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Sample records for coal solution final

  1. Disintegration of brown coal using alkaline solution

    Energy Technology Data Exchange (ETDEWEB)

    Vydra, J.; Skalicka, J.

    1985-01-01

    Investigations carried out by the Institute of Geology and Geotechnics of the Academy of Sciences of Czechoslovakia are discussed. The investigations were aimed at determining the optimum conditions for in situ solution mining of brown coal using alkaline solutions. Twelve brown coal samples with carbon content ranging from 64.5 to 90.7% were treated with sodium hydroxide solution with concentration ranging from 1 to 5%. Effects of hydrogen peroxide (15%) and ethanolamine (5%) also were investigated. Proportion of the 3 compounds in water was the following: 500 ml sodium hydroxide, 100 ml ethanolamine and 20 ml hydrogen peroxide. Effects of coal grain size on its disintegration in the alkaline solution also were analyzed. Conditions of in situ solution mining were simulated in the laboratory. Investigations showed that the optimum coal grain size was 2 mm, in which case disintegration efficiency depended on carbon content in coal. The lower the carbon content was, the more efficient was the alkaline disintegration. Alkaline solutions did not influence brown coal with carbon content higher than 85%. The optimum concentration of sodium hydroxide was 3%. Addition of hydrogen peroxide and ethanolamine did not influence disintegration. When alkaline solution was pumped 96 h long into a borehole, it penetrated coal to a depth of 2 mm causing swelling of the borehole walls but not coal disintegration. 8 references.

  2. Liquefaction of coals using ultra-fine particle, unsupported catalysts: In situ particle generation by rapid expansion of supercritical fluid solutions. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-01

    The research conducted by Textron Defense Systems (TDS) represents a potential new and innovative concept for dispersed coal liquefaction. The technical approach is generation of ultra-fine catalyst particles from supercritical solutions by rapid expansion of either catalyst only, or mixtures of catalyst and coal material in supersaturated solvents. The process of rapid expansion of supercritical fluid solutions was developed at Battelle`s Pacific Northwest Laboratories for the intended purpose of providing a new analytical technique for characterizing supercritical fluids. The concept forming the basis of this research is that ultra-fine particles can be generated from supercritical solutions by rapid expansion of either catalyst or catalyst/coal-material mixtures in supersaturated solvents, such as carbon dioxide or water. The focal point of this technique is the rapid transfer of low vapor pressure solute (i.e., catalyst), dissolved in the supercritical fluid solvent, to the gas phase as the solution is expanded through an orifice. The expansion process is characterized by highly nonequilibrium conditions which cause the solute to undergo extremely rapid supersaturation with respect to the solvent, leading to nucleation and particle growth resulting in nanometer size catalyst particles. A supercritical expansion system was designed and built by TDS at their Haverhill facility.

  3. Final Report of the Advanced Coal Technology Work Group

    Science.gov (United States)

    The Advanced Coal Technology workgroup reported to the Clean Air Act Advisory Committee. This page includes the final report of the Advanced Coal Technology Work Group to the Clean Air Act Advisory Committee.

  4. Pelletization of fine coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sastry, K.V.S.

    1995-12-31

    Coal is one of the most abundant energy resources in the US with nearly 800 million tons of it being mined annually. Process and environmental demands for low-ash, low-sulfur coals and economic constraints for high productivity are leading the coal industry to use such modern mining methods as longwall mining and such newer coal processing techniques as froth flotation, oil agglomeration, chemical cleaning and synthetic fuel production. All these processes are faced with one common problem area--fine coals. Dealing effectively with these fine coals during handling, storage, transportation, and/or processing continues to be a challenge facing the industry. Agglomeration by the unit operation of pelletization consists of tumbling moist fines in drums or discs. Past experimental work and limited commercial practice have shown that pelletization can alleviate the problems associated with fine coals. However, it was recognized that there exists a serious need for delineating the fundamental principles of fine coal pelletization. Accordingly, a research program has been carried involving four specific topics: (i) experimental investigation of coal pelletization kinetics, (ii) understanding the surface principles of coal pelletization, (iii) modeling of coal pelletization processes, and (iv) simulation of fine coal pelletization circuits. This report summarizes the major findings and provides relevant details of the research effort.

  5. Health impacts of coal and coal use: Possible solutions

    Science.gov (United States)

    Finkelman, R.B.; Orem, W.; Castranova, V.; Tatu, C.A.; Belkin, H.E.; Zheng, B.; Lerch, H.E.; Maharaj, S.V.; Bates, A.L.

    2002-01-01

    Coal will be a dominant energy source in both developed and developing countries for at least the first half of the 21st century. Environmental problems associated with coal, before mining, during mining, in storage, during combustion, and postcombustion waste products are well known and are being addressed by ongoing research. The connection between potential environmental problems with human health is a fairly new field and requires the cooperation of both the geoscience and medical disciplines. Three research programs that illustrate this collaboration are described and used to present a range of human health problems that are potentially caused by coal. Domestic combustion of coal in China has, in some cases, severely affected human health. Both on a local and regional scale, human health has been adversely affected by coals containing arsenic, fluorine, selenium, and possibly, mercury. Balkan endemic nephropathy (BEN), an irreversible kidney disease of unknown origin, has been related to the proximity of Pliocene lignite deposits. The working hypothesis is that groundwater is leaching toxic organic compounds as it passes through the lignites and that these organics are then ingested by the local population contributing to this health problem. Human disease associated with coal mining mainly results from inhalation of particulate matter during the mining process. The disease is Coal Worker's Pneumoconiosis characterized by coal dust-induced lesions in the gas exchange regions of the lung; the coal worker's "black lung disease". ?? 2002 Elsevier Science B.V. All rights reserved.

  6. Biological upgrading of coal liquids. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-02-01

    A large number of bacterial enrichments have been developed for their ability to utilize nitrogen and sulfur in coal liquids and the model compound naphtha. These bacteria include the original aerobic bacteria isolated from natural sources which utilize heteroatom compounds in the presence of rich media, aerobic nitrogen-utilizing bacteria and denitrifying bacteria. The most promising isolates include Mix M, a mixture of aerobic bacteria; ER15, a pyridine-utilizing isolate; ERI6, an aniline-utilizing isolate and a sewage sludge isolate. Culture optimization experiments have led to these bacteria being able to remove up to 40 percent of the sulfur and nitrogen in naphtha and coal liquids in batch culture. Continuous culture experiments showed that the coal liquid is too toxic to the bacteria to be fed without dilution or extraction. Thus either semi-batch operation must be employed with continuous gas sparging into a batch of liquid, or acid extracted coal liquid must be employed in continuous reactor studies with continuous liquid flow. Isolate EN-1, a chemical waste isolate, removed 27 percent of the sulfur and 19 percent of the nitrogen in fed batch experiments. Isolate ERI5 removed 28 percent of the nitrogen in coal liquid in 10 days in fed batch culture. The sewage sludge isolate removed 22.5 percent of the sulfur and 6.5 percent of the nitrogen from extracted coal liquid in continuous culture, and Mix M removed 17.5 percent of the nitrogen from medium containing extracted coal liquid. An economic evaluation has been prepared for the removal of nitrogen heteroatom compounds from Wilsonville coal liquid using acid extraction followed by fermentation. Similar technology can be developed for sulfur removal. The evaluation indicates that the nitrogen heteroatom compounds can be removed for $0.09/lb of coal liquid treated.

  7. Advanced coal liquefaction research: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Gall, W.; McIlvried, III, H. G.

    1988-07-01

    This study had two objectives: (1) To enhance the fundamental understanding of observed differences in the short contact time, donor solvent liquefaction of bituminous and subbituminous coals. (2) To determine if physical refining of subbituminous coals could be used to give a better feedstock for the first stage of two-stage liquefaction processes. Liquefaction studies using microautoclaves were carried out. Results are discussed. 11 refs., 25 figs., 29 tabs.

  8. Formation and retention of methane in coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  9. Coal surface control for advanced physical fine coal cleaning technologies. Final report, September 19, 1988--August 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-12-31

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO{sub 2} emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R&D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  10. X-ray Computed Tomography of coal: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Maylotte, D.H.; Spiro, C.L.; Kosky, P.G.; Lamby, E.J.

    1986-12-01

    X-ray Computed Tomography (CT) is a method of mapping with x-rays the internal structures of coal. The technique normally produces 2-D images of the internal structures of an object. These images can be recast to create pseudo 3-D representations. CT of coal has been explored for a variety of different applications to coal and coal processing technology. In a comparison of CT data with conventional coal analyses and petrography, CT was found to offer a good indication of the total ash content of the coal. The spatial distribution of the coal mineral matter as seen with CT has been suggested as an indicator of coal washability. Studies of gas flow through coal using xenon gas as a tracer have shown the extremely complicated nature of the modes of penetration of gas through coal, with significant differences in the rates at which the gas can pass along and across the bedding planes of coal. In a special furnace designed to allow CT images to be taken while the coal was being heated, the pyrolysis and gasification of coal have been studied. Gasification rates with steam and CO/sub 2/ for a range of coal ranks have been obtained, and the location of the gasification reactions within the piece of coal can be seen. Coal drying and the progress of the pyrolysis wave into coal have been examined when the coal was subjected to the kind of sudden temperature jump that it might experience in fixed bed gasifier applications. CT has also been used to examine stable flow structures within model fluidized beds and the accessibility of lump coal to microbial desulfurization. 53 refs., 242 figs., 26 tabs.

  11. Coal plasticity at high heating rates and temperatures. Final technical progress report

    Energy Technology Data Exchange (ETDEWEB)

    Gerjarusak, S.; Peters, W.A.; Howard, J.B.

    1995-05-01

    Plastic coals are important feedstocks in coke manufacture, coal liquefaction, gasification, and combustion. During these processes, the thermoplastic behavior of these coals is also important since it may contribute to desirable or undesirable characteristics. For example, during liquefaction, the plastic behavior is desired since it leads to liquid-liquid reactions which are faster than solid-liquid reactions. During gasification, the elastic behavior is undesired since it leads to caking and agglomeration of coal particles which result in bed bogging in fixed or fluidized bed gasifiers. The plastic behavior of different coals was studied using a fast-response plastometer. A modified plastometer was used to measure the torque required to turn at constant angular speed a cone-shaped disk embedded in a thin layer of coal. The coal particles were packed between two metal plates which are heated electrically. Heating rates, final temperatures, pressures, and durations of experiment ranged from 200--800 K/s, 700--1300 K, vacuum-50 atm helium, and 0--40 s, respectively. The apparent viscosity of the molten coal was calculated from the measured torque using the governing equation of the cone-and-plate viscometer. Using a concentrated suspension model, the molten coal`s apparent viscosity was related to the quantity of the liquid metaplast present during pyrolysis. Seven coals from Argonne National Laboratory Premium Coal Sample Bank were studied. Five bituminous coals, from high-volatile to low-volatile bituminous, were found to have very good plastic behavior. Coal type strongly affects the magnitude and duration of plasticity. Hvb coals were most plastic. Mvb and lvb coals, though the maximum plasticity and plastic period were less. Low rank coals such as subbituminous and lignite did not exhibit any plasticity in the present studies. Coal plasticity is moderately well correlated with simple indices of coal type such as the elemental C,O, and H contents.

  12. Magnetic relaxation - coal swelling, extraction, pore size. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Doetschman, D.C.

    1994-10-26

    The aim of the contract was to employ electron and nuclear magnetic relaxation techniques to investigate solvent swelling of coals, solvent extraction of coals and molecular interaction with solvent coal pores. Many of these investigations have appeared in four major publications and a conference proceedings. Another manuscript has been submitted for publication. The set of Argonne Premium Coals was chosen as extensively characterized and representative samples for this project.

  13. REDUCING THE INTENSITY OF TAKEAWAY PULVERIZED COAL BY USING SPECIAL SOLUTION

    Directory of Open Access Journals (Sweden)

    M. M. Biliaiev

    2017-04-01

    Full Text Available Purpose. The article is aimed: 1 to develop the coal coating solution in open railway cars or to cover coal piles to minimize the coal dust losses; 2 creating a mathematical model of the process of the solution feeding to the surface of coal. Methodology. To solve this problem, it was developed a special solution containing cheap industrial wastes and semiproducts of chemical industries. It was conducted a physical experiment to assess the intensity of coal dust loss when using the developed solution. A mathematical model based on the use of the motion equations of the ideal fluid and mass transfer was developed. The developed numerical models are the basis of the application program package created for assessing the quality of processing the coal surface by special solution. Findings. The results of the conducted physical experiment to assess the magnitude of the coal dust loss on the model of the coal pile in the processing of its surface with a special solution and without processing are presented in the article. It is shown that the application of the proposed solution for surface processing of coal can significantly reduce the coal dust loss. This makes it possible to reduce the amount of economic losses and reduce the level of air dust pollution in work areas. The results of computational experiments carried out on the basis of the constructed numerical models are presented in the article. Originality. Authors proposed a new solution for the coal surface processing in order to minimize the removal of pulverized coal from the coal pile, which substantially reduces the coal losses. There were created numerical models to take into account the relevant factors influencing the solution dispersion process in the atmosphere from coal processing in gondola cars. Practical value. Solution, proposed in the article has a low price, because it can be created on the basis of industrial production wastes. Application of this solution can significantly

  14. Energy Crisis in Pakistan and Thar Coal is Untapped Wealth and Solution

    OpenAIRE

    Anwar Ali Shah G.Syed; Faiz M. Shaikh; Abdul Sattar Shah

    2014-01-01

    This research investigates the Energy crisis and Thar coal is untapped and solution to engery problem in Pakistan. Data were collected from various secondary sources i.e. Annual Reports, News prepard, magazine and Reports from Thar coal development authority. It was revealed that Thar coal that there is now some hope for economic uplift as its natural wealth is being tapped. Geological Survey of Pakistan (GSP), discovered huge deposits of coal in 1922 at Thar during the research program, assi...

  15. Reactivity of coal in direct hydrogenation processes: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Baldwin, R. M.; Miller, R. L.

    1989-07-01

    This research program consisted of two facets dealing with fundamental and applied studies on coal reactivity under direct hydroliquefaction conditions. The first facet was concerned with an investigation of the relationship between coal reactivity and coal properties. Data on the rate and extent of direct coal hydroliquefaction for 5 bituminous coals from the Argonne Premium Sample Bank were measured. Data on rate of conversion of coal to THF and toluene solubles were modeled with a simple reversible rate expression, and activation energies for conversion to each solvent solubility class determined. Data on carbon and proton distribution in the coals were obtained by /sup 1/H-NMR and /sup 13/C-NMR. A strong correlation of activation energy with the aliphatic hydrogen content of the coal was found for conversion to THF solubles. The second facet of the program dealt with a mechanistic study of the effect of hydrogen on the rate and extent of coal liquefaction. The objective was to investigate the effect of radical quenching by aromatic and hydroaromatic vehicles on the activity and selectivity of hydrogen under conditions relevant to direct coal hydroliquefaction. The experimental portion of the program consisted of a series of runs on a model compound system, followed by experiments utilizing 5 bituminous coals from the Argonne Premium Coal sample bank. 45 refs., 14 figs., 17 tabs.

  16. Analysis of photographic records of coal pyrolysis. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Dodoo, J.N.D.

    1991-10-01

    Bituminous coals upon heating undergo melting and pyrolytic decomposition with significant parts of the coal forming an unstable liquid that can escape from the coal by evaporation. The transient liquid within the pyrolyzing coal causes softening or plastic behavior that can influence the chemistry and physics of the process. Bubbles of volatiles can swell the softened coal mass in turn affecting the combustion behavior of the coal particles. The swelling behavior of individual coal particles has to be taken into account both as the layout as well as for the operation of pyrolysis, coking and performance of coal-fired boilers. Increased heating rates generally increase the amount of swelling although it is also known that in some cases, even highly swelling coals can be transformed into char with no swelling if they are heated slowly enough. The swelling characteristics of individual coal particles have been investigated by a number of workers employing various heating systems ranging from drop tube and shock tube furnaces, flow rate reactors and electrical heating coils. Different methods have also been employed to determine the swelling factors. The following sections summarize some of the published literature on the subject and outline the direction in which the method of analysis will be further extended in the study of the swelling characteristics of hvA bituminous coal particles that have been pyrolyzed with a laser beam.

  17. Highly Dispersed Pseudo-Homogeneous and Heterogeneous Catalysts Synthesized via Inverse Micelle Solutions for the Liquefaction of Coal

    Energy Technology Data Exchange (ETDEWEB)

    Hampden-Smith, M.; Kawola, J.S.; Martino, A.; Sault, A.G.; Yamanaka, S.A.

    1999-01-05

    The mission of this project was to use inverse micelle solutions to synthesize nanometer sized metal particles and test the particles as catalysts in the liquefaction of coal and other related reactions. The initial focus of the project was the synthesis of iron based materials in pseudo-homogeneous form. The frost three chapters discuss the synthesis, characterization, and catalyst testing in coal liquefaction and model coal liquefaction reactions of iron based pseudo-homogeneous materials. Later, we became interested in highly dispersed catalysts for coprocessing of coal and plastic waste. Bifunctional catalysts . to hydrogenate the coal and depolymerize the plastic waste are ideal. We began studying, based on our previously devised synthesis strategies, the synthesis of heterogeneous catalysts with a bifunctional nature. In chapter 4, we discuss the fundamental principles in heterogeneous catalysis synthesis with inverse micelle solutions. In chapter 5, we extend the synthesis of chapter 4 to practical systems and use the materials in catalyst testing. Finally in chapter 6, we return to iron and coal liquefaction now studied with the heterogeneous catalysts.

  18. Developmental research study of coal-fines agglomeration for fixed-bed gasification. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Elmquist, S.A.; Girimont, J.A.; Korosi, F.A.; Kuby, O.A.; Nelson, S.G.; Paulin, M.O.; Peterson, C.A.; Baker, R.L.; Saller, E.

    1983-05-31

    This report presents the results of an intensive program to develop and evaluate agglomerates made from coal fines for use in a fixed-bed gasifier. There were several tasks completed earlier and their results published prior to this final report. These included: Task 1-A, a literature survey of coal agglomeration, binders and techniques used in coal agglomeration, coal and binder treatments and the results of work done by others; Task 1-B, an examination of performance of lump coals in coal gasification, testing and evaluation of the properties of these coals, and evaluation of mine site coal upgrading methods; and Task 1-C/D, a laboratory investigation of coal agglomerates, including wafers, briquettes and pellets, in which the agglomerated coal fines were formed and tested, and the performance of various coal/binder combinations was recorded and evaluated, and factors affecting commercial scale coal agglomeration and gasification were evaluated. These three prior tasks are presented in this report in condensed form.

  19. Recovery of Rare Earth Elements from Coal and Coal Byproducts via a Closed Loop Leaching Process: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Richard [Battelle Memorial Inst., Columbus, OH (United States); Heinrichs, Michael [Battelle Memorial Inst., Columbus, OH (United States); Argumedo, Darwin [Battelle Memorial Inst., Columbus, OH (United States); Taha, Rachid [Battelle Memorial Inst., Columbus, OH (United States); Winecki, Slawomir [Battelle Memorial Inst., Columbus, OH (United States); Johnson, Kathryn [Battelle Memorial Inst., Columbus, OH (United States); Lane, Ann [Battelle Memorial Inst., Columbus, OH (United States); Riordan, Daniel [Battelle Memorial Inst., Columbus, OH (United States)

    2017-08-31

    REEs using the ADP technology. In AOI 1, Ohio coal sources with the potential to provide a consistent source of rare earth element concentrations above 300 parts per million will be identified. Coal sample inventories from West Virginia and Pennsylvania will also be assessed for purposes of comparison. Three methods of preparing the coal ash will be evaluated for their potential to enhance the technical feasibility and economics of REE recovery. Three sources of coal ash are targeted for evaluation of the economics of REE recovery in this project: (1) coal ash from power generation stations, to include fly ash and/or bottom ash, (2) ash generated in a lower temperature ashing process, and (3) ash residual from Battelle’s coal liquefaction process. Making use of residual ash from coal liquefaction processes directly leverages work currently being conducted by Battelle for DOE NETL in response to DE-FOA-0000981 entitled “Greenhouse Gas Emissions Reductions Research and Development Leading to Cost-Competitive Coal-to-Liquids Based Jet Fuel Production.” Using the sample characterization results and regional information regarding REE concentration, availability and cost, a TEA will be developed. The previously generated laboratory testing results for leaching and REE recovery via the ADP will be used to perform the TEA, along with common engineering assumptions for scale up of equipment and labor costs. Finally, upon validation of the economic feasibility of the process by the TEA, limited laboratory testing will be performed to support the design of a bench scale system. In a future project phase, it is envisioned that the bench scale system will be constructed and operated to prove the process on a continuous basis.

  20. E-commerce finally finds the coal industry

    Energy Technology Data Exchange (ETDEWEB)

    Hudson, M.

    2000-12-01

    In the last few months, new web sites have come online which are not only showcase for coal mining products and equipment but also act as sales platforms. A large set of sites deal with the purchase of coal and other raw materials. Most of them offer 24-hour news updates, a coal library and a reference section to help with financing, insurance and transportation of purchased coal. Another group focuses on the sale of equipment. Short writeups are given of 18 web sites. 1 photo.

  1. Advanced physical fine coal cleaning spherical agglomeration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-01

    The project included process development, engineering, construction, and operation of a 1/3 tph proof-of-concept (POC) spherical agglomeration test module. The POC tests demonstrated that physical cleaning of ultrafine coal by agglomeration using heptane can achieve: (1) Pyritic sulfur reductions beyond that possible with conventional coal cleaning methods; (2) coal ash contents below those which can be obtained by conventional coal cleaning methods at comparable energy recoveries; (3) energy recoveries of 80 percent or greater measured against the raw coal energy content; (4) complete recovery of the heptane bridging liquid from the agglomerates; and (5) production of agglomerates with 3/8-inch size and less than 30 percent moisture. Test results met or exceeded all of the program objectives. Nominal 3/8-inch size agglomerates with less than 20 percent moisture were produced. The clean coal ash content varied between 1.5 to 5.5 percent by weight (dry basis) depending on feed coal type. Ash reductions of the run-of-mine (ROM) coal were 77 to 83 percent. ROM pyritic sulfur reductions varied from 86 to 90 percent for the three test coals, equating to total sulfur reductions of 47 to 72 percent.

  2. Extraction, separation, and analysis of high sulfur coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Olesik, S.V.; Pekay, L.A.; Larkins, W. Jr. [comps.

    1992-05-31

    The work described in this report studies the removal of sulfur by oxidative interaction of various cupric salts with coal and also considers the possibility of removing organic sulfur by the selective interaction of supercritical ethanol with the organic coal matrix. Either one of these methods could potentially be used to pretreat coals before burning. The primary purpose of these studies is to ascertain the nature of the chemical reactions occurring, the chemical composition of the resultant products, and information on possible reaction mechanisms. This information should allow prediction of reasonable reaction conditions for the removal of organosulfur compound from coal.

  3. Coal-sand attrition system and its importance in fine coal cleaning. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mehta, R.K.; Zhu, Qinsheng

    1993-08-01

    It is known that ultra-fine coals are prerequisite for the deep cleaning of most US coal seams if environmental pollution arising from the use of such coals is to be minimized. Therefore, the production of finely liberated coal particles in conjunction with reduced heavy metal contaminants at low costs is desirable, if not mandatory. The liberation of intimately disseminated impurities from the coal matrix therefore, demands that the material be ground to a high degree of fineness. Similarily, some technologies for coal utilization require superfine particles (i.e., sizes less than ten microns). This implies additional costs for coal preparation plants due to the high energy and media costs associated with fine grinding operations. Besides, there are problems such as severe product contaminations due to media wear and impairment of the quality of coal. Hence, proper choice of grinding media type is important from the viewpoints of cost reduction and product quality. The use of natural quartz sand as grinding media in the comminution of industrial minerals in stirred ball mills has been indicated. The advantages of natural sand compared to steel media include low specific energy inputs, elimination of heavy metal contaminants and low media costs. In this work, the effect of rotor speed, solids concentration and feed-size are studied on four coals in conjunction with silica sand and steel shot. The results obtained are used to evaluate the suitability of silica sands as an alternative grinding media. for coal. Coal-sand and coal-steel systems are compared in terms of specific energy consumption, product fineness, media/wear contaminationanalysis and calorific values, liberation spectrum and particle shape characteristics. In general cleaner flotation concentrate was obtained from coals when they were ground with sand media. The zeta potential of coals was found to be different and lower when they ground with sand.

  4. Final Safety Assessment of Coal Tar as Used in Cosmetics

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    Coal Tar is a semisolid by-product obtained in the destructive distillation of bituminous coal, which functions in cosmetic products as a cosmetic biocide and denaturant-antidandruff agent is also listed as a function, but this is considered an over-the-counter (OTC) drug use. In 2002, Coal Tar was reported to the Food and Drug Administration (FDA) to be used in four formulations, all of which appear to be OTC drug products. Coal Tar is monographed by the FDA as Category I (safe and effective) OTC drug ingredient for use in the treatment of dandruff, seborrhoea, and psoriasis. Coal Tar is absorbed through the skin of animals and humans and is systemically distributed. Although the Cosmetic Ingredient Review (CIR) Expert Panel believes that Coal Tar use as an antidandruff ingredient in OTC drug preparations is adequately addressed by the FDA regulations, the Panel also believes that the appropriate concentration of use of Coal Tar in cosmetic formulations should be that level that does not have a biological effect in the user. Additional data needed to make a safety assessment include product types in which Coal Tar is used (other than as an OTC drug ingredient), use concentrations, and the maximum concentration that does not induce a biological effect in users.

  5. Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. [California Univ., Berkeley, CA (United States); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. [Columbia Univ., New York, NY (United States); Hu, W.; Zou, Y.; Chen, W. [Utah Univ., Salt Lake City, UT (United States); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. [Praxis Engineers, Inc., Milpitas, CA (United States)

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  6. Permeability changes in coal resulting from gas desorption. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Levine, J.R.; Johnson, P.W.

    1992-11-30

    This report documents studies on the effects of gas sorption on coal, with the intent of eventually evaluating how sorption and strain affect permeability. These studies were, carried out at the University of Alabama during the period from 1989 through 1992. Two major experimental methods were developed and used. In the strain experiments, electronic strain gauges were attached to polished blocks of coal in order to measure linear and volumetric swelling due to gas sorption. The effects of bedding plane orientation, of gas type, and of coal type were investigated. In the gravimetric experiment the weight of small samples of coal was measured during exposure to high pressure gases. Sample measurements were corrected for buoyancy effects and for sample swelling, and the results were plotted in the form of Langmuir isotherms. Experiments were conducted to determine the effect of grain size, coal type, moisture, and of sorbant gas. The advantage of this method is that it can be applied to very small samples, and it enabled comparison liptinite versus vitrinite concentrates, and kerogen rich versus kerogen depleted oil shales. Also included is a detailed discussion of the makeup of coal and its effect on gas sorption behavior.

  7. Applied research and evaluation of process concepts for liquefaction and gasification of western coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wiser, W. H.

    1980-09-01

    Fourteen sections, including five subsections, of the final report covering work done between June 1, 1975 to July 31, 1980 on research programs in coal gasification and liquefaction have been entered individually into EDB and ERA. (LTN)

  8. Healy Clean Coal Project: Healy coal firing at TRW Cleveland Test Facility. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Koyama, T.; Petrill, E.; Sheppard, D.

    1991-08-01

    A test burn of two Alaskan coals was conducted at TRW`s Cleveland test facility in support of the Healy Clean Coal Project, as part of Clean Coal Technology III Program in which a new power plant will be constructed using a TRW Coal Combustion System. This system features ash slagging technology combined with NO{sub x} and SO{sub x} control. The tests, funded by the Alaska Industrial Development and Export Authority (AIDEA) and TRW, were conducted to verify that the candidate Healy station coals could be successfully fired in the TRW coal combustor, to provide data required for scale-up to the utility project size requirements, and to produce sufficient flash-calcined material (FCM) for spray dryer tests to be conducted by Joy/NIRO. The tests demonstrated that both coals are viable candidates for the project, provided the data required for scale-up, and produced the FCM material. This report describes the modifications to the test facility which were required for the test burn, the tests run, and the results of the tests.

  9. Coal desulfurization by bacterial treatment and column flotation. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Kawatra, S.K. [Michigan Technological Univ., Houghton, MI (United States)

    1994-06-01

    A review of the literature showed that bacterial leaching, using the microorganism Thiobacillus ferrooxidans, was a very effective technique for removing pyrite from coal, as it could dissolve even the finest pyrite particles without the need for expensive reagents or extreme processing conditions. Unfortunately, bacterial leaching is also rather slow, and so the initial goal of this research was to decrease the leaching time as much as possible. However, this still left the bacteria needing approximately a week to remove half of the pyritic sulfur, and so a faster technique was sought. Since it had been reported in the literature that T. ferrooxidans could be used to depress the flotation of pyrite during froth flotation of coal, this was investigated further. By studying the recovery mechanisms of coal-pyrite in froth flotation, it was found that pyrite was being recovered by entrainment and by locking to coal particles, not by true flotation of hydrophobic pyrite. Therefore, no pyrite depressant could be of any significant benefit for keeping pyrite out of the coal froth product, and it was much more important to prevent entrainment from occurring. Countercurrent flotation columns were invented to essentially eliminate entrainment effects, by washing the froth and reducing mixing of the froth and tailings products. Existing flotation columns tend to be quite simple, and in order to give reasonable product quality they must be very tall (typically 30--45 feet). As a result, they have difficulty in handling the high froth volumes which occur in coal flotation, and are awkward to install in existing plants. The bulk of this project therefore concentrated on developing an improved coal flotation column, and testing it under actual plant conditions.

  10. Surface magnetic enhancement for coal cleaning. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, J.Y.

    1992-10-01

    The program consisted of a fundamental study to define the chemistry for the interactions between magnetic reagent and mineral and coal particles, a laboratory study to determine the applicability of this technology on coal cleaning, and a parameter study to evaluate the technical and economical feasibility of this technology for desulfurization and de-ashing under various processing schemes. Surface magnetic enhancement using magnetic reagent is a new technology developed at the Institute. This technology can be applied to separate pyrite and other minerals particles from coal with a magnetic separation after adsorbing magnetic reagent on the surface of pyrite and other minerals particles. Particles which have absorbed magnetic reagent are rendered magnetic. The adsorption can be controlled to yield selectivity. Thus, the separation of traditionally nonmagnetic materials with a magnetic separator can be achieved. Experiments have been performed to demonstrate the theoretical fundamentals and the applications of the technology. Adsorbability, adsorption mechanisms, and adsorption selectivity are included in the fundamental study. The effects of particle size, magnetic reagent dosage, solid contents, magnetic matrix, applied magnetic field strengths, retention times, and feed loading capacities are included in the application studies. Three coals, including Illinois No. 6, Lower Kittanning and Pocahontas seams, have been investigated. More than 90% pyritic sulfur and ash reductions have been achieved. Technical and economic feasibilities of this technology have been demonstrated in this study. Both are competitive to that of the froth flotation approach for coal cleaning.

  11. Analysis of chemical coal cleaning processes. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1980-06-01

    Six chemical coal cleaning processes were examined. Conceptual designs and costs were prepared for these processes and coal preparation facilities, including physical cleaning and size reduction. Transportation of fine coal in agglomerated and unagglomerated forms was also discussed. Chemical cleaning processes were: Pittsburgh Energy Technology Center, Ledgemont, Ames Laboratory, Jet Propulsion Laboratory (two versions), and Guth Process (KVB). Three of the chemical cleaning processes are similar in concept: PETC, Ledgemont, and Ames. Each of these is based on the reaction of sulfur with pressurized oxygen, with the controlling factor being the partial pressure of oxygen in the reactor. All of the processes appear technically feasible. Economic feasibility is less certain. The recovery of process chemicals is vital to the JPL and Guth processes. All of the processes consume significant amounts of energy in the form of electric power and coal. Energy recovery and increased efficiency are potential areas for study in future more detailed designs. The Guth process (formally designed KVB) appears to be the simplest of the systems evaluated. All of the processes require future engineering to better determine methods for scaling laboratory designs/results to commercial-scale operations. A major area for future engineering is to resolve problems related to handling, feeding, and flow control of the fine and often hot coal.

  12. Coal anion structure and chemistry of coal alkylation. Final report, March 1, 1979-February 29, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Stock, L.M.

    1980-01-01

    In accord with Task 1, some ether cleavage reactions were carried out in two different media - potassium/naphthalene/tetrahydrofuran and potassium/ ammonia - so that the merits and demerits of the two methods could be compared. Preliminary results suggest that both systems yield the same products, and that the ammonia medium is more convenient to work with, because of the absence of by-products such as reduced naphthalenes and tetralin. Dialkyl ethers were found to be least reactive compounds while the benzyl and phenyl ethers were found to be most reactive, as would be expected. The reductive alkylation of coal was carried out in ammonia at 25/sup 0/C. The tetrahydrofuran solubility of the reaction product was surprisingly low. We have obtained additional /sup 13/C)/sup 1/H) nmr data for tetrahydrofuran-soluble butylated coal and some model compounds; obtained additional Styragel(R) chromatography data of tetrahydrofuran-soluble coal labelled with 98%-enriched butyl-1,1-d/sub 2/ iodide; and obtained /sup 2/D nmr spectra of all the deuterium-labelled, tetrahydrofuran-soluble coal products. In accord with Task 4, we have undertaken a review of the information now available concerning the nature of Illinois No. 6 coal. Also, the effects of organic additives on the exchange reactions between tetralin-d/sub 12/ and diphenyl-methane and on the thermal cleavage reactions of several model compounds in tetralin were investigated to probe the relationship between structure and reactivity. The exchange reaction can be accelerated by coal, asphaltene-preasphaltene fractions derived from coal, compounds with labile bonds, or compounds which can be reduced readily. The pyridine-insoluble coal product, acids, and bases are inactive toward the exchange reaction.

  13. Demonstrated reserve base for coal in New Mexico. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, G.K.

    1995-02-01

    The new demonstrated reserve base estimate of coal for the San Juan Basin, New Mexico, is 11.28 billion short tons. This compares with 4.429 billion short tons in the Energy Information Administration`s demonstrated reserve base of coal as of January 1, 1992 for all of New Mexico and 2.806 billion short tons for the San Juan Basin. The new estimate includes revised resource calculations in the San Juan Basin, in San Juan, McKinley, Sandoval, Rio Arriba, Bernalillo and Cibola counties, but does not include the Raton Basin and smaller fields in New Mexico. These estimated {open_quotes}remaining{close_quotes} coal resource quantities, however, include significant adjustments for depletion due to past mining, and adjustments for accessibility and recoverability.

  14. 21st Century Coal: Advanced Technology and Global Energy Solution

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-06-01

    Coal currently supplies with more than 40% of the world electricity consumption and it essential input of around 70% of world steel production, representing around 30% of the world primary energy supply. This is because coal is cheap, abundant, accessible, widely distributed and easy energy to transport, store and use. For these features, coal is projected to be intensively used in the future. Production and use of coal present a series of issues throughout the whole value chain. While existing technology allows addressing most of them (safety at work, land restoration, mercury, NOx and sulphur emissions avoidance, etc.), CO2 emissions continues to be the biggest challenge for coal use in the future. This report focuses on the technology path to near-zero emissions including useful insights in advanced coal power generation technologies and Carbon Capture, Utilisation and Storage, a promising technology with a large potential which can push Carbon Capture and Storage competitiveness. In addition, the report shows the features of the new generation of coal-fired power plants in terms of flexibility for dynamic operation and grid stability, requirements increasingly needed to operate on grids with significant wind and solar generation.

  15. Semiconductor electrochemistry of coal pyrite. Final technical report, September 1990--September 1995

    Energy Technology Data Exchange (ETDEWEB)

    Osseo-Asare, K.; Wei, Dawei

    1996-01-01

    This project seeks to advance the fundamental understanding of the physico-chemical processes occurring at the pyrite/aqueous interface, in the context of coal cleaning, coal desulfurization, and acid mine drainage. Central to this research is the use of synthetic microsize particles of pyrite as model microelectrodes to investigate the semiconductor electrochemistry of pyrite. The research focuses on: (a) the synthesis of microsize particles of pyrite in aqueous solution at room temperature, (b) the formation of iron sulfide complex, the precursor of FeS or FeS{sub 2}, and (c) the relationship between the semiconductor properties of pyrite and its interfacial electrochemical behavior in the dissolution process. In Chapter 2, 3 and 4, a suitable protocol for preparing microsize particles of pyrite in aqueous solution is given, and the essential roles of the precursors elemental sulfur and ``FeS`` in pyrite formation are investigated. In Chapter 5, the formation of iron sulfide complex prior to the precipitation of FeS or FeS{sub 2} is investigated using a fast kinetics technique based on a stopped-flow spectrophotometer. The stoichiometry of the iron sulfide complex is determined, and the rate and formation constants are also evaluated. Chapter 6 provides a summary of the semiconductor properties of pyrite relevant to the present study. In Chapters 7 and 8, the effects of the semiconductor properties on pyrite dissolution are investigated experimentally and the mechanism of pyrite dissolution in acidic aqueous solution is examined. Finally, a summary of the conclusions from this study and suggestions for future research are presented in Chapter 9.

  16. Biological production of ethanol from coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-01

    Due to the abundant supply of coal in the United States, significant research efforts have occurred over the past 15 years concerning the conversion of coal to liquid fuels. Researchers at the University of Arkansas have concentrated on a biological approach to coal liquefaction, starting with coal-derived synthesis gas as the raw material. Synthesis gas, a mixture of CO, H{sub 2}, CO{sub 2}, CH{sub 4} and sulfur gases, is first produced using traditional gasification techniques. The CO, CO{sub 2} and H{sub 2} are then converted to ethanol using a bacterial culture of Clostridium 1jungdahlii. Ethanol is the desired product if the resultant product stream is to be used as a liquid fuel. However, under normal operating conditions, the ``wild strain`` produces acetate in favor of ethanol in conjunction with growth in a 20:1 molar ratio. Research was performed to determine the conditions necessary to maximize not only the ratio of ethanol to acetate, but also to maximize the concentration of ethanol resulting in the product stream.

  17. Bottrop coal oil plant. Final report. Kohleoelanlage Bottrop. Abschlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    1988-03-01

    The production of liquid hydrocarbons from local hard coal was one major point in the master program 'energy research' of the Federal Government and the technology program of the Government of the Federal State of North-Rhine Westphalia in 1974. On the basis of the experience made by the IG-Farbenindustrie AG with coal hydrogenation during World War II., catalytic hydrogenation under pressure was adjusted to the present state-of-the-art of plant and process engineering. In contrast to 700 bar in the IG process, process pressure now is 300 bar, coal throughput has increased by about 50%, and the mechanical thermal processes of residue processing were replaced by modern distillation processes. The coal liquefaction plant in Bottrop with a daily throughput of 200 t is the result of these developments. In 1981 it was officially put into operation and during the experimental operation lasting 5 1/2 years there have been numerous modifications as regards its profitability, operational reliability, and environmental compatibility. In this connection special attention was focused on the system of feed material heating, the reactor concept, the integration of the refining stage and the processing of the hydrogenation residue. (RB).

  18. Coal-fired high performance power generating system. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-31

    As a result of the investigations carried out during Phase 1 of the Engineering Development of Coal-Fired High-Performance Power Generation Systems (Combustion 2000), the UTRC-led Combustion 2000 Team is recommending the development of an advanced high performance power generation system (HIPPS) whose high efficiency and minimal pollutant emissions will enable the US to use its abundant coal resources to satisfy current and future demand for electric power. The high efficiency of the power plant, which is the key to minimizing the environmental impact of coal, can only be achieved using a modern gas turbine system. Minimization of emissions can be achieved by combustor design, and advanced air pollution control devices. The commercial plant design described herein is a combined cycle using either a frame-type gas turbine or an intercooled aeroderivative with clean air as the working fluid. The air is heated by a coal-fired high temperature advanced furnace (HITAF). The best performance from the cycle is achieved by using a modern aeroderivative gas turbine, such as the intercooled FT4000. A simplified schematic is shown. In the UTRC HIPPS, the conversion efficiency for the heavy frame gas turbine version will be 47.4% (HHV) compared to the approximately 35% that is achieved in conventional coal-fired plants. This cycle is based on a gas turbine operating at turbine inlet temperatures approaching 2,500 F. Using an aeroderivative type gas turbine, efficiencies of over 49% could be realized in advanced cycle configuration (Humid Air Turbine, or HAT). Performance of these power plants is given in a table.

  19. Surface Properties of Photo-Oxidized Bituminous Coals: Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    Natural weathering has a detrimental effect on the hydrophobic nature of coal, which in turn can influence clean-coal recovery during flotation. Few techniques are available that can establish the quality of coal surfaces and that have a short analysis time to provide input for process control. Luminescence emissions which can be quantified with an optical microscope and photometer system, are measurably influenced by degree of weathering as well as by mild storage deterioration. In addition, it has been shown that when vitrinite is irradiated with a relatively high intensity flux of violet- or ultraviolet- light in the presence of air, photo-oxidation of the surface occurs. The combination of measuring the change in luminescence emission intensity with degree of surface oxidation provided the impetus for the current investigation. The principal aim of this research was to determine whether clear correlations could be established among surface oxygen functionality, hydrophobicity induced by photo-oxidation, and measurements of luminescence intensity and alteration. If successful, the project would result in quantitative luminescence techniques based on optical microscopy that would provide a measure of the changes in surface properties as a function of oxidation and relate them to coal cleanability. Two analytical techniques were designed to achieve these goals. Polished surfaces of vitrain bands or a narrow size fraction of powdered vitrain concentrates were photo-oxidized using violet or ultraviolet light fluxes and then changes in surface properties and chemistry were measured using a variety of near-surface analytical techniques. Results from this investigation demonstrate that quantitative luminescence intensity measurements can be performed on fracture surfaces of bituminous rank coals (vitrains) and that the data obtained do reveal significant variations depending upon the level of surface oxidation. Photo-oxidation induced by violet or ultraviolet light

  20. Development and testing of commercial-scale, coal-fired combustion systems: Phase III. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Based on studies that indicated a large potential for significantly increased coal-firing in the commercial sector, the U.S. Department of Energy`s Pittsburgh Energy Technology Center (PETC) sponsored a multi-phase development effort for advanced coal combustion systems. This Final Report presents the results of the last phase (Phase III) of a project for the development of an advanced coal-fired system for the commercial sector of the economy. The project performance goals for the system included dual-fuel capability (i.e., coal as primary fuel and natural gas as secondary fuel), combustion efficiency exceeding 99 percent, thermal efficiency greater than 80 percent, turndown of at least 3:1, dust-free and semi-automatic dry ash removal, fully automatic start-up with system purge and ignition verification, emissions performance exceeding New Source Performance Standards (NSPS) and approaching those produced by oil-fired, Commercial-sized units, and reliability, safety, operability, maintainability, and service life comparable to oil-fired units. The program also involved a site demonstration at a large facility owned by Striegel Supply Company, a portion of which was leased to MTCI. The site, mostly warehouse space, was completely unheated and the advanced coal-fired combustion system was designed and sized to heat this space. Three different coals were used in the project, one low and one high sulfur pulverized Pittsburgh No. 8 coal, and a micronized low volatile, bituminous coal. The sorbents used were Pfizer dolomitic limestone and an Anvil lime. More than 100 hours of screening test`s were performed to characterize the system. The parameters examined included coal firing rate, excess air level, ash recycle rate, coal type, dolomitic limestone feed rate, and steam injection rate. These tests indicated that some additional modifications for coal burning in the system were required.

  1. Investigation of formation of nitrogen compounds in coal combustion. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Blair, D.W.; Crane, I.D.; Wendt, J.O.L.

    1983-10-01

    This is the final report on DOE contract number DE-AC21-80MC14061. It concerns the formation of nitrogen oxide from fuel-bound nitrogen during coal combustion. The work reported was divided into three tasks. They addressed problems of time-resolving pyrolysis rates of coal under simulated combustion conditions, the combustion of the tar that results from such pyrolysis, and theoretical modeling of the pyrolysis process. In all of these tasks, special attention was devoted to the fate of coal nitrogen. The first two tasks were performed by Exxon Research and Engineering Company. 49 references.

  2. Characterization and evaluation of washability of Alaskan coals: Fifty selected seams from various coal fields: Final technical report, September 30, 1976-February 28, 1986. [50 coal seams

    Energy Technology Data Exchange (ETDEWEB)

    Rao, P.D.

    1986-09-01

    This final report is the result of a study initiated in 1976 to obtain washability data for Alaskan coals, to supplement the efforts of the US Department of Energy in their ongoing studies on washability of US coals. Washability characteristics were determined for fifty coal samples from the Northern Alaska, Chicago Creek, Unalakleet, Nenana, Matanuska, Beluga, Yentna and Herendeen Bay coal fields. The raw coal was crushed to 1-1/2 inches, 3/8 inch, 14 mesh and 65 mesh top sizes, and float-sink separations were made at 1.30, 1.40 and 1.60 specific gravities. A limited number of samples were also crushed to 200 and 325 mesh sizes prior to float-sink testing. Samples crushed to 65 mesh top size were also separated at 1.60 specific gravity and the float and sink products were characterized for proximate and ultimate analyses, ash composition and ash fusibility. 72 refs., 79 figs., 57 tabs.

  3. Healy Clean Coal Project, Healy, Alaska final Environmental Monitoring Plan

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-14

    This Environmental Monitoring Plan (EMP) provides the mechanism to evaluate the integrated coal combustion/emission control system being demonstrated by the Healy Clean Coal Project (HCCP) as part-of the third solicitation of the US Department of Energy (DOE) Clean Coal Technology Demonstration Program (CCT-III). The EMP monitoring is intended to satisfy two objectives: (1) to develop the information base necessary for identification, assessment, and mitigation of potential environmental problems arising from replication of the technology and (2) to identify and quantify project-specific and site-specific environmental impacts predicted in the National Environmental Policy Act (NEPA) documents (Environmental Impact Statement and Record of Decision). The EMP contains a description of the background and history of development of the project technologies and defines the processes that will take place in the combustion and spray dryer absorber systems, including the formation of flash-calcined material (FCM) and its use in sulfur dioxide (SO{sub 2}) removal from the flue gases. It also contains a description of the existing environmental resources of the project area. The EMP includes two types of environmental monitoring that are to be used to demonstrate the technologies of the HCCP: compliance monitoring and supplemental monitoring. Compliance monitoring activities include air emissions, wastewater effluents, and visibility. Monitoring of these resources provide the data necessary to demonstrate that the power plant can operate under the required state and federal statutes, regulations, and permit requirements.

  4. Phase equilibria in coal conversion processes. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Chao, K.C.

    1986-10-01

    Fluid-phase equilibrium data have been determined in simulation of coal liquefaction process conditions. Gas-liquid equilibrium and liquid-liquid equilibrium of water-containing mixtures have been the central interest while some water-free mixtures were also investigated. Experimental gas-liquid equilibrum studies were made for: hydrogen + water + m-cresol; hydrogen + water + quinoline; hydrogen + water + n-decane; methane + water + n-hexadecane; carbon dioxide + water + diethylamine; carbon dioxide + 1-hexadecene; carbon dioxide + n-propylcyclohexane; carbon dioxide + n-octadecane; carbon dioxide + phenyloctane; and propane + n-butyraldehyde. Mutual liquid-liquid solubilities have been determined for: water + m-cresol; water + quinoline; water + indoline; water + 1,2,3,4 - tetrahydroquinoline; water + thianaphthene; and water + 9,10 - dihydrophenanthrene. The Cubic Chain-of-Rotators (CCOR) equation of state was modified to extend to strongly polar substances. The modified equation was used to correlate the new fluid phase equilibrium data of water-containing mixtures. The original CCOR equation was used to correlate the vaporization equilibrium data of an Illinois coal liquid and a Wyoming coal liquid described in our previous report AP-3450. 107 refs., 32 figs., 19 tabs.

  5. Sulfur release from Ohio coals and sorbent kinetics in pulverized coal flames. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Essenhigh, R. [Ohio State Univ., Columbus, OH (United States). Robinson Lab.

    1992-08-01

    In this report we describe the results of investigations into the structure of combustion and sulfur release profiles from coal burning in One-Dimensional P.C. flames using a furnace of unique design for the measurements. Selected measurements were also-carried out in a special high-intensity furnace also of unique design. The formal project work started in late Fall 1989, with unfunded preliminary work in the months prior to that. The process of limestone injection into the flame to control sulfur oxides emissions is a long-standing concept that has been given particular formulation in the LIMB process, and studies of such systems provide bases for commercial system economics. Problems with LIMB and related systems indicated need for better understanding of, jointly, the sulfur release from the coal and the sorbent behavior by the limestone. The investigations as reported in Vol. 1 of this Report used 14 different coals under a range of different initial and operating conditions, and the resulting measurements have provided a database of major proportions, as tabulated in the attached Volumes 2, 3, 4, 5, 6, and 7 of this report. This database consists of sets of measurements totalling about 45,000 entries for all independent and dependent parameters involved. The independent parameters included: coal type (analysis), firing rate, stoichiometry (fuel/air ratio), and sorbent content of the

  6. Supercritical fluid thermodynamics for coal processing. Final report, September 15, 1988--September 14, 1991

    Energy Technology Data Exchange (ETDEWEB)

    van Swol, F. [Illinois Univ., Urbana, IL (United States). Dept. of Chemical Engineering; Eckert, C.A. [Georgia Inst. of Tech., Atlanta, GA (United States). School of Chemical Engineering

    1988-09-15

    The main objective of this research is to develop an equation of state that can be used to predict solubilities and tailor supercritical fluid solvents for the extraction and processing of coal. To meet this objective we have implemented a two-sided. approach. First, we expanded the database of model coal compound solubilities in higher temperature fluids, polar fluids, and fluid mixtures systems. Second, the unique solute/solute, solute/cosolvent and solute/solvent intermolecular interactions in supercritical fluid solutions were investigated using spectroscopic techniques. These results increased our understanding of the molecular phenomena that affect solubility in supercritical fluids and were significant in the development of an equation of state that accurately reflects the true molecular makeup of the solution. (VC)

  7. Alteration of coal by weathering. Final report; Alteracion del carbon a la intemperie. Informe final

    Energy Technology Data Exchange (ETDEWEB)

    Ramon Alvarez, W. [Instituto Nacional del Carbon, Oveido (Spain)

    1997-11-01

    Weathering studies were carried out on coal piles: firstly using a typical sophisticated blend used by the Spanish Steel Company ENSIDESA (13 different coals). A pile of 100 t of this blend was stored at INCAR`s stockyard and laboratory analysis and tests, pilot and semi-industrial scale carbonization tests were carried out at different intervals of time during about one year.

  8. Kinetics assisted design of catalysts for coal liquefaction. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Klein, M.T.; Foley, H.C.; Calkins, W.H.; Scouten, C.

    1998-02-01

    The thermal and catalytic reactions of 4-(1-naphthylmethyl)bibenzyl (NBBM), a resid and coal model compound, were examined. Catalytic reaction of NBBM was carried out at 400 C under hydrogen with a series of transition metal-based catalytic materials including Fe(CO){sub 4}PPh{sub 3}, Fe(CO){sub 3}(PPh{sub 3}){sub 2}, Fe(CO){sub 2}(PPh{sub 3}){sub 2}CS{sub 2}, Fe(CO){sub 5}, Mo(CO){sub 6}, Mn{sub 2}(CO){sub 10}, Fe{sub 2}O{sub 3} and MoS{sub 2}. Experimental findings and derived mechanistic insights were organized into molecular-level reaction models for NBBM pyrolysis and catalysis. Hydropyrolysis and catalysis reaction families occurring during NBBM hydropyrolysis at 420 C were summarized in the form of reaction matrices which, upon exhaustive application to the components of the reacting system, yielded the mechanistic reaction model. Each reaction family also had an associated linear free energy relationship (LFER) which provided an estimate of the rate constant k{sub i} given a structural property of species i or its reaction. Including the catalytic reaction matrices with those for the pyrolysis model provided a comprehensive NBBM catalytic reaction model and allowed regression of fundamental LFER parameters for the catalytic reaction families. The model also allowed specification of the property of an optimal catalyst. Iron, molybdenum and palladium were predicted to be most effective for model compound consumption. Due to the low costs associated with iron and its disposal, it is a good choice for coal liquefaction catalysis and the challenge remains to synthesize small particles able to access the full surface area of the coal macromolecule.

  9. Highly dispersed catalysts for coal liquefaction. Phase 1 final report, August 23--November 22, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Hirschon, A.S.; Wilson, R.B. [SRI International, Menlo Park, CA (United States); Ghaly, O. [Bechtel Corp., San Francisco, CA (United States)

    1995-03-22

    The ultimate goal of this project is to develop novel processes for making the conversion of coal into distillable liquids competitive to that of petroleum products in the range of $25/bbl. The objectives of Phase 1 were to determine the utility of new precursors to highly dispersed catalysts for use of syngas atmospheres in coal liquefaction, and to estimate the effect of such implementation on the cost of the final product. The project is divided into three technical tasks. Tasks 1 and 2 are the analyses and liquefaction experiments, respectively, and Task 3 deals with the economic effects of using these methods during coal liquefaction. Results are presented on the following: Analytical Support--screening tests and second-stage conversions; Laboratory-Scale Operations--catalysts, coal conversion in synthetic solvents, Black Thunder screening studies, and two-stage liquefaction experiments; and Technical and economic Assessment--commercial liquefaction plant description, liquefaction plant cost; and economic analysis.

  10. Advanced coal fueled industrial cogeneration gas turbine system. Final report, June 1986--April 1994

    Energy Technology Data Exchange (ETDEWEB)

    LeCren, R.T.

    1994-05-01

    Demonstration of a direct coal-fueled gas turbine system that is environmentally, technically, and economically viable depends on the satisfactory resolution of several key issues. Solar Turbines, Incorporates technical approach to these issues was to advance a complete direct coal-fueled gas turbine system that incorporated near-term technology solutions to both historically demonstrated problem areas such as deposition, erosion, and hot end corrosion, and to the emergent environmental constraints based on NO{sub x}, SO{sub x}, and particulates. Solar`s program approach was keyed to the full commercialization of the coal-fueled cogeneration gas turbine which would occur after extended field verification demonstrations conducted by the private sector. The program was structured in three phases plus an optional fourth phase: Phase 1 -- system description; Phase 2 -- component development; Phase 3 -- prototype system verification; and Phase 4 -- field evaluation.

  11. Simulated coal gas MCFC power plant system verification. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-07-30

    The objective of the main project is to identify the current developmental status of MCFC systems and address those technical issues that need to be resolved to move the technology from its current status to the demonstration stage in the shortest possible time. The specific objectives are separated into five major tasks as follows: Stack research; Power plant development; Test facilities development; Manufacturing facilities development; and Commercialization. This Final Report discusses the M-C power Corporation effort which is part of a general program for the development of commercial MCFC systems. This final report covers the entire subject of the Unocal 250-cell stack. Certain project activities have been funded by organizations other than DOE and are included in this report to provide a comprehensive overview of the work accomplished.

  12. Dandruff, seborrheic dermatitis, and psoriasis drug products containing coal tar and menthol for over-the-counter human use; amendment to the monograph. Final rule

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-03-15

    The Food and Drug Administration (FDA) is issuing a final rule amending the final monograph (FM) for over-the-counter (OTC) dandruff, seborrheic dermatitis, and psoriasis drug products to include the combination of 1.8 percent coal tar solution and 1.5 percent menthol in a shampoo drug product to control dandruff. FDA did not receive any comments or data in response to its previously proposed rule to include this combination. This final rule is part of FDA's ongoing review of OTC drug products.

  13. Appalachian Clean Coal Technology Consortium. Final report, October 10, 1994--March 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.H.; Parekh, B.K.; Meloy, T.

    1997-12-31

    The Appalachian Clean Coal Technology Consortium is a group comprised of representatives from the Virginia Polytechnic Institute and State University, West Virginia University, and the University of Kentucky Center for Applied Energy Research, that was formed to pursue research in areas related to the treatment and processing of fine coal. Each member performed research in their respective areas of expertise and the report contained herein encompasses the results that were obtained for the three major tasks that the Consortium undertook from October, 1994 through March, 1997. In the first task, conducted by Virginia Polytechnic Institute, novel methods (both mechanical and chemical) for dewatering fine coal were examined. In the second task, the Center for Applied Energy Research examined novel approaches for destabilization of [highly stable] flotation froths. And in the third task, West Virginia University developed physical and mathematical models for fine coal spirals. The Final Report is written in three distinctive chapters, each reflecting the individual member`s task report. Recommendations for further research in those areas investigated, as well as new lines of pursuit, are suggested.

  14. Rheology of coal-water slurries prepared by the high-pressure roll mill grinding of coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Fuerstenau, D.W.; De, A.

    1996-08-01

    The preparation of coal water slurries to replace fuel oil for direct combustion has become an important field in modem coal technology. The U.S. Department of Energy has planned or has underway several demonstration projects to burn coal-water slurries to replace fuel oil is attractive not only because there is an assured domestic supply of coal, but also on various technoeconomic grounds. Coal-water slurries combine the handling flexibility of fuel oil in power plants and various other industrial applications. This report discusses the rheology of coal-water slurries and the correlation to the coal preparation by grinding with a choke-fed high pressure roll mill. Performance of the roll mills and energy consumption are described.

  15. Upgraded modified forms of bituminous coal for the removal of safranin-T dye from aqueous solution.

    Science.gov (United States)

    Shaban, Mohamed; Abukhadra, Mostafa R; Shahien, Mohamed G; Khan, Aftab Aslam Parwaz

    2017-08-01

    investigated for more physical interpretation of the adsorption process. The calculated parameters (number of adsorbed molecules per site and number of receptor sites per unit mass) reflected the role of modification processes in the adsorption behavior of safranin. Graphical abstract High volatile bituminous coal and its modified forms have been used for the removal of Safranin-T dye from aqueous solution.

  16. Vaporization of trace element species from coal under gasification and combustion conditions: Final report

    Energy Technology Data Exchange (ETDEWEB)

    None

    1989-03-01

    The objective of this project was to establish the chemical forms and relative abundance of trace inorganic vapor species in coal during combustion and gasification. A joint experimental and calculational program to observe the vaporization of Illinois No. 6 bituminous and Wyodak subbituminous was performed. Experimental studies were performed by Knudsen cell mass spectroscopy on samples of each coal that were ashed at low temperature by an oxygen plasma. To simulate actual coal more closely, some samples were only partially ashed to retain more of the original organic components. Vapor species were identified and their abundances measured over the temperature range 300-1700 K. In the first year of the program, vaporization from the coal ash alone was studied. Dynamic partial pressures were measured against temperature and time. Vapor species of 32 major or trace elements were identified. During the second year of the program, mass spectrometry experiments addressed the effects of added gases (O/sub 2/, CO/sub 2/, and H/sub 2/O) on the identities and abundances of trace element vapor species. Coincident with experimental studies, trace element vaporization behavior was evaluated by Gibbs energy minimization calculations. A data base including both solution and pure condensed and gaseous components was compiled. The behavior of Wyodak coal at 1 atm total pressure was evaluated over the temperature range 300--1800 K and the oxygen partial pressure range from 10/sup /minus/1/ to 10/sup /minus/25/ atm. Results were used to evaluate the effects on trace element volatility of several proposed strategies for containment removal. 13 refs., 23 figs., 23 tabs.

  17. Solution of underground mine gas emissions on surface of abandoned mining sites where steep deposited coal seams have been exploited

    Energy Technology Data Exchange (ETDEWEB)

    Takla, G.; Froml, K. [OKD, DPB, Paskov (Czech Republic)

    2005-07-01

    The solution of uncontrolled gas emissions from abandoned underground coal mine sites in Ostrava-Karvina coal-field to surface ground in connection with old mine shafts and drifts and with old mining workings in horizontal and inclined coal seams has many forms. It varies according to geological and mining conditions and the disposition of the site surface. Since four years the gas emission risk has appeared in the area of former exploited vertical coal seams within the historical centre of Orlova town, which is protected by State Monument Protection office. A project based on such special nature of mining-geological and urban conditions was elaborated and already implemented. (authors)

  18. Solution of the two identical ion Penning trap final state

    OpenAIRE

    Blackburn, W.; Brown, T L; Cozzo, E.; Moyers, B.; Crescimanno, M.

    2001-01-01

    We have derived a closed form analytic expression for the asymptotic motion of a pair of identical ions in a high precision Penning trap. The analytic solution includes the effects of special relativity and the Coulomb interaction between the ions. The existence and physical relevance of such a final state is supported by a confluence of theoretical, experimental and numerical evidence.

  19. Mulled coal: A beneficiated coal form for use as a fuel or fuel intermediate. Phase 1 feasibility studies: Final

    Energy Technology Data Exchange (ETDEWEB)

    1991-10-01

    Energy International is developing a technology that will create a staged formulation with the first coal form (Mulled Coal) that can be stored, transported, and pumped. Just prior to combustion, the Mulled Coal (MC) would be modified to provide the properties needed for proper atomization. This concept is an alternative to the expensive and energy intensive thermal drying processing of fine coal wet cakes. The material is suitable for both direct feed use in conventional and fluid bed combustors as well as on-site conversion to combustible slurries. By maintaining the coal form relatively close to the feed wet cake, only minor processing with low additive levels and low energy blending needed at the point of production. Its conversion to slurry or other use-feed form is made near the time of use and thus the requirements for stability, climatic control, and other storage, transport, and handling requirements are much less severe.

  20. Coal Reserves Data Base report. Final report on the Demonstrated Reserve Base (DRB) of coal in Wyoming

    Energy Technology Data Exchange (ETDEWEB)

    Jones, R.W.; Glass, G.B.

