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Sample records for coke plant workers

  1. A complex approach to the health states of pitch coking plant workers

    Energy Technology Data Exchange (ETDEWEB)

    Kandus, J.

    1976-01-01

    206 workers of three pitch coking plants, who had been exposed for an average of 4 years to fumes containing 3,4 benzopyrene, were examined. No occupational carcinoma or precancerous foci were detected. The only statistically significant findings were chronic atrophic inflammations of upper respiratory pathways (26%). This investigation is the initial stage in a long-term study of this group of workers. A plan for preventive examinations (including specialized ones), contraindications applicable for this type of job, methods for epidemiological investigations and the follow-up of workers after leaving this work, are described in detail.

  2. Cancer mortality among coke oven workers.

    OpenAIRE

    Redmond, C K

    1983-01-01

    The OSHA standard for coke oven emissions, which went into effect in January 1977, sets a permissible exposure limit to coke oven emissions of 150 micrograms/m3 benzene-soluble fraction of total particulate matter (BSFTPM). Review of the epidemiologic evidence for the standard indicates an excess relative risk for lung cancer as high as 16-fold in topside coke oven workers with 15 years of exposure or more. There is also evidence for a consistent dose-response relationship in lung cancer mort...

  3. Assessment of PAH-exposure among coke oven workers

    Energy Technology Data Exchange (ETDEWEB)

    Vahakangas, K. [and others] [Oulu University, Oulu (Finland)

    1992-12-31

    Levels of BaP diol epoxide - DNA adducts in urine and blood were monitored for workers at the Raahe coking plant, Finland, and other relevant information was collected. All adduct values were low, but oven battery workers had slightly higher values than matched controls. Antibodies to these adducts increased somewhat after work at the plant started, no differences between smokers and non-smokers were found.

  4. Design and construction of coke battery 1A at Radlin coke plant, Poland

    Energy Technology Data Exchange (ETDEWEB)

    A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos' kova; N.I. Shkol' naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

  5. Priorities in the design of chemical shops at coke plants

    Energy Technology Data Exchange (ETDEWEB)

    V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

  6. Physical fitness examination in a selected group of the North-Moravian industrial population. I: Results in coke plant workers

    Energy Technology Data Exchange (ETDEWEB)

    Jirac, Z

    1974-01-01

    Basic spirographic and spiroergometric examinations, according to Hollman, were performed on 269 men, aged 20-60 years, who had been working at coke-oven batteries for 1, 16 and more years. There were no significant differences in the spirographic and spiroergometric indicators of cardiopulmonary efficiency in relation to the length of exposure within the age groups. Maximum oxygen uptake in younger men (20-29 years) was identical, in older age groups it was below average according to Hollmann. This phenomenon can be explained by a combined effect of a low physical load and the heat load on the cardiovascular system. Values were compared with those of Shepard. The working and sanitary conditions and investigation methods are described in detail.

  7. Ways of improving preparatory stage and reconstruction of coking plants

    Energy Technology Data Exchange (ETDEWEB)

    Rozenfel' d, M.S.; Martynenko, V.M.; Svyatogorov, A.A.; Kvitkin, I.A.; Zhurba, A.I.; Gurtovnik, P.F.

    1987-06-01

    Discusses economic and technological aspects of coking plant reconstruction and modernization in the USSR. Effects of standardized technologies on plant reconstruction are analyzed. A standardized planning procedure jointly developed by research institutes in the USSR for plant modernization or reconstruction is discussed: selecting the optimum reconstruction and repair time, sequence of operations without stoppage of a coke oven battery, coke oven cooling, repair of coke oven liners, heating systems, coke oven equipment, drying, initial heating, testing battery equipment. The procedure is aimed at reducing coke losses and eliminating delays during reconstruction operations. A graphic method for modelling plant reconstruction is discussed.

  8. Water protection in coke-plant design

    Energy Technology Data Exchange (ETDEWEB)

    G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

  9. Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant

    Energy Technology Data Exchange (ETDEWEB)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

  10. Japanese coke plant follows US lead

    Energy Technology Data Exchange (ETDEWEB)

    1980-06-01

    Nippon Steel has acquired the first licence for a US Steel/Firma Carl Still process for cleaning coke oven flushing liquor. The process is installed at 3 US Steel preheated coal batteries and is now being used at Nippon Steel's Muroran works. The process is important to the re-use of the water for quenching and is a vital first step in making the liquor harmless to the environment. It is particularly useful in plants using preheated coal where there is likely to be carry over of fine coal particles.

  11. Urinary 1-hydroxypyrene concentrations in Chinese coke oven workers relative to job category, respirator usage, and cigarette smoking

    Energy Technology Data Exchange (ETDEWEB)

    Bo Chen; Yunping Hu; Lixing Zheng; Qiangyi Wang; Yuanfen Zhou; Taiyi Jin [Fudan University, Shanghai (China). School of Public Health

    2007-09-15

    1-Hydroxypyrene (1-OHP) is a biomarker of recent exposure to polycyclic aromatic hydrocarbons (PAHs). We investigated whether urinary 1-OHP concentrations in Chinese coke oven workers (COWs) are modulated by job category, respirator usage, and cigarette smoking. The present cross-sectional study measured urinary 1-OHP concentrations in 197 COWs from Coking plant I and 250 COWs from Coking plant II, as well as 220 unexposed referents from Control plant I and 56 referents from Control plant II. Urinary 1-OHP concentrations (geometric mean, {mu}mol/mol creatinine) were 5.18 and 4.21 in workers from Coking plants I and II, respectively. The highest 1-OHP levels in urine were found among topside workers including lidmen, tar chasers, and whistlers. Benchmen had higher 1-OHP levels than other workers at the sideoven. Above 75% of the COWs exceeded the recommended occupational exposure limit of 2.3 {mu}mol/mol creatinine. Respirator usage and increased body mass index (BMI) slightly reduced 1-OHP levels in COWs. Cigarette smoking significantly increased urinary 1-OHP levels in unexposed referents but had no effect in COWs. Chinese COWs, especially topside workers and benchmen, are exposed to high levels of PAHs. Urinary 1-OHP concentrations appear to be modulated by respirator usage and BMI in COWs, as well as by smoking in unexposed referents.

  12. Coke

    Energy Technology Data Exchange (ETDEWEB)

    Trumble, M J

    1925-07-02

    Coke is obtained from coal, lignite, peat, or wood by heating the material in a retort and distilling off the volatiles by the passage of superheated steam or hot vapors, the hot porous residue being treated with a liquid hydrocarbon and the temperature being so maintained the latter is cracked and carbon deposited on the coke. The vapors or light oils are condensed and the incondensable gases are used as fuel.

  13. Remediation and demolition of coke by-products plants

    Energy Technology Data Exchange (ETDEWEB)

    Stiffler, M A; Gould, W C

    1992-08-01

    The programme undertaken by ICF Kaiser Engineers and LTV Steel Co. to clean up and demolish four closed coking plants is described, including PCB removal, asbestos abatement, pipe removal and cleaning, tank cleaning, demolition and soil bioremediation. Costs are discussed.

  14. Influence of rubber granulate in the coal blend on important process parameters of the coking plant

    Energy Technology Data Exchange (ETDEWEB)

    A. Winter; K. Pilz; A. Gahleitner; G. Woisetschlaeger; Monika Friedl [Voestalpine Stahl GmbH (Germany)

    2004-07-01

    The talk is outlined in a series of 14 slides/overheads. It discusses the use of scrapped tires in coking plant and traces the amount of zinc present in every product of the coking plant, blast furnaces and sintering plant - coke, coke breeze, sinter and waste water produced.

  15. Optimization of the coke-oven activated sludge plants

    Energy Technology Data Exchange (ETDEWEB)

    Raizer Neto, Ernesto [Santa Catarina Univ., Florianopolis, SC (Brazil); Colin, Francois [Institut de Recherches Hydrologiques, 54 - Nancy (France); Prost, Christian [Laboratoire de Sciences de Genie Chimique, Nancy (France)

    1993-12-31

    In the coke-oven activated sludge plants one of the greatest problems of malfunction is due to inffluent variability. The composition and, or, concentration variations of the inffluent substrate, which can cause an unstable system, are function of the pollutant load. Nevertheless, the knowledge of the kinetic biodegradation of the coke-oven effluent represents the limiting factor to develop an effective biological treatment. This work describes a computational model of the biological treatment which was elaborated and validated from continuous pilot scale experiments and calibrated by comparing its predictions to the pilot experiment`s results. 12 refs., 9 figs., 3 tabs.

  16. Optimization of the coke-oven activated sludge plants

    Energy Technology Data Exchange (ETDEWEB)

    Raizer Neto, Ernesto [Santa Catarina Univ., Florianopolis, SC (Brazil); Colin, Francois [Institut de Recherches Hydrologiques, 54 - Nancy (France); Prost, Christian [Laboratoire de Sciences de Genie Chimique, Nancy (France)

    1994-12-31

    In the coke-oven activated sludge plants one of the greatest problems of malfunction is due to inffluent variability. The composition and, or, concentration variations of the inffluent substrate, which can cause an unstable system, are function of the pollutant load. Nevertheless, the knowledge of the kinetic biodegradation of the coke-oven effluent represents the limiting factor to develop an effective biological treatment. This work describes a computational model of the biological treatment which was elaborated and validated from continuous pilot scale experiments and calibrated by comparing its predictions to the pilot experiment`s results. 12 refs., 9 figs., 3 tabs.

  17. Urine mutagenicity of steel workers exposed to coke oven emissions

    Energy Technology Data Exchange (ETDEWEB)

    De Meo, M.P.; Dumenil, G.; Botta, A.H.; Laget, M.; Zabaloueff, V.; Mathias, A.

    1987-03-01

    Urine mutagenicity of 19 individuals was investigated at a steel mill. All the subjects worked on the coal processing unit. Urine samples were collected at the end of a working day. Urine samples of two exposed workers were collected at the end of two periods of rest and two periods of working. Mutagens were extracted on XAD-2 resin and tested by the Salmonella microsomal assay and the SOS spot test. Mutagenic potencies of exposed smokers and exposed non-smokers were 8.62 +/- 6.56 and 1.1 +/- 0.48 revertants/mg creatinine respectively with Salmonella typhimurium strain TA98 + S9. Both values were significantly higher than those of unexposed smokers and non-smokers (5.07 +/- 3.33 and 0.47 +/- 0.72 revertants/mg creatinine respectively). The urinary mutagenic potency of the two exposed individuals increased at the end of periods of working (15.97 +/- 2.57 revertants/mg creatinine) and decreased at the end of periods of rest (12.31 +/- 2.45 revertants/mg creatinine). Urinary mutagens were detected with S. typhimurium strain TA100 + S9 to a lesser extent. No direct-acting mutagens were detected by the SOS spot test. Atmospheric benzo(a)pyrene (BaP) were also measured by h.p.l.c. on the coke battery. BaP concentrations ranged between 0.01 and 0.6 microgram/m3 air at the different working sites. Biological monitoring with short-term tests is discussed.

  18. Complete physico-chemical treatment for coke plant effluents.

    Science.gov (United States)

    Ghose, M K

    2002-03-01

    Naturally found coal is converted to coke which is suitable for metallurgical industries. Large quantities of liquid effluents produced contain a large amount of suspended solids, high COD, BOD, phenols, ammonia and other toxic substances which are causing serious pollution problem in the receiving water to which they are discharged. There are a large number of coke plants in the vicinity of Jharia Coal Field (JCF). Characteristics of the effluents have been evaluated. The present effluent treatment systems were found to be inadequate. Physico-chemical treatment has been considered as a suitable option for the treatment of coke plant effluents. Ammonia removal by synthetic zeolite, activated carbon for the removal of bacteria, viruses, refractory organics, etc. were utilized and the results are discussed. A scheme has been proposed for the complete physico-chemical treatment, which can be suitably adopted for the recycling, reuse and safe disposal of the treated effluent. Various unit process and unit operations involved in the treatment system have been discussed. The process may be useful on industrial scale at various sites.

  19. Urgent reconstruction and re-equipping of coking plants

    Energy Technology Data Exchange (ETDEWEB)

    Kvitkin, I.A.; Martynenko, V.M.; Rozenfel' d, M.S.; Svyatogorov, A.A.; Shvartsman, I.G.

    1986-03-01

    This paper discusses the various options involved: complete or partial reconstruction of existing buildings and equipment or new construction with new equipment and new underground and surface communications. It explains that reconstruction work is divided into three phases: initial phase (clearance, dismantling, closing down coking batteries); basic phase (fitting heat-resistant materials, prestart-up assembly work); final phase (drying out, heating up, adjustments, start-up). A structured scheme for a typical initial phase is described and a method of calculating the durations of the various phases is discussed. Conclusion is that there is an urgent requirement for a document to be produced for the control of reconstruction work; it should contain standard durations and could serve as a standard for coking plant reconstruction work.

  20. Raising lump coke formation capacity of semicoking briquets in the Deuben briquetting plant

    Energy Technology Data Exchange (ETDEWEB)

    Naundorf, W.; Trommer, D.; Schroeder, H.-W.; Dressler, H.

    1988-01-01

    Describes brown coal briquetting and coking experiments aimed at producing high quality lumpy coke suitable for heating, metallurgy and other industrial processes. The Deuben coking and gas plant produces low temperature carbonization briquets from coal with 13.2% ash content, 54.8% volatiles, 13.5% semicoking tar with the effect that coke produced from these briquets disintegrates completely into fines (0/15 mm grain size). The study centered on effects of briquetting and coking parameters including coal grain size, coal moisture, briquetting pressure, coking temperature, heating rate and application of sulfite liquor as binder. Graphs of briquetting and coking results are provided. The Deuben coal was shown to be suitable for producing lumpy coke (11.5 to over 20 MPa compression strength) from coal under the optimum briquetting parameters of 0/1 mm grain size, 11% coal moisture, briquetting temperature of 70 to 80 C and briquetting pressure over 120 MPa. Use of a binder was found to be advantageous but not necessary. The produced coke showed favorable combustion properties. 6 refs.

  1. Association of urinary metals levels with type 2 diabetes risk in coke oven workers

    International Nuclear Information System (INIS)

    Liu, Bing; Feng, Wei; Wang, Jing; Li, Yaru; Han, Xu; Hu, Hua; Guo, Huan; Zhang, Xiaomin; He, Meian

    2016-01-01

    Background: Studies indicated that occupationally exposed to metals could result in oxidative damage and inflammation and increase cardiovascular diseases risk. However, epidemiological studies about the associations of metals exposure with diabetes risk among coke oven workers were limited. Objectives: This study aims to investigate the potential associations of 23 metals levels with the risk of diabetes among coke oven workers. Methods: The analysis was conducted in a cross-sectional study including 1493 participants. Urinary metals and urinary polycyclic aromatic hydrocarbons (PAHs) metabolites levels were determined by inductively coupled plasma mass spectrometer and gas chromatograph-mass spectrometer respectively. Multivariate logistic regression was used to investigate the associations of urinary metal levels with diabetes risk with adjustment for potential confounding factors including gender, age, BMI, education, smoking, drinking, physical activity, hypertension, hyperlipidemia and urinary PAHs metabolites levels. Results: Compared with the normoglycemia group, the levels of urinary copper, zinc, arsenic, selenium, molybdenum, and cadmium were significantly higher in the diabetes group (all p < 0.05). Participants with the highest tertile of urinary copper and zinc had 2.12 (95%CI: 1.12–4.01) and 5.43 (95%CI: 2.61–11.30) fold risk of diabetes. Similar results were found for hyperglycemia risk. Besides, participants with the highest tertile of manganese, barium, and lead had 1.65(1.22–2.23), 1.60(1.19–2.16) and 1.45(1.05–1.99) fold risk of hyperglycemia when compared with the lowest tertlie. Conclusion: The results indicated that the urinary copper and zinc levels were positively associated with the risk of diabetes and hyperglycemia among coke oven workers. Urinary manganese, barium and lead levels were also associated with increased risk of hyperglycemia independently of other traditional risk factors. These findings need further validation

  2. Specific long non-coding RNAs response to occupational PAHs exposure in coke oven workers.

    Science.gov (United States)

    Gao, Chen; He, Zhini; Li, Jie; Li, Xiao; Bai, Qing; Zhang, Zhengbao; Zhang, Xiao; Wang, Shan; Xiao, Xinhua; Wang, Fangping; Yan, Yan; Li, Daochuan; Chen, Liping; Zeng, Xiaowen; Xiao, Yongmei; Dong, Guanghui; Zheng, Yuxin; Wang, Qing; Chen, Wen

    2016-01-01

    To explore whether the alteration of lncRNA expression is correlated with polycyclic aromatic hydrocarbons (PAHs) exposure and DNA damage, we examined PAHs external and internal exposure, DNA damage and lncRNAs (HOTAIR, MALAT1, TUG1 and GAS5) expression in peripheral blood lymphocytes (PBLCs) of 150 male coke oven workers and 60 non-PAHs exposure workers. We found the expression of HOTAIR, MALAT1, and TUG1 were enhanced in PBLCs of coke oven workers and positively correlated with the levels of external PAHs exposure (adjusted P trend  TUG1). However, only HOTAIR and MALAT1 were significantly associated with the level of internal PAHs exposure (urinary 1-hydroxypyrene) with adjusted β  = 0.298, P  = 0.024 for HOTAIR and β  = 0.090, P  = 0.034 for MALAT1. In addition, the degree of DNA damage was positively associated with MALAT1 and HOTAIR expression in PBLCs of all subjects (adjusted β  = 0.024, P  = 0.002 for HOTAIR and β  = 0.007, P  = 0.003 for MALAT1). Moreover, we revealed that the global histone 3 lysine 27 trimethylation (H3K27me3) modification was positively associated with the degree of genetic damage ( β  = 0.061, P  < 0.001) and the increase of HOTAIR expression ( β  = 0.385, P  = 0.018). Taken together, our findings suggest that altered HOTAIR and MALAT1 expression might be involved in response to PAHs-induced DNA damage.

  3. Specific long non-coding RNAs response to occupational PAHs exposure in coke oven workers

    Directory of Open Access Journals (Sweden)

    Chen Gao

    Full Text Available To explore whether the alteration of lncRNA expression is correlated with polycyclic aromatic hydrocarbons (PAHs exposure and DNA damage, we examined PAHs external and internal exposure, DNA damage and lncRNAs (HOTAIR, MALAT1, TUG1 and GAS5 expression in peripheral blood lymphocytes (PBLCs of 150 male coke oven workers and 60 non-PAHs exposure workers. We found the expression of HOTAIR, MALAT1, and TUG1 were enhanced in PBLCs of coke oven workers and positively correlated with the levels of external PAHs exposure (adjusted Ptrend < 0.001 for HOTAIR and MALAT1, adjusted Ptrend = 0.006 for TUG1. However, only HOTAIR and MALAT1 were significantly associated with the level of internal PAHs exposure (urinary 1-hydroxypyrene with adjusted β = 0.298, P = 0.024 for HOTAIR and β = 0.090, P = 0.034 for MALAT1. In addition, the degree of DNA damage was positively associated with MALAT1 and HOTAIR expression in PBLCs of all subjects (adjusted β = 0.024, P = 0.002 for HOTAIR and β = 0.007, P = 0.003 for MALAT1. Moreover, we revealed that the global histone 3 lysine 27 trimethylation (H3K27me3 modification was positively associated with the degree of genetic damage (β = 0.061, P < 0.001 and the increase of HOTAIR expression (β = 0.385, P = 0.018. Taken together, our findings suggest that altered HOTAIR and MALAT1 expression might be involved in response to PAHs-induced DNA damage. Keywords: Polycyclic aromatic hydrocarbons, Long non-coding RNA, Peripheral blood lymphocytes, DNA damage response, HOTAIR, MALAT

  4. Physico-chemical treatment of coke plant effluents for control of water pollution in India

    Energy Technology Data Exchange (ETDEWEB)

    Ghose, M.K. [Indian School of Mines, Dhanbad (India). Center of Mining Environmental

    2002-01-01

    Coal carbonizing industries in India are important and are growing every year. Large quantities of liquid effluents produced in this industry contain a large amount of suspended solids, high biochemical oxygen demand (BOD), chemical oxygen demand (COD), phenols, ammonia and other toxic substances, which are causing serious surface water pollution in the area. There is a large number of coke plants in the vicinity of Jharia Coal Field (JCF). The working principle of a coke plant and the effluents produced is described. One large coke plant was chosen to evaluate characteristics of the effluent and to suggest a proper treatment method. Present effluent treatment system was found to be inadequate and a large quantity of a very good quality coke breeze is being lost, which is also causing siltation on the riverbed in addition to surface water pollution. Physico-chemical treatment has been considered as a suitable option for the treatment of coke plant effluents. A scheme has been proposed for the treatment, which can be suitably adopted for the recycling, reuse or safe disposal of the treated effluent. Various unit process and unit operations are discussed. The process may be useful on industrial scale for various sites so as to maintain a clean environment.

  5. ECONOMIC MODEL AND TOOLS OF THE AIR PROTECTION MANAGEMENT BASED ON THE EXAMPLE OF A COKING PLANT

    Directory of Open Access Journals (Sweden)

    Danuta Hilse

    2014-10-01

    Full Text Available Legal-economic models of the air protection management at the Polish industrial plants, which take into account the regulations of the Act on “Environment protection law”, are far from being perfect. It is particularly noticeable in the coking industry where chargeable pollutions are chosen selectively, and unitary rates of emission charges are agreed at random. Tax deductions are not granted either to producers of fuel coke for reduction of pollutants emission in municipal-housing management after replacing coal with fuel coke. The proposed new economic model of the air protection management at coking plants eliminates the existing shortcomings.

  6. Influence of fly dust from coking plants on some biological processes of plants

    Energy Technology Data Exchange (ETDEWEB)

    Masek, V

    1972-03-01

    The influence of three typical samples of fly dust from a coking plant on enzymatic reactions, photosynthesis, chlorophyll concentration in leaves of bean plants was studied. The hydrolysis of starch with amylases and of the albumen with pepsin at 37 C and the inversion of sacharosis by invertase in a buffered environment were also examined. None of the three dust samples had a significant effect on enzymatic reactions. Applying the dust samples to the leaves of young bean plants reduced the intensity of photosynthesis and chlorophyll concentration. In aqueous extracts, the dust samples liberated only small quantities of nutrients, plants which were grown in a dust suspension showed no increase of dry substance and growth rate. A stimulating effect of the dust samples on root growth was determined. Mixing the dust samples with the soil influenced the accessibility of water to plants. 17 references, 6 figures, 9 tables.

  7. Concentration of carcinoembryonic antigen alpha-fetoprotein and beta-subunit of human chorionic gonadotropin in the serum of coke oven workers

    Energy Technology Data Exchange (ETDEWEB)

    Snit, M. [Silesian Medical Academy, Zabrze (Poland)

    1993-01-01

    Increased levels of carcinoembryonic antigen and {alpha}-fetoprotein were found in blood serum of coke oven workers, and also to some extent in smokers and in residents of industrial cities. The {beta} subunit of chorionic gonadotropin was barely detectable.

  8. Smoking modify the effects of polycyclic aromatic hydrocarbons exposure on oxidative damage to DNA in coke oven workers.

    Science.gov (United States)

    Yang, Jin; Zhang, Hongjie; Zhang, Huitao; Wang, Wubin; Liu, Yanli; Fan, Yanfeng

    2017-07-01

    Coke oven emissions containing polycyclic aromatic hydrocarbons (PAHs) are predominant toxic constituents of particulate air pollution that have been linked to increased risk of lung cancer. Numerous epidemiological studies have suggested that oxidative DNA damage may play a pivotal role in the carcinogenic mechanism of lung cancer. Little is known about the effect of interaction between PAHs exposure and lifestyle on DNA oxidative damage. The study population is composed by coke oven workers (365) and water treatment workers (144), and their urinary levels of four PAH metabolites and 8-hydroxydeoxyguanosine (8-OHdG) were determined. Airborne samples of exposed sites (4) and control sites (3) were collected, and eight carcinogenic PAHs were detected by high-performance liquid chromatography. The median values of the sum of eight carcinogenic PAHs and BaP in exposed sites were significantly higher than control sites (P < 0.01). The study found that the urinary PAH metabolites were significantly elevated in coke oven workers (P < 0.01). Multivariate logistic regression analysis revealed that the risk of high levels of urinary 8-OHdG will increase with increasing age, cigarette consumption, and levels of urinary 1-hydroxypyrene, and P for trend were all <0.05. Smoking can significantly modify the effects of urinary 1-hydroxypyrene on high concentrations urinary 8-OHdG, during co-exposure to both light or heavy smoking and high 1-hydroxypyrene levels (OR 4.28, 95% CI 1.32-13.86 and OR 5.05, 95% CI 1.63-15.67, respectively). Our findings quantitatively demonstrate that workers exposed to coke oven fumes and smoking will cause more serious DNA oxidative damage.

  9. Determination of polycyclic aromatic hydrocarbons in urine from coke-oven workers with a radioimmunoassay

    Energy Technology Data Exchange (ETDEWEB)

    Herikstad, B.V.; Ovrebo, S.; Haugen, A.; Hagen, I. (Center for Industrial Research, Oslo (Norway))

    1993-02-01

    Considerable amounts of polycyclic aromatic hydrocarbons (PAH) are present in the workplace. In order to obtain a better understanding of the occupational hazards connected with PAH exposure various biomonitoring methods need to be applied. The level of PAH in urine collected from coke-oven workers has been measured by a recently developed radioimmunoassay. A significant correlation between estimated exposure levels for PAH and urinary levels of PAH was observed. During the winter period the control group was found to have an average concentration of 0.44 ng PAH/mmol creatinine, whereas the low, medium and high exposure groups contained 0.44, 0.71 and 0.85 ng PAH/mmol creatinine respectively. The urinary PAH level in the samples collected during the summer period was higher, i.e. 0.81, 0.94 and 1.10 ng PAH/mmol creatinine, for the low, medium and high exposure groups. Furthermore, a correlation was also observed between smoking and levels of urinary PAH. We conclude that this radioimmunoassay may be suitable as a simple and sensitive routine assay for monitoring individuals exposed to PAH.

  10. Occupational health risk assessment of volatile organic compounds emitted from the coke production unit of a steel plant.

    Science.gov (United States)

    Dehghani, Fateme; Omidi, Fariborz; Heravizadeh, Omidreza; Barati Chamgordani, Saied; Gharibi, Vahid; Sotoudeh Manesh, Akbar

    2018-03-27

    In this study, cancer and non-cancer risks of exposure to volatile organic compounds in the coke production unit of a steel plant were evaluated. To determine individual exposure to benzene, toluene, xylene and ethylbenzene, personal samples were taken from the breathing zone of workers according to National Institute for Occupational Safety and Health (NIOSH) method 1501. Cancer and non-cancer risk assessment was performed, using US Environmental Protection Agency (US EPA) methods. Samples analysis showed that the concentration of benzene in the energy and biochemistry and the benzol refinement sections was higher than occupational exposure limits. The cancer risk for benzene in all sections was significantly higher than allowable limit; the non-cancer risk for benzene in all sections and toluene in the benzol refinement section was also higher than 1.0. In conclusion, the current control measures are not sufficient and should be improved for efficient control of occupational exposures.

  11. The Dawes Lane coke ovens by-products plant expert system

    Energy Technology Data Exchange (ETDEWEB)

    P. Warren [Corus Research Development and Technology (United Kingdom). Teeside Technology Department

    2002-07-01

    A system has been developed to provide comprehensive monitoring of the washer/scrubber processes on the by-products plant at Dawes Lane coke ovens where faulty operation may cause blockage of the gas stream leading to opening of the battery bleeders to release gas to atmosphere. The system developed and the additional instrumentation and practices have met the requirements for improved monitoring to reduce the likelihood of uncontrolled gas emissions. It is planned to further develop the system so that it will contribute towards optimisation of plant operation, and so to generate a financial benefit from the investment made. The paper was presented to the Midland Section of the Coke Oven Managers' Association at Corus Centre, Scunthorpe, UK on 20 May 2001. 11 figs., 1 tab.

  12. The Homecourt coke plant site: a successful redeveloped brown field case

    International Nuclear Information System (INIS)

    Charbonnier, P.; Piguet, O.; Lereboullet, L.

    2006-01-01

    The environmental diagnosis of the coke plant site in Homecourt has been carried out over the last 15 years. Bail Industrie has selected two zones on the site for a remediation program in view of their further redevelopment. The weakly polluted grounds were submitted to a bio treatment, while the more polluted grounds were treated by thermal desorption. Tars have been incinerated off site. To assess the effectiveness of the treatment, percolation tests are carried out. (authors)

  13. The aquatic toxicity and chemical forms of coke plant effluent cyanide -- Implications for discharge limits

    International Nuclear Information System (INIS)

    Garibay, R.; Rupnow, M.; Godwin-Saad, E.; Hall, S.

    1995-01-01

    Cyanide is present in treated cokemaking process waters at concentrations as high as 8.0 mg/L. In assessing options for managing the discharge of a treated effluent, the development and implementation of discharge limits for cyanide became a critical issue. A study was initiated to evaluate possible alternatives to cyanide permit limits at the US Steel Gary Works Facility. The objectives of the study were to: (1) evaluation the forms of cyanide present in coke plant effluent; (2) determine whether these forms of cyanide are toxic to selected aquatic organisms; (3) compare the aquatic toxicity of various chemical forms of cyanide; (4) identify if the receiving water modifies cyanide bioavailability; and (5) confirm, with respect to water quality-based effluent limits, an appropriate analytical method for monitoring cyanide in a coke plant effluent. The results of aquatic toxicity tests and corresponding analytical data are presented. Toxicity tests were conducted with various pure chemical forms of cyanide as well as whole coke plant effluent (generated from a pilot-scale treatment system). Test species included the fathead minnow (Pimephales promelas), rainbow trout (Oncorhynchus mykiss), Ceriodaphnia dubia (C. dubia) and Daphnia magna (D. magna). Analytical measurements for cyanide included total, weak acid dissociable, diffusible cyanide and selected metal species of cyanide. The findings presented by the paper are relevant with respect to the application of cyanide water quality criteria for a coke plant effluent discharge, the translation of these water quality-based effluent limits to permit limits, and methods for compliance monitoring for cyanide

  14. Coal and coke applied to metallurgy. Vol. 2. Carvao e coque aplicados a metalurgia

    Energy Technology Data Exchange (ETDEWEB)

    Masuda, H.

    1983-01-01

    Papers include: coking; control of pollution from coking plants; handling and storage of coal; preparation of coal for coking; politics of the supply of coal; coke for blast furnaces; selective preparation and briquetting of coal for coking; cooling and drying of coke; preheating of coal for coking; formed coke.

  15. Dale Coke: Coke Farm

    OpenAIRE

    Farmer, Ellen

    2010-01-01

    Dale Coke grew up on an apricot orchard in California’s Santa Clara Valley. In 1976 he bought ten acres of farmland near Watsonville in Santa Cruz County but continued to work repairing fuel injection systems rather than farming at his new home. In 1981, a struggle with cancer inspired him to rethink his life and become an organic farmer. His neighbor, who had grown strawberries using pesticides and chemical fertilizers, asserted that strawberries could not be grown organically. Coke set out ...

  16. Catalytic wet air oxidation of coke-plant wastewater on ruthenium-based eggshell catalysts in a bubbling bed reactor.

    Science.gov (United States)

    Yang, M; Sun, Y; Xu, A H; Lu, X Y; Du, H Z; Sun, C L; Li, C

    2007-07-01

    Catalytic wet air of coke-plant wastewater was studied in a bubbling bed reactor. Two types of supported Ru-based catalysts, eggshell and uniform catalysts, were employed. Compared with the results in the wet air oxidation of coke-plant wastewater, supported Ru uniform catalysts showed high activity for chemical oxygen demand (COD) and ammonia/ammonium compounds (NH3-N) removal at temperature of 250 degrees C and pressure of 4.8 MPa, and it has been demonstrated that the catalytic activity of uniform catalyst depended strongly on the distribution of active sites of Ru on catalyst. Compared to the corresponding uniform catalysts with the same Ru loading (0.25 wt.% and 0.1 wt.%, respectively), the eggshell catalysts showed higher activities for CODcr removal and much higher activities for NH3-N degradation. The high activity of eggshell catalyst for treatment of coke-plant wastewater can be attributed to the higher density of active Ru sites in the shell layer than that of the corresponding uniform catalyst with the same Ru loading. It has been also evidenced that the active Ru sites in the internal core of uniform catalyst have very little or no contribution to CODcr and NH3-N removal in the total oxidation of coke-plant wastewater.

  17. Isotopic ratio based source apportionment of children's blood lead around coking plant area.

    Science.gov (United States)

    Cao, Suzhen; Duan, Xiaoli; Zhao, Xiuge; Wang, Beibei; Ma, Jin; Fan, Delong; Sun, Chengye; He, Bin; Wei, Fusheng; Jiang, Guibin

    2014-12-01

    Lead exposure in the environment is a major hazard affecting human health, particularly for children. The blood lead levels in the local children living around the largest coking area in China were measured, and the source of blood lead and the main pathways of lead exposure were investigated based on lead isotopic ratios ((207)Pb/(206)Pb and (208)Pb/(206)Pb) in blood and in a variety of media, including food, airborne particulate matter, soil, dust and drinking water. The children's blood lead level was 5.25 (1.59 to 34.36 as range) μg dL(-1), lower than the threshold in the current criteria of China defined by the US Centers for Disease Control (10 μg dL(-1)). The isotopic ratios in the blood were 2.111±0.018 for (208)Pb/(206)Pb and 0.864±0.005 for (207)Pb/(206)Pb, similar to those of vegetables, wheat, drinking water, airborne particulate matter, but different from those of vehicle emission and soil/dust, suggesting that the formers were the main pathway of lead exposure among the children. The exposure pathway analysis based on the isotopic ratios and the human health risk assessment showed that dietary intake of food and drinking water contributed 93.67% of total exposed lead. The study further indicated that the coal used in the coking plant is the dominant pollution source of lead in children's blood. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Biological monitoring the exposure to polycyclic aromatic hydrocarbons of coke oven workers in relation to smoking and genetic polymorphisms for GSTM1 and GSTT1

    Energy Technology Data Exchange (ETDEWEB)

    Joost H.M. van Delft; Marie-Jose S.T. Steenwinkel; Jeff G. van Asten; Nico de Vogel; Truus C.D.M. Bruijntjes-Rozier; Ton Schouten; Patricia Cramers; Lou Maas; Marcel H. van Herwijnen; Frederik-Jan van Schooten; Piet M.J. Hopmans [TNO Nutrition and Food Research Institute (Netherlands). Toxicology Division

    2001-07-01

    Occupational exposure to polycyclic aromatic hydrocarbons (PAH) increases the risk of developing lung cancer. Human exposure is often demonstrated by increased internal levels of PAH metabolites and of markers for early biological effects, like DNA adducts and cytogenetic aberrations. This study aimed to assess whether the current exposure to PAH of coke oven workers in a Dutch plant induced biological effects, and to determine if these effects are influenced by tobacco smoking and by genetic polymorphisms for the glutathione S-transferase genes GSTM1 and GSTT1. Urinary 1-hydroxypyrene (1-OHpyr) levels were used to monitor the internal dose, while the internal effective dose was assessed by monitoring PAH-DNA adducts, DNA strand breaks (Comet assay), sister-chromatid exchanges (SCE) and cells with a high frequency of SCE (HFC) in lymphocytes together with micronuclei (MN) in exfoliated urothelial cells. Occupational exposure to PAH resulted in statistically significant increased 1-OHpyr levels, but it did not cause a significant induction of SCE, HFC, MN, DNA strand breaks or DNA adducts. Smoking caused a significant increase of 1-OHpyr, SCE, HFC and DNA adducts, but not of MN or DNA strand breaks. Following correction for the smoking-related effects, no occupational induction of the effect biomarkers could be discerned. Multi-variate analysis did not show a significant influence of GSTM1 and GSTT1 polymorphisms on any biomarker. Also no significant interactions were observed between the various biomarkers.

  19. The use of fractionated fly ash of thermal power plants as binder for production of briquettes of coke breeze and dust

    Science.gov (United States)

    Temnikova, E. Yu; Bogomolov, A. R.; Lapin, A. A.

    2017-11-01

    In this paper, we propose to use the slag and ash material of thermal power plants (TPP) operating on pulverized coal fuel. The elemental and chemical composition of fly ash of five Kuzbass thermal power plants differs insignificantly from the composition of the mineral part of coking coal because coke production uses a charge, whose composition defines the main task: obtaining coke with the required parameters for production of iron and steel. These indicators are as follows: CRI reactivity and strength of the coke residue after reaction with CO2 - CSR. The chemical composition of fly ash of thermal power plants and microsilica with bulk density of 0.3-0.6 t/m3 generated at production of ferroalloys was compared. Fly ash and microsilica are the valuable raw material for production of mineral binder in manufacturing coke breeze briquettes (fraction of 2-10 mm) and dust (0-200 μm), generated in large quantities during coking (up to 40wt%). It is shown that this binder is necessary for production of smokeless briquettes with low reactivity, high strength and cost, demanded for production of cupola iron and melting the silicate materials, basaltic rocks in low-shaft furnaces. It is determined that microsilica contains up to 90% of silicon oxide, and fly ash contains up to 60% of silicon oxide and aluminum oxide of up to 20%. On average, the rest of fly ash composition consists of basic oxides. According to calculation by the VUKHIN formula, the basicity index of briquette changes significantly, when fly ash is introduced into briquette raw material component as a binder. The technology of coke briquette production on the basis of the non-magnetic fraction of TPP fly ash in the ratio from 3.5:1 to 4.5:1 (coke breeze : coke dust) with the addition of the binder component to 10% is proposed. The produced briquettes meet the requirements by CRI and require further study on CSR requirements.

  20. A temperature measurement system for coke-oven walls at the coke-oven plant Kaiserstuhl in Dortmund (Germany). Pomiar temperatury w scianach baterii koksowniczej w koksownii Kaisertuhl w Dortmund (Niemcy)

    Energy Technology Data Exchange (ETDEWEB)

    Chojnacki, M.; Sitek, A. (Hanslik Laboratorium Oprgramowania, Katowice (Poland))

    1994-08-01

    In the article, the software and hardware solutions developed by Hanslik Software Laboratory for Ruhrkohle AG are presented. The system was installed at Kaiserstuhl in Dortmund (Germany), the most modern coke-oven plant in the world. The project covered a temperature measurement system for the coke-oven walls as well as monitoring of the protection sensors in real-time. The article describes also the testing methodology we adopted, using computer aided testing. For the testing purposes, a simulator of the coke-oven and a testing program running under Windows were developed at our laboratory. The article shows the advantages of using off the shelf programmable components for ruggedized industrial applications. (author). 4 refs.

  1. Cytochrome P450 1B1 mRNA levels in peripheral blood cells and exposure to polycyclic aromatic hydrocarbons in Chinese coke oven workers

    Energy Technology Data Exchange (ETDEWEB)

    Hanaoka, Tomoyuki; Tsugane, Shoichiro [Epidemiology and Biostatistics Division, National Cancer Center Research Institute East, 6-5-1 Kashiwanoha, Kashiwa-shi, 277-8577 Chiba (Japan); Yamano, Yuko; Kagawa, Jun [Tokyo Womens' Medical University, 8-1 Kawadacho, Shinjuku-ku, 162-8666 Tokyo (Japan); Pan, Guowei; Zhang, Shujuan [Liaoning Provincial Center for Disease Prevention and Control, 42-1 Jixian Street, 110005 Shenyang (China); Hara, Kunio [Institute for Science of Labour, 2-8-14 Miyamae-ku, 216-8501 Kawasaki (Japan); Ichiba, Masayoshi; Zhang, Jiusong [Saga Medical School, 5-1 Nabeshima, Saga-shi, 849-8501 Saga (Japan); Liu, Tiefu; Li, Landi [Angang Public Health and Anti-epidemic Station Lishan District, 23 Shengoushi Yutian Street, 114034 Anshan (China); Takahashi, Ken [University of Occupational and Environmental Health, 1-1 Iseigaoka, Yahatanishi-ku, 807-8555 Kitakyushu (Japan)

    2002-09-16

    Cytochrome P450 1B1 (CYP1B1) is induced through the Ah receptor and is involved in the activation of polycyclic aromatic hydrocarbons (PAHs). To determine the validity of a quantitative analysis of CYP1B1 mRNA in peripheral human blood cells for the estimation of PAH exposure, a real-time quantitative polymerase chain reaction method was used to measure the relative levels of CYP1B1 mRNA in 37 Chinese coke oven workers and 13 control workers. A large inter-individual difference in the levels was observed. The average level of the CYP1B1 mRNA in workers at the top work site, where the PAH exposure level from the coke ovens was highest, was significantly higher than in workers at the middle site (P<0.01) or the controls (P=0.02). A non-significant positive correlation was found between the CYP1B1 mRNA levels and urinary 1-hydroxypyrene (R=0.22, P=0.13), and a significant correlation between these mRNA levels and urinary cotinine (R=0.33, P=0.02). It was interesting that a significant positive correlation between CYP1B1 mRNA and 1-hydroxypyrene was observed in subjects with the Leu/Leu type of CYP1B1 Leu432Val polymorphism (R=0.33, P=0.02, n=38) and a non-significant correlation in subjects with the Leu/Val and Val/Val types (R=-0.36, P=0.25, n=12), although the number of subjects in this strata analysis was small. Our preliminary study suggests that PAH exposure in coke ovens and smoking maybe associated with CYP1B1 mRNA levels in peripheral blood cells although mRNA is generally unstable and could be expressed following exposure to other agents.

  2. Combined biological treatment of sinter plant waste water, blast furnace gas scrubber water polluted groundwater and coke plant effluent

    Energy Technology Data Exchange (ETDEWEB)

    Antoine van Hoorn [Corus Staal, IJmuiden (Netherlands)

    2006-07-01

    Waste water from the Corus coke plant in IJmuiden had been handled by the activated sludge process since start-up in 1972 but in the eighties it was clear that although this removed most phenols, the rest of the COD and thiocyanate must also be removed before discharge. The paper describes the original water treatment process and the higher pressure gas scrubber system for removal of SO{sub 2}, heavy metals and other harmful components. It goes on to describe development of a combined biological treatment system, the heart of which is the so-called Bio 2000. The performance of this new plant is discussed. COD concentrations are very constant but Total Kjeldahl Nitrogen (TKN) concentrations fluctuate. COD, TKN and heavy metals are in compliance but cyanide and suspended solids are not always so. A method of overcoming this is being sought. This paper was presented at a COMA meeting in March 2005 held in Scunthorpe, UK. 10 figs., 2 tabs.

  3. Environmental impact of heavy metals on the soils and plants around a coke-making factory of Jiyuan city, China

    Science.gov (United States)

    Lun Leung, Kwun

    2010-05-01

    The combustion of coal usually leads to many different kinds of pollution around coke-making factories. Among these pollutions, the heavy metal contamination in the soil and plants is one of the major concerns by people living around. Heavy metals are highly attracted to the biological tissue, and can stay in bodies of organisms for long period of time, causing a lot of hazardous diseases to human beings, animal and plants. In the developing regions of China, developing of industries has been based on the sacrifices of environments and human health. In order to evaluate the danger of heavy metal contamination from a coke factory to citizens of close inhabitants, a survey on soil and plants was conducted in the region around a coke-making factory in Jiyuan city, which is a major electricity supplying city for the Henan Province in China. In this study, 8 surface soil samples and 11 plant samples were collected from 8 different places around the coke-making factory in Jiyuan city. The collected samples are then treated in the laboratory, and 8 types of heavy metals, which include arsenic, cadmium, chromium, cobalt, copper, lead, nickel and zinc, are analyzed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES). The concentration data of heavy metals that collected from the analysis are then used to evaluate their toxicity towards living organisms and ecology by applying several biological effect standards, such as effect-range low (ERL), effect-range median (ERM) and several maximum allowances standards of heavy metal concentrations in soils and plants that established by different countries. Moreover, the relationship between the distance from the factory and the concentration of heavy metals in soils and plants are also evaluated in order to find out the contamination ranges of those heavy metals from the source. The result shows that the concentration of these 8 types of heavy metals in the

  4. Coke gasification costs, economics, and commercial applications

    International Nuclear Information System (INIS)

    Jahnke, F.C.; Falsetti, J.S.; Wilson, R.F.

    1996-01-01

    The disposition of petroleum coke remains a problem for modern high conversion refineries. Market uncertainty and the price for coke can prevent the implementation of otherwise attractive projects. The commercially proven Texaco Gasification Process remains an excellent option for clean, cost effective coke disposition as demonstrated by the new coke gasification units coming on-line and under design. Previous papers, have discussed the coke market and general economics of coke gasification. This paper updates the current market situation and economics, and provide more details on cost and performance based on recent studies for commercial plants

  5. Ecological situation at the coke plant of the Nizhnii Tagil Integrated Iron and Steel Works (according to data from an expert commission of Gosstroi USSR)

    International Nuclear Information System (INIS)

    Filippov, B.S.

    1990-01-01

    A main source of pollution is the Nizhnii Tagil Integrated Iron and Steel Works (NTMK), whose share in the total emissions of harmful substances is very significant. Thus, in 1987 the mean annual dust content in the atmosphere of the city surpassed the maximum admissible concentrations 1.3 times, phenol 2 times, ammonia 2.5 times, benzopyrene 6 times. In 1988 an even higher content of harmful substances was noted. Reconstruction of the coke plant now underway has been called upon to ensure a significant improvement in the ecological conditions together with an overall increase in its technical level. Restoration of the existing capacity of the coke batteries at domestic coke plants is being accomplished according to two variants: first - relining of the batteries with retention of the existing dimensions or with a slight very limited increase, with modernization of the designs of the ovens and chemical departments, and also machines and equipment (technical refitting); second - withdrawal from operation of the existing batteries and construction of new higher capacity coke batteries in the plant area (reconstruction). From the standpoint of ecology and economy of capital investment it would be more expedient to restore capacity at NTMK according to the first variant. However, restoration here is being carried out according to the second variant with construction of coke batteries 9 and 10 in a new area with dry coke quenching. There are plans to decommission batteries 1-4. An analysis is given of the sources of pollution from the coke plant and measures are defined to reduce pollutants

  6. Coke retorts

    Energy Technology Data Exchange (ETDEWEB)

    Jones, S; MacDonald, J D

    1916-07-15

    To charge vertical coke retorts while preventing escape of gases the coal is fed by a revolving drum to an archimedean screw at the base of the retort, the coke being discharged at the top through a water seal. The feed pockets of the drum which revolves between plates, deliver coal from the hopper to the revolving screw. The coke is forced under the hood to the water seal and is removed by rake conveyor, the gases escaping through the pipe to the main.

  7. Emissions and emission reduction systems in the coal derivative production facilities of a coking plant. Emissionsquellen in Kohlenwertstoffbetrieben von Kokereien und Massnahmen zu ihrer Verminderung

    Energy Technology Data Exchange (ETDEWEB)

    1985-01-01

    Coking plants may present odour unisances to their vicinity although these odours are no health problem. Typical odorants emitted by a coking plant are: Hydrogen sulfide, mercaptanes, carbon sulfide, naphthaline, phenol and ammonia. The odour threshold of these substances may be quite close to the analytical detection limit. There are a large number of emission sources, e.g. production and storage containers, baths, tar sinks, and ventilation systems. The report describes the possible sources of emissions as well as the countermeasures available at the present state of the art.

  8. Deciphering Cyanide-Degrading Potential of Bacterial Community Associated with the Coking Wastewater Treatment Plant with a Novel Draft Genome.

    Science.gov (United States)

    Wang, Zhiping; Liu, Lili; Guo, Feng; Zhang, Tong

    2015-10-01

    Biotreatment processes fed with coking wastewater often encounter insufficient removal of pollutants, such as ammonia, phenols, and polycyclic aromatic hydrocarbons (PAHs), especially for cyanides. However, only a limited number of bacterial species in pure cultures have been confirmed to metabolize cyanides, which hinders the improvement of these processes. In this study, a microbial community of activated sludge enriched in a coking wastewater treatment plant was analyzed using 454 pyrosequencing and Illumina sequencing to characterize the potential cyanide-degrading bacteria. According to the classification of these pyro-tags, targeting V3/V4 regions of 16S rRNA gene, half of them were assigned to the family Xanthomonadaceae, implying that Xanthomonadaceae bacteria are well-adapted to coking wastewater. A nearly complete draft genome of the dominant bacterium was reconstructed from metagenome of this community to explore cyanide metabolism based on analysis of the genome. The assembled 16S rRNA gene from this draft genome showed that this bacterium was a novel species of Thermomonas within Xanthomonadaceae, which was further verified by comparative genomics. The annotation using KEGG and Pfam identified genes related to cyanide metabolism, including genes responsible for the iron-harvesting system, cyanide-insensitive terminal oxidase, cyanide hydrolase/nitrilase, and thiosulfate:cyanide transferase. Phylogenetic analysis showed that these genes had homologs in previously identified genomes of bacteria within Xanthomonadaceae and even presented similar gene cassettes, thus implying an inherent cyanide-decomposing potential. The findings of this study expand our knowledge about the bacterial degradation of cyanide compounds and will be helpful in the remediation of cyanides contamination.

  9. Coke production in large coke ovens

    Energy Technology Data Exchange (ETDEWEB)

    Zhuravskii, A.A.; Sytenko, I.V.; Zhupraner, Z.S.; Vasil' ev, Yu.S.; Karpukhin, E.A.; Pliner, G.E.; Rud' , A.I.; Bulyga, N.I. (NPO Koksokhimiya (USSR))

    1990-08-01

    Analyzes operation of the No 9 battery with coke ovens with a volume of 41.6 m{sup 3}. Factors that influence coke oven operation and coke quality are analyzed. The following problems are evaluated: composition of coal mixtures (G, Zh, K, OS, GZh coal types), methods for coal mixture preparation (crushing degree, selective crushing), temperature distribution in a coke oven and effects of heating system, coke shrinkage during coking and factors that influence shrinkage, optimizing pressure used for coke pushing, chemical, mechanical and physical properties of coke. Regression equations used for forecasting coke properties are derived: the M10 coke wear index, M25 coke strength index, ash content etc. Recommendations for optimum coking conditions are made. 6 refs.

  10. Making coke

    Energy Technology Data Exchange (ETDEWEB)

    Wodehouse-Temple, C G

    1929-07-12

    Semi-coke is produced by mixing low-value absorbent solid carbonaceous material such as coal dust, slack, gas-works coke, lignite, torbanite, raphilite, cannel, or shale with not more than 20% of a carbonaceous binding material such as petroleum distillation residue, tarry residues, pitch bitumen, Trinidad asphalt, Manjak or the substance known under the registered Trade Mark Gilsonite and subjecting the mixture without briquetting to a temperature not exceeding 550/sup 0/C. According to the first Provisional Specification, the mixture may if desired be briquetted before being heated and the second constituent may be present to the extent of 30%.

  11. Study of the raw material base for a by-product coke plant by the method of thermal degradation of coal in a centrifugal field

    Energy Technology Data Exchange (ETDEWEB)

    Epimakhov, N.M.; Kardashova, V.F.; Sulimova, E.I.

    1982-01-01

    Coals from the Donbass and Karaganda basins, being supplied to a Bagley by-product coke plant were studied. A sharp distinction between coals of different degrees of metamorphism in respect to the yield of liquid nonvolatile products was demonstrated. A difference in respect to this index was recognized for individual coals from one and the same technological group from a single basin.

  12. Investigation on treatment of cyanide in waste water of coke-oven plant with radiation-technique

    International Nuclear Information System (INIS)

    Qi Shengchu; He Yongke; Wu Jilan

    1992-01-01

    The treatment of cyanide in waste water of coke-oven plant with radiation-technique was investigated. The investigation indicated that toxic products under γ-ray irradiation were changed into less-toxic or non-toxic products. Organic pollutants will compete with cyanide for scavenging active intermediates of water (H, e aq - and OH radical). Therefore, it will inhibit cyanide radiolysis. The pretreatment with active carbon increases the radiolytic decomposition rate of cyanide and damage rate of organism in waste water. H 2 O 2 and N 2 O convert e aq - into OH radical. however they improve the efficiency decomposition of cyanide. OH radical plays an important role in reducing cyanide content and COD value

  13. The influence of microporosity on resistance and carboxyreactivity of cokes

    Energy Technology Data Exchange (ETDEWEB)

    Medek, J.; Weishauptova, Z. [Academy of Sciences, Prague (Czech Republic). Inst. of Rock Structure and Mechanics

    1997-12-31

    Large sample collection of metallurgical cokes from Ostrava-Karvina coking plants, were used for correlation of the resistivity of the coke matter (carbon solid phase plus micropores) and carboxyreactivity of cokes with the value of microporosity. It results, from this correlation, that the characteristic values of the two mentioned quantities appartain to the solid phase of all metallurgical cokes studied, while the individual values of these quantities are caused by the different microporosity of the coke matter. The microporosity as a structure characteristic is a consequence of the discontinuity of the coke solid phase and can be quantitatively expressed as the degree of solid phase dispersion. (orig.)

  14. Increasing efficiency of reconstruction and technological development of coking enterprises

    Energy Technology Data Exchange (ETDEWEB)

    Rozenfel' d, M.S.; Martynenko, V.M.; Tytyuk, Yu.A.; Ivanov, V.V.; Svyatogorov, A.A.; Kolomiets, A.F. (NIISP, Voroshilovgrad (USSR))

    1989-07-01

    Discusses problems associated with reconstruction of coking plants in the USSR. Planning coking plant reconstruction is analyzed. Duration of individual stages of plant reconstruction is considered. A method developed by the Giprokoks research institute for calculating reconstruction time considering duration of individual stages of coke oven battery repair is analyzed: construction of storage facilities, transport of materials and equipment, safety requirements, coke oven cooling, dismantling, construction of coke oven walls, installation of machines and equipment. Advantages of using the methods for analysis of coke oven battery reconstruction and optimization of repair time are discussed.

  15. Coke from partially briquetted preheated coal mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Belitskii, A.N.; Sklyar, M.G.; Toryanik, Eh.I.; Bronshtein, A.P.

    1988-07-01

    Analyzes effects of partial coal charge briquetting on coking and on quality of coke for metallurgy. Effects of mixing hot coal briquets on temperature and moisture of coal were investigated on an experimental scale in a coking plant. Coal with a moisture content of 12% was used. Coking mixture consisted of 30% briquets and 70% crushed coal. Fifteen minutes after briquet mixing with coal, the mean coal charge temperature increased to 100-105 C and moisture content was lower than 2-5%. Results of laboratory investigations were verified by tests on a commercial scale. Experiments showed briquetting of weakly caking or non-caking coal charge components to be an efficient way of preventing coke quality decline. Adding 15-20% briquets consisting of weakly caking coal did not influence coke quality. Mixing hot coal briquets reduced moisture content in crushed coal, increased its temperature and reduced coking time.

  16. Statistical summary of coal mining, coking, and briquetting plants and review of the solid fuels market in 1976

    Energy Technology Data Exchange (ETDEWEB)

    Medaets, J

    1977-05-01

    This paper reviews the activities of the Belgian coal and coke industry noting that some of the figures are still provisional. Figures are given for production and stocks of coal; personnel; productivity; working hours; salaries; and the production of coke and briquettes.

  17. Scientific Council of the State Committee for Science and Technology on the problem 'New processes in the coking industry', Coke-Chemistry Section of the Scientific-Technical Council of the Ministry of Ferrous Metallurgy of the USSR and of the Central Administration of the Scientific-Technical Branch of Ferrous Metallurgy

    Energy Technology Data Exchange (ETDEWEB)

    Bukvareva, O.F.

    1986-12-01

    A report is presented on 3 conferences on the development of the Soviet coking industry held in February and April 1986. Papers delivered at the conferences and selected recommendations for development of equipment for coking, coking systems, optimization of coal mixtures for coking, environmental protection and research programs on coking are reviewed. The following problems were discussed: modernization of coke oven design, selecting the optimum size of coke ovens, prospects for dry coke quenching in the USSR, evaluation of operation of systems for dry coke quenching, utilization of waste heat from coke quenching for heat treatment of coal mixtures for coking, research programs on coking in the 12th five-year plan (1986-1990), partial briquetting of coal mixtures for coking and selecting optimum binders for partial briqetting, formed coke processes, economic analysis of formed coke processes, fire-resistant bricks and elements for coke oven construction, new coking technologies, pollution control in coking plants.

  18. The coke dilemma

    Energy Technology Data Exchange (ETDEWEB)

    Champagne, P E; Lewis, J A

    1989-08-01

    Coke-making capacity reductions and the current status of coke oven batteries in the USA are surveyed, as well as prior forecasts of the steel and coke markets. The future position is then analysed and it is concluded that the US coke supply situation should improve up to 1995, but that there could be major domestic coke production deficits in the period 1996-2000; critical decisions will soon have to be made about replacement of coking capacity.

  19. Bacterial community compositions of coking wastewater treatment plants in steel industry revealed by Illumina high-throughput sequencing.

    Science.gov (United States)

    Ma, Qiao; Qu, Yuanyuan; Shen, Wenli; Zhang, Zhaojing; Wang, Jingwei; Liu, Ziyan; Li, Duanxing; Li, Huijie; Zhou, Jiti

    2015-03-01

    In this study, Illumina high-throughput sequencing was used to reveal the community structures of nine coking wastewater treatment plants (CWWTPs) in China for the first time. The sludge systems exhibited a similar community composition at each taxonomic level. Compared to previous studies, some of the core genera in municipal wastewater treatment plants such as Zoogloea, Prosthecobacter and Gp6 were detected as minor species. Thiobacillus (20.83%), Comamonas (6.58%), Thauera (4.02%), Azoarcus (7.78%) and Rhodoplanes (1.42%) were the dominant genera shared by at least six CWWTPs. The percentages of autotrophic ammonia-oxidizing bacteria and nitrite-oxidizing bacteria were unexpectedly low, which were verified by both real-time PCR and fluorescence in situ hybridization analyses. Hierarchical clustering and canonical correspondence analysis indicated that operation mode, flow rate and temperature might be the key factors in community formation. This study provides new insights into our understanding of microbial community compositions and structures of CWWTPs. Copyright © 2014 Elsevier Ltd. All rights reserved.

  20. [NH4+-N removal stability of zeolite media packed multistage-biofilm system for coke-plant wastewater treatment].

    Science.gov (United States)

    Zhao, Wen-Tao; Huang, Xia; He, Miao; Zhang, Peng-Yi; Zuo, Chen-Yan

    2009-02-15

    The practical ammonia stripping effectiveness of coke-plant wastewater treatment may vary widely, and high NH4+-N shock loading will lead to the fluctuation of residual NH4+-N concentration of biological effluent. A zeolite media packed multistage-biofilm system (ZMBS) was used for coke-plant wastewater treatment for enhancing the NH4+-N treatment ability of the bio-system to shock loading, as well as achieving high COD removal efficiency. Treatment performance during steady-state and shock loading and transformation of organic pollutants in the system were investigated systematically. The experiment results indicated that when the system was operated at NH4+-N loading 0.21 kg/(m3 x d) and COD loading NH4+-N and COD concentrations were (2.2 +/- 1.2) mg/L, (228 +/- 60) mg/L with average removal efficiencies of (99.1 +/- 0.5)% and (86.0 +/- 2.6)%. During the twice NH4+-N shock loadings [0.03 kg/(m3 x d) and 0.06 kg/(m3 x d)], ZMBS showed a strong resisting ability with average removal efficiencies of 99.0% and 92.9% higher than those of a compared system's 96.8% and 89.3%. By monitoring the change of water quality along the length of the ZMBS's cells, two function zones for different pollutant removal were found to exist, named as decarbonization/nitrification (C/N) zone and nitrification (N) zone, and the NH4+-N removal rate in N zone was 2-8 times as that in C/N zone. TOC concentrations of organic matters with relative molecular weight 1 x 10(4), were 227.6, 104.8 and 35.0 mg/L in raw wastewater, and 31.2, 22.9 and 31.5 mg/L in the effluent, respectively. Organic matters with relative molecular weight 1x 10(3) were the main remained substances in the effluent.

  1. Study on treatment of distilled ammonia waste water from coke plant with activated carbon-NaClO catalytic oxidation method

    Energy Technology Data Exchange (ETDEWEB)

    Luo, D.; Yi, P.; Liu, J.; Chen, A. [Xiangtan Polytechnic University, Xiangtan (China). Dept. of Chemical Enginering

    2001-12-01

    Catalytic oxidation method for the treatment of distilled ammonia waste water from coke plant was investigated using activated carbon as catalyst and NaClO as oxidant. The influences of main factors, such as NaClO, activated carbon, pH and reactionary time were discussed. The results showed that under the conditions of 25{degree}C, NaClO/CODO=1.5, carbon/NaClO=0.6 and pH=3.0, the reaction completed within 120 minutes with 99.5% of phenol removal and 75.8% of COD removal when the distilled ammonia waste water from coke plant which containing phenol 510 mg/L and CODO 8420 mg/L was treated. 13 refs., 4 figs.

  2. Fractionation of trace elements and human health risk of submicron particulate matter (PM1) collected in the surroundings of coking plants.

    Science.gov (United States)

    Zajusz-Zubek, Elwira; Radko, Tomasz; Mainka, Anna

    2017-08-01

    Samples of PM1 were collected in the surroundings of coking plants located in southern Poland. Chemical fractionation provided information on the contents of trace elements As, Cd, Co, Cr, Hg, Mn, Ni, Pb, Sb and Se in all mobile (F1-F3) and not mobile (F4) fractions of PM1 in the vicinity of large sources of emissions related to energochemical processing of coal during the summer. The determined enrichment factors indicate the influence of anthropogenic sources on the concentration of the examined elements contained in PM1 in the areas subjected to investigation. The analysis of health risk for the assumed scenario of inhabitant exposure to the toxic effect of elements, based on the values of the hazard index, revealed that the absorption of the examined elements contained in the most mobile fractions of particulate matter via inhalation by children and adults can be considered potentially harmless to the health of people inhabiting the surroundings of coking plants during the summer (HI PM1, approximately four adults and one child out of one million people living in the vicinity of the coking plants may develop cancer.

  3. The reaction of Polish market to last year's changes on international coke and steel market

    Energy Technology Data Exchange (ETDEWEB)

    Czornik, G.; Gabriel, D. [Polski Koks S.A. (Poland)

    2004-07-01

    The presentation, outlined in 16 slides/overheads, discussed the following: Poland's position in the world market; the Polish coking industry and the world coke and steel industry; the reaction of Polish coke plants; the effect of the increase in coke prices; ownership changes in Poland's coking industry scenarios for the future; the role of Polski Koks in Poland's coking industry; and sales and exports of coke by Polski Koks.

  4. Evaluation and determination of soil remediation schemes using a modified AHP model and its application in a contaminated coking plant.

    Science.gov (United States)

    Li, Xingang; Li, Jia; Sui, Hong; He, Lin; Cao, Xingtao; Li, Yonghong

    2018-07-05

    Soil remediation has been considered as one of the most difficult pollution treatment tasks due to its high complexity in contaminants, geological conditions, usage, urgency, etc. The diversity in remediation technologies further makes quick selection of suitable remediation schemes much tougher even the site investigation has been done. Herein, a sustainable decision support hierarchical model has been developed to select, evaluate and determine preferred soil remediation schemes comprehensively based on modified analytic hierarchy process (MAHP). This MAHP method combines competence model and the Grubbs criteria with the conventional AHP. It not only considers the competence differences among experts in group decision, but also adjusts the big deviation caused by different experts' preference through sample analysis. This conversion allows the final remediation decision more reasonable. In this model, different evaluation criteria, including economic effect, environmental effect and technological effect, are employed to evaluate the integrated performance of remediation schemes followed by a strict computation using above MAHP. To confirm the feasibility of this developed model, it has been tested by a benzene workshop contaminated site in Beijing coking plant. Beyond soil remediation, this MAHP model would also be applied in other fields referring to multi-criteria group decision making. Copyright © 2018 Elsevier B.V. All rights reserved.

  5. World coking coal markets

    International Nuclear Information System (INIS)

    McCloskey, G.

    2010-01-01

    This article discussed conditions in world coking coal markets. There is increased demand from Asia for metallurgical coal imports. World iron production was up 22 percent in first 7 months of 2010. Supply is up in Australia, the United States, Canada, New Zealand, Russia, and Mongolia, but the unexpected surge in supply caused prices to drop following a robust start to the year. Coking coal exports are up for the United States and Australia, but a delay in expanded production is expected until 2014. There is increased demand from Brazil, India, Taiwan, South Korea, and Japan as well as new plants in Thailand, Indonesia, and Brazil. Unexpectedly, Australia is backing out of the Chinese market but increasing exports to Japan and South Korea. India is seeing flat performance in iron production and imports, and the United States has surged back into Asia. A considerable increase is expected in the seaborne import requirement by 2020. Prices are expected to fall and then rise. This presentation also discussed whether coking coal index pricing is impossible or inevitable. 3 tabs., 5 figs.

  6. Coking processes

    Energy Technology Data Exchange (ETDEWEB)

    Rollason, A

    1913-09-01

    In the production of light hydrocarbon oils from coals, cannels, or shales which are high in oxygen, from 3 to 5% of limestone or other suitable carbonate is added to the coking-charge. The carbonate added is proportionate to the oxygen contained in the coal etc. The charge is slowly heated up to a temperature of about 500/sup 0/C., water is driven off between 85 and 105/sup 0/C., and carbon dioxide is evolved at a low temperature and retards the evolution of combustible gases until a temperature between 130 and 175/sup 0/C., is reached. Upon formation of the endothermic hydrocarbons, the temperature of the charge becomes lowered, a large volume of light oils of the benzol series is produced, and an increased yield of ammonia is obtained, leaving the carbon in graphitic form.

  7. Fine art of coking

    Energy Technology Data Exchange (ETDEWEB)

    Dresner, S.

