14 MeV INAA nitrogen determination in coal conversion liquids

International Nuclear Information System (INIS)

Ehmann, W.D.; Khalil, S.R.

1980-01-01

Fast neutron activation analysis has been used for the direct determination of nitrogen in coal conversion liqui-ds. In our previous work on coals, solid standards such as N-1-napthylacetamide, NBS SRM 912 urea and NBS SRM 148 nicotinic acid were used for nitrogen determinations. In this work, a set of organic liquids was selected and evaluated for use as nitrogen standards in the analysis of coal-derived liquids. The use of the liquid standards minimizes problems associated with maintaining uniform irradation and counting geometries and self absorption differences related to varying matrix densities. The standard liquids were selected using criteria of high boiling point, well-defined stoichiometry, high-purity, non-hygroscopic nature and simple C-H-N elemental compositions. Excellent agreement between the 14 MeV INAA data and calculated stoichiometric values has been demonstrated for liquids with nitrogen contents from 1.89 to 39.95%. The liquid standards have been used to determine nitrogen in a set of typical coal conversion liquids and several international standards. (author)

Energy Conversion Alternatives Study (ECAS), Westinghouse phase 1. Volume 2: Materials considerations. [materials used in boilers and heat exchangers of energy conversion systems for electric power plants using coal

Science.gov (United States)

Thomas, D. E.

1976-01-01

Extensive studies are presented which were carried out on materials behavior in nine advanced energy conversion systems employing coal and coal-derived fuels. The areas of materials behavior receiving particular attention in this regard are: (1) fireside corrosion and erosion in boiler and heat exchanger materials, (2) oxidation and hot corrosion of gas turbine materials, (3) liquid metal corrosion and mass transport, (4) high temperature steam corrosion, (5) compatability of materials with coal slag and MHD seed, (6) reaction of materials with impure helium, (7) allowable stresses for boiler and heat exchanger materials, (8) environmental effects on mechanical properties, and (9) liquid metal purity control and instrumentation. Such information was then utilized in recommending materials for use in the critical components of the power systems, and at the same time to identify materials problem areas and to evaluate qualitatively the difficulty of solving those problems. Specific materials recommendations for critical components of the nine advanced systems under study are contained in summary tables.

Coal liquefaction and gas conversion contractors review conference: Proceedings

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-11-01

This volume contains 55 papers presented at the conference. They are divided into the following topical sections: Direct liquefaction; Indirect liquefaction; Gas conversion (methane conversion); and Advanced research liquefaction. Papers in this last section deal mostly with coprocessing of coal with petroleum, plastics, and waste tires, and catalyst studies. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

Materials for coal conversion and utilization

Energy Technology Data Exchange (ETDEWEB)

None,

1981-01-01

The Sixth annual conference on materials for coal conversion and utilization was held October 13-15, 1981 at the National Bureau of Standards Gaithersburg, Maryland. It was sponsored by the US Department of Energy, the Electric Power Research Institute, the Gas Research Institute and the National Bureau of Standards. Fifty-eight papers from the proceedings have been entered individually into EDB and ERA; four papers had been entered previously from other sources. (LTN)

Energy conversion alternatives study

Science.gov (United States)

Shure, L. T.

1979-01-01

Comparison of coal based energy systems is given. Study identifies and compares various advanced energy conversion systems using coal or coal derived fuels for baselaoad electric power generation. Energy Conversion Alternatives Study (ECAS) reports provede government, industry, and general public with technically consistent basis for comparison of system's options of interest for fossilfired electric-utility application.

Survey of industrial coal conversion equipment capabilities: valves

Energy Technology Data Exchange (ETDEWEB)

Bush, W. A.; Slade, E. C.

1978-06-01

A survey of the industrial capabilities of the valve and valve-actuator industry to supply large, high-pressure stop valves for the future coal conversion industry is presented in this report. Also discussed are development and testing capabilities of valve and valve-actuator manufacturers and anticipated lead times required to manufacture advanced design valves for the most stringent service applications. Results indicate that the valve and valve-actuator industry is capable of manufacturing in quantity equipment of the size and for the pressure and temperature ranges which would be required in the coal conversion industry. Valve manufacturers do not, however, have sufficient product application experience to predict the continuing functional ability of valves used for lock-hopper feeders, slurry feeders, and slag-char letdown service. Developmental and testing efforts to modify existing valve designs or to develop new valve concepts for these applications were estimated to range from 1 to 6 years. A testing facility to simulate actuation of critical valves under service conditions would be beneficial.

New coal-based energy systems

International Nuclear Information System (INIS)

Barnert, H.

1986-01-01

Conversion of coal into liquid fuels or into coal gas is considered and the use of high temperature nuclear reactors whose waste heat can be used for remote (district) heating mentioned. The use of high temperature reactors as energy source for coal gasification is also examined and, finally, the extraction of heat from combined coal, steel and high temperature nuclear reactors is suggested. (G.M.E.)

Pocess for the conversion of coal into benzine

Energy Technology Data Exchange (ETDEWEB)

Jacob, S M; Kuo, J C.W.; Wise, J J; Garwood, W E

1976-10-21

The effective conversion of coal into liquid hydrocarbon benzine with a high octane number is described in the claimed method for coal enrichment. The coal is converted with O/sub 2/ and H/sub 2/O at about 788 to 982/sup 0/C giving a synthesis product (containing CO, CO/sub 2/, H/sub 2/ and CH/sub 4/). The conversion of the carbon oxides and hydrogen to a product containing H/sub 2/O, C/sup -//sub 4/gas and C/sup +//sub 5/ aromatic benzine is catalyzed with a catalyst consisting of a crystalline alumino silicate zeolite with a SiO/sub 2//AlO/sub 2/ ratio of at least 12 and a forced index of 1 to 12. The C/sup -//sub 4/gas is separated into a C/sup -//sub 2/residual gas (CH/sub 4/, C/sub 2/H/sub 6/, C/sub 2/H/sub 4/) and alkylation material (saturated and unsaturated C/sub 3/, C/sub 4/ hydrocarbons), the latter alkylated with strong acid at about 232/sup 0/C, 35.2Kg/cm/sup 2/ pressure, the C/sub 7//C/sub 8/ product is mixed with the aromatic benzine, the C/sup -//sub 2/residual gas steam reformed to an auxiliary synthesis gas and converted into a synthetic natural gas by methanation catalysts.

Chemical coal conversion yesterday, today, and tomorrow; Der Chemierohstoff Kohle: gestern, heute und morgen

Energy Technology Data Exchange (ETDEWEB)

Talbiersky, J. [UCP Chemicals AG, Wien (Austria)

2007-01-15

Shortage in mineral oil and gas as well as a high price level have caused a renaissance in coal conversion technologies, at the end of the 70's. Today we have a similar situation. Now coal coversion technologies will be in the focus again but hopefully as a longterm strategy. The most important coal conversion technologies as liquefaction, gasification, coking and calcium carbide synthesis are discussed regarding their use for the production of chemicals. The most important source for aromatic chemicals from coal is till now coal tar with an availability of 22 Mio. t/a. The manufacturing of coal tar is discussed as an example for making aromatic products from a complex feed stock that you get by the fixed bed gasification, coal liquefaction and coking. Also the special marketing strategy that is necessary to be competitive against products from the petroindustry. It can be expected, that coal gasification as a source for synthesis gas will become more and more important. Synthesis gas is the access to aliphatic hydrocarbons by Fischer Tropsch synthesis and to methanol, a chemical with a high synthetic potential. Also the new hydrothermal carbonization of biomass to synthetic coal is mentioned. (orig.)

Radiation-thermal processes of conversion in the coals

International Nuclear Information System (INIS)

Mustafaev, I.I.

2002-01-01

effect in the generation of active hydrocarbons radicals from fuel oil, which play active role in the conversion of organic coal mass to the liquid and gas products. Under the optimal condition ( T=450 degrees centigrade, P=0,1 MPa, τ=20-25 minutes, (Rh/L)=3/1), up to 58% of the cleaned Yeni koy lignites converted to liquid and gaseous products. The fraction of liquid products of Co-pyrolysis of coals with oil fraction at optimal condition is determined. It is obvious that because of the destruction effect of the accelerated electron beam up to 19,2% liquid products are light fractions Tb 0 C. In these conditions, more than 55% sulphur content of the lignites is separated in the form of H 2 S and COS. b)Gasification: The radiation-thermal gasification reactions of various types of carbon (graphite, active coal and semi coke) with H 2 0 and CO 2 have been studied. The radiation effects are essential at the temperatures lower 500 degrees centigrade. It is connected to reactions of decomposition of gasified agents (H 2 O, CO 2 ) and intermediate products of their decomposition (OH, CO 2 * and other). Studies have been made of the formation of H 2 and CO at temperatures between 20 and 700 degrees centigrade on reacting graphite, activated carbon and semi coke with steam and carbon dioxide, respectively, in the presence of gamma radiation. The highest rates of H 2 and CO formation were observed on the gasification of semi coke. Investigation has been made of the temperature of semi coke production from lignite and also of the effect of preirradiation dose on the rate of CO formation in the semi coke/CO 2 system. An increase in the semi coke production temperature from 500 to 700 degrees centigrade reduced its reactivity with carbon dioxide by a factor of 1.4. Preirradiation of the semi coke with 200 kJ/kg decrease the reactivity by a factor of 2.8. A discussion is given of the mechanism of the effect of gamma-radiation on the gasification processes of different carbons in

Monitoring temperatures in coal conversion and combustion processes via ultrasound

Science.gov (United States)

Gopalsami, N.; Raptis, A. C.; Mulcahey, T. P.

1980-02-01

The state of the art of instrumentation for monitoring temperatures in coal conversion and combustion systems is examined. The instrumentation types studied include thermocouples, radiation pyrometers, and acoustical thermometers. The capabilities and limitations of each type are reviewed. A feasibility study of the ultrasonic thermometry is described. A mathematical model of a pulse-echo ultrasonic temperature measurement system is developed using linear system theory. The mathematical model lends itself to the adaptation of generalized correlation techniques for the estimation of propagation delays. Computer simulations are made to test the efficacy of the signal processing techniques for noise-free as well as noisy signals. Based on the theoretical study, acoustic techniques to measure temperature in reactors and combustors are feasible.

Measurement and modeling of advanced coal conversion processes. Annual report, October 1990--September 1991

Energy Technology Data Exchange (ETDEWEB)

Solomon, P.R.; Serio, M.A.; Hamblen, D.G.; Smoot, L.D.; Brewster, B.S. [Advanced Fuel Research, Inc., East Hartford, CT (United States)]|[Brigham Young Univ., Provo, UT (United States)

1991-12-31

The overall objective of this program is the development of predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. This program will merge significant advances made in measuring and quantitatively describing the mechanisms in coal conversion behavior. Comprehensive computer codes for mechanistic modeling of entrained-bed gasification. Additional capabilities in predicting pollutant formation will be implemented and the technology will be expanded to fixed-bed reactors.

Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction

Energy Technology Data Exchange (ETDEWEB)

Polyakov, Oleg

2013-12-31

Under the cooperative agreement program of DOE and funding from Wyoming State’s Clean Coal Task Force, Western Research Institute and Thermosolv LLC studied the direct conversion of Wyoming coals and coal-lignin mixed feeds into liquid fuels in conditions highly relevant to practice. During the Phase I, catalytic direct liquefaction of sub-bituminous Wyoming coals was investigated. The process conditions and catalysts were identified that lead to a significant increase of desirable oil fraction in the products. The Phase II work focused on systematic study of solvothermal depolymerization (STD) and direct liquefaction (DCL) of carbonaceous feedstocks. The effect of the reaction conditions (the nature of solvent, solvent/lignin ratio, temperature, pressure, heating rate, and residence time) on STD was investigated. The effect of a number of various additives (including lignin, model lignin compounds, lignin-derivable chemicals, and inorganic radical initiators), solvents, and catalysts on DCL has been studied. Although a significant progress has been achieved in developing solvothermal depolymerization, the side reactions – formation of considerable amounts of char and gaseous products – as well as other drawbacks do not render aqueous media as the most appropriate choice for commercial implementation of STD for processing coals and lignins. The trends and effects discovered in DCL point at the specific features of liquefaction mechanism that are currently underutilized yet could be exploited to intensify the process. A judicious choice of catalysts, solvents, and additives might enable practical and economically efficient direct conversion of Wyoming coals into liquid fuels.

Proceedings of the third annual underground coal conversion symposium

Energy Technology Data Exchange (ETDEWEB)

None

1977-01-01

The Third Annual Underground Coal Conversion Symposium was held at Fallen Leaf Lake, CA, June 6--9, 1977. It was sponsored by the U.S. Department of Energy and hosted by Lawrence Livermore Laboratory. Forty-one papers have been entered individually into EDB and ERA; ten papers had been entered previously from other sources. The papers cover the in-situ gasification of lignite, subbituminous coal and bituminous coal, in flat lying seams and a steeply dipping beds, at moderate and at greater depths, and describe various technologies of (borehole linking, well spacings, gasifying agents (air, oxygen, steam, hydrogen, including mixtures). Measuring instruments for diagnostic and process control purposes are described. Environmental impacts (ground subsidence and possible groundwater pollution) are the subject of several papers. Finally, mathematical modelling and projected economics of the process are developed. (LTN)

Biological conversion of coal synthesis gas to methane

Energy Technology Data Exchange (ETDEWEB)

Barik, S; Corder, R E; Clausen, E C; Gaddy, J L

1987-09-01

High temperatures and pressures are required, and therefore, high costs incurred during catalytic upgrading of coal synthesis gas to methane. Thus, the feasibility of biological reactions in converting synthesis gas to methane has been demonstrated in mixed and pure cultures. Complete conversion has been achieved in 2 hours with a mixed culture, and 45 minutes to 1.5 hours in pure cultures of P. productus and Methanothrix sp.. Typical sulfur levels involved during the process are found not to inhibit the bacteria and so sulfur does not have to be removed prior to biomethanation. Preliminary economic analyses indicate that coal gas may be biologically methanated for 50-60 cents/million Btu. Further studies with pure culture bacteria and increased pressure are expected to enhance biomethanation economics.

Nitrogen conversion during rapid pyrolysis of coal and petroleum coke in a high-frequency furnace

International Nuclear Information System (INIS)

Yuan, Shuai; Zhou, Zhi-jie; Li, Jun; Wang, Fu-chen

2012-01-01

Highlights: ► Use a high-frequency furnace to study N-conversion during rapid pyrolysis of coal. ► Scarcely reported N-conversion during rapid pyrolysis of petroleum coke was studied. ► Both of NH 3 and HCN can be formed directly from coal during rapid pyrolysis. ► NH 3 –N yields are higher than HCN–N yields in most conditions. ► NH 3 –N yields of petroleum coke increase with temperature and no HCN detected. -- Abstract: Rapid pyrolysis of three typical Chinese coals, lignite from Inner Mongolia, bituminous from Shenfu coalfield, and anthracite from Guizhou, as well as a petroleum coke were carried out in a drop-style high-frequency furnace. The reactor was induction coil heated and had a very small high-temperature zone, which could restrain secondary conversions of nitrogen products. The effects of temperature and coal rank on conversions of fuel-N to primary nitrogen products (char-N, HCN–N, NH 3 –N and (tar + N 2 )–N) have been investigated. The results showed that, the increasing temperature reduced the yields of char-N and promoted the conversion of fuel-N to N 2 . Char-N yields increased, while volatile-N yields decreased as the coal rank increased. In most of the conditions, NH 3 –N yields were higher than HCN–N yields during rapid pyrolysis of coal. In the case of petroleum coke, NH 3 –N yields increased gradually with the increasing temperature, but no HCN was detected. We argue that NH 3 –N can be formed directly through the primary pyrolysis without secondary reactions. Although volatile-N yields of lignite were higher than those of bituminous, yields of (HCN + NH 3 )–N in volatile-N of lignite were lower than those of bituminous. While the (HCN + NH 3 )–N yields of anthracite were the lowest of the three coals. Both of the (HCN + NH 3 )–N yields and (HCN + NH 3 )–N proportions in volatile-N of petroleum coke were lower than the three coals.

Comparison of coal reactivity during conversion into different oxidizing medium

International Nuclear Information System (INIS)

Korotkikh, A G; Slyusarskiy, K V; Larionov, K B; Osipov, V I

2016-01-01

Acoal conversion process of different coal samples into three different types of oxidizing medium (argon, air and steam) were studied by means of thermogravimetry. Two coal types with different metamorphism degree (lignite and bituminous coal) were used. The experimental procedure was carried out in non-isothermal conditions in temperature range from 373 K to 1273 K with 20 K/min heating rate. Purge gas consisted of argon and oxidizer with volumetric ratio 1:24 and had 250 ml/min flow rate.The ignition and burnout indexes were calculated to evaluate sample reactivity at different oxidizing mediums. The highest reactivity coefficient values in same atmosphere were obtained for lignite. It was caused by higher particle special surface area and volatile matter content. (paper)

Coal to SNG: Technical progress, modeling and system optimization through exergy analysis

International Nuclear Information System (INIS)

Li, Sheng; Ji, Xiaozhou; Zhang, Xiaosong; Gao, Lin; Jin, Hongguang

2014-01-01

Highlights: • Technical progresses of coal to SNG technologies are reported. • The entire coal to SNG system is modeled. • Coupling between SNG production and power generation is investigated. • Breakthrough points for further energy saving are determined. • System performance is optimized based on the first and second laws of thermodynamics. - Abstract: For both energy security and CO 2 emission reduction, synthetic natural gas (SNG) production from coal is an important path to implement clean coal technologies in China. In this paper, an overview of the progress of coal to SNG technologies, including the development of catalysts, reactor designs, synthesis processes, and systems integration, is provided. The coal to SNG system is modeled, the coupling between SNG production and power generation is investigated, the breakthrough points for further energy savings are determined, and the system performance is optimized based on the first and the second laws of thermodynamics. From the viewpoint of the first law of thermodynamics, the energy conversion efficiency of coal to SNG system can reach 59.8%. To reduce the plant auxiliary power, the breakthrough points are the development of low-energy-consumption oxygen production technology and gas purification technology or seeking new oxidants for coal gasification instead of oxygen. From the viewpoint of the second law of thermodynamics, the major exergy destruction in a coal to SNG system occurs in the coal gasification unit, SNG synthesis unit and the raw syngas cooling process. How to reduce the exergy destruction in these units is the key to energy savings and system performance enhancement. The conversion ratio of the first SNG synthesis reactor and the split ratio of the recycle gas are key factors that determine the performance of both the SNG synthesis process and the whole plant. A “turning point” phenomenon is observed: when the split ratio is higher than 0.90, the exergy destruction of the SNG

Evaluation of a Compact Coaxial Underground Coal Gasification System Inside an Artificial Coal Seam

Directory of Open Access Journals (Sweden)

Fa-qiang Su

2018-04-01

Full Text Available The Underground Coal Gasification (UCG system is a clean technology for obtaining energy from coal. The coaxial UCG system is supposed to be compact and flexible in order to adapt to complicated geological conditions caused by the existence of faults and folds in the ground. In this study, the application of a coaxial UCG system with a horizontal well is discussed, by means of an ex situ model UCG experiment in a large-scale simulated coal seam with dimensions of 550 × 600 × 2740 mm. A horizontal well with a 45-mm diameter and a 2600-mm length was used as an injection/production well. During the experiment, changes in temperature field and product gas compositions were observed when changing the outlet position of the injection pipe. It was found that the UCG reactor is unstable and expands continuously due to fracturing activity caused by coal crack initiation and extension under the influence of thermal stress. Therefore, acoustic emission (AE is considered an effective tool to monitor fracturing activities and visualize the gasification zone of coal. The results gathered from monitoring of AEs agree with the measured data of temperatures; the source location of AE was detected around the region where temperature increased. The average calorific value of the produced gas was 6.85 MJ/Nm3, and the gasification efficiency, defined as the conversion efficiency of the gasified coal to syngas, was 65.43%, in the whole experimental process. The study results suggest that the recovered coal energy from a coaxial UCG system is comparable to that of a conventional UCG system. Therefore, a coaxial UCG system may be a feasible option to utilize abandoned underground coal resources without mining.

Coal conversion process by the United Power Plants of Westphalia

Energy Technology Data Exchange (ETDEWEB)

1974-08-01

The coal conversion process used by the United Power Plants of Westphalia and its possible applications are described. In this process, the crushed and predried coal is degassed and partly gasified in a gas generator, during which time the sulfur present in the coal is converted into hydrogen sulfide, which together with the carbon dioxide is subsequently washed out and possibly utilized or marketed. The residual coke together with the ashes and tar is then sent to the melting chamber of the steam generator where the ashes are removed. After desulfurization, the purified gas is fed into an external circuit and/or to a gas turbine for electricity generation. The raw gas from the gas generator can be directly used as fuel in a conventional power plant. The calorific value of the purified gas varies from 3200 to 3500 kcal/cu m. The purified gas can be used as reducing agent, heating gas, as raw material for various chemical processes, or be conveyed via pipelines to remote areas for electricity generation. The conversion process has the advantages of increased economy of electricity generation with desulfurization, of additional gas generation, and, in long-term prospects, of the use of the waste heat from high-temperature nuclear reactors for this process.

Pyrolysis and liquefaction of acetone and mixed acetone/ tetralin swelled Mukah Balingian Malaysian sub-bituminous coal-The effect on coal conversion and oil yield

International Nuclear Information System (INIS)

Mohd Pauzi Abdullah; Mohd Azlan Mohd Ishak; Khudzir Ismail

2008-01-01

The effect of swelling on Mukah Balingian (MB) Malaysian sub-bituminous coal macrostructure was observed by pyrolysing the swelled coal via thermogravimetry under nitrogen at ambient pressure. The DTG curves of the pyrolyzed swelled coal samples show the presence of evolution peaks at temperature ranging from 235 - 295 degree Celsius that are due to releasing of light molecular weight hydrocarbons. These peaks, however, were not present in the untreated coal, indicating some changes in the coal macrostructure has occurred in the swelled coal samples. The global pyrolysis kinetics for coal that follows the first-order decomposition reaction was used to evaluate the activation energy of the pyrolyzed untreated and swelled coal samples. The results thus far have shown that the activation energy for the acetone and mixed acetone/ tetralin-swelled coal samples exhibit lower values than untreated coal, indicating less energy is required during the pyrolysis process due to the weakening of the coal-coal macromolecular interaction network. Moreover, liquefaction on the swelled coal samples that was carried out at temperatures ranging from 360 to 450 degree Celsius at 4 MPa of nitrogen pressure showed the enhancement of the coal conversion and oil yield at temperature of 420 degree Celsius, with retrogressive reaction started to dominate at higher temperature as indicated by decreased and increased in oil yield and high molecular weight pre-asphaltene, respectively. These observations suggest that the solvent swelling pre-treatment using acetone and mixed acetone/ tetralin can improve the coal conversion and oil yields at less severe liquefaction condition. (author)

Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base

International Nuclear Information System (INIS)

Croft, Gregory D.; Patzek, Tad W.

2009-01-01

By applying the multi-Hubbert curve analysis to coal production in the United States, we demonstrate that anthracite production can be modeled with a single Hubbert curve that extends to the practical end of commercial production of this highest-rank coal. The production of bituminous coal from existing mines is about 80% complete and can be carried out at the current rate for the next 20 years. The production of subbituminous coal from existing mines can be carried out at the current rate for 40-45 years. Significant new investment to extend the existing mines and build new ones would have to commence in 2009 to sustain the current rate of coal production, 1 billion tons per year, in 2029. In view of the existing data, we conclude that there is no spare coal production capacity of the size required for massive coal conversion to liquid transportation fuels. Our analysis is independent of other factors that will prevent large-scale coal liquefaction projects: the inefficiency of the process and either emissions of greenhouse gases or energy cost of sequestration

A Reduced Reaction Scheme for Volatile Nitrogen Conversion in Coal Combustion

DEFF Research Database (Denmark)

Pedersen, Lars Saaby; Glarborg, Peter; Dam-Johansen, Kim

1998-01-01

In pulverised coal flames, the most important volatile nitrogen component forming NOx is HCN. To be able to model the nitrogen chemistry in coal flames it is necessary to have an adequate model for HCN oxidation. The present work was concerned with developing a model for HCN/NH3/NO conversion based...... that the CO/H-2 chemistry was described adequately, the reduced HCN/NH3/NO model compared very well with the detailed model over a wide range of stoichiometries. Decoupling of the HCN chemistry from the CO/H-2 chemistry resulted in over-prediction of the HCN oxidation rate under fuel rich conditions, but had...... negligible effect on the CO/H-2 chemistry. Comparison with simplified HCN models from the literature revealed significant differences, indicating that these models should be used cautiously in modelling volatile nitrogen conversion....

Proceedings of the 5th underground coal conversion symposium

Energy Technology Data Exchange (ETDEWEB)

None

1979-05-01

The 5th underground coal conversion symposium was held at Alexandria, Virginia, June 18--21, 1979. Thirty-three papers have been entered individually into EDB and ERA. Seven papers were also abstracted for Energy Abstracts for Policy Analysis. Seven papers had been entered previously from other sources. The symposium was sponsored by the US Department of Energy, Division of Fossil Fuel Extraction. (LTN)

COAL CONVERSION WASTEWATER TREATMENT BY CATALYTIC OXIDATION IN SUPERCRITICAL WATER; FINAL

International Nuclear Information System (INIS)

Phillip E. Savage

1999-01-01

Wastewaters from coal-conversion processes contain phenolic compounds in appreciable concentrations. These compounds need to be removed so that the water can be discharged or re-used. Catalytic oxidation in supercritical water is one potential means of treating coal-conversion wastewaters, and this project examined the reactions of phenol over different heterogeneous oxidation catalysts in supercritical water. More specifically, we examined the oxidation of phenol over a commercial catalyst and over bulk MnO(sub 2), bulk TiO(sub 2), and CuO supported on Al(sub 2) O(sub 3). We used phenol as the model pollutant because it is ubiquitous in coal-conversion wastewaters and there is a large database for non-catalytic supercritical water oxidation (SCWO) with which we can contrast results from catalytic SCWO. The overall objective of this research project is to obtain the reaction engineering information required to evaluate the utility of catalytic supercritical water oxidation for treating wastes arising from coal conversion processes. All four materials were active for catalytic supercritical water oxidation. Indeed, all four materials produced phenol conversions and CO(sub 2) yields in excess of those obtained from purely homogeneous, uncatalyzed oxidation reactions. The commercial catalyst was so active that we could not reliably measure reaction rates that were not limited by pore diffusion. Therefore, we performed experiments with bulk transition metal oxides. The bulk MnO(sub 2) and TiO(sub 2) catalysts enhance both the phenol disappearance and CO(sub 2) formation rates during SCWO. MnO(sub 2) does not affect the selectivity to CO(sub 2), or to the phenol dimers at a given phenol conversion. However, the selectivities to CO(sub 2) are increased and the selectivities to phenol dimers are decreased in the presence of TiO(sub 2) , which are desirable trends for a catalytic SCWO process. The role of the catalyst appears to be accelerating the rate of formation of

Measurement and modeling of advanced coal conversion processes. Twenty-first quarterly report, October 1, 1991--December 31, 1991

Energy Technology Data Exchange (ETDEWEB)

Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [Advanced Fuel Research, Inc., East Hartford, CT (United States); Smoot, L.D.; Brewster, B.S. [Brigham Young Univ., Provo, UT (United States)

1991-12-31

The objective of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines.

Measurement and modeling of advanced coal conversion processes. 19th quarterly report, April 1, 1991--June 30, 1991

Energy Technology Data Exchange (ETDEWEB)

Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [Advanced Fuel Research, Inc., East Hartford, CT (United States); Smoot, L.D.; Brewster, B.S. [Brigham Young Univ., Provo, UT (United States)

1991-09-25

The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

Biological CO2 conversion to acetate in subsurface coal-sand formation using a high-pressure reactor system

Directory of Open Access Journals (Sweden)

Yoko eOhtomo

2013-12-01

Full Text Available Geological CO2 sequestration in unmineable subsurface oil/gas fields and coal formations has been proposed as a means of reducing anthropogenic greenhouse gasses in the atmosphere. However, the feasibility of injecting CO2 into subsurface depends upon a variety of geological and economic conditions, and the ecological consequences are largely unpredictable. In this study, we developed a new flow-through-type reactor system to examine potential geophysical, geochemical and microbiological impacts associated with CO2 injection by simulating in situ pressure (0–100 MPa and temperature (0–70°C conditions. Using the reactor system, anaerobic artificial fluid and CO2 (flow rate: 0.002 and 0.00001 mL/min, respectively were continuously supplemented into a column comprised of bituminous coal and sand under a pore pressure of 40 MPa (confined pressure: 41 MPa at 40°C for 56 days. 16S rRNA gene analysis of the bacterial components showed distinct spatial separation of the predominant taxa in the coal and sand over the course of the experiment. Cultivation experiments using sub-sampled fluids revealed that some microbes survived, or were metabolically active, under CO2-rich conditions. However, no methanogens were activated during the experiment, even though hydrogenotrophic and methylotrophic methanogens were obtained from conventional batch-type cultivation at 20°C. During the reactor experiment, the acetate and methanol concentration in the fluids increased while the δ13Cacetate, H2 and CO2 concentrations decreased, indicating the occurrence of homo-acetogenesis. 16S rRNA genes of homo-acetogenic spore-forming bacteria related to the genus Sporomusa were consistently detected from the sandstone after the reactor experiment. Our results suggest that the injection of CO2 into a natural coal-sand formation preferentially stimulates homo-acetogenesis rather than methanogenesis, and that this process is accompanied by biogenic CO2 conversion to

Process for complete conversion of coal oils, shale oils, etc

Energy Technology Data Exchange (ETDEWEB)

Dubois, P

1911-07-08

A process is described for complete conversion of mineral coal oil, shale oil, and other similar oils in pitch, characterized by these oils being mixed with a nonvolatile substance with a boiling point on the average higher than the boiling point of the oil to be treated, and then being heated under pressure with the introduction of air, whereby the heating is interrupted if necessary on account of the known exothermic reaction and the conversion of the oil in the pitch or its distillation can be carried out without further heating.

Effect of ultrafine iron and mineral matter on conversion of nitrogen and carbon during pyrolysis and gasification of coal

Energy Technology Data Exchange (ETDEWEB)

Ohtsuka, Y.; Furimsky, E. [Tohoku University, Sendai (Japan). Inst. for Chemical Reaction Science

1995-01-01

A subbituminous coal was used to determine the distribution of N{sub 2}, NH{sub 3}, and HCN during slow rate heating pyrolysis in He and gasification in 10% CO{sub 2} + He balance. During pyrolysis, the N{sub 2} was the major product followed by NH{sub 3} and HCN. During gasification, the N{sub 2} yields were significantly enhanced and those of NH{sub 3} and HCN decreased. Partial demineralization of coal resulted in a decrease in carbon and nitrogen conversion. This effect was also evident by comparing the nitrogen and carbon conversions of chars prepared at 500{degree}C from the fresh and demineralized coals. The addition of ultrafine Fe to coal increased conversion of carbon and nitrogen to N{sub 2} during gasification but had little effect during pyrolysis. Thus, during the former more than 80% of the coal nitrogen was released as N{sub 2}. Also, in the presence of Fe the temperature of N{sub 2} release was decreased by about 100{degree}C both during pyrolysis and gasification. During gasification of chars prepared at 1000{degree}C, the conversion of the coal nitrogen to N{sub 2} was much lower than that of carbon. 16 refs., 9 figs., 3 tabs.

Biological CO2 conversion to acetate in subsurface coal-sand formation using a high-pressure reactor system

Science.gov (United States)

Ohtomo, Y.; Ijiri, A.; Ikegawa, Y.; Tsutsumi, M.; Imachi, H.; Uramoto, G.; Hoshino, T.; Morono, Y.; Tanikawa, W.; Hirose, T.; Inagaki, F.

2013-12-01

The geological CO2 sequestration into subsurface unmineable oil/gas fields and coal formations has been considered as one of the possible ways to reduce dispersal of anthropogenic greenhouse gasses into the atmosphere. However, feasibility of CO2 injection largely depends on a variety of geological and economical settings, and its ecological consequences have remained largely unpredictable. To address these issues, we developed a new flow-through-type CO2 injection system designated as the 'geobio-reactor system' to examine possible geophysical, geochemical and microbiological impact caused by CO2 injection under in-situ pressure (0-100 MPa) and temperature (0-70°C) conditions. In this study, we investigated Eocene bituminous coal-sandstones in the northwestern Pacific coast, Hokkaido, Japan, using the geobio-reactor system. Anaerobic artificial fluid and CO2 (flow rate: 0.002 and 0.00001 mL/min, respectively) were continuously supplemented into the coal-sand column under the pore pressure of 40 MPa (confined pressure: 41 MPa) at 40°C for 56 days. Molecular analysis of bacterial 16S rRNA genes showed that predominant bacterial components were physically dispersed from coal to sand as the intact form during experiment. Cultivation experiments from sub-sampling fluids indicated that some terrestrial microbes could preserve their survival in subsurface condition. Molecular analysis of archaeal 16S rRNA genes also showed that no methanogens were activated during experiment. We also anaerobically incubated the coal sample using conventional batch-type cultivation technique with a medium for methanogens. After one year of the batch incubation at 20°C, methane could be detected from the cultures except for the acetate-fed culture. The sequence of archaeal 16S rRNA genes via PCR amplification obtained from the H2 plus formate-fed culture was affiliated with a hydrogenotrophic methanogen within the genus Methanobacterium, whereas the methanol plus trimethylamine culture

Superacid Catalyzed Depolymerization and Conversion of Coals. Final Technical Report. [HF:BF{sub 2}/H{sub 2}

Science.gov (United States)

Olah, G.

1980-01-01

We were interested in applying superacid catalyzed cleavage-depolymerization and ionic hydrogenation low temperature conversion of coal to liquid hydrocarbon, as well as obtaining information about the reactions involved and the structure of intermediates of the coal liquefaction process. In order to show the feasibility of our proposed research we have carried out preliminary investigation in these areas. Preceding our work there was no practical application of a superacid system to coal liquefaction. We carried out an extensive study of the potential of the HF:BF{sub 3}/H{sub 2} system for coal hydroliquefaction. Under varying conditions of reactant ratio, reaction time and temperature, we were able to obtain over 95% pyridine extractible product by treating coal in HF:BF{sub 3}:H{sub 2} system at approx. 100 degrees C for 4 hours. The coal to acid ratio was 1:5 and FB{sub 3} at 900 psi and H{sub 2} at 500 psi were used. These are extremely encouraging results in that the conditions used are drastically milder than those used in any known process, such as Exxon donor solvent and related processes. The cyclohexane extractibility of the treated coal was as high as 27% and the yield of liquid distillate at 400 degrees C/5 x 10{sup -3}/sup torr/ was approx. 30%. The infrared spectrum of product coal, extracts and distillates were distinctly different from the starting coal and show a significant increase in the amount of saturates. The {sup 1}H NMR spectrum of cyclohexane extract of the treated coal shows essentially all aliphatic photons. The spectra of other treated coal extracts show increased amounts and types of aliphatic protons as well as significant amounts of protons bound to unsaturated sites. This again indicates that the HF-BF{sub 3} system is depolymerizing the coal to small fragments which are soluble in non-polar solvents.

Critical evaluation of high-temperature gas-cooled reactors applicable to coal conversion

International Nuclear Information System (INIS)

Spiewak, I.; Jones, J.E. Jr.; Rittenhouse, P.L.; DeStefano, J.R.; Delene, J.G.

1975-12-01

A critical review is presented of the technology and costs of very high-temperature gas-cooled reactors (VHTRs) applicable to nuclear coal conversion. Coal conversion processes suitable for coupling to reactors are described. Vendor concepts of the VHTR are summarized. The materials requirements as a function of process temperature in the range 1400 to 2000 0 F are analyzed. Components, environmental and safety factors, economics and nuclear fuel cycles are reviewed. It is concluded that process heat supply in the range 1400 to 1500 0 F could be developed with a high degree of assurance. Process heat at 1600 0 F would require considerably more materials development. While temperatures up to 2000 0 F appear to be attainable, considerably more research and risk were involved. A demonstration plant would be required as a step in the commercialization of the VHTR

Fourth annual conference on materials for coal conversion and utilization

Energy Technology Data Exchange (ETDEWEB)

1979-01-01

The fourth annual conference on materials for coal conversion and utilization was held October 9 to 11, 1979, at the National Bureau of Standards, Gaithersburg, Maryland. It was sponsored by the National Bureau of Standards, the Electric Power Research Institute, the US Department of Energy, and the Gas Research Institute. The papers have been entered individually into EDB and ERA. (LTN)

Ninth annual international Pittsburgh coal conference - proceedings

International Nuclear Information System (INIS)

Anon.

1992-01-01

Over 200 papers are presented under the following headings: coal preparation; Clean Coal Technology Program status; pre- and post-utilization processing; advanced conversion technologies; integrated gasification combined cycle; indirect liquefaction; advanced liquefaction process development; conversion processes; coal - from a user's perspective; issues associated with coal use in heat engines; fundamentals of combustion; advanced combustion systems; low quality fuel applications/fluidised beds; combustion systems; ash and sludge disposal/utilization; developing SO 2 /NO x control technologies; technical overview of air toxics; scientific, economic and policy perspectives on global climate change; Clean Air Act compliance strategies; environmental policy/technology; spontaneous combustion; and special topics

Low temperature coal depolymerization-liquefaction: conversion of a North Dakota lignite to a light hydrocarbon oil

Energy Technology Data Exchange (ETDEWEB)

Shabtai, J.; Yuan Zhang (University of Utah, Salt Lake City, UT (USA). Dept. of Fuels Engineering)

1989-10-01

A new low temperature method of coal liquefaction is described which includes intercalation of the coal with FeCl{sub 3}, depolymerization under supercritical conditions, and hydroprocessing of the depolymerized product. Results indicate a high yield conversion of lignites to light hydrocarbon oils. 6 refs., 4 figs., 1 tab.

Energy conservation in coal conversion. Final report, September 15, 1977--September 1, 1978. Selected case studies and conservation methodologies

Energy Technology Data Exchange (ETDEWEB)

Purcupile, J.C.

1978-09-01

The purpose of this study is to apply the methodologies developed in the Energy Conservation in Coal Conversion August, 1977 Progress Report - Contract No. EY77S024196 - to an energy efficient, near-term coal conversion process design, and to develop additional, general techniques for studying energy conservation and utilization in coal conversion processes. The process selected for study was the Ralph M. Parsons Company of Pasadena, California ''Oil/Gas Complex, Conceptual Design/Economic Analysis'' as described in R and D Report No. 114 - Interim Report No. 4, published March, 1977, ERDA Contract No. E(49-18)-1975. Thirteen papers representing possible alternative methods of energy conservation or waste heat utilization have been entered individually into EDB and ERA. (LTN)

Comparative Evaluation of Phase 1 Results from the Energy Conversion Alternatives Study (ECAS). [coal utilization for electric power plants feasibility analysis

Science.gov (United States)

1976-01-01

Ten advanced energy conversion systems for central-station, based-load electric power generation using coal and coal-derived fuels which were studied by NASA are presented. Various contractors were selected by competitive bidding to study these systems. A comparative evaluation is provided of the contractor results on both a system-by-system and an overall basis. Ground rules specified by NASA, such as coal specifications, fuel costs, labor costs, method of cost comparison, escalation and interest during construction, fixed charges, emission standards, and environmental conditions, are presented. Each system discussion includes the potential advantages of the system, the scope of each contractor's analysis, typical schematics of systems, comparison of cost of electricity and efficiency for each contractor, identification and reconciliation of differences, identification of future improvements, and discussion of outside comments. Considerations common to all systems, such as materials and furnaces, are also discussed. Results of selected in-house analyses are presented, in addition to contractor data. The results for all systems are then compared.

Conversion of coal mining regions of France. La reconversion de la mineria del carbon en Francia

Energy Technology Data Exchange (ETDEWEB)

Torres, A.

1990-08-01

This programme of drastic reduction in coal mining in France has been made possible by the Economic Conversion Plan for the Coalfields. The Plan takes account of all areas of work affected by the reduction in coal mining and will assist in maintaining or even increase economic activity in the areas involved.

Possible improvements of efficiency by the use of new coal conversion technologies

International Nuclear Information System (INIS)

Krieb, K.H.

1976-01-01

Following a comparison of the efficiencies of conventional steam power processes, the gas fuel cell and the combined gas steam turbine processes are introduced as new coal utilization technologies. Coal conversion processes which can be coupled to combined gas-steam turbine processes such as the fluidized-bed firing, the solid bed gasification, the dust part-gasification and the fluidized-bed gasification are more closely mentioned and their coupling efficiencies discussed. The decoupling of third energy, such as low-temperature heat, high-temperature heat and chemical energy are briefly dealt with as third possibility for the improvement of the efficiency. (GG/LH) [de

Rationale for continuing R&D in direct coal conversion to produce high quality transportation fuels

Energy Technology Data Exchange (ETDEWEB)

Srivastava, R.D.; McIlvried, H.G. [Burns and Roe Services Corp., Pittsburgh, PA (United States); Gray, D. [Mitre Corp, McLean, VA (United States)] [and others

1995-12-31

For the foreseeable future, liquid hydrocarbon fuels will play a significant role in the transportation sector of both the United States and the world. Factors favoring these fuels include convenience, high energy density, and the vast existing infrastructure for their production and use. At present the U.S. consumes about 26% of the world supply of petroleum, but this situation is expected to change because of declining domestic production and increasing competition for imports from countries with developing economies. A scenario and time frame are developed in which declining world resources will generate a shortfall in petroleum supply that can be allieviated in part by utilizing the abundant domestic coal resource base. One option is direct coal conversion to liquid transportation fuels. Continued R&D in coal conversion technology will results in improved technical readiness that can significantly reduce costs so that synfuels can compete economically in a time frame to address the shortfall.

Reaction of methane with coal

Energy Technology Data Exchange (ETDEWEB)

Yang, K.; Batts, B.D.; Wilson, M.A.; Gorbaty, M.L.; Maa, P.S.; Long, M.A.; He, S.J.X.; Attala, M.I. [Macquarie University, Macquarie, NSW (Australia). School of Chemistry

1997-10-01

A study of the reactivities of Australian coals and one American coal with methane or methane-hydrogen mixtures, in the range 350-400{degree}C and a range of pressures (6.0-8.3 MPa, cold) is reported. The effects of aluminophosphates (AIPO) or zeolite catalysts, with and without exchanged metals, on reactivity have also been examined. Yields of dichloromethane extractable material are increased by using a methane rather than a nitrogen atmosphere and different catalysts assist dissolution to various extends. It appears that surface exchanged catalysts are effective, but incorporating metals during AIPO lattice formation is detrimental. Aluminium phosphate catalysts are unstable to water produced during coal conversion, but are still able to increase extraction yields. For the American coal, under methane-hydrogen and a copper exchanged zeolite, 51.5% conversion was obtained, with a product selectivity close to that obtained under hydrogen alone, and with only 2% hydrogen consumption. The conversion under methane-hydrogen was also to that obtained under hydrogen alone, while a linear dependence of conversion on proportion of methane would predict a 43% conversion under methane-hydrogen. This illustrates a synergistic effect of the methane-hydrogen atmosphere for coal liquefaction using this catalyst systems. 31 refs., 5 figs., 7 tabs.

Report of National Research Institute for Pollution and Resources for fiscal 1979. Research on conversion of coal to petroleum, research on coal liquefaction, high pressure liquid phase hydrogenation of coal by continuous test equipment, and manufacture of coal chemicals; 1979 nendo sekitan no yuka no kenkyu / sekitan no ekika no kenkyu / renzoku shiken sochi ni yoru sekitan no koatsu ekiso suisoka bunkai / coal chemicals no seizo

Energy Technology Data Exchange (ETDEWEB)

NONE

1980-07-01

Research was conducted on conversion of coal to petroleum for the purpose of securing substitute liquid fuel. Recovery of hydrogen from the waste gas from the conversion process was explained, as were the conversion results from various coals produced in Japan. In coal liquefaction researches with the aim of manufacturing artificial petroleum, a report was made on each of the researches, i.e., the experiment results of coal liquefaction using various catalysts, manufacture of hydrogen by water gas reaction, catalytic action against coal paste, action of mixed oil and pressure against coal paste, result of hydrogen adding test for coal paste using an intermediate scale device, test result of secondary hydrogen addition for coal liquefied oil, and the test result of continuous secondary hydrogen addition for the liquefied oil. In the manufacture of fuel oil by hydro-cracking of coal or tar, a report was made on high pressure liquid phase hydrogenation of coal using a continuous testing device. Aromatic chemicals useful as chemical materials are supposed to be obtained by cutting inter-polymerized-unit bonding to make low molecules from the chemical structure of coal, removing surrounding radicals and simplifying it. A report was also made on the experiment of manufacturing coal chemicals by combination of high pressure liquid phase hydrogenation and hydro-dealkylation. (NEDO)

Complete biocycle for solar energy conversion, storage, fuel and power generation, and coal conservation for future use

International Nuclear Information System (INIS)

Srivastava, S.C.