    1991-12-05

    The Coal Reserves Data Base (CRDB) Program is a cooperative data base development program sponsored by the Energy Information Administration (EIA). The objective of the CRDB Program is to involve knowledgeable coal resource authorities from the major coal-bearing regions in EIA`s effort to update the Nation`s coal reserves data. This report describes one of two prototype studies to update State-level reserve estimates. The CRDB data are intended for use in coal supply analyses and to support analyses of policy and legislative issues. They will be available to both Government and non-Government analysts. The data also will be part of the information used to supply United States energy data for international data bases and for inquiries from private industry and the public. (VC)

  1. Bioprocessing of lignite coals using reductive microorganisms. Final technical report, September 30, 1988--March 29, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, D.L.

    1992-03-29

    In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

  2. Improving the stability of coal slurries: Final report. [Polygalacturonic acid and gum tragacanth

    Energy Technology Data Exchange (ETDEWEB)

    Fogler, H.S.

    1988-12-01

    Polysaccharides were found to stabilize colloidal dispersions (such as coal particles and polystyrene latex particles) even at high ionic strengths. The stability studies with various kinds of polysaccharides showed that rod-like molecules (such as poly (galacturonic acid) and gum tragacanth) are much more effective stabilizers than highly-branched molecules such as arabinogalactan. This effective stabilization with the rod-like molecules was found to result from the adsorption of polysaccharides on the particles, i.e., the steric stabilization mechanism. The stability depends significantly on the solution pH, the molecular weight and the surface charge of particles. Adsorption isotherms, the zeta potential and the conformation of adsorbed molecules (the steric layer thicknesses) were measured as a function of the solution pH, the molecular weight and the surface charge. Photon correlation spectroscopy studies showed that the conformation of adsorbed molecules is strongly dependent on the solution pH, the molecular weight and the surface charge, suggesting that the dependence of stability on these parameters is due to the change of the conformation of the molecules adsorbed on the surface. In addition, the solution pH has a significant effect on the flocculation behavior of particles and can be modulated to bring about peptization of particles. This type of stabilization is referred to as electrosteric stabilization whereby steric stabilization is induced by changing the electrical properties of the system (the solution pH in this case). 41 refs., 43 figs., 10 tabs.

  3. Chemical kinetics and transport processes in supercritical fluid extraction of coal. Final report, August 10, 1990--December 30, 1992

    Energy Technology Data Exchange (ETDEWEB)

    McCoy, B.J.; Smith, J.M.; Wang, M.; Zhang, C.J.

    1993-02-01

    The overall objective of this project was to study the supercritical fluid extraction of hydrocarbons from coal. Beyond the practical concern of deriving products from coal, the research has provided insights into the structure, properties, and reactivities of coal. Information on engineering fundamentals of coal thermolysis and extraction, including physical and chemical processes, is presented in this final report. To accomplish the goals of the project we developed continuous-flow experiments for fixed-bed samples of coal that allow two types of analysis of the extract: continuous spectrophotometric absorbance measurements of the lumped concentration of extract, and chromatographic determinations of molecular-weight distributions as a function of time. Thermolysis of coal yields a complex mixture of many extract products whose molecular-weight distribution (MWD) varies with time for continuous-flow, semibatch experiments. The flow reactor with a differential, fixed bed of coal particles contacted by supercritical t-butanol was employed to provide dynamic MWD data by means of HPLC gel permeation chromatography of the extract. The experimental results, time-dependent MWDs of extract molecules, were interpreted by a novel mathematical model based on continuous-mixture kinetics for thermal cleavage of chemical bonds in the coal network. The parameters for the MWDs of extractable groups in the coal and the rate constants for one- and two-fragment reaction are determined from the experimental data. The significant effect of temperature on the kinetics of the extraction was explained in terms of one- and two-fragment reactions in the coal.

  4. Viscosity of aqueous solution of fulvic acid extracted from weathered coal

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Qijin; Zhang Dehe

    1987-06-01

    The reduced viscosity of aqueous solution of fulvic acid extracted from a weathered coal and its concentration relationship (eta/sub s/ C approx C) were determined at pH 6.25 and 25 C. Experimental results show that the viscosity of fulvic acid from weathered coal is similar to that of polyelectrolyte. The intrinsic viscosity eta obtained by Fuoss's method and extrapolation method, was found to be 50 and 6.5 ml/g respectively. The difference between these two values (43.5) is comparatively greater than 13.75, the difference for soil fulvic acid determined by Schnitzer. In the presence of various amounts of neutral salt, the eta/sub S//sub p//(C approx. C) curves converge to the same (eta) value, that is different from those of soil fulvic acid, too. The theoretical B value calculated according to Sanyal's method is 0.66 (l/mol) /sup -1/, which is much smaller than the experimental B value, 5.3 (l/mol) /sup -1/. Consequently, it is postulated that fulvic acid from weathered coal has a rather rigid molecular chain structure, while soil fulvic acid has a more flexible one.

  5. Assessment of underground coal gasification in bituminous coals: potential UCG products and markets. Final report, Phase I

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-01-31

    The following conclusions were drawn from the study: (1) The US will continue to require new sources of energy fuels and substitutes for petrochemical feedstocks into the foreseeable future. Most of this requirement will be met using coal. However, the cost of mining, transporting, cleaning, and preparing coal, disposing of ash or slag and scrubbing stack gases continues to rise; particularly, in the Eastern US where the need is greatest. UCG avoids these pitfalls and, as such, should be considered a viable alternative to the mining of deeper coals. (2) Of the two possible product gases LBG and MBG, MBG is the most versatile. (3) The most logical use for UCG product in the Eastern US is to generate power on-site using a combined-cycle or co-generation system. Either low or medium Btu gas (LBG or MBG) can be used. (4) UCG should be an option whenever surface gasification is considered; particularly, in areas where deeper, higher sulfur coal is located. (5) There are environmental and social benefits to use of UCG over surface gasification in the Eastern US. (6) A site could be chosen almost anywhere in the Illinois and Ohio area where amenable UCG coal has been determined due to the existence of existing transportation or transmission systems. (7) The technology needs to be demonstrated and the potential economic viability determined at a site in the East-North-Central US which has commercial quantities of amenable bituminous coal before utilities will show significant interest.

  6. Potential for thermal coal and Clean Coal Technology (CCT) in the Asia-Pacific. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, C.J.; Long, S.

    1991-11-22

    The Coal Project was able to make considerable progress in understanding the evolving energy situation in Asia and the future role of coal and Clean Coal Technologies. It is clear that there will be major growth in consumption of coal in Asia over the next two decades -- we estimate an increase of 1.2 billion metric tons. Second, all governments are concerned about the environmental impacts of increased coal use, however enforcement of regulations appears to be quite variable among Asian countries. There is general caution of the part of Asian utilities with respect to the introduction of CCT`s. However, there appears to be potential for introduction of CCT`s in a few countries by the turn of the century. It is important to emphasize that it will be a long term effort to succeed in getting CCT`s introduced to Asia. The Coal Project recommends that the US CCT program be expanded to allow the early introduction of CCT`s in a number of countries.

  7. Synthesis of hydroxy sodalite from coal fly ash using waste industrial brine solution.

    Science.gov (United States)

    Musyoka, Nicholas M; Petrik, Leslie F; Balfour, Gillian; Gitari, Wilson M; Hums, Eric

    2011-01-01

    The effect of using industrial waste brine solution instead of ultra pure water was investigated during the synthesis of zeolites using three South African coal fly ashes as Si feedstock. The high halide brine was obtained from the retentate effluent of a reverse osmosis mine water treatment plant. Synthesis conditions applied were; ageing of fly ash was at 47 ° C for 48 hours, and while the hydrothermal treatment temperature was set at 140 ° C for 48 hours. The use of brine as a solvent resulted in the formation of hydroxy sodalite zeolite although unconverted mullite and hematite from the fly ash feedstock was also found in the synthesis product.

  8. Effect of coal quality on maintenance costs at utility plants. Final report. [Effect of ash and sulfur content of coal

    Energy Technology Data Exchange (ETDEWEB)

    Holt, E.C. Jr.

    1980-06-01

    In an attempt to determine if correlation exists between coal quality, as measured by its ash and sulfur contents, and the maintenance cost at utility plants, an examination was made of the actual maintenance cost experience of selected portions of five TVA coal-fired power plants as a function of the fuel quality consumed during an extended period of time. The results indicate that, according to our decision rules developed in compliance with accepted statistical practices, correlation does exist in many portions of the coal-fired plants for which sufficient maintenance cost records were available. The degree of correlation varies significantly among the individual portions of a particular plant as well as among the various plants. However, the indicators are sufficient to confirm that a change (within the design constraints of the unit) in the ash and/or sulfur content of the coal being consumed by a utility boiler will have a proportionate effect on the maintenance cost at the plant. In the cases examined, each percent variation in ash content could have a monetary effect of from $0.05 to $0.10 per ton of coal consumed. Similarly, each percent variation in sulfur content could influence maintenance costs from $0.30 to $0.50 per ton of coal. Since these values are based on preliminary analysis of limited data, they must be approached with caution and not removed from the context in which they are presented. However, if borne out by further study, the potential magnitude of such savings may be sufficient to justify the acquisition of superior coal supplies, either by changing the source and/or using preparation to obtain a lower ash and sulfur fuel.

  9. Technical data. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project, Converse County, Wyoming

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-01-01

    This volume includes a description of the railway to transport the coal; possible unbalance in the electrical power supply is considered in detail, as well as communications, signalling, etc. The railway will also be used to transport ashes and sludges for waste disposal. Coal fines in the coal supply will be burned to generate power. A very brief description of the coal gasification plant and its components is accompanied by a printout of the dates final engineering is to be completed. Permit applications are listed and socio-economic factors are discussed. The financing plan is discussed in some detail: basically, a loan guarantee from the Synthetic Fuels Corporation; equity provided by investment tax credit, deferred taxes, AFUDC and the sponsors; price support; and gas purchase agreement (this whole section includes several legal details.). (LTN)

  10. Combustion of ultrafine coal/water mixtures and their application in gas turbines: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Toqan, M.A.; Srinivasachar, S.; Staudt, J.; Varela, F.; Beer, J.M.

    1987-10-01

    The feasibility of using coal-water fuels (CWF) in gas turbine combustors has been demonstrated in recent pilot plant experiments. The demands of burning coal-water fuels with high flame stability, complete combustion, low NO/sub x/ emission and a resulting fly ash particle size that will not erode turbine blades represent a significant challenge to combustion scientists and engineers. The satisfactory solution of these problems requires that the variation of the structure of CWF flames, i.e., the fields of flow, temperature and chemical species concentration in the flame, with operating conditions is known. Detailed in-flame measurements are difficult at elevated pressures and it has been proposed to carry out such experiments at atmospheric pressure and interpret the data by means of models for gas turbine combustor conditions. The research was carried out in five sequential tasks: cold flow studies; studies of conventional fine-grind CWF; combustion studies with ultrafine CWF fuel; reduction of NO/sub x/ emission by staged combustion; and data interpretation-ignition and radiation aspects. 37 refs., 61 figs., 9 tabs.

  11. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1986-12-01

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  12. Phase equilibrium properties of coal-derived liquids. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Yesavage, V.F.; Kidnay, A.J.

    1983-12-22

    An experimental apparatus capable of making accurate high temperature, high pressure vapor-liquid equilibria measurements was designed, constructed, and evaluated. The basic system is a flow equilibrium flash vaporization apparatus similar to those used for petroleum liquids. The final equilibrium cell is a visual cell using a sapphire window with a gold o-ring for sealing. Vapor pressures of pure water were measured from 126 to 307/sup 0/C to test the equipment. The system was next evaluated using the ethanol-water binary system. Data were obtained at 150, 200, and 250/sup 0/C. At 150/sup 0/C and 200/sup 0/C or at low ethanol concentrations there was substantial agreement between our data and data in the literature. At higher ethanol concentrations approaching the azeotrope there was some disagreement which was later found to be due to inconsistencies in the literature data. These results established the reliability of the equipment for binary mixture vapor liquid equilibrium measurements. The first system studied of relevance to coal-derived liquid properties was the m-cresol/quinoline binary system. This system was selected since these compounds are typical of the hetero-atomic species present in coal-derived liquids. Numerous difficulties were encountered. After resolving the experimental difficulties, reliable data were obtained for the system at 250/sup 0/C. An azeotrope was found in the system at a m-cresol composition in the region of 5 mole percent. 47 references, 19 figures, 16 tables.

  13. Europe, the final solution and the dynamics of intent.

    Science.gov (United States)

    Bloxham, Donald

    2010-01-01

    The scale and scope of the "final solution" of the "Jewish question" were extreme even in the horrific annals of genocide. Bloxham attempts to shed light on the pattern of mass murder in its expansion and contraction by viewing the Holocaust in a set of temporally and culturally specific contexts. It places the Holocaust into a broader European framework of violent ethnopolitics and geopolitics from the late nineteenth century through the mid-twentieth century. The Holocaust is depicted as an only partially discrete part of a continental process of traumatic flux, and a part, furthermore, that can itself be partially disaggregated into national and regional components. Bloxham moves from a general consideration of patterns of ethnic violence in the period to a closer causal explanation that shows the different valences of Nazi policy towards Jews in the lands directly ruled by Germany and those of Germany's allies respectively. He shows that the peculiarly extensive ambitions of the "final solution" at its most expansive can only be explained when wider geopolitical and strategic contextual terms are factored in along with consideration of Nazi ideology and the internal dynamics of some of the key institutions of the perpetrator state.

  14. Implication of world coal demand on U. S. port strategic planning. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Osleeb, J.P.; Ratick, S.J.; Buckley, P.; Lee, K.; Kuby, M.

    1983-10-01

    The Coal Logistics System (COLS) is developed and used to determine the effects of world coal demands on U.S. ports. The model simultaneously solves for the optimal sources and qualities of coal for export, systemwide least cost routes and modes for transporting coal, and the locations and activity levels of coal transhipments, or other maritime improvements at U.S. ports. Information regarding the necessary investment in coal handling equipment and operating costs at those ports is also provided. A number of scenarios were run with COLS, differing by assumptions made and data used. Some ports were found to have locational advantages with respect to the source of coal vis-a-vis its demand. Scenario results indicate that other ports can participate in the export trade without an appreciable increase in systemwide costs and could be encouraged to do so to increase reliability of U.S. coal supply and foster competition.

  15. Modeling of integrated environmental control systems for coal-fired power plants. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Rubin, E.S.; Salmento, J.S.; Frey, H.C.; Abu-Baker, A.; Berkenpas, M.

    1991-05-01

    The Integrated Environmental Control Model (IECM) was designed to permit the systematic evaluation of environmental control options for pulverized coal-fired (PC) power plants. Of special interest was the ability to compare the performance and cost of advanced pollution control systems to ``conventional`` technologies for the control of particulate, SO{sub 2} and NO{sub x}. Of importance also was the ability to consider pre-combustion, combustion and post-combustion control methods employed alone or in combination to meet tough air pollution emission standards. Finally, the ability to conduct probabilistic analyses is a unique capability of the IECM. Key results are characterized as distribution functions rather than as single deterministic values. (VC)

  16. Evaluation of technology modifications required to apply clean coal technologies in Russian utilities. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-01

    The report describes the following: overview of the Russian power industry; electric power equipment of Russia; power industry development forecast for Russia; clean coal technology demonstration program of the US Department of Energy; reduction of coal TPS (thermal power station) environmental impacts in Russia; and base options of advanced coal thermal power plants. Terms of the application of clean coal technology at Russian TPS are discussed in the Conclusions.

  17. Low-rank coal research: Volume 3, Combustion research: Final report. [Great Plains

    Energy Technology Data Exchange (ETDEWEB)

    Mann, M. D.; Hajicek, D. R.; Zobeck, B. J.; Kalmanovitch, D. P.; Potas, T. A.; Maas, D. J.; Malterer, T. J.; DeWall, R. A.; Miller, B. G.; Johnson, M. D.

    1987-04-01

    Volume III, Combustion Research, contains articles on fluidized bed combustion, advanced processes for low-rank coal slurry production, low-rank coal slurry combustion, heat engine utilization of low-rank coals, and Great Plains Gasification Plant. These articles have been entered individually into EDB and ERA. (LTN)

  18. Anaerobic biprocessing of low rank coals. Final technical report, September 12, 1990--August 10, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Jain, M.K.; Narayan, R.

    1993-08-05

    Coal solubilization under aerobic conditions results in oxygenated coal product which, in turn, makes the coal poorer fuel than the starting material. A novel approach has been made in this project is to remove oxygen from coal by reductive decarboxylation. In Wyodak subbituminous coal the major oxygen functionality is carboxylic groups which exist predominantly as carboxylate anions strongly chelating metal cations like Ca{sup 2+} and forming strong macromolecular crosslinks which contribute in large measure to network polymer structure. Removal of the carboxylic groups at ambient temperature by anaerobic organisms would unravel the macromoleculer network, resulting in smaller coal macromolecules with increased H/C ratio which has better fuel value and better processing prospects. These studies described here sought to find biological methods to remove carboxylic functionalities from low rank coals under ambient conditions and to assess the properties of these modified coals towards coal liquefaction. Efforts were made to establish anaerobic microbial consortia having decarboxylating ability, decarboxylate coal with the adapted microbial consortia, isolate the organisms, and characterize the biotreated coal products. Production of CO{sup 2} was used as the primary indicator for possible coal decarboxylation.

  19. Surface electrochemical control for fine coal and pyrite separation. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wadsworth, M.E.; Bodily, D.M.; Hu, Weibai; Chen, Wanxiong; Huang, Qinping; Liang, Jun; Riley, A.M.; Li, Jun; Wann, Jyi-Perng; Zhong, Tingke; Zhu, Ximeng

    1993-01-20

    Laboratory flotation tests were carried out on three coals and on coal pyrite. Floatability measurements included natural floatability, flotation with a xanthate collector and salt flotation. The ranking of the floatability of the three coals were: Upper Freeport > Pittsburgh > Illinois. The floatability of mineral pyrite and coal pyrite increased markedly with xanthate concentration, but decreased with increased pH. In general, coal pyrite was more difficult to float than mineral pyrite. This was attributed to the presence of surface carbonaceous and mineral matter, since floatability of coal pyrite improved by acid pretreatment. Flotation tests demonstrated that the floatability of coal and mineral pyrite was greatly enhanced by the presence of an electrolyte. Flotation was also enhanced by the addition of modifiers such as CuSO{sub 4}, Na{sub 2}S, CO{sub 2} and EDTA. Lime additions markedly reduced the floatability of coal pyrite. Enhanced floatability of coal pyrite resulted when the pyrite was anodically oxidized in a specially constructed electrochemical flotation cell Pretreatment in potential ranges previously observed for polysulfide and sulfur film formation resulted in the enhanced floatability. While interesting trends and influences, both chemical and electrochemical, markedly improved the floatability of coal, there is little hope for reverse flotation as an effective technology for coal/coal-pyrite separations. The effects of poor liberation and entrainment appear overriding.

  20. Cooperative research in coal liquefaction. Final report, May 1, 1990-- April 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P. [ed.

    1992-02-15

    The Consortium for Fossil Fuel Liquefaction Science (CFFLS) is currently engaged in a three year contract with the US Department of Energy investigating a range of research topics dealing with direct coal liquefaction. This report summarizes the results of this program in its second year, from May 1, 1990 to April 30, 1991. Accomplishments for this period are presented for the following tasks: Iron-based catalysts for coal liquefaction, exploratory research on coal conversion, novel coal liquefaction concepts, and novel catalysts for coal liquefaction.

  1. Analytical method for the evaluation of sulfur functionalities in American coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Attar, A.

    1983-05-01

    This investigation consisted of the following 6 tasks: (1) improve the instrumentation for the sulfur functional groups analysis and make it more reliable. (2) create a set of reference standards of sulfur-containing compounds. (3) examine the sulfur groups distribution in untreated and desulfurized coals. (4) examine the sulfur functionalities in raw and processed coals, i.e., liquefied coals. (5) determine the distribution of sulfur functionalities in modified coals. (6) prepare computer programs for calculations related to the distribution of sulfur functional groups in coal. Each task is discussed and results are presented. Appendix A contains the computer program used to interpret the data. 31 references, 56 figures, 17 tables.

  2. Chemomechanical phenomena in the grinding of coal. Final report, February 1, 1976--May 31, 1977

    Energy Technology Data Exchange (ETDEWEB)

    Macmillan, N.H.

    1977-08-01

    Vickers microhardness, drilling rate, grinding rate and zeta-potential measurements have been made on coals of various rank in both aqueous and organic environments in order to determine whether: (a) chemomechanical (Rebinder) effects exist in coal; and (b) any such effects as do exist can be used to improve the comminution of coal. The results reveal the mechanical behavior of coal to be remarkably environment-insensitive as compared to inorganic non-metals. As a result, it is concluded that chemomechanical phenomena offer little prospect of reducing the cost of comminuting coal.

  3. Structure of coal: new approaches to characterizing organonitrogen and organosulfur functionalities in coal and coal liquids. Final report. [Finnigan triple quadrupole mass spectrometers

    Energy Technology Data Exchange (ETDEWEB)

    Cooks, R.G.

    1983-01-01

    This report describes the application of tandem mass spectrometry (MS/MS) to the analysis of coal-related materials. A Finnigan Triple State Quadrupole mass spectrometer was used for most of the results obtained in this study. Both collision energy (0 to 30 eV) and collision gas pressure (0 to 2.5 mtorr, typically argon) have significant effects on the spectra. Increasing the collision energy or collision pressure results in an increased fragmentation of the selected ion. The analytical utility of different chemical ionization (CI) reagent gases is shown. The MS/MS spectra of a selected ion obtained by isobutane and ammonia CI are identical, which paves the way for development of MS/MS libraries. A library is being developed especially for the analysis of coal-related materials. Three principal MS/MS scan modes (daughter, parent and neutral loss) are utilized in the analysis of coal-related materials. Parent and neutral loss scans characterize the complex mixture for particular chemical moieties (functional groups, structure type), while daughter scans are used for identification of specific components. SRC II was the principal sample studied by CI. Laser desorption methodology for coal analysis was developed. Other fuel-related materials were examined to generalize the analytical methodology being developed for the coal-related materials, including shale oil and diesel exhaust particulates. 35 references, 50 figures, 3 tables.

  4. 76 FR 45612 - Notice of Availability of the Buckskin Mine Hay Creek II Coal Lease-by-Application Final...

    Science.gov (United States)

    2011-07-29

    ... Bureau of Land Management Notice of Availability of the Buckskin Mine Hay Creek II Coal Lease-by-Application Final Environmental Impact Statement, Wyoming AGENCY: Bureau of Land Management, Interior. ACTION: Notice of Availability. SUMMARY: In accordance with the National Environmental Policy Act of ] 1969 (NEPA...

  5. Characterization and supply of coal based fuels. Volume 1, Final report and appendix A (Topical report)

    Energy Technology Data Exchange (ETDEWEB)

    1992-06-01

    Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

  6. Testing of pyrite flotation techniques on selected Ohio coals: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Arnold, B. J.; Torak, E. R.

    1989-05-01

    The project was conceived to demonstrate the combining of conventional physical coal cleaning with emerging advanced physical coal cleaning technologies in a cost-effective manner. The objectives of the program were to demonstrate that conventional coal cleaning followed by advanced coal cleaning of a crushed mid-gravity portion of the run-of-mine coal would produce a clean coal, suitable for use as a thermal coal, having a lower ash content and a lower sulfur dioxide emission potential than a coal cleaned only be current conventional cleaning technologies. As part of this program a number of advanced flotation techniques were tested to determine the feasibility of including them in the design of their Advanced Coal Preparation Facility. The program consisted of testing the Pittsburgh seam, the Middle Kittanning seam, and the Meigs Creek seam coals in the pilot flotation circuit at EPRI's Coal Quality Development Center (CQDC) in Homer City, Pennsylvania. This report contains all the data from OCDO's pilot flotation test program at the CQDC and the test data from the Middle Kittanning and Meigs Creek reverse flotation tests. 13 figs., 40 tabs.

  7. Selective flotation of fossil resin from Western coal. Final report, July 1, 1990--May 25, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Jensen, G.F.; Miller, J.D.

    1992-05-25

    The proof-of-concept test program was designed to clarify a number of concerns that have been raised by coal companies who own the valuable resin resource. First, from laboratory bench-scale flotation experiments, a froth product from cleaner flotation containing more than 80% hexane-extractable resin at higher than 80% recovery can be produced. Pilot-plant testing was initiated to demonstrate the selective flotation of fossil resin and to establish a better confidence level in the new technology. Second, pilot-plant testing was designed to evaluate the effect and impact of random variation in slurry solids concentration and feed grade on this new selective fossil resin flotation technology. The flotation performance obtained under these industrial conditions is more realistic for process evaluation. Third, more accurate operating cost data was to be obtained for economic analysis. Fourth, sufficient quantities of the fossil resin concentrate were to be produced from the test program for evaluation by potential industrial users. Fifth, and finally, optimum levels for the operating variables were to be established. Such information was required for eventual scale-up and design of a fossil resin flotation plant. The pilot-plant proof-of-concept testing of selective resinate flotation has demonstrated that: (1) technically, the new flotation technologies discovered at the University of Utah and then improved upon by Advanced Processing Technologies, Inc. provide a highly efficient means to selectively recover fossil resin from coal. The proof-of-concept continuous flotation circuit (about 0.1 tph) resulted in fossil resin recovery with the same separation efficiency as was obtained from laboratory bench-scale testing (more than 80% recovery at about 80% concentrate grade); and (2) economically, the selective flotation process has been shown to be sufficiently profitable to justify the development of a fossil resin industry based on this new flotation process.

  8. Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Elmore, B.B.

    1993-08-01

    As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

  9. New reagents for coal desulfurization. Final technical report, September 1, 1990--August 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Buchanan, D.H.; Kalembasa, S.; Olson, D.; Wang, S.; Warfel, L.

    1991-12-31

    The primary goal of this project was development and exploration of potential new desulfurization reagents for the removal of ``organic sulfur`` from Illinois coals by mild chemical methods. Potential new desulfurization reagents were investigated using organic sulfur compounds of the types thought to be present in coals. Reagents included low-valent metal complexes based on nickel and on iron as well as possible Single Electron Transfer reagents. Soluble coal extracts served as second generation model compounds during this reagent development project.

  10. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Chunshan Song; Schobert, H.H.; Parfitt, D.P. [and others

    1997-11-01

    Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

  11. Synergistic Utilization of Coal Fines and Municipal Solid Waste in Coal-Fired Boilers. Phase I Final Report

    Energy Technology Data Exchange (ETDEWEB)

    V. Zamansky; P. Maly; M. Klosky

    1998-06-12

    A feasibility study was performed on a novel concept: to synergistically utilize a blend of waste coal fines with so-called E-fuel for cofiring and reburning in utility and industrial boilers. The E-fuel is produced from MSW by the patented EnerTech's slurry carbonization process. The slurry carbonization technology economically converts MSW to a uniform, low-ash, low-sulfur, and essentially chlorine-free fuel with energy content of about 14,800 Btu/lb.

  12. Development of a pulsed coal combustor fired with CWM (coal-water mixture): Phase 3, Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mansour, M.N.; Durai-Swamy, K.

    1986-11-01

    This report presents the results of an R and D program aimed at developing a new burner technology for coal-water mixture (CWM) fuels to enable the substitution of these new fuels in utility and industrial boilers and process heaters currently firing oil and gas. The application of pulse combustion to CWM fuels is chosen to alleviate many of the physical plant and environmental constraints presently associated with the direct use of these fuels in equipment designed for oil and gas firing. Pulse combustion has been shown to be capable of high-intensity burning of coal for acceptably complete combustion within relatively small equipment volumes. It also has the inherent capability to agglomerate ash particles, thus rendering ash more easily separable from the combustion gas prior to its entrance into the convective section of the boiler or heater, thereby reducing ash buildup and pluggage. Pulse combustion is also well-suited to staged combustion for NO/sub x/ control and has excellent potential for enhanced in-furnace SO/sub 2/ removal due to the enhanced levels of mass transfer brought about by the vigorous flow oscillations. The primary objective of the Phase 2 work was to develop a detailed program for laboratory development and evaluation of the pulse CWM combustor and system design concepts. 112 refs., 40 figs., 94 tabs.

  13. Molecular biological enhancement of coal biodesulfurization. Final report, October 1988--December 1991

    Energy Technology Data Exchange (ETDEWEB)

    Kilbane, J.J. II; Bielaga, B.A.

    1991-12-01

    The overall objective of this project was to use molecular genetics to develop strains of bacteria with enhanced ability to remove sulfur from coal, and to obtain data that will allow the performance and economics of a coal biodesulfurization process to be predicted. (VC)

  14. Low-rank coal research: Volume 2, Advanced research and technology development: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mann, M.D.; Swanson, M.L.; Benson, S.A.; Radonovich, L.; Steadman, E.N.; Sweeny, P.G.; McCollor, D.P.; Kleesattel, D.; Grow, D.; Falcone, S.K.

    1987-04-01

    Volume II contains articles on advanced combustion phenomena, combustion inorganic transformation; coal/char reactivity; liquefaction reactivity of low-rank coals, gasification ash and slag characterization, and fine particulate emissions. These articles have been entered individually into EDB and ERA. (LTN)

  15. Integrated coal preparation and CWF processing plant: Conceptual design and costing. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    McHale, E.T.; Paul, A.D.; Bartis, J.T. [Science Applications International Corp., McLean, VA (United States); Korkmaz, M. [Roberts and Schaefer Co., Salt Lake City, UT (United States)

    1992-12-01

    At the request of the US Department of Energy (DOE), Pittsburgh Energy Technology Center, a study was conducted to provide DOE with a reliable, documented estimate of the cost of producing coal-water fuel (CWF). The approach to the project was to specify a plant capacity and location, identify and analyze a suitable coal, and develop a conceptual design for an integrated coal preparation and CWF processing plant. Using this information, a definitive costing study was then conducted, on the basis of which an economic and sensitivity analysis was performed utilizing a financial evaluation model to determine a price for CWF in 1992. The design output of the integrated plant is 200 tons of coal (dry basis) per hour. Operating at a capacity factor of 83 percent, the baseline design yields approximately 1.5 million tons per year of coal on a dry basis. This is approximately equivalent to the fuel required to continuously generate 500 MW of electric power. The CWF produced by the plant is intended as a replacement for heavy oil or gas in electric utility and large industrial boilers. The particle size distribution, particularly the top size, and the ash content of the coal in the CWF are specified at significantly lower levels than is commonly found in typical pulverized coal grinds. The particle top size is 125 microns (vs typically 300m{mu} for pulverized coal) and the coal ash content is 3.8 percent. The lower top size is intended to promote complete carbon burnout at less derating in boilers that are not designed for coal firing. The reduced mineral matter content will produce ash of very fine particle size during combustion, which leads to less impaction and reduced fouling of tubes in convective passages.

  16. Temperature effects on chemical structure and motion in coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Maciel, G.E.

    1996-09-30

    The objective of this project was to apply recently developed, state-of-the-art nuclear magnetic resonance (NMR) techniques to examine in situ changes in the chemical structure and molecular/macromolecular motion in coal as the temperature is increased above room temperature. Although alterations in the chemical structure of coal have been studied previously by {sup 13}C NMR, using quenched samples, the goal of this project was to examine these chemical structural changes, and changes in molecular/macromolecular mobility that may precede or accompany the chemical changes, at elevated temperatures, using modern {sup 13}C and {sup 1}H NMR techniques, especially {sup 1}H dipolar-dephasing techniques and related experiments pioneered in the laboratory for examining pyridine-saturated coals. This project consisted of the following four primary segments and related efforts on matters relevant to the first four tasks. (1) {sup 1}H NMR characterization of coal structure and mobility as a function of temperature variation over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (2) {sup 1}H NMR characterization of coal structure, mobility and conversion as a function of temperature variation over a temperature range (240--500 C) for which chemical transformations of coal are known to occur. (3) {sup 13}C NMR investigation of coal structure/mobility as a function of temperature over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (4) {sup 13}C NMR investigation of coal structure, dynamics and conversion as a function of temperature variation over a range (240--500 C) for which chemical transformations of coal are known to occur. (5) Related matters relevant to the first four tasks: (a) {sup 1}H CRAMPS NMR characterization of oil shales and their kerogen concentrates; and (b) improved quantitation in {sup 13}C MAS characterization of coals.

  17. Development of the chemical and electrochemical coal cleaning (CECC) process. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Roe-Hoan; Basilio, C.I.

    1992-05-01

    The Chemical and Electrochemical Coal Cleaning (CECC) process developed at Virginia Polytechnic Institute and State University was studied further in this project. This process offers a new method of physically cleaning both low- and high-rank coals without requiring fine grinding. The CECC process is based on liberating mineral matter from coal by osmotic pressure. The majority of the work was conducted on Middle Wyodak, Pittsburgh No. 8 and Elkhorn No. 3 coals. The coal samples were characterized for a variety of physical and chemical properties. Parametric studies were then conducted to identify the important operating parameters and to establish the optimum conditions. In addition, fundamental mechanisms of the process were studied, including mineral matter liberation, kinetics of mineral matter and pyrite dissolution, ferric ion regeneration schemes and alternative methods of separating the cleaned coal from the liberated mineral matter. The information gathered from the parametric and fundamental studies was used in the design, construction and testing of a bench-scale continuous CECC unit. Using this unit, the ash content of a Middle Wyodak coal was reduced from 6.96 to 1.61% at a 2 lbs/hr throughput. With an Elkhorn No. 3 sample, the ash content was reduced from 9.43 to 1.8%, while the sulfur content was reduced from 1.57 to 0.9%. The mass balance and liberation studies showed that liberation played a more dominant role than the chemical dissolution in removing mineral matter and inorganic sulfur from the different bituminous coals tested. However, the opposite was found to be the case for the Wyodak coal since this coal contained a significant amount of acid-soluble minerals.

  18. Solute Concentrations Influence Microbial Methanogenesis in Coal-bearing Strata of the Cherokee Basin, USA.

    Science.gov (United States)

    Kirk, Matthew F; Wilson, Brien H; Marquart, Kyle A; Zeglin, Lydia H; Vinson, David S; Flynn, Theodore M

    2015-01-01

    Microorganisms have contributed significantly to subsurface energy resources by converting organic matter in hydrocarbon reservoirs into methane, the main component of natural gas. In this study, we consider environmental controls on microbial populations in coal-bearing strata of the Cherokee basin, an unconventional natural gas resource in southeast Kansas, USA. Pennsylvanian-age strata in the basin contain numerous thin (0.4-1.1 m) coalbeds with marginal thermal maturities (0.5-0.7% R o ) that are interbedded with shale and sandstone. We collected gas, water, and microbe samples from 16 commercial coalbed methane wells for geochemical and microbiological analysis. The water samples were Na-Cl type with total dissolved solids (TDS) content ranging from 34.9 to 91.3 g L(-1). Gas dryness values [C1/(C2 + C3)] averaged 2640 and carbon and hydrogen isotope ratios of methane differed from those of carbon dioxide and water, respectively, by an average of 65 and 183‰. These values are thought to be consistent with gas that formed primarily by hydrogenotrophic methanogenesis. Results from cultivation assays and taxonomic analysis of 16S rRNA genes agree with the geochemical results. Cultivable methanogens were present in every sample tested, methanogen sequences dominate the archaeal community in each sample (avg 91%), and few archaeal sequences (avg 4.2%) were classified within Methanosarcinales, an order of methanogens known to contain methylotrophic methanogens. Although hydrogenotrophs appear dominant, geochemical and microbial analyses both indicate that the proportion of methane generated by acetoclastic methanogens increases with the solute content of formation water, a trend that is contrary to existing conceptual models. Consistent with this trend, beta diversity analyses show that archaeal diversity significantly correlates with formation water solute content. In contrast, bacterial diversity more strongly correlates with location than solute content

  19. Solute concentrations influence microbial methanogenesis in coal-bearing strata of the Cherokee basin, USA

    Directory of Open Access Journals (Sweden)

    Matthew F Kirk

    2015-11-01

    Full Text Available Microorganisms have contributed significantly to subsurface energy resources by converting organic matter in hydrocarbon reservoirs into methane, the main component of natural gas. In this study, we consider environmental controls on microbial populations in coal-bearing strata of the Cherokee basin, an unconventional natural gas resource in southeast Kansas, USA. Pennsylvanian-age strata in the basin contain numerous thin (0.4-1.1 m coalbeds with marginal thermal maturities (0.5-0.7 %Ro that are interbedded with shale and sandstone. We collected gas, water, and microbe samples from 16 commercial coalbed methane wells for geochemical and microbiological analysis. The water samples were Na-Cl type with total dissolved solids (TDS content ranging from 34.9 to 91.3 g L-1. Gas dryness values [C1/(C2+C3] averaged 2640 and carbon and hydrogen isotope ratios of methane differed from those of carbon dioxide and water, respectively, by an average of 65‰ and 183‰. These values are thought to be consistent with gas that formed primarily by hydrogenotrophic methanogenesis. Results from cultivation assays and taxonomic analysis of 16S rRNA genes agree with the geochemical results. Cultivable methanogens were present in every sample tested, methanogen sequences dominate the archaeal community in each sample (avg 91%, and few archaeal sequences (avg 4.2% were classified within Methanosarcinales, an order of methanogens known to contain methylotrophic methanogens. Although hydrogenotrophs appear dominant, geochemical and microbial analyses both indicate that the proportion of methane generated by acetoclastic methanogens increases with the solute content of formation water, a trend that is contrary to existing conceptual models. Consistent with this trend, beta diversity analyses show that archaeal diversity significantly correlates with formation water solute content. In contrast, bacterial diversity more strongly correlates with location than solute

  20. Demonstration of coal reburning for cyclone boiler NO{sub x} control. Final project report

    Energy Technology Data Exchange (ETDEWEB)

    1994-02-01

    As part of the US Department of Energy`s (DOE`s) Innovative Clean Coal Technology Program, under Round 2, a project for Full Scale Demonstration of Coal Reburning for Cyclone Boiler Nitrogen Oxide (NO{sub x},) Control was selected. DOE sponsored The Babcock & Wilcox (B&W) Company, with Wisconsin Power & Light (WP&L) as the host utility, to demonstrate coal reburning technology at WP&L`s 110 MW{sub c}, cyclone-fired Unit No.2 at the Nelson Dewey Generating Station in Cassville, Wisconsin. The coal reburning demonstration was justified based on two prior studies. An Electric Power Research Institute (EPRI) and B&W sponsored engineering feasibility study indicated that the majority of cyclone-equipped boilers could successfully apply reburning technology to reduce NO{sub x}, emissions by 50 to 70%. An EPRI/Gas Research Institute (GRI)/B&W pilot-scale evaluation substantiated this conclusion through pilot-scale testing in B&W`s 6 million Btu/hr Small Boiler Simulator. Three different reburning fuels, natural gas, No. 6 oil, and pulverized coal were tested. This work showed that coal as a reburning fuel performs nearly as well as gas/oil without deleterious effects of combustion efficiency. Coal was selected for a full scale demonstration since it is available to all cyclone units and represents the highest level of technical difficulty-in demonstrating the technology.

  1. Crude-oil vs coal-oil processing comparison study. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1979-11-01

    This study evaluates three refinery schemes that have been developed for the processing of H-Coal liquids. The refinery processing employed for the naphtha and lighter components of the H-Coal liquid is essentially the same for all three schemes. It is in the processing of the H-Coal distillate product that refinery variations occur, and these differences are outlined: hydrotreating of the middle coal distillate to produce a No. 2 fuel oil equivalent product; hydrocracking of the total coal distillate to produce more gasoline and higher quality distillate fuel; and hydrotreating of the light coal distillate to a No. 2 fuel oil equivalent, and hydrogenating the heavy coal distillate to upgrade feedstock to a fluid catalytic cracking (FCC) unit. To provide a perspective of the value of coal liquid relative to petroleum, a parallel set of petroleum refinery schemes, processing a 65/35 Light/Heavy Arabian crude oil blend, was developed: reduced crude desulfurization with FCC processing of the desulfurized VGO; reduced crude desulfurization with hydrocracking of the desulfurized VGO; solvent demetallization of the vacuum pitch with desulfurization and FCC processing of VGO and demetallized oil; and solvent demetallization of the vacuum pitch with hydrocracking of the VGO and demetallized oil. Various gasoline to distillate ratios were set as parameters in developing the best possible processing schemes. Linear programming techniques were used to select the optimal schemes at various product ratios. Applying the same product prices to all cases and subtracting operating costs and the capital change, a comparative feedstock value is calculated. This method places the various refinery schemes on a common basis and gives an appraisal of the relative value of the H-Coal liquid charge stock, based on new refinery facilities.

  2. Mild coal pretreatment to improve liquefaction reactivity. Final technical report, September 1990--February 1994

    Energy Technology Data Exchange (ETDEWEB)

    Miller, R.L.; Shams, K.G.

    1994-07-01

    Recent research efforts in direct coal liquefaction are focused on lowering the level of reaction severity, identification and determination of the causes of retrogressive reactions, and improving the economics of the process. Ambient pretreatment of coals using methanol and a trace amount of hydrochloric acid was extensively studied in connection with low severity coal liquefaction. Ambient pretreatment of eight Argonne coals using methanol/HCl improved THF-soluble conversions 24.5 wt % (maf basis) for Wyodak subbituminous coal and 28.4 wt % for Beulah-Zap lignite with an average increase of 14.9 wt % for the eight Argonne coals at 623 K (350{degrees}C) reaction temperature and 30 minutes reaction time. Optimal pretreatment conditions were determined using Wyodak and Illinois No. 6 coals. Acid concentration was the most important pretreatment variable studied; liquefaction reactivity increased with increasing acid concentration up to 2 vol %. The FTIR spectra of treated and untreated Wyodak coal samples demonstrated formation of carboxylic functional groups during pretreatment, a result of divalent (Ca, Mg) cationic bridge destruction. The extent of liquefaction reactivity directly correlated with the amount of calcium removed during pretreatment, and results from calcium ``addback`` experiments supported the observation that calcium adversely affected coal reactivity at low severity reaction conditions. Model compound studies using benzyl phenyl ether demonstrated that calcium cations catalyzed retrogressive reactions, inhibited hydrogenation reactions at low severity reaction conditions, and were more active at higher reaction temperatures. Based on kinetic data, mechanisms for hydrogenation-based inhibition and base-catalyzed retrogressive reactions are proposed. The base-catalyzed retrogressive reactions are shown to occur via a hydrogen abstraction mechanism where hydrogenation inhibition reactions are shown to take place via a surface quenching mechanism.

  3. Characterization of organic nitrogen in IBCSP coals. Final technical report, September 1, 1990--August 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Kruge, M.A.

    1991-12-31

    The overall objective of this study was to determine the content and distribution of organic nitrogen in a series of IBCSP coals and their isolated macerals. The specific objectives were: to determine the bulk nitrogen contents for coals, isolated macerals, oxidation products and residues, solvent extracts and their liquid chromatographic fractions, and pyrolyzates; to determine the distribution of organic nitrogen in all coal derivatives enumerated in Objective 1 which are Gas Chromatography (GC)-amenable. This will be accomplished by GC-Thermionic Specific Detectors; to determine the molecular structure of the major nitrogen compounds detected in Objective 2, using mass spectrometry.

  4. Coal conversion and biomass conversion: Volume 1: Final report on USAID (Agency for International Development)/GOI (Government of India) Alternate Energy Resources and Development Program

    Energy Technology Data Exchange (ETDEWEB)

    Kulkarni, A.; Saluja, J.

    1987-06-30

    The United States Agency for International Development (AID), in joint collaboration with the Government of India (GOI), supported a research and development program in Alternate Energy Resources during the period March 1983 to June 1987. The primary emphasis of this program was to develop new and advanced coal and biomass conversion technologies for the efficient utilization of coal and biomass feedstocks in India. This final ''summary'' report is divided into two volumes. This Report, Volume I, covers the program overview and coal projects and Volume II summarizes the accomplishments of the biomass projects. The six projects selected in the area of coal were: Evaluation of the Freeboard Performance in a Fluidized-Bed Combustor; Scale-up of AFBC boilers; Rheology, Stability and Combustion of Coal-Water Slurries; Beneficiation of Fine Coal in Dense Medium Cyclones; Hot Gas Cleanup and Separation; and Cold Gas Cleanup and Separation.

  5. Cooperative research in coal liquefaction. Final report, May 1, 1992--April 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P. [ed.

    1996-03-01

    Research on sulfate and metal (Mo, Sn) promoted Fe{sub 2}O{sub 3} catalysts in the current year focused on optimization of conditions. Parameters varied included temperature, solvent, solvent-to-coal ratio, and the effect of presulfiding versus in situ sulfiding. Oil yields were found to increase approximately proportionately with both temperature and solvent-to-coal ratio. The donor solvent, tetralin, proved to give better total conversion and oil yields than either 1-methylnaphthalene or Wilsonville recycle oil. A significant enhancement of both total liquefaction yields and oil yields from lignites and subbituminous coals has been achieved by incorporating iron into the coal matrix by cation exchange. A study has been conducted on the synthesis of iron, molybdenum, and tungsten catalysts using a laser pyrolysis technique.

  6. Pelletizing/reslurrying as a means of distributing and firing clean coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Conkle, H.N.

    1992-09-29

    Battelle-Columbus and Amax Research & Development conducted a program to develop a process to transport, handle, store, and utilize ultra-fine, ultra-clean (UFUC) coals. The primary objective was to devise a cost-effective method, based on conventional pelletization techniques, to transform the sludge-like filter cake produced in advanced flotation cleaning processes into a product which could be used like lump coal. A secondary objective was the production of a pellet which could be readily converted into a coal water fuel (CWF) because the UFUC coal would ultimately be used as CWF. The resulting product would be a hard, waterproof pellet which could be easily reduced to small particle sizes and formulated with water into a liquid fuel.

  7. Determining the radiative properties of pulverized-coal particles from experiments. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Menguec, M.P.

    1992-02-01

    A comprehensive coupled experimental-theoretical study has been performed to determine the effective radiative properties of pulverized-coal/char particles. The results obtained show that the ``effective`` scattering phase function of coal particles are highly forward scattering and show less sensitivity to the size than predicted from the Lorenz-Mie theory. The main reason for this is the presence of smaller size particles associated with each larger particle. Also, the coal/char particle clouds display more side scattering than predicted for the same size range spheres, indicating the irregular shape of the particles and fragmentation. In addition to these, it was observed that in the visible wavelength range the coal absorption is not gray, and slightly vary with the wavelength. These two experimental approaches followed in this study are unique in a sense that the physics of the problem are not approximated. The properties determined include all uncertainties related to the particle shape, size distribution, inhomogeneity and spectral complex index of refraction data. In order to obtain radiative property data over a wider wavelength spectrum, additional ex-situ experiments have been carried out using a Fourier Transform Infrared (FT-IR) Spectrometer. The spectral measurements were performed over the wavelength range of 2 to 22 {mu}m. These results were interpreted to obtain the ``effective`` efficiency factors of coal particles and the corresponding refractive index values. The results clearly show that the coal/char radiative properties display significant wavelength dependency in the infrared spectrum.

  8. Superacid Catalyzed Coal Conversion Chemistry. Final Technical Report, September 1, 1983-September 1, 1986

    Science.gov (United States)

    Olah, G. A.

    1986-01-01

    This research project involved the study of a raw comparatively mild coal conversion process. The goal of the project was to study model systems to understand the basic chemistry involved and to provide a possible effective pretreatment of coal which significantly improves liquefaction-depolymerization under mild conditions. The conversion process operates at relatively low temperatures (170 degrees C) and pressures and uses an easily recyclable, stable superacid catalysts (HF-BF{sub 3}). It consequently offers an attractive alternative to currently available processes. From the present studies it appears that the modification of coal structure by electrophilic alkylation and subsequent reaction of alkylated coal with HF-BF{sub 3}-H{sub 2} system under mild conditions considerably improves the extractability of coal in pyridine and cyclohexane. On the other hand, nitration of coal and its subsequent reaction with HF-BF{sub 3}H{sub 2} decreases the pyridine and cyclohexane extractability. Study of model compounds under conditions identical with the superacidic HF/BF{sub 3}/H{sub 2} system provided significant information about the basic chemistry of the involved cleavage-hydrogenation reactions.

  9. Fundamental research on novel process alternatives for coal gasification: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Hill, A H; Knight, R A; Anderson, G L; Feldkirchner, H L; Babu, S P

    1986-10-01

    The Institute of Gas Technology has conducted a fundamental research program to determine the technical feasibility of and to prepare preliminary process evaluations for two new approaches to coal gasification. These two concepts were assessed under two major project tasks: Task 1. CO/sub 2/-Coal Gasification Process Concept; Task 2. Internal Recirculation Catalysts Coal Gasification Process Concept. The first process concept involves CO/sub 2/-O/sub 2/ gasification of coal followed by CO/sub 2/ removal from the hot product gas by a solid MgO-containing sorbent. The sorbent is regenerated by either a thermal- or a pressure-swing step and the CO/sub 2/ released is recycled back to the gasifier. The product is a medium-Btu gas. The second process concept involves the use of novel ''semivolatile'' materials as internal recirculating catalysts for coal gasification. These materials remain in the gasifier because their vapor pressure-temperature behavior is such that they will be in the vapor state at the hotter, char exit part of the reactor and will condense in the colder, coal-inlet part of the reactor. 21 refs., 43 figs., 43 tabs.

  10. Chemical modification of coal fly ash for the removal of phosphate from aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    P. Pengthamkeerati; T. Satapanajaru; P. Chularuengoaksorn [Kasetsart University, Bangkok (Thailand). Environmental Technology Research Unit (EnviTech), Department of Environmental Science

    2008-09-15

    This study investigated the chemical modifications of coal fly ash treated with HCl and NaOH. Sorption behavior of phosphate from water solution on treated fly ash was examined. Results showed that the HCl-treated fly ash (TFA-HCl) had a greater specific surface area (SSA) than the NaOH-treated fly ash (TFA-NaOH) and untreated fly ash (FA). The XRF, XRD patterns, and SEM images revealed the decreased CaO content in the TFA-HCl and observed the presence of NaP1 and sodalite zeolites in the TFA-NaOH. The P sorption capacity of all studied fly ashes increased with increasing initial P concentration and mechanisms of P sorption were influenced by the equilibrium pH. Maximum phosphate immobilization capacity obtained from Langmuir model was in the following manner, TFA-NaOH > FA > TFA-HCl (57.14, 23.20, and 6.90 mg P g{sup -1}, respectively). The decreased CaO content and acidic pH in the TFA-HCl were responsible for the lowest capacity of phosphate immobilization, because of unfavorable condition for calcium phosphate precipitation. In contrast, due to alkaline condition and relatively high calcium content, the precipitation of calcium phosphate was a key mechanism for phosphate removal in the FA and TFA-NaOH. The TFA-NaOH had a greatest phosphate immobilization, due to high CaO content and an increased SSA after the conversion of fly ash to zeolite. Both Langmuir and Freundlich models were good fitted for the TFA-NaOH, while was only Langmuir model for the FA and Freundlich model for the TFA-HCl. Results suggested that treating fly ash with alkaline solution was a promising way to enhance phosphate immobilization. 23 refs., 7 figs., 2 tabs.

  11. Deep subsurface drip irrigation using coal-bed sodic water: Part I. Water and solute movement

    Energy Technology Data Exchange (ETDEWEB)

    Bern, Carleton R; Breit, George N; Healy, Richard W; Zupancic, John W; Hammack, Richard

    2013-02-01

    Water co-produced with coal-bed methane (CBM) in the semi-arid Powder River Basin of Wyoming and Montana commonly has relatively low salinity and high sodium adsorption ratios that can degrade soil permeability where used for irrigation. Nevertheless, a desire to derive beneficial use from the water and a need to dispose of large volumes of it have motivated the design of a deep subsurface drip irrigation (SDI) system capable of utilizing that water. Drip tubing is buried 92 cm deep and irrigates at a relatively constant rate year-round, while evapotranspiration by the alfalfa and grass crops grown is seasonal. We use field data from two sites and computer simulations of unsaturated flow to understand water and solute movements in the SDI fields. Combined irrigation and precipitation exceed potential evapotranspiration by 300–480 mm annually. Initially, excess water contributes to increased storage in the unsaturated zone, and then drainage causes cyclical rises in the water table beneath the fields. Native chloride and nitrate below 200 cm depth are leached by the drainage. Some CBM water moves upward from the drip tubing, drawn by drier conditions above. Chloride from CBM water accumulates there as root uptake removes the water. Year over year accumulations indicated by computer simulations illustrate that infiltration of precipitation water from the surface only partially leaches such accumulations away. Field data show that 7% and 27% of added chloride has accumulated above the drip tubing in an alfalfa and grass field, respectively, following 6 years of irrigation. Maximum chloride concentrations in the alfalfa field are around 45 cm depth but reach the surface in parts of the grass field, illustrating differences driven by crop physiology. Deep SDI offers a means of utilizing marginal quality irrigation waters and managing the accumulation of their associated solutes in the crop rooting zone.

  12. Deep subsurface drip irrigation using coal-bed sodic water: part I. water and solute movement

    Science.gov (United States)

    Bern, Carleton R.; Breit, George N.; Healy, Richard W.; Zupancic, John W.; Hammack, Richard

    2013-01-01

    Water co-produced with coal-bed methane (CBM) in the semi-arid Powder River Basin of Wyoming and Montana commonly has relatively low salinity and high sodium adsorption ratios that can degrade soil permeability where used for irrigation. Nevertheless, a desire to derive beneficial use from the water and a need to dispose of large volumes of it have motivated the design of a deep subsurface drip irrigation (SDI) system capable of utilizing that water. Drip tubing is buried 92 cm deep and irrigates at a relatively constant rate year-round, while evapotranspiration by the alfalfa and grass crops grown is seasonal. We use field data from two sites and computer simulations of unsaturated flow to understand water and solute movements in the SDI fields. Combined irrigation and precipitation exceed potential evapotranspiration by 300-480 mm annually. Initially, excess water contributes to increased storage in the unsaturated zone, and then drainage causes cyclical rises in the water table beneath the fields. Native chloride and nitrate below 200 cm depth are leached by the drainage. Some CBM water moves upward from the drip tubing, drawn by drier conditions above. Chloride from CBM water accumulates there as root uptake removes the water. Year over year accumulations indicated by computer simulations illustrate that infiltration of precipitation water from the surface only partially leaches such accumulations away. Field data show that 7% and 27% of added chloride has accumulated above the drip tubing in an alfalfa and grass field, respectively, following 6 years of irrigation. Maximum chloride concentrations in the alfalfa field are around 45 cm depth but reach the surface in parts of the grass field, illustrating differences driven by crop physiology. Deep SDI offers a means of utilizing marginal quality irrigation waters and managing the accumulation of their associated solutes in the crop rooting zone.

  13. Measurement and prediction of aromatic solute distribution coefficients for aqueous-organic solvent systems. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, J.R.; Luthy, R.G.

    1984-06-01

    Experimental and modeling activities were performed to assess techniques for measurement and prediction of distribution coefficients for aromatic solutes between water and immiscible organic solvents. Experiments were performed to measure distribution coefficients in both clean water and wastewater systems, and to assess treatment of a wastewater by solvent extraction. The theoretical portions of this investigation were directed towards development of techniques for prediction of solute-solvent/water distribution coefficients. Experiments were performed to assess treatment of a phenolic-laden coal conversion wastewater by solvent extraction. The results showed that solvent extraction for recovery of phenolic material offered several wastewater processing advantages. Distribution coefficients were measured in clean water and wastewater systems for aromatic solutes of varying functionality with different solvent types. It was found that distribution coefficients for these compounds in clean water systems were not statistically different from distribution coefficients determined in a complex coal conversion process wastewater. These and other aromatic solute distribution coefficient data were employed for evaluation of modeling techniques for prediction of solute-solvent/water distribution coefficients. Eight solvents were selected in order to represent various chemical classes: toluene and benzene (aromatics), hexane and heptane (alkanes), n-octanol (alcohols), n-butyl acetate (esters), diisopropyl ether (ethers), and methylisobutyl ketone (ketones). The aromatic solutes included: nonpolar compounds such as benzene, toluene and naphthalene, phenolic compounds such as phenol, cresol and catechol, nitrogenous aromatics such as aniline, pyridine and aminonaphthalene, and other aromatic solutes such as naphthol, quinolinol and halogenated compounds. 100 references, 20 figures, 34 tables.

  14. Thermodynamic and rheological properties of solid-liquid systems in coal processing. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Kabadi, V.N.

    1995-06-30

    The work on this project was initiated on September 1, 1991. The project consisted of two different tasks: (1) Development of a model to compute viscosities of coal derived liquids, and (2) Investigate new models for estimation of thermodynamic properties of solid and liquid compounds of the type that exist in coal, or are encountered during coal processing. As for task 1, a model for viscosity computation of coal model compound liquids and coal derived liquids has been developed. The detailed model is presented in this report. Two papers, the first describing the pure liquid model and the second one discussing the application to coal derived liquids, are expected to be published in Energy & Fuels shortly. Marginal progress is reported on task 2. Literature review for this work included compilation of a number of data sets, critical investigation of data measurement techniques available in the literature, investigation of models for liquid and solid phase thermodynamic computations. During the preliminary stages it was discovered that for development of a liquid or solid state equation of state, accurate predictive models for a number of saturation properties, such as, liquid and solid vapor pressures, saturated liquid and solid volumes, heat capacities of liquids and solids at saturation, etc. Most the remaining time on this task was spent in developing predictive correlations for vapor pressures and saturated liquid volumes of organic liquids in general and coal model liquids in particular. All these developments are discussed in this report. Some recommendations for future direction of research in this area are also listed.

  15. High temperature alkali corrosion of ceramics in coal gas: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Pickrell, G.R.; Sun, T.; Brown, J.J. Jr.

    1994-12-31

    There are several ceramic materials which are currently being considered for use as structural elements in coal combustion and coal conversion systems because of their thermal and mechanical properties. These include alumina (refractories, membranes, heat engines); silicon carbide and silicon nitride (turbine engines, internal combustion engines, heat exchangers, particulate filters); zirconia (internal combustion engines, turbine engines, refractories); and mullite and cordierite (particulate filters, refractories, heat exchangers). High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, and zirconia. The study consists of identification of the alkali reaction products and determination of the kinetics of the alkali reactions as a function of temperature and time. 145 refs., 29 figs., 12 tabs.

  16. Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification

    Energy Technology Data Exchange (ETDEWEB)

    None

    1982-01-01

    This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

  17. Solvent-refined-coal (SRC) process. Volume II. Sections V-XIV. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1982-05-01

    This report documents the completion of development work on the Solvent Refined Coal Process by The Pittsburgh and Midway Coal Mining Co. The work was initiated in 1966 under Office of Coal Research, US Department of Interior, Contract No. 14-01-0001-496 and completed under US Department of Energy Contract No. DE-AC05-79ET10104. This report discusses work leading to the development of the SRC-I and SRC-II processes, construction of the Fort Lewis Pilot Plant for the successful development of these processes, and results from the operation of this pilot plant. Process design data generated on a 1 ton-per-day Process Development Unit, bench-scale units and through numerous research projects in support of the design of major demonstration plants are also discussed in summary form and fully referenced in this report.

  18. Steam pretreatment for coal liquefaction. Final report, September 26, 1990--March 18, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Graff, R.A.; Balogh-Nair, V.; Ivanenko, O.; Brathwaite, C.

    1995-10-16

    The objective of this study is to demonstrate the use of subcritical steam to pretreat coal for slurry liquefaction, allowing liquefaction to be carried out at lower severity and improving product yield and quality. Samples of Illinois No. 6 coal were pretreated in 750 psia steam at 340{degree}C for 15 minutes. These samples, as well as raw coal, were liquefied at high (400{degree}C, 30 min.) and low (385{degree}C, 15 min.) severity conditions under 1500 psia hydrogen with tetralin as the donor solvent. Improved yields were obtained at both conditions. (Improved yields were not obtained at a liquefaction temperature of 350{degree}C as that put the sample into the region of retrogressive reactions). The deleterious effects of slow heating and exposure of the sample to air were demonstrated. Under low severity conditions, steam pretreatment more that doubled the oil yield, increasing it from 12.5 to 29 wt %. Tests were also conducted with aromatic ethers as model compounds. These were exposed to inert gas and steam at pretreatment conditions and in some cases to liquid water at 315{degree}C. {alpha}-Benzylnaphthyl ether and {alpha}- naphthylmethyl phenyl ether show little difference in conversion and product distribution when the thermolysis atmosphere is changed from inert gas to steam. However when these compounds were reacted in the presence of 5 {angstrom} zeolite, the yields of the thermolysis products improved. Zeolite proved effective in suppressing isomerization of the starting materials. These results suggested that zeolites might be beneficial in steam pretreatment of coal and in coal liquefaction. Pretreatment and liquefaction of mixtures of coal and zeolites increases yields of asphaltenes and preasphaltenes.

  19. Thermodynamic model for calorimetric and phase coexistence properties of coal derived fluids. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Kabadi, V.N.