    1984-01-01

    The art and science of coking are discussed. Coke is the solid carbon made from the heavy, viscous residue left after the more useful products such as gasoline and diesel fuel have been refined out of the crude oil. Fuel grade coke can be a substitute for steam coal in many applications. Low-sulfur fuel coke is used in blast furnaces for steelmaking. The operations of Conoco's refineries for producing coke is described.

  8. Study on standard coal preparation plant for coking coal in Jharia Coalfield

    Energy Technology Data Exchange (ETDEWEB)

    Winiewski, J; Sarkar, G G

    1975-10-01

    The proposed standardization of coal preparation plant will be based on three standard types of crushing station, a standard jig washery or cyclone washery, and three standard types of slurry water treatment section. Some large installations, and some existing washeries after modification, may incorporate heavy media baths for coarse coal and jigs for slack coal, where coal is easy or moderately easy to wash. Flow sheets are given for the standard types of crushing plant, washery, and slurry water circuit. The storage of raw coal and saleable products is briefly discussed.

  9. Emission and profile characteristic of volatile organic compounds emitted from coke production, iron smelt, heating station and power plant in Liaoning Province, China.

    Science.gov (United States)

    Shi, Jianwu; Deng, Hao; Bai, Zhipeng; Kong, Shaofei; Wang, Xiuyan; Hao, Jiming; Han, Xinyu; Ning, Ping

    2015-05-15

    107 kinds of C₂-C₁₂ volatile organic compound (VOC) mass concentrations and profiles for four types of coal-fired stationary sources in Liaoning Province were studied by a dilution sampling system and GC-MS analysis method, which are of significant importance with regard to VOC emissions in northeast of China. The results showed that there were some differences among these VOC source profiles. The total mass concentrations of analyzed 107 VOC species varied from 10,917 to 19,652 μg m(-3). Halogenated hydrocarbons exhibited higher mass percentages for the VOC source profiles of iron smelt (48.8%) and coke production plant (37.7%). Aromatic hydrocarbons were the most abundant in heating station plant (69.1%). Ketones, alcohols and acetates held 45.0% of total VOCs in thermal power plant. For non-methane hydrocarbons (NMHCs), which are demanded for photochemical assessment in the USA, toluene and n-hexane were the most abundant species in the iron smelt, coke production and thermal power plant, with the mass percentages of 64.8%, 52.7% and 38.6%, respectively. Trimethylbenzene, n-propylbenzene and o,m-ethyltoluene approximately accounted for 70.0% in heating station plant. NMHCs emitted from coke production, iron smelt, heating station and power plant listed above presented different chemical reactivities. The average OH loss rate of NMHCs from heating station, was 4 to 5.6 times higher than that of NMHCs from iron smelt, coke production and power plant, which implies that VOCs emitted from heating station in northeast of China should be controlled firstly to avoid photochemical ozone pollution and protect human health. There are significant variations in the ratios of benzene/toluene and m, p-xylene/ethylbenzene of these coal-fired source profiles. The representativeness of the coal-fired sources studied and the VOC samples collected should be more closely examined. The accuracy of VOC source profiles related to coal-fired processes is highly dependent on

  10. 76 FR 52350 - Coke Oven Emissions Standard; Extension of the Office of Management and Budget's (OMB) Approval...

    Science.gov (United States)

    2011-08-22

    ... Standard provide protection for workers from the adverse health effects associated with exposure to coke...' exposure to coke oven emissions, monitor worker health, and provide workers with information about their exposures and the health effects of exposure to coke oven emissions. II. Special Issues for Comment OSHA has...

  11. The effects of heavy metals and their interactions with polycyclic aromatic hydrocarbons on the oxidative stress among coke-oven workers

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Tian; Feng, Wei; Kuang, Dan; Deng, Qifei [Department of Occupational and Environmental Health, State Key Laboratory of Environmental Health (Incubating), School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan (China); Zhang, Wangzhen [Institute of Industrial Health, Wuhan Iron & Steel (Group) Corporation, Wuhan 430070, China. (China); Wang, Suhan; He, Meian; Zhang, Xiaomin; Wu, Tangchun [Department of Occupational and Environmental Health, State Key Laboratory of Environmental Health (Incubating), School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan (China); Guo, Huan, E-mail: ghuan5011@hust.edu.cn [Department of Occupational and Environmental Health, State Key Laboratory of Environmental Health (Incubating), School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan (China)

    2015-07-15

    Heavy metals and polycyclic aromatic hydrocarbons (PAHs) are predominate toxic constituents of particulate air pollution that may be related to the increased risk of cardiopulmonary events. We aim to investigate the effects of the toxic heavy metals (arsenic, As; cadmium, Cd; chromium, Cr; nickel, Ni; and lead, Pb), and their interactions with PAHs on oxidative stress among coke-oven workers. A total of 1333 male workers were recruited in this study. We determined their urinary levels of As, Cd, Cr, Ni, Pb, twelve PAH metabolites, 8-hydroxydeoxyguanosine (8-OHdG), and 8-iso-prostaglandin-F2α (8-iso-PGF2α). Multivariate linear regression models were used to analyze the effects of these metals and their interactions with PAHs on 8-OHdG and 8-iso-PGF2α levels. It was found that only urinary As and Ni showed marginal or significant positive linear dose-dependent effects on 8-OHdG in this study population, especially among smokers (β=0.103, P=0.073 and β=0.110, P=0.002, respectively). After stratifying all participants by the quartiles of ΣOH-PAH, all five metals showed linear association with 8-OHdG in the highest quartile subgroup (Q4) of ΣOH-PAHs. However, these five urinary metals showed significantly consistent linear associations with 8-iso-PGF2α in all subjects and each stratum. Urinary ΣOH-PAHs can significant modify the effects of heavy metals on oxidative stress, while co-exposure to both high levels of ΣOH-PAHs and heavy metals render the workers with highest 8-OHdG and 8-iso-PGF2α (all P{sub interaction}≤0.005). This study showed evidence on the interaction effects of heavy metals and PAHs on increasing the oxidative stress, and these results warrant further investigation in more longitudinal studies. - Highlights: • Heavy metals and PAHs are predominate toxic constituents of particulate matters. • Urinary As and Ni showed linear dose-dependent effects on 8-OHdG and 8-iso-PGF2α. • PAHs significant interact with toxic metal in increasing 8

  12. The effects of heavy metals and their interactions with polycyclic aromatic hydrocarbons on the oxidative stress among coke-oven workers

    International Nuclear Information System (INIS)

    Wang, Tian; Feng, Wei; Kuang, Dan; Deng, Qifei; Zhang, Wangzhen; Wang, Suhan; He, Meian; Zhang, Xiaomin; Wu, Tangchun; Guo, Huan

    2015-01-01

    Heavy metals and polycyclic aromatic hydrocarbons (PAHs) are predominate toxic constituents of particulate air pollution that may be related to the increased risk of cardiopulmonary events. We aim to investigate the effects of the toxic heavy metals (arsenic, As; cadmium, Cd; chromium, Cr; nickel, Ni; and lead, Pb), and their interactions with PAHs on oxidative stress among coke-oven workers. A total of 1333 male workers were recruited in this study. We determined their urinary levels of As, Cd, Cr, Ni, Pb, twelve PAH metabolites, 8-hydroxydeoxyguanosine (8-OHdG), and 8-iso-prostaglandin-F2α (8-iso-PGF2α). Multivariate linear regression models were used to analyze the effects of these metals and their interactions with PAHs on 8-OHdG and 8-iso-PGF2α levels. It was found that only urinary As and Ni showed marginal or significant positive linear dose-dependent effects on 8-OHdG in this study population, especially among smokers (β=0.103, P=0.073 and β=0.110, P=0.002, respectively). After stratifying all participants by the quartiles of ΣOH-PAH, all five metals showed linear association with 8-OHdG in the highest quartile subgroup (Q4) of ΣOH-PAHs. However, these five urinary metals showed significantly consistent linear associations with 8-iso-PGF2α in all subjects and each stratum. Urinary ΣOH-PAHs can significant modify the effects of heavy metals on oxidative stress, while co-exposure to both high levels of ΣOH-PAHs and heavy metals render the workers with highest 8-OHdG and 8-iso-PGF2α (all P interaction ≤0.005). This study showed evidence on the interaction effects of heavy metals and PAHs on increasing the oxidative stress, and these results warrant further investigation in more longitudinal studies. - Highlights: • Heavy metals and PAHs are predominate toxic constituents of particulate matters. • Urinary As and Ni showed linear dose-dependent effects on 8-OHdG and 8-iso-PGF2α. • PAHs significant interact with toxic metal in increasing 8-OHd

  13. The Bricoke process for producing metallurgical coke in conventional ovens from blends containing a high percentage of non-coking coal

    Energy Technology Data Exchange (ETDEWEB)

    Vidal, R; Munnix, K; Dellieu, J

    1980-06-01

    The article discusses the following aspects:- description of the BRICOKE process; trials in pilot plant, showing the influence of the different parameters on the coke quality and delimiting the range of the suitable non-coking coals; industrial scale trials of long term with 33% of non-coking coal briquettes in the charge; influence on the coking process as well as on the blast furnace working and increase of the output of usual coke-oven by the BRICOKE process. (11 refs.)

  14. Effect of nut coke on the performance of the ironmaking blast furnace

    NARCIS (Netherlands)

    Song, Q.

    2013-01-01

    The blast furnace consumes a large amount of high quality metallurgy coke (size 35-80 mm) in addition to ore in the form of pellets and sinter. This coke is the coarse fraction, derived from the coke plant. The fine fraction (8 -35 mm), arise after sieving, named nut coke, can’t be directly used in

  15. Job creation, heterogeneous workers and technical change : matched worker/plant data : evidence from Norway

    OpenAIRE

    Salvanes, Kjell G.; Førre, Svein Erik

    2001-01-01

    Abstract: Using matched worker/plant level data for Norway, theories explaining the change in skill composition are assessed using direct evidence on the job creation and destruction for high, medium and low skilled workers. Skill based job creation is analysed in detail for plants in a high-skill service sector and in low- and high-tech manufacturing sectors. Given a compressed wage structure in Norway and increased supply of high skilled workers, the supply of skills may also explain the...

  16. Cocaine (Coke, Crack) Facts

    Science.gov (United States)

    ... That People Abuse » Cocaine (Coke, Crack) Facts Cocaine (Coke, Crack) Facts Listen Cocaine is a white ... 69 KB) "My life was built around getting cocaine and getting high." ©istock.com/ Marjot Stacey is ...

  17. New and revised standards for coke production

    Energy Technology Data Exchange (ETDEWEB)

    G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

  18. Alternative coke production from unconventional feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Smoot, D.; Eatough, C.N.; Heaton, J.S.; Eatough, S.R.; Miller, A.B. [Combustion Resources, Provo, UT (US)

    2004-07-01

    This presentation reports on US Department of Energy and company sponsored research and development to develop a technology and process for making metallurgical-quality coke from alternate feedstocks, including by-product and waste carbonaceous materials. The basic patent-pending process blends and presses these carbon-containing materials into briquettes of specified size. This product is referred to as CR Clean Coke because pollutant emission levels are carefully controlled to low levels with little or no vagrant emissions during processing. A wide range of feedstock materials has been investigated in over 600 tests for run-of-mine and waste coal fines of various rank with blends of coal tars and pitches, coal and biomass chars, met-coke breeze or petroleum coke. For various coal/pet-coke/tar feedstocks, CR has produced uniform-sized briquettes in commercial-scale briquettes in three nominal sizes: one inch, two inch, and three inch. These products have been successfully qualified according to stringent requirements for conventional met-coke use in a blast furnace. Several formulation have met and frequently exceeded these established met-coke specifications. One specific product containing coal, tar and pet-coke was selected as a base formulation for which preliminary process design and cost estimates have been completed for construction and operation of a demonstration plant capable of producing 120,000 tons per year of CR Clean Coke. Plant design elements and blast furnace test plans are presented. Tailoring of CR Clean Coke products to other prospective end users including foundry, sugar, soda ash, and ferrometals industries presents additional opportunities. The text is accompanied by 30 slides/overheads. 14 refs., 3 figs., 9 tabs.

  19. Hygiene of work in main shops of modern coking by-product industry. [USSR

    Energy Technology Data Exchange (ETDEWEB)

    Kapitul' skii, V B

    1984-07-01

    The hygiene of working conditions is evaluated and compared for coking by-product industry shops using modern technology and machines with those using obsolete equipment and methods. Most basic factors in contamination of atmosphere of coking, pitch-coking and metal-refining shops are coal and coke dust, carbon monoxide and polycyclic aromatic hydrocarbons, especially carcinogenic benzpyrene. Contamination of air of working zone is determined by details of technology: periodicity or continuity of industrial processes, use of improved equipment for smokeless injection of charge into stoves and of hermetic pipes to remove gas with hydraulically operated caps, position of machines in shops and in coal tar distillation removal of carcinogenic benzpyrene by sulfonation and aeration. In modernized shops of coking by-product industry, illness and loss of work capacity are significantly lower than in plants using obsolete methods and equipment. Measures are presented for hygienic improvement of working conditions; both methods to further increase efficiency of technological processes and methods to protect individual worker on job such as use of respirators, protective clothing, plexiglass shields, shampoos and skin creams. 14 references.

  20. Young employees of the coking industry for technological progress

    Energy Technology Data Exchange (ETDEWEB)

    Ladyzhinskii, V.M.; Shul' ga, I.V.

    1986-11-01

    A conference is reported on technology development in the Soviet coking industry held on December 9-10, 1985 at the Khar'kov Scientific-Research Coal-Chemistry Institute. Representatives of leading research institutes and coking plants delivered 25 papers on the following topics: increasing flotation efficiency by means of new flotation reagents, drum feeders for charging cars, new design of coke oven doors, mathematical models of coal transport to coke ovens, some characteristics of packing coal mixtures in coke ovens, heat treatments of coal mixtures at the Khar'kov experimental coking plant, investigating properties of long-flame and gas coal from the Donbaas used for manufacturing formed coke, modernization of the IGI-DMeTI method for determining properties of coal mixtures for formed coke processes, basic problems associated with environmental protection in formed coke processes, specific problems of coal gasification at 900-1050 C and its effects on coking, evaluating properties of formed coke produced from black coal from the Western Donbass for metallurgy, mixing hot briquets with coal slurries during partial briquetting of the coal charge.

  1. Education, training and work experience among nuclear power plant workers

    International Nuclear Information System (INIS)

    Blair, L.M.; Doggette, J.

    1980-01-01

    This paper uses a unique data set to examine the prior work experience, training, and education of skilled and technical workers in United States nuclear power plants. The data were collected in the latter half of 1977 by the International Brotherhood of Electrical Workers (IBEW) in a survey of union locals in nuclear power plants. The survey results provided substantial evidence that workers in United States nuclear power plants have a relatively high level of education, training, and skill development. Analysis of average education by age did not reveal any significant differences in years of schooling between younger and older workers. Very high rates of participation in formal training programmes were reported by all types of workers. The most common type of training programme was held on-site at the power plant and was provided by utility personnel. The majority of workers reported previous work experience related to nuclear power plant activities. Almost one-third of the workers had been directly involved in nuclear energy in a previous job, the majority of these through the United States Navy nuclear programme. However, the newer plants are hiring relatively fewer persons with previous nuclear experience. (author)

  2. Plant trial of a fast neutron and gamma-ray transmission gauge for the on-belt determination of moisture in lump coke

    International Nuclear Information System (INIS)

    Millen, M.J.; Rafter, P.T.; Sowerby, B.D.; Rainbow, M.T.; Jelenich, L.

    1990-01-01

    A fast neutron and γ-ray transmission (FNGT) gauge has been used to determine the moisture content of lump coke on the conveyor belt supplying the No. 3 blast furnace at the BHP Newcastle Steelworks. The gauge was operated on-line over the period June 1988-March 1989. Gauge moisture was compared with laboratory moisture, based on 30 increment composite samples taken from the belt, and with moisture determined by a second FNGT gauge on one of the hoppers feeding the conveyor belt. The r.m.s. difference between conveyor gauge moisture and laboratory moisture was 0.24 wt% during the calibration period for two hopper flow on the belt, which is normal plant condition. The accuracy of the conveyor belt gauge was maintained to within 0.37 wt% moisture over the full period of the plant trial. (author)

  3. Coking industry of China (conclusion of visit to People's Republic of China)

    Energy Technology Data Exchange (ETDEWEB)

    Sklyar, M.G. (NPO Koksokhimiya (USSR))

    1990-12-01

    Presents a report on the coking industry in China, in particular, research programs on coking. The report was prepared by Soviet specialists who visited China in March 1990 within the framework of an exchange program. The following aspects are discussed: characteristics of iron metallurgy and the coking industry in China, research institutes that specialize in problems of iron metallurgy and coking, main research programs of Chinese research institutes (development of a 12-category classification of black coal from China, coal preparation prior to coking including selective crushing, formed coke processes, quality of the products of bituminous coal coking, coal gasification and hydrogenation), installations used for research programs in China (delayed coking of black coal, hydrogenation of long-flame coal, coal briquetting), characteristics of selected coking plants in China, training for specialists in the coking industry in China.

  4. Impact on surface water quality due to coke oven effluents

    International Nuclear Information System (INIS)

    Ghose, M.K.; Roy, S.

    1994-01-01

    Large quantities of water are used for the quenching of hot coke and also for washing the gas produced from the coke ovens. Liquid effluents thus generated are highly polluted and are being discharged into the river Damodar without proper treatment. Four coke plants of Bharat Coking Coal Ltd.(BCCL) have been surveyed for characterization and to assess the impact on surface water quality. About 175-200 kilolitres of waste water is being generated per day by each of the coke plants. The concentration of CO, BOD, COD, TSS, phenol and cyanide in each of the coke plants were found to exceed the limits specified by pollution control board. Ammonia, oil and grease and TDS were found to be 19.33 mg/l, 7.81 mg/l, 1027.75 mg/l respectively. Types of samples collected, sampling frequencies, sample preservation and the results obtained have been discussed. (author). 6 refs., 1 tab., 1 fig

  5. Special analyses reveal coke-deposit structure

    International Nuclear Information System (INIS)

    Albright, L.F.

    1988-01-01

    A scanning electron microscope (SEM) and an energy dispersive X-ray analyzer (EDAX) have been used to obtain information that clarifies the three mechanisms of coke formation in ethylene furnaces, and to analyze the metal condition at the exit of furnace. The results can be used to examine furnace operations and develop improved ethylene plant practices. In this first of four articles on the analyses of coke and metal samples, the coking mechanisms and coke deposits in a section of tube from an actual ethylene furnace (Furnace A) from a plant on the Texas Gulf Coast are discussed. The second articles in the series will analyze the condition of the tube metal in the same furnace. To show how coke deposition and metal condition dependent on the operating parameters of an ethylene furnace, the third article in the series will show the coke deposition in a Texas Gulf Coast furnace tube (Furnace B) that operated at shorter residence time. The fourth article discusses the metal condition in that furnace. Some recommendations, based on the analyses and findings, are offered in the fourth article that could help extend the life of ethylene furnace tubes, and also improve overall ethylene plant operations

  6. System for reducing emissions during coke oven charging

    International Nuclear Information System (INIS)

    Schuecker, Franz-Josef

    2014-01-01

    This article describes a process which reduces emissions from coke production in coke plants. The focus is on the charging process, which can be partly responsible for the fact that statutory emissions limits, which were originally met, are exceeded as coke plants get older. This article presents a solution in the form of a newly developed system that allows the oven charging system - the charging car - to respond to age-related changes in the geometry of a coke oven and thereby reduce the level of emissions.

  7. Hot testing of coke

    Energy Technology Data Exchange (ETDEWEB)

    Balon, I D

    1976-07-01

    Earlier investigations failed to take full account of the factors affecting coke behavior within the blast furnace. An apparatus was accordingly developed for testing coke, based on a cyclone furnace where the sample could be held in a flow of hot oxidizing gases, simulating conditions in the blast furnace hearth. The results are said to be suitable for comprehensive assessment of the coke, including abrasive strength and its rate of gasification in a flow of carbon dioxide. Coke of size 6-10 mm tested at 1,100/sup 0/C in an atmosphere of oxidizing gases close to those obtaining in the blast furnace hearth, indicated that destruction and total gasification of the coke occurs after 5 minutes for a weak coke and 8 minutes for strong coke, depending on the physico-chemical and physico-mechanical properties of the particular coke. When samples were treated for a fixed period (3 minutes), the amount of coke remaining, and the percentage over 6 mm varied between 22 and 40 and between 4 and 7 percent respectively.

  8. Polyphasic bacterial community analysis of an aerobic activated sludge removing phenols and thiocyanate from coke plant effluent

    Energy Technology Data Exchange (ETDEWEB)

    Felfoldi, T.; Szekely, A.J.; Goral, R.; Barkacs, K.; Scheirich, G.; Andras, J.; Racz, A.; Marialigeti, K. [Eotvos Lorand University, Budapest (Hungary). Dept. of Microbiology

    2010-05-15

    Biological purification processes are effective tools in the treatment of hazardous wastes such as toxic compounds produced in coal coking. In this study, the microbial community of a lab-scale activated sludge system treating coking effluent was assessed by cultivation-based (strain isolation and identification, biodegradation tests) and culture-independent techniques (sequence-aided T-RFLP, taxon-specific PCR). The results of the applied polyphasic approach showed a simple microbial community dominated by easily culturable heterotrophic bacteria. Comamonas badia was identified as the key microbe of the system, since it was the predominant member of the bacterial community, and its phenol degradation capacity was also proved. Metabolism of phenol, even at elevated concentrations (up to 1500 mg/L), was also presented for many other dominant (Pseudomonas, Rhodanobacter, Oligella) and minor (Alcaligenes, Castellaniella, Microbacterium) groups, while some activated sludge bacteria (Sphingomonas, Rhodopseudomonas) did not tolerate it even in lower concentrations (250 mg/L). In some cases, closely related strains showed different tolerance and degradation properties. Members of the genus Thiobacillus were detected in the activated sludge, and were supposedly responsible for the intensive thiocyanate biodegradation observed in the system. Additionally, some identified bacteria (e.g. C. badia and the Ottowia-related strains) might also have had a significant impact on the structure of the activated sludge due to their floc-forming abilities.

  9. Using helical compressors for coke gas condensation

    Energy Technology Data Exchange (ETDEWEB)

    Privalov, V E; Rezunenko, Yu I; Lelyanov, N V; Zarnitzkii, G Eh; Gordienko, A A; Derebenko, I F; Venzhega, A G; Leonov, N P; Gorokhov, N N

    1982-08-01

    Coke oven gas compression is discussed. Presently used multilevel piston compressors are criticized. The paper recommends using helical machines which combine advantages of using volume condensing compressors and compact high-efficiency centrifugal machines. Two kinds of helical compressors are evaluated: dry and oil-filled; their productivities and coke oven gas chemical composition are analyzed. Experiments using helical compressors were undertaken at the Yasinovskii plant. Flowsheet of the installation is shown. Performance results are given in a table. For all operating conditions content of insolubles in oil compounds is found to be lower than the acceptable value (0.08%). Compressor productivity measurements with variable manifold pressure are evaluated. Figures obtained show that efficient condensation of raw coke oven gas is possible. Increasing oil-filled compressor productivity is recommended by decreasing amount of oil injected and simultaneously increasing rotation speed. The dry helical compressor with water seal is found to be most promising for raw coke oven gas condensation. (10 refs.)

  10. Effects of thermal desorption on the composition of two coking plant soils: Impact on solvent extractable organic compounds and metal bioavailability

    Energy Technology Data Exchange (ETDEWEB)

    Biache, Coralie [G2R UMR 7566, Nancy Universite, CNRS, Boulevard des Aiguillettes B.P. 239, F-54506 Vandoeuvre-les-Nancy (France); LIMOS UMR 7137, Nancy Universite, CNRS, Boulevard des Aiguillettes B.P. 239, F-54506 Vandoeuvre-les-Nancy (France)], E-mail: coralie.biache@g2r.uhp-nancy.fr; Mansuy-Huault, Laurence; Faure, Pierre [G2R UMR 7566, Nancy Universite, CNRS, Boulevard des Aiguillettes B.P. 239, F-54506 Vandoeuvre-les-Nancy (France); Munier-Lamy, Colette; Leyval, Corinne [LIMOS UMR 7137, Nancy Universite, CNRS, Boulevard des Aiguillettes B.P. 239, F-54506 Vandoeuvre-les-Nancy (France)

    2008-12-15

    To evaluate the efficiency and the influence of thermal desorption on the soil organic compartment, contaminated soils from coking plant sites (NM and H) were compared to their counterparts treated with thermodesorption. The extractable organic matter, and the metal content and distribution with soil compartments were studied. In both thermodesorbed soils, PAH (polycyclic aromatic hydrocarbon) degradation exceeded 90%. However, the thermal desorption led not only to a volatilization of the organic compounds but also to the condensation of extractable organic matter. The treatments only affected the Fe and Zn distribution within the more stable fractions, whereas the organic compound degradation did not affect their mobility and availability. - Thermal desorption does not induce a metal mobilization but condensation seems to occur during the treatment.

  11. Gasification of oil sand coke: review

    Energy Technology Data Exchange (ETDEWEB)

    Furimsky, E. [IMAF Group, Ottawa, ON (Canada)

    1998-08-01

    The production of synthetic crude from the tar sands in Western Canada has been steadily increasing. Most of the delayed coke produced by Suncor is combusted on site, whereas all fluid coke produced by Syncrude is stockpiled.The database on the chemical and physical properties of the oil sand coke, including the composition and fusion properties of the mineral matter, has been established. The reactivity of the coke was determined by oxygen chemisorption, fixed bed and fluid bed bench scale gasification and pilot plant gasification. The reactivity of the oil sand coke for gasification is rather low and comparable to high rank coals, such as anthracite. Slurrability tests revealed that a solid concentration in water, approaching 70 wt%, can be achieved. Gasification is the front runner among clean technologies for the conversion of carbonaceous solids to useful products. Several commercial gasifiers are available to cover the wide range of severity. Because of the low reactivity of oil sands coke, high severity conditions are required to achieve high gasification conversion. Such conditions can be attained in entrained bed gasifiers. Gasifiers employing both dry and slurry feeding systems are suitable. A high efficiency, low SO{sub x} and NO{sub x} emissions, as well as a low solid waste production are among the key advantages of the gasification technology compared with thecompeting technologies. Commercial gasification of oil sands coke is delayed because of the availability of natural gas on the site of the upgrading plants. Potential for the transportation of the oil sand coke to USA for electricity generation using the integrated gasification combined-cycle (IGCC) technology was evaluated. 27 refs., 17 figs., 9 tabs.

  12. Aircraft industry workers in evacuation: conditions of life of evacuated plants' workers in 1941-1945

    Directory of Open Access Journals (Sweden)

    Михаил Юрьевич Мухин

    2010-09-01

    Full Text Available The article is devoted to the work of the factories in 1941-1945 in the evacuation. The author analyzes the living conditions of workers in evacuated aviation plants, their daily life, maintenance, etc. The author concludes that in the early years of the War the conditions of life of the aviation industry's workers were very difficult, and the welfare and financial situation improved in 1944, the sure sign of fracture in the Second world war.

  13. Occupational health programme for lead workers in battery plants

    Science.gov (United States)

    Lee, Byung-Kook

    The realization of problems resulting from the exposure to undue high lead levels of workers in lead-using industries, particularly in storage battery plants, has given rise to a new occupational health service, the so-called type specific (harmful agent specific) group occupational health. In 1988, the Korean Ministry of Labor designated the Institute of Industrial Medicine, Soonchunhyang University, as an authorized organization to take care of lead workers in lead industries. The following occupational health services are provided by the Institute: (i) physical health examination; (ii) biological monitoring with zinc protoporphyrin, urine δ-aminolevulinic acid and blood lead; (iii) respiratory protection with maintenance-free respirators; (iv) measurement of the environmental condition of workplaces; (v) health education. A three-year occupational health programme for lead workers has contributed to improvements in the working conditions of lead industries, particularly in large-scale battery plants, and has decreased the unnecessary high lead burden of workers through on-going medical surveillance with biological monitoring and health education schemes. The strong commitment of both employers and the government to improve the working conditions of lead industries, together with the full cooperation of lead workers, has served to reduce the high lead burdens of lead workers. This decreases the number of lead-poisoning cases and provides more comfortable workplaces, particularly in battery plants.

  14. Polycyclic aromatic hydrocarbon contamination of American lobster, Homarus americanus, in the proximity of a coal-coking plant

    Energy Technology Data Exchange (ETDEWEB)

    Uthe, J F; Musial, C J

    1986-11-01

    Polycyclic aromatic hydrocarbons (PAH) are ubiquitous environmental contaminants resulting predominantly from anthropogenic pyrolytic and combustion processes. In addition to the usual methods of aerial and aqueous transport to the coastal marine environment substantial amounts of PAH are added through the use of products such as creosote, coal tar and coal tar pitch as preservative and antifouling agents in the marine environment. Many PAH compounds are known carcinogenic agents and are rapidly taken up by fish and shellfish from water. Therefore as human foodstuffs many of these shellfish species warrant monitoring for PAH. A study of PAH in lobster tissues has been carried out using lobsters captured in Sydney harbour, Nova Scotia, Canada. Two coal-coking ovens on the shore have discharged their liquid effluents into the harbour. Lobsters from this area were sampled in 1982 and 1984. This paper presents the materials and methods used in the sampling, the results and discussion of them. The results confirmed the ability of lobsters to accumulate extremely high amounts of PAH in their tissues. 14 references.

  15. Mineral matter reactions in cokes

    Energy Technology Data Exchange (ETDEWEB)

    D. French; R. Sakurovs; M. Grigore [CSIRO Energy Technology (Australia)

    2009-07-15

    Some cokes appear to be particularly susceptible to weakening in the blast furnace. A mechanism which has been postulated to explain this is silica reduction by coke. Thus this project was initiated to ascertain the behaviour of quartz and silicates in coke with an emphasis on the role of the clay minerals. It is now possible to obtain quantitative mineralogical data and, the case of coal, to also obtain quantitative data on mineral grain size, shape and association through the use of automated electron beam image analysis techniques. This new ability can allow relationships between the amount of minerals in a coke and its reactivity to be established for the first time. Samples of five Australian coking coals were selected based upon quartz and clay mineral contents, mineral grain size and association. Samples were also provided by BlueScope Steel of coal, feed coke, and tuyere coke samples from the bosh, deadman and raceway regions of the blast furnace. The analytical work program conducted was as follows: Preparation of cokes by CSIRO; Petrography of starting coals and cokes; QEMSCAN of coals; LTA and XRD of starting coals and cokes; Coke reactivity tests (NSC and small scale); Petrography, LTA and XRD of reacted cokes; Petrographic and XRD examination of heat treated cokes. This study indicates that the NSC reactivity test does not adequately reflect the behaviour of coke in the lower part of the blast furnace. Further investigation of the behaviour of coke in the lower part of the blast furnace is required.

  16. Producing metallurgic coke

    Energy Technology Data Exchange (ETDEWEB)

    Abe, T.; Isida, K.; Vada, Y.

    1982-11-18

    A mixture of power producing coals with coal briquets of varying composition is proposed for coking in horizontal chamber furnaces. The briquets are produced from petroleum coke, coal fines or semicoke, which make up less than 27 percent of the mixture to be briquetted and coals with a standard coking output of volatile substances and coals with high maximal Gizeler fluidity. The ratio of these coals in the mixture is 0.6 to 2.1 or 18 to 32 percent, respectively. Noncaking or poorly caking coals are used as the power producing coals. The hardness of the obtained coke is DJ15-30 = 90.5 to 92.7 percent.

  17. [Evaluating work intensity in major and auxiliary occupations of by-product coke industry].

    Science.gov (United States)

    Smagulov, N K; Alpysbayeva, Zh T

    2015-01-01

    The article covers evaluation of work strain in major and auxiliary occupations of by-product coke industry. The study results conclude that occupational activity of by-product coke industry workers, under exposure to occupational hazards, affects the workers' performance. Major occupations workers demonstrate higher level of functional strain of CNS, poor concentration of attention and lower ability to switch over, decreased general performance, vs. the auxiliary occupations workers who demonstrated increased cardiovascular and neuro-muscular strain due to occupational activity.

  18. Impact of co-combustion of petroleum coke and coal on fly ash quality: Case study of a Western Kentucky power plant

    International Nuclear Information System (INIS)

    Hower, James C.; Thomas, Gerald A.; Mardon, Sarah M.; Trimble, Alan S.

    2005-01-01

    Petroleum coke has been used as a supplement or replacement for coal in pulverized-fuel combustion. At a 444-MW western Kentucky power station, the combustion of nearly 60% petroleum coke with moderate- to high-sulfur Illinois Basin coal produces fly ash with nearly 50% uncombusted petroleum coke and large amounts of V and Ni when compared to fly ash from strictly pulverized coal burns. Partitioning of the V and Ni, known from other studies to be concentrated in petroleum coke, was noted. However, the distribution of V and Ni does not directly correspond to the amount of uncombusted petroleum coke in the fly ash. Vanadium and Ni are preferentially associated with the finer, higher surface area fly ash fractions captured at lower flue gas temperatures. The presence of uncombusted petroleum coke in the fly ash doubles the amount of ash to be disposed, makes the fly ash unmarketable because of the high C content, and would lead to higher than typical (compared to other fly ashes in the region) concentrations of V and Ni in the fly ash even if the petroleum coke C could be beneficiated from the fly ash. Further studies of co-combustion ashes are necessary in order to understand their behavior in disposal

  19. Briquetting and coking behavior of Bobov-Dol coal

    Energy Technology Data Exchange (ETDEWEB)

    Naundorf, W.

    1987-01-01

    Hard Bulgarian glance brown coal (23.2% ash content, 16% coal moisture 2.39% sulfur) was studied for its general suitability for partial black coal coke substitution in coking plants and for the possibility of producing pyrolysis briquets for coking purposes. Laboratory briquetting variants include coal briquetting without binders, with sulfite lye as binder, briquetting after partial demineralization by wet classification, briquetting of different screening fractions (0 to 4 mm), briquetting as a mixture with type 35 caking black coal as well as mixed with type 34 less caking black coal under addition of black coal tar, pitch or bitumen. Coking of the briquets produced was carried at with and without charge compacting. Graphs and tables provide briquetting and coking results. It is concluded that high strength coke can be produced from this brown coal, but it can only be used commercially as heating coke due to its high ash and sulfur content. Briquetting and coking of partially demineralized brown coal in a mixture with black coal and binders resulted in suitable metallurgical coke. Maximum percentage of brown coal in the briquetting mixture was 30%. 4 refs.

  20. Utilization of HSC-ROSE residue as coking aid for the production of high quality coke from brown coal

    Energy Technology Data Exchange (ETDEWEB)

    Bohlmann, D.; Limmer, H.; Naundorf, W.; Hood, R.L.; Washimi, K. (VEB Petrolchemisches Kombinat, Schwedt (German Democratic Republic))

    1989-04-01

    Evaluates suitability of HSC-ROSE petroleum pitch as binder for production of brown coal coke. This pitch has been available in the GDR since installation in 1988 of a 750 kt/a HSC (high conversion soaker cracking) plant, which processes 360 C visbreaker residue from Soviet crude oil, and the building of a ROSE (residue oil supercritical reaction) plant. Laboratory as well as semi-industrial experiments were carried out at the Freiberg Academy, GDR on pulverizing, briquetting and coking various brown coal types with HSC-ROSE pitch. Briquetting and coking results are shown in tables. Experiments showed that the resulting coke has 124% higher compression strength and 100% higher abrasion strength than regular brown coal coke without HSC-ROSE binder. The high quality coke is adequate for use as metallurgical blast furnace coke. An economic assessment of modifying an existing brown coal coking plant to process 2 Mt/a brown coal with 10% pitch binder is made. Required investment amounts to 54 million US dollars, estimated annual profits based on 1987 prices are 19.5 million US dollars. 4 refs.

  1. Significance and development of the utilization of brown coal high temperature coke in the economy of the GDR for the period 1964 to 1974

    Energy Technology Data Exchange (ETDEWEB)

    Klose, E.; Heschel, W.

    1979-01-01

    Brown coal high temperature coke production in GDR in the years since 1964 is described. In 1969 the second large brown coal high temperature coking plant, Schwarze Pumpe, went into operation, increasing the total brown coal high temperature coke production to 2 million tons annually. Utilization of the coke size classes in mm from 0-3.15, 3.15-20, 20-31.5, 31.5-45 and greater than 45 mm in the metallurgical, chemical, and energy industries as well as for household heating is shown with figures from 1964, 1970 and 1974. The increasing use of coke in households partly as briquet substitution is also shown (in 1970 42% of the coke was used in households). The substitution of black coal coke by brown coal coke in additional fields of industrial production was also further advanced. Coke production at the Schwarze Pumpe plant is scheduled to increase to 1.6 million tons by 1985 by means of the application of improved coking technologies. Investigations for future industrial solutions to the following coking problems are being conducted: processing coke fines (which make up 10 to 12% of the total produced coke) by briquetting with binders into formed coke, firing coke fines in blast furnaces and power plants, mixed briquetting of coke fines with limestone for carbide production and mixed briquetting of coke and ore fines for metallurgical purposes. (8 refs.) (In German)

  2. Coking oven for continuous coke production

    Energy Technology Data Exchange (ETDEWEB)

    Vabrousek, R

    1979-07-15

    The coking oven has a vertical rectangular chamber with lateral heating walls to which heat exchangers are attached. The roof from the face of the chamber is a hermetic chute, whose vertical walls are connected to the lateral walls of the chamber and which has the feed conveyor with an unloading and evening device; to the upper wall of which a hermetic loading funnel for coal is attached and a lead-off for gas. The bottom of the chamber consists of segmented locks that are taken up by the hermetic chute. The chute's vertical walls are connected to the vertical walls of the chamber and its horizontal wall has a hermetic unloading funnel with a conveyor for coke removal. Height and width of the chamber are similar to standard chambers; their length reaches 100 to 200 m and longer. Length depends on coke preparation time and speed with which the unloading device can transfer coal. For normal operation, the conveyor belt must function properly in conjunction with the unloading device and segmented locks that form the bottom of the chamber.

  3. Full scale treatment of phenolic coke coking waste water under unsteady conditions

    Energy Technology Data Exchange (ETDEWEB)

    Suschka, Jan [Institute for Ecology of Industrial Areas, Katowice (Poland); Morel, Jacek; Mierzwinski, Stanislaw; Januszek, Ryszard [Coke Plant Przyjazn, Dabrowa Gornicza (Poland)

    1993-12-31

    Phenolic waste water from the largest coke coking plant in Poland is treated at a full technical scale. From the very beginning it became evident that very high qualitative variations in short and long periods were to be expected. For this purpose, the biological treatment plant based on activated sludge is protected through preliminary physical-chemical treatment and the results are secured by a final chemical stage of treatment. Nevertheless, improvements in the performance of the treatment plant have been found necessary to introduce. In this work, the experience gained over the last five years is described and developed improvements were presented. 3 refs., 9 figs., 1 tab.

  4. Full scale treatment of phenolic coke coking waste water under unsteady conditions

    Energy Technology Data Exchange (ETDEWEB)

    Suschka, Jan [Institute for Ecology of Industrial Areas, Katowice (Poland); Morel, Jacek; Mierzwinski, Stanislaw; Januszek, Ryszard [Coke Plant Przyjazn, Dabrowa Gornicza (Poland)

    1994-12-31

    Phenolic waste water from the largest coke coking plant in Poland is treated at a full technical scale. From the very beginning it became evident that very high qualitative variations in short and long periods were to be expected. For this purpose, the biological treatment plant based on activated sludge is protected through preliminary physical-chemical treatment and the results are secured by a final chemical stage of treatment. Nevertheless, improvements in the performance of the treatment plant have been found necessary to introduce. In this work, the experience gained over the last five years is described and developed improvements were presented. 3 refs., 9 figs., 1 tab.

  5. Pace studying worldwide coke production

    International Nuclear Information System (INIS)

    Anon.

    1993-01-01

    Pace Consultants Inc., Houston, has started a multiclient study of world-wide petroleum coke production, examining environmental initiatives and eventually forecasting prices of fuel grade coke. Pace expects coker expansions, increased operating severity, and reduced cycle times to boost coke supply to more than 50 million metric tons/year in 2000, compared with 39.7 million metric tons in 1992. Increased supply and tightened environmental rules in countries consuming large amounts of petroleum coke will be the main factors affecting coke markets. The paper discusses coke quality and the Japanese market

  6. Kress indirect dry cooling system, Bethlehem Steel's Coke Plant demonstration at Sparrows Point, Maryland. Volume 2. Appendices G-N. Final report, February 1990-February 1992

    International Nuclear Information System (INIS)

    Ossman, A.G.

    1993-05-01

    The report provides an evaluation of the Kress Indirect Dry Cooling (KIDC) process. The KIDC process is an innovative system for the handling and cooling of coke produced from a slot type by-product coke oven battery. The report is based on the test work and demonstration of the system at Bethlehem Steel Corporation's Sparrows Point facility in 1991. The report covers both environmental and operational impacts of the KIDC process. The report, Volume 2, contains appendices G-N. Volume 1, PB93-191302, contains the technical report as well as appendices A-F. Volume 2 contains appendixes on coke quality data, blast furnace balwax model report, KIDC operating cost and maintenance requirements, Kress box thickness readings, KIDC coke discharge temperature, QA/QC program, door leak data, and coal data

  7. Accuracy and uncertainty analysis of soil Bbf spatial distribution estimation at a coking plant-contaminated site based on normalization geostatistical technologies.

    Science.gov (United States)

    Liu, Geng; Niu, Junjie; Zhang, Chao; Guo, Guanlin

    2015-12-01

    Data distribution is usually skewed severely by the presence of hot spots in contaminated sites. This causes difficulties for accurate geostatistical data transformation. Three types of typical normal distribution transformation methods termed the normal score, Johnson, and Box-Cox transformations were applied to compare the effects of spatial interpolation with normal distribution transformation data of benzo(b)fluoranthene in a large-scale coking plant-contaminated site in north China. Three normal transformation methods decreased the skewness and kurtosis of the benzo(b)fluoranthene, and all the transformed data passed the Kolmogorov-Smirnov test threshold. Cross validation showed that Johnson ordinary kriging has a minimum root-mean-square error of 1.17 and a mean error of 0.19, which was more accurate than the other two models. The area with fewer sampling points and that with high levels of contamination showed the largest prediction standard errors based on the Johnson ordinary kriging prediction map. We introduce an ideal normal transformation method prior to geostatistical estimation for severely skewed data, which enhances the reliability of risk estimation and improves the accuracy for determination of remediation boundaries.

  8. Substitutes for metallurgical coke in pyrometallurgical processes

    Energy Technology Data Exchange (ETDEWEB)

    Koshkarov, V.Ya.

    1982-08-01

    A briquetting process using sulphurous petroleum coke and a bituminous binder is described. The characteristics of briquettes made of petroleum coke, blends of coal and petroleum coke, and coal and metallurgical coke are compared. The prospect of replacing 25 to 50% of the metallurgical coke used in lime kilns with non-calcined petroleum coke briquettes is described. (4 refs.)

  9. Achievements and research programs of the Institute for Chemical Coal Processing in the field of conventional coking

    Energy Technology Data Exchange (ETDEWEB)

    Cieslar, R.; Kaziszyn, I.; Zawistowksi, J.

    1986-11-01

    This paper describes research programs of the Institute for Chemical Coal Processing in Zabrze on black coal coking and coke use in metallurgy from 1955 to 1990. In 1955-1970 the programs concentrated on coal mixture composition (selective crushing), optimization of coking conditions, mechanical coke treatment. In 1971-1980 research concentrated on coal preparation prior to coking and new coking systems for the Katowice steel plant (heat treatments, design of large coke ovens). The following research programs were implemented in 1981-1985: partial coal charge briquetting, production of foundry coke, coal charge preheating, production of blast furnace coke from black coal from Dobiensko, reducing coke consumption of blast furnaces. In 1986-1990 the Institute will concentrate on the following research programs: coal preparation schemes and coking schemes for coking low-quality weakly caking coals, optimization of coke oven design (e.g. use of packed charge), reducing coke consumption in metallurgy and heating systems, reducing air pollution from coking.

  10. 80. special meeting on coke

    Energy Technology Data Exchange (ETDEWEB)

    1986-01-01

    There were 12 papers presented at the special meeting on coke. These have the following headings: relationship between coal properties and optical anisotropic textures of coke; development of optical texture of chemically modified low rank coal; relationship between fluid and swelling properties of Akabira coal; estimation of coal fluidity; present state and future of robotics; on the thermal stress during the carbonisation process of coals; development of estimation model for coke porosity distribution in the coke oven using X-ray CT; carbonization reaction of coke oven; relationship between qualities of coke and width of coke oven; development of carbonization model in coke ovens - estimation of growing clearance between heating wall and charge; development of automatic transparency analyzer for activated sludge process.

  11. Problems of new processes in coking industry discussed at the Scientific Council of the GKNT and the Section of Coking Industry of the Scientific and Technological Council of the Ministry of Iron and Steel Industry of the USSR

    Energy Technology Data Exchange (ETDEWEB)

    Ermolova, V.P.

    1983-03-01

    A report is given from the conference on new processes in the Soviet coking industry held in Moscow on 28-29 October 1982. The following papers were delivered: implementing research programs on new coking processes, new trends in coking plant design and construction in the 11th 5 year plan and in the time period until 1990, increasing efficiency of coking industry, research program of the Scientific Council in 1983. The report concentrates on new trends in coking plant design. Considering that the raw material basis of the Eastern regions of the USSR is poor in high quality coking coal the new coking processes and technologies should use weakly coking coal. The following schemes are discussed: heat treatments (especially useful in the case of black coal from the Kuzbass characterized by intensive fluctuations of petrology), selective crushing (schemes developed by the VUKhIN Institute), partial briquetting of coal mixtures (experiments carried out by the UKhIN in the Donbass in 1982). Other problems of coking such as development of new systems of smokeless fuel feeding to coke ovens, dry coke quenching, increasing capacity of coke chambers to 41.6 m/sup 3/, environmental protection in coking industry and production of special coke types from poor quality coal for metallurgy are also described.

  12. Chromosome aberrations in workers of ignalina nuclear power plant

    Energy Technology Data Exchange (ETDEWEB)

    Griciene, B.; Januskeviciute, I.; Mierauskiene, J.; Slapsyte, G. [Vilnius Univ. (Lithuania)

    2006-07-01

    Full text of publication follows: The Ignalina Nuclear Power Plant (I.N.P.P.) workers and outside workers including visitors constitute the largest occupational group exposed to low doses of ionizing radiation in Lithuania. In 2004, the annual collective dose to these workers (4392 persons) was 6,83 man Sv. The maximum annual individual dose of I.N.P.P. workers was 19,16 mSv, and of outside workers was 29,41 mSv. However, according to calculations performed by the Lithuanian Radiation Protection Centre, the decommissioning of I.N.P.P. (the I.N.P.P. is to be shut down by 2009) will result in collective dose of 35 man Sv. Therefore, a special attention should be given to implementation of radiation protection programme. The importance of cytogenetic studies in the medical surveillance of radiation-exposed persons is generally acknowledged. The aim of the present study was to analyse chromosome aberration frequencies in lymphocytes of I.N.P.P. workers. The blood sampling of 27 male workers was performed in October 2004, after planned outage of I.N.P.P.. It was estimated that outages of I.N.P.P. Units contributed 84% to all annual occupational collective dose. Average cumulative dose of 18 workers was 290,7 mSv (group A), and of 9 workers - 71,7 mSv (group B). The mean annual doses averaged over the three-year-period were 15,2 mSv and 0,76 mSv, respectively. None of the exposed workers had ever exceeded the permissible dose limit. The average age of group A workers was 45,2 years, and group B 48,2 years. A questionnaire form with details on age, occupational history, smoking habit and alcohol intake, medication, history of recent illness was completed for each person at the time of blood collection. 64 non-exposed male donors approximately matched by age were used as controls (group C). Heparinized venous blood samples were taken and cultures were initiated within 24 h according to the standard procedures. At least 500 first cycle metaphases were analysed from each

  13. Chromosome aberrations in workers of ignalina nuclear power plant

    International Nuclear Information System (INIS)

    Griciene, B.; Januskeviciute, I.; Mierauskiene, J.; Slapsyte, G.

    2006-01-01

    Full text of publication follows: The Ignalina Nuclear Power Plant (I.N.P.P.) workers and outside workers including visitors constitute the largest occupational group exposed to low doses of ionizing radiation in Lithuania. In 2004, the annual collective dose to these workers (4392 persons) was 6,83 man Sv. The maximum annual individual dose of I.N.P.P. workers was 19,16 mSv, and of outside workers was 29,41 mSv. However, according to calculations performed by the Lithuanian Radiation Protection Centre, the decommissioning of I.N.P.P. (the I.N.P.P. is to be shut down by 2009) will result in collective dose of 35 man Sv. Therefore, a special attention should be given to implementation of radiation protection programme. The importance of cytogenetic studies in the medical surveillance of radiation-exposed persons is generally acknowledged. The aim of the present study was to analyse chromosome aberration frequencies in lymphocytes of I.N.P.P. workers. The blood sampling of 27 male workers was performed in October 2004, after planned outage of I.N.P.P.. It was estimated that outages of I.N.P.P. Units contributed 84% to all annual occupational collective dose. Average cumulative dose of 18 workers was 290,7 mSv (group A), and of 9 workers - 71,7 mSv (group B). The mean annual doses averaged over the three-year-period were 15,2 mSv and 0,76 mSv, respectively. None of the exposed workers had ever exceeded the permissible dose limit. The average age of group A workers was 45,2 years, and group B 48,2 years. A questionnaire form with details on age, occupational history, smoking habit and alcohol intake, medication, history of recent illness was completed for each person at the time of blood collection. 64 non-exposed male donors approximately matched by age were used as controls (group C). Heparinized venous blood samples were taken and cultures were initiated within 24 h according to the standard procedures. At least 500 first cycle metaphases were analysed from each

  14. Coke quality requirements in POSCO

    Energy Technology Data Exchange (ETDEWEB)

    Song, J.; Yi, J.; Wang, H. [POSCO (Republic of Korea). Cokemaking Dept.

    2001-07-01

    The 26 overheads describes coke quality requirements in POSCO, Republic of Korea. It is concluded that it is necessary to develop new coal and to prompt technical development in order to produce high quality coke. To improve coke quality. Posco had applied DMAIC (define, measurement, analysis, improvement, control) technique which is part of Six-Sigma activity.

  15. Possibilities of using pulverized non coking coals in ironmaking

    Energy Technology Data Exchange (ETDEWEB)

    Wijk, Olle; Mathiesen, Mihkel; Eketorp, Sven

    1977-08-01

    The use of pulverized coal in iron making suggests solutions to the mounting problems created by the increasing scarcity of coking coals, and other fossil fuels such as oil and natural gas. The unavailability of coke can be met with two principally different measures. Blast furnace coke rates can be decreased by substituting injected pulverized coal or other carbon containing fuels for part of the coke burden, and the coke itself may be substituted by formed coke. A more radical solution is to abandon the blast furnace process, and instead produce the raw iron in processes not requiring coke. Two such processes are discussed in the paper, the Inred process, developed by Boliden Kemi AB, Sweden, and the smelting reduction process by means of injection, currently being developed at the Royal Institute of Technology in Stockholm. Both processes have potential advantages over the coke oven/sintering plant/blast furnace-complex especially concerning energy requirements and structure, but also in economical terms. The injection process seems to present a further advantage in the possibility of gasifying coal in the process, thus yielding a synthesis gas for methanol production in addition to the raw iron.

  16. China's coke industry: Recent policies, technology shift, and implication for energy and the environment

    International Nuclear Information System (INIS)

    Huo, Hong; Lei, Yu; Zhang, Qiang; Zhao, Lijian; He, Kebin

    2012-01-01

    China is the largest coke producer in the world, accounting for over 60% of the world coke production, which makes the coke industry in China a significant coal consumer and air pollutant emitter. Recently, China has taken a series of measures to improve energy efficiency and reduce emissions from the coke industry, including eliminating old and low energy-efficiency coking technologies, promoting advanced technologies, and strengthening energy and environmental requirements on coking processes. As a consequence, China's coke industry is experiencing an unprecedented technology shift, which was characterized by the elimination of old, inefficient, and polluting indigenous ovens and small machinery ones within 10 years. This study examines the policies and the prompt technology shift in China's coke industry, as well as the associated energy and environmental effects, and discusses the implications with respect to the development of the coke industry in China towards a more efficient and clean future. As China sets stricter requirements on energy efficiency and the ambient environment, a more significant change focusing on technologies of energy saving and emission reduction is urgently needed at present. Those mature technologies, including coke dry quenching, coke oven gas recycle, fine particle removal, etc., should be enforced in the near future. - Highlights: ► With 60% of world coke output, China's coke making has big energy/pollution issues. ► Actions were taken to improve energy and environmental performance of coke plants. ► China's coke industry is experiencing an unprecedented technology shift. ► Another shift, focusing on technologies of energy and emission saving, is needed. ► More measurement studies on coking emissions are needed given the importance.

  17. Cooperation with COMECON members in coke chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Medricky. Z

    1987-05-01

    Discusses activities of the coking industry division of the standing committee for iron metallurgy of the COMECON. The following cooperation fields are analyzed: raw material basis for coking industry, coal charge preparation and methods for reducing proportion of coking coal in a coal charge (heat treatments, formed coke processes, partial briquetting, pelletizing, increasing coking temperature, packing etc.), coking technology, coke quenching, screening, chemical processing of coal gas, environmental protection in the coking industry, environmental effects of coking, pitch coke production, methods for increasing labor productivity. Research programs coordinated by member countries are reviewed. Programs in which Czechoslovakia participates are discussed.

  18. Record coking coal settlements

    Energy Technology Data Exchange (ETDEWEB)

    Macdonald, C.

    2005-02-01

    The US$100/tonne psychological barrier in coking coal prices has been well and truly smashed. The article examines developments in coal pricing. It includes quotes from many senior executives in the coal industry as collected at McCloskey's Australian Coal.04 conference held in Sydney, 18-19 November 2004. 2 photos.

  19. High coking value pitch

    Science.gov (United States)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  20. Thermal expansion of coking coals

    Energy Technology Data Exchange (ETDEWEB)

    Orlik, M.; Klimek, J. (Vyzkumny a Zkusebni Ustav Nova Hut, Ostrava (Czechoslovakia))

    1992-12-01

    Analyzes expansion of coal mixtures in coke ovens during coking. Methods for measuring coal expansion on both a laboratory and pilot plant scale are comparatively evaluated. The method, developed, tested and patented in Poland by the Institute for Chemical Coal Processing in Zabrze (Polish standard PN-73/G-04522), is discussed. A laboratory device developed by the Institute for measuring coal expansion is characterized. Expansion of black coal from 10 underground mines in the Ostrava-Karvina coal district and from 9 coal mines in the Upper Silesia basin in Poland is comparatively evaluated. Investigations show that coal expansion reaches a maximum for coal types with a volatile matter ranging from 20 to 25%. With increasing volatile matter in coal, its expansion decreases. Coal expansion increases with increasing swelling index. Coal expansion corresponds with coal dilatation. With increasing coal density its expansion increases. Coal mixtures should be selected in such a way that their expansion does not cause a pressure exceeding 40 MPa. 11 refs.

  1. On-line determination of moisture in coke on conveyor belts

    International Nuclear Information System (INIS)

    Millen, M.J.; Rafter, P.T.; Sowerby, B.D.

    1988-01-01

    A fast neutron and γ-ray transmission technique is being developed for the on-line determination of moisture in coke on conveyor belts. Calculations show that the technique is capable of determining coke moisture to within 0.3 wt% for coke thicknesses down to 50 mm provided that count rates are measured to within 0.1% relative. Laboratory measurements on static and moving coke samples showed that coke moisture can be determined to within 0.25 and 0.45 wt% for crushed and lump coke, respectively. It is planned to carry out a long-term plant trial of the technique on lump coke feed to the No. 3 blast furnace at BHP, Newcastle, NSW, Australia. (author)

  2. New technological solutions in construction and operation of batteries with large coke ovens

    Energy Technology Data Exchange (ETDEWEB)

    Volokita, G.I.; Bulyga, N.I.

    1988-11-01

    Describes design modifications to the No. 7 coke oven battery with 7.0 m high coke ovens in the Avdeevka coking plant. Temperature distribution in the large coke ovens was irregular due to the specific design of the heating system, distribution and dimensions of flue channels and thickness of flue channel walls. During coke battery reconstruction length of the peripheral flue channels was reduced by 70 mm, coke oven volume was reduced from 41.6 to 41.3 m/sup 3/. These design changes resulted in a more regular temperature distribution and reduced temperature difference between the coke oven center and zones close to the machine and pusher sides. Thickness of flue channel walls was reduced from 130 to 105 mm. Special reinforcing elements that guarantee more regular temperature distribution and increased wall service life were used.

  3. Adapting the experience of the operating authorities to the coke plant and power plant engineering markets. Adapter l'experience d'exploitants aux marches de l'ingenierie des cokeries et centrales

    Energy Technology Data Exchange (ETDEWEB)

    Robert, B [Charbonnages de France, Paris (France)

    1990-03-01

    Through its own engineering organization, created from the former engineering departments of the Houilleres de Bassins on markets abroad, Charbonnages de France (CdF) is exploiting its specific know-how in the field of extraction and use of coals. This exclusive know-how covers both coal conveying devices and the production of high quality cokes or the construction of power plants using fuels with low calorific values, all fields where CdF's techniques have acquired recognized experience both in design and in operations. This is because, during their careers, most of the engineers in CdF's engineering organization have run installations comparable to those which they are proposing to their clients. Among the recent tasks of CdF's engineering organization, those in the field of cogeneration and of circulating fluidized bed boilders should be given particular mention. In fact, CdF Engineering is the main contractor on the Carling 4 circulating fluidized bed boiler in Lorraine (electric power of 125 MW), and at Gardanne, at the Pechiney Aluminium plant, it constructed the first large industrial boiler of this type installed in France. And finally, it is now building, on the Island of La Reunion, a two-energy power plant, fed by both coal and bagasse (cane residue). 4 figs.

  4. Programmed heating of coke ovens for increased coke size

    Energy Technology Data Exchange (ETDEWEB)

    Jenkins, D.R.; Mahoney, M.R. [University of Newcastle, Callaghan, NSW (Australia)

    2010-11-15

    Large, uniform sized coke is desirable for blast furnace use. It has previously been shown that the coke oven flue temperature in the first few hours of coking is a key determinant of coke size. In this paper, the authors present a new programmed heating approach, which is called pulsed heating, aiming to increase coke mean size at a given average flue temperature. The approach takes into account the charging sequence in coke oven batteries and the authors demonstrate how existing operating practice can be modified in batteries with suitable heating systems to achieve the desired heating programme. A mathematical model of fissure formation provides a prediction of the increase in coke mean size using pulsed heating, compared with standard heating. Pilot scale experiments have also been performed to validate the modelling approach. The results of the modelling indicate that the mean coke size can be increased by several millimetres in some cases, although results from the pilot scale show that pulsed heating increases coke size, but by a smaller amount than that predicted by the model. The potential advantages and limitations of pulsed heating are discussed, as well as opportunities for further investigation of the approach.

  5. Materials for making coke

    Energy Technology Data Exchange (ETDEWEB)

    Kern, L

    1936-08-19

    In the preparation of carbonized fuel briquettes, material such as bituminous, lignitic, or anthracitic coal, slack, waste or shale is treated with an electropositive solution such as hydrochloric acid or an acidic chloride to bring ash-forming constituents into colloidal form. The mixture is pressed with a colloid precipitating electro-negative solution such as sodium hydroxide, and moulded, the product being heated in the absence of air and coked. In an example bituminous coal is ground and then masticated with dilute hydrochloric acid. Some dilute manganese chloride is added followed by a solution of sodium hydroxide which precipitates the metals and silica as colloidal gels while the mixture is thoroughly agitated. The plastic mass is briquetted and dried at about 125/sup 0/C and then coked in vertical ovens at 700/sup 0/C. Chlorides recovered with the distillate gases may be utilized as solvent instead of hydrochloric acid. If the coal contains a large amount of sulfur acidified manganese chloride including a large proportion of iron is used as colloid forming material, the oxides of manganese and iron subsequently precipitated forming stable compounds with the non-volatile sulfur on coking or combustion.

  6. Cancer risk in aluminum reduction plant workers (Canada)

    Energy Technology Data Exchange (ETDEWEB)

    Spinelli, J.J.; Demers, P.A.; Le, N.D.; Friesen, M.D.; Lorenzi, M.F.; Fang, R.; Gallagher, R.P. [British Columbia Cancer Agency, Vancouver, BC (Canada)

    2006-09-15

    A 14-year update to a previously published historical cohort study of aluminum reduction plant workers was conducted. All men with three or more years at an aluminum reduction plant in British Columbia (BC), Canada between the years 1954 and 1997 were included; a total of 6,423 workers. A total of 662 men were diagnosed with cancer, representing a 400% increase from the original study. Standardized mortality and incidence ratios were used to compare the cancer mortality and incidence of the cohort to that of the BC population. Poisson regression was used to examine risk by cumulative exposure to coal tar pitch volatiles (CTPV) measured as benzene soluble materials (BSM) and benzo(a)pyrene (BaP). The risk for bladder cancer was related to cumulative exposure to CTPV measured as BSM and BaP (p trends < 0.001), and the risk for stomach cancer was related to exposure measured by BaP (p trend BaP < 0.05). The risks for lung cancer (p trend < 0.001), non-Hodgkin lymphoma (p trend < 0.001), and kidney cancer (p trend < 0.01) also increased with increasing exposure, although the overall rates were similar to that of the general population. Analysis of the joint effect of smoking and CTPV exposure on cancer showed the observed dose-response relationships to be independent of smoking.

  7. Employment policies at the plant level : job and worker flows for heterogeneous labour in Norway

    OpenAIRE

    Salvanes, Kjell Gunnar

    1999-01-01

    Despite the large degree of plant-specific heterogeneity in turnover patterns recently found in the gross job and worker literature, very little is known about the sources of the heterogeneity in plant level employment policies. The present paper, studies in detail the employment management policies for heterogeneous plants and for heterogeneous labour, using a matched worker-employer data set for Norway. Within an econometric framework, I find that the job and worker flows above ...

  8. System for reducing emissions during coke oven charging; System zur Emissionsverringerung beim Fuellen von Koksoefen

    Energy Technology Data Exchange (ETDEWEB)

    Schuecker, Franz-Josef [ThyssenKrupp Industrial Solutions AG, Dortmund (Germany). Head of Oven Machine Dept., Coke Plant Technologies

    2014-10-01

    This article describes a process which reduces emissions from coke production in coke plants. The focus is on the charging process, which can be partly responsible for the fact that statutory emissions limits, which were originally met, are exceeded as coke plants get older. This article presents a solution in the form of a newly developed system that allows the oven charging system - the charging car - to respond to age-related changes in the geometry of a coke oven and thereby reduce the level of emissions.

  9. Production of rubbly culm coke from lignite

    Energy Technology Data Exchange (ETDEWEB)

    Koenigs, H B [Rheinische Braunkohlenwerke A.G., Koeln (Germany, F.R.). Hauptabteilung Kohleverarbeitung; Kurtz, R [Rheinische Braunkohlenwerke A.G., Frechen (Germany, F.R.). Abt. Verkokung und Chemie

    1977-08-01

    The article deals with the coke supply of the iron and steel industry, the design, function, and special features of the open-hearth, and describes the coking properties and applications of the culm coke produced from lignite.

  10. Production of fine coke from brown coal

    Energy Technology Data Exchange (ETDEWEB)

    Koenigs, H B

    1977-08-01

    The coke supply of the iron and steel industry, the design, function, and special features of the open-hearth are described, including coking properties and applications of the culm coke produced from brown coal. (In German)

  11. Education and training for workers of nuclear power plants

    International Nuclear Information System (INIS)

    Nishikawa, Motoyuki

    1985-01-01

    On the education concerning radiation control for the workers of nuclear power plants, the notice of the Ministry of Labor is to be observed in nuclear power stations from April-June, 1985, and to make the standard for executing it in unified state, the working group was organized in the Federation of Electric Power Companies. It drew up the ''Standard for education on radiation control''. First, the notice from the director of the Labor Standards Bureau, the Ministry of Labor, issued on June 26, 1984, is explained. The objective is to reduce the radiation exposure of workers by giving them the necessary knowledge and skill regarding the works involving radiation. The kinds of the education is divided into that given at the time of beginning the works involving radiation and that given after having taken up the job. Both studies and practical techniques are given. The ''Standard for education on radiation control'' stipulates its objective, the contents of the education, the object persons of education, the requirement for lecturers, the education curriculum, and records. In this standard, the details of education contents are determined. The time limit of the effectiveness of education is determined, and after it has expired, re-education is carried out. (Kako, I.)

  12. Lung cancer among workers at a uranium processing plant

    International Nuclear Information System (INIS)

    Cookfair, D.L.; Beck, W.L.; Shy, C.; Lushbaugh, C.C.; Sowder, C.L.

    1983-01-01

    This study examined the risk of dying from lung cancer among white males who received radiation to the lung as a result of inhaling uranium dust or the dust of uranium compounds. Cases and controls were chosen from a cohort of workers employed in a uranium processing plant during World War II. Cumulative radiation lung dose among study population members ranged from 0 to 75 rads. Relative risk was found to increase with increasing level of exposure even after controlling for age and smoking status, but only for those who were over the age of 45 when first exposed. A statistically significant excess in risk was found for men in this age group with a cumulative lung dose of 20 rads of more. These data suggest that older age groups may be more susceptible to radiation-induced lung cancer than younger age groups

  13. Chromosome analyses of nuclear-power plant workers

    International Nuclear Information System (INIS)

    Bauchinger, M.; Kolin-Gerresheim, J.; Schmid, E.; Dresp, J.

