Coal combustion aerothermochemistry research. Final report

Energy Technology Data Exchange (ETDEWEB)

Witte, A.B.; Gat, N.; Denison, M.R.; Cohen, L.M.

1980-12-15

On the basis of extensive aerothermochemistry analyses, laboratory investigations, and combustor tests, significant headway has been made toward improving the understanding of combustion phenomena and scaling of high swirl pulverized coal combustors. A special attempt has been made to address the gap between scientific data available on combustion and hardware design and scaling needs. Both experimental and theoretical investigations were conducted to improve the predictive capability of combustor scaling laws. The scaling laws derived apply to volume and wall burning of pulverized coal in a slagging high-swirl combustor. They incorporate the findings of this investigation as follows: laser pyrolysis of coal at 10/sup 6/ K/sec and 2500K; effect of coal particle shape on aerodynamic drag and combustion; effect of swirl on heat transfer; coal burnout and slag capture for 20 MW/sub T/ combustor tests for fine and coarse coals; burning particle trajectories and slag capture; particle size and aerodynamic size; volatilization extent and burnout fraction; and preheat level. As a result of this work, the following has been gained: an increased understanding of basic burning mechanisms in high-swirl combustors and an improved model for predicting combustor performance which is intended to impact hardware design and scaling in the near term.

Wabash River Coal Gasification Repowering Project: A DOE Assessment; FINAL

International Nuclear Information System (INIS)

National Energy Technology Laboratory

2002-01-01

The goal of the U.S. Department of Energy (DOE) Clean Coal Technology Program (CCT) is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage. This document serves as a DOE post-project assessment (PPA) of a project selected in CCT Round IV, the Wabash River Coal Gasification Repowering (WRCGR) Project, as described in a Report to Congress (U.S. Department of Energy 1992). Repowering consists of replacing an existing coal-fired boiler with one or more clean coal technologies to achieve significantly improved environmental performance. The desire to demonstrate utility repowering with a two-stage, pressurized, oxygen-blown, entrained-flow, integrated gasification combined-cycle (IGCC) system prompted Destec Energy, Inc., and PSI Energy, Inc., to form a joint venture and submit a proposal for this project. In July 1992, the Wabash River Coal Gasification Repowering Project Joint Venture (WRCGRPJV, the Participant) entered into a cooperative agreement with DOE to conduct this project. The project was sited at PSI Energy's Wabash River Generating Station, located in West Terre Haute, Indiana. The purpose of this CCT project was to demonstrate IGCC repowering using a Destec gasifier and to assess long-term reliability, availability, and maintainability of the system at a fully commercial scale. DOE provided 50 percent of the total project funding (for capital and operating costs during the demonstration period) of$438 million. Construction for the demonstration project was started in July 1993. Pre-operational tests were initiated in August 1995, and construction was completed in November 1995. Commercial operation began in November 1995, and the demonstration period was completed in December

Recovery of Rare Earth Elements from Coal and Coal Byproducts via a Closed Loop Leaching Process: Final Report

Energy Technology Data Exchange (ETDEWEB)

Peterson, Richard [Battelle Memorial Inst., Columbus, OH (United States); Heinrichs, Michael [Battelle Memorial Inst., Columbus, OH (United States); Argumedo, Darwin [Battelle Memorial Inst., Columbus, OH (United States); Taha, Rachid [Battelle Memorial Inst., Columbus, OH (United States); Winecki, Slawomir [Battelle Memorial Inst., Columbus, OH (United States); Johnson, Kathryn [Battelle Memorial Inst., Columbus, OH (United States); Lane, Ann [Battelle Memorial Inst., Columbus, OH (United States); Riordan, Daniel [Battelle Memorial Inst., Columbus, OH (United States)

2017-08-31

REEs using the ADP technology. In AOI 1, Ohio coal sources with the potential to provide a consistent source of rare earth element concentrations above 300 parts per million will be identified. Coal sample inventories from West Virginia and Pennsylvania will also be assessed for purposes of comparison. Three methods of preparing the coal ash will be evaluated for their potential to enhance the technical feasibility and economics of REE recovery. Three sources of coal ash are targeted for evaluation of the economics of REE recovery in this project: (1) coal ash from power generation stations, to include fly ash and/or bottom ash, (2) ash generated in a lower temperature ashing process, and (3) ash residual from Battelle’s coal liquefaction process. Making use of residual ash from coal liquefaction processes directly leverages work currently being conducted by Battelle for DOE NETL in response to DE-FOA-0000981 entitled “Greenhouse Gas Emissions Reductions Research and Development Leading to Cost-Competitive Coal-to-Liquids Based Jet Fuel Production.” Using the sample characterization results and regional information regarding REE concentration, availability and cost, a TEA will be developed. The previously generated laboratory testing results for leaching and REE recovery via the ADP will be used to perform the TEA, along with common engineering assumptions for scale up of equipment and labor costs. Finally, upon validation of the economic feasibility of the process by the TEA, limited laboratory testing will be performed to support the design of a bench scale system. In a future project phase, it is envisioned that the bench scale system will be constructed and operated to prove the process on a continuous basis.

Coal rebounds for the final quarter

Energy Technology Data Exchange (ETDEWEB)

Soras, C.; Stodden, J.

1987-11-01

Coal production in the USA is up 0.3% by the end of September 1987 from the pace of one year ago. Most impressive has been the growth in demand at power plants where coal consumption is up by 13.5 million tons through the month of July. The coal markets turnabout is based upon the entire economic spectrum not upon a single large market. US steel mills represent intense power consuming activities as do the US chemicals, plastics, paper and pulp industries.

International Coal Report's coal year 1991

Energy Technology Data Exchange (ETDEWEB)

McCloskey, G [ed.

1991-05-31

Following introductory articles on factors affecting trade in coal and developments in the freight market, tables are given for coal exports and coal imports for major countries worldwide for 1989 and 1990. Figures are also included for coal consumption in Canada and the Eastern bloc,, power station consumption in Japan, coal supply and demand in the UK, electric utility coal consumption and stocks in the USA, coal production in Australia, Canada and USA by state, and world hard coal production. A final section gives electricity production and hard coal deliveries in the EEC, sales of imported and local coal and world production of pig iron and steel.

E-commerce finally finds the coal industry

Energy Technology Data Exchange (ETDEWEB)

Hudson, M.

2000-12-01

In the last few months, new web sites have come online which are not only showcase for coal mining products and equipment but also act as sales platforms. A large set of sites deal with the purchase of coal and other raw materials. Most of them offer 24-hour news updates, a coal library and a reference section to help with financing, insurance and transportation of purchased coal. Another group focuses on the sale of equipment. Short writeups are given of 18 web sites. 1 photo.

Formation and retention of methane in coal. Final report

Energy Technology Data Exchange (ETDEWEB)

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Adsorption of anionic dyes from aqueous solutions onto coal fly ash and zeolite synthesized from coal fly ash

International Nuclear Information System (INIS)

Carvalho, Terezinha Elizabeth Mendes de

2010-01-01

Coal fly ash, a waste generated in coal-fired electric power plant, was used to synthesize zeolite by hydrothermal treatment with NaOH solution. The fly ash (CL-2) and this synthesized zeolite (ZM-2) that was characterized as hydroxy-sodalite were used as adsorbents for anionic dyes indigo carmine (IC), and reactive orange 16 (RO16) from aqueous solutions. Effects of contact time, initial dye concentration, pH, adsorbent mass, and temperature were evaluated in the adsorption processes. The kinetics studies indicated that the adsorption followed the pseudo-second order kinetics and that surface adsorption and intraparticle diffusion were involved in the adsorption mechanism. The thermodynamics parameters demonstrated that the adsorption was spontaneous for all adsorption processes. The enthalpy data confirmed the endothermic nature for all adsorption processes except for IC/ZM-2 system which was exothermic. The entropy data showed an increased disorder at the solid/solution interface during the adsorption for all systems except for IC/ZM-2 whose negative entropy value indicated a decreased disorder at the interface. The adsorption isotherms were closely fitted to the Langmuir linear equation. The maximum adsorption capacities were 1.48 mg/g for the IC/CL-2 system; 1.13 mg/g for IC/ZM-2; 0.96 mg/g for RO16/CL-2, and 1.14 mg/g for RO16/ZM-2 at room temperature. The desorption study carried out with water, with acid aqueous solutions, and with an alkali aqueous solution showed to be inefficient both for recovering the dyes and regenerating the adsorbents. (author)

Molecular accessibility in solvent swelled coals. Final report

Energy Technology Data Exchange (ETDEWEB)

Kispert, L.D.

1994-04-01

The conversion of coal by an economically feasible catalytic method requires the catalyst to diffuse into the coal sample so that hydrogenation catalysis can occur from within as well as the normal surface catalysis. Thus an estimate of the size, shape, and reactivity, of the pores in the coal before and after the swelling with different solvents is needed so that an optimum sized catalyst will be used. This study characterizes the accessible area found in Argonne Premium Coal Samples (APCS) using a EPR spin probe technique. The properties deduced in this manner correlate well with the findings deduced from SANS, NMR, SEM, SAXS and light scattering measurements. The use of nitroxide spin probes with swelling solvents is a simple way in which to gain an understanding of the pore structure of coals, how it changes in the presence of swelling solvents and the chemistry that occurs at the pore wall. Hydrogen bonding sites occur primarily in low-rank coals and vary in reactive strength as rank is varied. Unswelled coals contain small, spherical pores which disappear when coal is swelled in the presence of polar solvents. Swelling studies of polystyrene-divinyl benzene copolymers implied that coal is polymeric, contains significant quantities of covalent cross-links and the covalent cross-link density increases with rank.

Integrated coal preparation

International Nuclear Information System (INIS)

Buchanan, D.J.; Jones, T.F.

1992-01-01

Perceptions of quality have changed over the years. The attributes of a certain coal (its rank, slagging propensity, ash content etc) are traditionally referred to as its quality. However, the subject of this paper is quality in a much wider sense: quality as fitness for purpose: and all that such a wide definition entails. British Standard BS 5750 (ISO 9000) Quality Systems defines a systems approach to quality, and includes both the supplier of raw materials and the final customer within this boundary. Coal preparation starts at the production face. The greater the proportion of dirt in run-of-mine product the greater the challenge in satisfying the customer's needs. Significant advances have been made in minimizing mined dirt. For example, the sue of vertical steering on longwall faces improves productivity and quality. Unfortunately modern mining methods produce large quantities of fines, despite efforts to reduce them at the point of production and during transportation to the surface. Coal preparation also produces further fines. It has been estimated that fine coal costs 2.5 times as much to clean as large coal, and the costs of handing wet fine coal product will inflate this estimate. Handling considerations rightly concern our customers and are part of the wider meaning of quality. In this paper the authors address some novel solutions to the challenge posed by fines

Sorption of chlorophenols from aqueous solution by granular activated carbon, filter coal, pine and hardwood.

Science.gov (United States)

Hossain, G S M; McLaughlan, R G

2012-09-01

Wood and coal, as low-cost sorbents, have been evaluated as an alternative to commercial granular activated carbon (GAC) for chlorophenol removal. Kinetic experiments indicated that filter coal had a significantly lower rate of uptake (approximately 10% of final uptake was achieved after three hours) than the other sorbents, owing to intra-particle diffusion limitations. The data fitted a pseudo-second-order model. Sorption capacity data showed that GAC had a high sorption capacity (294-467 mg g(-1)) compared with other sorbents (3.2-7.5 mg(g-1)). However, wood and coal had a greater sorption capacity per unit surface area than GAC. Sorption equilibrium data was best predicted using a Freundlich adsorption model. The sorption capacity for all sorbents was 2-chlorophenol coal than the other sorbents. The results showed that pine, hardwood and filter coal can be used as sorbent materials for the removal of chlorophenol from water; however, kinetic considerations may limit the application of filter coal.

Low severity conversion of activated coal. Final report

Energy Technology Data Exchange (ETDEWEB)

Hirschon, A.S.; Ross, D.S.

1990-01-01

The results suggest that coal contains regions with structural components significantly reactive under the hydrothermal environment. Although the specific mechanism for this process remains to be developed, this activity is reminiscent of findings in studies of accelerated maturation of oil shale, where hydrothermal treatment (hydrous pyrolysis) leads to the production of petroleum hydrocarbons. In line with what has been seen in the oil shale work, the pretreatment-generated hydrocarbons and phenols appear to represent a further or more complete maturation of some fraction of the organic material within the coal. These observations could have an impact in two areas. The first is in the area of coal structure, where immature, reactive regions have not been included in the structures considered at present. The second area of interest is the more practical one of conversions to coal liquids and pyrolytic tars. It seems clear that the hydrothermal pretreatment changes the coal in some manner that favorably affects the product quality substantially and, as in the CO/water liquefaction case, favorably affects the yields. The conversions of coals of lower rank, i.e., less mature coals, could particularly benefit in terms of both product quality and product quantity. The second portion of this project also shows important benefits to coal conversion technology. It deals with synthesizing catalysts designed to cleave the weak links in the coal structure and then linking these catalysts with the pretreatment methods in Task 2. The results show that highly dispersed catalysts can effectively be used to increase the yields of soluble material. An important aspect of highly dispersed catalysts are that they can effectively catalyze coal conversion even in poor liquefaction solvents, thus making them very attractive in processes such as coprocessing where inexpensive liquefaction media such as resids are used.

Healy Clean Coal Project: Healy coal firing at TRW Cleveland Test Facility. Final report

Energy Technology Data Exchange (ETDEWEB)

Koyama, T.; Petrill, E.; Sheppard, D.

1991-08-01

A test burn of two Alaskan coals was conducted at TRW`s Cleveland test facility in support of the Healy Clean Coal Project, as part of Clean Coal Technology III Program in which a new power plant will be constructed using a TRW Coal Combustion System. This system features ash slagging technology combined with NO{sub x} and SO{sub x} control. The tests, funded by the Alaska Industrial Development and Export Authority (AIDEA) and TRW, were conducted to verify that the candidate Healy station coals could be successfully fired in the TRW coal combustor, to provide data required for scale-up to the utility project size requirements, and to produce sufficient flash-calcined material (FCM) for spray dryer tests to be conducted by Joy/NIRO. The tests demonstrated that both coals are viable candidates for the project, provided the data required for scale-up, and produced the FCM material. This report describes the modifications to the test facility which were required for the test burn, the tests run, and the results of the tests.

Advanced physical fine coal cleaning spherical agglomeration. Final report

Energy Technology Data Exchange (ETDEWEB)

1990-09-01

The project included process development, engineering, construction, and operation of a 1/3 tph proof-of-concept (POC) spherical agglomeration test module. The POC tests demonstrated that physical cleaning of ultrafine coal by agglomeration using heptane can achieve: (1) Pyritic sulfur reductions beyond that possible with conventional coal cleaning methods; (2) coal ash contents below those which can be obtained by conventional coal cleaning methods at comparable energy recoveries; (3) energy recoveries of 80 percent or greater measured against the raw coal energy content; (4) complete recovery of the heptane bridging liquid from the agglomerates; and (5) production of agglomerates with 3/8-inch size and less than 30 percent moisture. Test results met or exceeded all of the program objectives. Nominal 3/8-inch size agglomerates with less than 20 percent moisture were produced. The clean coal ash content varied between 1.5 to 5.5 percent by weight (dry basis) depending on feed coal type. Ash reductions of the run-of-mine (ROM) coal were 77 to 83 percent. ROM pyritic sulfur reductions varied from 86 to 90 percent for the three test coals, equating to total sulfur reductions of 47 to 72 percent.

Analysis on safety production in coal mines Henan Province

Institute of Scientific and Technical Information of China (English)

KONG Liu-an; ZHANG Wen-yong

2006-01-01

Based on the rigorous situation of safety production in coal mines, the paper analyzed the statistical data of recent accidents indexes in Henan's coal mines. Using investigation and comparison analysis methods, a specified analysis on mining conditions, technical facility level, safety input and vocational quality of workers in Henan's coal mines was conducted. The result indicates that there have been existing such main safety production problems as weak safety management, low-level facilities, inadequate safety input and poor vocational quality and so on. Finally it proposes such reference solutions as to establish and perfect coal mining supervision and management system, to increase safety investment into techniques and facilities and to strengthen workers' safety education and introduction of more high-level professional talents.

Thermodynamics of CoAl2O4-CoGa2O4 solid solutions

International Nuclear Information System (INIS)

Lilova, Kristina I.; Navrotsky, Alexandra; Melot, Brent C.; Seshadri, Ram

2010-01-01

CoAl 2 O 4 , CoGa 2 O 4 , and their solid solution Co(Ga z Al 1-z ) 2 O 4 have been studied using high temperature oxide melt solution calorimetry in molten 2PbO.B 2 O 3 at 973 K. There is an approximately linear correlation between lattice parameters, enthalpy of formation from oxides, and the Ga content. The experimental enthalpy of mixing is zero within experimental error. The cation distribution parameters are calculated using the O'Neill and Navrotsky thermodynamic model. The enthalpies of mixing calculated from these parameters are small and consistent with the calorimetric data. The entropies of mixing are calculated from site occupancies and compared to those for a random mixture of Ga and Al ions on octahedral site with all Co tetrahedral and for a completely random mixture of all cations on both sites. Despite a zero heat of mixing, the solid solution is not ideal in that activities do not obey Raoult's Law because of the more complex entropy of mixing. - Graphical abstract: Measured enthalpies of mixing of CoAl 2 O 4 -CoGa 2 O 4 solid solutions are close to zero but entropies of mixing reflect the complex cation distribution, so the system is not an ideal solution.

China and Indonesia Coal Trade Present and Future after the 2008 Financial Crisis

Directory of Open Access Journals (Sweden)

Chunchun Luo

2014-04-01

Full Text Available The policy of “zero tariff” has solved the problem of domestic coal using since 2008, but also raised the coal trade between China and Indonesia. However, some factors have affected on the coal trade in recent years, such as the Indonesian raising domestic demand reduced exports and Chinese policies for Indonesian coal imports controls. This article through to analysis the current situation and import and export capacity of the coal trade between China and Indonesia, utilizing the judgment index of regional economics, it is concluded that the comparative advantage of China and the degree of complementary, then illustrates the problems and solution suggestions in the process of coal trade between the two countries, finally prospects the coal trade of China and Indonesia.

Fundamental study for improvement of dewatering of fine coal/refuse. Final report, August 1981-December 1984

Energy Technology Data Exchange (ETDEWEB)

Chiang, S.H.; Klinzing, G.E.; Morsi, B.I.; Tierney, J.W.; Binkley, T.; Chi, S.M.; Huang, S.; Qamar, I.; Venkatadri, R.

1984-12-01

Fine coal in slurry form must be dewatered to minimize handling and transportation problems and be reduced to a desirable level for subsequent preparation of coal/water mixtures as a substitute utility fuel. The current practice is inadequate for the dewatering of fine coal, particularly for coal particles with sizes smaller than 400 mesh. Therefore, it is most desirable to develop improved mechanical methods for reducing the moisture content of fine coal. In the light of this, a fundamental study of the dewatering of fine coal/refuse was initiated in June 1979 and continued through 1984. The overall objective of the study is to seek improved methods of dewatering through a better understanding of the filtration and post-filtration processes. As a first step, efforts have been focused on the mechanism of dewatering in terms of the basic properties of coal (and refuse) particles and the microstructures of filter cakes, and their relations to filtration rate and final moisture content. Pittsburgh seam-Bruceton Mine coal was used as a base coal. During the past year, filter cakes from coals with widely varying size ranges were micrographically characterized. The effects of a number of surface active agents and of entrapped air bubbles on the filter cake properties were also studied. Modules of the network model for calculating single phase and two phase permeabilities were formulated and tested. The report is divided into four parts: summary and deliverables; work forecast for 1984-1985; detailed description of technical progress; and appendices. 21 refs., 55 figs., 17 tabs.

Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification

Energy Technology Data Exchange (ETDEWEB)

None

1982-01-01

This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

Coal surface structure and thermodynamics. Final report

Energy Technology Data Exchange (ETDEWEB)

Larsen, J.W.; Wernett, P.C.; Glass, A.S.; Quay, D.; Roberts, J.

1994-05-01

Coals surfaces were studied using static surface adsorption measurements, low angle x-ray scattering (LAXS), inverse gas chromatography (IGC) and a new {sup 13}C NMR relaxation technique. A comparison of surface areas determined by hydrocarbon gas adsorption and LAXS led to the twin conclusions that the hydrocarbons had to diffuse through the solid to reach isolated pores and that the coal pores do not form interconnected networks, but are largely isolated. This conclusion was confirmed when IGC data for small hydrocarbons showed no discontinuities in their size dependence as usually observed with porous solids. IGC is capable of providing adsorption thermodynamics of gases on coal surfaces. The interactions of non-polar molecules and coal surfaces are directly proportioned to the gas molecular polarizability. For bases, the adsorption enthalpy is equal to the polarizability interaction plus the heat of hydrogen bond formation with phenol. Amphoteric molecules have more complex interactions. Mineral matter can have highly specific effects on surface interactions, but with most of the molecules studied is not an important factor.

Temperature prediction in a coal fired boiler with a fixed bed by fuzzy logic based on numerical solution

International Nuclear Information System (INIS)

Biyikoglu, A.; Akcayol, M.A.; Oezdemir, V.; Sivrioglu, M.

2005-01-01

In this study, steady state combustion in boilers with a fixed bed has been investigated. Temperature distributions in the combustion chamber of a coal fired boiler with a fixed bed are predicted using fuzzy logic based on data obtained from the numerical solution method for various coal and air feeding rates. The numerical solution method and the discretization of the governing equations of two dimensional turbulent flow in the combustion chamber and one dimensional coal combustion in the fixed bed are explained. Control Volume and Finite Difference Methods are used in the discretization of the equations in the combustion chamber and in the fixed bed, respectively. Results are presented as contours within the solution domain and compared with numerical ones. Comparison of the results shows that the difference between the numerical solution and fuzzy logic prediction throughout the computational domain is less than 1.5%. The statistical coefficient of multiple determinations for the investigated cases is about 0.9993 to 0.9998. This accuracy degree is acceptable in predicting the temperature values. So, it can be concluded that fuzzy logic provides a feasible method for defining the system properties

Coal

International Nuclear Information System (INIS)

Teissie, J.; Bourgogne, D. de; Bautin, F.

2001-12-01

Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

Technical data. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project, Converse County, Wyoming

Energy Technology Data Exchange (ETDEWEB)

None

1982-01-01

This volume includes a description of the railway to transport the coal; possible unbalance in the electrical power supply is considered in detail, as well as communications, signalling, etc. The railway will also be used to transport ashes and sludges for waste disposal. Coal fines in the coal supply will be burned to generate power. A very brief description of the coal gasification plant and its components is accompanied by a printout of the dates final engineering is to be completed. Permit applications are listed and socio-economic factors are discussed. The financing plan is discussed in some detail: basically, a loan guarantee from the Synthetic Fuels Corporation; equity provided by investment tax credit, deferred taxes, AFUDC and the sponsors; price support; and gas purchase agreement (this whole section includes several legal details.). (LTN)

Nuclear assay of coal. Volume 6. Mass flow devices for coal handling. Final report

International Nuclear Information System (INIS)

Gozani, T.; Elias, E.; Bevan, R.

1980-04-01

The mass of coal entering the boiler per unit time is an essential parameter for determining the total rate of heat input. The mass flow rate of coal on a conveyor belt is generally determined as a product of the instantaneous mass of material on a short section of the belt and the belt velocity. Belt loading could be measured by conventional transducers incorporating mechanical or electromechanical weighers or by gamma-ray attenuation gauge. This report reviews the state of the art in mass flow devices for coal handling. The various methods are compared and commented upon. Special design issues are discussed relative to incorporating a mass flow measuring device in a Continuous On-Line Nuclear Analysis of Coal (CONAC) system

REMOVAL OF ASTROZON RED FROM AQUEOUS SOLUTIONS BY THE ADSORBENTS PRODUCED FROM LIGNITE COAL

Directory of Open Access Journals (Sweden)

Mehmet MAHRAMANLIOĞLU

2002-01-01

Full Text Available The adsorption of Astrozone Red on the activated coal from aqueous solutions was studied.The adsorption process followed the Lagergren first order kinetics equation. The adsorbent concentration affected the adsorption of Astrozone Red significiantly.The equilibrium data fit well in the Langmuir model and isotherm constants were calculated. The adsorption of Astrozon Red increased with increase of the pH value in the solution.The thermodynamics of adsorption indicated spontaneous and exothermic nature of the process.

Applied research and evaluation of process concepts for liquefaction and gasification of western coals. Final report

Energy Technology Data Exchange (ETDEWEB)

Wiser, W. H.

1980-09-01

Fourteen sections, including five subsections, of the final report covering work done between June 1, 1975 to July 31, 1980 on research programs in coal gasification and liquefaction have been entered individually into EDB and ERA. (LTN)

Potential for thermal coal and Clean Coal Technology (CCT) in the Asia-Pacific. Final technical report

Energy Technology Data Exchange (ETDEWEB)

Johnson, C.J.; Long, S.

1991-11-22

The Coal Project was able to make considerable progress in understanding the evolving energy situation in Asia and the future role of coal and Clean Coal Technologies. It is clear that there will be major growth in consumption of coal in Asia over the next two decades -- we estimate an increase of 1.2 billion metric tons. Second, all governments are concerned about the environmental impacts of increased coal use, however enforcement of regulations appears to be quite variable among Asian countries. There is general caution of the part of Asian utilities with respect to the introduction of CCT`s. However, there appears to be potential for introduction of CCT`s in a few countries by the turn of the century. It is important to emphasize that it will be a long term effort to succeed in getting CCT`s introduced to Asia. The Coal Project recommends that the US CCT program be expanded to allow the early introduction of CCT`s in a number of countries.

Insight conference reports : proceedings of the clean coal summit : business strategies, solutions and risk management in uncertain regulatory times

International Nuclear Information System (INIS)

2006-01-01

This conference was held to examine business options and risk management solutions in clean coal technologies. The conference was attended by coal industry representatives as well as members of both governmental and non-governmental agencies, who examined recent energy regulations and policies as well as a variety of issues related to sustainable energy development. Issues related to the attrition of Canada's older power plants were discussed and new coal gasification technologies were reviewed. The conference also addressed issues concerning public opinion and First Nations people. Conventional coal energy options were discussed along with advancements in emissions control technologies with particular reference to the role of clean coal science and technology. The conference featured 14 presentations, of which 4 have been catalogued separately for inclusion in this database. refs., tabs., figs

Final Safety Assessment of Coal Tar as Used in Cosmetics

Energy Technology Data Exchange (ETDEWEB)

NONE

2008-07-01

Coal Tar is a semisolid by-product obtained in the destructive distillation of bituminous coal, which functions in cosmetic products as a cosmetic biocide and denaturant-antidandruff agent is also listed as a function, but this is considered an over-the-counter (OTC) drug use. In 2002, Coal Tar was reported to the Food and Drug Administration (FDA) to be used in four formulations, all of which appear to be OTC drug products. Coal Tar is monographed by the FDA as Category I (safe and effective) OTC drug ingredient for use in the treatment of dandruff, seborrhoea, and psoriasis. Coal Tar is absorbed through the skin of animals and humans and is systemically distributed. Although the Cosmetic Ingredient Review (CIR) Expert Panel believes that Coal Tar use as an antidandruff ingredient in OTC drug preparations is adequately addressed by the FDA regulations, the Panel also believes that the appropriate concentration of use of Coal Tar in cosmetic formulations should be that level that does not have a biological effect in the user. Additional data needed to make a safety assessment include product types in which Coal Tar is used (other than as an OTC drug ingredient), use concentrations, and the maximum concentration that does not induce a biological effect in users.

Non-covalent associative structure of coal

Energy Technology Data Exchange (ETDEWEB)

Shui, H. [Anhui University of Technology, Maanshan (China). School of Chemistry and Chemical Engineering

2004-06-01

The recent progress of non-covalent associative structure of coal and the mechanisms of the carbon disulphide-N-methyl-2-pyrrolidone (CS{sub 2}/NMP) are mixed solvent and the additive addition enhancing the extraction yield of coals are reviewed, and the aggregation behaviour of coal in solid and solution states are presented, and the aggregation behavior of coal in solid and solution states are introduced in this paper. Coal extraction and swelling in organic solvents at room temperature were the most useful methods to understand the associative structure of coal. CS{sub 2}/NMP is a unique solvent to give high extraction yields for some bituminous coals. Some additives such as tetracyanoethylene (TCNE) can dissociate the stronger interactions among coal molecules and enhance the extraction yields of coal in the mixed solvent. 37 refs., 1 fig.

Removal of mercury ion from aqueous solution by activated carbons obtained from biomass and coals

Energy Technology Data Exchange (ETDEWEB)

Ekinci, E.; Yardim, F. [Faculty of Chemical Engineering, Istanbul Technical University, Ayazaga, 80626 Istanbul (Turkey); Budinova, T.; Petrov, N.; Razvigorova, M.; Minkova, V. [Institute of Organic Chemistry, Bulgarian Academy of Sciences, Acad.G.Bonchev, str. bl. 9, Sofia (Bulgaria)

2002-06-20

The adsorption of Hg(II) from aqueous solution at 293 K by activated carbons obtained from apricot stones, furfural and coals was studied. Adsorption studies were performed under the varying conditions of time of treatment, metal ion concentration and pH. The process of adsorption followed Langmuir isotherm. The removal of Hg(II) increased with the increase of pH of the solution from 2 to 5 and remained constant up to pH 10. Desorption studies were preformed.

Removal of organic and inorganic sulfur from Ohio coal by combined physical and chemical process. Final report

Energy Technology Data Exchange (ETDEWEB)

Attia, Y.A.; Zeky, M.El.; Lei, W.W.; Bavarian, F.; Yu, S. [Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering

1989-04-28

This project consisted of three sections. In the first part, the physical cleaning of Ohio coal by selective flocculation of ultrafine slurry was considered. In the second part, the mild oxidation process for removal of pyritic and organic sulfur.was investigated. Finally, in-the third part, the combined effects of these processes were studied. The physical cleaning and desulfurization of Ohio coal was achieved using selective flocculation of ultrafine coal slurry in conjunction with froth flotation as flocs separation method. The finely disseminated pyrite particles in Ohio coals, in particular Pittsburgh No.8 seam, make it necessary to use ultrafine ({minus}500 mesh) grinding to liberate the pyrite particles. Experiments were performed to identify the ``optimum`` operating conditions for selective flocculation process. The results indicated that the use of a totally hydrophobic flocculant (FR-7A) yielded the lowest levels of mineral matters and total sulfur contents. The use of a selective dispersant (PAAX) increased the rejection of pyritic sulfur further. In addition, different methods of floc separation techniques were tested. It was found that froth flotation system was the most efficient method for separation of small coal flocs.

Chemical kinetics and transport processes in supercritical fluid extraction of coal. Final report, August 10, 1990--December 30, 1992

Energy Technology Data Exchange (ETDEWEB)

McCoy, B.J.; Smith, J.M.; Wang, M.; Zhang, C.J.

1993-02-01

The overall objective of this project was to study the supercritical fluid extraction of hydrocarbons from coal. Beyond the practical concern of deriving products from coal, the research has provided insights into the structure, properties, and reactivities of coal. Information on engineering fundamentals of coal thermolysis and extraction, including physical and chemical processes, is presented in this final report. To accomplish the goals of the project we developed continuous-flow experiments for fixed-bed samples of coal that allow two types of analysis of the extract: continuous spectrophotometric absorbance measurements of the lumped concentration of extract, and chromatographic determinations of molecular-weight distributions as a function of time. Thermolysis of coal yields a complex mixture of many extract products whose molecular-weight distribution (MWD) varies with time for continuous-flow, semibatch experiments. The flow reactor with a differential, fixed bed of coal particles contacted by supercritical t-butanol was employed to provide dynamic MWD data by means of HPLC gel permeation chromatography of the extract. The experimental results, time-dependent MWDs of extract molecules, were interpreted by a novel mathematical model based on continuous-mixture kinetics for thermal cleavage of chemical bonds in the coal network. The parameters for the MWDs of extractable groups in the coal and the rate constants for one- and two-fragment reaction are determined from the experimental data. The significant effect of temperature on the kinetics of the extraction was explained in terms of one- and two-fragment reactions in the coal.

Nuclear assay of coal. Volume 4. Moisture determination in coal: survey of electromagnetic techniques. Final report

International Nuclear Information System (INIS)

Bevan, R.; Luckie, P.; Gozani, T.; Brown, D.R.; Bozorgmanesh, H.; Elias, E.

1979-01-01

This survey consists of two basic parts. The first consists of a survey of various non-nuclear moisture determination techniques. Three techniques are identified as promising for eventual on-line application with coal; these are the capacitance, microwave attenuation, and nuclear magnetic resonance (NMR) techniques. The second part is devoted to an in-depth analysis of these three techniques and the current extent to which they have been applied to coal. With a given coal type, accuracies of +- 1% absolute in moisture content are achievable with all three techniques. The accuracy of the two electromagnetic techniques has been demonstrated in the laboratory and on-line in coal burning plants, whereas only small samples have been analyzed with NMR. The current shortcoming of the simple electromagnetic techniques is the sensitivity of calibrations to physical parameters and coal type. NMR is currently limited by small sample sizes and non-rugged design. These findings are summarized and a list of manufacturers of moisture analyzers is given in the Appendix

Separation of the constituents of coal

Energy Technology Data Exchange (ETDEWEB)

Betrand, M F

1938-12-06

A process is disclosed of separating, by means of dense aqueous solutions, the constituents of coal, isolated by preliminary crushing from each other and/or from barren and carbonaceous shales, comprising the addition to the washing water before treatment or during any stage of the preparation of the coal before separation, or to the dense separating solution of agents improving the wetting of the coal by water.

Nuclear assay of coal. Volume 7. Coal rheology and its impact on nuclear assay. Final report

International Nuclear Information System (INIS)

Hogg, R.; Luckie, P.; Gozani, T.

1979-01-01

A number of possible techniques for introducing coal to a continuous on-line nuclear analysis of coal (CONAC) system have been evaluated, including flow methods and nonflow methods. A modified flat-belt feeder system was recommended. The success of such a coal-presentation technique would rely on proper entry to the feed hopper, shape of the withdrawal opening from the feed hopper, and a slow belt speed to minimize demixing

Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

Energy Technology Data Exchange (ETDEWEB)

1986-12-01

Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

Permeability changes in coal resulting from gas desorption. Final report

Energy Technology Data Exchange (ETDEWEB)

Levine, J.R.; Johnson, P.W.

1992-11-30

This report documents studies on the effects of gas sorption on coal, with the intent of eventually evaluating how sorption and strain affect permeability. These studies were, carried out at the University of Alabama during the period from 1989 through 1992. Two major experimental methods were developed and used. In the strain experiments, electronic strain gauges were attached to polished blocks of coal in order to measure linear and volumetric swelling due to gas sorption. The effects of bedding plane orientation, of gas type, and of coal type were investigated. In the gravimetric experiment the weight of small samples of coal was measured during exposure to high pressure gases. Sample measurements were corrected for buoyancy effects and for sample swelling, and the results were plotted in the form of Langmuir isotherms. Experiments were conducted to determine the effect of grain size, coal type, moisture, and of sorbant gas. The advantage of this method is that it can be applied to very small samples, and it enabled comparison liptinite versus vitrinite concentrates, and kerogen rich versus kerogen depleted oil shales. Also included is a detailed discussion of the makeup of coal and its effect on gas sorption behavior.

Nuclear assay of coal. Volume 8. Continuous nuclear assay of coal (CONAC). Final report

International Nuclear Information System (INIS)

Lagarias, J.; Irminger, P.; Dodson, W.

1979-01-01

Using californium-252 as a source of exciting neutrons, prompt gamma photons emitted by elemental nuclei in the coal have been measured using several detectors, including sodium-iodide and germanium-lithium. Several coal types, including bituminous, subbituminous lignite and anthracite were crushed to various top sizes and analyzed carefully by traditional ASTM wet chemistry techniques at two or three different laboratories. The elements (sulfur, hydrogen, carbon, aluminum, silicon, iron, calcium, sodium, nitrogen, and chlorine) were determined by prompt neutron activations and the quantities compared with those of the wet chemical analyses. Since satisfactory correlation has been obtained at bench-scale level using 100 to 200 kG samples, an apparatus has been designed to analyze a coal stream of up to 50 ton/hour, at an electric power generating station

STUDY OF SOLVENT AND CATALYST INTERACTIONS IN DIRECT COAL LIQUEFACTION; FINAL

International Nuclear Information System (INIS)

Michael T. Klein; William H. Calkins; Jasna Tomic

2000-01-01

To provide a better understanding of the roles of a solid catalyst and the solvent in Direct Coal Liquefaction, a small reactor was equipped with a porous-walled basket which was permeable to the solvent but was not permeable to the coal or solid catalyst. With this equipment and a high volatile bituminous coal it was found that direct contact between the catalyst in the basket and the coal outside the basket is not required for catalyzed coal liquefaction. The character of the solvent in this system makes a significant difference in the conversion of the coal, the better solvents being strong donor solvents. Because of the extensive use of thermogravimetric analysis in this laboratory, it was noted that the peak temperature for volatiles evolution from coal was a reliable measure of coal rank. Because of this observation, a variety of coals of a range of ranks was investigated. It was shown in this work that measuring the peak temperature for volatiles evolution was a quite precise indicator of rank and correlated closely with the rank value obtained by measuring vitrinite reflectance, a more difficult measurement to make. This prompted the desire to know the composition of the volatile material evolved as a function of coal rank. This was then measured by coupling a TGA to a mass spectrometer using laser activation and photoionization detection TG-PI-MS. The predominant species in volatiles of low rank coal turned out to be phenols with some alkenes. As the rank increases, the relative amounts of alkene and aromatic hydrocarbons increases and the oxygenated species decrease. It was shown that these volatiles were actually pyrolytic products and not volatilization products of the coal. Solvent extraction experiments coupled with Thermogravimetric-photoionization-mass spectrometry (TG-PI-MS) indicated that the low boiling and more extractable material are essentially similar in chemical types to the non-extractable portions but apparently higher molecular weight

Australian black coal statistics 1991

Energy Technology Data Exchange (ETDEWEB)

1992-01-01

This third edition of Australian black coal statistics covers anthracite, bituminous and subbituminous coals. It includes maps and figures on resources and coal fields and statistics (mainly based on the calendar year 1991) on coal demand and supply, production, employment and productivity in Australian coal mines, exports, prices and ports, and domestic consumption. A listing of coal producers by state is included. A final section presents key statistics on international world trade in 1991. 54 tabs.

Coal; Le charbon

Energy Technology Data Exchange (ETDEWEB)

Teissie, J.; Bourgogne, D. de; Bautin, F. [TotalFinaElf, La Defense, 92 - Courbevoie (France)

2001-12-15

Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report

Energy Technology Data Exchange (ETDEWEB)

Chunshan Song; Schobert, H.H.; Parfitt, D.P. [and others

1997-11-01

Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

21st Century Coal: Advanced Technology and Global Energy Solution

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-06-01

Coal currently supplies with more than 40% of the world electricity consumption and it essential input of around 70% of world steel production, representing around 30% of the world primary energy supply. This is because coal is cheap, abundant, accessible, widely distributed and easy energy to transport, store and use. For these features, coal is projected to be intensively used in the future. Production and use of coal present a series of issues throughout the whole value chain. While existing technology allows addressing most of them (safety at work, land restoration, mercury, NOx and sulphur emissions avoidance, etc.), CO2 emissions continues to be the biggest challenge for coal use in the future. This report focuses on the technology path to near-zero emissions including useful insights in advanced coal power generation technologies and Carbon Capture, Utilisation and Storage, a promising technology with a large potential which can push Carbon Capture and Storage competitiveness. In addition, the report shows the features of the new generation of coal-fired power plants in terms of flexibility for dynamic operation and grid stability, requirements increasingly needed to operate on grids with significant wind and solar generation.

Coal upgrading

Energy Technology Data Exchange (ETDEWEB)

Nunes, S. [IEA Clean Coal Centre, London (United Kingdom)

2009-10-15

This report examines current technologies and those likely to be used to produce cleaner coal and coal products, principally for use in power generation and metallurgical applications. Consideration is also given to coal production in the leading coal producing countries, both with developed and developing industries. A range of technologies are considered. These include the coal-based liquid fuel called coal water mixture (CWM) that may compete with diesel, the production of ultra-clean coal (UCC) and coal liquefaction which competes with oil and its products. Technologies for upgrading coal are considered, especially for low rank coals (LRC), since these have the potential to fill the gap generated by the increasing demand for coal that cannot be met by higher quality coals. Potential advantages and downsides of coal upgrading are outlined. Taking into account the environmental benefits of reduced pollution achieved through cleaner coal and reduced transport costs, as well as other positive aspects such as a predictable product leading to better boiler design, the advantages appear to be significant. The drying of low rank coals improves the energy productively released during combustion and may also be used as an adjunct or as part of other coal processing procedures. Coal washing technologies vary in different countries and the implications of this are outlined. Dry separation technologies, such as dry jigging and electrostatic separation, are also described. The demonstration of new technologies is key to their further development and demonstrations of various clean coal technologies are considered. A number of approaches to briquetting and pelletising are available and their use varies from country to country. Finally, developments in upgrading low rank coals are described in the leading coal producing countries. This is an area that is developing rapidly and in which there are significant corporate and state players. 81 refs., 32 figs., 3 tabs.

Wabash River Coal Gasification Repowering Project: A DOE Assessment; FINAL

International Nuclear Information System (INIS)

National Energy Technology Laboratory

2002-01-01

The goal of the U.S. Department of Energy (DOE) Clean Coal Technology Program (CCT) is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage. This document serves as a DOE post-project assessment (PPA) of a project selected in CCT Round IV, the Wabash River Coal Gasification Repowering (WRCGR) Project, as described in a Report to Congress (U.S. Department of Energy 1992). Repowering consists of replacing an existing coal-fired boiler with one or more clean coal technologies to achieve significantly improved environmental performance. The desire to demonstrate utility repowering with a two-stage, pressurized, oxygen-blown, entrained-flow, integrated gasification combined-cycle (IGCC) system prompted Destec Energy, Inc., and PSI Energy, Inc., to form a joint venture and submit a proposal for this project. In July 1992, the Wabash River Coal Gasification Repowering Project Joint Venture (WRCGRPJV, the Participant) entered into a cooperative agreement with DOE to conduct this project. The project was sited at PSI Energy's Wabash River Generating Station, located in West Terre Haute, Indiana. The purpose of this CCT project was to demonstrate IGCC repowering using a Destec gasifier and to assess long-term reliability, availability, and maintainability of the system at a fully commercial scale. DOE provided 50 percent of the total project funding (for capital and operating costs during the demonstration period) of$438 million

Flash pyrolysis of coal-solvent slurry prepared from the oxidized coal and the coal dissolved in solvent; Ichibu yokaishita sanka kaishitsutan slurry no jinsoku netsubunkai

Energy Technology Data Exchange (ETDEWEB)

Maki, T.; Mae, K.; Okutsu, H.; Miura, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

1996-10-28

In order to develop a high-efficiency coal pyrolysis method, flash pyrolysis was experimented on slurry prepared by using liquid-phase oxidation reformed coal and a methanol-based solvent mixture. Australian Morwell coal was used for the experiment. The oxidized coal, into which carboxyl groups have been introduced, has the condensation structure relaxed largely, and becomes highly fluid slurry by means of the solvent. Char production can be suppressed by making the oxidation-pretreated coal into slurry, resulting in drastically improved pyrolytic conversion. The slurry was divided into dissolved solution, dried substance, extracted residue, and residual slurry, which were pyrolized independently. The dissolved solution showed very high conversion. Improvement in the conversion is contributed by separating the dissolved substances (coal macromolecules) at molecular levels, coagulating the molecules, suppressing cross-link formation, and reducing molecular weight of the dissolved substances. Oxidized coal can be dissolved to 80% or higher by using several kinds of mixed solvents. As a result of the dissolution, a possibility was suggested on pyrolysis which is easy in handling and high in conversion. 7 refs., 6 figs., 2 tabs.

Temperature effects on chemical structure and motion in coal. Final report

Energy Technology Data Exchange (ETDEWEB)

Maciel, G.E.

1996-09-30

The objective of this project was to apply recently developed, state-of-the-art nuclear magnetic resonance (NMR) techniques to examine in situ changes in the chemical structure and molecular/macromolecular motion in coal as the temperature is increased above room temperature. Although alterations in the chemical structure of coal have been studied previously by {sup 13}C NMR, using quenched samples, the goal of this project was to examine these chemical structural changes, and changes in molecular/macromolecular mobility that may precede or accompany the chemical changes, at elevated temperatures, using modern {sup 13}C and {sup 1}H NMR techniques, especially {sup 1}H dipolar-dephasing techniques and related experiments pioneered in the laboratory for examining pyridine-saturated coals. This project consisted of the following four primary segments and related efforts on matters relevant to the first four tasks. (1) {sup 1}H NMR characterization of coal structure and mobility as a function of temperature variation over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (2) {sup 1}H NMR characterization of coal structure, mobility and conversion as a function of temperature variation over a temperature range (240--500 C) for which chemical transformations of coal are known to occur. (3) {sup 13}C NMR investigation of coal structure/mobility as a function of temperature over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (4) {sup 13}C NMR investigation of coal structure, dynamics and conversion as a function of temperature variation over a range (240--500 C) for which chemical transformations of coal are known to occur. (5) Related matters relevant to the first four tasks: (a) {sup 1}H CRAMPS NMR characterization of oil shales and their kerogen concentrates; and (b) improved quantitation in {sup 13}C MAS characterization of coals.

Clean utilization of coal

International Nuclear Information System (INIS)

Yueruem, Y.

1992-01-01

This volume contains 23 lectures presented at the Advanced Study Institute on 'Chemistry and Chemical Engineering of Catalytic Solid Fuel Conversion for the Production of Clean Synthetic Fuels', which was held at Akcay, Edremit, Turkey, between 21 July and August 3, 1991. Three main subjects: structure and reactivity of coal; cleaning of coal and its products, and factors affecting the environmental balance of energy usage and solutions for the future, were discussed in the Institute and these are presented under six groups in the book: Part 1. Structure and reactivity of coal; Part 2. Factors affecting environmental balance; Part 3. Pre-usage cleaning operations and processes; Part 4. Upgrading of coal liquids and gases; Part 5. Oxygen enriched processes; and Part 6. Probable future solution for energy and pollution problems. Separate abstracts have been prepared for all the lectures

Promotive study on preparation of basis for foreign coal import. Study on coal renaissance

Energy Technology Data Exchange (ETDEWEB)

Muraoka, Yoji [Japan Economic Research Institute, Tokyo

1988-09-16

This is an interim report on the coal renaissance study carried out in 1987 as a part of the Promotive Study on Preparation of Basis for Foreign Coal Import. The background and ideology of coal renaissance, future aspect of demand for coal, problems pertaining to the expansion of application, and a proposal for the expansion of coal usage are described in order. The role of coal expected as an alternate fuel for petroleum, development of new application fields for coal, conversion to coal, contribution of Japan to the stablization of international coal supply are outlined. Coal renaissance aims, based on technology, at stimulation of coal demand, change in the image of coal, and the utilization of the accumulated abundant knowhow. The aspect of coal demand in 2000, solution and current status of various restricting factors relating to the use of coal in general industry, and the remaining problems are discussed. 6 figures, 10 tables.