    1992-10-01

    The work on this project was initiated on September 1, 1989. The project consisted of three different tasks. 1. A thermodynamic model to predict VLE and calorimetric properties of coal liquids. 2. VLE measurements at high temperature and high pressure for coal model compounds and 3. Chromatographic characterization of coal liquids for distribution of heteroatoms. The thermodynamic model developed is an extension of the previous model developed for VLE of coal derived fluids (DOE Grant no. FG22-86PC90541). The model uses the modified UNIFAC correlation for the liquid phase. Some unavailable UNIFAC interactions parameters have been regressed from experimental VLE and excess enthalpy data. The model is successful in predicting binary VLE and excess enthalpy data. Further refinements of the model are suggested. An apparatus for the high pressure high temperature VLE data measurements has been built and tested. Tetralin-Quinoline is the first binary system selected for data measurements. The equipment was tested by measuring 325{degree}C isotherm for this system and comparing it with literature data. Additional isotherms at 350{degree}C and 370{degree}C have been measured. The framework for a characterization procedure for coal derived liquids has been developed. A coal liquid is defined by a true molecular weight distribution and distribution of heteroatoms as a function of molecular weights. Size exclusions liquid chromatography, elemental analysis and FTIR spectroscopy methods are used to obtain the molecular weight and hetroatom distributions. Further work in this area should include refinements of the characterization procedure, high temperature high pressure VLE data measurements for selective model compound binary systems, and improvement of the thermodynamic model using the new measured data and consistent with the developments in the characterization procedure.

  20. Documentation of the demonstrated reserve base of coal in the United States. Volume 2. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Herhal, A J; Britton, S G; Minnucci, C A

    1982-03-01

    The purpose of this report is to document the methodologies used to develop the 1979 Demonstrated Reserve Base (DRB) of coal. The main body of this report summarizes the methodological procedures used to develop each state reserve estimate. The appendices to the report provide a detailed description of the entire DRB process for each state.

  1. H-coal fluid dynamics. Final report, August 1, 1977-December 31, 1979

    Energy Technology Data Exchange (ETDEWEB)

    1980-04-16

    This report presents the results of work aimed at understanding the hydrodynamic behavior of the H-Coal reactor. A summary of the literature search related to the fluid dynamic behavior of gas/liquid/solid systems has been presented. Design details of a cold flow unit were discussed. The process design of this cold flow model followed practices established by HRI in their process development unit. The cold fow unit has been used to conduct experiments with nitrogen, kerosene, or kerosene/coal char slurries, and HDS catalyst, which at room temperature have properties similar to those existing in the H-Coal reactor. Mineral oil, a high-viscosity liquid, was also used. The volume fractions occupied by gas/liquid slurries and catalyst particles were determined by several experimental techniques. The use of a mini-computer for data collection and calculation has greatly accelerated the analysis and reporting of data. Data on nitrogen/kerosene/HDS catalyst and coal char fines are presented in this paper. Correlations identified in the literature search were utilized to analyze the data. From this analysis it became evident that the Richardson-Zaki correlation describes the effect of slurry flow rate on catalyst expansion. Three-phase fluidization data were analyzed with two models.

  2. Transformations of inorganic coal constituents in combustion systems. Volume 1, sections 1--5: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Helble, J.J. [ed.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. [PSI Technology Co., Andover, MA (United States); Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. [Arizona Univ., Tucson, AZ (United States); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. [Kentucky Univ., Lexington, KY (United States)

    1992-11-01

    The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon the size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles? What determines their composition? Whether or not particles deposit? How combustion conditions, including reactor size, affect these processes? remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.

  3. Materials, process, product analysis of coal process technology. Phase I final report

    Energy Technology Data Exchange (ETDEWEB)

    Saxton, J. C.; Roig, R. W.; Loridan, A.; Leggett, N. E.; Capell, R. G.; Humpstone, C. C.; Mudry, R. N.; Ayres, E.

    1976-02-01

    The purpose of materials-process-product analysis is a systematic evaluation of alternative manufacturing processes--in this case processes for converting coal into energy and material products that can supplement or replace petroleum-based products. The methodological steps in the analysis include: Definition of functional operations that enter into coal conversion processes, and modeling of alternative, competing methods to accomplish these functions; compilation of all feasible conversion processes that can be assembled from combinations of competing methods for the functional operations; systematic, iterative evaluation of all feasible conversion processes under a variety of economic situations, environmental constraints, and projected technological advances; and aggregative assessments (economic and environmental) of various industrial development scenarios. An integral part of the present project is additional development of the existing computer model to include: A data base for coal-related materials and coal conversion processes; and an algorithmic structure that facilitates the iterative, systematic evaluations in response to exogenously specified variables, such as tax policy, environmental limitations, and changes in process technology and costs. As an analytical tool, the analysis is intended to satisfy the needs of an analyst working at the process selection level, for example, with respect to the allocation of RDandD funds to competing technologies.

  4. Semiconductor electrochemistry of coal pyrite. Final technical report, September 1990--September 1995

    Energy Technology Data Exchange (ETDEWEB)

    Osseo-Asare, K.; Wei, D.

    1996-01-01

    This project is concerned with the physiochemical processes occuring at the pyrite/aqueous interface, in the context of coal cleaning, desulfurization, and acid mine drainage. The use of synthetic particles of pyrite as model electrodes to investigate the semiconductor electrochemistry of pyrite is employed.

  5. Coal precursors for carbon molecular sieves (CMS): Appendices A through L. Final report, October 1, 1994--March 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Kopp, O.C.; Sparks, C.R.; McKinney, M.L. [Tennessee Univ., Knoxville, TN (United States). Dept. of Geological Sciences; Fuller, E.L. Jr.; Rogers, M.R. [Oak Ridge National Lab., TN (United States)

    1996-03-31

    The data for each coal sample used in this study are included in a separate appendix. The information for each coal is presented in the following order: coal sample data (literature); coal sample data (measured); thermogravimetric data; mass spectroscopy data; mercury intrusion pore analysis; quantachrome gas sorption analysis (BET) using nitrogen (raw whole coal sample); quantachrome gas sorption analysis (BET) using nitrogen (activated whole coal sample; and plot of FTIR (DRIS) information absorbance vs wavenumbers).

  6. Cooperative research in coal liquefaction. Final report, May 1, 1991--April 30, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P. [ed.

    1996-03-01

    Extensive research continued on catalysts based on novel anion-treated (mainly sulfated) oxides and oxyhydroxides of iron [Fe{sub x}O{sub y}/SO{sub 4}]. In addition, sulfated oxides of tin as well as molybdenum promoted iron oxides were used. Incorporation of small amounts of sulfate, molybdate, or tungstate anions by wet precipitation/impregnation methods was found to increase the surface acidic character of iron oxides; more importantly, it reduced the grain sizes significantly with corresponding increases in specific surface areas. These anion-treated iron and tin oxides were more active for direct coal liquefaction and coal-heavy oil coprocessing than their untreated counterparts. With these catalyst systems, higher conversion levels are obtained as compared to the soluble precursors of iron and molybdenum at the same catalyst metalloading (3500 ppm iron and 50 ppm molybdenum with respect to coal). Sulfated iron oxides and oxyhydroxides were equally active as coal liquefaction catalysts. The sulfate, molybdate, and tungstate anions were found to have similar promotional effects on the properties and activities of iron oxides. One step in the synthesis of anion-treated iron and tin oxides is precipitation as hydroxides using either urea or ammonium hydroxide. The catalysts prepared using urea as a precipitation agent were more reproducible than those using ammonium, hydroxide in terms of activities and properties. These catalysts/catalyst precursors were characterized by several techniques to determine their physical (size and structure related) and chemical (acidity) properties. Sulfated and molybdated iron oxides were found to have grain sizes as small as 10-20 nm. An attempt was made to correlate the physicochemical properties of these catalysts with their activity for coal liquefaction.

  7. Effects of coal-derived trace species on performance of molten carbonate fuel cells. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1992-05-01

    The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

  8. Final Scientific Report - Wireless and Sensing Solutions Advancing Industrial Efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Budampati, Rama; McBrady, Adam; Nusseibeh, Fouad

    2009-09-28

    The project team's goal for the Wireless and Sensing Solution Advancing Industrial Efficiency award (DE-FC36-04GO14002) was to develop, demonstrate, and test a number of leading edge technologies that could enable the emergence of wireless sensor and sampling systems for the industrial market space. This effort combined initiatives in advanced sensor development, configurable sampling and deployment platforms, and robust wireless communications to address critical obstacles in enabling enhanced industrial efficiency.

  9. Training of Engineering Personnel for the Innovative Coal Industry: Problems and Ways of Solution

    Science.gov (United States)

    Zaruba, Natalya; Fraltsova, Tamara; Snegireva, Tatyana

    2017-11-01

    The article is written based on some results of the long-term scientific research of the problem related to the urgent need to find the ways of training personnel for the innovative coal industry in the higher education system. This is due to the fundamental changes in the Russian social and economic conditions: the change in the social system and the owner of the coal industry, the emergence of new technologies in the field of coal mining and processing, and in the management of these processes. At the same time, the system of training specialists for the coal industry in the higher education institutions has largely remained unchanged: technologies and principles of training, scientific approaches and concepts take little account of the changed situation, traditional views of specialists work-ing in the university continue to dominate innovative ideas. Many innovations, especially related to technology and the principles of education, struggle to make their way into the higher education system. The article substantiates the urgency of the problem of training personnel for the innovative coal industry in the higher education system, as well as the importance of scientific analysis of the problem in order to find the ways to solve it.

  10. BLAST FURNACE GRANULAR COAL INJECTION SYSTEM. Final Report Volume 2: Project Performance and Economics

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    1999-10-01

    Bethlehem Steel Corporation (BSC) requested financial assistance from the Department of Energy (DOE), for the design, construction and operation of a 2,800-ton-per-day blast furnace granulated coal injection (BFGCI) system for two existing iron-making blast furnaces. The blast furnaces are located at BSC's facilities in Burns Harbor, Indiana. The demonstration project proposal was selected by the DOE and awarded to Bethlehem in November 1990. The design of the project was completed in December 1993 and construction was completed in January 1995. The equipment startup period continued to November 1995 at which time the operating and testing program began. The blast furnace test program with different injected coals was completed in December 1998.

  11. Extraction of potential pollutants from Ohio coal by synergistic use of supercritical fluids. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S. [Akron Univ., OH (United States). Dept. of Chemical Engineering

    1990-08-03

    A synergistic supercritical extraction process was developed and its feasibility demonstrated using a semi-batch extraction process unit. The process was found to be effective in selectively cleaning organic sulfur from Ohio coals. Optimal case involved a mixture of CO{sub 2}, H{sub 2}O, and CH{sub 3}OH, and the removal of organic sulfur ranged from 35 to 55%. Combined with pyrite and mineral matter removal by gravity, the resulting coals would have 20--30% increased heating values and SO{sub 2} emissions would be down to 1.2--1.5 pounds per million Btu, thus meeting compliance requirements. Estimated cleaning cost including pyrite removal is $25 to 45 per ton. The most important cost factor is the operation at high pressures.

  12. Development of the electroacoustic dewatering (EAD) process for fine/ultrafine coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Chauhan, S.P.; Kim, B.C.; Menton, R.; Senapati, N.; Criner, C.L.; Jirjis, B.; Muralidhara, H.S.; Chou, Y.L.; Wu, H.; Hsieh, P. [Battelle, Columbus, OH (United States); Johnson, H.R.; Eason, R. [Ashbrook-Simon-Hartley Corp., Houston, TX (United States); Chiang, S.M.; Cheng, Y.S. [Pittsburgh Univ., PA (United States); Kehoe, D. [CQ, Inc., Homer City, PA (United States)

    1991-10-31

    Battelle (Columbus, Ohio) undertook development of its electro-acoustic (EAD) process to demonstrate its commercial potential for continuous dewatering of fine and ultrafine coals. The pilot plant and laboratory results, provided in this report, show that a commercial-size EAD machine is expected to economically achieve the dewatering targets for {minus}100 mesh and {minus}325 mesh coals. The EAD process utilizes a synergistic combination of electric and acoustic (e.g., ultrasonic) fields in conjunction with conventional mechanical processes, such as belt presses, screw presses, plate and frame filter presses, and vacuum filters. The application of EAD is typically most beneficial after a filter cake is formed utilizing conventional mechanical filtration. (VC)

  13. Cyclone reburn using coal-water fuel: Pilot-scale development and testing. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Eckhart, C.F.; DeVault, R.F.

    1991-10-01

    There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

  14. Advanced coal liquefaction. Final quarterly report, January 1, 1996--March 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-06-01

    Coal liquid upgrading using compound No. 9, 4-(1-naphthymethyl) bibenzyl, as a model was performed in a catalytic membrane reactor in this quarter. Membrane packed with granular catalyst synthesized from Si-CVD coatedy-Al{sub 2}O{sub 3} was used as a reactor. A control was also performed using the same reactor under a packed-bed operation mode. About 52% conversion of compound No. 9 was obtained in a packed-bed at 400{degrees}C and 200 psi. Under a similar operating condition, compound No. 9 was completely decomposed in the catalytic membrane reactor. The results offer the experimental evidence of enhanced upgrading efficiency of upgrading coal liquid using a membrane reactor. A similar study will be duplicated before the end of the contract.

  15. Molten salt coal gasification process development unit. Phase 1. Volume 1. PDU operations. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Kohl, A.L.

    1980-05-01

    This report summarizes the results of a test program conducted on the Molten Salt Coal Gasification Process, which included the design, construction, and operation of a Process Development Unit. In this process, coal is gasified by contacting it with air in a turbulent pool of molten sodium carbonate. Sulfur and ash are retained in the melt, and a small stream is continuously removed from the gasifier for regeneration of sodium carbonate, removal of sulfur, and disposal of the ash. The process can handle a wide variety of feed materials, including highly caking coals, and produces a gas relatively free from tars and other impurities. The gasification step is carried out at approximately 1800/sup 0/F. The PDU was designed to process 1 ton per hour of coal at pressures up to 20 atm. It is a completely integrated facility including systems for feeding solids to the gasifier, regenerating sodium carbonate for reuse, and removing sulfur and ash in forms suitable for disposal. Five extended test runs were made. The observed product gas composition was quite close to that predicted on the basis of earlier small-scale tests and thermodynamic considerations. All plant systems were operated in an integrated manner during one of the runs. The principal problem encountered during the five test runs was maintaining a continuous flow of melt from the gasifier to the quench tank. Test data and discussions regarding plant equipment and process performance are presented. The program also included a commercial plant study which showed the process to be attractive for use in a combined-cycle, electric power plant. The report is presented in two volumes, Volume 1, PDU Operations, and Volume 2, Commercial Plant Study.

  16. Improved Fischer-Tropsch catalysts for indirect coal liquefaction. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, R.B. Jr.; Tong, G.T.; Chan, Y.W.; Huang, H.W.; McCarty, J.G.

    1989-02-01

    The Fischer-Tropsch synthesis (FTS)reaction is the established technology for the production of liquid fuels from coal by an indirect route using coal-derived syngas (CO + H{sub 2}). Modern FTS catalysts are potassium- and copper-promoted iron preparations. These catalysts exhibit moderate activity with carbon monoxide-rich feedstocks such as the syngas produced by advanced coal gasification processes. However, the relatively large yields of by-product methane and high-molecular-weight hydrocarbon waxes detract from the production of desired liquid products in the C{sub 5}-C{sub 16} range needed for motor and aviation fuel. The goal of this program is to decrease undesirable portions of the FTS hydrocarbon yield by altering the Schultz-Flory polymerization product distribution through design and formulation of improved catalysts. Two approaches were taken: (1) reducing the yield of high-molecular-weight hydrocarbon waxes by using highly dispersed catalysts produced from surface-confined multiatomic clusters on acid supports and (2) suppressing methane production by uniformly pretreating active, selective conventional FTS catalysts with submonolayer levels of sulfur.

  17. Development of a coal fired pulse combustor for residential space heating. Phase I, Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1988-04-01

    This report presents the results of the first phase of a program for the development of a coal-fired residential combustion system. This phase consisted of the design, fabrication, testing, and evaluation of an advanced pulse combustor sized for residential space heating requirements. The objective was to develop an advanced pulse coal combustor at the {approximately} 100,000 Btu/hr scale that can be integrated into a packaged space heating system for small residential applications. The strategy for the development effort included the scale down of the feasibility unit from 1-2 MMBtu/hr to 100,000 Btu/hr to establish a baseline for isolating the effect of scale-down and new chamber configurations separately. Initial focus at the residential scale was concentrated on methods of fuel injection and atomization in a bare metal unit. This was followed by incorporating changes to the advanced chamber designs and testing of refractory-lined units. Multi-fuel capability for firing oil or gas as a secondary fuel was also established. Upon completion of the configuration and component testing, an optimum configuration would be selected for integrated testing of the pulse combustor unit. The strategy also defined the use of Dry Ultrafine Coal (DUC) for Phases 1 and 2 of the development program with CWM firing to be a product improvement activity for a later phase of the program.

  18. Life assessment and emissions monitoring of Indian coal-fired power plants. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1992-07-01

    At the request of the Pittsburgh Energy Technology Center (PETC) of the United States Department of Energy (USDOE), the traveler, along with Dr. R. P. Krishnan, Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee spent three weeks in India planning and performing emissions monitoring at the coal-fired Vijayawada Thermal Power Station (VTPS). The coordination for the Indian participants was provided by BHEL, Trichy and CPRI, Bangalore. The trip was sponsored by the PETC under the United States Agency for International Development (USAID)/Government of India (GOI)P Alternate Energy Resources Development (AERD) Project. The AERD Project is managed by PETC, and ORNL is providing the technical coordination and support for four coal projects that are being implemented with BHEL, Trichy. The traveler, after briefing the USAID mission in New Delhi visited BHEL, Trichy and CPRI, Bangalore to coordinate and plan the emissions test program. The site selection was made by BHEL, CPRI, TVA, and PETC. Monitoring was performed for 4 days on one of the 4 existing 210 MW coal-fired boilers at the VTPS, 400 km north of Madras, India.

  19. How to Manage Rejected Scientific Papers? UNAIS as Final Solution

    Directory of Open Access Journals (Sweden)

    Alessandro Diana

    2012-07-01

    Full Text Available Before publication, biomedical papers might undergo a very complex process, from journal selection, authors’ motivations for submissions, modifications, and final publication or refusal. UNAIS (Unpublished Articles In Science is an online repository in which authors can publish previously rejected scientific articles or articles that have never been submitted for publication. At UNAIS, authors can also publish the reasons behind the refusals to publication. UNAIS is more than an e-journal: it is a scientific drop box in which scientists can find indicative and negative results, as well as ideas that can inspire others. UNAIS’s goal is also to help students and scientists who want to learn how to write scientific articles. UNAIS’ aim is to exchange and promote knowledge. Have a look on www.unais.net.

  20. Petrographic, mineralogical, and chemical characterization of certain Alaskan coals and washability products. Final report, July 11, 1978-October 11, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Rao, P.D.; Wolff, E.N.

    1981-05-01

    Petrological, mineralogical and chemical characterization provides basic information needed for proper utilization of coals. Since many of these coals are likely to be beneficiated to reduce ash, the influence of coal washing on the characteristics of the washed product is important. Twenty samples of Alaskan coal seams were used for this study. The coals studied ranged in rank from lignite to high volatile A bituminous with vitrinite/ulminite reflectance ranging from 0.25 to 1.04. Fifteen raw coals were characterized for proximate and ultimate analysis reflectance rank, petrology, composition of mineral matter, major oxides and trace elements in coal ash. Washability products of three coals from Nenana, Beluga and Matanuska coal fields were used for characterization of petrology, mineral matter and ash composition. Petrological analysis of raw coals and float-sink products showed that humodetrinite was highest in top seam in a stratigraphic sequence

  1. Secondary Industrial Minerals from Coal Fly Ash and Aluminium Anodising Waste Solutions

    NARCIS (Netherlands)

    Nugteren, H.W.

    2010-01-01

    Minerals that are extracted from the earth’s crust to be directly used for their properties are called industrial minerals. This research shows that such minerals can also be produced from industrial residues, hence the name secondary industrial minerals. In this thesis coal fly ash is chosen as one

  2. Adsorption of Crystal Violet Dye from Aqueous Solution onto Zeolites from Coal Fly and Bottom Ashes

    Directory of Open Access Journals (Sweden)

    Tharcila Colachite Rodrigues Bertolini

    2013-11-01

    Full Text Available The adsorption of the cationic dye Crystal Violet (CV over zeolites from coal fly ash (ZFA and bottom ash (ZBA was evaluated. The coal fly ash (CFA and the coal bottom ash (CBA used in the synthesis of the zeolites by alkaline hydrothermal treatment were collected in Jorge Lacerda coal-fired power plant located at Capivari de Baixo County, in Santa Catarina State, Brazil. The zeolitic materials were characterized predominantly as hydroxy-sodalite and X. The dye adsorption equilibrium was reached after 10 min for ZFA and ZBA. The kinetics studies indicated that the adsorption followed the pseudo-second order kinetics and that surface adsorption and intraparticle diffusion were involved in the adsorption mechanism for both the adsorbents. The equilibrium data of ZFA was found to best fit to the Langmuir model, while ZBA was best explained by the Freundlich model. The maximum adsorption capacities were 19.6 mg g-1 for the CV/ZFA and 17.6 mg g-1 for the CV/ZBA.

  3. High Performance Building Facade Solutions - PIER Final Project Report

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Eleanor; Selkowitz, Stephen

    2009-12-31

    Building facades directly influence heating and cooling loads and indirectly influence lighting loads when daylighting is considered, and are therefore a major determinant of annual energy use and peak electric demand. Facades also significantly influence occupant comfort and satisfaction, making the design optimization challenge more complex than many other building systems.This work focused on addressing significant near-term opportunities to reduce energy use in California commercial building stock by a) targeting voluntary, design-based opportunities derived from the use of better design guidelines and tools, and b) developing and deploying more efficient glazings, shading systems, daylighting systems, facade systems and integrated controls. This two-year project, supported by the California Energy Commission PIER program and the US Department of Energy, initiated a collaborative effort between The Lawrence Berkeley National Laboratory (LBNL) and major stakeholders in the facades industry to develop, evaluate, and accelerate market deployment of emerging, high-performance, integrated facade solutions. The LBNL Windows Testbed Facility acted as the primary catalyst and mediator on both sides of the building industry supply-user business transaction by a) aiding component suppliers to create and optimize cost effective, integrated systems that work, and b) demonstrating and verifying to the owner, designer, and specifier community that these integrated systems reliably deliver required energy performance. An industry consortium was initiated amongst approximately seventy disparate stakeholders, who unlike the HVAC or lighting industry, has no single representative, multi-disciplinary body or organized means of communicating and collaborating. The consortium provided guidance on the project and more importantly, began to mutually work out and agree on the goals, criteria, and pathways needed to attain the ambitious net zero energy goals defined by California and

  4. Synthesis of model compounds for coal liquefaction research: Final report, June 21, 1990--July 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Hirschon, A.S.; Asaro, M.; Bottaro, J.

    1993-07-01

    The objectives of this project were to develop feasible synthetic routes to produce (1) 4(4{prime}-hydroxy-5{prime}6{prime},7{prime}8{prime}-tetrahydro-1{prime}-naphthylmethyl)-6-methyldibenzothiophene, and (2) a 1-hydroxynaphthalene-dibenzothiophene polymer. These compounds are thought to be representative of sulfur containing molecules in coal. The program was divided into two technical tasks. Unfortunately, the attempted syntheses of these compounds was unsuccessful due to their unusual reactivities. Attempted synthetic routes and possible future routes are described, and Appendix A lists the compounds that were synthesized during this program.

  5. Transformations of inorganic coal constituents in combustion systems. Volume 3, Appendices: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Helble, J.J. [ed.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. [PSI Technology Co., Andover, MA (United States); Kang, Shim-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Peterson, T.W.; Wendt, O.L.; Gallagher, N.B.; Bool, L. [Arizona Univ., Tucson, AZ (United States); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. [Kentucky Univ., Lexington, KY (United States)

    1992-11-01

    This report contains the computer codes developed for the coal combustion project. In Subsection B.1 the FORTRAN code developed for the percolative fragmentation model (or the discrete model, since a char is expressed as a collection of discrete elements in a discrete space) is presented. In Subsection B.2 the code for the continuum model (thus named because mineral inclusions are distributed in a continuum space) is presented. A stereological model code developed to obtain the pore size distribution from a two-dimensional data is presented in Subsection B.3.

  6. Transformations of inorganic coal constituents in combustion systems. Volume 2, Sections 6 and 7: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Helble, J.J. [ed.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. [PSI Technology Co., Andover, MA (United States); Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. [Arizona Univ., Tucson, AZ (United States); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. [Kentucky Univ., Lexington, KY (United States)

    1992-11-01

    Results from an experimental investigation of the mechanisms governing the ash aerosol size segregated composition resulting from the combustion of pulverized coal in a laboratory scale down-flow combustor are described. The results of modeling activities used to interpret the results of the experiments conducted under his subtask are also described in this section. Although results from the entire program are included, Phase II studies which emphasized: (1) alkali behavior, including a study of the interrelationship between potassium vaporization and sodium vaporization; and (2) iron behavior, including an examination of the extent of iron-aluminosilicate interactions, are highlighted. Idealized combustion determination of ash particle formation and surface stickiness are also described.

  7. Preconversion processing of bituminous coals: New directions to improved direct catalytic coal liquefaction. Final report, September 20, 1991--September 19, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-01

    One of the main goals for competitive coal liquefaction is to decrease gas yields to reduce hydrogen consumption. Complexing this element as methane and ethane decreases process efficiently and is less cost effective. To decrease the gas yield and increase the liquid yield, an effective preconversion process has been explored on the basis of the physically associated molecular nature of coal. Activities have been focused on two issues: (1) maximizing the dissolution of associated coal and (2) defining the different reactivity associated with a wide molecular weight distribution. Two-step soaking at 350{degrees}C and 400{degrees}C in a recycle oil was found to be very effective for coal solubilization. No additional chemicals, catalysts, and hydrogen are required for this preconversion process. High-volatile bituminous coals tested before liquefaction showed 80--90% conversion with 50--55% oil yields. New preconversion steps suggested are as follows: (1) dissolution of coal with two-step high-temperature soaking, (2) separation into oil and heavy fractions of dissolved coal with vacuum distillation, and (3) selective liquefaction of the separated heavy fractions under relatively mild conditions. Laboratory scale tests of the proposed procedure mode using a small autoclave showed a 30% increase in the oil yield with a 15--20% decrease in the gas yield. This batch operation projects a substantial reduction in the ultimate cost of coal liquefaction.

  8. Effect of coal beneficiation process on rheology/atomization of coal water slurries. Final report, October 1, 1992--July 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Ohene, F.

    1997-05-01

    To examine the factors that govern fine spray production during atomization of coal water slurries, an experimental study of the effect of coal beneficiation and their rheological properties on atomization of clean slurries was proposed. The objective of this study was to understand the effect of low shear, high shear rheology, and viscoelastic behavior on the atomization of beneficiated slurries.

  9. Cooperative research in coal liquefaction infratechnology and generic technology development: Final report, October 1, 1985 to December 31, 1986

    Energy Technology Data Exchange (ETDEWEB)

    Sendlein, L.V.A.

    1987-06-29

    During the first year of its research program, the Consortium for Fossil Fuel Liquefaction Science has made significant progress in many areas of coal liquefaction and coal structure research. Research topics for which substantial progress has been made include integrated coal structure and liquefaction studies, investigation of differential liquefaction processes, development and application of sophisticated techniques for structural analysis, computer analysis of multivariate data, biodesulfurization of coal, catalysis studies, co-processing of coal and crude oil, coal dissolution and extraction processes, coal depolymerization, determination of the liquefaction characteristics of many US coals for use in a liquefaction database, and completion of a retrospective technology assessment for direct coal liquefaction. These and related topics are discussed in considerably more detail in the remainder of this report. Individual projects are processed separately for the data base.

  10. Environmental impact of coal ash on tributary streams and nearshore water or Lake Erie. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wood, K.G.

    1978-08-01

    The environmental impact of coal ash disposal at a landfill site in north-central Chautauqua County, New York was studied from June 1975 through July 1977. Water samples taken from wells, ponds, and streams at 67 sites were analyzed for specific conductance, pH, alkalinity, arsenic, calcium, cadmium, chloride, chromium, copper, iron, magnesium, manganese, potassium, selenium, sodium, sulfate and zinc. Evidence suggests that ponds at the landfill were high in Ca, Fe, Mg, Mn, and SO/sub 4/ compared to control pands. A stream adjacent to the site contained greater Mn (207 ug/1) and SO/sub 4/ (229 ppm) than control streams. Shallow alkaline test wells in the landfill had elevated As, Ca, and Se. Acid-neutral test wells had elevated As, Ca, Cr, Mg and Mn. Household wells in the vicinity of the landfill showed no evident contamination from the landfill. Average iron concentrations in the biota were tripled, and manganese concentrations doubled in biota affected by the coal ash dump. However, any effects of the disposal area on the distribution of the biota could not be separated from effects of varying environment factors such as water movements, substrate composition and food availability. No harmful effects could be demonstrated on the biota in the creek which flowed past the disposal area.

  11. Diffusion of gases in coals and chars: Final report, September 15, 1985--September 14, 1988

    Energy Technology Data Exchange (ETDEWEB)

    Smith, D.M.

    1988-01-01

    Eight PSOC coals representing a wide range of rank and geographic origin have been subjected to a wide range of pore structure analysis methods as well as gas diffusion measurements. Pore structure analysis techniques employed included carbon dioxide and nitrogen adsorption, helium pycnometry, mercury porosimetry, and low-field NMR spin-lattice relaxation measurements. In principle, NMR pore structure analysis avoids many of the problems associated with conventional pore structure methods such as pore structure changes during drying, sample compression, network/percolation effects, pore shape assumptions, and a limited pore size range. Spin-lattice relaxation measurements were conducted at a proton frequency of 20 MHz and 303 K using water contained in the coal pores. Pore size distributions were obtained via deconvolution of the NMR relaxation measurements using the method of regularization and application of the ''two fraction-fast exchange'' model of pore fluid behavior. A qualitative comparison of the NMR pore size distributions and surface areas (CO/sub 2//N/sub 2/) yielded good agreement. Monodisperse and bidisperse pore size distributions were noted with pore volume in the size range of <0.5 nm to 0.5 ..mu..m. Effective diffusivities of methane and nitrogen were measured at 303 K and ambient pressure using a pulse tracer analysis method. 37 refs., 14 figs., 5 tabs.

  12. A study of toxic emissions from a coal-fired gasification plant. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-01

    Under the Fine Particulate Control/Air Toxics Program, the US Department of Energy (DOE) has been performing comprehensive assessments of toxic substance emissions from coal-fired electric utility units. An objective of this program is to provide information to the US Environmental Protection Agency (EPA) for use in evaluating hazardous air pollutant emissions as required by the Clean Air Act Amendments (CAAA) of 1990. The Electric Power Research Institute (EPRI) has also performed comprehensive assessments of emissions from many power plants and provided the information to the EPA. The DOE program was implemented in two. Phase 1 involved the characterization of eight utility units, with options to sample additional units in Phase 2. Radian was one of five contractors selected to perform these toxic emission assessments.Radian`s Phase 1 test site was at southern Company Service`s Plant Yates, Unit 1, which, as part of the DOE`s Clean Coal Technology Program, was demonstrating the CT-121 flue gas desulfurization technology. A commercial-scale prototype integrated gasification-combined cycle (IGCC) power plant was selected by DOE for Phase 2 testing. Funding for the Phase 2 effort was provided by DOE, with assistance from EPRI and the host site, the Louisiana Gasification Technology, Inc. (LGTI) project This document presents the results of that effort.

  13. Novel technique for coal pyrolysis and hydrogenation product analysis. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Pfefferle, L.D.; Boyle, J.

    1993-03-15

    A microjet reactor coupled to a VUV photoionization time-of-flight mass spectrometer has been used to obtain species measurements during high temperature pyrolysis and oxidation of a wide range of hydrocarbon compounds ranging from allene and acetylene to cyclohexane, benzene and toluene. Initial work focused on calibration of the technique, optimization of ion collection and detection and characterization of limitations. Using the optimized technique with 118 nm photoionization, intermediate species profiles were obtained for analysis of the hydrocarbon pyrolysis and oxidation mechanisms. The ``soft`` ionization, yielding predominantly molecular ions, allowed the study of reaction pathways in these high temperature systems where both sampling and detection challenges are severe. Work has focused on the pyrolysis and oxidative pyrolysis of aliphatic and aromatic hydrocarbon mixtures representative of coal pyrolysis and hydropyrolysis products. The detailed mass spectra obtained during pyrolysis and oxidation of hydrocarbon mixtures is especially important because of the complex nature of the product mixture even at short residence times and low primary reactant conversions. The combustion community has advanced detailed modeling of pyrolysis and oxidation to the C4 hydrocarbon level but in general above that size uncertainties in rate constant and thermodynamic data do not allow us to a priori predict products from mixed hydrocarbon pyrolyses using a detailed chemistry model. For pyrolysis of mixtures of coal-derived liquid fractions with a large range of compound structures and molecular weights in the hundreds of amu the modeling challenge is severe. Lumped models are possible from stable product data.

  14. Coal liquefaction process streams characterization and evaluation. Volume 2, Participants program final summary evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Brandes, S.D.; Robbins, G.A.; Winschel, R.A.; Burke, F.P.

    1994-05-01

    This 4.5-year project consisted of routine analytical support to DOE`s direct liquefaction process development effort (the Base Program), and an extensive effort to develop, demonstate, and apply new analytical methods for the characterization of liquefaction process streams (the Participants Program). The objective of the Base Program was to support the on-going DOE direct coal liquefaction process development program. Feed, process, and product samples were used to assess process operations, product quality, and the effects of process variables, and to direct future testing. The primary objective of the Participants Program was to identify and demonstrate analytical methods for use in support of liquefaction process develpment, and in so doing, provide a bridge between process design, development, and operation and analytical chemistry. To achieve this direct coal liquefaction-derived materials. CONSOL made an evaluation of each analytical technique. During the performance of this project, we obtained analyses on samples from numerous process development and research programs and we evaluated a variety of analytical techniques for their usefulness in supporting liquefaction process development. Because of the diverse nature of this program, we provide here an annotated bibliography of the technical reports, publications, and formal presentations that resulted from this program to serve as a comprehensive summary of contract activities.

  15. Removal of Copper(II and Zinc(II Ions From Aqueous Solution by Chemical Treatment of Coal Fly Ash

    Directory of Open Access Journals (Sweden)

    Eleonora Sočo

    2015-12-01

    Full Text Available The aim of this study was to investigate the chemical modifications of coal fly ash (CFA treated with HNO3 or ammonium acetate (AcNH4 or NaOH or sodium diethyldithiocarbamate (NaDDTC as an adsorbent for the removal of copper(II and zinc(II ions from aqueous solution. The morphology of fly ash grains before and after modification was examined via X-ray diffraction (XRD and images of scanning electron microscope (SEM. Adsorption of copper(II and zinc(II ions was conducted under batch process at different duration, concentrations and temperature of the suspension. Equilibrium experiments shows that the selectivity of CFA-NaOH nanoparticles towards Cu(II ions is greater than that of Zn(II ions, which is related to their hydrated ionic radius and first hydrolysis equilibrium constant. The adsorption isotherms were described by Langmuir and Freundlich models. Kinetic data revealed that the adsorption fits well by the pseudo-second-order rate model with high regression coefficients. Thermodynamic parameters suggested that the immobilization Cu(II and Zn(II ions onto CFA-NaOH is a spontaneous process. Results demonstrated that the treating coal fly ash with alkaline solution was a promising way to enhance Cu(II and Zn(II ions adsorption.

  16. Pressure combustion of Rhenish brown coal. Final report; Druckkohlenstaubverbrennung von rheinischer Braunkohle. Abschlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Ayar, A.; Fielenbach, C.; Gross, R.; Holfeld, T.; Lockemann, S.; Severin, C.; Thulfaut, C.; Hillemacher, B.

    2003-07-01

    NOx formation and reduction in the coal combustion process was investigated both experimentally and theoretically. The influence of coal grain size described in earlier publications was proved by the measurements at the DKSF test facility at Aachen. While no pressure dependence was established so far for lignite, measurements on Spitzbergen coal at 9 - 13 bar showed a decrease in NOx concentrations with increasing pressure. This effect will be investigated for Rhenish brown coal in further experiments. Modelling by the standard FLUENT code and by the user defined subroutines of the FLUENT code developed by the International Flame Research Foundation (IFRF), Ijmuiden, showed that the different predictions of flame temperatures have a decisive role in the modelling of NOx formation. A more accurate analysis of the NOx models as compared to ther measurements will be carried out in a melting chamber furnace with a stable flame. Additionally, measurements were carried out for investigating the kinetics of homogeneous gaseous phase reactions in flue gases, i.e. the thermal and additive-catalysed degradation of nitrous components was investigated. The kinetics of the process was also described by a code developed at Aachen University. On the base of a sensitivity analysis, a reduction of the detailed modelling of the reaction kinetics is achieved which permits 2D and 3D calculations on the decomposition of different flue gas components using a CFD code like FLUENT. The 1D and 2D calculations and the measurements were found to be in good agreement. [German] Im Rahmen des Forschungsschwerpunkts 3 wurde experimentell und theoretisch die NO{sub x}-Bildung und -Reduktion bei der Druckkohlenstaubverbrennung untersucht. Der zuvor beschriebene Einfluss der Kohlemahlung auf die Flamme konnte auch anhand der NO{sub x}-Messungen an der DKSF-Anlage Aachen bestaetigt werden. Waehrend mit Braunkohle im Staubfeuerungsbetrieb noch keine eindeutige Druckabhaengigkeit nachgewiesen werden

  17. Coal liquefaction: A research and development needs assessment: Final report, Volume II

    Energy Technology Data Exchange (ETDEWEB)

    Schindler, H.D.; Burke, F.P.; Chao, K.C.; Davis, B.H.; Gorbaty, M.L.; Klier, K.; Kruse, C.W.; Larsen, J.W.; Lumpkin, R.E.; McIlwain, M.E.; Wender, I.; Stewart, N.

    1989-03-01

    Volume II of this report on an assessment of research needs for coal liquefaction contains reviews of the five liquefaction technologies---direct, indirect, pyrolysis, coprocessing, and bioconversion. These reviews are not meant to be encyclopedic; several outstanding reviews of liquefaction have appeared in recent years and the reader is referred to these whenever applicable. Instead, these chapters contain reviews of selected topics that serve to support the panel's recommendations or to illustrate recent accomplishments, work in progress, or areas of major research interest. At the beginning of each of these chapters is a brief introduction and a summary of the most important research recommendations brought out during the panel discussions and supported by the material presented in the review. A review of liquefaction developments outside the US is included. 594 refs., 100 figs., 60 tabs.

  18. Renewable wood fuel: Fuel feed system for a pulverized coal boiler. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-01-01

    This report evaluates a pilot test program conducted by New York State Gas & Electric Corporation to evaluate the feasibility of co-firing a pulverized coal plant with renewable wood fuels. The goal was to establish that such a co-firing system can reduce air emissions while maintaining good operational procedures and cost controls. The test fuel feed system employed at Greenidge Station`s Boiler 6 was shown to be effective in feeding wood products. Emission results were promising and an economic analysis indicates that it will be beneficial to pursue further refinements to the equipment and systems. The report recommends further evaluation of the generation and emission impacts using woods of varied moisture contents and at varied Btu input rates to determine if a drying system would be a cost-effective option.

  19. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 4

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Bruce; Shea, Winton

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In

  20. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 1

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Bruce; Winton, Shea

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to

  1. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 3

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Bruce; Shea, Winton

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to

  2. Advanced NMR-based techniques for pore structure analysis of coal. Final project report

    Energy Technology Data Exchange (ETDEWEB)

    Smith, D.M.; Hua, D.W. [Univ. of New Mexico, Albuquerque, NM (United States). UNM/NSF Center for Micro-Engineered Ceramics; Earl, W. [Los Alamos National Lab., NM (United States)

    1996-02-01

    During the 3 year term of the project, new methods have been developed for characterizing the pore structure of porous materials such as coals, carbons, and amorphous silica gels. In general, these techniques revolve around; (1) combining multiple techniques such as small-angle x-ray scattering (SAXS) and adsorption of contrast-matched adsorbates or {sup 129}Xe NMR and thermoporometry (the change in freezing point with pore size), (2) combining adsorption isotherms over several pressure ranges to obtain a more complete description of pore filling, or (3) applying NMR ({sup 129}Xe, {sup 14}N{sub 2}, {sup 15}N{sub 2}) techniques with well-defined porous solids with pores in the large micropore size range (>1 nm).

  3. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 5

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Bruce; Shea, Winton

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In

  4. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 2

    Energy Technology Data Exchange (ETDEWEB)

    Miller, Bruce; Winton, Shea

    2010-12-31

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to

  5. Genetic approach to microbial coal desulfurization: Final report, January 1--December 31, 1988

    Energy Technology Data Exchange (ETDEWEB)

    Clark, D. P.

    1989-03-01

    Naturally occurring sulfur bacteria such as Thiobacillus and Sulfolobus have been shown to remove inorganic sulfur form coal. If genetically modified bacteria could be developed to attack the organic sulfur (which is not removed by natural sulfur bacteria) then it should be possible to devise a microbial process for coal desulfurization. Such a biological approach should be relatively cheap and safe and produce harmless waste products. We have developed a multiple mutant of Escherichia coli which can oxidize thiophene derivatives and are continuing to improve this strain. We have cloned DNA fragments from the chromosome of the triple mutant NAR30 thdA thdC thD. One plasmid pKA 15 carries what is presumably the thdA gene. Another plasmid, pKA 10, carries two genes designated thdF and thdG which, when present on a plasmid in multiple copies, confer the ability to oxidize thiophenes and furans. We think it probable that thdA is a regulator gene and that thdF and thdG are two of the structural genes which it regulates. Recently we have subcloned fragments of a large plasmid present in a natural isolate which degrades dibenzo-thiophene sulfone. No single fragment alone confers on an E. coli host the ability to degrade any aromatic substrate; however, certain mixtures of two or three fragments confer the ability to degrade benzoate. We have also mapped and partly characterized mutant affecting the enzyme thiosulfate: sulfur transferase (''rhodanese'') which removes (or inserts) sulfur from (or into) a variety of organic molecules. 26 refs., 6 figs., 6 tabs.

  6. Selenium transformation in coal mine spoils: Its environmental impact assessment. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Harness, J.; Atalay, A.; Koll, K.J.; Zhang, H.; Maggon, D.

    1991-12-31

    The objective of this program was to conduct an environmental impact assessment study for selenium from coal mine spoils. The use of in-situ lysimetry to predict selenium speciation, transformation, and mobility under natural conditions was evaluated. The scope of the study was to construct and test field-scale lysimeter and laboratory mini-column to assess mobility and speciation of selenium in coal mine overburden and soil systems; to conduct soil and groundwater sampling throughout the state of Oklahoma for an overall environmental impact assessment of selenium; and to conduct an in-depth literature review on the solubility, speciation, mobility, and toxicity of selenium from various sources. Groundwater and surface soil samples were also collected from each county in Oklahoma. Data collected from the lysimeter study indicated that selenium in the overburden of the abandoned mine site was mainly found in the selenite form. The amount of selenite found was too low and immobile to be of concern to the environment. The spoil had equilibrated long enough (over 50 years) that most of the soluble forms of selenium have already been lost. Examination of the overburden indicated the presence of pyrite crystals that precipitated over time. The laboratory mini-column study indicated that selenite is quite immobile and remained on the overburden material even after leaching with dilute acid. Data from groundwater samples indicated that based on the current permissible level for selenium in groundwater (0.01 mg Se/L), Oklahoma groundwater is widely contaminated with the element. However, according to the new regulation (0.05 mg Se/L), which is to be promulgated in 1992, only 9 of the 77 counties in the state exceed the limit.

  7. Protocols for the selective cleavage of carbon-sulfur bonds in coal. Final technical report, September 1, 1991--August 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Bausch, M. [Southern Illinois Univ., Carbondale, IL (United States)

    1992-12-31

    Summarized in the final technical report for our project ``Protocols for the Selective Cleavage of Carbon-Sulfur Bonds in Coal`` are results of research pertaining to chemical reactions that aim to selectively cleave C-S bonds in model compounds as well as Illinois coal. Removal of the organic sulfur in coal constitutes one of the major challenges facing fossil fuel scientists today. A cost-effective means of desulfurizing Illinois coal is, at present, non-existent. Research in our group aims to develop a simple protocol for sulfur removal by gaining understanding of how various additives and reaction conditions, including solvents, bases, added reagents, catalysts, oxidizing agents, electron acceptors, temperature, pressure, and light energy, can enhance the rates of C-S bond cleavage in Illinois coal and coal model compounds. These experiments have been at the focus of our research effort for the past twelve months. Previous quarterly reports described research results in which simple aromatic and aliphatic sulfides were allowed to react with (a) Lewis Acids such as zinc chloride and tin chloride; (b) electron accepting substrates such as 9-fluorenone and benzoquinone; (c) strong bases such as NaOH and KOH; (d) radical initiators such as AIBN; (e) neat solvents at reflux temperatures and higher temperatures; (f) molecular oxygen in the presence of dyes or sensitizers such as anthracene. In this final report, we report on additional experiments involving the photooxidation of organic sulfides, as well as some experiments aimed at evaluating and comparing the reactivities of simple organic sulfones with their sulfidyl analogues. Also contained in this final report is a brief summary of the research described in the previous three quarterly reports for ``Protocols for the Selective Cleavage of Carbon-Sulfur Bonds in Coal.``

  8. Simulation of coal and char nitrogen reactions in combustion. [Final report, September 1992--August 1993

    Energy Technology Data Exchange (ETDEWEB)

    Kumpaty, S.K.

    1993-10-01

    The observed rate of increase of N{sub 2}O (0.18% to 0.26% annually) is a matter of increasing concern both because N{sub 2}O is a greenhouse gas and has a major and unfavorable influence on the ozone layer (Weiss, 1981). The combustion contribution to the overall nitrous oxide budget is difficult to assess; yet the emission of N{sub 2}O from fluidized bed combustion (FBC) has been identified in the past few years as significant. It was concluded in the European workshop, 1988 that the emission level from a coal-fired fluidized bed boiler is 50--200 ppM but it is only 1--20 ppM in boilers equipped with other types of combustion devices. For this reason it is worthwhile to investigate the emissions from FBC more thoroughly. Gaseous fuels (Miller and Bowman, 1989), but the N{sub 2}O emissions under fluidized bed conditions is poorly understood. In fluidized bed combustion, N{sub 2}O can arise from homogeneous gas phase reactions involving amines and cyano species (Hiltunen et al, 1991) or it can be formed from heterogeneous reactions (eg. char oxidation). Removal of N{sub 2}O can be brought about by gas phase reactions or by catalytic or non-catalytic heterogeneous reduction on char/limestone. This work was carried out with an objective of enhancing the fundamental understanding of coal and char nitrogen reaction pathways in fluidized bed combustion environment. The formation and destruction of HCN and N{sub 2}O under variety of influential parameters were investigated. This simulation contained a nonisothermal single particle combustion in a preheated reactor and a gas phase reaction are designed to stimulate the nitrogen chemistry in a circulating fluidzied bed. The LSODE differential equation solver used for single particle combustion and the CHEMKIN package, developed by Sandia National Laboratories, was applied for gas phase reactions. This computational work was done as an exploratory research program under the solicitation of the DOE fossil energy utilization.

  9. The chemical enhancement of the triboelectric separation of coal from pyrite and ash: A novel approach for electrostatic separation of mineral matter from coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Gustafson, R.M.; DiMare, S.; Sabatini, J.

    1992-02-01

    Arthur D. Little, Inc., under contract to the US DOE Pittsburgh Energy Technology Center, has developed a triboelectric separation device for coal beneficiation, that employs an entrained-flow, rotating-cylinder concept. The described apparatus has been used to test the efficacy of chemical pretreatment and in-situ treatment of coal on separation efficiency. Coal particle entrainment is achieved with gaseous carbon dioxide and particle collection is accomplished by an electrostatic plate separator. The triboelectric separation device incorporates instrumentation for the direct measurement of charge in the dilute-phase particle stream. Some of the pretreatment materials investigated under this project to modify the surface charging characteristics of the coal included oleic acid, sodium oleate, quinoline and dicyclohexylamine. Ammonia and sulfur dioxide at a concentration up to 1000 ppM was used for in-situ treatment of the coal, with carbon dioxide as the carrier/inerting gas. Nitrogen was used earlier in the test program as the carrier/inerting gas for the coal, but a severe arcing problem was encountered in the electrostatic collector with nitrogen as the carrier gas. This problem did not occur when carbon dioxide was used. The report covers the chemical treatment employed, and summarizes and interprets the results achieved. In addition, an economic analysis of a full scale system based on this concept is presented.

  10. Effects of long-term coal supply contracts on technology adoption and improvements in the mining of coal. Final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Walton, D.R.; Hawkins, S.A.; Webb, P.F.; Kauffman, P.W.

    1979-08-01

    The relationship between long-term coal supply contracts and the adoption of new technology in the coal mining industry is a complex one. From this study certain conclusions can be drawn. New technologies and improvements in the mining of coal can be logically categorized into three areas: evolutionary technology, transitional technology, or innovative technology. Evolutionary improvements in technology can be categorized as improvements, or increased production capacities, in existing equipment. Transitional technology involves the adoption of existing or proven technologies into new conditions, or, proceeding from one technology type to a newer type for the same function. Innovative technology includes equipment, concepts, and systems not readily available, or untried, in the existing mining environment (seam conditions, etc.). Technology adoption is an economic decision. This point was repeatedly emphasized by industry representatives contacted during the study. The long-term coal supply contract influences the decision to adopt new technology and mining improvements in several ways depending on the technology type (i.e., evolutionary, transitional, or innovative), and also the coal supplier type (i.e., captive or independent producer). Several examples of the adoption of new technologies in mines under long-term coal supply contracts are discussed. (LTN)

  11. Petrographic characterization of Kentucky coals. Final report. Part IV. A petrographic and chemical model for the evolution of the Tradewater Formation coals in Western Kentucky

    Energy Technology Data Exchange (ETDEWEB)

    Graese, A.M.; Hower, J.C.; Ferm, J.C.

    1984-01-01

    A depositional model for the coals of the Tradewater Formation and associated rock units was constructed as a predictive device for the occurrence of economically important low sulfur coal. Twenty-one cores were examined and ninety-eight coal samples were analyzed for maceral, ash, and sulfur contents. These data were then analyzed to determine regional variation as well as vertical variation in single coal columns. Core data indicate that the majority of the Tradewater rocks consist of irregularly distributed, coarsening-upward, fine-grained detrital material which was deposited in shallow bodies of water. Minor fossiliferous shales and limestones suggest a marine influence. Less common coarse-grained, fining-upward sequences appear to be deposits of meandering channels. Like the detrital rocks, the coal seams are also irregularly distributed and exhibit variable petrographic and chemical properties reflecting changes in the Eh and pH of the coal swamp waters as well as detrital influx into the swamps. These swamps were relatively limited in extent and probably occupied the upper reaches of the tidal zone. The lack of significant stratigraphic and geographic trends in the regional data suggests that this mode of deposition was widespread and continued for a long period of time. 42 references, 19 figures, 9 tables.

  12. X-ray diffraction and scattering studies of coal constituents. Final technical report, January 1-December 31, 1983

    Energy Technology Data Exchange (ETDEWEB)

    Pavlovic, A. S.; Renton, J. T.

    1984-03-15

    The general objective of this work has been to use x-ray diffraction and scattering to examine whole coals, coal macerals and minerals in order to perform the following studies: (1) to identify and explain differences in vitrinites and framboids from various coals; (2) to correlate differences with basic coal compositions and properties; and (3) to determine the systematic variability in the micro compositional variation of macerals. The accomplishments have been: (a) the development of the Fourier transform technique to do proximate and ultimate analyses in a quick fashion; and (b) the investigation of the structure of pyrite framboids and preliminary studies of coal macerals. 3 figures, 12 tables.

  13. Solutions to the problem of waste deposition at a coal-fired power plant.

    Science.gov (United States)

    Oman, Janez; Dejanovic, Boris; Tuma, Matija

    2002-01-01

    This paper deals with the impact on the environment of the combined operation of a power plant and a coal mine located in Velenje, Slovenia. The consequences of intensive deep underground mining are the sinking of the surface and the filling up of the emerging hollows with water. As far as the various consequences of coal combustion are concerned, only the harmful effects of the surface deposition of ash and slag are discussed, with the poisoning of the lake and the river water being considered the most harmful. The integrated system of waste treatment at the power plant is presented. The idea of the system is to use the waste materials such as ash, slag, gypsum, contaminated water, etc. as the building materials or to apply them in the process of improving the ash dump and the environment. The system needs to be closed as much as possible, so that the waste cannot influence the surroundings of the dump. The physical and chemical properties of the waste materials from the power plant, the results of ecological measurements and the impact of the ecological damage are presented. In addition, we present: a description of the applied methods; the activities and the technical measures; the obtained results and the difficulties; and the problems that need to be overcome in order to normalise the ecological conditions.

  14. Assessment of instrumentation needs for advanced coal power plant applications: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, E.T.; Fischer, W.H.; Lipka, J.V.; Rutkowski, M.D.; Zaharchuk, R.

    1987-10-01

    The purpose of this study was to identify contaminants, identify instrumentation needs, assess available instrumentation and identify instruments that should be developed for controlling and monitoring gas streams encountered in the following power plants: Integrated Gasification Combined Cycle, Pressurized Fluidized Bed Combustion, and Gasification Molten Carbonate Fuel Cell. Emphasis was placed on hot gas cleanup system gas stream analysis, and included process control, research and environmental monitoring needs. Commercial process analyzers, typical of those currently used for process control purposes, were reviewed for the purpose of indicating commercial status. No instrument selection guidelines were found which were capable of replacing user interaction with the process analyzer vendors. This study leads to the following conclusions: available process analyzers for coal-derived gas cleanup applications satisfy current power system process control and regulatory requirements, but they are troublesome to maintain; commercial gas conditioning systems and in situ analyzers continue to be unavailable for hot gas cleanup applications; many research-oriented gas stream characterization and toxicity assessment needs can not be met by commercially available process analyzers; and greater emphasis should be placed on instrumentation and control system planning for future power plant applications. Analyzers for specific compounds are not recommended other than those needed for current process control purposes. Instead, some generally useful on-line laser-based and inductively coupled plasma methods are recommended for further development because of their potential for use in present hot gas cleanup research and future optimization, component protection and regulation compliance activities. 48 refs., 21 figs., 26 tabs.

  15. Management of solid wastes from the Limestone Injection Dry Scrubbing (LIDS) clean coal technology. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Musiol, W.F. Jr.; Czuczwa, J.M.

    1993-03-01

    The objectives of this project were to characterize by-products from a pilot Limestone Injection Dry Scrubbing (LIDS) process and to develop processes directed toward the safe and economic use or disposal of these wastes. Because LIDS is a developing Clean Coal technology, a database of chemical and physical characteristics of the by-product was first developed. During the course of this project, it was found that the waste alone did not form high-strength products sufficient for use in construction and engineering applications. Therefore, the project was redirected to evaluate the by-product as a soil-cement and Portland cement raw material, agricultural liming agent, backfill/landfill material component, and mine reclamation/neutralizing agent. Based on these evaluations, the most viable uses for the LIDS byproduct include use in mine reclamation or as a neutralization agent. If soluble sulfites can be minimized by avoiding a dolomitic LIDS reagent, use as an agricultural liming agent has promise. Interest from an Ohio utility in the LIDS process suggests possible application of results at the demonstration or commercial stages.

  16. Recovery of coal fines from preparation plant effluents. Final technical report, September 1, 1990--August 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Choudhry, V.

    1991-12-31

    The objectives of this project were to test and demonstrate the feasibility of recovering coal fines that are currently disposed of with coal preparation plant effluent streams and producing a fine clean coal product that can be blended with the plant coarse clean coal. This recovery was effected by means of Michigan Technological University`s static tube flotation process, which was successfully demonstrated on a number of raw coals to reject 85% of the pyritic sulfur and recover 90% of the combustible matter. Under this project, the process parameters for the technology were modified for this application in order to recover a low-ash, low-sulfur clean coal that is, at a minimum, compatible with the quality of the clean coal currently produced by the preparation plant.

  17. Coal and wood fuel for electricity production: An environmentally sound solution for waste and demolition wood

    Energy Technology Data Exchange (ETDEWEB)

    Penninks, F.W.M. [EPON, Zwolle (Netherlands)

    1997-12-31

    Waste wood from primary wood processing and demolition presents both a problem and a potential. If disposed in landfills, it consumes large volumes and decays, producing CH{sub 4}, CO{sub 2} and other greenhouse gases. As an energy source used in a coal fired power plant it reduces the consumption of fossil fuels reducing the greenhouse effect significantly. Additional advantages are a reduction of the ash volume and the SO{sub 2} and NO{sub x} emissions. The waste wood requires collection, storage, processing and burning. This paper describes a unique project which is carried out in the Netherlands at EPON`s Gelderland Power Plant (635 MW{sub e}) where 60 000 tonnes of waste and demolition wood will be used annually. Special emphasis is given to the processing of the powdered wood fuel. Therefore, most waste and demolition wood can be converted from an environmental liability to an environmental and economic asset. (author)

  18. Aquatic invertebrates in final void water bodies at an open-cut coal mine in central Queensland

    Energy Technology Data Exchange (ETDEWEB)

    Proctor, H.; Grigg, A. [Griffith University, Nathan, Qld. (Australia). Australian School of Environmental Studies

    2006-07-01

    We describe the diversity of aquatic invertebrates colonising water-filled final voids produced by an open-cut coal mine near Moura, central Queensland. Ten disused pits that had been filled with water from < 1 year to 22 years prior to the survey and three nearby 'natural' water bodies were sampled in December 1998 and again in March 1999. All invertebrates collected were identified to family with the exception of oligochaetes, cladocerans, ostracods and copepods, which were identified to these coarser taxonomic levels. Sixty-two taxa were recorded from > 20 000 individuals. The greatest familial richness was displayed by the Insecta (33 families) followed by the mites (Acari) with 12 families. While natural water bodies held the greatest diversity, several mine pits were almost as rich in families. Classification analyses showed that natural sites tended to cluster together, but the groupings did not clearly exclude pit sites. Mining pits that supported higher diversity tended to be older and had lower salinity (< 2000 {mu}S/cm); however, salinity in all water bodies varied with rainfall conditions. We conclude that ponds formed in final voids at this mine have the potential to provide habitat for many invertebrate taxa typical of lentic inland water bodies in central Queensland.

  19. An assessment of the long-term environmental impacts of reusing alkaline clay on coal refuse piles with a dynamic solute transport model at a watershed scale

    Science.gov (United States)

    Xu, Y.; Liang, X.; Davis, T. W.; Patterson, J.; Jaw, F. K.; Koranchie-Boah, P.

    2011-12-01

    Coal refuse piles play a significant role in producing acid mining drainage (AMD) that deteriorates water quality at a watershed scale. The waste produced from coal refuse piles results in a decrease of the pH value in soil water and river flow. Metal compounds, such as ferric and ferrous solutions, are also continuously released from the coal pile due to the extensive and complicated chemical reactions in the acidic environment. Alkaline clay, a byproduct of alumina refining process, has a high residual pH in the material. If the alkaline clay is used innovatively with the coal mine refuse, the problems associated with each (e.g., high and low pH values) are likely to be effectively resolved. In addition, the solubility of the sulfur and iron will be reduced significantly. This will effectively eliminate the AMD problem at the coal refuse pile and improve the water quality at the watershed scale. This study investigates the long-term impacts of the combined mixture (i.e., alkaline clay + coal refuse) on the environment (e.g., in the soil column and in the river system) through systematic modeling simulations in a combination with field measurements. In particular, a dynamic solute transport model that accounts for processes of the pyrite oxidation, oxygen diffusion, absorption, desorption, and advection is developed and is coupled with the Distributed Hydrology Soil and Vegetation Model (DHSVM) to assess the environmental impacts at the watershed scale. The model-simulated sulfur and iron concentrations are compared with field observations and the long-term impacts of the combined mixture (i.e., alkaline clay + coal refuse) on the environment are investigated. This study paves the way for monitoring and assessing the impacts of the reuse of the alkaline clay and refuse mixture on the environment at a watershed scale.

  20. Characteristics of American coals in relation to their conversion into clean-energy fuels. Final report. [1150 samples of US coals

    Energy Technology Data Exchange (ETDEWEB)

    Spackman, W.; Davis, A.; Walker, P.L.; Lovell, H.L.; Vastola, F.J.; Given, P.H.; Suhr, N.H.; Jenkins, R.G.

    1982-06-01

    To further characterize the Nation's coals, the Penn State Coal Sample Bank and Data Base were expanded to include a total of 1150 coal samples. The Sample Bank includes full-seam channel samples as well as samples of lithotypes, seam benches, and sub-seam sections. To the extent feasible and appropriate basic compositional data were generated for each sample and validated and computerized. These data include: proximate analysis, ultimate analysis, sulfur forms analysis, calorific value, maceral analysis, vitrinite reflectance analysis, ash fusion analysis, free-swelling index determination, Gray-King coke type determination, Hardgrove grindability determination, Vicker's microhardness determination, major and minor element analysis, trace element analysis, and mineral species analysis. During the contract period more than 5000 samples were prepared and distributed. A theoretical and experimental study of the pyrolysis of coal has been completed. The reactivity of chars, produced from all ranks of American coals, has been studied with regard to reactivity to air, CO/sub 2/, H/sub 2/ and steam. Another area research has concerned the catalytic effect of minerals and various cations on the gasification processes. Combustion of chars, low volatile fuels, coal-oil-water-air emulsions and other subjects of research are reported here. The products of this research can be found in 23 DOE Technical Research Reports and 49 published papers. As another mechanism of technology transfer, the results have been conveyed via more than 70 papers presented at a variety of scientific meetings. References to all of these are contained in this report.

  1. Subcontracted R and D final report: SRC-I phase equilibrium and enthalpy data for coal liquefaction and solvent recovery areas. Vol. 3

    Energy Technology Data Exchange (ETDEWEB)

    Mehta, D.C.; Chu, I.C.; Kidnay, A.J.; Yesavage, V.F.

