WorldWideScience

Sample records for clean fuel from coal process

  1. Design Fuels Corporation (DFC)-Apache, Inc. coal reclamation system for the plant of the future for processing clean coal

    International Nuclear Information System (INIS)

    The mechanical washing processing and drying portion of the DFC process offers an efficient method for cleaning of pyritic sulfur bearing compounds which represents 25% sulfur reduction from original run-of-mine coal quality. This reduction can be augmented with the use of calcium and sodium based compounds to reduce the sulfur in many coals to produce compliance quality coal. The use of mechanical/physical methods for the removal of the pyritic material found in coal is used by the DFC process as a first step to the final application of a complete coal refuse clean-up technology based on site specific conditions of the parent coal. The paper discusses the use of the DFC process to remediate slurry ponds and tailings piles and to improve coal cleaning by gravity separation methods, flotation, hydrocyclones and spiral separators, dense media separation, water only cyclones, and oil/solvent agglomeration. A typical DFC Project is the Rosa Coal Reclamation Project which involves the development of a bituminous coal waste impoundment reclamation and washery system. The plant would be located adjacent to a coal fines pond or tailings pond and refuse pile or gob pile at a former coal strip mine in Oneonta, Alabama. Design Fuels would provide a development program by which coal waste at the Rosa Mine could be reclaimed, cleaned and sold profitably. This feedstock could be furnished from recovered coal for direct use in blast furnaces, or as feedstock for coke ovens at 250,000 tons per year at an attractive price on a 10-year contract basis. The site has an old coal washing facility on the property that will be dismantled. Some equipment salvage has been considered; and removal of the existing plant would be the responsibility of Design Fuels. The paper briefly discusses the market potential of the process

  2. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    Energy Technology Data Exchange (ETDEWEB)

    Smit, F.J.; Jha, M.C.; Phillips, D.I.; Yoon, R.H.

    1997-04-25

    The goal of this project is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Its scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design and construction of a 2 t/h process development unit (PDU). Large lots of clean coal are to be produced in the PDU from three project coals. Investigation of the near-term applicability of the two advanced fine coal cleaning processes in an existing coal preparation plant is another goal of the project and is the subject of this report.

  3. Recent Advances in Precombustion Coal Cleaning Processes

    Institute of Scientific and Technical Information of China (English)

    Shiao-HungChiang; DaxinHe

    1994-01-01

    The mineral matter in coal constitutes a major impediment to the direct use of coal in power plants.A concerted effort has been mounted to reduce the ash/sulfur contents in product coal to meet the ever more stringent environmental regulations.In recent years,significant advances have taken place in fine coal cleaning technologies.A review of recent developments in aveanced physical,chemical and biological processes for deep-cleaning of fine coal is presented.

  4. Clean fuels from biomass

    Science.gov (United States)

    Hsu, Y.-Y.

    1976-01-01

    The paper discusses the U.S. resources to provide fuels from agricultural products, the present status of conversion technology of clean fuels from biomass, and a system study directed to determine the energy budget, and environmental and socioeconomic impacts. Conversion processes are discussed relative to pyrolysis and anaerobic fermentation. Pyrolysis breaks the cellulose molecules to smaller molecules under high temperature in the absence of oxygen, wheras anaerobic fermentation is used to convert biomass to methane by means of bacteria. Cost optimization and energy utilization are also discussed.

  5. CFBC evaluation of fuels processed from Illinois coals. Technical report, March 1, 1992--May 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Rajan, S. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mechanical Engineering and Energy Processes

    1992-10-01

    The combustion and emissions properties of (a) flotation slurry fuel beneficiated from coal fines at various stages of the cleaning process and (b) coal-sorbent pellets made from the flotation concentrate of the same beneficiation process using corn starch as binder is being investigated in a 4-inch internal diameter circulating fluidized bed combustor (CFBC). Combustion data such as SO{sub 2}, NO{sub x} emissions, combustion efficiency and ash mineral matter analyses from these fuels are compared with similar parameters from a reference coal burnt in the same fluidized bed combustor. In the last quarter, the CFBC was brought on line and tests were performed on standard coal No. 3 from the Illinois Basin Coal Sample Program (IBCSP). During this quarter, it was decided, that a more meaningful comparison could be obtained if, instead of using the IBCSP No. 3 coal as a standard, the run-of-mine Illinois No. 5 coal from the Kerr-McGee Galatia plant could be used as the reference coal for purposes of comparing the combustion and emissions performance, since the slurry and pellet fuels mentioned in (a) and (b) above were processed from fines recovered form this same Illinois No. 5 seam coal. Accordingly, run-of-the mine Illinois No. 5 coal from the Galatia plant were obtained, riffled and sieved to {minus}14+18 size for the combustion tests. Preliminary combustion tests have been made in the CFBC with this new coal. In preparation for the slurry tests, the moisture content of the beneficiated slurry samples was determined. Proximate and ultimate analyses of all the coal samples were performed. Using a Leeds and Northrup Model 7995-10 Microtrek particle size analyzer, the size distributions of the coal in the three slurry samples were determined. The mineral matter content of the coal in the three slurry samples and the Illinois No. 5 seam coal were investigated using energy dispersive x-ray analysis.

  6. Fuel production from coal by the Mobil Oil process using nuclear high-temperature process heat

    International Nuclear Information System (INIS)

    Two processes for the production of liquid hydrocarbons are presented: Direct conversion of coal into fuel (coal hydrogenation) and indirect conversion of coal into fuel (syngas production, methanol synthesis, Mobil Oil process). Both processes have several variants in which nuclear process heat may be used; in most cases, the nuclear heat is introduced in the gas production stage. The following gas production processes are compared: LURGI coal gasification process; steam reformer methanation, with and without coal hydrogasification and steam gasification of coal. (orig./EF)

  7. Application of microorganisms in coal cleaning processes

    International Nuclear Information System (INIS)

    A secure energy supply is one of the basic pre-requisites for a sound economic system, sustained standard and quality of life and eventually for the social well-being of each individual. For a progressive country like Pakistan, it is obligatory that all energy options must be pursued vigorously including coal utilization, which given the relatively large resources available, is considered to be one of the major options for the next few hundred years. Bioprocessing of coal in an emerging technology which has started to receive considerable research attention. Recent research activities involving coal cleaning, direct coal conversion, and indirect conversion of coal-derived materials have generated a plethora of facts regarding biochemistry, chemistry, and thermodynamic behavior of coal, in that its bioprocessing is on the verge of becoming and acceptable means to great coals. In this research report, investigations pertaining to the various aspects of coal bio processing, including desulfurization and depyritization are discussed. Bituminous coals varying in total sulfur contents of 3-6% were depyritized more than 90% by mesophilic acidophiles like Thiobacillus ferroxidans and Thiobacillus thio oxidans and thermophilic Sulfolobus brierleyi. The archaebacterium, Sulfolobus brierleyi was found to desulfurize inorganic and organic sulfur components of the coal. Conditions were established under which it can remove more than 30% of the organic sulfur present in the coals. Heterotrophic microorganisms including oxenic and soil isolates were also employed for studying sulfurization. A soil isolate, Oil-2, was found to remove more than 70% dibenzothiophenic sulfur present in an oil-water emulsion (1:20 ratio). Pseudomonas putida and the bacterium oil-2 also remove 60-70% organic sulfur present in the shale-oil. Preliminary results indicate the presence of putatively known Kodama's pathway in the oil-2. The mass balance for sulfate indicated the possibility of the presence

  8. Comprehensive Report to Congress Clean Coal Technology Program: Clean power from integrated coal/ore reduction

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    This report describes a clean coal program in which an iron making technology is paired with combined cycle power generation to produce 3300 tons per day of hot metal and 195 MWe of electricity. The COREX technology consists of a metal-pyrolyzer connected to a reduction shaft, in which the reducing gas comes directly from coal pyrolysis. The offgas is utilized to fuel a combined cycle power plant.

  9. COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.; Merriam, N.W.

    1994-10-01

    Western Research Institute (WRI) is developing a process to produce a stable, clean-burning, premium fuel from Powder River Basin (PRB) coal and other low-rank coals. This process is designed to overcome the problems of spontaneous combustion, dust formation, and readsorption of moisture that are experienced with PRB coal and with processed PRB coal. This process, called COMPCOAL{trademark}, results in high-Btu product that is intended for burning in boilers designed for midwestern coals or for blending with other coals. In the COMPCOAL process, sized coal is dried to zero moisture content and additional oxygen is removed from the coal by partial decarboxylation as the coal is contacted by a stream of hot fluidizing gas in the dryer. The hot, dried coal particles flow into the pyrolyzer where they are contacted by a very small flow of air. The oxygen in the air reacts with active sites on the surface of the coal particles causing the temperature of the coal to be raised to about 700{degrees}F (371{degrees}C) and oxidizing the most reactive sites on the particles. This ``instant aging`` contributes to the stability of the product while only reducing the heating value of the product by about 50 Btu/lb. Less than 1 scf of air per pound of dried coal is used to avoid removing any of the condensible liquid or vapors from the coal particles. The pyrolyzed coal particles are mixed with fines from the dryer cyclone and dust filter and the resulting mixture at about 600{degrees}F (316{degrees}C) is fed into a briquettor. Briquettes are cooled to about 250{degrees}F (121{degrees}C) by contact with a mist of water in a gas-tight mixing conveyor. The cooled briquettes are transferred to a storage bin where they are accumulated for shipment.

  10. Clean Processing and Utilization of Coal Energy

    Institute of Scientific and Technical Information of China (English)

    陈如清; 王海峰

    2006-01-01

    The dominant status of coal on the energy production and consumption structure of China will not be changed in the middle period of this century. To realize highly efficient utilization of coal, low pollution and low cost are great and impendent tasks. These difficult problems can be almost resolved through establishing large-scale pithead power stations using two-stage highly efficient dry coal-cleaning system before coal burning, which is a highly efficient, clean and economical strategy considering the current energy and environmental status of China. All these will be discussed in detail in this paper.

  11. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    International Nuclear Information System (INIS)

    Amax R ampersand D, Golden, Colorado by Entech Global for process evaluation tests. The tests successfully demonstrated the capability of advanced column flotation as well as selective agglomeration to produce ultra-clean coal at specified levels of purity and recovery efficiency. Test results and the experience gained during the operation of the PDU have provided valuable insights into the processes studied. Based on the design data obtained from the test work and a set of project design criteria, two sets of conceptual designs for commercial CWF production plants have been developed, one using column flotation and the other using selective agglomeration process. Using these designs, Capital as well as Operating and Maintenance (O ampersand M) cost estimates for the plants have been compiled. These estimates have then been used to derive the annualized cost of production of premium CWF on a commercial scale. Further, a series of sensitivity analysis have been completed to evaluate the effects of variations in selected cost components and process parameters on the overall economics of premium fuel production

  12. Process development studies on recovery of clean coal from ultra fine hardcoal tailings using enhanced gravity separator

    Energy Technology Data Exchange (ETDEWEB)

    Ozgen, S.; Turksoy, V.O.; Sabah, E.; Oruc, F. [Afyon Kocatepe Univ., Afyonkarahisar (Turkey). Dept. of Mining Engineering

    2009-10-15

    Gravity-based processing methods were used to process and recover clean coal from ultra-fine hardcoal tailings at a site in Turkey. The coal samples were analyzed using X-ray diffraction and X-ray fluorescence. A hydrocyclone was used to conduct classification tests and to separate the clay minerals from the coal. The effects of various operating parameters were also investigated. Regression analysis was used to characterize the relationship between the ash content and coal recovery rate and the feed solid, inlet pressure, diameter of vortex, and diameter of apex variables of the hydrocyclone. The effects of feed pressure were also investigated. The study showed that coal can be economically recovered from hardcoal tailings containing clay minerals. It was concluded that a coal sample with 6.98 per cent ash content and a net calorific value of 28,778 kJ was obtained with a weight recovery of 61.73 per cent. 25 refs., 8 tabs., 18 figs.

  13. Evaluation of Ultra Clean Fuels from Natural Gas

    Energy Technology Data Exchange (ETDEWEB)

    Robert Abbott; Edward Casey; Etop Esen; Douglas Smith; Bruce Burke; Binh Nguyen; Samuel Tam; Paul Worhach; Mahabubul Alam; Juhun Song; James Szybist; Ragini Acharya; Vince Zello; David Morris; Patrick Flynn; Stephen Kirby; Krishan Bhatia; Jeff Gonder; Yun Wang; Wenpeng Liu; Hua Meng; Subramani Velu; Jian-Ping Shen, Weidong Gu; Elise Bickford; Chunshan Song; Chao-Yang Wang; Andre' Boehman

    2006-02-28

    ConocoPhillips, in conjunction with Nexant Inc., Penn State University, and Cummins Engine Co., joined with the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) in a cooperative agreement to perform a comprehensive study of new ultra clean fuels (UCFs) produced from remote sources of natural gas. The project study consists of three primary tasks: an environmental Life Cycle Assessment (LCA), a Market Study, and a series of Engine Tests to evaluate the potential markets for Ultra Clean Fuels. The overall objective of DOE's Ultra Clean Transportation Fuels Initiative is to develop and deploy technologies that will produce ultra-clean burning transportation fuels for the 21st century from both petroleum and non-petroleum resources. These fuels will: (1) Enable vehicles to comply with future emission requirements; (2) Be compatible with the existing liquid fuels infrastructure; (3) Enable vehicle efficiencies to be significantly increased, with concomitantly reduced CO{sub 2} emissions; (4) Be obtainable from a fossil resource, alone or in combination with other hydrocarbon materials such as refinery wastes, municipal wastes, biomass, and coal; and (5) Be competitive with current petroleum fuels. The objectives of the ConocoPhillips Ultra Clean Fuels Project are to perform a comprehensive life cycle analysis and to conduct a market study on ultra clean fuels of commercial interest produced from natural gas, and, in addition, perform engine tests for Fisher-Tropsch diesel and methanol in neat, blended or special formulations to obtain data on emissions. This resulting data will be used to optimize fuel compositions and engine operation in order to minimize the release of atmospheric pollutants resulting from the fuel combustion. Development and testing of both direct and indirect methanol fuel cells was to be conducted and the optimum properties of a suitable fuel-grade methanol was to be defined. The results of the study are also

  14. Clean and Secure Energy from Coal

    Energy Technology Data Exchange (ETDEWEB)

    Smith, Philip; Davies, Lincoln; Kelly, Kerry; Lighty, JoAnn; Reitze, Arnold; Silcox, Geoffrey; Uchitel, Kirsten; Wendt, Jost; Whitty, Kevin

    2014-08-31

    The University of Utah, through their Institute for Clean and Secure Energy (ICSE), performed research to utilize the vast energy stored in our domestic coal resources and to do so in a manner that will capture CO2 from combustion from stationary power generation. The research was organized around the theme of validation and uncertainty quantification (V/UQ) through tightly coupled simulation and experimental designs and through the integration of legal, environment, economics and policy issues. The project included the following tasks: • Oxy-Coal Combustion – To ultimately produce predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. • High-Pressure, Entrained-Flow Coal Gasification – To ultimately provide a simulation tool for industrial entrained-flow integrated gasification combined cycle (IGCC) gasifier with quantified uncertainty. • Chemical Looping Combustion (CLC) – To develop a new carbon-capture technology for coal through CLC and to transfer this technology to industry through a numerical simulation tool with quantified uncertainty bounds. • Underground Coal Thermal Treatment – To explore the potential for creating new in-situ technologies for production of synthetic natural gas (SNG) from deep coal deposits and to demonstrate this in a new laboratory-scale reactor. • Mercury Control – To understand the effect of oxy-firing on the fate of mercury. • Environmental, Legal, and Policy Issues – To address the legal and policy issues associated with carbon management strategies in order to assess the appropriate role of these technologies in our evolving national energy portfolio. • Validation/Uncertainty Quantification for Large Eddy Simulations of the Heat Flux in the Tangentially Fired Oxy-Coal Alstom Boiler Simulation Facility – To produce predictive capability with quantified uncertainty bounds for the heat flux in commercial-scale, tangentially fired, oxy-coal boilers.

  15. Coal-water fuels - a clean coal solution for Eastern Europe

    International Nuclear Information System (INIS)

    Eastern Europe currently faces great economic and environmental problems. Among these problems is energy provision. Coal reserves are large but cause pollution while oil and gas need to be used for export. Formal 'clean coal technologies' are simply too expensive to be implemented on a large scale in the current economic crisis. The promised western investment and technological help has simply not taken place, western Europe must help eastern Europe with coal technology. The cheapest such technology is coal-water fuel slurry. It can substitute for oil, but research has not been carried out because of low oil prices. Coal-water fuel is one of the best methods of exploiting low rank coal. Many eastern European low rank coals have a low sulfur content, and thus make a good basis for a clean fuel. Italy and Russia are involved in such a venture, the slurry being transported in a pipeline. This technology would enable Russia to exploit Arctic coal reserves, thus freeing oil and gas for export. In Serbia the exploitation of sub-Danube lignite deposits with dredging mining produced a slurry. This led to the use and development of hot water drying, which enabled the removal of many of the salts which cause problems in pulverized fuel combustion. The system is economic, the fuel safer to transport then oil, either by rail or in pipelines. Many eastern European oil facilities could switch. 24 refs

  16. AGAPUTE - Advanced gas purification technologies for co-gasification of coal, refinery by-products, biomass & waste, targeted to clean power produced from gas & steam turbine generator sets and fuel cells. FINAL REPORT

    OpenAIRE

    Di Donato, Antonello; Puigjaner Corbella, Lluís; Velo García, Enrique; Nougués, José María; Pérez Fortes, María del Mar; Bojarski, Aarón David

    2010-01-01

    Informe Final del Projecte ECSC RFC-CR-04006: AGAPUTE - Advanced gas purification technologies for co-gasification of coal, refinery by-products, biomass & waste, targeted to clean power produced from gas & steam turbine generator sets and fuel cells

  17. Clean coal technologies

    International Nuclear Information System (INIS)

    The recent developments and implementations in clean coal technologies foe power generation and industry are reviewed in the present work. The requirements of the Clean Air Act in the United States, and the Directives of the European communities, on the limitations of emissions of pollutants from coal uses are firstly briefly reviewed, and later technological means that are available to coal producers and utilizers to comply with them. Coal cleaning, before combustion may be achieved by physical, chemical and biotechnological methods, these technologies are then examined as well as coal refining. The developments in clean coal combustion are extremely rapid, particularly in regard to poor coals, they are reviewed and in particular fluidized bed combustion, in its varieties, as well as coal gasification and combined cycle and the utilization of the gas in fuel cells. A further chapter is devoted to the control of emissions of gases from coal combustion, to reduce SO2 and NOx emitted in the atmosphere. The economic implications of the technologies are evaluated according to the most recent information available from published literature and from industry publications, and the results compared. The implications of meand to reduced the emission of CO2 to the atmosphere are also evaluated. (authors)

  18. Analysis of chemical coal cleaning processes. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1980-06-01

    Six chemical coal cleaning processes were examined. Conceptual designs and costs were prepared for these processes and coal preparation facilities, including physical cleaning and size reduction. Transportation of fine coal in agglomerated and unagglomerated forms was also discussed. Chemical cleaning processes were: Pittsburgh Energy Technology Center, Ledgemont, Ames Laboratory, Jet Propulsion Laboratory (two versions), and Guth Process (KVB). Three of the chemical cleaning processes are similar in concept: PETC, Ledgemont, and Ames. Each of these is based on the reaction of sulfur with pressurized oxygen, with the controlling factor being the partial pressure of oxygen in the reactor. All of the processes appear technically feasible. Economic feasibility is less certain. The recovery of process chemicals is vital to the JPL and Guth processes. All of the processes consume significant amounts of energy in the form of electric power and coal. Energy recovery and increased efficiency are potential areas for study in future more detailed designs. The Guth process (formally designed KVB) appears to be the simplest of the systems evaluated. All of the processes require future engineering to better determine methods for scaling laboratory designs/results to commercial-scale operations. A major area for future engineering is to resolve problems related to handling, feeding, and flow control of the fine and often hot coal.

  19. The production of a premium solid fuel from Powder River Basin coal. [COMPCOAL Process

    Energy Technology Data Exchange (ETDEWEB)

    Merriam, N.; Sethi, V.; Thomas, K.; Grimes, R.W.

    1992-01-01

    This report describes our initial evaluation of a process designed to produce premium-quality solid fuel from Powder River Basin (PRB) coal. The process is based upon our experience gained by producing highly-reactive, high-heating-value char as part of a mild-gasification project. In the process, char containing 20 to 25 wt % volatiles and having a gross heating value of 12,500 to 13,000 Btu/lb is produced. The char is then contacted by coal-derived liquid. The result is a deposit of 6 to 8 wt % pitch on the char particles. The lower boiling component of the coal-derived liquid which is not deposited on the char is burned as fuel. Our economic evaluation shows the process will be economically attractive if the product can be sold for about $20/ton or more. Our preliminary tests show that we can deposit pitch on to the char, and the product is less dusty, less susceptible to readsorption of moisture, and has reduced susceptibility to self heating.

  20. Clean coal initiatives in Indiana

    Science.gov (United States)

    Bowen, B.H.; Irwin, M.W.; Sparrow, F.T.; Mastalerz, Maria; Yu, Z.; Kramer, R.A.

    2007-01-01

    Purpose - Indiana is listed among the top ten coal states in the USA and annually mines about 35 million short tons (million tons) of coal from the vast reserves of the US Midwest Illinois Coal Basin. The implementation and commercialization of clean coal technologies is important to the economy of the state and has a significant role in the state's energy plan for increasing the use of the state's natural resources. Coal is a substantial Indiana energy resource and also has stable and relatively low costs, compared with the increasing costs of other major fuels. This indigenous energy source enables the promotion of energy independence. The purpose of this paper is to outline the significance of clean coal projects for achieving this objective. Design/methodology/approach - The paper outlines the clean coal initiatives being taken in Indiana and the research carried out at the Indiana Center for Coal Technology Research. Findings - Clean coal power generation and coal for transportation fuels (coal-to-liquids - CTL) are two major topics being investigated in Indiana. Coking coal, data compilation of the bituminous coal qualities within the Indiana coal beds, reducing dependence on coal imports, and provision of an emissions free environment are important topics to state legislators. Originality/value - Lessons learnt from these projects will be of value to other states and countries.

  1. Novel Intergrated Process to Process to Produce Fuels from Coal and Other Carbonaceous Feedstocks

    Energy Technology Data Exchange (ETDEWEB)

    Andrew Lucero

    2009-03-25

    BioConversion Technology, LLC has developed a novel gasifier design that produces a clean, medium to high BTU synthesis gas that can be utilized for a variety of applications. The staged, indirectly heated design produces high quality synthesis gas without the need for costly pure oxygen. This design also allows for extreme flexibility with respect to feedstocks (including those with high moisture contents) in addition to high throughputs in a small gasifier footprint. A pilot scale testing project was proposed to assist BCT with commercializing the process. A prototype gasifier constructed by BCT was transported to WRI for installation and testing. After troubleshooting, the gasifier was successfully operated with both coal and biomass feedstocks. Instrument upgrades are recommended for further testing.

  2. Clean coal technology: commercial-scale demonstration of the liquid phase methanol (LPMEOH{trademark}) process

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-04-01

    The report discusses the demonstration of Air Products and Chemical, Inc.`s Liquid Phase Methanol (LPMEOTH {trademark}) Process which is designed to convert synthesis gas derived from the gasification of coal into methanol for use as a chemical intermediate or as a low-sulfur dioxide and low-nitrogen oxides emitting alternative fuel. The project was selected for funding by the US Clean Coal Technology Program Round III in 1992. Construction of the Demonstration Project at Eastman Chemical Co`s Kingsport complex began in October 1995 and was completed in January 1997. Production rates of over 300 tons per day of methanol have been achieved and availability for the unit has exceeded 96% since startup. The LPMEOH{trademark} Process can enhance integrated gasification combined cycle (IGCC) power generation by converting part of the syngas from the gasifier to methanol which can be solid or used as a peak-sharing fuel. 50 refs., 5 figs., 7 photos.

  3. CPICOR{trademark}: Clean power from integrated coal-ore reduction

    Energy Technology Data Exchange (ETDEWEB)

    Wintrell, R.; Miller, R.N.; Harbison, E.J.; LeFevre, M.O.; England, K.S.

    1997-12-31

    The US steel industry, in order to maintain its basic iron production, is thus moving to lower coke requirements and to the cokeless or direct production of iron. The US Department of Energy (DOE), in its Clean Coal Technology programs, has encouraged the move to new coal-based technology. The steel industry, in its search for alternative direct iron processes, has been limited to a single process, COREX{reg_sign}. The COREX{reg_sign} process, though offering commercial and environmental acceptance, produces a copious volume of offgas which must be effectively utilized to ensure an economical process. This volume, which normally exceeds the internal needs of a single steel company, offers a highly acceptable fuel for power generation. The utility companies seeking to offset future natural gas cost increases are interested in this clean fuel. The COREX{reg_sign} smelting process, when integrated with a combined cycle power generation facility (CCPG) and a cryogenic air separation unit (ASU), is an outstanding example of a new generation of environmentally compatible and highly energy efficient Clean Coal Technologies. This combination of highly integrated electric power and hot metal coproduction, has been designated CPICOR{trademark}, Clean Power from Integrated Coal/Ore Reduction.

  4. Clean coal technology deployment: From today into the next millennium

    Energy Technology Data Exchange (ETDEWEB)

    Papay, L.T.; Trocki, L.K.; McKinsey, R.R. [Bechtel Technology and Consulting, San Francisco, CA (United States)

    1997-12-31

    The Department of Energy`s clean coal technology (CCT) program succeeded in developing more efficient, cleaner, coal-fired electricity options. The Department and its private partners succeeded in the demonstration of CCT -- a major feat that required more than a decade of commitment between them. As with many large-scale capital developments and changes, the market can shift dramatically over the course of the development process. The CCT program was undertaken in an era of unstable oil and gas prices, concern over acid rain, and guaranteed markets for power suppliers. Regulations, fuel prices, emergency of competing technologies, and institutional factors are all affecting the outlook for CCT deployment. The authors identify the major barriers to CCT deployment and then introduce some possible means to surmount the barriers.

  5. Clean Coal Diesel Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    Robert Wilson

    2006-10-31

    A Clean Coal Diesel project was undertaken to demonstrate a new Clean Coal Technology that offers technical, economic and environmental advantages over conventional power generating methods. This innovative technology (developed to the prototype stage in an earlier DOE project completed in 1992) enables utilization of pre-processed clean coal fuel in large-bore, medium-speed, diesel engines. The diesel engines are conventional modern engines in many respects, except they are specially fitted with hardened parts to be compatible with the traces of abrasive ash in the coal-slurry fuel. Industrial and Municipal power generating applications in the 10 to 100 megawatt size range are the target applications. There are hundreds of such reciprocating engine power-plants operating throughout the world today on natural gas and/or heavy fuel oil.

  6. Power generation from chemically cleaned coals: do environmental benefits of firing cleaner coal outweigh environmental burden of cleaning?

    DEFF Research Database (Denmark)

    Ryberg, Morten W.; Owsianiak, Mikolaj; Laurent, Alexis;

    2015-01-01

    beneficiation of coals using acid and alkali–acid leaching procedures is evaluated as a potential coal cleaning technology employing life cycle assessment (LCA). Taking into account the environmental benefits from firing cleaner coal in pulverized coal power plants and the environmental burden of the cleaning......Power generation from high-ash coals is a niche technology for power generation, but coal cleaning is deemed necessary to avoid problems associated with low combustion efficiencies and to minimize environmental burdens associated with emissions of pollutants originating from ash. Here, chemical...... on the impact category. The largest potential of the technology is observed for high-ash lignites, with initial ash content above 30%, for which the environmental benefits from firing cleaner coal can outweigh the environmental burden of cleaning for some impact categories. Overall, we recommend to policy...

  7. Fine coal cleaning via the micro-mag process

    Science.gov (United States)

    Klima, Mark S.; Maronde, Carl P.; Killmeyer, Richard P.

    1991-01-01

    A method of cleaning particulate coal which is fed with a dense medium slurry as an inlet feed to a cyclone separator. The coal particle size distribution is in the range of from about 37 microns to about 600 microns. The dense medium comprises water and ferromagnetic particles that have a relative density in the range of from about 4.0 to about 7.0. The ferromagnetic particles of the dense medium have particle sizes of less than about 15 microns and at least a majority of the particle sizes are less than about 5 microns. In the cyclone, the particulate coal and dense-medium slurry is separated into a low gravity product stream and a high gravity produce stream wherein the differential in relative density between the two streams is not greater than about 0.2. The low gravity and high gravity streams are treated to recover the ferromagnetic particles therefrom.

  8. Engineering development of advance physical fine coal cleaning for premium fuel applications

    Energy Technology Data Exchange (ETDEWEB)

    Jha, M.C.; Smit, F.J.; Shields, G.L. [AMAX R& D Center/ENTECH Global Inc., Golden, CO (United States)

    1995-11-01

    The objective of this project is to develop the engineering design base for prototype fine coal cleaning plants based on Advanced Column Flotation and Selective Agglomeration processes for premium fuel and near-term applications. Removal of toxic trace elements is also being investigated. The scope of the project includes laboratory research and bench-scale testing of each process on six coals followed by design, construction, and operation of a 2 tons/hour process development unit (PDU). Three coals will be cleaned in tonnage quantity and provided to DOE and its contractors for combustion evaluation. Amax R&D (now a subsidiary of Cyprus Amax Mineral Company) is the prime contractor. Entech Global is managing the project and performing most of the research and development work as an on-site subcontractor. Other participants in the project are Cyprus Amax Coal Company, Arcanum, Bechtel, TIC, University of Kentucky and Virginia Tech. Drs. Keller of Syracuse and Dooher of Adelphi University are consultants.

  9. Clean coal technologies

    International Nuclear Information System (INIS)

    According to the World Energy Council (WEC), at the beginning of the next century three main energy sources - coal, nuclear power and oil will have equal share in the world's total energy supply. This forecast is also valid for the USSR which possesses more than 40% of the world's coal resources and continuously increases its coal production (more than 700 million tons of coal are processed annually in the USSR). The stringent environmental regulations, coupled with the tendency to increase the use of coal are the reasons for developing different concepts for clean coal utilization. In this paper, the potential efficiency and environmental performance of different clean coal production cycles are considered, including technologies for coal clean-up at the pre-combustion stage, advanced clean combustion methods and flue gas cleaning systems. Integrated systems, such as combined gas-steam cycle and the pressurized fluidized bed boiler combined cycle, are also discussed. The Soviet National R and D program is studying new methods for coal utilization with high environmental performance. In this context, some basic research activities in the field of clean coal technology in the USSR are considered. Development of an efficient vortex combustor, a pressurized fluidized bed gasifier, advanced gas cleaning methods based on E-beam irradiation and plasma discharge, as well as new catalytic system, are are presented. In addition, implementation of technological innovations for retrofitting and re powering of existing power plants is discussed. (author)

  10. Effect of cleaning process on the combustion characteristics of two different rank coals

    Energy Technology Data Exchange (ETDEWEB)

    Kok, M.V.; Hicyilmaz, C.; Ozbas, K.E. [Middle East Technical University, Ankara (Turkey). Dept. of Mining Engineering

    2001-12-01

    In this research, thermogravimetry (TG/DTG) was used to determine the combustion characteristics of two different rank coals (Tuncbilek and Afsin Elbistan) before and after cleaning process. Applying sink-float process cleaned raw coal samples, and optimum-separating densities for each sample was determined using the criteria of 'degree of washability'. The results indicated that coal cleaning was very effective on Tuncbilek sample due to its high rank. TG/DTG analysis of raw and cleaned samples indicated different reaction regions occurring at different temperature intervals. Easy combustibility and long-lasting combustion were the distinctive effects of coal cleaning on raw coals. Kinetic analysis of the samples showed that clean coals require lower activation energies to initiate the combustion process than raw coals. 14 refs., 6 figs., 10 tabs.

  11. Clean energy from waste and coal

    International Nuclear Information System (INIS)

    Development of any new technology has traditionally been a controversial subject due to high expectations shared by proponents and results which many times fall short of these expectations. Solid and liquid waste management has been seen both success and failure in the implementation of new technology. For example, promises to commercially produce liquid or gaseous fuels and/or chemicals from municipal solid waste (MSW) or refuse derived fuel (RDF) have so far been unfulfilled after several attempts at demonstrating various technologies

  12. COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1993-07-01

    This report describes the Western Research Institute (WRI) COMPCOAL{trademark} process which is designed to produce a stable, high-Btu fuel from Powder River Basin (PRB) and other low-rank coals. The process is designed to overcome the problems of oxidation and spontaneous combustion, readsorption of moisture, and dust formation from the friable coal. PRB coal is susceptible to low-temperature oxidation and self-heating, particularly after it has been dried. This report describes a method WRI has developed to prevent self-heating of dried PRB coal. The ``accelerated aging`` not only stabilizes the dried coal, but it also increases the heating value of the COMPCOAL product. The stabilized COMPCOAL product has a heating value of 12,000 to 12,700 Btu/lb, contains 35 to 40 wt % volatiles, and is comparable to unprocessed PRB coal in self-heating and low-temperature oxidation characteristics. Importantly, the self-heating tendency can be controlled by slightly adjusting the ``aging`` step in the process.

  13. Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process

    Energy Technology Data Exchange (ETDEWEB)

    Hackett, Gregory A.; Gerdes, Kirk R.; Song, Xueyan; Chen, Yun; Shutthanandan, V.; Engelhard, Mark H.; Zhu, Zihua; Thevuthasan, Suntharampillai; Gemmen, Randall

    2012-09-15

    Solid oxide fuel cells (SOFCs) are presently being developed for gasification integrated power plants that generate electricity from coal at 50+% efficiency. The interaction of trace metals in coal syngas with the Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but direct test data from coal syngas exposure are sparsely available. This research effort evaluates the significance of SOFC performance losses associated with exposure of a SOFC anode to direct coal syngas. SOFC specimen of industrially relevant composition are operated in a unique mobile test skid that was deployed to the research gasifier at the National Carbon Capture Center (NCCC) in Wilsonville, AL. The mobile test skid interfaces with a gasifier slipstream to deliver hot syngas (up to 300°C) directly to a parallel array of 12 button cell specimen, each of which possesses an active area of approximately 2 cm2. During the 500 hour test period, all twelve cells were monitored for performance at four discrete operating current densities, and all cells maintained contact with a data acquisition system. Of these twelve, nine demonstrated good performance throughout the test, while three of the cells were partially compromised. Degradation associated with the properly functioning cells was attributed to syngas exposure and trace material attack on the anode structure that was accelerated at increasing current densities. Cells that were operated at 0 and 125 mA/cm² degraded at 9.1 and 10.7% per 1000 hours, respectively, while cells operated at 250 and 375 mA/cm² degraded at 18.9 and 16.2% per 1000 hours, respectively. Post-trial spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  14. Environmental control implications of generating electric power from coal. 1977 technology status report. Appendix A, Part 1. Coal preparation and cleaning assessment study

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-12-01

    This report evaluates the state of the art and effectiveness of physical coal cleaning as a potential strategy for controlling SO/sub x/ emissions in coal fired power generation. Coal properties which are significantly altered by physical coal cleaning were determined. The effects of the changes in properties as they relate to pulverized coal firing, fluidized bed combustion and low Btu gasification for combined cycle powered generation were studied. Available coal washability data were integrated by computer with U.S. coal reserve data. Approximately 18% of the demonstrated coal reserve were matched with washability data. Integrated data appear in the Appendix. Current coal preparation practices were reviewed. Future trends were determined. Five process flow sheets representing increasing levels of cleaning sophistication were prepared. The clean product from each flow sheet will meet U.S. EPA New Source Performance Standards. Capital and operating costs for each case were estimated. Environmental control technology and environmental impact associated with current coal preparation and cleaning operations were assessed. Physical coal cleaning is widely practiced today. Where applicable it represents the least expensive method of coal sulfur reduction. Developmental physical and chemical coal cleaning processes were studied. The chemical methods have the advantage of being able to remove both pyritic sulfur and organic sulfur present in the coal matrix. Further R and D efforts will be required before commercialization of these processes.

  15. MEDIUM PRESSURE HYDROUPGRADING PROCESS (MHUG) AND PRODUCTION OF CLEAN FUELS

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The medium pressure hydroupgrading process (MHUG) unit with an 800 kt/a processing capacity of Jinzhou Petrochemical Company is used to hydroupgrade the mixture of FCC LCO fuel and straight-run diesel fuel in the presence of RN/RT series catalysts for improvement of the quality of the diesel fuel. Meanwhile, catalytic reforming feedstock is also obtained. The sulfur, nitrogen and aromatics contained in the hydroupgraded diesel fuel products can be minimized and the cetane number can be heightened. The produced clean fuels can meet the requirements of environmental protection.

  16. The Charfuel coal refining process

    International Nuclear Information System (INIS)

    The patented Charfuel coal refining process employs fluidized hydrocracking to produce char and liquid products from virtually all types of volatile-containing coals, including low rank coal and lignite. It is not gasification or liquefaction which require the addition of expensive oxygen or hydrogen or the use of extreme heat or pressure. It is not the German pyrolysis process that merely 'cooks' the coal, producing coke and tar-like liquids. Rather, the Charfuel coal refining process involves thermal hydrocracking which results in the rearrangement of hydrogen within the coal molecule to produce a slate of co-products. In the Charfuel process, pulverized coal is rapidly heated in a reducing atmosphere in the presence of internally generated process hydrogen. This hydrogen rearrangement allows refinement of various ranks of coals to produce a pipeline transportable, slurry-type, environmentally clean boiler fuel and a slate of value-added traditional fuel and chemical feedstock co-products. Using coal and oxygen as the only feedstocks, the Charfuel hydrocracking technology economically removes much of the fuel nitrogen, sulfur, and potential air toxics (such as chlorine, mercury, beryllium, etc.) from the coal, resulting in a high heating value, clean burning fuel which can increase power plant efficiency while reducing operating costs. The paper describes the process, its thermal efficiency, its use in power plants, its pipeline transport, co-products, environmental and energy benefits, and economics

  17. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report No. 4

    Energy Technology Data Exchange (ETDEWEB)

    Smit, F.J.; Hogsett, R.F.; Jha, M.C.

    1993-11-04

    This project is a major step in the Department of Energy`s program to show that ultra-clean coal-water slurry fuel (CWF) can be produced from selected coals and that this premium fuel will be a cost-effective replacement for oil and natural gas now fueling some of the industrial and utility boilers in the United States. The replacement of oil and gas with CWF can only be realized if retrofit costs are kept to a minimum and retrofit boiler emissions meet national goals for clean air. These concerns establish the specifications for maximum ash and sulfur levels and combustion properties of the CWF. This cost-share contract is a 48-month program which started on September 30, 1992. This report discusses the technical progress made during the 4th quarter of the project from July 1 to September 30, 1993.

  18. Laboratory Scale of Liquid Coal Fuel Combustion Process and Exhaust Gas Formation

    OpenAIRE

    Kartika K. Hendratna; Osami Nishida; Hirotsugu Fujita; Wataru Harano

    2010-01-01

    Problem statement: Much research of coal has been already undertaken to ascertain the possibilities of coal being used as substitute for heavy fuel oil in the transportation sector. The effects of using coal as transportation fuel to the environment must also be considered. This study will review several aspects of the coal oil combustion process including combustion behavior, flame stability, some emissions from exhaust gas; CO, NOx and the particulate matter in a well insulated laboratory s...

  19. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    Energy Technology Data Exchange (ETDEWEB)

    Gary Harmond; Albert Tsang

    2003-03-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over a three year period, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. The WREL facility is a project selected and co-funded under the Round IV of the U.S. Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial

  20. Fossil fuels and clean, plentiful energy in the 21st century: the example of coal

    OpenAIRE

    Jaccard, Mark

    2007-01-01

    Many people believe we must quickly wean ourselves from fossil fuels to save the planet from environmental catastrophe, wars and economic collapse. However, we have the technological capability to use fossil fuels without emitting climate-threatening greenhouse gases or other pollutants. The natural transition from conventional oil and gas to unconventional oil, unconventional gas and coal for producing electricity, hydrogen and cleaner-burning fuels will decrease energy dependence on politic...

  1. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    Energy Technology Data Exchange (ETDEWEB)

    Albert Tsang

    2003-03-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. The WREL facility is a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., parent company of GEC and WREL, as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are

  2. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 15, April--June 1996

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-07-25

    Goal is engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. Scope includes laboratory research and bench-scale testing on 6 coals to optimize these processes, followed by design/construction/operation of a 2-t/hr PDU. During this quarter, parametric testing of the 30-in. Microcel{trademark} flotation column at the Lady Dunn plant was completed and clean coal samples submitted for briquetting. A study of a novel hydrophobic dewatering process continued at Virginia Tech. Benefits of slurry PSD (particle size distribution) modification and pH adjustment were evaluated for the Taggart and Hiawatha coals; they were found to be small. Agglomeration bench-scale test results were positive, meeting product ash specifications. PDU Flotation Module operations continued; work was performed with Taggart coal to determine scaleup similitude between the 12-in. and 6-ft Microcel{trademark} columns. Construction of the PDU selective agglomeration module continued.

  3. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Task 6 -- Selective agglomeration laboratory research and engineering development for premium fuels

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Jha, M.C.

    1997-06-27

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and benchscale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. This report represents the findings of Subtask 6.5 Selective Agglomeration Bench-Scale Testing and Process Scale-up. During this work, six project coals, namely Winifrede, Elkhorn No. 3, Sunnyside, Taggart, Indiana VII, and Hiawatha were processed in a 25 lb/hr continuous selective agglomeration bench-scale test unit.

  4. Innovative technologies on fuel assemblies cleaning for sodium fast reactors: First considerations on cleaning process

    International Nuclear Information System (INIS)

    Within the framework of Sodium Fast Reactor development, innovative fuel assembly cleaning operations are investigated to meet the GEN IV goals of safety and of process development. One of the challenges is to mitigate the Sodium Water Reaction currently used in these processes. The potential applications of aqueous solutions of mineral salts (including the possibility of using redox chemical reactions) to mitigate the Sodium Water Reaction are considered in a first part and a new experimental bench, dedicated to this study, is described. Anhydrous alternative options based on Na/CO2 interaction are also presented. Then, in a second part, a functional study conducted on the cleaning pit is proposed. Based on experimental feedback, some calculations are carried out to estimate the sodium inventory on the fuel elements, and physical methods like hot inert gas sweeping to reduce this inventory are also presented. Finally, the implementation of these innovative solutions in cleaning pits is studied in regard to the expected performances. (authors)

  5. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    Energy Technology Data Exchange (ETDEWEB)

    Albert Tsang

    2003-10-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Two project phases are planned for execution, including: (1) Feasibility study and conceptual design for an integrated demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The WREL facility is a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., parent company of GEC and WREL, as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction

  6. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    Energy Technology Data Exchange (ETDEWEB)

    Doug Strickland; Albert Tsang

    2002-10-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over a three year period, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial plants operated at Dow Chemical or Dow Corning chemical plant locations; (2) Research, development, and testing to define any technology gaps or critical design and integration issues; and (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. This report describes management planning, work breakdown structure development, and feasibility study activities by the IMPPCCT consortium in support of the first project phase. Project planning activities have been completed, and a project timeline and task list has been generated. Requirements for an economic model to evaluate the West Terre Haute implementation and for other commercial implementations are being defined. Specifications for methanol product and availability of local feedstocks for potential commercial embodiment plant sites have been defined. The WREL facility is a project selected and co-funded under the fifth phase solicitation of the U.S. Department of Energy's Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis

  7. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Lynch

    2004-01-07

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead previously by Gasification Engineering Corporation (GEC). The project is now under the leadership of ConocoPhillips Company (COP) after it acquired GEC and the E-Gas{trademark} gasification technology from Global Energy in July 2003. The Phase I of this project was supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while the Phase II is supported by Gas Technology Institute, TDA Research, Inc., and Nucon International, Inc. The two project phases planned for execution include: (1) Feasibility study and conceptual design for an integrated demonstration facility at Global Energy's existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The WREL facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now

  8. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  9. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  10. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  11. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler

  12. Clean coal technology: The new coal era

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    The Clean Coal Technology Program is a government and industry cofunded effort to demonstrate a new generation of innovative coal processes in a series of full-scale showcase`` facilities built across the country. Begun in 1986 and expanded in 1987, the program is expected to finance more than $6.8 billion of projects. Nearly two-thirds of the funding will come from the private sector, well above the 50 percent industry co-funding expected when the program began. The original recommendation for a multi-billion dollar clean coal demonstration program came from the US and Canadian Special Envoys on Acid Rain. In January 1986, Special Envoys Lewis and Davis presented their recommendations. Included was the call for a 5-year, $5-billion program in the US to demonstrate, at commercial scale, innovative clean coal technologies that were beginning to emerge from research programs both in the US and elsewhere in the world. As the Envoys said: if the menu of control options was expanded, and if the new options were significantly cheaper, yet highly efficient, it would be easier to formulate an acid rain control plan that would have broader public appeal.

  13. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 11, April--June, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1995-07-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 tons of each of three project coals, by each process. During Quarter 11 (April--June, 1995), work continued on the Subtask 3.2 in-plant testing of the Microcel{trademark} flotation column at the Lady Dunn Preparation Plant with the installation and calibration of a refurbished 30-inch diameter column. The evaluation of toxic trace element data for column flotation samples continued, with preliminary analysis indicating that reasonably good mass balances were achieved for most elements, and that significant reductions in the concentration of many elements were observed from raw coal, to flotation feed, to flotation product samples. Significant progress was made on Subtask 6.5 selective agglomeration bench-scale testing. Data from this work indicates that project ash specifications can be met for all coals evaluated, and that the bulk of the bridging liquid (heptane) can be removed from the product for recycle to the process. The detailed design of the 2 t/hr selective agglomeration module progressed this quarter with the completion of several revisions of both the process flow, and the process piping and instrument diagrams. Procurement of coal for PDU operation began with the purchase of 800 tons of Taggart coal. Construction of the 2 t/hr PDU continued through this reporting quarter and is currently approximately 60% complete.

  14. Bench-scale testing of a micronized magnetite, fine-coal cleaning process

    Energy Technology Data Exchange (ETDEWEB)

    Suardini, P.J. [Custom Coals, International, Pittsburgh, PA (United States)

    1995-11-01

    Custom Coals, International has installed and is presently testing a 500 lb/hr. micronized-magnetite, fine-coal cleaning circuit at PETC`s Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program`s, High Efficiency Preparation Subprogram. The project includes design, construction, testing, and decommissioning of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense medium cycloning of the 300 by 30 micron feed coal using a nominal minus 10 micron size magnetite medium, and medium recovery using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

  15. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  16. Clean coal technology

    International Nuclear Information System (INIS)

    Coal is the major source of energy in India at present as well as in foreseeable future. With gradual deterioration in coal quality as well as increased awareness on environmental aspects, clean coal technologies have to be adopted by major coal consuming sectors. The probable routes of restricting environmental degradation in power generation include beneficiation of power coal for maintaining consistency in coal supply and reducing pollutant emission, adoption of fluidized bed combustion on a larger scale, adoption of technologies for controlling SOx and NOx emission during and after combustion, adoption of larger capacity and improved and non-recovery type coke ovens

  17. Engineering Development of Advanced Physical Fine Coal Cleaning for Premium Fuel Applications: Task 9 - Selective agglomeration Module Testing and Evaluation.

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.` Jha, M.C.

    1997-09-29

    The primary goal of this project was the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing of both processes on six coals to optimize the processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by September 1997. This report summarizes the findings of all the selective agglomeration (SA) test work performed with emphasis on the results of the PDU SA Module testing. Two light hydrocarbons, heptane and pentane, were tested as agglomerants in the laboratory research program which investigated two reactor design concepts: a conventional two-stage agglomeration circuit and a unitized reactor that combined the high- and low-shear operations in one vessel. The results were used to design and build a 25 lb/hr bench-scale unit with two-stage agglomeration. The unit also included a steam stripping and condensation circuit for recovery and recycle of heptane. It was tested on six coals to determine the optimum grind and other process conditions that resulted in the recovery of about 99% of the energy while producing low ash (1-2 lb/MBtu) products. The fineness of the grind was the most important variable with the D80 (80% passing size) varying in the 12 to 68 micron range. All the clean coals could be formulated into coal-water-slurry-fuels with acceptable properties. The bench-scale results were used for the conceptual and detailed design of the PDU SA Module which was integrated with the existing grinding and dewatering circuits. The PDU was operated for about 9 months. During the first three months, the shakedown testing was performed to fine tune the operation and control of various equipment. This was followed by parametric testing, optimization/confirmatory testing, and finally a

  18. Coal cleaning: a viable strategy for reduced carbon emissions and improved environment in China?

    International Nuclear Information System (INIS)

    China is a dominant energy consumer in global context and current energy forecasts emphasise that China's future energy consumption also will rely heavily on coal. The coal use is the major source of the greenhouse gas CO2 and particles causing serious health damage. This paper looks into the question if coal washing might work as low cost strategy for both CO2 and particle emission reductions. Coal washing removes dirt and rock from raw coal, resulting in a coal product with higher thermal energy and less air pollutants. Coal cleaning capacity has so far not been developed in line with the market potential. In this paper an emerging market for cleaned coal is studied within a CGE model for China. The macro approach catches the repercussions of coal cleaning through increased energy efficiency, lower coal transportation costs and crowding out effect of investments in coal washing plants. Coal cleaning stimulates economic growth and reduces particle emissions, but total energy use, coal use and CO2 emissions increase through a rebound effect supported by the vast reserve of underemployed labourers. A carbon tax on fossil fuel combustion has a limited effect on total emissions. The reason is a coal leakage to tax exempted processing industries

  19. Fossil fuels. Pace and focus of the clean coal technology program need to be assessed

    International Nuclear Information System (INIS)

    DOE developed an elaborate process for evaluating, ranking, and selecting round-two project proposals. The criteria used to evaluate and select proposals for funding generally conformed to congressional and other program guidance. Also, the evaluation and selection process provided reasonable assurance that proposals were consistently and thoroughly evaluated and that projects were selected using the applicable criteria. GAO's analysis the evaluation and selection process showed that DOE picked the highest-ranked proposals submitted for the various mix of technologies that it was interested in seeing demonstrated. Of the 16 projects DOE selected in round two, 12 were rated weak in meeting certain of the evaluation criteria. Nine of the projects were rated weak in meeting the criterion that a project's technology has the potential to reduce nationwide emissions that cause acid rain. Although emphasis was to be focused on coal-burning projects nationwide to reduce emissions that cause acid rain, it still was only one of many criteria to be considered in evaluating proposals. If DOE had picked more projects with greater potential to reduce nationwide emissions from coal-fired facilities, it would have resulted in (1) the selection of lower ranked projects demonstrating technologies similar to the projects that were selected, and (2) projects selected which may not be successfully demonstrated or commercialized because of weaknesses in other criteria. GAO also noted that half of the 48 proposals that were evaluated in round-two fared poorly against 3 or more of the evaluation criteria. This could indicate that DOE may have problems in identifying and funding additional promising clean coal technology projects in future rounds. Furthermore, GAO's past work has shown that problems have delayed finalizing project cooperative agreements, delayed completion of various project phases, and extended the estimated completion dates for some projects in round-one. As of December

  20. Modeling and optimization of processes for clean and efficient pulverized coal combustion in utility boilers

    OpenAIRE

    Belošević Srđan V.; Tomanović Ivan D.; Crnomarković Nenad Đ.; Milićević Aleksandar R.; Tucaković Dragan R.

    2016-01-01

    Pulverized coal-fired power plants should provide higher efficiency of energy conversion, flexibility in terms of boiler loads and fuel characteristics and emission reduction of pollutants like nitrogen oxides. Modification of combustion process is a cost-effective technology for NOx control. For optimization of complex processes, such as turbulent reactive flow in coal-fired furnaces, mathematical modeling is regularly used. The NOx emission reduction by c...

  1. Effects of consumer subsidy on household fuel switching from coal to cleaner fuels: A case study for anthracites in Korea

    International Nuclear Information System (INIS)

    The Korean coal industry is in a transition under low carbon policy through the steady reduction of coal production. Since consumer subsidy for the consumption of anthracites briquette in low-income households caused a distortion in domestic coal market, the so-called coupon program will be the first target in energy reform policy in order to induce fuel switching from anthracites to alternative clean energy. This paper tries to identify various factors that influence households' fuel switching decision. Disutility from briquette consumption is also considered as an important factor. Using the 2007 census data on briquette-consuming households, it is found that the coupon program provides an adverse effect to switching fuels to clean energy while the disutility of briquettes is positively associated with the probability of fuel switching. However, the empirical finding suggests that the policy alone attempting to remove coupon program may fail to switch fuels unless the cost of boiler changes is substantially reduced through the provision of accessible networks to alternative energy sources. It indicates that reform policy for consumer subsidy must be understood in line with more comprehensive regional energy plans to resolve energy poverty issue. - Research highlights: → Various factors are identified for low income households' fuel switching from coal to clean energy. → Coupon program and accessibility to alternative energy sources are considered; Result shows that accessible network to alternative clean energy sources is essential for low income group. → More comprehensive regional energy plans are required to resolve energy poverty issue.

  2. Effects of consumer subsidy on household fuel switching from coal to cleaner fuels: A case study for anthracites in Korea

    Energy Technology Data Exchange (ETDEWEB)

    Park, Hojeong, E-mail: hjeongpark@korea.ac.k [Department of Food and Resource Economics, College of Life Sciences and Biotechnology, Korea University, Anam-Dong, Seongbuk-Gu, Seoul 136-701 (Korea, Republic of); Kwon, Hyucksoo [Korea Energy Economics Institute, Naeson 2-Dong, Euiwang-si, Kyonggi-do, 437-713 (Korea, Republic of)

    2011-03-15

    The Korean coal industry is in a transition under low carbon policy through the steady reduction of coal production. Since consumer subsidy for the consumption of anthracites briquette in low-income households caused a distortion in domestic coal market, the so-called coupon program will be the first target in energy reform policy in order to induce fuel switching from anthracites to alternative clean energy. This paper tries to identify various factors that influence households' fuel switching decision. Disutility from briquette consumption is also considered as an important factor. Using the 2007 census data on briquette-consuming households, it is found that the coupon program provides an adverse effect to switching fuels to clean energy while the disutility of briquettes is positively associated with the probability of fuel switching. However, the empirical finding suggests that the policy alone attempting to remove coupon program may fail to switch fuels unless the cost of boiler changes is substantially reduced through the provision of accessible networks to alternative energy sources. It indicates that reform policy for consumer subsidy must be understood in line with more comprehensive regional energy plans to resolve energy poverty issue. - Research highlights: {yields} Various factors are identified for low income households' fuel switching from coal to clean energy. {yields} Coupon program and accessibility to alternative energy sources are considered; Result shows that accessible network to alternative clean energy sources is essential for low income group. {yields} More comprehensive regional energy plans are required to resolve energy poverty issue.