1993-01-01

A complete carbon biocycle has been described, starting from coal in in situ condition in coal seams underground. Various steps involved are: (i) Biogasification of coal to methane, using a consortia of bacteria, has been reported. A group of bacteria degrades complex structure of coal to simpler structure. This simpler structure of coal, is then converted to methane by methanogens; (ii) Biophotolysis of methane and associated biodegradation, results in products, such as hydrogen and oxygen for use in fuel cells for power generation; (iii) Bioconversion of products so obtained is carried out to produce methanol or methane that could be used as fuel or recycled; (iv) In complete biocycle some methane is converted to biomass. In order to replace this methane, coal is converted to methane using group of bacteria, only to the extent methane has been converted to biomass; (v) The biomass so produced could be dumped underground from where coal has been gasified. Alternatively it could be burnt as fuel or else used as substitute of protein in animal food. Detailed concept of proposed technology for: (a) an alternative to conventional coal mining, (b) generation of power using products of bioconversion in fuel cell, and (c) conversation of solar energy for generation of alternative source of fuel and power, has been discussed. Possibility of developing a biofuel cell for conversion of solar energy through bioelectrochemical route has been suggested. (author). 48 refs., 3 figs

Bioassays for risk assessment of coal conversion products

Energy Technology Data Exchange (ETDEWEB)

Schacht, S.; Sinder, C.; Pfeifer, F.; Klein, J. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany)

1999-07-01

Traditional as well as biotechnological processing coal leads to complex mixtures of products. Besides chemical and physical characterization, which provides the information for product application, there is a need for bioassays to monitor properties that are probably toxic, mutagenic or cancerogenic. Investigations carried out focused on the selection, adaptation and validation of bioassays for the sensitive estimation of toxic effects. Organisms like bacteria, Daphnia magna and Scenedesmus subspicatus, representing different complexities in the biosphere, were selected as test systems for ecotoxicological and mutagenicity studies. The results obtained indicate that bioassays are, in principle, suitable tools for characterization and evaluation of coal-derived substances and bioconversion products. Using coal products, coal-relevant model compounds and bioconversion products, data for risk assessment are presented. (orig.)

Cogeneration Technology Alternatives Study (CTAS). Volume 3: Energy conversion system characteristics

Science.gov (United States)

1980-01-01

Six current and thirty-six advanced energy conversion systems were defined and combined with appropriate balance of plant equipment. Twenty-six industrial processes were selected from among the high energy consuming industries to serve as a frame work for the study. Each conversion system was analyzed as a cogenerator with each industrial plant. Fuel consumption, costs, and environmental intrusion were evaluated and compared to corresponding traditional values. The advanced energy conversion technologies indicated reduced fuel consumption, costs, and emissions. Fuel energy savings of 10 to 25 percent were predicted compared to traditional on site furnaces and utility electricity. With the variety of industrial requirements, each advanced technology had attractive applications. Fuel cells indicated the greatest fuel energy savings and emission reductions. Gas turbines and combined cycles indicated high overall annual savings. Steam turbines and gas turbines produced high estimated returns. In some applications, diesels were most efficient. The advanced technologies used coal derived fuels, or coal with advanced fluid bed combustion or on site gasifications. Data and information for both current and advanced energy conversion technology are presented. Schematic and physical descriptions, performance data, equipment cost estimates, and predicted emissions are included. Technical developments which are needed to achieve commercialization in the 1985-2000 period are identified.

Proceedings of the 2nd symposium on valves for coal conversion and utilization

Energy Technology Data Exchange (ETDEWEB)

Maxfield, D.A. (ed.)

1981-01-01

The 2nd symposium on valves for coal conversion and utilization was held October 15 to 17, 1980. It was sponsored by the US Department of Energy, Morgantown Energy Technology Center, in cooperation with the Valve Manufacturers Association. Seventeen papers have been entered individually into EDB and ERA. (LTN)

Conversion of different ash content brown coal in fluidized bed

Energy Technology Data Exchange (ETDEWEB)

Osipov, P.; Chernyavskiy, N.; Ryzhkov, A.; Remenuk, A. [Ural Federal Univ., Ekaterinburg (Russian Federation). Dept. of Thermal Power Plants; Dulienko, S. [National Academy of Science of Ukraine, Kiev (Ukraine). Coal Energy Technology Inst.

2013-07-01

Available equations used to determine combustion specific rate of coal-derived cokes describe the burning of carbon particles well enough but are not accurate in case of ash-containing coke particles combustion. This study is an attempt to account for the influence of both initial ash content and its increase in the course of carbon conversion in specific rate calculations. The results of experimental study of burn-out dynamics of Volchanskiy field (North Urals) brown coal and its coke with different ash content under conditions of fluidized bed combustion at impulse-type non-gradient reactor RSC-1 and dynamic installation Pyrolysis-M are summarized. Diffusion and heterogeneous (kinetic) components of carbon combustion rate are identified separately by using diffusion and kinetics equation with correction for carbon mass fraction in particles. Burning particle overheating values and heterogeneous combustion rate constants at different temperatures are estimated.

Design of generic coal conversion facilities: Indirect coal liquefaction, Fischer-Tropsch synthesis

Energy Technology Data Exchange (ETDEWEB)

1991-10-01

A comprehensive review of Fischer-Tropsch (F-T) technology, including fixed, fluidized, and bubble column reactors, was undertaken in order to develop an information base before initiating the design of the Fischer-Tropsch indirect liquefaction PDU as a part of the Generic Coal Conversion Facilities to be built at the Pittsburgh Energy Technology Center (PETC). The pilot plant will include a fixed bed and slurry bubble column reactor for the F-T mode of operation. The review encompasses current status of both these technologies, their key variables, catalyst development, future directions, and potential improvement areas. However, more emphasis has been placed on the slurry bubble column reactor since this route is likely to be the preferred technology for commercialization, offering process advantages and, therefore, better economics than fixed and fluidized bed approaches.

Microbiological desulfurization and conversion of coal

International Nuclear Information System (INIS)

Quigley, D.R.; Stoner, D.L.; Dugan, P.R.

1991-01-01

Bio processing of coal is a young and emerging technology. Until the early 1980's it consisted primarily of coal depyritization using Thiobacillus ferro oxidans to either oxidize pyritic sulfur or to alter particle wettability or floatation properties by binding to exposed pyrite inclusions. Since then, other major avenues of research have been pursued. One of these is the microbiologically mediated liquefaction of coal. Initial work indicated that microorganisms were able to transform low rank coal into a black liquid that was later identified as water solubilized by alkaline substances produced by the microbes and could be enhanced by the removal of multi valent cations from coal. Current work at the INEL involves of the identification and characterization of microorganisms that are able to alter the structure of polymeric desulfurization of coal. This work initially focused on the ability of microorganisms to oxidatively remove organic sulfur from model compounds that were representative of those sulfur containing moieties identified as being in coals (e.g., dibenzo thiophene). The work also focused on those organisms that were could remove the organic sulfur without degrading the carbon structure. While some organisms that are able to perform such these reactions will effectively remove organo sulfur from coal. These concerns stem from steric hindrance considerations and the thermodynamically unfavourable nature of reaction. Current work at the INEL involves the isolation and biochemical characterization of microorganisms that are able to desulfurize and solubilized coals that have high organic sulfur contents. (author)

Coal Mines Security System

OpenAIRE

Ankita Guhe; Shruti Deshmukh; Bhagyashree Borekar; Apoorva Kailaswar; Milind E.Rane

2012-01-01

Geological circumstances of mine seem to be extremely complicated and there are many hidden troubles. Coal is wrongly lifted by the musclemen from coal stocks, coal washeries, coal transfer and loading points and also in the transport routes by malfunctioning the weighing of trucks. CIL —Coal India Ltd is under the control of mafia and a large number of irregularities can be contributed to coal mafia. An Intelligent Coal Mine Security System using data acquisition method utilizes sensor, auto...

Coal conversion processes. Quarterly report, December 13, 1983-March 12, 1984

Energy Technology Data Exchange (ETDEWEB)

Cobb, J.T. Jr.; Biloen, P.; Holder, G.D.; Klinzing, G.E.; Tierney, J.W.

1984-05-01

Experimental work is continuing on four separate projects related to coal conversion processes. The direct digital control of exothermic multiphase reactions is being studied in an experimental adiabatic flow reactor. The existence of two stable steady states for the Fischer-Tropsch reaction network at the same temperature and feed condition has been verified and quantified. Various absorbents for SO/sub 2/ and NO/sub X/ are being studied. The absorption of NO/sub 2/ by methanol and N-cyclohexyl-2-pyrrolidone has been extensively examined. Preliminary data have been obtained with triethylene-tetraamine. Hindered amines will be studied next. Procedures for the preparation of liquid membranes have been tested and the incorporation of hindered amines in them will now be examined. Isotopic switching is being used to study the way in which promoters affect supported metal catalysts. With improved resolution from the mass spectrometer, early quantitative results give indications of three different surface species and of non-statistical ingrowth of /sup 13/C into the product molecules. A program for the study of the extraction of coal and oil shale using supercritical fluids is being carried out. The effect of the presence of piperidine on the amount of toluene solubles produced by supercritical extraction of coal with toluene/piperidine mixture has been determined. A new kinetic model for the extraction/liquefaction of coal by supercritical toluene and THF has been developed and proven satisfactory. Bruceton coal and Hi Na lignite have been extracted with supercritical water. 3 references, 7 figures, 6 tables.

Potential for Coal-to-Liquids Conversion in the United States-Fischer-Tropsch Synthesis

International Nuclear Information System (INIS)

Patzek, Tad W.; Croft, Gregory D.

2009-01-01

The United States has the world's largest coal reserves and Montana the highest potential for mega-mine development. Consequently, a large-scale effort to convert coal to liquids (CTL) has been proposed to create a major source of domestic transportation fuels from coal, and some prominent Montanans want to be at the center of that effort. We calculate that the energy efficiency of the best existing Fischer-Tropsch (FT) process applied to average coal in Montana is less than 1/2 of the corresponding efficiency of an average crude oil refining process. The resulting CO 2 emissions are 20 times (2000%) higher for CTL than for conventional petroleum products. One barrel of the FT fuel requires roughly 800 kg of coal and 800 kg of water. The minimum energy cost of subsurface CO 2 sequestration would be at least 40% of the FT fuel energy, essentially halving energy efficiency of the process. We argue therefore that CTL conversion is not the most valuable use for the coal, nor will it ever be, as long as it is economical to use natural gas for electric power generation. This finding results from the low efficiency inherent in FT synthesis, and is independent of the monumental FT plant construction costs, mine construction costs, acute lack of water, and the associated environmental impacts for Montana

Coal-fired high performance power generating system. Final report

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-08-31

As a result of the investigations carried out during Phase 1 of the Engineering Development of Coal-Fired High-Performance Power Generation Systems (Combustion 2000), the UTRC-led Combustion 2000 Team is recommending the development of an advanced high performance power generation system (HIPPS) whose high efficiency and minimal pollutant emissions will enable the US to use its abundant coal resources to satisfy current and future demand for electric power. The high efficiency of the power plant, which is the key to minimizing the environmental impact of coal, can only be achieved using a modern gas turbine system. Minimization of emissions can be achieved by combustor design, and advanced air pollution control devices. The commercial plant design described herein is a combined cycle using either a frame-type gas turbine or an intercooled aeroderivative with clean air as the working fluid. The air is heated by a coal-fired high temperature advanced furnace (HITAF). The best performance from the cycle is achieved by using a modern aeroderivative gas turbine, such as the intercooled FT4000. A simplified schematic is shown. In the UTRC HIPPS, the conversion efficiency for the heavy frame gas turbine version will be 47.4% (HHV) compared to the approximately 35% that is achieved in conventional coal-fired plants. This cycle is based on a gas turbine operating at turbine inlet temperatures approaching 2,500 F. Using an aeroderivative type gas turbine, efficiencies of over 49% could be realized in advanced cycle configuration (Humid Air Turbine, or HAT). Performance of these power plants is given in a table.

Proceedings of the symposium on assessing the industrial hygiene monitoring needs for the coal conversion and oil shale industries

Energy Technology Data Exchange (ETDEWEB)

White, O. Jr. (ed.)

1979-03-01

This work was supported by the United States Department of Energy, Division of Biomedical and Environmental Research, Analysis and Assessment Program, through the Safety and Environmental Protection Division at Brookhaven National Laboratory. The symposium program included presentations centering around the themes: Recognition of Occupational Health Monitoring Requirements for the Coal Conversion and Oil Shale Industries and Status of Dosimetry Technology for Occupational Health Monitoring for the Coal Conversion and Oil Shale Industries. Sixteen papers have been entered individually into EDB and ERA; six had been entered previously from other sources. (LTN)

Coal transportation research and information needs

Energy Technology Data Exchange (ETDEWEB)

Eck, R.W. (West Virginia Univ., Morgantown); Hui, C.Y.

1978-09-01

This paper examines some of the existing and emerging issues of interest to engineers and planners dealing with coal transportation. One conclusion is that any research or data collection efforts in this field must be of a multidisciplinary nature. Not only must transportation planners, highway engineers, maintenance engineers, and soils engineers work together but, in addition, engineers will need to work with geologists, economists, and marketing specialists for effective planning, design, and operation of the coal transportation system. Earlier sections of this paper may have given the erroneous impression that all future research should concentrate on problems of transporting coal by truck. Although the West Virginia coal conversion study documented information deficiencies relative to the highway transportation of coal, research efforts involving railroads and waterways should continue. There is a serious need for research and information relative to the interactions between modes. For example, in order to predict the impact of local coal conversions on rail and barge systems that serve retailers, it is necessary to have a knowledge of the typical volumes that would be required by retail facilities, frequency of delivery to retail yards, and transportation distances involved mine and retailer. This paper deals with relatively short-term planning, however, information is required on the long-range future of the coal industry. Decision makers involved with providing an adequate coal transportation system must have information on the future role that coal will play in United States energy policy. (MCW)

Coal use and coal technology study (KIS)

International Nuclear Information System (INIS)

Kram, T.; Okken, P.A.; Gerbers, D.; Lako, P.; Rouw, M.; Tiemersma, D.N.

1991-11-01

The title study aims to assess the possible role for coal in the Netherlands energy system in the first decades of the next century and the part new coal conversion technologies will play under various conditions. The conditions considered relate to (sectoral) energy demand derived from national scenarios in an international context, to energy prices, to environmental constraints (acidification, solid waste management and disposal) and to the future role for nuclear power production. Targets for reduction of greenhouse gas emissions are not explicitly included, but resulting CO 2 emissions are calculated for each variant case. The part that coal can play in the Dutch energy supply is calculated and analyzed by means

Energy Conversion Alternatives Study (ECAS), General Electric Phase 1. Volume 3: Energy conversion subsystems and components. Part 3: Gasification, process fuels, and balance of plant

Science.gov (United States)

Boothe, W. A.; Corman, J. C.; Johnson, G. G.; Cassel, T. A. V.

1976-01-01

Results are presented of an investigation of gasification and clean fuels from coal. Factors discussed include: coal and coal transportation costs; clean liquid and gas fuel process efficiencies and costs; and cost, performance, and environmental intrusion elements of the integrated low-Btu coal gasification system. Cost estimates for the balance-of-plant requirements associated with advanced energy conversion systems utilizing coal or coal-derived fuels are included.

Role of non-ferrous coal minerals and by-product metallic wastes in coal liquefaction. Technical progress report, December 1, 1980-February 28, 1981

Energy Technology Data Exchange (ETDEWEB)

Garg, D.; Givens, E.N.; Schweighardt, F.K.; Curtis, C.W.; Guin, J.A.; Huang, W.J.; Shridharani, K.

1981-04-01

Results from screening studies showed that the pyrite samples separated from various coal seams had similar catalytic activity. The addition of all the pyrite samples to feed slurry increased conversion of coal and production of oil. A sample of fusinite was also tested for its liquefaction behavior with and without added pyrite. The addition of pyrite increased the conversion of fusinite and production of oil. These results show that pyrite catalyzes the conversion of fusinite and therefore improves overall coal conversion. Conversion of coal and oil production increased by impregnating coal with iron and molybdenum compounds. Coal conversion and oil production also increased with increasing concentration of both iron and molybdenum impregnated on coal. Addition of various transition metal sulfides increased coal conversion and oil production. Dramatic improvements were noted with nickel, vanadium, and tin sulfides. Addition of transition metal naphthenates produced mixed results; some of them improved coal conversion and others had no effect. The effect of metal concentration on coal conversion was also not clear. Deep cleaning of coal did not affect coal conversion, but it significantly reduced oil production. Addition of pyrite separated from coal to deep cleaned coal sample regained the oil production to the original value, i.e., oil produced from liquefaction of raw coal.Coal cleaned by oil agglomeration gave highest coal conversion and oil production. Basic and non-basic nitrogen compounds reduced the naphthalene hydrogenation activity of both Co-Mo-Al and sulfided Fe/sub 2/O/sub 3/. Sulfided Fe/sub 2/O/sub 3/ was inactive for denitrogenation of quinoline, and the reaction product mainly consisted of hydrogenated and hydrocracked quinoline. On the contrary, Co-Mo-Al was active for denitrogenation of quinoline, resulting in lower quinoline poisoning.

Usage of waste products from thermal recycling of plastics waste in enhanced oil recovery or in-situ coal conversion

Energy Technology Data Exchange (ETDEWEB)

Fink, M; Fink, J K [Montanuniversitaet Leoben (Austria)

1998-09-01

In this contribution a thermal method for crude oil mobilization and in-situ liquefaction of coal is discussed, which will finally yield more organic material, as which has been put in from plastics waste originally into the process. The conversion product from thermal treatment is pumped down into exhausted crude oil reservoirs, where the hydrogen can degrade the residual high viscous oil to cause it to become more prone to flow so that it can be recovered. Such a process will envision two goals: 1. more organic raw material (as crude oil) will be recovered than is initially put in as waste product. 2. atmospheric pollutants from the conversion plant will be trapped in the reservoir, which simplifies the construction of the plant. An analogous process may be performed with coal seams. Coal seams with their high porosity and large specific surface are believed to be in particular useful to filter atmospheric pollutants. Depending on the type of coal the mobilization of organic material by this process may be in the background. (orig./SR)

Studies on the catalysts for coal liquefaction. ; Rheological studies of coal liquefaction process. Sekitan ekikayo shokubai ni kansuru kenkyu. ; Sekitan ekika process no rheology teki kenkyu

Energy Technology Data Exchange (ETDEWEB)

Muraoka, T; Oda, H; Yokokawa, C [Kansai University, Osaka (Japan). Faculty of Engineering

1991-11-07

Hydrogenolysis of different rank coals as Taiheiyo coal (75.7C%) and Pittston coal (85.4C%) were conducted in the presence of four kinds of catalysts (CuCrO4, Fe2O3+S, MoO3-TiO2 and MoS3-Al2O3) with an addition of tetralin as vehicle. The variation in viscosity in every reaction system was traced in the initial stage of the reaction by a torque meter attached to an autoclave. As a result, in every system, the torque decreased in the initial stage of temperature rise because of reduction of a solvent viscosity. The torque subsequently increased with temperature indicating two peaks before the following gradual decrease. In Taiheiyo coal, both peaks were low, and its coal conversion was more than 85%, while in Pittston coal, both peaks were sharp and high, and both subsequent torque reduction and coal conversion were smaller than those of Taiheiyo coal. 5 refs., 10 figs., 2 tabs.

Flash pyrolysis of coal-solvent slurry prepared from the oxidized coal and the coal dissolved in solvent; Ichibu yokaishita sanka kaishitsutan slurry no jinsoku netsubunkai

Energy Technology Data Exchange (ETDEWEB)

Maki, T.; Mae, K.; Okutsu, H.; Miura, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

1996-10-28

In order to develop a high-efficiency coal pyrolysis method, flash pyrolysis was experimented on slurry prepared by using liquid-phase oxidation reformed coal and a methanol-based solvent mixture. Australian Morwell coal was used for the experiment. The oxidized coal, into which carboxyl groups have been introduced, has the condensation structure relaxed largely, and becomes highly fluid slurry by means of the solvent. Char production can be suppressed by making the oxidation-pretreated coal into slurry, resulting in drastically improved pyrolytic conversion. The slurry was divided into dissolved solution, dried substance, extracted residue, and residual slurry, which were pyrolized independently. The dissolved solution showed very high conversion. Improvement in the conversion is contributed by separating the dissolved substances (coal macromolecules) at molecular levels, coagulating the molecules, suppressing cross-link formation, and reducing molecular weight of the dissolved substances. Oxidized coal can be dissolved to 80% or higher by using several kinds of mixed solvents. As a result of the dissolution, a possibility was suggested on pyrolysis which is easy in handling and high in conversion. 7 refs., 6 figs., 2 tabs.

DEVELOPMENT OF A VORTEX CONTAINMENT COMBUSTOR FOR COAL COMBUSTION SYTEMS

Science.gov (United States)

The report describes the development of a vortex containment combustor (VCC) for coal combustion systems, designed to solve major problems facing the conversion of oil- and gas-fired boilers to coal (e.g., derating, inorganic impurities in coal, and excessive formation of NOx and...

New coal

Energy Technology Data Exchange (ETDEWEB)

1979-07-01

Specially dedicated to coal, this edition comprises a series of articles of general interest dealing with the position of the French coalmining industry (interview with M.P. Gardent), the coal market in France, the work of CERCHAR, etc. New techniques, in-situ gasification of deep coal, gasification of coal by nuclear methods, the conversion of coal into petrol, the Emile Huchet power plant of Houilleres du Bassin de Lorraine, etc., are dealt with.

Measurement and modeling of advanced coal conversion processes, Volume II

Energy Technology Data Exchange (ETDEWEB)

Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

1993-06-01

A two dimensional, steady-state model for describing a variety of reactive and nonreactive flows, including pulverized coal combustion and gasification, is presented. The model, referred to as 93-PCGC-2 is applicable to cylindrical, axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using a discrete ordinates method. The particle phase is modeled in a lagrangian framework, such that mean paths of particle groups are followed. A new coal-general devolatilization submodel (FG-DVC) with coal swelling and char reactivity submodels has been added.

Howden-Microcoal system for the conversion of industrial oil or gas fired boilers

Energy Technology Data Exchange (ETDEWEB)

Cooper, J

1985-01-01

The technical and economic aspects of the conversion of an industrial boiler designed for oil firing at Courtaulds plc Greenfield site in North Wales to Howden-Microcoal firing are discussed. The production of Howden-Micro coal (an ultrafine or 'micronised' coal) is described and the Howden-Microcoal processor is compared with other fluid energy and mechanical mills. A typical boiler installation and modifications required for conversion to Howden-Microcoal firing are presented along with the main results of the Courtauld's tests. Cost, conversion time and the effect on average steam generation costs are considered.

Thermodynamic analysis of a coal-based polygeneration system with partial gasification

International Nuclear Information System (INIS)

Li, Yuanyuan; Zhang, Guoqiang; Yang, Yongping; Zhai, Dailong; Zhang, Kai; Xu, Gang

2014-01-01

This study proposed a polygeneration system based on coal partial gasification, in which methanol and power were generated. This proposed system, comprising chemical and power islands, was designed and its characteristics are analyzed. The commercial software Aspen Plus was used to perform the system analysis. In the case study, the energy and exergy efficiency values of the proposed polygeneration system were 51.16% and 50.58%, which are 2.34% and 2.10%, respectively, higher than that of the reference system. Energy-Utilization Diagram analysis showed that removing composition adjustment and recycling 72.7% of the unreacted gas could reduce the exergy destruction during methanol synthesis by 46.85% and that the char utilized to preheat the compressed air could reduce the exergy destruction during combustion by 10.28%. Sensitivity analysis was also performed. At the same capacity ratio, the energy and exergy efficiency values of the proposed system were 1.30%–2.48% and 1.21%–2.30% higher than that of the reference system, respectively. The range of chemical-to-power capacity ratio in the proposed system was 0.41–1.40, which was narrower than that in the reference system. But the range of 1.04–1.4 was not recommended for the disappearance of energy saving potential in methanol synthesis. - Highlights: • A novel polygeneration system based on coal partial gasification is proposed. • The efficient conversion method for methanol and power is explored. • The exergy destruction in chemical energy conversion processes is decreased. • Thermodynamic performance and system characteristics are analyzed

Variations in the stable isotope ratios of specific aromatic and aliphatic hydrocarbons from coal conversion processes

Energy Technology Data Exchange (ETDEWEB)

McRae, C.; Snape, C.E.; Fallick, A.E. [University of Strathclyde, Glasgow (United Kingdom). Dept. of Pure and Applied Chemistry

1998-07-01

To establish the scope for applying gas chromatography-isotope ratio mass spectrometry ({sup {delta}-13}C GC-IRMS) to molecular recognition problems in coal utilisation, {sup 13}C/{sup 12}C isotope ratios were determined for n-alkanes and polycyclic aromatic hydrocarbons (PAHs) as a function of coal rank and process conditions. Six coals ranging from a lignite to a low volatile bituminous coal were subjected to chloroform extraction, fixed-bed pyrolysis under hydrogen pressure (hydropyrolysis) and fluidised-bed (flash) pyrolysis. No significant variations in the stable isotope ratios of n-alkanes were evident as a function of either rank or conversion regime. In contrast, the isotope ratios of PAHs show large variations with those for hydropyrolysis (-23 to -25 parts per thousand) being similar to the bulk values of the initial coals and being isotopically heavier (less negative) than their fluidised-bed pyrolysis counterparts by 2-3 parts per thousand. However, the PAHs from fluidised-bed pyrolysis, which resemble closely those obtained from high temperature coal carbonization, are still heavier (by 2-3 parts per thousand) than those from diesel particulates and coal gasification and combustion residues. This provides a firm basis for the source apportionment of airborne PAHs in the proximity of coking plants, particularly with no major variations in the PAH isotope ratios being found as a function of rank.

Dispersed-phase catalysis in coal liquefaction

International Nuclear Information System (INIS)

Utz, B.R.; Cugini, A.V.; Frommell, E.A.

1990-01-01

This paper reports that the specific reaction (activation) conditions for the conversion of catalyst precursors to unsupported catalyst have a direct effect on the catalytic activity and dispersion. The importance of reaction intermediates in decomposition of ammonium heptamolybdate and ammonium tetrathiomolybdate, and the sensitivity of these intermediates to reaction conditions, were studied in coal liquefaction systems. Recent results indicate that optimization of activation conditions facilitates the formation of a highly dispersed and active form of molybdenum disulfide for coal liquefaction. The use of the catalyst precursors ammonium heptamolybdate, ammonium tetrathiomolybdate, and molybdenum trisulfide for the conversion of coal to soluble products will be discussed. The use of an unsupported dispersed-phase catalyst for direct coal liquefaction is not a novel concept and has been employed in may studies with varying success. Dispersed-phase catalysts soluble and oil-soluble salts, and as finely divided powders. While some methods of catalyst introduction give higher dispersion of the catalyst and greater activity for the liquefaction of coal, all of the techniques allow the formation of a finely dispersed inorganic phase

Changes in brown coal structure caused by coal-solubilizing microorganisms

Energy Technology Data Exchange (ETDEWEB)

Schmiers, H.; Koepsel, R.; Weber, A.; Winkelhoefer, M.; Grosse, S. [Technische Univ. Bergakademie Freiberg (Germany). Inst. fuer Energieverfahrenstechnik und Chemieingenieurwesen

1997-12-31

The phenomenon of coal solubilization caused by microorganisms has been explained by various mechanisms: extraction of non-covalently bonded polar components of the coal substance by biogenic agents (chelating agents, alkaline substances) and enzyme-catalyzed cleavage of covalent bonds by extracellular enzyme systems. For this it is assumed that bond cleavage occurs on the aliphatic carbon (methylene groups, aliphatic bridges or on ester groups). As the coal has usually been treated with oxidizing agents such as H{sub 2}O{sub 2} or HNO{sub 3} before bioconversion, there is a possibility that the result of bioconversion is overlaid with the effect of the chemical treatment. We therefore studied the structural changes in the organic coal substance during pre-oxidation with H{sub 2}O{sub 2}, treatment with MnP and conversion using the fungal strains of Trichoderma and Fusarium oxysporum. (orig.)

Microbial conversion of higher hydrocarbons to methane in oil and coal reservoirs

Energy Technology Data Exchange (ETDEWEB)

Kruger, Martin; Beckmaann, Sabrina; Siegert, Michael; Grundger, Friederike; Richnow, Hans [Geomicrobiology Group, Federal Institute for Geosciences and Natural Resources (Germany)

2011-07-01

In recent years, oil production has increased enormously but almost half of the oil now remaining is heavy/biodegraded and cannot be put into production. There is therefore a need for new technology and for diversification of energy sources. This paper discusses the microbial conversion of higher hydrocarbons to methane in oil and coal reservoirs. The objective of the study is to identify microbial and geochemical controls on methanogenesis in reservoirs. A graph shows the utilization of methane for various purposes in Germany from 1998 to 2007. A degradation process to convert coal to methane is shown using a flow chart. The process for converting oil to methane is also given. Controlling factors include elements such as Fe, nitrogen and sulfur. Atmospheric temperature and reservoir pressure and temperature also play an important role. From the study it can be concluded that isotopes of methane provide exploration tools for reservoir selection and alkanes and aromatic compounds provide enrichment cultures.

Coal conversion rate in 1t/d PSU liquefaction reactor; 1t/d PSU ekika hannoto ni okeru sekitan tenka sokudo no kento

Energy Technology Data Exchange (ETDEWEB)

Ikeda, K.; Imada, K. [Nippon Steel Corp., Tokyo (Japan); Nogami, Y.; Inokuchi, K. [Mitsui SRC Development Co. Ltd., Tokyo (Japan)

1996-10-28

To investigate the coal liquefaction characteristics, coal slurry samples were taken from the outlets of the reactors and slurry preheater of NEDOL process 1 t/d process supporting unit (PSU), and were analyzed. Tanito Harum coal was used for liquefaction, and the slurry was prepared with recycle solvent. Liquefaction was performed using synthetic iron sulfide catalyst at reaction temperatures, 450 and 465{degree}C. Solubility of various solid samples was examined against n-hexane, toluene, and tetrahydrofuran (THF). When considering the decrease of IMO (THF-insoluble and ash) as a characteristic of coal conversion reaction, around 20% at the outlet of the slurry preheater, around 70% within the first reactor, and several percents within the successive second and third reactors were converted against supplied coal. Increase of reaction temperature led to the increase of evaporation of oil fraction, which resulted in the decrease of actual slurry flow rate and in the increase of residence time. Thus, the conversion of coal was accelerated by the synergetic effect of temperature and time. Reaction rate constant of the coal liquefaction was around 2{times}10{sup -1} [min{sup -1}], which increased slightly with increasing the reaction temperature from 450 to 465{degree}C. 3 refs., 5 figs., 1 tab.

Molecular catalytic coal liquid conversion

Energy Technology Data Exchange (ETDEWEB)

Stock, L.M.; Yang, Shiyong [Univ. of Chicago, IL (United States)

1995-12-31

This research, which is relevant to the development of new catalytic systems for the improvement of the quality of coal liquids by the addition of dihydrogen, is divided into two tasks. Task 1 centers on the activation of dihydrogen by molecular basic reagents such as hydroxide ion to convert it into a reactive adduct (OH{center_dot}H{sub 2}){sup {minus}} that can reduce organic molecules. Such species should be robust withstanding severe conditions and chemical poisons. Task 2 is focused on an entirely different approach that exploits molecular catalysts, derived from organometallic compounds that are capable of reducing monocyclic aromatic compounds under very mild conditions. Accomplishments and conclusions are discussed.

Synthesis of beta-sialon from coal gangue

Energy Technology Data Exchange (ETDEWEB)

Luo, X.Y.; Sun, J.L.; Deng, C.J.; Hong, Y.R. [Beijing University Science & Technology, Beijing (China)

2003-01-01

It is worth studying the synthesis of beta-Sialon from coal gangue, because coal gangue is a waste of coal production and is a high quality kaolin contained carbon which is a perfect raw material of contained reducer itself for synthesis of beta-sialon. The study showed that a high conversion rate of 95% from coal gangue to beta-Sialon could be obtained by using process of carbothermal reduction nitridation when strictly controlling the thermodynamic conditions of synthesis. For controlling the synthesis conditions, the details of the effects of p(CO), P-O{sub 2} and T on the conversion rate of beta-sialon are discussed and the phase diagrams of oxygen pressure vs composition for Si{sub 3}N{sub 4}-A{sub l}N-Al{sub 2}O{sub 3}-SiO{sub 2} system at 1350, 1500, and 1600{sup o}C are constructed.

Card index of coal user-payers in the system of accounting and analysis of coal marketing

Energy Technology Data Exchange (ETDEWEB)

Czapka, D

1980-01-01

A card index of coal users-payers was formed on the basis of an existing card file of payers which functions in development of an earlier subsystem of financial accounting of coal users by means of a corresponding reorganization of the available set of data and supplementing it with new data on users. The card index performs a monitor and address function. Checked and refined data are input in subsequent technological cycles of data conversion. The structure of the card file, its functions, realization conditions with output of necessary following results are examined.

Gasification Characteristics of Coal/Biomass Mixed Fuels

Energy Technology Data Exchange (ETDEWEB)

Mitchell, Reginald [Stanford Univ., CA (United States). Mechanical Engineering Dept.

2014-09-01

A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co-produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle

Development of I and C system for the coal feeder of coal firing plant

Energy Technology Data Exchange (ETDEWEB)

Kim, Teak Soo; Park, Chan Ho [Korea Electric Power Corp. (KEPCO), Taejon (Korea, Republic of). Research Center

1996-12-31

KECC(Kepco Coal Feeder Control System) receives coal weight, conveyor speed and boiler demand signals. It controls coal flow by generating speed signal of feeder which conveys coal in hopper to pulverizer, displaying measured coal quantity and providing local auto and manual manipulator (author). 33 figs.

Coal conversion. 1977 technical report

Energy Technology Data Exchange (ETDEWEB)

None

1978-06-01

The status and progress in US DOE's projects in coal gasification, liquefaction, and fluidized-bed combustion are reviewed with financing, flowsheets, history, progress and status of each (57 projects). (LTN)

Exploratory Research on Novel Coal

Energy Technology Data Exchange (ETDEWEB)

Winschel, R.A.; Brandes, S.D.

1998-05-01

The report presents the findings of work performed under DOE Contract No. DE-AC22 -95PC95050, Task 3 - Flow Sheet Development. A novel direct coal liquefaction technology was investigated in a program being conducted by CONSOL Inc. with the University of Kentucky Center for Applied Energy Research and LDP Associates. The process concept explored consists of a first-stage coal dissolution step in which the coal is solubilized by hydride ion donation. In the second stage, the products are catalytically upgraded to refinery feedstocks. Integrated first-stage and solids-separation steps were used to prepare feedstocks for second-stage catalytic upgrading. An engineering and economic evaluation was conducted concurrently with experimental work throughout the program. Parameters were established for a low-cost, low-severity first-stage reaction system. A hydride ion reagent system was used to effect high coal conversions of Black Thunder Mine Wyoming subbituminous coal. An integrated first-stage and filtration step was successfully demonstrated and used to produce product filtrates with extremely low solids contents. High filtration rates previously measured off-line in Task 2 studies were obtained in the integrated system. Resid conversions of first-stage products in the second stage were found to be consistently greater than for conventional two-stage liquefaction resids. In Task 5, elementally balanced material balance data were derived from experimental results and an integrated liquefaction system balance was completed. The economic analysis indicates that the production of refined product (gasoline) via this novel direct liquefaction technology is higher than the cost associated with conventional two-stage liquefaction technologies. However, several approaches to reduce costs for the conceptual commercial plant were recommended. These approaches will be investigated in the next task (Task 4) of the program.

Thermocatalytical processing of coal and shales

Directory of Open Access Journals (Sweden)

Zhaksyntay Kairbekov

2012-12-01

Full Text Available The article investigates the questions of thermocatalytical conversion of organic mass of coal (OMC, it is shown that in the absence of a catalyst process is carried out by a radical process. Accumulated data on the properties for radicals of different structure and therefore different reaction capacity enables us to understand and interpret the conversion of OMC. Thermal conversion of OMC regarded as a kind of depolymerization, accompanied by decomposition of the functional groups with the formation of radicals, competing for hydrogen atom. Catalyst can change the direction and conditions of the process. Modern catalysts can reduce the process pressure up to 50 atm., with a high degree of coal conversion. We consider examples of simultaneous conversion of coal and shale, shale and masut, shale and tar.

Challenge of coal-liquid mixtures

Energy Technology Data Exchange (ETDEWEB)

Peirce, T

1985-09-01

The near-term prospect for coal-water (CWMs) mixtures as a convenient replacement fuel for UK oil-fired plant is discussed. Specific use of CWMs in industrial water-tube boilers is presented. The article shows how such developments complement the introduction of new, modern coal-designed industrial combustion equipment in the form of fully automatic stokers and fluidized bed combustion systems. Topics presented include properties and preparation of CWM, combustion characteristics of CWM, and boiler conversion. 9 references, 4 figures.

Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming

Energy Technology Data Exchange (ETDEWEB)

1982-01-01

Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section A

Science.gov (United States)

Knightly, W. F.

1980-01-01

Various advanced energy conversion systems (ECS) are compared with each other and with current technology systems for their savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidates which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented for coal fired process boilers. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented.

Science of coal-to-oil conversion

Energy Technology Data Exchange (ETDEWEB)

Spencer, W D

1944-01-01

A general review is given of the principles of the most important commercial processes for obtaining oil from coal, and of the yields obtained by, and special features of each process. The composition of typical tars obtained by the low-temperature carbonization of coal, yields of products other than tar, estimated costs of running a plant of 700 tons daily capacity and annual British statistics on the industry from 1930 through 1938 are tabulated. The text is chiefly concerned with the various types of retorts, which have been developed for use in this process. Economics and cost of production are discussed.

Advanced coal-fueled gas turbine systems

Energy Technology Data Exchange (ETDEWEB)

Wenglarz, R.A.

1994-08-01

Several technology advances since the early coal-fueled turbine programs that address technical issues of coal as a turbine fuel have been developed in the early 1980s: Coal-water suspensions as fuel form, improved methods for removing ash and contaminants from coal, staged combustion for reducing NO{sub x} emissions from fuel-bound nitrogen, and greater understanding of deposition/erosion/corrosion and their control. Several Advanced Coal-Fueled Gas Turbine Systems programs were awarded to gas turbine manufacturers for for components development and proof of concept tests; one of these was Allison. Tests were conducted in a subscale coal combustion facility and a full-scale facility operating a coal combustor sized to the Allison Model 501-K industrial turbine. A rich-quench-lean (RQL), low nitrogen oxide combustor design incorporating hot gas cleanup was developed for coal fuels; this should also be applicable to biomass, etc. The combustor tests showed NO{sub x} and CO emissions {le} levels for turbines operating with natural gas. Water washing of vanes from the turbine removed the deposits. Systems and economic evaluations identified two possible applications for RQL turbines: Cogeneration plants based on Allison 501-K turbine (output 3.7 MW(e), 23,000 lbs/hr steam) and combined cycle power plants based on 50 MW or larger gas turbines. Coal-fueled cogeneration plant configurations were defined and evaluated for site specific factors. A coal-fueled turbine combined cycle plant design was identified which is simple, compact, and results in lower capital cost, with comparable efficiency and low emissions relative to other coal technologies (gasification, advanced PFBC).

Preparation, Characterization, and Activation of Co-Mo/Y Zeolite Catalyst for Coal Tar Conversion to Liquid Fuel

Directory of Open Access Journals (Sweden)

Didi Dwi Anggoro

2017-05-01

Full Text Available One of many efforts to convert coal tar into alternative liquid fuel is by hydrocracking. This research aims to determine the impregnation of Co-Mo/Y zeolite, its characteristics, the effect of impregnation temperature and time, and also the best Co-Mo/Y zeolite impregnation condition for the conversion of coal tar. This research was conducted in several steps, impregnating Co from Co(NO32.6H2O and Mo from (NH46Mo7O24.4H2O into Zeolite Y in liquid media, drying at 100 °C for 24 hours, and calcination at 550 °C for 3 hours. Coal tar was then reacted with hydrogen gas (as a reactant, and Co-Mo/Zeolite Y (as a catalyst was conducted at 350 °C. Characteristic analysis showed that Co and Mo had impregnated into the Y zeolite, as well as it made no change of catalyst’s structure and increased the total acidity. The higher of impregnation temperature was increased the catalyst crystallinity, total acidity, and yield of gasoline. The longer impregnation time was reduced crystallinity value, but total acidity and yield were increased. GC analysis showed that products included into the gasoline product (C8, C9, and C10. Copyright © 2017 BCREC Group. All rights reserved Received: 13rd November 2016; Revised: 12nd February 2017; Accepted: 16th February 2017 How to Cite: Anggoro, D.D., Buchori, L., Silaen, G.C., Utami, R.N. (2017. Preparation, Characterization, and Activation of Co-Mo/Y Zeolite Catalyst for Coal Tar Conversion to Liquid Fuel. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (2: 219-226 (doi:10.9767/bcrec.12.2.768.219-226 Permalink/DOI: http://dx.doi.org/10.9767/bcrec.12.2.768.219-226

Coal-92

International Nuclear Information System (INIS)

Hillring, B.; Sparre, C.

1992-11-01

Swedish consumption of coal and coke during 1991 and trends in technology, environment and market aspects of coal use are reported. Steam coal use in the heating sector was unchanged from 1991, 1.2 Mtons. Reduced consumption in smaller district heating units (due to conversion to biofuels and gas) was compensated by increased use for power generation in cogeneration plants. Coal consumption in industry fell 0.10 Mton to 0.84 Mton due to lower production in one industry branch. Import of steam coal was 1.1 Mton (down 0.5 Mton from 1990) since new rules for strategic reserves allowed a reduction of stocks. During the last five years stocks have been reduced by 2 Mtons. Import of metallurgical coal was 1.6 Mton, unchanged from 1990. The report also gives statistics for the coal using plants in Sweden, on coal R and D, and on emission laws for coal firing. (9 tabs., 2 figs.)

Effect of Coal Contaminants on Solid Oxide Fuel System Performance and Service Life

Energy Technology Data Exchange (ETDEWEB)

Gopala Krishnan; P. Jayaweera; J. Bao; J. Perez; K. H. Lau; M. Hornbostel; A. Sanjurjo; J. R. Albritton; R. P. Gupta

2008-09-30

The U.S. Department of Energy's SECA program envisions the development of high-efficiency, low-emission, CO{sub 2} sequestration-ready, and fuel-flexible technology to produce electricity from fossil fuels. One such technology is the integrated gasification-solid oxide fuel cell (SOFC) that produces electricity from the gas stream of a coal gasifier. SOFCs have high fuel-to-electricity conversion efficiency, environmental compatibility (low NO{sub x} production), and modularity. Naturally occurring coal has many impurities and some of these impurities end in the fuel gas stream either as a vapor or in the form of fine particulate matter. Establishing the tolerance limits of SOFCs for contaminants in the coal-derived gas will allow proper design of the fuel feed system that will not catastrophically damage the SOFC or allow long-term cumulative degradation. The anodes of Ni-cermet-based SOFCs are vulnerable to degradation in the presence of contaminants that are expected to be present in a coal-derived fuel gas stream. Whereas the effects of some contaminants such as H{sub 2}S, NH{sub 3} and HCl have been studied, the effects of other contaminants such as As, P, and Hg have not been ascertained. The primary objective of this study was to determine the sensitivity of the performance of solid oxide fuel cells to trace level contaminants present in a coal-derived gas stream in the temperature range 700 to 900 C. The results were used to assess catastrophic damage risk and long-term cumulative effects of the trace contaminants on the lifetime expectancy of SOFC systems fed with coal-derived gas streams.

In Situ Catalytic Pyrolysis of Low-Rank Coal for the Conversion of Heavy Oils into Light Oils

Directory of Open Access Journals (Sweden)

Muhammad Nadeem Amin

2017-01-01

Full Text Available Lighter tars are largely useful in chemical industries but their quantity is quite little. Catalytic cracking is applied to improve the yield of light tars during pyrolysis. Consequently, in situ upgrading technique through a MoS2 catalyst has been explored in this research work. MoS2 catalyst is useful for the conversion of high energy cost into low energy cost. The variations in coal pyrolysis tar without and with catalyst were determined. Meanwhile, the obtained tar was analyzed using simulated distillation gas chromatograph and Elemental Analyzer. Consequently, the catalyst reduced the pitch contents and increased the fraction of light tar from 50 to 60 wt.% in coal pyrolysis tar. MoS2 catalyst increased the liquid yield from 18 to 33 (wt.%, db and decreased gas yield from 27 to 12 (wt.%, db compared to coal without catalyst. Moreover, it increased H content and hydrogen-to-carbon ratio by 7.9 and 3.3%, respectively, and reduced the contents of nitrogen, sulphur, and oxygen elements by 8.1%, 15.2%, and 23.9%, respectively, in their produced tars compared to coal without catalyst.

Pneumatic automation systems in coal mines

Energy Technology Data Exchange (ETDEWEB)

Shmatkov, N.A.; Kiklevich, Yu.N.

1981-04-01

Giprougleavtomatizatsiya, Avtomatgormash, Dongiprouglemash, VNIIGD and other plants develop 30 new pneumatic systems for mine machines and equipment control each year. The plants produce about 200 types of pneumatic systems. Major pneumatic systems for face systems, machines and equipment are reviewed: Sirena system for remote control of ANShch and AShchM face systems for steep coal seams, UPS control systems for pump stations, PAUZA control system for stowing machines, remote control system of B100-200 drilling machines, PUSK control system for coal cutter loaders with pneumatic drive (A-70, Temp), PUVSh control system for ventilation barriers activated from moving electric locomotives, PAZ control system for skip hoist loading. Specifications of the systems are given. Economic benefit produced by the pneumatic control systems are evaluated (from 1,500 to 40,000 rubles/year). Using the systems increases productivity of face machines and other machines used in black coal mines by 5 to 30%.

Effect of pre-swelling of coal on its liquefaction properties

Energy Technology Data Exchange (ETDEWEB)

Hengfu Shui; Zhicai Wang; Meixia Cao [Anhui University of Technology, Ma' anshan (China). School of Chemistry & Chemical Engineering

2007-07-01

The effects of pre-swelling of Shenhua coal on its liquefaction property were studied in this paper. It was found that pre-swelling treatments of Shenhua coal in three solvents, i.e toluene (TOL), N-methyl-2-pyrrolidinone (NMP) and tetralin (THN) increased its liquefaction conversion, and the liquefied product distributions were also quite different. Removal of the pre-swelling solvent from the swollen coals further increased the liquefaction conversion compared to that of the swollen coals with the swelling solvent existed in them. It was found that oil and gas yields for the liquefaction of swollen coals in NMP and TOL with swelling solvent existed dramatically decreased. Pre-swelling in THN at 120{sup o}C gave the highest liquefaction conversion, however the liquefaction conversion decreased with the increase of pre-swelling temperature in the case of NMP. TG and FTIR analyses of raw coal, the swollen coals and liquefied products were carried out and the mechanism of the effects of pre-swelling of coal on its extraction and liquefaction behaviors were probed in the paper. 12 refs., 6 figs., 3 tabs.