    1984-03-01

    The Enthalpy Program was a 20-month project initiated on January 18, 1982 by the International Coal Refining Company (ICRC) and under the technical direction of Professor Arthur J. Kidnay and Professor V.F. Yesavage at the Colorado School of Mines (CSM), Golden, Colorado. The objective of the program was to gather enthalpy data on representative pure model compounds, mixtures of model compounds, and selected coal-derived liquid samples furnished by ICRC. A copy of the technical agreement between ICRC and CSM is included in this report as Appendix A. This final report contains a complete description of the calorimeter and the experimental procedures used, separate data sections for each experimental task, and a copy of the technical agreement between ICRC and CSM. Data are presented for 11 coal liquid fractions. Each section of this report is organized to stand alone; thus, there are no general lists of references, tables of notation, or overall data tables.

  2. Superacid Catalyzed Depolymerization and Conversion of Coals. Final Technical Report. [HF:BF{sub 2}/H{sub 2}

    Science.gov (United States)

    Olah, G.

    1980-01-01

    We were interested in applying superacid catalyzed cleavage-depolymerization and ionic hydrogenation low temperature conversion of coal to liquid hydrocarbon, as well as obtaining information about the reactions involved and the structure of intermediates of the coal liquefaction process. In order to show the feasibility of our proposed research we have carried out preliminary investigation in these areas. Preceding our work there was no practical application of a superacid system to coal liquefaction. We carried out an extensive study of the potential of the HF:BF{sub 3}/H{sub 2} system for coal hydroliquefaction. Under varying conditions of reactant ratio, reaction time and temperature, we were able to obtain over 95% pyridine extractible product by treating coal in HF:BF{sub 3}:H{sub 2} system at approx. 100 degrees C for 4 hours. The coal to acid ratio was 1:5 and FB{sub 3} at 900 psi and H{sub 2} at 500 psi were used. These are extremely encouraging results in that the conditions used are drastically milder than those used in any known process, such as Exxon donor solvent and related processes. The cyclohexane extractibility of the treated coal was as high as 27% and the yield of liquid distillate at 400 degrees C/5 x 10{sup -3}/sup torr/ was approx. 30%. The infrared spectrum of product coal, extracts and distillates were distinctly different from the starting coal and show a significant increase in the amount of saturates. The {sup 1}H NMR spectrum of cyclohexane extract of the treated coal shows essentially all aliphatic photons. The spectra of other treated coal extracts show increased amounts and types of aliphatic protons as well as significant amounts of protons bound to unsaturated sites. This again indicates that the HF-BF{sub 3} system is depolymerizing the coal to small fragments which are soluble in non-polar solvents.

  3. The development of coal-based technologies for Department of Defense facilities: Phase 1 final report. Volume 1: Technical report

    Energy Technology Data Exchange (ETDEWEB)

    Miller, B.G.; Morrison, J.L.; Pisupati, S.V. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center] [and others

    1997-01-31

    The first phase of a three-phase project investigating the development of coal-based technologies for Department of Defense facilities has been completed. The objectives of the project are to: decrease DOD`s dependence on foreign oil and increase its use of coal; promote public and private sector deployment of technologies for utilizing coal-based fuels in oil-designed combustion equipment; and provide a continuing environment for research and development of coal-based fuel technologies for small-scale applications at a time when market conditions in the US are not favorable for the introduction of coal-fired equipment in the commercial and industrial capacity ranges. The Phase 1 activities were focused on developing clean, coal-based combustion technologies for the utilization of both micronized coal-water mixtures (MCWMs) and dry, micronized coal (DMC) in fuel oil-designed industrial boilers. The specific objective in Phase 1 was to deliver fully engineered retrofit options for a fuel oil-designed watertube boiler located on a DOD installation to fire either MCWM or DMC. This was achieved through a project consisting of fundamental, pilot-sale, and demonstration-scale activities investigating coal beneficiation and preparation, and MCWM and DMC combustion performance. In addition, detailed engineering designs and an economic analysis were conducted for a boiler located at the Naval Surface Warfare Center, near Crane, Indiana. Results are reported on MCWM and DMC combustion performance evaluation; engineering design; and cost/economic analysis.

  4. Effects of calcium magnesium acetate on the combustion of coal-water slurries. Final project report, 1 September 1989--28 February 1993

    Energy Technology Data Exchange (ETDEWEB)

    Levendis, Y.A.; Wise, D.; Metghalchi, H.; Cumper, J.; Atal, A.; Estrada, K.R.; Murphy, B.; Steciak, J.; Hottel, H.C.; Simons, G.

    1993-07-01

    To conduct studies on the combustion of coal water fuels (CWFs) an appropriate facility was designed and constructed. The main components were (1) a high-temperature isothermal laminar flow furnace that facilitates observation of combustion events in its interior. The design of this system and its characterization are described in Chapter 1. (2) Apparatus for slurry droplet/agglomerate particle generation and introduction in the furnace. These devices are described in Chapters 1 and 3 and other attached publications. (3) An electronic optical pyrometer whose design, construction theory of operation, calibration and performance are presented in Chapter 2. (4) A multitude of other accessories, such as particle fluidization devices, a suction thermometer, a velocimeter, high speed photographic equipment, calibration devices for the pyrometer, etc., are described throughout this report. Results on the combustion of CWF droplets and CWF agglomerates made from micronized coal are described in Chapter 3. In the same chapter the combustion of CWF containing dissolved calcium magnesium acetate (CMA) axe described. The combustion behavior of pre-dried CWF agglomerates of pulverized grain coal is contrasted to that of agglomerates of micronized coal in Chapter 4. In the same chapter the combustion of agglomerates of carbon black and diesel soot is discussed as well. The effect of CMA on the combustion of the above materials is also discussed. Finally, the sulfur capture capability of CMA impregnated micronized and pulverized bituminous coals is examined in Chapter 5.

  5. Novel nanodispersed coal liquefaction catalysts: Molecular design via microemulsion-based synthesis. Final technical report, October 1990--December 1994

    Energy Technology Data Exchange (ETDEWEB)

    Osseo-Asare, K.; Boakye, E.; Vittal, M. [and others

    1995-04-01

    This report described the synthesis of Molybdenum Sulfides in microemulsions by acidification of ammonium tetrathiomolybdate. Molybdenum Sulfides have been shown to be potential coal liquefaction catalysts. The importance of particle size, temperature effects, and coal surface chemistry to impregnation are discussed.

  6. Development of an advanced high efficiency coal combustor for boiler retrofit. Task 1, Cold flow burner development: Final report

    Energy Technology Data Exchange (ETDEWEB)

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.

    1989-10-01

    The overall objective of this program is to develop a high efficiency advanced coal combustor (HEACC) for coal-based fuels capable of being retrofitted to industrial boilers originally designed for firing natural gas, distillate, and/or residual oil. The HEACC system is to be capable of firing microfine coal water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system are that it be simple to operate and will offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal fired combustor technology. The specific objective of this report is to document the work carried out under Task 1.0 of this contract, ``Cold Flow Burner Development``. As are detailed in the report, key elements of this work included primary air swirler development, burner register geometry design, cold flow burner model testing, and development of burner scale up criteria.

  7. Combustion of Illinois coals and chars with natural gas. Final technical report, September 1, 1991--August 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Buckius, R.O.; Peters, J.E.; Krier, H. [Illinois Univ., Urbana-Champaign, IL (United States)

    1992-12-31

    Combined combustion of coal and natural gas offers advantages compared to burning coal or natural gas alone. For example, low volatile coals (or chars) derived from treatment or gasification processes can be of limited use due to their poor flammability characteristics. However, the use of natural gas in conjunction with the solid fuel can provide the necessary ``volatiles`` to enhance the combustion. Also, natural gas provides a clean cofiring fuel source which can enhance the usefulness of coals with high sulfur content. Addition of natural gas may reduce SO{sub x} emissions through increased sulfur retention in the ash and reduce NO{sub x} emissions by varying local stoichiometry and temperature levels. This research program addresses the contributions and the mechanisms of cofiring natural gas with Illinois coal through studies of particle ignition, burning rates and ash characterization.

  8. Exploration of coal-based pitch precursors for ultra-high thermal conductivity graphite fibers. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Deshpande, G.V. [Amoco Performance Products, Inc., Alpharetta, GA (United States)

    1996-12-27

    Goal was to explore the utility of coal-based pitch precursors for use in ultra high thermal conductivity carbon (graphite) fibers. From graphite electrode experience, it was established that coal-based pitches tend to form more highly crystalline graphite at lower temperatures. Since the funding was limited to year 1 effort of the 3 year program, the goal was only partially achieved. The coal-base pitches can form large domain mesophase in spite of high N and O contents. The mesophase reactivity test performed on one of the variants of coal-based pitch (DO84) showed that it was not a good candidate for carbon fiber processing. Optimization of WVU`s isotropic pitch process is required to tailor the pitch for carbon fiber processing. The hetero atoms in the coal pitch need to be reduced to improve mesophase formation.

  9. Performance of a diesel engine operating on raw coal-diesel fuel and solvent refined coal-diesel fuel slurries. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Marshall, H.P.

    1980-03-01

    Performance tests using an 11 kW single cylinder diesel engine were made to determine the effects of three different micronized coal-fuel oil slurries being considered as alternative fuels. Slurries containing 20, 32, and 40%-wt micronized raw coal in No. 2 fuel oil were used. Results are presented indicating the changes in the concentrations of SO/sub X/ and NO/sub X/ in the exhaust, exhaust opacity, power and efficiency, and in wear rates relative to operation on fuel oil No. 2. The engine was operated for 10 h at full load and 1400 rpm on al fuels except the 40%-wt slurry. This test was discontinued because of extremely poor performance.

  10. Comparative study of humic acid extract with ammoniacal solutions from coals in inferior rank and from Romanian soil

    Energy Technology Data Exchange (ETDEWEB)

    Chiriac, J.; Barca, F. [Universitatea Politehnica din Bucuresti, Bucharest (Romania)

    2009-04-15

    The paper shows the similitude that exists between humic acids extracted from Rosia (Jiu) and Schitu Golesti Romanian mining sites for coals with inferior rank and those extracted from soil. The possibility of utilization of useless coal for energy-industry to introduce organic mass and humic acids in poor soils is sustained by these similarities. These coals introduced in soil could be ecological materials which give a better soil quality.

  11. Investigation of the effect of coal particle sizes on the interfacial and rheological properties of coal-water slurry fuels: Final report, July 1, 1994-June 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Kihm, K.D.

    1996-10-01

    The scope of the project is two fold: (1) examining particle size effect on interfacial properties of CWS fuels by measuring static and dynamic surface tension properties of specially prepared CWS samples containing different ranges of coal particle sizes, and (2) studying the effect of particle size on CWS atomization characteristics by measuring mean diameters of several different CWS sprays generated by sonic air blasting. The results show that both static and dynamic surface tensions decrease with increasing coal particle size and mean droplet diameter of CW-S sprays also decreases with increasing coal particle size. Based on the experimental evidence we conjecture that three different energies are competing in slurry atomization: (1) the internal capillary holding between particles and water, (2) the interfacial surface tensile energy at the slurry surface contacting air, and (3) the external air blast shear energy acting against the former two energies. The internal capillary holding force decreases with increasing particle size. This force is believed to play a major role in determining the effect of particle size on CWS atomization.

  12. Utilisation potential of products of microbial coal liquefaction. Final report; Verwertungspotential der Produkte der mikrobiellen Kohleverfluessigung. Abschlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Koepsel, R.; Schmiers, H.; Grosse, S.; Weber, A.

    2002-07-01

    Ever since the discovery in the 1980s that microorganisms are capable of converting coal into soluble products research groups all over the world have been exploring the bioconversion of coal. It was at an advance stage of the present integrated project, which initially only involved microbiology research groups, that the need for a chemical working group with knowledge and experience in the area of coal chemistry and structural analysis of coal was recognised. The task of the chemical working group was to provide knowledge on the chemical nature of bioconversion products and the chemical processes of coal bioconversion. This involved identifying structural changes occurring in the feed coal as well as in its constituent humic acids and macromolecular matrix as a result of the activity of coal degrading microorganisms. [German] Nachdem Anfang der achtziger Jahre entdeckt wurde, dass sich Kohlen durch Mikroorganismen in loesliche Produkte ueberfuehren lassen, agieren weltweit Forschergruppen auf dem Gebiet der Biokonversion von Kohle. In einem fortgeschrittenen Bearbeitungsstadium des Verbundprojektes, an dem zunaechst nur mikrobiologische Arbeitsgruppen beteiligt waren, wurde die Notwendigkeit erkannt, eine chemische Arbeitsgruppe mit Kenntnissen und Erfahrungen auf den Gebieten der Kohlechemie und der Strukturanalytik von Kohlen zu integrieren. Aufgabenstellung der chemischen Arbeitsgruppe war und ist es, Erkenntnisse ueber die chemische Natur der Biokonversionsprodukte und die chemischen Ablaeufe der mikrobiellen Kohlekonversion bereitstellen. Die Aufgabenstellung umfasst die Aufklaerung der strukturellen Veraenderung der Einsatzkohle sowie ihrer Komponenten Huminsaeuren und makromolekulare Matrix durch die Einwirkung kohleabbauender Mikroorganismen. (orig.)

  13. Development of coatings for protection of coal during transport and storage. Final report, December 15, 1977--September 15, 1978

    Energy Technology Data Exchange (ETDEWEB)

    Kromrey, R V; Scheffee, R S; DePasquale, J A; Valentine, R S

    1978-11-01

    The use of coatings to prevent dust emissions and leachates from coal stockpiles was studied under sponsorship of the Department of Energy, Division of Environmental Control Technology. The coatings considered included compositions formed of a filler such as pulverized coal and a binder consisting of a combination of waxes and plastics. Various latex emulsions, both with and without fillers, were also evaluated. The purpose of coal coatings is to seal the surface of the stockpile. This prevents water penetration into the coal. By sealing the surface of the pile, dust losses are prevented and leachate formation is minimized. Air circulation through the stockpile is also greatly reduced. This yields the added benefits of reduced oxidation of the coal and prevention of spontaneous ignition. Cold weather handling characteristics of the coal are also improved. Physical properties of the coatings were measured. Included were such characteristics as resistance to water penetration and degradation as a result of thermal cycling. Application techniques were also evaluated. Both hot-applied and cold-applied coatings were considered. Protective coatings appear to be an attractive means of prevention of fugitive emissions from coal stockpiles. The economic benefits from reduced oxidation and improved handling more than off-set the cost of application. Use of coatings on unit trains or barges may also be attractive.

  14. Coal-fueled diesel system for stationary power applications -- Technology development. Final report, March 1988--June 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-01

    Morgantown Energy Technology Center, Cooper-Bessemer and Arthur D. Little have developed the technology to enable coal-water slurry to be utilized in large-bore, medium-speed diesel engines. The target application is modular power generation in the 10 to 100 MW size, with each plant using between two and eight engines. Such systems are expected to be economically attractive in the non-utility generation market after 2000, when oil and natural gas prices are expected to escalate rapidly compared to the price of coal. During this development program, over 1,000 hours of prototype engine operation have been achieved on coal-water slurry (CWS), including over 100 hours operation of a six-cylinder, 1.8 MW engine with an integrated emissions control system. Arthur D. Little, Inc., managed the coal-fueled diesel development, with Cooper-Bessemer as the principal subcontractor responsible for the engine design and testing. Several key technical advances which enable the viability of the coal-fueled diesel engine were made under this program. Principal among them are the development and demonstration of (1) durable injection nozzles; (2) an integrated emissions control system; ad (3) low-cost clean coal slurry formulations optimized for the engine. Significant advances in all subsystem designs were made to develop the full-scale Cooper-Bessemer coal engine components in preparation for a 100-hour proof-of-concept test of an integrated system, including emissions controls. The Clean Coal Diesel power plant of the future will provide a cost-competitive, low-emissions, modular, coal-based power generation option to the non-utility generation, small utility, independent power producer, and cogeneration markets. Combined cycle efficiencies will be approximately 48% (lower heating value basis) and installed cost will be approximately $1,300/kW (1992 dollars).

  15. Competitive adsorption of Pb2+ and Zn2+ ions from aqueous solutions by modified coal fly ash

    Science.gov (United States)

    Astuti, Widi; Martiani, Wulan; Any Ismawati Khair, N.

    2017-03-01

    Coal fly ash (CFA), which is a solid waste generated in large amounts worldwide, is mainly composed of some oxides having high crystallinity, including quartz (SiO2) and mullite (3Al2O3 2SiO2), and unburned carbon as a mesopore material that enables it to act as a dual site adsorbent. To decrease the crystallinity, CFA was modified by sodium hydroxide treatment. The modified fly ash (MFA) contains lower amount of Si and Al and has a higher specific surface area than the untreated fly ash (CFA). The objective of this study is to investigate the competitive adsorption of Pb2+ and Zn2+ from aqueous solutions by CFA and MFA. The effect of pH, contact time and initial concentration was investigated. Effective pH for Pb2+ and Zn2+ removal was 4. A greater percentage of Pb2+ and Zn2+ was removed with a decrease in the initial concentration of Pb2+ and Zn2+. Quasi-equilibrium reached in 240 min.

  16. Development of biological coal gasification (MicGAS process). Final report, May 1, 1990--May 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-31

    ARCTECH has developed a novel process (MicGAS) for direct, anaerobic biomethanation of coals. Biomethanation potential of coals of different ranks (Anthracite, bitumious, sub-bitumious, and lignites of different types), by various microbial consortia, was investigated. Studies on biogasification of Texas Lignite (TxL) were conducted with a proprietary microbial consortium, Mic-1, isolated from hind guts of soil eating termites (Zootermopsis and Nasutitermes sp.) and further improved at ARCTECH. Various microbial populations of the Mic-1 consortium carry out the multi-step MicGAS Process. First, the primary coal degraders, or hydrolytic microbes, degrade the coal to high molecular weight (MW) compounds. Then acedogens ferment the high MW compounds to low MW volatile fatty acids. The volatile fatty acids are converted to acetate by acetogens, and the methanogens complete the biomethanation by converting acetate and CO{sub 2} to methane.

  17. Subcontracted R and D final report: analysis of samples obtained from GKT gasification test of Kentucky coal. Nonproprietary version

    Energy Technology Data Exchange (ETDEWEB)

    Raman, S.V.

    1983-09-01

    A laboratory test program was performed to obtain detailed compositional data on the Gesellshaft fuer Kohle-Technologie (GKT) gasifier feed and effluent streams. GKT performed pilot gasification tests with Kentucky No. 9 coal and collected various samples which were analyzed by GKT and the Radian Corporation, Austin, Texas. The coal chosen had good liquefaction characteristics and a high gasification reactivity. No organic priority pollutants or PAH compounds were detected in the wash water, and solid waste leachates were within RCRA metals limits.

  18. TVA coal-gasification commercial demonstration plant project. Volume 5. Plant based on Koppers-Totzek gasifier. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1980-11-01

    This volume presents a technical description of a coal gasification plant, based on Koppers-Totzek gasifiers, producing a medium Btu fuel gas product. Foster Wheeler carried out a conceptual design and cost estimate of a nominal 20,000 TPSD plant based on TVA design criteria and information supplied by Krupp-Koppers concerning the Koppers-Totzek coal gasification process. Technical description of the design is given in this volume.

  19. Evaluation of the effect of coal cleaning of fugitive elements. Part II. Analytical methods. Final report, Phase II

    Energy Technology Data Exchange (ETDEWEB)

    Bosshart, R.E.; Price, A.A.; Ford, C.T.

    1980-03-01

    This report contains the analytical and test methods which were used routinely at Bituminous Coal Research, Inc. during the project. The procedures contained herein should aid coal industry laboratories and others, including commercial laboratories, who might be required to determine trace elements in coal. Some of the procedures have been presented in previous BCR reports; however, this report includes additional procedures which are described in greater detail. Also presented are many as the more basic coal methods which have been in use at BCR for many years, or which have been adapted or refined from other standard reference sources for coal and water. The basis for choosing specific analytical procedures for trace elements in coal is somewhat complex. At BCR, atomic absorption was selected as the basic method in the development of these procedures. The choice was based on sensitivity, selectivity, accuracy, precision, practicability, and economy. Whenever possible, the methods developed had to be both adequate and amenable for use by coal industry laboratories by virtue of relative simplicity and cost. This is not to imply that the methods described are simple or inexpensive; however, atomic abosrption techniques do meet these criteria in relation to more complex and costly methods such as neutron activation, mass spectrometry, and x-ray fluorescence, some of which require highly specialized personnel as well as access to sophisticated nuclear and computational facilities. Many of the analytical procedures for trace elements in coal have been developed or adapted specifically for the BCR studies. Their presentation is the principal purpose of this report.

  20. Clean Coal Technology III: 10 MW Demonstration of Gas Suspension Absorption final project performance and economics report

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, F.E.

    1995-08-01

    The 10 MW Demonstration of the Gas Suspension Absorption (GSA) program is a government and industry co-funded technology development. The objective of the project is to demonstrate the performance of the GSA system in treating a 10 MW slipstream of flue gas resulting from the combustion of a high sulfur coal. This project involves design, fabrication, construction and testing of the GSA system. The Project Performance and Economics Report provides the nonproprietary information for the ``10 MW Demonstration of the Gas Suspension Absorption (GSA) Project`` installed at Tennessee Valley Authority`s (TVA) Shawnee Power Station, Center for Emissions Research (CER) at Paducah, Kentucky. The program demonstrated that the GSA flue-gas-desulfurization (FGD) technology is capable of achieving high SO{sub 2} removal efficiencies (greater than 90%), while maintaining particulate emissions below the New Source Performance Standards (NSPS), without any negative environmental impact (section 6). A 28-day test demonstrated the reliability and operability of the GSA system during continuous operation. The test results and detailed discussions of the test data can be obtained from TVA`s Final Report (Appendix A). The Air Toxics Report (Appendix B), prepared by Energy and Environmental Research Corporation (EERC) characterizes air toxic emissions of selected hazardous air pollutants (HAP) from the GSA process. The results of this testing show that the GSA system can substantially reduce the emission of these HAP. With its lower capital costs and maintenance costs (section 7), as compared to conventional semi-dry scrubbers, the GSA technology commands a high potential for further commercialization in the United States. For detailed information refer to The Economic Evaluation Report (Appendix C) prepared by Raytheon Engineers and Constructors.

  1. Energy material transport, now through 2000, system characteristics and potential problems. Task 2 final report: coal transportation.

    Energy Technology Data Exchange (ETDEWEB)

    DeSteese, J.G.; Bamberger, J.A.; Franklin, A.L.; Hendrickson, P.L.; Lippek, H.E.; Loscutoff, W.V.; Wilson, C.L.

    1978-06-01

    This report contains a summary characterization of the existing domestic coal transportation system and an assessment of some potential problems which may impact coal transportation in the United States during the balance of the century. A primary purpose of this task is to provide information and perspective that contributes to the evaluation of research and development needs and priorities in future programs. Specific concerns are identified which warrant additional programmatic effort to fill apparent gaps in the coverage of other relevant programs. Recommendations are made for new programs to address these concerns according to their apparent importance under conditions known or anticipated in early 1978. These recommendations are intended to encourage new research initiatives by the coal transportation industry, the Department of Energy (DOE) and other cognizant agencies. Concerns were identified by the analysis of problem issues associated with currently-projected growth scenarios for domestic coal consumption. The assessment of potential problem effects on the adequacy of future coal transportation assumes domestic coal production levels of approximately one billion tons in 1985 and two billion tons by the year 2000. The relative priorities of potential problems were judged on the basis of their overall impact on the system and the immediacy of this potential impact.

  2. Consortium for coal log pipeline research and development. Final technical progress report, August 10, 1993--August 9, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Marrero, T.R.

    1996-10-01

    The main objective of this project was to conduct intensive research and development of the Coal Log Pipeline (CLP). Specifically, the R & D was to concentrate on previously neglected and insufficiently studied aspects of CLP which were deemed significant. With improvements in these areas, CLP could be implemented for commercial use within five years. CLP technology is capable of transporting coal logs for long distances. The many potential advantages of CLP over truck and railroad transportation include: lower freight costs, less energy consumption, less air pollution, decreased environmental problems, increased safety, and improved reliability. Previous studies have shown that CLP is advantageous over slurry pipeline technology. First, CLP uses one-third the water required by a coal slurry pipeline. Second, CLP provides easier coal dewatering. Third, the CLP conveying capacity of coal is twice as much as a slurry transport line of equal diameter. In many situations, the cost for transporting each ton of coal is expected to be less expensive by CLP as compared to other competing modes of transportation such as: truck, unit train and slurry pipeline.

  3. Removal of trivalent chromium from aqueous solution by zeolite synthesized from coal fly ash.

    Science.gov (United States)

    Wu, Deyi; Sui, Yanming; He, Shengbing; Wang, Xinze; Li, Chunjie; Kong, Hainan

    2008-07-15

    The capability of 14 zeolites synthesized from different fly ashes (ZFAs) to sequestrate Cr(III) from aqueous solutions was investigated in a batch mode. The influence of pH on the sorption of Cr(III) was examined. ZFAs had a much greater ability than fly ash to remove Cr(III), due to the high cation exchange capacity (CEC) and the high acid neutralizing capacity (ANC) of ZFAs. The mechanism of Cr(III) removal by ZFAs involved ion exchange and precipitation. A high-calcium content in both the fly ashes and ZFAs resulted in a high ANC value and, as a result, a high immobilization capacity for Cr(III). The pH strongly influenced Cr(III) removal by ZFAs. Inside the solubility range, removal of chromium increased with increasing pH. Hydroxysodalite made from a high-calcium fly ash had a higher sorptive capacity for Cr(III) than the NaP1 zeolite from medium- and low-calcium fly ashes. On the other hand, at pH values above the solubility range, the efficiency of chromium removal by the ZFAs approached 100% due to the precipitation of Cr(OH)3 on the sorbent surfaces. It is concluded that ZFAs and high-calcium fly ashes may be promising materials for the purification of Cr(III) from water/wastewater.

  4. Method of extracting coal from a coal refuse pile

    Science.gov (United States)

    Yavorsky, Paul M.

    1991-01-01

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  5. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction. Final technical report, Volume 2 - hydrogenative and hydrothermal pretreatments and spectroscopic characterization using pyrolysis-GC-MS, CPMAS {sup 13}C NMR and FT-IR

    Energy Technology Data Exchange (ETDEWEB)

    Chunshan Song; Hatcher, P.G.; Saini, A.K.; Wenzel, K.A.

    1998-01-01

    It has been indicated by DOE COLIRN panel that low-temperature catalytic pretreatment is a promising approach to the development of an improved liquefaction process. This work is a fundamental study on effects of pretreatments on coal structure and reactivity in liquefaction. The main objectives of this project are to study the coal structural changes induced by low-temperature catalytic and thermal pretreatments by using spectroscopic techniques; and to clarify the pretreatment-induced changes in reactivity or convertibility of coals. As the second volume of the final report, here we summarize our work on spectroscopic characterization of four raw coals including two subbituminous coals and two bituminous coals, tetrahydrofuran (THF)-extracted but unreacted coals, the coals (THF-insoluble parts) that have been thermally pretreated. in the absence of any solvents and in the presence of either a hydrogen-donor solvent or a non-donor solvent, and the coals (THF-insoluble parts) that have been catalytically pretreated in the presence of a dispersed Mo sulfide catalyst in the absence of any solvents and in the presence of either a hydrogen-donor solvent or a non-donor solvent.

  6. Phase-equilibria for design of coal-gasification processes: dew points of hot gases containing condensible tars. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Prausnitz, J.M.

    1980-05-01

    This research is concerned with the fundamental physical chemistry and thermodynamics of condensation of tars (dew points) from the vapor phase at advanced temperatures and pressures. Fundamental quantitative understanding of dew points is important for rational design of heat exchangers to recover sensible heat from hot, tar-containing gases that are produced in coal gasification. This report includes essentially six contributions toward establishing the desired understanding: (1) Characterization of Coal Tars for Dew-Point Calculations; (2) Fugacity Coefficients for Dew-Point Calculations in Coal-Gasification Process Design; (3) Vapor Pressures of High-Molecular-Weight Hydrocarbons; (4) Estimation of Vapor Pressures of High-Boiling Fractions in Liquefied Fossil Fuels Containing Heteroatoms Nitrogen or Sulfur; and (5) Vapor Pressures of Heavy Liquid Hydrocarbons by a Group-Contribution Method.

  7. Energy conservation in coal conversion. Final report, September 15, 1977--September 1, 1978. Selected case studies and conservation methodologies

    Energy Technology Data Exchange (ETDEWEB)

    Purcupile, J.C.

    1978-09-01

    The purpose of this study is to apply the methodologies developed in the Energy Conservation in Coal Conversion August, 1977 Progress Report - Contract No. EY77S024196 - to an energy efficient, near-term coal conversion process design, and to develop additional, general techniques for studying energy conservation and utilization in coal conversion processes. The process selected for study was the Ralph M. Parsons Company of Pasadena, California ''Oil/Gas Complex, Conceptual Design/Economic Analysis'' as described in R and D Report No. 114 - Interim Report No. 4, published March, 1977, ERDA Contract No. E(49-18)-1975. Thirteen papers representing possible alternative methods of energy conservation or waste heat utilization have been entered individually into EDB and ERA. (LTN)

  8. Weathering effects on the structure and reactivity of US coals: Final report, July 15, 1984-July 14, 1987. [Many data

    Energy Technology Data Exchange (ETDEWEB)

    Meuzelaar, H.L.C.; Hill, G.R.; Yun, Yongseung; Jakab, E.; Windig, W.; Urban, D.; Yon, Kyung Yol; Oestreich, J.; East, J.

    1987-01-01

    This report covers the work performed from July 1984 to July 1987 under the project entitled ''Weathering Effects on Structure and Reactivity of US Coals'' (grant number FG22-84PC70798). The main objectives of the study were to investigate the structural changes in coal during the weathering process as well as to develop a simple, reliable weathering index, which can monitor indirectly the weathering-induced changes in physical and chemical properties. Although there have been numerous publications on structure and reactivity of coal, most data reported in the literature thus far have been obtained on coal samples of uncertain weathering status and therefore need to be interpreted with great caution. Weathering has a profound effect on many important coal properties such as heating value, caking characteristics, acidity, flotability and reactivity in liquefaction, combustion and gasification processes. The objective of developing a weathering index is to predict these coal property changes due to weathering without resorting to real-time measurements or pilot plant runs. This report is comprised of four main chapters: I. Structural Changes due to Weathering; II. Material Balance in Weathering Process; III. Development of a Reliable Weathering Index; and IV. Proposed Weathering Mechanisms. A battery of sophisticated analytical tools and techniques was employed during this study. Pyrolysis mass spectrometry in time-integrated, as well as in time-resolved modes with computer-aided data analysis techniques (such as factor and discriminant analysis), gas chromatography, thermogravimetry/mass spectrometry and solvent extraction were used for determining the role of oxygen during the weathering process. Pyrolysis mass spectrometry, Free Swelling Index and a novel slurry pH technique were employed as weathering indicators. 170 refs.

  9. Efficient ultrasonic grinding: a new technology for micron-sized coal. Final report, September 15, 1979-December 14, 1980

    Energy Technology Data Exchange (ETDEWEB)

    Tarpley, W.B. Jr.; Howard, P.L.; Moulder, G.R.

    1981-01-01

    To burn coal most efficiently and cleanly, much smaller particle sizes are needed than can now be ground economically. This project was performed to demonstrate the technical feasibility of using ultrasonics to enhance grinding below the standard plant grind of 75 microns, and to extrapolate from this laboratory work the ultrasonic energy requirements for production use. Successively improved laboratory arrays demonstrated a repeatable production of particulates from 2000-micron coal to the desired size ranges (approximately 35% below 7 microns, 95% below 44 microns) with selective liberation of ash and pyrite inclusions to facilitate removal, with equipment translatable to production use, and the possibility of only 37 kwh/ton energy input requirement.

  10. Re-Use of Clean Coal Technology By-Products in the Construction of Low Permeability Liners. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wolfe, William E. [The Ohio State Univ., Columbus, OH (United States); Butalia, Tarunjit S. [The Ohio State Univ., Columbus, OH (United States); Walker, Harold [The Ohio State Univ., Columbus, OH (United States); Mitsch, William [The Ohio State Univ., Columbus, OH (United States)

    2005-07-15

    This final project report presents the results of a research program conducted at The Ohio State University from January 3, 2000 to June 30, 2005 to investigate the long-term use of stabilized flue gas desulfurization (FGD) materials in the construction of low permeability liners for ponds and wetlands. The objective of the research program was to establish long-term field-verified time-dependent relationships for the performance of liners constructed from stabilized FGD byproducts generated in Ohio. The project objective was accomplished with a coordinated program of testing and analyzing small-scale laboratory specimens under controlled conditions, mediumscale wetland experiments, and monitoring of a full-scale FGD-lined pond facility. Although the specific uses directly addressed by this report include liners for surface impoundments, the results presented in this study are also useful in other applications especially in the design of daily covers and liners for landfills, seepage cutoff walls and trenches, and for nutrient retention and pollution mitigation wetlands. The small-scale laboratory tests and monitoring of the full-scale FGD lined facility (capacity of one million gallons) shows that stabilized FGD materials can be used as low permeability liners in the construction of water and manure holding ponds. Actual long-term permeability coefficients in the range of 10-7 cm/sec (3 x 10-9 ft/sec) can be obtained in the field by compacting lime and fly ash enriched stabilized FGD materials. Leachate from the FGD material meets Ohio’s non-toxic criteria for coal combustion by-products, and for most potential contaminants the national primary and secondary drinking water standards are also met. The low permeability non-toxic FGD material investigated in this study poses very minimal risks, if any, for groundwater contamination. The FGD wetland experiments indicated no significant differences in phosphorus retention between the clay and FGD

  11. Estimates of water and solute release from a coal waste rock dump in the Elk Valley, British Columbia, Canada.

    Science.gov (United States)

    Villeneuve, S A; Barbour, S L; Hendry, M J; Carey, S K

    2017-12-01

    Long term (1999 to 2014) flow and water quality data from a rock drain located at the base of a coal waste rock dump constructed in the Elk Valley, British Columbia was used to characterize the release of three solutes (NO 3 - , Cl - and SO 4 2- ) from the dump and obtain whole dump estimates of net percolation (NP). The concentrations of dump derived solutes in the rock drain water were diluted by snowmelt waters from the adjacent natural watershed during the spring freshet and reached a maximum concentration during the winter baseflow period. Historical peak baseflow concentrations of conservative ions (NO 3 - and Cl - ) increased until 2006/07 after which they decreased. This decrease was attributed to completion of the flushing of the first pore volume of water stored within the dump. The baseflow SO 4 2- concentrations increased proportionally with NO 3 - and Cl - to 2007, but then continued to slowly increase as NO 3 - and Cl - concentrations decreased. This was attributed to ongoing production of SO 4 2- due to oxidation of sulfide minerals within the dump. Based on partitioning of the annual volume of water discharged from the rock drain to waste rock effluent (NP) and water entering the rock drain laterally from the natural watershed, the mean NP values were estimated to be 446±50mm/a (area normalized net percolation/year) for the dump and 172±71mm/a for the natural watershed. The difference was attributed to greater rates of recharge in the dump from summer precipitation compared to the natural watershed where rainfall interception and enhanced evapotranspiration will increase water losses. These estimates included water moving through subsurface pathways. However, given the limitations in quantifying these flows the estimated NP rates for both the natural watershed and the waste rock dump are considered to be low, and could be much higher (e.g. ~450mm/a and ~800mm/a). Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Research and Education of CO{sub 2} Separation from Coal Combustion Flue Gases with Regenerable Magnesium Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Joo-Youp

    2013-09-30

    A novel method using environment-friendly chemical magnesium hydroxide (Mg(OH){sub 2}) solution to capture carbon dioxide from coal-fired power plants flue gas has been studied under this project in the post-combustion control area. The project utilizes the chemistry underlying the CO{sub 2}-Mg(OH){sub 2} system and proven and well-studied mass transfer devices for high levels of CO{sub 2} removal. The major goals of this research were to select and design an appropriate absorber which can absorb greater than 90% CO{sub 2} gas with low energy costs, and to find and optimize the operating conditions for the regeneration step. During the project period, we studied the physical and chemical characteristics of the scrubbing agent, the reaction taking place in the system, development and evaluation of CO{sub 2} gas absorber, desorption mechanism, and operation and optimization of continuous operation. Both batch and continuous operations were performed to examine the effects of various parameters including liquid-to-gas ratio, residence time, lean solvent concentration, pressure drop, bed height, CO{sub 2} partial pressure, bubble size, pH, and temperature on the absorption. The dissolution of Mg(OH){sub 2} particles, formation of magnesium carbonate (MgCO{sub 3}), and vapor-liquid-solid equilibrium (VLSE) of the system were also studied. The dissolution of Mg(OH){sub 2} particles and the steady release of magnesium ions into the solution was a crucial step to maintain a level of alkalinity in the CO{sub 2} absorption process. The dissolution process was modeled using a shrinking core model, and the dissolution reaction between proton ions and Mg(OH){sub 2} particles was found to be a rate-controlling step. The intrinsic surface reaction kinetics was found to be a strong function of temperature, and its kinetic expression was obtained. The kinetics of MgCO{sub 3} formation was also studied in terms of different pH values and temperatures, and was enhanced under high p

  13. A novel LCD (coal tar) solution for psoriasis does not discolor naturally light or color-processed hair in an exaggerated exposure test model.

    Science.gov (United States)

    Johnson, Colleen; Edison, Brenda; Brouda, Irina; Green, Barbara

    2009-09-01

    Scalp psoriasis is reported to occur in 50-80% of psoriasis sufferers. Treatment of scalp psoriasis requires special consideration of product esthetics and staining potential due to the presence of hair. To evaluate the potential of a new, marketed liquor carbonis distillate (LCD; coal tar) solution to discolor naturally light or color-processed hair under exaggerated exposure conditions. Samples of naturally light and color-processed hair from a single donor were exposed to LCD solution repeatedly over 14 days and via submergence for 24 h. Color of LCD-treated hair samples was compared with untreated control hair samples. LCD solution did not discolor naturally light or color-processed hair following repeated exposures and 24 h submergence. The marketed LCD solution does not appear to discolor naturally light or color-processed hair.

  14. Demonstration and testing of coal/oil mixture as a fuel for a slot furnace. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Bjerklie, J.W.; Penty, R.A.

    1979-07-01

    An evaluation was made of the effects of heating with a coal/oil mixture (COM) on forgings and furnace construction materials. The forgings produced with COM in a slot forge furnace were subjected to an extensive series of metallurgical tests to determine what effect, if any, use of COM as a fuel had upon the parts forged. Fifty wt % bituminous coal crushed to 80% minus 325 mesh was mixed with 50 wt % number 6 fuel oil. Emulsifiers were added to keep the coal in suspension. It was demonstrated that the 50 wt % coal/oil mixture can be successfully used to produce steel forgings. Burning COM presented no problems in respect to the ease of heating the steel or in respect to the metallurgy of the forgings. The main findings of the investigation were that: COM can be used to forge steel successfully; use of COM requires that ceramic materials of furnace construction be selected with care; and the modifications required to burn COM are minor. There were no significant differences between steel forgings produced with number 2 fuel oil and steel forgings produced with COM.

  15. Revised users manual, Pulverized Coal Gasification or Combustion: 2-dimensional (87-PCGC-2): Final report, Volume 2. [87-PCGC-2

    Energy Technology Data Exchange (ETDEWEB)

    Smith, P.J.; Smoot, L.D.; Brewster, B.S.

    1987-12-01

    A two-dimensional, steady-state model for describing a variety of reactive and non-reactive flows, including pulverized coal combustion and gasification, is presented. Recent code revisions and additions are described. The model, referred to as 87-PCGC-2, is applicable to cylindrical axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using either a flux method or discrete ordinates method. The particle phase is modeled in a Lagrangian framework, such that mean paths of particle groups are followed. Several multi-step coal devolatilization schemes are included along with a heterogeneous reaction scheme that allows for both diffusion and chemical reaction. Major gas-phase reactions are modeled assuming local instantaneous equilibrium, and thus the reaction rates are limited by the turbulent rate mixing. A NO/sub x/ finite rate chemistry submodel is included which integrates chemical kinetics and the statistics of the turbulence. The gas phase is described by elliptic partial differential equations that are solved by an iterative line-by-line technique. Under-relaxation is used to achieve numerical stability. The generalized nature of the model allows for calculation of isothermal fluid mechanicsgaseous combustion, droplet combustion, particulate combustion and various mixtures of the above, including combustion of coal-water and coal-oil slurries. Both combustion and gasification environments are permissible. User information and theory are presented, along with sample problems. 106 refs.

  16. Measurement and modeling of advanced coal conversion processes, Volume I, Part 2. Final report, September 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

    1995-09-01

    This report describes work pertaining to the development of models for coal gasification and combustion processes. This volume, volume 1, part 2, contains research progress in the areas of large particle oxidation at high temperatures, large particle, thick-bed submodels, sulfur oxide/nitrogen oxides submodels, and comprehensive model development and evaluation.

  17. Development and testing of a high efficiency advanced coal combustor: Phase 3 industrial boiler retrofit. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Patel, R.L.; Thornock, D.E.; Miller, B.G.; Scaroni, A.W.; McGowan, J.G.

    1998-03-01

    Economics and/or political intervention may one day dictate the conversion from oil or natural gas to coal in boilers that were originally designed to burn oil or gas. In recognition of this future possibility the US Department of Energy, Federal Energy Technical Center (DOE-FETC) supported a program led by ABB Power Plant Laboratories with support from the Energy and Fuels Research Center of Penn State University with the goal of demonstrating the technical and economic feasibility of retrofitting a gas/oil designed boiler to burn micronized coal. In support of the overall goal the following specific objectives were targeted: develop a coal handling/preparation system that can meet the technical and operational requirements for retrofitting microfine coal on a boiler designed for burning oil or natural gas; maintain boiler thermal performance in accordance with specifications when burning oil or natural gas; maintain NOx emissions at or below 0.6 lb NO{sub 2} per million Btu; achieve combustion efficiencies of 98% or higher; and determine economic payback periods as a function of key variables.

  18. Adsorption of anionic dyes from aqueous solutions onto coal fly ash and zeolite synthesized from coal fly ash; Adsorcao de corantes anionicos de solucao aquoso em cinza leve de carvao e zeolita de cinza leve de carvao

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, Terezinha Elizabeth Mendes de

    2010-07-01

    Coal fly ash, a waste generated in coal-fired electric power plant, was used to synthesize zeolite by hydrothermal treatment with NaOH solution. The fly ash (CL-2) and this synthesized zeolite (ZM-2) that was characterized as hydroxy-sodalite were used as adsorbents for anionic dyes indigo carmine (IC), and reactive orange 16 (RO16) from aqueous solutions. Effects of contact time, initial dye concentration, pH, adsorbent mass, and temperature were evaluated in the adsorption processes. The kinetics studies indicated that the adsorption followed the pseudo-second order kinetics and that surface adsorption and intraparticle diffusion were involved in the adsorption mechanism. The thermodynamics parameters demonstrated that the adsorption was spontaneous for all adsorption processes. The enthalpy data confirmed the endothermic nature for all adsorption processes except for IC/ZM-2 system which was exothermic. The entropy data showed an increased disorder at the solid/solution interface during the adsorption for all systems except for IC/ZM-2 whose negative entropy value indicated a decreased disorder at the interface. The adsorption isotherms were closely fitted to the Langmuir linear equation. The maximum adsorption capacities were 1.48 mg/g for the IC/CL-2 system; 1.13 mg/g for IC/ZM-2; 0.96 mg/g for RO16/CL-2, and 1.14 mg/g for RO16/ZM-2 at room temperature. The desorption study carried out with water, with acid aqueous solutions, and with an alkali aqueous solution showed to be inefficient both for recovering the dyes and regenerating the adsorbents. (author)

  19. Coal; Le charbon

    Energy Technology Data Exchange (ETDEWEB)

    Teissie, J.; Bourgogne, D. de; Bautin, F. [TotalFinaElf, La Defense, 92 - Courbevoie (France)

    2001-12-15

    Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

  20. Unioned layer of coal resource calculation in the Danforth Hills coal field, Colorado (dan*fing)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — Final unioned polygon coverages and shapefiles used to calculate coal resources of the A through G coal zones, Danforth Hills coal field, northwestern Colorado....

  1. Analytical and Numerical Solutions of Generalized Fokker-Planck Equations - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Prinja, Anil K.

    2000-12-31

    The overall goal of this project was to develop advanced theoretical and numerical techniques to quantitatively describe the spreading of a collimated beam of charged particles in space, in angle, and in energy, as a result of small deflection, small energy transfer Coulomb collisions with the target nuclei and electrons. Such beams arise in several applications of great interest in nuclear engineering, and include electron and ion radiotherapy, ion beam modification of materials, accelerator transmutation of waste, and accelerator production of tritium, to name some important candidates. These applications present unique and difficult modeling challenges, but from the outset are amenable to the language of ''transport theory'', which is very familiar to nuclear engineers and considerably less-so to physicists and material scientists. Thus, our approach has been to adopt a fundamental description based on transport equations, but the forward peakedness associated with charged particle interactions precludes a direct application of solution methods developed for neutral particle transport. Unique problem formulations and solution techniques are necessary to describe the transport and interaction of charged particles. In particular, we have developed the Generalized Fokker-Planck (GFP) approach to describe the angular and radial spreading of a collimated beam and a renormalized transport model to describe the energy-loss straggling of an initially monoenergetic distribution. Both analytic and numerical solutions have been investigated and in particular novel finite element numerical methods have been developed. In the first phase of the project, asymptotic methods were used to develop closed form solutions to the GFP equation for different orders of expansion, and was described in a previous progress report. In this final report we present a detailed description of (i) a novel energy straggling model based on a Fokker-Planck approximation but

  2. Microbial recovery of metals from spent coal liquefaction catalysts. Final and quarterly report, July 1994--September 1994

    Energy Technology Data Exchange (ETDEWEB)

    Sandbeck, K.A.; Cleveland, D.

    1995-08-01

    Research is reported on the recovery of molybdenum and nickel from spent coal liquefaction catalysts. Mo release from spent coal liquefaction catalysts has been shown to be dependent upon many parameters, but release is dominated by microbial growth. The microbial Mo release is a rapid process requiring less than one week for 90% of the releaseable Mo to be solubilized from whole washed (THF) catalyst. It could be expected that the rates would be even greater with crushed catalyst. Efforts were centered on optimizing the parameters that stimulate microbial growth and action and further efforts centered on catalyst pre-treatment prior to microbial bio-leaching. Recent experiments suggest that hydrogen peroxide promises to be an effective pre-treatment wash. Hydrogen peroxide was also found to be an effective and economical agent for metals solubilization per se and could promote solubilization without subjecting the catalyst to microbial growth.

  3. Continuous thermodynamics and group contribution methods for coal liquids: Final report, October 1, 1986--October 1, 1989

    Energy Technology Data Exchange (ETDEWEB)

    Allen, D. T.; Behmanesh, N.; Vajdi, L. E.

    1989-01-01

    Structural profiles of narrow-boiling range fractions from three coal liquefaction processes were determined by identifying the major functional groups in the distillates and estimating their concentrations. The structural profiles were based on an extensive set of analytical data including results from elemental analysis, proton nuclear magnetic resonance, mass spectrometry, infrared spectroscopy and liquid chromatography. The functional group distributions were then interfaced with group contribution methods for property estimation. Heat capacities, critical constants, activity coefficients, hydrogen solubilities and vapor pressures were estimated for the narrow boiling fractions. The predictions have been compared to the predictions of more conventional property estimation methods and to experimental data. In addition, sensitivity analyses have been performed to determine which structural features in the coal derived liquids are most important in estimating the values of thermodynamic properties. 43 refs., 16 figs., 59 tabs.

  4. Novel approach to coal gasification using chemically incorporated catalysts (Phase II). Final report, May 1978-June 1981

    Energy Technology Data Exchange (ETDEWEB)

    Feldmann, H.F.; Conkle, H.N.; Appelbaum, H.R.; Chauhan, S.P.

    1981-01-01

    Since 1974, Battelle has been developing a catalytic treatment process that would allow more economic, efficient and reliable utilization of the vast deposits of eastern coals in gasification systems. In order to keep the process simple and economic, a disposable catalyst lime (CaO), was employed. It was found that the effectiveness of low concentrations of CaO was greatly increased by thorough incorporation into the coal. As a result of these efforts, a catalytic treatment system has been developed that promises to allow simplifications and improvements in existing commercial gasification processes as well as advanced gasification systems. One gasification system that appears exceptionally attractive utilizing the treatment system is direct fluid-bed hydrogasification or hydropyrolysis. A simple pressurized fluid-bed steam/oxygen gasification system is also an attractive option which could be commercialized quickly. Data generated under this program demonstrated the technical and economic advantages of these approaches.

  5. A novel concept for high conversion of coal to liquids. Final report, 1 September 1988--31 August 1992

    Energy Technology Data Exchange (ETDEWEB)

    Wiser, W.H.; Shabtai, J.

    1994-04-01

    A batch microreactor was designed and fabricated as a means of investigating maximum yields of liquids obtainable in very short reaction times of the order of a few seconds, and the maximum ratios of liquids/hydrocarbon (HC) gases obtainable under those conditions. A Wyodak sub-bituminous coal, crushed and sieved to {minus}200 mesh particle size, was used in the experiments, with a temperature of 500{degrees}C and a pressure of 1500 psi. The fine coal particles were fed dry to the reactor and heated to reaction temperature in times of one to two seconds. At a time of 3 seconds at reaction temperature, in a single pass a liquid yield of 60% by weight of the coal was obtained, accompanied by a ratio of liquids/(HC) gases of 30/1. When the unreacted solids were recycled to the reactor, and the results combined with those of the first pass, a liquid yield of 82% by weight of the coal was achieved, accompanied by a ratio of liquids/HC gases of 30/1. This ratio represents only about 3 wt percent HC gases, much lower that is produced in current advanced technologies, and represents a large saving in hydrogen consumption. A simulated distillation technique was applied to the liquids. The liquid product contained 86% by weight (of the liquids) total distillables (boiling point below 538{degrees}C), including 70% by weight of low-boiling fractions in the gasoline, kerosene and gas oil range (boiling point up to 325{degrees}C). The liquid product exhibited a H/C ratio of 1.5, which is considerably higher than observed in current advanced technologies for the primary liquids. Several catalysts were investigated. Iron catalysts, specifically ferric chloride hexahydrate and ferric sulfate pentahydrate, each produced these high conversions and high ratios of liquids/HC gases.

  6. Final report on CCQM-K87: Mono-elemental calibration solutions

    Science.gov (United States)

    Rienitz, Olaf; Schiel, Detlef; Görlitz, Volker; Jährling, Reinhard; Vogl, Jochen; Velina Lara-Manzano, Judith; Zon, Agnieszka; Fung, Wai-hong; Buzoianu, Mirella; Caciano de Sena, Rodrigo; dos Reis, Lindomar Augusto; Valiente, Liliana; Yim, Yong-Hyeon; Hill, Sarah; Champion, Rachel; Fisicaro, Paola; Bing, Wu; Turk, Gregory C.; Winchester, Michael R.; Saxby, David; Merrick, Jeffrey; Hioki, Akiharu; Miura, Tsutomu; Suzuki, Toshihiro; Linsky, Maré; Barzev, Alex; Máriássy, Michal; Cankur, Oktay; Ari, Betül; Tunç, Murat; Konopelko, L. A.; Kustikov, Yu A.; Bezruchko, Marina

    2012-01-01

    The aim of this comparison was to demonstrate the capability of national metrology institutes to measure elemental mass fractions at a level of w(E) ≈ 1 g/kg as found in almost all mono-elemental calibration solutions. These calibration solutions represent an important link in traceability systems in inorganic analysis. Virtually all traceable routine measurements are linked to the SI through these calibration solutions. Every participant was provided with three solutions of each of the three selected elements chromium, cobalt and lead. This comparison was a joint activity of the Inorganic Analysis Working Group (IAWG) and the Electrochemical Analysis Working Group (EAWG) of the CCQM and was piloted by the Physikalisch-Technische Bundesanstalt (PTB, Braunschweig, Germany) with the help of the Bundesanstalt für Materialforschung und -prüfung (BAM, Berlin, Germany), the Centro Nacional de Metrología (CENAM, Querétaro, Mexico) and the National Institute of Standards and Technology (NIST, Gaithersburg, USA). A small majority of participants applied inductively coupled plasma optical emission spectrometry (ICP OES) in combination with a variety of calibration strategies (one-point-calibration, bracketing, calibration curve, each with and without an internal standard). But also IDMS techniques were carried out on quadrupole, high resolution and multicollector ICP-MS machines as well as a TIMS machine. Several participants applied titrimetry. FAAS as well as ICP-MS combined with non-IDMS calibration strategies were used by at least one participant. The key comparison reference values (KCRV) were agreed upon during the IAWG/EAWG meeting in November 2011 held in Sydney as the added element content calculated from the gravimetric sample preparation. Accordingly the degrees of equivalence were calculated. Despite the large variety of methods applied no superior method could be identified. The relative deviation of the median of the participants' results from the

  7. Solid waste management of coal conversion residuals from a commercial-size facility: environmental engineering aspects. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Bern, J.; Neufeld, R. D.; Shapiro, M. A.

    1980-11-30

    Major residuals generated by the conversion process and its auxiliary operations include: (a) coal preparation wastes; (b) gasifier ash; (c) liquefaction solids-char; (d) tail gas or flue gas desulfurization sludge; (e) boiler flyash and bottom ash; (f) raw water treatment sludge, and; (g) biosludges from process wastewater treatment. Recovered sulfur may also require disposal management. Potential environmental and health impacts from each of the residues are described on the basis of characterization of the waste in the perspective of water quality degradation. Coal gasification and liquefaction systems are described in great detail with respect to their associated residuals. Management options are listed with the conclusion that land disposal of the major residual streams is the only viable choice. On-site versus off-site disposal is analyzed with the selection of on-site operations to reduce political, social and institutional pressures, and to optimize the costs of the system. Mechanisms for prevention of leachate generation are described, and various disposal site designs are outlined. It is concluded that co-disposal feasibility of some waste streams must be established in order to make the most preferred solid waste management system feasible. Capacity requirements for the disposal operation were calculated for a 50,000 bbl/day coal liquefaction plant or 250 million SCF/day gasification operation.

  8. Bioconversion of coal-derived synthesis gas to liquid fuels. Final technical report, September 1, 1990--August 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Jain, M.K.

    1991-12-31

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  9. Bioenergetic studies of coal sulfur oxidation by extremely thermophilic bacteria. Final report, September 15, 1992--August 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Kelly, R.M.; Han, C.J.

    1997-12-31

    Thermoacidophilic microorganisms have been considered for inorganic sulfur removal from coal because of expected improvements in rates of both biotic and abiotic sulfur oxidation reactions with increasing temperature. In this study, the bioenergetic response of the extremely thermoacidophilic archaeon, Metallosphaera sedula, to environmental changes have been examined in relation to its capacity to catalyze pyrite oxidation in coal. Given an appropriate bioenergetic challenge, the metabolic response was to utilize additional amounts of energy sources (i.e., pyrite) to survive. Of particular interest were the consequences of exposing the organism to various forms of stress (chemical, nutritional, thermal, pH) in the presence of coal pyrite. Several approaches to take advantage of stress response to accelerate pyrite oxidation by this organism were examined, including attempts to promote acquired thermal tolerance to extend its functional range, exposure to chemical uncouplers and decouplers, and manipulation of heterotrophic and chemolithotrophic tendencies to optimize biomass concentration and biocatalytic activity. Promising strategies were investigated in a continuous culture system. This study identified environmental conditions that promote better coupling of biotic and abiotic oxidation reactions to improve biosulfurization rates of thermoacidophilic microorganisms.

  10. Enthalpy and phase behavior of coal derived liquid mixtures: Final technical report. [Tetralin/m-cresol/quinoline

    Energy Technology Data Exchange (ETDEWEB)

    Yesavage, V.F.; Kidnay, A.J.; Flanigan, D.A.; Niesen, V.G.; DiGiacinto, S.S.; Joyce, T.P.; Yanaki, J.S.

    1988-04-15

    Measurements were made in a Freon 11, reference fluid, boil-off calorimeter, and an equilibrium flash vaporization apparatus, experimental systems which had already been developed. Previous studies had indicated that existing data and correlations developed for petroleum fluids are not applicable to coal derived liquids. This was due to the presence of significant concentrations of polar associating heteroatomics in the predominantly aromatic coal liquids. Thus, the ternary system was selected to include an aromatic, a basic nitrogen compound, and a cresol. Measurements were made over a wide range of temperature (200 to 700/degrees/) and pressure (20 to 1500 psia), for the three pure compounds, the three binary mixtures and selected compositions of the ternary. Both enthalpy and phase behavior measurements were made. This set of data will be useful as a standard for fitting and evaluating thermodynamic correlations and equations of state that are applicable to associating fluid mixtures, and thus to coal derived liquids. In addition efforts were and continue to be made at developing equation of state correlations which are applicable to these highly nonideal mixtures. 46 refs., 43 figs., 41 tabs.

  11. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

    1995-04-01

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  12. Use of pyrolysis gas from coal as reburn fuel. Final report; Einsatz von kohlestaemmigem Pyrolysegas als Reduktionsbrennstoff. Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Greul, U.; Magel, C.; Moersch, O.; Ruediger, H.; Storm, C.; Schnell, U.; Spliethoff, H.; Hein, K.R.G.

    1996-12-31

    The research project`s aim was to reduce nitrogen emissions from pulverized-coal furnaces by fuel staging with pyrolysis gas from coal. The test fuels were 6 German and Australian coals. The aim achieved has been the statement that the described method is an adequate means to attain to and remain below emission values of 200 mg/m{sup 3}. The method of fuel staging using coal-original gases was investigated with tests focussing the most important process parameters such as coal type, devolatilization ratio, temperature, residence time, and stoichiometry. The relevant features determined with an entrained flow reactor and with a fluidized-bed reactor were the impact of devolatilization temperatures on carbonized residue and pyrolysis products, the distribution of fuel nitrogen, and the quality of gas and tar, including the respective effects on NO{sub x} formation and reduction in staged combustion. The validation of the mathematical model was done with the experimentally obtained data. The criteria considered fundamental for achieving the NO{sub x} reduction level are temperature, air ratio, and residence time in the reduction zone of the furnace. The pyrolysis tests manifested the strong influence of the coal type and the devolatilization conditions on the composition of the gases and the attainable NO{sub x} reduction. The tars in the pyrolysis gases, with their nitrogen compounds, improve the reducing effect of available nitrogen oxides. By using pyrolysis gases from coal as reburning fuel, NO{sub x} emissions of less than 200 mg/m{sup 3} can be obtained at air ratios around 0.95. (orig./SR) [Deutsch] Das Forschungsprojekt verfolgte das Ziel mit 6 deutschen und australischen Kohlen die Stickoxidemissionen aus Kohlestaubfeuerungen durch Brennstoffstufung mit Pyrolysegas als Reduktionsbrennstoff zu verringern. Das erreichte Ziel war der Nachweis, dass mit dem beschriebenen Verfahren NO{sub x}-Emissionswerte von 200 mg/m{sup 3} erreicht und unterschritten werden

  13. Final Report - Montana State University - Microbial Activity and Precipitation at Solution-Solution Mixing Zones in Porous Media

    Energy Technology Data Exchange (ETDEWEB)

    Gerlach, Robin [Montana State University

    2014-10-31

    Background. The use of biological and chemical processes that degrade or immobilize contaminants in subsurface environments is a cornerstone of remediation technology. The enhancement of biological and chemical processes in situ, involves the transport, displacement, distribution and mixing of one or more reactive agents. Biological and chemical reactions all require diffusive transport of solutes to reaction sites at the molecular scale and accordingly, the success of processes at the meter-scale and larger is dictated by the success of phenomena that occur at the micron-scale. However, current understanding of scaling effects on the mixing and delivery of nutrients in biogeochemically dynamic porous media systems is limited, despite the limitations this imposes on the efficiency and effectiveness of the remediation challenges at hand. Objectives. We therefore proposed to experimentally characterize and computationally describe the growth, evolution, and distribution of microbial activity and mineral formation as well as changes in transport processes in porous media that receive two or more reactive amendments. The model system chosen for this project was based on a method for immobilizing 90Sr, which involves stimulating microbial urea hydrolysis with ensuing mineral precipitation (CaCO3), and co-precipitation of Sr. Studies at different laboratory scales were used to visualize and quantitatively describe the spatial relationships between amendment transport and consumption that stimulate the production of biomass and mineral phases that subsequently modify the permeability and heterogeneity of porous media. Biomass growth, activity, and mass deposition in mixing zones was investigated using two-dimensional micro-model flow cells as well as flow cells that could be analyzed using synchrotron-based x-ray tomography. Larger-scale flow-cell experiments were conducted where the spatial distribution of media properties, flow, segregation of biological activity and

  14. Effect of oxidation on the removal CU{sup 2+}, Cd{sup 2+} and Mn (VII) from dilute aqueous solutions by Upper Freeport bituminous coal. Quarterly report, June--August 1995

    Energy Technology Data Exchange (ETDEWEB)

    Bodine, D.L.