Review biodepyritisation of coal

Energy Technology Data Exchange (ETDEWEB)

Acharya, C.; Sukla, L.B.; Misra, V.N. [Regional Research Lab., Orissa (India)

2004-01-01

This review provides a detailed summary of the recent and past research activities in the area of biodesulfurisation of coal. It provides information about microorganisms important for biodesulfurisation of coal, with the emphasis on Thiobacillus ferrooxidans. The review presents an insight into various methods of desulfurisation of coal combining physical and biological methods. Also, there are discussions on coal structure, distribution, mechanism and kinetics of pyrite oxidation and jarosite precipitation. Finally, areas requiring further research are identified.

The ENCOAL Mild Coal Gasification Project, A DOE Assessment; FINAL

International Nuclear Information System (INIS)

National Energy Technology Laboratory

2002-01-01

This report is a post-project assessment of the ENCOAL(reg s ign) Mild Coal Gasification Project, which was selected under Round III of the U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Demonstration Program. The CCT Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of commercial-scale facilities. The ENCOAL(reg s ign) Corporation, a wholly-owned subsidiary of Bluegrass Coal Development Company (formerly SMC Mining Company), which is a subsidiary of Ziegler Coal Holding Company, submitted an application to the DOE in August 1989, soliciting joint funding of the project in the third round of the CCT Program. The project was selected by DOE in December 1989, and the Cooperative Agreement (CA) was approved in September 1990. Construction, commissioning, and start-up of the ENCOAL(reg s ign) mild coal gasification facility was completed in June 1992. In October 1994, ENCOAL(reg s ign) was granted a two-year extension of the CA with the DOE, that carried through to September 17, 1996. ENCOAL(reg s ign) was then granted a six-month, no-cost extension through March 17, 1997. Overall, DOE provided 50 percent of the total project cost of$90,664,000. ENCOAL(reg s ign) operated the 1,000-ton-per-day mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming, for over four years. The process, using Liquids From Coal (LFC(trademark)) technology originally developed by SMC Mining Company and SGI International, utilizes low-sulfur Powder River Basin (PRB) coal to produce two new fuels, Process-Derived Fuel (PDF(trademark)) and Coal-Derived Liquids (CDL(trademark)). The products, as alternative fuel sources, are capable of significantly lowering current sulfur emissions at industrial and utility boiler sites throughout the nation thus reducing pollutants causing acid rain. In support of this overall

New coal-based energy systems

International Nuclear Information System (INIS)

Barnert, H.

1986-01-01

Conversion of coal into liquid fuels or into coal gas is considered and the use of high temperature nuclear reactors whose waste heat can be used for remote (district) heating mentioned. The use of high temperature reactors as energy source for coal gasification is also examined and, finally, the extraction of heat from combined coal, steel and high temperature nuclear reactors is suggested. (G.M.E.)

Shale Failure Mechanics and Intervention Measures in Underground Coal Mines: Results From 50 Years of Ground Control Safety Research

Science.gov (United States)

2015-01-01

Ground control research in underground coal mines has been ongoing for over 50 years. One of the most problematic issues in underground coal mines is roof failures associated with weak shale. This paper will present a historical narrative on the research the National Institute for Occupational Safety and Health has conducted in relation to rock mechanics and shale. This paper begins by first discussing how shale is classified in relation to coal mining. Characterizing and planning for weak roof sequences is an important step in developing an engineering solution to prevent roof failures. Next, the failure mechanics associated with the weak characteristics of shale will be discussed. Understanding these failure mechanics also aids in applying the correct engineering solutions. The various solutions that have been implemented in the underground coal mining industry to control the different modes of failure will be summarized. Finally, a discussion on current and future research relating to rock mechanics and shale is presented. The overall goal of the paper is to share the collective ground control experience of controlling roof structures dominated by shale rock in underground coal mining. PMID:26549926

Characterization and suitability of superclean coals for hydroliquefaction feedstocks: Final report

Energy Technology Data Exchange (ETDEWEB)

Kim, Nam

1989-05-30

Superclean coals have been studied for their suitability as liquefaction feedstocks. The effects of ash and sulfur contents and two catalysts on a hydrogen donor solvent liquefaction reaction have been studied. Experiments were run using a unique coal of small particle size (90% <22 microns). The coal was characterized in terms of its chemical and its physical properties. This information made it possible to determine the effects of the static tube flotation separation on the coal. Once characterized the coals were liquefied in the hydrogen donor tetralin under a hydrogen atmosphere of 500 psig. The first series of experiments was to determine the effects of the ash on the liquefaction reaction. The second group of experiments dealt with the effects of catalysts (ammonium molybdate and titanium carbide) on low ash coals at various conditions. A model for batch liquefaction in a hydrogen donor solvent is then developed. This model is based on the assumption that the reaction is due to two competing mechanisms; (1) a thermal decomposition of the coal and (2) a catalytic reaction. The thermal reaction produces unwanted products while the catalytic reaction produces the desired products. To accurately model the batch system, mass transfer is considered. 51 refs., 50 figs., 29 tabs.

Biochemical Removal of HAP Precursors from Coal

Energy Technology Data Exchange (ETDEWEB)

Olson, Gregory J

1997-05-12

Column biooxidation tests with Kentucky coal confirmed results of earlier shake flask tests showing significant removal from the coal of arsenic, selenium, cobalt, manganese, nickel and cadmium. Rates of pyrite biooxidation in Kentucky coal were only slightly more than half the rates found previously for Indiana and Pittsburgh coals. Removal of pyrite from Pittsburgh coal by ferric ion oxidation slows markedly as ferrous ions accumulate in solution, requiring maintenance of high redox potentials in processes designed for removal of pyrite and hazardous air pollutant (HAP) precursors by circulation of ferric solutions through coal. The pyrite oxidation rates obtained in these tests were used by Unifield Engineering to support the conceptual designs for alternative pyrite and HAP precursor bioleaching processes for the phase 2 pilot plant. Thermophilic microorganisms were tested to determine if mercury could be mobilized from coal under elevated growth temperatures. There was no evidence for mercury removal from coal under these conditions. However, the activity of the organisms may have liberated mercury physically. It is also possible that the organisms dissolved mercury and it readsorbed to the clay preferentially. Both of these possibilities are undergoing further testing. The Idaho National Engineering and Environmental Laboratory's (INEEL) slurry column reactor was operated and several batches of feed coal, product coal, waste solids and leach solutions were submitted to LBL for HAP precursor analysis. Results to date indicate significant removal of mercury, arsenic and other HAP precursors in the combined physical-biological process.

Relevance of Clean Coal Technology for India’s Energy Security: A Policy Perspective

Science.gov (United States)

Garg, Amit; Tiwari, Vineet; Vishwanathan, Saritha

2017-07-01

Climate change mitigation regimes are expected to impose constraints on the future use of fossil fuels in order to reduce greenhouse gas (GHG) emissions. In 2015, 41% of total final energy consumption and 64% of power generation in India came from coal. Although almost a sixth of the total coal based thermal power generation is now super critical pulverized coal technology, the average CO2 emissions from the Indian power sector are 0.82 kg-CO2/kWh, mainly driven by coal. India has large domestic coal reserves which give it adequate energy security. There is a need to find options that allow the continued use of coal while considering the need for GHG mitigation. This paper explores options of linking GHG emission mitigation and energy security from 2000 to 2050 using the AIM/Enduse model under Business-as-Usual scenario. Our simulation analysis suggests that advanced clean coal technologies options could provide promising solutions for reducing CO2 emissions by improving energy efficiencies. This paper concludes that integrating climate change security and energy security for India is possible with a large scale deployment of advanced coal combustion technologies in Indian energy systems along with other measures.

Coal-fired high performance power generating system. Final report

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-08-31

As a result of the investigations carried out during Phase 1 of the Engineering Development of Coal-Fired High-Performance Power Generation Systems (Combustion 2000), the UTRC-led Combustion 2000 Team is recommending the development of an advanced high performance power generation system (HIPPS) whose high efficiency and minimal pollutant emissions will enable the US to use its abundant coal resources to satisfy current and future demand for electric power. The high efficiency of the power plant, which is the key to minimizing the environmental impact of coal, can only be achieved using a modern gas turbine system. Minimization of emissions can be achieved by combustor design, and advanced air pollution control devices. The commercial plant design described herein is a combined cycle using either a frame-type gas turbine or an intercooled aeroderivative with clean air as the working fluid. The air is heated by a coal-fired high temperature advanced furnace (HITAF). The best performance from the cycle is achieved by using a modern aeroderivative gas turbine, such as the intercooled FT4000. A simplified schematic is shown. In the UTRC HIPPS, the conversion efficiency for the heavy frame gas turbine version will be 47.4% (HHV) compared to the approximately 35% that is achieved in conventional coal-fired plants. This cycle is based on a gas turbine operating at turbine inlet temperatures approaching 2,500 F. Using an aeroderivative type gas turbine, efficiencies of over 49% could be realized in advanced cycle configuration (Humid Air Turbine, or HAT). Performance of these power plants is given in a table.

Shale gas vs. coal: Policy implications from environmental impact comparisons of shale gas, conventional gas, and coal on air, water, and land in the United States

International Nuclear Information System (INIS)

Jenner, Steffen; Lamadrid, Alberto J.

2013-01-01

The aim of this paper is to examine the major environmental impacts of shale gas, conventional gas and coal on air, water, and land in the United States. These factors decisively affect the quality of life (public health and safety) as well as local and global environmental protection. Comparing various lifecycle assessments, this paper will suggest that a shift from coal to shale gas would benefit public health, the safety of workers, local environmental protection, water consumption, and the land surface. Most likely, shale gas also comes with a smaller GHG footprint than coal. However, shale gas extraction can affect water safety. This paper also discusses related aspects that exemplify how shale gas can be more beneficial in the short and long term. First, there are technical solutions readily available to fix the most crucial problems of shale gas extraction, such as methane leakages and other geo-hazards. Second, shale gas is best equipped to smoothen the transition to an age of renewable energy. Finally, this paper will recommend hybrid policy regulations. - Highlights: ► We examine the impacts of (un)conventional gas and coal on air, water, and land. ► A shift from coal to shale gas would benefit public health. ► Shale gas extraction can affect water safety. ► We discuss technical solutions to fix the most crucial problems of shale gas extraction. ► We recommend hybrid regulations.

Identification and quantification of radionuclides in coal ash. Final report

International Nuclear Information System (INIS)

Alleman, J.E.; Clikeman, F.M.; Skronski, T.

1998-01-01

One of the important environmental issues raised recently in regard to coal ash reuse for highway construction purposes (e.g., embankment development) is that of worker, and public, exposure to radiation which might possibly be emitted by these types of residues. This research project subsequently addressed the associated issue of radiation emission by coal ash residuals generated within the State of Indiana, covering both fly ash and bottom ash materials. Samples were obtained at sixteen different coal-fired power generating facilities within Indiana and subjected to quantitative analysis of their associated gamma-ray emission levels. After identifying the responsible radionuclides, a conservative approximation was then developed for the worst-case potential occupational exposure with construction employees working on this type of high-volume, coal ash embankment. In turn, these potential emissions levels were compared to those of other traditional construction materials and other common sources

Cleavage and crosslinking of polymeric coal structures during pyrolysis. Final report

Energy Technology Data Exchange (ETDEWEB)

McMillen, D.F.; Malhotra, R.

1992-02-01

The ultimate objective of this project was to develop a better understanding of volatiles production to help optimize the yield and character of condensable coproducts during coal pyrolysis or mild gasification. The specific objectives were to (1) Develop pyrolysis procedures that minimize secondary reactions; and (2) Develop coal pretreatments that current knowledge suggests will prorate bond scission or prevent retrograde reactions. Our approach was to study the pyrolysis of coals and tar-loaded coals by using several techniques that span a range of heating rates and pressures. Slow-heating pyrolyses were performed at low pressures in the inlet of a field ionization mass spectrometer and at atmospheric pressures in a thermogravimetric analyzer. Moderately rapid-heating pyrolyses were performed in a vacuum TGA apparatus and in sealed silica ampules heated in a molten-salt bath. The fastest heating rates were achieved with laser pyrolysis at about 30,000 X/s. The high tar yield seen in this work where the entire volume of the coal particle becomes hot and fluid at very nearly the same time, taken together with the evident non-vapor transport of the tar under these conditions, emphasizes the importance of better understanding the development of fluidity during coal heating. This specifically includes the profound effects--long-recognized but poorly understood that mild oxidation has in suppressing coal fluidity. It also includes the more recently recognized fact that heating in the presence of an inert gas produced substantially greater fluidity than does heating in the presence of combustion gases, even if the conditions are very fuel rich and all the oxygen itself has already been consumed when the coal particles are encountered.

Too Much Coal, Too Little Oil

OpenAIRE

Frederick van der Ploeg; Cees Withagen

2011-01-01

Optimal climate policy is studied. Coal, the abundant resource, contributes more CO2 per unit of energy than the exhaustible resource, oil. We characterize the optimal sequencing oil and coal and departures from the Herfindahl rule. "Preference reversal" can take place. If coal is very dirty compared to oil, there is no simultaneous use. Else, the optimal outcome starts with oil, before using oil and coal together, and finally coal on its own, The "laissez-faire" outcome uses coal forever or ...

Analytical Study of Microwave Heating of the Coal Layer With Mixed Boundary Conditions of I and III Types

Directory of Open Access Journals (Sweden)

Salomatov Vladimir

2016-01-01

Full Text Available This work is dedicated to the search for the exact analytical dependences of microwave heating due to absorption of a plane electromagnetic wave by coal layer with asymmetric and non-uniform heat dissipation conditions I and III kind. Some of simplifications have been made, such as one-dimensional problem, uniformity and isotropic coal material, and the constancy of the electrical properties of thermal coal during heating of microwave radiation. This has led to the fact that the Maxwell’s task is solved separately from the Fourier’s task, and a heat source generated in the carbon layer is subject to Bouguer law. For the system of equations of heat transfer has been found a new dependent variable, which is to simplify the search for a final solution. All this has given the possibility of finding rigorous analytical solution of the problem of microwave heating of the coal layer in the presence of asymmetric and inhomogeneous boundary conditions I and III kind.

Measurement and prediction of aromatic solute distribution coefficients for aqueous-organic solvent systems. Final report

Energy Technology Data Exchange (ETDEWEB)

Campbell, J.R.; Luthy, R.G.

1984-06-01

Experimental and modeling activities were performed to assess techniques for measurement and prediction of distribution coefficients for aromatic solutes between water and immiscible organic solvents. Experiments were performed to measure distribution coefficients in both clean water and wastewater systems, and to assess treatment of a wastewater by solvent extraction. The theoretical portions of this investigation were directed towards development of techniques for prediction of solute-solvent/water distribution coefficients. Experiments were performed to assess treatment of a phenolic-laden coal conversion wastewater by solvent extraction. The results showed that solvent extraction for recovery of phenolic material offered several wastewater processing advantages. Distribution coefficients were measured in clean water and wastewater systems for aromatic solutes of varying functionality with different solvent types. It was found that distribution coefficients for these compounds in clean water systems were not statistically different from distribution coefficients determined in a complex coal conversion process wastewater. These and other aromatic solute distribution coefficient data were employed for evaluation of modeling techniques for prediction of solute-solvent/water distribution coefficients. Eight solvents were selected in order to represent various chemical classes: toluene and benzene (aromatics), hexane and heptane (alkanes), n-octanol (alcohols), n-butyl acetate (esters), diisopropyl ether (ethers), and methylisobutyl ketone (ketones). The aromatic solutes included: nonpolar compounds such as benzene, toluene and naphthalene, phenolic compounds such as phenol, cresol and catechol, nitrogenous aromatics such as aniline, pyridine and aminonaphthalene, and other aromatic solutes such as naphthol, quinolinol and halogenated compounds. 100 references, 20 figures, 34 tables.

Coal marketing manual 1986

Energy Technology Data Exchange (ETDEWEB)

1986-01-01

This manual presents information for the use of marketers, consumers, analysts and investors. The information is presented in a series of tables and figures. Statistics are given for: Australian export tonnages and average export values for 1978-1985; international pig iron production 1976 to 1985; and international crude steel production 1979 to 1985. Trends in Australian export tonnages and prices of coal are reviewed. Details of international loading and discharge ports are given, together with a historical summary of shipping freight-rates since 1982. Long term contract prices for thermal and coking coal to Japan are tabulated. A review of coal and standards is given, together with Australian standards for coal and coke. A section on coal quality is included containing information on consumer coal quality preferences and Australian and Overseas coal brands and qualities. Finally an index is given of contact details of Australian and Overseas exporting companies, government departments, and the Australian Coal Association.

Self-scrubbing coal

International Nuclear Information System (INIS)

Kindig, J.K.

1992-01-01

More than 502 million tons - 65 percent of all coal shipped to utilities in 1990 - were above 1.2 pounds of sulfur dioxide per million Btu. Most of the coal, even though cleaned in conventional coal preparation plants, still does not meet the emission limitation the Clean Air Act Amendments mandate for the year 2000. To cope with this fact, most utilities plan to switch to low sulfur (western U.S. or Central Appalachian) coal or install scrubbers. Both solutions have serous drawbacks. Switching puts local miners out of work and weakens the economy in the utility's service territory. Scrubbing requires a major capital expenditure by the utility. Scrubbers also increase the operating complexity and costs of the generating station and produce yet another environmental problem, scrubber sludge. Employing three new cost-effective technologies developed by Customer Coals International (CCl), most non-compliance coals east of the Mississippi River can be brought into year-2000 compliance. The compliance approach employed, depends upon the characteristics of the raw coal. Three types of raw coal are differentiated, based upon the amount of organic sulfur in the coals and the ease (or difficultly) of liberating the pyrite. They are: Low organic sulfur content and pyrite that liberates easily. Moderate organic sulfur content and pyrite that liberates easily. High organic sulfur content or the pyrite liberates with difficulty. In this paper examples of each type of raw coal are presented below, and the compliance approach employed for each is described. The names of the beneficiated coal products produced from each type of raw coal give above are: Carefree Coal, Self-Scrubbing Coal and Dry-Scrubbing Coal

COFIRING BIOMASS WITH LIGNITE COAL; FINAL

International Nuclear Information System (INIS)

Darren D. Schmidt

2002-01-01

The University of North Dakota Energy and Environmental Research Center, in support of the U.S. Department of Energy's (DOE) biomass cofiring program, completed a Phase 1 feasibility study investigating aspects of cofiring lignite coal with biomass relative to utility-scale systems, specifically focusing on a small stoker system located at the North Dakota State Penitentiary (NDSP) in Bismarck, North Dakota. A complete biomass resource assessment was completed, the stoker was redesigned to accept biomass, fuel characterization and fireside modeling tests were performed, and an engineering economic analysis was completed. In general, municipal wood residue was found to be the most viable fuel choice, and the modeling showed that fireside problems would be minimal. Experimental ash deposits from firing 50% biomass were found to be weaker and more friable compared to baseline lignite coal. Experimental sulfur and NO(sub x) emissions were reduced by up to 46%. The direct costs savings to NDSP, from cogeneration and fuel saving, results in a 15- to 20-year payback on a$1,680,000 investment, while the total benefits to the greater community would include reduced landfill burden, alleviation of fees for disposal by local businesses, and additional jobs created both for the stoker system as well as from the savings spread throughout the community

Maximizing efficiency in the transition to a coal-based economy

International Nuclear Information System (INIS)

Brathwaite, J.; Horst, S.; Iacobucci, J.

2010-01-01

Energy is the lynchpin of modern society. Since the early 1970s, growing dependence on foreign energy sources, oil in particular, has constrained US independence in foreign policy, and at times, inhibited economic stability and growth. Addressing oil dependence is politically and economically complex. Proposed solutions are multifaceted with various objectives such as energy efficiency and resource substitution. One solution is the partial transition from an oil- to coal-based economy. A number of facts support this solution including vast coal reserves in the US and the relative price stability of coal. However, several roadblocks exist. These include uncertain recoverable reserves and the immaturity of 'clean' coal technologies. This paper provides a first order analysis of the most efficient use of coal assuming the transition from oil to coal is desirable. Scenario analysis indicates two possible transition pathways: (1) bring the transportation sector onto the electric grid and (2) use coal-to-liquid fuels to directly power vehicles. The feasibility of each pathway is examined based on economic and environmental factors, among which are energy availability, affordability and efficiency, and environmental sustainability. Results indicate that partial transition of the transportation sector onto the electric grid offers the more viable solution for coal-based reduction of the US oil dependence.

Cooperative research in coal liquefaction. Final report, May 1, 1990-- April 30, 1991

Energy Technology Data Exchange (ETDEWEB)

Huffman, G.P. [ed.

1992-02-15

The Consortium for Fossil Fuel Liquefaction Science (CFFLS) is currently engaged in a three year contract with the US Department of Energy investigating a range of research topics dealing with direct coal liquefaction. This report summarizes the results of this program in its second year, from May 1, 1990 to April 30, 1991. Accomplishments for this period are presented for the following tasks: Iron-based catalysts for coal liquefaction, exploratory research on coal conversion, novel coal liquefaction concepts, and novel catalysts for coal liquefaction.

Electrostatic beneficiation of coal

Energy Technology Data Exchange (ETDEWEB)

Mazumder, M.K.; Tennal, K.B.; Lindquist, D.

1994-10-01

Dry physical beneficiation of coal has many advantages over wet cleaning methods and post combustion flue gas cleanup processes. The dry beneficiation process is economically competitive and environmentally safe and has the potential of making vast amounts of US coal reserves available for energy generation. While the potential of the electrostatic beneficiation has been studied for many years in laboratories and in pilot plants, a successful full scale electrostatic coal cleaning plant has not been commercially realized yet. In this paper the authors review some of the technical problems that are encountered in this method and suggest possible solutions that may lead toward its full utilization in cleaning coal.

Air oxidation of aqueous sodium sulfide solutions with coal fly ash

Energy Technology Data Exchange (ETDEWEB)

Mallik, D; Chaudhuri, S K [Southern Illinois University, Carbondale, IL (United States). Dept. of Mining Engineering

1999-02-01

The paper investigated the potential of coal fly ash as a catalyst in the air oxidation of aqueous sodium sulfide (Na{sub 2}S) solutions in the temperature range of 303-333 K. The rate of oxidation was found to be independent of the initial concentration of Na{sub 2}S in the range of 5.80 x 10{sup -2} - 28.45 x 10{sup -2} kmol/m{sup 3}. The effects of fly ash loading, source of fly ash, speed of agitation, air flow rate, fly ash particle size were also studied. Experimental results suggested a film-diffusion controlled reaction mechanism. The deactivation of the catalytic effect of fly ash was found to be less than 31% even after five repeated uses.

Final Scientific/Technical Report

Energy Technology Data Exchange (ETDEWEB)

Liang, Yanna

2017-12-20

To increase our understanding of coal biogasification and move this technology closer toward field scale demonstration, we have thoroughly investigated coal bioconversion both ex situ and in situ. Specifically, we have screened a total of 12 parameters and identified those that exert statistically positive influence on coal biogasification. Based on these evaluations, a recipe for a nutrient solution was developed. With the addition of this nutrient solution, methane yield from Illinois coal was enhanced dramatically. In addition, we have demonstrated that coal bioconversion can be sustained over a long period of time as long as suitable conditions were maintained. Furthermore, biogasification of coal was tested under pressure simulating in situ conditions. Surprisingly, pressure was found to have no negative effects on microbial activities. Thus, the same recipe developed for ex situ may be used in situ as well.

Coal surface control for advanced physical fine coal cleaning technologies

Energy Technology Data Exchange (ETDEWEB)

Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

1992-01-01

This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

Final report on dust monitoring near Kellingley coal mine, North Yorkshire

International Nuclear Information System (INIS)

Vallack, H.W.

1992-06-01

Dust deposition was monitored at a residential location near Kellingley Coal Mine over two four-weekly periods (November/December 1991 and March/April 1992) using a wet Frisbee dust deposit gauge. The mean rates of dust deposition for both periods (696.4 and 415.5 mg m -2 day -1 respectively) were well in excess of a proposed acceptable upper limit (195 mg m -2 day -1 ) for residential conditions. Mean estimated coal dust content during both periods (80.9 and 49.7 per cent) was also high. It is concluded that coal dust from Kellingley Coal Mine gave rise to excessively high levels of dust deposition at the monitoring site, especially during the first four-weekly period. The situation would appear to have deteriorated since a similar monitoring exercise was carried out in 1989. 4 refs, 2 figs, 2 tabs

Direct liquefaction of low-rank coals under mild conditions

Energy Technology Data Exchange (ETDEWEB)

Braun, N.; Rinaldi, R. [Max-Planck-Institut fuer Kohlenforschung, Muelheim an der Ruhr (Germany)

2013-11-01

Due to decreasing of petroleum reserves, direct coal liquefaction is attracting renewed interest as an alternative process to produce liquid fuels. The combination of hydrogen peroxide and coal is not a new one. In the early 1980, Vasilakos and Clinton described a procedure for desulfurization by leaching coal with solutions of sulphuric acid/H{sub 2}O{sub 2}. But so far, H{sub 2}O{sub 2} has never been ascribed a major role in coal liquefaction. Herein, we describe a novel approach for liquefying low-rank coals using a solution of H{sub 2}O{sub 2} in presence of a soluble non-transition metal catalyst. (orig.)

Coal competitiveness?

International Nuclear Information System (INIS)

Rogeaux, B.

2006-01-01

Will coal electrical plants be more competitive in the coming years? Answering this one cannot be limited to merely comparing estimates based on reference electricity production costs. The competitiveness of coal will indeed depend on the final product marketed, as the MWhs are not equal: is the purpose to produce base, half-base MWh? Does the electrical equipment structure require flexible MWh (for instance in the event of significant intermittent renewable energy amounts), and therefore plants able to adjust their power rapidly? But the competitiveness of coal will also depend on many factors that will correct reference cost estimates: uncertainties, risks, externalities. These factors will need to be appreciated on a case by case basis. We introduce some of the reasoning used to better appreciate the future competitiveness of coal, and the main factors conditioning it in three contrasting regions of the world: Europe, USA, china. (author)

Coal in Europe: what future?: prospects of the coal industry and impacts study of the Kyoto Protocol

International Nuclear Information System (INIS)

Rudianto, E.

2006-12-01

From the industrial revolution to the 1960's, coal was massively consumed in Europe and its utilization was constantly raised. In the aftermath of World War II, coal had also an important part in reconstruction of Western Europe's economy. However, since the late 1960's, its demand has been declining. There is a (mis)conception from a number of policy makers that saying coal mining and utilizations in Europe is unnecessary. Therefore in the European Union (EU) Green Paper 2000, coal is described as an 'undesirable' fuel and the production of coal on the basis of economic criteria has no prospect. Furthermore, the commitment to the Kyoto Protocol in reducing greenhouse gases emission has aggravated this view. Faced with this situation, the quest for the future of coal industry (mining and utilization) in the lines of an energy policy is unavoidable. This dissertation did a profound inquiry trying to seek answers for several questions: Does the European Union still need coal? If coal is going to play a part in the EU, where should the EU get the coal from? What should be done to diminish negative environmental impacts of coal mining and utilization? and finally in regard to the CO 2 emission concerns, what will the state of the coal industry in the future in the EU? To enhance the analysis, a system dynamic model, called the Dynamics Coal for Europe (the DCE) was developed. The DCE is an Energy-Economy-Environment model. It synthesizes the perspectives of several disciplines, including geology, technology, economy and environment. It integrates several modules including exploration, production, pricing, demand, import and emission. Finally, the model emphasizes the impact of delays and feed-back in both the physical processes and the information and decision-making processes of the system. The calibration process for the DCE shows that the model reproduces past numbers on the scale well for several variables. Based on the results of this calibration process, it can

Improving the stability of coal slurries: Final report. [Polygalacturonic acid and gum tragacanth

Energy Technology Data Exchange (ETDEWEB)

Fogler, H.S.

1988-12-01

Polysaccharides were found to stabilize colloidal dispersions (such as coal particles and polystyrene latex particles) even at high ionic strengths. The stability studies with various kinds of polysaccharides showed that rod-like molecules (such as poly (galacturonic acid) and gum tragacanth) are much more effective stabilizers than highly-branched molecules such as arabinogalactan. This effective stabilization with the rod-like molecules was found to result from the adsorption of polysaccharides on the particles, i.e., the steric stabilization mechanism. The stability depends significantly on the solution pH, the molecular weight and the surface charge of particles. Adsorption isotherms, the zeta potential and the conformation of adsorbed molecules (the steric layer thicknesses) were measured as a function of the solution pH, the molecular weight and the surface charge. Photon correlation spectroscopy studies showed that the conformation of adsorbed molecules is strongly dependent on the solution pH, the molecular weight and the surface charge, suggesting that the dependence of stability on these parameters is due to the change of the conformation of the molecules adsorbed on the surface. In addition, the solution pH has a significant effect on the flocculation behavior of particles and can be modulated to bring about peptization of particles. This type of stabilization is referred to as electrosteric stabilization whereby steric stabilization is induced by changing the electrical properties of the system (the solution pH in this case). 41 refs., 43 figs., 10 tabs.

Equilibrium Strategy Based Recycling Facility Site Selection towards Mitigating Coal Gangue Contamination

Directory of Open Access Journals (Sweden)

Jiuping Xu

2017-02-01

Full Text Available Environmental pollution caused by coal gangue has been a significant challenge for sustainable development; thus, many coal gangue reduction approaches have been proposed in recent years. In particular, coal gangue facility (CGF construction has been considered as an efficient method for the control and recycling of coal gangue. Meanwhile, the identification and selection of suitable CGF sites is a fundamental task for the government. Therefore, based on the equilibrium strategy, a site selection approach under a fuzzy environment is developed to mitigate coal gangue contamination, which integrates a geographical information system (GIS technique and a bi-level model to identify candidate CGF sites and to select the most suitable one. In this situation, the GIS technique used to identify potential feasible sites is able to integrate a great deal of geographical data tofitwithpracticalcircumstances;thebi-levelmodelusedtoscreentheappropriatesitecanreasonably dealwiththeconflictsbetweenthelocalauthorityandthecolliery. Moreover,aKarush–Kuhn–Tucker (KKT condition-based approach is used to find an optimal solution, and a case study is given to demonstrate the effectiveness of the proposed method. The results across different scenarios show that appropriate site selection can achieve coal gangue reduction targets and that a suitable excess stack level can realize an environmental-economic equilibrium. Finally, some propositions and management recommendations are given.

Efficient direct coal liquefaction of a premium brown coal catalyzed by cobalt-promoted fumed oxides

Energy Technology Data Exchange (ETDEWEB)

Trautmann, M.; Loewe, A.; Traa, Y. [Stuttgart Univ. (Germany). Inst. of Chemical Technology

2013-11-01

The search for alternatives in the fuel sector is an important technological challenge. An interim solution could be provided by direct coal liquefaction. Hydrogen economy and the lack of an efficient catalyst are the main obstacles for this process. We used a premium German brown coal with a high H/C molar ratio of 1.25 and nanostructured cobalt catalysts to improve the efficiency of direct coal liquefaction. We were able to recover and recycle the catalyst efficiently and reached good brown coal conversions and oil yields with single-stage coal liquefaction. The oil quality observed almost reached that of a conventional crude oil considering higher heating value (HHV), H/C molar ratio and aliphatic content. (orig.)

Dewatering of ultrafine coal: Final report, August 1984-December 1986

Energy Technology Data Exchange (ETDEWEB)

Chiang, Shiao-Hung; Klinzing, G.E.; Morsi, B.I.; Tierney, J.W.; Badgujar, M.; Binkley, T.; Cheng, Yisun; Huang, Suxuan; Qamar, I.; Venkatadri, R.

1986-12-01

The surfactant, Aerosol-OT, was used to wash distilled water cakes. In previous studies, cakes were washed with Triton X-114. The dewatering performance and influence on cake structure of the two reagents are compared. Also, filter cakes were analyzed using an image analysis system and micrographic analysis of coal particles was initiated. In the area of theoretical modelling, the concept of bond-flow correlation greatly improved the network model predicting the experimental desaturation curves. Predicted results for treated cakes suggested that the effect of the presence of surface-active agents was adequately accounted for. The effects of the various operating conditions on the filtration/dewatering characteristics of the 10 ..mu..m coal particles were assessed and comparisons with the -32 mesh coal were made as to its trends in response to changes in the operating conditions. 20 refs., 75 figs., 17 tabs.

The environment, public relations and coal

Energy Technology Data Exchange (ETDEWEB)

Wood, W.J. (Coal Association of Canada, Calgary, AB (Canada))

1990-09-01

Information is presented in note format. The presentation covers world environmental issues such as the greenhouse effect, an overview of the coal industry's role in atmospheric emissions of CO{sub 2}, and finally, the need for the coal industry to make the public aware of coal's current and future role in our economic and energy future.

Effects of long-term coal supply contracts on technology adoption and improvements in the mining of coal. Final technical report

Energy Technology Data Exchange (ETDEWEB)

Walton, D.R.; Hawkins, S.A.; Webb, P.F.; Kauffman, P.W.

1979-08-01

The relationship between long-term coal supply contracts and the adoption of new technology in the coal mining industry is a complex one. From this study certain conclusions can be drawn. New technologies and improvements in the mining of coal can be logically categorized into three areas: evolutionary technology, transitional technology, or innovative technology. Evolutionary improvements in technology can be categorized as improvements, or increased production capacities, in existing equipment. Transitional technology involves the adoption of existing or proven technologies into new conditions, or, proceeding from one technology type to a newer type for the same function. Innovative technology includes equipment, concepts, and systems not readily available, or untried, in the existing mining environment (seam conditions, etc.). Technology adoption is an economic decision. This point was repeatedly emphasized by industry representatives contacted during the study. The long-term coal supply contract influences the decision to adopt new technology and mining improvements in several ways depending on the technology type (i.e., evolutionary, transitional, or innovative), and also the coal supplier type (i.e., captive or independent producer). Several examples of the adoption of new technologies in mines under long-term coal supply contracts are discussed. (LTN)

Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report

Energy Technology Data Exchange (ETDEWEB)

Elmore, B.B.

1993-08-01

As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

Coal-related research, organic chemistry, and catalysis

International Nuclear Information System (INIS)

Anon.

1980-01-01

Coal chemistry research topics included: H exchange at 400 0 C, breaking C-C bonds in coal, molecular weight estimation using small-angle neutron scattering, 13 C NMR spectra of coals, and tunneling during H/D isotope effects. Studies of coal conversion chemistry included thermolysis of bibenzyl and 1-naphthol, heating of coals in phenol, advanced indirect liquefaction based on Koelbel slurry Fischer-Tropsch reactor, and plasma oxidation of coal minerals. Reactions of PAHs in molten SbCl 3 , a hydrocracking catalyst, were studied. Finally, heterogeneous catalysis (desulfurization etc.) was studied using Cu, Au, and Ni surfaces. 7 figures, 6 tables

Micronized Coal Reburning Demonstration for NOx Control: A DOE Assessment; FINAL

International Nuclear Information System (INIS)

National Energy Technology Laboratory

2001-01-01

The goal of the U.S. Department of Energy's (DOE) Clean Coal Technology (CCT) program is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage. This document serves as a DOE post-project assessment of a project selected in CCT Round IV, the Micronized Coal Reburning (MCR) Demonstration for NO(sub x) Control, as described in a report to Congress (U.S. Department of Energy 1999). The need to meet strict emissions requirements at a minimum cost prompted the Tennessee Valley Authority (TVA), in conjunction with Fuller Company, Energy and Environmental Research Corporation (EER), and Fluor Daniel, to submit the proposal for this project to be sited at TVA's Shawnee Fossil Plant. In July 1992, TVA entered into a cooperative agreement with DOE to conduct the study. However, because of operational and environmental compliance strategy changes, the Shawnee site became unavailable

Modeling of integrated environmental control systems for coal-fired power plants. Final report

Energy Technology Data Exchange (ETDEWEB)

Rubin, E.S.; Salmento, J.S.; Frey, H.C.; Abu-Baker, A.; Berkenpas, M.

1991-05-01

The Integrated Environmental Control Model (IECM) was designed to permit the systematic evaluation of environmental control options for pulverized coal-fired (PC) power plants. Of special interest was the ability to compare the performance and cost of advanced pollution control systems to ``conventional`` technologies for the control of particulate, SO{sub 2} and NO{sub x}. Of importance also was the ability to consider pre-combustion, combustion and post-combustion control methods employed alone or in combination to meet tough air pollution emission standards. Finally, the ability to conduct probabilistic analyses is a unique capability of the IECM. Key results are characterized as distribution functions rather than as single deterministic values. (VC)

Interaction and the structures of coal

Science.gov (United States)

Opaprakasit, Pakorn

The origin of a decrease in the amount of soluble material from coal upon a reflux treatment has been investigated in an attempt to obtain insight into the nature of the interaction in the macromolecular network structure of coal. This decrease in the extractable material is a result of an increase in the amount of physical cross-links associated with secondary interactions. The alternate possibility of covalent cross-link formation by ether linkage was found to be unlikely because the coal hydroxyl content remains unchanged upon heat treatment. The functional groups responsible for forming these physical cross-links and their contents vary from coal to coal with coal rank. Carboxylate/cation complexes, similar to those found in ionomers, dominate in low rank coal. In high rank coal, the clusters involving pi-cation interactions were observed. Both mechanisms seem to play a role in mid rank coals. These physical cross-links are responsible for a lowering of the extraction yield of coal, but are disrupted by a treatment with acid solution, resulting in an increase in the extraction yield. As a consequence, the cross-links in coal structure should be classified into two types; a "permanent" covalent cross-link, which break under extreme conditions such as chemical reaction and pyrolysis, and "reversible" cross-links, largely associated with ionomer-like structure and pi-cation interactions. The interaction between a "magic" solvent of N-methylpyrollidone and carbon disulfide (NMP/CS2) and its role in the unusual extractability enhancement of Upper Freeport coal has also been investigated. The results strongly suggest that NMP/CS2 mixed solvents form complexes with cations. These mixed solvents are capable of forming a solid complex with cations from NaOH and some simple salts, such as NaCl and LiCl. Given that Upper Freeport coal contains a large amount of mineral matter, it is not surprising that these types of complexes could be formed in the present of the mixed

Studies for the stabilization of coal-oil mixtures. Final report, August 1978-May 1981

Energy Technology Data Exchange (ETDEWEB)

Botsaris, G.D.; Glazman, Y.M.; Adams-Viola, M.

1981-01-01

A fundamental understanding of the stabilization of coal-oil mixtures (COM) was developed. Aggregation of the coal particles was determined to control both the sedimentation and rheological properties of the COM. Sedimentation stability of COM prepared with coal, 80% < 200 mesh, is achieved by particle aggregation, which leads to the formation of a network of particles throughout the oil. The wettability of coal powders was evaluated by the Pickering emulsion test and a spherical agglomeration test to assess its effect on the stability of various COM formulations. Sedimentation stability of hydrophilic coal-oil-water mixtures (COWM) involves the formation of water bridges between the coal particles, while less stabilization of oleophilic COWM is achieved by the formation of an emulsion. Anionic SAA were least sensitive to the coal type and enhanced the aggregation stability of the suspension. The effect of cationic SAA, nonionic SAA and polymer additives depended upon the specific chemical structure of the SAA, the water content of the COM and the type of coal. The sedimentation stability of ultrafine COM was not directly due to the fineness of the powder but due to the formation of a network of flocculated particles.

Coal supply and transportation markets during Phase One: Change, risk and opportunity. Final report

International Nuclear Information System (INIS)

Heller, J.N.; Kaplan, S.

1996-01-01

The Clean Air Act Amendments of 1990 (CAAA) required many utilities to sharply reduce sulfur emissions by January 1, 1995. This study describes and analyzes how the coal and transportation markets responded to this major development. The study focuses on five key coal supply regions and their associated transportation networks: the Uinta Basin (Colorado/Utah), Wyoming Powder River Basin, Illinois Basin, Monongahela region (Pittsburgh seam) and the central Appalachian region. From these regional studies, the report identifies key risk areas for future coal planning and general lessons for the fuels planning process. The study provides statistical information on coal production, demand, and transportation flows for each region. The analysis for each region focuses on developments which were generally unexpected; e.g., the relatively large volumes of medium-sulfur coal produced in the Illinois Basin and Monongahela region, the eastern penetration of Utah and Colorado coals, and the relatively modest growth in demand for central Appalachian coals. These developments generally worked to the advantage of utilities; i.e., medium- and low-sulfur coal was available at a lower price, in greater volumes and from a wider range of sources than many had expected. Utilities both took advantage of and helped to encourage these developments in the coal and transportation market. Looking ahead to Phase 11 strategies and future coal procurement, a major challenge will be to maintain the choice among supply and transportation alternatives which was so important to utility success in Phase 1. The report identifies rail transportation to be the major area of risk in most regions

Microbial desulfurization of coal

International Nuclear Information System (INIS)

Bos, P.; Boogerd, F.C.; Kuenen, J.G.

1992-01-01

In recent years, studies have been initiated to explore the possibilities of the use of biological systems in coal technology. This chapter discusses the principles behind the bioprocessing of coal, the advantages and disadvantages, and the economic feasibility of the process. For large-scale, coal-using, energy-producing plants, stack gas cleaning should be the treatment of choice. Biodesulfurization is preferable with industrial, small-scale, energy-producing plants. Treatment of the stack gases of these plants is not advisable because of high investment costs. Finally, it should be realized that biodesulfurization produces a waste stream that needs further treatment. 91 refs

Determining the radiative properties of pulverized-coal particles from experiments. Final report

Energy Technology Data Exchange (ETDEWEB)

Menguec, M.P.

1992-02-01

A comprehensive coupled experimental-theoretical study has been performed to determine the effective radiative properties of pulverized-coal/char particles. The results obtained show that the ``effective`` scattering phase function of coal particles are highly forward scattering and show less sensitivity to the size than predicted from the Lorenz-Mie theory. The main reason for this is the presence of smaller size particles associated with each larger particle. Also, the coal/char particle clouds display more side scattering than predicted for the same size range spheres, indicating the irregular shape of the particles and fragmentation. In addition to these, it was observed that in the visible wavelength range the coal absorption is not gray, and slightly vary with the wavelength. These two experimental approaches followed in this study are unique in a sense that the physics of the problem are not approximated. The properties determined include all uncertainties related to the particle shape, size distribution, inhomogeneity and spectral complex index of refraction data. In order to obtain radiative property data over a wider wavelength spectrum, additional ex-situ experiments have been carried out using a Fourier Transform Infrared (FT-IR) Spectrometer. The spectral measurements were performed over the wavelength range of 2 to 22 {mu}m. These results were interpreted to obtain the ``effective`` efficiency factors of coal particles and the corresponding refractive index values. The results clearly show that the coal/char radiative properties display significant wavelength dependency in the infrared spectrum.

Coal-based synthetic natural gas (SNG): A solution to China’s energy security and CO2 reduction?

International Nuclear Information System (INIS)

Ding, Yanjun; Han, Weijian; Chai, Qinhu; Yang, Shuhong; Shen, Wei

2013-01-01

Considering natural gas (NG) to be the most promising low-carbon option for the energy industry, large state owned companies in China have established numerous coal-based synthetic natural gas (SNG) projects. The objective of this paper is to use a system approach to evaluate coal-derived SNG in terms of life-cycle energy efficiency and CO 2 emissions. This project examined main applications of the SNG and developed a model that can be used for evaluating energy efficiency and CO 2 emissions of various fuel pathway systems. The model development started with the GREET model, and added the SNG module and an end-use equipment module. The database was constructed with Chinese data. The analyses show when the SNG are used for cooking, power generation, steam production for heating and industry, life-cycle energies are 20–108% higher than all competitive pathways, with a similar rate of increase in life-cycle CO 2 emissions. When a compressed natural gas (CNG) car uses the SNG, life-cycle CO 2 emission will increase by 150–190% compared to the baseline gasoline car and by 140–210% compared to an electric car powered by electricity from coal-fired power plants. The life-cycle CO 2 emission of SNG-powered city bus will be 220–270% higher than that of traditional diesel city bus. The gap between SNG-powered buses and new hybrid diesel buses will be even larger—life-cycle CO 2 emission of the former being around 4 times of that of the latter. It is concluded that the SNG will not accomplish the tasks of both energy conservation and CO 2 reduction. - Highlights: ► We evaluated life-cycle energy efficiency and CO 2 emissions of coal-derived SNG. ► We used GREET model and added a coal-based SNG and an end-use modules. ► The database was constructed with Chinese domestic data. ► Life-cycle energies and CO 2 emissions of coal-based SNG are 20–100% higher. ► Coal-based SNG is not a solution to both energy conservation and CO 2 reduction

Group separation of coal components and new ideas of coal utilization as petroleum

Energy Technology Data Exchange (ETDEWEB)

Zhi-hong Qin; Cui-li Hou; Juan Chen; Li-ying Zhang; Jie-qiong Ma [China University of Mining & Technology, Xuzhou (China). School of Chemical Engineering and Technology

2009-09-15

Four different groups of components were separated from coal under mild conditions of extraction and stripping process. Within these groups, and with pre-separation, individual utilization of all coal components can be realized, similar to petroleum components and enhance the inherent value and utilization value of coal, as well as increase environmental benefits. The characteristics of each component were analyzed with measurements by FTIR, GC/MS, TEM and the establishment of caking properties. The results show that coal can be separated into residues, ultra-pure coal, asphaltene components and light components by adding solvents for stripping into the CS{sub 2}/NMP mixed extraction solution. Those four groups of components present great differences in the presence of carbon and hydrogen elements, in the structure of functional groups, in their macroscopic structure and micro-morphology and caking properties. Every component possesses its own inherent values and approaches. A new idea of coal processes and utilization, similar to the use of petroleum is proposed. 11 refs., 6 figs., 6 tabs.

Coal beneficiation by gas agglomeration

Science.gov (United States)

Wheelock, Thomas D.; Meiyu, Shen

2003-10-14

Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

The contemporary coal industry: dancing to faster music

Energy Technology Data Exchange (ETDEWEB)

Knapp, R. [World Coal Institute, London (United Kingdom)

1997-09-01

Within a framework that supports sustainable development, the issues of changing coal markets, environmental policy and climate change, and the positive marketing of coal as a solution to energy demand are discussed. Changes affect both domestic and international markets, and each subset of the market is different. In Europe, coal consumption is declining in contrast with expanding Asian energy markets. Clean coal technologies improve efficiency and make coal more acceptable. The greatest reductions in carbon dioxide emissions can be realized within the least efficient areas of coal consumption, in particular the domestic markets in Asia, eastern Europe, and Africa.

Radioactivity of coals and ash and slag wastes at coal-fired thermal power plants

Science.gov (United States)

Krylov, D. A.; Sidorova, G. P.