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section B

Science.gov (United States)

Knightly, W. F.

1980-01-01

About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidate which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented. Two nocogeneration base cases are included: coal fired and residual fired process boilers.

A novel solar energy integrated low-rank coal fired power generation using coal pre-drying and an absorption heat pump

International Nuclear Information System (INIS)

Xu, Cheng; Bai, Pu; Xin, Tuantuan; Hu, Yue; Xu, Gang; Yang, Yongping

2017-01-01

Highlights: •An improved solar energy integrated LRC fired power generation is proposed. •High efficient and economic feasible solar energy conversion is achieved. •Cold-end losses of the boiler and condenser are reduced. •The energy and exergy efficiencies of the overall system are improved. -- Abstract: A novel solar energy integrated low-rank coal (LRC) fired power generation using coal pre-drying and an absorption heat pump (AHP) was proposed. The proposed integrated system efficiently utilizes the solar energy collected from the parabolic trough to drive the AHP to absorb the low-grade waste heat of the steam cycle, achieving larger amount of heat with suitable temperature for coal’s moisture removal prior to the furnace. Through employing the proposed system, the solar energy could be partially converted into the high-grade coal’s heating value and the cold-end losses of the boiler and the steam cycle could be reduced simultaneously, leading to a high-efficient solar energy conversion together with a preferable overall thermal efficiency of the power generation. The results of the detailed thermodynamic and economic analyses showed that, using the proposed integrated concept in a typical 600 MW LRC-fired power plant could reduce the raw coal consumption by 4.6 kg/s with overall energy and exergy efficiencies improvement of 1.2 and 1.8 percentage points, respectively, as 73.0 MW th solar thermal energy was introduced. The cost of the solar generated electric power could be as low as $0.044/kW h. This work provides an improved concept to further advance the solar energy conversion and utilisation in solar-hybrid coal-fired power generation.

Mercury in coal and the impact of coal quality on mercury emissions from combustion systems

International Nuclear Information System (INIS)

Kolker, Allan; Senior, Constance L.; Quick, Jeffrey C.

2006-01-01

The proportion of Hg in coal feedstock that is emitted by stack gases of utility power stations is a complex function of coal chemistry and properties, combustion conditions, and the positioning and type of air pollution control devices employed. Mercury in bituminous coal is found primarily within Fe-sulfides, whereas lower rank coal tends to have a greater proportion of organic-bound Hg. Preparation of bituminous coal to reduce S generally reduces input Hg relative to in-ground concentrations, but the amount of this reduction varies according to the fraction of Hg in sulfides and the efficiency of sulfide removal. The mode of occurrence of Hg in coal does not directly affect the speciation of Hg in the combustion flue gas. However, other constituents in the coal, notably Cl and S, and the combustion characteristics of the coal, influence the species of Hg that are formed in the flue gas and enter air pollution control devices. The formation of gaseous oxidized Hg or particulate-bound Hg occurs post-combustion; these forms of Hg can be in part captured in the air pollution control devices that exist on coal-fired boilers, without modification. For a given coal type, the capture efficiency of Hg by pollution control systems varies according to type of device and the conditions of its deployment. For bituminous coal, on average, more than 60% of Hg in flue gas is captured by fabric filter (FF) and flue-gas desulfurization (FGD) systems. Key variables affecting performance for Hg control include Cl and S content of the coal, the positioning (hot side vs. cold side) of the system, and the amount of unburned C in coal ash. Knowledge of coal quality parameters and their effect on the performance of air pollution control devices allows optimization of Hg capture co-benefit

Energy Conversion Alternatives Study (ECAS)

Science.gov (United States)

1977-01-01

ECAS compared various advanced energy conversion systems that can use coal or coal-derived fuels for baseload electric power generation. It was conducted in two phases. Phase 1 consisted of parametric studies. From these results, 11 concepts were selected for further study in Phase 2. For each of the Phase 2 systems and a common set of ground rules, performance, cost, environmental intrusion, and natural resource requirements were estimated. In addition, the contractors defined the state of the associated technology, identified the advances required, prepared preliminary research and development plans, and assessed other factors that would affect the implementation of each type of powerplant. The systems studied in Phase 2 include steam systems with atmospheric- and pressurized-fluidized-bed boilers; combined cycle gas turbine/steam systems with integrated gasifiers or fired by a semiclean, coal derived fuel; a potassium/steam system with a pressurized-fluidized-bed boiler; a closed-cycle gas turbine/organic system with a high-temperature, atmospheric-fluidized-bed furnace; a direct-coal-fired, open- cycle magnetohydrodynamic/steam system; and a molten-carbonate fuel cell/steam system with an integrated gasifier. The sensitivity of the results to changes in the ground rules and the impact of uncertainties in capital cost estimates were also examined.

ANALYSIS ON CONFLICTS OF CHINA’S COAL TAX REFORM

Directory of Open Access Journals (Sweden)

Dong Wang

2014-01-01

Full Text Available This paper investigates the conflicts which are resulted from coal tax reform in China from economic and public policy perspectives. An analytical framework involving actors, values, interests and institution has been applied. China’s central government eagers to achieve fiscal revenue increase, environmental protection and energy conversation goals by a good governance of coal system. As a traditional and feasible policy instrument, taxation is regarded for dealing with energy issues in politics and governance. However, coal tax reform proposal has induced many controversies in China. The causes of that include value conflicts of all actors, competing interests of all parties and institutional barriers of economic, politics and legislation. Therefore, the government cannot regulate coal issues only through taxation. The case reveals that good governance on coal cannot be achieved only by economic tools as coal system contains so high stake and involves so many players.

Coal option. [Shell Co

Energy Technology Data Exchange (ETDEWEB)

1978-01-01

This paper notes the necessity of developing an international coal trade on a very large scale. The role of Shell in the coal industry is examined; the regions in which Shell companies are most active are Australia, Southern Africa, Indonesia; Europe and North America. Research is being carried out on marketing and transportation, especially via slurry pipelines; coal-oil emulsions; briquets; fluidized-bed combustion; recovery of coal from potential waste material; upgrading of low-rank coals; unconventional forms of mining; coal conversion (the Shell/Koppers high-pressure coal gasification process). Techniques for cleaning flue gas (the Shell Flue Gas Desulfurization process) are being examined.

Challenges of coal conversion for decarbonized energy in Poland

Energy Technology Data Exchange (ETDEWEB)

Sciazko, Marek; Jalosinski, Krzysztof; Majchrzak, Henryk; Michalski, Mieczyslaw; Tymowski, Henryk; Witos, Tadeusz; Wroblewska, Elzbieta

2010-09-15

Carbon dioxide is considered to be the main challenge for the coal-based power generation as well as for any other industrial application of coal. Poland's energy sector is primarily based on coal combustion that covers almost 90% of demand. Future development of that sector depends on the restriction on value of carbon dioxide emission or trading allowances. There are two main technological approaches to development of new coal based generation capacity, namely: gasification and pre-combustion capture; supercritical combustion and post-combustion capture. The current situation in development of three this type projects in Poland is presented.

Conversion of Coal Mine Gas to LNG

Energy Technology Data Exchange (ETDEWEB)

None, None

2016-02-05

This project evolved from a 1995, DOE-NETL competitive solicitation for practical CMM capture and utilization concepts. Appalachian Pacific was one of three companies selected to proceed with the construction and operation of a cost-shared demonstration plant. In the course of trying to proceed with this demonstration plant, AP examined several liquefaction technologies, discussed obtaining rights to coal mine methane with a number of coal companies, explored marketing potential with a wide variety of customers in many sections of the United States, studied in great detail the impact of a carbon credit exchange, and developed a suite of analytical tools with which to evaluate possible project options. In the end, the newness of the product, reluctance on the part of the coal companies to venture away from time tested practices, difficulty with obtaining financing, the failure of a carbon credit market to develop and the emergence of shale derived gas production prevented a demonstration plant from being built.

Modeling of the flame propagation in coal-dust- methane air mixture in an enclosed sphere volume

International Nuclear Information System (INIS)

Krainov, A Yu; Moiseeva, K M

2016-01-01

The results of the numerical simulation of the flame front propagation in coal-dust- methane-air mixture in an enclosed volume with the ignition source in the center of the volume are presented. The mathematical model is based on a dual-velocity two-phase model of the reacting gas-dispersion medium. The system of equations includes the mass-conversation equation, the impulse-conversation equation, the total energy-conversation equation of the gas and particles taking into account the thermal conductivity and chemical reactions in the gas and on the particle surface, mass-conversation equation of the mixture gas components considering the diffusion and the burn-out and the particle burn-out equation. The influence of the coal particle mass on the pressure in the volume after the mixture burn out and on the burn-out time has been investigated. It has been shown that the burning rate of the coal-dust methane air mixtures depends on the coal particle size. (paper)

Coal: the future in South Africa

Energy Technology Data Exchange (ETDEWEB)

1976-07-01

The whole issue is devoted to the future of coal in South Africa, and includes articles on the Petrick report, coal conversion research in South Africa, the activities of the Fuel Research Institute (on beneficiation, briquetting, carbonization, fluidized bed combustion), Sasol's production of chemical feedstocks from coal, mining methods, and the coal requirements of the electric and chemical industries.

Coal gasification. Quarterly report, April--June 1977

Energy Technology Data Exchange (ETDEWEB)

None

1978-01-01

The conversion of coal to high-Btu gas requires a chemical and physical transformation of solid coal. However, because coal has widely differing chemical and physical properties, depending on where it is mined, it is difficult to process. Therefore, to develop the most suitable techniques for gasifying coal, ERDA, together with the American Gas Association, is sponsoring the development of several advanced conversion processes. Although the basic coal-gasification chemical reactions are the same for each process, the processes under development have unique characteristics. A number of the processes for converting coal to high Btu and to low Btu gas have reached the pilot plant stage. The responsibility for designing, constructing and operating each of these pilot plants is defined and progress on each during the quarter is described briefly. The accumulation of data for a coal gasification manual and the development of mathematical models of coal gasification processes are reported briefly. (LTN)

Prospects for advanced coal-fuelled fuel cell power plants

International Nuclear Information System (INIS)

Jansen, D.; Laag, P.C. van der; Oudhuis, A.B.J.; Ribberink, J.S.

1994-01-01

As part of ECN's in-house R and D programmes on clean energy conversion systems with high efficiencies and low emissions, system assessment studies have been carried out on coal gasification power plants integrated with high-temperature fuel cells (IGFC). The studies also included the potential to reduce CO 2 emissions, and to find possible ways for CO 2 extraction and sequestration. The development of this new type of clean coal technology for large-scale power generation is still far off. A significant market share is not envisaged before the year 2015. To assess the future market potential of coal-fuelled fuel cell power plants, the promise of this fuel cell technology was assessed against the performance and the development of current state-of-the-art large-scale power generation systems, namely the pulverized coal-fired power plants and the integrated coal gasification combined cycle (IGCC) power plants. With the anticipated progress in gas turbine and gas clean-up technology, coal-fuelled fuel cell power plants will have to face severe competition from advanced IGCC power plants, despite their higher efficiency. (orig.)

Coal devolatilization and char conversion under suspension fired conditions in O2/N2 and O2/CO2 atmospheres

DEFF Research Database (Denmark)

Jensen, Anker Degn; Brix, Jacob; Jensen, Peter Arendt

2010-01-01

have been carried out in an electrically heated entrained flow reactor that is designed to simulate the conditions in a suspension fired boiler. Coal devolatilized in N2 and CO2 atmospheres provided similar results regarding char morphology, char N2-BET surface area and volatile yield. This strongly......The aim of the present investigation is to examine differences between O2/N2 and O2/CO2 atmospheres during devolatilization and char conversion of a bituminous coal at conditions covering temperatures between 1173 K and 1673 K and inlet oxygen concentrations between 5 and 28 vol.%. The experiments...

Studies of coupled chemical and catalytic coal conversion methods

Energy Technology Data Exchange (ETDEWEB)

Stock, L.M.

1990-01-01

This report concerns our research on base-catalyzed coal solubilization and a new approach for hydrogen addition. The work on base-catalyzed, chemical solubilization is continuing. this report is focused on the hydrogenation research. Specifically it deals with the use of arene chromium carbonyl complexes as reagents for the addition of dideuterium to coal molecules. In one phase of the work, he has established that the aromatic hydrocarbons in a representative coal liquid can be converted in very good yield to arene chromium carbonyl compounds. In a second phase of the work directly related to our objective of improved methods for catalytic hydrogenation, he has established that the aromatic constituents of the same coal liquid add dideuterium in the presence of added napththalene chromium carbonyl.

Palynology in coal systems analysis-The key to floras, climate, and stratigraphy of coal-forming environments

Science.gov (United States)

Nichols, D.J.

2005-01-01

Palynology can be effectively used in coal systems analysis to understand the nature of ancient coal-forming peat mires. Pollen and spores preserved in coal effectively reveal the floristic composition of mires, which differed substantially through geologic time, and contribute to determination of depositional environment and paleo- climate. Such applications are most effective when integrated with paleobotanical and coal-petrographic data. Examples of previous studies of Miocene, Carboniferous, and Paleogene coal beds illustrate the methods and results. Palynological age determinations and correlations of deposits are also important in coal systems analysis to establish stratigraphic setting. Application to studies of coalbed methane generation shows potential because certain kinds of pollen are associated with gas-prone lithotypes. ??2005 Geological Society of America.

Technology assessment of various coal-fuel options

International Nuclear Information System (INIS)

Coenen, R.; Findling, B.; Klein-Vielhauer, S.; Nieke, E.; Paschen, H.; Tangen, H.; Wintzer, D.

1991-01-01

The technology assessment (TA) study of coal-based fuels presented in this report was performed for the Federal Ministry for Research and Technology. Its goal was to support decision-making of the Federal Ministry for Research and Technology in the field of coal conversion. Various technical options of coal liquefaction have been analyzed on the basis of hard coal as well as lignite -- direct liquefaction of coal (hydrogenation) and different possibilities of indirect liquefaction, that is the production of fuels (methanol, gasoline) by processing products of coal gasification. The TA study takes into consideration the entire technology chain from coal mining via coal conversion to the utilization of coal-based fuels in road transport. The analysis focuses on costs of the various options, overall economic effects, which include effects on employment and public budgets, and on environmental consequences compared to the use of liquid fuels derived from oil. Furthermore, requirements of infrastructure and other problems of the introduction of coal-based fuels as well as prospects for the export of technologies of direct and indirect coal liquefaction have been analyzed in the study. 14 figs., 10 tabs

The effect of temperature and oxygen content on coal burnout

Energy Technology Data Exchange (ETDEWEB)

K. Milenkova; A.G. Borrego; D. Alvarez; J. Xiberta; R. Menendez [Instituto Nacional del Carbon, CSIC, Oviedo (Spain)

2003-07-01

In this study chars from six coals differing in rank and maceral composition have been prepared at 1100 and 1300{sup o}C in a drop tube reactor using four oxygen concentrations (0, 2.5, 10 and 21% oxygen). Char burnout, reactivity, morphology and optical texture have been considered in an attempt to understand the effect of temperature and oxygen concentration in relation to coal characteristics. Temperature has shown to have a different effect on conversion depending on coal rank. The high volatile coals showed similar conversions at 1100 and 1300{sup o}C at the various atmospheres tested, whereas higher rank coals showed higher conversions at 1300 than at 1100{sup o}C. The presence of oxygen in the reacting gas appears to have two opposite effects on coal combustion. On the one hand it prevents swelling and devolatilisation and on the other it enhances combustion. The burnout will depend on which process dominates. In addition, this effect appears to be temperature dependant and the inhibiting effect of oxygen on coal devolatilisation has shown to be higher at higher temperature, since at low temperature it only affects the lowest ranked coals. The presence of oxygen also affects the structure of carbonaceous material since the lower the oxygen concentration the higher the anisotropy development. The difference in temperature separating the two series of experiments (1000 and 1300{sup o}C) did not have a positive effect on the conversion of coals yielding highly porous chars whereas for coals yielding more dense structures higher conversions were achieved at higher temperatures. 7 refs., 5 figs., 1 tab.

40 CFR 60.254 - Standards for coal processing and conveying equipment, coal storage systems, transfer and loading...

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 6 2010-07-01 2010-07-01 false Standards for coal processing and conveying equipment, coal storage systems, transfer and loading systems, and open storage piles. 60.254... (CONTINUED) STANDARDS OF PERFORMANCE FOR NEW STATIONARY SOURCES Standards of Performance for Coal Preparation...

Summary of the APEC coal trade and investment liberalization and facilitation workshop: Facilitating trade and investment in Indonesia's coal energy sector

International Nuclear Information System (INIS)

Johnson, C.J.

1997-08-01

The Workshop brought together experts from APEC economies to discuss important issues related to coal development, trade and consumption in the APEC region, with a focus on Indonesia. Papers ranged from broad regional coal-related issues to specific policy and contract terms. The host, Indonesia, was selected as the focus of the workshop because it: (a) has APEC's fastest growing electricity sector, (b) is in the process of switching from oil based electricity generation to coal and natural gas-based generation, (c) is among the fastest growing coal exporters in APEC, and (d) has a contract system for coal development that has been widely accepted by foreign investors. In addition, Indonesia is in the process of revising its coal policies, and might benefit from the timely discussions in this workshop. The papers presented in the workshop spanned the coal chain from coal resources and reserves, conversion technologies, economics and markets, legal and policy issues, to community and cultural concerns. Participants represented government, industry and academic interests, and provided perspectives of coal and technology suppliers, consumers, energy policy makers and legal experts

Ambitious coal to gasoline plan

Energy Technology Data Exchange (ETDEWEB)

Taffe, P

1979-06-20

A design study carried out by Badger Energy concludes that the first US commercial gasoline from coal facility could be completed in eight years. The cost of gasoline would be 1.09 US dollars/gal. in 1990 with coal at 25 US dollars/ton. The process involves oxygen-blown coal gasification, conversion to methanol by the Mobil process, gas fractionation and HF alkylation.

The Nanticoke conversion study

Energy Technology Data Exchange (ETDEWEB)

NONE

2001-04-01

A study was conducted to assess the conversion of the Nanticoke coal-fired power plant to cleaner burning natural gas combined-cycle gas turbines. The Nanticoke Generating Station on Lake Erie is responsible for more than 50 per cent of Ontario Power Generation's (OPG) coal-fired electricity production. The OPG is proposing to work towards compliance with the newly signed Ozone Annex to the 1991 Canada-United States Air Quality Agreement which will require fossil-fueled power plants in southern Ontario to reduce their smog-causing nitrogen oxides emissions by about 50 per cent by 2007. This study assessed the emission reduction benefits and financial costs of conversion compared to continuing to operate Nanticoke as a coal-fired plant. The analysis includes a base case set of data on fuel prices, retrofit costs, fuel efficiencies, annual capacity factors and other parameters. It was determined that conversion would cost the average household less than $3 per month on their electricity bill. Conversion would also reduce emissions nitrogen oxide, a major smog pollutant, by 83 per cent and the particulates that form the most health-threatening portion of smog would be reduced by 100 per cent. 15 tabs., 1 fig.

Sustainable development with clean coal

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-08-01

This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

Cyclone reburn using coal-water fuel: Pilot-scale development and testing

Energy Technology Data Exchange (ETDEWEB)

Eckhart, C.F.; DeVault, R.F.

1991-10-01

There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

Promotive study on preparation of basis for foreign coal import. Study on coal renaissance

Energy Technology Data Exchange (ETDEWEB)

Muraoka, Yoji [Japan Economic Research Institute, Tokyo

1988-09-16

This is an interim report on the coal renaissance study carried out in 1987 as a part of the Promotive Study on Preparation of Basis for Foreign Coal Import. The background and ideology of coal renaissance, future aspect of demand for coal, problems pertaining to the expansion of application, and a proposal for the expansion of coal usage are described in order. The role of coal expected as an alternate fuel for petroleum, development of new application fields for coal, conversion to coal, contribution of Japan to the stablization of international coal supply are outlined. Coal renaissance aims, based on technology, at stimulation of coal demand, change in the image of coal, and the utilization of the accumulated abundant knowhow. The aspect of coal demand in 2000, solution and current status of various restricting factors relating to the use of coal in general industry, and the remaining problems are discussed. 6 figures, 10 tables.

Analysis on Conflicts of China’s Coal Tax Reform

OpenAIRE

Wang, Dong

2012-01-01

This paper investigates the conflicts which are resulted from coal tax reform in China from economic and public policy perspectives. An analytical framework involving actors, values, interests and institution has been applied. China’s central government eagers to achieve fiscal revenue increase, environmental protection and energy conversation goals by a good governance of coal system. As a traditional and feasible policy instrument, taxation is regarded for dealing with energy issues in poli...

Coal liquefaction still a dream

Energy Technology Data Exchange (ETDEWEB)

Overberg, H

1982-03-19

Liquefaction of coal is not profitable in West Germany and will not be so far some time to coal. This is true for West German and imported coal. The result may be improved but not changed by combined conversion of coal and top residues of distilleries. These are the main statements of a study carried out by Messrs. Veba Oel AG, Gelsenkirchen, on behalf of the Federal Minister for Research and Technology. The results of the study are presented in 20 volumes.

Optimal thermionic energy conversion with established electrodes for high-temperature topping and process heating. [coal combustion product environments

Science.gov (United States)

Morris, J. F.

1980-01-01

Applied research-and-technology (ART) work reveals that optimal thermionic energy conversion (TEC) with approximately 1000 K to approximately 1100 K collectors is possible using well established tungsten electrodes. Such TEC with 1800 K emitters could approach 26.6% efficiency at 27.4 W/sq cm with approximately 1000 K collectors and 21.7% at 22.6 W/sq cm with approximately 1100 K collectors. These performances require 1.5 and 1.7 eV collector work functions (not the 1 eV ultimate) with nearly negligible interelectrode losses. Such collectors correspond to tungsten electrode systems in approximately 0.9 to approximately 6 torr cesium pressures with 1600 K to 1900 K emitters. Because higher heat-rejection temperatures for TEC allow greater collector work functions, interelectrode loss reduction becomes an increasingly important target for applications aimed at elevated temperatures. Studies of intragap modifications and new electrodes that will allow better electron emission and collection with lower cesium pressures are among the TEC-ART approaches to reduced interelectrode losses. These solutions will provide very effective TEC to serve directly in coal-combustion products for high-temperature topping and process heating. In turn this will help to use coal and to use it well.

Effects of fractal pore on coal devolatilization

Energy Technology Data Exchange (ETDEWEB)

Chen, Yongli; He, Rong [Tsinghua Univ., Beijing (China). Dept. of Thermal Engineering; Wang, Xiaoliang; Cao, Liyong [Dongfang Electric Corporation, Chengdu (China). Centre New Energy Inst.

2013-07-01

Coal devolatilization is numerically investigated by drop tube furnace and a coal pyrolysis model (Fragmentation and Diffusion Model). The fractal characteristics of coal and char pores are investigated. Gas diffusion and secondary reactions in fractal pores are considered in the numerical simulations of coal devolatilization, and the results show that the fractal dimension is increased firstly and then decreased later with increased coal conversions during devolatilization. The mechanisms of effects of fractal pores on coal devolatilization are analyzed.

Solar energy conversion systems

CERN Document Server

Brownson, Jeffrey R S

2013-01-01

Solar energy conversion requires a different mind-set from traditional energy engineering in order to assess distribution, scales of use, systems design, predictive economic models for fluctuating solar resources, and planning to address transient cycles and social adoption. Solar Energy Conversion Systems examines solar energy conversion as an integrative design process, applying systems thinking methods to a solid knowledge base for creators of solar energy systems. This approach permits different levels of access for the emerging broad audience of scientists, engineers, architects, planners

Characterization of solid residues from coal liquefaction processes. Phase I

Energy Technology Data Exchange (ETDEWEB)

Potter, J.; McDougall, W.M.; Kybett, B.D.; Neufeld, C.

1981-01-01

Various coal liquefaction and beneficiation processes are being investigated by independent research groups sponsored by the Canadian Federal Government. These processes include the co-processing of heavy oils and bitumen with coal, oxygen removal and hydrogenation of coal and supercritical gas extraction of coal. The end products, gaseous and liquid fuels and insoluble organic residues, vary with the experimental conditions. The physical properties and origin of the insoluble residue may influence such factors as degree of conversion, efficiency of the process, and ultimately, gaseous and liquid yields. One of the most suitable methods of assessing the nature of the insoluble residues is the use of petrography. This report deals with petrographic assessment of the coals and residues from various coal conversion processes; attempts were made to characterize the solid phases in the residues; to assess them in a quantitative manner and where possible; to correlate the results with experimental data; and to assess their effects on conversion. (30 refs.)

Type and amount of organic amendments affect enhanced biogenic methane production from coal and microbial community structure

Science.gov (United States)

Davis, Katherine J.; Lu, Shipeng; Barnhart, Elliott P.; Parker, Albert E.; Fields, Matthew W.; Gerlach, Robin

2018-01-01

Slow rates of coal-to-methane conversion limit biogenic methane production from coalbeds. This study demonstrates that rates of coal-to-methane conversion can be increased by the addition of small amounts of organic amendments. Algae, cyanobacteria, yeast cells, and granulated yeast extract were tested at two concentrations (0.1 and 0.5 g/L), and similar increases in total methane produced and methane production rates were observed for all amendments at a given concentration. In 0.1 g/L amended systems, the amount of carbon converted to methane minus the amount produced in coal only systems exceeded the amount of carbon added in the form of amendment, suggesting enhanced coal-to-methane conversion through amendment addition. The amount of methane produced in the 0.5 g/L amended systems did not exceed the amount of carbon added. While the archaeal communities did not vary significantly, the bacterial populations appeared to be strongly influenced by the presence of coal when 0.1 g/L of amendment was added; at an amendment concentration of 0.5 g/L the bacterial community composition appeared to be affected most strongly by the amendment type. Overall, the results suggest that small amounts of amendment are not only sufficient but possibly advantageous if faster in situcoal-to-methane production is to be promoted.

Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

Energy Technology Data Exchange (ETDEWEB)

Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

1995-04-01

Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

Co-gasification of biomass and coal in a pressurised fluidised bed gasifier

Energy Technology Data Exchange (ETDEWEB)

Andries, L; Hein, K R.G. [Lab. for Thermal Power Engineering, Dept. of Mechanical Engineering and Marine Technology, Delft Univ. of Technology (Netherlands)

1997-12-31

The Laboratory for Thermal Power Engineering of the Delft University of Technology is participating in an EU funded, international, R + D project which is designed to aid European industry in addressing issues regarding co-utilisation of biomass and/or waste in advanced coal conversion processes. The project comprises three main programmes, each of which includes a number of smaller subprogrammes. The three main programmes are: Coal-biomass systems component development and design; Coal-biomass environmental studies; Techno-economic assessment studies. (orig)

Co-gasification of biomass and coal in a pressurised fluidised bed gasifier

Energy Technology Data Exchange (ETDEWEB)

Andries, L.; Hein, K.R.G. [Lab. for Thermal Power Engineering, Dept. of Mechanical Engineering and Marine Technology, Delft Univ. of Technology (Netherlands)

1996-12-31

The Laboratory for Thermal Power Engineering of the Delft University of Technology is participating in an EU funded, international, R + D project which is designed to aid European industry in addressing issues regarding co-utilisation of biomass and/or waste in advanced coal conversion processes. The project comprises three main programmes, each of which includes a number of smaller subprogrammes. The three main programmes are: Coal-biomass systems component development and design; Coal-biomass environmental studies; Techno-economic assessment studies. (orig)

Coal gasification. Quarterly report, January--March 1977

Energy Technology Data Exchange (ETDEWEB)

None

1977-12-01

High-Btu natural gas has a heating value of 950 to 1,000 Btu per standard cubic foot, is composed essentially of methane, and contains virtually no sulfur, carbon monoxide, or free hydrogen. The conversion of coal to high-Btu gas requires a chemical and physical transformation of solid coal. However, because coal has widely differing chemical and physical properties, depending on where it is mined, it is difficult to process. Therefore, to develop the most suitable techniques for gasifying coal, ERDA, together with the American Gas Association is sponsoring the development of several advanced conversion processes. Although the basic coal-gasification chemical reactions are the same for each process, the processes under development have unique characteristics. A number of the processes for converting coal to high Btu and to low Btu gas have reached the pilot plant stage. The responsibility for designing, constructing and operating each of these pilot plants is defined and progress on each during the quarter is described briefly. The accumulation of data for a coal gasification manual and the development of mathematical models of coal gasification processes are reported briefly. (LTN)

Fast fluid bed coal gasification for conversion of existing oil-fired boilers - an investigation of conditions precedent for commercial realization

Energy Technology Data Exchange (ETDEWEB)

1969-06-01

The syndicate Nordisk Fluidbaeddfoergasning which is made up of the following Scandinavian companies. A. Ahlstroem o/y Burmeister and Wain AB, Svenska Maskinverken AB and Svenska Cellulosa AB has been working with the development of a gas generator which makes it possible for the oil-fired boilers to use coal. The report describes a pre-project and presents the calculation of costs and the estimation of the market potential. The following appraisements have been made: (i) a commercially functioning plant can be erected (ii) the energy cost can be lower than the corresponding cost of conversion to coal powder fuel or competing gasifiers, and (iii) the size of the market is sufficiently large.

Phasing out coal : 2006 progress report

International Nuclear Information System (INIS)

2006-01-01

In 2001, Ontario's minister of the environment issued a legally binding regulation requiring the phase-out of coal burning at the Lakeview Generating Station by 2005. On June 13, 2006, the premier of Ontario broke the promise to phase-out Ontario's 4 remaining coal-fired power plants by 2009, and directed the Ontario Power Authority (OPA) to develop a plan for coal-fired electricity generation in the province to be replaced by cleaner sources in the earliest practical time frame that ensured adequate generating capacity and electricity system reliability in Ontario. This report reviewed key milestones in Ontario's move towards a complete coal phase-out and outlined actions that the current provincial government might take, should they choose to renew their promise to phase-out all of Ontario's coal-fired power plants by 2009. Ontario's coal-free electricity resources were calculated to the year 2012. Ontario's summer peak required electricity resources from the year 2010 to 2012 were assessed. The coal phase-out gap between 2009 and 2012 was also investigated. It was suggested that Ontario could achieve a complete coal phase-out by 2009 by pursuing a more aggressive conservation and demand management strategy, as well as by adopting more aggressive renewable procurement targets for 2010. The phase-out could also be achieved by procuring more cogeneration or combined heat and power resources. It was concluded that the conversion of the Thunder Bay Generating Station to natural gas would permit the phase-out of coal-burning at the Atikokan and Thunder Bay Generating Stations in 2007 without jeopardizing electricity system reliability in Ontario. 29 refs., 8 tabs

Joint verification project on environmentally friendly coal utilization systems. Joint verification project on the water-saving coal preparation system; Kankyo chowagata sekitan riyo system kyodo jissho jigyo. Shosuigata sentan system kyodo jissho jigyo

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-09-01

In this verification project, clean technology which should be spread in China was verified and the base structure for its spread was prepared for the purpose of controlling emissions of environmental pollutants associated with the coal utilization in China and of contributing to secure energy acquisition of Japan. As joint verification projects, a general rehabilitation type coal preparation system was installed in the Wangfenggang coal preparation plant, and a central control coal preparation system was installed in the Qingtan coal preparation plant. In the former, a system is verified in which optimum operation, water-saving, high quality, and heightening of efficiency can be obtained by introducing two computing systems for operation control and quality control, various measuring instruments, and analyzers to coal preparation plants where analog operation is conducted helped by Russia and Porland and have problems about quality control. In the latter, a central control system achieving water saving is verified by introducing rapid ash meters, scales, desitometers and computers to coal preparation plants having zigzag or heavy-fluid cyclon and connecting various kinds of information through network. For fiscal 1994, investigation and study were conducted. 51 figs., 9 tabs.

Oil from coal: just not worth it, say NCB

Energy Technology Data Exchange (ETDEWEB)

Grainger, L

1970-01-01

The creation of new markets by making oil fuels from coal in Britain is unresolved at this time. The dominant factor in the economics is the price ratio between coal and oil, which in Britain is 3 times less favorable than in the U.S. Current conversion results in a price more than double that of natural oil; however, the National Coal Board (NCB) continues to assess oil-from-coal processes. A sound research background in the new field of coal derivatives from solvent processing is being developed to produce materials of higher specific value than fuels. A continuous pilot plant is being built to prepare coke from filtered coal solution on the scale of a half-a-ton per week. Future prospects of the industry lie in areas where markets for coal will diminish, such as metallurgical coke. The fate of the coal industry will depend more and more on its largest market-electricity generation. In order to compete with nuclear power, the NCB is developing a new system of fluidized combustion.

Investigations of coal ignition in a short-range flame burner using optical measuring systems; Untersuchungen zur Kohlezuendung am Flachflammenbrenner unter Verwendung optischer Messtechnik

Energy Technology Data Exchange (ETDEWEB)

Hackert, G.; Kremer, H.; Wirtz, S. [Bochum Univ. (Germany). Lehrstuhl fuer Energieanlagentechnik

1999-09-01

The short-range flame burner and the KOALA reactor of DMT are experimental facilities for realistic simulation of coal conversion processes at high temperatures and pressures in atmospheric conditions. The TOSCA system enable measurements of temperatures, sizes, shapes and velocities of the fuel particles, which serve as a basis for a three-dimensional simulation model of coal combustion. In the future, further parameter studies will deepen the present knowledge of coal dust combustion under pressure and enable optimisation of the numerical models for simulation of industrial-scale systems for coal dust combustion under pressure. [Deutsch] Mit dem Flachflammenbrenner und dem KOALA-Reaktor der DMT stehen Versuchsapparaturen zur Verfuegung, mit deren Hilfe die Kohleumwandlungsprozesse bei hohen Temperaturen unter Druck und unter atmosphaerischen Bedingungen realistisch wiedergegeben werden. Das TOSCA-System erlaubt dabei die Bestimmung von Temperaturen, Groessen, Formen und Geschwindigkeiten der Brennstoffpartikel. Diese Daten liefern die Grundlage fuer die Erstellung eines dreidimensionalen Simulationsmodells zur Modellierung der Kohleverbrennung. In Zukunft werden weitere Parameterstudien das Verstaendnis der Kohlenstaubdruckverbrennung vertiefen und ein Optimierung der numerischen Modelle ermoeglichen, so dass die Simulation grosstechnischer Kohlenstaubdruckverbrennungsanlagen realisiert werden kann. (orig.)

Cyclone reburn using coal-water fuel: Pilot-scale development and testing. Final report

Energy Technology Data Exchange (ETDEWEB)

Eckhart, C.F.; DeVault, R.F.

1991-10-01

There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

Coal combustion by-product quality at two stoker boilers: Coal source vs. fly ash collection system design

Energy Technology Data Exchange (ETDEWEB)

Mardon, Sarah M. [Kentucky Department for Environmental Protection, Division of Water, Frankfort, KY 40601 (United States); Hower, James C. [University of Kentucky Center for Applied Energy Research, 2540 Research Park Drive, Lexington, KY 40511 (United States); O' Keefe, Jennifer M.K. [Morehead State University, Department of Physical Sciences, Morehead, KY 40351 (United States); Marks, Maria N. [Environmental Consulting Services, Lexington, KY 40508 (United States); Hedges, Daniel H. [University of Kentucky, Department of Earth and Environmental Sciences, Lexington, KY 40506 (United States)

2008-09-15

Fly ashes from two stoker boilers burning Pennsylvanian Eastern Kentucky high volatile A bituminous coal blends were examined for their petrology and chemistry. The source coals have similar trace element contents. One of the ash collection systems was retrofitted with a baghouse (fabric filter) system, collecting a finer fly ash at a cooler flue gas temperature than the plant that has not been reconfigured. The baghouse ash has a markedly higher trace element content than the coarser fly ash from the other plant. The enhanced trace element content is most notable in the As concentration, reaching nearly 9000 ppm (ash basis) for one of the collection units. Differences in the ash chemistry are not due to any substantial differences in the coal source, even though the coal sources were from different counties and from different coal beds, but rather to the improved pollution control system in the steam plant with the higher trace element contents. (author)

Preliminary experimental studies of waste coal gasification

Energy Technology Data Exchange (ETDEWEB)

Su, S.; Jin, Y.G.; Yu, X.X.; Worrall, R. [CSIRO, Brisbane, QLD (Australia). Advanced Coal Technology

2013-07-01

Coal mining is one of Australia's most important industries. It was estimated that coal washery rejects from black coal mining was approximately 1.82 billion tonnes from 1960 to 2009 in Australia, and is projected to produce another one billion tonnes by 2018 at the current production rate. To ensure sustainability of the Australian coal industry, we have explored a new potential pathway to create value from the coal waste through production of liquid fuels or power generation using produced syngas from waste coal gasification. Consequently, environmental and community impacts of the solid waste could be minimized. However, the development of an effective waste coal gasification process is a key to the new pathway. An Australian mine site with a large reserve of waste coal was selected for the study, where raw waste coal samples including coarse rejects and tailings were collected. After investigating the initial raw waste coal samples, float/sink testing was conducted to achieve a desired ash target for laboratory-scale steam gasification testing and performance evaluation. The preliminary gasification test results show that carbon conversions of waste coal gradually increase as the reaction proceeds, which indicates that waste coal can be gasified by a steam gasification process. However, the carbon conversion rates are relatively low, only reaching to 20-30%. Furthermore, the reactivity of waste coal samples with a variety of ash contents under N{sub 2}/air atmosphere have been studied by a home-made thermogravimetric analysis (TGA) apparatus that can make the sample reach the reaction temperature instantly.

Feasibility of an energy conversion system in Canada involving large-scale integrated hydrogen production using solid fuels

International Nuclear Information System (INIS)

Gnanapragasam, Nirmal V.; Reddy, Bale V.; Rosen, Marc A.

2010-01-01

A large-scale hydrogen production system is proposed using solid fuels and designed to increase the sustainability of alternative energy forms in Canada, and the technical and economic aspects of the system within the Canadian energy market are examined. The work investigates the feasibility and constraints in implementing such a system within the energy infrastructure of Canada. The proposed multi-conversion and single-function system produces hydrogen in large quantities using energy from solid fuels such as coal, tar sands, biomass, municipal solid waste (MSW) and agricultural/forest/industrial residue. The proposed system involves significant technology integration, with various energy conversion processes (such as gasification, chemical looping combustion, anaerobic digestion, combustion power cycles-electrolysis and solar-thermal converters) interconnected to increase the utilization of solid fuels as much as feasible within cost, environmental and other constraints. The analysis involves quantitative and qualitative assessments based on (i) energy resources availability and demand for hydrogen, (ii) commercial viability of primary energy conversion technologies, (iii) academia, industry and government participation, (iv) sustainability and (v) economics. An illustrative example provides an initial road map for implementing such a system. (author)

Catalytic coal liquefaction with treated solvent and SRC recycle

Science.gov (United States)

Garg, Diwakar; Givens, Edwin N.; Schweighardt, Frank K.

1986-01-01

A process for the solvent refining of coal to distillable, pentane soluble products using a dephenolated and denitrogenated recycle solvent and a recycled, pentane-insoluble, solvent-refined coal material, which process provides enhanced oil-make in the conversion of coal.

Analysis of coals and biomass pyrolysis using the distributed activation energy model.

Science.gov (United States)

Li, Zhengqi; Liu, Chunlong; Chen, Zhichao; Qian, Juan; Zhao, Wei; Zhu, Qunyi

2009-01-01

The thermal decomposition of coals and biomass was studied using thermogravimetric analysis with the distributed activation energy model. The integral method resulted in Datong bituminous coal conversions of 3-73% at activation energies of 100-486 kJ/mol. The corresponding frequency factors were e(19.5)-e(59.0)s(-1). Jindongnan lean coal conversions were 8-52% at activation energies of 100-462 kJ/mol. Their corresponding frequency factors were e(13.0)-e(55.8)s(-1). The conversion of corn-stalk skins were 1-84% at activation energies of 62-169 kJ/mol with frequency factors of e(10.8)-e(26.5)s(-1). Datong bituminous coal, Jindongnan lean coal and corn-stalk skins had approximate Gaussian distribution functions with linear ln k(0) to E relationships.

Characterization of seven United States coal regions. The development of optimal terrace pit coal mining systems

Energy Technology Data Exchange (ETDEWEB)

Wimer, R.L.; Adams, M.A.; Jurich, D.M.

1981-02-01

This report characterizes seven United State coal regions in the Northern Great Plains, Rocky Mountain, Interior, and Gulf Coast coal provinces. Descriptions include those of the Fort Union, Powder River, Green River, Four Corners, Lower Missouri, Illinois Basin, and Texas Gulf coal resource regions. The resource characterizations describe geologic, geographic, hydrologic, environmental and climatological conditions of each region, coal ranks and qualities, extent of reserves, reclamation requirements, and current mining activities. The report was compiled as a basis for the development of hypothetical coal mining situations for comparison of conventional and terrace pit surface mining methods, under contract to the Department of Energy, Contract No. DE-AC01-79ET10023, entitled The Development of Optimal Terrace Pit Coal Mining Systems.

Highly-productive mechanization systems for coal mining in the Polish coal industry

Energy Technology Data Exchange (ETDEWEB)

Sikora, W

1985-01-01

Effects of mechanization on underground coal mining in Poland from 1960 to 1980 and mining equipment used in Poland is reviewed. In 1983 black coal output increased to 191.1 Mt. There were 765 working faces, 442 of which with powered supports. Six hundred thirty-four shearer loaders were in use. About 82.7% of coal output fell on faces mined by sets of mining equipment (shearer loaders, powered supports and chain conveyors). The average coal output per working face amounted to 889 t/d. About 50% of mine roadways was driven by heading machines (346 heading machines were in use). The average coal output per face mined by a set of mining equipment amounted to 1248 t/d. About 86% of shearer loaders fell on double drum shearer loaders. Types of mining equipment used in underground mining are reviewed: powered supports (Pioma, Fazos, Glinik and the SOW), shearer loaders (drum shearer loaders and double-drum shearer loaders with chain haulage and chainless haulage systems for unidirectional and bi-directional mining), chain conveyors (Samson, Rybnik). Statistical data on working faces with various sets of equipment are given. 3 references.

Planning new coal-fired power plants

Energy Technology Data Exchange (ETDEWEB)

Benesch, W.A. [STEAG encotec GmbH, Essen (Germany)

2001-07-01

When considering fossil energy sources, it can be seen that natural gas and oil will become much scarcer than coal. Therefore, one practical option is to investigate and further develop coal-based energy supplies for the future. However, the existing coal stocks must be used very sparingly. Consequently, the conversion efficiency of the chemically-bonded energy in power and heat needs to be improved. By these means, and also by modern environmental engineering, power can be generated from coal without harming the environment. (orig.)

Challenges And Opportunities For Coal Gasification In Developing Countries

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-10-01

Coal gasification for chemicals, gaseous and liquid fuels production can fulfil an important strategic need in those developing countries where coal is the primary fuel source and oil and gas energy security is an issue. At the same time, the establishment of major projects in such countries can be problematical for a number of technical and economic reasons, although it is encouraging that some projects appear to be moving forward. There are two developing countries where coal conversion projects to produce chemicals, gaseous and liquid fuels have been taken forward strongly. The first is South Africa, which established the world's only commercial-scale coal-to-liquids and coal-to-chemicals facilities at Secunda and Sasolburg respectively. The other is China, where there is a major gasification-based coal conversion development and deployment programme that is set to become a significant, large-scale commercial element in the nation's energy development plans. This will provide further major opportunities for the deployment of large-scale coal gasification technologies, various syngas conversion units and catalysts for the subsequent production of the required products. The role of China is likely to be critical in the dissemination of such technologies to other developing countries as it can not only provide the technical expertise but also financially underpin such projects, including the associated infrastructure needs.

Rosebud SynCoal Partnership, SynCoal{reg_sign} demonstration technology update

Energy Technology Data Exchange (ETDEWEB)

Sheldon, R.W. [Rosebud SynCoal Partnership, Billings, MT (United States)

1997-12-31

An Advanced Coal Conversion Process (ACCP) technology being demonstrated in eastern Montana (USA) at the heart of one of the world`s largest coal deposits is providing evidence that the molecular structure of low-rank coals can be altered successfully to produce a unique product for a variety of utility and industrial applications. The product is called SynCoal{reg_sign} and the process has been developed by the Rosebud SynCoal Partnership (RSCP) through the US Department of Energy`s multi-million dollar Clean Coal Technology Program. The ACCP demonstration process uses low-pressure, superheated gases to process coal in vibrating fluidized beds. Two vibratory fluidized processing stages are used to heat and convert the coal. This is followed by a water spray quench and a vibratory fluidized stage to cool the coal. Pneumatic separators remove the solid impurities from the dried coal. There are three major steps to the SynCoal{reg_sign} process: (1) thermal treatment of the coal in an inert atmosphere, (2) inert gas cooling of the hot coal, and (3) removal of ash minerals. When operated continuously, the demonstration plant produces over 1,000 tons per day (up to 300,000 tons per year) of SynCoal{reg_sign} with a 2% moisture content, approximately 11,800b Btu/lb and less than 1.0 pound of SO{sub 2} per million Btu. This product is obtained from Rosebud Mine sub-bituminous coal which starts with 25% moisture, 8,600 Btu/lb and approximately 1.6 pounds of SO{sub 2} per million Btu.

Coal-related research, organic chemistry, and catalysis

International Nuclear Information System (INIS)

Anon.