    1995-12-31

    Upper Freeport bituminous coal was able to remove Mn (VII) from dilute aqueous solution by concurrent adsorption and reduction of the manganese to lower valence, less toxic states. This type of reaction indicated the potential of using coal to remove oxidizing contaminants from effluents. Since oxidizing anions can degrade ion exchange resins and membranes, coal may be a viable alternative for detoxification. On analysis of the kinetics of copper and cadmium uptake from dilute aqueous solution, adsorption equilibria and functional groups analyses, it was apparent that the different oxidative pre-treatments affected both the surfaces and pore structure of Upper Freeport coal. The large amount of carboxyl and phenolic functional groups remaining after contact with copper and cadmium solutions, as determined by functional groups analyses, indicated the low affinity of the surface acid groups for these cations. Furthermore, there was almost no metal ion removal at low solution pH`s, which precludes the use of Upper Freeport for treating acidic wastes and effluents such as acid mine drainage. The coal surface functional groups are indeed able to exchange with cations, since the amount of these groups are measured by ion exchange with Na{sup +} and Ba{sup 2+}, however, it may be more difficult to displace the waters of hydration around Cu{sup 2+} and Cd{sup 2+}, to allow their uptake on the coal surface functional groups. Improved metal ion removal might be obtained using a lower rank coal, such as a subbituminous coal, which would be more susceptible to oxidation.

  15. Establishment and maintenance of a coal sample bank and data base. Final report, April 8, 1988--September 28, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Davis, A.; Glick, D.C.

    1993-11-01

    This DOE contract continued support for the DOE Coal Sample Bank and Data Base at Penn State. At the beginning of the contract, a new type of container was evaluated for long-term storage of coal samples ranging in quantity from a few grams to over 10 kg (22 lbs). Gieseler fluid behavior, oxidation of pyrite to sulfates, loss of heating value, and other properties were monitored over time. Based on preliminary results, these foil and polyethylene laminate bags were believed to be a significant improvement over the drums, buckets and cans previously used. Use of the bags was therefore instituted with DECS-1, the first sample collected under the contract. Twenty-two DECS samples were collected, ranging in rank from lignite to anthracite and representing the five most productive coal provinces of the US. Over 6500 containers of DECS samples were created under the contract and 750 containers of 34 PSOC samples are supported by the contract. Each sample was characterized by proximate and ultimate analysis, petrographic (vitrinite reflectance and maceral) analysis, physical and thermoplastic testing, and inorganic element analysis. The resulting data, and geologic data on each sample, were entered in a data base which can be used to produce a formatted five-page or one-page printout for each sample. An interactively operated data base can be searched, sorted or summarized to produce tables of selected data or to identify samples meeting a requestor`s criteria. During the period covered, 2,313 printouts, and 204 special data reports resulting in distribution of data on 34,086 samples, were provided on request.

  16. Material transport by tyred vehicles in coal mines. Final report; Logistica del transporto di materiale tramite mezzi gommati in miniere di carbone. Rapporto finale

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    The research was carried out at the Monte Sinni mine, a sub-bituminous coal mine located in the south west of Sardinia (Italy). The aim of the research has been to develop a control system for materials flow and for the traffic of the tyred vehicles designed specifically for coal mines. In particular, it has been tried to simulate control of each materials supply step starting from the surface stores to the working sites and vice-versa. The hardware has been supplied by Montan-Forschung (Germany) and the software has been produced by Tele Data Software in Cagliari (Italy). Instrumentation is made up by two physically separated parts. The first has been designed to control the run of the trolley truck and allows the exchange of both data and voice between the driver and a main receiving station. The second controls the run of each transport unit by means of data bearing tags (TPD) which are provided with a fixed numerical identification code and are attached to the units. The transport cycle is controlled by the operating software installed on a personal computer that operates as a `main station`. The control-system of the materials flow has given satisfactory results that have allowed the research to achieve its aims. The future application of the system in the mine will bring about certain advantages also by an economic point of view, mostly due to reduction of the materials supply times, as well as the impossibility of shunting mistakes and miscarriages of the load or part of it.

  17. Disaggregating regional energy supply/demand and flow data to 173 BEAs in support of export coal analysis. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1981-06-01

    This report documents the procedures and results of a study sponsored jointly by the US Department of Transportation and the US Department of Energy. The study was conducted to provide, Bureau of Economic Analysis (BEA)-level production/consumption data for energy materials for 1985 and 1990 in support of an analysis of transportation requirements for export coal. Base data for energy forecasts at the regional level were obtained from the Department of Energy, Energy Information Administration. The forecasts selected for this study are described in DOE/EIA's 1980 Annual Report to Congress, and are: 1985 Series, B, medium oil import price ($37.00/barrel); and 1990 Series B, medium oil import price ($41.00/barrel). Each forecast period is extensively described by approximately forty-three statistical tables prepared by EIA and made available to TERA for this study. This report provides sufficient information to enable the transportation analyst to appreciate the procedures employed by TERA to produce the BEA-level energy production/consumption data. The report presents the results of the procedures, abstracts of data tabulations, and various assumptions used for the preparation of the BEA-level data. The end-product of this effort was the BEA to BEA energy commodity flow data by more which serve as direct input to DOT's transportation network model being used for a detailed analysis of export coal transportation.

  18. Estimation of the deformation and filtration properties of coal by adsorption test data based on solution of the inverse problem

    Science.gov (United States)

    Nazarova, L. A.; Nazarov, L. A.; Vandamme, M.; Pereira, J.-M.

    2017-06-01

    A geomechanical 2D model of the experiment on constrained adsorption deformation of cylindrical rock samples and a numerical-analytical method of solving the corresponding boundary-value problem based on coordinatewise averaging of the system of poroelasticity equations for the orthotropic model of the medium have been developed. It has been shown that the axial and radial deformations measured in the experiment are proportional to the volume-averaged adsorption stresses. Using the results of laboratory testing of coal samples, the coefficient inverse problem of determining the deformation characteristics and permeability of the matrix has been stated and solved. It has been revealed that Young's moduli of the latter are greater by two or three times and the permeability is at least two orders of magnitude lower than the corresponding effective values for the sample, which is caused by the natural fracturing of coals.

  19. Relation of coal characteristics to liquefaction behavior. Part II. Continuous flow reactor studies by Gulf Research and Development Co. Final technical report, July 1976-February 1981

    Energy Technology Data Exchange (ETDEWEB)

    Given, P.H.; Spackman, W.; Davis, A.; Walker, P.L.; Lovell, H.L.; Coleman, M.M.; Painter, P.C.

    1982-05-01

    This part of the final report consists of an essentially verbatim transcription of a report by Ajay Sood and W.G. Moon on work performed by personnel of Gulf Research and Development Company under subcontract from this University, as part of the prime contract of the University with the US Department of Energy. Gulf's 1000 gm/h continuous flow reactor (the A-1 Unit) was to be used for all experiments, and a number of product analyses were to be performed. Although some of the results were included in Part I of this report, it has been thought worthwhile to reproduce in full the very detailed report, since it enables the interested reader to see exactly what raw data were collected and what options were selected in computing results from raw data. Generating data in a continuous flow liquefaction reactor operated with a process-derived solvent is a quite complicated process, and critical appraisal of the results requires an understanding of how they were obtained. Since the tasks performed by Gulf were conceived and planned by PSU staff as part of the whole DOE-supported program, it is proposed to comment briefly in this preface on the objectives and rationale of the tasks, and to describe some coals studied in some of the tasks (that is, those coals not already described in part I of this report. Some problems in duplicating the organic solvents used in the different equipments are described.

  20. Two-Stage Separation of V(IV) and Al(III) by Crystallization and Solvent Extraction from Aluminum-Rich Sulfuric Acid Leaching Solution of Stone Coal

    Science.gov (United States)

    Shi, Qihua; Zhang, Yimin; Liu, Tao; Huang, Jing; Liu, Hong

    2017-10-01

    To improve separation of V(IV) and Al(III) from aluminum-rich sulfuric acid leaching solution of stone coal, the two-stage separation by crystallization and solvent extraction methods have been developed. A co-extraction coefficient ( k) was put forward to evaluate comprehensively co-extraction extent in different solutions. In the crystallization stage, 68.2% of aluminum can be removed from the solution. In the solvent extraction stage, vanadium was selectively extracted using di-2-ethylhexyl phosphoric acid/tri-n-butyl phosphate from the crystalline mother solution, followed by H2SO4 stripped efficiently. A V2O5 product with purity of 98.39% and only 0.10% Al was obtained after oxidation, precipitation, and calcination. Compared with vanadium extraction from solution without crystallization, the counter-current extraction stage of vanadium can be decreased from 6 to 3 and co-extraction coefficient ( k) decreased from 2.51 to 0.58 with two-stage separation. It is suggested that the aluminum removal by crystallization can evidently weaken the influence of aluminum co-extraction on vanadium extraction and improve the selectivity of solvent extraction for vanadium.

  1. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction. Final technical report, Volume 1 - effects of solvents, catalysts and temperature conditions on conversion and structural changes of low-rank coals

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Lili [Pennsylvania State Univ., University Park, PA (United States); Schobert, Harold H. [Pennsylvania State Univ., University Park, PA (United States); Song, Chunshan [Pennsylvania State Univ., University Park, PA (United States)

    1998-01-01

    The main objectives of this project were to study the effects of low-temperature pretreatments on coal structure and their impacts on subsequent liquefaction. The effects of pretreatment temperatures, catalyst type, coal rank, and influence of solvent were examined. Specific objectives were to identify the basic changes in coal structure induced by catalytic and thermal pretreatments, and to determine the reactivity of the catalytically and thermally treated coals for liquefaction. In the original project management plan it was indicated that six coals would be used for the study. These were to include two each of bituminous, subbituminous, and lignite rank. For convenience in executing the experimental work, two parallel efforts were conducted. The first involved the two lignites and one subbituminous coal; and the second, the two bituminous coals and the remaining subbituminous coal. This Volume presents the results of the first portion of the work, studies on two lignites and one subbituminous coal. The remaining work accomplished under this project will be described and discussed in Volume 2 of this report. The objective of this portion of the project was to determine and compare the effects of solvents, catalysts and reaction conditions on coal liquefaction. Specifically, the improvements of reaction conversion, product distribution, as well as the structural changes in the coals and coal-derived products were examined. This study targeted at promoting hydrogenation of the coal-derived radicals, generated during thermal cleavage of chemical bonds, by using a good hydrogen donor-solvent and an effective catalyst. Attempts were also made in efforts to match the formation and hydrogenation of the free radicals and thus to prevent retrogressive reaction.

  2. Low-rank coal research. Final technical report, April 1, 1988--June 30, 1989, including quarterly report, April--June 1989

    Energy Technology Data Exchange (ETDEWEB)

    1989-12-31

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  3. SOLUTIONING

    Directory of Open Access Journals (Sweden)

    Maria de Hoyos Guajardo, Ph.D. Candidate, M.Sc., B.Eng.

    2004-11-01

    Full Text Available The theory that is presented below aims to conceptualise how a group of undergraduate students tackle non-routine mathematical problems during a problem-solving course. The aim of the course is to allow students to experience mathematics as a creative process and to reflect on their own experience. During the course, students are required to produce a written ‘rubric’ of their work, i.e., to document their thoughts as they occur as well as their emotionsduring the process. These ‘rubrics’ were used as the main source of data.Students’ problem-solving processes can be explained as a three-stage process that has been called ‘solutioning’. This process is presented in the six sections below. The first three refer to a common area of concern that can be called‘generating knowledge’. In this way, generating knowledge also includes issues related to ‘key ideas’ and ‘gaining understanding’. The third and the fourth sections refer to ‘generating’ and ‘validating a solution’, respectively. Finally, once solutions are generated and validated, students usually try to improve them further before presenting them as final results. Thus, the last section deals with‘improving a solution’. Although not all students go through all of the stages, it may be said that ‘solutioning’ considers students’ main concerns as they tackle non-routine mathematical problems.

  4. Geologic assessment of natural gas from coal seams in the Menefee Formation, San Juan Basin. Topical report, May 1988-May 1989. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Crist, T.E.; Kelso, B.S.; Boyer, C.M.

    1990-07-01

    The results of a regional geologic assessment of the San Juan Basin Menefee Formation include stratigraphic cross-section and overburden, net coal thickness, coal rank, and gas-in-place maps. A geologic investigation was conducted of two microstudy areas which further examine the site-specific characteristics of the coal seams. Natural gas-in-place estimates for the Menefee Formation coal seams range between 22.0 and 34.2 Tcf.

  5. Coal geology

    National Research Council Canada - National Science Library

    Thomas, Larry

    2013-01-01

    This book provides a comprehensive overview of the field of coal geology. All aspects of coal geology are covered in one volume, bridgint the gap between the academic aspects and the practical role of geology in the coal industry...

  6. ECOAL Project—Delivering Solutions for Integrated Monitoring of Coal-Related Fires Supported on Optical Fiber Sensing Technology

    Directory of Open Access Journals (Sweden)

    Joana Ribeiro

    2017-09-01

    Full Text Available The combustion of coal wastes resulting from mining is of particular environmental concern, and the importance of proper management involving real-time assessment of their status and identification of probable evolution scenarios is recognized. Continuous monitoring of the combustion temperature and emission levels of certain gases allows for the possibility of planning corrective actions to minimize their negative impact on the surroundings. Optical fiber technology is well suited to this purpose and here we describe the main attributes and results obtained from a fiber optic sensing system projected to gather data on distributed temperature and gas emissions in these harsh environments.

  7. Pyrite Iron Sulfide Solar Cells Made from Solution Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Law, Matt [Univ. of California, Irvine, CA (United States)

    2017-03-21

    This document summarizes research done under the SunShot Next Generation PV II project entitled, “Pyrite Iron Sulfide Solar Cells Made from Solution,” award number DE-EE0005324, at the University of California, Irvine, from 9/1/11 thru 11/30/16. The project goal was to develop iron pyrite (cubic FeS2) as an absorber layer for solution-processible p-n heterojunction solar cells with a pathway to >20% power conversion efficiency. Project milestones centered around seven main Tasks: (1) make device-quality pyrite thin-films from solar ink; (2) develop an ohmic bottom contact with suitable low resistivity; (3) produce a p-n heterojunction with VOC > 400 mV; (4) make a solar cell with >5% power conversion efficiency; (5) use alloying to increase the pyrite band gap to ~1.2-1.4 eV; (6) produce a p-n heterojunction with VOC > 500 mV; and finally (7) make a solar cell with >10% power conversion efficiency. In response to project findings, the Tasks were amended midway through the project to focus particular effort on passivating the surface of pyrite in order to eliminate excessively-strong surface band bending believed to be responsible for the low VOC of pyrite diodes. Major project achievements include: (1) development and detailed characterization of several new solution syntheses of high-quality thin-film pyrite, including two “molecular ink” routes; (2) demonstration of Mo/MoS2 bilayers as good ohmic bottom contacts to pyrite films; (3) fabrication of pyrite diodes with a glass/Mo/MoS2/pyrite/ZnS/ZnO/AZO layer sequence that show VOC values >400 mV and as high as 610 mV at ~1 sun illumination, although these high VOC values ultimately proved irreproducible; (4) established that ZnS is a promising n-type junction partner for pyrite; (5) used density functional theory to show that the band gap of pyrite can be increased from ~1.0 to a more optimal 1.2-1.3 eV by alloying with oxygen; (6) through extensive measurements of ultrahigh

  8. Monolithic solid oxide fuel cell technology advancement for coal-based power generation. Final report, September 1989--March 1994

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-01

    This project has successfully advanced the technology for MSOFCs for coal-based power generation. Major advances include: tape-calendering processing technology, leading to 3X improved performance at 1000 C; stack materials formulations and designs with sufficiently close thermal expansion match for no stack damage after repeated thermal cycling in air; electrically conducting bonding with excellent structural robustness; and sealants that form good mechanical seals for forming manifold structures. A stack testing facility was built for high-spower MSOFC stacks. Comprehensive models were developed for fuel cell performance and for analyzing structural stresses in multicell stacks and electrical resistance of various stack configurations. Mechanical and chemical compatibility properties of fuel cell components were measured; they show that the baseline Ca-, Co-doped interconnect expands and weakens in hydrogen fuel. This and the failure to develop adequate sealants were the reason for performance shortfalls in large stacks. Small (1-in. footprint) two-cell stacks were fabricated which achieved good performance (average area-specific-resistance 1.0 ohm-cm{sup 2} per cell); however, larger stacks had stress-induced structural defects causing poor performance.

  9. Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration). Draft final technical report

    Energy Technology Data Exchange (ETDEWEB)

    Quimby, J.M.; Kumar, K.S.

    1992-12-31

    The objective of this contract was to investigate the removal of SO{sub x} and particulate matter from direct coal fired combustion gas streams at high temperature and high pressure conditions. This investigation was to be accomplished through a bench scale testing and evaluation program for SO{sub x} removal and the innovative particulate collection concept of particulate growth through electrostatic agglomeration followed by high efficiency mechanical collection. The process goal was to achieve control better than that required by 1979 New Source Performance Standards. During Phase I, the designs of the combustor and gas cleanup apparatus were successfully completed. Hot gas cleanup was designed to be accomplished at temperature levels between 1800{degrees} and 2500{degrees}F at pressures up to 15 atmospheres. The combustor gas flow rate could be varied between 0.2--0.5 pounds per second. The electrostatic agglomerator residence time could be varied between 0.25 to 3 seconds. In Phase II, all components were fabricated, and erected successfully. Test data from shakedown testing was obtained. Unpredictable difficulties in pilot plant erection and shakedown consumed more budget resources than was estimated and as a consequence DOE, METC, decided ft was best to complete the contract at the end of Phase II. Parameters studied in shakedown testing revealed that high-temperature high pressure electrostatics offers an alternative to barrier filtration in hot gas cleanup but more research is needed in successful system integration between the combustor and electrostatic agglomerator.

  10. Advanced turbine design for coal-fueled engines. Phase 1, Erosion of turbine hot gas path blading: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Wagner, J.H.; Johnson, B.V.

    1993-04-01

    The investigators conclude that: (1) Turbine erosion resistance was shown to be improved by a factor of 5 by varying the turbine design. Increasing the number of stages and increasing the mean radius reduces the peak predicted erosion rates for 2-D flows on the blade airfoil from values which are 6 times those of the vane to values of erosion which are comparable to those of the vane airfoils. (2) Turbine erosion was a strong function of airfoil shape depending on particle diameter. Different airfoil shapes for the same turbine operating condition resulted in a factor of 7 change in airfoil erosion for the smallest particles studied (5 micron). (3) Predicted erosion for the various turbines analyzed was a strong function of particle diameter and weaker function of particle density. (4) Three dimensional secondary flows were shown to cause increases in peak and average erosion on the vane and blade airfoils. Additionally, the interblade secondary flows and stationary outer case caused unique erosion patterns which were not obtainable with 2-D analyses. (5) Analysis of the results indicate that hot gas cleanup systems are necessary to achieve acceptable turbine life in direct-fired, coal-fueled systems. In addition, serious consequences arise when hot gas filter systems fail for even short time periods. For a complete failure of the filter system, a 0.030 in. thick corrosion-resistant protective coating on a turbine blade would be eroded at some locations within eight minutes.

  11. Systems studies of coal-conversion processes using a reference simulator. Final report, March 12, 1976-August 12, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Reklaitis, G.V.; Sood, M.K.; Soni, Y.; Overturf, B.W.; Wiede, W.; Clark, S.; Buchanan, P.

    1979-12-01

    Methodology and general purpose software were developed which do allow computer-aided design and analysis of large scale coal conversion processes. The LINBAL package for larger scale balance calculations was demonstrated to be quick and efficient in solving problems involving over 100 streams, 20 species, and 80 or more flowsheet units. The LSP simulation package embodies constraint handling, recycle calculation, and information management features which are an advance of the state of the art. The two level strategy available in LSP was demonstrated on a reasonable sized simulation and shown to result in a 1/3 reduction of CPU time over conventional calculation strategies. The Physical Properties Package was used in all of the simulation models developed under this project and proved to be satisfactory within the limits of the thermodynamic correlations and estimation methods which are encoded. Although the package is largely conventional in overall design, it does employ features which make it convenient to use both within LSP and on a stand-along basis. The PCOST package represents a new approach to the design of this type of program. The program has proved to be simple to use, robust, and accurate within the limitations of the literature cost correlations that it contains. In summary, the project has accomplished its primary objectives. However, time and fiscal limitation did not permit the completion of an adequate slate of case studies.

  12. Selective Separation and Extraction of Vanadium (V) Over Manganese (II) from Co-Leaching Solution of Roasted Stone Coal and Pyrolusite Using Solvent Extraction

    Science.gov (United States)

    Cai, Z. L.; Feng, Y. L.; Zhou, Y. Z.; Li, H. R.; Wang, W. D.

    2013-11-01

    Based on the novel technology for selective separation and extraction of vanadium (V) over manganese (II) from co-leaching solution of roasted stone coal and pyrolusite using solvent extraction, the extraction effect of vanadium (V) and manganese (II) has been studied and many technical conditions have also been optimized. Meanwhile, countercurrent simulation experiments were conducted to verify the results of the experiments. The results indicated that with three countercurrent extraction stages, 99.21% vanadium (V) was extracted using 5% (v/v) N235 and 5% (v/v) secondary octyl alcohol at initial aqueous pH of 3.0 and O/A phase ratio of 1.0. Vanadium (V) could be completely stripped after three-stage countercurrent experiments with 20 wt.% NH4Cl at O/A phase ratio of 1.0. The process flow sheet for the recovery of vanadium (V), as well as manganese (II), was proposed.

  13. Concept of co-firing coal with biomass and natural gas: On track of sustainable solution for future thermal power plants

    National Research Council Canada - National Science Library

    Hodžić Nihad; Smajević Izet; Kazagić Anes

    2016-01-01

    This paper presents R&D project of multi fuel concept (MFC) for future coal-based power plants, demonstrated on example of cofiring Middle-Bosnia brown coal with waste woody biomass and natural gas...

  14. Ground level measurement of nuclei from coal development in the northern Great Plains: baseline measurements. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Davis, B. L.; Johnson, L. R.; Sengupta, S.; Yue, P. C.

    1978-11-01

    The Institute of Atmospheric Sciences of the South Dakota School of Mines and Technology has completed 20 months of ambient air sampling at rural and remote sites in a five-state region of the northern Great Plains. Sampling was accomplished by use of a 27-ft motor home laboratory containing living accommodations for a field crew of two. The laboratory was outfitted with a number of instruments for measurement of pollutant parameters: cloud condensation nuclei, ice nuclei, Aitken nuclei, size distribution information for Aitken size particulate, sulfur dioxide, ozone, raindrop size distributions, and pH of precipitation. In addition, an instrumented meteorological tower provided wind speed, wind direction, ambient air temperature, and dew-point temperature. Instruments varied as to durability and success of operation, but better than 90% data retrieval was possible for the entire 20-month sampling study. Analyses of the large quantities of data obtained were not possible under the initial baseline measurement program, but examination of most parameters indicate that the air masses in the northern Great Plains are still relatively clean and are influenced primarily by local sources of contamination rather than large regional sources. Particulate concentrations in these remote areas are representative of mountain stations or clean rural conditions, and sulfur dioxide concentrations are at the threshold of detectability of the instrument. Precipitation is only very slightly acidic, and no significant quantity of amorphous particles (such as coal dust or combustion products) is found in the quantitative analyses of the high-volume filter collections. A summary of ''average'' conditions observed over the study area is tabulated.

  15. Better planning in coal handling

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-09-15

    More coal terminals are purchasing planning applications to improve the planning process and optimize throughput. Port Kembla Coal Terminal in New South Wales has chosen Quintiq's integrated advanced planning and scheduling solution (APS) to maximise its capacity capabilities and provide seamless integration across its coal supply chain. Implementation will be completed in early 2010. QMASTOR claims to be the market leader in bulk materials software solutions. Its Horizon APS is used at one coal terminal to manage inbound transportation, stockyard allocations and ship loading. Fuelworx software developed by Energy Softworx can manage fuel procurement process, manage contracts and maintain audit controls. 1 fig., 1 photo.

  16. Aquatic toxicity of the decontamination agent: Multipurpose (DAM) decontamination solution. Final report, May-December 1992

    Energy Technology Data Exchange (ETDEWEB)

    Haley, M.V.; Kurnas, C.W.; Chester, N.A.; Muse, W.T.

    1994-05-01

    A new formulation, Decontaminating Agent: Multipurpose (DAM) Decontamination Solution, is being considered as a replacement to the DS-2 decontaminating solution. The new formulation is composed of calcium hypochlorite and N-cyclohexyl-2-pyrrolidinone. Since this is a new formulation little environmental data exists. To estimate potential impact to an aquatic environment, Daphnia magna and Photobacterium phosphoreum (a luminescent marine bacterium) were exposed to the DAM solution and to the individual components (Calcium hypochlorite and N-cyclohexyl-2-pyrrolidinone). The toxicity of the DAM solution to D. magna and P. phosphoreum was 5000 and 0.00053, respectively (highly toxic). The toxicity of calcium hypochlorite' and N-cyclohexyl-2-pyrrolidinone to daphnia was 0.04 mg/L (highly toxic) and 107 mg/L (moderately toxic), respectively.

  17. Analysis of organic sulfur and nitrogen in coal via tandem degradation methods. Final technical report, 1 September 1991--31 August 1992

    Energy Technology Data Exchange (ETDEWEB)

    Kruge, M.A.; Palmer, S.R. [Southern Illinois Univ., Carbondale, IL (United States)

    1992-12-31

    With the recent increase in concern for environmental issues and the implication of sulfur and nitrogen in coal combustion products as prime causes of acid rain, it has become clear that there is an urgent need for alternative methods for de g the nature of organic sulfur and nitrogen compounds in coal. The principal impediment to the molecular characterization of organic sulfur and nitrogen forms in coal is the polymeric nature of coal`s molecular structure, ordering coal insoluble and impossible to analyze by the necessary gas chromatographic (GC) methods. In our research, we apply mild chemical degradation techniques in order to render coal soluble in common organic solvents and thus amenable to standard GC characterization. The study also seeks to apply the degradative techniques to coal asphaltenes, since they are believed to be polymeric structures similar to the whole coal, but smaller and more readily analyzed. Of the degradation techniques used to date, oxidation by sodium dichromate provides the best chemical structural information. A variety of major sulfur compounds were detected in the dichromate oxidation products of demineralized IBC101 coal, including thiazoles (compounds which contains both sulfur and nitrogen) and a series of isomers of C{sub 2}-, C{sub 3}and C{sub 4}-alkylthiophene derivatives. Precise agreement between GC-MS and sulfur-selective GC-FPD data was obtained for these compounds, which probably originated as short alkyl chains on exterior portions of the original peat macromolecular structure that were sulfurized shortly after burial by H{sub 2}S. The results were further confirmed by the analysis of a non-Illinois Basin coal with nearly twice the organic sulfur content of IBC101.

  18. Analysis of organic sulfur and nitrogen in coal via tandem degradation methods. Final technical report, 1 September 1991--31 October 1992

    Energy Technology Data Exchange (ETDEWEB)

    Kruge, M.A.; Palmer, S.R. [Southern Illinois Univ., Carbondale, IL (United States)

    1992-12-31

    With the recent increase in concern for environmental issues and the implication of sulfur and nitrogen in coal combustion preducts as prime causes of acid rain, it has become clear that there is an urgent need for alternative methods for determining the nature of organic sulfur and nitrogen compounds in coal. The principal impediment to the molecular characterization of organic sulfur and nitrogen forms in coal is the polymeric nature of coal`s molecular structure, rendering coal insoluble and impossible to analyze by the necessary gas chromatographic (GC) methods. In our research, we apply mild chemical degradation techniques in order to render coal soluble in common organic solvents and thus amenable to standard GC characterization. The study also seeks to apply the degradative techniques to coal asphaltenes, since they are believed to be polymeric structures similar to the whole coal, but smaller and more readily analyzed. Of the degradation techniques used to date, oxidation by sodium dichromate provides the best chemical structure information. A variety of major sulfur compounds were detected in the dichromate oxidation products of demineralized IBC101 coal, including thiazoles (compounds which contains both sulfur and nitrogen) and a series of isomers of C{sub 2}-, C{sub 3}- and C{sub 4}-alkylthiophene derivatives. Precise agreement between GC-MS and sulfur-selective GC-FPD data was obtained for these compounds, which probably originated as short alkyl chains on exterior portions of the original peat macromolecular structure that were sulfurized shortly after burial by H{sub 2}S. The results were further confirmed by the analysis of a non-Illinois Basin coal with nearly twice the organic sulfur content of IBC101.

  19. Stability of antimicrobial activity of peracetic acid solutions used in the final disinfection process.

    Science.gov (United States)

    Costa, Solange Alves da Silva; Paula, Olívia Ferreira Pereira de; Silva, Célia Regina Gonçalves E; Leão, Mariella Vieira Pereira; Santos, Silvana Soléo Ferreira dos

    2015-01-01

    The instruments and materials used in health establishments are frequently exposed to microorganism contamination, and chemical products are used before sterilization to reduce occupational infection. We evaluated the antimicrobial effectiveness, physical stability, and corrosiveness of two commercial formulations of peracetic acid on experimentally contaminated specimens. Stainless steel specimens were contaminated with Staphylococcus aureus, Escherichia coli, Candida albicans, blood, and saliva and then immersed in a ready peracetic acid solution: 2% Sekusept Aktiv (SA) or 0.25% Proxitane Alpha (PA), for different times. Then, washes of these instruments were plated in culture medium and colony-forming units counted. This procedure was repeated six times per day over 24 non-consecutive days. The corrosion capacity was assessed with the mass loss test, and the concentration of peracetic acid and pH of the solutions were measured with indicator tapes. Both SA and PA significantly eliminated microorganisms; however, the SA solution was stable for only 4 days, whereas PA remained stable throughout the experiment. The concentration of peracetic acid in the SA solutions decreased over time until the chemical was undetectable, although the pH remained at 5. The PA solution had a concentration of 500-400 mg/L and a pH of 2-3. Neither formulation induced corrosion and both reduced the number of microorganisms (p = 0.0001). However, the differences observed in the performance of each product highlight the necessity of establishing a protocol for optimizing the use of each one.

  20. Stability of antimicrobial activity of peracetic acid solutions used in the final disinfection process

    Directory of Open Access Journals (Sweden)

    Solange Alves da Silva COSTA

    2015-01-01

    Full Text Available The instruments and materials used in health establishments are frequently exposed to microorganism contamination, and chemical products are used before sterilization to reduce occupational infection. We evaluated the antimicrobial effectiveness, physical stability, and corrosiveness of two commercial formulations of peracetic acid on experimentally contaminated specimens. Stainless steel specimens were contaminated with Staphylococcus aureus, Escherichia coli, Candida albicans, blood, and saliva and then immersed in a ready peracetic acid solution: 2% Sekusept Aktiv (SA or 0.25% Proxitane Alpha (PA, for different times. Then, washes of these instruments were plated in culture medium and colony-forming units counted. This procedure was repeated six times per day over 24 non-consecutive days. The corrosion capacity was assessed with the mass loss test, and the concentration of peracetic acid and pH of the solutions were measured with indicator tapes. Both SA and PA significantly eliminated microorganisms; however, the SA solution was stable for only 4 days, whereas PA remained stable throughout the experiment. The concentration of peracetic acid in the SA solutions decreased over time until the chemical was undetectable, although the pH remained at 5. The PA solution had a concentration of 500-400 mg/L and a pH of 2-3. Neither formulation induced corrosion and both reduced the number of microorganisms (p = 0.0001. However, the differences observed in the performance of each product highlight the necessity of establishing a protocol for optimizing the use of each one.

  1. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume IV. FBC-Model-II manual

    Energy Technology Data Exchange (ETDEWEB)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the fourth of the seven volume series of our Phase II Final Report. The purpose of this manual is to describe how to access and use M.I.T.'s Fluidized Bed Combustor (FBC) System Program. Presently, the FBC program is stored in a Honeywell Computer System and can be accessed using the Multics interactive system. The intention in writing this manual is to answer the questions that may arise regarding the mechanics of operating the system program, as well as warn the user of possible pitfalls and mistakes that could be made. No attempt is made here to describe the internals of the systems program. The manual describes the procedures an individual would follow to become an active user of the system program. It then explains the various options available for reaching the Multics interactive system on Honeywell 6180 computer on which the program runs. For users outside the Metropolitan Boston area, a public network for data communications is described which is relatively inexpensive. As the system program is approached through Multics using a special command facility TPSA, a separate introduction is provided for Multics TPSA. This facility allows commands appropriate for testing the program and carrying out parametric studies to be executed in a convenient way. Multics TPSA was formulated to meet the needs of the FBC project in particular. Finally, some sample sessions are presented which illustrate the login and logout procedures, the command language, and the data manipulation features of the FBC program. The use of commands helpful in debugging the program is also illustrated.

  2. A study of toxic emissions from a coal-fired power plant utilizing an ESP/wet FGD system. Final report, Volume 2 of 2 - appendices

    Energy Technology Data Exchange (ETDEWEB)

    1994-07-01

    This volume contains the appendices for a coal-fired power plant toxic emissions study. Included are Process data log sheets from Coal Creek, Auditing information, Sampling protocol, Field sampling data sheets, Quality assurance/quality control, Analytical protocol, and Uncertainty analyses.

  3. Pelletizing/reslurrying as a means of distributing and firing clean coal. Final quarterly technical progress report No. 4, April 1, 1991--June 30, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Conkle, H.N.; Raghavan, J.K.; Smit, F.J.; Jha, M.C.

    1991-09-20

    The objective of this study is to develop technology that permits the practical and economic preparation, storage, handling, and transportation of coal pellets, which can be formulated into Coal-Water Fuels (CWFs) suitable for firing in small- and medium-size commercial and industrial boilers, furnaces, and engines.

  4. The effect of moderate coal cleaning on microbial removal of organic sulfur. Final technical report, September 1, 1990--August 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Srivastava, V.J.

    1991-12-31

    The objective of this research is to provide data relevant to the development of an integrated physical, chemical, and microbiological process for the desulfurization of coal, utilizing existing technologies insofar as is possible. Specifically, the effect of increased surface area and porosity achieved by physical, chemical, and microbial treatments of coal on the subsequent microbiological removal of organic sulfur will be evaluated.

  5. Innovative Clean Coal Technology (ICCT). Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers: Volume 1. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO.) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO. to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal- fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: 1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels. 2) performance of the technology and effects on the balance-of- plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. 3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacturer under typical high-sulfur coal-fired utility operating conditions. These uncertainties were explored by operating nine small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. In addition, the test facility operating experience provided a basis for an economic study investigating the implementation of SCR technology.

  6. Modeling of fluidized-bed combustion of coal: Phase II, final reports. Volume II. Detailed description of the model

    Energy Technology Data Exchange (ETDEWEB)

    Louis, J.F.; Tung, S.E.

    1980-10-01

    This document is the second of a seven volume series of our Phase II Final Report. This volume deals with detailed descriptions of the structure of each program member (subroutines and functions), the interrelation between the members of a submodel, and the interrelation between the various submodels as such. The systems model for fluidized bed combustors (FBC-II) consists of a systematic combination of the following interrelated areas: fluid mechanics and bubble growth, char combustion and associated kinetics for particle burnout, sulfur capture, NO/sub x/ formation and reduction, freeboard reactions, and heat transfer. Program outline is shown in Figure 1.1. Input variables (supplied by the user are inspected to check that they lie inside the allowed range of values and are input to the various routines as needed. The necessary physical and fluid mechanical properties are calculated and utilized in estimating char combustion and sulfur capture in the bed and the freeboard. NO/sub x/ and CO emissions are estimated by taking into account all relevant chemical reactions. A material and energy balance is made over the bed. Figure 1.1 shows a block diagram of the systems program. In this diagram, the overall structure of the FBC program is illustrated in terms of the various submodels that together constitute the systems program. A more detailed outline of the systems program is shown in Figure 1.2. In this figure, all important subroutine members of the FBC program are shown, and their linkage to each other, as well as to the main program is indicated. A description of the exact sequence in which these various routines are called at time of program execution is provided in Chapter 8 under the executive routine MAIN.

  7. Ultracoatings: Enabling Energy and Power Solutions in High Contact Stress Environments through next-generation Nanocoatings Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Clifton B. Higdon III

    2012-03-20

    . Advancing this technology, called Ultracoatings, through initial development, scale up, and commercialization to a variety of markets would represent a transformative leap to surface engineering. Several application spaces were considered for immediate implementation of the Ultracoatings technology, including, but not limited to, a drive shaft for an aerospace fuel pump, engine timing components, and dry solids pump hardware for an innovative coal gasifier. The primary focus of the program was to evaluate and screen the performance of the selected (Ti, Zr)B2 Ultracoatings composition for future development. This process included synthesis of the material for physical vapor deposition, sputtering trials and coating characterization, friction and wear testing on sample coupons, and functional hardware testing. The main project deliverables used to gage the project's adherence to its original objective were: Development of a coating/substrate pairing that exhibits wear rate of 0.1 mg/hour or lower at a 1GPa contact pressure, while achieving a maximum coating cost of $0.10/cm2. Demonstrate the aforementioned wear rate in both lubricated and starved lubrication conditions. Although the (Ti, Zr) B2 coating was not tailored for low friction performance, friction and wear evaluations of the material demonstrated a coefficient of sliding friction as low as 0.09. This suggests that varying the percentage of TiB2 present in the composite could enhance the materials performance in water-based lubricants. In the aerospace drive shaft application, functional hardware coated with (Ti, Zr)B2 survived a variety of abuse and long-range durability tests, with contact pressures exceeding 2 GPa. For engine timing components, further work is planned to evaluate the Ultracoatings technology in direct injection and diesel engine conditions. In the final identified application space the dry solids pump hardware, discussions continue on the application of the Ultracoatings technology for those

  8. Environmentally conscious coal combustion

    Energy Technology Data Exchange (ETDEWEB)

    Hickmott, D.D.; Brown, L.F.; Currier, R.P. [and others

    1997-08-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The objective of this project was to evaluate the environmental impacts of home-scale coal combustion on the Navajo Reservation and develop strategies to reduce adverse health effects associated with home-scale coal combustion. Principal accomplishments of this project were: (1) determination of the metal and gaseous emissions of a representative stove on the Navajo Reservation; (2) recognition of cyclic gaseous emissions in combustion in home-scale combustors; (3) `back of the envelope` calculation that home-scale coal combustion may impact Navajo health; and (4) identification that improved coal stoves require the ability to burn diverse feedstocks (coal, wood, biomass). Ultimately the results of Navajo home-scale coal combustion studies will be extended to the Developing World, particularly China, where a significant number (> 150 million) of households continue to heat their homes with low-grade coal.

  9. Coal desulfurization. [using iron pentacarbonyl

    Science.gov (United States)

    Hsu, G. C. (Inventor)

    1979-01-01

    Organic sulfur is removed from coal by treatment with an organic solution of iron pentacarbonyl. Organic sulfur compounds can be removed by reaction of the iron pentacarbonyl with coal to generate CO and COS off-gases. The CO gas separated from COS can be passed over hot iron fillings to generate iron pentacarbonyl.

  10. Coal desulfurization

    Science.gov (United States)

    Corcoran, William H. (Inventor); Vasilakos, Nicholas P. (Inventor); Lawson, Daniel D. (Inventor)

    1982-01-01

    A method for enhancing solubilizing mass transport of reactive agents into and out of carbonaceous materials, such as coal. Solubility parameters of mass transfer and solvent media are matched to individual peaks in the solubility parameter spectrum of coals to enhance swelling and/or dissolution. Methanol containing reactive agent carriers are found particularly effective for removing organic sulfur from coals by chlorinolysis.

  11. Study of the adsorption of Cd (II from aqueous solution using zeolite-based geopolymer, synthesized from coal fly ash; kinetic, isotherm and thermodynamic studies

    Directory of Open Access Journals (Sweden)

    Hamedreza Javadian

    2015-11-01

    Full Text Available A specific type of zeolite, synthesized from coal fly ash, was used in our batch adsorption experiments in order to adsorb Cd (II ions from aqueous solution. Solid-state conversion of fly ash to an amorphous aluminosilicate adsorbent (geopolymer was investigated under specific conditions. The adsorbent ZFA was characterized using XRD, XRF, FT-IR, FE-SEM, LPS and BET surface area. The optimum conditions of sorption were found to be: a ZFA dose of 0.08 g in 25 mL of Cd (II with contact time of 7 h and pH 5. Four equations, namely Morris–Weber, Lagergren, Pseudo-second order and Elovich have been used in order to determine the kinetics of removal process. The collected kinetic data showed that pseudo-second order equations controlled the adsorption process. According to adsorption isotherm studies, the Langmuir isotherm was proved to be the best fit for our experimental data, in comparison to Freundlich, D–R and Tempkin models. The thermodynamic parameters ΔH, ΔS and ΔG are evaluated. Thermodynamic parameters showed that the adsorption of Cd (II onto ZFA was feasible, spontaneous and endothermic under studied conditions. To conduct desorption experiments, several solvents (including alkaline, bases and water have been employed. 84% of desorption efficiency was achieved using NaOH.

  12. 2012 Gordon Research Conference on Water and Aqueous Solutions, Final Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Ben-Amotz, Dor [Purdue Univ., West Lafayette, IN (United States)

    2012-08-17

    Understanding the fundamental principles governing the structure and dynamics of water - and particularly how water mediates chemical interactions and processes - continues to pose formidable challenges and yield abundant surprises. The focus of this Gordon Research Conference is on identifying key questions, describing emerging understandings, and unveiling surprising discoveries related to water and aqueous solutions. The talks and posters at this meeting will describe studies of water and its interactions with objects such as interfaces, channels, electrons, oils, ions, and proteins; probed using optical, electrical, and particle experiments, and described using classical, quantum, and multi-scale theories.

  13. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Volume 1, Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    A major objective of the coal-fired high performance power systems (HIPPS) program is to achieve significant increases in the thermodynamic efficiency of coal use for electric power generation. Through increased efficiency, all airborne emissions can be decreased, including emissions of carbon dioxide. High Performance power systems as defined for this program are coal-fired, high efficiency systems where the combustion products from coal do not contact the gas turbine. Typically, this type of a system will involve some indirect heating of gas turbine inlet air and then topping combustion with a cleaner fuel. The topping combustion fuel can be natural gas or another relatively clean fuel. Fuel gas derived from coal is an acceptable fuel for the topping combustion. The ultimate goal for HIPPS is to, have a system that has 95 percent of its heat input from coal. Interim systems that have at least 65 percent heat input from coal are acceptable, but these systems are required to have a clear development path to a system that is 95 percent coal-fired. A three phase program has been planned for the development of HIPPS. Phase 1, reported herein, includes the development of a conceptual design for a commercial plant. Technical and economic feasibility have been analysed for this plant. Preliminary R&D on some aspects of the system were also done in Phase 1, and a Research, Development and Test plan was developed for Phase 2. Work in Phase 2 include s the testing and analysis that is required to develop the technology base for a prototype plant. This work includes pilot plant testing at a scale of around 50 MMBtu/hr heat input. The culmination of the Phase 2 effort will be a site-specific design and test plan for a prototype plant. Phase 3 is the construction and testing of this plant.

  14. Coal surface control for advanced physical fine coal cleaning technologies

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-01-01

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  15. The attempt on the life of Reinhard Heydrich, architect of the "final solution": a review of his treatment and autopsy.

    Science.gov (United States)

    Weisz, George M; Albury, William R

    2014-04-01

    Reinhard Heydrich, architect of the "Final solution of the Jewish problem," had a meteoric career in the SS. He organized the Wannsee Conference and created the SS killing squads. Under his leadership as Acting Reich Protector of Bohemia and Moravia, the suppression of the Czech community was brutal. An attempt on his life in Prague was unsuccessful but it left him severely injured and he died eight days later. Reviewing the available information on his hospital treatment and the autopsy report, it is suggested that Heydrich received substandard medical treatment, quite likely a result of political interference from rival members of the SS hierarchy.

  16. Disposition of PUREX facility tanks D5 and E6 uranium and plutonium solutions. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Harty, D.P.

    1993-12-01

    Approximately 9 kilograms of plutonium and 5 metric tons of uranium in a 1 molar nitric acid solution are being stored in two PUREX facility vessels, tanks D5 and E6. The plutonium was accumulated during cleanup activities of the plutonium product area of the PUREX facility. Personnel at PUREX recently completed a formal presentation to the Surplus Materials Peer Panel (SMPP) regarding disposition of the material currently in these tanks. The peer panel is a group of complex-wide experts who have been chartered by EM-64 (Office of Site and Facility Transfer) to provide a third party independent review of disposition decisions. The information presented to the peer panel is provided in the first section of this report. The panel was generally receptive to the information provided at that time and the recommendations which were identified.

  17. Utilisation of chemically treated coal

    Directory of Open Access Journals (Sweden)

    Bežovská Mária

    2002-03-01

    Full Text Available The numerous application of coal with high content of humic substances are known. They are used in many branches of industry. The complex study of the composition of coal from upper Nitra mines has directed research to its application in the field of ecology and agriculture. The effective sorption layers of this coal and their humic acids can to trap a broad spectrum of toxic harmful substances present in industrial wastes, particularly heavy metals. A major source of humic acids is coal - the most abundant and predominant product of plant residue coalification. All ranks of coal containt humic acids but lignite from Nováky deposit represents the most easily available and concentrated form of humic acids. Deep oxidation of coal by HNO3 oxidation - degradation has been performed to produce water-soluble-organic acids. The possibilities of utilisation of oxidised coal and humic acids to remove heavy metals from waste waters was studied. The residual concentrations of the investigated metals in the aqueous phase were determined by AAs. From the results follows that the samples of oxidised coal and theirs humic acids can be used for the heavy metal removal from metal solutions and the real acid mine water.Oxidised coal with a high content of humic acids and nitrogen is used in agriculture a fertilizer. Humic acids are active component in coal and help to utilize almost quantitatively nitrogen in soil. The humic substances block and stabiliz toxic metal residues already present in soil.

  18. Solutions for Digital Video Transmission Technology Final Report CRADA No. TC02068.0

    Energy Technology Data Exchange (ETDEWEB)

    Smith, A. T. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Rivers, W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2017-09-07

    This Project aimed at development of software for seismic data processing based on the Geotool code developed by the American company Multimax., Inc. The Geotool code was written in early 90-es for the UNIX platform. Under Project# 2821, functions of the old Geotool code were transferred into a commercial version for the Microsoft XP and Vista platform with addition of new capabilities on visualization and data processing. The developed new version of the Geotool+ was implemented using the up-to-date tool Microsoft Visual Studio 2005 and uses capabilities of the .NET platform. C++ was selected as the main programming language for the Geotool+. The two-year Project was extended by six months and funding levels increased from 600,000 to $670,000. All tasks were successfully completed and all deliverables were met for the project even though both the industrial partner and LLNL principal investigator left the project before its final report.

  19. Interactions between multiple supermassive black holes in galactic nuclei: a solution to the final parsec problem

    Science.gov (United States)

    Ryu, Taeho; Perna, Rosalba; Haiman, Zoltán; Ostriker, Jeremiah P.; Stone, Nicholas C.

    2018-01-01

    Using few-body simulations, we investigate the evolution of supermassive black holes (SMBHs) in galaxies (M* = 1010-1012 M⊙ at z = 0) at 0 < z < 4. Following galaxy merger trees from the Millennium simulation, we model BH mergers with two extreme binary decay scenarios for the 'hard binary' stage: a full or an empty loss cone. These two models should bracket the true evolution, and allow us to separately explore the role of dynamical friction and that of multibody BH interactions on BH mergers. Using the computed merger rates, we infer the stochastic gravitational wave background (GWB). Our dynamical approach is a first attempt to study the dynamical evolution of multiple SMBHs in the host galaxies undergoing mergers with various mass ratios (10-4 < q* < 1). Our main result demonstrates that SMBH binaries are able to merge in both scenarios. In the empty loss cone case, we find that BHs merge via multibody interactions, avoiding the 'final parsec' problem, and entering the pulsar timing arrays band with substantial orbital eccentricity. Our full loss cone treatment, albeit more approximate, suggests that the eccentricity becomes even higher when GWs become dominant, leading to rapid coalescences (binary lifetime ≲1 Gyr). Despite the lower merger rates in the empty loss cone case, due to their higher mass ratios and lower redshifts, the GWB in the full/empty loss cone models are comparable (0.70 × 10-15 and 0.53 × 10-15 at a frequency of 1 yr-1, respectively). Finally, we compute the effects of high eccentricities on the GWB spectrum.

  20. Relevance of Clean Coal Technology for India’s Energy Security: A Policy Perspective

    Science.gov (United States)

    Garg, Amit; Tiwari, Vineet; Vishwanathan, Saritha

    2017-07-01

    Climate change mitigation regimes are expected to impose constraints on the future use of fossil fuels in order to reduce greenhouse gas (GHG) emissions. In 2015, 41% of total final energy consumption and 64% of power generation in India came from coal. Although almost a sixth of the total coal based thermal power generation is now super critical pulverized coal technology, the average CO2 emissions from the Indian power sector are 0.82 kg-CO2/kWh, mainly driven by coal. India has large domestic coal reserves which give it adequate energy security. There is a need to find options that allow the continued use of coal while considering the need for GHG mitigation. This paper explores options of linking GHG emission mitigation and energy security from 2000 to 2050 using the AIM/Enduse model under Business-as-Usual scenario. Our simulation analysis suggests that advanced clean coal technologies options could provide promising solutions for reducing CO2 emissions by improving energy efficiencies. This paper concludes that integrating climate change security and energy security for India is possible with a large scale deployment of advanced coal combustion technologies in Indian energy systems along with other measures.

  1. ParaText : scalable solutions for processing and searching very large document collections : final LDRD report.

    Energy Technology Data Exchange (ETDEWEB)

    Crossno, Patricia Joyce; Dunlavy, Daniel M.; Stanton, Eric T.; Shead, Timothy M.

    2010-09-01

    This report is a summary of the accomplishments of the 'Scalable Solutions for Processing and Searching Very Large Document Collections' LDRD, which ran from FY08 through FY10. Our goal was to investigate scalable text analysis; specifically, methods for information retrieval and visualization that could scale to extremely large document collections. Towards that end, we designed, implemented, and demonstrated a scalable framework for text analysis - ParaText - as a major project deliverable. Further, we demonstrated the benefits of using visual analysis in text analysis algorithm development, improved performance of heterogeneous ensemble models in data classification problems, and the advantages of information theoretic methods in user analysis and interpretation in cross language information retrieval. The project involved 5 members of the technical staff and 3 summer interns (including one who worked two summers). It resulted in a total of 14 publications, 3 new software libraries (2 open source and 1 internal to Sandia), several new end-user software applications, and over 20 presentations. Several follow-on projects have already begun or will start in FY11, with additional projects currently in proposal.

  2. Supply Chain-Based Solution to Prevent Fuel Tax Evasion: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Capps, Gary J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Franzese, Oscar [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Lascurain, Mary Beth [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Siekmann, Adam [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Engineering and Transportation Sciences Division; Barker, Alan M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Electrical and Electronics Systems Research Division

    2016-07-28

    The primary source of funding for the United States transportation system is derived from motor fuel and other highway use taxes. Loss of revenue attributed to fuel-tax evasion has been assessed to be somewhere between 1 billion and 3 billion per year. Any solution that addresses this problem needs to include not only the tax-collection agencies and auditors, but also the carriers transporting oil products and the carriers customers. This report presents a system developed by the Oak Ridge National Laboratory (ORNL) for the Federal Highway Administration which has the potential to reduce or eliminate many fuel-tax evasion schemes. The solution balances the needs of tax-auditors and those of the fuel-hauling companies and their customers. The system has three main components. The on-board subsystem combined sensors, tracking and communication devices, and software (the on-board Evidential Reasoning System, or obERS) to detect, monitor, and geo-locate the transfer of fuel among different locations. The back office sub-system (boERS) used self-learning algorithms to determine the legitimacy of the fuel loading and offloading (important for tax auditors) and detect potential illicit operations such as fuel theft (important for carriers and their customers, and may justify the deployment costs). The third sub-system, the Fuel Distribution and Auditing System or FDAS, is a centralized database, which together with a user interface allows tax auditors to query the data submitted by the fuel-hauling companies and correlate different parameters to quickly identify any anomalies. Industry partners included Barger Transport of Weber City, Virginia (fleet); Air-Weigh, of Eugene, Oregon (and their wires and harnesses); Liquid Bulk Tank (LBT) of Omaha, Nebraska (three five-compartment trailers); and Innovative Software Engineering (ISE) of Coralville, Iowa(on-board telematics device and back-office system). ORNL conducted a pilot test with the three instrumented vehicles

  3. Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

    Energy Technology Data Exchange (ETDEWEB)

    Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

    1982-01-01

    This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

  4. Green-House-Gas-Reduced Coal-and-Biomass-to-Liquid-Based Jet Fuel (GHGR-CBTL) Process - Final Technical report

    Energy Technology Data Exchange (ETDEWEB)

    Lux, Kenneth [Altex Technologies Corporation, Sunnyvale, CA (United States); Imam, Thamina [Altex Technologies Corporation, Sunnyvale, CA (United States); Chevanan, Nehru [Altex Technologies Corporation, Sunnyvale, CA (United States); Namazian, Mehdi [Altex Technologies Corporation, Sunnyvale, CA (United States); Wang, Xiaoxing [Pennsylvania State Univ., University Park, PA (United States); Song, Chunshan [Pennsylvania State Univ., University Park, PA (United States)

    2017-11-03

    This Final Technical Report describes the work and accomplishments of the project entitled, “Green-House-Gas-Reduced Coal-and-Biomass-to-Liquid-Based Jet Fuel (GHGR-CBTL) Process”. The main objective of the project was to raise the Technology Readiness Level (TRL) of the GHGR-CBTL fuel-production technology from TRL 4 to TRL 5 by producing a drop-in synthetic Jet Propellant 8 (JP-8) with a greenhouse-gas footprint less than or equal to petroleum-based JP-8 by utilizing mixtures of coal and biomass as the feedstock. The system utilizes the patented Altex fuel-production technology, which incorporates advanced catalysts developed by Pennsylvania State University. While the system was not fabricated and tested, major efforts were expended to design the 1-TPD and a full-scale plant. The system was designed, a Block-Flow Diagram (BFD), a Process-Flow Diagram (PFD), and Piping-and-Instrumentation Diagrams (P&IDs) were produced, a Bill of Materials (BOM) and associated spec sheets were produced, commercially available components were selected and procured, custom components were designed and fabricated, catalysts were developed and screened for performance, and permitting activities were conducted. Optimization tests for JP-8 production using C2 olefin as the feed were performed over a range of temperatures, pressures and WHSVs. Liquid yields of between 63 to 65% with 65% JP-8 fraction (41-42% JP-8 yield) at 50 psig were achieved. Life-Cycle Analysis (LCA) was performed by Argonne National Laboratory (ANL), and a GHGR-CBTL module was added to the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model. Based upon the experimental results, the plant design was reconfigured for zero natural-gas imports and minimal electricity imports. The LCA analysis of the reconfigured process utilizing the GREET model showed that if the char from the process was utilized to produce combined heat and power (CHP) then a feed containing 23 wt% biomass and

  5. Incineration of water pollutants with activated char from coal, wood, or crop residues in a system designed to produce energy and pyrolysis by-product chemicals. Final Technical completion report (Final)

    Energy Technology Data Exchange (ETDEWEB)

    Manahan, S.E.; Gale, R.W.; Laquer, F.C.; Smith, K.E.; Bornhop, D.J.

    1982-11-18

    A wastewater-treatment system, particularly useful for treating chemical leachates, was developed on a laboratory scale. Subbituminous coal, 20-60-mesh, was pyrolyzed. A synthetic wastewater containing 3520 ppm total organic carbon was contacted with nonactivated char, char activated in water-saturated nitrogen at 850/sup 0/C, and coal ash. During a contact time of 0.5 hour, organic removals from the wastewater were 13.3% by nonactivated char, 38.8% by activated char, and 46.5% by ash. For a contact time of 72 hours, organic removals were about 25% for nonactivated char, 58.8% for activated char, and 53.4% for ash. This treatment system is applicable where large amounts of waste carbonaceous material (coal, wood, crop residues) are available. The spent char can be incinerated. Heat from incineration can be used in the pyrolysis step, and the coal ash can be recycled to the water-purification step.

  6. 77 FR 5566 - Notice of Availability of the Final EIS for the HB In-Situ Solution Mine Project, Eddy County...

    Science.gov (United States)

    2012-02-03

    ...., Carlsbad, New Mexico 88220. Interested persons may also review the Final EIS on the Internet at http://www... method. Intrepid proposes to ] construct and operate a solution mine project in an existing deep mine...

  7. Schedules of Controlled Substances: Placement of FDA-Approved Products of Oral Solutions Containing Dronabinol [(-)-delta-9-trans- tetrahydrocannabinol (delta-9-THC)] in Schedule II. Final rule.

    Science.gov (United States)

    2017-11-22

    This final rule adopts without changes an interim final rule with request for comments published in the Federal Register on March 23, 2017. On July 1, 2016, the U.S. Food and Drug Administration (FDA) approved a new drug application for Syndros, a drug product consisting of dronabinol [(-)-delta-9-trans-tetrahydrocannabinol (delta-9-THC)] oral solution. The Drug Enforcement Administration (DEA) maintains FDA-approved products of oral solutions containing dronabinol in schedule II of the Controlled Substances Act.

  8. Re-Use of Clean Coal Technology By-Products in the Construction of Low Permeability Liners. Final report, 10/1/1996 - 3/31/2000

    Energy Technology Data Exchange (ETDEWEB)

    Wolfe, William E. [The Ohio State Univ., Columbus, OH (United States); Butalia, Tarunjit S. [The Ohio State Univ., Columbus, OH (United States); Whitlach, Jr., E. Earl [The Ohio State Univ., Columbus, OH (United States); Mitsch, William [The Ohio State Univ., Columbus, OH (United States)

    2000-12-31

    This final project report presents the results of a research program conducted at The Ohio State University from October 1, 1996 to March 31, 2000 to investigate the use of stabilized flue gas desulfurization (FGD) materials in the construction of low permeability liners. The objective of the research program was to establish field-verified time-dependent relationships for the performance of liners constructed from stabilized FGD by-products generated in Ohio. The project objective was accomplished with a coordinated program of testing and analyzing small scale laboratory specimens under controlled conditions, medium-scale wetland mesocosms, and a full-scale pond facility. Although the specific uses directly addressed by this report include liners for surface impoundments, the results presented in this study are also useful in other applications including design of daily cover and liners for landfills, seepage cutoff walls and trenches and for nutrient retention and pollution mitigation wetlands. The small scale laboratory tests, medium scale mesocosm wetland experiments, and construction and monitoring of a full-scale FGD lined facility (capacity of one million gallons) shows that stabilized FGD materials can be used as low permeability liners in the construction of water and manure holding ponds, and constructed wetlands for wastewater treatment. Actual permeability coefficients in the range of 10-7 cm/sec (3 x 10-9 ft/sec) can be obtained in the field by properly compacting lime and fly ash enriched stabilized FGD materials. Leachate from the FGD material meets Ohio’s non-toxic criteria for coal combustion by-products, and for most potential contaminants the national primary and secondary drinking water standards are also met. The low permeability non-toxic FGD material investigated in this study poses very minimal risks, if any, for groundwater contamination. Constructed FGD-lined wetlands offer the opportunity for increased phosphorous

  9. Phase states of methane in fossil coals

    Science.gov (United States)

    Alexeev, A. D.; Vasylenko, T. A.; Ul'yanova, E. V.

    2004-06-01

    NMR measurements have revealed that methane can exist in coal samples in the state of solid solution rather than only adsorbed gas, opening new ways to prevention of gas dynamic accidents in underground coal mines and true estimation of coalbed methane resources. Understanding molecular structure of coal constituents and forms of methane occurrence in coal is the only way of extracting safely either coal or methane. We had studied nuclear magnetic resonance lines in various coals at room or low temperatures and have found that there exist three species of methane molecules differing in molecular mobility. Based on estimated diffusion parameters, these species were attributed to free methane, adsorbed methane, and solid solution of methane in crystalline coal substance. While first two phases are well known and can be analyzed by many different techniques, the last one hardly can be studied by methods other than NMR, resulting in inadequate estimations of methane resources.

  10. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  11. Novel approach to coal gasification using chemically incorporated catalysts (Phase II). Appendix A-F. Final report, May 1978-June 1981

    Energy Technology Data Exchange (ETDEWEB)

    Feldmann, H.F.; Conkle, H.N.; Appelbaum, H.R.; Chauhan, S.P.

    1981-01-01

    This volume contains six appendices: experimental apparatus, test conditions, and results of catalytic coal treatment; direct hydrogasification; summary of test runs for hydrogasification of BTC; summary of test runs for hydrogasification of char; summary of steam/O/sub 2/ gasification runs; and process analysis. Forty tables and nine figures are also included.

  12. Novel process for depolymerization of coal to C{sub 2}-C{sub 4} hydrocarbons. Final report, 1 September 1989--31 August 1993

    Energy Technology Data Exchange (ETDEWEB)

    Wiser, W.H.; Oblad, A.G.

    1994-07-08

    A principal objective of this work was to study the conversion of coal to C{sub 2} {minus} C{sub 4} hydrocarbons in a two-stage reactor system. Coal was converted to liquids at 440{degrees}C in a stirred batch autoclave using tetralin as the hydrogen donor solvent. The liquids produced were separated from the unreacted coal and ash by filtration. The liquids were then fed into a second stage fixed bed reactor containing sulfided Ni-Mo/Al{sub 2}O{sub 3} and SiO{sub 2{minus}}Al{sub 2}O{sub 3} catalyst. The liquids were hydrocracked on the dual functional catalyst giving high yields of C{sub 2} {minus} C{sub 4}. hydrocarbons. The pressure was 1800 psi and the temperatures were in the range of 425 to 500{degrees}C. The kinetic parameters of the conversion of coal liquids to gases were determined. The activation energy was determined.

