors are summarized. During stage I, the radiation trace is smooth and the particle flame is spherically symmetric. The temperature measured using a three-color pyrometer is close to 3000 K. Because it exceeds the aluminum boiling point (2730 K), this temperature most likely characterizes the vapor phase flame zone rather than the aluminum surface. The dissolved oxygen content within particles quenched during stage I was below the detection sensitivity (about 1 atomic %) for Wavelength Dispersive Spectroscopy (WDS). After an increase in the radiation intensity (and simultaneous decrease in the measured color temperature from about 3000 to 2800 K) indicative of the transition to stage II combustion, the internal compositions of the quenched particles change. Both oxygen-rich (approx. 10 atomic %) and oxygen-lean (combustion behavior and the evolution of its internal composition, the change from the spherically symmetric to asymmetric flame shape occurring upon the transition from stage I to stage II combustion could not be understood based only on the fact that dissolved oxygen is detected in the particles. The connection between the two phenomena appeared even less significant because in earlier aluminum combustion studies carried in O2/Ar mixtures, flame asymmetry was not observed as opposed to experiments in air or O2/CO mixtures. It has been proposed that the presence of other gases, i.e., hydrogen, or nitrogen causes the change in the combustion regime.

Modeling of large-scale oxy-fuel combustion processes

DEFF Research Database (Denmark)

Yin, Chungen

2012-01-01

Quite some studies have been conducted in order to implement oxy-fuel combustion with flue gas recycle in conventional utility boilers as an effective effort of carbon capture and storage. However, combustion under oxy-fuel conditions is significantly different from conventional air-fuel firing......, among which radiative heat transfer under oxy-fuel conditions is one of the fundamental issues. This paper demonstrates the nongray-gas effects in modeling of large-scale oxy-fuel combustion processes. Oxy-fuel combustion of natural gas in a 609MW utility boiler is numerically studied, in which...... calculation of the oxy-fuel WSGGM remarkably over-predicts the radiative heat transfer to the furnace walls and under-predicts the gas temperature at the furnace exit plane, which also result in a higher incomplete combustion in the gray calculation. Moreover, the gray and non-gray calculations of the same...

International evaluation of the programme on engine-related combustion

Energy Technology Data Exchange (ETDEWEB)

Arcoumanis, D [Imperial College, London (United Kingdom); Greenhalgh, D [Cranfield Univ. (United Kingdom); Magnusson, B F [Norwegian Univ. of Science and Technology, Trondheim (Norway); Peters, N [Institut fuer Technische Mechanik, RWTH Aachen (Germany)

1996-11-01

The 12 projects in the engine related combustion programme cover the entire range from fundamental and theoretical aspects of combustion to more applied subjects such as engine control. The common denominator in the programme clearly is the internal combustion engine, both the reciprocating as well as the gas turbine engine. Such a large coverage by a relatively small number of projects necessarily leads to an isolation of some of the projects in terms of their subject as well as the methodology that is used. On the other hand, all the research areas of interest in combustion technology are represented by at least one of the projects. These are: mathematical and numerical methods in combustion; modelling of turbulent combustion; laser diagnostics of flows with combustion; studies of engine performance and their control; semi-empirical model development for practical applications. As a conclusion, the evaluation committee believes that the programme is well balanced between fundamental and applied projects. It covers the entire range of modern methodologies that are used on the international level and thereby contributes to the application and further development of these research tools in Sweden

Combustion

CERN Document Server

Glassman, Irvin

2008-01-01

Combustion Engineering, a topic generally taught at the upper undergraduate and graduate level in most mechanical engineering programs, and many chemical engineering programs, is the study of rapid energy and mass transfer usually through the common physical phenomena of flame oxidation. It covers the physics and chemistry of this process and the engineering applications-from the generation of power such as the internal combustion automobile engine to the gas turbine engine. Renewed concerns about energy efficiency and fuel costs, along with continued concerns over toxic and particulate emissions have kept the interest in this vital area of engineering high and brought about new developments in both fundamental knowledge of flame and combustion physics as well as new technologies for flame and fuel control. *New chapter on new combustion concepts and technologies, including discussion on nanotechnology as related to combustion, as well as microgravity combustion, microcombustion, and catalytic combustion-all ...

Challenges in simulation of chemical processes in combustion furnaces

Energy Technology Data Exchange (ETDEWEB)

Hupa, M.; Kilpinen, P. [Aabo Akademi, Turku (Finland)

1996-12-31

The presentation gives an introduction to some of the present issues and problems in treating the complex chemical processes in combustion. The focus is in the coupling of the hydrocarbon combustion process with nitrogen oxide formation and destruction chemistry in practical furnaces or flames. Detailed kinetic modelling based on schemes of elementary reactions are shown to be a useful novel tool for identifying and studying the key reaction paths for nitrogen oxide formation and destruction in various systems. The great importance of the interaction between turbulent mixing and combustion chemistry is demonstrated by the sensitivity of both methane oxidation chemistry and fuel nitrogen conversion chemistry to the reactor and mixing pattern chosen for the kinetic calculations. The fluidized bed combustion (FBC) nitrogen chemistry involves several important heterogeneous reactions. Particularly the char in the bed plays an essential role. Recent research has advanced rapidly and the presentation proposes an overall picture of the fuel nitrogen reaction routes in circulating FBC conditions. (author)

Challenges in simulation of chemical processes in combustion furnaces

Energy Technology Data Exchange (ETDEWEB)

Hupa, M; Kilpinen, P [Aabo Akademi, Turku (Finland)

1997-12-31

The presentation gives an introduction to some of the present issues and problems in treating the complex chemical processes in combustion. The focus is in the coupling of the hydrocarbon combustion process with nitrogen oxide formation and destruction chemistry in practical furnaces or flames. Detailed kinetic modelling based on schemes of elementary reactions are shown to be a useful novel tool for identifying and studying the key reaction paths for nitrogen oxide formation and destruction in various systems. The great importance of the interaction between turbulent mixing and combustion chemistry is demonstrated by the sensitivity of both methane oxidation chemistry and fuel nitrogen conversion chemistry to the reactor and mixing pattern chosen for the kinetic calculations. The fluidized bed combustion (FBC) nitrogen chemistry involves several important heterogeneous reactions. Particularly the char in the bed plays an essential role. Recent research has advanced rapidly and the presentation proposes an overall picture of the fuel nitrogen reaction routes in circulating FBC conditions. (author)

Analysis of exergy loss of gasoline surrogate combustion process based on detailed chemical kinetics

International Nuclear Information System (INIS)

Sun, Hongjie; Yan, Feng; Yu, Hao; Su, W.H.

2015-01-01

Highlights: • We explored the exergy loss sources of gasoline engine like combustion process. • The model combined non-equilibrium thermodynamics with detailed chemical kinetics. • We explored effects of initial conditions on exergy loss of combustion process. • Exergy loss decreases 15% of fuel chemical exergy by design of initial conditions. • Correspondingly, the second law efficiency increases from 38.9% to 68.9%. - Abstract: Chemical reaction is the most important source of combustion irreversibility in premixed conditions, but details of the exergy loss mechanisms have not been explored yet. In this study numerical analysis based on non-equilibrium thermodynamics combined with detailed chemical kinetics is conducted to explore the exergy loss mechanism of gasoline engine like combustion process which is simplified as constant volume combustion. The fuel is represented by the common accepted gasoline surrogates which consist of four components: iso-octane (57%), n-heptane (16%), toluene (23%), and 2-pentene (4%). We find that overall exergy loss is mainly composed of three peaks along combustion generated from chemical reactions in three stages, the conversion from large fuel molecules into small molecules (as Stage 1), the H 2 O 2 loop-related reactions (as Stage 2), and the violent oxidation reactions of CO, H, and O (as Stage 3). The effects of individual combustion boundaries, including temperature, pressure, equivalence ratio, oxygen concentration, on combustion exergy loss have been widely investigated. The combined effects of combustion boundaries on the total loss of gasoline surrogates are also investigated. We find that in a gasoline engine with a compression ratio of 10, the total loss can be reduced from 31.3% to 24.3% using lean combustion. The total loss can be further reduced to 22.4% by introducing exhaust gas recirculation and boosting the inlet charge. If the compression ratio is increased to 17, the total loss can be decreased to

MODELING SEGREGATED INSITU COMBUSTION PROCESSES THROUGH A VERTICAL DISPLACEMENT MODEL APPLIED TO A COLOMBIAN FIELD

OpenAIRE

Guerra Aristizábal, José-Julián; Grosso Vargas, Jorge-Luis

2005-01-01

Recently it has been proposed the incorporation of horizontal well technologies in thermal EOR processes like the in situ combustion process (ISC). This has taken to the conception of new recovery mechanisms named here as Segregated In-Situ Combustion processes which are conventional in-situ combustion process with a segregated flow component. Top/Down combustion, Combustion Override Splitproduction Horizontal-well and Toe-to-Heel Air Injection are three of these processes, which incorporate ...

In situ high-temperature gas sensors: continuous monitoring of the combustion quality of different wood combustion systems and optimization of combustion process

Directory of Open Access Journals (Sweden)

H. Kohler

2018-03-01

Full Text Available The sensing characteristics and long-term stability of different kinds of CO ∕ HC gas sensors (non-Nernstian mixed potential type during in situ operation in flue gas from different types of low-power combustion systems (wood-log- and wood-chip-fuelled were investigated. The sensors showed representative but individual sensing behaviour with respect to characteristically varying flue gas composition over the combustion process. The long-term sensor signal stability evaluated by repeated exposure to CO ∕ H2 ∕ N2 ∕ synthetic air mixtures showed no sensitivity loss after operation in the flue gas. Particularly for one of the sensors (Heraeus GmbH, this high signal stability was observed in a field test experiment even during continuous operation in the flue gas of the wood-chip firing system over 4 months. Furthermore, it was experimentally shown that the signals of these CO ∕ HC sensing elements yield important additional information about the wood combustion process. This was demonstrated by the adaptation of an advanced combustion airstream control algorithm on a wood-log-fed fireplace and by the development of a combustion quality monitoring system for wood-chip-fed central heaters.

Processing of combustible radioactive waste using incineration techniques

International Nuclear Information System (INIS)

Maestas, E.

1981-01-01

Among the OECD Nuclear Energy Agency Member countries numerous incineration concepts are being studied as potential methods for conditioning alpha-bearing and other types of combustible radioactive waste. The common objective of these different processes is volume reduction and the transformation of the waste to a more acceptable waste form. Because the combustion processes reduce the mass and volume of waste to a form which is generally more inert than the feed material, the resulting waste can be more uniformly compatible with safe handling, packaging, storage and/or disposal techniques. The number of different types of combustion process designed and operating specifically for alpha-bearing wastes is somewhat small compared with those for non-alpha radioactive wastes; however, research and development is under way in a number of countries to develop and improve alpha incinerators. This paper provides an overview of most alpha-incineration concepts in operation or under development in OECD/NEA Member countries. The special features of each concept are briefly discussed. A table containing characteristic data of incinerators is presented so that a comparison of the major programmes can be made. The table includes the incinerator name and location, process type, capacity throughput, operational status and application. (author)

Study on Combustion Characteristics and Propelling Projectile Motion Process of Bulk-Loaded Liquid Propellant

Science.gov (United States)

Xue, Xiaochun; Yu, Yonggang; Mang, Shanshan

2017-07-01

Data are presented showing that the problem of gas-liquid interaction instability is an important subject in the combustion and the propellant projectile motion process of a bulk-loaded liquid propellant gun (BLPG). The instabilities themselves arise from the sources, including fluid motion, to form a combustion gas cavity called Taylor cavity, fluid turbulence and breakup caused by liquid motion relative to the combustion chamber walls, and liquid surface breakup arising from a velocity mismatch on the gas-liquid interface. Typically, small disturbances that arise early in the BLPG combustion interior ballistic cycle can become amplified in the absence of burn rate limiting characteristics. Herein, significant attention has been given to developing and emphasizing the need for better combustion repeatability in the BLPG. Based on this goal, the concept of using different geometries of the combustion chamber is introduced and the concept of using a stepped-wall structure on the combustion chamber itself as a useful means of exerting boundary control on the combustion evolution to thus restrain the combustion instability has been verified experimentally in this work. Moreover, based on this background, the numerical simulation is devoted to a special combustion issue under transient high-pressure and high-temperature conditions, namely, studying the combustion mechanism in a stepped-wall combustion chamber with full monopropellant on one end that is stationary and the other end can move at high speed. The numerical results also show that the burning surface of the liquid propellant can be defined geometrically and combustion is well behaved as ignition and combustion progressivity are in a suitable range during each stage in this combustion chamber with a stepped-wall structure.

Problematic issues of air protection during thermal processes related to the energetic uses of sewage sludge and other waste. Case study: Co-combustion in peaking power plant.

Science.gov (United States)

Hroncová, Emília; Ladomerský, Juraj; Musil, Juraj

2018-03-01

Currently, it is necessary to deal with issues related to the emissions as there is a constantly increasing interest in combusting sludge from sewage treatment plants in the boilers for wood. An analysis of the energetic importance of the combustion of sewage sludge has already been carried out, but the effects of various treatments of the sludge are not always clear, e.g. composting and subsequent combustion to the air pollution. Investments in other thermal processes of energetic utilisation of sewage sludge and organic waste are not always successfully implemented. The objective of this paper is to point out some problematic cases for acceptance of thermal processes related to energetic use of waste in terms of the air protection. The other aim is to mention the experience with solutions of such issues in Slovakia. There are mentioned first results of the operational validation experiments during the energy generation in circulating fluidized bed boiler in peaking power plant (Power 110MW) with the addition of the so-called alternative fuel based on wood and sewage sludge to the main fuel - black coal (anthracite). And there has already been achieved the highest share of 12.4%w. (dry matter) of sewage sludge in form of compost in blend with black coal, which is technologically viable. Moreover analyzed the problems of the authorization and operation of the co-combustion of sewage sludge and of combustion of products of various kinds of pyrolysis waste - pyrolysis gas and pyrolysis oil are analyzed. Copyright © 2017 Elsevier Ltd. All rights reserved.

Experimental and theoretical analysis of the combustion process at low loads of a diesel natural gas dual-fuel engine

International Nuclear Information System (INIS)

Li, Weifeng; Liu, Zhongchang; Wang, Zhongshu

2016-01-01

To construct an effective method to analyze the combustion process of dual fuel engines at low loads, effects of combustion boundaries on the combustion process of an electronically controlled diesel natural gas dual-fuel engine at low loads were investigated. Three typical combustion modes, including h, m and n, appeared under different combustion boundaries. In addition, the time-sequenced characteristic and the heat release rate-imbalanced characteristic were found in the dual fuel engine combustion process. To quantify these characteristics, two quantitative indicators, including the TSC (time-sequenced coefficient) and the HBC (HRR-balanced coefficient) were defined. The results show that increasing TSC and HBC can decrease HC (hydrocarbon) emissions and improve the BTE (brake thermal efficiency) significantly. The engine with the n combustion mode can obtain the highest BTE and the lowest HC emissions, followed by m, and then h. However, the combustion process of the engine will deteriorate sharply if boundary conditions are not strictly controlled in the n combustion mode. Based on the n combustion mode, advancing the start of diesel injection significantly, using large EGR (exhaust gas recirculation) rate and appropriately intake throttling can effectively reduce HC emissions and improve the BTE of dual fuel engines at low loads with relatively high natural gas PES (percentage energy substitution). - Highlights: • We reported three typical combustion modes of a dual-fuel engine at low loads. • Time-sequenced characteristic was put forward and qualified. • HRR-imbalanced characteristic was put forward and qualified. • Three combustion modes appeared as equivalence ratio/diesel injection timing varied. • The engine performance varied significantly with different combustion mode.

Experimental Investigation and High Resolution Simulation of In-Situ Combustion Processes

Energy Technology Data Exchange (ETDEWEB)

Margot Gerritsen; Tony Kovscek

2008-04-30

This final technical report describes work performed for the project 'Experimental Investigation and High Resolution Numerical Simulator of In-Situ Combustion Processes', DE-FC26-03NT15405. In summary, this work improved our understanding of in-situ combustion (ISC) process physics and oil recovery. This understanding was translated into improved conceptual models and a suite of software algorithms that extended predictive capabilities. We pursued experimental, theoretical, and numerical tasks during the performance period. The specific project objectives were (i) identification, experimentally, of chemical additives/injectants that improve combustion performance and delineation of the physics of improved performance, (ii) establishment of a benchmark one-dimensional, experimental data set for verification of in-situ combustion dynamics computed by simulators, (iii) develop improved numerical methods that can be used to describe in-situ combustion more accurately, and (iv) to lay the underpinnings of a highly efficient, 3D, in-situ combustion simulator using adaptive mesh refinement techniques and parallelization. We believe that project goals were met and exceeded as discussed.

Development of spent solvent treatment process by a submerged combustion technique

International Nuclear Information System (INIS)

Uchiyama, Gunzo; Maeda, Mitsuru; Fujine, Sachio; Amakawa, Masayuki; Uchida, Katsuhide; Chida, Mitsuhisa

1994-01-01

An experimental study using a bench-scale equipment of 1 kg-simulated spent solvents per hour has been conducted in order to evaluate the applicability of a submerged combustion technique to the treatment of spent solvents contaminated with TRU elements. This report describes the experimental results on the combustion characteristics of the simulated spent solvents of tri-n-butyl phosphate and/or n-dodecane, and on the distribution behaviors of combustion products such as phosphoric acid, Ru, I, Zr and lanthanides as TRU simulants in the submerged combustion process. Also the experimental results of TRU separation from phosphoric acid solution by co-precipitation using bismuth phosphate are reported. It was shown that the submerged combustion technique was applicable to the treatment of spent solvents including the distillation residues of the solvent. Based on the experimental data, a new treatment process of spent solvent was proposed which consisted of submerged combustion, co-precipitation using bismuth phosphate, ceramic membrane filtration, cementation of TRU lean phosphate, and vitrification of TRU rich waste. (author)

Working group report: methane emissions from fuel combustion and industrial processes

International Nuclear Information System (INIS)

Berdowski, J.J.M.; Beck, L.; Piccot, S.; Olivier, J.G.J.; Veldt, C.

1993-01-01

This paper lists the source categories which are currently recognised as minor sources of methane. These fall into five broad groups: stationary fuel combustion (residential combustion of fuels, solid waste incineration at home sites, on-site agricultural waste burning, industrial and utility combustion of coal, wood, oil and gas, commercial and industrial waste incineration); mobile fuel combustion; non-combustion industrial processes (primary metals production, chemical manufacturing processes, petroleum refining, commercial charcoal manufacturing waste treatments); minor energy production sources (storage and distribution of automotive fuels, geothermal energy production; peat mining operations, oil shale mining operations); and miscellaneous sources. The paper also presents a preliminary estimate of global methane emissions from these minor sources and the results of the working group's discussion on recommendations for the IPCC/OECD methodology and specific research needs. A list of control options for emissions from minor sources is provided. 2 tabs

Comprehensive investigation of process characteristics for oxy-steam combustion power plants

International Nuclear Information System (INIS)

Jin, Bo; Zhao, Haibo; Zou, Chun; Zheng, Chuguang

2015-01-01

Highlights: • Oxy-steam combustion exhibits better performance than oxy-CO 2 combustion. • Cost of electricity in oxy-steam combustion is 6.62% less than oxy-CO 2 combustion. • The increase of oxygen concentration in oxidant can improve its system performance. • The decrease of excess oxygen coefficient can be helpful for its system performance. • Integration with solar technology can enhance its thermodynamic performance. - Abstract: Oxy-steam combustion, as an alternative option of oxy-fuel combustion technology, is considered as a promising CO 2 capture technology for restraining CO 2 emissions from power plants. To attain its comprehensive process characteristics, process simulation, thermodynamic assessment, and sensitivity analysis for oxy-steam combustion pulverized-coal-fired power plants are investigated whilst its corresponding CO 2 /O 2 recycled combustion (oxy-CO 2 combustion) power plant is served as the base case for comparison. Techno-economic evaluation and integration with solar parabolic trough collectors are also discussed to justify its economic feasibility and improve its thermodynamic performance further, respectively. It is found that oxy-steam combustion exhibits better performance than oxy-CO 2 combustion on both thermodynamic and economic aspects, in which the cost of electricity decreases about 6.62% whilst the net efficiency and exergy efficiency increase about 0.90 and 1.01 percentage points, respectively. The increment of oxygen concentration in oxidant (20–45 mol.%) and decrease of excess oxygen coefficient (1.01–1.09) in a certain range are favorable for improving oxy-steam combustion system performance. Moreover, its thermodynamic performance can be improved when considering solar parabolic trough collectors for heating recycled water, even though its cost of electricity increases about 2 $/(MW h)

Characterising Combustion in Diesel Engines : Using parameterised finite stage cylinder process models

NARCIS (Netherlands)

Ding, Y.

2011-01-01

Characterising combustion of diesel engines is not only necessary when researching the instantaneous combustion phenomena but also when investigating the change of the combustion process under variable engine operating conditions. An effective way to achieve this goal is to parameterize the

Retrofit MHB Hamm. Process-related optimization of the combustion air system MHB Hamm; Retrofit MHB Hamm. Prozess- und verfahrenstechnische Optimierung des Verbrennungsluftsystems MHB Hamm

Energy Technology Data Exchange (ETDEWEB)

Schumacher, Frank [SC Schumacher Consulting handelnd fuer Xervon Energy GmbH, Ritterhude (Germany); Lindke, Carsten [MHB Hamm Betriebsfuehrungsgesellschaft mbH, Hamm (Germany); Auel, Werner [Xervon Energy GmbH, Duisburg (Germany)

2012-11-01

The authors of the contribution under consideration report on a process-related optimization of the combustion air system of the waste incinerator Hamm. Subsequently to the historical aspects of this waste incinerator and the development of its calorific values, the authors describe the tender Retrofit, its implementation as well as the first practical experiences.

Catalytically enhanced combustion process

International Nuclear Information System (INIS)

Rodriguez, C.

1992-01-01

This patent describes a fuel having improved combustion efficiency. It comprises a petroleum based liquid hydrocarbon; and a combustion catalyst comprising from about 18 to about 21 weight percent naphthalene, from about 75 to about 80 weight percent toluene, and from about 2.8 to about 3.2 weight percent benzyl alcohol

Technology for Transient Simulation of Vibration during Combustion Process in Rocket Thruster

Science.gov (United States)

Zubanov, V. M.; Stepanov, D. V.; Shabliy, L. S.

2018-01-01

The article describes the technology for simulation of transient combustion processes in the rocket thruster for determination of vibration frequency occurs during combustion. The engine operates on gaseous propellant: oxygen and hydrogen. Combustion simulation was performed using the ANSYS CFX software. Three reaction mechanisms for the stationary mode were considered and described in detail. The way for obtaining quick CFD-results with intermediate combustion components using an EDM model was found. The way to generate the Flamelet library with CFX-RIF was described. A technique for modeling transient combustion processes in the rocket thruster was proposed based on the Flamelet library. A cyclic irregularity of the temperature field like vortex core precession was detected in the chamber. Frequency of flame precession was obtained with the proposed simulation technique.

Effects of Catalysts on Emissions of Pollutants from Combustion Processes of Liquid Fuels

Directory of Open Access Journals (Sweden)

Bok Agnieszka

2014-12-01

Full Text Available The dynamic growth of the use of non-renewable fuels for energy purposes results in demand for catalysts to improve their combustion process. The paper describes catalysts used mainly in the processes of combustion of motor fuels and fuel oils. These catalysts make it possible to raise the efficiency of oxidation processes simultanously reducing the emission of pollutants. The key to success is the selection of catalyst compounds that will reduce harmful emissions of combustion products into the atmosphere. Catalysts are introduced into the combustion zone in form of solutions miscible with fuel or with air supplied to the combustion process. The following compounds soluble in fuel are inclused in the composition of the described catalysts: organometallic complexes, manganese compounds, salts originated from organic acids, ferrocen and its derivatives and sodium chloride and magnesium chloride responsible for burning the soot (chlorides. The priority is to minimize emissions of volatile organic compounds, nitrogen oxides, sulphur oxides, and carbon monoxide, as well as particulate matter.

Effect of Electric Field in the Stabilized Premixed Flame on Combustion Process Emissions

Science.gov (United States)

Otto, Krickis

2017-10-01

The effect of the AC and DC electrical field on combustion processes has been investigated by various researchers. The results of these experiments do not always correlate, due to different experiment conditions and experiment equipment variations. The observed effects of the electrical field impact on the combustion process depends on the applied voltage polarity, flame speed and combustion physics. During the experiment was defined that starting from 1000 V the ionic wind takes the effect on emissions in flue gases, flame shape and combustion instabilities. Simulation combustion process in hermetically sealed chamber with excess oxygen amount 3 % in flue gases showed that the positive effect of electrical field on emissions lies in region from 30 to 400 V. In aforementioned voltage range carbon monoxide emissions were reduced by 6 % and at the same time the nitrogen oxide emissions were increased by 3.5 %.

Advanced Fuels and Combustion Processes for Propulsion

Science.gov (United States)

2010-09-01

production from biomass steam reforming – Conduct a feasibility analysis of the proposed integrated process Energia Technologies - D. Nguyen & K. Parimi...strength foam material development by Ultramet – Combustion experiments performed U. Of Alabama – End-user input provided by Solar Turbines Major

Steam generation by combustion of processed waste fats

Energy Technology Data Exchange (ETDEWEB)

Pudel, F.; Lengenfeld, P. [OEHMI Forschung und Ingenieurtechnik GmbH, Magdeburg (Germany)

1993-12-31

The use of specially processed waste fats as a fuel oil substitute offers, at attractive costs, an environmentally friendly alternative to conventional disposal like refuse incineration or deposition. For that purpose the processed fat is mixed with EL fuel oil and burned in a standard steam generation plant equipped with special accessories. The measured emission values of the combustion processes are very low.

Modeling segregated in- situ combustion processes through a vertical displacement model applied to a Colombian field

International Nuclear Information System (INIS)

Guerra Aristizabal, Jose Julian; Grosso Vargas, Jorge Luis

2005-01-01

Recently it has been proposed the incorporation of horizontal well technologies in thermal EOR processes like the in situ combustion process (ISC). This has taken to the conception of new recovery mechanisms named here as segregated in-situ combustion processes, which are conventional in-situ combustion process with a segregated flow component. Top/Down combustion, Combustion Override Split-production Horizontal-well and Toe-to-Heel Air Injection are three of these processes, which incorporate horizontal producers and gravity drainage phenomena. When applied to thick reservoirs a process of this nature could be reasonably modeled under concepts of conventional in-situ combustion and Crestal Gas injection, especially for heavy oils mobile at reservoir conditions. A process of this nature has been studied through an analytic model conceived for the particular conditions of the Castilla field, a homogeneous thick anticline structure containing high mobility heavy oil, which seems to be an excellent candidate for the application of these technologies

Dynamic simulation in the process of pressurized denitration based on oxy-fuel combustion

Science.gov (United States)

Huang, Qiang; Zhou, Dong

2018-02-01

Oxy-fuel combustion is considered as one of the most promising technologies for capturing CO2 from coal-fired power plants. It will greatly reduce the cost of gas purification if we remove NOx in the process of compression, which is the characteristic of oxy-combustion. In this paper, simulation of denitration process of oxy-fuel combustion flue gas was realized by the Aspen Plus software, systematically analyzed the effect of temperature, pressure, initial concentration of O2 and NO in the denitration process. Results show that the increasing of pressure, initial concentration of O2, initial concentration of NO and the decrease of temperature are all beneficial to the denitration process.

Thermodynamic diagnosis of diesel and biodiesel combustion processes during load-increase transient sequences

International Nuclear Information System (INIS)

Armas, Octavio; Ballesteros, Rosario; Cardenas, María Dolores

2012-01-01

Highlights: ► Thermodynamic diagnosis was applied to diesel combustion process during transient operation. ► Comparative analysis of thermodynamic results with different biodiesel fuels has been carried out. ► Biodiesel fuels studied have a slight effect on timing of the combustion process. ► Methodology used can be applied to improve engine control when using different alternative fuels. -- Abstract: The study of the diesel combustion process is a current topic by the need of thermal efficiency improving and the reduction of pollutant emissions. This circumstance has forced researchers and manufacturers to optimize this process not only in steady state operating conditions but also during transient operation. A zero dimensional thermodynamic diagnostic model, with three species (air, fuel evaporated and burned products), has been used to characterize the combustion process during load increase transient sequences at two different engine speed. In both sequences, three variables were studied: the valve position of the exhaust gas recirculation (EGR), the elapsed time of the transition process and the type of fuel. Three biodiesel fuels were tested pure: rapeseed, soybean and sunflower which were compared to a commercial diesel fuel used as reference. Results are presented comparing the in-cylinder average maximum pressure and temperature, and the phasing of the combustion process based on the calculation of heat release. This study has allowed the detection of the effect of the tested engine parameters and the biodiesel fuels used on the in-cylinder thermodynamic conditions during the load transient sequences studied.

Design of Hybrid Steam-In Situ Combustion Bitumen Recovery Processes

International Nuclear Information System (INIS)

Yang Xiaomeng; Gates, Ian D.

2009-01-01

Given enormous capital costs, operating expenses, flue gas emissions, water treatment and handling costs of thermal in situ bitumen recovery processes, improving the overall efficiency by lowering energy requirements, environmental impact, and costs of these production techniques is a priority. Steam-assisted gravity drainage (SAGD) is the most widely used in situ recovery technique in Athabasca reservoirs. Steam generation is done on surface and consequently, because of heat losses, the energy efficiency of SAGD can never be ideal with respect to the energy delivered to the sandface. An alternative to surface steam generation is in situ combustion (ISC) where heat is generated within the formation through injection of oxygen at a sufficiently high pressure to initiate combustion of bitumen. In this manner, the heat from the combustion reactions can be used directly to mobilize the bitumen. As an alternative, the heat can be used to generate steam within the formation which then is the agent to move heat in the reservoir. In this research, alternative hybrid techniques with simultaneous and sequential steam-oxygen injection processes are examined to maximize the thermal efficiency of the recovery process. These hybrid processes have the advantage that during ISC, steam is generated within the reservoir from injected and formation water and as a product of oxidation. This implies that ex situ steam generation requirements are reduced and if there is in situ storage of combustion gases, that overall gas emissions are reduced. In this research, detailed reservoir simulations are done to examine the dynamics of hybrid processes to enable design of these processes. The results reveal that hybrid processes can lower emitted carbon dioxide-to-oil ratio by about 46%, decrease the consumed natural gas-to-oil ratio by about 73%, reduce the cumulative energy-to-oil ratio by between 40% and 70% compared to conventional SAGD, and drop water consumption per unit oil produced

Synthesis of Diopside by Solution Combustion Process Using Glycine Fuel

Science.gov (United States)

Sherikar, Baburao N.; Umarji, A. M.

Nano ceramic Diopside (CaMgSi2O6) powders are synthesized by Solution Combustion Process(SCS) using Calcium nitrate, Magnesium nitrate as oxidizer and glycine as fuel, fumed silica as silica source. Ammonium nitrate (AN) is used as extra oxidizer. Effect of AN on Diopside phase formation is investigated. The adiabatic flame temperatures are calculated theoretically for varying amount of AN according to thermodynamic concept and correlated with the observed flame temperatures. A “Multi channel thermocouple setup connected to computer interfaced Keithley multi voltmeter 2700” is used to monitor the thermal events during the process. An interpretation based on maximum combustion temperature and the amount of gases produced during reaction for various AN compositions has been proposed for the nature of combustion and its correlation with the characteristics of as synthesized powder. These powders are characterized by XRD, SEM showing that the powders are composed of polycrystalline oxides with crystallite size of 58nm to 74nm.

Method and device for diagnosing and controlling combustion instabilities in internal combustion engines operating in or transitioning to homogeneous charge combustion ignition mode

Science.gov (United States)

Wagner, Robert M [Knoxville, TN; Daw, Charles S [Knoxville, TN; Green, Johney B [Knoxville, TN; Edwards, Kevin D [Knoxville, TN

2008-10-07

This invention is a method of achieving stable, optimal mixtures of HCCI and SI in practical gasoline internal combustion engines comprising the steps of: characterizing the combustion process based on combustion process measurements, determining the ratio of conventional and HCCI combustion, determining the trajectory (sequence) of states for consecutive combustion processes, and determining subsequent combustion process modifications using said information to steer the engine combustion toward desired behavior.

Numerical modelling of biomass combustion: Solid conversion processes in a fixed bed furnace

Science.gov (United States)

Karim, Md. Rezwanul; Naser, Jamal

2017-06-01

Increasing demand for energy and rising concerns over global warming has urged the use of renewable energy sources to carry a sustainable development of the world. Bio mass is a renewable energy which has become an important fuel to produce thermal energy or electricity. It is an eco-friendly source of energy as it reduces carbon dioxide emissions. Combustion of solid biomass is a complex phenomenon due to its large varieties and physical structures. Among various systems, fixed bed combustion is the most commonly used technique for thermal conversion of solid biomass. But inadequate knowledge on complex solid conversion processes has limited the development of such combustion system. Numerical modelling of this combustion system has some advantages over experimental analysis. Many important system parameters (e.g. temperature, density, solid fraction) can be estimated inside the entire domain under different working conditions. In this work, a complete numerical model is used for solid conversion processes of biomass combustion in a fixed bed furnace. The combustion system is divided in to solid and gas phase. This model includes several sub models to characterize the solid phase of the combustion with several variables. User defined subroutines are used to introduce solid phase variables in commercial CFD code. Gas phase of combustion is resolved using built-in module of CFD code. Heat transfer model is modified to predict the temperature of solid and gas phases with special radiation heat transfer solution for considering the high absorptivity of the medium. Considering all solid conversion processes the solid phase variables are evaluated. Results obtained are discussed with reference from an experimental burner.

FORMALIZATION OF DIESEL ENGINE OPERATION CONSIDERING THE EVALUATION OF VELOCITY DURING THE COMBUSTION PROCESSES

Directory of Open Access Journals (Sweden)

V. P. Litvinenko

2015-10-01

Full Text Available Purpose. Under modern conditions the applying methods and design models as well as the evaluation of the operational characteristics of diesel engines do not completely take into consideration the specifics of the combustion processes. In part, such situation is characterized by the complexity of considering of varied by its nature processes that haven’t been completely investigated. In this context it is necessary to find the new methods and models which would provide relatively simple solutions through the use of integrated factors based on the analysis of parameters of diesel engines. Methodology. The proposed algorithms for the estimating of the combustion process in the form of volumetric and linear velocities is based on the well-known parameters of power and mean effective pressure and allows to compare the efficiency of their behavior in various versions of diesel engines. Findings. The author specified that the volumetric / linear velocity ratio is characterized by some strength and depends on the geometric dimensions of the cylinder-piston group. Due to the assumptions it has become possible to consider the operation of a diesel engine as a system comprising: 1 the subsystem that provides the possibility of obtaining the thermal energy; 2 the subsystem providing the thermal energy transformation; 3 the subsystem that provides the necessary diesel engine power depending on terms of combustion of air-fuel mixture. Originality. The author of the paper proposed the indices of volumetric and linear combustion velocity of air-fuel mixture in the engine cylinder, that allow to obtain the comparative value in different modifications taking into account the possible choice of optimum ratio. Practical value. The usage of indices of volumetric and linear velocities of the combustion processes in the engine cylinder combined with a mathematical model will simplify the method of diesels calculating. Parametric indices of the mentioned velocities

Intelligent Integration between Human Simulated Intelligence and Expert Control Technology for the Combustion Process of Gas Heating Furnace

Directory of Open Access Journals (Sweden)

Yucheng Liu

2014-01-01

Full Text Available Due to being poor in control quality of the combustion process of gas heating furnace, this paper explored a sort of strong robust control algorithm in order to improve the control quality of the combustion process of gas heating furnace. The paper analyzed the control puzzle in the complex combustion process of gas heating furnace, summarized the cybernetics characteristic of the complex combustion process, researched into control strategy of the uncertainty complex control process, discussed the control model of the complex process, presented a sort of intelligent integration between human-simulated intelligence and expert control technology, and constructed the control algorithm for the combustion process controlling of gas heating furnace. The simulation results showed that the control algorithm proposed in the paper is not only better in dynamic and steady quality of the combustion process, but also obvious in energy saving effect, feasible, and effective in control strategy.

Research into three-component biodiesel fuels combustion process using a single droplet technique

Directory of Open Access Journals (Sweden)

L. Raslavičius

2007-12-01

Full Text Available In order to reduce the engine emission while at same time improving engine efficiency, it is very important to clarify the combustion mechanism. Even if, there are many researches into investigating the mechanism of engine combustion, so that to clarify the relationship between complicated phenomena, it is very difficult to investigate due to the complicated process of both physical and chemical reaction from the start of fuel injection to the end of combustion event. The numerical simulations are based on a detailed vaporization model and detailed chemical kinetics. The influence of different physical parameters like droplet temperature, gas phase temperature, ambient gas pressure and droplet burning velocity on the ignition delay process is investigated using fuel droplet combustion stand. Experimental results about their influence on ignition delay time were presented.

Introduction to Physics and Chemistry of Combustion Explosion, Flame, Detonation

CERN Document Server

Liberman, Michael A

2008-01-01

Most of the material covered in this book deals with the fundamentals of chemistry and physics of key processes and fundamental mechanisms for various combustion and combustion related phenomena in gaseous combustible mixture. It provides the reader with basic knowledge of burning processes and mechanisms of reaction wave propagation. The combustion of a gas mixture (flame, explosion, detonation) is necessarily accompanied by motion of the gas. The process of combustion is therefore not only a chemical phenomenon but also one of gas dynamics. The material selection focuses on the gas phase and

Combustion-Driven Oscillation in Process Heaters

Energy Technology Data Exchange (ETDEWEB)

Seebold, J.G. [Chevron Corporation (Retired), 198 James Avenue, Atherton, CA 94027 (United States)

2005-10-15

At this moment in thousands of process heaters all over the world there are, to borrow a phrase from the late Carl Sagan, 'billions and billions' of Btu/hr beneficially being released entirely free of pulsation. On those few occasions, perhaps a dozen and a half in my career, when I would get the inevitable 'Why me?' call, I have generally responsed with something like, 'Consider yourself lucky, you have a rare scientific curiosity on your hands'. Reflecting on the solutions ultimately found, I'm reminded that many years ago my friend Abbott Putnam shared with me an early AGA (American Gas Association) field-service bulletin that included a prescription for eliminating combustion-driven oscillations in home heating units; viz., 'Drill a hole; if that doesn't work, drill another hole' or words to that effect. Many times have I wished that I still had a copy of that bulletin and in this paper we will have occasion, once again, to reflect upon the value of that advice. In this paper we will discuss an instance that arose in a pioneering installation of a breakthrough development of 'extremely', to distinguish it from 'ultra', low-NOx lean premix burner technology. We will illustrate how, when and under what circumstances combustion-driven oscillation can arise; we will touch on the many alternatives for its elimination that were considered and investigated; and we will discuss three practical alternatives for eliminating combustion-driven oscillations.

Numerical simulation of a liquid droplet combustion experiment focusing on ignition process

International Nuclear Information System (INIS)

Yamaguchi, Akira; Tajima, Yuji

1999-11-01

SPHINCS (Sodium Fire phenomenology IN multi-Cell System) computer program has been developed for the safety analysis of sodium fire accident in a Fast Breeder Reactor. The program can deal with spray combustion and pool surface combustion. In this report the authors investigate a single droplet combustion phenomena focusing on an ignition process. The spray combustion model of SPHINCS is as follows. The liquid droplet-burning rate after ignition is based on the D-square law and a diffusion flame assumption. Before the droplet is ignited, the burning rate is evaluated by mass flux of oxidizer gases. Forced convection effect that skews the sphere shape of the flame zone surrounding a droplet is taken into consideration. It enhances the burning rate. The chemical equilibrium theory is used to determine the resultant fraction of reaction products of Na-O 2 -H 2 O system. It is noted that users have to give an ignition temperature based on empirical evidences. According to this model, it is obvious that a smaller liquid droplet with higher initial temperature tends to burn more easily. What is observed in a recent experiment is that the smallest liquid droplet (2mm diameter) did not ignited of itself and larger droplets (3.7mm and 4.5mm diameter) burnt at 300degC initial temperature. The current model for liquid droplet combustion cannot predict the experimental results. Therefore, in the present study, a surface reaction model has been developed to predict the ignition process. The model has been used to analyze a combustion experiment of a stationary liquid droplet. The authors investigate the validity of the physical modeling of the liquid droplet combustion and surface reaction. It has been found, as the results, that the model can predict the influence of the initial temperature on the temperature lower limit for spontaneous ignition and ignition delay time. Also investigated is the influence of the moisture on the ignition phenomena. From the present study, it has

The Siemens pyrolysis-combustion process; Das Siemens Schwel-Brenn-Verfahren

Energy Technology Data Exchange (ETDEWEB)

Schmitz, D [Siemens - KWU, Offenbach (Germany)

1997-12-31

The market introduction fo the SIEMENS pyrolysis-combustion process is a technical and ecological milestone in thermal waste processing. It bridges the gap between conventional incineration and recycling and is ideally suited for the modern waste management philosophy. The innovative combination of pyrolysis followed by high-temperature combustion produces energy and reusable materials nearly without emissions. (orig/sr) [Deutsch] Die Markteinfuehrung des Schwel-Brenn-Verfahrens hat im Bereich der thermischen Muellentsorgung eine technologische und oekologische Zeitenwende eingeleitet. Es fuegt sich als Bruecke zwischen herkoemmlicher Muellverbrennung und stofflichem Muell-Recyling ideal in das Konzept einer oekologischen Kreislaufwirtschaft. Die innovative Kombination von Muellverschwelung (Pyrolyse) und anschliessender Hochtemperaturverbrennung wandelt den unvermeidbaren Restmuell nahezu rueckstandsfrei in Wertstoffe und Energie um. (orig/SR)

The Siemens pyrolysis-combustion process; Das Siemens Schwel-Brenn-Verfahren

Energy Technology Data Exchange (ETDEWEB)

Schmitz, D. [Siemens - KWU, Offenbach (Germany)

1996-12-31

The market introduction fo the SIEMENS pyrolysis-combustion process is a technical and ecological milestone in thermal waste processing. It bridges the gap between conventional incineration and recycling and is ideally suited for the modern waste management philosophy. The innovative combination of pyrolysis followed by high-temperature combustion produces energy and reusable materials nearly without emissions. (orig/sr) [Deutsch] Die Markteinfuehrung des Schwel-Brenn-Verfahrens hat im Bereich der thermischen Muellentsorgung eine technologische und oekologische Zeitenwende eingeleitet. Es fuegt sich als Bruecke zwischen herkoemmlicher Muellverbrennung und stofflichem Muell-Recyling ideal in das Konzept einer oekologischen Kreislaufwirtschaft. Die innovative Kombination von Muellverschwelung (Pyrolyse) und anschliessender Hochtemperaturverbrennung wandelt den unvermeidbaren Restmuell nahezu rueckstandsfrei in Wertstoffe und Energie um. (orig/SR)

Electron beam processing of combustion flue gases

International Nuclear Information System (INIS)

1987-07-01

This report contains the papers presented at the consultants' meeting on electron beam processing of combustion flue gases. The meeting provided an excellent opportunity for exchanging information and reviewing the current status of technology development. Characteristics of the electron beam processing recognized by the meeting are: capability of simultaneous removals of SO 2 and NO x , safe technology and simplicity of control, dry process without waste water to be treated, cost benefit of electron beam processing compared with conventional technology and the conversion of SO 2 and NO x to a by-product that can be used as agricultural fertilizer. A separate abstract was prepared for each of the 22 papers in this technical report

Ignition and wave processes in combustion of solids

CERN Document Server

Rubtsov, Nickolai M; Alymov, Michail I

2017-01-01

This book focuses on the application of classical combustion theory to ignition and flame propagation in solid-solid and gas-solid systems. It presents experimental investigations in the areas of local ignition, filtration combustion, self-propagating high temperature synthesis and nanopowders protection. The authors highlight analytical formulas used in different areas of combustion in solids and propose an approach based on classical combustion theory. The book attempts to analyze the basic approaches to understanding of solid-solid and solid - gas combustion presented in contemporary literature in a unified approach based on classical combustion theory. .

Synthesis and characterization of CaTiO3 powder by combustion synthesis process

International Nuclear Information System (INIS)

Jung, C. W.; Shin, H. C.; Park, J. Y.; Lee, H. G.; Kim, H. Y.; Hong, K. W.

2000-01-01

Synroc is considered as a one of the most promising candidate for HLW solidification. CaTiO 3 , perovskite, which is a component of Synroc, can immobilize lanthanide and actinides by forming solid solutions. Generally most of the radioactive wastes elements were treated as a nitrate form. Therefore, the combustion process using metal nitrates as reactant materials can be easily applied to immobilize the radioactive waste elements. In this study, the feasibility of preparing fine, single-phase powders of multi-component oxide by a combustion process was investigated. Generally, the powder synthesized by combustion process showed different characteristics depending on the type and amount of fuel. And the spherical CaTiO 3 particles were directly prepared from the aqueous solution by an ultrasonic mist combustion process using an ultrasonic nebulizers as mist generators. The particles prepared with simple spray pyrolysis method using nitrate solution without fuel as precursor solution showed porous and hollow morphology, while the particles prepared with precursor solutions containing fuel showed dense solid morphology. Among various kinds of fuel tested, glycine showed the best result in reaction kinetics and crystalline phase purity

Combustion of lean hydrogen-air mixtures in the connected compartments

International Nuclear Information System (INIS)

Fan Liu; Yoshio Yoshizawa; Akio Miyori; Kenya Kubota

1997-01-01

A study of combustion experiments with premixed lean hydrogen-air mixtures was conducted in a vessel consisting of two compartments connected by a diameter-variable vent. Effects of various parameters (hydrogen concentration, vent diameter and initial pressure) on mechanical loads of the combustion processes including mainly the peak pressures and the rates of pressure rise were investigated. Relation of flow and combustion was approached. Ignition-combustion processes were discussed, and the combustion types were classified into three patterns according to the pressure-time histories and the flow characteristics in main combustion compartment

The Relation between Gas Flow and Combustibility using Actual Engine (Basic Experiment of Gas Flow and Combustibility under Low Load Condition)

OpenAIRE

田坂, 英紀; 泉, 立哉; 木村, 正寿

2003-01-01

Abstract ###Consideration of the global environment problems by exhaust gas is becoming important in recent years. ###Especially about internal combustion engine, social demand has been increasing about low pollution, high ###efficiency and so on. Controlling gas flow in cylinder becomes the key getting good combustion state in ###various driving states. ###The purpose of the research is analysis about the relation between gas flow and combustibility in the cylinder. ###So we measured gas flo...

Fundamental limitations of non-thermal plasma processing for internal combustion engine NOx control

International Nuclear Information System (INIS)

Penetrante, B.M.

1993-01-01

This paper discusses the physics and chemistry of non-thermal plasma processing for post-combustion NO x control in internal combustion engines. A comparison of electron beam and electrical discharge processing is made regarding their power consumption, radical production, NO x removal mechanisms, and by product formation. Can non-thermal deNO x operate efficiently without additives or catalysts? How much electrical power does it cost to operate? What are the by-products of the process? This paper addresses these fundamental issues based on an analysis of the electron-molecule processes and chemical kinetics

Analysis of briquetting process of sewage sludge with coal to combustion process

Directory of Open Access Journals (Sweden)

Kosturkiewicz Bogdan

2016-01-01

Full Text Available Energy recovery from sewage sludge can be achieved by several thermal technologies, but before those processes sewage sludge requires special pretreatment. The paper presents the investigation of the sewage sludge with coal briquettes as a fuel for combustion process. Research is conducted at Department of Manufacturing Systems and Department of Thermal Engineering and Environmental Protection, AGH University of Science and Technology to develop a technology of briquette preparation. The obtained results showed possibility of briquetting of municipal sewage sludge with coal in roll presses, equipped with asymmetric thickening gravity feed system. The following properties were determined for the obtained briquettes: density, drop strength and compressive strength. Based on physical and chemical analysis of prepared briquettes it was confirmed that briquettes have good fuel properties to combustion process. Thermal behaviour of studied sewage sludge and prepared mixture was investigated by thermogravimetric analysis (TG. For the thermo gravimetric analysis (TG the samples were heated in an alumina crucible from an ambient temperature up to 1000 °C at a constant rates: 10 °C/min, 40 °C/min and 100 °C/min in a 40 ml/min flow of air.

Specifics of phytomass combustion in small experimental device

Science.gov (United States)

Lenhard, Richard; Mičieta, Jozef; Jandačka, Jozef; Gavlas, Stanislav

2015-05-01

A wood pellet combustion carries out with high efficiency and comfort in modern pellet boilers. These facts help to increase the amount of installed pellet boilers in households. The combustion process quality depends besides the combustion conditions also on the fuel quality. The wood pellets, which don`t contain the bark and branches represent the highest quality. Because of growing pellet demand, an herbal biomass (phytomass), which is usually an agricultural by-product becomes economically attractive for pellet production. Although the phytomass has the net calorific value relatively slightly lower than the wood biomass, it is often significantly worse in view of the combustion process and an emission production. The combustion of phytomass pellets causes various difficulties in small heat sources, mainly due to a sintering of fuel residues. We want to avoid the ash sintering by a lowering of temperature in the combustion chamber below the ash sintering temperature of phytomass via the modification of a burner design. For research of the phytomass combustion process in the small boilers is constructed the experimental combustion device. There will investigate the impact of cooling intensity of the combustion chamber on the combustion process and emissions. Arising specific requirements from the measurement will be the basis for the design of the pellet burner and for the setting of operating parameters to the trouble-free phytomass combustion was guaranteed.

Specifics of phytomass combustion in small experimental device

Directory of Open Access Journals (Sweden)

Lenhard Richard

2015-01-01

Full Text Available A wood pellet combustion carries out with high efficiency and comfort in modern pellet boilers. These facts help to increase the amount of installed pellet boilers in households. The combustion process quality depends besides the combustion conditions also on the fuel quality. The wood pellets, which don`t contain the bark and branches represent the highest quality. Because of growing pellet demand, an herbal biomass (phytomass, which is usually an agricultural by-product becomes economically attractive for pellet production. Although the phytomass has the net calorific value relatively slightly lower than the wood biomass, it is often significantly worse in view of the combustion process and an emission production. The combustion of phytomass pellets causes various difficulties in small heat sources, mainly due to a sintering of fuel residues. We want to avoid the ash sintering by a lowering of temperature in the combustion chamber below the ash sintering temperature of phytomass via the modification of a burner design. For research of the phytomass combustion process in the small boilers is constructed the experimental combustion device. There will investigate the impact of cooling intensity of the combustion chamber on the combustion process and emissions. Arising specific requirements from the measurement will be the basis for the design of the pellet burner and for the setting of operating parameters to the trouble-free phytomass combustion was guaranteed.

Investigations of combustion process in combined cooker-boiler fired on solid fuels

Directory of Open Access Journals (Sweden)

Stojiljković Dragoslava D.

2006-01-01

Full Text Available The aim of the investigation was to make some reconstructions on the existing stove used for cooking and baking and to obtain the combined cooker-boiler which will fulfill the demands of European standard EN 12815. Implementation of modern scientific achievements in the field of combustion on stoves and furnaces fired on solid fuels was used. During the investigations four various constructions were made with different fresh air inlet and secondary air supply with the intention to obtain more complete combustion with increased efficiency and reduced CO emission. Three different fuels were used: firewood, coal, and wood briquette. A numerous parameters were measured: fuel weight changes during the combustion process, temperature of inlet and outlet water, flue gas composition (O2, CO, SO2, CO2, NOx, flue gas temperature, ash quantity etc. The result of the investigations is the stove with the efficiency of more than 75% - boiler Class 1 (according EN 12815 and CO emission of about 1% v/v. The results obtained during the measurements were used as parameters for modeling of combustion process. .