1980-01-01

Coal chemistry research topics included: H exchange at 400 0 C, breaking C-C bonds in coal, molecular weight estimation using small-angle neutron scattering, 13 C NMR spectra of coals, and tunneling during H/D isotope effects. Studies of coal conversion chemistry included thermolysis of bibenzyl and 1-naphthol, heating of coals in phenol, advanced indirect liquefaction based on Koelbel slurry Fischer-Tropsch reactor, and plasma oxidation of coal minerals. Reactions of PAHs in molten SbCl 3 , a hydrocracking catalyst, were studied. Finally, heterogeneous catalysis (desulfurization etc.) was studied using Cu, Au, and Ni surfaces. 7 figures, 6 tables

Hard coal; Steinkohle

Energy Technology Data Exchange (ETDEWEB)

Loo, Kai van de; Sitte, Andreas-Peter [Gesamtverband Steinkohle e.V., Herne (Germany)

2013-04-01

The year 2012 benefited from a growth of the consumption of hard coal at the national level as well as at the international level. Worldwide, the hard coal still is the number one energy source for power generation. This leads to an increasing demand for power plant coal. In this year, the conversion of hard coal into electricity also increases in this year. In contrast to this, the demand for coking coal as well as for coke of the steel industry is still declining depending on the market conditions. The enhanced utilization of coal for the domestic power generation is due to the reduction of the nuclear power from a relatively bad year for wind power as well as reduced import prices and low CO{sub 2} prices. Both justify a significant price advantage for coal in comparison to the utilisation of natural gas in power plants. This was mainly due to the price erosion of the inexpensive US coal which partly was replaced by the expansion of shale gas on the domestic market. As a result of this, the inexpensive US coal looked for an outlet for sales in Europe. The domestic hard coal has continued the process of adaptation and phase-out as scheduled. Two further hard coal mines were decommissioned in the year 2012. RAG Aktiengesellschaft (Herne, Federal Republic of Germany) running the hard coal mining in this country begins with the preparations for the activities after the time of mining.

Efficient direct coal liquefaction of a premium brown coal catalyzed by cobalt-promoted fumed oxides

Energy Technology Data Exchange (ETDEWEB)

Trautmann, M.; Loewe, A.; Traa, Y. [Stuttgart Univ. (Germany). Inst. of Chemical Technology

2013-11-01

The search for alternatives in the fuel sector is an important technological challenge. An interim solution could be provided by direct coal liquefaction. Hydrogen economy and the lack of an efficient catalyst are the main obstacles for this process. We used a premium German brown coal with a high H/C molar ratio of 1.25 and nanostructured cobalt catalysts to improve the efficiency of direct coal liquefaction. We were able to recover and recycle the catalyst efficiently and reached good brown coal conversions and oil yields with single-stage coal liquefaction. The oil quality observed almost reached that of a conventional crude oil considering higher heating value (HHV), H/C molar ratio and aliphatic content. (orig.)

The application of the coal grain analysis method to coal liberation studies

Energy Technology Data Exchange (ETDEWEB)

O' Brien, G.; Firth, B.; Adair, B. [CSIRO Earth Science & Resource Engineering Brisbane, Qld. (Australia)

2011-07-01

Emerging coal markets such as the use of coal for conversion to liquid fuels and its use in fuels cells and as coal water slurries in diesel engines require coal products with different coal quality specifications than those applicable to traditional coal markets of coke making and conventional power generation. As well as quantifying coals in terms of their chemical and physical properties, detailed knowledge of the mineral inclusions within the coal particles is required to identify coals that are suited to economically produce the low-ash value coals required for these markets. After mining and processing, some particles can consist of essentially pure components of a single maceral or mineral phase whilst others are composite particles that are comprised of varying amounts of macerals and minerals. The proportion of particles that are present as pure components or as composites will be a function of the characteristics of the coal and the particle size. In general, it is considered that size reduction will result in liberation and hence increased yield. The amount of liberation that occurs during crushing or grinding a coal is however coal specific. Particle characterization information provided by an optical microscopic-imaging method, Coal Grain Analysis, was used to identify coals that might benefit from additional crushing to improve recovery of clean coal by new density separation techniques and by flotation. As expected, the results of these studies suggest that the degree of liberation that is obtained is coal specific, and, hence, yield improvements are also coal specific. Hence a quantitative method of investigating this issue is required.

Effect of Recycle Solvent Hydrotreatment on Oil Yield of Direct Coal Liquefaction

Directory of Open Access Journals (Sweden)

Shansong Gao

2015-07-01

Full Text Available Effects of the recycle solvent hydrotreatment on oil yield of direct coal liquefaction were carried out in the 0.18 t/day direct coal liquefaction bench support unit of National Engineering Laboratory for Direct Coal Liquefaction (China. Results showed that the hydrogen-donating ability of the hydrogenated recycle solvent improved and the hydrogen consumption of solvent hydrotreatment was increased by decreasing liquid hourly space velocity (LHSV from 1.5 to 1.0 h−1 and increasing reaction pressure from 13.7 to 19.0 MPa. The hydrogen-donating ability of the hydrogenated recycle solvent was enhanced, thus promoting the oil yield and coal conversion of the liquefaction reaction. The coal conversion and distillates yield of coal liquefaction were increased from 88.74% to 88.82% and from 47.41% to 49.10%, respectively, with the increase in the solvent hydrotreatment pressure from 13.7 to 19.0 MPa. The coal conversion and distillates of coal liquefaction were increased from 88.82% to 89.27% and from 49.10% to 54.49%, respectively, when the LHSV decreased from 1.5 to 1.0 h−1 under the solvent hydrotreatment pressure of 19.0 MPa.

Study on denitration technology of coal char reduction method

Directory of Open Access Journals (Sweden)

Wenjie FU

2016-06-01

Full Text Available In order to more effectively control NO emissions in coal-fired flue gas, the denitration reaction is carried out with simulated industrial boiler flue gas in a fixed bed reactor. The influence of char types, reaction conditions, the composition of flue gas and other factors on the conversion rate of NO are discussed. The result shows that the industrial semi-coke is the most suitable experimental coal in the three coals studied, and the industrial semi-coke particle size of 0.6 ~ 10 mm is relatively suitable; The conversion rate of NO increases gradually with the increase of temperature, and when the reaction temperature is 700 ℃ and the space velocity is 10 000 h^-1, the conversion rate of NO can reach 99%; the conversion rate of NO decreases gradually as airspeed increases, but the airspeed change has no effect on the conversion rate of NO at 700 ℃; under anaerobic conditions,the change of NO concentration has no effect on the conversion rate of NO; at the same temperature, NO conversion rate is higher at the presence of oxygen compared with that at anaerobic situation, and the conversion rate of NO is the highest when O2 concentration is 4%; under aerobic conditions, the concentration change of SO2 and CO2 has no effect on the conversion rate of NO.

Fuel production from coal by the Mobil Oil process using nuclear high-temperature process heat

International Nuclear Information System (INIS)

Hoffmann, G.

1982-01-01

Two processes for the production of liquid hydrocarbons are presented: Direct conversion of coal into fuel (coal hydrogenation) and indirect conversion of coal into fuel (syngas production, methanol synthesis, Mobil Oil process). Both processes have several variants in which nuclear process heat may be used; in most cases, the nuclear heat is introduced in the gas production stage. The following gas production processes are compared: LURGI coal gasification process; steam reformer methanation, with and without coal hydrogasification and steam gasification of coal. (orig./EF) [de

Development of a dry-feed system for a coal-fired gas turbine

Energy Technology Data Exchange (ETDEWEB)

Rothrock, J.W. Jr.; Smith, C.F.

1993-11-01

The objective of the reported of the reported work is to develop a dry coal feed system that provides smooth, controllable flow of coal solids into the high pressure combustor of the engine and all test rigs. The system must start quickly and easily, run continuously with automatic transfer of coal from low pressure hoppers to the high pressure delivery system, and offer at least a 3:1 smooth turn-down ratio. cost of the equipment must be minimized to maintain the economic attractiveness of the whole system. Before the current contract started some work was done with dry powder coal. For safety and convenience reasons, coal water slurry was selected as the fuel for all work on the program. Much of the experimental work, including running the Allison 501-KM engine was done with coal slurry. Recent economic analysis led to a change to powdered coal.

Role of non-ferrous coal minerals and by-product metallic wastes in coal liquefaction. Technical progress report, March 1, 1981-May 31, 1981

Energy Technology Data Exchange (ETDEWEB)

Garg, D.; Givens, E.N.; Schweighardt, F.K.; Curtis, C.W.; Guin, J.A.; Huang, W.J.; Shridharani, K.

1981-06-01

This report covers results from both tubing-bomb experiments and continuous PDU runs. The following materials were evaluated in the PDU on Elkhorn No. 2 coal from Floyd County, Kentucky: Molybdic oxides; iron oxide; pyrite; pyrite/iron oxide mixture, and iron sulfate impregnation. A base case liquefaction run was also made for direct comparison. All of the above materials were examined at both 825 and 850/sup 0/F. Tubing-bomb experiments are reported on pyrite, red mud, sodium sulfide and organic compounds of cobalt, nickel, molybdenum, zinc, chromium and lead. Significant conclusions were drawn on the catalysis by different materials. Especially significant was the higher level of activity resulting from impregnation versus particle incorporation of the catalyst in the system. Impregnation of coal decreased the hydrocarbon gases yield and increased oil yield. Hydrogen consumption was significantly reduced by impregnation. Addition of molybdic oxide containing 90% MoO/sub 3/ and 10% silica to coal liquefaction reaction mixture had the following effect: coal conversion increased, oil yield increased by more than a factor of two at both temperatures, hydrogen consumption increased, solvent/oil fraction showed substantial increase in hydrogen content, and molybdenum in the resulting liquefaction residue was apparently transformed into an amorphous material. A more thorough evaluation of completely sulfided molybdenum will be made to see if its activity increases. In the tubing-bomb experiments organic compound of molybdenum showed the highest activity for coal conversion and oil production. Significant synergism was noted between red mud and sodium sulfide in the coal liquefaction reaction.

Continuous mercury monitors conditioning/conversion systems : what we have learned

Energy Technology Data Exchange (ETDEWEB)

Laudal, D.L.; Dunham, G.E.; Thompson, J.S. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

2006-07-01

The challenges of continuous mercury monitoring (CMM) in flue gas were discussed with reference to conditioning/conversion systems where a sample of gas of an unknown composition is conditioned to elemental mercury. Flue gas composition varies greatly depending on coal type and plant configuration. The widely used wet-chemistry systems remove interfering gas constituents by bubbling the sample gas through reactive solutions. Some concerns with the wet systems are the amount of chemicals used and the volume of the waste generated; capture of CO{sub 2} which affects the sample volume; mercury hang-up; condensation of flue gas constituents; and, potential for unidentified chemical reactions. The advantages of dry systems were discussed, such as the ability to convert all of the mercury present in the flue gas to elemental mercury. Some of the main concerns with dry systems are that some systems will require a correction for moisture, which means installing a moisture monitor. Dry systems can also be prone to mercury hang-up and calibration of some of the dilution systems remains a concern. The systems can also be susceptible a significant decrease in catalyst life. figs.

Modeling technological learning and its application for clean coal technologies in Japan

International Nuclear Information System (INIS)

Nakata, Toshihiko; Sato, Takemi; Wang, Hao; Kusunoki, Tomoya; Furubayashi, Takaaki

2011-01-01

Estimating technological progress of emerging technologies such as renewables and clean coal technologies becomes important for designing low carbon energy systems in future and drawing effective energy policies. Learning curve is an analytical approach for describing the decline rate of cost and production caused by technological progress as well as learning. In the study, a bottom-up energy-economic model including an endogenous technological learning function has been designed. The model deals with technological learning in energy conversion technologies and its spillover effect. It is applied as a feasibility study of clean coal technologies such as IGCC (Integrated Coal Gasification Combined Cycle) and IGFC (Integrated Coal Gasification Fuel Cell System) in Japan. As the results of analysis, it is found that technological progress by learning has a positive impact on the penetration of clean coal technologies in the electricity market, and the learning model has a potential for assessing upcoming technologies in future.

Microbial transformation of coal and coal relevant structures - presentation of a BMBF joint research project

Energy Technology Data Exchange (ETDEWEB)

Sinder, C.; Schacht, S.; Pfeifer, F.; Klein, J. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany)

1997-12-31

Investigations in the joint research project `Microbial transformation of coal and coal relevant structures` supported by the Ministry of Education, Science, Research and Technology (BMBF) of the Federal Republic of Germany and coordinated by the DMT-Gesellschaft fuer Forschung und Pruefung mbH (DMT) are focussed on research and development of biotechnological coal conversion processes. Up to now investigations carried out in the project lead to a number of important results. During work on the project a great number of different microorganisms was found able to degrade or solubilize coal or lignite. Enzymatic as well as regulation mechanisms of the microbial depolymerization processes have been characterized successfully. (orig.)

Hydrogen production from coal gasification for effective downstream CO{sub 2} capture

Energy Technology Data Exchange (ETDEWEB)

Gnanapragasam, Nirmal V.; Reddy, Bale V.; Rosen, Marc A. [Faculty of Engineering and Applied Science, University of Ontario Institute of Technology, 2000 Simcoe Street North, Oshawa, Ontario, L1H 7K4 (Canada)

2010-05-15

The coal gasification process is used in commercial production of synthetic gas as a means toward clean use of coal. The conversion of solid coal into a gaseous phase creates opportunities to produce more energy forms than electricity (which is the case in coal combustion systems) and to separate CO{sub 2} in an effective manner for sequestration. The current work compares the energy and exergy efficiencies of an integrated coal-gasification combined-cycle power generation system with that of coal gasification-based hydrogen production system which uses water-gas shift and membrane reactors. Results suggest that the syngas-to-hydrogen (H{sub 2}) system offers 35% higher energy and 17% higher exergy efficiencies than the syngas-to-electricity (IGCC) system. The specific CO{sub 2} emission from the hydrogen system was 5% lower than IGCC system. The Brayton cycle in the IGCC system draws much nitrogen after combustion along with CO{sub 2}. Thus CO{sub 2} capture and compression become difficult due to the large volume of gases involved, unlike the hydrogen system which has 80% less nitrogen in its exhaust stream. The extra electrical power consumption for compressing the exhaust gases to store CO{sub 2} is above 70% for the IGCC system but is only 4.5% for the H{sub 2} system. Overall the syngas-to-hydrogen system appears advantageous to the IGCC system based on the current analysis. (author)

Model documentation, Coal Market Module of the National Energy Modeling System

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-01-01

This report documents the objectives and the conceptual and methodological approach used in the development of the National Energy Modeling System`s (NEMS) Coal Market Module (CMM) used to develop the Annual Energy Outlook 1998 (AEO98). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of CMM`s two submodules. These are the Coal Production Submodule (CPS) and the Coal Distribution Submodule (CDS). CMM provides annual forecasts of prices, production, and consumption of coal for NEMS. In general, the CDS integrates the supply inputs from the CPS to satisfy demands for coal from exogenous demand models. The international area of the CDS forecasts annual world coal trade flows from major supply to major demand regions and provides annual forecasts of US coal exports for input to NEMS. Specifically, the CDS receives minemouth prices produced by the CPS, demand and other exogenous inputs from other NEMS components, and provides delivered coal prices and quantities to the NEMS economic sectors and regions.

Coal preparation

International Nuclear Information System (INIS)

Anon.

1991-01-01

The acid rain control legislation has prompted the Department of Energy (DOE) to seek new technology using the Clean Coal Technology program solicitation. The main goal of the program is to reduce SO 2 emissions below 9 Mt/a (10 million stpy) and NO x emission below 5.4 Mt/a (6 million stpy) by the year 2000. This would be accomplished by using precombustion, combustion, post combustion and conversion technology. Utilities are considering installing new scrubbers, switching fuel or possibly deep clean. However, the time required to implement the control technology is short. Due to the legislation, about 110 plants will have to adopt one of the approaches. This paper reports that in characterization of coal, Ames Laboratory used a scanning electron microscope- based, automated image analysis (SEM-AIA) technique to identify coal and mineral matter association. Various forms of organic sulfur were identified using peroxyacetic acid oxidation of coal. This was followed by subsequent microscopic, GC-MS, and HRMS analysis by Southern Illinois University. In ultrafine grinding of coal, it was reported by the Mining and Mineral Institute of Alabama that silica sand or flint shot used less energy compared to steel ball mills

Low-temperature catalytic conversion of carbonaceous materials

Directory of Open Access Journals (Sweden)

Tabakaev Roman B.

2015-01-01

Full Text Available Laws of the rate of carbon conversion in steam atmosphere at a temperature in modes of the catalytic low-temperature treatment of peat, brown coal, semi-coke from peat and brown coal are obtained by experiments. Increasing of the rate of carbon conversion in temperature range up to 500 °C is achieved by using of catalysts. The possibility of using results is associated with the burners, a working zone of which is porous filling from carbonaceous particles.

Gas core reactors for coal gasification

International Nuclear Information System (INIS)

Weinstein, H.

1976-01-01

The concept of using a gas core reactor to produce hydrogen directly from coal and water is presented. It is shown that the chemical equilibrium of the process is strongly in favor of the production of H 2 and CO in the reactor cavity, indicating a 98 percent conversion of water and coal at only 1500 0 K. At lower temperatures in the moderator-reflector cooling channels the equilibrium strongly favors the conversion of CO and additional H 2 O to CO 2 and H 2 . Furthermore, it is shown the H 2 obtained per pound of carbon has 23 percent greater heating value than the carbon so that some nuclear energy is also fixed. Finally, a gas core reactor plant floating in the ocean is conceptualized which produces H 2 , fresh water and sea salts from coal

Boiler briquette coal versus raw coal: Part I--Stack gas emissions.

Science.gov (United States)

Ge, S; Bai, Z; Liu, W; Zhu, T; Wang, T; Qing, S; Zhang, J

2001-04-01

Stack gas emissions were characterized for a steam-generating boiler commonly used in China. The boiler was tested when fired with a newly formulated boiler briquette coal (BB-coal) and when fired with conventional raw coal (R-coal). The stack gas emissions were analyzed to determine emission rates and emission factors and to develop chemical source profiles. A dilution source sampling system was used to collect PM on both Teflon membrane filters and quartz fiber filters. The Teflon filters were analyzed gravimetrically for PM10 and PM2.5 mass concentrations and by X-ray fluorescence (XRF) for trace elements. The quartz fiber filters were analyzed for organic carbon (OC) and elemental carbon (EC) using a thermal/optical reflectance technique. Sulfur dioxide was measured using the standard wet chemistry method. Carbon monoxide was measured using an Orsat combustion analyzer. The emission rates of the R-coal combustion (in kg/hr), determined using the measured stack gas concentrations and the stack gas emission rates, were 0.74 for PM10, 0.38 for PM2.5, 20.7 for SO2, and 6.8 for CO, while those of the BB-coal combustion were 0.95 for PM10, 0.30 for PM2.5, 7.5 for SO2, and 5.3 for CO. The fuel-mass-based emission factors (in g/kg) of the R-coal, determined using the emission rates and the fuel burn rates, were 1.68 for PM10, 0.87 for PM2.5, 46.7 for SO2, and 15 for CO, while those of the BB-coal were 2.51 for PM10, 0.79 for PM2.5, 19.9 for SO2, and 14 for CO. The task-based emission factors (in g/ton steam generated) of the R-coal, determined using the fuel-mass-based emission factors and the coal/steam conversion factors, were 0.23 for PM10, 0.12 for PM2.5, 6.4 for SO2, and 2.0 for CO, while those of the BB-coal were 0.30 for PM10, 0.094 for PM2.5, 2.4 for SO2, and 1.7 for CO. PM10 and PM2.5 elemental compositions are also presented for both types of coal tested in the study.

Boiler Briquette Coal versus Raw Coal: Part I-Stack Gas Emissions.

Science.gov (United States)

Ge, Su; Bai, Zhipeng; Liu, Weili; Zhu, Tan; Wang, Tongjian; Qing, Sheng; Zhang, Junfeng

2001-04-01

Stack gas emissions were characterized for a steam-generating boiler commonly used in China. The boiler was tested when fired with a newly formulated boiler briquette coal (BB-coal) and when fired with conventional raw coal (R-coal). The stack gas emissions were analyzed to determine emission rates and emission factors and to develop chemical source profiles. A dilution source sampling system was used to collect PM on both Teflon membrane filters and quartz fiber filters. The Teflon filters were analyzed gravimetrically for PM 10 and PM 2.5 mass concentrations and by X-ray fluorescence (XRF) for trace elements. The quartz fiber filters were analyzed for organic carbon (OC) and elemental carbon (EC) using a thermal/optical reflectance technique. Sulfur dioxide was measured using the standard wet chemistry method. Carbon monoxide was measured using an Orsat combustion analyzer. The emission rates of the R-coal combustion (in kg/hr), determined using the measured stack gas concentrations and the stack gas emission rates, were 0.74 for PM 10 , 0.38 for PM 25 , 20.7 for SO 2 , and 6.8 for CO, while those of the BB-coal combustion were 0.95 for PM 10 , 0.30 for PM 2 5 , 7.5 for SO 2 , and 5.3 for CO. The fuel-mass-based emission factors (in g/kg) of the R-coal, determined using the emission rates and the fuel burn rates, were 1.68 for PM 10 , 0.87 for PM 25 , 46.7 for SO 2 , and 15 for CO, while those of the BB-coal were 2.51 for PM 10 , 0.79 for PM 2.5 , 19.9 for SO 2 , and 14 for CO. The task-based emission factors (in g/ton steam generated) of the R-coal, determined using the fuel-mass-based emission factors and the coal/ steam conversion factors, were 0.23 for PM 10 , 0.12 for PM 2.5 , 6.4 for SO 2 , and 2.0 for CO, while those of the BB-coal were 0.30 for PM 10 , 0.094 for PM 2.5 , 2.4 for SO 2 , and 1.7 for CO. PM 10 and PM 2.5 elemental compositions are also presented for both types of coal tested in the study.

Using plasma-fuel systems at Eurasian coal-fired thermal power stations

Science.gov (United States)

Karpenko, E. I.; Karpenko, Yu. E.; Messerle, V. E.; Ustimenko, A. B.

2009-06-01

The development of plasma technology for igniting solid fuels at coal-fired thermal power stations in Russia, Kazakhstan, China, and other Eurasian countries is briefly reviewed. Basic layouts and technical and economic characteristics of plasma-fuel systems installed in different coal-fired boiles are considered together with some results from using these systems at coal-fired thermal power stations.

Coal liquefaction and gas conversion: Proceedings. Volume 1

Energy Technology Data Exchange (ETDEWEB)

1993-12-31

Volume I contains papers presented at the following sessions: AR-Coal Liquefaction; Gas to Liquids; and Direct Liquefaction. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

Research program for an environmentally-friendly coal utilization system in the Philippines

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

Feasibility studies are conducted on the introduction of an environmentally-friendly coal utilization system into the Filipino electric power industry, cement industry, and domestic fuel sector. The studies cover the current status of economy and energy in that country, supply and demand of coal, environmental protection and Government's policy, study of the above-said system relative to its application to the fields of electric power industry, cement industry, and domestic fuel sector, and a study about the effective utilization of Filipino domestic coal by the use of the system. Imported coal is used in the electric power industry because of its cost and quality. It is learned after research, however, that domestic coal will be able to compete against imported coal when some technologies are resorted to, such as those pertinent to denitrification in the furnace, novel low-NOx burner, coal pulverization, and combustion diagnosis. As for the treatment of flue gas, it is concluded that the simplified wet lime/gypsum process will be suitable. It is inferred that the CWM (coal-water mixture) process technology will be effective for the utilization of domestic low-grade coal. (NEDO)

Research program for an environmentally-friendly coal utilization system in the Philippines

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

Feasibility studies are conducted on the introduction of an environmentally-friendly coal utilization system into the Filipino electric power industry, cement industry, and domestic fuel sector. The studies cover the current status of economy and energy in that country, supply and demand of coal, environmental protection and Government's policy, study of the above-said system relative to its application to the fields of electric power industry, cement industry, and domestic fuel sector, and a study about the effective utilization of Filipino domestic coal by the use of the system. Imported coal is used in the electric power industry because of its cost and quality. It is learned after research, however, that domestic coal will be able to compete against imported coal when some technologies are resorted to, such as those pertinent to denitrification in the furnace, novel low-NOx burner, coal pulverization, and combustion diagnosis. As for the treatment of flue gas, it is concluded that the simplified wet lime/gypsum process will be suitable. It is inferred that the CWM (coal-water mixture) process technology will be effective for the utilization of domestic low-grade coal. (NEDO)

Catalytic Process for the Conversion of Coal-derived Syngas to Ethanol

Energy Technology Data Exchange (ETDEWEB)

James Spivery; Doug Harrison; John Earle; James Goodwin; David Bruce; Xunhau Mo; Walter Torres; Joe Allison Vis Viswanathan; Rick Sadok; Steve Overbury; Viviana Schwartz

2011-07-29

The catalytic conversion of coal-derived syngas to C{sub 2+} alcohols and oxygenates has attracted great attention due to their potential as chemical intermediates and fuel components. This is particularly true of ethanol, which can serve as a transportation fuel blending agent, as well as a hydrogen carrier. A thermodynamic analysis of CO hydrogenation to ethanol that does not allow for byproducts such as methane or methanol shows that the reaction: 2 CO + 4 H{sub 2} {yields} C{sub 2}H{sub 5}OH + H{sub 2}O is thermodynamically favorable at conditions of practical interest (e.g,30 bar, {approx}< 250 C). However, when methane is included in the equilibrium analysis, no ethanol is formed at any conditions even approximating those that would be industrially practical. This means that undesired products (primarily methane and/or CO{sub 2}) must be kinetically limited. This is the job of a catalyst. The mechanism of CO hydrogenation leading to ethanol is complex. The key step is the formation of the initial C-C bond. Catalysts that are selective for EtOH can be divided into four classes: (a) Rh-based catalysts, (b) promoted Cu catalysts, (c) modified Fischer-Tropsch catalysts, or (d) Mo-sulfides and phosphides. This project focuses on Rh- and Cu-based catalysts. The logic was that (a) Rh-based catalysts are clearly the most selective for EtOH (but these catalysts can be costly), and (b) Cu-based catalysts appear to be the most selective of the non-Rh catalysts (and are less costly). In addition, Pd-based catalysts were studied since Pd is known for catalyzing CO hydrogenation to produce methanol, similar to copper. Approach. The overall approach of this project was based on (a) computational catalysis to identify optimum surfaces for the selective conversion of syngas to ethanol; (b) synthesis of surfaces approaching these ideal atomic structures, (c) specialized characterization to determine the extent to which the actual catalyst has these structures, and (d) testing

Feasibility survey of the environmentally-friendly coal utilization system. Feasibility survey of the environmentally-friendly coal utilization system in Indonesia; Kankyo chowagata sekitan riyo system kanosei chosa. Indonesia ni okeru kankyo chowagata sekitan riyo system kanosei chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-03-01

With relation to the coal of Indonesia, where the expansion of the use of coal as a substitute for petroleum/plant fuel is aimed at, the paper grasped the situation of coal production/distribution/utilization and environmental problems, and analyzed the situation of the coal utilization/spread by industry including the commercial/residential use. The purpose of the survey is to work out a comprehensive master plan including Japan`s international cooperation for introducing the environmentally-friendly coal utilization system to Indonesia. Coal utilization systems, the introduction of which Indonesia should study in future, were picked up, according to the surveys in fiscal 1993 and 1994. In commercial/residential and small-scale industry sectors, needed is improvement of carbonization technology for production of coal carbonization briquette. Moreover, the introduction of bio-briquette should be studied in the future. In the power generation sector, studies should be made on the introduction of technology for SOx/NOx reduction and technology for coal ash treatment including the effective use of coal ash. For the introduction of coal boilers, the combustion mixed with bagasse, which is abundant in amount, is also necessary. In the coal production sector, coal preparation technology is studied, and a method to select the optimum process was proposed through the simulation. 76 figs., 43 tabs.

Inorganic Constituents in Coal

Directory of Open Access Journals (Sweden)

Rađenović A.

2006-02-01

Full Text Available Coal contains not only organic matter but also small amounts of inorganic constituents. More thanone hundred different minerals and virtually every element in the periodic table have been foundin coal. Commonly found group minerals in coal are: major (quartz, pyrite, clays and carbonates,minor, and trace minerals. Coal includes a lot of elements of low mass fraction of the orderof w=0.01 or 0.001 %. They are trace elements connected with organic matter or minerals comprisedin coal. The fractions of trace elements usually decrease when the rank of coal increases.Fractions of the inorganic elements are different, depending on the coal bed and basin. A varietyof analytical methods and techniques can be used to determine the mass fractions, mode ofoccurrence, and distribution of organic constituents in coal. There are many different instrumentalmethods for analysis of coal and coal products but atomic absorption spectroscopy – AAS is theone most commonly used. Fraction and mode of occurrence are one of the main factors that haveinfluence on transformation and separation of inorganic constituents during coal conversion.Coal, as an important world energy source and component for non-fuels usage, will be continuouslyand widely used in the future due to its relatively abundant reserves. However, there is aconflict between the requirements for increased use of coal on the one hand and less pollution onthe other. It’s known that the environmental impacts, due to either coal mining or coal usage, canbe: air, water and land pollution. Although, minor components, inorganic constituents can exert asignificant influence on the economic value, utilization, and environmental impact of the coal.

Biomass energy conversion: conventional and advanced technologies

Energy Technology Data Exchange (ETDEWEB)

Young, B C; Hauserman, W B [Energy and Environmental Research Center, University of North Dakota, Grand Forks, ND (United States)

1995-12-01

Increasing interest in biomass energy conversion in recent years has focused attention on enhancing the efficiency of technologies converting biomass fuels into heat and power, their capital and operating costs and their environmental emissions. Conventional combustion systems, such as fixed-bed or grate units and entrainment units, deliver lower efficiencies (<25%) than modem coal-fired combustors (30-35%). The gasification of biomass will improve energy conversion efficiency and yield products useful for heat and power generation and chemical synthesis. Advanced biomass gasification technologies using pressurized fluidized-bed systems, including those incorporating hot-gas clean-up for feeding gas turbines or fuel cells, are being demonstrated. However, many biomass gasification processes are derivatives of coal gasification technologies and do not exploit the unique properties of biomass. This paper examines some existing and upcoming technologies for converting biomass into electric power or heat. Small-scale 1-30 MWe units are emphasized, but brief reference is made to larger and smaller systems, including those that bum coal-biomass mixtures and gasifiers that feed pilot-fuelled diesel engines. Promising advanced systems, such as a biomass integrated gasifier/gas turbine (BIG/GT) with combined-cycle operation and a biomass gasifier coupled to a fuel cell, giving cycle efficiencies approaching 50% are also described. These advanced gasifiers, typically fluid-bed designs, may be pressurized and can use a wide variety of biomass materials to generate electricity, process steam and chemical products such as methanol. Low-cost, disposable catalysts are becoming available for hot-gas clean-up (enhanced gas composition) for turbine and fuel cell systems. The advantages, limitations and relative costs of various biomass gasifier systems are briefly discussed. The paper identifies the best known biomass power projects and includes some information on proposed and

Biomass energy conversion: conventional and advanced technologies

International Nuclear Information System (INIS)

Young, B.C.; Hauserman, W.B.

1995-01-01

Increasing interest in biomass energy conversion in recent years has focused attention on enhancing the efficiency of technologies converting biomass fuels into heat and power, their capital and operating costs and their environmental emissions. Conventional combustion systems, such as fixed-bed or grate units and entrainment units, deliver lower efficiencies (<25%) than modem coal-fired combustors (30-35%). The gasification of biomass will improve energy conversion efficiency and yield products useful for heat and power generation and chemical synthesis. Advanced biomass gasification technologies using pressurized fluidized-bed systems, including those incorporating hot-gas clean-up for feeding gas turbines or fuel cells, are being demonstrated. However, many biomass gasification processes are derivatives of coal gasification technologies and do not exploit the unique properties of biomass. This paper examines some existing and upcoming technologies for converting biomass into electric power or heat. Small-scale 1-30 MWe units are emphasized, but brief reference is made to larger and smaller systems, including those that bum coal-biomass mixtures and gasifiers that feed pilot-fuelled diesel engines. Promising advanced systems, such as a biomass integrated gasifier/gas turbine (BIG/GT) with combined-cycle operation and a biomass gasifier coupled to a fuel cell, giving cycle efficiencies approaching 50% are also described. These advanced gasifiers, typically fluid-bed designs, may be pressurized and can use a wide variety of biomass materials to generate electricity, process steam and chemical products such as methanol. Low-cost, disposable catalysts are becoming available for hot-gas clean-up (enhanced gas composition) for turbine and fuel cell systems. The advantages, limitations and relative costs of various biomass gasifier systems are briefly discussed. The paper identifies the best known biomass power projects and includes some information on proposed and

Early detection of spontaneous combustion of coal in underground coal mines with development of an ethylene enriching system

Energy Technology Data Exchange (ETDEWEB)

Xie, Jun; Xue, Sheng [CSIRO Earth Science and Resource Engineering, Kenmore (Australia); Cheng, Weimin; Wang, Gang [Shandong University of Science and Technology, Qingdao (China)

2011-01-01

Spontaneous combustion of coal (sponcom) is a major hazard in underground coal mining operations. If not detected early and managed properly, it can seriously affect mine safety and productivity. Gaseous products of sponcom, such as carbon monoxide, ethylene and hydrogen, are commonly used in coal mines as indicators to reflect the state of the sponcom. Studies have shown that ethylene starts to occur when sponcom reaches a characteristic temperature. However, due to dilution of ventilation air and detection limits of the instruments used for gas analysis at coal mines, ethylene cannot be detected until the sponcom has developed past its early stage, missing an optimum opportunity for mine operators to control the hazard. To address the issue, an ethylene-enriching system, based on its physical adsorption and desorption properties, has been developed to increase detection sensitivity of the ethylene concentration in mine air by about 10 times. This system has successfully been applied in a number of underground coal mines in China to detect sponcom at its early stage and enable mine operators to take effective control measures. This paper describes the ethylene enriching system and its application. (author)

The economic production of alcohol fuels from coal-derived synthesis gas

Energy Technology Data Exchange (ETDEWEB)

Kugler, E.L.; Dadyburjor, D.B.; Yang, R.Y.K. [West Virginia Univ., Morgantown, WV (United States)] [and others

1995-12-31

The objectives of this project are to discover, (1) study and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas. Specifically, alternative methods of preparing catalysts are to be investigated, and novel catalysts, including sulfur-tolerant ones, are to be pursued. (Task 1); (2) explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. (Task 1); (3) simulate by computer the most energy efficient and economically efficient process for converting coal to energy, with primary focus on converting syngas to fuel alcohols. (Task 2); (4) develop on the bench scale the best holistic combination of chemistry, catalyst, reactor and total process configuration integrated with the overall coal conversion process to achieve economic optimization for the conversion of syngas to liquid products within the framework of achieving the maximum cost effective transformation of coal to energy equivalents. (Tasks 1 and 2); and (5) evaluate the combustion, emission and performance characteristics of fuel alcohols and blends of alcohols with petroleum-based fuels. (Task 2)

Model documentation Coal Market Module of the National Energy Modeling System

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-04-30

This report documents objectives and conceptual and methodological approach used in the development of the National Energy Modeling System (NEMS) Coal Market Module (CMM) used to develop the Annual Energy Outlook 1996 (AEO96). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of CMM`s three submodules: Coal Production Submodule, Coal Export Submodule, and Coal Distribution Submodule.

Clean utilization of coal

International Nuclear Information System (INIS)

Yueruem, Y.

1992-01-01

This volume contains 23 lectures presented at the Advanced Study Institute on 'Chemistry and Chemical Engineering of Catalytic Solid Fuel Conversion for the Production of Clean Synthetic Fuels', which was held at Akcay, Edremit, Turkey, between 21 July and August 3, 1991. Three main subjects: structure and reactivity of coal; cleaning of coal and its products, and factors affecting the environmental balance of energy usage and solutions for the future, were discussed in the Institute and these are presented under six groups in the book: Part 1. Structure and reactivity of coal; Part 2. Factors affecting environmental balance; Part 3. Pre-usage cleaning operations and processes; Part 4. Upgrading of coal liquids and gases; Part 5. Oxygen enriched processes; and Part 6. Probable future solution for energy and pollution problems. Separate abstracts have been prepared for all the lectures

Role of non-ferrous coal minerals and by-product metallic wastes in coal liquefaction. Technical progress report, June 1, 1980-August 31, 1980

Energy Technology Data Exchange (ETDEWEB)

Garg, D; Givens, E N; Schweighardt, F K; Clinton, J H; Tarrer, A R; Guin, J A; Curtis, C W; Huang, W J; Shridharani, K

1980-09-01

Additional data on the pyrite catalysis of liquefaction of Elkhorn number 3 coal are presented. The liquefaction of Elkhorn number 3 coal was significantly catalyzed by the presence of pyrite. Coal conversion, oil yield and preasphaltene conversion all increased when pyrite was added. An increase in hydrocarbon gas make accompanied by a higher hydrogen consumption were also observed. The higher activity in the presence of pyrite could be utilized by running the liquefaction step at milder conditions which would mean a lower gas make. Although we had heard reports that sulfur elimination from the SRC was improved by use of pyrite, our data showed only very small changes. Nitrogen removal from the solvent, however, was definitely observed. At 850/sup 0/F nitrogen in the oil product went from 1.61 to 1.12 on adding pyrite. This increased nitrogen removal was also seen in the added ammonia yields. Kentucky number 9 coal also responded very well to the presence of pyrite. Conversions and oil yields increased while the hydrocarbon yields decreased at both temperatures that were tested, i.e., 825 and 850/sup 0/F. Hydrogen consumptions also increased. In the screening program the results from testing a number of materials are reported. None of the zeolites gave any significant improvement over coal itself. The iron, molybdenum, nickel, and cobalt rich materials had significant activity, all 85 to 90% conversion with high oil yields.Among materials specifically reported this period the clays failed to show any significant catalytic effect.

Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification

Energy Technology Data Exchange (ETDEWEB)

None

1982-01-01

This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

Solids throttling valves for coal conversion and utilization development. Final report

Energy Technology Data Exchange (ETDEWEB)

Sine, G.C.

1980-11-01

A complete test system to test, evaluate, and develop control valves for slurry letdown service in coal liquefaction plants is needed. The site identified for the test system was the SRC II Pilot Plant located at Ft. Lewis, Washington. The US Department of Energy, Morgantown Energy Technology Center, requested a test system design that would enable testing of various configuration letdown valves that would be compatible with the existing facility and have minimum impact on Pilot Plant operations. Drawings and specifications for such a test system were prepared, coordinated with Ft. Lewis personnel, revised to reflect Ft. Lewis operating personnel comments, and approved for use by the Morgantown Energy Technology Center. These drawings and specifications will enable the test system to be built, installed, and integrated with the existing facility by a general contractor.

Proceedings of the international symposium on coal - science, technology, industry, business, environment

Energy Technology Data Exchange (ETDEWEB)

Narasimhan, K.S.; Sen, S. [eds.

1996-12-31

Papers were presented which covered the areas of coal science, advanced coal preparation, coal utilization, coal chemicals and the environment. These included carbon aromaticity, mineral studies, utilization of low rank coals, bioconversion of methane, swelling of coals, photocatalytic activity, flotation and effects of oxidation, microbial desulfurization, deashing, briquetting, commercial scale conversion of coal to fuels and chemicals, role of coal in iron and steel making, coal-water mixtures, dyes and chemical products, nitrogen oxides emissions and pollution control. 45 papers have been abstracted separately for the IEA Coal Research CD-ROM.

The coal industry and its greenhouse challenge

International Nuclear Information System (INIS)

Armstrong, A.

1998-01-01

The Australian coal industry is actively involved in greenhouse gas emission management and abatement issues. An Australian Coal Association (ACA) position paper on greenhouse in November 1989, recommended a number of strategies to minimise the greenhouse effect, including the enhancement of energy utilisation efficiency, improved energy conversion efficiency at coal-fired power stations, expanded use of solar heating, and improved recycling. All of the strategies have been implemented to various degrees. The management and abatement of greenhouse gas emissions within the coal industry has been approached from an individual operational level, and a 'higher' industry level

Synergetic and inhibition effects in carbon dioxide gasification of blends of coals and biomass fuels of Indian origin.

Science.gov (United States)

Satyam Naidu, V; Aghalayam, P; Jayanti, S

2016-06-01

The present study investigates the enhancement of CO2 gasification reactivity of coals due to the presence of catalytic elements in biomass such as K2O, CaO, Na2O and MgO. Co-gasification of three Indian coal chars with two biomass chars has been studied using isothermal thermogravimetric analysis (TGA) in CO2 environment at 900, 1000 and 1100°C. The conversion profiles have been used to establish synergetic or inhibitory effect on coal char reactivity by the presence of catalytic elements in biomass char by comparing the 90% conversion time with and without biomass. It is concluded that both biomasses exhibit synergistic behavior when blended with the three coals with casuarina being more synergetic than empty fruit bunch. Some inhibitory effect has been noted for the high ash coal at the highest temperature with higher 90% conversion time for the blend over pure coal, presumably due to diffusional control of the conversion rate. Copyright © 2016 Elsevier Ltd. All rights reserved.

Mineral conversion and microstructure change in the melting process of Shenmu coal ash

Energy Technology Data Exchange (ETDEWEB)

Yang Jianguo; Deng Furong; Zhao Hong; Cen Kefa [Zhejiang University, Hangzhou (China). State Key Laboratory of Clean Energy Utilization

2007-05-15

China has rich reserves of Shenmu coal, which has the typical characteristic of low-melting-point ash. If used in the pulverized-coal boiler of a power plant, Shenmu coal would cause serious slagging. In order to solve the slagging problem of Shenmu coal, the melting mechanism of Shenmu coal ash was studied. One of the Shenmu coals - Wenjialiang coal - was selected for the study. Using thermogravimetry-differential scanning colorimetry (TG-DSC) methods, the change of the coal ash's physicochemistry with temperature was studied. The typical temperature points in the melting process were obtained. Ash samples of the different temperature points were prepared in a high-temperature furnace with parameters similar to those used in the TG-DSC test, and were then cooled quickly in water. Later, the ash samples were analyzed using X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDX) methods in detail. Wenjialiang coal ash started to melt at 980{sup o}C. The ash was found to melt to a great extent at 1200{sup o}C and formed a multiform microstructure. At 1260{sup o}C, it was found to melt into a dense body with many pores, and formed a piece of vitreous body at 1340{sup o}C. Anorthite and gehlenite are the intermediate products that exist between 980 and 1340{sup o}C. They may be the main cause of the ash having low melting points, so that they could convert into a eutectic at low temperatures.

Conversion to use of digital chest images for surveillance of coal workers' pneumoconiosis (black lung).

Science.gov (United States)

Levine, Betty A; Ingeholm, Mary Lou; Prior, Fred; Mun, Seong K; Freedman, Matthew; Weissman, David; Attfield, Michael; Wolfe, Anita; Petsonk, Edward

2009-01-01

To protect the health of active U.S. underground coal miners, the National Institute for Occupational Safety and Health (NIOSH) has a mandate to carry out surveillance for coal workers' pneumoconiosis, commonly known as Black Lung (PHS 2001). This is accomplished by reviewing chest x-ray films obtained from miners at approximately 5-year intervals in approved x-ray acquisition facilities around the country. Currently, digital chest images are not accepted. Because most chest x-rays are now obtained in digital format, NIOSH is redesigning the surveillance program to accept and manage digital x-rays. This paper highlights the functional and security requirements for a digital image management system for a surveillance program. It also identifies the operational differences between a digital imaging surveillance network and a clinical Picture Archiving Communication Systems (PACS) or teleradiology system.

Coal-nuclear energy system. Method of study. Examples of results

International Nuclear Information System (INIS)

Deneuve, F.; Le Penhuizic, B.

1981-01-01

Given the outlook for hydrocarbon depletion, three primary energy sources could enable supplies to be diversified, i.e. nuclear energy, coal and solar energy. These primary energy sources can rarely be used directly and must be converted into energy carriers such as electricity, hydrogen, substitute natural gas, liquid hydrocarbons derived from coal, etc. The nature of future gas carriers and their position in the national energy balance must be examined. Within the framework of an overall energy pattern. Many of the potential conversion processes are often interrelated through their production and consumption. Likewise, seasonal variations in consumption make it necessary to design production plants for peak demand or to create large-scale storage facilities. An initial model taking these interactions into consideration has been worked out to represent the variety of solutions possible. This model can be used to evaluate the technical paths to be followed within the framework of different assumptions concerning the future [fr

FY 1994 report on the Coal Liquefaction Committee; 1994 nendo sekitan ekika iinkai hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-03-01

The paper reported the FY 1994 activities of the Coal Liquefaction Committee. The Coal Liquefaction Committee in this fiscal year was held on November 29, 1994 (1st) and March 22, 1995 (2nd), and report was made on the bituminous coal liquefaction study and state of the R and D of liquefaction base technology. Report was also made on the state of construction of bituminous coal liquefaction PP, outline of the results of the PSU operation, outline of the 11th Japan-U.S. JTM, etc. In the liquefaction base study, report/discussion were made about the improvement/rationalization of liquefaction process, study of innovative technology of coal liquefaction, study of coal liquefaction conditions, study for higher liquefaction element technology, project on the internationalization of coal liquefaction technology, etc. As to the relation of the entrained bed coal gasification power plant, report/discussion were made about survey/study on the processing of coal for coal gasification use (survey of coal kind selection, development of information processing system for coal conversion technology). Besides, as a topic, report was made on the economical evaluation/calculation of a commercial plant for brown coal liquefaction. (NEDO)

Economic analysis of coal-based polygeneration system for methanol and power production

International Nuclear Information System (INIS)

Lin, Hu; Jin, Hongguang; Gao, Lin; Han, Wei

Polygeneration system for chemical and power co-production has been regarded as one of promising technologies to use fossil fuel more efficiently and cleanly. In this paper the thermodynamic and economic performances of three types of coal-based polygeneration system were investigated and the influence of energy saving of oxygenation systems on system economic performance was revealed. The primary cost saving ratio (PCS) is presented as a criterion, which represents the cost saving of polygeneration system compared with the single-product systems with the same products outputs, to evaluate economic advantages of polygeneration system. As a result, the system, adopting un-reacted syngas partly recycled to the methanol synthesis reactor and without the shift process, can get the optimal PCS of 11.8%, which results from the trade-off between the installed capital cost saving and the energy saving effects on the cost saving, and represents the optimal coupling relationship among chemical conversion, energy utilization and economic performance. And both of fuel price and the level of equipment capital cost affect on PCS faintly. This paper provides an evaluation method for polygeneration systems based on both technical and economic viewpoints. (author)

Groundwater and underground coal gasification in Alberta

International Nuclear Information System (INIS)

Haluszka, A.; MacMillan, G.; Maev, S.