    1980-01-01

    A brief report is given on chromosome aberration analyses of 57 healthy male employees of six German nuclear power plants. All had received annual doses below maximum permissible occupational limit of 5 rem and had worked with radiation for periods ranging from 1 - 14 years. Exposure was mainly due to external sources of γ rays and high energy x radiation. Controls were 11 healthy males with no radiation exposure except natural background. The yields of dicentrics and acentrics were significantly higher than in the unirradiated controls, but no dose dependence was apparent. These results are compared with the dose response dependence of dicentrics + rings found in nuclear dockyard workers by Evans et al. (1979). (U.K.)

  14. Mortality among female workers at a thorium-processing plant

    International Nuclear Information System (INIS)

    Liu, Zhiyuan; Lee, Tze-San.

    1994-01-01

    The mortality patterns among a cohort of 677 female workers at a thorium-processing plant are reported for the period from 1940 to 1982. Of the 677 women, 165 were reported dead; 459 were still alive; and 53 (7.8%) were lost to follow-up. The standardized mortality ratios from all causes (0.74), all cancers (0.53), and circulatory diseases (0.66) were significantly below those for the general US population. In this cohort, 5 deaths due to lung cancer and 1 death from leukemia were observed, with 4.53 and 1.69 deaths expected, respectively. No deaths from cancer of the liver, pancreas, or bone were observed. Poisson regression analysis was used for an internal comparison within the cohort. The results of the Poisson regression analysis showed no significant effect on mortality rates of all causes and cancers from the study factors, including job classification, duration of employment, and time since first employment

  15. Coking of residue hydroprocessing catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Gray, M.R.; Zhao, Y.X. [Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical Engineering; McKnight, C.A. [Syncrude Canada Ltd., Edmonton, AB (Canada); Komar, D.A.; Carruthers, J.D. [Cytec Industries Inc., Stamford, CT (United States)

    1997-11-01

    One of the major causes of deactivation of Ni/Mo and Co/Mo sulfide catalysts for hydroprocessing of heavy petroleum and bitumen fractions is coke deposition. The composition and amount of coke deposited on residue hydroprocessing catalysts depends on the composition of the liquid phase of the reactor. In the Athabasca bitumen, the high molecular weight components encourage coke deposition at temperatures of 430 to 440 degrees C and at pressures of 10 to 20 MPa hydrogen pressure. A study was conducted to determine which components in the heavy residual oil fraction were responsible for coking of catalysts. Seven samples of Athabasca vacuum residue were prepared by supercritical fluid extraction with pentane before being placed in the reactor. Carbon content and hydrodesulfurization activity was measured. It was concluded that the deposition of coke depended on the presence of asphaltenes and not on other compositional variables such as content of nitrogen, aromatic carbon or vanadium.

  16. Consumption of fuels and energy in the coking industry and ways of reducing consumption

    Energy Technology Data Exchange (ETDEWEB)

    Vasil' ev, Yu.S.; Tsel' ik, M.P.; Belkina, T.V. (Khar' kovskii Nauchno-Issledovatel' skii Uglekhimicheski Institut (USSR))

    1989-08-01

    Coking plants in the USSR consume 4,000 million kWh electric energy, 100 million GJ heat energy and 35,000 million m{sup 3} gaseous fuels per year. Structure of energy consumption is the following: 68% gaseous fuels, 24% steam and 8% electric energy. Processes of coal preparation, crushing, mixing, coking and quenching are analyzed from the point of view of energy consumption. The following methods for reducing energy consumption are discussed: using the FM-25 flotation machines for flotation of coking coal slurries, briquetting the whole coal charge for coking, optimization of air supply rates for combustion of gases used for coke oven heating, use of control systems for coke oven heating considering coal charge density, waste heat utilization from quenching. 4 refs.

  17. Investigations on high temperature coking of lignite with the help of radionuclide techniques

    International Nuclear Information System (INIS)

    Koennecke, H.G.; Luther, D.; Abendroth, H.C.

    1986-01-01

    The time characteristics and the varying flow characteristics of fine-grained briquettes during the high temperature coking of lignite according to Rammler and Bilkenroth were studied with the help of radionuclide technique. The process parameters (tsub(V), zsub(R), etc.) refer to the different zones of the coke furnace (bunker/dryer, coker/cooler). The different time charakteristics of the coke-grain fractions formed during the BHT-process enables a correlation of the retention time and the quality factors of the coke. The results obtained would enable a better operation of the individual furnaces in the plant and offer the basis for further process developments. (orig.) [de

  18. Petroleum coke as energy source: an update

    International Nuclear Information System (INIS)

    Pinelli, G.

    2008-01-01

    A previous review presented a critical evaluation of the use of petroleum coke as energy source. After some years, with reference to increased petroleum coke production, that paper is revised. In particular, the attention is now focused on world petroleum coke market trends and, in regard to petroleum coke used as fuel, on new Italian environment laws. [it

  19. The status of contractors workers operating in US nuclear power plants

    International Nuclear Information System (INIS)

    Lochard, J.

    1985-01-01

    The status of contractors operating in PWRs in the United States is described. The statistics concerning the trends of both the individual and collective exposures of these workers were analysed as well as their main demographic and sociological features. The data relative to the particular group of ''transient'' workers, i.e. those operating in several different power plants during the same year were also examined. The results presented show that the dosimetric and sociological profiles of contractors' workers, in US power plants, do not differ fundamentally from that of permanent workers [fr

  20. [Influencing factors for hearing loss in workers exposed to noise in a cement plant].

    Science.gov (United States)

    Wang, X M; Wu, H; Jiao, J; Li, Y H; Zhang, Z R; Zhou, W H; Yu, S F

    2016-12-20

    Objective: To investigate the incidence of noise-induced hearing loss (NIHL) and related influencing factors in workers exposed to noise in a cement plant. Methods: In October 2015, cluster sampling was used for questionnaire investigation and health examination of workers exposed to noise in a cement plant in Henan Province, China. The association of demographic features, living habits, cumulative noise exposure (CNE) , hypertension, and hyperlipidemia with NIHL was analyzed. Results: There was mainly medium-or high-frequency noise in the working place of this cement plant. The prevalence rate of NIHL was 18.4%, and male workers had a significantly higher prevalence rate than female workers (χ(2)=28.09, P workers who smoked had a significantly higher prevalence rate of NIHL than those who did not smoke (χ(2)=14.15, P workers with a drinking habit had a significantly higher prevalence rate of NIHL than those without such habit (χ(2)=7.95, P workers who did not wear earplugs had a significantly higher prevalence rate of NIHL than those who wore earplugs (χ(2)=19.93, P workers with hyperlipidemiahad a significantly higher prevalence rate of NIHL than those without hyperlipidemia (χ(2)=12.43, P workers in a cement plant have a high prevalence rate of NIHL, and CNE, sex, age, degree of education, use of earplugs, and hyperlipidemia may be influencing factors for NIHL.

  1. Application of Activated Sludge Process at Phenol Water Treatment Station in Yanzhou Coal Mine Distract Coking Plant%活性污泥法在兖州矿区焦化厂酚水处理站的应用

    Institute of Scientific and Technical Information of China (English)

    许寒冰; 牟增越

    2001-01-01

    论述活性污泥法处理焦化酚水的若干问题,包括活性污泥的培养、驯化、运行工艺指标、参数,管理中应把握的几个工艺点,运行中常出现的问题及对策,几点探索和体会。%Some of the technical problems of phenol water treatment in coking plant by using the activated sludge process are discussed. These technical problems are including culture, domestication, operation process index of activated sludge; a few of process point control in management; often happened technical problems and countermeasures in operation.

  2. PROSPECTS FOR COKE BREEZE RECOVERY

    Directory of Open Access Journals (Sweden)

    D. N. Mihnovets

    2012-01-01

    Full Text Available Researches give grounds to believe in the possibility of receiving briquettes from coke waste mixed with peat dry coal and their use for smelting iron in the cupola or as a household fuel.

  3. Health Effects of Petroleum Coke

    Science.gov (United States)

    Significant quantities of fugitive dust from pet coke storage and handling operations present a health risk. EPA’s research suggests that petcoke does not pose a different health risk than similar-sized particulate matter (PM10).

  4. Steam versus coking coal and the acid rain program

    International Nuclear Information System (INIS)

    Lange, Ian

    2010-01-01

    The Clean Air Act of 1990 initiated a tradable permit program for emissions of sulfur dioxide from coal-fired power plants. One effect of this policy was a large increase in the consumption of low-sulfur bituminous coal by coal-fired power plants. However, low-sulfur bituminous coal is also the ideal coking coal for steel production. The analysis presented here will attempt to determine how the market responded to the increased consumption of low-sulfur bituminous coal by the electricity generation sector. Was there a decrease in the quality and/or quantity of coking coal consumption or did extraction increase? Most evidence suggests that the market for coking coal was unaffected, even as the extraction and consumption of low-sulfur bituminous coal for electricity generation increased substantially.

  5. Utilization coke dust as fuel in the cement industry

    International Nuclear Information System (INIS)

    Nawaz, S.

    2006-01-01

    Utilization of coke dust available from coal carbonization plants, as a fuel in the cement industry has been undertaken and discussed in this research paper. The parameters studied include physical and chemical evaluation of the coke dust and its economic feasibility/ suitability as fuel for the cement plants. Detailed studies have been carried out on the above referred parameters. In addition a comparative study has been done to access its suitability in comparison to other fuels especially imported coal. It has been found that the coke dust contained about 66% fixed carbon, 29% ash, 4% volatile matter, 1% moisture and 0.48% sulphur. It gross calorific value was found to be 5292 Kcal/kg. The detailed analysis of coke dust ash was also performed to determine as to how its constituents will compare with the cement constituents. Keeping in view the experimental results/ data generated on the coke dust, it has been concluded that it can be quite a good substitute for imported coal. In doing so a substantial financial saving can be achieved which ranges 40-45%. (author)

  6. A study of the performance of a reclamation soil cover placed over an oilsands coke deposit

    Energy Technology Data Exchange (ETDEWEB)

    Fenske, D.S.; Barbour, S.L. [Saskatchewan Univ., Saskatoon, SK (Canada). Dept. of Civil Engineering; Qualizza, C. [Syncrude Canada Ltd., Fort McMurray, AB (Canada)

    2006-07-01

    Coke is a solid, carbonaceous residue that forms during the cracking of high-boiling point distillates and is one of the by-products of petroleum extraction from oilsands. Coke is known as a possible future energy source and therefore, must be stored within the reclaimed landscape in a form that allows it to be recovered. In addition, it also could be used as a low-density capping material over soft tailings. This paper presented the results of a study that examined the effects of coke in the environment. The study involved construction of two small instrumented watersheds at Syncrude Canada's Mildred Lake Settling Basin. Preliminary field data, highlighting the moisture dynamics within the covers and the underlying coke were discussed. Sand tailings underlie the hydraulically placed coke deposit. Overlying the coke were two different reclamation soil covers constructed of a peat/mineral mix over glacial or glacial lacustrine soils. Placing the finer textured soil cover over coarser grained coke produced a textural or capillary break which enhanced moisture storage for plant use while minimizing deep percolation of infiltrating water. The site has been instrumented with a meteorological station; automated soil stations to monitor suction, water content and temperature through the cover profile; lysimeters to collect net percolation; access tubes for water content monitoring; gas sampling points at depth in the coke; and standpipe piezometers to monitor water chemistry and total head in the coke at depth. 10 refs., 2 tabs., 16 figs.

  7. Carbon dioxide emission in hydrogen production technology from coke oven gas with life cycle approach

    Directory of Open Access Journals (Sweden)

    Burmistrz Piotr

    2016-01-01

    Full Text Available The analysis of Carbon Footprint (CF for technology of hydrogen production from cleaned coke oven gas was performed. On the basis of real data and simulation calculations of the production process of hydrogen from coke gas, emission indicators of carbon dioxide (CF were calculated. These indicators are associated with net production of electricity and thermal energy and direct emission of carbon dioxide throughout a whole product life cycle. Product life cycle includes: coal extraction and its transportation to a coking plant, the process of coking coal, purification and reforming of coke oven gas, carbon capture and storage. The values were related to 1 Mg of coking blend and to 1 Mg of the hydrogen produced. The calculation is based on the configuration of hydrogen production from coke oven gas for coking technology available on a commercial scale that uses a technology of coke dry quenching (CDQ. The calculations were made using ChemCAD v.6.0.2 simulator for a steady state of technological process. The analysis of carbon footprint was conducted in accordance with the Life Cycle Assessment (LCA.

  8. Demands for improvement in working surroundings for older workers in nuclear power plants

    International Nuclear Information System (INIS)

    Shizawa, Yasuhiro; Sakuda, Hiroshi; Ohashi, Tomoki

    2003-01-01

    Workers in three nuclear power plants belonging to Kansai Electric Power Co., Inc. were asked to complete a questionnaire. According to the accident reports, workers aged 50 or older had more accidents than those in 30s or 40s. Moreover, it is predicted that the average age of workers in Japan will increase during the first half of the 21st century. Therefore, investigations into working surroundings in which older workers can better perform their work would be useful. To this end, a questionnaire addressing issues related to working surroundings was conducted among workers in nuclear power plants and the demands for improvement of working surroundings for older workers are summarized. The demands of 'better lighting', 'making things less heavy', and installation of an elevator' were correlated with age, indicating that younger people have a tendency not to notice these issues. Thus, if the authority deciding on improvements in working surroundings is not an older worker, it is especially important that lighting, the weights of objects to be moved, and methods of moving between floors is taken into account. Findings specific to nuclear power plants were also reported. For example, employees who worked in the non-radiation controlled area demanded the installation of air conditioning and those who worked in the radiation controlled area demanded the establishment of a rest area. Further, we have developed a guidebook entitled 'a guidebook supporting workers' cooperation among all generations' to promote cooperation between older and younger workers. (author)

  9. Developing new technology of coal coking

    Energy Technology Data Exchange (ETDEWEB)

    Erkin, L.I.; Nefedov, P.Ya.

    1981-03-01

    This paper characterizes types of coke (grain size, compression strength, abrasion, porosity) used by: blast furnaces, shaft furnaces, ferroalloys and phosphorus production, and ore agglomeration. Development of formed metallurgical coke production on the basis of technologies worked out by the Eastern Research Scientific Institute for Coal Chemistry is analyzed. The following phases in the investigations are stressed: optimization of coal blends (increasing proportion of coals with poor caking properties, pressing briquets, carbonization, temperature distribution and temperature control, using heat emitted by hot coke for coal preheating (heat consumption of coking is reduced to 200 kcal/kg). On the basis of technology developed and tested by VUKhIN formed coke consisting of 60% G6 coal and 40% 2SS coal has been produced. Using the coke in blast furnaces increases furnace capacity by 5% and reduces coke consumption in a furnace by 2.6%. It is suggested that wide use of the proposed technology of formed metallurgical coke production in the Kuzbass (using coals with poor caking properties from surface mines) would increase coke production of the region to 50 Mt for a year. technology of producing formed foundry coke from: 80 to 86% anthracites, semianthracites and coals with poor caking properties, 5 to 10% coking coal, and 8% binder is evaluated. Formed foundry coke produced from the blend reduces coke consumption in a foundry by 25 to 30% and increases cast iron temperature by 20 to 50/sup 0/C. Technologies of producing coke for phosphorus industry by continuous coking of coals difficult to coke in vertical coke ovens and production of coke for ore agglomeration are also discussed. (In Russian)

  10. The mechanism of coking pressure generation I: Effect of high volatile matter coking coal, semi-anthracite and coke breeze on coking pressure and plastic coal layer permeability

    Energy Technology Data Exchange (ETDEWEB)

    Seiji Nomura; Merrick Mahoney; Koichi Fukuda; Kenji Kato; Anthony Le Bas; Sid McGuire [Nippon Steel Corporation, Chiba (Japan). Environment and Process Technology Center

    2010-07-15

    One of the most important aspects of the cokemaking process is to control and restrain the coking pressure since excessive coking pressure tends to lead to operational problems and oven wall damage. Therefore, in order to understand the mechanism of coking pressure generation, the permeability of the plastic coal layer and the coking pressure for the same single coal and the same blended coal were measured and the relationship between them was investigated. Then the 'inert' (pressure modifier) effect of organic additives such as high volatile matter coking coal, semi-anthracite and coke breeze was studied. The coking pressure peak for box charging with more uniform bulk density distribution was higher than that for top charging. It was found that the coking pressure peaks measured at different institutions (NSC and BHPBilliton) by box charging are nearly the same. The addition of high volatile matter coking coal, semi-anthracite and coke breeze to a low volatile matter, high coking pressure coal greatly increased the plastic layer permeability in laboratory experiments and correspondingly decreased the coking pressure. It was found that, high volatile matter coking coal decreases the coking pressure more than semi-anthracite at the same plastic coal layer permeability, which indicates that the coking pressure depends not only on plastic coal layer permeability but also on other factors. Coking pressure is also affected by the contraction behavior of the coke layer near the oven walls and a large contraction decreases the coal bulk density in the oven center and hence the internal gas pressure in the plastic layer. The effect of contraction on coking pressure needs to be investigated further. 33 refs., 18 figs., 5 tabs.

  11. Behavior of coke in large blast furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, N

    1978-01-01

    Three blast furnaces were quenched in operation and the contents were examined; the temperature distribution was also measured, using Tempil pellets. The furnaces examined included a low productivity one, which was examined to see what was wrong. Changes in the quality of coke as it descends in the furnace, and coke behavior in the raceway and hearth are reported. The functions required of coke, and the effects of poor coke quality, are explained, together with the coke quality required in large blast furnaces. A theoretical study of the role of coke in large blast furnaces is included.

  12. Estimation of thorium lung burden in mineral separation plant workers by thoron-in-breath measurements

    International Nuclear Information System (INIS)

    Radhakrishnan, Sujata; Sreekumar, K.; Tripathi, R.M.; Puranik, V.D.; Selvan, Esai

    2010-01-01

    The Minerals Separation Plant (MSP) of M/s Indian Rare Earths Ltd. (IREL) at Manavalakurichi in Tamil Nadu is engaged in the processing of beach sands to separate ilmenite, monazite, rutile, sillimanite, garnet, and zircon. The present study has been carried out on nearly 200 workers of the mineral separation plant who are chronically exposed to the radiation hazards. Measurement of thoron in the exhaled breath of the worker is an indirect method of estimating the body burden with regard to Th

  13. Application of flotational reagents obtained from coke-industry byproducts

    Energy Technology Data Exchange (ETDEWEB)

    N.I. Nikitin; I.N. Nikitin; N.I. Toporkova [Khar' kov Polytechnic Institute (Ukraine)

    2007-06-15

    Today, the operational efficiency of coal-preparation shops at coke plants largely depends on the flotation process, since flotation is the basic method of regenerating the slurry water in the water-slurry systems and the basic enrichment process for small-grain coal slurries. At The Coal-Chemistry Institute, attempts have been made to address the growing demand for readily available and relatively inexpensive flotational reagents. In particular, a list of promising coke-industry byproducts for use as flotational reagents has been compiled, and the possibility of reducing their toxicity has been established. In addition, various industrial byproducts and wastes have been investigated in terms of flotational activity.

  14. Projecting labor demand and worker immigration at nuclear power plant construction sites: an evaluation of methodology

    International Nuclear Information System (INIS)

    Herzog, H.W. Jr; Schlottmann, A.M.; Schriver, W.R.

    1981-12-01

    The study evaluates methodology employed for the projection of labor demand at, and worker migration to, nuclear power plant construction sites. In addition, suggestions are offered as to how this projection methodology might be improved. The study focuses on projection methodologies which forecast either construction worker migration or labor requirements of alternative types of construction activity. Suggested methodological improvements relate both to institutional factors within the nuclear power plant construction industry, and to a better use of craft-specific data on construction worker demand/supply. In addition, the timeliness and availability of the regional occupational data required to support, or implement these suggestions are examined

  15. Relationship between coal and coke microstructure and the high temperature properties of coke. [Temperature dependence

    Energy Technology Data Exchange (ETDEWEB)

    Tsuyuguchi, K; Yamaji, M; Sugimoto, Y

    1980-02-01

    This paper considers the relationship of the properties of coke and parent coal with the high temperature properties, including reactivity, of coke. Aspects considered include coke texture and grade, and the optical reflectivity of coal and coke. (8 refs.) (In Japanese)

  16. 46 CFR 148.04-15 - Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture).

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Petroleum coke, uncalcined; petroleum coke, uncalcined and calcined (mixture). 148.04-15 Section 148.04-15 Shipping COAST GUARD, DEPARTMENT OF HOMELAND... Requirements for Certain Material § 148.04-15 Petroleum coke, uncalcined; petroleum coke, uncalcined and...

  17. Dust emission from wet, low-emission coke quenching process

    Science.gov (United States)

    Komosiński, Bogusław; Bobik, Bartłomiej; Konieczny, Tomasz; Cieślik, Ewelina

    2018-01-01

    Coke plants, which produce various types of coke (metallurgical, foundry or heating), at temperatures between 600 and 1200°C, with limited access to oxygen, are major emitters of particulates and gaseous pollutants to air, water and soils. Primarily, the process of wet quenching should be mentioned, as one of the most cumbersome. Atmospheric pollutants include particulates, tar substances, organic pollutants including B(a)P and many others. Pollutants are also formed from the decomposition of water used to quench coke (CO, phenol, HCN, H2S, NH3, cresol) and decomposition of hot coke in the first phase of quenching (CO, H2S, SO2) [1]. The development of the coke oven technology has resulted in the changes made to different types of technological installations, such as the use of baffles in quench towers, the removal of nitrogen oxides by selective NOx reduction, and the introduction of fabric filters for particulates removal. The BAT conclusions for coke plants [2] provide a methodology for the measurement of particulate emission from a wet, low-emission technology using Mohrhauer probes. The conclusions define the emission level for wet quenching process as 25 g/Mgcoke. The conducted research was aimed at verification of the presented method. For two of three quench towers (A and C) the requirements included in the BAT conclusions are not met and emissions amount to 87.34 and 61.35 g/Mgcoke respectively. The lowest particulates emission was recorded on the quench tower B and amounted to 22.5 g/Mgcoke, therefore not exceeding the requirements.

  18. The mechanism of coking pressure generation II: Effect of high volatile matter coking coal, semi-anthracite and coke breeze on coking pressure and contraction

    Energy Technology Data Exchange (ETDEWEB)

    Merrick Mahoney; Seiji Nomura; Koichi Fukuda; Kenji Kato; Anthony Le Bas; David R. Jenkins; Sid McGuire [BHP Billiton Technology, Shortland, NSW (Australia)

    2010-07-15

    One of the most important aspects of the cokemaking process is to control and limit the coking pressure since excessive coking pressure can lead to operational problems and oven wall damage. Following on from a previous paper on plastic layer permeability we have studied the effect of contraction of semi-coke on coking pressure and the effect of organic additives on contraction. A link between contraction (or simulated contraction) outside the plastic layer and coking pressure was demonstrated. The interaction between this contraction, local bulk density around the plastic layer and the dependence of the permeability of the plastic layer on bulk density was discussed as possible mechanisms for the generation of coking pressure. The effect of blending either a high volatile matter coal or one of two semi-anthracites with low volatile matter, high coking pressure coals on the coking pressure of the binary blends has been explained using this mechanism. 25 refs., 10 figs., 4 tabs.

  19. The effect of ash elements in petroleum coke on hearth furnace heat recovery system performance

    Energy Technology Data Exchange (ETDEWEB)

    Akhmetov, M M

    1981-01-01

    Difficulties encountered in the operation of the heat recovery system of a calcination plant at Krasnovodsk Refinery caused by ash element deposits blocking the fire box are described. Deposits and coke ash composition are given. The main cause of blocking was found to be the removal of sea water salt elements which get on the coke surface when the retarded coking plant is discharged with a water-jet borer. Switching over to fresh water and air-blasting of heat recovery pipes decreased blocking considerably.

  20. Repair of walls of coke ovens with a volume of 41. 6 m/sup 3/

    Energy Technology Data Exchange (ETDEWEB)

    Pyatnitsa, V.A.; Bulyga, N.I.

    1988-11-01

    Discusses repair of coke oven walls and the heating system of a battery with coke ovens 7.0 m high in the Avdeevka plant. The following problems are evaluated: types of wall deformation and wear, distribution of wear zones, zones with maximum wear, coke oven repair without cooling and with cooling, repair of cracks in oven walls, effects of wall temperature (in schemes without cooling) on repair, behavior of walls in zones of temperature differences, sequence of repair operations, repair of heating channels, specific problems of wall repair at the machine side and at the pusher side of a coke oven battery, methods for reducing repair time, materials used for coke oven repair.

  1. Trends in the automation of coke production

    Energy Technology Data Exchange (ETDEWEB)

    R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

  2. Major growth in coke production takes place

    International Nuclear Information System (INIS)

    Swain, E.J.

    1991-01-01

    U.S. petroleum coke production has increased 64% during the 10-year period from 1980 to 1990. This dramatic rise makes it timely to discuss the history and future of U.S. coking capacity, production, and processing. The article covers the properties and uses of the various grades of petroleum coke, as well as pricing and market trends

  3. Power, cement industries shape coke future

    International Nuclear Information System (INIS)

    Swain, E.J.

    1991-01-01

    The production of petroleum coke by U.S. refineries is expected to continue to increase in the coming years. Process and market trends also indicate the likelihood of further increases in fuel-grade coke production. In this article, the properties and uses of the various grades of petroleum coke, as well as pricing and market trends, will be discussed

  4. Feasibility study on mental healthcare using indoor plants for office workers

    Science.gov (United States)

    Kubota, Tsuyoshi; Matsumoto, Hiroshi; Genjo, Kaori; Nakano, Takaoki

    2017-10-01

    In recent years, it has become a problem that office workers' stresses affect their intellectual productivity. As one of strategies mitigating the stress while working, many studies on the effect of indoor plants introduced into the office have been conducted. The psychological and physiological effects of indoor plants have been expected to mitigate the office workers' stresses. Also, the effects of green amenities such as improvement of productivity, control of the indoor thermal environment, relaxation and recovery of visual fatigue, and improvement of air quality have been expected. In this study, a field investigation on the green amenity effects of indoor plants on office workers' psychological and physiological responses in an actual office was conducted and discussed. This paper describes the measurement results of the physical environment and workers' psychological and physiological responses under the condition with shelves installed with indoor plants in an office room. It was suggested that indoor plants such as mint, basil and begonia, and a combination of red and green plants were effective for mitigating worker's stresses.

  5. Safety and health education and training of contract workers in nuclear power plants

    International Nuclear Information System (INIS)

    Matsumoto, Akikuni; Hara, Hisayuki; Nawata, Kazumitsu

    2008-01-01

    Nuclear power plants have used many contract workers. Their safety and health conditions are very important in Japan. Several amendments, which deregulate temporary personnel service and employment agency markets, have been done in recent years. The number of contract and temporary help agency workers have been rapidly increasing especially since the 1990s. As a result, ensuring the level of safety and health education and training of workers becomes a serious problem. This paper examines the possibility that the level of safety training of the contract workers is less than that of the direct-hire employees in nuclear power plants. We show that (1) the use of contract workers could be less efficient for ensuring the level of safety training, and (2) nuclear power plants still use contract workers in some situations in spite of the loss of efficiency. We also study legislations and past cases relating to nuclear power generation. We find that there are some structural problems that might make the contract workers less trained. (author)

  6. Concerning the structure of occupational accidents involving construction workers in the erection of nuclear power plants

    International Nuclear Information System (INIS)

    Nowak, B.; Roebenack, K.D.

    1991-01-01

    An investigation of 561 occupational accidents involving construction workers which took place during the construction of nuclear power plants failed to show any significant deviation in comparison with general construction as regards process classification, classification of accidents according to occupation and situation, and accidents severity. Occupational accidents which are typial for nuclear power plant construction are a rare exception. (orig.) [de

  7. Mortality and career radiation doses for workers at a commercial nuclear power plant: feasibility study

    International Nuclear Information System (INIS)

    Goldsmith, R.; Boice, J.D. Jr.; Hrubec, Z.; Hurwitz, P.E.; Goff, T.E.; Wilson, J.

    1989-01-01

    Career radiation doses for 8,961 male workers at the Calvert Cliffs Nuclear Power Plant (CCNPP) were determined for both utility (n = 4,960) and contractor (n = 4,001) employees. Workers were followed from the time of first employment at CCNPP (including plant construction) to the end of 1984 (mean follow-up = 5.4 y). Plant operation began in 1975. The mean duration of employment was 1.9 y at CCNPP and 3.1 y in the nuclear industry. Career radiation doses were determined from dosimetry records kept by the utility company and the U.S. Nuclear Regulatory Commission (NRC). For all exposed workers, the average career dose was 21 mSv and was higher for contractor (30 mSv) than utility (13 mSv) workers. Career doses were also higher among those employed in the nuclear industry for greater than or equal to 15 y (111 mSv) and among workers classified as health physicists (56 mSv). Cumulative doses of greater than or equal to 50 mSv were received by 12% of the workers; the maximum career dose reported was 470 mSv. The availability of social security numbers for practically all employees facilitated record-linkage methods to determine mortality; 161 deaths were identified. On average the workers experienced mortality from all causes that was 15% less than that of the general population of the U.S., probably due to healthier members of the population being selected for employment. Our investigation demonstrates that historical information is available from which career doses could be constructed and that, in principle, it is feasible to conduct epidemiologic studies of nuclear power plant workers in the U.S. Although difficult, the approach taken could prove useful until such time as a comprehensive registry of U.S. radiation workers is established

  8. Bio-coke as an alternative to petroleum coke and metallurgical coke; Bio-cokes als alternatief voor petroleumcokes en metallurgische cokes

    Energy Technology Data Exchange (ETDEWEB)

    Croezen, H.J.; Van Lieshout, M. [CE Delft, Delft (Netherlands); Sevenster, M.N. [Sevenster Environmental Consultancy, Australian Capital Territory ACT (Australia)

    2012-11-15

    In the framework of elaborating the Dutch Roadmap Chemistry 2030), CE Delft has conducted an exploratory study for the Association of the Dutch Chemical Industry (VNCI) on the options of replacing (petroleum) coke in the chemical sector by biocokes. Coke is used as a reducing agent and/or raw material in four companies in the Dutch chemical industry (Tronox, ESD-SIC, Thermphos, Aluchemie). Replacing coke at these four companies can potentially yield a direct CO2 reduction of expectedly several hundreds of kilotons per year. For a first exploration of the options of bio-coke, CE Delft first conducted a desk study to get information on the quality and production costs for bio-coke. Subsequently, CE Delft had contact with the four chemical companies and a made a number of company visits. Moreover, the technical, economic and organizational capabilities, constraints and requirements with regard to a possible (partial) switch to biocokes have been explored. Based on the information available so far it can be concluded that biocokes seems to be a technically and economically interesting innovation. For implementation to finally take place, it is necessary to gain better insight in the technical and economic potential [Dutch] In verband met de uitwerking van de Routekaart Chemie 2030 heeft CE Delft voor VNCI een verkenning uitgevoerd naar de mogelijkheden voor vervanging van (petroleum)cokes in de chemische sector door biocokes. Cokes wordt gebruikt als reductiemiddel en/of grondstof bij een viertal bedrijven in de Nederlandse chemie (Tronox, ESD-SIC, Thermphos, Aluchemie). Het vervangen van cokes bij deze vier bedrijven kan in potentie een directe CO2-reductie van naar verwachting enkele honderden kilotonnen/jaar opleveren. Voor een eerste verkenning van de mogelijkheden van bio-cokes heeft CE Delft eerst een bureaustudie uitgevoerd naar informatie over kwaliteit van en productiekosten voor bio-cokes. Vervolgens heeft CE Delft contact gehad met de vier chemische

  9. Estimation of unit risk for coke oven emissions

    International Nuclear Information System (INIS)

    Moolgavkar, S.H.; Luebeck, E.G.; Anderson, E.L.

    1998-01-01

    In 1984, based on epidemiological data on cohorts of coke oven workers, USEPA estimated a unit risk for lung cancer associated with continuous exposure from birth to 1 microg/m 3 of coke oven emissions, of 6.2 x 10 -4 . This risk assessment was based on information on the cohorts available through 1966. Follow-up of these cohorts has now been extended to 1982 and, moreover, individual job histories, which were not available in 1984, have been constructed. In this study, lung cancer mortality in these cohorts of coke oven workers with extended follow-up was analyzed using standard techniques of survival analysis and a new approach based on the two stage clonal expansion model of carcinogenesis. The latter approach allows the explicit consideration of detailed patterns of exposure of each individual in the cohort. The analyses used the extended follow-up data through 1982 and the detailed job histories now available. Based on these analyses, the best estimate of unit risk is 1.5 x 10 -4 with 95% confidence interval = 1.2 x 10 -4 --1.8 x 10 -4

  10. Prediction of operating parameters range for ammonia removal unit in coke making by-products

    Science.gov (United States)

    Tiwari, Hari Prakash; Kumar, Rajesh; Bhattacharjee, Arunabh; Lingam, Ravi Kumar; Roy, Abhijit; Tiwary, Shambhu

    2018-02-01

    Coke oven gas treatment plants are well equipped with distributed control systems (DCS) and therefore recording the vast amount of operational data efficiently. Analyzing the stored information manually from historians is practically impossible. In this study, data mining technique was examined for lowering the ammonia concentration in clean coke oven gas. Results confirm that concentration of ammonia in clean coke oven gas depends on the average PCDC temperature; gas scrubber temperatures stripped liquor flow, stripped liquor concentration and stripped liquor temperature. The optimum operating ranges of the above dependent parameters using data mining technique for lowering the concentration of ammonia is described in this paper.

  11. Geostatistical characterization of soil pollution at industrial sites Case of polycyclic aromatic hydrocarbons at former coking plants; Caracterisation geostatistique de pollutions industrielles de sols cas des hydrocarbures aromatiques polycycliques sur d'anciens sites de cokeries

    Energy Technology Data Exchange (ETDEWEB)

    Jeannee, N

    2001-05-15

    Estimating polycyclic aromatic hydrocarbons concentrations in soil at former industrial sites poses several practical problems on account of the properties of the contaminants and the history of site: 1)collection and preparation of samples from highly heterogeneous material, 2) high short scale variability, particularly in presence of backfill, 3) highly contrasted grades making the vario-gram inference complicated. The sampling strategy generally adopted for contaminated sites is based on the historical information. Systematic sampling recommended for geostatistical estimation is often considered to be excessive and unnecessary. Two former coking plants are used as test cases for comparing several geostatistical methods for estimating (i) in situ concentrations and (ii) the probability that they are above a pollution threshold. Several practical and methodological questions are considered: 1) the properties of various estimators of the experimental vario-gram and the validity of the results; 2) the use of soft data, such as historical information, organoleptic observations and semi-quantitative methods, with a view to improve the precision of the estimates; 3) the comparison of standard sampling strategies, taking into account vertical repartition of grades and the history of the site. Multiple analyses of the same sample give an approximation of the sampling error. Short scale sampling shows the difficulty of selecting soils in the absence of a spatial structure. Sensitivity studies are carried out to assess how densely sampled soft data can improve estimates. By using mainly existing models, this work aims at giving practical recommendations for the characterization of soil pollution. (author)

  12. Geostatistical characterization of soil pollution at industrial sites Case of polycyclic aromatic hydrocarbons at former coking plants; Caracterisation geostatistique de pollutions industrielles de sols cas des hydrocarbures aromatiques polycycliques sur d'anciens sites de cokeries

    Energy Technology Data Exchange (ETDEWEB)

    Jeannee, N.

    2001-05-15

    Estimating polycyclic aromatic hydrocarbons concentrations in soil at former industrial sites poses several practical problems on account of the properties of the contaminants and the history of site: 1)collection and preparation of samples from highly heterogeneous material, 2) high short scale variability, particularly in presence of backfill, 3) highly contrasted grades making the vario-gram inference complicated. The sampling strategy generally adopted for contaminated sites is based on the historical information. Systematic sampling recommended for geostatistical estimation is often considered to be excessive and unnecessary. Two former coking plants are used as test cases for comparing several geostatistical methods for estimating (i) in situ concentrations and (ii) the probability that they are above a pollution threshold. Several practical and methodological questions are considered: 1) the properties of various estimators of the experimental vario-gram and the validity of the results; 2) the use of soft data, such as historical information, organoleptic observations and semi-quantitative methods, with a view to improve the precision of the estimates; 3) the comparison of standard sampling strategies, taking into account vertical repartition of grades and the history of the site. Multiple analyses of the same sample give an approximation of the sampling error. Short scale sampling shows the difficulty of selecting soils in the absence of a spatial structure. Sensitivity studies are carried out to assess how densely sampled soft data can improve estimates. By using mainly existing models, this work aims at giving practical recommendations for the characterization of soil pollution. (author)

  13. The new coke oven battery heating control system at Rautaruukki Steel

    Energy Technology Data Exchange (ETDEWEB)

    Palmu, P.; Swanljung, J. [Rautaruukki Steel, Raahe (Finland)

    1998-07-01

    The heating control system of the coke oven batteries has been developed strongly during the existence of the coke oven plant. The first step of the heating control was a statistical model which had a good monitoring system. This was enough in those days due to bigger problems elsewhere. The second generation heating control system is designed for irregular coke oven battery operation. Coke production in Rautaruukki Steel is based on one coke-oven plant consisting of two batteries and a by-product plant. The whole coke production is cooled by three dry quenching units. The first coke-oven battery was taken into operation in October 1987 and the second in November 1992. Originally the plant was mainly designed and equipped by Ukrainian Giprokoks except Finnish CDQ-boilers, German ammonia recovery process and electric and automation designed by Rautaruukki. Before building of the second coke oven battery, there was a huge amount of development and modification work to do, to ensure the proper function of the coke production. For example all electronic and hydraulic systems of the Russian supplier were replaced by systems designed by Rautaruukki's own personnel. When the coke production capacity was doubled, the only design by Gibrokoks related to the battery and one additional dry quenching chamber. The expansion project itself was managed and executed by Rautaruukki. The expansion project consisted of: the second battery, third CDQ-unit, Desulphurization and Benzol plants for the by-product plant and upgrading of automation system. Battery and CDQ chamber refractory materials were Russian origin and all other main equipment were purchased by Rautaruukki from western and domestic manufacturers based on the operation difficulties and experience of coke oven battery No. 1. These modification practices made a good basis for later development in the field of coke oven battery automation. The hierarchy of the coke oven battery automation at Rautaruukki Steel consist

  14. Wage Differentials between Foreign Multinationals and Local Plants and Worker Quality in Malaysian Manufacturing

    OpenAIRE

    Eric D. Ramstetter

    2014-01-01

    Using industrial census data for 2000, and smaller sets of survey data for 2001–2004, this paper examines the extent of wage differentials between medium-large (20 or more workers) foreign multinational enterprises (MNEs) and local plants in Malaysia's manufacturing industries. On average, wages in sample MNEs were higher than in local plants by two-fifths or more. In addition to being more capital-intensive and relatively large, MNEs also hired higher shares of workers in highly paid occup...

  15. Wage Differentials between Foreign Multinationals and Local Plants and Worker Quality in Malaysian Manufacturing

    OpenAIRE

    エリック D., ラムステッター; Eric D. , Ramstetter

    2013-01-01

    Using industrial census data for 2000, and smaller sets of survey data for 2001-2004, this paper examines the extent of wage differentials between medium-large (20 or more workers) foreign multinational enterprises (MNEs) and local plants in Malaysia’s manufacturing industries. On average, wages in sample MNEs were higher than in local plants by two-fifths or more. MNEs also hired higher shares of workers in highly paid occupations and with moderate or high education, in addition to being mor...

  16. Commonalty initiatives in US nuclear power plants to improve radiation protection culture and worker efficiency

    International Nuclear Information System (INIS)

    Wood, W.; Miller, D.

    2003-01-01

    Many US nuclear power plants have learned that common procedures, policies, instrumentation, tools and work practices achieve improvements to the radiation protection culture. Significant worker efficiency achievements are accomplished especially during refuelling outages. This paper discusses commonalty initiatives currently being implemented at many US Plants to address management challenges presented by deregulation of the US electric industry, reduction in the pool of outage contractors and aging of the experienced radiation worker population. The new INPO 2005 dose goals of 650 person-mSv/year for PWRs and 1200 person-mSv/yr for PWRs will require new approaches to radiation protection management to achieve these challenging goals by 2005. (authors)

  17. Musculoskeletal disorders among workers in plastic manufacturing plants.

    Science.gov (United States)

    Fernandes, Rita de Cássia Pereira; Assunção, Ada Avila; Silvany Neto, Annibal Muniz; Carvalho, Fernando Martins

    2010-03-01

    Epidemiological studies have indicated an association between musculoskeletal disorders (MSDs) and physical work demands. Psychosocial work demands have also been identified as possible risk factors, but findings have been inconsistent. To evaluate factors associated with upper back, neck and upper limb MSD among workers from 14 plastic manufacturing companies located in the city of Salvador, Brazil. A cross-sectional study design was used to survey a stratified proportional random sample of 577 workers. Data were collected by questionnaire interviews. Factor analysis was carried out on 11 physical demands variables. Psychosocial work demands were measured by demand, control and social support questions. The role of socio-demographic factors, lifestyle and household tasks was also examined. Multiple logistic regression was used to identify factors related to upper back, neck and upper limb MSDs. Results from multiple logistic regression showed that distal upper limb MSDs were related to manual handling, work repetitiveness, psychosocial demands, job dissatisfaction, and gender. Neck, shoulder or upper back MSDs were related to manual handling, work repetitiveness, psychosocial demands, job dissatisfaction, and physical unfitness. Reducing the prevalence of musculoskeletal disorders requires: improving the work environment, reducing biomechanical risk factors, and replanning work organization. Programs must also be aware of gender specificities related to MSDs.

  18. Respiratory symptoms and pulmonary function tests in security and safety products plant workers.

    Science.gov (United States)

    Balbay, Ege Gulec; Toru, Umran; Arbak, Peri; Balbay, Oner; Suner, Kezban Ozmen; Annakkaya, Ali Nihat

    2014-01-01

    Lock and key factory workers are under the risk of metal pneumoconiosis and occupational asthma. In this cross-sectional study, it's aimed to evaluate the relationship between metal dust exposure and respiratory symptoms, pulmonary function tests of workers in different section of lock and key factory. 54 male workers (mean age, 32.8 ± 5.4) in a security and safety products plant were evaluated for respiratory symptoms, pulmonary function tests and smoking habits. Results have been interpreted by comparison of the painting (28/54) and grinding group workers (26/54). There was no significant difference between painting (32.1 ± 4.8) and grinding (33.6 ± 6.1) groups regarding mean age (P > 0.05). Smokers were in significantly higher in grinding group (18/26). Cough and sputum were reported 14.3% (4/28) in painting and 3.8% (1/26) in grinding workers (P > 0.05). Chest tightness was seen in 7.1% and 7.7% of painting and grinding workers, respectively (P > 0.05). But no chest tightness was reported in both groups when they were away work. Breathlessness was seen in 10.7% and 7.7% of painting and grinding workers, respectively (P > 0.05). Breathlessness was similar in both groups (7.1% vs. 3.8%) when they were away work. When comparing painting and grinding workers respiratory functions no significant difference observed. Chest radiography in painting and grinding workers showed hyperlucency (3.6% vs.11.4%), respectively. Painting groups in lock and key factory workers had more but statistically insignificantrespiratory complaints. Interestingly, chest tightness was only observed when both groups were at work. It was thought that ventilation and using personal protective equipment in factory could provide significant benefits.

  19. Exposure to trinitrotoluene and health effects among workers in an artillery and ammunition plant.

    Science.gov (United States)

    Kongtip, Pornpimol; Preklang, Smart; Yoosook, Witaya; Chantanakul, Suttinun

    2012-06-01

    To determine urinary trinitrotoluene (TNT), 2-amino-4, 6-dinitrotoluene (2ADNT) and 4-amino-2, 6-dinitrotoluene (4ADNT) and health effects upon workers in an ammunition plant. The urine samples from forty munition workers and forty office workers were monitored for TNT and its metabolites by gas chromatography-mass spectrometry. The workers were interviewed with a questionnaire. The median levels of TNT and its metabolites were 112.84 and ranged from non-detectable (ND) to 1,833.81 mg/L. Median levels for 2ADNT were 11.66, ranging from ND to 360.89 mg/L. Median levels for 4ADNT were 19.95 and ranged from ND to 314.28 mg/L. There were significant correlations between TNT and 2ADNT in urine (r = 0. 700, p-value workers reported eye, nose and throat irritations, weakness and headaches with considerably higher frequency than non-exposed workers. TNT levels in urine were strongly associated with 4ADNT and 2ADNT levels. Workers exposed to TNT complained of nose, throat and eye irritation, along with overall weakness and headaches.

  20. Fissure formation in coke. 2: Effect of heating rate, shrinkage and coke strength

    Energy Technology Data Exchange (ETDEWEB)

    D.R. Jenkins; M.R. Mahoney [CSIRO, North Ryde, NSW (Australia). Mathematical and Information Sciences

    2010-07-15

    We investigate the effects of the heating rate, coke shrinkage and coke breakage strength upon the fissure pattern developed in a coke oven charge during carbonisation. This is done principally using a mechanistic model of the formation of fissures, which considers them to be an array of equally spaced fissures, whose depth follows a 'period doubling' pattern based upon the time history of the fissures. The model results are compared with pilot scale coke oven experiments. The results show that the effect of heating rate on the fissure pattern is different to the effect of coke shrinkage, while the effect of coke breakage strength on the pattern is less pronounced. The results can be seen in both the shape and size of resulting coke lumps after stabilisation. The approach gives the opportunity to consider means of controlling the carbonisation process in order to tune the size of the coke lumps produced. 7 refs., 18 figs., 4 tabs.

  1. [Relationship between job satisfaction and occupational stress in the workers of a thermal power plant].

    Science.gov (United States)

    Gu, Gui-zhen; Yu, Shan-fa; Zhou, Wen-hui

    2011-12-01

    To explore the relationship between job satisfaction and occupational stress in the workers of a thermal power plant. The cluster sampling method was used to investigate 875 workers in a thermal power plant. The job satisfaction, occupational stressors, strains, personalities, meeting strategy and social support were measured using occupational stress instruments, job content questionnaire and effort-reward imbalance questionnaire. There were no significant differences of job satisfaction scores between different groups according to sex, educational level, marriage status, smoking and drinking (P > 0.05). But there were significant differences of job satisfaction scores between different age groups or between different service length groups (P responsibility for persons and things, promotion opportunity, job control, job stabilization, rewards, mental health, positive affectivity, self-esteem, superior support and coworker support scores (P responsibility for persons and things, promotion opportunity, job control, job stabilization, reward, mental health, positive affectivity, self-esteem and buffer scores of the workers with high job satisfaction scores were significantly higher than those of workers with moderate and lower job satisfaction scores (P four times as high as that for workers with high reward (OR = 3.773), the risks of job dissatisfaction for workers with low social support and mental locus of external work control were about two times as high as that for workers with high social support or mental locus of internal work control (OR = 2.419 and 2.219, respectively). The daily life stress, low control strategy, low support strategy, low job control and negative affectivity were risk factors of job dissatisfaction (OR = 1.125 approximately 1.790), but the self-esteem and positive affectivity could reduce the risk of job dissatisfaction. Increasing the decision level, social support, meeting strategy and reward or decreasing the role conflict and

  2. 75 FR 11920 - General Electric Lighting-Ravenna Lamp Plant, Lighting Division, Including On-Site Leased Workers...

    Science.gov (United States)

    2010-03-12

    ... to the production of high intensity discharge lamps. The review shows that on August 24, 2007, a...-Ravenna Lamp Plant, Lighting Division, Including On-Site Leased Workers from Devore Technologies, Ravenna..., 2009, applicable to workers of General Electric Lighting-Ravenna Lamp Plant, Lighting Division...

  3. 75 FR 38127 - Visteon Systems, LLC North Penn Plant Electronics Products Group Including On-Site Leased Workers...

    Science.gov (United States)

    2010-07-01

    ..., North Penn Plant, Electronics Products Group to be covered by this certification. The intent of the... North Penn Plant Electronics Products Group Including On-Site Leased Workers From Ryder Integrated... Certification Regarding Eligibility To Apply for Worker Adjustment Assistance and Alternative Trade Adjustment...

  4. The world coke market. Problems and outlook

    International Nuclear Information System (INIS)

    Anon.

    1998-01-01

    Outlooks to the world coke market are considered with regard to supply and demand as well as the current state of capacities for its production in some countries of Asia, Western and Eastern Europe, USA. In experts opinion increase of coke import from China, increase in service life of currently operating coke furnaces, as well as more extensive use of PCI coal mixture are among the most feasible opportunities for its Western consumers [ru

  5. Change in airway inflammatory markers in Danish energy plant workers during a working week

    Directory of Open Access Journals (Sweden)

    Yuduo Zheng

    2014-09-01

    Full Text Available [b]Introduction.[/b] It is well known that exposure to organic dust can cause adverse respiratory effect. The pathogen-associated molecular patterns (PAMPS in the organic dust, such as endotoxin from Gram-negative bacteria cell wall and fungal components, can trigger the release of cytokine (e.g. Interleukin 1β (IL-1β and chemokine (e.g. Interleukin 8 (IL-8 from the immune cells in the airways. [b]Objective.[/b] To evaluate the potential inflammatory effects of organic dust exposure in energy plants in Denmark. [b]Materials and methods[/b]. Nasal lavage (NAL and exhaled breath condensate (EBC were sampled at Monday morning (referred to as before work and again at Thursday afternoon (referred to as after work. NAL IL-8, EBC pH, IL-1β concentration were measured. Personal exposure to endotoxin and dust was calculated from time spent on different tasks and measured average work area exposures. [b]Results.[/b] Before work, workers from biofuel plants had a higher IL-1β and IL-8 concentration compared to conventional fuel plants (control group. Specifically, the IL-1β level of moderately and most exposed group, and IL-8 level of the least exposed group were higher compared to the control group. The changes of IL-1β, pH and IL-8 during a work week were not significant. Workers with rhinitis had a lower percentage change of IL-8 compared to healthy workers. [b]Conclusions[/b]. An increased level of EBC IL-1β in biofuel energy plant workers before work indicated a chronic or sub-chronic inflammation. The percentage change of IL-8 was lower in workers with rhinitis compared to healthy workers.

  6. Briquetting of Coke-Brown Coal Mixture

    Directory of Open Access Journals (Sweden)

    Ïurove Juraj

    1998-09-01

    Full Text Available The paper presents the results of the research of briquetting a coke-brown coal composite The operation consists of the feeding crushed coal and coke to moulds and pressing into briquettes which have been made in the Laboratories at the Mining Faculty of Technical University of Košice (Slovakia. In this research, all demands will be analyzed including the different aspects of the mechanical quality of briquettes, the proportion of fine pulverulent coal and coke in bricks, the requirements for briquetting the coke-brown coal materials.

  7. Effect of oxide film of heat resistant alloy on coke formation during naphtha pyrolysis

    International Nuclear Information System (INIS)

    Shiratori, Nobuo; Hosoya, Keizo

    2002-01-01

    The coking of cracking furnace tubes has been an important subject of ethylene plants. The coke formations rate on the heat resistant alloys of 20Cr-4.5Al-0.5Y 2 O 3 covered with Al 2 O 3 oxide film and 25Cr-35Ni covered with Cr 2 O 3 oxide film during the thermal cracking of naphtha was quantitatively evaluated at temperatures ranging from 810 to 930 .deg. C. The experimental results showed that the coke formation rate on 20Cr-4.5Al-0.5Y 2 O 3 was lower than that on 25Cr-35Ni because of the difference of a catalytic activity to coke formation, especially in the case of a pre-carburized condition. Namely, the Al 2 O 3 formed on 20Cr-4.5Al-0.5Y 2 O 3 was stable even after carburization treatment and inert for catalytic coke formation, while coke formation on 25Cr-35Ni was under the control of catalytic coke formation, and carburization of 25Cr-35Ni accelerated catalytic coke formation. The stability of Al 2 O 3 and Cr 2 O 3 in a hydrocarbon with steam environment was thermodynamically calculated in 0.1mol of steam, 0.2mol of ethylene and 0.1mol of methane at 1,100 .deg. C. The simulation result shows that Al 2 O 3 is exceedingly stable while Cr 2 O 3 could be decomposed partially into chromium carbide. Therefore, it is concluded that Al 2 O 3 on 20Cr-4.5Al-0.5Y 2 O 3 is more stable than Cr 2 O 3 on 25Cr-35Ni, and 20Cr-4.5Al-0.5Y 2 O 3 is more resistant to coke formation and carburization than 25Cr-35Ni in a hydrocarbon with steam environment at high temperature

  8. Research and development in production of special coke types

    Energy Technology Data Exchange (ETDEWEB)

    Nefedov, P.Ya.; Unterberger, O.G.; Strakhov, V.M. (Vostochnyi Nauchno-Issledovatel' skii Uglekhimicheskii Institut (USSR))

    1991-03-01

    Discusses methods for increasing quality of foundry coke and quality of special coke types used in non-ferrous metallurgy. Types of coal from various coal basins for production of foundry coke, types of petroleum and coal-derived additives improving caking and coking properties of the standard coal mixtures and effects of partial coal charge briquetting are discussed. Three types of partial coal charge briquetting are comparatively evaluated: continuous coking of the briquetted mixtures of weakly caking lean coal types, anthracites and coking coal mixed with thermosoftening binders; continuous coking of identical mixtures briquetted with non-thermosoftening binders; coking coke dust mixed with thermoreactive binders and briquetted at 200-300 C. Coking conditions, the final coking temperature, binder consumption rates, dimensions of coal briquets, ash content, sulfur content and coke mechanical properties (compression strength and wear) are comparatively evaluated.

  9. Production of blast furnace coke from soft brown coal

    Energy Technology Data Exchange (ETDEWEB)

    Scholz, G.; Wundes, H.; Schkommodau, F.; Zinke, H.-G. (VEB Gaskombinat Schwarze Pumpe (German Democratic Republic))

    1988-01-01

    Reviews experimental production and utilization of high quality brown coal coke in the GDR during 1985 and 1986. The technology of briquetting and coking brown coal dust is described; the superior parameters of produced coke quality are listed in comparison to those of regular industrial coke made from brown and black coal. Dust emission from high quality brown coal coke was suppressed by coke surface treatment with dispersion foam. About 4,200 t of this coke were employed in black coal coke substitution tests in a blast furnace. Substitution rate was 11%, blast furnace operation was positive, a substitution factor of 0.7 t black coal coke per 1 t of brown coal coke was calculated. Technology development of high quality brown coal coke production is regarded as complete; blast furnace coke utilization, however, requires further study. 8 refs.

  10. Research and development of SCOPE21 (super coke oven for productivity and environment enhancement towards the 21st century)

    Energy Technology Data Exchange (ETDEWEB)

    Oshima, H.; Otsuka, J.; Nishioka, K.; Kamijo, T. [Japan Iron and Steel Federation, Tokyo (Japan)

    2000-07-01

    Coke ovens in Japan have 28 years of service on the average and the supply of coke is foreseen to suffer a shortage at the early years of the 21st century. Furthermore, the existing cokemaking process entails a lot of issues such as an effective use of coal resources, an adverse effect on environment. Thus, the Japan Iron and Steel Federation has launched a 9 year research programme called SCOPE 21 in collaboration with the Center for Coal Utilization, Japan in 1994. The programme pursues the following targets. The use ratio of poor coking coal increases from 20-50% with the improvement of coking property of coal by rapid heating and the increase of bulk density by mixing the briquetted coal. The coking time is reduced by rapid heating to 350 to 400{degree}C at the preheater, coking up to 750-850{degree}C at oven chamber, and reheating up to 1000{degree}C at the upgrading chamber, thus trebling productivity. The environment of coke oven is improved by emission free system and by improving the heating system of coke oven to reduce NOx in oven exhaust gas. After two years of preliminary feasible study the programme has advanced to basic research and to a bench scale test. It is in a stage of the construction of a pilot plant. This report describes the outline of the programme and the results obtained through the basic research and the bench scale plant tests. 2 refs., 17 figs., 5 tabs.

  11. Soil sanitation in the course of rehabilitation measures for an abandoned colliery and coking plant site in the anthracite region of Aachen

    International Nuclear Information System (INIS)

    Blesken, M.; Reisinger, H.

    1993-01-01

    The sanitation measures for the contaminated industrial site ''Carolus Magnus'' consists of three components, thermal treatment, securing measures and ground water treatment. Within 1 1/2 years 50000 t of contaminated soil were treated in the thermal plant, 6000 m 3 of less contaminated soil were deposited in a secured deposit site and 70000 m 3 of uncontaminated material which dropped out during the separation process were relocated for landscapping. (orig.)

  12. New designs in the reconstruction of coke-sorting systems

    Energy Technology Data Exchange (ETDEWEB)

    A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

  13. Lung Cancer Mortality among Uranium Gaseous Diffusion Plant Workers: A Cohort Study 1952–2004

    Directory of Open Access Journals (Sweden)

    LW Figgs

    2013-07-01

    Full Text Available Background: 9%–15% of all lung cancers are attributable to occupational exposures. Reports are disparate regarding elevated lung cancer mortality risk among workers employed at uranium gaseous diffusion plants. Objective: To investigate whether external radiation exposure is associated with lung cancer mortality risk among uranium gaseous diffusion workers. Methods: A cohort of 6820 nuclear industry workers employed from 1952 to 2003 at the Paducah uranium gaseous diffusion plant (PGDP was assembled. A job-specific exposure matrix (JEM was used to determine likely toxic metal exposure categories. In addition, radiation film badge dosimeters were used to monitor cumulative external ionizing radiation exposure. International Classification for Disease (ICD codes 9 and 10 were used to identify 147 lung cancer deaths. Logistic and proportional hazards regression were used to estimate lung cancer mortality risk. Results: Lung cancer mortality risk was elevated among workers who experienced external radiation >3.5 mrem and employment duration >12 years. Conclusion: Employees of uranium gaseous diffusion plants carry a higher risk of lung cancer mortality; the mortality is associated with increased radiation exposure and duration of employment.

  14. Training in radiation protection of workers at Electricite de France nuclear power plants

    International Nuclear Information System (INIS)

    Aye, Louis

    1980-01-01

    The safety of workers and the population is a major concern of the nuclear industry. In order to carry out its programme of PWR power plants, Electricite de France has largely developed the training in radiation protection of its personnel. Operation workers now represent some 5000 persons; they first receive a formation organized at the national level consisting in training courses, which are completed and continued on the spot. The training makes a wide use of audiovisuals; it is checked by tests and leads to better qualification. Close coordination is sought with outside competent organizations [fr

  15. Assessment of chronic neuropsychological effects of mercury vapour poisoning in chloral-alkali plant workers.

    Science.gov (United States)

    Pranjić, Nurka; Sinanović, Osman; Karamehić, Jasenko; Jakubović, Rusid

    2002-12-01

    A prospective case study was conducted in the Department of Occupational Medicine, Tuzla. The purpose of this study was to indicate negative effects from occupational exposure to mercury on behavioural and mental health, memory and psychomotor function that was tested in 46 chloral-alkali plant workers (mean age was 38. 8+/- 5. 7 years; mean age of occupational history 16. 5+/- 6. 0 years). Data on toxicological monitoring on atomic absorption spectrometer, and data on mental health were collected, psychiatric and other subjective symptoms, and behavioural, psychomotor and memory function tested. The data were compared to control group, 32 healthy non exposed workers. The study was designed to assess blood and urine mercury levels and length of occupational exposure and investigate its relationships to effects on the mental health. The mean air mercury levels were 0.23 mg/m3, the mean blood mercury concentrations was 3. 6 mg/ dl and the mean urine mercury concentrations were 151.7 +/- 180.4 mg/l. In 25 (53%) workers exposed to mercury vapour was identified Depression-Hypochondrias Syndrome (p trend 2. 9 mg/ dl, or urine mercury levels > 87 mg/l workers exposed to mercury vapour knew that toxic effects in body resulted in loosing some of intellectual abilities, and that people who handle chemicals had an increased health risk (ESW questionnaire). The occupational mercury exposed workers had introvert behaviour (EPQ). Aggressiveness was found in 71.7% workers. The cognitive disturbances: short-term memory loss, difficult to concentrate on tasks which require attention and thinking, were significantly differed compared to those of controls (p trend < 0. 001). In 24 (52%) exposed to mercury workers we have determined ego strength loss and regressive defensive mechanisms (LB). Handwriting disturbances-micrography we have identified in 27 (58.7%) workers.

  16. Combined effects of ototoxic solvents and noise on hearing in automobile plant workers in Iran.

    Science.gov (United States)

    Mohammadi, Saber; Labbafinejad, Yasser; Attarchi, Mirsaeed

    2010-09-01

    Exposure of workers to mixtures of organic solvents and to occupational noise is frequent in a number of industries. Recent studies suggest that exposure to both can cause a more severe hearing loss than exposure to noise alone. Our cross-sectional study included 411 workers of a large automobile plant divided in three groups. The first group included assembly workers exposed to noise alone; the second included workers in a new paint shop, who were exposed to a mixture of organic solvents at a permissible level; and the third group included paint shop workers exposed to both noise and higher than permissible levels of organic solvents in an old paint shop. These groups were compared in terms of low-frequency hearing loss (model 1; average hearing threshold >25 dB at 0.5 kHz, 1 kHz, and 2 kHz) and high-frequency hearing loss (model 2; average hearing threshold >25 dB at 3 kHz, 4 kHz, 6 kHz, and 8 kHz). High-frequency hearing loss was more common in workers exposed to a combination of noise and mixed organic solvents even at permissible levels than in workers exposed to noise alone even after correction for confounding variables. This study shows that combined exposure to mixed organic solvents and occupational noise can exacerbate hearing loss in workers. Therefore, an appropriate hearing protection programme is recommended, that would include short-interval audiometric examinations and efficient hearing protectors.

  17. The effect of calcination conditions on the graphitizability of novel synthetic and coal-derived cokes

    Science.gov (United States)

    Bennett, Barbara Ellen

    The effects of calcination heating rate and ultimate calcination temperature upon calcined coke and subsequent graphitic material microstructures were studied for materials prepared from three different precursors. The pitch precursors used were Mitsubishi AR pitch (a synthetic, 100% mesophase pitch), the NMP-extracted portion of a raw coal, and the NMP-extracted fraction of a coal liquefaction residue obtained from an HTI pilot plant. These materials were all green-coked under identical conditions. Optical microscopy confirmed that the Mitsubishi coke was very anisotropic and the HTI coke was nearly as anisotropic. The coke produced from the direct coal extract was very isotropic. Crystalline development during calcination heating was verified by high-temperature x-ray diffraction. Experiments were performed to ascertain the effects of varying calcination heating rate and ultimate temperature. It was determined that calcined coke crystallite size increased with increasing temperature for all three materials but was found to be independent of heating rate. The graphene interplanar spacing decreased with increasing temperature for the isotropic NMP-extract material but increased with increasing temperature for the anisotropic materials---Mitsubishi and HTI cokes. Graphene interplanar spacing was also found to be independent of heating rate. Calcined coke real densities were, likewise, found to be independent of heating rate. The anisotropic cokes (Mitsubishi and HTI) exhibited increasing real density with increasing calcination temperature. The NMP-extract coke increased in density up to 1050°C and then suffered a dramatic reduction in real density when heated to 1250°C. This is indicative of puffing. Since there was no corresponding disruption in the crystalline structure, the puffing phenomena was determined to be intercrystalline rather than intracrystalline. After the calcined cokes were graphitized (under identical conditions), the microstructures were re

  18. Study of Real Time Location System For Worker in Containment Building at Nuclear Power Plant

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S. Y.; Kim, G. S. [Samchang Enterprise Company, Ulsan (Korea, Republic of); Kim, H. S. [Ulsan Univ., Ulsan (Korea, Republic of)

    2012-03-15

    Workers are required special management to minimize radiation exposure in nuclear power plant. Especially, there are many limitation in their activities at containment building in nuclear power plant. Test personnel shall administer the workers by tracing the location of them inside containment building in nuclear power plant. They may be exposed to the unnecessary radiation due to a complex and high radiation area in the building. Test personnel needs to manage efficiently for worker's safety and work hours at containment building. Therefore, it is critical for the test personnel to notice the risk to the workers by identifying the location when the workers are facing the dangerous situation on the high area. In this paper, we introduce requirements and design method to develop the one and two dimensional RTLS(Real Time Locating System) by using CSS(Chirp Spread Spectrum) which enables precise location measurement and robust data communication even indoor environment with serious electromagnetic interference caused by complicated structure such as the inside of containment building in the nuclear power plant. In the algorithm to compute the distance, it is suggested to use SDS-TWR(Symmetrical Double-Sided Two-Way Ranging) to solve the issue of indirect routes, and develop the power circuit with 10mW of designing gain for output power to meet the KCC standard in order to increase the raging distance, in addition, communication between Anchor and distance measuring computer shall be designed to increase energy using time of Tags(nodes) by using CAN(Controller Area Network) communication.

  19. Production of conductive coke for cathodic protection

    Energy Technology Data Exchange (ETDEWEB)

    Mogollon, E.G.; Henao, L.E.; Pacheco, L.A.; Ortiz, J.L.; Diaz, J.J. [Universidad Nacional de Colombia, Bogota (Colombia). Departamento de Quimica

    1999-07-01

    The reduction of resistivity of coke by means of the cocarbonization of mixtures of coking coals was studied using coal tar as an additive. Optimum temperature and blending conditions for decreased resistivity were investigated. The effect of particle size on the dependency of coal rank was investigated. 2 refs., 4 figs., 2 tabs.

  20. Q Fever Outbreak among Workers at a Waste-Sorting Plant.

    Directory of Open Access Journals (Sweden)

    Eva Alonso

    Full Text Available An outbreak of Q fever occurred in February-April 2014 among workers at a waste-sorting plant in Bilbao (Spain. The outbreak affected 58.5% of investigated employees, 47.2% as confirmed cases (PCR and/or serology and 11.3% as probable cases (symptoms without laboratory confirmation. Only employees who had no-access to the waste processing areas of the plant were not affected and incidence of infection was significantly higher among workers not using respiratory protection masks. Detection by qPCR of Coxiella burnetii in dust collected from surfaces of the plant facilities confirmed exposure of workers inside the plant. Animal remains sporadically detected among the residues received for waste-sorting were the most probable source of infection. After cleaning and disinfection, all environmental samples tested negative. Personal protection measures were reinforced and made compulsory for the staff and actions were taken to raise farmers' awareness of the biological risk of discharging animal carcasses as urban waste.