  3. Advances in ultrasonic fuel cleaning

    International Nuclear Information System (INIS)

    Ultrasonic fuel cleaning has been demonstrated to be effective for avoiding or postponing the axial offset anomaly (AOA) in high-duty PWRs. In addition, the reduction in corrosion product inventory achieved by this method of fuel cleaning has been shown to reduce ex-core dose rates, and hence reduce personnel exposure. Through laboratory mock-up tests as well as tests on discharged fuel in the Callaway spent fuel pool, the EPRI ultrasonic fuel cleaning system was demonstrated to clean crud from fuel rods throughout the assembly without deleterious effects on fuel integrity. This paper presents details of the evaluation tests at AmerenUE's Callaway PWR, as well as the full-reload ultrasonic cleaning for Cycle 12. Ninety-six once-burned fuel assemblies were cleaned via the EPRI ultrasonic process during refueling outage 11 in April 2001. Fuel cleaning activities presented no special problems in or around the fuel pool, neither in terms of activity nor in terms of turbidity of the pool water, nor were special radiological situations encountered by personnel working in the area. The corrosion products were captured on cartridge filters designed to avoid loss of material into the fuel pool water during interim storage. Activity levels on the cartridges were maintained sufficiently low for ease of handling, processing, and shipment in Radwaste. The fuel cleaning operation was completed within a time window of approximately 48 hours. The cleaned fuel was returned to service in May 2001 for Cycle 12. To date, this fuel cycle remains free of AOA (Axial Offset Anomaly). This result is in contrast to earlier cycles of similar design and power duty, but without reload fuel cleaning. These cycles were operated at a reduced TAVE in order to mitigate AOA. Nevertheless, Cycle 11 experienced AOA starting as early as 6 GWD/MTU. Based on the favorable Cycle 12 data, the utility intends to institute fuel cleaning as a routine outage activity, thus expecting to recover the TAVE

  4. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLGIES (IMPPCCT)

    Energy Technology Data Exchange (ETDEWEB)

    Albert C. Tsang

    2004-03-26

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy in July 2003. The project has completed Phase I, and is currently in Phase II of development. The two project phases include: (1) Feasibility study and conceptual design for an integrated demonstration facility at Global Energy's existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations; and (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The Phase I of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase II is supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The WREL integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical

  5. Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT)

    Energy Technology Data Exchange (ETDEWEB)

    Conocophillips

    2007-09-30

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project was established to evaluate integrated electrical power generation and methanol production through clean coal technologies. The project was under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy Inc. in July 2003. The project has completed both Phase 1 and Phase 2 of development. The two project phases include the following: (1) Feasibility study and conceptual design for an integrated demonstration facility at SG Solutions LLC (SGS), previously the Wabash River Energy Limited, Gasification Facility located in West Terre Haute, Indiana, and for a fence-line commercial embodiment plant (CEP) operated at the Dow Chemical Company or Dow Corning Corporation chemical plant locations. (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. Phase 1 of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase 2 was supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The SGS integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other carbonaceous fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas (syngas) is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine

  6. The Clean Coal Technology Program: Lessons learned

    Energy Technology Data Exchange (ETDEWEB)

    1994-07-01

    The Clean Coal Technology (CCT) Program is a unique partnership between the federal government and industry that has as its primary goal the successful introduction of new clean coal utilization technologies into the energy marketplace. Clean coal technologies being demonstrated under the CCT Program are establishing a technology base that will enable the nation to meet more stringent energy and environmental goals. Most of the, demonstrations are being conducted at commercial scale, in actual user environments, and under circumstances typical of commercial operations. These features allow the potential of the technologies to be evaluated in their intended commercial applications. Each application addresses one of the following four market sectors: advanced electric power generation; environmental control devices; coal processing for clean fuels; and industrial applications. The purpose of this report is fourfold: Explain the CCT program as a model for successful joint government industry partnership for selecting and demonstrating technologies that have promise for adaptation to the energy marketplace; set forth the process by which the process has been implemented and the changes that have been made to improve that process; outline efforts employed to inform potential users and other interested parties about the technologies being developed; and examine some of the questions which must be considered in determining if the CCT Program model can be applied to other programs.

  7. The NOXSO clean coal project

    Energy Technology Data Exchange (ETDEWEB)

    Black, J.B.; Woods, M.C.; Friedrich, J.J.; Browning, J.P. [NOXSO Corp., Bethel Park, PA (United States)

    1997-12-31

    The NOXSO Clean Coal Project will consist of designing, constructing, and operating a commercial-scale flue-gas cleanup system utilizing the NOXSO Process. The process is a waste-free, dry, post-combustion flue-gas treatment technology which uses a regenerable sorbent to simultaneously adsorb sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) from flue gas from coal-fired boilers. The NOXSO plant will be constructed at Alcoa Generating Corporation`s (AGC) Warrick Power Plant near Evansville, Indiana and will treat all the flue gas from the 150-MW Unit 2 boiler. The NOXSO plant is being designed to remove 98% of the SO{sub 2} and 75% of the NO{sub x} when the boiler is fired with 3.4 weight percent sulfur, southern-Indiana coal. The NOXSO plant by-product will be elemental sulfur. The elemental sulfur will be shipped to Olin Corporation`s Charleston, Tennessee facility for additional processing. As part of the project, a liquid SO{sub 2} plant has been constructed at this facility to convert the sulfur into liquid SO{sub 2}. The project utilizes a unique burn-in-oxygen process in which the elemental sulfur is oxidized to SO{sub 2} in a stream of compressed oxygen. The SO{sub 2} vapor will then be cooled and condensed. The burn-in-oxygen process is simpler and more environmentally friendly than conventional technologies. The liquid SO{sub 2} plant produces 99.99% pure SO{sub 2} for use at Olin`s facilities. The $82.8 million project is co-funded by the US Department of Energy (DOE) under Round III of the Clean Coal Technology program. The DOE manages the project through the Pittsburgh Energy Technology Center (PETC).

  8. Recovery of reagent in a process for producing ultra clean coal

    Energy Technology Data Exchange (ETDEWEB)

    K.M. Steel; J.W. Patrick [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre

    2003-07-01

    A technique for selectively separating approximately 65 wt% of the Si(IV) in coal has been developed. The technique first uses aqueous HF to react with aluminosilicates and quartz to form fluoride complexed Al and Si species in solution. Aluminium cations, in the form of Al(NO{sub 3}){sub 3}, are then added to the solution to complex fluoride as AlF{sub 2}{sup +} and hydrolyse the silicon fluoride species to silicon hydroxide, which precipitates as pure silica gel and is removed by filtration. The solution is then distilled to recover a water stream, a nitric acid stream and a solid residue. The water stream is used to pyrohydrolyse the solid residue at temperatures in excess of 500{sup o}C to liberate HF for recycling. To complete the circuit, the solid remaining after pyrohydrolysis is treated with the nitric acid stream to produce Al(NO{sub 3}){sub 3} for recycling. The application of this work is primarily as part of a process for producing ultra-clean coal. As it is a technique for the selective separation of Al and Si from aluminosilicates, it may have application in other areas of mineral processing. 10 refs., 3 figs., 2 tabs.

  9. Regulating Greenhouse Gases from Coal Power Plants under the Clean Air Act

    OpenAIRE

    Joshua Linn; Erin Mastrangelo; Dallas Burtraw

    2014-01-01

    The Clean Air Act has assumed the central role in US climate policy, directing the development of regulations governing greenhouse gas emissions from existing coal-fired power plants. This paper uses a model of power plant operation and efficiency investments to compare the cost-effectiveness of alternative policies to reduce greenhouse gas emissions from coal plants. We empirically estimate the key model parameters from a data set of the operation of coal-fired generating units over 25 years...

  10. Self-Scrubbing Coal -- an integrated approach to clean air

    Energy Technology Data Exchange (ETDEWEB)

    Harrison, K.E. [Custom Coals Corp., Pittsburgh, PA (United States)

    1997-12-31

    Carefree Coal is coal cleaned in a proprietary dense-media cyclone circuit, using ultrafine magnetite slurries, to remove noncombustible material, including up to 90% of the pyritic sulfur. Deep cleaning alone, however, cannot produce a compliance fuel from coals with high organic sulfur contents. In these cases, Self-Scrubbing Coal will be produced. Self-Scrubbing Coal is produced in the same manner as Carefree Coal except that the finest fraction of product from the cleaning circuit is mixed with limestone-based additives and briquetted. The reduced ash content of the deeply-cleaned coal will permit the addition of relatively large amounts of sorbent without exceeding boiler ash specifications or overloading electrostatic precipitators. This additive reacts with sulfur dioxide (SO{sub 2}) during combustion of the coal to remove most of the remaining sulfur. Overall, sulfur reductions in the range of 80--90% are achieved. After nearly 5 years of research and development of a proprietary coal cleaning technology coupled with pilot-scale validation studies of this technology and pilot-scale combustion testing of Self-Scrubbing Coal, Custom Coals Corporation organized a team of experts to prepare a proposal in response to DOE`s Round IV Program Opportunity Notice for its Clean Coal Technology Program under Public Law 101-121 and Public Law 101-512. The main objective of the demonstration project is the production of a coal fuel that will result in up to 90% reduction in sulfur emissions from coal-fired boilers at a cost competitive advantage over other technologies designed to accomplish the same sulfur emissions and over naturally occurring low sulfur coals.

  11. Triboelectrostatic Separation-an Efficient Method of Producing Low Ash Clean Coal

    Institute of Scientific and Technical Information of China (English)

    章新喜; 边炳鑫; 段超红; 熊建军

    2002-01-01

    At present, coal is mainly consumed as fuel. In fact, coal is also a kind of precious raw material in chemical industry on the premise that some harmful minerals should be removed from coal. The paper presents the results of the research on producing low ash (<2%) coal with triboelectrostatic separator used for producing high-grade active carbon. The test is conducted in bench-scale system, whose capacity is 30~100 kg/h. The results indicate that: 1) the ash content of clean coal increases with the increase of solid content of feedstock, on the contrary, the yield of clean coal is declining; 2) a high velocity may result in a good separation efficiency; 3) for the same solid content, the reunion caused by intermolecular force makes the separation efficiency drop down when the ultra-fine coal is separated; 4) the separation efficiency is improved with the increase of electric field intensity, but there is a good optimized match between the electric field intensity and yield of clean coal; 5) a low rank coal is easy-to-wash in triboelectrostatic separation process; 6) the yield of clean coal can be enhanced and the ash decreased through adapting optimized conditions according to various coals.

  12. Sustainable development with clean coal

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-08-01

    This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

  13. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  14. Laboratory Scale of Liquid Coal Fuel Combustion Process and Exhaust Gas Formation

    Directory of Open Access Journals (Sweden)

    Kartika K. Hendratna

    2010-01-01

    Full Text Available Problem statement: Much research of coal has been already undertaken to ascertain the possibilities of coal being used as substitute for heavy fuel oil in the transportation sector. The effects of using coal as transportation fuel to the environment must also be considered. This study will review several aspects of the coal oil combustion process including combustion behavior, flame stability, some emissions from exhaust gas; CO, NOx and the particulate matter in a well insulated laboratory scale furnace for more stable of combustion. Approach: New way for preparation for liquid coal oil steady combustion on a 2.75 m horizontal boiler with four annular segment tubes, a water jacket system and a system for measurement of water temperature inside was archived. Data was gained by applying liquid coal in the experiment. Detailed preparation and setting for steady combustion of coal oil and formation of the exhaust gas were discussed based on data sampling from four sample points in each centre of the angular tube segments. Results: Preparation for coal oil combustion is an important point in the successful of combustion. Heating coal fuel to than 100°C, heating the fuel line to the same temperature and providing enough air pressure for atomization of coal oil until 0.1 MPa allows coal fuel smoothly atomized in the semi gas phase. There was enough of air combustion via a blower with 4500 L min-1 of flow rate and a 24 L min-1 of water flow rate in the water jacket transforms the energy of the fuel to the heat. Uncolored of the exhaust gas and the physical inspection describes the completion of combustion. This result close-relates with the pollutants formation in the exhaust gas. Conclusion: By conducting a deep research process, there is a chance for the substitute of heavy fuel oil with liquid coal fuel with no special treatment needed in combustion process without ignoring the contribution of the combustion results as an environmental problem.

  15. A novel process for preparation of ultra-clean micronized coal by high pressure water jet comminution technique

    Energy Technology Data Exchange (ETDEWEB)

    Longlian Cui; Liqian An; Weili Gong; Hejin Jiang [China University of Mining and Technology, Beijing (China). School of Mechanics, Architecture and Civil Engineering

    2007-03-15

    A novel process for the preparation of ultra-clean micronized coal is presented in this paper. High pressure water jet mill replacing the ball mill is employed for coal comminution in the new preparation process, which is the essential difference from the traditional one. To compare the new preparation process with the traditional one, the comparison experiments were performed, with froth flotation tests of the fine particles ground by both mills using diesel oil and n-dodecane as collector, 2-octanol as frother, and sink-float separation tests using mixtures of carbon tetrachloride-benzene and carbon tetrachloride-bromoform as dense liquid. Different parameters including combustible recovery, ash content of the clean coal, separation efficiency, and energy consumption were investigated based on the two different preparation processes. The results show that the new preparation process has high combustible recovery, low ash content of the product, high separation efficiency, and low energy consumption compared with the traditional one. The comminution mechanism of high pressure water jet mill is introduced in this paper. The high pressure water jet comminution technique has great potential in coal pulverization, having the advantages of low energy consumption, low iron content, and low equipment wear. 35 refs., 4 figs., 7 tabs.

  16. Comparative kinetic analysis of raw and cleaned coals

    Energy Technology Data Exchange (ETDEWEB)

    Ozbas, K.E.; Kok, M.V.; Hicyilmaz, C.

    2002-07-01

    Thermogravimetry (TG/DTG) was used to determine the kinetic analysis of different coals and effect of cleaning process on kinetic parameters of raw and cleaned coal samples from Soma, Tuncbilek and Afsin Elbistan regions. Kinetic parameters of the samples were determined using Arrhenius and Coats and Redfern kinetic models and the results are discussed.

  17. An evaluation of Substitute natural gas production from different coal gasification processes based on modeling

    International Nuclear Information System (INIS)

    Coal and lignite will play a significant role in the future energy production. However, the technical options for the reduction of CO2 emissions will define the extent of their share in the future energy mix. The production of synthetic or substitute natural gas (SNG) from solid fossil fuels seems to be a very attractive process: coal and lignite can be upgraded into a methane rich gas which can be transported and further used in high efficient power systems coupled with CO2 sequestration technologies. The aim of this paper is to present a modeling analysis comparison between substitute natural gas production from coal by means of allothermal steam gasification and autothermal oxygen gasification. In order to produce SNG from syngas several unit operations are required such as syngas cooling, cleaning, potential compression and, of course, methanation reactors. Finally the gas which is produced has to be conditioned i.e. removal of unwanted species, such as CO2 etc. The heat recovered from the overall process is utilized by a steam cycle, producing power. These processes were modeled with the computer software IPSEpro™. An energetic and exergetic analysis of the coal to SNG processes have been realized and compared. -- Highlights: ► The production of SNG from coal is examined. ► The components of the process were simulated for integrated autothermal or allothermal coal gasification to SNG. ► The energetic and exergetic evaluation of the two processes is presented.

  18. Open-Cycle Gas Turbine/Steam Turbine Combined Cycles with synthetic fuels from coal

    Science.gov (United States)

    Shah, R. P.; Corman, J. C.

    1977-01-01

    The Open-Cycle Gas Turbine/Steam Turbine Combined Cycle can be an effective energy conversion system for converting coal to electricity. The intermediate step in this energy conversion process is to convert the coal into a fuel acceptable to a gas turbine. This can be accomplished by producing a synthetic gas or liquid, and by removing, in the fuel conversion step, the elements in the fuel that would be harmful to the environment if combusted. In this paper, two open-cycle gas turbine combined systems are evaluated: one employing an integrated low-Btu gasifier, and one utilizing a semi-clean liquid fuel. A consistent technical/economic information base is developed for these two systems, and is compared with a reference steam plant burning coal directly in a conventional furnace.

  19. Metal emission into the air from processes of energetic fuel utilization in Poland. Part 2. Burning of brown coal, coke, gas, fuel oil, wood

    International Nuclear Information System (INIS)

    Indicators of metal emission into atmospheric air from burning processes of the above mentioned fuels have been discussed and the emission size of these metals in Poland in 1990 given. (author). 7 refs, 1 fig., 3 tabs

  20. Clean Coal Technology Demonstration Program. Program update 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-04-01

    The Clean Coal Technology Demonstration Program (CCT Program) is a $7.14 billion cost-shared industry/government technology development effort. The program is to demonstrate a new generation of advanced coal-based technologies, with the most promising technologies being moved into the domestic and international marketplace. Clean coal technologies being demonstrated under the CCT program are creating the technology base that allows the nation to meet its energy and environmental goals efficiently and reliably. The fact that most of the demonstrations are being conducted at commercial scale, in actual user environments, and under conditions typical of commercial operations allows the potential of the technologies to be evaluated in their intended commercial applications. The technologies are categorized into four market sectors: advanced electric power generation systems; environmental control devices; coal processing equipment for clean fuels; and industrial technologies. Sections of this report describe the following: Role of the Program; Program implementation; Funding and costs; The road to commercial realization; Results from completed projects; Results and accomplishments from ongoing projects; and Project fact sheets. Projects include fluidized-bed combustion, integrated gasification combined-cycle power plants, advanced combustion and heat engines, nitrogen oxide control technologies, sulfur dioxide control technologies, combined SO{sub 2} and NO{sub x} technologies, coal preparation techniques, mild gasification, and indirect liquefaction. Industrial applications include injection systems for blast furnaces, coke oven gas cleaning systems, power generation from coal/ore reduction, a cyclone combustor with S, N, and ash control, cement kiln flue gas scrubber, and pulse combustion for steam coal gasification.

  1. Physical and chemical coal cleaning

    Science.gov (United States)

    Wheelock, T. D.; Markuszewski, R.

    1981-02-01

    Coal is cleaned industrially by freeing the occluded mineral impurities and physically separating the coal and refuse particles on the basis of differences in density, settling characteristics, or surface properties. While physical methods are very effective and low in cost when applied to the separation of coarse particles, they are much less effective when applied to the separation of fine particles. Also they can not be used to remove impurities which are bound chemically to the coal. These deficiencies may be overcome in the future by chemical cleaning. Most of the chemical cleaning methods under development are designed primarily to remove sulfur from coal, but several methods also remove various trace elements and ash-forming minerals. Generally these methods will remove most of the sulfur associated with inorganic minerals, but only a few of the methods seem to remove organically bound sulfur. A number of the methods employ oxidizing agents as air, oxygen, chlorine, nitrogen dioxide, or a ferric salt to oxidize the sulfur compounds to soluble sulfates which are then extracted with water. The sulfur in coal may also be solubilized by treatment with caustic. Also sulfur can be removed by reaction with hydrogen at high temperature. Furthermore, it is possible to transform the sulfur bearing minerals in coal to materials which are easily removed by magnetic separation.

  2. NEW SOLID FUELS FROM COAL AND BIOMASS WASTE; FINAL

    International Nuclear Information System (INIS)

    Under DOE sponsorship, McDermott Technology, Inc. (MTI), Babcock and Wilcox Company (B and W), and Minergy Corporation developed and evaluated a sludge derived fuel (SDF) made from sewage sludge. Our approach is to dry and agglomerate the sludge, combine it with a fluxing agent, if necessary, and co-fire the resulting fuel with coal in a cyclone boiler to recover the energy and to vitrify mineral matter into a non-leachable product. This product can then be used in the construction industry. A literature search showed that there is significant variability of the sludge fuel properties from a given wastewater plant (seasonal and/or day-to-day changes) or from different wastewater plants. A large sewage sludge sample (30 tons) from a municipal wastewater treatment facility was collected, dried, pelletized and successfully co-fired with coal in a cyclone-equipped pilot. Several sludge particle size distributions were tested. Finer sludge particle size distributions, similar to the standard B and W size distribution for sub-bituminous coal, showed the best combustion and slagging performance. Up to 74.6% and 78.9% sludge was successfully co-fired with pulverized coal and with natural gas, respectively. An economic evaluation on a 25-MW power plant showed the viability of co-firing the optimum SDF in a power generation application. The return on equity was 22 to 31%, adequate to attract investors and allow a full-scale project to proceed. Additional market research and engineering will be required to verify the economic assumptions. Areas to focus on are: plant detail design and detail capital cost estimates, market research into possible project locations, sludge availability at the proposed project locations, market research into electric energy sales and renewable energy sales opportunities at the proposed project location. As a result of this program, wastes that are currently not being used and considered an environmental problem will be processed into a renewable

  3. Modeling and optimization of processes for clean and efficient pulverized coal combustion in utility boilers

    Directory of Open Access Journals (Sweden)

    Belošević Srđan V.

    2016-01-01

    Full Text Available Pulverized coal-fired power plants should provide higher efficiency of energy conversion, flexibility in terms of boiler loads and fuel characteristics and emission reduction of pollutants like nitrogen oxides. Modification of combustion process is a cost-effective technology for NOx control. For optimization of complex processes, such as turbulent reactive flow in coal-fired furnaces, mathematical modeling is regularly used. The NOx emission reduction by combustion modifications in the 350 MWe Kostolac B boiler furnace, tangentially fired by pulverized Serbian lignite, is investigated in the paper. Numerical experiments were done by an in-house developed three-dimensional differential comprehensive combustion code, with fuel- and thermal-NO formation/destruction reactions model. The code was developed to be easily used by engineering staff for process analysis in boiler units. A broad range of operating conditions was examined, such as fuel and preheated air distribution over the burners and tiers, operation mode of the burners, grinding fineness and quality of coal, boiler loads, cold air ingress, recirculation of flue gases, water-walls ash deposition and combined effect of different parameters. The predictions show that the NOx emission reduction of up to 30% can be achieved by a proper combustion organization in the case-study furnace, with the flame position control. Impact of combustion modifications on the boiler operation was evaluated by the boiler thermal calculations suggesting that the facility was to be controlled within narrow limits of operation parameters. Such a complex approach to pollutants control enables evaluating alternative solutions to achieve efficient and low emission operation of utility boiler units. [Projekat Ministarstva nauke Republike Srbije, br. TR-33018: Increase in energy and ecology efficiency of processes in pulverized coal-fired furnace and optimization of utility steam boiler air preheater by using in

  4. Second annual clean coal technology conference: Proceedings

    International Nuclear Information System (INIS)

    This report contains paper on the following topics: coal combustion/coal processing; advanced electric power generation systems; combined nitrogen oxide/sulfur dioxide control technologies; and emerging clean coal issues and environmental concerns. These paper have been cataloged separately elsewhere

  5. Characteristics of American coals in relation to their conversion into clean-energy fuels. Final report. [1150 samples of US coals

    Energy Technology Data Exchange (ETDEWEB)

    Spackman, W.; Davis, A.; Walker, P.L.; Lovell, H.L.; Vastola, F.J.; Given, P.H.; Suhr, N.H.; Jenkins, R.G.

    1982-06-01

    To further characterize the Nation's coals, the Penn State Coal Sample Bank and Data Base were expanded to include a total of 1150 coal samples. The Sample Bank includes full-seam channel samples as well as samples of lithotypes, seam benches, and sub-seam sections. To the extent feasible and appropriate basic compositional data were generated for each sample and validated and computerized. These data include: proximate analysis, ultimate analysis, sulfur forms analysis, calorific value, maceral analysis, vitrinite reflectance analysis, ash fusion analysis, free-swelling index determination, Gray-King coke type determination, Hardgrove grindability determination, Vicker's microhardness determination, major and minor element analysis, trace element analysis, and mineral species analysis. During the contract period more than 5000 samples were prepared and distributed. A theoretical and experimental study of the pyrolysis of coal has been completed. The reactivity of chars, produced from all ranks of American coals, has been studied with regard to reactivity to air, CO/sub 2/, H/sub 2/ and steam. Another area research has concerned the catalytic effect of minerals and various cations on the gasification processes. Combustion of chars, low volatile fuels, coal-oil-water-air emulsions and other subjects of research are reported here. The products of this research can be found in 23 DOE Technical Research Reports and 49 published papers. As another mechanism of technology transfer, the results have been conveyed via more than 70 papers presented at a variety of scientific meetings. References to all of these are contained in this report.

  6. Clean-up and processing of coal-derived gas for hydrogen applications

    Science.gov (United States)

    Kasper, S.

    It appears that only a few large-scale industrial applications need to be examined for utilization of coal-derived hydrogen. Applications selected as representative for considerations of purification are related to ammonia, methanol, iron ore reduction, fuel cells, and pipeline gas. Purity requirements and raw gas composition are discussed, and a description of purification processes is provided. Attention is given to particulates, tar, ammonia and water, light oils, bulk acid gas removal, trace sulfur removal, carbon monoxide, hydrogen cyanide, cryogenic purification, and molecular sieves. In view of the very high purity requirements for many hydrogen applications, and the variety of undesirable components in the raw coal gas, the purification task may seem to be too formidable. However, the utilization of hydrogen gas for the production of methanol and ammonia in many countries proves that such a purification is economically feasible.

  7. Surface magnetic enhancement for coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, J.Y.

    1989-01-01

    The fundamental chemistry for selective adsorption of magnetizing reagent on coal-associated minerals to enhance the magnetic susceptibility of minerals have been established in Phase I study. The application of the results on coal cleaning is in progress in the Phase II study. The task in Phase II study for coal selection, preparation, and characterization is completed in this reporting period. The optimization of adsorption conditions for {minus}48 mesh ROM coals and flotation concentrates is about completed. Experiments have shown that successful coal cleaning can be obtained with this magnetizing reagent approach. The task to adapt the approach to various processing schemes is just initiated.

  8. WABASH RIVER IMPPCCT, INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES

    Energy Technology Data Exchange (ETDEWEB)

    Doug Strickland

    2001-09-28

    In a joint effort with the U.S. Department of Energy, working under a Cooperative Agreement Award from the ''Early Entrance Coproduction Plant'' (EECP) initiative, the Gasification Engineering Corporation and an Industrial Consortium are investigating the application of synthesis gas from the E-GAS{trademark} technology to a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an Early Entrance Coproduction Plant located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, financial, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry. The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), and supported by Air Products and Chemicals Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution, including: (1) Feasibility Study and conceptual design for an integrated demonstration facility and for fence-line commercial plants operated at The Dow Chemical Company or Dow Corning Corporation chemical plant locations (i.e. the Commercial Embodiment Plant or CEP) (2) Research, development, and testing to address any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial

  9. Optimization of a Multi Gravity Separator to produce clean coal from Turkish lignite fine coal tailings

    Energy Technology Data Exchange (ETDEWEB)

    Selcuk Ozgen; Ozkan Malkoc; Ceyda Dogancik; Eyup Sabah; Filiz Oruc Sapci [Afyon Kocatepe University, Afyonkarahisar (Turkey). Department of Mining Engineering

    2011-04-15

    In this study, the beneficiation of two lignite tailings by Multi Gravity Separator (MGS) was investigated. The tailings samples from the Tuncbilek/Kutahya and Soma/Manisa regions have ash contents of 66.21% and 52.65%, respectively. Significant operational parameters of MGS such as solid ratio, drum speed, tilt angle, shaking amplitude, wash water rate, and feed rate were varied. Empirical equations for recovery and ash content were derived by a least squares method using Minitab 15. The equations, which are second-order response functions, were expressed as functions of the six operating parameters of MGS. The results showed that it is possible to produce a coal concentrate containing 22.83% ash with a recovery of 49.32% from Tuncbilek coal tailings, and a coal concentrate containing 22.89% ash with a recovery of 60.01% from Soma coal tailings. 27 refs., 6 figs., 5 tabs.

  10. Effects of consumer subsidy on household fuel switching from coal to cleaner fuels: a case study for anthracites in Korea

    Energy Technology Data Exchange (ETDEWEB)

    Hojeong Park; Hyucksoo Kwon [Korea University, Seoul (Republic of Korea). Department of Food and Resource Economics

    2011-03-15

    The Korean coal industry is in a transition under low carbon policy through the steady reduction of coal production. Since consumer subsidy for the consumption of anthracites briquette in low-income households caused a distortion in domestic coal market, the so-called coupon program will be the first target in energy reform policy in order to induce fuel switching from anthracites to alternative clean energy. This paper tries to identify various factors that influence households' fuel switching decision. Disutility from briquette consumption is also considered as an important factor. Using the 2007 census data on briquette-consuming households, it is found that the coupon program provides an adverse effect to switching fuels to clean energy while the disutility of briquettes is positively associated with the probability of fuel switching. However, the empirical finding suggests that the policy alone attempting to remove coupon program may fail to switch fuels unless the cost of boiler changes is substantially reduced through the provision of accessible networks to alternative energy sources. It indicates that reform policy for consumer subsidy must be understood in line with more comprehensive regional energy plans to resolve energy poverty issue. 8 refs., 4 tabs.

  11. Wanted: Clean Coal Burning Technology

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    China is intent on developing clean coal burning technology, an objective it can achieve through installing desulfurization facilities at coal-burning power plants that will control SO2 emissions and environmental pollution. According to kuo Yi, deputy director general of the Department of Science and Technology of the State Environmental Protection Agency, China is a major coal-buming country:

  12. Clean fuel technology for world energy security

    Energy Technology Data Exchange (ETDEWEB)

    Sunjay, Sunjay

    2010-09-15

    Clean fuel technology is the integral part of geoengineering and green engineering with a view to global warming mitigation. Optimal utilization of natural resources coal and integration of coal & associated fuels with hydrocarbon exploration and development activities is pertinent task before geoscientist with evergreen energy vision with a view to energy security & sustainable development. Value added technologies Coal gasification,underground coal gasification & surface coal gasification converts solid coal into a gas that can be used for power generation, chemical production, as well as the option of being converted into liquid fuels.

  13. Clean utilization of low-rank coals for low-cost power generation

    International Nuclear Information System (INIS)

    Despite the unique utilization problems of low-rank coals, the ten US steam electric plants having the lowest operating cost in 1990 were all fueled on either lignite or subbituminous coal. Ash deposition problems, which have been a major barrier to sustaining high load on US boilers burning high-sodium low-rank coals, have been substantially reduced by improvements in coal selection, boiler design, on-line cleaning, operating conditions, and additives. Advantages of low-rank coals in advanced systems are their noncaking behavior when heated, their high reactivity allowing more complete reaction at lower temperatures, and the low sulfur content of selected deposits. The principal barrier issues are the high-temperature behavior of ash and volatile alkali derived from the coal-bound sodium found in some low-rank coals. Successful upgrading of low-rank coals requires that the product be both stable and suitable for end use in conventional and advanced systems. Coal-water fuel produced by hydrothermal processing of high-moisture low-rank coal meets these criteria, whereas most dry products from drying or carbonizing in hot gas tend to create dust and spontaneous ignition problems unless coated, agglomerated, briquetted, or afforded special handling

  14. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    Energy Technology Data Exchange (ETDEWEB)

    Albert Tsang

    2003-03-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over several years, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana.

  15. Prospects for coal and clean coal technology in the Philippines

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-03-15

    This report examines the current energy outlook for the Philippines in regard not only to coal but also other energy resources. The history of the power sector, current state of play and future plans to meet the increasing energy demand from a growing population are discussed. There is also analysis of the trends for coal demand and production, imports and exports of coal and the types of coal-fired power stations that have been built. This includes examination of the legislation involving coal and the promotion of clean coal technologies.

  16. Membrane-integrated oxy-fuel combustion of coal: Process design and simulation

    NARCIS (Netherlands)

    Chen, Wei; Ham, van der A.G.J.; Nijmeijer, A.; Winnubst, A.J.A.

    2015-01-01

    A membrane-integrated oxy-fuel combustion process is designed and simulated in UniSim Design®. The results of the simulation indicate that a net efficiency of 31.8% is obtained for a coal-fired power plant of 182 MWth (assuming only carbon in the coal), including the compression of CO2 to 100 bar. T

  17. Advanced physical fine coal cleaning spherical agglomeration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1990-09-01

    The project included process development, engineering, construction, and operation of a 1/3 tph proof-of-concept (POC) spherical agglomeration test module. The POC tests demonstrated that physical cleaning of ultrafine coal by agglomeration using heptane can achieve: (1) Pyritic sulfur reductions beyond that possible with conventional coal cleaning methods; (2) coal ash contents below those which can be obtained by conventional coal cleaning methods at comparable energy recoveries; (3) energy recoveries of 80 percent or greater measured against the raw coal energy content; (4) complete recovery of the heptane bridging liquid from the agglomerates; and (5) production of agglomerates with 3/8-inch size and less than 30 percent moisture. Test results met or exceeded all of the program objectives. Nominal 3/8-inch size agglomerates with less than 20 percent moisture were produced. The clean coal ash content varied between 1.5 to 5.5 percent by weight (dry basis) depending on feed coal type. Ash reductions of the run-of-mine (ROM) coal were 77 to 83 percent. ROM pyritic sulfur reductions varied from 86 to 90 percent for the three test coals, equating to total sulfur reductions of 47 to 72 percent.

  18. Principles of processes used for coal gas cleaning and recovery of chemical products of coking. Part II. [Poland

    Energy Technology Data Exchange (ETDEWEB)

    Ulatowski, R.

    1983-02-01

    This paper discusses removal of tars, ammonia, benzene and desulfurization of coal gas from black coal coking. About 30% of coal gas produced by coking plants in Poland is desulfurized. The average content of hydrogen sulfide in coal gas ranges from 6 to 8 g/m/sup 3/. After desulfurization hydrogen sulfur content does not exceed 0.2 g/m/sup 3/. Two processes are used in Poland for coal gas desulfurization: the vacuum carbonate process and the Thylox process. Chemical reactions during gas desulfurization with the two processes are discussed. Regeneration systems, productivity and efficiency of gas desulfurization using the two processes are compared. The following processes used in other countries are comparatively evaluated: the Fumaks-Rodax process in Japan, the Perox process, the Stretford process, the Sulfiban process in the USA and the Claus process.

  19. KNFC Fuel cleaning technology development

    International Nuclear Information System (INIS)

    The filtration system to collect crud particles detached from the fuel assemblies was also developed. The fuel cleaning system connected with the filtration system was successfully demonstrated at Ulchin plant 2. Within several minutes detachable crud deposits were effectively removed from the clad surfaces of the fuel assembly. Also to characterize the crud particles for each fuel assembly, a small crud sampling device was connected with the filtration system during the cleaning operation. Crud samples were acquired from crud sampling device of fuel cleaning and fuel rod using sticky tape and steel knife analysis at two plants, respectively. Crud analysis in pie facility showed that 95wt% crud particles can be collected by a 0.5μm filtering system and major compositions were Ni, Fe, and Cr. KNFC constructed and qualified the complete fuel cleaning system

  20. Synthesis and characterization of zeolite from waste coal flyash for tailored application in bio-refining and process water cleaning: An innovative approach towards a cleaner circular economy

    OpenAIRE

    Das, Gaurav

    2016-01-01

    The purpose of the investigation was to assess if Finnish coal flyash (CFA) waste could be used to synthesize zeolites. The world produces 750 million tonnes of CFA annually which is also the largest quantity waste produced. This figure will only increase as India, China, South America and Africa charges ahead with industrialization. The global recycle rate is 15% annually. Finland produces about 750,000 tonnes of CFA per year. It is also estimated that millions of tonnes of CFA is backfilled...

  1. Management of solid wastes from the Limestone Injection Dry Scrubbing (LIDS) clean coal technology. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Musiol, W.F. Jr.; Czuczwa, J.M.

    1993-03-01

    The objectives of this project were to characterize by-products from a pilot Limestone Injection Dry Scrubbing (LIDS) process and to develop processes directed toward the safe and economic use or disposal of these wastes. Because LIDS is a developing Clean Coal technology, a database of chemical and physical characteristics of the by-product was first developed. During the course of this project, it was found that the waste alone did not form high-strength products sufficient for use in construction and engineering applications. Therefore, the project was redirected to evaluate the by-product as a soil-cement and Portland cement raw material, agricultural liming agent, backfill/landfill material component, and mine reclamation/neutralizing agent. Based on these evaluations, the most viable uses for the LIDS byproduct include use in mine reclamation or as a neutralization agent. If soluble sulfites can be minimized by avoiding a dolomitic LIDS reagent, use as an agricultural liming agent has promise. Interest from an Ohio utility in the LIDS process suggests possible application of results at the demonstration or commercial stages.

  2. Clean coal technology demonstration program: Program update 1996-97

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    The Clean Coal Technology Demonstration Program (known as the CCT Program) reached a significant milestone in 1996 with the completion of 20 of the 39 active projects. The CCT Program is responding to a need to demonstrate and deploy a portfolio of technologies that will assure the U.S. recoverable coal reserves of 297 billion tons could continue to supply the nation`s energy needs economically and in a manner that meets the nation`s environmental objectives. This portfolio of technologies includes environmental control devices that contributed to meeting the accords on transboundary air pollution recommended by the Special Envoys on Acid Rain in 1986. Operational, technical, environmental, and economic performance information and data are now flowing from highly efficient, low-emission, advanced power generation technologies that will enable coal to retain its prominent role into the next millennium. Further, advanced technologies are emerging that will enhance the competitive use of coal in the industrial sector, such as in steelmaking. Coal processing technologies will enable the entire coal resource base to be used while complying with environmental requirements. These technologies are producing products used by utilities and industrial processes. The capability to coproduce products, such as liquid and solid fuels, electricity, and chemicals, is being demonstrated at a commercial scale by projects in the CCT Program. In summary, this portfolio of technologies is satisfying the national need to maintain a multifuel energy mix in which coal is a key component because of its low-cost, availability, and abundant supply within the nation`s borders.

  3. Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  4. Upgrading of brown coal by slurry-dewatering; Kattan no yuchu dassui ni yoru clean kotai nenryo no seizo

    Energy Technology Data Exchange (ETDEWEB)

    Okuma, O.; Shimizu, T.; Inoue, T.; Shigehisa, T.; Deguchi, T.; Katsushima, S. [Kobe Steel, Ltd., Kobe (Japan)

    1996-10-28

    This paper describes an outline of solid fuel production process from brown coal and the investigation results of its elemental techniques. Dried coal is produced by this process which consists of a dewatering of crushed brown coal in oil-based solvent, a solid and liquid separation of slurry, and a remained oil recovery by heating. This process is characterized by the higher thermal efficiency compared with usual drying and the restraint of spontaneous combustion of product coal. It was revealed that solid fuel with low moisture, low ash, low sulfur, and suppressed spontaneous combustion property can be produced from Australian brown coal through this process. From the comparison between kerosene and fuel oil A, it was confirmed that the oil content during dewatering was smaller and the oil recovery by heating was easier by using a solvent with lower boiling point. It was also confirmed that the spontaneous combustion property can be suppressed using small amount of asphalt by solving asphalt in the solvent and adsorbing asphalt on the surface of brown coal. From these results, low rank coals including brown coal, which are difficult to use, are expected to be used as clean coal with low ash and low sulfur through this process. 2 refs., 7 figs., 2 tabs.

  5. Corrosion behaviour of the tool steel of the fuel charge machine during cleaning process

    International Nuclear Information System (INIS)

    In the framework of the experimentation activity of the PEC Reactor components, presently in course at the Casaccia Energy Research Centre (CRE Casaccia), the sodium removal process has been usually carried out by means of Butylcellosolve. Recently, in order to eliminate flammable organic solvent from the reactor building, it was decided to evaluate the possibility of using an atomized water method for the cleaning of the Fuel Charge Machine (FCM). Two important problems have been immediately identified: - lower removal process efficiency; since the geometries of the PEC Reactor FCM are complex, there are a number of areas of retention, where liquid access is difficult, - component damage due to the corrosion process. The main risk is associated with the formation of aqueous NaOH which can give rise to caustic stress corrosion cracking. In order to know something more about the above mentioned problems, a test programme was designed whose main aims were: - cleaning tests efficiency determination of gripper prototype by atomized water method using nitrogen gas or alternatively carbon dioxide; - study of the corrosion behaviour of tool steel in caustic solutions. This paper reports the results of the corrosion tests

  6. Development of clean coal and clean soil technologies using advanced agglomeration techniques

    Energy Technology Data Exchange (ETDEWEB)

    Ignasiak, B.; Ignasiak, T.; Szymocha, K.

    1990-01-01

    Three major topics are discussed in this report: (1) Upgrading of Low Rank Coals by the Agflotherm Process. Test data, procedures, equipment, etc., are described for co-upgrading of subbituminous coals and heavy oil; (2) Upgrading of Bituminous Coals by the Agflotherm Process. Experimental procedures and data, bench and pilot scale equipments, etc., for beneficiating bituminous coals are described; (3) Soil Clean-up and Hydrocarbon Waste Treatment Process. Batch and pilot plant tests are described for soil contaminated by tar refuse from manufactured gas plant sites. (VC)

  7. Development of clean coal and clean soil technologies using advanced agglomeration techniques

    International Nuclear Information System (INIS)

    Three major topics are discussed in this report: (1) Upgrading of Low Rank Coals by the Agflotherm Process. Test data, procedures, equipment, etc., are described for co-upgrading of subbituminous coals and heavy oil; (2) Upgrading of Bituminous Coals by the Agflotherm Process. Experimental procedures and data, bench and pilot scale equipments, etc., for beneficiating bituminous coals are described; (3) Soil Clean-up and Hydrocarbon Waste Treatment Process. Batch and pilot plant tests are described for soil contaminated by tar refuse from manufactured gas plant sites. (VC)

  8. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 9, October 1, 1994--December 31, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C. [AMAX Research and Development Center, Golden, CO (United States)

    1995-01-25

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by design, and construction of a 2-t/hr process development unit (PDU). The PDU will then be operated to generate 200 ton lots of each of three project coals, by each process. The project began in October, 1992 and is scheduled for completion by March, 1997. During Quarter 9 (October--December, 1995), parametric and optimization testing was completed for the Taggart, Sunnyside, and Indiana VII coal using a 12-inch Microcel{trademark} flotation column. The detailed design of the 2-t/hr PDU grinding, flotation, and dewatering circuits neared completion with the specification of the major pieces of capital equipment to be purchased for these areas. Selective agglomeration test work investigated the properties of various industrial grades of heptane for use during bench- and PDU-scale testing. It was decided to use a hydrotreated grade of commercial heptane due to its low cost and low concentration of aromatic compounds. The final Subtask 6.4 CWF Formulation Studies Test Plan was issued. A draft version of the Subtask 6.5 Preliminary Design and Test Plan Report was also issued, discussing the progress made in the design of the bench-scale selective agglomeration unit. PDU construction work moved forward through the issuing of 26 request for quotations and 21 award packages for capital equipment.

  9. Proceedings of a workshop on the utilization of coal fuels in process heaters

    Energy Technology Data Exchange (ETDEWEB)

    1979-01-01

    Almost 5% of the nation's energy consumption takes place in tubular process heaters. Currently, these units are gas- and, to a lesser extent, oil-fired. Process heaters provide energy for refining petroleum and the manufacture of numerous chemicals and petrochemicals. Since the current state-of-the-art, using waste heat recovery and forced draft burners, can achieve thermal efficiencies of about 90%, it is unlikely that current process heat and fuel requirements will be dramatically reduced by process modifications and/or conservation measures. Hence, if this sizeable, inexorable drain on our fluid petroleum reserves is to be halted, it seems reasonable to consider the utilization of coal and/or coal-based fuels to fire process heaters. In order to assess the feasibility and potential for a coal-based process heater industry, Brookhaven National Laboratory (BNL) organized a workshop to define and explore the various problems that must be solved in order to burn coal in process heaters. A primary aim of the workshop was to consider the design methodology for process heaters when firing coal and compare it to those for gas and oil firing. The overall conclusions were: that retrofitting present process heaters to coal fuel was impractical; that it would be difficult to fit larger heaters designed to burn coal into present refineries; that there would be difficulties with process heaters burning coal; and that a better approach would be one large utility coal heater with a circulating heat transfer medium. Seven papers have been entered individually into EDB and ERA. (LTN)

  10. Clean coal technology

    International Nuclear Information System (INIS)

    This paper shows data of current and projected SO2 emissions, ambient pollution in major Asian cities; Benefits of natural gas Use in Power Generation; Efficiency of thermal power plants in India and China. It discusses Coal Benefitiation meaning use of high efficiency coal technologies i.e. reducing particulate emissions

  11. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2004-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

  12. Coal-water slurry as utility boiler fuel. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Scheffee, R.S.; Boyd, T.J.; Rossmeissl, N.P.; McHale, E.T.; Henderson, C.B.; Glenn, R.D.

    1982-03-01

    Coal-water slurries are a potential replacement for heavy fuel oil in utility boilers. Slurries have the major advantages of low cost, ease of handling, and early availability. A program was conducted to characterize the formulation, processing, handling, combustion, and storage of coal-water slurries made from cleaned coals. Acceptable slurries containing between 67 and 70% coal (by weight) were made from two different coals. A selected slurry was burned with good results in the Atlantic Research Corporation's one-million Btu/h experimental furnace. Approximately five tons (4,500 kg) of slurry were prepared on a pilot line for testing in the four-million Btu/h Babcock and Wilcox Basic Combustion Test Unit. A plant flowsheet was developed for a slurry plant designed to process five-million tons (4.5 x 10/sup 9/ kg) of coal a year. Total plant investment is estimated at $104-million (1980). Assuming a delivered coal cost of $50/ton (800 kg), the production costs are estimated to be $58/ton of coal or $2.14/million Btu. This cost compares favorably to a cost of $4.76/million Btu for heavy fuel oil at $30/barrel. These costs exclude certain ancillary costs such as marketing, fees and permits, insurance, interest on capital, profit, local taxes, and corporate income tax.

  13. Clean Coal Technologies - Accelerating Commerical and Policy Drivers for Deployment

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    Coal is and will remain the world's most abundant and widely distributed fossil fuel. Burning coal, however, can pollute and it produces carbon dioxide. Clean coal technologies address this problem. The widespread deployment of pollution-control equipment to reduce sulphur dioxide, Nox and dust emissions from industry is just one example which has brought cleaner air to many countries. Since the 1970s, various policy and regulatory measures have created a growing commercial market for these clean coal technologies, with the result that costs have fallen and performance has improved. More recently, the need to tackle rising CO2 emissions to address climate change means that clean coal technologies now extend to include those for CO2 capture and storage (CCS). This short report from the IEA Coal Industry Advisory Board (CIAB) presents industry's considered recommendations on how to accelerate the development and deployment of this important group of new technologies and to grasp their very signifi cant potential to reduce emissions from coal use. It identifies an urgent need to make progress with demonstration projects and prove the potential of CCS through government-industry partnerships. Its commercialisation depends upon a clear legal and regulatory framework,public acceptance and market-based financial incentives. For the latter, the CIAB favours cap-and-trade systems, price supports and mandatory feed-in tariffs, as well as inclusion of CCS in the Kyoto Protocol's Clean Development Mechanism to create demand in developing economies where coal use is growing most rapidly. This report offers a unique insight into the thinking of an industry that recognises both the threats and growing opportunities for coal in a carbon constrained world.

  14. Process for converting coal into liquid fuel and metallurgical coke

    Science.gov (United States)

    Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  15. Coal surface control for advanced physical fine coal cleaning technologies

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-01-01

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  16. Combined Removal of Surface Moisture and Dust from Feed Coal for Coal Dry Cleaning with an Air-solid Fluidized Bed

    Institute of Scientific and Technical Information of China (English)

    YANG Guo-hua; ZHAO Yue-min; CHEN Qing-ru

    2005-01-01

    A demonstration plant and a commercial plant employing coal dry cleaning technology with an air-solid fluidized bed were built in China. The operation practice of these two plants shows that the surface moisture and the fines or dust of feed coal must be well controlled as low as possible. For this purpose, a new process of combined removal of surface moisture and dust from feed coal using a vibrated fluidized bed dryer was investigated in a batch test apparatus and a pilot test system. A mathematical model on drying kinetics of coal surface moisture was developed and three empirical formulas of the model coefficient involving the main operating variables were determined based on the test results from the batch test apparatus. The mathematical model shows that the surface moisture retained in coal during drying decreases exponentially with drying time. According to this model, a new divisional heat supply mode, in which the inlet gas of higher temperature was introduced into the fore part of the dryer and the inlet gas of lower temperature into the rear part of the dryer, was employed in the pilot test system. The pilot tests show that 1) the new divisional heat supply mode is effective for lowering down the average temperature and reducing the total heat loss of the outlet gas off the dryer, 2) the moist coal of about 60 g/kg surface moisture contentcan be dried to about 10 g/kg, and simultaneously the fines (<1mm in diameter) adhering to the surface of coarse coal particles are completely washed off by the gas flow.

  17. Appalachian clean coal technology consortium

    Energy Technology Data Exchange (ETDEWEB)

    Kutz, K.; Yoon, Roe-Hoan [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States)

    1995-11-01

    The Appalachian Clean Coal Technology Consortium (ACCTC) has been established to help U.S. coal producers, particularly those in the Appalachian region, increase the production of lower-sulfur coal. The cooperative research conducted as part of the consortium activities will help utilities meet the emissions standards established by the 1990 Clean Air Act Amendments, enhance the competitiveness of U.S. coals in the world market, create jobs in economically-depressed coal producing regions, and reduce U.S. dependence on foreign energy supplies. The research activities will be conducted in cooperation with coal companies, equipment manufacturers, and A&E firms working in the Appalachian coal fields. This approach is consistent with President Clinton`s initiative in establishing Regional Technology Alliances to meet regional needs through technology development in cooperation with industry. The consortium activities are complementary to the High-Efficiency Preparation program of the Pittsburgh Energy Technology Center, but are broader in scope as they are inclusive of technology developments for both near-term and long-term applications, technology transfer, and training a highly-skilled work force.

  18. Preparation and combustion of coal-water fuel from the Sin Pun coal deposit, southern Thailand

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    In response to an inquiry by the Department of Mineral Resources in Thailand, the Energy & Environmental Research Center (EERC) prepared a program to assess the responsiveness of Sin Pun lignite to the temperature and pressure conditions of hot-water drying. The results indicate that drying made several improvements in the coal, notably increases in heating value and carbon content and reductions in equilibrium moisture and oxygen content. The equilibrium moisture content decreased from 27 wt% for the raw coal to about 15 wt% for the hot-water-dried (HWD) coals. The energy density for a pumpable coal-water fuel (CWF) indicates an increase from 4500 to 6100 Btu/lb by hot-water drying. Approximately 650 lb of HWD Sin Pun CWF were fired in the EERC`s combustion test facility. The fuel burned extremely well, with no feed problems noted during the course of the test. Fouling and slagging deposits each indicated a very low rate of ash deposition, with only a dusty layer formed on the cooled metal surfaces. The combustor was operated at between 20% and 25% excess air, resulting in a flue gas SO{sub 2} concentration averaging approximately 6500 parts per million.

  19. Clean fuel for demanding environmental markets

    Energy Technology Data Exchange (ETDEWEB)

    Josewicz, W.; Natschke, D.E. [Acurex Environmental Corp., Research Triangle Park, NC (United States)

    1995-12-31

    Acurex Environmental Corporation is bringing Clean Fuel to the environmentally demand Krakow market, through the cooperative agreement with the U.S. Department of Energy. Clean fuel is a proprietary clean burning coal-based energy source intended for use in stoves and hand stoked boilers. Clean Fuel is a home heating fuel that is similar in form and function to raw coal, but is more environmentally friendly and lower in cost. The heating value of Clean Fuel is 24,45 kJ/kg. Extensive sets of confirmation runs were conducted in the Academy of Mining and Metallurgy in the Krakow laboratories. It demonstrated up to 54 percent reduction of particulate matter emission, up to 35 percent reduction of total hydrocarbon emissions. Most importantly, polycyclic aromatic hydrocarbons (toxic and carcinogens compounds) emissions were reduced by up to 85 percent, depending on species measured. The above comparison was made against premium chunk coal that is currently available in Krakow for approximately $83 to 93/ton. Clean Fuel will be made available in Krakow at a price approximately 10 percent lower than that of the premium chunk coal.

  20. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation

    Energy Technology Data Exchange (ETDEWEB)

    1990-01-01

    a study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery. This document is the eighth quarterly report prepared in accordance with the project reporting requirements covering the period from July 1,1990 to September 30, 1990. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. The data from the basic research on coal surfaces, bench scale testing and proof-of-concept scale testing will be utilized to design a final conceptual flowsheet. The economics of the flowsheet will be determined to enable industry to assess the feasibility of incorporating the advanced fine coal cleaning technology into the production of clean coal for generating electricity. 22 figs., 11 tabs.

  1. Development of high energy density fuels from mild gasification of coal

    Energy Technology Data Exchange (ETDEWEB)

    Greene, Marvin

    1991-12-01

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily skimmed'' from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  2. Development of high energy density fuels from mild gasification of coal. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1991-12-01

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily ``skimmed`` from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  3. Technical support for the Ohio Clean Coal Technology Program. Volume 2, Baseline of knowledge concerning process modification opportunities, research needs, by-product market potential, and regulatory requirements: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L. [Battelle, Columbus, OH (United States)

    1989-08-28

    This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LR1 and comprises two volumes. Volume 1 presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume 2 consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

  4. A Medium-Scale 50 MW fuel Biomass Gasification Based Bio-SNG Plant: A Developed Gas Cleaning Process

    OpenAIRE

    Ramiar Sadegh-Vaziri; Marko Amovic; Rolf Ljunggren; Klas Engvall

    2015-01-01

    Natural gas is becoming increasingly important as a primary energy source. A suitable replacement for fossil natural gas is bio-SNG, produced by biomass gasification, followed by methanation. A major challenge is efficient gas cleaning processes for removal of sulfur compounds and other impurities. The present study focuses on development of a gas cleaning step for a product gas produced in a 50 MW fuel gasification system. The developed gas cleaning washing process is basically a modificatio...

