Comparison of volatiles and mosquito capture efficacy for three carbohydrate sources in a yeast-fermentation CO2 generator

Science.gov (United States)

Mosquito surveillance in remote areas with limited access to canisters of CO2 or dry ice will benefit from an effective alternative CO2 source. In this study, we document the differences in mosquito and non-mosquito capture rates from CO2 baited (dry ice or yeast fermentation of carbohydrates) CDC t...

Indirect ultraviolet photodesorption from CO:N2 binary ices — an efficient grain-gas process

International Nuclear Information System (INIS)

Bertin, Mathieu; Poderoso, Hugo A. M.; Michaut, Xavier; Philippe, Laurent; Jeseck, Pascal; Fillion, Jean-Hugues; Fayolle, Edith C.; Linnartz, Harold; Romanzin, Claire; Öberg, Karin I.

2013-01-01

Ultraviolet (UV) ice photodesorption is an important non-thermal desorption pathway in many interstellar environments that has been invoked to explain observations of cold molecules in disks, clouds, and cloud cores. Systematic laboratory studies of the photodesorption rates, between 7 and 14 eV, from CO:N 2 binary ices, have been performed at the DESIRS vacuum UV beamline of the synchrotron facility SOLEIL. The photodesorption spectral analysis demonstrates that the photodesorption process is indirect, i.e., the desorption is induced by a photon absorption in sub-surface molecular layers, while only surface molecules are actually desorbing. The photodesorption spectra of CO and N 2 in binary ices therefore depend on the absorption spectra of the dominant species in the sub-surface ice layer, which implies that the photodesorption efficiency and energy dependence are dramatically different for mixed and layered ices compared with pure ices. In particular, a thin (1-2 ML) N 2 ice layer on top of CO will effectively quench CO photodesorption, while enhancing N 2 photodesorption by a factor of a few (compared with the pure ices) when the ice is exposed to a typical dark cloud UV field, which may help to explain the different distributions of CO and N 2 H + in molecular cloud cores. This indirect photodesorption mechanism may also explain observations of small amounts of complex organics in cold interstellar environments.

A sublimation technique for high-precision measurements of δ13CO2 and mixing ratios of CO2 and N2O from air trapped in ice cores

Directory of Open Access Journals (Sweden)

H. Fischer

2011-07-01

Full Text Available In order to provide high precision stable carbon isotope ratios (δ13CO2 or δ13C of CO2 from small bubbly, partially and fully clathrated ice core samples we developed a new method based on sublimation coupled to gas chromatography-isotope ratio mass spectrometry (GC-IRMS. In a first step the trapped air is quantitatively released from ~30 g of ice and CO2 together with N2O are separated from the bulk air components and stored in a miniature glass tube. In an off-line step, the extracted sample is introduced into a helium carrier flow using a minimised tube cracker device. Prior to measurement, N2O and organic sample contaminants are gas chromatographically separated from CO2. Pulses of a CO2/N2O mixture are admitted to the tube cracker and follow the path of the sample through the system. This allows an identical treatment and comparison of sample and standard peaks. The ability of the method to reproduce δ13C from bubble and clathrate ice is verified on different ice cores. We achieve reproducibilities for bubble ice between 0.05 ‰ and 0.07 ‰ and for clathrate ice between 0.05 ‰ and 0.09 ‰ (dependent on the ice core used. A comparison of our data with measurements on bubble ice from the same ice core but using a mechanical extraction device shows no significant systematic offset. In addition to δ13C, the CO2 and N2O mixing ratios can be volumetrically derived with a precision of 2 ppmv and 8 ppbv, respectively.

Comparison of CO/sub 2/ measurements by two laboratories on air from bubbles in polar ice

Energy Technology Data Exchange (ETDEWEB)

Barnola, J.M.; Raynaud, D.; Neftel, A.; Oeschger, H.

1983-06-02

The CO/sub 2/ content of air enclosed in bubbles in polar ice has been reported by two laboratories (in Grenoble and Bern) to be representative of the atmospheric CO/sub 2/ concentration at the time the ice was formed. Such ice core studies indicate lower concentrations in ice formed at the end of the ice age, around 18,000 yr BP, and several explanations have been proposed for such a change. Both laboratories are currently measuring various ice cores in order to determine the pre-AD 1850 CO/sub 2/ level in the atmosphere, which relates to the partitioning of anthropogenic CO/sub 2/ among the atmospheric, biospheric and oceanic reservoirs. The two laboratories use different ice cores and different analytical procedures and, therefore, there is a need to know to what extent the measurements are quantitatively comparable. The results are presented of a comparison between the two laboratories based on measurements from the same ice core sections, which indicate that the measurements can be compared with great confidence. The results suggest that the mean CO/sub 2/ level recorded by Antartic ice for the period 800-2500 yr BP is about 260 p.p.m.v.

FIRST INFRARED BAND STRENGTHS FOR AMORPHOUS CO{sub 2}, AN OVERLOOKED COMPONENT OF INTERSTELLAR ICES

Energy Technology Data Exchange (ETDEWEB)

Gerakines, Perry A.; Hudson, Reggie L., E-mail: Reggie.Hudson@NASA.gov [Astrochemistry Laboratory, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

2015-08-01

Solid carbon dioxide (CO{sub 2}) has long been recognized as a component of both interstellar and solar system ices, but a recent literature search has revealed significant qualitative and quantitative discrepancies in the laboratory spectra on which the abundances of extraterrestrial CO{sub 2} are based. Here we report new infrared (IR) spectra of amorphous CO{sub 2}-ice along with band intensities (band strengths) of four mid-IR absorptions, the first such results in the literature. A possible thickness dependence for amorphous-CO{sub 2} IR band shapes and positions also is investigated, and the three discordant reports of amorphous CO{sub 2} spectra in the literature are addressed. Applications of our results are discussed with an emphasis on laboratory investigations and results from astronomical observations. A careful comparison with earlier work shows that the IR spectra calculated from several databases for CO{sub 2} ices, all ices being made near 10 K, are not for amorphous CO{sub 2}, but rather for crystalline CO{sub 2} or crystalline-amorphous mixtures.

SYSTEMATIC VARIATIONS IN CO2/H2O ICE ABUNDANCE RATIOS IN NEARBY GALAXIES FOUND WITH AKARI NEAR-INFRARED SPECTROSCOPY

International Nuclear Information System (INIS)

Yamagishi, M.; Kaneda, H.; Ishihara, D.; Oyabu, S.; Onaka, T.; Shimonishi, T.; Suzuki, T.

2015-01-01

We report CO 2 /H 2 O ice abundance ratios in seven nearby star-forming galaxies based on the AKARI near-infrared (2.5–5.0 μm) spectra. The CO 2 /H 2 O ice abundance ratios show clear variations between 0.05 and 0.2 with the averaged value of 0.14 ± 0.01. The previous study on M82 revealed that the CO 2 /H 2 O ice abundance ratios strongly correlate with the intensity ratios of the hydrogen recombination Brα line to the polycyclic aromatic hydrocarbon (PAH) 3.3 μm feature. In the present study, however, we find no correlation for the seven galaxies as a whole due to systematic differences in the relation between CO 2 /H 2 O ice abundance and Brα/PAH 3.3 μm intensity ratios from galaxy to galaxy. This result suggests that there is another parameter that determines the CO 2 /H 2 O ice abundance ratios in a galaxy in addition to the Brα/PAH 3.3 μm ratios. We find that the CO 2 /H 2 O ice abundance ratios positively correlate with the specific star formation rates of the galaxies. From these results, we conclude that CO 2 /H 2 O ice abundance ratios tend to be high in young star-forming galaxies

First estimates of the contribution of CaCO3 precipitation to the release of CO2 to the atmosphere during young sea ice growth

Science.gov (United States)

Geilfus, N.-X.; Carnat, G.; Dieckmann, G. S.; Halden, N.; Nehrke, G.; Papakyriakou, T.; Tison, J.-L.; Delille, B.

2013-01-01

report measurements of pH, total alkalinity, air-ice CO2 fluxes (chamber method), and CaCO3 content of frost flowers (FF) and thin landfast sea ice. As the temperature decreases, concentration of solutes in the brine skim increases. Along this gradual concentration process, some salts reach their solubility threshold and start precipitating. The precipitation of ikaite (CaCO3.6H2O) was confirmed in the FF and throughout the ice by Raman spectroscopy and X-ray analysis. The amount of ikaite precipitated was estimated to be 25 µmol kg-1 melted FF, in the FF and is shown to decrease from 19 to 15 µmol kg-1 melted ice in the upper part and at the bottom of the ice, respectively. CO2 release due to precipitation of CaCO3 is estimated to be 50 µmol kg-1 melted samples. The dissolved inorganic carbon (DIC) normalized to a salinity of 10 exhibits significant depletion in the upper layer of the ice and in the FF. This DIC loss is estimated to be 2069 µmol kg-1 melted sample and corresponds to a CO2 release from the ice to the atmosphere ranging from 20 to 40 mmol m-2 d-1. This estimate is consistent with flux measurements of air-ice CO2 exchange. Our measurements confirm previous laboratory findings that growing young sea ice acts as a source of CO2 to the atmosphere. CaCO3 precipitation during early ice growth appears to promote the release of CO2 to the atmosphere; however, its contribution to the overall release by newly formed ice is most likely minor.

Investigation into solar drying of potato: effect of sample geometry on drying kinetics and CO2 emissions mitigation.

Science.gov (United States)

Tripathy, P P

2015-03-01

Drying experiments have been performed with potato cylinders and slices using a laboratory scale designed natural convection mixed-mode solar dryer. The drying data were fitted to eight different mathematical models to predict the drying kinetics, and the validity of these models were evaluated statistically through coefficient of determination (R(2)), root mean square error (RMSE) and reduced chi-square (χ (2)). The present investigation showed that amongst all the mathematical models studied, the Modified Page model was in good agreement with the experimental drying data for both potato cylinders and slices. A mathematical framework has been proposed to estimate the performance of the food dryer in terms of net CO2 emissions mitigation potential along with unit cost of CO2 mitigation arising because of replacement of different fossil fuels by renewable solar energy. For each fossil fuel replaced, the gross annual amount of CO2 as well as net amount of annual CO2 emissions mitigation potential considering CO2 emissions embodied in the manufacture of mixed-mode solar dryer has been estimated. The CO2 mitigation potential and amount of fossil fuels saved while drying potato samples were found to be the maximum for coal followed by light diesel oil and natural gas. It was inferred from the present study that by the year 2020, 23 % of CO2 emissions can be mitigated by the use of mixed-mode solar dryer for drying of agricultural products.

CO2 and CH4 in sea ice from a subarctic fjord under influence of riverine input

DEFF Research Database (Denmark)

Crabeck, O.; Delille, B.; Thomas, D. N.

2014-01-01

We present CH4 concentration [CH4] and the partial pressure of CO2 (pCO2) in bulk sea ice from subarctic, land-fast sea ice in the Kapisillit fjord, Greenland. The bulk ice [CH4] ranged from 1.8 to 12.1 nmol L−1, which corresponds to a partial pressure range of 3 to 28 ppmv. This is markedly higher......-saturated compared to the atmosphere (390 ppmv). Our study adds to the few existing studies of CH4 and CO2 in sea ice and concludes that sub-arctic sea can be a sink for atmospheric CO2, while being a net source of CH4. Processes related to the freezing and melting of sea ice represents large unknowns...... to the exchange of CO2 but also CH4. It is therefore imperative to assess the consequences of these unknowns through further field campaigns and targeted research under other sea ice conditions at both hemispheres....

THE THERMAL EVOLUTION OF ICES IN THE ENVIRONMENTS OF NEWLY FORMED STARS: THE CO2 DIAGNOSTIC

International Nuclear Information System (INIS)

Cook, A. M.; Whittet, D. C. B.; Shenoy, S. S.; Gerakines, P. A.; White, D. W.; Chiar, J. E.

2011-01-01

Archival data from the Infrared Spectrometer of the Spitzer Space Telescope are used to study the 15 μm absorption feature of solid CO 2 toward 28 young stellar objects (YSOs) of approximately solar mass. Fits to the absorption profile using laboratory spectra enable categorization according to the degree of thermal processing of the ice matrix that contains the CO 2 . The majority of YSOs in our sample (20 out of 28) are found to be consistent with a combination of polar (H 2 O-rich) and nonpolar (CO-rich) ices at low temperature; the remainder exhibit profile structure consistent with partial crystallization as the result of significant heating. Ice-phase column densities of CO 2 are determined and compared with those of other species. Lines of sight with crystallization signatures in their spectra are found to be systematically deficient in solid-phase CO, as expected if CO is being sublimated in regions where the ices are heated to crystallization temperatures. Significant variation is found in the CO 2 abundance with respect to both H 2 O (the dominant ice constituent) and total dust column (quantified by the extinction, A V ). YSOs in our sample display typically higher CO 2 concentrations (independent of evidence for thermal processing) in comparison to quiescent regions of the prototypical cold molecular cloud. This suggests that enhanced CO 2 production is driven by photochemical reactions in proximity to some YSOs, and that photoprocessing and thermal processing may occur independently.

Application of ozonated dry ice (ALIGAL™ Blue Ice) for packaging and transport in the food industry.

Science.gov (United States)

Fratamico, Pina M; Juneja, Vijay; Annous, Bassam A; Rasanayagam, Vasuhi; Sundar, M; Braithwaite, David; Fisher, Steven

2012-05-01

Dry ice is used by meat and poultry processors for temperature reduction during processing and for temperature maintenance during transportation. ALIGAL™ Blue Ice (ABI), which combines the antimicrobial effect of ozone (O(3)) along with the high cooling capacity of dry ice, was investigated for its effect on bacterial reduction in air, in liquid, and on food and glass surfaces. Through proprietary means, O(3) was introduced to produce dry ice pellets to a concentration of 20 parts per million (ppm) by total weight. The ABI sublimation rate was similar to that of dry ice pellets under identical conditions, and ABI was able to hold the O(3) concentration throughout the normal shelf life of the product. Challenge studies were performed using different microorganisms, including E. coli, Campylobacter jejuni, Salmonella, and Listeria, that are critical to food safety. ABI showed significant (P Food Technologists®

Ikaite crystal distribution in winter sea ice and implications for CO2 system dynamics

Science.gov (United States)

Rysgaard, S.; Søgaard, D. H.; Cooper, M.; Pućko, M.; Lennert, K.; Papakyriakou, T. N.; Wang, F.; Geilfus, N. X.; Glud, R. N.; Ehn, J.; McGinnis, D. F.; Attard, K.; Sievers, J.; Deming, J. W.; Barber, D.

2013-04-01

The precipitation of ikaite (CaCO3 ⋅ 6H2O) in polar sea ice is critical to the efficiency of the sea ice-driven carbon pump and potentially important to the global carbon cycle, yet the spatial and temporal occurrence of ikaite within the ice is poorly known. We report unique observations of ikaite in unmelted ice and vertical profiles of ikaite abundance and concentration in sea ice for the crucial season of winter. Ice was examined from two locations: a 1 m thick land-fast ice site and a 0.3 m thick polynya site, both in the Young Sound area (74° N, 20° W) of NE Greenland. Ikaite crystals, ranging in size from a few μm to 700 μm, were observed to concentrate in the interstices between the ice platelets in both granular and columnar sea ice. In vertical sea ice profiles from both locations, ikaite concentration determined from image analysis, decreased with depth from surface-ice values of 700-900 μmol kg-1 ice (~25 × 106 crystals kg-1) to values of 100-200 μmol kg-1 ice (1-7 × 106 crystals kg-1) near the sea ice-water interface, all of which are much higher (4-10 times) than those reported in the few previous studies. Direct measurements of total alkalinity (TA) in surface layers fell within the same range as ikaite concentration, whereas TA concentrations in the lower half of the sea ice were twice as high. This depth-related discrepancy suggests interior ice processes where ikaite crystals form in surface sea ice layers and partly dissolve in layers below. Melting of sea ice and dissolution of observed concentrations of ikaite would result in meltwater with a pCO2 of <15 μatm. This value is far below atmospheric values of 390 μatm and surface water concentrations of 315 μatm. Hence, the meltwater increases the potential for seawater uptake of CO2.

Modelling the effects of ice-sheet activity on CO2 outgassing by Icelandic volcanoes

Science.gov (United States)

Armitage, J. J.; Ferguson, D.; Petersen, K. D.; Creyts, T. T.

2017-12-01

Glacial cycles may play a significant role in mediating the flux of magmatic CO2 between the Earth's mantle and atmosphere. In Iceland, it is thought that late-Pleistocene deglaciation led to a significant volcanic pulse, evidenced by increased post-glacial lava volumes and changes in melt chemistry consistent with depressurization. Investigating the extent to which glacial activity may have affected volcanic CO2 emissions from Iceland, and crucially over what timescale, requires detailed knowledge of how the magma system responded to the growth and collapse of the ice-sheet before and after the LGM. To investigate this, we coupled a model of magma generation and transport with a history of ice-sheet activity. Our results show that the emplacement and removal of the LGM ice-sheet likely led to two significant pulses of magmatic CO2. The first, and most significant of these, is associated with ice-sheet growth and occurs as the magma system recovers from glacial loading. This recovery happens from the base of the melting region upwards, producing a pulse of CO2 rich magma that is predicted to reach the surface around 20 ka after the loading event, close in time to the LGM. The second peak in CO2 output occurs abruptly following deglaciation as a consequence of increased rates of melt generation and transport in the shallow mantle. Although these post-glacial melts are relatively depleted in CO2, the increase in magma flux leads to a short-lived period of elevated CO2 emissions. Our results therefore suggest a negative feedback, whereby ice-sheet growth produces a delayed pulse of magmatic CO2, which, in addition to increased geothermal heat flux, may contribute towards driving deglaciation, which itself then causes further magmatism and CO2 outgassing. This model is consistent with the seismic structure of the asthenosphere below Iceland, and the established compositional and volumetric trends for sub- and post-glacial volcanism in Iceland. These trends show that

Air-sea flux of CO2 in arctic coastal waters influenced by glacial melt water and sea ice

DEFF Research Database (Denmark)

Sejr, Mikael Kristian; Krause-Jensen, Dorte; Rysgaard, Søren

2011-01-01

Annual air–sea exchange ofCO2 inYoung Sound,NEGreenlandwas estimated using pCO2 surface-water measurements during summer (2006–2009) and during an ice-covered winter 2008. All surface pCO2 values were below atmospheric levels indicating an uptake of atmospheric CO2. During sea ice formation...... and thereby efficiently blocked air–sea CO2 exchange. During sea ice melt, dissolution of CaCO3 combined with primary production and strong stratification of the water column acted to lower surface-water pCO2 levels in the fjord. Also, a large input of glacial melt water containing geochemically reactive...... year-to-year variation in annual gas exchange....

Ikaite crystal distribution in Arctic winter sea ice and implications for CO2 system dynamics

Science.gov (United States)

Rysgaard, S.; Søgaard, D. H.; Cooper, M.; Pućko, M.; Lennert, K.; Papakyriakou, T. N.; Wang, F.; Geilfus, N. X.; Glud, R. N.; Ehn, J.; McGinnnis, D. F.; Attard, K.; Sievers, J.; Deming, J. W.; Barber, D.

2012-12-01

The precipitation of ikaite (CaCO3·6H2O) in polar sea ice is critical to the efficiency of the sea ice-driven carbon pump and potentially important to the global carbon cycle, yet the spatial and temporal occurrence of ikaite within the ice is poorly known. We report unique observations of ikaite in unmelted ice and vertical profiles of ikaite abundance and concentration in sea ice for the crucial season of winter. Ice was examined from two locations: a 1 m thick land-fast ice site and a 0.3 m thick polynya site, both in the Young Sound area (74° N, 20° W) of NE Greenland. Ikaite crystals, ranging in size from a few µm to 700 µm were observed to concentrate in the interstices between the ice platelets in both granular and columnar sea ice. In vertical sea-ice profiles from both locations, ikaite concentration determined from image analysis, decreased with depth from surfaceice values of 700-900 µmol kg-1 ice (~ 25 × 106 crystals kg-1) to bottom-layer values of 100-200 µmol kg-1 ice (1-7 × 106 kg-1), all of which are much higher (4-10 times) than those reported in the few previous studies. Direct measurements of total alkalinity (TA) in surface layers fell within the same range as ikaite concentration whereas TA concentrations in bottom layers were twice as high. This depth-related discrepancy suggests interior ice processes where ikaite crystals form in surface sea ice layers and partly dissolved in bottom layers. From these findings and model calculations we relate sea ice formation and melt to observed pCO2 conditions in polar surface waters, and hence, the air-sea CO2 flux.

Landscape Evolution and the Reincarnation of the Residual CO2 Ice Cap of Mars

Science.gov (United States)

Byrne, S.; Zuber, M.

2006-12-01

Observations of the southern residual CO2 cap of Mars reveal a wide range of landforms including flat-floored quasi-circular pits with steep walls (dubbed Swiss-cheese features). Interannual comparisons show that these depressions are expanding laterally at rates of ~2m/yr to ~4m/yr, prompting suggestions of climate change. The residual CO2 ice cap is up to 10m thick and underlain by an involatile basement, it also contains layers roughly 2m thick representing different accumulation episodes in the recent past. Changes in the appearance of the residual ice between the Mariner 9 and Viking missions indicate that the top-most layer was deposited in that time-frame, soon after the global dust storm of 1971. The spatial density of the Swiss-cheese features, and the rate at which they expand, mean that it is unlikely that any part of the residual ice cap is older than a few centuries. Given this, we may ask: how can there be a residual cap present today for us to observe? To answer this and other questions we have developed a model to examine the evolution of a CO2 ice landscape. This model reproduces the morphologies and expansion rates seen in the actual residual CO2 ice cap. Our model results indicate that the fate of CO2 ice surfaces is controlled by their surface roughness. Surface roughness always increases with time, which results in an unstable situation. When the surface roughness exceeds a critical point small pits can begin to develop. The walls of these pits rapidly steepen and begin retreating which enlarges and deepens the pit. This situation always occurs even if the surface of the CO2 slab has a high enough albedo to have a net mass gain each year. Once these pits begin expanding they quickly erode the entire ice slab. When the underlying non-CO2 material is exposed, it will not frost over again if Mars were to repeat like clockwork every year. We conclude that interannual climatic variability is actually a requirement for the continued existence of a

Ikaite crystals in melting sea ice - implications for pCO2 and pH levels in Arctic surface waters

Science.gov (United States)

Rysgaard, S.; Glud, R. N.; Lennert, K.; Cooper, M.; Halden, N.; Leakey, R. J. G.; Hawthorne, F. C.; Barber, D.

2012-08-01

A major issue of Arctic marine science is to understand whether the Arctic Ocean is, or will be, a source or sink for air-sea CO2 exchange. This has been complicated by the recent discoveries of ikaite (a polymorph of CaCO3·6H2O) in Arctic and Antarctic sea ice, which indicate that multiple chemical transformations occur in sea ice with a possible effect on CO2 and pH conditions in surface waters. Here, we report on biogeochemical conditions, microscopic examinations and x-ray diffraction analysis of single crystals from a melting 1.7 km2 (0.5-1 m thick) drifting ice floe in the Fram Strait during summer. Our findings show that ikaite crystals are present throughout the sea ice but with larger crystals appearing in the upper ice layers. Ikaite crystals placed at elevated temperatures disintegrated into smaller crystallites and dissolved. During our field campaign in late June, melt reduced the ice floe thickness by 0.2 m per week and resulted in an estimated 3.8 ppm decrease of pCO2 in the ocean surface mixed layer. This corresponds to an air-sea CO2 uptake of 10.6 mmol m-2 sea ice d-1 or to 3.3 ton km-2 ice floe week-1. This is markedly higher than the estimated primary production within the ice floe of 0.3-1.3 mmol m-2 sea ice d-1. Finally, the presence of ikaite in sea ice and the dissolution of the mineral during melting of the sea ice and mixing of the melt water into the surface oceanic mixed layer accounted for half of the estimated pCO2 uptake.

Buried CO2 Ice traces in South Polar Layered Deposits of Mars detected by radar sounder

Science.gov (United States)

Castaldo, L.; Mège, D.; Orosei, R.; Séjourné, A.

2014-12-01

SHARAD (SHAllow RADar) is the subsurface sounding radar provided by the Italian Space Agency (ASI) as a facility instrument to NASA's 2005 Mars Reconnaissance Orbiter (MRO). The Reduced Data Record of SHARAD data covering the area of the South Polar Layered Deposits (SPLD), has been used. The elaboration and interpretation of the data, aimed to estimate electromagnetic properties of surface layers, has been performed in terms of permittivity. The theory of electromagnetic scattering from fractal surfaces, and the estimation of geometric parameters from topographic data by Mars Orbiter Laser Altimeter (MOLA) which was one of five instruments on board the Mars Global Surveyor (MGS) spacecraft, has been used. A deep analysis of inversion has been made on all Mars and extended to the South Polar Caps in order to extract the area with a permittivity constant of CO2 ice. Several corrections have been applied to the data, moreover the calibration of the signal requires the determination of a constant that takes into account the power gain due to the radar system and the surface in order to compensate the power losses due to the orbitographic phenomena. The determination of regions with high probability of buried CO2 ice in the first layer of the Martian surface, is obtained extracting the real part of the permittivity constant of the CO2 ice (~2), estimated by other means. The permittivity of CO2ice is extracted from the Global Permittivity Map of Mars using the global standard deviation of itself as following: ɛCO2ice=ɛCO2ice+ Σ (1)where Σ=±std(ɛMapMars)/2Figure 1(a) shows the south polar areas where the values of the permittivity point to the possibility of a CO2 ice layer. Figure 1(b) is the corresponding geologic map. The comparison between the two maps indicates that the area with probable buried CO2 overlaps Hesperian and Amazonian polar units (Hp, Hesperian plains-forming deposits marked by narrow sinuous, anabranching ridges and irregular depressions, and

Prediction of dry ice mass for firefighting robot actuation

Science.gov (United States)

Ajala, M. T.; Khan, Md R.; Shafie, A. A.; Salami, MJE; Mohamad Nor, M. I.

2017-11-01

The limitation in the performance of electric actuated firefighting robots in high-temperature fire environment has led to research on the alternative propulsion system for the mobility of firefighting robots in such environment. Capitalizing on the limitations of these electric actuators we suggested a gas-actuated propulsion system in our earlier study. The propulsion system is made up of a pneumatic motor as the actuator (for the robot) and carbon dioxide gas (self-generated from dry ice) as the power source. To satisfy the consumption requirement (9cfm) of the motor for efficient actuation of the robot in the fire environment, the volume of carbon dioxide gas, as well as the corresponding mass of the dry ice that will produce the required volume for powering and actuation of the robot, must be determined. This article, therefore, presents the computational analysis to predict the volumetric requirement and the dry ice mass sufficient to power a carbon dioxide gas propelled autonomous firefighting robot in a high-temperature environment. The governing equation of the sublimation of dry ice to carbon dioxide is established. An operating time of 2105.53s and operating pressure ranges from 137.9kPa to 482.65kPa were achieved following the consumption rate of the motor. Thus, 8.85m3 is computed as the volume requirement of the CAFFR while the corresponding dry ice mass for the CAFFR actuation ranges from 21.67kg to 75.83kg depending on the operating pressure.

The fate of the Greenland Ice Sheet in a geoengineered, high CO2 world

International Nuclear Information System (INIS)

Irvine, Peter J; Lunt, Daniel J; Stone, Emma J; Ridgwell, Andy

2009-01-01

Solar radiation management (SRM) geoengineering has been proposed as one means of helping avoid the occurrence of dangerous climate change and undesirable state transitions ('tipping points') in the Earth system. The irreversible melting of the Greenland Ice Sheet is a case in point-a state transition that could occur as a result of CO 2 -driven elevated global temperatures, and one leading to potentially catastrophic sea-level rise. SRM schemes such as the creation of a 'sunshade' or injection of sulfate aerosols into the stratosphere could reduce incoming solar radiation, and in theory balance, in a global mean, the greenhouse warming resulting from elevated concentrations of CO 2 in the atmosphere. Previous work has highlighted that a geoengineered world would have: warming towards the poles, cooling in the tropics, and a reduction in the global hydrological cycle, which may have important implications for the Greenland Ice Sheet. Using a fully coupled global climate model in conjunction with an ice sheet model, we assess the consequences for the mass balance of the Greenland Ice Sheet of the reorganization of climate patterns by the combination of high CO 2 and geoengineering. We find that Greenland surface temperature and precipitation anomalies, compared to the pre-industrial situation, decrease almost linearly with increasing levels of SRM geoengineering, but that these combine to create a highly non-linear response of the ice sheet. The substantial melting of the Greenland Ice Sheet predicted for four times pre-industrial CO 2 levels is prevented in our model with only a partial application of SRM, and hence without having to fully restore the global average temperature back to pre-industrial levels. This suggests that the degree of SRM geoengineering required to mitigate the worst impacts of greenhouse warming, such as sea-level rise, need not be as extensive as generally assumed.

Atmospheric CO2 variations over the last three glacial-interglacial climatic cycles deduced from the Dome Fuji deep ice core, Antarctica using a wet extraction technique

International Nuclear Information System (INIS)

Kawamura, Kenji; Nakazawa, Takakiyo; Aoki, Shuji

2003-01-01

A deep ice core drilled at Dome Fuji, East Antarctica was analyzed for the CO 2 concentration using a wet extraction method in order to reconstruct its atmospheric variations over the past 320 kyr, which includes three full glacial-interglacial climatic cycles, with a mean time resolution of about 1.1 kyr. The CO 2 concentration values derived for the past 65 kyr are very close to those obtained from other Antarctic ice cores using dry extraction methods, although the wet extraction method is generally thought to be inappropriate for the determination of the CO 2 concentration. The comparison between the CO 2 and Ca 2+ concentrations deduced from the Dome Fuji core suggests that calcium carbonate emitted from lands was mostly neutralized in the atmosphere before reaching the central part of Antarctica, or that only a small part of calcium carbonate was involved in CO 2 production during the wet extraction process. The CO 2 concentration for the past 320 kyr deduced from the Dome Fuji core varies between 190 and 300 ppmv, showing clear glacial-interglacial variations similar to the result of the Vostok ice core. However, for some periods, the concentration values of the Dome Fuji core are higher by up to 20 ppmv than those of the Vostok core. There is no clear indication that such differences are related to variations of chemical components of Ca 2+ , microparticle and acidity of the Dome Fuji core

Ikaite crystal distribution in winter sea ice and implications for CO2 system dynamics

DEFF Research Database (Denmark)

Rysgaard, Søren; Søgaard, D.H.; Cooper, M.

2013-01-01

The precipitation of ikaite (CaCO3 ⋅ 6H2O) in polar sea ice is critical to the efficiency of the sea ice-driven carbon pump and potentially important to the global carbon cycle, yet the spatial and temporal occurrence of ikaite within the ice is poorly known. We report unique observations of ikai...

Ikaite crystals in melting sea ice – implications for pCO2 and pH levels in Arctic surface waters

Directory of Open Access Journals (Sweden)

R. J. G. Leakey

2012-08-01

Full Text Available A major issue of Arctic marine science is to understand whether the Arctic Ocean is, or will be, a source or sink for air–sea CO2 exchange. This has been complicated by the recent discoveries of ikaite (a polymorph of CaCO3·6H2O in Arctic and Antarctic sea ice, which indicate that multiple chemical transformations occur in sea ice with a possible effect on CO2 and pH conditions in surface waters. Here, we report on biogeochemical conditions, microscopic examinations and x-ray diffraction analysis of single crystals from a melting 1.7 km2 (0.5–1 m thick drifting ice floe in the Fram Strait during summer. Our findings show that ikaite crystals are present throughout the sea ice but with larger crystals appearing in the upper ice layers. Ikaite crystals placed at elevated temperatures disintegrated into smaller crystallites and dissolved. During our field campaign in late June, melt reduced the ice floe thickness by 0.2 m per week and resulted in an estimated 3.8 ppm decrease of pCO2 in the ocean surface mixed layer. This corresponds to an air–sea CO2 uptake of 10.6 mmol m−2 sea ice d−1 or to 3.3 ton km−2 ice floe week−1. This is markedly higher than the estimated primary production within the ice floe of 0.3–1.3 mmol m−2 sea ice d−1. Finally, the presence of ikaite in sea ice and the dissolution of the mineral during melting of the sea ice and mixing of the melt water into the surface oceanic mixed layer accounted for half of the estimated pCO2 uptake.

Parameterization of atmosphere-surface exchange of CO₂ over sea ice

DEFF Research Database (Denmark)

Sørensen, L. L.; Jensen, B.; Glud, Ronnie N.

2014-01-01

are discussed. We found the flux to be small during the late winter with fluxes in both directions. Not surprisingly we find that the resistance across the surface controls the fluxes and detailed knowledge of the brine volume and carbon chemistry within the brines as well as knowledge of snow cover and carbon...... chemistry in the ice are essential to estimate the partial pressure of pCO2 and CO2 flux. Further investigations of surface structure and snow cover and driving parameters such as heat flux, radiation, ice temperature and brine processes are required to adequately parameterize the surface resistance....

Interannual observations and quantification of summertime H2O ice deposition on the Martian CO2 ice south polar cap

Science.gov (United States)

Brown, Adrian J.; Piqueux, Sylvain; Titus, Timothy N.

2014-01-01

The spectral signature of water ice was observed on Martian south polar cap in 2004 by the Observatoire pour l'Mineralogie, l'Eau les Glaces et l'Activite (OMEGA) ( Bibring et al., 2004). Three years later, the OMEGA instrument was used to discover water ice deposited during southern summer on the polar cap ( Langevin et al., 2007). However, temporal and spatial variations of these water ice signatures have remained unexplored, and the origins of these water deposits remains an important scientific question. To investigate this question, we have used observations from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) instrument on the Mars Reconnaissance Orbiter (MRO) spacecraft of the southern cap during austral summer over four Martian years to search for variations in the amount of water ice. We report below that for each year we have observed the cap, the magnitude of the H2O ice signature on the southern cap has risen steadily throughout summer, particularly on the west end of the cap. The spatial extent of deposition is in disagreement with the current best simulations of deposition of water ice on the south polar cap (Montmessin et al., 2007). This increase in water ice signatures is most likely caused by deposition of atmospheric H2O ice and a set of unusual conditions makes the quantification of this transport flux using CRISM close to ideal. We calculate a ‘minimum apparent‘ amount of deposition corresponding to a thin H2O ice layer of 0.2 mm (with 70% porosity). This amount of H2O ice deposition is 0.6–6% of the total Martian atmospheric water budget. We compare our ‘minimum apparent’ quantification with previous estimates. This deposition process may also have implications for the formation and stability of the southern CO2 ice cap, and therefore play a significant role in the climate budget of modern day Mars.

In search of in-situ radiocarbon in Law Dome ice and firn

CERN Document Server

Smith, A M; Etheridge, D M; Lowe, D C; Hua, Q; Trudinger, C M; Zoppi, U; El-Cheikh, A

2000-01-01

Results of AMS radiocarbon measurements on CO and CO sub 2 separated from firn air directly pumped from the ice sheet, and on CO sub 2 separated from air extracted from ice cores by a dry grating technique, are presented. The firn air samples and ice cores used in this study were collected from the region of Law Dome, Antarctica. No evidence of in-situ sup 1 sup 4 CO sub 2 was found in the firn air samples or the ice core air samples from one site although a slight enhancement of sup 1 sup 4 CO above expected polar atmospheric concentrations was observed for some firn air samples. A clear in-situ sup 1 sup 4 CO sub 2 signal for ice pre-dating the radiocarbon bomb pulse was found, however, in air samples extracted from an ice core from a second site. We compare these results and propose an hypothesis to explain this apparent contradiction. The degree to which in-situ sup 1 sup 4 C is released from the ice crystals during trapping and bubble formation is considered and discussed. The selectivity of the dry grat...

Production of CO-rich Hydrogen Gas from Methane Dry Reforming over Co/CeO2 Catalyst

Directory of Open Access Journals (Sweden)

Bamidele V. Ayodele

2016-08-01

Full Text Available Production of CO-rich hydrogen gas from methane dry reforming was investigated over CeO2-supported Co catalyst. The catalyst was synthesized by wet impregnation and subsequently characterized by field emission scanning electron microscope (FESEM, energy dispersion X-ray spectroscopy (EDX, liquid N2 adsorption-desorption, X-ray diffraction (XRD, Fourier transform infrared spectroscopy (FTIR and thermogravimetric analysis (TGA for the structure, surface and thermal properties. The catalytic activity test of the Co/CeO2 was investigated between 923-1023 K under reaction conditions in a stainless steel fixed bed reactor. The composition of the products (CO2 and H2 from the methane dry reforming reaction was measured by gas chromatography (GC coupled with thermal conductivity detector (TCD. The effects of feed ratios and reaction temperatures were investigated on the catalytic activity toward product selectivity, yield, and syngas ratio. Significantly, the selectivity and yield of both H2 and CO increases with feed ratio and temperature. However, the catalyst shows higher activity towards CO selectivity. The highest H2 and CO selectivity of 19.56% and 20.95% respectively were obtained at 1023 K while the highest yield of 41.98% and 38.05% were recorded for H2 and CO under the same condition. Copyright © 2016 BCREC GROUP. All rights reserved Received: 21st January 2016; Revised: 23rd February 2016; Accepted: 23rd February 2016 How to Cite: Ayodele, B.V., Khan, M.R., Cheng, C. K. (2016. Production of CO-rich Hydrogen Gas from Methane Dry Reforming over Co/CeO2 Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (2: 210-219 (doi:10.9767/bcrec.11.2.552.210-219 Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.2.552.210-219

Dry ice blasting as a substitution for the conventional electroplating pre-treatments

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Uhlmann Eckart

2016-01-01

Full Text Available For high quality electroplated products, surfaces must be thoroughly pre-treated. For this purpose electroplating currently needs a variety of chemical baths. The used chemicals are injurious to health and harmful to the environment. In addition, the conventional pre-treatment has a long process time which results in high costs. Dry ice blasting alone or in combination with other processes has the potential to completely substitute these conventional pre-treatment processes. Three process sequences as pre-treatment methods prior to electroplating were investigated on the aluminium alloys AlSi12 and AlMg3. The used processes are dry ice blasting, tempering during dry ice blasting and glass bead blasting followed by dry ice blasting. The influence of the parameters on the surface roughness, surface topography and surface tension of the workpieces was examined. A model to describe the correlation between the dry ice blasting parameters and surface parameters was developed. Finally, an adhesion test of electroplated specimen was conducted in order to determine the suitability of these alternative pre-treatment processes.

Trapping of CH4, CO, and CO2 in Amorphous Water Ice

Science.gov (United States)

Mastrapa, R. M. E.; Brown, R. H.; Anicich, V. G.; Cohen, B. A.; Dai, W.; Lunine, J. I.

1999-09-01

In this study, CO, CH4, and CO2 were trapped in H2O at temperatures as low as 20 K and pressures between 10-5 and 10-8 Torr. IR spectra were taken of each sample before sublimation to confirm the presence of volatiles. The samples were then heated at rates from 0.25 K/min to 1 K/min and the escape ranges were measured with a mass spectrometer. The volatiles escaped from the ice mixtures in temperature ranges similar to those found in previous work (1, 2, 3), namely 48-52 K, 145-160 K, 170-185 K. H2O is released from 150 K to 185 K. However, the temperature range of escape is strongly dependent on deposition temperature and heating rate. If the deposition temperature is below the point where the solid volatile rapidly sublimates in the ambient environment of our experiment, then the first range of volatile escape is centered around it's sublimation point, and there is little of the volatile remaining from 170-185 K. The location of the third escape range shifts to lower temperatures with slower sublimation rate. It was determined that 0.5 K/min is the ideal sample heating rate to determine these escape ranges. In our data, the infrared spectrum of CO trapped in water ice shows a splitting of the 2145 cm-1 solid CO line into two bands at 2343 cm-1 and 2135 cm-1. These shifts are similar to those seen by Sandford, et al. (4). (1) Bar-Nun, A., G. Herman, D. Laufer, and M. L. Rappaport, (1985), Icarus, 63, 317-332. (2) Bar-Nun, A., J. Dror, E. Kochavi, and D. Laufer, (1987), Physical Review B, 35, no. 5, 2427-2435. (3) Hudson, R. L., and B. Donn, (1991), Icarus, 94, 326-332. (4) Sandford, S. A., L. J. Allamandola, A. G. G. M. Tielens, and G. J. Valero, (1988), Astrophysical Journal, 329, 498-510.

Evaluation of supercritical CO2 dried cellulose aerogels as nano-biomaterials

Science.gov (United States)

Lee, Sinah; Kang, Kyu-Young; Jeong, Myung-Joon; Potthast, Antje; Liebner, Falk

2017-10-01

Cellulose is the renewable, biodegradable and abundant resource and is suggested as an alternative material to silica due to the high price and environmental load of silica. The first step for cellulose aerogel production is to dissolve cellulose, and hydrated calcium thiocyanate molten salt is one of the most effective solvents for preparing porous material. Cellulose aerogels were prepared from dissolved cellulose samples of different degree of polymerization (DP) and drying methods, and tested with shrinkage, density and mechanical strength. Supercritical CO2 dried cellulose aerogels shrank less compared to freeze-dried cellulose aerogels, whereas the densities were increased according to the DP increases in both cellulose aerogels. Furthermore, scanning electron microscope (SEM) images showed that the higher DP cellulose aerogels were more uniform with micro-porous structure. Regarding the mechanical strength of cellulose aerogels, supercritical CO2 dried cellulose aerogels with higher molecular weight were much more solid.

CO-ices in embedded Young Stellar Objects

Science.gov (United States)

Teixeira, Teresa Cláeira V. S.

1998-09-01

significance of the results is discussed. Excellent fits to the nonpolar component of the CO-ices along the observed lines-of-sight are produced with ion irradiated pure CO ices. The possible origin of the ion irradiation is discussed, covering flares on the YSOs, cosmic rays and X-ray and UV processing. Predictions are made for the abundance of CO2 and methanol in the mantles. Furthermore, a comparison is made between the results of observations of CO and H2 O ices towards the Taurus and Ophiuchus dark clouds. The column densities of the ices are compared with the visual extinction, Av, through the clouds, and with the 1.3mm continuum emission from the YSOs. The inclusion of the objects in Taurus observed in this work resulted in the appearance of a discontinuity in the relation between the water-ice column density and Av, at the value of Av for which the optical depth at 3 microns (the wavelength of the water-ice absorption feature) is unity. Finally, all the observations and results discussed throughout the thesis are brought together to address their implications in the current understanding of the conditions in Taurus and Ophiuchus. Thesis and published paper available at http://www.obs.aau.dk/~tct/

Ikaite crystal distribution in Arctic winter sea ice and implications for CO2 system dynamics

DEFF Research Database (Denmark)

Rysgaard, Søren; Søgaard, D. H.; Cooper, M.

2012-01-01

The precipitation of ikaite (CaCO3·6H2O) in polar sea ice is critical to the efficiency of the sea ice-driven carbon pump and potentially important to the global carbon cycle, yet the spatial and temporal occurrence of ikaite within the ice is poorly known. We report unique observations of ikaite...