2013-04-01

This paper presents an analysis of published data on the content of radioactive nuclides in coals originating from various coal deposits, and in ash and slag wastes produced at coal-fired thermal power plants, as well as in fly ash emitted from thermal power plants into the atmosphere. Problems related to the use of coals with an elevated content of natural radionuclides (NRNs) and methods of their solution implemented at the Urtuyskoe coalfield are dealt with. Data on the analysis of Transbaikal coals for the NRN content, as well as weighted mean content of uranium and thorium in coals from the Siberian Region, are given. In order to reduce irradiation of plant personnel and the population of the areas where coal producers and coal-fired thermal power plants are located, it is necessary to organize very careful control of the NRN content in both coals and products of their combustion that are released into the environment. To solve the problem related to the control of radioactivity, the centralized approach and creation of a proper normative base are needed. Experience gained in developing the Urtuyskoe coalfield shows that it is possible to create an efficient system of coal quality control with respect to the radiation hygiene factor and provide protection of the environment and health of the population.

acme: The Amendable Coal-Fire Modeling Exercise. A C++ Class Library for the Numerical Simulation of Coal-Fires

Science.gov (United States)

Wuttke, Manfred W.

2017-04-01

At LIAG, we use numerical models to develop and enhance understanding of coupled transport processes and to predict the dynamics of the system under consideration. Topics include geothermal heat utilization, subrosion processes, and spontaneous underground coal fires. Although the details make it inconvenient if not impossible to apply a single code implementation to all systems, their investigations go along similar paths: They all depend on the solution of coupled transport equations. We thus saw a need for a modular code system with open access for the various communities to maximize the shared synergistic effects. To this purpose we develop the oops! ( open object-oriented parallel solutions) - toolkit, a C++ class library for the numerical solution of mathematical models of coupled thermal, hydraulic and chemical processes. This is used to develop problem-specific libraries like acme( amendable coal-fire modeling exercise), a class library for the numerical simulation of coal-fires and applications like kobra (Kohlebrand, german for coal-fire), a numerical simulation code for standard coal-fire models. Basic principle of the oops!-code system is the provision of data types for the description of space and time dependent data fields, description of terms of partial differential equations (pde), their discretisation and solving methods. Coupling of different processes, described by their particular pde is modeled by an automatic timescale-ordered operator-splitting technique. acme is a derived coal-fire specific application library, depending on oops!. If specific functionalities of general interest are implemented and have been tested they will be assimilated into the main oops!-library. Interfaces to external pre- and post-processing tools are easily implemented. Thus a construction kit which can be arbitrarily amended is formed. With the kobra-application constructed with acme we study the processes and propagation of shallow coal seam fires in particular in

The orthopositronium lifetime puzzle and its final solution

International Nuclear Information System (INIS)

Liu Feng; Wu Jianda; Zhan Liang; Ye Bangjiao

2004-01-01

The ortho-positronium (o-Ps), which consists of an electron and positron, is a pure lepton bound system. The o-Ps lifetime can be calculated accurately by quantum electrodynamics, but there is a long-standing discrepancy between the theoretical calculations and the experimental results. Theoretical and experimental physicists have worked hard for a long time to solve the problem, and recently finally solved this lifetime puzzle. The authors briefly outline the discrepancy between the theoretical calculations of the o-Ps annihilation decay rate and some of the experimental measurements, as well as recent developments of experimental techniques, and its final solution. In particular, the final results of the Tokyo and michigan groups are discussed

How can we reduce carbon in ash in firing pulverized coal

Energy Technology Data Exchange (ETDEWEB)

O' Keefe, W. (and others)

1992-12-01

The article discusses solutions to the problem of reducing carbon in ash in firing pulverized coal. Suggested solutions to the problem include: reviewing air flow through the mills; examining the pulverizers for coal fineness variations; investigating air distribution in the burners; review dual-firing equations; examining the burners for slag build up; checking coal fineness is appropriate to the boiler; increasing air flow; and checking instrumentation. 2 figs., 1 photo.

Nuclear assay of coal. Volume 1. Coal composition by prompt neutron activation analysis: basic experiments. Final report

International Nuclear Information System (INIS)

Reynolds, G.; Bozorganesh, H.; Elias, E.; Gozani, T.; Maung, T.; Orphan, V.

1979-01-01

Using californium-252 as a source of exciting neutrons, prompt gamma photons emitted by elemental nuclei in the coal have been measured using several detectors, including sodium--iodide and germanium--lithium. Several coal types, including bituminous, subbituminous lignite and anthracite were crushed to various top sizes and analyzed carefully be traditional ASTM wet chemistry techniques at two or three different laboratories. The elements (sulfur, hydrogen, carbon, aluminum, silicon, iron, calcium, sodium, nitrogen, and chlorine) were determined by prompt neutron activations and the quantities compared with those of the wet chemical analyses

Too little oil, too much coal: Optimal carbon tax and when to phase in oil, coal and renewables

OpenAIRE

van der Ploeg, Frederick; Withagen, Cees A.

2011-01-01

Our main message is that it is optimal to use less coal and more oil once one takes account of coal being a backstop which emits much more CO2 than oil. The way of achieving this is to have a steeply rising carbon tax during the initial oil-only phase, a less-steeply rising carbon tax during the intermediate phase where oil and coal are used alongside each other and the following coal-only phase, and a flat carbon tax during the final renewables-only phase. The "laissez-faire" outcome uses co...

Process for electrochemically gasifying coal using electromagnetism

Science.gov (United States)

Botts, Thomas E.; Powell, James R.

1987-01-01

A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

Coal distribution, January--June 1991

International Nuclear Information System (INIS)

1991-01-01

The Coal Distribution report provides information on coal production, distribution, and stocks in the United States to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. The data in this report are collected and published by the Energy Information Administration (EIA) to fulfill its data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275, Sections 5 and 13, as amended). This issue presents information for January through June 1991. Coal distribution data are shown (in Tables 1--34) by coal-producing Sate of origin, consumer use, method of transportation, and State of destination. All data in this report were collected by the EIA on Form EIA-6, ''Coal Distribution Report.'' A copy of the form and the instructions for filing appear in Appendix B. All data in this report for 1991 are preliminary. Data for previous years are final. 6 figs., 34 tabs

Black coal. Annual report 1997

International Nuclear Information System (INIS)

1997-01-01

An overview is given of the situation of the world energy industry with regard to all energy carriers. Then energy-political conclusions are drawn for German black coal and the resulting prospects are detailed. Finally, some socio-political aspects are considered with regard to German black-coal mining: Workforce policy, tariff policy, social security and social safeguards for the adaptation process. (orig.) [de

A study of Multistage/Multifunction Column for Fine Coal Cleaning CRADA PC93-005, Final Report; FINAL

International Nuclear Information System (INIS)

Ralph Lai; Shiao-Hung Chiang; Daxin He; Yuru Feng

1998-01-01

The overall objective of the this research project is to explore the potential applicability of a multistage column for fine coal cleaning and other applications in fluid particle separation. The research work identifies the design parameters and their effects on the performance of the separation device. The results of this study provide an engineering data basis for further development of this technology in coal cleaning and in general areas of fluid and particle separations

NMR investigation of coal extracts

Energy Technology Data Exchange (ETDEWEB)

Lang, I; Sebor, G [Ceskoslovenska Akademie Ved, Prague. Hornicky Ustav; Sebor, G Jr; Hajek, M; Mostecky, J [Vysoka Skola Chemicko-Technologicka, Prague (Czechoslovakia)

1978-07-01

Proton NMR spectroscopy was used for the evaluation of 10% coal extract solutions in deuterated pyridine. Four types of Czechoslovak coal were analyzed. Agreement was found between the aromaticity of coal extracts calculated from /sup 1/H NMR data using Brown's method and Ladner's and Williams' method and the characterization of an average molecule of the coal extract by the number of non-bridge carbon atoms of aromatic rings, by the overall number of aromatic ring carbon atoms and the number of aromatic rings, determined by the Williams and Ferris methods. The methods for calculating carbon distribution from /sup 1/H NMR data, however, contain some constants theoretically estimated or experimentally found using the method which still remain to be verified.

Cooperative research in coal liquefaction. Final report, May 1, 1992--April 30, 1993

Energy Technology Data Exchange (ETDEWEB)

Huffman, G.P. [ed.

1996-03-01

Research on sulfate and metal (Mo, Sn) promoted Fe{sub 2}O{sub 3} catalysts in the current year focused on optimization of conditions. Parameters varied included temperature, solvent, solvent-to-coal ratio, and the effect of presulfiding versus in situ sulfiding. Oil yields were found to increase approximately proportionately with both temperature and solvent-to-coal ratio. The donor solvent, tetralin, proved to give better total conversion and oil yields than either 1-methylnaphthalene or Wilsonville recycle oil. A significant enhancement of both total liquefaction yields and oil yields from lignites and subbituminous coals has been achieved by incorporating iron into the coal matrix by cation exchange. A study has been conducted on the synthesis of iron, molybdenum, and tungsten catalysts using a laser pyrolysis technique.

Characterization and supply of coal based fuels. Volume 1, Final report and appendix A (Topical report)

Energy Technology Data Exchange (ETDEWEB)

1992-06-01

Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

Width design for gobs and isolated coal pillars based on overall burst-instability prevention in coal mines

Directory of Open Access Journals (Sweden)

Junfei Zhang

2016-08-01

Full Text Available An investigation was conducted on the overall burst-instability of isolated coal pillars by means of the possibility index diagnosis method (PIDM. First, the abutment pressure calculation model of the gob in side direction was established to derive the abutment pressure distribution curve of the isolated coal pillar. Second, the overall burst-instability ratio of the isolated coal pillars was defined. Finally, the PIDM was utilized to judge the possibility of overall burst-instability and recoverability of isolated coal pillars. The results show that an overall burst-instability may occur due to a large gob width or a small pillar width. If the width of the isolated coal pillar is not large enough, the shallow coal seam will be damaged at first, and then the high abutment pressure will be transferred to the deep coal seam, which may cause an overall burst-instability accident. This approach can be adopted to design widths of gobs and isolated coal pillars and to evaluate whether an existing isolated coal pillar is recoverable in skip-mining mines.

Environmental problems in Russian coal industry

International Nuclear Information System (INIS)

Kharchenko, V.; Oumnov, V.

1996-01-01

The state of the Russian coal industry is complicated both economically and environmentally. Most mines are unprofitable. Several coal mines are intended to be closed. So, under existing conditions, coal mines are unable to give much attention to environmental protection problems. At the same time, coal mining is one of the most polluting industries. The main trends in this industry's negative influence upon the environment are: land spoilage and immobilization to lay out open-pit mines and mineral waste dump areas and tailing piles as well as with industrial waste water runoff; atmospheric pollution with the air coming from underground and substances blown off from dumps, hydrogeological regime intervention in coal mining areas, etc. One way to solve environmental problems in coal mining is a more rational utilization of the accompanying natural coal resources. Such measures make it possible to obtain complementary profits not only at the expense of reducing environmental destruction but producing new kinds of goods or services as well. Examples of similar solutions are solid mineral wastes utilization, underground space utilization, coal gas utilization and other issues

Coal and clean coal technology: challenges and opportunities

Energy Technology Data Exchange (ETDEWEB)

Minchener, Andrew [IEA Clean Coal Centre, London (United Kingdom)

2013-07-01

Globally, there is a growing concern about fuel diversity and security of supply, particularly with regard to oil and natural gas. In contrast, coal is available from a much wider range of sources and has greater price stability. Consequently, coal use is increasing rapidly, and by 2030 may well reach a level of more than 4,500 Mtoe, corresponding to close to a doubling of current levels. However, at the same time, tightening regulations will require better solutions for achieving environmental compliance, for which coal has a number of key issues to address. Most of the coal will be used in the power generation sector. Consequently, the key research challenges are to develop and deploy methods by which coal can be used cleanly, efficiently, and in a sustainable way. These include improvements to existing coal utilisation technologies, particularly to improve operational flexibility and availability, while reducing energy use through higher efficiencies. There is an increasing need to ensure improved emissions control, with the emphasis on achieving ever-lower emissions of particulates, SO{sub 2} and NO{sub x} while also introducing control of trace species, particularly mercury. Alongside this, a key challenge is the integration of techniques that can capture CO{sub 2} then transport and store it within secure geological formations, thereby resulting in near zero emissions of CO{sub 2}. From a power plant perspective, the need is to achieve such integration while minimising any adverse impact on power plant efficiency, performance of existing emissions control systems, operational flexibility and availability. At the same time, means to minimize the additional costs associated with such technology must be established.

Analysis of ecological environment impact of coal exploitation and utilization

Science.gov (United States)

Zhang, Baoliu; Luo, Hong; Lv, Lianhong; Wang, Jian; Zhang, Baoshi

2018-02-01

Based on the theory of life cycle assessment, the ecological and environmental impacts of coal mining, processing, utilization and transportation will be analyzed, with analysing the status of china’s coal exploitation and utilization as the basis, it will find out the ecological and environmental impact in the development and utilization of coal, mainly consist of ecological impact including land damage, water resource destructionand biodiversity loss, etc., while the environmental impact include air, water, solid waste pollutions. Finally with a summary of the ecological and environmental problems, to propose solutionsand countermeasures to promote the rational development and consumption of coal, as well as to reduce the impact of coal production and consumption on the ecological environment, finally to achieve the coordinated development of energy and the environment.

Chemomechanical phenomena in the grinding of coal. Final report, February 1, 1976--May 31, 1977

Energy Technology Data Exchange (ETDEWEB)

Macmillan, N.H.

1977-08-01

Vickers microhardness, drilling rate, grinding rate and zeta-potential measurements have been made on coals of various rank in both aqueous and organic environments in order to determine whether: (a) chemomechanical (Rebinder) effects exist in coal; and (b) any such effects as do exist can be used to improve the comminution of coal. The results reveal the mechanical behavior of coal to be remarkably environment-insensitive as compared to inorganic non-metals. As a result, it is concluded that chemomechanical phenomena offer little prospect of reducing the cost of comminuting coal.

Macroscopic observation of thermal behavior of concentrated solution of coal extracts

Energy Technology Data Exchange (ETDEWEB)

Masao Suzuki; Koyo Norinaga; Masashi Iino [Tohoku University, Sendai (Japan). Institute of Multidisciplinary Research for Advanced Materials

2004-11-01

The solvent extracts of Upper Freeport and Illinois No.6 coals were mixed with N-methyl-2-pyrolidinone (NMP) and annealed at 353 K to produce the gelatinous materials. Differential scanning calorimetric measurements revealed that the materials can hold significant amounts of nonfreezable NMP (as much as 3 g NMP per 1 g coal extracts) which disperse in the materials on a molecular scale, indicating the materials are not phase separated. The thermal behaviors were measured macroscopically as a function of the extract concentration using a needle penetrometer during heating from 223 to 360 K. The penetration-temperature curves were analyzed to estimate the apparent viscosity ({eta}{sub a}). During the penetrations, {eta}{sub a} was decreased very rapidly, approximately four orders of the magnitude by a temperature increase of 20 K, suggesting that the coal extracts-NMP mixtures undergoes a gel to sol transition. The heats of dissociation of crosslinks ({Delta}H{sub m}) were estimated by applying Eldridge-Ferry equation. The {Delta}H{sub m} of coal extracts-NMP mixtures was relatively small, i.e. approximately 10 kJ/mol, whereas the ?Hm of polyvinyl alcohol-NMP gel in which the hydrogen bonds contribute the formation of the physical network structures, was about 65 kJ/mol. Not the specific interaction such as hydrogen bonds, but weak interactions such as van der Waals force were likely to contribute the formation of the coal extracts-NMP gel. 28 refs., 7 figs., 2 tabs.

Hydrogenolysis reactions characteristics of deashed coal under low temperature; Teionka ni okeru dakkai shoritan no suisoka bunkai hanno tokusei

Energy Technology Data Exchange (ETDEWEB)

Owada, T.; Mashimo, K.; Wainai, T. [Nihon University, Tokyo (Japan). College of Science and Technology

1996-10-28

In relation to coal liquefaction, the effect of inorganic minerals on liquefaction reactivity and the effect of hydrofluoric acid (HF) treatment on organic molecular structure of coals were studied by demineralization of low-rank coals in HCl or HF solution. In experiment, Taiheiyo coal specimen was deashed in HCl solution at 25-70{degree}C for 6 hours while agitating, and in addition, deashed in HF solution. Hydrogenolysis of the deashed coal specimen was conducted using tetralin or methylnaphthalene as solvent under initial hydrogen pressure of 1.96MPa at reaction temperature of 693K for 60min. The experimental results are as follows. The ash content of Taiheiyo coal hardly offers catalysis in hydrogenolysis reaction. Carboxyl group increases in demineralization of coal because of breakage of bridged bonds. Organic structure of coal changes by demineralization in dense HF solution. Change in organic structure of coal by demineralization in dense HF solution is dependent on treatment temperature. 2 refs., 4 figs., 1 tab.

British coal-down to the line

International Nuclear Information System (INIS)

Anon.

1993-01-01

The long-running saga of British Coal's decline is in its final stages with virtually no change from last October when the British government announced plants to close 31 of the 50 remaining mines. That announcement produced a political outcry but having privatized the electricity industry in 1990 the government had effectively left itself up the creek without a paddle. It had no powers to force the generators to buy more coal. The status of the British coal industry is discussed

Bioprocessing of lignite coals using reductive microorganisms. Final technical report, September 30, 1988--March 29, 1992

Energy Technology Data Exchange (ETDEWEB)

Crawford, D.L.

1992-03-29

In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

Mercury stable isotope signatures of world coal deposits and historical coal combustion emissions.

Science.gov (United States)

Sun, Ruoyu; Sonke, Jeroen E; Heimbürger, Lars-Eric; Belkin, Harvey E; Liu, Guijian; Shome, Debasish; Cukrowska, Ewa; Liousse, Catherine; Pokrovsky, Oleg S; Streets, David G

2014-07-01

Mercury (Hg) emissions from coal combustion contribute approximately half of anthropogenic Hg emissions to the atmosphere. With the implementation of the first legally binding UNEP treaty aimed at reducing anthropogenic Hg emissions, the identification and traceability of Hg emissions from different countries/regions are critically important. Here, we present a comprehensive world coal Hg stable isotope database including 108 new coal samples from major coal-producing deposits in South Africa, China, Europe, India, Indonesia, Mongolia, former USSR, and the U.S. A 4.7‰ range in δ(202)Hg (-3.9 to 0.8‰) and a 1‰ range in Δ(199)Hg (-0.6 to 0.4‰) are observed. Fourteen (p coal Hg emissions tracing. A revised coal combustion Hg isotope fractionation model is presented, and suggests that gaseous elemental coal Hg emissions are enriched in the heavier Hg isotopes relative to oxidized forms of emitted Hg. The model explains to first order the published δ(202)Hg observations on near-field Hg deposition from a power plant and global scale atmospheric gaseous Hg. Yet, model uncertainties appear too large at present to permit straightforward Hg isotope source identification of atmospheric forms of Hg. Finally, global historical (1850-2008) coal Hg isotope emission curves were modeled and indicate modern-day mean δ(202)Hg and Δ(199)Hg values for bulk coal emissions of -1.2 ± 0.5‰ (1SD) and 0.05 ± 0.06‰ (1SD).

Brayton Point coal conversion project (NEPCO)

Energy Technology Data Exchange (ETDEWEB)

Sullivan, W.F. Jr.

1982-05-01

The New England Power Company (NEPCO) recently converted Brayton Point Power Station Units 1, 2, and 3 from oil to coal. The coal conversion project is the largest coal conversion project in the nation to date. Stone and Webster Engineering Corporation (SWEC) was hired as the engineer/constructor for the project. Units 1 and 2 are 250-MW Combustion Engineering boilers, and Unit 3 is a 650-MW Babcock and Wilcox boiler. All three units were originally designed to burn pulverized coal but were converted to oil during the years of low oil prices. Studies performed by NEPCO and SWEC indicated that the areas discussed in the following paragraphs required upgrading before the units could efficiently burn coal and meet Federal and State environmental requirements. All units have been converted and are operating. This paper discusses design modifications required to burn coal, startup, and initial operating problems, and solutions.

1988 coal price negotiation

Energy Technology Data Exchange (ETDEWEB)

Senmura, Akira

1988-12-01

In the negotiation on raw coal price for 1988, which began at the end of 1987, Australia requested price rise of 4 - 5 dollars for the reason of rise of Australian dollars, conditions of mines, price drop in the past five years, and world supply/demand of coal. Japan insisted to maintain the price of preceding year. The talk ended in a dead lock which could last a long time. Negotiation on the Canadian coal price also encountered difficulties but an agreement was obtained in March as Japan accepted the increased price. After which, Japan and Australia agreed to raise the price by 2.90 dollars and an increase over last year. Producing countries also requested a wide price rise as 7.50 dollars for general coal, making in this area very difficult to progress. Finally, they agreed to raise the price by 6.30 dollars and the electric power utility in Japan responded by importing of U.S. coal, which has a lower heat output but is also cheaper. It depends on Australia for 70% of coal supply but started to diversify the source. 3 tabs.

Impact and environmental handling of the coal in Colombia

International Nuclear Information System (INIS)

Garcia Lozada, Hector

1999-01-01

The coal is a natural resource of great strategic importance for Colombia, in virtue not only of the magnitude of the reserves that possesses the country, but also of its physical-chemistry characteristic, which make it very attractive for the energy generation mainly in European countries and in United States, for the environmental advantages that it offers to consume a coal with contained low percentage of sulfur (maximum 1%) and high heating power. In this chapter a general vision of the Colombian carboniferous sector is presented, followed by a discussion on the environmental impacts of more relevance, associated to the industry and the carboniferous mining that happen in the country. Finally activities and projects of environmental administration are commented, that are in Colombia, with the object to improve the environmental administration of this mineral resource, from the institutional perspective of the participation of the economic agents of the sector, in the solution of the environmental conflicts

Effects of calcium magnesium acetate on the combustion of coal-water slurries. Final project report, 1 September 1989--28 February 1993

Energy Technology Data Exchange (ETDEWEB)

Levendis, Y.A.; Wise, D.; Metghalchi, H.; Cumper, J.; Atal, A.; Estrada, K.R.; Murphy, B.; Steciak, J.; Hottel, H.C.; Simons, G.

1993-07-01

To conduct studies on the combustion of coal water fuels (CWFs) an appropriate facility was designed and constructed. The main components were (1) a high-temperature isothermal laminar flow furnace that facilitates observation of combustion events in its interior. The design of this system and its characterization are described in Chapter 1. (2) Apparatus for slurry droplet/agglomerate particle generation and introduction in the furnace. These devices are described in Chapters 1 and 3 and other attached publications. (3) An electronic optical pyrometer whose design, construction theory of operation, calibration and performance are presented in Chapter 2. (4) A multitude of other accessories, such as particle fluidization devices, a suction thermometer, a velocimeter, high speed photographic equipment, calibration devices for the pyrometer, etc., are described throughout this report. Results on the combustion of CWF droplets and CWF agglomerates made from micronized coal are described in Chapter 3. In the same chapter the combustion of CWF containing dissolved calcium magnesium acetate (CMA) axe described. The combustion behavior of pre-dried CWF agglomerates of pulverized grain coal is contrasted to that of agglomerates of micronized coal in Chapter 4. In the same chapter the combustion of agglomerates of carbon black and diesel soot is discussed as well. The effect of CMA on the combustion of the above materials is also discussed. Finally, the sulfur capture capability of CMA impregnated micronized and pulverized bituminous coals is examined in Chapter 5.

NEW SOLID FUELS FROM COAL AND BIOMASS WASTE; FINAL

International Nuclear Information System (INIS)

Hamid Farzan

2001-01-01

Under DOE sponsorship, McDermott Technology, Inc. (MTI), Babcock and Wilcox Company (B and W), and Minergy Corporation developed and evaluated a sludge derived fuel (SDF) made from sewage sludge. Our approach is to dry and agglomerate the sludge, combine it with a fluxing agent, if necessary, and co-fire the resulting fuel with coal in a cyclone boiler to recover the energy and to vitrify mineral matter into a non-leachable product. This product can then be used in the construction industry. A literature search showed that there is significant variability of the sludge fuel properties from a given wastewater plant (seasonal and/or day-to-day changes) or from different wastewater plants. A large sewage sludge sample (30 tons) from a municipal wastewater treatment facility was collected, dried, pelletized and successfully co-fired with coal in a cyclone-equipped pilot. Several sludge particle size distributions were tested. Finer sludge particle size distributions, similar to the standard B and W size distribution for sub-bituminous coal, showed the best combustion and slagging performance. Up to 74.6% and 78.9% sludge was successfully co-fired with pulverized coal and with natural gas, respectively. An economic evaluation on a 25-MW power plant showed the viability of co-firing the optimum SDF in a power generation application. The return on equity was 22 to 31%, adequate to attract investors and allow a full-scale project to proceed. Additional market research and engineering will be required to verify the economic assumptions. Areas to focus on are: plant detail design and detail capital cost estimates, market research into possible project locations, sludge availability at the proposed project locations, market research into electric energy sales and renewable energy sales opportunities at the proposed project location. As a result of this program, wastes that are currently not being used and considered an environmental problem will be processed into a renewable

Evaluation of technology modifications required to apply clean coal technologies in Russian utilities. Final report

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-12-01

The report describes the following: overview of the Russian power industry; electric power equipment of Russia; power industry development forecast for Russia; clean coal technology demonstration program of the US Department of Energy; reduction of coal TPS (thermal power station) environmental impacts in Russia; and base options of advanced coal thermal power plants. Terms of the application of clean coal technology at Russian TPS are discussed in the Conclusions.

US coal industry seeks export markets

Energy Technology Data Exchange (ETDEWEB)

1981-07-01

Problems encountered in the expansion of the USA export market for coal are discussed, including: lack of port facilities to handle bulk coal shipments; inadequate rail facilities and the already high costs; and delays caused by complex legislation. Solutions to the problem of ports are suggested, and also the advantages of coal export expansion with respect to industry as a whole and unemployment. Details of projects on the Canton Railroad and the terminal in Baltimore are given. Views of the American Association of Port Authorities on navigation are expressed.

Question marks of the Czech coal mining industry

International Nuclear Information System (INIS)

Dopita, M.; Pesek, J.

1995-01-01

An overview of brown and black coal mining in the Czech Republic is presented, and problems of the extent of coal reserves and of the profitability of deep black coal mining are discussed. Costs of coal mining in foreign countries are given. Coal mining in the Czech Republic can be expected to be loss-making unless coal prices are increased. Since coal resources in the Czech Republic are limited, additional nuclear power plants will have to be constructed or else coal for power generation will have to be imported. The environmental aspects of coal mining and burning are discussed. Medium-term and long-term solutions to reduce the environmental burden include thermal power plant desulfurization, application of the fluidized-bed combustion regime to coals with large ash and/or sulfur contents, and introduction of gas in towns and power plants. In the short run, large-scale consumers in towns and coal basins should be obliged to accumulate reserves of low-sulfur coal for later use. (J.B.). 2 tabs., 3 figs., 8 refs

Low-rank coal research: Volume 2, Advanced research and technology development: Final report

Energy Technology Data Exchange (ETDEWEB)

Mann, M.D.; Swanson, M.L.; Benson, S.A.; Radonovich, L.; Steadman, E.N.; Sweeny, P.G.; McCollor, D.P.; Kleesattel, D.; Grow, D.; Falcone, S.K.

1987-04-01

Volume II contains articles on advanced combustion phenomena, combustion inorganic transformation; coal/char reactivity; liquefaction reactivity of low-rank coals, gasification ash and slag characterization, and fine particulate emissions. These articles have been entered individually into EDB and ERA. (LTN)

Density equation of bio-coal briquettes and quantity of maize cob in Phitsanulok, Thailand

Energy Technology Data Exchange (ETDEWEB)

Patomsok Wilaipon [Naresuan University, Phitsanulok (Thailand). Department of Mechanical Engineering

2008-07-01

One of the most important crops in Phitsanulok, a province in Northern Thailand, is maize. BaseD on the calculation, the quantity of maize cob produced in this region was approximately 220 kton year{sup -1}. The net heating value of maize cob was found to be 14.2 MJ kg{sup -1}. Therefore, the total energy over 874 TJ year-1 can be obtained from this agricultural waste. In the experiments, maize cob was utilized as the major ingredient for producing biomass-coal briquettes. The maize cob was treated with sodium hydroxide solution before mixing with coal fine. The ratios of coal:maize were 1:2 and 1:3, respectively. The range of briquetting pressures was from 4-8 MPa. The result showed that the density was strongly affected by both parameters. Finally, the relationship between biomass ratio, briquetting pressures and briquette density was developed and validated by using regression technique. 13 refs., 2 figs.

Quarterly coal statistics of OECD countries

Energy Technology Data Exchange (ETDEWEB)

1992-04-27

These quarterly statistics contain data from the fourth quarter 1990 to the fourth quarter 1991. The first set of tables (A1 to A30) show trends in production, trade, stock change and apparent consumption data for OECD countries. Tables B1 to B12 show detailed statistics for some major coal trade flows to and from OECD countries and average value in US dollars. A third set of tables, C1 to C12, show average import values and indices. The trade data have been extracted or derived from national and EEC customs statistics. An introductory section summarizes trends in coal supply and consumption, deliveries to thermal power stations; electricity production and final consumption of coal and tabulates EEC and Japanese steam coal and coking coal imports to major countries.

77 FR 56717 - Specifications for Medical Examinations of Underground Coal Miners

Science.gov (United States)

2012-09-13

... CFR Part 37 Specifications for Medical Examinations of Underground Coal Miners; Final Rule #0;#0... 0920-AA21 Specifications for Medical Examinations of Underground Coal Miners AGENCY: Centers for... medical examinations of underground coal miners. Existing regulations established specifications for...

Utilisation of chemically treated coal

International Nuclear Information System (INIS)

Bezovska, M.

2002-01-01

The numerous application of coal with high content of humic substances are known. They are used in many branches of industry. The complex study of the composition of coal from upper Nitra mines has directed research to its application in the field of ecology and agriculture. The effective sorption layers of this coal and their humic acids can trap a broad spectrum of toxic harmful substances present in industrial wastes, particularly heavy metals. A major source of humic acids is coal - the most abundant and predominant product of plant residue coalification. All ranks of coal contain humic acids but lignite from Novaky deposit represents the most easily available and concentrated from of humic acids. The possibilities of utilisation of humic acids to remove heavy metals from waste waters was studied. The residual concentrations of the investigated metals in the aqueous phase were determined by AAs. From the results follows that the samples of coals humic acids can be used for the heavy metal removal from metal solutions and the real acid mine water. Oxidised coal with high content of humic acids and nitrogen is used in agriculture as fertilizer. Humic acids are active component in coal and can help to utilize almost quantitatively nitrogen in soil. The humic substances block and stabilize toxic metal residues already present in soil. (author)

Evaluating the costs and achievable benefits of extending technologies for uneconomical coal resources in South Africa: the case of underground coal gasification

CSIR Research Space (South Africa)

Zieleniewski, M

2008-11-01

Full Text Available -3433. Shoko, E., McLellan, B., Dicks, A.L., Diniz da Costa, J.C., 2006. Hydrogen from coal: Production and utilisation technologies. International Journal of Coal Geology, 65(3-4): 213-222. Simeons, C., 1978. Coal: Its role in tomorrow’s technol- ogy... the consideration of other, alternative solutions to the energy shortage problem. Underground coal gasifi- cation (UCG) is among the most promising tech- nologies and, to an acceptable degree, the proven feasible one (Walker et al., 2001; Ergo Exergy, 2005...

Utilisation of chemically treated coal

Directory of Open Access Journals (Sweden)

Bežovská Mária

2002-03-01

Full Text Available The numerous application of coal with high content of humic substances are known. They are used in many branches of industry. The complex study of the composition of coal from upper Nitra mines has directed research to its application in the field of ecology and agriculture. The effective sorption layers of this coal and their humic acids can to trap a broad spectrum of toxic harmful substances present in industrial wastes, particularly heavy metals. A major source of humic acids is coal - the most abundant and predominant product of plant residue coalification. All ranks of coal containt humic acids but lignite from Nováky deposit represents the most easily available and concentrated form of humic acids. Deep oxidation of coal by HNO3 oxidation - degradation has been performed to produce water-soluble-organic acids. The possibilities of utilisation of oxidised coal and humic acids to remove heavy metals from waste waters was studied. The residual concentrations of the investigated metals in the aqueous phase were determined by AAs. From the results follows that the samples of oxidised coal and theirs humic acids can be used for the heavy metal removal from metal solutions and the real acid mine water.Oxidised coal with a high content of humic acids and nitrogen is used in agriculture a fertilizer. Humic acids are active component in coal and help to utilize almost quantitatively nitrogen in soil. The humic substances block and stabiliz toxic metal residues already present in soil.

Coal geology and assessment of coal resources and reserves in the Powder River Basin, Wyoming and Montana

Science.gov (United States)

Luppens, James A.; Scott, David C.

2015-01-01

This report presents the final results of the first assessment of both coal resources and reserves for all significant coal beds in the entire Powder River Basin, northeastern Wyoming and southeastern Montana. The basin covers about 19,500 square miles, exclusive of the part of the basin within the Crow and Northern Cheyenne Indian Reservations in Montana. The Powder River Basin, which contains the largest resources of low-sulfur, low-ash, subbituminous coal in the United States, is the single most important coal basin in the United States. The U.S. Geological Survey used a geology-based assessment methodology to estimate an original coal resource of about 1.16 trillion short tons for 47 coal beds in the Powder River Basin; in-place (remaining) resources are about 1.15 trillion short tons. This is the first time that all beds were mapped individually over the entire basin. A total of 162 billion short tons of recoverable coal resources (coal reserve base) are estimated at a 10:1 stripping ratio or less. An estimated 25 billion short tons of that coal reserve base met the definition of reserves, which are resources that can be economically produced at or below the current sales price at the time of the evaluation. The total underground coal resource in coal beds 10–20 feet thick is estimated at 304 billion short tons.

A spatial analysis of China's coal flow

International Nuclear Information System (INIS)

Mou Dunguo; Li Zhi

2012-01-01

The characteristics of China's energy structure and the distribution of its coal resources make coal transportation a very important component of the energy system; moreover, coal transportation acts as a bottleneck for the Chinese economy. To insure the security of the coal supply, China has begun to build regional strategic coal reserves at some locations, but transportation is still the fundamental way to guaranty supply security. Here, we study China's coal transportation quantitatively with a linear programming method that analyses the direction and volume of China's coal flows with the prerequisite that each province's supply and demand balance is guaranteed. First, we analyse the optimal coal transportation for the status quo coal supply and demand given the bottleneck effects that the Daqin Railway has on China's coal flow; second, we analyse the influence of future shifts in the coal supply zone in the future, finding that China's coal flows will also change, which will pressure China to construct railways and ports; and finally, we analyse the possibility of exploiting Yangtze River capacity for coal transportation. We conclude the paper with suggestions for enhancing China's coal transportation security. - Highlights: ► We use linear programming to study China's coal transportation. ► First, analyse the optimal coal flow under the status quo condition. ► Second, analyse influences of coal supply zone shifts to Neimeng and Xinjiang. ► Third, analyse the influence of using Yangtze River for coal transportation. ► At last, we give suggestions about infrastructure construction to guaranty China's long-run coal supply security.

Methane emissions from coal mining

International Nuclear Information System (INIS)

Williams, A.; Mitchell, C.

1993-01-01

This paper outlines some of the problems associated with the prediction of levels of methane emission from underground and surface coal mines. Current knowledge of coal mining emissions sources is outlined. On the basis of this information the methodology proposed by the IPCC/OECD Programme on National Inventories is critically examined and alternatives considered. Finally, the technical options for emissions control are examined together with their feasibility. 8 refs., 6 figs., 2 tabs

Computer application in coal preparation industry in China

Energy Technology Data Exchange (ETDEWEB)

Lu, M.; Wu, L.; Ni, Q. (China Univ. of Mining and Technology, Xuzhou (China))

1990-01-01

This paper describes several packages of microcomputer programs developed for designing and managing the coal preparation plants. Three parts are included: Coal Cleaning Package (CCP), Coal Preparation Optimization Program (CPO) and Coal Preparation Computer Aided Design System (CPCAD). The function of CCP is: evaluating and predicting coal cleaning result. Coal presentation process modelling and optimization; coal preparation flowsheet design and optimization. The CPO is a nonlinear optimization program. It can simulate and optimize the profit for different flowsheet to get the best combination of the final products. The CPCAD was developed based upon AutoCAD and makes full use of AutoLISP, digitizer menus and AutoCAD commands, combining the functions provided by AutoCAD and the principle used in conventional coal preparation plant design, forming a designer-oriented CPCAD system. These packages have proved to be reliable, flexible and easy to learn and use. They are a powerful tool for coal preparation plant design and management. (orig.).

National coal utilization assessment. An integrated assessment of increased coal use in the Midwest: impacts and constraints

Energy Technology Data Exchange (ETDEWEB)

Hoover, L. John

1977-10-01

This study was performed as a part of the Argonne National Laboratory Regional Studies program, which is sponsored by the Department of Energy. The purpose is to assess the impacts and consequences associated with alternative energy options on a regional basis, and to identify and analyze alternative mitigation and solution strategies for increasing the acceptability of these options. The National Coal Utilization Assessment is being conducted as a part of the Regional Studies Program. This particular study is focusing on impacts and constraints on increased coal utilization. In addition, a major focal point for the study is the identification and analysis of alternative solution strategies applicable to these constraints and problems.

H-coal fluid dynamics. Final report, August 1, 1977-December 31, 1979

Energy Technology Data Exchange (ETDEWEB)

1980-04-16

This report presents the results of work aimed at understanding the hydrodynamic behavior of the H-Coal reactor. A summary of the literature search related to the fluid dynamic behavior of gas/liquid/solid systems has been presented. Design details of a cold flow unit were discussed. The process design of this cold flow model followed practices established by HRI in their process development unit. The cold fow unit has been used to conduct experiments with nitrogen, kerosene, or kerosene/coal char slurries, and HDS catalyst, which at room temperature have properties similar to those existing in the H-Coal reactor. Mineral oil, a high-viscosity liquid, was also used. The volume fractions occupied by gas/liquid slurries and catalyst particles were determined by several experimental techniques. The use of a mini-computer for data collection and calculation has greatly accelerated the analysis and reporting of data. Data on nitrogen/kerosene/HDS catalyst and coal char fines are presented in this paper. Correlations identified in the literature search were utilized to analyze the data. From this analysis it became evident that the Richardson-Zaki correlation describes the effect of slurry flow rate on catalyst expansion. Three-phase fluidization data were analyzed with two models.

Materials, process, product analysis of coal process technology. Phase I final report

Energy Technology Data Exchange (ETDEWEB)

Saxton, J. C.; Roig, R. W.; Loridan, A.; Leggett, N. E.; Capell, R. G.; Humpstone, C. C.; Mudry, R. N.; Ayres, E.

1976-02-01

The purpose of materials-process-product analysis is a systematic evaluation of alternative manufacturing processes--in this case processes for converting coal into energy and material products that can supplement or replace petroleum-based products. The methodological steps in the analysis include: Definition of functional operations that enter into coal conversion processes, and modeling of alternative, competing methods to accomplish these functions; compilation of all feasible conversion processes that can be assembled from combinations of competing methods for the functional operations; systematic, iterative evaluation of all feasible conversion processes under a variety of economic situations, environmental constraints, and projected technological advances; and aggregative assessments (economic and environmental) of various industrial development scenarios. An integral part of the present project is additional development of the existing computer model to include: A data base for coal-related materials and coal conversion processes; and an algorithmic structure that facilitates the iterative, systematic evaluations in response to exogenously specified variables, such as tax policy, environmental limitations, and changes in process technology and costs. As an analytical tool, the analysis is intended to satisfy the needs of an analyst working at the process selection level, for example, with respect to the allocation of RDandD funds to competing technologies.

Solvent-refined-coal (SRC) process. Volume II. Sections V-XIV. Final report

Energy Technology Data Exchange (ETDEWEB)

1982-05-01

This report documents the completion of development work on the Solvent Refined Coal Process by The Pittsburgh and Midway Coal Mining Co. The work was initiated in 1966 under Office of Coal Research, US Department of Interior, Contract No. 14-01-0001-496 and completed under US Department of Energy Contract No. DE-AC05-79ET10104. This report discusses work leading to the development of the SRC-I and SRC-II processes, construction of the Fort Lewis Pilot Plant for the successful development of these processes, and results from the operation of this pilot plant. Process design data generated on a 1 ton-per-day Process Development Unit, bench-scale units and through numerous research projects in support of the design of major demonstration plants are also discussed in summary form and fully referenced in this report.

Optimal carbon tax with a dirty backstop: Oil, coal, or renewables?

OpenAIRE

van der Ploeg, Frederick; Withagen, Cees A.

2011-01-01

Optimal climate policy is studied. Coal, the abundant resource, contributes more CO2 per unit of energy than the exhaustible resource, oil. We characterize the optimal sequencing oil and coal and departures from the Herfindahl rule. "Preference reversal" can take place. If coal is very dirty compared to oil, there is no simultaneous use. Else, the optimal outcome starts with oil, before using oil and coal together, and finally coal on its own. The "laissez-faire" outcome uses coal forever or ...

Australian coal prospects and response to air quality issues

International Nuclear Information System (INIS)

Cain, D.A.

1992-01-01

Australia is unique in its high dependency on coal as a domestic energy source and as a major export commodity. Coal provides about 41% of Australia's primary energy and is the country's largest export. Australia's domestic air quality issues and standards are reviewed and current Australian research aimed at reducing emissions from both bituminous and brown coal combustion is summarized. Australia's greenhouse policy is also discussed. The future role of coal in the world, particularly in the Asia-Pacific region, where three quarters of Australia's coal exports are sold, is reviewed. Forecasts of the world import demand for both metallurgical coal and thermal coal to the year 2000 are provided. The supply capacity of major coal exporting countries in summarized and estimates of export coal market shares in 2000 given. Finally, the future of Australia's domestic use of coal is discussed, in the light of climate change concerns

Blackout: coal, climate and the last energy crisis

Energy Technology Data Exchange (ETDEWEB)

Heinberg, R. [Post Carbon Institute in California, CA (United States)

2009-07-15

Coal fuels more than 30 per cent of UK electricity production, and about 50 per cent in the US, providing a significant portion of total energy output. China and India's recent ferocious economic growth has been based almost entirely on coal-generated electricity. Coal currently looks like a solution to many of our fast-growing energy problems. However, while coal advocates are urging us full steam ahead, the increasing reliance on this dirtiest of all fossil fuels has crucial implications for energy policy, pollution levels, the global climate, world economy and geopolitics. Drawbacks to a coal-based energy strategy include: Scarcity - new studies suggest that the peak of world coal production may actually be less than two decades away; Cost - the quality of produced coal is declining, while the expense of transportation is rising, leading to spiralling costs and increasing shortages; and, Climate impacts - our ability to deal with the historic challenge of climate change may hinge on reducing coal consumption in future years.

Exploration of coal-based pitch precursors for ultra-high thermal conductivity graphite fibers. Final report

Energy Technology Data Exchange (ETDEWEB)

Deshpande, G.V. [Amoco Performance Products, Inc., Alpharetta, GA (United States)

1996-12-27

Goal was to explore the utility of coal-based pitch precursors for use in ultra high thermal conductivity carbon (graphite) fibers. From graphite electrode experience, it was established that coal-based pitches tend to form more highly crystalline graphite at lower temperatures. Since the funding was limited to year 1 effort of the 3 year program, the goal was only partially achieved. The coal-base pitches can form large domain mesophase in spite of high N and O contents. The mesophase reactivity test performed on one of the variants of coal-based pitch (DO84) showed that it was not a good candidate for carbon fiber processing. Optimization of WVU`s isotropic pitch process is required to tailor the pitch for carbon fiber processing. The hetero atoms in the coal pitch need to be reduced to improve mesophase formation.

A clean coal: myth or reality?

International Nuclear Information System (INIS)

2010-01-01

The first part of this report comments the evolution of coal demand which has doubled during the last 35 years for different reasons (increase of electricity production, development of China and India), but is still based on local production although coal international trade increased indeed quicker than coal demand. It notices that there is still a lot of coal available for the future, and that demand will keep on increasing. It outlines that coal will have to reduce its impacts on the environment, and presents the technologies which will allow this reduction. It also presents the technologies for CO 2 capture and storage (CCS), and evokes its regulatory issues and its environmental impacts. Some research and development projects in CCS in different countries (Europe, Germany, United States, Australia) are presented. Finally, it stresses the importance of a global deployment of much less polluting technologies to limit greenhouse gas emissions

Use of analcime zeolite from mineral coal fly ash in adsorption of Cu"+"2 and Cd"+"2 in aqueous solutions

International Nuclear Information System (INIS)

Rocha Junior, C.A.F.; Santos, S.C.A.; Angelica, R.S.; Neves, R.F.; Souza, C.A.G.

2011-01-01

The use of zeolite for removing heavy metals from contaminated effluents over the years has been widespread due to its high cation exchange capacity in aqueous solutions. Thus this study aims to use analcime zeolite for removal of Cu"+"2 and Cd"+"2 from aqueous solutions at different concentrations, and the zeolitic material synthesized from coal fly ash generated in an alumina plant in northern Brazil . The use of zeolite analcime proved quite satisfactory, since this product has removed almost entirely Cu"+"2 and Cd"+"2 solutions with concentrations up to 200ppm, and demonstrated an average capacity for solutions of 400ppm, which shows good applicability of this material for the treatment of effluent contamination in the ranges studied. The adsorption models of Langmuir and Freundlich showed a good fit to experimental data generated in this work. (author)

Gasification in pulverized coal flames. Final report (Part I). Pulverized coal combustion and gasification in a cyclone reactor: experiment and model

Energy Technology Data Exchange (ETDEWEB)

Barnhart, J. S.; Laurendeau, N. M.

1979-05-01

A unified experimental and analytical study of pulverized coal combustion and low-BTU gasification in an atmospheric cyclone reactor was performed. Experimental results include several series of coal combustion tests and a coal gasification test carried out via fuel-rich combustion without steam addition. Reactor stability was excellent over a range of equivalence ratios from .67 to 2.4 and air flowrates from 60 to 220 lb/hr. Typical carbon efficiencies were 95% for air-rich and stoichiometric tests and 80% for gasification tests. The best gasification results were achieved at an equivalence ratio of 2.0, where the carbon, cold gas and hot gas efficiencies were 83, 45 and 75%, respectively. The corresponding product gas heating value was 70 BTU/scf. A macroscopic model of coal combustion in the cyclone has been developed. Fuel-rich gasification can also be modeled through a gas-phase equilibrium treatment. Fluid mechanics are modeled by a particle force balance and a series combination of a perfectly stirred reactor and a plug flow reactor. Kinetic treatments of coal pyrolysis, char oxidation and carbon monoxide oxidation are included. Gas composition and temperature are checked against equilibrium values. The model predicts carbon efficiency, gas composition and temperature and reactor heat loss; gasification parameters, such as cold and hot gas efficiency and make gas heating value, are calculated for fuel-rich conditions. Good agreement exists between experiment and theory for conditions of this investigation.