  13. A study of toxic emissions from a coal-fired power plant utilizing the SNOX innovative clean coal technology demonstration. Volume 1, Sampling/results/special topics: Final report

    Energy Technology Data Exchange (ETDEWEB)

    1994-07-01

    This study was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE during 1993. The motivation for those assessments was the mandate in the 1990 Clean Air Act Amendments that a study be made of emissions of hazardous air pollutants (HAPs) from electric utilities. The report is organized in two volumes. Volume 1: Sampling describes the sampling effort conducted as the basis for this study; Results presents the concentration data on HAPs in the several power plant streams, and reports the results of evaluations and calculations conducted with those data; and Special Topics report on issues such as comparison of sampling methods and vapor/solid distributions of HAPs. Volume 2: Appendices include quality assurance/quality control results, uncertainty analysis for emission factors, and data sheets. This study involved measurements of a variety of substances in solid, liquid, and gaseous samples from input, output, and process streams at the Innovative Clean Coal Technology Demonstration (ICCT) of the Wet Sulfuric Acid-Selective Catalytic Reduction (SNOX) process. The SNOX demonstration is being conducted at Ohio Edison`s Niles Boiler No. 2 which uses cyclone burners to burn bituminous coal. A 35 megawatt slipstream of flue gas from the boiler is used to demonstrate SNOX. The substances measured at the SNOX process were the following: 1. Five major and 16 trace elements, including mercury, chromium, cadmium, lead, selenium, arsenic, beryllium, and nickel; 2. Acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate); 3. Ammonia and cyanide; 4. Elemental carbon; 5. Radionuclides; 6. Volatile organic compounds (VOC); 7. Semi-volatile compounds (SVOC) including polynuclear aromatic hydrocarbons (PAH); and 8. Aldehydes.

  14. Innovative Clean Coal Technology (ICCT). Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers: Volume 2, Appendices A--N. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    Volume 2 contains the following appendices: Appendix A, Example Material Safety Data Sheet; Appendix B, Initial Site Characterization Test Results; Appendix C, Testing Proposal, Southern Research Institute; Appendix D, Example Laboratory Catalyst Test Protocol; Appendix E, Detailed Coal Analysis Data; Appendix F, Standard Methods-QA/QC Document; Appendix G, Task No. 1 Commissioning Tests; Appendix H, Task No. 2 Commissioning Tests; Appendix I, First Parametric Sequence Spreadsheets; Appendix J, Second Parametric Sequence Spreadsheets; Appendix K, Third Parametric Sequence Spreadsheets; Appendix L, Fourth Parametric Sequence Spreadsheets; Appendix M, Fifth Parametric Sequence Spreadsheets; and Appendix N, First Series-Manual APH Tests.

  15. "Final solution" in Myanmar?

    Science.gov (United States)

    Lintner, B

    1992-07-01

    The conditions of Burmese prostitutes in Thailand's border communities are described to show how they are mistreated and denied health information on AIDS prevention. The police had been returning prostitutes to Myanmar, until it was brought to their attention that 25 female prostitutes had been fatally injected with cyanide by Burmese authorities to stop the spread of HIV. Myanmar's military rulers have concentrated AIDS education on the military. They do not want the soldiers, who keep the military regime in power to become infected with AIDS. The reports of Burmese murders of prostitutes have come from all quarters. In the group of 25 prostitutes were two cousins of a Burmese citizen who reported the disappearance of his relatives after they left for a shopping trip in the southern Thai city of Ranong, opposite Kawthaung in Myanmar. Thai police found that the two cousins had been kidnapped and sold into prostitution in a brothel in Ranong, which had been raided by police. In the northern city of Chiang Mai, it is estimated that 10,000 of the prostitutes are Burmese girls and women. UNICEF has reported that as many as 40,000 Burmese girls are sold into prostitution in Bangkok and border towns such as Ranong and Chiang Mai. Anti-Slavery International estimated that more than 1500 of the prostitutes in Ranong are Burmese girls and women who have been forced into this work. Their condition is very similar to slavery. Girls are forced to work long hours and may be fed only a bowl of rice with watery soup. Prostitution flourished because 20,000 Burmese fisherman, who are at sea for prolonged periods, frequent the brothels on their return. There is a growing prevalence of HIV infection in Ranong in part due to the fishermen's widespread heroin use aboard ship. In Ranong, 1 in 5 prostitutes were found to be HIV positive including 1 in 3 of the Burmese women. Those locked in brothels are not included in the figures. Unfortunately the Burmese captives know no or very little Thai or English, which means there is no exposure to AIDS prevention efforts. Conditions were reported in a letter signed by 73 Burmese captive prostitutes who wanted to return to their parents. The letter was smuggled out of brothel operating in the Grand Victoria Hotel in Ranong. POlice raids and the return of prostitute to Myanmar by boat have been hindered by brothel owners who bribe officials.

  16. Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming

    Energy Technology Data Exchange (ETDEWEB)

    1982-01-01

    Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

  17. Biochemical Removal of HAP Precursors from Coal

    Energy Technology Data Exchange (ETDEWEB)

    Olson, Gregory J

    1997-05-12

    Column biooxidation tests with Kentucky coal confirmed results of earlier shake flask tests showing significant removal from the coal of arsenic, selenium, cobalt, manganese, nickel and cadmium. Rates of pyrite biooxidation in Kentucky coal were only slightly more than half the rates found previously for Indiana and Pittsburgh coals. Removal of pyrite from Pittsburgh coal by ferric ion oxidation slows markedly as ferrous ions accumulate in solution, requiring maintenance of high redox potentials in processes designed for removal of pyrite and hazardous air pollutant (HAP) precursors by circulation of ferric solutions through coal. The pyrite oxidation rates obtained in these tests were used by Unifield Engineering to support the conceptual designs for alternative pyrite and HAP precursor bioleaching processes for the phase 2 pilot plant. Thermophilic microorganisms were tested to determine if mercury could be mobilized from coal under elevated growth temperatures. There was no evidence for mercury removal from coal under these conditions. However, the activity of the organisms may have liberated mercury physically. It is also possible that the organisms dissolved mercury and it readsorbed to the clay preferentially. Both of these possibilities are undergoing further testing. The Idaho National Engineering and Environmental Laboratory's (INEEL) slurry column reactor was operated and several batches of feed coal, product coal, waste solids and leach solutions were submitted to LBL for HAP precursor analysis. Results to date indicate significant removal of mercury, arsenic and other HAP precursors in the combined physical-biological process.

  18. Enthalpy measurement of coal-derived liquids. Final report, April 1981-September 1983. [517 to 10342 kPa; 340 to 664 K

    Energy Technology Data Exchange (ETDEWEB)

    Kidnay, A.J.; Yesavage, V.F.

    1983-11-10

    This report summarizes the results of experimental measurements of enthalpies for quinoline using a freon boil-off flow calorimeter, and an investigation of the applicability of cubic equations of state to correlating the enthalpy of coal-liquids. In Part A the compound quinoline is discussed. Process flow in the flow calorimeter, operational problems, and equipment modifications are described. Procedural modifications, including a new sample purification procedure, are described. Part B discusses the correlational effort. This includes a discussion of past correlational work and the difficulties associated with a general correlation for coal liquid enthalpy. In addition experimental data and computer generated predictions are presented. Three equations of state were used to predict vapor pressures and enthalpies for ten pure component systems previously studied in the lab. In general, the results were encouraging. All three equations were found to be effective in predicting both enthalpies and vapor pressures. In addition, the equations worked well when fit to mixture enthalpies. The Modified SRK equation was found to be superior to the other equations and modeled all properties for both associating and nonassociating systems well. The Modified SRK equation did have a drawback in that it was not readily generalized since it required two parameters which must be fit to data for best results. In sum, it was shown that a four parameter equation of state could be used successfully to correlate the enthalpy of coal-liquid model compounds.

  19. Development of a coal-fired combustion system for industrial process heating applications. Phase 3 final report, November 1992--December 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-26

    A three phase research and development program has resulted in the development and commercialization of a Cyclone Melting System (CMS{trademark}), capable of being fueled by pulverized coal, natural gas, and other solid, gaseous, or liquid fuels, for the vitrification of industrial wastes. The Phase 3 research effort focused on the development of a process heater system to be used for producing value added glass products from the vitrification of boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project was to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential for successful commercialization. The demonstration test consisted of one test run with a duration of 105 hours, approximately one-half (46 hours) performed with coal as the primary fuel source (70% to 100%), the other half with natural gas. Approximately 50 hours of melting operation were performed vitrifying approximately 50,000 lbs of coal-fired utility boiler flyash/dolomite mixture, producing a fully-reacted vitrified product.

  20. Concept of co-firing coal with biomass and natural gas: On track of sustainable solution for future thermal power plants

    Directory of Open Access Journals (Sweden)

    Hodžić Nihad

    2016-01-01

    Full Text Available This paper presents R&D project of multi fuel concept (MFC for future coal-based power plants, demonstrated on example of cofiring Middle-Bosnia brown coal with waste woody biomass and natural gas. Pulverised Combustion (PC lab-scale furnace has been used for the cofiring tests, varying up to 20%w portion of biomass and up to 10%th portion of natural gas in the fuel mix. Tests were purposed to optimize the combustion temperature, air distribution, including Over Fire Air System (OFAS, fuel combination and fuel distribution, including reburning concept, as function of emissions and combustion efficiency estimated through the ash deposits behaviours and unburnt. Considering application of proposed MFC in case of TPP Kakanj unit 6 (118 MWe set here as a referent power plant, temperature levels and fuel distributions for lowest emissions of CO2 and NOx were found during lab tests, provided that combustion efficiency is at an acceptable level. Derived research results yield input data for calculation sustainability indicators of MFC for the referent power plant, considering 6 fuel options - different combinations of coal, biomass and natural gas. Single criteria analysis and multicriteria sustainability assessment have been done, giving an advantage to the options of cofiring coal with woody biomass and natural gas in the case demonstrated.

  1. DRUCKFLAMM - Investigation on combustion and hot gas cleanup in pulverized coal combustion systems. Final report; DRUCKFLAMM - Untersuchungen zur Verbrennung und Heissgasreinigung bei der Druckkohlenstaubfeuerung. Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Hein, K.R.G.; Benoehr, A.; Schuermann, H.; Stroehle, J.; Klaiber, C.; Kuhn, R.; Maier, J.; Schnell, U.; Unterberger, S.

    2001-07-01

    The ambitions of making energy supply more efficient and less polluting brought forth the development of coal based combined cycle power plants allowing considerable increases in net efficiencies. One of the regarded firing concepts for a coal based combined cycle power plant is represented by the pressurised pulverised coal combustion process which has the highest efficiency potential compared with the other coal based concepts. The fundamental purpose of the project was to gain firm knowledge concerning firing behaviour of coal in a pressurised pulverised coal combustion system. Detailed investigations were carried out in a pressurised entrained flow reactor taking into account fuel conversion and particle behaviour, pollutant formation and material behaviour under conditions of a pressurised pulverised coal firing. During the project's investigations several different measurement techniques were tested and partially also acquired (e.g. a two-colour-pyrometry system to measure simultaneous particle surface temperature and particle diameter of burning fuel particles). Calculation models under pressurised conditions for pressure vessel simulation and better scale-up were developed synchronously with the experimental investigations. The results gained using the pressurised entrained flow reactor show that many combustion mechanisms are influenced by increased pressure, for instance the fuel conversion is intensified and at the same time pollutant emissions decreased. The material investigations show that the ceramic materials used due to the very high combustion temperatures are very sensitive versus slagging and fast temperature changes, therefore further development requirements are needed to fully realise the high durability of ceramics in the pressurised furnace. Concerning the improvement of existing models for furnace simulation under pressurised conditions, a good resemblance can be observed when considering the actual measurement results from the test

  2. Impacts of Coal Seam Gas (Coal Bed Methane) and Coal Mining on Water Resources in Australia

    Science.gov (United States)

    Post, D. A.

    2013-12-01

    Mining of coal bed methane deposits (termed ';coal seam gas' in Australia) is a rapidly growing source of natural gas in Australia. Indeed, expansion of the industry is occurring so quickly that in some cases, legislation is struggling to keep up with this expansion. Perhaps because of this, community concern about the impacts of coal seam gas development is very strong. Responding to these concerns, the Australian Government has recently established an Independent Expert Scientific Committee (IESC) to provide advice to the Commonwealth and state regulators on potential water-related impacts of coal seam gas and large coal mining developments. In order to provide the underlying science to the IESC, a program of ';bioregional assessments' has been implemented. One aim of these bioregional assessments is to improve our understanding of the connectivity between the impacts of coal seam gas extraction and groundwater aquifers, as well as their connection to surface water. A bioregional assessment can be defined as a scientific analysis of the ecology, hydrology, geology and hydrogeology of a bioregion, with explicit assessment of the potential direct, indirect and cumulative impacts of coal seam gas and large coal mining development on water resources. These bioregional assessments are now being carried out across large portions of eastern Australia which are underlain by coal reserves. This presentation will provide an overview of the issues related to the impacts of coal seam gas and coal mining on water resources in Australia. The methodology of undertaking bioregional assessments will be described, and the application of this methodology to six priority bioregions in eastern Australia will be detailed. Preliminary results of the program of research to date will be assessed in light of the requirements of the IESC to provide independent advice to the Commonwealth and State governments. Finally, parallels between the expansion of the industry in Australia with that

  3. Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

  4. Dependence of liquefaction behavior on coal characteristics. Part VI. Relationship of liquefaction behavior of a set of high sulfur coals to chemical structural characteristics. Final technical report, March 1981 to February 1984

    Energy Technology Data Exchange (ETDEWEB)

    Neill, P. H.; Given, P. H.

    1984-09-01

    The initial aim of this research was to use empirical mathematical relationships to formulate a better understanding of the processes involved in the liquefaction of a set of medium rank high sulfur coals. In all, just over 50 structural parameters and yields of product classes were determined. In order to gain a more complete understanding of the empirical relationships between the various properties, a number of relatively complex statistical procedures and tests were applied to the data, mostly selected from the field of multivariate analysis. These can be broken down into two groups. The first group included grouping techniques such as non-linear mapping, hierarchical and tree clustering, and linear discriminant analyses. These techniques were utilized in determining if more than one statistical population was present in the data set; it was concluded that there was not. The second group of techniques included factor analysis and stepwise multivariate linear regressions. Linear discriminant analyses were able to show that five distinct groups of coals were represented in the data set. However only seven of the properties seemed to follow this trend. The chemical property that appeared to follow the trend most closely was the aromaticity, where a series of five parallel straight lines was observed for a plot of f/sub a/ versus carbon content. The factor patterns for each of the product classes indicated that although each of the individual product classes tended to load on factors defined by specific chemical properties, the yields of the broader product classes, such as total conversion to liquids + gases and conversion to asphaltenes, tended to load largely on factors defined by rank. The variance explained and the communalities tended to be relatively low. Evidently important sources of variance have still to be found.

  5. The use of Clay minerals in stratigraphic correlations of carboniferous coal deposits. Les mineraux argileux au service des correlations stratigraphiques des formations houilleres du Carbonifere; Rapport final

    Energy Technology Data Exchange (ETDEWEB)

    Lorenzi, G.; Bossiroy, D.; Dreesen, R. (ISSeP, Liege (Belgium))

    1992-01-01

    The main objective of this research project has been achieved: the development of a new tool for the lithostratigraphical correlation of cored boreholes. The proposed technique is based on the processing and interpretation of the results of mineralogical analyses, carried out on the clay minerals from finegrained siliciclastic rocks, associated with coal seams. For this study, the stratigraphical interval below and above the Quaregnon Marine Band (limit between the Westphalian A and B), and more precisely the rock sequence between coal seams no KS 71 and 44 was selected: this interval has been recorded in several cored boreholes, north of the actual exploitation limits of the Beringen and Zolder-Houthalen collieries (Belgian Campine). Over 1000 samples (mainly from mudstones, some siltstones and sandstones) were taken out of the cores, at a regular spacing (about 2m), for further mineralogical analysis. Simultaneously, a sedimentological study was carried out on the the sampled sequences, as well as a petrographical analysis of the main rock types. This resulted in a reconstruction of the Westphalian depositional environments and in a better knowledge of the 'behaviour' (geological history) of the clay minerals. The mineralogical composition of the clay minerals was identified through X-ray diffraction and computer-aided graphical processing of the resulting data produced percentage or intensity ratio curves, which could then be used as a lithostratigraphical correlation tool. Correlations have been shown between relatively simple rock sequences (without split seams) in neighbouring boreholes (1 to 3 km apart) and positive correlations revealed between more complex sequences containing multiple coals seams. Some positive but less obvious correlations have also been discovered between sequences from widely spaced boreholes ({+-}10 km apart).

  6. Solid state 13C NMR analysis of shales and coals from Laramide Basins. Final report, March 1, 1995--March 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Miknis, F.P.; Jiao, Z.S.; Zhao, Hanqing; Surdam, R.C.

    1998-12-31

    This Western Research Institute (WRI) jointly sponsored research (JSR) project augmented and complemented research conducted by the University of Wyoming Institute For Energy Research for the Gas Research Institute. The project, {open_quotes}A New Innovative Exploitation Strategy for Gas Accumulations Within Pressure Compartments,{close_quotes} was a continuation of a project funded by the GRI Pressure Compartmentalization Program that began in 1990. That project, {open_quotes}Analysis of Pressure Chambers and Seals in the Powder River Basin, Wyoming and Montana,{close_quotes} characterized a new class of hydrocarbon traps, the discovery of which can provide an impetus to revitalize the domestic petroleum industry. In support of the UW Institute For Energy Research`s program on pressure compartmentalization, solid-state {sup 13}C NMR measurements were made on sets of shales and coals from different Laramide basins in North America. NMR measurements were made on samples taken from different formations and depths of burial in the Alberta, Bighorn, Denver, San Juan, Washakie, and Wind River basins. The carbon aromaticity determined by NMR was shown to increase with depth of burial and increased maturation. In general, the NMR data were in agreement with other maturational indicators, such as vitrinite reflectance, illite/smectite ratio, and production indices. NMR measurements were also obtained on residues from hydrous pyrolysis experiments on Almond and Lance Formation coals from the Washakie Basin. These data were used in conjunction with mass and elemental balance data to obtain information about the extent of carbon aromatization that occurs during artificial maturation. The data indicated that 41 and 50% of the original aliphatic carbon in the Almond and Lance coals, respectively, aromatized during hydrous pyrolysis.

  7. Field study for disposal of solid wastes from Advanced Coal Processes: Ohio LIMB Site Assessment. Final report, April 1986--November 1994

    Energy Technology Data Exchange (ETDEWEB)

    Weinberg, A.; Coel, B.J.; Butler, R.D.

    1994-10-01

    New air pollution regulations will require cleaner, more efficient processes for converting coal to electricity, producing solid byproducts or wastes that differ from conventional pulverized-coal combustion ash. Large scale landfill test cells containing byproducts were built at 3 sites and are to be monitored over at least 3 years. This report presents results of a 3-y field test at an ash disposal site in northern Ohio; the field test used ash from a combined lime injection-multistage burner (LIMB) retrofit at the Ohio Edison Edgewater plant. The landfill test cells used LIMB ash wetted only to control dusting in one cell, and LIMB ash wetted to optimize compaction density in the other cell. Both test cells had adequate load-bearing strength for landfill stability but had continuing dimensional instability. Heaving and expansion did not affect the landfill stability but probably contributed to greater permeability to infiltrating water. Leachate migration occurred from the base, but effects on downgradient groundwater were limited to increased chloride concentration in one well. Compressive strength of landfilled ash was adequate to support equipment, although permeability was higher and strength was lower than anticipated. Average moisture content has increased to about 90% (dry weight basis). Significant water infiltration has occurred; the model suggests that as much as 20% of the incident rainfall will pass through and exit as leachate. However, impacts on shallow ground water is minimal. Results of this field study suggest that LIMB ash from combustion of moderate to high sulfur coals will perform acceptably if engineering controls are used to condition and compact the materials, reduce water influx to the landfill, and minimize leachate production. Handling of the ash did not pose serious problems during cell construction; steaming and heat buildup were moderate.

  8. Evaluation of technical feasibility of closed-cycle non-equilibrium MHD power generation with direct coal firing. Final report, Task I

    Energy Technology Data Exchange (ETDEWEB)

    1981-11-01

    Program accomplishments in a continuing effort to demonstrate the feasibility of direct coal-fired, closed-cycle MHD power generation are reported. This volume contains the following appendices: (A) user's manual for 2-dimensional MHD generator code (2DEM); (B) performance estimates for a nominal 30 MW argon segmented heater; (C) the feedwater cooled Brayton cycle; (D) application of CCMHD in an industrial cogeneration environment; (E) preliminary design for shell and tube primary heat exchanger; and (F) plant efficiency as a function of output power for open and closed cycle MHD power plants. (WHK)

  9. Unconventional methods for coal extraction from coal deposits

    Energy Technology Data Exchange (ETDEWEB)

    Skalicka, J.; Vydra, J.

    1984-06-01

    Unconventional methods for coal seam extraction are discussed which could be suitable for mining and geologic conditions of Czechoslovakia. The following methods are comparatively evaluated: in-situ gasification (tests carried out in Czechoslovakia in Borislav, Brezno I, Brezno II), cutting coal by jets of water at a pressure of 10 MPa or pulses of water jets at a pressure of 1400 MPa, in-situ dissolution of coal seams (using hydrocarbons as a solvent at a temperature of 300 to 400 C), in-situ hydrogenation, in-situ distillation, fluid injection of chemical compounds which cause coal fracturing and comminution under water pressure (injection of sodium hydroxides or a mixture of nitrogen, oxygen followed by water solution of ammonia, temperature from 10 to 100 C, pressure from 0.1 to 10.0 MPa). From among the evaluated unconventional coal extraction methods, in-situ gasification, coal cutting by water jets and use of fluid injection of chemical compounds which cause coal fracturing are most suitable for geologic conditions in Czechoslovakia. 9 references.

  10. Environmental Justice and Sustainability Impact Assessment: In Search of Solutions to Ethnic Conflicts Caused by Coal Mining in Inner Mongolia, China

    OpenAIRE

    Lee Liu; Jie Liu; Zhenguo Zhang

    2014-01-01

    The Chinese government adopted more specific and stringent environmental impact assessment (EIA) guidelines in 2011, soon after the widespread ethnic protests against coal mining in Inner Mongolia. However, our research suggests that the root of the ethnic tension is a sustainability problem, in addition to environmental issues. In particular, the Mongolians do not feel they have benefited from the mining of their resources. Existing environmental assessment tools are inadequate to address su...

  11. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX{reg_sign}) molten carbonate fuel cell. Volumes 1--6, Final report

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-01

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  12. A study of toxic emissions from a coal-fired power plant utilizing an ESP/Wet FGD system. Volume 1, Sampling, results, and special topics: Final report

    Energy Technology Data Exchange (ETDEWEB)

    1994-07-01

    This was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE-PETC in 1993 as mandated by the 1990 Clean Air Act. It is organized into 2 volumes; Volume 1 describes the sampling effort, presents the concentration data on toxic chemicals in several power plant streams, and reports the results of evaluations and calculations. The study involved solid, liquid, and gaseous samples from input, output, and process streams at Coal Creek Station Unit No. 1, Underwood, North Dakota (1100 MW mine-mouth plant burning lignite from the Falkirk mine located adjacent to the plant). This plant had an electrostatic precipitator and a wet scrubber flue gas desulfurization unit. Measurements were conducted on June 21--24, 26, and 27, 1993; chemicals measured were 6 major and 16 trace elements (including Hg, Cr, Cd, Pb, Se, As, Be, Ni), acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate), ammonia and cyanide, elemental C, radionuclides, VOCs, semivolatiles (incl. PAH, polychlorinated dioxins, furans), and aldehydes. Volume 2: Appendices includes process data log sheets, field sampling data sheets, uncertainty calculations, and quality assurance results.

  13. A study of toxic emissions from a coal-fired power plant utilizing an ESP while demonstrating the ICCT CT-121 FGD Project. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-16

    The US Department of Energy is performing comprehensive assessments of toxic emissions from eight selected coal-fired electric utility units. This program responds to the Clean Air Act Amendments of 1990, which require the US Environmental Protection Agency (EPA) to evaluate emissions of hazardous air pollutants (HAPs) from electric utility power plants for Potential health risks. The resulting data will be furnished to EPA utility power plants and health risk determinations. The assessment of emissions involves the collection and analysis of samples from the major input, process, and output streams of each of the eight power plants for selected hazardous Pollutants identified in Title III of the Clean Air Act. Additional goals are to determine the removal efficiencies of pollution control subsystems for these selected pollutants and the Concentrations associated with the particulate fraction of the flue gas stream as a function of particle size. Material balances are being performed for selected pollutants around the entire power plant and several subsystems to identify the fate of hazardous substances in each utility system. Radian Corporation was selected to perform a toxics assessment at a plant demonstrating an Innovative Clean Coal Technology (ICCT) Project. The site selected is Plant Yates Unit No. 1 of Georgia Power Company, which includes a Chiyoda Thoroughbred-121 demonstration project.

  14. Kinetics of coal pyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Seery, D.J.; Freihaut, J.D.; Proscia, W.M. (United Technologies Research Center, East Hartford, CT (USA)); Howard, J.B.; Peters, W.; Hsu, J.; Hajaligol, M.; Sarofim, A. (Massachusetts Inst. of Tech., Cambridge, MA (USA)); Jenkins, R.; Mallin, J.; Espindola-Merin, B. (Pennsylvania State Univ., University Park, PA (USA)); Essenhigh, R.; Misra, M.K. (Ohio State Univ., Columbus, OH (USA))

    1989-07-01

    This report contains results of a coordinated, multi-laboratory investigation of coal devolatilization. Data is reported pertaining to the devolatilization for bituminous coals over three orders of magnitude in apparent heating rate (100 to 100,000 + {degree}C/sec), over two orders of magnitude in particle size (20 to 700 microns), final particle temperatures from 400 to 1600{degree}C, heat transfer modes ranging from convection to radiative, ambient pressure ranging from near vacuum to one atmosphere pressure. The heat transfer characteristics of the reactors are reported in detail. It is assumed the experimental results are to form the basis of a devolatilization data base. Empirical rate expressions are developed for each phase of devolatilization which, when coupled to an awareness of the heat transfer rate potential of a particular devolatilization reactor, indicate the kinetics emphasized by a particular system reactor plus coal sample. The analysis indicates the particular phase of devolatilization that will be emphasized by a particular reactor type and, thereby, the kinetic expressions appropriate to that devolatilization system. Engineering rate expressions are developed from the empirical rate expressions in the context of a fundamental understanding of coal devolatilization developed in the course of the investigation. 164 refs., 223 figs., 44 tabs.

  15. Tracking correction for portable coal inventory instrument

    Science.gov (United States)

    Yang, Deshan; Dong, Lili; Liang, Qianqian; Zhang, Wang; Xu, Wenhai

    2017-03-01

    In the process of measuring the tracking of portable coal inventory instrument, the location accuracy is reduced and the tracking is broken due to float solution of RTK. A tracking correction method based on RTK localization data is proposed. First, the location data of the float solution is filtered by the median filtering algorithm, which reduces the location err and dispersion of the float solution. Then the forward and inverse position estimation is performed by using the fixed solution data before and after the track breakage. The filtering of the float solution positioning data for translation and rotation, make the first point and the end point coincidence with the point estimated. Complete measurement track stitching. In the actual coal inventory experiment, the measurement error is improved from 12.6% to 0.79% after tracking corrected. By using this method we can effectively solve the tracking deviation of actual measurement of coal, improve the portable coal inventory instrument measuring accuracy and adaptability.

  16. Liquefaction of calcium-containing subbituminous coals and coals of lower rank

    Science.gov (United States)

    Gorbaty, Martin L.; Taunton, John W.

    1980-01-01

    A process for the treatment of a calcium-containing subbituminous coal and coals of lower rank to form insoluble, thermally stable calcium salts which remain within the solids portions of the residue on liquefaction of the coal, thereby suppressing the formation scale, made up largely of calcium carbonate deposits, e.g., vaterite, which normally forms within the coal liquefaction reactor (i.e., coal liquefaction zone), e.g., on reactor surfaces, lines, auxiliary equipment and the like. A solution of a compound or salt characterized by the formula MX, where M is a Group IA metal of the Periodic Table of the Elements, and X is an anion which is capable of forming water-insoluble, thermally stable calcium compounds, is maintained in contact with a particulate coal feed sufficient to impregnate said salt or compound into the pores of the coal. On separation of the impregnated particulate coal from the solution, the coal can be liquefied in a coal liquefaction reactor (reaction zone) at coal liquefaction conditions without significant formation of vaterite or other forms of calcium carbonate on reactor surfaces, auxiliary equipment and the like; and the Group IA metal which remains within the liquefaction bottoms catalyzes the reaction when the liquefaction bottoms are subjected to a gasification reaction.

  17. Coal beneficiation by gas agglomeration

    Science.gov (United States)

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  18. Coal catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Kroenig, W.

    1944-02-11

    Some considerations in the selection of a catalyst for the liquid phase of coal hydrogenation are discussed. Some of the previous history of such selections is mentioned. At one stage of the development, the principal catalyst had been iron sulfate (FeSO/sub 4/.7H/sub 2/O). Later, for reasons of cost and availability of large supplies, selections had turned to mixtures of iron sulfate and one or another of some iron oxide- and aluminum oxide-containing byproducts of aluminum manufacture, namely Bayermasse, Luxamsse, or Lautamasse. Much of the discussion centered on optimal proportions for such mixtures, particularly as related to pH values of resulting coal pastes. Upper Silesian coal was more alkaline than Ruhr coal, and Bayermasse, etc., were quite alkaline. Thus, since the iron sulfate served as a partial neutralizer for the coal as well as a catalyst, it seemed necessary to increase the proportions of iron sulfate in the catalyst mixture when processing coal of greater alkalinity. A further reason for a greater proportion of iron sulfate seemed to be that most of the catalytic activity of the iron came from the ferrous iron of iron sulfate rather than from the ferric iron of the other materials. Ferrous-ferric ratios also seemed to indicate that Luxmasse or Lautamasse might be better catalyst components than Bayermasse but their water content sometimes caused handling problems, so Bayermasse had been more widely used. Formation of deposits in the preheater was more likely due to the Bayermasse than to the iron sulfate; sodium sulfide could help to prevent them.

  19. Characterizing toxic emissions from a coal-fired power plant demonstrating the AFGD ICCT Project and a plant utilizing a dry scrubber/baghouse system: Bailly Station Units 7 and 8 and AFGD ICCT Project. Final report. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Dismukes, E.B.

    1994-10-20

    This report describes results of assessment of the risk of emissions of hazardous air pollutants at one of the electric power stations, Bailly Station, which is also the site of a Clean Coal Technology project demonstrating the Pure Air Advanced Flue Gas Desulfurization process (wet limestone). This station represents the configuration of no NO{sub x} reduction, particulate control with electrostatic precipitators, and SO{sub 2} control with a wet scrubber. The test was conducted September 3--6, 1993. Sixteen trace metals were determined along with 5 major metals. Other inorganic substances and organic compounds were also determined.

  20. A study of the interfacial chemistry of pyrite and coal in fine coal cleaning using flotation

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Chengliang [Univ. of Kentucky, Lexington, KY (United States)

    1993-01-01

    Surface oxidation, surface charge, and flotation properties have been systematically studied for coal, coal-pyrite and ore-pyrite. Electrochemical studies show that coal-pyrite exhibits much higher and more complex surface oxidation than ore-pyrite and its oxidation rate depends strongly on the carbon/coal content. Flotation studies indicate that pyrites have no self-induced floatability. Fuel oil significantly improves the floatability of coal and induces considerable flotation for coal-pyrite due to the hydrophobic interaction of fuel oil with the carbon/coal inclusions on the pyrite surface. Xanthate is a good collector for ore-pyrite but a poor collector for coal and coal-pyrite. The results from thermodynamic calculations, flotation and zeta potential measurements show that iron ions greatly affect the flotation of pyrite with xanthate and fuel oil. Various organic and inorganic chemicals have been examined for depressing coal-pyrite. It was found, for the first time, that sodium pyrophosphate is an effective depressant for coal-pyrite. Solution chemistry shows that pyrophosphate reacts with iron ions to form stable iron pyrophosphate complexes. Using pyrophosphate, the complete separation of pyrite from coal can be realized over a wide pH range at relatively low dosage.

  1. The contemporary coal industry: dancing to faster music

    Energy Technology Data Exchange (ETDEWEB)

    Knapp, R. [World Coal Institute, London (United Kingdom)

    1997-09-01

    Within a framework that supports sustainable development, the issues of changing coal markets, environmental policy and climate change, and the positive marketing of coal as a solution to energy demand are discussed. Changes affect both domestic and international markets, and each subset of the market is different. In Europe, coal consumption is declining in contrast with expanding Asian energy markets. Clean coal technologies improve efficiency and make coal more acceptable. The greatest reductions in carbon dioxide emissions can be realized within the least efficient areas of coal consumption, in particular the domestic markets in Asia, eastern Europe, and Africa.

  2. Generating cleaner, cheaper coal power

    Energy Technology Data Exchange (ETDEWEB)

    Hanft, S. [Waste Treatment Technology News (USA)

    2002-05-01

    This paper reports on the development of bio-based and waste materials designed for the removal of flue gas pollutants from coal-fired power plants. Under the US DoE's Biomass Co-Firing Program, the University of North Dakota's Energy and Environmental Research Center has completed a pair of feasibility studies involving biomass (such ash turkey manure, sawdust and wood and finally sunflower hulls) cofiring with lower rank coals. Another project involves cocombusting municipal wood waste and lignite. At Brookhaven National Laboratory's Energy Sciences and Technology Dept., strains of bacteria have been developed to digest sulphur and heavy metals in coal to make it a cleaner burning fuel. A corn-derived activated carbon has been fully tested at a 30 MW co-generation plant in Urbana-Champaign for removing mercury and mercuric chloride from coal combustion flue gases. 6 refs., 3 figs., 1 tab.

  3. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 5, Appendix D: Cost support information: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Sadowski, R.S.; Brown, M.J.; Harriz, J.T.; Ostrowski, E.

    1991-01-01

    The cost estimate provided for the DOE sponsored study of Air Blown Coal Gasification was developed from vendor quotes obtained directly for the equipment needed in the 50 MW, 100 MW, and 200 MW sized plants and from quotes from other jobs that have been referenced to apply to the particular cycle. Quotes were generally obtained for the 100 MW cycle and a scale up/down factor was used to generate the cost estimates for the 200 MW and 50 MW cycles, respectively. Information from GTPro (property of Thermoflow, Inc.) was used to estimate the cost of the 200 MW and 50 MW gas turbine, HRSG, and steam turbines. To available the use of GTPro`s estimated values for this equipment, a comparison was made between the quotes obtained for the 100 MW cycle (ABB GT 11N combustion turbine and a HSRG) against the estimated values by GTPro.

  4. Combustion testing of ceramic coal-water (CWF) atomizers in Unit No. 1 Chatham New Brunswick generating station, final report, baghouse demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Rankin, D.M.

    1986-01-01

    The baghouse demonstration project was undertaken at New Brunswick Power's Chatham thermal generating plant. A number of objectives were outlined: 1) to reduce the particulate in the fuel gas while burning coal water fuel (CWF); 2) to obtain performance data on different fabrics to assist in the selection of filter bags for a CWF demonstration, and, 3) to establish a procedure for operating a baghouse when burning fuel oil, fuel oil and CWF, CWF, and switching between different modes of operation. The demonstration showed that combined firing of CWF and heavy fuel oil can be handled by a baghouse, and indicate that the Nomex fabrix was the most effective of the three tested. Extensive appendices are included. 15 figs., 6 tabs.

  5. Significance and technology of coal mine packing

    Science.gov (United States)

    Wang, Yunliang

    2017-08-01

    Packing is a kind of mining method which is used to fill the goaf with filling material to control the movement of overlying strata and reduce the deformation of the surface. This paper mainly discusses the significance of coal mine packing, and introduces the current method of filling and mining. Finally, the future of coal mine packing is forecasted.

  6. Innovative Clean Coal Technology (ICCT). Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers: Volume 3, Appendices O--T. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    Volume 3 contains the following appendices: Appendix O, Second Series-Manual APH Tests; Appendix P, Third Series-Manual APH Tests; Appendix Q, ABB Analysis of Air Preheaters-Final Report; Appendix R, ABB Corrosion Analysis Study; Appendix S, SRI Waste Stream Impacts Study; and Appendix T, Economic Evaluation.

  7. Development of technical solutions on a coal-fired boiler for a power plant unit of 800 MW with steam parameters of 35 MPa and 700/720°C

    Science.gov (United States)

    Shvarts, A. L.; Verbovetsky, E. Kh.; Somova, E. V.; Smolin, A. V.

    2015-12-01

    Development of a coal-fired boiler for a power plant unit of 800 MW with advanced ultra-supercritical steam parameters of 35 MPa and 700/720°C is presented. The main technical solutions providing the reliability, profitability, and low emissions of harmful substances in the atmosphere are given. The fuel is the black coal of (Taldinskoye field, Kuznetsk basin). The gross efficiency of the boiler is 94%. The U-shaped configuration of a boiler is chosen, which allows the reduction of the capital expenditure for steam turbine piping made of expensive nickel alloys. The horizontal connection flue of the boiler, where the primary and reheat steam screens are located, is equipped with two cold funnels. The upper section of the convection shaft is separated with a vertical screen wall into two parallel "split tail" flues, which allows one to control the reheat steam temperature by redistributing the flue gas between the gas flues. The URS screens are two-stage with a lifting motion of the medium and a partial bypassing of the first stage. The lower radiant section is two-stage. To reduce the temperature of screen walls at the fire chamber outlet, the lowering motion of the working medium and combustion gases is used. The hydrodynamics of the screens with the lowering motion of the medium for preventing the aperiodic instability in the start regimes is analyzed. Besides the stepwise combustion of coal dust providing the improved environmental parameters, the boiler plant is equipped with a selective catalytic reduction (SCR) system, an ash collector (an electric filter combined with a filter bag), and a desulphurization device.

  8. Equilibrium Strategy Based Recycling Facility Site Selection towards Mitigating Coal Gangue Contamination

    Directory of Open Access Journals (Sweden)

    Jiuping Xu

    2017-02-01

    Full Text Available Environmental pollution caused by coal gangue has been a significant challenge for sustainable development; thus, many coal gangue reduction approaches have been proposed in recent years. In particular, coal gangue facility (CGF construction has been considered as an efficient method for the control and recycling of coal gangue. Meanwhile, the identification and selection of suitable CGF sites is a fundamental task for the government. Therefore, based on the equilibrium strategy, a site selection approach under a fuzzy environment is developed to mitigate coal gangue contamination, which integrates a geographical information system (GIS technique and a bi-level model to identify candidate CGF sites and to select the most suitable one. In this situation, the GIS technique used to identify potential feasible sites is able to integrate a great deal of geographical data tofitwithpracticalcircumstances;thebi-levelmodelusedtoscreentheappropriatesitecanreasonably dealwiththeconflictsbetweenthelocalauthorityandthecolliery. Moreover,aKarush–Kuhn–Tucker (KKT condition-based approach is used to find an optimal solution, and a case study is given to demonstrate the effectiveness of the proposed method. The results across different scenarios show that appropriate site selection can achieve coal gangue reduction targets and that a suitable excess stack level can realize an environmental-economic equilibrium. Finally, some propositions and management recommendations are given.

  9. Environmental Justice and Sustainability Impact Assessment: In Search of Solutions to Ethnic Conflicts Caused by Coal Mining in Inner Mongolia, China

    Directory of Open Access Journals (Sweden)

    Lee Liu

    2014-12-01

    Full Text Available The Chinese government adopted more specific and stringent environmental impact assessment (EIA guidelines in 2011, soon after the widespread ethnic protests against coal mining in Inner Mongolia. However, our research suggests that the root of the ethnic tension is a sustainability problem, in addition to environmental issues. In particular, the Mongolians do not feel they have benefited from the mining of their resources. Existing environmental assessment tools are inadequate to address sustainability, which is concerned with environmental protection, social justice and economic equity. Thus, it is necessary to develop a sustainability impact assessment (SIA to fill in the gap. SIA would be in theory and practice a better tool than EIA for assessing sustainability impact. However, China’s political system presents a major challenge to promoting social and economic equity. Another practical challenge for SIA is corruption which has been also responsible for the failing of EIA in assessing environmental impacts of coal mining in Inner Mongolia. Under the current political system, China should adopt the SIA while continuing its fight against corruption.

  10. Atmospheric pollution and heating plants in urban area. What technical solutions for the coal and the heavy oil? For which costs?; Pollution atmospherique et chaufferies en milieu urbain. Quelles solutions techniques pour le charbon et le fioul lourd?. A quel couts?

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-07-01

    In France, furnaces fed with coal and heavy fuel and established in urban area, are bound by many restraints: a reinforcement of the regulations on atmospheric emissions, a strong social demand bound to the urban air quality improvement and a necessary costs mastership. So buildings managers and persons responsible for district heating are confronted with technical and strategical choices. To answer their questions ADEME organized a day of information around four main themes: the urban heating in France, actions on fuels, possible technics for the smokes desulfurization and nitrogen oxides reduction, costs and financing of the solutions. (A.L.B.)

  11. Coal industry annual 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  12. Coal industry annual 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  13. Coal Industry Annual 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  14. Microbial solubilization of coal

    Science.gov (United States)

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  15. Research guidance studies to assess gasoline from coal by methanol-to-gasoline and sasol-type Fischer--Tropsch technologies. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Schreiner, M.

    1978-08-01

    This study provides a technical and economic comparison between the new Mobil methanol-to-gasoline technology under development and the commercially available Fischer--Tropsch technology for the production of motor gasoline meeting U.S. quality standards. Conceptual plant complexes, sited in Wyoming, are complete grass-roots facilities. The Lurgi dry-ash, pressure technology is used to gasify sub-bituminous strip coal. Except for the Mobil process, processes used are commercially available. Coproduction of products, namely SNG, LPG and gasoline, is practiced. Four sensitivity cases have also been developed in less detail from the two base cases. In all areas, the Mobil technology is superior to Fischer--Tropsch: process complexity, energy usage, thermal efficiency, gasoline selectivity, gasoline quality, investment and gasoline selectivity, gasoline quality, investment and gasoline cost. Principal advantages of the Mobil process are its selective yield of excellent quality gasoline with minimum ancillary processing. Fischer--Tropsch not only yields a spectrum of products, but the production of a gasoline meeting U.S. specifications is difficult and complex. This superiority results in about a 25% reduction in the gasoline cost. Sensitivity study conclusions include: (1) the conversion of methanol into gasoline over the Mobil catalyst is highly efficient, (2) if SNG is a valuable product, increased gasoline yield via the reforming of SNG is uneconomical, and (3) fluid-bed operation is somewhat superior to fixed-bed operation for the Mobil methanol conversion technology.

  16. A study of toxic emissions from a coal-fired power plant: Niles Station Boiler No. 2. Volume 1, Sampling/results/special topics: Final report

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    This study was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for US Department of Energy, Pittsburgh Energy Technology Center (DOE-PETC) during 1993. The motivation for those assessments was the mandate in the 1990 Clean Air Act Amendments that a study be made of emissions of hazardous air pollutants (HAPs) from electrical utilities. The results of this study will be used by the US Environmental Protection Agency to evaluate whether regulation of HAPs emissions from utilities is warranted. This report is organized in two volumes. Volume 1: Sampling/Results/Special Topics describes the sampling effort conducted as the basis for this study, presents the concentration data on toxic chemicals in the several power plant streams, and reports the results of evaluations and calculations conducted with those data. The Special Topics section of Volume 1 reports on issues such as comparison of sampling methods and vapor/particle distributions of toxic chemicals. Volume 2: Appendices include field sampling data sheets, quality assurance results, and uncertainty calculations. The chemicals measured at Niles Boiler No. 2 were the following: five major and 16 trace elements, including mercury, chromium, cadmium, lead, selenium, arsenic, beryllium, and nickel; acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate); ammonia and cyanide; elemental carbon; radionuclides; volatile organic compounds (VOC); semivolatile compounds (SVOC) including polynuclear aromatic hydrocarbons (PAH), and polychlorinated dioxins and furans; and aldehydes.

  17. Final design of a superconducting MHD magnet for the Coal-Fired Flow Facility at the University of Tennessee Space Institute

    Energy Technology Data Exchange (ETDEWEB)

    Wang, S T; Turner, L R; Genens, L; Pelczarski, W; Hoffman, J; Gonczy, J; Ludwig, H; Niemann, R C; Mataya, K; Kraft, E

    1979-01-01

    The superconducting magnet system (SCMS) consisting of the superconducting magnet, magnet cryostat, a helium refrigerator/liquefier facility, a helium gas-handling system, apparatus for cryogenic transfer and storage, a magnet power supply, a integrated instrumentation and control system including a computer for magnet operation, data acquisition, system status and diagnosis, and magnet protection is described. The complete system will be tested at Argonne and installed at the Coal-Fired Flow Facility (CFFF) at the University of Tennessee Space Institute (UTSI) in 1981. The coil configuration is the US SCMS type circular saddle. The coil wil be assembled on the magnet tube with spiral banding. The bore tube will be about 6.3 cm thick (in the thickest section) and the banding will be strong enough for coil assembly but too weak to transmit the 30,180 kgf/cm maximum burst force to the bore tube. Fifteen ring girders will be used as the superstructure to contain the force. The decentering force of about 0.2177 x 10/sup 6/ kgf will be taken up by end flanges and bore tubes.

  18. Safer blasting agents and procedures for blasting in gassy non-coal mines. Final report, September 9, 1990--December 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-01

    Hundreds of tests have been conducted in the Bureau`s Lake Lynn Laboratory Cannon Gallery to evaluate the incendivity characteristics of both commercially available and experimental explosive products. The cannon gallery test results have clearly identified several lower incendive explosives that can and have significantly reduced the gas and/or dust ignition hazards associated with blasting in non-coal mines. Several of the lower incendive explosive formulations have undergone full-scale field evaluations and, to date, had been very successful in preventing ignitions in base metal mines with high sulphur-bearing ore. Tests in the cannon gallery have shown that an inert gelled water material outperforms most other stemming agents in preventing the ignition of flammable gases and/or combustible dusts outside of the bore. A new water stemming plug was evaluated in the cannon gallery and shown to be a very effective stemming device. As a means to better evaluate explosive incendivity, the initial development of two instrument sensors are underway. A fiber optic rate probe has been redesigned to accurately measure the detonation velocity of explosives in the cannon bore. A photometric sensor is also under development to measure the peak temperatures of the detonation products exiting the bore. This report discusses the results of the research program including the test apparatus and procedures and summarizes the incendivity data obtained from the various explosives. Results from the full-scale field testing of the lower incendive products in an operating mine are then presented.

  19. Ultrafine calcium aerosol: Generation and use of a sorbent for sulfur in coal combustion. Volume 2, Economics: Final report, August 1, 1988--October 31, 1991

    Energy Technology Data Exchange (ETDEWEB)

    Alam, M.K.; Nahar, N.U.; Stewart, G.D.; Prudich, M.E. [comps.] [Ohio Coal Research Center, Athens, OH (United States)

    1991-11-01

    The goal of this study is to determine the cost effectiveness of using calcium-hydroxide powder sorbent in a commercial power plant flue gas desulfurization (FGD) application. The cost analysis methodology found herein is a direct application of the one found in the January 1986 report, ``Economic Evaluation of Dry-Injection Flue Gas Desulfurization Technology by the Electric Power Research Institute (EPRI). The EPRI study addresses the economic issue of installing a dry-injection FGD system on a 1000 MW (2-500 MW units) power plant using sodium-rich powder sorbents derived from nahcolite and trona ores. In this report`s treatment, the calcium-based derivatives of hydrated limestone are compared directly to nahcolite and trona for both low and high sulfur coals. This type of evaluation is allowable due to the similar material handling properties of 1/4 inch hydrated limestone in comparison to those properties for nahcolite and trona. Thus, this report repeats the EPRI cost analysis for a slightly modified limestone-based FGD design. Note that the calculation methodology is not discussed, in this report as it has already been outlined in the EPRI study. Instead, Appendices A and B contain copies of the calculation spreadsheets based on the EPRI method for the hydrated limestone system.

  20. The effects of halides on the performance of coal gas-fueled molten carbonate fuel cells: Final report, October 1986-October 1987

    Energy Technology Data Exchange (ETDEWEB)

    Magee, T.P.; Kunz, H.R.; Krasij, M.; Cote, H.A.

    1987-10-01

    This report presents the results of a program to determine the probable tolerable limits of hydrogen chloride and hydrogen fluoride present in the fuel and oxidant streams of molten carbonate fuel cells that are operating on gasified coal. A literature survey and thermodynamic analyses were performed to determine the likely effects of halides on cell performance and materials. Based on the results of these studies, accelerated corrosion experiments and electrode half-cell performance tests were conducted using electrolyte which contained chloride and fluoride. These data and the results of previous in-cell tests were used to develop a computer for predicting the performance decay due to these halides. The tolerable limits were found to be low (less than 1 PPM) and depend on the power plant system configuration, the operating conditions of the fuel cell stack, the cell design and initial electrolyte inventory, and the ability of the cell to scrub low levels of halide from the reactant streams. The primary decay modes were conversion of the electrolyte from pure carbonate to a carbonate-halide mixture and accelerated electrolyte evaporation. 75 figs., 16 tabs.

  1. Environmental protection during coal mining

    Energy Technology Data Exchange (ETDEWEB)

    Tkachenko, N.G.; Vavilin, V.P.; Reznikov, I.G.; Perel' , Eh.P.; Kirilenko, V.M.

    1983-03-01

    The paper evaluates effects of surfactants used in underground coal mining for dust suppression on efficiency of water treatment and on mine water pollution. Two surfactant types are compared: conventional surfactants such as BD, OP-7 or OP-10 and a new generation of soft surfactants which do not have a negative influence on water treatment systems (active sludge, nitrification process, etc.). The results of tests carried out by the KGMI Institute and the VNIIPAV Institute are discussed. About 100 surfactants of both types were evaluated. Coal samples of the following coal types were used: PZh, Zh, G, K, A, T and D coal. Coal samples with grain size from 0.315 mm to 0.4 mm were wet by surfactant solutions in water. The following surfactant concentrations were used: 0.001, 0.005, 0.01, 0.05, 0.1 and 0.5 g/l. Fresh water and mine water with increased mineral content was used. Selected results of the experiments aimed at determining the optimum surfactants for use in underground coal mining are shown in a table. The following surfactants are described: secondary alkyl sulfates (of the 'Progress' type), diethanolamides, monoethanolamides, alkyl sulfonates, Avirol', Savo, Sintanol DC-10, etc.

  2. Specific Energy of Hard Coal Under Load

    Science.gov (United States)

    Bogusz, Anna; Bukowska, Mirosława

    2015-03-01

    The article presents results of experimental tests of energy parameters of hard coals under loading, collected from research sites located within five main geologic structures of Upper Silesian Coal Basin (GZW) - Main Trough, Main Anticline, Bytom Trough, Rybnik Trough and Chwałowice Trough. Coals from12 mines were analysed, starting with seams of group 200, through groups 400, 500, 600 and, finally, seams of group 700. Coal of each of the groups of seams underwent uniaxial compression stress of the energy parameters, in a servo-controlled testing machine MTS-810NEW, for the full range of strain of the tested coal samples. Based on the tests the dependence of different types of specific energy of longitudinal strain of coals on the value of uniaxial compression strength was determined. The dependence of the value of dissipated energy and kinetic energy of coals on the uniaxial compression strength was described with a linear function, both for coals which due to their age belong to various bed sand for various lithotypes of coal. An increase in the value of dissipated energy and in kinetic energy was observed, which was correlated with an increase in uniaxial compression strength of coal. The share of dissipated energy is dominant in the total energy of strain. Share of recoverable energy in the total energy of strain is small, independent of the compression strength of coals and is at most a few per cent high. In coals of low strength and dominant share of dissipated energy, share of recoverable energy is the biggest among the tested coals. It was shown that following an increase in compression strength the share of recoverable energy decreases, while the share of dissipated energy in the total energy increases. Further studies of specific energy of longitudinal strain of rocks in the full-range strain will be the next step inperfecting methodology of research into natural rock burst susceptibility of Carboniferous rock mass and changes in the susceptibility

  3. Phase behavior of coal fluids: Data for correlation development

    Energy Technology Data Exchange (ETDEWEB)

    Robinson, R.J. Jr.; Gasem, K.A.M.; Shaver, R.D.

    1990-01-01

    The effective design and operation of processes for conversion of coal to fluid fuels requires accurate knowledge of the phase behavior of the fluid mixtures encountered in the conversion process. The overall objective of the author's work is to develop accurate predictive methods for representation of vapor-liquid equilibria in systems encountered in coal conversion processes. The objectives of the present project include: (1) measurements of binary vapor-liquid phase behavior data for selected solute gases (e.g. CO{sub 2} and C{sub 2}H{sub 6}) in a series of heavy hydrocarbon solvents to permit evaluation of interaction parameters in models for phase behavior, (2) measurements on ternary systems in which high-melting-point solvents are dissolved in more volatile aromatics to provide mixed solvents, (3) evaluation of existing equations-of-state and other models for representation of phase behavior in systems of the type studied experimentally; development of new correlation frameworks as needed, and (4) generalization of the interaction parameters for the solutes studied to a wide spectrum of heavy solvents; presentations of final results in formats useful in the design/optimization of coal liquefaction processes. This quarter, our framework for correlating saturation properties using a scaled-variable-reduced-coordinate'' approach was further developed to provide for generalized vapor pressure predictions. 59 refs., 6 figs., 8 tabs.

  4. Coal industry annual 1993

    Energy Technology Data Exchange (ETDEWEB)

    1994-12-06

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  5. Shale Failure Mechanics and Intervention Measures in Underground Coal Mines: Results From 50 Years of Ground Control Safety Research

    Science.gov (United States)

    Murphy, M. M.

    2016-02-01

    Ground control research in underground coal mines has been ongoing for over 50 years. One of the most problematic issues in underground coal mines is roof failures associated with weak shale. This paper will present a historical narrative on the research the National Institute for Occupational Safety and Health has conducted in relation to rock mechanics and shale. This paper begins by first discussing how shale is classified in relation to coal mining. Characterizing and planning for weak roof sequences is an important step in developing an engineering solution to prevent roof failures. Next, the failure mechanics associated with the weak characteristics of shale will be discussed. Understanding these failure mechanics also aids in applying the correct engineering solutions. The various solutions that have been implemented in the underground coal mining industry to control the different modes of failure will be summarized. Finally, a discussion on current and future research relating to rock mechanics and shale is presented. The overall goal of the paper is to share the collective ground control experience of controlling roof structures dominated by shale rock in underground coal mining.

  6. Enthalpy measurement of coal-derived liquids. Final technical progress report. [200 to 740/sup 0/F and 200 to 1500 psia

    Energy Technology Data Exchange (ETDEWEB)

    Kidnay, A.J.; Yesavage, V.F.

    1981-05-01

    This final report presents the results of the enthalpy measurements on the model compound m-cresol. The measurements cover the temperature range 200 to 740/sup 0/F and the pressure range 200 to 1500 psia. These data are compared with earlier data taken on m-cresol and with other thermophysical properties taken from the literature.

  7. Coal pillar design procedures

    CSIR Research Space (South Africa)

    York, G

    2000-03-01

    Full Text Available Final Project Report Coal pillar design procedures G. York, I. Canbulat, B.W. Jack Research agency: CSIR Mining Technology Project number: COL 337 Date: March 2000 2 Executive Summary Examination of collapsed pillar cases outside of the empirical... in strength occurs with increasing specimen size. 45 40 35 30 25 20 15 10 5 0 20 40 60 80 100 120 140 160 UNIAX IA L COMPR EHEN SIV E S TR ENG TH (M Pa ) CUBE SIZE (cm) Figure 1...

  8. 75 FR 56124 - Notice of Issuance of Final Determination Concerning APC InfraStruXure® Solutions and of Certain...

    Science.gov (United States)

    2010-09-15

    ... enclosures/assemblies have a strong focus on cooling, power distribution, cable management, and environmental... non-racked IT loads as well as a flexible, assemble-to- order solution that provides variable fan... processes involving sheet metal work, soldering, brazing, and welding. The units use firmware developed and...

  9. Rapid pyrolysis of Serbian soft brown coals

    Energy Technology Data Exchange (ETDEWEB)

    Goran G. Jankes; Olga Cvetkovic; Nebojsa M. Milovanovic; Marko Ercegovaci Ercegovac; Miroljub Adzic; Mirjana Stamenic [University of Belgrade, Belgrade (Serbia). Faculty of Mechanical Engineering

    2009-07-01

    Soft brown coals of the open coal fields of Kolubara and Kostolac are the main domestic energy sources of Serbia. This paper presents the results of investigations on rapid devolatilization of these two coals which have covered kinetics of devolatilization (based on total volatile yield), forms of sulphur and petrographic analysis of coal and char. Experiments of devolatilization were performed in inert gas (N{sub 2}) at atmospheric pressure and in batch-type hot-wire screen reactor. The mass-loss values of both coals at selected final reaction temperatures (300-900{sup o}C) and retention times (3-28 s) were obtained. Anthony and Howard's kinetic model was applied over two temperature ranges (300-500 and 700-900{sup o}C). The types of sulphur as monosulphide, sulphate, pyritic, and organic sulphur were determined for chars and original coals. Strong transformation of pyrite was evident even at low temperatures (300{sup o}C). Devolatilization of all types of sulphur has started over 600 and at 900{sup o}C the content of sulphur in char remained only 66% of total sulphur in original coal. Microscopic investigations were carried out on samples prepared for reflected light measurements. The petrographic analysis included: the ratio of unchanged and changed coal, maceral types, the share of cenospheres, isotropic mixed carbonized grains, mixed grains, small fragments, clay, and pyrite. The change of the structure of devolatilized coal was also observed. 20 refs., 10 figs., 6 tabs.

  10. Rapid pyrolysis of Serbian soft brown coals

    Directory of Open Access Journals (Sweden)

    Jankes Goran

    2009-01-01

    Full Text Available Soft brown coals of the open coal fields of Kolubara and Kostolac are the main domestic energy sources of Serbia. This paper presents the results of investigations on rapid devolatilization of these two coals which have covered kinetics of devolatilization (based on total volatile yield, forms of sulphur and petrographic analysis of coal and char. Experiments of devolatilization were performed in inert gas (N2 at atmospheric pressure and in batch-type hot-wire screen reactor. The mass-loss values of both coals at selected final reaction temperatures (300-900°C and retention times (3-28 s were obtained. Anthony and Howard's kinetic model was applied over two temperature ranges (300-500 and 700-900°C. The types of sulphur as monosulphide, sulphate, pyritic, and organic sulphur were determined for chars and original coals. Strong transformation of pyrite was evident even at low temperatures (300°C. Devolatilization of all types of sulphur has started over 600 and at 900°C the content of sulphur in char remained only 66% of total sulphur in original coal. Microscopic investigations were carried out on samples prepared for reflected light measurements. The petrographic analysis included: the ratio of unchanged and changed coal, maceral types, the share of cenosferes, isotropic mixed carbonized grains, mixed grains, small fragments, clay, and pyrite. The change of the structure of devolatilized coal was also observed.

  11. Radioactivity of coals and ash and slag wastes at coal-fired thermal power plants

    Science.gov (United States)

    Krylov, D. A.; Sidorova, G. P.

    2013-04-01

    This paper presents an analysis of published data on the content of radioactive nuclides in coals originating from various coal deposits, and in ash and slag wastes produced at coal-fired thermal power plants, as well as in fly ash emitted from thermal power plants into the atmosphere. Problems related to the use of coals with an elevated content of natural radionuclides (NRNs) and methods of their solution implemented at the Urtuyskoe coalfield are dealt with. Data on the analysis of Transbaikal coals for the NRN content, as well as weighted mean content of uranium and thorium in coals from the Siberian Region, are given. In order to reduce irradiation of plant personnel and the population of the areas where coal producers and coal-fired thermal power plants are located, it is necessary to organize very careful control of the NRN content in both coals and products of their combustion that are released into the environment. To solve the problem related to the control of radioactivity, the centralized approach and creation of a proper normative base are needed. Experience gained in developing the Urtuyskoe coalfield shows that it is possible to create an efficient system of coal quality control with respect to the radiation hygiene factor and provide protection of the environment and health of the population.

  12. Coal liquefaction

    Science.gov (United States)

    Schindler, Harvey D.

    1985-01-01

    In a two-stage liquefaction wherein coal, hydrogen and liquefaction solvent are contacted in a first thermal liquefaction zone, followed by recovery of an essentially ash free liquid and a pumpable stream of insoluble material, which includes 850.degree. F.+ liquid, with the essentially ash free liquid then being further upgraded in a second liquefaction zone, the liquefaction solvent for the first stage includes the pumpable stream of insoluble material from the first liquefaction stage, and 850.degree. F.+ liquid from the second liquefaction stage.

  13. Development of a ceramic heat exchanger for a combined cycle plant with pressurized coal dust combustion. Final report; Entwicklung eines keramischen Waermeaustauschers fuer eine Kombianlage mit Kohlenstaubdruckfeuerung. Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Leithner, R.; Ehlers, C.