2010-01-01

Underground coal gasification has potential in Alberta. This presentation provided background information on underground coal gasification and discussed groundwater and the Laurus Energy demonstration project. A multi-disciplined approach to project assessment was described with particular reference to geologic and hydrogeologic setting; geologic mapping; and a hydrogeologic numerical model. Underground coal gasification involves the conversion of coal into synthesis gas or syngas. It can be applied to mined coal at the surface or applied to non-mined coal seams using injection and production wells. Underground coal gasification can effect groundwater as the rate of water influx into the coal seams influences the quality and composition of the syngas. Byproducts created include heat as well as water with dissolved concentrations of ammonia, phenols, salts, polyaromatic hydrocarbons, and liquid organic products from the pyrolysis of coal. A process overview of underground coal gasification was also illustrated. It was concluded that underground coal gasification has the potential in Alberta and risks to groundwater could be minimized by a properly designed project. refs., figs.

Coal Integrated Gasification Fuel Cell System Study

Energy Technology Data Exchange (ETDEWEB)

Chellappa Balan; Debashis Dey; Sukru-Alper Eker; Max Peter; Pavel Sokolov; Greg Wotzak

2004-01-31

This study analyzes the performance and economics of power generation systems based on Solid Oxide Fuel Cell (SOFC) technology and fueled by gasified coal. System concepts that integrate a coal gasifier with a SOFC, a gas turbine, and a steam turbine were developed and analyzed for plant sizes in excess of 200 MW. Two alternative integration configurations were selected with projected system efficiency of over 53% on a HHV basis, or about 10 percentage points higher than that of the state-of-the-art Integrated Gasification Combined Cycle (IGCC) systems. The initial cost of both selected configurations was found to be comparable with the IGCC system costs at approximately $1700/kW. An absorption-based CO2 isolation scheme was developed, and its penalty on the system performance and cost was estimated to be less approximately 2.7% and $370/kW. Technology gaps and required engineering development efforts were identified and evaluated.

A novel concept for high conversion of coal to liquids. Final report, 1 September 1988--31 August 1992

Energy Technology Data Exchange (ETDEWEB)

Wiser, W.H.; Shabtai, J.

1994-04-01

A batch microreactor was designed and fabricated as a means of investigating maximum yields of liquids obtainable in very short reaction times of the order of a few seconds, and the maximum ratios of liquids/hydrocarbon (HC) gases obtainable under those conditions. A Wyodak sub-bituminous coal, crushed and sieved to {minus}200 mesh particle size, was used in the experiments, with a temperature of 500{degrees}C and a pressure of 1500 psi. The fine coal particles were fed dry to the reactor and heated to reaction temperature in times of one to two seconds. At a time of 3 seconds at reaction temperature, in a single pass a liquid yield of 60% by weight of the coal was obtained, accompanied by a ratio of liquids/(HC) gases of 30/1. When the unreacted solids were recycled to the reactor, and the results combined with those of the first pass, a liquid yield of 82% by weight of the coal was achieved, accompanied by a ratio of liquids/HC gases of 30/1. This ratio represents only about 3 wt percent HC gases, much lower that is produced in current advanced technologies, and represents a large saving in hydrogen consumption. A simulated distillation technique was applied to the liquids. The liquid product contained 86% by weight (of the liquids) total distillables (boiling point below 538{degrees}C), including 70% by weight of low-boiling fractions in the gasoline, kerosene and gas oil range (boiling point up to 325{degrees}C). The liquid product exhibited a H/C ratio of 1.5, which is considerably higher than observed in current advanced technologies for the primary liquids. Several catalysts were investigated. Iron catalysts, specifically ferric chloride hexahydrate and ferric sulfate pentahydrate, each produced these high conversions and high ratios of liquids/HC gases.

Dissolution of subbituminous coal in tetrahydroquinoline

Energy Technology Data Exchange (ETDEWEB)

Silver, H F; Frazee, W S; Broderick, T E; Hurtubise, R J

1986-05-01

Two different samples of Wyodak subbituminous coal from the Powder River Basin in Wyoming were liquefied in a two dm/sup 3/ batch reactor using 1,2,3,4 tetrahydroquinoline, THQ, as a solvent. Sufficient sample was produced to determine product boiling ranges by distillation and to measure THQ distribution in the product. Product distillation showed that even at cyclohexane conversions greater than 50%, net distillate yields produced using THQ as a solvent were negative. In some cases, high boiling, coal-derived residue yields were greater than the dry coal charged to the reactor. These observations have been attributed to THQ losses resulting from dimerization of the THQ and reactions between THQ and coal derived components. 5 references.

76 FR 70075 - Proximity Detection Systems for Continuous Mining Machines in Underground Coal Mines

Science.gov (United States)

2011-11-10

... Detection Systems for Continuous Mining Machines in Underground Coal Mines AGENCY: Mine Safety and Health... proposed rule addressing Proximity Detection Systems for Continuous Mining Machines in Underground Coal... Detection Systems for Continuous Mining Machines in Underground Coal Mines. MSHA conducted hearings on...

Study on structuring the supervision system of coal mine associated with radionuclides in Xinjiang

International Nuclear Information System (INIS)

Feng Guangwen; Jia Xiahui

2012-01-01

Xinjiang is one of China's rich coal provinces (areas) and it accounts for about 40% national coal reserves. In the long-term radioactive scientific research, monitoring and environmental impact assessment works, we found parts of Yili and Hetian's coal was associated with higher radionuclide, and parts of coal seam even reached nuclear mining level. However the laws and regulations about associated radioactive coal mine supervision were not perfect, and the supervision system is still in the exploration. This article mainly started with the coal mine enterprises' geological prospecting reports, radiation environmental impact assessment and monitoring report preparation for environment acceptance checking and supervisory monitoring, controlled the coal radioactive pollution from the sources, and carried out the research of building Xinjiang associated radioactive coal mine supervision system. The establishment of supervision system will provide technical guidance for the enterprises' coal exploitation and cinders using on the one hand, and on the other hand will provide decision-making basis for strengthening the associated radioactive coal mine supervision for Xinjiang environmental regulators. (authors)

Measurement and modeling of advanced coal conversion processes, Volume III

Energy Technology Data Exchange (ETDEWEB)

Ghani, M.U.; Hobbs, M.L.; Hamblen, D.G. [and others

1993-08-01

A generalized one-dimensional, heterogeneous, steady-state, fixed-bed model for coal gasification and combustion is presented. The model, FBED-1, is a design and analysis tool that can be used to simulate a variety of gasification, devolatilization, and combustion processes. The model considers separate gas and solid temperatures, axially variable solid and gas flow rates, variable bed void fraction, coal drying, devolatilization based on chemical functional group composition, depolymerization, vaporization and crosslinking, oxidation, and gasification of char, and partial equilibrium in the gas phase.

Technical analysis of advanced wastewater-treatment systems for coal-gasification plants

Energy Technology Data Exchange (ETDEWEB)

1981-03-31

This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

Feasibility study of environmentally friendly type coal utilization systems. Feasibility study of environmentally friendly type coal utilization systems in sectors except the coal industry in China; Kankyo chowagata sekitan riyo system kanosei chosa. Chugoku no sekitan kogyo igai no bumon ni okeru kankyo chowagata sekitan riyo system kanosei chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-03-01

For the purpose of working out a comprehensive master plan for application of the coal utilization system, the paper surveyed and studied the coal utilization system in terms of environmental measures and efficiency improvement in the utilization of coal. As a result of the discussion with NEDO and the National Planning Committee of China, Liaoning Province (the whole China) and Shenyang City were selected as a model area and a model city for the survey and study. As energy conservation measures taken in the former, desirable are intensifying/capacity-increase of boilers, kilns, etc. and adoption of new-type/high-efficient equipment. Also expected are reinforcement of combustion control and improvement of efficiency by using coal preparation, industrial use coal briquette, etc. Measures taken in the latter are the same as those taken in the whole China. As SOx reduction measures for Liaoning Province, desirable is installation of dry-type desulfurization equipment and simple desulfurization equipment. As dust prevention measures for it, desirable is installation of electrostatic precipitators or high-functional bag filters. SOx reduction measures for Shenyang City are the same as those taken in the whole China. SOx can be reduced by using coal-prepared low-sulfur coal and industrial use coal briquette added with desulfurizing agent. 88 figs., 163 tabs.

Effect of pre-swelling of coal on its solvent extraction and liquefaction properties

Energy Technology Data Exchange (ETDEWEB)

Hengfu Shui; Zhicai Wang; Meixia Cao [Anhui University of Technology, Ma' anshan (China). School of Chemistry and Chemical Engineering

2008-10-15

Effects of pre-swelling of coal on solvent extraction and liquefaction properties were studied with Shenhua coal. It was found that pre-swelling treatments of the coal in three solvents, i.e., toluene (TOL), N-methyl-2-pyrrolidinone (NMP) and tetralin (THN) increased its extraction yield and liquefaction conversion, and differed the liquefied product distributions. The pre-swollen coals after removing the swelling solvents showed increased conversion in liquefaction compared with that of the swollen coals in the presence of swelling solvents. It was also found that the yields of (oil + gas) in liquefaction of the pre-swollen coals with NMP and TOL dramatically decreased in the presence of swelling solvent. TG and FTIR analyses of the raw coal, the swollen coals and the liquefied products were carried out in order to investigate the mechanism governing the effects of pre-swelling treatment on coal extraction and liquefaction. The results showed that the swelling pre-treatment could disrupt some non-covalent interactions of the coal molecules, relax its network structure and loosened the coal structure. It would thus benefit diffusion of a hydrogen donor solvent into the coal structure during liquefaction, and also enhance the hydrogen donating ability of the hydrogen-rich species derived from the coal. 21 refs., 4 figs., 3 tabs.

Study of mobilization and speciation of trace elements in coal pyrolysis

International Nuclear Information System (INIS)

Ting, B.T.G.

1979-01-01

Various types of coal contain high levels of a number of trace elements. Little is known of the fates of these trace elements during the conversion of coal to liquid and gaseous products. Studies were undertaken of mobilization and speciation of trace elements in coal pyrolysis, one of the major coal conversion processes. The bituminous coal was pyrolyzed to produce liquid and gaseous products. The pyrolysis products were collected in traps in an inert gas stream. In addition mildly hydrogenated coal was prepared by mixing with tetralin, a hydrogen donor solvent, at boiling temperature. In order to characterize each element specifically during pyrolysis, base samples of coal and mildly hydrogenated coal (H-coal) were spiked with heavy metal sulfides, trace metals bound to partially oxidized coal (coal humates), and halide salts prior to carrying out pyrolysis. Eight elements were investigated in this research. They are As, Br, Cl, Co, Cr, Mn, Se, and V. Pre-spiked hydrogenated coal, i.e., pulverized coal spiked with halide salts and heavy metal sulfides then hydrogenated with tetralin, was prepared and studied for the fates of these elements during pyrolysis. Chlorinated and brominated coals were also prepared to compare the volatility differences between organically and inorganically bound halogens during the pyrolysis reaction. These products and the coal char residues were analyzed for the spiked elements mainly by neutron activation analysis for the spiked elements to determine their degree of volatility. Volatility and recovery (mass balance) will be discussed for those elements that appeared highly volatile during pyrolysis. In order to understand the halogenated compounds in the pyrolysis products, gas chromatograms were taken to the collected pyrolysis products of coal, hydrogenated coal, NaCl spiked coal, NaBr spiked coal, chlorinated coal, and brominated coal

Unexpectedly high uptake of palladium by bituminous coals

Energy Technology Data Exchange (ETDEWEB)

Lakatos, J. [Research Lab. for Mining Chemistry, Hungarian Academy of Sciences, Miskolc-Egyetemvaros (Hungary); Brown, S.D.; Snape, C.E. [Univ. of Strathclyde, Dept. of Pure and Applied Chemistry, Glasgow (United Kingdom)

1997-12-31

The uptake of palladium as a conversion catalyst onto coals of different rank was investigated. Palladium fixation occurs by a different mode to that for alkaline earth and first row transition metals. Therefore, the dispersion of relatively high concentration of palladium by an ion sorption process is even possible for bituminous coals. (orig.)

Creating a Chinese-style coal-industry economic system

Energy Technology Data Exchange (ETDEWEB)

Gao, Y

1985-04-25

Efforts to keep China's coal industry financially healthy and to continue increasing production also created problems in terms of output, transport, environmental damage, accidents, and labor pressures. In addition to the historical and economic reasons for these pressures, inadequate leadership and policy errors made things worse. An analysis suggests three problems: (1) an inequitable division of duties between government and business, (2) a neglected marketplace, and (3) the dominance of egalitarianism. The report relates these problems to the production of coal and a package of reforms which restructured the economic system of the industry to give it more autonomy and economic responsibility. The reforms emphasize rational pricing and use of coal as well as management of the industry.

NOVEL SLURRY PHASE DIESEL CATALYSTS FOR COAL-DERIVED SYNGAS

Energy Technology Data Exchange (ETDEWEB)

Dr. Dragomir B. Bukur; Dr. Ketil Hanssen; Alec Klinghoffer; Dr. Lech Nowicki; Patricia O' Dowd; Dr. Hien Pham; Jian Xu

2001-01-07

This report describes research conducted to support the DOE program in novel slurry phase catalysts for converting coal-derived synthesis gas to diesel fuels. The primary objective of this research program is to develop attrition resistant catalysts that exhibit high activities for conversion of coal-derived syngas.

Oxy-Fuel Combustion of Coal

DEFF Research Database (Denmark)

Brix, Jacob

This Ph.D. thesis describes an experimental and modeling investigation of the thermal conversion of coal and an experimental investigation of the emission of NO from char combustion in O2/N2 and O2/CO2 atmospheres. The motivation for the work has been the prospective use of the technology “Oxy......-Fuel Combustion” as a mean of CO2 abatement in large scale energy conversion. Entrained Flow Reactor (EFR) experiments have been conducted in O2/N2 and O2/CO2 mixtures in the temperature interval 1173 K – 1673 K using inlet O2 concentrations between 5 – 28 vol. %. Bituminous coal has been used as fuel in all....... % it was found that char conversion rate was lowered in O2/CO2 compared to O2/N2. This is caused by the lower diffusion coefficient of O2 in CO2 (~ 22 %) that limits the reaction rate in zone III compared to combustion in O2/N2. Using char sampled in the EFR experiments ThermoGravimetric Analyzer (TGA...

The coal cleat system: A new approach to its study

Directory of Open Access Journals (Sweden)

C.F. Rodrigues

2014-06-01

Full Text Available After a general analysis regarding the concept of coal “cleat system”, its genetic origin and practical applications to coalbed methane (CBM commercial production and to CO2 geological sequestration projects, the authors have developed a method to answer, quickly and accurately in accordance with the industrial practice and needs, the following yet unanswered questions: (1 how to define the spatial orientation of the different classes of cleats presented in a coal seam and (2 how to determine the frequency of their connectivites. The new available and presented techniques to answer these questions have a strong computer based tool (geographic information system, GIS, able to build a complete georeferentiated database, which will allow to three-dimensionally locate the laboratory samples in the coalfield. It will also allow to better understand the coal cleat system and consequently to recognize the best pathways to gas flow through the coal seam. Such knowledge is considered crucial for understanding what is likely to be the most efficient opening of cleat network, then allowing the injection with the right spatial orientation, of pressurized fluids in order to directly drain the maximum amount of gas flow to a CBM exploitation well. The method is also applicable to the CO2 geological sequestration technologies and operations corresponding to the injection of CO2 sequestered from industrial plants in coal seams of abandoned coal mines or deep coal seams.

The Rheology of a Three Component System: COAL/WATER/#4 Oil Emulsions.

Science.gov (United States)

Gilmartin, Barbara Jean

The purpose of this investigation was to study the rheology of a three component system, coal/water/#4 oil emulsions (COW), in which the third component, water, was present in a significant concentration, and to determine the applicability of existing theories from suspension rheology to the three component system studied. In a coal/water/oil emulsion, free coal particles adhere to the surface of the water droplets, preventing their coagulation, while the larger coal particles reside in the matrix of stabilized water droplets. The use of liquid fuels containing coal is a means of utilizing our nation's coal reserves while conserving oil. These fuels can be burned in conventional oil-fired furnaces. In this investigation, a high sulfur, high ash, bituminous coal was used, along with a heavy #4 oil to prepare the emulsions. The coal was ground to a log-normal distribution with an average particle size of 62 microns. A Haake RV3 concentric cylinder viscometer, with a ribbed measuring system, was used to determine the viscosity of the emulsions. A physical pendulum settling device measured the shift in center of mass of the COW as a function of time. The flow behavior of the fuel in pipes was also tested. In interpreting the data from the viscometer and the pipe flow experiments, a power law analysis was used in the region from 30 s('-1) to 200 s('-1). Extrapolation methods were used to obtain the low and high shear behavior of the emulsions. In the shear rate region found in boiler feed systems, COW are shear thinning with a flow behavior index of 0.7. The temperature dependent characteristic of the emulsions studied were similar and followed an Arrhenius type relationship. The viscosity of the COW decreases with increasing coal average particle size and is also a function of the width of the size distribution used. The type of coal used strongly influences the rheology of the fuel. The volatile content and the atomic oxygen to nitrogen ratio of the coal are the most

The effect of catalysts blending on coal pyrolysis

Energy Technology Data Exchange (ETDEWEB)

Pinto, F.; Gulyurtlu, I.; Lobo, L.S.; Cabrita, I. [INETI, Lisbon (Portugal)

1999-05-01

The effect of several catalysts on coal hydropyrolysis efficiency was studied, having selected catalysts with different characteristics and behaviours. For the experimental conditions used Fe{sub 2}O{sub 3} and ICI 41-6 showed selectivity towards lighter fractions, whilst ZnCl{sub 2} led to the highest coal conversion and to the greatest preasphaltenes yields. These results suggested the use of mixtures of catalysts. The heavier molecules of asphaltenes produced as a result of ZnCl{sub 2} action, could then be converted into lighter fractions by the action of a selective catalyst. Coal hydropyrolysis tests were undertaken using ZnCl{sub 2} mixed with Fe{sub 2}O{sub 3} or ICI 41-6. These mixtures of catalysts led to increased conversions and higher product yields. The best results were obtained in the presence of ZnCl{sub 2} mixed with Fe{sub 2}O{sub 3}. In an attempt to interpret these results, coal structure before and after swelling pre-treatment was also studied using SEM. 17 refs., 11 figs., 1 tab.

Organic coal reserves in field and forest systems vs. Avifauna biodiversity

Directory of Open Access Journals (Sweden)

Szyszko-Podgórska Katarzyna

2017-12-01

Full Text Available The objective of this work was to determine the occurrence of birds depending on the use of the area and the content of organic coal in field-and-forest systems. The research demonstrated a great diversity of bird species and great differences in the content of organic coal in individual areas. According to the conducted analyses, human economic activity can influence the content of organic coal and, therefore, it also influences the occurrence of specific bird species. In connection with the fact that the entire area covered with the research has been modelled by humans, the content of organic coal, the composition of bird species and their functioning in spatial systems are derivatives of such an activity.

Gondwana basins and their coal resources in Bangladesh

International Nuclear Information System (INIS)

Nehaluddin, M.; Sultan-ul-Islam, M.

1994-01-01

Fault bounded five Gondwana basins have been discovered in the north western Bangladesh. Among these basins show considerable amount of coal deposits. The Gondwana rocks are highly formed during the Permo-carboniferous diastrophism and later on acquired dynamic characters. In almost all basins, the Permian rocks overlie the Precambrian basement and underlie either the Tertiary or the Cretaceous sediments, structural, stratigraphic, and depositional history of these basins is more or less similar. The sedimentary sequences are composed of light to dark gray, fine to very coarse grained, sub angular to sub rounded felspathic sandstone, dark grey carbonaceous shale and sandstone, variegated conglomerate and thick coal seams (single seam max. 42.38m). The rocks are often alternated and bear the characteristics of cyclic sedimentation. The depositional environments varied from restricted drainage to open fluvial dominated low to moderate sinuous drainage system. The coal bearing basins were flanked by vegetated and swampy over bank. Age of these coals is suggested to be the late permian. Proved and probable reserves of coal in Jamalganj-Paharpur basin are 670 and 1,460 million metric tons, in Barapukuria basin 303 and 3899 million metric tons; in Barapukuria basin 303 and 389 million metric tons; and in Khalaspir basin 143 and 685 million metric tons respectively. The coal is high volatile, low sulphur, bituminous type. It can be used for different forms of thermal conversion. (author)

Processing needs and methodology for wastewaters from the conversion of coal, oil shale, and biomass to synfuels

Energy Technology Data Exchange (ETDEWEB)

1980-05-01

The workshop identifies needs to be met by processing technology for wastewaters, and evaluates the suitability, approximate costs, and problems associated with current technology. Participation was confined to DOE Environmental Control Technology contractors to pull together and integrate past wastewater-related activities, to assess the status of synfuel wastewater treatability and process options, and to abet technology transfer. Particular attention was paid to probable or possible environmental restrictions which cannot be economically met by present technology. Primary emphasis was focussed upon process-condensate waters from coal-conversion and shale-retorting processes. Due to limited data base and time, the workshop did not deal with transients, upsets, trade-offs and system optimization, or with solids disposal. The report is divided into sections that, respectively, survey the water usage and effluent situation (II); identify the probable and possible water-treatment goals anticipated at the time when large-scale plants will be constructed (III); assess the capabilities, costs and shortcomings of present technology (IV); explore particularly severe environmental-control problems (V); give overall conclusions from the Workshop and recommendations for future research and study (VI); and, finally, present Status Reports of current work from participants in the Workshop (VII).

Firing a sub-bituminous coal in pulverized coal boilers configured for bituminous coals

Energy Technology Data Exchange (ETDEWEB)

N. Spitz; R. Saveliev; M. Perelman; E. Korytni; B. Chudnovsky; A. Talanker; E. Bar-Ziv [Ben-Gurion University of the Negev, Beer-Sheva (Israel)

2008-07-15

It is important to adapt utility boilers to sub-bituminous coals to take advantage of their environmental benefits while limiting operation risks. We discuss the performance impact that Adaro, an Indonesian sub-bituminous coal with high moisture content, has on opposite-wall and tangentially-fired utility boilers which were designed for bituminous coals. Numerical simulations were made with GLACIER, a computational-fluid-dynamic code, to depict combustion behavior. The predictions were verified with full-scale test results. For analysis of the operational parameters for firing Adaro coal in both boilers, we used EXPERT system, an on-line supervision system developed by Israel Electric Corporation. It was concluded that firing Adaro coal, compared to a typical bituminous coal, lowers NOx and SO{sub 2} emissions, lowers LOI content and improves fouling behavior but can cause load limitation which impacts flexible operation. 21 refs., 7 figs., 3 tabs.

ULTRA LOW NOx INTEGRATED SYSTEM FOR NOx EMISSION CONTROL FROM COAL-FIRED BOILERS

Energy Technology Data Exchange (ETDEWEB)

Galen H. Richards; Charles Q. Maney; Richard W. Borio; Robert D. Lewis

2002-12-30

ALSTOM Power Inc.'s Power Plant Laboratories, working in concert with ALSTOM Power's Performance Projects Group, has teamed with the U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient NOx control technologies for retrofit to pulverized coal fired utility boilers. The objective of this project was to develop retrofit NOx control technology to achieve less than 0.15 lb/MMBtu NOx (for bituminous coals) and 0.10 lb/MMBtu NOx (for subbituminous coals) from existing pulverized coal fired utility boilers at a cost which is at least 25% less than SCR technology. Efficient control of NOx is seen as an important, enabling step in keeping coal as a viable part of the national energy mix in this century, and beyond. Presently 57% of U.S. electrical generation is coal based, and the Energy Information Agency projects that coal will maintain a lead in U.S. power generation over all other fuel sources for decades (EIA 1998 Energy Forecast). Yet, coal-based power is being strongly challenged by society's ever-increasing desire for an improved environment and the resultant improvement in health and safety. The needs of the electric-utility industry are to improve environmental performance, while simultaneously improving overall plant economics. This means that emissions control technology is needed with very low capital and operating costs. This project has responded to the industry's need for low NOx emissions by evaluating ideas that can be adapted to present pulverized coal fired systems, be they conventional or low NOx firing systems. The TFS 2000{trademark} firing system has been the ALSTOM Power Inc. commercial offering producing the lowest NOx emission levels. In this project, the TFS 2000{trademark} firing system served as a basis for comparison to other low NOx systems evaluated and was the foundation upon which refinements were made to further

Life-Cycle Analysis of Greenhouse Gas Emissions and Water Consumption – Effects of Coal and Biomass Conversion to Liquid Fuels as Analyzed with the GREET Model

Energy Technology Data Exchange (ETDEWEB)

Li, Qianfeng [Argonne National Lab. (ANL), Argonne, IL (United States); Cai, Hao [Argonne National Lab. (ANL), Argonne, IL (United States); Han, Jeongwoo [Argonne National Lab. (ANL), Argonne, IL (United States)

2017-06-01

The vast reserves of coal in the U.S. provide a significant incentive for the development of processes for coal conversion to liquid fuels (CTL). Also, CTL using domestic coal can help move the U.S. toward greater energy independence and security. However, current conversion technologies are less economically competitive and generate greater greenhouse gas (GHG) emissions than production of petroleum fuels. Altex Technologies Corporation (Altex, hereinafter) and Pennsylvania State University have developed a hybrid technology to produce jet fuel from a feedstock blend of coal and biomass. Collaborating with Altex, Argonne National Laboratory has expanded and used the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model to assess the life-cycle GHG emissions and water consumption of this hybrid technology. Biomass feedstocks include corn stover, switchgrass, and wheat straw. The option of biomass densification (bales to pellets) is also evaluated in this study. The results show that the densification process generates additional GHG emissions as a result of additional biomass process energy demand. This process coproduces a large amount of char, and this study investigates two scenarios to treat char: landfill disposal (Char-LF) and combustion for combined heat and power (CHP). Since the CHP scenarios export excess heat and electricity as coproducts, two coproduct handling methods are used for well-to-wake (WTWa) analysis: displacement (Char-CHP-Disp) and energy allocation (Char-CHP-EnAllo). When the feedstock contains 15 wt% densified wheat straw and 85 wt% lignite coal, WTWa GHG emissions of the coal-and-biomass-to-liquid pathways are 116, 97, and 137 gCO2e per megajoule (MJ) under the Char-LF, Char-CHP-Disp, and Char-CHP-EnAllo scenarios, respectively, as compared to conventional jet fuel production at 84 gCO2e/MJ. WTWa water consumption values are 0.072, -0.046, and 0.044 gal/MJ for Char-LF, Char-CHP-Disp, and Char

Assessment of industrial energy options based on coal and nuclear systems

International Nuclear Information System (INIS)

Anderson, T.D.; Bowers, H.I.; Bryan, R.H.; Delene, J.G.; Hise, E.C.; Jones, J.E. Jr.; Klepper, O.H.; Reed, S.A.; Spiewak, I.

1975-07-01

Industry consumes about 40 percent of the total primary energy used in the United States. Natural gas and oil, the major industrial fuels, are becoming scarce and expensive; therefore, there is a critical national need to develop alternative sources of industrial energy based on the more plentiful domestic fuels--coal and nuclear. This report gives the results of a comparative assessment of nuclear- and coal-based industrial energy systems which includes technical, environmental, economic, and resource aspects of industrial energy supply. The nuclear options examined were large commercial nuclear power plants (light-water reactors or high-temperature gas-cooled reactors) and a small [approximately 300-MW(t)] special-purpose pressurized-water reactor for industrial applications. Coal-based systems selected for study were those that appear capable of meeting environmental standards, especially with respect to sulfur dioxide; these are (1) conventional firing using either low- or high-sulfur coal with stack-gas scrubbing equipment, (2) fluidized-bed combustion using high-sulfur coal, (3) low- and intermediate-Btu gas, (4) high-Btu pipeline-quality gas, (5) solvent-refined coal, (6) liquid boiler fuels, and (7) methanol from coal. Results of the study indicated that both nuclear and coal fuel can alleviate the industrial energy deficit resulting from the decline in availability of natural gas and oil. However, because of its broader range of application and relative ease of implementation, coal is expected to be the more important substitute industrial fuel over the next 15 years. In the longer term, nuclear fuels could assume a major role for supplying industrial steam. (U.S.)

Coal conversion processes and analysis methodologies for synthetic fuels production. [technology assessment and economic analysis of reactor design for coal gasification

Science.gov (United States)

1979-01-01

Information to identify viable coal gasification and utilization technologies is presented. Analysis capabilities required to support design and implementation of coal based synthetic fuels complexes are identified. The potential market in the Southeast United States for coal based synthetic fuels is investigated. A requirements analysis to identify the types of modeling and analysis capabilities required to conduct and monitor coal gasification project designs is discussed. Models and methodologies to satisfy these requirements are identified and evaluated, and recommendations are developed. Requirements for development of technology and data needed to improve gasification feasibility and economies are examined.

The clean coal initiative: An appropriate response to complex environmental issues

International Nuclear Information System (INIS)

Miller, C.L.

1991-01-01

The paper discusses the Department of Energy's Clean Coal Technology Program that can offer significant benefits when these technologies are used for power production, pollution control or the conversion of coal into other alternative energy products. The paper describes the status of the program, the 35 projects currently in the program, and the environmental role of clean coal technologies

Coal marketing in Asia: Opportunities and challenges

International Nuclear Information System (INIS)

Klingner, D.

1996-01-01

In Asia, coal currently accounts for over 40 percent of the fossil fuel used for commercial energy. This paper briefly surveys the forces that are likely to decide the future role coal will play as a prime source of energy in the vigorous economies of Asia. As Australia is well placed to profit from Asia's growing need for coal, the challenge to Australian coal suppliers is how to maximize its potential contribution. Four-fifths of all new coal fired electrical generating capacity in the world in the next decade will be located in Asia. Three-quarters of Australia's coal exports are to Asian customers and, conversely, 40 percent of Asian imports are from Australia. Australian coal suppliers have established ties and a depth of marketing experience in the region on which to build. However, pricing policies, and the emergence of the private power producers, together with environmental pressures, will present challenges for the future. (author). 1 fig

Coal-fired high performance power generating system

Energy Technology Data Exchange (ETDEWEB)

1992-07-01

The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of > 47% thermal efficiency; NO[sub x] SO [sub x] and Particulates < 25% NSPS; Cost of electricity 10% lower; coal > 65% of heat input and all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW[sub e] combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (HITAF) which integrates several combustor and air heater designs with appropriate ash management procedures. Most of this report discusses the details of work on these components, and the R D Plan for future work. The discussion of the combustor designs illustrates how detailed modeling can be an effective tool to estimate NO[sub x] production, minimum burnout lengths, combustion temperatures and even particulate impact on the combustor walls. When our model is applied to the long flame concept it indicates that fuel bound nitrogen will limit the range of coals that can use this approach. For high nitrogen coals a rapid mixing, rich-lean, deep staging combustor will be necessary. The air heater design has evolved into two segments: a convective heat exchanger downstream of the combustion process; a radiant panel heat exchanger, located in the combustor walls; The relative amount of heat transferred either radiatively or convectively will depend on the combustor type and the ash properties.

Autonomous renewable energy conversion system

Energy Technology Data Exchange (ETDEWEB)

Valtchev, V. [Technical University of Varna (Bulgaria). Dept. of Electronics; Bossche, A. van den; Ghijselen, J.; Melkebeek, J. [University of Gent (Belgium). Dept. of Electrical Power Engineering

2000-02-01

This paper briefly reviews the need for renewable power generation and describes a medium-power Autonomous Renewable Energy Conversion System (ARECS), integrating conversion of wind and solar energy sources. The objectives of the paper are to extract maximum power from the proposed wind energy conversion scheme and to transfer this power and the power derived by the photovoltaic system in a high efficiency way to a local isolated load. The wind energy conversion operates at variable shaft speed yielding an improved annual energy production over constant speed systems. An induction generator (IG) has been used because of its reduced cost, robustness, absence of separate DC source for excitation, easier dismounting and maintenance. The maximum energy transfer of the wind energy is assured by a simple and reliable control strategy adjusting the stator frequency of the IG so that the power drawn is equal to the peak power production of the wind turbine at any wind speed. The presented control strategy also provides an optimal efficiency operation of the IG by applying a quadratic dependence between the IG terminal voltage and frequency V {approx} f{sup 2}. For improving the total system efficiency, high efficiency converters have been designed and implemented. The modular principle of the proposed DC/DC conversion provides the possibility for modifying the system structure depending on different conditions. The configuration of the presented ARECS and the implementation of the proposed control algorithm for optimal power transfer are fully discussed. The stability and dynamic performance as well as the different operation modes of the proposed control and the operation of the converters are illustrated and verified on an experimental prototype. (author)

Energy conversion using hydrogen PEM fuel cells

International Nuclear Information System (INIS)

Stoenescu, D.; Patularu, L.; Culcer, M.; Lazar, R.; Mirica, D.; Varlam, M.; Carcadea, E.; Stefanescu, I.

2004-01-01

It is well known that hydrogen is the most promising solution of future energy, both for long and medium term strategies. Hydrogen can be produced using many primary sources (naphthalene, natural gas, methanol, coal, biomass), solar cells power, etc. It can be burned or chemically reacted having a high yield of energy conversion and is a non-polluted fuel. This paper presents the results obtained by ICSI Rm. Valcea in an experimental-demonstrative conversion energy system consisting in a catalytic methane reforming plant for hydrogen production and three synthesis gas purification units in order to get pure hydrogen with a CO level lower than 10 ppm that finally feeds a hydrogen fuel stock. (authors)

Fiscal 1997 survey report. Feasibility study of the environmentally friendly type coal utilization system (feasibility study of the environmentally friendly type coal utilization system in India); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Indo ni okeru kankyo chowagata sekitan riyo system kanosei chosa)

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

The survey was conducted of the present situation of coal utilization and the present coal situation such as the environmental state of India which is a coal producing/consuming country next to China in Asia. The paper studied a feasibility of the introduction of the environmental friendly type coal utilization system` to be planned in India. The items for survey are the present situation of economy and energy and the future trend, environmental problems on coal utilization, the present status of the coal distribution system and study subjects, the present status of coal utilization by field and study subjects, a possibility of briquette use, a possibility of coal fluidization, electric power development plans and coal combustion technology in each industry, etc. The subjects are the obligation of coal preparation to coal thermal power plants 1000 km away from coal mines starting 2001, measures taken for effective ash use, measures taken for superannuated gas furnaces, etc. Based on the results of these site surveys and reports of the investigation under consignment from CMPDI, the paper studied/analyzed possibilities of introducing the coal utilization system having actual introduction results in Japan to India, and made an investigational report. 39 refs., 12 figs., 56 tabs.

Microbially-Enhanced Coal Bed Methane: Strategies for Increased Biogenic Production

Science.gov (United States)

Davis, K.; Barhart, E. P.; Schweitzer, H. D.; Cunningham, A. B.; Gerlach, R.; Hiebert, R.; Fields, M. W.

2014-12-01

Coal is the largest fossil fuel resource in the United States. Most of this coal is deep in the subsurface making it costly and potentially dangerous to extract. However, in many of these deep coal seams, methane, the main component of natural gas, has been discovered and successfully harvested. Coal bed methane (CBM) currently accounts for approximately 7.5% of the natural gas produced in the U.S. Combustion of natural gas produces substantially less CO2 and toxic emissions (e.g. heavy metals) than combustion of coal or oil thereby making it a cleaner energy source. In the large coal seams of the Powder River Basin (PRB) in southeast Montana and northeast Wyoming, CBM is produced almost entirely by biogenic processes. The in situ conversion of coal to CBM by the native microbial community is of particular interest for present and future natural gas sources as it provides the potential to harvest energy from coal seams with lesser environmental impacts than mining and burning coal. Research at Montana State University has shown the potential for enhancing the subsurface microbial processes that produce CBM. Long-term batch enrichments have investigated the methane enhancement potential of yeast extract as well as algal and cyanobacterial biomass additions with increased methane production observed with all three additions when compared to no addition. Future work includes quantification of CBM enhancement and normalization of additions. This presentation addresses the options thus far investigated for increasing CBM production and the next steps for developing the enhanced in situ conversion of coal to CBM.

Materials, process, product analysis of coal process technology. Phase I final report

Energy Technology Data Exchange (ETDEWEB)

Saxton, J. C.; Roig, R. W.; Loridan, A.; Leggett, N. E.; Capell, R. G.; Humpstone, C. C.; Mudry, R. N.; Ayres, E.

1976-02-01

The purpose of materials-process-product analysis is a systematic evaluation of alternative manufacturing processes--in this case processes for converting coal into energy and material products that can supplement or replace petroleum-based products. The methodological steps in the analysis include: Definition of functional operations that enter into coal conversion processes, and modeling of alternative, competing methods to accomplish these functions; compilation of all feasible conversion processes that can be assembled from combinations of competing methods for the functional operations; systematic, iterative evaluation of all feasible conversion processes under a variety of economic situations, environmental constraints, and projected technological advances; and aggregative assessments (economic and environmental) of various industrial development scenarios. An integral part of the present project is additional development of the existing computer model to include: A data base for coal-related materials and coal conversion processes; and an algorithmic structure that facilitates the iterative, systematic evaluations in response to exogenously specified variables, such as tax policy, environmental limitations, and changes in process technology and costs. As an analytical tool, the analysis is intended to satisfy the needs of an analyst working at the process selection level, for example, with respect to the allocation of RDandD funds to competing technologies.

Final Scientific/Technical Report for project “Increasing the Rate and Extent of Microbial Coal to Methane Conversion through Optimization of Microbial Activity, Thermodynamics, and Reactive Transport”

Energy Technology Data Exchange (ETDEWEB)

Fields, Matthew [Montana State Univ., Bozeman, MT (United States)

2018-01-17

Currently, coal bed methane (CBM) wells have a limited lifetime since the rate of methane removal via the installed wells is much faster than the in situ methane production rates. Along with water issues created by large amounts of CBM production water, the short life span of CBM wells is a huge deterrent to the environmental and economic feasibility of CBM production. The process of biogenic methanogenesis can be enhanced via the stimulation of the associated microbial communities that can convert the organic fractions of coal to methane. This process is termed Microbially-Enhanced Coal Bed Methane (MECBM). However, the rates of methane production are still limited and long incubation times are necessary. We hypothesized that the elucidation of chemical and biological parameters that limited MECBM together with thermodynamic considerations would inform strategies to optimize the process under flow conditions. We incorporated microbiological, physicochemical, and engineering processes to develop a more sustainable CBM production scheme with native coal and native microorganisms. The proposed combination of microbial ecology and physiology as well as optimized engineering principles minimized key constraints that impact microbial coal conversion to methane under environmentally relevant conditions. The combined approach for bench-scale tests resulted in more effective and less environmentally burdensome coal-dependent methane production with the potential for H2O and CO2 management.

Design of generic coal conversion facilities: Process release---Direct coal liquefaction

Energy Technology Data Exchange (ETDEWEB)

1991-09-01

The direct liquefaction portion of the PETC generic direct coal liquefaction process development unit (PDU) is being designed to provide maximum operating flexibility. The PDU design will permit catalytic and non-catalytic liquefaction concepts to be investigated at their proof-of-the-concept stages before any larger scale operations are attempted. The principal variations from concept to concept are reactor configurations and types. These include thermal reactor, ebullating bed reactor, slurry phase reactor and fixed bed reactor, as well as different types of catalyst. All of these operating modes are necessary to define and identify the optimum process conditions and configurations for determining improved economical liquefaction technology.

Thermodynamic comparison and efficiency enhancement mechanism of coal to alternative fuel systems

International Nuclear Information System (INIS)

Ji, Xiaozhou; Li, Sheng; Gao, Lin; Jin, Hongguang

2016-01-01

Highlights: • Energy and exergy analysis are presented to three coal-to-alternative-fuels systems. • Internal reasons for performance differences for different systems are disclosed. • The temperature and heat release of synthesis reactions are key to plant efficiency. • The distillation unit and purge gas recovery are important to efficiency enhancement. - Abstract: Coal to alternative fuels is an important path to enforce energy security and to provide clean energy. In this paper, we use exergy analysis and energy utilization diagram (EUD) methods to disclose the internal reasons for performance differences in typical coal to alternative fuel processes. ASPEN plus software is used to simulate the coal-based energy systems, and the simulation results are verified with engineering data. Results show that coal to substitute natural gas (SNG) process has a higher exergy efficiency of 56.56%, while the exergy efficiency of traditional coal to methanol process is 48.65%. It is indicated that three key factors impact the performance enhancement of coal to alternative fuel process: (1) whether the fuel is distillated, (2) the synthesis temperature and the amount of heat release from reactions, and (3) whether the chemical purge gases from synthesis and distillation units are recovered. Distillation unit is not recommended and synthesis at high temperature and with large heat release is preferable for coal to alternative fuel systems. Gasification is identified as the main source of exergy destruction, and thereby how to decrease its destruction is the key direction of plant efficiency improvement in the future. Also, decreasing the power consumption in air separation unit by seeking for advanced technologies, i.e. membrane, or using another kind of oxidant is another direction to improve plant performance.

Overall requirements for an advanced underground coal extraction system. [environment effects, miner health and safety, production cost, and coal conservation

Science.gov (United States)

Goldsmith, M.; Lavin, M. L.

1980-01-01

Underground mining systems suitable for coal seams expoitable in the year 2000 are examined with particular relevance to the resources of Central Appalachia. Requirements for such systems may be summarized as follows: (1) production cost; (2)miner safety; (3) miner health; (4) environmental impact; and (5) coal conservation. No significant trade offs between production cost and other performance indices were found.

Combined coal gasification and Fe{sub 3}O{sub 4}-reduction using high-temperature solar process heat

Energy Technology Data Exchange (ETDEWEB)

Tamaura, Y [Tokyo Inst. of Technology, Tokyo (Japan); Ehrensberger, K; Steinfeld, A [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

1997-06-01

The coal/Fe{sub 3}O{sub 4} system was experimentally studied at PSI solar furnace. The reactants were directly exposed to a solar flux irradiation of 3,000 suns (1 sun = 1 kW/m{sup 2}). The combined gasification of coal and reduction of Fe{sub 2}O{sub 3} proceeded rapidly after only one second exposure, suggesting an efficient heat transfer and chemical conversion by direct solar energy absorption at the reaction site. The proposed solar thermochemical process offers the possibility of converting coal to a cleaner fluid fuel with a solar-upgraded calorific value. (author) 2 figs., 8 refs.

The behavior of catalysts in hydrogasification of sub-bituminous coal in pressured fluidized bed

International Nuclear Information System (INIS)

Yan, Shuai; Bi, Jicheng; Qu, Xuan

2017-01-01

Highlights: •CCHG in a pressured fluidized bed achieved 77.3 wt.% of CH 4 yield in 30 min. •Co-Ca and Ni-Ca triggered catalytic coal pyrolysis and char hydrogasification. •The reason for better catalytic performance of 5%Co-1%Ca was elucidated. •Sintered catalyst blocked the reactive sites and suppressed coal conversion. •Co-Ca made the catalyzed coal char rich in mesopore structures and reactive sites. -- Abstract: The catalytic hydrogasification of the sub-bituminous coal was carried out in a lab-scale pressurized fluidized bed with the Co-Ca, Ni-Ca and Fe-Ca as catalysts at 850 °C and 3 MPa. The effect of different catalysts on the characteristics of gasification products was investigated, and the behavior of the catalysts was also explored by means of the X-ray diffraction (XRD), FT-Raman, Brunauer–Emmett–Teller (BET), etc. Experiment results showed that all the catalysts promoted the carbon conversion in the coal catalytic hydrogasification (CCHG), and the catalytic activity was in the order: 5%Co-1%Ca > 5%Ni-1%Ca > 5%Fe-1%Ca. Compared with the raw coal hydrogasification, the carbon conversion increased from 43.4 wt.% to 91.3 wt.%, and the CH 4 yield increased from 23.7 wt.% to 77.3 wt.% within 30 min after adding the 5%Co-1%Ca catalyst into the coal. Co-Ca and Ni-Ca possessed catalytic effect on both processes of pyrolysis of coal and hydrogasification of coal char in CCHG, by which the graphitization of the coal was suppressed and methane formation rate was significantly accelerated. Fe/Co/Ni-Ca could penetrate into the interior of coal during CCHG, making the catalytic production of CH 4 conduct in the pore structures. The activity difference of the catalysts was owing to the different ability of rupturing the amorphous C−C bonds in coal structure. The incomplete carbon conversion of the 5%Co-1%Ca loaded coal was due to the agglomeration of the catalyst and the blockage of the reactive sites by the sintered catalyst. This work will provide

Underground coal gasification with integrated carbon dioxide mitigation supports Bulgaria's low carbon energy supply

Science.gov (United States)

Nakaten, Natalie; Kempka, Thomas; Azzam, Rafig

2013-04-01

Underground coal gasification allows for the utilisation of coal reserves that are economically not exploitable due to complex geological boundary conditions. The present study investigates underground coal gasification as a potential economic approach for conversion of deep-seated coals into a high-calorific synthesis gas to support the Bulgarian energy system. Coupling of underground coal gasification providing synthesis gas to fuel a combined cycle gas turbine with carbon capture and storage is considered to provide substantial benefits in supporting the Bulgarian energy system with a competitive source of energy. In addition, underground voids originating from coal consumption increase the potential for geological storage of carbon dioxide resulting from the coupled process of energy production. Cost-effectiveness, energy consumption and carbon dioxide emissions of this coupled process are investigated by application of a techno-economic model specifically developed for that purpose. Capital (CAPEX) and operational expenditure (OPEX) are derived from calculations using six dynamic sub-models describing the entire coupled process and aiming at determination of the levelised costs of electricity generation (COE). The techno-economic model is embedded into an energy system-modelling framework to determine the potential integration of the introduced low carbon energy production technology into the Bulgarian energy system and its competitiveness at the energy market. For that purpose, boundary conditions resulting from geological settings as well as those determined by the Bulgarian energy system and its foreseeable future development have to be considered in the energy system-modelling framework. These tasks comprise integration of the present infrastructure of the Bulgarian energy production and transport system. Hereby, the knowledge on the existing power plant stock and its scheduled future development are of uttermost importance, since only phasing-out power

The future of coal-fired generation

Energy Technology Data Exchange (ETDEWEB)

White, G. [Sherritt International Corp., Calgary, AB (Canada)

2004-07-01

The 3 features that will ensure coal's place as a primary energy source are its affordability, availability and its abundance. Coal reserves represent more than 200 years of supply. Graphs depicting coal consumption in North America, Central and South America, Western Europe, Easter Europe, Middle East, Africa, and Asia show that coal use is expected to grow 1.5 per cent annually. Asia is the greatest consumer of coal, while the consumption of coal in Eastern Europe is steadily declining. About half of the electricity supply in the United States will continue to be generated by coal and non-electrical utilization is also expected to grow. Emerging technologies that are promoting efficiency of coal utilization include combustion technology, clean coal technology, conversion technology and emissions technology. These technologies also address environmental concerns regarding coal combustion, such as removal of carbon dioxide through sequestration and reduction in nitrogen oxides, sulphur dioxide and particulates. Mercury mitigation technologies are also being developed. It was noted that the use of coal is mitigated by other available supply such as nuclear, natural gas and hydro which provide the base load generation. Renewable energy supply can meet up to 20 per cent of the base load, while coal can fill be gap between base load and peak loads. It was noted that the use of coal in direct industrial processes allows for synergies such as syngas for bitumen upgrading, coal as a chemical feedstock with electricity as a by-product, combined heat and power and cogeneration. tabs., figs.