Modelling of a combustion process for the incineration of municipal solid waste

International Nuclear Information System (INIS)

Rohyiza Ba'an Sivapalan Kathiravale Mohamad Puad Abu Muhd Noor Muhd Yunus

2005-01-01

Municipal Solid Waste (MSW) in Malaysia is increasing rapidly with increase in the population and economic growth. Landfill capacity required to accommodate the generated waste is anticipated to exceed 20,000 tons per day by year 2020. The current management system of solely depending on landfill disposal is inadequate and calls for a more environmentally friendly management system, which include the prospects of an eco park. To understand the combustion process, the development of mathematical model based on waste characteristic is required. Hence this paper will present the mathematical model developed to predict the mass and heat balance for MSW combustion process. This results of this mathematical model will be compared against the actual combustion of MSW in Thermal Oxidation Plant, so that the accuracy of the developed model can be determined accordingly. (Author)

Low NOx combustion technologies for high-temperature natural gas combustion

International Nuclear Information System (INIS)

Flamme, Michael

1999-01-01

Because of the high process temperature which is required for some processes like glass melting and the high temperature to which the combustion air is preheated, NOx emission are extremely high. Even at these high temperatures, NOx emissions could be reduced drastically by using advanced combustion techniques such as staged combustion or flame-less oxidation, as experimental work has shown. In the case of oxy-fuel combustion, the NOx emission are also very high if conventional burners are used. The new combustion techniques achieve similar NOx reductions. (author)

[Real time diagnostics of instantaneous temperature of combustion and explosion process by modern spectroscopy].

Science.gov (United States)

Zhou, Xue-tie; Wang, Jun-de; Li, Yan; Liu, Da-bing

2003-04-01

The combustion temperature is one of the important parameters to express flame combustion and explosion characteristics. It will effectively guide the design and manufacture of new model explosives, industrial explosive materials, and weapons. The recent developments and applications of real time diagnostics of instantaneous temperature of combustion and explosion processes by modern spectroscopic methods, such as atomic absorption-emission method, atomic emission two-line spectroscopy, atomic emission multiline spectroscopy, molecular rotation-vibration spectroscopy, coherent anti-stokes Raman scattering (CARS) and plane laser-induced fluorescence (PLIF), were reviewed in this paper. The maximum time resolution of atomic absorption-emission method is 25 microseconds. The time resolution of atomic emission two-line spectroscopy can reach 0.1 microsecond. These two methods can completely suit the need of real time and instantaneous temperature diagnostics of violent explosion and flame combustion. Other methods will also provide new effective research methods for the processes and characteristics of combustion, flame and explosion.

Model predictive control as a tool for improving the process operation of MSW combustion plants

International Nuclear Information System (INIS)

Leskens, M.; Kessel, L.B.M. van; Bosgra, O.H.

2005-01-01

In this paper a feasibility study is presented on the application of the advanced control strategy called model predictive control (MPC) as a tool for obtaining improved process operation performance for municipal solid waste (MSW) combustion plants. The paper starts with a discussion of the operational objectives and control of such plants, from which a motivation follows for applying MPC to them. This is followed by a discussion on the basic idea behind this advanced control strategy. After that, an MPC-based combustion control system is proposed aimed at tackling a typical MSW combustion control problem and, using this proposed control system, an assessment is made of the improvement in performance that an MPC-based MSW combustion control system can provide in comparison to conventional MSW combustion control systems. This assessment is based on simulations using an experimentally obtained process and disturbance model of a real-life large-scale MSW combustion plant

Artificial intelligence for the modeling and control of combustion processes: a review

Energy Technology Data Exchange (ETDEWEB)

Kalogirou, S.A. [Higher Technical Inst., Nicosia, Cyprus (Greece). Dept. of Mechanical Engineering

2003-07-01

Artificial intelligence (AI) systems are widely accepted as a technology offering an alternative way to tackle complex and ill-defined problems. They can learn from examples, are fault tolerant in the sense that they are able to handle noisy and incomplete data, are able to deal with non-linear problems, and once trained can perform prediction and generalization at high speed. They have been used in diverse applications in control, robotics, pattern recognition, forecasting, medicine, power systems, manufacturing, optimization, signal processing, and social/psychological sciences. They are particularly useful in system modeling such as in implementing complex mappings and system identification. Al systems comprise areas like, expert systems, artificial neural networks, genetic algorithms, fuzzy logic and various hybrid systems, which combine two or more techniques. The major objective of this paper is to illustrate how Al techniques might play an important role in modeling and prediction of the performance and control of combustion process. The paper outlines an understanding of how AI systems operate by way of presenting a number of problems in the different disciplines of combustion engineering. The various applications of AI are presented in a thematic rather than a chronological or any other order. Problems presented include two main areas: combustion systems and internal combustion (IC) engines. Combustion systems include boilers, furnaces and incinerators modeling and emissions prediction, whereas, IC engines include diesel and spark ignition engines and gas engines modeling and control. Results presented in this paper, are testimony to the potential of Al as a design tool in many areas of combustion engineering. (author)

PCDD/PCDF reduction by the co-combustion process.

Science.gov (United States)

Lee, Vinci K C; Cheung, Wai-Hung; McKay, Gordon

2008-01-01

A novel process, termed the co-combustion process, has been developed and designed to utilise the thermal treatment of municipal solid waste (MSW) in cement clinker production and reduce PCDD/PCDF emissions. To test the conceptual design; detailed engineering design of the process and equipment was performed and a pilot plant was constructed to treat up to 40 tonnes MSW per day. The novel process features included several units external to the main traditional cement rotary kiln: an external calcinations unit in which the hot gas calcined the limestone thus making significant energy savings for this chemical reaction; the lime generated was used in a second chamber to act as a giant acid gas scrubber to remove SOx and particularly HCl (a source of chloride); an external rotary kiln and secondary combustion unit capable of producing a hot gas at 1200 degrees C; a gas cooler to simulate a boiler turbogenerator set for electricity generation; the incorporation of some of the bottom ash, calcined lime and dust collector solids into the cement clinker. A PCDD/PCDF inventory has been completed for the entire process and measured PCDD/PCDF emissions were 0.001 ng I-TEQ/Nm(3) on average which is 1% of the best practical means [Hong Kong Environmental Protection Department, 2001. A guidance note on the best practicable means for incinerators (municipal waste incineration), BPM12/1] MSW incineration emission limit values.

Analysis of selected problems of biomass combustion process in batch boilers - experimental and numerical approach

Science.gov (United States)

Szubel, Mateusz

2016-03-01

It is possible to list numerous groups of heating units that are used in households, such as boilers, stoves and units used as supporting heat sources, namely fireplaces. In each case, however, the same operational problems may be evoked [1]. To understand the causes of energy losses in a boiler system, a proper definition of significant elements of the unit's heat balance is necessary. In the group of energy losses, the flue gas loss and the incomplete combustion loss are the most significant factors. The problem with the loss resulting from incomplete combustion, which is related to the presence of combustible substances in the exhaust, is especially significant in case of biomass boilers [2, 3]. The paper presents results of the research and the optimisation of the biomass combustion process in the 180 kW batch boiler. The studies described have been focused on the reduction of the pollutants emission, which was primarily realised by the modifications of the air feeding system. Results of the experiments and the CFD simulations have been compared and discussed. Both in case of the model as well as the experiment, positive influence of the modifications on the emission have been observed.

Application of LES for Analysis of Unsteady Effects on Combustion Processes and Misfires in DISI Engine

Directory of Open Access Journals (Sweden)

Goryntsev D.

2013-10-01

Full Text Available Cycle-to-cycle variations of combustion processes strongly affect the emissions, specific fuel consumption and work output. Internal combustion engines such as Direct Injection Spark-Ignition (DISI are very sensitive to the cyclic fluctuations of the flow, mixing and combustion processes. Multi-cycle Large Eddy Simulation (LES analysis has been used in order to characterize unsteady effects of combustion processes and misfires in realistic DISI engine. A qualitative analysis of the intensity of cyclic variations of in-cylinder pressure, temperature and fuel mass fraction is presented. The effect of ignition probability and analysis of misfires are pointed out. Finally, the fuel history effects along with the effect of residual gas on in-cylinder pressure and temperature as well as misfires are discussed.

Assessment of Literature Related to Combustion Appliance Venting Systems

Energy Technology Data Exchange (ETDEWEB)

Rapp, V. H.; Less, B. D.; Singer, B. C.; Stratton, J. C.; Wray, C. P.

2015-02-01

In many residential building retrofit programs, air tightening to increase energy efficiency is often constrained by safety concerns with naturally vented combustion appliances. Tighter residential buildings more readily depressurize when exhaust equipment is operated, making combustion appliances more prone to backdraft or spill combustion exhaust into the living space. Several measures, such as installation guidelines, vent sizing codes, and combustion safety diagnostics, are in place with the intent to prevent backdrafting and combustion spillage, but the diagnostics conflict and the risk mitigation objective is inconsistent. This literature review summarizes the metrics and diagnostics used to assess combustion safety, documents their technical basis, and investigates their risk mitigations. It compiles information from the following: codes for combustion appliance venting and installation; standards and guidelines for combustion safety diagnostics; research evaluating combustion safety diagnostics; research investigating wind effects on building depressurization and venting; and software for simulating vent system performance.

Pulsating combustion - Combustion characteristics and reduction of emissions

Energy Technology Data Exchange (ETDEWEB)

Lindholm, Annika

1999-11-01

In the search for high efficiency combustion systems pulsating combustion has been identified as one of the technologies that potentially can meet the objectives of clean combustion and good fuel economy. Pulsating combustion offers low emissions of pollutants, high heat transfer and efficient combustion. Although it is an old technology, the interest in pulsating combustion has been renewed in recent years, due to its unique features. Various applications of pulsating combustion can be found, mainly as drying and heating devices, of which the latter also have had commercial success. It is, however, in the design process of a pulse combustor, difficult to predict the operating frequency, the heat release etc., due to the lack of a well founded theory of the phenomenon. Research concerning control over the combustion process is essential for developing high efficiency pulse combustors with low emissions. Natural gas fired Helmholtz type pulse combustors have been the experimental objects of this study. In order to investigate the interaction between the fluid dynamics and the chemistry in pulse combustors, laser based measuring techniques as well as other conventional measuring techniques have been used. The experimental results shows the possibilities to control the combustion characteristics of pulsating combustion. It is shown that the time scales in the large vortices created at the inlet to the combustion chamber are very important for the operation of the pulse combustor. By increasing/decreasing the time scale for the large scale mixing the timing of the heat release is changed and the operating characteristics of the pulse combustor changes. Three different means for NO{sub x} reduction in Helmholtz type pulse combustors have been investigated. These include exhaust gas recirculation, alteration of air/fuel ratio and changed inlet geometry in the combustion chamber. All used methods achieved less than 10 ppm NO{sub x} emitted (referred to stoichiometric

Optimization of combustion chamber geometry for stoichiometric diesel combustion using a micro genetic algorithm

Energy Technology Data Exchange (ETDEWEB)

Park, Sung Wook

2010-11-15

This paper describes the optimization of combustion chamber geometry and engine operating conditions for stoichiometric diesel combustion, targeting lower gross indicated specific fuel consumption. The KIVA code, coupled with a micro genetic algorithm population of nine for each generation was used. The optimization variables were composed of ten variables related to the combustion chamber geometry and engine operating conditions. In addition, an auto mesh generator was developed for generating various kinds of combustion chambers, such as open-crater, re-entrant, deep, and shallow types. In addition, the computational models were validated against the experimental results for a stoichiometric process in terms of the combustion pressure history and emissions. Through the preset optimization, a 35% improvement in the gross indicated that specific fuel consumption was achieved. In addition, the optimization results showed that the optimum engine operating conditions employed a premixed charge compression ignition combustion regime with early injection and a narrow spray included angle. Furthermore, a higher boost pressure was used to prevent fuel film formation. (author)

Artificial intelligence for the modeling and control of combustion processes: a review

Energy Technology Data Exchange (ETDEWEB)

Soteris A. Kalogirou, [Higher Technical Institute, Nicosia (Cyprus). Department of Mechanical Engineering

2003-07-01

Artificial intelligence (AI) systems are widely accepted as a technology offering an alternative way to tackle complex and ill-defined problems. They can learn from examples, are fault tolerant in the sense that they are able to handle noisy and incomplete data, are able to deal with non-linear problems, and once trained can perform prediction and generalization at high speed. They have been used in diverse applications in control, robotics, pattern recognition, forecasting, medicine, power systems, manufacturing, optimization, signal processing, and social/psychological sciences. They are particularly useful in system modeling such as in implementing complex mappings and system identification. AI systems comprise areas like, expert systems, artificial neural networks, genetic algorithms, fuzzy logic and various hybrid systems, which combine two or more techniques. The major objective of this paper is to illustrate how AI techniques might play an important role in modeling and prediction of the performance and control of combustion process. The paper outlines an understanding of how AI systems operate by way of presenting a number of problems in the different disciplines of combustion engineering. The various applications of AI are presented in a thematic rather than a chronological or any other order. Problems presented include two main areas: combustion systems and internal combustion (IC) engines. Combustion systems include boilers, furnaces and incinerators modeling and emissions prediction, whereas, IC engines include diesel and spark ignition engines and gas engines modeling and control. Results presented in this paper, are testimony to the potential of AI as a design tool in many areas of combustion engineering. 109 refs., 31 figs., 11 tabs.

CFD modeling of combustion processes using KIVA3V Code with partially stirred reactor model for turbulence-combustion interactions

International Nuclear Information System (INIS)

Jarnicki, R.; Sobiesiak, A.

2002-01-01

In order to solve the averaged conservation equations for turbulent reacting flow one is faced with a task of specifying the averaged chemical reaction rate. This is due to turbulence influence on the mean reaction rates that appear in the species concentration Reynolds-averaged equation. In order to investigate the Partially Stirred Reactor (PaSR) combustion model capabilities, a CFD modeling using KIVA3V Code with the PaSR model of two very different combustion processes, was performed. Experimental results were compared with modeling

Robust Low Cost Liquid Rocket Combustion Chamber by Advanced Vacuum Plasma Process

Science.gov (United States)

Holmes, Richard; Elam, Sandra; Ellis, David L.; McKechnie, Timothy; Hickman, Robert; Rose, M. Franklin (Technical Monitor)

2001-01-01

Next-generation, regeneratively cooled rocket engines will require materials that can withstand high temperatures while retaining high thermal conductivity. Fabrication techniques must be cost efficient so that engine components can be manufactured within the constraints of shrinking budgets. Three technologies have been combined to produce an advanced liquid rocket engine combustion chamber at NASA-Marshall Space Flight Center (MSFC) using relatively low-cost, vacuum-plasma-spray (VPS) techniques. Copper alloy NARloy-Z was replaced with a new high performance Cu-8Cr-4Nb alloy developed by NASA-Glenn Research Center (GRC), which possesses excellent high-temperature strength, creep resistance, and low cycle fatigue behavior combined with exceptional thermal stability. Functional gradient technology, developed building composite cartridges for space furnaces was incorporated to add oxidation resistant and thermal barrier coatings as an integral part of the hot wall of the liner during the VPS process. NiCrAlY, utilized to produce durable protective coating for the space shuttle high pressure fuel turbopump (BPFTP) turbine blades, was used as the functional gradient material coating (FGM). The FGM not only serves as a protection from oxidation or blanching, the main cause of engine failure, but also serves as a thermal barrier because of its lower thermal conductivity, reducing the temperature of the combustion liner 200 F, from 1000 F to 800 F producing longer life. The objective of this program was to develop and demonstrate the technology to fabricate high-performance, robust, inexpensive combustion chambers for advanced propulsion systems (such as Lockheed-Martin's VentureStar and NASA's Reusable Launch Vehicle, RLV) using the low-cost VPS process. VPS formed combustion chamber test articles have been formed with the FGM hot wall built in and hot fire tested, demonstrating for the first time a coating that will remain intact through the hot firing test, and with

Improved correlations of hydrogen content versus combustion performance related properties of aviation turbine fuels

Energy Technology Data Exchange (ETDEWEB)

Nagpal, J.M.; Sharma, R.L.; Sagu, M.L.; Tiwari, G.B. (Indian Institute of Petroleum, Dehradun (India))

1994-01-01

In recent years the hydrogen content of Aviation Fuels has generated considerable interest. Various investigators have suggested correlation of hydrogen content with combustion related properties of aviation turbine fuel (ATF). A suitable threshold value of hydrogen content 13.8 wt% is being considered as a waiver of specifications such as specific energy, aniline gravity product, smoke point, aromatic content, naphthalenes and luminometer number. In the present paper relationship between the hydrogen content and combustion related properties has been examined and improved correlations of hydrogen content with several combustion related properties have been developed by incorporating a characterization factor in the equations. The supporting threshold value of a hydrogen content of 13.8wt% is verified with 25 data points for waiving of combustion properties such as specific energy, aniline gravity product, smoke point and aromatic content from aviation turbine fuel. 6 refs., 12 figs., 2 tabs.

LES and RANS modeling of pulverized coal combustion in swirl burner for air and oxy-combustion technologies

International Nuclear Information System (INIS)

Warzecha, Piotr; Boguslawski, Andrzej

2014-01-01

Combustion of pulverized coal in oxy-combustion technology is one of the effective ways to reduce the emission of greenhouse gases into the atmosphere. The process of transition from conventional combustion in air to the oxy-combustion technology, however, requires a thorough investigations of the phenomena occurring during the combustion process, that can be greatly supported by numerical modeling. The paper presents the results of numerical simulations of pulverized coal combustion process in swirl burner using RANS (Reynolds-averaged Navier–Stokes equations) and LES (large Eddy simulation) methods for turbulent flow. Numerical simulations have been performed for the oxyfuel test facility located at the Institute of Heat and Mass Transfer at RWTH Aachen University. Detailed analysis of the flow field inside the combustion chamber for cold flow and for the flow with combustion using different numerical methods for turbulent flows have been done. Comparison of the air and oxy-coal combustion process for pulverized coal shows significant differences in temperature, especially close to the burner exit. Additionally the influence of the combustion model on the results has been shown for oxy-combustion test case. - Highlights: • Oxy-coal combustion has been modeled for test facility operating at low oxygen ratio. • Coal combustion process has been modeled with simplified combustion models. • Comparison of oxy and air combustion process of pulverized coal has been done. • RANS (Reynolds-averaged Navier–Stokes equations) and LES (large Eddy simulation) results for pulverized coal combustion process have been compared

Molten salt combustion of radioactive wastes

International Nuclear Information System (INIS)

Grantham, L.F.; McKenzie, D.E.; Richards, W.L.; Oldenkamp, R.D.

1976-01-01

The Atomics International Molten Salt Combustion Process reduces the weight and volume of combustible β-γ contaminated transuranic waste by utilizing air in a molten salt medium to combust organic materials, to trap particulates, and to react chemically with any acidic gases produced during combustion. Typically, incomplete combustion products such as hydrocarbons and carbon monoxide are below detection limits (i.e., 3 ) is directly related to the sodium chloride vapor pressure of the melt; >80% of the particulate is sodium chloride. Essentially all metal oxides (combustion ash) are retained in the melt, e.g., >99.9% of the plutonium, >99.6% of the europium, and >99.9% of the ruthenium are retained in the melt. Both bench-scale radioactive and pilot scale (50 kg/hr) nonradioactive combustion tests have been completed with essentially the same results. Design of three combustors for industrial applications are underway

Effects of Fuel Quantity on Soot Formation Process for Biomass-Based Renewable Diesel Fuel Combustion

KAUST Repository

Jing, Wei; Wu, Zengyang; Roberts, William L.; Fang, Tiegang

2016-01-01

Soot formation process was investigated for biomass-based renewable diesel fuel, such as biomass to liquid (BTL), and conventional diesel combustion under varied fuel quantities injected into a constant volume combustion chamber. Soot measurement

Analysis of selected problems of biomass combustion process in batch boilers - experimental and numerical approach

Directory of Open Access Journals (Sweden)

Szubel Mateusz

2016-01-01

Full Text Available It is possible to list numerous groups of heating units that are used in households, such as boilers, stoves and units used as supporting heat sources, namely fireplaces. In each case, however, the same operational problems may be evoked [1]. To understand the causes of energy losses in a boiler system, a proper definition of significant elements of the unit’s heat balance is necessary. In the group of energy losses, the flue gas loss and the incomplete combustion loss are the most significant factors. The problem with the loss resulting from incomplete combustion, which is related to the presence of combustible substances in the exhaust, is especially significant in case of biomass boilers [2, 3]. The paper presents results of the research and the optimisation of the biomass combustion process in the 180 kW batch boiler. The studies described have been focused on the reduction of the pollutants emission, which was primarily realised by the modifications of the air feeding system. Results of the experiments and the CFD simulations have been compared and discussed. Both in case of the model as well as the experiment, positive influence of the modifications on the emission have been observed.

Hydrothermal processing of radioactive combustible waste

International Nuclear Information System (INIS)

Worl, L.A.; Buelow, S.J.; Harradine, D.; Le, L.; Padilla, D.D.; Roberts, J.H.

1998-01-01

Hydrothermal processing has been demonstrated for the treatment of radioactive combustible materials for the US Department of Energy. A hydrothermal processing system was designed, built and tested for operation in a plutonium glovebox. Presented here are results from the study of the hydrothermal oxidation of plutonium and americium contaminated organic wastes. Experiments show the destruction of the organic component to CO 2 and H 2 O, with 30 wt.% H 2 O 2 as an oxidant, at 540 C and 46.2 MPa. The majority of the actinide component forms insoluble products that are easily separated by filtration. A titanium liner in the reactor and heat exchanger provide corrosion resistance for the oxidation of chlorinated organics. The treatment of solid material is accomplished by particle size reduction and the addition of a viscosity enhancing agent to generate a homogeneous pumpable mixture

Straw combustion on slow-moving grates

DEFF Research Database (Denmark)

Kær, Søren Knudsen

2005-01-01

Combustion of straw in grate-based boilers is often associated with high emission levels and relatively poor fuel burnout. A numerical grate combustion model was developed to assist in improving the combustion performance of these boilers. The model is based on a one-dimensional ‘‘walking......-column’’ approach and includes the energy equations for both the fuel and the gas accounting for heat transfer between the two phases. The model gives important insight into the combustion process and provides inlet conditions for a computational fluid dynamics analysis of the freeboard. The model predictions...... indicate the existence of two distinct combustion modes. Combustion air temperature and mass flow-rate are the two parameters determining the mode. There is a significant difference in reaction rates (ignition velocity) and temperature levels between the two modes. Model predictions were compared...

Mass spectrometric analysis and aerodynamic properties of various types of combustion-related aerosol particles

Science.gov (United States)

Schneider, J.; Weimer, S.; Drewnick, F.; Borrmann, S.; Helas, G.; Gwaze, P.; Schmid, O.; Andreae, M. O.; Kirchner, U.

2006-12-01

Various types of combustion-related particles in the size range between 100 and 850 nm were analyzed with an aerosol mass spectrometer and a differential mobility analyzer. The measurements were performed with particles originating from biomass burning, diesel engine exhaust, laboratory combustion of diesel fuel and gasoline, as well as from spark soot generation. Physical and morphological parameters like fractal dimension, effective density, bulk density and dynamic shape factor were derived or at least approximated from the measurements of electrical mobility diameter and vacuum aerodynamic diameter. The relative intensities of the mass peaks in the mass spectra obtained from particles generated by a commercial diesel passenger car, by diesel combustion in a laboratory burner, and by evaporating and re-condensing lubrication oil were found to be very similar. The mass spectra from biomass burning particles show signatures identified as organic compounds like levoglucosan but also others which are yet unidentified. The aerodynamic behavior yielded a fractal dimension (Df) of 2.09 +/- 0.06 for biomass burning particles from the combustion of dry beech sticks, but showed values around three, and hence more compact particle morphologies, for particles from combustion of more natural oak. Scanning electron microscope images confirmed the finding that the beech combustion particles were fractal-like aggregates, while the oak combustion particles displayed a much more compact shape. For particles from laboratory combusted diesel fuel, a Df value of 2.35 was found, for spark soot particles, Df [approximate] 2.10. The aerodynamic properties of fractal-like particles from dry beech wood combustion indicate an aerodynamic shape factor [chi] that increases with electrical mobility diameter, and a bulk density of 1.92 g cm-3. An upper limit of [chi] [approximate] 1.2 was inferred for the shape factor of the more compact particles from oak combustion.

Hydrothermal processing of transuranic contaminated combustible waste

International Nuclear Information System (INIS)

Buelow, S.J.; Worl, L.; Harradine, D.; Padilla, D.; McInroy, R.

2001-01-01

Experiments at Los Alamos National Laboratory have demonstrated the usefulness of hydrothermal processing for the disposal of a wide variety of transuranic contaminated combustible wastes. This paper provides an overview of the implementation and performance of hydrothermal treatment for concentrated salt solutions, explosives, propellants, organic solvents, halogenated solvents, and laboratory trash, such as paper and plastics. Reaction conditions vary from near ambient temperatures and pressure to over 1000degC and 100 MPa pressure. Studies involving both radioactive and non-radioactive waste simulants are discussed. (author)

Combustion

CERN Document Server

Glassman, Irvin

1997-01-01

This Third Edition of Glassman's classic text clearly defines the role of chemistry, physics, and fluid mechanics as applied to the complex topic of combustion. Glassman's insightful introductory text emphasizes underlying physical and chemical principles, and encompasses engine technology, fire safety, materials synthesis, detonation phenomena, hydrocarbon fuel oxidation mechanisms, and environmental considerations. Combustion has been rewritten to integrate the text, figures, and appendixes, detailing available combustion codes, making it not only an excellent introductory text but also an important reference source for professionals in the field. Key Features * Explains complex combustion phenomena with physical insight rather than extensive mathematics * Clarifies postulates in the text using extensive computational results in figures * Lists modern combustion programs indicating usage and availability * Relates combustion concepts to practical applications.

Measurements of gas parameters in plasma-assisted supersonic combustion processes using diode laser spectroscopy

International Nuclear Information System (INIS)

Bolshov, Mikhail A; Kuritsyn, Yu A; Liger, V V; Mironenko, V R; Leonov, S B; Yarantsev, D A

2009-01-01

We report a procedure for temperature and water vapour concentration measurements in an unsteady-state combustion zone using diode laser absorption spectroscopy. The procedure involves measurements of the absorption spectrum of water molecules around 1.39 μm. It has been used to determine hydrogen combustion parameters in M = 2 gas flows in the test section of a supersonic wind tunnel. The relatively high intensities of the absorption lines used have enabled direct absorption measurements. We describe a differential technique for measurements of transient absorption spectra, the procedure we used for primary data processing and approaches for determining the gas temperature and H 2 O concentration in the probed zone. The measured absorption spectra are fitted with spectra simulated using parameters from spectroscopic databases. The combustion-time-averaged (∼50 ms) gas temperature and water vapour partial pressure in the hot wake region are determined to be 1050 K and 21 Torr, respectively. The large signal-to-noise ratio in our measurements allowed us to assess the temporal behaviour of these parameters. The accuracy in our temperature measurements in the probed zone is ∼40 K. (laser applications and other topics in quantum electronics)

ANALYSIS OF INTERNAL COMBUSTION ENGINE WITH A NEW CONCEPT OF POROUS MEDIUM COMBUSTION FOR THE FUTURE CLEAN ENGINE

Directory of Open Access Journals (Sweden)

Ashok A Dhale

2010-01-01

Full Text Available At present, the emissions of internal combustion engine can only be improved by catalytic treatments of the exhaust gases. Such treatments, however, result in high costs and relatively low conversion efficiency. This suggests that a new combustion technique should be developed to yield improved primary combustion processes inside the engine with drastically reduced exhaust gas emissions. To fulfill all requirements, Dr. Franz Drust has proposed a new combustion concept to perform homogenous combustion in internal combustion engines. This concept used the porous medium combustion technique and is called "PM-engine". It is shown that the PM combustion technique can be applied to internal combustion engines. Theoretical considerations are presented for internal combustion engines, indicating that an overall improvement in thermal efficiency can be achieved for the PM-engine. This is explained and general performance of the new PM-engines is demonstrated for a single cylinder, water cooled, direct injection diesel engine. Verification of experiments at primary stage is described that were carried out as a part of the present study.

Spray-combustion process characterization in a common rail diesel engine fuelled with butanol-diesel blends by conventional methods and optical diagnostics

Directory of Open Access Journals (Sweden)

Simona Silvia Merola

2014-04-01

Full Text Available The target of a sustainable mobility has led to investigate advanced combustion modes and fuels technologies. On the other side, the increasing global energy demand and the decreasing fossil-energy resources are enhancing the interest in the use of renewable alternative fuels for compression ignition engines with the target of near-zero emission levels. Although performance and emissions of alternative-fuel within light-duty diesel engines have been extensively investigated, results of fuel chemical composition impact on combustion by integrated optical methodologies are lacking. In order to meet this challenge, one of the main objectives of the research efforts is to characterize the combustion and species evolution. In this investigation, conventional tests and optical diagnostics were employed to enhance the comprehension of the combustion process and chemical markers in a common rail compression ignition engine powered by butanol-diesel blends. The investigation was focused on the effect of the injection strategy and blend composition on in-cylinder spray combustion and soot formation, through UV-visible digital imaging and natural emission spectroscopy. Experiments were performed in an optically accessible single cylinder high swirl compression ignition engine, equipped with a common rail multi-jets injection system. UV-visible emission spectroscopy was used to follow the evolution of the combustion process chemical markers. Spectral features of OH were identified and followed during the spray combustion process examining different pilot-main dwell timings. Soot spectral evidence in the visible wavelength range was correlated to soot engine out emissions. In this work, conventional and optical data related to diesel fuel blended with 40 % of n-butanol will be presented.

Advanced Diagnostics in Oxy-Fuel Combustion Processes

DEFF Research Database (Denmark)

Brix, Jacob; Toftegaard, Maja Bøg; Clausen, Sønnik

This report sums up the findings in PSO-project 010069, “Advanced Diagnostics in Oxy- Fuel Combustion Processes”. Three areas of optic diagnostics are covered in this work: - FTIR measurements in a 30 kW swirl burner. - IR measurements in a 30 kW swirl burner. - IR measurements in a laboratory...... technique was an invaluable tool in the discussion of data obtained by gas analysis, and it allowed for estimation of combustion times in O2/CO2 where the high CO2 concentration prevents the use of the carbon mass balance for that purpose. During the project the data have been presented at a conference......, formed the basis of a publication and it is part of two PhD dissertations. The name of the conference the journal and the dissertations are listed below. - Joint Meeting of the Scandinavian-Nordic and French Sections of the Combustion Institute, Combustion of Char Particles under Oxy-Fuel Conditions...

Influence of injector technology on injection and combustion development - Part 2: Combustion analysis

Energy Technology Data Exchange (ETDEWEB)

Payri, R.; Salvador, F.J.; Gimeno, J.; Morena, J. de la [CMT-Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, E-46022 (Spain)

2011-04-15

The influence of injection technology on the fuel-air mixing process and the combustion development are analyzed by means of visualization techniques. For this purpose, two injectors (one solenoid and one piezoelectric) are characterized using an optical accessible two stroke engine. Visualization of liquid penetration has allowed the measurement of the stabilized liquid length, which is related with the efficiency of fuel-air mixing process. A theoretical derivation is used in order to relate this liquid length with chamber conditions, as well as to make a temporal analysis of these phenomena. After this, natural flame emission and chemiluminescence techniques are carried out. These results indicate that the piezoelectric system has a more efficient fuel-air mixing and combustion, reducing the characteristic times as well as soot formation. Finally, a correlation for the ignition delay of the two systems is obtained. (author)

Sandia Combustion Research: Technical review

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-07-01

This report contains reports from research programs conducted at the Sandia Combustion Research Facility. Research is presented under the following topics: laser based diagnostics; combustion chemistry; reacting flow; combustion in engines and commercial burners; coal combustion; and industrial processing. Individual projects were processed separately for entry onto the DOE databases.

Effects of pressure fluctuations on the combustion process in turbulent premixed flames

Science.gov (United States)

Beardsell, Guillaume; Lapointe, Simon; Blanquart, Guillaume

2016-11-01

The need for a thorough understanding of turbulence-combustion interactions in compressible flows is driven by recent technological developments in propulsion as well as renewed interest in the development of next generation supersonic and hypersonic vehicles. In such flows, pressure fluctuations displaying a wide range of length and timescales are present. These fluctuations are expected to impact the combustion process to varying degrees, depending amongst other things on the amplitude of the pressure variations and the timescales of the chemical reactions taking place in the flame. In this context, numerical simulations of these flows can provide insight into the impact of pressure fluctuations on the combustion process. In the present work, we analyze data from simulations of statistically-flat premixed n-heptane/air flames at high Karlovitz numbers. The compressible Navier-Stokes equations are solved exactly (DNS) and results obtained with both detailed kinetic modeling and one-step chemistry are considered. The effects of pressure fluctuations on the fuel burning rate are investigated. The findings are compared with results obtained from simulations of one-dimensional premixed flames subjected to various pressure waves.

A review of internal combustion engine combustion chamber process studies at NASA Lewis Research Center

Science.gov (United States)

Schock, H. J.

1984-01-01

The performance of internal combustion stratified-charge engines is highly dependent on the in-cylinder fuel-air mixing processes occurring in these engines. Current research concerning the in-cylinder airflow characteristics of rotary and piston engines is presented. Results showing the output of multidimensional models, laser velocimetry measurements and the application of a holographic optical element are described. Models which simulate the four-stroke cycle and seal dynamics of rotary engines are also discussed.

The new energy processes and the new approaches of the combustion. The environmental impact decrease; Nouveaux procedes energetiques et nouvelles approches de la combustion. Reduction de l'impact environnemental

Energy Technology Data Exchange (ETDEWEB)

Cabot, G. [CORIA, 76 - Mont Saint Aignan (France); Caillat, S. [Ecole des Mines de Douai, Dept. Energetique, 59 (France); Guillet, R. [Gaz de France, GDF DR, 93 - La Plaine Saint-Denis (France)] [and others

2001-07-01

During this day organized by the french society of the science of heat (SFT), seven papers have been presented. They deal with new processes of combustion leading to a better air quality for the environment. The first process concerns the wet combustion, an energy efficient and environmentally friendly technique, its properties and the DHC (hygrometric diagram of combustion) analysis. The flames mechanisms and the swirl process are presented in a second part with the analysis of the radiant heat transfers and the nitrogen oxides emissions. (A.L.B.)

Combustion Characteristics of Chlorine-Free Solid Fuel Produced from Municipal Solid Waste by Hydrothermal Processing

Directory of Open Access Journals (Sweden)

Kunio Yoshikawa

2012-11-01

Full Text Available An experimental study on converting municipal solid waste (MSW into chlorine-free solid fuel using a combination of hydrothermal processing and water-washing has been performed. After the product was extracted from the reactor, water-washing experiments were then conducted to obtain chlorine-free products with less than 3000 ppm total chlorine content. A series of combustion experiments were then performed for the products before and after the washing process to determine the chlorine content in the exhaust gas and those left in the ash after the combustion process at a certain temperature. A series of thermogravimetric analyses were also conducted to compare the combustion characteristics of the products before and after the washing process. Due to the loss of ash and some volatile matter after washing process, there were increases in the fixed carbon content and the heating value of the product. Considering the possible chlorine emission, the washing process after the hydrothermal treatment should be necessary only if the furnace temperature is more than 800 °C.

Synthesis of nanocrystalline Gd doped ceria by combustion technique

DEFF Research Database (Denmark)

Jadhav, L. D.; Chourashiya, M. G.; Subhedar, K. M.

2009-01-01

chemical method of combustion where in the combustion of precursors results in the formation of nanoparticles relatively at lower processing temperature. The thermogravimetric study was carried out to understand the ignition temperature and optimize the fuel-to-oxidant ratio. The successful synthesis...

Fuel and combustion stratification study of Partially Premixed Combustion

OpenAIRE

Izadi Najafabadi, M.; Dam, N.; Somers, B.; Johansson, B.

2016-01-01

Relatively high levels of stratification is one of the main advantages of Partially Premixed Combustion (PPC) over the Homogeneous Charge Compression Ignition (HCCI) concept. Fuel stratification smoothens heat release and improves controllability of this kind of combustion. However, the lack of a clear definition of “fuel and combustion stratifications” is obvious in literature. Hence, it is difficult to compare stratification levels of different PPC strategies or other combustion concepts. T...

Combustion of diesel fuel from a toxicological perspective. I. Origin of incomplete combustion products.

Science.gov (United States)

Scheepers, P T; Bos, R P

1992-01-01

Since the use of diesel engines is still increasing, the contribution of their incomplete combustion products to air pollution is becoming ever more important. The presence of irritating and genotoxic substances in both the gas phase and the particulate phase constituents is considered to have significant health implications. The quantity of soot particles and the particle-associated organics emitted from the tail pipe of a diesel-powered vehicle depend primarily on the engine type and combustion conditions but also on fuel properties. The quantity of soot particles in the emissions is determined by the balance between the rate of formation and subsequent oxidation. Organics are absorbed onto carbon cores in the cylinder, in the exhaust system, in the atmosphere and even on the filter during sample collection. Diesel fuel contains polycyclic aromatic hydrocarbons (PAHs) and some alkyl derivatives. Both groups of compounds may survive the combustion process. PAHs are formed by the combustion of crankcase oil or may be resuspended from engine and/or exhaust deposits. The conversion of parent PAHs to oxygenated and nitrated PAHs in the combustion chamber or in the exhaust system is related to the vast amount of excess combustion air that is supplied to the engine and the high combustion temperature. Whether the occurrence of these derivatives is characteristic for the composition of diesel engine exhaust remains to be ascertained. After the emission of the particles, their properties may change because of atmospheric processes such as aging and resuspension. The particle-associated organics may also be subject to (photo)chemical conversions or the components may change during sampling and analysis. Measurement of emissions of incomplete combustion products as determined on a chassis dynamometer provides knowledge of the chemical composition of the particle-associated organics. This knowledge is useful as a basis for a toxicological evaluation of the health hazards of

Study on the combustion and hydrocarbon emission characteristics of direct injection spark-ignition engines during the direct-start process

International Nuclear Information System (INIS)

Shi, Lei; Xiao, Maoyu; Deng, Kangyao

2015-01-01

Highlights: • Mixture concentration in first-combustion cylinder of direct start is measured. • Factors that affect direct start performances are investigated. • Combustion characteristics of first-combustion cylinder are analyzed. • Hydrocarbon emission is considered to determined control strategies of direct start. - Abstract: This study was conducted to investigate the combustion and emissions characteristics of the first-combustion cylinder in a direct-start process. The explosive energy of the first combustion is important for the success of a direct start, but this combustion was rarely addressed in recent research. For a 2.0 L direct-injection spark-ignition engine, the in-cylinder mixture concentration, cylinder pressure, engine speed and exhaust hydrocarbon concentration were detected to analyze the fuel evaporation, combustion, engine movement and engine emissions, respectively. In the first-combustion cylinder of the direct-start process, the injected fuel was often enriched to ensure that an appropriate mixture concentration was obtained for ignition without misfiring. Approximately one-third of the injected fuel would not participate in the combustion process and would therefore reduce the exhaust hydrocarbon emissions. The start position determined the amount of the total explosive energy in the first-combustion cylinder, and an optimal start position for a direct start was found to be at a 70–80° crank angle before the top dead center to obtain a better combustion performance and lower emissions. A lower coolant temperature increased the maximum explosion energy of the first combustion, but additional hydrocarbon emissions were generated. Because there was almost no problem in the direct-start capability with different coolant temperatures after an idling stop, it was necessary to maintain the coolant temperature when the engine was stopped

Combustion Stratification for Naphtha from CI Combustion to PPC

KAUST Repository

Vallinayagam, R.

2017-03-28

This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON = 46). The motored pressure at TDC is maintained at 35 bar and fuelMEP is kept constant at 5.1 bar to account for the difference in fuel properties between naphtha and diesel. Single injection strategy is employed and the fuel is injected at a pressure of 800 bar. Photron FASTCAM SA4 that captures in-cylinder combustion at the rate of 10000 frames per second is employed. The captured high speed video is processed to study the combustion homogeneity based on an algorithm reported in previous studies. Starting from late fuel injection timings, combustion stratification is investigated by advancing the fuel injection timings. For late start of injection (SOI), a direct link between SOI and combustion phasing is noticed. At early SOI, combustion phasing depends on both intake air temperature and SOI. In order to match the combustion phasing (CA50) of diesel, the intake air temperature is increased to 90°C for naphtha. The combustion stratification from CI to PPC is also investigated for various level of dilution by displacing oxygen with nitrogen in the intake. The start of combustion (SOC) was delayed with the increase in dilution and to compensate for this, the intake air temperature is increased. The mixture homogeneity is enhanced for higher dilution due to longer ignition delay. The results show that high speed image is initially blue and then turned yellow, indicating soot formation and oxidation. The luminosity of combustion images decreases with early SOI and increased dilution. The images are processed to generate the level of stratification based on the image intensity. The level of stratification is same for diesel and naphtha at various SOI. When O concentration in the intake is decreased to 17.7% and 14

Review of the investigation of mixture formation and combustion process using rapid compression machine and direct visualization system

Science.gov (United States)

Jaat, M.; Khalid, Amir; Manshoor, B.; Ramsy, Him

2013-12-01

This paper reviews of some applications of optical visualization systems to compute the fuel-air mixing process during early stage of mixture formation in Diesel Combustion Engines. A number of studies have contributed to the understanding of fuel air mixing in DI diesel engine. This review has shown that the mixture formation process affects initial flame development. The review also found that injection pressure has a great effect on the mixture formation then the flame development and combustion characteristics. The method of the simulation of real phenomenon of diesel combustion with optical access rapid compression machine is also reviewed and experimental results are presented. The application of these methods to the investigation of diesel sprays highlights mechanisms which govern propagation and distribution of the formation of a combustible fuel-air mixture. A summary of the implementation of constant volume chamber and optical visualization system are shown in the accompanying tables and figures. The visualization of the formation process of diesel spray and its combustion in the diesel combustion chamber of diesel engine has been recognized as one of the best ways to understand the characteristics of the mixture formation.

A review of internal combustion engine combustion chamber process studies at NASA Lewis Research Center

Science.gov (United States)

Schock, H. J.

1984-01-01

The performance of internal combustion stratified-charge engines is highly dependent on the in-cylinder fuel-air mixing processes occurring in these engines. Current research concerning the in-cylinder airflow characteristics of rotary and piston engines is presented. Results showing the output of multidimensional models, laser velocimetry measurements and the application of a holographic optical element are described. Models which simulate the four-stroke cycle and seal dynamics of rotary engines are also discussed. Previously announced in STAR as N84-24999

Effects of injection angles on combustion processes using multiple injection strategies in an HSDI diesel engine

Energy Technology Data Exchange (ETDEWEB)

Tiegang Fang; Robert E. Coverdill; Chia-fon F. Lee; Robert A. White [North Carolina State University, Raleigh, NC (United States). Department of Mechanical and Aerospace Engineering

2008-11-15

Effects of injection angles and injection pressure on the combustion processes employing multiple injection strategies in a high-speed direct-injection (HSDI) diesel engine are presented in this work. Whole-cycle combustion and liquid spray evolution processes were visualized using a high-speed video camera. NOx emissions were measured in the exhaust pipe. Different heat release patterns are seen for two different injectors with a 70-degree tip and a 150-degree tip. No evidence of fuel-wall impingement is found for the first injection of the 150-degree tip, but for the 70-degree tip, some fuel impinges on the bowl wall and a fuel film is formed. For the second injection, a large amount of fuel deposition is observed for the 70-degree tip. Weak flame is seen for the first injection of the 150-degree tip while two sorts of flames are seen for the first injection of the 70-degree tip including an early weak flame and a late luminous film combustion flame. Ignition occurs near the spray tip in the vicinity of the bowl wall for the second injection events of the 150-degree tip, however, it is near the injector tip in the central region of the bowl for the 70-degree tip. The flame is more homogeneous for the 150-degree tip with higher injection pressure with little soot formation similar to a premixed-charge-compression-ignition (PCCI) combustion. For other cases, liquid fuel is injected into flames showing diffusion flame combustion. More soot luminosity is seen for the 70-degree tip due to significant fuel film deposition on the piston wall with fuel film combustion for both injection events. Lower NOx emissions were obtained for the narrow-angle injector due to the rich air-fuel mixture near the bowl wall during the combustion process. 30 refs., 11 figs., 3 tabs.

Stochastic disturbances and dynamics of thermal processes. With application to municipal solid waste combustion

Energy Technology Data Exchange (ETDEWEB)

Van Kessel, L.B.M.

2003-06-11

The main topic of this thesis is the research into the disturbances and dynamics of the Municipal and Solid Waste Combustion (MSWC) process. As already said, the MSWC process suffers from large disturbances in the calorific value. At the start of this research it was obvious that for a good process analysis of the dynamics more information about the disturbances would be necessary. Therefore, a new on-line calorific value sensor was developed, which is described in chapter 2. The new on-line calorific value sensor makes it possible to monitor on-line important process variables like the calorific value and the water content of the fuel. The sensor is used to collect data from four different MSWC plants. Results from these MSWC plants will be presented. A comparison with traditional off-line methods and possible applications will be discussed as well. After revealing the main disturbances of the process the study of the process dynamics can be performed. A mathematical dynamic model of the process is very useful for studying the dynamics of a process. Therefore, in chapter 3 a general model for the dynamics of thermal processes is derived. This general model is applied to MSWC, which yields a completely new model description of the MSWC process. However, a model has to be validated with practical data. Unfortunately, MSWC plants suffer from large disturbances, which makes a good validation complicated. As no good information for the validation of processes like MSWC was available in literature, new validation techniques have been applied to MSWC plants. The validation results will be presented. The results from the validation experiments will show that the combustion process in practice can become completely different when different primary air temperatures are used. Two situations with different primary air temperatures will be discussed in detail including the application of the derived dynamic model to explain the differences. When the disturbances are measured

Thermal effects from the release of selenium from a coal combustion during high-temperature processing: a review.

Science.gov (United States)

Hu, Jianjun; Sun, Qiang; He, Huan

2018-04-11

The release of selenium (Se) during coal combustion can have serious impacts on the ecological environment and human health. Therefore, it is very important to study the factors that concern the release of Se from coal combustion. In this paper, the characteristics of the release of Se from coal combustion, pyrolysis, and gasification of different coal species under different conditions are studied. The results show that the amount of released Se increases at higher combustion temperatures. There are obvious increases in the amount of released Se especially in the temperature range of 300 to 800 °C. In addition, more Se is released from the coal gasification than coal combustion process, but more Se is released from coal combustion than pyrolysis. The type of coal, rate of heating, type of mineral ions, and combustion atmosphere have different effects on the released percentage of Se. Therefore, having a good understanding of the factors that surround the release of Se during coal combustion, and then establishing the combustion conditions can reduce the impacts of this toxic element to humans and the environment.

The combustion of sound and rotten coarse woody debris: a review

Science.gov (United States)

Joshua C. Hyde; Alistair M.S. Smith; Roger D. Ottmar; Ernesto C. Alvarado; Penelope Morgan

2011-01-01

Coarse woody debris serves many functions in forest ecosystem processes and has important implications for fire management as it affects air quality, soil heating and carbon budgets when it combusts. There is relatively little research evaluating the physical properties relating to the combustion of this coarse woody debris with even less specifically addressing...

Analysis and control of harmful emissions from combustion processes

OpenAIRE

Jafari, Ahmad

2000-01-01

This thesis was submitted for the degree of Doctor of Philosophy and awarded by Brunel University. The harmful effects of air pollutants on human beings and environment have been the major reason for efforts in sampling, analysis and control of their sources. The major pollutants emitted to atmosphere from stationary combustion processes are nitrogen oxides, inorganic acids, carbon dioxide, carbon monoxide, hydrocarbon and soot. In the current work two methods are developed for sampl...

A novel device for processing radioactive combustibles

International Nuclear Information System (INIS)

Phelan, P.F.; Thompson, T.K.

1991-01-01

Los Alamos National Laboratory is assisting EG ampersand G Rocky Flats, Colorado, with the development of a special incinerator for wastes contaminated with plutonium, a radioactive element. This paper describes one conceptual design that was developed by T.K. Thompson, Inc., under contract to Los Alamos National Laboratory. The design is a tentative proposal that tries to address the many constraints that are peculiar to this project. It has not been endorsed or accepted by EG ampersand G Rocky Flats, and it is subject to revision. Nevertheless, it is noteworthy because of the novel concepts it embodies. Before examining the design itself, it is instructive to understand the constraints imposed by safety and operational concerns. There are three main requirements related to safety: There may be no emissions of radioactive material either to the atmosphere or into the building that houses the incinerator. The outer surfaces of the combustion chamber must be kept below 140oF so that the lead-lined rubber gloves will not melt if the operator reaches inside the glovebox while the incinerator is hot. The combustion chambers and other locations where plutonium-containing ash could accumulate must be designed in such a way that it would be impossible for a critically accident to occur. 3 figs

Modeling and optimization of processes for clean and efficient pulverized coal combustion in utility boilers

Directory of Open Access Journals (Sweden)

Belošević Srđan V.

2016-01-01

Full Text Available Pulverized coal-fired power plants should provide higher efficiency of energy conversion, flexibility in terms of boiler loads and fuel characteristics and emission reduction of pollutants like nitrogen oxides. Modification of combustion process is a cost-effective technology for NOx control. For optimization of complex processes, such as turbulent reactive flow in coal-fired furnaces, mathematical modeling is regularly used. The NOx emission reduction by combustion modifications in the 350 MWe Kostolac B boiler furnace, tangentially fired by pulverized Serbian lignite, is investigated in the paper. Numerical experiments were done by an in-house developed three-dimensional differential comprehensive combustion code, with fuel- and thermal-NO formation/destruction reactions model. The code was developed to be easily used by engineering staff for process analysis in boiler units. A broad range of operating conditions was examined, such as fuel and preheated air distribution over the burners and tiers, operation mode of the burners, grinding fineness and quality of coal, boiler loads, cold air ingress, recirculation of flue gases, water-walls ash deposition and combined effect of different parameters. The predictions show that the NOx emission reduction of up to 30% can be achieved by a proper combustion organization in the case-study furnace, with the flame position control. Impact of combustion modifications on the boiler operation was evaluated by the boiler thermal calculations suggesting that the facility was to be controlled within narrow limits of operation parameters. Such a complex approach to pollutants control enables evaluating alternative solutions to achieve efficient and low emission operation of utility boiler units. [Projekat Ministarstva nauke Republike Srbije, br. TR-33018: Increase in energy and ecology efficiency of processes in pulverized coal-fired furnace and optimization of utility steam boiler air preheater by using in

Fuels and Combustion

KAUST Repository

Johansson, Bengt

2016-08-17

This chapter discusses the combustion processes and the link to the fuel properties that are suitable for them. It describes the basic three concepts, including spark ignition (SI) and compression ignition (CI), and homogeneous charge compression ignition (HCCI). The fuel used in a CI engine is vastly different from that in an SI engine. In an SI engine, the fuel should sustain high pressure and temperature without autoignition. Apart from the dominating SI and CI engines, it is also possible to operate with a type of combustion: autoignition. With HCCI, the fuel and air are fully premixed before combustion as in the SI engine, but combustion is started by the increased pressure and temperature during the compression stroke. Apart from the three combustion processes, there are also a few combined or intermediate concepts, such as Spark-Assisted Compression Ignition (SACI). Those concepts are discussed in terms of the requirements of fuel properties.

Fuels and Combustion

KAUST Repository

Johansson, Bengt

2016-01-01

This chapter discusses the combustion processes and the link to the fuel properties that are suitable for them. It describes the basic three concepts, including spark ignition (SI) and compression ignition (CI), and homogeneous charge compression ignition (HCCI). The fuel used in a CI engine is vastly different from that in an SI engine. In an SI engine, the fuel should sustain high pressure and temperature without autoignition. Apart from the dominating SI and CI engines, it is also possible to operate with a type of combustion: autoignition. With HCCI, the fuel and air are fully premixed before combustion as in the SI engine, but combustion is started by the increased pressure and temperature during the compression stroke. Apart from the three combustion processes, there are also a few combined or intermediate concepts, such as Spark-Assisted Compression Ignition (SACI). Those concepts are discussed in terms of the requirements of fuel properties.

Compositional Simulation of In-Situ Combustion EOR: A Study of Process Characteristics

DEFF Research Database (Denmark)

Jain, Priyanka; Stenby, Erling Halfdan; von Solms, Nicolas

2010-01-01

In order to facilitate the study of the influence of reservoir process characteristics in In-Situ combustion modeling and advance the work of Kristensen et al. in this domain; a fully compositional In-situ combustion (ISC) model of Virtual Kinetic Cell (VKC; single-cell model) for laboratory scale....... This incorporates fourteen pseudo components and fourteen reactions (distributed amongst thermal cracking, low temperature oxidation and high temperature oxidation). The paper presents a set of derivative plots indicating that reservoir process characterization in terms of thermal behavior of oil can be well...... construed in terms of thermo-oxidative sensitivity of SARA fractions. It can be interpreted from the results that operating parameters like air injection rate, oxygen feed concentration and activation energy have significant influence on oil recovery; an increase in air injection rate can lead to cooling...