    2001-12-01

    State of Research: The Pressurized Pulverized Coal Combustion Combined Cycle (PPCCCC) with a directly fired gas turbine can reach electrical efficiencies beyond 50%. The required gas quality upstream the gas turbine has not been reached yet at temperatures above 1000 C. One approach tested is the precipitation of ash and alkalines at temperatures above the ash melting point. This principle contains problems concerning the remaining content of ash and alkalines in the flue gas and damages to the refractory materials due to corrosion. Goal of the Investigation: An alternative process had to be investigated in which the flue gas is cleaned according to the state of the art, i.e. below the ash fusion temperature. This principle requires cooling down the flue gas and heating it up again after cleaning in a high temperature heat exchanger. Method: A ceramic tube-and-shell heat exchanger in a model scale was designed and was operated at realistic conditions in an atmospheric test plant in connection with a high temperture precipitation. Result: The heat exchanger showed a good performance concerning design and material. The expected temperatures were not reached totally because of untight joints. Clogging occurred in the tube entrances at high temperatures because of sintered ash agglomerates. First tests to clean the entrances during operation showed positive results. The ash precipitation by means of a cyclone and ceramic filter candles was performed without difficulties. Conclusion: Avoiding and improving joints will help to achieve higher temperatures. A process of cleaning the tubes in-line has to be introduced to prevent the clogging effects. If this is successfully done for high temperatures, an attractive principle for a PPCCCC-process is available which reaches the gas purity required. (orig.) [German] Derzeitiger Stand der Forschung: Der Kohlenstaubdruckfeuerungs-Kombiprozess mit direkt befeuerter Gasturbine verspricht elektrische Wirkungsgrade ueber 50%. Die

  14. Discussion on Wastewater Treatment Process of Coal Chemical Industry

    Science.gov (United States)

    Zhao, Dongyan; Lun, Weijie; Wei, Junjie

    2017-12-01

    Coal chemical wastewater has such characteristics as high concentration of oil, ammonia nitrogen and COD. In this paper, treatment process of coal chemical industry is described mainly, such as pretreatment process, biochemical treatment process and polishing process. Through the recovery of phenol and ammonia and the treatment of wastewater from abroad, the new technology of wastewater treatment in coal chemical industry was expounded. Finally, The development of coal chemical wastewater treatment technology is prospected, and the pretreatment technology is emphasized. According to the diversification and utilization of water, zero discharge of coal chemical wastewater will be fulfilled.

  15. Coal in Italy `would double but for environmentalists and politics`

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-04-01

    Italy is the real Cinderella among coal users for electricity generation, gaining first prize on the international stage for squandering L1000 bn of energy annually, using gas instead of coal. Much of the reason for this is environmentalist objections to coal-fired plant. Coal is bought by ENEL on small long-term contracts - ensuring a diversity of supply. This could change, if and when the privatisation of ENEL finally takes place. Other consumers of imported coal include the cement industry, the steel industry and possibly independent power producers. 2 figs.

  16. Biotechnology and microbiology of coal degradation

    Energy Technology Data Exchange (ETDEWEB)

    Fakoussa, R.M. [Inst. fuer Mikrobiologie and Biotechnologie, Rheinische Friedrich-Wilhelms-Univ. Bonn, Bonn (Germany); Hofrichter, M. [Inst. fuer Mikrobiologie, Friedrich Schiller-Univ. Jena, Jena (Germany)

    1999-07-01

    For several years it has been known that fungi and bacteria can attack and even liquefy low rank coals. This review covers the progress in coal biotechnology and microbiology, mainly during the last decade, from describing the first effects to elucidating the mechanisms used by the microorganisms. More than one mechanism is responsible for microbial coal degradation/liquefaction: oxidative enzymes (peroxidases, laccases), hydrolytic enzymes (esterases), alkaline metabolites and natural chelators. Due to the heterogeneous structure of coal, which is described in one section, and for economic reasons the review focuses on the enzymatic depolymerization of brown coal. Approaches which seem not so promising are discussed (anaerobic, reductive pathways, chemical pretreatment). Finally the possible applications and products in this field are summarized, as lignite with a worldwide production of about 940 million tons a year will continue to play an important economic role in the future. (orig.)

  17. COAL Conference Poster

    OpenAIRE

    Brown, Taylor Alexander; McGibbney, Lewis John

    2017-01-01

    COAL Conference Poster This archive contains the COAL conference poster for the AGU Fall Meeting 2017 by Taylor Alexander Brown. The Inkscape SVG source is available at https://github.com/capstone-coal/coal-conference-poster/ under the Creative Commons Attribution-ShareAlike 4.0 International license.

  18. Analytical support for coal technologies

    Directory of Open Access Journals (Sweden)

    Valášek Václav

    1998-09-01

    Full Text Available On the basis of success in the selection negotiation The Brown Coal Research Institute j.s.c. Most was authorized to process the project Phare D5/93 with the title "Analytical support to clean coal technologies". The elaboration of the task run in 1997 in a close cooperation with the Mining University - TU Ostrava; DBI - AUA GmbH, Freiberg, Germany; DMT mbH, Essen, Germany and Cerchar, Mazingarbe, France. In the work the available reserves of brown and hard coal and from them following possible levels of annual minings in relation to prognosed needs of the electro-energetics and heating-industry were evaluated. The knowledge about the contents of selected trace elements (As, Be, Cd, Cl, Co, Cr, Cu, F, Hg, Mn, Ni, Pb, Sb, Se, Te, Tl, V, Zn in Czech (CZ coal were also evaluated it was investigated. Further, the distribution of trace elements during the burning process in four types of boilers in CZ. was investigated. The CZ and EU legislation related to trace elements in coal and combustion products was finally comparred. It was stated that the CZ legal standards are not at variant with EU the standards.

  19. Final report on LDRD project: A phenomenological model for multicomponent transport with simultaneous electrochemical reactions in concentrated solutions

    Energy Technology Data Exchange (ETDEWEB)

    CHEN,KEN S.; EVANS,GREGORY H.; LARSON,RICHARD S.; NOBLE,DAVID R.; HOUF,WILLIAM G.

    2000-01-01

    A phenomenological model was developed for multicomponent transport of charged species with simultaneous electrochemical reactions in concentrated solutions, and was applied to model processes in a thermal battery cell. A new general framework was formulated and implemented in GOMA (a multidimensional, multiphysics, finite-element computer code developed and being enhanced at Sandia) for modeling multidimensional, multicomponent transport of neutral and charged species in concentrated solutions. The new framework utilizes the Stefan-Maxwell equations that describe multicomponent diffusion of interacting species using composition-insensitive binary diffusion coefficients. The new GOMA capability for modeling multicomponent transport of neutral species was verified and validated using the model problem of ternary gaseous diffusion in a Stefan tube. The new GOMA-based thermal battery computer model was verified using an idealized battery cell in which concentration gradients are absent; the full model was verified by comparing with that of Bernardi and Newman (1987) and validated using limited thermal battery discharge-performance data from the open literature (Dunning 1981) and from Sandia (Guidotti 1996). Moreover, a new Liquid Chemkin Software Package was developed, which allows the user to handle manly aspects of liquid-phase kinetics, thermodynamics, and transport (particularly in terms of computing properties). Lastly, a Lattice-Boltzmann-based capability was developed for modeling pore- or micro-scale phenomena involving convection, diffusion, and simplified chemistry; this capability was demonstrated by modeling phenomena in the cathode region of a thermal battery cell.

  20. Volume and accessibility of entrained (solution) methane in deep geopressured reservoirs - tertiary formations of the Texas Gulf Coast. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Gregory, A.R.; Dodge, M.M.; Posey, J.S.; Morton, R.A.

    1980-10-01

    The objective of this project was to appraise the total volume of in-place methane dissolved in formation waters of deep sandstone reservoirs of the onshore Texas Gulf Coast within the stratigraphic section extending from the base of significant hydrocarbon production (8000 ft)* to the deepest significant sandstone occurrence. The area of investigation is about 50,000 mi/sup 2/. Factors that determine the total methane resource are reservoir bulk volume, porosity, and methane solubility; the latter is controlled by the temperature, pressure, and salinity of formation waters. Regional assessment of the volume and the distribution of potential sandstone reservoirs was made from a data base of 880 electrical well logs, from which a grid of 24 dip cross sections and 4 strike cross sections was constructed. Solution methane content in each of nine formations or divisions of formations was determined for each subdivision. The distribution of solution methane in the Gulf Coast was described on the basis of five reservoir models. Each model was characterized by depositional environment, reservoir continuity, porosity, permeability, and methane solubility.

  1. Steam coal forecaster

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    This quarterly forecasting service provides a short-term analysis and predictions of the international steam coal trade. Sections are entitled: market review; world steam coal at a glance; economics/foreign exchange; demand (reviewing the main purchasing companies country-by-country); supply (country-by-country information on the main producers of steam coal); and freight. A subscription to Steam Coal Forecaster provides: a monthly PDF of McCloskey's Steam Coal Forecaster sent by email; access to database of stories in Steam Coal Forecaster via the search function; and online access to the latest issue of Steam Coal.

  2. Modeling the international competitiveness of Botswana's coal

    Science.gov (United States)

    Fichani, Khaulani

    Botswana has vast proven deposits of steam coal, which for a long time it has wanted to develop but without much success. The main objectives of this study are: (1) to analyze the time schedule of coal exports likely to be forthcoming from Botswana and the land routes for these exports; (2) to determine the competitiveness of Botswana's coal in the world steam coal markets and (3) to make recommendations on the appropriate policy for the exploitation of this coal. To accomplish these objectives, we construct a model of the seaborne steam coal trade consisting of exporters and importers with a substantial share in this trade. We econometrically estimate the long run marginal cost functions for net exporters and employ these to construct a spatial and dynamic model of the world steam coal trade with elastic supply and inelastic demand. This model is applied to simulate Botswana's competitiveness in this trade over the period 1995 to 2010 from a 1990 base year with a decision criterion that minimizes the sum of discounted capital costs of mine development, variable supply costs, rail and maritime transportation costs. Finally, we employ the model to forecast the likely optimal size of mine, timing of production capacity and choice of export port for Botswana's coal for the years 2005 and 2010. The base year for the forecast is 2000. The simulation results indicate that Botswana's coal would have been competitive in the steam coal markets of Western Europe and Asia. The forecast results indicate that Botswana's coal would also be competitive in these markets in the future. These results are least sensitive to changes in rail transportation and variable supply costs but are sensitive to capital costs for mine development.

  3. Unioned layer of coal resource calculation in the southern Piceance Basin, Colorado (ps*fing)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — These are shapefiles and coverages of final unioned polygon coverages used to calculate coal resources of the Cameo/Fairfield coal group east of 107 deg 15'...

  4. Coal data: A reference

    Energy Technology Data Exchange (ETDEWEB)

    1995-02-01

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  5. China's Coal: Demand, Constraints, and Externalities

    Energy Technology Data Exchange (ETDEWEB)

    Aden, Nathaniel; Fridley, David; Zheng, Nina

    2009-07-01

    This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of

  6. Coal and clean coal technology: challenges and opportunities

    Energy Technology Data Exchange (ETDEWEB)

    Minchener, Andrew [IEA Clean Coal Centre, London (United Kingdom)

    2013-07-01

    Globally, there is a growing concern about fuel diversity and security of supply, particularly with regard to oil and natural gas. In contrast, coal is available from a much wider range of sources and has greater price stability. Consequently, coal use is increasing rapidly, and by 2030 may well reach a level of more than 4,500 Mtoe, corresponding to close to a doubling of current levels. However, at the same time, tightening regulations will require better solutions for achieving environmental compliance, for which coal has a number of key issues to address. Most of the coal will be used in the power generation sector. Consequently, the key research challenges are to develop and deploy methods by which coal can be used cleanly, efficiently, and in a sustainable way. These include improvements to existing coal utilisation technologies, particularly to improve operational flexibility and availability, while reducing energy use through higher efficiencies. There is an increasing need to ensure improved emissions control, with the emphasis on achieving ever-lower emissions of particulates, SO{sub 2} and NO{sub x} while also introducing control of trace species, particularly mercury. Alongside this, a key challenge is the integration of techniques that can capture CO{sub 2} then transport and store it within secure geological formations, thereby resulting in near zero emissions of CO{sub 2}. From a power plant perspective, the need is to achieve such integration while minimising any adverse impact on power plant efficiency, performance of existing emissions control systems, operational flexibility and availability. At the same time, means to minimize the additional costs associated with such technology must be established.

  7. Final LDRD report : science-based solutions to achieve high-performance deep-UV laser diodes.

    Energy Technology Data Exchange (ETDEWEB)

    Armstrong, Andrew M.; Miller, Mary A.; Crawford, Mary Hagerott; Alessi, Leonard J.; Smith, Michael L.; Henry, Tanya A.; Westlake, Karl R.; Cross, Karen Charlene; Allerman, Andrew Alan; Lee, Stephen Roger

    2011-12-01

    We present the results of a three year LDRD project that has focused on overcoming major materials roadblocks to achieving AlGaN-based deep-UV laser diodes. We describe our growth approach to achieving AlGaN templates with greater than ten times reduction of threading dislocations which resulted in greater than seven times enhancement of AlGaN quantum well photoluminescence and 15 times increase in electroluminescence from LED test structures. We describe the application of deep-level optical spectroscopy to AlGaN epilayers to quantify deep level energies and densities and further correlate defect properties with AlGaN luminescence efficiency. We further review our development of p-type short period superlattice structures as an approach to mitigate the high acceptor activation energies in AlGaN alloys. Finally, we describe our laser diode fabrication process, highlighting the development of highly vertical and smooth etched laser facets, as well as characterization of resulting laser heterostructures.

  8. Understanding Long-Term Solute Transport in Sedimentary Basins: Simulating Brine Migration in the Alberta Basin. Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Alicia M. Wilson

    2009-11-30

    Mass transport in deep sedimentary basins places important controls on ore formation, petroleum migration, CO2 sequestration, and geochemical reactions that affect petroleum reservoir quality, but large-scale transport in this type of setting remains poorly understood. This lack of knowledge is highlighted in the resource-rich Alberta Basin, where geochemical and hydrogeologic studies have suggested residence times ranging from hundreds of millions of years to less than 5 My, respectively. Here we developed new hydrogeologic models that were constrained by geochemical observations to reconcile these two very different estimates. The models account for variable-density fluid flow, heat transport, solute transport, sediment deposition and erosion, sediment compressibility, and dissolution of salt deposits, including Cl/Br systematics. Prior interpretations of Cl/Br ratios in the Alberta Basin concluded that the brines were derived from evaporatively-concentrated brines that were subsequently diluted by seawater and freshwater; models presented here show that halite dissolution must have contributed strongly as well, which implies significantly greater rates of mass transport. This result confirms that Cl/Br ratios are subject to significant non-uniqueness and thus do not provide good independent indicators of the origin of brines. Salinity and Cl/Br ratios provided valuable new constraints for basin-scale models, however. Sensitivity studies revealed that permeabilities obtained from core- and field-scale tests were appropriate for basin-scale models, despite the differences in scale between the tests and the models. Simulations of groundwater age show that the residence time of porefluids in much of the basin is less than 100 My. Groundwater age increases with depth and approaches 200 My in the deepest part of the basin, but brines are significantly younger than their host rocks throughout the basin.

  9. Technical support for the Ohio Clean Coal Technology Program. Volume 2, Baseline of knowledge concerning process modification opportunities, research needs, by-product market potential, and regulatory requirements: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L. [Battelle, Columbus, OH (United States)

    1989-08-28

    This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LR1 and comprises two volumes. Volume 1 presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume 2 consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

  10. Coal desulfurization process

    Science.gov (United States)

    Hsu, G. C.; Gavalas, G. R.; Ganguli, P. S.; Kalfayan, S. H.

    1978-01-01

    A method for chlorinolysis of coal is an organic solvent at a moderate temperautre and atmospheric pressure has been proven to be effective in removing sulfur, particularly the organic sulfur, from coal. Chlorine gas is bubbled through a slurry of moist coal in chlorinated solvent. The chlorinated coal is separated, hydrolyzed and the dechlorinated. Preliminary results of treating a high sulfutr (4.77%S) bituminous coal show that up to 70% organic sulfur, 90% hyritic sulfur and 76% total sulfur can be removed. The treated coal is dechlorinated by heating at 500 C. The presence of moisture helps to remove organic sulfur.

  11. Sustainable Energy Solutions Task 4.2: UV Degradation Prevention on Fiber-Reinforced Composite Blades. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Twomey, Janet M. [Wichita State Univ., KS (United States)

    2010-03-01

    Use of wind energy has expanded very quickly because of the energy prices, environmental concerns and improved efficiency of wind generators. Rather than using metal and alloy based wind turbine blades, larger size fiber (glass and carbon) reinforced composite blades have been recently utilized to increase the efficiency of the wind energy in both high and low wind potential areas. In the current composite manufacturing, pre-preg and vacuum-assisted/heat sensitive resin transfer molding and resin infusion methods are employed. However, these lighter, stiffer and stronger composite blades experience ultraviolet (UV) light degradation where polymers (epoxies and hardeners) used for the blades manufacturing absorb solar UV lights, and cause photolytic, thermo-oxidative and photo-oxidative reactions resulting in breaking of carbon-hydrogen bonds, polymer degradation and internal and external stresses. One of the main reasons is the weak protective coatings/paints on the composite blades. This process accelerates the aging and fatigue cracks, and reduces the overall mechanical properties of the blades. Thus, the lack of technology on coatings for blade manufacturing is forcing many government agencies and private companies (local and national windmill companies) to find a better solution for the composite wind blades. Kansas has a great wind potential for the future energy demand, so efficient wind generators can be an option for continuous energy production. The research goal of the present project was to develop nanocomposite coatings using various inclusions against UV degradation and corrosion, and advance the fundamental understanding of degradation (i.e., physical, chemical and physiochemical property changes) on those coatings. In pursuit of the research goal, the research objective of the present program was to investigate the effects of UV light and duration on various nanocomposites made mainly of carbon nanotubes and graphene nanoflakes, contribute the

  12. Efficient direct coal liquefaction of a premium brown coal catalyzed by cobalt-promoted fumed oxides

    Energy Technology Data Exchange (ETDEWEB)

    Trautmann, M.; Loewe, A.; Traa, Y. [Stuttgart Univ. (Germany). Inst. of Chemical Technology

    2013-11-01

    The search for alternatives in the fuel sector is an important technological challenge. An interim solution could be provided by direct coal liquefaction. Hydrogen economy and the lack of an efficient catalyst are the main obstacles for this process. We used a premium German brown coal with a high H/C molar ratio of 1.25 and nanostructured cobalt catalysts to improve the efficiency of direct coal liquefaction. We were able to recover and recycle the catalyst efficiently and reached good brown coal conversions and oil yields with single-stage coal liquefaction. The oil quality observed almost reached that of a conventional crude oil considering higher heating value (HHV), H/C molar ratio and aliphatic content. (orig.)

  13. International perspectives on coal preparation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  14. Supercritical fluid thermodynamics for coal processing

    Energy Technology Data Exchange (ETDEWEB)

    van Swol, F. (Illinois Univ., Urbana, IL (United States). Dept. of Chemical Engineering); Eckert, C.A. (Georgia Inst. of Tech., Atlanta, GA (United States). School of Chemical Engineering)

    1988-09-15

    The main objective of this research is to develop an equation of state that can be used to predict solubilities and tailor supercritical fluid solvents for the extraction and processing of coal. To meet this objective we have implemented a two-sided. approach. First, we expanded the database of model coal compound solubilities in higher temperature fluids, polar fluids, and fluid mixtures systems. Second, the unique solute/solute, solute/cosolvent and solute/solvent intermolecular interactions in supercritical fluid solutions were investigated using spectroscopic techniques. These results increased our understanding of the molecular phenomena that affect solubility in supercritical fluids and were significant in the development of an equation of state that accurately reflects the true molecular makeup of the solution. (VC)

  15. Chemical and Pyrolytic Thermogravimetric Characterization of Nigerian Bituminous Coals

    Directory of Open Access Journals (Sweden)

    Nyakuma Bemgba Bevan

    2016-12-01

    Full Text Available The discovery of new coal deposits in Nigeria presents solutions for nation’s energy crises and prospects for socioeconomic growth and sustainable development. Furthermore, the quest for sustainable energy to limit global warming, climate change, and environmental degradation has necessitated the exploration of alternatives using cleaner technologies such as coal pyrolysis. However, a lack of comprehensive data on physico-chemical and thermal properties of Nigerian coals has greatly limited their utilization. Therefore, the physico-chemical properties, rank (classification, and thermal decomposition profiles of two Nigerian bituminous coals – Afuze (AFZ and Shankodi-Jangwa (SKJ – were examined in this study. The results indicate that the coals contain high proportions of C, H, N, S, O and a sufficiently high heating value (HHV for energy conversion. The coal classification revealed that the Afuze (AFZ coal possesses a higher rank, maturity, and coal properties compared to the Shankodi-Jangwa (SKJ coal. A thermal analysis demonstrated that coal pyrolysis in both cases occurred in three stages; drying (30-200 °C, devolatilization (200-600 °C, and char decomposition (600-1000 °C. The results also indicated that pyrolysis at 1000 °C is not sufficient for complete pyrolysis. In general, the thermochemical and pyrolytic fuel properties indicate that the coal from both places can potentially be utilized for future clean energy applications.

  16. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Kalyan Annamalai; Dr. John Sweeten; Dr. Sayeed Mukhtar

    2000-10-24

    The following are proposed activities for quarter 1 (6/15/00-9/14/00): (1) Finalize the allocation of funds within TAMU to co-principal investigators and the final task lists; (2) Acquire 3 D computer code for coal combustion and modify for cofiring Coal:Feedlot biomass and Coal:Litter biomass fuels; (3) Develop a simple one dimensional model for fixed bed gasifier cofired with coal:biomass fuels; and (4) Prepare the boiler burner for reburn tests with feedlot biomass fuels. The following were achieved During Quarter 5 (6/15/00-9/14/00): (1) Funds are being allocated to co-principal investigators; task list from Prof. Mukhtar has been received (Appendix A); (2) Order has been placed to acquire Pulverized Coal gasification and Combustion 3 D (PCGC-3) computer code for coal combustion and modify for cofiring Coal: Feedlot biomass and Coal: Litter biomass fuels. Reason for selecting this code is the availability of source code for modification to include biomass fuels; (3) A simplified one-dimensional model has been developed; however convergence had not yet been achieved; and (4) The length of the boiler burner has been increased to increase the residence time. A premixed propane burner has been installed to simulate coal combustion gases. First coal, as a reburn fuel will be used to generate base line data followed by methane, feedlot and litter biomass fuels.

  17. Coal Production 1992

    Energy Technology Data Exchange (ETDEWEB)

    1993-10-29

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  18. Coal worker's pneumoconiosis

    Science.gov (United States)

    ... this page: //medlineplus.gov/ency/article/000130.htm Coal worker's pneumoconiosis To use the sharing features on this page, please enable JavaScript. Coal worker's pneumoconiosis (CWP) is a lung disease that ...

  19. Enzymatic desulfurization of coal

    Energy Technology Data Exchange (ETDEWEB)

    Boyer, Y.N.; Crooker, S.C.; Kitchell, J.P.; Nochur, S.V. (DynaGen, Inc., Cambridge, MA (United States)); Marquis, J.K. (Boston Univ., MA (United States). School of Medicine)

    1989-11-07

    Our experimental approach focuses on the use of enzymes which catalyze the addition of oxygen to organic compounds. In tailoring the application of these enzymes to coal processing, we are particularly interested in ensuring that oxidation occurs at sulfur and not at carbon-carbon bonds. Previous studies with DBT have shown that the reaction most frequently observed in microbial oxidative pathways is one in which DBT is oxidized at ring carbons. These reactions, as we have said, are accompanied by a considerable decrease in the energy content of the compound. In addition, microbial pathways have been identified in which the sulfur atom is sequentially oxidized to sulfoxide, to sulfone, to sulfonate, and finally to sulfuric acid. In this case, the fuel value of the desulfurized compounds is largely retained. We are evaluating the potential of commercially available enzymes to selectively catalyze oxidation at sulfur.

  20. Coal terminal project report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-03-01

    Malaysia is building the necessary infrastructure to cope with an increasing demand for electricity. Its restructured energy policy has led to construction of the 2,100 MW Manjung coal-fired power plant in the state of Perak, for which coal has to be imported via the new Lekiv Bulk Terminal (LBT) adjacent to the plant. Contracts for the LBC and the TNBJ coal stockyard were awarded to the Koch Consortium. The article describes equipment for handling and storing coal. 4 photos.

  1. Inorganic constituents in coal

    Energy Technology Data Exchange (ETDEWEB)

    A. Radenovic [University of Zagreb, Sisak (Croatia). Faculty of Metallurgy

    2006-07-01

    Coal contains not only organic matter but also small amounts of inorganic constituents. More than one hundred different minerals and virtually every element in the periodic table have been found in coal. Commonly found group minerals in coal are: major (quartz, pyrite, clays and carbonates), minor, and trace minerals. Coal includes a lot of elements of low mass fraction of the order of w=0.01 or 0.001 %. They are trace elements connected with organic matter or minerals comprised in coal. The fractions of trace elements usually decrease when the rank of coal increases. Fractions of the inorganic elements are different, depending on the coal bed and basin. A variety of analytical methods and techniques can be used to determine the mass fractions, mode of occurrence, and distribution of organic constituents in coal. There are many different instrumental methods for analysis of coal and coal products but atomic absorption spectroscopy (AAS) is the one most commonly used. Fraction and mode of occurrence are one of the main factors that have influence on transformation and separation of inorganic constituents during coal conversion. Coal, as an important world energy source and component for non-fuels usage, will be continuously and widely used in the future due to its relatively abundant reserves. However, there is a conflict between the requirements for increased use of coal on the one hand and less pollution on the other. It's known that the environmental impacts, due to either coal mining or coal usage, can be: air, water and land pollution. Although, minor components, inorganic constituents can exert a significant influence on the economic value, utilization, and environmental impact of the coal.

  2. Inorganic Constituents in Coal

    Directory of Open Access Journals (Sweden)

    Rađenović A.

    2006-02-01

    Full Text Available Coal contains not only organic matter but also small amounts of inorganic constituents. More thanone hundred different minerals and virtually every element in the periodic table have been foundin coal. Commonly found group minerals in coal are: major (quartz, pyrite, clays and carbonates,minor, and trace minerals. Coal includes a lot of elements of low mass fraction of the orderof w=0.01 or 0.001 %. They are trace elements connected with organic matter or minerals comprisedin coal. The fractions of trace elements usually decrease when the rank of coal increases.Fractions of the inorganic elements are different, depending on the coal bed and basin. A varietyof analytical methods and techniques can be used to determine the mass fractions, mode ofoccurrence, and distribution of organic constituents in coal. There are many different instrumentalmethods for analysis of coal and coal products but atomic absorption spectroscopy – AAS is theone most commonly used. Fraction and mode of occurrence are one of the main factors that haveinfluence on transformation and separation of inorganic constituents during coal conversion.Coal, as an important world energy source and component for non-fuels usage, will be continuouslyand widely used in the future due to its relatively abundant reserves. However, there is aconflict between the requirements for increased use of coal on the one hand and less pollution onthe other. It’s known that the environmental impacts, due to either coal mining or coal usage, canbe: air, water and land pollution. Although, minor components, inorganic constituents can exert asignificant influence on the economic value, utilization, and environmental impact of the coal.

  3. Coal technology program. Progress report, May 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-07-01

    Two successful operability tests with sustained operation of the bench-scale hydrocarbonizer were achieved with Illinois No. 6 coal diluted with char. Several activities in the area of nondestructive testing of coatings are reviewed. Failure analysis activities included examination of several components from the solvent refined coal plants at Wilsonville, Alabama, and Tacoma, Washington. In the gas-fired potassium boiler project, all of the design work were completed except for several of the instrument and control drawings. In the design studies of a coal-fired alkali metal vapor topping cycle, the first phase of a cycle analysis and the design and analysis of a metal vapor turbine were completed. A report entitled ''Critical Component Test Facility--Advance Planning for Test Modules'' presents the planning study for the conceptual design of component test modules on a nonsite-specific basis. Engineering studies, project evaluation and process and program analysis of coal conversion processes were continued. A report on the landfill storage of solid wastes from coal conversion is being finalized. In the coal-fueled MIUS project, a series of successful tests of the coal feeding system and a report on the analysis of 500-hr fire-side corrosion tests in a fluidized bed combustor were completed.

  4. Coal production 1989

    Energy Technology Data Exchange (ETDEWEB)

    1990-11-29

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  5. Coal geology and assessment of coal resources and reserves in the Powder River Basin, Wyoming and Montana

    Science.gov (United States)

    Luppens, James A.; Scott, David C.

    2015-01-01

    This report presents the final results of the first assessment of both coal resources and reserves for all significant coal beds in the entire Powder River Basin, northeastern Wyoming and southeastern Montana. The basin covers about 19,500 square miles, exclusive of the part of the basin within the Crow and Northern Cheyenne Indian Reservations in Montana. The Powder River Basin, which contains the largest resources of low-sulfur, low-ash, subbituminous coal in the United States, is the single most important coal basin in the United States. The U.S. Geological Survey used a geology-based assessment methodology to estimate an original coal resource of about 1.16 trillion short tons for 47 coal beds in the Powder River Basin; in-place (remaining) resources are about 1.15 trillion short tons. This is the first time that all beds were mapped individually over the entire basin. A total of 162 billion short tons of recoverable coal resources (coal reserve base) are estimated at a 10:1 stripping ratio or less. An estimated 25 billion short tons of that coal reserve base met the definition of reserves, which are resources that can be economically produced at or below the current sales price at the time of the evaluation. The total underground coal resource in coal beds 10–20 feet thick is estimated at 304 billion short tons.

  6. Cleaner Coal in China [Chinese Version

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    China’s rapid economic growth has aroused intense interest around the world. Policy makers, industrialists, investors, environmentalists, researchers and others want to better understand the issues that this populous nation faces as it further develops an already thriving economy largely fuelled by coal. This study sheds light on the Chinese coal supply and transformation sectors. China’s rapid economic growth has aroused intense interest around the world. Policy makers, industrialists, investors, environmentalists, researchers and others want to better understand the issues that this populous nation faces as it further develops an already thriving economy largely fuelled by coal. This study sheds light on the Chinese coal supply and transformation sectors. China’s coal, mined locally and available at a relatively low cost, has brought enormous benefits to energy consumers in China and to those outside the country who enjoy the products of its coal-based economy. Yet from another perspective, China’s coal use has a high cost. Despite progress, health and safety in the thousands of small coal mines lag far behind the standards achieved in China’s modern, large mines. Environmental degradation is a real and pressing problem at all stages of coal production, supply and use. Adding to these burdens, emissions of carbon dioxide are of concern to the Chinese government as it embarks on its own climate protection strategy. Technology solutions are already transforming the way coal is used in China and elsewhere. This study explores the context in which the development and deployment of these technologies can be accelerated. Providing a large amount of new data, it describes in detail the situation in China as well as the experiences of other countries in making coal cleaner. Above all, the report calls for much greater levels of collaboration – existing bi-lateral and multi-lateral co-operation with China on coal is found lacking. China’s growing openness

  7. Analysis of conduction responses during an underground coal gasification experiment. [Hanna II

    Energy Technology Data Exchange (ETDEWEB)

    Hommert, P.J.

    1978-01-01

    The Laramie Energy Research Center (LERC) conducted an underground coal gasification experiment in a 9-m thick subbituminous coal seam near Hanna, Wyoming. Sandia Laboratories designed and fielded an extensive instrumentation array which included approximately eight thermocouples within the seam in each of 15 diagnostic wells. The instrumentation provided thermal data related to the process during both reverse combustion linkage and forward gasification. Portions of these data suitable for analysis by inverse heat conduction techniques included (1) the responses from the approximately cylindrical reverse combustion linkage path and (2) the responses at thermocouples outside the gasified zone due to conduction from the final boundary. Because of the effects of property variations and water vaporization on the conduction response, an exact analytical solution could not be used. Instead, the approach was to adjust parameters of the constant property analytical solutions to fit numerical calculations that included property variations and water vaporization. Sensitivity studies performed to estimate the accuracy of solutions obtained indicated that parameters relating to size and distance should be identifiable within +- 0.25 m; however, accurate estimates of temperature could not be obtained. Results allowed the position of the reverse combustion linkage path to be mapped, and estimates of its size (approximately 1 m in diameter) and average temperature (750 K--1000 K) to be obtained. With respect to forward gasification, the analysis yielded estimates of the final boundaries established by the burn and characterizations of how the front approached its final position.

  8. Specific Energy of Hard Coal Under Load

    Directory of Open Access Journals (Sweden)

    Bogusz Anna

    2015-03-01

    Full Text Available The article presents results of experimental tests of energy parameters of hard coals under loading, collected from research sites located within five main geologic structures of Upper Silesian Coal Basin (GZW - Main Trough, Main Anticline, Bytom Trough, Rybnik Trough and Chwałowice Trough. Coals from12 mines were analysed, starting with seams of group 200, through groups 400, 500, 600 and, finally, seams of group 700. Coal of each of the groups of seams underwent uniaxial compression stress of the energy parameters, in a servo-controlled testing machine MTS-810NEW, for the full range of strain of the tested coal samples. Based on the tests the dependence of different types of specific energy of longitudinal strain of coals on the value of uniaxial compression strength was determined. The dependence of the value of dissipated energy and kinetic energy of coals on the uniaxial compression strength was described with a linear function, both for coals which due to their age belong to various bed sand for various lithotypes of coal. An increase in the value of dissipated energy and in kinetic energy was observed, which was correlated with an increase in uniaxial compression strength of coal. The share of dissipated energy is dominant in the total energy of strain. Share of recoverable energy in the total energy of strain is small, independent of the compression strength of coals and is at most a few per cent high. In coals of low strength and dominant share of dissipated energy, share of recoverable energy is the biggest among the tested coals. It was shown that following an increase in compression strength the share of recoverable energy decreases, while the share of dissipated energy in the total energy increases. Further studies of specific energy of longitudinal strain of rocks in the full-range strain will be the next step inperfecting methodology of research into natural rock burst susceptibility of Carboniferous rock mass and changes in the

  9. Storage of buffy-coat-derived platelets in additive solution: in vitro effects on platelets of the air bubbles and foam included in the final unit.

    Science.gov (United States)

    Sandgren, Per; Saeed, Kharija

    2011-04-01

    The air bubbles and foam that develop during the preparation of platelet units have traditionally been considered to interact with the platelets, causing activation and release reactions. However, there actually seems to be no data available concerning the platelet damage that may occur as a result of air bubbles and foam present in the final unit. In this in vitro study we, therefore, investigated the effects of not removing air bubbles/foam from final platelet units, by measuring in vitro parameters during a 7-day storage period. Platelet samples (n=8) from eight pools of 12 buffy-coats were aliquoted and prepared with the OrbiSac system for storage with (test) or without (reference) air bubbles/foam included in the final units. The metabolic, cellular and activation parameters of all units, comprising approximately 30% plasma and 70% SSP+ platelet additive solution, were analysed during the 7-day storage period. Differences in platelet counts and contents between the test and reference units were detected throughout storage (pstorage in the test units and was significantly higher than in the reference units (pstorage between the units (p=NS). Aggregates were visible (day 7) and occurred in three of the test units. pH was maintained at >6.8 (day 7) and swirling remained at the highest level (score =2) for all units throughout storage. This study shows that storage with air bubbles/foam causes considerable enhancement of disintegration of platelets. In addition, various in vitro parameters of the platelets remaining seem to be negatively affected. The results of this study suggest that platelets should be stored without air bubbles/foam, given that these cause increased disintegration of platelets.

  10. Coal ash removal in Schkopau

    Energy Technology Data Exchange (ETDEWEB)

    Geisler

    1945-05-22

    This short paper outlined an ash removal process as revealed by a conversation with a Mr. Boerner. Boerner worked with Dr. Strohfeldt in February and March of 1945 on an ash removal process performed at the Schkopau Works. A mill supplied 3 tons/hr of crushed coal, which was mixed with a dilute HCl solution. The acid suspension was immediately supplied to the first concentrator. The thickened paste was transferred by means of a diaphragm pump to the second concentator where a small amount of HCl solution was added. After concentrating in the second apparatus, the paste went to a tank car where the suspension was maintained by air bubbling. Difficulty in filtration was avoided by introduction of a rotating filter cake remover and equally-sized coal granules. The filter yield was estimated at 150 kg of wet cake per m/sup 2/ per hr. The water content of the cake was approximately 50% to 55%, and it was thought that a decrease in water content would result by slowing down the throughput rate. Ash and water analyses of the processed coal were set up, but were not run. No other specific values were given such as ash content, acid concentation, or amounts of reagents added.

  11. Cooperative research program in coal liquefaction. Quarterly report, May 1, 1993--October 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, G.P. [ed.

    1994-07-01

    This report summarizes progress in four areas of research under the general heading of Coal Liquefaction. Results of studies concerning the coliquefaction of coal with waste organic polymers or chemical products of these polymers were reported. Secondly, studies of catalytic systems for the production of clean transportation fuels from coal were discussed. Thirdly, investigations of the chemical composition of coals and their dehydrogenated counterparts were presented. These studies were directed toward elucidation of coal liquefaction processes on the chemical level. Finally, analytical methodologies developed for in situ monitoring of coal liquefaction were reported. Techniques utilizing model reactions and methods based on XAFS, ESR, and GC/MS are discussed.

  12. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 2, Appendix A: Fixed bed gasifier and sulfur sorbent regeneration subsystem computer model development: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Blough, E.; Russell, W.; Leach, J.W.

    1990-08-01

    Computer models have been developed for evaluating conceptual designs of integrated coal gasification combined cycle power plants. An overall system model was developed for performing thermodynamic cycle analyses, and detailed models were developed for predicting performance characteristics of fixed bed coal gasifiers and hot gas clean up subsystem components. The overall system model performs mass and energy balances and does chemical equilibrium analyses to determine the effects of changes in operating conditions, or to evaluate proposed design changes. An existing plug flow model for fixed bed gasifiers known as the Wen II model was revised and updated. Also, a spread sheet model of zinc ferrite sulfur sorbent regeneration subsystem was developed. Parametric analyses were performed to determine how performance depends on variables in the system design. The work was done to support CRS Sirrine Incorporated in their study of standardized air blown coal gasifier gas turbine concepts.

  13. Use of analcime zeolite from mineral coal fly ash in adsorption of Cu{sup +2} and Cd{sup +2} in aqueous solutions; Utilizacao de zeolita analcima a partir de cinza leve de carvao mineral na adsorcao de Cu{sup +2} e Cd{sup +2} em soluoes aquosas

    Energy Technology Data Exchange (ETDEWEB)

    Rocha Junior, C.A.F.; Santos, S.C.A.; Angelica, R.S.; Neves, R.F.; Souza, C.A.G., E-mail: augustorocha2@gmail.com [Universidade Federal do Para (UFPA), Coqueiro, PA (Brazil)

    2011-07-01

    The use of zeolite for removing heavy metals from contaminated effluents over the years has been widespread due to its high cation exchange capacity in aqueous solutions. Thus this study aims to use analcime zeolite for removal of Cu{sup +2} and Cd{sup +2} from aqueous solutions at different concentrations, and the zeolitic material synthesized from coal fly ash generated in an alumina plant in northern Brazil . The use of zeolite analcime proved quite satisfactory, since this product has removed almost entirely Cu{sup +2} and Cd{sup +2} solutions with concentrations up to 200ppm, and demonstrated an average capacity for solutions of 400ppm, which shows good applicability of this material for the treatment of effluent contamination in the ranges studied. The adsorption models of Langmuir and Freundlich showed a good fit to experimental data generated in this work. (author)

  14. Coal to gas substitution using coal?!

    Science.gov (United States)

    Kempka, Thomas; Schlüter, Ralph

    2010-05-01

    Substitution of carbon-intensive coal with less carbon-intensive natural gas for energy production is discussed as one main pillar targeting reduction of antrophogenic greenhouse gas emissions by means of climate change mitigation. Other pillars are energy efficiency, renewable energies, carbon capture and storage as well as further development of nuclear energy. Taking into account innovative clean coal technologies such as UCG-CCS (underground coal gasification with carbon capture and storage), in which coal deposits are developed using directional drilling technologies and subsequently converted into a synthesis gas of high calorific value, the coupled conceptual approach can provide a synergetic technology for coal utilization and mitigation of carbon emissions. This study aims at the evaluation of UCǴ s carbon mitigation potentials and the review of the economical boundary conditions. The analytical models applied within this study are based on data available from world-wide UCG projects and extensive laboratory studies. In summary, scenarios considering costs and carbon storage potentials are economically feasible and thus competitive with less carbon-intensive energy generation technologies such as natural gas. Thus, coal to gas substitution can be one of the coal based options.

  15. Environmentally and economically efficient utilization of coal processing waste.

    Science.gov (United States)

    Dmitrienko, Margarita A; Strizhak, Pavel A

    2017-11-15

    High concentrations of hazardous anthropogenic emissions (sulfur, nitrogen and carbon oxides) from solid fuel combustion in coal burning plants cause environmental problems that have been especially pressing over the last 20-30 years. A promising solution to these problems is a switch from conventional pulverized coal combustion to coal-water slurry fuel. In this paper, we pay special attention to the environmental indicators characterizing the combustion of different coal ranks (gas, flame, coking, low-caking, and nonbaking coals) and coal-water slurry fuels based on the coal processing waste - filter cakes. There have been no consistent data so far on the acceptable intervals for the anthropogenic emissions of sulfur (SOx), nitrogen (NOx) and carbon (CO, CO2) oxides. Using a specialized combustion chamber and gas analyzing system, we have measured the concentrations of typical coal and filter-cake-based CWS combustion products. We have also calculated the typical combustion heat of the fuels under study and measured the ratio between environmental and energy attributes. The research findings show that the use of filter cakes in the form of CWS is even better than coals in terms of environment and economy. Wide utilization of filter cakes solves many environmental problems: the areas of contaminated sites shrink, anthropogenic emissions decrease, and there is no need to develop new coal mines anymore. Copyright © 2017 Elsevier B.V. All rights reserved.

  16. Direct liquefaction of low-rank coals under mild conditions

    Energy Technology Data Exchange (ETDEWEB)

    Braun, N.; Rinaldi, R. [Max-Planck-Institut fuer Kohlenforschung, Muelheim an der Ruhr (Germany)

    2013-11-01

    Due to decreasing of petroleum reserves, direct coal liquefaction is attracting renewed interest as an alternative process to produce liquid fuels. The combination of hydrogen peroxide and coal is not a new one. In the early 1980, Vasilakos and Clinton described a procedure for desulfurization by leaching coal with solutions of sulphuric acid/H{sub 2}O{sub 2}. But so far, H{sub 2}O{sub 2} has never been ascribed a major role in coal liquefaction. Herein, we describe a novel approach for liquefying low-rank coals using a solution of H{sub 2}O{sub 2} in presence of a soluble non-transition metal catalyst. (orig.)

  17. Enzymantic Conversion of Coal to Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Richard Troiano

    2011-01-31

    The work in this project focused on the conversion of bituminous coal to liquid hydrocarbons. The major steps in this process include mechanical pretreatment, chemical pretreatment, and finally solubilization and conversion of coal to liquid hydrocarbons. Two different types of mechanical pretreatment were considered for the process: hammer mill grinding and jet mill grinding. After research and experimentation, it was decided to use jet mill grinding, which allows for coal to be ground down to particle sizes of 5 {mu}m or less. A Fluid Energy Model 0101 JET-O-MIZER-630 size reduction mill was purchased for this purpose. This machine was completed and final testing was performed on the machine at the Fluid Energy facilities in Telford, PA. The test results from the machine show that it can indeed perform to the required specifications and is able to grind coal down to a mean particle size that is ideal for experimentation. Solubilization and conversion experiments were performed on various pretreated coal samples using 3 different approaches: (1) enzymatic - using extracellular Laccase and Manganese Peroxidase (MnP), (2) chemical - using Ammonium Tartrate and Manganese Peroxidase, and (3) enzymatic - using the live organisms Phanerochaete chrysosporium. Spectral analysis was used to determine how effective each of these methods were in decomposing bituminous coal. After analysis of the results and other considerations, such as cost and environmental impacts, it was determined that the enzymatic approaches, as opposed to the chemical approaches using chelators, were more effective in decomposing coal. The results from the laccase/MnP experiments and Phanerochaete chrysosporium experiments are presented and compared in this final report. Spectra from both enzymatic methods show absorption peaks in the 240nm to 300nm region. These peaks correspond to aromatic intermediates formed when breaking down the coal structure. The peaks then decrease in absorbance over time

  18. Analytical Study of Microwave Heating of the Coal Layer With Mixed Boundary Conditions of I and III Types

    Directory of Open Access Journals (Sweden)

    Salomatov Vladimir

    2016-01-01

    Full Text Available This work is dedicated to the search for the exact analytical dependences of microwave heating due to absorption of a plane electromagnetic wave by coal layer with asymmetric and non-uniform heat dissipation conditions I and III kind. Some of simplifications have been made, such as one-dimensional problem, uniformity and isotropic coal material, and the constancy of the electrical properties of thermal coal during heating of microwave radiation. This has led to the fact that the Maxwell’s task is solved separately from the Fourier’s task, and a heat source generated in the carbon layer is subject to Bouguer law. For the system of equations of heat transfer has been found a new dependent variable, which is to simplify the search for a final solution. All this has given the possibility of finding rigorous analytical solution of the problem of microwave heating of the coal layer in the presence of asymmetric and inhomogeneous boundary conditions I and III kind.

  19. Impacts of Coal Seam Gas (Coal Bed Methane) Extraction on Water Resources in Australia

    Science.gov (United States)

    Post, David

    2014-05-01

    While extraction of methane from shale gas deposits has been the principal source of the recent expansion of the industry in the United States and potentially in Europe, extraction of methane from coal bed methane deposits (termed 'coal seam gas' in Australia) has been the focus in Australia. The two sources of methane share many of the same characteristics, with hydraulic fracturing generally (but not always) required to extract coal seam gas also. However, as coal seam gas deposits generally occur at shallower depths than shale gas, the potential impacts of extraction and hydraulic fracturing on surface and groundwater resources may be potentially of more concern for coal seam gas than for shale gas. To determine the potential for coal seam gas extraction (and coal mining more generally) to impact on water resources and water-related assets in Australia, the Commonwealth Government has recently established an Independent Expert Scientific Committee (the IESC) to provide advice to Commonwealth and State Government regulators on potential water-related impacts of coal seam gas and large coal mining developments. The IESC has in turn implemented a program of research termed 'bioregional assessments' to investigate these potential impacts. A bioregional assessment can be defined as a scientific analysis of the ecology, hydrology, geology and hydrogeology of a bioregion, with explicit assessment of the potential direct, indirect and cumulative impacts of coal seam gas and large coal mining development on water resources. These bioregional assessments are now being carried out across large portions of eastern Australia which are underlain by coal reserves. Further details of the program can be found at http://www.environment.gov.au/coal-seam-gas-mining/bioregional-assessments.html. This presentation will provide an overview of the issues related to the impacts of coal seam gas extraction on surface and groundwater resources and water-related assets in Australia. The

  20. Coal sector profile

    Energy Technology Data Exchange (ETDEWEB)

    1990-06-05

    Coal is our largest domestic energy resource with recoverable reserves estimated at 268 billion short tons or 5.896 quads Btu equivalent. This is approximately 95 percent of US fossil energy resources. It is relatively inexpensive to mine, and on a per Btu basis it is generally much less costly to produce than other energy sources. Its chief drawbacks are the environmental, health and safety concerns that must be addressed in its production and consumption. Historically, coal has played a major role in US energy markets. Coal fueled the railroads, heated the homes, powered the factories. and provided the raw materials for steel-making. In 1920, coal supplied over three times the amount of energy of oil, gas, and hydro combined. From 1920 until the mid 1970s, coal production remained fairly constant at 400 to 600 million short tons a year. Rapid increases in overall energy demands, which began during and after World War II were mostly met by oil and gas. By the mid 1940s, coal represented only half of total energy consumption in the US. In fact, post-war coal production, which had risen in support of the war effort and the postwar Marshall plan, decreased approximately 25 percent between 1945 and 1960. Coal demand in the post-war era up until the 1970s was characterized by increasing coal use by the electric utilities but decreasing coal use in many other markets (e.g., rail transportation). The oil price shocks of the 1970s, combined with natural gas shortages and problems with nuclear power, returned coal to a position of prominence. The greatly expanded use of coal was seen as a key building block in US energy strategies of the 1970s. Coal production increased from 613 million short tons per year in 1970 to 950 million short tons in 1988, up over 50 percent.

  1. Applying Rock Engineering Systems (RES approach to Evaluate and Classify the Coal Spontaneous Combustion Potential in Eastern Alborz Coal Mines

    Directory of Open Access Journals (Sweden)

    Amir Saffari

    2013-12-01

    Full Text Available Subject analysis of the potential of spontaneous combustion in coal layers with analytical and numerical methods has been always considered as a difficult task because of the complexity of the coal behavior and the number of factors influencing it. Empirical methods, due to accounting for certain and specific factors, have not accuracy and efficiency for all positions. The Rock Engineering Systems (RES approach as a systematic method for analyzing and classifying is proposed in engineering projects. The present study is concerned with employing the RES approach to categorize coal spontaneous combustion in coal regions. Using this approach, the interaction of parameters affecting each other in an equal scale on the coal spontaneous combustion was evaluated. The Intrinsic, geological and mining characteristics of coal seams were studied in order to identifying important parameters. Then, the main stages of implementation of the RES method i.e. interaction matrix formation, coding matrix and forming a list category were performed. Later, an index of Coal Spontaneous Combustion Potential (CSCPi was determined to format the mathematical equation. Then, the obtained data related to the intrinsic, geological and mining, and special index were calculated for each layer in the case study (Pashkalat coal region, Iran. So, the study offers a perfect and comprehensive classification of the layers. Finally, by using the event of spontaneous combustion occurred in Pashkalat coal region, an initial validation for this systematic approach in the study area was conducted, which suggested relatively good concordance in Pashkalat coal region.

  2. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 2 -- Jointly sponsored research program. Final report, October 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.

    1994-09-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  3. Briquetting of brown coal with hydrolized lignin

    Energy Technology Data Exchange (ETDEWEB)

    Saranchuk, V.I.; Galushko, L.Ja.; Pashchenko, L.V.; Khazipov, V.A. [L.M. Litvinenko Institute of Physical, Organic and Coal Chemistry, Donetsk (Ukraine)

    1995-12-31

    In present the briquetting of coal fines becomes one of priory directions in the solution of problem of provision of needs of people with solid fuel because of deficiency in energetic resources in Ukraine. One of possible ways of developing production of briquets as consumer fuel is the utilization of secondary material resources as additions, in particular, waste products of hydrolysis production-lignin.

  4. Chemical Fixation of CO2 in Coal Combustion Products and Recycling through Biosystems

    Energy Technology Data Exchange (ETDEWEB)

    C. Henry Copeland; Paul Pier; Samantha Whitehead; David Behel

    2001-09-30

    This Annual Technical Progress Report presents the principle results in enhanced growth of algae using coal combustion products as a catalyst to increase bicarbonate levels in solution. A co-current reactor is present that increases the gas phase to bicarbonate transfer rate by a factor of five to nine. The bicarbonate concentration at a given pH is approximately double that obtained using a control column of similar construction. Algae growth experiments were performed under laboratory conditions to obtain baseline production rates and to perfect experimental methods. The final product of this initial phase in algae production is presented.

  5. An LCA study of an electricity coal supply chain

    Directory of Open Access Journals (Sweden)

    Chao Wang

    2014-01-01

    Full Text Available Purpose: The aim of this paper is to provide methods to find the emission source and estimate the amount of waste gas emissions in the electricity coal supply chain, establish the model of the environmental impact (burden in the electricity coal supply chain, detect the critical factor which causes significant environmental impact, and then identify the key control direction and reduce amount of environmental pollution in the electricity coal supply chain. Design/methodology/approach: In this context, life cycle inventory and life cycle assessment of China’s electricity coal were established in three difference stages: coal mining, coal transportation, and coal burning. Then the outcomes were analyzed with the aim to reduce waste gases emissions’ environmental impact in the electricity coal supply chain from the perspective of sensitivity analysis. Findings: The results and conclusion are as follow: (1 In terms of total waste gas emissions in electricity coal supply chain, CO2 is emitted in the greatest quantity, accounting for 98-99 wt% of the total waste gas emissions. The vast majority of the CO2, greater than 93%, is emitted from the power plant when the coal is combusted. (2 Other than CO2, the main waste gas is CH4, SO2 and so on. CH4 is mainly emitted from Coal Bed Methane (CBM, so the option is to consider capturing some of the CH4 from underground mines for an alternative use. SO2 is mainly emitted from power plant when the coal is combusted. (3 The environmental burden of coal burning subsystem is greatest, followed by the coal mining subsystem, and finally the coal transportation subsystem. Improving the coal-burning efficiency of coal-fired power plant in electricity coal supply chain is the most effective way to reduce the environmental impact of waste gas emissions. (4 Of the three subsystems examined (coal mining, coal transportation, and coal burning, transportation requires the fewest resources and has the lowest waste gas

  6. Coal, culture and community

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-11-01

    16 papers are presented with the following titles: the miners; municipalisation and the millenium - Bolton-upon-Dearne Urban District Council 1899-1914; the traditional working class community revisited; the cultural capital of coal mining communities; activities, strike-breakers and coal communities; the limits of protest - media coverage of the Orgreave picket during the miners` strike; in defence of home and hearth? Families, friendships and feminism in mining communities; young people`s attitudes to the police in mining communities; the determinants of productivity growth in the British coal mining industry, 1976-1989; strategic responses to flexibility - a case study in coal; no coal turned in Yorkshire?; the North-South divide in the Central Coalfields; the psychological effects of redundancy and worklessness - a case study from the coalfields; the Dearne Valley initiative; the future under labour: and coal, culture and the community.

  7. Coal tar in dermatology

    Energy Technology Data Exchange (ETDEWEB)

    Roelofzen, J.H.J.; Aben, K.K.H.; Van Der Valk, P.G.M.; Van Houtum, J.L.M.; Van De Kerkhof, P.C.M.; Kiemeney, L.A.L.M. [Radboud University Nijmegen Medical Center, Nijmegen (Netherlands). Dept. of Dermatology

    2007-07-01

    Coal tar is one of the oldest treatments for psoriasis and eczema. It has anti-inflammatory, antibacterial, antipruritic and antimitotic effects. The short-term side effects are folliculitis, irritation and contact allergy. Coal tar contains carcinogens. The carcinogenicity of coal tar has been shown in animal studies and studies in occupational settings. There is no clear evidence of an increased risk of skin tumors or internal tumors. Until now, most studies have been fairly small and they did not investigate the risk of coal tar alone, but the risk of coal tar combined with other therapies. New, well-designed, epidemiological studies are necessary to assess the risk of skin tumors and other malignancies after dermatological use of coal tar.

  8. WABASH RIVER COAL GASIFICATION REPOWERING PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2000-09-01

    The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

  9. Microbial desulfurization of coal

    Science.gov (United States)

    Dastoor, M. N.; Kalvinskas, J. J.

    1978-01-01

    Experiments indicate that several sulfur-oxidizing bacteria strains have been very efficient in desulfurizing coal. Process occurs at room temperature and does not require large capital investments of high energy inputs. Process may expand use of abundant reserves of high-sulfur bituminous coal, which is currently restricted due to environmental pollution. On practical scale, process may be integrated with modern coal-slurry transportation lines.

  10. Washability of Indian coals - a scenerio

    Energy Technology Data Exchange (ETDEWEB)

    P. Selvakumaran; A. Rajamohan; R. Pattabhi Raman; M. Karunakara Reddy [Bharat Heavy Electrical Ltd., Tiruchirapalli (India)

    2005-07-01

    Recent mine scale washability test results indicate other wise that, many coals from India used in Power generation could be economically washed (with yields of 70% to 80%) to levels of 24% to 32% ash in the final product. These test results are in line with bore hole sample test results conducted by the Central Mine Planning Development Institute. A super thermal power station using ROM coal was selected for the purpose of our study. On site samples were collected from BOBR/Box-n rail wagons, (both merry go round & distant rail) and Power plant belt conveyors. Huge quantities of coal samples from all the four sources were encountered during screen analysis and the quantity has to be reduced before transporting for washability tests in reputed lab. Washability and M curves were prepared mine wise & size wise. Specific gravities used ranged from 1.40 to 1.90. Investigations on proximate, ultimate analysis, gross calorific value, ash composition analysis, Hardgrove Grindability Indices, YGP Indices, {alpha}-Quartz contents, and petrographic analysis on both washed coals and corresponding unwashed coals were studied. Considering the present economics of boiler operation with high ash, highly abrasive coals, we can envisage that considerable reduction of the ash content of coal will result in, increase in rated capacity of the boilers, increase in peak load capacity and finally increase in boiler availability for existing units. For new units it will reduce investment costs and consequent reduction in Electricity tariff to ultimate customers and it will ease the effort in building larger capacity thermal units say 660 to 800 MW. 6 figs., 6 tabs.

  11. Fluidized bed coal desulfurization

    Science.gov (United States)

    Ravindram, M.

    1983-01-01

    Laboratory scale experiments were conducted on two high volatile bituminous coals in a bench scale batch fluidized bed reactor. Chemical pretreatment and posttreatment of coals were tried as a means of enhancing desulfurization. Sequential chlorination and dechlorination cum hydrodesulfurization under modest conditions relative to the water slurry process were found to result in substantial sulfur reductions of about 80%. Sulfur forms as well as proximate and ultimate analyses of the processed coals are included. These studies indicate that a fluidized bed reactor process has considerable potential for being developed into a simple and economic process for coal desulfurization.

  12. Pyrolysis of Coal

    Directory of Open Access Journals (Sweden)

    Rađenović, A.

    2006-07-01

    Full Text Available The paper presents a review of relevant literature on coal pyrolysis.Pyrolysis, as a process technology, has received considerable attention from many researchers because it is an important intermediate stage in coal conversion.Reactions parameters as the temperature, pressure, coal particle size, heating rate, soak time, type of reactor, etc. determine the total carbon conversion and the transport of volatiles and therebythe product distribution. Part of the possible environmental pollutants could be removed by optimising the pyrolysis conditions. Therefore, this process will be subsequently interesting for coal utilization in the future

  13. Cooperative research program in coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, G.P. (ed.)

    1991-01-01

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  14. Classification of bituminous coals - Application of the technique of optimal sections in coal classification

    Science.gov (United States)

    Peng, C.

    1981-01-01

    The method of optimal sections was used for the classification of bituminous coals according to the degree of metamorphism and processing properties (e.g., the caking property). Coals are classified into low volatile, medium-low volatile, and high volatile depending on the amounts of volatiles with metamorphism section points of 20, 28, and 36% on a dry and ash-free basis. Based on the coke strength as the cross-reference, the coals are grouped into the noncaking, weakly caking, medium caking, and strongly caking types. Finally, the coals are subdivided into seven groups including noncaking and extra-strongly caking; thus, a natural classification is evolved and a numerical system set up for their classification.

  15. Coal data base - thesaurus 1980

    Energy Technology Data Exchange (ETDEWEB)

    1980-01-01

    The thesaurus contains the vocabulary used to index the Coal Data Base maintained by IEA Coal Research Technical Information Service. The Data Base contains indexed and abstracted references to publicly-available literature covering all aspects of the coal industry. The subject areas covered include: economics and management, reserves and exploration, mining, preparation, transport and handling, coal properties and constitution, processing and conversion, combustion, waste management, environ mental aspects, coal products, and health and safety. The indexing terms are used in the preparation of the annual subject index to Coal Abstracts and should be useful in searching other data bases for material relevant to the coal industry. (Available from IEA Coal Research)

  16. Enhanced Combustion Low NOx Pulverized Coal Burner

    Energy Technology Data Exchange (ETDEWEB)

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30

    For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for

  17. 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Public design report (preliminary and final)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-07-01

    This Public Design Report presents the design criteria of a DOE Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of NO{sub x} emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 (500 MW) near Rome, Georgia. The technologies being demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NO{sub x} burner. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NO{sub x} burners, advanced overfire systems, and digital control system.

  18. Coals of Hungary

    Energy Technology Data Exchange (ETDEWEB)

    Landis, E.R.; Rohrbacher, T.J.; Gluskoter, H.; Fodor, B.; Gombar, G.; Sebestyen, I.

    1999-07-01

    As part of the activities conducted under the U.S. Hungarian Science and Technology Fund, a total of 39 samples from five coal mines in Hungary were selected for standard coal analyses and major, minor and trace elements analysis. The mine areas sampled were selected to provide a spectrum of coal quality information for comparison with other coal areas in central Europe and worldwide. All of the areas are of major importance in the energy budget of Hungary. The five sample sites contain coal in rocks of Jurassic, Cretaceous, Eocene, Miocene, and Pliocene age. The coals, from four underground and one surface mine, range in rank from high volatile bituminous to lignite B. Most of the coal produced from the mines sampled is used to generate electricity. Some of the power plants that utilize the coals also provide heat for domestic and process usage. The standard coal analysis program is based on tests performed in accordance with standards of the American Society for Testing and Materials (ASTM). Proximate and ultimate analyses were supplemented by determinations of the heating value, equilibrium moisture, forms of sulfur, free-swelling index, ash fusion temperatures (both reducing and oxidizing), apparent specific gravity and Hardgrove Grindability index. The major, minor and trace element analyses were performed in accordance with standardized procedures of the U.S. Geological Survey. The analytical results will be available in the International Coal Quality Data Base of the USGS. The results of the program provide data for comparison with test data from Europe and information of value to potential investors or cooperators in the coal industry of Hungary and Central Europe.