  5. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for

  6. Processes of elimination of activated corrosion products. Chemical decontamination - fuel cleaning

    International Nuclear Information System (INIS)

    The abatement of the individual and collective dose of a PWR imposes to control the source term through different processes implemented during the plant exploitation. When the limits of these different optimization processes are reached, the abatement of dose rates requires the implementation of curative processes. The objective is thus to eliminate the contaminated oxides and deposits present on surfaces free of radiation flux, and eventually on surfaces under radiation flux and on the fuel itself. The chemical decontamination of equipments and systems is the main and universal remedy implemented at different levels. On the other hand, the ultrasonic cleaning of fuel assemblies is a promising process. This paper aims at illustrating these different techniques using concrete examples of application in France and abroad (decontamination during steam generator replacement, decontamination of primary pump scroll in hot workshop, decontamination of loop sections, ultrasonic cleaning of fuel). The description of these different operations stresses on their efficiency in terms of dosimetric gain, duration of implementation, generation of wastes, and recontamination following their implementation. (J.S.)

  7. Synthesis and analysis of jet fuel from shale oil and coal syncrudes

    Science.gov (United States)

    Gallagher, J. P.; Collins, T. A.; Nelson, T. J.; Pedersen, M. J.; Robison, M. G.; Wisinski, L. J.

    1976-01-01

    Thirty-two jet fuel samples of varying properties were produced from shale oil and coal syncrudes, and analyzed to assess their suitability for use. TOSCO II shale oil and H-COAL and COED syncrudes were used as starting materials. The processes used were among those commonly in use in petroleum processing-distillation, hydrogenation and catalytic hydrocracking. The processing conditions required to meet two levels of specifications regarding aromatic, hydrogen, sulfur and nitrogen contents at two yield levels were determined and found to be more demanding than normally required in petroleum processing. Analysis of the samples produced indicated that if the more stringent specifications of 13.5% hydrogen (min.) and 0.02% nitrogen (max.) were met, products similar in properties to conventional jet fuels were obtained. In general, shale oil was easier to process (catalyst deactivation was seen when processing coal syncrudes), consumed less hydrogen and yielded superior products. Based on these considerations, shale oil appears to be preferred to coal as a petroleum substitute for jet fuel production.

  8. Economic Feasibility Of Clean Coal Technologies

    OpenAIRE

    Marroquín, Miguel; Clemente Jul, María del Carmen

    2009-01-01

    Reéent developments in the energy sector prove that we are wítnessing a shift in the place of commodities withm global economy. Coal as a source of heat and power has kept and is meant to keep its hegemony in Europe and the USA; this along with recent encouraged fight against global warming and the factual lower yield of coal teclmologies claims for the review of these and the development of lesspollutant processes per uñií of useful energy, so-called Clean Coal Technologies. This document pr...

  9. COST BENEFITS ASSOCIATED WITH THE USE OF PHYSICALLY CLEANED COAL

    Science.gov (United States)

    The report identifies and quantifies several benefits associated with the use of physically cleaned coal in the operation of utility electric power plants. The benefits occur in: coal and ash handling, boiler operation, and gas handling and cleaning. Cleaning removes sulfur from ...

  10. Transport fuels from two-stage coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Benito, A.; Cebolla, V.; Fernandez, I.; Martinez, M.T.; Miranda, J.L.; Oelert, H.; Prado, J.G. (Instituto de Carboquimica CSIC, Zaragoza (Spain))

    1994-03-01

    Four Spanish lignites and their vitrinite concentrates were evaluated for coal liquefaction. Correlationships between the content of vitrinite and conversion in direct liquefaction were observed for the lignites but not for the vitrinite concentrates. The most reactive of the four coals was processed in two-stage liquefaction at a higher scale. First-stage coal liquefaction was carried out in a continuous unit at Clausthal University at a temperature of 400[degree]C at 20 MPa hydrogen pressure and with anthracene oil as a solvent. The coal conversion obtained was 75.41% being 3.79% gases, 2.58% primary condensate and 69.04% heavy liquids. A hydroprocessing unit was built at the Instituto de Carboquimica for the second-stage coal liquefaction. Whole and deasphalted liquids from the first-stage liquefaction were processed at 450[degree]C and 10 MPa hydrogen pressure, with two commercial catalysts: Harshaw HT-400E (Co-Mo/Al[sub 2]O[sub 3]) and HT-500E (Ni-Mo/Al[sub 2]O[sub 3]). The effects of liquid hourly space velocity (LHSV), temperature, gas/liquid ratio and catalyst on the heteroatom liquids, and levels of 5 ppm of nitrogen and 52 ppm of sulphur were reached at 450[degree]C, 10 MPa hydrogen pressure, 0.08 kg H[sub 2]/kg feedstock and with Harshaw HT-500E catalyst. The liquids obtained were hydroprocessed again at 420[degree]C, 10 MPa hydrogen pressure and 0.06 kg H[sub 2]/kg feedstock to hydrogenate the aromatic structures. In these conditions, the aromaticity was reduced considerably, and 39% of naphthas and 35% of kerosene fractions were obtained. 18 refs., 4 figs., 4 tabs.

  11. Second annual clean coal technology conference: Proceedings

    International Nuclear Information System (INIS)

    The Second Annual Clean Coal Technology Conference was held at Atlanta, Georgia, September 7--9, 1993. The Conference, cosponsored by the US Department of Energy (USDOE) and the Southern States Energy Board (SSEB), seeks to examine the status and role of the Clean Coal Technology Demonstration Program (CCTDP) and its projects. The Program is reviewed within the larger context of environmental needs, sustained economic growth, world markets, user performance requirements and supplier commercialization activities. This will be accomplished through in-depth review and discussion of factors affecting domestic and international markets for clean coal technology, the environmental considerations in commercial deployment, the current status of projects, and the timing and effectiveness of transfer of data from these projects to potential users, suppliers, financing entities, regulators, the interested environmental community and the public. Individual papers have been entered separately

  12. The economic production of alcohol fuels from coal-derived synthesis gas

    Energy Technology Data Exchange (ETDEWEB)

    Kugler, E.L.; Dadyburjor, D.B.; Yang, R.Y.K. [West Virginia Univ., Morgantown, WV (United States)] [and others

    1995-12-31

    The objectives of this project are to discover, (1) study and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas. Specifically, alternative methods of preparing catalysts are to be investigated, and novel catalysts, including sulfur-tolerant ones, are to be pursued. (Task 1); (2) explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. (Task 1); (3) simulate by computer the most energy efficient and economically efficient process for converting coal to energy, with primary focus on converting syngas to fuel alcohols. (Task 2); (4) develop on the bench scale the best holistic combination of chemistry, catalyst, reactor and total process configuration integrated with the overall coal conversion process to achieve economic optimization for the conversion of syngas to liquid products within the framework of achieving the maximum cost effective transformation of coal to energy equivalents. (Tasks 1 and 2); and (5) evaluate the combustion, emission and performance characteristics of fuel alcohols and blends of alcohols with petroleum-based fuels. (Task 2)

  13. Removal of mercury from coal via a microbial pretreatment process

    Science.gov (United States)

    Borole, Abhijeet P.; Hamilton, Choo Y.

    2011-08-16

    A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

  14. Clean Coal Program Research Activities

    Energy Technology Data Exchange (ETDEWEB)

    Larry Baxter; Eric Eddings; Thomas Fletcher; Kerry Kelly; JoAnn Lighty; Ronald Pugmire; Adel Sarofim; Geoffrey Silcox; Phillip Smith; Jeremy Thornock; Jost Wendt; Kevin Whitty

    2009-03-31

    Although remarkable progress has been made in developing technologies for the clean and efficient utilization of coal, the biggest challenge in the utilization of coal is still the protection of the environment. Specifically, electric utilities face increasingly stringent restriction on the emissions of NO{sub x} and SO{sub x}, new mercury emission standards, and mounting pressure for the mitigation of CO{sub 2} emissions, an environmental challenge that is greater than any they have previously faced. The Utah Clean Coal Program addressed issues related to innovations for existing power plants including retrofit technologies for carbon capture and sequestration (CCS) or green field plants with CCS. The Program focused on the following areas: simulation, mercury control, oxycoal combustion, gasification, sequestration, chemical looping combustion, materials investigations and student research experiences. The goal of this program was to begin to integrate the experimental and simulation activities and to partner with NETL researchers to integrate the Program's results with those at NETL, using simulation as the vehicle for integration and innovation. The investigators also committed to training students in coal utilization technology tuned to the environmental constraints that we face in the future; to this end the Program supported approximately 12 graduate students toward the completion of their graduate degree in addition to numerous undergraduate students. With the increased importance of coal for energy independence, training of graduate and undergraduate students in the development of new technologies is critical.

  15. Innovative clean coal technology (ICCT): demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emission from high-sulfur, coal-fired boilers - economic evaluation of commercial-scale SCR applications for utility boilers

    International Nuclear Information System (INIS)

    This report presents the results of an economic evaluation produced as part of the Innovative Clean Coal Technology project, which demonstrated selective catalytic reduction (SCR) technology for reduction of NOx emissions from utility boilers burning U.S. high-sulfur coal. The document includes a commercial-scale capital and O ampersand M cost evaluation of SCR technology applied to a new facility, coal-fired boiler utilizing high-sulfur U.S. coal. The base case presented herein determines the total capital requirement, fixed and variable operating costs, and levelized costs for a new 250-MW pulverized coal utility boiler operating with a 60-percent NOx removal. Sensitivity evaluations are included to demonstrate the variation in cost due to changes in process variables and assumptions. This report also presents the results of a study completed by SCS to determine the cost and technical feasibility of retrofitting SCR technology to selected coal-fired generating units within the Southern electric system

  16. Clean coal technologies and future prospects for coal

    International Nuclear Information System (INIS)

    The purpose of this paper is to analyze the future potential of coal in the US economy during the next 25 years in light of clean coal technologies. According to official US Department of Energy (DOE) designations, these technologies pertain only to the beneficiation, transformation, combustion, and postcombustion clean-up stages of the coal cycle; no coal mining or coal transport technologies are included. In general, clean coal technologies offer the prospect of mitigating environmental side-effects of coal utilization, primarily through improved operating efficiencies and lowered costs of air emission controls. If they prove successful, coal users will be able to meet more stringent environmental regulations at little or no additional cost. In assessing the influence of clean coal technologies on coal demand, we focus on the economics of three crucial areas: their development, their deployment, and coal utilization implications of their operation

  17. Advanced clean coal utilization technologies

    Energy Technology Data Exchange (ETDEWEB)

    Moritomi, Hiroshi [National Inst. for Resources and Environment, Tsukuba, Ibaraki (Japan)

    1993-12-31

    The most important greenhouse gas is CO{sub 2} from coal utilization. Ways of mitigating CO{sub 2} emissions include the use of alternative fuels, using renewable resources and increasing the efficiency of power generation and end use. Adding to such greenhouse gas mitigation technologies, post combustion control by removing CO{sub 2} from power station flue gases and then storing or disposing it will be available. Although the post combustion control have to be evaluated in a systematic manner relating them to whether they are presently available technology, to be available in the near future or long term prospects requiring considerable development, it is considered to be a less promising option owing to the high cost and energy penalty. By contrast, abatement technologies aimed at improving conversion efficiency or reducing energy consumption will reduce emissions while having their own commercial justification.

  18. Development of OTM Syngas Process and Testing of Syngas Derived Ultra-clean Fuels in Diesel Engines and Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    E.T. Robinson; John Sirman; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Dan Corgard; John Hemmings

    2005-05-01

    This final report summarizes work accomplished in the Program from January 1, 2001 through December 31, 2004. Most of the key technical objectives for this program were achieved. A breakthrough material system has lead to the development of an OTM (oxygen transport membrane) compact planar reactor design capable of producing either syngas or hydrogen. The planar reactor shows significant advantages in thermal efficiency and a step change reduction in costs compared to either autothermal reforming or steam methane reforming with CO{sub 2} recovery. Syngas derived ultra-clean transportation fuels were tested in the Nuvera fuel cell modular pressurized reactor and in International Truck and Engine single cylinder test engines. The studies compared emission and engine performance of conventional base fuels to various formulations of ultra-clean gasoline or diesel fuels. A proprietary BP oxygenate showed significant advantage in both applications for reducing emissions with minimal impact on performance. In addition, a study to evaluate new fuel formulations for an HCCI engine was completed.

  19. Adoption of clean coal technologies in India

    International Nuclear Information System (INIS)

    Coal is a major Indian energy resource. It is being utilized in conventional power stations now. Considerable coal resources are not located near load centers and therefore involve transport by rail. India is becoming more concerned with environmental matters and particularly with the health of its population. Clean coal electricity generation technologies are at the commercial demonstration stage in Europe and the USA in unit capacities appropriate to Indian needs. These technologies minimize environmental problems and promise 25% more efficiency. This competitive technology can be introduced to India in greenfield power stations, in repowering older power stations and in providing an enviable alternative for existing and new power stations presently depending on liquid or gas as fuel. (author)

  20. Fuel assemblies chemical cleaning

    International Nuclear Information System (INIS)

    NPP Paks found a thermal-hydraulic anomaly in the reactor core during cycle 14 that was caused by corrosion product deposits on fuel assemblies (FAs) that increased the hydraulic resistance of the FAs. Consequently, the coolant flow through the FAs was insufficient resulting in a temperature asymmetry inside the reactor core. Based on this fact NPP Paks performed differential pressure measurements of all fuel assemblies in order to determine the hydraulic resistance and subsequently the limit values for the hydraulic acceptance of FAs to be used. Based on the hydraulic investigations a total number of 170 FAs was selected for cleaning. The necessity for cleaning the FAs was explained by the fact that the FAs were subjected to a short term usage in the reactor core only maximum of 1,5 years and had still a capacity for additional 2 fuel cycles. (authors)

  1. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

  2. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 9, April--June 1991

    Energy Technology Data Exchange (ETDEWEB)

    Chow, O.K.; Nsakala, N.Y.

    1991-08-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. During the second quarter of 1991, the following technical progress was made: completed drop tube furnace devolatilization tests of the spherical oil agglomeration beneficiated products; continued analyses of samples to determine devolatilization kinetics; continued analyses of the data and samples from the CE pilot-scale tests of nine fuels; completed writing a summary topical report including all results to date on he nine fuels tested; and presented three technical papers on the project results at the 16th International Conference on Coal & Slurry Technologies.

  3. New Approach to Study the Ignition Processes of Organic Coal-Water Fuels in an Oxidizer Flow

    Science.gov (United States)

    Valiullin, T. R.; Dmitrienko, M. A.; Strizhak, P. A.

    2016-02-01

    To converge the conditions of organic water-coal fuel composition combustion in the typical power equipment we developed a new approach and installed an experimental setup, eliminating the traditional fixing the fuel droplets on the thermocouples or rods. Specialized cone-shaped chamber was used to implement the process of lingering of organic water-coal fuel droplets. Necessary and sufficient conditions for the lingering of organic water-coal fuel droplets were established. We determined the parameters of the system (droplet size of 0.4-0.6 mm, temperatures 823-903 K and the velocity of the oxidizer flow 1.5-6 m/s) at which the droplets were consistently ignited in the process of lingering. Minimum temperatures and ignition delay times of organic water-coal fuel droplets based on brown coal, used motor, turbine, transformer oils, kerosene, gasoline and water were defined.

  4. New Approach to Study the Ignition Processes of Organic Coal-Water Fuels in an Oxidizer Flow

    Directory of Open Access Journals (Sweden)

    Valiullin T.R.

    2016-01-01

    Full Text Available To converge the conditions of organic water-coal fuel composition combustion in the typical power equipment we developed a new approach and installed an experimental setup, eliminating the traditional fixing the fuel droplets on the thermocouples or rods. Specialized cone-shaped chamber was used to implement the process of lingering of organic water-coal fuel droplets. Necessary and sufficient conditions for the lingering of organic water-coal fuel droplets were established. We determined the parameters of the system (droplet size of 0.4-0.6 mm, temperatures 823-903 K and the velocity of the oxidizer flow 1.5-6 m/s at which the droplets were consistently ignited in the process of lingering. Minimum temperatures and ignition delay times of organic water-coal fuel droplets based on brown coal, used motor, turbine, transformer oils, kerosene, gasoline and water were defined.

  5. Coal liquefaction processes

    Energy Technology Data Exchange (ETDEWEB)

    Baker, N.R.; Blazek, C.F.; Tison, R.R.

    1979-07-01

    Coal liquefaction is an emerging technology receiving great attention as a possible liquid fuel source. Currently, four general methods of converting coal to liquid fuel are under active development: direct hydrogenation; pyrolysis/hydrocarbonization; solvent extraction; and indirect liquefaction. This work is being conducted at the pilot plant stage, usually with a coal feed rate of several tons per day. Several conceptual design studies have been published recently for large (measured in tens of thousands of tons per day coal feed rate) commercial liquefaction plants, and these reports form the data base for this evaluation. Products from a liquefaction facility depend on the particular method and plant design selected, and these products range from synthetic crude oils up through the lighter hydrocarbon gases, and, in some cases, electricity. Various processes are evaluated with respect to product compositions, thermal efficiency, environmental effects, operating and maintenance requirements, and cost. Because of the large plant capacities of current conceptual designs, it is not clear as to how, and on what scale, coal liquefaction may be considered appropriate as an energy source for Integrated Community Energy Systems (CES). Development work, both currently under way and planned for the future, should help to clarify and quantify the question of applicability.

  6. Clean coal technology: Export finance programs

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-30

    Participation by US firms in the development of Clean Coal. Technology (CCT) projects in foreign countries will help the United States achieve multiple national objectives simultaneously--addressing critical goals related to energy, environmental technology, industrial competitiveness and international trade. US participation in these projects will result in an improved global environment, an improvement in the balance of payments and an increase in US jobs. Meanwhile, host countries will benefit from the development of economically- and environmentally-sound power facilities. The Clean Air Act Amendments of 1990 (Public Law 101-549, Section 409) as supplemented by a requirement in the Energy Policy Act of 1992 (Public Law 102-486, Section 1331(f)) requires that the Secretary of Energy, acting through the Trade Promotion Coordinating Committee Subgroup on Clean Coal Technologies, submit a report to Congress with information on the status of recommendations made in the US Department of Energy, Clean Coal Technology Export Programs, Report to the United States Congress, February 1992. Specific emphasis is placed on the adequacy of financial assistance for export of CCTS. This report fulfills the requirements of the Act. In addition, although this report focuses on CCT power projects, the issues it raises about the financing of these projects are also relevant to other CCT projects such as industrial applications or coal preparation, as well as to a much broader range of energy and environmental technology projects worldwide.

  7. Combustion characterization of beneficiated coal-based fuels

    Energy Technology Data Exchange (ETDEWEB)

    Chow, O.K.; Nsakala, N.Y.

    1990-11-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a three-year project on Combustion Characterization of Beneficiated Coal-Based Fuels.'' The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are being run at the cleaning facility in Homer City, Pennsylvania, to produce 20-ton batches of fuels for shipment to CE's laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CVVT) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Science, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFS, and two conventionally cleaned coals for full-scale tests. Approximately, nine BCFs will be in dry microfine coal (DMPC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

  8. Clean coal technologies: Research, development, and demonstration program plan

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-01

    The US Department of Energy, Office of Fossil Energy, has structured an integrated program for research, development, and demonstration of clean coal technologies that will enable the nation to use its plentiful domestic coal resources while meeting environmental quality requirements. The program provides the basis for making coal a low-cost, environmentally sound energy choice for electric power generation and fuels production. These programs are briefly described.

  9. The Shell coal gasification process

    International Nuclear Information System (INIS)

    This paper reports that Future Integrated Gasification Combined Cycle (IGCC) power plants will have superior environmental performance and unmatched efficiency. Efficiency depends on many factors including the type of coal, the gasification process, the gas turbine, the steam cycle. NOx reduction measures and the degree and manner of integration. The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an IGCC plant. SCGP flexibility has been demonstrated for feeds ranging from bituminous coals to lignites and petroleum coke, and the process is ideally suited for combined cycle power generation, resulting in efficiencies of 42 to 46% (LHV). The excellent environmental capabilities of IGCC systems are based on well established treating processes for removing sulphur and nitrogen species form the syngas. IGCC processes produce modest volumes of environmentally acceptable effluents. Gas turbine burner developments imply lower NOx emissions. In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology is being built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). The plant is scheduled to start up in 1993

  10. Clean Coal Technology Programs: Program Update 2009

    Energy Technology Data Exchange (ETDEWEB)

    None

    2009-10-01

    The purpose of the Clean Coal Technology Programs: Program Update 2009 is to provide an updated status of the U.S. Department of Energy (DOE) commercial-scale demonstrations of clean coal technologies (CCT). These demonstrations have been performed under the Clean Coal Technology Demonstration Program (CCTDP), the Power Plant Improvement Initiative (PPII), and the Clean Coal Power Initiative (CCPI). Program Update 2009 provides: (1) a discussion of the role of clean coal technology demonstrations in improving the nation’s energy security and reliability, while protecting the environment using the nation’s most abundant energy resource—coal; (2) a summary of the funding and costs of the demonstrations; and (3) an overview of the technologies being demonstrated, along with fact sheets for projects that are active, recently completed, or recently discontinued.

  11. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 8, January--March 1991

    Energy Technology Data Exchange (ETDEWEB)

    Chow, O.K.; Nsakala, N.Y.

    1991-07-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. During the third quarter of 1991, the following technical progress was made: Calculated the kinetic characteristics of chars from the combustion of spherical oil agglomeration beneficiated products; continued drop tube devolatilization tests of the spherical oil agglomeration beneficiated products; continued analyses of the data and samples from the CE pilot-scale tests of nine fuels; and started writing a summary topical report to include all results on the nine fuels tested.

  12. Characterization and supply of coal based fuels

    Energy Technology Data Exchange (ETDEWEB)

    1992-06-01

    Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

  13. Coal derived fuel gases for molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    1979-11-01

    Product streams from state-of-the-art and future coal gasification systems are characterized to guide fuel cell program planners and researchers in establishing performance goals and developing materials for molten carbonate fuel cells that will be compatible with gasifier product gases. Results are presented on: (1) the range of gasifier raw-gas compositions available from the major classes of coal gasifiers; (2) the degree of gas clean-up achievable with state-of-the-art and future gas clean-up systems; and (3) the energy penalties associated with gas clean-up. The study encompasses fixed-bed, fluid-bed, entrained-bed, and molten salt gasifiers operating with Eastern bituminous and Western subbituminous coals. Gasifiers operating with air and oxygen blowing are evaluated, and the coal gasification product streams are characterized with respect to: (1) major gas stream constituents, e.g., CO, H/sub 2/, CO/sub 2/, CH/sub 4/, N/sub 2/, H/sub 2/O; (2) major gas stream contaminants, e.g., H/sub 2/S, COS, particulates, tars, etc.; and (3) trace element contaminants, e.g., Na, K, V, Cl, Hg, etc.

  14. Clean coal: Global opportunities for small businesses

    International Nuclear Information System (INIS)

    The parallel growth in coal demand and environmental concern has spurred interest in technologies that burn coal with greater efficiency and with lower emissions. Clean Coal Technologies (CCTs) will ensure that continued use of the world's most abundant energy resource is compatible with a cleaner, healthier environment. Increasing interest in CCTs opens the door for American small businesses to provide services and equipment for the clean and efficient use of coal. Key players in most coal-related projects are typically large equipment manufacturers, power project developers, utilities, governments, and multinational corporations. At the same time, the complexity and scale of many of these projects creates niche markets for small American businesses with high-value products and services. From information technology, control systems, and specialized components to management practices, financial services, and personnel training methods, small US companies boast some of the highest value products and services in the world. As a result, American companies are in a prime position to take advantage of global niche markets for CCTs. This guide is designed to provide US small businesses with an overview of potential international market opportunities related to CCTs and to provide initial guidance on how to cost-effectively enter that growing global market

  15. Clean coal: Global opportunities for small businesses

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    The parallel growth in coal demand and environmental concern has spurred interest in technologies that burn coal with greater efficiency and with lower emissions. Clean Coal Technologies (CCTs) will ensure that continued use of the world`s most abundant energy resource is compatible with a cleaner, healthier environment. Increasing interest in CCTs opens the door for American small businesses to provide services and equipment for the clean and efficient use of coal. Key players in most coal-related projects are typically large equipment manufacturers, power project developers, utilities, governments, and multinational corporations. At the same time, the complexity and scale of many of these projects creates niche markets for small American businesses with high-value products and services. From information technology, control systems, and specialized components to management practices, financial services, and personnel training methods, small US companies boast some of the highest value products and services in the world. As a result, American companies are in a prime position to take advantage of global niche markets for CCTs. This guide is designed to provide US small businesses with an overview of potential international market opportunities related to CCTs and to provide initial guidance on how to cost-effectively enter that growing global market.

  16. Prospects for coal and clean coal technologies in Indonesia

    Energy Technology Data Exchange (ETDEWEB)

    Baruya, P.

    2009-06-15

    Indonesia has become the largest exporter of steam coal in the world, but the long-term future of coal exports is being brought into question as domestic demand is projected to grow by a significant amount, from 40-50 Mt/y in 2007 to more than 100 Mt/y by 2013, and even higher beyond 2013. Exports reached 200-210 Mt in 2008, and is set to rise in the future. Import volumes are negligible, while indigenous production was estimated to be around 240-260 Mt in 2008. Illegal mining is being addressed and in the past could have accounted for at least 20 Mt/y of production, but obtaining reliable export and production figures as a result is therefore not straight forward. Indonesia is the fourth most populous country in the world. This fact coupled with robust GDP growth means there is more pressure on the state-controlled electricity industry to invest and build an adequate infrastructure to meet the rising demand for power. Part of this investment is being driven by government policy to build 10 GWe of coal-fired power by 2010 and a second tranche by 2013. However, the investment programme, commonly known as the 'crash programme' is more likely to be delayed by 2-3 years. Nevertheless, the likely 20-30 Mt/y or so of additional coal demand from the first tranche alone will put pressure on domestic coal producers to meet expanding demand both at home and abroad for low rank and exportable bituminous coals. This report covers four main topics, the Indonesian coal industry, the power generating sector and its use of clean coal technology, changes in coal demand and its impact on international trade, and finally a brief look at upgrading low rank coals within the country. 80 refs., 22 figs., 11 tabs.

  17. The production of a premium solid fuel from Powder River Basin coal

    Energy Technology Data Exchange (ETDEWEB)

    Merriam, N.; Sethi, V.; Thomas, K.; Grimes, R.W.

    1992-09-01

    This report describes our initial evaluation of a process designed to produce premium-quality solid fuel from Powder River Basin (PRB) coal. The process is based upon our experience gained by producing highly-reactive, high-heating-value char as part of a mild-gasification project. In the process, char containing 20 to 25 wt % volatiles and having a gross heating value of 12,500 to 13,000 Btu/lb is produced. The char is then contacted by coal-derived liquid. The result is a deposit of 6 to 8 wt % pitch on the char particles. The lower boiling component of the coal-derived liquid which is not deposited on the char is burned as fuel. Our economic evaluation shows the process will be economically attractive if the product can be sold for about $20/ton or more. Our preliminary tests show that we can deposit pitch on to the char, and the product is less dusty, less susceptible to readsorption of moisture, and has reduced susceptibility to self heating.

  18. The production of a premium solid fuel from Powder River Basin coal

    International Nuclear Information System (INIS)

    This paper describes our initial evaluation of a process designed to produce premium-quality solid fuel from Powder River Basin (PRB) coal. The process is based upon our experience gained by producing highly-reactive, high-heating-value char as part of a mild-gasification project. In the process char containing 20 to 25 wt % volatiles and having a gross heating value of 12,500 to 13,000 Btu/lb is produced. The char is then contacted by coal-derived liquid. The result is a deposit of 6 to 8 wt % pitch on the char particles. The lower boiling component of the coal-derived liquid which is not deposited on the char is burned as fuel. The authors' economic alveolation shows the process will be economically attractive if the product can be sold for about $20/ton or more. The authors' preliminary tests show that we can deposit pitch on to the char, and the product is less dusty, less susceptible to reabsorption of moisture, and has reduced susceptibility to self heating

  19. Cleaning of liquid LLW from decontamination processes using semipermeable membranes

    International Nuclear Information System (INIS)

    Of the three processes, which have been used extensively for liquid radioactive waste purification, evaporation and ion exchange are costly and flocculation gives a low degree of purification. By comparison to that, reverse osmosis offers intermediate purification at reasonable cost. Present research is examining the potential of using a membrane filtration system for the removal of dissolved radionuclides, but chemical treatment showed as necessary to convert soluble radionuclides, organic traces and metals to insoluble, filterable species. Liquid wastes within a CANDU station are segregated into normal and low-activity waste streams. The normal-activity waste includes wastes from the laboratories, laundries, some service-building drains, upgrade drains, and decontamination center. The drains from the reactor building, the heavy-water area, the spent-fuel pool, and the resin storage area are also directed to this normal activity wastes from showers and building drains in areas of the service building that would not normally be contaminated. The aqueous liquid wastes from the decontamination center and the other collected wastes from the chemical drain system are currently treated by the membrane plant. Generally, the liquid waste streams are effectively volume-reduced by a combination of continuous crossflow microfiltration (MF), spiral wound reverse osmosis (SWRO) and tubular reverse osmosis membrane technologies. Backwash chemical cleaning wastes from the membrane plant are further volume-reduced by evaporation. The concentrate from the membrane plant is ultimately immobilized with bitumen. The ability of the MF/SWRO technology to remove impurities non-selectively makes it suitable for the treatment of radioactive effluents from operating nuclear plants, with proper membrane selection, feed characterization, system configuration and system chemistry control. The choice of polysulfonate material for membrane was based on the high flow rates achievable with this

  20. The Healy clean coal project: An overview

    Energy Technology Data Exchange (ETDEWEB)

    Olson, J.B.; McCrohan, D.V. [Alaska Industrial Development and Export Authority, Anchorage, AK (United States)

    1997-12-31

    The Healy Clean Coal Project, selected by the US Department of Energy under Round III of the Clean Coal Technology Program is currently in construction. The project is owned and financed by the Alaska Industrial Development and Export Authority (AIDEA), and is cofunded by the US Department of Energy. Construction is scheduled to be completed in August of 1997, with startup activity concluding in December of 1997. Demonstration, testing and reporting of the results will take place in 1998, followed by commercial operation of the facility. The emission levels of NOx, SO{sub 2} and particulates from this 50 megawatt plant are expected to be significantly lower than current standards. The project status, its participants, a description of the technology to be demonstrated, and the operational and performance goals of this project are presented.

  1. Catalytic Processes for Clean Hydrogen Production from Hydrocarbons

    OpenAIRE

    ÖNSAN, Zeynep İlsen

    2007-01-01

    Conversion of hydrocarbon fuels to hydrogen with a high degree of purity acceptable for fuel cell operation presents interesting challenges for the design of new selective catalysts and catalytic processes. Natural gas, LPG, gasoline, and diesel are regarded as promising hydrocarbon fuels. Methanol has received attention despite its toxicity, and ethanol has recently become of interest as a much less toxic and renewable resource. Selective catalytic processes considered for commerci...

  2. Clean Coal Technology Demonstration Program: Program update 1993

    Energy Technology Data Exchange (ETDEWEB)

    1994-03-01

    The Clean Coal Technology Demonstration Program (also referred to as the CCT Program) is a $6.9 billion cost-shared industry/government technology development effort. The program is to demonstrate a new generation of advanced coal-based technologies, with the most promising technologies being moved into the domestic and international marketplace. Technology has a vital role in ensuring that coal can continue to serve U.S. energy interests and enhance opportunities for economic growth and employment while meeting the national committment to a clean and healthy global environment. These technologies are being advanced through the CCT Program. The CCT Program supports three substantive national objectives: ensuring a sustainable environment through technology; enhancing energy efficiency and reliability; providing opportunities for economic growth and employment. The technologies being demonstrated under the CCT Program reduce the emissions of sulfur oxides, nitrogen oxides, greenhouse gases, hazardous air pollutants, solid and liquid wastes, and other emissions resulting from coal use or conversion to other fuel forms. These emissions reductions are achieved with efficiencies greater than or equal to currently available technologies.

  3. Prospects For Coal And Clean Coal Technologies In Kazakhstan

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-12-15

    The coal sector in Kazakhstan is said to have enough reserves to last over 100 years, but the forecasted reserves are expected to last several hundreds of years. This makes investing in the fuel and energy sector of the country an attractive option for many international and private organisations. The proven on-shore reserves will ensure extraction for over 30 years for oil and 75 years for gas. The future development of the domestic oil sector depends mainly on developing the Kazakh sector of the Caspian Sea. The coal sector, while not a top priority for the Kazakh government, puts the country among the world's top ten coal-rich countries. Kazakhstan contains Central Asia's largest recoverable coal reserves. In future, the development of the raw materials base will be achieved through enriching and improving the quality of the coal and the deep processing of coal to obtain fluid fuel and synthetic substances. Developing shale is also topical. The high concentration of methane in coal layers makes it possible to extract it and utilise it on a large scale. However, today the country's energy sector, which was largely established in the Soviet times, has reached its potential. Kazakhstan has about 18 GW of installed electricity capacity, of which about 80% is coal fired, most of it built before 1990. Being alert to the impending problems, the government is planning to undertake large-scale modernisation of the existing facilities and construct new ones during 2015-30. The project to modernise the national electricity grid aims to upgrade the power substations to ensure energy efficiency and security of operation. The project will result in installation of modern high-voltage equipment, automation and relay protection facilities, a dispatch control system, monitoring and data processing and energy management systems, automated electricity metering system, as well as a digital corporate telecommunication network.

  4. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 10, July--September 1991

    Energy Technology Data Exchange (ETDEWEB)

    Chow, O.K.; Nsakala, N.Y.

    1991-11-01

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. During the third quarter of 1991, the following technical progress was made: Continued analyses of drop tube furnace samples to determine devolatilization kinetics; completed analyses of the samples from the pilot-scale ash deposition tests of unweathered Upper Freeport fuels; completed editing of the first three quarterly reports and sent them to the publishing office; presented the project results at the Annual Contractors` Conference.

  5. Asia's coal and clean coal technology market potential

    International Nuclear Information System (INIS)

    The Asian region is unique in the world in having the highest economic growth rate, the highest share of coal in total primary energy consumption and the highest growth rate in electricity generation capacity. The outlook for the next two decades is for accelerated efforts to control coal related emissions of particulates and SO2 and to a lessor extent NOx and CO2. Only Japan has widespread use of Clean Coal Technologies (CCTs) however a number of economies have plans to install CCTs in future power plants. Only CCTs for electricity generation are discussed, and are defined for the purpose of this paper as technologies that substantially reduce SO2 and/or NOx emissions from coal-fired power plants. The main theses of this paper are that major increases in coal consumption will occur over the 1990-2010 period, and this will be caccompanied by major increases in coal related pollution in some Asian economies. Coal fired electricity generation is projected to grow at a high rate of about 6.9 percent per year over the 1990-2010 period. CCTs are projected to account for about 150 GW of new coal-fired capacity over the 1990-2010 period of about one-third of all new coal-fired capacity. A speculative conclusion is that China will account for the largest share of CCT additions over the 1990-2010 period. Both the US and Japan have comparative advantages that might be combined through cooperation and joint ventures to gain a larger share of the evolving CCT market in Asia. 5 refs., 7 figs., 4 tabs

  6. High quality coal extraction and environmental remediation of fine coal refuse ponds using advanced cleaning technologies

    International Nuclear Information System (INIS)

    A vast number of coal refuse ponds represent a significant economical resource base that are also considered to be environmentally harmful. Significant amounts of cleanable fine coal generally exist in the refuse ponds due to the inability of conventional technologies to effectively separate the fine coal from the associated gangue particles. In addition, acid generation, generally a result of pyrite oxidation, has potential to adversely affect the surrounding environment. An integrated processing strategy of simultaneously recovering high quality coal and pyrite-rich products from the treatment of a coal refuse pond slurry has been successfully evaluated using an advanced physical cleaning circuit. A clean coal product having ash and pyritic sulfur contents of 10.1% and 0.41% was recovered with a mass yield of nearly 49%. In addition, a pyrite-rich product containing nearly 83% of the coal pyrite particles present in the refuse pond material was generated for neutralization purposes for the environmental remediation of the slurry pond. 4 refs

  7. 5. annual clean coal technology conference: powering the next millennium. Volume 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-06-01

    The Fifth Annual Clean Coal Technology Conference focuses on presenting strategies and approaches that will enable clean coal technologies to resolve the competing, interrelated demands for power, economic viability, and environmental constraints associated with the use of coal in the post-2000 era. The program addresses the dynamic changes that will result from utility competition and industry restructuring, and to the evolution of markets abroad. Current projections for electricity highlight the preferential role that electric power will have in accomplishing the long-range goals of most nations. Increase demands can be met by utilizing coal in technologies that achieve environmental goals while keeping the cost- per-unit of energy competitive. Results from projects in the DOE Clean Coal Technology Demonstration Program confirm that technology is the pathway to achieving these goals. The industry/government partnership, cemented over the past 10 years, is focused on moving the clean coal technologies into the domestic and international marketplaces. The Fifth Annual Clean Coal Technology Conference provides a forum to discuss these benchmark issues and the essential role and need for these technologies in the post-2000 era. This volume contains technical papers on: advanced coal process systems; advanced industrial systems; advanced cleanup systems; and advanced power generation systems. In addition, there are poster session abstracts. Selected papers from this proceedings have been processed for inclusion in the Energy Science and Technology database.

  8. Prospects for advanced coal-fuelled fuel cell power plants

    International Nuclear Information System (INIS)

    As part of ECN's in-house R and D programmes on clean energy conversion systems with high efficiencies and low emissions, system assessment studies have been carried out on coal gasification power plants integrated with high-temperature fuel cells (IGFC). The studies also included the potential to reduce CO2 emissions, and to find possible ways for CO2 extraction and sequestration. The development of this new type of clean coal technology for large-scale power generation is still far off. A significant market share is not envisaged before the year 2015. To assess the future market potential of coal-fuelled fuel cell power plants, the promise of this fuel cell technology was assessed against the performance and the development of current state-of-the-art large-scale power generation systems, namely the pulverized coal-fired power plants and the integrated coal gasification combined cycle (IGCC) power plants. With the anticipated progress in gas turbine and gas clean-up technology, coal-fuelled fuel cell power plants will have to face severe competition from advanced IGCC power plants, despite their higher efficiency. (orig.)

  9. A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES

    Energy Technology Data Exchange (ETDEWEB)

    John T. Kelly; George Miller; Mehdi Namazian

    2001-07-01

    Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was

  10. A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES; FINAL

    International Nuclear Information System (INIS)

    Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was

  11. Uranium content of coal ashes from Southern Brazil coal fueled power stations, by the fission track registration technique

    International Nuclear Information System (INIS)

    The feasibility of the application of the fission track registration technique for the determination of uranium in coal ashes was shown. The wet method was employed using as detector the Makrofol KG=10 μm, manufactured by Bayer. The coal ashes were originated from coal-fueled power stations localized in Southern Brazil. The results obtained ranged from 10 to 27 mg U/kg. Since the total error variation was from 18,4% to 23,8%, the method used was considered excellent. The determination of the uranium content in coal ashes is of considerable interest in environmental control in power stations, in their vicinity and wherever these ashes are used or stored. The technique used is the work proved to be very appropriate for the purpose aimed at. (Author)

  12. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research.

  13. The shell coal gasification process

    Energy Technology Data Exchange (ETDEWEB)

    Koenders, L.O.M.; Zuideveld, P.O. [Shell Internationale Petroleum Maatschappij B.V., The Hague (Netherlands)

    1995-12-01

    Future Integrated Coal Gasification Combined Cycle (ICGCC) power plants will have superior environmental performance and efficiency. The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an ICGCC plant. SCGP flexibility has been demonstrated for high-rank bituminous coals to low rank lignites and petroleum coke, and the process is well suited for combined cycle power generation, resulting in efficiencies of 42 to 46% (LHV), depending on choice of coal and gas turbine efficiency. In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology has been built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). The construction of the unit was completed end 1993 and is now followed by start-up and a 3 year demonstration period, after that the plant will be part of the Dutch electricity generating system.

  14. The Magnetic Beneficiation of Coal

    OpenAIRE

    Male, S.E.

    1985-01-01

    The magnetic demineralization of coal can produce a fuel containing lower leveIs of sulphur and ash forming minerals. The ability of the magnetic separation technique to process material over a wide range of particle sizes (I-1000 µm) and to operate on either liquid or gaseous feed enables a number of possible coal processing applications. These range from dry desulphurization of power station pulverized fuel to the cleaning of solvent refined coals. This article reviews work on the developme...

  15. Need for Clean Coal Mining in India

    Directory of Open Access Journals (Sweden)

    Sribas Goswami

    2014-04-01

    Full Text Available Coal mining contributes largely towards economic development of the nation although it has a great impact on the human health. It also has an impact on a socio-cultural aspect of workers and people residing in and around coal mining areas. Thus a holistic approach to taking up with mining activities, keeping in mind the concerns over adjoining habitats and ecosystem, is the need of the hour. This requires identification of various sites where minerals exist, of various factors ranging from an appropriate angle of the slope of overburden dumps to safe disposal drains, of safe techniques to various silt control structures etc. In India, coal companies are now working towards “clean coal” strategies which aim to reduce environmental impacts. The reduced ash contents of the washed coal increase thermal efficiency of combustion which, in turn, makes a direct impact on reducing emissions of pollutants. However, the coal washing requires extra water and it can turn towards a pollution free society.

  16. Need for Clean Coal Mining in India

    Directory of Open Access Journals (Sweden)

    Sribas Goswami

    2014-01-01

    Full Text Available Coal mining contributes largely towards economic development of the nation although it has a great impact on the human health. It also has an impact on a socio-cultural aspect of workers and people residing in and around coal mining areas. Thus a holistic approach to taking up with mining activities, keeping in mind the concerns over adjoining habitats and ecosystem, is the need of the hour. This requires identification of various sites where minerals exist, of various factors ranging from an appropriate angle of the slope of overburden dumps to safe disposal drains, of safe techniques to various silt control structures etc. In India, coal companies are now working towards “clean coal” strategies which aim to reduce environmental impacts. The reduced ash contents of the washed coal increase thermal efficiency of combustion which, in turn, makes a direct impact on reducing emissions of pollutants. However, the coal washing requires extra water and it can turn towards a pollution free society.DOI: http://dx.doi.org/10.5755/j01.erem.66.4.4870

  17. Physical properties of solid fuel briquettes from bituminous coal waste and biomass

    Institute of Scientific and Technical Information of China (English)

    ZARRINGHALAM-MOGHADDAM A; GHOLIPOUR-ZANJANI N; DOROSTIS; VAEZ M

    2011-01-01

    Biomass and bituminous coal fines from four different coalfields were used to produce fuel briquettes.Two physical properties of briquettes,water resistance index and compressive strength were analyzed.The influence of type and quantity of biomass on physical properties was also studied.The results reveal that depending on the mineral content of the coal,the physical properties of the briquettes differ noticeably.The comparison of briquettes with and without biomass showed that the presence of the beet pulp increased CS in all types of coal samples.Samples containing beet pulp had better physical properties than sawdust.Mezino Ⅱ coal briquettes had highest CS and WRI than the other ones.Calorific value of biomass/Mezino Ⅱ coal briquettes was lessened in comparison with raw coal,but it remained in an acceptable range.

  18. Process simulation of oxy-fuel combustion for a 300 MW pulverized coal-fired power plant using Aspen Plus

    International Nuclear Information System (INIS)

    Graphical abstract: This paper studied the combustion processes of pulverized coal in a 300 MW power plant using Aspen Plus software. The amount of each component in flue gas in coal-fired processes with air or O2/CO2 as oxidizer was obtained. The differences between the two processes were identified, and the parameter influences of temperature, excess oxygen ratio and molar fraction of O2/CO2 on the proportions of different components in flue gas were examined by sensitivity analysis. - Highlights: • Combustion processes were studied with Aspen Plus for a 300 MW pulverized coal power plant. • The amount of each flue gas component in coal-fired processes with air or O2/CO2 as oxidizer was obtained. • Differences between the two process models were identified. • The influences of operation parameters on the flue gas components were examined. - Abstract: This work focuses on the amounts and components of flue gas for oxy-fuel combustion in a coal-fired power plant (CFPP). The combustion process of pulverized coal in a 300 MW power plant is studied using Aspen Plus software. The amount of each component in flue gas in coal-fired processes with air or O2/CO2 as oxidizer is obtained. The differences between the two processes are identified, and the influences of temperature, excess oxygen ratio and molar fraction of O2/CO2 on the proportions of different components in flue gas are examined by sensitivity analysis. The process simulation results show that replacing atmospheric air by a 21%O2/79%CO2 mixture leads the decrease of the flame temperature from 1789 °C to 1395 °C. The equilibrium amount of NOx declines obviously but the SOx are still at the same level. The mass fraction of CO2 in flue gas increased from 21.3% to 81.5%. The amount of NOx is affected sensitively by the change of temperature and the excess oxygen ratio, but the change of O2/CO2 molar fraction has a little influence to the generation of NOx. With the increasing of O2 concentration, the

  19. Coal desulfurization during the combustion of coal/oil/water emulsions: an economic alternative clean liquid fuel. Interim report, October 1978-November 15, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Dooher, J. P.

    1979-11-15

    The rheological and combustion properties of coal/water/oil mixtures have been investigated. In addition the use of alkaline additives to remove the sulfur oxide gases has been studied. Results on stability and pumpability indicate that mixtures of 50% by weight of coal and stoichiometric concentrations of alkaline absorbents are pumpable. Correlation between viscometer data and pumping data follows a power law behavior for these mixtures. Thermal efficiencies are about the same as for pure oil. Combustion efficiencies are approximately 97%. It is possible to remove in a small scale combustion from 50 to 80% of the sulfur dioxide gases.

  20. Coal surface control for advanced physical fine coal cleaning technologies

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.-H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Venkatadri, R.; Bi, H.; Campbell, P.; Ciocco, M.; Hittle, L.; Kim, S.; Perez, L.

    1990-01-01

    The progress achieved in leading to effective surface control for selective agglomeration processes was summarized. Several analytical techniques developed in Task 3 were utilized during this quarter to characterize coal samples obtained from agglomeration tests. Surface and near surface (1 {mu}m depth) functional groups were analyzed using Diffuse Reflectance Infrared Fourier Transform spectroscopy. Surface composition analyses were conducted using Laser Microprobe Mass Analyzer. The results of these analysis are being used to relate the agglomeration results with surface modifications to the properties of coal samples. The development of a method a for direct determination of pyrite using X-ray diffraction was continued. The sample preparation technique was improved in order to increase the reproducibility of the analysis. The contact angle of n-heptane droplets on coal pellets immersed in water were measured. The results of these measurements suggest that high shear mixing is necessary for wetting coal surfaces with n-heptane. Agglomeration tests using n-heptane as agglomerant were carried out this quarter. For Pittsburgh {number sign}8 coal, better performance was obtained using n-heptane than using n-pentane. For Upper Freeport coal, however, lower pyritic sulfur rejection was obtained with n-heptane. A n-heptane to coal ratio between 1.25 and 1.5 was found to produce the best performance results for Illinois {number sign}6 coal. A study of the effect of agglomeration time on the agglomeration process performance for Illinois {number sign}6 coal using n-pentane and n-heptane as agglomerants indicates that no significant gains in performance are possible using agglomeration times longer than 60 seconds. The addition of tall oil as a binding agent after the high shear agglomeration step resulted in a large increase in overall coal yield and energy recovery for Illinois {number sign}6 coal. 27 figs., 13 tabs.

  1. DOE Coal Gasification Multi-Test Facility: fossil fuel processing technical/professional services

    Energy Technology Data Exchange (ETDEWEB)

    Hefferan, J.K.; Lee, G.Y.; Boesch, L.P.; James, R.B.; Rode, R.R.; Walters, A.B.

    1979-07-13

    A conceptual design, including process descriptions, heat and material balances, process flow diagrams, utility requirements, schedule, capital and operating cost estimate, and alternative design considerations, is presented for the DOE Coal Gasification Multi-Test Facility (GMTF). The GMTF, an engineering scale facility, is to provide a complete plant into which different types of gasifiers and conversion/synthesis equipment can be readily integrated for testing in an operational environment at relatively low cost. The design allows for operation of several gasifiers simultaneously at a total coal throughput of 2500 tons/day; individual gasifiers operate at up to 1200 tons/day and 600 psig using air or oxygen. Ten different test gasifiers can be in place at the facility, but only three can be operated at one time. The GMTF can produce a spectrum of saleable products, including low Btu, synthesis and pipeline gases, hydrogen (for fuel cells or hydrogasification), methanol, gasoline, diesel and fuel oils, organic chemicals, and electrical power (potentially). In 1979 dollars, the base facility requires a $288 million capital investment for common-use units, $193 million for four gasification units and four synthesis units, and $305 million for six years of operation. Critical reviews of detailed vendor designs are appended for a methanol synthesis unit, three entrained flow gasifiers, a fluidized bed gasifier, and a hydrogasifier/slag-bath gasifier.

  2. Subtask 3.11 - Production of CBTL-Based Jet Fuels from Biomass-Based Feedstocks and Montana Coal

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, Ramesh

    2014-06-01

    The Energy & Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from Exxon Mobil, undertook Subtask 3.11 to use a recently installed bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. The process involves liquefaction of Rosebud mine coal (Montana coal) coupled with an upgrading scheme to produce a naphthenic fuel. The upgrading comprises catalytic hydrotreating and saturation to produce naphthenic fuel. A synthetic jet fuel was prepared by blending equal volumes of naphthenic fuel with similar aliphatic fuel derived from biomass and 11 volume % of aromatic hydrocarbons. The synthetic fuel was tested using standard ASTM International techniques to determine compliance with JP-8 fuel. The composite fuel thus produced not only meets but exceeds the military aviation fuel-screening criteria. A 500-milliliter synthetic jet fuel sample which met internal screening criteria was submitted to the Air Force Research Laboratory (AFRL) at Wright–Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with U.S. Air Force-prescribed alternative aviation fuel initial screening criteria. The results show that this fuel meets or exceeds the key specification parameters for JP-8, a petroleum-based jet fuel widely used by the U.S. military. JP-8 specifications include parameters such as freeze point, density, flash point, and others; all of which were met by the EERC fuel sample. The fuel also exceeds the thermal stability specification of JP-8 fuel as determined by the quartz crystalline microbalance (QCM) test also performed at an independent laboratory as well as AFRL. This means that the EERC fuel looks and acts identically to petroleum-derived jet fuel and can be used

  3. Clean and Highly Efficient Utilization of Coal

    Institute of Scientific and Technical Information of China (English)

    WANG Jianguo; YANG Li

    2011-01-01

    @@ Clean and highly efficient utilization of coal is an important scientific and technological issue.As the petroleum resource decreases but its consumption increases, all of the countries in the world have to face the big issue of sustainable development of energy and economy and protection of environment.Therefore, study on clean coal technology (CCT) has attracted much attention and become one of important themes of energy research.

  4. State perspectives on clean coal technology deployment

    Energy Technology Data Exchange (ETDEWEB)

    Moreland, T. [State of Illinois Washington Office, Washington, DC (United States)

    1997-12-31

    State governments have been funding partners in the Clean Coal Technology program since its beginnings. Today, regulatory and market uncertainties and tight budgets have reduced state investment in energy R and D, but states have developed program initiatives in support of deployment. State officials think that the federal government must continue to support these technologies in the deployment phase. Discussions of national energy policy must include attention to the Clean Coal Technology program and its accomplishments.

  5. An assessment of cleaning amenability of salt range coal through physical cleaning methods

    International Nuclear Information System (INIS)

    Representative coal samples from the eastern salt range (Modern Engineering and Kishor coal mines, Pakistan) and the central salt range (Punjmin coal mine, Pakistan) were collected and examined for their chemical composition. The chemical characteristics indicate that the salt range coal belongs to sub-bituminous category. Washability analysis on selected coal samples (6.70 , 0.212 mm) using zinc chloride solution with a specific gravity from 1.3 to 1.7 were executed. The results classify the central salt range coal as easily washable while, the Eastern salt range coal as moderately difficult to wash. Jigging, shaking table and spiral techniques were applied to check the cleaning amenability of the salt range coal through these techniques. Among these techniques, shaking table revealed the most promising results for all the three coals. Punjmin coal showed the maximum rejection of ash of 55% and that of total sulphur of 74% with a recovery of 46%. (author)

  6. Self-scrubbing coal{sup TM}: An integrated approach to clean air. A proposed Clean Coal Technology Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    This environmental assessment (EA) was prepared by the U.S.Department of Energy (DOE), with compliance with the National Environmental Policy Act (NEPA) of 1969, Council on Environmental Quality (CE) regulations for implementating NEPA (40 CFR 1500-1508) and DOE regulations for compliance with NEPA (10 CFR 1021), to evaluate the potential environmental impacts associated with a proposed demonstration project to be cost-shared by DOE and Custom Coals International (CCI) under the Clean Coal Technology (CCT) Demonstration Program of DOE`s Office of Fossil Energy. CCI is a Pennsylvania general partnership located in Pittsburgh, PA engaged in the commercialization of advanced coal cleaning technologies. The proposed federal action is for DOE to provide, through a cooperative agreement with CCI, cost-shared funding support for the land acquisition, design, construction and demonstration of an advanced coal cleaning technology project, {open_quotes}Self-Scrubbing Coal: An Integrated Approach to Clean Air.{close_quotes} The proposed demonstration project would take place on the site of the presently inactive Laurel Coal Preparation Plant in Shade Township, Somerset County, PA. A newly constructed, advanced design, coal preparation plant would replace the existing facility. The cleaned coal produced from this new facility would be fired in full-scale test burns at coal-fired electric utilities in Indiana, Ohio and PA as part of this project.