Healy Clean Coal Project, Healy, Alaska final Environmental Monitoring Plan

Energy Technology Data Exchange (ETDEWEB)

1994-06-14

This Environmental Monitoring Plan (EMP) provides the mechanism to evaluate the integrated coal combustion/emission control system being demonstrated by the Healy Clean Coal Project (HCCP) as part-of the third solicitation of the US Department of Energy (DOE) Clean Coal Technology Demonstration Program (CCT-III). The EMP monitoring is intended to satisfy two objectives: (1) to develop the information base necessary for identification, assessment, and mitigation of potential environmental problems arising from replication of the technology and (2) to identify and quantify project-specific and site-specific environmental impacts predicted in the National Environmental Policy Act (NEPA) documents (Environmental Impact Statement and Record of Decision). The EMP contains a description of the background and history of development of the project technologies and defines the processes that will take place in the combustion and spray dryer absorber systems, including the formation of flash-calcined material (FCM) and its use in sulfur dioxide (SO{sub 2}) removal from the flue gases. It also contains a description of the existing environmental resources of the project area. The EMP includes two types of environmental monitoring that are to be used to demonstrate the technologies of the HCCP: compliance monitoring and supplemental monitoring. Compliance monitoring activities include air emissions, wastewater effluents, and visibility. Monitoring of these resources provide the data necessary to demonstrate that the power plant can operate under the required state and federal statutes, regulations, and permit requirements.

Kinetic comparison of biological and conventional flotation of coal

Energy Technology Data Exchange (ETDEWEB)

Amini, E.; Oliazadeh, M.; Kolahdoozan, M. [University of Queensland, Brisbane, Qld. (Australia)

2009-03-15

Froth flotation is commonly used in coal processing to selectively recover the organic material (coal) from inorganic waste material. Tabas coal, located in east Iran, contains fine disseminated pyrite which is floated with coal during flotation, and hence decreasing the quality of the final concentrate. Reagents, such as sodium cyanide, are typically added to depress pyrite. Due to the toxicity of cyanide, alternative strategies for depressing pyrite flotation are being investigated. In this paper the metallurgical performance of Tabas coal treated with sodium cyanide is compared to that of Tabas coal which has undergone bacterial treatment using Acidithiobacillus ferrooxidans. Results indicate that bacterial treatment decreases the flotation rate of pyrite and improves the selectivity between coal and gangue. The possibility of using bacteria in place of toxic chemicals such as cyanide has significant environmental benefit.

Prospect of coal liquefaction in Indonesia

International Nuclear Information System (INIS)

Hartiniati; Dasuki, A.S.; Artanto, Yu.; Sulaksono, D.; Gunanjar

1997-01-01

With the current known oil reserves of about 11 billion barrel and annual production of approximately 500 million barrel, the country's oil reserves will be depleted by 2010, and Indonesia would have become net oil importer if no major oil fields be found somewhere in the archipelago. Under such circumstances the development of new sources of liquid fuel becomes a must, and coal liquefaction can be one possible solution for the future energy problem in Indonesia, particularly in the transportation sector due to the availability of coal in huge amount. This paper present the prospect of coal liquefaction in Indonesia and look at the possibility of integrating the process with HTR as a heat supplier. Evaluation of liquidability of several low grade Indonesian coals will also be presented. Coal from South Banko-Tanjung Enim is found to be one of the most suitable coal for liquefaction. Several studies show that an advanced coal liquefaction technology recently developed has the potential to reduce not only the environmental impact but also the production cost. The price of oil produced in the year 2000 is expected to reach US $ 17.5 ∼ 19.2/barrel and this will compete with the current oil price. Not much conclusion can be drawn from the idea of integrating HTR with coal liquefaction plant due to limited information available. (author). 7 figs, 3 tabs

Coal, economic development and the environment

International Nuclear Information System (INIS)

Tallboys, Richard.

1995-01-01

This paper discusses the current importance of coal to the world's energy supply. It outlines its growing importance as a fuel for many developing economies around the world and for the most dynamic industrialised countries of Asia. It then refers to the key environmental issues that are involved in a growing worldwide use of coal and emphasises the role that coal will increasingly play in generating the electricity that accompanies an improving standard of living for the world's poor. Finally, the environmental consequences of economic development by and for those who want to live at a standard of living that Australians take for granted are discussed. 4 tabs

Alkali-assisted coal extraction with polar aprotic solvents

Energy Technology Data Exchange (ETDEWEB)

Makgato, M.H.; Moitsheki, L.J.; Shoko, L.; Kgobane, B.L.; Morgan, D.L.; Focke, W.W. [SARChI Chair in Carbon Technology and Materials, Institute of Applied Materials, University of Pretoria, Pretoria 0002 (South Africa)

2009-04-15

Coal extraction experiments were conducted using a coal, containing ca. 10% ash, from the Tshikondeni mine in South Africa. This coal dissolves only to a limited extent in pure polar aprotic solvents such as dimethylformamide (DMF) and N-methyl-2-pyrrolidinone (NMP). However, the addition of a strong base, e.g. sodium hydroxide (NaOH) or sodium tert-butoxide increased the degree of coal dissolution in these organic solvents. Depending on the extraction conditions, carbon extraction efficiencies of up to 90% were obtained. Carbon precursor material was recovered from the solution as a gel by precipitation with water. Ash content was reduced from 10% in the coal to less than 1.6% in the coal extracts. Sodium sulfide (Na{sub 2}S) addition further reduced ash content and aided the recovery of carbon precursors that led to graphitizable cokes but the degree of extraction was significantly reduced. (author)

Activated carbons from Mongolian coals by thermal treatment

Directory of Open Access Journals (Sweden)

A Ariunaa

2014-09-01

Full Text Available Mongolian different rank coals were used as raw material to prepare activatedcarbons by physical activation method. The coal derived carbons were oxidized with nitric acid in order to introduce surface oxygen groups. The ultimate elemental analysis, scanning electron microscopy, surface area, pore size distribution analysis and selective neutralization method were used to characterize the surface properties of activated carbons, oxidizedcarbons and raw coals. The effect of coal grade on the adsorption properties of the carbons were studied. It was concluded that Naryn sukhait bituminous coal could be serve as suitable raw material for production of activated carbons for removal of heavy metal ions from solution.DOI: http://dx.doi.org/10.5564/mjc.v12i0.174 Mongolian Journal of Chemistry Vol.12 2011: 60-64

China's Coal: Demand, Constraints, and Externalities

Energy Technology Data Exchange (ETDEWEB)

Aden, Nathaniel; Fridley, David; Zheng, Nina

2009-07-01

This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of

Superacid Catalyzed Depolymerization and Conversion of Coals. Final Technical Report. [HF:BF{sub 2}/H{sub 2}

Science.gov (United States)

Olah, G.

1980-01-01

We were interested in applying superacid catalyzed cleavage-depolymerization and ionic hydrogenation low temperature conversion of coal to liquid hydrocarbon, as well as obtaining information about the reactions involved and the structure of intermediates of the coal liquefaction process. In order to show the feasibility of our proposed research we have carried out preliminary investigation in these areas. Preceding our work there was no practical application of a superacid system to coal liquefaction. We carried out an extensive study of the potential of the HF:BF{sub 3}/H{sub 2} system for coal hydroliquefaction. Under varying conditions of reactant ratio, reaction time and temperature, we were able to obtain over 95% pyridine extractible product by treating coal in HF:BF{sub 3}:H{sub 2} system at approx. 100 degrees C for 4 hours. The coal to acid ratio was 1:5 and FB{sub 3} at 900 psi and H{sub 2} at 500 psi were used. These are extremely encouraging results in that the conditions used are drastically milder than those used in any known process, such as Exxon donor solvent and related processes. The cyclohexane extractibility of the treated coal was as high as 27% and the yield of liquid distillate at 400 degrees C/5 x 10{sup -3}/sup torr/ was approx. 30%. The infrared spectrum of product coal, extracts and distillates were distinctly different from the starting coal and show a significant increase in the amount of saturates. The {sup 1}H NMR spectrum of cyclohexane extract of the treated coal shows essentially all aliphatic photons. The spectra of other treated coal extracts show increased amounts and types of aliphatic protons as well as significant amounts of protons bound to unsaturated sites. This again indicates that the HF-BF{sub 3} system is depolymerizing the coal to small fragments which are soluble in non-polar solvents.

Cooperative research in coal liquefaction. Final report, May 1, 1991--April 30, 1992

Energy Technology Data Exchange (ETDEWEB)

Huffman, G.P. [ed.

1996-03-01

Extensive research continued on catalysts based on novel anion-treated (mainly sulfated) oxides and oxyhydroxides of iron [Fe{sub x}O{sub y}/SO{sub 4}]. In addition, sulfated oxides of tin as well as molybdenum promoted iron oxides were used. Incorporation of small amounts of sulfate, molybdate, or tungstate anions by wet precipitation/impregnation methods was found to increase the surface acidic character of iron oxides; more importantly, it reduced the grain sizes significantly with corresponding increases in specific surface areas. These anion-treated iron and tin oxides were more active for direct coal liquefaction and coal-heavy oil coprocessing than their untreated counterparts. With these catalyst systems, higher conversion levels are obtained as compared to the soluble precursors of iron and molybdenum at the same catalyst metalloading (3500 ppm iron and 50 ppm molybdenum with respect to coal). Sulfated iron oxides and oxyhydroxides were equally active as coal liquefaction catalysts. The sulfate, molybdate, and tungstate anions were found to have similar promotional effects on the properties and activities of iron oxides. One step in the synthesis of anion-treated iron and tin oxides is precipitation as hydroxides using either urea or ammonium hydroxide. The catalysts prepared using urea as a precipitation agent were more reproducible than those using ammonium, hydroxide in terms of activities and properties. These catalysts/catalyst precursors were characterized by several techniques to determine their physical (size and structure related) and chemical (acidity) properties. Sulfated and molybdated iron oxides were found to have grain sizes as small as 10-20 nm. An attempt was made to correlate the physicochemical properties of these catalysts with their activity for coal liquefaction.

Modelling a coal subcrop using the impedance method

Energy Technology Data Exchange (ETDEWEB)

Wilson, G.A.; Thiel, D.V.; O' Keefe, S.G. [Griffith University, Nathan, Qld. (Australia). School of Microelectronic Engineering

2000-07-01

An impedance model was generated for two coal subcrops in the Biloela and Middlemount areas (Queensland, Australia). The model results were compared with actual surface impedance data. It was concluded that the impedance method satisfactorily modelled the surface response of the coal subcrops in two dimensions. There were some discrepancies between the field data and the model results, due to factors such as the method of discretization of the solution space in the impedance model and the lack of consideration of the three-dimensional nature of the coal outcrops. 10 refs., 8 figs.

Recovering uranium from coal in-situ. Final report, February 1980-July 1981

International Nuclear Information System (INIS)

1981-01-01

In Situ Technology, Inc., ''InTech,'' has designed a new process for recovery of uranium from coal in situ. Prime objectives of the program reported herein are to reduce two uncertainties related to eventual commercialization of the process. The first uncertainty concerns appropriate field sites and their potential. The work involved laboratory tests and analysis of field samples, burning the samples to ash and leaching uranium from residual ash at laboratory scale, and burning the samples to ash and leaching uranium from residual ash at pilot plant scale. Laboratory and pilot plant tests were designed to simulate significant elements of the underground process. Field samples from New Mexico averaged 0.061% U 3 O 8 and from North Dakota 0.058% of U 3 O 8 in the coal, both on a dry basis. Phase I laboratory tests on New Mexico field samples were successfully conducted with no difficulties in reducing uraniferous coal to ash. Leaching tests resulted in uranium recoveries to 77.9% with acid leach and to 56% with alkaline leach. Phase II laboratory and pilot plant scale tests were successfully conducted on North Dakota field samples, but required supplemental fuel and/or enrichment for reducing uraniferous coal to ash. Acid leaching of residual ash resulted in uranium recoveries to 83.8%. Acid consumption was 71.0 pounds per ton during pilot plant scale leaching tests. The overall analysis and test program is considered to be highly successful and resulted in significant reduction of the uncertainties for eventual commercialization of the process. 3 refs

A computerized coal-water slurry transportation model

Energy Technology Data Exchange (ETDEWEB)

Ljubicic, B.R.; Trostad, B. [Univ. of North Dakota, Grand Forks, ND (United States); Bukurov, Z.; Cvijanovic, P. [Univ. of Novi Sad (Yugoslavia)

1995-12-01

Coal-water fuel (CWF) technology has been developed to the point where full-scale commercialization is just a matter of gaining sufficient market confidence in the price stability of alternate fossil fuels. In order to generalize alternative fuel cost estimates for the desired combinations of processing and/or transportation, a great deal of flexibility is required owing to the understood lack of precision in many of the newly emerging coal technologies. Previously, decisions regarding the sequential and spatial arrangement of the various process steps were made strictly on the basis of experience, simplified analysis, and intuition. Over the last decade, computer modeling has progressed from empirically based correlation to that of intricate mechanistic analysis. Nomograms, charts, tables, and many simple rules of thumb have been made obsolete by the availability of complex computer models. Given the ability to view results graphically in real or near real time, the engineer can immediately verify, from a practical standpoint, whether the initial assumptions and inputs were indeed valid. If the feasibility of a project is being determined in the context of a lack of specific data, the ability to provide a dynamic software-based solution is crucial. Furthermore, the resulting model can be used to establish preliminary operating procedures, test control logic, and train plant/process operators. Presented in this paper is a computerized model capable of estimating the delivered cost of CWF. The model uses coal-specific values, process and transport requirements, terrain factors, and input costs to determine the final operating configuration, bill of materials, and, ultimately, the capital, operating, and unit costs.

Analytical support for coal technologies

Directory of Open Access Journals (Sweden)

Valášek Václav

1998-09-01

Full Text Available On the basis of success in the selection negotiation The Brown Coal Research Institute j.s.c. Most was authorized to process the project Phare D5/93 with the title "Analytical support to clean coal technologies". The elaboration of the task run in 1997 in a close cooperation with the Mining University - TU Ostrava; DBI - AUA GmbH, Freiberg, Germany; DMT mbH, Essen, Germany and Cerchar, Mazingarbe, France. In the work the available reserves of brown and hard coal and from them following possible levels of annual minings in relation to prognosed needs of the electro-energetics and heating-industry were evaluated. The knowledge about the contents of selected trace elements (As, Be, Cd, Cl, Co, Cr, Cu, F, Hg, Mn, Ni, Pb, Sb, Se, Te, Tl, V, Zn in Czech (CZ coal were also evaluated it was investigated. Further, the distribution of trace elements during the burning process in four types of boilers in CZ. was investigated. The CZ and EU legislation related to trace elements in coal and combustion products was finally comparred. It was stated that the CZ legal standards are not at variant with EU the standards.

Commission on energy and the environment. Coal study. An overview paper by the NCB

Energy Technology Data Exchange (ETDEWEB)

1979-01-01

The environmental effects of deep-mined production and opencast coal production are examined. Methods of using coal and some environmental consequences of coal utilisation are considered. Finally it describes the geographical pattern of coal production and exploration and deals briefly with the planning and employment implications - particularly for new capacity. (25 refs.) Available from IEA Coal Research, please quote ICTIS/M0105.

Kinetics assisted design of catalysts for coal liquefaction. Final report

Energy Technology Data Exchange (ETDEWEB)

Klein, M.T.; Foley, H.C.; Calkins, W.H.; Scouten, C.

1998-02-01

The thermal and catalytic reactions of 4-(1-naphthylmethyl)bibenzyl (NBBM), a resid and coal model compound, were examined. Catalytic reaction of NBBM was carried out at 400 C under hydrogen with a series of transition metal-based catalytic materials including Fe(CO){sub 4}PPh{sub 3}, Fe(CO){sub 3}(PPh{sub 3}){sub 2}, Fe(CO){sub 2}(PPh{sub 3}){sub 2}CS{sub 2}, Fe(CO){sub 5}, Mo(CO){sub 6}, Mn{sub 2}(CO){sub 10}, Fe{sub 2}O{sub 3} and MoS{sub 2}. Experimental findings and derived mechanistic insights were organized into molecular-level reaction models for NBBM pyrolysis and catalysis. Hydropyrolysis and catalysis reaction families occurring during NBBM hydropyrolysis at 420 C were summarized in the form of reaction matrices which, upon exhaustive application to the components of the reacting system, yielded the mechanistic reaction model. Each reaction family also had an associated linear free energy relationship (LFER) which provided an estimate of the rate constant k{sub i} given a structural property of species i or its reaction. Including the catalytic reaction matrices with those for the pyrolysis model provided a comprehensive NBBM catalytic reaction model and allowed regression of fundamental LFER parameters for the catalytic reaction families. The model also allowed specification of the property of an optimal catalyst. Iron, molybdenum and palladium were predicted to be most effective for model compound consumption. Due to the low costs associated with iron and its disposal, it is a good choice for coal liquefaction catalysis and the challenge remains to synthesize small particles able to access the full surface area of the coal macromolecule.

Panorama 2010: World coal resources

International Nuclear Information System (INIS)

Bessereau, G.; Saniere, A.

2010-01-01

At a time when the international community must face the key challenges posed by global warming as well as sustainability in general and many of our fellow citizens have come to look unfavorably upon fossil energies, the world is still heavily dependent on these energies to cover growing global energy demand. With proved reserves equivalent to more than 120 years at the present rate of extraction, with a better worldwide geographical distribution than petroleum, coal seems like an especially secure energy. While the renewable energies are showing rapid growth but still only represent a small proportion of the world energy mix, coal was the energy whose consumption grew at the fastest rate and for the sixth consecutive year. This gives cause for concern when one realizes that coal is also the most environmentally harmful energy at local level (its extraction generates pollution) and globally (its combustion emits CO 2 ). So how is it possible to reconcile the apparently irreconcilable, especially when, in some countries, coal represents the bulk of the energy resources? Since it is impossible to do without coal, the solution is to develop new 'clean coal' technologies, among which the capture and storage of CO 2 looks like a promising pathway. In the process, it will be necessary to overcome major technical, economic and social challenges. (author)

Nanometre-sized pores in coal: Variations between coal basins and coal origin

Science.gov (United States)

Sakurovs, Richard; Koval, Lukas; Grigore, Mihaela; Sokolava, Anna; Ruppert, Leslie F.; Melnichenko, Yuri B.

2018-01-01

We have used small angle neutron scattering (SANS) to investigate the differences in methane and hexane penetration in pores in bituminous coal samples from the U.S., Canada, South Africa, and China, and maceral concentrates from Australian coals. This work is an extension of previous work that showed consistent differences between the extent of penetration by methane into 10–20 nm size pores in inertinite in bituminous coals from Australia, North America and Poland.In this study we have confirmed that there are differences in the response of inertinite to methane and hexane penetration in coals sourced from different coal basins. Inertinite in Permian Australian coals generally has relatively high numbers of pores in the 2.5–250 nm size range and the pores are highly penetrable by methane and hexane; coals sourced from Western Canada had similar penetrability to these Australian coals. However, the penetrability of methane and hexane into inertinite from the Australian Illawarra Coal Measures (also Permian) is substantially less than that of the other Australian coals; there are about 80% fewer 12 nm pores in Illawarra inertinite compared to the other Australian coals examined. The inertinite in coals sourced from South Africa and China had accessibility intermediate between the Illawarra coals and the other Australian coals.The extent of hexane penetration was 10–20% less than CD4 penetration into the same coal and this difference was most pronounced in the 5–50 nm pore size range. Hexane and methane penetrability into the coals showed similar trends with inertinite content.The observed variations in inertinite porosity between coals from different coal regions and coal basins may explain why previous studies differ in their observations of the relationships between gas sorption behavior, permeability, porosity, and maceral composition. These variations are not simply a demarcation between Northern and Southern Hemisphere coals.

Polymers for combatting sudden outbursts in coal mines

Energy Technology Data Exchange (ETDEWEB)

Gadzhiev, G P; Sukhanov, V V

1988-02-01

Describes investigations in coal mines in the Donetsk basin (hazardous because of the high methane presence, the risk of outbursts of coal and gas, underground fires and the high dust levels) with the aim of studying the toxic emissions of formaldehyde and methanol produced when a urea formaldehyde resin binder is applied to the coal seam. The measurements taken led to the following recommendations: the amount of free formaldehyde in the binder should be limited to 0.5%; the use of concentrated (50%) solutions should be limited to 10 l per ton of coal in areas where there are geologic faults; underground workings need ventilation of at least 200 m/sup 3//min; the binder should be introduced to the borehole separately from the water and hardener; individual protection measures and wet dusting should be used during coal extraction; a period of not less than 4 months should elapse between application of the resin and commencement of coal extraction; there should be at least 80 m between the point where the binder is applied and the coal face.

Cooperative research in coal liquefaction infratechnology and generic technology development: Final report, October 1, 1985 to December 31, 1986

Energy Technology Data Exchange (ETDEWEB)

Sendlein, L.V.A.

1987-06-29

During the first year of its research program, the Consortium for Fossil Fuel Liquefaction Science has made significant progress in many areas of coal liquefaction and coal structure research. Research topics for which substantial progress has been made include integrated coal structure and liquefaction studies, investigation of differential liquefaction processes, development and application of sophisticated techniques for structural analysis, computer analysis of multivariate data, biodesulfurization of coal, catalysis studies, co-processing of coal and crude oil, coal dissolution and extraction processes, coal depolymerization, determination of the liquefaction characteristics of many US coals for use in a liquefaction database, and completion of a retrospective technology assessment for direct coal liquefaction. These and related topics are discussed in considerably more detail in the remainder of this report. Individual projects are processed separately for the data base.

Statistical assessment of coal charge effect on metallurgical coke quality

Directory of Open Access Journals (Sweden)

Pavlína Pustějovská

2016-06-01

Full Text Available The paper studies coke quality. Blast furnace technique has been interested in iron ore charge; meanwhile coke was not studied because, in previous conditions, it seemed to be good enough. Nowadays, requirements for blast furnace coke has risen, especially, requirements for coke reactivity. The level of reactivity parameter is determined primarily by the composition and properties of coal mixtures for coking. The paper deals with a statistical analysis of the tightness and characteristics of the relationship between selected properties of coal mixture and coke reactivity. Software Statgraphic using both simple linear regression and multiple linear regressions was used for the calculations. Obtained regression equations provide a statistically significant prediction of the reactivity of coke, or its strength after reduction of CO2, and, thus, their subsequent management by change in composition and properties of coal mixture. There were determined indexes CSR/CRI for coke. Fifty – four results were acquired in the experimental parts where correlation between index CRI and coal components were studied. For linear regression the determinant was 55.0204%, between parameters CRI – Inertinit 21.5873%. For regression between CRI and coal components it was 31.03%. For multiple linear regression between CRI and 3 feedstock components determinant was 34.0691%. The final correlation has shown the decrease in final coke reactivity for higher ash, higher content of volatile combustible in coal increases the total coke reactivity and higher amount of inertinit in coal increases the reactivity. Generally, coke quality is significantly affected by coal processing, carbonization and maceral content of coal mixture.

Relocation of belt conveyors along the final slope of the Belacevac surface coal mine

Energy Technology Data Exchange (ETDEWEB)

Maksimovic, N; Rosic, Z

1987-07-01

Describes how following a landslide on the northern wing of the Belacevac surface coal mine the belt conveyor lines had to be relocated in order to assure a reliable coal supply to the Kosovo A and Kosovo B thermal power stations. The relocation was achieved in three phases with new approach cuts being made, necessitating the removal of 280,000 m/sup 3/ of overburden in the first phase and 870,000 m/sup 3/ in the second phase of the reconstruction. Illustrates the relocation of the conveyor system by means of site plans and notes that the production of coal and the removal of overburden were not interrupted during the relocation exercise. 2 refs.

Low-rank coal research. Final technical report, April 1, 1988--June 30, 1989, including quarterly report, April--June 1989

Energy Technology Data Exchange (ETDEWEB)

1989-12-31

This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

Cleaner Coal in China [Chinese Version

Energy Technology Data Exchange (ETDEWEB)

NONE

2009-07-01

China’s rapid economic growth has aroused intense interest around the world. Policy makers, industrialists, investors, environmentalists, researchers and others want to better understand the issues that this populous nation faces as it further develops an already thriving economy largely fuelled by coal. This study sheds light on the Chinese coal supply and transformation sectors. China’s rapid economic growth has aroused intense interest around the world. Policy makers, industrialists, investors, environmentalists, researchers and others want to better understand the issues that this populous nation faces as it further develops an already thriving economy largely fuelled by coal. This study sheds light on the Chinese coal supply and transformation sectors. China’s coal, mined locally and available at a relatively low cost, has brought enormous benefits to energy consumers in China and to those outside the country who enjoy the products of its coal-based economy. Yet from another perspective, China’s coal use has a high cost. Despite progress, health and safety in the thousands of small coal mines lag far behind the standards achieved in China’s modern, large mines. Environmental degradation is a real and pressing problem at all stages of coal production, supply and use. Adding to these burdens, emissions of carbon dioxide are of concern to the Chinese government as it embarks on its own climate protection strategy. Technology solutions are already transforming the way coal is used in China and elsewhere. This study explores the context in which the development and deployment of these technologies can be accelerated. Providing a large amount of new data, it describes in detail the situation in China as well as the experiences of other countries in making coal cleaner. Above all, the report calls for much greater levels of collaboration – existing bi-lateral and multi-lateral co-operation with China on coal is found lacking. China’s growing openness

Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment. Final technical report

Energy Technology Data Exchange (ETDEWEB)

Baldwin, R.M.; Miller, R.L.

1991-12-01

The findings in the first phase were as follows: 1. Both reductive (non-selective) alkylation and selective oxygen alkylation brought about an increase in liquefaction reactivity for both coals. 2. Selective oxygen alkylation is more effective in enhancing the reactivity of low rank coals. In the second phase of studies, the major findings were as follows: 1. Liquefaction reactivity increases with increasing level of alkylation for both hydroliquefaction and co-processing reaction conditions. 2. the increase in reactivity found for O-alkylated Wyodak subbituminous coal is caused by chemical changes at phenolic and carboxylic functional sites. 3. O-methylation of Wyodak subbituminous coal reduced the apparent activation energy for liquefaction of this coal.

Oil from coal: just not worth it, say NCB

Energy Technology Data Exchange (ETDEWEB)

Grainger, L

1970-01-01

The creation of new markets by making oil fuels from coal in Britain is unresolved at this time. The dominant factor in the economics is the price ratio between coal and oil, which in Britain is 3 times less favorable than in the U.S. Current conversion results in a price more than double that of natural oil; however, the National Coal Board (NCB) continues to assess oil-from-coal processes. A sound research background in the new field of coal derivatives from solvent processing is being developed to produce materials of higher specific value than fuels. A continuous pilot plant is being built to prepare coke from filtered coal solution on the scale of a half-a-ton per week. Future prospects of the industry lie in areas where markets for coal will diminish, such as metallurgical coke. The fate of the coal industry will depend more and more on its largest market-electricity generation. In order to compete with nuclear power, the NCB is developing a new system of fluidized combustion.

A guide to coal chute replacement

Energy Technology Data Exchange (ETDEWEB)

O' Neil, M. [Parramatta Group (United States)

2006-11-15

Good material flow can reduce coal yard maintenance and operational problems. A thorough inspection of the conveyor system can reveal some of the obvious signs of underperforming material transfer points in a power generation facility. The author gives 10 reasons why plant owners may need to look at an engineered transfer solution to improve flow, particularly of Powder River Basin coal. Items are ordered starting from auditing the inside of the chute walls, moving to liners, then to general buildup and outside spillage. 3 photos.

Application of coals as sorbents for the removal of Cr from aqueous waste streams

Energy Technology Data Exchange (ETDEWEB)

Lakatos, J.; Brown, S.D.; Snape, C.E. [University of Miskolc, Miskolc (Hungary). Dept. of Analytical Chemistry

2001-09-01

The study reported further understanding of how various electron transfer processes operate for Cr(VI) with a view to using coals for the removal of Cr(VI) from waste streams. Skye peat, Spanish and German lignites, UK high and low volatility bituminous coals and an activated carbon were used. After treatment to remove exchangeable cations, ion exchange experiments were conducted in 0.1 M acetic acid-sodium acetate (1:1) buffer and 0.05 M sulphuric acid solutions and the slurries were agitated once a day. The ion concentrations in the solutions were determined by flame atomic absorption spectroscopy. The Cr(VI) renaming in solution was determined by the standard calorimetric 1,5-diphenylcarbazide method. Peat and low rank (Spanish Mequinenza) coal exhibited a larger capacity for Cr(VI) removal than bituminous coal. Redox mechanisms are operative coupled with the oxidation of the coal and peat surfaces. Desorption of Cr(III) formed by reduction which occurs in strongly acidic media also needs to be considered. 1 ref., 3 figs.

Training of Engineering Personnel for the Innovative Coal Industry: Problems and Ways of Solution

Science.gov (United States)

Zaruba, Natalya; Fraltsova, Tamara; Snegireva, Tatyana

2017-11-01

The article is written based on some results of the long-term scientific research of the problem related to the urgent need to find the ways of training personnel for the innovative coal industry in the higher education system. This is due to the fundamental changes in the Russian social and economic conditions: the change in the social system and the owner of the coal industry, the emergence of new technologies in the field of coal mining and processing, and in the management of these processes. At the same time, the system of training specialists for the coal industry in the higher education institutions has largely remained unchanged: technologies and principles of training, scientific approaches and concepts take little account of the changed situation, traditional views of specialists work-ing in the university continue to dominate innovative ideas. Many innovations, especially related to technology and the principles of education, struggle to make their way into the higher education system. The article substantiates the urgency of the problem of training personnel for the innovative coal industry in the higher education system, as well as the importance of scientific analysis of the problem in order to find the ways to solve it.

Coal as an abundant source of graphene quantum dots

Science.gov (United States)

Ye, Ruquan; Xiang, Changsheng; Lin, Jian; Peng, Zhiwei; Huang, Kewei; Yan, Zheng; Cook, Nathan P.; Samuel, Errol L. G.; Hwang, Chih-Chau; Ruan, Gedeng; Ceriotti, Gabriel; Raji, Abdul-Rahman O.; Martí, Angel A.; Tour, James M.

2013-12-01

Coal is the most abundant and readily combustible energy resource being used worldwide. However, its structural characteristic creates a perception that coal is only useful for producing energy via burning. Here we report a facile approach to synthesize tunable graphene quantum dots from various types of coal, and establish that the unique coal structure has an advantage over pure sp2-carbon allotropes for producing quantum dots. The crystalline carbon within the coal structure is easier to oxidatively displace than when pure sp2-carbon structures are used, resulting in nanometre-sized graphene quantum dots with amorphous carbon addends on the edges. The synthesized graphene quantum dots, produced in up to 20% isolated yield from coal, are soluble and fluorescent in aqueous solution, providing promise for applications in areas such as bioimaging, biomedicine, photovoltaics and optoelectronics, in addition to being inexpensive additives for structural composites.

Release of polyaromatic hydrocarbons from coal tar contaminated soils

International Nuclear Information System (INIS)

Priddy, N.D.; Lee, L.S.

1996-01-01

A variety of process wastes generated from manufactured gas production (MGP) have contaminated soils and groundwater at production and disposal sites. Coal tar, consisting of a complex mixture of hydrocarbons present as a nonaqueous phase liquid, makes up a large portion of MGP wastes. Of the compounds in coal tar, polyaromatic hydrocarbons (PAHs) are the major constituents of environmental concern due to their potential mutagenic and carcinogenic hazards. Characterization of the release of PAHs from the waste-soil matrix is essential to quantifying long-term environmental impacts in soils and groundwater. Currently, conservative estimates for the release of PAHs to the groundwater are made assuming equilibrium conditions and using relationships derived from artificially contaminated soils. Preliminary work suggests that aged coal tar contaminated soils have much lower rates of desorption and a greater affinity for retaining organic contaminants. To obtain better estimates of desorption rates, the release of PAHs from a coal tar soil was investigated using a flow-interruption, miscible displacement technique. Methanol/water solutions were employed to enhance PAH concentrations above limits of detection. For each methanol/water solution employed, a series of flow interrupts of varying times was invoked. Release rates from each methanol/water solution were estimated from the increase in concentration with duration of flow interruption. Aqueous-phase release rates were then estimated by extrapolation using a log-linear cosolvency model

Dynamic Game Analysis of Coal Electricity Market Involving Multi-Interests

Directory of Open Access Journals (Sweden)

Yu Xiaobao

2016-01-01

Full Text Available The coal consumption of China reached 2.75 billion tons of standard coal in 2013, which accounted for 67.5% of total energy consumption and more than 50% of global coal consumption. Therefore, the impact of coal price is huge on coal market and even energy market in China. As a large consumer of coal, thermal power enterprise has a strong sensitivity to coal price. In order to balance the rising cost of enterprises due to coal price, we need to analyze the interests of multiple stakeholders. Firstly, this paper combined the Nash equilibrium and cobweb model and proposed the characteristics in different cobweb model. Then, for coal, power, and energy companies, the dynamic game analysis model is constructed. This model gives a game analysis in four scenarios and quantifies the decision of each stakeholder in different coal prices. Finally, the impact figure of different coal prices on each stakeholder has been drawn. The impacts of different coal or thermal power prices on different markets have been put forward, so relevant policy recommendations have been proposed combined with the cobweb model.

Analytical Model of Water Flow in Coal with Active Matrix

Science.gov (United States)

Siemek, Jakub; Stopa, Jerzy

2014-12-01

This paper presents new analytical model of gas-water flow in coal seams in one dimension with emphasis on interactions between water flowing in cleats and coal matrix. Coal as a flowing system, can be viewed as a solid organic material consisting of two flow subsystems: a microporous matrix and a system of interconnected macropores and fractures. Most of gas is accumulated in the microporous matrix, where the primary flow mechanism is diffusion. Fractures and cleats existing in coal play an important role as a transportation system for macro scale flow of water and gas governed by Darcy's law. The coal matrix can imbibe water under capillary forces leading to exchange of mass between fractures and coal matrix. In this paper new partial differential equation for water saturation in fractures has been formulated, respecting mass exchange between coal matrix and fractures. Exact analytical solution has been obtained using the method of characteristics. The final solution has very simple form that may be useful for practical engineering calculations. It was observed that the rate of exchange of mass between the fractures and the coal matrix is governed by an expression which is analogous to the Newton cooling law known from theory of heat exchange, but in present case the mass transfer coefficient depends not only on coal and fluid properties but also on time and position. The constant term of mass transfer coefficient depends on relation between micro porosity and macro porosity of coal, capillary forces, and microporous structure of coal matrix. This term can be expressed theoretically or obtained experimentally. W artykule zaprezentowano nowy model matematyczny przepływu wody i gazu w jednowymiarowej warstwie węglowej z uwzględnieniem wymiany masy między systemem szczelin i matrycą węglową. Węgiel jako system przepływowy traktowany jest jako układ o podwójnej porowatości i przepuszczalności, składający się z mikroporowatej matrycy węglowej oraz z

An determination of man-made γ-emitting radionuclides in coal fly ash and standard solution

International Nuclear Information System (INIS)

Xu Cuihua; Zhou Qiang

2004-01-01

We participated an international comparison on the determination of man-made γ-emitting radionuclides in coal fly ash and in standard solution organized by the Analytical Quality Control Service of the IAEA in 2002. The sample was dispensed in 100.0 ± 0.1 g aliquots in plastic container and was spiked with known amounts of certified standard γ-emitting radionuclides 54 Mn, 57 Co, 60 Co, 65 Zn, 88 Y, 134 Cs, 137 Cs and 241 Am. The determination of the anthropogenic )γ-emitting radionuclides in the test samples was carried out with an ORTEC gamma-ray spectrometry system coupled with a HPGe detector with resolution of 1.75 keV and relative efficiency of 55% for 137 Cs, located in a 10 cm thick lead container. The energy and efficiency calibration were with home-made volume calibration sources containing some of the radionuclides to be analyzed. The analysis procedure is described elsewhere. Table 1 lists the results of the determination and the comparisons with IAEA reference data and evaluation. Overall our results are agreeable in ±8.6% with the IAEA reference data, except for 60 Co. The differences for 60 Co was -10.8%. It may be caused by the 60 Co calibration source made with residual of quiet old standard solution. The difference for 241 Am is due to self-absorption in the fly ash sample. This bias was small for the solution sample. For standard solution sample, the results are agreeable within ±3.7% for all radionuclides except for 60 Co, being 12%. (authors)

The Philippine coal industry its challenges and opportunities

International Nuclear Information System (INIS)

Aragon, Francisco B.

1997-01-01

The demand for energy has been increasing over the years especially with the country's accelerated economic growth as we move closer its vision of industrialization by the turn of the century. Pursuant to this, the Department of Energy (DOE) was mandated to ensure the country's energy supply availability at affordable costs with due consideration to environmental concerns. Likewise, our organization, the Philippine Chamber of Coal Mines, Inc. (PHILCOAL), an association of local coal producers has taken the role of continuing its task of promoting the development and growth of the coal industry and to cooperate with the governmental agencies in their program of accelerating the development; growth and stability of the energy's coal sector. This paper will present a brief overview of the current situation of the coal industry, citing among others the country's coal reserves, quality, the industry's performance and the coal supply and demand projected for a five-year period. This paper shall also briefly discuss the government's plan to intensify coal exploration efforts so as to ensure the expansion of the country's production capabilities, the establishment of more terminals and infrastructures and accelerate the implementation of mine-mouth power generation and co-regeneration projects in potential coal areas. The implementation of the government's plan for the coal sector will require substantial capital and this paper will cite the principal areas where local and foreign project can come in. Finally this paper conclusively state that the country will remain a net importer of coal on account of the inability of local coal producers to meet increasing rate and coal demand. (author)

Definition of the form of coal spontaneous combustion source as the inverse problem of geoelectrics

Directory of Open Access Journals (Sweden)

Sirota Dmitry

2017-01-01

Full Text Available The paper reviews the method of determining the shape and size of the coal self-heating source on coal pit benches and in coal piles during mining of coal by the open method. The method is based on the regularity found in the 1970s of the previous century and related to the distribution of potential of the natural electrical field arising from the temperature in the vicinity of the center of self-heating. The problem is reduced to the solution of inverse ill-posed problem of mathematical physics. The study presents the developed algorithm of its solution and the results of numerical simulation.

New approach for coal analysis

Energy Technology Data Exchange (ETDEWEB)

1985-05-01

The paper describes current progress of coal analysis and the existing problems. It focuses on the current major tasks of coal analysis, namely, to achieve three goals and to finish five tasks. Specific measures are mentioned, strengthening leadership and improvement of management, correct handling of three relations, i.e. relations between local and overall interests, between quantity and quality, and between rewards and punishments. The weak links should be improved i.e. the organization, the quality of the staff and the testing facilities should be improved. Finally, the paper says that improvement must be dependent on the progress of science and technology.

Rapid pyrolysis of Serbian soft brown coals

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Jankes Goran

2009-01-01

Full Text Available Soft brown coals of the open coal fields of Kolubara and Kostolac are the main domestic energy sources of Serbia. This paper presents the results of investigations on rapid devolatilization of these two coals which have covered kinetics of devolatilization (based on total volatile yield, forms of sulphur and petrographic analysis of coal and char. Experiments of devolatilization were performed in inert gas (N2 at atmospheric pressure and in batch-type hot-wire screen reactor. The mass-loss values of both coals at selected final reaction temperatures (300-900°C and retention times (3-28 s were obtained. Anthony and Howard's kinetic model was applied over two temperature ranges (300-500 and 700-900°C. The types of sulphur as monosulphide, sulphate, pyritic, and organic sulphur were determined for chars and original coals. Strong transformation of pyrite was evident even at low temperatures (300°C. Devolatilization of all types of sulphur has started over 600 and at 900°C the content of sulphur in char remained only 66% of total sulphur in original coal. Microscopic investigations were carried out on samples prepared for reflected light measurements. The petrographic analysis included: the ratio of unchanged and changed coal, maceral types, the share of cenosferes, isotropic mixed carbonized grains, mixed grains, small fragments, clay, and pyrite. The change of the structure of devolatilized coal was also observed.

Biological removal of sulfur from coal flotation concentrate by culture isolated from coal washery plant tailing dump

Energy Technology Data Exchange (ETDEWEB)

Jorjani, E. [Azad University, Tehran (Iran). Mining Engineering Dept.

2005-10-15

A combination of flotation and microbial leaching processes was used to achieve acceptable level of sulfur and ash in Tabas coal sample of Iran. Representative sample of the minus 500 micron size fraction was subjected to flotation separation for the removal of ash and sulfur. The final concentrate with recovery, combustion value and sulfur content of 86.03, 86.45 and 1.35% respectively was achieved at pH 8 and following reagent dosage and operating conditions: collector: diesel oil (1200 g/ton), frother: MIBC (5%) + pine oil (95%) with concentration of 120 (g/ton), depressant: sodium silicate (1000 g/ton), particle size: {lt} 500 {mu} m and pulp density: 7%. Because of fine distribution of sulfur on Tabas coal macerals and lithotypes, high percentage of total sulfur (79.9%) is distributed in flotation concentrate and only 20.1% is yielded in the tails. So microbial leaching using a species isolated from coal washery plant tailing dump was used in batch system to remove sulfur from flotation concentrate. The conditions were optimized for the maximum removal of sulfur. These conditions were found to be pH of 2, particle size less than 0.18 mm; pulp density: 8%, temperature: 30 {sup o}C, shaking rate: 150 rpm conditions. Total sulfur and ash content was reduced by bioleaching from 13.55 and 1.35 in flotation concentrate to 9.47 and 0.55 in the final leached concentrate, a reduction of 35 and 61.9% respectively. Sterilization of coal adversely affects the sulfur reduction. The results suggest that the isolated culture is sufficiently effective for depyritization of Tabas coal flotation concentrate in stirred system.

A new approach to group separation of coals

Energy Technology Data Exchange (ETDEWEB)

Zhi-Hong Qin; Zhi-Min Zong; Chun Jiang; Hao Sun; Li-Li Zhou; Xian-Yong Wei [China University of Mining and University, Jiangsu (China). School of Chemical Engineering

2005-07-01

Three coal samples were extracted with carbon disulfide/N-methyl-2-pyrrolidinone (CS{sub 2}/NMP) mixed solvent. The extraction solutions were separated to three layers: insoluble fraction (under layer), CS{sub 2} solution (middle layer) and water/NMP solution (upper layer) by water addition. Most of NMP was concentrated to the upper layer. 7 refs., 3 figs., 3 tabs.

Prospects for the development of coal-steam plants in Russia

Science.gov (United States)

Tumanovskii, A. G.

2017-06-01

Evaluation of the technical state of the modern coal-fired power plants and quality of coal consumed by Russian thermal power plants (TPP) is provided. Measures aimed at improving the economic and environmental performance of operating 150-800 MW coal power units are considered. Ways of efficient use of technical methods of NO x control and electrostatic precipitators' upgrade for improving the efficiency of ash trapping are summarized. Examples of turbine and boiler equipment efficiency upgrading through its deep modernization are presented. The necessity of the development and introduction of new technologies in the coal-fired power industry is shown. Basic technical requirements for a 660-800 MW power unit with the steam conditions of 28 MPa, 600/600°C are listed. Design solutions taking into account features of Russian coal combustion are considered. A field of application of circulating fluidized bed (CFB) boilers and their effectiveness are indicated. The results of development of a new generation coal-fired TPP, including a steam turbine with an increased efficiency of the compartments and disengaging clutch, an elevated steam conditions boiler, and a highly efficient NO x /SO2 and ash particles emission control system are provided. In this case, the resulting ash and slag are not to be sent to the ash dumps and are to be used to a maximum advantage. Technical solutions to improve the efficiency of coal gasification combined cycle plants (CCP) are considered. A trial plant based on a 16 MW gas turbine plant (GTP) and an air-blown gasifier is designed as a prototype of a high-power CCP. The necessity of a state-supported technical reequipment and development program of operating coal-fired power units, as well as putting into production of new generation coal-fired power plants, is noted.

Biological action of coal dust formed during excavation of seams after physicochemical treatment

Energy Technology Data Exchange (ETDEWEB)

Sukhanov, V V; Gadzhiev, G P

1982-03-01

Destruction of the self-cleansing function of lungs by dust is important in the development of pneumoconiosis. It is expedient to study the influence of chemical substances, injected into coal seams to prevent methane bursts and reduce dust formation, on the physiologic mechanisms for the protection of the lungs from dust (macrophageal reaction of lungs, function of mucociliary transport). An investigation using 15, 24 and 50% solutions of binder KM/SUB/2 modified by polyvinyl alcohol, and 3% hydrochloric acid solution was conducted on 200 white rats. Reaction of rats treated with solutions of binder in different concentrations proved that accumulation of dust in lungs and lymph nodes was directly related to the strength of the solution. Three percent hydrochloric acid solution diminished dust accumulation in paratracheal lymph nodes and content of lipids and collagen in the lungs. Inhalation of dust treated with a 50% solution of binder KM/SUB/2 increases the deposit of dust in the lungs and increases fiber production. Therefore, solutions of more than 24% binder should not be used to treat coal. Solutions of 15% and 24% do not significantly affect the process of dust accumulation in the lungs. A 3% solution of hydrochloric acid reduces the dust-forming capacity of the coal mass. (13 refs.) (In Russian)

Chemical and Pyrolytic Thermogravimetric Characterization of Nigerian Bituminous Coals

Directory of Open Access Journals (Sweden)

Nyakuma Bemgba Bevan

2016-12-01

Full Text Available The discovery of new coal deposits in Nigeria presents solutions for nation’s energy crises and prospects for socioeconomic growth and sustainable development. Furthermore, the quest for sustainable energy to limit global warming, climate change, and environmental degradation has necessitated the exploration of alternatives using cleaner technologies such as coal pyrolysis. However, a lack of comprehensive data on physico-chemical and thermal properties of Nigerian coals has greatly limited their utilization. Therefore, the physico-chemical properties, rank (classification, and thermal decomposition profiles of two Nigerian bituminous coals – Afuze (AFZ and Shankodi-Jangwa (SKJ – were examined in this study. The results indicate that the coals contain high proportions of C, H, N, S, O and a sufficiently high heating value (HHV for energy conversion. The coal classification revealed that the Afuze (AFZ coal possesses a higher rank, maturity, and coal properties compared to the Shankodi-Jangwa (SKJ coal. A thermal analysis demonstrated that coal pyrolysis in both cases occurred in three stages; drying (30-200 °C, devolatilization (200-600 °C, and char decomposition (600-1000 °C. The results also indicated that pyrolysis at 1000 °C is not sufficient for complete pyrolysis. In general, the thermochemical and pyrolytic fuel properties indicate that the coal from both places can potentially be utilized for future clean energy applications.

Coal geopolitics

International Nuclear Information System (INIS)

Giraud, P.N.; Suissa, A.; Coiffard, J.; Cretin, D.