Low pCO2 under sea-ice melt in the Canada Basin of the western Arctic Ocean

Science.gov (United States)

Kosugi, Naohiro; Sasano, Daisuke; Ishii, Masao; Nishino, Shigeto; Uchida, Hiroshi; Yoshikawa-Inoue, Hisayuki

2017-12-01

In September 2013, we observed an expanse of surface water with low CO2 partial pressure (pCO2sea) (Ocean. The large undersaturation of CO2 in this region was the result of massive primary production after the sea-ice retreat in June and July. In the surface of the Canada Basin, salinity was low ( 20 µmol kg-1) in the subsurface low pCO2sea layer in the Canada Basin indicated significant net primary production undersea and/or in preformed condition. If these low pCO2sea layers surface by wind mixing, they will act as additional CO2 sinks; however, this is unlikely because intensification of stratification by sea-ice melt inhibits mixing across the halocline.

Experimental investigation of insolation-driven dust ejection from Mars' CO2 ice caps

Science.gov (United States)

Kaufmann, E.; Hagermann, A.

2017-01-01

Mars' polar caps are - depending on hemisphere and season - partially or totally covered with CO2 ice. Icy surfaces such as the polar caps of Mars behave differently from surfaces covered with rock and soil when they are irradiated by solar light. The latter absorb and reflect incoming solar radiation within a thin layer beneath the surface. In contrast, ices are partially transparent in the visible spectral range and opaque in the infrared. Due to this fact, the solar radiation can penetrate to a certain depth and raise the temperature of the ice or dust below the surface. This may play an important role in the energy balance of icy surfaces in the solar system, as already noted in previous investigations. We investigated the temperature profiles inside CO2 ice samples including a dust layer under Martian conditions. We have been able to trigger dust eruptions, but also demonstrated that these require a very narrow range of temperature and ambient pressure. We discuss possible implications for the understanding of phenomena such as arachneiform patterns or fan shaped deposits as observed in Mars' southern polar region.

Dynamic ikaite production and dissolution in sea ice - control by temperature, salinity and pCO2 conditions

Science.gov (United States)

Rysgaard, S.; Wang, F.; Galley, R. J.; Grimm, R.; Lemes, M.; Geilfus, N.-X.; Chaulk, A.; Hare, A. A.; Crabeck, O.; Else, B. G. T.; Campbell, K.; Papakyriakou, T.; Sørensen, L. L.; Sievers, J.; Notz, D.

2013-12-01

Ikaite is a hydrous calcium carbonate mineral (CaCO3 · 6H2O). It is only found in a metastable state, and decomposes rapidly once removed from near-freezing water. Recently, ikaite crystals have been found in sea ice and it has been suggested that their precipitation may play an important role in air-sea CO2 exchange in ice-covered seas. Little is known, however, of the spatial and temporal dynamics of ikaite in sea ice. Here we present evidence for highly dynamic ikaite precipitation and dissolution in sea ice grown at an out-door pool of the Sea-ice Environmental Research Facility (SERF). During the experiment, ikaite precipitated in sea ice with temperatures below -3 °C, creating three distinct zones of ikaite concentrations: (1) a mm to cm thin surface layer containing frost flowers and brine skim with bulk concentrations of > 2000 μmol kg-1, (2) an internal layer with concentrations of 200-400 μmol kg-1 and (3) a~bottom layer with concentrations of ikaite crystals under acidic conditions. Manual removal of the snow cover allowed the sea ice to cool and brine salinities to increase, resulting in rapid ikaite precipitation. The modeled (FREZCHEM) ikaite concentrations were in the same order of magnitude as observations and suggest that ikaite concentration in sea ice increase with decreasing temperatures. Thus, varying snow conditions may play a key role in ikaite precipitation and dissolution in sea ice. This will have implications for CO2 exchange with the atmosphere and ocean.

The Radiolytic Destruction of Glycine Diluted in H2O and CO2 Ice: Implications for Mars and Other Planetary Environments

Science.gov (United States)

Gerakines, Perry A.; Hudson, R. L.

2013-10-01

Future missions to Mars and other planetary surfaces will probe under the surfaces of these worlds for signs of organic chemistry. In previous studies we have shown that glycine and other amino acids have radiolytic destruction rates that depend on temperature and on dilution within an H2O ice matrix (Gerakines et al., 2012; Gerakines and Hudson 2013). In the new work presented here, we have examined the destruction of glycine diluted in CO2 ice at various concentrations and irradiated with protons at 0.8 MeV, typical of cosmic rays and solar energetic particles. Destruction rates for glycine were measured by infrared spectroscopy in situ, without removing or warming the ice samples. New results on the half life of glycine in solid CO2 will be compared to those found in H2O ice matrices. The survivability of glycine in icy planetary surfaces rich in H2O and CO2 ice will be discussed, and the implications for planetary science missions will be considered. References: Gerakines, P. A., Hudson, R. L., Moore, M. H., and Bell, J-L. (2012). In-situ Measurements of the Radiation Stability of Amino Acids at 15 - 140 K. Icarus, 220, 647-659. Gerakines, P. A. and Hudson, R. L. (2013). Glycine's Radiolytic Destruction in Ices: First in situ Laboratory Measurements for Mars. Astrobiology, 13, 647-655.

Thermodynamic analysis on the CO2 conversion processes of methane dry reforming for hydrogen production and CO2 hydrogenation to dimethyl ether

Science.gov (United States)

He, Xinyi; Liu, Liping

2017-12-01

Based on the principle of Gibbs free energy minimization, the thermodynamic analysis on the CO2 conversion processes of dry reforming of methane for H2 and CO2 hydrogenation to dimethyl ether was carried out. The composition of the reaction system was determined on the basis of reaction mechanism. The effects of reaction temperature, pressure and raw material composition on the equilibrium conversion and the selectivity of products were analyzed. The results show that high temperature, low pressure, CO2/CH4 molar ratio of 1.0-1.5 and appropriate amount of oxygen are beneficial to the dry reforming of methane. For CO2 hydrogenation to dimethyl ether, low temperature, high pressure, the appropriate H2/CO2 and the proper CO addition in feed are favorable. The calculated results are compared with the relevant studies, indicating that industrial catalytic technology needs further improvement.

Performance analysis of K-based KEP-CO2P1 solid sorbents in a bench-scale continuous dry-sorbent CO{sub 2} capture process

Energy Technology Data Exchange (ETDEWEB)

Park, Young Cheol; Jo, Sung-Ho; Lee, Seung-Yong; Moon, Jong-Ho; Yi, Chang-Keun [Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, Daejeon (Korea, Republic of); Ryu, Chong Kul; Lee, Joong Beom [Korea Electric Power Corporation Research Institute, Daejeon (Korea, Republic of)

2016-01-15

Korea Institute of Energy Research (KIER) and Korea Electric Power Corporation Research Institute (KEPCORI) have been developing a CO{sub 2} capture technology using dry sorbents. In this study, KEP-CO2P1, a potassium-based dry sorbent manufactured by a spray-drying method, was used. We employed a bench-scale dry-sorbent CO{sub 2} capture fluidized-bed process capable of capturing 0.5 ton CO{sub 2}/day at most. We investigated the sorbent performance in continuous operation mode with solid circulation between a fast fluidized-bed-type carbonator and a bubbling fluidizedbed- type regenerator. We used a slip stream of a real flue gas from 2MWe coal-fired circulating fluidized-bed (CFB) power facilities installed at KIER. Throughout more than 50 hours of continuous operation, the temperature of the carbonator was maintained around 70-80 .deg. C using a jacket-type heat exchanger, while that of the regenerator was kept above 180 .deg. C using an electric furnace. The differential pressure of both the carbonator and regenerator was maintained at a stable level. The maximum CO{sub 2} removal was greater than 90%, and the average CO{sub 2} removal was about 83% during 50 hours of continuous operation.

Synergism between elevated pCO2 and temperature on the Antarctic sea ice diatom Nitzschia lecointei

Directory of Open Access Journals (Sweden)

A. Torstensson

2013-10-01

Full Text Available Polar oceans are particularly susceptible to ocean acidification and warming. Diatoms play a significant role in sea ice biogeochemistry and provide an important food source to grazers in ice-covered oceans, especially during early spring. However, the ecophysiology of ice-living organisms has received little attention in terms of ocean acidification. In this study, the synergism between temperature and partial pressure of CO2 (pCO2 was investigated in relationship to the optimal growth temperature of the Antarctic sea ice diatom Nitzschia lecointei. Diatoms were kept in cultures at controlled levels of pCO2 (∼390 and ∼960 μatm and temperature (−1.8 and 2.5 °C for 14 days. Synergism between temperature and pCO2 was detected in growth rate and acyl lipid fatty acid (FA content. Optimal growth rate was observed around 5 °C in a separate experiment. Carbon enrichment only promoted (6% growth rate closer to the optimal growth, but not at the control temperature (−1.8 °C. At −1.8 °C and at ∼960 μatm pCO2, the total FA content was reduced relative to the ∼390 μatm treatment, although no difference between pCO2 treatments was observed at 2.5 °C. A large proportion (97% of the total FAs comprised on average of polyunsaturated fatty acids (PUFA at −1.8 °C. Cellular PUFA content was reduced at ∼960 relative to ∼390 μatm pCO2. Effects of carbon enrichment may be different depending on ocean warming scenario or season, e.g. reduced cellular FA content in response to elevated CO2 at low temperatures only, reflected as reduced food quality for higher trophic levels. Synergy between warming and acidification may be particularly important in polar areas since a narrow thermal window generally limits cold-water organisms.

Supporting evidence from the EPICA Dronning Maud Land ice core for atmospheric CO2 changes during the past millennium

International Nuclear Information System (INIS)

Siegenthaler, Urs; Monnin, Eric; Kawamura, Kenji; Spahni, Renato; Schwander, Jakob; Stauffer, Bernhard; Stocker, Thomas F.; Fischer, Hubertus

2005-01-01

The most direct method of investigating past variations of the atmospheric CO 2 concentration before 1958, when continuous direct atmospheric CO 2 measurements started, is the analysis of air extracted from suitable ice cores. Here we present a new detailed CO 2 record from the Dronning Maud Land (DML) ice core, drilled in the framework of the European Project for Ice Coring in Antarctica (EPICA) and some new measurements on a previously drilled ice core from the South Pole. The DML CO 2 record shows an increase from about 278 to 282 parts per million by volume (ppmv) between ad 1000 and ad 1200 and a fairly continuous decrease to a mean value of about 277 ppmv around ad 1700. While the new South Pole measurements agree well with DML at the minimum at ad 1700 they are on average about 2 ppmv lower during the period ad 1000-1500. Published measurements from the coastal high-accumulation site Law Dome are considered as very reliable because of the reproducibility of the measurements, high temporal resolution and an accurate time scale. Other Antarctic ice cores could not, or only partly, reproduce the pre-industrial measurements from Law Dome. A comparison of the trends of DML and Law Dome shows a general agreement. However we should be able to rule out co-variations caused by the same artefact. Two possible effects are discussed, first production of CO 2 by chemical reactions and second diffusion of dissolved air through the ice matrix into the bubbles. While the first effect cannot be totally excluded, comparison of the Law Dome and DML record shows that dissolved air diffusing to bubbles cannot be responsible for the pre-industrial variation. Therefore, the new record is not a proof of the Law Dome results but the first very strong support from an ice core of the Antarctic plateau

CO2 dry cleaning: Acoustic cavitation and other mechanisms to induce mechanical action

NARCIS (Netherlands)

Sutanto, S.; Dutschk, Victoria; Mankiewicz, J.; van Roosmaalen, M.; Warmoeskerken, Marinus

2014-01-01

High pressure carbon dioxide (CO2) is a potential solvent for textile dry cleaning. However, the particulate soil (e.g. clay, sand) removal in CO2 is generally insufficient. Since cavitation has been proven to be beneficial in other CO2 cleaning applications, this study aims to investigate the

Brief communication: ikaite (CaCO3*6H2O) discovered in Arctic sea ice

Science.gov (United States)

Dieckmann, G. S.; Nehrke, G.; Uhlig, C.; Göttlicher, J.; Gerland, S.; Granskog, M. A.; Thomas, D. N.

2010-02-01

We report for the first time on the discovery of calcium carbonate crystals as ikaite (CaCO3*6H2O) in sea ice from the Arctic (Kongsfjorden, Svalbard). This finding demonstrates that the precipitation of calcium carbonate during the freezing of sea ice is not restricted to the Antarctic, where it was observed for the first time in 2008. This finding is an important step in the quest to quantify its impact on the sea ice driven carbon cycle and should in the future enable improvement parametrization sea ice carbon models.

Studies on CO2 removal and reduction. CO2 taisaku kenkyu no genjo

Energy Technology Data Exchange (ETDEWEB)

Shindo, Y [National Institute of Materials and Chemical Research, Tsukuba (Japan)

1993-02-01

This paper summarizes study trends mainly in CO2 fixing processes. Underground CO2 storage is a most promising method because it can fix a huge amount of CO2 and has low effects on ecological systems. Storing CO2 in ocean includes such methods as storing it in deep oceans; storing it in deep ocean beds; dissolving it into sea water; neutralizing it with calcium carbonates; and precipitating it as dry ice. Japan, disposing CO2 in these ways, may create international problems. Separation of CO2 may use a chemical absorption process as a superior method. Other processes discussed include a physical adsorption method and a membrane separation method. A useful method for CO2 fixation using marine organisms is fixation using coral reefs. This process will require an overall study including circulation of phosphorus and nitrogen. Marine organisms may include planktons and algae. CO2 fixation using land plants may be able to fix one trillion and 8 hundred billion tons of CO2 as converted to carbon. This process would require forest protection, prevention of desertification, and tree planting. Discussions are being given also on improving power generation cycles, recovering CO2 from automotive exhausts, and backfilling carbons into ground by means of photosynthesis. 23 refs., 7 figs., 1 tab.

Sliding-surface-liquefaction of sand-dry ice mixture and submarine landslides

Science.gov (United States)

Fukuoka, H.; Tsukui, A.

2010-12-01

methane hydrates in laboratories because no explosion protection facility is required. In order to prevent rapid gasification, the specimen was prepared without water. Applied total normal stress was 200 kPa and initial normal stress was maintained at about 70 kPa by slightly opening the drainage valve to vent pressured CO2 gas. When the sample was sheared at 30 cm/s, the stress path reached failure line of friction angle of about 37 degrees immediately. However, excess pore air pressure increased soon after and the stress path moved to the origin along the failure line. This means rapid shearing generates frictional heat and it accelerates the gasification of dry ice quickly. On the other hand, crushing of pellets may contribute to increase the total surface area of dry ice and to acceleration of gasification, to some extent. Authors are conducting to examine the velocity weakening characteristics of the samples and upcoming results will give more detail of the mechanism. But this sliding-surface-liquefaction in the mixture supports the possibility of similar accelerating displacement in the sand-MH mixture or boundaries between MH and sand layer induced by certain strong ground motion under sea floor.

Mapping the depth to ice-cemented ground in the high elevation Dry Valleys, Antarctica

Science.gov (United States)

Marinova, M.; McKay, C. P.; Heldmann, J. L.; Davila, A. F.; Andersen, D. T.; Jackson, A.; Lacelle, D.; Paulsen, G.; Pollard, W. H.; Zacny, K.

2011-12-01

The high elevation Dry Valleys of Antarctica provide a unique location for the study of permafrost distribution and stability. In particular, the extremely arid and cold conditions preclude the presence of liquid water, and the exchange of water between the ice-cemented ground and the atmosphere is through vapour transport (diffusion). In addition, the low atmospheric humidity results in the desiccation of the subsurface, forming a dry permafrost layer (i.e., cryotic soils which are dry and not ice-cemented). Weather data suggests that subsurface ice is unstable under current climatic conditions. Yet we do find ice-cemented ground in these valleys. This contradiction provides insight into energy balance modeling, vapour transport, and additional climate effects which stabilize subsurface ice. To study the driving factors in the stability and distribution of ice-cemented ground, we have extensively mapped the depth to ice-cemented ground in University Valley (1730 m; 77°S 51.8', 160°E 43'), and three neighbouring valleys in the Beacon Valley area. We measured the depth to ice-cemented ground at 15-40 locations per valley by digging soil pits and drilling until ice was reached; for each location 3-5 measurements within a ~1 m2 area were averaged (see figure). This high-resolution mapping of the depth to ice-cemented ground provides new insight on the distribution and stability of subsurface ice, and shows significant variability in the depth to ground ice within each valley. We are combining data from mapping the depth to ice-cemented ground with year-round, in situ measurements of the atmospheric and subsurface conditions, such as temperature, humidity, wind, and light, to model the local stability of ice-cemented ground. We are using this dataset to examine the effects of slopes, shading, and soil properties, as well as the suggested importance of snow recurrence, to better understand diffusion-controlled subsurface ice stability.

REVISITING THE SCATTERING GREENHOUSE EFFECT OF CO2 ICE CLOUDS

International Nuclear Information System (INIS)

Kitzmann, D.

2016-01-01

Carbon dioxide ice clouds are thought to play an important role for cold terrestrial planets with thick CO 2 dominated atmospheres. Various previous studies showed that a scattering greenhouse effect by carbon dioxide ice clouds could result in a massive warming of the planetary surface. However, all of these studies only employed simplified two-stream radiative transfer schemes to describe the anisotropic scattering. Using accurate radiative transfer models with a general discrete ordinate method, this study revisits this important effect and shows that the positive climatic impact of carbon dioxide clouds was strongly overestimated in the past. The revised scattering greenhouse effect can have important implications for the early Mars, but also for planets like the early Earth or the position of the outer boundary of the habitable zone

Ikaite crystals in melting sea ice – implications for pCO2 and pH levels in Arctic surface waters

DEFF Research Database (Denmark)

Rysgaard, Søren; Glud, R.N.; Lennert, K.

2012-01-01

A major issue of Arctic marine science is to understand whether the Arctic Ocean is, or will be, a source or sink for air-sea CO 2 exchange. This has been complicated by the recent discoveries of ikaite (a polymorph of CaCO 3•6H 2O) in Arctic and Antarctic sea ice, which indicate that multiple...... chemical transformations occur in sea ice with a possible effect on CO 2 and pH conditions in surface waters. Here, we report on biogeochemical conditions, microscopic examinations and x-ray diffraction analysis of single crystals from a melting 1.7 km 2 (0.5-1 m thick) drifting ice floe in the Fram Strait...... during summer. Our findings show that ikaite crystals are present throughout the sea ice but with larger crystals appearing in the upper ice layers. Ikaite crystals placed at elevated temperatures disintegrated into smaller crystallites and dissolved. During our field campaign in late June, melt reduced...

CO ICE PHOTODESORPTION: A WAVELENGTH-DEPENDENT STUDY

International Nuclear Information System (INIS)

Fayolle, Edith C.; Linnartz, Harold; Bertin, Mathieu; Romanzin, Claire; Michaut, Xavier; Fillion, Jean-Hugues; Oeberg, Karin I.

2011-01-01

UV-induced photodesorption of ice is a non-thermal evaporation process that can explain the presence of cold molecular gas in a range of interstellar regions. Information on the average UV photodesorption yield of astrophysically important ices exists for broadband UV lamp experiments. UV fields around low-mass pre-main-sequence stars, around shocks and in many other astrophysical environments are however often dominated by discrete atomic and molecular emission lines. It is therefore crucial to consider the wavelength dependence of photodesorption yields and mechanisms. In this work, for the first time, the wavelength-dependent photodesorption of pure CO ice is explored between 90 and 170 nm. The experiments are performed under ultra high vacuum conditions using tunable synchrotron radiation. Ice photodesorption is simultaneously probed by infrared absorption spectroscopy in reflection mode of the ice and by quadrupole mass spectrometry of the gas phase. The experimental results for CO reveal a strong wavelength dependence directly linked to the vibronic transition strengths of CO ice, implying that photodesorption is induced by electronic transition (DIET). The observed dependence on the ice absorption spectra implies relatively low photodesorption yields at 121.6 nm (Lyα), where CO barely absorbs, compared to the high yields found at wavelengths coinciding with transitions into the first electronic state of CO (A 1 Π at 150 nm); the CO photodesorption rates depend strongly on the UV profiles encountered in different star formation environments.

ELECTRON IRRADIATION OF KUIPER BELT SURFACE ICES: TERNARY N2-CH4-CO MIXTURES AS A CASE STUDY

International Nuclear Information System (INIS)

Kim, Y. S.; Kaiser, R. I.

2012-01-01

The space weathering of icy Kuiper Belt Objects was investigated in this case study by exposing methane (CH 4 ) and carbon monoxide (CO) doped nitrogen (N 2 ) ices at 10 K to ionizing radiation in the form of energetic electrons. Online and in situ Fourier transform infrared spectroscopy was utilized to monitor the radiation-induced chemical processing of these ices. Along with isocyanic acid (HNCO), the products could be mainly derived from those formed in irradiated binary ices of the N 2 -CH 4 and CO-CH 4 systems: nitrogen-bearing products were found in the form of hydrogen cyanide (HCN), hydrogen isocyanide (HNC), diazomethane (CH 2 N 2 ), and its radical fragment (HCN 2 ); oxygen-bearing products were of acetaldehyde (CH 3 CHO), formyl radical (HCO), and formaldehyde (H 2 CO). As in the pure ices, the methyl radical (CH 3 ) and ethane (C 2 H 6 ) were also detected, as were carbon dioxide (CO 2 ) and the azide radical (N 3 ). Based on the temporal evolution of the newly formed products, kinetic reaction schemes were then developed to fit the temporal profiles of the newly formed species, resulting in numerical sets of rate constants. The current study highlights important constraints on the preferential formation of isocyanic acid (HNCO) over hydrogen cyanide (HCN) and hydrogen isocyanide (HNC), thus guiding the astrobiological and chemical evolution of those distant bodies.

Glycine formation in CO2:CH4:NH3 ices induced by 0-70 eV electrons

Science.gov (United States)

Esmaili, Sasan; Bass, Andrew D.; Cloutier, Pierre; Sanche, Léon; Huels, Michael A.

2018-04-01

Glycine (Gly), the simplest amino-acid building-block of proteins, has been identified on icy dust grains in the interstellar medium, icy comets, and ice covered meteorites. These astrophysical ices contain simple molecules (e.g., CO2, H2O, CH4, HCN, and NH3) and are exposed to complex radiation fields, e.g., UV, γ, or X-rays, stellar/solar wind particles, or cosmic rays. While much current effort is focused on understanding the radiochemistry induced in these ices by high energy radiation, the effects of the abundant secondary low energy electrons (LEEs) it produces have been mostly assumed rather than studied. Here we present the results for the exposure of multilayer CO2:CH4:NH3 ice mixtures to 0-70 eV electrons under simulated astrophysical conditions. Mass selected temperature programmed desorption (TPD) of our electron irradiated films reveals multiple products, most notably intact glycine, which is supported by control measurements of both irradiated or un-irradiated binary mixture films, and un-irradiated CO2:CH4:NH3 ices spiked with Gly. The threshold of Gly formation by LEEs is near 9 eV, while the TPD analysis of Gly film growth allows us to determine the "quantum" yield for 70 eV electrons to be about 0.004 Gly per incident electron. Our results show that simple amino acids can be formed directly from simple molecular ingredients, none of which possess preformed C—C or C—N bonds, by the copious secondary LEEs that are generated by ionizing radiation in astrophysical ices.

Additions and corrections to the absorption coefficients of CO2 ice: Applications to the Martian south polar cap

International Nuclear Information System (INIS)

Calvin, W.M.

1990-01-01

Reflectance spectra of carbon dioxide frosts were calculated using the optical constants provided by Warren (1986) for the wavelength region 2-6 μm. In comparing these calculated spectra to spectra of frosts observed in the laboratory and on the surface of Mars, problems in the optical constants presented by Warren (1986) became apparent. Absorption coefficients for CO 2 ice have been derived using laboratory reflectance measurements and the Hapke (1981) model for calculating diffuse reflectance. This provides approximate values in regions where no data were previously available and indicates where corrections to the compilation by Warren (1986) are required. Using these coefficients to calculate the reflectance of CO 2 ice at varying grain sizes indicates that a typical Mariner polar cap spectrum is dominated by absorptions due to CO 2 frost or ice at grain sizes that are quite large, probably of the order of millimeters to centimeters. There are indications of contamination of water frost or dust, but confirmation will require more precise absorption coefficients for solid CO 2 than can be obtained from the method used here

Experimental determination of surface heat transfer coefficient in a dry ice-ethanol cooling bath using a numerical approach.

Science.gov (United States)

Santos, M V; Sansinena, M; Zaritzky, N; Chirife, J

BACKGROUND: Dry ice-ethanol bath (-78 degree C) have been widely used in low temperature biological research to attain rapid cooling of samples below freezing temperature. The prediction of cooling rates of biological samples immersed in dry ice-ethanol bath is of practical interest in cryopreservation. The cooling rate can be obtained using mathematical models representing the heat conduction equation in transient state. Additionally, at the solid cryogenic-fluid interface, the knowledge of the surface heat transfer coefficient (h) is necessary for the convective boundary condition in order to correctly establish the mathematical problem. The study was to apply numerical modeling to obtain the surface heat transfer coefficient of a dry ice-ethanol bath. A numerical finite element solution of heat conduction equation was used to obtain surface heat transfer coefficients from measured temperatures at the center of polytetrafluoroethylene and polymethylmetacrylate cylinders immersed in a dry ice-ethanol cooling bath. The numerical model considered the temperature dependence of thermophysical properties of plastic materials used. A negative linear relationship is observed between cylinder diameter and heat transfer coefficient in the liquid bath, the calculated h values were 308, 135 and 62.5 W/(m 2 K) for PMMA 1.3, PTFE 2.59 and 3.14 cm in diameter, respectively. The calculated heat transfer coefficients were consistent among several replicates; h in dry ice-ethanol showed an inverse relationship with cylinder diameter.

Dry Ice Blast Decontamination to in-service equipment in Japanese PWR plant

International Nuclear Information System (INIS)

2016-01-01

MHI had developed several mechanical decontamination methods. Mechanical decontamination is beneficial when it is applied to equipment whose surface is narrow. Especially in terms of secondary waste reduction, MHI started the study of application of Dry Ice Blast Decontamination to actual PWR plant. This paper provides an introduction to Dry Ice Blast Decontamination principle, its system and actual application result to PWR plant. (J.P.N.)

Sea Ice as a Sink for CO2 and Biogeochemical Material: a Novel Sampling Method and Astrobiological Applications

Science.gov (United States)

Wilner, J.; Hofmann, A.; Hand, K. P.

2017-12-01

Accurately modelling the intensification of greenhouse gas effects in the polar regions ("polar amplification") necessitates a thorough understanding of the geochemical balance between atmospheric, sea ice, and oceanic layers. Sea ice is highly permeable to CO2 and therefore represents a major sink of oceanic CO2 in winter and of atmospheric CO2 in summer, sinks that are typically either poorly constrained in or fully absent from global climate models. We present a novel method for sampling both trapped and dissolved gases (CO2, CH4 and δ13CH4) in sea ice with a Picarro 2132-i Methane Analyzer, taking the following sampling considerations into account: minimization of water and air contamination, full headspace sampling, prevention of inadvertent sample bag double-puncturing, and ease of use. This method involves melting of vacuum-sealed ice cores to evacuate trapped gases to the headspace and sampling the headspace gas with a blunt needle sheathed by a beveled puncturing needle. A gravity catchment tube prevents input of dangerous levels of liquid water to the Picarro cavity. Subsequent ultrasonic degassing allows for dissolved gas measurement. We are in the process of using this method to sample gases trapped and dissolved in Arctic autumn sea ice cores and atmospheric samples collected during the 2016 Polarstern Expedition and during a May 2017 field campaign north of Barrow, Alaska. We additionally employ this method, together with inductively coupled plasma mass spectrometry (ICP-MS), to analyze the transfer of potential biogeochemical signatures of underlying hydrothermal plumes to sea ice. This has particular relevance to Europa and Enceladus, where hypothetical hydrothermal plumes may deliver seafloor chemicals to the overlying ice shell. Hence, we are presently investigating the entrainment of methane and other hydrothermal material in sea ice cores collected along the Gakkel Ridge that may serve as biosignatures of methanogenic organisms in seafloor

In Situ Raman Analysis of CO2—Assisted Drying of Fruit-Slices

Directory of Open Access Journals (Sweden)

Andreas Siegfried Braeuer

2017-05-01

Full Text Available This work explores the feasibility of applying in situ Raman spectroscopy for the online monitoring of the supercritical carbon dioxide (SC-CO2 drying of fruits. Specifically, we investigate two types of fruits: mango and persimmon. The drying experiments were carried out inside an optical accessible vessel at 10 MPa and 313 K. The Raman spectra reveal: (i the reduction of the water from the fruit slice and (ii the change of the fruit matrix structure during the drying process. Two different Raman excitation wavelengths were compared: 532 nm and 785 nm. With respect to the quality of the obtained spectra, the 532 nm excitation wavelength was superior due to a higher signal-to-noise ratio and due to a resonant excitation scheme of the carotenoid molecules. It was found that the absorption of CO2 into the fruit matrix enhances the extraction of water, which was expressed by the obtained drying kinetic curve.

In Situ Raman Analysis of CO2—Assisted Drying of Fruit-Slices

Science.gov (United States)

Braeuer, Andreas Siegfried; Schuster, Julian Jonathan; Gebrekidan, Medhanie Tesfay; Bahr, Leo; Michelino, Filippo; Zambon, Alessandro; Spilimbergo, Sara

2017-01-01

This work explores the feasibility of applying in situ Raman spectroscopy for the online monitoring of the supercritical carbon dioxide (SC-CO2) drying of fruits. Specifically, we investigate two types of fruits: mango and persimmon. The drying experiments were carried out inside an optical accessible vessel at 10 MPa and 313 K. The Raman spectra reveal: (i) the reduction of the water from the fruit slice and (ii) the change of the fruit matrix structure during the drying process. Two different Raman excitation wavelengths were compared: 532 nm and 785 nm. With respect to the quality of the obtained spectra, the 532 nm excitation wavelength was superior due to a higher signal-to-noise ratio and due to a resonant excitation scheme of the carotenoid molecules. It was found that the absorption of CO2 into the fruit matrix enhances the extraction of water, which was expressed by the obtained drying kinetic curve. PMID:28505120

TEMPORARY STORAGE OF BOVINE SEMEN CRYOPRESERVED IN LIQUID NITROGEN ON DRY ICE AND REFREEZING OF FROZEN-THAWED SEMEN.

Science.gov (United States)

Abdussamad, A M; Gauly, M; Holtz, W

2015-01-01

Two experiments were conducted. The purpose of Experiment 1 was to investigate whether viability of bovine semen stored in liquid nitrogen (-196°C) will be adversely affected by temporary exposure to dry ice (-79°C). It was convincingly shown that post thaw-motility was not affected, regardless whether semen was thawed immediately or after being returned to liquid nitrogen. Shipping or temporary storage on dry ice, thus, is a viable option. In Experiment 2, refreezing of frozen-thawed semen was attempted. The proportion of motile spermatozoa was reduced by a factor of ten to between 6.0 % and 7.4 %, regardless whether thawing occurred directly after removal from liquid nitrogen or after an interim period on dry ice. When semen was refrozen on dry ice before being returned to liquid nitrogen, motility rates were significantly improved (13.0 % to 17.0 %, P<0.05). In both experiments sperm cells that remained motile displayed vigorous forward movement and normal morphological appearance.

Implications for carbon processing beneath the Greenland Ice Sheet from dissolved CO2 and CH4 concentrations of subglacial discharge

Science.gov (United States)

Pain, A.; Martin, J.; Martin, E. E.

2017-12-01

Subglacial carbon processes are of increasing interest as warming induces ice melting and increases fluxes of glacial meltwater into proglacial rivers and the coastal ocean. Meltwater may serve as an atmospheric source or sink of carbon dioxide (CO2) or methane (CH4), depending on the magnitudes of subglacial organic carbon (OC) remineralization, which produces CO2 and CH4, and mineral weathering reactions, which consume CO2 but not CH4. We report wide variability in dissolved CO2 and CH4 concentrations at the beginning of the melt season (May-June 2017) between three sites draining land-terminating glaciers of the Greenland Ice Sheet. Two sites, located along the Watson River in western Greenland, drain the Isunnguata and Russell Glaciers and contained 1060 and 400 ppm CO2, respectively. In-situ CO2 flux measurements indicated that the Isunnguata was a source of atmospheric CO2, while the Russell was a sink. Both sites had elevated CH4 concentrations, at 325 and 25 ppm CH4, respectively, suggesting active anaerobic OC remineralization beneath the ice sheet. Dissolved CO2 and CH4 reached atmospheric equilibrium within 2.6 and 8.6 km downstream of Isunnguata and Russell discharge sites, respectively. These changes reflect rapid gas exchange with the atmosphere and/or CO2 consumption via instream mineral weathering. The third site, draining the Kiagtut Sermiat in southern Greenland, had about half atmospheric CO2 concentrations (250 ppm), but approximately atmospheric CH4 concentrations (2.1 ppm). Downstream CO2 flux measurements indicated ingassing of CO2 over the entire 10-km length of the proglacial river. CO2 undersaturation may be due to more readily weathered lithologies underlying the Kiagtut Sermiat compared to Watson River sites, but low CH4 concentrations also suggest limited contributions of CO2 and CH4 from OC remineralization. These results suggest that carbon processing beneath the Greenland Ice Sheet may be more variable than previously recognized

REVISITING THE SCATTERING GREENHOUSE EFFECT OF CO{sub 2} ICE CLOUDS

Energy Technology Data Exchange (ETDEWEB)

Kitzmann, D., E-mail: daniel.kitzmann@csh.unibe.ch [Center for Space and Habitability, University of Bern, Sidlerstr. 5, 3012 Bern (Switzerland)

2016-02-01

Carbon dioxide ice clouds are thought to play an important role for cold terrestrial planets with thick CO{sub 2} dominated atmospheres. Various previous studies showed that a scattering greenhouse effect by carbon dioxide ice clouds could result in a massive warming of the planetary surface. However, all of these studies only employed simplified two-stream radiative transfer schemes to describe the anisotropic scattering. Using accurate radiative transfer models with a general discrete ordinate method, this study revisits this important effect and shows that the positive climatic impact of carbon dioxide clouds was strongly overestimated in the past. The revised scattering greenhouse effect can have important implications for the early Mars, but also for planets like the early Earth or the position of the outer boundary of the habitable zone.

Decontamination of surfaces by blasting with crystals of H2O and CO2

International Nuclear Information System (INIS)

Benson, C.E.; Parfitt, J.E.; Patton, B.D.

1995-02-01

A major mission of the US Department of Energy during the 1990s is site and environmental cleanup. In pursuit of this mission, numerous remediation projects are under way and many others are being planned at Oak Ridge National Laboratory (ORNL). In this report, tests using two proposed methods for decontaminating surfaces one using water ice crystals [Crystalline Ice Blast (CIB)], the other using dry ice crystals (CO 2 Cleanblast trademark) -- are described. Both methods are adaptations of the commonly used sand blasting technology. The two methods tested differ from sand blasting in that the particles are not particularly abrasive and do not accumulate as particles in the wastes. They differ from each other in that the CO 2 particles sublime during and after impact and the ice particles melt. Thus, the two demonstrations provide important information about two strong candidate decontamination methodologies. Each process was tested at ORNL using contaminated lead bricks and contaminated tools and equipment. Demonstrations with the prototype Crystalline Ice Blast and the CO 2 Cleanblast systems showed that paint, grease, and oil can be removed from metal, plastic, asphalt, and concrete surfaces. Furthermore, removal of contamination from lead bricks was highly effective. Both processes were found to be less effective, under the conditions tested, with contaminated tools and equipment that had chemically bonded contamination or contamination located in crevices since neither technology abrades the substrates or penetrates deeply into crevices to remove particulates. Some process improvements are recommended

Implantation of energetic D{sup +} ions into carbon dioxide ices and implications for our solar system: formation of D{sub 2}O and D{sub 2}CO{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Bennett, Chris J.; Ennis, Courtney P.; Kaiser, Ralf I., E-mail: ralfk@hawaii.edu [Department of Chemistry, University of Hawai' i at Mānoa, Honolulu, HI 96822 (United States)

2014-10-10

Carbon dioxide (CO{sub 2}) ices were irradiated with energetic D{sup +} ions to simulate the exposure of oxygen-bearing solar system ices to energetic protons from the solar wind and magnetospheric sources. The formation of species was observed online and in situ by exploiting FTIR spectroscopy. Molecular products include ozone (O{sub 3}), carbon oxides (CO{sub 3}(C {sub 2v}, D {sub 3h}), CO{sub 4}, CO{sub 5}, CO{sub 6}), D2-water (D{sub 2}O), and D2-carbonic acid (D{sub 2}CO{sub 3}). Species released into the gas phase were sampled via a quadrupole mass spectrometer, and possible minor contributions from D2-formaldehyde (D{sub 2}CO), D4-methanol (CD{sub 3}OD), and D2-formic acid (DCOOD) were additionally identified. The feasibility of several reaction networks was investigated by determining their ability to fit the observed temporal column densities of 10 key species that were quantified during the irradiation period. Directly relevant to the CO{sub 2}-bearing ices of comets, icy satellites in the outer solar system, and the ice caps on Mars, this work illustrates for the first time that D2-water is formed as a product of the exposure of CO{sub 2} ices to D{sup +} ions. These findings provide strong support for water formation from oxygen-bearing materials via non-thermal hydrogen atoms, and predict reaction pathways that are likely to be unfolding on the surfaces of asteroids and the Moon.

Effects of intermittent CO2 convection under far-infrared radiation on vacuum drying of pre-osmodehydrated watermelon.

Science.gov (United States)

Chakraborty, Rajat; Mondal, Pijus

2017-08-01

Watermelon, a tropical seasonal fruit with high nutrient content, requires preservation through drying due to its perishable nature. Nevertheless, drying of watermelon through conventional processes has a negative impact either on the drying time or on the final product quality. In this work, osmotic dehydration of watermelon followed by far-infrared radiation-assisted vacuum drying (FIRRAVD) was optimized to develop dehydrated watermelon with minimum moisture content. Significantly, during FIRRAVD, an attempt was made to further intensify the drying rate by forced convection through intermittent CO 2 injection. Drying kinetics of each operation and physicochemical qualities of dried products were evaluated. FIRRAVD was a viable method of watermelon drying with appreciably high moisture diffusivity (D eff,m ) of 4.97 × 10 -10 to 1.49 × 10 -9 m 2 s -1 compared to conventional tray drying. Moreover, intermittent CO 2 convection during FIRRAVD (ICFIRRAVD) resulted in appreciable intensification of drying rate, with enhanced D eff,m (9.93 × 10 -10 to 1.99 × 10 -9 m 2 s -1 ). Significantly, ICFIRRAVD required less energy and approximately 16% less time compared to FIRRAVD. The quality of the final dehydrated watermelon was superior compared to conventional drying protocols. The novel CO 2 convective drying of watermelon in the presence of far-infrared radiation demonstrated an energy-efficient and time-saving operation rendering a dehydrated watermelon with acceptable quality parameters. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Precession and atmospheric CO2 modulated variability of sea ice in the central Okhotsk Sea since 130,000 years ago

Science.gov (United States)

Lo, Li; Belt, Simon T.; Lattaud, Julie; Friedrich, Tobias; Zeeden, Christian; Schouten, Stefan; Smik, Lukas; Timmermann, Axel; Cabedo-Sanz, Patricia; Huang, Jyh-Jaan; Zhou, Liping; Ou, Tsong-Hua; Chang, Yuan-Pin; Wang, Liang-Chi; Chou, Yu-Min; Shen, Chuan-Chou; Chen, Min-Te; Wei, Kuo-Yen; Song, Sheng-Rong; Fang, Tien-Hsi; Gorbarenko, Sergey A.; Wang, Wei-Lung; Lee, Teh-Quei; Elderfield, Henry; Hodell, David A.

2018-04-01

Recent reduction in high-latitude sea ice extent demonstrates that sea ice is highly sensitive to external and internal radiative forcings. In order to better understand sea ice system responses to external orbital forcing and internal oscillations on orbital timescales, here we reconstruct changes in sea ice extent and summer sea surface temperature (SSST) over the past 130,000 yrs in the central Okhotsk Sea. We applied novel organic geochemical proxies of sea ice (IP25), SSST (TEX86L) and open water marine productivity (a tri-unsaturated highly branched isoprenoid and biogenic opal) to marine sediment core MD01-2414 (53°11.77‧N, 149°34.80‧E, water depth 1123 m). To complement the proxy data, we also carried out transient Earth system model simulations and sensitivity tests to identify contributions of different climatic forcing factors. Our results show that the central Okhotsk Sea was ice-free during Marine Isotope Stage (MIS) 5e and the early-mid Holocene, but experienced variable sea ice cover during MIS 2-4, consistent with intervals of relatively high and low SSST, respectively. Our data also show that the sea ice extent was governed by precession-dominated insolation changes during intervals of atmospheric CO2 concentrations ranging from 190 to 260 ppm. However, the proxy record and the model simulation data show that the central Okhotsk Sea was near ice-free regardless of insolation forcing throughout the penultimate interglacial, and during the Holocene, when atmospheric CO2 was above ∼260 ppm. Past sea ice conditions in the central Okhotsk Sea were therefore strongly modulated by both orbital-driven insolation and CO2-induced radiative forcing during the past glacial/interglacial cycle.

A state of the art report on the decontamination technology for dry ice blasting

International Nuclear Information System (INIS)

Shin, J. M.; Kim, K. H.; Park, J. J.; Lee, H. H.; Yang, M. S.; Nam, S. H.; Kim, M. J.

2000-05-01

DUPIC fuel fabrication process is a dry processing technology to manufacture CANDU compatible fuel through a direct reprocessing fabrication process from spent PWR fuel. DUPIC fuel fabrication process consists of the slitting of the spent PWR fuel rods, OREOX processing, homogeneous mixing, pelletizing and sintering. All these processes should be conducted by remote means in a M6 hot cell at IMEF. Since DUPIC fuel fabrication process includes powder handling process of highly radioactive spent fuel, decontamination of highly radioactive particulates from all types of surfaces such as DUPIC fuel manufacturing equipment, hot cell floor, tools is very important to improve the safety of hot cell and reduce the dose exposure to operator, This report describes various technologies for dry ice blasting. It provides the fundamentals of dry ice blasting decontamination and technical review of dry ice blasting on the radioactive decontamination

A state of the art report on the decontamination technology for dry ice blasting

Energy Technology Data Exchange (ETDEWEB)

Shin, J M; Kim, K H; Park, J J; Lee, H H; Yang, M S; Nam, S H; Kim, M J

2000-05-01

DUPIC fuel fabrication process is a dry processing technology to manufacture CANDU compatible fuel through a direct reprocessing fabrication process from spent PWR fuel. DUPIC fuel fabrication process consists of the slitting of the spent PWR fuel rods, OREOX processing, homogeneous mixing, pelletizing and sintering. All these processes should be conducted by remote means in a M6 hot cell at IMEF. Since DUPIC fuel fabrication process includes powder handling process of highly radioactive spent fuel, decontamination of highly radioactive particulates from all types of surfaces such as DUPIC fuel manufacturing equipment, hot cell floor, tools is very important to improve the safety of hot cell and reduce the dose exposure to operator, This report describes various technologies for dry ice blasting. It provides the fundamentals of dry ice blasting decontamination and technical review of dry ice blasting on the radioactive decontamination.