Internal combustion engine using premixed combustion of stratified charges

Science.gov (United States)

Marriott, Craig D [Rochester Hills, MI; Reitz, Rolf D [Madison, WI

2003-12-30

During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

Oxy-fuel combustion of solid fuels

DEFF Research Database (Denmark)

Toftegaard, Maja Bøg; Brix, Jacob; Jensen, Peter Arendt

2010-01-01

Oxy-fuel combustion is suggested as one of the possible, promising technologies for capturing CO2 from power plants. The concept of oxy-fuel combustion is removal of nitrogen from the oxidizer to carry out the combustion process in oxygen and, in most concepts, recycled flue gas to lower the flame...... provide additional options for improvement of process economics are however likewise investigated. Of particular interest is the change of the combustion process induced by the exchange of carbon dioxide and water vapor for nitrogen as diluent. This paper reviews the published knowledge on the oxy......-fuel process and focuses particularly on the combustion fundamentals, i.e. flame temperatures and heat transfer, ignition and burnout, emissions, and fly ash characteristics. Knowledge is currently available regarding both an entire oxy-fuel power plant and the combustion fundamentals. However, several...

Tools for the efficient use of the gas: Combustion diagrams

International Nuclear Information System (INIS)

Amell Andres; Maya Ruben D

1997-01-01

In this work the results of an investigation carried out with the purpose of developing a fundamental tool related to the process of optimization of the combustion are presented: The combustion diagrams with the optimization are looked for using the maximum heat generated in the reaction and to avoid the production of pollutants, product of an incomplete combustion. This is carried out controlling the stability of the flame and the composition of the smoke by means of the adjustment of the ratio air/combustible basically and with a homogeneous mixture. A constant pursuit of the dry smoke allows to determine the presence of pollutants and to establish the combustion type. A valuable tool to establish the conditions in which this process is carried out, this is the combustion diagram; this diagram uses the values of the concentration of O2 and CO2 in the dry smoke, starting from the sampling of the products by an analyzer to determine the composition of these smoke, the percentage of air really used, the air in excess and the combustion type

New approaches for description of nitrogen chemistry in combustion processes

Energy Technology Data Exchange (ETDEWEB)

Hupa, M.; Kilpinen, P.; Nordstroem, T. [Aabo Akademi, Turku (Finland). Combustion Chemistry Research Group

1997-10-01

The aim of the project is to assist in development of more efficient in-furnace control methods for nitrogen oxide emission from energy conversion technologies based on combustion and/or gasification. Main emphasis in put on technologies such as fluidized bed combustion (CFBC, BFBC) and combined cycle processes (PFBC, IGCC). The project consists of two parts: (a) detailed kinetic elementary reaction modelling and (b) prediction of NO{sub x} emission from full scale combustors. The following topics have been studied during 1996: (a) Detailed kinetic modelling Effect of HCl on CO burn-out under FBC freeboard conditions. Effect of pressure on the Thermal DeNO{sub x} process under PFBC conditions. Mechanism of NH{sub 3} destruction to N{sub 2} by selective oxidation (SO): -the importance of formation of NO{sub 2} from NO and O{sub 2} at low temperatures. (b) Prediction of NO{sub x} emission from full scale combustors Prediction of NO{sub x} emission from BFBC freeboard: a case study using flow tubes and detailed chemistry. The work has been made partly in collaboration with VTT Energy (projects 213 and 214) and Tampere University of Technology (project 210). (orig.)

DIAGNOSIS OF FAILURE OF COMBUSTION IN THE COMBUSTION CHAMBER WITH A THERMOVISION EQUIPMENT

Directory of Open Access Journals (Sweden)

S. V. Vorobiev

2014-01-01

Full Text Available The use of thermovision technology to diagnose failure of the combustion flame test tube of the main combustion chamber gas turbine engine is deal with in the article. Join the thermal radiation of the jet of combustion products and the internal elements was carried out using short-wave thermovision system AGA-782 with spectral spectral filters in several ranges from 3.2 to 5.6 microns. Thermovision is mounted on the axis of the flame tube. The output signal was recorded and processed on a computer in real time, allowing monitor the combustion process and the thermal state of the object during the experiment.

Large eddy simulation of the low temperature ignition and combustion processes on spray flame with the linear eddy model

Science.gov (United States)

Wei, Haiqiao; Zhao, Wanhui; Zhou, Lei; Chen, Ceyuan; Shu, Gequn

2018-03-01

Large eddy simulation coupled with the linear eddy model (LEM) is employed for the simulation of n-heptane spray flames to investigate the low temperature ignition and combustion process in a constant-volume combustion vessel under diesel-engine relevant conditions. Parametric studies are performed to give a comprehensive understanding of the ignition processes. The non-reacting case is firstly carried out to validate the present model by comparing the predicted results with the experimental data from the Engine Combustion Network (ECN). Good agreements are observed in terms of liquid and vapour penetration length, as well as the mixture fraction distributions at different times and different axial locations. For the reacting cases, the flame index was introduced to distinguish between the premixed and non-premixed combustion. A reaction region (RR) parameter is used to investigate the ignition and combustion characteristics, and to distinguish the different combustion stages. Results show that the two-stage combustion process can be identified in spray flames, and different ignition positions in the mixture fraction versus RR space are well described at low and high initial ambient temperatures. At an initial condition of 850 K, the first-stage ignition is initiated at the fuel-lean region, followed by the reactions in fuel-rich regions. Then high-temperature reaction occurs mainly at the places with mixture concentration around stoichiometric mixture fraction. While at an initial temperature of 1000 K, the first-stage ignition occurs at the fuel-rich region first, then it moves towards fuel-richer region. Afterwards, the high-temperature reactions move back to the stoichiometric mixture fraction region. For all of the initial temperatures considered, high-temperature ignition kernels are initiated at the regions richer than stoichiometric mixture fraction. By increasing the initial ambient temperature, the high-temperature ignition kernels move towards richer

Waste plastics as supplemental fuel in the blast furnace process: improving combustion efficiencies.

Science.gov (United States)

Kim, Dongsu; Shin, Sunghye; Sohn, Seungman; Choi, Jinshik; Ban, Bongchan

2002-10-14

The possibility of using waste plastics as a source of secondary fuel in a blast furnace has been of recent interest. The success of this process, however, will be critically dependent upon the optimization of operating systems. For instance, the supply of waste plastics must be reliable as well as economically attractive compared with conventional secondary fuels such as heavy oil, natural gas and pulverized coal. In this work, we put special importance on the improvement of the combustibility of waste plastics as a way to enhance energy efficiency in a blast furnace. As experimental variables to approach this target, the effects of plastic particle size, blast temperature, and the level of oxygen enrichment were investigated using a custom-made blast model designed to simulate a real furnace. Lastly, the combustion efficiency of the mixture of waste plastics and pulverized coal was tested. The observations made from these experiments led us to the conclusion that with the increase of both blast temperature and the level of oxygen enrichment, and with a decrease in particle size, the combustibility of waste polyethylene could be improved at a given distance from the tuyere. Also it was found that the efficiency of coal combustion decreased with the addition of plastics; however, the combustion efficiency of mixture could be comparable at a longer distance from the tuyere.

Analysis of Combustion Process in Industrial Gas Engine with Prechamber-Based Ignition System

Directory of Open Access Journals (Sweden)

Rafał Ślefarski

2018-02-01

Full Text Available Application of a pre-combustion chamber (PCC ignition system is one of the methods to improve combustion stability and reduce toxic compounds emission, especially NOx. Using PCC allows the operation of the engine at lean combustion conditions or the utilization of low calorific gaseous fuels such as syngas or biogas. The paper presents the results of an experimental study of the combustion process in two stroke, large bore, stationary gas engine GMVH 12 equipped with two spark plugs (2-SP and a PCC ignition system. The experimental research has been performed during the normal operation of the engine in an industrial compression station. It was observed that application of PCC provides less cycle-to-cycle combustion variation (more than 10% and nitric oxide and carbon monoxide emissions decreased to 60% and 26% respectively. The total hydrocarbon (THC emission rate is 25% higher for the engine equipped with PCC, which results in roughly two percent engine efficiency decrease. Another important criterion of engine retrofitting was the PCC location in the engine head. The experimental results show that improvement of engine operating parameters was recorded only for a configuration with one port offset by 45° from the axis of the main chamber. The study of the ignition delay angle and equivalence ratio in PCC did not demonstrate explicit influence on engine performance.

Exergetic analysis of cogeneration plants through integration of internal combustion engine and process simulators

Energy Technology Data Exchange (ETDEWEB)

Carvalho, Leonardo de Oliveira [Petroleo Brasileiro S.A. (PETROBRAS), Rio de Janeiro, RJ (Brazil)], E-mail: leonardo.carvalho@petrobras.com.br; Leiroz, Albino Kalab; Cruz, Manuel Ernani [Coordenacao dos Programas de Pos-Graduacao de Engenharia (COPPE/UFRJ), RJ (Brazil). Programa de Engenharia Mecanica], Emails: leiroz@mecanica.ufrj.br, manuel@mecanica.ufrj.br

2010-07-01

Internal combustion engines (ICEs) have been used in industry and power generation much before they were massively employed for transportation. Their high reliability, excellent power-to-weight ratio, and thermal efficiency have made them a competitive choice as main energy converters in small to medium sized power plants. Process simulators can model ICE powered energy plants with limited depth, due to the highly simplified ICE models used. Usually a better understanding of the global effects of different engine parameters is desirable, since the combustion process within the ICE is typically the main cause of exergy destruction in systems which utilize them. Dedicated commercial ICE simulators have reached such a degree of maturity, that they can adequately model a wide spectrum of phenomena that occur in ICEs. However, ICE simulators are unable to incorporate the remaining of power plant equipment and processes in their models. This paper presents and exploits the integration of an internal combustion engine simulator with a process simulator, so as to evaluate the construction of a fully coupled simulation platform to analyze the performance of ICE-based power plants. A simulation model of an actual cogeneration plant is used as a vehicle for application of the proposed computational methodology. The results show that by manipulating the engine mapping parameters, the overall efficiency of the plant can be improved. (author)

Seismic monitoring of in situ combustion process in a heavy oil field

International Nuclear Information System (INIS)

Zadeh, Hossein Mehdi; Srivastava, Ravi P; Vedanti, Nimisha; Landrø, Martin

2010-01-01

Three time-lapse 3D seismic surveys are analysed to monitor the effect of in situ combustion, a thermal-enhanced oil recovery process in the Balol heavy oil reservoir in India. The baseline data were acquired prior to the start of the in situ combustion process in four injection wells, while the two monitor surveys were acquired 1 and 2 years after injection start, respectively. We present the results of baseline and second monitor surveys. Fluid substitution studies based on acoustic well logs predict a seismic amplitude decrease at the top reservoir and an increase at the base reservoir. Both the amplitude dimming at the top reservoir and the brightening at the base reservoir are observed in the field data. The extent of the most pronounced 4D anomaly is estimated from the seismic amplitude and time shift analysis. The interesting result of seismic analysis is that the anomalies are laterally shifted towards the northwest, rather than the expected east, from the injector location suggesting a northwest movement of the in situ combustion front. No clear evidence of air leakage into other sand layers, neither above nor below the reservoir sand, is observed. This does not necessarily mean that all the injected air is following the reservoir sand, especially if the thief sand layers are thin. These layers might be difficult to observe on seismic data

Fuel and combustion stratification study of Partially Premixed Combustion

NARCIS (Netherlands)

Izadi Najafabadi, M.; Dam, N.; Somers, B.; Johansson, B.

2016-01-01

Relatively high levels of stratification is one of the main advantages of Partially Premixed Combustion (PPC) over the Homogeneous Charge Compression Ignition (HCCI) concept. Fuel stratification smoothens heat release and improves controllability of this kind of combustion. However, the lack of a

CFD simulation of the combustion process of the low-emission vortex boiler

Science.gov (United States)

Chernov, A. A.; Maryandyshev, P. A.; Pankratov, E. V.; Lubov, V. K.

2017-11-01

Domestic heat and power engineering needs means and methods for optimizing the existing boiler plants in order to increase their technical, economic and environmental work. The development of modern computer technology, methods of numerical modeling and specialized software greatly facilitates the solution of many emerging problems. CFD simulation allows to obtaine precise results of thermochemical and aerodynamic processes taking place in the furnace of boilers in order to optimize their operation modes and develop directions for their modernization. The paper presents the results of simulation of the combustion process of a low-emission vortex coal boiler of the model E-220/100 using the software package Ansys Fluent. A hexahedral grid with a number of 2 million cells was constructed for the chosen boiler model. A stationary problem with a two-phase flow was solved. The gaseous components are air, combustion products and volatile substances. The solid phase is coal particles at different burnup stages. The Euler-Lagrange approach was taken as a basis. Calculation of the coal particles trajectories was carried out using the Discrete Phase Model which distribution of the size particle of coal dust was accounted for using the Rosin-Rammler equation. Partially Premixed combustion model was used as the combustion model which take into account elemental composition of the fuel and heat analysis. To take turbulence into account, a two-parameter k-ε model with a standard wall function was chosen. Heat transfer by radiation was calculated using the P1-approximation of the method of spherical harmonics. The system of spatial equations was numerically solved by the control volume method using the SIMPLE algorithm of Patankar and Spaulding. Comparison of data obtained during the industrial-operational tests of low-emission vortex boilers with the results of mathematical modeling showed acceptable convergence of the tasks of this level, which confirms the adequacy of the

Combustion synthesis of TiB2-based cermets: modeling and experimental results

International Nuclear Information System (INIS)

Martinez Pacheco, M.; Bouma, R.H.B.; Katgerman, L.

2008-01-01

TiB 2 -based cermets are prepared by combustion synthesis followed by a pressing stage in a granulate medium. Products obtained by combustion synthesis are characterized by a large remaining porosity (typically 50%). To produce dense cermets, a subsequent densification step is performed after the combustion process and when the reacted material is still hot. To design the process, numerical simulations are carried out and compared to experimental results. In addition, physical and electrical properties of the products related to electrical contact applications are evaluated. (orig.)

Development of a Premixed Combustion Capability for Scramjet Combustion Experiments

Science.gov (United States)

Rockwell, Robert D.; Goyne, Christopher P.; Rice, Brian E.; Chelliah, Harsha; McDaniel, James C.; Edwards, Jack R.; Cantu, Luca M. L.; Gallo, Emanuela C. A.; Cutler, Andrew D.; Danehy, Paul M.

2015-01-01

Hypersonic air-breathing engines rely on scramjet combustion processes, which involve high speed, compressible, and highly turbulent flows. The combustion environment and the turbulent flames at the heart of these engines are difficult to simulate and study in the laboratory under well controlled conditions. Typically, wind-tunnel testing is performed that more closely approximates engine testing rather than a careful investigation of the underlying physics that drives the combustion process. The experiments described in this paper, along with companion data sets being developed separately, aim to isolate the chemical kinetic effects from the fuel-air mixing process in a dual-mode scramjet combustion environment. A unique fuel injection approach is taken that produces a nearly uniform fuel-air mixture at the entrance to the combustor. This approach relies on the precombustion shock train upstream of the dual-mode scramjet combustor. A stable ethylene flame anchored on a cavity flameholder with a uniformly mixed combustor inflow has been achieved in these experiments allowing numerous companion studies involving coherent anti-Stokes Raman scattering (CARS), particle image velocimetry (PIV), and planar laser induced fluorescence (PLIF) to be performed.

Research on the Combustion Characteristics of a Free-Piston Gasoline Engine Linear Generator during the Stable Generating Process

Directory of Open Access Journals (Sweden)

Yuxi Miao

2016-08-01

Full Text Available The free-piston gasoline engine linear generator (FPGLG is a new kind of power plant consisting of free-piston gasoline engines and a linear generator. Due to the elimination of the crankshaft mechanism, the piston motion process and the combustion heat release process affect each other significantly. In this paper, the combustion characteristics during the stable generating process of a FPGLG were presented using a numerical iteration method, which coupled a zero-dimensional piston dynamic model and a three-dimensional scavenging model with the combustion process simulation. The results indicated that, compared to the conventional engine (CE, the heat release process of the FPGLG lasted longer with a lower peak heat release rate. The indicated thermal efficiency of the engine was lower because less heat was released around the piston top dead centre (TDC. Very minimal difference was observed on the ignition delay duration between the FPGLG and the CE, while the post-combustion period of the FPGLG was significantly longer than that of the CE. Meanwhile, the FPGLG was found to operate more moderately due to lower peak in-cylinder gas pressure and a lower pressure rising rate. The potential advantage of the FPGLG in lower NOx emission was also proven with the simulation results presented in this paper.

Reconstruction of an engine combustion process with a neural network

Energy Technology Data Exchange (ETDEWEB)

Jacob, P J; Gu, F; Ball, A D [School of Engineering, University of Manchester, Manchester (United Kingdom)

1998-12-31

The cylinder pressure waveform in an internal combustion engine is one of the most important parameters in describing the engine combustion process. It is used for a range of diagnostic tasks such as identification of ignition faults or mechanical wear in the cylinders. However, it is very difficult to measure this parameter directly. Never-the-less, the cylinder pressure may be inferred from other more readily obtainable parameters. In this presentation it is shown how a Radial Basis Function network, which may be regarded as a form of neural network, may be used to model the cylinder pressure as a function of the instantaneous crankshaft velocity, recorded with a simple magnetic sensor. The application of the model is demonstrated on a four cylinder DI diesel engine with data from a wide range of speed and load settings. The prediction capabilities of the model once trained are validated against measured data. (orig.) 4 refs.

Reconstruction of an engine combustion process with a neural network

Energy Technology Data Exchange (ETDEWEB)

Jacob, P.J.; Gu, F.; Ball, A.D. [School of Engineering, University of Manchester, Manchester (United Kingdom)

1997-12-31

The cylinder pressure waveform in an internal combustion engine is one of the most important parameters in describing the engine combustion process. It is used for a range of diagnostic tasks such as identification of ignition faults or mechanical wear in the cylinders. However, it is very difficult to measure this parameter directly. Never-the-less, the cylinder pressure may be inferred from other more readily obtainable parameters. In this presentation it is shown how a Radial Basis Function network, which may be regarded as a form of neural network, may be used to model the cylinder pressure as a function of the instantaneous crankshaft velocity, recorded with a simple magnetic sensor. The application of the model is demonstrated on a four cylinder DI diesel engine with data from a wide range of speed and load settings. The prediction capabilities of the model once trained are validated against measured data. (orig.) 4 refs.

Applied Gaussian Process in Optimizing Unburned Carbon Content in Fly Ash for Boiler Combustion

Directory of Open Access Journals (Sweden)

Chunlin Wang

2017-01-01

Full Text Available Recently, Gaussian Process (GP has attracted generous attention from industry. This article focuses on the application of coal fired boiler combustion and uses GP to design a strategy for reducing Unburned Carbon Content in Fly Ash (UCC-FA which is the most important indicator of boiler combustion efficiency. With getting rid of the complicated physical mechanisms, building a data-driven model as GP is an effective way for the proposed issue. Firstly, GP is used to model the relationship between the UCC-FA and boiler combustion operation parameters. The hyperparameters of GP model are optimized via Genetic Algorithm (GA. Then, served as the objective of another GA framework, the predicted UCC-FA from GP model is utilized in searching the optimal operation plan for the boiler combustion. Based on 670 sets of real data from a high capacity tangentially fired boiler, two GP models with 21 and 13 inputs, respectively, are developed. In the experimental results, the model with 21 inputs provides better prediction performance than that of the other. Choosing the results from 21-input model, the UCC-FA decreases from 2.7% to 1.7% via optimizing some of the operational parameters, which is a reasonable achievement for the boiler combustion.

An Experimental Investigation on the Combustion and Heat Release Characteristics of an Opposed-Piston Folded-Cranktrain Diesel Engine

Directory of Open Access Journals (Sweden)

Fukang Ma

2015-06-01

Full Text Available In opposed-piston folded-cranktrain diesel engines, the relative movement rules of opposed-pistons, combustion chamber components and injector position are different from those of conventional diesel engines. The combustion and heat release characteristics of an opposed-piston folded-cranktrain diesel engine under different operating conditions were investigated. Four phases: ignition delay, premixed combustion, diffusion combustion and after combustion are used to describe the heat release process of the engine. Load changing has a small effect on premixed combustion duration while it influences diffusion combustion duration significantly. The heat release process has more significant isochoric and isobaric combustion which differs from the conventional diesel engine situation, except at high exhaust pressure and temperature, due to its two-stroke and uniflow scavenging characteristics. Meanwhile, a relatively high-quality exhaust heat energy is produced in opposed-piston folded-cranktrain diesel engines.

Visualization research on spray atomization, evaporation and combustion processes of ethanol–diesel blend under LTC conditions

International Nuclear Information System (INIS)

Huang, Sheng; Deng, Peng; Huang, Ronghua; Wang, Zhaowen; Ma, Yinjie; Dai, Hui

2015-01-01

Highlights: • Spray combustion of E20 diesel in LTC condition shows a U-shape flame structure. • The chasing behavior of fuel spray exists near the spray axis. • Fuel ignition doesn’t initiate at the spray tip but in peripheral regions behind it. • An improper chamber structure may lead to a long post-combustion duration. - Abstract: Utilization of ethanol in diesel engines has been widely studied by means of engine experiments and emission detection. However, pertinent studies on the spray combustion process of ethanol–diesel blends are scarce. In order to verify the effect of ethanol in modern diesel engines, an experiment is conducted to visualize the spray combustion process of ethanol–diesel blend under LTC conditions. Stages including atomization, evaporation and combustion, are investigated individually to realize synergistic analysis. Meanwhile, considering the long time scale of combustion after fuel injection finishes, characteristics during and after injection period are both targeted in this paper. Moreover, measurement of macroscopic characteristics, such as spray tip penetration, spray spreading cone angle and flame lift off length, provides a quantitative profile of the spray structure. Results show that, evaporation, different from atomization, has little influence on spray penetration, but promotes the spray spreading angle and spray projected area. So does combustion, which enlarges the spray projected area further. Ignition takes place on the periphery behind the spray tip, then quickly extends to the whole head of the spray and forms a U-shape diffusion structure. After the injection period, the residual spray tail develops into wavelike structures due to absence of subsequent entrainment force. Also, the penetration speed falls greatly to an extent much slower than flame propagation, which frees the flame from the lift-off effect. Subsequently, the flame propagates upstream towards the nozzle orifice. After consumed all fuel in

How in-situ combustion process works in a fractured system : two-dimensional, core and block scale simulation

Energy Technology Data Exchange (ETDEWEB)

Fadaei, H.; Renard, G. [Inst. Francais du Petrole, Lyon (France); Quintard, M.; Debenest, G. [L' Inst. de Mecanique des Fluides de Toulouse, Toulouse (France); Kamp, A.M. [Centre Huile Lourde Ouvert et Experimental CHLOE, Pau (France)

2008-10-15

Core and matrix block scale simulations of in situ combustion (ISC) processes in a fractured reservoir were conducted. ISC propagation conditions and oil recovery mechanisms were studied at core scale, while the 2-D behaviour of ISC was also studied at block-scale in order to determine dominant processes for combustion propagation and the characteristics of different steam fronts. The study examined 2-phase combustion in a porous medium containing a solid fuel as well as 2-D conventional dry combustion methods. The aim of the study was to predict ISC extinction and propagation conditions as well as to understand the mechanisms of oil recovery using ISC processes. The simulations were also used to develop up-scaling guidelines for fractured systems. Computations were performed using different oxygen diffusion and matrix permeability values. The effect of each production mechanism was studied separately. The multi-phase simulations showed that ISC in fractured reservoirs is feasible. The study showed that ISC propagation is dependent on the oxygen diffusion coefficient, while matrix permeability plays an important role in oil production. Oil production was governed by gravity drainage and thermal effects. Heat transfer due to the movement of combustion front velocity in the study was minor when compared to heat transfer by conduction and convection. It was concluded that upscaling methods must also consider the different zones distinguished for oil saturation and temperatures. 15 refs., 2 tabs., 15 figs.

Combustion chemistry and formation of pollutants; Chimie de la combustion et formation des polluants

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-12-31

This book of proceedings reports on 7 papers on combustion chemistry and formation of pollutants presented during the workshop organized by the `Combustion and Flames` section of the French society of thermal engineers. The chemistry of combustion is analyzed in various situations such as: turbojet engines, spark ignition engines, industrial burners, gas turbines etc... Numerical simulation is used to understand the physico-chemical processes involved in combustion, to describe the kinetics of oxidation, combustion and flame propagation, and to predict the formation of pollutants. (J.S.)

Risk analysis of a biomass combustion process using MOSAR and FMEA methods.

Science.gov (United States)

Thivel, P-X; Bultel, Y; Delpech, F

2008-02-28

Thermal and chemical conversion processes that convert in energy the sewage sludge, pasty waste and other pre-processed waste are increasingly common, for economic and ecological reasons. Fluidized bed combustion is currently one of the most promising methods of energy conversion, since it burns biomass very efficiently, and produces only very small quantities of sulphur and nitrogen oxides. The hazards associated with biomass combustion processes are fire, explosion and poisoning from the combustion gases (CO, etc.). The risk analysis presented in this paper uses the MADS-MOSAR methodology, applied to a semi-industrial pilot scheme comprising a fluidization column, a conventional cyclone, two natural gas burners and a continuous supply of biomass. The methodology uses a generic approach, with an initial macroscopic stage where hazard sources are identified, scenarios for undesired events are recognized and ranked using a grid of SeverityxProbability and safety barriers suggested. A microscopic stage then analyzes in detail the major risks identified during the first stage. This analysis may use various different tools, such as HAZOP, FMEA, etc.: our analysis is based on FMEA. Using MOSAR, we were able to identify five subsystems: the reactor (fluidized bed and centrifuge), the fuel and biomass supply lines, the operator and the environment. When we drew up scenarios based on these subsystems, we found that malfunction of the gas supply burners was a common trigger in many scenarios. Our subsequent microscopic analysis, therefore, focused on the burners, looking at the ways they failed, and at the effects and criticality of those failures (FMEA). We were, thus, able to identify a number of critical factors such as the incoming gas lines and the ignition electrode.

Risk analysis of a biomass combustion process using MOSAR and FMEA methods

International Nuclear Information System (INIS)

Thivel, P.-X.; Bultel, Y.; Delpech, F.

2008-01-01

Thermal and chemical conversion processes that convert in energy the sewage sludge, pasty waste and other pre-processed waste are increasingly common, for economic and ecological reasons. Fluidized bed combustion is currently one of the most promising methods of energy conversion, since it burns biomass very efficiently, and produces only very small quantities of sulphur and nitrogen oxides. The hazards associated with biomass combustion processes are fire, explosion and poisoning from the combustion gases (CO, etc.). The risk analysis presented in this paper uses the MADS-MOSAR methodology, applied to a semi-industrial pilot scheme comprising a fluidization column, a conventional cyclone, two natural gas burners and a continuous supply of biomass. The methodology uses a generic approach, with an initial macroscopic stage where hazard sources are identified, scenarios for undesired events are recognized and ranked using a grid of Severity x Probability and safety barriers suggested. A microscopic stage then analyzes in detail the major risks identified during the first stage. This analysis may use various different tools, such as HAZOP, FMEA, etc.: our analysis is based on FMEA. Using MOSAR, we were able to identify five subsystems: the reactor (fluidized bed and centrifuge), the fuel and biomass supply lines, the operator and the environment. When we drew up scenarios based on these subsystems, we found that malfunction of the gas supply burners was a common trigger in many scenarios. Our subsequent microscopic analysis, therefore, focused on the burners, looking at the ways they failed, and at the effects and criticality of those failures (FMEA). We were, thus, able to identify a number of critical factors such as the incoming gas lines and the ignition electrode

Process engineering design of pathological waste incinerator with an integrated combustion gases treatment unit.

Science.gov (United States)

Shaaban, A F

2007-06-25

Management of medical wastes generated at different hospitals in Egypt is considered a highly serious problem. The sources and quantities of regulated medical wastes have been thoroughly surveyed and estimated (75t/day from governmental hospitals in Cairo). From the collected data it was concluded that the most appropriate incinerator capacity is 150kg/h. The objective of this work is to develop the process engineering design of an integrated unit, which is technically and economically capable for incinerating medical wastes and treatment of combustion gases. Such unit consists of (i) an incineration unit (INC-1) having an operating temperature of 1100 degrees C at 300% excess air, (ii) combustion-gases cooler (HE-1) generating 35m(3)/h hot water at 75 degrees C, (iii) dust filter (DF-1) capable of reducing particulates to 10-20mg/Nm(3), (iv) gas scrubbers (GS-1,2) for removing acidic gases, (v) a multi-tube fixed bed catalytic converter (CC-1) to maintain the level of dioxins and furans below 0.1ng/Nm(3), and (vi) an induced-draft suction fan system (SF-1) that can handle 6500Nm(3)/h at 250 degrees C. The residence time of combustion gases in the ignition, mixing and combustion chambers was found to be 2s, 0.25s and 0.75s, respectively. This will ensure both thorough homogenization of combustion gases and complete destruction of harmful constituents of the refuse. The adequate engineering design of individual process equipment results in competitive fixed and operating investments. The incineration unit has proved its high operating efficiency through the measurements of different pollutant-levels vented to the open atmosphere, which was found to be in conformity with the maximum allowable limits as specified in the law number 4/1994 issued by the Egyptian Environmental Affairs Agency (EEAA) and the European standards.

Development of flameless combustion; Desarrollo de la combustion sin flama

Energy Technology Data Exchange (ETDEWEB)

Flores Sauceda, M. Leonardo; Cervantes de Gortari, Jaime Gonzalo [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)]. E-mail: 8344afc@prodigy.net.mx; jgonzalo@servidor.unam.mx

2010-11-15

The paper intends contribute to global warming mitigation joint effort that develops technologies to capture the CO{sub 2} produced by fossil fuels combustion and to reduce emission of other greenhouse gases like the NO{sub x}. After reviewing existing combustion bibliography is pointed out that (a) touches only partial aspects of the collective system composed by Combustion-Heat transfer process-Environment, whose interactions are our primary interest and (b) most specialists think there is not yet a clearly winning technology for CO{sub 2} capture and storage. In this paper the study of combustion is focused as integrated in the aforementioned collective system where application of flameless combustion, using oxidant preheated in heat regenerators and fluent gas recirculation into combustion chamber plus appropriated heat and mass balances, simultaneously results in energy saving and environmental impact reduction. [Spanish] El trabajo pretende contribuir al esfuerzo conjunto de mitigacion del calentamiento global que aporta tecnologias para capturar el CO{sub 2} producido por la combustion de combustibles fosiles y para disminuir la emision de otros gases invernadero como NOx. De revision bibliografica sobre combustion se concluye que (a) trata aspectos parciales del sistema compuesto por combustion-proceso de trasferencia de calor-ambiente, cuyas interacciones son nuestro principal interes (b) la mayoria de especialistas considera no hay todavia una tecnologia claramente superior a las demas para captura y almacenaje de CO{sub 2}. Se estudia la combustion como parte integrante del mencionado sistema conjunto, donde la aplicacion de combustion sin flama, empleando oxidante precalentado mediante regeneradores de calor y recirculacion de gases efluentes ademas de los balances de masa y energia adecuados, permite tener simultaneamente ahorros energeticos e impacto ambiental reducido.

High Frequency Combustion Instabilities of LOx/CH4 Spray Flames in Rocket Engine Combustion Chambers

NARCIS (Netherlands)

Sliphorst, M.

2011-01-01

Ever since the early stages of space transportation in the 1940’s, and the related liquid propellant rocket engine development, combustion instability has been a major issue. High frequency combustion instability (HFCI) is the interaction between combustion and the acoustic field in the combustion

Non-traditional Process of Hydrogen Containing Fuel Mixtures Production for Internal-combustion Engines

Directory of Open Access Journals (Sweden)

Gennady G. Kuvshinov

2012-12-01

Full Text Available The article justifies the perspectives of development of the environmentally sound technology of hydrogen containing fuel mixtures for internal-combustion engines based on the catalytic process of low-temperature decomposition of hydrocarbons into hydrogen and nanofibrous carbon.

Investigating co-combustion characteristics of bamboo and wood.

Science.gov (United States)

Liang, Fang; Wang, Ruijuan; Jiang, Changle; Yang, Xiaomeng; Zhang, Tao; Hu, Wanhe; Mi, Bingbing; Liu, Zhijia

2017-11-01

To investigate co-combustion characteristics of bamboo and wood, moso bamboo and masson pine were torrefied and mixed with different blend ratios. The combustion process was examined by thermogravimetric analyzer (TGA). The results showed the combustion process of samples included volatile emission and oxidation combustion as well as char combustion. The main mass loss of biomass blends occurred at volatile emission and oxidation combustion stage, while that of torrefied biomass occurred at char combustion stage. With the increase of bamboo content, characteristic temperatures decreased. Compared with untreated biomass, torrefied biomass had a higher initial and burnout temperature. With the increase of heating rates, combustion process of samples shifted to higher temperatures. Compared with non-isothermal models, activation energy obtained from isothermal model was lower. The result is helpful to promote development of co-combustion of bamboo and masson pine wastes. Copyright © 2017 Elsevier Ltd. All rights reserved.

Effects of Injection Rate Profile on Combustion Process and Emissions in a Diesel Engine

Directory of Open Access Journals (Sweden)

Fuqiang Bai

2017-01-01

Full Text Available When multi-injection is implemented in diesel engine via high pressure common rail injection system, changed interval between injection pulses can induce variation of injection rate profile for sequential injection pulse, though other control parameters are the same. Variations of injection rate shape which influence the air-fuel mixing and combustion process will be important for designing injection strategy. In this research, CFD numerical simulations using KIVA-3V were conducted for examining the effects of injection rate shape on diesel combustion and emissions. After the model was validated by experimental results, five different shapes (including rectangle, slope, triangle, trapezoid, and wedge of injection rate profiles were investigated. Modeling results demonstrate that injection rate shape can have obvious influence on heat release process and heat release traces which cause different combustion process and emissions. It is observed that the baseline, rectangle (flat, shape of injection rate can have better balance between NOx and soot emissions than the other investigated shapes. As wedge shape brings about the lowest NOx emissions due to retarded heat release, it produces the highest soot emissions among the five shapes. Trapezoid shape has the lowest soot emissions, while its NOx is not the highest one. The highest NOx emissions were produced by triangle shape due to higher peak injection rate.

Process and device for automatic control of air ratio in combustion

Energy Technology Data Exchange (ETDEWEB)

Rohr, F J; Holick, H

1976-06-24

The device concerns a process for the automatic control of the air ratio in combustion, by setting the fuel-air mixture for combustion depending on the air number lambda. The control of the air ratio of combustion engines is carried out using a zirconium dioxide measuring probe, which is situated in the exhaust gas. It is a disadvantage that this is only sensitive for an air number lambda of 1. In order to achieve control of the air ratio for air numbers greater or smaller than 1, according to the invention an auxiliary gas is mixed with the hot exhaust gas, or a component of the gas is withdrawn, so that a corrected exhaust gas flow is produced, whose air number is detected by the measuring sensor and controlled to a value of about 1. The auxiliary gas flow is chosen so that an air ratio differing from lambda equals 1 is formed when the air number of the corrected exhaust gas flow is regulated to a value of lambda equals 1 approximately. In order to keep the demand for auxiliary gas low, only part of the exhaust gas flow is used for the measurement. The exhaust gas part flow is kept constant while the auxiliary gas flow or the removed component of gas flow are altered. Hydrogen or oxygen are used as auxiliary gases, depending whether excess or reduced air is required. Instead of hydrogen, fuel or its combustion products can be used. According to the invention, the hydrogen or oxygen can be produced electrolytically. Dosing takes place by the current used for electrolysis.

Computational fluid dynamics (CFD) analysis of the combustion process of a leather residuals gasification fuel gas: influence of fuel moisture content

Energy Technology Data Exchange (ETDEWEB)

Antonietti, Anderson Jose; Beskow, Arthur Bortolin; Silva, Cristiano Vitorino da [Universidade Regional Integrada do Alto Uruguai e das Missoes (URI), Erechim, RS (Brazil)], E-mails: arthur@uricer.edu.br, mlsperb@unisinos.br; Indrusiak, Maria Luiza Sperb [Universidade do Vale do Rio dos Sinos (UNISINOS), Sao Leopoldo, RS (Brazil)], E-mail: cristiano@uricer.edu.br

2010-07-01

This work presents a numerical study of the combustion process of leather residuals gasification gas, aiming the improvement of the process efficiency, considering different concentrations of water on the gas. The heating produced in this combustion process can be used to generation of thermal and/or electrical energy, for use at the leather industrial plant. However, the direct burning of this leather-residual-gas into the chambers is not straightforward. The alternative in development consists in processing this leather residuals by gasification or pyrolysis, separating the volatiles and products of incomplete combustion, for after use as fuel in a boiler. At these processes, different quantities of water can be used, resulting at different levels of moisture content in this fuel gas. This humidity can affect significantly the burning of this fuel, producing unburnt gases, as the carbon monoxide, or toxic gases as NOx, which must have their production minimized on the process, with the purpose of reducing the emission of pollutants to the atmosphere. Other environment-harmful-gases, remaining of the chemical treatment employed at leather manufacture, as cyanide, and hydrocarbons as toluene, must burn too, and the moisture content has influence on it. At this way, to increase understanding of the influence of moisture in the combustion process, it was made a numerical investigation study of reacting flow in the furnace, evaluating the temperature field, the chemical species concentration fields, flow mechanics and heat transfer at the process. The commercial CFD code CFX Ansys Inc. was used. Considering different moisture contents in the fuel used on the combustion process, with this study was possible to achieve the most efficient burning operation parameters, with improvement of combustion efficiency, and reduction of environmental harmful gases emissions. It was verified that the different moisture contents in the fuel gas demand different operation conditions

Development of High Efficiency Clean Combustion Engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines

Energy Technology Data Exchange (ETDEWEB)

Marriott, Craig; Gonzalez, Manual; Russell, Durrett

2011-06-30

This report summarizes activities related to the revised STATEMENT OF PROJECT OBJECTIVES (SOPO) dated June 2010 for the Development of High-Efficiency Clean Combustion engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines (COOPERATIVE AGREEMENT NUMBER DE-FC26-05NT42415) project. In both the spark- (SI) and compression-ignition (CI) development activities covered in this program, the goal was to develop potential production-viable internal combustion engine system technologies that both reduce fuel consumption and simultaneously met exhaust emission targets. To be production-viable, engine technologies were also evaluated to determine if they would meet customer expectations of refinement in terms of noise, vibration, performance, driveability, etc. in addition to having an attractive business case and value. Prior to this activity, only proprietary theoretical / laboratory knowledge existed on the combustion technologies explored The research reported here expands and develops this knowledge to determine series-production viability. Significant SI and CI engine development occurred during this program within General Motors, LLC over more than five years. In the SI program, several engines were designed and developed that used both a relatively simple multi-lift valve train system and a Fully Flexible Valve Actuation (FFVA) system to enable a Homogeneous Charge Compression Ignition (HCCI) combustion process. Many technical challenges, which were unknown at the start of this program, were identified and systematically resolved through analysis, test and development. This report documents the challenges and solutions for each SOPO deliverable. As a result of the project activities, the production viability of the developed clean combustion technologies has been determined. At this time, HCCI combustion for SI engines is not considered production-viable for several reasons. HCCI combustion is excessively sensitive to control variables

Simple model of inhibition of chain-branching combustion processes

Science.gov (United States)

Babushok, Valeri I.; Gubernov, Vladimir V.; Minaev, Sergei S.; Miroshnichenko, Taisia P.

2017-11-01

A simple kinetic model has been suggested to describe the inhibition and extinction of flame propagation in reaction systems with chain-branching reactions typical for hydrocarbon systems. The model is based on the generalised model of the combustion process with chain-branching reaction combined with the one-stage reaction describing the thermal mode of flame propagation with the addition of inhibition reaction steps. Inhibitor addition suppresses the radical overshoot in flame and leads to the change of reaction mode from the chain-branching reaction to a thermal mode of flame propagation. With the increase of inhibitor the transition of chain-branching mode of reaction to the reaction with straight-chains (non-branching chain reaction) is observed. The inhibition part of the model includes a block of three reactions to describe the influence of the inhibitor. The heat losses are incorporated into the model via Newton cooling. The flame extinction is the result of the decreased heat release of inhibited reaction processes and the suppression of radical overshoot with the further decrease of the reaction rate due to the temperature decrease and mixture dilution. A comparison of the results of modelling laminar premixed methane/air flames inhibited by potassium bicarbonate (gas phase model, detailed kinetic model) with the results obtained using the suggested simple model is presented. The calculations with the detailed kinetic model demonstrate the following modes of combustion process: (1) flame propagation with chain-branching reaction (with radical overshoot, inhibitor addition decreases the radical overshoot down to the equilibrium level); (2) saturation of chemical influence of inhibitor, and (3) transition to thermal mode of flame propagation (non-branching chain mode of reaction). The suggested simple kinetic model qualitatively reproduces the modes of flame propagation with the addition of the inhibitor observed using detailed kinetic models.

Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust

Science.gov (United States)

Wijmans, Johannes G [Menlo Park, CA; Merkel, Timothy C [Menlo Park, CA; Baker, Richard W [Palo Alto, CA

2012-05-15

A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

Twenty-fifth symposium (international) on combustion

International Nuclear Information System (INIS)

Anon.

1994-01-01

Approximately two-thirds of the papers presented at this conference are contained in this volume. The other one-third appear in special issues of ''Combustion and Flame'', Vol. 99, 1994 and Vol. 100, 1995. Papers are divided into the following sections: Supersonic combustion; Detonations and explosions; Internal combustion engines; Practical aspects of combustion; Incineration and wastes; Sprays and droplet combustion; Coal and organic solids combustion; Soot and polycyclic aromatic hydrocarbons; Reaction kinetics; NO x ; Turbulent flames; Turbulent combustion; Laminar flames; Flame spread, fire and halogenated fire suppressants; Global environmental effects; Ignition; Two-phase combustion; Solid propellant combustion; Materials synthesis; Microgravity; and Experimental diagnostics. Papers have been processed separately for inclusion on the data base

Effects of stepwise gas combustion on NOx generation

International Nuclear Information System (INIS)

Woperane Seredi, A.; Szepesi, E.

1999-01-01

To decrease NO x emission from gas boilers, the combustion process of gas has been modified from continuous combustion to step-wise combustion. In this process the combustion temperature, the temperature peaks in the flame, the residence time of combustion products in the high-temperature zone and the oxygen partial pressure are changed advantageously. Experiments were performed using multistage burners, and the NO x emission was recorded. It was found that the air factor of the primary combustion space has a determining effect on the NO x reduction. (R.P.)

Co-combustion of waste materials using fluidized bed technology

Energy Technology Data Exchange (ETDEWEB)

M. Lopes; I. Gulyurtlu; P. Abelha; T. Crujeira; D. Boavida; I. Cabrita [INETI-DEECA, Lisbon (Portugal)

2004-07-01

There is growing interest in using renewable fuels in order to sustain the CO{sub 2} accumulation. Several waste materials can be used as coal substitutes as long as they contain significant combustible matter, as for example MSW and sewage sludge. Besides the outcome of the energetic valorization of such materials, combustion must be regarded as a pre-treatment process, contributing to the safe management of wastes. Landfilling is an expensive management option and requires a previous destruction of the organic matter present in residues, since its degradation generates greenhouse gases and produces acidic organic leachates. Fluidized bed combustion is a promising technology for the use of mixtures of coal and combustible wastes. This paper presents INETI's experience in the co-combustion of coal with this kind of residues performed in a pilot fluidized bed. Both the RDF (from MSW and sewage sludge) and sewage sludge combustion problems were addressed, relating the gaseous emissions, the behaviour of metals and the leachability of ashes and a comparison was made between co-combustion and mono-combustion in order to verify the influence of the utilization of coal. 9 refs., 1 fig., 3 tabs.

The use of an electric field as a processing parameter in the combustion synthesis of ceramics and composites

International Nuclear Information System (INIS)

Munir, Z.A.

1996-01-01

The imposition of an electric field is shown to activate self-propagating combustion reactions and thus makes possible the synthesis of a variety of ceramic and composite phases. Experimental observations and modeling studies indicated that activation is accomplished by the localized effect of the current. The relationship between wave propagation and the direction of the applied field was investigated. The synthesis of composites by field-activated combustion synthesis (FACS) was demonstrated. It was shown that the imposition of a field during the combustion synthesis of MoSi 2 results in a decrease /in the product particle size. The results suggest that the field can be used as a processing parameter in self-propagating combustion synthesis

Chaotic combustion in spark ignition engines

International Nuclear Information System (INIS)

Wendeker, Miroslaw; Czarnigowski, Jacek; Litak, Grzegorz; Szabelski, Kazimierz

2003-01-01

We analyse the combustion process in a spark ignition engine using the experimental data of an internal pressure during the combustion process and show that the system can be driven to chaotic behaviour. Our conclusion is based on the observation of unperiodicity in the time series, suitable stroboscopic maps and a complex structure of a reconstructed strange attractor. This analysis can explain that in some circumstances the level of noise in spark ignition engines increases considerably due to nonlinear dynamics of a combustion process

A spectroscopy study of gasoline partially premixed compression ignition spark assisted combustion

International Nuclear Information System (INIS)

Pastor, J.V.; García-Oliver, J.M.; García, A.; Micó, C.; Durrett, R.

2013-01-01

Highlights: ► PPC combustion combined with spark assistance and gasoline fuel on a CI engine. ► Chemiluminescence of different chemical species describes the progress of combustion reaction. ► Spectra of a novel combustion mode under SACI conditions is described. ► UV–Visible spectrometry, high speed imaging and pressure diagnostic were employed for analysis. - Abstract: Nowadays many research efforts are focused on the study and development of new combustion modes, mainly based on the use of locally lean air–fuel mixtures. This characteristic, combined with exhaust gas recirculation, provides low combustion temperatures that reduces pollutant formation and increases efficiency. However these combustion concepts have some drawbacks, related to combustion phasing control, which must be overcome. In this way, the use of a spark plug has shown to be a good solution to improve phasing control in combination with lean low temperature combustion. Its performance is well reported on bibliography, however phenomena involving the combustion process are not completely described. The aim of the present work is to develop a detailed description of the spark assisted compression ignition mode by means of application of UV–Visible spectrometry, in order to improve insight on the combustion process. Tests have been performed in an optical engine by means of broadband radiation imaging and emission spectrometry. The engine hardware is typical of a compression ignition passenger car application. Gasoline was used as the fuel due to its low reactivity. Combining broadband luminosity images with pressure-derived heat-release rate and UV–Visible spectra, it was possible to identify different stages of the combustion reaction. After the spark discharge, a first flame kernel appears and starts growing as a premixed flame front, characterized by a low and constant heat-release rate in combination with the presence of remarkable OH radical radiation. Heat release increases

Combustion visualization and experimental study on spark induced compression ignition (SICI) in gasoline HCCI engines

International Nuclear Information System (INIS)

Wang Zhi; He Xu; Wang Jianxin; Shuai Shijin; Xu Fan; Yang Dongbo

2010-01-01

Spark induced compression ignition (SICI) is a relatively new combustion control technology and a promising combustion mode in gasoline engines with high efficiency. SICI can be divided into two categories, SACI and SI-CI. This paper investigated the SICI combustion process using combustion visualization and engine experiment respectively. Ignition process of SICI was captured by high speed photography in an optical engine with different compression ratios. The results show that SICI is a combustion mode combined with partly flame propagation and main auto-ignition. The spark ignites the local mixture near spark electrodes and the flame propagation occurs before the homogeneous mixture is auto-ignited. The heat release from central burned zone due to the flame propagation increases the in-cylinder pressure and temperature, resulting in the unburned mixture auto-ignition. The SICI combustion process can be divided into three stages of the spark induced stage, the flame propagation stage and the compression ignition stage. The SICI combustion mode is different from the spark ignition (SI) knocking in terms of the combustion and emission characteristics. Furthermore, three typical combustion modes including HCCI, SICI, SI, were compared on a gasoline direct injection engine with higher compression ratio and switchable cam-profiles. The results show that SICI has an obvious combustion characteristic with two-stage heat release and lower pressure rise rate. The SICI combustion mode can be controlled by spark timings and EGR rates and utilized as an effective method for high load extension on the gasoline HCCI engine. The maximum IMEP of 0.82 MPa can be achieved with relatively low NO x emission and high thermal efficiency. The SICI combustion mode can be applied in medium-high load region for high efficiency gasoline engines.

Combustion visualization and experimental study on spark induced compression ignition (SICI) in gasoline HCCI engines

Energy Technology Data Exchange (ETDEWEB)

Wang Zhi, E-mail: wangzhi@tsinghua.edu.c [State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084 (China); He Xu; Wang Jianxin; Shuai Shijin; Xu Fan; Yang Dongbo [State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084 (China)

2010-05-15

Spark induced compression ignition (SICI) is a relatively new combustion control technology and a promising combustion mode in gasoline engines with high efficiency. SICI can be divided into two categories, SACI and SI-CI. This paper investigated the SICI combustion process using combustion visualization and engine experiment respectively. Ignition process of SICI was captured by high speed photography in an optical engine with different compression ratios. The results show that SICI is a combustion mode combined with partly flame propagation and main auto-ignition. The spark ignites the local mixture near spark electrodes and the flame propagation occurs before the homogeneous mixture is auto-ignited. The heat release from central burned zone due to the flame propagation increases the in-cylinder pressure and temperature, resulting in the unburned mixture auto-ignition. The SICI combustion process can be divided into three stages of the spark induced stage, the flame propagation stage and the compression ignition stage. The SICI combustion mode is different from the spark ignition (SI) knocking in terms of the combustion and emission characteristics. Furthermore, three typical combustion modes including HCCI, SICI, SI, were compared on a gasoline direct injection engine with higher compression ratio and switchable cam-profiles. The results show that SICI has an obvious combustion characteristic with two-stage heat release and lower pressure rise rate. The SICI combustion mode can be controlled by spark timings and EGR rates and utilized as an effective method for high load extension on the gasoline HCCI engine. The maximum IMEP of 0.82 MPa can be achieved with relatively low NO{sub x} emission and high thermal efficiency. The SICI combustion mode can be applied in medium-high load region for high efficiency gasoline engines.

Underground treatment of combustible minerals

Energy Technology Data Exchange (ETDEWEB)

Sarapuu, E

1954-10-14

A process is described for treating oil underground, consisting in introducing several electrodes spaced one from the other in a bed of combustibles underground so that they come in electric contact with this bed of combustibles remaining insulated from the ground, and applying to the electrodes a voltage sufficient to produce an electric current across the bed of combustibles, so as to heat it and create an electric connection between the electrodes on traversing the bed of combustibles.

Fuel accountability and control at Combustion Engineering, Inc

International Nuclear Information System (INIS)

Kersteen, G.C.

1978-01-01

Combustion Engineering, Inc. has recently developed and installed an automated data collection, data processing system for the accounting and control of special nuclear material. The system uses a variety of data collection techniques and some relatively new data processing ideas. The next few pages describe the Fuel Accountability and Control System

SELECTION OF SUSTAINABLE TECHNOLOGIES FOR COMBUSTION OF BOSNIAN COALS

Directory of Open Access Journals (Sweden)

Anes Kazagić

2010-01-01

Full Text Available This paper deals with optimization of coal combustion conditions to support selection a sustainable combustion technology and an optimal furnace and boiler design. A methodology for optimization of coal combustion conditions is proposed and demonstrated on the example of Bosnian coals. The properties of Bosnian coals vary widely from one coal basin to the next, even between coal mines within the same basin. Very high percentage of ash (particularly in Bosnian brown coal makes clear certain differences between Bosnian coal types and other world coal types, providing a strong argument for investigating specific problems related to the combustion of Bosnian coals, as well as ways to improve their combustion behaviour. In this work, options of the referent energy system (boiler with different process temperatures, corresponding to the different combustion technologies; pulverised fuel combustion (slag tap or dry bottom furnace and fluidized bed combustion, are under consideration for the coals tested. Sustainability assessment, based on calculation economic and environment indicators, in combination with common low cost planning method, is used for the optimization. The total costs in the lifetime are presented by General index of total costs, calculated on the base of agglomeration of basic economic indicators and the economic indicators derived from environmental indicators. So, proposed methodology is based on identification of those combustion technologies and combustion conditions for coals tested for which the total costs in lifetime of the system under consideration are lowest, provided that all environmental issues of the energy system is fulfilled during the lifetime. Inputs for calculation of the sustainability indicators are provided by the measurements on an experimental furnace with possibility of infinite variation of process temperature, supported by good praxis from the power plants which use the fuels tested and by thermal

Greenhouse impact due to the use of combustible fuels: life cycle viewpoint and relative radiative forcing commitment.