  1. Microwave-assisted grinding of metallurgical coke

    International Nuclear Information System (INIS)

    Ruisanchez, E.; Juarez-Perez, E. J.; Arenillas, A.; Bermudez, J. M.; Menendez, J. A.

    2014-01-01

    Metallurgical cokes are composed of graphitic carbon (s2p2) and different inorganic compounds with very different capacities to absorb microwave radiation. Moreover, due to the electric conductivity shown by the metallurgical cokes, microwave radiation produces electric arcs or microplasmas, which gives rise to hot spots. Therefore, when these cokes are irradiated with microwaves some parts of the particle experiment a rapid heating, while some others do not heat at all. As a result of the different expansion and stress caused by thermal the shock, small cracks and micro-fissures are produced in the particle. The weakening of the coke particles, and therefore an improvement of its grind ability, is produced. This paper studies the microwave-assisted grinding of metallurgical coke and evaluates the grinding improvement and energy saving. (Author)

  2. Benzole still reflux system - Dawes Lane Coke Ovens

    Energy Technology Data Exchange (ETDEWEB)

    Hardwick, J.

    2005-07-01

    The paper describes a project carried out at Dawes Lane coking plant (in Scunthorpe, UK) to access current performance of the batch reflux system with respect to the operation of personnel and to recommend a solution to eliminate naphthalene blockage and problems previously caused by the use of hot debenzolised oil (DBO) as make-up. A successful solution was found and implemented. The benzole product now being produced is within specification and regularly achieves the composition produced by the previous hot reflux system (83% benzole, 7% naphthalene) with an addition reduction in wash oil usage of 20%. Problems of naphthalene blockages in reflux pipework have been cured. The expenses on the project were small. The paper was presented at a COMA meeting at Monckton Coke Ovens on 19 May 2005. 6 figs.

  3. Job characteristics and musculoskeletal pain among shift workers of a poultry processing plant in Southern Brazil.

    Science.gov (United States)

    Barro, Dânia; Olinto, Maria Teresa Anselmo; Macagnan, Jamile Block Araldi; Henn, Ruth Liane; Pattussi, Marcos Pascoal; Faoro, Mariana Wentz; Garcez, Anderson da Silva; Paniz, Vera Maria Vieira

    2015-01-01

    The purpose of this study was to evaluate the association between job characteristics and musculoskeletal pain among shift workers employed at a 24-hour poultry processing plant in Southern Brazil. This was a cross-sectional study of 1,103 production line workers aged 18-52 years. The job characteristics of interest were shift (day/night), shift duration, and plant sector ambient temperature. Musculoskeletal pain was defined as self-reported occupational-related pain in the upper or lower extremities and trunk, occurring often or always, during the last 12 months. The mean (SD) participant age was 30.8 (8.5) years, and 65.7% of participants were women. The prevalence of musculoskeletal pain was greater among female participants than male participants. After adjustment for job characteristics and potential confounders, the prevalence ratios (PR) of lower extremity musculoskeletal pain among female workers employed in extreme-temperature conditions those working the night shift, and those who had been working longer on the same shift were 1.75 (95% CI 1.12, 2.71), 1.69 (95% CI 1.05, 2.70), and 1.64 (95% CI 1.03, 2.62), respectively. In male workers, only extreme-temperature conditions showed a significant association with lower extremity musculoskeletal pain (PR=2.17; 95% CI 1.12, 4.22) after adjustment analysis. These findings suggest a need for implementation of measures to mitigate the damage caused by nighttime work and by working under extreme temperature conditions, especially among female shift workers, such as changing positions frequently during work and implementation of rest breaks and a workplace exercise program, so as to improve worker quality of life.

  4. Factors influencing workers to follow food safety management systems in meat plants in Ontario, Canada.

    Science.gov (United States)

    Ball, Brita; Wilcock, Anne; Aung, May

    2009-06-01

    Small and medium sized food businesses have been slow to adopt food safety management systems (FSMSs) such as good manufacturing practices and Hazard Analysis Critical Control Point (HACCP). This study identifies factors influencing workers in their implementation of food safety practices in small and medium meat processing establishments in Ontario, Canada. A qualitative approach was used to explore in-plant factors that influence the implementation of FSMSs. Thirteen in-depth interviews in five meat plants and two focus group interviews were conducted. These generated 219 pages of verbatim transcripts which were analysed using NVivo 7 software. Main themes identified in the data related to production systems, organisational characteristics and employee characteristics. A socio-psychological model based on the theory of planned behaviour is proposed to describe how these themes and underlying sub-themes relate to FSMS implementation. Addressing the various factors that influence production workers is expected to enhance FSMS implementation and increase food safety.

  5. Solar thermochemical production of syngas from petroleum coke: feasibility study for injection of coke slurries

    International Nuclear Information System (INIS)

    Vidal, A.; Romero, M.; Kritter F; Steinfeld A

    2006-01-01

    The steam-gasification of pet-coke using concentrated solar radiation is proposed as a viable alternative to solar hydrogen production. Pet-coke is major solid byproduct from the processing of heavy and extra-heavy oils using delay-coking technology. This report summarizes the major accomplishments to develop a cheap and efficient feeding of petroleum coke by coke water slurries without the need of a carrier gas. The samples were Delayed coke of different grain sizes, in particular from 1,8 to 200 mm (as received). In order to analyse the flow properties of the slurries, some tests were conducted to measure the viscosity of the samples. Then, the pet-coke water slurries were injected into the reactor to study the gasification process. In these experiments, some operational parameters were: molar ratio from 2 to 3 (water/coke), temperature up to 1000 C, residence times from 5 to 9 s. In those conditions, the coke is converted primarily to CO, H 2 , CO 2 and small amounts of methane. Concentration of outlet gases of about 30-50 of H 2 ; 15-20 of CO, 10-15 CO 2 , 1-2% CH 4 were obtained with X coke ∼ 65 to 85%. (authors)

  6. Effect of moisture on the accuracy of coke-ash determination by X-ray backscattering

    International Nuclear Information System (INIS)

    Pandey, H.D.; Prasad, M.S.

    1984-01-01

    Effect of moisture on the rapid non-destructive estimation of ash content in coal specimens using the X-ray backscattering technique has been studied extensively by various workers. In the present work, an attempt has been made to estimate its influence when the technique is extended to coke-ash determinations. From the study of the variation of backscattered intensity with change in the moisture content of a coke specimen, it is observed that the ash content varies significantly at moisture levels higher than 5%. The variation, however, remains within allowable limits if the moisture level is kept below 5%. This observation is confirmed by the actual measurement of ash percentages in thirteen coke specimens containing three different states of moisture levels viz. (i) in the dry state, (ii) with 5% moisture and (iii) with 10% moisture. (author)

  7. Does the use of biofuels affect respiratory health among male Danish energy plant workers?

    DEFF Research Database (Denmark)

    Schlünssen, Vivi; Madsen, Anne Mette; Skov, Simon

    2011-01-01

    were collected by questionnaire. Spirometry, metacholine provocation tests and skin prick tests were performed on 310 workers. The work area concentrations of ‘total dust’ (n=181), airborne endotoxin (n=179), cultivable Aspergillus fumigatus (n=373) and cultivable fungi (n=406) were measured at each...... plant. Personal exposure was calculated from the time spent on different tasks and average work area exposures. Results Median (range) average personal exposures in biofuel plants were 0.05 (0 to 0.33) mg/m3 for ‘total’ dust and 3.5 (0 to 294) endotoxin units/m3 for endotoxin. Fungi were cultivated from...

  8. Coking

    Energy Technology Data Exchange (ETDEWEB)

    Simpson, D; Simpson, A

    1917-03-08

    Oil is obtained from bituminous shales and the like by downward distillation at such restricted temperature that the volatile products only are obtained without liberation of the so-called fixed carbon, the distilled vapors being treated in a de-sulfurizing reaction chamber subsequent to being condensed into oil.

  9. Determination of electrical resistivity of dry coke beds

    Energy Technology Data Exchange (ETDEWEB)

    Eidem, P.A.; Tangstad, M.; Bakken, J.A. [NTNU, Trondheim (Norway)

    2008-02-15

    The electrical resistivity of the coke bed is of great importance when producing FeMn, SiMn, and FeCr in a submerged arc furnace. In these processes, a coke bed is situated below and around the electrode tip and consists of metallurgical coke, slag, gas, and metal droplets. Since the basic mechanisms determining the electrical resistivity of a coke bed is not yet fully understood, this investigation is focused on the resistivity of dry coke beds consisting of different carbonaceous materials, i.e., coke beds containing no slag or metal. A method that reliably compares the electrical bulk resistivity of different metallurgical cokes at 1500{sup o} C to 1600{sup o}C is developed. The apparatus is dimensioned for industrial sized materials, and the electrical resistivity of anthracite, charcoal, petroleum coke, and metallurgical coke has been measured. The resistivity at high temperatures of the Magnitogorsk coke, which has the highest resistivity of the metallurgical cokes investigated, is twice the resistivity of the Corus coke, which has the lowest electrical resistivity. Zdzieszowice and SSAB coke sort in between with decreasing resistivities in the respective order. The electrical resistivity of anthracite, charcoal, and petroleum coke is generally higher than the resistivity of the metallurgical cokes, ranging from about two to about eight times the resistivity of the Corus coke at 1450{sup o}C. The general trend is that the bulk resistivity of carbon materials decreases with increasing temperature and increasing particle size.

  10. 78 FR 8587 - American Showa, Inc.; Blanchester Plant, Including On-Site Leased Workers From Adecco and Sims...

    Science.gov (United States)

    2013-02-06

    ....; Blanchester Plant, Including On-Site Leased Workers From Adecco and Sims Bros., Inc.; Blanchester, OH; Amended... workers from Sims Bros., Inc. were working on-site at the subject firm during the relevant period and that the services supplied by Sims Bros., Inc. were related to the production of gear boxes (and parts...

  11. 75 FR 22627 - Chrysler LLC, St. Louis North Assembly Plant Including On-Site Leased Workers From HAAS TCM, Inc...

    Science.gov (United States)

    2010-04-29

    ... North Assembly Plant Including On-Site Leased Workers From HAAS TCM, Inc., Logistics Services, Inc., Robinson Solutions, Logistics Management Services, Inc., Corrigan Company and Murphy Company, Fenton, MO... workers from HAAS TCM, Inc., Logistics Services, Inc., Robinson Solutions, Logistics Management Services...

  12. 75 FR 11918 - General Electric Kentucky Glass Plant, Lighting, LLC, Including On-Site Leased Workers From the...

    Science.gov (United States)

    2010-03-12

    ... DEPARTMENT OF LABOR Employment and Training Administration [TA-W-72,011] General Electric Kentucky Glass Plant, Lighting, LLC, Including On-Site Leased Workers From the Patty Tipton Company, Aetna Building Maintenance, and Concentra, Lexington, KY; Amended Certification Regarding Eligibility To Apply for Worker Adjustment Assistance In accordanc...

  13. Genesis of natural cokes: Some Indian examples

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Ashok K.; Sharma, Mamta [Central Institute of Mining and Fuel Research, Dhanbad, PIN-828108 (India); Singh, Mahendra P. [Banaras Hindu University, Varanasi, PIN-221005 (India)

    2008-06-13

    In Indian coalfields huge amounts of natural coke have been produced due to magmatic intrusions. Jharia Coalfield in eastern part of India alone contains approximately 2000 Mt of baked coking coal as a consequence of these intrusions in the form of discordant and concordant bodies. This paper is an effort to investigate the effect of carbonization in two intrusion affected coal seams of Ena (seam XIII) and Alkusa (seam XIV) collieries of Jharia Coalfield. Natural coke is derived from coking coal under in-situ conditions due to intense magmatic induced heat and overburden pressure. Natural coke is characterized by the presence of low volatile matter and high ash contents and organic constituents showing isotropy and anisotropy. Through physical, petrographic and chemical properties of natural coke or 'jhama' as determined by various methods it has been established that the reactives in the unaltered coals (vitrinite, liptinite, pseudovitrinite, reactive semifusinite, etc.) are < 25.0 vol.%, moisture < 2.5%, volatile matter < 15.0% and hydrogen < 4.0%. The temperatures attained in the coal seams have been deciphered using some standard models, which indicate that a temperature {proportional_to} 1000 C was attained. This produced huge amount of anisotropic and deposited carbons. An attempt has been made to understand the factors that influence the genesis of natural coke and heat altered maceral products in coals in Indian coalfields. (author)

  14. Chromosome analysis of nuclear power plant workers using fluorescence in situ hybridization and Giemsa assay

    International Nuclear Information System (INIS)

    Hristova, Rositsa; Hadjidekova, Valeria; Grigorova, Mira; Nikolova, Teodora; Bulanova, Minka; Popova, Ljubomira; Staynova, Albena; Benova, Donka

    2013-01-01

    The aim of this study was to evaluate the genotoxic effects of ionizing radiation in vivo in exposed Bulgarian nuclear power plant workers by using classical cytogenetic and molecular cytogenetic analyses of peripheral lymphocytes. Chromosome analysis using fluorescence in situ hybrydization (FISH) and Giemsa techniques was undertaken on 63 workers and 45 administrative staff controls from the Bulgarian Nuclear Power Plant. Using the Giemsa method, the frequencies of cells studied with chromosome aberrations, dicentrics plus rings and chromosome fragments in the radiation workers were significantly higher compared with the control group (P=0.044, P=0.014, and P=0.033, respectively). A significant association between frequencies of dicentrics plus rings and accumulated doses was registered (P<0.01). In the present study, a FISH cocktail of whole chromosome paints for chromosomes 1, 4 and 11 was used. A significant association between frequency of translocations and accumulated doses was also observed (P<0.001). Within the control group, a correlation was found between age and the spontaneous frequency of translocations. No correlation was found between smoking status and frequency of translocations. When compared with the control group, workers with accumulated doses up to 100 mSv showed no increase in genome translocation frequency, whereas workers with accumulated doses from 101 to 200 mSv showed a statistically significant doubling of genome translocation frequency (P=0.009). Thus, in cases of chronic exposure and for purposes of retrospective dosimetry, the genome frequency of translocations is a more useful marker for evaluation of genotoxic effects than dicentric frequency. (author)

  15. [Health survey of plant workers for an occupational exposure to ammonium perchlorate].

    Science.gov (United States)

    Chen, Hong-xia; Shao, Yuan-peng; Wu, Feng-hong; Li, Yang-ping; Peng, Kai-liang

    2013-01-01

    To understand the occupational hazards of ammonium perchlorate dust on operating workers and to provide the basis preventive measures for protecting the workers' health. 36 workers exposed to ammonium perchlorate dust and 48 unexposed workers from one factory were selected as the exposure and control groups. Investigations on the general condition, sampling of dust in the workplaces and a special medical examination were conducted for two groups, including occupational history, clinical manifestations, blood routine test, hepatic and renal functions, indexes of thyroid hormone, spirometric test and chest X-ray. The total dust concentration of AP in the batch plant reached to 51.63 ± 43.27 mg/m(3), exceeding the U.S. Occupational Safety and Health Administration (OSHA) permission exposure limits. The systolic blood pressure in the exposure group was higher than that of the control group (146.14 ± 21.03 VS 134.67 ± 18.58), and the difference was statistically significant (P detection rates of the cumulative total symptoms, short of breath and skin itch symptoms in the exposure group were significantly higher than those in the control group (86.11% VS 66.67%; 30.56% VS 12.50%) (P detected on the left of lung door area in the control group. The systolic blood pressure of workers in the exposure group was significantly higher, which could not exclude related to the exposure to AP dust; The T(3) levels in the exposure workers were lower than those in the control group, which may due to AP exposure, suggesting that long-term chronic exposure to AP dust may affect thyroid function.

  16. Study of Epidemiology Conducted in Indian Nuclear Power Plants-Occupational Workers and Family Members

    International Nuclear Information System (INIS)

    Ramamirtham, B.; Shringi, K.; Wagh, P. M.

    2004-01-01

    At present in India, a nuclear generation capacity of 2720 MWe is in operation with 12 units of pressurised heavy water reactors (PHWRs) and 2 units of boiling water reactors (BWRs). The nature of the effects of the low-doses from ionizing radiation has been the subject considerable interest in the scientific community. The radiation exposures due to the operation of the NPPs are small and at low dose rates. The specific objective of the study were to compute the morbidity (prevalence) of cancer among the radiation occupational workers and their families and to compare with suitable controls and to study prevalence of congenital anomalies among the offspring of the employees of the nuclear power plants in India and to determine, if any, their causal relation with radiation exposure. The data collection work was carried out for survey by the local academic medical institutions near the NPP sites under the guidance of Tata Memorial Hospital, Mumbai. The distribution of the confounding factors among the radiation and non-radiation workers did not show any significant difference and thus the possibility of biased results was minimized. The cross-sectional survey has shown that there was no difference in the prevalence of malignancies in the radiation workers as compared to non-radiation workers, nor was there any difference in the prevalence of malignancies in the radiation workers as compared to non-radiation workers, nor was there any difference in the prevalence of malignancies in spouses and offspring. The study did not show any excess cancers among the study population. The congenital abnormalities observed in the offspring of the employees were much less than the reported values among the newborn children. The study has provided useful indicators and generated reliable baseline data for carrying out further work. Scientific thematic Area: 1) Radiation Effects. (Author)

  17. Experimental and numerical investigations of coke descending behavior in a coke dry quenching cooling shaft

    International Nuclear Information System (INIS)

    Feng Yanhui; Zhang Xinxin; Yu Quan; Shi Zhongyin; Liu Zhicheng; Zhang Hu; Liu Huafei

    2008-01-01

    A viscous flow model based on the Navier-Stokes equation is developed to describe coke descending behavior in the 1/7-scaled-down experimental setup of an actual 75 t/h cooling shaft. It is found that the internal friction due to cokes viscosity significantly influences the descending behavior of cokes in the lower part of the shaft, while the external wall friction dominates the sluggish flow of the cokes in the shaft. An asymptotic friction coefficient expression is proposed for granular mixtures flowing along the shaft wall modified from normal wall tress, and the concept of bulk solid viscosity is introduced to describe the internal friction between coke particles. The results simulated by the present model are compared with those by the potential flow and the kinematic model without friction. The viscous flow model is quite good to simulate the bulk coke flow as the physically important frictions are engaged

  18. The coke drum thermal kinetic effects

    Energy Technology Data Exchange (ETDEWEB)

    Aldescu, Maria M.; Romero, Sim; Larson, Mel [KBC Advanced Technologies plc, Surrey (United Kingdom)

    2012-07-01

    The coke drum thermal kinetic dynamics fundamentally affect the coker unit yields as well as the coke product properties and unit reliability. In the drum the thermal cracking and polymerization or condensation reactions take place in a semi-batch environment. Understanding the fundamentals of the foaming kinetics that occur in the coke drums is key to avoiding a foam-over that could result in a unit shutdown for several months. Although the most dynamic changes with time occur during drum filling, other dynamics of the coker process will be discussed as well. KBC has contributed towards uncovering and modelling the complexities of heavy oil thermal dynamics. (author)

  19. A hydraulic device for unloading coke

    Energy Technology Data Exchange (ETDEWEB)

    Kretinin, M.V.; Abizgildin, U.M.; Kirillov, T.S.; Makarov, M.I.; Prokopov, O.I.; Solov' ev, A.M.

    1979-07-15

    A hydraulic device for unloading petroleum coke from slow carbonization chambers is characterized by an arrangement whereby in order to increase the output of large size coke by controlling the increment of the cutting line of the coke, the mechanism used to move the rod in the hydraulic cutter is built in the form of a rod rotation rotor; a gear wheel is mounted on the immobile section of this rotor, and on the mobile section a multi-stage regulator is installed. The drive gear of the regulator is engaged with the gear wheel, while the driven gear is connected to the rack, which is fastened to the rod.

  20. OCCUPATIONAL EXPOSURE TO TRICHLOROETHYLENE AND CANCER RISK FOR WORKERS AT THE PADUCAH GASEOUS DIFFUSION PLANT

    Science.gov (United States)

    BAHR, DEBRA E.; ALDRICH, TIMOTHY E.; SEIDU, DAZAR; BRION, GAIL M.; TOLLERUD, DAVID J.; MULDOON, SUSAN; REINHART, NANCY; YOUSEEFAGHA, AHMED; MCKINNEY, PAUL; HUGHES, THERESE; CHAN, CAROLINE; RICE, CAROL; BREWER, DAVID E.; FREYBERG, RONALD W.; MOHLENKAMP, ADRIANE MOSER; HAHN, KRISTEN; HORNUNG, RICHARD; HO, MONA; DASTIDAR, ANIRUDDHA; FREITAS, SAMANTHA; SAMAN, DANIEL; RAVDAL, HEGE; SCUTCHFIELD, DOUGLAS; EGER, KENNETH J.; MINOR, STEVE

    2016-01-01

    Objective The Paducah Gaseous Diffusion Plant (PGDP) became operational in 1952; it is located in the western part of Kentucky. We conducted a mortality study for adverse health effects that workers may have suffered while working at the plant, including exposures to chemicals. Materials and Methods We studied a cohort of 6820 workers at the PGDP for the period 1953 to 2003; there were a total of 1672 deaths to cohort members. Trichloroethylene (TCE) is a specific concern for this workforce; exposure to TCE occurred primarily in departments that clean the process equipment. The Life Table Analysis System (LTAS) program developed by NIOSH was used to calculate the standardized mortality ratios for the worker cohort and standardized rate ratio relative to exposure to TCE (the U.S. population is the referent for age-adjustment). LTAS calculated a significantly low overall SMR for these workers of 0.76 (95% CI: 0.72–0.79). A further review of three major cancers of interest to Kentucky produced significantly low SMR for trachea, bronchus, lung cancer (0.75, 95% CI: 0.72–0.79) and high SMR for Non-Hodgkin's lymphoma (NHL) (1.49, 95% CI: 1.02–2.10). Results No significant SMR was observed for leukemia and no significant SRRs were observed for any disease. Both the leukemia and lung cancer results were examined and determined to reflect regional mortality patterns. However, the Non-Hodgkin's Lymphoma finding suggests a curious amplification when living cases are included with the mortality experience. Conclusions Further examination is recommended of this recurrent finding from all three U.S. Gaseous Diffusion plants. PMID:21468904

  1. Scientific and technical problems in the production of coke

    Energy Technology Data Exchange (ETDEWEB)

    Glushchenko, I M

    1979-05-01

    This paper lists several scientific and technological problems facing the producers of coke in the future. The demand for coke on the world market is steadily increasing despite the efforts of metallurgists to find non-coke methods of ore smelting. The major problems are held to be the gap between very successful results of research and the lack of their application to industry, unsatisfactory coke oven construction, problems in quenching and imperfections in the formed coke process. (In Russian)

  2. Operation car for horizontal coke ovens. Bedienungswagen fuer waagrechte Verkokungsoefen

    Energy Technology Data Exchange (ETDEWEB)

    Kwasnik, H J; Piduch, H G

    1981-07-30

    An operation car which is driveable on the coke side of a coke oven battery is described. The operation car is equipped with a door lifter, a door and frame cleaner, a coke guiding grid and a collection hood for emissions developed on coke pushing. The car has a portal construction and it is driveable on both sides of the path of the coke receiving car. The operation has a considerable lower weight than usual cars. (HGOE).

  3. Blood Pressure of Jordanian Workers Chronically Exposed to Noise in Industrial Plants

    Directory of Open Access Journals (Sweden)

    Saed Nserat

    2017-10-01

    Full Text Available Background: Occupational studies investigating the association between blood pressure and noise exposure are almost lacking in the Eastern Mediterranean Region countries. Objective: To determine the association between occupational exposure to high level of noise and blood pressure among a group of workers in Jordan. Methods: All workers who had been exposing to noise for at least 3 years in 3 plants in Madaba governorate in Jordan were included in this cross-sectional study. A structured questionnaire was used to collect data. The occupational noise level was measured with a portable calibrated sound meter. Results: We studied 191 male workers, of whom 145 (75.9% were exposed to a noise level higher than the permissible limit of 85 dBA. The mean systolic blood pressure (SBP and diastolic blood pressure (DBP and the prevalence of hypertension were significantly higher among those exposed to higher noise level. In multivariate analysis, workers exposed to high level of noise had a significantly higher odds of hypertension compared to those exposed to noise level lower than the permissible limit (OR 4.7, 95% CI 1.6 to 13.8. The odds of hypertension increased by 17% (95% CI 10% to 30% for each dB increase in noise intensity. Conclusion: Exposure to high level of noise is associated with elevated blood pressure.

  4. Isomer pattern and elimination of dioxins in workers exposed at a municipal waste incineration plant

    Science.gov (United States)

    YAMAMOTO, Kenya; KUDO, Mitsuhiro; ARITO, Heihachiro; OGAWA, Yasutaka; TAKATA, Tsutomu

    2015-01-01

    The aim of this study was to clarify patterns of serum concentrations of dioxins in the employees of a waste incineration plant and to estimate elimination rates and half-lives of serum dioxin isomers, and the maximum serum concentrations of dioxin isomers at the time of plant shutdown. Sixteen subjects participating 3 times or more in annual health examinations during an 8-yr period from 2000 to 2007 were recruited for this study. Serum concentrations of dioxins expressed as TEQ/g lipid decreased gradually after plant shutdown with the highest decrease observed in polychlorinated dibenzofurans (PCDFs) followed by polychlorinated deibenzo-p-dioxins (PCDDs) and then coplanar PCBs. The serum toxic equivalency (TEQ) concentrations of PCDF and PCDD congeners in the employees were higher than those in the general population survey by the Ministry of the Environment, Japan, whereas the serum concentrations of coplanar PCBs were similar to those in the general population. The estimated half-lives and elimination rates of PCDDs and PCDFs in the highly exposed workers increased compared with the moderately exposed workers. The estimated geometric mean serum concentrations of PCDDs, PCDFs and total dioxins at the time of plant shutdown were 35, 53 and 107 pg TEQ/g lipid, respectively. PMID:26118856

  5. Assessment of chronic neuropsychological effects of mercury vapour poisoning in chloral-alkali plant workers

    Directory of Open Access Journals (Sweden)

    Nurka Pranjić

    2002-02-01

    Full Text Available A prospective case study was conducted in the Department of Occupational Medicine, Tuzla. The purpose of this study was to indicate negative effects from occupational exposure to mercury on behavioural and mental health, memory and psychomotor function that was tested in 46 chloral-alkali plant workers (mean age was 38. 8+/- 5. 7 years; mean age of occupational history 16. 5+/- 6. 0 years. Data on toxicological monitoring on atomic absorption spectrometer, and data on mental health were collected, psychiatric and other subjective symptoms, and behavioural, psychomotor and memory function tested. The data were compared to control group, 32 healthy non exposed workers. The study was designed to assess blood and urine mercurylevels and length of occupational exposure and investigate its relationships to effects on the mental health. The mean air mercury levels were 0.23 mg/m3, the mean blood mercury concentrations was 3. 6 mg/ dl and the mean urine mercuryconcentrations were 151.7 +/- 180.4 mg/l. In 25 (53% workers exposed to mercury vapour was identified Depression-Hypochondrias Syndrome (p trend < 0. 001 with higher scores for scales: Hysteria (p trend <0. 001, Schizoid and Psychoastenia (MMPI. All psychological parameters were in highly significantly correlations with mercury levels and length of occupational exposure. Pathological parameters were possible general identified if the concentration of blood mercury levels are >2. 9 mg/ dl, or urine mercury levels > 87 mg/l workers exposed to mercury vapour knew that toxic effects in body resulted in loosing some of intellectual abilities, and that people who handle chemicals had an increased health risk (ESW questionnaire. The occupational mercury exposed workers had introvert behaviour (EPQ. Aggressiveness was found in 71.7% workers. The cognitive disturbances: short-term memory loss, difficult to concentrate on tasks which require attention and thinking

  6. Fundamentals of Delayed Coking Joint Industry Project

    Energy Technology Data Exchange (ETDEWEB)

    Michael Volk; Keith Wisecarver

    2003-09-26

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world

  7. Prospects for the use of coke-works gas in the manufacture of sponge iron

    Energy Technology Data Exchange (ETDEWEB)

    Hatarascu, O; Orosz, R

    1978-01-01

    This paper presents the results of tests conducted in the laboratory of the I.C.E.M. (National research institute for the mining industry) at Hunedoara; these investigations dealt with the reduction of iron oxide by gas from coking plant. The direct application of coke-works gas for the direct reduction of iron ores represents a new move towards the profitable utilization of this gas which, owing to its high content of hydrogen and CH4, can be transformed into CO and H2 using current conversion techniques (water-vapour or CO2 methods). The article presents a diagram of the 'MIDREX' reduction plant. Also includes a study of the variation in the specific coke-gas consumption as a function of the reducer-gas throughput together with an analysis of the reduction process for recycled and regenerated gas at a temperature of 900 C.

  8. Advanced coking process control at Rautaruukki Steel

    Energy Technology Data Exchange (ETDEWEB)

    Ritamaki, O.; Luhtaniemi, H. [Rautaruukki Engineering (Finland)

    1999-12-01

    The paper presents the latest development of the Coking Process Management System (CPMS) at Raahe Steel. The latest third generation system is based on the previous system with the addition of fuzzy logic controllers. (The previous second generation system was based simultaneous feed forward and feedback control.) The system development has resulted in balanced coke oven battery heating, decreased variation in process regulation between shifts and increase of process information for operators. The economic results are very satisfactory. 7 figs.

  9. Polish scenery of coking industry activity

    International Nuclear Information System (INIS)

    Zielinski, H.

    1994-01-01

    The cooking industry in Poland and the world depends on conditions of iron and steel industry. Nowadays it is observed depression of this industry. On the other hand it is occurred a strong public pressure to reduce pollution by coking works. It is known that modernizing enterprises need a great deal of funds, but they are necessary, in order to keep coking industry on market. (author). 2 tabs

  10. Method of determining coking temperature of coke. [Experimental method of determining final coking temperature using a small sample and calibration graph

    Energy Technology Data Exchange (ETDEWEB)

    Mel' nichuk, A.Yu.; Bondarenko, A.K.; Fialkov, B.S.; Khegay, L.U.; Khvan, L.A.; Muzyzhuk, V.D.; Zakharov, A.G.; Zelenskiy, V.P.

    1985-01-01

    The coking temperature of coke should be determined from the magnitude of the ionization current of the medium during heating (3/sup 0//min) of a coke sample (2 g, fraction < 0.2 mm) in an oxidation medium with air supply (1 1/min). The coking temperature is determined from the maximum magnitude of current using a graduated graph constructed during analysis of coke samples obtained with different final coking temperatures. The discrepancy between the established coking temperature and that defined from the proposed method is 8-19/sup 0/, and that defined from electrical resistance of coke is 26-43/sup 0/. In addition to high accuracy, this method reduces the time outlays for making the analysis.

  11. Assessment of potential doses to workers during postulated accident conditions at the Waste Isolation Pilot Plant

    International Nuclear Information System (INIS)

    Hoover, M.D.; Newton, G.J.; Farrell, R.F.

    1996-01-01

    This qualitative hazard evaluation systematically assessed potential doses to workers during postulated accident conditions at the U.S. Department of Energy's Waste Isolation Pilot Plant (WIPP). Postulated accidents included the spontaneous ignition of a waste drum, puncture of a waste drum by a forklift, dropping of a waste drum from a forklift, and simultaneous dropping of seven drums during a crane failure. The descriptions and estimated frequencies of occurrence for these accidents were developed by the Hazard and Operability Study for CH TRU Waste Handling System (WCAP 14312). The estimated materials at risk, damage ratios, airborne release fractions and respirable fractions for these accidents were taken from the 1995 Safety Analysis Report (SAR) update and from the DOE handbook Airborne Release Fractions/Rates and Respirable Fractions for Nonreactor Nuclear Facilities (DOE-HDBK-3010-94). A Monte Carlo simulation was used to estimate the range of worker exposures that could result from each accident. Guidelines for evaluating the adequacy of defense-in-depth for worker protection at WIPP were adopted from a scheme presented by the International Commission on Radiological Protection in its publication on Protection from Potential Exposure: A Conceptual Framework (ICRP Publication 64). Probabilities of exposures greater than 5, 50, and 300 rem were less than 10 -2 , 10 -4 , and 10 -6 per year, respectively. In conformance with the guidance of DOE standard 3009-94, Appendix A (draft), we emphasize that use of these evaluation guidelines is not intended to imply that these numbers constitute acceptable limits for worker exposure under accident conditions. However, in conjunction with the extensive safety assessment in the 1995 SAR update, these results indicate that the Carlsbad Area Office strategy for the assessment of hazards and accidents assures the protection of workers, as well as members of the public and the environment

  12. Comparison of p53 levels in lymphocytes and in blood plasma of nuclear power plant workers

    International Nuclear Information System (INIS)

    Roessner, Pavel; Chvatalova, Irena; Schmuczerova, Jana; Milcova, Alena; Roessner, Pavel; Sram, Radim J.

    2004-01-01

    p53 levels were assessed in lymphocytes and in blood plasma of workers from two Czech nuclear power plants (NPP): 114 subjects working in Temelin and 108 subjects working in Dukovany. Ionizing radiation (IR) exposure data were available for 64 and 59 subjects working in the monitored zones from the NPP in Temelin and Dukovany, respectively. The short-term doses of IR for these subjects were 0.01 and 0.12 mSv, and the long-term doses were 0.46 and 5.68 mSv, in the Temelin and Dukovany NPP, respectively. As a control group, 46 subjects living in Ceske Budejovice, a city nearby the Temelin NPP, were analyzed. The concentration of p53 in lymphocytes was significantly higher in workers from the monitored zone in the Dukovany NPP (median value 6.4 pg/μg protein, P < 0.001) than in workers from the Temelin NPP (3.2 pg/μg) as well as in the control group (3.5 pg/μg). In contrast, plasma levels of p53 were comparable in the control group (median value 116 pg/ml plasma) and workers from the monitored zone of Dukovany NPP (102 pg/ml), but lower in workers from Temelin NPP (5 pg/ml). Other factors affecting p53 levels were studied. Smoking resulted in increased p53 lymphocyte levels. The effect of polymorphisms in metabolic and DNA repair genes on p53 levels was analyzed. The correlation was found between p53 levels in lymphocytes and p53 codon 72 polymorphism in subjects working in NPPs, but not in the control group. The results of measurement p53 levels in lymphocytes suggest that this biomarker could reflect the short-term as well as long-term effects of low doses IR. Its impact on human health should be further explored

  13. Chronic psychological effects of exposure to mercury vapour among chlorine-alkali plant workers.

    Science.gov (United States)

    Pranjić, N; Sinanović, O; Jakubović, R

    2003-01-01

    Quantitative assessment of nervous system function is essential in characterising the nature and extent of impairment in individuals experiencing symptoms following work-place mercury vapour exposure. The purpose of this study was the application of standardised tests of behavioural, psychomotor and memory function to understand the neuropsychological effects of mercury in occupationally exposed chlorine-alkali plant workers. The study comprised 45 workers at a chlorine-alkali plant with the mean age of 39.36 +/- 5.94 years, who had been exposed to daily inhalation of mercury vapour over long-term employment of 16.06 +/- 4.29 years. The cumulative mercury index was 155.32 +/- 95.02 micrograms/g creatinine, the mean of urinary mercury concentrations on the first day of the study was 119.50 +/- 157.24 micrograms/g creatinine, and the mean of urinary mercury concentrations 120 days after cessation of exposure was 21.70 +/- 26.07 micrograms/g creatinine. The analysis included tests of behavioural, psychomotor and memory function. The behavioural test battery consisted of: Environmental Worry Scale (EWS), Minnesota Modified Personal Inventory (MMPI-2), Purdue standard 25 minute test, and adapted, 10 minutes test, Bender's Visual-Motor Gestalt test (BGT), and Eysenck Personality Inventory (EPQ). The data were compared to a control group of 32 not directly exposed workers. In the mercury vapour exposed workers with relatively high level exposure to inorganic mercury vapour (TWA/TLV = 0.12 mg/m3/0.025 mg/m3) we identified somatic depression-hypochondria symptoms with higher scores for scales: hysteria (P introvert behaviour (EPQ, MMPI-2). The cognitive disturbances in mercury-exposed workers were identified as: concentration difficulty, psychomotor, perceptual and motor coordination disturbances, and brain effects. We identified fine tremor of the hands in 34 out of 45 mercury-exposed workers (BGT). The results point to a relationship between the duration of mercury

  14. Review of health issues of workers engaged in operations related to the accident at the Fukushima Daiichi Nuclear Power Plant.

    Science.gov (United States)

    Hiraoka, Koh; Tateishi, Seiichiro; Mori, Koji

    2015-01-01

    The aim of this review was to summarize the lessons learned from the experience in protecting the health of workers engaged in operations following the accident at the Fukushima Daiichi Nuclear Power Plant (NPP). We reviewed all types of scientific papers examining workers' health found in Medline and Web of Sciences as well as some official reports published by the Ministry of Health, Labour and Welfare of Japan and other governmental institutes. The papers and reports were classified into those investigating workers at the Fukushima Daiichi and Daini NPPs, workers engaged in decontamination operations in designated areas, and other workers. Regarding workers at the NPPs, many efforts were made to establish an emergency-care and occupational health system. Risk management efforts were undertaken for radiation exposure, heat stress, psychological stress, outbreak of infectious diseases, and fitness for work. Only a few reports dealt with decontamination workers and others; however, the health management of these workers was clearly weaker than that for workers at the NPPs. Many lessons can be learned from what occurred. That knowledge can be applied to ongoing decommissioning work and to future disasters. In addition, it is necessary to study the long-term health effects of radiation exposure and to accumulate data about the health of workers engaged in decontamination work and other areas.

  15. Hydrotreating catalyst deactivation by coke from SRC-II oil

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, Y.; Kumata, F.; Massoth, F.E.

    1988-10-01

    Samples of a CoMo/Al/sub 2/O/sub 3/ catalyst were partially deactivated with SRC-II feed in an autoclave reactor to give coked samples of 5 to 18% C. The coked catalysts were analyzed for surface area, pore volume, coronene adsorption and diffusivity, and their catalytic activity determined for hydrodesulfurization (HDS), hydrodeoxygenation (HDO) and C-N hydrogenolysis (CNH) using model compounds. All of the above measurements decreased with increase in coke content. Property data indicate that some pores are blocked by coke and diffusivity results show narrowing of pore mouths with increasing coke content. Catalyst deactivation versus coke level was identical for HDS and HDO, but less for CNH. A simple model of coke deactivation was developed to relate activity to coke content. Coke is envisioned as forming wedge-like deposits in the catalyst pores. 11 refs., 5 figs., 3 tabs.

  16. Guidance for Deployment of Mobile Technologies for Nuclear Power Plant Field Workers

    Energy Technology Data Exchange (ETDEWEB)

    Heather D. Medema; Ronald K. Farris

    2012-09-01

    This report is a guidance document prepared for the benefit of commercial nuclear power plants’ (NPPs) supporting organizations and personnel who are considering or undertaking deployment of mobile technology for the purpose of improving human performance and plant status control (PSC) for field workers in an NPP setting. This document especially is directed at NPP business managers, Electric Power Research Institute, Institute of Nuclear Power Operations, and other non-Information Technology personnel. This information is not intended to replace basic project management practices or reiterate these processes, but is to support decision-making, planning, and preparation of a business case.

  17. Processing of coke oven gas. Primary gas cooling

    Energy Technology Data Exchange (ETDEWEB)

    Ullrich, H [Otto (C.) und Co. G.m.b.H., Bochum (Germany, F.R.)

    1976-11-01

    The primary cooler is an indispensable part of all byproduct processing plants. Its purpose is to cool the raw gas from the coke oven battery and to remove the accompanying water vapor. The greater part of the cooling capacity is utilized for the condensation of water vapor and only a small capacity is needed for the gas cooling. Impurities in the gas, like naphthalene, tar and solid particles, necessitate a special design in view of the inclination to dirt accumulation. Standard types of direct and indirect primary gas coolers are described, with a discussion of their advantages and disadvantages.

  18. An influence of occupational exposure on level of chromosome aberrations in nuclear power plant workers

    International Nuclear Information System (INIS)

    Birute Griciene; Grazina Slapsyte

    2007-01-01

    Complete text of publication follows. Objective. The workers of Ignalina Nuclear Power Plant (INPP) receive the highest occupational ionising radiation doses in Lithuania. Their occupational exposure results mainly from external low LET gamma radiation. Some workers receive additional internal and neutron exposure. Though exposure doses are generally low and don't exceed the annual dose limit, the higher doses are obtained during outages. The aim of the present study was to analyse chromosome aberration frequencies in lymphocytes of INPP workers exposed to the different types of ionising radiation. Methods. The blood sampling of 52 INPP male workers was performed in 2004-2006. For 29 workers radiation exposure resulted from the external gamma rays only. Their mean annual dose averaged over the 3-year period prior blood sampling was 11.7±8.7 mSv. The mean cumulative dose - 197.7±174.7 mSv. 15 workers had an intake of gamma radionuclides ( 60 Co, 137 Cs), contributing to the doses less than 0.1 mSv. Their mean cumulative dose - 278.2±191.9 mSv. The mean annual dose averaged over the 3-year period prior blood sampling was 11.8±5.3 mSv. For 8 subjects neutron doses below 0.2 mSv were recorded. Their mean annual dose averaged over the 3-year period prior blood sampling was 7.0±2.9 mSv. The mean cumulative dose was 241.8±93.0 mSv. Heparinized venous blood samples were taken and cultures were initiated according to the standard procedures. Phytohaemagglutinin (7.8 μg/ml) stimulated cultures were incubated at 37degC for 72 hours in RPMI 1640 medium supplemented with 12% heat-inactivated newborn calf serum, 40 μg/ml gentamycin. Colchicine was added to the culture during the initiation at a final concentration of 0,25 μg/ml. The harvested lymphocytes were treated with hypotonic KCl (0,075 M) and then fixed in methanol-glacial acetic acid (3:1). Flame-dried slides were stained with Giemsa, coded and scored blind. Generally 500 first-division cells per individual were

  19. Results of tuyere coke sampling with regard to application of appropriate coke strength after reaction (CSR for a blast furnace

    Directory of Open Access Journals (Sweden)

    Shiau J-S.

    2017-01-01

    Full Text Available Raising pulverized coal injection (PCI will decrease coke rate, but increase the residence time of coke and abrasion in the blast furnace (BF. Thus, insufficient coke strength will generate more coke fines in the lower BF and result in lower permeability and production of hot metal (HM. For understanding the behavior of coke at various HM productivities, a tuyere coke sampler was used to collect the coke samples for measuring the coke strength. Firstly, the difference of sampled coke under the conditions of various HM productivities was explored. Secondly, the BF operating conditions and causes of generating more coke fines was correlated by testing the coke reaction rate after reaction. Finally, according to the above analysis results, the relative regression equations had been obtained for sampling coke properties, BF operation conditions and BF permeability. Furthermore, the coke strength after reaction (CSR quantitative target and its online system at various blast conditions were set to provide some reference for coke and HM production.

  20. Dose-reduction techniques for high-dose worker groups in nuclear power plants

    International Nuclear Information System (INIS)

    Khan, T.A.; Baum, J.W.; Dionne, B.J.

    1991-03-01

    This report summarizes the main findings of a study of the extent of radiation dose received by special work groups in the nuclear power industry. Work groups which chronically get large doses were investigated, using information provided by the industry. The tasks that give high doses to these work groups were examined and techniques described that were found to be particularly successful in reducing dose. Quantitative information on the extent of radiation doses to various work groups shows that significant numbers of workers in several critical groups receive doses greater than 1 and even 2 rem per year, particularly contract personnel and workers at BWR-type plants. The number of radiation workers whose lifetime dose is greater than their age is much less. Although the techniques presented would go some way in reducing dose, it is likely that a sizeable reduction to the high-dose work groups may require development of new dose-reduction techniques as well as major changes in procedures. 10 refs., 26 tabs

  1. Pulmonary fibrosis in cable plant workers exposed to mist and vapor of petroleum distillates.

    Science.gov (United States)

    Skyberg, K; Rønneberg, A; Kamøy, J I; Dale, K; Borgersen, A

    1986-08-01

    Twenty-five cable plant workers exposed to mists and vapors of mineral oils and kerosene for 5-35 years have been investigated in a cross-sectional, matched pairs study. The exposed cohort and the referents were examined by radiology, pulmonary function measurements, and a questionnaire for symptoms of respiratory disease. Lung tissue from a deceased worker with 35 years of exposure was investigated by histopathologic methods and by scanning electron microscopy. Exposure measurements were performed by personal sampling. Previous employment and smoking habits were recorded for all subjects. An increased prevalence of slight basal lung fibrosis was found in chest films of the exposed workers. Pulmonary fibrosis was confirmed histopathologically. A moderately decreased vital capacity (VC) and forced expiratory volume (FEV1) was found. Oil mist was measured to time-weighted average levels of 0.15-0.30 mg/m3 with short-term vapor exposure of up to 4000 mg/m3. It is concluded that mists and vapors from petroleum distillates are the most probable causes of the findings.

  2. Coking coal consumption of POSCO

    International Nuclear Information System (INIS)

    Yoo, B.C.

    1991-01-01

    Pohang Iron and Steel Company Limited (POSCO) was established in 1968. Molten iron was first produced in July 1973 after a 3 year construction period. The long awaited start up of Korea's first integrated steel works provided the momentum for the fast growth of our steel industry. In 1973, the first year of operation, POSCO purchased 770,000 tons of coal from the United States and Australia. The import tonnage was more than doubled in 1976 when we completed the second stage of Pohang Works and has continued to increase reaching 13.1 million tons last year. POSCO's coal consumption will increase one more time next year as the fourth stage of Kwangyang works starts to operate a new blast furnace with an annual molten iron production capacity of 2.8 million tons. Even though the new blast furnace will have the same capacity as the other 3 in Kwangyang, the additional coking coal requirement will be much smaller than the tonnages we needed for the other stages of the works. This paper reports that this is due to the increased use of pulverized coal

  3. 77 FR 15123 - Foundry Coke From China; Scheduling of an Expedited Five-Year Review

    Science.gov (United States)

    2012-03-14

    ... submitted by ABC Coke, Erie Coke, Tonawanda Coke Corporation, and Walter Coke Co. to be individually... Analyst... Cynthia Foreso (205-3348). Attorney Charles St. Charles (205-2782). Supervisory Investigator...

  4. A Cohort Mortality Study of Workers in a Second Soup Manufacturing Plant.

    Science.gov (United States)

    Faramawi, Mohammed F; Ndetan, Harrison; Jadhav, Supriya; Johnson, Eric S

    2015-01-01

    The authors previously reported on mortality among workers in a Baltimore soup plant. Increased mortality was observed for cancers of the floor of the mouth, rectosigmoid colon/rectum/anus, epilepsy, and chronic nephritis. Here, the authors report on mortality on a second soup plant in the same locality. Excess mortality was similarly recorded for cancers of the tonsils/oropharynx, rectosigmoid colon/rectum/anus, and lung and myelofibrosis. Excess risk from cardiovascular, cerebrovascular, kidney, and infectious diseases was also observed. These 2 studies are important because firstly, to the authors' knowledge, they are the only reports of mortality in this occupational group in spite of their having a potential for exposure to hazardous carcinogenic agents. Secondly, there is no information on any exposure assessment in this industry. These 2 reports will draw attention to the need to conduct more detailed exposure and mortality investigations in this little-studied group.

  5. Economic costs due to workers' sick leave at wastewater treatment plants in Bulgaria.

    Science.gov (United States)

    Toseva, Elka Ilieva; Stoyanova, Rumyana; Turnovska, Tanya

    2018-03-09

    The compensatory mechanisms of social security include expenses for sick leave. The aim of the study is to determine the economic cost due to sick leave among workers in wastewater treatment plants (WWTPs), comparing with the same economic indicators of the National Social Security Institute (NSSI) in Bulgaria. The sick leave of 111 workers at 3 WWTPs was studied in the period 2012-2014 on the grounds of registered absences from work due to temporary incapacity for work. The economic indicators of the NSSI, the gross salary at WWTPs, payable social security contributions and compensatory payments for sick leave have been used for economic cost calculation for temporary incapacity of the workers. The frequency of cases and the frequency of lost days due to temporary incapacity were increased in the observed period at WWTPs and in Bulgaria, and it is significantly higher for the employed at WWTPs. The percentage share of workers equivalent to 1.66% at WWTPs have not worked for an entire year as a result of temporary incapacity in 2012, 2.76% - in 2013, and 4.61% - in 2014. The economic burden due to sick leave at WWTPs was raised from EUR 4913.02 in 2012 to EUR 16 895.80 for 2014 for employers and the NSSI. The frequency of cases and the frequency of lost days due to temporary incapacity were increased in the observed period at WWTPs and in Bulgaria, and it is significantly higher for the employed at WWTPs. The economic burden was equally distributed between employers and the NSSI. Med Pr 2018;69(2):129-141. This work is available in Open Access model and licensed under a CC BY-NC 3.0 PL license.

  6. Assessment of potential doses to workers during postulated accident conditions at the Waste Isolation Pilot Plant

    Energy Technology Data Exchange (ETDEWEB)

    Hoover, M.D.; Farrell, R.F. [DOE, Carlsbad, NM (United States); Newton, G.J.

    1995-12-01

    The recent 1995 WIPP Safety Analysis Report (SAR) Update provided detailed analyses of potential radiation doses to members of the public at the site boundary during postulated accident scenarios at the U.S. Department of Energy`s Waste Isolation Pilot Plant (WIPP). The SAR Update addressed the complete spectrum of potential accidents associated with handling and emplacing transuranic waste at WIPP, including damage to waste drums from fires, punctures, drops, and other disruptions. The report focused on the adequacy of the multiple layers of safety practice ({open_quotes}defense-in-depth{close_quotes}) at WIPP, which are designed to (1) reduce the likelihood of accidents and (2) limit the consequences of those accidents. The safeguards which contribute to defense-in-depth at WIPP include a substantial array of inherent design features, engineered controls, and administrative procedures. The SAR Update confirmed that the defense-in-depth at WIPP is adequate to assure the protection of the public and environment. As a supplement to the 1995 SAR Update, we have conducted additional analyses to confirm that these controls will also provide adequate protection to workers at the WIPP. The approaches and results of the worker dose assessment are summarized here. In conformance with the guidance of DOE Standard 3009-94, we emphasize that use of these evaluation guidelines is not intended to imply that these numbers constitute acceptable limits for worker exposures under accident conditions. However, in conjunction with the extensive safety assessment in the 1995 SAR Update, these results indicate that the Carlsbad Area Office strategy for the assessment of hazards and accidents assures the protection of workers, members of the public, and the environment.

  7. Dose assessment for emergency workers in early phase of Fukushima Daiichi nuclear power plant accident

    Energy Technology Data Exchange (ETDEWEB)

    Sadeghi, Nahid; Ahangari, Rohollah; Kasesaz, Yaser; Noori-kalkhoran, O. [Nuclear Science and Technology Research Institute (NSTRI), Tehran (Iran, Islamic Republic of). Reactor Research School

    2017-11-15

    In the case of Fukushima Daiichi nuclear power plant (FNP) accident, the radioactive material was released from reactor units 1-3 and transported to short and long distances due to the atmospheric pathways-motions. Power sources for monitoring posts were lost due to earthquake and tsunami. Based on air dose rates and other data measured by monitoring cars, the amount of radioactive material released to the atmosphere from the power station was obtained. The atmospheric dispersion and the transport model used in the RASCAL code, estimate the radionuclide concentrations downwind, both in the air and on the ground due to deposition. The calculated concentrations are then used to estimate the projected doses for workers in vicinity of the accident area in the first minutes of accident time. For dose modeling, we assumed that each worker was 15 min in vicinity of FNP in accident situation, once without and once with protective clothes or respirator. According to Tokyo Electric Power Company (TEPCO) report six workers had received doses over 250 mSv (309 to 678 mSv) apparently due to inhaling Iodine-131 fume. In this paper the calculated dose results using RASCAL code shows that, if emergency workers who work in early phase of accident had not used protective equipment, for 15 min, inhalation doses from iodine in their thyroid gland up to 12 March afternoon would have been 520 mSv. A comparison between calculation results and TEPCO report shows that dose calculated virtually is nearly equal to TEPCO measurement results.

  8. Long-term mortality study of workers occupationally exposed to metallic nickel at the Oak Ridge Gaseous Diffusion Plant

    International Nuclear Information System (INIS)

    Godbold, J.H. Jr.; Tompkins, E.A.

    1979-01-01

    This study was undertaken to determine whether mortality from respiratory cancer among workers occupationally exposed to metallic nickel at the Oak Ridge Gaseous Diffusion Plant (ORGDP) differed from that of workers at the same plant with no record of occupational exposure to metallic nickel or any nickel compound. A cohort of 814 nickel-exposed workers and one of 1600' controls were identified. The members of both cohorts had a minimum follow-up period of 19 years. Mortality from respiratory cancer and from other causes was examined in both groups. The data showed no evidence of an increased risk of mortality due to respiratory cancer among the nickel-exposed workers. The exposed cohort experienced lower mortality than the controls, both in deaths due to respiratory cancer and in deaths due to all causes, although neither of these differences was statistically significant

  9. Study of cancer incidence among 6363 male workers in four Norwegian ferromanganese and silicomanganese producing plants.

    Science.gov (United States)

    Hobbesland, A; Kjuus, H; Thelle, D S

    1999-09-01

    Little has been known about the risk of cancer associated with occupational exposure to manganese. The objective of this study was therefore to examine the associations between duration of specific work and cancer incidence among employees in four Norwegian ferromanganese and silicomanganese producing plants. Among men first employed in 1933-91 and with at least 6 months in these plants, the incident cases of cancer during 1953-91 were obtained from The Cancer Registry of Norway. The numbers of various cancers were compared with expected figures calculated from age and calendar time specific rates for Norwegian men during the same period. Internal comparisons of rates were performed with Poisson regression analysis. The final cohort comprised 6363 men. A total of 607 cases of cancer were observed against 596 cases expected (standardised incidence ratio (SIR) 1.02). Internal comparisons of rates showed a positive trend between the rate of all cancers and duration of furnace work. A slightly weaker trend was also found for duration of blue collar non-furnace work when lags of 25 or 30 years were applied in the analyses. However, several results indicated that the incidence of all cancers among the non-furnace workers decreased during the period of active employment. Furnace and non-furnace workers may have exposures that increase the incidence of several cancers. The low incidence of cancer among non-furnace workers during the period of ongoing exposure cannot be explained. As this study cannot identify any causal factors, the role of exposure to manganese remains unclear.

  10. An innovative program to increase safety culture for workers on a nuclear power plant

    International Nuclear Information System (INIS)

    Schryvers, Vincent

    2007-01-01

    Full text: To implement the WENRA harmonized guidelines and the IAEA reference guides, Electrabel has recently introduced a major training program for both its own staff and the contractors working on the sites of its Nuclear Power Plants. This training program stresses the importance of safety culture on both theoretical and practical level and is mostly focused on the behavioural aspects during activities performed at the site of a Nuclear Power Plant. Further emphasis is put on radiation protection, industrial safety, environmental protection and explosion prevention. The training scheme for both the staff of Electrabel and contractors typically contains a theoretical part introducing the basic concepts of nuclear safety and safety culture and a practical exercise in a simulated environment. A novel element in the training cycle is the use of a simulated environment, where the actual working conditions in the nuclear part of the installation are simulated. This mock-up installation enables the workers to train the nuclear safety constraints linked to the actual installation and to enhance safety culture by responding on simulated problems and changing conditions possibly being encountered during an intervention at the real working site. To analyze the behaviour of the future workers, the activities are videotaped and commented for further improvement. A refresh of the training courses is implemented after 3 years.Although this training program has only been in operation for just 6 months, the response of the contractors and the staff to this training has been enthusiastic. At this moment, more than 1.000 workers have successfully completed the training course. (author)

  11. Fine coke production from brown coal (Report on ECSC contract 6220-72/1/102)

    Energy Technology Data Exchange (ETDEWEB)

    1977-01-01

    The possibility of producing a dry brown coal suitable for the production of fine coke and the development of a suitable carbonization process were studied. To prepare the coal it should be screened at 1 mm with the oversize going to fine coke production and the undersize going to briquette production. To increase fine coke production it is necessary to screen the raw smalls less than 2 mm and to pelletize, dry and carbonize them with the coarser constituents. The planning and construction of a hearth oven furnace plant was begun and this is now in operation. A fluidized bed can be used to preheat the coal to improve the oven performance. (In German)

  12. The year-book of the Coke Oven Managers' Association 2006

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The 87th volume of the Year Book outlines activities of the Coke Oven Managers' Association throughout 2006 and reproduces transactions presented to the industry through its various sections. It includes lists of Council and Committee members and representation on committees and past presidents, and a full list of members. Reports of Council 2004-5 and of the annual general meeting 2005 are included. The Presidential address by M. Gore is on the last five years of Monckton Coke and Chemical Company. Carbonisation and briquetting works in the United Kingdom, Koppers carbon materials and chemical works in the UK and Europe, European coking plants, their addresses and managers are listed. Seven transactions are abstracted separately on the Coal Abstracts database.

  13. The year-book of the Coke Oven Managers' Association 2008

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    The 89th volume of the Year Book outlines activities of the Coke Oven Managers' Association throughout 2008 and reproduces transactions presented to the industry through its various sections. It includes lists of Council and Committee members and representation on committees and past presidents, and a full list of members. Reports of Council 2006-7 and of the annual general meeting 2007 are included. The Presidential address by A. Moore is about his experiences at Redcar Coke Ovens. Carbonisation and briquetting works in the United Kingdom, Koppers carbon materials and chemical works in the UK and Europe, European coking plants, their addresses and managers are listed. Six transactions are abstracted separately on the Coal Abstracts database.

  14. The year-book of the Coke Oven Managers' Association 2007

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    The 88th volume of the Year Book outlines activities of the Coke Oven Managers' Association throughout 2007 and reproduces transactions presented to the industry through its various sections. It includes lists of Council and committee members and representation on committees and past presidents, and a full list of members. Reports of Council 2005-6 and of the annual general meeting 2005 are included. The Presidential address by R.G.W. Sargent looks at the situation faced by coke oven managers through the decades with some predictions for the future. Carbonisation and briquetting works in the United Kingdom, Koppers carbon materials and chemical works in the UK and Europe, European coking plants, their addresses and managers are listed. Nine transactions are abstracted separately on the Coal Abstracts database.

  15. Clean utilization of high sulphur petroleum coke by circulating fluidized bed combustion (CFBC) in Romania

    International Nuclear Information System (INIS)

    Dragos, L.; Flueraru, C.; Girjoaba, M.

    1996-01-01

    The economic and environmental problems caused by inefficient utilization of residual high-sulphur petroleum coke resulted from oil cracking in Romania is discussed. A special research programme applying CFBC technology has been carried out in the Institute for Power Equipment, Bucharest. The results from both laboratory facilities and pilot plant are presented. The main operating conditions and parameters are pointed out. Data on quality and composition of petroleum coke, combustion efficiency, temperature range in different zones and flue gas composition at distinct operating loads are given. The results obtained will be used for innovative design of CFBC boilers based on petroleum coke. A project for implementing a CFBC boiler in one of the Romanian oil refineries is being developed. An analysis of technical and economic advantages of these boilers for energy generation is presented

  16. Foreign Workers, Foreign Multinationals, and Wages after Controlling for Occupation and Sex in Malaysia’s Manufacturing Plants during the mid-1990s

    OpenAIRE

    Eric D., Ramstetter

    2017-01-01

    This paper investigates the effects of foreign worker shares and MNE ownership on wages after controlling for worker sex and occupation in Malaysian manufacturing plants during 1994-1996, an important period during which use of foreign workers began to increase substantially. In a previous paper, I estimated similar wage equations separately for five occupation groups of both sexes in large heterogeneous samples of plants in many industries and more homogeneous samples of plants in seven indu...

  17. Study and modelling of deactivation by coke in catalytic reforming of hydrocarbons on Pt-Sn/Al{sub 2}O{sub 3} catalyst; La microbalance inertielle: etude et modelisation cinetique de la desactivation par le coke en reformage catalytique des hydrocarbures sur catalyseur Pt-Sn/Al{sub 2}O{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Mathieu-Deghais, S.

    2004-07-01

    Catalytic reforming is the refining process that produces gasoline with a high octane number. During a reforming operation, undesired side reactions promote the formation of carbon deposits (coke) on the surface of the catalyst. As the reactions proceed, the coke accumulation leads to a progressive decrease of the catalyst activity and to a change in its selectivity. Getting this phenomenon under control is interesting to optimize the industrial plants. This work aims to improve the comprehension and the modeling of coke formation and its deactivating effect on reforming reactions, while working under conditions chosen within a range as close as possible to the industrial conditions of the regenerative process. The experimental study is carried out with a micro unit that is designed to observe simultaneously the coke formation and its influence on the catalyst activity. A vibrational microbalance reactor (TEOM - Tapered Element Oscillating Microbalance) is used to provide continuous monitoring of coke. On-line gas chromatography is used to observe the catalyst activity and selectivity as a function of the coke content. The coking experiments are performed on a fresh Pt-Sn/alumina catalyst, with mixtures of hydrocarbon molecules of 7 carbon atoms as hydrocarbon feeds. The coking tests permitted to highlight the operating parameters that may affect the amount of coke, and to identify the hydrocarbon molecules that behave as coke intermediate. A kinetic model for coke formation could be developed through the compilation of these results. The catalytic activity analysis permitted to point out the coke effect on both of the active phases of the catalyst, to construct a simplified reforming kinetic model that simulates the catalyst activity under the reforming conditions, and to quantify deactivation via deactivation functions. (author)

  18. Coke fouling monitoring by electrical resistivity

    Energy Technology Data Exchange (ETDEWEB)

    Bombardelli, Clovis; Mari, Livia Assis; Kalinowski, Hypolito Jose [Universidade Tecnologica Federal do Parana (UTFPR), Curitiba, PR (Brazil). Programa de Pos-Graduacao em Engenharia Eletrica e Informatica Industrial (CPGEI)

    2008-07-01

    An experimental method to simulate the growth of the coke fouling that occurs in the oil processing is proposed relating the thickness of the encrusted coke to its electrical resistivity. The authors suggest the use of the fouling electrical resistivity as a transducer element for determining its thickness. The sensor is basically two electrodes in an electrically isolated device where the inlay can happen in order to compose a purely resistive transducer. Such devices can be easily constructed in a simple and robust form with features capable to face the high temperatures and pressures found in relevant industrial processes. For validation, however, it is needed a relationship between the electrical resistivity and the fouling thickness, information not yet found in the literature. The present work experimentally simulates the growth of a layer of coke on an electrically insulating surface, equipped with electrodes at two extremities to measure the electrical resistivity during thermal cracking essays. The method is realized with a series of consecutive runs. The results correlate the mass of coke deposited and its electrical resistivity, and it can be used to validate the coke depositions monitoring employing the resistivity as a control parameter. (author)

  19. Health-hazard evaluation report No. HETA-88-377-2120, Armco Coke Oven, Ashland Kentucky

    International Nuclear Information System (INIS)

    Kinnes, G.M.; Fleeger, A.K.; Baron, S.L.

    1991-06-01

    In response to a request from the Oil, Chemical and Atomic Workers International Union, a study was made of possible hazardous working conditions at ARMCO Coke Oven (SIC-3312), Ashland, Kentucky. The facility produces about 1,000,000 tons of coke annually. Of the approximately 400 total employees at the coke oven site, 55 work in the by products area. Air quality sampling results indicated overexposure to both benzene (71432) and coal tar pitch volatiles (CTPVs). Airborne levels of benzene ranged as high as 117 parts per million (ppm) with three of 17 samples being above the OSHA limit of 1ppm. Airborne concentrations of CTPVs ranged as high as 0.38mg/cu m with two of six readings being above OSHA limit of 0.2mg/cu m. Several polynuclear aromatic hydrocarbons were also detected. The authors conclude that by products area workers are potentially overexposed to carcinogens, including benzene, CTPVs, and polynuclear aromatic hydrocarbons. An epidemiologic study is considered unlikely to yield meaningful information at this time, due to the small number of workers and the short follow up period. The authors recommend specific measures for reducing potential employee exposures, including an environmental sampling program, a preventive maintenance program, improved housekeeping procedures, and reducing exposure in operators' booths

  20. Evaluation of coke microstructure and its effects on graphite fabrication

    International Nuclear Information System (INIS)

    Fotourehchian, S.; Ahmadi, S.

    2001-01-01

    A variety of applications for cokes (metallurgy, petroleum, etc.) have been defined in parallel to the new industrial technology growth. Coke is rich in carbon and has the main role in manufacturing carbonaceous materials such as graphite, steel, silicon carbide, titanium carbide, etc. Among the most important applications of different variety of cokes is their usage for different graphite fabrications. The crystalline structure of graphite (hexagonal with sp 2 hybrid) is based upon the microstructure of coke and it causes anisotropy in properties of produced graphite. Thus, the study of macrostructure and anisotropy degree of cokes is of importance. There are several theoretical and experimental methods to determine the Coke's microstructure and anisotropy. Numerous tests have been conducted on different variety of cokes based on the used method. Here, it is attempted to introduce an applied method to determine the microstructure and anisotropy degree of cokes based upon the kind of application

  1. Technology for beneficiation of non-coking coals

    Energy Technology Data Exchange (ETDEWEB)

    Bose, S.K.

    1987-04-01

    This article outlines the need for efficient non-coking coal beneficiation plants in India to cope with mass production from opencast coal mines. The existing use of magnetite in heavy medium separation processes is expensive and not very efficient in respect to removing shales from opencast lump coals. Instead a new technique is proposed using a ROMJIG washing plant developed in the Federal Republic of Germany. This provides a very efficient, low cost washing system for the coals and allows the continued integration with the coal blending plants. This simplified technology allows for flexible working hours to meet demand and will allow new developments to continue including fuel slurry pipelines, automated testing of coals and new pulverized boiler fuels.