Massive CO2 Ice Deposits Sequestered in the South Polar Layered Deposits of Mars

Science.gov (United States)

Phillips, Roger J.; Davis, Brian J.; Tanaka, Kenneth L.; Byrne, Shane; Mellon, Michael T.; Putzig, Nathaniel E.; Haberle, Robert M.; Kahre, Melinda A.; Campbell, Bruce A.; Carter, Lynn M.; Smith, Isaac B.; Holt, John W.; Smrekar, Suzanne E.; Nunes, Daniel C.; Plaut, Jeffrey J.; Egan, Anthony F.; Titus, Timothy N.; Seu, Roberto

2011-01-01

Shallow Radar soundings from the Mars Reconnaissance Orbiter reveal a buried deposit of carbon dioxide (CO2) ice within the south polar layered deposits of Mars with a volume of 9500 to 12,500 cubic kilometers, about 30 times that previously estimated for the south pole residual cap. The deposit occurs within a stratigraphic unit that is uniquely marked by collapse features and other evidence of interior CO2 volatile release. If released into the atmosphere at times of high obliquity, the CO2 reservoir would increase the atmospheric mass by up to 80%, leading to more frequent and intense dust storms and to more regions where liquid water could persist without boiling.

Surface decontamination using dry ice snow

International Nuclear Information System (INIS)

Ryu, Jungdong; Park, Kwangheon; Lee, Bumsik; Kim Yangeun

1999-01-01

An adjustable nozzle for controlling the size of dry ice snow was developed. The converging/diverging nozzle can control the size of snows from sub-microns to 10 micron size. Using the nozzle, a surface decontamination device was made. The removal mechanisms of surface contaminants are mechanical impact, partial dissolving and evaporation process, and viscous flow. A heat supply system is added for the prevention of surface ice layer formation. The cleaning power is slightly dependent on the size of snow. Small snows are the better in viscous flow cleaning, while large snows are slightly better in dissolving and sublimation process. Human oils like fingerprints on glass were easy to remove. Decontamination ability was tested using a contaminated pump-housing surface. About 40 to 80% of radioactivity was removed. This device is effective in surface-decontamination of any electrical devices like detector, controllers which cannot be cleaned in aqueous solution. (author)

Brief Communication: Ikaite (CaCO3·6H2O) discovered in Arctic sea ice

Science.gov (United States)

Dieckmann, G. S.; Nehrke, G.; Uhlig, C.; Göttlicher, J.; Gerland, S.; Granskog, M. A.; Thomas, D. N.

2010-05-01

We report for the first time on the discovery of calcium carbonate crystals as ikaite (CaCO3·6H2O) in sea ice from the Arctic (Kongsfjorden, Svalbard) as confirmed by morphology and indirectly by X-ray diffraction as well as XANES spectroscopy of its amorophous decomposition product. This finding demonstrates that the precipitation of calcium carbonate during the freezing of sea ice is not restricted to the Antarctic, where it was observed for the first time in 2008. This observation is an important step in the quest to quantify its impact on the sea ice driven carbon cycle.

Dynamic ikaite production and dissolution in sea ice – control by temperature, salinity and pCO₂ conditions

OpenAIRE

S. Rysgaard; F. Wang; R. J. Galley; R. Grimm; M. Lemes; N.-X. Geilfus; A. Chaulk; A. A. Hare; O. Crabeck; B. G. T. Else; K. Campbell; T. Papakyriakou; L. L. Sørensen; J. Sievers; D. Notz

2013-01-01

Ikaite is a hydrous calcium carbonate mineral (CaCO3 · 6H2O). It is only found in a metastable state, and decomposes rapidly once removed from near-freezing water. Recently, ikaite crystals have been found in sea ice and it has been suggested that their precipitation may play an important role in air-sea CO2 exchange in ice-covered seas. Little is known, however, of the spatial and temporal dynamics of ikaite in sea ice. Here we present evidence for highly dynamic ik...

Dry reforming of methane with CO{sub 2} at elevated pressures

Energy Technology Data Exchange (ETDEWEB)

Milanov, A.; Schwab, E.; Wasserschaff, G. [BASF SE, Ludwigshafen (Germany); Schunk, S. [hte AG, Heidelberg (Germany)

2013-11-01

The indirect conversion of natural gas into higher value chemicals and fuels via syngas is superior with regard to efficiency compared to the currently available direct conversion technologies and remains the industrially preferred route. Typically the syngas production route is generally dictated by the H{sub 2}/CO ratio requirements of the downstream synthesis process. Processes such as direct DME synthesis, high-temperature Fischer-Tropsch and acetic acid synthesis require CO rich syngas that is not readily accessible by established technologies like steam methane reforming (SMR) and autothermal reforming of methane (ATR). The CO{sub 2} reforming of methane, also known as dry reforming (DRM), is an attractive alternative technology for the production of CO-rich syngas. This paper gives an overview of the current joint research activities at BASF and hte AG aiming to develop suitable catalysts for CO{sub 2} reforming of methane at elevated pressures with minimized input of process steam. The performance profiles of two newly developed base metal catalysts are presented and discussed. The catalysts exhibit high degrees of methane and CO{sub 2} conversion in combination with an extraordinary coking resistance under high severity process conditions. (orig.)

Supercritical CO2 drying of poly(methyl methacrylate) photoresist for deep x-ray lithography: a brief note

Science.gov (United States)

Shukla, Rahul; Abhinandan, Lala; Sharma, Shivdutt

2017-07-01

Poly(methyl methacrylate) (PMMA) is an extensively used positive photoresist for deep x-ray lithography. The post-development release of the microstructures of PMMA becomes very critical for high aspect ratio fragile and freestanding microstructures. Release of high aspect ratio comb-drive microstructure of PMMA made by one-step x-ray lithography (OXL) is studied. The effect of low-surface tension Isopropyl alcohol (IPA) over water is investigated for release of the high aspect ratio microstructures using conventional and supercritical (SC) CO2 drying. The results of conventional drying are also compared for the samples released or dried in both in-house developed and commercial SC CO2 dryer. It is found that in all cases the microstructures of PMMA are permanently deformed and damaged while using SC CO2 for drying. For free-standing high aspect ratio microstructures of PMMA made by OXL, it is advised to use low-surface tension IPA over DI water. However, this brings a limitation on the design of the microstructure.

Sensitivity to ocean acidification parallels natural pCO2 gradients experienced by Arctic copepods under winter sea ice

Science.gov (United States)

Lewis, Ceri N.; Brown, Kristina A.; Edwards, Laura A.; Cooper, Glenn; Findlay, Helen S.

2013-01-01

The Arctic Ocean already experiences areas of low pH and high CO2, and it is expected to be most rapidly affected by future ocean acidification (OA). Copepods comprise the dominant Arctic zooplankton; hence, their responses to OA have important implications for Arctic ecosystems, yet there is little data on their current under-ice winter ecology on which to base future monitoring or make predictions about climate-induced change. Here, we report results from Arctic under-ice investigations of copepod natural distributions associated with late-winter carbonate chemistry environmental data and their response to manipulated pCO2 conditions (OA exposures). Our data reveal that species and life stage sensitivities to manipulated OA conditions were correlated with their vertical migration behavior and with their natural exposures to different pCO2 ranges. Vertically migrating adult Calanus spp. crossed a pCO2 range of >140 μatm daily and showed only minor responses to manipulated high CO2. Oithona similis, which remained in the surface waters and experienced a pCO2 range of <75 μatm, showed significantly reduced adult and nauplii survival in high CO2 experiments. These results support the relatively untested hypothesis that the natural range of pCO2 experienced by an organism determines its sensitivity to future OA and highlight that the globally important copepod species, Oithona spp., may be more sensitive to future high pCO2 conditions compared with the more widely studied larger copepods. PMID:24297880

Release of N 2, CH 4, CO 2, and H 2O from surface ices on Enceladus

Science.gov (United States)

Hodyss, Robert; Goguen, Jay D.; Johnson, Paul V.; Campbell, Colin; Kanik, Isik

2008-09-01

We vapor deposit at 20 K a mixture of gases with the specific Enceladus plume composition measured in situ by the Cassini INMS [Waite, J.H., Combi, M.R., Ip, W.H., Cravens, T.E., McNutt, R.L., Kasprzak, W., Yelle, R., Luhmann, J., Niemann, H., Gell, D., Magee, B., Fletcher, G., Lunine, J., Tseng, W.L., 2006. Science 311, 1419-1422] to form a mixed molecular ice. As the sample is slowly warmed, we monitor the escaping gas quantity and composition with a mass spectrometer. Pioneering studies [Schmitt, B., Klinger, J., 1987. Different trapping mechanisms of gases by water ice and their relevance for comet nuclei. In: Rolfe, E.J., Battrick, B. (Eds.), Diversity and Similarity of Comets. SP-278. ESA, Noordwijk, The Netherlands, pp. 613-619; Bar-Nun, A., Kleinfeld, I., Kochavi, E., 1988. Phys. Rev. B 38, 7749-7754; Bar-Nun, A., Kleinfeld, I., 1989. Icarus 80, 243-253] have shown that significant quantities of volatile gases can be trapped in a water ice matrix well above the temperature at which the pure volatile ice would sublime. For our Enceladus ice mixture, a composition of escaping gases similar to that detected by Cassini in the Enceladus plume can be generated by the sublimation of the H 2O:CO 2:CH 4:N 2 mixture at temperatures between 135 and 155 K, comparable to the high temperatures inferred from the CIRS measurements [Spencer, J.R., Pearl, J.C., Segura, M., Flasar, F.M., Mamoutkine, A., Romani, P., Buratti, B.J., Hendrix, A.R., Spilker, L.J., Lopes, R.M.C., 2006. Science 311, 1401-1405] of the Enceladus "tiger stripes." This suggests that the gas escape phenomena that we measure in our experiments are an important process contributing to the gases emitted from Enceladus. A similar experiment for ice deposited at 70 K shows that both the processes of volatile trapping and release are temperature dependent over the temperature range relevant to Enceladus.

Clouds in the atmospheres of extrasolar planets. V. The impact of CO2 ice clouds on the outer boundary of the habitable zone

OpenAIRE

Kitzmann, Daniel

2017-01-01

Clouds have a strong impact on the climate of planetary atmospheres. The potential scattering greenhouse effect of CO2 ice clouds in the atmospheres of terrestrial extrasolar planets is of particular interest because it might influence the position and thus the extension of the outer boundary of the classic habitable zone around main sequence stars. Here, the impact of CO2 ice clouds on the surface temperatures of terrestrial planets with CO2 dominated atmospheres, orbiting different types of...

δ13Catm and [CO2] measurements in Antarctic ice cores, 160 kyrBP - present

Science.gov (United States)

Eggleston, Sarah; Schmitt, Jochen; Schneider, Robert; Joos, Fortunat; Fischer, Hubertus

2014-05-01

Measurements from Antarctic ice cores allow us to reconstruct atmospheric concentrations of climatically important gases including CO2 over the past 800 kyr. Such measurements show that [CO2] has varied in parallel with Antarctic temperatures on glacial-interglacial timescales. Knowledge of the variations of the stable carbon isotope of CO2, δ13Catm, can help us better understand the processes involved in these fluctuations. Here, we present a first complete δ13Catmrecord extending from 160 kyrBP to the present accompanied by δ15N2 measurements during Marine Isotope Stage 3 (MIS 3, 57 - 29 kyrBP). The present record, measured primarily on ice from the EPICA Dome C and Talos Dome ice cores, has an average resolution of 500 yr, focused mainly on the Last Glacial Maximum and termination (180 yr; Schmitt et al., 2012), MIS 3 (660 yr), and Termination II through MIS 5.4 (590 yr; Schneider et al., 2013). Throughout the record, δ13Catm varies between approximately -6.8 and -6.4‰Following a period of relatively constant δ13Catm at the end of MIS 6 (around -6.8), the boundaries of MIS 5 correspond roughly with the beginning and end of a gradual enrichment in this isotope. In comparison, the more recent record depicts three more abrupt excursions to lighter values around 63 - 59, 46, and 17 kyrBP, in each case followed by a slower return (0.4o over the course of 5 - 15 kyr) to more enriched isotopic values. These coincide with Heinrich events 6, 5, and 1, respectively. No direct correlation is observed between the concentration and carbon isotope of CO2 over the last 160 kyr. The data indicate rather that numerous processes, such as uptake and release of atmospheric CO2 by the ocean and land biosphere, perhaps influenced by regions of growing permafrost during MIS 3 and 4, acting on a variety of timescales must be considered in explaining the evolution of δ13Catm on glacial-interglacial timescales. References: Schmitt, J. et al. Science 336, 711-714 (2012) Schneider

Brief Communication: Ikaite (CaCO3·6H2O discovered in Arctic sea ice

Directory of Open Access Journals (Sweden)

M. A. Granskog

2010-05-01

Full Text Available We report for the first time on the discovery of calcium carbonate crystals as ikaite (CaCO3·6H2O in sea ice from the Arctic (Kongsfjorden, Svalbard as confirmed by morphology and indirectly by X-ray diffraction as well as XANES spectroscopy of its amorophous decomposition product. This finding demonstrates that the precipitation of calcium carbonate during the freezing of sea ice is not restricted to the Antarctic, where it was observed for the first time in 2008. This observation is an important step in the quest to quantify its impact on the sea ice driven carbon cycle.

Interaction of ice storms and management practices on current carbon sequestration in forests with potential mitigation under future CO2 atmosphere

Science.gov (United States)

Heather R. McCarthy; Ram Oren; Hyun-Seok Kim; Kurt H. Johnsen; Chris Maier; Seth G. Pritchard; Michael A. Davis

2006-01-01

Ice storms are disturbance events with potential impacts on carbon sequestration. Common forest management practices, such as fertilization and thinning, can change wood and stand properties and thus may change vulnerability to ice storm damage. At the same time, increasing atmospheric CO2 levels may also influence ice storm vulnerability. Here...

Efficiency of radial transport of ices in protoplanetary disks probed with infrared observations: the case of CO2

Science.gov (United States)

Bosman, Arthur D.; Tielens, Alexander G. G. M.; van Dishoeck, Ewine F.

2018-04-01

Context. Radial transport of icy solid material from the cold outer disk to the warm inner disk is thought to be important for planet formation. However, the efficiency at which this happens is currently unconstrained. Efficient radial transport of icy dust grains could significantly alter the composition of the gas in the inner disk, enhancing the gas-phase abundances of the major ice constituents such as H2O and CO2. Aim. Our aim is to model the gaseous CO2 abundance in the inner disk and use this to probe the efficiency of icy dust transport in a viscous disk. From the model predictions, infrared CO2 spectra are simulated and features that could be tracers of icy CO2, and thus dust, radial transport efficiency are investigated. Methods: We have developed a 1D viscous disk model that includes gas accretion and gas diffusion as well as a description for grain growth and grain transport. Sublimation and freeze-out of CO2 and H2O has been included as well as a parametrisation of the CO2 chemistry. The thermo-chemical code DALI was used to model the mid-infrared spectrum of CO2, as can be observed with JWST-MIRI. Results: CO2 ice sublimating at the iceline increases the gaseous CO2 abundance to levels equal to the CO2 ice abundance of 10-5, which is three orders of magnitude more than the gaseous CO2 abundances of 10-8 observed by Spitzer. Grain growth and radial drift increase the rate at which CO2 is transported over the iceline and thus the gaseous CO2 abundance, further exacerbating the problem. In the case without radial drift, a CO2 destruction rate of at least 10-11 s-1 or a destruction timescale of at most 1000 yr is needed to reconcile model prediction with observations. This rate is at least two orders of magnitude higher than the fastest destruction rate included in chemical databases. A range of potential physical mechanisms to explain the low observed CO2 abundances are discussed. Conclusions: We conclude that transport processes in disks can have

ICE CHEMISTRY ON OUTER SOLAR SYSTEM BODIES: ELECTRON RADIOLYSIS OF N{sub 2}-, CH{sub 4}-, AND CO-CONTAINING ICES

Energy Technology Data Exchange (ETDEWEB)

Materese, Christopher K.; Cruikshank, Dale P.; Sandford, Scott A.; Imanaka, Hiroshi; Nuevo, Michel [NASA Ames Research Center, MS 245-6, Moffett Field, CA 94035-1000 (United States)

2015-10-20

Radiation processing of the surface ices of outer Solar System bodies may be an important process for the production of complex chemical species. The refractory materials resulting from radiation processing of known ices are thought to impart to them a red or brown color, as perceived in the visible spectral region. In this work, we analyzed the refractory materials produced from the 1.2-keV electron bombardment of low-temperature N{sub 2}-, CH{sub 4}-, and CO-containing ices (100:1:1), which simulates the radiation from the secondary electrons produced by cosmic ray bombardment of the surface ices of Pluto. Despite starting with extremely simple ices dominated by N{sub 2}, electron irradiation processing results in the production of refractory material with complex oxygen- and nitrogen-bearing organic molecules. These refractory materials were studied at room temperature using multiple analytical techniques including Fourier-transform infrared spectroscopy, X-ray absorption near-edge structure (XANES) spectroscopy, and gas chromatography coupled with mass spectrometry (GC-MS). Infrared spectra of the refractory material suggest the presence of alcohols, carboxylic acids, ketones, aldehydes, amines, and nitriles. XANES spectra of the material indicate the presence of carboxyl groups, amides, urea, and nitriles, and are thus consistent with the IR data. Atomic abundance ratios for the bulk composition of these residues from XANES analysis show that the organic residues are extremely N-rich, having ratios of N/C ∼ 0.9 and O/C ∼ 0.2. Finally, GC-MS data reveal that the residues contain urea as well as numerous carboxylic acids, some of which are of interest for prebiotic and biological chemistries.

Late winter under ice pelagic microbial communities in the high Arctic Ocean and the impact of short-term exposure to elevated CO2 levels

Directory of Open Access Journals (Sweden)

Adam eMonier

2014-09-01

Full Text Available Polar Oceans are natural CO2 sinks because of the enhanced solubility of CO2 in cold water. The Arctic Ocean is at additional risk of accelerated ocean acidification (OA because of freshwater inputs from sea ice and rivers, which influence the carbonate system. Winter conditions in the Arctic are of interest because of both cold temperatures and limited CO2 venting to the atmosphere when sea ice is present. Earlier OA experiments on Arctic microbial communities conducted in the absence of ice cover, hinted at shifts in taxa dominance and diversity under lowered pH. The Catlin Arctic Survey provided an opportunity to conduct in situ, under-ice, OA experiments during late Arctic winter. Seawater was collected from under the sea ice off Ellef Ringnes Island, and communities were exposed to three CO2 levels for 6 days. Phylogenetic diversity was greater in the attached fraction compared to the free-living fraction in situ, in the controls and in the treatments. The dominant taxa in all cases were Gammaproteobacteria but acidification had little effect compared to the effects of containment. Phylogenetic net relatedness indices suggested that acidification may have decreased the diversity within some bacterial orders, but overall there was no clear trend. Within the experimental communities, alkalinity best explained the variance among samples and replicates, suggesting subtle changes in the carbonate system need to be considered in such experiments. We conclude that under ice communities have the capacity to respond either by selection or phenotypic plasticity to heightened CO2 levels over the short term.

Laboratory Studies of Solid CO2 Ices at Different Temperatures and Annealing Times in Support of Spitzer Space Telescope Observations

Science.gov (United States)

White, Douglas; Gerakines, P. A.

2007-12-01

The infrared absorption features of solid carbon dioxide have been detected by space observatories in nearly all lines of sight probing the dense interstellar medium (ISM). It has also been shown that the absorption feature of solid CO2 near 658 cm-1 (15.2 μm) should be a sensitive indicator of the physical conditions of the ice (e.g., temperature and composition). However, the profile structure of this feature is not well understood, and previous laboratory studies have concentrated on a limited range of temperatures and compositions for comparisons to observed spectra from both the Infrared Space Observatory and the Spitzer Space Telescope. In the laboratory study described here, the infrared spectra of ices bearing H2O, CH3OH, and CO2 have been measured with systematically varying compositions and temperatures that span the range of the values expected in the interstellar medium. The mid-infrared spectra (λ = 2.5-25 µm) were measured for 47 different ice compositions at temperatures ranging from 5 K to evaporation (at 5 K intervals). Additionally, annealing experiments of some of these ice compositions have been investigated. These data may be used to determine thermal histories of interstellar ices. This research was supported by NASA award NNG05GE44G under the Astronomy and Physics Research & Analysis Program (APRA).

Evidence of amino acid precursors: C-N bond coupling in simulated interstellar CO2/NH3 ices

Science.gov (United States)

Esmaili, Sasan

2015-08-01

Low energy secondary electrons are abundantly produced in astrophysical or planetary ices by the numerous ionizing radiation fields typically encountered in space environments and may thus play a role in the radiation processing of such ices [1]. One approach to determine their chemical effect is to irradiate nanometer thick molecular solids of simple molecular constituents, with energy selected electron beams and to monitor changes in film chemistry with the surface analytical techniques [2].Of particular interest is the formation of HCN, which is a signature of dense gases in interstellar clouds, and is ubiquitous in the ISM. Moreover, the chemistry of HCN radiolysis products such as CN- may be essential to understand of the formation of amino acids [3] and purine DNA bases. Here we present new results on the irradiation of multilayer films of CO2 and NH3 with 70 eV electrons, leading to CN bond formations. The electron stimulated desorption (ESD) yields of cations and anions are recorded as a function of electron fluence. The prompt desorption of cationic reaction/scattering products [4], is observed at low fluence (~4x1013 electrons/cm2). Detected ions include C2+, C2O2+, C2O+, CO3+, C2O3+ or CO4+ from pure CO2, and N+, NH+, NH2+, NH3+, NH4+, N2+, N2H+ from pure NH3, and NO+, NOH+ from CO2/NH3 mixtures. Most saliently, increasing signals of negative ion products desorbing during prolonged irradiation of CO2/NH3 films included C2-, C2H-, C2H2-, as well as CN-, HCN- and H2CN-. The identification of particular product ions was accomplished by using 13CO2 and 15NH3 isotopes. The chemistry induced by electrons in pure films of CO2 and NH3 and mixtures with composition ratios (3:1), (1:1), and (1:3), was also studied by X-ray photoelectron spectroscopy (XPS). Irradiation of CO2/NH3 mixed films at 22 K produces species containing the following bonds/functional groups identified by XPS: C=O, O-H, C-C, C-O, C=N and N=O. (This work has been funded by NSERC).

Ice rink installations working with natural refrigerants; Kunst-ijsbanen met NH3 en CO2, natuurlijker kan het niet

Energy Technology Data Exchange (ETDEWEB)

Berends, E. [Grenco, Den Bosch (Netherlands)

2004-07-01

In a growing number of countries it is not allowed anymore to use big amounts of ammonia in areas occupied by many people. So new skating halls with direct ammonia systems are not built anymore although those systems are the best solution, concerning ice quality and energy consumption. An indirect system NH3/glycol or brine uses circa 20% more energy. By using (H)CFC's instead of NH3 the energy consumption might even be higher. During the last years CO2 has proven itself not only as an excellent refrigerant but also as a very usable secondary refrigerant in stead of brines, etc. In this article the successful application of the newly developed NH3/CO2 system on an existing ice rink is described. [Dutch] Een overzicht wordt gegeven van de voordelen en de nadelen van verschillende koelmiddelen voor kunstijsbanen in Nederland (ammoniak, CO2, glycol)

Synthetic gas production from dry black liquor gasification process using direct causticization with CO2 capture

International Nuclear Information System (INIS)

Naqvi, Muhammad; Yan, Jinyue; Dahlquist, Erik

2012-01-01

Highlights: ► We study synthetic gas production from dry black liquor gasification system. ► Direct causticization eliminates energy intensive lime kiln reducing biomass use. ► Results show large SNG production potential at significant energy efficiency (58%). ► Substantial CO 2 capture potential plus CO 2 reductions from natural gas replacement. ► Significant transport fuel replacement especially in Sweden and Europe. -- Abstract: Synthetic natural gas (SNG) production from dry black liquor gasification (DBLG) system is an attractive option to reduce CO 2 emissions replacing natural gas. This article evaluates the energy conversion performance of SNG production from oxygen blown circulating fluidized bed (CFB) black liquor gasification process with direct causticization by investigating system integration with a reference pulp mill producing 1000 air dried tonnes (ADt) of pulp per day. The direct causticization process eliminates use of energy intensive lime kiln that is a main component required in the conventional black liquor recovery cycle with the recovery boiler. The paper has estimated SNG production potential, the process energy ratio of black liquor (BL) conversion to SNG, and quantified the potential CO 2 abatement. Based on reference pulp mill capacity, the results indicate a large potential of SNG production (about 162 MW) from black liquor but at a cost of additional biomass import (36.7 MW) to compensate the total energy deficit. The process shows cold gas energy efficiency of about 58% considering black liquor and biomass import as major energy inputs. About 700 ktonnes per year of CO 2 abatement i.e. both possible CO 2 capture and CO 2 offset from bio-fuel use replacing natural gas, is estimated. Moreover, the SNG production offers a significant fuel replacement in transport sector especially in countries with large pulp and paper industry e.g. in Sweden, about 72% of motor gasoline and 40% of total motor fuel could be replaced.

Diurnal dynamics of the CO2 concentration in water of the coastal zone of lake Baikal in the ice period (testing of the DIEL - CO2 method for assessment of lake metabolic rate)

Science.gov (United States)

Panchenko, M. V.; Domysheva, V. M.; Pestunov, D. A.; Sakirko, M. V.; Ivanov, V. G.; Shamrin, A. M.

2017-11-01

Results of three long cycles of 24-hour measurements of the carbon dioxide content in the surface and bottom water in the ice period of 2014-2016 in the Baikal coastal zone are analyzed. The diurnal dynamics of the CO2 concentration in the subglacial water, in which photosynthesis plays the leading role, is described. It is found that, in comparison with the surface subglacial water (that is, directly adjacent to the ice bottom), the more pronounced diurnal rhythm of CO2 is observed in the bottom layer in all realizations. This rhythm is well correlated with pyranometer readings. The data on the diurnal dynamics of CO2 are used to estimate the gross primary production in the bottom water with the DIEL method based on the analysis of temporal variability of the carbon dioxide concentration in water in situ.

Freeze-drying for controlled nanoparticle distribution in Co/SiO 2 Fischer–Tropsch catalysts

NARCIS (Netherlands)

Eggenhuisen, T.M.; Munnik, P.; Talsma, H.; de Jongh, P.E.; de Jong, K.P.

2013-01-01

Controlling the nanoparticle distribution over a support is considered essential to arrive at more stable catalysts. By developing a novel freeze drying method, the nanoparticle distribution was successfully manipulated for the preparation of Co/SiO2 Fischer-Tropsch catalysts using a commercial

Supercritical CO2 extraction of raw propolis and its dry ethanolic extract

Directory of Open Access Journals (Sweden)

L. C. Paviani

2012-06-01

Full Text Available Three types of propolis extract were prepared and analyzed with respect to their global extraction yields and with respect to the concentration of the following markers: 3,5-diprenyl-4-hydroxycinnamic acid; 3-prenyl-4-hydroxycinnamic acid; 4-hydroxycinnamic acid and 4-methoxy-3,5,7-trihydroxyflavone. The extract EEP (ethanolic extract of propolis was obtained by the conventional method from raw propolis using ethanol as solvent. The extracts (SFE were obtained by supercritical solvent extraction from the raw propolis using supercritical carbon dioxide (sc-CO2, with and without the addition of ethanol as a co-solvent. The fractionated supercritical extracts (FSCE were obtained by fractionation (extract and raffinate of the dry EEP with sc-CO2. EEP yields of 39.5% were obtained and maximum global extraction yields were 7.3% for SFE with no co-solvent, 51% for SFE with 15% ethanol and 18% for the FSCE extract fraction. The concentrations of the markers in the different extracts differed as a function of the operational parameters, indicating that the addition of co-solvent and the selectivity of sc-CO2 could be manipulated so as to obtain extracts with the yields and concentrations of interest.

Transient responses of SFG spectra of D 2O ice/CO/Pt(1 1 1) interface with irradiation of ultra-short NIR pump pulses

Science.gov (United States)

Kubota, Jun; Wada, Akihide; Domen, Kazunari; Kano, Satoru S.

2002-08-01

The behavior of D 2O ice on CO/Pt(1 1 1) and Pt(1 1 1) under the irradiation of near-IR pulses (NIR) was studied by sum-frequency generation (SFG) spectroscopy. The peaks assigned to the O-D stretching modes of ice were obtained for the first 30 molecular layers on Pt(1 1 1). When the D2O/ CO/ Pt(1 1 1) was irradiated, the signal of D 2O was weakened after 500 ps, but that of CO was weakened immediately after the pumping. A similar time response was observed for the D 2O peak in D2O/ Pt(1 1 1) . The weakening of SFG is attributed to the broadening of bands due to thermal excitation. This indicates that the energy of the pump pulse is deposited on the Pt(1 1 1) surface and diffused into the layers of D 2O ice in the 500 ps timescale.

Assessing the techno-environmental performance of CO2 utilization via dry reforming of methane for the production of dimethyl ether

NARCIS (Netherlands)

Schakel, Wouter|info:eu-repo/dai/nl/369280784; Oreggioni, Gabriel; Singh, Bhawna; Strømman, Anders; Ramírez, Andrea|info:eu-repo/dai/nl/284852414

2016-01-01

Abstract CO2 utilization is gaining attention as a greenhouse gas abatement strategy complementary to CO2 storage. This study explores the techno-environmental performance of CO2 utilization trough dry reforming of methane into syngas for the production of dimethyl ether (DME). The CO2 source is a

Effect of Controlled Ice Nucleation on Stability of Lactate Dehydrogenase During Freeze-Drying.

Science.gov (United States)

Fang, Rui; Tanaka, Kazunari; Mudhivarthi, Vamsi; Bogner, Robin H; Pikal, Michael J

2018-03-01

Several controlled ice nucleation techniques have been developed to increase the efficiency of the freeze-drying process as well as to improve the quality of pharmaceutical products. Owing to the reduction in ice surface area, these techniques have the potential to reduce the degradation of proteins labile during freezing. The objective of this study was to evaluate the effect of ice nucleation temperature on the in-process stability of lactate dehydrogenase (LDH). LDH in potassium phosphate buffer was nucleated at -4°C, -8°C, and -12°C using ControLyo™ or allowed to nucleate spontaneously. Both the enzymatic activity and tetramer recovery after freeze-thawing linearly correlated with product ice nucleation temperature (n = 24). Controlled nucleation also significantly improved batch homogeneity as reflected by reduced inter-vial variation in activity and tetramer recovery. With the correlation established in the laboratory, the degradation of protein in manufacturing arising from ice nucleation temperature differences can be quantitatively predicted. The results show that controlled nucleation reduced the degradation of LDH during the freezing process, but this does not necessarily translate to vastly superior stability during the entire freeze-drying process. The capability of improving batch homogeneity provides potential advantages in scaling-up from lab to manufacturing scale. Copyright © 2018 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

Effect of elevated [CO2] and nutrient management on wet and dry season rice production in subtropical India

Institute of Scientific and Technical Information of China (English)

Sushree Sagarika Satapathy; Dillip Kumar Swain; Surendranath Pasupalak; Pratap Bhanu Singh Bhadoria

2015-01-01

The present experiment was conducted to evaluate the effect of elevated [CO2] with varying nutrient management on rice–rice production system. The experiment was conducted in the open field and inside open-top chambers（OTCs） of ambient [CO2]（≈ 390 μmol L-1） and elevated [CO2] environment（25% above ambient） during wet and dry seasons in 2011–2013at Kharagpur, India. The nutrient management included recommended doses of N, P, and K as chemical fertilizer（CF）, integration of chemical and organic sources, and application of increased（25% higher） doses of CF. The higher [CO2] level in the OTC increased aboveground biomass but marginally decreased filled grains per panicle and grain yield of rice, compared to the ambient environment. However, crop root biomass was increased significantly under elevated [CO2]. With respect to nutrient management, increasing the dose of CF increased grain yield significantly in both seasons. At the recommended dose of nutrients, integrated nutrient management was comparable to CF in the wet season, but significantly inferior in the dry season, in its effect on growth and yield of rice. The [CO2] elevation in OTC led to a marginal increase in organic C and available P content of soil, but a decrease in available N content. It was concluded that increased doses of nutrients via integration of chemical and organic sources in the wet season and chemical sources alone in the dry season will minimize the adverse effect of future climate on rice production in subtropical India.

Effect of elevated [CO2] and nutrient management on wet and dry season rice production in subtropical India

Institute of Scientific and Technical Information of China (English)

Sushree Sagarika Satapathy; Dillip Kumar Swain; Surendranath Pasupalak; Pratap Bhanu Singh Bhadoria

2015-01-01

The present experiment was conducted to evaluate the effect of elevated [CO2] with varying nutrient management on rice–rice production system. The experiment was conducted in the open field and inside open-top chambers (OTCs) of ambient [CO2] (≈390μmol L−1) and elevated [CO2] environment (25%above ambient) during wet and dry seasons in 2011–2013 at Kharagpur, India. The nutrient management included recommended doses of N, P, and K as chemical fertilizer (CF), integration of chemical and organic sources, and application of increased (25%higher) doses of CF. The higher [CO2] level in the OTC increased aboveground biomass but marginally decreased filled grains per panicle and grain yield of rice, compared to the ambient environment. However, crop root biomass was increased significantly under elevated [CO2]. With respect to nutrient management, increasing the dose of CF increased grain yield significantly in both seasons. At the recommended dose of nutrients, integrated nutrient management was comparable to CF in the wet season, but significantly inferior in the dry season, in its effect on growth and yield of rice. The [CO2] elevation in OTC led to a marginal increase in organic C and available P content of soil, but a decrease in available N content. It was concluded that increased doses of nutrients via integration of chemical and organic sources in the wet season and chemical sources alone in the dry season will minimize the adverse effect of future climate on rice production in subtropical India.

The study of ikaite (CaCO3·6H2O) formation and its impact on biogeochemical processes in artificial sea ice brine

OpenAIRE

Hu, Yubin

2014-01-01

Calcium carbonate precipitation in polar sea ice has been proposed as one of the driving forces for the carbon pump in sea ice covered regions. After decades of controversial discussion on whether calcium carbonate can be precipitated in sea ice, the mineral ikaite (CaCO3·6H2O) was for the first time discovered in Antarctic sea ice (Dieckmann et al., 2008) and later also found in Arctic sea ice (Dieckmann et al., 2010). However, the mechanism of ikaite precipitation in sea ice is not well kno...

Characterization of ikaite (CaCO3•6H2O) crystals in first year Arctic sea ice north of Svalbard

OpenAIRE

Nomura, Daiki; Assmy, Philipp; Nehrke, Gernot; Granskog, Mats A.; Fischer, Michael; Dieckmann, Gerhard; Fransson, Agneta; Hu, Yubin; Schnetger, Bernhard

2013-01-01

We identified ikaite crystals (CaCO3·6H2O) and examined their shape and size distribution in first-year Arctic pack ice, overlying snow and slush layers during the spring melt onset north of Svalbard. Additional measurements of total alkalinity (TA) were made for melted snow and sea-ice samples. Ikaite crystals were mainly found in the bottom of the snowpack, in slush and the surface layers of the sea ice where the temperature was generally lower and salinity higher than in the ic...

Estimating surface CO2 fluxes from space-borne CO2 dry air mole fraction observations using an ensemble Kalman Filter

Directory of Open Access Journals (Sweden)

S. Dance

2009-04-01

Full Text Available We have developed an ensemble Kalman Filter (EnKF to estimate 8-day regional surface fluxes of CO2 from space-borne CO2 dry-air mole fraction observations (XCO2 and evaluate the approach using a series of synthetic experiments, in preparation for data from the NASA Orbiting Carbon Observatory (OCO. The 32-day duty cycle of OCO alternates every 16 days between nadir and glint measurements of backscattered solar radiation at short-wave infrared wavelengths. The EnKF uses an ensemble of states to represent the error covariances to estimate 8-day CO2 surface fluxes over 144 geographical regions. We use a 12×8-day lag window, recognising that XCO2 measurements include surface flux information from prior time windows. The observation operator that relates surface CO2 fluxes to atmospheric distributions of XCO2 includes: a the GEOS-Chem transport model that relates surface fluxes to global 3-D distributions of CO2 concentrations, which are sampled at the time and location of OCO measurements that are cloud-free and have aerosol optical depths 2 profiles to XCO2, accounting for differences between nadir and glint measurements, and the associated scene-dependent observation errors. We show that OCO XCO2 measurements significantly reduce the uncertainties of surface CO2 flux estimates. Glint measurements are generally better at constraining ocean CO2 flux estimates. Nadir XCO2 measurements over the terrestrial tropics are sparse throughout the year because of either clouds or smoke. Glint measurements provide the most effective constraint for estimating tropical terrestrial CO2 fluxes by accurately sampling fresh continental outflow over neighbouring oceans. We also present results from sensitivity experiments that investigate how flux estimates change with 1 bias and unbiased errors, 2 alternative duty cycles, 3 measurement density and correlations, 4 the spatial resolution of estimated flux estimates, and 5 reducing the length of the lag window and the

Variability of Seasonal CO2 Ice Caps on Mars for Mars Years 26 through 29

Science.gov (United States)

Feldman, W. C.; Maurice, S.; Prettyman, T. H.

2011-12-01

We have developed an improved thermal, epithermal, and fast neutron counting-rate time series data of the Mars Odyssey Neutron Spectrometer (MONS), optimized to greatly reduce both statistical and systematic uncertainties. This new data set was applied to study temporal and spatial distributions of the growth, decay, and maximum amount of precipitated CO2 ice during Martian years (MY) 26, 27, 28, and 29. For this study, we concentrate on the epithermal counting rate detected using the down-looking prism (P1) of MONS, and a combination of the epithermal and thermal counting rate detected by the forward-looking sensor (P2) of MONS. Although the energy range of neutrons detected by P2 covers both the thermal and epithermal range, it is heavily weighted to the thermal range. We find that the variance of the maximum epithermal counting rate is remarkably small over both north and south seasonal caps, varying by less than 3% over the four-year period. In contrast, although the maximum P2 counting rate over both poles is sensibly the same within error bars (about 2%) during the first three years, it drops by 18% over the north pole and 8% over the south pole during MY 29. The most-likely explanation of this drop is that abundances of the non-condensable gases N2 and Ar, are unusually enhanced during MY 29. Movies were also made of maps of the growth and decay of P2 counting rates summed over the first three years of these data. Careful inspection shows that both the growth and decay in the north were cylindrically symmetric, centered near the geographic north pole. In contrast, both the growth and decay of CO2 buildup in the south were skewed off the geographic pole to the center of the CO2 residual cap, and contained a small, but definitely distinct ring-like annular enhancement centered at a latitude of about 83.5° S spread over a longitude range that extends between about -35° and +35° E. This arc runs parallel to, and overlays, the very steep drop in altitude from

The radiation stability of the RNA base uracil in H2O-ice and CO2-ice: in-situ laboratory measurements with applications to comets, Europa, and Mars

Science.gov (United States)

Gerakines, Perry A.; Frail, Sarah; Hudson, Reggie L.

2017-10-01

Planetary bodies of astrobiological interest, such as Mars, are often exposed to harsh incident radiation, which will influence the times that molecules can survive on them. Some or all of these bodies may well contain biologically-important organic molecules, some may even have supported life at some point in their history, and some may support life today. Future searches for organic molecules likely will include sampling the martian subsurface or a cometary surface sample return mission, where organics may be frozen in ices dominated by either H2O or CO2, which provide some protection from ionizing radiation.Recently, our research group has published studies of the radiation stability of amino acids, with a focus on glycine - in both undiluted form and in mixtures with H2O and CO2. Here, we present a similar study that focuses on the radiation-chemical kinetics of the RNA base uracil. We compare results for uracil decay for dilution in both H2O and CO2 ices. Moreover, we compare these new results with those for glycine. For each sample, we measured uracil’s destruction rate constant and half-life dose due to irradiation by 0.9-MeV protons. All measurements were made in situ at the temperature of irradiation using IR spectroscopy. Trends with dilution (up to ~300:1) and temperature (up to ~150 K) are considered, and results are discussed in the context of icy planetary surfaces.Acknowledgment: Our work is supported in part by the NASA Emerging Worlds Program and by the NASA Astrobiology Institute through the Goddard Center for Astrobiology.

Effect of biochar addition on short-term N2O and CO2 emissions during repeated drying and wetting of an anthropogenic alluvial soil.

Science.gov (United States)

Yang, Fang; Lee, Xinqing; Theng, Benny K G; Wang, Bing; Cheng, Jianzhong; Wang, Qian

2017-06-01

Agricultural soils are an important source of greenhouse gases (GHG). Biochar application to such soils has the potential of mitigating global anthropogenic GHG emissions. Under irrigation, the topsoils in arid regions experience repeated drying and wetting during the crop growing season. Biochar incorporation into these soils would change the soil microbial environment and hence affect GHG emissions. Little information, however, is available regarding the effect of biochar addition on carbon dioxide (CO 2 ) and nitrous oxide (N 2 O) emissions from agricultural soils undergoing repeated drying and wetting. Here, we report the results of a 49-day aerobic incubation experiment, incorporating biochar into an anthropogenic alluvial soil in an arid region of Xinjiang Province, China, and measuring CO 2 and N 2 O emissions. Under both drying-wetting and constantly moist conditions, biochar amendment significantly increased cumulative CO 2 emission. At the same time, there was a significant reduction (up to ~20 %) in cumulative N 2 O emission, indicating that the addition of biochar to irrigated agricultural soils may effectively slow down global warming in arid regions of China.

CO2 cycle

Science.gov (United States)

Titus, Timothy N.; Byrne, Shane; Colaprete, Anthony; Forget, Francois; Michaels, Timothy I.; Prettyman, Thomas H.

2017-01-01

This chapter discusses the use of models, observations, and laboratory experiments to understand the cycling of CO2 between the atmosphere and seasonal Martian polar caps. This cycle is primarily controlled by the polar heat budget, and thus the emphasis here is on its components, including solar and infrared radiation, the effect of clouds (water- and CO2-ice), atmospheric transport, and subsurface heat conduction. There is a discussion about cap properties including growth and regression rates, albedos and emissivities, grain sizes and dust and/or water-ice contamination, and curious features like cold gas jets and araneiform (spider-shaped) terrain. The nature of the residual south polar cap is discussed as well as its long-term stability and ability to buffer atmospheric pressures. There is also a discussion of the consequences of the CO2 cycle as revealed by the non-condensable gas enrichment observed by Odyssey and modeled by various groups.

An ice rink refrigeration system based on CO{sub 2} as secondary fluid in copper tubes

Energy Technology Data Exchange (ETDEWEB)

Shahzad, Khuram [Royal Inst. of Technology, Stockholrn (Sweden). Dept. of Energy Technology

2006-06-15

This report is a study of the use of copper tubes with CO{sub 2} as heat transfer fluid in ice rink applications. Copper tubes can be rolled rather easily up to the required length which decreases installation cost and simplifies the procedure. A test ice rink was built at IUC Ref Centre, Katrineholm with copper tubes. FEMLAB and EES are two softwares that were used for analysis. The comparison between 12.7 mm diameter copper tubes with and without plastic foil cover, 9.5 mm diameter copper tubes with and without plastic foil cover, 21.3 mm diameter steel pipes and 25 mm diameter plastic pipes is presented in the report. The reason to have plastic foil over copper tubes is to avoid the minor risk of chemical corrosion. Furthermore the foil serves as mechanical wear protection as well, which in this case could appear if rubbing would occur due to thermal expansion and contraction. It is found that 12.7 mm copper tube with plastic foil is good choice in terms of heat transfer. At rated heat flux of 100 W/m{sup 2} and with a pitch of 100 mm, it is 0.18 deg C better than 9.5 mm copper tube with plastic foil. This report includes the investigation which shows that there is no danger of movement of copper tubes inside the rink bed due to thermal expansion and contraction during operation. It also includes the comparison of average Friedel pressure drop model and average homogeneous pressure drop model with experimental results. Average Friedel pressure drop method gave good results. It predicted 20 to 25 % higher pressure drop at lower CR and about 60 % at higher CR than the experimental results for 120 meter long and 12.7 mm diameter copper tubes. 120 meter long copper tubes are good choice; as header can be placed on short side of the ice rink. It will reduce the header length and connections to half. FEMLAB modelling for conduction heat transfer gave good results and can be used as a tool for design and optimization. The optimization of the pitch of the copper tubes

Fundamentals and applications of dry CO2 cryogenic aerosol for photomask cleaning

Science.gov (United States)

Varghese, Ivin; Balooch, Mehdi; Bowers, Charles W.