Science.gov (United States)

Kirkinen, Johanna; Palosuo, Taru; Holmgren, Kristina; Savolainen, Ilkka

2008-09-01

Extensive information on the greenhouse impacts of various human actions is important in developing effective climate change mitigation strategies. The greenhouse impacts of combustible fuels consist not only of combustion emissions but also of emissions from the fuel production chain and possible effects on the ecosystem carbon storages. It is important to be able to assess the combined, total effect of these different emissions and to express the results in a comprehensive way. In this study, a new concept called relative radiative forcing commitment (RRFC) is presented and applied to depict the greenhouse impact of some combustible fuels currently used in Finland. RRFC is a ratio that accounts for the energy absorbed in the Earth system due to changes in greenhouse gas concentrations (production and combustion of fuel) compared to the energy released in the combustion of fuel. RRFC can also be expressed as a function of time in order to give a dynamic cumulative picture on the caused effect. Varying time horizons can be studied separately, as is the case when studying the effects of different climate policies on varying time scales. The RRFC for coal for 100 years is about 170, which means that in 100 years 170 times more energy is absorbed in the atmosphere due to the emissions of coal combustion activity than is released in combustion itself. RRFC values of the other studied fuel production chains varied from about 30 (forest residues fuel) to 190 (peat fuel) for the 100-year study period. The length of the studied time horizon had an impact on the RRFC values and, to some extent, on the relative positions of various fuels.

IMPROVED COMBUSTION PROCESSES IN MEDICAL WASTES ...

African Journals Online (AJOL)

A small rig was designed for conducting tests on the incineration of rural clinical wastes in Botswana. Experimental results showed that if proper combustion conditions are applied to low technology rural clinical waste incinerators, the operating temperatures could increase from around 400 to above 850oC. It was ...

CFD analysis of the pulverized coal combustion processes in a 160 MWe tangentially-fired-boiler of a thermal power plant

Energy Technology Data Exchange (ETDEWEB)

Silva, Cristiano V. da; Beskow, Arthur B. [Universidade Regional Integrada do Alto Uruguai e das Misses (LABSIM/GEAPI/URI), Erechim, RS (Brazil). Dept. de Engenharia e Ciencia da Computacao. Grupo de Engenharia Aplicada a Processos Industriais], Emails: cristiano@uricer.edu.br, Arthur@uricer.edu.br; Indrusiak, Maria Luiza S. [Universidade do Vale do Rio dos Sinos (UNISINOS), Sao Leopoldo, RS (Brazil). Programa de Engenharia Mecanica], E-mail: sperbindrusiak@via-rs.net

2010-10-15

The strategic role of energy and the current concern with greenhouse effects, energetic and exegetic efficiency of fossil fuel combustion greatly enhance the importance of the studies of complex physical and chemical processes occurring inside boilers of thermal power plants. The state of the art in computational fluid dynamics and the availability of commercial codes encourage numeric studies of the combustion processes. In the present work the commercial software CFX Ansys Europe Ltd. was used to study the combustion of coal in a 160 MWe commercial thermal power plant with the objective of simulating the operational conditions and identifying factors of inefficiency. The behavior of the flow of air and pulverized coal through the burners was analyzed, and the three-dimensional flue gas flow through the combustion chamber and heat exchangers was reproduced in the numeric simulation. (author)

Analysis the ECFM-3Z Combustion Model for Simulating the Combustion Process and Emission Characteristics in a HSDI Diesel Engine

Directory of Open Access Journals (Sweden)

Raouf Mobasheri

2015-12-01

Full Text Available An advanced CFD simulation has been performed to analyze the ECFM-3Z (Extended Coherent Flame Model-3Z combustion model for simulating the combustion process and emission characteristics in a high speed direct injection (HSDI diesel engine. A four cylinders, HSDI diesel engine based on a Ford production engine with a 2nd generation Delphi common rail fuel injection system has been modeled in this research. 3D CFD simulation was carried out from intake valve closing (IVC to exhaust valve opening (EVO. A good agreement of calculated and measured in-cylinder pressure trace as well as pollutant formation trends could be observed for all investigated operating points. Based on the confidence gained from validation, the study is extended to evaluate the effect of fuel injection timing on engine performance and emissions. For this purpose, a comprehensive study of the effect of injection timing with respect to performance and emissions has been considered. Three main injection timing, (1 2.65 BTDC, (2 0.65 BTDC and (3 1.35 ATDC, all with 30 crank angle pilot separations has been used to investigate the effect of the injection timing. The results show that the current methodology can be applied as a beneficial tool for analyzing the parameters of the diesel combustion under HSDI operating condition.

A thermodynamic analysis of the environmental indicators of natural gas combustion processes

Science.gov (United States)

Elsukov, V. K.

2010-07-01

Environmental indicators of the natural gas combustion process are studied using the model of extreme intermediate states developed at the Melent’ev Institute of Power Engineering Systems. Technological factors responsible for generation of polycyclic aromatic hydrocarbons and hydrogen cyanide are revealed. Measures for reducing the amounts of polycyclic aromatic hydrocarbons, hydrogen cyanide, nitrogen oxide, and other pollutants emitted from boilers are developed.

Mechanisms and kinetics of granulated sewage sludge combustion.

Science.gov (United States)

Kijo-Kleczkowska, Agnieszka; Środa, Katarzyna; Kosowska-Golachowska, Monika; Musiał, Tomasz; Wolski, Krzysztof

2015-12-01

This paper investigates sewage sludge disposal methods with particular emphasis on combustion as the priority disposal method. Sewage sludge incineration is an attractive option because it minimizes odour, significantly reduces the volume of the starting material and thermally destroys organic and toxic components of the off pads. Additionally, it is possible that ashes could be used. Currently, as many as 11 plants use sewage sludge as fuel in Poland; thus, this technology must be further developed in Poland while considering the benefits of co-combustion with other fuels. This paper presents the results of experimental studies aimed at determining the mechanisms (defining the fuel combustion region by studying the effects of process parameters, including the size of the fuel sample, temperature in the combustion chamber and air velocity, on combustion) and kinetics (measurement of fuel temperature and mass changes) of fuel combustion in an air stream under different thermal conditions and flow rates. The combustion of the sludge samples during air flow between temperatures of 800 and 900°C is a kinetic-diffusion process. This process determines the sample size, temperature of its environment, and air velocity. The adopted process parameters, the time and ignition temperature of the fuel by volatiles, combustion time of the volatiles, time to reach the maximum temperature of the fuel surface, maximum temperature of the fuel surface, char combustion time, and the total process time, had significant impacts. Copyright © 2015 Elsevier Ltd. All rights reserved.

Multi-stage combustion using nitrogen-enriched air

Science.gov (United States)

Fischer, Larry E.; Anderson, Brian L.

2004-09-14

Multi-stage combustion technology combined with nitrogen-enriched air technology for controlling the combustion temperature and products to extend the maintenance and lifetime cycles of materials in contact with combustion products and to reduce pollutants while maintaining relatively high combustion and thermal cycle efficiencies. The first stage of combustion operates fuel rich where most of the heat of combustion is released by burning it with nitrogen-enriched air. Part of the energy in the combustion gases is used to perform work or to provide heat. The cooled combustion gases are reheated by additional stages of combustion until the last stage is at or near stoichiometric conditions. Additional energy is extracted from each stage to result in relatively high thermal cycle efficiency. The air is enriched with nitrogen using air separation technologies such as diffusion, permeable membrane, absorption, and cryogenics. The combustion method is applicable to many types of combustion equipment, including: boilers, burners, turbines, internal combustion engines, and many types of fuel including hydrogen and carbon-based fuels including methane and coal.

Key factors of combustion from kinetics to gas dynamics

CERN Document Server

Rubtsov, Nikolai M

2017-01-01

This book summarizes the main advances in the mechanisms of combustion processes. It focuses on the analysis of kinetic mechanisms of gas combustion processes and experimental investigation into the interrelation of kinetics and gas dynamics in gas combustion. The book is complimentary to the one previously published, The Modes of Gaseous Combustion.

Combustion of Waste Wood. Second phase of the collaboration project on waste wood combustion

International Nuclear Information System (INIS)

Andersson, Annika; Andersson, Christer; Eriksson, Jan; Hemstroem, Bengt; Jungstedt, Jenny; Kling, Aasa; Bahr, Bo von; Ekvall, Annika; Eskilsson, David; Tullin, Claes; Harnevie, Henrik; Sieurin, Jan; Keihaes, Juha; Mueller, Christian; Berg, Magnus; Wikman, Karin

2003-08-01

Combustion of waste wood has during the last decade increased dramatically and this has resulted in a number of Swedish plants using this fuel, e.g. Handeloe P11 (Norrkoeping) and ldbaecken P3 (Nykoeping), and yet other plants that are under construction (e.g. Nynaeshamn). The experience from these plants are that waste wood combustion results in a number of operational problems. To some extent these problems are different compared with the problems related to combustion of other biofuels but the situation is not directly comparable to waste incinerators. The problems are mainly related to slagging and fouling of heat exchanger surfaces and accelerated corrosion at relatively low temperature compared to the situation for ordinary biofuels. In some cases an increase in the emissions of specific substances can also result in difficulties to fulfil the EC-directive on waste combustion. Within previous projects the main problems related to combustion of waste wood have been identified and to some extent the cause of these problems has been clarified. One result of this reported investigation is a deeper understanding of the actual causes of these problems. However, the most important result is a number of recommendations for different measures on how to achieve disturbance-free combustion of waste wood. These recommendations actually summarises the most important possible solutions on how to achieve a disturbance-free operation and a lower maintenance cost for boilers combusting waste wood and can thereby be regarded as a short summery of the whole project: 1) Improving fuel quality by Improved sorting at the source and Sieving of the fuel -> Reducing the amount of metals and chlorine and Separation of fines and thereby reducing the amount of metals. 2) Combustion modifications by Avoiding reducing conditions at the heat exchanger surfaces -> Minimising slagging, fouling and corrosion. 3) Additives or co-combustion by Addition of sulphur with the fuel; Injection of

CFD analysis of combustion of natural gas and syngas from biomass pyrolysis in the combustion chamber of a micro gas turbine

Energy Technology Data Exchange (ETDEWEB)

Fantozzi, Francesco; Laranci, Paolo; D' Alessandro, Bruno [University of Perugia (DII/UNIPG) (Italy). Dept. of Industrial Engineering], Emails: fanto@unipg.it, paolo.laranci@unipg.it, dalessandro@bio-net.it

2009-07-01

Micro gas turbines (MGT) can be profitably used for the production of distributed energy (DE), with the possibility to use gaseous fuels with low BTU derived from biomass or waste through the pyrolysis or gasification processes. These synthesis gases (SG) show significant differences with respect to natural gas (NG), in terms of composition, calorific value, content of hydrogen, tar and particulate matter content; such differences can be turn into problems of ignition, instability burning, difficulties in controlling the emissions and fouling. CFD analysis of the combustion process is an essential tool for identifying the main critical arising in using these gases, in order to modify existing geometries and to develop new generation of combustor for use with low BTU gases. This paper describes the activities of experimental and numerical analysis carried out to study the combustion process occurring inside an existing annular Rich-Quench-Lean (RQL) Combustion Chamber (CC) of a 80 kW MGT. In the paper some results of a CFD study of the combustion process performed with an original developed chemical models are reported in terms of temperature and velocity distributions inside the CC and in terms of compositions of turbine inlet gas and of its thermodynamic parameters (mass flow, temperature, pressure). An evaluation of pollutant emissions of CO, CO{sub 2} and NOx and a comparison with the available experimental data relating to the case of combustion of NG is also provided in the paper. Moreover, the carried out investigation concerns the case of operation with a SG fuel derived from biomass in an Integrated Pyrolysis Regenerated Plant (IPRP). (author)

Control device for combustible gas concentration

International Nuclear Information System (INIS)

Osawa, Yasuo.

1988-01-01

Purpose: To control the concentration of combustible gases such as hydrogen evolved in a reactor container upon loss-of-coolant accidents. Constitution: Combustible gases evolved from the lower area of a drywell in which a combustible atmosphere is liable to be formed locally are taken out through a take-out pipeway to the outside of a reactor container and processed by a hydrogen-oxygen recombiner. Combustible gases in other areas of the drywell are also introduced to the lower area of the drywell and then taken-out externally for procession. Further, combustible gases in the suppression chamber are introduced by the opening of a vacuum breaking valve through a gas supply pipe to the lower area of the drywell and fluids in the drywell are stirred and diluted with fluids exhausted from the gas supply pipe. Disposition of such take-out pipeway and gas supply pipe can reduce the possibility of forming local combustible atmosphere to improve the integrity of the reactor container. (Kamimura, M.)

New technologies reducing emissions from combustion of biofuels

International Nuclear Information System (INIS)

Oravainen, H.

1997-01-01

In reducing CO 2 emissions, bioenergy will be the most important source of renewable energy in the next few decades. In principle, combustion of biomass is friendly to the environment because CO 2 released during combustion is recycled back into natural circulation. Biofuels normally contain little nitrogen and sulphur. However, depending on the combustion technology used, emissions may be quite high. This is true of combustion of biomass fuels in small appliances like wood stoves, fireplaces, small boilers etc. When fuels having high content of volatile matter are burnt in appliances using batch type combustion, the process is rather an unsteady-state combustion. Emissions of carbon monoxide, other combustible gases and particulates are quite difficult to avoid. With continuous combustion processes this is not normally a problem. This conference paper presents some means of reducing emissions from combustion of biofuels. 5 refs., 4 figs

Comparison of thermal and radical effects of EGR gases on combustion process in dual fuel engines at part loads

International Nuclear Information System (INIS)

Pirouzpanah, V.; Khoshbakhti Saray, R.; Sohrabi, A.; Niaei, A.

2007-01-01

Dual fuel engines at part load inevitably suffer from lower thermal efficiency and higher emission of carbon monoxide and unburned fuel. This work is conducted to investigate the combustion characteristics of a dual fuel (Diesel-gas) engine at part loads using a single zone combustion model with detailed chemical kinetics for combustion of natural gas fuel. In this home made software, the presence of the pilot fuel is considered as a heat source that is deriving form two superposed Wiebe's combustion functions to account for its contribution to ignition of the gaseous fuel and the rest of the total released energy. The chemical kinetics mechanism consists of 112 reactions with 34 species. This combustion model is able to establish the development of the combustion process with time and the associated important operating parameters, such as pressure, temperature, heat release rate (HRR) and species concentration. Therefore, this work is an attempt to investigate the combustion phenomenon at part load and using exhaust gas recirculation (EGR) to improve the above mentioned problems. Also, the results of this work show that each of the different cases of EGR (thermal, chemical and radical cases) has an important role on the combustion process in dual fuel engines at part loads. It is found that all the different cases of EGR have positive effects on the performance and emission parameters of dual fuel engines at part loads despite the negative effect of some diluent gases in the chemical case, which moderates too much the positive effects of the thermal and radical cases of EGR. Predicted values show good agreement with corresponding experimental values over the whole range of engine operating conditions. Implications will be discussed in detail

Experimental validation for combustion analysis of GOTHIC code in 2-dimensional combustion chamber

International Nuclear Information System (INIS)

Lee, J. W.; Yang, S. Y.; Park, K. C.; Jung, S. H.

2002-01-01

In this study, the prediction capability of GOTHIC code for hydrogen combustion phenomena was validated with the results of two-dimensional premixed hydrogen combustion experiment executed by Seoul National University. The experimental chamber has about 24 liter free volume (1x0.024x1 m 3 ) and 2-dimensional rectangular shape. The test were preformed with 10% hydrogen/air gas mixture and conducted with combination of two igniter positions (top center, top corner) and two boundary conditions (bottom full open, bottom right half open). Using the lumped parameter and mechanistic combustion model in GOTHIC code, the SNU experiments were simulated under the same conditions. The GOTHIC code prediction of the hydrogen combustion phenomena did not compare well with the experimental results. In case of lumped parameter simulation, the combustion time was predicted appropriately. But any other local information related combustion phenomena could not be obtained. In case of mechanistic combustion analysis, the physical combustion phenomena of gas mixture were not matched experimental ones. In boundary open cases, the GOTHIC predicted very long combustion time and the flame front propagation could not simulate appropriately. Though GOTHIC showed flame propagation phenomenon in adiabatic calculation, the induction time of combustion was still very long compare with experimental results. Also, it was found that the combustion model of GOTHIC code had some weak points in low concentration of hydrogen combustion simulation

Processes subject to integrated pollution control. Combustion processes: reheat and heat treatment furnaces 50 MW(th) and over

International Nuclear Information System (INIS)

1995-01-01

This document, part of a series offering guidance on pollution control regulations issued by Her Majesty's Inspectorate of Pollution, focuses on combustion processes involved with reheat and heat treatment furnaces of 50 MW (th) and over. Techniques for controlling releases into air, water and to land are detailed as are the various pollution monitoring strategies. (UK)

Sulfur retention by ash during coal combustion. Part I. A model of char particle combustion

Directory of Open Access Journals (Sweden)

BORISLAV GRUBOR

2003-02-01

Full Text Available A model for the combustion of porous char particles as a basis for modeling the process of sulfur retention by ash during coal combustion is developed in this paper. The model belongs to the microscopic intrinsic models and describes the dynamic behavior of a porous char particle during comustion, taking into account temporal and spatial changes of all important physical properties of the char particle and various combustion parameters. The parametric analysis of the enhanced model shows that the model represents a good basis for the development of a model for the process of sulfur retention by ash during coal combustion. The model enables the prediction of the values of all parameters necessary for the introduction of reactions between sulfur compounds and mineral components in ash, primarily calcium oxide.

Analysis of combustion efficiency in a pelletizing furnace

Directory of Open Access Journals (Sweden)

Rafael Simões Vieira de Moura

Full Text Available Abstract The objective of this research is to assess how much the improvement in the combustion reaction efficiency can reduce fuel consumption, maintaining the same thermal energy rate provided by the reaction in a pelletizing furnace. The furnace for pelletizing iron ore is a complex thermal machine, in terms of energy balance. It contains recirculation fan gases and constant variations in the process, and the variation of a single process variable can influence numerous changes in operating conditions. This study demonstrated how the main variables related to combustion in the burning zone influence fuel consumption (natural gas from the furnace of the Usina de Pelotização de Fábrica (owned by VALE S/A, without changing process conditions that affect production quality. Variables were analyzed regarding the velocity and pressure of the fuel in the burners, the temperature of the combustion air and reactant gases, the conversion rate and the stoichiometric air/fuel ratio of the reaction. For the analysis, actual data of the furnace in operation was used, and for the simulation of chemical reactions, the software Gaseq® was used. The study showed that the adjustment of combustion reaction stoichiometry provides a reduction of 9.25% in fuel consumption, representing a savings of US$ 2.6 million per year for the company.

A combustion model of vegetation burning in "Tiger" fire propagation tool

Science.gov (United States)

Giannino, F.; Ascoli, D.; Sirignano, M.; Mazzoleni, S.; Russo, L.; Rego, F.

2017-11-01

In this paper, we propose a semi-physical model for the burning of vegetation in a wildland fire. The main physical-chemical processes involved in fire spreading are modelled through a set of ordinary differential equations, which describe the combustion process as linearly related to the consumption of fuel. The water evaporation process from leaves and wood is also considered. Mass and energy balance equations are written for fuel (leaves and wood) assuming that combustion process is homogeneous in space. The model is developed with the final aim of simulating large-scale wildland fires which spread on heterogeneous landscape while keeping the computation cost very low.

Analysis of energy cascade utilization in a chemically recuperated scramjet with indirect combustion

International Nuclear Information System (INIS)

Qin, Jiang; Cheng, Kunlin; Zhang, Silong; Zhang, Duo; Bao, Wen; Han, Jiecai

2016-01-01

The working process of scramjet with regenerative cooling, which was actually the chemical recuperation process, was analyzed in view of energy cascade utilization. The indirect combustion was realized through pyrolysis reaction of fuel. The relative yields of thermal exergy obtained by indirect combustion have been predicted both assuming an ideal pyrolysis reaction and using the experimental results of thermal pyrolysis of n-decane. The results showed that the influence mechanism of regenerative cooling improved the scramjet engine performance by the energy cascade utilization, and the combustion process was supposed to be designed with the cooling process together to utilize the chemical energy of fuel in a more effective way. A maximum value of 11% of the relative yield was obtained with the ideal pyrolysis reaction while a value less than 3% existed in the thermal pyrolysis experiments because of the domination of chemical kinetics rather than chemical thermodynamics in the real experiments. In spite of the difference between the ideal and the present experimental results, the indirect combustion was prospective to achieve a better energy cascade utilization in a chemically recuperated scramjet if the pyrolysis reaction was further optimized. The results in this paper were beneficial for the performance optimization of a regenerative cooling scramjet. - Highlights: • A new method of energy cascade utilization in a chemically recuperated scramjet. • 11% exergy loss is reduced by ideal pyrolysis reaction with indirect combustion. • Regenerative cooling with chemical recuperation can improve engine performance.

Burning Questions in Gravity-Dependent Combustion Science

Science.gov (United States)

Urban, David; Chiaramonte, Francis P.

2012-01-01

Building upon a long history of spaceflight and ground based research, NASA's Combustion Science program has accumulated a significant body of accomplishments on the ISS. Historically, NASAs low-gravity combustion research program has sought: to provide a more complete understanding of the fundamental controlling processes in combustion by identifying simpler one-dimensional systems to eliminate the complex interactions between the buoyant flow and the energy feedback to the reaction zone to provide realistic simulation of the fire risk in manned spacecraft and to enable practical simulation of the gravitational environment experienced by reacting systems in future spacecraft. Over the past two decades, low-gravity combustion research has focused primarily on increasing our understanding of fundamental combustion processes (e.g. droplet combustion, soot, flame spread, smoldering, and gas-jet flames). This research program was highly successful and was aided by synergistic programs in Europe and in Japan. Overall improvements were made in our ability to model droplet combustion in spray combustors (e.g. jet engines), predict flame spread, predict soot production, and detect and prevent spacecraft fires. These results provided a unique dataset that supports both an active research discipline and also spacecraft fire safety for current and future spacecraft. These experiments have been conducted using the Combustion Integrated Rack (CIR), the Microgravity Science Glovebox and the Express Rack. In this paper, we provide an overview of the earlier space shuttle experiments, the recent ISS combustion experiments in addition to the studies planned for the future. Experiments in combustion include topics such as droplet combustion, gaseous diffusion flames, solid fuels, premixed flame studies, fire safety, and super critical oxidation processes.

Advanced methods for processing ceramics

Energy Technology Data Exchange (ETDEWEB)

Carter, W.B. [Georgia Institute of Technology, Atlanta, GA (United States)

1997-04-01

Combustion chemical vapor deposition (combustion CVD) is being developed for the deposition of high temperature oxide coatings. The process is being evaluated as an alternative to more capital intensive conventional coating processes. The thrusts during this reporting period were the development of the combustion CVD process for depositing lanthanum monazite, the determination of the influence of aerosol size on coating morphology, the incorporation of combustion CVD coatings into thermal barrier coatings (TBCs) and related oxidation research, and continued work on the deposition of zirconia-yttria coatings.

Catalytic combustion for the elimination of methane, BTEX and other VOC : IV

International Nuclear Information System (INIS)

Hayes, R.E.; Wanke, S.E.

2008-01-01

Options for volatile organic compound combustion include homogeneous combustion (flaring) or catalytic combustion involving a flameless combustion process that uses a solid catalyst to promote the combustion reaction. This presentation discussed relative reactivity testing for volatile organic compounds (VOCs) over commercial catalysts. Several commercial pad catalysts were tested, as well as other powders. The relative reactivity of methane as well as benzene, toluene, ethylbenzene, and xylene (BTEX) were investigated. The purpose of the project was to evaluate combustion of concentrated methane streams that contained BTEX compounds; evaluate catalytic combustion using a counter diffusive radiant heater; develop mathematical models for the reactor to enhance design and understanding; improve the catalyst for BTEX combustion; and target application-dehydrator units. Topics that were addressed in the presentation included methane and benzene conversion; catalytic radiant heaters; small industrial and commercial units; measured temperature distribution; fuel slippage, methane conversion; the effect of water and hydrocarbons; the effect of water-liquid injection; and water addition as vapour. Several observations were offered, including that high percentages of injected liquid water can reduce reactor operating temperature; combustion of BTEX remained highly efficient, however liquid injection could also cause temperature reductions and ultimately the reactor would extinguish; and pre-heating the feed can eliminate the temperature drop and pad wetness problem. It was concluded that BTEX compounds are reactive, and the technology appears promising. 19 figs

Catalytic combustion for the elimination of methane, BTEX and other VOC : IV

Energy Technology Data Exchange (ETDEWEB)

Hayes, R.E.; Wanke, S.E. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical and Materials Engineering

2008-07-01

Options for volatile organic compound combustion include homogeneous combustion (flaring) or catalytic combustion involving a flameless combustion process that uses a solid catalyst to promote the combustion reaction. This presentation discussed relative reactivity testing for volatile organic compounds (VOCs) over commercial catalysts. Several commercial pad catalysts were tested, as well as other powders. The relative reactivity of methane as well as benzene, toluene, ethylbenzene, and xylene (BTEX) were investigated. The purpose of the project was to evaluate combustion of concentrated methane streams that contained BTEX compounds; evaluate catalytic combustion using a counter diffusive radiant heater; develop mathematical models for the reactor to enhance design and understanding; improve the catalyst for BTEX combustion; and target application-dehydrator units. Topics that were addressed in the presentation included methane and benzene conversion; catalytic radiant heaters; small industrial and commercial units; measured temperature distribution; fuel slippage, methane conversion; the effect of water and hydrocarbons; the effect of water-liquid injection; and water addition as vapour. Several observations were offered, including that high percentages of injected liquid water can reduce reactor operating temperature; combustion of BTEX remained highly efficient, however liquid injection could also cause temperature reductions and ultimately the reactor would extinguish; and pre-heating the feed can eliminate the temperature drop and pad wetness problem. It was concluded that BTEX compounds are reactive, and the technology appears promising. 19 figs.

Emission of pollutants from the combustion of composite fuels by metallurgical processes

Directory of Open Access Journals (Sweden)

J. Łabaj

2015-10-01

Full Text Available This paper presents the results of the study on emission characteristics of pollutants resulting from combustion process of composite alternative fuels for use in the processes of pyrometallurgy of copper as an alternative fuel to currently used coke breeze. These fuels are mainly based on waste carrier of “C” element, and the composition of the fuel is modelled in order to obtain the appropriate energy and emission parameters as well as strength parameters. These studies confirmed the possibility of using composite fuels as an alternative reducing agent as well as an energy carrier in the processes of pyrometallurgy of copper.

Comparison methods between methane and hydrogen combustion for useful transfer in furnaces

International Nuclear Information System (INIS)

Ghiea, V.V.

2009-01-01

The advantages and disadvantages of hydrogen use by industrial combustion are critically presented. Greenhouse effect due natural water vapors from atmosphere and these produced by hydrogen industrial combustion is critically analyzed, together with problems of gas fuels containing hydrogen as the relative largest component. A comparison method between methane and hydrogen combustion for pressure loss in burner feeding pipe, is conceived. It is deduced the ratio of radiation useful heat transfer characteristics and convection heat transfer coefficients from combustion gases at industrial furnaces and heat recuperators for hydrogen and methane combustion, establishing specific comparison methods. Using criterial equations special processed for convection heat transfer determination, a calculation generalizing formula is established. The proposed comparison methods are general valid for different gaseous fuels. (author)

Review of Membrane Oxygen Enrichment for Efficient Combustion

Science.gov (United States)

Ariono, Danu; Kusuma Wardani, Anita

2017-07-01

Oxygen enrichment from air is a simple way of increasing the efficiency of combustion process, as in oxy-combustion. Oxy-combustion has become one of the most attracting combustion technologies because of its potential to address both pollutant reduction and CO2 capture. In oxy-combustion, the fuel and recycled flue gas are combusted with oxygen enriched air (OEA). By using OEA, many benefits can be obtained, such as increasing available heat, improving ignition characteristics, flue gas reduction, increasing productivity, energy efficiency, turndown ratio, and flame stability. Membrane-based gas separation for OEA production becomes an attractive technology over the conventional technology due to the some advantages, including low capital cost, low energy consumption, compact size, and modularity. A single pass through membrane usually can enrich O2 concentration in the air up to 35% and a 50% concentration can be achieved with a double pass of membrane. The use of OEA in the combustion process eliminates the presence of nitrogen in the flue gas. Hence, the flue gas is mainly composed of CO2 and condensable water that can be easily separated. This paper gives an overview of oxy-combustion with membrane technology for oxygen enrichment process. Special attention is given to OEA production and the effect of OEA to the efficiency of combustion.

Reactivity studies of rice husk combustion using TGA

International Nuclear Information System (INIS)

Ismail, A.F.; Shamsuddin, A.H.; Mahdi, F.M.A.

2000-01-01

The reactivity of rice husks combustion is systematically studied the thermogravimetric analyzer (TGA). The kinetic parameters are determined from the Arrhenius plots based on the data of weight loss over temperature at different combustion heating rates. The results of proximate analysis (the moisture, volatile matters, fixed carbon, and ash contents) are also presented in this paper. The effects of process conditions on the self-ignition phenomenon of rice husk combustion are quantified. Finally, these results and compared with results for coal combustion. This research is part of the work to determine the optimal process conditions of rice husk combustion for energy production. (Author)

Application of pulse combustion technology in spray drying process

Directory of Open Access Journals (Sweden)

I. Zbicinski

2000-12-01

Full Text Available The paper presents development of valved pulse combustor designed for application in drying process and drying tests performed in a specially built installation. Laser technique was applied to investigate the flow field and structure of dispersed phase during pulse combustion spray drying process. PDA technique was used to determine initial atomization parameters as well as particle size distribution, velocity of the particles, mass concentration of liquid phase in the cross section of spray stream, etc., in the drying chamber during drying tests. Water was used to estimate the level of evaporation and 5 and 10% solutions of sodium chloride to carry out drying tests. The Computational Fluid Dynamics technique was used to perform theoretical predictions of time-dependent velocity, temperature distribution and particle trajectories in the drying chamber. Satisfactory agreement between calculations and experimental results was found in certain regions of the drying chamber.

A comprehensive review of oil spill combustion studies

International Nuclear Information System (INIS)

Walavalkar, A.Y.; Kulkarni, A.K.

1996-01-01

The complex process of in-situ burning of oil or a water-in-oil emulsion floating on top of a water-base, such as the ocean, was discussed. The process was examined before, during and after actual combustion. In general, the success of oil spill combustion is measured in terms of the fraction of the spilled oil or emulsion that is burned away. However, the air and aquatic pollution caused by the combustion should also be considered. The physical conditions such as wind velocity, waves and the presence or absence of a containment device, such as a fire boom, could determine the continuation of the combustion process. An overview of the oil spill combustion techniques was provided. There still remains a need for fundamental studies, especially in mathematical modeling, to understand the basic mechanisms and predict the applicability of the in-situ combustion. 74 refs., 7 tabs., 3 figs

The John Zink Hamworthy combustion handbook

CERN Document Server

Baukal, Charles E

2013-01-01

Despite the length of time it has been around, its importance, and vast amounts of research, combustion is still far from being completely understood. Issues regarding the environment, cost, and fuel consumption add further complexity, particularly in the process and power generation industries. Dedicated to advancing the art and science of industrial combustion, The John Zink Hamworthy Combustion Handbook, Second Edition: Volume 3 - Applications offers comprehensive, up-to-date coverage of equipment used in the process and power generation industries. Under the leadership of Charles E. Baukal

Establishment of Combustion Model for Isooctane HCCI Marine Diesel Engine and Research on the Combustion Characteristic

Directory of Open Access Journals (Sweden)

Li Biao

2016-01-01

Full Text Available The homogeneous charge compression ignition (HCCI combustion mode applied in marine diesel engine is expected to be one of alternative technologies to decrease nitrogen oxide (NOX emission and improve energy utilization rate. Applying the chemical-looping combustion (CLC mechanism inside the cylinder, a numerical study on the HCCI combustion process is performed taking a marine diesel engine as application object. The characteristic feature of combustion process is displayed. On this basis, the formation and emission of NOX are analyzed and discussed. The results indicate that the HCCI combustion mode always exhibit two combustion releasing heats: low-temperature reaction and high-temperature reaction. The combustion phase is divided into low-temperature reaction zone, high-temperature reaction zone and negative temperature coefficient (NTC zone. The operating conditions of the high compression ratio, high intake air temperature, low inlet pressure and small excess air coefficient would cause the high in-cylinder pressure which often leads engine detonation. The low compression ratio, low intake air temperature and big excess air coefficient would cause the low combustor temperature which is conducive to reduce NOX emissions. These technological means and operating conditions are expected to meet the NOX emissions limits in MARPOL73/78 Convention-Annex VI Amendment.

Reaction Mechanisms and HCCI Combustion Processes of Mixtures of n-Heptane and the Butanols

Directory of Open Access Journals (Sweden)

Hu eWang

2015-03-01

Full Text Available A reduced primary reference fuel (PRF-Alcohol-Di-tert-butyl Peroxide (DTBP mechanism with 108 species and 435 reactions, including sub-mechanisms of PRF, methanol, ethanol, DTBP and the four butanol isomers, is proposed for homogeneous charge compression ignition (HCCI engine combustion simulations of butanol isomers/n-heptane mixtures. HCCI experiments fuelled with butanol isomer/n-heptane mixtures on two different engines are conducted for the validation of proposed mechanism. The mechanism has been validated against shock tube ignition delays, laminar flame speeds, species profiles in premixed flames and engine HCCI combustion data, and good agreements with experimental results are demonstrated under various validation conditions. It is found that although the reactivity of neat tert-butanol is the lowest, mixtures of tert-butanol/n-heptane exhibit the highest reactivity among the butanol isomer/n-heptane mixtures if the n-heptane blending ratio exceeds 20% (mole. Kinetic analysis shows that the highest C-H bond energy in the tert-butanol molecule is partially responsible for this phenomenon. It is also found that the reaction tC4H9OH+CH3O2 =tC4H9O+CH3O2H plays important role and eventually produces the OH radical to promote the ignition and combustion. The proposed mechanism is able to capture HCCI combustion processes of the butanol/n-heptane mixtures under different operating conditions. In addition, the trend that tert-butanol /n-heptane has the highest reactivity is also captured in HCCI combustion simulations. The results indicate that the current mechanism can be used for HCCI engine predictions of PRF and alcohol fuels.

Plasma assisted measurements of alkali metal concentrations in pressurised combustion processes

Energy Technology Data Exchange (ETDEWEB)

Hernberg, R; Haeyrinen, V [Tampere Univ. of Technology (Finland)

1997-10-01

In this project the continuous alkali measurement method plasma excited alkali resonance line spectroscopy (PEARLS) was developed, tested and demonstrated in pressurised combustion facilities. The PEARLS method has been developed at Tampere University of Technology (TUT). During 1994-1996 the PEARLS method was developed from the laboratory level to an industrial prototype. The alkali measuring instrument has been tested and used for regular measurements in four different pressurised combustion installations ranging up to industrial pilot scale. The installations are: (1) a pressurised entrained flow reactor (PEFR) at VTT Energy in Jyvaeskylae, Finland (2) a pressurised fluidised bed combustion facility, called FRED, at DMT in Essen, Germany. (3) a 10 MW pressurised circulating fluidised bed combustion pilot plant at Foster Wheeler Energia Oy in Karhula, Finland (4) PFBC Research Facility at ABB Carbon in Finspaang, Sweden

Combustion from basics to applications

CERN Document Server

Lackner, Maximilian; Winter, Franz

2013-01-01

Combustion, the process of burning, is defined as a chemical reaction between a combustible reactant (the fuel) and an oxidizing agent (such as air) in order to produce heat and in most cases light while new chemical species (e.g., flue gas components) are formed. This book covers a gap on the market by providing a concise introduction to combustion. Most of the other books currently available are targeted towards the experienced users and contain too many details and/or contain knowledge at a fairly high level. This book provides a brief and clear overview of the combustion basics, suitable f

2017 Laser Diagnostics in Combustion GRC/GRS

Science.gov (United States)

2017-10-06

scientists and engineers . The goal of GRC was to bring together scientists and engineers with a strong interest in laser-based combustion diagnostics to...processes. The GRS, held the weekend before the GRC, was organized to bring together emerging leaders in the field at an early stage in their careers ...coupled multi-scale combustion processes. The GRC on Laser Diagnostics in Combustion was designed to bring together scientists and engineers working at

Integrating multi-objective optimization with computational fluid dynamics to optimize boiler combustion process of a coal fired power plant

International Nuclear Information System (INIS)

Liu, Xingrang; Bansal, R.C.

2014-01-01

Highlights: • A coal fired power plant boiler combustion process model based on real data. • We propose multi-objective optimization with CFD to optimize boiler combustion. • The proposed method uses software CORBA C++ and ANSYS Fluent 14.5 with AI. • It optimizes heat flux transfers and maintains temperature to avoid ash melt. - Abstract: The dominant role of electricity generation and environment consideration have placed strong requirements on coal fired power plants, requiring them to improve boiler combustion efficiency and decrease carbon emission. Although neural network based optimization strategies are often applied to improve the coal fired power plant boiler efficiency, they are limited by some combustion related problems such as slagging. Slagging can seriously influence heat transfer rate and decrease the boiler efficiency. In addition, it is difficult to measure slag build-up. The lack of measurement for slagging can restrict conventional neural network based coal fired boiler optimization, because no data can be used to train the neural network. This paper proposes a novel method of integrating non-dominated sorting genetic algorithm (NSGA II) based multi-objective optimization with computational fluid dynamics (CFD) to decrease or even avoid slagging inside a coal fired boiler furnace and improve boiler combustion efficiency. Compared with conventional neural network based boiler optimization methods, the method developed in the work can control and optimize the fields of flue gas properties such as temperature field inside a boiler by adjusting the temperature and velocity of primary and secondary air in coal fired power plant boiler control systems. The temperature in the vicinity of water wall tubes of a boiler can be maintained within the ash melting temperature limit. The incoming ash particles cannot melt and bond to surface of heat transfer equipment of a boiler. So the trend of slagging inside furnace is controlled. Furthermore, the

Sulfur Chemistry in Combustion I

DEFF Research Database (Denmark)

Johnsson, Jan Erik; Glarborg, Peter

2000-01-01

of the sulphur compounds in fossil fuels and the possibilities to remove them will be given. Then the combustion of sulphur species and their influence on the combustion chemistry and especially on the CO oxidation and the NOx formation will be described. Finally the in-situ removal of sulphur in the combustion...... process by reaction between SO2 and calcium containing sorbents and the influence on the NOx chemistry will be treated....

Combustion Gases And Heat Release Analysis During Flame And Flameless Combustion Of Wood Pellets

Directory of Open Access Journals (Sweden)

Horváth Jozef

2015-06-01

Full Text Available With the growing prices of fossil fuels, alternative fuels produced of biomass come to the fore. They are made of waste materials derived from the processing of wood and wood materials. The main objective of this study was to analyse the fire-technical characteristics of wood pellets. The study analysed three dust samples acquired from wood pellets made of various types of wood biomass. Wood pellet dust is produced when manipulating with pellets. During this process a potentially hazardous situations may occur. Biomass is chemically composed mostly of hemicellulose, cellulose and lignin. During straining of the biomass by heat flux, combustion initiation occurs. Also, there was a change in the composition of material throughout combustion gases production, and the amount of heat generated by a flame or flameless combustion. Measurement of fire characteristics was conducted according to ISO 5660-1 standard using a cone calorimeter. Two samples of wood pellet dust were tested under the heat flux of 35 kW.m−2 and 50 kW.m−2. The process of combustion, the time to ignition, the carbon monoxide concentration and the amount of released heat were observed.

Development and Experimental Validation of Large Eddy Simulation Techniques for the Prediction of Combustion-Dynamic Process in Syngas Combustion: Characterization of Autoignition, Flashback, and Flame-Liftoff at Gas-Turbine Relevant Operating Conditions

Energy Technology Data Exchange (ETDEWEB)

Ihme, Matthias [Univ. of Michigan, Ann Arbor, MI (United States); Driscoll, James [Univ. of Michigan, Ann Arbor, MI (United States)

2015-08-31

The objective of this closely coordinated experimental and computational research effort is the development of simulation techniques for the prediction of combustion processes, relevant to the oxidation of syngas and high hydrogen content (HHC) fuels at gas-turbine relevant operating conditions. Specifically, the research goals are (i) the characterization of the sensitivity of syngas ignition processes to hydrodynamic processes and perturbations in temperature and mixture composition in rapid compression machines and ow-reactors and (ii) to conduct comprehensive experimental investigations in a swirl-stabilized gas turbine (GT) combustor under realistic high-pressure operating conditions in order (iii) to obtain fundamental understanding about mechanisms controlling unstable flame regimes in HHC-combustion.

ACACIA Project - Development of a Post-Combustion CO2 Capture Process. Case of the DMXTM Process

International Nuclear Information System (INIS)

Gomez, A.; Briot, P.; Raynal, L.; Broutin, P.; Gimenez, M.; Soazic, M.; Cessat, P.; Saysset, S.

2014-01-01

The objective of the ACACIA project was to develop processes for post-combustion CO 2 capture at a lower cost and with a higher energetic efficiency than first generation processes using amines such as Monoethanolamine (MEA) which are now considered for the first Carbon Capture and Storage (CCS) demonstrators. The partners involved in this project were: Rhodia (Solvay since then), Arkema, Lafarge, GDF SUEZ, Veolia Environnement, IFP Energies nouvelles, IRCE Lyon, LMOPS, LTIM, LSA Armines. To validate the relevance of the breakthrough processes studied in this project, techno-economic evaluations were carried out with comparison to the reference process using a 30 wt% MEA solvent. These evaluation studies involved all the industrial partners of the project, each partner bringing specific cases of CO 2 capture on their industrial facilities. From these studies, only the process using de-mixing solvent, DMX TM , developed by IFPEN appears as an alternative solution to the MEA process. (authors)

Research on combustion of black-liquor drops

International Nuclear Information System (INIS)

Macek, A.

1999-01-01

Black liquor, the major by-product of the kraft process for production of pulp, is one of the most important industrial fuels. It is burned in recovery boilers in the form of large spray drops (mm), with the objective of simultaneous recovery of heat and chemicals (sodium and sulfur). Even though black-liquor combustion in boilers has been practised for over half a century, research efforts toward improvement of combustion efficiency and abatement of environmental emissions are much more recent. The present paper addresses a specific aspect of that research, namely, elucidation of processes which occur during combustion of black-liquor drops in boiler-gas streams. The paper (a) gives a brief description of the kraft process, (b) reviews the experimental and theoretical (modeling) research advances on combustion of kraft-liquor drops during the 1980s and 1990s, (c) re-examines the results of an earlier combustion study in which black-liquor drops were observed in free flight at temperatures near those in recovery boilers, and (d) recommends input for the modeling of in-flight combustion of kraft-liquor drops in recovery boilers. (author)

Numerical investigation to the dual-fuel spray combustion process in an ethanol direct injection plus gasoline port injection (EDI + GPI) engine

International Nuclear Information System (INIS)

Huang, Yuhan; Hong, Guang; Huang, Ronghua

2015-01-01

Highlights: • A 5D PDF table was used to model the dual-fuel turbulence–chemistry interactions. • The cooling effect of ethanol direct injection (EDI) was examined. • The higher flame speed of ethanol in EDI + GPI increased the thermal efficiency. • The partially premixed combustion in EDI + GPI reduced the combustion temperature. • Ethanol’s low evaporation rate in low temperature led to incomplete combustion. - Abstract: Ethanol direct injection plus gasoline port injection (EDI + GPI) is a new technology to make the use of ethanol fuel more effective and efficient in spark ignition engines. Multi-dimensional computational fluid dynamics modelling was conducted on an EDI + GPI engine in both single and dual fuelled conditions. The in-cylinder flow field was solved in the realizable k−ε turbulence model with detailed engine geometry. The temporal and spatial distributions of the liquid and vapour fuels were simulated with the spray breakup and evaporation models. The combustion process was modelled with the partially premixed combustion concept in which both mixture fraction and progress variable were solved. The three-dimensional and five-dimensional presumed Probability Density Function (PDF) look-up tables were used to model the single-fraction-mixture and two-fraction-mixture turbulence–chemistry interactions respectively. The model was verified by comparing the numerical and experimental results of spray pattern and cylinder pressure. The simulation results showed that the combustion process of EDI + GPI dual-fuelled condition was partially premixed combustion because of the low evaporation rate of ethanol spray in low temperature environment before combustion. Compared with GPI only, the higher flame speed of ethanol fuel contributed to the greater pressure rise rate and maximum cylinder pressure in EDI + GPI condition, which consequently resulted in higher power output and thermal efficiency. The lower adiabatic flame temperature of

Investigation of the combustion kinetics and polycyclic aromatic hydrocarbon emissions from polycaprolactone combustion.

Science.gov (United States)

Chien, Y C; Yang, S H

2013-01-01

Polycaprolactone (PCL) is one of the most attractive biodegradable plastics that has been widely used in medicine and agriculture fields. Because of the large increase in biodegradable plastics usage, the production of waste biodegradable plastics will be increasing dramatically, producing a growing environmental problem. Generally, waste PCL is collected along with municipal solid wastes and then incinerated. This study investigates the combustion kinetics and emission factors of 16 US Environmental Protection Agency (EPA) priority polycyclic aromatic hydrocarbons (PAHs) in the PCL combustion. Experimentally, two reactions are involved in the PCL combustion process, possibly resulting in the emission of carbon dioxide, propanal, protonated caprolactone and very small amounts of PAH produced by incomplete combustion. The intermediate products may continuously be oxidized to form CO2. The emission factors for 16 US EPA priority PAHs are n.d. -2.95 microg/g, which are much lower than those of poly lactic acid and other plastics combustion. The conversion of PCL is 100%. Results from this work suggest that combustion is a good choice for the waste PCL disposal.

Calibration and Data Processing in Gas Chromatography Combustion Isotope Ratio Mass Spectrometry

Science.gov (United States)

Zhang, Ying; Tobias, Herbert J.; Sacks, Gavin L.; Brenna, J. Thomas

2013-01-01

Compound-specific isotope analysis (CSIA) by gas chromatography combustion isotope ratio mass spectrometry (GCC-IRMS) is a powerful technique for the sourcing of substances, such as determination of the geographic or chemical origin of drugs and food adulteration, and it is especially invaluable as a confirmatory tool for detection of the use of synthetic steroids in competitive sport. We review here principles and practices for data processing and calibration of GCC-IRMS data with consideration to anti-doping analyses, with a focus on carbon isotopic analysis (13C/12C). After a brief review of peak definition, the isotopologue signal reduction methods of summation, curve-fitting, and linear regression are described and reviewed. Principles for isotopic calibration are considered in the context of the Δ13C = δ13CM – δ13CE difference measurements required for establishing adverse analytical findings for metabolites relative to endogenous reference compounds. Considerations for the anti-doping analyst are reviewed. PMID:22362612

Environmental Performance of Hypothetical Canadian Pre-Combustion Carbon Dioxide Capture Processes Using Life-Cycle Techniques

Directory of Open Access Journals (Sweden)

Lakkana Piewkhaow

2016-03-01

Full Text Available The methodology of life-cycle assessment was applied in order to evaluate the environmental performance of a hypothetical Saskatchewan lignite-fueled Integrated Gasification Combined Cycle (IGCC electricity generation, with and without pre-combustion carbon dioxide (CO2 capture from a full life-cycle perspective. The emphasis here is placed on environmental performance associated with air contaminants of the comparison between IGCC systems (with and without CO2 capture and a competing lignite pulverized coal-fired electricity generating station in order to reveal which technology offers the most positive environmental effects. Moreover, ambient air pollutant modeling was also conducted by using American Meteorological Society/Environmental Protection Agency Regulatory Model (AERMOD air dispersion modeling to determine the ground-level concentration of pollutants emitted from four different electricity generating stations. This study assumes that all stations are located close to Estevan. The results showed a significant reduction in greenhouse gas (GHG emissions and acidification potential by applying both post-combustion and pre-combustion CO2 capture processes. The GHG emissions were found to have reduced by 27%–86%, and IGCC systems were found to compare favorably to pulverized coal systems. However, in other environmental impact categories, there are multiple environmental trade-offs depending on the capture technology used. In the case of post-combustion capture, it was observed that the environmental impact category of eutrophication potential, summer smog, and ozone depletion increased due to the application of the CO2 capture process and the surface mining coal operation. IGCC systems, on the other hand, showed the same tendency as the conventional coal-fired electricity generation systems, but to a lesser degree. This is because the IGCC system is a cleaner technology that produces lower pollutant emission levels than the electricity

Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process

Energy Technology Data Exchange (ETDEWEB)

Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

2011-10-16

Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

Study on the combustion behavior of high impact polystyrene nanocomposites produced by different extrusion processes

Directory of Open Access Journals (Sweden)

2008-08-01

Full Text Available The combustion behavior of a blend made of high impact polystyrene (HIPS with sodium montmorillonite (MMT-Na+ and triphenyl phosphite (TPP, as a halogen-free flame retardant, is analyzed in detail in this work. The blend is processed through various extrusion methods aimed to improve clay dispersion. The UL94 method in vertical position, oxygen index and cone calorimetric measurements assess HIPS blend behavior in combustion. TGA, FTIR, SEM and X-ray measurements, together with mechanical and rheological tests evaluate the thermal degradation, morphology, intercalation and degree of dispersion of particles. The use of a static-mixing die placed at the extreme of a single screw extruder improves clay platelets distribution and reduces the peak heat release rate better than employing a twin screw extrusion process. In addition, mechanical and rheological properties are affected substantially by changing the extrusion process. A correlation between clay dispersion and HIPS fire retardant properties is found, as the peak heat release rate decreases with good clay dispersion in cone calorimetric tests.

FY1996 annual report on the advanced combustion science in microgravity field

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-03-01

Research was implemented continuously from the previous year on combustion equipment enabling advanced combustion technologies, by studying combustion in a microgravity field, for the purpose of preventing environmental pollution caused by diversification of energy sources and exhaust gasses. In joint studies with NASA, the themes of the previous year were continued, for which tests were conducted 37 times using Japanese drop test equipment and 131 times using NASA's. The evaluation and analysis of the experiments and test data by the microgravity test equipment were, in addition to the themes of the previous year, such that micro observation for ignition/combustion mechanism of fuel spray droplets was made, as well as studies on fuel droplets combustion by a laser diagnostic device, concerning combustion of fuel droplets and vaporization process, that flame spread on solid substances was researched in relation to combustion characteristics of high density fuels, and that mixed gas combustion on a solid surface was studied in connection with the research on flammability limits. Furthermore, a study on combustion technology for gas turbines was added for the purpose of studying an advanced combustor. (NEDO)

Modeling and simulating combustion and generation of NOx

International Nuclear Information System (INIS)

Lazaroiu, Gheorghe

2007-01-01

This paper deals with the modeling and simulation of combustion processes and generation of NO x in a combustion chamber and boiler, with supplementary combustion in a gas turbine installation. The fuel burned in the combustion chamber was rich gas with a chemical composition more complex than natural gas. Pitcoal was used in the regenerative boiler. From the resulting combustion products, 17 compounds were retained, including nitrogen and sulphur compounds. Using the developed model, the simulation resulted in excess air for a temperature imposed at the combustion chamber exhaust. These simulations made it possible to determine the concentrations of combustion compounds with a variation in excess combustion. (author)

Oxy-fuel combustion as an alternative for increasing lime production in rotary kilns

International Nuclear Information System (INIS)

Granados, D.A.; Chejne, F.; Mejía, J.M.