1991-01-01

This book divided into seven chapters, describes coal economic cycle. Chapter one: coals definition; the principle characteristics and properties (origin, calorific power, international classification...) Chapter two: the international coal cycle: coal mining, exploration, coal reserves estimation, coal handling coal industry and environmental impacts. Chapter three: the world coal reserves. Chapter four: the consumptions, productions and trade. Chapter five: the international coal market (exporting mining companies; importing companies; distributors and spot market operators) chapter six: the international coal trade chapter seven: the coal price formation. 234 refs.; 94 figs. and tabs [fr

Fundamental studies of coal liquefaction

Energy Technology Data Exchange (ETDEWEB)

1995-01-01

The authors have examined the pyrolysis of Argonne samples of Wyodak and Illinois No. 6 coal in argon, undecane, Tetralin, and water. The effects of the pyrolysis on individual particles of coal were monitored visually in a cell with diamond windows capable of operation to temperature and pressures in excess of 500{degrees}C and 3000 psi. The changes in the particles from ambient to 460{degrees}C were recorded in real time on video tape, and images were then taken from the tape record and analyzed. The study showed that in argon both coals developed tars at 350{degrees}-370{degrees}C. The tars then quickly evaporated, leaving core particles remarkably similar in size and shape to the initial particles. These observations suggest that coal does not melt nor become fully liquid when heated. Nor does the softened coal undergo crosslinking to generate coke. Rather the simple loss of volatiles leaves behind the core residue as coke. Contrary to the common view, there appears to be no link between the bond-breaking processes yielding tar and the interaction of the coal with H-donors leading to liquefaction. Water as a medium was surprising in its effect. Both coals began to shrink at 300{degrees}-350{degrees}C, with the effect appearing to be more of an erosion rather than a uniform loss of substance as seen in Tetralin. The Wyodak continued to shrink to 460{degrees}C to about half its initial size. With the Illinois No. 6 coal, however, the process reversed at around 420{degrees}C, and the particles appeared to grow with the evolution of a tar, continuing to 460{degrees}C. The authors submit that this final observation is evidence for hydrothermal synthesis of hydrocarbons at these conditions.

Impacts of Natural Surfactant Soybean Phospholipid on Wettability of High-rank Coal Reservoir

Science.gov (United States)

Lyu, S.; Xiao, Y.; Yuan, M.; Wang, S.

2017-12-01

It is significant to change the surface wettability of coal rock with the surfactant in coal mining and coalbed methane exploitation. Soybean phospholipid (SP) is a kind of natural zwitterionic surfactant which is non-toxic and degradable. In order to study the effects of soybean phospholipid on wettability of high-rank coal in Qinshui Basin, some experiments including surface tension test, contact angle measurement on the coal surface, coal fines imbibition, observation of dispersion effect and gas permeability test were carried out, and water locking mechanism of fracturing fluid in micro fractures of coal reservoir was analyzed. The results show that the surface of high-rank coal was negatively charged in solution and of weak hydrophilicity. The soybean phospholipid with the mass fraction of 0.1% reduced the surface tension of water by 69%, and increased the wettability of coal. Meanwhile, the soybean phospholipid helped coal fines to disperse by observation of the filter cake with the scanning electron microscope. The rising rate of soybean phospholipid solution in the pipe filled with coal fines was lower than that of anionic and cationic surfactant, higher than that of clean water and non-ionic surfactant. Composite surfactant made up of soybean phospholipid and OP-10 at the ratio of 1:3 having a low surface tension and large contact angle, reduced the capillary force effectively, which could be conducive to discharge of fracturing fluid from coal reservoir micro fracture and improve the migration channels of gas. Therefore it has a broad application prospect.

Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

Energy Technology Data Exchange (ETDEWEB)

Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

1995-04-01

Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

Life assessment and emissions monitoring of Indian coal-fired power plants. Final report

Energy Technology Data Exchange (ETDEWEB)

1992-07-01

At the request of the Pittsburgh Energy Technology Center (PETC) of the United States Department of Energy (USDOE), the traveler, along with Dr. R. P. Krishnan, Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee spent three weeks in India planning and performing emissions monitoring at the coal-fired Vijayawada Thermal Power Station (VTPS). The coordination for the Indian participants was provided by BHEL, Trichy and CPRI, Bangalore. The trip was sponsored by the PETC under the United States Agency for International Development (USAID)/Government of India (GOI)P Alternate Energy Resources Development (AERD) Project. The AERD Project is managed by PETC, and ORNL is providing the technical coordination and support for four coal projects that are being implemented with BHEL, Trichy. The traveler, after briefing the USAID mission in New Delhi visited BHEL, Trichy and CPRI, Bangalore to coordinate and plan the emissions test program. The site selection was made by BHEL, CPRI, TVA, and PETC. Monitoring was performed for 4 days on one of the 4 existing 210 MW coal-fired boilers at the VTPS, 400 km north of Madras, India.

Kinetics of coal pyrolysis

Energy Technology Data Exchange (ETDEWEB)

Seery, D.J.; Freihaut, J.D.; Proscia, W.M. (United Technologies Research Center, East Hartford, CT (USA)); Howard, J.B.; Peters, W.; Hsu, J.; Hajaligol, M.; Sarofim, A. (Massachusetts Inst. of Tech., Cambridge, MA (USA)); Jenkins, R.; Mallin, J.; Espindola-Merin, B. (Pennsylvania State Univ., University Park, PA (USA)); Essenhigh, R.; Misra, M.K. (Ohio State Univ., Columbus, OH (USA))

1989-07-01

This report contains results of a coordinated, multi-laboratory investigation of coal devolatilization. Data is reported pertaining to the devolatilization for bituminous coals over three orders of magnitude in apparent heating rate (100 to 100,000 + {degree}C/sec), over two orders of magnitude in particle size (20 to 700 microns), final particle temperatures from 400 to 1600{degree}C, heat transfer modes ranging from convection to radiative, ambient pressure ranging from near vacuum to one atmosphere pressure. The heat transfer characteristics of the reactors are reported in detail. It is assumed the experimental results are to form the basis of a devolatilization data base. Empirical rate expressions are developed for each phase of devolatilization which, when coupled to an awareness of the heat transfer rate potential of a particular devolatilization reactor, indicate the kinetics emphasized by a particular system reactor plus coal sample. The analysis indicates the particular phase of devolatilization that will be emphasized by a particular reactor type and, thereby, the kinetic expressions appropriate to that devolatilization system. Engineering rate expressions are developed from the empirical rate expressions in the context of a fundamental understanding of coal devolatilization developed in the course of the investigation. 164 refs., 223 figs., 44 tabs.

Test and evaluate the tri-gas low-Btu coal-gasification process. Final report, October 21, 1977-October 31, 1980

Energy Technology Data Exchange (ETDEWEB)

Zabetakis, M.G.

1980-12-01

This report describes the continuation of work done to develop the BCR TRI-GAS multiple fluidized-bed gasification process. The objective is the gasification of all ranks of coals with the only product being a clean, low-Btu fuel gas. Design and construction of a 100 lb/h process and equipment development unit (PEDU) was completed on the previous contract. The process consists of three fluid-bed reactors in series, each having a specific function: Stage 1 - pretreatment; Stage 2- - gasification; Stage 3 - maximization of carbon utilization. Under the present contract, 59 PEDU tests have been conducted. A number of these were single-stage tests, mostly in Stage 1; however, integrated PEDU tests were conducted with a western coal (Rosebud) and two eastern coals (Illinois No. 6 and Pittsburgh seam). Both Rosebud and Pittsburgh seam coals were gasified with the PEDU operating in the design mode. Operation with Illinois No. 6 seam coal was also very promising; however, time limitations precluded further testing with this coal. One of the crucial tasks was to operate the Stage 1 reactor to pretreat and devolatilize caking coals. By adding a small amount of air to the fluidizing gas, the caking properties of the coal can be eliminated. However, it was also desirable to release a high percentage of the volatile matter from the coal in this vessel. To accomplish this, the reactor had to be operated above the agglomerating temperature of caking coals. By maintaining a low ratio of fresh to treated coal, this objective was achieved. Both Illinois No. 6 and Pittsburgh seam coals were treated at temperatures of 800 to 900 F without agglomerating in the vessel.

Possibilities of using pulverized non coking coals in ironmaking

Energy Technology Data Exchange (ETDEWEB)

Wijk, Olle; Mathiesen, Mihkel; Eketorp, Sven

1977-08-01

The use of pulverized coal in iron making suggests solutions to the mounting problems created by the increasing scarcity of coking coals, and other fossil fuels such as oil and natural gas. The unavailability of coke can be met with two principally different measures. Blast furnace coke rates can be decreased by substituting injected pulverized coal or other carbon containing fuels for part of the coke burden, and the coke itself may be substituted by formed coke. A more radical solution is to abandon the blast furnace process, and instead produce the raw iron in processes not requiring coke. Two such processes are discussed in the paper, the Inred process, developed by Boliden Kemi AB, Sweden, and the smelting reduction process by means of injection, currently being developed at the Royal Institute of Technology in Stockholm. Both processes have potential advantages over the coke oven/sintering plant/blast furnace-complex especially concerning energy requirements and structure, but also in economical terms. The injection process seems to present a further advantage in the possibility of gasifying coal in the process, thus yielding a synthesis gas for methanol production in addition to the raw iron.

Performance of a diesel engine operating on raw coal-diesel fuel and solvent refined coal-diesel fuel slurries. Final report

Energy Technology Data Exchange (ETDEWEB)

Marshall, H.P.

1980-03-01

Performance tests using an 11 kW single cylinder diesel engine were made to determine the effects of three different micronized coal-fuel oil slurries being considered as alternative fuels. Slurries containing 20, 32, and 40%-wt micronized raw coal in No. 2 fuel oil were used. Results are presented indicating the changes in the concentrations of SO/sub X/ and NO/sub X/ in the exhaust, exhaust opacity, power and efficiency, and in wear rates relative to operation on fuel oil No. 2. The engine was operated for 10 h at full load and 1400 rpm on al fuels except the 40%-wt slurry. This test was discontinued because of extremely poor performance.

Heating plant overcomes coal crisis

International Nuclear Information System (INIS)

Sobinkovic, B.

2006-01-01

At the last moment Kosice managed to overcome the threat of a more than 30-percent heating price increase. The biggest local heat producer, Teplaren Kosice, is running out of coal supplies. The only alternative would be gas, which is far more expensive. The reason for this situation was a dispute of the heating plant with one of its suppliers, Kimex. Some days ago, the dispute was settled and the heating plant is now expecting the first wagon loads of coal to arrive. These are eagerly awaited, as its supplies will not last for more than a month. It all started with a public tender for a coal supplier. Teplaren Kosice (TEKO) announced the tender for the delivery of 120,000 tons of coal in June. Kimex, one of the traditional and biggest suppliers, was disqualified in the course of the tender. The winners of the tender were Slovenergo, Bratislava and S-Plus Trade, Vranov nad Toplou. TEKO signed contracts with them but a district court in Kosice prohibited the company from purchasing coal from these contractors. Kimex filed a complaint claiming that it was disqualified unlawfully. Based on this the court issued a preliminary ruling prohibiting the purchase of coal from the winners of the tender. The heating plant had to wait for the final verdict. The problem was then solved by the company's new Board of Directors, who were appointed in mid October who managed to sign new contracts with the two winners and Kimex. The new contracts cover the purchase of 150-thousand tons of coal, which is 30,000 more than in the original tender specification. Each company will supply one third. (authors)

Coal and gas competition in global markets

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-07-01

Global consumption of commercial energy totalled 18 Gt of coal equivalent in 2010. With a 28% share, coal ranked second after oil as one of the major sources of primary energy and natural gas (at 21%) ranked third. Gross power generation with coal was approximately 41% and gas 22%. Natural gas as a global commodity is growing rapidly with the advent of unconventional sources such as shale gas. Recently, gas has become the fuel of choice for new power generating plants in some countries. Overall production of coal has increased in the same time-frame. The share of coal in electricity production was constant in Europe from early 2000 but recently increased. This was due to the high cost of gas in Europe and a low emissions penalty levied by the regulator, making coal currently more competitive in Europe compared to gas. Coal utilisation continues to increase in Asia but is facing serious competition with gas in the USA, where the share of electricity generated with coal dropped in 2012. However, natural gas used to generate electricity in early 2013 was below the high level seen during the comparable 2012 period, when low natural gas prices led to significant displacement of coal by natural gas for power generation. The current consensus in the USA is that while coal may recover ground in the short term, it loses in the long term as coal plants are retired. The discovery, production and availability of significant amounts of gas have implications for not only the price of natural gas but also the price of coal as well as supply and demand, and utilisation of both fuels internationally. The interaction between coal and gas in the global markets today is investigated in this review and the near-term outlook and impact on both fuels is presented. In this report, reserves, production and trade, supply and demand, pricing, utilisation and consumption, public attitudes and finally near/short to medium-term prospects are discussed for both coal and gas.

Transformations of inorganic coal constituents in combustion systems. Volume 1, sections 1--5: Final report

Energy Technology Data Exchange (ETDEWEB)

Helble, J.J. [ed.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. [PSI Technology Co., Andover, MA (United States); Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. [Arizona Univ., Tucson, AZ (United States); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. [Kentucky Univ., Lexington, KY (United States)

1992-11-01

The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon the size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles? What determines their composition? Whether or not particles deposit? How combustion conditions, including reactor size, affect these processes? remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.

Potential health and environmental impacts attributable to the nuclear and coal fuel cycles: Final report

International Nuclear Information System (INIS)

Gotchy, R.L.

1987-06-01

Estimates of mortality and morbidity are presented based on present-day knowledge of health effects resulting from current component designs and operations of the nuclear and coal fuel cycles, and anticipated emission rates and occupational exposure for the various fuel cycle facilities expected to go into operation during the next decade. The author concluded that, although there are large uncertainties in the estimates of potential health effects, the coal fuel cycle alternative has a greater health impact on man than the uranium fuel fycle. However, the increased risk of health effects for either fuel cycle represents a very small incremental risk to the average individual in the public for the balance of this century. The potential for large impacts exists in both fuel cycles, but the potential impacts associated with a runaway Greenhouse Effect from combustion of fossil fuels, such as coal, cannot yet be reasonably quantified. Some of the potential environmental impacts of the coal fuel cycle cannot currently be realistically estimated, but those that can appear greater than those from the nuclear fuel cycle. 103 refs., 1 fig., 18 tabs

Occurrence of trace elements in respirable coal dust

International Nuclear Information System (INIS)

Sahoo, B.N.

1991-01-01

Inhalation of fine particles of coal dust contributes significantly to the occurrence of the disease, pneumoconiosis, prevailing in coal mining community. It is not presently known whether only the coal dust or specific chemical compounds or synergistic effects of several compounds associated with respirable coal dust is responsible for the disease, pneumoconiosis. The present paper describes the quantitative determination of ten minor and trace elements in respirable coal dust particles by atomic absorption spectrophotometric methods. The respirable coal dust samples are collected at the mine atmosphere during drilling in coal scams by using Messrs. Casella's Hexlet apparatus specially designed and fitted with horizontal elutriator to collect the respirable coal dust fraction simulating as near as possible to the lung's retention of the coal miners. After destruction of organic matter by wet oxidation and filtering off clay and silica, Fe, Ca, Mg, Na, K, Mn, Cu, Zn, Cd, and Ni were determined directly in the resulting solution by atomic absorption spectrophotometric procedures. The results show that the trace metals are more acute in lower range of size spectrum. Correlation coefficient, enrichment factor and linear regression values and their inverse relationship between the slope and EF values suggest that, in general, the trace metals in respirable particulates are likely to be from coal derived source if their concentrations are likewise high in the coal. The trace metal analytical data of respirable particulates fitted well to the linear regressive equation. The results of the studies are of importance as it may throw some light on the respirable lung disease 'pneumoconiosis' which are predominant in coal mining community. (author). 13 refs., 6 tabs

Effectiveness of underground coal extraction. Effektivnost' podzemnoy dobychi uglya

Energy Technology Data Exchange (ETDEWEB)

Pirskiy, A A

1982-01-01

This book examines the possibility of improving the efficiency of underground coal extraction based on the solution to the scientific-technical problem of monitoring and controlling concentration and intensifying mining operations. The problem has been resolved as applied to conditions of working coal fields of the Lvov-Volynskiy basin, West Donbass and other regions which are similar in relation to mining-geological conditions. The main conclusions and recommendations consist of the following: synthesized concept ''concentration of mining operations'' is determined by regulation and concentration, intensification of mining operations by using progressive technology, mechanization and organization of production in order to increase extraction, improve productivity of labor and reduce the net cost of coal. The structure of concentration of mining operations is based on the synthesis of natural, technical and organizational conditions for working coal seams. The problem of monitoring and control of the concentration of mining operations was realized by using the systems method based on the laws of development, principles of comprehensive evaluation and optimization of the level of concentration based on economic-mathematical modeling. The use of the systems approach guarantees a comprehensive solution to the problem. In definite periods of development of the coal industry, between the organizational-technical potentialities, natural conditions and trends determined in the sector for the change in the level of mining operation concentration, disproportions develop. The level of work concentration goes beyond the limits of optimal values, and the effectiveness of coal extraction is reduced. In order to predict and eliminate this phenomenon, it is recommended that the level of mining concentration be controlled.

The effects of coal quality on NO{sub x} emissions and carbon burnout in pulverised coal-fired utility boilers

Energy Technology Data Exchange (ETDEWEB)

O`Connor, M. [National Power plc, Swindon (United Kingdom)

1999-04-01

A comprehensive study is reported on the impact of coal quality on nitrogen oxides emissions and carbon burnout in utility boilers, with the aim of assessing their relationship and developing predictive tools for assessing coals. Experimental work was carried out on various laboratory-scale apparatus and on single burner test facilities ranging from 160 kW{sub th} to 40 MW{sub th} in size and measurements were obtained from full-scale 500 MW{sub e} utility boiler trials. This data and basic coal data were then used to develop mathematical models to predict full-scale boiler performance with respect to NO{sub x} emissions and carbon burnout. Power station trials demonstrated that coal quality effects nitrogen oxides and burnout. The variability in boiler conditions also impacted on these factors. Lower nitrogen and higher volatile coals generally produced less NO{sub x}. Volatile content was the most important generic coal property for predicting burnout. Modelling rig tests, using data from advanced laboratory-scale tests, were found to be just as successful as using rig tests for predicting NO{sub x} performance of different coals. Laboratory-scale tests were found to be successful in providing accurate predictions of burnout for the coals studied. Mathematical models, however, were found to be less successful in this area and further work to develop this is required. A major achievement was CFD solutions of full-scale utility boiler furnaces in a single mesh. 32 refs., 15 figs., 33 tabs., 2 apps.

Evaluation of risk strategy and market efficiency in the International coal market: A case study of the Japanese coking coal market

International Nuclear Information System (INIS)

Wang, T.

1992-01-01

Market efficiency and buyers' risk strategy in the Japanese coking import market are examined. The Japanese coal market is found to be inefficient. Japanese buyers traditionally have purchased coals from the United States at a high price and, since the second half of the 1980's, have paid the highest average price to Canadian producers. Given the abundant low cost Australian coals, this purchasing pattern does not meet the cost minimization criteria for efficiency. This is explained mainly by the buyers' risk management strategy. To more accurately examine price differentiation, the complexity of coal quality is considered first. A statistical method is used to estimate comparison of supply regions and a detailed investigation on market conduct is based on quality-adjusted prices, which are assumed to represent the prices of homogeneous coals. Although various reasons are used by researchers to explain Japanese buyers power, this study finds vertical integration of the Japanese companies to be the most important factor creating that power. A detailed survey of vertical integration is made. Finally, a monetary value of the risk premium is estimated by using the partial elasticity of substitution. Total payments by Japanese coking coal buyers for risk premiums are estimated. These represent the extra dollars paid by the Japanese to US and Canadian coal producers for purchasing their coals instead of Australian coals

Development of an inexact optimization model for coupled coal and power management in North China

International Nuclear Information System (INIS)

Liu, Y.; Huang, G.H.; Cai, Y.P.; Cheng, G.H.; Niu, Y.T.; An, K.

2009-01-01

In this study, an inexact coupled coal and power management (ICCPM) model was developed for planning coupled coal and power management systems through integrating chance-constrained programming (CCP), interval linear programming (ILP) and mixed integer linear programming (MILP) techniques. The ICCPM model can effectively handle uncertainties presented in terms of probability density functions and intervals. It can also facilitate dynamic analysis of capacity expansions, facility installation and coal inventory planning within a multi-period and multi-option context. Complexities in coupled coal and power management systems can be systematically reflected in this model, thus applicability of the modeling process would be highly enhanced. The developed ICCPM model was applied to a case of long-term coupled coal and power management systems planning in north China. Interval solutions associated with different risk levels of constraint violations have been obtained, which can be used for generating decision alternatives and helping identify desired policies. The generated results can also provide desired solutions for coal and power generation, capacity initiation and expansion, and coal blending with a minimized system cost, a maximized system reliability and a maximized coal transportation security. Tradeoffs between system costs and constraint-violation risks can also be tackled.

Development of biological coal gasification (MicGAS process). Final report, May 1, 1990--May 31, 1995

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-12-31

ARCTECH has developed a novel process (MicGAS) for direct, anaerobic biomethanation of coals. Biomethanation potential of coals of different ranks (Anthracite, bitumious, sub-bitumious, and lignites of different types), by various microbial consortia, was investigated. Studies on biogasification of Texas Lignite (TxL) were conducted with a proprietary microbial consortium, Mic-1, isolated from hind guts of soil eating termites (Zootermopsis and Nasutitermes sp.) and further improved at ARCTECH. Various microbial populations of the Mic-1 consortium carry out the multi-step MicGAS Process. First, the primary coal degraders, or hydrolytic microbes, degrade the coal to high molecular weight (MW) compounds. Then acedogens ferment the high MW compounds to low MW volatile fatty acids. The volatile fatty acids are converted to acetate by acetogens, and the methanogens complete the biomethanation by converting acetate and CO{sub 2} to methane.

Dustfall design of open coal yard in the power plant-a case study on the closed reconstruction project of coal storage yard in shengli power plant

Science.gov (United States)

Wang, Kunpeng; Ji, Weidong; Zhang, Feifei; Yu, Wei; Zheng, Runqing

2018-02-01

This thesis, based on the closed reconstruction project of the coal storage yard of Shengli Power Plant which is affiliated to Sinopec Shengli Petroleum Administration, first makes an analysis on the significance of current dustfall reconstruction of open coal yard, then summarizes the methods widely adopted in the dustfall of large-scale open coal storage yard of current thermal power plant as well as their advantages and disadvantages, and finally focuses on this project, aiming at providing some reference and assistance to the future closed reconstruction project of open coal storage yard in thermal power plant.

Utilisation potential of products of microbial coal liquefaction. Final report; Verwertungspotential der Produkte der mikrobiellen Kohleverfluessigung. Abschlussbericht

Energy Technology Data Exchange (ETDEWEB)

Koepsel, R.; Schmiers, H.; Grosse, S.; Weber, A.

2002-07-01

Ever since the discovery in the 1980s that microorganisms are capable of converting coal into soluble products research groups all over the world have been exploring the bioconversion of coal. It was at an advance stage of the present integrated project, which initially only involved microbiology research groups, that the need for a chemical working group with knowledge and experience in the area of coal chemistry and structural analysis of coal was recognised. The task of the chemical working group was to provide knowledge on the chemical nature of bioconversion products and the chemical processes of coal bioconversion. This involved identifying structural changes occurring in the feed coal as well as in its constituent humic acids and macromolecular matrix as a result of the activity of coal degrading microorganisms. [German] Nachdem Anfang der achtziger Jahre entdeckt wurde, dass sich Kohlen durch Mikroorganismen in loesliche Produkte ueberfuehren lassen, agieren weltweit Forschergruppen auf dem Gebiet der Biokonversion von Kohle. In einem fortgeschrittenen Bearbeitungsstadium des Verbundprojektes, an dem zunaechst nur mikrobiologische Arbeitsgruppen beteiligt waren, wurde die Notwendigkeit erkannt, eine chemische Arbeitsgruppe mit Kenntnissen und Erfahrungen auf den Gebieten der Kohlechemie und der Strukturanalytik von Kohlen zu integrieren. Aufgabenstellung der chemischen Arbeitsgruppe war und ist es, Erkenntnisse ueber die chemische Natur der Biokonversionsprodukte und die chemischen Ablaeufe der mikrobiellen Kohlekonversion bereitstellen. Die Aufgabenstellung umfasst die Aufklaerung der strukturellen Veraenderung der Einsatzkohle sowie ihrer Komponenten Huminsaeuren und makromolekulare Matrix durch die Einwirkung kohleabbauender Mikroorganismen. (orig.)

Adsorption isotherms and kinetics of activated carbons produced from coals of different ranks.

Science.gov (United States)

Purevsuren, B; Lin, Chin-Jung; Davaajav, Y; Ariunaa, A; Batbileg, S; Avid, B; Jargalmaa, S; Huang, Yu; Liou, Sofia Ya-Hsuan

2015-01-01

Activated carbons (ACs) from six coals, ranging from low-rank lignite brown coal to high-rank stone coal, were utilized as adsorbents to remove basic methylene blue (MB) from an aqueous solution. The surface properties of the obtained ACs were characterized via thermal analysis, N2 isothermal sorption, scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and Boehm titration. As coal rank decreased, an increase in the heterogeneity of the pore structures and abundance of oxygen-containing functional groups increased MB coverage on its surface. The equilibrium data fitted well with the Langmuir model, and adsorption capacity of MB ranged from 51.8 to 344.8 mg g⁻¹. Good correlation coefficients were obtained using the intra-particle diffusion model, indicating that the adsorption of MB onto ACs is diffusion controlled. The values of the effective diffusion coefficient ranged from 0.61 × 10⁻¹⁰ to 7.1 × 10⁻¹⁰ m² s⁻¹, indicating that ACs from lower-rank coals have higher effective diffusivities. Among all the ACs obtained from selected coals, the AC from low-rank lignite brown coal was the most effective in removing MB from an aqueous solution.

Modeling the international competitiveness of Botswana's coal

Science.gov (United States)

Fichani, Khaulani

Botswana has vast proven deposits of steam coal, which for a long time it has wanted to develop but without much success. The main objectives of this study are: (1) to analyze the time schedule of coal exports likely to be forthcoming from Botswana and the land routes for these exports; (2) to determine the competitiveness of Botswana's coal in the world steam coal markets and (3) to make recommendations on the appropriate policy for the exploitation of this coal. To accomplish these objectives, we construct a model of the seaborne steam coal trade consisting of exporters and importers with a substantial share in this trade. We econometrically estimate the long run marginal cost functions for net exporters and employ these to construct a spatial and dynamic model of the world steam coal trade with elastic supply and inelastic demand. This model is applied to simulate Botswana's competitiveness in this trade over the period 1995 to 2010 from a 1990 base year with a decision criterion that minimizes the sum of discounted capital costs of mine development, variable supply costs, rail and maritime transportation costs. Finally, we employ the model to forecast the likely optimal size of mine, timing of production capacity and choice of export port for Botswana's coal for the years 2005 and 2010. The base year for the forecast is 2000. The simulation results indicate that Botswana's coal would have been competitive in the steam coal markets of Western Europe and Asia. The forecast results indicate that Botswana's coal would also be competitive in these markets in the future. These results are least sensitive to changes in rail transportation and variable supply costs but are sensitive to capital costs for mine development.

Reducing Heavy Metal Element from Coal Bottom Ash by Using Citric Acid Leaching Treatment

Directory of Open Access Journals (Sweden)

Yahya Ahmad Asyari

2017-01-01

Full Text Available Coal ash is the residue that is produced during coal combustion for instance fly ash, bottom ash or boiler slag which was primarily produced from the combustion of coal. With growth in coal burning power station, huge amount of coal bottom ash (CBA considered as hazardous material which are normally disposed in an on-site disposal system without any commercialization purpose. Previous researchers have studied the extraction of silica from agricultural wastes such as palm ash and rice husk ash (RHA and CBA by using leaching treatment method. In this study, the weaker acid, citric acid solution was used to replace the strong acid in leaching treatment process. Result showed that the heavy metal content such as Copper (Cu, Zinc (Zn and Lead (Pb can be decrease. Meanwhile the silica can be extracted up to 44% from coal bottom ash using citric acid leaching treatment under the optimum reaction time of 60 minutes with solution temperature of 60°C and concentration of citric acid more than 2%.

Coal 1992

Energy Technology Data Exchange (ETDEWEB)

1992-01-01

ACR's Coal 1992, the successor to the ACR Coal Marketing Manual, contains a comprehensive set of data on many aspects of the Australian coal industry for several years leading up to 1992. Tables and text give details of coal production and consumption in New South Wales, Queensland and other states. Statistics of the Australian export industry are complemented by those of South Africa, USA, New Zealand, Canada, Indonesia, China, Colombia, Poland and ex-USSR. Also listed are prices of Australian coking and non-coking coal, Australian coal stocks (and those of other major countries), loading port capacities, freight rates and coal quality requirements (analysis of coals by brand and supplier). A listing of Australian coal exporting companies is provided. A description of the spot Coal Screen Dealing System is given. World hard coal imports are listed by country and coal imports by major Asian countries tabulated. A forecast of demand by coal type and country up to the year 2000 is included.

Characterization of Coal Porosity for Naturally Tectonically Stressed Coals in Huaibei Coal Field, China

Science.gov (United States)

Li, Xiaoshi; Hou, Quanlin; Li, Zhuo; Wei, Mingming

2014-01-01

The enrichment of coalbed methane (CBM) and the outburst of gas in a coal mine are closely related to the nanopore structure of coal. The evolutionary characteristics of 12 coal nanopore structures under different natural deformational mechanisms (brittle and ductile deformation) are studied using a scanning electron microscope (SEM) and low-temperature nitrogen adsorption. The results indicate that there are mainly submicropores (2~5 nm) and supermicropores (coal and mesopores (10~100 nm) and micropores (5~10 nm) in brittle deformed coal. The cumulative pore volume (V) and surface area (S) in brittle deformed coal are smaller than those in ductile deformed coal which indicates more adsorption space for gas. The coal with the smaller pores exhibits a large surface area, and coal with the larger pores exhibits a large volume for a given pore volume. We also found that the relationship between S and V turns from a positive correlation to a negative correlation when S > 4 m2/g, with pore sizes coal. The nanopore structure (coal. PMID:25126601

Research on mechanism of and catalysts for extraction liquefaction of coal using coal-based solvents; Sekitankei yozai ni yoru sekitan no chushutsu ekika kiko to shokubai no kenkyu

Energy Technology Data Exchange (ETDEWEB)

NONE

1981-07-01

Papers of Professor Yoshio Kamiya of Tokyo University are compiled into this report. The list of the papers includes (1) Synthesis of heavy fuel oils from coal; (2) Research and development of coal liquefaction; (3) Dissolution reaction of coal by hydrogen-donating aromatic solvents (I); (4) Effect of hydrogen-donor solvent on the liquefaction of coal; (5) Recent studies on the chemical structure of solvent refined coal; (6) Dissolution reaction of coal by hydrogen-donating aromatic solvents (II); (7) Future of coal as energy material; (8), (9), (10) same as (6) in the subject discussed; (11) Recent studies on coal liquefaction catalysts; (12) Environmental problems and drain treatment to accompany processes of converting fossil resources into fuels; (13) Chemistry of coal oxidation; (14) Fractionation and analysis of solvent refined coal by gel permeation chromatography; (15) Current state of research and development of coal liquefaction; (16) Properties and components of coal oils from coal liquefaction processes under development; (17) Solvent effect of coal derived aromatic compounds on the liquefaction of Akabira coal; (18) Chemistry of coal liquefaction; (19) Research and development of coal liquefaction in the U.S.; (20) Thermal treatment of coal-related aromatic ethers in tetralin solution; (21) Recent technology of utilizing heavy carbon resources; (22) Chemical properties and reactivity of coal; (23) Current state and future of development of coal liquefaction processes; and (24) Development of overseas coal liquefaction projects. (NEDO)

Applying Rock Engineering Systems (RES approach to Evaluate and Classify the Coal Spontaneous Combustion Potential in Eastern Alborz Coal Mines

Directory of Open Access Journals (Sweden)

Amir Saffari

2013-12-01

Full Text Available Subject analysis of the potential of spontaneous combustion in coal layers with analytical and numerical methods has been always considered as a difficult task because of the complexity of the coal behavior and the number of factors influencing it. Empirical methods, due to accounting for certain and specific factors, have not accuracy and efficiency for all positions. The Rock Engineering Systems (RES approach as a systematic method for analyzing and classifying is proposed in engineering projects. The present study is concerned with employing the RES approach to categorize coal spontaneous combustion in coal regions. Using this approach, the interaction of parameters affecting each other in an equal scale on the coal spontaneous combustion was evaluated. The Intrinsic, geological and mining characteristics of coal seams were studied in order to identifying important parameters. Then, the main stages of implementation of the RES method i.e. interaction matrix formation, coding matrix and forming a list category were performed. Later, an index of Coal Spontaneous Combustion Potential (CSCPi was determined to format the mathematical equation. Then, the obtained data related to the intrinsic, geological and mining, and special index were calculated for each layer in the case study (Pashkalat coal region, Iran. So, the study offers a perfect and comprehensive classification of the layers. Finally, by using the event of spontaneous combustion occurred in Pashkalat coal region, an initial validation for this systematic approach in the study area was conducted, which suggested relatively good concordance in Pashkalat coal region.

Comprehensive evaluation on low-carbon development of coal enterprise groups.

Science.gov (United States)

Wang, Bang-Jun; Wu, Yan-Fang; Zhao, Jia-Lu

2017-12-19

Scientifically evaluating the level of low-carbon development in terms of theoretical and practical significance is extremely important to coal enterprise groups for implementing national energy-related systems. This assessment can assist in building institutional mechanisms that are conducive for the economic development of coal business cycle and energy conservation as well as promoting the healthy development of coal enterprises to realize coal scientific development and resource utilization. First, by adopting systematic analysis method, this study builds low-carbon development evaluation index system for coal enterprise groups. Second, to determine the weight serving as guideline and criteria of the index, analytic hierarchy process (AHP) is applied using integrated linear weighted sum method to evaluate the level of low-carbon development of coal enterprise groups. Evaluation is also performed by coal enterprise groups, and the process comprises field analysis and evaluation. Finally, industrial policies are proposed regarding the development of low-carbon coal conglomerate strategies and measures. This study aims mainly to guide the low-carbon development of coal enterprise groups, solve the problem of coal mining and the destruction of ecological environment, support the conservation of raw materials and various resources, and achieve the sustainable development of the coal industry.

ANFO bulk loading in coal mines

Energy Technology Data Exchange (ETDEWEB)

Gajjar, A.

1987-08-01

With India's total coal production projected to increase from 152 to 237 million tons by 1990, net additional production from new mines must be more because of substantial depletion in existing mines. This article discusses the best possible application of explosive techniques in open-cast coal mines to economize production cost. The most energy-efficient and safest explosive is ANFO (ammonium nitrate, fuel oil); however, manual charging by INFO is not possible. Therefore, the solution is the application of bulk-loading systems of ANFO for giant mining operations. Cost of blasting per ton of coal production in India is in the range of Rs 25. Thus, the author suggests it will be the responsibility of mining engineers to see that the ANFO based bulk-loading system is implemented and the cost of production per ton reduced to Rs 19.50.

Emissions of organic hazardous air pollutants during Chinese coal combustion

Energy Technology Data Exchange (ETDEWEB)

Yan, R.; Zhu, H.J.; Zheng, C.G.; Xu, M.H. [Environmental Technology Institute, Singapore (Singapore). Innovative Center

2002-05-01

The emissions of organic hazardous air pollutants (HAPs) during the combustion of several typical Chinese coals were investigated. First, the distribution of four types of HAP, i.e., aliphatics, cyclic hydrocarbons, monoaromatic compounds and PAHs, in the CH{sub 2}C{sub l2} extracts of six Chinese coals were studied and the influences of the extractive times and coal varieties were also evaluated. Second, the partitioning of these HAPs in the flue gas during coal combustion in a small-scale reactor were investigated, depending on oven temperatures (500, 600, 700, 800, 900{sup o}C) and coal varieties. The behaviors of HAP in the combustion flue gas were compared with those in the CH{sub 2}, Cl{sub 2}, extracts. Finally, combustion was conducted at given conditions in two laboratory-scale reactors: a fluidized bed and a fixed bed. Two coals (Shengmu bituminous coal and Xunhuan anthracite coal) and one coke were considered. The HAP partitioning both in flue gases and in ashes were evaluated and compared between the two combustors.

Ultrasonic characterization of coal liquefaction products. Final report, April 11, 1979-February 11, 1980

Energy Technology Data Exchange (ETDEWEB)

Leffert, C. B.; Weisman, L.; Moore, D.

1980-02-29

The Wayne State University ultrasonic device and technique was used successfully to calibrate coal-derived 0 to 45% wt % asphaltene-in-oil mixtures (2 wt % increments) for transmitted signal strength versus temperature (25 to 100/sup 0/C). Computer-aided cross plots of the transmitted signal strength versus concentration of asphaltene showed that a wide range of concentration and temperature exists where the viscosity-dominated (lower temperature) sound absorption is such that a single-valued number for the concentration of the asphaltene can be obtained from measurement of the sample temperature and transmitted signal strength and thus obtain a measure of the quality of the coal-derived product. Sufficient samples were not provided to obtain a complete calibration of added particulate matter of ash and undissolved coal at all asphaltene in oil concentrations; however, calibrations were made of added ash to three concentrations of asphaltene-in-oil and the data showed the greatest effect at the higher temperatures indicating (as planned) that sound attenuation from Rayleigh scattering is predominant with the suspended particles. We conclude from these two sets of measurements that there is a excellent expectation that the Wayne State ultrasonic device and technique could be used to simultaneously measure (on-line) the suspended particle concentration as well as the quality of the coal-derived product.

Specific Energy of Hard Coal Under Load

Directory of Open Access Journals (Sweden)

Bogusz Anna

2015-03-01

Full Text Available The article presents results of experimental tests of energy parameters of hard coals under loading, collected from research sites located within five main geologic structures of Upper Silesian Coal Basin (GZW - Main Trough, Main Anticline, Bytom Trough, Rybnik Trough and Chwałowice Trough. Coals from12 mines were analysed, starting with seams of group 200, through groups 400, 500, 600 and, finally, seams of group 700. Coal of each of the groups of seams underwent uniaxial compression stress of the energy parameters, in a servo-controlled testing machine MTS-810NEW, for the full range of strain of the tested coal samples. Based on the tests the dependence of different types of specific energy of longitudinal strain of coals on the value of uniaxial compression strength was determined. The dependence of the value of dissipated energy and kinetic energy of coals on the uniaxial compression strength was described with a linear function, both for coals which due to their age belong to various bed sand for various lithotypes of coal. An increase in the value of dissipated energy and in kinetic energy was observed, which was correlated with an increase in uniaxial compression strength of coal. The share of dissipated energy is dominant in the total energy of strain. Share of recoverable energy in the total energy of strain is small, independent of the compression strength of coals and is at most a few per cent high. In coals of low strength and dominant share of dissipated energy, share of recoverable energy is the biggest among the tested coals. It was shown that following an increase in compression strength the share of recoverable energy decreases, while the share of dissipated energy in the total energy increases. Further studies of specific energy of longitudinal strain of rocks in the full-range strain will be the next step inperfecting methodology of research into natural rock burst susceptibility of Carboniferous rock mass and changes in the

Study of the Radiological Impact of the Coal Fired Power Plants on the Environment. The As Pontes coal-fired Power Plant

International Nuclear Information System (INIS)

Cancio, D.; Robles, B.; Mora, J. C.

2009-01-01

As part of the Study carried out to determine the radiological impact of the four main Spanish coal-fired power plants, the Study on the As Pontes Coal-Fired Coal Power Plant was finalized. In the Report containing the study are included every measurement performed, as well as the modelling and evaluations carried out in order to assess the radiological impact. The general conclusion obtained is that under a radiological point of view, the impact of this installation on the public and the environment is very small. Also the radiological impact on the workers of the installation was assessed, obtaining too very small increases over the natural background. (Author) 61 refs.

FUNDAMENTAL KINETICS OF SUPERCRITICAL COAL LIQUEFACTION: EFFECT OF CATALYSTS AND HYDROGEN-DONOR SOLVENTS; FINAL

International Nuclear Information System (INIS)

Benjamin J. McCoy; J.M. Smith

1998-01-01

This report outlines a distribution kinetics approach to macromolecular reactions that has been applied to several processes. The objective was to develop an understanding of high-temperature, dense-phase thermolytic processes for complex macromolecular systems, such as coal. Experiments and theory are described for chemical models that simulate depolymerization of coal. The approach has been exceptionally successful for the model macromolecular systems. Development of a novel chemical reaction engineering analysis, based on distribution kinetics, was a major accomplishment of the current research

Effects of coal gangue content on water movement and solute transport in a China loess plateau soil

Energy Technology Data Exchange (ETDEWEB)

Beibei, Zhou; Quanjiu, Wang [Institute of Water Resources and Hydro-electric Engineering, Xi' an University of Technology, Xi' an (China); State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau, Institute of Soil and Water Conservation, Northwest A and F University, Yangling, Shaanxi (China); Ming' an, Shao; Mingxia, Wen [State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau, Institute of Soil and Water Conservation, Northwest A and F University, Yangling, Shaanxi (China); College of Resources and Environment, Northwest A and F University, Yangling, Shaanxi (China); Horton, Robert [Department of Agronomy, Iowa State University, Ames, Iowa (United States)

2010-11-15

The mining industry has grown strongly in China in recent decades, resulting in large amounts of coal gangues, which cause water and soil pollution, soil erosion, and various other environmental problems. They are often used in reclamation projects in attempts to restore land damaged by mining, hence they are frequently present (in widely varying proportions) in the topsoil in areas around mines. Their presence can strongly affect key soil variables, including its bulk density, structure, water retention, water movement, and solute transport rates. In the study presented here, the effects of gangue contents on infiltration, saturated hydraulic conductivity, and solute transport parameters of a Chinese Loess plateau soil were examined. The results show that infiltration rates and saturated hydraulic conductivity decreased with increasing gangue content. The Peck-Watson equation modeled these relationships well, but Bouwer-Rice equations provided poorer matches with the acquired data. Cumulative infiltration over time was described well by both the Philip equation and Kostiakov equation. Both the simplified convection-dispersion equation and a two-region model described the solute transport processes well. In addition, the dispersion increased, while both the Peclet number and mobile water fraction decreased, with increases in gangue contents. (Copyright copyright 2010 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Development of a pulsed coal combustor fired with CWM (coal-water mixture): Phase 3, Final report

Energy Technology Data Exchange (ETDEWEB)

Mansour, M.N.; Durai-Swamy, K.

1986-11-01

This report presents the results of an R and D program aimed at developing a new burner technology for coal-water mixture (CWM) fuels to enable the substitution of these new fuels in utility and industrial boilers and process heaters currently firing oil and gas. The application of pulse combustion to CWM fuels is chosen to alleviate many of the physical plant and environmental constraints presently associated with the direct use of these fuels in equipment designed for oil and gas firing. Pulse combustion has been shown to be capable of high-intensity burning of coal for acceptably complete combustion within relatively small equipment volumes. It also has the inherent capability to agglomerate ash particles, thus rendering ash more easily separable from the combustion gas prior to its entrance into the convective section of the boiler or heater, thereby reducing ash buildup and pluggage. Pulse combustion is also well-suited to staged combustion for NO/sub x/ control and has excellent potential for enhanced in-furnace SO/sub 2/ removal due to the enhanced levels of mass transfer brought about by the vigorous flow oscillations. The primary objective of the Phase 2 work was to develop a detailed program for laboratory development and evaluation of the pulse CWM combustor and system design concepts. 112 refs., 40 figs., 94 tabs.

Bio-coal briquettes using low-grade coal

Science.gov (United States)

Estiaty, L. M.; Fatimah, D.; Widodo

2018-02-01

The technology in using briquettes for fuel has been widely used in many countries for both domestic and industrial purposes. Common types of briquette used are coal, peat, charcoal, and biomass. Several researches have been carried out in regards to the production and the use of briquettes. Recently, researches show that mixing coal and biomass will result in an environmentally friendly briquette with better combustion and physical characteristics. This type of briquette is known as bio-coal briquettes. Bio-coal briquettes are made from agriculture waste and coal, which are readily available, cheap and affordable. Researchers make these bio-coal briquettes with different aims and objectives, depending on the issues to address, e.g. utilizing agricultural waste as an alternative energy to replace fossil fuels that are depleting its reserves, adding coal to biomass in order to add calorific value to bio-coal briquette, and adding biomass to coal to improve its chemical and physical properties. In our research, biocoal briquettes are made to utilize low grade coal. The biomass we use, however, is different from the ones used in past researches because it has undergone fermentation. The benefits of using such biomass are 1. Fermentation turns the hemi cellulose into a simpler form, so that the burning activation energy decreases while the calorific value increases. 2. Enzym produced will bind to heavy metals from coal as co-factors, forming metals that are environmentally friendly.

British Coal and the energy scene

Energy Technology Data Exchange (ETDEWEB)

Cruttenden, M G [British Coal Corporation, London (United Kingdom)

1992-01-01

This paper attempts to describe British Coal's (BCC) present position in a rapidly changing UK Energy Market where competition, with imported coal and with other fuels, particularly natural gas is likely to continue to increase. As a relatively high cost coal producer by world standards BCC, while continuing its efforts to improve productivity and lower costs, must work to enhance the value of its product in the market place both by improving quality to more closely match customers individual needs and by offering supporting services which ensure overall customer satisfaction. The paper explores each market sector and describes the steps which the Corporation is taking to improve its competitive position in each market with particular reference to quality standards and supporting services. Finally it attempts to forecast some possible new developments for the future. 3 tabs.

Gas core reactors for coal gasification

International Nuclear Information System (INIS)

Weinstein, H.

1976-01-01

The concept of using a gas core reactor to produce hydrogen directly from coal and water is presented. It is shown that the chemical equilibrium of the process is strongly in favor of the production of H 2 and CO in the reactor cavity, indicating a 98 percent conversion of water and coal at only 1500 0 K. At lower temperatures in the moderator-reflector cooling channels the equilibrium strongly favors the conversion of CO and additional H 2 O to CO 2 and H 2 . Furthermore, it is shown the H 2 obtained per pound of carbon has 23 percent greater heating value than the carbon so that some nuclear energy is also fixed. Finally, a gas core reactor plant floating in the ocean is conceptualized which produces H 2 , fresh water and sea salts from coal

CoalVal-A coal resource valuation program

Science.gov (United States)

Rohrbacher, Timothy J.; McIntosh, Gary E.