2010-09-01

There is a dire need for the removal of all printable defects on lithography masks. As the technology node advances, smaller particles need to be efficiently removed from smaller features without any damage or adders. CO2 cryogenic aerosol cleaning is a dry, residue-free and chemically inert technique that doesn't suffer from disadvantages of conventional wet cleaning methods such as transmission/reflectivity loss, phase change, CD change, haze/progressive defects, and/or limitation on number of cleaning cycles. Ultra-pure liquid CO2 when dispensed through an optimally designed nozzle results in CO2 clusters that impart the required momentum for defect removal. Historically nanomachining debris removal has been established with this technique. Several improvements have been incorporated for cleaning of advanced node masks, which has enabled Full Mask Final Clean, a new capability that has been successfully demonstrated. The properties of the CO2 clusters can be captured utilizing the Phase Doppler Anemometry (PDA) and effect of varying process and design parameters can be verified. New nozzles have been designed to widen the cleaning process window for advanced node optical masks, without any damage to the weak primary features and/or sub-resolution assist features (SRAFs). This capability has been experimentally proven for high aspect ratio SRAFs e.g. 2.79 (52nm wide by 145 nm tall) as well as SRAFs 45nm wide by 73 nm tall. In this paper, 100% removal of soft defects that would have printed on advanced node masks is demonstrated. No printed defects larger than 50nm is observed after the CO2 cleaning. Stability of the cleaning and handling mechanisms has been demonstrated over the last 4.5 months in a production environment. The CO2 cleaning technique is expected to be effective for more advanced masks and Extreme Ultra-Violet (EUV) lithography.

Controlled ice nucleation using freeze-dried Pseudomonas syringae encapsulated in alginate beads.

Science.gov (United States)

Weng, Lindong; Tessier, Shannon N; Swei, Anisa; Stott, Shannon L; Toner, Mehmet

2017-04-01

The control of ice nucleation is of fundamental significance in many process technologies related to food and pharmaceutical science and cryobiology. Mechanical perturbation, electromagnetic fields and ice-nucleating agents (INAs) have been known to induce ice nucleation in a controlled manner. But these ice-nucleating methods may suffer from cumbersome manual operations, safety concerns of external fields, and biocompatibility and recovery issues of INA particles, especially when used in living systems. Given the automatic ice-seeding nature of INAs, a promising solution to overcome some of the above limitations is to engineer a biocomposite that accommodates the INA particles but minimizes their interactions with biologics, as well as enabling the recovery of used particles. In this study, freeze-dried Pseudomonas syringae, a model ice-nucleating agent, was encapsulated into microliter-sized alginate beads. We evaluated the performance of the bacterial hydrogel beads to initiate ice nucleation in water and aqueous glycerol solution by investigating factors including the size and number of the beads and the local concentration of INA particles. In the aqueous sample of a fixed volume, the total mass of the INA particles (m) was found to be the governing parameter that is solely responsible for determining the ice nucleation performance of the bacterial hydrogel beads. The freezing temperature has a strong positive linear correlation with log 10 m. The findings in this study provide an effective, predictable approach to control ice nucleation, which can improve the outcome and standardization of many ice-assisted process technologies. Copyright © 2017 Elsevier Inc. All rights reserved.

Between ice and gas: CO2 on the icy satellites of Jupiter and Saturn

Science.gov (United States)

Hibbitts, C.

2010-12-01

CO2 exists in the surfaces of the icy Galilean and Saturnian satellites [1-6], yet despite its discovery over a decade ago on Ganymede, and five years ago on the Saturnian satellites, its nature is still debated [7]. On the Galilean satellites Callisto and Ganymede, the CO2 that is detected is bound to, or trapped within, the non-ice materials that prevent it from sublimating or otherwise escaping from the surface. On Europa, it resides within both the ice and nonice materials [8,9]. While greater abundances of CO2 may exist in the interiors of these moons, or small amounts may be continually created through particle bombardment of the surface, the observed CO2 is only a trace material, with a few hundred molecules responsible for the deepest absorption features and an estimated molar abundance of 0.1% [2; 10-12]. Yet its presence may provide essential clues to processes that shape the surfaces of the moon [13] and potentially key to understanding the composition of potential oceans in the subsurfaces. We continue measurements of the infrared properties associated with CO2 adsorbed onto nonice materials under pressures and at temperatures relevant to these icy satellites using bidirectional reflectance spectroscopy from ~ 1.5 to 5.5 μm. Previous measurements, using transmission spectroscopy, demonstrated both a compositional and a temperature dependence on the spectral signature of adsorbed CO2 [14]. Bidirectional spectroscopy enables detection of lower concentrations of adsorbate on fine-grained materials such as clays due to their large surface area to volume ratios and thus large surface areas that may be covered by adsorbate [15]. The effectiveness of transmission spectroscopy was also limited by the strong absorption of light within the pressed sample and its impermeability, which limited the coverage by adsorbate to the pellet’s outer surface. All measurements demonstrate that CO2 adsorbs onto montmorillonite clays, possibly due to its quadrupole moment

Synthesis of HCN and HNC in Ion-Irradiated N2-Rich Ices

Science.gov (United States)

Moore, M. H.; Hudson, R. L.; Ferrante, R. F.

2002-11-01

Near-IR observations reveal that nitrogen-rich ice containing small amounts of methane, CH4, and carbon monoxide, CO, is abundant on the surfaces of Triton, a moon of Neptune, and Pluto (Cruikshank et al.. 1993; Owen et al., 1993). N2-rich apolar ices are also possible in some interstellar environments (Ehrenfreund et al., 1998). To investigate the radiation chemical behavior of N2-dominated ices we performed a systematic IR study of ion-irradiated N2-rich ices containing CH4 and CO. Experiments at 18 K, showed that HCN, HNC, and the reactive molecule diazomethane, CH2N2, formed along with several radicals. NH3 was also identified in irradiated N2 + CH4. Comparing results from similarly photolyzed ices (Bohn et al., 1994) shows that the significant difference between radiolysis and photolysis of these N2-dominated ices is that photolyzed ices do not form detectable HCN and HNC. Our experiments examined different N2/CH4 ratios, the half-life of CH4, possible HCN and HNC formation routes, and competing pathways in the presence of CO. Intrinsic band strengths (A(HCN) and A(HNC)) were measured and used to calculate nearly equal values of HCN and HNC yields in N2+CH4 irradiated ices. Low temperature results apply to interstellar ices. Reaction products that appear at 30-35 K are also expected to form and survive on the surfaces of Triton and Pluto and interstellar grains. We examined the evolution of ice features as species undergo acid-base (acids such as HCN, HNC, HNCO and a base NH3) reactions triggered by warming from 18 K to 30-35 K. We identified anions (OCN-, CN- and N3-) attributed to relatively stable salts in ices where NH4+ is the likely cation. These results also have an astrobiology implication since many of these products (HCN, HNC, HNCO, NH3, NH4OCN, and NH4CN) are reactants used in synthesis studies of bio- molecules such as amino acids and peptides.

Production of nanostructured molecular liquids by supercritical CO2 processing

Directory of Open Access Journals (Sweden)

Sudhir Kumar Sharma

2017-01-01

Full Text Available Stable molecular clusters of ibuprofen and naproxen were prepared in dry ice, by supersonic jet expansion of their supercritical CO2 drug formulations into a liquid nitrogen cooled collection vessel, with up to 80% yield. Mixing the “dry ice” in water, resulted in the solubilization of the clusters and in the case of ibuprofen, we were able to create solutions, with concentrations of up to 6 mg/ml, a 300-fold increase over previously reported values. Drop casting and ambient drying of these solutions on silicon substrate resulted in a stable, viscous liquid film, referred to as nanostructured molecular liquids. These liquids exhibited a highly aligned, fine (self-assembled super lattice features. In vitro cancer cell viability studies of these formulations exhibited similar cytotoxicity to that of the original raw materials, thus retaining their original potency. Besides its scientific importance, this invention is expected to open up new drug delivery platforms.

Long-Term Observations of Atmospheric CO2, O3 and BrO over the Transitioning Arctic Ocean Pack-ice: The O-Buoy Chemical Network

Science.gov (United States)

Matrai, P.

2016-02-01

Autonomous, sea ice-tethered O-Buoys have been deployed (2009-2016) across the Arctic sea ice for long-term atmospheric measurements (http://www.o-buoy.org). O-Buoys (15) provide in-situ concentrations of three sentinel atmospheric chemicals, ozone, CO2 and BrO, as well as meteorological parameters and imagery, over the frozen ocean. O-Buoys were designed to transmit daily data over a period of 2 years while deployed in sea ice, as part of automated ice-drifting stations that include snow/ice measurement systems (e.g. Ice Mass Balance buoys) and oceanographic measurements (e.g. Ice Tethered Profilers). Seasonal changes in Arctic atmospheric chemistry are influenced by changes in the characteristics and presence of the sea ice vs. open water as well as air mass trajectories, especially during the winter-spring and summer-fall transitions when sea ice is melting and freezing, respectively. The O-Buoy Chemical Network provides the unique opportunity to observe these transition periods in real-time with high temporal resolution, and to compare them with those collected on land-based monitoring stations located. Due to the logistical challenges of measurements over the Arctic Ocean region, most long term, in-situ observations of atmospheric chemistry have been made at coastal or island sites around the periphery of the Arctic Ocean, leaving large spatial and temporal gaps that O-Buoys overcome. Advances in floatation, communications, power management, and sensor hardware have been made to overcome the challenges of diminished Arctic sea ice. O-Buoy data provide insights into enhanced seasonal, interannual and spatial variability in atmospheric composition, atmospheric boundary layer control on the amount of halogen activation, enhancement of the atmospheric CO2 signal over the more variable and porous pack ice, and to develop an integrated picture of the coupled ocean/ice/atmosphere system. As part of the Arctic Observing Network, we provide data to the community (www.aoncadis.org).

Recent Scientific Progress on Developing Supported Ni Catalysts for Dry (CO2 Reforming of Methane

Directory of Open Access Journals (Sweden)

Hyun Ook Seo

2018-03-01

Full Text Available Two major green house gases (CO2 and CH4 can be converted into useful synthetic gas (H2 and CO during dry reforming of methane (DRM reaction, and a lot of scientific efforts has been made to develop efficient catalysts for dry reforming of methane (DRM. Noble metal-based catalysts can effectively assist DRM reaction, however they are not economically viable. Alternatively, non-noble based catalysts have been studied so far, and supported Ni catalysts have been considered as a promising candidate for DRM catalyst. Main drawback of Ni catalysts is its catalytic instability under operating conditions of DRM (>700 °C. Recently, it has been demonstrated that the appropriate choice of metal-oxide supports can address this issue since the chemical and physical of metal-oxide supports can prevent coke formation and stabilize the small Ni nanoparticles under harsh conditions of DRM operation. This mini-review covers the recent scientific findings on the development of supported Ni catalysts for DRM reaction, including the synthetic methods of supported Ni nanoparticles with high sintering resistance.

Sea-ice dynamics strongly promote Snowball Earth initiation and destabilize tropical sea-ice margins

Directory of Open Access Journals (Sweden)

A. Voigt

2012-12-01

Full Text Available The Snowball Earth bifurcation, or runaway ice-albedo feedback, is defined for particular boundary conditions by a critical CO₂ and a critical sea-ice cover (SI, both of which are essential for evaluating hypotheses related to Neoproterozoic glaciations. Previous work has shown that the Snowball Earth bifurcation, denoted as (CO₂, SI^*, differs greatly among climate models. Here, we study the effect of bare sea-ice albedo, sea-ice dynamics and ocean heat transport on (CO₂, SI^* in the atmosphere–ocean general circulation model ECHAM5/MPI-OM with Marinoan (~ 635 Ma continents and solar insolation (94% of modern. In its standard setup, ECHAM5/MPI-OM initiates a~Snowball Earth much more easily than other climate models at (CO₂, SI^* ≈ (500 ppm, 55%. Replacing the model's standard bare sea-ice albedo of 0.75 by a much lower value of 0.45, we find (CO₂, SI^* ≈ (204 ppm, 70%. This is consistent with previous work and results from net evaporation and local melting near the sea-ice margin. When we additionally disable sea-ice dynamics, we find that the Snowball Earth bifurcation can be pushed even closer to the equator and occurs at a hundred times lower CO₂: (CO₂, SI^* ≈ (2 ppm, 85%. Therefore, the simulation of sea-ice dynamics in ECHAM5/MPI-OM is a dominant determinant of its high critical CO₂ for Snowball initiation relative to other models. Ocean heat transport has no effect on the critical sea-ice cover and only slightly decreases the critical CO₂. For disabled sea-ice dynamics, the state with 85% sea-ice cover is stabilized by the Jormungand mechanism and shares characteristics with the Jormungand climate states. However, there is no indication of the Jormungand bifurcation and hysteresis in ECHAM5/MPI-OM. The state with 85% sea-ice cover therefore is a soft Snowball state rather than a true

Evaluation of Dry Sorbent Injection Technology for Pre-Combustion CO{sub 2} Capture

Energy Technology Data Exchange (ETDEWEB)

Richardson, Carl [URS Group, Inc., Austin, TX (United States); Steen, William [URS Group, Inc., Austin, TX (United States); Triana, Eugenio [URS Group, Inc., Austin, TX (United States); Machalek, Thomas [URS Group, Inc., Austin, TX (United States); Davila, Jenny [URS Group, Inc., Austin, TX (United States); Schmit, Claire [URS Group, Inc., Austin, TX (United States); Wang, Andrew [URS Group, Inc., Austin, TX (United States); Temple, Brian [URS Group, Inc., Austin, TX (United States); Lu, Yongqi [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Lu, Hong [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Zhang, Luzheng [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Ruhter, David [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Rostam-Abadi, Massoud [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Sayyah, Maryam [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Ito, Brandon [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Suslick, Kenneth [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States)

2013-09-30

This document summarizes the work performed on Cooperative Agreement DE-FE0000465, “Evaluation of Dry Sorbent Technology for Pre-Combustion CO{sub 2} Capture,” during the period of performance of January 1, 2010 through September 30, 2013. This project involves the development of a novel technology that combines a dry sorbent-based carbon capture process with the water-gas-shift reaction for separating CO{sub 2} from syngas. The project objectives were to model, develop, synthesize and screen sorbents for CO{sub 2} capture from gasified coal streams. The project was funded by the DOE National Energy Technology Laboratory with URS as the prime contractor. Illinois Clean Coal Institute and The University of Illinois Urbana-Champaign were project co-funders. The objectives of this project were to identify and evaluate sorbent materials and concepts that were suitable for capturing carbon dioxide (CO{sub 2}) from warm/hot water-gas-shift (WGS) systems under conditions that minimize energy penalties and provide continuous gas flow to advanced synthesis gas combustion and processing systems. Objectives included identifying and evaluating sorbents that efficiently capture CO{sub 2} from a gas stream containing CO{sub 2}, carbon monoxide (CO), and hydrogen (H{sub 2}) at temperatures as high as 650 °C and pressures of 400-600 psi. After capturing the CO{sub 2}, the sorbents would ideally be regenerated using steam, or other condensable purge vapors. Results from the adsorption and regeneration testing were used to determine an optimal design scheme for a sorbent enhanced water gas shift (SEWGS) process and evaluate the technical and economic viability of the dry sorbent approach for CO{sub 2} capture. Project work included computational modeling, which was performed to identify key sorbent properties for the SEWGS process. Thermodynamic modeling was used to identify optimal physical properties for sorbents and helped down-select from the universe of possible sorbent

Seasonal variation of air-sea CO2 fluxes in the Terra Nova Bay of the Ross Sea, Antarctica, based on year-round pCO2 observations

Science.gov (United States)

Zappa, C. J.; Rhee, T. S.; Kwon, Y. S.; Choi, T.; Yang, E. J.; Kim, J.

2017-12-01

The polar oceans are rapidly changing in response to climate variability. In particular, augmented inflow of glacial melt water and shrinking sea-ice extent impacts the polar coastal oceans, which may in turn shift the biogeochemistry into an unprecedented paradigm not experienced previously. Nonetheless, most research in the polar oceans is limited to the summer season. Here, we present the first direct observations of ocean and atmospheric pCO2 measured near the coast of Terra Nova Bay in the Ross Sea, Antarctica, ongoing since February, 2015 at Jang Bogo Station. The coastal area is covered by landfast sea-ice from spring to fall while continually exposed to the atmosphere during summer season only. The pCO2 in seawater swung from 120 matm in February to 425 matm in early October. Although sea-ice still covers the coastal area, pCO2 already started decreasing after reaching the peak in October. In November, the pCO2 suddenly dropped as much as 100 matm in a week. This decrease of pCO2 continued until late February when the sea-ice concentration was minimal. With growing sea ice, the pCO2 increased logarithmically reaching the atmospheric concentration in June/July, depending on the year, and continued to increase until October. Daily mean air-sea CO2 flux in the coastal area widely varied from -70 mmol m-2 d-1 to 20 mmol m-2 d-1. Based on these observations of pCO2 in Terra Nova Bay, the annual uptake of CO2 is 8 g C m-2, estimated using the fraction of sea-ice concentration estimated from AMSR2 microwave emission imagery. Extrapolating to all polynyas surrounding Antarctica, we expect the annual uptake of 8 Tg C in the atmosphere. This is comparable to the amount of CO2 degassed into the atmosphere south of the Antarctic Polar Front (62°S).

Identifying Different Types of Catalysts for CO2 Reduction by Ethane through Dry Reforming and Oxidative Dehydrogenation.

Science.gov (United States)

Porosoff, Marc D; Myint, Myat Noe Zin; Kattel, Shyam; Xie, Zhenhua; Gomez, Elaine; Liu, Ping; Chen, Jingguang G

2015-12-14

The recent shale gas boom combined with the requirement to reduce atmospheric CO2 have created an opportunity for using both raw materials (shale gas and CO2 ) in a single process. Shale gas is primarily made up of methane, but ethane comprises about 10 % and reserves are underutilized. Two routes have been investigated by combining ethane decomposition with CO2 reduction to produce products of higher value. The first reaction is ethane dry reforming which produces synthesis gas (CO+H2 ). The second route is oxidative dehydrogenation which produces ethylene using CO2 as a soft oxidant. The results of this study indicate that the Pt/CeO2 catalyst shows promise for the production of synthesis gas, while Mo2 C-based materials preserve the CC bond of ethane to produce ethylene. These findings are supported by density functional theory (DFT) calculations and X-ray absorption near-edge spectroscopy (XANES) characterization of the catalysts under in situ reaction conditions. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

CHEMICAL EVOLUTION OF A CO ICE INDUCED BY SOFT X-RAYS

Energy Technology Data Exchange (ETDEWEB)

Ciaravella, A.; Cecchi-Pestellini, C.; Jiménez-Escobar, A. [INAF—Osservatorio Astronomico di Palermo, P.za Parlamento 1, I-90134 Palermo (Italy); Chen, Y.-J.; Chuang, K.-J.; Huang, C.-H. [Department of Physics, National Central University, Jhongli City, Taoyuan County 32054, Taiwan (China); Muñoz Caro, G. M., E-mail: aciaravella@astropa.unipa.it [Centro de Astrobiología (INTA-CSIC), Carretera de Ajalvir, km 4, Torrejón de Ardoz, E-28850 Madrid (Spain)

2016-03-01

We irradiated a pure carbon monoxide ice with soft X-rays of energies up to 1.2 keV. The experiments were performed using the spherical grating monochromator beamline at the National Synchrotron Radiation Research Center in Taiwan, exploiting both monochromatic (at 0.3 and 0.55 keV) and broader energy (0.25–1.2 keV) fluxes. The infrared spectra of the irradiated ices showed the formation of a number of products such as polycarbon mono- and dioxides C{sub n}O{sub m}, and chains containing up to 10 carbon atoms. While a gentle increase in the energy absorbed by the ice sample is reflected by an increase in the column densities of newly born species, such correlation breaks down at very high fluxes. In this regime the production yield falls down sharply by about a factor of 100. The refractory residue obtained in the broad energy irradiation is a “compromise” between those obtained with proton irradiation of C{sub 3}O{sub 2} and CO ices in previous experiments. Finally, we discuss the possible implications for space chemistry.

Dry (CO_2) reforming of methane over Pt catalysts studied by DFT and kinetic modeling

International Nuclear Information System (INIS)

Niu, Juntian; Du, Xuesen; Ran, Jingyu; Wang, Ruirui

2016-01-01

Graphical abstract: - Highlights: • CH appears to be the most abundant species on Pt(1 1 1) surface in CH_4 dissociation. • CO_2* + H* → COOH* + * → CO* + OH* is the dominant reaction pathway in CO_2 activation. • Major reaction pathway in CH oxidation: CH* + OH* → CHOH* + * → CHO* + H* → CO* + 2H*. • C* + OH* → COH* + * → CO* + H* is the dominant reaction pathway in C oxidation. - Abstract: Dry reforming of methane (DRM) is a well-studied reaction that is of both scientific and industrial importance. In order to design catalysts that minimize the deactivation and improve the selectivity and activity for a high H_2/CO yield, it is necessary to understand the elementary reaction steps involved in activation and conversion of CO_2 and CH_4. In our present work, a microkinetic model based on density functional theory (DFT) calculations is applied to explore the reaction mechanism for methane dry reforming on Pt catalysts. The adsorption energies of the reactants, intermediates and products, and the activation barriers for the elementary reactions involved in the DRM process are calculated over the Pt(1 1 1) surface. In the process of CH_4 direct dissociation, the kinetic results show that CH dissociative adsorption on Pt(1 1 1) surface is the rate-determining step. CH appears to be the most abundant species on the Pt(1 1 1) surface, suggesting that carbon deposition is not easy to form in CH_4 dehydrogenation on Pt(1 1 1) surface. In the process of CO_2 activation, three possible reaction pathways are considered to contribute to the CO_2 decomposition: (I) CO_2* + * → CO* + O*; (II) CO_2* + H* → COOH* + * → CO* + OH*; (III) CO_2* + H* → mono-HCOO* + * → bi-HCOO* + * [CO_2* + H* → bi-HCOO* + *] → CHO* + O*. Path I requires process to overcome the activation barrier of 1.809 eV and the forward reaction is calculated to be strongly endothermic by 1.430 eV. In addition, the kinetic results also indicate this process is not easy to

Formation of interstellar methanol ice prior to the heavy CO freeze-out stage

Science.gov (United States)

Qasim, D.; Chuang, K.-J.; Fedoseev, G.; Ioppolo, S.; Boogert, A. C. A.; Linnartz, H.

2018-04-01

Context. The formation of methanol (CH3OH) on icy grain mantles during the star formation cycle is mainly associated with the CO freeze-out stage. Yet there are reasons to believe that CH3OH also can form at an earlier period of interstellar ice evolution in CO-poor and H2O-rich ices. Aims: This work focuses on CH3OH formation in a H2O-rich interstellar ice environment following the OH-mediated H-abstraction in the reaction, CH4 + OH. Experimental conditions are systematically varied to constrain the CH3OH formation yield at astronomically relevant temperatures. Methods: CH4, O2, and hydrogen atoms are co-deposited in an ultrahigh vacuum chamber at 10-20 K. OH radicals are generated by the H + O2 surface reaction. Temperature programmed desorption - quadrupole mass spectrometry (TPD-QMS) is used to characterize CH3OH formation, and is complemented with reflection absorption infrared spectroscopy (RAIRS) for CH3OH characterization and quantitation. Results: CH3OH formation is shown to be possible by the sequential surface reaction chain, CH4 + OH → CH3 + H2O and CH3 + OH → CH3OH at 10-20 K. This reaction is enhanced by tunneling, as noted in a recent theoretical investigation Lamberts et al. (2017, A&A, 599, A132). The CH3OH formation yield via the CH4 + OH route versus the CO + H route is approximately 20 times smaller for the laboratory settings studied. The astronomical relevance of the new formation channel investigated here is discussed.

Efficacy of dry-ice blasting in preventive maintenance of auto robotic assemblies

Science.gov (United States)

Baluch, Nazim; Mohtar, Shahimi; Abdullah, Che Sobry

2016-08-01

Welding robots are extensively applied in the automotive assemblies and `Spot Welding' is the most common welding application found in the auto stamping assembly manufacturing. Every manufacturing process is subject to variations - with resistance welding, these include; part fit up, part thickness variations, misaligned electrodes, variations in coating materials or thickness, sealers, weld force variations, shunting, machine tooling degradation; and slag and spatter damage. All welding gun tips undergo wear; an elemental part of the process. Though adaptive resistance welding control automatically compensates to keep production and quality up to the levels needed as gun tips undergo wear so that the welds remain reliable; the system cannot compensate for deterioration caused by the slag and spatter on the part holding fixtures, sensors, and gun tips. To cleanse welding robots of slag and spatter, dry-ice blasting has proven to be an effective remedy. This paper describes Spot welding process, analyses the slag and spatter formation during robotic welding of stamping assemblies, and concludes that the dry ice blasting process's utility in cleansing of welding robots in auto stamping plant operations is paramount and exigent.

From 14C/12C measurements towards radiocarbon dating of ice

NARCIS (Netherlands)

Oerlemans, J.; Wal, R.S.W. van de; Roijen, J.J. van; Raynaud, D.; Borg, K. van der; Jong, A.F.M. de; Lipenkov, V.; Huybrechts, P.

1994-01-01

A dry extraction method of CO2 included in glacier ice adds a contamination equivalent to 1.8 μg modern carbon for a 35 μg C sample. This enables radiocarbon dating by accelerator mass spectrometry of 35 μg C samples to about 25 000 BP. Measured 14C/12C ratios are presented for a part of the Vostok

The Abundance of Atmospheric CO{sub 2} in Ocean Exoplanets: a Novel CO{sub 2} Deposition Mechanism

Energy Technology Data Exchange (ETDEWEB)

Levi, A.; Sasselov, D. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Podolak, M., E-mail: amitlevi.planetphys@gmail.com [Dept. of Geosciences, Tel Aviv University, Tel Aviv, 69978 (Israel)

2017-03-20

We consider super-Earth sized planets which have a water mass fraction large enough to form an external mantle composed of high-pressure water-ice polymorphs and also lack a substantial H/He atmosphere. We consider such planets in their habitable zone, so that their outermost condensed mantle is a global, deep, liquid ocean. For these ocean planets, we investigate potential internal reservoirs of CO{sub 2}, the amount of CO{sub 2} dissolved in the ocean for the various saturation conditions encountered, and the ocean-atmosphere exchange flux of CO{sub 2}. We find that, in a steady state, the abundance of CO{sub 2} in the atmosphere has two possible states. When wind-driven circulation is the dominant CO{sub 2} exchange mechanism, an atmosphere of tens of bars of CO{sub 2} results, where the exact value depends on the subtropical ocean surface temperature and the deep ocean temperature. When sea-ice formation, acting on these planets as a CO{sub 2} deposition mechanism, is the dominant exchange mechanism, an atmosphere of a few bars of CO{sub 2} is established. The exact value depends on the subpolar surface temperature. Our results suggest the possibility of a negative feedback mechanism, unique to water planets, where a reduction in the subpolar temperature drives more CO{sub 2} into the atmosphere to increase the greenhouse effect.

Simulation and experiment for oxygen-enriched combustion engine using liquid oxygen to solidify CO2

Science.gov (United States)

Liu, Yongfeng; Jia, Xiaoshe; Pei, Pucheng; Lu, Yong; Yi, Li; Shi, Yan

2016-01-01

For capturing and recycling of CO2 in the internal combustion engine, Rankle cycle engine can reduce the exhaust pollutants effectively under the condition of ensuring the engine thermal efficiency by using the techniques of spraying water in the cylinder and optimizing the ignition advance angle. However, due to the water spray nozzle need to be installed on the cylinder, which increases the cylinder head design difficulty and makes the combustion conditions become more complicated. In this paper, a new method is presented to carry out the closing inlet and exhaust system for internal combustion engines. The proposed new method uses liquid oxygen to solidify part of cooled CO2 from exhaust system into dry ice and the liquid oxygen turns into gas oxygen which is sent to inlet system. The other part of CO2 is sent to inlet system and mixed with oxygen, which can reduce the oxygen-enriched combustion detonation tendency and make combustion stable. Computing grid of the IP52FMI single-cylinder four-stroke gasoline-engine is established according to the actual shape of the combustion chamber using KIVA-3V program. The effects of exhaust gas recirculation (EGR) rate are analyzed on the temperatures, the pressures and the instantaneous heat release rates when the EGR rate is more than 8%. The possibility of enclosing intake and exhaust system for engine is verified. The carbon dioxide trapping device is designed and the IP52FMI engine is transformed and the CO2 capture experiment is carried out. The experimental results show that when the EGR rate is 36% for the optimum EGR rate. When the liquid oxygen of 35.80-437.40 g is imported into the device and last 1-20 min, respectively, 21.50-701.30 g dry ice is obtained. This research proposes a new design method which can capture CO2 for vehicular internal combustion engine.

CO2 Orbital Trends in Comets

Science.gov (United States)

Kelley, Michael; Feaga, Lori; Bodewits, Dennis; McKay, Adam; Snodgrass, Colin; Wooden, Diane

2014-12-01

Spacecraft missions to comets return a treasure trove of details of their targets, e.g., the Rosetta mission to comet 67P/Churyumov-Gerasimenko, the Deep Impact experiment at comet 9P/Tempel 1, or even the flyby of C/2013 A1 (Siding Spring) at Mars. Yet, missions are rare, the diversity of comets is large, few comets are easily accessible, and comet flybys essentially return snapshots of their target nuclei. Thus, telescopic observations are necessary to place the mission data within the context of each comet's long-term behavior, and to further connect mission results to the comet population as a whole. We propose a large Cycle 11 project to study the long-term activity of past and potential future mission targets, and select bright Oort cloud comets to infer comet nucleus properties, which would otherwise require flyby missions. In the classical comet model, cometary mass loss is driven by the sublimation of water ice. However, recent discoveries suggest that the more volatile CO and CO2 ices are the likely drivers of some comet active regions. Surprisingly, CO2 drove most of the activity of comet Hartley 2 at only 1 AU from the Sun where vigorous water ice sublimation would be expected to dominate. Currently, little is known about the role of CO2 in comet activity because telluric absorptions prohibit monitoring from the ground. In our Cycle 11 project, we will study the CO2 activity of our targets through IRAC photometry. In conjunction with prior observations of CO2 and CO, as well as future data sets (JWST) and ongoing Earth-based projects led by members of our team, we will investigate both long-term activity trends in our target comets, with a particular goal to ascertain the connections between each comet's coma and nucleus.

CO2 as a refrigerant

CERN Document Server

2014-01-01

A first edition, the IIR guide “CO2 as a Refrigerant” highlights the application of carbon dioxide in supermarkets, industrial freezers, refrigerated transport, and cold stores as well as ice rinks, chillers, air conditioning systems, data centers and heat pumps. This guide is for design and development engineers needing instruction and inspiration as well as non-technical experts seeking background information on a specific topic. Written by Dr A.B. Pearson, a well-known expert in the field who has considerable experience in the use of CO2 as a refrigerant. Main topics: Thermophysical properties of CO2 – Exposure to CO2, safety precautions – CO2 Plant Design – CO2 applications – Future prospects – Standards and regulations – Bibliography.

Dry (CO{sub 2}) reforming of methane over Pt catalysts studied by DFT and kinetic modeling

Energy Technology Data Exchange (ETDEWEB)

Niu, Juntian [Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Ministry of Education of PRC, Chongqing University, Chongqing, 400044 (China); College of Power Engineering, Chongqing University, Chongqing, 400044 (China); Du, Xuesen, E-mail: xuesendu@cqu.edu.cn [Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Ministry of Education of PRC, Chongqing University, Chongqing, 400044 (China); College of Power Engineering, Chongqing University, Chongqing, 400044 (China); Ran, Jingyu, E-mail: jyran@189.cn [Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Ministry of Education of PRC, Chongqing University, Chongqing, 400044 (China); College of Power Engineering, Chongqing University, Chongqing, 400044 (China); Wang, Ruirui [Key Laboratory of Low-grade Energy Utilization Technologies and Systems, Ministry of Education of PRC, Chongqing University, Chongqing, 400044 (China); College of Power Engineering, Chongqing University, Chongqing, 400044 (China)

2016-07-15

Graphical abstract: - Highlights: • CH appears to be the most abundant species on Pt(1 1 1) surface in CH{sub 4} dissociation. • CO{sub 2}* + H* → COOH* + * → CO* + OH* is the dominant reaction pathway in CO{sub 2} activation. • Major reaction pathway in CH oxidation: CH* + OH* → CHOH* + * → CHO* + H* → CO* + 2H*. • C* + OH* → COH* + * → CO* + H* is the dominant reaction pathway in C oxidation. - Abstract: Dry reforming of methane (DRM) is a well-studied reaction that is of both scientific and industrial importance. In order to design catalysts that minimize the deactivation and improve the selectivity and activity for a high H{sub 2}/CO yield, it is necessary to understand the elementary reaction steps involved in activation and conversion of CO{sub 2} and CH{sub 4}. In our present work, a microkinetic model based on density functional theory (DFT) calculations is applied to explore the reaction mechanism for methane dry reforming on Pt catalysts. The adsorption energies of the reactants, intermediates and products, and the activation barriers for the elementary reactions involved in the DRM process are calculated over the Pt(1 1 1) surface. In the process of CH{sub 4} direct dissociation, the kinetic results show that CH dissociative adsorption on Pt(1 1 1) surface is the rate-determining step. CH appears to be the most abundant species on the Pt(1 1 1) surface, suggesting that carbon deposition is not easy to form in CH{sub 4} dehydrogenation on Pt(1 1 1) surface. In the process of CO{sub 2} activation, three possible reaction pathways are considered to contribute to the CO{sub 2} decomposition: (I) CO{sub 2}* + * → CO* + O*; (II) CO{sub 2}* + H* → COOH* + * → CO* + OH*; (III) CO{sub 2}* + H* → mono-HCOO* + * → bi-HCOO* + * [CO{sub 2}* + H* → bi-HCOO* + *] → CHO* + O*. Path I requires process to overcome the activation barrier of 1.809 eV and the forward reaction is calculated to be strongly endothermic by 1.430 eV. In

Temporal and spatial variations of oceanic pCO2 and air-sea CO2 flux in th Greenland Sea and the Barents Sea

International Nuclear Information System (INIS)

Nakaoka, Shin-Ichiro; Aoki, Shuji; Nakazawa, Takakiyo; Yoshikawa-Inoue, Hisayuki

2006-01-01

In order to elucidate the seasonal and inter annual variations of oceanic CO 2 uptake in the Greenland Sea and the Barents Sea, the partial pressure of CO 2 in the surface ocean (pCO 2 sea ) was measured in all seasons between 1992 and 2001. We derived monthly varying relationships between pCO 2 sea and sea surface temperature (SST) and combined them with the SST data from the NCEP/NCAR reanalysis to determine pCO 2 sea and air-sea CO 2 flux in these seas. The pCO 2 sea values were normalized to the year 1995 by assuming that pCO 2 sea increased at the same growth rate (1.5 μatm/yr) of the pCO 2 in the air (pCO 2 air ) between 1992 and 2001. In 1995, the annual net air-sea CO 2 fluxes were evaluated to be 52 ± 20 gC/m 2 /yr in the Greenland Sea and 46 ± 18 gC/m 2 /yr in the Barents Sea. The CO 2 flux into the ocean reached its maximum in winter and minimum in summer. The wind speed and (delta)pCO 2 (=pCO 2 air -pCO 2 sea ) exerted a greater influence on the seasonal variation than the sea ice coverage. The annual CO 2 uptake examined in this study (70-80 deg N, 20 deg W-40 deg E) was estimated to be 0.050 ± 0.020 GtC/yr in 1995. The inter annual variation in the annual CO 2 uptake was found to be positively correlated with the North Atlantic Oscillation Index (NAOI) via wind strength but negatively correlated with (delta)pCO 2 and the sea ice coverage. The present results indicate that the variability in wind speed and sea ice coverage play a major role, while that in (delta)pCO 2 plays a minor role, in determining the interannual variation of CO 2 uptake in this area

Caldera unrest driven by CO2-induced drying of the deep hydrothermal system.

Science.gov (United States)

Moretti, R; Troise, C; Sarno, F; De Natale, G

2018-05-29

Interpreting volcanic unrest is a highly challenging and non-unique problem at calderas, since large hydrothermal systems may either hide or amplify the dynamics of buried magma(s). Here we use the exceptional ground displacement and geochemical datasets from the actively degassing Campi Flegrei caldera (Southern Italy) to show that ambiguities disappear when the thermal evolution of the deep hydrothermal system is accurately tracked. By using temperatures from the CO 2 -CH 4 exchange of 13 C and thermodynamic analysis of gas ascending in the crust, we demonstrate that after the last 1982-84 crisis the deep hydrothermal system evolved through supercritical conditions under the continuous isenthalpic inflow of hot CO 2 -rich gases released from the deep (~8 km) magma reservoir of regional size. This resulted in the drying of the base of the hot hydrothermal system, no more buffered along the liquid-vapour equilibrium, and excludes any shallow arrival of new magma, whose abundant steam degassing due to decompression would have restored liquid-vapour equilibrium. The consequent CO 2 -infiltration and progressive heating of the surrounding deforming rock volume cause the build-up of pore pressure in aquifers, and generate the striking temporal symmetry that characterizes the ongoing uplift and the post-1984 subsidence, both originated by the same but reversed deformation mechanism.

How reversible is sea ice loss?

Directory of Open Access Journals (Sweden)

J. K. Ridley

2012-02-01

Full Text Available It is well accepted that increasing atmospheric CO₂ results in global warming, leading to a decline in polar sea ice area. Here, the specific question of whether there is a tipping point in the sea ice cover is investigated. The global climate model HadCM3 is used to map the trajectory of sea ice area under idealised scenarios. The atmospheric CO₂ is first ramped up to four times pre-industrial levels (4 × CO₂, then ramped down to pre-industrial levels. We also examine the impact of stabilising climate at 4 × CO₂ prior to ramping CO₂ down to pre-industrial levels. Against global mean temperature, Arctic sea ice area is reversible, while the Antarctic sea ice shows some asymmetric behaviour – its rate of change slower, with falling temperatures, than its rate of change with rising temperatures. However, we show that the asymmetric behaviour is driven by hemispherical differences in temperature change between transient and stabilisation periods. We find no irreversible behaviour in the sea ice cover.

Atmospheric CO2 and abrupt climate change on submillennial timescales

Science.gov (United States)

Ahn, Jinho; Brook, Edward

2010-05-01

How atmospheric CO2 varies and is controlled on various time scales and under various boundary conditions is important for understanding how the carbon cycle and climate change are linked. Ancient air preserved in ice cores provides important information on past variations in atmospheric CO2. In particular, concentration records for intervals of abrupt climate change may improve understanding of mechanisms that govern atmospheric CO2. We present new multi-decadal CO2 records that cover Greenland stadial 9 (between Dansgaard-Oeschger (DO) events 8 and 9) and the abrupt cooling event at 8.2 ka. The CO2 records come from Antarctic ice cores but are well synchronized with Greenland ice core records using new high-resolution CH4 records,precisely defining the timing of CO2 change with respect to abrupt climate events in Greenland. Previous work showed that during stadial 9 (40~38 ka), CO2 rose by about 15~20 ppm over around 2,000 years, and at the same time temperatures in Antarctica increased. Dust proxies indicate a decrease in dust flux over the same period. With more detailed data and better age controls we now find that approximately half of the CO2 increase during stadial 9 occurred abruptly, over the course of decades to a century at ~39.6 ka. The step increase of CO2 is synchronous with a similar step increase of Antarctic isotopic temperature and a small abrupt change in CH4, and lags after the onset of decrease in dust flux by ~400 years. New atmospheric CO2 records at the well-known ~8.2 ka cooling event were obtained from Siple Dome ice core, Antarctica. Our preliminary CO2 data span 900 years and include 19 data points within the 8.2 ka cooling event, which persisted for ~160 years (Thomas et al., Quarternary Sci. Rev., 2007). We find that CO2 increased by 2~4 ppm during that cooling event. Further analyses will improve the resolution and better constrain the CO2 variability during other times in the early Holocene to determine if the variations observed

Policy options to reduce passenger car CO2 emissions after 2020

Energy Technology Data Exchange (ETDEWEB)

De Wilde, H.P.J.; Kroon, P. [ECN Beleidsstudies, Petten (Netherlands)

2013-02-15

The EU has set emission targets for new cars up to 2020 and is now preparing the post 2020 legislation. The present study aims to give insight in the design of policies to further reduce passenger car emissions after 2020. Internal combustion engine (ICE) vehicles are now expected to enable deeper and less costly CO2 emission reductions than envisioned until recently. However, even advanced ICE vehicles will not enable to meet the very stringent long term emission reduction targets for passenger cars. Therefore transport policies need not only to reduce emissions of ICE vehicles, but also ensure that electric and hydrogen vehicles are phased in timely, along with low-CO2 electricity and hydrogen. Current legislation to regulate tank-to-wheel vehicle emissions is based on CO2-limits, expressed in g CO2/km. On the short term it is important to maximize the efficiency of conventional vehicles. At the same time it is essential to foster the market introduction of electric and hydrogen vehicles, given their potential to reach eventually much deeper overall CO2-reductions. When the market share of electric and hydrogen vehicles grows it becomes increasingly important to maximize their efficiency and to minimize their upstream CO2 emissions. Maximizing both efficiency and overall CO2-performance of all vehicle types - ICE, electric, and hydrogen - will be complicated to achieve with a single CO2-based standard. At this point an efficiency-based standard is more effective, and may offer some additional benefits too. The current report provides basic directions of how such legislation could be shaped.

X-RAY IRRADIATION OF H{sub 2}O + CO ICE MIXTURES WITH SYNCHROTRON LIGHT

Energy Technology Data Exchange (ETDEWEB)

Jiménez-Escobar, A.; Ciaravella, A.; Micela, G.; Cecchi-Pestellini, C. [INAF–Osservatorio Astronomico di Palermo, P.za Parlamento 1, I-90134 Palermo (Italy); Chen, Y.-J.; Huang, C.-H., E-mail: jimenezea@astropa.inaf.it, E-mail: ciarave@astropa.inaf.it, E-mail: giusi@astropa.inaf.it, E-mail: cecchi-pestellini@astropa.inaf.it, E-mail: asperchen@phy.ncu.edu.tw, E-mail: 101222023@cc.ncu.edu.tw [Department of Physics, National Central University, Jhongli District, Taoyuan City 32054, Taiwan (China)

2016-03-20

We irradiated a (4:1) mixture of water and carbon monoxide with soft X-rays of energies up to 1.2 keV. The experiments were performed using the spherical grating monochromator beamline at National Synchrotron Radiation Research Center in Taiwan. Both monochromatic (300 and 900 eV) and broader energy fluxes (250–1200 eV) were employed. During the irradiation, the H{sub 2}O + CO mixture was ionized, excited, and fragmented, producing a number of reactive species. The composition of the ice has been monitored throughout both the irradiation and warm-up phases. We identified several products, which can be related through a plausible chemical reaction scheme. Such chemistry is initiated by the injection of energetic photoelectrons that produce multiple ionization events generating a secondary electron cascade. The results have been discussed in light of a model for protoplanetary disks around young solar-type stars.