2015-01-01

Highlights: • A one-dimensional model for oxy-fuel combustion in a rotary kiln was developed. • Flue gas recirculation becomes an important parameter for controlling the process. • Combustion process decreases the flame length making it more dense. • Increases of 12% in raw material with 40% of FGR and conversion of 98% was obtained. - Abstract: The effect of Flue Gas Recirculation (FGR) on the decarbonation process during oxy-fuel combustion in a lime (and cement) rotary kiln is analyzed using an unsteady one-dimensional Eulerian–Lagrangian mathematical model. The model considers gas and limestone as continuous phases and the coal particles as the discrete phase. The model predicts limestone decarbonation, temperature and species distribution of gas and solid phases along the kiln. Simulation results of an air-combustion case are successfully validated with reported experimental data. This model is used to study and to compare the conventional air combustion process with oxy-fuel combustion with FGR ratios between 30% and 80% as controller parameter in this process. Changes in decarbonation process due to energy fluxes by convection and radiation with different FGRs were simulated and analyzed. Simulation results indicate a temperature increase of 20% in the gas and solid phases and a higher decarbonation rate of 40% in relation to the air-combustion case, for a given constant fuel consumption rate. However, for a given temperature, the increase of the CO_2 partial pressure in the oxy-fuel case promotes a reduction of the decarbonation rate. Therefore, there is a compromise between FGR and decarbonation rate, which is analyzed in the present study. Simulation results of the decarbonation step in low FGR cases, compared to air-combustion case, shows that conversion takes place in shorter distances in the kiln, suggesting that the production rate can be increased for existing kilns in oxy-fuel kilns or, equivalently, shorter kilns can be designed for an

Oxyfuel combustion for below zero CO{sub 2} emissions

Energy Technology Data Exchange (ETDEWEB)

Boeg Toftegaard, M; Hansen, Kim G; Fisker, D [DONG Energy Power, Hvidovre (Denmark); Brix, J; Brun Hansen, B; Putluru, S S.R.; Jensen, Peter Arendt; Glarborg, Peter; Degn Jensen, A [Technical Univ. of Denmark. CHEC Research Centre, Kgs. Lyngby (Denmark); Montgomery, M [Technical Univ. of Denmark. DTU Mechanical Engineering, Kgs. Lyngby (Denmark)

2011-07-01

The reduction of CO{sub 2} emissions is of highest concern in relation to limiting the anthropogenic impacts on the environment. Primary focus has gathered on the large point sources of CO{sub 2} emissions constituted by large heat and power stations and other heavy, energy-consuming industry. Solutions are sought which will enable a significant reduction of the anthropogenic CO{sub 2} emissions during the transformation period from the use of fossil fuels to renewable sources of energy. Carbon capture and storage (CCS) has the potential to significantly reduce CO{sub 2} emissions from power stations while allowing for the continuous utilisation of the existing energy producing system in the transformation period. Oxyfuel combustion is one of the possible CCS technologies which show promising perspectives for implementation in industrial scale within a relatively short period of time. Oxyfuel combustion deviates from conventional combustion in air by using a mixture of pure oxygen and recirculated flue gas as the combustion medium thereby creating a flue gas highly concentrated in CO{sub 2} making the capture process economically more feasible compared to technologies with capture from more dilute CO{sub 2} streams. This project has investigated a number of the fundamental and practical issues of the oxyfuel combustion process by experimental, theoretical, and modelling investigations in order to improve the knowledge of the technology. The subjects investigated cover: general combustion characteristics of coal and biomass (straw) and mixtures thereof, formation and emission of pollutants, ash characteristics, flue gas cleaning for SO{sub 2} by wet scrubbing with limestone and for NO{sub x} by selective catalytic reduction (SCR), corrosion of boiler heat transfer surfaces, operation and control of large suspension-fired boilers, and the perspectives for the implementation of oxyfuel combustion s a CO{sub 2} sequestration solution in the Danish power production

Alcohol combustion chemistry

KAUST Repository

Sarathy, Mani

2014-10-01

Alternative transportation fuels, preferably from renewable sources, include alcohols with up to five or even more carbon atoms. They are considered promising because they can be derived from biological matter via established and new processes. In addition, many of their physical-chemical properties are compatible with the requirements of modern engines, which make them attractive either as replacements for fossil fuels or as fuel additives. Indeed, alcohol fuels have been used since the early years of automobile production, particularly in Brazil, where ethanol has a long history of use as an automobile fuel. Recently, increasing attention has been paid to the use of non-petroleum-based fuels made from biological sources, including alcohols (predominantly ethanol), as important liquid biofuels. Today, the ethanol fuel that is offered in the market is mainly made from sugar cane or corn. Its production as a first-generation biofuel, especially in North America, has been associated with publicly discussed drawbacks, such as reduction in the food supply, need for fertilization, extensive water usage, and other ecological concerns. More environmentally friendly processes are being considered to produce alcohols from inedible plants or plant parts on wasteland. While biofuel production and its use (especially ethanol and biodiesel) in internal combustion engines have been the focus of several recent reviews, a dedicated overview and summary of research on alcohol combustion chemistry is still lacking. Besides ethanol, many linear and branched members of the alcohol family, from methanol to hexanols, have been studied, with a particular emphasis on butanols. These fuels and their combustion properties, including their ignition, flame propagation, and extinction characteristics, their pyrolysis and oxidation reactions, and their potential to produce pollutant emissions have been intensively investigated in dedicated experiments on the laboratory and the engine scale

Oxy combustion with CO{sub 2} capture

Energy Technology Data Exchange (ETDEWEB)

NONE

2012-01-15

An update for oxyfuel-combustion carbon capture in the power industry is provided. The report was developed by the Electric Power Research Institute (EPRI) on behalf of the Global CCS Institute. In the oxyfuel-combustion processes, the bulk nitrogen is removed from the air before combustion. The resulting combustion products will have CO2 content up to about 90 per cent (dry basis). The flue gas impurities (predominantly O2, N2, and Ar) may be removed by reducing the flue gas (at moderate pressure) to a temperature at which the CO2 condenses and the impurities do not. Oxyfuel-combustion may be employed with solid fuels such as coal, petroleum coke, and biomass, as well as liquid and gaseous fuels. Some key points raised in the oxyfuel-combustion carbon capture report are: The oxyfuel-combustion/CO2 capture power plant designs being developed and deployed for service in the next four or five years are based on individual component technologies and arrangements which have demonstrated sufficient maturity, with the greatest remaining technical challenge being integrating the systems into a complete steam-electric power plant; By its nature, an oxyfuel-coal power plant is likely to be a 'near zero' emitter of all criteria pollutants; Existing air-fired power plants might be retrofitted with an air separation unit, oxyfuel-fired burners, flue gas recycle, and a CO2 processing unit, with the large fleet of air-fired power plants in service calling for more study of this option; and, Future efficiency improvements to the oxyfuel-combustion process for power generation point toward an oxyfuel-combustion plant with near zero emissions of conventional pollutants, up to 98 per cent CO2 capture, and efficiency comparable to the best power plants currently being built.

Combustion characteristics of lemongrass (Cymbopogon flexuosus) oil in a partial premixed charge compression ignition engine

OpenAIRE

Avinash Alagumalai

2015-01-01

Indeed, the development of alternate fuels for use in internal combustion engines has traditionally been an evolutionary process in which fuel-related problems are met and critical fuel properties are identified and their specific limits defined to resolve the problem. In this regard, this research outlines a vision of lemongrass oil combustion characteristics. In a nut-shell, the combustion phenomena of lemongrass oil were investigated at engine speed of 1500 rpm and compression ratio of 17....

Heavy metals behaviour during mono-combustion and co-combustion of sewage sludge

Energy Technology Data Exchange (ETDEWEB)

Lopes, M. Helena; Abelha, Pedro; Olieveira, J.F. Santos; Gulyurtlu, Ibrahim; Cabrita, Isabel [INETI-DEECA, Lisboa (Portugal)

2005-03-01

This paper presents the study of the combustion of granular dry sewage sludge performed on a pilot fluidized bed system. The results of mono-combustion of sludge and co-combustion with coal were compared with those of coal combustion for ash partitioning, the formation of gaseous pollutants and heavy metals behaviour. It was found that the mineral matter of sludge was essentially retained as bottom ashes. The production of fines ashes was small during the mono-combustion due to the tendency of coal to produce fine ashes which also contained unburned char. The degree of heavy metal volatilization was found to be slightly higher during co-combustion than in mono-combustion; however, most of them were retained in ashes and their emissions were found to be below the regulated levels. Hg was completely volatilized; however, during combustion trials involving coal it was captured by cyclone ashes at temperatures below 300 deg C. During sludge mono-combustion the retention of Hg in cyclone ashes containing low LOI was not enough to decrease emissions below the regulated levels; hence, it is necessary to install dedicated flue gas treatment for Hg removal. The leachability and ecotoxicity of sludge and ashes was compared with the new regulatory limits for landfill disposal in the EU. It was found that the release of organic matter and heavy metals found in the sludge was low from granular bed ashes; hence, except for sulphate release, bed ashes were converted into inert and non-ecotoxic materials. Ashes from test with limestone and cyclone ashes seemed to be more problematic because of pH effects and contamination with steel corrosion products. The recovery and reutilization of sludge bed ashes could, therefore, be possible, as long as the release of sulphate do not interfere with the process.

FY1995 annual report on the advanced combustion science in microgravity field

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-03-01

Research was implemented continuously from the previous year on combustion equipment enabling advanced combustion technologies, by studying combustion in a microgravity field, for the purpose of preventing environmental pollution caused by diversification of energy sources and exhaust gasses. In joint studies with NASA, the 1995 themes were continued, for which tests were conducted 34 times using Japanese drop test equipment. Further, studies were added for flammability limits and flame dynamics of spherical flames in homogeneous and heterogeneous mixed fuels. The evaluation and analysis of the experiments and test data by the microgravity test equipment were such that laser ignitions of floating or fuel-oozing droplets, spherical/cylindrical combustion of liquid fuels, for example, were studied in regards to the combustion and vaporization process of fuel droplets, that high calorie fuel combustion in microgravitation field for example was investigated in relation to the combustion characteristics of high density fuels, that flame stability of lean premixed gasses for example was researched concerning flammability limit, and that NOx generation mechanism in liquid fuel combustion was looked into in connection with emission mechanisms of pollutant gaseous materials. (NEDO)

The Multi-User Droplet Combustion Apparatus: the Development and Integration Concept for Droplet Combustion Payloads in the Fluids and Combustion Facility Combustion Integrated Rack

Science.gov (United States)

Myhre, C. A.

2002-01-01

using liquid combustibles on Earth and in space. As a result of the concurrent design process of MDCA and CIR, the MDCA team continues to work closely with the CIR team, developing Integration Agreements and an Interface Control Document during preliminary integration activities. Integrated testing of hardware and software systems will occur at the Engineering Model and Flight Model phases. Because the engineering model is a high fidelity unit, it will be upgraded to a flight equivalent Ground Integration Unit (GIU) when the engineering model phase is completed. The GIU will be available on the ground for troubleshooting of any on-orbit problems. Integrated verification testing will be conducted with the MDCA flight unit and the CIR flight unit. Upon successful testing, the MDCA will be shipped to the Kennedy Space Center for a post-shipment checkout and final turn-over to CIR for final processing and launch to the International Space Station. Once on-orbit, the MDCA is managed from the GRC Telescience Support Center (TSC). The MDCA operations team resides at the TSC. Data is transmitted to the PI's at their home sites by means of TREK workstations, allowing direct interaction between the PI and operations staff to maximum science. Upon completion of a PI's experiment, the MDCA is reconfigured for the next of the three follow-on experiments or ultimately removed from the CIR, placed into stowage, and returned to Earth.

Numerical investigation of spray combustion towards HITAC conditions

NARCIS (Netherlands)

Zhu, Shanglong

2017-01-01

The features of High Temperature Air Combustion (HiTAC), i.e. high-efficiency combustion processes creating a uniform temperature distribution with low NOX and CO emissions, lend itself ideally for the combustion of all sorts of "difficult” fuels, ranging from low-calorific gases such as

Ash related behaviour in staged and non-staged combustion of biomass fuels and fuel mixtures

International Nuclear Information System (INIS)

Becidan, Michaël; Todorovic, Dusan; Skreiberg, Øyvind; Khalil, Roger A.; Backman, Rainer; Goile, Franziska; Skreiberg, Alexandra; Jovovic, Aleksandar; Sørum, Lars

2012-01-01

The fate of selected elements (with focus on the important players in corrosion i.e. Na, K, Pb, Zn, Cl and S) are investigated for three biomasses (wood, demolition wood and coffee waste) and six mixtures of these as pellets both with and without air staging in a laboratory reactor. In order to get a complete overview of the combustion products, both online and offline analytical methods are used. Information is collected about: flue gas composition, particle (fly ash) size distribution and composition, bottom ash composition and melting properties. The main findings are: (1) complex interactions are taking place between the mixed fuels during combustion; (2) the mode of occurrence of an element as well as the overall structure of the fuel are important for speciation; (3) the pelletisation process, by bringing chemical elements into intimate contact, may affect partitioning and speciation; (4) staging and mixing might simultaneously have positive and negative effects on operation; (5) staging affects the governing mechanisms of fly ash (aerosols) formation. -- Highlights: ► Complex interactions are taking place between the mixed fuels during combustion. ► The mode of occurrence of an element as well as the overall structure of the fuel are important for speciation. ► The pelletisation process, by bringing chemical elements into intimate contact, may affect partitioning and speciation. ► Staging and mixing might simultaneously have positive and negative effects on operation. ► Staging affects the governing mechanisms of fly ash (aerosols) formation.

Sound quality assessment of Diesel combustion noise using in-cylinder pressure components

Science.gov (United States)

Payri, F.; Broatch, A.; Margot, X.; Monelletta, L.

2009-01-01

The combustion process in direct injection (DI) Diesel engines is an important source of noise, and it is thus the main reason why end-users could be reluctant to drive vehicles powered with this type of engine. This means that the great potential of Diesel engines for environment preservation—due to their lower consumption and the subsequent reduction of CO2 emissions—may be lost. Moreover, the advanced combustion concepts—e.g. the HCCI (homogeneous charge compression ignition)—developed to comply with forthcoming emissions legislation, while maintaining the efficiency of current engines, are expected to be noisier because they are characterized by a higher amount of premixed combustion. For this reason many efforts have been dedicated by car manufacturers in recent years to reduce the overall level and improve the sound quality of engine noise. Evaluation procedures are required, both for noise levels and sound quality, that may be integrated in the global engine development process in a timely and cost-effective manner. In previous published work, the authors proposed a novel method for the assessment of engine noise level. A similar procedure is applied in this paper to demonstrate the suitability of combustion indicators for the evaluation of engine noise quality. These indicators, which are representative of the peak velocity of fuel burning and the resonance in the combustion chamber, are well correlated with the combustion noise mark obtained from jury testing. Quite good accuracy in the prediction of the engine noise quality has been obtained with the definition of a two-component regression, which also permits the identification of the combustion process features related to the resulting noise quality, so that corrective actions may be proposed.

Numerical simulation of combustion and soot under partially premixed combustion of low-octane gasoline

KAUST Repository

An, Yanzhao

2017-09-23

In-cylinder combustion visualization and engine-out soot particle emissions were investigated in an optical diesel engine fueled with low octane gasoline. Single injection strategy with an early injection timing (−30 CAD aTDC) was employed to achieve partially premixed combustion (PPC) condition. A high-speed color camera was used to record the combustion images for 150 cycles. The regulated emission of carbon dioxide, carbon monoxide, nitrogen oxides and soot mass concentration were measured experimentally. Full cycle engine simulations were performed using CONVERGE™ and the simulation results matched with the experimental results. The in-cylinder soot particle evolution was performed by coupling a reduced toluene reference fuel mechanism including the PAHs formation/oxidation reactions with particulate size mimic model. The results showed that PPC presents typical stratified combustion characteristics, which is significantly different from the conventional diesel spray-driven combustion. The in-cylinder temperature and equivalence ratio overlaid with soot-NO formation regime revealed that PPC operating condition under study mostly avoided the main sooting conditions throughout the entire combustion. The evaluation of temperature distribution showed formaldehyde could be regarded as an indicator for low temperature reactions, while hydroxyl group represents the high temperature reactions. Soot evolution happened during the combustion process, hydroxyl radicals promoted the soot oxidation.

Numerical simulation of combustion and soot under partially premixed combustion of low-octane gasoline

KAUST Repository

An, Yanzhao; Jaasim, Mohammed; Vallinayagam, R.; Vedharaj, S.; Im, Hong G.; Johansson, Bengt.

2017-01-01

In-cylinder combustion visualization and engine-out soot particle emissions were investigated in an optical diesel engine fueled with low octane gasoline. Single injection strategy with an early injection timing (−30 CAD aTDC) was employed to achieve partially premixed combustion (PPC) condition. A high-speed color camera was used to record the combustion images for 150 cycles. The regulated emission of carbon dioxide, carbon monoxide, nitrogen oxides and soot mass concentration were measured experimentally. Full cycle engine simulations were performed using CONVERGE™ and the simulation results matched with the experimental results. The in-cylinder soot particle evolution was performed by coupling a reduced toluene reference fuel mechanism including the PAHs formation/oxidation reactions with particulate size mimic model. The results showed that PPC presents typical stratified combustion characteristics, which is significantly different from the conventional diesel spray-driven combustion. The in-cylinder temperature and equivalence ratio overlaid with soot-NO formation regime revealed that PPC operating condition under study mostly avoided the main sooting conditions throughout the entire combustion. The evaluation of temperature distribution showed formaldehyde could be regarded as an indicator for low temperature reactions, while hydroxyl group represents the high temperature reactions. Soot evolution happened during the combustion process, hydroxyl radicals promoted the soot oxidation.

Combustion synthesis of micron-sized Sm2Co17 particles via mechanochemical processing

International Nuclear Information System (INIS)

Liu, W.; McCormick, P.G.

1998-01-01

Full text: The spontaneous formation of Sm 2 Co 17 micron-sized particles via a mechanically induced combustion reaction has been investigated. Sm 2 Co 17 alloy particles of 0.1--2 μm in size embedded in a CaO matrix formed directly via a combustion reaction induced by milling the powder mixture of Sm 2 O 3 , CoO, CaO and Ca over a critical time. The micron-sized Sm 2 Co 17 particles were found to have the TbCu 7 -type structure and characterized by a coercivity value of 7.8 kOe while embedded in the CaO matrix. The effect of subsequent heat treatment on the structure and magnetic properties of as-milled samples was also investigated. Removal of the CaO by a carefully controlled washing process yielded micron-sized Sm 2 Co 17 particles without significant oxidation of the particles. These fine Sm 2 Co 17 particles can be used to produce anisotropic bulk or bonded magnets

Center for commercial applications of combustion in space (CCACS); A partnership for space commercialization at the Colorado School of Mines

Science.gov (United States)

Schowengerdt, F. D.; Kee, Bob; Linne, Mark; McKinnon, Tom; Moore, John; Parker, Terry; Readey, Dennis; Tilton, John E.; Helble, Joe

1997-01-01

The Center for Commercial Applications of Combustion in Space (CCACS) is a NASA/Industry/University consortium at the Colorado School of Mines (CSM). The mission of the Center is to assist industry in developing commercial products by conducting combustion research which takes advantage of the unique properties of space. By conducting experiments in near-zero gravity, convection and buoyancy effects can be minimized and new fundamental design-related knowledge can be gained which can be used to improve combustion-related products and processes on earth. Companies, government laboratories and universities most actively involved in CCACS at present include ABB Combustion, ADA Technologies, Advanced Refractory Technologies, Golden Technologies, Lockheed-Martin, Southwest Sciences, Space Systems/Lora, NASA-Lewis, JPL, the Baylor Dental School and the University of Connecticut. Products and processes of interest to the Center participants include industrial process combustors; catalytic combustion; Halon replacements; ceramic powders, whiskers and fibers; metal-matrix composites; NiTi for bone replacement; diamond coatings for oil-well drill bits; zeolites; imaging sensor arrays and other instrumentation for flame and particulate diagnostics. The center also assists member companies in marketing the resulting products and processes.

Meta-control of combustion performance with a data mining approach

Science.gov (United States)

Song, Zhe

Large scale combustion process is complex and proposes challenges of optimizing its performance. Traditional approaches based on thermal dynamics have limitations on finding optimal operational regions due to time-shift nature of the process. Recent advances in information technology enable people collect large volumes of process data easily and continuously. The collected process data contains rich information about the process and, to some extent, represents a digital copy of the process over time. Although large volumes of data exist in industrial combustion processes, they are not fully utilized to the level where the process can be optimized. Data mining is an emerging science which finds patterns or models from large data sets. It has found many successful applications in business marketing, medical and manufacturing domains The focus of this dissertation is on applying data mining to industrial combustion processes, and ultimately optimizing the combustion performance. However the philosophy, methods and frameworks discussed in this research can also be applied to other industrial processes. Optimizing an industrial combustion process has two major challenges. One is the underlying process model changes over time and obtaining an accurate process model is nontrivial. The other is that a process model with high fidelity is usually highly nonlinear, solving the optimization problem needs efficient heuristics. This dissertation is set to solve these two major challenges. The major contribution of this 4-year research is the data-driven solution to optimize the combustion process, where process model or knowledge is identified based on the process data, then optimization is executed by evolutionary algorithms to search for optimal operating regions.

Real gas CFD simulations of hydrogen/oxygen supercritical combustion

Science.gov (United States)

Pohl, S.; Jarczyk, M.; Pfitzner, M.; Rogg, B.

2013-03-01

A comprehensive numerical framework has been established to simulate reacting flows under conditions typically encountered in rocket combustion chambers. The model implemented into the commercial CFD Code ANSYS CFX includes appropriate real gas relations based on the volume-corrected Peng-Robinson (PR) equation of state (EOS) for the flow field and a real gas extension of the laminar flamelet combustion model. The results indicate that the real gas relations have a considerably larger impact on the flow field than on the detailed flame structure. Generally, a realistic flame shape could be achieved for the real gas approach compared to experimental data from the Mascotte test rig V03 operated at ONERA when the differential diffusion processes were only considered within the flame zone.

Monitoring temperatures in coal conversion and combustion processes via ultrasound

Science.gov (United States)

Gopalsami, N.; Raptis, A. C.; Mulcahey, T. P.

1980-02-01

The state of the art of instrumentation for monitoring temperatures in coal conversion and combustion systems is examined. The instrumentation types studied include thermocouples, radiation pyrometers, and acoustical thermometers. The capabilities and limitations of each type are reviewed. A feasibility study of the ultrasonic thermometry is described. A mathematical model of a pulse-echo ultrasonic temperature measurement system is developed using linear system theory. The mathematical model lends itself to the adaptation of generalized correlation techniques for the estimation of propagation delays. Computer simulations are made to test the efficacy of the signal processing techniques for noise-free as well as noisy signals. Based on the theoretical study, acoustic techniques to measure temperature in reactors and combustors are feasible.

Particulate and gaseous emissions from residential biomass combustion

International Nuclear Information System (INIS)

Boman, Christoffer

2005-04-01

different stoves were determined with variations in fuel, appliance and operational properties. The emissions of PICs as well as PM tot from wood combustion were in general shown to be considerably higher compared to pellets combustion. PAH tot emissions were determined in the range of 1,300-220,000 μg/MJ for wood stoves and 2-300 μg/MJ for pellet stoves with phenantrene, fluoranthene and pyrene generally found as major PAHs. The PM emissions from present residential appliances was found to consist of significant but varying fractions of PICs, with emissions in the range 35-350 mg/MJ for wood stoves compared to 15-45 mg/MJ for pellet stoves. Accordingly, the use of up-graded biomass fuels, combusted under continuous and controlled conditions give advantageous combustion conditions compared to traditional batch wise firing of wood logs. The importance of high temperature in well mixed isothermal conditions was further illustrated during pellets combustion to obtain complete combustion with almost a total depletion of PICs. Fine (100-300 nm) particles dominated in all studied cases the PM with 80-95% as PM 1 . Beside varying fractions of carbonaceous material, the fine PM consisted of inorganic volatilized ash elements, mainly found as KCl, K 3 Na(SO 4 ) 2 and K 2 SO 4 with mass concentrations at 15-20 mg/MJ during complete combustion. The importance of the behavior of alkali elements for the ash transformation and fine particle formation processes was further shown, since the stability, distributions and compositions also directly control the degree of volatilization. In addition to the alkali metals, zinc was found as an important element in fine particles from residential biomass combustion. Finally, the behaviour of volatile trace elements, e.g. Zn and Cd, during pellets production and combustion were studied. A significant enrichment in the pellet fuel during the drying process was determined. The magnitude and importance of the enrichment was, however, relative small

Coal Combustion Behavior in New Ironmaking Process of Top Gas Recycling Oxygen Blast Furnace

Science.gov (United States)

Zhou, Zhenfeng; Xue, Qingguo; Tang, Huiqing; Wang, Guang; Wang, Jingsong

2017-10-01

The top gas recycling oxygen blast furnace (TGR-OBF) is a new ironmaking process which can significantly reduce the coke ratio and emissions of carbon dioxide. To better understand the coal combustion characteristics in the TGR-OBF, a three dimensional model was developed to simulate the lance-blowpipe-tuyere-raceway of a TGR-OBF. The combustion characteristics of pulverized coal in TGR-OBF were investigated. Furthermore, the effects of oxygen concentration and temperature were also analyzed. The simulation results show that the coal burnout increased by 16.23% compared to that of the TBF. The oxygen content has an obvious effect on the burnout. At 70% oxygen content, the coal burnout is only 21.64%, with a decrease of 50.14% compared to that of TBF. Moreover, the effect of oxygen temperature is also very obvious.

Les méthodes thermiques de production des hydrocarbures. Chapitre 5 : Combustion "in situ". Pricipes et études de laboratoire Thermal Methods of Hydrocarbon Production. Chapter 5 : "In Situ" Combustion. Principles and Laboratory Research

Directory of Open Access Journals (Sweden)

Burger J.

2006-11-01

Full Text Available II existe plusieurs variantes de la combustion in situ, suivant le sens de déplacement du front de combustion, à co-courant ou à contre-courant, et suivant la nature des fluides injectés, air seul ou injection combinée d'air et d'eau. Les réactions de pyrolyse, d'oxydation et de combustion mises en jeu par ces techniques sont discutées, en particulier la cinétique des principaux mécanismes réactionnels, l'importance du dépôt de coke et l'exothermicité des réactions d'oxydation et de combustion. Les résultats d'essais de déplacement unidirectionnel du front de combustion dans des cellules de laboratoire sont présentés et discutés. Enfin on indique les conditions pratiques d'application des méthodes de combustion in situ sur champ. Possible variations of in situ combustion technique ore as follows : forward or reverse combustion depending on the relative directions of the air flow and the combustion front, dry combustion if air is the only fluid injected into the oil-bearing formation, or fixe/woter flooding if water is injected along with air. The chemical reactions of pyrolysis, oxidation and combustion involved in these processes are described. The kinetics of these reactions is discussed as well as fuel availability in forward combustion and the exothermicity of the oxidation and combustion reactions. The results obtained in the laboratory when a combustion front propagates in unidirectional adiabatic tells are described and discussed. This type of experimentation provides extensive information on the characteristics of the processes. Screening criteria for the practical application of in situ combustion techniques are presented.

Combustion Mode Design with High Efficiency and Low Emissions Controlled by Mixtures Stratification and Fuel Reactivity

Directory of Open Access Journals (Sweden)

Hu eWang

2015-08-01

Full Text Available This paper presents a review on the combustion mode design with high efficiency and low emissions controlled by fuel reactivity and mixture stratification that have been conducted in the authors’ group, including the charge reactivity controlled homogeneous charge compression ignition (HCCI combustion, stratification controlled premixed charge compression ignition (PCCI combustion, and dual-fuel combustion concepts controlled by both fuel reactivity and mixture stratification. The review starts with the charge reactivity controlled HCCI combustion, and the works on HCCI fuelled with both high cetane number fuels, such as DME and n-heptane, and high octane number fuels, such as methanol, natural gas, gasoline and mixtures of gasoline/alcohols, are reviewed and discussed. Since single fuel cannot meet the reactivity requirements under different loads to control the combustion process, the studies related to concentration stratification and dual-fuel charge reactivity controlled HCCI combustion are then presented, which have been shown to have the potential to achieve effective combustion control. The efforts of using both mixture and thermal stratifications to achieve the auto-ignition and combustion control are also discussed. Thereafter, both charge reactivity and mixture stratification are then applied to control the combustion process. The potential and capability of thermal-atmosphere controlled compound combustion mode and dual-fuel reactivity controlled compression ignition (RCCI/highly premixed charge combustion (HPCC mode to achieve clean and high efficiency combustion are then presented and discussed. Based on these results and discussions, combustion mode design with high efficiency and low emissions controlled by fuel reactivity and mixtures stratification in the whole operating range is proposed.

Effects of ignition parameters on combustion process of a rotary engine fueled with natural gas

International Nuclear Information System (INIS)

Fan, Baowei; Pan, Jianfeng; Liu, Yangxian; Zhu, Yuejin

2015-01-01

Highlights: • A 3-D simulation model based on the chemical reaction kinetics is established. • The tumble near the trailing spark plug is beneficial for the combustion rate. • The best position of the trailing spark plug is at the rear of the tumble zone. • An increase of the tumble effect time can improve the combustion rate. • Considering the rate of pressure rise, the best ignition timing is 50 °CA (BTDC). - Abstract: The side-ported rotary engine fueled with natural gas is a new, clean, efficient energy system. This work aims to numerically study the performance, combustion and emission characteristics of a side-ported rotary engine fueled with natural gas under different ignition positions and ignition timings. Simulations were performed using multi-dimensional software ANASYS Fluent. On the basis of the software, a three-dimensional dynamic simulation model was established by writing dynamic mesh programs and choosing a detailed reaction mechanism. The three-dimensional dynamic simulation model, based on the chemical reaction kinetics, was also validated by the experimental data. Meanwhile, further simulations were then conducted to investigate how to impact the combustion process by the coupling function between ignition operating parameter and the flow field inside the cylinder. Simulation results showed that in order to improve the combustion efficiency, the trailing spark plug should be located at the rear of the tumble zone and the ignition timing should be advanced properly. This was mainly caused by the trailing spark plug being located at the rear of the tumble zone, as it not only allowed the fuel in the rear of combustion chamber to be burnt without delay, but also permitted the acceleration of the flame propagation by the tumble. Meanwhile, with advanced ignition timing, the time between ignition timing and the timing of the tumble disappearance increased, which led to an increase of the tumble effect time used to improve the combustion

Mechanisms and characteristics of silicon combustion in nitrogen

Energy Technology Data Exchange (ETDEWEB)

Mukasian, A.S.; Martynenko, V.M.; Merzhanov, A.G.; Borovinskaia, I.P.; Blinov, M.IU.

1986-10-01

An experimental study is made of the principal characteristics of combustion in the system silicon-nitrogen associated with phase transitions of the first kind (silicon melting and silicon nitride dissociation). Concepts of the combustion mechanism are developed on the basis of elementary models of combustion of the second kind and filtering combustion theory. In particular, it is shown that, in the pressure range studied (10-20 MPa), filtering does not limit the combustion process. Details of the experimental procedure and results are presented. 22 references.

Spray combustion of biomass-based renewable diesel fuel using multiple injection strategy in a constant volume combustion chamber

KAUST Repository

Jing, Wei; Wu, Zengyang; Roberts, William L.; Fang, Tiegang

2016-01-01

Effect of a two-injection strategy associated with a pilot injection on the spray combustion process was investigated under conventional diesel combustion conditions (1000 K and 21% O2 concentration) for a biomass-based renewable diesel fuel, i

Soot temperature and KL factor for biodiesel and diesel spray combustion in a constant volume combustion chamber

KAUST Repository

Zhang, Ji

2013-07-01

This paper presents measurements of the soot temperature and KL factor for biodiesel and diesel combustion in a constant volume chamber using a two-color technique. This technique uses a high-speed camera coupled with two narrowband filters (550. nm and 650. nm, 10. nm FWHM). After calibration, statistical analysis shows that the uncertainty of the two-color temperature is less than 5%, while it is about 50% for the KL factor. This technique is then applied to the spray combustion of biodiesel and diesel fuels under an ambient oxygen concentration of 21% and ambient temperatures of 800, 1000 and 1200. K. The heat release result shows higher energy utilization efficiency for biodiesel compared to diesel under all conditions; meanwhile, diesel shows a higher pressure increase due to its higher heating value. Biodiesel yields a lower temperature inside the flame area, a longer soot lift-off length, and a smaller soot area compared to diesel. Both the KL factor and the total soot with biodiesel are lower than with diesel throughout the entire combustion process, and this difference becomes larger as the ambient temperature decreases. Biodiesel shows approximately 50-100. K lower temperatures than diesel at the quasi-steady stage for 1000 and 1200. K ambient temperature, while diesel shows a lower temperature than biodiesel at 800. K ambient. This result may raise the question of how important the flame temperature is in explaining the higher NO. x emissions often observed during biodiesel combustion. Other factors may also play an important role in controlling NO. x emissions. Both biodiesel and diesel temperature measurements show a monotonic dependence on the ambient temperature. However, the ambient temperature appears to have a more significant effect on the soot formation and oxidation in diesel combustion, while biodiesel combustion soot characteristics shows relative insensitivity to the ambient temperature. © 2013 Elsevier Ltd.

Do factors related to combustion-based sources explain ...

Science.gov (United States)

Introduction: Spatial heterogeneity of effect estimates in associations between PM2.5 and total non-accidental mortality (TNA) in the United States (US), is an issue in epidemiology. This study uses rate ratios generated from the Multi-City/Multi-Pollutant study (1999-2005) for 313 core-based statistical areas (CBSA) and their metropolitan divisions (MD) to examine combustion-based sources of heterogeneity.Methods: For CBSA/MDs, area-specific log rate ratios (betas) were derived from a model adjusting for time, an interaction with age-group, day of week, and natural splines of current temperature, current dew point, and unconstrained temperature at lags 1, 2, and 3. We assessed the heterogeneity in the betas by linear regression with inverse variance weights, using average NO2, SO2, and CO, which may act as a combustion source proxy, and these pollutants’ correlations with PM2.5. Results: We found that weighted mean PM2.5 association (0.96 percent increase in total non-accidental mortality for a 10 µg/m3 increment in PM2.5) increased by 0.26 (95% confidence interval 0.08 , 0.44) for an interquartile change (0.2) in the correlation of SO2 and PM2.5., but betas showed less dependence on the annual averages of SO2 or NO2. Spline analyses suggest departures from linearity, particularly in a model that examined correlations between PM2.5 and CO.Conclusions: We conclude that correlations between SO2 and PM2.5 as an indicator of combustion sources explains some hete

Studies in combustion dynamics

Energy Technology Data Exchange (ETDEWEB)

Koszykowski, M.L. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01

The goal of this program is to develop a fundamental understanding and a quantitative predictive capability in combustion modeling. A large part of the understanding of the chemistry of combustion processes comes from {open_quotes}chemical kinetic modeling.{close_quotes} However, successful modeling is not an isolated activity. It necessarily involves the integration of methods and results from several diverse disciplines and activities including theoretical chemistry, elementary reaction kinetics, fluid mechanics and computational science. Recently the authors have developed and utilized new tools for parallel processing to implement the first numerical model of a turbulent diffusion flame including a {open_quotes}full{close_quotes} chemical mechanism.

Combustion/particle sizing experiments at the Naval Postgraduate School Combustion Research Laboratory

Science.gov (United States)

Powers, John; Netzer, David

1987-01-01

Particle behavior in combustion processes is an active research area at NPS. Currently, four research efforts are being conducted: (1) There is a long standing need to better understand the soot production and combustion processes in gas turbine combustors, both from a concern for improved engine life and to minimize exhaust particulates. Soot emissions are strongly effected by fuel composition and additives; (2) A more recent need for particle sizing/behavior measurements is in the combustor of a solid fuel ramjet which uses a metallized fuel. High speed motion pictures are being used to study rather large burning particles; (3) In solid propellant rocket motors, metals are used to improve specific impulse and/or to provide damping for combustion pressure oscillations. Particle sizing experiments are being conducted using diode arrays to measure the light intensity as a function of scattering angle; (4) Once a good quality hologram is attained, a need exists for obtaining the particle distributions from hologram in a short period of time. A Quantimet 720 Image Analyzer is being used to reconstruct images.

Optimization of a Gas Switching Combustion process through advanced heat management strategies

International Nuclear Information System (INIS)

Cloete, Schalk; Zaabout, Abdelghafour; Romano, Matteo C.; Chiesa, Paolo; Lozza, Giovanni; Gallucci, Fausto; Sint Annaland, Martin van; Amini, Shahriar

2017-01-01

Highlights: • GSC is a promising new reactor concept for power production with cost effective CO 2 capture. • The standalone fluidized bed reactors employed will allow for easy process scale-up. • The GSC simple configuration achieves higher efficiencies than conventional solutions. • Further increases in efficiency can be achieved via advanced heat management. • The 41.9% maximum efficiency is in line with other CLC–IGCC configurations. - Abstract: Gas Switching Combustion (GSC) is a promising new process concept for energy efficient power production with integrated CO 2 capture. In comparison to conventional Chemical Looping Combustion (CLC) carried out in interconnected fluidized beds, the GSC concept will be substantially easier to design and scale up, especially for pressurized conditions. One potential drawback of the GSC concept is the gradual temperature variation over the transient process cycle, which leads to a drop in electric efficiency of the plant. This article investigates heat management strategies to mitigate this issue both through simulations and experiments. Simulation studies of the GSC concept integrated into an IGCC power plant show that heat management using a nitrogen recycle stream can increase plant efficiency by 3 percentage points to 41.6% while maintaining CO 2 capture ratios close to 90%. Reactive multiphase flow simulations of the GSC reactor also showed that heat management can eliminate fuel slip problems. In addition, the GSC concept offers the potential to remove the need for a nitrogen recycle stream by implementing a concentrated air injection that extracts heat while only a small percentage of oxygen reacts. Experiments have shown that, similar to nitrogen recycle, this strategy reduces transient temperature variations across the cycle and therefore merits further investigation.

Infrared monitoring of combustion

International Nuclear Information System (INIS)

Bates, S.C.; Morrison, P.W. Jr.; Solomon, P.R.

1991-01-01

In this paper, the use of Fourier Transform Infrared (FT-IR) spectroscopy for combustion monitoring is described. A combination of emission, transmission, and reflection FT-IR spectroscopy yields data on the temperature and composition of the gases, surfaces and suspended particles in the combustion environment. Detection sensitivity of such trace exhaust gases as CO, CO 2 , SO 2 , NO x , and unburned hydrocarbons is at the ppm level. Tomographic reconstruction converts line-of-sight measurements into spatially resolved temperature and concentration data. Examples from various combustion processes are used to demonstrate the capabilities of the technique. Industrial measurements are described that have been performed directly in the combustion zone and in the exhaust duct of a large chemical recovery boiler. Other measurements of hot slag show how FT-IR spectroscopy can determine the temperature and optical properties of surfaces. In addition, experiments with water droplets show that transmission FT-IR data yield spectra that characterize particle size and number density

Large eddy simulation and combustion instabilities; Simulation des grandes echelles et instabilites de combustion

Energy Technology Data Exchange (ETDEWEB)

Lartigue, G.

2004-11-15

The new european laws on pollutants emission impose more and more constraints to motorists. This is particularly true for gas turbines manufacturers, that must design motors operating with very fuel-lean mixtures. Doing so, pollutants formation is significantly reduced but the problem of combustion stability arises. Actually, combustion regimes that have a large excess of air are naturally more sensitive to combustion instabilities. Numerical predictions of these instabilities is thus a key issue for many industrial involved in energy production. This thesis work tries to show that recent numerical tools are now able to predict these combustion instabilities. Particularly, the Large Eddy Simulation method, when implemented in a compressible CFD code, is able to take into account the main processes involved in combustion instabilities, such as acoustics and flame/vortex interaction. This work describes a new formulation of a Large Eddy Simulation numerical code that enables to take into account very precisely thermodynamics and chemistry, that are essential in combustion phenomena. A validation of this work will be presented in a complex geometry (the PRECCINSTA burner). Our numerical results will be successfully compared with experimental data gathered at DLR Stuttgart (Germany). Moreover, a detailed analysis of the acoustics in this configuration will be presented, as well as its interaction with the combustion. For this acoustics analysis, another CERFACS code has been extensively used, the Helmholtz solver AVSP. (author)

Method for the combustion of a gas, in fixed bed, with an oxidized solid and associated installation

OpenAIRE

Abanades García, Juan Carlos; Fernández García, José Ramón

2014-01-01

[EN] The present invention pertains to the field of the generation of energy from combustible gases, incorporating the capture of carbon dioxide for use or permanent storage and, specifically relates to cyclical methods of gas combustion with oxidized solids (chemical looping processes), in fixed bed, for solving the problem of controlling temperature in the combustion of gaseous fuels in fixed beds of metal oxides operating at high pressures, and also the associated installation.

Improved Modeling of Finite-Rate Turbulent Combustion Processes in Research Combustors

Science.gov (United States)

VanOverbeke, Thomas J.

1998-01-01

The objective of this thesis is to further develop and test a stochastic model of turbulent combustion in recirculating flows. There is a requirement to increase the accuracy of multi-dimensional combustion predictions. As turbulence affects reaction rates, this interaction must be more accurately evaluated. In this work a more physically correct way of handling the interaction of turbulence on combustion is further developed and tested. As turbulence involves randomness, stochastic modeling is used. Averaged values such as temperature and species concentration are found by integrating the probability density function (pdf) over the range of the scalar. The model in this work does not assume the pdf type, but solves for the evolution of the pdf using the Monte Carlo solution technique. The model is further developed by including a more robust reaction solver, by using accurate thermodynamics and by more accurate transport elements. The stochastic method is used with Semi-Implicit Method for Pressure-Linked Equations. The SIMPLE method is used to solve for velocity, pressure, turbulent kinetic energy and dissipation. The pdf solver solves for temperature and species concentration. Thus, the method is partially familiar to combustor engineers. The method is compared to benchmark experimental data and baseline calculations. The baseline method was tested on isothermal flows, evaporating sprays and combusting sprays. Pdf and baseline predictions were performed for three diffusion flames and one premixed flame. The pdf method predicted lower combustion rates than the baseline method in agreement with the data, except for the premixed flame. The baseline and stochastic predictions bounded the experimental data for the premixed flame. The use of a continuous mixing model or relax to mean mixing model had little effect on the prediction of average temperature. Two grids were used in a hydrogen diffusion flame simulation. Grid density did not effect the predictions except

Bifurcation, pattern formation and chaos in combustion

International Nuclear Information System (INIS)

Bayliss, A.; Matkowsky, B.J.

1991-01-01

In this paper problems in gaseous combustion and in gasless condensed phase combustion are studied both analytically and numerically. In gaseous combustion we consider the problem of a flame stabilized on a line source of fuel. The authors find both stationary and pulsating axisymmetric solutions as well as stationary and pulsating cellular solutions. The pulsating cellular solutions take the form of either traveling waves or standing waves. Transitions between these patterns occur as parameters related to the curvature of the flame front and the Lewis number are varied. In gasless condensed phase combustion both planar and nonplanar problems are studied. For planar condensed phase combustion we consider two models: accounts for melting and does not. Both models are shown to exhibit a transition from uniformly to pulsating propagating combustion when a parameter related to the activation energy is increased. Upon further increasing this parameter both models undergo a transition to chaos: by intermittency and by a period doubling sequence. In nonplanar condensed phase combustion the nonlinear development of a branch of standing wave solutions is studied and is shown to lead to relaxation oscillations and subsequently to a transition to quasi-periodicity

Methodology for processing pressure traces used as inputs for combustion analyses in diesel engines

International Nuclear Information System (INIS)

Rašić, Davor; Vihar, Rok; Baškovič, Urban Žvar; Katrašnik, Tomaž

2017-01-01

This study proposes a novel methodology for designing an optimum equiripple finite impulse response (FIR) filter for processing in-cylinder pressure traces of a diesel internal combustion engine, which serve as inputs for high-precision combustion analyses. The proposed automated workflow is based on an innovative approach of determining the transition band frequencies and optimum filter order. The methodology is based on discrete Fourier transform analysis, which is the first step to estimate the location of the pass-band and stop-band frequencies. The second step uses short-time Fourier transform analysis to refine the estimated aforementioned frequencies. These pass-band and stop-band frequencies are further used to determine the most appropriate FIR filter order. The most widely used existing methods for estimating the FIR filter order are not effective in suppressing the oscillations in the rate- of-heat-release (ROHR) trace, thus hindering the accuracy of combustion analyses. To address this problem, an innovative method for determining the order of an FIR filter is proposed in this study. This method is based on the minimization of the integral of normalized signal-to-noise differences between the stop-band frequency and the Nyquist frequency. Developed filters were validated using spectral analysis and calculation of the ROHR. The validation results showed that the filters designed using the proposed innovative method were superior compared with those using the existing methods for all analyzed cases. Highlights • Pressure traces of a diesel engine were processed by finite impulse response (FIR) filters with different orders • Transition band frequencies were determined with an innovative method based on discrete Fourier transform and short-time Fourier transform • Spectral analyses showed deficiencies of existing methods in determining the FIR filter order • A new method of determining the FIR filter order for processing pressure traces was

Optimization of combustion process for radiation-treated solid fuels in dust state

International Nuclear Information System (INIS)

Askarova, A.S.; Bajdullaeva, G.E.

1997-01-01

Computation experiment on combustion of solid radiation-treated fuel in burning chamber of boiler at Pavlodar thermal electric plant is carried out. Velocity, temperature distribution and concentration of combustion products by height of chamber are received. Analysis of received results shows that radiation treatment of fuels exerts substantial effect on egress parameters of thermal electric plant. It is shown, that radiation treatment allows to improve effectiveness of boiler device and reduce of harmful substances discharge in atmosphere. Results of conducted numerical experiments allow to create complete methods of solid fuel combustion with high moisture and ashiness

Combustion engineering

CERN Document Server

Ragland, Kenneth W

2011-01-01

Introduction to Combustion Engineering The Nature of Combustion Combustion Emissions Global Climate Change Sustainability World Energy Production Structure of the Book   Section I: Basic Concepts Fuels Gaseous Fuels Liquid Fuels Solid Fuels Problems Thermodynamics of Combustion Review of First Law Concepts Properties of Mixtures Combustion StoichiometryChemical EnergyChemical EquilibriumAdiabatic Flame TemperatureChemical Kinetics of CombustionElementary ReactionsChain ReactionsGlobal ReactionsNitric Oxide KineticsReactions at a Solid SurfaceProblemsReferences  Section II: Combustion of Gaseous and Vaporized FuelsFlamesLaminar Premixed FlamesLaminar Flame TheoryTurbulent Premixed FlamesExplosion LimitsDiffusion FlamesGas-Fired Furnaces and BoilersEnergy Balance and EfficiencyFuel SubstitutionResidential Gas BurnersIndustrial Gas BurnersUtility Gas BurnersLow Swirl Gas BurnersPremixed-Charge Engine CombustionIntroduction to the Spark Ignition EngineEngine EfficiencyOne-Zone Model of Combustion in a Piston-...

Effects of biomass on dynamics of combustion in circulating fluidized beds

Directory of Open Access Journals (Sweden)

Tourunen Antti

2004-01-01

Full Text Available Fluidized bed technology is very suitable for the combustion of biomass Nevertheless substitution of coal with biomass affects boiler operation and especially dynamics and controllability. Non-homogeneity of biomass and fuel feeding disturbances cause process instability, such as variations in temperatures and pressures, which reduce lifetime of equipment and structures. Because of process instability higher air coefficient must be used in order to avoid CO emissions, which is not economical. Combustion profiles for coal, wood and peat, measured at the VTT Processes Pilot circulating fluidized bed reactor, have been compared. Process stability and char inventories have been studied by the measurements and the model. Biofuel are usually very reactive and their combustion profiles are quite different compared to coals. Because of high reactivity and low char content combustion process with biofuel is very sensitive for fuel feeding. Also low char inventory effect on load changes combined with combustion profile that differs from coals. Because of different combustion profile heat transfer can be a limiting factor in load changes despite the high reactivity and fast oxygen response.

Thermodynamic energy and exergy analysis of three different engine combustion regimes

International Nuclear Information System (INIS)

Li, Yaopeng; Jia, Ming; Chang, Yachao; Kokjohn, Sage L.; Reitz, Rolf D.

2016-01-01

Highlights: • Energy and exergy distributions of three different combustion regimes are studied. • CDC demonstrates the highest utilization efficiency of heat transfer and exhaust. • HCCI achieves the highest energy and exergy efficiencies over CDC and RCCI. • HCCI and RCCI demonstrate lower exergy destruction than CDC. • Combustion temperature, rate, duration and regime affect exergy destruction. - Abstract: Multi-dimensional models were coupled with a detailed chemical mechanism to investigate the energy and exergy distributions of three different combustion regimes in internal combustion engines. The results indicate that the 50% heat release point (CA50) considerably affects fuel efficiency and ringing intensity (RI), in which RI is used to quantify the knock level. Moreover, the burn duration from the 10% heat release point (CA10) to CA50 dominates RI, and the position of 90% heat release point (CA90) affects fuel efficiency. The heat transfer losses of conventional diesel combustion (CDC) strongly depend on the local temperature gradient, while it is closely related to the heat transfer area for homogeneous charge compression ignition (HCCI) and reactivity controlled compression ignition (RCCI). Among the three combustion regimes, CDC has the largest utilization efficiency for heat transfer and exhaust energy due to its higher temperature in the heat transfer layer and higher exhaust pressure and temperature. The utilization efficiency of heat transfer and exhaust in RCCI is less affected by the variation of CA50 compared to those in CDC and HCCI. Exergy destruction is closely related to the homogeneity of in-cylinder temperature and equivalence ratio during combustion process, the combustion temperature, the chemical reaction rate, and the combustion duration. Under the combined effect, HCCI and RCCI demonstrate lower exergy destruction than CDC at the same load. Overall, the variations of the exergy distribution for the three combustion regimes

Proceedings of IEA combustion 2009 : IEA 31. task leaders meeting on energy conservation and emissions reduction in combustion

International Nuclear Information System (INIS)

2009-01-01

The International Energy Agency (IEA) supports research and development in energy technology. This meeting provided a forum to discuss combustion processes, which is fundamental to achieving further improvements in fuel use efficiency, reducing the production of pollutants such as nitrogen oxides, and facilitating the transition to alternative fuels. The presentations demonstrated recent studies in improving the efficiency and fuel flexibility of automotive engines; improving the performance of industrial furnaces; emissions formation and control mechanisms; and fuel injection and fuel/air mixing. The conference also highlighted studies involving hydrogen combustion, alternative fuels, particulate diagnostics, fuel sprays, gas turbines, and advanced combustion processes such as homogeneous charge compression ignition (HCCI). The sessions were entitled: HCCI fuels; sprays; nanoparticle diagnostics; alternative fuels; hydrogen internal combustion engines; turbines; energy security; and collaborative task planning. All 45 presentations from the conference have been catalogued separately for inclusion in this database. refs., tabs., figs.

Influence of the hydrothermal dewatering on the combustion characteristics of Chinese low-rank coals

International Nuclear Information System (INIS)

Ge, Lichao; Zhang, Yanwei; Xu, Chang; Wang, Zhihua; Zhou, Junhu; Cen, Kefa

2015-01-01

This study investigates the influence of hydrothermal dewatering performed at different temperatures on the combustion characteristics of Chinese low-rank coals with different coalification maturities. It was found that the upgrading process significantly decreased the inherent moisture and oxygen content, increased the calorific value and fixed carbon content, and promoted the damage of the hydrophilic oxygen functional groups. The results of oxygen/carbon atomic ratio indicated that the upgrading process converted the low-rank coals near to high-rank coals which can also be gained using the Fourier transform infrared spectroscopy. The thermogravimetric analysis showed that the combustion processes of upgraded coals were delayed toward the high temperature region, and the upgraded coals had higher ignition and burnout temperature. On the other hand, based on the higher average combustion rate and comprehensive combustion parameter, the upgraded coals performed better compared with raw brown coals and the Da Tong bituminous coal. In ignition segment, the activation energy increased after treatment but decreased in the combustion stage. The changes in coal compositions, microstructure, rank, and combustion characteristics were more notable as the temperature in hydrothermal dewatering increased from 250 to 300 °C or coals of lower ranks were used. - Highlights: • Typical Chinese lignites with various ranks are upgraded by hydrothermal dewatering. • Upgraded coals exhibit chemical compositions comparable with that of bituminous coal. • FTIR show the change of microstructure and improvement in coal rank after upgrading. • Upgraded coals exhibit difficulty in ignition but combust easily. • More evident effects are obtained for raw brown coal with relative lower rank.