2010-01-01

CoalVal is a menu-driven Windows program that produces cost-of-mining analyses of mine-modeled coal resources. Geological modeling of the coal beds and some degree of mine planning, from basic prefeasibility to advanced, must already have been performed before this program can be used. United States Geological Survey mine planning is done from a very basic, prefeasibility standpoint, but the accuracy of CoalVal's output is a reflection of the accuracy of the data entered, both for mine costs and mine planning. The mining cost analysis is done by using mine cost models designed for the commonly employed, surface and underground mining methods utilized in the United States. CoalVal requires a Microsoft Windows? 98 or Windows? XP operating system and a minimum of 1 gigabyte of random access memory to perform operations. It will not operate on Microsoft Vista?, Windows? 7, or Macintosh? operating systems. The program will summarize the evaluation of an unlimited number of coal seams, haulage zones, tax entities, or other area delineations for a given coal property, coalfield, or basin. When the reader opens the CoalVal publication from the USGS website, options are provided to download the CoalVal publication manual and the CoalVal Program. The CoalVal report is divided into five specific areas relevant to the development and use of the CoalVal program: 1. Introduction to CoalVal Assumptions and Concepts. 2. Mine Model Assumption Details (appendix A). 3. CoalVal Project Tutorial (appendix B). 4. Program Description (appendix C). 5. Mine Model and Discounted Cash Flow Formulas (appendix D). The tutorial explains how to enter coal resource and quality data by mining method; program default values for production, operating, and cost variables; and ones own operating and cost variables into the program. Generated summary reports list the volume of resource in short tons available for mining, recoverable short tons by mining method; the seam or property being mined

The determination of methane resources from liquidated coal mines

Science.gov (United States)

Trenczek, Stanisław

2017-11-01

The article refers to methane presented in hard coal seams, which may pose a serious risk to workers, as evidenced by examples of incidents, and may also be a high energy source. That second issue concerns the possibility of obtaining methane from liquidated coal mines. There is discussed the current methodology for determination of methane resources from hard coal deposits. Methods of assessing methane emissions from hard coal deposits are given, including the degree of rock mass fracture, which is affected and not affected by mining. Additional criteria for methane recovery from the methane deposit are discussed by one example (of many types) of methane power generation equipment in the context of the estimation of potential viable resources. Finally, the concept of “methane resource exploitation from coal mine” refers to the potential for exploitation of the resource and the acquisition of methane for business purposes.

Study on coal char ignition by radiant heat flux.

Science.gov (United States)

Korotkikh, A. G.; Slyusarskiy, K. V.

2017-11-01

The study on coal char ignition by CO2-continuous laser was carried out. The coal char samples of T-grade bituminous coal and 2B-grade lignite were studied via CO2-laser ignition setup. Ignition delay times were determined at ambient condition in heat flux density range 90-200 W/cm2. The average ignition delay time value for lignite samples were 2 times lower while this difference is larger in high heat flux region and lower in low heat flux region. The kinetic constants for overall oxidation reaction were determined using analytic solution of simplified one-dimensional heat transfer equation with radiant heat transfer boundary condition. The activation energy for lignite char was found to be less than it is for bituminous coal char by approximately 20 %.

MINIMIZATION OF NO EMISSIONS FROM MULTI-BURNER COAL-FIRED BOILERS; FINAL

International Nuclear Information System (INIS)

E.G. Eddings; A. Molina; D.W. Pershing; A.F. Sarofim; T.H. Fletcher; H. Zhang; K.A. Davis; M. Denison; H. Shim

2002-01-01

The focus of this program is to provide insight into the formation and minimization of NO(sub x) in multi-burner arrays, such as those that would be found in a typical utility boiler. Most detailed studies are performed in single-burner test facilities, and may not capture significant burner-to-burner interactions that could influence NO(sub x) emissions. Thus, investigations of such interactions were made by performing a combination of single and multiple burner experiments in a pilot-scale coal-fired test facility at the University of Utah, and by the use of computational combustion simulations to evaluate full-scale utility boilers. In addition, fundamental studies on nitrogen release from coal were performed to develop greater understanding of the physical processes that control NO formation in pulverized coal flames-particularly under low NO(sub x) conditions. A CO/H(sub 2)/O(sub 2)/N(sub 2) flame was operated under fuel-rich conditions in a flat flame reactor to provide a high temperature, oxygen-free post-flame environment to study secondary reactions of coal volatiles. Effects of temperature, residence time and coal rank on nitrogen evolution and soot formation were examined. Elemental compositions of the char, tar and soot were determined by elemental analysis, gas species distributions were determined using FTIR, and the chemical structure of the tar and soot was analyzed by solid-state(sup 13)C NMR spectroscopy. A laminar flow drop tube furnace was used to study char nitrogen conversion to NO. The experimental evidence and simulation results indicated that some of the nitrogen present in the char is converted to nitric oxide after direct attack of oxygen on the particle, while another portion of the nitrogen, present in more labile functionalities, is released as HCN and further reacts in the bulk gas. The reaction of HCN with NO in the bulk gas has a strong influence on the overall conversion of char-nitrogen to nitric oxide; therefore, any model that

Coking coal outlook from a coal producer's perspective

International Nuclear Information System (INIS)

Thrasher, E.

2008-01-01

Australian mine production is recovering from massive flooding while Canadian coal shipments are limited by mine and rail capacity. Polish, Czech, and Russian coking coal shipments have been reduced and United States coking coal shipments are reaching their maximum capacity. On the demand side, the Chinese government has increased export taxes on metallurgical coal, coking coal, and thermal coal. Customers seem to be purchasing in waves and steel prices are declining. This presentation addressed the global outlook for coal as well as the challenges ahead in terms of supply and demand. Supply challenges include regulatory uncertainty; environmental permitting; labor; and geology of remaining reserves. Demand challenges include global economic uncertainty; foreign exchange values; the effect of customers making direct investments in mining operations; and freight rates. Consolidation of the coal industry continued and several examples were provided. The presentation also discussed other topics such as coking coal production issues; delayed mining permits and environmental issues; coking coal contract negotiations; and stock values of coking coal producers in the United States. It was concluded that consolidation will continue throughout the natural resource sector. tabs., figs

Evaluation of the effect of coal cleaning of fugitive elements. Part II. Analytical methods. Final report, Phase II

Energy Technology Data Exchange (ETDEWEB)

Bosshart, R.E.; Price, A.A.; Ford, C.T.

1980-03-01

This report contains the analytical and test methods which were used routinely at Bituminous Coal Research, Inc. during the project. The procedures contained herein should aid coal industry laboratories and others, including commercial laboratories, who might be required to determine trace elements in coal. Some of the procedures have been presented in previous BCR reports; however, this report includes additional procedures which are described in greater detail. Also presented are many as the more basic coal methods which have been in use at BCR for many years, or which have been adapted or refined from other standard reference sources for coal and water. The basis for choosing specific analytical procedures for trace elements in coal is somewhat complex. At BCR, atomic absorption was selected as the basic method in the development of these procedures. The choice was based on sensitivity, selectivity, accuracy, precision, practicability, and economy. Whenever possible, the methods developed had to be both adequate and amenable for use by coal industry laboratories by virtue of relative simplicity and cost. This is not to imply that the methods described are simple or inexpensive; however, atomic abosrption techniques do meet these criteria in relation to more complex and costly methods such as neutron activation, mass spectrometry, and x-ray fluorescence, some of which require highly specialized personnel as well as access to sophisticated nuclear and computational facilities. Many of the analytical procedures for trace elements in coal have been developed or adapted specifically for the BCR studies. Their presentation is the principal purpose of this report.

The development of coal-based technologies for Department of Defense facilities: Phase 1 final report. Volume 1: Technical report

Energy Technology Data Exchange (ETDEWEB)

Miller, B.G.; Morrison, J.L.; Pisupati, S.V. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center] [and others

1997-01-31

The first phase of a three-phase project investigating the development of coal-based technologies for Department of Defense facilities has been completed. The objectives of the project are to: decrease DOD`s dependence on foreign oil and increase its use of coal; promote public and private sector deployment of technologies for utilizing coal-based fuels in oil-designed combustion equipment; and provide a continuing environment for research and development of coal-based fuel technologies for small-scale applications at a time when market conditions in the US are not favorable for the introduction of coal-fired equipment in the commercial and industrial capacity ranges. The Phase 1 activities were focused on developing clean, coal-based combustion technologies for the utilization of both micronized coal-water mixtures (MCWMs) and dry, micronized coal (DMC) in fuel oil-designed industrial boilers. The specific objective in Phase 1 was to deliver fully engineered retrofit options for a fuel oil-designed watertube boiler located on a DOD installation to fire either MCWM or DMC. This was achieved through a project consisting of fundamental, pilot-sale, and demonstration-scale activities investigating coal beneficiation and preparation, and MCWM and DMC combustion performance. In addition, detailed engineering designs and an economic analysis were conducted for a boiler located at the Naval Surface Warfare Center, near Crane, Indiana. Results are reported on MCWM and DMC combustion performance evaluation; engineering design; and cost/economic analysis.

Coal contract cost reduction through resale of coal

International Nuclear Information System (INIS)

Simon, R.

1990-01-01

The weak coal market of the 1980's has enabled utilities and other users of coal to enjoy stable or falling prices for coal supplies. Falling prices for coal stimulated the renegotiation of numerous coal contracts in recent years, as buyers look to take advantage of lower fuel prices available in the marketplace. This paper examines the use of coal resale transactions as a means of reducing fuel costs, and analyzes the benefits and risks associated with such transactions

The Concept of Resource Use Efficiency as a Theoretical Basis for Promising Coal Mining Technologies

Science.gov (United States)

Mikhalchenko, Vadim

2017-11-01

The article is devoted to solving one of the most relevant problems of the coal mining industry - its high resource use efficiency, which results in high environmental and economic costs of operating enterprises. It is shown that it is the high resource use efficiency of traditional, historically developed coal production systems that generates a conflict between indicators of economic efficiency and indicators of resistance to uncertainty and variability of market environment parameters. The traditional technological paradigm of exploitation of coal deposits also predetermines high, technology-driven, economic risks. The solution is shown and a real example of the problem solution is considered.

Problems and solutions of reliability issues for external power supply in the coal mines

Directory of Open Access Journals (Sweden)

И. Ю. Семыкина

2017-08-01

Full Text Available Restructuring of the energy sector  and liberalization of the electricity market resulted in separation of a single industry into a multitude of generating companies, federal and interregional distribution utilities, regional power providers and energy suppliers. For a number of reasons, related to the process of managing separate companies, faults in the laws and regulations, and unsatisfactory technical state of the energy equipment both on the part of distributors and consumers, reliability of energy supply faces increasing negative trends, which potentially can lead to big problems. Up to this day the energy sector does not have a developed database on the state of equipment and results of its maintenance, nor has it defined criteria to actually assess technical conditions of the equipment. The authors propose to develop and implement a mechanism aimed at technical auditing and monitoring of the engineering state of external power supply system, whose results can help in the development of more efficient and economically sound measures to improve reliability of energy supply. In recent years, a lot of attention has been paid to the issues of enhanced security of industrial power supply. However, specific characteristics of underground coal mining and enormous work load of the production process limit the applicability of developed methods and algorithms. Existing research does not address economic issues of reliable energy supply, either direct (economic damage from power interruptions, contractual security of supply, tariff regulation or indirect (charges for utility connection with a required level of reliability. There is no explicit definition for the term «autonomous energy source», nor is there a list of power receivers falling into the first and «special» categories according to their reliability. The paper contains a range of urgent problems and solutions that will increase reliability of external power supply in the coal mines.

WABASH RIVER COAL GASIFICATION REPOWERING PROJECT

Energy Technology Data Exchange (ETDEWEB)

Unknown

2000-09-01

The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

POTENTIAL OF LIVESTOCK MANURE FOR COAL ACTIVATION

Directory of Open Access Journals (Sweden)

EllIN HARlIA HARlIA

2017-06-01

Full Text Available The natural methane formed by bacteria in anaerobic conditions is known as biogenic gas. Gas trapped in coal, formed through thermogenesis as well as biogenesisis known as coal-bed methane (CBM. The availability of organic material as decomposition of this material into methane is continuously required for the production of methane in the coal aquifer. The aim of this research was to investigate whether or not cattle feces bacteria were able to grow and produce methane in coal. Parameters measured were Volatile Fatty Acids (VFA and the production of biogas, such as nitrogen, hydrogen, carbon dioxide, and methane. Explorative method was used and data obtained was analyzed by descriptive approach. The results showed that the bacteria found in the feces survived in the coal and produce biogas. On day 2 when the process was at the acidogenesis phase, it produced VFA with the largest component of acetic acid. Acetic acid would undergo decarboxylation and reduction of CO2 followed by reactions of H2and CO2 to produce methane (CH4 and carbon dioxide (CO2 as the final products. ,

Australian Coal Company Risk Factors: Coal and Oil Prices

OpenAIRE

M. Zahid Hasan; Ronald A. Ratti

2014-01-01

Examination of panel data on listed coal companies on the Australian exchange over January 1999 to February 2010 suggests that market return, interest rate premium, foreign exchange rate risk, and coal price returns are statistically significant in determining the excess return on coal companies’ stock. Coal price return and oil price return increases have statistically significant positive effects on coal company stock returns. A one per cent rise in coal price raises coal company returns ...

Coal Tar and Coal-Tar Pitch

Science.gov (United States)

Learn about coal-tar products, which can raise your risk of skin cancer, lung cancer, and other types of cancer. Examples of coal-tar products include creosote, coal-tar pitch, and certain preparations used to treat skin conditions such as eczema, psoriasis, and dandruff.

COAL CONVERSION WASTEWATER TREATMENT BY CATALYTIC OXIDATION IN SUPERCRITICAL WATER; FINAL

International Nuclear Information System (INIS)

Phillip E. Savage

1999-01-01

Wastewaters from coal-conversion processes contain phenolic compounds in appreciable concentrations. These compounds need to be removed so that the water can be discharged or re-used. Catalytic oxidation in supercritical water is one potential means of treating coal-conversion wastewaters, and this project examined the reactions of phenol over different heterogeneous oxidation catalysts in supercritical water. More specifically, we examined the oxidation of phenol over a commercial catalyst and over bulk MnO(sub 2), bulk TiO(sub 2), and CuO supported on Al(sub 2) O(sub 3). We used phenol as the model pollutant because it is ubiquitous in coal-conversion wastewaters and there is a large database for non-catalytic supercritical water oxidation (SCWO) with which we can contrast results from catalytic SCWO. The overall objective of this research project is to obtain the reaction engineering information required to evaluate the utility of catalytic supercritical water oxidation for treating wastes arising from coal conversion processes. All four materials were active for catalytic supercritical water oxidation. Indeed, all four materials produced phenol conversions and CO(sub 2) yields in excess of those obtained from purely homogeneous, uncatalyzed oxidation reactions. The commercial catalyst was so active that we could not reliably measure reaction rates that were not limited by pore diffusion. Therefore, we performed experiments with bulk transition metal oxides. The bulk MnO(sub 2) and TiO(sub 2) catalysts enhance both the phenol disappearance and CO(sub 2) formation rates during SCWO. MnO(sub 2) does not affect the selectivity to CO(sub 2), or to the phenol dimers at a given phenol conversion. However, the selectivities to CO(sub 2) are increased and the selectivities to phenol dimers are decreased in the presence of TiO(sub 2) , which are desirable trends for a catalytic SCWO process. The role of the catalyst appears to be accelerating the rate of formation of

Coal summit II

Energy Technology Data Exchange (ETDEWEB)

1983-01-01

Various papers were presented on world coal trade. Papers include: Poland as a producer and exporter of coal; the dynamics of world coal trade; Cerrejon coal production perspectives; present state of the Australian coal industry; present state of the EC coal market and future prospects; prospects of US coal exports to Europe; forecast of Italian coal supply and demand through 1990; statistics from coal transportation outlook; status of world coal ports.

Cooperative research program in coal liquefaction. Quarterly report, May 1, 1993--October 31, 1993

Energy Technology Data Exchange (ETDEWEB)

Hoffman, G.P. [ed.

1994-07-01

This report summarizes progress in four areas of research under the general heading of Coal Liquefaction. Results of studies concerning the coliquefaction of coal with waste organic polymers or chemical products of these polymers were reported. Secondly, studies of catalytic systems for the production of clean transportation fuels from coal were discussed. Thirdly, investigations of the chemical composition of coals and their dehydrogenated counterparts were presented. These studies were directed toward elucidation of coal liquefaction processes on the chemical level. Finally, analytical methodologies developed for in situ monitoring of coal liquefaction were reported. Techniques utilizing model reactions and methods based on XAFS, ESR, and GC/MS are discussed.

Management of coal combustion wastes

Energy Technology Data Exchange (ETDEWEB)

NONE

2014-02-01

It has been estimated that 780 Mt of coal combustion products (CCPs) were produced worldwide in 2010. Only about 53.5% were utilised, the rest went to storage or disposal sites. Disposal of coal combustion waste (CCW) on-site at a power plant may involve decades-long accumulation of waste, with hundreds of thousands, if not millions, of tonnes of dry ash or wet ash slurry being stored. In December 2008, a coal combustion waste pond in Kingston, Tennessee, USA burst. Over 4 million cubic metres of ash sludge poured out, burying houses and rivers in tonnes of toxic waste. Clean-up is expected to continue into 2014 and will cost $1.2 billion. The incident drew worldwide attention to the risk of CCW disposal. This caused a number of countries to review CCW management methods and regulations. The report begins by outlining the physical and chemical characteristics of the different type of ashes generated in a coal-fired power plant. The amounts of CCPs produced and regulations on CCW management in selected countries have been compiled. The CCW disposal methods are then discussed. Finally, the potential environmental impacts and human health risks of CCW disposal, together with the methods used to prevent them, are reviewed.

Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

Energy Technology Data Exchange (ETDEWEB)

Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

1982-01-01

This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

Quantitative Modelling of Trace Elements in Hard Coal.

Science.gov (United States)

Smoliński, Adam; Howaniec, Natalia

2016-01-01

The significance of coal in the world economy remains unquestionable for decades. It is also expected to be the dominant fossil fuel in the foreseeable future. The increased awareness of sustainable development reflected in the relevant regulations implies, however, the need for the development and implementation of clean coal technologies on the one hand, and adequate analytical tools on the other. The paper presents the application of the quantitative Partial Least Squares method in modeling the concentrations of trace elements (As, Ba, Cd, Co, Cr, Cu, Mn, Ni, Pb, Rb, Sr, V and Zn) in hard coal based on the physical and chemical parameters of coal, and coal ash components. The study was focused on trace elements potentially hazardous to the environment when emitted from coal processing systems. The studied data included 24 parameters determined for 132 coal samples provided by 17 coal mines of the Upper Silesian Coal Basin, Poland. Since the data set contained outliers, the construction of robust Partial Least Squares models for contaminated data set and the correct identification of outlying objects based on the robust scales were required. These enabled the development of the correct Partial Least Squares models, characterized by good fit and prediction abilities. The root mean square error was below 10% for all except for one the final Partial Least Squares models constructed, and the prediction error (root mean square error of cross-validation) exceeded 10% only for three models constructed. The study is of both cognitive and applicative importance. It presents the unique application of the chemometric methods of data exploration in modeling the content of trace elements in coal. In this way it contributes to the development of useful tools of coal quality assessment.

Semiconductor electrochemistry of coal pyrite. Final technical report, September 1990--September 1995

Energy Technology Data Exchange (ETDEWEB)

Osseo-Asare, K.; Wei, D.

1996-01-01

This project is concerned with the physiochemical processes occuring at the pyrite/aqueous interface, in the context of coal cleaning, desulfurization, and acid mine drainage. The use of synthetic particles of pyrite as model electrodes to investigate the semiconductor electrochemistry of pyrite is employed.

Prospects for recovering gallium from extracted coal

Energy Technology Data Exchange (ETDEWEB)

Ratynskiy, V M; Reznik, A M; Zekel, L A; Zharov, Yu N

1979-01-01

The authors conducted research in order to establish the physical-chemical mechanisms governing the behavior of rare and dispersed elements within the thermal treatment processes used to treat coal and enrichment waste. New means are proposed for obtaining concentrations of gallium. These methods are under consideration primarily for the isolation of gallium as a by-product during the production of aggloporite from coal waste. The authors examine in detail the results of research dealing with the transfer of gallium compounds in a solution, the extraction of gallium from solutions, the separation of impurities from gallium, and the isolation of gallium from extract. Utilizing research results, the authors determine the expenditure coefficient and costs for additives used to extract gallium from waste by-products. The realization of this gallium extraction process from those products having the best prospects for gallium content resulted in economic savings.

Quantitative characterization of pulverized coal and biomass–coal blends in pneumatic conveying pipelines using electrostatic sensor arrays and data fusion techniques

International Nuclear Information System (INIS)

Qian, Xiangchen; Wang, Chao; Yan, Yong; Shao, Jiaqing; Wang, Lijuan; Zhou, Hao

2012-01-01

Quantitative data about the dynamic behaviour of pulverized coal and biomass–coal blends in fuel injection pipelines allow power plant operators to detect variations in fuel supply and oscillations in the flow at an early stage, enable them to balance fuel distribution between fuel feeding pipes and ultimately to achieve higher combustion efficiency and lower greenhouse gas emissions. Electrostatic sensor arrays and data fusion algorithms are combined to provide a non-intrusive solution to the measurement of fuel particle velocity, relative solid concentration and flow stability under pneumatic conveying conditions. Electrostatic sensor arrays with circular and arc-shaped electrodes are integrated in the same sensing head to measure ‘averaged’ and ‘localized’ characteristics of pulverized fuel flow. Data fusion techniques are applied to optimize and integrate the results from the sensor arrays. Experimental tests were conducted on the horizontal section of a 150 mm bore pneumatic conveyor circulating pulverized coal and sawdust under various flow conditions. Test results suggest that pure coal particles travel faster and carry more electrostatic charge than biomass–coal blends. As more biomass particles are added to the flow, the overall velocity of the flow reduces, the electrostatic charge level on particles decreases and the flow becomes less stable compared to the pure coal flow. (paper)

Quantitative characterization of pulverized coal and biomass-coal blends in pneumatic conveying pipelines using electrostatic sensor arrays and data fusion techniques

Science.gov (United States)

Qian, Xiangchen; Yan, Yong; Shao, Jiaqing; Wang, Lijuan; Zhou, Hao; Wang, Chao

2012-08-01

Quantitative data about the dynamic behaviour of pulverized coal and biomass-coal blends in fuel injection pipelines allow power plant operators to detect variations in fuel supply and oscillations in the flow at an early stage, enable them to balance fuel distribution between fuel feeding pipes and ultimately to achieve higher combustion efficiency and lower greenhouse gas emissions. Electrostatic sensor arrays and data fusion algorithms are combined to provide a non-intrusive solution to the measurement of fuel particle velocity, relative solid concentration and flow stability under pneumatic conveying conditions. Electrostatic sensor arrays with circular and arc-shaped electrodes are integrated in the same sensing head to measure ‘averaged’ and ‘localized’ characteristics of pulverized fuel flow. Data fusion techniques are applied to optimize and integrate the results from the sensor arrays. Experimental tests were conducted on the horizontal section of a 150 mm bore pneumatic conveyor circulating pulverized coal and sawdust under various flow conditions. Test results suggest that pure coal particles travel faster and carry more electrostatic charge than biomass-coal blends. As more biomass particles are added to the flow, the overall velocity of the flow reduces, the electrostatic charge level on particles decreases and the flow becomes less stable compared to the pure coal flow.

Synergistic Utilization of Coal Fines and Municipal Solid Waste in Coal-Fired Boilers. Phase I Final Report

Energy Technology Data Exchange (ETDEWEB)

V. Zamansky; P. Maly; M. Klosky

1998-06-12

A feasibility study was performed on a novel concept: to synergistically utilize a blend of waste coal fines with so-called E-fuel for cofiring and reburning in utility and industrial boilers. The E-fuel is produced from MSW by the patented EnerTech's slurry carbonization process. The slurry carbonization technology economically converts MSW to a uniform, low-ash, low-sulfur, and essentially chlorine-free fuel with energy content of about 14,800 Btu/lb.

Effects of coal-derived trace species on performance of molten carbonate fuel cells. Final report

Energy Technology Data Exchange (ETDEWEB)

1992-05-01

The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

Coal, an energy for the future: Energy transition - Promises difficult to be kept; Asset repurchasing - those who still believe in it; Technologies - in the pursuit of green coal; Interview 'Coal will still be here in 2040'

International Nuclear Information System (INIS)

Cognasse, Olivier; Delamarche, Myrtille; Dupin, Ludovic

2017-01-01

A first article evokes the recent evolution of world coal demand which is notably due to its ban in some European countries, and to its decrease in China for environmental reasons and in the USA for economic reasons (emergence of shale gas). However, the demand is still increasing in India, in South-East Asia and in Africa. The article also evokes the difficulties of banks and governments to implement their commitments to phase out coal, and outlines that some emerging countries are able to implement a better transition. As the main European energy utilities are committed in phasing out coal, a second article evokes various purchases of coal plants made by other actors (utilities or investors) in different countries. The third article proposes an overview of technological efforts and achievements to reduce CO_2 emissions by coal plants (super-critical and ultra-critical plants, projects of carbon capture and storage). The next article presents the case of the German RDK8 supercritical coal plant which, as other new German coal plants, implements new technologies to improve its efficiency. An article proposes an overview of the various carbon and particle emissions and water pollution associated with the different stages of coal use, from its extraction to its use in the most modern thermal plants. Finally, an expert comments in an interview the general trend of thermal coal, the shutting down of Chinese installations and the evolution of Chinese consumption, and expected evolutions in other Asian countries, in the USA and in Europe. She outlines that coal will still be present in 2040

Direct measurement of oxygen in brown coals and carbochemical products by means of fast neutron analysis

International Nuclear Information System (INIS)

Raeppel, P.; Foerster, H.

1990-01-01

Analyses of elemental oxygen by means of fast neutron activation permit high-accuracy measurements of oxygen concentrations in East German brown coal; this applies to run-of-mine brown coal as well as to demineralized brown coal. The relative error was 4% in the first case and 2% in the latter case. Pre-washing with 1n ammonium acetate solution permits direct analyses of the oxygen bonded to the coal minerals. The method is applicable to other carbonaceous materials, e.g. coal ashes, solid hydrogenation residues, cokes, coal extracts, asphaltenes, oils, etc., at oxygen concentrations of 1-50%. (orig.) [de

Coal-92

International Nuclear Information System (INIS)

Hillring, B.; Sparre, C.

1992-11-01

Swedish consumption of coal and coke during 1991 and trends in technology, environment and market aspects of coal use are reported. Steam coal use in the heating sector was unchanged from 1991, 1.2 Mtons. Reduced consumption in smaller district heating units (due to conversion to biofuels and gas) was compensated by increased use for power generation in cogeneration plants. Coal consumption in industry fell 0.10 Mton to 0.84 Mton due to lower production in one industry branch. Import of steam coal was 1.1 Mton (down 0.5 Mton from 1990) since new rules for strategic reserves allowed a reduction of stocks. During the last five years stocks have been reduced by 2 Mtons. Import of metallurgical coal was 1.6 Mton, unchanged from 1990. The report also gives statistics for the coal using plants in Sweden, on coal R and D, and on emission laws for coal firing. (9 tabs., 2 figs.)

Phosphorite ash in coal of certain beds of the Orzeskich (Zaleskich) layers. [Poland

Energy Technology Data Exchange (ETDEWEB)

Kuhl, J

1982-01-01

In ashes from coals of the Orzeskich (Zaleskich) layers, the variable content of P/sub 2/O/sub 5/ (0.4-1.15%) rises in an inverse proportion to the ash content of the coal. Chemical and mineral compositions of the ash in the coals of two levels of the mine ''Manifest Liptsovy'' are presented. The coal which yields phosphorite ash belongs to the type G. The phosphorus is mainly fruits and seeds of swamp plants. The smaller part of the phosphorus is formed by influx of terrigenous and volcanic material, as well as hydrothermal solutions.

A newer concept of setting up coal refineries in coal utilising industries through environmentally sound clean coal technology of organosuper refining of coals

International Nuclear Information System (INIS)

Sharma, D.K.

1994-01-01

In order to reduce the losses of premium organic matter of coal and its immense potential energy which is present in the form of stronger interatomic and intramolecular bonding energies, a newer and convenient technique of recovering the premium organic matter from low grade coals by organosuper-refining technique which operates under ambient pressure conditions has been developed. The residual coal obtained can be used as environmentally clean fuel or as a feedstock for the industries based on carbonization and gasification. It is suggested that a beginning be made by setting up coal refineries in coal utilizing industries on the basis of the presently developed new technology of organosuper-refining of coals to recover premium grade organic chemical feed stocks from coals before utilizing coal by techniques such as bubble bed or recirculatory fluidized bed or pulverized coal combustion in thermal power stations, carbonization in steel plants or other carbonization units, gasification in fertilizer industries or in integrated coal gasification combined cycle power generation. Thus, coal refineries may produce value added aromatic chemical feed stocks, formed coke or coke manufacturing; and carbon fillers for polymers. (author). 100 refs., 1 fig

Disposal of heavy metal cations in aqueous media by adsorption on coal to Ghazni

Directory of Open Access Journals (Sweden)

О.М. Заславський

2008-03-01

Full Text Available  Adsorption of Pb and Cu cations and their mixture on the surface of modified and non-modified anti-gas coal trough different time intervals have been studied. The maximum adsorption capacity of coal relative to each cations have been determined. Absence  of concurrence between cations of Pb and Cu during adsorption from mixture is explained by difference of  types of their interaction with coal surface. The high effectiveness and perspectivities of application of anti-gas coal for neutralization of heavy metal cations in aqueous solution was shown.

Effect of multiphase radiation on coal combustion in a pulverized coal jet flame

International Nuclear Information System (INIS)

Wu, Bifen; Roy, Somesh P.; Zhao, Xinyu; Modest, Michael F.

2017-01-01

The accurate modeling of coal combustion requires detailed radiative heat transfer models for both gaseous combustion products and solid coal particles. A multiphase Monte Carlo ray tracing (MCRT) radiation solver is developed in this work to simulate a laboratory-scale pulverized coal flame. The MCRT solver considers radiative interactions between coal particles and three major combustion products (CO 2 , H 2 O, and CO). A line-by-line spectral database for the gas phase and a size-dependent nongray correlation for the solid phase are employed to account for the nongray effects. The flame structure is significantly altered by considering nongray radiation and the lift-off height of the flame increases by approximately 35%, compared to the simulation without radiation. Radiation is also found to affect the evolution of coal particles considerably as it takes over as the dominant mode of heat transfer for medium-to-large coal particles downstream of the flame. To investigate the respective effects of spectral models for the gas and solid phases, a Planck-mean-based gray gas model and a size-independent gray particle model are applied in a frozen-field analysis of a steady-state snapshot of the flame. The gray gas approximation considerably underestimates the radiative source terms for both the gas phase and the solid phase. The gray coal approximation also leads to under-prediction of the particle emission and absorption. However, the level of under-prediction is not as significant as that resulting from the employment of the gray gas model. Finally, the effect of the spectral property of ash on radiation is also investigated and found to be insignificant for the present target flame. - Highlights: • A Monte Carlo–based nongray radiation solver is developed to study effects of radiation. • Radiation alters the lift-off height, and the distribution of temperature andspecies for the target flame. • Radiation alters the heat transfer mechanism of medium

Experimental Investigation of Coal Dust Wettability Based on Surface Contact Angle

Directory of Open Access Journals (Sweden)

Gang Zhou

2016-01-01

Full Text Available Wettability is one of the key chemical properties of coal dust, which is very important to dedusting. In this paper, the theory of liquid wetting solid was presented firstly; then, taking the gas coal of Xinglongzhuang coal mine in China as an example, by determination of critical surface tension of coal piece, it can be concluded that only when the surface tension of surfactant solution is less than 45 mN/m can the coal sample be fully wetted. Due to the effect of particle dispersity, compared with the contact angle of milled coal particle, not all the contact angles of screened coal powder with different sizes have a tendency to increase. Furthermore, by the experiments of coal samples’ specific surface areas and porosities, it can be achieved that the volume of single-point total pore decreases with the gradual decreasing of coal’s porosity, while the ultramicropores’ dispersities and multipoint BET specific surface areas increase. Besides, by a series of contact angle experiments with different surfactants, it can be found that with the increasing of porosity and the decreasing of volume percentage of ultramicropore, the contact angle tends to reduce gradually and the coal dust is much easier to get wetted.

Electrochemistry of carbonaceous materials; 1. Oxidation of Sardinian coal by Fe(III) ions

Energy Technology Data Exchange (ETDEWEB)

Tomat, R.; Salmaso, R.; Zecchin, S. (CNR-Instituto di Polarografia ed Elettrochimica Preparativa, Padova (Italy))

1992-04-01

Oxidation of subbitiminous coal (Sulcis basin, Sardinia, Italy) by Fe(III) ions in aqueous H{sub 2}SO{sub 4} solution was investigated over a wide temperature range (20-80{degree}C). Experimental results are in accord with a reaction scheme involving a reversible complex between coal particles and Fe(III) ions as a first step in the oxidation process. At low coal concentration, the reaction rate follows first-order kinetics in both coal and ferric ions (overall second order), while at sufficiently high coal concentration, the reaction rate is consistent with first-order kinetics in Fe(III) concentration, appearing to be independent of coal concentration. The kinetic results obtained give preliminary information on the advantageous use of the Fe(III)/slurried coal reaction system to depolarize the anodic compartment of an electrolysis cell, for the production of H{sub 2}. 11 refs., 5 figs.

PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS

Energy Technology Data Exchange (ETDEWEB)

Dady Dadyburjor; Philip R. Biedler; Chong Chen; L. Mitchell Clendenin; Manoj Katakdaunde; Elliot B. Kennel; Nathan D. King; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

2004-08-31

economically competitive with current processes, and yet be environmentally friendly as well. The solvent extraction process developed uses mild hydrogenation of low cost oils to create powerful solvents that can dissolve the organic portion of coal. The insoluble portion, consisting mainly of mineral matter and fixed carbon, is removed via centrifugation or filtration, leaving a liquid solution of coal chemicals and solvent. This solution can be further refined via distillation to meet specifications for products such as synthetic pitches, cokes, carbon foam and fibers. The most economical process recycles 85% of the solvent, which itself is obtained as a low-cost byproduct from industrial processes such as coal tar or petroleum refining. Alternatively, processes have been developed that can recycle 100% of the solvent, avoiding any need for products derived from petroleum or coal tar.

Cyclone reburn using coal-water fuel: Pilot-scale development and testing. Final report

Energy Technology Data Exchange (ETDEWEB)

Eckhart, C.F.; DeVault, R.F.

1991-10-01

There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

Predicted coal production trends in Kentucky: The results of available coal resources, coal quality demands, and regulatory factors

International Nuclear Information System (INIS)

Watson, W.D.

1993-01-01

Many factors affect the viability of regional coal production markets including (1) coal quality and recoverable tonnage, (2) coal mining cost, (3) the regional and time varying patterns of coal demand growth, (4) regulations and other institutional constraints that affect coal demand and utilization, and (5) the regional array of coal transport modes and rates. This analysis integrates these factors into an assessment of coal production prospects (separately) for eastern and western Kentucky coal producing counties for the decade of the 90's. The integration indicates that eastern Kentucky coal production will peak and begin to decline by the end of the decade whereas western Kentucky coal production will continue to grow. No single factor explains these trends. There is plenty of available minable coal. The combination of changes in environmental regulations, some increase in coal mining costs, and the mining-out of low sulfur reserves are the main factors that account for the production trends

Birth and first steps of mineral coal industry in the USA

International Nuclear Information System (INIS)

Martin-Amouroux, Jean-Marie

2015-10-01

The author proposes a brief history of the emergence of a mineral coal industry in the USA. He notices that wood has been the first source of energy used by settlers for housing heating, and then in industry and transports for heat and steam production. As demand and supply conditions were bad, coal production, although mining sites had been quickly identified and used, only emerged from the 1840's. Different kinds of coal (anthracite, bitumen) have been extracted depending on the region. Then, urbanisation and industrialisation created new opportunities for coal, and the share of coal regularly increased. The author describes how the coal industry was organised: seven regions, central position of Pittsburgh. He outlines the tremendous growth of coal production between 1840 and 1913; comments the distribution of this production among the different states. He describes and comments how this production has been industrialised. This industrialisation resulted in a dramatic increase of productivity between 1890 and 1910. He finally evokes the rather late creation of federal bodies

77 FR 5566 - Notice of Availability of the Final EIS for the HB In-Situ Solution Mine Project, Eddy County...

Science.gov (United States)

2012-02-03

...] Notice of Availability of the Final EIS for the HB In-Situ Solution Mine Project, Eddy County, New Mexico... Statement (Final EIS) for the HB In-Situ Solution Mine Project, and by this notice is announcing its... the Federal Register. ADDRESSES: Copies of the HB In-Situ Solution Mining EIS are available for public...

Variability of Mercury Content in Coal Matter From Coal Seams of The Upper Silesia Coal Basin

Science.gov (United States)

Wierzchowski, Krzysztof; Chećko, Jarosław; Pyka, Ireneusz

2017-12-01

The process of identifying and documenting the quality parameters of coal, as well as the conditions of coal deposition in the seam, is multi-stage and extremely expensive. The taking and analyzing of seam samples is the method of assessment of the quality and quantity parameters of coals in deep mines. Depending on the method of sampling, it offers quite precise assessment of the quality parameters of potential commercial coals. The main kind of seam samples under consideration are so-called "documentary seam samples", which exclude dirt bands and other seam contaminants. Mercury content in coal matter from the currently accessible and exploited coal seams of the Upper Silesian Coal Basin (USCB) was assessed. It was noted that the mercury content in coal seams decreases with the age of the seam and, to a lesser extent, seam deposition depth. Maps of the variation of mercury content in selected lithostratigraphic units (layers) of the Upper Silesian Coal Basin have been created.

Coal blending preparation for non-carbonized coal briquettes

Science.gov (United States)

Widodo; Fatimah, D.; Estiaty, L. M.

2018-02-01

Referring to the national energy policy targets for the years 2025, the government has launched the use of coal briquettes as an alternative energy replacement for kerosene and firewood. Non-carbonized briquettes in the form of coal briquettes as well as bio-coal briquettes are used in many small-medium industries and households, and are rarely used by large industries. The standard quality of coal briquettes used as raw material for non-carbonized briquettes is a minimum calorific value of 4,400 kcal/kg (adb); total sulfur at a maximum of 1% (adb), and water content at plants), the environment of deposition, and the geological conditions of the surrounding area, so that the coal deposits in each region will be different as well as the amount and also the quality. Therefore, the quantity and the quality of coal in each area are different to be eligible in the making of briquettes to do blending. In addition to the coal blending, it is also necessary to select the right materials in the making of coal briquettes and bio-coal briquettes. The formulation of the right mixture of material in the making of briquettes, can be produced of good quality and environmental friendly.

Late Cretaceous coal overlying karstic bauxite deposits in the Parnassus-Ghiona Unit, Central Greece: Coal characteristics and depositional environment

Energy Technology Data Exchange (ETDEWEB)

Kalaitzidis, Stavros; Siavalas, George; Christanis, Kimon [Dept. of Geology, University of Patras, 26504 Rio-Patras (Greece); Skarpelis, Nikos [Dept. of Geology and Geoenvironment, University of Athens, 15784 Zografou (Greece); Araujo, Carla Viviane [Petrobras-Cenpes GEOQ/PDEXP, Rua Horacio Macedo n 950, Cidade Universitaria - Ilha do Fundao, 21941-915 Rio de Janeiro (Brazil)

2010-04-01

The Pera-Lakkos coal located on top of bauxite deposits in the Ghiona mining district (Central Greece), is the only known Mesozoic (Late Cretaceous) coal in the country. It was derived from herbaceous plants and algae growing in mildly brackish mires that formed behind a barrier system during a regression of the sea, on a karstified limestone partly filled in with bauxitic detritus. Petrological, mineralogical and geochemical data point to the predominance of reducing conditions and intense organic matter degradation in the palaeomires. O/C vs. H/C and OI vs. HI plots, based on elemental analysis and Rock-Eval data, characterize kerogen types I/II. This reflects the relatively high liptinite content of the coal. Besides kerogen composition, O/C vs. H/C plot for the Pera-Lakkos coals is in accordance with a catagenesis stage of maturation in contrast with vitrinite reflectance and T{sub max} from Rock-Eval pyrolysis, which indicate the onset of oil window maturation stage. Suppression of vitrinite reflectance should be considered and the high liptinite content corroborates this hypothesis. Despite some favourable aspects for petroleum generation presented by the Pera-Lakkos coal, its maximum thickness (up to 50 cm) points to a restricted potential for petroleum generation. Coal oxidation took place either during the late stage of peat formation, due to wave action accompanying the subsequent marine transgression, or epigenetically after the emergence of the whole sequence due to percolation of drainage waters. Both options are also supported by the REE shale-normalized profiles, which demonstrate an upwards depletion in the coal layer. Oxidation also affected pyrite included in the coal; this led to the formation of acidic (sulfate-rich) solutions, which percolated downwards resulting in bleaching of the upper part of the underlying bauxite. (author)

Removal of chlorine from Illinois coal by high-temperature leaching: Final report, March 1--December 31, 1987

Energy Technology Data Exchange (ETDEWEB)

Chen, Han Lin

1988-03-01

The objectives of this research are to: (1) conduct experimental investigations of the removal of chlorine from coal by high- temperature leaching; (2) identify important factors affecting the chlorine removal process; (3) understand the mechanisms involved; and (4) develop a mathematical model to describe the process. A generalized mathematical model based on diffusion and relaxation has been developed for water leaching of chlorine from coal. The model has been fitted to four different samples of Illinois No. 6 coal: C22175, C22651, C8601, and C8602. The weight percent of chlorine ranged from 0.42 to 0.82. The experimental data on these samples covered a temperature range of 297 to 370K and a particle size range of 60 to 325 mesh. Based on the type of coal and the conditions of leaching, it was found that 40 to 80% of the original chlorine could be leached from the coal matrix. The model based on diffusion-relaxation concept predicted the leaching data within +-5% average absolute deviation. The diffusion rate constants at different temperatures were correlated to Arrhenius type relations. Attempts made to correlate the constants in the Arrhenius equations with the chlorine content in coal and with particle size have been discussed. The water leaching data were used to extract Fickian diffusivities based on the time required for 50% desorption. The calculated diffusivity values ranged from 0.6 to 3 /times/ 10/sup /minus/11/ cm/sup 2//sec. The effect of chemical additives on the rate of leaching has also been studied. Both HNO/sub 3/ and NH/sub 4/OH were used as additives. 28 refs., 3 figs., 7 tabs.

Firing a sub-bituminous coal in pulverized coal boilers configured for bituminous coals

Energy Technology Data Exchange (ETDEWEB)

N. Spitz; R. Saveliev; M. Perelman; E. Korytni; B. Chudnovsky; A. Talanker; E. Bar-Ziv [Ben-Gurion University of the Negev, Beer-Sheva (Israel)

2008-07-15

It is important to adapt utility boilers to sub-bituminous coals to take advantage of their environmental benefits while limiting operation risks. We discuss the performance impact that Adaro, an Indonesian sub-bituminous coal with high moisture content, has on opposite-wall and tangentially-fired utility boilers which were designed for bituminous coals. Numerical simulations were made with GLACIER, a computational-fluid-dynamic code, to depict combustion behavior. The predictions were verified with full-scale test results. For analysis of the operational parameters for firing Adaro coal in both boilers, we used EXPERT system, an on-line supervision system developed by Israel Electric Corporation. It was concluded that firing Adaro coal, compared to a typical bituminous coal, lowers NOx and SO{sub 2} emissions, lowers LOI content and improves fouling behavior but can cause load limitation which impacts flexible operation. 21 refs., 7 figs., 3 tabs.

Studying the dependence of quality of coal fine briquettes on technological parameters of their production

Directory of Open Access Journals (Sweden)

Т. Н. Александрова

2016-08-01

Full Text Available The study characterizes the role of coal in the fuel and energy balance of the Far East Region and points out the issue of losses of coal fines in the processes of coal mining, transportation and processing. To solve the problem of losses of coal fines, the mined coal is sorted into different size classes and fuel briquettes are produced from coal fines. Physical foundations are presented in short of briquetting solid combustible mineral resources. The dependences and variations of briquette compression strength limit are studied vs. charge humidity and briquetting pressure. Optimal parameters are retrieved for briquetting coal fines. The principal technological scheme is given of the process of briquette production. The developed technological solutions include sorting regular coal and briquetting coal fines, as well as the involvement of technogenic carbon-containing wastes from the hydrolysis production lines, plus residuals from oil refining.

Fuel production from microwave assisted pyrolysis of coal with carbon surfaces

International Nuclear Information System (INIS)

Mushtaq, Faisal; Mat, Ramli; Ani, Farid Nasir

2016-01-01

Highlights: • MW heating of coal was carried out with uniformly distributed carbon surfaces. • The effects of carbon loading, MW power and N 2 flow rate were investigated. • Heating profile, pyrolysis products are influenced by the process variables. • Highest coal-tar obtained when final temperature sustained for longer duration. • Coal-tar is mainly composed of aromatics and saturated aliphatics hydrocarbons. - Abstract: In this study, coal solids were subjected to Microwave (MW) pyrolysis conditions. Coconut Activated Carbon (CAC) solids used as a MW absorber was distributed uniformly over coal solids to reduce hotspots. Three process parameters; CAC loading, MW power and N 2 flow rate were studies on pyrolysis heating performance. The highest coal-tar yield of 18.59 wt% was obtained with 600 W, 75 wt% CAC loading and 4 Liter per Minute (LPM) of N 2 flow rate. This improved coal-tar yield is mainly of the fact that higher MW power and CAC loading produced sustained pyrolysis conditions for longer duration for the complete conversion of pyrolysis solids. The coal-tar was composed mainly of aromatics (naphthalenes, benzenes and xylene) and saturated aliphatics (alkanes and alkenes) hydrocarbons. The gas produced from pyrolysis of coal is mainly of H 2 40.23–65.22 vol%.

Geochemistry of coals, coal ashes and combustion wastes from coal-fired power stations

International Nuclear Information System (INIS)

Vassilev, S.V.; Vassileva, C.G.

1997-01-01

Contents, concentration trends, and modes of occurrence of 67 elements in coals, coal ashes, and combustion wastes at eleven Bulgarian thermoelectric power stations (TPS) were studied. A number of trace elements in coal and coal ash have concentrations greater than their respective worldwide average contents (Clarke values). Trace elements are concentrated mainly in the heavy accessory minerals and organic matter in coal. In decreasing order of significance, the trace elements in coal may occur as: element-organic compounds; impurities in the mineral matter; major components in the mineral matter; major and impurity components in the inorganic amorphous matter; and elements in the fluid constituent. A number of trace elements in the waste products, similar to coal ashes, exceed known Clarke contents. Trace elements are mainly enriched in non-magnetic, heavy and fine-grained fractions of fly ash. They are commonly present as impurities in the glass phases, and are included in the crystalline components. Their accessory crystalline phases, element-organic compounds, liquid and gas forms, are of subordinate importance. Some elements from the chalcophile, lithophile and siderophile groups may release into the atmosphere during coal burning. For others, the combustion process appears to be a powerful factor causing their relative enrichment in the fly ash and rarely in the bottom ash and slag. 65 refs., 1 fig., 11 tabs

Task 27 -- Alaskan low-rank coal-water fuel demonstration project

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-10-01

Development of coal-water-fuel (CWF) technology has to-date been predicated on the use of high-rank bituminous coal only, and until now the high inherent moisture content of low-rank coal has precluded its use for CWF production. The unique feature of the Alaskan project is the integration of hot-water-drying (HWD) into CWF technology as a beneficiation process. Hot-water-drying is an EERC developed technology unavailable to the competition that allows the range of CWF feedstock to be extended to low-rank coals. The primary objective of the Alaskan Project, is to promote interest in the CWF marketplace by demonstrating the commercial viability of low-rank coal-water-fuel (LRCWF). While commercialization plans cannot be finalized until the implementation and results of the Alaskan LRCWF Project are known and evaluated, this report has been prepared to specifically address issues concerning business objectives for the project, and outline a market development plan for meeting those objectives.