  2. Fissure formation in coke. 3: Coke size distribution and statistical analysis

    Energy Technology Data Exchange (ETDEWEB)

    D.R. Jenkins; D.E. Shaw; M.R. Mahoney [CSIRO, North Ryde, NSW (Australia). Mathematical and Information Sciences

    2010-07-15

    A model of coke stabilization, based on a fundamental model of fissuring during carbonisation is used to demonstrate the applicability of the fissuring model to actual coke size distributions. The results indicate that the degree of stabilization is important in determining the size distribution. A modified form of the Weibull distribution is shown to provide a better representation of the whole coke size distribution compared to the Rosin-Rammler distribution, which is generally only fitted to the lump coke. A statistical analysis of a large number of experiments in a pilot scale coke oven shows reasonably good prediction of the coke mean size, based on parameters related to blend rank, amount of low rank coal, fluidity and ash. However, the prediction of measures of the spread of the size distribution is more problematic. The fissuring model, the size distribution representation and the statistical analysis together provide a comprehensive capability for understanding and predicting the mean size and distribution of coke lumps produced during carbonisation. 12 refs., 16 figs., 4 tabs.

  3. Longitudinal effects of disaster-related experiences on mental health among Fukushima nuclear plant workers: The Fukushima NEWS Project Study.

    Science.gov (United States)

    Ikeda, A; Tanigawa, T; Charvat, H; Wada, H; Shigemura, J; Kawachi, I

    2017-08-01

    The Fukushima Nuclear Energy Workers' Support (NEWS) Project Study previously showed that experiences related to the Fukushima nuclear disaster on 11 March 2011 had a great impact on psychological states, including post-traumatic stress response (PTSR) and general psychological distress (GPD), among the Fukushima nuclear plant workers. To determine the causal relationship between disaster-related experiences and levels of psychological states, we conducted a 3-year longitudinal study from 2011 to 2014. PTSR and GPD of the nuclear plant workers were assessed by annual questionnaires conducted from 2011 to 2014. The present study included a total of 1417 workers who provided an assessment at baseline (2011). A total of 4160 observations were used in the present analysis. The relationship between disaster-related experiences and psychological states over time was analysed using mixed-effects logistic regression models. A declining influence of disaster-related experiences on PTSR over time was found. However, the impact on PTSR remained significantly elevated even 3 years after the disaster in several categories of exposure including the experience of life-threatening danger, experiences of discrimination, the witnessing of plant explosion, the death of a colleague and home evacuation. The associations between GPD and disaster-related experiences showed similar effects. The effects of disaster-related experiences on psychological states among the nuclear plant workers reduced over time, but remained significantly high even 3 years after the event.

  4. Closed-cycle process of coke-cooling water in delayed coking unit

    International Nuclear Information System (INIS)

    Zhou, P.; Bai, Z.S.; Yang, Q.; Ma, J.; Wang, H.L.

    2008-01-01

    Synthesized processes are commonly used to treat coke-cooling wastewater. These include cold coke-cut water, diluting coke-cooling water, adding chemical deodorization into oily water, high-speed centrifugal separation, de-oiling and deodorization by coke adsorption, and open nature cooling. However, because of water and volatile evaporation loss, it is not suitable to process high-sulphur heavy oil using open treatments. This paper proposed a closed-cycling process in order to solve the wastewater treatment problem. The process is based on the characteristics of coke-cooling water, such as rapid parametric variation, oil-water-coke emulsification and steam-water mixing. The paper discussed the material characteristics and general idea of the study. The process of closed-cycle separation and utilization process of coke-cooling water was presented along with a process flow diagram. Several applications were presented, including a picture of hydrocyclones for pollution separation and a picture of equipments of pollution separation and components regeneration. The results showed good effect had been achieved since the coke-cooling water system was put into production in 2004. The recycling ratios for the components of the coke-cooling water were 100 per cent, and air quality in the operating area reached the requirements of the national operating site circumstance and the health standards. Calibration results of the demonstration unit were presented. It was concluded that since the devices went into operation, the function of production has been normal and stable. The operation was simple, flexible, adjustable and reliable, with significant economic efficiency and environmental benefits. 10 refs., 2 tabs., 3 figs

  5. Calcinating petroleum coke in a furnace with a rotating hearth

    Energy Technology Data Exchange (ETDEWEB)

    Akhmetov, M M; Ezhov, B M; Galeeva, Z G; Goriunov, V S; Karpinskaia, N N; Zaitseva, S A

    1980-01-01

    A scheme is described for an industrial device with a bottom furnace for calcinating coke from slow coking. The consumption and operational indicators of the process during the calcination of standard and needle cokes are given, together with data on the quality of dry and calcinated cokes under different conditions. The basic drawbacks in the operation of the device are described, and measures are proposed for increasing its operational effectiveness.

  6. Monitoring of exposure to selected metals in workers of a ferroalloy production plant using NAA and PIXE

    International Nuclear Information System (INIS)

    Kucera, J.; Havranek, V.; Hnatowicz, V.; Bencko, V.; Fabianova, E.; Sysalova, J.

    1998-01-01

    Advantages and pitfalls of direct and biological monitoring of occupational exposure are briefly mentioned and a project aimed at evaluating exposure to chromium (and possibly manganese) in workers of a ferro-alloy production plant using both the above approaches is outlined. Facilities for NAA and PIXE at the Nuclear Physics Institute at Rez to be used in the project are described. Results of quality assurance of INAA method for analysis of workplace air born particulate matter and blood sampling are presented. Results from previous work relating to this Co-ordinated Research Programme - studying exposure of workers of a vanadium pentoxide production plant are also briefly reviewed. (author)

  7. Mean-term forecast of coke production in the world

    International Nuclear Information System (INIS)

    Ukhmylova, G.S.

    1996-01-01

    The causes of decrease in consumption of metallurgical coke in the world in the ninetieth and at the present time are analyzed. Reduction of reliable coke supply sources to the world market is noted. The data on the coke import and export in the world in 1990-1994 are presented and corresponding forecasts for 2000 and 2005 are given

  8. Fundamentals of Delayed Coking Joint Industry Project

    Energy Technology Data Exchange (ETDEWEB)

    Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

    2003-02-07

    The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

  9. Urinary nickel as bioindicator of workers' Ni exposure in a galvanizing plant in Brazil.

    Science.gov (United States)

    Oliveira, J P; de Siqueira, M E; da Silva, C S

    2000-01-01

    We measured urinary nickel (U-Ni) in ten workers (97 samples) from a galvanizing plant that uses nickel sulfate, and in ten control subjects (55 samples) to examine the association between occupational exposure to airborne Ni and Ni absorption. Samples from the exposed group were taken before and after the work shift on 5 successive workdays. At the same time airborne Ni (A-Ni) was measured using personal samplers. Ni levels in biological material and in the airborne were determined by a graphite furnace atomic absorption spectrometry validated method. In the control group the urine samples were collected twice a day, in the before and after the work shift, on 3 successive days. Ni exposure low to moderate was detected in all the examined places in the plant, the airborne levels varying between 2.8 and 116.7 micrograms/m3 and the urine levels, from samples taken postshift, between 4.5 and 43.2 micrograms/g creatinine (mean 14.7 micrograms/g creatinine). Significant differences in U-Ni creatinine were seen between the exposed and control groups (Student's t test, P galvanizing plants regardless of the day of the workweek on which the samples are collected.

  10. Case-control study of lung cancer among workers at a uranium processing plant

    International Nuclear Information System (INIS)

    Cookfair, D.L.

    1982-01-01

    The purpose of this case-control study was to investigate the relationship between exposure to radiation resulting from the inhalation of uranium dust and the dust of uranium-bearing compounds and death due to lung cancer. Cases and controls were chosen from a cohort of white male workers employed at one uranium processing plant during World War II. The 330 cases consisted of all lung cancer deaths occurring in the cohort between 1943 and 1973. Level of exposure to radiation and other potential workplace carcinogens was determined for each worker using process manuals, industrial hygiene reports, air monitoring data and individual work histories. Smoking status and information regarding medical variables was determined from employee medical records. Cumulative radiation lung dose among study population members ranged from 0 to 75 rads. Data were analyzed using Mantel-Haenszel stratified analysis and logistic regression. Relative risk was found to increase with increasing level of lung dose exposure even after controlling for age, smoking status and other workplace exposures, but only for those who were over the age of 44 when first exposed. A statistically significant excess in risk was found for men in this hire age group with a cumulative lung dose of 20 rads or more. The risk associated with the overall work environment was also investigated using a summary measure of total workplace exposure called chemical rank. A similar relationship existed between chemical rank and lung cancer to that found for cumulative lung dose and lung cancer

  11. Ionizing radiation dose control for workers in a nuclear plant working with unsealed sources

    International Nuclear Information System (INIS)

    Gerulis, Eduardo

    2006-01-01

    With the liberation of the use of the nuclear energy for peaceful applications, International Commission Radiological Protection, ICRP, founded in 1928, created a system of protection of the undesirable doses of ionizing radiation in 1958. This has been received by workers, members of the public and environment and hence it became possible for the introduction of these applications. This protection system is adopted by the International Agency of Energy Atomic, IAEA, that publishes recommendations in safety series, 88 and by the Comissao Nacional de Energia Nuclear, CNEN, which publishes these regulations. The international recommendations and national regulations were adapted and they need to be applied in this way. The present paper uses recommendations of the publication 75 from ICRP, of the publication 115 from 88 and regulations of the regulation NN 3.01 from CNEN to present, through radiological protection measures, the ionizing radiation dose control for workers in a nuclear plant that works in the research, production, division and packing of unsealed sources to be used in clinical applications. In that way it is possible to prevent appropriately the undesirable doses and to confirm the received doses. (author)

  12. Estimation of impact from natural sources of radiation sources in two non nuclear plant workers and nearby residents

    International Nuclear Information System (INIS)

    Sousa, Wanderson de Oliveira

    2005-09-01

    Naturally occurring radioactive materials, often referred to as NORM, are and always have been a part of our world. Our planet 'Earth' and its atmosphere contain many different types of naturally occurring radioactive species , mainly minerals containing radionuclides of uranium and thorium decay series. Human activities for e x p l o i t a t i o n of mineral resources as mining, necessarily, do not enhance the concentration of NORM in products , by-products or residues, but can be a concern, simply due to the increased potential for human exposure. The goal of this work is to assess the impact of the presence of two non-nuclear plants (coal mining and monazite extraction plant) to workers and general population living in the vicinities of plants, by calculating their internal exposure to natural radionuclides . Excreta samples (urine and feces) were collected from workers and inhabitants of the two small towns where workers reside. The activities of 238 U, 234 U ( o n l y in feces), 226 Ra , 210 Pb and 210 Po (only in urine),- present in the samples were determined. The results of daily excretion in urine and feces of the groups, indicate that workers from coal mining, are exposed to natural radionuclides by inhalation and ingestion. The intake of some radionuclides ( 238 U and 210 Po ) are influenced by the professional activity . The results also indicate a chronic intake of 226 Ra by workers of the coal mining and their neighbors. Workers from the monazite extraction plant and inhabitants of the vicinity of the plant are exposed, mainly by ingestion. The intake through diet is the major source of incorporation of natural radionuclides. (author)

  13. Dynamic Impact of Fluoride Dust on Industrial Workers in Thermal Power Plant and its Feasibility Study on Troposphere

    Science.gov (United States)

    Katiyar, Swati; Kumar, Pawan

    2016-07-01

    Fluorine is a common element that does not occur in the elemental state in nature because of its high reactivity. It accounts for about 0.3 g kg-1 of the Earth's crust and exists in the form of fluorides in a number of minerals, of which fluorspar, cryolite and fluorapatite are the most common. This paper focuses on the analysis of flouride on the industrial workers in various working conditions on troposphere. To check the impact of flouride on workers various samples were taken from different conditions of aluminum plant industries like pot room workers and non-pot room workers as fluoride has both beneficial and detrimental effects on human health. 50 workers in pot room and 10 workers in non pot room were chosen for taking urine and serum samples. 0.09 to 3.77 mg Kg -1 and 0.39 to 1.15 mg Kg-1 (of ash weight) was recorded in the nails of pot room and non pot room workers respectively. The average flouride content was recorded as 1.10 mg Kg -1 and 0.65 mg Kg -1 in pot room and non pot room workers respectively. The outcome results clearly indicated the ill effect and dangerous for the dental health as well as physical health of the workers. A preventive measure or precaution should be taken by the management or persons to avoid the impact of flouride on the body. The clinical significance lie in the maintaining hygienic condition while preventing the any possible effect of flouride on the workers of the industries, as this will affect the production as well as the human value in term of physical capabilities and social aspects in providing medical facilities. Keywords: Fluoride, Ecosystem, Dynamic impact, Air pollutant, detrimental effects.

  14. Blast-furnace coke production in high capacity coke oven batteries from the viewpoint of domestic raw material resources

    Energy Technology Data Exchange (ETDEWEB)

    Krause, W

    1977-05-01

    The problem is treated in a complex manner taking into account such technological improvements as: oiling, drying, charge preheating, dry quenching of coke as well as mechanical processing of coke which taken together will give blast furnace coke of the highest quality from domestic coals.

  15. Basic characteristics of new shape formed coke in burden distribution; Shingata seikei cokes no sonyu bunpu tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Ichida, M; Yamamoto, T; Komaki, I; Oda, H; Matsunaga, S; Matsuzaki, S; Deno, T; Konno, N [Nippon Steel Corp., Tokyo (Japan)

    1996-12-01

    Basic characteristics in burden distribution and charging pattern of new shape formed coke developed in order to improve the properties of small size and low void fraction that pillow-type formed coke h s were conducted by 1/3 scale charging model and mathematical model of blast furnace. Basic characteristics, those are, inclination angle, coke-collapse and trajectory of new shape formed coke are almost the same as those of conventional coke. In the case of wall charging of new shape formed coke, until 60% of total charged coke, new shape formed coke is able to be charged without it`s rolling to the center. It is possible to apply RABIT model to new shape formed coke charging without it`s major modification. In the case of new shape formed coke wall charging, the fluctuation in furnace is supposed to be smaller than that in the case of pillow-type formed coke wall charging. Moreover, it`s center charging is supposed to be applied to actual blast furnace. More accurate estimation of in-furnace phenomena by mathematical model considering coke reactivity, is a subject to be worked out in future. 11 refs., 9 figs., 5 tabs.

  16. Actions taken in order to reduce doses to workers in PWR power plants

    International Nuclear Information System (INIS)

    Jeanson, P.

    1978-01-01

    The dose limitation for workers in nuclear power plants is a permanent aim of Electricite de France. Many ways are followed at the same time to reach it, some of them in collaboration with C.E.A. Theoretical studies concern mostly sources and transfers of corrosion and fission products in the primary circuit of pressurized water reactors as well as the means for reducing the deposited activity. Practical studies concern design problems for equipment and buildings. They try to specify rules for these purposes. They also concern maintenance conditions of all components: for the most important components, special tools are designed. At last, studies and experimentation of daily dosimetry should bring a better knowledge of the distribution of collective doses and, subsequently, should give a better idea of the actions to be undertaken [fr

  17. Biometric estimation of chest wall thickness in female nonradiation workers of a monazite processing plant

    International Nuclear Information System (INIS)

    Radhakrishnan, Sujata; Maniyan, C.G.; Pillai, P.M.B.; Khan, A.H.

    2003-01-01

    Chest wall thickness (CWT) was estimated in fifty four female nonradiation workers of a monazite processing plant by biometric measurements. The CWT ranged from 4.12 cm to 6.94 cm giving an average of 5.19 ± 0.76 cm. CWT was found to have very good correlation with percent Body Fat and abdominal circumference but poor correlation with Body Mass Index, Body Build Index, Slenderness, age etc. CWT increases with age especially in the upper middle-aged group (> 35 years). A single measurement of abdominal circumference can be used to estimate CWT with 94 % accuracy. A factor of 0.0587 was derived to estimate CWT from abdominal circumference. The study also showed that about 11 % of the subjects were obese. The results obtained will be very useful for the accurate measurement of Low Energy Photons like 239 Pu and 241 Am deposited in the lung. (author)

  18. Fundamentals of Delayed Coking Joint Industry Project

    Energy Technology Data Exchange (ETDEWEB)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world

  19. Emission and source characterization of monoaromatic hydrocarbons from coke production

    Energy Technology Data Exchange (ETDEWEB)

    He, Q.S.; Wang, X.M.; Sheng, G.Y.; Fu, J.M. [Chinese Academy of Sciences, Guangzhou (China). State Key Laboratory of Organic Geochemistry

    2005-09-15

    Monoaromatic hydrocarbons (MAHs) from indigenous and industrial coking processes are studied in Shanxi province. They are sampled on the top of coke ovens and in the chimneys using stainless steel canister and determined by GC/MSD after preconcentration with liquid nitrogen. Benzene, toluene and xylene are the main components among MAHs emitted from coking processes. Benzene and the total MAHs concentrations were as high as 3421.0 microg/m3 and 4 865.9 microg/m3 in the air from indigenous coking, 548.7 microg/m3 and 1 054.8 microg/m3 in the oventop air from industrial coking, and 1 376.4 microg/m3 and 1 819.4 microg/m3 in stack gas from industrial coking, respectively. The MAHs concentrations vary greatly during the indigenous coking process, which in the prophase (from firing to 10 days) is obviously higher than in the anaphase (10 days to quenching the coke). In industrial coking the MAHs in the oventop air are highest when charging the coal and next when transferring the hot coke, but in stack gas they are highest when charging coal and lowest when transferring the coke. Benzene, toluene, ethylbenzene and xylene (BTEX) in industrial coking samples show good linearity, indicating that MAHs in industrial coking might come predominantly from coal pyrolysis; but BTEX distribute dispersedly in indigenous coking samples, indicating that its emission might be affected by many factors. In all samples BTEX ratios especially high B/E ratio, is unique among MAHs sources, and might be helpful to characterize pollution from coking.

  20. [Emission and source characterization of monoaromatic hydrocarbons from coke production].

    Science.gov (United States)

    He, Qiu-Sheng; Wang, Xin-Ming; Sheng, Guo-Ying; Fu, Jia-Mo

    2005-09-01

    Monoaromatic hydrocarbons (MAHs) from indigenous and industrial coking processes are studied in Shanxi province. They are sampled on the top of coke ovens and in the chimneys using stainless steel canister and determined by GC/MSD after preconcentration with liquid nitrogen. Benzene, toluene and xylene are the main components among MAHs emitted from coking processes. Benzene and the total MAHs concentrations were as high as 3421.0 microg/m3 and 4 865.9 microg/m3 in the air from indigenous coking, 548.7 microg/m3 and 1 054.8 microg/m3 in the oventop air from industrial coking, and 1 376.4 microg/m3 and 1 819.4 microg/m3 in stack gas from industrial coking, respectively. The MAHs concentrations vary greatly during the indigenous coking process, which in the prophase (from firing to 10 days) is obviously higher than in the anaphase (10 days to quenching the coke). In industrial coking the MAHs in the oventop air are highest when charging the coal and next when transferring the hot coke, but in stack gas they are highest when charging coal and lowest when transferring the coke. Benzene, toluene, ethylbenzene and xylene (BTEX) in industrial coking samples show good linearity, indicating that MAHs in industrial coking might come predominantly from coal pyrolysis; but BTEX distribute dispersedly in indigenous coking samples, indicating that its emission might be affected by many factors. In all samples BTEX ratios especially high B/E ratio, is unique among MAHs sources, and might be helpful to characterize pollution from coking.

  1. Zinc exposure for female workers in a galvanizing plant in Northern Italy.

    Science.gov (United States)

    Riccò, Matteo; Cattani, Silvia; Signorelli, Carlo

    2018-01-01

    Very little is known regarding the toxicokinetics of inhaled zinc, in particular in the case of female workers and for modern, low exposure settings. Our aim is to evaluate the relationship of external zinc levels to those of serum and urine for female workers. Eleven female workers (age: 41.7±8 years old, body mass index (BMI): 23.5±4.2 kg/m2) in a galvanizing plant were investigated. Exposure assessment consisted of personal/environmental air samples, and measurement of zinc in serum (collected at the end of first shift of the working week (T1)) and urine, collected before the first shift of the working week (T0), T1 and at the end of the last shift of the working week (T2). Both environmental and personal air samplings for zinc and zinc compounds were below the recommended by the German Research Foundation (Deutsche Forschungsgemeinschaft - DFG) limit values of 2 mg/m3 (7.34±2.8 μg/m3 and 8.31±2.4 μg/ m3, respectively). Serum (118.6±20.9 μg /dl) and urine zinc levels were within reference values for female Italian subjects: the latter increased from 56.4±33.5 μg/dl at T0, to 59.8±37.0 μg/dl at T1, and ultimately 65.4±34.4 μg/dl at T2, but no significant trend was found. End of shift (Spearman's correlation coefficient p value = 0.027) and differential excretion of urinary zinc (both: T0 vs. T1 and T0 vs. T2) were correlated with airborne zinc concentration (p = 0.002 and 0.006, respectively). In general, our data suggests that urine may be a useful medium also for female in order to assess zinc exposure. Further studies are required in order to evaluate whether differential excretion may be useful for the biomonitoring of zinc exposure in the workplaces also for male workers. Int J Occup Med Environ Health 2018;31(1):113-124. This work is available in Open Access model and licensed under a CC BY-NC 3.0 PL license.

  2. Gender, aging, and work: aging workers' strategies to confront the demands of production in maquiladora plants in nogales, Mexico.

    Science.gov (United States)

    Adarga, Mireya Scarone; Becerril, Leonor Cedillo; Champion, Catalina Denman

    2010-01-01

    This work is part of a qualitative socio-cultural investigation with a group of men and women 40 years and older in the maquila export industry in Nogales, Sonora, Mexico. In 1994, as a result of the North American Free Trade Agreement, maquila plants combined traditional intensive work methods with new "just in time" production norms that impacted work and health conditions, particularly in older, or aging, workers. The workers that were interviewed for this study show a reduction in their functional ability to work starting at 40 years of age. Work organization demands, general health conditions, and a decrease in physical abilities brings these 40-year-old workers to prematurely construct an image of themselves as aging workers and to develop coping strategies that vary by gender.

  3. Influence of biological aerosol from wastewater treatment plants on workers and the local residents health – literature review

    Directory of Open Access Journals (Sweden)

    Aleksandra Michalak

    2012-12-01

    Full Text Available Bioaerosol forms microbes, their toxins and fragments of microorganisms suspended as small droplets or solid particles. The group particularly exposed are workers of sewage treatment plants and local residents. Literature reports stress the role of the fecal bacteria from the Enterobacteriaceae family and yeasts, which create a real risk of air pollution near the waste water treatment plants Emission of pathogenic microbes prevails in the neighbourhood of of sedimentation tanks, sludge drying beds. Research shows that the extent of bioaerosol influence reaches the distance of 3 km away from any waster water treatment plant.. The most frequent symptoms reported by workers from waste water treatment plants and local residents are respiratory disorders. There are also gastrointestinal and skin problems and general disorders, that can be explained by exposure to endotoxins in bioaerosol.

  4. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    Energy Technology Data Exchange (ETDEWEB)

    T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  5. Mortality risk in a historical cohort of nuclear power plant workers in Germany: results from a second follow-up

    International Nuclear Information System (INIS)

    Merzenich, Hiltrud; Troeltzsch, Katrin; Ruecker, Kai; Buncke, Johanna; Blettner, Maria; Hammer, Gael P.; Fehringer, Franz

    2014-01-01

    Possible health effects of low and protracted doses of ionizing radiation are relevant for persons who are exposed to an occupational context like nuclear industry workers. A historical cohort study was therefore conducted to examine mortality risks following occupational radiation exposure among 4,844 German nuclear power plant workers. This cohort included workers from ten nuclear power plants with an observational period from 1991 until 1997. The results of an enlarged cohort with 8,972 workers from all 17 nuclear power plants in West Germany are now available. During the extended follow-up period from 1991 to 2008, a total of 310 deaths among men were observed. The standardized mortality ratio (SMR) from all causes of deaths was estimated at 0.50 [95 % confidence interval (CI) 0.45-0.56]. A total of 126 deaths due to cancer occurred (SMR = 0.65; 95 % CI 0.51-0.82) and seven deaths due to leukemia (SMR = 1.23; 95 % CI 0.42-2.84). Overall, a reduced mortality compared to the general population of West Germany was observed indicating a healthy worker effect. In the dose-response analysis, no statistically significant risk due to ionizing radiation was seen. The hazard ratio (HR/mSv) for leukemia excluding chronic lymphocytic leukemia was estimated at 1.004 (95 % CI 0.997-1.011). In conclusion, the cohort is small and made up of young workers, most of whom were still employed at the end of the observational period in 2008. Results of the external analysis are difficult to interpret as influenced by a healthy worker effect. In the internal analysis, no excess of risk due to radiation was detected. (orig.)

  6. Mortality risk in a historical cohort of nuclear power plant workers in Germany: results from a second follow-up

    Energy Technology Data Exchange (ETDEWEB)

    Merzenich, Hiltrud; Troeltzsch, Katrin; Ruecker, Kai; Buncke, Johanna; Blettner, Maria [University Medical Center Mainz, Institute of Medical Biostatistics, Epidemiology and Informatics, Mainz (Germany); Hammer, Gael P. [University Medical Center Mainz, Institute of Medical Biostatistics, Epidemiology and Informatics, Mainz (Germany); Laboratoire National de Sante E.P., Registre Morphologique des Tumeurs, Dudelange (Luxembourg); Fehringer, Franz [Berufsgenossenschaft Energie Textil Elektro Medienerzeugnisse (BGETEM), Cologne (Germany)

    2014-05-15

    Possible health effects of low and protracted doses of ionizing radiation are relevant for persons who are exposed to an occupational context like nuclear industry workers. A historical cohort study was therefore conducted to examine mortality risks following occupational radiation exposure among 4,844 German nuclear power plant workers. This cohort included workers from ten nuclear power plants with an observational period from 1991 until 1997. The results of an enlarged cohort with 8,972 workers from all 17 nuclear power plants in West Germany are now available. During the extended follow-up period from 1991 to 2008, a total of 310 deaths among men were observed. The standardized mortality ratio (SMR) from all causes of deaths was estimated at 0.50 [95 % confidence interval (CI) 0.45-0.56]. A total of 126 deaths due to cancer occurred (SMR = 0.65; 95 % CI 0.51-0.82) and seven deaths due to leukemia (SMR = 1.23; 95 % CI 0.42-2.84). Overall, a reduced mortality compared to the general population of West Germany was observed indicating a healthy worker effect. In the dose-response analysis, no statistically significant risk due to ionizing radiation was seen. The hazard ratio (HR/mSv) for leukemia excluding chronic lymphocytic leukemia was estimated at 1.004 (95 % CI 0.997-1.011). In conclusion, the cohort is small and made up of young workers, most of whom were still employed at the end of the observational period in 2008. Results of the external analysis are difficult to interpret as influenced by a healthy worker effect. In the internal analysis, no excess of risk due to radiation was detected. (orig.)

  7. 77 FR 32998 - Foundry Coke From China

    Science.gov (United States)

    2012-06-04

    ... China Determination On the basis of the record \\1\\ developed in the subject five-year review, the United... China would be likely to lead to continuation or recurrence of material injury to an industry in the... Publication 4326 (May 2012), entitled Foundry Coke from China: Investigation No. 731-TA-891 (Second Review...

  8. Alternative method for assessing coking coal plasticity

    Energy Technology Data Exchange (ETDEWEB)

    Dzuy Nguyen; Susan Woodhouse; Merrick Mahoney [University of Adelaide (Australia). BHP Billiton Newcastle Technology Centre

    2008-07-15

    Traditional plasticity measurements for coal have a number of limitations associated with the reproducibility of the tests and their use in predicting coking behaviour. This report reviews alternative rheological methods for characterising the plastic behaviour of coking coals. It reviews the application of more fundamental rheological measurements to the coal system as well as reviewing applications of rheology to other physical systems. These systems may act as potential models for the application of fundamental rheological measurements to cokemaking. The systems considered were polymer melts, coal ash melts, lava, bread making and ice cream. These systems were chosen because they exhibit some physically equivalent processes to the processes occurring during cokemaking, eg, the generation of bubbles within a softened system that then resolidifies. A number of recommendations were made; the steady and oscillatory shear squeeze flow techniques be further investigated to determine if the measured rheology characteristics are related to transformations within the coke oven and the characteristics of resultant coke; modification of Gieseler plastometers for more fundamental rheology measurements not be attempted.

  9. Trend of collective dose and dose reduction measures of Mitsubishi Electric Corporation workers in nuclear power plants

    International Nuclear Information System (INIS)

    Yamato, I.; Nakayama, T.; Shimokawa, F.; Yamamoto, T.

    1996-01-01

    MELCO has supplied the reactor instrumentation control system, reactor coolant pump motors, turbine generator and central control system for the pressurized water type nuclear power plant. For the legal periodical inspection and repair work, MELCO has also received orders for the periodical inspection for 23 power plants (including 4 plants under construction) of 5 electric power companies, and executed the inspection work from the view point of preventive maintenance. The annual dose for MELCO's workers is liable to be decreased in spite of increased number of plants. The dose for new plant in particular is 50, or less as compared with that for conventional plant. This is because the measures taken for the conventional plant against the dose reduction is reflected upon the new plant. The dose reduction measures are taken for each system for which order was received. Such measures are mainly intended to improve the work procedures and equipment for reduction of work time in the radioactive area and to arrange the working process, so as to perform the work in such period when the dose level at the working environment is low. To enhance the workers' consciousness for reduction of dose, MELCO provided the workers with dose predictive training, and let them aware of such items known at the tool box briefing (TBX), which could realize the dose reduction for workers. MELCO has been positively promoting the activity to arrange the desirable work environment for extermination of 3Ks (giken, gitsui, titanai) or 3Ds (dangerous, difficult, dirty) including protection against radiation in corporation with electric power companies. (author)

  10. The impact of liquid-liquid-vapour phase behaviour on coke formation from model coke precusors

    Energy Technology Data Exchange (ETDEWEB)

    Minicucci, D.; Shaw, J.M. [Univ. of Toronto, Dept. of Chemical Engineering and Applied Chemistry, Toronto, ON (Canada)

    2000-08-01

    Catalysts used in the hydroprocessing of heavy feedstocks deactivate due to coke deposition. Although the mechanism for coke formation is not fully understood, condensation reactions of polynuclear aromatic compounds present in the feeds are a key aspect. The effect of coke deposition on catalyst performance is typically modelled using accelerated aging agents comprising model coke precursors. Mixtures employed in such studies polynuclear aromatic compounds such as anthracene as the coke precursor, and long chain alkanes such as hexadecane as a diluent. We show in this paper that binary and pseudo binary mixtures of polynuclear aromatic compounds and n-alkanes present TYPE II, TYPE IV, or TYPE III phase behaviour according to the van Konynenburg and Scott (1980) phase projection nomenclature, Incubation periods and the apparent autocatalytic effects associated with coke deposition in such systems are explained through a combination of high temperature phase equilibrium experiments and computations with the model systems n-alkane + anthracene + hydrogen, n-alkane + pyrene + hydrogen, and n-alkane + dibenzo[a,k]chrysene + hydrogen. (au)

  11. Nitrogen Chemistry and Coke Transformation of FCC Coked Catalyst during the Regeneration Process

    Science.gov (United States)

    Shi, Junjun; Guan, Jianyu; Guo, Dawei; Zhang, Jiushun; France, Liam John; Wang, Lefu; Li, Xuehui

    2016-06-01

    Regeneration of the coked catalyst is an important process of fluid catalytic cracking (FCC) in petroleum refining, however, this process will emit environmentally harmful gases such as nitrogen and carbon oxides. Transformation of N and C containing compounds in industrial FCC coke under thermal decomposition was investigated via TPD and TPO to examine the evolved gaseous species and TGA, NMR and XPS to analyse the residual coke fraction. Two distinct regions of gas evolution are observed during TPD for the first time, and they arise from decomposition of aliphatic carbons and aromatic carbons. Three types of N species, pyrrolic N, pyridinic N and quaternary N are identified in the FCC coke, the former one is unstable and tends to be decomposed into pyridinic and quaternary N. Mechanisms of NO, CO and CO2 evolution during TPD are proposed and lattice oxygen is suggested to be an important oxygen resource. Regeneration process indicates that coke-C tends to preferentially oxidise compared with coke-N. Hence, new technology for promoting nitrogen-containing compounds conversion will benefit the in-situ reduction of NO by CO during FCC regeneration.

  12. Upgrading oil sands bitumen with FLUID COKING and FLEXICOKING technologies

    Energy Technology Data Exchange (ETDEWEB)

    Kamienski, P.; Phillips, G. [ExxonMobil Research and Engineering Co., Fairfax, VA (United States); McKnight, C.; Rumball, B. [Syncrude Canada Ltd., Calgary, AB (Canada)

    2009-07-01

    This presentation described EMRE's Fluid Coking and Flexicoking technologies that are well suited for upgrading Alberta's heavy crudes and oil sands bitumen into pipelineable crudes or synthetic crudes, which can be further processed into transportation fuels. The Fluid Coking technology uses a fluidized bed reactor that thermally converts the heavy oils into light gases, liquids and coke. The metals and much of the sulphur are concentrated in the coke. Combustion of the coke provides process heat and the remaining coke is sold or stored on site for later recovery. Syncrude Canada currently operates 3 Fluid Coking units in northern Alberta. Flexicoking extends fluid coking by integrating air gasification to produce a carbon monoxide/hydrogen rich fuel gas that helps meet fuel and energy requirements of bitumen recovery and upgrading. The yields of light gas and liquids are similar to those of the Fluid Coking process. The partial combustion of coke provides the process heat for the thermal conversion and gasification steps. The remaining coke is gasified and desulphurized using Flexsorb technology. At present, there are 5 Flexicoking units in operation around the world. Interest in the technology is growing, particularly in locations with large demand for clean fuel or electricity. It is also suitable for steam assisted gravity drainage (SAGD) operations in Alberta. This presentation outlined the operating principles of the Flexicoking integrated gasification system and compared it with more expensive oxygen gasification processes. tabs., figs.

  13. Medical surveillance of nuclear power plant workers during reactor shutdown using whole-body counting and excretion analysis

    International Nuclear Information System (INIS)

    Le Roux-Desmis, C.

    1987-01-01

    After a review of radioactivity basis and radiation protection principles, the various aspects of medical surveillance of nuclear power plant workers during reactor shutdown, are presented. Internal contamination incidents that happened during 1986-1987 shutdown of Paluel reactor are exposed. Internal contamination levels are evaluated using whole-body counting and radionuclide determination in feces and urine and compared with dose limits [fr

  14. 75 FR 20382 - Chrysler LLC, St. Louis North Assembly Plant, Including On-Site Leased Workers From HAAS TCM, Inc...

    Science.gov (United States)

    2010-04-19

    ...., Diversified Contract Service, Inc. 639, and Logistics Management Services, Inc., Fenton, MO; Amended... Logistics Management Services, Inc. worked on-site at the Chrysler LLC, Fenton, Missouri plant (Logistics... Department is amending this certification to include workers leased from Logistics Management Services, Inc...

  15. 75 FR 20384 - Chrysler LLC, St. Louis North Assembly Plant, Including On-Site Leased Workers From Haas TCM, Inc...

    Science.gov (United States)

    2010-04-19

    .... Diversified Contract Service, Inc. 639, and Logistics Management Services, Inc. Fenton, MO; Amended... Logistics Management Services, Inc. worked on-site at the Chrysler LLC, Fenton, Missouri plant (Logistics... Department is amending this certification to include workers leased from Logistics Management Services, Inc...

  16. Gasification reactivities of cokes derived from Athabasca bitumen

    Energy Technology Data Exchange (ETDEWEB)

    Furimsky, E.

    1985-10-01

    Gasification reactivities of cokes obtained from Athabasca bitumen by delayed coking and fluid coking were compared in fixed and fluidized bed systems. In both systems the C + O/sub 2/ reaction accounted for the most of converted carbon. The C + H/sub 2/O reaction proceeded to a smaller extent. The bulk reactivity of the fluid coke was higher than that of delayed coke, when comparing -20 to +60 mesh particles in fluidized bed and -14 to +20 mesh particles in fixed bed, respectively. However, the reactivity of the delayed coke expressed per unit of surface area was markedly higher than that of the fluid coke. 9 figs., 7 tabs., 6 refs. (A.V.)

  17. Analysis of industrial coke samples by activation with cyclotron protons

    International Nuclear Information System (INIS)

    Chaudhri, M.A.; Lee, M.M.; Spicer, B.M.

    1982-01-01

    A Melbourne Petrochemical Company was experiencing excessive coke formation in its ''cracking furnaces'', which was causing unnecessary stoppage of production and wastage of energy due to additional insulation. In order to investigate the possible causes of this excessive coke formation, we analyzed various coke samples and other coke-like materials obtained from these furnaces by activation with cyclotron-protons. Our results showed that, out of the two suspected coke promoters As and Sb whose small concentration in feed would produce greatly accelerated coke formation, As could not be detected in any of the eight samples investigated, while Sb was present in only one sample. However, we did observe Ca, Cr and Fe in all the samples, with surprisingly high concentrations in some of them. It has, therefore, been suggested that Ca, and perhaps Cr and Fe, but not As or Sb, could have been responsible for the excessive coke formation in the ''cracking furnaces''

  18. Fluid coking : a competitive option for heavy feed processing

    International Nuclear Information System (INIS)

    Hammond, D.G.; Feinberg, A.S.; McCaffrey, D.S.

    1997-01-01

    Fluid coking is a proven thermal conversion process for converting heavy hydrocarbon feeds to lighter products. Fluid coking was commercialized by Exxon over 40 years ago. A total of 13 units have been built with over 330 years of cumulative operating experience. Fluid coking can process many different feeds at once and is usually insensitive to feed contaminants such as sulfur, nitrogen and metals. New developments in coke utilization and flue gas desulfurization/departiculation have prompted new economic studies. Fluid coking is competitive and is the most attractive option compared to delayed coking, particularly for very heavy feed stocks such as deasphalter bottoms. Viewgraphs describe the fluid coking process, its advantages, utilization, and commercial viability. 7 tabs., 3 figs

  19. Emission characteristics and size distribution of polycyclic aromatic hydrocarbons from coke production in China

    Science.gov (United States)

    Mu, Ling; Peng, Lin; Liu, Xiaofeng; He, Qiusheng; Bai, Huiling; Yan, Yulong; Li, Yinghui

    2017-11-01

    Coking is regarded as a major source of atmospheric polycyclic aromatic hydrocarbons (PAHs), but few researches have been conducted on the emission characteristics of PAHs from coke production. In this study, emissions of size-segregated particulate matter (PM) and particle-bound PAHs emitted from charging of coal (CC) and pushing of coke (PC) in four typical coke plants were determined. The emission factors on average, sums of CC and PC, were 4.65 mg/kg, 5.96 mg/kg, 19.18 μg/kg and 20.69 μg/kg of coal charged for PM2.1 (≤ 2.1 μm), PM, PAHs in PM2.1 and total-PAHs, respectively. PM and PAHs emission from plants using stamp charging were significantly more than those using top charging. The profile of PAHs in PM with size ≤ 1.4 μm (PM1.4) emitted from CC process were similar with that from PC, however, it revealed obviously different tendency for PAHs in PM with size > 1.4 μm, indicating the different formation mechanism for coarse particles emitted from CC and PC. Size distributions of PM and PAHs indicated that they were primarily connected with PM1.4, and the contributions of PM1.4 to PM and PAHs emitted from the plants using stamp charging were higher than those using top charging. Some improved technology in air-pollution control devices should be considered in coke production in future based on the considerable impacts of PM1.4 and PAHs on human health and ambient air quality.

  20. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    Energy Technology Data Exchange (ETDEWEB)

    Kevin C. Galbreath; Donald L. Toman; Christopher J. Zygarlicke

    1999-09-01

    Petroleum coke, a byproduct of the petroleum-refining process, is an attractive primary or supplemental fuel for power production primarily because of a progressive and predictable increase in the production volumes of petroleum coke (1, 2). Petroleum coke is most commonly blended with coal in proportions suitable to meet sulfur emission compliance. Petroleum coke is generally less reactive than coal; therefore, the cofiring of petroleum coke with coal typically improves ignition, flame stability, and carbon loss relative to the combustion of petroleum coke alone. Although petroleum coke is a desirable fuel for producing relatively inexpensive electrical power, concerns about the effects of petroleum coke blending on combustion and pollution control processes exist in the coal-fired utility industry (3). The Energy & Environmental Research Center (EERC) completed a 2-year technical assessment of petroleum coke as a supplemental fuel. A survey questionnaire was sent to seven electric utility companies that are currently cofiring coal and petroleum coke in an effort to solicit specific suggestions on research needs and fuel selections. An example of the letter and survey questionnaire is presented in Appendix A. Interest was expressed by most utilities in evaluating the effects of petroleum coke blending on grindability, combustion reactivity, fouling, slagging, and fly ash emissions control. Unexpectedly, concern over corrosion was not expressed by the utilities contacted. Although all seven utilities responded to the question, only two utilities, Northern States Power Company (NSP) and Ameren, sent fuels to the EERC for evaluation. Both utilities sent subbituminous coals from the Power River Basin and petroleum shot coke samples. Petroleum shot coke is produced unintentionally during operational upsets in the petroleum refining process. This report evaluates the effects of petroleum shot coke blending on grindability, fuel reactivity, fouling/slagging, and

  1. [Seroprevalence of brucelosis in the workers of a plant of treatment of sanitary wastes].

    Science.gov (United States)

    López Hernández, Begoña; Almagro Nievas, Diego; Cabrera Castillo, María José

    2003-03-22

    The management of biosanitary (hospital) waste, while being a key issue in the prevention of public health risks, involves professional risks as well. The objective of this study was to analyze the risks of infection and their relation with the various works within a cluster of brucellosis detected in an infectious waste plant. Cross-descriptive study of the total of 24 employees at the waste plant. A survey was carried out taking into account personal as well as professional items and serological tests. Both bivariant (contingency charts and mean comparison) and multivariant (logistic regression) analyses were carried out. The seroprevalence of brucella infection was 45.93% (CI95%, 26.17-66.76). The estimated risk (OR) for processing workers was 33.72 (CI95%, 2.73-415.96). The permanence within the posts was not different among groups. Infection seroprevalence was higher than that found in endemic populations. The post of processing was found to hold a relation with the contact with Brucella sp.

  2. Lung scintigraphy evaluation in workers exposed to abrasive dusts

    International Nuclear Information System (INIS)

    Terra Filho, Mario

    1995-01-01

    The production process of abrasives use aluminium, or silicon carbide a synthetic material with a hardness only slightly less than that of a diamond. It is popularly known as carborundum since it was first manufactured as an abrasive in 1891, produced by the fusion of high grade silica and petroleum coke with sawdust. For many years silicon carbide was thought not to give rise to pulmonary lesions. Recently several researchers suggested the existence of a carborundum pneumoconiosis. The aim of this study was to evaluate the role of the pulmonary clearance of 99m Technetium chelated to diethylene-triamine penta-acetate ( 99m Tc DTPA), and 67 Gallium lung scanning in workers exposed to abrasive dusts. Thirty seven subjects, 13 smokers and 24 nonsmokers and ex smokers were studied. In 32 (86,48%) 67 Gallium lung scanning was positive including 13 (40,62%) retired workers. We conclude that non smoking workers of abrasives plants have a pulmonary alveolar epithelial permeability disturbance similar as observed in smoking workers and smoking controls. Most workers, ex-workers of these industries and in patients with carborundum pneumoconiosis there is an evidence of pulmonary inflammation measured with abnormal 67 Gallium lung scan. (author)

  3. Coronary artery atherosclerosis associated with shift work in chemical plant workers by using coronary CT angiography.

    Science.gov (United States)

    Kang, WonYang; Park, Won-Ju; Jang, Keun-Ho; Kim, Soo-Hyeon; Gwon, Do-Hyeong; Lim, Hyeong-Min; Ahn, Ji-Sung; Moon, Jai-Dong

    2016-08-01

    The aim of this study was to investigate whether shift work is related to elevated risk of coronary artery disease (CAD) by determining the coronary artery calcium (CAC) score and the presence of coronary artery stenosis by using coronary artery CT angiography (CCTA). In this study, 110 male workers participated and underwent a CCTA examination for CAC scoring, which represents coronary artery plaque, and were evaluated for luminal stenosis. All of the participants were working in the same chemical plant, of whom 70 worked day shifts and 40 worked rotating shifts. In a multivariate logistic regression analysis, including age, smoking status, alcohol consumption, regular exercise and waist circumference, shift work was associated with a 2.89-fold increase in the odds of developing coronary plaque compared with day work (OR, 2.89; 95% CI 1.07 to 7.82). The association between shift work and coronary plaque was strong after adjustment for age, low-density lipoprotein cholesterol, hypertension and diabetes mellitus (OR, 2.92; 95% CI 1.02 to 8.33). In addition, the number of years of shift work employment was associated with coronary plaque. However, no association was found between shift work and coronary artery stenosis. Shift work could induce CAD onset via the atherosclerotic process, and shift work employment duration was associated with an increased risk of atherosclerosis in male workers. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://www.bmj.com/company/products-services/rights-and-licensing/

  4. Radiation doses and cause-specific mortality among workers at a nuclear materials fabrication plant

    International Nuclear Information System (INIS)

    Checkoway, H.; Pearce, N.; Crawford-Brown, D.J.; Cragle, D.L.

    1988-01-01

    A historical cohort mortality study was conducted among 6781 white male employees from a nuclear weapons materials fabrication plant for the years 1947-1979. Exposures of greatest concern are alpha and gamma radiation emanating primarily from insoluble uranium compounds. Among monitored workers, the mean cumulative alpha radiation dose to the lung was 8.21 rem, and the mean cumulative external whole body penetrating dose from gamma radiation was 0.96 rem. Relative to US white males, the cohort experienced mortality deficits from all causes combined, cardiovascular diseases, and from most site-specific cancers. Mortality excesses of lung and brain and central nervous system cancers were seen from comparisons with national and state rates. Dose-response trends were detected for lung cancer mortality with respect to cumulative alpha and gamma radiation, with the most pronounced trend occurring for gamma radiation among workers who received greater than or equal to 5 rem of alpha radiation. These trends diminished in magnitude when a 10-year latency assumption was applied. Under a zero-year latency assumption, the rate ratio for lung cancer mortality associated with joint exposure of greater than or equal to 5 versus less than 1 rem of both types of radiation is 4.60 (95% confidence limits (CL) 0.91, 23.35), while the corresponding result, assuming a 10-year latency, is 3.05 (95% CL 0.37, 24.83). While these rate ratios, which are based on three and one death, respectively, lack statistical precision, the observed dose-response trends indicate potential carcinogenic effects to the lung of relatively low-dose radiation. There are no dose-response trends for mortality from brain and central nervous system cancers

  5. Studies in biological excretion of inhaled plutonium in the case of a few occupational workers in a fuel reprocessing plant

    International Nuclear Information System (INIS)

    Hedge, A.G.; Chandramouli, S.; Iyer, R.S.; Bhat, I.S.

    1992-01-01

    A power reactor fuel reprocessing plant is in operation at Tarapur. The various processes involved in the plant are: fuel rod cutting, dissolution in nitric acid, separation of plutonium, and handling of separated plutonium. The chemical form of plutonium could be nitrate, TBP complex, or oxide depending upon the nature of the process involved. Possible internal exposure to plant personnel occurs mainly by inhalation and occasionally through a contaminated wound. Occupational workers are regularly monitored for internal contamination by urinary excretion analysis as well as by in-vivo lung counting. This paper presents a follow-up study of plutonium elimination in four inhalation exposure cases. (author) 8 refs.; 6 figs

  6. Partial briquetting of coal charges as a means of utilizing lower-grade coal for coke making

    Energy Technology Data Exchange (ETDEWEB)

    Pieters, B.J. (Iscor Limited, Newcastle (South Africa))

    1991-08-01

    The paper describes the difficulties experienced with inferior coking coals as Iscor began using larger blast furnaces for the production of liquid iron. Research conducted at Iscor from 1977 to 1979 showed that benefits could be gained from the use of partially briquetted charges, and it was decided to install briquetting plants at the Vanderbijlpark and Newcastle Works. Details are given of the latter plant, which was supplied by a consortium consisting of Voest Alpine, Didier Engineering, and Sumitomo Metal Industries. Sumitomo also supplied information on the optimization of coke quality along the lines of their Sumicoal System. The results have been a marked improvement in coke quality, much better blast-furnace operation, and increased productivity. 11 figs., 3 tabs.

  7. Development of Work Verification System for Cooperation between MCR Operators and Field Workers in Nuclear Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Seung Min; Seong, Poong Hyun [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Lee, Hyun Chul [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2014-05-15

    In this work, as an application of digital devices to NPPs, a cooperation support system to aid communication between MCR operators and field workers in Nuclear Power Plants (NPPs), NUclear COoperation Support and MObile document System (Nu-COSMOS), is suggested. It is not easy for MCR operators to estimate whether field workers conduct their work correctly because MCR operators cannot monitor field workers at a real time, and records on paper procedure written by field workers do not contain the detailed information about work process and results. Thus, for safety operation without any events induced by misunderstand and miscommunication between MCR operators and field workers, the Nu-COSMOS is developed and it will be useful from the supporting cooperation point of view. To support the cooperation between MCR operators and field workers in NPPs, the cooperation support and mobile documentation system Nu-COSMOS is suggested in this work. To improve usability and applicability of the suggested system, the results of using existed digital device based support systems were analyzed. Through the analysis, the disincentive elements of using digital device-based developments and the recommendations for developing new mobile based system were derived. Based on derived recommendations, two sub systems, the mobile device based in-formation storing system and the large screen based information sharing system were suggested. The usability of the suggested system will be conducted by a survey with questionnaires. Field workers and operators, and nuclear-related person who had experiences as an operator, graduate students affiliated in nuclear engineering department will use and test the functions of the suggested system. It is expected that the mobile based information storing system can reduce the field workers' work load and enhance the understanding of MCR operators about field operators work process by monitoring all work results and work processes stored in devices.

  8. Development of Work Verification System for Cooperation between MCR Operators and Field Workers in Nuclear Power Plants

    International Nuclear Information System (INIS)

    Lee, Seung Min; Seong, Poong Hyun; Lee, Hyun Chul

    2014-01-01

    In this work, as an application of digital devices to NPPs, a cooperation support system to aid communication between MCR operators and field workers in Nuclear Power Plants (NPPs), NUclear COoperation Support and MObile document System (Nu-COSMOS), is suggested. It is not easy for MCR operators to estimate whether field workers conduct their work correctly because MCR operators cannot monitor field workers at a real time, and records on paper procedure written by field workers do not contain the detailed information about work process and results. Thus, for safety operation without any events induced by misunderstand and miscommunication between MCR operators and field workers, the Nu-COSMOS is developed and it will be useful from the supporting cooperation point of view. To support the cooperation between MCR operators and field workers in NPPs, the cooperation support and mobile documentation system Nu-COSMOS is suggested in this work. To improve usability and applicability of the suggested system, the results of using existed digital device based support systems were analyzed. Through the analysis, the disincentive elements of using digital device-based developments and the recommendations for developing new mobile based system were derived. Based on derived recommendations, two sub systems, the mobile device based in-formation storing system and the large screen based information sharing system were suggested. The usability of the suggested system will be conducted by a survey with questionnaires. Field workers and operators, and nuclear-related person who had experiences as an operator, graduate students affiliated in nuclear engineering department will use and test the functions of the suggested system. It is expected that the mobile based information storing system can reduce the field workers' work load and enhance the understanding of MCR operators about field operators work process by monitoring all work results and work processes stored in devices

  9. Coking coal of Checua Lenguazaque area

    International Nuclear Information System (INIS)

    Arboleda Otalora, Carlos Ariel

    1987-06-01

    In this report a summary of the main characteristics of the coal of the area of Checua-Samaca is presented. Using the main works carried out on this area, the most important geologic, physical-chemical, technological and petrographic aspects are compiled that are considered essential to carry out a technical evaluation of these coal and all the analyses they take to conclude that in this area, bituminous coal are presented with very good coking properties, on the other hand, it is demonstrated by the use that is given to the coal extracted by the small existent mining. However, keeping in mind the demands of the international market of the coking coal, it becomes necessary to improve the existent geologic information to be able to make reliable stratigraphic correlations

  10. South Bank Coke Ovens heating performance improvements

    Energy Technology Data Exchange (ETDEWEB)

    Fraser, A.J. [South Bank Coke Ovens (United Kingdom)

    1995-12-31

    The coke oven batteries at South Bank Coke Ovens had a history of refractory failure, overheating, and poor environmental performance despite repeated attempts to solve the problem. The fundamental design was poor, but previous upgrade attempts had a history of short term improvements followed by renewed decline, suggesting that the problem may not merely with the equipment. An audit of the area showed multiple morale, equipment and communications problems, although a significant proportion of the workforce were interested in improving the situation. A group of those interested in performance improvements was called together and objectives agreed upon. Communications were upgraded and problem walls analysed for their particular weaknesses. A team approach was used for maintenance, leading to slowly improving pushing emission factors. Temperature control equipment ensured better environmental performance and lower electricity consumption. 5 refs., 3 figs.

  11. New processes in iron metallurgy discussed by the Coking Section of the Scientific Council of the Main Committee of Science and Technology of the USSR

    Energy Technology Data Exchange (ETDEWEB)

    Bukvareva, O.F.

    1991-02-01

    Discusses problems evaluated in October 1990 by the Section during the meeting devoted to research programs in the twelfth five-year plan, research and development of continuous coking methods, prospects for new coke quenching processes. Selected research programs, coordinated research programs and development programs as well as recommendations for future research programs are evaluated. The following research programs aimed at use of weakly caking and noncaking coals in the coking plants are evaluated: coal preheating and charging preheated mixtures to coke ovens, partial coal charge briquetting and equipment for coal briquetting, development of commercial systems for packing coal charges in coke ovens, production of formed coke for metallurgy, processes for coal gas cleaning (especially ammonia separation), development of systems for utilization of waste heat from dry coke quenching for coal charge preheating. Participation of individual research institutes in the programs is discussed. The most significant projects of individual institutes are discussed. Recommendations for research programs for the period 1991 to 1995 are made.

  12. Estimation of annual dose equivalent (internal and external) for new thorium plant workers of IRE OSCOM, Orissa

    International Nuclear Information System (INIS)

    Vidya Sagar, D.; Tripathy, S.K.; Khan, A.H.; Maharana, L.N.

    2001-01-01

    In addition to thoron, thoron daughters and gamma radiation, the New Thorium Plant workers are exposed to long lived alpha emitters due to inhalation of thorium fine dust present in the working environment. Air samplers were used for measurement of thoron daughters and long lived alpha concentration. Each sample was counted for 3-4 hours for alpha activity and the long lived alpha concentration was calculated after taking the self absorption effect of the deposit on the filter paper into account. Internal dose of individual workers due to thoron daughter concentration and long lived alpha concentration was determined using time weighted factors. Based on the results, it is observed that contribution of thoron daughters, long lived alpha and external gamma is about 2 mSv /y, 1 mSv /y and 5 mSv/y, respectively, to total dose to the workers. (author)

  13. Historical reconstruction of polychlorinated biphenyl (PCB) exposures for workers in a capacitor manufacturing plant.

    Science.gov (United States)

    Hopf, Nancy B; Ruder, Avima M; Waters, Martha A

    2014-05-01

    We developed a semiquantitative job exposure matrix (JEM) for workers exposed to polychlorinated biphenyls (PCBs) at a capacitor manufacturing plant from 1946 to 1977. In a recently updated mortality study, mortality of prostate and stomach cancer increased with increasing levels of cumulative exposure estimated with this JEM (trend p values = 0.003 and 0.04, respectively). Capacitor manufacturing began with winding bales of foil and paper film, which were placed in a metal capacitor box (pre-assembly), and placed in a vacuum chamber for flood-filling (impregnation) with dielectric fluid (PCBs). Capacitors dripping with PCB residues were then transported to sealing stations where ports were soldered shut before degreasing, leak testing, and painting. Using a systematic approach, all 509 unique jobs identified in the work histories were rated by predetermined process- and plant-specific exposure determinants; then categorized based on the jobs' similarities (combination of exposure determinants) into 35 job exposure categories. The job exposure categories were ranked followed by a qualitative PCB exposure rating (baseline, low, medium, and high) for inhalation and dermal intensity. Category differences in other chemical exposures (solvents, etc.) prevented further combining of categories. The mean of all available PCB concentrations (1975 and 1977) for jobs within each intensity rating was regarded as a representative value for that intensity level. Inhalation (in microgram per cubic milligram) and dermal (unitless) exposures were regarded as equally important. Intensity was frequency adjusted for jobs with continuous or intermittent PCB exposures. Era-modifying factors were applied to the earlier time periods (1946-1974) because exposures were considered to have been greater than in later eras (1975-1977). Such interpolations, extrapolations, and modifying factors may introduce non-differential misclassification; however, we do believe our rigorous method

  14. Characterisation of coking activity during supercritical hydrocarbon pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Gascoin, Nicolas; Gillard, Philippe; Bernard, Stephane [Laboratoire Energetique, Explosion, Structure, UPRES-EA 1205, 63, avenue de Lattre de Tassigny, 18020 Bourges Cedex (France); Bouchez, Marc [MBDA France, 8, rue Le Brix, 18000 Bourges (France)

    2008-12-15

    The active cooling of the Supersonic Combustion Ramjet engine, for hypersonic flight purpose, is ensured thanks to fuel, n-dodecane for the present study. The endothermic fuel pyrolysis, starting above 800 K, could generate an unwanted coke formation. Experimental tests up to 1125 K and between 1 MPa and 6 MPa have been performed on the hydrocarbon fuel pyrolysis to evaluate the coking activity. 316L stainless steel, low carbon steel and titanium reactors have been considered. A witness of the coke formation, based on its thermal insulation and pressure loss effects, has been found. A correlation between methane production and coke deposit was found. The coke has been studied with Scanning Electron Microscope (SEM), Energy Dispersion Spectroscopy (EDS), X-ray diffractometer and Fourier Transform Infrared (FTIR) spectroscopy. The porosity, the density and the permeability of the coke have been estimated. (author)

  15. Clinical aspects of the health disturbances in Chernobyl Nuclear Power Plant accident clean-up workers (liquidators) from Latvia.

    Science.gov (United States)

    Eglite, M E; Zvagule, T J; Rainsford, K D; Reste, J D; Curbakova, E V; Kurjane, N N

    2009-06-01

    The health status of some 6,000 workers from Latvia who went to clean-up the Chernobyl Nuclear Power Plant (CNPP) site following the explosion on 26 April 1986 has been analyzed. The data on these workers have been recorded in the Latvian State Register of Occupational disease patients and people exposed to ionizing radiation due to Chernobyl NPP accident (Latvian State Register) that was established in 1994. From these data, estimates have been made of external ionizing radiation to which these workers were exposed together with observations on the impact of exposure to heavy metals (especially lead and zinc) and radioactive isotopes released during the reactor 'meltdown'. These factors along with psycho-emotional and social-economic stresses account for a marked excess of mortality and morbidity in the group of CNPP accident clean-up workers compared with that of the non-exposed normal Latvian population adjusted for age and sex. The number of diseases or conditions in the CNPP accident clean-up workers has progressively risen from an average of 1.3 in 1986 to 10.9 in 2007. This exceeds for the Latvian population when adjusted for age and sex. The most serious conditions affect the nervous, digestive, respiratory, cardiovascular, endocrine (especially thyroid) and immunological systems. While the morbidity associated with diseases of the respiratory and digestive systems has decreased in recent years that in the other systems is increasing. In recent years, there has been an increased occurrence of cancers affecting the thyroid, prostate and stomach. Clinical and laboratory investigations suggest that surviving CNPP accident clean-up workers exhibit signs of immuno-inflammatory reactions causing premature aging with evidence of autoimmune diseases and immunological deficiencies or abnormalities. It is suggested that the CNPP accident clean-up workers may have a specific syndrome, the 'Chernobyl post-radiation neurosomatic polypathy', due to sustained oxidant

  16. Reemployment of Displaced Workers – The Case of a Plant Closing on a Remote Region in Finland

    Directory of Open Access Journals (Sweden)

    Arja Jolkkonen

    2012-02-01

    Full Text Available The aims of this article are to examine the reemployment of displaced workers and individual factors that predict reemployment and education, earnings in new jobs, and paths to reemployment. This article is based on a case study of the closing down of the Perlos Ltd plants in North Karelia in eastern Finland. From the 1990s, the Perlos Corporation grew from a Nokia subcontractor into a globally operating limited company with a global workforce of over 13,000 workers and almost 2,000 workers in North Karelia. In 2007, the corporation closed down all its production activities in Finland. In the case study, various data sources were used but this article is based mainly on the questionnaire conducted in 2008 among 1,217 trade union members. Logistic and multinomial regression analyses are used as analysis methods. Against expectations, the fast reemployment of the displaced workers was a surprise, which can be explained by the good demand and hidden need for labor in other firms in this region. However, the demand was specific and differentiated between the workers’ job opportunities. White-collar workers had better chances of reemployment. Gender, next to the occupational status, was an important predictor for reemployment. On the other hand, education, the willingness to move, and family status were not statistically significant explanatory factors for reemployment. The age of the job seekers was one important factor predicting unemployment.

  17. Dependence of microhardness of coke on carbon content and final coking temperature

    Energy Technology Data Exchange (ETDEWEB)

    Kaloc, M.; Dvorak, P.

    1995-12-31

    At present time is important the coke-quality, tested by various methods again. The new methods of evaluation of coke quality as e.g. CSR, CRI, ACRI etc. demonstrate, that the mechanical stability parameters are in connection of microstructure of coke mass. The purpose of present paper is to investigate the dependence of microhardness on the carbon content and the final carbonisation temperature in the coal-coke series. The samples prepared experimentally in more series from different coal blends from 20{degrees}C to 1100{degrees}C were investigated both mega- and microscopically. The tests of microhardness are based on the use of the Hanemann microhardness tester. Principally this method consists in impressing the diamond pyramid into the surface of the sample. The data on the pressure applied are subtracted on the scale of load. An important factor influencing the results is the choice of the points from which the sample is to be withdrawn. The choice is dependent on the aim to be achieved. For the determination of an average microhardness it is sufficient to take sample from the middle part of the coke block representing the half width of the coking chamber. The choice of the point is also of great importance. In strong and homogeneous walls, sharply bounded, impressions can be found with a distinct diagonal cross. In thin walls the impressions are distinguished by distinct boundaries, the middle part, however, not being distinct as the pyramidal point did not penetrate the wall. Impressions providing accurate values are those distinctly bounded by a distinct diagonal cross. The walls not having been chosen correctly, the errors reveal themselves as the scattering of the points in the diagrams of microhardness.

  18. Coke breakage behaviour in relation to its structure

    Energy Technology Data Exchange (ETDEWEB)

    Peirce, T J; Horton, A E; Tucker, J

    1980-06-14

    The relationship between coke macrostructure and volumetric (coarse) breakage behaviour, and the manner in which both features are affected by the coal charge composition are discussed. Coke pieces which are extensively fissured fail spontaneously after only a few revolutions in the drum; coke pieces which are less fissured require an extended treatment in the drum and finally fail in a manner consistent with that of fatigue crack growth induced by repeated impact. This heterogeneity in breakage behaviour was demonstrated in terms of an abrupt change in gradient of the Weibull distribution function for the coke. Heterogeneity may be removed by fully stabilising the coke or by the use of a more energetic test method. The role of fatigue crack growth in coke breakage was studied by cutting fissures of defined depth in full stabilised coke and assessing the rate of crack growth as a function of fissure depth and fracture toughness. The form of the results was consistent with that given by the Paris-Erdogan law and the rate of crack growth (for a given stress intensity level) was shown to increase with reducing coke toughness. Explanations are suggested to account for the role of blend additives in modifying the fissured properties and fracture toughness of coke made from high-volatile coal.

  19. Process for the preparation of isotropic petroleum coke

    International Nuclear Information System (INIS)

    Kegler, W.H.; Huyser, M.E.

    1975-01-01

    A description is given of a process for preparing isotropic coke from oil residue charge. It includes blowing air into the residue until it reaches a softening temperature of around 49 to 116 deg C, the deferred coking of the residue having undergone blowing at a temperature of around 247 to 640 deg C, at a pressure between around 1.38x10 5 and 1.72x10 6 Pa, and the recovery of isotropic coke with a thermal expansion coefficient ratio under 1.5 approximately. The isotropic coke is used for preparing hexagonal graphite bars for nuclear reactor moderators [fr

  20. Producing hydrogen from coke-oven gas: the Solmer project. [PSA process

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, G; Vidal, J

    1984-05-01

    After presenting the energy situation at the Solmer plant, where coke-oven gas is produced to excess, the authors examine the technical and economic possibilities of utilizing this gas for hydrogen extraction. They describe a project (based on the PSA process) for producing some 65 t/d of hydrogen and present the technical features of the scheme. An evaluation of the energy and financial costs of producing the hydrogen confirms the competitive status of the process.

  1. EPA Administrative Order on Consent (AOC) with ERP Compliant Coke, LLC

    Science.gov (United States)

    This Administrative Order on Consent with ERP Compliant Coke was effective August 2016. The Walter Coke facility located in North Birmingham was purchased by ERP Compliant Coke, LLC in February 2016 out of bankruptcy proceedings.