  7. Power technology complex for production of motor fuel from brown coals with power supply from NPPs

    International Nuclear Information System (INIS)

    With the present-day challenge of efficient use of low-grade coals and current restructuring of coal industry in the Russian Federation, it is urgent to organise the motor fuel production by the synthesis from low grade coals and heavy petroleum residues. With this objective in view, the Institute of Physics and Power Engineering of RF Minatom and Combustible Resources Institute of RF Mintopenergo proposed a project of a standard nuclear power technology complex for synthetic liquid fuel (SLF) production using fast neutron reactors for power supply. The proposed project has two main objectives: (1) Engineering and economical optimization of the nuclear power supply for SLF production; and (2) Engineering and economical optimization of the SLF production by hydrogenisation of brown coals and heavy petroleum residues with a complex development of advanced coal chemistry. As a first approach, a scheme is proposed with the use of existing reactor cooling equipment, in particular, steam generators of BN-600, limiting the effect on safety of reactor facility operation at minimum in case of deviations and abnormalities in the operation of technological complex. The possibility to exclude additional requirements to the equipment for nuclear facility cooling was also taken into account. It was proposed to use an intermediate steam-water circuit between the secondary circuit sodium and the coolant to heat the technological equipment. The only change required for the BN-600 equipment will be the replacement of sections of intermediate steam superheaters at the section of main steam superheaters. The economic aspects of synthetic motor fuel production proposed by the joint project depend on the evaluation of integral balances: thermal power engineering, chemical technology, the development of advanced large scale coal chemistry of high profitability; utilisation of ash and precious microelements in waste-free technology; production of valuable isotopes; radical solution of

  8. Fuel supply investment cost: coal and nuclear. Commercial electric power cost studies (6)

    International Nuclear Information System (INIS)

    This study presents an accounting model for calculating the capital investment requirements for coal and nuclear fuel supply facilities. The study addresses mining, processing, fabrication, and transportation of coal and nuclear fuels. A generic example is provided, for coal from different sources, and for nuclear fuel. The relationship of capital investment requirements to delivered prices is included in each example

  9. Role of the Liquids From Coal process in the world energy picture

    Energy Technology Data Exchange (ETDEWEB)

    Frederick, J.P.; Knottnerus, B.A. [ENCOAL Corp., Gillette, WY (United States)

    1997-12-31

    ENCOAL Corporation, a wholly owned indirect subsidiary of Zeigler Coal Holding Company, has essentially completed the demonstration phase of a 1,000 Tons per day (TPD) Liquids From Coal (LFC{trademark}) plant near Gillette, Wyoming. The plant has been in operation for 4{1/2} years and has delivered 15 unit trains of Process Derived Fuel (PDF{trademark}), the low-sulfur, high-Btu solid product to five major utilities. Recent test burns have indicated the PDF{trademark} can offer the following benefits to utility customers: lower sulfur emissions, lower NO{sub x} emissions, lower utilized fuel costs to power plants, and long term stable fuel supply. More than three million gallons of Coal Derived Liquid (CDL{trademark}) have also been delivered to seven industrial fuel users and one steel mill blast furnace. Additionally, laboratory characteristics of CDL{trademark} and process development efforts have indicated that CDL{trademark} can be readily upgraded into higher value chemical feedstocks and transportation fuels. Commercialization of the LFC{trademark} is also progressing. Permit work for a large scale commercial ENCOAL{reg_sign} plant in Wyoming is now underway and domestic and international commercialization activity is in progress by TEK-KOL, a general partnership between SGI International and a Zeigler subsidiary. This paper covers the historical background of the project, describes the LFC{trademark} process and describes the worldwide outlook for commercialization.

  10. Agenda and briefing book: Clean Coal Technology Coordinating Committee, September 16, 1991, Louisville, Kentucky

    Energy Technology Data Exchange (ETDEWEB)

    1991-09-16

    A considerable amount of time was spent discussing the Clean Air Act Amendments pending before Congress. Several members pointed out provisions of the legislation that would have serious impacts on the coal industry and the electric utility industry. The need for increased electricity in Florida raised the question about coal fired Power Plants. It is generally believed that most people in Florida do not know that over 55 percent of the electricity now comes from coal-fired generators. However, publicly, people will say they do not want coal-fired facilities built in Florida. People in Florida are concerned with the EMF Issue just as much as the source of power. It was stated that the coal industry has a very poor image and DOE should assume responsibility for improving the image of coal. it was agreed that it would take a considerable financial commitment to do this and that in addition to government the industry would have to be willing to contribute financially. The Partial results of a survey to utilities concerning the future use of clean coal technologies was reported. Utilities are not ignoring coal technologies but acknowledged that the amendments to the Clean Air Act would be the driving force in future decisions. It was learned through the survey that the DOE negotiation process in the Clean Coal Technology Program was in need of improvement. DOE had recently changed the procedure internally and it was anticipated that the procedure would be smoother in the future.

  11. Clean coal technology - Indian context

    Energy Technology Data Exchange (ETDEWEB)

    Mishra, B.C.; Varma, S.K.; Chakrabarti, R.K. [CMPDI, Ranchi (India)

    1997-12-31

    Indian coal reserves are substantial but their quality is poor. Quality is also falling as good reserves are mined out. More positively, sulphur and chlorine contents are low, as in general are toxic trace elements. Ash content of the coal can be reduced by coal preparation, although many customers at present will not pay the cost of coal preparation. Nonetheless plants are being built and their use will increase. Washed coal costs more, but is cheaper to transport and to burn, besides reducing ash quantity. An IGCC demonstration plant is being planned. 4 figs., 1 tab.

  12. DEVELOPMENT OF A NOVEL FINE COAL CLEANING SYSTEM

    Energy Technology Data Exchange (ETDEWEB)

    Manoj K. Mohanty

    2005-06-01

    The goal of the proposed project was to develop a novel fine coal separator having the ability to clean 1 mm x 0 size coal in a single processing unit. The novel fine coal separator, named as EG(Enhanced Gravity) Float Cell, utilizes a centrifugal field to clean 1 mm x 250 micron size coal, whereas a flotation environment to clean minus 250 micron coal size fraction. Unlike a conventional enhanced gravity concentrator, which rotates to produce a centrifugal field requiring more energy, the EG Float Cell is fed with a tangential feed slurry to generate an enhanced gravity field without any rotating part. A prototype EG Float Cell unit having a maximum diameter of 60 cm (24 inch) was fabricated during the first-half of the project period followed by a series of exploratory tests to make suitable design modification. Test data indicated that there was a significant concentration of coarse heavy materials in the coarse tailings discharge of the EG Float Cell. The increase in weight (%) of 1 mm x 250 micron (16 x 60 mesh) size fraction from 48.9% in the feed to 72.2% in the coarse tailings discharge and the corresponding increase in the ash content from 56.9% to 87.0% is indicative of the effectiveness of the enhanced gravity section of the EG Float Cell. However, the performance of the flotation section needs to be improved. Some of the possible design modifications may include more effective air sparging system for the flotation section to produce finer bubbles and a better wash water distributor.

  13. Hydrogenation Technology for Producing Clean Diesel Fuel

    Institute of Scientific and Technical Information of China (English)

    Chen Shuiyin; Xiong Zhenlin; Gao Xiaodong; Nie Hong

    2004-01-01

    With the standard of environmental protection becoming increasingly strict, it is required to remove sulfur and aromatics in diesel deeply. RIPP has developed several new hydrogenation catalysts and flexible processes, by means of which clean diesel fuel with low sulfur and low aromatic contents can be produced. From SRGO (Straight Run Gas Oil), which has an aromatic content of less than 30m%, a low sulfur and low aromatic diesel fuel or ultra-low sulfur diesel can be obtained by adopting a new process operating on highly active RN-series catalysts. From a feed with higher aromatic content (A=30~80m%),such as FCC-LCO, a low sulfur and low aromatic diesel fuel can be obtained by the SSHT, MHUG and DDA processes.

  14. Challenges and opportunities for clean coal technology

    International Nuclear Information System (INIS)

    A report is given of some presentations and discussions at the Sixth Clean Coal Technology Conference held in Reno, Nevada, 28 April - 1 May 1998. Accomplishments in 18 projects in the US DOE's Clean Coal Technology Programme were reported upon. The CCT Program has provided a portfolio of technologies to deal effectively with acid rain concerns but challenges remain in achieving ozone standards (an NOx control issue), fine particulate control of PM2.5 and CO2 emission reduction per the Kyoto Protocol in the absence of trading between developed and developing countries under a proposed Clean Development Mechanism and/or sequestration. 9 photos

  15. Conclusions drawn from actions implemented within the first stage of the Cracow program of energy conservation and clean fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Bieda, J.; Bardel, J.; Pierce, B.

    1995-12-31

    Since 1992 Brookhaven National Laboratory (BNL) and Pacific Northwest Laboratory (PNL), acting on behalf of the U.S. Department of Energy, executed the first stage of the Cracow Program of Energy Conservation and Clean Fossil Fuels, called also American-Polish Program of Actions for Elimination of Low Emission Sources in Cracow. The main contractor for BNL and PNL was the Cracow Development Office (BRK). The interest in improving the condition of Cracow air results from the fact that the standard for permissible air pollution was exceeded several times in Cracow and especially within the central part of the town. Therefore, air pollution appeared one of the most important problems that faced the municipal authorities. It followed from monitoring investigations that the high level of air pollutant concentration is caused by in-home coal-fired tile stoves operated in winter seasons and by coal- and coke-fired boiler houses simulated mainly in the central part of the town. The results obtained in first stage are presented. This paper is an attempt to formulate conclusions drawn from these works and recommendations with regard to the future policy of the town authorities; selected results are presented to clarify or illustrate the conclusions.

  16. Technology assessment of various coal-fuel options

    International Nuclear Information System (INIS)

    The technology assessment (TA) study of coal-based fuels presented in this report was performed for the Federal Ministry for Research and Technology. Its goal was to support decision-making of the Federal Ministry for Research and Technology in the field of coal conversion. Various technical options of coal liquefaction have been analyzed on the basis of hard coal as well as lignite -- direct liquefaction of coal (hydrogenation) and different possibilities of indirect liquefaction, that is the production of fuels (methanol, gasoline) by processing products of coal gasification. The TA study takes into consideration the entire technology chain from coal mining via coal conversion to the utilization of coal-based fuels in road transport. The analysis focuses on costs of the various options, overall economic effects, which include effects on employment and public budgets, and on environmental consequences compared to the use of liquid fuels derived from oil. Furthermore, requirements of infrastructure and other problems of the introduction of coal-based fuels as well as prospects for the export of technologies of direct and indirect coal liquefaction have been analyzed in the study. 14 figs., 10 tabs

  17. Re-generation of hydrofluoric acid and selective separation of Si(IV) in a process for producing ultra-clean coal

    Energy Technology Data Exchange (ETDEWEB)

    Steel, Karen M.; Patrick, John W. [Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering, Nottingham University, Nottingham NG7 2RD (United Kingdom)

    2004-11-25

    A technique for selectively separating approximately 65 wt.% of the Si(IV) in coal has been developed. The technique first uses aqueous hydrofluoric acid (HF) to react with aluminosilicates and quartz to form fluoride complexed Al and Si species in solution. Aluminium cations, in the form of Al(NO{sub 3}){sub 3}, are then added to the solution to complex fluoride as AlF{sub 2+} and hydrolyse the silicon fluoride species to silicon hydroxide, which precipitates as a gel and is removed by filtration. The solution is then distilled to recover a water stream, a nitric acid stream and a solid residue. The water stream is used to pyrohydrolyse the solid residue at temperatures in excess of 500C to liberate HF for recycling. To complete the circuit, the solid remaining after pyrohydrolysis is treated with the nitric acid stream to produce Al(NO{sub 3}){sub 3} for recycling. The technique satisfies the objective of not requiring on-going purchase of chemicals. The application of this work is primarily as part of a process for producing ultra-clean coal. As it is a technique for the selective separation of Al and Si from aluminosilicates, it may have application in other areas of mineral processing.

  18. Metamorphosis of the coal sector. From dirty to clean?; Metamorfose van de kolensector. Van vies naar schoon?

    Energy Technology Data Exchange (ETDEWEB)

    Van den Heuvel, S.

    2008-05-15

    The author surveys the extreme make-over of the coal industry: from dirty to clean. To many of us, coal might seem the energy source of the past. In many countries of Western Europe, coal mines were closed decades ago and in most cases gas has replaced coal for heating. However, the worldwide use of coal has never been as high as it is today and coal consumption is expected to increase by 70% until 2030. This increase has mainly to do with the rapid growth of energy consumption in China and India. There are, however, environmental problems related to coal, the most prominent being the very high CO2 emissions, causing climate change. Capturing CO2 and burying it in geological formation underground, a technology called Carbon Capture and Storage (CCS), could potentially alleviate the CO2 burden that is inevitably related to coal. However, CCS is not yet a proven method and there are many uncertainties to be taken away. This leaves a gap between the international and European policy goals of decreasing global CO2 emissions and the emissions caused by coal. In fact, it shows the necessity of reaching an international climate agreement (post Kyoto) and of creating a fair efforts sharing balance between the industrialized and developing countries. [Dutch] De auteur geeft een overzicht van de extreme veranderingen in de steenkoolindustrie om deze schoner te laten produceren. Voor velen van ons lijken kolen misschien de energiebron van het verleden. In veel landen van West-Europa, werden kolenmijnen tientallen jaren geleden gesloten en in de meeste gevallen heeft aardgas steenkool vervangen voor verwarming. Echter, het wereldwijde gebruik van steenkool is nog nooit zo hoog geweest als nu en het verbruik van steenkool zal naar verwachting met 70% stijgen tot 2030. Deze stijging heeft vooral te maken met de snelle groei van het energieverbruik in China en India. Er zijn echter milieuproblemen in verband met steenkool, waarvan de meest prominente de zeer hoge CO2-uitstoot

  19. Wood fuel from early thinning and plantation cleaning. Summary of an international review

    International Nuclear Information System (INIS)

    This paper summaries the results of an international of wood fuel from early thinning and plantation cleaning. The economic and biological benefits from early thinning have been well documented. However, removing forest biomass during early stages of stand development from sites which are low in one or more nutrients may contribute a loss of nutrients and organic matter. Depending on the pre-thinning density and the thinning intensity, the potential yield of wood fuel from early thinning may be as much as 79 dry tons per hectare. Thus, wood fuel from the thinnings could be an important source of revenue to forest owners and would contribute to domestic energy requirements. Motor-manual felling predominates in early thinning, mainly due to the lack of appropriate technology for thinning small trees. However, the productivity of motor-manual felling is greatly affected by the initial stand density and declines dramatically at densities greater than 10 000 stems per ha. Under these conditions, purpose-built wood fuel harvesters with small-tree harvesting capability offer the greatest potential for increasing felling productivity and reducing the cost of wood fuel. The cost of wood fuel from early thinnings varies widely between countries from USD 25.00 - 87.50 per dry ton depending on stand conditions, harvesting system, transport distance, domestic tax rates, and stumpage prices. At the low end of this range, wood fuel chips from early thinning are competitive with wood fuel produced from mill waste, the residues from clearfell operations, or from later thinnings

  20. Development of a multi-fuel burner for coal gasification process; Entwicklung eines Kombibrenners fuer den Kohlevergasungsprozess

    Energy Technology Data Exchange (ETDEWEB)

    Al-Halbouni, Ahmad; Rahms, Hendrik; Chalh-Andreas, Bachir [Brinkmann Industrielle Feuerungssysteme GmbH, Voerde (Germany); Giese, Anne [Gas- und Waerme-Institut Essen e.V., Essen (Germany); Benim, Ali Cemal [Fachhochschule Duesseldorf (Germany)

    2013-08-15

    In the course of a German ZIM cooperative research project, Brinkmann Industrielle Feuerungssysteme GmbH develops a supersonic oxygen-multi-fuel burner in close cooperation with its research partners Gas- und Waerme-Institut essen e.V. (GWI) and Duesseldorf University of Applied Sciences (FHD). This burner is capable of combusting natural gas as well as light oil efficiently, using pure oxygen as an oxidizer. It is intended to be used primarily for energy-intensive applications, but especially as a start-up burner for coal gasification processes. In these processes, specific operating conditions can be found, such as fluctuating pressures, high temperatures and inert atmospheres. Therefore, the main goal of the development is aimed at utilizing the high energy densities found in supersonic by oxy-fuel combustion. This article covers several burner development phases, from initial design and manufacturing activities to burner testing and optimisation. Results achieved up to now are presented and next steps defined. (orig.)

  1. Study of methanol-to-gasoline process for production of gasoline from coal

    Institute of Scientific and Technical Information of China (English)

    HE Tian-cai; CHENG Xiao-han; LI Ling; MENG Guo-ying

    2009-01-01

    The methanol-to-gasoline (MTG) process is an efficient way to produce liquid fuel.The academic basis of the coal-to-liquid process is described and two different syn-thesis processes are focused on: Fixed MTG process and Fluid Bed MTG process.Then,the superiority of the Fluid Bed MTG Process is pointed out relative to the Fixed MTG Process.In addition,the development of the coal-to-liquid technique in China is briefly summarized.

  2. Coal alternative fuel production from municipal solid wastes employing hydrothermal treatment

    International Nuclear Information System (INIS)

    Highlights: ► Experimental study of the conversion of Japanese municipal solid waste (MSW) to solid fuel by using hydrothermal treatment. ► Treatment system capable of processing up to 1 ton MSW per batch, applies medium-pressure saturated steam at 2 MPa for one hour. ► Energy required was 1/4th the energy content in the treated MSW. ► Raw MSW became easily dryable, having calorific value equal to that of low-grade sub-bituminous coal. ► Organic chlorine in the raw MSW was transformed to water-soluble inorganic chlorine. -- Abstract: An experimental study of the conversion of Japanese municipal solid waste (MSW) to solid fuel by using an innovative hydrothermal treatment has been performed. The treatment system is capable of processing up to 1 ton MSW per batch, applies medium-pressure saturated steam at the pressure of approximately 2 MPa in a stirred reactor for one hour. After undergoing the process, MSWs of various sizes and forms became slump materials that were easily dryable to a powdery product with a 10% moisture content and an average heating value of 20 MJ/kg (dry basis), which is equal to that of low-grade sub-bituminous coal. Because the MSW used in the experiments contained a significant amount of plastics, the reduction of chlorine content, which is known to promote clogging, corrosion, and dioxin formation in the furnace, was imperative. It was observed that water-insoluble organic chlorine generated from poly vinyl chloride containers was approximately 10,000 ppm (dry basis) in the raw MSW and was reduced to approximately 2000 ppm (dry basis) because of the transformation to water-soluble inorganic chlorine during the hydrothermal process. These changes in chlorine content were very evident at elevated temperature and pressure. These results indicate that the hydrothermal treatment is a viable way to treat MSW and obtain an alternative low chlorine content solid fuel.

  3. High-pressure coal fuel processor development

    Energy Technology Data Exchange (ETDEWEB)

    Greenhalgh, M.L.

    1992-11-01

    The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

  4. Survey and evaluation of current and potential coal beneficiation processes

    Energy Technology Data Exchange (ETDEWEB)

    Singh, S. P.N.; Peterson, G. R.

    1979-03-01

    Coal beneficiation is a generic term used for processes that prepare run-of-mine coal for specific end uses. It is also referred to as coal preparation or coal cleaning and is a means of reducing the sulfur and the ash contents of coal. Information is presented regarding current and potential coal beneficiation processes. Several of the processes reviewed, though not yet commercial, are at various stages of experimental development. Process descriptions are provided for these processes commensurate with the extent of information and time available to perform the evaluation of these processes. Conceptual process designs, preliminary cost estimates, and economic evaluations are provided for the more advanced (from a process development hierarchy viewpoint) processes based on production levels of 1500 and 15,000 tons/day (maf) of cleaned product coal. Economic evaluations of the coal preparation plants are conducted for several project financing schemes and at 12 and 15% annual after-tax rates of return on equity capital. A 9% annual interest rate is used on the debt fraction of the plant capital. Cleaned product coal prices are determined using the discounted cash flow procedure. The study is intended to provide information on publicly known coal beneficiation processes and to indicate the relative costs of various coal beneficiation processes. Because of severe timeconstraints, several potential coal beneficiation processes are not evaluated in great detail. It is recommended that an additional study be conducted to complement this study and to more fully appreciate the potentially significant role of coal beneficiation in the clean burning of coal.

  5. Advanced Coal Conversion Process Demonstration Project. Final technical progress report, January 1, 1995--December 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-05-01

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1995 through December 31, 1995. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal Process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal Process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,5000 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. During this reporting period, the primary focus for the ACCP Demonstration Project team was to expand SynCoal market awareness and acceptability for both the products and the technology. The ACCP Project team continued to focus on improving the operation, developing commercial markets, and improving the SynCoal products as well as the product`s acceptance.

  6. Underground Coal Thermal Treatment: Task 6 Topical Report, Utah Clean Coal Program

    Energy Technology Data Exchange (ETDEWEB)

    Smith, P.J.; Deo, M.; Edding, E.G.; Hradisky, M.; Kelly, K.E.; Krumm, R.; Sarofim, Adel; Wang, D.

    2014-08-15

    The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand the feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. CO2 storage. In order to help determine the amount of CO2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.

  7. Coal Cleaning Using Resonance Disintegration for Mercury and Sulfur Reduction Prior to Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Andrew Lucero

    2005-04-01

    Coal-cleaning processes have been utilized to increase the heating value of coal by extracting ash-forming minerals in the coal. These processes involve the crushing or grinding of raw coal followed by physical separation processes, taking advantage of the density difference between carbonaceous particles and mineral particles. In addition to the desired increase in the heating value of coal, a significant reduction of the sulfur content of the coal fed to a combustion unit is effected by the removal of pyrite and other sulfides found in the mineral matter. WRI is assisting PulseWave to develop an alternate, more efficient method of liberating and separating the undesirable mineral matter from the carbonaceous matter in coal. The approach is based on PulseWave's patented resonance disintegration technology that reduces that particle size of materials by application of destructive resonance, shock waves, and vortex generating forces. Illinois No.5 coal, a Wyodak coal, and a Pittsburgh No.8 coal were processed using the resonance disintegration apparatus then subjected to conventional density separations. Initial microscopic results indicate that up to 90% of the pyrite could be liberated from the coal in the machine, but limitations in the density separations reduced overall effectiveness of contaminant removal. Approximately 30-80% of the pyritic sulfur and 30-50% of the mercury was removed from the coal. The three coals (both with and without the pyritic phase separated out) were tested in WRI's 250,000 Btu/hr Combustion Test Facility, designed to replicate a coal-fired utility boiler. The flue gases were characterized for elemental, particle bound, and total mercury in addition to sulfur. The results indicated that pre-combustion cleaning could reduce a large fraction of the mercury emissions.

  8. DRY CLEANING OF COAL WITH AIR DENSE MEDIUM FLUIDIZED BED

    Institute of Scientific and Technical Information of China (English)

    陈清如; 杨毅; 余智敏; 李建明

    1990-01-01

    This paper deals with the experimental study of dry cleaning of coal with air dense medium fluidized bed. This technique opens up an efficient way of coal separation for vast areas in the country where water resources are in short supply or coals tend to slime seriously in wet process. Tests show that it can separate any kind of coal (6--50mm) efficiently. The probable error E, can reach 0.05--0.08. The separating density can be adjusted in the range of 1.0--2.0 g/cm3. This technique brings about enormous economic benifits.

  9. Strategic considerations for clean coal R and D

    International Nuclear Information System (INIS)

    While present interest in coal-fired power generation is centred on the developing countries, with new natural-gas-fired power stations predominating in the developed world, in the long term coal will return to being the fuel of choice for power generation for much of the world. To minimise the global impact of coal use it is essential, therefore, that coal technologies are developed that are efficient, clean and economically attractive. Techno-economic analyses of the options for coal are presented together with a strategic overview of potential lines of development. The broad conclusions are that new coal plants will not be truly competitive with natural gas until the price of gas increases to about 3.3 EURO/GJ, compared with a coal price of 1.3 EURO/GJ. Present state-of-the-art pulverised coal-fired plant is close to its optimum techno-economic performance and further improvements depend on the development of cost-effective super-alloys. However, there are good opportunities to increase the efficiency of coal use to greater than 50% (LHV basis) using gasification-based power generation cycles. Unless credit is given for the much lower emissions provided by these cycles, the pulverised coal and pressurised fluidised bed combustion will remain the most economic options. (author)

  10. Household Air Pollution from Coal and Biomass Fuels in China: Measurements, Health Impacts, and Interventions

    OpenAIRE

    Zhang, Junfeng; SMITH, KIRK R.

    2007-01-01

    Objective Nearly all China’s rural residents and a shrinking fraction of urban residents use solid fuels (biomass and coal) for household cooking and/or heating. Consequently, global meta-analyses of epidemiologic studies indicate that indoor air pollution from solid fuel use in China is responsible for approximately 420,000 premature deaths annually, more than the approximately 300,000 attributed to urban outdoor air pollution in the country. Our objective in this review was to help elucidat...

  11. Clean Coal Technologies: Accelerating Commercial and Policy Drivers for Deployment [Russian Version

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    Coal is and will remain the world’s most abundant and widely distributed fossil fuel. Burning coal, however, can pollute and it produces carbon dioxide. Clean coal technologies address this problem. The widespread deployment of pollution-control equipment to reduce sulphur dioxide, Nox and dust emissions from industry is just one example which has brought cleaner air to many countries. Since the 1970s, various policy and regulatory measures have created a growing commercial market for these clean coal technologies, with the result that costs have fallen and performance has improved. More recently, the need to tackle rising CO2 emissions to address climate change means that clean coal technologies now extend to include those for CO2 capture and storage (CCS). This short report from the IEA Coal Industry Advisory Board (CIAB) presents industry’s considered recommendations on how to accelerate the development and deployment of this important group of new technologies and to grasp their very signifi cant potential to reduce emissions from coal use. It identifies an urgent need to make progress with demonstration projects and prove the potential of CCS through government-industry partnerships. Its commercialisation depends upon a clear legal and regulatory framework,public acceptance and market-based financial incentives. For the latter, the CIAB favours cap-and-trade systems, price supports and mandatory feed-in tariffs, as well as inclusion of CCS in the Kyoto Protocol’s Clean Development Mechanism to create demand in developing economies where coal use is growing most rapidly. This report offers a unique insight into the thinking of an industry that recognises both the threats and growing opportunities for coal in a carbonconstrained world.

  12. Coal upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Nunes, S. [IEA Clean Coal Centre, London (United Kingdom)

    2009-10-15

    This report examines current technologies and those likely to be used to produce cleaner coal and coal products, principally for use in power generation and metallurgical applications. Consideration is also given to coal production in the leading coal producing countries, both with developed and developing industries. A range of technologies are considered. These include the coal-based liquid fuel called coal water mixture (CWM) that may compete with diesel, the production of ultra-clean coal (UCC) and coal liquefaction which competes with oil and its products. Technologies for upgrading coal are considered, especially for low rank coals (LRC), since these have the potential to fill the gap generated by the increasing demand for coal that cannot be met by higher quality coals. Potential advantages and downsides of coal upgrading are outlined. Taking into account the environmental benefits of reduced pollution achieved through cleaner coal and reduced transport costs, as well as other positive aspects such as a predictable product leading to better boiler design, the advantages appear to be significant. The drying of low rank coals improves the energy productively released during combustion and may also be used as an adjunct or as part of other coal processing procedures. Coal washing technologies vary in different countries and the implications of this are outlined. Dry separation technologies, such as dry jigging and electrostatic separation, are also described. The demonstration of new technologies is key to their further development and demonstrations of various clean coal technologies are considered. A number of approaches to briquetting and pelletising are available and their use varies from country to country. Finally, developments in upgrading low rank coals are described in the leading coal producing countries. This is an area that is developing rapidly and in which there are significant corporate and state players. 81 refs., 32 figs., 3 tabs.

  13. Coal derived-briquetted solid fuels

    International Nuclear Information System (INIS)

    Despite considerable progress, there are some regions in Central and Eastern Europe where residential heating is dominated by direct burning of bituminous or brown coal with all environmental consequences. In Poland, the residential heating consumes more than 25 mln tons of coal annually. It is estimated that during the heating season coal-fired individual home ovens and local heating stations in some Polish heavily populated areas contribute up to 22% in total emission of dust, 86% of SO2, and 56% of tar species. It has been proposed to replace some of the fuel, i.e. directly burnt coal by more ecological solid fuels in a form of briquettes. Considering the emissive characteristics, solid ecological fuels can be divided into two groups. The first one manufactured on the basis of high rank coals, and a cold briquetting with some additives capturing harmful combustion products. Production of these fuels is reasonably cheap and simple and the result of their use is a noticeable decrease in dust, sulfur oxides and soot emissions. The second one is ecologically clean fuel, i.e. smokeless fuel, produced on the basis of deeply degasified coals and a hot briquetting with the addition of either binder or caking coals and other compounds aimed at capturing harmful combustion products. The technology of production of the smokeless fuels is much more complicated and expensive, but as a result of their use a significant decrease in atmospheric emission is achieved. The best results are observed in decreasing the emission of tars and aromatic hydrocarbons. Technologies of production of ecological fuels are non-waste and non-emissive. The paper deals with the economical and technological side of briquetted solid fuels of both types. Emission factors of chosen components for ecological fuels with reference to primary coal are also discussed

  14. SYSTEM AND PROCESS FOR PRODUCTION OF METHANOL FROM COMBINED WIND TURBINE AND FUEL CELL POWER

    Science.gov (United States)

    The paper examines an integrated use of ultra-clean wind turbines and high temperature fuel cells to produce methanol, especially for transportation purposes. The principal utility and application of the process is the production of transportation fuel from domestic resources to ...

  15. Healy Clean Coal Project, Healy, Alaska final Environmental Monitoring Plan

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-14

    This Environmental Monitoring Plan (EMP) provides the mechanism to evaluate the integrated coal combustion/emission control system being demonstrated by the Healy Clean Coal Project (HCCP) as part-of the third solicitation of the US Department of Energy (DOE) Clean Coal Technology Demonstration Program (CCT-III). The EMP monitoring is intended to satisfy two objectives: (1) to develop the information base necessary for identification, assessment, and mitigation of potential environmental problems arising from replication of the technology and (2) to identify and quantify project-specific and site-specific environmental impacts predicted in the National Environmental Policy Act (NEPA) documents (Environmental Impact Statement and Record of Decision). The EMP contains a description of the background and history of development of the project technologies and defines the processes that will take place in the combustion and spray dryer absorber systems, including the formation of flash-calcined material (FCM) and its use in sulfur dioxide (SO{sub 2}) removal from the flue gases. It also contains a description of the existing environmental resources of the project area. The EMP includes two types of environmental monitoring that are to be used to demonstrate the technologies of the HCCP: compliance monitoring and supplemental monitoring. Compliance monitoring activities include air emissions, wastewater effluents, and visibility. Monitoring of these resources provide the data necessary to demonstrate that the power plant can operate under the required state and federal statutes, regulations, and permit requirements.

  16. Wear mechanism and wear prevention in coal-fueled diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Wakenell, J.F.; Fritz, S.G.; Schwalb, J.A.

    1991-07-01

    Over the past several years, interest has arisen in the development of coal-fired diesel engines for the purpose of efficiently utilizing the extensive coal reserves in the United States, and therefore reducing dependence on foreign oil. One process, which is being considered for use in producing clean coal fuel products involves mild gasification. This process produces by-products which can be further refined and, when blended with neat diesel fuel, used as an engine fuel. The purpose of this task was to test a blend of this coal liquid and diesel fuel (referred to as coal-lite) in an engine, and determine if any detrimental results were observed. This was done by performing a back-to-back performance and emission test of neat diesel fuel and the coal-lite fuel, followed by a 500-hour test of the coal-lite fuel, and completed by a back-to-back performance and emission test of the coal-lite fuel and neat diesel fuel.

  17. Wear mechanism and wear prevention in coal-fueled diesel engines. Task 7, Extended wear testing

    Energy Technology Data Exchange (ETDEWEB)

    Wakenell, J.F.; Fritz, S.G.; Schwalb, J.A.

    1991-07-01

    Over the past several years, interest has arisen in the development of coal-fired diesel engines for the purpose of efficiently utilizing the extensive coal reserves in the United States, and therefore reducing dependence on foreign oil. One process, which is being considered for use in producing clean coal fuel products involves mild gasification. This process produces by-products which can be further refined and, when blended with neat diesel fuel, used as an engine fuel. The purpose of this task was to test a blend of this coal liquid and diesel fuel (referred to as coal-lite) in an engine, and determine if any detrimental results were observed. This was done by performing a back-to-back performance and emission test of neat diesel fuel and the coal-lite fuel, followed by a 500-hour test of the coal-lite fuel, and completed by a back-to-back performance and emission test of the coal-lite fuel and neat diesel fuel.

  18. Physical Cleaning of Lakhra Coal by Dense Medium Separation Method

    Directory of Open Access Journals (Sweden)

    Sikandar Ali Channa

    2015-07-01

    Full Text Available This research is an attempt to upgrade Lakhra Lignite Coal using ?Dense Medium Separation? technique, to make it techno-environmentally acceptable product for different industries. The air-dried samples of ROM (Run of Mine coal were crushed, screened, ground and subjected to initial analysis and specific gravity based sink-float tests. The initial analysis of air-dried samples shows the average values of moisture 19%, volatile matter 22.33%, ash 27.41%, fixed carbon 31.26% and sulphur 4.98%. The investigational results of sink-float analysis indicate that physical cleaning at particle size range from -5.6 to +0.3 mm and 75% clean coal recovery can potentially reduce the ash yield and sulphur content of Lakhra coal up to 41 and 42.4% respectively. This washed coal is techno-environmentally acceptable yield and simultaneously qualifies the quality parameters set by various industries of Pakistan

  19. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.H.; Luttrell, G.H.; Adel, G.T. [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States)

    1995-11-01

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both the ash and sulfur contents of run-of-mine coals. The extent of cleaning depends on the liberation characteristics of the coal, which generally improve with reducing particle size. however, since most of the advanced technologies are wet processes, the clean coal product must be dewatered before it can be transported and burned in conventional boilers. This additional treatment step significantly increases the processing cost and makes the industrial applicability of these advanced technologies much less attractive. In order to avoid problems associated with fine coal dewatering, researchers at the Pittsburgh Energy Technology Center (PETC) developed a novel triboelectrostatic separation (TES) process that can remove mineral matter from dry coal. In this technique, finely pulverized coal is brought into contact with a material (such as copper) having a work function intermediate to that of the carbonaceous material and associated mineral matter. Carbonaceous particles having a relatively low work function become positively charged, while particles of mineral matter having significantly higher work functions become negatively charged. once the particles become selectively charged, a separation can be achieved by passing the particle stream through an electrically charged field. Details related to the triboelectrostatic charging phenomenon have been discussed elsewhere (Inculet, 1984).

  20. Potential contribution of the Clean Coal Program to reducing global emissions of greenhouse gases

    International Nuclear Information System (INIS)

    Environmental considerations of Clean Coal Program (CCP) initially focused on reducing emissions of sulfur dioxide (SO2) and nitrogen oxides (NOx) to the atmosphere. However, it has also become apparent that some Clean Coal Technologies (CCTs) may contribute appreciably to reducing emissions of carbon dioxide (CO2), thereby diminishing the rate of any global warming that may result from greenhouse effects. This is particularly true for CCTs involving replacement of a major portion of an existing facility and/or providing the option of using a different fuel form (the repowering CCTs). Because the subject of global-scale climate warming is receiving increased attention, the effect of CCTs on Co2 emissions has become a topic of increasing interest. The Final Programmatic Environmental Impact Statement for the Clean Coal Technology Demonstration Program projected that with full implementation of those repowering CCTs that would be most effective at reducing CO2 emissions (Pressurized Fluidized Bed and Coal Gasification Fuel Cell technologies), the national fossil-fuel Co2 emissions by the year 2010 would be roughly 90% of the emissions that would occur with no implementation of any CCTs by the same date. It is the purpose of this paper to examine the global effect of such a reduction in greenhouse gas emissions, and to compare that effect with effects of other strategies for reducing global greenhouse gas emissions

  1. Clean Coal Technology Demonstration Program: Project fact sheets 2000, status as of June 30, 2000

    International Nuclear Information System (INIS)

    The Clean Coal Technology Demonstration Program (CCT Program), a model of government and industry cooperation, responds to the Department of Energy's (DOE) mission to foster a secure and reliable energy system that is environmentally and economically sustainable. The CCT Program represents an investment of over$5.2 billion in advanced coal-based technology, with industry and state governments providing an unprecedented 66 percent of the funding. With 26 of the 38 active projects having completed operations, the CCT Program has yielded clean coal technologies (CCTs) that are capable of meeting existing and emerging environmental regulations and competing in a deregulated electric power marketplace. The CCT Program is providing a portfolio of technologies that will assure that U.S. recoverable coal reserves of 274 billion tons can continue to supply the nation's energy needs economically and in an environmentally sound manner. As the nation embarks on a new millennium, many of the clean coal technologies have realized commercial application. Industry stands ready to respond to the energy and environmental demands of the 21st century, both domestically and internationally, For existing power plants, there are cost-effective environmental control devices to control sulfur dioxide (S02), nitrogen oxides (NO,), and particulate matter (PM). Also ready is a new generation of technologies that can produce electricity and other commodities, such as steam and synthetic gas, and provide efficiencies and environmental performance responsive to global climate change concerns. The CCT Program took a pollution prevention approach as well, demonstrating technologies that remove pollutants or their precursors from coal-based fuels before combustion. Finally, new technologies were introduced into the major coal-based industries, such as steel production, to enhance environmental performance. Thanks in part to the CCT Program, coal-abundant, secure, and economical-can continue in its

  2. Coal diesel combined-cycle project. Comprehensive report to Congress: Clean Coal Technology Program

    Energy Technology Data Exchange (ETDEWEB)

    1994-05-01

    One of the projects selected for funding is a project for the design, construction, and operation of a nominal 90 ton-per-day 14-megawatt electrical (MWe), diesel engine-based, combined-cycle demonstration plant using coal-water fuels (CWF). The project, named the Coal Diesel Combined-Cycle Project, is to be located at a power generation facility at Easton Utilities Commission`s Plant No. 2 in Easton, Talbot County, Maryland, and will use Cooper-Bessemer diesel engine technology. The integrated system performance to be demonstrated will involve all of the subsystems, including coal-cleaning and slurrying systems; a selective catalytic reduction (SCR) unit, a dry flue gas scrubber, and a baghouse; two modified diesel engines; a heat recovery steam generation system; a steam cycle; and the required balance of plant systems. The base feedstock for the project is bituminous coal from Ohio. The purpose of this Comprehensive Report is to comply with Public Law 102-154, which directs the DOE to prepare a full and comprehensive report to Congress on each project selected for award under the CCT-V Program.

  3. Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Huffman, Gerald

    2012-12-31

    This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation's urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

  4. Options for improving the carbon dioxide capture process from flue gases of coal-fired power stations

    International Nuclear Information System (INIS)

    In many parts of the world, coal is used as a fuel source for the production of electricity. While coal is not a renewable resource, abundant reserves throughout the world make it a cheap fuel source and the preferred method of electric generation for many power companies. Based on the projected world energy consumption by fuel type, coal-fired power stations will be around for the next several decades. Unforunately, coal is a dirty fuel that results in massive emissions of nitrouns oxides (NOx), sulfur oxides (SOx), carbon dioxide (CO2), and in some cases, mercury, several initiatives have been undertaken to develop clean coal technologies. The capture of CO2 falls into this category, and represents the most pressing issue considering the recent passing of the Kyoto Protocol. In order for coal to be a viable fuel for electricity production in the future, an economical technology for CO2 capture is needed. Abrorption is the most suitable method for capturing CO2 from large power plants. Current research projects at the International Test Centre for CO2 Capture aim to reduce the cost of CO2 capture. Various aspects of the process are being investigated in order to achieve a net improvement in the process. One of the key areas of research ia in the actual absorber. The effective contact of gas and liquid phases inside the absorber is a crusial parameter. Traditional tray columns have been replaced in large part by columns containing random packing. Recently, the use of structured packing in absorbers has been increasing due to their successful performance in distillation columns. In addition to this development, new memberance-based absorbers are starting to emerge as a possible alternative to packed columns. In memberane absorbers a microporous membrance separates the gas and liquid phases. Contact between phases is made after the gas diffuses through the porous membrane. This type of arrangement allows for independent liquid and gas flow rates, thereby eliminating

  5. Hydrogen from coal: Production and utilisation technologies

    International Nuclear Information System (INIS)

    Although coal may be viewed as a dirty fuel due to its high greenhouse emissions when combusted, a strong case can be made for coal to be a major world source of clean H2 energy. Apart from the fact that resources of coal will outlast oil and natural gas by centuries, there is a shift towards developing environmentally benign coal technologies, which can lead to high energy conversion efficiencies and low air pollution emissions as compared to conventional coal fired power generation plant. There are currently several world research and industrial development projects in the areas of Integrated Gasification Combined Cycles (IGCC) and Integrated Gasification Fuel Cell (IGFC) systems. In such systems, there is a need to integrate complex unit operations including gasifiers, gas separation and cleaning units, water gas shift reactors, turbines, heat exchangers, steam generators and fuel cells. IGFC systems tested in the USA, Europe and Japan employing gasifiers (Texaco, Lurgi and Eagle) and fuel cells have resulted in energy conversions at efficiency of 47.5% (HHV) which is much higher than the 30-35% efficiency of conventional coal fired power generation. Solid oxide fuel cells (SOFC) and molten carbonate fuel cells (MCFC) are the front runners in energy production from coal gases. These fuel cells can operate at high temperatures and are robust to gas poisoning impurities. IGCC and IGFC technologies are expensive and currently economically uncompetitive as compared to established and mature power generation technology. However, further efficiency and technology improvements coupled with world pressures on limitation of greenhouse gases and other gaseous pollutants could make IGCC/IGFC technically and economically viable for hydrogen production and utilisation in clean and environmentally benign energy systems. (author)

  6. Clean fuel technologies and clean and reliable energy: a summary

    International Nuclear Information System (INIS)

    There are two major areas covered by this current Special Issue: Cleaner Fuel Technologies and Waste Processing. In addition, the Special Issue, also includes some recent developments in various fields of energy efficiency research. The first group of contributions considers in detail, hydrogen production from biomass and hydrogen production by the sorption-enhanced steam methane reforming process (SE-SMR). Biomass-related technologies are also discussed for a design of an integrated biorefinery, production of clean diesel fuel by co-hydrogenation of vegetable oil with gas oil and utilization of microwave and ultrasound pretreatments in the production of bioethanol from corn. Waste Processing aspects are considered in the second group of papers. This section includes integrated waste-to-energy plants, utilisation of municipal solid waste in the cement industry and urban supply and disposal systems. The third topic is intentionally made rather loose: it includes different research topics on various aspects of energy efficiency, e.g. resource-saving network design, new research on divided wall columns, vehicle logistics as process-network synthesis for energy consumption and CO2 reduction.

  7. Clean fuel technologies and clean and reliable energy: a summary

    Energy Technology Data Exchange (ETDEWEB)

    Bulatov, Igor [The University of Manchester, Centre for Process Integration, CEAS, Manchester (United Kingdom); Klemes, Jiri Jaromir [University of Pannonia, Centre for Process Integration and Intensification (CPI2), Research Institute of Chemical and Process Engineering, Faculty of Information Technology, Veszprem (Hungary)

    2011-08-15

    There are two major areas covered by this current Special Issue: Cleaner Fuel Technologies and Waste Processing. In addition, the Special Issue, also includes some recent developments in various fields of energy efficiency research. The first group of contributions considers in detail, hydrogen production from biomass and hydrogen production by the sorption-enhanced steam methane reforming process (SE-SMR). Biomass-related technologies are also discussed for a design of an integrated biorefinery, production of clean diesel fuel by co-hydrogenation of vegetable oil with gas oil and utilization of microwave and ultrasound pretreatments in the production of bioethanol from corn. Waste Processing aspects are considered in the second group of papers. This section includes integrated waste-to-energy plants, utilisation of municipal solid waste in the cement industry and urban supply and disposal systems. The third topic is intentionally made rather loose: it includes different research topics on various aspects of energy efficiency, e.g. resource-saving network design, new research on divided wall columns, vehicle logistics as process-network synthesis for energy consumption and CO{sub 2} reduction.

  8. Second annual clean coal technology conference: Proceedings. Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    1993-09-09

    The Second Annual Clean Coal Technology Conference was held at Atlanta, Georgia, September 7--9, 1993. The Conference, cosponsored by the US Department of Energy (USDOE) and the Southern States Energy Board (SSEB), seeks to examine the status and role of the Clean Coal Technology Demonstration Program (CCTDP) and its projects. The Program is reviewed within the larger context of environmental needs, sustained economic growth, world markets, user performance requirements and supplier commercialization activities. This will be accomplished through in-depth review and discussion of factors affecting domestic and international markets for clean coal technology, the environmental considerations in commercial deployment, the current status of projects, and the timing and effectiveness of transfer of data from these projects to potential users, suppliers, financing entities, regulators, the interested environmental community and the public. Individual papers have been entered separately.

  9. Advanced coal conversion process demonstration. Technical progress report, April 1--June 30, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high moisture, low rank coals to a high quality, low sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep bed stratifier cleaning process to separate the pyrite rich ash from the coal. The SynCoal process enhances low rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 Btu/lb, by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45 ton per hour unit is located adjacent to a unit train load out facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. During this report period the primary focus has been to continue the operation of the demonstration facility. Production has been going to area power plants. Modifications and maintenance work was also performed this quarter.

  10. Clean coal technologies for gas turbines

    International Nuclear Information System (INIS)

    The oil and gas fired gas turbines combined cycle penetration of industrial and utility applications has escalated rapidly due to the lower costs, higher efficiency and demonstrated reliability of gas turbine equipment in combination with gas economics. Recent advances in gas turbine design proven in operation above 240 MW, are establishing new levels of combined cycle plant efficiencies up to 59% and providing the potential for significant shift to gas turbine solid fuel power plant technologies. The research engineers of RENEL (Romanian Electricity Authority) give an great importance in their activity to those new technologies and solutions for the utilization of coal for energy (electric and thermal) production, especially for the Integrated Gasification Combines Cycle (IGCC). The application present IGCC process and a few considerations of the possibilities for the implementation of IGCC in the existing power plant. (Author)

  11. A study of toxic emissions from a coal-fired power plant utilizing the SNOX innovative clean coal technology demonstration. Volume 1, Sampling/results/special topics: Final report

    Energy Technology Data Exchange (ETDEWEB)

    1994-07-01

    This study was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE during 1993. The motivation for those assessments was the mandate in the 1990 Clean Air Act Amendments that a study be made of emissions of hazardous air pollutants (HAPs) from electric utilities. The report is organized in two volumes. Volume 1: Sampling describes the sampling effort conducted as the basis for this study; Results presents the concentration data on HAPs in the several power plant streams, and reports the results of evaluations and calculations conducted with those data; and Special Topics report on issues such as comparison of sampling methods and vapor/solid distributions of HAPs. Volume 2: Appendices include quality assurance/quality control results, uncertainty analysis for emission factors, and data sheets. This study involved measurements of a variety of substances in solid, liquid, and gaseous samples from input, output, and process streams at the Innovative Clean Coal Technology Demonstration (ICCT) of the Wet Sulfuric Acid-Selective Catalytic Reduction (SNOX) process. The SNOX demonstration is being conducted at Ohio Edison`s Niles Boiler No. 2 which uses cyclone burners to burn bituminous coal. A 35 megawatt slipstream of flue gas from the boiler is used to demonstrate SNOX. The substances measured at the SNOX process were the following: 1. Five major and 16 trace elements, including mercury, chromium, cadmium, lead, selenium, arsenic, beryllium, and nickel; 2. Acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate); 3. Ammonia and cyanide; 4. Elemental carbon; 5. Radionuclides; 6. Volatile organic compounds (VOC); 7. Semi-volatile compounds (SVOC) including polynuclear aromatic hydrocarbons (PAH); and 8. Aldehydes.

  12. Comparison of Coal-Based Dimethyl Ether and Diesel as Vehicle Fuels from Well to Wheel in China

    Institute of Scientific and Technical Information of China (English)

    ZHANG Liang; HUANG Zhen

    2009-01-01

    With life cycle assessment (LCA) methodology, a life cycle model of coal-based vehicle fuels (CBVFs) including coal-based dimethyl ether (CBDME) and coal-based diesel (CBD) is established. Their primary energy consumption (PEC) and global warming potential (GWP) from well to wheel including feedstock extraction, fuel production, fuel consumption in vehicle and energy transportation are calculated and compared. Results show that the life cycle PEC and GWP of CBD pathway are 1.17 and 1.34 times as CBDME pathway. Based on the above results, CBDME will become a choice with great potential to replace conventional petroleum-based diesel (CPBD) in China.

  13. New stage of clean coal technology in Japan; Clean coal technology no aratana tenkai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kawaguchi, Y. [Agency of Natural Resources and Energy, Tokyo (Japan)

    1996-09-01

    The paper described the positioning and new development of clean coal technology. Coal is an important resource which supplies approximately 30% of the energy consumed in all the world. In the Asian/Pacific region, especially, a share of coal in energy is high, around 60% of the world, and it is indispensable to continue using coal which is abundantly reserved. Japan continues using coal as an important energy among petroleum substituting energies taking consideration of the global environment, and is making efforts for development and promotion of clean coal technology aiming at further reduction of environmental loads. Moreover, in the Asian region where petroleum depends greatly upon outside the region, it is extremely important for stabilization of Japan`s energy supply that coal producing countries in the region promote development/utilization of their coal resources. For this, it is a requirement for Japan to further a coal policy having an outlook of securing stable coal supply/demand in the Asian region. 6 figs., 2 tabs.

  14. Integrated hot fuel gas cleaning for advanced gasification combined cycle process

    Energy Technology Data Exchange (ETDEWEB)

    Nieminen, M.; Kangasmaa, K.; Laatikainen, J.; Staahlberg, P.; Kurkela, E. [VTT Energy, Espoo (Finland). Gasification and Advanced Combustion

    1996-12-01

    The fate of halogens in pressurised fluidized-bed gasification and hot gas filtration is determined. Potential halogen removal sorbents, suitable for integrated hot gas cleaning, are screened and some selected sorbents are tested in bench scale. Finally, halogen removal results are verified using the PDU-scale pressurised fluidized-bed gasification and integrated hot gas cleaning facilities of VTT. The project is part of the JOULE II Extension programme of the European Union. (author)

  15. Methodology for comparing the health effects of electricity generation from uranium and coal fuels

    International Nuclear Information System (INIS)

    A methodology was developed for comparing the health risks of electricity generation from uranium and coal fuels. The health effects attributable to the construction, operation, and decommissioning of each facility in the two fuel cycle were considered. The methodology is based on defining (1) requirement variables for the materials, energy, etc., (2) effluent variables associated with the requirement variables as well as with the fuel cycle facility operation, and (3) health impact variables for effluents and accidents. The materials, energy, etc., required for construction, operation, and decommissioning of each fuel cycle facility are defined as primary variables. The materials, energy, etc., needed to produce the primary variable are defined as secondary requirement variables. Each requirement variable (primary, secondary, etc.) has associated effluent variables and health impact variables. A diverging chain or tree is formed for each primary variable. Fortunately, most elements reoccur frequently to reduce the level of analysis complexity. 6 references, 11 figures, 6 tables

  16. Geophysics and clean development mechanisms (CDM) - Applications to coal fires

    Science.gov (United States)

    Meyer, U.; Chen-Brauchler, D.; Schlömer, S.; Kus, J.; Lambrecht, A.; Rüter, H.; Fischer, C.; Bing, K.

    2009-04-01

    The largest hard coal resources worldwide are found in the coal belt through Northern China and Inner Mongolia. Because of still existing technological problems and a steeply rising demand of coal in this region the most coal fires occur. Once established, coal fires are difficult to extinguish, destroy large amounts of coal and are major challenge to the environment. The Sino-German coal fire research initiative "Innovative technologies for exploration, extinction and monitoring of coal fires in Northern China" conducts field investigations, laboratory measurements and experiments as well as numerical modelling of coal fires in close co-operation with Chinese coal fire fighting departments. A special task within this project is to help the Chinese partners to develop methodologies and project designs to extinguish coal fires under the frame of the Kyoto protocol. In practise, this task requires a robust method to estimate the CO2 baseline of coal fires including fire detection and monitoring. In order to estimate the fire volume, fire propagation and the resulting CO2 exhaust gas volume, different types of geophysical measurements are necessary as near surface temperature and gas measurements, ground penetrating radar etc. Three different types of CO2 exhaust gas estimations from coal fires are discussed: the energy approach, the volume approach and the direct approach. The energy approach highly depends on accurate near surface and gas temperature plus the gas flux data. The volume approach is based on radar and near surface geomagnetic surveying and monitoring. The direct approach relies on the exact knowledge of gas fluxes and volumes. All approaches need reference data as regional to local weather data and petrological parameters of the burning coal. The approaches are evaluated for their use in CO2 baseline estimations and thus for clean development mechanisms.

  17. CHEMICAL AND BIOLOGICAL CHARACTERIZATION OF LEACHATES FROM COAL SOLID WASTES

    Science.gov (United States)

    The report gives results of the chemical and mineralogical characterization of coal solid wastes. The wastes included three Lurgi gasification ashes, mineral residues from the SRC-1 and H-Coal liquefaction processes, two chars, two coal-cleaning residues, and a fly-ash-and-water-...

  18. Conceptual design of coal-fueled diesel system for stationary power applications

    Energy Technology Data Exchange (ETDEWEB)

    1989-05-01

    A preliminary conceptual design of a coal-fueled diesel system was prepared as part of a previous systems study. Since then, our team has accumulated extensive results from testing coal-water slurry on the 13-inch bore JS engine (400 rpm) in 1987 and 1988. These results provided new insights into preferred design concepts for engine components. One objective, therefore, was to revise the preliminary design to incorporate these preferred design concepts. In addition there were certain areas where additional, more detailed analysis was required as a result of the previous conceptual design. Another objective, therefore was to perform additional detailed design efforts, such as: (1) market applications and engine sizes, (2) coal-water slurry cleaning and grinding processes, (3) emission controls and hot gas contaminant controls, (4) component durability, (5) cost and performance assessments. (VC)

  19. Environmental issues affecting clean coal technology deployment

    Energy Technology Data Exchange (ETDEWEB)

    Miller, M.J. [Electric Power Research Inst., Palo Alto, CA (United States)

    1997-12-31

    The author outlines what he considers to be the key environmental issues affecting Clean Coal Technology (CCT) deployment both in the US and internationally. Since the international issues are difficult to characterize given different environmental drivers in various countries and regions, the primary focus of his remarks is on US deployment. However, he makes some general remarks, particularly regarding the environmental issues in developing vs. developed countries and how these issues may affect CCT deployment. Further, how environment affects deployment depends on which particular type of clean coal technology one is addressing. It is not the author`s intention to mention many specific technologies other than to use them for the purposes of example. He generally categorizes CCTs into four groups since environment is likely to affect deployment for each category somewhat differently. These four categories are: Precombustion technologies such as coal cleaning; Combustion technologies such as low NOx burners; Postcombustion technologies such as FGD systems and postcombustion NOx control; and New generation technologies such as gasification and fluidized bed combustion.

  20. Clean Coal and Gasification Technology: How it Works?

    OpenAIRE

    Marina Sidorová; Gabriel Wittenberger

    2006-01-01

    Gasification of coal is the oldest method for the production of hydrogen. Coal gasification is a process that converts coal from a solid to a gaseous state. The gas that is created is very similar to natural gas and can be used to produce chemicals, fertilizers, and/or the electric power [1]. Cleanest of all coal-based electric power technologies, gasification has significantly lower levels of air emissions (including volatile mercury), solid wastes, and wastewater.Due to its high efficiencie...

  1. Coal processing and utilization

    Science.gov (United States)

    Schilling, H.-D.