Effects of Regeneration Conditions on Sorption Capacity of CO{sub 2} Dry Potassium Sorbent During Carbonation

Energy Technology Data Exchange (ETDEWEB)

Kim, Yunseop; Park, Young Cheol; Jo, Sung-Ho; Ryu, Ho-Jung; Yi, Chang-Keun [Korea Institute of Energy Research, Daejeon (Korea, Republic of); Rhee, Young Woo [Chungnam National University, Daejeon (Korea, Republic of)

2015-02-15

In this study, we investigated carbonation-regeneration and agglomeration characteristics of dry sorbents. Experiment has been proceeded in the batch-type reactor, which is made of quartz: 0.05 m of I.D and 0.8 m in height. The sorbents that is collected at the cyclone of the carbonation reactor of continuous process were used in this study. The reactivity was studied at the various concentrations of water vapor, N{sub 2} and CO{sub 2} in the fluidizing gas at regeneration reaction. As a result, the reactivity increased as the regeneration temperature increased, the reactivity decreased as the concentration of water vapor increased. The absorption capacity showed the highest value in case of using N{sub 2} 100% as regeneration gas. And decreased in order of H{sub 2}O+N{sub 2}, CO{sub 2} 100% and H{sub 2}O+CO{sub 2}. The agglomeration characteristics were investigated according to the particle sizes and concentrations of water vapor at carbonation reaction. As a result, the particle with smaller size and higher concentration of water vapor showed the higher agglomeration characteristic.

[Effects of drying and wetting cycles induced by tides on net ecosystem exchange of CO2 over a salt marsh in the Yellow River Delta, China.

Science.gov (United States)

He, Wen Jun; Han, Guang Xuan; Xu, Yan Ning; Zhang, Xi Tao; Wang, An Dong; Che, Chun Guang; Sun, Bao Yu; Zhang, Xiao Shuai

2018-01-01

As a unique hydrological characteristic, the tidal action can strongly affect carbon balance in a salt marsh despite their short duration. Using the eddy covariance technique, we measured the net ecosystem CO 2 exchange (NEE) and its environmental factors and tidal change over a salt marsh in the Yellow River Delta. It aimed to investigate the effect of tidal process and drying and wetting cycles induced by tides on NEE. The results showed that the tidal process promoted the daytime CO 2 uptake, but it didn't clearly affect the nighttime CO 2 release. Tidal inundation was a major factor influencing daytime NEE. The diurnal change of NEE showed a distinct U-shaped curve on both drought and wet stages, but not with substantial variation in its amplitude during the drought stage. The drying and wetting cycles enhanced the absorption of daytime CO 2 . Under drought stage, the mean of the maximum photosynthetic rate (A max ), apparent quantum yield (α) and ecosystem respiration (R eco ) were higher than those in wet stage. In addition, the drying and wetting cycles suppressed the nighttime CO 2 release from the salt marsh but increased its temperature sensitivity.

Thermal design of heat-exchangeable reactors using a dry-sorbent CO2 capture multi-step process

International Nuclear Information System (INIS)

Moon, Hokyu; Yoo, Hoanju; Seo, Hwimin; Park, Yong-Ki; Cho, Hyung Hee

2015-01-01

The present study proposes a multi-stage CO 2 capture process that incorporates heat-exchangeable fluidized-bed reactors. For continuous multi-stage heat exchange, three dry regenerable sorbents: K 2 CO 3 , MgO, and CaO, were used to create a three-stage temperature-dependent reaction chain for CO 2 capture, corresponding to low (50–150 °C), middle (350–650 °C), and high (750–900 °C) temperature stages, respectively. Heat from carbonation in the high and middle temperature stages was used for regeneration for the middle and low temperature stages. The feasibility of this process is depending on the heat-transfer performance of the heat-exchangeable fluidized bed reactors as the focus of this study. The three-stage CO 2 capture process for a 60 Nm 3 /h CO 2 flow rate required a reactor area of 0.129 and 0.130 m 2 for heat exchange between the mid-temperature carbonation and low-temperature regeneration stages and between the high-temperature carbonation and mid-temperature regeneration stages, respectively. The reactor diameter was selected to provide dense fluidization conditions for each bed with respect to the desired flow rate. The flow characteristics and energy balance of the reactors were confirmed using computational fluid dynamics and thermodynamic analysis, respectively. - Highlights: • CO 2 capture process is proposed using a multi-stage process. • Reactor design is conducted considering heat exchangeable scheme. • Reactor surface is designed by heat transfer characteristics of fluidized bed

The role of water ice clouds in the Martian hydrologic cycle

Science.gov (United States)

James, Philip B.

1990-01-01

A one-dimensional model for the seasonal cycle of water on Mars has been used to investigate the direction of the net annual transport of water on the planet and to study the possible role of water ice clouds, which are included as an independent phase in addition to ground ice and water vapor, in the cycle. The calculated seasonal and spatial patterns of occurrence of water ice clouds are qualitatively similar to the observed polar hoods, suggesting that these polar clouds are, in fact, an important component of water cycle. A residual dry ice in the south acts as a cold trap which, in the absence of sources other than the caps, will ultimately attract the water ice from the north cap; however, in the presence of a source of water in northern midlatitudes during spring, it is possible that the observed distribution of vapor and ice can be in a steady state even if a residual CO2 cap is a permanent feature of the system.

Measurements of 14C in ancient ice from Taylor Glacier, Antarctica constrain in situ cosmogenic 14CH4 and 14CO production rates

Science.gov (United States)

Petrenko, Vasilii V.; Severinghaus, Jeffrey P.; Schaefer, Hinrich; Smith, Andrew M.; Kuhl, Tanner; Baggenstos, Daniel; Hua, Quan; Brook, Edward J.; Rose, Paul; Kulin, Robb; Bauska, Thomas; Harth, Christina; Buizert, Christo; Orsi, Anais; Emanuele, Guy; Lee, James E.; Brailsford, Gordon; Keeling, Ralph; Weiss, Ray F.

2016-03-01

Carbon-14 (14C) is incorporated into glacial ice by trapping of atmospheric gases as well as direct near-surface in situ cosmogenic production. 14C of trapped methane (14CH4) is a powerful tracer for past CH4 emissions from ;old; carbon sources such as permafrost and marine CH4 clathrates. 14C in trapped carbon dioxide (14CO2) can be used for absolute dating of ice cores. In situ produced cosmogenic 14C in carbon monoxide (14CO) can potentially be used to reconstruct the past cosmic ray flux and past solar activity. Unfortunately, the trapped atmospheric and in situ cosmogenic components of 14C in glacial ice are difficult to disentangle and a thorough understanding of the in situ cosmogenic component is needed in order to extract useful information from ice core 14C. We analyzed very large (≈1000 kg) ice samples in the 2.26-19.53 m depth range from the ablation zone of Taylor Glacier, Antarctica, to study in situ cosmogenic production of 14CH4 and 14CO. All sampled ice is >50 ka in age, allowing for the assumption that most of the measured 14C originates from recent in situ cosmogenic production as ancient ice is brought to the surface via ablation. Our results place the first constraints on cosmogenic 14CH4 production rates and improve on prior estimates of 14CO production rates in ice. We find a constant 14CH4/14CO production ratio (0.0076 ± 0.0003) for samples deeper than 3 m, which allows the use of 14CO for correcting the 14CH4 signals for the in situ cosmogenic component. Our results also provide the first unambiguous confirmation of 14C production by fast muons in a natural setting (ice or rock) and suggest that the 14C production rates in ice commonly used in the literature may be too high.

Carbon Dioxide Transfer Through Sea Ice: Modelling Flux in Brine Channels

Science.gov (United States)

Edwards, L.; Mitchelson-Jacob, G.; Hardman-Mountford, N.

2010-12-01

For many years sea ice was thought to act as a barrier to the flux of CO2 between the ocean and atmosphere. However, laboratory-based and in-situ observations suggest that while sea ice may in some circumstances reduce or prevent transfer (e.g. in regions of thick, superimposed multi-year ice), it may also be highly permeable (e.g. thin, first year ice) with some studies observing significant fluxes of CO2. Sea ice covered regions have been observed to act both as a sink and a source of atmospheric CO2 with the permeability of sea ice and direction of flux related to sea ice temperature and the presence of brine channels in the ice, as well as seasonal processes such as whether the ice is freezing or thawing. Brine channels concentrate dissolved inorganic carbon (DIC) as well as salinity and as these dense waters descend through both the sea ice and the surface ocean waters, they create a sink for CO2. Calcium carbonate (ikaite) precipitation in the sea ice is thought to enhance this process. Micro-organisms present within the sea ice will also contribute to the CO2 flux dynamics. Recent evidence of decreasing sea ice extent and the associated change from a multi-year ice to first-year ice dominated system suggest the potential for increased CO2 flux through regions of thinner, more porous sea ice. A full understanding of the processes and feedbacks controlling the flux in these regions is needed to determine their possible contribution to global CO2 levels in a future warming climate scenario. Despite the significance of these regions, the air-sea CO2 flux in sea ice covered regions is not currently included in global climate models. Incorporating this carbon flux system into Earth System models requires the development of a well-parameterised sea ice-air flux model. In our work we use the Los Alamos sea ice model, CICE, with a modification to incorporate the movement of CO2 through brine channels including the addition of DIC processes and ice algae production to

Estimates of ikaite export from sea ice to the underlying seawater in a sea ice-seawater mesocosm

Science.gov (United States)

Geilfus, Nicolas-Xavier; Galley, Ryan J.; Else, Brent G. T.; Campbell, Karley; Papakyriakou, Tim; Crabeck, Odile; Lemes, Marcos; Delille, Bruno; Rysgaard, Søren

2016-09-01

The precipitation of ikaite and its fate within sea ice is still poorly understood. We quantify temporal inorganic carbon dynamics in sea ice from initial formation to its melt in a sea ice-seawater mesocosm pool from 11 to 29 January 2013. Based on measurements of total alkalinity (TA) and total dissolved inorganic carbon (TCO2), the main processes affecting inorganic carbon dynamics within sea ice were ikaite precipitation and CO2 exchange with the atmosphere. In the underlying seawater, the dissolution of ikaite was the main process affecting inorganic carbon dynamics. Sea ice acted as an active layer, releasing CO2 to the atmosphere during the growth phase, taking up CO2 as it melted and exporting both ikaite and TCO2 into the underlying seawater during the whole experiment. Ikaite precipitation of up to 167 µmol kg-1 within sea ice was estimated, while its export and dissolution into the underlying seawater was responsible for a TA increase of 64-66 µmol kg-1 in the water column. The export of TCO2 from sea ice to the water column increased the underlying seawater TCO2 by 43.5 µmol kg-1, suggesting that almost all of the TCO2 that left the sea ice was exported to the underlying seawater. The export of ikaite from the ice to the underlying seawater was associated with brine rejection during sea ice growth, increased vertical connectivity in sea ice due to the upward percolation of seawater and meltwater flushing during sea ice melt. Based on the change in TA in the water column around the onset of sea ice melt, more than half of the total ikaite precipitated in the ice during sea ice growth was still contained in the ice when the sea ice began to melt. Ikaite crystal dissolution in the water column kept the seawater pCO2 undersaturated with respect to the atmosphere in spite of increased salinity, TA and TCO2 associated with sea ice growth. Results indicate that ikaite export from sea ice and its dissolution in the underlying seawater can potentially hamper

Seasonal and temporal CO2 dynamics in three tropical mangrove creeks - A revision of global mangrove CO2 emissions

Science.gov (United States)

Rosentreter, Judith A.; Maher, D. T.; Erler, D. V.; Murray, R.; Eyre, B. D.

2018-02-01

Continuous high-resolution surface water pCO2 and δ13C-CO2 and 222Rn (dry season only) were measured over two tidal cycles in the wet and dry season in three tropical tidal mangrove creeks on the north-eastern coast of Queensland, Australia. Mangrove surface water pCO2 followed a clear tidal pattern (ranging from 387 to 13,031 μatm) with higher pCO2-values in the wet season than in the dry season. The δ13C-CO2 in the mangrove waters ranged from -21.7 to -8.8‰ and was rather indicative of a mixed source than a distinct mangrove signature. Surface water CO2 was likely driven by a combination of mangrove and external carbon sources, e.g. exchange with groundwater/pore water enriched in 13C, or terrestrial carbon inputs with a significant contribution of C4-vegetation (sugar cane) source. The kinetic and equilibrium fractionation during the gas exchange at the water-atmosphere interface may have further caused a 13C-enrichment of the CO2 pool in the mangrove surface waters. Average CO2 evasion rates (58.7-277.6 mmol m-2 d-1) were calculated using different empirical gas transfer velocity models. Using our high-resolution time series data and previously published data, the average CO2 flux rate in mangrove ecosystems was estimated to be 56.5 ± 8.9 mmol m-2 d-1, which corresponds to a revised global mangrove CO2 emission of 34.1 ± 5.4 Tg C per year.

FORMATION OF S-BEARING SPECIES BY VUV/EUV IRRADIATION OF H2S-CONTAINING ICE MIXTURES: PHOTON ENERGY AND CARBON SOURCE EFFECTS

International Nuclear Information System (INIS)

Chen, Y.-J.; Juang, K.-J.; Qiu, J.-M.; Chu, C.-C.; Yih, T.-S.; Nuevo, M.; Jiménez-Escobar, A.; Muñoz Caro, G. M.; Wu, C.-Y. R.; Fung, H.-S.; Ip, W.-H.

2015-01-01

Carbonyl sulfide (OCS) is a key molecule in astrobiology that acts as a catalyst in peptide synthesis by coupling amino acids. Experimental studies suggest that hydrogen sulfide (H 2 S), a precursor of OCS, could be present in astrophysical environments. In the present study, we used a microwave-discharge hydrogen-flow lamp, simulating the interstellar UV field, and a monochromatic synchrotron light beam to irradiate CO:H 2 S and CO 2 :H 2 S ice mixtures at 14 K with vacuum ultraviolet (VUV) or extreme ultraviolet (EUV) photons in order to study the effect of the photon energy and carbon source on the formation mechanisms and production yields of S-containing products (CS 2 , OCS, SO 2 , etc.). Results show that (1) the photo-induced OCS production efficiency in CO:H 2 S ice mixtures is higher than that of CO 2 :H 2 S ice mixtures; (2) a lower concentration of H 2 S enhances the production efficiency of OCS in both ice mixtures; and (3) the formation pathways of CS 2 differ significantly upon VUV and EUV irradiations. Furthermore, CS 2 was produced only after VUV photoprocessing of CO:H 2 S ices, while the VUV-induced production of SO 2 occurred only in CO 2 :H 2 S ice mixtures. More generally, the production yields of OCS, H 2 S 2 , and CS 2 were studied as a function of the irradiation photon energy. Heavy S-bearing compounds were also observed using mass spectrometry during the warm-up of VUV/EUV-irradiated CO:H 2 S ice mixtures. The presence of S-polymers in dust grains may account for the missing sulfur in dense clouds and circumstellar environments

Al2O3 Coated Concentration-Gradient Li[Ni0.73Co0.12Mn0.15]O2 Cathode Material by Freeze Drying for Long-Life Lithium Ion Batteries

International Nuclear Information System (INIS)

Wang, Jingpeng; Du, Chunyu; Yan, Chunqiu; He, Xiaoshu; Song, Bai; Yin, Geping; Zuo, Pengjian; Cheng, Xinqun

2015-01-01

Highlights: • Al 2 O 3 -coated concentration-gradient oxide is synthesized by a freeze drying method. • The effect of Al 2 O 3 -coating on concentration-gradient cathode is firstly studied. • Al 2 O 3 -coated sample exhibits high capacity and significantly enhanced cyclability. • Improved cyclability is ascribed to the effective protection of uniform Al 2 O 3 layer. - Abstract: In order to enhance the electrochemical performance of the high capacity layered oxide cathode with a Ni-rich core and a concentration-gradient shell (NRC-CGS), we use a freeze drying method to coat Al 2 O 3 layer onto the surface of NRC-CGS Li[Ni 0.73 Co 0.12 Mn 0.15 ]O 2 material. The samples are characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, charge-discharge measurements and electrochemical impedance spectroscopy. It is revealed that an amorphous Al 2 O 3 layer of about 5 nm in thickness is uniformly formed on the surface of NRC-CGS Li[Ni 0.73 Co 0.12 Mn 0.15 ]O 2 material by the freeze drying procedure. The freeze drying Al 2 O 3 -coated (FD-Al 2 O 3 -coated) sample demonstrates similar discharge capacity and significantly enhanced cycling performances, in comparison to the pristine and conventional heating drying Al 2 O 3 -coated (HD-Al 2 O 3 -coated) samples. The capacity decay rate of FD-Al 2 O 3 -coated Li[Ni 0.73 Co 0.12 Mn 0.15 ]O 2 material is 1.7% after 150 cycles at 55 °C, which is 9 and 12 times lower than that of the pristine and HD-Al 2 O 3 -coated samples. The superior electrochemical stability of the FD-Al 2 O 3 -coated sample is attributed to the synergistic protection of CGS and high-quality Al 2 O 3 coating that effectively protect the active material from electrolyte attack. The freeze drying process provides an effective method to prepare the high performance surface-coated electrode materials

Drivers of inorganic carbon dynamics in first-year sea ice: A model study

Science.gov (United States)

Moreau, Sébastien; Vancoppenolle, Martin; Delille, Bruno; Tison, Jean-Louis; Zhou, Jiayun; Kotovich, Marie; Thomas, David; Geilfus, Nicolas-Xavier; Goosse, Hugues

2015-04-01

Sea ice is an active source or a sink for carbon dioxide (CO2), although to what extent is not clear. Here, we analyze CO2 dynamics within sea ice using a one-dimensional halo-thermodynamic sea ice model including gas physics and carbon biogeochemistry. The ice-ocean fluxes, and vertical transport, of total dissolved inorganic carbon (DIC) and total alkalinity (TA) are represented using fluid transport equations. Carbonate chemistry, the consumption and release of CO2 by primary production and respiration, the precipitation and dissolution of ikaite (CaCO3•6H2O) and ice-air CO2 fluxes, are also included. The model is evaluated using observations from a 6-month field study at Point Barrow, Alaska and an ice-tank experiment. At Barrow, results show that the DIC budget is mainly driven by physical processes, wheras brine-air CO2 fluxes, ikaite formation, and net primary production, are secondary factors. In terms of ice-atmosphere CO2 exchanges, sea ice is a net CO2 source and sink in winter and summer, respectively. The formulation of the ice-atmosphere CO2 flux impacts the simulated near-surface CO2 partial pressure (pCO2), but not the DIC budget. Because the simulated ice-atmosphere CO2 fluxes are limited by DIC stocks, and therefore < 2 mmol m-2 day-1, we argue that the observed much larger CO2 fluxes from eddy covariance retrievals cannot be explained by a sea ice direct source and must involve other processes or other sources of CO2. Finally, the simulations suggest that near surface TA/DIC ratios of ~2, sometimes used as an indicator of calcification, would rather suggest outgassing.

Calcium carbonate as ikaite crystals in Antarctic sea ice

Science.gov (United States)

Dieckmann, Gerhard S.; Nehrke, Gernot; Papadimitriou, Stathys; Göttlicher, Jörg; Steininger, Ralph; Kennedy, Hilary; Wolf-Gladrow, Dieter; Thomas, David N.

2008-04-01

We report on the discovery of the mineral ikaite (CaCO3.6H2O) in sea-ice from the Southern Ocean. The precipitation of CaCO3 during the freezing of seawater has previously been predicted from thermodynamic modelling, indirect measurements, and has been documented in artificial sea ice during laboratory experiments but has not been reported for natural sea-ice. It is assumed that CaCO3 formation in sea ice may be important for a sea ice-driven carbon pump in ice-covered oceanic waters. Without direct evidence of CaCO3 precipitation in sea ice, its role in this and other processes has remained speculative. The discovery of CaCO3.6H2O crystals in natural sea ice provides the necessary evidence for the evaluation of previous assumptions and lays the foundation for further studies to help elucidate the role of ikaite in the carbon cycle of the seasonally sea ice-covered regions

Effects of ocean acidification on the physiological performance and carbon production of the Antarctic sea ice diatom Nitzschia sp. ICE-H.

Science.gov (United States)

Qu, Chang-Feng; Liu, Fang-Ming; Zheng, Zhou; Wang, Yi-Bin; Li, Xue-Gang; Yuan, Hua-Mao; Li, Ning; An, Mei-Ling; Wang, Xi-Xi; He, Ying-Ying; Li, Lu-Lu; Miao, Jin-Lai

2017-07-15

Ocean acidification (OA) resulting from increasing atmospheric CO 2 strongly influences marine ecosystems, particularly in the polar ocean due to greater CO 2 solubility. Here, we grew the Antarctic sea ice diatom Nitzschia sp. ICE-H in a semicontinuous culture under low (~400ppm) and high (1000ppm) CO 2 levels. Elevated CO 2 resulted in a stimulated physiological response including increased growth rates, chlorophyll a contents, and nitrogen and phosphorus uptake rates. Furthermore, high CO 2 enhanced cellular particulate organic carbon production rates, indicating a greater shift from inorganic to organic carbon. However, the cultures grown in high CO 2 conditions exhibited a decrease in both extracellular and intracellular carbonic anhydrase activity, suggesting that the carbon concentrating mechanisms of Nitzschia sp. ICE-H may be suppressed by elevated CO 2 . Our results revealed that OA would be beneficial to the survival of this sea ice diatom strain, with broad implications for global carbon cycles in the future ocean. Copyright © 2017. Published by Elsevier Ltd.

Influence of Solvent Composition on the Performance of Spray-Dried Co-Amorphous Formulations

DEFF Research Database (Denmark)

Mishra, Jaya; Rades, Thomas; Löbmann, Korbinian

2018-01-01

Ball-milling is usually used to prepare co-amorphous drug–amino acid (AA) mixtures. In this study, co-amorphous drug–AA mixtures were produced using spray-drying, a scalable industrially preferred preparation method. The influence of the solvent type and solvent composition was investigated....... Mixtures of indomethacin (IND) and each of the three AAs arginine, histidine, and lysine were ball-milled and spray-dried at a 1:1 molar ratio, respectively. Spray-drying was performed at different solvent ratios in (a) ethanol and water mixtures and (b) acetone and water mixtures. Different ratios...... that using spray-drying as a preparation method, all IND–AA mixtures could be successfully converted into the respective co-amorphous forms, irrespective of the type of solvent used, but depending on the solvent mixture ratios. Both ball-milled and spray-dried co-amorphous samples showed an enhanced...

CO_2 valorization - Part. 2: chemical transformation ways

International Nuclear Information System (INIS)

Dumergues, Laurent

2016-01-01

Carbon dioxide (CO_2) can be used in many ways as a raw material or chemical reagent. The chemical conversion of CO_2 used as a feedstock is achievable by different techniques: mineralization, organic synthesis, hydrogenation, dry reforming, electrolysis, thermolysis, etc. The products obtained have applications as energy products, chemicals, building materials, etc. Choosing an appropriate CO_2 reuse technology will depend on technical and economic requirements (such as the CO_2 purity needed, technological maturity, cost-effectiveness, etc.) and also environmental and social criteria

FORMATION OF S-BEARING SPECIES BY VUV/EUV IRRADIATION OF H{sub 2}S-CONTAINING ICE MIXTURES: PHOTON ENERGY AND CARBON SOURCE EFFECTS

Energy Technology Data Exchange (ETDEWEB)

Chen, Y.-J.; Juang, K.-J.; Qiu, J.-M.; Chu, C.-C.; Yih, T.-S. [Department of Physics, National Central University, Jhongli City, Taoyuan County 32054, Taiwan (China); Nuevo, M. [NASA Ames Research Center, Moffett Field, CA 94035 (United States); Jiménez-Escobar, A.; Muñoz Caro, G. M. [Centro de Astrobiología, INTA-CSIC, Torrejón de Ardoz, E-28850 Madrid (Spain); Wu, C.-Y. R. [Space Sciences Center and Department of Physics and Astronomy, University of Southern California, Los Angeles, CA 90089-1341 (United States); Fung, H.-S. [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China); Ip, W.-H. [Graduate Institute of Astronomy, National Central University, Jhongli City, Taoyuan County 32049, Taiwan (China)

2015-01-10

Carbonyl sulfide (OCS) is a key molecule in astrobiology that acts as a catalyst in peptide synthesis by coupling amino acids. Experimental studies suggest that hydrogen sulfide (H{sub 2}S), a precursor of OCS, could be present in astrophysical environments. In the present study, we used a microwave-discharge hydrogen-flow lamp, simulating the interstellar UV field, and a monochromatic synchrotron light beam to irradiate CO:H{sub 2}S and CO{sub 2}:H{sub 2}S ice mixtures at 14 K with vacuum ultraviolet (VUV) or extreme ultraviolet (EUV) photons in order to study the effect of the photon energy and carbon source on the formation mechanisms and production yields of S-containing products (CS{sub 2}, OCS, SO{sub 2}, etc.). Results show that (1) the photo-induced OCS production efficiency in CO:H{sub 2}S ice mixtures is higher than that of CO{sub 2}:H{sub 2}S ice mixtures; (2) a lower concentration of H{sub 2}S enhances the production efficiency of OCS in both ice mixtures; and (3) the formation pathways of CS{sub 2} differ significantly upon VUV and EUV irradiations. Furthermore, CS{sub 2} was produced only after VUV photoprocessing of CO:H{sub 2}S ices, while the VUV-induced production of SO{sub 2} occurred only in CO{sub 2}:H{sub 2}S ice mixtures. More generally, the production yields of OCS, H{sub 2}S{sub 2}, and CS{sub 2} were studied as a function of the irradiation photon energy. Heavy S-bearing compounds were also observed using mass spectrometry during the warm-up of VUV/EUV-irradiated CO:H{sub 2}S ice mixtures. The presence of S-polymers in dust grains may account for the missing sulfur in dense clouds and circumstellar environments.

Solid oxide fuel cell technology coupled with methane dry reforming: A viable option for high efficiency plant with reduced CO2 emissions

International Nuclear Information System (INIS)

Barelli, L.; Ottaviano, A.

2014-01-01

Nowadays the control of greenhouse gas is probably the most challenging environmental policy issue. Since CO 2 is considered the major greenhouse gas (GHG) that contributes to the global warming, enforcing technological strategies aiming to avoid or reuse CO 2 emissions becomes crucial, in order to mitigate GHG environmental impact. Currently, solutions conventionally adopted to this purpose are carbon capture and storage (CCS) technologies. In this context, instead, the followed strategy aims to further improvements in energetic conversion efficiency with related reduced specific CO 2 emissions (per produced kWh e ). Therefore, with particular reference to the electric power generation, this paper proposes an innovative energy conversion system, based on solid oxide fuel cell (SOFC), characterized by higher efficiency and reduced CO 2 emission factor respect to an analogous conventional energy plant. In particular, the innovative solution consists of combining SOFC to methane dry reforming technology, while the conventional system refers to steam methane reforming-SOFC coupling. The innovative system performance up to 65% electric efficiency as cited in the paper, was validated through simulations carried out in Aspen Plus environment. - Highlights: • An innovative high efficiency plant with low CO 2 emissions is presented. • The new solution combined SOFC to methane dry reforming technology (CDR–SOFC). • A comparison between CDR–SOFC and SMR–SOFC system was carried out in Aspen Plus. • CDR–SOFC efficiency is greater of 6.4% percentage points respect to SMR–SOFC. • A CO 2 emission factor reduction of about 10% was achieved by CDR–SOFC plant

Influence of Solvent Composition on the Performance of Spray-Dried Co-Amorphous Formulations

Directory of Open Access Journals (Sweden)

Jaya Mishra

2018-04-01

Full Text Available Ball-milling is usually used to prepare co-amorphous drug–amino acid (AA mixtures. In this study, co-amorphous drug–AA mixtures were produced using spray-drying, a scalable industrially preferred preparation method. The influence of the solvent type and solvent composition was investigated. Mixtures of indomethacin (IND and each of the three AAs arginine, histidine, and lysine were ball-milled and spray-dried at a 1:1 molar ratio, respectively. Spray-drying was performed at different solvent ratios in (a ethanol and water mixtures and (b acetone and water mixtures. Different ratios of these solvents were chosen to study the effect of solvent mixtures on co-amorphous formulation. Residual crystallinity, thermal properties, salt/partial salt formation, and powder dissolution profiles of the IND–AA mixtures were investigated and compared to pure crystalline and amorphous IND. It was found that using spray-drying as a preparation method, all IND–AA mixtures could be successfully converted into the respective co-amorphous forms, irrespective of the type of solvent used, but depending on the solvent mixture ratios. Both ball-milled and spray-dried co-amorphous samples showed an enhanced dissolution rate and maintained supersaturation compared to the crystalline and amorphous IND itself. The spray-dried samples resulting in co-amorphous samples were stable for at least seven months of storage.

Characterization of Amorphous and Co-Amorphous Simvastatin Formulations Prepared by Spray Drying

Directory of Open Access Journals (Sweden)

Goedele Craye

2015-12-01

Full Text Available In this study, spray drying from aqueous solutions, using the surface-active agent sodium lauryl sulfate (SLS as a solubilizer, was explored as a production method for co-amorphous simvastatin–lysine (SVS-LYS at 1:1 molar mixtures, which previously have been observed to form a co-amorphous mixture upon ball milling. In addition, a spray-dried formulation of SVS without LYS was prepared. Energy-dispersive X-ray spectroscopy (EDS revealed that SLS coated the SVS and SVS-LYS particles upon spray drying. X-ray powder diffraction (XRPD and differential scanning calorimetry (DSC showed that in the spray-dried formulations the remaining crystallinity originated from SLS only. The best dissolution properties and a “spring and parachute” effect were found for SVS spray-dried from a 5% SLS solution without LYS. Despite the presence of at least partially crystalline SLS in the mixtures, all the studied formulations were able to significantly extend the stability of amorphous SVS compared to previous co-amorphous formulations of SVS. The best stability (at least 12 months in dry conditions was observed when SLS was spray-dried with SVS (and LYS. In conclusion, spray drying of SVS and LYS from aqueous surfactant solutions was able to produce formulations with improved physical stability for amorphous SVS.

Characterization of Amorphous and Co-Amorphous Simvastatin Formulations Prepared by Spray Drying.

Science.gov (United States)

Craye, Goedele; Löbmann, Korbinian; Grohganz, Holger; Rades, Thomas; Laitinen, Riikka

2015-12-03

In this study, spray drying from aqueous solutions, using the surface-active agent sodium lauryl sulfate (SLS) as a solubilizer, was explored as a production method for co-amorphous simvastatin-lysine (SVS-LYS) at 1:1 molar mixtures, which previously have been observed to form a co-amorphous mixture upon ball milling. In addition, a spray-dried formulation of SVS without LYS was prepared. Energy-dispersive X-ray spectroscopy (EDS) revealed that SLS coated the SVS and SVS-LYS particles upon spray drying. X-ray powder diffraction (XRPD) and differential scanning calorimetry (DSC) showed that in the spray-dried formulations the remaining crystallinity originated from SLS only. The best dissolution properties and a "spring and parachute" effect were found for SVS spray-dried from a 5% SLS solution without LYS. Despite the presence of at least partially crystalline SLS in the mixtures, all the studied formulations were able to significantly extend the stability of amorphous SVS compared to previous co-amorphous formulations of SVS. The best stability (at least 12 months in dry conditions) was observed when SLS was spray-dried with SVS (and LYS). In conclusion, spray drying of SVS and LYS from aqueous surfactant solutions was able to produce formulations with improved physical stability for amorphous SVS.

A Molecular Explanation of How the Fog Is Produced When Dry Ice Is Placed in Water

Science.gov (United States)

Kuntzleman, Thomas S.; Ford, Nathan; No, Jin-Hwan; Ott, Mark E.

2015-01-01

Everyone enjoys seeing the cloudy white fog generated when solid carbon dioxide (dry ice) is placed in water. Have you ever wondered what physical and chemical processes occur to produce this fog? When asked this question, many chemical educators suggest that the fog is produced when atmospheric water vapor condenses on cold carbon dioxide gas…

ICE CHEMISTRY IN STARLESS MOLECULAR CORES

Energy Technology Data Exchange (ETDEWEB)

Kalvans, J., E-mail: juris.kalvans@venta.lv [Engineering Research Institute “Ventspils International Radio Astronomy Center” of Ventspils University College, Inzenieru 101, Ventspils, LV-3601 (Latvia)

2015-06-20

Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, surface, and mantle) model. We considered the center part of five starless cores, with their physical conditions derived from observations. The ice chemistry of oxygen, nitrogen, sulfur, and complex organic molecules (COMs) was analyzed. We found that an ice-depth dimension, measured, e.g., in monolayers, is essential for modeling of chemistry in interstellar ices. Particularly, the H{sub 2}O:CO:CO{sub 2}:N{sub 2}:NH{sub 3} ice abundance ratio regulates the production and destruction of minor species. It is suggested that photodesorption during the core-collapse period is responsible for the high abundance of interstellar H{sub 2}O{sub 2} and O{sub 2}H and other species synthesized on the surface. The calculated abundances of COMs in ice were compared to observed gas-phase values. Smaller activation barriers for CO and H{sub 2}CO hydrogenation may help explain the production of a number of COMs. The observed abundance of methyl formate HCOOCH{sub 3} could be reproduced with a 1 kyr, 20 K temperature spike. Possible desorption mechanisms, relevant for COMs, are gas turbulence (ice exposure to interstellar photons) or a weak shock within the cloud core (grain collisions). To reproduce the observed COM abundances with the present 0D model, 1%–10% of ice mass needs to be sublimated. We estimate that the lifetime for starless cores likely does not exceed 1 Myr. Taurus cores are likely to be younger than their counterparts in most other clouds.

Abrupt rise in atmospheric CO2 at the onset of the Bølling/Allerød: in-situ ice core data versus true atmospheric signals

Directory of Open Access Journals (Sweden)

J. Chappellaz

2011-05-01

Full Text Available During the last glacial/interglacial transition the Earth's climate underwent abrupt changes around 14.6 kyr ago. Temperature proxies from ice cores revealed the onset of the Bølling/Allerød (B/A warm period in the north and the start of the Antarctic Cold Reversal in the south. Furthermore, the B/A was accompanied by a rapid sea level rise of about 20 m during meltwater pulse (MWP 1A, whose exact timing is a matter of current debate. In-situ measured CO2 in the EPICA Dome C (EDC ice core also revealed a remarkable jump of 10 ± 1 ppmv in 230 yr at the same time. Allowing for the modelled age distribution of CO2 in firn, we show that atmospheric CO2 could have jumped by 20–35 ppmv in less than 200 yr, which is a factor of 2–3.5 greater than the CO2 signal recorded in-situ in EDC. This rate of change in atmospheric CO2 corresponds to 29–50% of the anthropogenic signal during the last 50 yr and is connected with a radiative forcing of 0.59–0.75 W m−2. Using a model-based airborne fraction of 0.17 of atmospheric CO2, we infer that 125 Pg of carbon need to be released into the atmosphere to produce such a peak. If the abrupt rise in CO2 at the onset of the B/A is unique with respect to other Dansgaard/Oeschger (D/O events of the last 60 kyr (which seems plausible if not unequivocal based on current observations, then the mechanism responsible for it may also have been unique. Available δ13CO2 data are neutral, whether the source of the carbon is of marine or terrestrial origin. We therefore hypothesise that most of the carbon might have been activated as a consequence of continental shelf flooding during MWP-1A. This potential impact of rapid sea level rise on atmospheric CO2 might define the point of no return during the last deglaciation.

Fast Atmosphere-Ocean Model Runs with Large Changes in CO2

Science.gov (United States)

Russell, Gary L.; Lacis, Andrew A.; Rind, David H.; Colose, Christopher; Opstbaum, Roger F.

2013-01-01

How does climate sensitivity vary with the magnitude of climate forcing? This question was investigated with the use of a modified coupled atmosphere-ocean model, whose stability was improved so that the model would accommodate large radiative forcings yet be fast enough to reach rapid equilibrium. Experiments were performed in which atmospheric CO2 was multiplied by powers of 2, from 1/64 to 256 times the 1950 value. From 8 to 32 times, the 1950 CO2, climate sensitivity for doubling CO2 reaches 8 C due to increases in water vapor absorption and cloud top height and to reductions in low level cloud cover. As CO2 amount increases further, sensitivity drops as cloud cover and planetary albedo stabilize. No water vapor-induced runaway greenhouse caused by increased CO2 was found for the range of CO2 examined. With CO2 at or below 1/8 of the 1950 value, runaway sea ice does occur as the planet cascades to a snowball Earth climate with fully ice covered oceans and global mean surface temperatures near 30 C.

Synthesis of Li{sub 2}MnO{sub 3}-stabilized LiCoO{sub 2} cathode material by spray-drying method and its high-voltage performance

Energy Technology Data Exchange (ETDEWEB)

Wang, Zhiguo; Wang, Zhixing, E-mail: zxwang.csu@hotmail.com; Guo, Huajun; Peng, Wenjie; Li, Xinhai

2015-03-25

Highlights: • Li{sub 2}MnO{sub 3} is introduced to stabilize the structure of LiCoO{sub 2} at high voltages. • xLi{sub 2}MnO{sub 3}·(1−x)LiCoO{sub 2} with fine particles prepared by a simple spray-drying method. • The modified sample exhibits enhanced high-voltage electrochemical performance. • Possible kinetic behaviors of the electrode surface are discussed. - Abstract: xLi{sub 2}MnO{sub 3}⋅(1 − x)LiCoO{sub 2} (x = 0, 0.02, 0.05, 0.1) as a cathode material for lithium ion batteries has been prepared by a spray-drying assisted solid-state method. The effects of Li{sub 2}MnO{sub 3} content on crystal structure, morphology, and high-voltage electrochemical performance of LiCoO{sub 2} have been characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and galvanostatic charge–discharge test. XRD results reveal that all samples have a well-ordered layered structure. SEM and EDS analyses confirm that homogeneous powders with a primary particle size of about 2 μm are observed and the elementals distribute uniformly in the particles. Electrochemical tests demonstrate that the modified samples exhibit obviously enhanced cycling stability in the voltage ranges of 3.0–4.5 V and 3.0–4.6 V, although they deliver somewhat lower discharge capacity. Specifically, 0.02Li{sub 2}MnO{sub 3}⋅0.98LiCoO{sub 2} delivers the initial discharge capacity of 189.0, 216.8 mA h g{sup −1} at 0.1 C in the voltage range of 3.0–4.5 V and 3.0–4.6 V, respectively, and excellent cycling behaviors at 1 C are achieved.

The relative contributions of biological and abiotic processes to carbon dynamics in subarctic sea ice

DEFF Research Database (Denmark)

Søgaard, Dorte Haubjerg; Thomas, David; Rysgaard, Søren

2013-01-01

Knowledge on the relative effects of biological activity and precipitation/dissolution of calcium carbonate (CaCO3) in influencing the air-ice CO2 exchange in sea-ice-covered season is currently lacking. Furthermore, the spatial and temporal occurrence of CaCO3 and other biogeochemical parameters...... in sea ice are still not well described. Here we investigated autotrophic and heterotrophic activity as well as the precipitation/dissolution of CaCO3 in subarctic sea ice in South West Greenland. Integrated over the entire ice season (71 days), the sea ice was net autotrophic with a net carbon fixation...... and CaCO3 precipitation. The net biological production could only explain 4 % of this sea-ice-driven CO2 uptake. Abiotic processes contributed to an air-sea CO2 uptake of 1.5 mmol m(-2) sea ice day(-1), and dissolution of CaCO3 increased the air-sea CO2 uptake by 36 % compared to a theoretical estimate...

The Effect of Broadband Soft X-Rays in SO2-Containing Ices: Implications on the Photochemistry of Ices toward Young Stellar Objects

Science.gov (United States)

Pilling, S.; Bergantini, A.

2015-10-01

We investigate the effects produced mainly by broadband soft X-rays up to 2 keV (plus fast (˜keV) photoelectrons and low-energy (˜eV) induced secondary electrons) in the ice mixtures containing H2O:CO2:NH3:SO2 (10:1:1:1) at two different temperatures (50 and 90 K). The experiments are an attempt to simulate the photochemical processes induced by energetic photons in SO2-containing ices present in cold environments in the ices surrounding young stellar objects (YSO) and in molecular clouds in the vicinity of star-forming regions, which are largely illuminated by soft X-rays. The measurements were performed using a high-vacuum portable chamber from the Laboratório de Astroquímica e Astrobiologia (LASA/UNIVAP) coupled to the spherical grating monochromator beamline at the Brazilian Synchrotron Light Source (LNLS) in Campinas, Brazil. In situ analyses were performed by a Fourier transform infrared spectrometer. Sample processing revealed the formation of several organic molecules, including nitriles, acids, and other compounds such as H2O2, H3O+, SO3, CO, and OCN-. The dissociation cross section of parental species was on the order of (2-7) × 10-18 cm2. The ice temperature does not seem to affect the stability of SO2 in the presence of X-rays. Formation cross sections of new species produced were also determined. Molecular half-lives at ices toward YSOs due to the presence of incoming soft X-rays were estimated. The low values obtained employing two different models of the radiation field of YSOs (TW Hydra and typical T-Tauri star) reinforce that soft X-rays are indeed a very efficient source of molecular dissociation in such environments.

THE EFFECT OF BROADBAND SOFT X-RAYS IN SO2-CONTAINING ICES: IMPLICATIONS ON THE PHOTOCHEMISTRY OF ICES TOWARD YOUNG STELLAR OBJECTS

International Nuclear Information System (INIS)

Pilling, S.; Bergantini, A.

2015-01-01

We investigate the effects produced mainly by broadband soft X-rays up to 2 keV (plus fast (∼keV) photoelectrons and low-energy (∼eV) induced secondary electrons) in the ice mixtures containing H 2 O:CO 2 :NH 3 :SO 2 (10:1:1:1) at two different temperatures (50 and 90 K). The experiments are an attempt to simulate the photochemical processes induced by energetic photons in SO 2 -containing ices present in cold environments in the ices surrounding young stellar objects (YSO) and in molecular clouds in the vicinity of star-forming regions, which are largely illuminated by soft X-rays. The measurements were performed using a high-vacuum portable chamber from the Laboratório de Astroquímica e Astrobiologia (LASA/UNIVAP) coupled to the spherical grating monochromator beamline at the Brazilian Synchrotron Light Source (LNLS) in Campinas, Brazil. In situ analyses were performed by a Fourier transform infrared spectrometer. Sample processing revealed the formation of several organic molecules, including nitriles, acids, and other compounds such as H 2 O 2 , H 3 O + , SO 3 , CO, and OCN − . The dissociation cross section of parental species was on the order of (2–7) × 10 −18 cm 2 . The ice temperature does not seem to affect the stability of SO 2 in the presence of X-rays. Formation cross sections of new species  produced were also determined. Molecular half-lives at ices toward YSOs due to the presence of incoming soft X-rays were estimated. The low values obtained employing two different models of the radiation field of YSOs (TW Hydra and typical T-Tauri star) reinforce that soft X-rays are indeed a very efficient source of molecular dissociation in such environments

Formation and High-order Carboxylic Acids (RCOOH) in Interstellar Analogous Ices of Carbon Dioxide (CO2) and Methane(CH4)

Science.gov (United States)

Zhu, Cheng; Turner, Andrew M.; Abplanalp, Matthew J.; Kaiser, Ralf I.