  2. Statistical assessment of coal charge effect on metallurgical coke quality

    Directory of Open Access Journals (Sweden)

    Pavlína Pustějovská

    2016-06-01

    Full Text Available The paper studies coke quality. Blast furnace technique has been interested in iron ore charge; meanwhile coke was not studied because, in previous conditions, it seemed to be good enough. Nowadays, requirements for blast furnace coke has risen, especially, requirements for coke reactivity. The level of reactivity parameter is determined primarily by the composition and properties of coal mixtures for coking. The paper deals with a statistical analysis of the tightness and characteristics of the relationship between selected properties of coal mixture and coke reactivity. Software Statgraphic using both simple linear regression and multiple linear regressions was used for the calculations. Obtained regression equations provide a statistically significant prediction of the reactivity of coke, or its strength after reduction of CO2, and, thus, their subsequent management by change in composition and properties of coal mixture. There were determined indexes CSR/CRI for coke. Fifty – four results were acquired in the experimental parts where correlation between index CRI and coal components were studied. For linear regression the determinant was 55.0204%, between parameters CRI – Inertinit 21.5873%. For regression between CRI and coal components it was 31.03%. For multiple linear regression between CRI and 3 feedstock components determinant was 34.0691%. The final correlation has shown the decrease in final coke reactivity for higher ash, higher content of volatile combustible in coal increases the total coke reactivity and higher amount of inertinit in coal increases the reactivity. Generally, coke quality is significantly affected by coal processing, carbonization and maceral content of coal mixture.

  3. Dry purification of aspirational air in coke-sorting systems with wet slaking of coke

    Energy Technology Data Exchange (ETDEWEB)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

  4. Alteration in eating habits among shift workers of a poultry processing plant in southern Brazil.

    Science.gov (United States)

    de Freitas, Elisângela da Silva; Canuto, Raquel; Henn, Ruth Liane; Olinto, Beatriz Anselmo; Macagnan, Jamile Block Araldi; Pattussi, Marcos Pascoal; Busnello, Fernanda Michelin; Olinto, Maria Teresa Anselmo

    2015-08-01

    The relationship between shift work and the eatinghabits of workers was investigated in a slaughterhouse in southern Brazil. It involved a cross-sectional study with 1,206 workers of both sexes between 18 and 50 years of age. A standardized questionnaire was used to gather demographic, socioeconomic, work shift and eating habit information. The shift of work was categorized into daytime and nighttime, based on the starting and ending times of the shift. The eating habits of workers were evaluated as follows: number and type of meals eaten during the 24 hours of a normal day, the inappropriateness of the hoursof these meals and the dietaryrisk score. This was built on the risk score of the weekly consumption of 13 food items. After adjusting for potential confounders, non-Caucasian and younger male workers were more likely to manifest eating risk habits. Nighttimeshift workers consumed ahigher number of meals/day with greater inappropriateness of meal times than daytimeshift workers. The night shift can negatively influence the eating habits of workers of that shift.

  5. [Labor management and the health and safety of thermoelectric plant workers: a study from the viewpoint of the activity].

    Science.gov (United States)

    Guida, Hilka Flavia Saldanha; Brito, Jussara; Alvarez, Denise

    2013-11-01

    This article presents the labor management changes and the implications for occupational health and safety that occurred after two thermoelectric plants were acquired by a government-owned, joint stock with private investors, energy corporation. The changes led part of these workers to question their own professional abilities, as previously experienced workers were suddenly considered unqualified due to the new organizational model and restructuring implemented in their units. It was seen how lack of professional recognition in the workplace led to negative health and safety consequences for workers, as there were numerous cases of psychic anguish, emotional disorders, musculoskeletal problems, gastrointestinal disorders, etc. It was also seen that it is now possible to introduce a series of measures that can contribute to improve working conditions and, consequently, the lives of the workers. The benchmark used was Ergology, as well as aspects of the Psychodynamics of Work and the Ergonomics of the Activity. The methodology included a bibliographical survey of the theme, document analysis, semi-structured interviews, systematic activities observations and the validation of results with the research subjects.

  6. Investigations on Health Conditions of Chernobyl Nuclear Power Plant Accident Recovery Workers from Latvia in Late Period after Disaster

    Directory of Open Access Journals (Sweden)

    Reste Jeļena

    2016-10-01

    Full Text Available The paper summarises the main findings on Chernobyl Nuclear Power Plant (CNPP accident recovery workers from Latvia and their health disturbances, which have been studied by the authors during the last two decades. Approximately 6000 persons from Latvia participated in CNPP clean-up works in 1986–1991. During their work period in Chernobyl they were exposed to external as well as to internal irradiation, but since their return to Latvia they were living in a relatively uncontaminated area. Regular careful medical examinations and clinical studies of CNPP clean-up workers have been conducted during the 25 years after disaster, gathering knowledge on radiation late effects. The aim of the present review is to summarise the most important information about Latvian CNPP clean-up worker health revealed by thorough follow-up and research conducted in the period of 25 years after the accident. This paper reviews data of the Latvian State Register of Persons Exposed to Radiation due to CNPP Accident and gives insight in main health effects found by the researchers from the Centre of Occupational and Radiological Medicine (Pauls Stradiņš Clinical University Hospital and Rīga Stradiņš University in a number of epidemiological, clinical, biochemical, immunological, and physiological studies. Latvian research data on health condition of CNPP clean-up workers in the late period after disaster indicate that ionising radiation might cause premature ageing and severe polymorbidity in humans.

  7. Fluid coking of heavy hydrocarbons and apparatus therefor

    Energy Technology Data Exchange (ETDEWEB)

    1956-07-11

    A process for the conversion of hydrocarbon oils comprises injecting a plurality of streams of oil into an enlarged coking vessel containing a mass of finely divided solids, thereby, preventing agglutination of the solids, circulating the solids through an external heating zone and back to the coking vessel to maintain the vessel at a coking temperature between 850 and 1,200/sup 0/F, passing gaseous material upwardly through the coking vessel at a superficial velocity of between 0.1 and 5.0 feet per second, controlled to maintain the body of solids in a dense turbulent fluidized state, maintaining the oil within coking the vessel for a period sufficient to convert into vapors and coke, withdrawing vapors from the top of the vessel through an outlet, separating high-boiling ends from vapors, returning at least a portion of the high-boiling ends to the coking vessel for further cracking and withdrawing excess of coke formed in the process.

  8. Coke degradation by surface breakage in a modified tumble drum

    Energy Technology Data Exchange (ETDEWEB)

    Litster, J D

    1987-01-01

    The surface breakage rate constant for three Australian battery cokes was measured in a specially modified tumble drum using a previously developed technique. The effect of experimental test parameters - coke size, sample mass, drum speed, lifter height and lifter number - on the surface breakage rate constant was examined. The motion of coke particles within a tumble drum was filmed in a simulation experiment with a 0.31 m diameter drum. Particles were raised on the lifters, fell and collided with the bottom of the drum. These collisions were the main source of fines (minus 1 mm) production rather than true abrasion as depicted by a rubbing, rolling action. Hence the term 'surface breakage' is more appropriate than 'abrasion' to describe the breakage process. By measuring the volume of coke carried by each lifter and the height of fall of the coke, the effect of drum speed, sample mass, lifter height and number on the rate of surface breakage was successfully explained. The surface breakage rate constant was found to be proportional to particle size to the power 0.33 for the three cokes studied. A normalized surface breakage rate constant was derived which allowed comparison of cokes with different size distributions. This parameter characterises the coke surface breakage resistance.

  9. Combustion kinetics of the coke on deactivated dehydrogenation catalysts

    NARCIS (Netherlands)

    Luo, Sha; He, Songbo; Li, XianRu; Li, Jingqiu; Bi, Wenjun; Sun, Chenglin

    2015-01-01

    The coke combustion kinetics on the deactivated catalysts for long chain paraffin dehydrogenation was studied by the thermogravimetry and differential thermogravimetry (TG–DTG) technique. The amount and H/C mole ratio of the coke were determined by the TG and elemental analysis. And the

  10. Study on the Inference Factors of Huangling Coking Coal Pyrolysis

    Science.gov (United States)

    Du, Meili; Yang, Zongyi; Fan, Jinwen

    2018-01-01

    In order to reasonably and efficiently utilize Huangling coking coal resource, coal particle, heating rate, holding time, pyrolysis temperature and others factors were dicussed for the influence of those factor on Huangling coking coal pyrolysis products. Several kinds of coal blending for coking experiments were carried out with different kinds of coal such as Huangling coking coal, Xida coal with high ash low sufur, Xinghuo fat coal with hign sulfur, Zhongxingyi coking coal with high sulfur, Hucun lean coal, mixed meager and lean coal. The results shown that the optimal coal particle size distribution was 0.5~1.5mm, the optimal heating rate was 8°C/min, the optimal holding time was 15min, the optimal pyrolysis temperature was 800°C for Huangling coking coal pyrolysis, the tar yield increased from 4.7% to 11.2%. The maximum tar yield of coal blending for coking under the best single factor experiment condition was 10.65% when the proportio of Huangling coking coal was 52%.

  11. Coke formation on hydrodesulphurization catalysts. [Including effects of different promoters

    Energy Technology Data Exchange (ETDEWEB)

    Ternan, M.; Furimsky, E.; Parsons, B.I.

    1979-02-01

    The extent of coke formation was measured on a number of different hydrodesulfurization catalysts, primarily as a function of the catalyst chemical composition. Variations in the concentration of MoO/sub 3/ on the alumina, the type of catalyst promoter, the promoter/MoO/sub 3/ ratio, the presulfiding material and the reaction temperature were made. Increases in the reaction rate caused by either changes in the catalyst composition or by moderate changes in the reaction temperature were compared to the catalyst coke content. It was suggested that two types of coke were present on the catalyst, a reactive coke which is subsequently converted to reaction products and an unreactive coke which blocks catalytic sites.

  12. Reducibility mill scale industrial waste via coke breeze at 850-950ºC

    Directory of Open Access Journals (Sweden)

    Gaballah N.M.

    2015-01-01

    Full Text Available Mill scale is a very attractive industrial waste due to its elevated iron content (about = 69.33% Fe besides being suiTab. for direct recycling to the blast furnace via sintering plant. In this paper the characteristics of raw materials and the briquettes produced from this mill scale were studied by different methods of analyses. The produced briquettes were reduced with different amounts of coke breeze at varying temperatures, and the reduction kinetics was determined. The activation energy of this reaction ≈ 61.5 kJ/mole for reduction of mill scale with coke breeze in the form of briquettes with 2% molasses where the chemical reaction interface model is applicable.

  13. [Factors influencing electrocardiogram results in workers exposed to noise in steel-making and steel-rolling workshops of an iron and steel plant].

    Science.gov (United States)

    Li, Y H; Yu, S F; Gu, G Z; Chen, G S; Zhou, W H; Wu, H; Jiao, J

    2016-02-20

    To investigate the factors influencing the electrocardiogram results in the workers exposed to noise in steel-making and steel rolling workshops of an iron and steel plant. From September to December, 2013, cluster sampling was used to select 3 150 workers exposed to noise in the steel-making and steel-rolling workshops of an iron and steel plant, and a questionnaire survey and physical examinations were performed. The number of valid workers was 2 915, consisting of 1 606 workers in the steel-rolling workshop and 1 309 in the steel-making workshop. The electrocardiogram results of the workers in steel-making and steel-rolling workshops were analyzed. The overall abnormal rate of electrocardiogram was 26.35%, and the workers in the steel-making workshop had a significantly higher abnormal rate of electrocardiogram than those in the steel-rolling workshop(32.24% vs 21.54%, Pelectrocardiogram than female workers(27.59% vs 18.61%, Pelectrocardiogram than those who did not drink(28.17% vs 23.75%, Pelectrocardiogram than those who were not exposed to high temperature(29.43% vs 20.14%, Pelectrocardiogram in the workers with cumulative noise exposure levels of electrocardiogram results. High cumulative noise exposure, alcohol consumption, and high temperature may affect the abnormal rate of electrocardiogram in the workers exposed to noise in steel-making and steel-rolling workshops.

  14. Mortality of workers at the Chapelcross plant of British Nuclear Fuels

    International Nuclear Information System (INIS)

    Binks, K.; Thomas, D.I.; McElvenny, D.

    1989-01-01

    Standardised Mortality Ratio (SMR) and trend analysis results are reported for those 1796 Chapelcross worker first employed before 1 January 1976 with follow up to the end of 1983. 221 workers were found to have died, 42 (19%) of them from cancer. None of the SMRs are significantly greater than 100, but trends in mortality with increasing whole body exposure are of borderline significance for two disease groupings; malignant neoplasm of the lung and non malignant respiratory diseases. (author)

  15. A new method for manufacturing ICEM form coke and its coking in slanted furnaces. Part II. Obtaining ICEM form coke in slanted furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Barbu, I; Coposescu, V; Kost, J; Manolescu, A; Michailidis, N; Solceriu, R; Stoicoi, A

    1978-01-01

    An engineering scheme of the process is given, together with the characteristics of the chamber furnaces with an inclined hearth and the quality of the coke obtained in the industrial assembly at a gas factory. The assembly consists of 56 chamber furnaces with a volume up to 10 cubic meters. The height of the chambers is 4000 mm on one side and 4295 mm on the other with a length of 7500 mm and a width of 360-480 mm. The heating temperature is 1200/sup 0/, and the coking time is 22-24 hours. The annual production of the batteries for metallurgical coke is 90 thousand tons, and the average strength of the coke is M40-66.0; M10-15.51.

  16. Furnace coking simulations in a laboratory apparatus

    Energy Technology Data Exchange (ETDEWEB)

    Eaton, Paul [Champion Technologies Inc (United States)], email: paul.eaton@champ-tech.com; Newman, Bruce [ConocoPhillips (United States)], email: Bruce.A.Newman@conocophillips.com; Gray, Murray; Kubis, Alan; Derakhshesh, Marzie; Holt, Chris; Mitlin, David [Department of Chemical and Materials Engineering, University of Alberta (Canada)

    2010-07-01

    This work deals with simulating fouling behavior of crude oil in a delayed coker furnace. Fouling on different heated metal probes was investigated; these were mainly stainless steel, iron, or mild steel probes. Heat transfer theory was used to calculate the system fouling factor, and this parameter was recorded as a function of time to model in-situ fouling intensity. Physical and chemical properties such as buildup thickness and composition were investigated using different measuring techniques, most important of which were extractive-iron-nickel ion chromatography, optical and scanning electron microscopy (SEM), and electron dispersion spectroscopy (EDS). Changes in surface layers of the metallic probe during coke formation along with microstructures of the coke were examined using a focused-ion beam (FIB). It was shown that the iron probe exhibited more buildups on its surface than stainless steels, and fouling of mild steel came in between. As for oils with different concentrations, fouling of diluted atmospheric tower bottom (ATB) was greater than that of undiluted ATP.

  17. Microbiological air pollution of production room of the meat processing plant as a potential threat to the workers

    Directory of Open Access Journals (Sweden)

    Barbara Breza-Boruta

    2015-12-01

    Full Text Available Introduction. Production rooms of the meat plants are the specific environment that require constant monitoring of microbiological air purity. Bioaerosols pose a threat to the safety of produced food and a considerable risk to health of exposed workers. The aim of this study was to estimate the air microbiological pollution in production rooms of the meat processing plant and exposure of the workers to biological aerosol. Material and methods. Air samples were collected at 3 stands in production rooms during winter, with the compaction method using the impactor MAS-100. The total number of bacteria and moulds, Staphylococci and bacteria of the family Enterobacteriaceae were determined in the studied bioaerosol. The concentration of microorganisms was presented in the form of colony forming units in 1m3 of air. Results. The highest concentration of mesophylic bacteria was found at stand 1 – at the freezing tunnel; whereas the highest contamination with staphylococci and fungal aerosol was found in the room where several workers were employed at packing frozen food. Among determined fungi predominated moulds of the genera: Penicillium, Alternaria and Cladosporium. Also species of potentially pathogenic fungi which produce toxins and have allergizing properties were detected in the studied bioaerosol. Bacteria of the family Enterobacteriaceae, which also may cause many infavourable health effects in exposed people, occurred at all stands. Conclusion. The concentration level and microbial composition in the inhaled air make valuable information for determination of occupational risk and a potential threat to workers of their workstations. Potentially pathogenic microorganisms present in the studied air (staphylococci, bacteria of the family Enterobacteriaceae and some moulds according to the Directive 2000/54/EC l belong to the 2nd group of risk and threat of harmful biological agents. Identification of biological threats makes it easier for the

  18. Non-cancer mortality in poultry slaughtering/processing plant workers belonging to a union pension fund.

    Science.gov (United States)

    Johnson, Eric S; Ndetan, Harrison

    2011-02-01

    The role of the biological environment in the occurrence of many chronic human diseases has been little studied. Humans are commonly exposed to transmissible agents that infect and cause a wide variety of subacute and chronic diseases in chickens and turkeys. The objective of this study is to investigate whether these agents cause similar diseases in humans, by studying workers in poultry slaughtering and processing plants who have one of the highest human exposures to these agents. Mortality in poultry workers was compared with that in the United States general population through the estimation of standardized mortality ratios. Excess mortality from infectious and parasitic diseases was observed in the poultry workers. In addition, excess occurrences of deaths involving several sites of the cardiovascular, neurological, endocrine, gastrointestinal and reproductive systems, were observed, although the numbers involved were few in some instances. The results indicate that poultry workers are at increased risk of dying from certain causes of death, including infections. This is consistent with other reports. Although it is possible that occupational exposure to transmissible agents present in poultry may be one of the causes of the excess occurrence of some of these diseases, other factors that were not considered because of the nature of the study design, could be equally important. Also, the small number of deaths involved in some instances calls for caution in interpreting the results. However, the study is important, as it has succeeded in newly identified areas that need further research, and which may have implications not only for workers, but also for the general population. Copyright © 2010 Elsevier Ltd. All rights reserved.

  19. An unusual case of organophosphate intoxication of a worker in a plastic bottle recycling plant: an important reminder.

    OpenAIRE

    Wang, C L; Chuang, H Y; Chang, C Y; Liu, S T; Wu, M T; Ho, C K

    2000-01-01

    A young man was sent to our emergency unit because he had suffered from vomiting and cold sweating for 2 days. At the time he was admitted, he had no acute abdominal pains or gastrointestinal symptoms, and a physical examination revealed nothing but a faster heart rate and moist, flushing skin. The patient had worked for 6 years at a plastic bottle-recycling factory, but none of his co-workers had the same symptoms. Nevertheless, because the plant also recycled pesticide bottles, we suspected...

  20. Adsorption of organic pollutants from coking and papermaking wastewaters by bottom ash.

    Science.gov (United States)

    Sun, Wei-ling; Qu, Yan-zhi; Yu, Qing; Ni, Jin-ren

    2008-06-15

    Bottom ash, a power plant waste, was used to remove the organic pollutants in coking wastewater and papermaking wastewater. Particular attention was paid on the effect of bottom ash particle size and dosage on the removal of chemical oxygen demand (COD). UV-vis spectra, fluorescence excitation-emission matrix (FEEM) spectra, Fourier transform infrared (FTIR) spectra, and scanning electron microscopic (SEM) photographs were investigated to characterize the wastewaters and bottom ash. The results show that the COD removal efficiencies increase with decreasing particle sizes of bottom ash, and the COD removal efficiency for coking wastewater is much higher than that for papermaking wastewater due to its high percentage of particle organic carbon (POC). Different trends of COD removal efficiency with bottom ash dosage are also observed for coking and papermaking wastewaters because of their various POC concentrations. Significant variations are observed in the FEEM spectra of wastewaters after treatment by bottom ash. New excitation-emission peaks are found in FEEM spectra, and the fluorescence intensities of the peaks decrease. A new transmittance band in the region of 1400-1420 cm(-1) is observed in FTIR spectra of bottom ash after adsorption. The SEM photographs reveal that the surface of bottom ash particles varies evidently after adsorption.

  1. Adsorption of organic pollutants from coking and papermaking wastewaters by bottom ash

    International Nuclear Information System (INIS)

    Sun Weiling; Qu Yanzhi; Yu Qing; Ni Jinren

    2008-01-01

    Bottom ash, a power plant waste, was used to remove the organic pollutants in coking wastewater and papermaking wastewater. Particular attention was paid on the effect of bottom ash particle size and dosage on the removal of chemical oxygen demand (COD). UV-vis spectra, fluorescence excitation-emission matrix (FEEM) spectra, Fourier transform infrared (FTIR) spectra, and scanning electron microscopic (SEM) photographs were investigated to characterize the wastewaters and bottom ash. The results show that the COD removal efficiencies increase with decreasing particle sizes of bottom ash, and the COD removal efficiency for coking wastewater is much higher than that for papermaking wastewater due to its high percentage of particle organic carbon (POC). Different trends of COD removal efficiency with bottom ash dosage are also observed for coking and papermaking wastewaters because of their various POC concentrations. Significant variations are observed in the FEEM spectra of wastewaters after treatment by bottom ash. New excitation-emission peaks are found in FEEM spectra, and the fluorescence intensities of the peaks decrease. A new transmittance band in the region of 1400-1420 cm -1 is observed in FTIR spectra of bottom ash after adsorption. The SEM photographs reveal that the surface of bottom ash particles varies evidently after adsorption

  2. A HEALTH SURVEY OF WORKERS IN THE PENTACHLOROPHENOL SECTION OF A CHEMICAL MANUFACTURING PLANT

    NARCIS (Netherlands)

    CHENG, WN; COENRAADS, PJ; HAO, ZH; LIU, GF

    During 1968 to 1985, 109 workers who had been engaged in the production of pentachlorophenol, using non-gamma isomers of hexachloroclohexane (BHC) as the raw material, were surveyed. Endemic chloracne among them had been noted since 1974. The prevalence of chloracne was 73.4% (80/109) in total and

  3. Surface structure and oxidation reactivity of oil sand coke particles

    Energy Technology Data Exchange (ETDEWEB)

    Fairbridge, C.; Palmer, A.D.; Ng, S.H.; Furimsky, E.

    1987-05-01

    Fractions of particles of varying mean diameter were isolated from coke obtained from the fluid coking of Athabasca bitumen. Correlations were established between the rate of oxygen sorption and the apparent surface area as measured by carbon dioxide adsorption. The rate of oxygen sorption, r/sub o/, could be related to particle radius, R, by r/sub o/ varying with R/sup D/ T over a range of particle size where D is the fractal dimension of the coke. The existence of such correlations may be related to the iterative processes which form the particles. 14 refs., 5 figs., 2 tabs.

  4. Probabilistic reconstruction of internal exposure for nuclear power plant workers using air concentration measurements

    International Nuclear Information System (INIS)

    Linkov, I.; Burmistrov, D.

    2000-01-01

    Air surveys, whole-body counting, bioassays or combination of these measurements can be utilized for purposes or assessing internal doses to determine compliance with occupational dose equivalent limits. Air sampling with a little support provided by whole body counting and/or bioassays was often relied on in dose calculations. The utility of air sampling for internal dose reconstruction is addressed in this paper through the probabilistic analysis of environmental factors and their impact on dose estimates. In this paper we attempt to reconstruct an internal dose due to inhalation of beta + gamma emitting radionuclides for a contractual electrician, Mr. X. The data available for reconstruction of internal dose for Mr. X was found to be highly variable and uncertain. Uncertainty describes a lack of knowledge about a parameter, this lack of knowledge theoretically can be reduced, e.g., if more measurements were to be taken (for example, estimated activities for alpha-emitting radionuclides are uncertain due to the influence of naturally-occurring alpha-emitters). Variability describes the existence of different values that represent different environmental conditions (for example, the air concentrations of radionuclides may vary over time because of the different tasks performed by workers in the area). Variability can not be reduced by additional data collection because the varying values reflect the variable nature of the environment, not a lack of data. The high variability in measured air concentrations in the restricted areas of a LWR nuclear power plant where he worked do not allow adequate reconstruction of his individual internal dose using deterministic methods and therefore probabilistic methods are desirable. The guidance for probabilistic assessment developed by the United States Environmental Protection Agency as well as recommendations of the National Council of Radiation Protection provide an adequate framework for probabilistic reconstruction of

  5. Numerical analysis of macro-crack formation behavior within the lump coke; Cokes sonai kiretsu shinten kiko no kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, H; Sato, H; Miura, T [Tohoku University, Sendai (Japan). Faculty of Engineering

    1995-03-15

    The thermal stress analysis within lump coke was studied in order to investigate macro-crack formation and deformation behavior which strongly influence heat and mass transfer in a coke oven chamber. The dilatation of plastic layer, heating rate dependence of thermophysical and mechanical properties of coal/coke, creep in the plastic and semi-coke layers, macro-crack propagation and radiative heat transfer within the macro-crack were considered in an analytical model. The macro-crack propagation was determined from the estimated crack tip stress intensity factor, K{sub I}, at the macro-crack tip compared with the plane strain fracture toughness, K{sub IC}, through the unsteady-state calculation. Calculated results on crack formation and deformation behavior of lump coke were in good agreement with experimental observations in a laboratory-scale oven chamber. The analytical model could predict micro-crack formation within the lump coke normal to the heated wall and the coke surface close to the heated wall. 12 refs., 13 figs.

  6. Effects of heat treatments of coal on coke destruction under blast furnace conditions

    Energy Technology Data Exchange (ETDEWEB)

    Shkoller, M.B.; Dinel' t, V.M.; Korchuganova, G.S.; Petrov, V.B.

    1983-09-01

    This paper discusses results of investigations on effects of chemical reactions in a blast furnace on coke disintegration and destruction. The investigations were carried out by the VUKhIN Institute branch in Kuznetsk. Effects of silicates and carbonates of sodium, potassium and zinc on mechanical coke properties were investigated under laboratory conditions. Coke samples were placed in a reactor and were treated by vapors of metal compounds. Coke produced from a coal mixture with conventional moisture content and from preheated coal mixture was used. Coal properties are given in a table. Design of laboratory equipment used for tests is shown in 2 schemes. Heat treatments influenced coke porosity and its structural strength. Proportion of large pores accessible to sodium and potassium in coke from preheated coal was 4.5 times lower than in coke from a conventional mixture. Adsorption of sodium and potassium on coke from preheated charge was lower (from 0.22% to 0.24%) than on coke from a conventional mixture (from 2.5% to 2.9%). Adsorption of alkali metals on coke reduced its structural strength and increased coke oxidation rate by carbon dioxide. Use of heat treatments of coal for coking reduced adsorption of alkali metals on coke in a blast furnace, increased coke structural strength and reduced coke oxidation rate by carbon dioxide. (16 refs.) (In Russian)

  7. Scientific research in the area of coking and coking by-products (based on material from the All-Union Coordinating Conference)

    Energy Technology Data Exchange (ETDEWEB)

    Rydkevich, M.I.; Tselik, M.P.; Belkina, T.V.

    1985-06-01

    Subjects covered in the all-union coordinating conference on coking and chemical by-products of coking, which took place on 13-15 July 1984, are discussed. One hundred forty eight on-going and new research themes accepted as research projects for 1985-86 were discussed. Areas of research include coals from the eastern deposits and Pechora basin as raw materials for coking; coals from the southern deposits as coking raw materials; technology of coal preparation for coking; technology for producing blast furnace coke and methods of assessing its quality; technology for producing other kinds of coke and carbon graphite materials; methods for extraction processing and producing chemical products from coking.

  8. Radiation dose to construction workers at operating nuclear power plant sites. Volume 2. Appendices A--F. Final report, September 1975--September 1978

    International Nuclear Information System (INIS)

    Endres, G.W.R.; Shipler, D.B.

    1978-12-01

    These appendices contain the dosimetry procedures and details of the personnel and environmental dosimeters used for the Radiation Dose to Construction Workers at Operating Nuclear Power Plant Sites Study. A printout of the computer codes used to analyze dosimeter data is included along with all the raw data obtained. Appendices C through F contain computer output and log-normal plots of dosimetry data for environmental location and construction worker groups

  9. In-vitro monitoring of occupational workers from Technology Demonstration Plant, Mumbai

    International Nuclear Information System (INIS)

    Jha, Kundan Kumar; Prabhu, Supreetha P.; Sawant, Pramilla D.; Rao, D.D.

    2014-01-01

    The present paper reports the baseline monitoring data of these workers for U(nat.) using solid extraction chromatography technique. 232 U Working standard of 21.6 mBq/ml was prepared by diluting NPL standard (103.5± 1.0 Bq/g,) with 3M HNO 3 . 1 g UTEVA resin of 100-150 μm particle size was used for separation of U from urine. The urinary excretion rate observed for the individual in the present study can be treated as the existing level of U in urine for TDP workers. The values observed need to be subtracted from subsequent results obtained during future routine monitoring programmes in the facility to identify potential intakes, if any, before assignment of internal dose

  10. Baking and coking properties of hard coal under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Beyer, H.D.

    1981-09-01

    For a better assessment of the baking and coking properties of hard coal under high pressure as in modern coal beneficiation processes, the determination of the swelling index and the dilatation curve are investigated.

  11. KCBX Petroleum Coke Storage Pile Sampling Logbook and Photos

    Science.gov (United States)

    This documentation of KCBX's petcoke sampling locations and methods demonstrates adherence to the pet coke sampling plan previously submitted and approved by EPA, at both North Terminal and South Terminal stockpiles.

  12. Coke briquets for metallurgy based on a thermoreactive binder

    Energy Technology Data Exchange (ETDEWEB)

    Tjutjunnikov, J.B.; Florinskij, V.N.; Orechov, V.N.; Nefedov, P.J.; Sasmurin, V.I.; Kirenskij, V.N. (Khar' kovskii Inzhenerno-Ehkonomicheskii Institut (USSR))

    1992-02-01

    Describes a process for production of briquets for metallurgy with binder and coke fines or anthracite. The suggested binder is waste phenol resin from the production of phenol (cumene method). Resin properties are given. Possible reaction mechanisms yielding solidified matter are discussed. The production process requires 10-15% binder and applies charge heating up to 200 C over 30 min. Catalytic amounts of sodium hydroxide or sulfuric acid were also employed. The production process is shown in a flowsheet. Properties of produced briquets are tabulated. The briquets were used in a 8 t/h cupola furnace and their performance was compared to that of KL-1 coke. Performance was found to be comparable; the cost of coke briquets was less than that of heating coke. 2 refs.

  13. Prediction of coking dynamics for wet coal charge

    Directory of Open Access Journals (Sweden)

    Kardaś Dariusz

    2015-09-01

    Full Text Available A one-dimensional transient mathematical model describing thermal and flow phenomena during coal coking in an oven chamber was studied in the paper. It also accounts for heat conduction in the ceramic oven wall when assuming a constant temperature at the heating channel side. The model was solved numerically using partly implicit methods for gas flow and heat transfer problems. The histories of temperature, gas evolution and internal pressure were presented and analysed. The theoretical predictions of temperature change in the centre plane of the coke oven were compared with industrialscale measurements. Both, the experimental data and obtained numerical results show that moisture content determines the coking process dynamics, lagging the temperature increase above the water steam evaporation temperature and in consequence the total coking time. The phenomenon of internal pressure generation in the context of overlapping effects of simultaneously occurring coal transitions - devolatilisation and coal permeability decrease under plastic stage - was also discussed.

  14. Variation in mineral composition of coal during enrichment and coking

    Energy Technology Data Exchange (ETDEWEB)

    M.L. Ulanovskii; A.N. Likhenko [Ukrkoks Coke Producers' Association, Dnepropetrovsk (Ukraine)

    2009-06-15

    The parameters I{sub b} and B{sub b} used in developing an optimal coking-batch composition are determined from data on the chemical composition of the ash in Donetsk Basin and other coal. It is found that, when the ash content is reduced in deeper enrichment of coal with an increased content of fine pyrite, there will be accompanying increase in the Fe{sub 2}O{sub 3} content and decrease in the SiO{sub 2} content of the ash in lighter fractions. This increases I{sub b}. In other words, reducing the ash content of the coal is an unpromising means of increasing CRI and CSR of the coke produced. Three ash-containing elements (silicon, aluminum, and iron) are experimentally proven to transfer from coal to coke. Specific behavior of calcium, magnesium, alkali metals, and sulfur during coking.

  15. Crystallinity and shape of crushed calcined coke particles

    International Nuclear Information System (INIS)

    Fecioru, M.; Petrescu, M.; Georgeoni, P.

    1993-01-01

    The particle eccentricity is a very important property of the petroleum coke in determining the anisotropy of the properties of the final graphite and it affects the manner in which its properties change in the specific applications. (orig.)

  16. Crystallinity and shape of crushed calcined coke particles

    Energy Technology Data Exchange (ETDEWEB)

    Fecioru, M. (DACIA Synthetic Diamonds Factory, Bucharest (Romania)); Petrescu, M. (DACIA Synthetic Diamonds Factory, Bucharest (Romania) Polytechnic Inst., Bucharest (Romania)); Georgeoni, P. (DACIA Synthetic Diamonds Factory, Bucharest (Romania))

    1993-11-01

    The particle eccentricity is a very important property of the petroleum coke in determining the anisotropy of the properties of the final graphite and it affects the manner in which its properties change in the specific applications. (orig.).

  17. Evidence of organizational injustice in poultry processing plants: Possible effects on occupational health and safety among Latino workers in North Carolina.

    Science.gov (United States)

    Marín, Antonio J; Grzywacz, Joseph G; Arcury, Thomas A; Carrillo, Lourdes; Coates, Michael L; Quandt, Sara A

    2009-01-01

    Over 250,000 workers are employed in poultry processing, one of the most dangerous industries in the US. These jobs are increasingly held by immigrant workers who are frequently undocumented, lack knowledge of workers' rights to workplace safety, and who are reluctant to pursue their rights. This situation creates the potential for organizational injustice, made visible through abusive supervisory practices, and leads to situations in which occupational illnesses and injuries are likely to occur. This paper draws on data collected during the research phases of a community-based participatory research and social justice project. Two hundred survey interviews and 26 in-depth interviews were collected in representative, community-based samples in western North Carolina. Analyses describe associations between one aspect of organizational injustice, abusive supervision, and worker injuries. Workers' reports of abusive supervision are associated with a variety of specific and summary health indicators. The associations are stronger for women than for men. These suggest that the use of relative power within the plant may be the basis for injuries and illnesses. Three types of power relations are described that form the basis for these abusive interactions in the plant: ethnicity (American vs. Latino), immigration status ("good papers" vs. undocumented), and rank (supervisor vs. worker). Two factors modify these relations: kinship (preferences and privileges for family members) and gender. Among Latino immigrants working in poultry plants, power differences reflecting organizational injustice in the form of abusive supervision may promote occupational illnesses and injuries, particularly for women. (c) 2008 Wiley-Liss, Inc.

  18. New formulae for the manufacture of formed coke of the ICEM type and carbonization of this type of coke in oblique ovens

    Energy Technology Data Exchange (ETDEWEB)

    Barbu, I.; Georgescu, I.

    1978-01-01

    This paper presents the industrial experiences between 1971 and 1976 which led to the elaboration of new formulae for the manufacture of ICEM type coke briquettes, plus the results of coking the latter in a vertical oven. The possibility of using this type of coke in the chemical industry and in metallurgy instead of ordinary coke was simultaneously examined but this proved unsuccessful. Gives a detailed report of all the tests carried out by the State undertaking, Victoria-Galan.

  19. Demand outlook for sulfur and high-sulfur petroleum coke

    Energy Technology Data Exchange (ETDEWEB)

    Koshkarov, V.Ya.; Danil' yan, P.G.; Feotov, V.E.; Gimaev, R.N.; Koshkarova, M.E.; Sadykova, S.R.; Vodovichenko, N.S.

    1980-01-01

    The feasibility of using sulfur and high-sulfur petroleum coke fines in pyrometallurgical processes and also in the chemical and coal-tar chemical industry is examined. Results of industrial tests on briquetting fines of petroleum coke with a petroleum binder are presented. The feasibility of using the obtained briquets in shaft furnace smelting of oxidized nickel ores, production of anode stock, and also in the chemical industry are demonstrated.

  20. Emission of Polychlorinated Dibenzo-p-Dioxins (PCDDs and Polychlorinated Dibenzofurans (PCDFs from Underfiring System of Coke Oven Battery

    Directory of Open Access Journals (Sweden)

    Rafał Bigda

    2017-11-01

    Full Text Available A coke oven battery is not considered as a significant source of PCDDs/PCDFs emissions; however, due to small amounts of chlorine in coal dioxins, dibenzofurans may be formed. The paper presents the attempts to determine the level of emission of PCDDs/PCDFs from the COB underfiring system and to confront the obtained results with the calculations based on the mass balance of chlorine in the coking process and reactions of both chlorophenols formation and PCDDs and PCDFs formation from mono- and polychlorophenols. There were PCDDs/PCDFs concentrations measured in flue gases from the underfiring system of two COBs at a Polish coking plant. The measurements included both an old and a new battery. The obtained concentrations of PCDDs/PCDFs were lower than reported in the literature (0.5-1.7 ng I-TEQ/tcoke, while the results for old COB were on average 3 times higher than for the new one. It was found that PCDD/F emission from COB underfiring system is insignificant and that PCDDs/PCDFs formation during coal coking should consider the mechanisms of their formation from mono- and polychlorophenols, as well as the influence of process parameters on the synthesis.

  1. Risk perception of workers at nuclear power plants from Angra dos Reis, Rio de Janeiro State: preliminary study of a reality on health

    International Nuclear Information System (INIS)

    Scliar, Claudio; Vasconcelos, Ana S.F.; Rodrigues, Anacely S.; Santos, Gloria R.R.; Albuquerque, Patricia O.; Carvalho, Sirlene L.A.; Oliveira, Simone

    1999-01-01

    The present paper analyses some social and occupational parameters that may have an influence on the risk perception levels of the workers in Brazilian Nuclear Power pLants, emphasizing possible relationship between the specificity of job tasks/literacy and risk perception. This study was based on two findings from the scientific literature: risk perception increases proportionally with literacy; risk perception decreases proportionally with the specificity of job tasks. The results of this pilot study indicates that risk perception levels of the workers in Brazilian Nuclear Power Plants increases proportionally with the literacy and specificity of their job tasks, contrasting with the american and european profiles. These results appears as a singular reality of those workers and the possibility of a new regard over the management and decision making process in the Brazilian Nuclear Power Plants. (author)

  2. Impact of the Tokai reprocessing plant on the workers and on the surrounding environment

    International Nuclear Information System (INIS)

    Tago, I.

    1996-01-01

    The Tokai reprocessing plant began operation in September 1977 to establish oxide fuel reprocessing technology in Japan. Its designed capacity is about 0.7 metric tons of uranium per day. This report gives an example of the evaluation of the health and environmental aspects of a reprocessing plant. (author)

  3. Assessment of thermal efficiency of heat recovery coke making

    Science.gov (United States)

    Tiwari, H. P.; Saxena, V. K.; Haldar, S. K.; Sriramoju, S. K.

    2017-08-01

    The heat recovery stamp charge coke making process is quite complicated due to the evolved volatile matter during coking, is partially combusted in oven crown and sole flue in a controlled manner to provide heat for producing metallurgical coke. Therefore, the control and efficient utilization of heat in the oven crown, and sole flue is difficult, which directly affects the operational efficiency. Considering the complexity and importance of thermal efficiency, evolution of different gases, combustion of gasses in oven crown and sole flue, and heating process of coke oven has been studied. A nonlinear regression methodology was used to predict temperature profile of different depth of coal cake during the coking. It was observed that the predicted temperature profile is in good agreement with the actual temperature profile (R2 = 0.98) and is validated with the actual temperature profile of other ovens. A complete study is being done to calculate the material balance, heat balance, and heat losses. This gives an overall understanding of heat flow which affects the heat penetration into the coal cake. The study confirms that 60% heat was utilized during coking.

  4. Coking coal outlook from a coal producer's perspective

    International Nuclear Information System (INIS)

    Thrasher, E.

    2008-01-01

    Australian mine production is recovering from massive flooding while Canadian coal shipments are limited by mine and rail capacity. Polish, Czech, and Russian coking coal shipments have been reduced and United States coking coal shipments are reaching their maximum capacity. On the demand side, the Chinese government has increased export taxes on metallurgical coal, coking coal, and thermal coal. Customers seem to be purchasing in waves and steel prices are declining. This presentation addressed the global outlook for coal as well as the challenges ahead in terms of supply and demand. Supply challenges include regulatory uncertainty; environmental permitting; labor; and geology of remaining reserves. Demand challenges include global economic uncertainty; foreign exchange values; the effect of customers making direct investments in mining operations; and freight rates. Consolidation of the coal industry continued and several examples were provided. The presentation also discussed other topics such as coking coal production issues; delayed mining permits and environmental issues; coking coal contract negotiations; and stock values of coking coal producers in the United States. It was concluded that consolidation will continue throughout the natural resource sector. tabs., figs

  5. Fissure formation in coke. 1: The mechanism of fissuring

    Energy Technology Data Exchange (ETDEWEB)

    D.R. Jenkins; M.R. Mahoney; J.C. Keating [CSIRO Mathematical and Information Sciences, North Ryde, NSW (Australia)

    2010-07-15

    Pilot scale coke oven experiments, in which carbonisation has been arrested after 2 and 4 h, have been used to identify key aspects of the initial formation and propagation of fissuring in coke. The experiments show that the primary fissure network is formed within the first few hours of coking and the fissures propagate towards the centre of the oven as coking progresses. They also show that some of the initially formed fissures stop propagating, thus increasing the effective fissure spacing as coking continues. A model for the propagation of regular crack arrays has been used to identify the cause of the initial formation of the fissure network, evaluate the fissure spacing and explain the fissure coarsening effect. The coarsening is shown to be due to an instability, in the form of every second fissure stopping. The formation of lateral fissures is shown to be due to tensile stress formation near the tips of stopped fissures and also to increased shrinkage due to a maximum in the coke contraction coefficient at around 700{sup o}C. 45 refs., 11 figs., 1 tab.

  6. Proceedings of the Joint Meeting of The Fuel Society of Japan (1991). 28th Coal Science Conference/91st Coke Meeting; (Sha) nenryo kyokai godo taikai happyo ronbunshu (1991). Dai 28 kai sekitan kagaku kaigi dai 91 kai cokes tokubetsukai

    Energy Technology Data Exchange (ETDEWEB)

    1991-11-07

    Relating to coke, studies are made on the rapid coke production method, oven investigation during carbonization, and operational management/control. As to coal science, studies are mainly on the brown coal two-stage liquefaction (BCL) method, and data on the pilot plant and PSU are reported. Concerning bituminous coal liquefaction, PSU data mostly including the NEDOL process, and characteristics of liquefaction residue and its effective utilization by thermal decomposition are reported. Regarding the liquefaction mechanism, an experimentally extensive study on catalyst, solvent and reaction conditions is made using model materials and coal itself on the bench scale and also in the pilot plant. Engineering subjects on residue, solvent deashing, scale attachment and coprocessing are also reported. Relations of decomposition process to coal chemical structure changes and reaction conditions are investigated. As to coal gasification, studies, which are not many, are conducted on material balance, heat balance, and image characteristics of char for gasification and factors controlling reactivity.

  7. Fatigue behaviour of coke drum materials under thermal-mechanical cyclic loading

    Directory of Open Access Journals (Sweden)

    Jie Chen

    2014-01-01

    Full Text Available Coke drums are vertical pressure vessels used in the delayed coking process in petroleum refineries. Significant temperature variation during the delayed coking process causes damage in coke drums in the form of bulging and cracking. There were some studies on the fatigue life estimation for the coke drums, but most of them were based on strain-fatigue life curves at constant temperatures, which do not consider simultaneous cyclic temperature and mechanical loading conditions. In this study, a fatigue testing system is successfully developed to allow performing thermal-mechanical fatigue (TMF test similar to the coke drum loading condition. Two commonly used base and one clad materials of coke drums are then experimentally investigated. In addition, a comparative study between isothermal and TMF lives of these materials is conducted. The experimental findings lead to better understanding of the damage mechanisms occurring in coke drums and more accurate prediction of fatigue life of coke drum materials.

  8. Investigating combined influence of petrology and technological parameters on strength of porous coke body

    Energy Technology Data Exchange (ETDEWEB)

    Dinel' t, V.M.; Shkoller, M.B.; Stankevich, A.S.; Korchuganova, G.S.

    1983-09-01

    The VUKhIN branch in Kuznetsk investigated effects of coal petrology and coking conditions on structural strength of coke in blast furnaces. Structural strength of coke produced from black coal from the Kuzbass as well as structural strength of coke partially gasified by carbon dioxide under conditions similar to those in blast furnaces was investigated. Fourteen samples of coal mixtures from the Kuzbass were used. Regression analysis was applied. Equations for forecasting coke properties on the basis of coal petrology and selected parameters characterizing coking were derived. Analyses showed that coke structural strength was decisively influenced by coefficients which characterized the average reflectivity of vitrinite in a coal mixture and its average density. After partial coke gasification by carbon dioxide effects of coefficients which characterized coal mixture nonhomogeneity (fluctuations of vitrinite reflectivity) and coal mixture density increased. Increasing coal density partially compensated negative effects of fluctuations of vitrinite reflectivity on coke structural strength. (10 refs.) (In Russian)

  9. Update of the mortality study of workers exposed to polychlorinated biphenyls (Pcbs) in two Italian capacitor manufacturing plants.

    Science.gov (United States)

    Pesatori, Angela Cecilia; Grillo, P; Consonni, D; Caironi, M; Sampietro, G; Olivari, Leonella; Ghisleni, Silvia; Bertazzi, P A

    2013-01-01

    PCB carcinogenicity to humans is still controversial. Cohort mortality studies in PCB-exposed workers reported elevated risks for the following causes of death: liver, stomach, digestive, brain, prostate cancers and non-Hodgkin lymphoma. The purpose of this study was to update as of December 2006 the mortality experience of two Italian cohorts of workers employed in the manufacture of capacitors impregnated with PCBs. Age-gender-and calendar period adjusted Standardized Mortality Ratios (SMRs) and 95% Confidence Intervals (CI) were calculated using regional rates. Analyses by duration of employment and time since first employment were performed Results: Vital status was ascertained for 98.9% of the study subjects. Mortality from biliary tract cancer among males (SMR 3.91; 95%CI 1.47-10.41), digestive cancer "not otherwise specified" in the whole cohort (SMR 2.54; 95%CI 1.21-5.34), and brain cancer in Plant I (SMR 2.13; 95%CI 1.02-4.48), were significantly increased. Increased risks were also observed for Hodgkin's and non-Hodgkin lymphoma. No linear associations between mortality and duration of employment or latency were observed for these cancers. Mortality from stomach cancer did not differ from expectation in the whole cohort, however an increasing risk with increasing duration of employment was detected (p for trend=0.02). The current update suggests possibly increased cancer risks in PCB-exposed workers, affecting in particular the digestive system, brain, and lymphohemopoietic tissue. However the limited sample size, the lack of clear trends with duration of employment or with latency period, preclude to derive definite conclusions about PCB exposure and the increased cancer risks.

  10. Engineering solutions to improve environmental characteristics of coke-chemical industry

    Energy Technology Data Exchange (ETDEWEB)

    Lavrov, K G; Cherkashina, O I; Pushkarev, G P; Pakhomov, V A; Florinskii, N V; Oleinik, K P; Likhogub, E P; Dorfman, G A; Gorelik, Ya L; Vorona, V K

    1979-06-01

    In future projects consideration will be given to reduction of air and water pollution. Escape of dust from coke-batteries and coal preparation plants will be stopped by using hermetic enclosures with aspirators. Effluent gases and vapours will be curbed by using more efficient scrubbers and flare systems. Effluent waters will be treated at two-stage flotation stations and recycled to 95% as cooling and utility water. Cooling water consumption will be reduced by the use of air coolers. Pollution monitoring will be improved.

  11. Contribution to the assessment of sampling data of coke. Beitrag zur Auswertung von Probenahme-ergebnissen von Koks

    Energy Technology Data Exchange (ETDEWEB)

    Goell, G; Helfricht, R; Mueller, H [Forschungsinstitut fuer Aufbereitung, Freiberg (Germany, F.R.)

    1991-03-01

    Controlling the quality characteristics of disperse material systems in plants where these are produced and applied, by means of test procedures, assumes that samples are taken from mass flows. In this contribution, a report is presented on research on the clarification of the causes of fluctuations and differences of test results for coke between supplier and customer. It is revealed that for an appraisal, prehistory and material behaviour of the test material as well as analysis of the actual condition of the sampling and processing systems of both plants are to be considered. The magnitude of the individual error in relation to the total sampling error is explored and conclusions are drawn, to rule out differences as well as unfavourable developments in the production, utilization and the appraisal of coke products. 15 refs., 7 figs.

  12. Improving the safety of workers in the vicinity of mobile plant

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-07-01

    This report investigates possible approaches and technologies to improve the safety of pedestrians around mobile plant. The study has considered mobile plant in underground mining, surface mineral extraction and warehousing and materials handling. It investigates vehicle ergonomics and visual task analysis, aids to improve reversing and sight lines, direct body detection techniques, conventional transponder (RFID) and VLF magnetic dipole detection technologies. 43 refs., 5 apps.

  13. Asbestos related diseases among workers of asbestos processing plants in relation to type of production and asbestos use.

    Science.gov (United States)

    Szeszenia-Dąbrowska, Neonila; Świątkowska, Beata; Sobala, Wojciech; Szubert, Zuzanna; Wilczyńska, Urszula

    2015-01-01

    Asbestos dust is one of the most dangerous pneumoconiotic and carcinogenic agents. The aim of this study was to assess the occurrence of asbestosis and pleural mesothelioma, depending on asbestos consumption and the type of manufactured products, among former asbestos workers in Poland. The study subjects included employees of 18 large state-owned asbestos processing enterprises operating in the Polish market in 1945-1998. The study is based on data obtained from asbestos company records and the Central Register of Occupational Diseases data on the cases of asbestosis and mesothelioma for the period from 1970 till 2012 as well as data from Amiantus Programme. The analysis was performed for 5 sectors comprising plants classified according to the products manufactured and applied production technology. In the study period, 2160 cases of asbestosis and 138 cases of mesothelioma were reported. The plants processed a total of about 2 million tons of asbestos, including about 7.5% of crocidolite. Total asbestosis consumption was a strong predictor of the rate of asbestosis incidence (R2 = 0.68, p = 0.055). The highest risk occurrence of asbestosis was observed in the production of textiles and sealing products. Mesothelioma occurred only in plants where crocidolite had been ever processed. Total asbestos consumption was a strong predictor of the rate of asbestosis incidence. The observation confirms the relationship between exposure to crocidolite and the occurrence of mesothelioma, regardless of the manufactured products, and suggests the absence of such a link for the total volume of asbestos consumption.

  14. Combined effects of radiation and other agents on the stomach cancer incidence among Mayak Atomic Plant workers

    Energy Technology Data Exchange (ETDEWEB)

    Zhuntova, G.V.; Tokarskaya, Z.B.; Belyaeva, Z.D. [Branch No 1 of State Research Center of Public Health Ministry of the Russian Federation, Ozyorsk (Russian Federation). Biophysics Inst.; Rovny, S.I.; Sirchikov, V.A.

    2000-05-01

    The gravity of a problem of the combined action of radiation and other factors again was confirmed sessions UNSCEAR in May, 1998. It especially is important at study of cancer diseases in connection with the polyetiology and multistage of them development. The estimation of radiation, medico-biological factors and condition of life in occurrence of a stomach cancer among Mayak personnel was specified by case-cohort research. For a quota 503 men (157 cases of a stomach cancer, 346 men of the healthy personnel) attributive risk of the radiation factors was 8.8%, medico-biological - 57,2% (from them by greatest was influence chronic gastritis with secreting insufficiency - 35.4%), tobacco consumption - 31,6%. At an estimation of risk of a stomach cancer depending on external {gamma}-irradiation best fitting was received at use of square-law model. The excess relative risk was 0,27 Gr{sup -2} (F=44,5; P=0,007). For {sup 239}Pu incorporation was not revealed of distinct connection with stomach cancer incidences. Interaction of the radiation and non-radiation factors also was appreciated. The interaction of gastritis with external {gamma}-irradiation or {sup 239}Pu was multiplicate. The interaction of smoking with {gamma}-irradiation or {sup 239}Pu incorporation was multiplicate also. The distribution histological types of a stomach cancer among the workers of Mayak plant differed in comparison with not working. Among the workers the increase poorly differentiated adenocarcinoma was observed. (author)

  15. Combined effects of radiation and other agents on the stomach cancer incidence among Mayak Atomic Plant workers

    International Nuclear Information System (INIS)

    Zhuntova, G.V.; Tokarskaya, Z.B.; Belyaeva, Z.D.; Rovny, S.I.; Sirchikov, V.A.

    2000-01-01

    The gravity of a problem of the combined action of radiation and other factors again was confirmed sessions UNSCEAR in May, 1998. It especially is important at study of cancer diseases in connection with the polyetiology and multistage of them development. The estimation of radiation, medico-biological factors and condition of life in occurrence of a stomach cancer among Mayak personnel was specified by case-cohort research. For a quota 503 men (157 cases of a stomach cancer, 346 men of the healthy personnel) attributive risk of the radiation factors was 8.8%, medico-biological - 57,2% (from them by greatest was influence chronic gastritis with secreting insufficiency - 35.4%), tobacco consumption - 31,6%. At an estimation of risk of a stomach cancer depending on external γ-irradiation best fitting was received at use of square-law model. The excess relative risk was 0,27 Gr -2 (F=44,5; P=0,007). For 239 Pu incorporation was not revealed of distinct connection with stomach cancer incidences. Interaction of the radiation and non-radiation factors also was appreciated. The interaction of gastritis with external γ-irradiation or 239 Pu was multiplicate. The interaction of smoking with γ-irradiation or 239 Pu incorporation was multiplicate also. The distribution histological types of a stomach cancer among the workers of Mayak plant differed in comparison with not working. Among the workers the increase poorly differentiated adenocarcinoma was observed. (author)

  16. New risk indicator approach for Operators, Workers, Bystanders and Residents for a sustainable use of plant protection products.

    Science.gov (United States)

    Sacchettini, Gabriele; Calliera, Maura; Marchis, Alexandru; Glass, Richard; Ellis, Clare Butler; Machera, Kyriaki; Gerritsen-Ebben, Rianda; Spanoghe, Pieter; Capri, Ettore

    2015-11-01

    In 2009, the European Union adopted the Directive on Sustainable Use of pesticides (SUD, Directive 2009/128/EC) establishing a framework for achieving a sustainable use of Plant Protection Products (PPPs) through reducing the risks and impacts of PPP use on human health and the environment, promoting integrated pest management and stimulating effective non-chemical alternatives. The core idea of the SUD is that it is necessary to monitor the use of PPPs through the implementation of an appropriate set of risk indicators to monitor progress and trends in risk reduction within the Member States. To contribute to this direction, following a comprehensive analysis of the risk (including procedures of risk assessment and risk management) and involving stakeholders in the decision process, specific toolboxes of practical indirect risk indicators of exposure of Operators, Workers, Bystanders and Residents were developed and are now available to be used by Member States (MSs) based on their specific context.

  17. Enrichment of reactive macerals in coal: its characterization and utilization in coke making

    Science.gov (United States)

    Nag, Debjani; Kopparthi, P.; Dash, P. S.; Saxena, V. K.; Chandra, S.

    2018-01-01

    Macerals in coal are of different types: reactive and inert. These macerals are differ in their physical and chemical properties. Column flotation method has been used to separate the reactive macerals in a non-coking coal. The enriched coal is then characterized in order to understand the changes in the coking potential by different techniques. It is then used in making of metallurgical coke by proper blending with other coals. Enriched coal enhance the properties of metallurgical coke. This shows a path of utilization of non-coking coal in metallurgical coke making.

  18. Effects of radiation and apolipoprotein E on lipid profile among workers of nuclear power plants in Korea

    International Nuclear Information System (INIS)

    Ki-Eun Moon; Mee-Seon Jung; Suk-Hee Sung; Youn-Koun Chang; Il-Keun Park; Yun-Mi Paek; Tae-In Choi; Soo-Geun Kim

    2007-01-01

    Complete text of publication follows. Several studies reported that the radiation was positively related to fatty liver, low HDL cholesterol, and hypertriglyceridemia. Genetic polymorphism affect prevalence of chronic disease by molecular epidemiology studies. Apolipoprotein E is an important genetic determinant of cardiovascular disease (CVD), namely through its influence on lipid metabolism. Thus, we investigated whether radiation and apo E polymorphism, and environmental factors contribute to the lipid profile in workers of nuclear power plants in Korea. DNA was extracted from the whole blood of 6896 study subjects (6357 males and 359 females), and apo E polymorphism was investigated using PCR. Plasma lipid profiles were measured by standardized enzymatic procedures and radiation dose was measured by the thermoluminescence dosemeter (TLD). Environmental factors such as exercise, smoking were measured from health management database of KHNP. Total of 6802 subjects (aged 20-58) were investigated and radiation exposure dose was 168.51±463.94 mSv in the recent 1-year dose and 248.24±559.21 mSv in the total accumulative dose. In addition, Apo E polymorphism was associated with significant differences in total cholesterol, HDL cholesterol, radiation dose, AI but others no significant. The multiple regression model showed that total cholesterol was positively correlated with age, SBP, BMI, AI, fasting glucose. HDL cholesterol was negatively correlated with AI. LDL cholesterol was positively correlated with age, BMI, fasting glucose. And triglyceride was significantly correlated in the BMI, AI, somking dose, vegetables but others no significant. Metabolic syndrome did not show any relation to the others; only age, SBP, DBP, BMI, fasting glucose, HOMA-IR influenced. However, there was no significant association between radiation dose and lipid profile. In conclusion, Apo E and well-known variables such as SBP, BMI were significantly associated with lipid profile level

  19. Petroleum Coke in the Urban Environment: A Review of Potential Health Effects

    Directory of Open Access Journals (Sweden)

    Joseph A. Caruso

    2015-05-01

    Full Text Available Petroleum coke, or petcoke, is a granular coal-like industrial by-product that is separated during the refinement of heavy crude oil. Recently, the processing of material from Canadian oil sands in U.S. refineries has led to the appearance of large petcoke piles adjacent to urban communities in Detroit and Chicago. The purpose of this literature review is to assess what is known about the effects of petcoke exposure on human health. Toxicological studies in animals indicate that dermal or inhalation petcoke exposure does not lead to a significant risk for cancer development or reproductive and developmental effects. However, pulmonary inflammation was observed in long-term inhalation exposure studies. Epidemiological studies in coke oven workers have shown increased risk for cancer and chronic obstructive pulmonary diseases, but these studies are confounded by multiple industrial exposures, most notably to polycyclic aromatic hydrocarbons that are generated during petcoke production. The main threat to urban populations in the vicinity of petcoke piles is most likely fugitive dust emissions in the form of fine particulate matter. More research is required to determine whether petcoke fine particulate matter causes or exacerbates disease, either alone or in conjunction with other environmental contaminants.

  20. Pyrolisator Coal to be Cokes (Coal Cokes Casting Metal Industry Standard

    Directory of Open Access Journals (Sweden)

    Sukamto

    2016-01-01

    Full Text Available Pyrolisis of coal is partial combustion to reduce total moisture, volatile matter and sulfur contens and increase the calorific value of coal. The results of pyrolysis of coal is coke. At the laboratory level studies, pyrolisis done in batch using different calorie, namely 5800, 6000, 6300 kcal/kg and a time of 15-60 minutes and the temperature 400-800°C. Maximum results obtained total moisture (0.44%, fixed carbon (89%, volatile matter (2.4%, sulfur content (undetected and ash (7.2%. Then applied to the scale miniplant with continuous processes using multitube pyrolisator which are designed to operate in the temperature range 400-800°C and a flow rate of 240-730 kg/h, obtained coal cokes that meets industry quality standards, namely TM (0.42%, FC (90.40%, VM (2.16%, S (not detected, Ash (6.8% incalori 6300 kcal/h, a flow rate of 240 kg / h and temperatures between 600-700°C

  1. Lung scintigraphy evaluation in workers exposed to abrasive dusts; Avaliacao cintilografica pulmonar em trabalhadores de industria de abrasivos

    Energy Technology Data Exchange (ETDEWEB)

    Terra Filho, Mario

    1996-12-31

    The production process of abrasives use aluminium, or silicon carbide a synthetic material with a hardness only slightly less than that of a diamond. It is popularly known as carborundum since it was first manufactured as an abrasive in 1891, produced by the fusion of high grade silica and petroleum coke with sawdust. For many years silicon carbide was thought not to give rise to pulmonary lesions. Recently several researchers suggested the existence of a carborundum pneumoconiosis. The aim of this study was to evaluate the role of the pulmonary clearance of {sup 99m} Technetium chelated to diethylene-triamine penta-acetate ({sup 99m} Tc DTPA), and {sup 67} Gallium lung scanning in workers exposed to abrasive dusts. Thirty seven subjects, 13 smokers and 24 nonsmokers and ex smokers were studied. In 32 (86,48%) {sup 67} Gallium lung scanning was positive including 13 (40,62%) retired workers. We conclude that non smoking workers of abrasives plants have a pulmonary alveolar epithelial permeability disturbance similar as observed in smoking workers and smoking controls. Most workers, ex-workers of these industries and in patients with carborundum pneumoconiosis there is an evidence of pulmonary inflammation measured with abnormal {sup 67} Gallium lung scan. (author) 101 refs., 2 figs., 11 tabs.

  2. Lung scintigraphy evaluation in workers exposed to abrasive dusts; Avaliacao cintilografica pulmonar em trabalhadores de industria de abrasivos

    Energy Technology Data Exchange (ETDEWEB)

    Terra Filho, Mario

    1995-12-31

    The production process of abrasives use aluminium, or silicon carbide a synthetic material with a hardness only slightly less than that of a diamond. It is popularly known as carborundum since it was first manufactured as an abrasive in 1891, produced by the fusion of high grade silica and petroleum coke with sawdust. For many years silicon carbide was thought not to give rise to pulmonary lesions. Recently several researchers suggested the existence of a carborundum pneumoconiosis. The aim of this study was to evaluate the role of the pulmonary clearance of {sup 99m} Technetium chelated to diethylene-triamine penta-acetate ({sup 99m} Tc DTPA), and {sup 67} Gallium lung scanning in workers exposed to abrasive dusts. Thirty seven subjects, 13 smokers and 24 nonsmokers and ex smokers were studied. In 32 (86,48%) {sup 67} Gallium lung scanning was positive including 13 (40,62%) retired workers. We conclude that non smoking workers of abrasives plants have a pulmonary alveolar epithelial permeability disturbance similar as observed in smoking workers and smoking controls. Most workers, ex-workers of these industries and in patients with carborundum pneumoconiosis there is an evidence of pulmonary inflammation measured with abnormal {sup 67} Gallium lung scan. (author) 101 refs., 2 figs., 11 tabs.

  3. Mortality among workers in a die-casting and electroplating plant.

    Science.gov (United States)

    Silverstein, M; Mirer, F; Kotelchuck, D; Silverstein, B; Bennett, M

    1981-01-01

    A proportional mortality and case-referent analysis of 238 deaths among hourly employees in an automobile hardware manufacturing plant was conducted. The major operations of the plant were zinc die casting and electroplating. Chemical exposure included die-casting emissions and mists from chrome and nickel plating. The chief proportional mortality finding was a significant excess of lung cancer among both white men and women. A case-referent analysis indicated a possible association between lung cancer and work in certain departments. The findings support the hypothesis of a work-related carcinogenic risk. Follow-up recommendations have been made.

  4. Integrated process for synthetic natural gas production from coal and coke-oven gas with high energy efficiency and low emission

    International Nuclear Information System (INIS)

    Man, Yi; Yang, Siyu; Qian, Yu

    2016-01-01

    Highlights: • A novel coal and coke-oven gas to SNG (CGtSNG) process is proposed. • Energy efficiency of CGtSNG increases 8% compared to coal-to-SNG process. • CGtSNG reduces 60% CO_2 emission and 72% effluent discharge. • CGtSNG proposes an idea of using redundant coke-oven gas for producing SNG production. - Abstract: There was a rapid development of coal to synthetic natural gas (SNG) projects in the last few years in China. The research from our previous work and some other researchers have found coal based SNG production process has the problems of environmental pollution and emission transfer, including CO_2 emission, effluent discharge, and high energy consumption. This paper proposes a novel co-feed process of coal and coke-oven gas to SNG process by using a dry methane reforming unit to reduce CO_2 emissions, more hydrogen elements are introduced to improve resource efficiency. It is shown that the energy efficiency of the co-feed process increases by 4%, CO_2 emission and effluent discharge is reduced by 60% and 72%, whereas the production cost decreases by 16.7%, in comparison to the conventional coal to SNG process. As coke-oven gas is a waste gas in most of the coking plant, this process also allows to optimize the allocation of resources.

  5. Mini-PROven. Reduced emissions from small and medium-size coke ovens thanks to single-chamber pressure control; Mini-PROven. Emissionsreduzierung an kleinen und mittleren Koksoefen mit einer Einzelkammerdruckregelung

    Energy Technology Data Exchange (ETDEWEB)

    Huhn, Friedrich; Krebber, Frank; Kuehn-Gajdzik, Joanna; Ueberschaer, Kerstin [ThyssenKrupp Uhde GmbH, Dortmund (Germany). Coke Plant Technologies Div.

    2012-07-01

    For environment and occupational health reasons it is becoming increasingly important for coke plants to be operated with the lowest possible level of emissions. In the past, changing pressure conditions in each individual oven, with particularly high values at the beginning of the coking period, often resulted in considerable emissions at the oven closures. To prevent this happening on modern large-scale ovens, ThyssenKrupp Uhde developed the PROven trademark (Pressure Regulated Oven), a single-chamber pressure control system which regulates the pressure in the individual coke chambers down to a constantly low level. In the meantime, after many years of successful service, the system has been upgraded in both its design and process engineering. The result is Mini-PROven, which in future can also be retro-fitted to old small and medium-size coke oven batteries in the interest of better environmental protection. (orig.)