TFTR power conversion and plasma feedback systems

International Nuclear Information System (INIS)

Neumeyer, C.

1985-01-01

Major components of the Tokamak Fusion Test Reactor (TFTR) power conversion system include 39 thyristor rectifier power supplies, 12 energy storage capacitor banks, and 6 ohmic heating interrupters. These components are connected in various series/parallel configurations to provide controlled pulses of current to the Toroidal Field (TF), Ohmic Heating (OH), Equilibrium (vertical) Field (EF), and Horizontal Field (HF) magnet coil systems. Real-time control of the power conversion system is accomplished by a centralized dedicated computer; local control is minimal. Power supply firing angles, capacitor bank charge and discharge commands, interrupter commands, etc., are all determined and issued by the central computer. Plasma Position and Current Control (PPCC) reference signals to power conversion (OH, EF, HF) are determined by separate analog electronics but invoked through the power conversion computer. Real-time fault sensing of plasma parameters, gas injection, neutral beams, etc., are monitored by a separate Discharge Fault System (DFS) but routed through the power conversion computer for pre-programmed shutdown response

Coal 1992

Energy Technology Data Exchange (ETDEWEB)

1992-01-01

ACR's Coal 1992, the successor to the ACR Coal Marketing Manual, contains a comprehensive set of data on many aspects of the Australian coal industry for several years leading up to 1992. Tables and text give details of coal production and consumption in New South Wales, Queensland and other states. Statistics of the Australian export industry are complemented by those of South Africa, USA, New Zealand, Canada, Indonesia, China, Colombia, Poland and ex-USSR. Also listed are prices of Australian coking and non-coking coal, Australian coal stocks (and those of other major countries), loading port capacities, freight rates and coal quality requirements (analysis of coals by brand and supplier). A listing of Australian coal exporting companies is provided. A description of the spot Coal Screen Dealing System is given. World hard coal imports are listed by country and coal imports by major Asian countries tabulated. A forecast of demand by coal type and country up to the year 2000 is included.

Life cycle assessment of solar aided coal-fired power system with and without heat storage

International Nuclear Information System (INIS)

Zhai, Rongrong; Li, Chao; Chen, Ying; Yang, Yongping; Patchigolla, Kumar; Oakey, John E.

2016-01-01

Highlights: • The comprehensive performances of three kinds of different systems were compared through LCA. • The comprehensive results of all systems were evaluated by grey relation theory. • The effects of life span, coal price, and solar collector field cost, among other factors, on the results were explored. - Abstract: Pollutant emissions from coal-fired power system have been receiving increasing attention over the past few years. Integration of solar thermal energy can greatly reduce pollutant emissions from these power stations. The performances of coal-fired power system (S1), solar aided coal-fired power system with thermal storage (S2), and solar aided coal-fired power system without thermal storage (S3) with three capacities of each kind of system (i.e., nine subsystems) were analyzed over the entire life span. The pollutant emissions and primary energy consumptions (PECs) of S1, S2, and S3 were estimated using life cycle assessment (LCA). The evaluation value of global warming potential (GWP), acidification potential (AP), respiratory effects potential (REP) and PEC were obtained based on the LCA results. Furthermore, the system investments were estimated, and grey relation theory was used to evaluate the performance of the three types of systems comprehensively. Finally, in order to find the effect of some main factors on the solar aided coal-fired power system (SACFPS), uncertainty analysis has been carried out. The LCA results show that the pollutant emissions and PEC mainly take place in the fuel processing and operation stages for all three system types, and S2 performs the best among the three systems based on the grey relation analysis results. And the uncertainty analysis shows that with longer life span, the power system have better performance; with higher coal price, the power system will have worse performance; with lower solar collector field cost, the solar aided coal-fired power system will be more profitable than the base

Low NOx firing systems for bituminous coal and lignite

International Nuclear Information System (INIS)

Knyrim, W.; Scheffknecht, G.

1997-01-01

In the case of lignite fluidized boilers the denitrification down to less than 200 mg/m 3 was possible with primary measures on the firing side only. On account of the excellent results achieved with the reconstructed plants the firing systems for the new generation of brown coal fire steam generators with a capacity of 800 MW and more is designed in a similar way. For bituminous coal fire steam generators the primary measures on the firing side are nor sufficient to keep the German NO x emission limit. Therefore these units had to be retrofitted with a SCR-DENOX plant. The experience with the new firing system made in a 110 MW steam generator in Austria with a wide range of fuels is introduced. One of the largest bituminous coal fired once-trough steam generator built by EVT is the boiler for the power station Bexbach I (750 MW). The firing system is designed as a tangential firing system with 32 jet burners. These are arranged in pairs in the corners and divided into 4 burner levels with 4 burner pairs each. One mill is allocated to each burner level. An important characteristic feature is that the four bowl mills are arranged on one side of the steam generator. The plant is constructed with upper air nozzles which are arranged above the top burner level for the reduced of nitrogen oxides. During tests at steam generator with similar design, the nO x formation could be reduced from 750 to 500 mg/m 3 s.t.p. (dry, 6% O 2 ) with an addition of upper air of 20% at 100% unit capacity and constant total flow. As a main approach for the further reduction of the primary NO x emission at bituminous coal fired steam generators with tangential firing systems, the experience gained from the firing of brown coal has also been taken into account. A fundamental aspect in this respect was the vertical air staging in the direction of the furnace height. The results of many tests in a test reactor have shown that the differences of the achievable NO x values of brown and

Microwave radiation improves biodiesel yields from waste cooking oil in the presence of modified coal fly ash

Directory of Open Access Journals (Sweden)

Yulin Xiang

2017-11-01

Full Text Available This paper studied the effects of using modified coal fly ash as a catalyst to convert waste cooking oil (WCO into biodiesel under microwave-strengthened action. Coal fly ash was modified with sodium sulphate and sodium hydroxide, and the obtained catalyst was characterized using FT-IR and X-ray diffraction (XRD. The experimental results showed that the modified coal fly ash catalyst improved biodiesel yields under the microwave-assisted system, and the maximum biodiesel yield from waste cooking oil reached 94.91% at a molar ratio of methanol to WCO of 9.67:1 with 3.99% wt% of modified coal fly ash catalyst (based on oil weight at a 66.20 °C reaction temperature. The reusability of the modified coal fly ash catalyst was excellent, and the conversion yield remained greater than 90% after the catalyst was reused 8 times. The produced biodiesel met the main parameters of the ASTM D-6751 and EN14214 standards. Keywords: Biodiesel, Modified coal fly ash, Microwave assisted system, Waste cooking oil

Energy Conversion and Storage Program

Energy Technology Data Exchange (ETDEWEB)

Cairns, E.J.

1992-03-01

The Energy Conversion and Storage Program applies chemistry and materials science principles to solve problems in (1) production of new synthetic fuels, (2) development of high-performance rechargeable batteries and fuel cells, (3) development of advanced thermochemical processes for energy conversion, (4) characterization of complex chemical processes, and (5) application of novel materials for energy conversion and transmission. Projects focus on transport-process principles, chemical kinetics, thermodynamics, separation processes, organic and physical chemistry, novel materials, and advanced methods of analysis. Electrochemistry research aims to develop advanced power systems for electric vehicle and stationary energy storage applications. Topics include identification of new electrochemical couples for advanced rechargeable batteries, improvements in battery and fuel-cell materials, and the establishment of engineering principles applicable to electrochemical energy storage and conversion. Chemical Applications research includes topics such as separations, catalysis, fuels, and chemical analyses. Included in this program area are projects to develop improved, energy-efficient methods for processing waste streams from synfuel plants and coal gasifiers. Other research projects seek to identify and characterize the constituents of liquid fuel-system streams and to devise energy-efficient means for their separation. Materials Applications research includes the evaluation of the properties of advanced materials, as well as the development of novel preparation techniques. For example, the use of advanced techniques, such as sputtering and laser ablation, are being used to produce high-temperature superconducting films.

Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Feasibility study of the environmentally friendly type coal utilization system in the Philippines; Kankyo chowagata sekitan riyo system kanosei chosa. Philippines ni okeru kankyo chowagata sekitan riyo system kanosei chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-03-01

Grasping the present situation of coal utilization technology in the Philippines, the paper proposed a feasibility study of introduction of the environmentally friendly type coal utilization system which seems to be needed in the future. (1) Introduction of the environmentally friendly type coal utilization system in the electric power generation sector: there are only four full-scale running coal thermal power plants in the Philippines. In the future, several coal thermal plants are planned to be constructed by 2005, but for the new installation, it is desirable to adopt fluidized bed boilers with wide application to coal kinds. In case of 0.3-1.0 million MW class plants, it is planned to adopt high grade import coals, and it will be natural to fire pulverized coal. For the processing of flue gas, it is a must to install desulfurization facilities and smoke/soot removal devices. (2) Utilization/development of domestic low grade coals: at the mine-mouth generating plant, it is necessary to investigate the economically minable amount of coal, confirm productivity, survey coal quality, etc., and select boiler. As to coal briquetting technology, it is necessary to examine coal quality for tests and make a thorough study of what technology is most suitable. 50 figs., 78 tabs.

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

Energy Technology Data Exchange (ETDEWEB)

Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

2001-12-01

The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

Coal - 96

International Nuclear Information System (INIS)

Sparre, C.

1996-09-01

The report deals mainly with coal consumption, but also gives some information about technology, environmental aspects and markets. Data have been collected by questionnaires or via telephone. The use of steam coal for heating was 0.8 Mtons (down 20% from 1994). Cogeneration plants were the main users. Taxes and environmental reasons cause a reduction of the coal use that will probably continue the next years. Use of steam coal in industry has been constant at a level of 0.7 Mtons. The import of metallurgical coal rests constant at a level of 1.6 Mtons. 1.2 Mtons of coke was produced, and 0.3 Mtons imported. The PFBC-plant at Vaertan, Stockholm used 0.13 Mtons of coal, while some coal fired power plants have been converted to peat and wood fuels. The average price of steam coal imported to Sweden in 1995 was 333 SEK/ton, 6% higher than in 1994. The contract prices for delivery 1996 are about the same as at the end of 1995. All cogeneration plants have some sort of SO 2 removal system, mostly wet-dry. The largest plant, at Vaesteraas, has recently invested in a SCR system for NO x removal. Most other plants are using low NO x burners or SNCR systems, based on ammonia or urea, which reduce the emissions 50 - 70%. Some statistic about the world coal market is also given in the report

Feasibility survey of the environmentally-friendly coal utilization system. Feasibility survey of the environmentally-friendly coal utilization system in the Philippines; Kankyo chowagata sekitan riyo system kanosei chosa. Philippines ni okeru kankyo chowagata sekitan riyo system kanosei chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-03-01

With relation to the coal of the Philippines, where the expansion of the use of coal as a substitute for petroleum/plant fuel is aimed at, the paper grasped the situation of coal production/development, the trend of coal import and domestic distribution, the coal utilization trend, and environmental problems, and analyzed the situation of coal utilization/spread by industry including the commercial/residential use. The purpose of the survey is to draw up a master plan for the introduction of the environmentally-friendly coal utilization system. As to the use of environmentally-friendly coal technology which should be adopted to the coal mining industry and commercial/residential sector, cited are the introduction of coal preparation technology and power transmission technology, and the development/spread of briquette as a firewood substituting fuel. In the electric power sector, the problem is the treatment of ash after combustion and the effective use. Relating to the treatment of flue gas, there is no installation at all of desulfurization facilities and denitrification facilities. In the cement industry sector, they wish to return fuel from heavy oil to coal. For it, it is necessary to study dust preventive measures. In the other sectors, coal hasn`t been used very much. An increase in coal demand is not expected also in the future, and big problems concerning coal haven`t occurred. 42 figs., 64 tabs.

A Study on the Hydrotreating of Coal Hydroliquefaction Residue and its Kinetics

Directory of Open Access Journals (Sweden)

Jinsheng Gao

2010-09-01

Full Text Available Hydro-conversion of coal hydroliquefaction residue obtained from a 6t/day pilot plant of Shenhua Group in Shanghai was carried out under the hydrotreating condition. The coal hydroliquefaction residue and its product were extracted in sequence with n-hexane, toluene and tetrahydrofuran in a Soxhlet apparatus. The n-hexane soluble fractions increased with the increase of reaction temperature and time. Its amount increased from 14.14% to a maximum of 40.86% under the conditions of 470 °C and 30 min, which meant that moderate extension of coal residence time in the coal hydroliquefaction reactor is beneficial to the increase of oil yield. A 4-lumped kinetic model of coal hydroliquefaction residue hydro-conversion was performed using solubility-based lumped fractions. In the model, the tetrahydrofuran insoluble fractions were classified into two parts: easily reactive part and unreactive part. The kinetic parameters were estimated by a fourth-order Runge-Kutta method and a nonlinear least squares method, and the apparent activation energies were calculated according to the Arrhenius Equation. A large quantity of total catalyst consisting of remained liquefaction catalyst, part of the mineral from raw coal and additive Fe-based catalyst could considerably reduce the apparent activation energy of hydro-conversion for the toluene insoluble/tetrahydrofuran insoluble fractions to 36.79 kJ•mol-1. The calculated values of the model coincided well with the experimental values.

SECA Coal-Based Systems - LGFCS

Energy Technology Data Exchange (ETDEWEB)

Goettler, Richard

2014-01-31

LGFCS is developing an integrated planar (IP) SOFC technology for mega-watt scale power generation including the potential for use in highly efficient, economically competitive central generation power plant facilities fuel by coal synthesis gas. This Department of Energy Solid-State Energy Conversion Alliance (SECA) program has been aimed at achieving further cell and stack technical advancements and assessing the readiness of the LGFCS SOFC stack technology to be scaled to larger-scale demonstrations as a path to commercialization. Significant progress was achieved in reducing to practice a higher performance and lower cost cell technology, identifying and overcoming degradation mechanisms, confirming the structural capability of the porous substrate for reliability, maturing the strip design for improved flow to allow high fuel utilization operation while minimizing degradation mechanisms and obtaining full scale block testing at 19 kW under representative conditions for eventual product and meeting SECA degradation metrics. The SECA program has played a key role within the overall LGFCS development program in setting the foundation of the technology to justify the progression of the technology to the next level of technology readiness testing.

The future of coal as an energy source

International Nuclear Information System (INIS)

Wells, W.L.

1991-01-01

This paper reports on the future of such coal as an energy source which the author believes, is inextricably related to its economic and environmental acceptability. Technologies have been - and are being - developed that will help assure that coal retains its traditional share of the United States energy market. In addition, there are some 900 million tons per year of coal equivalent oil and gas currently being consumed (22.5 quads of 12.500 BTU/lb coal) in the United States that may be considered for potential coal conversion. Lastly, one can see trends emerging that may justify reconsideration of coal as a source of hydrocarbon to substitute for petrochemical industry feedstocks in addition to its customary role as a BTU supplier. The balance of this report will provide a background on environmental and legislative initiatives and discuss some of these technologies and new directions for coal research in the 1990s and beyond

Fiscal 1975 Sunshine Project. Technology assessment on coal gasification and liquefaction; 1975 nendo sekitan no gas ka ekika gijutsu no technology assessment seika hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

1976-03-31

This research was intended to find the desirable direction of technological development, by discussing the effects of coal gasification/liquefaction technologies from every angle, for the purpose coping with the social demand for steadily and continuously obtaining clean energy. This year, the examination was conducted not only on the energy conversion technologies of coal gasification/liquefaction, but also on the impact generating from the entire supply system of coal energy from coal mine development to mining, transportation, storage and conversion to secondary energy. For this purpose, while the outline was grasped of coal resources in the world as well as each technology for the mining, transportation, storage, electric power generation by gasification, and high calorie gasification, a case study was made on the assumption that electric power generation and high calorie gasification were conducted by importing 1,000 tons of coal from overseas, extracting the impact on the basis of this case study. In addition, examination was made on the position of coal energy in the energy supply of the future, with an impact investigated on condition that about 300 million tons were imported equivalent to roughly 16% of energy supply in the year 2000 or about. (NEDO)

Wind Energy Conversion Systems Technology and Trends

CERN Document Server

2012-01-01

Wind Energy Conversion System covers the technological progress of wind energy conversion systems, along with potential future trends. It includes recently developed wind energy conversion systems such as multi-converter operation of variable-speed wind generators, lightning protection schemes, voltage flicker mitigation and prediction schemes for advanced control of wind generators. Modeling and control strategies of variable speed wind generators are discussed, together with the frequency converter topologies suitable for grid integration. Wind Energy Conversion System also describes offshore farm technologies including multi-terminal topology and space-based wind observation schemes, as well as both AC and DC based wind farm topologies. The stability and reliability of wind farms are discussed, and grid integration issues are examined in the context of the most recent industry guidelines. Wind power smoothing, one of the big challenges for transmission system operators, is a particular focus. Fault ride th...

SYSTEM ANALYSIS OF NUCLEAR-ASSISTED SYNGAS PRODUCTION FROM COAL

International Nuclear Information System (INIS)

E. A. Harvego; M. G. McKellar; J. E. O'Brien

2008-01-01

A system analysis has been performed to assess the efficiency and carbon utilization of a nuclear-assisted coal gasification process. The nuclear reactor is a high-temperature helium-cooled reactor that is used primarily to provide power for hydrogen production via high-temperature electrolysis. The supplemental hydrogen is mixed with the outlet stream from an oxygen-blown coal gasifier to produce a hydrogen-rich gas mixture, allowing most of the carbon dioxide to be converted into carbon monoxide, with enough excess hydrogen to produce a syngas product stream with a hydrogen/carbon monoxide molar ratio of about 2:1. Oxygen for the gasifier is also provided by the high-temperature electrolysis process. Results of the analysis predict 90.5% carbon utilization with a syngas production efficiency (defined as the ratio of the heating value of the produced syngas to the sum of the heating value of the coal plus the high-temperature reactor heat input) of 66.1% at a gasifier temperature of 1866 K for the high-moisture-content lignite coal considered. Usage of lower moisture coals such as bituminous can yield carbon utilization approaching 100% and 70% syngas production efficiency

System Analysis of Nuclear-Assisted Syngas Production from Coal

International Nuclear Information System (INIS)

Harvego, E.A.; McKellar, M.G.; O'Brien, J.E.

2009-01-01

A system analysis has been performed to assess the efficiency and carbon utilization of a nuclear-assisted coal gasification process. The nuclear reactor is a high-temperature helium-cooled reactor that is used primarily to provide power for hydrogen production via high temperature electrolysis. The supplemental hydrogen is mixed with the outlet stream from an oxygen-blown coal gasifier to produce a hydrogen-rich gas mixture, allowing most of the carbon dioxide to be converted into carbon monoxide, with enough excess hydrogen to produce a syngas product stream with a hydrogen/carbon monoxide molar ratio of about 2:1. Oxygen for the gasifier is also provided by the high-temperature electrolysis process. Results of the analysis predict 90.5% carbon utilization with a syngas production efficiency (defined as the ratio of the heating value of the produced syngas to the sum of the heating value of the coal plus the high-temperature reactor heat input) of 64.4% at a gasifier temperature of 1866 K for the high-moisture-content lignite coal considered. Usage of lower moisture coals such as bituminous can yield carbon utilization approaching 100% and 70% syngas production efficiency.

Modeling on a PWR power conversion system with system program

International Nuclear Information System (INIS)

Gao Rui; Yang Yanhua; Lin Meng

2007-01-01

Based on the power conversion system of nuclear and conventional islands of Daya Bay Power Station, this paper models the thermal-hydraulic systems of primary and secondary loops for PWR by using the PWR best-estimate program-RELAP5. To simulate the full-scope power conversion system, not only the traditional basic system models of nuclear island, but also the major system models of conventional island are all considered and modeled. A comparison between the calculated results and the actual data of reactor demonstrates a fine match for Daya Bay Nuclear Power Station, and manifests the feasibility in simulating full-scope power conversion system of PWR by RELAP5 at the same time. (authors)

Thermogravimetric analysis of multi-stage hydropyrolysis of different coals

Energy Technology Data Exchange (ETDEWEB)

Li, W.; Wang, N.; Li, B [Chinese Academy of Sciences, Taiyuan (China). State Key Lab. of Coal Conversion

2001-09-01

Based on the characteristic of hydropyrolysis (HyPy), a multi-stage MHyPy of different coals was investigated using thermogravimetry. The results show that keeping the near peak temperature for some time in HyPy process can obviously increase the conversion rate, which is believed due to the full match between formation rate of free radicals and supply of hydrogen. The fast heating in MHyPy process results in the same conversion rate as that of the slow heating in HyPy process, which leads to the less reaction time and high yield of oil. The effect of MHyPy depends on the coal structure itself and it is notable for the coal with high H/C ratio. This suggests that the external hydrogen promotes the reaction between intrinsic hydrogen and free radicals. The MHyPy improves the removal of sulfur and nitrogen. 5 refs., 7 figs., 2 tabs.

Liquid CO₂/Coal Slurry for Feeding Low Rank Coal to Gasifiers

Energy Technology Data Exchange (ETDEWEB)

Marasigan, Jose [Electric Power Research Institute, Inc., Palo Alto, CA (United States); Goldstein, Harvey [Electric Power Research Institute, Inc., Palo Alto, CA (United States); Dooher, John [Electric Power Research Institute, Inc., Palo Alto, CA (United States)

2013-09-30

This study investigates the practicality of using a liquid CO₂/coal slurry preparation and feed system for the E-Gas™ gasifier in an integrated gasification combined cycle (IGCC) electric power generation plant configuration. Liquid CO₂ has several property differences from water that make it attractive for the coal slurries used in coal gasification-based power plants. First, the viscosity of liquid CO₂ is much lower than water. This means it should take less energy to pump liquid CO₂ through a pipe compared to water. This also means that a higher solids concentration can be fed to the gasifier, which should decrease the heat requirement needed to vaporize the slurry. Second, the heat of vaporization of liquid CO₂ is about 80% lower than water. This means that less heat from the gasification reactions is needed to vaporize the slurry. This should result in less oxygen needed to achieve a given gasifier temperature. And third, the surface tension of liquid CO₂ is about 2 orders of magnitude lower than water, which should result in finer atomization of the liquid CO₂ slurry, faster reaction times between the oxygen and coal particles, and better carbon conversion at the same gasifier temperature. EPRI and others have recognized the potential that liquid CO₂ has in improving the performance of an IGCC plant and have previously conducted systemslevel analyses to evaluate this concept. These past studies have shown that a significant increase in IGCC performance can be achieved with liquid CO₂ over water with certain gasifiers. Although these previous analyses had produced some positive results, they were still based on various assumptions for liquid CO₂/coal slurry properties.

Coal conversion and aquatic environments: overview of impacts and strategies for monitoring. Environmental Sciences Division publication No. 1112

Energy Technology Data Exchange (ETDEWEB)

Roop, R. D.; Sanders, F. S.; Barnthouse, L. W.

1977-01-01

Impact assessment and environmental monitoring are difficult but crucial steps needed to ensure the environmentally safe development of coal conversion technologies. This paper summarizes strategies for impact assessment and monitoring developed at Oak Ridge National Laboratory for DOE's program to build demonstration facilities. Impacts on aquatic environments depend heavily on the abiotic and biotic characteristics of the site and details of facility design. Key issues include availability of water, use of ''zero-discharge'' designs, and methods of handling solid wastes. In monitoring programs emphasis is placed on (1) thorough use of existing data, (2) use of a synoptic reconnaissance survey, criteria for choosing parameters to be measured, and the search for ecologically meaningful, cost-effective methods.

Australian coal mine methane emissions mitigation potential using a Stirling engine-based CHP system

International Nuclear Information System (INIS)

Meybodi, Mehdi Aghaei; Behnia, Masud

2013-01-01

Methane, a major contributor to global warming, is a greenhouse gas emitted from coal mines. Abundance of coal mines and consequently a considerable amount of methane emission requires drastic measures to mitigate harmful effects of coal mining on the environment. One of the commonly adopted methods is to use emitted methane to fuel power generation systems; however, instability of fuel sources hinders the development of systems using conventional prime movers. To address this, application of Stirling engines may be considered. Here, we develop a techno-economic methodology for conducting an optimisation-based feasibility study on the application of Stirling engines as the prime movers of coal mine CHP systems from an economic and an environmental point of view. To examine the impact of environmental policies on the economics of the system, the two commonly implemented ones (i.e. a carbon tax and emissions trading scheme) are considered. The methodology was applied to a local coal mine. The results indicate that incorporating the modelled system not only leads to a substantial reduction in greenhouse gas emissions, but also to improved economics. Further, due to the heavy economic burden, the carbon tax scheme creates great incentive for coal mine industry to address the methane emissions. -- Highlights: •We study the application of Stirling engines in coal mine CHP systems. •We develop a thermo-economic approach based on the net present worth analysis. •We examine the impact of a carbon tax and ETS on the economics of the system. •The modeled system leads to a substantial reduction in greenhouse gas emissions. •Carbon tax provides a greater incentive to address the methane emissions

Slag processing system for direct coal-fired gas turbines

Science.gov (United States)

Pillsbury, Paul W.

1990-01-01

Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The gas turbine system includes a primary zone for burning coal in the presence of compressed air to produce hot combustion gases and debris, such as molten slag. The turbine system further includes a secondary combustion zone for the lean combustion of the hot combustion gases. The operation of the system is improved by the addition of a cyclone separator for removing debris from the hot combustion gases. The cyclone separator is disposed between the primary and secondary combustion zones and is in pressurized communication with these zones. In a novel aspect of the invention, the cyclone separator includes an integrally disposed impact separator for at least separating a portion of the molten slag from the hot combustion gases.

Characterization of substances in products, effluents, and wastes from coal conversion processes

International Nuclear Information System (INIS)

Petersen, M.R.

1978-01-01

Researchers at Pacific Northwest Laboratory (PNL) are investigating materials from synthetic fossil fuel processes. During the past year, samples have been collected from the Solvent Refining Coal Pilot Plant (SRC-I mode), Lignite Gasification Pilot Plant, Eyring Research Institute Gasifier, and Hanna III In Situ Coal Gasification Experiment. Inorganic and organic analyses have been performed, and comparisons of the data show some important differences in the potential emissions

System applications CRC -Biomass + Coal; Aplicaciones Sistema CRC-Biomasa+Carbon

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-07-01

Main object of Phase I of the project is to analyse the technical-economic feasibility of the combined use of biomass and coal for power generation in the Spanish region of Andalusia, by means of new medium-size independent power plants or using biomass as supplementary fuel in existing large coal power plants, including: -Analysis and classification of biomass and coal resources in the region -Technical-economic study of conventional alternatives using the steam cycle -Analysis of efficiency improvement provided by advanced Rankine-cycle technologies, like the SMR cycle -Analysis of alternatives based on parallel combined cycles using gas turbines, including advanced solutions, like the EAPI and CRC-EAPI systems. -Description and evaluation of different biomass drying systems. -Description and evaluation of the three main biomass gasification systems currently under development: atmospheric direct, atmospheric indirect and pressurized. Main objects of Phase II of the project are to analyse a specific application of the EAPI system to a real cogeneration plant project and to analyse the application of the CRC2 system to a commercial supercritical power plant, including technical-economic study of both applications. (Author)

A system to analyze the complex physiological states of coal solubilizing fungi

Energy Technology Data Exchange (ETDEWEB)

Hoelker, U.; Moenkemann, H.; Hoefer, M. [Universitaet Bonn, Bonn (Germany). Botanisches Institut

1997-11-01

The mechanism by which some microorganisms solubilize brown coal is still unknown. The paper discusses the deuteromycetes Fusarium oxysporum and Trichoderma atroviride as a suitable test system to analyse the complex fungal physiology relating to coal solubilization. The two fungi can occur in two different growth substrate-controlled physiological states: a coal-solubilizing one, when cells are grown on glutamate or gluconate as substrate and a non-solubilizing one, when grown on carbohydrates. When grown on carbohydrates, F.oxysporum produces the pigment bikaverein. Purified bikaverein inhibits also coal solubilization by T. atroviride. The ability to solubilize coal is constitutive in F. oxysporum, while in T. atroviride, it has to be induced. 10 refs., 3 figs., 3 tabs.

USGS compilation of geographic information system (GIS) data of coal mines and coal-bearing areas in Mongolia

Science.gov (United States)

Trippi, Michael H.; Belkin, Harvey E.

2015-09-10

Geographic information system (GIS) information may facilitate energy studies, which in turn provide input for energy policy decisions. The U.S. Geological Survey (USGS) has compiled GIS data representing coal mines, deposits (including those with and without coal mines), occurrences, areas, basins, and provinces of Mongolia as of 2009. These data are now available for download, and may be used in a GIS for a variety of energy resource and environmental studies of Mongolia. Chemical data for 37 coal samples from a previous USGS study of Mongolia (Tewalt and others, 2010) are included in a downloadable GIS point shapefile and shown on the map of Mongolia. A brief report summarizes the methodology used for creation of the shapefiles and the chemical analyses run on the samples.

Monetization of Nigeria coal by conversion to hydrocarbon fuels through Fischer-Tropsch process

Energy Technology Data Exchange (ETDEWEB)

Oguejiofor, G.C. [Nnamdi Azikiwe University, Awka (Nigeria). Dept. of Chemical Engineering

2008-07-01

Given the instability of crude oil prices and the disruptions in crude oil supply chains, this article offers a complementing investment proposal through diversification of Nigeria's energy source and dependence. Therefore, the following issues were examined and reported: A comparative survey of coal and hydrocarbon reserve bases in Nigeria was undertaken and presented. An excursion into the economic, environmental, and technological justifications for the proposed diversification and roll-back to coal-based resource was also undertaken and presented. The technology available for coal beneficiation for environmental pollution control was reviewed and reported. The Fischer-Tropsch synthesis and its advances into Sasol's slurry phase distillate process were reviewed. Specifically, the adoption of Sasol's advanced synthol process and the slurry phase distillate process were recommended as ways of processing the products of coal gasification. The article concludes by discussing all the above-mentioned issues with regard to value addition as a means of wealth creation and investment.

Seca Coal-Based Systems Program

International Nuclear Information System (INIS)

Alinger, Matthew

2008-01-01

This report summarizes the progress made during the August 1, 2006 - May 31, 2008 award period under Cooperative Agreement DE-FC26-05NT42614 for the U. S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled 'SECA Coal Based Systems'. The initial overall objective of this program was to design, develop, and demonstrate multi-MW integrated gasification fuel cell (IGFC) power plants with >50% overall efficiency from coal (HHV) to AC power. The focus of the program was to develop low-cost, high performance, modular solid oxide fuel cell (SOFC) technology to support coal gas IGFC power systems. After a detailed GE internal review of the SOFC technology, the program was de-scoped at GE's request. The primary objective of this program was then focused on developing a performance degradation mitigation path for high performing, cost-effective solid oxide fuel cells (SOFCs). There were two initial major objectives in this program. These were: (1) Develop and optimize a design of a >100 MWe integrated gasification fuel cell (IGFC) power plant; (2) Resolve identified barrier issues concerning the long-term economic performance of SOFC. The program focused on designing and cost estimating the IGFC system and resolving technical and economic barrier issues relating to SOFC. In doing so, manufacturing options for SOFC cells were evaluated, options for constructing stacks based upon various cell configurations identified, and key performance characteristics were identified. Key factors affecting SOFC performance degradation for cells in contact with metallic interconnects were be studied and a fundamental understanding of associated mechanisms was developed using a fixed materials set. Experiments and modeling were carried out to identify key processes/steps affecting cell performance degradation under SOFC operating conditions. Interfacial microstructural and elemental changes were characterized, and their relationships to observed degradation

Applying Rock Engineering Systems (RES approach to Evaluate and Classify the Coal Spontaneous Combustion Potential in Eastern Alborz Coal Mines

Directory of Open Access Journals (Sweden)

Amir Saffari

2013-12-01

Full Text Available Subject analysis of the potential of spontaneous combustion in coal layers with analytical and numerical methods has been always considered as a difficult task because of the complexity of the coal behavior and the number of factors influencing it. Empirical methods, due to accounting for certain and specific factors, have not accuracy and efficiency for all positions. The Rock Engineering Systems (RES approach as a systematic method for analyzing and classifying is proposed in engineering projects. The present study is concerned with employing the RES approach to categorize coal spontaneous combustion in coal regions. Using this approach, the interaction of parameters affecting each other in an equal scale on the coal spontaneous combustion was evaluated. The Intrinsic, geological and mining characteristics of coal seams were studied in order to identifying important parameters. Then, the main stages of implementation of the RES method i.e. interaction matrix formation, coding matrix and forming a list category were performed. Later, an index of Coal Spontaneous Combustion Potential (CSCPi was determined to format the mathematical equation. Then, the obtained data related to the intrinsic, geological and mining, and special index were calculated for each layer in the case study (Pashkalat coal region, Iran. So, the study offers a perfect and comprehensive classification of the layers. Finally, by using the event of spontaneous combustion occurred in Pashkalat coal region, an initial validation for this systematic approach in the study area was conducted, which suggested relatively good concordance in Pashkalat coal region.

Fiscal 1996 survey report on the environmentally friendly type coal utilization system feasibility study. Feasibility study of the environmentally friendly type coal utilization system in Malaysia and Vietnam; Kankyo chowagata sekitan riyo system kanosei chosa. Malaysia Vietnam ni okeru kankyo chowagata sekitan riyo system kanosei chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-03-01

This survey arranged the status of coal utilization technology and the status of coal production, supply, etc. in Malaysia and Vietnam, examined/studied coal utilization systems in both countries, and finally assessed feasibility of introducing the environmentally friendly type coal utilization system. As a country of primary energy source which is abundant in crude oil, natural gas, hydroelectric power, coal, etc., Malaysia now depends on crude oil and natural gas for 80% of its energy, and places emphasis on exploration of natural gas and oil refining. In electric power and cement industries where coal is consumed, effectiveness and environmental issues in association with coal utilization are future subjects. In Vietnam, the north is abundant in hydroelectric power and anthracite, and the south in oil and gas resource, but the north and central districts are in a state of undevelopment. Coal is used for coal thermal power generation, cement industry, and residential/commercial fuel. In the future, effective coal utilization and environmental issues will be subjects. 16 refs., 38 figs., 75 tabs.

Coal/Polymer Coprocessing with Efficient Use of Hydrogen.

Energy Technology Data Exchange (ETDEWEB)

Broadbelt, L.J.

1997-08-31

The objective of the current research is to investigate the feasibility of coprocessing coal with waste polymers, with particular interest in employing the polymers as an alternate hydrogen source for coal upgrading and simultaneously recovering high valued fuels and chemicals from plastic waste. A chemical modeling approach was employed in which real and model feedstocks were used to identify the underlying reaction pathways, kinetics, and mechanisms controlling coal liquefaction in the presence of plastics and catalysts. Simple model systems were employed to facilitate product analysis and obtain information about the intrinsic reactivity. When reacted in binary mixtures, the conversion of tetradecane, a model compound of polyethylene, increased while the selectivities to primary products of 4-(naphthylmethyl) bibenzyl were enhanced. Experiments in the last six months in which the relative concentrations of the components were varied revealed that the effect was indeed a chemical one and not simply a result of dilution. An experimental protocol was developed to conduct experiments at elevated pressures more representative of coal liquefaction conditions. Preliminary experiments with real feedstocks allowed the extrinsic factors (i.e., diffusion limitations, solvent effects) to be identified. The combination of these two sets of experiments will ultimately be used to carry out process optimization and formulate strategies for catalyst development.

76 FR 63238 - Proximity Detection Systems for Continuous Mining Machines in Underground Coal Mines

Science.gov (United States)

2011-10-12

... Detection Systems for Continuous Mining Machines in Underground Coal Mines AGENCY: Mine Safety and Health... Agency's proposed rule addressing Proximity Detection Systems for Continuous Mining Machines in... proposed rule for Proximity Detection Systems on Continuous Mining Machines in Underground Coal Mines. Due...

76 FR 54163 - Proximity Detection Systems for Continuous Mining Machines in Underground Coal Mines

Science.gov (United States)

2011-08-31

... Detection Systems for Continuous Mining Machines in Underground Coal Mines AGENCY: Mine Safety and Health... (except full-face continuous mining machines) with proximity detection systems. Miners working near..., each underground coal mine operator would be required to install proximity detection systems on...

Determining phenols in coal conversion products by nuclear magnetic resonance

Energy Technology Data Exchange (ETDEWEB)

Kanitskaya, L.V.; Kushnarev, D.F.; Polonov, V.M.; Kalabin, G.A.

1985-03-01

Possibility of using nuclear magnetic resonance spectra of the hydrogen 1 (/sup 1/H) isotope for a qualitative and quantitative evaluation of the hydroxyl groups in the products of coal processing is investigated. The basis of the method is the fact that in NMR spectra of the /sup 1/H in organic compounds with acid protons, the latter are unprotected when strong bases are used as solvents because of intermolecular hydrogen bonds. The resin from the medium-temperature semicoking of Cheremkhovskii coals, its hydrogenate, and phenol fraction of the hydrogenate were used for the investigation. The results were compared with the results of other NMR spectroscopy methods. The high solubility of hexamethanol and the fact that the products can be analyzed in the natural state, are some advantages of the method. 18 references.

A study on the hydrotreating of coal hydro liquefaction residue and its kinetics

Energy Technology Data Exchange (ETDEWEB)

Huang, J.; Lu, X.; Zhang, D.; Gao, J. [Department of Chemical Engineering for Energy Resources, East China University of Science and Technology, Shanghai (China)

2010-09-15

Hydro-conversion of coal hydro liquefaction residue obtained from a 6 t/day pilot plant of Shenhua Group in Shanghai was carried out under the hydrotreating condition. The coal hydro liquefaction residue and its product were extracted in sequence with n-hexane, toluene and tetrahydrofuran in a Soxhlet apparatus. The n-hexane soluble fractions increased with the increase of reaction temperature and time. Its amount increased from 14.14% to a maximum of 40.86% under the conditions of 470 {sup o}C and 30 min, which meant that moderate extension of coal residence time in the coal hydro liquefaction reactor is beneficial to the increase of oil yield. A 4-lumped kinetic model of coal hydro liquefaction residue hydro-conversion was performed using solubility-based lumped fractions. In the model, the tetrahydrofuran insoluble fractions were classified into two parts: easily reactive part and unreactive part. The kinetic parameters were estimated by a fourth-order Runge-Kutta method and a nonlinear least squares method, and the apparent activation energies were calculated according to the Arrhenius Equation. A large quantity of total catalyst consisting of remained liquefaction catalyst, part of the mineral from raw coal and additive Fe-based catalyst could considerably reduce the apparent activation energy of hydro-conversion for the toluene insoluble/tetrahydrofuran insoluble fractions to 36.79 kJ-mol{sup -1}. The calculated values of the model coincided well with the experimental values. (authors)

Deuterium as a tracer in coal liquefaction. Pt. 1

International Nuclear Information System (INIS)

Wilson, M.A.; Collin, P.J.; Barron, P.F.; Vassallo, A.M.

1982-01-01

Deuterium has been used to trace the pathways by which hydrogen reacts with an Australian bituminous coal (Liddell) in the presence of a nickel/molybdenum catalyst. The results show that at 400 0 C extensive scrambling of hydrogen and deuterium occurs among aromatic and α to aromatic aliphatic hydrogen and deuterium substituents. Deuterium can enter all structural groups in both asphaltene and hexane-soluble fractions of the coal-derived liquids, but it enters aromatic and α to aromatic groups in preference to alkyl groups remote from aromatic rings. Thus the results indicate that hydrogen atoms are very mobile during coal hydrogenation. Deuterium from deuterium oxide generated during conversion can also be incorporated into the coal-derived liquids. During coal hydrogenation, the eventual fate of much of the hydrogen in the gas phase is to substitute for hydrogen already in the coal. (Auth.)

Influence of reaction parameters on brown coal-polyolefinic plastic co-pyrolysis behavior

Energy Technology Data Exchange (ETDEWEB)

Sharypov, V.I.; Beregovtsova, N.G.; Kuznetsov, B.N. [Institute of Chemistry and Chemical Technology SB RAS, K.Marx Str. 42, 660049 Krasnoyarsk (Russian Federation); Cebolla, V.L. [Instituto de Carboquimica, CSIC, Miguel Luesma, 4, 50015 Zaragoza (Spain); Collura, S.; Finqueneisel, G.; Zimny, T.; Weber, J.V. [Laboratoire de Chimie et Applications, Universite de Metz, rue V.Demange, 57500 Saint-Avold (France)

2007-03-15

Co-processing of polyolefinic polymers with Kansk-Achinsk (Russia) brown coal was investigated by thermogravimetry (TG) and autoclave pyrolysis under argon and hydrogen pressure in catalytic conditions (or not). Gas chromatography-mass spectrometry (GC-MS) and high performance thin layer chromatography (HPTLC) were used to analyze the distillate products. Some synergistic effects indicate chemical interaction between the products of thermal decomposition of coal and plastic. In co-pyrolysis under H{sub 2} a significant increasing of coal conversion degree as a function of polymer amount in feedstock was found. Simultaneously the coal promoted formation of distillate products from polymers. Some alkyl aromatic and O-containing substances were detected in co-pyrolysis fraction boiling in the range 180-350 C, indicating interactions between coal and plastic. Iron containing ore materials, modified by mechanochemical treatment, demonstrated a catalytic activity in hydropyrolysis process. In catalytic conditions, increases of the mixtures conversion degree by 9-13 wt.%, of distillate fraction yields by 1.2-1.6 times and a decrease of olefins and polycyclic components were observed. (author)

Cooperative research in coal liquefaction. Final report, May 1, 1990-- April 30, 1991

Energy Technology Data Exchange (ETDEWEB)

Huffman, G.P. [ed.

1992-02-15

The Consortium for Fossil Fuel Liquefaction Science (CFFLS) is currently engaged in a three year contract with the US Department of Energy investigating a range of research topics dealing with direct coal liquefaction. This report summarizes the results of this program in its second year, from May 1, 1990 to April 30, 1991. Accomplishments for this period are presented for the following tasks: Iron-based catalysts for coal liquefaction, exploratory research on coal conversion, novel coal liquefaction concepts, and novel catalysts for coal liquefaction.

Overview of fuel conversion

International Nuclear Information System (INIS)

Green, A.E.S.

1991-01-01

The conversion of solid fuels to cleaner-burning and more user-friendly solid liquid or gaseous fuels spans many technologies. In this paper, the authors consider coal, residual oil, oil shale, tar sends tires, municipal oil waste and biomass as feedstocks and examine the processes which can be used in the production of synthetic fuels for the transportation sector. The products of mechanical processing to potentially usable fuels include coal slurries, micronized coal, solvent refined coal, vegetable oil and powdered biomall. The thermochemical and biochemical processes considered include high temperature carbide production, liquefaction, gasification, pyrolysis, hydrolysis-fermentation and anaerobic digestion. The products include syngas, synthetic natural gas, methanol, ethanol and other hydrocarbon oxygenates synthetic gasoline and diesel and jet engine oils. The authors discuss technical and economic aspects of synthetic fuel production giving particular attention and literature references to technologies not discussed in the five chapters which follow. Finally the authors discuss economic energy, and environmental aspects of synthetic fuels and their relationship to the price of imported oil

Fiscal 1997 feasibility survey of an environment friendly type coal utilization system. Feasibility survey of the environment friendly type coal utilization system in Malaysia and Vietnam (case of Vietnam); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Malaysia oyobi Vietnam ni okeru kankyo chowagata sekitan riyo system kanosei chosa (Vietnam ban))

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

The paper grasped the state of coal utilization by coal consumption field, the state of coal physical flow in Vietnam, etc., surveyed/studied a possibility of introducing the environment friendly type coal utilization system, and assessed the possibility. As to energy resources, the north is abundant in hydroelectric and coal (mainly anthracite) resources, and the south in oil and natural gas resources. Coal production in fiscal 1997 is planned to be 10 million tons. Coal preparation technique presently available is only grain size sieving. Accordingly, it is necessary to study for heightening efficiency of facilities and modernizing facilities in accordance with the introduction of the environment friendly type coal utilization technology. During the study, it is possible to propose improvement on coal processing technology (coal preparation technology). Assessment and study are made especially of the coal selection system, fine coal recovery system and waste water treatment system. For the plan on new coal-fired power plants (300MWtimes4), there is left much necessity of proposing studying models considered of the anthracite combustion technology and environmental improvement and of assessing/studying them. 60 figs., 117 tabs.