    1980-04-01

    It is noted that the rising price of oil as well as supply concerns have lead to an increase in the use of coal. It is shown that in order for coal to take a greater role in energy supply, work must commence now in the areas of coal extraction and processing. Attention is given to new technologies such as coke production, electricity and heat generation, coal gasification, and coal liquifaction. Also covered are a separator for nitrogen oxides and active coal regeneration. Finally, the upgrading of coal is examined.

  2. Nuclear and clean coal technology options for sustainable development in India

    International Nuclear Information System (INIS)

    Due to the growing energy needs along with increasing concerns towards control of greenhouse gas emissions, most developing countries are under pressure to find alternative methods for energy conversion and policies to make these technologies economically viable. Most of the energy is produced from fossil fuel in India which is not a sustainable source of energy. In this paper Indian power sector has been examined by using MARKAL model for introduction of clean coal and advanced nuclear technologies with implementation of energy conservation potential. The result shows that application of clean technologies gives energy security but not significant reduction in carbon dioxide emissions. When clean technologies apply with energy conservation a huge amount of CO2 can be reduced and also economically viable. Three scenarios including base case scenario have been developed to estimate the resource allocations and CO2 mitigation. The clean technologies with maximum savings potential shows 70% CO2 reduction in the year 2045.

  3. Characteristics of process oils from HTI coal/plastics co-liquefaction runs

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A. [and others

    1995-12-31

    The objective of this project is to provide timely analytical support to DOE`s liquefaction development effort. Specific objectives of the work reported here are presented. During a few operating periods of Run POC-2, HTI co-liquefied mixed plastics with coal, and tire rubber with coal. Although steady-state operation was not achieved during these brief tests periods, the results indicated that a liquefaction plant could operate with these waste materials as feedstocks. CONSOL analyzed 65 process stream samples from coal-only and coal/waste portions of the run. Some results obtained from characterization of samples from Run POC-2 coal/plastics operation are presented.

  4. Synthesis and analysis of jet fuels from shale oil and coal syncrudes

    Science.gov (United States)

    Antoine, A. C.; Gallagher, J. P.

    1976-01-01

    The technical problems involved in converting a significant portion of a barrel of either a shale oil or coal syncrude into a suitable aviation turbine fuel were studied. TOSCO shale oil, H-Coal and COED coal syncrudes were the starting materials. They were processed by distillation and hydrocracking to produce two levels of yield (20 and 40 weight percent) of material having a distillation range of approximately 422 to 561 K (300 F to 550 F). The full distillation range 311 to 616 K (100 F to 650 F) materials were hydrotreated to meet two sets of specifications (20 and 40 volume percent aromatics, 13.5 and 12.75 weight percent H, 0.2 and 0.5 weight percent S, and 0.1 and 0.2 weight percent N). The hydrotreated materials were distilled to meet given end point and volatility requirements. The syntheses were carried out in laboratory and pilot plant equipment scaled to produce thirty-two 0.0757 cu m (2-gal)samples of jet fuel of varying defined specifications. Detailed analyses for physical and chemical properties were made on the crude starting materials and on the products.

  5. The Mesaba Energy Project: Clean Coal Power Initiative, Round 2

    Energy Technology Data Exchange (ETDEWEB)

    Stone, Richard; Gray, Gordon; Evans, Robert

    2014-07-31

    The Mesaba Energy Project is a nominal 600 MW integrated gasification combine cycle power project located in Northeastern Minnesota. It was selected to receive financial assistance pursuant to code of federal regulations (?CFR?) 10 CFR 600 through a competitive solicitation under Round 2 of the Department of Energy?s Clean Coal Power Initiative, which had two stated goals: (1) to demonstrate advanced coal-based technologies that can be commercialized at electric utility scale, and (2) to accelerate the likelihood of deploying demonstrated technologies for widespread commercial use in the electric power sector. The Project was selected in 2004 to receive a total of $36 million. The DOE portion that was equally cost shared in Budget Period 1 amounted to about $22.5 million. Budget Period 1 activities focused on the Project Definition Phase and included: project development, preliminary engineering, environmental permitting, regulatory approvals and financing to reach financial close and start of construction. The Project is based on ConocoPhillips? E-Gas? Technology and is designed to be fuel flexible with the ability to process sub-bituminous coal, a blend of sub-bituminous coal and petroleum coke and Illinois # 6 bituminous coal. Major objectives include the establishment of a reference plant design for Integrated Gasification Combined Cycle (?IGCC?) technology featuring advanced full slurry quench, multiple train gasification, integration of the air separation unit, and the demonstration of 90% operational availability and improved thermal efficiency relative to previous demonstration projects. In addition, the Project would demonstrate substantial environmental benefits, as compared with conventional technology, through dramatically lower emissions of sulfur dioxide, nitrogen oxides, volatile organic compounds, carbon monoxide, particulate matter and mercury. Major milestones achieved in support of fulfilling the above goals include obtaining Site, High Voltage

  6. Flotation machine and process for removing impurities from coals

    Science.gov (United States)

    Szymocha, Kazimierz; Ignasiak, Boleslaw; Pawlak, Wanda; Kulik, Conrad; Lebowitz, Howard E.

    1995-01-01

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal.

  7. Refining clean fuels for the future

    International Nuclear Information System (INIS)

    To which extent transportation fuels will reasonably be changed in the coming years? LPG and natural gas are expected to challenge conventional fuels, hydrogen and methanol are bounded to possible fuel cells development. Among others, security of supply, competitive economics and environmental protection issues will be the key to the changes in the coming years. But taking into account expected transportation development, liquid fuels from oil should prevail as the reference energy. Though most of technologies and catalysts needed for the future are still existing or under marketing plans, the industry has to cope with the growing share of middle distillates. Indeed future zero heavy fuel-oil refineries are technically feasible through many existing and recent technologies. However their potential profitability is weighed down deeply by the very high investments and operating costs which are tied up. Tomorrow's main gasoline challenges deal with sulfur in FCC gasoline, aromatics and olefins contents together with a possible ban of ethers, hampering future octane demand and its technical feasibility. In a similar way diesel oil issues for the future imply a very deep desulfurization with possible aromatics hydrogenation and rings opening in order to comply with cetane and poly-aromatics ratings. Natural gas upgrading via syngas chemistry is still expected to open the way to clean fuels for the future via improved and integrated FT's GTL technologies which could as a matter provide most of future increases in clean fuels demand without decreasing the related fatal carbon losses as CO2. As an overall view, clean fuels production for the future is technically feasible. Advanced hydro-refining and hydro-conversion technologies open the way to clean fuels and allow the best flexibility in the gasoline/middle distillates ratio. However cost reduction remains a key issue since the huge investments needed are faced with low and volatile refining margins. In addition, CO2

  8. Proof of concept for integrating oxy-fuel combustion and the removal of all pollutants from a coal fired flame

    Energy Technology Data Exchange (ETDEWEB)

    Ochs, Thomas L.; Patrick, Brian (Jupiter Oxygen Corp.); Oryshchyn, Danylo B.; Gross, Alex (Jupiter Oxygen Corp.); Summers, Cathy A.; Simmons, William (CoalTeck LLC); Schoenfield, Mark (Jupiter Oxygen Corp.); Turner, Paul C.

    2005-01-01

    The USDOE/Albany Research Center and Jupiter Oxygen Corporation, working together under a Cooperative Research and Development Agreement, have demonstrated proof-of-concept for the integration of Jupiter’s oxy-fuel combustion and an integrated system for the removal of all stack pollutants, including CO2, from a coal-fired flame. The components were developed using existing process technology with the addition of a new oxy-coal combustion nozzle. The results of the test showed that the system can capture SOx, NOx, particulates, and even mercury as a part of the process of producing liquefied CO2 for sequestration. This is part of an ongoing research project to explore alternative methods for CO2 capture that will be applicable to both retrofit and new plant construction.

  9. Power Generation from Coal 2011

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    This report focuses mainly on developments to improve the performance of coal-based power generation technologies, which should be a priority -- particularly if carbon capture and storage takes longer to become established than currently projected. A close look is taken of the major ongoing developments in process technology, plant equipment, instrumentation and control. Coal is an important source of energy for the world, particularly for power generation. To meet the growth in demand for energy over the past decade, the contribution from coal has exceeded that of any other energy source. Additionally, coal has contributed almost half of total growth in electricity over the past decade. As a result, CO2 emissions from coal-fired power generation have increased markedly and continue to rise. More than 70% of CO2 emissions that arise from power generation are attributed to coal. To play its role in a sustainable energy future, its environmental footprint must be reduced; using coal more efficiently is an important first step. Beyond efficiency improvement, carbon capture and storage (CCS) must be deployed to make deep cuts in CO2 emissions. The need for energy and the economics of producing and supplying it to the end-user are central considerations in power plant construction and operation. Economic and regulatory conditions must be made consistent with the ambition to achieve higher efficiencies and lower emissions. In essence, clean coal technologies must be more widely deployed.

  10. RESEARCH ON CARBON PRODUCTS FROM COAL USING AN EXTRACTIVE PROCESS

    Energy Technology Data Exchange (ETDEWEB)

    Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo; Chong Chen; Brian Bland; David Fenton

    2002-03-31

    This report presents the results of a one-year effort directed at the exploration of the use of coal as a feedstock for a variety of industrially-relevant carbon products. The work was basically divided into three focus areas. The first area dealt with the acquisition of laboratory equipment to aid in the analysis and characterization of both the raw coal and the coal-derived feedstocks. Improvements were also made on the coal-extraction pilot plant which will now allow larger quantities of feedstock to be produced. Mass and energy balances were also performed on the pilot plant in an attempt to evaluate the scale-up potential of the process. The second focus area dealt with exploring hydrogenation conditions specifically aimed at testing several less-expensive candidate hydrogen-donor solvents. Through a process of filtration and vacuum distillation, viable pitch products were produced and evaluated. Moreover, a recycle solvent was also isolated so that the overall solvent balance in the system could be maintained. The effect of variables such as gas pressure and gas atmosphere were evaluated. The pitch product was analyzed and showed low ash content, reasonable yield, good coking value and a coke with anisotropic optical texture. A unique plot of coke yield vs. pitch softening point was discovered to be independent of reaction conditions or hydrogen-donor solvent. The third area of research centered on the investigation of alternate extraction solvents and processing conditions for the solvent extraction step. A wide variety of solvents, co-solvents and enhancement additives were tested with varying degrees of success. For the extraction of raw coal, the efficacy of the alternate solvents when compared to the benchmark solvent, N-methyl pyrrolidone, was not good. However when the same coal was partially hydrogenated prior to solvent extraction, all solvents showed excellent results even for extractions performed at room temperature. Standard analyses of the

  11. Coal conversion processes and analysis methodologies for synthetic fuels production. [technology assessment and economic analysis of reactor design for coal gasification

    Science.gov (United States)

    1979-01-01

    Information to identify viable coal gasification and utilization technologies is presented. Analysis capabilities required to support design and implementation of coal based synthetic fuels complexes are identified. The potential market in the Southeast United States for coal based synthetic fuels is investigated. A requirements analysis to identify the types of modeling and analysis capabilities required to conduct and monitor coal gasification project designs is discussed. Models and methodologies to satisfy these requirements are identified and evaluated, and recommendations are developed. Requirements for development of technology and data needed to improve gasification feasibility and economies are examined.

  12. Prospects for production of synthetic liquid fuel from low-grade coal

    Science.gov (United States)

    Shevyrev, Sergei; Bogomolov, Aleksandr; Alekssev, Maksim

    2015-01-01

    In the paper, we compare the energy costs of steam and steam-oxygen gasification technologies for production of synthetic liquid fuel. Results of mathematic simulation and experimental studies on gasification of low-grade coal are presented.

  13. Safety aspects of the cleaning and conditioning of radioactive sludge from spent fuel storage pool on 'RA' Research reactor in the Vinca Institute

    International Nuclear Information System (INIS)

    Spent fuel elements from nuclear reactors in the Vinca Institute have been temporary stored in water filled storage pool. Due to the fact that the water in the spent fuel elements storage pool have not been purified for a long time, all metallic components submerged in the water have been hardly corroded and significant amount of the sludge has been settled on the bottom of the pool. As a first step in improving spent fuel elements storage conditions and slowing down corrosion in the storage spent fuel elements pool we have decided to remove the sludge from the bottom of the pool. Although not high, but slightly radioactive, this sludge had to be treated as radioactive waste material. Some safety aspects and radiation protection measures in the process of the spent fuel storage pool cleaning are presented in this paper

  14. The Impact of Leachate From Clean Coal Technology Waste on the Stability of Clay and Synthetic Liners

    International Nuclear Information System (INIS)

    This project was developed to provide design criteria for landfill disposal sites used for sludges such as those generated using the Clean Coal Technologies (CCT) tested at the Public Service Company of Colorado's Arapahoe Power Plant. The CCT wastes used were produced at the Arapahoe Plant Unit No. 4 that was equipped with the integrated dry NOx/S2 emissions control system installed under the Clean Coal Technology (CCT) Program. The investigation emphasized the potential impact of clean coal technology materials (sodium and calcium injection systems, and urea injection) on the permeability and stability characteristics of clay liner materials and the stability of synthetic liner materials. Flexible-wall permeameters were used to determine the hydraulic conductivities (HC) of the clay liner materials impacted by various compactive conditions. Tests were conducted using the waste materials overlying the clay liner materials under wet/dry cycles, freeze/thaw cycles, and over 120-day periods. The impact of CCT materials on the characteristics of the clay liner materials studied in this project was minimal The HC measurements of the waste/clay liner systems were similar to the water/clay liner systems. HC decreased for clay liners compacted at moisture levels slightly higher than optimum (standard Procter) and increased for liners compacted at moisture levels lower than optimum (standard Procter). Although some swelling was evident in the sodium materials, the sludge materials did not have a negative impact on the integrity of the liners over 120-day tests. Wet/dry cycles tended to result in lower HC, while freeze/thaw cycles substantially increased HC for the liners tested

  15. Ecological aspects of water coal fuel transportation and application

    Directory of Open Access Journals (Sweden)

    Anna SHVORNIKOVA

    2010-01-01

    Full Text Available This paper deals with the aspects of influence of transportation process and burning of water coal fuel on an ecological condition of environment. Also mathematical dependences between coal ash level and power consumption for transportation are presented.

  16. Review of wood fuel from early thinning and plantation cleaning in Sweden

    International Nuclear Information System (INIS)

    Cleaning is carried out in order to influence the competitive situation of controlling the distribution of volume growth and the quality of timber. today, cleaning is conducted on about 200 000 ha per year in Sweden, most if which is cleaned motor-manually. The degree of mechanization is less than 1 % of. The biomass content of a cleaned stand is generally low, ranging from 1 to 2 tons dry matter per ha, but in some stands it can amount to over 20 tons per ha. The main motivation for removing biomass from a cleaned stand is the possibility of reducing overall cleaning costs. Few studies have been made on the environmental effects of the biomass removal in connection with cleaning. Studies made in connection with thinning, primarily conifers, indicate that the negative effects, such as increased soil acidification, reduced pools of base cations and nitrogen losses, can occur. It should be possible to compensate these undesirable effects through measures such as fertilization or ash recycling. Estimates of impacts on the flora and fauna suggests that effects are small and reversible. However, certain biotopes require special attention. Cost and performance studies indicate that it can be profitable for individual landowners to remove biofuel from very tall, dense stands, whereas better technology is required for more commercial operations. The development of such techniques is under way today. For large-scale removal of biofuel in connection with cleaning, simple forecasting tools will have to be developed that can help in determining when and where biomass should be removed. The decision should be based on economic, ecological and technical considerations. Furthermore, thorough analyses of the effects on the nutrient balance need to be made, and any reductions in the quality and growth of timber need to be quantified 21 refs

  17. Brown coal coke in biological waste water cleaning

    International Nuclear Information System (INIS)

    Biological sewage plants working by the activated sludge process are often confronted by the following problems: the formation of expanded bubbles, lack of decomposition performance, unstable operation and insufficient excess sludge dewatering. In the former East Germany, there is also the problem of too little nitrificaion/denitrification, caused by obsolete plant. The use of brown coal coke guarantees efficient cleaning of waste water. (orig.)

  18. Healy Clean Coal Project 1993 annual progress report

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    The primary objective of the HCCP is to demonstrate a new power plant design integrating an advanced combustor and heat recovery system coupled with both high and low temperature emission control processes. The parties anticipate that, if the demonstration project is successful, the technology will be commercialized in the late 1990s and be capable of (1) achieving significant reductions in the emissions of sulfur dioxide and the oxides of nitrogen from existing facilities, (2) providing for future energy needs in an environmentally acceptable manner. Alaskan bituminous and subbituminous coals will be the fuels. Emissions of SO{sub 2}, and NO{sub x}, from the plant will be controlled using TRW`s slagging coal combustor with limestone injection, in conjunction with a boiler supplied by Foster Wheeler. Further SO{sub 2}, and particulate removal will be accomplished using Joy Technologies, Inc.`s (Joy) Activated Recycle Spray Absorber System. Successful demonstration of these technologies is expected to result in NO{sub x}, emissions of less than 0.2 lb/MMBtu and SO{sub 2}, removal efficiencies greater than 90 percent. The heart of the system being demonstrated is a combustion system. Each combustor consists of two cylindrical sections followed by a short duct that connects the combustor to the boiler. A precombustor burns about 35 percent of the coal to preheat the main combustor secondary air. The preheated air enters the main combustor section tangentially to impart a swirling motion to the coal and air. The balance of the coal is injected axially through multiple injection ports at the front end of this cylindrical section.

  19. Field study of disposed solid wastes from advanced coal processes

    International Nuclear Information System (INIS)

    Radian Corporation and the North Dakota Energy and Environmental Research Center (EERC) are funded to develop information to be used by private industry and government agencies for managing solid wastes produced by advanced coal combustion processes. This information will be developed by conducting several field studies on disposed wastes from these processes. Data will be collected to characterize these wastes and their interactions with the environments in which they are disposed. Three sites were selected for the field studies: Colorado Ute's fluidized bed combustion (FBC) unit in Nucla, Colorado; Ohio Edison's limestone injection multistage burner (LIMB) retrofit in Lorain, Ohio; and Freeman United's mine site in central Illinois with wastes supplied by the nearby Midwest Grain FBC unit. During the past year, field monitoring and sampling of the four landfill test cases constructed in 1989 and 1991 has continued. Option 1 of the contract was approved last year to add financing for the fifth test case at the Freeman United site. The construction of the Test Case 5 cells is scheduled to begin in November, 1992. Work during this past year has focused on obtaining data on the physical and chemical properties of the landfilled wastes, and on developing a conceptual framework for interpreting this information. Results to date indicate that hydration reactions within the landfilled wastes have had a major impact on the physical and chemical properties of the materials but these reactions largely ceased after the first year, and physical properties have changed little since then. Conditions in Colorado remained dry and no porewater samples were collected. In Ohio, hydration reactions and increases in the moisture content of the waste tied up much of the water initially infiltrating the test cells

  20. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    Energy Technology Data Exchange (ETDEWEB)

    Paul A. Erickson

    2006-01-01

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  1. Release of inorganic trace elements from high-temperature gasification of coal

    Energy Technology Data Exchange (ETDEWEB)

    Blaesing, Marc

    2012-05-30

    The development of cleaner, more efficient techniques in next-generation coal power plants is becoming increasingly important, especially regarding to the discussion of the influence of CO{sub 2} emissions on global warming. A promising coal utilisation process is the integrated gasification combined cycle process. The direct use of the raw gas requires gas clean-up to prevent downstream parts of the gasifier from several problems. An increased efficiency and a decreased amount of harmful species can be achieved through hot fuel gas cleaning. This clean-up technique requires a comprehensive knowledge of the release characteristics of inorganic coal constituents. The aim of this thesis was to provide enhanced knowledge of the effect of key process parameters and of the chemical constitution of coal on the release of Na, K, S, and Cl species from high-temperature coal gasification. The experimental setup consisted of atmospheric flow tube furnaces and a pressurised furnace. In-situ analysis of the product gas was carried out using molecular beam mass spectrometry. A broad spectrum of different coals with assumed qualitative and quantitative differences in the release characteristics was investigated. Additionally, experiments with model substances were performed. The results of the experimental investigation were compared with thermodynamic calculations. Finally, recommendations, for the operation of a high-temperature gasifier are formulated. (orig.)

  2. Coal desulfurization process

    Science.gov (United States)

    Hsu, G. C.; Gavalas, G. R.; Ganguli, P. S.; Kalfayan, S. H.

    1978-01-01

    A method for chlorinolysis of coal is an organic solvent at a moderate temperautre and atmospheric pressure has been proven to be effective in removing sulfur, particularly the organic sulfur, from coal. Chlorine gas is bubbled through a slurry of moist coal in chlorinated solvent. The chlorinated coal is separated, hydrolyzed and the dechlorinated. Preliminary results of treating a high sulfutr (4.77%S) bituminous coal show that up to 70% organic sulfur, 90% hyritic sulfur and 76% total sulfur can be removed. The treated coal is dechlorinated by heating at 500 C. The presence of moisture helps to remove organic sulfur.

  3. Fuel properties of bituminous coal and pyrolytic oil mixture

    Science.gov (United States)

    Hamdan, Hazlin; Sharuddin, Munawar Zaman; Daud, Ahmad Rafizan Mohamad; Syed-Hassan, Syed Shatir A.

    2014-10-01

    Investigation on the thermal decomposition kinetics of coal-biooil slurry (CBS) fuel prepared at different ratios (100:0,70:30,60:40,0:100) was conducted using a Thermogravimetric Analyzer (TGA). The materials consisted of Clermont bituminous coal (Australia) and bio-oil (also known as pyrolytic oil) from the source of Empty Fruit Bunch (EFB) that was thermally converted by means of pyrolysis. Thermal decomposition of CBS fuel was performed in an inert atmosphere (50mL/min nitrogen) under non-isothermal conditions from room temperature to 1000°C at heating rate of 10°C/min. The apparent activation energy (Ea.) and pre-exponential factor (A) were calculated from the experimental results by using an Arrhenius-type kinetic model which first-order decomposition reaction was assumed. All kinetic parameters were tabulated based on the TG data obtained from the experiment. It was found that, the CBS fuel has higher reactivity than Clermont coal fuel during pyrolysis process, as the addition of pyrolytic oil will reduce the Ea values of the fuel. The thermal profiles of the mixtures showed potential trends that followed the characteristics of an ideal slurry fuel where high degradation rate is desirable. Among the mixture, the optimum fuel was found at the ratio of 60:40 of pyrolytic oil/coal mixtures with highest degradation rate. These findings may contribute to the development of a slurry fuel to be used in the vast existing conventional power plants.

  4. Life Cycle Assessment of Ultra-clean Micronized Coal Oil Water Slurry

    Institute of Scientific and Technical Information of China (English)

    Ji Ming; Xu Jing

    2009-01-01

    Life cycle assessment is applied to assess the ultra-clean micronized coal oil water slurry (UCMCOWS) with Si-maPro and the environmental impact of UCMCOWS on its whole life cycle is also analyzed. The result shows that the consumption of energy and products are increasing along with the deepening of UCMCOWS processing, UCMCOWS making and combustion arc the two periods which have a bigger impact on eco-system and hu-man health. As a new substitute of fuel, UCMCOWS merits to be utilized more efficiently and reasonably.

  5. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2004-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  6. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2005-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  7. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the first six months of the subject contract (DE-FC26-02NT-4159), from October 1, 2002 through March 31, 2003.

  8. Modeling technological learning and its application for clean coal technologies in Japan

    International Nuclear Information System (INIS)

    Estimating technological progress of emerging technologies such as renewables and clean coal technologies becomes important for designing low carbon energy systems in future and drawing effective energy policies. Learning curve is an analytical approach for describing the decline rate of cost and production caused by technological progress as well as learning. In the study, a bottom-up energy-economic model including an endogenous technological learning function has been designed. The model deals with technological learning in energy conversion technologies and its spillover effect. It is applied as a feasibility study of clean coal technologies such as IGCC (Integrated Coal Gasification Combined Cycle) and IGFC (Integrated Coal Gasification Fuel Cell System) in Japan. As the results of analysis, it is found that technological progress by learning has a positive impact on the penetration of clean coal technologies in the electricity market, and the learning model has a potential for assessing upcoming technologies in future.

  9. Need for Clean Coal Mining in India

    OpenAIRE

    Sribas Goswami

    2014-01-01

    Coal mining contributes largely towards economic development of the nation although it has a great impact on the human health. It also has an impact on a socio-cultural aspect of workers and people residing in and around coal mining areas. Thus a holistic approach to taking up with mining activities, keeping in mind the concerns over adjoining habitats and ecosystem, is the need of the hour. This requires identification of various sites where minerals exist, of various factors ranging from an...

  10. The element technology of clean fuel alcohol plant construction

    Energy Technology Data Exchange (ETDEWEB)

    Lee, D.S; Lee, D.S. [Sam-Sung Engineering Technical Institute (Korea, Republic of); Choi, C.Y [Seoul National University, Seoul (Korea, Republic of)] [and others

    1996-02-01

    The fuel alcohol has been highlighted as a clean energy among new renewable energy sources. However, the production of the fuel alcohol has following problems; (i)bulk distillate remains is generated and (ii) benzene to be used as a entertainer in the azeotropic distillation causes the environmental problem. Thus, we started this research on the ground of preserving the cleanness in the production of fuel alcohol, a clean energy. We examined the schemes of replacing the azotropic distillation column which causes the problems with MSDP(Molecular Sieve Dehydration Process) system using adsorption technology and of treating the bulk distillate remains to be generated as by-products. In addition, we need to develop the continuous yea station technology for the continuous operation of fuel alcohol plant as a side goal. Thus, we try to develop a continuous ethanol fermentation process by high-density cell culture from tapioca, a industrial substrate, using cohesive yeast. For this purpose, we intend to examine the problem of tapioca, a industrial substrate, where a solid is existed and develop a new process which can solve the problem. Ultimately, the object of this project is to develop each element technology for the construction of fuel alcohol plant and obtain the ability to design the whole plant. (author) 54 refs., 143 figs., 34 tabs.

  11. Characteristic parameters of the coal briquetting process

    International Nuclear Information System (INIS)

    The complete knowledge about the energetic sources in our country - Republic of Macedonia, point to the fact that coals are the most attractive and highly productive, still keeping the leadership position. However, the process of lignite exploitation causes their degradation and formation of large amount of fine fractions. The industrial valorization of these fractions is the most actual problem that could be solved only through production of made-up enriched fuels of wide spectrum of application. Thus, briquetting formation, with or without use of binds, is a process of mechanical or combined modification of coal fine fractions. At the same time, this is a possible procedure of solid fuels enrichment. Lignite from the Macedonian coal deposits 'Suvodol', 'Priskupshtina' and 'Brik-Berovo' is analyzed, in order to examine the possibilities of its briquetting. The results show that the 'Suvodol' lignite satisfy the quality requirements given with the MKS B H1.031 standard as well as the 'Brik-Berovo' lignite

  12. Physical cleaning of lakhra coal by dense medium separation method

    International Nuclear Information System (INIS)

    This research is an attempt to upgrade Lakhra Lignite Coal using 'Dense Medium Separation' technique, to make it techno-environmentally acceptable product for different industries. The air-dried samples of ROM (Run of Mine) coal were crushed, screened, ground and subjected to initial analysis and specific gravity based sink-float tests. The initial analysis of air-dried samples shows the average values of moisture 19%, volatile matter 22.33%, ash 27.41 %, fixed carbon 31.26% and sulphur 4.98%. The investigational results of sink-float analysis indicate that physical cleaning at particle size range from-5.6 to +0.3 mm and 75% clean coal recovery can potentially reduce the ash yield and sulphur content of Lakhra coal up to 41 and 42.4 % respectively. This washed coal is techno-environmentally acceptable yield and simultaneously qualifies the quality parameters set by various industries of Pakistan. (author)

  13. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    Energy Technology Data Exchange (ETDEWEB)

    R.H. Yoon; G.H. Luttrell; E.S. Yan; A.D. Walters

    2001-04-30

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both ash- and sulfur-forming minerals from coal. However, most of the processes involve fine grinding and use water as the cleaning medium; therefore, the clean coal products must be dewatered before they can be transported and burned. Unfortunately, dewatering fine coal is costly, which makes it difficult to deploy advanced coal cleaning processes for commercial applications. As a means of avoiding problems associated with the fine coal dewatering, the National Energy Technology Laboratory (NETL) developed a dry coal cleaning process in which mineral matter is separated from coal without using water. In this process, pulverized coal is subjected to triboelectrification before being placed in an electric field for electrostatic separation. The triboelectrification is accomplished by passing a pulverized coal through an in-line mixer made of copper. Copper has a work function that lies between that of carbonaceous material (coal) and mineral matter. Thus, coal particles impinging on the copper wall lose electrons to the metal thereby acquiring positive charges, while mineral matter impinging on the wall gain electrons to acquire negative charges. The charged particles then pass through an electric field where they are separated according to their charges into two or more products depending on the configuration of the separator. The results obtained at NETL showed that it is capable of removing more than 90% of the pyritic sulfur and 70% of the ash-forming minerals from a number of eastern U.S. coals. However, the BTU recoveries were less than desirable. The laboratory-scale batch triboelectrostatic separator (TES) used by NETL relied on adhering charged particles on parallel electrode surfaces and scraping them off. Therefore, its throughput will be proportional to the electrode surface area. If this laboratory device is scaled-up as is, it would

  14. Clean Coal Technology Programs: Program Update 2003 (Volume 1)

    Energy Technology Data Exchange (ETDEWEB)

    Assistant Secretary for Fossil Energy

    2003-12-01

    Annual report on the Clean Coal Technology Demonstration Program (CCTDP), Power Plant Improvement Initiative (PPII), and Clean Coal Power Initiative (CCPI). The report addresses the roles of the programs, implementation, funding and costs, project descriptions, legislative history, program history, environmental aspects, and project contacts. The project descriptions describe the technology and provides a brief summary of the demonstration results.

  15. Clean Coal Technology Programs: Completed Projects (Volume 2)

    Energy Technology Data Exchange (ETDEWEB)

    Assistant Secretary for Fossil Energy

    2003-12-01

    Annual report on the Clean Coal Technology Demonstration Program (CCTDP), Power Plant Improvement Initiative (PPII), and Clean Coal Power Initiative (CCPI). The report addresses the roles of the programs, implementation, funding and costs, project descriptions, legislative history, program history, environmental aspects, and project contacts. The project descriptions describe the technology and provides a brief summary of the demonstration results.

  16. Electricity and fluid fuels from biomass and coal using advanced technologies: a cost comparison for developing country applications

    International Nuclear Information System (INIS)

    Recent analyses of alternative global energy supply strategies, such as the forthcoming report of the Intergovernmental Panel on Climate Change (IPCC), to be published in 1996, have drawn attention to the possibility that biomass modernized with advanced technologies could play an important role in meeting global energy needs in the next century. This paper discusses two promising classes of advanced technologies that offer the potential for providing modem energy carriers (electricity and fluid fuels) from biomass at competitive costs within one or two decades. These technologies offer significantly more efficient use of land than currently commercial technologies for producing electricity and fluid fuels from biomass, as well as substantially improved energy balances. Electricity is Rely to be the first large market for modernized biomass, but the potential market for fluid fuel production is likely to be much larger. As coal is likely to present a more serious competitive challenge to biomass in the long run, we present an economic comparison with coal-based electricity and fluid fuels. A meaningful economic comparison between coal and biomass is possible because these feedstocks are sufficiently alike in their physical characteristics that similar conversion technologies may well be used for producing electricity and fluid fuels from them. When similar conversion technologies are used for both feedstocks, the relative costs of electricity or fluid fuels will be determined by the distinguishing technical characteristics of the feedstocks (sulphur content, moisture content and reactivity) and by the relative feedstock prices. Electric power generation from biomass and coal are compared here using an advanced integrated gasifier/gas turbine cycle that offers the potential for achieving high efficiency, low unit capital cost and low local pollutant emissions: the steam-injected gas turbine coupled to an air-blown gasifier. For both feedstocks, generation costs are

  17. Use of pyrolysis gas from coal as reburn fuel. Final report; Einsatz von kohlestaemmigem Pyrolysegas als Reduktionsbrennstoff. Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Greul, U.; Magel, C.; Moersch, O.; Ruediger, H.; Storm, C.; Schnell, U.; Spliethoff, H.; Hein, K.R.G.

    1996-12-31

    The research project`s aim was to reduce nitrogen emissions from pulverized-coal furnaces by fuel staging with pyrolysis gas from coal. The test fuels were 6 German and Australian coals. The aim achieved has been the statement that the described method is an adequate means to attain to and remain below emission values of 200 mg/m{sup 3}. The method of fuel staging using coal-original gases was investigated with tests focussing the most important process parameters such as coal type, devolatilization ratio, temperature, residence time, and stoichiometry. The relevant features determined with an entrained flow reactor and with a fluidized-bed reactor were the impact of devolatilization temperatures on carbonized residue and pyrolysis products, the distribution of fuel nitrogen, and the quality of gas and tar, including the respective effects on NO{sub x} formation and reduction in staged combustion. The validation of the mathematical model was done with the experimentally obtained data. The criteria considered fundamental for achieving the NO{sub x} reduction level are temperature, air ratio, and residence time in the reduction zone of the furnace. The pyrolysis tests manifested the strong influence of the coal type and the devolatilization conditions on the composition of the gases and the attainable NO{sub x} reduction. The tars in the pyrolysis gases, with their nitrogen compounds, improve the reducing effect of available nitrogen oxides. By using pyrolysis gases from coal as reburning fuel, NO{sub x} emissions of less than 200 mg/m{sup 3} can be obtained at air ratios around 0.95. (orig./SR) [Deutsch] Das Forschungsprojekt verfolgte das Ziel mit 6 deutschen und australischen Kohlen die Stickoxidemissionen aus Kohlestaubfeuerungen durch Brennstoffstufung mit Pyrolysegas als Reduktionsbrennstoff zu verringern. Das erreichte Ziel war der Nachweis, dass mit dem beschriebenen Verfahren NO{sub x}-Emissionswerte von 200 mg/m{sup 3} erreicht und unterschritten werden

  18. Hydrogen as alternative clean fuel: Economic analysis

    International Nuclear Information System (INIS)

    In analogy to biofuel production from biomasses, the electrolytic conversion of other renewable energies into hydrogen as an alternative clean fuel is considered. This solution allows the intermittent renewable energy sources, as photovoltaics and wind energy, to enhance their development and enlarge the role into conventional fuel market. A rough economic analysis of hydrogen production line shows the costs, added by electrolysis and storage stages, can be recovered by properly accounting for social and environmental costs due to whole cycle of conventional fuels, from production to use. So, in a perspective of attaining the economic competitiveness of renewable energy, the hydrogen, arising from intermittent renewable energy sources, will be able to compete in the energy market with conventional fuels, making sure that their substitution will occur in a significant amount and the corresponding environment

  19. Radiation-thermal processes of conversion in the coals

    International Nuclear Information System (INIS)

    effect in the generation of active hydrocarbons radicals from fuel oil, which play active role in the conversion of organic coal mass to the liquid and gas products. Under the optimal condition ( T=450 degrees centigrade, P=0,1 MPa, τ=20-25 minutes, (Rh/L)=3/1), up to 58% of the cleaned Yeni koy lignites converted to liquid and gaseous products. The fraction of liquid products of Co-pyrolysis of coals with oil fraction at optimal condition is determined. It is obvious that because of the destruction effect of the accelerated electron beam up to 19,2% liquid products are light fractions Tb0C. In these conditions, more than 55% sulphur content of the lignites is separated in the form of H2S and COS. b)Gasification: The radiation-thermal gasification reactions of various types of carbon (graphite, active coal and semi coke) with H20 and CO2 have been studied. The radiation effects are essential at the temperatures lower 500 degrees centigrade. It is connected to reactions of decomposition of gasified agents (H2O, CO2) and intermediate products of their decomposition (OH, CO2* and other). Studies have been made of the formation of H2 and CO at temperatures between 20 and 700 degrees centigrade on reacting graphite, activated carbon and semi coke with steam and carbon dioxide, respectively, in the presence of gamma radiation. The highest rates of H2 and CO formation were observed on the gasification of semi coke. Investigation has been made of the temperature of semi coke production from lignite and also of the effect of preirradiation dose on the rate of CO formation in the semi coke/CO2 system. An increase in the semi coke production temperature from 500 to 700 degrees centigrade reduced its reactivity with carbon dioxide by a factor of 1.4. Preirradiation of the semi coke with 200 kJ/kg decrease the reactivity by a factor of 2.8. A discussion is given of the mechanism of the effect of gamma-radiation on the gasification processes of different carbons in steam and carbon

  20. The Clean Coal Program's contributions to addressing the requirements of the Clean Air Act Amendments of 1990

    International Nuclear Information System (INIS)

    The purpose of this paper is to examine the potential contributions of the US Department of Energy's Clean Coal Program (CCP) to addressing the requirements of the Clean Air Act (CAA) Amendments of 1990 (CAA90). Initially funded by Congress in 1985, the CCP is a government and industry co-funded effort to demonstrate a new generation of more efficient, economically feasible, and environmentally acceptable coal technologies in a series of full- scale ''showcase'' facilities built across the country. The CCP is expected to provide funding for more than $5 billion of projects during five rounds of competition, with at least half of the funding coming from the private sector. To date, 42 projects have been selected in the first 4 rounds of the CCP. The CAA and amendments form the basis for regulating emissions of air pollutants to protect health and the environment throughout the United States. Although the origin of the CAA can be traced back to 1955, many amendments passed since that time are testimony to the iterative process involved in the regulation of air pollution. Three key components of CAA90, the first major amendments to the CAA since 1977, include mitigation measures to reduce levels of (1) acid deposition, (2) toxic air pollutants, and (3) ambient concentrations of air pollutants. This paper focuses on the timeliness of clean coal technologies in contributing to these provisions of CAA90

  1. Application of Commercial Sorbent into Coal-derived Syngas Desulfurization Field for Clean Coal technologies Development

    OpenAIRE

    Chien, H.-Y.

    2015-01-01

    Advanced applications of producer gas (e.g. fuel cells, catalytic processes for liquid fuels production) require deep gas cleaning. Dry desulfurization technologies of fuel gas select appropriate sorbents according to material’s physical and chemical properties like sulfur capacity, attainable sulphur concentration in gas, price, etc.. The properties of a commercial sorbent were determined by means of XRD, ICP-OES, SEM and surface area measurement. The main components of the sorbent were ZnO,...

  2. Comprehensive report to Congress, Clean Coal Technology program: Wabash River Coal Gasification Repowering Project

    International Nuclear Information System (INIS)

    Funding has been requested from DOE for the design, construction, and operation of a nominal 2544 ton-per-day (TPD) (265 MWe) two-stage, oxygen-blown, coal gasification combined-cycle (CGCC) repowering demonstration project, to be named the Wabash River Coal Gasification Repowering Project. The CGCC system will consist of an oxygen-blown, entrained-flow, Two-stage coal gasifier, which is capable of utilizing high sulfur bituminous coal; a gas conditioning system for removing sulfur compounds and particulates; systems or mechanical devices for improved coal feed; a combined-cycle power generation system wherein the conditioned fuel gas is combusted in a combustion turbine generator; a heat recovery steam generator; a gas cleanup system; and all necessary coal handling equipment

  3. Hydrogen production from coal

    Science.gov (United States)

    1975-01-01

    The gasification reactions necessary for the production of hydrogen from montana subbituminous coal are presented. The coal composition is given. The gasifier types mentioned include: suspension (entrained) combustion; fluidized bed; and moving bed. Each gasification process is described. The steam-iron process, raw and product gas compositions, gasifier feed quantities, and process efficiency evaluations are also included.

  4. Composition of neutral oils obtained in processing coals from Kansko-Achinsk basin

    Energy Technology Data Exchange (ETDEWEB)

    Plotskii, E.Y.; Kirilets, V.M.; Sidel' nikov, V.N.; Utkin, V.A.

    1986-03-01

    The authors used isopropyl alcohol as a solvent for coal from the Nazarovo deposit of the Kansko-Achinsk Basin. The separation and analysis of the liquid product obtained by supercritical dissolution (SCD) were performed in accordance with the scheme of separation and analysis of products from supercritical dissolution of coal presented in the paper. The group composition of the SCD liquid product and the elemental composition of the compounds recovered from this product (benzene-solubles, nitrogen bases, carboxylic acids, phenols, asphaltenes, paraffins, and neutral oils) are evidence of its value as a raw material for the production of motor fuels and as a raw material for the chemical industry.

  5. Clean electricity through advanced coal technologies handbook of pollution prevention and cleaner production

    CERN Document Server

    Cheremisinoff, Nicholas P

    2012-01-01

    Coal power is a major cause of air pollution and global warming and has resulted in the release of toxic heavy metals and radionuclides, which place communities at risk for long-term health problems. However, coal-fired power plants also currently fuel 41% of global electricity. Clean Electricity Through Advanced Coal Technologies discusses the environmental issues caused by coal power, such as air pollution, greenhouse gas emissions and toxic solid wastes. This volume focuses on increasingly prevalent newer generation technologies with smaller environmental footprints than the existing c

  6. Combustion characterization of beneficiated coal-based fuels

    Energy Technology Data Exchange (ETDEWEB)

    Chow, O.K.; Levasseur, A.A.

    1995-11-01

    The Pittsburgh Energy Technology Center (PETC) of the U.S. Department of Energy is sponsoring the development of advanced coal-cleaning technologies aimed at expanding the use of the nation`s vast coal reserves in an environmentally and economically acceptable manner. Because of the lack of practical experience with deeply beneficiated coal-based fuels, PETC has contracted Combustion Engineering, Inc. to perform a multi-year project on `Combustion Characterization of Beneficiated Coal-Based Fuels.` The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of Beneficiated Coal-Based Fuels (BCs) influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs.

  7. Clean Coal Technology Demonstration Program: Project fact sheets 2000, status as of June 30, 2000

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-09-01

    The Clean Coal Technology Demonstration Program (CCT Program), a model of government and industry cooperation, responds to the Department of Energy's (DOE) mission to foster a secure and reliable energy system that is environmentally and economically sustainable. The CCT Program represents an investment of over $5.2 billion in advanced coal-based technology, with industry and state governments providing an unprecedented 66 percent of the funding. With 26 of the 38 active projects having completed operations, the CCT Program has yielded clean coal technologies (CCTs) that are capable of meeting existing and emerging environmental regulations and competing in a deregulated electric power marketplace. The CCT Program is providing a portfolio of technologies that will assure that U.S. recoverable coal reserves of 274 billion tons can continue to supply the nation's energy needs economically and in an environmentally sound manner. As the nation embarks on a new millennium, many of the clean coal technologies have realized commercial application. Industry stands ready to respond to the energy and environmental demands of the 21st century, both domestically and internationally, For existing power plants, there are cost-effective environmental control devices to control sulfur dioxide (S02), nitrogen oxides (NO,), and particulate matter (PM). Also ready is a new generation of technologies that can produce electricity and other commodities, such as steam and synthetic gas, and provide efficiencies and environmental performance responsive to global climate change concerns. The CCT Program took a pollution prevention approach as well, demonstrating technologies that remove pollutants or their precursors from coal-based fuels before combustion. Finally, new technologies were introduced into the major coal-based industries, such as steel production, to enhance environmental performance. Thanks in part to the CCT Program, coal--abundant, secure, and economical

  8. Working group report: methane emissions from fuel combustion and industrial processes

    International Nuclear Information System (INIS)

    This paper lists the source categories which are currently recognised as minor sources of methane. These fall into five broad groups: stationary fuel combustion (residential combustion of fuels, solid waste incineration at home sites, on-site agricultural waste burning, industrial and utility combustion of coal, wood, oil and gas, commercial and industrial waste incineration); mobile fuel combustion; non-combustion industrial processes (primary metals production, chemical manufacturing processes, petroleum refining, commercial charcoal manufacturing waste treatments); minor energy production sources (storage and distribution of automotive fuels, geothermal energy production; peat mining operations, oil shale mining operations); and miscellaneous sources. The paper also presents a preliminary estimate of global methane emissions from these minor sources and the results of the working group's discussion on recommendations for the IPCC/OECD methodology and specific research needs. A list of control options for emissions from minor sources is provided. 2 tabs

  9. Prospects for production of synthetic liquid fuel from low-grade coal

    Directory of Open Access Journals (Sweden)

    Shevyrev Sergei

    2015-01-01

    Full Text Available In the paper, we compare the energy costs of steam and steam-oxygen gasification technologies for production of synthetic liquid fuel. Results of mathematic simulation and experimental studies on gasification of low-grade coal are presented.

  10. DEVELOPMENT OF OTM SYNGAS PROCESS AND TESTING OF SYNGAS-DERIVED ULTRA-CLEAN FUELS IN DIESEL ENGINES AND FUEL CELLS

    Energy Technology Data Exchange (ETDEWEB)

    E.T. (Skip) Robinson; James P. Meagher; Ravi Prasad

    2001-10-31

    This topical report summarizes work accomplished for the Program from January 1 through September 15, 2001 in the following task areas: Task 1--materials development; Task 2--composite element development; Task 3--tube fabrication; Task 4--reactor design and process optimization; Task 5--catalyst development; Task 6--P-1 operation; Task 8--fuels and engine testing; and Task 10--project management. OTM benchmark material, LCM1, exceeds the commercial oxygen flux target and was determined to be sufficiently robust to carry on process development activities. Work will continue on second-generation OTM materials that will satisfy commercial life targets. Three fabrication techniques for composite elements were determined to be technically feasible. These techniques will be studied and a lead manufacturing process for both small and large-scale elements will be selected in the next Budget Period. Experiments in six P-0 reactors, the long tube tester (LTT) and the P-1 pilot plant were conducted. Significant progress in process optimization was made through both the experimental program and modeling studies of alternate reactor designs and process configurations. Three tailored catalyst candidates for use in OTM process reactors were identified. Fuels for the International diesel engine and Nuvera fuel cell tests were ordered and delivered. Fuels testing and engine development work is now underway.

  11. DEVELOPMENT OF OTM SYNGAS PROCESS AND TESTING OF SYNGAS-DERIVED ULTRA-CLEAN FUELS IN DIESEL ENGINES AND FUEL CELLS; TOPICAL

    International Nuclear Information System (INIS)

    This topical report summarizes work accomplished for the Program from January 1 through September 15, 2001 in the following task areas: Task 1--materials development; Task 2--composite element development; Task 3--tube fabrication; Task 4--reactor design and process optimization; Task 5--catalyst development; Task 6--P-1 operation; Task 8--fuels and engine testing; and Task 10--project management. OTM benchmark material, LCM1, exceeds the commercial oxygen flux target and was determined to be sufficiently robust to carry on process development activities. Work will continue on second-generation OTM materials that will satisfy commercial life targets. Three fabrication techniques for composite elements were determined to be technically feasible. These techniques will be studied and a lead manufacturing process for both small and large-scale elements will be selected in the next Budget Period. Experiments in six P-0 reactors, the long tube tester (LTT) and the P-1 pilot plant were conducted. Significant progress in process optimization was made through both the experimental program and modeling studies of alternate reactor designs and process configurations. Three tailored catalyst candidates for use in OTM process reactors were identified. Fuels for the International diesel engine and Nuvera fuel cell tests were ordered and delivered. Fuels testing and engine development work is now underway

  12. A Hybrid Gas Cleaning Process for Production of Ultraclean Syngas

    Energy Technology Data Exchange (ETDEWEB)

    Merkel, T.C.; Turk, B.S.; Gupta, R.P.; Cicero, D.C.; Jain, S.C.

    2002-09-20

    The overall objective of this project is to develop technologies for cleaning/conditioning IGCC generated syngas to meet contaminant tolerance limits for fuel cell and chemical production applications. The specific goals are to develop processes for (1) removal of reduced sulfur species to sub-ppm levels using a hybrid process consisting of a polymer membrane and a regenerable ZnO-coated monolith or a mixed metal oxide sorbent; (2) removal of hydrogen chloride vapors to sub-ppm levels using an inexpensive, high-surface-area material; and (3) removal of NH3 with acidic adsorbents followed by conversion of this NH3 into nitrogen and water. Existing gasification technologies can effectively and efficiently convert a wide variety of carbonaceous feedstocks (coal, petcoke, resids, biomass, etc.) into syngas, which predominantly contains carbon monoxide and hydrogen. Unfortunately, the impurities present in these carbonaceous feedstocks are converted to gaseous contaminants such as H2S, COS, HCl, NH3, alkali macromolecules and heavy metal compounds (such as Hg) during the gasification process. Removal of these contaminants using conventional processes is thermally inefficient and capital intensive. This research and development effort is focused on investigation of modular processes for removal of sulfur, chlorine, nitrogen and mercury compounds from syngas at elevated temperature and pressures at significantly lower costs than conventional technologies.

  13. Toxic substances from coal combustion: Laboratory studies

    Energy Technology Data Exchange (ETDEWEB)

    Senior, C.L.; Bool, L.E. III [PSI Technologies, Andover, MA (United States); Huffman, G.P.; Huggins, F.E.; Shah, N. [Univ. of Kentucky, Lexington, KY (United States); Sarofim, A.F.; Olmez, I.; Zheng, T. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

    1996-12-31

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. PSI Technologies (PSIT) is teaming with researches from USGS, MIT, the University of Arizona, the University of Kentucky, the University of Connecticut, and Princeton University to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NO{sub x} combustion systems, and new power generation plants. Development of ToPEM will be based on PSIT`s existing Engineering Model for Ash Formation (EMAF). Extensive coal characterization and laboratory work will be conducted in order to develop and test new sub-models, including direct identification of the modes of occurrence of trace inorganic species in coal and ash using unique analytical techniques such as XAFS analysis and selective leaching and combustion testing too evaluate the formation and partitioning of inorganic toxic compounds as a function of mode of occurrence and combustion conditions at a range of combustion scales. Preliminary analysis of two American bituminous coals has focused on the forms of arsenic in both coal and ash. Trends in trace metal concentration in coal particles as a function of particle size have also been documented.

  14. Oxy-fuel Combustion and Integrated Pollutant Removal as Retrofit Technologies for Removing CO2 from Coal Fired Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Ochs, T.L.; Oryshchyn, D.B.; Summers, C.A.; Gerdemann, S.J.

    2001-01-01

    One third of the US installed capacity is coal-fired, producing 49.7% of net electric generation in 20051. Any approach to curbing CO2 production must consider the installed capacity and provide a mechanism for preserving this resource while meeting CO2 reduction goals. One promising approach to both new generation and retrofit is oxy-fuel combustion. Using oxygen instead of air as the oxidizer in a boiler provides a concentrated CO2 combustion product for processing into a sequestration-ready fluid.... Post-combustion carbon capture and oxy-fuel combustion paired with a compression capture technology such as IPR are both candidates for retrofitting pc combustion plants to meet carbon emission limits. This paper will focus on oxy-fuel combustion as applied to existing coal power plants.

  15. Techno-Economic Analysis of Scalable Coal-Based Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Chuang, Steven S. C. [Univ. of Akron, OH (United States)

    2014-08-31

    Researchers at The University of Akron (UA) have demonstrated the technical feasibility of a laboratory coal fuel cell that can economically convert high sulfur coal into electricity with near zero negative environmental impact. Scaling up this coal fuel cell technology to the megawatt scale for the nation’s electric power supply requires two key elements: (i) developing the manufacturing technology for the components of the coal-based fuel cell, and (ii) long term testing of a kW scale fuel cell pilot plant. This project was expected to develop a scalable coal fuel cell manufacturing process through testing, demonstrating the feasibility of building a large-scale coal fuel cell power plant. We have developed a reproducible tape casting technique for the mass production of the planner fuel cells. Low cost interconnect and cathode current collector material was identified and current collection was improved. In addition, this study has demonstrated that electrochemical oxidation of carbon can take place on the Ni anode surface and the CO and CO2 product produced can further react with carbon to initiate the secondary reactions. One important secondary reaction is the reaction of carbon with CO2 to produce CO. We found CO and carbon can be electrochemically oxidized simultaneously inside of the anode porous structure and on the surface of anode for producing electricity. Since CH4 produced from coal during high temperature injection of coal into the anode chamber can cause severe deactivation of Ni-anode, we have studied how CH4 can interact with CO2 to produce in the anode chamber. CO produced was found able to inhibit coking and allow the rate of anode deactivation to be decreased. An injection system was developed to inject the solid carbon and coal fuels without bringing air into the anode chamber. Five planner fuel cells connected in a series configuration and tested. Extensive studies on the planner fuels

  16. Eleventh annual international Pittsburgh coal conference proceedings: Volume 1

    International Nuclear Information System (INIS)

    The technical program featured over 300 papers in 39 separate sessions. These presentations are grouped into five topical areas: the technologies in pre- and post-utilization of coal, research and development in coal conversion, advanced coal combustion, environmental control technologies, and environmental policy issues related to coal use. The program has expanded its coverage in non-fuel use of coal. This is reflected in the three sessions on use of coal in the steel industry and a session on carbon products and non-fuel coal applications. Volume 1 contains two of these sessions as well as sessions on the following: coal resource characterization; coal by-products, properties, and utilization; indirect liquefaction of coal; combustion strategies to meet the Clean Air Act; cleanup technologies for advanced power systems; coal utilization--energy and environmental policy developments; fluidized bed combustion; petrochemicals from syngas; combustion models and bench scale combustion techniques; meeting emission requirements and improving combustion efficiencies; effect of coal chlorine content level on utility combustion performance; the effects of Clean Air Act amendments on by-product utilization; direct liquefaction; instrumentation and control of conventional coal boilers; hazardous air pollutants; legislative issues in the coal industry; pre-utilization/post-utilization processing; conversion technologies; and combustion systems. All papers have been processed separately for inclusion on the data base

  17. Final report spent nuclear fuel retrieval system primary cleaning development testing

    Energy Technology Data Exchange (ETDEWEB)

    Ketner, G.L.; Meeuwsen, P.V.

    1997-09-01

    Developmental testing of the primary cleaning station for spent nuclear fuel (SNF) and canisters is reported. A primary clean machine will be used to remove the gross sludge from canisters and fuel while maintaining water quality in the downstream process area. To facilitate SNF separation from canisters and minimize the impact to water quality, all canisters will be subjected to mechanical agitation and flushing with the Primary Clean Station. The Primary Clean Station consists of an outer containment box with an internally mounted, perforated wash basket. A single canister containing up to 14 fuel assemblies will be loaded into the wash basket, the confinement box lid closed, and the wash basket rotated for a fixed cycle time. During this cycle, basin water will be flushed through the wash basket and containment box to remove and entrain the sludge and carry it out of the box. Primary cleaning tests were performed to provide information concerning the removal of sludge from the fuel assemblies while in the basin canisters. The testing was also used to determine if additional fuel cleaning is required outside of the fuel canisters. Hydraulic performance and water demand requirements of the cleaning station were also evaluated. Thirty tests are reported in this document. Tests demonstrated that sludge can be dislodged and suspended sufficiently to remove it from the canister. Examination of fuel elements after cleaning suggested that more than 95% of the exposed fuel surfaces were cleaned so that no visual evidence of remained. As a result of testing, recommendations are made for the cleaning cycle. 3 refs., 16 figs., 4 tabs.