  6. Fatigue life estimation on coke drum due to cycle optimization

    Science.gov (United States)

    Siahaan, Andrey Stephan; Ambarita, Himsar; Kawai, Hideki; Daimaruya, Masashi

    2018-04-01

    In the last decade, due to the increasing demand of petroleum product, the necessity for converting the heavy oil are increasing. Thus, demand for installing coke drum in whole world will be increase. The coke drum undergoes the cyclic high temperature and suddenly cooling but in fact is not designed to withstand that kind of cycle, thus the operational life of coke drum is much shorter in comparison to other equipment in oil refinery. Various factors determine in order to improve reliability and minimize the down time, and it is found that the cycle optimization due to cycle, temperature, and pressure have an important role. From this research it is found that the fatigue life of the short cycle is decrease by a half compare to the normal cycle. It also found that in the preheating stage, the stress peak is far exceed the yield strength of coke drum material and fall into plastic deformation. This is happened because of the temperature leap in the preheating stage that cause thermal shock in the upper part of the skirt of the coke drum.

  7. Utilization of formed coke from HBNPC in the Dunkerque blast furnaces

    Energy Technology Data Exchange (ETDEWEB)

    Le Scour, C; Capelani, R

    1978-01-01

    Recalls the aspects involved in the manufacture of formed coke together with the coke characteristics. Describes the features of blast-furnaces No. 1 and No. 2 at Dunkerque. The blend used for producing the ovoids is composed of 70 to 80% non-coking coal and the ovoids are carbonized at 900 C. The first stage of the tests was carried out with 25% formed coke and the second stage with 22%. The formed coke was charged separately. The results were as follows: the coke rate was comparable and the permeability identical; there was no change in the behaviour of the furnace chamber and no problems were experienced at the hearth stage. The replacement of 30% of the conventional coke by HBNPC formed coke seemed a practical proposition.

  8. Department of Energy's safety and health program for enrichment plant workers is not adequately implemented

    International Nuclear Information System (INIS)

    Staats, E.B.

    1980-01-01

    The Department of Energy's (DOE's) program to protect the safety and health of employees at its contractor-operated uranium enrichment plants has not been fully implemented by DOE's Oak Ridge Operations Office. Appraisals and inspections of plant conditions are not as frequent and/or as thorough as required. Instead of independently investigating employee complaints, DOE has delegated this responsibility to the contractor. It is recommended that the Secretary of Energy make sure that Oak Ridge properly conducts inspections and appraisals and investigates and follows up on all employee complaints. He should also take steps to provide increased independence and objectivity in the Oak Ridge Operations Office's safety and health program. Furthermore, the Congress should authorize the Secretary of Energy to institute a program of non-reimbursable penalties and fines for violations of safety and health standards and procedures

  9. Mortality among flavour and fragrance chemical plant workers in the United States.

    Science.gov (United States)

    Thomas, T L

    1987-01-01

    Vital status on 1 January 1981 was determined for a cohort of 1412 white men employed in a flavour and fragrance chemical plant between 1945 and 1965 in order to investigate the risks from fatal diseases among men exposed to multiple chemicals in the manufacture of fragrances, flavours, aroma chemicals, and other organic substances. Cause specific standardised mortality ratios (SMRs) were calculated for the entire study population and for several subsets by likelihood of exposure to chemicals, duration of employment, and year of hire. SMRs for rectal cancer and ischaemic heart disease were raised among white male employees whose jobs were in production, maintenance, laboratory, or other jobs that would involve exposure to multiple chemicals used and produced in the plant. The excess of rectal cancer was confined to employees who had worked as chemical operators and mortality was significantly raised among men who worked for ten or more years. Traces of dioxin were recently found in and around plant buildings that used trichlorophenol in the production of hexachlorophene. The study group was small and had limited power to detect excess risk of rare causes of death; however, no soft tissue sarcomas were observed during the study period. PMID:3689704

  10. Biological monitoring to determine worker dose in a butadiene processing plant

    Energy Technology Data Exchange (ETDEWEB)

    Bechtold, W.E.; Hayes, R.B. [National Cancer Inst., Bethesda, MD (United States)

    1995-12-01

    Butadiene (BD) is a reactive gas used extensively in the rubber industry and is also found in combustion products. Although BD is genotoxic and acts as an animal carcinogen, the evidence for carcinogenicity in humans is limited. Extrapolation from animal studies on BD carcinogenicity to risk in humans has been controversial because of uncertainties regarding relative biologic exposure and related effects in humans vs. experimental animals. To reduce this uncertainty, a study was designed to characterize exposure to BD at a polymer production facility and to relate this exposure to mutational and cytogenetic effects. Biological monitoring was used to better assess the internal dose of BD received by the workers. Measurement of 1,2-dihydroxy-4-(N-acetylcysteinyl) butane (M1) in urine served as the biomarker in this study. M1 has been shown to correlate with area monitoring in previous studies. Most studies that relate exposure to a toxic chemical with its biological effects rely on exposure concentration as the dose metric; however, exposure concentration may or may not reflect the actual internal dose of the chemical.

  11. Microstructures and microtextures of natural cokes: A case study of heat-affected coking coals from the Jharia coalfield, India

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Ashok K. [Central Fuel Research Institute, CSIR, Dhanbad-828108 (India); Singh, Mahendra P. [Department of Geology, Banaras Hindu University, Varanasi-221005 (India); Sharma, Mamta; Srivastava, Sunil K.

    2007-07-02

    In Jharia coalfield, nearly 1250 Mt of coking coal has been devolatilized due to igneous intrusives and {proportional_to} 1900 Mt due to mine fires. This paper is an effort to investigate the effect of carbonization in two intrusive affected coal seams of Ena (seam XIII) and Alkusa (seam XIV) collieries of this coalfield. Through petrographic studies by microscopy, characterization of normal and heat-affected coals was carried out. The microstructures and microtextures produced due to extraneous heat have been related to nature and extent of heat, location of heating source, and quality and quantity of natural coke produced. Based on the results of this study and earlier studies, an effort has been made to study the classification scheme for microtextures of natural cokes generated through in-situ carbonization of the coal seams. It has been observed that in case of such heat effects under overburden pressure, the anisotropy is much more pronounced as compared to laboratory-carbonized cokes. In the mildly carbonized coals (pre-plastic phase, < 300 C) the vitrinite attained higher reflectance than normal vitrinite, liptinite started disappearing, and inertinite remained unaffected. In the moderately affected coals (plastic phase, 300-500 C), mesophase spheres and fused natural cokes were generated from the reactives (vitrinite and liptinite maceral groups), the liptinites disappeared, and structurally, the inertinites remained almost unchanged with slight increase in the reflectance value. In the severely heat-affected coals (post plastic phase, > 500 C) the identified microtextures were mesophase spheres, different shapes and sizes of natural cokes, graphitic sphaeroliths, pyrolytic carbons, inerts with morpho-structural changes and slightly higher reflectance values, and altered and unaltered mineral matters. A gradual change in the heat-affected coals with increasing temperature was observed with respect to location of intrusive body. It has been concluded that

  12. [A cohort study on occupational noise induced hearing loss in workers at an iron and steel plant].

    Science.gov (United States)

    Yu, S F; Chen, G S; Jiao, J; Gu, G Z; Zhang, H L; Wang, X M; Zhou, W H; Wu, H; Li, Y H; Zheng, Y X

    2017-01-06

    Objective: To analyze the incidence rate of occupational noise-induced hearing loss in noise-exposed workers in an iron and steel plant from 2006 to 2015. Methods: Using a cohort study method, workers exposed to occupational noise from Jan 1, 2006 to Dec 12, 2015 were followed up and the pure tone hearing test was conducted. In total, 6 297 subjects completed two or more physical checks and the pure tone hearing test and were included in the analysis. The noise exposure level at the workplace and the equivalent continuous A-weighted sound pressure level for workers was monitored and the cumulative noise exposure dose was evaluated. The subjects were divided into low, middle and high exposure groups according to the noise exposure level, and the equivalent continuous A-weighted sound pressure level for 8 hours for each group was 80.6-85.0, 85.1-90.0 and 90.1-103.4 dB (A), respectively. While the RR and 95% CI were derived from unconditional logistic regression models. In logistic regression analysis, confounding factors such as age, gender, smoking habit, drinking habit, high temperature exposure and chemical hazards exposure level were controlled. Results: During the follow-up period, 392 cases of occupational noise-induced hearing loss were diagnosed among the 6 297 subjects, with an incidence rate of 6.23%; 318 cases of high-frequency hearing loss were diagnosed, with an incidence rate of 5.05%; and 74 cases of occupational noise-induced deafness were diagnosed, with an incidence rate of 1.18% . The incidence rates of hearing loss among the high, medium and low exposure groups were 9.22% (158/1 737), 6.49% (204/3 142) and 2.08% (30/1 442), respectively; the rates of high-frequency hearing loss were 7.41% (127/1 737), 5.25% (165/3 142) and 1.80% (26/1 442), respectively; and the rates of occupational noise-induced deafness were 1.81% (31/1 737), 1.24% (39/3 142) and 0.28% (4/1 442), respectively. For the groups corresponding to cumulative noise exposure doses of

  13. Simulation and optimization of a coking wastewater biological treatment process by activated sludge models (ASM).

    Science.gov (United States)

    Wu, Xiaohui; Yang, Yang; Wu, Gaoming; Mao, Juan; Zhou, Tao

    2016-01-01

    Applications of activated sludge models (ASM) in simulating industrial biological wastewater treatment plants (WWTPs) are still difficult due to refractory and complex components in influents as well as diversity in activated sludges. In this study, an ASM3 modeling study was conducted to simulate and optimize a practical coking wastewater treatment plant (CWTP). First, respirometric characterizations of the coking wastewater and CWTP biomasses were conducted to determine the specific kinetic and stoichiometric model parameters for the consecutive aeration-anoxic-aeration (O-A/O) biological process. All ASM3 parameters have been further estimated and calibrated, through cross validation by the model dynamic simulation procedure. Consequently, an ASM3 model was successfully established to accurately simulate the CWTP performances in removing COD and NH4-N. An optimized CWTP operation condition could be proposed reducing the operation cost from 6.2 to 5.5 €/m(3) wastewater. This study is expected to provide a useful reference for mathematic simulations of practical industrial WWTPs. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. Microporous Cokes Formed in Zeolite Catalysts Enable Efficient Solar Evaporation

    KAUST Repository

    Wang, Jianjian

    2017-03-13

    Cokes are inevitably generated during zeolite-catalyzed reactions as deleterious side products that deactivate the catalyst. In this study, we in-situ converted cokes into carbons within the confined microporous zeolite structures and evaluated their performances as absorbing materials for solar-driven water evaporation. With a properly chosen zeolite, the cokederived carbons possessed ordered interconnected pores and tunable compositions. We found that the porous structure and the oxygen content in as-prepared carbons had important influences on their energy conversion efficiencies. Among various investigated carbon materials, the carbon derived from the methanol-to-olefins reaction over zeolite Beta gave the highest conversion efficiency of 72% under simulated sunlight with equivalent solar intensity of 2 suns. This study not only demonstrates the great potential of traditionally useless cokes for solar thermal applications but also provides new insights into the design of carbon-based absorbing materials for efficient solar evaporation.

  15. Influence of thermal charge preparation on coke comminution under blast-furnace operating conditions

    Energy Technology Data Exchange (ETDEWEB)

    Shkoller, M.B.; Dinel' t, V.M.; Korchuganova, G.S.; Petrov, V.B.

    1983-09-01

    Reactions of coke in the blast furnace are determined mainly by the nature of the coke itself which depends on the coal properties, its preparation and the coking conditions. In the blast furnace the coke reacts with alkali and alkaline earth metals in the burden. Preheated coal charges were found to absorb far less sodium and potassium carbonates than a conventional moist charge over an equivalent period, due to the smaller pore volume available.

  16. The coke formation during the pyrolysis of 1,2-dichloroethane - results of radiotracer experiments

    International Nuclear Information System (INIS)

    Kopinke, F.D.; Zychlinski, W.; Rodewald, D.

    1990-01-01

    The formation of coke-like deposits during the pyrolysis of dichloroethane has been investigated by means of 14 C-labelled compounds. Starting from industrial feedstocks coke is formed from dichloroethane and its primary reaction products as well as from trace impurities with comparable rates. Chloroprene has been revealed as an effective coke precursor. The coke formation from industrial feedstocks can be reduced significantly by suitable purification methods. (author)

  17. Coke industry and steel metallurgy as the source of soil contamination by technogenic magnetic particles, heavy metals and polycyclic aromatic hydrocarbons.

    Science.gov (United States)

    Rachwał, Marzena; Magiera, Tadeusz; Wawer, Małgorzata

    2015-11-01

    Application of integrated magnetic, geochemical and mineralogical methods for qualitative and quantitative assessment of forest topsoils exposed to the industrial emissions was the objective of this manuscript. Volume magnetic susceptibility (κ) in three areas of southern Poland close to the coke and metallurgical plants was measured directly in the field. Representative topsoil samples were collected for further chemical and mineralogical analyses. Topsoil magnetic susceptibility in the studied areas depended mainly on the content of technogenic magnetic particles (TMPs) and decreased downwind at increasing distance from the emitters. In the vicinity of coking plants a high amount of polycyclic aromatic hydrocarbons (PAHs) was observed, especially the most carcinogenic ones with four- and five-member rings. No significant concentration of TMPs (estimated on the base of κ values) and heavy metals (HM) was observed in area where the coke plant was the only pollution source. In areas with both coke and metallurgical industry, higher amounts of TMPs, PAHs and HM were detected. Morphological and mineralogical analyses of TMPs separated from contaminated soil samples revealed their high heterogeneity in respect of morphology, grain size, mineral and chemical constitution. Pollution load index and toxicity equivalent concentration of PAHs used for soil quality assessment indicated its high level of pollution. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. An unusual case of organophosphate intoxication of a worker in a plastic bottle recycling plant: an important reminder.

    Science.gov (United States)

    Wang, C L; Chuang, H Y; Chang, C Y; Liu, S T; Wu, M T; Ho, C K

    2000-11-01

    A young man was sent to our emergency unit because he had suffered from vomiting and cold sweating for 2 days. At the time he was admitted, he had no acute abdominal pains or gastrointestinal symptoms, and a physical examination revealed nothing but a faster heart rate and moist, flushing skin. The patient had worked for 6 years at a plastic bottle-recycling factory, but none of his co-workers had the same symptoms. Nevertheless, because the plant also recycled pesticide bottles, we suspected organophosphate pesticide intoxication. The patient's plasma acetylcholinesterase level was checked, revealing 1498.6 microU/L (normal range: 2,000-5, 000) on the first day and 1,379 microU/L on the second day. Upon questioning, the patient recalled that one of his shoe soles had been damaged and that his foot had been wet from walking all day in rain collected on the factory floor on the day that his symptoms first occurred. We conducted a study in the change of preshift and postshift acetylcholinesterase levels among six of his co-workers on a rainy day. We used the Wilcoxon signed rank test to compare the preshift and postshift plasma acetylcholinesterase levels; no significant difference was revealed (p = 0.600), leaving contamination via the damaged shoe sole suspect. We reviewed the literature on organophosphate intoxication; pesticide bottle-recycling factories were reported to be at a low risk of organophosphate toxicity in the working environment. However, because the potential risk of intoxication is still present, protective equipment such as clothing, gloves, and water-proof shoes should be worn, and employees should be educated on the potential risks.

  19. Effects of electromagnetic fields exposure on plasma hormonal and inflammatory pathway biomarkers in male workers of a power plant

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhaopin; Fei, Ying; Liu, Hui [Zhejiang Univ., Hangzhou (China). Dept. of Epidemiology and Health Statistics; Zhejiang Univ., Hangzhou (China). Chronic Disease Research Inst.; and others

    2016-01-15

    The potential health risks of electromagnetic fields (EMFs) have currently raised considerable public concerns. The aim of this study was to evaluate the effects of EMF exposure on levels of plasma hormonal and inflammatory pathway biomarkers in male workers of an electric power plant. Seventy-seven male workers with high occupational EMF exposure and 77 male controls with low exposure, matched by age, were selected from a cross-sectional study. Moreover, high EMF exposure group was with walkie-talkies usage and exposed to power frequency EMF at the work places for a longer duration than control group. A questionnaire was applied to obtain relevant information, including sociodemographic characteristics, lifestyle factors, and EMF exposures. Plasma levels of testosterone, estradiol, melatonin, NF-KB, heat-shock protein (HSP) 70, HSP27, and TET1 were determined by an enzyme-linked immunosorbent assay. EMF exposure group had statistically significantly lower levels of testosterone (β = -0.3 nmol/L, P = 0.015), testosterone/estradiol (T/E2) ratio (β = -15.6, P = 0.037), and NF-KB (β = -20.8 ng/L, P = 0.045) than control group. Moreover, joint effects between occupational EMF exposure and employment duration, mobile phone fees, years of mobile phone usage, and electric fees on levels of testosterone and T/E2 ratio were observed. Nevertheless, no statistically significant associations of EMF exposures with plasma estradiol, melatonin, HSP70, HSP27, and TET1 were found. The findings showed that chronic exposure to EMF could decrease male plasma testosterone and T/E2 ratio, and it might possibly affect reproductive functions in males. No significant associations of EMF exposure with inflammatory pathway biomarkers were found.

  20. Scientific Council on problems on new processes in the coking industry. [Effect on coke consumption of moisture, sulfur and ash; substitution possibility

    Energy Technology Data Exchange (ETDEWEB)

    Filippov, B.S.

    1981-07-01

    This paper presents a report on the Coking Section of the Scientific Council held on November 20, 1980 in Moscow. The following problems were discussed: indexes characterizing blast furnace coke (for furnaces with a volume of 5580 M/sup 3/); replacing metallurgical coke with other types of fuels; use of brown coal; liners of coke ovens. Papers delivered during the session are summarized. Reducing moisture content in blast furnace coke permits its consumption to be reduced by 2%. Reducing sulfur content in blast furnace coke by 0.1% permits its consumption to be reduced from 10 to 15 kg for 1 t of pig iron. Increase in ash content of coke by 1% causes coke consumption increase ranging from 1.5 to 2.0%. About 10 Mmt of coke class with grains above 25 mm in USSR is used for purposes other than blast furnaces. Possibilities of substituting coke with lean coal are evaluated (particularly from Kuzbass). A method for briquetting a mixture of black and brown coal is proposed. Briquets are a suitable fuel in metallurgy. A new type of liner, which consists of at least 92% silicon dioxide, is described. Physical and mechanical properties of the liners are discussed.

  1. Associations between disaster exposures, peritraumatic distress, and posttraumatic stress responses in Fukushima nuclear plant workers following the 2011 nuclear accident: the Fukushima NEWS Project study.

    Science.gov (United States)

    Shigemura, Jun; Tanigawa, Takeshi; Nishi, Daisuke; Matsuoka, Yutaka; Nomura, Soichiro; Yoshino, Aihide

    2014-01-01

    The 2011 Fukushima Daiichi Nuclear Power Plant accident was the worst nuclear disaster since Chernobyl. The nearby Daini plant also experienced substantial damage but remained intact. Workers for the both plants experienced multiple stressors as disaster victims and workers, as well as the criticism from the public due to their company's post-disaster management. Little is known about the psychological pathway mechanism from nuclear disaster exposures, distress during and immediately after the event (peritraumatic distress; PD), to posttraumatic stress responses (PTSR). A self-report questionnaire was administered to 1,411 plant employees (Daiichi, n = 831; Daini, n = 580) 2-3 months post-disaster (total response rate: 80.2%). The socio-demographic characteristics and disaster-related experiences were assessed as independent variables. PD and PTSR were measured by the Japanese versions of Peritraumatic Distress Inventory and the Impact of Event Scale-Revised, respectively. The analysis was conducted separately for the two groups. Bivariate regression analyses were performed to assess the relationships between independent variables, PD, and PTSR. Significant variables were subsequently entered in the multiple regression analyses to explore the pathway mechanism for development of PTSR. For both groups, PTSR highly associated with PD (Daiichi: adjusted β, 0.66; pdisaster-related variables were likely to be associated with PD than PTSR. Among the Fukushima nuclear plant workers, disaster exposures associated with PD. PTSR was highly affected by PD along with discrimination/slurs experience.

  2. Radiation occupational health interventions offered to radiation workers in response to the complex catastrophic disaster at the Fukushima Daiichi Nuclear Power Plant

    International Nuclear Information System (INIS)

    Shimura, Tsutomu; Yamaguchi, Ichiro; Terada, Hiroshi; Kunugita, Naoki; Okuda, Kengo; Svendsen, E.R.

    2015-01-01

    The Fukushima Daiichi Nuclear Power Plant (NPP) 1 was severely damaged from the chain reaction of the Great East Japan Earthquake and Tsunami on 11 March 2011, and the consequent meltdown and hydrogen gas explosions. This resulted in the worst nuclear accident since the Chernobyl accident of 1986. Just as in the case of Chernobyl, emergency workers were recruited to conduct a wide range of tasks, including disaster response, rescuing activities, NPP containment, and radiation decontamination. This paper describes the types and efficacy of the various occupational health interventions introduced to the Fukushima NPP radiation workers. Such interventions were implemented in order to prevent unnecessary radiation overexposure and associated adverse health effects and work injuries. Less than 1% of all emergency workers were exposed to external radiation of >100 mSv, and to date no death or health adversities from radiation have been reported for those workers. Several occupational health interventions were conducted, including setting of new regulatory exposure limits, improving workers' radiation dosimetry, administration of stable iodine, running an occupational health tracking system, and improving occupational medicine and preventative care. Those interventions were not only vital for preventing unnecessary radiation, but also for managing other general health issues such as mental health, heat illness and infectious disease. Long-term administration of the aforementioned occupational health interventions is essential to ensure the ongoing support and care for these workers, who were put under one of the most severe occupational health risk conditions ever encountered. (author)

  3. Monitoring intakes of radionuclides by nuclear power plants workers in France: materials, methods and results

    Energy Technology Data Exchange (ETDEWEB)

    Gonin, M.; Le Guen, B.; Bailloeuil, C.; Gerondal, M. [Electricite De France (France)

    2000-05-01

    EDF (Electricite de France) owns 57 operating reactors distributed on 20 sites. Individual monitoring for intakes of radionuclides is done by whole body gamma countings and excretion bioassays. This monitoring concerns all EDF workers (about 20,000), and also subcontractor personnel (about 40,000 people per year). The aim of monitoring is to detect any intake above the recording level and to assess, as precisely as possible, internal doses. ICRP publications no.30 and 54 are used for internal dose calculations. Whole body countings (approximately 200,000 per year) are made by occupational health services on each nuclear site. The equipment consists of: 1. two whole body counters with two large NaI detectors, the approximate detection limit is 150 Bq in Co-60 for a 1-minute count. 2. one shielded chair with two smallers NaI detectors (one for thyroid and one for thoraco-abdominal region), specially designed for iodine contamination case, or casualties on stretchers. A special medical software program incorporates: 3. an operating system containing a module to ensure the quality control of measurements. 4. a measurement interpretation system with a screening histogram facility for activity alarm levels and spectrometry gamma analysis. 5. an administrative database for nationwide monitoring of all EDF and non-EDF workers. An EDF central radiotoxicology laboratory, located in the suburbs of Paris, analyses all the biological samples (about 8,000 per year, urines, faeces or nose blows) and centralises the results. At the occupational health service's request, the following analyses can be done: 1. tritium activity measurements (liquid scintillation) with a detection limit of 75 Bq per litre, 2. gamma spectrometry (HPGe detectors) on urines and faeces ash samples with a detection limit of 0.5 Bq per sample for one hours of counting. 3. alpha spectrometry (after chemical treatment) on urines and faeces ash samples with a lower detection limit of 0.2 mBq per sample

  4. Monitoring intakes of radionuclides by nuclear power plants workers in France: materials, methods and results

    International Nuclear Information System (INIS)

    Gonin, M.; Le Guen, B.; Bailloeuil, C.; Gerondal, M.

    2000-01-01

    EDF (Electricite de France) owns 57 operating reactors distributed on 20 sites. Individual monitoring for intakes of radionuclides is done by whole body gamma countings and excretion bioassays. This monitoring concerns all EDF workers (about 20,000), and also subcontractor personnel (about 40,000 people per year). The aim of monitoring is to detect any intake above the recording level and to assess, as precisely as possible, internal doses. ICRP publications no.30 and 54 are used for internal dose calculations. Whole body countings (approximately 200,000 per year) are made by occupational health services on each nuclear site. The equipment consists of: 1. two whole body counters with two large NaI detectors, the approximate detection limit is 150 Bq in Co-60 for a 1-minute count. 2. one shielded chair with two smallers NaI detectors (one for thyroid and one for thoraco-abdominal region), specially designed for iodine contamination case, or casualties on stretchers. A special medical software program incorporates: 3. an operating system containing a module to ensure the quality control of measurements. 4. a measurement interpretation system with a screening histogram facility for activity alarm levels and spectrometry gamma analysis. 5. an administrative database for nationwide monitoring of all EDF and non-EDF workers. An EDF central radiotoxicology laboratory, located in the suburbs of Paris, analyses all the biological samples (about 8,000 per year, urines, faeces or nose blows) and centralises the results. At the occupational health service's request, the following analyses can be done: 1. tritium activity measurements (liquid scintillation) with a detection limit of 75 Bq per litre, 2. gamma spectrometry (HPGe detectors) on urines and faeces ash samples with a detection limit of 0.5 Bq per sample for one hours of counting. 3. alpha spectrometry (after chemical treatment) on urines and faeces ash samples with a lower detection limit of 0.2 mBq per sample for 72

  5. Perceived Workplace Interpersonal Support Among Workers of the Fukushima Daiichi Nuclear Power Plants Following the 2011 Accident: The Fukushima Nuclear Energy Workers' Support (NEWS) Project Study.

    Science.gov (United States)

    Takahashi, Sho; Shigemura, Jun; Takahashi, Yoshitomo; Nomura, Soichiro; Yoshino, Aihide; Tanigawa, Takeshi

    2017-10-10

    The 2011 Fukushima Daiichi nuclear accident was the worst nuclear disaster since Chernobyl. The Daiichi workers faced multiple stressors (workplace trauma, victim experiences, and public criticism deriving from their company's post-disaster management). Literatures suggest the importance of workplace interpersonal support (WIS) in enhancing psychological health among disaster workers. We sought to elucidate the role of their demographics, disaster-related experiences, and post-traumatic stress symptoms on perceived WIS. We analyzed self-report questionnaires of 885 workers 2-3 months post-disaster. We used sociodemographic and disaster exposure-related variables and post-traumatic stress symptoms (measured by the Impact of Event Scale-Revised) as independent variables. We asked whether WIS from colleagues, supervisors, or subordinates was perceived as helpful, and used yes or no responses as a dependent variable. Logistic regression analyses were performed to assess correlates of WIS. Of the participants, one-third (34.7%) reported WIS. WIS was associated with younger age (20-28 years [vs 49-], adjusted odds ratio [aOR]: 3.25, 95% CI: 1.99-5.32), supervisory work status (aOR: 2.30, 95% CI: 1.35-3.92), and discrimination or slur experience (aOR: 1.65, 95% CI: 1.08-2.53). Educational programs focusing on WIS might be beneficial to promote psychological well-being among nuclear disaster workers, especially younger workers, supervisors, and workers with discrimination experiences. (Disaster Med Public Health Preparedness. 2017; page 1 of 4).

  6. The influence of calcination on the physical and chemical properties of petroleum and mixed cokes

    Energy Technology Data Exchange (ETDEWEB)

    Sikora, K; Syrek, H

    1980-01-01

    Freshly prepared petroleum and coal-petroleum cokes, before utilization for the production of various materials, are subjected to calcining--thermal treatment in a neutral or reducing atmosphere without the admission of air at less than or equal to 1400/sup 0/. During calcining, stabilization of the physical and chemical properties of the cokes takes place. The properties of the obtained coke depend chiefly on the calcining time and temperature. During calcining, volatile substances are removed almost completely from the coke; the coke density is increased, and its structure is put in order; the electrical conductivity is improved; the mechanical strength is increased; and the reactivity of the coke is decreased. Laboratory studies were conducted on calcining mixed coal-petroleum cokes of two grades at 1200, 1250, and 1300/sup 0/ for 2-6 h. In the calcining products the content of volatile substances, the ash content, S content, and density were determined. It was ascertained that calcining of mixed coal-petroleum cokes goes analogously to calcining of pure petroleum cokes. Raising the temperature and increasing the time of calcining has a substantial effect on improvement of coke physical and chemical properties. For high-quality coke, calcining is to be carried out at greater than or equal to 1300/sup 0/ for 4-6 h, for ordinary coke at > 1200/sup 0/ and greater than or equal to 4 h. The results are regarded as starting data for an industrial study of the calcining process.

  7. 40 CFR 63.302 - Standards for by-product coke oven batteries.

    Science.gov (United States)

    2010-07-01

    ... batteries. 63.302 Section 63.302 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.302 Standards for by-product coke oven batteries... oven emissions from each affected existing by-product coke oven battery that exceed any of the...

  8. 40 CFR 63.303 - Standards for nonrecovery coke oven batteries.

    Science.gov (United States)

    2010-07-01

    ... batteries. 63.303 Section 63.303 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... National Emission Standards for Coke Oven Batteries § 63.303 Standards for nonrecovery coke oven batteries... existing nonrecovery coke oven battery that exceed any of the following emission limitations or...

  9. Development of a facility for the recovery of high-purity hydrogen from coke oven gas by pressure swing adsorption

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, M; Saida, K; Uenoyama, K; Sugishita, M; Imokawa, K

    1985-01-01

    This paper reports 1) a pressure swing adsorption (PSA) system comprising three towers, each packed with three different adsorbents; and 2) studies of the application of this system to the recovery of high-purity hydrogen from coke oven gas. Running the adsorption plant at 35 C and 9.5 kg/cm/sup 2/ gives optimum operating stability and economy. In addition, an optimum time cycle for the three-tower system has been developed. Gas from the PSA equipment proper still contains traces of oxygen. This is removed in a further tower packed with Pd catalyst. The ultimate recovery of hydrogen is closely related to its concentration in the raw coke oven gas and to the degree of purity attained. 3 references.

  10. Coke detection in furnaces tubes by radiographic examination

    International Nuclear Information System (INIS)

    Santos, I.S. dos

    1987-01-01

    The coke detection technique by radiographic examinations allows to quantify the coke in furnace coils of Petroleum refineries and petrochemical industries. The paper describes how was determined the radiographic parameters, the wall apparent thickness calculation, the distance source-film, the position of the source and films, the chosen of films and the calculation of exposure time, aiming to obtain high producticity and good quality image. This technique is being used and improved for more than two years with good results. (E.G.) [pt

  11. Study of phenol extraction from coke-chemical sources

    Energy Technology Data Exchange (ETDEWEB)

    Catana, E.; Mateescu, I.; Giurcaneanu, V.; Bota, T.

    1990-09-01

    The paper presents an experimental study of the phase equilibrium in the coke-chemical tarphenols-solvent system (NaOH) solution and (phenolate solution) implied in the extraction of the phenols from coke-chemical sources. The possibility of using the phenolate solution as an extraction agent, thus making possible the improvement of the specific consumption and also simplifying the problem of the corrosion and of the waste water at the same time is presented. The influence of the solvent tar mass ratio on the selectivity of the process is discussed, this criterion being considered for establishing the conditions of the extraction. 2 figs., 7 tabs., 13 refs.

  12. Split and collectorless flotation to medium coking coal fines for multi-product zero waste concept

    Energy Technology Data Exchange (ETDEWEB)

    Dey, Shobhana; Bhattacharyya, K.K. [Mineral Processing Division, National Metallurgical Laboratory, Jamshedpur-831007 (India)

    2007-06-15

    The medium coking coal fines of - 0.5 mm from Jharia coal field were taken for this investigation. The release analysis of the composite coal reveals that yield is very low at 10.0% ash, about 25% at 14% ash and 50% at 17% ash level. The low yield is caused by the presence of high ash finer fraction. The size-wise ash analysis of - 0.5 mm coal indicated that - 0.5 + 0.15 mm fraction contains less ash than - 0.15 mm fraction. Thus, the composite feed was split into - 0.5 + 0.15 mm and - 0.15 mm fractions and subjected to flotation separately. The low ash bearing fraction (- 0.5 + 0.15 mm) was subjected to two stages collectorless flotation to achieve the concentrate with 10% ash. The cleaner concentrate (18.9%) with 10% ash was recovered which has an application in metallurgical industries. The concentrate of 30.2% yield with 12.5% ash could be achieved in one stage collectorless flotation which is suitable for use in coke making as sweetener. As the - 0.15 mm fraction contains relatively high ash, collector aided flotation using sodium silicate was performed to get a concentrate of 23.6% yield with about 17% ash. The blending of this product with cleaner tail obtained from - 0.5 + 0.15 mm produces about 35.0% yield with 17% ash and that can be utilized for coke making. The reject from the two fractions can be used for conventional thermal power plant or cement industries using a 23.5% ash after one stage collector aided flotation and the final tailings produced content ash of 61.6% can be used for fluidization combustion bed (FBC). This eventually leads to complete utilization of coal. (author)

  13. Safe meat-handling knowledge, attitudes and practices of private and government meat processing plants' workers: implications for future policy.

    Science.gov (United States)

    Adesokan, H K; Raji, A O Q

    2014-03-01

    Food-borne disease outbreaks remain a major global health challenge and cross-contamination from raw meat due to poor handling is a major cause in developing countries. Adequate knowledge of meat handlers is important in limiting these outbreaks. This study evaluated and compared the safe meat-handling knowledge, attitudes and practices (KAP) of private (PMPP) and government meat processing plants' (GMPP) workers in south-western Nigeria. This cross sectional study comprised 190 meat handlers (PMPP = 55; GMPP = 135). Data concerning their safe meat-handling knowledge, attitudes and practices as well as their socio-demographic characteristics, such as age, gender and work experience were collected. A significant association was observed between the type of meat processing plants and their knowledge (p = 0.000), attitudes (p = 0.000) and practices (p = 0.000) of safe meat-handling. Meat handlers in the GMPP were respectively, about 17 times (OR = 0.060, 95% CI: 0.018-0.203), 57 times (OR = 0.019, 95% CI: 0.007-0.054) and 111 times (OR = 0.009, 95% CI: 0.001- 0.067) less likely to obtain good knowledge, attitude and practice level of safe meat-handling than those from PMPP. Further, KAP levels were significantly associated with age group, education and work experience (p < 0.05). Study findings suggest the need for future policy in food industry in developing countries to accommodate increased involvement of private sector for improved food safety and quality delivery. Public health education on safe food handling and hygiene should be on the front burner among food handlers in general.

  14. New process of co-coking of waste plastics and blend coal

    Energy Technology Data Exchange (ETDEWEB)

    Liao, H.; Yu, G.; Zhao, P. (and others) [Shougang Technical Research Institute, Beijing (China)

    2006-07-01

    To recycle and reuse waste plastics, as well as to get a new resource of coking, co-coking process of waste plastics and blend coal has been developed by Nippon Steel. However, the ratio of waste plastics in blend coal should be limited in the range of 1% to maintain the coke strength. This paper suggested a new process of co-coking of waste plastics and blend coal. The new process can add the waste plastics ratio up to 2-4%; when the waste plastics ratio is 2%, the coke strength after reaction with CO{sub 2} (CSR) increased 8%. 8 refs., 2 figs., 3 tabs.

  15. Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas

    Energy Technology Data Exchange (ETDEWEB)

    V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15

    The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

  16. Dose assessment following an overexposure of a worker at a Swiss nuclear power plant.

    Science.gov (United States)

    Bailat, Claude J; Laedermann, Jean-Pascal; Baechler, Sébastien; Desorgher, Laurent; Aroua, Abbas; Bochud, François O

    2017-12-01

    The aim of this work was to assess the doses received by a diver exposed to a radiation source during maintenance work in the fuel transfer pool at a Swiss nuclear power plant, and to define whether the statutory limit was breached or not. Onsite measurements were carried out and different scenarios were simulated using the MicroShield Software and the MCNPX Monte Carlo radiation transport code to estimate the activity of the irradiating object as well as the doses to the limbs and the effective dose delivered to the operator. The activity of the object was estimated to 1.8 TBq. From the various dose estimations, a conservative value of 7.5 Sv was proposed for the equivalent dose to the skin on the hands and an effective dose of 28 mSv. The use of different experimental and calculation methods allowed us to accurately estimate the activity of the object and the dose delivered to the diver, useful information for making a decision on the most appropriate scheme of follow up for the patient.

  17. Application of the Alara principle to the occupationally exposed workers in nuclear power plants

    International Nuclear Information System (INIS)

    Mueller, W.; Haider, G.

    1988-01-01

    This report sets down how the Alara (as low as reasonably achievable) principle is applied in radiation protection of the occupationally exposed personnel at light-water reactors in EC countries. In some instances the practices, experiences and results from EC countries are supplemented by the practice in other States (e.g. USA, Sweden). Commencing with a short summary of the legal situation in the Member States of the European Community with regard to Alara, the report describes the framework in which the optimization practice has been developed. The main chapters elaborate in detail how the Alara principle has been put into practice in design and operation in LWRs. The importance of qualification and training of power-plant personnel in relation to optimization of radiation protection is considered and some comparisons are drawn with the US practice. Recommendations are made where reason for modification or harmonization of practices is seen in the conclusions of the different chapters and the overall conclusions and summary of the report

  18. Planning of occupational dose reduction at BWR power plant by past dose record analysis combined with on-site workers' idea analysis

    International Nuclear Information System (INIS)

    Konno, T.; Taira, J.; Hayashida, T.; Suzuki, A.; Hayashi, K.; Kato, S.; Ishikawa, T.; Konno, T.; Hayashi, K.

    2011-01-01

    In order to establish a plan for occupational dose reduction at operating plants, outage inspection works that involve high-dose exposure were selected and a determination of the major causes of high-dose exposure made by plant-by-plant comparison of doses received during inspection works. The comparison was made to investigate the relationship between exposure and the volume of objects to be inspected, working time and man-hour of each work process and ambient dose rates at work areas. In parallel with this, an analysis has also been carried out on 400 data items in a questionnaire survey conducted on relevant individuals, including foremen, radiation safety personnel, on-site workers and plant designers regarding ideas for dose reduction methods. With combination of these two analyses, matters that require improvement will be highlighted, then modification of equipment or revision of work procedures necessary for occupational dose reduction will be planned by plant designers through review. (authors)

  19. Use of a palladium catalyst in the purification of coke oven gas

    Energy Technology Data Exchange (ETDEWEB)

    Gotoh, T; Nakamura, M; Hirooka, N

    1986-01-01

    In the production of hydrogen from coke oven gas (COG) by pressure swing adsorption (PSA), various impurities in the COG have to be removed prior to the PSA. The stages of this purification are as follows: 1) removal of polymerizable substances such as NO gum by compressing the COG and then feeding it through a hot bottle and cooler arrangement; 2) removal of BTX in a scrubber; 3) removal of naphthalene and mist by means of chillers and filters; 4) removal of oxygen in a special reactor using a Pd catalyst. These various purification treatments have enabled the PSA plant to operate smoothly for 3.5 years. The authors report the results of pilot plant tests, and compare the results obtained using alternative purification techniques. 4 figures, 5 tables.

  20. Practical aspects of coking in Cundinamarca y Boyacá

    Directory of Open Access Journals (Sweden)

    Segundo Manuel Romero-Balaguera

    2014-12-01

    Full Text Available Taking advantage of the excellent qualities of the studied coals from the coalfields in Cundinamarca and terms of the types of coking ovens, for excellent performance and quality that allows them to be very competitive.The international market is very demanding in terms of the quality of coke and CRI and CSR indexes, that is why coals laboratories were implemented and improved the system of sampling and analysis of laboratories for more agile and modern. Mixtures were made with the test methodology and empirical methods combining swelling index and rank cals were the theree main types: high, medium and low volatile. But with studies and techological change and enviromental control, process is managed, allowing the coke industry to serve as a development center for the promotion of industries in the central area of this country. In the study the whole process is presented beginning with the explotaitation of coking coals, the care that must be taken into account to mainttain good quality, transport and enviromental measures, the process of crushing and grinding to prepare the optimal mix and laboratory tests necessary to maintain quality control, the types of ovens in Boyacá Colombia, yields and advances in the se technologies, and finally, the system shutdown process. All of the above was addressed in order to add value to the product with the fulfillment of the international market standards.

  1. Refractory compounds for repairing coke-oven brickwork

    Energy Technology Data Exchange (ETDEWEB)

    Hanganu, M.; Dragomir, C. (and others)

    1984-01-01

    A number of refractory compounds are presented, based on aluminium phosphate, phosphoric acid, sodium silicate and fire-clay and mullitic zirconium mastic, including their composition, properties and application (by impregnation, spray application or pouring), which are suitable for repairing various types of coke-oven brickwork. The results obtained are given.

  2. The development of coke smelting and the industrial revolution

    OpenAIRE

    Macfarlane, Alan

    2004-01-01

    Abraham Darby and the origins of the industrial revolution in Britain. Alan Macfarlane talks to John about the reasons for the area near Birmingham becoming the epi-centre of the industrial development, and the development of coke furnaces and iron smelting.

  3. Retort for coking peat, brown coal, bituminous shale, etc

    Energy Technology Data Exchange (ETDEWEB)

    1902-05-14

    The retort leads the gases and vapors into the coking chamber, between the inside heater and the outer heating shaft-wall. Over-lapping, double-faced acting rings are arranged, over which the charge in two or more separate vertical layers is transported.

  4. Continuous moisture measurement in metallurgical coke with automatic charge correction

    International Nuclear Information System (INIS)

    Watzke, H.; Mehlhose, D.

    1981-01-01

    A process control system has been developed for automatic batching of the coke amount necessary for metallurgical processes taking into account the moisture content. The measurement is performed with a neutron moisture gage consisting of an Am-Be neutron source and a BF 3 counter. The output information of the counter is used for computer-controlled batching

  5. Process for converting coal into liquid fuel and metallurgical coke

    Science.gov (United States)

    Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  6. modelling and modelling and simulation of coking in the riser

    African Journals Online (AJOL)

    eobe

    into the modeling of FCC riser by predicting catalyst coke content as a function of reaction by predicting ... understanding of the process, hence restricting scale up to within the ... MATLAB (R2009a) on a Compaq HP CQ61 laptop. The following ...

  7. Acute respiratory effects on workers exposed to metalworking fluid aerosols in an automotive transmission plant.

    Science.gov (United States)

    Robins, T; Seixas, N; Franzblau, A; Abrams, L; Minick, S; Burge, H; Schork, M A

    1997-05-01

    Exposure to metalworking fluids has been linked to modest cross-shift reductions in FEV1 and occupational asthma. To identify responsible agents, we measured personal exposures to thoracic particulate (TP), viable plus nonviable thoracic bacteria (BAC), and vapor phase nicotine (VPN) (as a surrogate for tobacco particulate) among 83 machinists exposed to soluble oils and 46 dry assemblers working in an automotive transmission machining plant using biocides infrequently. The participants completed interviews and performed pre- and postshift spirometry on Monday and Thursday of the same week in each of three rounds of data collection (June 1992, January 1993, June 1993). Generalized estimating equations were used to combine information across rounds in multiple regression models of cross-shift and cross-week changes in forced expiratory volume, I second (FEV1) and forced vital capacity (FVC). Mean seniority was 19 years among machinists. Mean personal TP levels were 0.41 mg/m3 in machinists and 0.13 mg/m3 in assemblers. Six of the 83 machinists and none of the 46 assemblers experienced a greater than 19% cross-shift decrement in FEV1 or FVC at least once (p = .07). In regression models using either TP or BAC, among subjects with lower baseline (Monday preshift) FEV1/FVC ratios, increasing exposure was significantly associated with increasing cross-shift decrements in FEV1 and FVC in linear models, and with increased likelihood of a 10% or greater cross-shift decrement in FEV1 or FVC in logistic models. Adjustment of TP for VPN did not affect models significantly. We conclude that clinically important cross-shift decrements in pulmonary function are associated with exposure to metalworking fluid aerosols within a high-seniority population.

  8. A review of cancer mortality data of radiation workers of Nuclear Power Plant, Paks, Hungary, in the light the international radiation epidemiology study

    International Nuclear Information System (INIS)

    Turai, I.; Kerekes, A.; Otos, M.; Veress, K.

    2007-01-01

    Complete text of publication follows. Objective: To give a review of cancer mortality data among Hungarian radiation workers in nuclear industry in comparison with the results of the international nuclear workers' study prevailing the size of the study group of all former studies. Methods: Retrospective cohort study including 598,068 workers of 154 nuclear establishments in 15 countries (AUS, BEL, CAN, FIN, FRA, GER, HUN, JAP, LIT, ROK, SLK, SPA, SWE, UK, USA) coordinated by the International Agency for Research on Cancer (IARC, Lyon, France). The national study was extended for an additional 4-year period. Results: In the international study 407,391 persons in 13 years of average employment received 19.4 mSv mean cumulative dose, while in the national study 3322 radiation workers of Nuclear Power Plant (NPP) Paks, Hungary, in 14 years of follow-up period accumulated in average 5.13 mSv, only. There were 5233 cancer deaths registered in the international study, associated with an estimated ERR of 0.97 per Sv. Thus, 19.4 mSv recorded cumulative dose can explain 1 to 2% of cancer death cases. In radiation workers of NPP, Paks, during the period of 1985-1998 there were 40 cancer deaths observed against the expected 58.8 cases. In a further four year period (1999-2002) 29 cancer death cases were identified vs. the expected 65.5 cases. The SMR for the cancer death cases registered in recent and former radiation workers of NPP, Paks in the 18-year follow-up period is 56%. The SMR from all causes was even lower, 40% only. Conclusions: In the international study the mean accumulated radiation dose received by nuclear workers in 13 years is below of the recent annual dose limit (20 mSv/yr of the effective dose). The average value for the whole of radiation workers in 15 countries is almost 4-times higher of that registered in Hungary. The 'healthy worker effect' in the nuclear industry, and particularly in Hungary has been proven, once again. Nevertheless, the results

  9. Study of variation grain size in desulfurization process of calcined petroleum coke

    Science.gov (United States)

    Pintowantoro, Sungging; Setiawan, Muhammad Arif; Abdul, Fakhreza

    2018-04-01

    Indonesia is a country with abundant natural resources, such as mineral mining and petroleum. In petroleum processing, crude oil can be processed into a source of fuel energy such as gasoline, diesel, oil, petroleum coke, and others. One of crude oil potentials in Indonesia is petroleum coke. Petroleum coke is a product from oil refining process. Sulfur reducing process in calcined petroleum cokes can be done by desulfurization process. The industries which have potential to become petroleum coke processing consumers are industries of aluminum smelting (anode, graphite block, carbon mortar), iron riser, calcined coke, foundry coke, etc. Sulfur reducing process in calcined petroleum coke can be done by thermal desulfurization process with alkaline substance NaOH. Desulfurization of petroleum coke process can be done in two ways, which are thermal desulfurization and hydrodesulphurization. This study aims to determine the effect of various grain size on sulfur, carbon, and chemical bond which contained by calcined petroleum coke. The raw material use calcined petroleum coke with 0.653% sulfur content. The grain size that used in this research is 50 mesh, then varied to 20 mesh and 100 mesh for each desulfurization process. Desulfurization are tested by ICP, UV-VIS, and FTIR to determine levels of sulfur, carbon, chemical bonding and sulfur dissolved water which contained in the residual washing of calcined petroleum coke. From various grain size that mentioned before, the optimal value is on 100 mesh grain size, where the sulfur content in petroleum coke is 0.24% and carbon content reaches the highest level of 97.8%. Meanwhile for grain size 100 mesh in the desulfurization process is enough to break the chemical bonds of organic sulfur in petroleum coke.

  10. Management system in the dose assessment due to the intake of "1"3"1I in occupationally exposed workers (OEW) in a radioisotope production plant

    International Nuclear Information System (INIS)

    Koga, Roberto; Jara, Raul; Defilippi, Luis; Osores, Jose

    2015-01-01

    This article presents the evaluation and management processes due to the incorporation of "1"3"1I in occupationally exposed workers (OEW) of a Radioisotope Production Plant by in vivo measurement of the retained activity of this radionuclide in thyroid. The procedures for the occupational control of the OWE were established, including intermediate checks and calibration of the equipment according to the NTP ISO/IEC 17025:2006 standard. (author)

  11. Electrical conductivity of the screening residuals of coke production in context of ferrochromium production in a submerged arc furnace

    Energy Technology Data Exchange (ETDEWEB)

    Rousu, Arto; Mattila, Olli [Lab. of Process Metallurgy, Univ. of Oulu (Finland)

    2009-11-15

    Coke is used as a reducing agent in the production of ferrochromium in a submerged arc furnace (SAF). Its good electrical conductivity compared to other input materials makes it a dominant current conductivity substance in the burden. The resistance of the coke has to be high enough to ensure the proper functionality of the furnace. Used cokes for submerged arc furnace production are relatively small in size compared to e.g. blast furnace (BF) cokes. A common practice is to use screening residual coke, which is too small for the BF, in SAF. The goal of this study was to show differences in the electrical properties of screening residual cokes compared to coke formed in different parts of the coke battery, in dependence of particle size. The resistances of different cokes were measured and XRD measurements were performed to define the crystallographic structure of the selected cokes. The results indicate that small coke particles have higher overall resistance, which is due to their internal properties. This small weakly carbonized coke is formed in the middle of the coking battery and is subject to changes in varying coking practices. Continuous quality control of screening residual coke is needed to use it in the SAF. (orig.)

  12. Geochemical characteristics of oil sands fluid petroleum coke

    International Nuclear Information System (INIS)

    Nesbitt, Jake A.; Lindsay, Matthew B.J.; Chen, Ning

    2017-01-01

    The geochemical characteristics of fluid petroleum coke from the Athabasca Oil Sands Region (AOSR) of northern Alberta, Canada were investigated. Continuous core samples were collected to 8 m below surface at several locations (n = 12) from three coke deposits at an active oil sands mine. Bulk elemental analyses revealed the coke composition was dominated by C (84.2 ± 2.3 wt%) and S (6.99 ± 0.26 wt%). Silicon (9210 ± 3000 mg kg"−"1), Al (5980 ± 1200 mg kg"−"1), Fe (4760 ± 1200 mg kg"−"1), and Ti (1380 ± 430 mg kg"−"1) were present in lesser amounts. Vanadium (1280 ± 120 mg kg"−"1) and Ni (230 ± 80 mg kg"−"1) exhibited the highest concentrations among potentially-hazardous minor and trace elements. Sequential extractions revealed potential for release of these metals under field-relevant conditions. Synchrotron powder X-ray diffraction revealed the presence of Si and Ti oxides, organically-complexed V and hydrated Ni sulfate, and provided information about the asphaltenic carbon matrix. X-ray absorption near edge structure (XANES) spectroscopy at the V and Ni K-edges revealed that these metals were largely hosted in porphyrins and similar organic complexes throughout coke grains. Minor differences among measured V and Ni K-edge spectra were largely attributed to slight variations in local coordination of V(IV) and Ni(II) within these organic compounds. However, linear combination fits were improved by including reference spectra for inorganic phases with octahedrally-coordinated V(III) and Ni(II). Sulfur and Fe K-edge XANES confirmed that thiophenic coordination and pyritic-ilmenitic coordination are predominant, respectively. These results provide new information on the geochemical and mineralogical composition of oil sands fluid petroleum coke and improve understanding of potential controls on associated water chemistry. - Highlights: • Oil sands fluid petroleum coke contains wide range of major, minor and

  13. Characterization of norm sources in petroleum coke calcining processes - 16314

    International Nuclear Information System (INIS)

    Hamilton, Ian S.; Halter, Donald A.; Fruchtnicht, Erich H.; Arno, Matthew G.; Haumann, Donald F

    2009-01-01

    Petroleum coke, or 'petcoke', is a waste by-product of the oil refining industry. The majority of petcoke consumption is in energy applications; catalyst coke is used as refinery fuel, anode coke for electricity conduction, and marketable coke for heating cement kilns. Roskill has predicted that long-term growth in petroleum coke production will be maintained, and may continue to increase slightly through 2012. Petcoke must first be calcined to drive off any undesirable petroleum by-products that would shorten the coke product life cycle. As an example, the calcining process can take place in large, rotary kilns heated to maximum temperatures as high as approximately 1400-1540 deg. C. The kilns and combustion/settling chambers, as well as some cooler units, are insulated with refractory bricks and other, interstitial materials, e.g., castable refractory materials, to improve the efficiency of the calcining process. The bricks are typically made of 70-85-percent bauxite, and are slowly worn away by the calcining process; bricks used to line the combustion chambers wear away, as well, but at a slower rate. It has been recognized that the refractory materials contain slight amounts of naturally occurring radioactive materials (NORM) from the uranium- and thorium-decay series. Similarly, low levels of NORM could be present in the petcoke feed stock given the nature of its origin. Neither the petcoke nor the refractory bricks represent appreciable sources of radiation or radioactive waste. However, some of the demolished bricks that have been removed from service because of the aforementioned wearing process have caused portal alarms to activate at municipal disposal facilities. This has lead to the current investigation into whether there is a NORM concentrating mechanism facilitated by the presence of the slightly radioactive feed stock in the presence of the slightly radioactive refractory materials, at calcining-zone temperatures. Research conducted to date has been

  14. Associations between disaster exposures, peritraumatic distress, and posttraumatic stress responses in Fukushima nuclear plant workers following the 2011 nuclear accident: the Fukushima NEWS Project study.

    Directory of Open Access Journals (Sweden)

    Jun Shigemura

    Full Text Available BACKGROUND: The 2011 Fukushima Daiichi Nuclear Power Plant accident was the worst nuclear disaster since Chernobyl. The nearby Daini plant also experienced substantial damage but remained intact. Workers for the both plants experienced multiple stressors as disaster victims and workers, as well as the criticism from the public due to their company's post-disaster management. Little is known about the psychological pathway mechanism from nuclear disaster exposures, distress during and immediately after the event (peritraumatic distress; PD, to posttraumatic stress responses (PTSR. METHODS: A self-report questionnaire was administered to 1,411 plant employees (Daiichi, n = 831; Daini, n = 580 2-3 months post-disaster (total response rate: 80.2%. The socio-demographic characteristics and disaster-related experiences were assessed as independent variables. PD and PTSR were measured by the Japanese versions of Peritraumatic Distress Inventory and the Impact of Event Scale-Revised, respectively. The analysis was conducted separately for the two groups. Bivariate regression analyses were performed to assess the relationships between independent variables, PD, and PTSR. Significant variables were subsequently entered in the multiple regression analyses to explore the pathway mechanism for development of PTSR. RESULTS: For both groups, PTSR highly associated with PD (Daiichi: adjusted β, 0.66; p<0.001; vs. Daini: adjusted β, 0.67; p<0.001. PTSR also associated with discrimination/slurs experience (Daiichi: 0.11; p<0.001; vs. Daini, 0.09; p = 0.005 and presence of preexisting illness(es (Daiichi: 0.07; p = 0.005; vs. Daini: 0.15; p<.0001. Other disaster-related variables were likely to be associated with PD than PTSR. CONCLUSION: Among the Fukushima nuclear plant workers, disaster exposures associated with PD. PTSR was highly affected by PD along with discrimination/slurs experience.

  15. Radiation occupational health interventions offered to radiation workers in response to the complex catastrophic disaster at the Fukushima Daiichi Nuclear Power Plant.

    Science.gov (United States)

    Shimura, Tsutomu; Yamaguchi, Ichiro; Terada, Hiroshi; Okuda, Kengo; Svendsen, Erik Robert; Kunugita, Naoki

    2015-05-01

    The Fukushima Daiichi Nuclear Power Plant (NPP) 1 was severely damaged from the chain reaction of the Great East Japan Earthquake and Tsunami on 11 March 2011, and the consequent meltdown and hydrogen gas explosions. This resulted in the worst nuclear accident since the Chernobyl accident of 1986. Just as in the case of Chernobyl, emergency workers were recruited to conduct a wide range of tasks, including disaster response, rescuing activities, NPP containment, and radiation decontamination. This paper describes the types and efficacy of the various occupational health interventions introduced to the Fukushima NPP radiation workers. Such interventions were implemented in order to prevent unnecessary radiation overexposure and associated adverse health effects and work injuries. Less than 1% of all emergency workers were exposed to external radiation of >100 mSv, and to date no deaths or health adversities from radiation have been reported for those workers. Several occupational health interventions were conducted, including setting of new regulatory exposure limits, improving workers' radiation dosimetry, administration of stable iodine, running an occupational health tracking system, and improving occupational medicine and preventative care. Those interventions were not only vital for preventing unnecessary radiation, but also for managing other general health issues such as mental health, heat illness and infectious diseases. Long-term administration of the aforementioned occupational health interventions is essential to ensure the ongoing support and care for these workers, who were put under one of the most severe occupational health risk conditions ever encountered. © The Author 2014. Published by Oxford University Press on behalf of The Japan Radiation Research Society and Japanese Society for Radiation Oncology.

  16. Granulation of coke breeze fine for using in the sintering process

    Directory of Open Access Journals (Sweden)

    Mohamed F.M.

    2010-01-01

    Full Text Available Coke breeze is the main fuel used in the sintering process. The value of -3+1 mm. represents the most favorable particle size for coke breeze in the sintering process. About 20% of total coke fines (-0.5 mm are produced during different steps of preparation. Introducing these fines during the sintering process proves to be very harmful for different operating parameters. Thus ,this study aims at investigating the production of granules resulting from these fines using molasses as organic binder and its application in sintering of an iron ore. The results showed that the granules having the highest mechanical properties were obtained with 14.5 wt % molasses addition. The sintering experiments were performed by using coke breeze in different shapes (-3+1 mm in size, coke breeze without sieving and coke breeze granules -3+1 mm. The reduction experiments, microscopic structure and X-ray analysis for the produced sinter were carried out. The results revealed that, all sinter properties (such as shatter test, productivity of sinter machine and blast furnace, reduction time and chemical composition for produced sinter by using coke breeze with size -3+1 mm and coke breeze granules were almost the same. The iron ore sinter which was produced by using coke breeze without sieving yielded low productivity for both sinter machine and blast furnace. Furthermore, using coke breeze without sieving in sintering of an iron ore decreases the vertical velocity of sinter machine and increases the reduction time.

  17. Quantification of mineral matter in commercial cokes and their parent coals

    Energy Technology Data Exchange (ETDEWEB)

    Sakurovs, Richard; French, David; Grigore, Mihaela [CRC for Coal in Sustainable Development, CSIRO Energy Technology, PO Box 330 Newcastle 2300 (Australia)

    2007-10-01

    The nature of mineral matter in coke is an important factor in determining the behaviour of coke in the blast furnace. However, there have been few quantitative determinations of the types of mineral matter in coke and the feed coal. Here we use a technique of quantitative X-ray diffraction - SIROQUANT trademark - to determine the nature and quantity of mineral matter in eleven cokes and their parent materials, using samples of coals and their cokes utilised commercially in blast furnaces around the world. In some of these coals a considerable proportion of the phosphorus was present as goyazite, an aluminium phosphate. In the cokes, most of the iron was incorporated into amorphous aluminosilicate material; metallic iron accounted for about 15% of the iron present, and a similar amount was present as sulfides. Potassium and sodium were largely present as amorphous aluminosilicate material. Most of the quartz in the coal was unaffected by the coking, but a small fraction was transformed into other minerals. Quartz is not completely inert during coking. The amount of the catalytic forms of iron in the coke - iron, iron oxides and iron sulfides - was not related to the amount of pyrite and siderite in the starting coal, indicating that estimation of catalytic iron requires investigation of the mineral matter in coke directly and cannot be estimated from the minerals in the coal. (author)

  18. Modelling of Coke Layer Collapse during Ore Charging in Ironmaking Blast Furnace by DEM

    Science.gov (United States)

    Narita, Yoichi; Mio, Hiroshi; Orimoto, Takashi; Nomura, Seiji

    2017-06-01

    A technical issue in an ironmaking blast furnace operation is to realize the optimum layer thickness and the radial distribution of burden (ore and coke) to enhance its efficiency and productivity. When ore particles are charged onto the already-embedded coke layer, the coke layer-collapse phenomenon occurs. The coke layer-collapse phenomenon has a significant effect on the distribution of ore and coke layer thickness in the radial direction. In this paper, the mechanical properties of coke packed bed under ore charging were investigated by the impact-loading test and the large-scale direct shear test. Experimental results show that the coke particle is broken by the impact force of ore charging, and the particle breakage leads to weaken of coke-layer strength. The expression of contact force for coke in Discrete Element Method (DEM) was modified based on the measured data, and it followed by the 1/3-scaled experiment on coke's collapse phenomena. Comparing a simulation by modified model to the 1/3-scaled experiment, they agreed well in the burden distribution.

  19. Respiratory health status and its predictors: a cross-sectional study among coal-based sponge iron plant workers in Barjora, India.

    Science.gov (United States)

    Chattopadhyay, Kaushik; Chattopadhyay, Chaitali; Kaltenthaler, Eva

    2015-03-20

    During the past decade, coal-based sponge iron plants, a highly polluted industry, have grown rapidly in Barjora, India. The toxic effects of particulate matters and gaseous pollutants include various respiratory diseases. Understanding workers' perception of respiratory health is essential in people-centred healthcare. The aim of the study was to assess their respiratory health status and to determine its predictors. Cross-sectional study. Coal-based sponge iron plants in Barjora, India. 258 coal-based sponge iron plant workers. Respiratory health status was measured using the St. George's respiratory questionnaire (SGRQ) total score. 100 and 0 represent the worst and best possible respiratory health status, respectively. The two-part model (frequency (any worse respiratory health status) and severity (amount of worse respiratory health status)) was developed for the score, as the data were positively skewed with many zeros. The mean (SD) SGRQ total score was 7.7 (14.5), the median (IQR) was 0.9 (9.0), and the observed range was 0-86.6. The best possible SGRQ total score was reported by 46.9% of workers. Independent predictors of worse respiratory health status were cleaner domestic cooking fuel (coefficient -0.76, 95% CI -1.46 to -0.06, p=0.034) and personal history of any respiratory disease (1.76, 1.04 to 2.47, pworkers in Barjora have the best possible respiratory health status. The predictors of worse respiratory health status were identified. The study findings could be taken into consideration in future interventional studies aimed at improving the respiratory health status of these workers. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

  20. Self-assessment of hearing status and risk of noise-induced hearing loss in workers in a rolling stock plant.

    Science.gov (United States)

    Pawlaczyk-Łuszczyńska, Małgorzata; Dudarewicz, Adam; Zamojska, Małgorzata; Sliwinska-Kowalska, Mariola

    2012-01-01

    Noise measurements and questionnaire inquiries were carried out for 124 workers of a rolling stock plant to develop a hearing conservation program. On the basis of that data, the risk of noise-induced hearing loss (NIHL) was evaluated. Additionally, the workers' hearing ability was assessed with the (modified) Amsterdam inventory for auditory disability and handicap, (m)AIADH. The workers had been exposed to noise at A-weighted daily noise exposure levels of 74-110 dB for 1-40 years. Almost one third of the workers complained of hearing impairment and the (m)AIADH results showed some hearing difficulties in over half of them. The estimated risk of hearing loss over 25 dB in the frequency range of 3-6 kHz was 41-50% when the standard method of predicting NIHL specified in Standard No. ISO 1999:1990 was used. This risk increased to 50-67% when noise impulsiveness, coexposure to organic solvents, elevated blood pressure and smoking were included in calculations.

  1. Heat input control in coke ovens battery using artificial intelligence

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, R.; Kannan, C.; Sistla, S.; Kumar, D. [Tata Steel, Jamshedpur (India)

    2005-07-01

    Controlled heating is very essential for producing coke with certain desired properties. Controlled heating involves controlling the heat input into the battery dynamically depending on the various process parameters like current battery temperature, the set point of battery temperature, moisture in coal, ambient temperature, coal fineness, cake breakage etc. An artificial intelligence (AI) based heat input control has been developed in which currently some of the above mentioned process parameters are considered and used for calculating the pause time which is applied between reversal during the heating process. The AI based model currently considers 3 input variables, temperature deviation history, current deviation of the battery temperature from the target temperature and the actual heat input into the battery. Work is in progress to control the standard deviation of coke end temperature using this model. The new system which has been developed in-house has replaced Hoogovens supplied model. 7 figs.

  2. Composition and method for coke retardant during hydrocarbon processing

    International Nuclear Information System (INIS)

    Reid, D.K.

    1988-01-01

    A process is described for inhibiting the formation and deposition of filamentous coke on metallic surfaces in contact with a hydrocarbon having a temperature of 600 0 -1300 0 F which comprises adding to the hydrocarbon a sufficient amount for the purpose of a boron compound selected from the group of boron oxide compounds, boric acid and metal borides, with the proviso that when boric acid is used, it is substantially free of water

  3. Understanding the mechanisms behind coking pressure: Relationship to pore structure

    Energy Technology Data Exchange (ETDEWEB)

    John J. Duffy; M. Castro Diaz; Colin E. Snape; Karen M. Steel; Merrick R. Mahoney [University of Nottingham, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

    2007-09-15

    Three low volatile coals A, B and C with oven wall pressures of 100 kPa, 60 kPa and 20 kPa respectively were investigated using high-temperature rheometry, {sup 1}H NMR, thermogravimetric analysis and SEM, with the primary aim to better understand the mechanisms behind the coking pressure phenomenon. Rheometer plate displacement measurements ({Delta}L) have shown differences in the expansion and contraction behaviour of the three coals, which seem to correlate with changes in rheological properties; while SEM images have shown that the expansion process coincides with development of pore structure. It is considered that the point of maximum plate height ({Delta}L{sub max}) prior to contraction may be indicative of a cell opening or pore network forming process, based on analogies with other foam systems. Such a process may be considered important for coking pressure since it provides a potential mechanism for volatile escape, relieving internal gas pressure and inducing charge contraction. For coal C, which has the highest fluidity {delta}L{sub max} occurs quite early in the softening process and consequently a large degree of contraction is observed; while for the lower fluidity coal B, the process is delayed since pore development and consequently wall thinning progress at a slower rate. When {Delta}L{sub max} is attained, a lower degree of contraction is observed because the event occurs closer to resolidification where the increasing viscosity/elasticity can stabilise the expanded pore structure. For coal A which is relatively high fluidity, but also high coking pressure, a greater degree of swelling is observed prior to cell rupture, which may be due to greater fluid elasticity during the expansion process. This excessive expansion is considered to be a potential reason for its high coking pressure. 58 refs., 15 figs., 1 tab.