  19. Economic assessment of coal-burning locomotives: Topical report

    Energy Technology Data Exchange (ETDEWEB)

    1986-02-01

    The General Electric Company embarked upon a study to evaluate various alternatives for the design and manufacture a coal fired locomotive considering various prime movers, but retaining the electric drive transmission. The initial study was supported by the Burlington-Northern and Norfolk-Southern railroads, and included the following alternatives: coal fired diesel locomotive; direct fired gas turbine locomotives; direct fired gas turbine locomotive with steam injection; raw coal gasifier gas turbine locomotive; and raw coal fluid bed steam turbine locomotive. All alternatives use the electric drive transmission and were selected for final evaluation. The first three would use a coal water slurry as a fuel, which must be produced by new processing plants. Therefore, use of a slurry would require a significant plant capital investment. The last two would use classified run-of-the-mine (ROM) coal with much less capital expenditure. Coal fueling stations would be required but are significantly lower in capital cost than a coal slurry plant. For any coal fired locomotive to be commercially viable, it must pass the following criteria: be technically feasible and environmentally acceptable; meet railroads' financial expectations; and offer an attractive return to the locomotive manufacturer. These three criteria are reviewed in the report.

  20. Predicting the ancient occurrence of coal deposits using paleoclimate modeling

    Science.gov (United States)

    Beck, Mandi

    Coals are accumulated and consolidated remains of plant material, which means that in order to form coals, a certain amount of annual precipitation is required. This study uses paleo-precipitation data obtained from Fast Ocean Atmosphere Model (FOAM) and predicts where paleo-coal deposits might occur. All predicted coal localities were plotted on paleogeographic reconstructions (obtained from the PALEOMAP Project) for thirteen time intervals from the Early Carboniferous to present. Once these predicted coal deposits were plotted, observed coals from the Boucot et al., 2012 database were then plotted on the same reconstructed basemaps. The predicted coal deposits were then compared with the observed coals to determine if a statistical correlation between the predicted and observed coal deposits could be made. The results show poor visual correlation between the predicted and the observed coals for the Cenozoic and the Mesozoic and works for most of the Paleozoic. There are many factors that could cause this thesis prediction to fail the hypothesis. First, it can be observed that any time interval that has predicted coals in higher latitudes is more likely to pass the null hypothesis. It can also be seen that there is less predicted coal area for the older time intervals. With less prediction you have less opportunity to have hits. Finally, climate patterns may have been different during the older time intervals. We do not fully understand the climates during the older time intervals and prediction models use modern climate patterns to model past climates. With future exploration, this technique can possibly predict where other climate indicators formed to help better understand past climates and paleo-geology.

  1. A computerized coal-water slurry transportation model

    Energy Technology Data Exchange (ETDEWEB)

    Ljubicic, B.R.; Trostad, B. [Univ. of North Dakota, Grand Forks, ND (United States); Bukurov, Z.; Cvijanovic, P. [Univ. of Novi Sad (Yugoslavia)

    1995-12-01

    Coal-water fuel (CWF) technology has been developed to the point where full-scale commercialization is just a matter of gaining sufficient market confidence in the price stability of alternate fossil fuels. In order to generalize alternative fuel cost estimates for the desired combinations of processing and/or transportation, a great deal of flexibility is required owing to the understood lack of precision in many of the newly emerging coal technologies. Previously, decisions regarding the sequential and spatial arrangement of the various process steps were made strictly on the basis of experience, simplified analysis, and intuition. Over the last decade, computer modeling has progressed from empirically based correlation to that of intricate mechanistic analysis. Nomograms, charts, tables, and many simple rules of thumb have been made obsolete by the availability of complex computer models. Given the ability to view results graphically in real or near real time, the engineer can immediately verify, from a practical standpoint, whether the initial assumptions and inputs were indeed valid. If the feasibility of a project is being determined in the context of a lack of specific data, the ability to provide a dynamic software-based solution is crucial. Furthermore, the resulting model can be used to establish preliminary operating procedures, test control logic, and train plant/process operators. Presented in this paper is a computerized model capable of estimating the delivered cost of CWF. The model uses coal-specific values, process and transport requirements, terrain factors, and input costs to determine the final operating configuration, bill of materials, and, ultimately, the capital, operating, and unit costs.

  2. COAL USE REPORT

    Science.gov (United States)

    The world's coal reserves have been estimated to be about one exagram accessible with current extraction technology. The energy content has been valued at 290 zettajourles. Using a value of 15 terawatt as the current global energy consumption, the coal supply could global needs f...

  3. Improving coal handling effectiveness

    Energy Technology Data Exchange (ETDEWEB)

    Walker, S.

    2003-10-01

    Appropriate coal handling systems are essential for successful coal utilisation. The paper looks at some of the options available, including crushers and hammer mills, wear-resistant liners for chutes and wagons, and dewatering systems. These are individual components within larger systems such as stockyard stacking and reclaiming installations. 5 photos.

  4. Management of coal stockpiles

    Energy Technology Data Exchange (ETDEWEB)

    Carpenter, A.M. [IEA Coal Research, London (United Kingdom)

    1999-10-01

    Stockpile management is an important part of the coal handling process from mine to customer. Virtually all coal producers and consumers make use of stockpiles at their facilities, either to serve as a buffer between material delivery and processing or to enable coal blending to meet quality requirements. This report begins by examining why stockpiles are employed. The stacking and reclaiming of piles, and the reduction of noise arising from the handling equipment is then discussed, along with stockpile automation and management. Good sampling and analysis procedures are essential for coal quality management. Sampling systems, representative samples and on-line analysis are described. Stock auditing to reconcile the amount of coal in the stockpiles is also covered. Coals are susceptible to weathering and atmospheric oxidation during storage in open-air piles. Properties and processes affected by coal oxidation and weathering, including heating value losses, handleability, cleaning, combustion and coking are examined. Spontaneous combustion poses safety, environmental, economic and handling problems if it becomes established in stockpiles. Factors affecting spontaneous combustion are discussed with the emphasis on prevention, detection and control. Stockyard operators are under constant social and political pressures to improve the environmental acceptability of their operations. Thus the control, prevention, and monitoring of fugitive dust emissions, and the composition, collection and treatment of stockpile runoff are addressed. The prevention and control of flowslides is also covered. Experience has shown that with good stockpile design and management, most coals can be safely stored in an environmentally acceptable way. 187 refs., 41 figs., 8 tabs.

  5. Biostimulators from coal

    Energy Technology Data Exchange (ETDEWEB)

    Semenov, L.V.

    1984-04-01

    A report is presented on a meeting of the Bureau of the Scientific Council of the Ministry of Coal Industry of the USSR on chemistry of fossil fuels held on 21-22 November 1983 in Moscow. Papers delivered during the meeting are evaluated. Chemistry of black and brown coal from the USSR was analyzed. Chemical coal properties which are of particular significance for coal use as an agricultural fertilizer (biostimulator of plant growth) were investigated. Brown and black coal with the highest oxidation level used as a fuel by power plants could be used for production of fertilizers with a high content of humic acids. Tests carried out in the USSR in various climatic zones (in the North and in Central Asia) showed that biostimulators from coal improved plant growth, reduced ripening period, increased crops, improved physical properties of soils (prevented moisture losses). Utilizing selected wastes from coal processing for production of biostimulators was also discussed. Methods for coal preparation for biostimulant production (crushing, screening, chemical processing) were evaluated. Prospects of biostimulator use in land reclamation were discussed.

  6. Coal for the world

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-01-15

    With reserves of 7 billion t of coal, Colombia is the world's fourth-largest exporter of bituminous coal and has the potential to grow further. The paper discusses current production and the future potential of the La Guajira reserves with Carbones del Cerrejon Ltd., Colombia. 1 ref.

  7. Biodesulphurisation of coal

    OpenAIRE

    Prayuenyong, P.

    2001-01-01

    The emission of sulphur oxides during the combustion of coal is one of the causes of an environmental problem known as acid rain. Biodesulphurisation technology applied as a method to remove sulphur before coal combustion was investigated in this work. The desulphurisation abilities of three specific bacterial strains including Rhodococcus erythropolis IGTS8, R. erythropolis X309 and Shewanella putrefaciens strain NCIMB 8...

  8. Development of coal resources

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-09-01

    It is an important issue to expand stable coal supply areas for Japan, especially to assure stable supply of overseas coals. The investigations on geological structures in foreign countries perform surveys on geological structures in overseas coal producing countries and basic feasibility studies. The investigations select areas with greater business risks in coal producing countries and among private business entities. The geological structure investigations were carried out on China, Indonesia and Malaysia and the basic feasibility studies on Indonesia during fiscal 1994. The basic coal resource development investigations refer to the results of previous physical explorations and drilling tests to develop practical exploration technologies for coal resources in foreign countries. The development feasibility studies on overseas coals conduct technological consultation, surface surveys, physical explorations, and trial drilling operations, and provide fund assistance to activities related thereto. Fiscal 1994 has provided fund assistance to two projects in Indonesia and America. Fund loans are provided on investigations for development and import of overseas coals and other related activities. Liability guarantee for development fund is also described.

  9. Electrolysis of coal slurries

    Energy Technology Data Exchange (ETDEWEB)

    Anthony, K.E.; Tran, T.; Swinkels, D.

    1984-01-01

    The major aims of the project were: to verify early reports of the American workers and demonstrate the feasibility of the concept of electrolysis of coal slurries; investigate reaction mechanisms and the stoichiometry; measure the reducing power and oxidation kinetics of selected Australian coals; investigate some process variables, and demonstrate an electrolysis cell with practical electrode geometry.

  10. Coal Formation and Geochemistry

    Science.gov (United States)

    Orem, W. H.; Finkelman, R. B.

    2003-12-01

    Coal is one of the most complex and challenging natural materials to analyze and to understand. Unlike most rocks, which consist predominantly of crystalline mineral grains, coal is largely an assemblage of amorphous, degraded plant remains metamorphosed to various degrees and intermixed with a generous sprinkling of minute syngenetic, diagenetic, epigenetic, and detrital mineral grains, and containing within its structure various amounts of water, oils, and gases. Each coal is unique, having been derived from different plant sources over geologic time, having experienty -45ced different thermal histories, and having been exposed to varying geologic processes. This diversity presents a challenge to constructing a coherent picture of coal geochemistry and the processes that influence the chemical composition of coal.Despite the challenge coal presents to geochemists, a thorough understanding of the chemistry and geology of this complex natural substance is essential because of its importance to our society. Coal is, and will remain for sometime, a crucial source of energy for the US and for many other countries (Figure 1). In the USA, more than half of the electricity is generated by coal-fired power plants, and almost 90% of the coal mined in the USA is sold for electricity generation (Pierce et al., 1996). It is also an important source of coke for steel production, chemicals, pharmaceuticals, and even perfumes ( Schobert, 1987). It may also, in some cases, be an economic source of various mineral commodities. The utilization of coal through mining, transport, storage, combustion, and the disposal of the combustion by-products, also presents a challenge to geochemists because of the wide range of environmental and human health problems arising from these activities. The sound and effective use of coal as a natural resource requires a better understanding of the geochemistry of coal, i.e., the chemical and mineralogical characteristics of the coal that control its

  11. Enzymatic desulfurization of coal

    Energy Technology Data Exchange (ETDEWEB)

    Boyer, Y.N.; Crooker, S.C.; Kitchell, J.P.; Nochur, S.V.

    1991-05-16

    The overall objective of this program was to investigate the feasibility of an enzymatic desulfurization process specifically intended for organic sulfur removal from coal. Toward that end, a series of specific objectives were defined: (1) establish the feasibility of (bio)oxidative pretreatment followed by biochemical sulfate cleavage for representative sulfur-containing model compounds and coals using commercially-available enzymes; (2) investigate the potential for the isolation and selective use of enzyme preparations from coal-utilizing microbial systems for desulfurization of sulfur-containing model compounds and coals; and (3) develop a conceptual design and economic analysis of a process for enzymatic removal of organic sulfur from coal. Within the scope of this program, it was proposed to carry out a portion of each of these efforts concurrently. (VC)

  12. Industrial coal utilization

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-01-01

    The effects of the National Energy Act on the use of coal in US industrial and utility power plants are considered. Innovative methods of using coal in an environmentally acceptable way are discussed: furnace types, fluidized-bed combustion, coal-oil-mixtures, coal firing in kilns and combustion of synthetic gas and liquid fuels. Fuel use in various industries is discussed with trends brought about by uncertain availability and price of natural gas and fuel oils: steel, chemical, cement, pulp and paper, glass and bricks. The symposium on Industrial Coal Utilization was sponsored by the US DOE, Pittsburgh Energy Technology Center, April 3 to 4, 1979. Twenty-one papers have been entered individually into the EDB. (LTN)

  13. Underground Coal Thermal Treatment

    Energy Technology Data Exchange (ETDEWEB)

    Smith, P. [Univ. of Utah, Salt Lake City, UT (United States); Deo, M. [Univ. of Utah, Salt Lake City, UT (United States); Eddings, E. [Univ. of Utah, Salt Lake City, UT (United States); Sarofim, A. [Univ. of Utah, Salt Lake City, UT (United States); Gueishen, K. [Univ. of Utah, Salt Lake City, UT (United States); Hradisky, M. [Univ. of Utah, Salt Lake City, UT (United States); Kelly, K. [Univ. of Utah, Salt Lake City, UT (United States); Mandalaparty, P. [Univ. of Utah, Salt Lake City, UT (United States); Zhang, H. [Univ. of Utah, Salt Lake City, UT (United States)

    2012-01-11

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coal's carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO2 sequestration.

  14. EVALUATION OF BROWN COAL SPONTANEOUS COMBUSTION AND SOURCES GENESIS PROGNOSES

    Directory of Open Access Journals (Sweden)

    Vlastimil MONI

    2014-10-01

    Full Text Available This article presents summarizing information about the solution of partial part of research problem of prognoses of deposited brown coal spontaneous combustion sources genesis as a part of project TA01020351 – program ALFA. We will gradually describe the results of long term measurements carried out on selected brown coal heaps realized from 2011 to 2013. The attention is devoted to characterization of key parameters. These parameters influence the genesis of combustion. The second problem is the comparison of results of thermal imaging with laboratory results of gas and coal samples sampled in situ, with the influence of atmospheric conditions (insolation, aeration, rainfall, atmospheric pressure changes etc., with influence of coal mass degradation, physical and chemical factors and another failure factors to brown coal spontaneous combustion processes.

  15. Selected methods for reducing hazards of spontaneous coal oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Skalicka, J.; Vydra, J.

    1988-01-01

    Discusses methods of preventing coal spontaneous combustion in underground mines. Injection methods and the spraying of inhibiting compounds are comparatively evaluated: injection is aimed at reducing air flow from a ventilation system to a center of spontaneous combustion; spraying reduces the active surface of coal exposed to oxidation. Injection of polyurethane foam and urea-formaldehyde foam is described. Spraying coal with the following compounds is discussed: a mixture of bentonite with calcium chloride, a mixture of water solution of water glass and limestone dust, the Plamor mixture developed by the Bratislava Technical University, the Neoxiplast mixture on the basis of acrylates. Combined use of injection methods, spraying inhibiting mixtures and reducing air access is discussed. Effects of mining schemes without leaving support pillars and reducing coal losses on hazards of coal spontaneous combustion are discussed. 2 refs.

  16. Thermodynamic study of brown-coal gasification

    Energy Technology Data Exchange (ETDEWEB)

    Vonka, P.; Holub, R.; Schoengut, S.; Schoengut, J.

    1988-04-01

    Describes a method for calculating and assessing results of partial adiabatic oxidation of brown coal from the North Bohemian brown-coal field, which may in future act as a source of raw material for production of energy and synthesis gas. Calculations assume idealized fluid and burner generators and reaction parameters were selected to cover a range of operational values (these parameters include pressure, temperature, gasification ratio, water content, ash content and degree of coal conversion). After describing mathematics involved, concludes that thermodynamic analysis shows burner generator to have some advantages over fluid generator for production of synthesis gas, and vice versa for production of energy gas. However, final conclusions must await experimental evidence with regard to degree of conversion and composition of gas mixture; also, validity of this assessment is limited by the fact that no account was taken of the possibility of using reaction heat for production of steam or of any energy consumption involved. 10 refs.

  17. Impregnating Coal With Calcium Carbonate

    Science.gov (United States)

    Sharma, Pramod K.; Voecks, Gerald E.; Gavalas, George R.

    1991-01-01

    Relatively inexpensive process proposed for impregnating coal with calcium carbonate to increase rates of gasification and combustion of coal and to reduce emission of sulfur by trapping sulfur in calcium sulfide. Process involves aqueous-phase reactions between carbon dioxide (contained within pore network of coal) and calcium acetate. Coal impregnated with CO2 by exposing it to CO2 at high pressure.

  18. Re-evaluation of the importance of coal in world energy supplies to the year 2000. Pt. 3

    Energy Technology Data Exchange (ETDEWEB)

    Jakisch, R.R.; Hempel, C.

    1982-08-12

    Part three of the series discusses the regional significance of solid fuels and the developments in world coal trade. The development of world coal production from 1935 to 2000 is presented by countries and by regions. All in all, there is an increasing tendency. The trends in the foreign trade of coal and coal products are characterized by a strongly expanding market. Of the consumer regions, the COMECON countries are those in which the contribution of coal to energy supply is highest. Finally, forecasts for the future world coal trade are compared.

  19. CERAMIC MEMBRANES FOR HYDROGEN PRODUCTION FROM COAL

    Energy Technology Data Exchange (ETDEWEB)

    George R. Gavalas

    2004-04-01

    The preparation and performance of membranes for application to hydrogen separation from coal-derived gas is described. The membrane material investigated was dense amorphous silica deposited on a suitable support by chemical vapor deposition (CVD). Two types of support materials were pursued. One type consisted of a two-layer composite, zeolite silicalite/{alpha}-Al{sub 2}O{sub 3}, in the form of tubes approximately 0.7 cm in diameter. The other type was porous glass tubes of diameter below 0.2 cm. The first type of support was prepared starting from {alpha}-Al{sub 2}O{sub 3} tubes of 1{micro}m mean pore diameter and growing by hydrothermal reaction a zeolite silicalite layer inside the pores of the alumina at the OD side. After calcination to remove the organic template used in the hydrothermal reaction, CVD was carried out to deposit the final silica layer. CVD was carried out by alternating exposure of the surface with silicon tetrachloride and water vapor. SEM and N2 adsorption measurements were employed to characterize the membranes at several stages during their preparation. Permeation measurements of several gases yielded H{sub 2}:N{sub 2} ideal selectivity of 150-200 at room temperature declining to 110 at 250 C. The second type of support pursued was porous glass tubes prepared by a novel extrusion technique. A thick suspension of borosilicate glass powder in a polyethersulfone solution was extruded through a spinneret and after gelation the glass-polymer tube was heat treated to obtain a gas-tight glass tube. Leaching of the glass tube in hot water yielded connected pores with diameter on the order of 100 nm. CVD of the final silica layer was not carried out on these tubes on account of their large pore size.

  20. Coal Technology Program progress report, March 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-05-01

    In the final hydrocarbonization experiment with Wyodak subbituminous coal, the coal was hydrocarbonized at 1100/sup 0/F and 300 psig in the recirculating fluidized bed. Two-dimensional pyrolysis behavior of an eastern bituminous coal (Pittsburgh seam) continues to be examined. Results to date indicate that swelling is significantly more pronounced at very low heating rates. Several activities in progress are related to inspection techniques for wear- and process-resistant coatings. Experimental investigations of fireside corrosion on tubing from a fluidized bed combustor have proceeded with metallographic examination and analyses of the scale formed during the test exposure. Methods for nondestructively determining remaining tube wall thickness and scale thickness were developed. Failure prevention and analysis work was aimed at several parts from the Solvent Refined Coal Plant in Ft. Lewis, Washington. The mechanical design of the gas-fired potassium boiler system was completed with the issue of the last four drawings. One electrical and five instrument and control drawings were completed and some fabrication work was completed. Surveys of industrial coal conversion capabilities continued with emphasis on rotating components, valves, hot gas cleanup devices, and heat recovery equipment. Process and program analysis research studies continued with work on low-Btu gasification, direct combustion, advanced power conversion, liquefaction, high-Btu gasification, in-situ gasification, and beneficiation. In the fossil energy environmental project, a first draft of a landfill assessment report was issued for review. Work continued on the Environmental Monitoring Handbook and Pipeline Gas Programmatic Assessment.

  1. Remoção de íons Zn2+, Cd2+ e Pb2+ de soluções aquosas usando compósito magnético de zeólita de cinzas de carvão Removal of Zn2+, Cd2+ e Pb2+ ions from aqueous solutions by magnetic composite of zeolite from coal ashes

    Directory of Open Access Journals (Sweden)

    Denise Alves Fungaro

    2010-01-01

    Full Text Available For this study, magnetic composite of zeolite-magnetite was prepared by mixing magnetite nanoparticles suspension with synthetic zeolite. The nanoparticles in suspension were synthesized by precipitating iron ions in a NaOH solution. The zeolite was synthesized from coal fly ash by alkaline hydrothermal treatment. The magnetic composite was characterized by XDR, SEM, magnetization measurements, IR, and BET surface area. Batch tests were carried out to investigate the adsorption of metal ions of Zn2+, Cd2+ and Pb2+ from aqueous solution onto magnetic composite. Adsorption isotherms were analyzed using Freundlich and Langmuir equations. The adsorption equilibrium data fitted well to the Langmuir equation with maximum adsorption capacities in the range of 28.5-127 mg g-1.

  2. Definition of the form of coal spontaneous combustion source as the inverse problem of geoelectrics

    Directory of Open Access Journals (Sweden)

    Sirota Dmitry

    2017-01-01

    Full Text Available The paper reviews the method of determining the shape and size of the coal self-heating source on coal pit benches and in coal piles during mining of coal by the open method. The method is based on the regularity found in the 1970s of the previous century and related to the distribution of potential of the natural electrical field arising from the temperature in the vicinity of the center of self-heating. The problem is reduced to the solution of inverse ill-posed problem of mathematical physics. The study presents the developed algorithm of its solution and the results of numerical simulation.

  3. Coal desulfurization by aqueous chlorination

    Science.gov (United States)

    Kalvinskas, J. J.; Vasilakos, N.; Corcoran, W. H.; Grohmann, K.; Rohatgi, N. K. (Inventor)

    1982-01-01

    A method of desulfurizing coal is described in which chlorine gas is bubbled through an aqueous slurry of coal at low temperature below 130 degrees C., and at ambient pressure. Chlorinolysis converts both inorganic and organic sulfur components of coal into water soluble compounds which enter the aqueous suspending media. The media is separated after chlorinolysis and the coal dechlorinated at a temperature of from 300 C to 500 C to form a non-caking, low-sulfur coal product.

  4. Coal. A human history

    Energy Technology Data Exchange (ETDEWEB)

    Freese, B.

    2002-07-01

    Prized as 'the best stone in Britain' by Roman invaders who carved jewellery out of it, coal has transformed societies, powered navies, fueled economies, and expanded frontiers. Yet the mundane mineral that built our global economy and even today powers our electrical plants, has also caused death, disease, and environmental destruction. As early as 1306, King Edward I tried to ban coal (unsuccessfully) because its smoke became so obnoxious. Its recent identification as a primary cause of global warming has made it a cause celebre of a new kind. This book describes the history of coal, that began three hundred million years ago and spans the globe.

  5. Coal-fired generation

    CERN Document Server

    Breeze, Paul

    2015-01-01

    Coal-Fired Generation is a concise, up-to-date and readable guide providing an introduction to this traditional power generation technology. It includes detailed descriptions of coal fired generation systems, demystifies the coal fired technology functions in practice as well as exploring the economic and environmental risk factors. Engineers, managers, policymakers and those involved in planning and delivering energy resources will find this reference a valuable guide, to help establish a reliable power supply address social and economic objectives. Focuses on the evolution of the traditio

  6. Quantitative Modelling of Trace Elements in Hard Coal.

    Science.gov (United States)

    Smoliński, Adam; Howaniec, Natalia

    2016-01-01

    The significance of coal in the world economy remains unquestionable for decades. It is also expected to be the dominant fossil fuel in the foreseeable future. The increased awareness of sustainable development reflected in the relevant regulations implies, however, the need for the development and implementation of clean coal technologies on the one hand, and adequate analytical tools on the other. The paper presents the application of the quantitative Partial Least Squares method in modeling the concentrations of trace elements (As, Ba, Cd, Co, Cr, Cu, Mn, Ni, Pb, Rb, Sr, V and Zn) in hard coal based on the physical and chemical parameters of coal, and coal ash components. The study was focused on trace elements potentially hazardous to the environment when emitted from coal processing systems. The studied data included 24 parameters determined for 132 coal samples provided by 17 coal mines of the Upper Silesian Coal Basin, Poland. Since the data set contained outliers, the construction of robust Partial Least Squares models for contaminated data set and the correct identification of outlying objects based on the robust scales were required. These enabled the development of the correct Partial Least Squares models, characterized by good fit and prediction abilities. The root mean square error was below 10% for all except for one the final Partial Least Squares models constructed, and the prediction error (root mean square error of cross-validation) exceeded 10% only for three models constructed. The study is of both cognitive and applicative importance. It presents the unique application of the chemometric methods of data exploration in modeling the content of trace elements in coal. In this way it contributes to the development of useful tools of coal quality assessment.

  7. Clean coal initiatives in Indiana

    Science.gov (United States)

    Bowen, B.H.; Irwin, M.W.; Sparrow, F.T.; Mastalerz, Maria; Yu, Z.; Kramer, R.A.

    2007-01-01

    Purpose - Indiana is listed among the top ten coal states in the USA and annually mines about 35 million short tons (million tons) of coal from the vast reserves of the US Midwest Illinois Coal Basin. The implementation and commercialization of clean coal technologies is important to the economy of the state and has a significant role in the state's energy plan for increasing the use of the state's natural resources. Coal is a substantial Indiana energy resource and also has stable and relatively low costs, compared with the increasing costs of other major fuels. This indigenous energy source enables the promotion of energy independence. The purpose of this paper is to outline the significance of clean coal projects for achieving this objective. Design/methodology/approach - The paper outlines the clean coal initiatives being taken in Indiana and the research carried out at the Indiana Center for Coal Technology Research. Findings - Clean coal power generation and coal for transportation fuels (coal-to-liquids - CTL) are two major topics being investigated in Indiana. Coking coal, data compilation of the bituminous coal qualities within the Indiana coal beds, reducing dependence on coal imports, and provision of an emissions free environment are important topics to state legislators. Originality/value - Lessons learnt from these projects will be of value to other states and countries.

  8. Data base for the analysis of compositional charateristics of coal seams and macerals. Final report, Part 6. Petrography and depositional environment of the Herrin (No. 6) seam in central, eastern and northwestern Illinois

    Energy Technology Data Exchange (ETDEWEB)

    Russell, S.J.

    1984-01-01

    The objectives of this study were to characterize and compare the petrography of the Herrin (No. 6) seam in the sampling areas and to relate the petrography to the sedimentology, conditions during peat deposition and to the paleobotany of the seam. Sixteen column samples of the Herrin (no. 6) seam from 9 mines in central, eastern and northwestern Illinois were described megascopically in terms of the lithotypes vitrain, clarain, duroclarain, clarodurain, durain and fusain. Ten of the columns were also analyzed petrographically. The columns were divided into subsections based on the maceral content. Two characteristic seam profiles were identified. Samples from northwestern Illinois and from central Illinois west of the peat-contemporaneous Walshville channel have a profile consisting of alternating subsections of relatively inertinite-rich lower subsections and inertinite-poor upper subsections. All coal columns studied terminate upward in n inertinite-poor subsection. The coal petrography is believed to have been controlled by fluctuations in the water table during peat deposition which were caused either by variation in rainfall or by changes in sea level. Prior to the marine transgression which ended peat accumulation, the water table in the swamp rose everywhere within the study area. The results of this work compare favorably with paleobotanical studies of the Herrin (No. 6) seam. 151 references, 41 figures, 13 tables.

  9. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  10. Final Closeout report for grant FG36-08GO18018, titled: Functional Multi-Layer Solution Processable Polymer Solar Cells

    Energy Technology Data Exchange (ETDEWEB)

    Adam J. Moule

    2012-05-01

    single heterojunction layer is based upon the idea of balancing good and bad properties within a single film. This proposal addresses the idea that the use of multiple layers that have differing electrical and optical functions could lead to greater efficiency because fewer materials compromises must be made. This idea is not new, multiple functional layer have been successfully used in cross-linked OLED's and organic small molecule evaporated PV devices. The main reason that multiple layers of polymers are not commonly deposited is that most conjugated polymers are mutually soluble in the same solvents. The work outlined in the proposal was intended to develop a new deposition strategy that would allow multiple organic layers to be deposited from solution using spin coating. The deposition method that we proposed was successful, sometimes, but ultimately not reliable. Instead we focused on more reliable methods to implement doping along the interface between layers. This work has been very successful. We found that using PEDOT:PSS, the PSS would form a surface layer of {approx}2-3 nm thickness that would mix with and electrochemically react with P3HT upon heating. This mechanism is also a crosslinking reaction in that H{sub 2} is released and permanent new bonds are formed. Using the Plextronics Inc. replacement to PEDOT:PSS, for which there are no mobile dopants, we were able to show that a second and different mechanism can be used to p-type dope organic materials. We are currently working with Plextronics to develop a new product. Finally we produced n-type doping of a thin fullerene layer near the cathode also using a self-assembly method. Low work function metals will diffuse into the BHJ layer and dope the fullerene upon heating. This doping also affects the vertical segregation of BHJ materials in a predictable way. We accomplished all of the scientific goals that we set out in the proposal written in May 2007. Some of the methods we proposed were not fully

  11. PULVERIZATION INDUCED CHARGE: IN-LINE DRY COAL CLEANING

    Energy Technology Data Exchange (ETDEWEB)

    John M. Stencel

    1999-11-12

    The technical feasibility of separating mineral matter and pyrite from coal as it is transported from pulverizers to burners in pulverized coal combustion units is examined. The charge imparted on coal during pulverization and transport to pulverized coal (PC) burners in a utility boiler is quantified. In addition to field charge measurements, an existing computational model is extended to numerically simulate charged particle motion in a turbulent gas through coal transport pipes and triboelectrostatic separation zone. Results from the field tests and numerical modeling are employed in a conceptual design and a 4--40 kg/hr laboratory-scale separator is constructed and tested. This laboratory unit is used to quantify the magnitude and differential charge imparted on coals during pulverization and transport typical in utility PC units. An electrostatic separator, designed for in-line operation between pulverizers and PC boilers, will be used to clean prepulverized coals. Theoretical and experimental data are to be used in preparing a preliminary and conceptual design for a 15 ton/hr, in-line, electrostatic coal cleaning device. Finally, the economic potential for applications to PC units is assessed.

  12. The past decade of coal research at ACERC

    Energy Technology Data Exchange (ETDEWEB)

    Smoot, L.D. [Brigham Young Univ., Provo, UT (United States). Advanced Combustion Engineering Research Center

    1996-12-31

    The mission of the Advanced Combustion Engineering Research Center (ACERC) is to develop advanced combustion technology through fundamental engineering research and educational and technology transfer programs aimed at the solution of critical combustion problems in the clean and efficient use of fossil fuels and waste materials, particularly coal. Research highlights in six thrust areas emphasizing coal combustion are noted, as are directions for the next century.

  13. Coal and the Present Energy Situation: Abundant coal reserves can be used to alleviate the oil and gas shortage.

    Science.gov (United States)

    Osborn, E F

    1974-02-08

    To summarize, we must make greater use of coal, an energy resource that the nation has in great abundance, if we are to approach our former position of self-sufficiency in energy production. The first step is to move immediately to replace the oil and gas used in electric generating plants with coal and to require that coal be used in fossil fuel electric plants planned or under construction in the next few years. The technology to remove sulfur and particulates from the stack gases is at hand, and therefore environmental regulations can be met. Producing and transporting the required increased tonnages of coal are problems that can be met with appropriate incentives to the coal and transportation industries. Improved mining technology would be helpful but is not a requiremlent. Oil and gas from coal should be in significant commercial production in about a decade. Underground, or in situ, gasification of coal, now in field tests, looks promising as a practical process for recovering the energy from coal, especially in deep or thick beds that cannot be mined efficiently. Recoverable methane occurs in coal beds in the United States in an amount approximately equal to the total reserves of natural gas-about 260 trillion cubic feet. This large reserve of natural gas should be exploited as quickly as possible. Only minor investments in exploration and modest advances in technology are required. Finally, as coal production is expanded. adequate planning and the most modern technology should be used to ensure that coal is extracted with maximum recovery and with minimum damage to the environment.

  14. Dynamic Game Analysis of Coal Electricity Market Involving Multi-Interests

    Directory of Open Access Journals (Sweden)

    Yu Xiaobao

    2016-01-01

    Full Text Available The coal consumption of China reached 2.75 billion tons of standard coal in 2013, which accounted for 67.5% of total energy consumption and more than 50% of global coal consumption. Therefore, the impact of coal price is huge on coal market and even energy market in China. As a large consumer of coal, thermal power enterprise has a strong sensitivity to coal price. In order to balance the rising cost of enterprises due to coal price, we need to analyze the interests of multiple stakeholders. Firstly, this paper combined the Nash equilibrium and cobweb model and proposed the characteristics in different cobweb model. Then, for coal, power, and energy companies, the dynamic game analysis model is constructed. This model gives a game analysis in four scenarios and quantifies the decision of each stakeholder in different coal prices. Finally, the impact figure of different coal prices on each stakeholder has been drawn. The impacts of different coal or thermal power prices on different markets have been put forward, so relevant policy recommendations have been proposed combined with the cobweb model.

  15. Coal handling for IPPs

    Energy Technology Data Exchange (ETDEWEB)

    Phillips, K.

    2000-02-01

    Demand for seaborne steam coal in Asia is expected to increase. By 2010, for example, Japan alone is expected to double its coal-fired power generating electricity capacity. At end-FY 1999 an extra 13 IPPs should come on line. Demand for new materials handling equipment at ports will increase. In terms of scraper reclaimers for stockyard storing and homogenising systems for coal handling and blending, Gustac Schade of Germany is a world leader. Schade introduced the first cantilever scraper reclaimer system at Scholven power station of VKR in Germany in 1968. Later designs have incorporated portal scraper reclaimers. Systems are available for longtidunal and circular coal storage systems, both open and enclosed. 3 photos.

  16. Coal Mine Permit Boundaries

    Data.gov (United States)

    Earth Data Analysis Center, University of New Mexico — ESRI ArcView shapefile depicting New Mexico coal mines permitted under the Surface Mining Control and Reclamation Act of 1977 (SMCRA), by either the NM Mining these...

  17. Healy Clean Coal Project: A DOE Assessment

    Energy Technology Data Exchange (ETDEWEB)

    National Energy Technology Laboratory

    2003-09-01

    The goal of the U.S. Department of Energy's (DOE) Clean Coal Technology (CCT) Program is to provide the energy marketplace with advanced, more efficient, and environmentally responsible coal utilization options by conducting demonstrations of new technologies. These demonstration projects are intended to establish the commercial feasibility of promising advanced coal technologies that have been developed to a level at which they are ready for demonstration testing under commercial conditions. This document serves as a DOE post-project assessment (PPA) of the Healy Clean Coal Project (HCCP), selected under Round III of the CCT Program, and described in a Report to Congress (U.S. Department of Energy, 1991). The desire to demonstrate an innovative power plant that integrates an advanced slagging combustor, a heat recovery system, and both high- and low-temperature emissions control processes prompted the Alaska Industrial Development and Export Authority (AIDEA) to submit a proposal for this project. In April 1991, AIDEA entered into a cooperative agreement with DOE to conduct this project. Other team members included Golden Valley Electric Association (GVEA), host and operator; Usibelli Coal Mine, Inc., coal supplier; TRW, Inc., Space & Technology Division, combustor technology provider; Stone & Webster Engineering Corp. (S&W), engineer; Babcock & Wilcox Company (which acquired the assets of Joy Environmental Technologies, Inc.), supplier of the spray dryer absorber technology; and Steigers Corporation, provider of environmental and permitting support. Foster Wheeler Energy Corporation supplied the boiler. GVEA provided oversight of the design and provided operators during demonstration testing. The project was sited adjacent to GVEA's Healy Unit No. 1 in Healy, Alaska. The objective of this CCT project was to demonstrate the ability of the TRW Clean Coal Combustion System to operate on a blend of run-of-mine (ROM) coal and waste coal, while meeting strict

  18. Prospects for coal and clean coal technology in the Philippines

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-03-15

    This report examines the current energy outlook for the Philippines in regard not only to coal but also other energy resources. The history of the power sector, current state of play and future plans to meet the increasing energy demand from a growing population are discussed. There is also analysis of the trends for coal demand and production, imports and exports of coal and the types of coal-fired power stations that have been built. This includes examination of the legislation involving coal and the promotion of clean coal technologies.

  19. Coal stockyard systems

    Energy Technology Data Exchange (ETDEWEB)

    Phillips, K.

    2001-10-01

    Selection criteria for coal stockyard materials handling systems at bulk terminals is far more complex than it appears at first sight. Criteria for the selection of the best suitable layout and equipment for coal terminals, include the homogenisation of material and the layout of the stockpile in the form of conventional longitudinal piles or circular piles. The article reviews the current state-of-the-art concepts for coal terminals, and groups these ideas into a workable set of guidelines for the coal mine or stockyard operator. As priorities for each application are different, utmost flexibility in the layout and design of bulk terminals is required. It describes storage systems chosen for the transhipment terminal at the Port of Koper in Slovenia, the Callide coal mine in Queensland, Australia, and the Ho-Ping coal-fired power plant in Taiwan. The recent agreement for a combined sales and marketing cooperation between Aumund in Germany and BLW Mechanical Handling in the UK is mentioned. 3 photos.

  20. Australian coal conference

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-06-01

    Almost 600 people attended this year's Australian Coal Conference on Queensland's Gold Coast. The article reports on issues raised at the conference which included the effects of globalisation and the difficulties of raising funds faced by the coal industry and environmental issues. A life cycle analysis of coal's emissions compared to other fuels, released at the conference had demonstrated that coal was a legitimate part of the world's future energy mix. Conference speakers included Michael Pinnock, Queensland Mining Council Chief Executive Officer, Dr Louis Wibberley and Rich Gazzard of BHP, Robin Batterham, the Australian Governments Chief Scientist, Mark Vale, Federal Minister for Trade, Tony Armor of EPRI, Daren Fooks, Clayton Utz Lawyers, Ron Knapp, Chief Executive of the World Coal Institute and Andrew Tucker, Australian Competition and Consumer Commission. Highlights of their addresses are given. Winners of the five research awards presented by the Australian Coal Association at the conference are reported. 11 photos.

  1. Using Mathematica software for coal gasification simulations – Selected kinetic model application

    Directory of Open Access Journals (Sweden)

    Sebastian Iwaszenko

    2015-01-01

    Full Text Available Coal gasification is recognized as a one of promising Clean Coal Technologies. As the process itself is complicated and technologically demanding, it is subject of many research. In the paper a problem of using volumetric, non-reactive core and Johnson model for coal gasification and underground coal gasification is considered. The usage of Mathematica software for models' equations solving and analysis is presented. Coal parameters were estimated for five Polish mines: Piast, Ziemowit, Janina, Szczygłowice and Bobrek. For each coal the models' parameters were determined. The determination of parameters was based on reactivity assessment for 50% char conversion. The calculations show relatively small differences between conversion predicted by volumetric and non reactive core model. More significant differences were observed for Johnson model, but they do not exceeded 10% for final char conversion. The conceptual model for underground coal gasification was presented.

  2. Coal 99; Kol 99

    Energy Technology Data Exchange (ETDEWEB)

    Sparre, C.

    2000-07-01

    The following report deals with the use of coal and coke during 1998. Some information about techniques, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used. The use of steam coal for heating purposes during 1998 was 680 000 tons and somewhat lower than in 1997. The extremely high figures of 1996 were due to twice the production of electricity because of lack of waterpower. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generating plants. During the top year 1987 coal was used in 18 hot water plants and 11 co-generation plants. During 1998 these figures are 1 and 8. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. Steel-works, however, increase their use of steam coal in order to replace the more expensive coke. The import of metallurgical coal in 1998 was 1.6 mill tons like the year before. 1.1 mill tons of coke were produced. The coke consumption in the industry was 1.4 mill tons from which 0.3 mill tons were imported. Several other plants have plans to replace the coal with forest fuels, waste fuels and NG. Even the biggest plant, Vaesteraas, has ordered a block for bio fuels. Helsingborg has started to use wood pellets. The pellets replace most of the coal for the heat production in the co-generation plant. Norrkoeping Kraft AB has put a fluid bed boiler for various fuels into operation, leading to more than half the coal consumption compared with previous years. They have also rebuilt one of their travelling grates for bio fuels. Stockholm Energi, Haesselbyverket, has invested

  3. Trace elements in coal ash

    Science.gov (United States)

    Deonarine, Amrika; Kolker, Allan; Doughten, Michael W.

    2015-01-01

    Coal ash is a residual waste product primarily produced by coal combustion for electric power generation. Coal ash includes fly ash, bottom ash, and flue-gas desulfurization products (at powerplants equipped with flue-gas desulfurization systems). Fly ash, the most common form of coal ash, is used in a range of products, especially construction materials. A new Environmental Protection Agency ruling upholds designation of coal ash as a non-hazardous waste under Subtitle D of the Resource Conservation and Recovery Act, allowing for the continued beneficial use of coal ash and also designating procedures and requirements for its storage.

  4. Variability of Mercury Content in Coal Matter From Coal Seams of The Upper Silesia Coal Basin

    Science.gov (United States)

    Wierzchowski, Krzysztof; Chećko, Jarosław; Pyka, Ireneusz

    2017-12-01

    The process of identifying and documenting the quality parameters of coal, as well as the conditions of coal deposition in the seam, is multi-stage and extremely expensive. The taking and analyzing of seam samples is the method of assessment of the quality and quantity parameters of coals in deep mines. Depending on the method of sampling, it offers quite precise assessment of the quality parameters of potential commercial coals. The main kind of seam samples under consideration are so-called "documentary seam samples", which exclude dirt bands and other seam contaminants. Mercury content in coal matter from the currently accessible and exploited coal seams of the Upper Silesian Coal Basin (USCB) was assessed. It was noted that the mercury content in coal seams decreases with the age of the seam and, to a lesser extent, seam deposition depth. Maps of the variation of mercury content in selected lithostratigraphic units (layers) of the Upper Silesian Coal Basin have been created.

  5. Coal fires in Indonesia

    Energy Technology Data Exchange (ETDEWEB)

    Whitehouse, Alfred E.; Mulyana, Asep A.S. [Office of Surface Mining/Ministry of Energy and Mineral Resources Coal Fire Project, Ministry of Energy and Mineral Resources, Agency for Training and Education, Jl. Gatot Subroto, Kav. 49, Jakarta 12950 (Indonesia)

    2004-07-12

    Indonesia's fire and haze problem is increasingly being ascribed to large-scale forest conversion and land clearing activities making way for pulpwood, rubber and oil palm plantations. Fire is the cheapest tool available to small holders and plantation owners to reduce vegetation cover and prepare and fertilize extremely poor soils. Fires that escaped from agricultural burns have ravaged East Kalimantan forests on the island of Borneo during extreme drought periods in 1982-1983, 1987, 1991, 1994 and 1997-1998. Estimates based on satellite data and ground observations are that more than five million hectares were burned in East Kalimantan during the 1997/1998 dry season. Not only were the economic losses and ecological damage from these surface fires enormous, they ignited coal seams exposed at the ground surface along their outcrops.Coal fires now threaten Indonesia's shrinking ecological resources in Kutai National Park and Sungai Wain Nature Reserve. Sungai Wain has one of the last areas of unburned primary rainforest in the Balikpapan-Samarinda area with an extremely rich biodiversity. Although fires in 1997/1998 damaged nearly 50% of this Reserve and ignited 76 coal fires, it remains the most valuable water catchment area in the region and it has been used as a reintroduction site for the endangered orangutan. The Office of Surface Mining provided Indonesia with the capability to take quick action on coal fires that presented threats to public health and safety, infrastructure or the environment. The US Department of State's Southeast Asia Environmental Protection Initiative through the US Agency for International Development funded the project. Technical assistance and training transferred skills in coal fire management through the Ministry of Energy and Mineral Resource's Training Agency to the regional offices; giving the regions the long-term capability to manage coal fires. Funding was also included to extinguish coal fires as

  6. Schedules of Controlled Substances: Placement of FDA-Approved Products of Oral Solutions Containing Dronabinol [(-)-delta-9-transtetrahydrocannabinol (delta-9-THC)] in Schedule II. Interim final rule, with request for comments.

    Science.gov (United States)

    2017-03-23

    On July 1, 2016, the U.S. Food and Drug Administration (FDA) approved a new drug application for Syndros, a drug product consisting of dronabinol [(-)-delta-9-trans-tetrahydrocannabinol (delta-9-THC)] oral solution. Thereafter, the Department of Health and Human Services (HHS) provided the Drug Enforcement Administration (DEA) with a scheduling recommendation that would result in Syndros (and other oral solutions containing dronabinol) being placed in schedule II of the Controlled Substances Act (CSA). In accordance with the CSA, as revised by the Improving Regulatory Transparency for New Medical Therapies Act, DEA is hereby issuing an interim final rule placing FDA-approved products of oral solutions containing dronabinol in schedule II of the CSA.

  7. Forecasting European thermal coal spot prices

    Directory of Open Access Journals (Sweden)

    Alicja Krzemień

    2015-01-01

    Finally, in order to analyse the time series model performance a Generalized Regression Neural Network (GRNN was used and its performance compared against the whole AR(2 process. Empirical results obtained confirmed that there is no statistically significant difference between both methods. The GRNN analysis also allowed pointing out the main drivers that move the European Thermal Coal Spot prices: crude oil, USD/CNY change and supply side drivers.

  8. Mill performance of coal blends

    Energy Technology Data Exchange (ETDEWEB)

    P.A. Bennett; G. O' Brien; D. Holcombe [CoalTech Pty Ltd. (Australia)

    2005-07-01

    Evaluating the potential performance of coal blends for use as pulverised fuel (PF) in power plants and pulverised coal injection (PCI) into blast furnaces requires knowledge of the size distribution of the organic and mineral matter components of a blend, especially when there are significant differences in the Hardgrove Grindability Index (HGI) of the component coals. The size distribution of the organic matter impacts on combustibility of thermal and PCI coal blends and handleability of PCI coal blends. Petrography techniques were used to examine four size fractions from the PF of single coals and blends to measure the size distribution of maceral groups. For most coals, a good estimate of a blend's size distribution can be made assuming that the size distribution of the individual coals, milled under the same conditions, are added together in the proportions of the blend. The exception is when a very soft coal (HGI 90) is blended with a very hard coal (HGI 35). In this case preferential milling (more reporting to the smaller size fractions) of the softer coal occurred. All coals studied in this project show some sign of preferential grinding of the softer maceral group when the coal was milled individually or in a blend. It is only when there is a large difference in the relative strength of the maceral groups of the coals blended that the preferential milling of a coal in a blend is observed in the size distribution of the blend. The results indicate that the breakage characteristics (change in size reduction per unit of energy) of maceral groups in individual coals do not change when they are blended with other coals. 12 refs., 5 figs., 2 tabs.

  9. Effect of multiphase radiation on coal combustion in a pulverized coal jet flame

    Science.gov (United States)

    Wu, Bifen; Roy, Somesh P.; Zhao, Xinyu; Modest, Michael F.

    2017-08-01

    The accurate modeling of coal combustion requires detailed radiative heat transfer models for both gaseous combustion products and solid coal particles. A multiphase Monte Carlo ray tracing (MCRT) radiation solver is developed in this work to simulate a laboratory-scale pulverized coal flame. The MCRT solver considers radiative interactions between coal particles and three major combustion products (CO2, H2O, and CO). A line-by-line spectral database for the gas phase and a size-dependent nongray correlation for the solid phase are employed to account for the nongray effects. The flame structure is significantly altered by considering nongray radiation and the lift-off height of the flame increases by approximately 35%, compared to the simulation without radiation. Radiation is also found to affect the evolution of coal particles considerably as it takes over as the dominant mode of heat transfer for medium-to-large coal particles downstream of the flame. To investigate the respective effects of spectral models for the gas and solid phases, a Planck-mean-based gray gas model and a size-independent gray particle model are applied in a frozen-field analysis of a steady-state snapshot of the flame. The gray gas approximation considerably underestimates the radiative source terms for both the gas phase and the solid phase. The gray coal approximation also leads to under-prediction of the particle emission and absorption. However, the level of under-prediction is not as significant as that resulting from the employment of the gray gas model. Finally, the effect of the spectral property of ash on radiation is also investigated and found to be insignificant for the present target flame.

  10. Enthalpy studies. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mathias, P.M.; Stein, F.P.

    1984-05-01

    This report describes the evaluation and enhancement of the enthalpy model developed for the SRC-I process (as well as the other coal-liquefaction processes). A preliminary version of the model was used in the Post-Baseline review of the SRC-I process design (Duffy et al., 1983), and the final version will be employed by APCI in the ASPEN PLUS Model of the SRC-I Demonstration Plant (APCI, 1984). ICRC, recognizing the need for thermophysical data on coal liquids and coal-fluid model compounds, embarked upon a 2-year experimental program. Specifically, the overall program objectives were to obtain vapor/liquid equilibrium (VLE) and enthalpy data to develop correlations and verify the designs of several important pieces of process equipment in the SRC-I demonstration plant. The enthalpy model uses a modification of the Peng-Robinson (1976) equation of state proposed by Mathias ad Copeman (1983). It was developed mainly from publicly available data on coal fluids and related model compounds (Mathias and Monks, 1982). The generalized (predictive) model has provided good agreement with experimental data on coal fluids. Surprisingly, the agreement with the data on model-compound mixtures is not as good. The practical conclusion is that, within the frame work of the present model, it is better to lump various types of components within the same pseudocomponent. The enthalpy model has achieved the main objective of an improved model for the design of several key heat exchangers in the SRC-I process. Further, the work has identified deficiencies in existing models, which suggest the focus of future research. 24 references.

  11. Experimental Studies of Coal and Biomass Fuel Synthesis and Flame Characterization for Aircraft Engines

    Science.gov (United States)

    2012-03-31

    of biomass and coal to produce appropriate aviation liquid fuels. Fundamentals of fast- pyrolysis and fast-hydropyrolysis were systematically studied...optimization accounting for changes in the heating value of the input coal . In another study by Lackner et al. [2.18, 2.19] , the pyrolysis ...Final Performance Report 3. DATES COVERED (From - To) 01-09-2008 to 31-03-2012 4. TITLE AND SUBTITLE Experimental Studies of Coal and Biomass Fuel

  12. World coal trade up to the year 2010 - the 1992 update. Statistical addedum

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, P.

    1992-03-02

    The statistical addendum to the main review document (Energy/WP.1/GE.2/R.5) contains data on figures for demand, production, imports and exports of coal received from coal-producing countries in response to questionnaires. It presents tables of compiled data for world coal trade up to the year 2010 on consumption, production, imports, exports and demand by country and by regions. Finally, data for production, consumption, imports and exports are given. 11 figs., 13 tabs.

  13. Gas Hydrates of Coal Layers as a Methane Source in the Atmosphere and Mine Working

    Directory of Open Access Journals (Sweden)

    Dyrdin Valery

    2017-01-01

    Full Text Available Living conditions of gas hydrates of a methane in a coal matrix as one of possible forms of finding of molecules of a methane in coal layers are considered. However, gas hydrates are formed not in all mineral coals even under the thermobaric conditions corresponding to their equilibrium state as the minimum humidity and the corresponding pore width are necessary for each brand of coal for formation of gas hydrate. It is shown that it depends on electric electrical dipole moment of a macromolecule of coal. Coals of brands K, D, Zh were considered. The electric field created by the surface of coal does not allow molecules of water to carry out threedimensional driving, and they keep on an internal surface of a time. By means of theoretical model operation a dipole - dipole interaction of molecules of water with the steam surface of coal values of energy of fiber interaction for various functional groups located in coal “fringe” which size for the first and second layers does not allow molecules of water to participate in formation of gas hydrates are received. For coals of brands K, Zh, D, considering distribution of a time on radiuses, the percent of moisture, which cannot share in education solid coal of gas solutions, is calculated.

  14. Biochemical removal of HAP precursors from coal. Quarterly technical report, October 1, 1996--December 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    Olson, G.J.

    1997-01-01

    This fifth quarterly report covers the period of October through December of 1996. Results are presented of pyrite and HAP precursor removal from Kentucky No. 9 coal in shake flasks and from Indiana No. 5 coal in columns. With Kentucky coal, rates of pyrite oxidation were about 6% per day, and significant As, Co, Cd, Mn, and Ni were removed from the coal. These same five HAP precursors also were significantly removed from Indiana No. 5 coal. Additionally, test results are presented of pyrite and HAP precursor removal from Indiana No. 5 and Pittsburgh No. 8 coal using high initial concentrations of ferric ions. These tests showed faster depyritization of coal than in previous tests done with low initial ferric ion concentrations. In addition, faster and more extensive removal of Cd, Co, Mn, and Ni from Indiana No. 5 coal occurred under high ferric conditions. High solution ferric ion concentration are expected in any biodepyritization process due to progressive biooxidation of pyrite to ferric sulfate. Ferric ions are probably the primary oxidant of pyrite and many of the HAP precursors in coal. Analysis of HAP precursors in Stockton Coal, used by PETC in HAP precursor combustion-mass balance test, was done and compared to PETC analytical data. The INEL slurry column reactor was operated in several shake down runs to prepare for complete HAP precursor removal-mass balance tests. Good separation of coal from ash-forming minerals was observed in these tests.

  15. Gas Hydrates of Coal Layers as a Methane Source in the Atmosphere and Mine Working

    Science.gov (United States)

    Dyrdin, Valery; Shepeleva, Sofya; Kim, Tatiana

    2017-11-01

    Living conditions of gas hydrates of a methane in a coal matrix as one of possible forms of finding of molecules of a methane in coal layers are considered. However, gas hydrates are formed not in all mineral coals even under the thermobaric conditions corresponding to their equilibrium state as the minimum humidity and the corresponding pore width are necessary for each brand of coal for formation of gas hydrate. It is shown that it depends on electric electrical dipole moment of a macromolecule of coal. Coals of brands K, D, Zh were considered. The electric field created by the surface of coal does not allow molecules of water to carry out threedimensional driving, and they keep on an internal surface of a time. By means of theoretical model operation a dipole - dipole interaction of molecules of water with the steam surface of coal values of energy of fiber interaction for various functional groups located in coal "fringe" which size for the first and second layers does not allow molecules of water to participate in formation of gas hydrates are received. For coals of brands K, Zh, D, considering distribution of a time on radiuses, the percent of moisture, which cannot share in education solid coal of gas solutions, is calculated.

  16. Modeling on the Effect of Coal Loads on Kinetic Energy of Balls for Ball Mills

    Directory of Open Access Journals (Sweden)

    Yan Bai

    2015-07-01

    Full Text Available This paper presents a solution for the detection and control of coal loads that is more accurate and convenient than those currently used. To date, no research has addressed the use of a grinding medium as the controlled parameter. To improve the accuracy of the coal load detection based on the kinetic energy of balls in a tubular ball mill, a Discrete Element Method (DEM model for ball kinematics based on coal loads is proposed. The operating process for a ball mill and the ball motion, as influenced by the coal quality and the coal load, was analyzed carefully. The relationship between the operating efficiency of a coal pulverizing system, coal loads, and the balls’ kinetic energy was obtained. Origin and Matlab were utilized to draw the variation of parameters with increasing coal loads in the projectile and cascading motion states. The parameters include the balls’ real-time kinetic energy, the friction energy consumption, and the mill’s total work. Meanwhile, a method of balanced adjacent degree and a physical experiment were proposed to verify the considerable effect of the balls’ kinetic energy on coal loads. The model and experiment results indicate that a coal load control method based on the balls’ kinetic energy is therefore feasible for the optimized operation of a coal pulverizing system.

  17. Exchange of experience: sieve analyses of coal and coal paste

    Energy Technology Data Exchange (ETDEWEB)

    1943-02-01

    This report consisted of a cover letter (now largely illegible) and a graph. The graph showed percentages of material left behind as residue on sieves of various mesh sizes, graphed against the mesh sizes themselves. The materials for which data were shown were both dry coal and coal paste from Ludwigshafen, Scholven, Gelsenberg, and Poelitz. The dry coal from Poelitz seemed to be by far the least finely-ground, but the coal paste from Poelitz seemed to be the most finely-ground. The values for coal paste from the other three plants were very close together over most of the range of mesh sizes. The dry coal from Gelsenberg seemed to be the most finely-ground dry coal, while the dry coals from Scholven and Ludwigshafen gave similar values over most of the range of mesh sizes. In all cases, the coal paste from a plant was more finely-ground than the dry coal from the same plant, but for Gelsenberg, the difference between the two was not nearly as great as it was for the other plants, especially Poelitz. For example, for a sieve with about 3,600 cells per square centimeter, only about 10% of the Poelitz coal paste was retained versus about 85% of the Poelitz dry coal retained, whereas the corresponding figures for Gelsenberg materials were about 36% versus about 53%.

  18. Estimation of Moisture Content in Coal in Coal Mills

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Mataji, Babak

    2006-01-01

    For coal-fired power plants information of the moisture content in the coal is important to determine and control the dynamical behavior of the power plants. E.g. a high moisture content in the coal can result in a decreased maximum load gradient of the plant. In this paper a method for estimating...

  19. Estimation of Moisture Content in Coal in Coal Mills

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Mataji, B.

    For coal-fired power plants information of the moisture content in the coal is important to determine and control the dynamical behavior of the power plants. E.g. a high moisture content in the coal can result in a decreased maximum load gradient of the plant. In this paper a method for estimating...

  20. Coal liquefaction processes

    Energy Technology Data Exchange (ETDEWEB)

    Baker, N.R.; Blazek, C.F.; Tison, R.R.

    1979-07-01

    Coal liquefaction is an emerging technology receiving great attention as a possible liquid fuel source. Currently, four general methods of converting coal to liquid fuel are under active development: direct hydrogenation; pyrolysis/hydrocarbonization; solvent extraction; and indirect liquefaction. This work is being conducted at the pilot plant stage, usually with a coal feed rate of several tons per day. Several conceptual design studies have been published recently for large (measured in tens of thousands of tons per day coal feed rate) commercial liquefaction plants, and these reports form the data base for this evaluation. Products from a liquefaction facility depend on the particular method and plant design selected, and these products range from synthetic crude oils up through the lighter hydrocarbon gases, and, in some cases, electricity. Various processes are evaluated with respect to product compositions, thermal efficiency, environmental effects, operating and maintenance requirements, and cost. Because of the large plant capacities of current conceptual designs, it is not clear as to how, and on what scale, coal liquefaction may be considered appropriate as an energy source for Integrated Community Energy Systems (CES). Development work, both currently under way and planned for the future, should help to clarify and quantify the question of applicability.

  1. Final Report to the National Energy Technology Laboratory on FY14- FY15 Cooperative Research with the Consortium for Electric Reliability Technology Solutions

    Energy Technology Data Exchange (ETDEWEB)

    Vittal, Vijay [Arizona State Univ., Tempe, AZ (United States); Lampis, Anna Rosa [Arizona State Univ., Tempe, AZ (United States)

    2018-01-16

    The Power System Engineering Research Center (PSERC) engages in technological, market, and policy research for an efficient, secure, resilient, adaptable, and economic U.S. electric power system. PSERC, as a founding partner of the Consortium for Electric Reliability Technology Solutions (CERTS), conducted a multi-year program of research for U.S. Department of Energy (DOE) Office of Electricity Delivery and Energy Reliability (OE) to develop new methods, tools, and technologies to protect and enhance the reliability and efficiency of the U.S. electric power system as competitive electricity market structures evolve, and as the grid moves toward wide-scale use of decentralized generation (such as renewable energy sources) and demand-response programs. Phase I of OE’s funding for PSERC, under cooperative agreement DE-FC26-09NT43321, started in fiscal year (FY) 2009 and ended in FY2013. It was administered by DOE’s National Energy Technology Laboratory (NETL) through a cooperative agreement with Arizona State University (ASU). ASU provided sub-awards to the participating PSERC universities. This document is PSERC’s final report to NETL on the activities for OE, conducted through CERTS, from September 2015 through September 2017 utilizing FY 2014 to FY 2015 funding under cooperative agreement DE-OE0000670. PSERC is a thirteen-university consortium with over 30 industry members. Since 1996, PSERC has been engaged in research and education efforts with the mission of “empowering minds to engineer the future electric energy system.” Its work is focused on achieving: • An efficient, secure, resilient, adaptable, and economic electric power infrastructure serving society • A new generation of educated technical professionals in electric power • Knowledgeable decision-makers on critical energy policy issues • Sustained, quality university programs in electric power engineering. PSERC core research is funded by industry, with a budget supporting

  2. Low-rank coal research

    Energy Technology Data Exchange (ETDEWEB)

    Weber, G. F.; Laudal, D. L.

    1989-01-01

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  3. Sustainable development with clean coal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-08-01

    This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

  4. PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS

    Energy Technology Data Exchange (ETDEWEB)

    Dady Dadyburjor; Philip R. Biedler; Chong Chen; L. Mitchell Clendenin; Manoj Katakdaunde; Elliot B. Kennel; Nathan D. King; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-08-31

    economically competitive with current processes, and yet be environmentally friendly as well. The solvent extraction process developed uses mild hydrogenation of low cost oils to create powerful solvents that can dissolve the organic portion of coal. The insoluble portion, consisting mainly of mineral matter and fixed carbon, is removed via centrifugation or filtration, leaving a liquid solution of