New coal

Energy Technology Data Exchange (ETDEWEB)

1979-07-01

Specially dedicated to coal, this edition comprises a series of articles of general interest dealing with the position of the French coalmining industry (interview with M.P. Gardent), the coal market in France, the work of CERCHAR, etc. New techniques, in-situ gasification of deep coal, gasification of coal by nuclear methods, the conversion of coal into petrol, the Emile Huchet power plant of Houilleres du Bassin de Lorraine, etc., are dealt with.

Coal briquetting at the presence of humates as the binding substance

Directory of Open Access Journals (Sweden)

Zh. Arziev

2013-09-01

Full Text Available The results of coal briquetting at the presence of humates derived from coal at the stage of its chemical preparation by the extraction method are resulted in the paper. The conditions of briquetting and strength characteristics of the received briquettes are optimized. It is demonstrated that briquettes with the durability reaching 3 MPa can be derived from a coal fines using sodium, ammonium and silicate humates as binding substance. Water solutions of ammonium, sodium and silicate humates with concentration from 0,1-2% can be recommended for practical purposes. It is recommended to expose coal briquettes on a basis of ammonium humate to the thermal treatment at temperature 200°C as necessary of long storage (more than a year. The technological scheme of briquetting and the working project of creation of briquette factory with productivity of 40 000 tons of coal per year are developed.

Biochemical removal of HAP precursors from coal. Quarterly technical progress report, April--June 1996

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-12-31

Analytical methods were finalized and all analyses completed on shake flask tests with Indiana No. 5 and Pittsburgh No. 8 coal. A column leaching-rotating biological contractor (RBC) unit was used to bioleach pyrite and hazardous air pollutant precursors from Pittsburgh No. 8 coal. Shake flask tests with Rosebud subbituminous coal were begun. In connection with upcoming slurry column reactor tests, coal was prepared and shipped to INEL, and a detailed work plan was developed for operation and sampling for the tests. A manuscript and poster was prepared for presentation at the PETC contractors conference.

The application of a coupled artificial neural network and fault tree analysis model to predict coal and gas outbursts

Energy Technology Data Exchange (ETDEWEB)

Ruilin, Zhang [School of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo, Henan Province, 454003, PR (China); Lowndes, Ian S. [Process and Environmental Research Division, Faculty of Engineering, University of Nottingham, University Park, Nottingham, NG7 2RD (United Kingdom)

2010-11-01

This paper proposes the use of a coupled fault tree analysis (FTA) and artificial neural network (ANN) model to improve the prediction of the potential risk of coal and gas outburst events during the underground mining of thick and deep Chinese coal seams. The model developed has been used to investigate the gas emission characteristics and the geological conditions that exist within the Huaibei coal mining region, Anhui province, China. The coal seams in this region exhibit a high incidence of coal and gas outbursts. An analysis of the results obtained from an initial application of an FTA model, identified eight dominant model parameters related to the gas content or geological conditions of the coal seams, which characterize the potential risk of in situ coal and gas outbursts. The eight dominant model parameters identified by the FTA method were subsequently used as input variables to an ANN model. The results produced by the ANN model were used to develop a qualitative risk index to characterize the potential risk level of occurrence of coal and gas outburst events. Four different potential risk alarm levels were defined: SAFE, POTENTIAL, HIGH and STRONG. Solutions to the prediction model were obtained using a combination of quantitative and qualitative data including the gas content or gas pressure and the geological and geotechnical conditions of coal seams. The application of this combined solution method identified more explicit and accurate model relationships between the in situ geological conditions and the potential risk of coal and gas outbursts. An analysis of the model solutions concluded that the coupled FTA and ANN model may offer a reliable alternative method to forecast the potential risk of coal and gas outbursts. (author)

Implications of Declining Enrolment for the Schools of Ontario. A Statement of Effects and Solutions. Final Report. [Incidences de la Baisse des Effectifs Scolaires sur les Ecoles de l'Ontario. Problemes et Solutions. Rapport Final].

Science.gov (United States)

Jackson, R. W. B.

In this final report concerning declining enrollments in Ontario, the problems are defined almost entirely in economic and financial terms, and the solutions expressed in those terms. The first section of the report briefly reviews the essential background, the economic and financial constraints, and finally the demographic facts. The arguments…

Black coal. Annual report 2002; Steinkohle. Jahresbericht 2002

Energy Technology Data Exchange (ETDEWEB)

NONE

2002-10-01

An overview is given of the situation of the world energy industry with regard to all energy carriers. Then energy-political conclusions are drawn for German black coal and the resulting prospects are detailed. Finally, some socio-political aspects are considered with regard to German black-coal mining. [German] Es wird eine Uebersicht ueber die Situation der Welt-Energiewirtschaft unter Beruecksichtigung aller Energietraeger gegeben. Anschliessend werden die energiepolitischen Folgerungen fuer die deutsche Steinkohle gezogen, und es werden die resultierenden Perspektiven erlaeutert. Abschliessend werden einige sozialpolitische Aspekte bezueglich des deutschen Steinkohlenbergbaus behandelt.

Industrial use of coal and clean coal technology

Energy Technology Data Exchange (ETDEWEB)

Leibson, I; Plante, J J.M.

1990-06-01

This report builds upon two reports published in 1988, namely {ital The use of Coal in the Industrial, Commercial, Residential and Transportation Sectors} and {ital Innovative Clean Coal Technology Deployment}, and provides more specific recommendations pertaining to coal use in the US industrial sector. The first chapter addresses industrial boilers which are common to many industrial users. The subsequent nine chapters cover the following: coke, iron and steel industries; aluminium and other metals; glass, brick, ceramic, and gypsum industries; cement and lime industries; pulp and paper industry; food and kindred products; durable goods industry; textile industry; refining and chemical industry. In addition, appendices supporting the contents of the study are provided. Each chapter covers the following topics as applicable: energy overview of the industry sector being discussed; basic processes; foreign experience; impediments to coal use; incentives that could make coal a fuel of choice; current and projected use of clean coal technology; identification of coal technology needs; conclusions; recommendations.

Refining and end use study of coal liquids II - linear programming analysis

Energy Technology Data Exchange (ETDEWEB)

Lowe, C.; Tam, S.

1995-12-31

A DOE-funded study is underway to determine the optimum refinery processing schemes for producing transportation fuels that will meet CAAA regulations from direct and indirect coal liquids. The study consists of three major parts: pilot plant testing of critical upgrading processes, linear programming analysis of different processing schemes, and engine emission testing of final products. Currently, fractions of a direct coal liquid produced form bituminous coal are being tested in sequence of pilot plant upgrading processes. This work is discussed in a separate paper. The linear programming model, which is the subject of this paper, has been completed for the petroleum refinery and is being modified to handle coal liquids based on the pilot plant test results. Preliminary coal liquid evaluation studies indicate that, if a refinery expansion scenario is adopted, then the marginal value of the coal liquid (over the base petroleum crude) is $3-4/bbl.

Thermal dynamic analysis of sulfur removal from coal by electrolysis

Energy Technology Data Exchange (ETDEWEB)

Li, D.; Gao, J.; Meng, F. [Qinghua University, Beijing (China). Dept. of Thermal Engineering

2002-06-01

The electrolytic reactions about sulfur removal from coal were studied by using chemical thermal dynamic analysis. According to the thermodynamical data, the Gibbs free energy value of the electrolytic reactions of pyritic and organic sulfur removal from coal is higher than zero. So, these electrolytic reactions are not spontaneous chemical reactions. In order to carry out desulfurisation by electrolysis, a certain voltage is necessary and important. Because theoretic decomposition voltage of pyrite and some parts of organic sulfur model compound is not very high, electrolysis reactions are easily to be carried out by using electrolysis technology. Mn ion and Fe ion are added into electrolysis solutions to accelerate the desulfurisation reaction. The electrolytic decomposition of coal is discussed. Because the theoretical decomposition voltage of some organic model compound is not high, the coal decomposition might happen. 17 refs., 4 tabs.

Automatic crack detection method for loaded coal in vibration failure process.

Directory of Open Access Journals (Sweden)

Chengwu Li

Full Text Available In the coal mining process, the destabilization of loaded coal mass is a prerequisite for coal and rock dynamic disaster, and surface cracks of the coal and rock mass are important indicators, reflecting the current state of the coal body. The detection of surface cracks in the coal body plays an important role in coal mine safety monitoring. In this paper, a method for detecting the surface cracks of loaded coal by a vibration failure process is proposed based on the characteristics of the surface cracks of coal and support vector machine (SVM. A large number of cracked images are obtained by establishing a vibration-induced failure test system and industrial camera. Histogram equalization and a hysteresis threshold algorithm were used to reduce the noise and emphasize the crack; then, 600 images and regions, including cracks and non-cracks, were manually labelled. In the crack feature extraction stage, eight features of the cracks are extracted to distinguish cracks from other objects. Finally, a crack identification model with an accuracy over 95% was trained by inputting the labelled sample images into the SVM classifier. The experimental results show that the proposed algorithm has a higher accuracy than the conventional algorithm and can effectively identify cracks on the surface of the coal and rock mass automatically.

Economic evaluation of coal deposits. Ekonomicheskaya otsenka ugolinykh mestorozhdenii

Energy Technology Data Exchange (ETDEWEB)

Raikhel' , B L

1979-01-01

A presentation is made of theoretical problems, methods, and criteria for the economic evaluation of coal deposits. An examination is made of factors which influence the formation of magnitudes that are utilized in economic evaluations as well as problems whose solution requires the consideration of the economic evaluation of coal deposits (evaluation of useful mineral losses, substantiation for the extraction of reserves under various conditions, sectioning off reserves to an operating mine, the completeness of reserve extraction, and technico-economic substantiation for quality). Extensive experience in planning is summarized and data are illustrated by examples. The book is intended for engineering-technical personnel of enterprises, organizations, planning, and scientific-research institutes of the coal industry as well as geological organizations. 29 references, 27 tables.

Effect of hydrothermal dewatering on the slurryability of brown coals

International Nuclear Information System (INIS)

Yu Yujie; Liu Jianzhong; Wang Ruikun; Zhou Junhu; Cen Kefa

2012-01-01

Highlights: ► Brown coals are upgraded by hydrothermal dewatering. ► The moisture content and oxygen functional groups decrease during the process. ► The point of zero charge and the contact angle rise as the temperature increases. ► The products were highly hydrophobic. ► The improvement on slurryability of solid products were examined. - Abstract: Two brown coals from China were dewatered under hydrothermal dewatering (HTD) conditions at 250–320 °C for 1 h in a 2 L autoclave. The hydrothermally dewatered products were used to prepare coal water slurry (CWS) with a lower viscosity than brown raw coal slurry. Moreover, the coal rank and heat value of the brown coal increased as the inherent moisture and oxygen content decreased during the HTD process. The maximum solid concentration of CWS prepared from XiMeng coal increased from 45.7% to 59.3%, whereas that of CWS prepared from BaoTou coal increased from 53.7% to 62.1%, after being dewatered at 320 °C. The improvement in the slurryability of brown coal significantly depended on the final temperature of the HTD process, the mechanism of which can be explained by the chemical analysis of oxygen functional groups, zeta potential, and the contact angle of the surface between coal and water. The oxygen functional groups, the oxygen/carbon ratio and hydrogen/carbon ratio in brown coal decreased, indicating that the coal rank was upgraded during the HTD process. As a result, both the point of zero charge and the contact angle increased, implying that the HTD products were highly hydrophobic.

Sustainable global energy development: The case of coal

International Nuclear Information System (INIS)

Brendow, Klaus

2004-01-01

. Even more expensive advanced clean coal combustion technologies could noticeably displace gas-fired combined cycle plants in regions with 'reasonably cheap gas prices' (EU) at regimes higher than 6500 h/year and even 4500 h/year. The worldwide replacement of old coal power plants by advanced coal combustion technologies would reduce world CO 2 emissions by 7 - 8 %. For the next decade or more, advanced clean coal combustion may well be the most effective single technology option to combat climate change, bridging the time for coal sequestration to gain maturity. Carbon sequestration in integrated multi-product chemical refineries - the next step - and carbon disposal are the subject of intense research. Against these realities and perspectives, coal's image remained poor. The global coal and associated industries would be well advised to join forces in a proactive campaign highlighting the potential of sustainable development from coal. Acceptance by the public and more balanced policies are at that price. Coal is not part of the problem of sustainability and energy poverty, but part of the solution. (author)

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

Energy Technology Data Exchange (ETDEWEB)

Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

2001-12-01

The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

Potential growth of nuclear and coal electricity generation in the US

International Nuclear Information System (INIS)

Bloomster, C.H.; Merrill, E.T.

1989-08-01

Electricity demand should continue to grow at about the same rate as GNP, creating a need for large amounts of new generating capacity over the next fifty years. Only coal and nuclear at this time have the abundant domestic resources and assured technology to meet this need. However, large increase in both coal and nuclear usage will require solutions to many of the problems that now deter their increased usage. For coal, the problems center around the safety and environmental impacts of increased coal mining and coal combustion. For nuclear, the problems center around reactor safety, radioactive waste disposal, financial risk, and nuclear materials safeguards. This report assesses the impacts associated with a range of projected growth rates in electricity demand over the next 50 years. The resource requirements and waste generation resulting from pursuing the coal and nuclear fuel options to meet the projected growth rates are estimated. The fuel requirements and waste generation for coal plants are orders of magnitude greater than for nuclear. Improvements in technology and waste management practices must be pursued to mitigate environmental and safety concerns about electricity generation from both options. 34 refs., 18 figs., 14 tabs

Extraction of Coal and Gangue Geometric Features with Multifractal Detrending Fluctuation Analysis

Directory of Open Access Journals (Sweden)

Kai Liu

2018-03-01

Full Text Available The separation of coal and gangue is an important process of the coal preparation technology. The conventional way of manual selection and separation of gangue from the raw coal can be replaced by computer vision technology. In the literature, research on image recognition and classification of coal and gangue is mainly based on the grayscale and texture features of the coal and gangue. However, there are few studies on characteristics of coal and gangue from the perspective of their outline differences. Therefore, the multifractal detrended fluctuation analysis (MFDFA method is introduced in this paper to extract the geometric features of coal and gangue. Firstly, the outline curves of coal and gangue in polar coordinates are detected and achieved along the centroid, thereby the multifractal characteristics of the series are analyzed and compared. Subsequently, the modified local singular spectrum widths Δ h of the outline curve series are extracted as the characteristic variables of the coal and gangue for pattern recognition. Finally, the extracted geometric features by MFDFA combined with the grayscale and texture features of the images are compared with other methods, indicating that the recognition rate of coal gangue images can be increased by introducing the geometric features.

Accumulation of dissolved gases at hydrophobic surfaces in water and sodium chloride solutions: Implications for coal flotation

Energy Technology Data Exchange (ETDEWEB)

Hampton, M.A.; Nguyen, A.V. [University of Queensland, Brisbane, Qld. (Australia). Division of Chemical Engineering

2009-08-15

Dissolved gases can preferentially accumulate at the hydrophobic solid-water interface as revealed by neutron reflectivity measurements. In this paper, atomic force microscopy (AFM) was used to examine accumulation of dissolved gases at a hydrophobic surface in water and sodium chloride solutions. The solvent-exchange method was used to artificially form gaseous domains accumulated at the interface suitable for AFM imaging. Smooth graphite surfaces were used as model surfaces to minimize the secondary effect of surface roughness on the imaging. The concentration of NaCl up to 1 M was found to have a negligible influence on the geometry and population of pre-existing nanobubbles, nanopancakes and nanobubble-nanopancake composites. The implications of the findings on coal flotation in saline water are discussed in terms of attraction between hydrophobic surfaces in water, bubble-particle attachment and hydrophobic coagulation between particles.

The world behind electricity from coal. The dubious origin of coal for Dutch coal-fired power plants

International Nuclear Information System (INIS)

2008-01-01

Five energy companies in the Netherlands want to build additional coal-fired power plants: Essent and Nuon, the German company RWE and E.ON and the Belgian company Electrabel. Coal-fired power plants emit 70 percent more CO2 than gas-fired power plants. Especially because of the threat to the climate Greenpeace believes that no more coal-fired power plants should be built. In this publication Greenpeace explores the pollution, the working conditions and human rights with regard to the exploitation of coal. That has been elaborated for the three countries from which Dutch energy companies import coal: South Africa, Colombia and Indonesia. In addition to information about the origin of coal also insight is given into the coal market (stocks and use), the enormous coal transport and the world trade [nl

Coal refuse reclamation project

Energy Technology Data Exchange (ETDEWEB)

Zellmer, S.D.

1979-04-06

A 13.8 ha abandoned coal refuse site in southwestern Illinois was reclaimed by recontouring the refuse material and covering it with a minimum 30 cm of soil. The reclamation procedure included determination of the site's final land use, collection of preconstruction environmental data, and development and implementation of engineering plans. The project is demonstrating methods that can be used to reclaim abandoned coal refuse sites, and a multidisciplinary approach is being used to evaluate postconstruction environmental and economic effects of the reclamation effort. Surface water quality has shown significant improvement and plant cover is becoming established on the site. Soil microbial populations are developing and wildlife habitats are forming. The economic value of the site and adjacent properties has increased substantially and the area's aesthetic value has been enhanced. This project is providing valuable design data for future reclamation efforts of this type.

Analysis of radionuclides in airborne effluents from coal-fired power plants

Energy Technology Data Exchange (ETDEWEB)

Rosner, G.; Chatterjee, B.; Hoetzl, H.; Winkler, R.

1982-01-01

In order to assess the level of radioactivity emitted by coal-fired power plants in detail, specific activities of several radionuclides have been measured in samples from a coal-fired and a brown coal-fired plant in the Federal Republic of Germany. Samples measured included coal, brown coal, bottom ash, collected fly ash from the various electrostatic precipitator stages and sieve fractions of collected fly ash as well as samples of escaping fly ash taken from the exhaust stream, all taken simultaneously on three operating days. Nuclides measured were U-238, U-234, Th-232, Th-230, Th-228, Ra-226, Pb-210, Po-210 and K-40. Methods applied included (i) direct gamma spectrometry, (ii) radiochemical separation with subsequent alpha spectrometry and (iii) direct alpha spectrometry. Methods are described and discussed. Finally, annual emission rates of airborne radionuclides are calculated for both plants.

Analysis of radionuclides in airborne effluents from coal-fired power plants

International Nuclear Information System (INIS)

Rosner, G.; Chatterjee, B.; Hoetzl, H.; Winkler, R.

1982-01-01

In order to assess the level of radioactivity emitted by coal-fired power plants in detail, specific activities of several radionuclides have been measured in samples from a coal-fired and a brown coal-fired plant in the Federal Republic of Germany. Samples measured included coal, brown coal, bottom ash, collected fly ash from the various electrostatic precipitator stages and sieve fractions of collected fly ash as well as samples of escaping fly ash taken from the exhaust stream, all taken simultaneously on three operating days. Nuclides measured were U-238, U-234, Th-232, Th-230, Th-228, Ra-226, Pb-210, Po-210 and K-40. Methods applied included (i) direct gamma spectrometry, (ii) radiochemical separation with subsequent alpha spectrometry and (iii) direct alpha spectrometry. Methods are described and discussed. Finally, annual emission rates of airborne radionuclides are calculated for both plants. (orig.)

Assessment of coal and ash environmental impact with the use of gamma- and X-ray spectrometry

International Nuclear Information System (INIS)

Kierzek, J.; Malozewska-Bucko, B.; Bukowski, P.; Parus, J.L.; Ciurapisnki, A.; Zaras, S.; Kunach, B.; Wiland, K.

1999-01-01

Gamma-ray spectrometry (GS), energy dispersive X-ray fluorescence (EDXRF) analysis methods and wavelength dispersive X-ray fluorescence (WDXRF) were applied for the studies of some coal components, e.g., sulphur, light and heavy metal element concentrations and naturally occurring radioactive isotope contents. Hundred fifty coal samples originating mostly from eight different coal mines from Upper Silesian Coal Basin and 150 samples of ash obtained from these coal samples in laboratory by total combustion at final temperature of 820 deg C, were analyzed. Such comparative analyses can be helpful in selection of most suitable kind of coal for burning in electrical power and heat plants to minimize the environmental pollution. (author)

Environmental indicators of the combustion of prospective coal water slurry containing petrochemicals.

Science.gov (United States)

Dmitrienko, Margarita A; Nyashina, Galina S; Strizhak, Pavel A

2017-09-15

Negative environmental impact of coal combustion has been known to humankind for a fairly long time. Sulfur and nitrogen oxides are considered the most dangerous anthropogenic emissions. A possible solution to this problem is replacing coal dust combustion with that of coal water slurry containing petrochemicals (CWSP). Coal processing wastes and used combustible liquids (oils, sludge, resins) are promising in terms of their economic and energy yield characteristics. However, no research has yet been conducted on the environmental indicators of fuels based on CWSP. The present work contains the findings of the research of CO, CO2, NOx, SOx emissions from the combustion of coals and CWSPs produced from coal processing waste (filter cakes). It is demonstrated for the first time that the concentrations of dangerous emissions from the combustion of CWSPs (carbon oxide and dioxide), even when combustible heavy liquid fractions are added, are not worse than those of coal. As for the concentration of sulfur and nitrogen oxides, it is significantly lower for CWSPs combustion as compared to coals. The presented research findings illustrate the prospects of the wide use of CWSPs as a fuel that is cheap and beneficial, in terms of both energy output and ecology, as compared to coal. Copyright © 2017 Elsevier B.V. All rights reserved.

Meeting of Commission of International Committee on Petrology of Coals

Energy Technology Data Exchange (ETDEWEB)

Timofeev, P P; Bogolyubova, L I

1982-03-01

In Urbana, Illinois from 18-20 May 1979 the XXXII session of the International Committee on Petrology met. Reports were made on standards for the study of bituminous and anthracite coals. Use of reflective capacity of vitrain to determine coalification of coals was discussed along with a proposition to establish numerical boundaries between brown, bituminous and anthracite coals. The re-editing of the International Dictionary on Petrology of Coals was agreed upon in view of new facts on microcomponents of coal and methods of studying them. The next meeting of the Commission took place at Ostrav, Czechoslovakia from 14-26 April 1980. At the plenary session, new officials were elected and agreement to re-edit the Dictionary on Petrology of Coals was confirmed. At the meeting of the Commission on Coal Petrography the question of the determination of components of coal by quantitative diagnosis, and results of determining components of vitrain by measuring its reflective capacity were reported on. At the meeting of the Committee on Applying Facts of Petrology in Geology, the classification of solid oil bitumen and organic substance of sediments was discussed. At the meeting of the Committee on the Application of the Petrology of Coals in Industry, attention was given to discussing basic parameters for the international classification of coals to be presented at the meeting of the Economic Commission of Europe in Geneva. In the final plenary session of the commission, results of discussions were summarized. The next session was to be held in France in 1981. (In Russian)

Coal information 1995

International Nuclear Information System (INIS)

1996-01-01

This volume is a comprehensive reference book on current world coal market trends and long-term prospects to 2010. It contains an in-depth analysis of the 1995 international coal market covering prices, demand, trade, supply and production capacity as well as over 450 pages of country specific statistics on OECD and key non-OECD coal producing and consuming countries. The book also includes a summary of environmental policies on climate change and on coal-related air quality issues as well as essential facts on coal-fired power stations in coal-importing regions, on coal ports world-wide and on emission standards for coal-fired boilers in OECD countries. Coal Information is one of a series of annual IEA statistical publications on major energy sources; other reports are Oil and Gas Information and Electricity Information. Coal Information 1995 is published in July 1996. (author)

The come back of liquid coal

International Nuclear Information System (INIS)

Caulier, S.

2010-01-01

The coal-to-liquid (CTL) process has made important progresses and is now perfectly mastered by the South-African company Sasol. At least 6 CTL facilities are under construction in China. Each will produce 80000 barrels/day of diesel fuel and the production is planned to start up by 2017 or 2018. The CTL process is profitable when the oil barrel price exceeds 100 US$ but it depends also of the coal price. However, the process itself is highly energy consuming and also highly polluting with strong CO 2 emissions. A solution to these drawbacks would come from the implementation of poly-generation (separate generation of energy, electricity and heat), and from the use of a combined cycle with integrated gasification. (J.S.)

Regulations implementing the Byrd Amendments to the Black Lung Benefits Act: determining coal miners' and survivors' entitlement to benefits. Final rule.

Science.gov (United States)

2013-09-25

This final rule revises the Black Lung Benefits Act (BLBA or Act) regulations to implement amendments made by the Patient Protection and Affordable Care Act (ACA). The ACA amended the BLBA in two ways. First, it revived a rebuttable presumption of total disability or death due to pneumoconiosis for certain claims. Second, it reinstituted automatic entitlement to benefits for certain eligible survivors of coal miners whose lifetime benefit claims were awarded because they were totally disabled due to pneumoconiosis. These regulations clarify how the statutory presumption may be invoked and rebutted and the application and scope of the survivor-entitlement provision. The rule also eliminates several unnecessary or obsolete provisions.

The clean coal technologies for lignitic coal power generation in Pakistan

International Nuclear Information System (INIS)

Mir, S.; Raza, Z.; Aziz-ur-Rehman, A.

1995-01-01

Pakistan contains huge reserves of lignitic coals. These are high sulphur, high ash coals. In spite of this unfortunate situation, the heavy demand for energy production, requires the development utilization of these indigenous coal reserves to enhance energy production. The central of the environmental pollution caused by the combustion of these coals has been a major hindrance in their utilization. Recently a substantial reduction in coal combustion emissions have been achieved through the development of clean coal technologies. Pakistan through the transfer and adaptation of the advanced clean coal technologies can utilize incurring the high sulphur coals for energy production without incurring the environmental effects that the developed countries have experienced in the past. The author discusses the recently developed clean coal utilization technologies, their applications economies and feasibility of utilization with specific reference to Pakistan''s coal. (author)

Coal information 1996

International Nuclear Information System (INIS)

1997-01-01

Coal Information (1997 edition) is the latest edition of a publication that has been produced annually by the IEA since 1983. The report is intended to provide both Member countries of the OECD and those employed in all sectors of the coal industry with information on current world coal market trends and long-term prospects. It includes information on coal prices, demand, trade, supply, production capacity, transport, environmental issues (including emission standards for coal-fired boilers), coal ports, coal-fired power stations and coal used in non -OECD countries. Part I of the publication contains a wide ranging review of world coal market developments in 1996 and current prospects to 2010. The review is based on historical data of OECD energy supply and demand, data on other world regions, projections of OECD coal supply, demand and trade and information provided by the CIAB. Part II provides, in tabular and graphical form, a more detailed and comprehensive statistical picture of coal developments and future prospects for coal in the OECD, by region and for individual Member countries. Readers interested in projections are strongly advised to read the notes for individual countries in Principles and Definitions in Part II. Coal statistics for non-OECD countries are presented in Part III of the book. Summary data are available on hard coal supply and end-use statistics for about 40 countries and regions world-wide. Data are based on official national submissions to the United Nations in Geneva and New York, national energy publications, information provided to the IEA Secretariat by national statistical offices as well as other unofficial Secretariat sources. Further information on coal used in non-OECD countries is published annually by the IEA in Energy Statistics and Balances of Non-OECD Countries. Also included in Part III are the Survey of Coal Ports world-wide and the Survey of Coal-fired Power Stations in coal-importing countries

Environmental evaluation for sustainable development of coal mining in Qijiang, Western China

Energy Technology Data Exchange (ETDEWEB)

Si, Hu; Bi, Haipu [College of Resource and Environment Science, Chongqing University, Chongqing 400030 (China); Key Lab for the Exploitation of Southwestern Resource and the Environment Disaster Control Engineering, the Ministry of Education, Chongqing University, Chongqing 400030 (China); Li, Xiaohong; Yang, Chunhe [Key Lab for the Exploitation of Southwestern Resource and the Environment Disaster Control Engineering, the Ministry of Education, Chongqing University, Chongqing 400030 (China)

2010-03-01

Environmental degradation associated with mining activities may seriously threaten the health of local people and the sustainable development of coal mining, which may need to be addressed by improved environmental evaluation system. Based on analyzing environmental pollution from coal mining and the increasing need for raw coal, this paper establishes an environmental evaluation system, covering environmental situation, resource protection and economic benefit, for sustainable development in coal mining. This paper proposes methods for calculating the weight of each index and the environmental sustainable capability taking into account the method of Analytic Hierarchy Process (AHP). Finally, the index system is used to evaluate the environmental sustainability of coal mining in the Qijiang area, Western China, which has demonstrated the validity of the index system. It may also be useful as a tool to assess the environmental impact of mining areas, as well as a measure to promote sustainable development in coal mining. (author)

Coal industry annual 1997

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-12-01

Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

Coal industry annual 1997

International Nuclear Information System (INIS)

1998-12-01

Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs

Data base for the analysis of compositional characteristics of coal seams and macerals. Final report - Part 10. Variability in the inorganic content of United States' coals: a multivariate statistical study

Energy Technology Data Exchange (ETDEWEB)

Glick, D.C.; Davis, A.

1984-07-01

The multivariate statistical techniques of correlation coefficients, factor analysis, and cluster analysis, implemented by computer programs, can be used to process a large data set and produce a summary of relationships between variables and between samples. These techniques were used to find relationships for data on the inorganic constituents of US coals. Three hundred thirty-five whole-seam channel samples from six US coal provinces were analyzed for inorganic variables. After consideration of the attributes of data expressed on ash basis and whole-coal basis, it was decided to perform complete statistical analyses on both data sets. Thirty variables expressed on whole-coal basis and twenty-six variables expressed on ash basis were used. For each inorganic variable, a frequency distribution histogram and a set of summary statistics was produced. These were subdivided to reveal the manner in which concentrations of inorganic constituents vary between coal provinces and between coal regions. Data collected on 124 samples from three stratigraphic groups (Pottsville, Monongahela, Allegheny) in the Appalachian region were studied using analysis of variance to determine degree of variability between stratigraphic levels. Most variables showed differences in mean values between the three groups. 193 references, 71 figures, 54 tables.

Health and environmental effects of coal-fired electric power plants

International Nuclear Information System (INIS)

Morris, S.C.; Hamilton, L.D.

1984-05-01

This paper describes health and environmental impacts of coal-fired electric power plants. Effects on man, agriculture, and natural ecosystems are considered. These effects may result from direct impacts or exposures via air, water, and food chains. The paper is organized by geographical extent of effect. Occupational health impacts and local environmental effects such as noise and solid waste leachate are treated first. Then, regional effects of air pollution, including acid rain, are analyzed. Finally, potential global impacts are examined. Occupational health concerns considered include exposure to noise, dust, asbestos, mercury, and combustion products, and resulting injury and disease. Local effects considered include noise; air and water emissions of coal storage piles, solid waste operations, and cooling systems. Air pollution, once an acute local problem, is now a regional concern. Acute and chronic direct health effects are considered. Special attention is given to potential effects of radionuclides in coal and of acid rain. Finally, potential global impacts associated with carbon dioxide emissions are considered. 88 references, 9 tables

Phyto-bioconversion of hard coal in the Cynodon dactylon/coal rhizosphere.

Science.gov (United States)

Igbinigie, Eric E; Mutambanengwe, Cecil C Z; Rose, Peter D

2010-03-01

Fundamental processes involved in the microbial degradation of coal and its derivatives have been well documented. A mutualistic interaction between plant roots and certain microorganisms to aid growth of plants such as Cynodon dactylon (Bermuda grass) on hard coal dumps has recently been suggested. In the present study coal bioconversion activity of nonmycorrhizal fungi was investigated in the C. dactylon/coal rhizosphere. Fungal growth on 2% Duff-agar, gutation formation on nitric acid treated coal and submerged culture activity in nitrogen-rich and -deficient broth formed part of the screening and selection of the fungi. The selected fungal isolates were confirmed to be found in pristine C. dactylon/coal rhizosphere. To simulate bioconversion, a fungal aliquot of this rhizosphere was used as inoculum for a Perfusate fixed bed bioreactor, packed with coal. The results demonstrate an enhanced coal bioconversion facilitated by low molecular weight organics and the bioconversion of coal may be initiated by an introduction of nitrogen moieties to the coal substrate. These findings suggest a phyto-bioconversion of hard coal involving plant and microbes occurring in the rhizosphere to promote the growth of C. dactylon. An understanding of this relationship can serve as a benchmark for coal dumps rehabilitation as well as for the industrial scale bioprocessing of hard coal.

Slagging behavior of upgraded brown coal and bituminous coal in 145 MW practical coal combustion boiler

Energy Technology Data Exchange (ETDEWEB)

Akiyama, Katsuya; Pak, Haeyang; Takubo, Yoji [Kobe Steel, Ltd, Kobe (Japan). Mechanical Engineering Research Lab.; Tada, Toshiya [Kobe Steel, Ltd, Takasago (Japan). Coal and Energy Technology Dept.; Ueki, Yasuaki [Nagoya Univ. (Japan). Energy Science Div.; Yoshiie, Ryo; Naruse, Ichiro [Nagoya Univ. (Japan). Dept. of Mechanical Science and Engineering

2013-07-01

The purpose of this study is to quantitatively evaluate behaviors of ash deposition during combustion of Upgraded Brown Coal (UBC) and bituminous coal in a 145 MW practical coal combustion boiler. A blended coal consisting 20 wt% of the UBC and 80 wt% of the bituminous coal was burned for the combustion tests. Before the actual ash deposition tests, the molten slag fractions of ash calculated by chemical equilibrium calculations under the combustion condition was adopted as one of the indices to estimate the tendency of ash deposition. The calculation results showed that the molten slag fraction for UBC ash reached approximately 90% at 1,523 K. However, that for the blended coal ash became about 50%. These calculation results mean that blending the UBC with a bituminous coal played a role in decreasing the molten slag fraction. Next, the ash deposition tests were conducted, using a practical pulverized coal combustion boiler. A water-cooled stainless-steel tube was inserted in locations at 1,523 K in the boiler to measure the amount of ash deposits. The results showed that the mass of deposited ash for the blended coal increased and shape of the deposited ash particles on the tube became large and spherical. This is because the molten slag fraction in ash for the blended coal at 1,523 K increased and the surface of deposited ash became sticky. However, the mass of the deposited ash for the blended coal did not greatly increase and no slagging problems occurred for 8 days of boiler operation under the present blending conditions. Therefore, appropriate blending of the UBC with a bituminous coal enables the UBC to be used with a low ash melting point without any ash deposition problems in a practical boiler.

Coal yearbook 1993

International Nuclear Information System (INIS)

Anon.

1993-01-01

This book is the first coal yearbook published by ATIC (France). In a first chapter, economical context of coal worldwide market is analyzed: comparative evaluations on coal exports and imports, coal industry, prices, production in USA, Australia, South Africa, China, former USSR, Poland, Colombia, Venezuela and Indonesia are given. The second chapter describes the french energy context: national coal production, imports, sectorial analysis, maritime transport. The third chapter describes briefly the technologies of clean coal and energy saving developed by Charbonnages de France: fossil-fuel power plants with combined cycles and cogeneration, fluidized beds for the recovery of coal residues, recycling of agricultural wastes (sugar cane wastes) in thermal power plant, coal desulfurization for air pollution abatement. In the last chapter, statistical data on coal, natural gas and crude oil are offered: world production, world imports, world exports, french imports, deliveries to France, coal balance, french consumption of primary energy, power generation by fuel type

Underground Coal Gasification - Experience of ONGC

Science.gov (United States)

Jain, P. K.

2017-07-01

with Ministry of Coal (MoC), MoC finally allotted in-principle Vastan Lignite block to GIPCL in Aug. 2015. The project was to be carried out through a joint venture between ONGC and GIPCL. Unfortunately, efforts lacking sincerity were made by GIPCL for JV. MOC also did not bother adequately to monitor development of JV between ONGC and GIPCL. And finally, GIPCL citing the company to be small sized and it being without any experience on UCG, withdrew from the project in Dec. 2016. Now the block allocation process for the Vastan will have to be initiated afresh by MOC. The future of ONGC yet another UCG campaign seems to have once again hanged in balance. In view of the association with UCG for the decade and based on the feedback from the world-wide status of the technology, the author tries to make important suggestions in the paper for expeditious and efficient implementation of UCG technology in the country.

Application of Biologically Activated Brown Coal in Cu(II Sorption

Directory of Open Access Journals (Sweden)

Andrea Beňová

2004-12-01

Full Text Available The removal of heavy metal ions from wastewaters using different adsorbents is currently of great interest. Adsorption of cooper ions from aqueous solutions on biologically activated brown coal was investigated. Four families of adsorbents were prepared from brown coal by microorganisms activity. There were used soi microfungi such as Aspergillus niger, Aspergillus clavatus, Penicillium glabrum and Trichoderma viride. The equilibrium of the adsorption process was well described by the Langmuir isotherm and the maximum capacity of the sorbents was determined.

Prospects for coal and clean coal technology in the Philippines

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-03-15

This report examines the current energy outlook for the Philippines in regard not only to coal but also other energy resources. The history of the power sector, current state of play and future plans to meet the increasing energy demand from a growing population are discussed. There is also analysis of the trends for coal demand and production, imports and exports of coal and the types of coal-fired power stations that have been built. This includes examination of the legislation involving coal and the promotion of clean coal technologies.

The development of coal-based technologies for Department of Defense facilities. Technical progress report, September 1995 - March 1996

Energy Technology Data Exchange (ETDEWEB)

Miller, B.G.; Pisupati, S.V.; Scaroni, A.W. [and others

1996-10-01

The U.S. Department of Defense (DOD), through an Interagency Agreement with the U.S. Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Slurry Fuel Technology, with the aim of decreasing DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE. Activities this reporting period are summarized by phase. During this reporting period, the Phase I final report was completed. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations included completing a study to identify appropriate SO{sub 2} and NO{sub x} control technologies for coal-fired industrial boilers. In addition, work continued on the design of a ceramic filtering device for installation on the demonstration boiler. The ceramic filtering device will be used to demonstrate a smaller and more efficient filtering device for retrofit applications. Work related to coal preparation and utilization, and the economic analysis was primarily focused on preparing the final report. Work in Phase III focused on coal preparation studies and economic analyses of coal use. Coal preparation studies were focused on continuing activities on particle size control, physical separations, surface-based separation processes, and dry processing. The economic study focused on community sensitivity to coal usage, regional economic impacts of new coal utilization technologies, and constructing a national energy portfolio.

Rosebud SynCoal Partnership, SynCoal{reg_sign} demonstration technology update

Energy Technology Data Exchange (ETDEWEB)

Sheldon, R.W. [Rosebud SynCoal Partnership, Billings, MT (United States)

1997-12-31

An Advanced Coal Conversion Process (ACCP) technology being demonstrated in eastern Montana (USA) at the heart of one of the world`s largest coal deposits is providing evidence that the molecular structure of low-rank coals can be altered successfully to produce a unique product for a variety of utility and industrial applications. The product is called SynCoal{reg_sign} and the process has been developed by the Rosebud SynCoal Partnership (RSCP) through the US Department of Energy`s multi-million dollar Clean Coal Technology Program. The ACCP demonstration process uses low-pressure, superheated gases to process coal in vibrating fluidized beds. Two vibratory fluidized processing stages are used to heat and convert the coal. This is followed by a water spray quench and a vibratory fluidized stage to cool the coal. Pneumatic separators remove the solid impurities from the dried coal. There are three major steps to the SynCoal{reg_sign} process: (1) thermal treatment of the coal in an inert atmosphere, (2) inert gas cooling of the hot coal, and (3) removal of ash minerals. When operated continuously, the demonstration plant produces over 1,000 tons per day (up to 300,000 tons per year) of SynCoal{reg_sign} with a 2% moisture content, approximately 11,800b Btu/lb and less than 1.0 pound of SO{sub 2} per million Btu. This product is obtained from Rosebud Mine sub-bituminous coal which starts with 25% moisture, 8,600 Btu/lb and approximately 1.6 pounds of SO{sub 2} per million Btu.

Role of iron catalyst impregnated by solvent swelling method in pyrolytic removal of coal nitrogen

Energy Technology Data Exchange (ETDEWEB)

Hayashi, J.; Kusakabe, K.; Morooka, S.; Nielsen, M.; Furimsky, E. [Kyushu University, Fukuoka (Japan). Dept. of Chemical Science and Technology

1995-11-01

Organometallic iron precursors, ferrocene and ferric acetate, were impregnated into Illinois No. 6 (IL), Wyoming (WY) and Yallourn (YL) coals by solvent swelling technique in THF, ethanol, and a THF/ethanol binary solvent. Then iron-impregnated coals were pyrolyzed in a flow of helium at atmospheric pressure in a fixed bed and a thermobalance. Conversion of coal nitrogen to N{sub 2} was 20, 38 and 30% respectively, for original IL, WY, and YL coals. Iron formed from both precursors lowered the onset temperature of N{sub 2} evolution by 20-100{degree}C. When ferrocene was impregnated in coals at a concentration of 1.7-1.8 wt% as Fe, nitrogen conversion was increased to 52, 71 and 68% for IL, WY and YL coals, respectively. Ferric acetate impregnated into IL coal from THF/ethanol solution increased the nitrogen conversion much more than that from ethanol solution. The expansion of microporous coal structure by the swelling was essential for better dispersion of the catalyst precursor. The evolution of HCN as well as NH{sub 3} was effectively suppressed above 600{degree}C by the presence of iron but not influenced significantly by combinations of catalyst precursors and solvents. The increase in N{sub 2} yield was compensated by the decrease in nitrogen emitted as HCN and NH{sub 3} and in tar and char. The increase in CO evolution from the iron-impregnated IL coal at 600-800{degree}C was explained by catalytic rearrangement of aromatic structure of char, accompanying the removal of nitrogen as N{sub 2}. In a range of 600-750{degree}C, the evolution of CO as well as N{sub 2} from the other coals increased remarkably with a significant decrease in CO{sub 2} gasification in char microproes. 32 refs., 9 figs., 3 tabs.

Perspectives for the coal thermoelectric generation; Perspectivas para a geracao termeletrica a carvao

Energy Technology Data Exchange (ETDEWEB)

Marreco, Juliana de M. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Planejamento Energetico; Pereira Junior, Amaro; Tavares, Marina E. [EPE - Empresa de Pesquisa Energetica, Rio de Janeiro, RJ (Brazil)

2006-07-01

This paper presents coal future perspectives on power generation. Based on a global market point of view and on demand scenarios. Positive and negative aspects are analysed: if on one hand it may be the solution for safety energy supply, by the other hand it may jeopardize the environment. Nevertheless, new clean coal technologies are now available overcoming some of these difficulties. Without any bias, the paper objective is to provide data for a fair valuation over the coal expansion on power generation in the world and in Brazil. (author)

Coal Transition in Spain. An historical case study for the project 'Coal Transitions: Research and Dialogue on the Future of Coal'

International Nuclear Information System (INIS)

Del Rio, Pablo

2017-01-01

This is one of the 6 country case-studies commissioned to collect experience on past coal transitions. The 6 countries are: Czech Republic, the Netherlands, Poland, Spain, UK, USA. Their role in the Coal Transitions project was to provide background information for a Synthesis Report for decision makers, and provide general lessons for national project teams to take into account in developing their coal transitions pathways for the future. Spain has had a long tradition of coal mining at least since the 18. century. However, it is also one of the jurisdictions committing to phase-out of subsidies and implementing it in recent times. This case study discusses the main features of the coal transition in Spain, the factors influencing this transition as well as the policies which both drove it and accompanied their detrimental socioeconomic effects on the workers and regions. The analysis is based on a desktop research of relevant documents, including official communications from the Ministry of Industry (MINETUR) and the European Commission as well as statements of position from the industry association (CARBUNION) and labour unions (UGT and CCOO). Documents on national coal from other institutions (Foundations, NGOs) have also been consulted. Finally, an analysis of articles in the mass media has been carried out. This contains useful statements from different types of stakeholders. A strong reduction in production and employment in the coal industry has been experienced at least in the last two decades in this country. Successive plans by the government have aimed at reducing coal production, early retirement of workers and closing mines. Caught in the middle of the mining coalition on the one hand and EU legislation and public opinion on the other, the government has had to approve drastic measures leading to phase out. On the other hand, it has tried to accompany the phase out with measures which have tried to mitigate the negative impact on the affected zones

The application of the coal grain analysis method to coal liberation studies

Energy Technology Data Exchange (ETDEWEB)

O' Brien, G.; Firth, B.; Adair, B. [CSIRO Earth Science & Resource Engineering Brisbane, Qld. (Australia)

2011-07-01

Emerging coal markets such as the use of coal for conversion to liquid fuels and its use in fuels cells and as coal water slurries in diesel engines require coal products with different coal quality specifications than those applicable to traditional coal markets of coke making and conventional power generation. As well as quantifying coals in terms of their chemical and physical properties, detailed knowledge of the mineral inclusions within the coal particles is required to identify coals that are suited to economically produce the low-ash value coals required for these markets. After mining and processing, some particles can consist of essentially pure components of a single maceral or mineral phase whilst others are composite particles that are comprised of varying amounts of macerals and minerals. The proportion of particles that are present as pure components or as composites will be a function of the characteristics of the coal and the particle size. In general, it is considered that size reduction will result in liberation and hence increased yield. The amount of liberation that occurs during crushing or grinding a coal is however coal specific. Particle characterization information provided by an optical microscopic-imaging method, Coal Grain Analysis, was used to identify coals that might benefit from additional crushing to improve recovery of clean coal by new density separation techniques and by flotation. As expected, the results of these studies suggest that the degree of liberation that is obtained is coal specific, and, hence, yield improvements are also coal specific. Hence a quantitative method of investigating this issue is required.