2018-01-01

This laboratory study simulated the abiotic formation of carboxylic acids (RCOOH) in interstellar analogous ices of carbon dioxide (CO2) and methane (CH4) at 10 K upon exposure to energetic electrons. The chemical processing of the ices and the subsequent warm-up phase were monitored online and in situ, exploiting Fourier Transform Infrared Spectrometry and quadrupole mass spectrometry. Characteristic absorptions of functional groups of carboxylic acids (RCOOH) were observed in the infrared spectra of the irradiated ice. Two proposed reaction mechanisms replicated the kinetic profiles of the carboxylic acids along with the decay profile of the precursors during the irradiation via hydrocarbon formation, followed by carboxylation and/or through acetic acid along with mass growth processes of the alkyl chain. Mass spectra recorded during the warm-up phase demonstrated that these acids are distributed from acetic acid (CH3COOH) up to decanoic acid (C9H19COOH). High-dose irradiation studies (91 ± 14 eV) converted low-molecular-weight acids such as acetic acid (CH3COOH) and propionic acid (C2H5COOH) to higher-molecular-weight carboxylic acids, compared to low-dose irradiation studies (18 ± 3 eV). The traces of the {{{H}}}2{{C}}= {{C}}({OH}{)}2+ (m/z = 60) fragment—a link to linear carboxylic acids—implied that higher-order acids (C n H2n+1COOH, n ≥ 5) are likely branched, which correlates with the recent analysis of the structures of the monocarboxylic acids in the Murchison meteorite.

Volcanic CO2 Emissions and Glacial Cycles: Coupled Oscillations

Science.gov (United States)

Burley, J. M.; Huybers, P. J.; Katz, R. F.

2016-12-01

Following the mid-Pleistocene transition, the dominant period of glacial cycles changed from 40 ka to 100 ka. It is broadly accepted that the 40 ka glacial cycles were driven by cyclical changes in obliquity. However, this forcing does not explain the 100 ka glacial cycles. Mechanisms proposed for 100 ka cycles include isostatic bed depression and proglacial lakes destabilising the Laurentide ice sheet, non-linear responses to orbital eccentricity, and Antarctic ice sheets influencing deep-ocean stratification. None of these are universally accepted. Here we investigate the hypothesis that variations in volcanic CO2 emissions can cause 100 ka glacial cycles. Any proposed mechanism for 100 ka glacial cycles must give the Earth's climate system a memory of 10^4 - 10^5years. This timescale is difficult to achieve for surface processes, however it is possible for the solid Earth. Recent work suggests volcanic CO2 emissions change in response to glacial cycles [1] and that there could be a 50 ka delay in that response [2]. Such a lagged response could drive glacial cycles from 40 ka cycles to an integer multiple of the forcing period. Under what conditions could the climate system admit such a response? To address this, we use a simplified climate model modified from Huybers and Tziperman [3]. Our version comprises three component models for energy balance, ice sheet growth and atmospheric CO2 concentration. The model is driven by insolation alone with other components varying according to a system of coupled, differential equations. The model is run for 500 ka to produce several glacial cycles and the resulting changes in global ice volume and atmospheric CO2 concentration.We obtain a switch from 40 ka to 100 ka cycles as the volcanic CO2 response to glacial cycles is increased. These 100 ka cycles are phase-locked to obliquity, lasting 80 or 120 ka. Whilst the MOR response required (in this model) is larger than plausible estimates based on [2], it illustrates the

Observations of CO2 in Comets C/2012 S1 ISON and C/2012 K1 PANSTARRS

Science.gov (United States)

McKay, Adam; Kelley, Michael; DiSanti, Michael; Cochran, Anita; Dello Russo, Neil; Lisse, Carey; Chanover, Nancy

2013-10-01

Comets have undergone very little thermal evolution in their lifetimes, resulting in a primitive composition. This primitive composition makes observations of comets very important tools for understanding the origin of the Solar System. The ices H2O, CO2, and CO are the primary ices present in cometary nuclei, and constraining their abundances has tremendous implications for the formation and evolutionary history of comets. Of these ices, H2O and CO can be observed from the ground, while CO2 cannot. A potentially effective tracer for CO2 in comets that is accessible from the ground is atomic oxygen. However, the relationship between these ices and atomic oxygen is only understood at a qualitative level. We propose to use Spitzer observations in IRAC's 4.5 micron band pass to observe the CO2 v3 band at 4.26 microns in comets C/2012 S1 ISON and C/2012 K1 PANSTARRS. These observations will be coordinated with observations of atomic oxygen obtained at Apache Point Observatory and McDonald Observatory and observations of H2O and CO at Keck and IRTF. These observations of H2O, CO2, and atomic oxygen in a cometary coma will increase our understanding of the link between these primary ices and atomic oxygen. With a complete understanding of the relationship between atomic oxygen and the primary ices on the nucleus, observations of atomic oxygen can serve as a powerful proxy for the production of CO2. In addition, ISON is the target of an extensive observing campaign led by NASA, and the proposed Spitzer observations fill a vital niche as the only observatory that can observe CO2 during both the near-perihelion time frame and significantly (months) after perihelion. Understanding the evolution of the CO2 abundance over the apparition is a key piece to understanding how the volatile compostion of the comet changes over the apparition.

Phase modification induced drying shrinkage reduction on Na2CO3 activated slag by incorporating Na2SO4

NARCIS (Netherlands)

Yuan, B.; Yu, Q.; Brouwers, H.J.H.

2017-01-01

This paper aims to study the phase modification, reaction kinetics, mechanical properties and drying shrinkage of sodium carbonate activated slag by incorporating sodium sulfate in the activator. The results show that the reaction process is firstly controlled by CO32− anions, and later runs similar

Preparation and characterization of spray-dried co-amorphous drug-amino acid salts

DEFF Research Database (Denmark)

Jensen, Katrine Birgitte Tarp; Blaabjerg, Lasse Ingerslev; Lenz, Elisabeth

2016-01-01

scale. In this study, spray-drying was investigated as a scale up preparation method for co-amorphous indomethacin (IND)-amino acid mixtures. In addition, the physico-chemical properties of the different co-amorphous systems were investigated with respect to the amino acids' ability towards co...... dissolution behaviour, and physical stability at various storage conditions, were examined. KEY FINDINGS: Results showed that IND could be converted into an amorphous form in combination with the amino acids arginine (ARG), histidine (HIS) and lysine (LYS) by spray-drying. Solid state characterization...... mixtures were physically stable (>10 months) at room temperature and 40°C under dry conditions. Intrinsic dissolution of the co-amorphous mixtures showed an improved dissolution behaviour under intestinal pH conditions for IND-ARG compared with the crystalline and amorphous forms of the drug. On the other...

Reviews and syntheses: Ice acidification, the effects of ocean acidification on sea ice microbial communities

Science.gov (United States)

McMinn, Andrew

2017-09-01

Sea ice algae, like some coastal and estuarine phytoplankton, are naturally exposed to a wider range of pH and CO2 concentrations than those in open marine seas. While climate change and ocean acidification (OA) will impact pelagic communities, their effects on sea ice microbial communities remain unclear. Sea ice contains several distinct microbial communities, which are exposed to differing environmental conditions depending on their depth within the ice. Bottom communities mostly experience relatively benign bulk ocean properties, while interior brine and surface (infiltration) communities experience much greater extremes. Most OA studies have examined the impacts on single sea ice algae species in culture. Although some studies examined the effects of OA alone, most examined the effects of OA and either light, nutrients or temperature. With few exceptions, increased CO2 concentration caused either no change or an increase in growth and/or photosynthesis. In situ studies on brine and surface algae also demonstrated a wide tolerance to increased and decreased pH and showed increased growth at higher CO2 concentrations. The short time period of most experiments (bacterial communities in general, impacts appear to be minimal. In sea ice also, the few reports available suggest no negative impacts on bacterial growth or community richness. Sea ice ecosystems are ephemeral, melting and re-forming each year. Thus, for some part of each year organisms inhabiting the ice must also survive outside of the ice, either as part of the phytoplankton or as resting spores on the bottom. During these times, they will be exposed to the full range of co-stressors that pelagic organisms experience. Their ability to continue to make a major contribution to sea ice productivity will depend not only on their ability to survive in the ice but also on their ability to survive the increasing seawater temperatures, changing distribution of nutrients and declining pH forecast for the water

Adsorption of trace gases to ice surfaces: surface, bulk and co-adsorbate effects

Science.gov (United States)

Kerbrat, Michael; Bartels-Rausch, Thorsten; Huthwelker, Thomas; Schneebeli, Martin; Pinzer, Bernd; Ammann, Markus

2010-05-01

Atmospheric ices frequently interact with trace gases and aerosol making them an important storage, transport or reaction medium in the global ecosystem. Further, this also alters the physical properties of the ice particles with potential consequences for the global irradiation balance and for the relative humidity of surrounding air masses. We present recent results from a set of laboratory experiments of atmospheric relevance to investigate the nature of the uptake processes. The focus of this talk will be placed on the partitioning of acidic acid and nitrous acid on ice surfaces.The presented results span from very simple reversible adsorption experiments of a single trace gas onto ice surfaces to more complex, but well controlled, experimental procedures that successfully allowed us to - Disentangle surface adsorption and uptake into the ice matrix using radioactive labelled trace gases. - Show that simultaneous adsorption of acetic acid and nitrous acid to an ice surface is consistent with the Langmuir co-adsorption model. The experiments were done in a packed ice bed flow tube at atmospheric pressure and at temperatures between 213 and 253 K. The HONO gas phase mixing ratio was between 0.4 and 137 ppbv, the mixing ratio of acetic acid between 5 and 160 ppbv . The use of the radioactive labelled nitrous acid molecules for these experiments enabled in situ monitoring of the migration of trace gas in the flow tube. The measurements showed that the interactions do not only occur through adsorption but also via diffusion into polycrystalline ice. A method is suggested to disentangle the bulk and the surface processes. The co-adsorption of acetic and nitrous acids was also investigated. The measurements are well reproduced by a competitive Langmuir adsorption model.

AKARI NEAR-INFRARED SPECTROSCOPIC SURVEY FOR CO2 IN 18 COMETS

International Nuclear Information System (INIS)

Ootsubo, Takafumi; Kawakita, Hideyo; Hamada, Saki; Kobayashi, Hitomi; Yamaguchi, Mitsuru; Usui, Fumihiko; Nakagawa, Takao; Ueno, Munetaka; Ishiguro, Masateru; Sekiguchi, Tomohiko; Watanabe, Jun-ichi; Sakon, Itsuki; Shimonishi, Takashi; Onaka, Takashi

2012-01-01

We conducted a spectroscopic survey of cometary volatiles with the Infrared Camera on board the Japanese infrared satellite AKARI in the wavelength range from 2.5 to 5 μm. In our survey, 18 comets, including both the Oort cloud comets and the Jupiter-family comets, were observed in the period from 2008 June to 2010 January, most of which were observed at least twice. The prominent emission bands in the observed spectra are the fundamental vibrational bands of water (H 2 O) at 2.7 μm and carbon dioxide (CO 2 ) at 4.3 μm. The fundamental vibrational band of carbon monoxide (CO) around 4.7 μm and the broad emission feature, probably related to carbon-hydrogen-bearing molecules, can also be recognized around the 3.3-3.5-μm region in some of the comets. With respect to H 2 O, gas production rate ratios of CO 2 have been derived in 17 comets, except for the comet 29P/Schwassmann-Wachmann 1. Our data set provides the largest homogeneous database of CO 2 /H 2 O production rate ratios in comets obtained so far. The CO 2 /H 2 O production rate ratios are considered to reflect the composition of cometary ice when a comet is observed at a heliocentric distance within ∼2.5 AU, since H 2 O ice fully sublimates there. The CO 2 /H 2 O ratio in cometary ice spans from several to ∼30% among the comets observed at 2 in the comets seems to be smaller than unity based on our observations, although we only obtain upper limits for CO in most of the comets.

Dry calving processes at the ice cliff of an antarctic local glacier: the study case of Strandline Glacier (Northern Victoria Land, Antarctica)

Science.gov (United States)

Smiraglia, C.; Motta, M.; Vassena, G.; Diolaiuti, G.

2003-04-01

In Antartic coastal area, where the ice sheet and the large outlet glaciers do not reach the sea and where some rugged mountain chains are often present, many small glaciers can be found. They are the so called local or alpine type glaciers, which have their terminus ground-based such as the real alpine glaciers and rarely reach the main valley floors. They are practically isolated and independent from the supply flowing down from the plateau and their mass balance is mainly controlled by sublimation and aeolic erosion and accumulation. The glaciers closer to the coast are submitted to the melting as well, and when the terminus is cliff-shaped they are also affected by dry calving. The most known and studied Antarctic local glaciers are placed in the Dry Valleys region (Chinn, 1985), but this kind of glaciers is also diffused all along the Northern Victoria Land coastal region (Chinn and others, 1989). Since the first Italian Antarctic expedition (1985), many studies have been carried out on this type of glaciers, which can be usefull for detailed mass balance evaluations and for obtaining information about the effects of the present climatic dynamics on the Antarctic coastal environment (Baroni and Orombelli, 1987; Baroni and others, 1995; Meneghel, 1999; Vassena and others., 2001). The Strandline Glacier (74 41 S; 164 07 E), in particular is a small alpine glacier (0,79 kmq) on the coast of Terra Nova Bay, Northern Victoria Land; it is a cold glacier where accumulation and ablation basins are mainly controlled by wind processes. Its terminus forms in the central part a grounded ice cliff about 30 m high, about 130 m far from the sea. On that glacier mass balance, surface velocity and calving rate were measured. During the southern summer season 2000-2001 many topographycal profiles of the ice cliff were surveyed by using both classical topographical and glaciological methods (total station and stakes) and GPS technique. It was so possible to detect the short term

Indoor air quality in ice skating rinks in Hong Kong

International Nuclear Information System (INIS)

Guo, H.; Lee, S.C.; Chan, L.Y.

2004-01-01

Indoor air quality in ice skating rinks has become a public concern due to the use of propane- or gasoline-powered ice resurfacers and edgers. In this study, the indoor air quality in three ice rinks with different volumes and resurfacer power sources (propane and gasoline) was monitored during usual operating hours. The measurements included continuous recording of carbon monoxide (CO), carbon dioxide (CO 2 ), total volatile organic compounds (TVOC), particulate matter with a diameter less than 2.5 μm (PM 2.5 ), particulate matter with diameter less than 10 μm (PM 10 ), nitric oxide (NO), nitrogen dioxide (NO 2 ), nitrogen oxide (NO x ), and sulfur dioxide (SO 2 ). The average CO, CO 2 , and TVOC concentrations ranged from 3190 to 6749 μg/m 3 , 851 to 1329 ppm, and 550 to 765 μg/m 3 , respectively. The average NO and NO 2 concentrations ranged from 69 to 1006 μg/m 3 and 58 to 242 μg/m 3 , respectively. The highest CO and TVOC levels were observed in the ice rink which a gasoline-fueled resurfacer was used. The highest NO and NO 2 levels were recorded in the ice rink with propane-fueled ice resurfacers. The air quality parameters of PM 2.5 , PM 10 , and SO 2 were fully acceptable in these ice rinks according to HKIAQO standards. Overall, ice resurfacers with combustion engines cause indoor air pollution in ice rinks in Hong Kong. This conclusion is similar to those of previous studies in Europe and North America

Causes of ice age intensification across the Mid-Pleistocene Transition

Science.gov (United States)

Chalk, Thomas B.; Hain, Mathis P.; Foster, Gavin L.; Rohling, Eelco J.; Sexton, Philip F.; Badger, Marcus P. S.; Cherry, Soraya G.; Hasenfratz, Adam P.; Haug, Gerald H.; Jaccard, Samuel L.; Martínez-García, Alfredo; Pälike, Heiko; Pancost, Richard D.; Wilson, Paul A.

2017-12-01

During the Mid-Pleistocene Transition (MPT; 1,200–800 kya), Earth's orbitally paced ice age cycles intensified, lengthened from ˜40,000 (˜40 ky) to ˜100 ky, and became distinctly asymmetrical. Testing hypotheses that implicate changing atmospheric CO2 levels as a driver of the MPT has proven difficult with available observations. Here, we use orbitally resolved, boron isotope CO2 data to show that the glacial to interglacial CO2 difference increased from ˜43 to ˜75 μatm across the MPT, mainly because of lower glacial CO2 levels. Through carbon cycle modeling, we attribute this decline primarily to the initiation of substantive dust-borne iron fertilization of the Southern Ocean during peak glacial stages. We also observe a twofold steepening of the relationship between sea level and CO2-related climate forcing that is suggestive of a change in the dynamics that govern ice sheet stability, such as that expected from the removal of subglacial regolith or interhemispheric ice sheet phase-locking. We argue that neither ice sheet dynamics nor CO2 change in isolation can explain the MPT. Instead, we infer that the MPT was initiated by a change in ice sheet dynamics and that longer and deeper post-MPT ice ages were sustained by carbon cycle feedbacks related to dust fertilization of the Southern Ocean as a consequence of larger ice sheets.

Preparation and recrystallization behavior of spray-dried co-amorphous naproxen-indomethacin

DEFF Research Database (Denmark)

Beyer, Andreas; Radi, Lydia; Grohganz, Holger

2016-01-01

(2) factorial design and the obtained samples were analyzed with X-ray powder diffractometry and Fourier-transformed infrared spectroscopy. Evaluation of the data revealed that the preparation of fully amorphous samples could be achieved depending on the process conditions. The resulting recrystallization......To improve the dissolution properties and the physical stability of amorphous active pharmaceutical ingredients, small molecule stabilizing agents may be added to prepare co-amorphous systems. The objective of the study was to investigate if spray-drying allows the preparation of co-amorphous drug...

Patterns and possible mechanisms of soil CO2 uptake in sandy soil.

Science.gov (United States)

Fa, Ke-Yu; Zhang, Yu-Qing; Wu, Bin; Qin, Shu-Gao; Liu, Zhen; She, Wei-Wei

2016-02-15

It has been reported that soils in drylands can absorb CO2, although the patterns and mechanisms of such a process remain under debate. To address this, we investigated the relationships between soil CO2 flux and meteorological factors and soil properties in Northwest China to reveal the reasons for "anomalous" soil CO2 flux in a desert ecosystem. Soil CO2 flux increased significantly and exponentially with surficial turbulence at the diel scale under dry conditions (Psoil CO2 flux demonstrated remarkable negative correlation with soil air pressure (Psoil water content was insufficient to dissolve the absorbed CO2 in dry conditions, but was sufficient in wet conditions. The concentration of soil HCO3(-) in the morning was higher than in the evening in dry conditions, but this pattern was reversed in wet conditions. These results imply that CO2 outgassing induced by turbulence, expansion of soil air, CO2 effusion from soil water, and carbonate precipitation during daytime can explain the abiotic diurnal CO2 release. Moreover, CO2 pumping from the atmosphere into the soil, caused mainly by carbonate dissolution, can account for nocturnal CO2 absorption in dry conditions. The abiotic soil CO2 flux pattern (CO2 absorption throughout the diel cycle) in wet conditions can be attributed to downward mass flow of soil CO2 and intensified soil air shrinkage, CO2 dissolving in soil water, and carbonate dissolution. These results provide a basis for determining the location of abiotic fixed carbon within soils in desert ecosystems. Copyright © 2015 Elsevier B.V. All rights reserved.

A centrifuge CO2 pellet cleaning system

Science.gov (United States)

Foster, C. A.; Fisher, P. W.; Nelson, W. D.; Schechter, D. E.

1995-01-01

An advanced turbine/CO2 pellet accelerator is being evaluated as a depaint technology at Oak Ridge National Laboratory (ORNL). The program, sponsored by Warner Robins Air Logistics Center (ALC), Robins Air Force Base, Georgia, has developed a robot-compatible apparatus that efficiently accelerates pellets of dry ice with a high-speed rotating wheel. In comparison to the more conventional compressed air 'sandblast' pellet accelerators, the turbine system can achieve higher pellet speeds, has precise speed control, and is more than ten times as efficient. A preliminary study of the apparatus as a depaint technology has been undertaken. Depaint rates of military epoxy/urethane paint systems on 2024 and 7075 aluminum panels as a function of pellet speed and throughput have been measured. In addition, methods of enhancing the strip rate by combining infra-red heat lamps with pellet blasting and by combining the use of environmentally benign solvents with the pellet blasting have also been studied. The design and operation of the apparatus will be discussed along with data obtained from the depaint studies.

A role for atmospheric CO2 in preindustrial climate forcing

NARCIS (Netherlands)

Hoof, T.B. van; Wagner-Cremer, F.; Kürschner, W.M.; Visscher, H.

2008-01-01

Complementary to measurements in Antarctic ice cores, stomatal frequency analysis of leaves of land plants preserved in peat and lake deposits can provide a proxy record of preindustrial atmospheric CO2 concentration. CO2 trends based on leaf remains of Quercus robur (English oak) from the

The influence of ice sheets on temperature during the past 38 million years inferred from a one-dimensional ice sheet-climate model

Science.gov (United States)

Stap, Lennert B.; van de Wal, Roderik S. W.; de Boer, Bas; Bintanja, Richard; Lourens, Lucas J.

2017-09-01

Since the inception of the Antarctic ice sheet at the Eocene-Oligocene transition (˜ 34 Myr ago), land ice has played a crucial role in Earth's climate. Through feedbacks in the climate system, land ice variability modifies atmospheric temperature changes induced by orbital, topographical, and greenhouse gas variations. Quantification of these feedbacks on long timescales has hitherto scarcely been undertaken. In this study, we use a zonally averaged energy balance climate model bidirectionally coupled to a one-dimensional ice sheet model, capturing the ice-albedo and surface-height-temperature feedbacks. Potentially important transient changes in topographic boundary conditions by tectonics and erosion are not taken into account but are briefly discussed. The relative simplicity of the coupled model allows us to perform integrations over the past 38 Myr in a fully transient fashion using a benthic oxygen isotope record as forcing to inversely simulate CO2. Firstly, we find that the results of the simulations over the past 5 Myr are dependent on whether the model run is started at 5 or 38 Myr ago. This is because the relation between CO2 and temperature is subject to hysteresis. When the climate cools from very high CO2 levels, as in the longer transient 38 Myr run, temperatures in the lower CO2 range of the past 5 Myr are higher than when the climate is initialised at low temperatures. Consequently, the modelled CO2 concentrations depend on the initial state. Taking the realistic warm initialisation into account, we come to a best estimate of CO2, temperature, ice-volume-equivalent sea level, and benthic δ18O over the past 38 Myr. Secondly, we study the influence of ice sheets on the evolution of global temperature and polar amplification by comparing runs with ice sheet-climate interaction switched on and off. By passing only albedo or surface height changes to the climate model, we can distinguish the separate effects of the ice-albedo and surface

Investigation of Wyoming Bentonite Hydration in Dry to Water-Saturated Supercritical CO2: Implications for Caprock Integrity

Science.gov (United States)

Loring, J. S.; Chen, J.; Thompson, C.; Schaef, T.; Miller, Q. R.; Martin, P. F.; Ilton, E. S.; Qafoku, O.; Felmy, A. R.; Rosso, K. M.

2012-12-01

The effectiveness of geologic sequestration as an enterprise for CO2 storage depends partly on the reactivity of supercritical CO2 (scCO2) with caprock minerals. Injection of scCO2 will displace formation water, and the pore space adjacent to overlying caprocks could eventually be dominated by dry to water-saturated scCO2. Caprock formations have high concentrations of clay minerals, including expandable montmorillonites. Water-bearing scCO2 is highly reactive and capable of hydrating or dehydrating clays, possibly leading to porosity and permeability changes that directly impact caprock performance. Dehydration will cause montmorillonite clay minerals in caprocks to contract, thereby decreasing solid volume and possibly increasing caprock permeability and porosity. On the other hand, water intercalation will cause these clays to expand, thereby increasing solid volume and possibly leading to self-sealing of caprock fractures. Pacific Northwest National Laboratory's Carbon Sequestration Initiative is developing capabilities for studying wet scCO2-mineral reactions in situ. Here, we introduce novel in situ infrared (IR) spectroscopic instrumentation that enables quantitative titrations of reactant minerals with water in scCO2. Results are presented for the infrared spectroscopic titrations of Na-, Ca-, and Mg-saturated Wyoming betonites with water over concentrations ranging from zero to scCO2 saturated. These experiments were carried out at 50°C and 90 bar. Transmission IR spectroscopy was used to measure concentrations of water dissolved in the scCO2 or intercalated into the clays. The titration curves evaluated from the transmission-IR data are compared between the three types of clays to assess the effects of the cation on water partitioning. Single-reflection attenuated total reflection (ATR) IR spectroscopy was used to collect the spectrum of the clays as they hydrate at every total water concentration during the titration. Clay hydration is evidenced by

Hydrogeomorphic processes of thermokarst lakes with grounded-ice and floating-ice regimes on the Arctic coastal plain, Alaska

Science.gov (United States)

Arp, C.D.; Jones, Benjamin M.; Urban, F.E.; Grosse, G.

2011-01-01

Thermokarst lakes cover > 20% of the landscape throughout much of the Alaskan Arctic Coastal Plain (ACP) with shallow lakes freezing solid (grounded ice) and deeper lakes maintaining perennial liquid water (floating ice). Thus, lake depth relative to maximum ice thickness (1·5–2·0 m) represents an important threshold that impacts permafrost, aquatic habitat, and potentially geomorphic and hydrologic behaviour. We studied coupled hydrogeomorphic processes of 13 lakes representing a depth gradient across this threshold of maximum ice thickness by analysing remotely sensed, water quality, and climatic data over a 35-year period. Shoreline erosion rates due to permafrost degradation ranged from L) with periods of full and nearly dry basins. Shorter-term (2004–2008) specific conductance data indicated a drying pattern across lakes of all depths consistent with the long-term record for only shallow lakes. Our analysis suggests that grounded-ice lakes are ice-free on average 37 days longer than floating-ice lakes resulting in a longer period of evaporative loss and more frequent negative P − EL. These results suggest divergent hydrogeomorphic responses to a changing Arctic climate depending on the threshold created by water depth relative to maximum ice thickness in ACP lakes.

CO{sub 2} uptake by the Kalanchoe plant; CO{sub 2}-opname bij Kalanchoe

Energy Technology Data Exchange (ETDEWEB)

Verberkt, H.

1994-01-01

The results of a study on the assimilation of the Kalanchoe plant are presented. The aim of the study is to determine the optimal time period of a natural day (24 hours) to supply carbon dioxide to a Kalanchoe plant. A Kalanchoe plant originally is a so-called CAM (Crassulacean Acid Metabolism) plant: CO{sub 2} uptake at night and chemical conversion of CO{sub 2} into malic acid. By day the fixed CO{sub 2} is used for photosynthesis. It appears that a Kalanchoe plant also takes up CO{sub 2} by day, which is directly used for photosynthesis. For Dutch horticulture conditions (20C, sufficient moisture) extra CO{sub 2} supply by day in the spring results in an increase of both the fresh weight and the dry weight compared to no extra CO{sub 2} supply. 10 figs., 3 tabs., 19 refs., 4 appendices

The counteracting effects of elevated atmospheric CO2 concentrations and drought episodes: Studies of enchytraeid communities in a dry heathland

DEFF Research Database (Denmark)

Maraldo, Kristine; Krogh, Paul Henning; Linden, Leon

2010-01-01

The potential impacts of interactions of multiple climate change factors in soil ecosystems have received little attention. Most studies have addressed effects of single factors such as increased temperature or atmospheric CO2 but little is known about how such environmental factors will interact...... impact of drought on the enchytraeids, compared to the year with a wet summer and autumn (2007). Our study emphasises the importance of multi-factorial experimental design as a means to investigate effects of climatic changes.......The potential impacts of interactions of multiple climate change factors in soil ecosystems have received little attention. Most studies have addressed effects of single factors such as increased temperature or atmospheric CO2 but little is known about how such environmental factors will interact....... In the present study we investigate the effects of in situ exposure to elevated atmospheric CO2 concentration, increased temperatures and prolonged drought episodes on field communities of Enchytraeidae (Oligochaeta) in a dry heathland (Brandbjerg, Denmark). Increased CO2 had a positive effect on enchytraeid...

AKARI NEAR-INFRARED SPECTROSCOPIC SURVEY FOR CO{sub 2} IN 18 COMETS

Energy Technology Data Exchange (ETDEWEB)

Ootsubo, Takafumi [Astronomical Institute, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578 (Japan); Kawakita, Hideyo; Hamada, Saki; Kobayashi, Hitomi; Yamaguchi, Mitsuru [Koyama Astronomical Observatory, Kyoto Sangyo University, Motoyama, Kamigamo, Kita-Ku, Kyoto 603-8555 (Japan); Usui, Fumihiko; Nakagawa, Takao; Ueno, Munetaka [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan); Ishiguro, Masateru [Department of Physics and Astronomy, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul 151-742 (Korea, Republic of); Sekiguchi, Tomohiko [Department of Teacher Training, Hokkaido University of Education, Asahikawa Campus, Hokumon 9, Asahikawa, Hokkaido 070-8621 (Japan); Watanabe, Jun-ichi [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Sakon, Itsuki; Shimonishi, Takashi; Onaka, Takashi, E-mail: ootsubo@astr.tohoku.ac.jp [Department of Astronomy, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)

2012-06-10

We conducted a spectroscopic survey of cometary volatiles with the Infrared Camera on board the Japanese infrared satellite AKARI in the wavelength range from 2.5 to 5 {mu}m. In our survey, 18 comets, including both the Oort cloud comets and the Jupiter-family comets, were observed in the period from 2008 June to 2010 January, most of which were observed at least twice. The prominent emission bands in the observed spectra are the fundamental vibrational bands of water (H{sub 2}O) at 2.7 {mu}m and carbon dioxide (CO{sub 2}) at 4.3 {mu}m. The fundamental vibrational band of carbon monoxide (CO) around 4.7 {mu}m and the broad emission feature, probably related to carbon-hydrogen-bearing molecules, can also be recognized around the 3.3-3.5-{mu}m region in some of the comets. With respect to H{sub 2}O, gas production rate ratios of CO{sub 2} have been derived in 17 comets, except for the comet 29P/Schwassmann-Wachmann 1. Our data set provides the largest homogeneous database of CO{sub 2}/H{sub 2}O production rate ratios in comets obtained so far. The CO{sub 2}/H{sub 2}O production rate ratios are considered to reflect the composition of cometary ice when a comet is observed at a heliocentric distance within {approx}2.5 AU, since H{sub 2}O ice fully sublimates there. The CO{sub 2}/H{sub 2}O ratio in cometary ice spans from several to {approx}30% among the comets observed at <2.5 AU (13 out of the 17 comets). Alternatively, the ratio of CO/CO{sub 2} in the comets seems to be smaller than unity based on our observations, although we only obtain upper limits for CO in most of the comets.

Following the south polar cap recession as viewed by OMEGA/MEX using automatic detection of H2O and CO2 ices.

Science.gov (United States)

Schmidt, F.; Doute, S.; Schmitt, B.

In order to understand Mars' current climate it is necessary to detect, characterize and monitor CO2 and H2O at the surface (permanent and seasonal icy deposits) and in the atmosphere (vapor and clouds). Here we will focus on the South Seasonal Polar Cap (SSPC) whose recession was previously observed with different techniques : from earth in the visible range with HST [James 1996], or from MGS spacecraft with MOC images [Benson 2005], in the thermal IR range by the TES [Kieffer 2000], in the near infrared by OMEGA/MEX [Langevin submitted]. The time and space evolutions of the SSPC is a major annual climatic signal both at the global and the regional scales. In particular the measurement of the temporal and spatial distributions of CO2 constrains exchange processes between both surface and atmosphere. This exchange may involve preponderant species : H2O, CO2 and dust. In this work we will apply a new detection technique : "wavanglet" in order to follow the recession of the SSPC thanks to OMEGA/MEX observations. This method was especially developed in the goal to classify a huge dataset, such OMEGA ones. We propose to use "wavanglet" as a supervised automatic classification method that identifies spectral features and classifies the image in spectrally homogeneous units. Additionally we will evaluate quantitative detection limits of "wavanglet" based on synthetic dataset simulating OMEGA spectra in typical situation of the SSPC. This detection limit will be discussed in terms of abundance for H2O and CO2 ices in order to improve the interpretation of the classification. Finally we will present the recession of the SSPC using "wavanglet" and we will compare the results with those of earlier investigation. An interpretation of the similarities and disagreements between those maps will be done.

Development of decontamination system for radioactive matter on paved road using dry ice blast method

International Nuclear Information System (INIS)

Nagamine, Haruo; Wakayama, Masanori; Nakamura, Hiroshi

2014-01-01

As a decontamination method for paved road surface, the 'Dry Ice Blast Decontamination System' has been developed. This decontamination system has characteristic as follows; 1) Generation of decontamination waste is extremely small, 2) not using water, 3) not damaging the pavement surface. In actual decontamination work, more than 60% average (maximum 84%) reduction rate of the radiation counting rate has been achieved. In addition to these features, this system prevent the diffusion into the surrounding and the radiation exposure of workers by sucking waste quickly using attached dust collecting function. This system is also characterized in that it does not cause a difference in skill by the operator because of faceted decontamination using repetitive motion by concatenating three pellet injection nozzle and self-propelled decontamination machine. (author)

Advanced turbine/CO2 pellet accelerator

International Nuclear Information System (INIS)

Foster, C.A.; Fisher, P.W.

1994-01-01

An advanced turbine/CO 2 pellet accelerator is being evaluated as a depaint technology at Oak Ridge National Laboratory. The program, sponsored by Warner Robins Air Logistics Center, Robins Air Force Base, Georgia, has developed a robot-compatible apparatus that efficiently accelerates pellets of dry ice with a high-speed rotating wheel. In comparison to the more conventional compressed air sandblast pellet accelerators, the turbine system can achieve higher pellet speeds, has precise speed control, and is more than ten times as efficient. A preliminary study of the apparatus as a depaint technology has been undertaken. Depaint rates of military epoxy/urethane paint systems on 2024 and 7075 aluminum panels as a function of pellet speed and throughput have been measured. In addition, methods of enhancing the strip rate by combining infra-red heat lamps with pellet blasting have also been studied. The design and operation of the apparatus will be discussed along with data obtained from the depaint studies. Applications include removal of epoxy-based points from aircraft and the cleaning of surfaces contaminated with toxic, hazardous, or radioactive substances. The lack of a secondary contaminated waste stream is of great benefit

Tightened constraints on the time-lag between Antarctic temperature and CO2 during the last deglaciation

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T. D. van Ommen

2012-07-01

Full Text Available Antarctic ice cores provide clear evidence of a close coupling between variations in Antarctic temperature and the atmospheric concentration of CO2 during the glacial/interglacial cycles of at least the past 800-thousand years. Precise information on the relative timing of the temperature and CO2 changes can assist in refining our understanding of the physical processes involved in this coupling. Here, we focus on the last deglaciation, 19 000 to 11 000 yr before present, during which CO2 concentrations increased by ~80 parts per million by volume and Antarctic temperature increased by ~10 °C. Utilising a recently developed proxy for regional Antarctic temperature, derived from five near-coastal ice cores and two ice core CO2 records with high dating precision, we show that the increase in CO2 likely lagged the increase in regional Antarctic temperature by less than 400 yr and that even a short lead of CO2 over temperature cannot be excluded. This result, consistent for both CO2 records, implies a faster coupling between temperature and CO2 than previous estimates, which had permitted up to millennial-scale lags.

Scalable organic solvent free supercritical fluid spray drying process for producing dry protein formulations.

Science.gov (United States)

Nuchuchua, O; Every, H A; Hofland, G W; Jiskoot, W

2014-11-01

In this study, we evaluated the influence of supercritical carbon dioxide (scCO2) spray drying conditions, in the absence of organic solvent, on the ability to produce dry protein/trehalose formulations at 1:10 and 1:4 (w/w) ratios. When using a 4L drying vessel, we found that decreasing the solution flow rate and solution volume, or increasing the scCO2 flow rate resulted in a significant reduction in the residual water content in dried products (Karl Fischer titration). The best conditions were then used to evaluate the ability to scale the scCO2 spray drying process from 4L to 10L chamber. The ratio of scCO2 and solution flow rate was kept constant. The products on both scales exhibited similar residual moisture contents, particle morphologies (SEM), and glass transition temperatures (DSC). After reconstitution, the lysozyme activity (enzymatic assay) and structure (circular dichroism, HP-SEC) were fully preserved, but the sub-visible particle content was slightly increased (flow imaging microscopy, nanoparticle tracking analysis). Furthermore, the drying condition was applicable to other proteins resulting in products of similar quality as the lysozyme formulations. In conclusion, we established scCO2 spray drying processing conditions for protein formulations without an organic solvent that holds promise for the industrial production of dry protein formulations. Copyright © 2014 Elsevier B.V. All rights reserved.

Reviews and syntheses: Ice acidification, the effects of ocean acidification on sea ice microbial communities

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A. McMinn

2017-09-01

Full Text Available Sea ice algae, like some coastal and estuarine phytoplankton, are naturally exposed to a wider range of pH and CO2 concentrations than those in open marine seas. While climate change and ocean acidification (OA will impact pelagic communities, their effects on sea ice microbial communities remain unclear. Sea ice contains several distinct microbial communities, which are exposed to differing environmental conditions depending on their depth within the ice. Bottom communities mostly experience relatively benign bulk ocean properties, while interior brine and surface (infiltration communities experience much greater extremes. Most OA studies have examined the impacts on single sea ice algae species in culture. Although some studies examined the effects of OA alone, most examined the effects of OA and either light, nutrients or temperature. With few exceptions, increased CO2 concentration caused either no change or an increase in growth and/or photosynthesis. In situ studies on brine and surface algae also demonstrated a wide tolerance to increased and decreased pH and showed increased growth at higher CO2 concentrations. The short time period of most experiments (< 10 days, together with limited genetic diversity (i.e. use of only a single strain, however, has been identified as a limitation to a broader interpretation of the results. While there have been few studies on the effects of OA on the growth of marine bacterial communities in general, impacts appear to be minimal. In sea ice also, the few reports available suggest no negative impacts on bacterial growth or community richness. Sea ice ecosystems are ephemeral, melting and re-forming each year. Thus, for some part of each year organisms inhabiting the ice must also survive outside of the ice, either as part of the phytoplankton or as resting spores on the bottom. During these times, they will be exposed to the full range of co-stressors that pelagic organisms experience. Their ability

Methanol ice co-desorption as a mechanism to explain cold methanol in the gas-phase

Science.gov (United States)

Ligterink, N. F. W.; Walsh, C.; Bhuin, R. G.; Vissapragada, S.; van Scheltinga, J. Terwisscha; Linnartz, H.

2018-05-01

Context. Methanol is formed via surface reactions on icy dust grains. Methanol is also detected in the gas-phase at temperatures below its thermal desorption temperature and at levels higher than can be explained by pure gas-phase chemistry. The process that controls the transition from solid state to gas-phase methanol in cold environments is not understood. Aims: The goal of this work is to investigate whether thermal CO desorption provides an indirect pathway for methanol to co-desorb at low temperatures. Methods: Mixed CH3OH:CO/CH4 ices were heated under ultra-high vacuum conditions and ice contents are traced using RAIRS (reflection absorption IR spectroscopy), while desorbing species were detected mass spectrometrically. An updated gas-grain chemical network was used to test the impact of the results of these experiments. The physical model used is applicable for TW Hya, a protoplanetary disk in which cold gas-phase methanol has recently been detected. Results: Methanol release together with thermal CO desorption is found to be an ineffective process in the experiments, resulting in an upper limit of ≤ 7.3 × 10-7 CH3OH molecules per CO molecule over all ice mixtures considered. Chemical modelling based on the upper limits shows that co-desorption rates as low as 10-6 CH3OH molecules per CO molecule are high enough to release substantial amounts of methanol to the gas-phase at and around the location of the CO thermal desorption front in a protoplanetary disk. The impact of thermal co-desorption of CH3OH with CO as a grain-gas bridge mechanism is compared with that of UV induced photodesorption and chemisorption.

Local drying underwater cutting of reactor core internals by CO laser

International Nuclear Information System (INIS)

Beppu, Seiji; Takano, Genta; Matsumoto, Osa; Sugihara, Masaaki; Miya, Kenzo.

1991-01-01

Since the CO laser operates at shorter wavelength than the CO 2 laser, the former has superior ability to cut materials. Its applicability to the cutting of reactor core internals in a nuclear power plant has been studied. In order to use such a laser for cutting actual structures, it would be useful to develop underwater cutting technology for the purpose of minimizing radiation exposure during cutting. However, since the laser beam is absorbed by water, a path needs to be cleared along the laser's line of sight. The authors have developed a nozzle that forms a local dry zone and have demonstrated that CO laser cutting can be carried out under water as it is in air. (author)

A MULTILAYER BIOCHEMICAL DRY DEPOSITION MODEL 2. MODEL EVALUATION

Science.gov (United States)

The multilayer biochemical dry deposition model (MLBC) described in the accompanying paper was tested against half-hourly eddy correlation data from six field sites under a wide range of climate conditions with various plant types. Modeled CO2, O3, SO2<...

Immunomodulatory effects of supercritical fluid CO2 extracts from freeze-dried powder of Tenebrio molitor larvae (yellow mealworm

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QingFeng TANG

2016-01-01

Full Text Available Abstract In order to take full advantage of Tenebrio molitor larvae (yellow mealworm resources, the supercritical CO2 fluid freeze-dried powder of T. molitor larvae (fdTML extraction on the immune systems of mice was carried out. The results about the effects of supercritical CO2 fluid fdTML extraction on carbon expurgation and phagocytosis of peritoneal macrophages experiments of mice indicated that the fdTML extraction enhanced observably carbon expurgatory index, phagocytic rate and phagocytic index. The fdTML extraction could stimulate response of delayed hypersensitivity. The proliferation of ConA-induced mitogenic reponse for spleen lymphocyte was also increased. The amount of hemolytic antibody in mice serum increased compared with those of the control group mice. The half of hemolysis values in serum of treated mice increased compared to the control group. Furthermore, serum NO content in all treatment groups was higher than that of the control group whereas acid phosphatase and alkaline phosphatase activity was only significantly higher relative to the control group. Our findings suggest that supercritical CO2 fluid the fdTML extraction has potential as a health food supplement.

Plio-Pleistocene climate sensitivity evaluated using high-resolution CO2 records.