Combustion optimization and HCCI modeling for ultra low emission

Energy Technology Data Exchange (ETDEWEB)

Koten, Hasan; Yilmaz, Mustafa; Zafer Gul, M. [Marmara University Mechanical Engineering Department (Turkey)], E-mail: hasan.koten@marmara.edu.tr

2011-07-01

With the coming shortage of fossil fuels and the rising concerns over the environment it is important to develop new technologies both to reduce energy consumption and pollution at the same time. In the transportation sector, new combustion processes are under development to provide clean diesel combustion with no particulate or NOx emissions. However, these processes have issues such as limited power output, high levels of unburned hydrocarbons, and carbon monoxide emissions. The aim of this paper is to present a methodology for optimizing combustion performance. The methodology consists of the use of a multi-objective genetic algorithm optimization tool; homogeneous charge compression ignition engine cases were studied with the ECFM-3Z combustion model. Results showed that injected fuel mass led to a decrease in power output, a finding which is in keeping with previous research. This paper presented on optimization tool which can be useful in improving the combustion process.

Internal and Surface Phenomena in Heterogenous Metal Combustion

Science.gov (United States)

Dreizin, Edward L.

1997-01-01

The phenomenon of gas dissolution in burning metals was observed in recent metal combustion studies, but it could not be adequately explained by the traditional metal combustion models. The research reported here addresses heterogeneous metal combustion with emphasis on the processes of oxygen penetration inside burning metal and its influence on the metal combustion rate, temperature history, and disruptive burning. The unique feature of this work is the combination of the microgravity environment with a novel micro-arc generator of monodispersed metal droplets, ensuring repeatable formation and ignition of uniform metal droplets with a controllable initial temperature and velocity. Burning droplet temperature is measured in real time with a three wavelength pyrometer. In addition, particles are rapidly quenched at different combustion times, cross-sectioned, and examined using SEM-based techniques to retrieve the internal composition history of burning metal particles. When the initial velocity of a spherical particle is nearly zero, the microgravity environment makes it possible to study the flame structure, the development of flame nonsymmetry, and correlation of the flame shape with the heterogeneous combustion processes.

Emissions from small scale biomass combustion - Research needs

International Nuclear Information System (INIS)

Gustavsson, L.; Karlsson, M.L.; Larfeldt, J.; Leckner, B.

1994-01-01

Earlier investigations have shown that small scale biomass combustion leads to unacceptable emissions in the air. The most important problem is high levels of unburnt hydrocarbons. This report analyzes which are the most important reasons to these emissions and which research efforts that are necessary to increase the knowledge about the combustion processes, thereby promoting the development of environmentally feasible equipment. The following factors are defined as most crucial to emission levels: size of combustion chamber, air excess ratio, means of combustion air supply, mixing between air and fuel, transient events, and fuel quality. It is concluded that both basic and research within the area is needed. More specific, research in the form of systematic analysis of best available technology, reactor experiments, compilation of knowledge about relevant basic combustion processes, mathematical modelling as well as development of measurement techniques are called for. 15 refs, 11 figs, 1 tab

LIEKKI 2 - Combustion technology is environmental technology

Energy Technology Data Exchange (ETDEWEB)

Hupa, M. [Aabo Akademi, Turku (Finland)

1996-12-31

Finland has wide experience in applications of various combustion technologies and fuels and in supplying energy to industry and municipalities. Furthermore, combustion hardware and equipment are amongst our most important export products. Above all, fluidized bed boilers, recovery boilers for pulp mills and heavy diesel engines and diesel power plants have achieved excellent success in the world markets. Exports of these products alone have amounted to several billions of Finnish marks of annual sales in recent years. Within modern combustion technology, the objective is to control flue gas emissions as far as possible in the process itself, thus doing away with the need for the separate scrubbing of flue gases. To accomplish this it has been necessary to conduct a large amount of research on the details of the chemistry of combustion emissions and the flows in furnaces and engine cylinders. A host of completely new products are being developed for the combustion technology field. The LIEKKI programme has been particularly interested in so-called combined-cycle processes based on pressurized fluidized bed technology

Sandia Combustion Research Program

Energy Technology Data Exchange (ETDEWEB)

Johnston, S.C.; Palmer, R.E.; Montana, C.A. (eds.)

1988-01-01

During the late 1970s, in response to a national energy crisis, Sandia proposed to the US Department of Energy (DOE) a new, ambitious program in combustion research. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''user facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative-involving US inventories, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions several research projects which have been simulated by working groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship program, supported through the Office of Energy Research, has been instrumental in the success of some of these joint efforts. The remainder of this report presents results of calendar year 1988, separated thematically into eleven categories. Referred journal articles appearing in print during 1988 and selected other publications are included at the end of Section 11. Our traditional'' research activities--combustion chemistry, reacting flows, diagnostics, engine and coal combustion--have been supplemented by a new effort aimed at understanding combustion-related issues in the management of toxic and hazardous materials.

Manifold methods for methane combustion

Energy Technology Data Exchange (ETDEWEB)

Yang, B.; Pope, S.B. [Cornell Univ., Ithaca, NY (United States)

1995-10-01

Great progresses have been made in combustion research, especially, the computation of laminar flames and the probability density function (PDF) method in turbulent combustion. For one-dimensional laminar flames, by considering the transport mechanism, the detailed chemical kinetic mechanism and the interactions between these two basic processes, today it is a routine matter to calculate flame velocities, extinction, ignition, temperature, and species distributions from the governing equations. Results are in good agreement with those obtained for experiments. However, for turbulent combustion, because of the complexities of turbulent flow, chemical reactions, and the interaction between them, in the foreseeable future, it is impossible to calculate the combustion flow field by directly integrating the basic governing equations. So averaging and modeling are necessary in turbulent combustion studies. Averaging, on one hand, simplifies turbulent combustion calculations, on the other hand, it introduces the infamous closure problems, especially the closure problem with chemical reaction terms. Since in PDF calculations of turbulent combustion, the averages of the chemical reaction terms can be calculated, PDF methods overcome the closure problem with the reaction terms. It has been shown that the PDF method is a most promising method to calculate turbulent combustion. PDF methods have been successfully employed to calculate laboratory turbulent flames: they can predict phenomena such as super equilibrium radical levels, and local extinction. Because of these advantages, PDF methods are becoming used increasingly in industry combustor codes.

Aerosol Combustion Synthesis of Nanopowders and Processing to Functional Thin Films

Science.gov (United States)

Yi, Eongyu

In this dissertation, the advantages of liquid-feed flame spray pyrolysis (LF-FSP) process in producing nanoparticles (NPs) as well as processing the produced NPs to ceramic/polymer nanocomposite films and high density polycrystalline ceramic films are demonstrated. The LF-FSP process aerosolizes alcohol solutions of metalloorganic precursors by oxygen and combusts them at > 1500 °C. The combustion products are rapidly quenched ( 10s of ms) to green and potentially lower cost alternative. We then show the versatility of NPs in formulating flexible ceramic/polymer nanocomposites (BaTiO3/epoxy) with superior properties. Volume fractions of the BaTiO3 filler and composite film thicknesses were controlled to adjust the net dielectric constant and the capacitance. Measured net dielectric constants further deviated from theory, with increasing solids loadings, due to NP agglomeration. Wound nanocomposite capacitors showed ten times higher capacitance compared to the commercial counterpart. Following series of studies explore the use of flame made NPs in processing Li+ conducting membranes. Systematic doping studies were conducted in the LiTi2(PO4)3 system to modify the lattice constant, conduction channel width, and sintering behavior by introducing Al3+ and Si4+ dopants. Excess Li2O content was also adjusted to observe its effect on final microstructures and phase compositions. Improved densification rates were found in Li1.7 Al0.3Ti1.7Si0.4P2.6O 12 composition and thin films (52+/-1 microm) with conductivities of 0.3-0.5 mS cm-1 were achieved. Li6.25M0.25La3Zr2O12 (M = Al3+, Ga3+) thin films (25-28 microm) with conductivities of 0.2-1.3 mS cm-1 were also successfully processed using flame made NPs, overcoming processing challenges extant, resulting in significantly reduced energy input required for densification. Heating schedules, sintering atmospheres, and types of substrates were controlled to observe their effect on the sintering behavior. Furthermore, green film

Quantitative Measurement of Oxygen in Microgravity Combustion

Science.gov (United States)

Silver, Joel A.

1997-01-01

A low-gravity environment, in space or in ground-based facilities such as drop towers, provides a unique setting for studying combustion mechanisms. Understanding the physical phenomena controlling the ignition and spread of flames in microgravity has importance for space safety as well as for better characterization of dynamical and chemical combustion processes which are normally masked by buoyancy and other gravity-related effects. Due to restrictions associated with performing measurements in reduced gravity, diagnostic methods which have been applied to microgravity combustion studies have generally been limited to capture of flame emissions on film or video, laser Schlieren imaging and (intrusive) temperature measurements using thermocouples. Given the development of detailed theoretical models, more sophisticated diagnostic methods are needed to provide the kind of quantitative data necessary to characterize the properties of microgravity combustion processes as well as provide accurate feedback to improve the predictive capabilities of the models. When the demands of space flight are considered, the need for improved diagnostic systems which are rugged, compact, reliable, and operate at low power becomes apparent. The objective of this research is twofold. First, we want to develop a better understanding of the relative roles of diffusion and reaction of oxygen in microgravity combustion. As the primary oxidizer species, oxygen plays a major role in controlling the observed properties of flames, including flame front speed (in solid or liquid flames), extinguishment characteristics, flame size and flame temperature. The second objective is to develop better diagnostics based on diode laser absorption which can be of real value in both microgravity combustion research and as a sensor on-board Spacelab as either an air quality monitor or as part of a fire detection system. In our prior microgravity work, an eight line-of-sight fiber optic system measured

Flow and Combustion in Advanced Gas Turbine Combustors

CERN Document Server

Janicka, Johannes; Schäfer, Michael; Heeger, Christof

2013-01-01

With regard to both the environmental sustainability and operating efficiency demands, modern combustion research has to face two main objectives, the optimization of combustion efficiency and the reduction of pollutants. This book reports on the combustion research activities carried out within the Collaborative Research Center (SFB) 568 “Flow and Combustion in Future Gas Turbine Combustion Chambers” funded by the German Research Foundation (DFG). This aimed at designing a completely integrated modeling and numerical simulation of the occurring very complex, coupled and interacting physico-chemical processes, such as turbulent heat and mass transport, single or multi-phase flows phenomena, chemical reactions/combustion and radiation, able to support the development of advanced gas turbine chamber concepts.

Experimental investigations of butanol-gasoline blends effects on the combustion process in a SI engine

Energy Technology Data Exchange (ETDEWEB)

Merola, Simona Silvia; Tornatore, Cinzia; Machitto, Luca; Valentino, Gerardo; Corcione, Felice Esposito [Istituto Motori-CNR, Naples (Italy)

2012-07-01

Fuel blend of alcohol and conventional hydrocarbon fuels for a spark-ignition engine can increase the fuel octane rating and the power for a given engine displacement and compression ratio. In this work, the influence of butanol addition to gasoline in a port fuel-injection, spark ignition engine was investigated. The experiments were realized in a single cylinder ported fuel injection SI engine with an external boosting device. The optical accessible engine was equipped with the head of commercial SI turbocharged engine with the same geometrical specifications (bore, stroke, compression ratio) as the research engine. The effect on the spark ignition combustion process of 20% and 40% of n-butanol blended in volume with pure gasoline was investigated through cycle resolved visualization. The engine worked at low speed, medium boosting and wide open throttle. Fuel injections both in closed valve and open valve conditions were considered. Comparisons between the parameters related to the flame luminosity and the pressure signals were performed. Butanol blends allowed working in more advanced spark timing without knocking occurrence. The duration of injection for Butanol blends was increased to obtain stoichiometric mixture. In open valve injection condition, the fuel deposits on intake manifold and piston surfaces decreased, allowing a reduction in fuel consumption. BU40 granted the performance levels of gasoline and in open valve injection allowed to minimize the abnormal combustion effects including the emission of ultrafine carbonaceous particles at the exhaust. In-cylinder investigations were correlated to engine out emissions. (orig.)

Hydrogen combustion modelling in large-scale geometries

International Nuclear Information System (INIS)

Studer, E.; Beccantini, A.; Kudriakov, S.; Velikorodny, A.

2014-01-01

Hydrogen risk mitigation issues based on catalytic recombiners cannot exclude flammable clouds to be formed during the course of a severe accident in a Nuclear Power Plant. Consequences of combustion processes have to be assessed based on existing knowledge and state of the art in CFD combustion modelling. The Fukushima accidents have also revealed the need for taking into account the hydrogen explosion phenomena in risk management. Thus combustion modelling in a large-scale geometry is one of the remaining severe accident safety issues. At present day there doesn't exist a combustion model which can accurately describe a combustion process inside a geometrical configuration typical of the Nuclear Power Plant (NPP) environment. Therefore the major attention in model development has to be paid on the adoption of existing approaches or creation of the new ones capable of reliably predicting the possibility of the flame acceleration in the geometries of that type. A set of experiments performed previously in RUT facility and Heiss Dampf Reactor (HDR) facility is used as a validation database for development of three-dimensional gas dynamic model for the simulation of hydrogen-air-steam combustion in large-scale geometries. The combustion regimes include slow deflagration, fast deflagration, and detonation. Modelling is based on Reactive Discrete Equation Method (RDEM) where flame is represented as an interface separating reactants and combustion products. The transport of the progress variable is governed by different flame surface wrinkling factors. The results of numerical simulation are presented together with the comparisons, critical discussions and conclusions. (authors)

A Mixing Based Model for DME Combustion in Diesel Engines

DEFF Research Database (Denmark)

Bek, Bjarne H.; Sorenson, Spencer C.

1998-01-01

A series of studies has been conducted investigating the behavior of di-methyl ether (DME) fuel jets injected into quiescent combus-tion chambers. These studies have shown that it is possible to make a good estimate of the penetration of the jet based on existing correlations for diesel fuel......, by using appropriate fuel properties. The results of the spray studies have been incorporated into a first generation model for DME combustion. The model is entirely based on physical mixing, where chemical processes have been assumed to be very fast in relation to mixing. The assumption was made...

A mixing based model for DME combustion in diesel engines

DEFF Research Database (Denmark)

Bek, Bjarne Hjort; Sorenson, Spencer C

2001-01-01

A series of studies has been conducted investigating the behavior of di-methyl ether (DME) fuel jets injected into quiescent combustion chambers. These studies have shown that it is possible to make a good estimate of the penetration of the jet based on existing correlations for diesel fuel......, by using appropriate fuel properties. The results of the spray studies have been incorporated into a first generation model for DME combustion. The model is entirely based on physical mixing, where chemical processes have been assumed to be very fast in relation to mixing. The assumption was made...

Investigation of Spark Ignition and Autoignition in Methane and Air Using Computational Fluid Dynamics and Chemical Reaction Kinetics. A numerical Study of Ignition Processes in Internal Combustion Engines

Energy Technology Data Exchange (ETDEWEB)

Nordrik, R.

1993-12-01

The processes in the combustion chamber of internal combustion engines have received increased attention in recent years because their efficiencies are important both economically and environmentally. This doctoral thesis studies the ignition phenomena by means of numerical simulation methods. The fundamental physical relations include flow field conservation equations, thermodynamics, chemical reaction kinetics, transport properties and spark modelling. Special attention is given to the inclusion of chemical kinetics in the flow field equations. Using his No Transport of Radicals Concept method, the author reduces the computational efforts by neglecting the transport of selected intermediate species. The method is validated by comparison with flame propagation data. A computational method is described and used to simulate spark ignition in laminar premixed methane-air mixtures and the autoignition process of a methane bubble surrounded by hot air. The spark ignition simulation agrees well with experimental results from the literature. The autoignition simulation identifies the importance of diffusive and chemical processes acting together. The ignition delay times exceed the experimental values found in the literature for premixed ignition delay, presumably because of the mixing process and lack of information on low temperature reactions in the skeletal kinetic mechanism. Transient turbulent methane jet autoignition is simulated by means of the KIVA-II code. Turbulent combustion is modelled by the Eddy Dissipation Concept. 90 refs., 81 figs., 3 tabs.

Combustion

CERN Document Server

Glassman, Irvin

1987-01-01

Combustion, Second Edition focuses on the underlying principles of combustion and covers topics ranging from chemical thermodynamics and flame temperatures to chemical kinetics, detonation, ignition, and oxidation characteristics of fuels. Diffusion flames, flame phenomena in premixed combustible gases, and combustion of nonvolatile fuels are also discussed. This book consists of nine chapters and begins by introducing the reader to heats of reaction and formation, free energy and the equilibrium constants, and flame temperature calculations. The next chapter explores the rates of reactio

Combustion chemistry - activities in the CHEK research programme

Energy Technology Data Exchange (ETDEWEB)

Dam-Johansen, K.; Johnsson, J.E.; Glarborg, P.; Frandsen, F.; Jensen, A.; Oestberg, M. [Technical Univ. of Denmark, Lyngby (Denmark). Dept. of Chemical Engineering

1997-10-01

The combustion chemistry in the oxidation of fossil fuels and biofuels determines together with mixing and heat transfer the required size of a furnace, the emission of gaseous pollutants, and the formation of ash and deposits on surfaces. This presentation describes technologies for solid fuels combustion and gives a summary of the fuels, the pollutant chemistry and the inorganic chemistry in combustion processes. Emphasis is put on the work carried out in the CHEC (Combustion and Harmful Emission Control) Research Programme. (orig.)

14th congress of combustion by-products and their health effects-origin, fate, and health effects of combustion-related air pollutants in the coming era of bio-based energy sources.

Science.gov (United States)

Weidemann, Eva; Andersson, Patrik L; Bidleman, Terry; Boman, Christoffer; Carlin, Danielle J; Collina, Elena; Cormier, Stephania A; Gouveia-Figueira, Sandra C; Gullett, Brian K; Johansson, Christer; Lucas, Donald; Lundin, Lisa; Lundstedt, Staffan; Marklund, Stellan; Nording, Malin L; Ortuño, Nuria; Sallam, Asmaa A; Schmidt, Florian M; Jansson, Stina

2016-04-01

The 14th International Congress on Combustion By-Products and Their Health Effects was held in Umeå, Sweden from June 14th to 17th, 2015. The Congress, mainly sponsored by the National Institute of Environmental Health Sciences Superfund Research Program and the Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning, focused on the "Origin, fate and health effects of combustion-related air pollutants in the coming era of bio-based energy sources". The international delegates included academic and government researchers, engineers, scientists, policymakers and representatives of industrial partners. The Congress provided a unique forum for the discussion of scientific advances in this research area since it addressed in combination the health-related issues and the environmental implications of combustion by-products. The scientific outcomes of the Congress included the consensus opinions that: (a) there is a correlation between human exposure to particulate matter and increased cardiac and respiratory morbidity and mortality; (b) because currently available data does not support the assessment of differences in health outcomes between biomass smoke and other particulates in outdoor air, the potential human health and environmental impacts of emerging air-pollution sources must be addressed. Assessment will require the development of new approaches to characterize combustion emissions through advanced sampling and analytical methods. The Congress also concluded the need for better and more sustainable e-waste management and improved policies, usage and disposal methods for materials containing flame retardants.

Methods for Characterization of the Diesel Combustion and Emission Formation Processes

Energy Technology Data Exchange (ETDEWEB)

Lindstroem, Mikael

2011-07-01

In this thesis various aspects of the diesel engine fuel injection, combustion and emission formation processes have been evaluated. Several types of evaluation tools and methods have been applied. Fuel spray momentum was used to characterize injection rate and hole-to-hole variations in fuel injectors. Using both instantaneous fuel impulse rates and instantaneous mass flow measurements, spray velocity and nozzle flow parameters were evaluated. Several other hole-to-hole resolved injector characterization methods were used to characterize a set of fuel injectors subjected to long term testing. Fuel injector nozzle hole-to-hole variations were found to have a large influence on engine efficiency and emissions. The degree of hole-to-hole variations for an injector has been shown to correlate well with the performance deterioration of that injector. The formation and atomization of fuel sprays, ignition onset and the development of diffusion flames were studied using an optical engine. Flame temperature evaluations have been made using two different methods. NO-formation depends strongly on flame temperature. By applying a NO-formation evaluation method based on both heat release rate and flame and gas temperature it was possible to achieve a reasonable degree of correlation with measured exhaust emissions for very varying operating conditions. The prediction capability of the NO-formation evaluation method was utilized to evaluate spatially and temporally resolved NO-formation from flame temperature distributions. This made it possible to pinpoint areas with a high degree of NO-formation. It was found that small hot zones in the flames can be responsible for a large part of the total amount of NO that is produced, especially in combustion cases where no EGR is used to lower the flame temperature. By applying optical diagnostics methods the combustion and emission formation phenomena encountered during production engine transients were evaluated. The transient

Real-time combustion control and diagnostics sensor-pressure oscillation monitor

Science.gov (United States)

Chorpening, Benjamin T [Morgantown, WV; Thornton, Jimmy [Morgantown, WV; Huckaby, E David [Morgantown, WV; Richards, George A [Morgantown, WV

2009-07-14

An apparatus and method for monitoring and controlling the combustion process in a combustion system to determine the amplitude and/or frequencies of dynamic pressure oscillations during combustion. An electrode in communication with the combustion system senses hydrocarbon ions and/or electrons produced by the combustion process and calibration apparatus calibrates the relationship between the standard deviation of the current in the electrode and the amplitudes of the dynamic pressure oscillations by applying a substantially constant voltage between the electrode and ground resulting in a current in the electrode and by varying one or more of (1) the flow rate of the fuel, (2) the flow rate of the oxidant, (3) the equivalence ratio, (4) the acoustic tuning of the combustion system, and (5) the fuel distribution in the combustion chamber such that the amplitudes of the dynamic pressure oscillations in the combustion chamber are calculated as a function of the standard deviation of the electrode current. Thereafter, the supply of fuel and/or oxidant is varied to modify the dynamic pressure oscillations.

Examinations of the process of hard coal and biomass blend combustion in OEA (oxygen enriched atmosphere)

International Nuclear Information System (INIS)

Pawlak-Kruczek, Halina; Ostrycharczyk, Michał; Czerep, Michał; Baranowski, Marcin; Zgóra, Jacek

2015-01-01

The benefits of oxygen enrichment have been demonstrated in a variety of industrial combustion applications, but to date no implementation of oxygen enrichment in boilers has been reported, primarily due to their already high thermal efficiencies and a very large scale of such systems, which require significant amounts of oxygen. But recently, oxygen combustion in boilers has become one of the CCS technologies which can be an effective tool for reducing greenhouse gases emissions, and oxygen enriched combustion is suitable for low-calorific fuels, including biomass. This paper analyses the use of oxygen enrichment in a furnace for co-firing of different kinds of biomass with hard coal in terms of emission and burnout impact (LOI). As a part of this research, the effect of injection oxygen mode and total oxygen concentration on the flue gas emission (SO_2, NO_x) and burnout from co-firing of straw and wooden biomass in different proportions (20% and 40%) with hard coal were studied. The co-firing tests were carried out in an isothermal flow reactor. One of the benefits from the OEA (oxygen enriched atmosphere) technology is more effective separation of CO_2 owing to the higher CO_2 concentration in the flue gas. The additional advantage of the OEA combustion technology in comparison with oxy-fuel combustion is that the OEA process needs lower O_2 purities and therefore it is cost-effective. Experimental tests on co-firing of 20% straw-hard coal blend were conducted in oxygen enriched (up to 25 and 30%) atmospheres with three variants of O_2 injection modes. NO_x, SO_2 emissions and burnout for the various atmospheres in the combustion chamber were studied. Moreover, co-firing tests were performed with 40% share of wooden biomass to examine the effect of the biomass share and a type on emission of NO_x and SO_2 in OEA. The two O_2 injection modes were investigated. In each case, the emission of SO_2 increases alongside an increase of oxygen concentration in

THE INFLUENCE OF SELECTED GASEOUS FUELS ON THE COMBUSTION PROCESS IN THE SI ENGINE

Directory of Open Access Journals (Sweden)

Marek FLEKIEWICZ

2017-09-01

Full Text Available This paper presents the results of SI engine tests, carried out for different gaseous fuels. The analysis carried out made it possible to define the correlation between fuel composition and engine operating parameters. The tests covered various gaseous mixtures: methane with hydrogen from 5% to 50% by volume and LPG with DME from 5% to 26% by mass. The first group, considered as low-carbon-content fuels can be characterized by low CO2 emissions. Flammability of hydrogen added in those mixtures realizes the function of the combustion process activator. Thus, hydrogen addition improves energy conversion by about 3%. The second group of fuels is constituted by LPG and DME mixtures. DME mixes perfectly with LPG, and differently than other hydrocarbon fuels, consisting of oxygen as well, which makes the stoichiometric mixture less oxygen demanding. In the case of this fuel an improvement in engine volumetric and overall engine efficiency has been noticed compared with LPG. For the 11% DME share in the mixture an improvement of 2% in the efficiency has been noticed. During the tests, standard CNG–LPG feeding systems have been used, which underlines the utility value of the research. The stand-test results have been followed by combustion process simulation including exhaust forming and charge exchange.

NO-diagnostics in the combustion chamber of a gasoline direct-injection engine with spray-guided combustion process in a four-cylinder transparent engine; NO-Diagnostik im Brennraum eines direkteinspritzenden Ottomotors mit strahlgefuehrtem Brennverfahren an einem Vierzylinder-Transparentmotor

Energy Technology Data Exchange (ETDEWEB)

Suck, G.; Jakobs, J. [Volkswagen AG - Konzernforschung, Wolfsburg (Germany); Nicklitzsch, S. [IAV GmbH - Versuch Ottomotoren, Chemnitz (Germany); Bessler, W.G.; Hofmann, M.; Schulz, C. [PCI, Universitaet Heidelberg (Germany)

2004-07-01

For further reduction of fuel consumption in modern gasoline direct-injection engines, the Volkswagen Group Research is investigating the spray-guided combustion process. To benefit from fuel economy achieved by this combustion process in the sustained development of the Volkswagen FSI {sup registered} -technology, minimizing the engine-out NO{sub x}-emissions is necessary. In this proceeding, we report on the application of several measurement techniques, which include NO-LIF, in-cylinder gas sampling and fast CLD. The aim is the identification of major factors which effect NO-formation in a spray-guided combustion process. Double-injection during the compression stroke allows the generation of double-stratification of the air-fuel mixture cloud. A fuel-rich core with good ignition characteristics is surrounded by a fuel-lean gas mixture. These conditions show that NO-emissions can significantly be reduced while maintaining the good fuel economy. Spray-guided direct-injection allows the expansion of the operation-map area with stratified operation in comparison to recent serial production gasoline DI engines with wall-guided or air-guided combustion processes. It is, however, only possible to benefit from this advantage under realistic conditions of an operating automobile application when the engine-out NO{sub x}-flux is below a limit given by the storage capacity of the catalyst. NO{sub x} exhaust aftertreatment with storage catalysts requires regeneration cycles with fuel-air equivalent ratios {phi} > 1, which effectively increase fuel consumption. (orig.)

Thermogravimetric analysis of biowastes during combustion

International Nuclear Information System (INIS)

Otero, M.; Sanchez, M.E.; Gomez, X.; Moran, A.

2010-01-01

The combustion of sewage sludge (SS), animal manure (AM) and the organic fraction of municipal solid waste (OFMSW) was assessed and compared with that of a semianthracite coal (SC) and of a PET waste by thermogravimetric (TG) analysis. Differences were found in the TG curves obtained for the combustion of these materials accordingly to their respective proximate analysis. Non-isothermal thermogravimetric data were used to assess the kinetics of the combustion of these biowastes. The present paper reports on the application of the Vyazovkin model-free isoconversional method for the evaluation of the activation energy necessary for the combustion of these biowastes. The activation energy related to SS combustion (129.1 kJ/mol) was similar to that corresponding to AM (132.5 kJ/mol) while the OFMSW showed a higher value (159.3 kJ/mol). These values are quite higher than the one determined in the same way for the combustion of SC (49.2 kJ/mol) but lower than that for the combustion of a PET waste (165.6 kJ/mol).

Coal slurry combustion and technology. Volume 2

Energy Technology Data Exchange (ETDEWEB)

1983-01-01

Volume II contains papers presented at the following sessions of the Coal Slurry Combustion and Technology Symposium: (1) bench-scale testing; (2) pilot testing; (3) combustion; and (4) rheology and characterization. Thirty-three papers have been processed for inclusion in the Energy Data Base. (ATT)

Technology for emission control in internal combustion engines; Kakushu nainen kikan ni okeru hai gas joka gijutsu

Energy Technology Data Exchange (ETDEWEB)

Shioji, M. [Kyoto University, Kyoto (Japan)

1998-09-01

Described herein are emission control technology and exhaust gas cleaning measures for internal combustion engines. Gas turbines burn relatively high-quality fuels, such as natural gas, kerosene, diesel oil and gas oil, where the major concerns are to reduce NOx and dust emissions. The NOx abatement techniques fall into two general categories; wet processes which inject water or steam, and dry processes which depend on improved combustion. Power generation and cogeneration which burn natural gas adopt lean, premixed combustion and two-stage combustion as the major approaches. Low-speed, large-size diesel engines, which realize very high thermal efficiency, discharge high concentrations of NOx. Delayed fuel injection timing is the most easy NOx abatement technique to meet the related regulations, but is accompanied by decreased fuel economy. Use of water-emulsified fuel, water layer injection and multi-port injection can reduce NOx emissions without decreasing fuel economy, depending on optimization methods adopted. Automobile gasoline engines are required to further clean exhaust gases by catalystic systems. 9 refs., 10 figs., 6 tabs.

Analysis of cumulative energy consumption in an oxy-fuel combustion power plant integrated with a CO2 processing unit

International Nuclear Information System (INIS)

Ziębik, Andrzej; Gładysz, Paweł

2014-01-01

Highlights: • Oxy-fuel combustion is promising CCS technology. • Sum of direct and indirect energy consumption ought to be consider. • This sum is expressed by cumulative energy consumption. • Input–output analysis is adequate method of CCS modeling. - Abstract: A balance of direct energy consumption is not a sufficient tool for an energy analysis of an oxy-fuel combustion power plant because of the indirect consumption of energy in preceding processes in the energy-technological set of interconnections. The sum of direct and indirect consumption expresses cumulative energy consumption. Based on the “input–output” model of direct energy consumption the mathematical model of cumulative energy consumption concerning an integrated oxy-fuel combustion power plant has been developed. Three groups of energy carriers or materials are to be distinguished, viz. main products, by-products and external supplies not supplementing the main production. The mathematical model of the balance of cumulative energy consumption based on the assumption that the indices of cumulative energy consumption of external supplies (mainly fuels and raw materials) are known a’priori. It results from weak connections between domestic economy and an integrated oxy-fuel combustion power plant. The paper presents both examples of the balances of direct and cumulative energy consumption. The results of calculations of indices of cumulative energy consumption concerning main products are presented. A comparison of direct and cumulative energy effects between three variants has been worked out. Calculations of the indices of cumulative energy consumption were also subjected to sensitive analysis. The influence of the indices of cumulative energy consumption of external supplies (input data), as well as the assumption concerning the utilization of solid by-products of the combustion process have been investigated

Numerical investigation of the effect of injection strategy on mixture formation and combustion process in a port injection natural gas rotary engine

International Nuclear Information System (INIS)

Fan, Baowei; Pan, Jianfeng; Yang, Wenming; Liu, Yangxian; Bani, Stephen; Chen, Wei

2017-01-01

Highlights: • For injection timing, the fuel movement is controlled by the intensity of the vortex I. • For injection duration, the fuel movement is controlled by the value of jet flux. • The ideal fuel distribution at ignition timing for high combustion rate is studied. • The optimal injection strategy had an increase in the peak pressure and NO emissions. - Abstract: This work aimed to numerically study the influence of injection strategy on mixture formation and combustion process in a port injection natural gas rotary engine. On the base of a 3D dynamic simulation model which was established in our previous work, some critical information was obtained, which was difficult to obtain through experiment, in terms of the flow field, the fuel distribution, the temperature field and the concentration fields of some intermediates. Simulation results showed that for mixture formation, the movements of fuel in injection stage were mainly controlled by the intensity of the vortex I for injection timing, and the value of jet flux for injection duration respectively. With retarded injection timing, the decreasing intensity of the vortex I resulted in less fuel moving toward the back of the combustion chamber. With the extension in injection duration, the decreasing value of jet flux resulted in more fuel staying at the back of the combustion chamber. For combustion process, the overall combustion rate for injection strategy which had an injection timing of 390 °CA (BTDC) and injection duration of 51.5 °CA (case ID4) was the fastest. This was mainly due to the fact that the accumulation area of fuel was at the middle and front of the combustion chamber. Meanwhile, fuel concentration near the leading and trailing spark plugs was conducive for the flame kernel formation. Compared with the injection strategy which had an injection timing of 450 °CA (BTDC) and an injection duration of 55 °CA (case IT1), the improved combustion rate of case ID4 had a 23% increase in

Combustion chemistry. Activities in the CHEC research programme

Energy Technology Data Exchange (ETDEWEB)

Dam-Johansen, K; Johnsson, J E; Glarborg, P; Frandsen, F; Jensen, A; Oestberg, M [Technical Univ. of Denmark, Dept. of Chemical Engineering, Lyngby (Denmark)

1996-12-01

The combustion chemistry in the oxidation of fossil fuels and biofuels determines together with mixing and heat transfer the required size of a furnace, the emission of gaseous pollutants, and the formation of ash and deposits on surfaces. This paper describes technologies for solid fuels combustion and gives a summary of the fuels, the pollutant chemistry and the inorganic chemistry in combustion processes. Emphasis is put on the work carried out in the CHEC (Combustion and Harmful Emission Control Research Programme). (au) 173 refs.

Numerical investigation of biogas flameless combustion

International Nuclear Information System (INIS)

Hosseini, Seyed Ehsan; Bagheri, Ghobad; Wahid, Mazlan Abdul

2014-01-01

Highlights: • Fuel consumption decreases from 3.24 g/s in biogas conventional combustion to 1.07 g/s in flameless mode. • The differences between reactants and products temperature intensifies irreversibility in traditional combustion. • The temperature inside the chamber is uniform in biogas flameless mode and exergy loss decreases in this technique. • Low O 2 concentration in the flameless mode confirms a complete and quick combustion process in flameless regime. - Abstract: The purpose of this investigation is to analyze combustion characteristics of biogas flameless mode based on clean technology development strategies. A three dimensional (3D) computational fluid dynamic (CFD) study has been performed to illustrate various priorities of biogas flameless combustion compared to the conventional mode. The effects of preheated temperature and wall temperature, reaction zone and pollutant formation are observed and the impacts of combustion and turbulence models on numerical results are discussed. Although preheated conventional combustion could be effective in terms of fuel consumption reduction, NO x formation increases. It has been found that biogas is not eligible to be applied in furnace heat up due to its low calorific value (LCV) and it is necessary to utilize a high calorific value fuel to preheat the furnace. The required enthalpy for biogas auto-ignition temperature is supplied by enthalpy of preheated oxidizer. In biogas flameless combustion, the mean temperature of the furnace is lower than traditional combustion throughout the chamber. Compared to the biogas flameless combustion with uniform temperature, very high and fluctuated temperatures are recorded in conventional combustion. Since high entropy generation intensifies irreversibility, exergy loss is higher in biogas conventional combustion compared to the biogas flameless regime. Entropy generation minimization in flameless mode is attributed to the uniform temperature inside the chamber

Stratified charge rotary engine combustion studies

Science.gov (United States)

Shock, H.; Hamady, F.; Somerton, C.; Stuecken, T.; Chouinard, E.; Rachal, T.; Kosterman, J.; Lambeth, M.; Olbrich, C.

1989-07-01

Analytical and experimental studies of the combustion process in a stratified charge rotary engine (SCRE) continue to be the subject of active research in recent years. Specifically to meet the demand for more sophisticated products, a detailed understanding of the engine system of interest is warranted. With this in mind the objective of this work is to develop an understanding of the controlling factors that affect the SCRE combustion process so that an efficient power dense rotary engine can be designed. The influence of the induction-exhaust systems and the rotor geometry are believed to have a significant effect on combustion chamber flow characteristics. In this report, emphasis is centered on Laser Doppler Velocimetry (LDV) measurements and on qualitative flow visualizations in the combustion chamber of the motored rotary engine assembly. This will provide a basic understanding of the flow process in the RCE and serve as a data base for verification of numerical simulations. Understanding fuel injection provisions is also important to the successful operation of the stratified charge rotary engine. Toward this end, flow visualizations depicting the development of high speed, high pressure fuel jets are described. Friction is an important consideration in an engine from the standpoint of lost work, durability and reliability. MSU Engine Research Laboratory efforts in accessing the frictional losses associated with the rotary engine are described. This includes work which describes losses in bearing, seal and auxillary components. Finally, a computer controlled mapping system under development is described. This system can be used to map shapes such as combustion chamber, intake manifolds or turbine blades accurately.

HTR combustion head end comparison of the shaft furnace and fluidized bed processes

Energy Technology Data Exchange (ETDEWEB)

Boehnert, R.; Kaiser, G.; Pirk, H.; Tillessen, U.

1975-01-15

Two methods are described for the combustion of the graphite of HTR fuel elements, a sufficient description of the principles being given to permit an understanding of the processes. The present state of the technology of the two processes is then compared on the basis of the results obtained at Gulf General Atomic. Finally, the possibilities of further development are examined using a pilot plant designed to deliver a reactor power of 7000 MWe as the basis. The present report is a collection of facts. It contains neither an evaluation nor a recommendation. A summarized comparison of the state of the technology and the possibilities of development is given in tabular form.

Measurement of O2 in the Combustion Chamber of Apulverized Coal Boiler

Directory of Open Access Journals (Sweden)

Břetislav Janeba

2012-01-01

Full Text Available Operational measurements of the O2 concentration in the combustion chamber of a pulverized coal boiler are not yet common practice. Operators are generally satisfied with measuring the O2 concentration in the second pass of the boiler, usually behind the economizer, where a flue gas sample is extracted for analysis in a classical analyzer. A disadvantage of this approach is that there is a very weak relation between the measured value and the condition in specific locations in the fireplace, e.g. the function of the individual burners and the combustion process as a whole. A new extractionline was developed for measuring the O2 concentration in the combustion chamber. A planar lambda probe is used in this approach. The extraction line is designed to get outputs that can be used directly for diagnosis or management of the combustion in the boiler.

Obtaining zeolites from slags and ashes from a waste combustion plant in an autoclave process

Directory of Open Access Journals (Sweden)

Grela Agnieszka

2017-01-01

Full Text Available Waste combustion is associated with the generation of post-processing solid products – waste such as slag and ash. One of the promising technologies in waste management and processing is the synthesis of zeolites and other materials exhibiting sorption properties. The aim of this study was to characterise and assess the physicochemical properties of the waste and the products synthesised from it. This paper presents the possibility of synthesis zeolites from the slag and ash from two waste combustion plants. The investigated waste is classified as hazardous waste and denoted by the EWC code 190111*. The paper presents the results of physicochemical studies of these materials. As a result of synthesis in an autoclave at 140°C with the use of 2 M NaOH, and other compounds, such zeolite forms as chabazite and sodalite were obtained. Textural studies and ion-exchange capacity investigations carried out allowed characterisation of the sorption properties of the materials. It was found that the materials obtained are characterised by the BET specific surface areas of 25.45 m2/g and 16.79 m2/g.

Co-combustion performance of coal with rice husks and bamboo

Energy Technology Data Exchange (ETDEWEB)

Kwong, P.C.W.; Chao, C.Y.H.; Wang, J.H.; Cheung, C.W.; Kendall, G. [Hong Kong University of Science & Technology, Kowloon (China). Dept. of Mechanical Engineering

2007-11-15

Biomass has been regarded as an important form of renewable energy due to the reduction of greenhouse gas emission such as carbon dioxide. An experimental study of co-combustion of coal and biomass was performed in a laboratory-scale combustion facility. Rice husks and bamboo were the selected biomass fuels in this study due to their abundance in the Asia-Pacific region. Experimental parameters including the biomass blending ratio in the fuel mixture, relative moisture content and biomass grinding size were investigated. Both energy release data and pollutant emission information were obtained. Due to the decrease in the heating value from adding biomass in the fuel mixture, the combustion temperature and energy output from the co-firing process were reduced compared with coal combustion. On the other hand, gaseous pollutant emissions including carbon monoxide (CO), carbon dioxide (CO{sub 2}), nitrogen oxides (NOx) and sulfur dioxide (SO{sub 2}) were reduced and minimum energy-based emission factors were found in the range of 10-30% biomass blending ratio. With an increase in the moisture content in the biomass, decreases in combustion temperature, SO{sub 2}, NOx and CO{sub 2} emissions were observed, while an increase in CO emissions was found. It has also been observed that chemical kinetics may play an important role compared to mass diffusion in the co-firing process and the change in biomass grinding size does not have much effect on the fuel burning rate and pollutant emissions tinder the current experimental conditions.

Fuel and Additive Characterization for HCCI Combustion

International Nuclear Information System (INIS)

Aceves, S M; Flowers, D; Martinez-Frias, J; Espinosa-Loza, F; Pitz, W J; Dibble, R

2003-01-01

This paper shows a numerical evaluation of fuels and additives for HCCl combustion. First, a long list of candidate HCCl fuels is selected. For all the fuels in the list, operating conditions (compression ratio, equivalence ratio and intake temperature) are determined that result in optimum performance under typical operation for a heavy-duty engine. Fuels are also characterized by presenting Log(p)-Log(T) maps for multiple fuels under HCCl conditions. Log(p)-Log(T) maps illustrate important processes during HCCl engine operation, including compression, low temperature heat release and ignition. Log(p)-Log(T) diagrams can be used for visualizing these processes and can be used as a tool for detailed analysis of HCCl combustion. The paper also includes a ranking of many potential additives. Experiments and analyses have indicated that small amounts (a few parts per million) of secondary fuels (additives) may considerably affect HCCl combustion and may play a significant role in controlling HCCl combustion. Additives are ranked according to their capability to advance HCCl ignition. The best additives are listed and an explanation of their effect on HCCl combustion is included

Testing fireproof materials in a combustion chamber

Directory of Open Access Journals (Sweden)

Kulhavy Petr

2017-01-01

Full Text Available This article deals with a prototype concept, real experiment and numerical simulation of a combustion chamber, designed for testing fire resistance some new insulating composite materials. This concept of a device used for testing various materials, providing possibility of monitoring temperatures during controlled gas combustion. As a fuel for the combustion process propane butane mixture has been used and also several kinds of burners with various conditions of inlet air (forced, free and fuel flows were tested. The tested samples were layered sandwich materials based on various materials or foams, used as fillers in fire shutters. The temperature distribution was measured by using thermocouples. A simulation of whole concept of experimental chamber has been carried out as the non-premixed combustion process in the commercial final volume sw Pyrosim. The result was to design chamber with a construction suitable, according to the international standards, achieve the required values (temperature in time. Model of the combustion based on a stoichiometric defined mixture of gas and the tested layered samples showed good conformity with experimental results – i.e. thermal distribution inside and heat release rate that has gone through the sample.

OxyFuel combustion of Coal and Biomass

DEFF Research Database (Denmark)

Toftegaard, Maja Bøg

The power and heat producing sector is facing a continuously increasing demand to reduce its emissions of CO2. Oxyfuel combustion combined with CO2 storage is suggested as one of the possible, promising technologies which will enable the continuous use of the existing fleet of suspension-fired po......The power and heat producing sector is facing a continuously increasing demand to reduce its emissions of CO2. Oxyfuel combustion combined with CO2 storage is suggested as one of the possible, promising technologies which will enable the continuous use of the existing fleet of suspension......-fired power plants burning coal or other fuels during the period of transition to renewable energy sources. The oxyfuel combustion process introduces several changes to the power plant configuration. Most important, the main part of the flue gas is recirculated to the boiler and mixed with pure oxygen....... The oxidant thus contains little or no nitrogen and a near-pure CO2 stream can be produced by cooling the flue gas to remove water. The change to the oxidant composition compared to combustion in air will induce significant changes to the combustion process. This Ph.D. thesis presents experimental...

Tunable diode laser spectroscopy as a technique for combustion diagnostics

International Nuclear Information System (INIS)

Bolshov, M.A.; Kuritsyn, Yu.A.; Romanovskii, Yu.V.

2015-01-01

Tunable diode laser absorption spectroscopy (TDLAS) has become a proven method of rapid gas diagnostics. In the present review an overview of the state of the art of TDL-based sensors and their applications for measurements of temperature, pressure, and species concentrations of gas components in harsh environments is given. In particular, the contemporary tunable diode laser systems, various methods of absorption detection (direct absorption measurements, wavelength modulation based phase sensitive detection), and relevant algorithms for data processing that improve accuracy and accelerate the diagnostics cycle are discussed in detail. The paper demonstrates how the recent developments of these methods and algorithms made it possible to extend the functionality of TDLAS in the tomographic imaging of combustion processes. Some prominent examples of applications of TDL-based sensors in a wide range of practical combustion aggregates, including scramjet engines and facilities, internal combustion engines, pulse detonation combustors, and coal gasifiers, are given in the final part of the review. - Highlights: • Overview of modern TDL-based sensors for combustion • TDL systems, methods of absorption detection and algorithms of data processing • Prominent examples of TDLAS diagnostics of the combustion facilities • Extension of the TDLAS on the tomographic imaging of combustion processes

New Metamaterials with Combined Subnano - and Mesoscale Topology for High-efficiency Catalytic Combustion Chambers of Innovative Gas Turbine Engines

Science.gov (United States)

Knysh, Yu A.; Xanthopoulou, G. G.

2018-01-01

The object of the study is a catalytic combustion chamber that provides a highly efficient combustion process through the use of effects: heat recovery from combustion, microvortex heat transfer, catalytic reaction and acoustic resonance. High efficiency is provided by a complex of related technologies: technologies for combustion products heat transfer (recuperation) to initial mixture, catalytic processes technology, technology for calculating effective combustion processes based on microvortex matrices, technology for designing metamaterials structures and technology for obtaining the required topology product by laser fusion of metal powder compositions. The mesoscale level structure provides combustion process with the use of a microvortex effect with a high intensity of heat and mass transfer. High surface area (extremely high area-to-volume ratio) created due to nanoscale periodic structure and ensures catalytic reactions efficiency. Produced metamaterial is the first multiscale product of new concept which due to combination of different scale level periodic topologies provides qualitatively new set of product properties. This research is aimed at solving simultaneously two global problems of the present: ensure environmental safety of transport systems and power industry, as well as the economy and rational use of energy resources, providing humanity with energy now and in the foreseeable future.

Catalytic Combustion of Gasified Waste

Energy Technology Data Exchange (ETDEWEB)

Kusar, Henrik

2003-09-01

This thesis concerns catalytic combustion for gas turbine application using a low heating-value (LHV) gas, derived from gasified waste. The main research in catalytic combustion focuses on methane as fuel, but an increasing interest is directed towards catalytic combustion of LHV fuels. This thesis shows that it is possible to catalytically combust a LHV gas and to oxidize fuel-bound nitrogen (NH{sub 3}) directly into N{sub 2} without forming NO{sub x} The first part of the thesis gives a background to the system. It defines waste, shortly describes gasification and more thoroughly catalytic combustion. The second part of the present thesis, paper I, concerns the development and testing of potential catalysts for catalytic combustion of LHV gases. The objective of this work was to investigate the possibility to use a stable metal oxide instead of noble metals as ignition catalyst and at the same time reduce the formation of NO{sub x} In paper II pilot-scale tests were carried out to prove the potential of catalytic combustion using real gasified waste and to compare with the results obtained in laboratory scale using a synthetic gas simulating gasified waste. In paper III, selective catalytic oxidation for decreasing the NO{sub x} formation from fuel-bound nitrogen was examined using two different approaches: fuel-lean and fuel-rich conditions. Finally, the last part of the thesis deals with deactivation of catalysts. The various deactivation processes which may affect high-temperature catalytic combustion are reviewed in paper IV. In paper V the poisoning effect of low amounts of sulfur was studied; various metal oxides as well as supported palladium and platinum catalysts were used as catalysts for combustion of a synthetic gas. In conclusion, with the results obtained in this thesis it would be possible to compose a working catalytic system for gas turbine application using a LHV gas.

Sludge combustion in fluidized bed reactors at laboratory scale

International Nuclear Information System (INIS)

Chirone, R.; Cammarota, A.

2001-01-01

The combustion of a dried sewage sludge in laboratory scale fluidized bed has been studied in Naples by the Istituto di ricerche sulla combustione (Irc) in the framework of a National project named Thermal Process with Energy Recovery to be used in laboratory and pre-pilot scale apparatus. The attention has been focused on emissions of unreacted carbon as elutriated fines, on the emissions of pollutant gases and on the assessment of the inventory of fly- and bottom ashes. The combustion behaviour of sewage sludge has been compared with those of a market available Tyre Derived Fuel (TDF) and a biomass from Mediterranean area (Robinia Pseudoacacia) and with that of a South African bituminous coal. Stationary combustion tests were carried out at 850 0 C by feeding particles in the size range 0-1 mm into a bed of silica sand without any sorbent addition. The fluidized bed combustor has been operated, at a superficial gas velocity of 0.4 m/s and different excesses of air ranging between 14 and 98%. Relatively high combustion efficiency, larger than 98.9% has been obtained in experiments carried out with sewage sludge and excess of air larger than 20%. These values, are comparable with those obtained in previously experimental activity carried out under similar operative conditions with a South Africa Bituminous coal (97-98%). It is larger than those obtained by using a Tyre Derived Fuel (89-90%) and the Robinia Pseudoacacia Biomass (93-93%). The relative importance of carbon fines elutriation, CO emissions and volatile bypassing the bed in determining the loss of combustion efficiency has been evaluated for the different fuels tested [it

Energy from Waste--clean, efficient, renewable: transitions in combustion efficiency and NOx control.

Science.gov (United States)

Waldner, M H; Halter, R; Sigg, A; Brosch, B; Gehrmann, H J; Keunecke, M

2013-02-01

Traditionally EfW (Energy from Waste) plants apply a reciprocating grate to combust waste fuel. An integrated steam generator recovers the heat of combustion and converts it to steam for use in a steam turbine/generator set. This is followed by an array of flue gas cleaning technologies to meet regulatory limitations. Modern combustion applies a two-step method using primary air to fuel the combustion process on the grate. This generates a complex mixture of pyrolysis gases, combustion gases and unused combustion air. The post-combustion step in the first pass of the boiler above the grate is intended to "clean up" this mixture by oxidizing unburned gases with secondary air. This paper describes modifications to the combustion process to minimize exhaust gas volumes and the generation of noxious gases and thus improving the overall thermal efficiency of the EfW plant. The resulting process can be coupled with an innovative SNCR (Selective Non-Catalytic Reduction) technology to form a clean and efficient solid waste combustion system. Measurements immediately above the grate show that gas compositions along the grate vary from 10% CO, 5% H(2) and 0% O(2) to essentially unused "pure" air, in good agreement with results from a mathematical model. Introducing these diverse gas compositions to the post combustion process will overwhelm its ability to process all these gas fractions in an optimal manner. Inserting an intermediate step aimed at homogenizing the mixture above the grate has shown to significantly improve the quality of combustion, allowing for optimized process parameters. These measures also resulted in reduced formation of NO(x) (nitrogenous oxides) due to a lower oxygen level at which the combustion process was run (2.6 vol% O(2,)(wet) instead of 6.0 vol% O(2,)(wet)). This reduction establishes optimal conditions for the DyNOR™ (Dynamic NO(x) Reduction) NO(x) reduction process. This innovative SNCR technology is adapted to situations typically

Laser-assisted homogeneous charge ignition in a constant volume combustion chamber

Science.gov (United States)

Srivastava, Dhananjay Kumar; Weinrotter, Martin; Kofler, Henrich; Agarwal, Avinash Kumar; Wintner, Ernst

2009-06-01

Homogeneous charge compression ignition (HCCI) is a very promising future combustion concept for internal combustion engines. There are several technical difficulties associated with this concept, and precisely controlling the start of auto-ignition is the most prominent of them. In this paper, a novel concept to control the start of auto-ignition is presented. The concept is based on the fact that most HCCI engines are operated with high exhaust gas recirculation (EGR) rates in order to slow-down the fast combustion processes. Recirculated exhaust gas contains combustion products including moisture, which has a relative peak of the absorption coefficient around 3 μm. These water molecules absorb the incident erbium laser radiations ( λ=2.79 μm) and get heated up to expedite ignition. In the present experimental work, auto-ignition conditions are locally attained in an experimental constant volume combustion chamber under simulated EGR conditions. Taking advantage of this feature, the time when the mixture is thought to "auto-ignite" could be adjusted/controlled by the laser pulse width optimisation, followed by its resonant absorption by water molecules present in recirculated exhaust gas.