  18. Environmental control implications of generating electric power from coal. 1977 technology status report. Appendix A (Part 2). Coal preparation and cleaning assessment study appendix

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-12-01

    This report presents the results of integrating coal washability and coal reserves data obtained from the U.S. Bureau of Mines. Two computer programs were developed to match the appropriate entries in each data set and then merge the data into the form presented in this report. Approximately 18% of the total demonstrated coal reserves were matched with washability data. However, about 35% of the reserves that account for 80% of current production were successfully matched. Each computer printout specifies the location and size of the reserve, and then describes the coal with data on selected physical and chemical characteristics. Washability data are presented for three crush sizes (1.5 in., /sup 3///sub 8/ in., and 14 mesh) and several specific gravities. In each case, the percent recovery, Btu/lb, percent ash, percent sulfur, lb SO/sub 2//10/sup 6/ Btu, and reserves available at 1.2 lb SO/sub 2//10/sup 6/ Btu are given. The sources of the original data and the methods used in the integration are discussed briefly.

  19. Cleaning and Dewatering Fine Coal using Hydrophobic Displacement

    OpenAIRE

    Smith, Kara E.

    2008-01-01

    A new processing technique, known as hydrophobic displacement, was explored as a means of simultaneously removing both mineral matter and surface moisture from coal in a single process. Previous thermodynamic analysis suggests that coal moisture will be spontaneously displaced by any oil with a contact angle greater than ninety degrees in water. Based on these results, six methods of hydrophobic displacement were evaluated: hand shaking, screening, air classification, centrifugation, filtra...

  20. Developing clean fuels: Novel techniques for desulfurization

    Science.gov (United States)

    Nehlsen, James P.

    The removal of sulfur compounds from petroleum is crucial to producing clean burning fuels. Sulfur compounds poison emission control catalysts and are the source of acid rain. New federal regulations require the removal of sulfur in both gasoline and diesel to very low levels, forcing existing technologies to be pushed into inefficient operating regimes. New technology is required to efficiently produce low sulfur fuels. Two processes for the removal of sulfur compounds from petroleum have been developed: the removal of alkanethiols by heterogeneous reaction with metal oxides; and oxidative desulfurization of sulfides and thiophene by reaction with sulfuric acid. Alkanethiols, common in hydrotreated gasoline, can be selectively removed and recovered from a hydrocarbon stream by heterogeneous reaction with oxides of Pb, Hg(II), and Ba. The choice of reactive metal oxides may be predicted from simple thermodynamic considerations. The reaction is found to be autocatalytic, first order in water, and zero order in thiol in the presence of excess oxide. The thiols are recovered by reactive extraction with dilute oxidizing acid. The potential for using polymer membrane hydrogenation reactors (PEMHRs) to perform hydrogenation reactions such as hydrodesulfurization is explored by hydrogenating ketones and olefins over Pt and Au group metals. The dependence of reaction rate on current density suggests that the first hydrogen addition to the olefin is the rate limiting step, rather than the adsorption of hydrogen, for all of the metals tested. PEMHRs proved unsuccessful in hydrogenating sulfur compounds to perform HDS. For the removal of sulfides, a two-phase reactor is used in which concentrated sulfuric acid oxidizes aromatic and aliphatic sulfides present in a hydrocarbon solvent, generating sulfoxides and other sulfonated species. The polar oxidized species are extracted into the acid phase, effectively desulfurizing the hydrocarbon. A reaction scheme is proposed for this

  1. A review of trace element emissions from the combustion of refuse-derived fuel with coal

    International Nuclear Information System (INIS)

    The effects of cocombusting refuse-derived fuel (RDF) with coal on stack emissions of trace elements in the ash stream were reviewed. The large number of variables and uncertainties involved precluded drawing definitive conclusions regarding many of the trace elements. However, it is evident that cocombustion resulted in increased emissions of Cd, Cu, Hg, Pb, and Zn. Emissions of As and Ni tended to decrease when RDF was fired with coal. Modeling studies indicated that ambient levels of trace elements during cocombustion should be within acceptable limits. However, periodic monitoring of Cd, Hg, and Pb may be warranted in some instances

  2. METC Clean Coal Technology status -- 1995 update

    Energy Technology Data Exchange (ETDEWEB)

    Carpenter, L.K.

    1995-06-01

    The Department of Energy (DOE) Clean Coal Technology (CCT) Program is assisting the private sector by funding demonstration programs to validate that CCT technologies are a low-risk, environmentally attractive, cost-competitive option for utility and industrial users. Since 1987, DOE has awarded 45 CCT projects worth a total value of $7 billion (including more than $2.3 billion of DOE funding). Within the CCT Program, the Morgantown Energy Technology Center (METC) is responsible for 17 advanced power generation systems and major industrial applications. METC is an active partner in advancement of these technologies via direct CCT funding and via close cooperation and coordination of internal and external research and development activities. By their nature, METC projects are typically 6-10 years in duration and, in some cases, very complex in nature. However, as a result of strong commercial partnerships, progress in the development and commercialization of major utility and industrial projects has, and will continue to occur. It is believed that advanced power generation systems and industrial applications are on the brink of commercial deployment. A status of METC CCT activities will be presented. Two projects have completed their operational phase, operations are underway at one project (two others are in the latter stages of construction/shakedown), four projects are in construction, six restructured. Also, present a snapshot of development activities that are an integral part of the advancement of these CCT initiatives will be presented.

  3. Fe and Mn removal from mining drainage using goaf filling materials obtained from coal mining process.

    Science.gov (United States)

    Zhang, Liping; Chen, Aolei; Qu, Hongbin; Xu, Shouqiang; Zhang, Xue; He, Xuwen

    2015-01-01

    Coal gangue, sandy soil and clay (mass ratio 45:4:1) as goaf filling materials acquired from coal mining processes were applied to remove Fe and Mn effectively from mining drainage. The results of an adsorption kinetic study showed that the Fe adsorption equation was y=21.454y+8.4712, R2=0.9924 and the Mn adsorption equation was y=7.5409x+0.905, R2=0.9957. Meanwhile, the goaf filling materials had low desorption capacity (Fe 6.765 μg/g, Mn 1.52 μg/g) and desorption ratio (Fe 8.98%, Mn 11.04%). Experiments demonstrated that Fe and Mn from mining drainage could be removed stably at a flow rate of 1.2 L/min, Fe inlet concentration of less than 40 mg/L, Mn inlet concentration of less than 2 mg/L and neutral or alkaline conditions. During a procedure of continuous experiments, the effluent quality could meet the requirement of the 'Code for Engineering Design of Sewage Regeneration-GB503352-2002'. A real-application project using goaf filling materials to treat mining drainage in Shendong coal mine showed that the average cost per ton of mining drainage was about 0.55 RMB, which could bring about considerable economic benefit for coal mining enterprises. PMID:26606087

  4. Integration of in-situ CO2-oxy coal gasification with advanced power generating systems performing in a chemical looping approach of clean combustion

    International Nuclear Information System (INIS)

    Highlights: • Integration of CO2/O2 based UCG, CLC and CCS for clean coal utilization. • Incorporation of CLC system reduces the ASU load of the power plant. • Use of CO enriched UCG gas in Ni based CLC reduces the difficulty of heat balance. • Coupling of the proposed UCG with IGCC and IGST for the efficient power generation. • Demonstration of reduced CCS energy penalty in the advanced coupled system. - Abstract: Underground coal gasification (UCG) is a clean coal technology to utilize deep coal resources effectively. In-situ CO2-oxy coal gasification may eliminate the operational difficulty of the steam gasification process and utilize CO2 (greenhouse gas) effectively. Furthermore, it is necessary to convert the clean gasified energy from the UCG into clean combustion energy for an end-use. In order to achieve efficient clean power production, the present work investigates the thermodynamic feasibility of integration of CO2 based UCG with power generating systems operating in a chemical looping combustion (CLC) of product gas. The use of CO enriched syngas from O2/CO2 based UCG reduces the difficulty of the heat balance between a fuel reactor and an air reactor in a nickel oxygen-carrier based CLC system. Thermodynamic analyses have been made for various routes of power generation systems such as subcritical, supercritical and ultra-supercritical boiler based steam turbines and gas turbines for the UCG integrated system. It is shown, based on mass and energy balance analysis, that the integration of CO2 based UCG with the CLC system reduces the energy penalty of carbon capture and storage (CCS) significantly. A net thermal efficiency of 29.42% is estimated for the CCS incorporated system, which operates in a subcritical condition based steam turbine power plant. Furthermore, it is found that the efficiency of the proposed steam turbine system increases to 35.40% for an ultra-supercritical operating condition. The effect of operating temperature of the

  5. Ultra-clean Fischer-Tropsch (F-T) Fuels Production and Demonstration Project

    Energy Technology Data Exchange (ETDEWEB)

    Stephen P. Bergin

    2006-06-30

    The objective of the DOE-NETL Fischer-Tropsch (F-T) Production and Demonstration Program was to produce and evaluate F-T fuel derived from domestic natural gas. The project had two primary phases: (1) fuel production of ultra-clean diesel transportation fuels from domestic fossil resources; and (2) demonstration and performance testing of these fuels in engines. The project also included a well-to-wheels economic analysis and a feasibility study of small-footprint F-T plants (SFPs) for remote locations such as rural Alaska. During the fuel production phase, ICRC partnered and cost-shared with Syntroleum Corporation to complete the mechanical design, construction, and operation of a modular SFP that converts natural gas, via F-T and hydro-processing reactions, into hydrogensaturated diesel fuel. Construction of the Tulsa, Oklahoma plant started in August 2002 and culminated in the production of over 100,000 gallons of F-T diesel fuel (S-2) through 2004, specifically for this project. That fuel formed the basis of extensive demonstrations and evaluations that followed. The ultra-clean F-T fuels produced had virtually no sulfur (less than 1 ppm) and were of the highest quality in terms of ignition quality, saturation content, backend volatility, etc. Lubricity concerns were investigated to verify that commercially available lubricity additive treatment would be adequate to protect fuel injection system components. In the fuel demonstration and testing phase, two separate bus fleets were utilized. The Washington DC Metropolitan Area Transit Authority (WMATA) and Denali National Park bus fleets were used because they represented nearly opposite ends of several spectra, including: climate, topography, engine load factor, mean distance between stops, and composition of normally used conventional diesel fuel. Fuel evaluations in addition to bus fleet demonstrations included: bus fleet emission measurements; F-T fuel cold weather performance; controlled engine dynamometer

  6. Clean coal technology promotion and dissemination

    Energy Technology Data Exchange (ETDEWEB)

    Minchener, A.J.; McMullan, J.T.; Kubica, K. (and others) [IEA Coal Research Ltd, London (United Kingdom)

    2008-07-01

    This project has provided a means to valorise the technical achievements of the CCT power generation RD&D activities arising from the ECSC and RFCS coal utilisation programmes. The focus has been on promotion and dissemination of such results to major coal-using Member States that have recently joined the European Union, namely Poland, the Czech Republic and Romania. A comprehensive review of the scope and achievements of the ECSC and RFCS projects on coal-fired power generation RD&D has been prepared and posted on the IEACCC website. This document has been translated by the partners in the three designated States and disseminated to their respective national stakeholders. Workshops have been held successfully in each country to promote the findings of the review and to determine their respective primary interests in future RD&D. The attendees have included representatives of major power plant operators, equipment manufacturers and developers, research institutes and universities. Very positive feedback was received from those stakeholders. The project has been completed with the circulation of the report and associated information to comparable stakeholders in the EU-15 countries and other newer members of the European Union via various networks and associations. 2 tabs., 3 apps.

  7. PFBC - Clean coal technology status and experience

    International Nuclear Information System (INIS)

    There are currently 4 PFBC (Pressurized Fluidized Bed Combustion) plants in operation (Sweden, Spain, US, Japan), utilizing five of ABB's P200 PFBC modules, with a total of 53,000 hours on coal. Results show that the PFBC process and its main specific components do function as intended over the full load range. Environmental performance has been as expected or better (sulfur and NOx emissions). Some technical problems have been found and corrected, such as a high cycle fatigue of blades for the variable speed low pressure turbine; the shape and the material of the blades have been modified, and resonance frequencies avoided. Other PFBC projects (Japan) are presented. 3 tabs

  8. Coal conversion. 1978 technical report. [US DOE

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-09-01

    The United States has more energy available in coal than in petroleum, natural gas, oil shale, and tar sands combined. Nationwide energy shortages, together with the availability of abundant coal reserves, make commercial production of synthetic fuels from coal vital to the Nation's total supply of clean energy. In response to this need, the Division of Fossil Fuel Processing - US Department of Energy is conducting a research, development and demonstration program to provide technology that will permit rapid commercialization of processes for converting coal into products that substitute for those derived from oil and natural gas. These substitute fuels include crude oil, fuel oil and distillates; chemical feedstocks; pipeline quality and fuel gas; and other products such as char that may be useful in energy production.

  9. Processing and properties of a solid energy fuel from municipal solid waste (MSW) and recycled plastics.

    Science.gov (United States)

    Gug, JeongIn; Cacciola, David; Sobkowicz, Margaret J

    2015-01-01

    Diversion of waste streams such as plastics, woods, papers and other solid trash from municipal landfills and extraction of useful materials from landfills is an area of increasing interest especially in densely populated areas. One promising technology for recycling municipal solid waste (MSW) is to burn the high-energy-content components in standard coal power plant. This research aims to reform wastes into briquettes that are compatible with typical coal combustion processes. In order to comply with the standards of coal-fired power plants, the feedstock must be mechanically robust, free of hazardous contaminants, and moisture resistant, while retaining high fuel value. This study aims to investigate the effects of processing conditions and added recyclable plastics on the properties of MSW solid fuels. A well-sorted waste stream high in paper and fiber content was combined with controlled levels of recyclable plastics PE, PP, PET and PS and formed into briquettes using a compression molding technique. The effect of added plastics and moisture content on binding attraction and energy efficiency were investigated. The stability of the briquettes to moisture exposure, the fuel composition by proximate analysis, briquette mechanical strength, and burning efficiency were evaluated. It was found that high processing temperature ensures better properties of the product addition of milled mixed plastic waste leads to better encapsulation as well as to greater calorific value. Also some moisture removal (but not complete) improves the compacting process and results in higher heating value. Analysis of the post-processing water uptake and compressive strength showed a correlation between density and stability to both mechanical stress and humid environment. Proximate analysis indicated heating values comparable to coal. The results showed that mechanical and moisture uptake stability were improved when the moisture and air contents were optimized. Moreover, the briquette

  10. Integrating coal cleaning with pulverized coal and fluidized bed boilers to meet the Clean Air Act Amendment and for new plant construction

    International Nuclear Information System (INIS)

    Integrating coal cleaning into a two boiler, pulverized coal-fired/fluidized bed (PC/FBC) power plant can reduce emissions at low cost for both retrofit projects and new power plants. The technology, because it relies on proven equipment and practices, albeit in a novel context, is low risk and near term. Its low cost makes it particularly suitable to retrofit many of the older coal- fired power plants in the US, and also for retrofitting power plants in the less affluent Eastern European and Asian countries that rely on coal for power generation and need to reduce emission but cannot afford scrubbers. In retrofit applications the technology involves a simple coal cleaning plant and the addition of a small fluidized bed boiler with its steam circuitry integrated into the plant's steam cycle. The clean coal stream will be fired in the existing boiler while the fluidized bed will use the low grade (waste) stream from the coal cleaning plant. This paper reports that this approach is particularly applicable to the many power plants along the Ohio River

  11. Automated cleaning and pre-processing of immunoglobulin gene sequences from high-throughput sequencing

    Directory of Open Access Journals (Sweden)

    Miri eMichaeli

    2012-12-01

    Full Text Available High throughput sequencing (HTS yields tens of thousands to millions of sequences that require a large amount of pre-processing work to clean various artifacts. Such cleaning cannot be performed manually. Existing programs are not suitable for immunoglobulin (Ig genes, which are variable and often highly mutated. This paper describes Ig-HTS-Cleaner (Ig High Throughput Sequencing Cleaner, a program containing a simple cleaning procedure that successfully deals with pre-processing of Ig sequences derived from HTS, and Ig-Indel-Identifier (Ig Insertion – Deletion Identifier, a program for identifying legitimate and artifact insertions and/or deletions (indels. Our programs were designed for analyzing Ig gene sequences obtained by 454 sequencing, but they are applicable to all types of sequences and sequencing platforms. Ig-HTS-Cleaner and Ig-Indel-Identifier have been implemented in Java and saved as executable JAR files, supported on Linux and MS Windows. No special requirements are needed in order to run the programs, except for correctly constructing the input files as explained in the text. The programs' performance has been tested and validated on real and simulated data sets.

  12. The return on investment of the clean coal technology program in the USA

    International Nuclear Information System (INIS)

    We analyze the return on investment of the U.S. federal government’s clean coal technology (CCT) program for the period 2000–2020. We estimate total costs to government and industry and quantify benefits for: (1) Reduced capital costs of advanced technologies in new plants; (2) Reduced capital and operating costs at existing plants to remain compliant with environmental regulations; (3) Reduced fuel costs due to higher efficiencies; (4) Avoided environmental costs; (5) The value of clean coal technology export sales; (6) Jobs created. We find that benefits over the 20-year period total $111 billion (2008 dollars); the benefits in individual categories range from $15 billion in fuel cost savings to $39 billion for capital and technology cost savings in new and existing plants; and that total jobs created exceed 1.2 million, with an annual average of about 60,000 jobs created. We also find that the return on investment to DOE from the CCT program is favorable and is growing rapidly: By 2020, the cumulative DOE costs will likely total $8.5 billion, for an ROI of more than 13. - Highlights: ► Its benefits far exceed costs, and benefits are increasing rapidly. ► The ROIs to federal govt. and private industry are very high. ► It will create 100,000 jobs annually. ► Independent reviews find it to be exemplary and well-managed

  13. Emissions from slow pyrolysis of solid fuels studied by GC/MS in a miniature reactor

    Energy Technology Data Exchange (ETDEWEB)

    Pedersen, J.R.; Stroemberg, K.; Olsson, J.O. [Chalmers University of Technology, Gothenburg (Sweden). Dept. of Physical Chemistry

    1996-12-31

    In an effort to increase knowledge of slow pyrolysis processes of coal and biomass a miniature pyrolysis reactor suited for GC/MS analysis was designed. Three solid fuels were investigated: bituminous coal, sawdust from spruce and chips from eucalyptus. Coal pyrolysis produced comparatively high amounts of alkanes, naphthalene and polycyclic aromatic hydrocarbon not found in the wood samples. Coal also produced alkyl substituted phenols. Sawdust from spruce produced almost the same products as eucalyptus. However, the product distributions from spruce and eucalyptus were more substituted than these from spruce. The products from wood samples were dominated by oxygenates: fatty acids, cyclic oxygenates and methoxy substituted phenols. This approach can be used for selecting solid fuels suitable for clean combustion and production of bio-oils. 9 refs., 4 figs.

  14. Coal surface control for advanced physical fine coal cleaning technologies. Final report, September 19, 1988--August 31, 1992

    Energy Technology Data Exchange (ETDEWEB)

    Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

    1992-12-31

    This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO{sub 2} emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R&D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

  15. Coal and nuclear electricity fuels

    International Nuclear Information System (INIS)

    Comparative economic analysis is used to contrast the economic advantages of nuclear and coal-fired electric generating stations for Canadian regions. A simplified cash flow method is used with present value techniques to yield a single levelized total unit energy cost over the lifetime of a generating station. Sensitivity analysis illustrates the effects of significant changes in some of the cost data. The analysis indicates that in Quebec, Ontario, Manitoba and British Columbia nuclear energy is less costly than coal for electric power generation. In the base case scenario the nuclear advantage is 24 percent in Quebec, 29 percent in Ontario, 34 percent in Manitoba, and 16 percent in British Columbia. Total unit energy cost is sensitive to variations in both capital and fuel costs for both nuclear and coal-fuelled power stations, but are not very sensitive to operating and maintenance costs

  16. Lab-scale investigation of Middle-Bosnia coals to achieve high-efficient and clean combustion technology

    Directory of Open Access Journals (Sweden)

    Smajevic Izet

    2014-01-01

    Full Text Available This paper describes full lab-scale investigation of Middle-Bosnia coals launched to support selection an appropriate combustion technology and to support optimization of the boiler design. Tested mix of Middle-Bosnia brown coals is projected coal for new co-generation power plant Kakanj Unit 8 (300-450 MWe, EP B&H electricity utility. The basic coal blend consisting of the coals Kakanj: Breza: Zenica at approximate mass ratio of 70:20:10 is low grade brown coal with very high percentage of ash - over 40%. Testing that coal in circulated fluidized bed combustion technique, performed at Ruhr-University Bohum and Doosan Lentjes GmbH, has shown its inconveniency for fluidized bed combustion technology, primarily due to the agglomeration problems. Tests of these coals in PFC (pulverized fuel combustion technology have been performed in referent laboratory at Faculty of Mechanical Engineering of Sarajevo University, on a lab-scale PFC furnace, to provide reliable data for further analysis. The PFC tests results are fitted well with previously obtained results of the burning similar Bosnian coal blends in the PFC dry bottom furnace technique. Combination of the coals shares, the process temperature and the air combustion distribution for the lowest NOx and SO2 emissions was found in this work, provided that combustion efficiency and CO emissions are within very strict criteria, considering specific settlement of lab-scale furnace. Sustainability assessment based on calculation economic and environmental indicators, in combination with Low Cost Planning method, is used for optimization the power plant design. The results of the full lab-scale investigation will help in selection optimal Boiler design, to achieve sustainable energy system with high-efficient and clean combustion technology applied for given coals.

  17. TOXIC SUBSTANCES FROM COAL COMBUSTION

    Energy Technology Data Exchange (ETDEWEB)

    Kolker, A.; Sarofim, A.F.; Palmer, C.A.; Huggins, F.E.; Huffman, G.P.; Lighty, J.; Veranth, J.; Helble, J.J.; Wendt, J.O.L.; Ames, M.R.; Finkelman, R.; Mamani-Paco, M.; Sterling, R.; Mroczkowsky, S.J.; Panagiotou, T.; Seames, W.

    1999-05-10

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environ-mental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NOx combustion systems, and new power generation plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 January 1999 to 31 March 1999. During this period, a full Program Review Meeting was held at the University of Arizona. At this meeting, the progress of each group was reviewed, plans for the following 9 month period were discussed, and action items (principally associated with the transfer of samples and reports among the various investigators) were identified.

  18. Coal liquefaction. Quarterly report, April--June 1977

    Energy Technology Data Exchange (ETDEWEB)

    None

    1978-01-01

    The United States has more energy available in coal than in petroleum, natural gas, oil shale, and tar sands combined. Nationwide energy shortages, together with the availability of abundant coal reserves, make commercial production of synthetic fuels from coal vital to the Nation's total supply of clean energy. In response to this need, the Office of Fossil Energy of the Energy Research and Development Administration (ERDA) is conducting a research and development program to provide technology that will permit rapid commercialization of processes for converting coal to synthetic liquid and gaseous fuels and for improved direct combustion of coal. These fuels must be storable and suitable for power generation, transportation, and residential and industrial uses. ERDA's program for the conversion of coal to liquid fuels was begun by two of ERDA's predecessor agencies: Office of Coal Research (OCR) in 1962, and Bureau of Mines, U.S. Department of the Interior, in the 1930's. Current work in coal liquefaction is aimed at improved process configurations for both catalytic and non-catalytic processes to provide more attractive processing economics and lower capital investment. Coal liquefaction can now be achieved under more moderate processing conditions and more rapidly than was the case in the 1930's. The advantage of coal liquefaction is that the entire range of liquid products, including heavy boiler fuel, distillate fuel oil, gasoline, jet fuel, and diesel oil, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquid fuels also have the potential for use as chemical feedstocks. To determine the most efficient means of utilizing coal resources, ERDA is sponsoring the development of several conversion processes that are currently in the pilot plant stage. Nineteen projects under development are described and progress for each in the quarter is detailed briefly

  19. Cooperative research program in coal liquefaction. Quarterly report, May 1, 1993--October 31, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Hoffman, G.P. [ed.

    1994-07-01

    This report summarizes progress in four areas of research under the general heading of Coal Liquefaction. Results of studies concerning the coliquefaction of coal with waste organic polymers or chemical products of these polymers were reported. Secondly, studies of catalytic systems for the production of clean transportation fuels from coal were discussed. Thirdly, investigations of the chemical composition of coals and their dehydrogenated counterparts were presented. These studies were directed toward elucidation of coal liquefaction processes on the chemical level. Finally, analytical methodologies developed for in situ monitoring of coal liquefaction were reported. Techniques utilizing model reactions and methods based on XAFS, ESR, and GC/MS are discussed.

  20. Preliminary investigation of the effects of coal-water slurry fuels on the combustion in GE coal fueled diesel engine (Task 1. 1. 2. 2. 1, Fuels)

    Energy Technology Data Exchange (ETDEWEB)

    1990-06-01

    In prior work with the coal fired diesel research engine, a necessity to determine the sensitivity of the engine to a wider range of fuels was resolved and included in the R and D Test Plan submitted on 2/9/89. In general, the economic viability and universal acceptance of the commercial engine will be a factor of its ability to tolerate the widest range of source fuels with minimal fuel beneficiation. As detailed in the R and D Test Plan, a preliminary investigation on the effects of coal-water slurry (CWS) fuels on the combustion in a GE single cylinder test engine was conducted. The following conclusions are obtained from this investigation. All the test CWS fuels were successfully burned in the GE engine combustion system. They include: 3 to 15 microns mean particle size; 0.7 to 2.8% ash level; KY Blue Gem and PA Mariana bituminous coal, WY Kemmer and Spring Creek Sub-Bituminous coal; coal beneficiated with physical and chemical processes; two kinds of additives for OTISCA CWS; and burnout is not effected by ash or particle size within the test range. For each kind of CWS fuel, the detail design parameters of the fuel injection system has to be compatible. With sufficiently high fuel injection pressure, the 3 micron mean particle size OTISCA fuel burns faster than the 5 micron ones. For OTISCA fuel, the burn rate using Ammonium Lignosulfonate as additive is faster than using Ammonium Condensed Naphthalene Sulfonate. Appendices contain data on heat release, fuel characterization reports from two laboratories, general engine test data, and particulate size distribution. 3 refs.

  1. Advanced Coal-Fueled Gas Turbine Program

    Energy Technology Data Exchange (ETDEWEB)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  2. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2003-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. These feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. Some highlights of the results obtained during the first year of the current research contract are summarized as: (1) Terminal alkynes are an effective chain initiator for Fischer-Tropsch (FT) reactions, producing normal paraffins with C numbers {ge} to that of the added alkyne. (2) Significant improvement in the product distribution towards heavier hydrocarbons (C{sub 5} to C{sub 19}) was achieved in supercritical fluid (SCF) FT reactions compared to that of gas-phase reactions. (3) Xerogel and aerogel silica supported cobalt catalysts were successfully employed for FT synthesis. Selectivity for diesel range products increased with increasing Co content. (4) Silicoaluminophosphate (SAPO) molecular sieve catalysts have been developed for methanol to olefin conversion, producing value-added products such as ethylene and propylene. (5) Hybrid Pt-promoted tungstated and sulfated zirconia catalysts are very effective in cracking n-C{sub 36} to jet and diesel fuel; these catalysts will be tested for cracking of FT wax. (6) Methane, ethane, and propane are readily decomposed to pure

  3. Method and device for cleaning spent fuel assembly

    International Nuclear Information System (INIS)

    A spent fuel assembly is immersed in a liquid metal in a pot disposed below a cleaning vessel which is under the floor of an argon gas cell, and the liquid metal in the pot is heated by a heater disposed at the periphery of the cleaning vessel, and the spent fuel assembly is preheated by the heated liquid metal. Then, in a state where the spent fuel is pulled up from the pot in the cleaning vessel, heating gases are blown to the fuel assembly from above, high temperature argon gases are blown to wash out the liquid metals deposited on the spent fuel assembly. In this way, the spent fuel assembly can be heated to a predetermined preheating temperature in a short period of time. Since the amount of the liquid metal to be recovered by a vapor trap is reduced, the capacity of a storage tank exclusively used for vapor trap can be reduced. (T.M.)

  4. Crud Cleaning for Reloaded PLUS7 Nuclear Fuels

    International Nuclear Information System (INIS)

    Crud which is made in reactor system as a corrosion product stains high burnup nuclear fuel cladding while flowing with a fluid in nuclear system. AOA(Axial Offset Anomaly) which is define as a significant negative axial offset deviation from the predicted nuclear design value was resulted from deposition of Crud. For solving AOA, there are several methods to solve it like improving nuclear fuel design, reactor-operating and water hydrochemistry. However, the most effective method is cleaning Crud directly on nuclear fuel cladding by ultrasonic waves which are effective and safety means. Hereupon, KNF developed Crud cleaning technique some years ago, and apply it in domestic reloaded nuclear fuel. For this time, Crud cleaning was performed about PLUS7 fuel designed in-country. Reloaded 108 PLUS7 fuels were cleaned and the result of visual inspection showed first burned fuel was 20% cleaned a Crud, and second burned fuel was 80%. The outcome was as same as other plants in abroad since the quantity of collecting Crud was 269g. By accomplishing the project, KNF was able to gather data about different type of fuel and nuclear plant can produce electricity stably

  5. Innovative clean coal technology (ICCT): demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emission from high-sulfur, coal-fired boilers - economic evaluation of commercial-scale SCR applications for utility boilers

    Energy Technology Data Exchange (ETDEWEB)

    Healy, E.C.; Maxwell, J.D.; Hinton, W.S.

    1996-09-01

    This report presents the results of an economic evaluation produced as part of the Innovative Clean Coal Technology project, which demonstrated selective catalytic reduction (SCR) technology for reduction of NO{sub x} emissions from utility boilers burning U.S. high-sulfur coal. The document includes a commercial-scale capital and O&M cost evaluation of SCR technology applied to a new facility, coal-fired boiler utilizing high-sulfur U.S. coal. The base case presented herein determines the total capital requirement, fixed and variable operating costs, and levelized costs for a new 250-MW pulverized coal utility boiler operating with a 60-percent NO{sub x} removal. Sensitivity evaluations are included to demonstrate the variation in cost due to changes in process variables and assumptions. This report also presents the results of a study completed by SCS to determine the cost and technical feasibility of retrofitting SCR technology to selected coal-fired generating units within the Southern electric system.

  6. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Kalyan Annamalai; Dr. John Sweeten; Dr. Sayeed Mukhtar

    2000-10-24

    The following are proposed activities for quarter 1 (6/15/00-9/14/00): (1) Finalize the allocation of funds within TAMU to co-principal investigators and the final task lists; (2) Acquire 3 D computer code for coal combustion and modify for cofiring Coal:Feedlot biomass and Coal:Litter biomass fuels; (3) Develop a simple one dimensional model for fixed bed gasifier cofired with coal:biomass fuels; and (4) Prepare the boiler burner for reburn tests with feedlot biomass fuels. The following were achieved During Quarter 5 (6/15/00-9/14/00): (1) Funds are being allocated to co-principal investigators; task list from Prof. Mukhtar has been received (Appendix A); (2) Order has been placed to acquire Pulverized Coal gasification and Combustion 3 D (PCGC-3) computer code for coal combustion and modify for cofiring Coal: Feedlot biomass and Coal: Litter biomass fuels. Reason for selecting this code is the availability of source code for modification to include biomass fuels; (3) A simplified one-dimensional model has been developed; however convergence had not yet been achieved; and (4) The length of the boiler burner has been increased to increase the residence time. A premixed propane burner has been installed to simulate coal combustion gases. First coal, as a reburn fuel will be used to generate base line data followed by methane, feedlot and litter biomass fuels.

  7. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS

    International Nuclear Information System (INIS)

    The following are proposed activities for quarter 1 (6/15/00-9/14/00): (1) Finalize the allocation of funds within TAMU to co-principal investigators and the final task lists; (2) Acquire 3 D computer code for coal combustion and modify for cofiring Coal:Feedlot biomass and Coal:Litter biomass fuels; (3) Develop a simple one dimensional model for fixed bed gasifier cofired with coal:biomass fuels; and (4) Prepare the boiler burner for reburn tests with feedlot biomass fuels. The following were achieved During Quarter 5 (6/15/00-9/14/00): (1) Funds are being allocated to co-principal investigators; task list from Prof. Mukhtar has been received (Appendix A); (2) Order has been placed to acquire Pulverized Coal gasification and Combustion 3 D (PCGC-3) computer code for coal combustion and modify for cofiring Coal: Feedlot biomass and Coal: Litter biomass fuels. Reason for selecting this code is the availability of source code for modification to include biomass fuels; (3) A simplified one-dimensional model has been developed; however convergence had not yet been achieved; and (4) The length of the boiler burner has been increased to increase the residence time. A premixed propane burner has been installed to simulate coal combustion gases. First coal, as a reburn fuel will be used to generate base line data followed by methane, feedlot and litter biomass fuels

  8. Amenability to dry processing of high ash thermal coal using a pneumatic table

    Institute of Scientific and Technical Information of China (English)

    Dey Shobhana; Gangadhar B.; Gopalkrishna S.J.

    2015-01-01

    High ash thermal coal from India was used to conduct the dry processing of fine coal using a pneumatic table to evolve a techno-economically novel technique. The fine as-received sample having 55.2%ash was subjected to washability studies at variant densities from 1.4 to 2.2 to assess the amenability to separa-tion. The experiments were conducted using a central composite design for assessing the interactive effects of the variable parameters of a pneumatic table on the product yield and ash content. The perfor-mance of the pneumatic table was analyzed in terms of clean coal yield, recovery of combustibles, separation efficiency (Esp) and useful heat value of clean coal. The combustibles of clean coal obtained through a single stage operation at 35% and 38.7% ash were 40% and 63% respectively. However, the two stage processing was more effective in reducing the ash content in the clean coal. The rougher con-centrate generated at higher ash level was subsequently processed in different conditions at 35% ash level, and 58%combustibles could be recovered. Hence, two stage processing increases the combustibles by 18 units and the useful heat value of clean coal increases from 1190 kcal/kg to 3750 kcal/kg.

  9. Development of OTM Syngas Process and Testing of Syngas Derived Ulta-clean Fuels in Diesel Engines and Fuel Cells Budget Period 3

    Energy Technology Data Exchange (ETDEWEB)

    E.T. Robinson; John Sirman; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Dan Corgard; Siv Aasland; Kjersti Kleveland; Ann Hooper; Leo Bonnell; John Hemmings; Jack Chen; Bart A. Van Hassel

    2004-12-31

    This topical report summarizes work accomplished for the Program from January 1, 2003 through December 31,2004 in the following task areas: Task 1--Materials Development; Task 2--Composite Development; Task 4--Reactor Design and Process Optimization; Task 8--Fuels and Engine Testing; 8.1 International Diesel Engine Program; and Task IO: Program Management. Most of the key technical objectives for this budget period were achieved. Only partial success was achieved relative to cycle testing under pressure Major improvements in material performance and element reliability have been achieved. A breakthrough material system has driven the development of a compact planar reactor design capable of producing either hydrogen or syngas. The planar reactor shows significant advantages in thermal efficiency and costs compared to either steam methane reforming with CO{sub 2} recovery or autothermal reforming. The fuel and engine testing program is complete The single cylinder test engine evaluation of UCTF fuels begun in Budget Period 2 was finished this budget period. In addition, a study to evaluate new fuel formulations for an HCCl engine was completed.

  10. Innovative Clean Coal Technology (ICCT). Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers: Volume 1. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-01

    The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO.) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO. to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal- fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: 1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels. 2) performance of the technology and effects on the balance-of- plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. 3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacturer under typical high-sulfur coal-fired utility operating conditions. These uncertainties were explored by operating nine small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. In addition, the test facility operating experience provided a basis for an economic study investigating the implementation of SCR technology.

  11. Clean-up and disposal process of polluted sediments from urban rivers

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    In this paper, the discussion is concentrated on the properties of the polluted sediments and the combination of clean-up and disposal process for the upper layer heavily polluted sediments with good flowability. Based on the systematic analyses of various clean-up processes, a suitable engineering process has been evaluated and recommended. The process has been applied to the river reclamation in Yangpu District of Shanghai metropolis. An improved centrifuge is used for dewatering the dredged sludge,which plays an important role in the combination of clean-up and disposal process. The assessment of the engineering process shows its environmental and technical economy feasibility, which is much better than that of traditional dredging-disposal processes.

  12. Coal gasification and its applications

    Energy Technology Data Exchange (ETDEWEB)

    Bell, D.; Towler, B.

    2010-07-01

    This book approaches coal gasification and related technologies from a process engineering point of view, with topics chosen to aid the process engineer who is interested in a complete, coal-to-products system. It provides a perspective for engineers and scientists who analyze and improve components of coal conversion processes. The first topic describes the nature and availability of coal. Next, the fundamentals of gasification are described, followed by a description of gasification technologies and gas cleaning processes. The conversion of syngas to electricity, fuels and chemicals is then discussed. Finally, process economics are covered. Emphasis is given to the selection of gasification technology based on the type of coal fed to the gasifier and desired end product: E.g., lower temperature gasifiers produce substantial quantities of methane, which is undesirable in an ammonia synthesis feed. This book also reviews gasification kinetics which is informed by recent papers and process design studies by the US Department of Energy and other groups. Approaches coal gasification and related technologies from a process engineering point of view, providing a perspective for engineers and scientists who analyze and improve components of coal conversion processes - Describes the fundamentals of gasification, gasification technologies, and gas cleaning processes - Emphasizes the importance of the coal types fed to the gasifier and desired end products - Covers gasification kinetics.

  13. Burning clean fuel gas improves energetic efficiency

    International Nuclear Information System (INIS)

    One the most critical problems faced by refineries nowadays is the continuous increasing of legislation urging emissions reductions specifically SO2, NOx, and particles. Therefore there is a substantial need for refineries to burn fuel gas instead of fuel oil and avoiding, if possible, the use of imported natural gas. The refinery case study presents a substantial excess of fuel gas resulting from the production of hydrogen to obtain clean flues with low sulphurs. The aim of this paper is to optimize the use of the hydrogen excess with the implementation of a gas turbine with heat recovery with a feed near 28-31% of hydrogen. The cogeneration system was modelled by GateCycle 5.34.0.r. and the results obtained for the simulation were considered optimistic. Considering a production of 13 MW of electrical power the overall efficiency reached a value of 76% and 22 t/h of vapour (17 MW) from a feed of 3 t/h of fuel gas (39 MW). These results allow a higher electrical power production and a consequent reduction in the emissions of SO2 and CO2.

  14. Burning clean fuel gas improves energetic efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Fonseca, Andre; Gomes, Luisa A.C.N. [Chemical Engineering Department, Instituto Superior de Engenharia do Porto, Rua Dr. Antonio Bernardino de Almeida 431, P4200-072 Porto (Portugal); Tavares, Manuel L.C. [Galp Energia, Area de Tecnologia, Apartado 3015, 4451-852 Leca da Palmeira (Portugal)

    2010-03-15

    One the most critical problems faced by refineries nowadays is the continuous increasing of legislation urging emissions reductions specifically SO{sub 2}, NO{sub x}, and particles. Therefore there is a substantial need for refineries to burn fuel gas instead of fuel oil and avoiding, if possible, the use of imported natural gas. The refinery case study presents a substantial excess of fuel gas resulting from the production of hydrogen to obtain clean flues with low sulphurs. The aim of this paper is to optimize the use of the hydrogen excess with the implementation of a gas turbine with heat recovery with a feed near 28-31% of hydrogen. The cogeneration system was modelled by GateCycle 5.34.0.r. and the results obtained for the simulation were considered optimistic. Considering a production of 13 MW of electrical power the overall efficiency reached a value of 76% and 22 t/h of vapour (17 MW) from a feed of 3 t/h of fuel gas (39 MW). These results allow a higher electrical power production and a consequent reduction in the emissions of SO{sub 2} and CO{sub 2}. (author)

  15. Nutritional status and access to clean fuels: Evidence from South Asia

    OpenAIRE

    Bhagowalia, Priya; Gupta, Parul

    2011-01-01

    Indoor air pollution due to solid fuels is among the ten most important risk factors in global burden of disease leading to respiratory diseases, anaemia, blindness and other disorders. This study examines the correlations between fuel choice and the nutritional status of children. We also explore if factors such as income, kitchen location and education play any role in conditioning fuel choice. Our results suggest that the choice and use of fuel has long lasting effects on the growth and he...

  16. Use of the GranuFlow Process in Coal Preparation Plants to Improve Energy Recovery and Reduce Coal Processing Wastes

    Energy Technology Data Exchange (ETDEWEB)

    Glenn A. Shirey; David J. Akers

    2005-12-31

    With the increasing use of screen-bowl centrifuges in today's fine coal cleaning circuits, a significant amount of low-ash, high-Btu coal can be lost during the dewatering step due to the difficulty in capturing coal of this size consist (< 100 mesh or 0.15mm). The GranuFlow{trademark} technology, developed and patented by an in-house research group at DOE-NETL, involves the addition of an emulsified mixture of high-molecular-weight hydrocarbons to a slurry of finesized coal before cleaning and/or mechanical dewatering. The binder selectively agglomerates the coal, but not the clays or other mineral matter. In practice, the binder is applied so as to contact the finest possible size fraction first (for example, froth flotation product) as agglomeration of this fraction produces the best result for a given concentration of binder. Increasing the size consist of the fine-sized coal stream reduces the loss of coal solids to the waste effluent streams from the screen bowl centrifuge circuit. In addition, the agglomerated coal dewaters better and is less dusty. The binder can also serve as a flotation conditioner and may provide freeze protection. The overall objective of the project is to generate all necessary information and data required to commercialize the GranuFlow{trademark} Technology. The technology was evaluated under full-scale operating conditions at three commercial coal preparation plants to determine operating performance and economics. The handling, storage, and combustion properties of the coal produced by this process were compared to untreated coal during a power plant combustion test.

  17. Trace and major element pollution originating from coal ash suspension and transport processes.

    Science.gov (United States)

    Popovic, A; Djordjevic, D; Polic, P

    2001-04-01

    Coal ash obtained by coal combustion in the "Nikola Tesla A" power plant in Obrenovac, near Belgrade, Yugoslavia, is mixed with water of the Sava river and transported to the dump. In order to assess pollution caused by leaching of some minor and major elements during ash transport through the pipeline, two sets of samples (six samples each) were subjected to a modified sequential extraction. The first set consisted of coal ash samples taken immediately after combustion, while the second set was obtained by extraction with river water, imitating the processes that occur in the pipeline. Samples were extracted consecutively with distilled water and a 1 M solution of KCl, pH 7, and the differences in extractability were compared in order to predict potential pollution. Considering concentrations of seven trace elements as well as five major elements in extracts from a total of 12 samples, it can be concluded that lead and cadmium do not present an environmental threat during and immediately after ash transport to the dump. Portions of zinc, nickel and chromium are released during the ash transport, and arsenic and manganese are released continuously. Copper and iron do not present an environmental threat due to element leaching during and immediately after the coal ash suspension and transport. On the contrary, these elements, as well as chromium, become concentrated during coal ash transport. Adsorbed portions of calcium, magnesium and potassium are also leached during coal ash transport. PMID:11341293

  18. Symbiotic Nuclear—Coal Systems for Production of Liquid Fuels

    Science.gov (United States)

    Taczanowski, S.

    The notion of safety is not confined to the technological or non-proliferation aspects. It covers also the elements of energy policy: irrational reactions of societies, emotions, egoistic interests of more or less powerful pressure of economical and external political factors. One should be conscious that the country's privilege of being equipped by the Nature with rich resources of oil or gas is not solely economical, but even more a political one. Simultaneously, the gradual depletion of world hydrocarbons that draws behind irrevocable price increase has to be expected within the time scale of exploitation of power plants (now amounted to ~60 years). Therefore consequences of energy policy last much longer than the perspectives the political or economical decision makers are planning and acting within and the public is expecting successes and finally evaluating them. The world oil and gas resources are geopolitically very non-uniformly distributed, in contrast to coal and uranium. Since the level of energy self-sufficiency of the EU is highest for coal, the old idea of synfuels production from coal is recalled. Yet, in view of limits to the CO2 emissions in the EU another method has to be used here than the conventional coal liquefaction just applied in China. Simultaneously, an interesting evolution of energy prices was be observed, namely an increase in that of motor fuels in contrast to that of electricity remaining well stable. This fact suggests that the use of electricity (mainly the off-peak load), generated without emissions of CO2 for production of liquid fuels can prove reasonable. Thus, the essence of the presented idea of coal-nuclear symbiosis lies in the supply of energy in the form of H2, necessary for this process, from a nuclear reactor. Particularly, in the present option H2 is obtained by electrolytic water splitting supplying also O2 as a precious by-product in well mature and commercially available already since decades, Light Water Reactors

  19. Influence of flue gas cleaning system on characteristics of PM2.5 emission from coal-fired power plants

    Institute of Scientific and Technical Information of China (English)

    Ao Wang; Qiang Song; Gongming Tu; Hui Wang; Yong Yue; Qiang Yao

    2014-01-01

    This study investigated the influence of precipitators and wet flue gas desulfurization equipment on charac-teristics of PM2.5 emission from coal-fired power stations. We measured size distribution and removal efficiencies, including hybrid electrostatic precipitator/bag filters (ESP/BAGs) which have rarely been studied. A bimodal distribution of particle concentrations was observed at the inlet of each precipitator. After the precipitators, particle concentrations were significantly reduced. Although a bimodal distribution was still observed, all peak positions shifted to the smaller end. The removal efficiencies of hybrid ESP/BAGs reached 99%for PM2.5, which is considerably higher than those for other types of precipitators. In particular, the influence of hybrid ESP/BAG operating conditions on the performance of dust removal was explored. The efficiency of hybrid ESP/BAGs decreased by 1.9%when the first electrostatic field was shut down. The concentrations and distributions of particulate matter were also measured in three coal-fired power plants before and after desulfurization devices. The results showed diverse removal efficiencies for different desulfurization towers. The reason for the difference requires further research. We estimated the influence of removal technology for particulate matter on total emissions in China. Substituting ESPs with hybrid ESP/BAGs could reduce the total emissions to 104.3 thousand tons, with 47.48 thousand tons of PM2.5.

  20. Removal of organic and inorganic sulfur from Ohio coal by combined physical and chemical process. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Attia, Y.A.; Zeky, M.El.; Lei, W.W.; Bavarian, F.; Yu, S. [Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering

    1989-04-28

    This project consisted of three sections. In the first part, the physical cleaning of Ohio coal by selective flocculation of ultrafine slurry was considered. In the second part, the mild oxidation process for removal of pyritic and organic sulfur.was investigated. Finally, in-the third part, the combined effects of these processes were studied. The physical cleaning and desulfurization of Ohio coal was achieved using selective flocculation of ultrafine coal slurry in conjunction with froth flotation as flocs separation method. The finely disseminated pyrite particles in Ohio coals, in particular Pittsburgh No.8 seam, make it necessary to use ultrafine ({minus}500 mesh) grinding to liberate the pyrite particles. Experiments were performed to identify the ``optimum`` operating conditions for selective flocculation process. The results indicated that the use of a totally hydrophobic flocculant (FR-7A) yielded the lowest levels of mineral matters and total sulfur contents. The use of a selective dispersant (PAAX) increased the rejection of pyritic sulfur further. In addition, different methods of floc separation techniques were tested. It was found that froth flotation system was the most efficient method for separation of small coal flocs.

  1. Priority pollutants and associated constituents in untreated and treated discharges from coal mining or processing facilities in Pennsylvania, USA

    Science.gov (United States)

    Cravotta, Charles; Keith B.C. Brady

    2015-01-01

    Clean sampling and analysis procedures were used to quantify more than 70 inorganic constituents, including 35 potentially toxic or hazardous constituents, organic carbon, and other characteristics of untreated (influent) and treated (effluent) coal-mine discharges (CMD) at 38 permitted coal-mining or coal-processing facilities in the bituminous coalfield and 4 facilities in the anthracite coalfield of Pennsylvania. Of the 42 facilities sampled during 2011, 26 were surface mines, 11 were underground mines, and 5 were coal refuse disposal operations. Treatment of CMD with caustic soda (NaOH), lime (CaO or Ca(OH)2), flocculent, or limestone was ongoing at 21%, 40%, 6%, and 4% of the facilities, respectively; no chemicals were added at the remaining facilities. All facilities with CMD treatment incorporated structures for active or passive aeration and settling of metal-rich precipitate.

  2. TOXIC SUBSTANCES FROM COAL COMBUSTION

    Energy Technology Data Exchange (ETDEWEB)

    A KOLKER; AF SAROFIM; CL SENIOR; FE HUGGINS; GP HUFFMAN; I OLMEZ; J LIGHTY; JOL WENDT; JOSEPH J HELBLE; MR AMES; N YAP; R FINKELMAN; T PANAGIOTOU; W SEAMES

    1998-12-08

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, the Lignite Research Council, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environmental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NO combustion systems, and new power generation x plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 July 1998 through 30 September 1998. During this period distribution of all three Phase II coals was completed. Standard analyses for the whole coal samples were also completed. Mössbauer analysis of all project coals and fractions received to date has been completed in order to obtain details of the iron mineralogy. The analyses of arsenic XAFS data for two of the project coals and for some high arsenic coals have been completed. Duplicate splits of the Ohio 5,6,7 and North Dakota lignite samples were taken through all four steps of the selective leaching procedure. Leaching analysis of the Wyodak coal has recently commenced. Preparation of polished coal/epoxy pellets for probe/SEM studies is underway. Some exploratory mercury LIII XAFS work was

  3. Zinc isotopic composition of particulate matter generated during the combustion of coal and coal + tire-derived fuels.

    Science.gov (United States)

    Borrok, David M; Gieré, Reto; Ren, Minghua; Landa, Edward R

    2010-12-01

    Atmospheric Zn emissions from the burning of coal and tire-derived fuel (TDF) for power generation can be considerable. In an effort to lay the foundation for tracking these contributions, we evaluated the Zn isotopes of coal, a mixture of 95 wt % coal + 5 wt % TDF, and the particulate matter (PM) derived from their combustion in a power-generating plant. The average Zn concentrations and δ(66)Zn were 36 mg/kg and 183 mg/kg and +0.24‰ and +0.13‰ for the coal and coal + TDF, respectively. The δ(66)Zn of the PM sequestered in the cyclone-type mechanical separator was the lightest measured, -0.48‰ for coal and -0.81‰ for coal+TDF. The δ(66)Zn of the PM from the electrostatic precipitator showed a slight enrichment in the heavier Zn isotopes relative to the starting material. PM collected from the stack had the heaviest δ(66)Zn in the system, +0.63‰ and +0.50‰ for the coal and coal + TDF, respectively. Initial fractionation during the generation of a Zn-rich vapor is followed by temperature-dependent fractionation as Zn condenses onto the PM. The isotopic changes of the two fuel types are similar, suggesting that their inherent chemical differences have only a secondary impact on the isotopic fractionation process. PMID:21047059

  4. Processing and properties of a solid energy fuel from municipal solid waste (MSW) and recycled plastics

    Energy Technology Data Exchange (ETDEWEB)

    Gug, JeongIn, E-mail: Jeongin_gug@student.uml.edu; Cacciola, David, E-mail: david_cacciola@student.uml.edu; Sobkowicz, Margaret J., E-mail: Margaret_sobkowiczkline@uml.edu

    2015-01-15

    Highlights: • Briquetting was used to produce solid fuels from municipal solid waste and recycled plastics. • Optimal drying, processing temperature and pressure were found to produce stable briquettes. • Addition of waste plastics yielded heating values comparable with typical coal feedstocks. • This processing method improves utilization of paper and plastic diverted from landfills. - Abstract: Diversion of waste streams such as plastics, woods, papers and other solid trash from municipal landfills and extraction of useful materials from landfills is an area of increasing interest especially in densely populated areas. One promising technology for recycling municipal solid waste (MSW) is to burn the high-energy-content components in standard coal power plant. This research aims to reform wastes into briquettes that are compatible with typical coal combustion processes. In order to comply with the standards of coal-fired power plants, the feedstock must be mechanically robust, free of hazardous contaminants, and moisture resistant, while retaining high fuel value. This study aims to investigate the effects of processing conditions and added recyclable plastics on the properties of MSW solid fuels. A well-sorted waste stream high in paper and fiber content was combined with controlled levels of recyclable plastics PE, PP, PET and PS and formed into briquettes using a compression molding technique. The effect of added plastics and moisture content on binding attraction and energy efficiency were investigated. The stability of the briquettes to moisture exposure, the fuel composition by proximate analysis, briquette mechanical strength, and burning efficiency were evaluated. It was found that high processing temperature ensures better properties of the product addition of milled mixed plastic waste leads to better encapsulation as well as to greater calorific value. Also some moisture removal (but not complete) improves the compacting process and results in

  5. Processing and properties of a solid energy fuel from municipal solid waste (MSW) and recycled plastics

    International Nuclear Information System (INIS)

    Highlights: • Briquetting was used to produce solid fuels from municipal solid waste and recycled plastics. • Optimal drying, processing temperature and pressure were found to produce stable briquettes. • Addition of waste plastics yielded heating values comparable with typical coal feedstocks. • This processing method improves utilization of paper and plastic diverted from landfills. - Abstract: Diversion of waste streams such as plastics, woods, papers and other solid trash from municipal landfills and extraction of useful materials from landfills is an area of increasing interest especially in densely populated areas. One promising technology for recycling municipal solid waste (MSW) is to burn the high-energy-content components in standard coal power plant. This research aims to reform wastes into briquettes that are compatible with typical coal combustion processes. In order to comply with the standards of coal-fired power plants, the feedstock must be mechanically robust, free of hazardous contaminants, and moisture resistant, while retaining high fuel value. This study aims to investigate the effects of processing conditions and added recyclable plastics on the properties of MSW solid fuels. A well-sorted waste stream high in paper and fiber content was combined with controlled levels of recyclable plastics PE, PP, PET and PS and formed into briquettes using a compression molding technique. The effect of added plastics and moisture content on binding attraction and energy efficiency were investigated. The stability of the briquettes to moisture exposure, the fuel composition by proximate analysis, briquette mechanical strength, and burning efficiency were evaluated. It was found that high processing temperature ensures better properties of the product addition of milled mixed plastic waste leads to better encapsulation as well as to greater calorific value. Also some moisture removal (but not complete) improves the compacting process and results in

  6. Combustion and fuel characterization of coal-water fuels

    Energy Technology Data Exchange (ETDEWEB)

    1989-07-01

    Pittsburgh Energy Technology Center (PETC) of the Department of Energy initiated a comprehensive effort in 1982 to develop the necessary performance and cost data and to assess the commercial viability of coal water fuels (CWFs) as applied to representative utility and industrial units. The effort comprised six tasks beginning with coal resource evaluation and culminating in the assessment of the technical and economic consequences of switching representative commercial units from oil to state-of-the-art CWF firing. Extensive bench, pilot and commercial-scale tests were performed to develop necessary CWF combustion and fireside performance data for the subsequent boiler performance analyses and retrofit cost estimates. This report (Volume 2) provides a review of the fuel selection and procurement activities. Included is a discussion on coal washability, transport of the slurry, and characterization. 20 figs., 26 tabs.