Clean Coal Technologies in China: Current Status and Future Perspectives

Directory of Open Access Journals (Sweden)

Shiyan Chang

2016-12-01

Full Text Available Coal is the dominant primary energy source in China and the major source of greenhouse gases and air pollutants. To facilitate the use of coal in an environmentally satisfactory and economically viable way, clean coal technologies (CCTs are necessary. This paper presents a review of recent research and development of four kinds of CCTs: coal power generation; coal conversion; pollution control; and carbon capture, utilization, and storage. It also outlines future perspectives on directions for technology research and development (R&D. This review shows that China has made remarkable progress in the R&D of CCTs, and that a number of CCTs have now entered into the commercialization stage.

Capital cost: high and low sulfur coal plants-1200 MWe. [High sulfur coal

Energy Technology Data Exchange (ETDEWEB)

1977-01-01

This Commercial Electric Power Cost Study for 1200 MWe (Nominal) high and low sulfur coal plants consists of three volumes. The high sulfur coal plant is described in Volumes I and II, while Volume III describes the low sulfur coal plant. The design basis and cost estimate for the 1232 MWe high sulfur coal plant is presented in Volume I, and the drawings, equipment list and site description are contained in Volume II. The reference design includes a lime flue gas desulfurization system. A regenerative sulfur dioxide removal system using magnesium oxide is also presented as an alternate in Section 7 Volume II. The design basis, drawings and summary cost estimate for a 1243 MWe low sulfur coal plant are presented in Volume III. This information was developed by redesigning the high sulfur coal plant for burning low sulfur sub-bituminous coal. These coal plants utilize a mechanical draft (wet) cooling tower system for condenser heat removal. Costs of alternate cooling systems are provided in Report No. 7 in this series of studies of costs of commercial electrical power plants.

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES; FINAL

International Nuclear Information System (INIS)

Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

2001-01-01

The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO(sub x)). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process

Clean coal technologies

International Nuclear Information System (INIS)

Aslanyan, G.S.

1993-01-01

According to the World Energy Council (WEC), at the beginning of the next century three main energy sources - coal, nuclear power and oil will have equal share in the world's total energy supply. This forecast is also valid for the USSR which possesses more than 40% of the world's coal resources and continuously increases its coal production (more than 700 million tons of coal are processed annually in the USSR). The stringent environmental regulations, coupled with the tendency to increase the use of coal are the reasons for developing different concepts for clean coal utilization. In this paper, the potential efficiency and environmental performance of different clean coal production cycles are considered, including technologies for coal clean-up at the pre-combustion stage, advanced clean combustion methods and flue gas cleaning systems. Integrated systems, such as combined gas-steam cycle and the pressurized fluidized bed boiler combined cycle, are also discussed. The Soviet National R and D program is studying new methods for coal utilization with high environmental performance. In this context, some basic research activities in the field of clean coal technology in the USSR are considered. Development of an efficient vortex combustor, a pressurized fluidized bed gasifier, advanced gas cleaning methods based on E-beam irradiation and plasma discharge, as well as new catalytic system, are are presented. In addition, implementation of technological innovations for retrofitting and re powering of existing power plants is discussed. (author)

Dispatcher's monitoring systems of coal preparation processes. Systemy dyspozytorskiej kontroli procesow wzbogacania wegla

Energy Technology Data Exchange (ETDEWEB)

Cierpisz, S [Politechnika Slaska, Gliwice (Poland); Cierpisz, T; Glowacki, D; Puczylowski, T [Min-Tech Sp. z o.o., Katowice (Poland)

1994-08-01

The computer-based control and dispatcher's monitoring systems for coal preparation plants are described. The article refers to the local automation systems of coal blending production, control systems of heavy media separation process and dispatcher's visualization systems of technological lines operation. The effects of implementation of the above mentioned systems as well as some experiences gained at the designing and operational stages are given. (author). 2 refs., 6 figs.

CoalVal-A coal resource valuation program

Science.gov (United States)

Rohrbacher, Timothy J.; McIntosh, Gary E.

2010-01-01

CoalVal is a menu-driven Windows program that produces cost-of-mining analyses of mine-modeled coal resources. Geological modeling of the coal beds and some degree of mine planning, from basic prefeasibility to advanced, must already have been performed before this program can be used. United States Geological Survey mine planning is done from a very basic, prefeasibility standpoint, but the accuracy of CoalVal's output is a reflection of the accuracy of the data entered, both for mine costs and mine planning. The mining cost analysis is done by using mine cost models designed for the commonly employed, surface and underground mining methods utilized in the United States. CoalVal requires a Microsoft Windows? 98 or Windows? XP operating system and a minimum of 1 gigabyte of random access memory to perform operations. It will not operate on Microsoft Vista?, Windows? 7, or Macintosh? operating systems. The program will summarize the evaluation of an unlimited number of coal seams, haulage zones, tax entities, or other area delineations for a given coal property, coalfield, or basin. When the reader opens the CoalVal publication from the USGS website, options are provided to download the CoalVal publication manual and the CoalVal Program. The CoalVal report is divided into five specific areas relevant to the development and use of the CoalVal program: 1. Introduction to CoalVal Assumptions and Concepts. 2. Mine Model Assumption Details (appendix A). 3. CoalVal Project Tutorial (appendix B). 4. Program Description (appendix C). 5. Mine Model and Discounted Cash Flow Formulas (appendix D). The tutorial explains how to enter coal resource and quality data by mining method; program default values for production, operating, and cost variables; and ones own operating and cost variables into the program. Generated summary reports list the volume of resource in short tons available for mining, recoverable short tons by mining method; the seam or property being mined

Lance for injecting highly-loaded coal slurries into the blast furnace

Energy Technology Data Exchange (ETDEWEB)

Illuminati, D.

1991-10-29

A lance is used to inject fuel oil into a blast furnace. This simple design permits conversion of coal water and coal tar slurries to a fine mist at very low flow rates. This design prevents the build-up of deposits which increases service life and steadies the flow rate.

Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

Energy Technology Data Exchange (ETDEWEB)

1986-12-01

Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

Study on coal mine macro, meso and micro safety management system

Directory of Open Access Journals (Sweden)

Longkang Wang

2016-03-01

Full Text Available In recent years, the coal mine safety production situation in our country improved year by year, but severe accidents still occurred; the accidents caused great economic loss to the national economy. According to statistical analysis, almost all of the coal mine accidents will expose the hidden danger in before, most of the accidents caused due to safety management not reaching the designated position and the hidden danger management does not take any decision in time. Based on the coal mine safety management holes in our country, the coal mine macro, meso and micro safety management system was established in this paper, which includes meaning and conception of the theories of the macro, meso and micro safety management, and also includes the matching hardware equipment, in order to achieve the hidden danger's closed-loop control and dynamic early warning in the process of coal mine production.

STUDY OF SOLVENT AND CATALYST INTERACTIONS IN DIRECT COAL LIQUEFACTION; SEMIANNUAL

International Nuclear Information System (INIS)

Michael T. Klein

2000-01-01

There are several aspects of the Direct Coal Liquefaction process which are not fully understood and which if better understood might lead to improved yields and conversions. Among these questions are the roles of the catalyst and the solvent. While the solvent is known to act by transfer of hydrogen atoms to the free radicals formed by thermal breakdown of the coal in an uncatalyzed system, in the presence of a solid catalyst as is now currently practiced, the yields and conversions are higher than in an uncatalyzed system. The role of the catalyst in this case is not completely understood. DOE has funded many projects to produce ultrafine and more active catalysts in the expectation that better contact between catalyst and coal might result. This approach has met with limited success probably because mass transfer between two solids in a fluid medium i.e. the catalyst and the coal, is very poor. It is to develop an understanding of the role of the catalyst and solvent in Direct Liquefaction that this project was initiated. Specifically it was of interest to know whether direct contact between the coal and the catalyst was important. By separating the solid catalyst in a stainless steel basket permeable to the solvent but not the coal in the liquefaction reactor, it was shown that the catalyst still maintains a catalytic effect on the liquefaction process. There is apparently transfer of hydrogen atoms from the catalyst through the basket wall to the coal via the solvent. Strong hydrogen donor solvents appear to be more effective in this respect than weak hydrogen donors. It therefore appears that intimate contact between catalyst and coal is not a requirement, and that the role of the catalyst may be to restore the hydrogen donor strength to the solvent as the reaction proceeds. A range of solvents of varying hydrogen donor strength was investigated. Because of the extensive use of thermogravimetric analysis in this laboratory in was noted that the peak

Prospects for coal: technical developments

Energy Technology Data Exchange (ETDEWEB)

Kaye, W G; Peirce, T J

1983-07-01

This article summarises the reasons for predicting an increase in the use of coal as an industrial energy source in the United Kingdom. The development of efficient and reliable coal-burning techniques is therefore of great importance. Various techniques are then discussed, including conventional combustion systems, fluidised bed combustion systems, fluidised bed boilers and furnaces, coal and ash handling, coal-liquid mixtures, coal gasification and coal liquefaction. (4 refs.)

Product Characterization for Entrained Flow Coal/Biomass Co-Gasification

Energy Technology Data Exchange (ETDEWEB)

Maghzi, Shawn; Subramanian, Ramanathan; Rizeq, George; Singh, Surinder; McDermott, John; Eiteneer, Boris; Ladd, David; Vazquez, Arturo; Anderson, Denise; Bates, Noel

2011-09-30

The U.S. Department of Energy‘s National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GE‘s bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation, and

Product Characterization for Entrained Flow Coal/Biomass Co-Gasification

Energy Technology Data Exchange (ETDEWEB)

Maghzi, Shawn [General Electric Global Research, Niskayuna, NY (United States); Subramanian, Ramanathan [General Electric Global Research, Niskayuna, NY (United States); Rizeq, George [General Electric Global Research, Niskayuna, NY (United States); Singh, Surinder [General Electric Global Research, Niskayuna, NY (United States); McDermott, John [General Electric Global Research, Niskayuna, NY (United States); Eiteneer, Boris [General Electric Global Research, Niskayuna, NY (United States); Ladd, David [General Electric Global Research, Niskayuna, NY (United States); Vazquez, Arturo [General Electric Global Research, Niskayuna, NY (United States); Anderson, Denise [General Electric Global Research, Niskayuna, NY (United States); Bates, Noel [General Electric Global Research, Niskayuna, NY (United States)

2011-12-11

The U.S. Department of Energy's National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GE's bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation

Renewable energy systems advanced conversion technologies and applications

CERN Document Server

Luo, Fang Lin

2012-01-01

Energy conversion techniques are key in power electronics and even more so in renewable energy source systems, which require a large number of converters. Renewable Energy Systems: Advanced Conversion Technologies and Applications describes advanced conversion technologies and provides design examples of converters and inverters for renewable energy systems-including wind turbine and solar panel energy systems. Learn Cutting-Edge Techniques for Converters and Inverters Setting the scene, the book begins with a review of the basics of astronomy and Earth physics. It then systematically introduc

Converting coal

Energy Technology Data Exchange (ETDEWEB)

Avigliano, A. [Bedeschi (Italy)

2006-10-15

In September 2005, Bedeschi was commissioned to design and supply a coal unloading, conveying and storage facility for a new raw coal line system within Hatien II Cement Co. The new plant is composed of a grab unloader, a conveyor system, a storage shed with stacking and reclaiming facilities, a complete dedusting system and civil and steel structure engineering. The scope of supply includes a local fabrication portion; however, main components will be imported. The project will be completed in 21 months. The paper looks into the mechanics of loading and unloading coal. 4 figs., 4 photos.

Hydropyrolysis of coal at very low pressure

Energy Technology Data Exchange (ETDEWEB)

Bi, J.; Kamo, T.; Kodera, Y.; Yamaguchi, H.; Sato, Y. [National Institute for Resources and Environment, Tsukuba-city (Japan). Energy Resources Department

1998-07-01

In the present study, Taiheiyo coal was heated under a pressure of 0.6 Torr and a temperature range of 20-800{degree}C in the presence and absence of hydrogen atoms. The yielded char, gas and liquid were measured and analyzed by TG-MS and GC-MS respectively. The result shows that the conversion of coal with hydrogen atoms is higher than that without, and more gas and liquid products are obtained in the presence of hydrogen atoms. 3 refs., 5 figs.

Role of iron catalyst impregnated by solvent swelling method in pyrolytic removal of coal nitrogen

Energy Technology Data Exchange (ETDEWEB)

Hayashi, J.; Kusakabe, K.; Morooka, S.; Nielsen, M.; Furimsky, E. [Kyushu University, Fukuoka (Japan). Dept. of Chemical Science and Technology

1995-11-01

Organometallic iron precursors, ferrocene and ferric acetate, were impregnated into Illinois No. 6 (IL), Wyoming (WY) and Yallourn (YL) coals by solvent swelling technique in THF, ethanol, and a THF/ethanol binary solvent. Then iron-impregnated coals were pyrolyzed in a flow of helium at atmospheric pressure in a fixed bed and a thermobalance. Conversion of coal nitrogen to N{sub 2} was 20, 38 and 30% respectively, for original IL, WY, and YL coals. Iron formed from both precursors lowered the onset temperature of N{sub 2} evolution by 20-100{degree}C. When ferrocene was impregnated in coals at a concentration of 1.7-1.8 wt% as Fe, nitrogen conversion was increased to 52, 71 and 68% for IL, WY and YL coals, respectively. Ferric acetate impregnated into IL coal from THF/ethanol solution increased the nitrogen conversion much more than that from ethanol solution. The expansion of microporous coal structure by the swelling was essential for better dispersion of the catalyst precursor. The evolution of HCN as well as NH{sub 3} was effectively suppressed above 600{degree}C by the presence of iron but not influenced significantly by combinations of catalyst precursors and solvents. The increase in N{sub 2} yield was compensated by the decrease in nitrogen emitted as HCN and NH{sub 3} and in tar and char. The increase in CO evolution from the iron-impregnated IL coal at 600-800{degree}C was explained by catalytic rearrangement of aromatic structure of char, accompanying the removal of nitrogen as N{sub 2}. In a range of 600-750{degree}C, the evolution of CO as well as N{sub 2} from the other coals increased remarkably with a significant decrease in CO{sub 2} gasification in char microproes. 32 refs., 9 figs., 3 tabs.

57Fe NGR studies on three-stage hydroliquefaction of coals

International Nuclear Information System (INIS)

Jamond, M.; Bacaud, R.; Bussiere, P.; Charcosset, H.; Nickel-Pepin-Donat, B.

1990-01-01

Iron Moessbauer spectroscopy has been performed on liquefaction residues of two different French coals. In a three-stage liquefaction of high volatile bituminous coal (Freyming), without an added catalyst, the coal pyrite is not entirely converted into pyrrhotites, whereas in the presence of an added catalyst, coal pyrite is totally transformed into more dispersed pyrrhotites than those from the sample without an added catalyst; furthermore, the whole added catalyst precursor is reduced into pyrrhotites. In the case of liquefaction of subbituminous coal (Gardanne), full conversion of coal pyrite into pyrrhotites (even without an added catalyst) occurs. In addition, in the presence of the added catalyst, besides pyrrhotites, FeS is evidenced. When molybdenum-iron oxide is added as a catalyst precursor, no mixed Fe-Mo phase is detected. (orig.)

Increasing flexibility of coal power plant by control system modifications

Directory of Open Access Journals (Sweden)

Marušić Ante

2016-01-01

Full Text Available Expanding implementation of intermittent renewable energy sources has already started to change the role of thermal power plants in energy systems across Europe. Traditionally base load plants are now forced to operate as peaking plants. A familiar transition in upcoming years is expected in Croatia and coal power plant operators are preparing accordingly. To evaluate cycling capabilities and control system operation for flexible operation of selected 210 MW coal plant, series of tests with different load gradients were performed and results were thoroughly analyzed. Two possible “bottlenecks” are identified, thermal stress in superheater header, and achievable ramping rate considering operational limitations of coal feeders, firing system and evaporator dynamics. Several unexpected readings were observed, usually caused by malfunctioning sensors and equipment, resulting in unexpected oscillations of superheated steam temperature. Based on superheater geometry and experimental data, maximal steam temperature gradient during ramping was evaluated. Since thermal stress was well inside the safety margins, the simulation model of the whole boiler was used to evaluate achievable ramping on electric side.

Study of catalytic effects of mineral matter level on coal reactivity

Energy Technology Data Exchange (ETDEWEB)

Mazzocco, Nestor J.; Klunder, Edgar B.; Krastman, Donald

1981-03-01

Coal liquefaction experiments using a 400-lb/day bubble-column reactor tested the catalytic effects of added mineral matter level on coal conversion, desulfurization, and distillate yields in continuous operation under recycle conditions, with specific emphasis on the use of a disposable pyrite catalyst indigenous to the feed coal. Western Kentucky No. 11 run-of-mine (ROM) and washed coals were used as feedstocks to determine the effects of levels of mineral matter, specifically iron compounds. Liquefaction reactivity as characterized by total distillate yield was lower for washed coal, which contained less mineral matter. Liquefaction reactivity was regained when pyrite concentrate was added as a disposable catalyst to the washed coal feed in sufficient quantity to match the feed iron concentration of the run-of-mine coal liquefaction test run.

Utilization of coal-water fuels in fire-tube boilers

International Nuclear Information System (INIS)

Sommer, T.M.; Melick, T.A.

1991-01-01

The Energy and Environmental Research Corporation (EER), in cooperation with the University of Alabama and Jim Walter Resources, has been awarded a DOE contract to retrofit an existing fire-tube boiler with a coal-water slurry firing system. Recognizing that combustion efficiency is the principle concern when firing slurry in fire-tube boilers, EER has focused the program on innovative approaches for improving carbon burnout without major modifications to the boiler. This paper reports on the program which consists of five tasks. Task 1 provides for the design and retrofit of the host boiler to fire coal-water slurry. Task 2 is a series of optimization tests that will determine the effects of adjustable parameters on boiler performance. Task 3 will perform about 1000 hours of proof-of-concept system tests. Task 4 will be a comprehensive review of the test data in order to evaluate the economics of slurry conversions. Task 5 will be the decommissioning of the test facility if required

HYDROKINETIC ENERGY CONVERSION SYSTEMS: PROSPECTS ...

African Journals Online (AJOL)

eobe

Hydrokinetic energy conversion systems utilize the kinetic energy of flowing water bodies with little or no head to generate ... generator. ... Its principle of operation is analogous to that of wind ..... Crisis-solar and wind power systems, 2009,.

Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Technical progress report, October 1995--December 1995

Energy Technology Data Exchange (ETDEWEB)

Song, C.; Cooke, W.S.; Schmidt, E.; Schobert, H.H.

1996-02-01

Coal liquefaction involves cleavage of methylene, dimethylene and ether bridges connecting polycyclic aromatic units and the reactions of various oxygen functional groups. Here in this quarterly, we report on the catalytic effects of several molybdenum-, cobalt-, and iron-containing compounds in the reactions of dibenzothiophene (DBT) with hydrogen under conditions related to coal liquefaction. The catalytic effects of several molybdenum-, cobalt-, and iron-containing compounds have been examined in the hydrogenation and hydrodesulfurization reactions of dibenzothiophene (DBT) under conditions related to coal liquefaction. The metal compounds are candidate catalyst precursors for direct coal liquefaction. The reactions were carried out in batch microautoclave reactors at 400{degrees}C for 30 minutes with 6.9 MPa (cold) hydrogen pressure, and tridecane solvent. A metal loading of 0.5 mol% resulted in low conversion and only hydrogenation. Addition of sulfur in 4:1 molar ratio led only to a minor increase in conversion and hydrodesulfurization. The use of a higher boiling solvent (octadecane vs. tridecane) was beneficial in providing increased conversion, hydrodesulfurization, and hydrogenation. An increase in metal compound loading to 36.2 mol% led to a dramatic increase in conversion, hydrodesulfurization, and hydrocracking. Molybdenum hexacarbonyl at 36 mol% loading, with added sulfur at 6:1 ratio and octadecane solvent, gave 100% conversion of dibenzothiophene to other products with 100% hydrodesulfurization. Ammonium tetrathiomolybdate and molybdenum(III) chloride are less active under similar conditions. A cobalt-molybdenum thiocubane complex gave unexpectedly low conversions. Iron and cobalt carbonyls also provided very low conversions, even with added sulfur.

A coal combine

Energy Technology Data Exchange (ETDEWEB)

Wlachovsky, I; Bartos, J

1980-02-15

A design is presented for a coal combine, equipped with two drum operational units, on whose both ends of the upper surface of the body, two coal saws are mounted with the help of a lever system. These saws, found in an operational position, form a gap in the block of the coal block, which is not embraced by the drum operational unit. The coal block, found between the gap and the support, falls down onto the longwall scraper conveyor. The lever system of each coal saw is controlled by two hydraulic jacks. One of the jacks is mounted vertically on the facial wall of the body of the combine and is used for the hoisting for the required height of the horizontal arm of the lever, reinforced by one end in the hinge on the body of the combine. On the ''free'' end of that lever, a coal saw is mounted in a hinge-like fashion and which is connected by the hydraulic jack to the horizontal arm of the lever system. This hydraulic jack is used for the clamping of the coal saw to the face.

Environmentally favourable electricity production using allothermal coal gasification in accordance with the MBG system

International Nuclear Information System (INIS)

Rost, M.; Heek, K.H. van; Knop, K.

1988-01-01

Combined gas- and steam turbine power plants with integrated coal gasification are an important foundation alone for the further development of coal processing. The basis of the development is a new allothermal coal gasification system in a fluidized bed, which has been developed from the long operating experience accumulated at a half-scale plant. In contrast with the concept adopted so far of combination with nuclear process heat, in the MGB system (M.A.N.-Bergbauforschung-Gaserzeugung) the reaction heat required for the gasification is obtained by burning part of the coal gas produced. The gasification in the fluidized bed occurs at temperatures of between 800 and 850 0 C within a pressure range of between 20 and 25 bar. The paper describes the integration of the MBG system into a 250 MW power plant as well as the state of development of allothermal coal gasification and test results from the half-scale experimental plant. The construction of a demonstration plant, which will be incorporated in the bypass of a bituminous coal-fired unit, is planned in order to prove the function of the gas generator. (orig.) [de

Coal anion structure and chemistry of coal alkylation. Fourth quarterly progress report, December 1, 1977--February 28, 1978. [Carbon atoms in butyl groups

Energy Technology Data Exchange (ETDEWEB)

Stock, L.M.

1978-01-01

Three research problems are in progress. First, work is progressing well concerning the methods appropriate for the reductive alkylation of Illinois No. 6 coal samples. We have investigated the influence of the leaving group on the conversion of the Illinois coal to a soluble material. We find that the n-butyl iodide is more effective than other n-butyl halides. Second, preliminary results have been obtained concerning the distribution of hydrogen and deuterium atoms in the reaction of Illinois No. 6 coal samples with perdeuteriotetralin at 400/sup 0/C. Third, the nuclear magnetic resonance spectra of appropriate model compounds with n-butyl groups have been tabulated for comparison with the spectroscopic results obtained from coal alkylation products. Fourth, the chromatographic procedures necessary for the separation of the coal samples are being developed.

America's Changing Energy Landscape - USGS National Coal Resources Data System Changes to National Energy Resources Data System.

Science.gov (United States)

East, J. A., II

2016-12-01

The U.S. Geological Survey's (USGS) Eastern Energy Resources Science Center (EERSC) has an ongoing project which has mapped coal chemistry and stratigraphy since 1977. Over the years, the USGS has collected various forms of coal data and archived that data into the National Coal Resources Data System (NCRDS) database. NCRDS is a repository that houses data from the major coal basins in the United States and includes information on location, seam thickness, coal rank, geologic age, geographic region, geologic province, coalfield, and characteristics of the coal or lithology for that data point. These data points can be linked to the US Coal Quality Database (COALQUAL) to include ultimate, proximate, major, minor and trace-element data. Although coal is an inexpensive energy provider, the United States has shifted away from coal usage recently and branched out into other forms of non-renewable and renewable energy because of environmental concerns. NCRDS's primary method of data capture has been USGS field work coupled with cooperative agreements with state geological agencies and universities doing coal-related research. These agreements are on competitive five-year cycles that have evolved into larger scope research efforts including solid fuel resources such as coal-bed methane, shale gas and oil. Recently these efforts have expanded to include environmental impacts of the use of fossil fuels, which has allowed the USGS to enter into agreements with states for the Geologic CO2 Storage Resources Assessment as required by the Energy Independence and Security Act. In 2016 they expanded into research areas to include geothermal, conventional and unconventional oil and gas. The NCRDS and COALQUAL databases are now online for the public to use, and are in the process of being updated to include new data for other energy resources. Along with this expansion of scope, the database name will change to the National Energy Resources Data System (NERDS) in FY 2017.

Wind energy conversion system

Science.gov (United States)

Longrigg, Paul

1987-01-01

The wind energy conversion system includes a wind machine having a propeller connected to a generator of electric power, the propeller rotating the generator in response to force of an incident wind. The generator converts the power of the wind to electric power for use by an electric load. Circuitry for varying the duty factor of the generator output power is connected between the generator and the load to thereby alter a loading of the generator and the propeller by the electric load. Wind speed is sensed electro-optically to provide data of wind speed upwind of the propeller, to thereby permit tip speed ratio circuitry to operate the power control circuitry and thereby optimize the tip speed ratio by varying the loading of the propeller. Accordingly, the efficiency of the wind energy conversion system is maximized.

Role of non-ferrous coal minerals and by-product metallic wastes in coal liquefaction. Technical progress report, September 1, 1980-November 30, 1980

Energy Technology Data Exchange (ETDEWEB)

Garg, D.; Givens, E.N.; Schweighardt, F.K.; Curtis, C.W.; Guin, J.A.; Shridharani, K.; Huang, W.J.

1981-02-01

The effects of minerals and inexpensive ores or by-products (pyrites, red mud, flue dust, speculites, zinc sulfides, calcium oxide, dolomites, mica, molybdenite) in catalysing coal liquefaction or the hydrogenation of process solvents was studied with different cokes and solvents. Improved results were obtained in several cokes and th results are given in terms of oil fields, hydrogen consumption, desulfurization of SRC, etc. The addition of pyrite resulted in increased production of oils and increased conversion of coal; however, the effects varied from coal to coal. Dolomite, mica and molybdenite had insignificant catalytic activity. The reduction of pyrite, Fe/sub 2/O/sub 3/ and Fe/sub 3/O/sub 4/ at process conditions was studied. (LTN)

Energy and environmental (JSR) research emphasizing low-rank coal

Energy Technology Data Exchange (ETDEWEB)

Sharp, L.L.

1994-12-01

The products of plastic thermal depolymerization can be used for the manufacture of new plastics or various other hydrocarbon-based products. One thermal depolymerization development effort is ongoing at the Energy & Environmental Research Center (EERC) of the University of North Dakota, under joint sponsorship of the American Plastics Council, the 3M corporation, and the Department of Energy. Thermal depolymerization process development began at the EERC with a benchscale program that ran from 9/92 to 6/93 (1). Testing was conducted in a 1-4-lb/hr continuous fluid-bed reactor (CFBR) unit using individual virgin resins and resin blends and was intended to determine rough operating parameters and product yields and to identify product stream components. Process variables examined included temperature and bed material, with a lesser emphasis on gas fluidization velocity and feed material mix. The following work was performed: (1) a short program to determine the suitability of using CaO in a postreactor, fixed bed for chlorine remediation, (2) thermal depolymerization of postconsumer plastics, and (3) testing of industrial (3M) products and wastes to determine their suitability as feed to a thermal depolymerization process. The involvement of DOE in the development of the plastics thermal depolymerization process has helped to facilitate the transfer of coal conversion technology to a new and growing technology area -- waste conversion. These two technology areas are complementary. The application of known coal conversion technology has accelerated the development of plastics conversion technology, and findings from the plastics depolymerization process development, such as the development of chlorine remediation techniques and procedures for measurement of organically associated chlorine, can be applied to new generations of coal conversion processes.

Novel Fuel Cells for Coal Based Systems

Energy Technology Data Exchange (ETDEWEB)

Thomas Tao

2011-12-31

The goal of this project was to acquire experimental data required to assess the feasibility of a Direct Coal power plant based upon an Electrochemical Looping (ECL) of Liquid Tin Anode Solid Oxide Fuel Cell (LTA-SOFC). The objective of Phase 1 was to experimentally characterize the interaction between the tin anode, coal fuel and cell component electrolyte, the fate of coal contaminants in a molten tin reactor (via chemistry) and their impact upon the YSZ electrolyte (via electrochemistry). The results of this work will provided the basis for further study in Phase 2. The objective of Phase 2 was to extend the study of coal impurities impact on fuel cell components other than electrolyte, more specifically to the anode current collector which is made of an electrically conducting ceramic jacket and broad based coal tin reduction. This work provided a basic proof-of-concept feasibility demonstration of the direct coal concept.

Tube bundle system: for monitoring of coal mine atmosphere.

Science.gov (United States)

Zipf, R Karl; Marchewka, W; Mohamed, K; Addis, J; Karnack, F

2013-05-01

A tube bundle system (TBS) is a mechanical system for continuously drawing gas samples through tubes from multiple monitoring points located in an underground coal mine. The gas samples are drawn via vacuum pump to the surface and are typically analyzed for oxygen, methane, carbon dioxide and carbon monoxide. Results of the gas analyses are displayed and recorded for further analysis. Trends in the composition of the mine atmosphere, such as increasing methane or carbon monoxide concentration, can be detected early, permitting rapid intervention that prevents problems, such as a potentially explosive atmosphere behind seals, fire or spontaneous combustion. TBS is a well-developed technology and has been used in coal mines around the world for more than 50 years. Most longwall coal mines in Australia deploy a TBS, usually with 30 to 40 monitoring points as part of their atmospheric monitoring. The primary uses of a TBS are detecting spontaneous combustion and maintaining sealed areas inert. The TBS might also provide mine atmosphere gas composition data after a catastrophe occurs in an underground mine, if the sampling tubes are not damaged. TBSs are not an alternative to statutory gas and ventilation airflow monitoring by electronic sensors or people; rather, they are an option to consider in an overall mine atmosphere monitoring strategy. This paper describes the hardware, software and operation of a TBS and presents one example of typical data from a longwall coal mine.

Temperature effects on chemical structure and motion in coal. Final report

Energy Technology Data Exchange (ETDEWEB)

Maciel, G.E.

1996-09-30

The objective of this project was to apply recently developed, state-of-the-art nuclear magnetic resonance (NMR) techniques to examine in situ changes in the chemical structure and molecular/macromolecular motion in coal as the temperature is increased above room temperature. Although alterations in the chemical structure of coal have been studied previously by {sup 13}C NMR, using quenched samples, the goal of this project was to examine these chemical structural changes, and changes in molecular/macromolecular mobility that may precede or accompany the chemical changes, at elevated temperatures, using modern {sup 13}C and {sup 1}H NMR techniques, especially {sup 1}H dipolar-dephasing techniques and related experiments pioneered in the laboratory for examining pyridine-saturated coals. This project consisted of the following four primary segments and related efforts on matters relevant to the first four tasks. (1) {sup 1}H NMR characterization of coal structure and mobility as a function of temperature variation over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (2) {sup 1}H NMR characterization of coal structure, mobility and conversion as a function of temperature variation over a temperature range (240--500 C) for which chemical transformations of coal are known to occur. (3) {sup 13}C NMR investigation of coal structure/mobility as a function of temperature over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (4) {sup 13}C NMR investigation of coal structure, dynamics and conversion as a function of temperature variation over a range (240--500 C) for which chemical transformations of coal are known to occur. (5) Related matters relevant to the first four tasks: (a) {sup 1}H CRAMPS NMR characterization of oil shales and their kerogen concentrates; and (b) improved quantitation in {sup 13}C MAS characterization of coals.

Molecular accessibility in solvent swelled coals. Final report

Energy Technology Data Exchange (ETDEWEB)

Kispert, L.D.

1994-04-01

The conversion of coal by an economically feasible catalytic method requires the catalyst to diffuse into the coal sample so that hydrogenation catalysis can occur from within as well as the normal surface catalysis. Thus an estimate of the size, shape, and reactivity, of the pores in the coal before and after the swelling with different solvents is needed so that an optimum sized catalyst will be used. This study characterizes the accessible area found in Argonne Premium Coal Samples (APCS) using a EPR spin probe technique. The properties deduced in this manner correlate well with the findings deduced from SANS, NMR, SEM, SAXS and light scattering measurements. The use of nitroxide spin probes with swelling solvents is a simple way in which to gain an understanding of the pore structure of coals, how it changes in the presence of swelling solvents and the chemistry that occurs at the pore wall. Hydrogen bonding sites occur primarily in low-rank coals and vary in reactive strength as rank is varied. Unswelled coals contain small, spherical pores which disappear when coal is swelled in the presence of polar solvents. Swelling studies of polystyrene-divinyl benzene copolymers implied that coal is polymeric, contains significant quantities of covalent cross-links and the covalent cross-link density increases with rank.

Fiscal 1997 for the upgrading of the Asia/Pacific coal development. Survey of the optimization of the coal transportation system in Indonesia; 1997 nendo Asia Taiheiyo sekitan kaihatsu kodoka chosa. Indonesia ni okeru sekitan yuso system saitekika chosa

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

The paper summarized the results of Phase 1 and Phase 2 surveys conducted based on `Agreement on the comprehensive survey of a coal transportation system in South Sumatra` concluded between NEDO and the Ministry of Mine and Energy in Indonesia. In addition to the data collection and site surveys made in Phase 1, conducted in Phase 2 were determination of sites for harbors, determination of a scenario on coal transportation from coal mines to harbors, optimization of the coal transportation system, social/economic assessment, and proposal on the optimum transportation system. The results of the simulation were as follows: It is the most advantageous to transport coal from coal deposit area to harbor by rail and from harbor to Paiton by barge weighed over 10,000 tons. Tanjung Api Api is the most advantageous as harbor. The production scale which is profitable became more than 15 million tons. The present coal price of PTBA is $25/t arriving Suralaya. The coal in this case is said to be 5500kcal/kg in quality, and the coal of the same quality to this is only profitable. 8 refs., 68 figs., 104 tabs.

Seca Coal-Based Systems Program

Energy Technology Data Exchange (ETDEWEB)

Matthew Alinger

2008-05-31

This report summarizes the progress made during the August 1, 2006 - May 31, 2008 award period under Cooperative Agreement DE-FC26-05NT42614 for the U. S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled 'SECA Coal Based Systems'. The initial overall objective of this program was to design, develop, and demonstrate multi-MW integrated gasification fuel cell (IGFC) power plants with >50% overall efficiency from coal (HHV) to AC power. The focus of the program was to develop low-cost, high performance, modular solid oxide fuel cell (SOFC) technology to support coal gas IGFC power systems. After a detailed GE internal review of the SOFC technology, the program was de-scoped at GE's request. The primary objective of this program was then focused on developing a performance degradation mitigation path for high performing, cost-effective solid oxide fuel cells (SOFCs). There were two initial major objectives in this program. These were: (1) Develop and optimize a design of a >100 MWe integrated gasification fuel cell (IGFC) power plant; (2) Resolve identified barrier issues concerning the long-term economic performance of SOFC. The program focused on designing and cost estimating the IGFC system and resolving technical and economic barrier issues relating to SOFC. In doing so, manufacturing options for SOFC cells were evaluated, options for constructing stacks based upon various cell configurations identified, and key performance characteristics were identified. Key factors affecting SOFC performance degradation for cells in contact with metallic interconnects were be studied and a fundamental understanding of associated mechanisms was developed using a fixed materials set. Experiments and modeling were carried out to identify key processes/steps affecting cell performance degradation under SOFC operating conditions. Interfacial microstructural and elemental changes were characterized, and their relationships to observed

Fiscal 1995 survey report on the environmentally friendly type coal utilization system joint demonstration project. Water-saving coal preparation system joint demonstration project; Kankyo chowagata sekitan riyo system kyodo jissho jigyo. Shosuigata sentan system kyodo jissho jigyo

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-03-01

This project makes demonstration of clean coal technology (CCT) in China and preparation for the base of its spread, controlled environmental pollution due to the coal use by the countries concerned, and contributes to stably secure energy of Japan. The paper made analog operation in the 1960s-1970s, supported by Russia and Poland, introduced two computer systems for operational control and quality control, densimeter, level meter, flow meter and analyzer to coal preparation plants having problems on productivity and quality control, made the optimum operational diagnosis for the plants, and at the same time, demonstrated the comprehensive rehabilitation type system by which water saving, high quality and high effectiveness are obtained. Various types of sensors such as rapid ash meter, scale and densitometer and computers are introduced to coal preparation plants which were recently constructed in China, have jig or heavy liquid cyclone as main preparation equipment and conducts operational control. There, the central control system was demonstrated in which various information collected in the central operation room and in-site equipment is combined by network for high-grade data processing and water saving is achieved. 50 figs., 11 tabs.

Transport fuels from two-stage coal liquefaction

Energy Technology Data Exchange (ETDEWEB)

Benito, A.; Cebolla, V.; Fernandez, I.; Martinez, M.T.; Miranda, J.L.; Oelert, H.; Prado, J.G. (Instituto de Carboquimica CSIC, Zaragoza (Spain))

1994-03-01

Four Spanish lignites and their vitrinite concentrates were evaluated for coal liquefaction. Correlationships between the content of vitrinite and conversion in direct liquefaction were observed for the lignites but not for the vitrinite concentrates. The most reactive of the four coals was processed in two-stage liquefaction at a higher scale. First-stage coal liquefaction was carried out in a continuous unit at Clausthal University at a temperature of 400[degree]C at 20 MPa hydrogen pressure and with anthracene oil as a solvent. The coal conversion obtained was 75.41% being 3.79% gases, 2.58% primary condensate and 69.04% heavy liquids. A hydroprocessing unit was built at the Instituto de Carboquimica for the second-stage coal liquefaction. Whole and deasphalted liquids from the first-stage liquefaction were processed at 450[degree]C and 10 MPa hydrogen pressure, with two commercial catalysts: Harshaw HT-400E (Co-Mo/Al[sub 2]O[sub 3]) and HT-500E (Ni-Mo/Al[sub 2]O[sub 3]). The effects of liquid hourly space velocity (LHSV), temperature, gas/liquid ratio and catalyst on the heteroatom liquids, and levels of 5 ppm of nitrogen and 52 ppm of sulphur were reached at 450[degree]C, 10 MPa hydrogen pressure, 0.08 kg H[sub 2]/kg feedstock and with Harshaw HT-500E catalyst. The liquids obtained were hydroprocessed again at 420[degree]C, 10 MPa hydrogen pressure and 0.06 kg H[sub 2]/kg feedstock to hydrogenate the aromatic structures. In these conditions, the aromaticity was reduced considerably, and 39% of naphthas and 35% of kerosene fractions were obtained. 18 refs., 4 figs., 4 tabs.

Digital coal mine integrated automation system based on Controlnet

Energy Technology Data Exchange (ETDEWEB)

Jin-yun Chen; Shen Zhang; Wei-ran Zuo [China University of Mining and Technology, Xuzhou (China). School of Chemical Engineering and Technology

2007-06-15

A three-layer model for digital communication in a mine is proposed. Two basic platforms are discussed: a uniform transmission network and a uniform data warehouse. An actual, ControlNet based, transmission network platform suitable for the Jining No.3 coal mine in China is presented. This network is an information superhighway intended to integrate all existing and new automation subsystems. Its standard interface can be used with future subsystems. The network, data structure and management decision-making all employ this uniform hardware and software. This effectively avoids the problems of system and information islands seen in traditional mine-automation systems. The construction of the network provides a stable foundation for digital communication in the Jining No.3 coal mine. 9 refs., 5 figs.

Thermodynamic analysis and conceptual design for partial coal gasification air preheating coal-fired combined cycle

Science.gov (United States)

Xu, Yue; Wu, Yining; Deng, Shimin; Wei, Shirang

2004-02-01

The partial coal gasification air pre-heating coal-fired combined cycle (PGACC) is a cleaning coal power system, which integrates the coal gasification technology, circulating fluidized bed technology, and combined cycle technology. It has high efficiency and simple construction, and is a new selection of the cleaning coal power systems. A thermodynamic analysis of the PGACC is carried out. The effects of coal gasifying rate, pre-heating air temperature, and coal gas temperature on the performances of the power system are studied. In order to repower the power plant rated 100 MW by using the PGACC, a conceptual design is suggested. The computational results show that the PGACC is feasible for modernizing the old steam power plants and building the new cleaning power plants.

Experience in a 6.2 MW{sub e} pressurized fluidized bed gasifier with high ash Indian coals

Energy Technology Data Exchange (ETDEWEB)

Viswanathan, G.; Rajasekaran, A.; Periyakaruppan, V.; Krishnamoorthy, S. [Bharat Heavy Electricals Ltd., Tiruchirappalli (India)

2006-07-01

Bharat Heavy Electrical Limited has installed a 165 tons/day air-blown pressurized fluidized bed gasifier (PFBG) as an add-on to their 6.2 MW IGCC demonstration plant and has operated it for more than 4000 hours. Improvements in the gasifier refractory lining, ash extraction and cooling devices, air distribution and temperature measuring devices were incorporated to improve the reliability and performance. Coal with 30-42% ash and high calorific value in the range of 15-20 MJ/kg was used during these operations with crushed coal of 1-4 mm as well as -6 mm coal with fines. Tests were conducted at gasifier pressure of 0.3-1.0 MPa, fluidized bed temperature of 980-1050{sup o}C and at various fluidized velocities and air to steam ratios. Once through carbon conversion efficiency of 90%, cold gas efficiency of 69% and dry gas calorific value of 4.4-4.6 MJ/Nm{sup 3} were obtained. About 15% char in fly ash (with 40% ash coal) was established by TGA. Seal pot system was added for recyling fly ash from the first cyclone to enhance carbon conversion, other parameters and to reduce the char in fly ash to acceptable level. Trends and correlations were established for constituents of gas, carbon conversion efficiency, cold gas efficiency, calorific value of gas and gas yield. BHEL is currently working with a partner to install a 125 MW IGCC plant. The paper elaborates the schematic and constructional details of the PFBG, operating experience and performance. 3 refs., 9 figs.

SECA Coal-Based Systems - FuelCell Energy, Inc.

Energy Technology Data Exchange (ETDEWEB)

Ayagh, Hossein [Fuelcell Energy, Inc., Danbury, CT (United States)

2014-01-31

The overall goal of this U.S. Department of Energy (DOE) sponsored project is the development of solid oxide fuel cell (SOFC) cell and stack technology suitable for use in highly-efficient, economically-competitive central generation power plant facilities fueled by coal synthesis gas (syngas). This program incorporates the following supporting objectives: • Reduce SOFC-based electrical power generation system cost to $700 or less (2007 dollars) for a greater than 100 MW Integrated Gasification Fuel Cell (IGFC) power plant, exclusive of coal gasification and CO₂ separation subsystem costs. • Achieve an overall IGFC power plant efficiency of at least 50%, from coal (higher heating value or HHV) to AC power (exclusive of CO₂ compression power requirement). • Reduce the release of CO2 to the environment in an IGFC power plant to no more than 10% of the carbon in the syngas. • Increase SOFC stack reliability to achieve a design life of greater than 40,000 hours. At the inception of the project, the efforts were focused on research, design and testing of prototype planar SOFC power generators for stationary applications. FuelCell Energy, Inc. successfully completed the initial stage of the project by meeting the program metrics, culminating in delivery and testing of a 3 kW system at National Energy Technology Laboratory (NETL). Subsequently, the project was re-aligned into a three phase effort with the main goal to develop SOFC technology for application in coal-fueled power plants with >90% carbon capture. Phase I of the Coal-based efforts focused on cell and stack size scale-up with concurrent enhancement of performance, life, cost, and manufacturing characteristics. Also in Phase I, design and analysis of the baseline (greater than 100 MW) power plant system—including concept identification, system definition, and cost analysis—was conducted. Phase II efforts focused on development of a ≥25 kW SOFC stack tower incorporating

Conceptual design of coal-fueled diesel system for stationary power applications

Energy Technology Data Exchange (ETDEWEB)

1989-05-01

A preliminary conceptual design of a coal-fueled diesel system was prepared as part of a previous systems study. Since then, our team has accumulated extensive results from testing coal-water slurry on the 13-inch bore JS engine (400 rpm) in 1987 and 1988. These results provided new insights into preferred design concepts for engine components. One objective, therefore, was to revise the preliminary design to incorporate these preferred design concepts. In addition there were certain areas where additional, more detailed analysis was required as a result of the previous conceptual design. Another objective, therefore was to perform additional detailed design efforts, such as: (1) market applications and engine sizes, (2) coal-water slurry cleaning and grinding processes, (3) emission controls and hot gas contaminant controls, (4) component durability, (5) cost and performance assessments. (VC)

FY1995 design of environment-friendly and generation-type conversion title of system for unused carbon resources by developing highly functional materials; 1995 nendo kokino zakryo kaihatsu ni yoru kankyo chowagata jisedai miriyo tanso shigen tenkan system no kochiku

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-03-01

Carbon resources such as coal, heavy oil, bitumen and so on are not suitable for the utilization as energy resources from the view-point of the global environment because those contain a great deal of heteroatoms, minerals and water. Therefore, the purpose of this project is to establish the environment-friendly and next generation-type conversion system for unused carbon resources by developing highly functional materials. This project aims at the following researches necessary to establish the conversion system for the unused carbon resources. (1) Development of technologies for pre-treating carbon resources (2) Development of recoverable hydrogenation catalysts capable of repeated use (3) Development of gasification catalysts active at low temperatures (4) Development of inorganic membranes for H{sub 2} or CO{sub 2} separation (5) Development of adsorption separation technologies in the supercritical phase (6) Development of highly active catalysts for CO hydrogenation Each development has been successfully completed and we have much prospect of establishing the conversion system for unused carbon resources. (NEDO)

REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

Energy Technology Data Exchange (ETDEWEB)

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2005-05-18

This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2005-11-17

This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Refinery Integration of By-Products from Coal-Derived Jet Fuels

Energy Technology Data Exchange (ETDEWEB)

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

2004-09-17

This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Characterisation of model compounds and a synthetic coal by TG/MS/FTIR to represent the pyrolysis behaviour of coal

Energy Technology Data Exchange (ETDEWEB)

Arenillas, A.; Pevida, C.; Rubiera, F.; Garcia, R.; Pis, J.J. [Instituto Nacional del Carbon, CSIC, Apartado 73, 33080 Oviedo (Spain)

2004-06-01

Coal pyrolysis is the initial, accompanying reaction of a number of coal conversion processes such as hydrogenation, combustion and gasification. However, because of the inherent complexity of coal composition, it is difficult to describe coal pyrolysis clearly. Single model compounds have been used before in order to provide additional insight into the complex processes that occur in the pyrolysis of coal. Yet the picture obtained is a simplified one and certain important aspects such as coal structure, interactions between different surface groups and cross-links are omitted. The approach used in this work involves the preparation of a synthetic coal, SC, with a known structure by curing a mixture of single, well-defined model compounds. By means of chemical characterisation, the SC was shown to contain the macroscopic features of a high volatile coal (proximate and ultimate analyses). FTIR characterisation revealed the presence of functional groups similar to those of coal in the structure of the SC. Temperature-programmed pyrolysis tests were performed in a thermobalance linked to a mass spectrometer and a Fourier transform infrared analyser (TG/MS/FTIR). The thermal behaviour of the synthetic coal (i.e., rate of mass loss and the evolution profiles of gaseous compounds during pyrolysis tests) is very similar to that of the high volatile bituminous coal which was used as a reference material. The great advantage of using SC lies in the fact that its composition and structure can be accurately determined and employed in subsequent applications in basic and mechanistic studies.