Numerical studies of spray combustion processes of palm oil biodiesel and diesel fuels using reduced chemical kinetic mechanisms

KAUST Repository

Kuti, Olawole; Sarathy, Mani; Nishida, Keiya; Roberts, William L.

2014-01-01

Spray combustion processes of palm oil biodiesel (PO) and conventional diesel fuels were simulated using the CONVERGE CFD code. Thermochemical and reaction kinetic data (115 species and 460 reactions) by Luo et al. (2012) and Lu et al. (2009) (68

Boiler for combustion fuel in a fluidized bed

Directory of Open Access Journals (Sweden)

Laković Mirjana S.

2015-01-01

Full Text Available Fuel combustion in fluidized bed combustion is a process that is current and which every day gives more attention and there are many studies that have been closely associated with this technology. This combustion technology is widespread and constantly improving the range of benefits it provides primarily due to reduced emissions. This paper presents the boilers for combustion in a fluidized bed, whit characteristics and advantages. Also is shown the development of this type of boilers in Republic of Serbia. In this paper is explained the concept of fluidized bed combustion. Boilers for this type of combustion can be improved and thereby increase their efficiency level. More detailed characteristics are given for boilers with bubbling and circulating fluidized bed as well as their mutual comparison.

Towards Control-Oriented Modeling of Natural Gas-Diesel RCCI Combustion

NARCIS (Netherlands)

Bekdemir, C.; Baert, R.; Willems, F.; Somers, B.

2015-01-01

For natural gas (NG)-diesel RCCI, a multi-zonal, detailed chemistry modeling approach is presented. This dual fuel combustion process requires further understanding of the ignition and combustion processes to maximize thermal efficiency and minimize (partially) unburned fuel emissions. The

Towards control-oriented modeling of natural gas-diesel RCCI combustion

NARCIS (Netherlands)

Bekdemir, C.; Baert, R.S.G.; Willems, F.P.T.; Somers, L.M.T.

2015-01-01

For natural gas (NG)-diesel RCCI, a multi-zonal, detailed chemistry modeling approach is presented. This dual fuel combustion process requires further understanding of the ignition and combustion processes to maximize thermal efficiency and minimize (partially) unburned fuel emissions. The

Annual Report: Advanced Combustion (30 September 2012)

Energy Technology Data Exchange (ETDEWEB)

Hawk, Jeffrey [NETL; Richards, George

2012-09-30

The Advanced Combustion Project addresses fundamental issues of fire-side and steam-side corrosion and materials performance in oxy-fuel combustion environments and provides an integrated approach into understanding the environmental and mechanical behavior such that environmental degradation can be ameliorated and long-term microstructural stability, and thus, mechanical performance can lead to longer lasting components and extended power plant life. The technical tasks of this effort are Oxy-combustion Environment Characterization, Alloy Modeling and Life Prediction, and Alloy Manufacturing and Process Development.

Combustible structural composites and methods of forming combustible structural composites

Science.gov (United States)

Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

2013-04-02

Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

Combustion of pulverized fuel under oxycoal conditions at low oxygen concentrations

Energy Technology Data Exchange (ETDEWEB)

Toporov D.; Foerster M.; Kneer R. [RWTH Aachen University, Aachen (Germany). Institute of Heat and Mass Transfer

2007-07-01

Oxycoal combustion followed by post-combustion CO{sub 2} sequestration has gained justified interest as an option for significant and relatively quick reduction of emissions from fossil fuel power generation, while taking advantage of the existing power plant infrastructure. Burning pulverised coal in a mixture of CO{sub 2}/O{sub 2} instead of air, however, will lead to modified distributions of temperature, species, and radiation fluxes inside the combustion chamber causing a retroaction on the homogeneous and heterogeneous reactions. Utilizing a burner design, which was optimised for coal combustion in air, for oxycoal combustion will lead to flame instability and poor burnout. Stabilisation of the combustion process can be obtained by: i) an increased oxygen concentration (more than 21% vol.) in the oxidiser mixture, thus achieving similar reaction rates and temperature levels to a pulverised fuel-air flame without significant changes to the flame aerodynamics. ii) modifications to the burner aerodynamics, as presented here. The results in this study are obtained in the frame of OXYCOAL-AC, the research project, having the aim to burn a pulverised coal in a CO{sub 2}/O{sub 2}-atmosphere with oxygen, produced from high-temperature ceramic membrane thus leading to higher efficiency of the whole oxycoal process. Numerical and experimental investigations of a stable oxycoal flame, obtained with {le} 21% oxygen concentration in the burning mixture at the RWTH test facility are reported. Two different burner designs are considered, conclusions concerning the achievement of a stable oxycoal flame at O{sub 2} volume concentrations equal and less to the one of oxygen in air are derived. 8 refs., 7 figs., 1 tab.

Study of mechanically activated coal combustion

Directory of Open Access Journals (Sweden)

Burdukov Anatolij P.

2009-01-01

Full Text Available Combustion and air gasification of mechanically activated micro-ground coals in the flux have been studied. Influence of mechanically activated methods at coals grinding on their chemical activeness at combustion and gasification has been determined. Intense mechanical activation of coals increases their chemical activeness that enables development of new highly boosted processing methods for coals with various levels of metamorphism.

Emissions from carpet combustion in a pilot-scale rotary kiln: comparison with coal and particle-board combustion

Energy Technology Data Exchange (ETDEWEB)

Stephanie Lucero Konopa; James A. Mulholland; Matthew J. Realff; Paul M. Lemieux [Georgia Institute of Technology, Atlanta, GA (United States). School of Civil and Environmental Engineering

2008-08-15

The use of post-consumer carpet as a potential fuel substitute in cement kilns and other high-temperature processes is being considered to address the problem of huge volumes of carpet waste and the opportunity of waste-to-energy recovery. Carpet represents a high volume waste stream, provides high energy value, and contains other recoverable materials for the production of cement. This research studied the emission characteristics of burning 0.46-kg charges of chopped nylon carpet squares, pulverized coal, and particle-board pellets in a pilot-scale natural gas-fired rotary kiln. Carpet was tested with different amounts of water added. Emissions of oxygen, carbon dioxide, nitric oxide (NO), sulfur dioxide (SO{sub 2}), carbon monoxide (CO), and total hydrocarbons and temperatures were continuously monitored. It was found that carpet burned faster and more completely than coal and particle board, with a rapid volatile release that resulted in large and variable transient emission peaks. NO emissions from carpet combustion ranged from 0.06 to 0.15 g/MJ and were inversely related to CO emissions. Carpet combustion yielded higher NO emissions than coal and particleboard combustion, consistent with its higher nitrogen content. S{sub 2} emissions were highest for coal combustion, consistent with its higher sulfur content than carpet or particle board. Adding water to carpet slowed its burn time and reduced variability in the emission transients, reducing the CO peak but increasing NO emissions. Results of this study indicate that carpet waste can be used as an effective alternative fuel, with the caveats that it might be necessary to wet carpet or chop it finely to avoid excessive transient puff emissions due to its high volatility compared with other solid fuels, and that controlled mixing of combustion air might be used to control NO emissions from nylon carpet. 13 refs., 5 figs., 1 tab.

Application of Pareto-efficient combustion modeling framework to large eddy simulations of turbulent reacting flows

Science.gov (United States)

Wu, Hao; Ihme, Matthias

2017-11-01

The modeling of turbulent combustion requires the consideration of different physico-chemical processes, involving a vast range of time and length scales as well as a large number of scalar quantities. To reduce the computational complexity, various combustion models are developed. Many of them can be abstracted using a lower-dimensional manifold representation. A key issue in using such lower-dimensional combustion models is the assessment as to whether a particular combustion model is adequate in representing a certain flame configuration. The Pareto-efficient combustion (PEC) modeling framework was developed to perform dynamic combustion model adaptation based on various existing manifold models. In this work, the PEC model is applied to a turbulent flame simulation, in which a computationally efficient flamelet-based combustion model is used in together with a high-fidelity finite-rate chemistry model. The combination of these two models achieves high accuracy in predicting pollutant species at a relatively low computational cost. The relevant numerical methods and parallelization techniques are also discussed in this work.

Investigations on Bi25FeO40 powders synthesized by hydrothermal and combustion-like processes

International Nuclear Information System (INIS)

Köferstein, Roberto; Buttlar, Toni; Ebbinghaus, Stefan G.

2014-01-01

The syntheses of phase-pure and stoichiometric iron sillenite (Bi 25 FeO 40 ) powders by a hydrothermal (at ambient pressure) and a combustion-like process are described. Phase-pure samples were obtained in the hydrothermal reaction at 100 °C (1), whereas the combustion-like process leads to pure Bi 25 FeO 40 after calcination at 750 °C for 2 h (2a). The activation energy of the crystallite growth process of hydrothermally synthesized Bi 25 FeO 40 was calculated as 48(9) kJ mol −1 . The peritectic point was determined as 797(1) °C. The optical band gaps of the samples are between 2.70(7) eV and 2.81(6) eV. Temperature and field-depending magnetization measurements (5−300 K) show a paramagnetic behaviour with a Curie constant of 55.66×10 −6 m 3 K mol −1 for sample 1 and C=57.82×10 −6 m 3 K mol −1 for sample 2a resulting in magnetic moments of µ mag =5.95(8) µ B mol −1 and µ mag =6.07(4) µ B mol −1 . The influence of amorphous iron-oxide as a result of non-stoichiometric Bi/Fe ratios in hydrothermal syntheses on the magnetic behaviour was additionally investigated. - Graphical abstract: Bi 25 FeO 40 powders were prepared by a hydrothermal method and a combustion process. The optical band gaps and the peritectic point were determined. The magnetic behaviour was investigated depending on the synthesis and the initial Bi/Fe ratios. The influence of amorphous iron-oxide on the magnetic properties was examined. - Highlights: • Two simple syntheses routes for stoichiometric Bi 25 FeO 40 powders using starch as polymerization agent. • Monitoring the phase evolution and crystallite growth kinetics during the syntheses. • Determination of the optical band gap and melting point. • Investigations of the magnetic behaviour of Bi 25 FeO 40 powders. • Influence of amorphous iron oxide and a non-stoichiometric Bi/Fe ratio on the magnetic behaviour

Carbon Shale Combustion in the Fluidized Bed Reactor

Directory of Open Access Journals (Sweden)

Olek Małgorzata

2014-06-01

Full Text Available The purpose of this article is to present the possibilities of coal shale combustion in furnaces with bubbling fluidized bed. Coal shale can be autothermally combusted in the fluidized bed, despite the low calorie value and high ash content of fuel. Established concentrations of CO (500 ppm and VOC (30 mg/m3 have indicated a high conversion degree of combustible material during combustion process. Average concentrations of SO2 and NOx in the flue gas were higher than this received from the combustion of high quality hard coal, 600 ppm and 500 ppm, respectively. Optional reduction of SO2 and NOx emission may require the installation of flue gas desulphurization and de-NOx systems.

Influence of process parameters on coal combustion performance. Review, experiments and engineering modeling

Energy Technology Data Exchange (ETDEWEB)

Lans, R.P. van der

1997-04-01

The objective of this study is to improve the understanding of nitrogen oxide formation and carbon burnout during the combustion of pulverized coal, and to contribute to addressing the potential of chemical engineering models for the prediction of furnace temperatures, NO emissions and the amount of carbon in ash. To this purpose, the effect of coal quality on NO and burnout has been investigated experimentally, a radiation heat balance has been developed based on a simple chemical engineering methodology, and a mixing study has been conducted in order to describe the near burner macro mixing in terms of a reactor configuration. The influence of coal type and process conditions on NO formation and carbon burnout has been investigated experimentally in a 400 MW{sub e} corner fired boiler with over fire air, a 350 MW{sub e} opposed fired boiler, and in a 160 kW{sub t} pilot scale test rig. Three different coals were fired in each of the furnaces as part of the activities in group 3 of the European Union JOULE 2 Extension project `Atmospheric Pressure Combustion of Pulverized Coal and Coal Based Blends for Power Generation`. On the pilot scale test both single stage and air staged tests were performed. A simple, one-dimensional combustion and radiation heat transfer model has been developed for the furnace of full scale boilers. The model has been applied to the two boilers mentioned above, and is validated against measured temperatures and carbon in ash concentrations. A mixing study has been performed in order to initiate an investigation of the potential of chemical engineering models to predict NO from pulverized fuel burners. (EG) 11 refs.

Space Station Freedom combustion research

Science.gov (United States)

Faeth, G. M.

1992-01-01

Extended operations in microgravity, on board spacecraft like Space Station Freedom, provide both unusual opportunities and unusual challenges for combustion science. On the one hand, eliminating the intrusion of buoyancy provides a valuable new perspective for fundamental studies of combustion phenomena. On the other hand, however, the absence of buoyancy creates new hazards of fires and explosions that must be understood to assure safe manned space activities. These considerations - and the relevance of combustion science to problems of pollutants, energy utilization, waste incineration, power and propulsion systems, and fire and explosion hazards, among others - provide strong motivation for microgravity combustion research. The intrusion of buoyancy is a greater impediment to fundamental combustion studies than to most other areas of science. Combustion intrinsically heats gases with the resulting buoyant motion at normal gravity either preventing or vastly complicating measurements. Perversely, this limitation is most evident for fundamental laboratory experiments; few practical combustion phenomena are significantly affected by buoyancy. Thus, we have never observed the most fundamental combustion phenomena - laminar premixed and diffusion flames, heterogeneous flames of particles and surfaces, low-speed turbulent flames, etc. - without substantial buoyant disturbances. This precludes rational merging of theory, where buoyancy is of little interest, and experiments, that always are contaminated by buoyancy, which is the traditional path for developing most areas of science. The current microgravity combustion program seeks to rectify this deficiency using both ground-based and space-based facilities, with experiments involving space-based facilities including: laminar premixed flames, soot processes in laminar jet diffusion flames, structure of laminar and turbulent jet diffusion flames, solid surface combustion, one-dimensional smoldering, ignition and flame

Sodium nitrate combustion limit tests

International Nuclear Information System (INIS)

Beitel, G.A.

1976-04-01

Sodium nitrate is a powerful solid oxidant. Energetically, it is capable of exothermically oxidizing almost any organic material. Rate-controlling variables such as temperature, concentration of oxidant, concentration of fuel, thermal conductivity, moisture content, size, and pressure severely limit the possibility of a self-supported exothermic reaction (combustion). The tests reported in this document were conducted on one-gram samples at atmospheric pressure. Below 380 0 C, NaNO 3 was stable and did not support combustion. At moisture concentrations above 22 wt percent, exothermic reactions did not propagate in even the most energetic and reactive compositions. Fresh resin and paraffin were too volatile to enable a NaNO 2 -supported combustion process to propagate. Concentrations of NaNO 3 above 95 wt percent or below 35 wt percent did not react with enough energy release to support combustion. The influence of sample size and confining pressure, both important factors, was not investigated in this study

Investigations on H2 combustion processes

International Nuclear Information System (INIS)

Breitung, W.; Hesselschwerdt, E.; Massier, H.; Moeschke, M.; Redlinger, R.; Wilkening, H.; Werle, H.; Wolff, J.

1995-01-01

During 1994 results were obtained for turbulent deflagrations, detonation ignition criteria, and detonations. In the field of turbulent deflagrations, two different 2-d codes have been developed, which are capable of describing the large spectrum of combustion regimes important for severe accident analysis. Two series of large scale experiments on turbulent H 2 -air combustion have been completed, one with premixed atmospheres, one with dynamic H 2 -injection into the test volume. They provided new clean data for code evaluation on reactor relevant scale (up to 480 m 3 volume). In the field of detonation ignition criteria different mechanisms were investigated which can trigger a transition from deflagration to detonation (DDT). Large scale experiments were performed on turbulent jet ignition of unconfined H 2 -air mixtures. As in earlier small scale tests, detonation ignition was only observed above 25% hydrogen in air. Such reactive mixtures will be rare in severe accidents. Pressure wave focussing was also investigated experimentally. The Mach numbers necessary to trigger a local detonation in different geometries and in different H 2 -air mixtures were measured on small scale. The conditions necessary for a shockless detonation ignition by induction time gradients were calculated. Only close to the reactor pressure vessel the corresponding temperatures and temperature gradients can possibly exist, not in the remainder of the containment. In the field of detonation modeling the code development was completed. Detonation experiments were performed in a 12 m tube equipped with complex obstacles. Some of the data were used to validate the codes. The remaining analysis will be performed in early 1995. The codes can describe well all important physical phenomena which influence detonation loads in complex 3-d geometries. The validated codes were used to calculate local detonation loads in a preliminary EPR containment. (orig./HP)

Hadron–Quark Combustion as a Nonlinear, Dynamical System

Science.gov (United States)

Ouyed, Amir; Ouyed, Rachid; Jaikumar, Prashanth

2018-03-01

The hadron-quark combustion front is a system that couples various processes, such as chemical reactions, hydrodynamics, diffusion, and neutrino transport. Previous numerical work has shown that this system is very nonlinear, and can be very sensitive to some of these processes. In these proceedings, we contextualize the hadron-quark combustion as a nonlinear system, subject to dramatic feedback triggered by leptonic weak decays and neutrino transport.

Advanced methods for processing ceramics

Energy Technology Data Exchange (ETDEWEB)

Carter, W.B. [Georgia Institute of Technology, Atlanta, GA (United States)

1995-05-01

Combustion chemical vapor deposition (CCVD) is a flame assisted, open air chemical vapor deposition (CVD) process. The process is capable of producing textured, epitaxial coatings on single crystal substrates using low cost reagents. Combustion chemical vapor deposition is a relatively inexpensive, alternative thin film deposition process with potential to replace conventional coating technologies for certain applications. The goals of this project are to develop the CCVD process to the point that potential industrial applications can be identified and reliably assessed.

Effects of Fuel Quantity on Soot Formation Process for Biomass-Based Renewable Diesel Fuel Combustion

KAUST Repository

Jing, Wei

2016-12-01

Soot formation process was investigated for biomass-based renewable diesel fuel, such as biomass to liquid (BTL), and conventional diesel combustion under varied fuel quantities injected into a constant volume combustion chamber. Soot measurement was implemented by two-color pyrometry under quiescent type diesel engine conditions (1000 K and 21% O2 concentration). Different fuel quantities, which correspond to different injection widths from 0.5 ms to 2 ms under constant injection pressure (1000 bar), were used to simulate different loads in engines. For a given fuel, soot temperature and KL factor show a different trend at initial stage for different fuel quantities, where a higher soot temperature can be found in a small fuel quantity case but a higher KL factor is observed in a large fuel quantity case generally. Another difference occurs at the end of combustion due to the termination of fuel injection. Additionally, BTL flame has a lower soot temperature, especially under a larger fuel quantity (2 ms injection width). Meanwhile, average soot level is lower for BTL flame, especially under a lower fuel quantity (0.5 ms injection width). BTL shows an overall low sooting behavior with low soot temperature compared to diesel, however, trade-off between soot level and soot temperature needs to be carefully selected when different loads are used.

Combustion control and sensors: a review

International Nuclear Information System (INIS)

Docquier, N.; Candel, S.

2002-01-01

There is an increased interest in the application of control to combustion. The objective is to optimize combustor operation, monitor the process and alleviate instabilities and their severe consequences. One wishes to improve the system performance, for example by reducing the levels of pollutant emissions or by smoothing the pattern factor at the combustor exhaust. In other cases, the aim is to extend the stability domain by reducing the level of oscillation induced by coupling between resonance modes and combustion. As combustion systems have to meet increasingly more demanding air pollution standards, their design and operation becomes more complex. The trend towards reduced NO x levels has led to new developments in different fields. Automotive engines and gas turbine combustors are considered in this article. In the first case, complex exhaust aftertreatment is being applied and dedicated engine control systems are required to ensure and maintain high pollutant conversion efficiency. For gas turbines, premixed combustors, which operate at lower local temperatures than conventional systems have been designed. In both cases, monitoring and control of the operating point of the process have to be achieved with great precision to obtain the full benefits of the NO x reduction scheme. For premixed combustors operating near the lean stability limit, the flame is more susceptible to blowout, oscillation or flashback. Research is now carried out to reduce these dynamical problems with passive and active control methods. In addition to a broad range of fundamental problems raised by Active Combustion Control (ACC) and Operating Point Control (OPC), there are important technological issues. This paper contains a review of some facets of combustion control and focuses on the sensors that take or could take part to combustion control solutions. The current status of ACC and OPC is presented together with the associated control concepts. The state of the art in sensors is

Two phase exhaust for internal combustion engine

Science.gov (United States)

Vuk, Carl T [Denver, IA

2011-11-29

An internal combustion engine having a reciprocating multi cylinder internal combustion engine with multiple valves. At least a pair of exhaust valves are provided and each supply a separate power extraction device. The first exhaust valves connect to a power turbine used to provide additional power to the engine either mechanically or electrically. The flow path from these exhaust valves is smaller in area and volume than a second flow path which is used to deliver products of combustion to a turbocharger turbine. The timing of the exhaust valve events is controlled to produce a higher grade of energy to the power turbine and enhance the ability to extract power from the combustion process.

Mercury and toxic metals in ash from combustion and incineration processes; Mercurio y metales toxicos en cenizas provenientes de procesos de combustion e incineracion

Energy Technology Data Exchange (ETDEWEB)

Mugica, V.; Amador, M.A.; Torres, M.; Figueroa, J. de J. [Universidad Autonomo-Metropolitana-Azcapotzalco, Reynosa (Mexico)

2003-07-01

In Mexico, most of the ashes from combustion and incineration process were not appropriately disposed, they are either left on industrial yards and cliffs or thrown away in open spaces and then carried by the wind to places where they can harm population, affect aquatic environment or soils. For prevention and control, the knowledge on the concentration of trace elements in waste ashes is necessary. In this study, several oxidation methods for digestion of ashes followed by inductively coupled plasma emission spectrometry were evaluated. Hg, Cd, Cr, Cu, Ni, Pb and V were determined in ashes from coal and fuel oil combustion, as well as in ashes from the incineration of municipal, water treatment sludge, and medical wastes. Results showed important concentrations of different trace elements in the ashes. This suggests that adequate disposal of these wastes should be mandatory. On the other hand, concentration of trace elements in the leachates indicated that these wastes are not toxic and they could be disposed in sanitary landfill. 23 refs.

Combustion and fuel loading characteristics of Hanford Site transuranic solid waste

International Nuclear Information System (INIS)

Greenhalgh, W.O.

1994-01-01

The Waste Receiving and Processing (WRAP) Facility is being designed for construction in the north end of the Central Waste Complex. The WRAP Facility will receive, store, and process radioactive solid waste of both transuranic (TRU) and mixed waste (mixed radioactive-chemical waste) categories. Most of the waste is in 208-L (55-gal) steel drums. Other containers such as wood and steel boxes, and various sized drums will also be processed in the facility. The largest volume of waste and the type addressed in this report is TRU in 208-L (55-gal) drums that is scheduled to be processed in the Waste Receiving and Processing Facility Module 1 (WRAP 1). Half of the TRU waste processed by WRAP 1 is expected to be retrieved stored waste and the other half newly generated waste. Both the stored and new waste will be processed to certify it for permanent storage in the Waste Isolation Pilot Plant (WIPP) or disposal. The stored waste will go through a process of retrieval, examination, analysis, segregation, repackaging, relabeling, and documentation before certification and WIPP shipment. Newly generated waste should be much easier to process and certify. However, a substantial number of drums of both retrievable and newly generated waste will require temporary storage and handling in WRAP. Most of the TRU waste is combustible or has combustible components. Therefore, the presence of a substantial volume of drummed combustible waste raises concern about fire safety in WRAP and similar waste drum storage facilities. This report analyzes the fire related characteristics of the expected WRAP TRU waste stream

Hybrid Combustion-Gasification Chemical Looping

Energy Technology Data Exchange (ETDEWEB)

Herbert Andrus; Gregory Burns; John Chiu; Gregory Lijedahl; Peter Stromberg; Paul Thibeault

2009-01-07

For the past several years Alstom Power Inc. (Alstom), a leading world-wide power system manufacturer and supplier, has been in the initial stages of developing an entirely new, ultra-clean, low cost, high efficiency power plant for the global power market. This new power plant concept is based on a hybrid combustion-gasification process utilizing high temperature chemical and thermal looping technology The process consists of the oxidation, reduction, carbonation, and calcination of calcium-based compounds, which chemically react with coal, biomass, or opportunity fuels in two chemical loops and one thermal loop. The chemical and thermal looping technology can be alternatively configured as (i) a combustion-based steam power plant with CO{sub 2} capture, (ii) a hybrid combustion-gasification process producing a syngas for gas turbines or fuel cells, or (iii) an integrated hybrid combustion-gasification process producing hydrogen for gas turbines, fuel cells or other hydrogen based applications while also producing a separate stream of CO{sub 2} for use or sequestration. In its most advanced configuration, this new concept offers the promise to become the technology link from today's Rankine cycle steam power plants to tomorrow's advanced energy plants. The objective of this work is to develop and verify the high temperature chemical and thermal looping process concept at a small-scale pilot facility in order to enable AL to design, construct and demonstrate a pre-commercial, prototype version of this advanced system. In support of this objective, Alstom and DOE started a multi-year program, under this contract. Before the contract started, in a preliminary phase (Phase 0) Alstom funded and built the required small-scale pilot facility (Process Development Unit, PDU) at its Power Plant Laboratories in Windsor, Connecticut. Construction was completed in calendar year 2003. The objective for Phase I was to develop the indirect combustion loop with CO{sub 2

Computational experience with a three-dimensional rotary engine combustion model

Science.gov (United States)

Raju, M. S.; Willis, E. A.

1990-04-01

A new computer code was developed to analyze the chemically reactive flow and spray combustion processes occurring inside a stratified-charge rotary engine. Mathematical and numerical details of the new code were recently described by the present authors. The results are presented of limited, initial computational trials as a first step in a long-term assessment/validation process. The engine configuration studied was chosen to approximate existing rotary engine flow visualization and hot firing test rigs. Typical results include: (1) pressure and temperature histories, (2) torque generated by the nonuniform pressure distribution within the chamber, (3) energy release rates, and (4) various flow-related phenomena. These are discussed and compared with other predictions reported in the literature. The adequacy or need for improvement in the spray/combustion models and the need for incorporating an appropriate turbulence model are also discussed.

Thermal and dynamic loads on the EPR containment due to hydrogen combustion

International Nuclear Information System (INIS)

Eyink, J.; Movahed, M.; Petzold, K.G.; Kotchourko, A.; Royl, P.; Travis, J.R.

2001-01-01

A major aspect of the EPR safety concept is to cope with severe accidents including core melt and to maintain the integrity of the containment even for those hypothetical events. One potential threat for the containment is related to the combustion of hydrogen, which may be produced in a large amount during core degradation. The European Pressurized Water Reactor (EPR) hydrogen mitigation concept consists of about 44 recombiners, located mainly in the equipment rooms (only 4 recombiners are located in the dome area). This paper is devoted to two important potential threats on the containment related to hydrogen removal: - Thermal loads resulting from recombiner action and/or combustion are of importance also with respect to the integrity of the local composite liner foreseen at some crucial locations of the containment; - Dynamic loads resulting from fast deflagration may impair containment wall or internal walls even if the AICC (adiabatic isochoric complete combustion) pressure is below the design pressure. Two types of combustion calculations have been performed: a) In cases, where fast deflagration cannot be excluded, combustion has been calculated with COM3D, a special CFD code developed to calculate dynamic pressure loads on walls, and b) 'Standing flame' combustion as well as recombination processes have been calculated with GASFLOW for bounding scenarios in order to evaluate maximum containment wall surface temperatures for cases of long-lasting combustion, mainly with emphasis on the application of a partial liner. Because of the depressurization of the reactor coolant system directly into the containment atmosphere via a relief tank and rupture discs a high concentration of steam is available for nearly all scenarios. For these scenarios no threat to internal walls is expected based on the combustion loads identified by the analyses presented here. In case of fast secondary cool-down a large amount of energy is removed to the secondary side of the SG and

Decrease of noxious emissions in the residual fuel oil combustion; Disminucion de emisiones nocivas en la combustion de aceite combustible residual

Energy Technology Data Exchange (ETDEWEB)

Mandoki W, Jorge [Econergia S. de R. L. de C. V. Mexico, D. F. (Mexico)

1994-12-31

The residual fuel oil combustion emits noxious substances such as carbonaceous particulate, nitrogen oxides, and sulfur trioxide at unacceptable levels. Water emulsified in the fuel substantially reduces such emissions, achieving besides, in most of the cases, a net saving in the fuel consumption. The beneficial effects are shown in burning the residual fuel oil as a water emulsion, as well as the method to produce an adequate emulsion. The emulsified fuel technology offers a low cost option to reduce air pollution. The fuel oil quality has been declining during the last decades due to: 1. Increase in the production of crude heavy oils, generally with higher content of asphaltens and sulfur. 2. Less availability of vacuum distillation residues due to its conversion into greater value products. 3. More intensive conversion processes such as catalytic cracking, visbreaking, etc. that increase the asphaltenes concentration in the bottoms, causing instability problems. 4. The increase in the vanadium and other metals content as the concentration of asphaltenes increases. The use of emulsified fuel oil provides an efficient and economical method to substantially reduce the noxious emissions to the atmosphere. The emulsion contains water particles in a diameter between 2 and 20 microns, uniformly distributed in the fuel oil, generally in a proportion generally of 5 to 10%; besides, it contains a tensioactive agent to assure a stable emulsion capable of withstanding the shearing forces of the pumping and distribution systems. When the atomized oil drops get into the combustion chamber, the emulsified water flashes into high pressure steam, originating a violent secondary atomization. The effect of this secondary atomization is the rupture of the oil drops of various hundred microns, producing drops of 5 to 15 microns in diameter. Since the necessary time for combustion is an exponential function of the drop diameter, a very substantial improvement in the combustion is

A study of the current group evaporation/combustion theories

Science.gov (United States)

Shen, Hayley H.

1990-01-01

Liquid fuel combustion can be greatly enhanced by disintegrating the liquid fuel into droplets, an effect achieved by various configurations. A number of experiments carried out in the seventies showed that combustion of droplet arrays and sprays do not form individual flames. Moreover, the rate of burning in spray combustion greatly deviates from that of the single combustion rate. Such observations naturally challenge its applicability to spray combustion. A number of mathematical models were developed to evaluate 'group combustion' and the related 'group evaporation' phenomena. This study investigates the similarity and difference of these models and their applicability to spray combustion. Future work that should be carried out in this area is indicated.

The toxicity of particles from combustion processes

International Nuclear Information System (INIS)

Henderson, R.F.; Mauderly, J.L.

1991-01-01

The pulmonary toxicity of inhaled particles will depend on their size, solubility and inherent toxicity. Many combustion-derived particles, such as soot and fly ash, are of a respirable size and, being poorly soluble, are retained for prolonged periods in the lung. The acute toxicity of fly ash from coal combustion was compared to that of a known toxic particle, alpha-quartz, by exposures of rats to 35 mg/m 3 of each type of particle for 7 hr/day, 5 days/wk for 4 wk. The acute pulmonary toxicity was measured by analysis of bronchoalveolar lavage fluid. One year after the exposures, fibrosis with granulomas was observed in the quartz-exposed rats, while little or no fibrosis developed in the fly-ash-exposed rats. The toxicity of soot from diesel exhaust was determined by chronic (30 mo) exposures of rats, 7 hr/day, 5 days/wk to exhaust containing 0.35, 3.5 or 7.0 mg/m 3 soot. The two higher exposures caused persistent pulmonary inflammation, fibrosis and neoplasmas. Rats exposed to the lowest concentration demonstrated no toxic responses and there was no life shortening caused by any exposure. Ongoing comparative studies indicate that pure carbon black particles cause responses similar to those caused by diesel exhaust, indicating that much of the toxicity induced by the diesel soot results from the presence of the large lung burdens of carbonaceous particles

Appraisal of possible combustion hazards associated with a high-temperature gas-cooled reactor

International Nuclear Information System (INIS)

Palmer, H.B.; Sibulkin, M.; Strehlow, R.A.; Yang, C.H.

1978-03-01

The report presents a study of combustion hazards that may be associated with the High Temperature Gas Cooled Reactor (HTGR) in the event of a primary coolant circuit depressurization followed by water or air ingress into the prestressed concrete reactor vessel (PCRV). Reactions between graphite and steam or air produce the combustible gases H 2 and/or CO. When these gases are mixed with air in the containment vessel (CV), flammable mixtures may be formed. Various modes of combustion including diffusion or premixed flames and possibly detonation may be exhibited by these mixtures. These combustion processes may create high over-pressure, pressure waves, and very hot gases within the CV and hence may threaten the structural integrity of the CV or damage the instrumentation and control system installations within it. Possible circumstances leading to these hazards and the physical characteristics related to them are delineated and studied in the report

NIR to visible upconversion in Er3+/Yb3+ co-doped CaYAl3O7 phosphor obtained by solution combustion process

International Nuclear Information System (INIS)

Singh, Vijay; Rai, Vineet Kumar; Al-Shamery, Katharina; Nordmann, Joerg; Haase, Markus

2011-01-01

Using the combustion synthesis, CaYAl 3 O 7 :Er 3+ phosphor powders co-doped with Yb 3+ have been prepared at low temperatures (550 o C) in a few minutes. Formation of the compound was confirmed by X-ray powder diffraction. Near-infrared to visible upconversion fluorescence emission in the Er 3+ doped CaYAl 3 O 7 phosphor powder has been observed. The effect of co-doping with triply ionized ytterbium in the CaYAl 3 O 7 :Er 3+ phosphor has been studied and the process involved is discussed. - Highlights: → The green emitting up-conversion CaYAl 3 O 7 :Er 3+ phosphor powders co-doped with Yb 3+ have been prepared by easy combustion method. → The combustion method is a simple, energy saving, fast and economical viable process. → The luminescence intensity in the co-doped phosphor is enhanced by several times compared to that of the singly (Er 3+ ) doped phosphor.

Combustion stratification study of partially premixed combustion using Fourier transform analysis of OH* chemiluminescence images

KAUST Repository

Izadi Najafabadi, Mohammad

2017-11-06

A relatively high level of stratification (qualitatively: lack of homogeneity) is one of the main advantages of partially premixed combustion over the homogeneous charge compression ignition concept. Stratification can smooth the heat release rate and improve the controllability of combustion. In order to compare stratification levels of different partially premixed combustion strategies or other combustion concepts, an objective and meaningful definition of “stratification level” is required. Such a definition is currently lacking; qualitative/quantitative definitions in the literature cannot properly distinguish various levels of stratification. The main purpose of this study is to objectively define combustion stratification (not to be confused with fuel stratification) based on high-speed OH* chemiluminescence imaging, which is assumed to provide spatial information regarding heat release. Stratification essentially being equivalent to spatial structure, we base our definition on two-dimensional Fourier transforms of photographs of OH* chemiluminescence. A light-duty optical diesel engine has been used to perform the OH* bandpass imaging on. Four experimental points are evaluated, with injection timings in the homogeneous regime as well as in the stratified partially premixed combustion regime. Two-dimensional Fourier transforms translate these chemiluminescence images into a range of spatial frequencies. The frequency information is used to define combustion stratification, using a novel normalization procedure. The results indicate that this new definition, based on Fourier analysis of OH* bandpass images, overcomes the drawbacks of previous definitions used in the literature and is a promising method to compare the level of combustion stratification between different experiments.

Gasoline Combustion Fundamentals DOE FY17 Report

Energy Technology Data Exchange (ETDEWEB)

Ekoto, Isaac W. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2017-11-01

Advanced automotive gasoline engines that leverage a combination of reduced heat transfer, throttling, and mechanical losses; shorter combustion durations; and higher compression and mixture specific heat ratios are needed to meet aggressive DOE VTP fuel economy and pollutant emission targets. Central challenges include poor combustion stability at low-power conditions when large amounts of charge dilution are introduced and high sensitivity of conventional inductive coil ignition systems to elevated charge motion and density for boosted high-load operation. For conventional spark ignited operation, novel low-temperature plasma (LTP) or pre-chamber based ignition systems can improve dilution tolerances while maintaining good performance characteristics at elevated charge densities. Moreover, these igniters can improve the control of advanced compression ignition (ACI) strategies for gasoline at low to moderate loads. The overarching research objective of the Gasoline Combustion Fundamentals project is to investigate phenomenological aspects related to enhanced ignition. The objective is accomplished through targeted experiments performed in a single-cylinder optically accessible research engine or an in-house developed optically accessible spark calorimeter (OASC). In situ optical diagnostics and ex situ gas sampling measurements are performed to elucidate important details of ignition and combustion processes. Measurements are further used to develop and validate complementary high-fidelity ignition simulations. The primary project audience is automotive manufacturers, Tier 1 suppliers, and technology startups—close cooperation has resulted in the development and execution of project objectives that address crucial mid- to long-range research challenges.

Combustion aerosols from potassium-containing fuels

Energy Technology Data Exchange (ETDEWEB)

Balzer Nielsen, Lars

1999-12-31

The scope of the work presented in this thesis is the formation and evolution of aerosol particles in the submicron range during combustion processes, in particular where biomass is used alone or co-fired with coal. An introduction to the formation processes of fly ash in general and submicron aerosol in particular during combustion is presented, along with some known problems related to combustion of biomass for power generation. The work falls in two parts. The first is the design of a laboratory setup for investigation of homogeneous nucleation and particle dynamics at high temperature. The central unit of the setup is a laminar flow aerosol condenser (LFAC), which essentially is a 173 cm long tubular furnace with an externally cooled wall. A mathematical model is presented which describes the formation and evolution of the aerosol in the LFAC, where the rate of formation of new nuclei is calculated using the so-called classical theory. The model includes mass and energy conservation equations and an expression for the description of particle growth by diffusion. The resulting set of nonlinear second-order partial differential equations are solved numerically using the method of orthogonal collocation. The model is implemented in the FORTRAN code MONAERO. The second part of this thesis describes a comprehensive investigation of submicron aerosol formation during co-firing of coal and straw carried out at a 380 MW{sub Th} pulverized coal unit at Studstrup Power Plant, Aarhus. Three types of coal are used, and total boiler load and straw input is varied systematically. Straw contains large amounts of potassium, which is released during combustion. Submicron aerosol is sampled between the two banks of the economizer at a flue gas temperature of 350 deg. C using a novel ejector probe. The aerosol is characterized using the SMPS system and a Berner-type low pressure impactor. The chemical composition of the particles collected in the impactor is determined using

Combustion aerosols from potassium-containing fuels

International Nuclear Information System (INIS)

Balzer Nielsen, Lars

1998-01-01

The scope of the work presented in this thesis is the formation and evolution of aerosol particles in the submicron range during combustion processes, in particular where biomass is used alone or co-fired with coal. An introduction to the formation processes of fly ash in general and submicron aerosol in particular during combustion is presented, along with some known problems related to combustion of biomass for power generation. The work falls in two parts. The first is the design of a laboratory setup for investigation of homogeneous nucleation and particle dynamics at high temperature. The central unit of the setup is a laminar flow aerosol condenser (LFAC), which essentially is a 173 cm long tubular furnace with an externally cooled wall. A mathematical model is presented which describes the formation and evolution of the aerosol in the LFAC, where the rate of formation of new nuclei is calculated using the so-called classical theory. The model includes mass and energy conservation equations and an expression for the description of particle growth by diffusion. The resulting set of nonlinear second-order partial differential equations are solved numerically using the method of orthogonal collocation. The model is implemented in the FORTRAN code MONAERO. The second part of this thesis describes a comprehensive investigation of submicron aerosol formation during co-firing of coal and straw carried out at a 380 MW Th pulverized coal unit at Studstrup Power Plant, Aarhus. Three types of coal are used, and total boiler load and straw input is varied systematically. Straw contains large amounts of potassium, which is released during combustion. Submicron aerosol is sampled between the two banks of the economizer at a flue gas temperature of 350 deg. C using a novel ejector probe. The aerosol is characterized using the SMPS system and a Berner-type low pressure impactor. The chemical composition of the particles collected in the impactor is determined using chemical

Combustion aerosols from potassium-containing fuels

Energy Technology Data Exchange (ETDEWEB)

Balzer Nielsen, Lars

1998-12-31

The scope of the work presented in this thesis is the formation and evolution of aerosol particles in the submicron range during combustion processes, in particular where biomass is used alone or co-fired with coal. An introduction to the formation processes of fly ash in general and submicron aerosol in particular during combustion is presented, along with some known problems related to combustion of biomass for power generation. The work falls in two parts. The first is the design of a laboratory setup for investigation of homogeneous nucleation and particle dynamics at high temperature. The central unit of the setup is a laminar flow aerosol condenser (LFAC), which essentially is a 173 cm long tubular furnace with an externally cooled wall. A mathematical model is presented which describes the formation and evolution of the aerosol in the LFAC, where the rate of formation of new nuclei is calculated using the so-called classical theory. The model includes mass and energy conservation equations and an expression for the description of particle growth by diffusion. The resulting set of nonlinear second-order partial differential equations are solved numerically using the method of orthogonal collocation. The model is implemented in the FORTRAN code MONAERO. The second part of this thesis describes a comprehensive investigation of submicron aerosol formation during co-firing of coal and straw carried out at a 380 MW{sub Th} pulverized coal unit at Studstrup Power Plant, Aarhus. Three types of coal are used, and total boiler load and straw input is varied systematically. Straw contains large amounts of potassium, which is released during combustion. Submicron aerosol is sampled between the two banks of the economizer at a flue gas temperature of 350 deg. C using a novel ejector probe. The aerosol is characterized using the SMPS system and a Berner-type low pressure impactor. The chemical composition of the particles collected in the impactor is determined using

Application of macro-cellular SiC reactor to diesel engine-like injection and combustion conditions

Science.gov (United States)

Cypris, Weclas, M.; Greil, P.; Schlier, L. M.; Travitzky, N.; Zhang, W.

2012-05-01

One of novel combustion technologies for low emissions and highly efficient internal combustion engines is combustion in porous reactors (PM). The heat release process inside combustion reactor is homogeneous and flameless resulting in a nearly zero emissions level. Such combustion process, however is non-stationary, is performed under high pressure with requirement of mixture formation directly inside the combustion reactor (high pressure fuel injection). Reactor heat capacity resulting in lowering of combustion temperature as well as internal heat recuperation during the engine cycle changes the thermodynamic conditions of the process as compared to conventional engine. For the present investigations a macro-cellular lattice structure based on silicon carbide (non-foam structure) with 600 vertical cylindrical struts was fabricated and applied to engine-like combustion conditions (combustion chamber). The lattice design with a high porosity > 80% was shaped by indirect three-dimensional printing of a SiC powder mixed with a dextrin binder which also serves as a carbon precursor. In order to perform detailed investigations on low-and high-temperature oxidation processes in porous reactors under engine-like conditions, a special combustion chamber has been built and equipped with a Diesel common-rail injection system. This system simulates the thermodynamic conditions at the time instance of injection onset (corresponding to the nearly TDC of compression in a real engine). Overall analysis of oxidation processes (for variable initial pressure, temperature and air excess ratio) for free Diesel spray combustion and for combustion in porous reactor allows selection of three regions representing different characteristics of the oxidation process represented by a single-step and multi-step reactions Another characteristic feature of investigated processes is reaction delay time. There are five characteristic regions to be selected according to the delay time (t) duration

IEA combustion agreement : a collaborative task on alternative fuels in combustion

International Nuclear Information System (INIS)

Larmi, M.

2009-01-01

The focus of the alternative fuels in combustion task of the International Energy Agency is on high efficiency engine combustion, furnace combustion, and combustion chemistry. The objectives of the task are to develop optimum combustion for dedicated fuels by fully utilizing the physical and chemical properties of synthetic and renewable fuels; a significant reduction in carbon dioxide, NOx and particulate matter emissions; determine the minimum emission levels for dedicated fuels; and meet future emission standards of engines without or with minimum after-treatment. This presentation discussed the alternative fuels task and addressed issues such as synthetic fuel properties and benefits. The anticipated future roadmap was presented along with a list of the synthetic and renewable engine fuels to be studied, such as neat oxygenates like alcohols and ethers, biogas/methane and gas combustion, fuel blends, dual fuel combustion, high cetane number diesel fuels like synthetic Fischer-Tropsch diesel fuel and hydrogenated vegetable oil, and low CN number fuels. Implementation examples were also discussed, such as fuel spray studies in optical spray bombs; combustion research in optical engines and combustion chambers; studies on reaction kinetics of combustion and emission formation; studies on fuel properties and ignition behaviour; combustion studies on research engines; combustion optimization; implementing the optimum combustion in research engines; and emission measurements. Overall milestone examples and the overall schedule of participating countries were also presented. figs.

Hadron–Quark Combustion as a Nonlinear, Dynamical System

Directory of Open Access Journals (Sweden)

Amir Ouyed

2018-03-01

Full Text Available The hadron–quark combustion front is a system that couples various processes, such as chemical reactions, hydrodynamics, diffusion, and neutrino transport. Previous numerical work has shown that this system is very nonlinear, and can be very sensitive to some of these processes. In these proceedings, we contextualize the hadron–quark combustion as a nonlinear system, subject to dramatic feedback triggered by leptonic weak decays and neutrino transport.

New combustion, environment regulations: the answers for natural gas; Nouvelles reglementations, combustion, environnement: les reponses pour le gaz naturel

Energy Technology Data Exchange (ETDEWEB)

Le Peltier-Marc, A. [Gaz de France (GDF), 75 - Paris (France)

1997-12-31

This paper reports on the point of view from Gaz de France (GdF) company concerning the potential consequences of the use of natural gas in combustion systems with respect to the new regulations about combustion and environment. Details concerning the measures relative to the limitation of pollutants in small combustion installations (2 - 20 MW) are given (chimney height, SO{sub x}, NO{sub x} and dusts content in exhaust gases). (J.S.)

The John Zink Hamworthy combustion handbook, v.1 fundamentals

CERN Document Server

Baukal, Charles E

2012-01-01

Despite the length of time it has been around, its importance, and vast amounts of research, combustion is still far from being completely understood. Environmental, cost, and fuel consumption issues add further complexity, particularly in the process and power generation industries. Dedicated to advancing the art and science of industrial combustion, The John Zink Hamworthy Combustion Handbook, Second Edition: Volume One - Fundamentals gives you a strong understanding of the basic concepts and theory. Under the leadership of Charles E. Baukal, Jr., top combustion engineers and technologists f

Numerical Simulation of In Situ Combustion of Oil Shale

Directory of Open Access Journals (Sweden)

Huan Zheng

2017-01-01

Full Text Available This paper analyzes the process of in situ combustion of oil shale, taking into account the transport and chemical reaction of various components in porous reservoirs. The physical model is presented, including the mass and energy conservation equations and Darcy’s law. The oxidation reactions of oil shale combustion are expressed by adding source terms in the conservation equations. The reaction rate of oxidation satisfies the Arrhenius law. A numerical method is established for calculating in situ combustion, which is simulated numerically, and the results are compared with the available experiment. The profiles of temperature and volume fraction of a few components are presented. The temperature contours show the temperature variation in the combustion tube. It is found that as combustion reaction occurs in the tube, the concentration of oxygen decreases rapidly, while the concentration of carbon dioxide and carbon monoxide increases contrarily. Besides, the combustion front velocity is consistent with the experimental value. Effects of gas injection rate, permeability of the reservoir, initial oil content, and injected oxygen content on the ISC process were investigated in this study. Varying gas injection rate and oxygen content is important in the field test of ISC.

Accurate Anharmonic Zero-Point Energies for Some Combustion-Related Species from Diffusion Monte Carlo.

Science.gov (United States)

Harding, Lawrence B; Georgievskii, Yuri; Klippenstein, Stephen J

2017-06-08

Full-dimensional analytic potential energy surfaces based on CCSD(T)/cc-pVTZ calculations have been determined for 48 small combustion-related molecules. The analytic surfaces have been used in Diffusion Monte Carlo calculations of the anharmonic zero-point energies. The resulting anharmonicity corrections are compared to vibrational perturbation theory results based both on the same level of electronic structure theory and on lower-level electronic structure methods (B3LYP and MP2).

Combustion Stratification for Naphtha from CI Combustion to PPC

KAUST Repository

Vallinayagam, R.; Vedharaj, S.; An, Yanzhao; Dawood, Alaaeldin; Izadi Najafabadi, Mohammad; Somers, Bart; Johansson, Bengt

2017-01-01

This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON

An incinerator for combustable radwastes

International Nuclear Information System (INIS)

Li Jingquan; Jiang Yun; Zhang Yinsheng; Chen Boling; Zhang Shihang

1989-01-01

An incinerator has been built up in Shanghai. In this paper, the devices of the incinerator, main parameters of the process, and the results of non-radioactive waste and simulated radwaste combustion tests were contributed. That provides reference information for radwaste treatment with incineration process

Recent Trends in the Production, Combustion and Modeling of Furan-Based Fuels

Directory of Open Access Journals (Sweden)

Mazen A. Eldeeb

2018-02-01

Full Text Available There is growing interest in the use of furans, a class of alternative fuels derived from biomass, as transportation fuels. This paper reviews recent progress in the characterization of its combustion properties. It reviews their production processes, theoretical kinetic explorations and fundamental combustion properties. The theoretical efforts are focused on the mechanistic pathways for furan decomposition and oxidation, as well as the development of detailed chemical kinetic models. The experiments reviewed are mostly concerned with the temporal evolutions of homogeneous reactors and the propagation of laminar flames. The main thrust in homogeneous reactors is to determine global chemical time scales such as ignition delay times. Some studies have adopted a comparative approach to bring out reactivity differences. Chemical kinetic models with varying degrees of predictive success have been established. Experiments have revealed the relative behavior of their combustion. The growing body of literature in this area of combustion chemistry of alternative fuels shows a great potential for these fuels in terms of sustainable production and engine performance. However, these studies raise further questions regarding the chemical interactions of furans with other hydrocarbons. There are also open questions about the toxicity of the byproducts of combustion.

combustion properties of briquettes produced from maize cob

African Journals Online (AJOL)

joke

2014-03-01

Mar 1, 2014 ... were densified into briquettes using starch as binder. Combustion related ... Keywords: Briquette, maize cob, combustion properties, mesh sizes, binding agent ... smaller space requirement for storage (Yaman et al., 2000 and ...

Chemiluminescence analysis of the effect of butanol-diesel fuel blends on the spray-combustion process in an experimental common rail diesel engine

Directory of Open Access Journals (Sweden)

Merola Simona Silvia S.

2015-01-01

Full Text Available Combustion process was studied from the injection until the late combustion phase in an high swirl optically accessible combustion bowl connected to a single cylinder 2-stroke high pressure common rail compression ignition engine. Commercial diesel and blends of diesel and n-butanol (20%: BU20 and 40%: BU40 were used for the experiments. A pilot plus main injection strategy was investigated fixing the injection pressure and fuel mass injected per stroke. Two main injection timings and different pilot-main dwell times were explored achieving for any strategy a mixing controlled combustion. Advancing the main injection start, an increase in net engine working cycle (>40% together with a strong smoke number decrease (>80% and NOx concentration increase (@50% were measured for all pilot injection timings. Compared to diesel fuel, butanol induced a decrease in soot emission and an increase in net engine working area when butanol ratio increased in the blend. A noticeable increase in NOx was detected at the exhaust for BU40 with a slight effect of the dwell-time. Spectroscopic investigations confirmed the delayed auto-ignition (~60 ms of the pilot injection for BU40 compared to diesel. The spectral features for the different fuels were comparable at the start of combustion process, but they evolved in different ways. Broadband signal caused by soot emission, was lower for BU40 than diesel. Different balance of the bands at 309 and 282 nm, due to different OH transitions, were detected between the two fuels. The ratio of these intensities was used to follow flame temperature evolution.