Comparative emissions from Pakistani coals and traditional coals

Energy Technology Data Exchange (ETDEWEB)

Du, Y X [Guangzhou Medical College (China). Dept. of Hygiene; Huang, L F [Guangzhou Health and Anti-epidemic Station (China)

1994-12-31

Briquette coal has been widely used for domestic cooking and heating in many Chinese cites over the last two decades. To determine whether burning briquette coal contributes significantly to indoor air pollution, a study was performed in cities-of Southern China in which the measured levels of SO{sub 2}, NO{sub x}, TSP, SD, B(a)P in the kitchens of coal burning families were compared with levels obtained in families using gas. Significantly higher contentions of these pollutants, whose peaks correlated with daily cooking episodes, were detected in coal burning families. The levels of TSP and B(a)P were further found to be dependent on cooking methods, with deep frying and stir-frying of meat generating the most indoor TSP and B(a)P. Briquette coal burning was found to be the source of B(a)P contamination in food. A higher incidence of chronic pharyngitis as well as a suppressed salivary bacteriolytic enzyme activity were found in children of coal burning families. Epidemiologic and laboratory studies also show a close association between coal burning and the incidence of lung cancer in females. (author)

Third symposium on coal preparation. NCA/BCR coal conference and Expo IV

Energy Technology Data Exchange (ETDEWEB)

None

1977-01-01

The third Symposium on Coal preparation, sponsored by the National Coal Association and Bituminous Coal Research, Inc., was held at the Kentucky Fair and Exposition Center, Louisville, Kentucky, October 18-20, 1977. Fourteen papers from the proceedings have been entered individually into EDB and ERA; five additional papers had been entered previously from other sources. Topics covered involved chemical comminution and chemical desulfurization of coal (aimed at reducing sulfur sufficiently with some coals to meet air quality standards without flue gas desulfurization), coal cleaning concepts, removing coal fines and recycling wash water, comparative evaluation of coal preparation methods, coal refuse disposal without polluting the environment, spoil bank reprocessing, noise control in coal preparation plants, etc. (LTN)

Coal pyrolysis under hydrogen-rich gases

Energy Technology Data Exchange (ETDEWEB)

Liao, H.; Sun, C.; Li, B.; Liu, Z. [Chinese Academy of Sciences, Taiyuan (China). State Key Laboratory of Coal Conversion, Institute of Coal Chemistry

1998-04-01

To improve the economy of the pyrolysis process by reducing the hydrogen cost, it is suggested to use cheaper hydrogen-rich gases such as coke-oven gas (COG) or synthesis gas (SG) instead of pure hydrogen. The pyrolysis of Chinese Xianfeng lignite which was carried out with real COG and SG at 3-5 MPa, a final temperature of 650{degree}C and a heating rate of 5{degree}C/min in a 10g fixed-bed reactor is compared with coal pyrolysis with pure hydrogen and nitrogen under the same conditions. The results indicate that compared with hydropyrolysis at the same total pressure, the total conversion and tar yields from coal pyrolysis with COG and SG decreases while the unwanted water increases. However, at the same H{sub 2} partial pressure, the tar yields and yields of BBTX, PCX and naphthalene from the pyrolysis of coal with COG and SG are all significantly higher than those of hydropyrolysis. Therefore, it is possible to use COG and SG instead of pure hydrogen. 8 refs., 3 figs., 6 tabs.

Coal industry annual 1993

Energy Technology Data Exchange (ETDEWEB)

1994-12-06

Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

Coal industry annual 1993

International Nuclear Information System (INIS)

1994-01-01

Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993

Technological challenges for boosting coal production with environmental sustainability.

Science.gov (United States)

Ghose, Mrinal K

2009-07-01

The global energy requirement has grown at a phenomenon rate and the consumption of primary energy sources has been a very high positive growth. This paper focuses on the consumption of different primary energy sources and it identifies that coal will continue to remain as the prime energy source in foreseeable future. It examines the energy requirement perspective for India and demand of coal as the prime energy source. Economic development and poverty alleviation depend on securing affordable energy sources and Indian coal mining industry offers a bright future for the country's energy security, provided the industry is allowed to develop by supportive government policies and adopts latest technologies for mining. It is an irony that in-spite of having a plentiful reserves, India is not able to jack up coal production to meet its current and future demand. It discusses the strategies to be adopted for growth and meeting the coal demand. But such energy are very much concerned with environmental degradation and must be driven by contemporary managerial acumen addressing environmental and social challenges effectively The paper highlights the emissions of greenhouse gases due to burning of fossil fuels and environmental consequences of global warming and sea-level rise. Technological solutions for environment friendly coal mining and environmental laws for the abatement of environmental degradation are discussed in this paper.

Coal and Energy.

Science.gov (United States)

Bryant, Reba; And Others

This teaching unit explores coal as an energy resource. Goals, student objectives, background information, and activity options are presented for each major section. The sections are: (1) an introduction to coal (which describes how and where coal was formed and explains the types of coal); (2) the mining of coal (including the methods and ways of…

Stress distribution characteristics in the vicinity of coal seam floor

Science.gov (United States)

Cui, Zimo; Chanda, Emmanuel; Zhao, Jingli; Wang, Zhihe

2018-01-01

Although longwall top-coal caving (LTCC) has been a popular, more productive and cost-effective method in recent years, roadway floor heave and rock bursts frequently appear when exploiting such coal seams with large dip angle. This paper proposes addressing this problem by adopting three-dimensional roadway layout of stagger arrangement (3-D RLSA). In this study, the first step was to analyse the stress distribution characteristics in the vicinity of coal seam floor based on the stress slip line field theory. In the second step, numerical calculation using FLAC3D was conducted. Finally, an evaluation of the 3-D RLSA for solving this particular issue was given. Results indicate that for this particular mine the proposed 3-D RLSA results in 24% increase in the coal recovery ratio and a modest reduction in excavation and maintenance costs compared to the conventional LTCC method.

Characterization of coal types by their content of volatile matter

Energy Technology Data Exchange (ETDEWEB)

Scholz, A. (Ruhrkohle A.G., Essen (Germany, F.R.). Qualitaetsstelle)

1979-08-01

First of all, the difference between mineral content and ash content, the effect of minerals on the content of volatile matter and the connection between the ash and volatile matter contents is examined. Then three processes are described, to determine the content of organic fuels in the volatile matter of hard coal. The results are compared and the applicability of the processes is assessed. The conversion formulae recommended for the ASTM and NCB classifications are examined regarding their applicability to German types of coal. Finally an equation is proposed, in order to calculate the estimated value for the content of water and mineral free fuel in volatile matter. Apart from the content of volatile matter in water free coal, one only needs the figures ash content and the mineral factor for this. The equation can also be used for mixtures the usability of the equation is tested for Ruhr coal.

Asia's coal and clean coal technology market potential

International Nuclear Information System (INIS)

Johnson, C.J.; Binsheng Li

1992-01-01

The Asian region is unique in the world in having the highest economic growth rate, the highest share of coal in total primary energy consumption and the highest growth rate in electricity generation capacity. The outlook for the next two decades is for accelerated efforts to control coal related emissions of particulates and SO 2 and to a lessor extent NO x and CO 2 . Only Japan has widespread use of Clean Coal Technologies (CCTs) however a number of economies have plans to install CCTs in future power plants. Only CCTs for electricity generation are discussed, and are defined for the purpose of this paper as technologies that substantially reduce SO 2 and/or NO x emissions from coal-fired power plants. The main theses of this paper are that major increases in coal consumption will occur over the 1990-2010 period, and this will be caccompanied by major increases in coal related pollution in some Asian economies. Coal fired electricity generation is projected to grow at a high rate of about 6.9 percent per year over the 1990-2010 period. CCTs are projected to account for about 150 GW of new coal-fired capacity over the 1990-2010 period of about one-third of all new coal-fired capacity. A speculative conclusion is that China will account for the largest share of CCT additions over the 1990-2010 period. Both the US and Japan have comparative advantages that might be combined through cooperation and joint ventures to gain a larger share of the evolving CCT market in Asia. 5 refs., 7 figs., 4 tabs

AISI Direct Steelmaking Program. Final technical report

Energy Technology Data Exchange (ETDEWEB)

Aukrust, E.

1994-08-01

This final report deals with the results of a 5-yr project for developing a more energy-efficient, environmentally friendly, less costly process for producing hot metal than current coke ovens and blast furnaces. In the process, iron ore pellets are smelted in a foamy slag created by reaction of coal char with molten slag to produce CO. The CO further reacts with oxygen, which also reacts with coal volatile matter, to produce the heat necessary to sustain the endothermic reduction reaction. The uncombusted CO and H{sub 2} from the coal are used to preheat and prereduce hematite pellets for the most efficient use of the energy in the coal. Laboratory programs confirmed that the process steps worked. Pilot plant studies were successful. Economic analysis for a 1 million tpy plant is promising.

Coal - 96

International Nuclear Information System (INIS)

Sparre, C.

1996-09-01

The report deals mainly with coal consumption, but also gives some information about technology, environmental aspects and markets. Data have been collected by questionnaires or via telephone. The use of steam coal for heating was 0.8 Mtons (down 20% from 1994). Cogeneration plants were the main users. Taxes and environmental reasons cause a reduction of the coal use that will probably continue the next years. Use of steam coal in industry has been constant at a level of 0.7 Mtons. The import of metallurgical coal rests constant at a level of 1.6 Mtons. 1.2 Mtons of coke was produced, and 0.3 Mtons imported. The PFBC-plant at Vaertan, Stockholm used 0.13 Mtons of coal, while some coal fired power plants have been converted to peat and wood fuels. The average price of steam coal imported to Sweden in 1995 was 333 SEK/ton, 6% higher than in 1994. The contract prices for delivery 1996 are about the same as at the end of 1995. All cogeneration plants have some sort of SO 2 removal system, mostly wet-dry. The largest plant, at Vaesteraas, has recently invested in a SCR system for NO x removal. Most other plants are using low NO x burners or SNCR systems, based on ammonia or urea, which reduce the emissions 50 - 70%. Some statistic about the world coal market is also given in the report

An innovative concept for maximizing the use of coal and nuclear energy for co-generation applications

International Nuclear Information System (INIS)

Choong, P.T.S.

1995-01-01

Despite the abundance in coal reserves in the world, coal fired power plants are not the desirable long-term solution to the energy shortage in most nations, because of environmental and transportation difficulties. However, nuclear power is inherently inefficient due to low temperature operations. The prudent solution to world's energy crisis should address both the immediate need for electricity and the long-term need for an environmentally sound energy system capable of providing low cost electricity and district heating energy utilizing mainly indigenous energy resources (coal, uranium, and thorium). The new energy utilization system has to be environment friendly. A conceptual solution plan is the subject matter of this presentation. The concept calls for an innovative integration of coal gasification, gas turbine, steam turbine and an intermediate bulk coolant heating nuclear power technologies. The output of the nuclear heated coolant is to cool the syngas output which is to drive the high temperature gas turbine generator. The waste heat from the gas turbine is recovered to drive the steam turbine. The exhaust steam from the steam turbine is used for district heating. The siting of the nuclear power plant is to be near the coal mines and water resources. Bulk of the electricity output is transmitted via HVDC lines to far away population centers. Excess coal gas from the gasification plant is to be piped to surrounding districts to drive remote combined cycle power plants. The thermal efficiency of power cycle can be over 50%. The overall energy utilization efficiency can be as high as 85% when district heating effect included. An example of INCTES (Integrated Nuclear/Coal Total Energy System) for China power/energy infra structure is briefly touched upon

Modes of occurrence of potentially hazardous elements in coal: levels of confidence

Science.gov (United States)

Finkelman, R.B.

1994-01-01

The modes of occurrence of the potentially hazardous elements in coal will be of significance in any attempt to reduce their mobilization due to coal combustion. Antimony and selenium may be present in solid solution in pyrite, as minute accessory sulfides dispersed throughout the organic matrix, or in organic association. Because of these modes of occurrence it is anticipated that less than 50% of these elements will be routinely removed by conventional coal cleaning procedures. Arsenic and mercury occur primarily in late-stage coarse-grained pyrite therefore physical coal cleaning procedures should be successful in removing substantial proportions of these elements. Cadmium occurs in sphalerite and lead in galena. Both of these minerals exhibit a wide range of particle sizes and textural relations. Depending on the particle size and textural relations, physical coal cleaning may remove as little as 25% of these elements or as much as 75%. Manganese in bituminous coal occurs in carbonates, especially siderite. Physical coal cleaning should remove a substantial proportion of this element. More information is needed to elucidate the modes of occurrence of beryllium, chromium, cobalt, and nickel. ?? 1994.

High resolution seismic survey (of the) Rawlins, Wyoming underground coal gasification area. Final report

Energy Technology Data Exchange (ETDEWEB)

Youngberg, A.D.; Berkman, E.; Orange, A.S.

1983-01-01

In October 1982, a high resolution seismic survey was conducted at the Gulf Research and Development Company's underground coal gasification test site near Rawlins, Wyoming. The objectives of the survey were to utilize high resolution seismic technology to locate and characterize two underground coal burn zones. Seismic data acquisition and processing parameters were specifically designed to emphasize reflections at the shallow depths of interest. A three-dimensional grid of data was obtained over the Rawlins burn zones. Processing included time varying filters, trace composition, and two-dimensional areal stacking of the data in order to identify burn zone anomalies. An anomaly was discernable resulting from the rubble-collapse cavity associated with the burn zone which was studied in detail at the Rawlins 1 and 2 test sites. 21 refs., 20 figs.

Process for treating bituminous coal, lignite, peat, and shale, and products obtained

Energy Technology Data Exchange (ETDEWEB)

Schabelitz, E J

1951-06-27

A process is described comprising leaching bituminous coal, lignite, peat, or shale by immersing said material in ethylene dichloride for a period of time sufficient to remove the ethylene dichloride-soluble constituents, separating the treated material from the ethylene dichloride solution and recovering from the solution the soluble constituents of the material dissolved in the solution. Soluble constituents include oils and waxes.

75 FR 17511 - Coal Mine Dust Sampling Devices

Science.gov (United States)

2010-04-06

... base and free to oscillate at its narrow or free end on which the collection filter is mounted... coal mines from power stations, electric motors and remote control transmitters. The final rule... electromagnetic interference. The FCC is an independent Federal agency that regulates radiofrequency emitting...

Adsorption of Heavy Metals on Biologically Activated Brown Coal Sludge

Directory of Open Access Journals (Sweden)

Mária Praščáková

2005-11-01

Full Text Available Adsorption of cooper (II and zinc (II ions from aqueous solutions on a biologically activated brown coal sludge was investigated. Four families of adsorbents were prepared from the brown coal sludge bya microorganism’s activity. There were used microscopic fungi such as Aspergillus niger, Aspergillus clavatus, Penicillium glabrum and Trichoderma viride. Prepared sorbents were capable of removing Cu (II and Zn (II. The sorption isotherm has been constructed and the specific metal uptake and the maximum capacity of the adsorbent have been determined.

Swelling behavior of several bituminous coals and their thermally treated coals

Energy Technology Data Exchange (ETDEWEB)

Shui, Heng-fu; Cao, Mei-xia; Wang, Zhi-cai [Anhui University of Technology, Maanshan (China). School of Chemistry & Chemical Engineering

2007-07-01

The swelling behavior in different solvents of 4 bituminous coals with different ranks and their residues from extraction by CS{sub 2}/NMP mixed solvent (l:1 in volume) were measured. The change in swelling property of the four coals thermally treated at different temperature was observed. The results show that the swelling ratio decreases with increasing rank of coal. For lower rank bituminous coals the swelling ratios in polar solvent are higher than those in non-polar solvent, and this difference decreases with increasing rank. The cross-linking densities of the four residues decrease, and the swelling ratios increase compared with those of raw coals. The swelling ratios of the four thermally treated coals under 150{sup o}C in CS{sub 2} increase, suggesting the decrease in crosslinking density of them. When the thermal treatment temperature increases to 240{sup o}C, the swelling rations of the other three coals in NMP and CS{sub 2} increase again except gas coal, demonstrating the further decrease in crosslinking density. This result is coincident with the extraction yield change in the mixed solvent of the thermally treated coal. For example, the extraction yield of lean coal treated at 240{sup o}C increases from 6.9% to 17.3%. FT-IR results show the removal of oxygen group of the thermally treated coals. This may explain the increase in swelling ratio and extraction yield in the mixed solvent of coal after thermal treatment. The cross-linking density of the thermally treated coal decreases because of the break of hydrogen bonds due to removal of C = 0 and -OH oxygen groups during the thermal treatment, resulting in the increases of swelling ratio and extraction yield in the mixed solvent of thermally treated coal compared with those of raw coal. 15 refs., 3 figs., 6 tabs.

The 3R anthracite clean coal technology: Economical conversion of brown coal to anthracite type clean coal by low temperature carbonization pre-treatment process

Directory of Open Access Journals (Sweden)

Someus Edward

2006-01-01

Full Text Available The preventive pre-treatment of low grade solid fuels is safer, faster, better, and less costly vs. the "end-of-the-pipe" post treatment solutions. The "3R" (Recycle-Reduce-Reuse integrated environment control technology provides preventive pre-treatment of low grade solid fuels, such as brown coal and contaminated solid fuels to achieve high grade cleansed fuels with anthracite and coke comparable quality. The goal of the 3R technology is to provide cost efficient and environmentally sustainable solutions by preventive pre-treatment means for extended operations of the solid fuel combustion power plants with capacity up to 300 MWe power capacities. The 3R Anthracite Clean Coal end product and technology may advantageously be integrated to the oxyfuel-oxy-firing, Foster Wheeler anthracite arc-fired utility type boiler and Heat Pipe Reformer technologies in combination with CO2 capture and storage programs. The 3R technology is patented original solution. Advantages. Feedstock flexibility: application of pre-treated multi fuels from wider fuel selection and availability. Improved burning efficiency. Technology flexibility: efficient and advantageous inter-link to proven boiler technologies, such as oxyfuel and arcfired boilers. Near zero pollutants for hazardous-air-pollutants: preventive separation of halogens and heavy metals into small volume streams prior utilization of cleansed fuels. >97% organic sulphur removal achieved by the 3R thermal pre-treatment process. Integrated carbon capture and storage (CCS programs: the introduction of monolitic GHG gas is improving storage safety. The 3R technology offers significant improvements for the GHG CCS conditions. Cost reduction: decrease of overall production costs when all real costs are calculated. Improved safety: application of preventive measures. For pre-treatment a specific purpose designed, developed, and patented pyrolysis technology used, consisting of a horizontally arranged externally

Proceedings of the sixth APEC Coal Flow Seminar. Coal in the new millennium

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-08-01

The 6th APEC Coal Flow Seminar titled on 'The coal in the new millennium' was held in Korea from March 14 to March 16, 2000, and the proceedings were summed up. In this seminar, as to economies of coal consumption countries and coal supply countries in the APEC region, discussions were made on coal supply/demand, coal price, environmental problems and others. The keynote address was 'Twenty first century coal in the APEC region and Republic of Korea' given by Mr. Gam Yeol Lee from Korea. The main theme of the seminar was 'The status quo for the coal market,' and lectures titled on the following were given from Japan: 'The status quo of coal purchase by the Japanese electric company and its outlook' and 'A perspective of coal fired IPP under environmental constraints and deregulation of electricity.' Lectures from Australia: 'Responding to coal market growth in APEC regions by the Australian coal industry' and 'The coal price impact on coal supply and demand.' Further discussions were made on 'The long-term outlook for coal supply/demand' and 'Economies report on the outlook for coal supply/demand.' (NEDO)

Mechanisms of coal solubilization by the deuteromycetes Trichoderma atroviride and Fusarium oxysporum

Energy Technology Data Exchange (ETDEWEB)

Hoelker, U.; Ludwig, S.; Scheel, T.; Hoefer, M. [Bonn Univ. (Germany). Botanisches Inst. und Botanischer Garten

1999-07-01

Three different mechanisms can be envisaged that are used by fungi to solubilize coal: the production of alkaline substances, the extrusion of chelators and, of special interest in the scope of biotechnology, the action of enzymes. Whether these mechanisms are operating separately or in various combinations has not yet been finally assessed. The two deuteromycetes Fusarium oxysporum and Trichoderma atroviride solubilize coal by synergistic effects of various different mechanisms depending on the cell metabolism. F. oxysporum seems to solubilize coal by increasing the pH of the mycelial surroundings and by the action of chelators induced during growth in glutamate-containing media (without involvement of enzymes). T. atroviride, on the other hand, appears to use, in addition to an alkaline pH and a high chelator activity, at least two classes of enzyme activity to attack coal: hydrolytic activity for coal solubilization and ligninolytic activity for degradation of humic acids. (orig.)

TVA coal-gasification commercial demonstration plant project. Volume 5. Plant based on Koppers-Totzek gasifier. Final report

Energy Technology Data Exchange (ETDEWEB)

1980-11-01

This volume presents a technical description of a coal gasification plant, based on Koppers-Totzek gasifiers, producing a medium Btu fuel gas product. Foster Wheeler carried out a conceptual design and cost estimate of a nominal 20,000 TPSD plant based on TVA design criteria and information supplied by Krupp-Koppers concerning the Koppers-Totzek coal gasification process. Technical description of the design is given in this volume.

Coal industry annual 1996

International Nuclear Information System (INIS)

1997-11-01

This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs

Coal industry annual 1996

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-11-01

This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

Coal Industry Annual 1995

International Nuclear Information System (INIS)

1996-10-01

This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995

Coal Industry Annual 1995

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-10-01

This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

South Blackwater Coal`s maintenance program

Energy Technology Data Exchange (ETDEWEB)

Nash, J. [South Blackwater Coal Limited, Blackwater, Qld. (Australia)

1998-09-01

The South Blackwater operation consists of two opencut mining areas and two underground mines (Laleham and Kenmure) near Blackwater in central Queensland, all of which supply coal to a central coal preparation plant. South Blackwater Coal Ltd. recently developed a maintenance improvement programme, described in this article. The programme involved implementation systems of key performance indicators (KPIs), benchmaking, condition monitoring, work planning and control, failure analysis and maintenance audit. Some improvements became almost immediately apparent, others were quite gradual. Major results included: improved availability (and reliability) of all opencast fleets, improvements in rear dump availability; reduced maintenance man-hours for opencast fleets; and increased availability of the coal handling and preparation plant. The paper is an edited version of that presented at the `Maintenance in mining conference` 16-19 March 1998, held in Bali, Indonesia. 4 figs., 2 photos.

Efficient and large scale synthesis of graphene from coal and its film electrical properties studies.

Science.gov (United States)

Wu, Yingpeng; Ma, Yanfeng; Wang, Yan; Huang, Lu; Li, Na; Zhang, Tengfei; Zhang, Yi; Wan, Xiangjian; Huang, Yi; Chen, Yongsheng

2013-02-01

Coal, which is abundant and has an incompact structure, is a good candidate to replace graphite as the raw material for the production of graphene. Here, a new solution phase technique for the preparation of graphene from coal has been developed. The precursor: graphene oxide got from coal was examined by atomic force microscopy, dynamic light scattering and X-ray diffraction, the results showed the GO was a small and single layer sheet. The graphene was examined by X-ray photoelectron spectroscopy, and Raman spectroscopy. Furthermore, graphene films have been prepared using direct solution process and the electrical conductivity and Hall effect have been studied. The results showed the conductivity of the films could reach as high as 2.5 x 10(5) Sm(-1) and exhibited an n-type behavior.

SALES DOCUMENTS IN PURCHASE AND SALE TRANSACTIONS OF STEAM COAL IN POLAND

Directory of Open Access Journals (Sweden)

Anna Galik

2015-06-01

Full Text Available This article describes sales documents in purchase and sale transactions of steam coal in Poland. In relation to introducing the excise tax on steam coal at the beginning in 2012, additional requirements appeared in documents during the sale of goods. Now the seller is obliged to issue various documents depending on the type of the buyer and the destination of goods. The article presents the coal sales documents for households, companies with no tax payment and companies with tax payment. The purpose of this article is to present complicated and time-consuming procedures during the sale of goods, as a result of the current excise tax on steam coal. In conclusion the author identify new solutions that are beneficial for the seller and the buyer.

Hard coal; Steinkohle

Energy Technology Data Exchange (ETDEWEB)

Loo, Kai van de; Sitte, Andreas-Peter [Gesamtverband Steinkohle e.V., Herne (Germany)

2013-04-01

The year 2012 benefited from a growth of the consumption of hard coal at the national level as well as at the international level. Worldwide, the hard coal still is the number one energy source for power generation. This leads to an increasing demand for power plant coal. In this year, the conversion of hard coal into electricity also increases in this year. In contrast to this, the demand for coking coal as well as for coke of the steel industry is still declining depending on the market conditions. The enhanced utilization of coal for the domestic power generation is due to the reduction of the nuclear power from a relatively bad year for wind power as well as reduced import prices and low CO{sub 2} prices. Both justify a significant price advantage for coal in comparison to the utilisation of natural gas in power plants. This was mainly due to the price erosion of the inexpensive US coal which partly was replaced by the expansion of shale gas on the domestic market. As a result of this, the inexpensive US coal looked for an outlet for sales in Europe. The domestic hard coal has continued the process of adaptation and phase-out as scheduled. Two further hard coal mines were decommissioned in the year 2012. RAG Aktiengesellschaft (Herne, Federal Republic of Germany) running the hard coal mining in this country begins with the preparations for the activities after the time of mining.

Coal prices rise

International Nuclear Information System (INIS)

McLean, A.

2001-01-01

Coking and semi hard coking coal price agreements had been reached, but, strangely enough, the reaching of common ground on semi soft coking coal, ultra low volatile coal and thermal coal seemed some way off. More of this phenomenon later, but suffice to say that, traditionally, the semi soft and thermal coal prices have fallen into place as soon as the hard, or prime, coking coal prices have been determined. The rise and rise of the popularity of the ultra low volatile coals has seen demand for this type of coal grow almost exponentially. Perhaps one of the most interesting facets of the coking coal settlements announced to date is that the deals appear almost to have been preordained. The extraordinary thing is that the preordination has been at the prescience of the sellers. Traditionally, coking coal price fixing has been the prerogative of the Japanese Steel Mills (JSM) cartel (Nippon, NKK, Kawasaki, Kobe and Sumitomo) who presented a united front to a somewhat disorganised force of predominantly Australian and Canadian sellers. However, by the time JFY 2001 had come round, the rules of the game had changed

Coals as sorbents for the removal and reduction of hexavalent chromium from aqueous waste streams

Energy Technology Data Exchange (ETDEWEB)

Lakatos, J.; Brown, S.D.; Snape, C.E. [University of Miskolc, Miskolc (Hungary). Dept. of Analytical Chemistry

2002-03-01

The aim of this study is to demonstrate the potential of coals as a low-cost reactive barrier material for environmental protection applications, with the ability to prevent leaching of toxic Cr(VI) and other transition metals. Depending upon the type of ion and the surface functionalities, the uptake can involve ion sorption, ion exchange, chelation and redox mechanisms with the surface functionalities being considered as partners in electron transfer processes. The capacity for Cr(VI) uptake of low rank coals and oxidized bituminous coals has been found to lie within the range 02-0.6 mM g{sup -1}. Air oxidation of bituminous coals can increase their Cr(VI) removal capacities. The effect of air oxidation of coals on uptake capacity was more pronounced for Cr(VI) than Cr(III) but less than for Hg(II) and the other ions (Ca{sup 2+}, Ba{sup 2+}, Zn{sup 2+}, Cd{sup 2}) investigated. As previously found for Hg(II), redox mechanisms plays an important role in Cr(VI) uptake, with resultant Cr(III) is exchanged back into solution by hydrogen ions, but some of the sorbed chromium is irreversibly bound to the coal. The reduction of Cr(VI) alone is often considered a satisfactory solution in view of Cr(III) being essentially nontoxic. 56 refs., 11 figs., 1 tab.

New method for reduction of burning sulfur of coal

International Nuclear Information System (INIS)

Lyutskanov, L.; Dushanov, D.

1998-01-01

The coal pyrolysis is key phase in the the pyrolysis-combustion cycle as it provides char for combustor. The behaviour of sulfur compounds during coal pyrolysis depends on factors as rank of coal, quantity of sulfur and sulfur forms distribution in the coal, quantity and kind of mineral matter and the process conditions. The mineral content of coal may inhibit or catalyze the formation of volatile sulfur compounds. The pyrolysis itself is a mean of removing inorganic and organic sulfur but anyway a portion of it remains in the char while the other moves into the tar and gas. The aim of this study was to determine an optimal reduction of burning sulfur at the coal pyrolysis by varying parametric conditions. The pyrolysis of different kinds of coal has been studied. The samples with size particles o C at atmospheric pressure and with a heating rate of 6-50 o C min -1 . They were treated with exhaust gas and nitrogen at an addition of steam and air. The char obtained remains up to 10 min at the final temperature. The char samples cool without a contact with air. Two methods of desulfurization-pyrolysis were studied - using 9-vertical tubular reactor and 9-horizontal turning reactor. The results obtained show that at all samples there is a decrease of burning sulfur with maximal removal efficiency 83%. For example at a pyrolysis of Maritsa Iztok lignite coal the burning sulfur is only 16% in comparison with the control sample. The remained is 90% sulfate, 10% organic and pyrite traces when a mixture 'exhaust gas-water stream-air' was used. The method of desulfurization by pyrolysis could be applied at different kinds of coal and different conditions. Char obtained as a clean product can be used for generating electric power. This innovation is in a stage of patenting

Oxidation and carbonisation of coals: a case study of coal fire affected coals from the Wuda coalfield, Inner Mongolia, China

Science.gov (United States)

Kus, Jolanta; Meyer, Uwe; Ma, Jianwei; Chen-Brauchler, Dai

2010-05-01

At the coalfield of Wuda (Inner Mongolia, PR China) extensive underground coal fires cause widespread thermal and oxidative effects in coal seams. Within phase B of the Coal Fire Research Project of the Sino-German Initiative, methods for innovative fire-extinguishing technologies were investigated in multifaceted research approaches. Extensive investigations of oxidative and thermally affected coal seams in coal fire zone 18 were conducted in 2008 prior to application of new fire-extinguishing methods. We present results from the outcrop of coal seam No. 4 in the fire zone 18. The coal of seam No. 4 is of Early Permian age and belongs stratigraphically to the Shanxi Formation. The unaffected coal displays a high volatile bituminous A rank with a background value of random vitrinite reflectance ranging from 0.90 to 0.96 % Rr. Coal channel samples were coallected at actively extracted coal faces along multiple profiles with surface temperatures ranging from about 50° to 600°C. Microscopic examinations revealed a variety of products of coal exposure to the fire. Within coal samples, a marked rise in vitrinite reflectance from background values to 5.55% Rr (6.00 % Rmax) is encountered. In addition, a number of coal samples showed suppressed vitrinite reflectances ranging between 0.82 to 0.88% Rr. Further, seemingly heat unaffected coal samples display intensive development of oxidations rims at coal grain edges and cracks as well as shrinkage cracks and formation of iron oxides/hydroxides. Instead, thermally affected coal samples with higher coalification grade are further characterised by development of macropores (devolatilisation pores) in vitrinitic streaks, transformation of liptinite to meta-liptinite and micrinite as well as by natural coke particles of mostly porous nature and fine to coarse grained anisotropic mosaic. Coal petrographic investigations confirmed a hypothesis that both, oxidations as well as low temperature carbonisation govern the thermal

Baseload coal investment decisions under uncertain carbon legislation.

Science.gov (United States)

Bergerson, Joule A; Lave, Lester B

2007-05-15

More than 50% of electricity in the U.S. is generated by coal. The U.S. has large coal resources, the cheapest fuel in most areas. Coal fired power plants are likely to continue to provide much of U.S. electricity. However, the type of power plant that should be built is unclear. Technology can reduce pollutant discharges and capture and sequester the CO2 from coal-fired generation. The U.S. Energy Policy Act of 2005 provides incentives for large scale commercial deployment of Integrated Coal Gasification Combined Cycle (IGCC) systems (e.g., loan guarantees and project tax credits). This analysis examines whether a new coal plant should be Pulverized Coal (PC) or IGCC. Do stricter emissions standards (PM, SO2, NOx, Hg) justify the higher costs of IGCC over PC? How does potential future carbon legislation affect the decision to add carbon capture and storage (CCS) technology? Finally, can the impact of uncertain carbon legislation be minimized? We find that SO2, NOx, PM, and Hg emission standards would have to be far more stringent than twice current standards to justify the increased costs of the IGCC system. A C02 tax less than $29/ton would lead companies to continuing to choose PC, paying the tax for emitted CO2. The earlier a decision-maker believes the carbon tax will be imposed and the higher the tax, the more likely companies will choose IGCC w/CCS. Having government announce the date and level of a carbon tax would promote more sensible decisions, but government would have to use a tax or subsidy to induce companies to choose the technology that is best for society.

Healy Clean Coal Project: A DOE Assessment

Energy Technology Data Exchange (ETDEWEB)

National Energy Technology Laboratory

2003-09-01

The goal of the U.S. Department of Energy's (DOE) Clean Coal Technology (CCT) Program is to provide the energy marketplace with advanced, more efficient, and environmentally responsible coal utilization options by conducting demonstrations of new technologies. These demonstration projects are intended to establish the commercial feasibility of promising advanced coal technologies that have been developed to a level at which they are ready for demonstration testing under commercial conditions. This document serves as a DOE post-project assessment (PPA) of the Healy Clean Coal Project (HCCP), selected under Round III of the CCT Program, and described in a Report to Congress (U.S. Department of Energy, 1991). The desire to demonstrate an innovative power plant that integrates an advanced slagging combustor, a heat recovery system, and both high- and low-temperature emissions control processes prompted the Alaska Industrial Development and Export Authority (AIDEA) to submit a proposal for this project. In April 1991, AIDEA entered into a cooperative agreement with DOE to conduct this project. Other team members included Golden Valley Electric Association (GVEA), host and operator; Usibelli Coal Mine, Inc., coal supplier; TRW, Inc., Space & Technology Division, combustor technology provider; Stone & Webster Engineering Corp. (S&W), engineer; Babcock & Wilcox Company (which acquired the assets of Joy Environmental Technologies, Inc.), supplier of the spray dryer absorber technology; and Steigers Corporation, provider of environmental and permitting support. Foster Wheeler Energy Corporation supplied the boiler. GVEA provided oversight of the design and provided operators during demonstration testing. The project was sited adjacent to GVEA's Healy Unit No. 1 in Healy, Alaska. The objective of this CCT project was to demonstrate the ability of the TRW Clean Coal Combustion System to operate on a blend of run-of-mine (ROM) coal and waste coal, while meeting strict

Proceedings of the sixth APEC Coal Flow Seminar. Coal in the new millennium

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-08-01

The 6th APEC Coal Flow Seminar titled on 'The coal in the new millennium' was held in Korea from March 14 to March 16, 2000, and the proceedings were summed up. In this seminar, as to economies of coal consumption countries and coal supply countries in the APEC region, discussions were made on coal supply/demand, coal price, environmental problems and others. The keynote address was 'Twenty first century coal in the APEC region and Republic of Korea' given by Mr. Gam Yeol Lee from Korea. The main theme of the seminar was 'The status quo for the coal market,' and lectures titled on the following were given from Japan: 'The status quo of coal purchase by the Japanese electric company and its outlook' and 'A perspective of coal fired IPP under environmental constraints and deregulation of electricity.' Lectures from Australia: 'Responding to coal market growth in APEC regions by the Australian coal industry' and 'The coal price impact on coal supply and demand.' Further discussions were made on 'The long-term outlook for coal supply/demand' and 'Economies report on the outlook for coal supply/demand.' (NEDO)

Coal -98

International Nuclear Information System (INIS)

Sparre, C.

1998-01-01

The following report deals with the use of coal and coke during 1997. Some information about technic, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from SCB have also been used. The use of steam coal for heating purposes during 1997 was 730 000 tons and about 500 000 tons lower than in 1996. The extremely high figures of 1996 were due to twice the production of electricity because of lack of hydro power. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generating plants. Some foreign analysts, however, estimate a doubled use of coal for energy use after 2020 because of the plans to phase out the nuclear power. During the top year 1987 coal was used in 18 hot water plants and 11 co-generation plants. 1997 these figures are 2 and 8. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. The import of metallurgical coal in 1997 was 1.6 mill tons like the year before. 1.2 mill tons coke were produced. The coke consumption in the industry was 1.5 Mill tons. 0.3 mill tons of coke were imported. Several other plants have plans to replace the coal with forest fuels, waste fuels and NG. Even the biggest plant, Vaesteraas, has plans to build a block for bio fuels. Helsingborg has started to use wood pellets. The pellets replace most of the coal for the heat production in the co-generation plant. Norrkoeping Kraft AB has taken a fluid bed boiler for different fuels in operation, leading to more than half the coal consumption compared with previous years. They have also rebuilt one of their travelling grates for bio fuels. Stockholm

Coal marketing manual 1987

Energy Technology Data Exchange (ETDEWEB)

1987-01-01

This manual provides information on the international coal market in tabulated format. Statistics are presented for the Australian coal industry, exports, currency movements, world coal production, coal and coke imports and exports. Detailed information is provided on the Australian coal industry including mine specific summaries. Pricing summaries for thermal and coking coal in 1987, coal quality standards and specifications, trends in coal prices and stocks. Imports and exports for World coal and coke, details of shipping, international ports and iron and steel production. An exporters index of Australian and overseas companies with industry and government contacts is included. 15 figs., 67 tabs.

Fiscal 1993 survey of the base arrangement promotion for foreign coal import. Survey of the general situation of Thai coal; 1993 nendo kaigaitan yunyu kiban seibi sokushin chosa. Thai sekitan sogo jijo chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-03-01

The paper reported the energy situation in Thailand, the present and future status of coal supply/demand, the present situation of environmental policy and air pollution prevention policy and problems concerning coal and the measures for solution, and a possibility of Japan`s cooperation. In Thailand, the total coal supply amount in 1992 is 16.079 million tons, which is 9.1% of all the primary energy supply amount. The country produces only a few amount of anthracite and subbituminous coal beside brown coal. The domestic coal equals brown coal, the production of which was 15.335 million tons in 1992, 13.9% of all the primary energy demand. Concerning brown coal, 79.7% of all the brown coal supply are for electric power use, and others for industrial use such as the cement industry. The remaining reserve in developed areas is 151.4 billion tons, and the proven reserve in undeveloped areas 756 million tons. The demand for import coal was 11.25 million tons in 1996, and is expected to be 201.73 million tons in 2000. The paper pointed out some problems arising from coal production and spread of coal utilization, and described measures to solve the problems and fields where there are possibilities of Japan`s cooperation. 36 refs., 44 figs., 73 tabs.

Workability of coal seams in the Upper Silesian Coal Basin

Energy Technology Data Exchange (ETDEWEB)

Sikora, W; Fels, M; Soltysik, K

1978-04-01

This paper presents results of an investigation on workability of coal seams of stratigraphic groups from 100 to 700 in the: Upper Silesian Coal Basin. Analyzed are 2900 petrographic logs taken in the longwall workings and in narrow openings as well as about 9000 individual samples. Workability of coal seams, floors and partings is determined. Workability is described by the indicator f, (according to the Protodyakonov shatter method) and the indicator U, (compression strength of the unshaped test samples). The mean percentage content of indivi dual petrographic groups of coal as well as the mean workability indicator, f, of coals in the stratigraphic groups of coal seams in Upper Silesia are also determined.

Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994

Energy Technology Data Exchange (ETDEWEB)

Hepworth, M.T.; Slimane, R.B.

1994-11-01

The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

Assessing coal burnout

Energy Technology Data Exchange (ETDEWEB)

Lowe, A. [Pacific Power, Sydney, NSW (Australia)

1999-11-01

Recent research has allowed a quantitative description of the basic process of burnout for pulverized coals to be made. The Cooperative Research Centre for Black Coal Utilization has built on this work to develop a coal combustion model which will allow plant engineers and coal company representatives to assess their coals for combustion performance. The paper describes the model and its validation and outlines how it is run. 2 figs.

Lightweight monitoring and control system for coal mine safety using REST style.

Science.gov (United States)

Cheng, Bo; Cheng, Xin; Chen, Junliang

2015-01-01

The complex environment of a coal mine requires the underground environment, devices and miners to be constantly monitored to ensure safe coal production. However, existing coal mines do not meet these coverage requirements because blind spots occur when using a wired network. In this paper, we develop a Web-based, lightweight remote monitoring and control platform using a wireless sensor network (WSN) with the REST style to collect temperature, humidity and methane concentration data in a coal mine using sensor nodes. This platform also collects information on personnel positions inside the mine. We implement a RESTful application programming interface (API) that provides access to underground sensors and instruments through the Web such that underground coal mine physical devices can be easily interfaced to remote monitoring and control applications. We also implement three different scenarios for Web-based, lightweight remote monitoring and control of coal mine safety and measure and analyze the system performance. Finally, we present the conclusions from this study and discuss future work. Copyright © 2014 ISA. Published by Elsevier Ltd. All rights reserved.

Ultravitrinite coals from Chukotka

Energy Technology Data Exchange (ETDEWEB)

Lapo, A.V.; Letushova, I.A.

1979-03-01

Chemical and petrographic analysis was conducted on coals from the Anadyrya and Bukhti Ugol'noi deposits. Characteristics of the most prevalent type of vitrinite coals in both regions are presented here. Anadyrya coals belong to a transitional phase between brown coal and long flame. Ultravitrinite coals predominate. Gas coals from Bukti Ugol'noi have a higher carbon content than Anadyrya coals. They also have a higher hydrogen content and yield of initial resin. In several cases there was also a higher yield of volatile substances. Chukotka coals are characterized by a 10 percent higher initial resin yield than equally coalified Donetsk coals, other indicators were equal to those of Donetsk coals. Because of this, Chukotka coals are suitable for fuel in power plants and as raw materials in the chemical industry. (15 refs.) (In Russian)

Post-test analysis of 20kW molten carbonate fuel cell stack operated on coal gas. Final report, August 1993--February 1996

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-05-01

A 20kW carbonate fuel cell stack was operated with coal gas for the first time in the world. The stack was tested for a total of 4,000 hours, of which 3,900 hours of testing was conducted at the Louisiana Gasification Technology Incorporated, Plaquemine, Louisiana outdoor site. The operation was on either natural gas or coal gas and switched several times without any effects, demonstrating duel fuel capabilities. This test was conducted with 9142 kJ/m{sup 3} (245 Btu/cft) coal gas provided by a slipstream from Destec`s entrained flow, slagging, slurry-fed gasifier equipped with a cold gas cleanup subsystem. The stack generated up to 21 kW with this coal gas. Following completion of this test, the stack was brought to Energy Research Corporation (ERC) and a detailed post-test analysis was conducted to identify any effects of coal gas on cell components. This investigation has shown that the direct fuel cell (DFC) can be operated with properly cleaned and humidified coal-as, providing stable performance. The basic C direct fuel cell component materials are stable and display normal stability in presence of the coal gas. No effects of the coal-borne contaminants are apparent. Further cell testing at ERC 1 17, confirmed these findings.

Acid leaching of coal: to produce clean fuels from Turkish lignite

Energy Technology Data Exchange (ETDEWEB)

Seferinoglu, Meryem [Mineral Research and Exploration Directorate (Turkey)], email: meryem_seferinoglu66@yahoo.com; Duzenli, Derya [Ankara Central Laboratory (Turkey)

2011-07-01

With the increasing concerns about the environment, energy producers and governments are looking at developing clean energy sources. However, Turkey has limited clean energy resources and is using low grade coal which has high sulphur content as an alternative energy source. The aim of this paper is to study the possibility of generating clean fuel from Edirne Lignite and to get a better understanding of chemical mechanisms involved in coal leaching with hydrofluoric acid (HF) solutions. Leaching was conducted on Edirne Lignite with HF solution at ambient temperature and the effects of parameters such as reaction time and concentration of acid solutions on the process were evaluated. The optimum conditions were found and it was shown that ash levels can be reduced from 28.9% to 10.5% and the calorific value increased by 500kcal/kg with the HF leaching method. This study demonstrated that the production of clean fuel from high sulphur lignite is possible.

Computer-aided planning of brown coal seam mining in regard to coal quality

Energy Technology Data Exchange (ETDEWEB)

Ciesielski, R.; Lehmann, A.; Rabe, H.; Richter, S.

1988-09-01

Discusses features of the geologic SORVER software developed at the Freiberg Fuel Institute, GDR. The program processes geologic data from exploratory wells, petrographic characteristics of a coal seam model, technological mining parameters and coal quality requirements of consumers. Brown coal reserves of coking coal, gasification coal, briquetting coal and steam coal are calculated. Vertical seam profiles and maps of seam horizon isolines can be plotted using the program. Coal quality reserves along the surface of mine benches, mining block widths and lengths for excavators, maximum possible production of individual coal qualities by selective mining, and coal quality losses due to mining procedures are determined. The program is regarded as a means of utilizing deposit reserves more efficiently. 5 refs.

COAL Conference Poster

OpenAIRE

Brown, Taylor Alexander; McGibbney, Lewis John

2017-01-01

COAL Conference Poster This archive contains the COAL conference poster for the AGU Fall Meeting 2017 by Taylor Alexander Brown. The Inkscape SVG source is available at https://github.com/capstone-coal/coal-conference-poster/ under the Creative Commons Attribution-ShareAlike 4.0 International license.

External cost of coal based electricity generation: A tale of Ahmedabad city

International Nuclear Information System (INIS)

Mahapatra, Diptiranjan; Shukla, Priyadarshi; Dhar, Subash

2012-01-01

Electricity production causes unintended impacts. Their exclusion by the market leads to suboptimal resource allocations. Monetizing and internalizing of external costs, though challenging and debatable, leads to a better allocation of economic resources and welfare. In this paper, a life-cycle analysis (LCA) on the production of electricity from conventional coal based electricity generation system has been performed in order to examine the environmental impacts of coal based electricity generating systems in the twin-city of Ahmedabad and Gandhinagar in western India. By using dose–response functions, we make an attempt to estimate the damages to human health, crops, and building materials resulting from the operation of coal power plants and its associated mines. Further, we use geographic information system to account for spatially dependent data. Finally, monetary values have been assigned to estimate the damage to human health, crops and building materials. This study reveals that the health as well as on non-health impacts of air pollution resulting from coal based electricity generation may not be ignored both in absolute as well as economic value terms. Highlights: ► External cost from coal power generating systems has been calculated. ► We use LCA approach to monetize externalities. ► Geographic information software has been used to account for spatially dependent data. ► This study monetizes damages only to human health, crops, and building materials. ► We finally recommend policy directions to arrest this externality.

Preparation and Evaluation of Adsorbents from Coal and Irvingia gabonensis Seed Shell for the Removal of Cd(II and Pb(II Ions from Aqueous Solutions

Directory of Open Access Journals (Sweden)

Mercy A. Ezeokonkwo

2018-01-01

Full Text Available Cd(II and Pb(II ions removal using adsorbents prepared from sub-bituminous coal, lignite, and a blend of coal and Irvingia gabonensis seed shells was investigated. Fourier transform infrared, scanning electron microscope and X-ray fluorescence analyses implicated hydroxyl, carbonyl, Al2O3, and SiO2 as being responsible for attaching the metal ions on the porous adsorbents. The optimum adsorption of carbonized lignite for the uptake of Cd(II and Pb(II ions from aqueous media were 80.93 and 87.85%, respectively. Batch adsorption was done by effect of adsorbent dosage, pH, contact time, temperature, particle size, and initial concentration. Equilibrium for the removal of Pb(II and Cd(II was established within 100 and 120 min respectively. Blending the lignite-derived adsorbent with I. gabonensis seed shell improved the performance significantly. More improvement was observed on modification of the blend using NaOH and H3PO4. Pb(II was preferentially adsorbed than Cd(II in all cases. Adsorption of Cd(II and Pb(II ions followed Langmuir isotherm. The adsorption kinetics was best described by pseudo-second order model. The potential for using a blend of coal and agricultural byproduct (I. gabonensis seed shell was found a viable alternative for removal of toxic heavy metals from aqueous solutions.