A Wireless LAN and Voice Information System for Underground Coal Mine

Directory of Open Access Journals (Sweden)

Yu Zhang

2014-06-01

Full Text Available In this paper we constructed a wireless information system, and developed a wireless voice communication subsystem based on Wireless Local Area Networks (WLAN for underground coal mine, which employs Voice over IP (VoIP technology and Session Initiation Protocol (SIP to achieve wireless voice dispatching communications. The master control voice dispatching interface and call terminal software are also developed on the WLAN ground server side to manage and implement the voice dispatching communication. A testing system for voice communication was constructed in tunnels of an underground coal mine, which was used to actually test the wireless voice communication subsystem via a network analysis tool, named Clear Sight Analyzer. In tests, the actual flow charts of registration, call establishment and call removal were analyzed by capturing call signaling of SIP terminals, and the key performance indicators were evaluated in coal mine, including average subjective value of voice quality, packet loss rate, delay jitter, disorder packet transmission and end-to- end delay. Experimental results and analysis demonstrate that the wireless voice communication subsystem developed communicates well in underground coal mine environment, achieving the designed function of voice dispatching communication.

The French coal board and French society

International Nuclear Information System (INIS)

Ladoucette, Ph. de

2004-01-01

On 19 April 1946 the French national assembly passed a law for nationalizing the mineral fuel industry by a vote of 516 against only 31. 'Charbonnages de France' (CDF), the French coal board, was created and prospects were promising. During the reconstruction period (1945 - 1960), coal industry was a pillar of the French economy, the production of coal had been steadily growing to reach its top in 1958 with 59 Mt. The sixties showed the beginning of the decline of coal to the benefit of oil, natural gas and later nuclear energy. As early as 1967 CDF had a policy of promoting new industries in regions of mines in order to break down the mono-industry scheme and to favor staff conversion massively. In 1947 the number of people on the payroll of CDF was 360.000, this number was decreasing steadily to reach 23.000 in 1990. In 2004 the last deep mine to work in France was closed down. This article tells the story of coal mining in France by describing its ups and downs and by assessing its social impact

Proceedings of the advanced coal-fired power systems `95 review meeting, Volume I

Energy Technology Data Exchange (ETDEWEB)

McDaniel, H.M.; Mollot, D.J.; Venkataraman, V.K.

1995-06-01

This document contains papers presented at The advanced Coal-Fired Power Systems 1995 Review Meeting. Research was described in the areas of: integrated gasification combined cycle technology; pressurized fluidized-bed combustion; externally fired combined cycles; a summary stauts of clean coal technologies; advanced turbine systems and hot gas cleanup. Individual projects were processed separately for the United States Department of Energy databases.

Nuke-to-coal switch nixed in Texas, still alive in Ohio

International Nuclear Information System (INIS)

Anon.

1985-01-01

A feasibility study found it uneconomical to convert the South Texas Project from nuclear to coal, but the Zimmer plant in Ohio is continuing to pursue the conversion concept. The main issue in Ohio is the accounting treatment of the investment in the 800-MW single unit project that was cancelled in 1984. The owners hope that interested parties can agree on a package stipulating what portion of the costs of the existing plant will be disallowed from the rate base prior to state commission review. A favorable study shows that about 45% of the $1.7 billion investment is usable in a coal plant. Conversion will require an additional $1.7 billion to provide a 1300-MW coal-fired plant. Feasibility for the Zimmer plant is due to its 97% level of completion, while construction at the Texas plant is not as far along

Bed retained products in swept fixed bed (SFB) coal hydropyrolysis

Energy Technology Data Exchange (ETDEWEB)

Mastral, A.M.; Perez-Surio, M.J. [CSIC, Zaragosa (Spain). Inst. de Carboquimica

1997-12-31

The hydropyrolysis of a low rank coal in a swept fixed bed (SFB) reactor is carried out by fixing the hydrogen pressure (40 kg/cm{sup 2}), the hydrogen flow (2 l/min) and the residence time (10 min) at increasing temperatures (400 C, 500 C and 600 C) and coal bed heights (h, 1.5h, 2h, 2.5h and 3h). It is shown that the percentages of tars and char directly depend on the coal bed height and that there is not only a quantitative dependence, but also the height of the coal bed is very important and plays a relevant role on the nature of the conversion products. (orig.)

Lightweight monitoring and control system for coal mine safety using REST style.

Science.gov (United States)

Cheng, Bo; Cheng, Xin; Chen, Junliang

2015-01-01

The complex environment of a coal mine requires the underground environment, devices and miners to be constantly monitored to ensure safe coal production. However, existing coal mines do not meet these coverage requirements because blind spots occur when using a wired network. In this paper, we develop a Web-based, lightweight remote monitoring and control platform using a wireless sensor network (WSN) with the REST style to collect temperature, humidity and methane concentration data in a coal mine using sensor nodes. This platform also collects information on personnel positions inside the mine. We implement a RESTful application programming interface (API) that provides access to underground sensors and instruments through the Web such that underground coal mine physical devices can be easily interfaced to remote monitoring and control applications. We also implement three different scenarios for Web-based, lightweight remote monitoring and control of coal mine safety and measure and analyze the system performance. Finally, we present the conclusions from this study and discuss future work. Copyright © 2014 ISA. Published by Elsevier Ltd. All rights reserved.

Studies of coupled chemical and catalytic coal conversion methods. Tenth quarterly report, January--March 1990

Energy Technology Data Exchange (ETDEWEB)

Stock, L.M.

1990-12-31

This report concerns our research on base-catalyzed coal solubilization and a new approach for hydrogen addition. The work on base-catalyzed, chemical solubilization is continuing. this report is focused on the hydrogenation research. Specifically it deals with the use of arene chromium carbonyl complexes as reagents for the addition of dideuterium to coal molecules. In one phase of the work, he has established that the aromatic hydrocarbons in a representative coal liquid can be converted in very good yield to arene chromium carbonyl compounds. In a second phase of the work directly related to our objective of improved methods for catalytic hydrogenation, he has established that the aromatic constituents of the same coal liquid add dideuterium in the presence of added napththalene chromium carbonyl.

A System for Electromagnetic Field Conversion

DEFF Research Database (Denmark)

2003-01-01

A system is provided for conversion of a first electromagnetic field into a desired second electromagnetic field, for example for coupling modes between waveguides or into microstructured waveguides. The system comprises a complex spatial electromagnetic field converter that is positioned...... for reception of at least a part of the first electromagnetic field and that is adapted for conversion of the received field into the desired electromagnetic field, and wherein at least one of the first and second fields matches a mode of a microstructured waveguide. It is an important advantage of the present...

Economic comparison of clean coal generating technologies with natural gas-combined cycle systems

International Nuclear Information System (INIS)

Sebesta, J.J.; Hoskins, W.W.

1990-01-01

This paper reports that there are four combustion technologies upon which U.S. electric utilities are expected to rely for the majority of their future power generating needs. These technologies are pulverized coal- fired combustion (PC); coal-fired fluidized bed combustion (AFBC); coal gasification, combined cycle systems (CGCC); and natural gas-fired combined cycle systems (NGCC). The engineering and economic parameters which affect the choice of a technology include capital costs, operating and maintenance costs, fuel costs, construction schedule, process risk, environmental and site impacts, fuel efficiency and flexibility, plant availability, capacity factors, timing of startup, and the importance of utility economic and financial factors

Selected problems of coal mining mechanization in the coal industry of Poland

Energy Technology Data Exchange (ETDEWEB)

Antoniak, J; Sikora, W [Politechnika Slaska, Gliwice (Poland)

1987-01-01

Discusses conditions for underground coal mining in Poland, types of equipment for coal cutting, mine haulage and strata control and development trends of mining technologies. In 1985, black coal output was 191.6 Mt; 85.3% came from longwall faces mined by sets of mining equipment (coal cutters, chain conveyors and powered supports). The average coal output per longwall face was 881 t/d, output per face mined by sets for mining equipment was 1,134 t/d. In 1985, 653 shearer loaders and 77 coal plows were used in Polish coal mines. Number of shearer loaders is increasing. Shearer loaders with chainless haulage system were safest and most economic. The shearer loaders were equipped with the POLTRAK chainless haulage system developed in Poland. Research programs concentrate on development of new mining equipment for thin seam mining, steep seam mining, longwall mining with hydraulic stowing, efficient strata control by powered or shield supports under conditions of increased stresses or rock burst hazards. 4 refs.

The carbon dioxide gasification characteristics of biomass char samples and their effect on coal gasification reactivity during co-gasification.

Science.gov (United States)

Mafu, Lihle D; Neomagus, Hein W J P; Everson, Raymond C; Okolo, Gregory N; Strydom, Christien A; Bunt, John R

2018-06-01

The carbon dioxide gasification characteristics of three biomass char samples and bituminous coal char were investigated in a thermogravimetric analyser in the temperature range of 850-950 °C. Char SB exhibited higher reactivities (R i , R s , R f ) than chars SW and HW. Coal char gasification reactivities were observed to be lower than those of the three biomass chars. Correlations between the char reactivities and char characteristics were highlighted. The addition of 10% biomass had no significant impact on the coal char gasification reactivity. However, 20 and 30% biomass additions resulted in increased coal char gasification rate. During co-gasification, chars HW and SW caused increased coal char gasification reactivity at lower conversions, while char SB resulted in increased gasification rates throughout the entire conversion range. Experimental data from biomass char gasification and biomass-coal char co-gasification were well described by the MRPM, while coal char gasification was better described by the RPM. Copyright © 2018 Elsevier Ltd. All rights reserved.

Studies on classifying Indian coals. Part II. A new system for grading and pricing

Energy Technology Data Exchange (ETDEWEB)

Tumuluri, S.G.; Shrikhande, S.K.; Rao, S.K.; Haque, R.

1985-07-01

The new system is self-complete through grading to pricing. It grades non-coking coal by moisture and ash contents. Coking coal is graded by GKLT coke type and ash content. Volatile matter content is used as a supporting indexer, where necessary. Through the grade data, a coal is evaluated into a single numeral which depicts the coaly matter content and its nature or effectiveness. This value, called effective coaly matter, is converted to a relative rupee value or price index/price. Pragmatics and versatility of the system are discussed.

Continuous bench-scale slurry catalyst testing direct coal liquefaction rawhide sub-bituminous coal

Energy Technology Data Exchange (ETDEWEB)

Bauman, R.F.; Coless, L.A.; Davis, S.M. [and others

1995-12-31

In 1992, the Department of Energy (DOE) sponsored research to demonstrate a dispersed catalyst system using a combination of molybdenum and iron precursors for direct coal liquefaction. This dispersed catalyst system was successfully demonstrated using Black Thunder sub-bituminous coal at Wilsonville, Alabama by Southern Electric International, Inc. The DOE sponsored research continues at Exxon Research and Development Laboratories (ERDL). A six month continuous bench-scale program using ERDL`s Recycle Coal Liquefaction Unit (RCLU) is planned, three months in 1994 and three months in 1995. The initial conditions in RCLU reflect experience gained from the Wilsonville facility in their Test Run 263. Rawhide sub-bituminous coal which is similar to the Black Thunder coal tested at Wilsonville was used as the feed coal. A slate of five dispersed catalysts for direct coal liquefaction of Rawhide sub-bituminous coal has been tested. Throughout the experiments, the molybdenum addition rate was held constant at 100 wppm while the iron oxide addition rate was varied from 0.25 to 1.0 weight percent (dry coal basis). This report covers the 1994 operations and accomplishments.

Trends in Japanese coal trade

Energy Technology Data Exchange (ETDEWEB)

Nakajima, S

1986-01-01

The author discusses 1) the latest forecast for coal demand in Japan; 2) trends in Japanese steam coal demand, with breakdown by industry; 3) the organization of steam coal supply, with details of the distribution network and of the new coal cartridge system; 4) the demand for metallurgical coal. Other topics outlined include the current status of Japanese coal production, Japanese coal trade, and the development of overseas coal resources. 1 figure, 5 tables.

Underground coal gasification: An overview of groundwater contamination hazards and mitigation strategies

Energy Technology Data Exchange (ETDEWEB)

Camp, David W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); White, Joshua A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2015-03-13

Underground coal gasification is the in situ conversion of coal into an energy-rich product gas. It takes place deep underground, using chemical reactions to consume the coal and grow a cavity. Gas wells, drilled into the coal seam, inject reactant air, oxygen, and/or steam to sustain the reactions. Production wells then extract the product gas. Careful analysis and understanding of likely failure modes will help prevent and minimize impacts. This document provides a general description of the relevant processes, potential failure modes, and practical mitigation strategies. It can guide critical review of project design and operations.

Automated cost modeling for coal combustion systems

International Nuclear Information System (INIS)

Rowe, R.M.; Anast, K.R.

1991-01-01

This paper reports on cost information developed at AMAX R and D Center for coal-water slurry production implemented in an automated spreadsheet (Lotus 123) for personal computer use. The spreadsheet format allows the user toe valuate impacts of various process options, coal feedstock characteristics, fuel characteristics, plant location sites, and plant sizes on fuel cost. Model flexibility reduces time and labor required to determine fuel costs and provides a basis to compare fuels manufactured by different processes. The model input includes coal characteristics, plant flowsheet definition, plant size, and market location. Based on these inputs, selected unit operations are chosen for coal processing

Coal 95

International Nuclear Information System (INIS)

Sparre, C.

1995-01-01

The report deals with the use of coal and coke in Sweden during 1994. Some information about technology, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used.The use of steam coal for heating purposes has been unchanged during 1994 at a level of 1 Mtons. The production in the cogeneration plants has been constant, but has increased for electricity production. The minor plants have increased their use of forest fuels. The use of steam coal will probably go down in the next years both for heat and cogeneration plants. During the top year 1987 coal was used in 18 hot water and 11 cogeneration plants. 1994 these figures are 3 and 12. Taxes and environmental reasons explain this trend. The use of steam coal in industry has been constant at the level 0.7 Mtons. The import of metallurgical coal in 1993 was 1.6 Mtons, like 1992. Import of 0.3 Mtons of coke gives the total consumption of coke in industry as 1.5 Mtons. the average price of steam coal imported to Sweden was 317 SEK/ton, 3% higher than 1993. All Swedish plants meet their emission limit of dust, SO 2 and NO x as given by county administrations or concession boards. The cogeneration plants all have some SO 2 removal system. The biggest cogeneration plant (Vaesteraas) has recently invested in a SCR NO x cleaning system. Most other plants use low NO x burners or SNR injection systems based on ammonia or urea. 2 figs, 13 tabs

High pressure hydropyrolysis of coals by using a continuous free-fall reactor

Energy Technology Data Exchange (ETDEWEB)

W.-C. Xu; K. Matsuoka; H. Akiho; M. Kumagai; A. Tomita [Institute of Research and Innovation, Kashiwa (Japan)

2003-04-01

Rapid hydropyrolysis of coal was carried out at temperatures ranging from 923 to 1123 K and H{sub 2} pressures up to 7 MPa by using a continuous free-fall pyrolyzer. The effects of the reaction conditions on product yields were investigated. Carbon mass balance was fairly good. It was revealed that a large amount of methane was produced due to the hydrogenolysis of higher hydrocarbons and the hydrogasification of char. The influence of pyrolysis temperature was significant on both reactions while H{sub 2} pressure mainly affected the latter. A considerable amount of reactive carbon was formed during hydropyrolysis of coal. It was converted to methane at high temperatures and high H{sub 2} pressures, while the hydrogasification of reactive carbon takes place relatively slowly at low temperatures and low H{sub 2} pressures, resulting in a low overall carbon conversion. The coal conversions observed in the present study were much higher than those obtained with using reactors where the contact between coal particles and H{sub 2} is insufficient. 25 refs., 6 figs., 6 tabs.

Fiscal 1997 survey report. Feasibility study of the environmentally friendly type coal utilization system (survey of the coal utilization in Pakistan); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Pakistan ni okeru sekitan riyo gaikyo chosa)

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

This paper made a literature survey, hearing survey, site survey/study on the coal in Pakistan such as the coal utilization system and the environmental situation, etc., and aimed at pre-examination for the survey of the introduction of the environmentally friendly type coal utilization system to be planned in Pakistan in the future. The examination, data collection and preparation were conducted in terms of the following items: the structure of coal consumption in energy supply, structure of coal consumption, mainly of domestic brown coal consumption, the situation of coal utilization by industry and by region, environmental problems caused by coal utilization such as air pollution, the trend of policies of environmental regulation, etc. The literature on the following was obtained and surveyed: the situation of economy/energy in Pakistan, coal utilization technology by industrial field, and environmental protection technology. The hearing survey was made to institutions concerned, corporation groups and men of learning and experience. Site surveys were conducted for the typically selected coal utilization equipment and existing environmental protection equipment. 66 figs., 56 tabs.

Combined production of synthetic liquid fuel and electricity from coal using H2S and CO2 removal systems

Directory of Open Access Journals (Sweden)

Elina A. Tyurina

2015-11-01

Full Text Available The main aim of the research is to continue the studies on promising technologies of coal conversion into synthetic liquid fuel (methanol. The object of study is the plants for combined production of electricity and synthetic liquid fuel (PCPs, which are eco-friendly and more efficient as compared to the plants for separate production. The previous studies on PCPs consider the systems for fine cleaning of gasification products in a simplified way. This study presents the detailed mathematical modeling of the aforementioned systems and determines the values of energy consumption and investment in them. The obtained values are used to carry out the optimization studies and find the optimal parameters of PCPs with different degree of CO2 removal from gasification products providing fine cleaning of gasification products from H2S.

Chemical and Pyrolytic Thermogravimetric Characterization of Nigerian Bituminous Coals

Directory of Open Access Journals (Sweden)

Nyakuma Bemgba Bevan

2016-12-01

Full Text Available The discovery of new coal deposits in Nigeria presents solutions for nation’s energy crises and prospects for socioeconomic growth and sustainable development. Furthermore, the quest for sustainable energy to limit global warming, climate change, and environmental degradation has necessitated the exploration of alternatives using cleaner technologies such as coal pyrolysis. However, a lack of comprehensive data on physico-chemical and thermal properties of Nigerian coals has greatly limited their utilization. Therefore, the physico-chemical properties, rank (classification, and thermal decomposition profiles of two Nigerian bituminous coals – Afuze (AFZ and Shankodi-Jangwa (SKJ – were examined in this study. The results indicate that the coals contain high proportions of C, H, N, S, O and a sufficiently high heating value (HHV for energy conversion. The coal classification revealed that the Afuze (AFZ coal possesses a higher rank, maturity, and coal properties compared to the Shankodi-Jangwa (SKJ coal. A thermal analysis demonstrated that coal pyrolysis in both cases occurred in three stages; drying (30-200 °C, devolatilization (200-600 °C, and char decomposition (600-1000 °C. The results also indicated that pyrolysis at 1000 °C is not sufficient for complete pyrolysis. In general, the thermochemical and pyrolytic fuel properties indicate that the coal from both places can potentially be utilized for future clean energy applications.

South Blackwater Coal`s maintenance program

Energy Technology Data Exchange (ETDEWEB)

Nash, J. [South Blackwater Coal Limited, Blackwater, Qld. (Australia)

1998-09-01

The South Blackwater operation consists of two opencut mining areas and two underground mines (Laleham and Kenmure) near Blackwater in central Queensland, all of which supply coal to a central coal preparation plant. South Blackwater Coal Ltd. recently developed a maintenance improvement programme, described in this article. The programme involved implementation systems of key performance indicators (KPIs), benchmaking, condition monitoring, work planning and control, failure analysis and maintenance audit. Some improvements became almost immediately apparent, others were quite gradual. Major results included: improved availability (and reliability) of all opencast fleets, improvements in rear dump availability; reduced maintenance man-hours for opencast fleets; and increased availability of the coal handling and preparation plant. The paper is an edited version of that presented at the `Maintenance in mining conference` 16-19 March 1998, held in Bali, Indonesia. 4 figs., 2 photos.

Rosebud syncoal partnership SynCoal{sup {reg_sign}} demonstration technology development update

Energy Technology Data Exchange (ETDEWEB)

Sheldon, R.W. [Rosebud SynCoal Company, Billings, MT (United States); Heintz, S.J. [Department of Energy, Pittsburgh, PA (United States)

1995-12-01

Rosebud SynCoal{reg_sign} Partnership`s Advanced Coal Conversion Process (ACCP) is an advanced thermal coal upgrading process coupled with physical cleaning techniques to upgrade high moisture, low-rank coals to produce a high-quality, low-sulfur fuel. The coal is processed through two vibrating fluidized bed reactors where oxygen functional groups are destroyed removing chemically bound water, carboxyl and carbonyl groups, and volatile sulfur compounds. After thermal upgrading, the SynCoal{reg_sign} is cleaned using a deep-bed stratifier process to effectively separate the pyrite rich ash. The SynCoal{reg_sign} process enhances low-rank western coals with moisture contents ranging from 2555%, sulfur contents between 0.5 and 1.5 %, and heating values between 5,500 and 9,000 Btu/lb. The upgraded stable coal product has moisture contents as low as 1 %, sulfur contents as low as 0.3%, and heating values up to 12,000 Btu/lb.

Performance simulations for Co-gasification of coal and methane

Energy Technology Data Exchange (ETDEWEB)

Niksa, Stephen [Niksa Energy Associates LLC, Belmont, CA (United States); Lim, J.P.; Del Rio Diaz Jara, D.; Eckstrom, D.; Steele, D.; Malhotra, R.; Wilson, R.B. [SRI International, Menlo Park, CA (United States). Chemistry and Chemical Engineering Dept.

2013-07-01

In the process under development, coal suspended in mixtures of CH{sub 4}, H{sub 2}, and steam is rapidly heated to temperatures above 1,400 C under 5-7 MPa for at least 1 s. The coal first decomposes into volatiles and char while CH{sub 4} is converted into CO/H{sub 2} mixtures. Then the char is converted into CO/H{sub 2} mixtures via steam gasification on longer time scales, and into CH{sub 4} via hydrogasification. Throughout all stages, homogeneous chemistry reforms all intermediate fuel components into the syngas feedstock for methanol synthesis. Fully validated reaction mechanisms for each chemical process were used to quantitatively interpret a co-gasification test series in SRI's lab-scale gasification facility. Homogeneous reforming chemistry generates equilibrium gas compositions at 1,500 C in the available transit time of 1.4 s, but not at any of the lower temperatures. Methane conversion in the gas phase increases for progressively hotter temperatures, in accord with the data. But the strong predicted dependence on steam concentration was not evident in the measured CH{sub 4} conversions, even when steam concentration was the subject test variable. Char hydrogasification adds CH{sub 4} to the product gas stream, but this process probably converts no more than 15-20% of the char in the lab-scale tests and the bulk of the char is converted by steam gasification. The correlation coefficient between predicted and measured char conversions exceeded 0.8 and the std. dev. was 3.4%, which is comparable to the measurement uncertainties. The evaluation of the predicted CH{sub 4} conversions gave a std. dev. greater than 20%. Simulations of commercial conditions with realistic suspension loadings and no diluents in the feed gave slightly lower conversions of both CH{sub 4} and coal, because hydrogasification accounts for more of the char conversion, and occurs at rates slower than for steam gasification.

Research report of FY 1997 on the environmentally acceptable coal utilization system feasibility survey. Environmentally acceptable coal utilization system feasibility survey in Malaysia and Vietnam (Malaysia); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Malaysia oyobi Vietnam ni okeru kankyo chowagata sekitan riyo system kanosei chosa (Malaysia ban))

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-03-01

In this survey, the coal utilization status in individual consumption sectors and coal distribution status in Malaysia are summarized as basic data for the introduction of environmentally acceptable coal utilization systems. In this fiscal year, the status of existing coal utilization technology and environmental issues in Malaysia are summarized as basic data for the introduction of above-mentioned systems on the basis of data and information collected by basic research and site survey in FY 1996. Malaysia is one of the rich countries producing the primary resources with crude petroleum, natural gas, hydro-power, and coal. The coal demand will be realized after saturating LNG development since 2000. The major coal consumption industries are power generation sector and cement industry sector. As expected increase in the future coal consumption, efficiency of coal utilization and environmental issues are problems in the future. Based on the FS results of this survey, the survey will be continued for planning and conducting the model project required from Malaysia. 8 figs., 34 tabs.

Report of activities of the advanced coal extraction systems definition project, 1979 - 1980

Science.gov (United States)

Lavin, M. L.; Isenberg, L.

1981-01-01

During this period effort was devoted to: formulation of system performance goals in the areas of production cost, miner safety, miner health, environmental impact, and coal conservation, survey and in depth assessment of promising technology, and characterization of potential resource targets. Primary system performance goals are to achieve a return on incremental investment of 150% of the value required for a low risk capital improvement project and to reduce deaths and disability injuries per million man-hour by 50%. Although these performance goals were developed to be immediately applicable to the Central Appalachian coal resources, they were also designed to be readily adaptable to other coals by appending a geological description of the new resource. The work done on technology assessment was concerned with the performance of the slurry haulage system.

Biotechnological lignite conversion - a large-scale concept

Energy Technology Data Exchange (ETDEWEB)

Reich-Walber, M.; Meyrahn, H.; Felgener, G.W. [Rheinbraun AG, Koeln (Germany). Fuel Technology and Lab. Dept.

1997-12-31

Concerning the research on biotechnological lignite upgrading, Rheinbraun`s overall objective is the large-scale production of liquid and gaseous products for the energy and chemical/refinery sectors. The presentation outlines Rheinbraun`s technical concept for electricity production on the basis of biotechnologically solubilized lignite. A first rough cost estimate based on the assumptions described in the paper in detail and compared with the latest power plant generation shows the general cost efficiency of this technology despite the additional costs in respect of coal solubilization. The main reasons are low-cost process techniques for coal conversion on the one hand and cost reductions mainly in power plant technology (more efficient combustion processes and simplified gas clean-up) but also in coal transport (easy fuel handling) on the other hand. Moreover, it is hoped that an extended range of products will make it possible to widen the fields of lignite application. The presentation also points out that there is still a huge gap between this scenario and reality by limited microbiological knowledge. To close this gap Rheinbraun started a research project supported by the North-Rhine Westphalian government in 1995. Several leading biotechnological companies and institutes in Germany and the United States are involved in the project. The latest results of the current project will be presented in the paper. This includes fundamental research activities in the field of microbial coal conversion as well as investigations into bioreactor design and product treatment (dewatering, deashing and desulphurization). (orig.)

STUDY OF SOLVENT AND CATALYST INTERACTIONS IN DIRECT COAL LIQUEFACTION; FINAL

International Nuclear Information System (INIS)

Michael T. Klein; William H. Calkins; Jasna Tomic

2000-01-01

To provide a better understanding of the roles of a solid catalyst and the solvent in Direct Coal Liquefaction, a small reactor was equipped with a porous-walled basket which was permeable to the solvent but was not permeable to the coal or solid catalyst. With this equipment and a high volatile bituminous coal it was found that direct contact between the catalyst in the basket and the coal outside the basket is not required for catalyzed coal liquefaction. The character of the solvent in this system makes a significant difference in the conversion of the coal, the better solvents being strong donor solvents. Because of the extensive use of thermogravimetric analysis in this laboratory, it was noted that the peak temperature for volatiles evolution from coal was a reliable measure of coal rank. Because of this observation, a variety of coals of a range of ranks was investigated. It was shown in this work that measuring the peak temperature for volatiles evolution was a quite precise indicator of rank and correlated closely with the rank value obtained by measuring vitrinite reflectance, a more difficult measurement to make. This prompted the desire to know the composition of the volatile material evolved as a function of coal rank. This was then measured by coupling a TGA to a mass spectrometer using laser activation and photoionization detection TG-PI-MS. The predominant species in volatiles of low rank coal turned out to be phenols with some alkenes. As the rank increases, the relative amounts of alkene and aromatic hydrocarbons increases and the oxygenated species decrease. It was shown that these volatiles were actually pyrolytic products and not volatilization products of the coal. Solvent extraction experiments coupled with Thermogravimetric-photoionization-mass spectrometry (TG-PI-MS) indicated that the low boiling and more extractable material are essentially similar in chemical types to the non-extractable portions but apparently higher molecular weight

Geochemical database of feed coal and coal combustion products (CCPs) from five power plants in the United States

Science.gov (United States)

Affolter, Ronald H.; Groves, Steve; Betterton, William J.; William, Benzel; Conrad, Kelly L.; Swanson, Sharon M.; Ruppert, Leslie F.; Clough, James G.; Belkin, Harvey E.; Kolker, Allan; Hower, James C.

2011-01-01

The principal mission of the U.S. Geological Survey (USGS) Energy Resources Program (ERP) is to (1) understand the processes critical to the formation, accumulation, occurrence, and alteration of geologically based energy resources; (2) conduct scientifically robust assessments of those resources; and (3) study the impacts of energy resource occurrence and (or) their production and use on both the environment and human health. The ERP promotes and supports research resulting in original, geology-based, non-biased energy information products for policy and decision makers, land and resource managers, other Federal and State agencies, the domestic energy industry, foreign governments, non-governmental groups, and academia. Investigations include research on the geology of oil, gas, and coal, and the impacts associated with energy resource occurrence, production, quality, and utilization. The ERP's focus on coal is to support investigations into current issues pertaining to coal production, beneficiation and (or) conversion, and the environmental impact of the coal combustion process and coal combustion products (CCPs). To accomplish these studies, the USGS combines its activities with other organizations to address domestic and international issues that relate to the development and use of energy resources.

DOLOMITE DESULFURIZATION BEHAVIOR IN A BUBBLING FLUIDIZED BED PILOT PLANT FOR HIGH ASH COAL

Directory of Open Access Journals (Sweden)

G. M. F. Gomes

Full Text Available Abstract Although fluidized bed in situ desulphurization from coal combustion has been widely studied, there are aspects that remain under investigation. Additionally, few publications address Brazilian coal desulphurization via fluidized beds. This study used a 250 kWth bubbling fluidized bed pilot plant to analyze different aspects of the dolomite desulphurization of two Brazilian coals. Superficial velocities of 0.38 and 0.46 m/s, flue gas recycling, Ca/S molar ratios and elutriation were assessed. Results confirmed the influence of the Ca/S molar ratio and superficial velocity - SO2 conversion up to 60.5% was achieved for one coal type, and 70.9% was achieved for the other type. A recycling ratio of 54.6% could increase SO2 conversion up to 86.1%. Elutriation and collection of ashes and Ca-containing products did not present the same behavior because a lower wt. % of CaO was collected by the gas controlled mechanism compared to the ash.

Optical Energy Transfer and Conversion System

Science.gov (United States)

Hogan, Bartholomew P. (Inventor); Stone, William C. (Inventor)

2018-01-01

An optical energy transfer and conversion system comprising a fiber spooler and an electrical power extraction subsystem connected to the spooler with an optical waveguide. Optical energy is generated at and transferred from a base station through fiber wrapped around the spooler, and ultimately to the power extraction system at a remote mobility platform for conversion to another form of energy. The fiber spooler may reside on the remote mobility platform which may be a vehicle, or apparatus that is either self-propelled or is carried by a secondary mobility platform either on land, under the sea, in the air or in space.

Clean Coal Day '93. Hokkaido Seminar; Clean Coal Day '93. Hokkaido Seminar

Energy Technology Data Exchange (ETDEWEB)

NONE

1993-11-01

The titles of the lectures in this record are 1) Coal energy be friendly toward the earth, 2) Future development of coal-fired thermal power generation, 3) Current status of research and development of coalbed methane in the U.S., and 4) PFBC (pressurized fluidized bed combustion combined cycle) system. Under title 1), the reason is explained why coal is back as an energy source and is made much of. The actualities of coal being labelled as a dirty energy source are explained. The rapid growth of demand for coal in Asia is commented on and what is expected of clean coal technology is stated. Under title 2), it is predicted that atomic energy, LNG (liquefied natural gas), and coal will be the main energy sources for electric power in Japan. Under title 3), it is stated that 10% of America's total amount of methane production is attributable to coal mining, that methane is the cleanest of the hydrocarbon fuels although it is a pollution source from an environmental point of view, and that it is therefore reasonable to have its collection and utilization placed in the domain of clean coal technology. Under title 4), a PFBC system to serve as the No. 3 machine for the Tomahigashi-Atsuma power plant is described. (NEDO)

Optimal coal import strategy

International Nuclear Information System (INIS)

Chen, C.Y.; Shih, L.H.

1992-01-01

Recently, the main power company in Taiwan has shifted the primary energy resource from oil to coal and tried to diversify the coal supply from various sources. The company wants to have the imported coal meet the environmental standards and operation requirements as well as to have high heating value. In order to achieve these objectives, establishment of a coal blending system for Taiwan is necessary. A mathematical model using mixed integer programming technique is used to model the import strategy and the blending system. 6 refs., 1 tab

Coal background paper. Coal demand

International Nuclear Information System (INIS)

1997-01-01

Statistical data are presented on coal demands in IEA and OECD member countries and in other countries. Coal coaking and coaking coal consumption data are tabulated, and IEA secretariat's coal demand projections are summarized. Coal supply and production data by countries are given. Finally, coal trade data are presented, broken down for hard coal, steam coal, coking coal (imports and export). (R.P.)

Intelligent control and maintenance of management integrated system based on multi-agents for coal preparation plant

Energy Technology Data Exchange (ETDEWEB)

Meng, F.; Wang, Y. [China University of Mining and technology, Xuzhou (China). School of Information and Electrical Engineering

2006-06-15

This paper discusses the progress of computer integrated processing (CIPS) of coal preparation and then presents an intelligence controlled production process, device-maintenance and production-management system of coal preparation based on multi-agents (IICMMS-CP). The construction of the IICMMS-CP, the distributed network control system based on live intelligence control stations and the strategy of implementing a distributed intelligence control system are studied in order to overcome the disadvantages brought about by the wide use of the PLC system by coal preparation plants. The software frame, based on a Multi-Agent Intelligence Control and Maintenance Management integrated system, is studied and the implementation methods of IICMMS-CP are discussed. The characteristics of distributed architecture, cooperation and parallel computing meet the needs of integrated control of coal preparation plants with large-scale spatial production distribution, densely-related processes and complex systems. Its application further improves the reliability and precision of process control, accuracy of fault identification and intelligence of production adjustment, establishes a technical basis for system integration and flexible production. The main function of the system has been tested in a coal preparation plant to good effect in stabilizing product quality, improving efficiency and reducing consumption. 17 refs., 4 figs.

Direct liquefaction of plastics and coprocessing of coal with plastics

Energy Technology Data Exchange (ETDEWEB)

Huffman, G.P.; Feng, Z.; Mahajan, V. [Univ. of Kentucky, Lexington, KY (United States)

1995-12-31

The objectives of this work were to optimize reaction conditions for the direct liquefaction of waste plastics and the coprocessing of coal with waste plastics. In previous work, the direct liquefaction of medium and high density polyethylene (PE), polypropylene (PPE), poly(ethylene terephthalate) (PET), and a mixed plastic waste, and the coliquefaction of these plastics with coals of three different ranks was studied. The results established that a solid acid catalyst (HZSM-5 zeolite) was highly active for the liquefaction of the plastics alone, typically giving oil yields of 80-95% and total conversions of 90-100% at temperatures of 430-450 {degrees}C. In the coliquefaction experiments, 50:50 mixtures of plastic and coal were used with a tetralin solvent (tetralin:solid = 3:2). Using approximately 1% of the HZSM-5 catalyst and a nanoscale iron catalyst, oil yields of 50-70% and total conversion of 80-90% were typical. In the current year, further investigations were conducted of the liquefaction of PE, PPE, and a commingled waste plastic obtained from the American Plastics Council (APC), and the coprocessing of PE, PPE and the APC plastic with Black Thunder subbituminous coal. Several different catalysts were used in these studies.

Inclined fluidized bed system for drying fine coal

Science.gov (United States)

Cha, Chang Y.; Merriam, Norman W.; Boysen, John E.

1992-02-11

Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

Protective coatings on structural materials for energy conversion systems

International Nuclear Information System (INIS)

John, J.T.; De, P.K.; Srinivasa, R.S.

2000-01-01

Full text: Structural Materials and Components used in coal fired energy conversion systems, crude oil refineries and coal gasification plants are subjected to degradation due to oxidation, sulfidation, carbonization and halogenation. Suitable protective coatings can significantly enhance their life. Protective coatings work by forming a highly stable, self-healing and slow growing protective scale at the operating temperatures. These scales act as barriers between the corrosive environment and the alloy and prevent degradation of the substitute. Three types of scales that provide such protection are based on Al 2 O 3 , Cr 2 O 3 and SiO 2 . Aluminide coatings are major alumina forming protecting coatings, applied on nickel, cobalt and iron base alloys. Aluminide coatings are prepared by enriching the surface of a component by aluminum. In this paper the formation of aluminide coatings of nickel, IN738, Alloy 800, Zircaloy-2 and pure iron by chemical vapor deposition has been described. In this technique, Aluminum chloride vapors from bath kept at 353-373 K are carried in a stream of hydrogen gas into a Hot Walled CVD chamber kept at 1173-1373 K. The AlCl 3 vapors were allowed to react with pure aluminum whereby aluminum sub-chlorides like AlCl and AlCl 2 are produced which deposit aluminum on the substrates. At the high temperature of the deposition, aluminum diffuses into the substrate and forms the aluminide coating. The process can be represented by the reaction Al (i) + AlCl 3(g) AlCl 2(s) + AlCl 2 (g) . XRD and optical microscopic studies have characterized the coatings. On pure nickel and Alloy 800 the coating consists of Ni 2 Al 3 and NiAl respectively. On pure iron the coatings consisted of FeAl. On Zircaloy-2, ZrAl 2 was also detected. The CVD coating process, XRD and optical microscopy data will be discussed further

Healy Clean Coal Project: Healy coal firing at TRW Cleveland Test Facility

Energy Technology Data Exchange (ETDEWEB)

Koyama, T.; Petrill, E.; Sheppard, D.

1991-08-01

A test burn of two Alaskan coals was conducted at TRW's Cleveland test facility in support of the Healy Clean Coal Project, as part of Clean Coal Technology III Program in which a new power plant will be constructed using a TRW Coal Combustion System. This system features ash slagging technology combined with NO{sub x} and SO{sub x} control. The tests, funded by the Alaska Industrial Development and Export Authority (AIDEA) and TRW, were conducted to verify that the candidate Healy station coals could be successfully fired in the TRW coal combustor, to provide data required for scale-up to the utility project size requirements, and to produce sufficient flash-calcined material (FCM) for spray dryer tests to be conducted by Joy/NIRO. The tests demonstrated that both coals are viable candidates for the project, provided the data required for scale-up, and produced the FCM material. This report describes the modifications to the test facility which were required for the test burn, the tests run, and the results of the tests.

ASPEN Plus simulation of coal integrated gasification combined blast furnace slag waste heat recovery system

International Nuclear Information System (INIS)

Duan, Wenjun; Yu, Qingbo; Wang, Kun; Qin, Qin; Hou, Limin; Yao, Xin; Wu, Tianwei

2015-01-01

Highlights: • An integrated system of coal gasification with slag waste heat recovery was proposed. • The goal of BF slag heat saving and emission reduction was achieved by this system. • The optimal parameters were obtained and the waste heat recovery rate reached 83.08%. • About 6.64 kmol/min syngas was produced when using one ton BF slag to provide energy. - Abstract: This article presented a model for the system of coal gasification with steam and blast furnace slag waste heat recovery by using the ASPEN Plus as the simulating and modeling tool. Constrained by mass and energy balance for the entire system, the model included the gasifier used to product syngas at the chemical equilibrium based on the Gibbs free energy minimization approach and the boiler used to recover the heat of the blast furnace slag (BF slag) and syngas. Two parameters of temperature and steam to coal ratio (S/C) were considered to account for their impacts on the Datong coal (DT coal) gasification process. The carbon gasification efficiency (CE), cold gasification efficiency (CGE), syngas product efficiency (PE) and the heating value of syngas produced by 1 kg pulverized coal (HV) were adopted as the indicators to examine the gasification performance. The optimal operating temperature and S/C were 800 °C and 1.5, respectively. At this condition, CE reached above 90% and the maximum values of the CGE, PE and HV were all obtained. Under the optimal operating conditions, 1000 kg/min BF slag, about 40.41 kg/min DT pulverized coal and 77.94 kg/min steam were fed into the gasifier and approximate 6.64 kmol/min syngas could be generated. Overall, the coal was converted to clean syngas by gasification reaction and the BF slag waste heat was also recovered effectively (reached up to 83.08%) in this system, achieving the objective of energy saving and emission reduction

Numerical simulations for the coal/oxidant distribution effects between two-stages for multi opposite burners (MOB) gasifier

International Nuclear Information System (INIS)

Unar, Imran Nazir; Wang, Lijun; Pathan, Abdul Ghani; Mahar, Rasool Bux; Li, Rundong; Uqaili, M. Aslam

2014-01-01

Highlights: • We simulated a double stage 3D entrained flow coal gasifier with multi-opposite burners. • The various reaction mechanisms have evaluated with experimental results. • The effects of coal and oxygen distribution between two stages on the performance of gasifier have investigated. • The local coal to oxygen ratio is affecting the overall efficiency of gasifier. - Abstract: A 3D CFD model for two-stage entrained flow dry feed coal gasifier with multi opposite burners (MOB) has been developed in this paper. At each stage two opposite nozzles are impinging whereas the two other opposite nozzles are slightly tangential. Various numerical simulations were carried out in standard CFD software to investigate the impacts of coal and oxidant distributions between the two stages of the gasifier. Chemical process was described by Finite Rate/Eddy Dissipation model. Heterogeneous and homogeneous reactions were defined using the published kinetic data and realizable k–ε turbulent model was used to solve the turbulence equations. Gas–solid interaction was defined by Euler–Lagrangian frame work. Different reaction mechanism were investigated first for the validation of the model from published experimental results. Then further investigations were made through the validated model for important parameters like species concentrations in syngas, char conversion, maximum inside temperature and syngas exit temperature. The analysis of the results from various simulated cases shows that coal/oxidant distribution between the stages has great influence on the overall performance of gasifier. The maximum char conversion was found 99.79% with coal 60% and oxygen 50% of upper level of injection. The minimum char conversion was observed 95.45% at 30% coal with 40% oxygen at same level. In general with oxygen and coal above or equal to 50% of total at upper injection level has shown an optimized performance

The Conversion of Wiswesser Line Notations to Ring Codes. I. The Conversion of Ring Systems

Science.gov (United States)

Granito, Charles E.; And Others

1972-01-01

The computerized conversion of Wiswesser Line Notations to Ring Codes, using a two-part approach, and the set of computer programs generated for the conversion of ring systems are described. (9 references) (Author)

Coal gasification systems engineering and analysis. Appendix G: Commercial design and technology evaluation

Science.gov (United States)

1980-01-01

A technology evaluation of five coal gasifier systems (Koppers-Totzek, Texaco, Babcock and Wilcox, Lurgi and BGC/Lurgi) and procedures and criteria for evaluating competitive commercial coal gasification designs is presented. The technology evaluation is based upon the plant designs and cost estimates developed by the BDM-Mittelhauser team.

Hydrothermal conversion of South African coal fly ash into pure phase Zeolite Na-P1

CSIR Research Space (South Africa)

Gitari, MW

2016-08-01

Full Text Available South African coal combustion power utilities generate huge amounts of coal fly ash that can be beneficiated into zeolitic products. This chapter reports on the optimization of the presynthesis and synthesis conditions for a pure-phase zeolite Na-P1...

Geographic information system (GIS) representation of coal-bearing areas in India and Bangladesh

Science.gov (United States)

Trippi, Michael H.; Tewalt, Susan J.

2011-01-01

Geographic information system (GIS) information may facilitate energy studies, which in turn provide input for energy policy decisions. Prior to this study, no GIS file representing the occurrence of coal-bearing units in India or Bangladesh was known to exist. This Open-File Report contains downloadable shapefiles representing the coalfields of India and Bangladesh and a limited number of chemical and petrographic analyses of India and Bangladesh coal samples. Also included are maps of India and Bangladesh showing the locations of the coalfields and coal samples in the shapefiles, figures summarizing the stratigraphic units in the coalfields of India and Bangladesh, and a brief report summarizing the stratigraphy and geographic locations of coal-bearing deposits in India and Bangladesh.

Prospects For Coal And Clean Coal Technologies In Kazakhstan

Energy Technology Data Exchange (ETDEWEB)

NONE

2011-12-15