Evaluation of self-combustion risk in tire derived aggregate fills.

Science.gov (United States)

Arroyo, Marcos; San Martin, Ignacio; Olivella, Sebastian; Saaltink, Maarten W

2011-01-01

Lightweight tire derived aggregate (TDA) fills are a proven recycling outlet for waste tires, requiring relatively low cost waste processing and being competitively priced against other lightweight fill alternatives. However its value has been marred as several TDA fills have self-combusted during the early applications of this technique. An empirical review of these cases led to prescriptive guidelines from the ASTM aimed at avoiding this problem. This approach has been successful in avoiding further incidents of self-combustion. However, at present there remains no rational method available to quantify self-combustion risk in TDA fills. This means that it is not clear which aspects of the ASTM guidelines are essential and which are accessory. This hinders the practical use of TDA fills despite their inherent advantages as lightweight fill. Here a quantitative approach to self-combustion risk evaluation is developed and illustrated with a parametric analysis of an embankment case. This is later particularized to model a reported field self-combustion case. The approach is based on the available experimental observations and incorporates well-tested methodological (ISO corrosion evaluation) and theoretical tools (finite element analysis of coupled heat and mass flow). The results obtained offer clear insights into the critical aspects of the problem, allowing already some meaningful recommendations for guideline revision. Copyright © 2011 Elsevier Ltd. All rights reserved.

DFT studies of hydrocarbon combustion on metal surfaces.

Science.gov (United States)

Arya, Mina; Mirzaei, Ali Akbar; Davarpanah, Abdol Mahmood; Barakati, Seyed Masoud; Atashi, Hossein; Mohsenzadeh, Abas; Bolton, Kim

2018-02-02

Catalytic combustion of hydrocarbons is an important technology to produce energy. Compared to conventional flame combustion, the catalyst enables this process to operate at lower temperatures; hence, reducing the energy required for efficient combustion. The reaction and activation energies of direct combustion of hydrocarbons (CH → C + H) on a series of metal surfaces were investigated using density functional theory (DFT). The data obtained for the Ag, Au, Al, Cu, Rh, Pt, and Pd surfaces were used to investigate the validity of the Brønsted-Evans-Polanyi (BEP) and transition state scaling (TSS) relations for this reaction on these surfaces. These relations were found to be valid (R 2  = 0.94 for the BEP correlation and R 2  = 1.0 for the TSS correlation) and were therefore used to estimate the energetics of the combustion reaction on Ni, Co, and Fe surfaces. It was found that the estimated transition state and activation energies (E TS  = -69.70 eV and E a  = 1.20 eV for Ni, E TS  = -87.93 eV and E a  = 1.08 eV for Co and E TS  = -92.45 eV and E a  = 0.83 eV for Fe) are in agreement with those obtained by DFT calculations (E TS  = -69.98 eV and E a  = 1.23 eV for Ni, E TS  = -87.88 eV and E a  = 1.08 eV for Co and E TS  = -92.57 eV and E a  = 0.79 eV for Fe). Therefore, these relations can be used to predict energetics of this reaction on these surfaces without doing the time consuming transition state calculations. Also, the calculations show that the activation barrier for CH dissociation decreases in the order Ag ˃ Au ˃ Al ˃ Cu ˃ Pt ˃ Pd ˃ Ni > Co > Rh > Fe.

Processing of SiO2 protective layer using HMDS precursor by combustion CVD.

Science.gov (United States)

Park, Kyoung-Soo; Kim, Youngman

2011-08-01

Hexamethyldisilazane (HMDS, [(CH3)3Si]2NH) was used as a precursor to form SiO2 protective coatings on IN738LC alloys by combustion chemical vapor deposition (CCVD). SEM and XPS showed that the processed coatings were composed mainly of SiO2. The amount of HMDS had the largest effect on the size of the SiO2 agglomerates and the thickness of the deposited coatings. The specimens coated with SiO2 using the 0.05 mol/l HMDS solution showed a significantly higher temperature oxidation resistance than those deposited under other conditions.

Experimental and numerical studies on two-stage combustion of biomass

Energy Technology Data Exchange (ETDEWEB)

Houshfar, Eshan

2012-07-01

In this thesis, two-stage combustion of biomass was experimentally/numerically investigated in a multifuel reactor. The following emissions issues have been the main focus of the work: 1- NOx and N2O 2- Unburnt species (CO and CxHy) 3- Corrosion related emissions.The study had a focus on two-stage combustion in order to reduce pollutant emissions (primarily NOx emissions). It is well known that pollutant emissions are very dependent on the process conditions such as temperature, reactant concentrations and residence times. On the other hand, emissions are also dependent on the fuel properties (moisture content, volatiles, alkali content, etc.). A detailed study of the important parameters with suitable biomass fuels in order to optimize the various process conditions was performed. Different experimental studies were carried out on biomass fuels in order to study the effect of fuel properties and combustion parameters on pollutant emissions. Process conditions typical for biomass combustion processes were studied. Advanced experimental equipment was used in these studies. The experiments showed the effects of staged air combustion, compared to non-staged combustion, on the emission levels clearly. A NOx reduction of up to 85% was reached with staged air combustion using demolition wood as fuel. An optimum primary excess air ratio of 0.8-0.95 was found as a minimizing parameter for the NOx emissions for staged air combustion. Air staging had, however, a negative effect on N2O emissions. Even though the trends showed a very small reduction in the NOx level as temperature increased for non-staged combustion, the effect of temperature was not significant for NOx and CxHy, neither in staged air combustion or non-staged combustion, while it had a great influence on the N2O and CO emissions, with decreasing levels with increasing temperature. Furthermore, flue gas recirculation (FGR) was used in combination with staged combustion to obtain an enhanced NOx reduction. The

Determination of combustion parameters using engine crankshaft speed

Science.gov (United States)

Taglialatela, F.; Lavorgna, M.; Mancaruso, E.; Vaglieco, B. M.

2013-07-01

Electronic engine controls based on real time diagnosis of combustion process can significantly help in complying with the stricter and stricter regulations on pollutants emissions and fuel consumption. The most important parameter for the evaluation of combustion quality in internal combustion engines is the in-cylinder pressure, but its direct measurement is very expensive and involves an intrusive approach to the cylinder. Previous researches demonstrated the direct relationship existing between in-cylinder pressure and engine crankshaft speed and several authors tried to reconstruct the pressure cycle on the basis of the engine speed signal. In this paper we propose the use of a Multi-Layer Perceptron neural network to model the relationship between the engine crankshaft speed and some parameters derived from the in-cylinder pressure cycle. This allows to have a non-intrusive estimation of cylinder pressure and a real time evaluation of combustion quality. The structure of the model and the training procedure is outlined in the paper. A possible combustion controller using the information extracted from the crankshaft speed information is also proposed. The application of the neural network model is demonstrated on a single-cylinder spark ignition engine tested in a wide range of speeds and loads. Results confirm that a good estimation of some combustion pressure parameters can be obtained by means of a suitable processing of crankshaft speed signal.

Chemical kinetics and combustion modeling

Energy Technology Data Exchange (ETDEWEB)

Miller, J.A. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01

The goal of this program is to gain qualitative insight into how pollutants are formed in combustion systems and to develop quantitative mathematical models to predict their formation rates. The approach is an integrated one, combining low-pressure flame experiments, chemical kinetics modeling, theory, and kinetics experiments to gain as clear a picture as possible of the process in question. These efforts are focused on problems involved with the nitrogen chemistry of combustion systems and on the formation of soot and PAH in flames.

Process and Material Design for Micro-Encapsulated Ionic Liquids in Post-Combustion CO₂ Capture

Energy Technology Data Exchange (ETDEWEB)

Hong, Bo [Univ. of Notre Dame, IN (United States); Brennecke, Joan F [Univ. of Notre Dame, IN (United States); McCready, Mark [Univ. of Notre Dame, IN (United States); Stadtherr, Mark [Univ. of Notre Dame, IN (United States)

2016-11-18

Aprotic Heterocyclic Anion (AHA) Ionic Liquids (ILs) have been identified as promising new solvents for post-combustion carbon capture due to their high CO₂ uptake and the high tenability 1,2 of their binding energy with CO₂. Some of these compounds change phase (solid to liquid) on absorption of CO₂; these Phase Change ILs (PCILs)3 offer the additional advantage that part of the heat needed to desorb the CO2 from the absorbent is provided by the heat of fusion as the PCIL solidifies upon release of CO₂. However, the relatively high viscosity of AHA ILs and the occurrence of a phase change in PCILs present challenges for conventional absorption equipment. To overcome these challenges we are pursuing the use of new technology to micro-encapsulate the AHA ILs and PCILs. Our partners at Lawrence Livermore National Laboratory have successfully demonstrated this technology in the application of post-combustion carbon capture with sodium and potassium carbonate solutions,4 and have recently shown the feasibility of micro-encapsulation of an AHA IL for carbon capture.5 The large effective surface area and high CO₂ permeability of the micro-capsules is expected to offset the drawback of the high IL viscosity and to provide for a more efficient and cost-effective mass transfer operation involving AHA ILs and PCILs. These opportunities, however, present us with both process and materials design questions. For example, what is the target CO₂ absorption strength (enthalpy of chemical absorption) for the tunable AHA IL? What is the target for micro-capsule diameter in order to obtain a high mass transfer rate and good fluidization performance? What are the appropriate temperatures and pressures for the absorber and stripper? In order to address these and other questions, we have developed a rate-based model of a post-combustion CO₂ capture process using micro-encapsulated ILs. As a performance baseline

Heat release rate from the combustion of uranium

International Nuclear Information System (INIS)

Solbrig, C.W.

1995-01-01

Fuel treatment is planned at the Argonne National Laboratory on EBR-II spent fuel. The electrochemical treatment process is carried out in a cell with an argon atmosphere to prevent any reaction. The amount of fuel processed at any time is limited by the amount of energy which could be released by metal combustion if air is inadvertently allowed into the cell since the heat release would increase the cell pressure. The cell pressure is required to be below atmospheric even if combustion occurs to ensure no cell gas/aerosol is released to the environment. Metal fires can release large amounts of heat. In certain configurations such as fine particulate, metal can be pyrophoric at room temperature. When the metal is a nuclear fuel, it is important to be able to predict the reaction/heat release rate if the metal is inadvertently exposed to air. A realistic combustion model is needed to predict heat release rates for the many different flow and transport configurations which exist in the various fuel processing steps. A model for the combustion of uranium is developed here which compares satisfactorily to experimental data

Development and applications of laser spectroscopic techniques related to combustion diagnostics

International Nuclear Information System (INIS)

Alden, Marcus

2006-01-01

Thanks to features as non-intrusiveness combined with high spatial and temporal resolution, various laser diagnostic techniques have during the last decades become of utmost importance for characterization of combustion related phenomena. In the following presentation some further development of the techniques will be highlighted aiming at a) surface temperatures using Thermographic Phosphors, TP, b) species specific, spatially and temporally resolved detection of species absorbing in the IR spectral region using polarization spectroscopy and Laser-induced fluorescence, and finally c) high speed visualization using a special designed laser system in combination with a framing camera. In terms of surface thermometry, Thermographic Phosphors have been used for many years for temperature measurements on solid surfaces. We have during the last years further developed and applied this technique for temperature measurements on burning surfaces and on materials going through phase shifts, e.g. pyrolysis and droplets. The basic principle behind this technique is to apply micron size particles to the surface of interest. By exciting the TP with a short pulse UV laser (ns), the phosphorescence will exhibit a behaviour where the spectral emission as well as the temporal decay are dependent on the temperature. It is thus possible to measure the temperature both in one and two dimensions. The presentation will include basic description of the technique as well as various applications, e.g in fire science, IC engines and gasturbines. Several of the species of interest for combustion/flow diagnostics exhibit a molecular structure which inhibits the use of conventional laser-induced fluorescence for spatially and spectrally resolved measurements. We have during the last years investigated the use of excitation and detection in the infrared region of the spectrum. Here, it is possible to detect both carbonmono/dioxide, water as well as species specific hydrocarbons. The techniques

Straw combustion on slow-moving grates - a comparison of model predictions with experimental data

Energy Technology Data Exchange (ETDEWEB)

Kaer, S.K. [Aalborg Univ. (Denmark). Inst. of Energy Technology

2005-03-01

Combustion of straw in grate-based boilers is often associated with high emission levels and relatively poor fuel burnout. A numerical grate combustion model was developed to assist in improving the combustion performance of these boilers. The model is based on a one-dimensional ''walking-column'' approach and includes the energy equations for both the fuel and the gas accounting for heat transfer between the two phases. The model gives important insight into the combustion process and provides inlet conditions for a computational fluid dynamics analysis of the freeboard. The model predictions indicate the existence of two distinct combustion modes. Combustion air temperature and mass flow-rate are the two parameters determining the mode. There is a significant difference in reaction rates (ignition velocity) and temperature levels between the two modes. Model predictions were compared to measurements in terms of ignition velocity and temperatures for five different combinations of air mass flow and temperature. In general, the degree of correspondence with the experimental data is favorable. The largest difference between measurements and predictions occurs when the combustion mode changes. The applicability to full-scale is demonstrated by predictions made for an existing straw-fired boiler located in Denmark. (author)

Interactive wood combustion for botanical tree models

KAUST Repository

Pirk, Sören

2017-11-22

We present a novel method for the combustion of botanical tree models. Tree models are represented as connected particles for the branching structure and a polygonal surface mesh for the combustion. Each particle stores biological and physical attributes that drive the kinetic behavior of a plant and the exothermic reaction of the combustion. Coupled with realistic physics for rods, the particles enable dynamic branch motions. We model material properties, such as moisture and charring behavior, and associate them with individual particles. The combustion is efficiently processed in the surface domain of the tree model on a polygonal mesh. A user can dynamically interact with the model by initiating fires and by inducing stress on branches. The flames realistically propagate through the tree model by consuming the available resources. Our method runs at interactive rates and supports multiple tree instances in parallel. We demonstrate the effectiveness of our approach through numerous examples and evaluate its plausibility against the combustion of real wood samples.

Experimental investigation of wood combustion in a fixed bed with hot air

Energy Technology Data Exchange (ETDEWEB)

Markovic, Miladin, E-mail: m.markovic@utwente.nl; Bramer, Eddy A.; Brem, Gerrit

2014-01-15

Highlights: • Upward combustion is a new combustion concept with ignition by hot primary air. • Upward combustion has three stages: short drying, rapid devolatilization and char combustion. • Variation of fuel moisture and inert content have little influence on the combustion. • Experimental comparison between conventional and upward combustion is presented. - Abstract: Waste combustion on a grate with energy recovery is an important pillar of municipal solid waste (MSW) management in the Netherlands. In MSW incinerators fresh waste stacked on a grate enters the combustion chamber, heats up by radiation from the flame above the layer and ignition occurs. Typically, the reaction zone starts at the top of the waste layer and propagates downwards, producing heat for drying and devolatilization of the fresh waste below it until the ignition front reaches the grate. The control of this process is mainly based on empiricism. MSW is a highly inhomogeneous fuel with continuous fluctuating moisture content, heating value and chemical composition. The resulting process fluctuations may cause process control difficulties, fouling and corrosion issues, extra maintenance, and unplanned stops. In the new concept the fuel layer is ignited by means of preheated air (T > 220 °C) from below without any external ignition source. As a result a combustion front will be formed close to the grate and will propagate upwards. That is why this approach is denoted by upward combustion. Experimental research has been carried out in a batch reactor with height of 4.55 m, an inner diameter of 200 mm and a fuel layer height up to 1 m. Due to a high quality two-layer insulation adiabatic conditions can be assumed. The primary air can be preheated up to 350 °C, and the secondary air is distributed via nozzles above the waste layer. During the experiments, temperatures along the height of the reactor, gas composition and total weight decrease are continuously monitored. The influence of

Combustion of Sewage Sludge as Alternative Fuel for Cement Industry

Institute of Scientific and Technical Information of China (English)

LI Fuzhou; ZHANG Wei

2011-01-01

The combustion of sewage sludge and coal was studied by thermogravimetric analysis.Both differential scanning calorimetric analysis and derivative thermogravimetric profiles showed differences between combustion of sewage sludge and coal, and non-isothermal kinetics analysis method was applied to evaluate the combustion process. Based on Coats-Redfem integral method, some reaction models were tested,the mechanism and kinetics of the combustion reaction were discussed. The results show that the combustion of sewage sludge is mainly in the Iow temperature stage, meanwhile the ignition temperature and Arrhenius activation energy are lower than that of coal. The combustion of sewage sludge has the advantage over coal in some aspects, thus sewage sludge can partly replace coal used as cement industry fuel.

Pre-Combustion Carbondioxide Capture in Integrated Gasification Combined Cycles

Directory of Open Access Journals (Sweden)

M. Zeki YILMAZOĞLU

2010-02-01

Full Text Available Thermal power plants have a significant place big proportion in the production of electric energy. Thermal power plants are the systems which converts heat energy to mechanical energy and also mechanical energy to electrical energy. Heat energy is obtained from combustion process and as a result of this, some harmful emissions, like CO2, which are the reason for global warming, are released to atmosphere. The contribution of carbondioxide to global warming has been exposed by the previous researchs. Due to this fact, clean energy technologies are growing rapidly all around the world. Coal is generally used in power plants and when compared to other fossil energy sources unit electricity production cost is less than others. When reserve rate is taken into account, coal may be converted to energy in a more efficient and cleaner way. The aim for using the clean coal technologies are to eradicate the harmful emissions of coal and to store the carbondioxide, orginated from combustion, in different forms. In line with this aim, carbondioxide may be captured by either pre-combustion, by O2/CO2 recycling combustion systems or by post combustion. The integrated gasification combined cycles (IGCC are available in pre-combustion capture systems, whereas in O2/CO2 recycling combustion systems there are ultrasuper critical boiler technologies and finally flue gas washing systems by amines exists in post combustion systems. In this study, a pre-combustion CO2 capture process via oxygen blown gasifiers is compared with a conventional power plant in terms of CO2 emissions. Captured carbondioxide quantity has been presented as a result of the calculations made throughout the study.

Emissions of hydrocarbons from combustion of biofuels

International Nuclear Information System (INIS)

Olsson, Mona; Persson, Eva Marie.

1991-10-01

Evaluations and measurements of emissions of hydrocarbons from power plants with a capacity exceeding 1 MW using biofuels (wood fuels and peat) have been studied in order to identify and quantify the emissions of incompletely combusted hydrocarbons. The influence of the type of fuel and the combustion technology applied were also studied, using literature references. The report summarizes monitoring results from a number of plants using biofuels. The reported emissions from the different plants can not be compared as they are relatively few and the test results have been obtained under various conditions using different methods of testing and analysis. The methods used are often poorly documented in the studied reports. Few investigations of emissions of hydrocarbons from plants in the range of 1 to 10 MW have been carried out. The plant and the technology used are important factors determining the amount and type of emissions of hydrocarbons. Larger temporary emissions can occur during start up, operational disturbances or when using fuel of inhomogeneous quality. In order to minimize the emissions the combustion process must be efficiently controlled, and a fuel of a hohogeneous quality must be used. The report also summarizes sampling and analysis methods used for monitoring emissions of hydrocarbons. (29 refs., 17 figs.)

Use of nitrogen stable isotope analysis to understand char nitrogen evolution during the fluidized-bed co-combustion of coal and sewage sludge

Energy Technology Data Exchange (ETDEWEB)

Ana Arenillas; Roberto Garcia; Chenggong Sun; Colin E. Snape; Angel H. Moreno; Fernando Rubiera; Jose J. Pis [University of Nottingham, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

2005-04-01

NOx emissions from sewage sludge combustion are a concern, because of the usually high nitrogen content of this fuel. The interactions during co-combustion in a fluidized-bed reactor of sewage sludge and a bituminous coal were evaluated, in relation to the nitrogen evolution during the combustion process. The nitrogen stable isotope measurements provide novel results regarding the tracing of nitrogen during combustion. Our preliminary results show that the co-combustion chars retain more nitrogen than expected, with the additional nitrogen being mainly derived from the sludge. Additional measurements are planned on the resultant co-combustion gases, to aid source apportionment of the NOx arising from coal/sewage interactions. 14 refs., 3 figs., 2 tabs.

Developing a zero-CO{sub 2}-emission coal combustion process for power generation; Entwicklung eines CO{sub 2}-emissionsfreien Kohleverbrennungsprozesses zur Stromerzeugung

Energy Technology Data Exchange (ETDEWEB)

Kneer, R.; Abel, D.; Niehuis, R.; Meier, H.R.; Modigell, M.; Peters, N. [RWTH Aachen (Germany)

2005-07-01

Besides measures for efficiency improvements by means of increased steam parameters, research on oxyfuel cycles in the main strategy for reduction of CO{sub 2}-emissions from fossil coal-fired power plants. The largest publicity founded German oxyfuel project is the so-called OXYCOAL-AC project, where 6 institutes from RWTH Aachen University and 5 industrial partners collaborate in the development of a CO{sub 2}-free coal combustion power plant cycle. This will be achieved by sing pure oxygen and recirculated CO{sub 2} for the combustion process. The oxygen is provided by a high temperature ceramic membrane module, which separates oxygen from an air feed flow. The challenges of this project and the related research topics are presented by discussing the main components of the OXYCOAL-AC cycle. While this description of the cycle is based on a 400 MW reference power plant, its realisation at the existing test facility at RWTH Aachen University will also be explained. Finally, an outlook on future activities is presented. (orig.)

Combustion stratification for naphtha from CI combustion to PPC

NARCIS (Netherlands)

Vallinayagam, R.; Vedharaj, S.; An, Y.; Dawood, A.; Izadi Najafabadi, M.; Somers, L.M.T.; Johansson, B.H.

2017-01-01

This study demonstrated the change in combustion homogeneity from conventional diesel combustion via partially premixed combustion towards HCCI. Experiments are performed in an optical diesel engine at a speed of 1200 rpm with diesel fuel. Single injection strategy is employed and the fuel is

A computational study of free-piston diesel engine combustion

Energy Technology Data Exchange (ETDEWEB)

Mikalsen, R.; Roskilly, A.P. [Sir Joseph Swan Institute for Energy Research, Newcastle University, Devonshire Building, Newcastle upon Tyne, NE1 7RU (United Kingdom)

2009-07-15

This paper investigates the in-cylinder gas motion, combustion process and nitrogen oxide formation in a free-piston diesel engine and compares the results to those of a conventional engine, using a computational fluid dynamics engine model. Enhanced radial gas flow (squish and reverse squish) around top dead centre is found for the free-piston engine compared to a conventional engine, however it is found that this has only minor influence on the combustion process. A higher heat release rate from the pre-mixed combustion phase due to an increased ignition delay was found, along with potential reductions in nitrogen oxides emissions formation for the free-piston engine. (author)

Highly time-resolved imaging of combustion and pyrolysis product concentrations in solid fuel combustion: NO formation in a burning cigarette.

Science.gov (United States)

Zimmermann, Ralf; Hertz-Schünemann, Romy; Ehlert, Sven; Liu, Chuan; McAdam, Kevin; Baker, Richard; Streibel, Thorsten

2015-02-03

The highly dynamic, heterogeneous combustion process within a burning cigarette was investigated by a miniaturized extractive sampling probe (microprobe) coupled to photoionization mass spectrometry using soft laser single photon ionization (SPI) for online real-time detection of molecular ions of combustion and pyrolysis products. Research cigarettes smoked by a smoking machine are used as a reproducible model system for solid-state biomass combustion, which up to now is not addressable by current combustion-diagnostic tools. By combining repetitively recorded online measurement sequences from different sampling locations in an imaging approach, highly time- and space-resolved quantitative distribution maps of, e.g., nitrogen monoxide, benzene, and oxygen concentrations were obtained at a near microscopic level. The obtained quantitative distribution maps represent a time-resolved, movie-like imaging of the respective compound's formation and destruction zones in the various combustion and pyrolysis regions of a cigarette during puffing. Furthermore, spatially resolved kinetic data were ascertainable. The here demonstrated methodology can also be applied to various heterogenic combustion/pyrolysis or reaction model systems, such as fossil- or biomass-fuel pellet combustion or to a positional resolved analysis of heterogenic catalytic reactions.

Atmospheric processing of combustion aerosols as a source of soluble iron to the open ocean

OpenAIRE

伊藤, 彰記; ITO, Akinori

2015-01-01

The majority of bioavailable iron (Fe) from the atmosphere is delivered from arid and semiarid regions to the oceans because the global deposition of iron from combustion sources is small compared with that from mineral dust. Atmospheric processing of mineral aerosols by inorganic and organic acids from anthropogenic and natural sources has been shown to increase the iron solubility of soils (initially < 0.5%) up to about 10%. On the other hand, atmospheric observations have shown that iron i...

Combustion instability control in the model of combustion chamber

International Nuclear Information System (INIS)

Akhmadullin, A N; Ahmethanov, E N; Iovleva, O V; Mitrofanov, G A

2013-01-01

An experimental study of the influence of external periodic perturbations on the instability of the combustion chamber in a pulsating combustion. As an external periodic disturbances were used sound waves emitted by the electrodynamics. The purpose of the study was to determine the possibility of using the method of external periodic perturbation to control the combustion instability. The study was conducted on a specially created model of the combustion chamber with a swirl burner in the frequency range from 100 to 1400 Hz. The study found that the method of external periodic perturbations may be used to control combustion instability. Depending on the frequency of the external periodic perturbation is observed as an increase and decrease in the amplitude of the oscillations in the combustion chamber. These effects are due to the mechanisms of synchronous and asynchronous action. External periodic disturbance generated in the path feeding the gaseous fuel, showing the high efficiency of the method of management in terms of energy costs. Power required to initiate periodic disturbances (50 W) is significantly smaller than the thermal capacity of the combustion chamber (100 kW)

Combustibility of tetraphenylborate solids

International Nuclear Information System (INIS)

Walker, D.D.

1989-01-01

Liquid slurries expected under normal in-tank processing (ITP) operations are not ignitible because of their high water content. However, deposits of dry solids from the slurries are combustible and produce dense, black smoke when burned. The dry solids burn similarly to Styrofoam and more easily than sawdust. It is the opinion of fire hazard experts that a benzene vapor deflagration could ignite the dry solids. A tetraphenylborate solids fire will rapidly plug the waste tank HEPA ventilation filters due to the nature of the smoke produced. To prevent ignition and combustion of these solids, the waste tanks have been equipped with a nitrogen inerting system

Combustion and Magnetohydrodynamic Processes in Advanced Pulse Detonation Rocket Engines

Science.gov (United States)

Cole, Lord Kahil

A number of promising alternative rocket propulsion concepts have been developed over the past two decades that take advantage of unsteady combustion waves in order to produce thrust. These concepts include the Pulse Detonation Rocket Engine (PDRE), in which repetitive ignition, propagation, and reflection of detonations and shocks can create a high pressure chamber from which gases may be exhausted in a controlled manner. The Pulse Detonation Rocket Induced Magnetohydrodynamic Ejector (PDRIME) is a modification of the basic PDRE concept, developed by Cambier (1998), which has the potential for performance improvements based on magnetohydrodynamic (MHD) thrust augmentation. The PDRIME has the advantage of both low combustion chamber seeding pressure, per the PDRE concept, and efficient energy distribution in the system, per the rocket-induced MHD ejector (RIME) concept of Cole, et al. (1995). In the initial part of this thesis, we explore flow and performance characteristics of different configurations of the PDRIME, assuming quasi-one-dimensional transient flow and global representations of the effects of MHD phenomena on the gas dynamics. By utilizing high-order accurate solvers, we thus are able to investigate the fundamental physical processes associated with the PDRIME and PDRE concepts and identify potentially promising operating regimes. In the second part of this investigation, the detailed coupling of detonations and electric and magnetic fields are explored. First, a one-dimensional spark-ignited detonation with complex reaction kinetics is fully evaluated and the mechanisms for the different instabilities are analyzed. It is found that complex kinetics in addition to sufficient spatial resolution are required to be able to quantify high frequency as well as low frequency detonation instability modes. Armed with this quantitative understanding, we then examine the interaction of a propagating detonation and the applied MHD, both in one-dimensional and two

Gaseous emissions from sewage sludge combustion in a moving bed combustor.

Science.gov (United States)

Batistella, Luciane; Silva, Valdemar; Suzin, Renato C; Virmond, Elaine; Althoff, Chrtistine A; Moreira, Regina F P M; José, Humberto J

2015-12-01

Substantial increase in sewage sludge generation in recent years requires suitable destination for this residue. This study evaluated the gaseous emissions generated during combustion of an aerobic sewage sludge in a pilot scale moving bed reactor. To utilize the heat generated during combustion, the exhaust gas was applied to the raw sludge drying process. The gaseous emissions were analyzed both after the combustion and drying steps. The results of the sewage sludge characterization showed the energy potential of this residue (LHV equal to 14.5 MJ kg(-1), db) and low concentration of metals, polycyclic aromatic hydrocarbons (PAH), polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF). The concentration of CO, NOx, BTEX (benzene, toluene, ethylbenzene and xylenes) emitted from the sludge combustion process were lower than the legal limits. The overall sludge combustion and drying process showed low emissions of PCDD/PCDF (0.42 ng I-TEQ N m(-3)). BTEX and PAH emissions were not detected. Even with the high nitrogen concentration in the raw feed (5.88% db), the sludge combustion process presented NOx emissions below the legal limit, which results from the combination of appropriate feed rate (A/F ratio), excess air, and mainly the low temperature kept inside the combustion chamber. It was found that the level of CO emissions from the overall sludge process depends on the dryer operating conditions, such as the oxygen content and the drying temperature, which have to be controlled throughout the process in order to achieve low CO levels. The aerobic sewage sludge combustion process generated high SO2 concentration due to the high sulfur content (0.67 wt%, db) and low calcium concentration (22.99 g kg(-1)) found in the sludge. The high concentration of SO2 in the flue gas (4776.77 mg N m(-3)) is the main factor inhibiting PCDD/PCDF formation. Further changes are needed in the pilot plant scheme to reduce SO2 and particulate matter emissions

Catalytic Unmixed Combustion of Coal with Zero Pollution

Energy Technology Data Exchange (ETDEWEB)

George Rizeq; Parag Kulkarni; Raul Subia; Wei Wei

2005-12-01

GE Global Research is developing an innovative energy-based technology for coal combustion with high efficiency and near-zero pollution. This Unmixed Combustion of coal (UMC-Coal) technology simultaneously converts coal, steam and air into two separate streams of high pressure CO{sub 2}-rich gas for sequestration, and high-temperature, high-pressure vitiated air for producing electricity in gas turbine expanders. The UMC process utilizes an oxygen transfer material (OTM) and eliminates the need for an air separation unit (ASU) and a CO{sub 2} separation unit as compared to conventional gasification based processes. This is the final report for the two-year DOE-funded program (DE-FC26-03NT41842) on this technology that ended in September 30, 2005. The UMC technology development program encompassed lab- and pilot-scale studies to demonstrate the UMC concept. The chemical feasibility of the individual UMC steps was established via lab-scale testing. A pilot plant, designed in a related DOE funded program (DE-FC26-00FT40974), was reconstructed and operated to demonstrate the chemistry of UMC process in a pilot-scale system. The risks associated with this promising technology including cost, lifetime and durability OTM and the impact of contaminants on turbine performance are currently being addressed in detail in a related ongoing DOE funded program (DE-FC26-00FT40974, Phase II). Results obtained to date suggest that this technology has the potential to economically meet future efficiency and environmental performance goals.

Combustion in fluidized bed reactors; Verbrennung in Wirbelschichtreaktoren

Energy Technology Data Exchange (ETDEWEB)

Thome-Kozmiensky, Karl J. [vivis CONSULT GmbH, Nietwerder (Germany)

2013-03-01

Since the first application for the coal gasification, the fluidized bed technology has passed an impressive development. Nowadays, the fluidized bed technology is utilized at chemical processes, drying and cooling, gasification, combustion and purification of exhaust gas. In the firing technology, the fluidized technology initially has been proved in the combustion of very high ash coal and sewage sludge. Recently, the fluidized bed technology also is applied in the drying of sewage sludge, combustion of domestic waste - as in Japan and Sweden - as well as in the gasification and combustion of substitute fuels, biomass - wood pellets, wood chips, straw, cocoa shells and so forth - and residues from the paper manufacturing - such as in Germany and Austria. Under this aspect, the author of the contribution under consideration reports on the combustion of sewage sludge, substitute fuels and biomass.

Homogeneous Charge Compression Ignition Combustion of Dimethyl Ether

DEFF Research Database (Denmark)

Pedersen, Troels Dyhr

This thesis is based on experimental and numerical studies on the use of dimethyl ether (DME) in the homogeneous charge compression ignition (HCCI) combustion process. The first paper in this thesis was published in 2007 and describes HCCI combustion of pure DME in a small diesel engine. The tests...... were designed to investigate the effect of engine speed, compression ratio and equivalence ratio on the combustion timing and the engine performance. It was found that the required compression ratio depended on the equivalence ratio used. A lower equivalence ratio requires a higher compression ratio...... before the fuel is burned completely, due to lower in-cylinder temperatures and lower reaction rates. The study provided some insight in the importance of operating at the correct compression ratio, as well as the operational limitations and emission characteristics of HCCI combustion. HCCI combustion...

Theoretical study of the combustion de pellets of biomass coming from the sugar cane

International Nuclear Information System (INIS)

Verdecia Torres, David; Macías Socarrás, Idalberto; Gaskins Espinosa, Benjamín Gabriel

2012-01-01

In the follow work they are an a examinations of the kinetic quimestry of the combustions process, we obtain the combustions time in functions of the kinetic combustions model and we made a experiment design for determinations of the theory's mathematics models in that process. (author)

A Preliminary Study on Rock Bed Heat Storage from Biomass Combustion for Rice Drying

Science.gov (United States)

Nelwan, L. O.; Wulandani, D.; Subrata, I. D. M.

2018-05-01

One of the main constraints of biomass fuel utilization in a small scale rice drying system is the operating difficulties related to the adjustment of combustion/feeding rate. Use of thermal storage may reduce the problem since combustion operation can be accomplished in a much shorter time and then the use of heat can be regulated by simply adjusting the air flow. An integrated biomass furnace-rock bed thermal storage with a storage volume of 540 L was designed and tested. There were four experiments conducted in this study. Charging was performed within 1-2 hours with a combustion rate of 11.5-15.5 kg/h. In discharging process, the mixing of air passing through the rock bed and ambient air were regulated by valves. Without adjusting the valve during the discharging process, air temperature increased up to 80°C, which is not suitable for rice batch drying process. Charging with sufficiently high combustion rate (14 kg/h) within 1 hour continued by adjusting the valve during discharging process below 60°C increased the discharge-charge time ratio (DCTR) up to 5.33 at average air temperature of 49°C and ambient temperature of 33°C.The efficiency of heat discharging was ranged from 34.5 to 45.8%. From the simulation, as much as 156.8-268.8 kg of rice was able to be dried by the discharging conditions.

Comparative sinterability of combustion synthesized and commercial titanium carbides

International Nuclear Information System (INIS)

Manley, B.W.

1984-11-01

The influence of various parameters on the sinterability of combustion synthesized titanium carbide was investigaged. Titanium carbide powders, prepared by the combustion synthesis process, were sintered in the temperature range 1150 to 1600 0 C. Incomplete combustion and high oxygen contents were found to be the cause of reduced shrinkage during sintering of the combustion syntheized powders when compared to the shrinkage of commercial TiC. Free carbon was shown to inhibit shrinkage. The activation energy for sintering was found to depend on stoichiometry (C/Ti). With decreasing C/Ti, the rate of sintering increased. 29 references, 16 figures, 13 tables

Study on the Combustion Process and Emissions of a Turbocharged Diesel Engine with EGR

Directory of Open Access Journals (Sweden)

Mei Deqing

2012-01-01

Full Text Available A high pressure EGR system was adopted to a turbocharged inter-cooled diesel engine, to analyze its combustion and emission characteristics under the condition of different loads and constant speed. Under the same steady operating mode, with the increase of EGR rate, the temperature of compressed gas ascended, the ignition delay was shortened, the pressure and temperature of the burned gas descended, and the combustion process was prolonged. According to the experimental data, it was found that, at the same EGR rate, lower the load of engine was, lower the temperature in cylinder, and higher the increase rate of CO was. However, the increase rate of HC present a falling trend. The decrease rate of the specific emission of NOx linearly varied with EGR rate with a slope of 1.651. The increase rate of smoke opacity behaved a second-order polynomial uprising trend, and the higher the load was, the sharpener the smoke opacity deteriorated, with the increase of EGR rate. From the point of emission view, the engine with EGR system can achieve the lesser exhaust emissions in some operations by adjusting the engine parameters.

Fluidized bed combustion: mixing and pollutant limitation

Energy Technology Data Exchange (ETDEWEB)

Leckner, B. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Energy Conversion

1997-10-01

Fluidized bed combustion (FBC) has been applied commercially during a few decades, and sufficient knowledge is gained to design boilers with sizes of up to several hundreds of megawatt thermal power (MW{sub th}). The knowledge of what goes on inside a large combustion chamber is still limited, however, and this impedes further optimization and efficient solution of problems that might occur. Despite this lack of knowledge the present survey deals with combustion chamber processes and discusses mixing and distribution of fuel and air in the combustion chamber and its importance for sulphur capture and reduction of emissions of nitrogen oxides. It is desirable to present the material in a general way and to cover the entire field of FBC. However, the scarce openly published information deals mostly with coal combustion in atmospheric circulating fluidized bed (CFB) combustors, and therefore this application will receive most attention, but reference is also made to pressurized combustion and to other fuels than coal. In this context the important work made in the LIEKKI project on the analysis of different fuels and on the influence of pressure should be especially pointed out. (orig.)

Low emission turbulent technology for fuel combustion

International Nuclear Information System (INIS)

Finker, F. Z.; Kubyshkin, I. B.; Zakharov, B. Yu.; Akhmedov, D. B.; Sobchuk, Ch.

1997-01-01

The company 'POLITEKHENERGO' in co-operation and the Russian-Poland firm 'EnergoVIR' have performed investigations for modernization of the current existing boilers. A low emission turbulent technology has been used for the modernization of 10 industrial boilers. The reduction of NO x emissions is based on the following processes: 1) multistage combustion assured by two counter-deviated fluxes; 2) Some of the combustion facilities have an abrupt slope and a reduced air supply which leads to an intense separation of the fuel in the bottom part and a creation of a low-temperature combustion zone where the active restoration of the NO x takes part; 3) The influence of the top high-temperature zone on the NO x formation is small. Thus the 'sandwich' consisting of 'cold' and'hot' combustion layers provides a full rate combustion. This technique permits to: decrease of the NO x and CO x down to the European standard values;increase of the efficiency in 1-2%; obtain a stable coal combustion up to 97-98%; assure the large loading range (30 -100%); modernize and use the old boilers

Relation of Hydrogen and Methane to Carbon Monoxide in Exhaust Gases from Internal-Combustion Engines

Science.gov (United States)

Gerrish, Harold C; Tessmann, Arthur M

1935-01-01

The relation of hydrogen and methane to carbon monoxide in the exhaust gases from internal-combustion engines operating on standard-grade aviation gasoline, fighting-grade aviation gasoline, hydrogenated safety fuel, laboratory diesel fuel, and auto diesel fuel was determined by analysis of the exhaust gases. Two liquid-cooled single-cylinder spark-ignition, one 9-cylinder radial air-cooled spark-ignition, and two liquid-cooled single-cylinder compression-ignition engines were used.

Rotary combustion device

NARCIS (Netherlands)

2008-01-01

Rotary combustion device (1) with rotary combustion chamber (4). Specific measures are taken to provide ignition of a combustible mixture. It is proposed that a hollow tube be provided coaxially with the axis of rotation (6), so that a small part of the mixture is guided into the combustion chamber.

Numerical simulations of industrial processes involving fluid dynamics, combustion and radiation

Energy Technology Data Exchange (ETDEWEB)

Ducrocq, J [Air Liquide, Centre de Recherche Claude-Delorme, Jouy-en-Josas (France)

1998-12-31

Moving out of the scientific community research laboratories, computational fluid dynamics (CFD) software packages are now allowing industrials to analyse and optimize industrial processes involving the use of gases, liquids and even some two-phase fluids. Their attractiveness and their impact stems out from the opportunity they offer to bring insight into an existing unit, or even at the design stage, by displaying the spatial distribution of process relevant variables such as temperature, concentration. The filling of the spacing in between a two-layer window is a simple example. This new opportunity of visualisation is at times an unique way, when the process environment is an opaque one, such as liquid metal flowing into a tundish or when measurements of flows may be a long and tedious work, such as flows within water treatment basins. This environment we are to investigate in order to optimize can also be a harsh one, due to its high temperature level for example. Such are burners. But then pure fluid flow analysis, such as cold flow water models, has too many shortcomings. The description of combustion processes and of radiation become a necessary feature in order to describe thermal heat transfer or to locate `hot spots`. Such numerical models showing our oxycombustion expertise in glass melting will be presented. (author)

Numerical simulations of industrial processes involving fluid dynamics, combustion and radiation

Energy Technology Data Exchange (ETDEWEB)

Ducrocq, J. [Air Liquide, Centre de Recherche Claude-Delorme, Jouy-en-Josas (France)

1997-12-31

Moving out of the scientific community research laboratories, computational fluid dynamics (CFD) software packages are now allowing industrials to analyse and optimize industrial processes involving the use of gases, liquids and even some two-phase fluids. Their attractiveness and their impact stems out from the opportunity they offer to bring insight into an existing unit, or even at the design stage, by displaying the spatial distribution of process relevant variables such as temperature, concentration. The filling of the spacing in between a two-layer window is a simple example. This new opportunity of visualisation is at times an unique way, when the process environment is an opaque one, such as liquid metal flowing into a tundish or when measurements of flows may be a long and tedious work, such as flows within water treatment basins. This environment we are to investigate in order to optimize can also be a harsh one, due to its high temperature level for example. Such are burners. But then pure fluid flow analysis, such as cold flow water models, has too many shortcomings. The description of combustion processes and of radiation become a necessary feature in order to describe thermal heat transfer or to locate `hot spots`. Such numerical models showing our oxycombustion expertise in glass melting will be presented. (author)

Study of electrophysical processes during spontaneous combustion of gases and vapors of organic substances

Energy Technology Data Exchange (ETDEWEB)

Fialkov, B.S.; Shebeko, Yu.N.; Muravlev, V.K.; Il' in, A.B.

Combustion of organic substances is accompanied by non-equilibrium ionization, the greatest degree of ionization being in the high temperature zone of the flame, although notable concentrations of ions have been observed in the earlier, low temperature stages of combustion. Since this phenomenon has been studied for only a small number of compounds, a study was undertaken of the electrophysical phenomena taking place during spontaneous combustion of a large variety of compounds, viz., ethanol, acetone, benzene, diethylamine, pentane, diethyl ether, A-72 gasoline, dibromotetrafluoroethane, dichloromethane, and three mixtures of ethanol with 1,2-dibromotetrafluoroethane. Relationships of temperature to passive sonde potential and conductivity current during the induction period were determined. The effective activation energy for the conductivity current-temperature relationship was found to be 230 kilojoules per mole, which agrees with that determined for the induction period in the spontaneous combustion of acetylene-air mixtures in shock waves. 14 references, 3 figures.

Recovery of 238PuO2 by Molten Salt Oxidation Processing of 238PuO2 Contaminated Combustibles (Part II)

Science.gov (United States)

Remerowski, Mary Lynn; Dozhier, C.; Krenek, K.; VanPelt, C. E.; Reimus, M. A.; Spengler, D.; Matonic, J.; Garcia, L.; Rios, E.; Sandoval, F.; Herman, D.; Hart, R.; Ewing, B.; Lovato, M.; Romero, J. P.

2005-02-01

Pu-238 heat sources are used to fuel radioisotope thermoelectric generators (RTG) used in space missions. The demand for this fuel is increasing, yet there are currently no domestic sources of this material. Much of the fuel is material reprocessed from other sources. One rich source of Pu-238 residual material is that from contaminated combustible materials, such as cheesecloth, ion exchange resins and plastics. From both waste minimization and production efficiency standpoints, the best solution is to recover this material. One way to accomplish separation of the organic component from these residues is a flameless oxidation process using molten salt as the matrix for the breakdown of the organic to carbon dioxide and water. The plutonium is retained in the salt, and can be recovered by dissolution of the carbonate salt in an aqueous solution, leaving the insoluble oxide behind. Further aqueous scrap recovery processing is used to purify the plutonium oxide. Recovery of the plutonium from contaminated combustibles achieves two important goals. First, it increases the inventory of Pu-238 available for heat source fabrication. Second, it is a significant waste minimization process. Because of its thermal activity (0.567 W per gram), combustibles must be packaged for disposition with much lower amounts of Pu-238 per drum than other waste types. Specifically, cheesecloth residues in the form of pyrolyzed ash (for stabilization) are being stored for eventual recovery of the plutonium.

Recovery of 238PuO2 by Molten Salt Oxidation Processing of 238PuO2 Contaminated Combustibles (Part II)

International Nuclear Information System (INIS)

Remerowski, Mary Lynn; Dozhier, C.; Krenek, K.; VanPelt, C. E.; Reimus, M. A.; Spengler, D.; Matonic, J.; Garcia, L.; Rios, E.; Sandoval, F.; Herman, D.; Hart, R.; Ewing, B.; Lovato, M.; Romero, J. P.

2005-01-01

Pu-238 heat sources are used to fuel radioisotope thermoelectric generators (RTG) used in space missions. The demand for this fuel is increasing, yet there are currently no domestic sources of this material. Much of the fuel is material reprocessed from other sources. One rich source of Pu-238 residual material is that from contaminated combustible materials, such as cheesecloth, ion exchange resins and plastics. From both waste minimization and production efficiency standpoints, the best solution is to recover this material. One way to accomplish separation of the organic component from these residues is a flameless oxidation process using molten salt as the matrix for the breakdown of the organic to carbon dioxide and water. The plutonium is retained in the salt, and can be recovered by dissolution of the carbonate salt in an aqueous solution, leaving the insoluble oxide behind. Further aqueous scrap recovery processing is used to purify the plutonium oxide. Recovery of the plutonium from contaminated combustibles achieves two important goals. First, it increases the inventory of Pu-238 available for heat source fabrication. Second, it is a significant waste minimization process. Because of its thermal activity (0.567 W per gram), combustibles must be packaged for disposition with much lower amounts of Pu-238 per drum than other waste types. Specifically, cheesecloth residues in the form of pyrolyzed ash (for stabilization) are being stored for eventual recovery of the plutonium

Development and test of combustion chamber for Stirling engine heated by natural gas

Science.gov (United States)

Li, Tie; Song, Xiange; Gui, Xiaohong; Tang, Dawei; Li, Zhigang; Cao, Wenyu

2014-04-01

The combustion chamber is an important component for the Stirling engine heated by natural gas. In the paper, we develop a combustion chamber for the Stirling engine which aims to generate 3˜5 kWe electric power. The combustion chamber includes three main components: combustion module, heat exchange cavity and thermal head. Its feature is that the structure can divide "combustion" process and "heat transfer" process into two apparent individual steps and make them happen one by one. Since natural gas can mix with air fully before burning, the combustion process can be easily completed without the second wind. The flame can avoid contacting the thermal head of Stirling engine, and the temperature fields can be easily controlled. The designed combustion chamber is manufactured and its performance is tested by an experiment which includes two steps. The experimental result of the first step proves that the mixture of air and natural gas can be easily ignited and the flame burns stably. In the second step of experiment, the combustion heat flux can reach 20 kW, and the energy utilization efficiency of thermal head has exceeded 0.5. These test results show that the thermal performance of combustion chamber has reached the design goal. The designed combustion chamber can be applied to a real Stirling engine heated by natural gas which is to generate 3˜5 kWe electric power.

Internal and surface phenomena in metal combustion

Science.gov (United States)

Dreizin, Edward L.; Molodetsky, Irina E.; Law, Chung K.

1995-01-01

liquid fuel droplet combustion studies. In addition, the internal compositions of rapidly quenched metal particles will be analyzed using SEM technique. Such compositions are similar to those existing during the combustion and provide new insight on metal combustion processes. The results of this experimental work will be used to model the fundamental mechanisms of metal combustion. Preliminary experimental results on Al and Zr particle combustion at normal gravity are discussed here.

State of art in incineration technology of radioactive combustible solid wastes

International Nuclear Information System (INIS)

Karita, Yoichi

1984-01-01

The features of incineration treatment as the method of treating radioactive wastes are the effect of volume reduction and inorganic stabilization (change to ash). The process of incineration treatment is roughly divided into dry process and wet process. But that in practical use is dry incineration by excess air combustion or suppressed combustion. The important things in incineration techniques are the techniques of exhaust gas treatment as well as combustion techniques. In Europe and USA, incineration has been practiced in laboratories and reprocessing plants for low level combustible solids, but the example of application in nuclear power stations is few. In Japan, though the fundamental techniques are based on the introduction from Europe, the incineration treatment of combustible solids has been carried out in laboratories, reprocessing plants, nuclear fuel production facilities and also nuclear power stations. The techniques of solidifying ash by incineration and the techniques of incinerating spent ion exchange resin are actively developed, and the development of the treatment of radioactive wastes in the lump including incineration also is in progress. (Kako, I.)

Influence of forest biomass grown in fertilised soils on combustion and gasification processes as well as on the environment with integrated bioenergy production

Energy Technology Data Exchange (ETDEWEB)

Jaanu, K; Orjala, M [VTT Energy, Jyvaeskylae (Finland). Fuel Production

1997-12-01

This presentation describes research carried out by VTT Energy and METLA during 1996, as part of the collaborative EU project involving Finland, Portugal and Spain. The main objectives of this project are to carry out experimental studies of both combustion and gasification under atmospheric (Portugal and Spain) and pressurised conditions (Finland) using biomass from different countries, namely Finland, Portugal and Spain. This was to determine the influence of biomass fertilising conditions on the process itself and the impact on the integrated energy production facilities, such as gas turbines. The aim of the research was carried out during 1996: (1) To complete the biomass collection, analyses and selection of the samples for combustion and gasification tests. This task has been carried out in co-operation with VTT and METLA, (2) To start the combustion and gasification tests under pressurised and atmospheric conditions. The combustion research in Finland is being performed in pressurised entrained flow reactor at VTT in Jyvaeskylae and the gasification research is being conducted at VTT in Espoo. The collection of biomass samples has been completed. The analyses of the samples show that for instance potassium and phosphorus content will be increased by about 30-50 % due to fertilisation. In the ash fusion tests, the ash from fertilised bark and branches and needles may start to soften already at 900 deg C under reducing conditions depending on the composition of the ash. In oxidising atmospheres the ash softening seems to occur at higher temperatures. Preliminary results indicate that the fertilisation may have an influence on the combustion process

Combustion physics

Science.gov (United States)

Jones, A. R.

1985-11-01

Over 90% of our energy comes from combustion. By the year 2000 the figure will still be 80%, even allowing for nuclear and alternative energy sources. There are many familiar examples of combustion use, both domestic and industrial. These range from the Bunsen burner to large flares, from small combustion chambers, such as those in car engines, to industrial furnaces for steel manufacture or the generation of megawatts of electricity. There are also fires and explosions. The bountiful energy release from combustion, however, brings its problems, prominent among which are diminishing fuel resources and pollution. Combustion science is directed towards finding ways of improving efficiency and reducing pollution. One may ask, since combustion is a chemical reaction, why physics is involved: the answer is in three parts. First, chemicals cannot react unless they come together. In most flames the fuel and air are initially separate. The chemical reaction in the gas phase is very fast compared with the rate of mixing. Thus, once the fuel and air are mixed the reaction can be considered to occur instantaneously and fluid mechanics limits the rate of burning. Secondly, thermodynamics and heat transfer determine the thermal properties of the combustion products. Heat transfer also plays a role by preheating the reactants and is essential to extracting useful work. Fluid mechanics is relevant if work is to be performed directly, as in a turbine. Finally, physical methods, including electric probes, acoustics, optics, spectroscopy and pyrometry, are used to examine flames. The article is concerned mainly with how physics is used to improve the efficiency of combustion.