  7. A clean coal: myth or reality?

    International Nuclear Information System (INIS)

    The first part of this report comments the evolution of coal demand which has doubled during the last 35 years for different reasons (increase of electricity production, development of China and India), but is still based on local production although coal international trade increased indeed quicker than coal demand. It notices that there is still a lot of coal available for the future, and that demand will keep on increasing. It outlines that coal will have to reduce its impacts on the environment, and presents the technologies which will allow this reduction. It also presents the technologies for CO2 capture and storage (CCS), and evokes its regulatory issues and its environmental impacts. Some research and development projects in CCS in different countries (Europe, Germany, United States, Australia) are presented. Finally, it stresses the importance of a global deployment of much less polluting technologies to limit greenhouse gas emissions

  8. Surface magnetic enhancement for coal cleaning. Quarterly technical progress report no. 6, May 1--July 31, 1989

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, J.Y.

    1989-12-31

    The fundamental chemistry for selective adsorption of magnetizing reagent on coal-associated minerals to enhance the magnetic susceptibility of minerals have been established in Phase I study. The application of the results on coal cleaning is in progress in the Phase II study. The task in Phase II study for coal selection, preparation, and characterization is completed in this reporting period. The optimization of adsorption conditions for {minus}48 mesh ROM coals and flotation concentrates is about completed. Experiments have shown that successful coal cleaning can be obtained with this magnetizing reagent approach. The task to adapt the approach to various processing schemes is just initiated.

  9. Selective flotation of inorganic sulfides from coal

    Science.gov (United States)

    Miller, Kenneth J.; Wen, Wu-Wey

    1989-01-01

    Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow.

  10. Clean Coal Technology Demonstration Program: Program update 1991 (as of December 31, 1991)

    International Nuclear Information System (INIS)

    The Clean Coal Technology Demonstration Program (also referred to as the CCT Program) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of large-scale ''showcase'' facilities built across the country. The program takes the most promising advanced coal-based technologies and moves them into the commercial marketplace through demonstration. These demonstrations are on a scale large enough to generate all the data, from design, construction and operation, that are necessary for the private sector to judge commercial potential and make informed, confident decisions on commercial readiness. The CCT Program has been identified in the National Energy Strategy as major initiative supporting the strategy's overall goals to: increase efficiency of energy use; secure future energy supplies; enhance environmental quality; fortify foundations. The technologies being demonstrated under the CCT Program when commercially available will enable coal to reach its full potential as a source of energy for the nation and the international marketplace. The goal of the program is to furnish the US and international energy marketplaces with a number of advanced, highly efficient, and environmentally acceptable coal-using technologies

  11. Applying environmental externalities to US Clean Coal Technologies for Asia

    International Nuclear Information System (INIS)

    The United States is well positioned to play an expanding role in meeting the energy technology demands of the Asian Pacific Basin, including Indonesia, Thailand, and the Republic of China (ROC-Taiwan). The US Department of Energy Clean Coal Technology (CCT) Demonstration Program provides a proving ground for innovative coal-related technologies that can be applied domestically and abroad. These innovative US CCTs are expected to satisfy increasingly stringent environmental requirements while substantially improving power generation efficiencies. They should also provide distinct advantages over conventional pulverized coal-fired combustors. Finally, they are expected to be competitive with other energy options currently being considered in the region. This paper presents potential technology scenarios for Indonesia, Thailand, and the ROC-Taiwan and considers an environmental cost-benefit approach employing a newly developed method of applying environmental externalities. Results suggest that the economic benefits from increased emission control can indeed be quantified and used in cost-benefit comparisons, and that US CCTs can be very cost effective in reducing emissions

  12. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  13. Fuel economy: thermochemical regeneration and new method of coal gasification

    Energy Technology Data Exchange (ETDEWEB)

    Nosach, V.H.

    1982-02-01

    Heat regeneration and coal gasification are two means of increasing the efficiency of utilizing fossil fuel resources. Two methods of heat regeneration are discussed: air regeneration and a new method, thermochemical regeneration. Use of thermochemical regeneration in heat-utilizing aggregates has increased fuel efficiency by 15-20%, and the combined use of both heat regeneration methods is also highly effective. The increased use of coal is generally associated with the greater air pollution. The most effective method of controlling harmful atmospheric emissions by coal-fueled power plants is a two-stage combustion system with preliminary coal gasification to remove sulfur and ash and combustion of the pure gasification products. But the introduction of coal gasification has increased the need for designing new gas generators. The advantages of using coal gasification at electric power plants include increasing the reliability of steam generators, decreasing expenditures for transporting fuel, and more complete utilization of coal. Coal gasification also broadens the use of low-quality coal. Gasification of Siberian coal with the production of synthetic natural gas also lessens the problem of transporting energy resources from Siberia to central regions of the USSR. A continuous method has been developed for producing synthetic gas by steam gasification of coal without use of oxygen.

  14. Report to the United States Congress clean coal technology export markets and financing mechanisms

    International Nuclear Information System (INIS)

    This report responds to a Congressional Conference Report that requests that $625,000 in funding provided will be used by the Department to identify potential markets for clean coal technologies in developing countries and countries with economies in transition from nonmarket economies and to identify existing, or new, financial mechanisms or financial support to be provided by the Federal government that will enhance the ability of US industry to participate in these markets. The Energy Information Administration (EIA) expects world coal consumption to increase by 30 percent between 1990 and 2010, from 5.1 to 6.5 billion short tons. Five regions stand out as major foreign markets for the export of US clean coal technologies: China; The Pacific Rim (other than China); South Asia (primarily India); Transitional Economies (Central Europe and the Newly Independent States); and Other Markets (the Americas and Southern Africa). Nearly two-thirds of the expected worldwide growth in coal utilization will occur in China, one quarter in the United States. EIA forecasts nearly a billion tons per year of additional coal consumption in China between 1990 and 2010, a virtual doubling of that country's coal consumption. A 30-percent increase in coal consumption is projected in other developing countries over that same period. This increase in coal consumption will be accompanied by an increase in demand for technologies for burning coal cost-effectively, efficiently and cleanly. In the Pacific Rim and South Asia, rapid economic growth coupled with substantial indigenous coal supplies combine to create a large potential market for CCTS. In Central Europe and the Newly Independent States, the challenge will be to correct the damage of decades of environmental neglect without adding to already-considerable economic disruption. Though the situation varies, all these countries share the basic need to use indigenous low-quality coal cleanly and efficiently

  15. CONCEPTUAL STUDIES OF A FUEL-FLEXIBLE LOW-SWIRL COMBUSTION SYSTEM FOR THE GAS TURBINE IN CLEAN COAL POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    Smith, K.O.; Littlejohn, David; Therkelsen, Peter; Cheng, Robert K.; Ali, S.

    2009-11-30

    This paper reports the results of preliminary analyses that show the feasibility of developing a fuel flexible (natural gas, syngas and high-hydrogen fuel) combustion system for IGCC gas turbines. Of particular interest is the use of Lawrence Berkeley National Laboratory's DLN low swirl combustion technology as the basis for the IGCC turbine combustor. Conceptual designs of the combustion system and the requirements for the fuel handling and delivery circuits are discussed. The analyses show the feasibility of a multi-fuel, utility-sized, LSI-based, gas turbine engine. A conceptual design of the fuel injection system shows that dual parallel fuel circuits can provide range of gas turbine operation in a configuration consistent with low pollutant emissions. Additionally, several issues and challenges associated with the development of such a system, such as flashback and auto-ignition of the high-hydrogen fuels, are outlined.

  16. Trace and major element pollution originating from coal ash suspension and transport processes

    Energy Technology Data Exchange (ETDEWEB)

    Popovic, A.; Djordjevic, D.; Polic, P. [University of Belgrade, Belgrade (Yugoslavia). Faculty of Science, Dept. of Chemistry

    2001-07-01

    Coal ash obtained from Nikola Tesla A power plant in Obrenovac, near Belgrade, Yugoslavia, is mixed with water of the Sava river and transported to the dump. In order to assess pollution caused by leaching of some minor and major elements during ash transport through the pipeline, two sets of samples (six samples each) were subjected to a modified sequential extraction. The first set consisted of coal ash samples taken immediately after combustion, while the second set was obtained by extraction with river water, imitating the processes that occur in the pipeline. Samples were extracted consecutively with distilled water and a 1 M solution of KCl, pH 7, and the differences in extractability were compared in order to predict potential pollution. It is concluded that lead and cadmium do not present an environmental threat during and immediately after ash transport to the dump. Portions of zinc, nickel and chromium are released during the ash transport, and arsenic and manganese are released continuously. Copper and iron do not present an environmental threat due to element leaching during and immediately after the coal ash suspension and transport. On the contrary, these elements, as well as chromium, become concentrated during coal ash transport. Adsorbed portions of calcium, magnesium and potassium are also leached during coal ash transport.

  17. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman

    2006-03-30

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe

  18. Gasification Studies Task 4 Topical Report, Utah Clean Coal Program

    Energy Technology Data Exchange (ETDEWEB)

    Whitty, Kevin [Univ. of Utah, Salt Lake City, UT (United States); Fletcher, Thomas [Univ. of Utah, Salt Lake City, UT (United States); Pugmire, Ronald [Univ. of Utah, Salt Lake City, UT (United States); Smith, Philip [Univ. of Utah, Salt Lake City, UT (United States); Sutherland, James [Univ. of Utah, Salt Lake City, UT (United States); Thornock, Jeremy [Univ. of Utah, Salt Lake City, UT (United States); Hunsacker, Isaac [Univ. of Utah, Salt Lake City, UT (United States); Li, Suhui [Univ. of Utah, Salt Lake City, UT (United States); Kelly, Kerry [Univ. of Utah, Salt Lake City, UT (United States); Puntai, Naveen [Univ. of Utah, Salt Lake City, UT (United States); Reid, Charles [Univ. of Utah, Salt Lake City, UT (United States); Schurtz, Randy [Univ. of Utah, Salt Lake City, UT (United States)

    2011-10-01

    A key objective of the Task 4 activities has been to develop simulation tools to support development, troubleshooting and optimization of pressurized entrained-flow coal gasifiers. The overall gasifier models (Subtask 4.1) combine submodels for fluid flow (Subtask 4.2) and heat transfer (Subtask 4.3) with fundamental understanding of the chemical (Subtask 4.4) and physical (Subtask 4.5) processes that take place as coal particles are converted to synthesis gas and slag. However, it is important to be able to compare predictions from the models against data obtained from actual operating coal gasifiers, and Subtask 4.6 aims to provide an accessible, non-proprietary system, which can be operated over a wide range of conditions to provide well-characterized data for model validation.

  19. Study on characteristics of pipeline transportation and sulfur fixing of cleaned coal logs

    Institute of Scientific and Technical Information of China (English)

    LIN Yu; LIN Qun; TANG Jun; LIU Tong-cheng

    2006-01-01

    As special cylindrical briquettes of coal for long distance pipeline transportation and directly cleaned combustion the cleaned coal logs should possess two characteristics of transportation in pipeline and cleaned combustion. In order to make cleaned coal logs a rational technology for manufacturing, cleaned coal logs was designed and compound sulfur fixing binders with high effects of binding and sulfur-fixing was selected and combined. In addition, by means of characteristic experiments of strength, wear, waterproof and sulfur-fixing five different cleaned coal logs made with different compound sulfur fixing binders in different compaction conditions was tested and measured. Experimental results indicated that the manufacturing technology of cleaned coal logs was reasonable and the combination of compound sulfur fixing binders was scientific. Cleaned coal logs made up with the fourth group of coal mixture had high strength, good waterproof property, efficient sulfur-fixing, good characteristic of transportation, and achieved the performance requirement for pipeline transportation and sulfur fixing.

  20. Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

    Energy Technology Data Exchange (ETDEWEB)

    Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

    1982-01-01

    This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

  1. Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis of liquid fuels from coal to minimize carbon dioxide emissions

    Energy Technology Data Exchange (ETDEWEB)

    Gerald P. Huffman [University of Kentucky, Lexington, KY (United States). Consortium for Fossil Fuel Science and Department of Chemical & Materials Engineering

    2011-08-15

    Synthesis gas (syngas) produced from coal typically has hydrogen to carbon monoxide ratios in the range of approximately 0.7-1.1, depending on the gasification method. In order to produce liquid fuels from this syngas by Fischer-Tropsch synthesis (FTS), these ratios must be raised to 2.0 or higher. If this is accomplished by the water-gas shift reaction, the traditional method, large emissions of carbon dioxide are produced. In this paper, it is shown that catalytic dehydrogenation (CDH) of the gaseous C1-C4 products of FT synthesis and recycling of the resulting hydrogen to the syngas feed-stream can increase the H{sub 2}/CO ratio to the desired values with little or no production of carbon dioxide. All carbon from the CDH reaction is in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWCNT). The amounts of hydrogen and MWCNT produced, carbon dioxide emissions avoided, and water saved are calculated for a 50,000 bbl/day FTS-CDH plant and it is demonstrated that the energy balance for the process is favorable. Methods of utilizing the large quantity of MWCNT produced are discussed. 50 refs., 6 figs., 3 tabs.

  2. Comprehensive report to Congress Clean Coal Technology Program

    International Nuclear Information System (INIS)

    This project will provide a full-scale demonstration of Micronized Coal Reburn (MCR) technology for the control of NOx on a wall-fired steam generator. This demonstration is expected to reduce NOx emissions by 50 to 60%. Micronized coal is coal that has been very finely pulverized (80% less than 325 mesh). This micronized coal, which may comprise up to 30% of the total fuel fired in the furnace, is fired high in the furnace in a fuel-rich reburn zone at a stoichiometry of 0.8. Above the reburn zone, overfire air is injected into the burnout zone at high velocity for good mixing to ensure complete combustion. Overall excess air is 15%. MCR technology reduces NOx emissions with minimal furnace modifications, and the improved burning characteristics of micronized coal enhance boiler performance

  3. Advanced CFB for clean and efficient coal power

    Energy Technology Data Exchange (ETDEWEB)

    H. Nevalainen; J. Saastamoinen; M. Jegoroff (and others) [VTT, Jyvaskyla (Finland)

    2009-07-01

    The European Union's Clefco project (2004-06) aimed to promote the development of once through steam cycle (OTSC) CFB technology. This was carried out by increasing the process knowledge that is essential for successful boiler design and demonstration of the multi-fuel flexibility of the process. To fulfil the development needs of OTSC CFB technology, a comprehensive understanding of CFB combustion processes needed to be achieved. Intensive research in laboratory, pilot and full-scale combustors was required to fulfil the abovementioned objectives. In the project, each partner worked in its own field of research. Cooperation between partners enabled the best-possible understanding of the process. In order to study different process characteristics and verify measurements and simulations, experiments were carried out with different size reactors - VTT's laboratory scale CFB reactor, VTT's 50 kW pilot CFB reactor, Chalmers' 12 MW CFB boiler, cold rig and several commercial boilers. To find out possibilities for end-use of ash, national legislations and standards were studied. Knowledge was applied to ash management possibilities for coal combustion and co-combustion of coal and biomass. The studies were based on the ash characterisation, which was carried out for ash samples collected during the projects' combustion tests. 52 refs., 122 figs., 42 tabs.

  4. Development of coal-based technologies for Department of Defense Facilities. Semiannual technical progress report, March 28, 1997--September 27, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Miller, B.G.; Miller, S.F.; Morrison, J.L. [and others

    1998-01-06

    The U.S. Department of Defense (DOD), through an Interagency Agreement with the U.S. Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Slurry Fuel Technology, with the aim of developing technologies which can potentially decrease DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE. Phase I was completed on November 1, 1995. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations included performing pilot-scale air toxics (i.e., trace elements and volatile organic compounds) testing and evaluating a ceramic filtering device on the demonstration boiler. Also, a sodium bicarbonate duct injection system was installed on the demonstration boiler. An economic analysis was conducted which investigated the benefits of decreased dependence on imported oil by using new coal combustion technologies. Work related to coal preparation and utilization was primarily focused on preparing the final report. Work in Phase III focused on coal preparation studies, pilot-scale NO{sub x} reduction studies, economic analyses of coal use, and evaluation of deeply-cleaned coal as boiler fuel. Coal preparation studies were focused on continuing activities on particle size control, physical separations, and surface-based separation processes. The evaluation of deeply-cleaned coal as boiler fuel included receiving three cleaned coals from Cyprus-Amax.

  5. OxyFuel combustion of Coal and Biomass

    DEFF Research Database (Denmark)

    Toftegaard, Maja Bøg

    and oxyfuel atmospheres. Apart from slightly improved burnout and reduced emissions of NO during oxyfuel combustion these operating conditions yield similar combustion characteristics in both environments. Co-firing coal and biomass or combustion of pure biomass in an oxyfuel power plant could yield...... power plants burning coal or other fuels during the period of transition to renewable energy sources. The oxyfuel combustion process introduces several changes to the power plant configuration. Most important, the main part of the flue gas is recirculated to the boiler and mixed with pure oxygen...... with a straw share of 50 wt% has added valuable understanding to the trends in ash and deposits chemistry for coal/straw co-firing. Recirculation of untreated flue gas in oxyfuel plants will increase the in-boiler levels of NO and SO2 significantly. Experiments with simulated recirculation of NO and SO2 have...

  6. Application of Fly Ash from Solid Fuel Combustion in Concrete

    DEFF Research Database (Denmark)

    Pedersen, Kim Hougaard

    2008-01-01

    in the feeding phase or during the combustion process, which gave rise to increased formation of soot. A low-NOx tangential fired 875 MWth power plant burning bituminous coal have been operated under extreme conditions in order to test the impact of the operating conditions on fly ash adsorption behavior and NOx......Application of Fly Ash from Solid Fuel Combustion in Concrete Kim H. Pedersen Abstract Industrial utilization of fly ash from pulverized coal combustion plays an important role in environmentally clean and cost effective power generation. Today, the primary market for fly ash utilization...... with implementation of low-NOx combustion technologies. The present thesis concerns three areas of importance within this field: 1) testing of fly ash adsorption behavior; 2) the influence of fuel type and combustion conditions on the ash adsorption behaviour including full-scale experiments at the power plant...

  7. Can propane compete in the clean alternate fuels market

    International Nuclear Information System (INIS)

    This paper presents the status of various clean fuels programs for fleet vehicles. It also identifies and assesses the fleet market for clean fuels in nonattainment areas and addresses the factors critical to penetrating this market. Title II of the Clean Air Act Amendments of 1990 (CAAA) have defined clean fuels as ethanol, methanol, other alcohols, hydrogen, electricity, natural gas, and LP-Gas (propane). Leading clean fuels are identified and discussed. This paper also assesses the advantages and disadvantages for propane versus the other clean vehicle fuel options

  8. VERIFICATION TESTING OF EMISSIONS FROM THE COMBUSTION OF A-55 CLEAN FUELS IN A FIRETUBE BOILER

    Science.gov (United States)

    The report gives results of testing three fuels in a small (732 kW) firetube package boiler to determine emissions of carbon monoxide (CO), nitrogen oxide (NO), particulate matter (PM), and total hydrocarbons (THCs). The tests were part of EPA's Environmental Technology Verificat...

  9. PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS

    Energy Technology Data Exchange (ETDEWEB)

    Dady Dadyburjor; Philip R. Biedler; Chong Chen; L. Mitchell Clendenin; Manoj Katakdaunde; Elliot B. Kennel; Nathan D. King; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2004-08-31

    This Department of Energy National Energy Technology Laboratory sponsored project developed carbon products, using mildly hydrogenated solvents to extract the organic portion of coal to create synthetic pitches, cokes, carbon foam and carbon fibers. The focus of this effort was on development of lower cost solvents, milder hydrogenation conditions and improved yield in order to enable practical production of these products. This technology is needed because of the long-term decline in production of domestic feedstocks such as petroleum pitch and coal tar pitch. Currently, carbon products represents a market of roughly 5 million tons domestically, and 19 million tons worldwide. Carbon products are mainly derived from feedstocks such as petroleum pitch and coal tar pitch. The domestic supply of petroleum pitch is declining because of the rising price of liquid fuels, which has caused US refineries to maximize liquid fuel production. As a consequence, the long term trend has a decline in production of petroleum pitch over the past 20 years. The production of coal tar pitch, as in the case of petroleum pitch, has likewise declined significantly over the past two decades. Coal tar pitch is a byproduct of metallurgical grade coke (metcoke) production. In this industry, modern metcoke facilities are recycling coal tar as fuel in order to enhance energy efficiency and minimize environmental emissions. Metcoke production itself is dependent upon the production requirements for domestic steel. Hence, several metcoke ovens have been decommissioned over the past two decades and have not been replaced. As a consequence sources of coal tar are being taken off line and are not being replaced. The long-term trend is a reduction in coal tar pitch production. Thus import of feedstocks, mainly from Eastern Europe and China, is on the rise despite the relatively large transportation cost. To reverse this trend, a new process for producing carbon products is needed. The process must be

  10. Coal liquefaction process streams characterization and evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1992-03-01

    CONSOL R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  11. Coal liquefaction process streams characterization and evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Winschel, R.A.; Brandes, S.D.; Robbins, G.A.; Burke, F.P.

    1991-11-01

    Consol R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-field: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

  12. Thermochemical production of liquid fuels from biomass: Thermo-economic modeling, process design and process integration analysis

    Energy Technology Data Exchange (ETDEWEB)

    Tock, Laurence; Gassner, Martin; Marechal, Francois [Industrial Energy Systems Laboratory, Ecole Polytechnique Federale de Lausanne, Station postale 9, CH-1015 Lausanne (Switzerland)

    2010-12-15

    A detailed thermo-economic model combining thermodynamics with economic analysis and considering different technological alternatives for the thermochemical production of liquid fuels from lignocellulosic biomass is presented. Energetic and economic models for the production of Fischer-Tropsch fuel (FT), methanol (MeOH) and dimethyl ether (DME) by means of biomass drying with steam or flue gas, directly or indirectly heated fluidized bed or entrained flow gasification, hot or cold gas cleaning, fuel synthesis and upgrading are reviewed and developed. The process is integrated and the optimal utility system is computed. The competitiveness of the different process options is compared systematically with regard to energetic, economic and environmental considerations. At several examples, it is highlighted that process integration is a key element that allows for considerably increasing the performance by optimal utility integration and energy conversion. The performance computations of some exemplary technology scenarios of integrated plants yield overall energy efficiencies of 59.8% (crude FT-fuel), 52.5% (MeOH) and 53.5% (DME), and production costs of 89, 128 and 113 EURMWh{sup -1} on fuel basis. The applied process design approach allows to evaluate the economic competitiveness compared to fossil fuels, to study the influence of the biomass and electricity price and to project for different plant capacities. Process integration reveals in particular potential energy savings and waste heat valorization. Based on this work, the most promising options for the polygeneration of fuel, power and heat will be determined in a future thermo-economic optimization. (author)

  13. Characterization and supply of coal based fuels. Volume 1, Final report and appendix A (Topical report)

    Energy Technology Data Exchange (ETDEWEB)

    1992-06-01

    Studies and data applicable for fuel markets and coal resource assessments were reviewed and evaluated to provide both guidelines and specifications for premium quality coal-based fuels. The fuels supplied under this contract were provided for testing of advanced combustors being developed under Pittsburgh Energy Technology Center (PETC) sponsorship for use in the residential, commercial and light industrial (RCLI) market sectors. The requirements of the combustor development contractors were surveyed and periodically updated to satisfy the evolving needs based on design and test experience. Available coals were screened and candidate coals were selected for further detailed characterization and preparation for delivery. A team of participants was assembled to provide fuels in both coal-water fuel (CWF) and dry ultrafine coal (DUC) forms. Information about major US coal fields was correlated with market needs analysis. Coal fields with major reserves of low sulfur coal that could be potentially amenable to premium coal-based fuels specifications were identified. The fuels requirements were focused in terms of market, equipment and resource constraints. With this basis, the coals selected for developmental testing satisfy the most stringent fuel requirements and utilize available current deep-cleaning capabilities.

  14. Clean Coal Technology Demonstration Program: Program Update 2001

    Energy Technology Data Exchange (ETDEWEB)

    Assistant Secretary for Fossil Energy

    2002-07-30

    Annual report on the Clean Coal Technology Demonstration Program (CCT Program). The report address the role of the CCT Program, implementation, funding and costs, accomplishments, project descriptions, legislative history, program history, environmental aspects, and project contacts. The project descriptions describe the technology and provides a brief summary of the demonstration results. Also includes Power Plant Improvement Initiative Projects.

  15. Clean Coal Technology Demonstration Program: Program Update 1998

    Energy Technology Data Exchange (ETDEWEB)

    Assistant Secretary for Fossil Energy

    1999-03-01

    Annual report on the Clean Coal Technology Demonstration Program (CCT Program). The report address the role of the CCT Program, implementation, funding and costs, accomplishments, project descriptions, legislative history, program history, environmental aspects, and project contacts. The project descriptions describe the technology and provides a brief summary of the demonstration results.

  16. Extraction process of fission products from spent nuclear fuel elements

    International Nuclear Information System (INIS)

    Process for extracting fission products contained in irradiated nuclear fuel elements consisting in bringing these elements into contact with water after having treated them mechanically to remove their cladding and/or cut them up, then separate these treated elements from the aqueous solution and recuperating at least one of the fission products concerned from this by concentrating it by distillation so as to obtain a concentrate containing these fission products and then processing this concentrate in order to ensure a long term storage of these fission products

  17. Novel Fuel Cells for Coal Based Systems

    Energy Technology Data Exchange (ETDEWEB)

    Thomas Tao

    2011-12-31

    The goal of this project was to acquire experimental data required to assess the feasibility of a Direct Coal power plant based upon an Electrochemical Looping (ECL) of Liquid Tin Anode Solid Oxide Fuel Cell (LTA-SOFC). The objective of Phase 1 was to experimentally characterize the interaction between the tin anode, coal fuel and cell component electrolyte, the fate of coal contaminants in a molten tin reactor (via chemistry) and their impact upon the YSZ electrolyte (via electrochemistry). The results of this work will provided the basis for further study in Phase 2. The objective of Phase 2 was to extend the study of coal impurities impact on fuel cell components other than electrolyte, more specifically to the anode current collector which is made of an electrically conducting ceramic jacket and broad based coal tin reduction. This work provided a basic proof-of-concept feasibility demonstration of the direct coal concept.

  18. Clean coal reference plants: Atmospheric CFB. Topical report, Task 1

    Energy Technology Data Exchange (ETDEWEB)

    Rubow, L.N.; Harvey, L.E.; Buchanan, T.L.; Carpenter, R.G.; Hyre, M.R.; Zaharchuk, R.

    1992-06-01

    The Clean Coal Technology Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the US energy marketplace with a number of advanced, more efficient and environmentally responsive coal-using technologies. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which correspond to the center`s areas of technology development, including atmospheric fluidized bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications. A measure of success in the CCT program will be the commercial acceptance of the new technologies being demonstrated. The dissemination of project information to potential users is being accomplished by producing a series of reference plant designs which will provide the users a basis for the selection of technologies applicable to their future energy requirements. As a part of DOE`s monitoring and evaluation of the CCT Projects, Gilbert/Commonwealth (G/C) has been contracted to assist in this effort by producing the design of a commercial size Reference Plant, utilizing technologies developed in the CCT Program. This report, the first in a series, describes the design of a 400 MW electric power plant, utilizing an atmospheric pressure, circulating fluidized bed combustor (ACFB) similar to the one which was demonstrated at Colorado-Ute`s Nucla station, funded in Round 1 of the CCT Program. The intent of the reference plant design effort was to portray a commercial power plant with attributes considered important to the utility industry. The logical choice for the ACFB combustor was Pyropower since they supplied the ACFB for the Nucla Project.

  19. Environmental control implications of generating electric power from coal. Appendix B. Assessment of status of technology for solvent refining of coal. 1977 technology status report

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-12-01

    This report reviews the technology and environmental impacts of the solvent refined coal process to produce clean solid fuel (SRC-I). Information on SRC-I pilot plant operation, process design, and economics is presented. A bibliography of current available literature in this technology area, divided into fourteen categories with abstracts of the references, is appended. The history, current operations, and future plans for the SRC pilot plants at Fort Lewis and Wilsonville are reviewed. Process data generated at these pilot plants for various coals are used as a basis for a conceptual commercial plant design with a capacity to process 20,000 tons per day (TPD) of prepared coal. Block flow diagrams, material balances, an energy balance, and a list of raw materials for the plant are also provided. Capital cost estimates for a 20,000 TPD coal feed plant derived from four prior economic studies range from $706 million to $1093 million in 1976 dollars. The annual net operating cost is estimated at $238.6 million (1976 dollars) and the average product cost at $2.71/MM Btu based on utility financing (equity 25:debt 75) with $25/ton as the delivered price of the dry coal. The report also discusses special technical considerations associated with some of the process operations and major equipment items and enumerates technical risks associated with the commercialization of the SRC-I process.

  20. Use of a Nuclear High Temperature Gas Reactor in a Coal-To-Liquids Process

    International Nuclear Information System (INIS)

    AREVA's High Temperature Gas Reactor (HTGR) can potentially provide nuclear-generated, high-level heat to chemical process applications. The use of nuclear heat to help convert coal to liquid fuels is particularly attractive because of concerns about the future availability of petroleum for vehicle fuels. This report was commissioned to review the technical and economic aspects of how well this integration might actually work. The objective was to review coal liquefaction processes and propose one or more ways that nuclear process heat could be used to improve the overall process economics and performance. Shell's SCGP process was selected as the gasifier for the base case system. It operates in the range of 1250 to 1600 C to minimize the formation of tars, oil, and methane, while also maximizing the conversion of the coal's carbon to gas. Synthesis gas from this system is cooled, cleaned, reacted to produce the proper ratio of hydrogen to carbon monoxide and fed to a Fischer-Tropsch (FT) reaction and product upgrading system. The design coal-feed rate of 18,800 ton/day produces 26.000 barrels/day of FT products. Thermal energy at approximately 850 C from a HTGR does not directly integrate into this gasification process efficiently. However, it can be used to electrolyze water to make hydrogen and oxygen, both of which can be beneficially used in the gasification/FT process. These additions then allow carbon-containing streams of carbon dioxide and FT tail-gas to be recycled in the gasifier, greatly improving the overall carbon recovery and thereby producing more FT fuel for the same coal input. The final process configuration, scaled to make the same amount of product as the base case, requires only 5,800 ton/day of coal feed. Because it has a carbon utilization of 96.9%, the process produces almost no carbon dioxide byproduct Because the nuclear-assisted process requires six AREVA reactors to supply the heat, the capital cost is high. The conventional plant is

  1. Appalachian Clean Coal Technology Consortium. Final report, October 10, 1994--March 31, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, R.H.; Parekh, B.K.; Meloy, T.

    1997-12-31

    The Appalachian Clean Coal Technology Consortium is a group comprised of representatives from the Virginia Polytechnic Institute and State University, West Virginia University, and the University of Kentucky Center for Applied Energy Research, that was formed to pursue research in areas related to the treatment and processing of fine coal. Each member performed research in their respective areas of expertise and the report contained herein encompasses the results that were obtained for the three major tasks that the Consortium undertook from October, 1994 through March, 1997. In the first task, conducted by Virginia Polytechnic Institute, novel methods (both mechanical and chemical) for dewatering fine coal were examined. In the second task, the Center for Applied Energy Research examined novel approaches for destabilization of [highly stable] flotation froths. And in the third task, West Virginia University developed physical and mathematical models for fine coal spirals. The Final Report is written in three distinctive chapters, each reflecting the individual member`s task report. Recommendations for further research in those areas investigated, as well as new lines of pursuit, are suggested.

  2. Production of synthetic fuels using syngas from a steam hydrogasification and reforming process

    Science.gov (United States)

    Raju, Arun Satheesh Kumar

    from carbonaceous feedstocks. Experimental work on the Fischer-Tropsch synthesis has also been performed. A life cycle analysis has been performed with the objective of comparing the life cycle energy consumption and emissions of synthetic diesel fuel produced through the CE-CERT process with other fuel/vehicle combinations. The experimental and simulation results presented here demonstrate that the CE-CERT process is versatile and can potentially handle a number of different feedstocks. CE-CERT process appears to be suitable for commercialization in very large scales with a coal feedstock and also in a distributed network of smaller scale reactors utilizing localized renewable feedstocks.

  3. Wabash River Coal Gasification Combined Cycle Repowering Project: Clean Coal Technology Program

    International Nuclear Information System (INIS)

    The proposed project would result in a combined-cycle power plant with lower emissions and higher efficiency than most existing coal-fired power plants of comparable size. The net plant heat rate (energy content of the fuel input per useable electrical generation output; i.e., Btu/kilowatt hour) for the new repowered unit would be a 21% improvement over the existing unit, while reducing SO2 emissions by greater than 90% and limiting NOx emissions by greater than 85% over that produced by conventional coal-fired boilers. The technology, which relies on gasified coal, is capable of producing as much as 25% more electricity from a given amount of coal than today's conventional coal-burning methods. Besides having the positive environmental benefit of producing less pollutants per unit of power generated, the higher overall efficiency of the proposed CGCC project encourages greater utilization to meet base load requirements in order to realize the associated economic benefits. This greater utilization (i.e., increased capacity factor) of a cleaner operating plant has global environmental benefits in that it is likely that such power would replace power currently being produced by less efficient plants emitting a greater volume of pollutants per unit of power generated

  4. Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications

    Energy Technology Data Exchange (ETDEWEB)

    Joseph Rabovitser

    2009-06-30

    , pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

  5. SUBTASK 3.12 – GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS PRODUCTION WITH ILLINOIS COAL

    Energy Technology Data Exchange (ETDEWEB)

    Stanislowski, Joshua; Curran, Tyler; Henderson, Ann

    2014-06-30

    The goal of this project was to evaluate the performance of Illinois No. 6 coal blended with biomass in a small-scale entrained-flow gasifier and demonstrate the production of liquid fuels under three scenarios. The first scenario used traditional techniques for cleaning the syngas prior to Fischer–Tropsch (FT) synthesis, including gas sweetening with a physical solvent. In the second scenario, the CO2 was not removed from the gas stream prior to FT synthesis. In the third scenario, only warm-gas cleanup techniques were used, such that the feed gas to the FT unit contained both moisture and CO2. The results of the testing showed that the liquid fuels production from the FT catalyst was significantly hindered by the presence of moisture and CO2 in the syngas. Further testing would be needed to determine if this thermally efficient process is feasible with other FT catalysts. This subtask was funded through the EERC–U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the Illinois Clean Coal Institute.

  6. Enzymantic Conversion of Coal to Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Richard Troiano

    2011-01-31

    The work in this project focused on the conversion of bituminous coal to liquid hydrocarbons. The major steps in this process include mechanical pretreatment, chemical pretreatment, and finally solubilization and conversion of coal to liquid hydrocarbons. Two different types of mechanical pretreatment were considered for the process: hammer mill grinding and jet mill grinding. After research and experimentation, it was decided to use jet mill grinding, which allows for coal to be ground down to particle sizes of 5 {mu}m or less. A Fluid Energy Model 0101 JET-O-MIZER-630 size reduction mill was purchased for this purpose. This machine was completed and final testing was performed on the machine at the Fluid Energy facilities in Telford, PA. The test results from the machine show that it can indeed perform to the required specifications and is able to grind coal down to a mean particle size that is ideal for experimentation. Solubilization and conversion experiments were performed on various pretreated coal samples using 3 different approaches: (1) enzymatic - using extracellular Laccase and Manganese Peroxidase (MnP), (2) chemical - using Ammonium Tartrate and Manganese Peroxidase, and (3) enzymatic - using the live organisms Phanerochaete chrysosporium. Spectral analysis was used to determine how effective each of these methods were in decomposing bituminous coal. After analysis of the results and other considerations, such as cost and environmental impacts, it was determined that the enzymatic approaches, as opposed to the chemical approaches using chelators, were more effective in decomposing coal. The results from the laccase/MnP experiments and Phanerochaete chrysosporium experiments are presented and compared in this final report. Spectra from both enzymatic methods show absorption peaks in the 240nm to 300nm region. These peaks correspond to aromatic intermediates formed when breaking down the coal structure. The peaks then decrease in absorbance over time

  7. New particle formation in the fresh flue-gas plume from a coal-fired power plant: effect of flue-gas cleaning

    Science.gov (United States)

    Mylläri, Fanni; Asmi, Eija; Anttila, Tatu; Saukko, Erkka; Vakkari, Ville; Pirjola, Liisa; Hillamo, Risto; Laurila, Tuomas; Häyrinen, Anna; Rautiainen, Jani; Lihavainen, Heikki; O'Connor, Ewan; Niemelä, Ville; Keskinen, Jorma; Dal Maso, Miikka; Rönkkö, Topi

    2016-06-01

    Atmospheric emissions, including particle number and size distribution, from a 726 MWth coal-fired power plant were studied experimentally from a power plant stack and flue-gas plume dispersing in the atmosphere. Experiments were conducted under two different flue-gas cleaning conditions. The results were utilized in a plume dispersion and dilution model taking into account particle formation precursor (H2SO4 resulted from the oxidation of emitted SO2) and assessment related to nucleation rates. The experiments showed that the primary emissions of particles and SO2 were effectively reduced by flue-gas desulfurization and fabric filters, especially the emissions of particles smaller than 200 nm in diameter. Primary pollutant concentrations reached background levels in 200-300 s. However, the atmospheric measurements indicated that new particles larger than 2.5 nm are formed in the flue-gas plume, even in the very early phases of atmospheric ageing. The effective number emission of nucleated particles were several orders of magnitude higher than the primary particle emission. Modelling studies indicate that regardless of continuing dilution of the flue gas, nucleation precursor (H2SO4 from SO2 oxidation) concentrations remain relatively constant. In addition, results indicate that flue-gas nucleation is more efficient than predicted by atmospheric aerosol modelling. In particular, the observation of the new particle formation with rather low flue-gas SO2 concentrations changes the current understanding of the air quality effects of coal combustion. The results can be used to evaluate optimal ways to achieve better air quality, particularly in polluted areas like India and China.

  8. Coal gasification technology. 1977-1978 (citations from the American Petroleum Institute data base). Report for 1977-78. [174 abstracts

    Energy Technology Data Exchange (ETDEWEB)

    Cavagnaro, D.M.

    1980-06-01

    This bibliography cites studies relating to the coal gasification processes. Topics include design, equipment used, performance, and cost analysis. Coal desulfurization, cleaning, or preparation, which do not involve conversion to fuels or chemicals, are not covered. (This updated bibliography contains 174 abstracts, none of which are new entries to the previous edition.)

  9. Coal cleaning residues and Fe-minerals implications.

    Science.gov (United States)

    Silva, Luis F O; Macias, Felipe; Oliveira, Marcos L S; da Boit, M Kátia; Waanders, Frans

    2011-01-01

    In the present investigation, a study was undertaken to understand the origin of Fe-minerals presents in Brazilian coal mining and to understand the environmental implication and the chemical heterogeneity in the study area. Coal cleaning residue samples rich in clays, quartz, sulphides, carbonates, sulphates, etc. were sampled from Lauro Muller, Urussanga, Treviso, Siderópolis, and Criciúma cities in the Santa Catarina State and a total of 19 samples were collected and Mössbauer, XRD, SEM/EDX, and TEM analyses were conducted on the samples. The major Fe-minerals identified are represented by the major minerals chlorite, hematite, illite, and pyrite, while the minor minerals include, ankerite, chalcopyrite, goethite, hematite, jarosite, maghemite, magnetie, marcasite, melanterite, natrojarosite, oligonite, pyrrhotite, rozenite, schwertmannite, siderite, and sideronatrile. Pyrite is relatively abundant in some cases, making up to around 10% of the mineral matter in several samples. The sulphates minerals such as jarosite and others, probably represent oxidation products of pyrite, developed during exposure or storage. PMID:20127406

  10. Ninth international conference on CANDU fuel, 'fuelling a clean future'

    International Nuclear Information System (INIS)

    The Canadian Nuclear Society's 9th International Conference on CANDU fuel took place in Belleville, Ontario on September 18-21, 2005. The theme for this year's conference was 'Fuelling a Clean Future' bringing together over 80 delegates ranging from: designers, engineers, manufacturers, researchers, modellers, safety specialists and managers to share the wealth of their knowledge and experience. This international event took place at an important turning point of the CANDU technology when new fuel design is being developed for commercial application, the Advanced CANDU Reactor is being considered for projects and nuclear power is enjoying a renaissance as the source energy for our future. Most of the conference was devoted to the presentation of technical papers in four parallel sessions. The topics of these sessions were: Design and Development; Fuel Safety; Fuel Modelling; Fuel Performance; Fuel Manufacturing; Fuel Management; Thermalhydraulics; and, Spent Fuel Management and Criticalty

  11. Coal-fueled diesel technology development -- Fuel injection equipment for coal-fueled diesel engines

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, R.N.; Hayden, H.L.

    1994-01-01

    Because of the abrasive and corrosive nature of coal water slurries, the development of coal-fueled diesel engine technology by GE-Transportation Systems (GE-TS) required special fuel injection equipment. GE-Corporate Research and Development (GE-CRD) undertook the design and development of fuel injectors, piston pumps, and check valves for this project. Components were tested at GE-CRD on a simulated engine cylinder, which included a cam-actuated jerk pump, prior to delivery to GE-TS for engine testing.

  12. Development of coal-based technologies for Department of Defense Facilities. Semiannual technical progress report, September 28, 1996--March 27, 1997

    Energy Technology Data Exchange (ETDEWEB)

    Miller, B.G.; Miller, S.F.; Pisupati, S.V. [and others

    1997-07-22

    The U.S. Department of Defense (DOD), through an Interagency Agreement with the U.S. Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Slurry Fuel Technology, with the aim of developing technologies which can potentially decrease DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Work in Phase III focused on coal preparation studies, pilot-scale NO{sub x} reduction studies, economic analyses of coal use, and evaluation of deeply-cleaned coal as boiler fuel. Coal preparation studies were focused on continuing activities on particle size control, physical separations, surface-based separation processes, and dry processing. Preliminary pilot-scale NO{sub x} reduction catalyst tests were conducted when firing natural gas in Penn State`s down-fired combustor. This is the first step in the scale-up of bench-scale results obtained in Phase II to the demonstration boiler scale when firing coal. The economic study focused on community sensitivity to coal usage, regional/national economic impacts of new coal utilization technologies, and constructing a national energy portfolio. The evaluation of deeply-cleaned coal as boiler fuel included installing a ribbon mixer into Penn State`s micronized coal-water mixture circuit for reentraining filter cake. In addition, three cleaned coals were received from CQ Inc. and three cleaned coals were received from Cyprus-Amax.

  13. Arrangement for cleaning and decontamination of fuel element transport containers

    International Nuclear Information System (INIS)

    The bottom of the transport container can be cleaned by a rotatory nozzle arrangement in connection with rotatory brushes. The cleaning arrangement of the reprocessing plant is located inside a splash guard jacket with a catch basin and above the opening in the transport plane of the transport container. The opening can be sealed from the transport container. Trough windows in the splash guard wall the personnel can control the cleaning process from a service platform. (DG)

  14. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO sub x ) emissions from coal-fired boilers

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-21

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company's Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as parameters such as particulate characteristics and boiler efficiency.

  15. Innovative Clean Coal Technology (ICCT): 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Technical progress report, fourth quarter 1991

    Energy Technology Data Exchange (ETDEWEB)

    1992-04-21

    This quarterly report discusses the technical progress of an Innovative Clean Coal Technology (ICCT) demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. The project is being conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The primary goal of this project is the characterization of the low NO{sub x} combustion equipment through the collection and analysis of long-term emissions data. A target of achieving fifty percent NO{sub x} reduction using combustion modifications has been established for the project. The project provides a stepwise retrofit of an advanced overfire air (AOFA) system followed by low NO{sub x} burners (LNB). During each test phase of the project, diagnostic, performance, long-term, and verification testing will be performed. These tests are used to quantify the NO{sub x} reductions of each technology and evaluate the effects of those reductions on other combustion parameters such as parameters such as particulate characteristics and boiler efficiency.

  16. Economic comparison of clean coal generating technologies with natural gas-combined cycle systems

    International Nuclear Information System (INIS)

    This paper reports that there are four combustion technologies upon which U.S. electric utilities are expected to rely for the majority of their future power generating needs. These technologies are pulverized coal- fired combustion (PC); coal-fired fluidized bed combustion (AFBC); coal gasification, combined cycle systems (CGCC); and natural gas-fired combined cycle systems (NGCC). The engineering and economic parameters which affect the choice of a technology include capital costs, operating and maintenance costs, fuel costs, construction schedule, process risk, environmental and site impacts, fuel efficiency and flexibility, plant availability, capacity factors, timing of startup, and the importance of utility economic and financial factors

  17. Effect of syngas and coal composition of performance of solid oxide fuel cell

    International Nuclear Information System (INIS)

    Gasification technology includes the conversion of fossil fuels into either combustible gas or synthesis gas (syngas) for subsequent utilization. It finds its applications in the productions of clean power as well as chemicals. Coal is one of the world's important source of energy fueling around 40% of the power stations around the world. It is commonly agreed that coal pits will be mined more intensively and in more numbers in the coming years and that lignite and hard coals will be the major energy suppliers until 2100. Integrated gasification fuel cell hybrid power generation system is a promising system for coal utilization. It combines clean coal gasification technology with efficient fuel cell technology. In this paper , effect of syngas and coal composition on performance of solid oxide fuel cell was studied. It was observed that different ratios of H2 and CO affect the current and voltage fuel cell. With higher molar fraction of H2 the better output voltage was obtained under the same working conditions. The trace species in coal also affect the performance of solid oxide fuel cell. Ni, Be, Cr, K and Na trace species present in coal also affect the performance to some extent. (author)

  18. Hydrometallurgical-UV process to produce ferrous sulfate from the pyrite present in coal tailings

    International Nuclear Information System (INIS)

    The oxidation of pyrite can promote acid mine drainage (AMD). This study developed a hydrometallurgical-UV route for the production of ferrous sulfate. The laboratory study was conducted using a pyrite concentrate obtained from a processed coal tailing. Leaching of the tailing was performed in packed bed columns in an oxidizing environment with an aqueous medium. Recirculation of the liquor produced an Fe3+ iron rich extract. Ultraviolet irradiation was then used to convert the Fe3+ to Fe2+. Heat provided by the UV lamps caused the ferrous sulfate to crystallize. X-ray diffraction (XRD) studies of the crystals demonstrated that it is possible to produce commercial-grade ferrous sulfate heptahydrate crystals from the pyrite present in coal tailings. The crystals are used to treat anemia in humans and animals, and are also used as reagents for waste and waste water treatment. 7 refs., 2 tabs., 2 figs.

  19. Determination of Sectional Constancy of Organic Coal-Water Fuel Compositions

    Science.gov (United States)

    Dmitrienko, Margarita A.; Nyashina, Galina S.; Strizhak, Pavel A.

    2016-02-01

    To use widespreadly the waste of coals and oils processing in the great and the small-scale power generation, the key parameter, which is sectional constancy of promising organic coal-water fuels (OCWF), was studied. The compo-sitions of OCWF from brown and bituminous coals, filter cakes, used motor, turbine and dielectrical oils, water-oil emul-sion and special wetting agent (plasticizer) were investigated. Two modes of preparation were considered. They are with homogenizer and cavitator. It was established that the constancy did not exceed 5-7 days for the compositions of OCWF with brown coals, and 12-15 days for that compositions with bituminous coals and filter cakes. The injection of used oils in a composition of OCWF led to increase in viscosity of fuel compositions and their sectional constancy.

  20. A Systematic Analysis of Coal Accumulation Process

    Institute of Scientific and Technical Information of China (English)

    CHENG Aiguo

    2008-01-01

    Formation of coal seam and coal-rich zone is an integrated result of a series of factors in coal accumulation process. The coal accumulation system is an architectural aggregation of coal accumulation factors. It can be classified into 4 levels: the global coal accumulation super-system, the coal accumulation domain mega.system, the coal accumulation basin system, and the coal seam or coal seam set sub-system. The coal accumulation process is an open, dynamic, and grey system, and is meanwhile a system with such natures as aggregation, relevance, entirety, purpose-orientated, hierarchy, and environment adaptability. In this paper, we take coal accumulation process as a system to study origin of coal seam and coal-rich zone; and we will discuss a methodology of the systematic analysis of coal accumulation process. As an example, the Ordos coal basin was investigated to elucidate the application of the method of the coal accumulation system analysis.

  1. The perspectives of energy production from coal-fired power plants in an enlarged EU

    International Nuclear Information System (INIS)

    The aim of this paper is to present the current status of the coal-fired power sector in an enlarged EU (EU-15 plus EU member candidate states) in relation with the main topics of the European Strategy for the energy production and supply. It is estimated that 731 thermoelectric units, larger than 100 MWe, are operating nowadays, and their total installed capacity equals to 200.7 GWe. Coal contribution to the total electricity generation with reference to other fuel sources, is far more intensive in the non-EU part (EU member candidate states), compared to the EU member states. It is expected that even after the enlargement, the European Union will strongly relate to coal. Enlargement will bring additional factors into play in order to meet the requirements of rising consumption, growing demand for conventional fuels and increasing dependence on imports. Besides the technology, boiler size, efficiency, age and environmental performance will determine the necessities of the coal-fired power sector in each country. Depending on the case, lifetime extension measures in operating coal-fired power plants or clean coal technologies can play an important role towards the energy sector restructuring. Low efficiency values in the non-EU coal-fired units and heavily aged power plants in EU countries will certainly affect decisions in favour of upgrading or reconstruction. The overall increase of efficiency, the reduction of harmful emissions from generating processes and the co-combustion of coal with biomass and wastes for generating purposes indicate that coal can be cleaner and more efficient. Additionally, plenty of rehabilitation projects based on CCT applications, have already been carried out or are under progress in the EU energy sector. The proclamations of the countries' energy policies in the coming decades, includes integrated renovation concepts of the coal-fired power sector. Further to the natural gas penetration in the electricity generation and CO2

  2. Optimal process design for thermochemical production of fuels from biomass

    OpenAIRE

    Gassner, Martin; Maréchal, François

    2008-01-01

    Transport applications are a major global source of greenhouse gas emissions and the production of fuels that are renewable and neutral in CO2 is an important issue in chemical process research and development. Contrary to the biological routes that produce bioethanol and -diesel on industrial scale through fermentation or esterification, 2nd generation biofuels obtained through thermochemical processing of lignocellulosic and waste biomass by means of gasification and fuel reforming are expe...

  3. Coal atlas. Data and facts about a global fuel

    International Nuclear Information System (INIS)

    Germany is world champion. In the production of lignite. But not only the brown coal, the coal leaves traces to. A quarter of German greenhouse gas emissions are discharged from the 30 largest coal-fired plants. But with its hunger for coal Germany neither in Europe nor in the world ist not alone. The governments of the 20 largest industrial countries subsidize the search for new fossil fuels each year with many billion dollars, although these projects have no future. In addition, there is the partly dramatic damage to the air, on the environment and on humans. Above all reports the Coal Atlas. It is published at a time, in which in Germany is an intense debate in progress about the future of this energy sector. In fact, it comes to the phasing out of coal for generating elektricity. The coal Atlas shows in understandable texts with illustrative graphics: This is technically possible and necessary.