Science.gov (United States)

Martínez-Botí, M A; Foster, G L; Chalk, T B; Rohling, E J; Sexton, P F; Lunt, D J; Pancost, R D; Badger, M P S; Schmidt, D N

2015-02-05

Theory and climate modelling suggest that the sensitivity of Earth's climate to changes in radiative forcing could depend on the background climate. However, palaeoclimate data have thus far been insufficient to provide a conclusive test of this prediction. Here we present atmospheric carbon dioxide (CO2) reconstructions based on multi-site boron-isotope records from the late Pliocene epoch (3.3 to 2.3 million years ago). We find that Earth's climate sensitivity to CO2-based radiative forcing (Earth system sensitivity) was half as strong during the warm Pliocene as during the cold late Pleistocene epoch (0.8 to 0.01 million years ago). We attribute this difference to the radiative impacts of continental ice-volume changes (the ice-albedo feedback) during the late Pleistocene, because equilibrium climate sensitivity is identical for the two intervals when we account for such impacts using sea-level reconstructions. We conclude that, on a global scale, no unexpected climate feedbacks operated during the warm Pliocene, and that predictions of equilibrium climate sensitivity (excluding long-term ice-albedo feedbacks) for our Pliocene-like future (with CO2 levels up to maximum Pliocene levels of 450 parts per million) are well described by the currently accepted range of an increase of 1.5 K to 4.5 K per doubling of CO2.

Plio-Pleistocene climate sensitivity evaluated using high-resolution CO2 records

Science.gov (United States)

Martínez-Botí, M. A.; Foster, G. L.; Chalk, T. B.; Rohling, E. J.; Sexton, P. F.; Lunt, D. J.; Pancost, R. D.; Badger, M. P. S.; Schmidt, D. N.

2015-02-01

Theory and climate modelling suggest that the sensitivity of Earth's climate to changes in radiative forcing could depend on the background climate. However, palaeoclimate data have thus far been insufficient to provide a conclusive test of this prediction. Here we present atmospheric carbon dioxide (CO2) reconstructions based on multi-site boron-isotope records from the late Pliocene epoch (3.3 to 2.3 million years ago). We find that Earth's climate sensitivity to CO2-based radiative forcing (Earth system sensitivity) was half as strong during the warm Pliocene as during the cold late Pleistocene epoch (0.8 to 0.01 million years ago). We attribute this difference to the radiative impacts of continental ice-volume changes (the ice-albedo feedback) during the late Pleistocene, because equilibrium climate sensitivity is identical for the two intervals when we account for such impacts using sea-level reconstructions. We conclude that, on a global scale, no unexpected climate feedbacks operated during the warm Pliocene, and that predictions of equilibrium climate sensitivity (excluding long-term ice-albedo feedbacks) for our Pliocene-like future (with CO2 levels up to maximum Pliocene levels of 450 parts per million) are well described by the currently accepted range of an increase of 1.5 K to 4.5 K per doubling of CO2.

Late-glacial atmospheric CO{sub 2} reconstructions from western Norway using fossil leaves

Energy Technology Data Exchange (ETDEWEB)

Birks, H H; Birks, H J.B. [Sheffield Univ. (United Kingdom). Dept. of Animal and Plant Sciences; Beerling, D J; Woodward, F I [Bergen Univ. (Norway). Botanical Inst.

1996-12-31

Analyses of air bubbles trapped in Antarctic ice-cores have shown that atmospheric CO{sub 2} concentrations are 180-200 ppmv during glacial periods, and ca. 280 ppmv during interglacials, including the Holocene. The change from glacial to Holocene concentrations occurred steadily over ca. 5000 years, slightly lagging the temperature increase inferred from {delta}{sup 18}. Antarctic ice cores lack fine time resolution over the late-glacial/early Holocene period 12-9000 {sup 14}C yr BP, that includes the Younger Dryas cold oscillation. The stomatal density on leaves is inversely proportional to the concentration of atmospheric CO{sub 2}. A late glacial sequence at Kraakenes, western Norway, contains well-preserved Salix herbacea (dwarf willow) leaves, dated from 11700-9600 {sup 14}C yr BP. If the stomatal density is measured on the fossil leaves, a calibration derived from the relationship of stomatal density of modern material of the same species to known CO{sub 2} concentrations can be used to reconstruct CO{sub 2} concentrations of the past. Because of the decadal time-resolution available at Kraakenes through the late-glacial and early Holocene, a detailed record of CO{sub 2} concentrations can be reconstructed over this period, that will complement the ice core record. (author)

Late-glacial atmospheric CO{sub 2} reconstructions from western Norway using fossil leaves

Energy Technology Data Exchange (ETDEWEB)

Birks, H.H.; Birks, H.J.B. [Sheffield Univ. (United Kingdom). Dept. of Animal and Plant Sciences; Beerling, D.J.; Woodward, F.I. [Bergen Univ. (Norway). Botanical Inst.

1995-12-31

Analyses of air bubbles trapped in Antarctic ice-cores have shown that atmospheric CO{sub 2} concentrations are 180-200 ppmv during glacial periods, and ca. 280 ppmv during interglacials, including the Holocene. The change from glacial to Holocene concentrations occurred steadily over ca. 5000 years, slightly lagging the temperature increase inferred from {delta}{sup 18}. Antarctic ice cores lack fine time resolution over the late-glacial/early Holocene period 12-9000 {sup 14}C yr BP, that includes the Younger Dryas cold oscillation. The stomatal density on leaves is inversely proportional to the concentration of atmospheric CO{sub 2}. A late glacial sequence at Kraakenes, western Norway, contains well-preserved Salix herbacea (dwarf willow) leaves, dated from 11700-9600 {sup 14}C yr BP. If the stomatal density is measured on the fossil leaves, a calibration derived from the relationship of stomatal density of modern material of the same species to known CO{sub 2} concentrations can be used to reconstruct CO{sub 2} concentrations of the past. Because of the decadal time-resolution available at Kraakenes through the late-glacial and early Holocene, a detailed record of CO{sub 2} concentrations can be reconstructed over this period, that will complement the ice core record. (author)

Dry reforming of methane with CO2 on an electron-activated iron catalytic bed.

Science.gov (United States)

Labrecque, Raynald; Lavoie, Jean-Michel

2011-12-01

A preliminary experimental investigation of dry reforming of methane with carbon dioxide, that has been performed on an iron bed activated with an electric current is reported. Operating conditions for the reaction included temperature ranging from 700 to 800° C and pressure close to 1 atm. The reaction, involving an excess of pure methane and carbon dioxide, was performed with and without addition of water vapour, provided by hot water saturation of the gaseous feed. According to syngas compositions, the electron flow has a dramatic effect on the conversion of both methane and carbon dioxide. It was shown also that hot water saturation of the CO(2) and CH(4) mixture allowed very good conversion, giving a syngas with a composition very close to what was expected from equilibrium calculations. Copyright © 2011 Elsevier Ltd. All rights reserved.

Cosmic ray processing of N2-containing interstellar ice analogues at dark cloud conditions

Science.gov (United States)

Fedoseev, G.; Scirè, C.; Baratta, G. A.; Palumbo, M. E.

2018-04-01

N2 is believed to lock considerable part of nitrogen elemental budget and, therefore, to be one of the most abundant ice constituent in cold dark clouds. This laboratory-based research utilizes high energetic processing of N2 containing interstellar ice analogues using 200 keV H+ and He+ ions that mimics cosmic ray processing of the interstellar icy grains. It aims to investigate the formation of (iso)cyanates and cyanides in the ice mantles at the conditions typical for cold dark clouds and prestellar cores. Investigation of cosmic ray processing as a chemical trigger mechanism is explained by the high stability of N2 molecules that are chemically inert in most of the atom- and radical-addition reactions and cannot be efficiently dissociated by cosmic ray induced UV-field. Two sets of experiments are performed to closer address solid-state chemistry occurring in two distinct layers of the ice formed at different stages of dark cloud evolution, i.e. `H2O-rich' and `CO-rich' ice layers. Formation of HNCO and OCN- is discussed in all of the performed experiments. Corresponding kinetic curves for HNCO and OCN- are obtained. Furthermore, a feature around 2092 cm-1 assigned to the contributions of 13CO, CN-, and HCN is analysed. The kinetic curves for the combined HCN/CN- abundance are derived. In turn, normalized formation yields are evaluated by interpolation of the obtained results to the low irradiation doses relevant to dark cloud stage. The obtained values can be used to interpret future observations towards cold dark clouds using James Webb Space Telescope.

Experiments and geochemical modelling of CO{sub 2} sequestration by olivine: Potential, quantification

Energy Technology Data Exchange (ETDEWEB)

Garcia, B., E-mail: Bruno.Garcia@ifp.fr [Institut Francais du Petrole, 1 et 4 Avenue du Bois Preau, 92852 Rueil Malmaison (France); Beaumont, V.; Perfetti, E.; Rouchon, V.; Blanchet, D. [Institut Francais du Petrole, 1 et 4 Avenue du Bois Preau, 92852 Rueil Malmaison (France); Oger, P.; Dromart, G. [Universite de Lyon, CNRS, UMR 5570, ENS de Lyon, Site Monod, 15 Parvis Rene Descartes BP 7000, Lyon F-69342 (France); Huc, A.-Y.; Haeseler, F. [Institut Francais du Petrole, 1 et 4 Avenue du Bois Preau, 92852 Rueil Malmaison (France)

2010-09-15

Aqueous solutions equilibrated with supercritical CO{sub 2} (150 deg. C and total pressure of 150 bar) were investigated in order to characterize their respective conditions of carbonation. Dissolution of olivine and subsequent precipitation of magnesite with a net consumption of CO{sub 2} were expected. A quantified pure mineral phase (powders with different olivine grain diameter [20-80 {mu}m], [80-125 {mu}m], [125-200 {mu}m] and [>200 {mu}m]), and CO{sub 2} (as dried ice) were placed in closed-batch reactors (soft Au tubes) in the presence of solutions. Different salinities (from 0 to 3400 mM) and different ratios of solution/solid (mineral phase) (from 0.1 to 10) were investigated. Experiments were performed over periods from 2 to 8 weeks. Final solid products were quantified by the Rock-Eval 6 technique, and identified using X-ray diffraction, Raman spectroscopy, electron microprobe and scanning electron microscopy. Gaseous compounds were quantified by a vacuum line equipped with a Toepler pump and identified and measured by gas chromatography (GC). Carbon mass balances were calculated. Olivine reacted completely with CO{sub 2}, trapping up to 57 {+-} 2% (eqC of initial CO{sub 2}) as magnesite; some amorphous silica also formed. Olivine grain diameter and solution/mineral ratios appeared to be the primary controls on the reaction, salinity acting as a second order parameter. During the experiments, fluid analyses may not be performed with approach adopted but, geochemical modelling was attempted to give information about the solution composition. This showed an interesting mineral matrix evolution. Under the experimental conditions, olivine appeared to be a good candidate for CO{sub 2} trapping into a geologically stable carbonate, magnesite. The possible use of mafic and ultramafic rocks for CO{sub 2} sequestration is discussed.

Assessment of the sea-ice carbon pump: Insights from a three-dimensional ocean-sea-ice biogeochemical model (NEMO-LIM-PISCES

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Sébastien Moreau

2016-08-01

Full Text Available Abstract The role of sea ice in the carbon cycle is minimally represented in current Earth System Models (ESMs. Among potentially important flaws, mentioned by several authors and generally overlooked during ESM design, is the link between sea-ice growth and melt and oceanic dissolved inorganic carbon (DIC and total alkalinity (TA. Here we investigate whether this link is indeed an important feature of the marine carbon cycle misrepresented in ESMs. We use an ocean general circulation model (NEMO-LIM-PISCES with sea-ice and marine carbon cycle components, forced by atmospheric reanalyses, adding a first-order representation of DIC and TA storage and release in/from sea ice. Our results suggest that DIC rejection during sea-ice growth releases several hundred Tg C yr−1 to the surface ocean, of which < 2% is exported to depth, leading to a notable but weak redistribution of DIC towards deep polar basins. Active carbon processes (mainly CaCO3 precipitation but also ice-atmosphere CO2 fluxes and net community production increasing the TA/DIC ratio in sea-ice modified ocean-atmosphere CO2 fluxes by a few Tg C yr−1 in the sea-ice zone, with specific hemispheric effects: DIC content of the Arctic basin decreased but DIC content of the Southern Ocean increased. For the global ocean, DIC content increased by 4 Tg C yr−1 or 2 Pg C after 500 years of model run. The simulated numbers are generally small compared to the present-day global ocean annual CO2 sink (2.6 ± 0.5 Pg C yr−1. However, sea-ice carbon processes seem important at regional scales as they act significantly on DIC redistribution within and outside polar basins. The efficiency of carbon export to depth depends on the representation of surface-subsurface exchanges and their relationship with sea ice, and could differ substantially if a higher resolution or different ocean model were used.

THE EFFECT OF BROADBAND SOFT X-RAYS IN SO{sub 2}-CONTAINING ICES: IMPLICATIONS ON THE PHOTOCHEMISTRY OF ICES TOWARD YOUNG STELLAR OBJECTS

Energy Technology Data Exchange (ETDEWEB)

Pilling, S.; Bergantini, A., E-mail: sergiopilling@pq.cnpq.br [Universidade do Vale do Paraíba (UNIVAP), Laboratório de Astroquímica e Astrobiologia (LASA), São José dos Campos, SP (Brazil)

2015-10-01

We investigate the effects produced mainly by broadband soft X-rays up to 2 keV (plus fast (∼keV) photoelectrons and low-energy (∼eV) induced secondary electrons) in the ice mixtures containing H{sub 2}O:CO{sub 2}:NH{sub 3}:SO{sub 2} (10:1:1:1) at two different temperatures (50 and 90 K). The experiments are an attempt to simulate the photochemical processes induced by energetic photons in SO{sub 2}-containing ices present in cold environments in the ices surrounding young stellar objects (YSO) and in molecular clouds in the vicinity of star-forming regions, which are largely illuminated by soft X-rays. The measurements were performed using a high-vacuum portable chamber from the Laboratório de Astroquímica e Astrobiologia (LASA/UNIVAP) coupled to the spherical grating monochromator beamline at the Brazilian Synchrotron Light Source (LNLS) in Campinas, Brazil. In situ analyses were performed by a Fourier transform infrared spectrometer. Sample processing revealed the formation of several organic molecules, including nitriles, acids, and other compounds such as H{sub 2}O{sub 2}, H{sub 3}O{sup +}, SO{sub 3}, CO, and OCN{sup −}. The dissociation cross section of parental species was on the order of (2–7) × 10{sup −18} cm{sup 2}. The ice temperature does not seem to affect the stability of SO{sub 2} in the presence of X-rays. Formation cross sections of new species  produced were also determined. Molecular half-lives at ices toward YSOs due to the presence of incoming soft X-rays were estimated. The low values obtained employing two different models of the radiation field of YSOs (TW Hydra and typical T-Tauri star) reinforce that soft X-rays are indeed a very efficient source of molecular dissociation in such environments.

The Cheshire-cat-like Behavior of 2nu(sub 3) Overtone of Co2 near 2.134 micron: NIR Lab Spectra of Solid CO2 in H2O and CH3OH

Science.gov (United States)

Bernstein, Max; Sandford, Scott; Cruikshank, Dale

2005-01-01

Infrared (IR) spectra have demonstrated that solid H2O is very common in the outer Solar System, and solid carbon dioxide (CO2) has been detected on icy satellites, comets, and planetismals throughout the outer Solar System. In such environments, CO2 and H2O must sometimes be mixed at a molecular level, changing their IR absorption features. In fact, the IR spectra of CO2-H2O mixtures are not equivalent to a linear combination of the spectra of the pure materials. Laboratory IR spectra of pure CO2 and H2O have been published but a lack of near-IR spectra of CO2-H2O mixtures has made the interpretation of outer Solar System spectra more difficult. We present near infrared (IR) spectra of CO2 in H2O and in CH3OH compared to that of pure solid CO2 and find significant differences. Peaks not present in either pure H2O or pure CO2 spectra become evident. First, the CO2 (2nu(sub 3)) overtone near 2.134 micron (4685/ cm) that is not seen in pure solid CO2 is prominent in the spectrum of a CO2/H2O = 25 mixture. Second, a 2.74 micron (3650/ cm) dangling OH feature of water (and a potentially related peak at 1.89 micron) appear in the spectra of CO2-H2O ice mixtures, but may not be specific to the presence of CO2. Other CO2 peaks display shifts in position and increased width because of intermolecular interactions with water. Changes in CO2 peak positions and profiles on warming of a CO2/H2O = 5 mixture are consistent with 'segregation' of the ice into nearly pure separate components. Absolute strengths for absorptions of CO2 in solid H2O are estimated. Similar results are observed for CO2 in solid CH3OH. Since the CO2 ( 2nu(sub 3)) overtone near 2.134 micron (4685/ cm) is not present in pure CO2 but prominent in mixtures it may be a good observational indicator of whether solid CO2 is a pure material or intimately mixed with other molecules. Significant changes in the near IR spectrum of solid CO2 in the presence of H2O and CH3OH means that the abundance of solid CO2 in the

Simulation of an extended surface detector IceVeto for IceCube-Gen2

Energy Technology Data Exchange (ETDEWEB)

Hansmann, Tim; Auffenberg, Jan; Haack, Christian; Hansmann, Bengt; Kemp, Julian; Konietz, Richard; Leuner, Jakob; Raedel, Leif; Stahlberg, Martin; Schoenen, Sebastian; Wiebusch, Christopher [III. Physikalisches Institut B, RWTH Aachen University (Germany); Collaboration: IceCube-Collaboration

2016-07-01

IceCube is a neutrino observatory located at the geographic South Pole. The main backgrounds for IceCube's primary goal, the measurement of astrophysical neutrinos, are muons and neutrinos from cosmic-ray air showers in the Earth's atmosphere. Strong supression of these backgrounds from the Southern hemisphere has been demonstrated by coincident detection of these air showers with the IceTop surface detector. For an extended instrument, IceCube-Gen2, it is considered to build an enlarged surface array, IceVeto, that will improve the detection capabilities of coincident air showers. We will present simulation studies to estimate the IceVeto capabilities to optimize the IceCube-Gen2 design.

Diffusion and infrared properties of molecules in ice mantles

International Nuclear Information System (INIS)

Schmitt, B.; Grim, R.; Greenberg, J.M.

1989-01-01

Within dense molecular clouds the formation of frozen icy mantles on interstellar dust grains is thought to be the result of various growth conditions. The molecules, which make up the ice mantles are probably completely mixed. To study the physical properties of such ice mixtures the experiments were performed on the evaporation processes and on the spectroscopic properties of CO, CO2, and CH4 in water rich ices. The decrease in concentration of volatile molecules in ice samples deposited at 10 K and subsequently heated is found to occur essentially in two steps. The first one, corresponding to an evaporation of part of the volatile molecules, starts at about 25 K for CO, 32 K for CH4, and 70 K for CO2. During the crystallization of H2O ice at temperatures greater than 120 K a second evaporation occurs leading to the complete disappearance of the volatile molecules in the solid phase. The main astrophysical implications of the diffusion and spectroscopic behaviors are presented. The possible effects of a heating source on the fraction of volatile molecules, such as CO trapped in grain mantles, are discussed

Hot Melt Extrusion and Spray Drying of Co-amorphous Indomethacin-Arginine With Polymers

DEFF Research Database (Denmark)

Lenz, Elisabeth; Löbmann, Korbinian; Rades, Thomas

2017-01-01

Co-amorphous drug-amino acid systems have gained growing interest as an alternative to common amorphous formulations which contain polymers as stabilizers. Several preparation methods have recently been investigated, including vibrational ball milling on a laboratory scale or spray drying......, and stability. Results were compared to those of spray-dried formulations with the same compositions and to spray-dried indomethacin-copovidone. Overall, stable co-amorphous systems could be prepared by extrusion without or with copovidone, which exhibited comparable molecular interaction properties...... to the respective spray-dried products, while phase separation was detected by differential scanning calorimetry in several cases. The formulations containing indomethacin in combination with arginine and copovidone showed enhanced dissolution behavior over the formulations with only copovidone or arginine....

Emission and absorption of CO2 during the sea ice formation and melting in the high Arctic

Directory of Open Access Journals (Sweden)

A. P. Nedashkovsky

2012-01-01

Full Text Available The carbonate system of the Arctic sea ice is considered. The observations were conducted in the Nansen Basin at the drifting station North Pole-35 in 2007–2008. It was found that total alkalinity – salinity ratio (TA/S and total inorganic carbon – salinity ratio (TC/S as well as TA/TC ratio in the ice column and seawater column are similar. The deviations from that pattern were observed in the upper thin layer of the young and first-year ice and in the ice snow cap. The TA/TC ratio (equals to ~2 in the ice snow cap was related with the calcium hydrocarbonate decay and CO₂ removal. It was shown that CO₂ removal was due to its emission into the atmosphere. The CO₂ flux was equal to ~0.02 mol/m² for season. The water formed during melting of the first-year ice was significantly under saturated of CO₂ and hence it may be a sink of 0.05 0.07 mol/m² of the atmospheric CO₂ per season.

Martian Gullies: Formation by CO2 Fluidification

Science.gov (United States)

Cedillo-Flores, Y.; Durand-Manterola, H. J.

2006-12-01

Some of the geomorphological features in Mars are the gullies. Some theories developed tried explain its origin, either by liquid water, liquid carbon dioxide or flows of dry granular material. We made a comparative analysis of the Martian gullies with the terrestrial ones. We propose that the mechanism of formation of the gullies is as follows: In winter CO2 snow mixed with sand falls in the terrain. In spring the CO2 snow sublimate and gaseous CO2 make fluid the sand which flows like liquid eroding the terrain and forming the gullies. By experimental work with dry granular material, we simulated the development of the Martian gullies injecting air in the granular material. We present the characteristics of some terrestrial gullies forms at cold environment, sited at Nevado de Toluca Volcano near Toluca City, México. We compare them with Martian gullies choose from four different areas, to target goal recognize or to distinguish, (to identify) possible processes evolved in its formation. Also, we measured the lengths of those Martian gullies and the range was from 24 m to 1775 meters. Finally, we present results of our experimental work at laboratory with dry granular material.

Cutting weeds with a CO2 laser

DEFF Research Database (Denmark)

Heisel, T.; Schou, Jørgen; Christensen, S.

2001-01-01

Stems of Chenopodium album. and Sinapis arvensis. and leaves of Lolium perenne. were cut with a CO2 laser or with a pair of scissors. Treatments were carried out on greenhouse-grown pot plants at three different growth stages and at two heights. Plant dry matter was measured 2 to 5 weeks after...... treatment. The relationship between dry weight and laser energy was analysed using a non-linear dose-response regression model. The regression parameters differed significantly between the weed species. At all growth stages and heights S. arvensis was more difficult to cut with a CO2 laser than C. album....... When stems were cut below the meristems, 0.9 and 2.3 J mm(-1) of CO2 laser energy dose was sufficient to reduce by 90% the biomass of C. album and S. arvensis respectively. Regrowth appeared when dicotyledonous plant stems were cut above meristems, indicating that it is important to cut close...

Improving Heat Transfer at the Bottom of Vials for Consistent Freeze Drying with Unidirectional Structured Ice.

Science.gov (United States)

Rosa, Mónica; Tiago, João M; Singh, Satish K; Geraldes, Vítor; Rodrigues, Miguel A

2016-10-01

The quality of lyophilized products is dependent of the ice structure formed during the freezing step. Herein, we evaluate the importance of the air gap at the bottom of lyophilization vials for consistent nucleation, ice structure, and cake appearance. The bottom of lyophilization vials was modified by attaching a rectified aluminum disc with an adhesive material. Freezing was studied for normal and converted vials, with different volumes of solution, varying initial solution temperature (from 5°C to 20°C) and shelf temperature (from -20°C to -40°C). The impact of the air gap on the overall heat transfer was interpreted with the assistance of a computational fluid dynamics model. Converted vials caused nucleation at the bottom and decreased the nucleation time up to one order of magnitude. The formation of ice crystals unidirectionally structured from bottom to top lead to a honeycomb-structured cake after lyophilization of a solution with 4% mannitol. The primary drying time was reduced by approximately 35%. Converted vials that were frozen radially instead of bottom-up showed similar improvements compared with normal vials but very poor cake quality. Overall, the curvature of the bottom of glass vials presents a considerable threat to consistency by delaying nucleation and causing radial ice growth. Rectifying the vials bottom with an adhesive material revealed to be a relatively simple alternative to overcome this inconsistency.

The roles of convection, extratropical mixing, and in-situ freeze-drying in the Tropical Tropopause Layer

Directory of Open Access Journals (Sweden)

W. G. Read

2008-10-01

Full Text Available Mechanisms for transporting and dehydrating air across the tropical tropopause layer (TTL are investigated with a conceptual two dimensional (2-D model. The 2-D TTL model combines the Holton and Gettelman cold trap dehydration mechanism (Holton and Gettelman, 2001 with the two column convection model of Folkins and Martin (2005. We investigate 3 possible transport scenarios through the TTL: 1 slow uniform ascent across the level of zero radiative heating without direct convective mixing, 2 convective mixing of H₂O vapor at 100% relative humidity with respect to ice (RHi with no ice retention, and 3 convective mixing of extremely subsaturated air (100% RHi following the moist adiabatic temperature above the level of neutral buoyancy with sufficient ice retention such that total H₂O is 100%RHi. The three mechanisms produce similar seasonal cycles for H₂O that are in good quantitative agreement with the Aura Microwave Limb Sounder (MLS measurements. We use Aura MLS measurement of CO and Atmospheric Chemistry Experiment-Fourier Transform Spectrometer measurement of HDO to distinguish among the transport mechanisms. Model comparisons with the observations support the view that H₂O is predominantly controlled by regions having the lowest cold point tropopause temperature but the trace species CO and HDO support the convective mixing of dry air and lofted ice. The model provides some insight into the processes affecting the long term trends observed in stratospheric H₂O.

Vacuum ultraviolet emission spectrum measurement of a microwave-discharge hydrogen-flow lamp in several configurations: Application to photodesorption of CO ice

Energy Technology Data Exchange (ETDEWEB)

Chen, Y.-J.; Wu, C.-Y. R. [Space Sciences Center and Department of Physics and Astronomy, University of Southern California, Los Angeles, CA 90089-1341 (United States); Chuang, K.-J.; Chu, C.-C.; Yih, T.-S. [Department of Physics, National Central University, Jhongli City, Taoyuan County 32054, Taiwan (China); Muñoz Caro, G. M. [Centro de Astrobiología, INTA-CSIC, Torrejón de Ardoz, E-28850 Madrid (Spain); Nuevo, M. [NASA Ames Research Center, Moffett Field, CA 94035 (United States); Ip, W.-H., E-mail: yujung@usc.edu [Graduate Institute of Astronomy, National Central University, Jhongli City, Taoyuan County 32049, Taiwan (China)

2014-01-20

We report measurements of the vacuum ultraviolet (VUV) emission spectra of a microwave-discharge hydrogen-flow lamp (MDHL), a common tool in astrochemistry laboratories working on ice VUV photoprocessing. The MDHL provides hydrogen Ly-α (121.6 nm) and H{sub 2} molecular emission in the 110-180 nm range. We show that the spectral characteristics of the VUV light emitted in this range, in particular the relative proportion of Ly-α to molecular emission bands, strongly depend on the pressure of H{sub 2} inside the lamp, the lamp geometry (F type versus T type), the gas used (pure H{sub 2} versus H{sub 2} seeded in He), and the optical properties of the window used (MgF{sub 2} versus CaF{sub 2}). These different configurations are used to study the VUV irradiation of CO ice at 14 K. In contrast to the majority of studies dedicated to the VUV irradiation of astrophysical ice analogs, which have not taken into consideration the emission spectrum of the MDHL, our results show that the processes induced by photons in CO ice from a broad energy range are different and more complex than the sum of individual processes induced by monochromatic sources spanning the same energy range, as a result of the existence of multistate electronic transitions and discrepancy in absorption cross sections between parent molecules and products in the Ly-α and H{sub 2} molecular emission ranges.

Vacuum ultraviolet emission spectrum measurement of a microwave-discharge hydrogen-flow lamp in several configurations: Application to photodesorption of CO ice

International Nuclear Information System (INIS)

Chen, Y.-J.; Wu, C.-Y. R.; Chuang, K.-J.; Chu, C.-C.; Yih, T.-S.; Muñoz Caro, G. M.; Nuevo, M.; Ip, W.-H.

2014-01-01

We report measurements of the vacuum ultraviolet (VUV) emission spectra of a microwave-discharge hydrogen-flow lamp (MDHL), a common tool in astrochemistry laboratories working on ice VUV photoprocessing. The MDHL provides hydrogen Ly-α (121.6 nm) and H 2 molecular emission in the 110-180 nm range. We show that the spectral characteristics of the VUV light emitted in this range, in particular the relative proportion of Ly-α to molecular emission bands, strongly depend on the pressure of H 2 inside the lamp, the lamp geometry (F type versus T type), the gas used (pure H 2 versus H 2 seeded in He), and the optical properties of the window used (MgF 2 versus CaF 2 ). These different configurations are used to study the VUV irradiation of CO ice at 14 K. In contrast to the majority of studies dedicated to the VUV irradiation of astrophysical ice analogs, which have not taken into consideration the emission spectrum of the MDHL, our results show that the processes induced by photons in CO ice from a broad energy range are different and more complex than the sum of individual processes induced by monochromatic sources spanning the same energy range, as a result of the existence of multistate electronic transitions and discrepancy in absorption cross sections between parent molecules and products in the Ly-α and H 2 molecular emission ranges.

Reduced probability of ice-free summers for 1.5 °C compared to 2 °C warming

Science.gov (United States)

Jahn, Alexandra

2018-05-01

Arctic sea ice has declined rapidly with increasing global temperatures. However, it is largely unknown how Arctic summer sea-ice impacts would vary under the 1.5 °C Paris target compared to scenarios with greater warming. Using the Community Earth System Model, I show that constraining warming to 1.5 °C rather than 2.0 °C reduces the probability of any summer ice-free conditions by 2100 from 100% to 30%. It also reduces the late-century probability of an ice cover below the 2012 record minimum from 98% to 55%. For warming above 2 °C, frequent ice-free conditions can be expected, potentially for several months per year. Although sea-ice loss is generally reversible for decreasing temperatures, sea ice will only recover to current conditions if atmospheric CO2 is reduced below present-day concentrations. Due to model biases, these results provide a lower bound on summer sea-ice impacts, but clearly demonstrate the benefits of constraining warming to 1.5 °C.

Temporal dynamics of ikaite in experimental sea ice

OpenAIRE

S. Rysgaard; F. Wang; R. J. Galley; R. Grimm; D. Notz; M. Lemes; N.-X. Geilfus; A. Chaulk; A. A. Hare; O. Crabeck; B. G. T. Else; K. Campbell; L. L. Sørensen; J. Sievers; T. Papakyriakou

2014-01-01

Ikaite (CaCO3 · 6H2O) is a metastable phase of calcium carbonate that normally forms in a cold environment and/or under high pressure. Recently, ikaite crystals have been found in sea ice, and it has been suggested that their precipitation may play an important role in air–sea CO2 exchange in ice-covered seas. Little is known, however, of the spatial and temporal dynamics of ikaite in sea ice. Here we present evidence for highly dynamic ikaite precipitation and dissolution i...

Lithium-Rich Nanoscale Li _1.2 Mn _0.54 Ni _0.13 Co _0.13 O ₂ Cathode Material Prepared by Co-Precipitation Combined Freeze Drying (CP-FD) for Lithium-Ion Batteries

Energy Technology Data Exchange (ETDEWEB)

Bai, Ying; Li, Yu; Wu, Chuan; Lu, Jun; Li, Hui; Liu, Zhaolin; Zhong, Yunxia; Chen, Shi; Zhang, Cunzhong; Amine, Khalil; Wu, Feng

2015-07-14

Nanoscale Li-rich Li1.2Mn0.54Ni0.13Co0.13O2 material is synthesized by a co-precipitation combined freeze drying (CP-FD) method, and compared with a conventional co-precipitation method combined vacuum drying (CP-VD). With the combination of X-ray diffraction (XRD) and scanning electron microscopy (SEM), it is found that the sample from CP-FD method consists of a pure phase with good crystallinity and small, homogenous particles (100-300 nm) with uniform particle size distribution. Inductively coupled plasma spectroscopy (ICP) shows that the sample has a stoichiometric ratio of n((Li)): n((Mn)): n((Ni)): n((Co))=9: 4: 1: 1; and its Brunauer-Emmett-Teller (BET) specific surface area is 5.749 m(2)g(-1). This sample achieves excellent electrochemical properties: its initial discharge capacities are 298.9 mAhg(-1) at 0.1C (20 mAg(-1)), 246.1 mAhg(-1) at 0.5C, 215.8 mAhg(-1) at 1C, and 154.2 mAhg(-1) at 5C (5C charge and 5C discharge), as well as good cycling performance. In addition, the Li+ chemical diffusion coefficient of Li1.2Mn0.54Ni0.13Co0.13O2 material prepared by the CP-FD method is 4.59 x 10(-11) cm(2) s(-1), which is higher than that of the Li1.2Mn0.54Ni0.13Co0.13O2 material prepared by CP-VD. This phenomenon illustrates the potential for Li1.2Mn0.54Ni0.13Co0.13O2 with good rate performance synthesized by CP-FD method.

Mechanism of Bacillus subtilis spore inactivation by and resistance to supercritical CO2 plus peracetic acid.

Science.gov (United States)

Setlow, B; Korza, G; Blatt, K M S; Fey, J P; Setlow, P

2016-01-01

Determine how supercritical CO2 (scCO2 ) plus peracetic acid (PAA) inactivates Bacillus subtilis spores, factors important in spore resistance to scCO2 -PAA, and if spores inactivated by scCO2 -PAA are truly dead. Spores of wild-type B. subtilis and isogenic mutants lacking spore protective proteins were treated with scCO2 -PAA in liquid or dry at 35°C. Wild-type wet spores (aqueous suspension) were more susceptible than dry spores. Treated spores were examined for viability (and were truly dead), dipicolinic acid (DPA), mutations, permeability to nucleic acid stains, germination under different conditions, energy metabolism and outgrowth. ScCO2 -PAA-inactivated spores retained DPA, and survivors had no notable DNA damage. However, DPA was released from inactivated spores at a normally innocuous temperature (85°C), and colony formation from treated spores was salt sensitive. The inactivated spores germinated but did not outgrow, and these germinated spores had altered plasma membrane permeability and defective energy metabolism. Wet or dry coat-defective spores had increased scCO2 -PAA sensitivity, and dry spores but not wet spores lacking DNA protective proteins were more scCO2 -PAA sensitive. These findings suggest that scCO2 -PAA inactivates spores by damaging spores' inner membrane. The spore coat provided scCO2 -PAA resistance for both wet and dry spores. DNA protective proteins provided scCO2 -PAA resistance only for dry spores. These results provide information on mechanisms of spore inactivation of and resistance to scCO2 -PAA, an agent with increasing use in sterilization applications. © 2015 The Society for Applied Microbiology.

Precision requirements for space-based X(CO2) data

International Nuclear Information System (INIS)

Miller, C.E.; Crisp, D.; Miller, C.E.; Salawitch, J.; Sander, S.P.; Sen, B.; Toon, C.; DeCola, P.L.; Olsen, S.C.; Randerson, J.T.; Michalak, A.M.; Alkhaled, A.; Michalak, A.M.; Rayner, P.; Jacob, D.J.; Suntharalingam, P.; Wofsy, S.C.; Jacob, D.J.; Suntharalingam, P.; Wofsy, S.C.; Jones, D.B.A.; Denning, A.S.; Nicholls, M.E.; O'Brien, D.; Doney, S.C.; Pawson, S.; Pawson, S.; Connor, B.J.; Fung, I.Y.; Tans, P.; Wennberg, P.O.; Yung, Y.L.; Law, R.M.

2007-01-01

Precision requirements are determined for space-based column-averaged CO 2 dry air mole fraction X(CO 2 ) data. These requirements result from an assessment of spatial and temporal gradients in X(CO 2 ), the relationship between X(CO 2 ) precision and surface CO 2 flux uncertainties inferred from inversions of the X(CO 2 ) data, and the effects of X(CO 2 ) biases on the fidelity of CO 2 flux inversions. Observational system simulation experiments and synthesis inversion modeling demonstrate that the Orbiting Carbon Observatory mission design and sampling strategy provide the means to achieve these X(CO 2 ) data precision requirements. (authors)

Possible significance of cubic water-ice, H2O-Ic, in the atmospheric water cycle of Mars

Science.gov (United States)

Gooding, James L.

1988-01-01

The possible formation and potential significance of the cubic ice polymorph on Mars is discussed. When water-ice crystallizes on Earth, the ambient conditions of temperature and pressure result in the formation of the hexagonal ice polymorph; however, on Mars, the much lower termperature and pressures may permit the crystallization of the cubic polymorph. Cubic ice has two properties of possible importance on Mars: it is an excellant nucleator of other volatiles (such as CO2), and it undergoes an exothermic transition to hexagonal ice at temperatures above 170 K. These properties may have significant implications for both martian cloud formation and the development of the seasonal polar caps.

Enrichment of methylated molecules using enhanced-ice-co-amplification at lower denaturation temperature-PCR (E-ice-COLD-PCR) for the sensitive detection of disease-related hypermethylation.

Science.gov (United States)

Mauger, Florence; Kernaleguen, Magali; Lallemand, Céline; Kristensen, Vessela N; Deleuze, Jean-François; Tost, Jörg

2018-05-01

The detection of specific DNA methylation patterns bears great promise as biomarker for personalized management of cancer patients. Co-amplification at lower denaturation temperature-PCR (COLD-PCR) assays are sensitive methods, but have previously only been able to analyze loss of DNA methylation. Enhanced (E)-ice-COLD-PCR reactions starting from 2 ng of bisulfite-converted DNA were developed to analyze methylation patterns in two promoters with locked nucleic acid (LNA) probes blocking amplification of unmethylated CpGs. The enrichment of methylated molecules was compared to quantitative (q)PCR and quantified using serial dilutions. E-ice-COLD-PCR allowed the multiplexed enrichment and quantification of methylated DNA. Assays were validated in primary breast cancer specimens and circulating cell-free DNA from cancer patients. E-ice-COLD-PCR could prove a useful tool in the context of DNA methylation analysis for personalized medicine.

IceProd 2 Usage Experience

Science.gov (United States)

Delventhal, D.; Schultz, D.; Diaz Velez, J. C.

2017-10-01

IceProd is a data processing and management framework developed by the IceCube Neutrino Observatory for processing of Monte Carlo simulations, detector data, and data driven analysis. It runs as a separate layer on top of grid and batch systems. This is accomplished by a set of daemons which process job workflow, maintaining configuration and status information on the job before, during, and after processing. IceProd can also manage complex workflow DAGs across distributed computing grids in order to optimize usage of resources. IceProd has recently been rewritten to increase its scaling capabilities, handle user analysis workflows together with simulation production, and facilitate the integration with 3rd party scheduling tools. IceProd 2, the second generation of IceProd, has been running in production for several months now. We share our experience setting up the system and things we’ve learned along the way.

Temporal dynamics of ikaite in experimental sea ice

DEFF Research Database (Denmark)

Rysgaard, Søren; Wang, F.; Galley, R.J.

2014-01-01

Ikaite (CaCO3·6H2O) is a metastable phase of calcium carbonate that normally forms in a cold environment and/or under high pressure. Recently, ikaite crystals have been found in sea ice, and it has been suggested that their precipitation may play an important role in air–sea CO2 exchange in ice......-covered seas. Little is known, however, of the spatial and temporal dynamics of ikaite in sea ice. Here we present evidence for highly dynamic ikaite precipitation and dissolution in sea ice grown at an outdoor pool of the Sea-ice Environmental Research Facility (SERF) in Manitoba, Canada. During...... the experiment, ikaite precipitated in sea ice when temperatures were below −4 C, creating three distinct zones of ikaite concentrations: (1) a millimeter-to-centimeter-thin surface layer containing frost flowers and brine skim with bulk ikaite concentrations of > 2000 μmol kg−1, (2) an internal layer...

In-operando elucidation of bimetallic CoNi nanoparticles during high-temperature CH 4 /CO 2 reaction

KAUST Repository

Al-Sabban, Bedour E.; Falivene, Laura; Kozlov, Sergey M.; Aguilar Tapia, Antonio; Ould-Chikh, Samy; Hazemann, Jean-Louis; Cavallo, Luigi; Basset, Jean-Marie; Takanabe, Kazuhiro

2017-01-01

Dry reforming of methane (DRM) proceeds via CH4 decomposition to leave surface carbon species, followed by their removal with CO2-derived species. Reactivity tuning for stoichiometric CH4/CO2 reactants was attempted by alloying the non-noble metals

Assessment of the sea-ice carbon pump

DEFF Research Database (Denmark)

Grimm, R.; Notz, D.; Glud, Ronnie N.

2016-01-01

-induced oceanic CO2 uptake ranges from 2 to 14 Tg C yr−1, which is up to 7% of the simulated net CO2 uptake in polar regions, but far less than 1% of the cur-rent global oceanic CO2 uptake. Hence, while we find that the SICP plays a minor role in the modern global carbon cycle, it is of importance......It has been suggested that geochemical processes related to sea-ice growth and melt might be important for the polar carbon cycle via the so called sea-ice carbon pump (SICP). The SICP affects the air-sea CO2 exchange by influencing the composition of dissolved inorganic carbon (DIC) and total...... for the regional carbon cycle at high latitudes....

Rapid changes in surface water carbonate chemistry during Antarctic sea ice melt

Science.gov (United States)

Jones, Elizabeth M.; Bakker, Dorothee C. E.; Venables, Hugh J.; Whitehouse, Michael J.; Korb, Rebecca E.; Watson, Andrew J.

2010-11-01

ABSTRACT The effect of sea ice melt on the carbonate chemistry of surface waters in the Weddell-Scotia Confluence, Southern Ocean, was investigated during January 2008. Contrasting concentrations of dissolved inorganic carbon (DIC), total alkalinity (TA) and the fugacity of carbon dioxide (fCO2) were observed in and around the receding sea ice edge. The precipitation of carbonate minerals such as ikaite (CaCO3.6H2O) in sea ice brine has the net effect of decreasing DIC and TA and increasing the fCO2 in the brine. Deficits in DIC up to 12 +/- 3 μmol kg-1 in the marginal ice zone (MIZ) were consistent with the release of DIC-poor brines to surface waters during sea ice melt. Biological utilization of carbon was the dominant processes and accounted for 41 +/- 1 μmol kg-1 of the summer DIC deficit. The data suggest that the combined effects of biological carbon uptake and the precipitation of carbonates created substantial undersaturation in fCO2 of 95 μatm in the MIZ during summer sea ice melt. Further work is required to improve the understanding of ikaite chemistry in Antarctic sea ice and its importance for the sea ice carbon pump.

Correlation between plant physiology and CO2 removable

Science.gov (United States)

Leman, A. M.; Shamsuri, Mohd Mahathir Suhaimi; Hariri, Azian; Kadir, Aeslina Abdul; Idris, Ahmad Fu'ad; Afandi, Azizi

2017-09-01

Certain plants that are able to live in the building are known as indoor plants. Plants have tolerance with indoor environment in order to survive. Usually these plants are able to improve indoor air quality (IAQ). Absorption of carbon dioxide (CO2) by plants is one of the indicators that plants are still alive during photosynthesis process. The possibility of plants structure (plant physiology) to affect CO2 absorption had been the concerns of former researchers. This research intends to study the significant of plant structure (leaf area, fresh weight, and dry weight) that leads to reducing the concentration of CO2 by seven plant species (Anthurium, Dumb Cane, Golden Pothos, Kadaka Fern, Prayer Plants, Spider Plants, and Syngonium). The data of CO2 reduction by plants has been obtained from previous studies. Based on results show that, the leaf area is the most contributing the significant effect to the plant absorb CO2 compare to fresh weight and dry weight. It can be prove by Pearson Correlation, where only the value of leaf area is more than 0.5 for every four conditions. This study can be conclude that the leaf area is quite plays an important role to the plant treat air from CO2, while concentration of light and CO2 will become catalytic factor for the plants improve their photosynthesis process.