  4. Combined XRD and Raman studies of coke types found in SAPO-34 after methanol and propene conversion

    DEFF Research Database (Denmark)

    Wragg, David S.; Grønvold, Arne; Voronov, Alexey

    2013-01-01

    oligomerisation (PO) reactions. The coke caused by MTO leads to two distinct sets of HRPD peaks which can be indexed by two SAPO-34 unit cells with different lattice parameters and coke contents. We believe that these unit cells represent different zones of the catalyst filled with different coke types. PO coking...... does not lead to splitting of the diffraction peaks. Raman spectra show differences between the coke types produced by MTO and PO with the same overall trend of increasingly polyaromatic coke with increasing coke mass. The intensity of the monocyclic and polyaromatic peaks in the MTO Raman spectra...... correspond to the phase fractions of the two cell types used in the Rietveld refinement, suggesting a link between the two phases and the two coke types. The PO Raman spectra have a stronger polyaromatic band at low coke, suggesting that polyaromatics form faster. In situ powder XRD studies suggest...

  5. Mortality among 24,865 workers exposed to polychlorinated biphenyls (PCBs) in three electrical capacitor manufacturing plants: A ten-year update

    Science.gov (United States)

    Ruder, Avima M.; Hein, Misty J.; Hopf, Nancy B.; Waters, Martha A.

    2015-01-01

    The objective of this analysis was to evaluate mortality among a cohort of 24,865 capacitor-manufacturing workers exposed to polychlorinated biphenyls (PCBs) at plants in Indiana, Massachusetts, and New York and followed for mortality through 2008. Cumulative PCB exposure was estimated using plant-specific job-exposure matrices. External comparisons to US and state-specific populations used standardized mortality ratios, adjusted for gender, race, age and calendar year. Among long-term workers employed 3 months or longer, within-cohort comparisons used standardized rate ratios and multivariable Poisson regression modeling. Through 2008, more than one million person-years at risk and 8749 deaths were accrued. Among long-term employees, all-cause and all-cancer mortality were not elevated; of the a priori outcomes assessed only melanoma mortality was elevated. Mortality was elevated for some outcomes of a priori interest among subgroups of long-term workers: all cancer, intestinal cancer and amyotrophic lateral sclerosis (women); melanoma (men); melanoma and brain and nervous system cancer (Indiana plant); and melanoma and multiple myeloma (New York plant). Standardized rates of stomach and uterine cancer and multiple myeloma mortality increased with estimated cumulative PCB exposure. Poisson regression modeling showed significant associations with estimated cumulative PCB exposure for prostate and stomach cancer mortality. For other outcomes of a priori interest – rectal, liver, ovarian, breast, and thyroid cancer, non-Hodgkin lymphoma, Alzheimer disease, and Parkinson disease – neither elevated mortality nor positive associations with PCB exposure were observed. Associations between estimated cumulative PCB exposure and stomach, uterine, and prostate cancer and myeloma mortality confirmed our previous positive findings. PMID:23707056

  6. Mortality among 24,865 workers exposed to polychlorinated biphenyls (PCBs) in three electrical capacitor manufacturing plants: a ten-year update.

    Science.gov (United States)

    Ruder, Avima M; Hein, Misty J; Hopf, Nancy B; Waters, Martha A

    2014-03-01

    The objective of this analysis was to evaluate mortality among a cohort of 24,865 capacitor-manufacturing workers exposed to polychlorinated biphenyls (PCBs) at plants in Indiana, Massachusetts, and New York and followed for mortality through 2008. Cumulative PCB exposure was estimated using plant-specific job-exposure matrices. External comparisons to US and state-specific populations used standardized mortality ratios, adjusted for gender, race, age and calendar year. Among long-term workers employed 3 months or longer, within-cohort comparisons used standardized rate ratios and multivariable Poisson regression modeling. Through 2008, more than one million person-years at risk and 8749 deaths were accrued. Among long-term employees, all-cause and all-cancer mortality were not elevated; of the a priori outcomes assessed only melanoma mortality was elevated. Mortality was elevated for some outcomes of a priori interest among subgroups of long-term workers: all cancer, intestinal cancer and amyotrophic lateral sclerosis (women); melanoma (men); melanoma and brain and nervous system cancer (Indiana plant); and melanoma and multiple myeloma (New York plant). Standardized rates of stomach and uterine cancer and multiple myeloma mortality increased with estimated cumulative PCB exposure. Poisson regression modeling showed significant associations with estimated cumulative PCB exposure for prostate and stomach cancer mortality. For other outcomes of a priori interest--rectal, liver, ovarian, breast, and thyroid cancer, non-Hodgkin lymphoma, Alzheimer disease, and Parkinson disease--neither elevated mortality nor positive associations with PCB exposure were observed. Associations between estimated cumulative PCB exposure and stomach, uterine, and prostate cancer and myeloma mortality confirmed our previous positive findings. Published by Elsevier GmbH.

  7. Nickel and vanadium extraction from the Syrian petroleum coke

    International Nuclear Information System (INIS)

    Shlewit, H.; Alibrahim, M.

    2007-01-01

    Syrian petroleum coke samples were characterized and submitted for salt-roasting treatment in electric furnace to evaluate the convenience of this procedure for the extraction of the vanadium, nickel and sulfur from coke. Both solution and solid residue remaining after salt roasting were separated by filtration and were analyzed for vanadium, nickel and sulfur. The solution was analyzed by UV-Visible spectroscopy for vanadium and nickel and gravimetrically for sulfur. The solid residue and the untreated samples of petroleum coke were analyzed by XRF spectrometry. Results showed that more than 90% of sulfur and 60% of vanadium could be extracted by salt roasting treatment. An alternative procedure has been suggested, in which, more than 80% of sulfur and small percentage of vanadium can be leached by 0.75 M of Na 2 CO 3 solution at 70-80 Co. Vanadium was selectively extracted by DEHPA/TBP from the loaded leached solution. The extraction procedure flowsheet was also suggested. (authors)

  8. Denitrification of coking wastewater with micro-electrolysis.

    Science.gov (United States)

    Lv, Yanli; Wang, Yanqiu; Shan, Mingjun; Shen, Xue; Su, Ying

    2011-06-01

    The denitrification for the coking wastewater was conducted by means of original battery principle with Fe-C micro-electrolysis. Fe-C serves as positive and negative electrodes, by which N02(-)-N and TN were reduced to nitrogen, and then the purpose of denitrifieation for coking wastewater was realized. The influences of pH value, carbon particle size, Fe/C ratio (mass ratio), reaction time and coagulation pH value on removal rate of N02(-)-N and TN were investigated. Coking wastewater originated from Jiamusi Coal Chemistry Engineering Company. The optimum conditions of treatment were as follows: the initial pH was 3.0, the dosage of Fe 73.5 g/L, reaction time 70 min, mass ratio of Fe/C ratio 1.0:1.3, coagulation pH 9.0 and sedimentation time 40 min. Under those conditions, nitrogen removal efficiencies of N02(-)-N and TN were beyond 50% and 45%, respectively. Copyright © 2011 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

  9. An additive for a petroleum coke and water suspension

    Energy Technology Data Exchange (ETDEWEB)

    Khiguti, K.; Igarasi, T.; Isimura, Y.; Kharaguti, S.; Tsudzina, T.

    1983-03-04

    The patent covers an additive for a petroleum coke and watersuspension which contains soap of an aliphatic acid (AM) and or a salt of a maleic acid copolymer (SMK). The aliphatic acid soap is a salt of an alkaline earth metal of C6 to C22 aliphatic acid, an ammonium salt or a salt of a lower amine. The maleic acid copolymer is a salt (sodium, NH4) of a lower amine of a maleic anhydride copolymer with a copolymerizing vinyl additive. Capric acid, lauric acid, palmatic acid, aleic and other acids may be used as the aliphatic acid, while methylamine, trimethylamine, diethanolamine, morpholine and so on may be used as the lower amine salt. Ethylene, vinylchloride, methyl(meta)acrylate and so on are used as the polymerizing vinyl compound. The molar ratio of the maleic anhydride to the polymerizing vinyl compound is in a range from 1 to 1 to 1 to 10 (preferably 1 to 1 to 1 to 3). The maleic acid copolymer has a mean molecular mass within 1,000 to 5,000. The additive with the optimal composition contains a solvent, a thickener, an anticorrosion substance, anticoagulants, surfacants (PAV) and so on. A highly concentrated suspension of oil coke and water with a 50 to 75 percent concentration of powder form petroleum coke may be produced using the patented additive. Such a suspension is characterized by low viscosity, high stability and forms no foam during processing.

  10. Identification of causes of oil sands coke leachate toxicity

    International Nuclear Information System (INIS)

    Puttaswamy, N.; Liber, K.

    2010-01-01

    The potential causes of oil sands coke leachate toxicity were investigated. Chronic 7-day toxicity tests were conducted to demonstrate that oil sands coke leachates (CL) are acutely toxic to Ceriodaphnia dubia (C. dubia). CLs were generated in a laboratory to perform toxicity identification evaluation (TIE) tests in order to investigate the causes of the CL toxicity. The coke was subjected to a 15-day batch leaching process at 5.5 and 9.5 pH values. The leachates were then filtered and used for chemical and toxicological characterization. The 7-day estimates for the C. dubia survival were 6.3 for a pH of 5.5 and 28.7 per cent for the 9.5 CLs. The addition of EDTA significantly improved survival and reproduction in a pH of 5.5 CL, but not in a pH of 9.5 CL. The toxicity of the pH 5.5 CL was removed with a cationic resin treatment. The toxicity of the 9.5 pH LC was removed using an anion resin treatment. Toxicity re-appeared when nickel (Ni) and vanadium (V) were added back to the resin-treated CLs. Results of the study suggested that Ni and V were acting as primary toxicants in the pH 5.5 CL, while V was the primary cause of toxicity in the pH 9.5 CL.

  11. Factors affecting coke size and fissuring during cokemaking part 2

    Energy Technology Data Exchange (ETDEWEB)

    Merrick Mahoney; Jeff Keating; Susan Woodhouse [BHP Billiton Newcastle Technology Centre (Australia)

    2007-12-15

    This work addressed the mechanism of fissuring during metallurgical cokemaking and extends on a previous ACARP project. Considerable progress has been made in understanding the mechanism by an integrated modelling work; experimental program. The work points to opportunities for controlling the carbonisation process to achieve required outcomes in terms of coke lump size and distribution. Key outcomes of the work included: A methodology for determination of the minimum spacing between fissures, and the time at which period doublings (i.e. every second fissure stopping) occur, has been developed and implemented. Implementation of the methodology allows the determination of the complete fissure pattern (at least those perpendicular to the oven walls) for a given coke oven/charge configuration. A plausible mechanistic explanation of the formation of lateral fissures (those that are parallel to the oven walls) has been developed. Knowledge of the fissure pattern, combined with the lateral fissuring explanation, enables the determination of typical size and shape of lumps after stabilisation of the coke.

  12. The combustion characteristics of refuse derived fuels using coke/waste tire

    Energy Technology Data Exchange (ETDEWEB)

    Park, M.H. [Dep. of Mechanical Eng., Samcheok Nat' l Univ., Samcheok (Korea); Shin, D.Y. [Research Center for Advanced Mineral Aggregate Composite Products, Kangwon Nat' l Univ., Chuncheon (Korea)

    2005-07-01

    Today every nation faces serious problems of energy supply. Reasonable technologies to make use of coal (including coke) can not only help the mining-related economy which is showing a downward trend but also may fit in with the governmental energy policy. In this research, we aim to supply heating systems in factories, homes, and farms with a substitute fuel by developing coke/waste tire compound fuel with high efficiency for rational use of energy and for recycling of industrial products. A coke/waste boiler was used for this experiment, and different kinds of fuel were experimented including coke, waste tire, coke/waste A and coke/waste B. Four kinds of exhaust gas were also sampled by a gas analyzer, including CO, CO{sub 2}, NO and NO{sub 2} at different temperatures. (orig.)

  13. Automatic combustion control of the ArcelorMittal Tubarao coke oven batteries

    Energy Technology Data Exchange (ETDEWEB)

    L. Barbosa de Oliveira Mello; C.-H. Sampaio Dandrea; G.-H. Marietto Goncalves; A. Estevao Torres; N.-L. Biccas

    2008-05-15

    The objective of the automatic combustion control is to guarantee the operational stability of the coke batteries based on the control of the coking time and consequently, minimize the reduction of useful life of the ovens. This control is guided by a mathematical model whose inputs are process variables and raw materials parameters and outputs are combustion parameters. Therefore, this paper will present the evolution of the performance of the burning process, providing a stability of the coking time.

  14. 46 CFR 148.04-17 - Petroleum coke, calcined, at 130 °F or above.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Petroleum coke, calcined, at 130 °F or above. 148.04-17...-17 Petroleum coke, calcined, at 130 °F or above. (a) The requirements of this part do not apply to bulk shipments of petroleum coke, calcined, on any vessel when the material is less than 130 °F. (b...

  15. Graphitization of Coke and Its Interaction with Slag in the Hearth of a Blast Furnace

    Science.gov (United States)

    Li, Kejiang; Zhang, Jianliang; Liu, Yanxiang; Barati, Mansoor; Liu, Zhengjian; Zhong, Jianbo; Su, Buxin; Wei, Mengfang; Wang, Guangwei; Yang, Tianjun

    2016-04-01

    Coke reaction behavior in the blast furnace hearth has yet to be fully understood due to limited access to the high temperature zone. The graphitization of coke and its interaction with slag in the hearth of blast furnace were investigated with samples obtained from the center of the deadman of a blast furnace during its overhaul period. All hearth coke samples from fines to lumps were confirmed to be highly graphitized, and the graphitization of coke in the high temperature zone was convinced to start from the coke surface and lead to the formation of coke fines. It will be essential to perform further comprehensive investigations on graphite formation and its evolution in a coke as well as its multi-effect on blast furnace performance. The porous hearth cokes were found to be filled up with final slag. Further research is required about the capability of coke to fill final slag and the attack of final slag on the hearth bottom refractories since this might be a new degradation mechanism of refractories located in the hearth bottom.

  16. Properties and potential of formed cokes derived from two Turkish lignites by carbonization of binderless briquettes

    Energy Technology Data Exchange (ETDEWEB)

    Bayraktur, K.N.; Lawson, G.J.

    1984-09-01

    Two high-sulphur Turkish lignites were briquetted at room temperature under pressures of 113 or 212 MPa and the briquettes were carbonized to 1158-1173 K over special heating cycles. The lowerrank lignite gave a formed coke of superior mechanical strength, lower porosity and higher sulphur content than typical blast furnace cokes. The formed coke produced from the higher-rank lignite briquettes had slightly poorer mechanical strength, lower porosity and much higher ash and sulphur content than conventional cokes. The products were considered attractive for use in non-ferrous metallurgy.

  17. Properties and potential of formed cokes derived from two Turkish lignites by carbonization of binderless briquettes

    Energy Technology Data Exchange (ETDEWEB)

    Bayraktar, K.N.; Lawson, G.J.

    1984-09-01

    Two high-sulphur Turkish lignites were briquetted at room temperature under pressures of 113 or 212 MPa and the briquettes were carbonized to 1158-1173 K over special heating cycles. The lower-rank lignite gave a formed coke of superior mechanical strength, lower porosity and higher sulphur content than typical blast furnace cokes. The formed coke produced from the higher-rank lignite briquettes had slightly poorer mechanical strength, lower porosity and much higher ash yield and sulphur content than conventional cokes. The products were considered attractive for use in non-ferrous metallurgy. 38 references.

  18. Combined effects of petrographic and technological parameters on strength of porous coke substance

    Energy Technology Data Exchange (ETDEWEB)

    Dinel' t, V.M.; Shkoller, M.B.; Stankevich, A.S.; Korchuganova, G.S.

    1983-09-01

    The proportion of coke in modern blast furnaces has been reduced and at the same time ore burdens have increased. The coke itself now derives from a much wider range of coals. Laboratory tests related to the structural strength of cokes were carried out with charges composed of 14 representative coals. Results showed that vitrinite reflectance and bulk density were the critical parameters, followed by petrographic composition. Increasing bulk density of the charge from 0.6 to 0.9 g/cm/sup 3/ produces coke with a structural strength which counteracts the effects of increasing diversity in both petrography and reflectance in any one charge.

  19. On-Line Fuel Deoxygenation for Coke Suppression ASME GT-2002-30071

    National Research Council Canada - National Science Library

    Spadaccini, Louis

    2002-01-01

    Fuel deoxygenation is being developed as a means for suppressing autoxidative coke formation in aircraft fuel systems, thereby increasing the exploitable cooling capacity of the fuel, enabling major...

  20. Epidemiologic investigation on health hazard of potential exposure to ionizing radiation among nuclear workers and residents near nuclear power plants in Korea

    International Nuclear Information System (INIS)

    Yoo, Keun Young

    1998-01-01

    This study was conducted to evaluate the health hazard of potential exposure to ionizing radiation among nuclear workers of the KEPCO and community residents nearby nuclear power plants since 1990 in Korea. The objectives of this study encompass 1) to delineate the relationship between cancer occurrence in the target population and radiation possibly emitted from the nuclear power plant, and 2) to provide special health service for health promotion of the community residents including periodic health examinations. The phase I study has been conducted during 1990-1995, which will be followed up by the phase II study until 2003. Hereby the interim report on the phase I study will be presented. As a baseline survey, the cross-sectional comparison shows that there were no significant difference in the health status of nuclear workers and control groups. This prospective study could eventually provide a valid conclusion on the causal relationship of radiation and cancer occurrence among residents nearby nuclear power plants through the phase II study which will be launched out during 1998-2000. (Cho, G. S.)

  1. Occupational coke oven emissions exposure and risk of abnormal liver function: modifications of body mass index and hepatitis virus infection

    Energy Technology Data Exchange (ETDEWEB)

    Y. Hu; B. Chen; J. Qian; L. Jin; T. Jin; D. Lu [Fudan University, Shanghai (China). Department of Occupational and Environmental Health

    2010-03-15

    Occupational coke oven emissions (COEs) have been considered an important health issue. However, there are no conclusive data on human hepatic injury due to COE exposure. The association of COE exposure with liver function was explored and the effects of modification of potential non-occupational factors were assessed. 705 coke oven workers and 247 referents were investigated. Individual cumulative COE exposure was quantitatively estimated. Serum alanine aminotransferase (ALT), aspartate aminotransferase (AST), {gamma}-glutamyl transferase, alkaline phosphatase, hepatitis B surface antigen and anti-hepatitis C antibody were measured. Among those with high COE exposure, the adjusted ORs of abnormal ALT and AST were 5.23 (95% CI 2.66 to 10.27) and 1.95 (95% CI 1.18 to 3.52), respectively. Overweight individuals (body mass index (BMI) {>=}25 kg/m{sup 2}) with high COE exposure had elevated risks of abnormal ALT (adjusted OR 23.93, 95% CI 8.73 to 65.62) and AST (adjusted OR 5.18, 95% CI 2.32 to 11.58). Risk of liver damage in hepatitis B virus- or hepatitis C virus-positive individuals with COE exposure was also elevated. Long-term exposure to COE increases the risk of liver dysfunction, which is more prominent among those with higher BMI and hepatitis virus infection. The risk assessment of liver damage associated with COE exposure should take BMI and hepatitis virus infection into consideration.

  2. Worker doses and potential health effects resulting from the accident at the Fukushima nuclear power plant in 2011.

    Science.gov (United States)

    Etherington, George; Zhang, Wei; Harrison, John; Walsh, Linda

    2014-11-01

    The reliability of exposure scenarios used in the World Health Organization's Health Risk Assessment (HRA) for Fukushima workers was examined. HRA risk estimates for cancer incidence in these workers were then reviewed. The HRA constructed four exposure scenarios to estimate worker radiation doses; recent individual dosimetric data were used to assess their reliability. Risks of specified cancer types attributable to radiation exposure were estimated in the HRA by calculating Lifetime Attributable Risks (LAR) for each scenario, and comparisons of LAR are provided. The scenarios were confirmed as reliable for the purposes of the HRA. For the lowest dose scenario (Scenario 1: 69% of the workforce), the HRA found that any elevated cancer risk was insignificant. Significantly elevated cancer risks were, however, found for the three higher dose scenarios. For the highest dose scenario (Scenario 4: 13 workers), LAR values for thyroid cancer up to 3.5% were estimated, but a radiation-related increase in thyroid cancer incidence is unlikely to be observed because of the small number of workers. For the two intermediate dose scenarios, a small number of cancer cases may occur, but these are unlikely to be observed because the variability in baseline rates of cancer incidence is much larger than the predicted radiation-related incidence rates.

  3. Rapid production of metallurgical coke by a pressurized hot-briquetting method. Netsukan kaatsu seikei ni yoru cokes no jinsoku seizo no kokoromi

    Energy Technology Data Exchange (ETDEWEB)

    Miura, K.; Hayashi, J.; Noguchi, N. (Kyoto University, Kyoto (Japan). Research Laboratory of Carbonaceous Resources Conversion Technology); Hashimoto, K. (Kyoto University, Kyoto (Japan). Faculty of Engineering)

    1993-09-20

    Rapid production of metallurgical coke from non- and slightly coking coals was studied by pressurized hot-briquetting method. Coal specimens were filled into the mold after pulverizing, and heated at a constant temperature rise rate up to caking temperature under loading pressure to obtain caked coal specimens. Such specimens were then carbonized in nitrogen gas at 800[degree]C. As a result, the coke obtained was superior in compressive strength as compared with commercial cokes, however, its CO2 reactivity was very high requiring heating up to 1,000[degree]C to decrease it, while the reactivity was strongly dependent on coal kind. The optimum processing conditions for slightly coking coal were as follows; loading pressure: 10 [times] 10[sup 5] Pa or more, temperature range under loading pressure: 300-450[degree]C, temperature rise rate: 2-100[degree]C/min, and caking temperature: nearly 500[degree]C. No coke could be produced from coking coals because no volatile matter could be removed from it in a short time under pressure. 13 refs., 8 figs., 1 tab.

  4. Development of the super coke oven for productivity and environment enhancement toward the 21st century (SCOPE 21); Sekitan kodo tenkan cokes seizo gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Sugiyama, T [Center for Coal Utilization, Japan, Tokyo (Japan); Nakashima, Y; Nishioka, K; Otsuka, J [The Japan Iron and Steel Federation, Tokyo (Japan)

    1996-09-01

    Serious shortage is predicted on cokes for blast furnaces in the first half of the 21st century. In order to deal flexibly with the fluid world market in the future, it is necessary to have a technology developed, by which coals from coking coal to non-coking dust coal can be used. The Japan Iron and Steel Federation and the Center for Coal Utilization, Japan are working on research and development of a new process with enhanced environmentality and economy (SCOPE 21) as a coke manufacturing process to respond to the requirements arisen from the above situation. The process is assessed basing on basic technological seeds such as rapid coal heating and high-speed carbonization and reformation of middle to low temperature cokes. The organizations are moving forward an eight-year development program which has started in fiscal 1994. This paper reports the summary of the development, and results of investigations and researches performed during fiscals 1994 and 1995. Rapid heating tests, middle to low temperature coke reformation tests, and tests for plug transportation of high-temperature coal have been performed. It has been verified, for example, that rapid coal heating can improve coke strength. The development work is being promoted toward grain size distribution and upscaling problems. 5 refs., 16 figs., 2 tabs.

  5. Radiation situation and irradiation level in forest workers in places of timber works in alienation zone of Chernobyl Atomic Power Plant

    International Nuclear Information System (INIS)

    Kalashnikova, Z.V.; Karachov, Yi.Yi.; Berezhna, T.Yi.; Kuchma, M.D.

    1997-01-01

    The radiation hygienic situation in the forest plots and dose load of the personnel at timber works in the alienation zone of the Chernobyl Atomic Power Plant was evaluated.It has been revealed that the density of contamination of the forest soil at the areas of timber works was 155.4-447.3 kBq centre dot m 2 . Maximum year equivalent dose on the lungs and total dose of external and internal irradiation in the forest workers in the zone of alienation during the work at the areas were about 40% of the values of the respective dose limits for the population of B category

  6. Foreign Workers, Foreign Multinationals, and Wages by Occupation and Sex in Malaysia’s Manufacturing Plants during the mid-1990s

    OpenAIRE

    Eric D. , Ramstetter

    2016-01-01

    This paper investigates the effects of foreign worker shares and MNE ownership on wages paid to males and female in five occupation groups in Malaysian manufacturing plants during 1994-1996, an important period coinciding with the end of the decade-long economic boom that preceded the Asian financial crisis. Random effects estimates of Mincer-type equations by occupation group and sex in large samples of all industries and in seven industry-level samples both suggest that use of foreign worke...

  7. Quality-oriented production of brown-coal coke with due regard to its application in metallurgy and environmental protection; Qualitaetsgerechte Erzeugung von Braunkohlenkoks unter Beruecksichtigung der Anwendung in Metallurgie und Umweltschutz

    Energy Technology Data Exchange (ETDEWEB)

    Achtelik, M.; Erken, M.; Juessen, P.; Knapp, A. [Rheinbraun AG, Koeln (Germany)

    1998-12-31

    In the nineteen seventies the Fortuna Nord refining factory of Rheinbraun AG began to restructure its operations from domestic coal briquetting to the manufacture of industrial products. One of these products, high-temperature brown-coal coke, is produced in two hearth-type furnaces. Coke produced in these plants is mainly used in metallurgy and environmental engineering, in the latter especially for flue gas purification. Rheinbraun has succeeded in introducing a quality management system for brown-coal coke which ensures high quality and security of supply. (orig.) [Deutsch] Im Veredlungsbetrieb Fabrik Fortuna-Nord der Rheinbraun AG begann in den 70er Jahren der Strukturwandel vom Hausbrandbrikett zu Industrieprodukten. Eins dieser Produkte, der Hochtemperatur-Braunkohlenkoks, wird in zwei Herdofenanlagen erzeugt. Die Haupteinsatzbereiche des Herdofenkokses sind die Metallurgie sowie der Umweltschutz und hier insbesondere die Rauchgasreinigung. Um die hohe Produktqualitaet und die Liefersicherheit zu gewaehrleisten, hat Rheinbraun ein Qualitaetsmanagementsystem fuer Braunkohlenkoks erfolgreich eingefuehrt. (orig.)

  8. Effects of Coke Calcination Level on Pore Structure in Carbon Anodes

    Science.gov (United States)

    Fang, Ning; Xue, Jilai; Lang, Guanghui; Bao, Chongai; Gao, Shoulei

    2016-02-01

    Effects of coke calcination levels on pore structure of carbon anodes have been investigated. Bench anodes were prepared by 3 types of cokes with 4 calcination temperatures (800°C, 900°C, 1000°C and 1100°C). The cokes and anodes were characterized using hydrostatic method, air permeability determination, mercury porosimetry, image analysis and confocal microscopy (CSLM). The cokes with different calcination levels are almost the same in LC values (19-20 Å) and real density (1.967-1.985 g/cm3), while the anode containing coke calcined at 900°C has the lowest open porosity and air permeability. Pore size distribution (represented by Anode H sample) can be roughly divided into two ranges: small and medium pores in diameter of 10-400 μm and large pores of 400-580 μm. For the anode containing coke calcined at 800°C, a number of long, narrow pores in the pore size range of 400-580 μm are presented among cokes particles. Formation of these elongated pores may be attributed to coke shrinkages during the anode baking process, which may develop cracking in the anode under cell operations. More small or medium rounded pores with pore size range of 10-400 μm emerge in the anodes with coke calcination temperatures of 900°C, 1000°C and 1100°C, which may be generated due to release of volatiles from the carbon anode during baking. For the anode containing coke calcined at 1100°C, it is found that many rounded pores often closely surround large coke particles, which have potential to form elongated, narrow pores.

  9. Coke Formation During Hydrocarbons Pyrolysis. Part One: Steam Cracking Formation de coke pendant la pyrolise des hydrocarbures. Première partie : vapocraquage

    Directory of Open Access Journals (Sweden)

    Weill J.

    2006-11-01

    Full Text Available Thermal cracking is always accompanied by coke formation, which becomes deposited on the wall and limits heat transfers in the reactor while increasing pressure drops and possibly even plugging up the reactor. This review article covers undesirable coking operations in steam craking reactors. These coking reactions may take place in the gas phase and/or on the surface of the reactor, with coke being produced during pyrolysis by a complex mechanism that breaks down into a catalytic sequence and a noncatalytic sequence. After a brief description of different experimental set-ups used to measure the coke deposition, on the basis of research described in the literature, the different factors and their importance for coke formation are listed. In particular, we describe the effects of surface properties of stainless-steel and quartz reactors as well as the influence of the cracked feedstock, of temperature, of dilution, of residence time and of the conversion on coke deposition. Some findings about the morphology of coke are described and linked to formation mechanisms. To illustrate this review, some particularly interesting research is referred to concerning models developed to assess coke formation during propane steam cracking. Le craquage thermique est toujours accompagné de la formation de coke qui, en se déposant à la paroi, limite les transferts de chaleur au réacteur, augmente les pertes de charges et même peut boucher celui-ci. Cet article fait le point sur les réactions indésirables de cokage dans les réacteurs de vapocraquage. Ces réactions de cokage peuvent avoir lieu en phase gazeuse et/ou sur la surface du réacteur, le coke étant produit pendant la pyrolyse par un mécanisme complexe qui se décompose en une séquence catalytique et une séquence non catalytique. Après une brève présentation des différents montages expérimentaux utilisés pour mesurer le dépôt de coke, il est mentionné, à partir de travaux de la

  10. Development of digital device based work verification system for cooperation between main control room operators and field workers in nuclear power plants

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Seung Min, E-mail: jewellee@kaeri.re.kr [Korea Atomic Energy Research Institute, 305-353, 989-111 Daedeok-daero, Yuseong-gu, Daejeon (Korea, Republic of); Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Lee, Hyun Chul, E-mail: leehc@kaeri.re.kr [Korea Atomic Energy Research Institute, 305-353, 989-111 Daedeok-daero, Yuseong-gu, Daejeon (Korea, Republic of); Ha, Jun Su, E-mail: junsu.ha@kustar.ac.ae [Department of Nuclear Engineering, Khalifa University of Science Technology and Research, Abu Dhabi P.O. Box 127788 (United Arab Emirates); Seong, Poong Hyun, E-mail: phseong@kaist.ac.kr [Department of Nuclear and Quantum Engineering, Korea Advanced Institute of Science and Technology, 373-1, Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)

    2016-10-15

    Highlights: • A digital device-based work verification and cooperation support system was developed. • Requirements were derived by interviewing field operators having experiences with mobile-based work support systems. • The usability of the proposed system was validated by conducting questionnaire surveys. • The proposed system will be useful if the manual or the set of guidelines is well constructed. - Abstract: Digital technologies have been applied in the nuclear field to check task results, monitor events and accidents, and transmit/receive data. The results of using digital devices have proven that these devices can provide high accuracy and convenience for workers, allowing them to obtain obvious positive effects by reducing their workloads. In this study, as one step forward, a digital device-based cooperation support system, the nuclear cooperation support and mobile documentation system (Nu-COSMOS), is proposed to support communication between main control room (MCR) operators and field workers by verifying field workers’ work results in nuclear power plants (NPPs). The proposed system consists of a mobile based information storage system to support field workers by providing various functions to make workers more trusted by MCR operators; also to improve the efficiency of meeting, and a large screen based information sharing system supports meetings by allowing both sides to share one medium. The usability of this system was estimated by interviewing field operators working in nuclear power plants and experts who have experience working as operators. A survey to estimate the usability of the suggested system and the suitability of the functions of the system for field working was conducted for 35 subjects who have experience in field works or with support system development-related research. The usability test was conducted using the system usability scale (SUS), which is widely used in industrial usability evaluation. Using questionnaires

  11. Development of digital device based work verification system for cooperation between main control room operators and field workers in nuclear power plants

    International Nuclear Information System (INIS)

    Lee, Seung Min; Lee, Hyun Chul; Ha, Jun Su; Seong, Poong Hyun

    2016-01-01

    Highlights: • A digital device-based work verification and cooperation support system was developed. • Requirements were derived by interviewing field operators having experiences with mobile-based work support systems. • The usability of the proposed system was validated by conducting questionnaire surveys. • The proposed system will be useful if the manual or the set of guidelines is well constructed. - Abstract: Digital technologies have been applied in the nuclear field to check task results, monitor events and accidents, and transmit/receive data. The results of using digital devices have proven that these devices can provide high accuracy and convenience for workers, allowing them to obtain obvious positive effects by reducing their workloads. In this study, as one step forward, a digital device-based cooperation support system, the nuclear cooperation support and mobile documentation system (Nu-COSMOS), is proposed to support communication between main control room (MCR) operators and field workers by verifying field workers’ work results in nuclear power plants (NPPs). The proposed system consists of a mobile based information storage system to support field workers by providing various functions to make workers more trusted by MCR operators; also to improve the efficiency of meeting, and a large screen based information sharing system supports meetings by allowing both sides to share one medium. The usability of this system was estimated by interviewing field operators working in nuclear power plants and experts who have experience working as operators. A survey to estimate the usability of the suggested system and the suitability of the functions of the system for field working was conducted for 35 subjects who have experience in field works or with support system development-related research. The usability test was conducted using the system usability scale (SUS), which is widely used in industrial usability evaluation. Using questionnaires

  12. 75 FR 51845 - Chrysler Group, LLC Manufacturing Division St. Louis North Plant Including On-Site Leased Workers...

    Science.gov (United States)

    2010-08-23

    ... produce performance coating solutions for vehicles. The company reports that workers leased from DuPont Performance Coatings, a wholly-owned subsidiary of E.I. DuPont de Nemours Company, OEM, were employed on-site..., C R Associates, Syncreon, Robinson Solutions and Dupont Performance Coatings Fenton, MO; Amended...

  13. 77 FR 31643 - Siltronic Corporation FAB1 Plant Including On-Site Leased Workers From Express Temporaries...

    Science.gov (United States)

    2012-05-29

    ... Secure Solutions USA, SBM Management Services, LP, ALSCO Portland Industrial, VWR International, Inc... G4S Secure Solutions USA, SBM Management Services, LP, Alsco Portland Industrial, VWR International... workers from Express Temporaries, Aerotek Commercial Staffing, G4S Secure Solutions USA, SBM Management...

  14. Effects of Two-stage Heat Treatment on Delayed Coke and Study of Their Surface Texture Characteristics

    Science.gov (United States)

    Im, Ui-Su; Kim, Jiyoung; Lee, Seon Ho; Lee, Byung-Rok; Peck, Dong-Hyun; Jung, Doo-Hwan

    2017-12-01

    In the present study, surface texture features and chemical properties of two types of cokes, made from coal tar by either 1-stage heat treatment or 2-stage heat treatment, were researched. The relationship between surface texture characteristics and the chemical properties was identified through molecular weight distribution, insolubility of coal tar, weight loss with temperature increase, coking yield, and polarized light microscope analysis. Rapidly cleared anisotropy texture in cokes was observed in accordance with the coking temperature rise. Quinoline insolubility and toluene insolubility of coal tar increased with a corresponding increases in coking temperature. In particular, the cokes produced by the 2-stage heat treatment (2S-C) showed surface structure of needle cokes at a temperature approximately 50°C lower than the 1-stage heat treatment (1S-C). Additionally, the coking yield of 2S-C increased by approximately 14% in comparison with 1S-C.

  15. [The assessment of the general functional status and of the psychosomatic complaints of workers at hydroelectric power plants].

    Science.gov (United States)

    Danev, S; Dapov, E; Pavlov, E; Nikolova, R

    1992-01-01

    Evaluation of the general functional status and psychosomatic complaints of 61 workers from the hydroelectric power stations is made. The following methods are used: 1. Assessment of the general functional state, by means of computer analysis of the cardiac variability, analysing the changes in the values of the following indices: average value of the cardiac intervals (X), their standard deviation (SD), coefficient of variation (CV), amplitude of the mode (AMO), index of stress (IS), index of the vegetative balance (IVB), homeostatic index (HI). The last 3 indices serve for determination of the complex evaluation of chronic fatigue and work adaptation (ChFWA). 2. Evaluation of the psychosomatic complaints, by the use of a questionnaire for the subjective psychosomatic complaints. 3. Studying the systolic and diastolic blood pressure. The average values received in workers from HPS were compared with the average values of the population of the country and with the average values of a similar working activity of a group of operators from the thermal power station HPS. In conclusion it could be noted that concerning ChFWA the received values in workers from HPS are not more unfavourable generalized values from that measured in workers, occupied with similar type of work in other industrial branches of the country. However, they are with more unfavourable data in comparison with the workers from HPS. The subjective evaluation of the operators concerning their psychic and body health status is moderately worse, both in comparison with the values of the index for the country, and in comparison with those of the operators from HPS.

  16. Pulsed corona discharge for improving treatability of coking wastewater.

    Science.gov (United States)

    Liu, Ming; Preis, Sergei; Kornev, Iakov; Hu, Yun; Wei, Chao-Hai

    2018-02-01

    Coking wastewater (CW) contains toxic and macromolecular substances that inhibit biological treatment. The refractory compounds remaining in biologically treated coking wastewater (BTCW) provide chemical oxygen demand (COD) and color levels that make it unacceptable for reuse or disposal. Gas-phase pulsed corona discharge (PCD) utilizing mostly hydroxyl radicals and ozone as oxidants was applied to both raw coking wastewater (RCW) and BTCW wastewater as a supplemental treatment. The energy efficiency of COD, phenol, thiocyanate and cyanide degradation by PCD was the subject of the research. The cost-effective removal of intermediate oxidation products with addition of lime was also studied. The energy efficiency of oxidation was inversely proportional to the pulse repetition frequency: lower frequency allows more effective utilization of ozone at longer treatment times. Oxidative treatment of RCW showed the removal of phenol and thiocyanate at 800 pulses per second from 611 to 227mg/L and from 348 to 86mg/L, respectively, at 42kWh/m 3 delivered energy, with substantial improvement in the BOD 5 /COD ratio (from 0.14 to 0.43). The COD and color of BTCW were removed by 30% and 93%, respectively, at 20kWh/m 3 , showing energy efficiency for the PCD treatment exceeding that of conventional ozonation by a factor of 3-4. Application of lime appeared to be an effective supplement to the PCD treatment of RCW, degrading COD by about 28% at an energy input of 28kWh/m 3 and the lime dose of 3.0kg/m 3 . The improvement of RCW treatability is attributed to the degradation of toxic substances and fragmentation of macromolecular compounds. Copyright © 2017. Published by Elsevier B.V.

  17. Worker Entrepreneurship.

    Science.gov (United States)

    Doucouliagos, Chris

    1992-01-01

    Evaluates the experience of worker entrepreneurship, highlighting successes and failures in Europe, and analyzes the relative importance of factors to worker entrepreneurship such as access to finance, education and training, organizational culture, and worker risk taking. (JOW)

  18. Synthesis of carbon nanotubes by gasification of petroleum coke

    International Nuclear Information System (INIS)

    Abdullayeva, S.H.; Musayeva, N.N.; Jabbarov, R.B.; Abdullayeva, S.H.; Musayeva, N.N.; Jabbarov, R.B.; Matsuda, T.

    2013-01-01

    Carbon nanotubes have been synthesized by using petroleum coke (PC) as carbon source. Different positions of the PC in the reactor chamber and some other factors markedly increase quantity of the synthesized CNTs and lead to changing of their characteristics such as crystallinity, diameter, straight and etc. confirmed by scanning electron microscope (SEM), transmission electron microscope (TEM) studies.The thickness of the Fe catalyst deposited on Si and SiO 2 substrates strongly influence to the quality, quantity and uniformity of the grown CNTs. Wet-coated thin films of FeCl 2 works well as catalyst, which can be profitable for mass production of CNTs

  19. Coke properties in relation to charge preparation techniques. [Selective crushing

    Energy Technology Data Exchange (ETDEWEB)

    Morozov, O S

    1979-01-01

    Selective crushing is essential to obtain the required coke properties, so that in the coarse fractions there is a considerable reduction in the middlings and dirt normally difficult to crush. These are at the same time enriched with vitrinite so that there is an increase in the coal substance as such, reflected in improved caking capacity in the coarse size range. Various methods of selective crushing are employed, including air entrainment mills, fluidised bed systems. Other advantages claimed for selective crushing are the uniform pore distribution and air permeability and also the diminished breakage stress.

  20. Dependence of coke properties on the method of charge preparation

    Energy Technology Data Exchange (ETDEWEB)

    Morozov, O S

    1979-04-01

    Selective crushing is essential to obtain the required coke properties, so that in the coarse fractions there is a considerable reduction in the middlings and dirt normally difficult to crush. These are at the same time enriched with vitrinite so that there is an increase in the coal substance as such, reflected in improved caking capacity in the coarse size range. Various methods of selective crushing are employed, including air entrainment mills, fluidised bed systems. Other advantages claimed for selective crushing are the uniform pore distribution and air permeability and also the diminished breakage stress.

  1. Process development of coke oven gas to methanol integrated with CO2 recycle for satisfactory techno-economic performance

    International Nuclear Information System (INIS)

    Yi, Qun; Gong, Min-Hui; Huang, Yi; Feng, Jie; Hao, Yan-Hong; Zhang, Ji-Long; Li, Wen-Ying

    2016-01-01

    A novel process designed for producing methanol from coke oven gas (COG) integrated with CO 2 recycle is proposed. In the new system, oxygen replacing air is blown to combustor for assisting combustion of COG and unreacted syngas from methanol synthesis process. The combustion process provides to the heat required in the coking process. The rest COG reacts with the recycled CO 2 separated from the exhaust gas to produce syngas for methanol synthesis. The unreacted syngas from methanol synthesis process with low grade energy level is recycled to the combustor. In the whole methanol production process, there is no additional process with respect to supplementary carbon, and the carbon resource only comes from the internal CO 2 recycle in the plant. With the aid of techno-economic analysis, the new system presents the energy or exergy saving by 5–10%, the CO 2 emission reduction by about 70% and the internal rate of return increase by 5–8%, respectively, in comparison with the traditional COG to methanol process. - Highlights: • A process for producing methanol from COG integrated with CO 2 recycle is first proposed. • CO 2 from the exhaust gas is recycled to supply carbon for producing syngas. • New integrated plant simplifies the production process with 5–8% IRR increase. • New system presents about 5–10% energy saving, about 70% CO 2 emission reduction.

  2. 40 CFR 63.305 - Alternative standards for coke oven doors equipped with sheds.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 9 2010-07-01 2010-07-01 false Alternative standards for coke oven doors equipped with sheds. 63.305 Section 63.305 Protection of Environment ENVIRONMENTAL PROTECTION... SOURCE CATEGORIES National Emission Standards for Coke Oven Batteries § 63.305 Alternative standards for...

  3. Modelling and Simulation of Coking in the Riser of an Industrial ...

    African Journals Online (AJOL)

    Modelling and Simulation of Coking in the Riser of an Industrial Fluid Catalytic Cracking (FCC) Unit. ... Log in or Register to get access to full text downloads. ... The yields of LCO, gasoline, gas and coke that were predicted by the model for industrial risers were ... Full Text: EMAIL FREE FULL TEXT EMAIL FREE FULL TEXT

  4. Issues behind Radiation management of workers at Fukushima Nuclear Power Plant of Tokyo Electric Power Company. From the viewpoint of radiation exposure of the ocular lens and the biological effects to the lens

    International Nuclear Information System (INIS)

    Hayashida, Toshiyuki; Sasaki, Hiroshi; Hatsusaka, Natsuko; Hamada, Nobuyuki; Tatsuzaki, Hideo; Akahane, Keiichi; Yokoyama, Sumi

    2017-01-01

    In March 2011, the accident occurred at the Fukushima Daiichi Nuclear Power Plant of Tokyo Electric Power Company. During recovery from critical situations, the radiation dose for some emergency workers exceeded the effective dose limit recommended for an emergency situation. A month after the accident, the International Commission on Radiological Protection issued a statement on tissue reactions recommending significant reduction of the equivalent dose limit to the lens of the eye. Many radiation workers will need to be involved in treatment of water contaminated with radionuclides, fuel debris retrieval, and decommissioning of reactors for a long period of time. Thus, the optimized radiation control in the fields, exposure reduction, prevention of tissue reactions, and reduction of stochastic risks for workers becomes necessary. This paper discusses issues in relation to radiation protection of the ocular lens in such recovery workers, from the viewpoint of radiation exposure of workers, its management, manifestations and mechanisms of the lens effects. (author)

  5. Binderless briquetting of some selected South African prime coking, blend coking and weathered bituminous coals and the effect of coal properties on binderless briquetting

    Energy Technology Data Exchange (ETDEWEB)

    Mangena, S.J. [Division of Mining Technology, CSIR, PO Box 395, Pretoria, 0001 (South Africa); du Cann, V.M. [Coal and Mineral Technologies (Pty) Ltd, SABS, PO Box 73656, Lynnwood Ridge, Pretoria, 0040 (South Africa)

    2007-07-02

    The binderless briquetting of some selected South African prime coking and blend coking coals, as well as the effects of weathering on the binderless briquetting of some inertinite-rich bituminous coals, were investigated in the laboratory. Selected properties of these coals were determined and the coals were briquetted at various moisture contents and pressures. Based on the results obtained in this study, binderless briquetting was found to be most successful in the cases of the fresh, vitrinite-rich coking and blend coking coals and satisfactory in the fresh inertinite-rich Witbank coals. However, the bonding process seemed to be adversely affected by weathering. The negative impact on bonding could be ameliorated to some extent by the presence of a significant kaolinite content when the percentage ash reports in the order of more than 15% (air-dry basis). It should, however, be noted that kaolinite may reduce the water resistance of the briquettes. (author)

  6. Exposure to occupational air pollution and cardiac function in workers of the Esfahan Steel Industry, Iran.

    Science.gov (United States)

    Golshahi, Jafar; Sadeghi, Masoumeh; Saqira, Mohammad; Zavar, Reihaneh; Sadeghifar, Mostafa; Roohafza, Hamidreza

    2016-06-01

    Air pollution is recognized as an important risk factor for cardiovascular disease. We investigated association of exposure to occupational air pollution and cardiac function in the workers of the steel industry. Fifty male workers of the agglomeration and coke-making parts of the Esfahan Steel Company were randomly selected (n = 50). Workers in the administrative parts were studied as controls (n = 50). Those with known history of hypertension, dyslipidemia, or diabetes, and active smokers were not included. Data of age, body mass index, employment duration, blood pressure, fasting blood sugar, and lipid profile were gathered. Echocardiography was performed to evaluate cardiac function. Left ventricular ejection fraction was lower in workers of the agglomeration/coke-making parts than in controls (mean difference = 5 to 5.5 %, P steel industry is associated with left heart systolic dysfunction. Possible right heart insults due to air pollution exposure warrant further investigations.

  7. Enhanced specific capacitance of modified needle cokes by controlling oxidation treatment

    International Nuclear Information System (INIS)

    Yang, Sunhye; Kim, Ick-Jun; Choi, In-Sik; Soo Kim, Hyun; Tack Kim, Yu

    2010-01-01

    The electric double-layer performance of needle cokes can be affected by the morphology of structures. Hence, we introduce modified needle cokes by using simple oxidation treatment. The degree of graphitization with high specific capacitance is controlled by acid and heat treatment. The active sites of cokes are increased with increasing oxidation time. Dilute nitric acid (HNO 3 ) and sodium chlorate (NaClO 3 ) are used for the activation of cokes. In this case, the interlayer distance is dramatically increased from 3.5 to 8.9 A. The specific capacitances are 33 F g -1 and 30 F ml -1 , respectively, on a two-electrode system with a potential range of 0-2.5 V. The behaviors of double-layer capacitance are demonstrated by the charge-discharge process and the morphologies of modified needle cokes are analyzed by XRD, FE-SEM, BET and elemental analysis.

  8. Microwave-assisted grinding of metallurgical coke; Molienda asistida con microondas de un coque metalurgico

    Energy Technology Data Exchange (ETDEWEB)

    Ruisanchez, E.; Juarez-Perez, E. J.; Arenillas, A.; Bermudez, J. M.; Menendez, J. A.

    2014-10-01

    Metallurgical cokes are composed of graphitic carbon (s2p2) and different inorganic compounds with very different capacities to absorb microwave radiation. Moreover, due to the electric conductivity shown by the metallurgical cokes, microwave radiation produces electric arcs or microplasmas, which gives rise to hot spots. Therefore, when these cokes are irradiated with microwaves some parts of the particle experiment a rapid heating, while some others do not heat at all. As a result of the different expansion and stress caused by thermal the shock, small cracks and micro-fissures are produced in the particle. The weakening of the coke particles, and therefore an improvement of its grind ability, is produced. This paper studies the microwave-assisted grinding of metallurgical coke and evaluates the grinding improvement and energy saving. (Author)

  9. Delayed coking studies on Athabasca bitumen and Cold Lake heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Govindhakannan, J.; Khulbe, C. [National Centre for Upgrading Technology, Devon, AB (Canada); Natural Resources Canada, Devon, AB (Canada). CanmetENERGY

    2009-07-01

    This poster highlighted the results of a study that quantified the delayed coking product yields of Athabasca bitumen and Cold Lake heavy oil. It also investigated the effect of operating pressure and feed rates on product yield and quality. The effect of pressure on conversion of sulphur and nitrogen was also examined. Experimental results revealed that the yield of liquid products decreases and the yields of coke and gases increase as the operating pressure increases. Sulphur and nitrogen conversions increase with increasing pressure. In this study, the yield and quality of delayed coking products were not influenced by the variation in feed rates. It was concluded that feed rate changes do not significantly affect the yield and quality of delayed coking products because the residual liquid and coke trapped in the coker drum reside there for a duration that approaches infinity, compared to much smaller average residence time for vapor-phase compounds. tabs., figs.

  10. Crack coke in layer heat transfer analysis; Kiretsu no shinten wo tomonau kokusu sonai dennetsu kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, Hideyuki [Tohoku University, Miyagi (Japan)

    1999-03-05

    The research method heat transfer process by physical change of the coke by heat transfer from furnace wall in the retorting of coal seam filled in coke oven and flow of the gas is very complicated chamber oven style, and it does not become clear. For the purpose of the elucidation of in layer crack generation and progress mechanism, he is (1) The expansion of the softening cohesive layer. (2) Programming rate dependence of the heat. Mechanical property value on coal seam and semi- coke layer in the retorting. (3) The creep property of softening cohesive layer and semi- coke layer. (4) The setting of crack growth condition of stress intensity factor in crack tip and fracture property value of the coke by the comparison. (5) By considering the radiative heat transfer in the crack, coke in layer thermal stress analysis was carried out. The validity of these analytical result it was confirmed by the comparison with the experimental result of crack growth. Deformation behavior in the small dry distillation furnace, and crack growth mechanism in the coke layer became clear, and the prediction of the stress as micro-crack cause of generation of heating surface side coke surface and inside became possible. The numerical analysis method of the above crack growth mechanism greatly contributes to the prediction of dry distillation heating requirement and grain size of coke lump which is an index to the coke quality. Heat on material process which is accompanied by the solidification. Contraction from the softening and material migration phenomenon have been clarified by the creative research method, while this research is directly useful for energy saving of pig ironmaking process of becoming one of the ringleaders of the CO{sub 2} generation. (translated by NEDO)

  11. [Prevalence and influence factors of hypertension among the workers exposed to noise in steel making and steel rolling workshop of an iron and steel plant].

    Science.gov (United States)

    Li, Yanhong; Chen, Guoshun; Yu, Shanfa

    2015-05-01

    To investigate the prevalence and influence factors of hypertension among the workers exposed to noise in steel making and steel rolling workshop of an iron and steel plant. Using cluster sampling method, 3 150 workers exposed to noise participated in this study. According to do questionnaire survey and blood pressure measurement, 2 924 workers were tested, among which 1 313 workers were from steel making workshop and 1 611 workers were from steel rolling workshop. The relationships between different demographic characteristics, different habits, and different cumulative noise exposures of workers exposed to noise and hypertension were analyzed. For the hypertension prevalence rate, the total prevalence rate was 27.43% (802/2 924), the male was higher than the female (29.88 % (753/2 520) vs 12.13% (49/404), χ² = 55.13, P married ones were higher than the unmarried (29.84% (718/2 406) vs 16.22% (84/518), χ² = 39.76, P vs 24.61% (364/1 479), χ² = 11.93, P = 0.001), drinking ones were higher than the no drinking (31.53% (541/1 716) vs 21.61% (261/1 208), χ² = 35.05, P < 0.001). The hypertension prevalence rates among the subjects with education background in junior high school and below, high school (secondary) and university and above were separately 44.96%(125/278), 29.95%(455/1 519) and 19.70%(222/1 127) (χ² = 81.65, P < 0.001), among cumulative exposure groups 77-89, 90-94, 95-99, 100-104 and 105-113 were separately 8.43% (14/166), 14.48% (53/366), 24.28% (297/1 223), 36.65% (335/914) and 40.39%(103/255) (χ² = 127.58, P < 0.001). Multivariate logistic regression analysis showed that workers who exposed to cumulative noise in 95-99, 100-104 and 105-113 dB(A) ·year had the higher risk of hypertension, the OR (95%CI) were 1.84 (95% CI: 1.35-2.51), 1.74 (95% CI: 1.24-2.45) and 1.68 (95% CI: 1.09-2.58). Drinking (OR = 1.60, 95% CI: 1.32-1.95) and BMI ≥ 24.0 kg/m² (OR = 1.26, 95% CI: 1.22-1.30) were the risk factors for hypertension as well. Cumulative

  12. Health-related quality-of-life of coal-based sponge iron plant workers in Barjora, India: a cross-sectional study.

    Science.gov (United States)

    Chattopadhyay, Kaushik; Chattopadhyay, Chaitali; Kaltenthaler, Eva

    2014-09-04

    During the last decade, coal-based sponge iron plants, a highly polluted industry, have grown rapidly in Barjora, India. Understanding their workers' perception of health is essential in people-centered healthcare. The aim of the study was to assess their health-related quality-of-life (HRQoL), and to determine factors that independently predict their HRQoL. Cross-sectional study. Coal-based sponge iron plants in Barjora, India. 258 coal-based sponge iron plant workers. HRQoL was measured using the EuroQol-5D-5L. The response rate was 100%. Participants with problems in mobility, self-care, usual activities, pain/discomfort and anxiety/depression were 23.3%, 5.1%, 10.9%, 39.5% and 45.5%, respectively. 36.8% of participants reported health state 11111 (no problem in any EQ-5D dimension). The mean visual analogue scale (EQ-VAS) was 69.8 (18.5 SD). The odds of mobility problems decreased with age (OR 0.95, 95% CI 0.91 to 0.99, p=0.016), were lower in participants with presence/history of any respiratory disease (0.27, 0.13 to 0.55, pworkers (0.44, 0.22 to 0.89, p=0.021), manual workers (0.40, 0.16 to 0.99, p=0.047) and non-smokers (2.63, 1.27 to 5.46, p=0.009). The odds of pain/discomfort and anxiety/depression were lower in participants with any respiratory disease (0.44, 0.24 to 0.79, p=0.006; and 0.52, 0.29 to 0.92, p=0.026, respectively). The EQ-VAS was worse in manual participants (coefficient -6.91, 95% CI -12.40 to -1.41, p=0.014), with any respiratory disease (-8.13, -13.12 to -3.13, p=0.002), alcohol drinkers (-4.81, -9.47 to -0.15, p=0.043), literates (7.70, 0.97 to 14.43, p=0.025) and Hindus (13.41, 2.62 to 24.20, p=0.015). Many coal-based sponge iron plant workers in Barjora have problems in their HRQoL, and the predictors of different aspects of HRQoL were identified. The study findings could be taken into consideration in future interventional studies aimed at improving the HRQoL of these workers. Published by the BMJ Publishing Group Limited. For

  13. Researching the technology of tar removal from coke-chemical plants’ wastewater by reagent flotation method

    Directory of Open Access Journals (Sweden)

    Anna V. Ivanchenko

    2015-03-01

    Full Text Available The study aims to identify process patterns of tars and oils removal from phenolic wastewater by reagent flotation with bringing those components’ content to acceptable concentrations. For the first time established is the effect of Al2(SO43, AlCl3, FeSO4, Fe2(SO43, Al2(OH5Cl and FeCl3 doses onto residual tar content in phenolic wastewater. Results obtained give the possibility to prevent air pollution resulting from the toxic substances emission at the wet quenching with water containing excessive oils and to increase the quality of wastewater biological treatment. It is shown experimentally that the most efficient are Fe2(SO43, FeCl3 and Al2(OH5Cl at optimum concentrations of 50, 30 and 30 mg/dm3 respectively. The Al2(OH5Cl can be recommended for implementation at industry on existing coking plants and municipal wastewater treatment plants to improve the environmental air and water resources condition in Ukraine.

  14. The Release of Trace Elements in the Process of Coal Coking

    Directory of Open Access Journals (Sweden)

    Jan Konieczyński

    2012-01-01

    Full Text Available In order to assess the penetration of individual trace elements into the air through their release in the coal coking process, it is necessary to determine the loss of these elements by comparing their contents in the charge coal and in coke obtained. The present research covered four coke oven batteries differing in age, technology, and technical equipment. By using mercury analyzer MA-2 and the method of ICP MS As, Be, Cd, Co, Hg, Mn, Ni, Se, Sr, Tl, V, and Zn were determined in samples of charge coal and yielded coke. Basing on the analyses results, the release coefficients of selected elements were determined. Their values ranged from 0.5 to 94%. High volatility of cadmium, mercury, and thallium was confirmed. The tests have shown that although the results refer to the selected case studies, it may be concluded that the air purity is affected by controlled emission occurring when coke oven batteries are fired by crude coke oven gas. Fugitive emission of the trace elements investigated, occurring due to coke oven leaks and openings, is small and, is not a real threat to the environment except mercury.

  15. Nature of nitrogen specie in coke and their role in NOx formation during FCC catalyst regeneration

    International Nuclear Information System (INIS)

    Babich, I.V.; Seshan, K.; Lefferts, L.

    2005-01-01

    NO x emission during the regeneration of coked fluid catalytic cracking (FCC) catalysts is an environmental problem. In order to follow the route to NO x formation and try to find ways to suppress it, a coked industrial FCC catalyst has been prepared using model N-containing compounds, e.g., pyridine, pyrrole, aniline and hexadecane-pyridine mixture. Nitrogen present in the FCC feed is incorporated as polyaromatic compounds in the coke deposited on the catalyst during cracking. Its functionality has been characterized using XPS. Nitrogen specie of different types, namely, pyridine, pyrrolic or quaternary-nitrogen (Q-N) have been discriminated. Decomposition of the coke during the catalyst regeneration (temperature programmed oxidation (TPO) and isothermal oxidation) has been monitored by GC and MS measurements of the gaseous products formed. The pyrrolic- and pyridinic-type N specie, present more in the outer coke layers, are oxidized under conditions when still large amount of C or CO is available from coke to reduced NO x formed to N 2 . ''Q-N'' type species are present in the inner layer, strongly adsorbed on the acid sites on the catalyst. They are combusted last during regeneration. As most of the coke is already combusted at this point, lack of reductants (C, CO, etc.) results in the presence of NO x in the tail gas

  16. PROBLEMS WITH DETERMINATION OF FUGITIVE EMISSION OF POLYCYCLIC AROMATIC HYDROCARBONS FROM COKE OVEN BATTERY

    Directory of Open Access Journals (Sweden)

    Rafał Bigda

    2017-03-01

    Full Text Available Coke oven battery is complex and multifaceted facility in terms of air pollutant emissions. As far as stack or quenching tower does not cause major difficulties of emission measurement, the fugitive emission measurement from sources such as battery top elements (charging holes, ascension pipes or oven doors is still complicated and not fully solved problem. This article presents the discussion concerning main problems and errors likely to be made in particular stages of procedure of fugitive emissions characterization from coke oven battery (selection of sampling points, sampling itself, measurement of air velocity over battery top and laboratory analyses. In addition, results of concentrations measurements of selected substances characteristic for the coking process (naphthalene, anthracene, 4 PAHs and TSP originating from fugitive sources of coke oven battery and subjected to reporting under the E-PRTR are presented. The measurements were carried out on coke oven battery top in points selected on the basis of the preceding detailed air convection velocity measurements over battery top. Results of the velocity measurements were compared with results of numerical modelling using CFD software. The presented material is an attempt to cross-sectional presentation of issues related to the quantitative evaluation of fugitive emission from coke oven battery, discussed on the example of PAHs emission as a group of substances characteristic for coking of coal.

  17. Incidence of Raynaud's phenomenon in relation to hand-arm vibration exposure among male workers at an engineering plant a cohort study

    Directory of Open Access Journals (Sweden)

    Lundström Ronnie

    2008-06-01

    Full Text Available Abstract Background The objective of this study was to assess the incidence of Raynaud's phenomenon in relation to hand-arm vibration exposure in a cohort consisting of male office and manual workers. Methods The baseline population consisted of 94 office and 147 manual workers at an engineering plant. Raynaud's phenomenon (RP was assessed at baseline and at follow up (at 5, 10 and 15 years. A retrospective and a prospective cohort analysis of data were done. Hand-arm vibration exposure dose was defined as the product of exposure duration and the weighted hand-arm vibration exposure value according to ISO 5349-1. Results The retrospective/prospective incidence of Raynaud's phenomenon was 16/14 per 1000 exposure years among exposed and 2.4/5.0 per 1000 years among the not exposed. The retrospective dose response curve based on 4 dose classes showed that class 2, 3 and 4 had similar response and showed higher incidence than the not-exposed. The dose with RP response to hand-arm vibration corresponded to a 10 year A(8 value between 0.4–1.0 m/s2. Conclusion The results indicate that the EU directive on an action value for hand-arm vibration of 2.5 m/s2 is not too low. Rather, it suggests that employers should take on actions even at exposure values of 1 m/s2A(8.

  18. Increased Suicide Risk among Workers following Toxic Metal Exposure at the Paducah Gaseous Diffusion Plant From 1952 to 2003: A Cohort Study

    Directory of Open Access Journals (Sweden)

    LW Figgs

    2011-09-01

    Full Text Available Background: Suicide is a problem worldwide and occupation is an important risk factor. In the last decade, 55 200 deaths in the US were attributed to occupational risk factors. Objective: To determine if toxic metal exposure was associated with suicide risk among Paducah gaseous diffusion plant (PGDP workers. Methods: We assembled a cohort of 6820 nuclear industry workers employed from 1952 to 2003. A job-specific exposure matrix (JEM was used to determine metal exposure likelihood. Uranium exposure was also assessed by urinalysis. All suicide/self-injury International Classification for Disease (ICD codes were used to identify suicides. Standardized mortality ratios (SMR, odds ratios (OR, and hazard ratios (HR were used to estimate suicide risk. Results: PGDP suicide victims typically were younger white men. Within exposure likelihood categories, several suicide SMRs were typically elevated for several metals. Only beryllium exposure likelihood was associated with an increased HR. Uranium urine concentration was associated with an elevated suicide risk after stratification by urinalysis frequency. Conclusion: Suicide risk is associated with uranium exposure.

  19. Distillation of tar and tar fractions in the presence of surface-active coke

    Energy Technology Data Exchange (ETDEWEB)

    Jaeppelt, A; Klaus, J

    1943-01-01

    The tar obtained by low-temperature carbonization of Upper Silesian gas coke and fractions from this tar were distilled in the presence of different grades of coke dust with varying surface activity; the coke had been activated by steam in the course of its production by low-temperature carbonization. The surface activity of the coke dusts was measured by determining the heat of wetting with C/sub 6/H/sub 6/. Tar and coke dust, both anhydrous, were mixed in a kneading machine in such proportions that the capillaries of the dust were saturated and enough ''externally'' bound tar was present to permit briquetting. The briquets were distilled without cracking and with steam as heating medium. The yield and quality of the distillate depended on the magnitude of the internal surface of the coke dust used; a mixture of a very active coke from brown coal and tar yielded a distillate with Conradson carbon residue of 1.34 percent, asphalt content 6.1 percent and eta/sub 20/ 5.4/sup 0/ E. as compared with C residue of 10.95 percent, asphalt content 33.5 percent and eta/sub 20/ 123.6/sup 0/ E. of the distillate obtained in the absence of surface-active coke. Even higher-boiling fractions can be improved by this treatment, although it is preferable to use oils with an initial boiling point below 300/sup 0/. The ratio of oil to adsorbent is not critical, but better results were obtained with higher percentages of added coke dust. The process in its present form is not suited for the conversion of crude creosote to useful phenols.

  20. Development of reduced crude processing technology in delayed coking units; Desenvolvimento da tecnologia de processamento de residuo atmosferico em unidade de coqueamento retardado

    Energy Technology Data Exchange (ETDEWEB)

    Soares, Gloria Maria Gomes; Bartros, Francisco Carlos da Costa; Goncalves, Natalie Jorge; Pala, Danielle Marins; Nadolni, Aline Voigt [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    Delayed Coking Technology can be described as thermal cracking of low value refinery residual streams into high-value products. This process has been applied in petroleum refining schemes in order to upgrade heavy and ultra-heavy crude oils. The typical feedstock is vacuum residue (VR). When we have an increasing medium distillates demand and refining schemes which have gas oil and VR excess, the simultaneous conversion of these streams becomes economically attractive, due mainly to the increase of diesel production. Thus, the processing of atmospheric residue (AR) in Delayed Coking Units (DCU) has fueled great interest for PETROBRAS. This work presents the results of industrial and pilot plant tests with AR and VR showing the increasing of diesel yields and decreasing of coke yields processing AR as feedstock. When we process all the AR in the DCU with high recycle rate we observe an increasing of 25% on refinery diesel production related to conventional schemes. The refining scheme of the new PETROBRAS refinery at Northeast of Brazil is based on this technology. This refinery will process heavy oils maximizing diesel production with minimum investment. (author)