Exploring the MIS M2 glaciation occurring during a warm and high atmospheric CO2 Pliocene background climate

Science.gov (United States)

Tan, Ning; Ramstein, Gilles; Dumas, Christophe; Contoux, Camille; Ladant, Jean-Baptiste; Sepulchre, Pierre; Zhang, Zhongshi; De Schepper, Stijn

2017-08-01

Prior to the Northern Hemisphere glaciation around ∼2.7 Ma, a large global glaciation corresponding to a 20 to 60 m sea-level drop occurred during Marine Isotope Stage (MIS) M2 (3.312-3.264 Ma), interrupted the period of global warmth and high CO2 concentration (350-450 ppmv) of the mid Piacenzian. Unlike the late Quaternary glaciations, the M2 glaciation only lasted 50 kyrs and occurred under uncertain CO2 concentration (220-390 ppmv). The mechanisms causing the onset and termination of the M2 glaciation remain enigmatic, but a recent geological hypothesis suggests that the re-opening and closing of the shallow Central American Seaway (CAS) might have played a key role. In this article, thanks to a series of climate simulations carried out using a fully coupled Atmosphere Ocean General Circulation Model (GCM) and a dynamic ice sheet model, we show that re-opening of the shallow CAS helps precondition the low-latitude oceanic circulation and affects the related northward energy transport, but cannot alone explain the onset of the M2 glaciation. The presence of a shallow open CAS, together with favourable orbital parameters, 220 ppmv of CO2 concentration, and the related vegetation and ice sheet feedback, led to a global ice sheet build-up producing a global sea-level drop in the lowest range of proxy-derived estimates. More importantly, our results show that the simulated closure of the CAS has a negligible impact on the NH ice sheet melt and cannot explain the MIS M2 termination.

ICESat-2, its retrievals of ice sheet elevation change and sea ice freeboard, and potential synergies with CryoSat-2

Science.gov (United States)

Neumann, Thomas; Markus, Thorsten; Smith, Benjamin; Kwok, Ron

2017-04-01

Understanding the causes and magnitudes of changes in the cryosphere remains a priority for Earth science research. Over the past decade, NASA's and ESA's Earth-observing satellites have documented a decrease in both the areal extent and thickness of Arctic sea ice, and an ongoing loss of grounded ice from the Greenland and Antarctic ice sheets. Understanding the pace and mechanisms of these changes requires long-term observations of ice-sheet mass, sea-ice thickness, and sea-ice extent. NASA's ICESat-2 mission is the next-generation space-borne laser altimeter mission and will use three pairs of beams, each pair separated by about 3 km across-track with a pair spacing of 90 m. The spot size is 17 m with an along-track sampling interval of 0.7 m. This measurement concept is a result of the lessons learned from the original ICESat mission. The multi-beam approach is critical for removing the effects of ice sheet surface slope from the elevation change measurements of most interest. For sea ice, the dense spatial sampling (eliminating along-track gaps) and the small footprint size are especially useful for sea surface height measurements in the, often narrow, leads needed for sea ice freeboard and ice thickness retrievals. Currently, algorithms are being developed to calculate ice sheet elevation change and sea ice freeboard from ICESat-2 data. The orbits of ICESat-2 and Cryosat-2 both converge at 88 degrees of latitude, though the orbit altitude differences result in different ground track patterns between the two missions. This presentation will present an overview of algorithm approaches and how ICESat-2 and Cryosat-2 data may augment each other.

Arctic Ocean CO2 uptake: an improved multiyear estimate of the air-sea CO2 flux incorporating chlorophyll a concentrations

Science.gov (United States)

Yasunaka, Sayaka; Siswanto, Eko; Olsen, Are; Hoppema, Mario; Watanabe, Eiji; Fransson, Agneta; Chierici, Melissa; Murata, Akihiko; Lauvset, Siv K.; Wanninkhof, Rik; Takahashi, Taro; Kosugi, Naohiro; Omar, Abdirahman M.; van Heuven, Steven; Mathis, Jeremy T.

2018-03-01

We estimated monthly air-sea CO2 fluxes in the Arctic Ocean and its adjacent seas north of 60° N from 1997 to 2014. This was done by mapping partial pressure of CO2 in the surface water (pCO2w) using a self-organizing map (SOM) technique incorporating chlorophyll a concentration (Chl a), sea surface temperature, sea surface salinity, sea ice concentration, atmospheric CO2 mixing ratio, and geographical position. We applied new algorithms for extracting Chl a from satellite remote sensing reflectance with close examination of uncertainty of the obtained Chl a values. The overall relationship between pCO2w and Chl a was negative, whereas the relationship varied among seasons and regions. The addition of Chl a as a parameter in the SOM process enabled us to improve the estimate of pCO2w, particularly via better representation of its decline in spring, which resulted from biologically mediated pCO2w reduction. As a result of the inclusion of Chl a, the uncertainty in the CO2 flux estimate was reduced, with a net annual Arctic Ocean CO2 uptake of 180 ± 130 Tg C yr-1. Seasonal to interannual variation in the CO2 influx was also calculated.

Comparison of Dry Gas Seasonal Storage with CO2 Storage and Re-Use Potential

OpenAIRE

Killerud, Marie

2013-01-01

To make large-scale CO2 storage economic, many groups have proposed using CO2in EOR projects to create value for CO2 storage. However, CO2 EOR projectsgenerally require a large and variable supply of CO2 and consequently may requiretemporary storage of CO2 in geological formations. In order to store CO2 atoffshore sites as a source for CO2 EOR projects, the CO2 needs to be extractedfrom a storage site to a certain extent. Alternatively, CO2 EOR projects maybe developed alongside saline aquife...

Hot Melt Extrusion and Spray Drying of Co-amorphous Indomethacin-Arginine With Polymers.

Science.gov (United States)

Lenz, Elisabeth; Löbmann, Korbinian; Rades, Thomas; Knop, Klaus; Kleinebudde, Peter

2017-01-01

Co-amorphous drug-amino acid systems have gained growing interest as an alternative to common amorphous formulations which contain polymers as stabilizers. Several preparation methods have recently been investigated, including vibrational ball milling on a laboratory scale or spray drying in a larger scale. In this study, the feasibility of hot melt extrusion for continuous manufacturing of co-amorphous drug-amino acid formulations was examined, challenging the fact that amino acids melt with degradation at high temperatures. Furthermore, the need for an addition of a polymer in this process was evaluated. After a polymer screening via the solvent evaporation method, co-amorphous indomethacin-arginine was prepared by a melting-solvent extrusion process without and with copovidone. The obtained products were characterized with respect to their solid-state properties, non-sink dissolution behavior, and stability. Results were compared to those of spray-dried formulations with the same compositions and to spray-dried indomethacin-copovidone. Overall, stable co-amorphous systems could be prepared by extrusion without or with copovidone, which exhibited comparable molecular interaction properties to the respective spray-dried products, while phase separation was detected by differential scanning calorimetry in several cases. The formulations containing indomethacin in combination with arginine and copovidone showed enhanced dissolution behavior over the formulations with only copovidone or arginine. Copyright © 2016 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

NiCo as catalyst for magnetically induced dry reforming of methane

Science.gov (United States)

Varsano, F.; Bellusci, M.; Provini, A.; Petrecca, M.

2018-03-01

In this paper we report the activation of the dry reforming reaction by induction heating of a NiCo alloy. The catalyst plays a double role, serving both as a promoter for the reforming reaction and producing the heat induced by dissipation of the electromagnetic energy. The elevated temperatures imposed by the reforming reaction suggest the choice of an alloy with a Curie temperature >800°C. In this respect Ni:Co ratio 60:40 was chosen. Alloy active sites for CH4and CO2activation are created by a mechanochemical treatment of the alloy that increases solid-state defects. The catalyst has been successfully tested in a continuous-flow reactor working under atmospheric pressure. Methane conversion and hydrogen production yields have been measured as a function of the applied magnetic field, reactant flow rate and time on stream.

Low impact of dry conditions on the CO2 exchange of a Northern-Norwegian blanket bog

International Nuclear Information System (INIS)

Lund, Magnus; Parmentier, F J W; Bjerke, J W; Tømmervik, H; Drake, B G; Engelsen, O; Hansen, G H; Powell, T L; Silvennoinen, H; Weldon, S; Rasse, D P; Sottocornola, M

2015-01-01

Northern peatlands hold large amounts of organic carbon (C) in their soils and are as such important in a climate change context. Blanket bogs, i.e. nutrient-poor peatlands restricted to maritime climates, may be extra vulnerable to global warming since they require a positive water balance to sustain their moss dominated vegetation and C sink functioning. This study presents a 4.5 year record of land–atmosphere carbon dioxide (CO 2 ) exchange from the Andøya blanket bog in northern Norway. Compared with other peatlands, the Andøya peatland exhibited low flux rates, related to the low productivity of the dominating moss and lichen communities and the maritime settings that attenuated seasonal temperature variations. It was observed that under periods of high vapour pressure deficit, net ecosystem exchange was reduced, which was mainly caused by a decrease in gross primary production. However, no persistent effects of dry conditions on the CO 2 exchange dynamics were observed, indicating that under present conditions and within the range of observed meteorological conditions the Andøya blanket bog retained its C uptake function. Continued monitoring of these ecosystem types is essential in order to detect possible effects of a changing climate. (letter)

Growth of nicotiana in response to atmospheric CO sub 2 enrichment and various light regimes

Energy Technology Data Exchange (ETDEWEB)

Pope, S.; Thomas, J.F. (North Carolina State Univ., Raleigh (USA))

1989-04-01

Nicotiana tabacum NCTG-22, N. tabacum Petite Havana and N. plumbaginifolia were grown in chambers (24 C, 12-h light) under daytime atmospheric CO{sub 2} levels of 340 ppm (ambient) or 1000 ppm (enriched). All 3 types of tobacco grew faster and had open flowers sooner under CO2 enrichment, but patterns of dry weight distribution varied with type of tobacco. In N. plumbaginifolia significant proportions of dry weight were allocated to stems and branches, while in tabacum types, less was allocated to stems and more to leaves and roots. Increases in dry weight due to CO2 enrichment were accompanied by increases in leaf area and thickness. Plants given a far-red low intensity night break exhibited few differences from controls except having thinner leaves under ambient CO2; but under enriched CO2, had greater total dry weight and thicker leaves containing a higher proportion of spongy mesophyll than controls. A 50% reduction in light intensity led to a comparable reduction in dry weight and leaf area across treatments.

Temporal dynamics of ikaite in experimental sea ice

Science.gov (United States)

Rysgaard, S.; Wang, F.; Galley, R. J.; Grimm, R.; Notz, D.; Lemes, M.; Geilfus, N.-X.; Chaulk, A.; Hare, A. A.; Crabeck, O.; Else, B. G. T.; Campbell, K.; Sørensen, L. L.; Sievers, J.; Papakyriakou, T.

2014-08-01

Ikaite (CaCO3 · 6H2O) is a metastable phase of calcium carbonate that normally forms in a cold environment and/or under high pressure. Recently, ikaite crystals have been found in sea ice, and it has been suggested that their precipitation may play an important role in air-sea CO2 exchange in ice-covered seas. Little is known, however, of the spatial and temporal dynamics of ikaite in sea ice. Here we present evidence for highly dynamic ikaite precipitation and dissolution in sea ice grown at an outdoor pool of the Sea-ice Environmental Research Facility (SERF) in Manitoba, Canada. During the experiment, ikaite precipitated in sea ice when temperatures were below -4 °C, creating three distinct zones of ikaite concentrations: (1) a millimeter-to-centimeter-thin surface layer containing frost flowers and brine skim with bulk ikaite concentrations of >2000 μmol kg-1, (2) an internal layer with ikaite concentrations of 200-400 μmol kg-1, and (3) a bottom layer with ikaite concentrations of ikaite crystals to dissolve. Manual removal of the snow cover allowed the sea ice to cool and brine salinities to increase, resulting in rapid ikaite precipitation. The observed ikaite concentrations were on the same order of magnitude as modeled by FREZCHEM, which further supports the notion that ikaite concentration in sea ice increases with decreasing temperature. Thus, varying snow conditions may play a key role in ikaite precipitation and dissolution in sea ice. This could have a major implication for CO2 exchange with the atmosphere and ocean that has not been accounted for previously.

SmaggIce 2.0: Additional Capabilities for Interactive Grid Generation of Iced Airfoils

Science.gov (United States)

Kreeger, Richard E.; Baez, Marivell; Braun, Donald C.; Schilling, Herbert W.; Vickerman, Mary B.

2008-01-01

The Surface Modeling and Grid Generation for Iced Airfoils (SmaggIce) software toolkit has been extended to allow interactive grid generation for multi-element iced airfoils. The essential phases of an icing effects study include geometry preparation, block creation and grid generation. SmaggIce Version 2.0 now includes these main capabilities for both single and multi-element airfoils, plus an improved flow solver interface and a variety of additional tools to enhance the efficiency and accuracy of icing effects studies. An overview of these features is given, especially the new multi-element blocking strategy using the multiple wakes method. Examples are given which illustrate the capabilities of SmaggIce for conducting an icing effects study for both single and multi-element airfoils.

Westerly Winds and the Southern Ocean CO2 Sink Since the Last Glacial-Interglacial Transition

Science.gov (United States)

Hodgson, D. A.; Saunders, K. M.; Roberts, S. J.; Perren, B.; Butz, C.; Sime, L. C.; Davies, S. J.; Grosjean, M.

2017-12-01

The capacity of the Southern Ocean carbon sink is partly controlled by the Southern Hemisphere westerly winds (SHW) and sea ice. These regulate the upwelling of dissolved carbon-rich deep water to Antarctic surface waters, determine the surface area for air-sea gas exchange and therefore modulate the net uptake of atmospheric CO2. Some models have proposed that strengthened SHW will result in a weakening of the Southern Ocean CO2 sink. If these models are correct, then one would expect that reconstructions of changes in SHW intensity on centennial to millennial timescales would show clear links with Antarctic ice core and Southern Ocean marine geological records of atmospheric CO2, temperature and sea ice. Here, we present a 12,300 year reconstruction of past wind strength based on three independent proxies that track the changing inputs of sea salt aerosols and minerogenic particles into lake sediments on sub-Antarctic Macquarie Island. The proxies are consistent in showing that periods of high wind intensity corresponded with the increase in CO2 across the late Last Glacial-Interglacial Transition and in the last 7,000 years, suggesting that the winds have contributed to the long term outgassing of CO2 from the ocean during these periods.

The effects of additional black carbon on the albedo of Arctic sea ice: variation with sea ice type and snow cover

Directory of Open Access Journals (Sweden)

A. A. Marks

2013-07-01

Full Text Available The response of the albedo of bare sea ice and snow-covered sea ice to the addition of black carbon is calculated. Visible light absorption and light-scattering cross-sections are derived for a typical first-year and multi-year sea ice with both "dry" and "wet" snow types. The cross-sections are derived using data from a 1970s field study that recorded both reflectivity and light penetration in Arctic sea ice and snow overlying sea ice. The variation of absorption cross-section over the visible wavelengths suggests black carbon is the dominating light-absorbing impurity. The response of first-year and multi-year sea ice albedo to increasing black carbon, from 1 to 1024 ng g−1, in a top 5 cm layer of a 155 cm-thick sea ice was calculated using a radiative-transfer model. The albedo of the first-year sea ice is more sensitive to additional loadings of black carbon than the multi-year sea ice. An addition of 8 ng g−1 of black carbon causes a decrease to 98.7% of the original albedo for first-year sea ice compared to a decrease to 99.7% for the albedo of multi-year sea ice, at a wavelength of 500 nm. The albedo of sea ice is surprisingly unresponsive to additional black carbon up to 100 ng g−1 . Snow layers on sea ice may mitigate the effects of black carbon in sea ice. Wet and dry snow layers of 0.5, 1, 2, 5 and 10 cm depth were added onto the sea ice surface. The albedo of the snow surface was calculated whilst the black carbon in the underlying sea ice was increased. A layer of snow 0.5 cm thick greatly diminishes the effect of black carbon in sea ice on the surface albedo. The albedo of a 2–5 cm snow layer (less than the e-folding depth of snow is still influenced by the underlying sea ice, but the effect of additional black carbon in the sea ice is masked.

Ultraviolet spectrophotometry of comet Giacobini-Zinner during the ICE encounter. [International Cometary Explorer (ICE)

Science.gov (United States)

Ahearn, Michael F.; Mcfadden, Lucy A.; Feldman, Paul D.; Boehnhardt, Hermann; Rahe, Juergen; Festou, Michael; Brandt, John C.; Maran, Stephen P.; Niedner, Malcom B.; Smith, Andrew M.

1986-01-01

The IUE spectrophotometry of Comet P/Giacobini-Zinner was acquired in support of the International Cometary Explorer (ICE) mission. The abundances (or upper limits) of UV-active species were calculated. During the ICE encounter the H2O production rate was 3 times 10 to the 28th power/sec, + or - 50%, consistent with values derived from the ICE experiments. Comparison of the abundance of CO2(+) ions with the total electron density measured by the plasma electron experiment on ICE indicates a deficiency of ions relative to electrons indicating a population of ions not detected by remote sensing. The absence of detectable Mg(+) rules out this species as a possible ion of M/Q = 24 detected by the Ion Composition Instrument, part of the ICE complement of instruments.

Characterization of Amorphous and Co-Amorphous Simvastatin Formulations Prepared by Spray Drying

DEFF Research Database (Denmark)

Craye, Goedele; Löbmann, Korbinian; Grohganz, Holger

2015-01-01

In this study, spray drying from aqueous solutions, using the surface-active agent sodium lauryl sulfate (SLS) as a solubilizer, was explored as a production method for co-amorphous simvastatin-lysine (SVS-LYS) at 1:1 molar mixtures, which previously have been observed to form a co...

Inorganic carbon dynamics of melt pond-covered first year sea ice in the Canadian Arctic

DEFF Research Database (Denmark)

Geilfus, Nicolas-Xavier; Galley, R.J.; Crabeck, O.

2014-01-01

Melt pond formation is a common feature of the spring and summer Arctic sea ice. However, the role of the melt ponds formation and the impact of the sea ice melt on both the direction and size of CO2 flux between air and sea is still unknown. Here we describe the CO2-carbonate chemistry of melting...... a strong decrease of the total alkalinity (TA), total dissolved inorganic carbon (TCO2) and partial pressure of CO2 (pCO2) within the bulk sea ice and the brine. Later on, melt pond formation affects both the bulk sea ice and the brine system. As melt ponds are formed from melted snow the in situ melt pond...

Modeling Plasma-based CO2 and CH4 Conversion in Mixtures with N2, O2 and H2O: the Bigger Plasma Chemistry Picture

KAUST Repository

Wang, Weizong; Snoeckx, Ramses; Zhang, Xuming; Cha, Min; Bogaerts, Annemie

2018-01-01

performed regarding the single component gases, i.e. CO2 splitting and CH4 reforming, as well as for two component mixtures, i.e. dry reforming of methane (CO2/CH4), partial oxidation of methane (CH4/O2), artificial photosynthesis (CO2/H2O), CO2

Martian Gullies: H2O or CO2 snow?

Science.gov (United States)

Yolanda, C.; Durand-Manterola, H. J.

2007-05-01

The theories proposed to try to explain the origin of the Martian gullies involve either liquid water, liquid carbon dioxide or flows of dry granular material. We propose another processes that can be favorable for the origin of the Martian gullies, with our model by gaseous fluidification of CO2. We propose that on the Martian slopes, CO2 snow and dust transported by winds, are accumulate. During the Martian spring, sublimation of carbonic snow starts because of heat and weigth of the frezze layer, causing that the material mixed its fluidifized and slide downslope by gravity. By experimental work with dry granular material, we simulated the development of the Martian gullies injecting air inside the granular material. We also present the characteristics of some terrestrial gullies forms at cold environment, sited at Nevado de Toluca Volcano near Toluca City, México. We compared them with some Martian gullies, to identify possible processes evolved in its formation. We measured the lengths of those Martian gullies and the range was from 24 meters to 1775 meters. Finally, we present results of our experimental work at laboratory with dry granular material and our field trip to Nevado de Toluca Volcano.

Polyimide hollow fiber membranes for CO2 separation from wet gas mixtures

Directory of Open Access Journals (Sweden)

F. Falbo

2014-12-01

Full Text Available Matrimid®5218 hollow fiber membranes were prepared using the dry-wet spinning process. The transport properties were measured with pure gases (H2, CO2, N2, CH4 and O2 and with a mixture (30% CO2 and 70% N2 in dry and wet conditions at 25 ºC, 50 ºC, 60 ºC and 75 ºC and up to 600 kPa. Interesting values of single gas selectivity up to 60 ºC (between 31 and 28 for CO2/N2 and between 33 and 30 for CO2/CH4 in dry condition were obtained. The separation factor measured for the mixture was 20% lower compared to the single gas selectivity, in the whole temperature range analyzed. In saturation conditions the data showed that water influences the performance of the membranes, inducing a reduction of the permeance of all gases. Moreover, the presence of water caused a decrease of single gas selectivity and separation factor, although not so significant, highlighting the very high water resistance of hollow fiber membrane modules.

Retention of radiolytic CO gas in irradiated pepper grains and irradiation detection of spices and dry grains with the level of stocked CO gas

International Nuclear Information System (INIS)

Furuta, M.; Dohmaru, T.; Katayama, T.; Toratani, H.; Takeda, A.

1995-01-01

The release of radiolytic CO gas from 60Co gamma-irradiated pepper seeds was unexpectedly slower than that of radiolytic H2 gas during a storage period after irradiation. These gases were retained in the grains and could be recovered by pulverization under gaslight condition. Using this procedure, 10-kGy-irradiated pepper grains could be distinguished from nonirradiated samples for more than 2 months by the level of CO and H2 gases. The patterns of CO change at 10, 20, and 30 kGy were similar, and the CO amounts were proportional to irradiation doses at any point of the storage period after irradiation. 60Co gamma-irradiated grains of allspice, cinnamon, cumin, polished rice, and wheat could be distinguished from nonirradiated ones by the level of retained CO gas even after 2 months of storage at room temperature. Thus, radiolytic CO gas could be an effective probe for rapid screening of irradiated pepper and dry grains

Dynamic Ocular Surface and Lacrimal Gland Changes Induced in Experimental Murine Dry Eye

Science.gov (United States)

Xiao, Bing; Wang, Yu; Reinach, Peter S.; Ren, Yueping; Li, Jinyang; Hua, Shanshan; Lu, Huihui; Chen, Wei

2015-01-01

Dry eye disease can be a consequence of lacrimal gland insufficiency in Sjögren’s Syndrome or increased tear film evaporation despite normal lacrimal gland function. To determine if there is a correlation between severity effects in these models and underlying pathophysiological responses, we compared the time dependent changes in each of these parameters that occur during a 6 week period. Dry eye was induced in 6-week-old female C57BL/6 mice by exposing them to an Intelligently Controlled Environmental System (ICES). Sixty mice were housed in ICES for 1, 2, 4 and 6 weeks respectively. Twelve were raised in normal environment and received subcutaneous injections of scopolamine hydrobromide (SCOP) 3 times daily for 5 days. Another sixty mice were housed in a normal environment and received no treatment. Corneal fluorescein staining along with corneal MMP-9 and caspase-3 level measurements were performed in parallel with the TUNEL assay. Interleukin-17(IL-17), IL-23, IL-6, IL-1, TNF-α, IFN-γ and TGF-β2 levels were estimated by real-time PCR measurements of conjunctival and lacrimal gland samples (LGs). Immunohistochemistry of excised LGs along with flow cytometry in cervical lymph nodes evaluated immune cell infiltration. Light and transmission electron microscopy studies evaluated LGs cytoarchitectural changes. ICES induced corneal epithelial destruction and apoptosis peaked at 2 weeks and kept stable in the following 4 weeks. In the ICES group, lacrimal gland proinflammatory cytokine level increases were much lower than those in the SCOP group. In accord with the lower proinflammatory cytokine levels, in the ICES group, lacrimal gland cytosolic vesicular density and size exceeded that in the SCOP group. ICES and SCOP induced murine dry eye effects became progressively more severe over a two week period. Subsequently, the disease process stabilized for the next four weeks. ICES induced local effects in the ocular surface, but failed to elicit lacrimal gland

Dynamic ocular surface and lacrimal gland changes induced in experimental murine dry eye.

Science.gov (United States)

Xiao, Bing; Wang, Yu; Reinach, Peter S; Ren, Yueping; Li, Jinyang; Hua, Shanshan; Lu, Huihui; Chen, Wei

2015-01-01

Dry eye disease can be a consequence of lacrimal gland insufficiency in Sjögren's Syndrome or increased tear film evaporation despite normal lacrimal gland function. To determine if there is a correlation between severity effects in these models and underlying pathophysiological responses, we compared the time dependent changes in each of these parameters that occur during a 6 week period. Dry eye was induced in 6-week-old female C57BL/6 mice by exposing them to an Intelligently Controlled Environmental System (ICES). Sixty mice were housed in ICES for 1, 2, 4 and 6 weeks respectively. Twelve were raised in normal environment and received subcutaneous injections of scopolamine hydrobromide (SCOP) 3 times daily for 5 days. Another sixty mice were housed in a normal environment and received no treatment. Corneal fluorescein staining along with corneal MMP-9 and caspase-3 level measurements were performed in parallel with the TUNEL assay. Interleukin-17(IL-17), IL-23, IL-6, IL-1, TNF-α, IFN-γ and TGF-β2 levels were estimated by real-time PCR measurements of conjunctival and lacrimal gland samples (LGs). Immunohistochemistry of excised LGs along with flow cytometry in cervical lymph nodes evaluated immune cell infiltration. Light and transmission electron microscopy studies evaluated LGs cytoarchitectural changes. ICES induced corneal epithelial destruction and apoptosis peaked at 2 weeks and kept stable in the following 4 weeks. In the ICES group, lacrimal gland proinflammatory cytokine level increases were much lower than those in the SCOP group. In accord with the lower proinflammatory cytokine levels, in the ICES group, lacrimal gland cytosolic vesicular density and size exceeded that in the SCOP group. ICES and SCOP induced murine dry eye effects became progressively more severe over a two week period. Subsequently, the disease process stabilized for the next four weeks. ICES induced local effects in the ocular surface, but failed to elicit lacrimal gland

The influence of ice sheets on temperature during the past 38 million years inferred from a one-dimensional ice sheet–climate model

Directory of Open Access Journals (Sweden)

L. B. Stap

2017-09-01

Full Text Available Since the inception of the Antarctic ice sheet at the Eocene–Oligocene transition (∼ 34 Myr ago, land ice has played a crucial role in Earth's climate. Through feedbacks in the climate system, land ice variability modifies atmospheric temperature changes induced by orbital, topographical, and greenhouse gas variations. Quantification of these feedbacks on long timescales has hitherto scarcely been undertaken. In this study, we use a zonally averaged energy balance climate model bidirectionally coupled to a one-dimensional ice sheet model, capturing the ice–albedo and surface–height–temperature feedbacks. Potentially important transient changes in topographic boundary conditions by tectonics and erosion are not taken into account but are briefly discussed. The relative simplicity of the coupled model allows us to perform integrations over the past 38 Myr in a fully transient fashion using a benthic oxygen isotope record as forcing to inversely simulate CO2. Firstly, we find that the results of the simulations over the past 5 Myr are dependent on whether the model run is started at 5 or 38 Myr ago. This is because the relation between CO2 and temperature is subject to hysteresis. When the climate cools from very high CO2 levels, as in the longer transient 38 Myr run, temperatures in the lower CO2 range of the past 5 Myr are higher than when the climate is initialised at low temperatures. Consequently, the modelled CO2 concentrations depend on the initial state. Taking the realistic warm initialisation into account, we come to a best estimate of CO2, temperature, ice-volume-equivalent sea level, and benthic δ18O over the past 38 Myr. Secondly, we study the influence of ice sheets on the evolution of global temperature and polar amplification by comparing runs with ice sheet–climate interaction switched on and off. By passing only albedo or surface height changes to the climate model, we can distinguish the

A TENTATIVE IDENTIFICATION OF HCN ICE ON TRITON

International Nuclear Information System (INIS)

Burgdorf, M.; Cruikshank, D. P.; Dalle Ore, C. M.; Sekiguchi, T.; Nakamura, R.; Orton, G.; Quirico, E.; Schmitt, B.

2010-01-01

Spectra of Triton between 1.8 and 5.5 μm, obtained in 2007 May and 2009 November, have been analyzed to determine the global surface composition. The spectra were acquired with the grism and the prism of the Infrared Camera on board AKARI with spectral resolutions of 135 and 22, respectively. The data from 4 to 5 μm are shown in this Letter and compared to the spectra of N 2 , CO, and CO 2 , i.e., all the known ices on this moon that have distinct bands in this previously unexplored wavelength range. We report the detection of a 4σ absorption band at 4.76 μm (2101 cm -1 ), which we attribute tentatively to the presence of solid HCN. This is the sixth ice to be identified on Triton and an expected component of its surface because it is a precipitating photochemical product of Triton's thin N 2 and CH 4 atmosphere. It is also formed directly by irradiation of mixtures of N 2 and CH 4 ices. Here we consider only pure HCN, although it might be dissolved in N 2 on the surface of Triton because of the evaporation and recondensation of N 2 over its seasonal cycle. The AKARI spectrum of Triton also covers the wavelengths of the fundamental (1-0) band of β-phase N 2 ice (4.296 μm, 2328 cm -1 ), which has never been detected in an astronomical body before, and whose presence is consistent with the overtone (2-0) band previously reported. Fundamental bands of CO and CO 2 ices are also present.

Chitosan-graphene oxide films and CO2-dried porous aerogel microspheres: Interfacial interplay and stability.

Science.gov (United States)

Frindy, Sana; Primo, Ana; Ennajih, Hamid; El Kacem Qaiss, Abou; Bouhfid, Rachid; Lahcini, Mohamed; Essassi, El Mokhtar; Garcia, Hermenegildo; El Kadib, Abdelkrim

2017-07-01

The intimate interplay of chitosan (CS) and graphene oxide (GO) in aqueous acidic solution has been explored to design upon casting, nanostructured "brick-and-mortar" films (CS-GO-f) and by acidic-to-basic pH inversion, porous CO 2 -dried aerogel microspheres (CS-GO-m). Owing to the presence of oxygenated functional groups in GO, good-quality crack-free hybrid films were obtained. Mechanical properties were improved independently of the GO content and it was found that a 20wt% loading affords hybrid film characterized with a Young modulus three times superior to that reached with the same loading of layered clay. The presence of graphene oxide was found to be detrimental for the thermal stability of the polysaccharide at T <350°C, a fact attributed to the well-established decomposition of the oxygenated functional groups of the graphene sheets. Irrespective to the graphene oxide loading, chitosan-graphene oxide mixture preserves the gelation memory of the polysaccharide. Supercritical drying of the resulting soft hydrogels provides macroporous network with surface areas ranging from 226m 2 g -1 to 554m 2 g -1 . XPS and RAMAN analyses evidenced the selective reduction of GO sheets inside of these microspheres, affording the hitherto unknown macroporous chitosan-entangled-reduced graphene oxide (CS-rGO-m) aerogels. Improvement in both hydrothermal stability (under water reflux) and chemical stability (under acidic conditions) have been noticed for chitosan-graphene oxide microspheres with respect to non-modified chitosan and chitosan-clay bio-hybrids, a result rooted in the substantial hydrophobic character imparted by the addition of graphenic material to the polysaccharide skeleton. In essence, this contribution demonstrates that graphene oxide loading do not disturb neither the filmogenicity of chitosan nor its gelation ability and constitutes a promising route for novel chitosan-based functional hybrid materials. Copyright © 2017 Elsevier Ltd. All rights

Spatial and temporal variability of seawater pCO2 within the Canadian Arctic Archipelago and Baffin Bay during the summer and autumn 2011

Science.gov (United States)

Geilfus, N.-X.; Pind, M. L.; Else, B. G. T.; Galley, R. J.; Miller, L. A.; Thomas, H.; Gosselin, M.; Rysgaard, S.; Wang, F.; Papakyriakou, T. N.

2018-03-01

The partial pressure of CO2 in surface water (pCO2sw) measured within the Canadian Arctic Archipelago (CAA) and Baffin Bay was highly variable with values ranging from strongly undersaturated (118 μatm) to slightly supersaturated (419 μatm) with respect to the atmospheric levels ( 386 μatm) during summer and autumn 2011. During summer, melting sea ice contributed to cold and fresh surface water and enhanced the ice-edge bloom, resulting in strong pCO2sw undersaturation. Coronation Gulf was the only area with supersaturated pCO2sw, likely due to warm CO2-enriched freshwater input from the Coppermine River. During autumn, the entire CAA (including Coronation Gulf) was undersaturated, despite generally increasing pCO2sw. Coronation Gulf was the one place where pCO2sw decreased, likely due to seasonal reduction in discharge from the Coppermine River and the decreasing sea surface temperature. The seasonal summer-to-autumn increase in pCO2sw across the archipelago is attributed in part to the continuous uptake of atmospheric CO2 through both summer and autumn and to the seasonal deepening of the surface mixed layer, bringing CO2-rich waters to the surface. These observations demonstrate how freshwater from sea ice melt and rivers affect pCO2sw differently. The general pCO2sw undersaturation during summer-autumn 2011 throughout the CAA and Baffin Bay give an estimated net oceanic sink for atmospheric CO2 over the study period of 11.4 mmol CO2 m-2 d-1, assuming no sea-air CO2 flux exchange across the sea-ice covered areas.

MECHANISTICAL STUDIES ON THE PRODUCTION OF FORMAMIDE (H2NCHO) WITHIN INTERSTELLAR ICE ANALOGS

International Nuclear Information System (INIS)

Jones, Brant M.; Bennett, Christopher J.; Kaiser, Ralf I.

2011-01-01

Formamide, H 2 NCHO, represents the simplest molecule containing the peptide bond. Consequently, the formamide molecule is of high interest as it is considered an important precursor in the abiotic synthesis of amino acids, and thus significant to further prebiotic chemistry, in more suitable environments. Previous experiments have demonstrated that formamide is formed under extreme conditions similar throughout the interstellar medium via photolysis and the energetic processing of ultracold interstellar and solar system ices with high-energy protons; however, no clear reaction mechanism has been identified. Utilizing a laboratory apparatus capable of simulating the effects of galactic cosmic radiation on ultralow temperature ice mixtures, we have examined the formation of formamide starting from a variety of carbon monoxide (CO) to ammonia (NH 3 ) ices of varying composition. Our results suggest that the primary reaction step leading to the production of formamide in low-temperature ices involves the cleavage of the nitrogen-hydrogen bond of ammonia forming the amino radical (NH 2 ) and atomic hydrogen (H), the latter of which containing excess kinetic energy. These suprathermal hydrogen atoms can then add to the carbon-oxygen triple bond of the carbon monoxide (CO) molecule, overcoming the entrance barrier, and ultimately producing the formyl radical (HCO). From here, the formyl radical may combine without an entrance barrier with the neighboring amino radical if the proper geometry for these two species exists within the matrix cage.

A field study of the geomorphic effects of sublimating CO2 blocks on dune slopes at Coral Pink Dunes, Utah.

Science.gov (United States)

Bourke, Mary; Nield, Jo; Diniega, Serina; Hansen, Candy; McElwaine, Jim

2016-04-01

The seasonal sublimation of CO2 ice is an active driver of present-day surface change on Mars. Diniega et al (2013) proposed that a discrete type of Martian gully, found on southern hemisphere dunes, were formed by the movement of CO2 seasonal ice blocks. These 'Linear Gullies' consist primarily of long (100 m - 2.5 km) grooves with near-uniform width (few-10 m wide), and typical depth of nudge it moved downslope. The dynamics of the block movement were recorded using a pair of high resolution video cameras. Geomorphological observations were noted and topographic change was quantified using a Leica P20 terrestrial laser scanner with a resolution of 0.8 mm at 10 m, and change detection limits less than 3 mm. The block run was repeated a total of 10 times and launched from the same location at the dune brink. The experiment ran for 45 minutes. The block size was reduced to (45 x 190 x 195 mm) by the end of the run series. The resultant geomorphology shows that the separate block runs occupied different tracks leading to a triangular plan form shape with a maximum width of 3.5 m. This is different from the findings in Arizona where a narrower track span was recorded (1.7m) (Bourke et al, 2016). Similar block dynamics were observed at both sites (as blocks moved straight, swiveled and bounced downslope). Distinctive pits with arcuate rims on their downslope edge were formed where blocks bounced on the surface. These pits are at an almost equidistant spacing. Despite a longer slope (16 m as opposed to 8m at Grand Falls), no depositional apron was formed. Levee development was less consistent compared to the Arizona site, but a pronounced unpaired-levee formed towards the base of the lee slope. These data show that sublimating blocks of CO2 ice leave signatures of transport paths and are capable of eroding and transporting sediment. Diniega,S. et al (2013) A new dry hypothesis for the formation of Martian linear gullies. Icarus. Vol. 225, 1, p. 526-537. Bourke, M.C. et

CARBON TRACE GASES IN LAKE AND BEAVER POND ICE NEAR THOMPSON, MANITOBA, CANADA

Science.gov (United States)

Concentrations of CO2, CO, and CH4 were measured in beaver pond and lake ice in April 1996 near Thompson, Manitoba to derive information on possible impacts of ice melting on corresponding atmospheric trace gas concentrations. CH4 concentrations in beaver pond and lake ice ranged...

Evaluation of CO2-based cold sterilization of a model hydrogel.

Science.gov (United States)

Jiménez, A; Zhang, J; Matthews, M A

2008-12-15

The purpose of the present work is to evaluate a novel CO(2)-based cold sterilization process in terms of both its killing efficiency and its effects on the physical properties of a model hydrogel, poly(acrylic acid-co-acrylamide) potassium salt. Suspensions of Staphylococcus aureus and Escherichia coli were prepared for hydration and inoculation of the gel. The hydrogels were treated with supercritical CO(2) (40 degrees C, 27.6 MPa). The amount of bacteria was quantified before and after treatment. With pure CO(2), complete killing of S. aureus and E. coli was achieved for treatment times as low as 60 min. After treatment with CO(2) plus trace amounts of H(2)O(2) at the same experimental conditions, complete bacteria kill was also achieved. For times less than 30 min, incomplete kill was noted. Several physical properties of the gel were evaluated before and after SC-CO(2) treatment. These were largely unaffected by the CO(2) process. Drying curves showed no significant change between treated (pure CO(2) and CO(2) plus 30% H(2)O(2)) and untreated samples. The average equilibrium swelling ratios were also very similar. No changes in the dry hydrogel particle structure were evident from SEM micrographs.

Effect of land albedo, CO2, orography, and oceanic heat transport on extreme climates

Directory of Open Access Journals (Sweden)

V. Romanova

2006-01-01

Full Text Available Using an atmospheric general circulation model of intermediate complexity coupled to a sea ice – slab ocean model, we perform a number of sensitivity experiments under present-day orbital conditions and geographical distribution to assess the possibility that land albedo, atmospheric CO2, orography and oceanic heat transport may cause an ice-covered Earth. Changing only one boundary or initial condition, the model produces solutions with at least some ice-free oceans in the low latitudes. Using some combination of these forcing parameters, a full Earth's glaciation is obtained. We find that the most significant factor leading to an ice-covered Earth is the high land albedo in combination with initial temperatures set equal to the freezing point. Oceanic heat transport and orography play only a minor role for the climate state. Extremely low concentrations of CO2 also appear to be insufficient to provoke a runaway ice-albedo feedback, but the strong deviations in surface air temperatures in the Northern Hemisphere point to the existence of a strong nonlinearity in the system. Finally, we argue that the initial condition determines whether the system can go into a completely ice covered state, indicating multiple equilibria, a feature known from simple energy balance models.

Remarkable separability of the circulation response to Arctic sea ice loss and greenhouse gas forcing

Science.gov (United States)

McCusker, K. E.; Kushner, P. J.; Fyfe, J. C.; Sigmond, M.; Kharin, V. V.; Bitz, C. M.

2017-12-01

Arctic sea ice loss has an important effect on local climate through increases in ocean to atmosphere heat flux and associated feedbacks, and may influence midlatitude climate by changing large-scale circulation that can enhance or counter changes that are due to greenhouse gases. The extent to which climate change in a warming world can be understood as greenhouse gas-induced changes that are modulated by Arctic sea ice loss depends on how additive the responses to the separate influences are. Here we use a novel sea ice nudging methodology in the Canadian Earth System Model, which has a fully coupled ocean, to isolate the effects of Arctic sea ice loss and doubled atmospheric carbon dioxide (CO2) to determine their additivity and sensitivity to mean state. We find that the separate effects of Arctic sea ice loss and doubled CO2 are remarkably additive and relatively insensitive to mean climate state. This separability is evident in several thermodynamic and dynamic fields throughout most of the year, from hemispheric to synoptic scales. The extent to which the regional response to sea ice loss sometimes agrees with and sometimes cancels the response to CO2 is quantified. In this model, Arctic sea ice loss enhances the CO2-induced surface air temperature changes nearly everywhere and zonal wind changes over the Pacific sector, whereas sea ice loss counters CO2-induced sea level pressure changes nearly everywhere over land and zonal wind changes over the Atlantic sector. This separability of the response to Arctic sea ice loss from the response to CO2 doubling gives credence to the body of work in which Arctic sea ice loss is isolated from the forcing that modified it, and might provide a means to better interpret the diverse array of modeling and observational studies of Arctic change and influence.

Younger Dryas cooling and the Greenland climate response to CO2.

Science.gov (United States)

Liu, Zhengyu; Carlson, Anders E; He, Feng; Brady, Esther C; Otto-Bliesner, Bette L; Briegleb, Bruce P; Wehrenberg, Mark; Clark, Peter U; Wu, Shu; Cheng, Jun; Zhang, Jiaxu; Noone, David; Zhu, Jiang

2012-07-10

Greenland ice-core δ(18)O-temperature reconstructions suggest a dramatic cooling during the Younger Dryas (YD; 12.9-11.7 ka), with temperatures being as cold as the earlier Oldest Dryas (OD; 18.0-14.6 ka) despite an approximately 50 ppm rise in atmospheric CO(2). Such YD cooling implies a muted Greenland climate response to atmospheric CO(2), contrary to physical predictions of an enhanced high-latitude response to future increases in CO(2). Here we show that North Atlantic sea surface temperature reconstructions as well as transient climate model simulations suggest that the YD over Greenland should be substantially warmer than the OD by approximately 5 °C in response to increased atmospheric CO(2). Additional experiments with an isotope-enabled model suggest that the apparent YD temperature reconstruction derived from the ice-core δ(18)O record is likely an artifact of an altered temperature-δ(18)O relationship due to changing deglacial atmospheric circulation. Our results thus suggest that Greenland climate was warmer during the YD relative to the OD in response to rising atmospheric CO(2), consistent with sea surface temperature reconstructions and physical predictions, and has a sensitivity approximately twice that found in climate models for current climate due to an enhanced albedo feedback during the last deglaciation.