  4. Power generation from solid fuels

    CERN Document Server

    Spliethoff, Hartmut

    2010-01-01

    Power Generation from Solid Fuels introduces the different technologies to produce heat and power from solid fossil (hard coal, brown coal) and renewable (biomass, waste) fuels, such as combustion and gasification, steam power plants and combined cycles etc. The book discusses technologies with regard to their efficiency, emissions, operational behavior, residues and costs. Besides proven state of the art processes, the focus is on the potential of new technologies currently under development or demonstration. The main motivation of the book is to explain the technical possibilities for reduci

  5. Production of synthetic liquid fuel from run-of-mine oil shales, brown coals and waste of petrochemical and chemical industry

    International Nuclear Information System (INIS)

    Modern and perspective technologies have been developed for processing run-of-mine oil shales into liquid products foreseen for producing motor fuels and chemical feedstock. Baltic run-of-mine oil shales, high-sulfur oil shales of the Volga basin, brown coals of Kansk-Atchinsk basin, as well as heavy crude oils and oil-bearing sands, solid waste of petrochemical and chemical industry may be processed. The proposed high-efficiency technology enables to produce high yields of naphtha (gasoline fraction) and diesel fuel fraction, feedstock for catalytic and hydro cracking processes, electrode coke, different adhesive materials, refractories, anodic mass, phenols, individual hydrocarbons, Ni- and V- concentrates. The process proposed is carried out using oil shales. Their organic matter has unique hydrogen donor properties which enable them to activate the thermal conversion of brown coals, high-boiling waste of petrochemical industry etc. This complex technology is based on the thermochemical conversion process of oil shales in the hydro carbonic solvent at 333-440 deg C, under the pressure of 3-5 MPa, and volumetric rate 3-6 h-1. A paste-forming substance boiling between 200-340 deg C is used as the medium. The process runs with a deficiency (up to 30 %) of regenerated paste-forming substance and therefore respective measures have been worked out to intensify the process. It enabled to close the process with respect to regenerated paste-forming substance and to design new routes for thermochemical processing of oil shales. These procedures have the following essential advantages: 1.There is no need for previous separation of asphaltenes and metals (Ni, V) from heavy petrochemical feedstock as they precipitate on the mineral part of oil shales and are discharged together with liquid products of the process. 2. Thermal cracking is carried out without molecular hydrogen and thermal hydro cracking without catalysts. 3. Raw material is considerably desulfurized.(author)

  6. Alpha Removal Process Filter Cleaning Recommendations

    International Nuclear Information System (INIS)

    The Savannah River Site (SRS) is developing a process to treat radioactive waste that is low in cesium-137, but high in strontium-90, plutonium, uranium, and neptunium. Defense Waste Processing Facility (DWPF) personnel asked Savannah River Technology Center (SRTC) personnel to provide recommendations for chemically cleaning the Alpha Removal Process filters. The authors reviewed previous SRTC filter cleaning experience with bench-scale radioactive filters and pilot-scale simulant filters from tests with simulated and actual waste. From reviewing the previous filter cleaning data and assuming the heel in the 512-S filtration system is 85 gallons or less, the authors recommendations and approach to the inquiry are contained in this report

  7. Toxicologic studies of emissions from coal gasification process. I. Subchronic feeding studies.

    Science.gov (United States)

    Kostial, K; Kello, D; Blanusa, M; Maljković, T; Rabar, I; Bunarević, A; Stara, J F

    1980-09-01

    The increasing use of new sources of energy may result in additional contamination of the human environment with inorganic and organic pollutants which are not yet adequately investigated with regard to their potential impact on human health. However, some evidence exists that several trace inorganic and organic contaminants found in coal processing residues may constitute potential health problems. Therefore, the comparative biological hazards of solid wastes and effluents from a Lurgi coal gasification plant were initially evaluated using acute and chronic feeding experiments in male and female rats. In the subchronic experiment, six-week old animals were fed diets wih various levels of ash (slag) additive (0.5%, 1%, and 5%) for period of 16 weeks. Following exposure, blood samples were taken and 22-hour urine samples were collected. Livers and kidneys, and testicles in males, were taken for trace element analysis or histologic examination. The urinary values, erythrocyte and leucocyte count, hemoglobin, packed cell volume, and concentration of trace elements in exposed animals were determined. The addition of ash (slag) to the diet in concentrations much higher than expected in conditions of environmental contamination had no measurable health effects. Although these initial results obtained in relatively short-term experiments cannot be directly extrapolated to human health effects, particularly not for carcinogenic assessment, there is an indication that exposure to solid wastes from the coal gasification plant may not be toxic. PMID:7462912

  8. Process for the production of hydrogen and electricity from carbonaceous fuels and process heat

    International Nuclear Information System (INIS)

    This patent application concerns the simultaneous production of hydrogen and electricity from carbonaceous fuels and process heat. An acid formed from a non-metallic oxide or a mixture of a halogen and water are used as the oxygen carrier for the combustion of the carbonaceous fuel at a high pressure. The combustion gases are pressure relieved in a turbine to generate electricity. The chemical components required for forming the initial material (acid or mixture of water and halogen) are separated from the waste gas. These processes have distinct advantages compared with previously introduced processes for producing hydrogen and electricity. (orig.)

  9. The Healy Clean Coal Project: Design verification tests

    International Nuclear Information System (INIS)

    As part of the Healy Clean Coal Project, TRW Inc., the supplier of the advanced slagging coal combustors, has successfully completed design verification tests on the major components of the combustion system at its Southern California test facility. These tests, which included the firing of a full-scale precombustor with a new non-storage direct coal feed system, supported the design of the Healy combustion system and its auxiliaries performed under Phase 1 of the project. Two 350 million BTU/hr combustion systems have been designed and are now ready for fabrication and erection, as part of Phase 2 of the project. These systems, along with a back-end Spray Dryer Absorber system, designed and supplied by Joy Technologies, will be integrated with a Foster Wheeler boiler for the 50 MWe power plant at Healy, Alaska. This paper describes the design verification tests and the current status of the project

  10. Characteristics of American coals in relation to their conversion into clean energy fuels. Quarterly technical progress report, January--March 1976. [2 appendices; 19 refs. Dryflo separation tests data

    Energy Technology Data Exchange (ETDEWEB)

    Spackman, W.; Davis, A.; Walker, P. L.; Lovell, H. L.; Essenhigh, R. H.; Vastola, F. J.; Given, P. H.

    1976-05-01

    Responses to the questionnaire, which was distributed to determine the extent to which the nation's coal seams have been sampled and characterized, are being received. Early comparisons indicate a mathematical relationship between average random reflectance (Rapid Scan) and the mean-maximum reflectance as obtained by standard reflectance analysis. Results obtained so far show support of a diffusion dominance mechanism in the oxidation region of a combustion pot and a chemical kinetic mechanism in the gasification region. Values of reaction rates in coke beds have been calculated from experiments with a fixed bed shaft gasifier. Devolatilization of a North Dakota lignite in a laminar flow reactor and subsequent treatment of the resulting char has shown that weight loss is strongly dependent upon the isothermal decomposition time. Although gasification rates increase with increase in partial pressure of oxygen, the mechanism for gasification of a given char is independent of partial pressure of oxygen. Study of the reactivity of ion-exchanged lignite chars to steam shows that increased heat treatment decreases reactivity and ion exchange increases reactivity. Use of the DSC technique to study the thermal effects involved during chemisorption of oxygen on Saran carbon has yielded information on the activation energy (EA) of the reaction. Work on the infinite parallel plane char combustion computer model has determined that low volatile chars and coals can be suitable fuels if adequate available internal surface area is present.

  11. Dispersed catalysts for co-processing and coal liquefaction

    Energy Technology Data Exchange (ETDEWEB)

    Bockrath, B.; Parfitt, D.; Miller, R. [Pittsburgh Energy Technology Center, PA (United States)

    1995-12-31

    The basic goal is to improve dispersed catalysts employed in the production of clean fuels from low value hydrocarbons. The immediate objective is to determine how the properties of the catalysts may be altered to match the demands placed on them by the properties of the feedstock, the qualities of the desired end products, and the economic constraints put upon the process. Several interrelated areas of the application of dispersed catalysts to co-processing and coal conversion are under investigation. The first involves control of the selectivity of MoS{sub 2} catalysts for HDN, HDS, and hydrogenation of aromatics. A second area of research is the development and use of methods to evaluate dispersed catalysts by means of activity and selectivity tests. A micro-flow reactor has been developed for determining intrinsic reactivities using model compounds, and will be used to compare catalysts prepared in different ways. Micro-autoclaves will also be used to develop data in batch experiments at higher partial pressures of hydrogen. The third area under investigation concerns hydrogen spillover reactions between MoS{sub 2} catalysts and carbonaceous supports. Preliminary results obtained by monitoring H{sub 2}/D{sub 2} exchange reactions with a pulse-flow microreactor indicate the presence of spillover between MoS{sub 2} and a graphitic carbon. A more complete study will be made at a later stage of the project. Accomplishments and conclusions are discussed.

  12. Process for electrochemically gasifying coal using electromagnetism

    Science.gov (United States)

    Botts, Thomas E.; Powell, James R.

    1987-01-01

    A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

  13. Air toxic emissions from the combustion of coal: Identifying and quantifying hazardous air pollutants from US coals

    International Nuclear Information System (INIS)

    This report addresses the key air toxic emissions likely to emanate from continued and expanded use of domestic coal. It identifies and quantifies those trace elements specified in the US 1990 Clean Air Act Amendments, by tabulating selected characterization data on various source coals by region, state, and rank. On the basis of measurements by various researchers, this report also identifies those organic compounds likely to be derived from the coal combustion process (although their formation is highly dependent on specific boiler configurations and operating conditions)

  14. Air toxic emissions from the combustion of coal: Identifying and quantifying hazardous air pollutants from US coals

    Energy Technology Data Exchange (ETDEWEB)

    Szpunar, C.B.

    1992-09-01

    This report addresses the key air toxic emissions likely to emanate from continued and expanded use of domestic coal. It identifies and quantifies those trace elements specified in the US 1990 Clean Air Act Amendments, by tabulating selected characterization data on various source coals by region, state, and rank. On the basis of measurements by various researchers, this report also identifies those organic compounds likely to be derived from the coal combustion process (although their formation is highly dependent on specific boiler configurations and operating conditions).

  15. Coal-fueled diesel engines for locomotive applications

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, B.D.; Najewicz, D.J.; Cook, C.S.

    1993-11-01

    GE Transportation Systems (GE/TS) completed a two and one half year study into the economic viability of a coal fueled locomotive. The coal fueled diesel engine was deemed to be one of the most attractive options. Building on the BN-NS study, a proposal was submitted to DOE to continue researching economic and technical feasibility of a coal fueled diesel engine for locomotives. The contract DE-AC21-85MC22181 was awarded to GE Corporate Research and Development (GE/CRD) for a three year program that began in March 1985. This program included an economic assessment and a technical feasibility study. The economic assessment study examined seven areas and their economic impact on the use of coal fueled diesels. These areas included impact on railroad infrastructure, expected maintenance cost, environmental considerations, impact of higher capital costs, railroad training and crew costs, beneficiated coal costs for viable economics, and future cost of money. The results of the study indicated the merits for development of a coal-water slurry (CWS) fueled diesel engine. The technical feasibility study examined the combustion of CWS through lab and bench scale experiments. The major accomplishments from this study have been the development of CWS injection hardware, the successful testing of CWS fuel in a full size, single cylinder, medium speed diesel engine, evaluation of full scale engine wear rates with metal and ceramic components, and the characterization of gaseous and particulate emissions.

  16. Innovative clean coal technology: 500 MW demonstration of advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. Final report, Phases 1 - 3B

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-01-01

    This report presents the results of a U.S. Department of Energy (DOE) Innovative Clean Coal Technology (ICCT) project demonstrating advanced wall-fired combustion techniques for the reduction of nitrogen oxide (NOx) emissions from coal-fired boilers. The project was conducted at Georgia Power Company`s Plant Hammond Unit 4 located near Rome, Georgia. The technologies demonstrated at this site include Foster Wheeler Energy Corporation`s advanced overfire air system and Controlled Flow/Split Flame low NOx burner. The primary objective of the demonstration at Hammond Unit 4 was to determine the long-term effects of commercially available wall-fired low NOx combustion technologies on NOx emissions and boiler performance. Short-term tests of each technology were also performed to provide engineering information about emissions and performance trends. A target of achieving fifty percent NOx reduction using combustion modifications was established for the project. Short-term and long-term baseline testing was conducted in an {open_quotes}as-found{close_quotes} condition from November 1989 through March 1990. Following retrofit of the AOFA system during a four-week outage in spring 1990, the AOFA configuration was tested from August 1990 through March 1991. The FWEC CF/SF low NOx burners were then installed during a seven-week outage starting on March 8, 1991 and continuing to May 5, 1991. Following optimization of the LNBs and ancillary combustion equipment by FWEC personnel, LNB testing commenced during July 1991 and continued until January 1992. Testing in the LNB+AOFA configuration was completed during August 1993. This report provides documentation on the design criteria used in the performance of this project as it pertains to the scope involved with the low NOx burners and advanced overfire systems.

  17. Gaseous emissions from coal stockpiles

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-01-15

    Stockpiled coal undergoes atmospheric oxidation and desorption processes during open air storage. These processes release gases to the environment which may effect health and safety by their toxicity and flammability. In extreme cases, this could lead to a fire. This report discusses gaseous emissions from coal stockpiles. It covers gas emission mechanisms, and gas sampling and testing methods, before examining in more detail the principal gases that have been emitted. It concludes that there is limited research in this area and more data are needed to evaluate the risks of gaseous emissions. Some methods used to prevent coal self-heating and spontaneous combustion can be applied to reduce emissions from coal stockpiles.

  18. Production of Biodiesel Fuel from Waste Soya bean Cooking Oil by Alkali Trans-esterification Process

    Directory of Open Access Journals (Sweden)

    Ajinkya Dipak Deshpande*,

    2016-04-01

    Full Text Available Biodiesel is biodegradable, clean-burning, non-toxic, renewable, high-quality, and cheap diesel fuel made primarily from waste vegetable oil which can be used without any alterations in engine design. The paper is concerned with the extraction and quality evaluation of the biodiesel fuels synthesized from waste soya bean cooking oil. Waste soya bean cooking oil had high amount of free fatty acid. Thus, single step transesterification process with the aid of homogeneous catalyst as 1% potassium hydroxide were implemented in this experiment. Methanol was chosen as alcohol solvent. In the transesterification process, the triglycerides in waste cooking oil was reacted with a methanol to form esters and glycerol as by product.The biodiesel were extracted for different oil to methanol ratio as 1:2, 1:3 and 1:4. The highest biodiesel yield of 76% was obtained at 1:3 volumetric ratio for 60 ºC reaction temperature and 1250 rpm stirring speed. Results show that the optimal methyl ester yield of 90% occurred at methanol: oil volume ratio of 3:1. The product met the ASTM fuel standards for relative density, acid value, relative density, calorific value, flash point and kinematic viscosity.

  19. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    International Nuclear Information System (INIS)

    It is the objective of the project to further develop the triboelectrostatic separation (TES) process developed at the Federal Energy Technology Center (FETC) and to test the process at a proof-of-concept (POC) scale. This process has a distinct advantage over other coal cleaning processes in that it does not entail costly steps of dewatering. The POC-scale unit is to be developed based on (i) the charging characteristics of coal and mineral matter that can be determined using the novel on-line tribocharge measuring device developed at Virginia Tech and (ii) the results obtained from bench-scale TES tests conducted on three different coals. During the past quarter, most of the personnel assigned to this project have been performing work elements associated with the engineering design (Task 3) of the TES process. This activity has been subdivided into three subtasks, i.e., Charger Tests (Subtask 3.1), Separator Tests (Subtask 3.2), and Final POC Design (Subtask 3.3). In Subtask 3.1, several different tribocharging devices have been constructed using materials of various work functions. They are currently being tested to establish the best materials to be used for designing and manufacturing the optimum tribochargers that can maximum charge differences between coal and mineral matter. In Subtask 3.2, bench-scale cleaning tests have been conducted to study the effects of the various operating and design parameters on the performance of the electrostatic separator. Two different TES units have been tested to date. One uses drum-type electrodes to separate charged particles, while the other uses plate-type electrodes for the separation. The test results showed that a major improvement in separation efficiency can be achieved by recycling the middlings back to the feed stream. It has also been established that the major source of inefficiency arises from the difficulty in separating ultrafine particles. Understanding the behavior of the ultrafine particles and finding

  20. LESSONS LEARNED FROM CLEANING OUT THE SLUDGE FROM THE SPENT FUEL STORAGE BASINS AT HANFORD ICEM-07

    International Nuclear Information System (INIS)

    Until 2004, the K Basins at Hanford, in southeastern Washington State, held the largest collection of spent nuclear fuel in the United States Department of Energy (DOE) complex. The K East and K West Basins are massive pools each holding more than 4 million liters of water - that sit less than 450 meters from the Columbia River. In a significant multi-year campaign that ended in 2004, Fluor Hanford removed all of the fuel from the two Basins, over 2,300 metric tons (4.6 million pounds), dried it, and then placed it into dry storage in a specially designed facility away from the River. Removing the fuel, however, did not finish the cleanup work at the K Basins. The years of underwater storage had corroded the metallic uranium fuel, leaving behind a thick and sometimes hard-packed layer of sludge that coated the walls, floors and equipment inside the Basins. In places, the depth of the sludge was measured in feet rather than inches, and its composition was definitely not uniform. Together the Basins held an estimated 50 cubic meters of sludge (42 cubic meters in K East and 8 cubic meters in K West). The K East sludge retrieval and transfer work was completed in May 2007. Vacuuming up the sludge into large underwater containers in each of the Basins and then consolidating it all in containers in the K West Basin have presented significant challenges, some unexpected. This paper documents some of those challenges and presents the lessons learned so that other nuclear cleanup projects can benefit from the experience at Hanford

  1. LESSONS LEARNED FROM CLEANING OUT THE SLUDGE FROM THE SPENT FUEL STORAGE BASINS AT HANFORD ICEM-07

    Energy Technology Data Exchange (ETDEWEB)

    KNOLLMEYER PM

    2007-08-31

    Until 2004, the K Basins at Hanford, in southeastern Washington State, held the largest collection of spent nuclear fuel in the United States Department of Energy (DOE) complex. The K East and K West Basins are massive pools each holding more than 4 million liters of water - that sit less than 450 meters from the Columbia River. In a significant multi-year campaign that ended in 2004, Fluor Hanford removed all of the fuel from the two Basins, over 2,300 metric tons (4.6 million pounds), dried it, and then placed it into dry storage in a specially designed facility away from the River. Removing the fuel, however, did not finish the cleanup work at the K Basins. The years of underwater storage had corroded the metallic uranium fuel, leaving behind a thick and sometimes hard-packed layer of sludge that coated the walls, floors and equipment inside the Basins. In places, the depth of the sludge was measured in feet rather than inches, and its composition was definitely not uniform. Together the Basins held an estimated 50 cubic meters of sludge (42 cubic meters in K East and 8 cubic meters in K West). The K East sludge retrieval and transfer work was completed in May 2007. Vacuuming up the sludge into large underwater containers in each of the Basins and then consolidating it all in containers in the K West Basin have presented significant challenges, some unexpected. This paper documents some of those challenges and presents the lessons learned so that other nuclear cleanup projects can benefit from the experience at Hanford.

  2. An environmentally-friendly vacuum reduction metallurgical process to recover germanium from coal fly ash.

    Science.gov (United States)

    Zhang, Lingen; Xu, Zhenming

    2016-07-15

    The demand for germanium in the field of semiconductor, electronics, and optical devices is growing rapidly; however, the resources of germanium are scarce worldwide. As a secondary material, coal fly ash could be further recycled to retrieve germanium. Up to now, the conventional processes to recover germanium have two problems as follows: on the one hand, it is difficult to be satisfactory for its economic and environmental effect; on the other hand, the recovery ratio of germanium is not all that could be desired. In this paper, an environmentally-friendly vacuum reduction metallurgical process (VRMP) was proposed to recover germanium from coal fly ash. The results of the laboratory scale experiments indicated that the appropriate parameters were 1173K and 10Pa with 10wt% coke addition for 40min, and recovery ratio germanium was 93.96%. On the basis of above condition, the pilot scale experiments were utilized to assess the actual effect of VRMP for recovery of germanium with parameter of 1473K, 1-10Pa and heating time 40min, the recovery ratio of germanium reached 94.64%. This process considerably enhances germanium recovery, meanwhile, eliminates much of the water usage and residue secondary pollution compared with other conventional processes. PMID:27015376

  3. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    Energy Technology Data Exchange (ETDEWEB)

    Paul A. Erickson

    2005-09-30

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the eighth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2004-September 30, 2005 and includes an entire review of the progress for year 2 of the project. This year saw progress in eight areas. These areas are: (1) steam reformer transient response, (2) steam reformer catalyst degradation, (3) steam reformer degradation tests using bluff bodies, (4) optimization of bluff bodies for steam reformation, (5) heat transfer enhancement, (6) autothermal reforming of coal derived methanol, (7) autothermal catalyst degradation, and (8) autothermal reformation with bluff bodies. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  4. Modules for estimating solid waste from fossil-fuel technologies

    International Nuclear Information System (INIS)

    Solid waste has become a subject of increasing concern to energy industries for several reasons. Increasingly stringent air and water pollution regulations result in a larger fraction of residuals in the form of solid wastes. Control technologies, particularly flue gas desulfurization, can multiply the amount of waste. With the renewed emphasis on coal utilization and the likelihood of oil shale development, increased amounts of solid waste will be produced. In the past, solid waste residuals used for environmental assessment have tended only to include total quantities generated. To look at environmental impacts, however, data on the composition of the solid wastes are required. Computer modules for calculating the quantities and composition of solid waste from major fossil fuel technologies were therefore developed and are described in this report. Six modules have been produced covering physical coal cleaning, conventional coal combustion with flue gas desulfurization, atmospheric fluidized-bed combustion, coal gasification using the Lurgi process, coal liquefaction using the SRC-II process, and oil shale retorting. Total quantities of each solid waste stream are computed together with the major components and a number of trace elements and radionuclides

  5. Modules for estimating solid waste from fossil-fuel technologies

    Energy Technology Data Exchange (ETDEWEB)

    Crowther, M.A.; Thode, H.C. Jr.; Morris, S.C.

    1980-10-01

    Solid waste has become a subject of increasing concern to energy industries for several reasons. Increasingly stringent air and water pollution regulations result in a larger fraction of residuals in the form of solid wastes. Control technologies, particularly flue gas desulfurization, can multiply the amount of waste. With the renewed emphasis on coal utilization and the likelihood of oil shale development, increased amounts of solid waste will be produced. In the past, solid waste residuals used for environmental assessment have tended only to include total quantities generated. To look at environmental impacts, however, data on the composition of the solid wastes are required. Computer modules for calculating the quantities and composition of solid waste from major fossil fuel technologies were therefore developed and are described in this report. Six modules have been produced covering physical coal cleaning, conventional coal combustion with flue gas desulfurization, atmospheric fluidized-bed combustion, coal gasification using the Lurgi process, coal liquefaction using the SRC-II process, and oil shale retorting. Total quantities of each solid waste stream are computed together with the major components and a number of trace elements and radionuclides.

  6. Methodology and a preliminary data base for examining the health risks of electricity generation from uranium and coal fuels

    Energy Technology Data Exchange (ETDEWEB)

    El-Bassioni, A.A.

    1980-08-01

    An analytical model was developed to assess and examine the health effects associated with the production of electricity from uranium and coal fuels. The model is based on a systematic methodology that is both simple and easy to check, and provides details about the various components of health risk. A preliminary set of data that is needed to calculate the health risks was gathered, normalized to the model facilities, and presented in a concise manner. Additional data will become available as a result of other evaluations of both fuel cycles, and they should be included in the data base. An iterative approach involving only a few steps is recommended for validating the model. After each validation step, the model is improved in the areas where new information or increased interest justifies such upgrading. Sensitivity analysis is proposed as the best method of using the model to its full potential. Detailed quantification of the risks associated with the two fuel cycles is not presented in this report. The evaluation of risks from producing electricity by these two methods can be completed only after several steps that address difficult social and technical questions. Preliminary quantitative assessment showed that several factors not considered in detail in previous studies are potentially important. 255 refs., 21 figs., 179 tabs.

  7. Krakow clean fossil fuels and energy efficiency project

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, B.L.; Butcher, T.A.

    1994-06-01

    Almost half of the energy used for beating in Krakow is supplied by low-efficiency boilerhouses and home coal stoves. Within the town, there are more than 1,300 boilerhouses with a total capacity of 1,071 MW, and about 100,000 home furnaces with a total capacity of about 300 MW. More than 600 boilerhouses and 60 percent of the home furnaces are situated near the city center. These facilities are referred to as ``low emission sources`` because they have low stacks. They are the primary sources of particulates and hydrocarbons in the city, and major contributors of sulfur dioxide and carbon monoxide. The Support for Eastern European Democracy (SEED) Act of 1989 directed the US Department of Energy (DOE) to undertake an equipment assessment project aimed at developing the capability within Poland to manufacture or modify industrial-scale combustion equipment to utilize fossil fuels cleanly. This project is being implemented in Krakow as the ``Krakow Clean Fossil Fuels and Energy Efficiency Project.`` Funding is provided through the US Agency for International Development (AID). The project is being conducted in a manner that can be generalized to all of Poland and to the rest of Eastern Europe.

  8. Krakow clean fossil fuels and energy efficiency project

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, T.A.; Pierce, B.L. [Brookhaven National Lab., Upton, NY (United States)

    1995-11-01

    The Support for Eastern European Democracy (SEED) Act of 1989 directed the U.S. Department of Energy (DOE) to undertake an equipment assessment project aimed at developing the capability within Poland to manufacture or modify industrial-scale combustion equipment to utilize fossil fuels cleanly. This project is being implemented in the city of Krakow as the `Krakow Clean Fossil Fuels and Energy Efficiency Project.` Funding is provided through the U.S. Agency for International Development (AID). The project is being conducted in a manner that can be generalized to all of Poland and to the rest of Eastern Europe. The historic city of Krakow has a population of 750,000. Almost half of the heating energy used in Krakow is supplied by low-efficiency boilerhouses and home coal stoves. Within the town, there are more than 1,300 local boilerhouses and 100,000 home stoves. These are collectively referred to as the `low emission sources` and they are the primary sources of particulates and hydrocarbon emissions in the city and major contributors of sulfur dioxide and carbon monoxide.

  9. Krakow clean fossil fuels and energy efficiency project

    International Nuclear Information System (INIS)

    The Support for Eastern European Democracy (SEED) Act of 1989 directed the U.S. Department of Energy (DOE) to undertake an equipment assessment project aimed at developing the capability within Poland to manufacture or modify industrial-scale combustion equipment to utilize fossil fuels cleanly. This project is being implemented in the city of Krakow as the 'Krakow Clean Fossil Fuels and Energy Efficiency Project.' Funding is provided through the U.S. Agency for International Development (AID). The project is being conducted in a manner that can be generalized to all of Poland and to the rest of Eastern Europe. The historic city of Krakow has a population of 750,000. Almost half of the heating energy used in Krakow is supplied by low-efficiency boilerhouses and home coal stoves. Within the town, there are more than 1,300 local boilerhouses and 100,000 home stoves. These are collectively referred to as the 'low emission sources' and they are the primary sources of particulates and hydrocarbon emissions in the city and major contributors of sulfur dioxide and carbon monoxide

  10. Open-gradient magnetic separation for physical coal cleaning

    Energy Technology Data Exchange (ETDEWEB)

    Doctor, R.D.; Livengood, C.D.

    1990-01-01

    Open-Gradient Magnetic Separation (OGMS) using superconducting quadrupole magnets offers a novel beneficiation technology for removing pyritic sulfur from pulverized dry coal. It is estimated to have a power demand 75% lower than techniques using conventional electromagnets, while achieving higher separation forces. Additionally, the system operates in a continuous mode and uses no chemicals. Because OGMS is specifically applicable to finely ground coal (120--325 mesh), its development could encourage the commercialization of other unconventional coal technologies, such as coal-water slurries, fluidized-bed combustion, and synfuels. 3 figs., 1 tab.

  11. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no

  12. Coal diesel combined-cycle project. Annual report, January 1996--January 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The Clean Coal Diesel project will demonstrate a new Clean Coal Technology that has technical, economic and environmental advantages over conventional power generating methods. This innovative technology enables utilization of coal-based fuel in large-bore, medium-speed, diesel engines. Modular power generating applications in the 10 to 100 megawatt size range are the target applications. The University of Alaska campus in Fairbanks, Alaska, is the project`s host site. At this location, the University will construct and operate the Clean Coal Diesel System, which will serve as a 6.2 MW diesel powerplant addition. The University will also assemble and operate a 5-ton per hour coal-water fuel processing plant. The plant will utilize local coal, brought by truck from Usibelli`s mine in Healey, AK. The estimated performance characteristics of the mature commercial embodiment of the Clean Coal Diesel, if achieved, will make this technology quite competitive: 48% efficiency; $1,300/kW installed cost; and emission levels controlled to 50--70% below New Source Performance Standards. Specific objectives are to demonstrate that the Coal Diesel Technology: is durable and can operate 6,000 hours in a realistic commercial setting; will meet efficiency targets; can effectively control criteria pollutants to levels that are well below anticipated standards, as well as reduce greenhouse gas emissions; and can accommodate substantial power demand swings.

  13. Research in cleaning water-walls of the TP-45 boiler with water during combustion of Angren brown coal

    Energy Technology Data Exchange (ETDEWEB)

    Zagrutdinov, R.Sh.; Shpakovich, E.Ya.; Guzenko, S.I.; Timofeev, A.P.; Perevezentsev, V.P.; Vasil' ev, V.V.

    1982-08-01

    With the growth of the electric power industry, great significance is placed on combustion of low-grade coals in large deposits with infavorable properties. Angren brown coal is an inexpensive low-grade fuel with 20-22% dry ash. During its combustion in steam generators with a radiant heat surface associated deposits are formed. Research on the problem of preventing slag formation on heating surfaces during the combustion of Angren brown coal is discussed. The use of water to clean these surfaces is also discussed.

  14. Process to refine flyash captured from pulverized coal fired boilers and auxiliary equipment

    International Nuclear Information System (INIS)

    This patent describes a separating and refining process for particulate that has been removed from the exhaust gases of an organic fuel combustion process. It includes determining relative sizes of carbon rich and carbon lean particles that are found in the exhaust gases for the combustion process; supplying the particulate matter from the exhaust of the combustion process; providing a means for conveying the particulate matter between the following steps; separating, by size, coarse and fine particles in the exhaust particulate so as to yield carbon rich and carbon lean fractions

  15. PULSE COMBUSTOR DESIGN QUALIFICATION TEST AND CLEAN COAL FEEDSTOCK TEST - VOLUME I AND VOLUME II

    Energy Technology Data Exchange (ETDEWEB)

    Unknown

    2002-02-08

    For this Cooperative Agreement, the pulse heater module is the technology envelope for an indirectly heated steam reformer. The field of use of the steam reformer pursuant to this Cooperative Agreement with DOE is for the processing of sub-bituminous coals and lignite. The main focus is the mild gasification of such coals for the generation of both fuel gas and char--for the steel industry is the main focus. An alternate market application for the substitution of metallurgical coke is also presented. This project was devoted to qualification of a 253-tube pulse heater module. This module was designed, fabricated, installed, instrumented and tested in a fluidized bed test facility. Several test campaigns were conducted. This larger heater is a 3.5 times scale-up of the previous pulse heaters that had 72 tubes each. The smaller heater has been part of previous pilot field testing of the steam reformer at New Bern, North Carolina. The project also included collection and reduction of mild gasification process data from operation of the process development unit (PDU). The operation of the PDU was aimed at conditions required to produce char (and gas) for the Northshore Steel Operations. Northshore Steel supplied the coal for the process unit tests.

  16. PULSE COMBUSTOR DESIGN QUALIFICATION TEST AND CLEAN COAL FEEDSTOCK TEST - VOLUME I AND VOLUME II; FINAL

    International Nuclear Information System (INIS)

    For this Cooperative Agreement, the pulse heater module is the technology envelope for an indirectly heated steam reformer. The field of use of the steam reformer pursuant to this Cooperative Agreement with DOE is for the processing of sub-bituminous coals and lignite. The main focus is the mild gasification of such coals for the generation of both fuel gas and char-for the steel industry is the main focus. An alternate market application for the substitution of metallurgical coke is also presented. This project was devoted to qualification of a 253-tube pulse heater module. This module was designed, fabricated, installed, instrumented and tested in a fluidized bed test facility. Several test campaigns were conducted. This larger heater is a 3.5 times scale-up of the previous pulse heaters that had 72 tubes each. The smaller heater has been part of previous pilot field testing of the steam reformer at New Bern, North Carolina. The project also included collection and reduction of mild gasification process data from operation of the process development unit (PDU). The operation of the PDU was aimed at conditions required to produce char (and gas) for the Northshore Steel Operations. Northshore Steel supplied the coal for the process unit tests

  17. Advanced coal gasifier-fuel cell power plant systems design

    Science.gov (United States)

    Heller, M. E.

    1983-01-01

    Two advanced, high efficiency coal-fired power plants were designed, one utilizing a phosphoric acid fuel cell and one utilizing a molten carbonate fuel cell. Both incorporate a TRW Catalytic Hydrogen Process gasifier and regenerator. Both plants operate without an oxygen plant and without requiring water feed; they, instead, require makeup dolomite. Neither plant requires a shift converter; neither plant has heat exchangers operating above 1250 F. Both plants have attractive efficiencies and costs. While the molten carbonate version has a higher (52%) efficiency than the phosphoric acid version (48%), it also has a higher ($0.078/kWh versus $0.072/kWh) ten-year levelized cost of electricity. The phosphoric acid fuel cell power plant is probably feasible to build in the near term: questions about the TRW process need to be answered experimentally, such as weather it can operate on caking coals, and how effective the catalyzed carbon-dioxide acceptor will be at pilot scale, both in removing carbon dioxide and in removing sulfur from the gasifier.

  18. Oxy-Fuel Combustion of Coal

    DEFF Research Database (Denmark)

    Brix, Jacob

    model and experiments is caused by an experimental delay in ignition that is not captured by the model. Though this causes a deviation in total conversion COCOMO still predicts conversion rates accurately after ignition. A laboratory scale Fixed Bed Reactor (FBR), operated isothermally at 1073 K, has......This Ph.D. thesis describes an experimental and modeling investigation of the thermal conversion of coal and an experimental investigation of the emission of NO from char combustion in O2/N2 and O2/CO2 atmospheres. The motivation for the work has been the prospective use of the technology “Oxy......-Fuel Combustion” as a mean of CO2 abatement in large scale energy conversion. Entrained Flow Reactor (EFR) experiments have been conducted in O2/N2 and O2/CO2 mixtures in the temperature interval 1173 K – 1673 K using inlet O2 concentrations between 5 – 28 vol. %. Bituminous coal has been used as fuel in all...

  19. Comparison of CO2 From Coal Capture Processes and Valorisation Technologies

    OpenAIRE

    Martin Gonzalez, Mercedes; Clemente Jul, María del Carmen

    2011-01-01

    Coal is the most plentiful and evenly distributed fossil fuel worldwide. Based on current production, it is estimated that the reserves will last approximately 130 years. Its use worldwide has been increasing, mainly due to consumption by emerging countries. CO2 emissions generated by combustion and the repercussions of such on climate change support the view that it could no longer be used. CO2 capture may be the solution to continue using it, which would cater for the growing energy demand ...

  20. Alternative, Green Processes for the Precision Cleaning of Aerospace Hardware

    Science.gov (United States)

    Maloney, Phillip R.; Grandelli, Heather Eilenfield; Devor, Robert; Hintze, Paul E.; Loftin, Kathleen B.; Tomlin, Douglas J.

    2014-01-01

    Precision cleaning is necessary to ensure the proper functioning of aerospace hardware, particularly those systems that come in contact with liquid oxygen or hypergolic fuels. Components that have not been cleaned to the appropriate levels may experience problems ranging from impaired performance to catastrophic failure. Traditionally, this has been achieved using various halogenated solvents. However, as information on the toxicological and/or environmental impacts of each came to light, they were subsequently regulated out of use. The solvent currently used in Kennedy Space Center (KSC) precision cleaning operations is Vertrel MCA. Environmental sampling at KSC indicates that continued use of this or similar solvents may lead to high remediation costs that must be borne by the Program for years to come. In response to this problem, the Green Solvents Project seeks to develop state-of-the-art, green technologies designed to meet KSCs precision cleaning needs.Initially, 23 solvents were identified as potential replacements for the current Vertrel MCA-based process. Highly halogenated solvents were deliberately omitted since historical precedents indicate that as the long-term consequences of these solvents become known, they will eventually be regulated out of practical use, often with significant financial burdens for the user. Three solvent-less cleaning processes (plasma, supercritical carbon dioxide, and carbon dioxide snow) were also chosen since they produce essentially no waste stream. Next, experimental and analytical procedures were developed to compare the relative effectiveness of these solvents and technologies to the current KSC standard of Vertrel MCA. Individually numbered Swagelok fittings were used to represent the hardware in the cleaning process. First, the fittings were cleaned using Vertrel MCA in order to determine their true cleaned mass. Next, the fittings were dipped into stock solutions of five commonly encountered contaminants and were

  1. Impact of the state of-the-art of flue cleaning on mercury species emissions from coal-fired steam generators

    International Nuclear Information System (INIS)

    When balancing the element mercury (Hg) two coal-fired power plant units - one with slag tap boilers (ST, 2 x 220 MW) and one with a dry bottom boiler (DB, 475 MW) were compared. Both systems are provided with electrostatic precipitators (ESP), nitrogen oxides removal (DeNOx) and flue gas desulfurization (FGD) systems. The Hg in the flue gas is predominantly in gas phase. Only 15% of the Hg introduced by the coal leaves the unit with the bottom or fly ash. Depending on the operating mode, 30 to 40% of the Hg is separated in the FGD systems. The overall separation rate for the total system ranges between 45 to 55%, the residue is emitted in the form of gaseous Hg species. At full load, the Hg concentration in the cleaned gas is less than 6 μg/m32. In the flue gas path of another dry bottom boiler (DB1, 480 MW) the concentrations of the gaseous species of bivalent mercury (Hg2+), elemental mercury (Hg0), and total mercury content (ΣHg) were determined. The sum of the concentration of Hg2+ and Hg0 is in agreement with the measurement of ΣHg. Directly downstream of the boiler Hg2+ dominated with 77%, while Hg0 amounts to 23%. In the high-dust DeNOx system Hg0 is oxidized almost completely to Hg2+ (96%). Air heater and electrostatic precipitator do not influence the Hg species concentrations. The FGD system eliminates approximately 80% of the Hg2+. At the same time the quantity of Hg0 increases by the factor 10. In the cleaned gas Hg0 dominated with 76% as compared to Hg2+ with 24%. At full load the concentration of σHg in the cleaned gas is also below 6μg/m3. 13 refs., 4 figs., 1 tab

  2. Dilute chemical cleaning of PWR steam generators off-line cleaning process evaluation

    International Nuclear Information System (INIS)

    This project evaluated the feasibility of using a low-concentration (approx. 0.5 wt %) chemical cleaning process to remove corrosion product deposits from steam generator surfaces and magnetite from tube-to-support plate crevices of PWR steam generators. The primary objective was to develop a dilute process that could be safely applied at scheduled intervals, such as during normal refueling outages, to maintain a clean operating condition in the steam generator. The dilute chemical cleaning process developed in this project was demonstrated successfully on two model generators which were operated on faulted chemistry by DOE/CRC at Commonwealth's State Line Facility. Unit 5 was cleaned after 48 days of operation with 1% seawater fouling, and Unit 6 was cleaned after 112 days of operations with Lake Michigan water. This report describes work leading to the model generator cleaning demonstrations and provides details of the cleaning operation for each model steam generator

  3. Ultra Efficient CHHP Using a High Temperature Fuel Cell to Provide On-Site Process Reducing Gas, Clean Power, and Heat

    Energy Technology Data Exchange (ETDEWEB)

    Jahnke, Fred C. [Fuelcell Energy, Inc., Danbury, CT (United States)

    2015-06-30

    FuelCell Energy and ACuPowder investigated and demonstrated the use of waste anode exhaust gas from a high temperature fuel cell for replacing the reducing gas in a metal processing furnace. Currently companies purchase high pressure or liquefied gases for the reducing gas which requires substantial energy in production, compression/liquefaction, and transportation, all of which is eliminated by on-site use of anode exhaust gas as reducing gas. We performed research on the impact of the gas composition on product quality and then demonstrated at FuelCell Energy’s manufacturing facility in Torrington, Connecticut. This demonstration project continues to operate even though the research program is completed as it provides substantial benefits to the manufacturing facility by supplying power, heat, and hydrogen.

  4. Optimization of the process of steel strip perforation and nickel platting for the purpose of elimination of trichloroethylene from the cleaning process of perforated steel strip

    Directory of Open Access Journals (Sweden)

    Petrović Aleksandra B.

    2009-01-01

    Full Text Available In the production of pocket type electrodes for Ni-Cd batteries perforation of proper steel strips and then nickel platting of perforated steel strips were made. In the nickel platting process, the organic solvent, trichloroethylene, has previously been used for cleaning. Due to the carcinogenic nature of trichloroethylene and the many operations previously required during cleaning, it was considered to do cleaning of perforated steel strips without use of the mentioned organic solvent. In the purpose of elimination of trichloroethylene from the cleaning process of perforated steel strips, the tests of perforation of steel strips with use of oils of different viscosity were made. It was shown that there was no dysfunction during the work of the perforation plants, meaning there was no additional heating of the strips, deterring of the steel filings, nor excessive wearing of the perforation apparatus. The perforation percent was the same irrelevant of the viscosity of the used oil. Before being perforated using the oils with different viscosity, the nickel platting steel strips were cleaned in different degreasers (based on NaOH as well as on KOH. It was shown that efficient cleaning without the use of trichloroethylene is possible with the use of oil with smaller viscosity in the perforated steel strips process and the degreaser based on KOH in the cleaning process, before nickel platting. It also appeared that the alkali degreaser based on KOH was more efficient, bath corrections were made less often and the working period of the baths was longer, which all in summary means less quantity of chemicals needed for degreasing of perforated steel strips.

  5. Commercializing Canada's emerging energies : capitalising on large-scale power project opportunities from wind and hydro power, to biomass and clean coal

    International Nuclear Information System (INIS)

    The Canada Institute conference on Commercialising Canada's Emerging Energies was held in Calgary, Alberta, Canada on May 28-29, 2007. This publication provides cutting-edge project updates and best practices on how to take advantage of new business opportunities, while both identifying and mitigating the risks associated with future large-scale projects. Emerging energies - wind, hydro, biomass and clean coal - are no longer the future, they are todayAre you ready to take advantage of Canada's next generation of clean and green power opportunities?Canada's electricity industry is changing dramatically. Power projects are becoming less centralized. Governments are shifting their focus to clean and green sources of energy. The cost-effectiveness of applying emerging energy technologies for large-scale (5mw+) power projects has significantly improved - especially with new regulatory incentives.However, many challenges still need to be addressed to bring many of these projects into the mainstream market. Ensuring adequate supply, system reliability and transmission capacity are among the key technical issues. Improvements to community consultation practice, project planning and implementation skills, and government incentives are also expected to improve emerging energy economics and deliverability

  6. Emissions from slow pyrolysis of solid fuels studied by GC/MS in a miniature reactor

    Energy Technology Data Exchange (ETDEWEB)

    Pedersen, J.R.; Stroemberg, K.; Olsson, J.O. [Chalmers University of Technology, Goeteborg (Sweden). Dept. of Physical Chemistry

    1995-12-31

    The effect of fuel structure on emissions must be better known to promote cleaner combustion of solid fuels. In commercial combustors initial slow pyrolysis steps produce emission of numerous possible organic species. Biomass is today also considered for upgrading by pyrolysis to bio-oils. Knowledge of slow pyrolysis processes of coal and biomass is limited. A miniature pyrolysis reactor suited for GC/MS analysis has been designed. In the evaluation of the approach three distinct solid fuels were investigated: bituminous coal, sawdust from spruce and chips from eucalyptus. Coal pyrolysis produced comparatively high amounts of alkanes, naphthalenes and PAH not found at all in the wood samples. Coal also produced alkyl substituted phenols. Sawdust from spruce produced almost the same species as eucalyptus. However, the product distributions from spruce and eucalyptus pyrolysis differed. The products from eucalyptus were significantly more substituted than the products from spruce. The products from wood samples were dominated by oxygenates: fatty acids, cyclic oxygenates and methoxy substituted phenols. The present approach can be used for selecting solid fuels suitable for clean combustion and production of bio-oils. 9 refs., 7 figs.

  7. 7th clean coal technology conference. Proceedings, volume II, technical papers

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    The theme of the conference was '21st century coal utilization: prospects for economic viability, global prosperity and a cleaner environment'. The papers discussed, combustion systems - how CCTs can meet the needs; gasification systems - how CCTs can meet the needs; and beyond 2010 - technology opportunities and R & D needs. They include: Wabash River, Polk Power Station IGCC project, Pinon Pine project, LPMEOH process, Healy clean coal project, Lakeland McIntosh Unit 4 circulating fluidized bed combustion cycle demonstration project, and JEA large-scale CFB combustion demonstration project.

  8. Clean electricity from photovoltaics

    CERN Document Server

    Archer, Mary D

    2001-01-01

    Photovoltaic cells provide clean, reversible electrical power from the sun. Made from semiconductors, they are durable, silent in operation and free of polluting emissions. In this book, experts from all sectors of the PV community - materials scientists, physicists, production engineers, economists and environmentalists - give their critical appraisals of where the technology is now and what its prospects are. Sample Chapter(s). Chapter 2.1: Introduction (306 KB). Chapter 2.2: Semiconductor device equations (121 KB). Chapter 2.3: The p-n junction model of Shockley (1,017 KB). Chapter 2.4: Rea

  9. Cleaning of process and utility systems

    International Nuclear Information System (INIS)

    The cleaning of the process and utility equipment and systems forms part of the underlying strategy of planning and implementation. General observation shows that planning is the first essential element to a successful project. A prerequisite to good planning is establishing the goals and objectives at the very outset of the Abandonment Planning. These goals and objectives must be measurable against preestablished criteria so that the project can be evaluated to establish the level of success. Good planning can be viewed as a series of hurdles that one must clear to achieve the pre-set goals and objectives. Understanding of the legal, safety, environmental and legislative requirements allows the perimeters and constraints to be established before the final implementation of the, ''CLEANING OF PROCESS AND UTILITY EQUIPMENT AND SYSTEMS'' activities. The very subject of ''CLEANING OF PROCESS AND UTILITY EQUIPMENT AND SYSTEMS'' that may be considered straight forward, because some of these activities often form part of the normal platform operations performed from time to time on these systems. Before implementation of these activities, there must be an understanding of the ground rules and terminology used together with the resultant implications. A question that demonstrates the inherent problems, what does the term ''Clean'' mean? A limited list has been compiled to give some examples of what the dictionary defines the term clean to be; NOT DIRTY; UN-POLLUTED; DECONTAMINATED; STAINLESS; UNCONTAMINATED; SPOTLESS; VIRGIN; UNSTAINED; UNADULTERATED; STERILE; Liaison with Government departments during recent planning activities established a consensus for understanding the term ''Clean'' so that unreasonable expectation with regards to the level of cleanliness would not be greater than that which is practicable

  10. Impacts on human health from the coal and nuclear fuel cycles and other technologies associated with electric power generation and transmission

    International Nuclear Information System (INIS)

    Major public health impacts of electric power generation and transmission associated with the nuclear fuel cycle and with coal use are evaluated. Only existing technology is evaluated. The only health effects of concern are those leading to definable human disease and injury. Health effects are scaled to a nominal 1000 Megawatt (electric) plant fueled by either option. Comparison of the total health effects to the general public gives: nuclear, 0.03 to 0.05 major health effects per 1000 MWe per year; coal, 0.7 to 3.7 per 1000 MWe per year. Thus for the general public the health risks from the coal cycle are about 50 times greater than for the nuclear cycle. Health effects to workers in the industry are currently quite high. For the nuclear cycle, 4.6 to 5.1 major health impacts per 1000 MWe per year; for coal, 6.5 to 10.9. The two-fold greater risk for the coal cycle is primarily due to high injury rates in coal miners. There is no evidence that electrical transmission contributes any health effects to the general public, except for episodes where broken power lines come in contact with people. For power line workers, the risk is estimated at 0.1 serious injury per 1000 MWe per year

  11. Evaluation of technology modifications required to apply clean coal technologies in Russian utilities. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-01

    The report describes the following: overview of the Russian power industry; electric power equipment of Russia; power industry development forecast for Russia; clean coal technology demonstration program of the US Department of Energy; reduction of coal TPS (thermal power station) environmental impacts in Russia; and base options of advanced coal thermal power plants. Terms of the application of clean coal technology at Russian TPS are discussed in the Conclusions.

  12. Regional trends in the take-up of clean coal technologies

    Energy Technology Data Exchange (ETDEWEB)

    Wootten, J.M. [Peabody Holding Co., Inc., St. Louis, MO (United States)

    1997-12-31

    Using surveys of the electricity industry taken in major OECD coal producing/coal consuming regions of North America, Europe, Southern Africa, and Asia/Pacific, this paper reports on the attitudes of power plant operators and developers toward clean coal technologies, the barriers to their use and the policies and measures that might be implemented, if a country or region desired to encourage greater use of clean coal technologies.

  13. Solidification of liquid waste from the Freon based dry cleaning process

    International Nuclear Information System (INIS)

    The operating license of the BNPD-S radioactive waste management facility does not permit the storage of radioactive liquids. Samples of Freon based waste have been analyzed and two solidification methods for these samples were investigated in this work. Waste from the commissioning of the dry cleaning facility contains in excess of 96% Freon 113 and it is recommended that this waste be redistilled to recover the Freon. The preferred immobilization technique involves absorption of the waste into a porous medium. This should be adequate for storage purposes. When disposal facilities are available and if the activity of the waste is measurable then the mixture together with its container can be encapsulated in cement. Incineration of the waste is expected to produce corrosive gases as a result of the thermal decomposition of Freon 113 and is not recommended unless the Freon content can be substantially reduced

  14. Conversion of existing oil and gas units to coal fuel

    Energy Technology Data Exchange (ETDEWEB)

    Talmud, F.M.

    1978-01-01

    The feasibility and technical aspects of various alternatives for converting gas- or oil-fired utility and industrial boilers to coal firing are reviewed. These alternatives involve direct coal firing, the use of modified coal fuels, and firing with fuels produced by coal gasification. (LCL)

  15. New progress in the processing and efficient utilization of coal

    Institute of Scientific and Technical Information of China (English)

    Zhao Yuemin; Liu Jiongtian; Wei Xianyong; Luo Zhenfu; Chen Qingru; Song Shulei

    2011-01-01

    Coal accounts for about 70% of the primary energy sources in China.The environmental pollution and resources waste involved with coal processing and utilization are serious.It is therefore urgent to develop highly-efficient coal resources utilization theory and methods with low-carbon discharge.Based on our long-term basic research and technology development,the progress in beneficiation,cleaning,and transformation of coal,which includes dense phase fluidized bed dry beneficiation,deep screening of wet fine coal,micro-bubble flotation column separation,molecular coal chemistry,and transformation and separation of coal and its derivatives into value-added chemicals under mild conditions,is discussed.

  16. Development of a Novel Oxygen Supply Process and its Integration with an Oxy-Fuel Coal-Fired Boiler

    Energy Technology Data Exchange (ETDEWEB)

    None

    2006-12-31

    BOC, the world's second largest industrial gas company, has developed a novel high temperature sorption based technology referred to as CAR (Cyclic Autothermal Recovery) for oxygen production and supply to oxy-fuel boilers with flue gas recycle. This technology is based on sorption and storage of oxygen in a fixed bed containing mixed ionic and electronic conductor materials. The objective of the proposed work was to construct a CAR PDU that was capable of producing 10-scfm of oxygen, using steam or recycled flue gas as the sweep gas, and install it in the Combustion Test Facility. The unit was designed and fabricated at BOC/The Linde Group, Murray Hill, New Jersey. The unit was then shipped to WRI where the site had been prepared for the unit by installation of air, carbon dioxide, natural gas, nitrogen, computer, electrical and infrastructure systems. Initial experiments with the PDU consisted of flowing air into both sides of the absorption systems and using the air heaters to ramp up the bed temperatures. The two beds were tested individually to operational temperatures up to 900 C in air. The cycling process was tested where gases are flowed alternatively from the top then bottom of the beds. The PDU unit behaved properly with respect to flow, pressure and heat during tests. The PDU was advanced to the point where oxygen production testing could begin and integration to the combustion test facility could occur.

  17. US Department of Energy first annual clean coal technology conference

    International Nuclear Information System (INIS)

    The first public review of the US DOE/Industry co-funded program to demonstrate the commercial readiness of Clean Coal Technologies (CCT) was held at Cleveland, Ohio Sept. 22--24, 1992. The objectives were to provide electric utilities, independent power producers, and potential foreign users information on the DOE-supported CCT projects including status, results, and technology performance potential; to further understanding of the institutional, financial, and technical considerations in applying CCTs to Clean Air Act compliance strategies; to discuss to export market, financial and institutional assistance, and the roles of government and industry in pursuing exports of CCTs; and to facilitate meetings between domestic and international attendees to maximize export opportunities

  18. International prospects for clean coal technologies (Focus on Asia)

    Energy Technology Data Exchange (ETDEWEB)

    Gallaspy, D.T. [Southern Energy, Inc., Atlanta, GA (United States)

    1997-12-31

    The purpose of this paper is to propose Asia as a focus market for commercialization of CCT`s; describe the principles for successful penetration of CCT`s in the international market; and summarize prospects for CCT`s in Asia and other international markets. The paper outlines the following: Southern Company`s clean coal commitment; acquisition of Consolidated Electric Power Asia (CEPA); the prospects for CCT`s internationally; requirements for CCT`s widespread commercialization; CEPA`s application of CCT`s; and gas turbine power plants as a perfect example of a commercialization driver.

  19. Producing usable fuel from municipal solid waste

    Science.gov (United States)

    Ohlsson, O. O.

    Refuse disposal is a matter of increasing concern for municipalities and state governments. As existing land-fills become filled to capacity, and new landfills become more costly to site, it has become critical to develop alternative disposal methods. Some of the refuse that is presently being landfilled has the potential to provide considerable quantities of energy and thereby replace conventional fossil fuels. Another environmental concern is the problem of the emissions associated with combustion of traditional fossil fuels. The Clean Air Act Amendments of 1990 significantly restrict the level of sulfur dioxide (SO2) and nitrogen oxides (NO(x)) emissions permissible as effluent from combustion facilities. To address both of these concerns, Argonne National Laboratory, under sponsorship of the U.S. Department of Energy (DOE), has developed a means of producing fuel from municipal solid waste that can be co-fired with coal to supplement coal supplies and reduce problematic emissions.

  20. CHINA'S RECENT DEVELOPMENT IN COAL MINING,PROCESSING AND UTILIZATION

    Institute of Scientific and Technical Information of China (English)

    范维唐; 王成龙; 朱德仁

    1996-01-01

    This paper describes the state-of-the-art and outlook of coal mining and clean coal echnology in China. As the major mining method,underground mining accounts for 96% of the total production. Among the state own mines, the percentage of mechanized mining reached 71%. A rapid development of high-productive and high-profitable mines,especially those with longwall sublevel caving method, is described. The issues of heavy duty equipment, roof bolting, mine safety are also addressed. The Chinese government is paying more and more attention on the environmental problems inducing from coal mining,processing and utilization. A basic framework of clean coal technology is being formed and a wide range of technology is included.

  1. The influence of heat transfer conditions on the parameters characterizing the ignition of coal-water fuel particles

    Science.gov (United States)

    Syrodoy, S. V.; Kuznetsov, G. V.; Salomatov, V. V.

    2015-10-01

    The future of thermal power engineering both in Russia and abroad will depend in many respects on the use of coal as main fuel for generating heat and electricity. In this connection, matters concerned with development and introduction of new environmentally friendly and energy efficient coal firing technologies are becoming of much importance. Firing coal in the form of coal-water fuel is one of the most promising solutions. However, despite a rather long history of its development (more than 40 years), this technology has not found wide use as yet, which in all likelihood is due to lack of full mathematical and physicochemical models describing the processes that take place when a coal-water fuel particle undergoes thermal treatment and ignition. The article presents the results obtained from numerical solution of the coal-water fuel particle ignition problem taking into account simultaneously occurring main thermal treatment processes (thermal conductivity, water evaporation, filtration heat and mass transfer, thermal decomposition of the fuel organic part, and thermochemical interaction between water vapor and coke carbon). The ignition problem is solved using the finite difference method. For calculating the evaporation process taking into account nonequilibrium nature of the parameters at the interface boundary of the initial "coal-water fuel—dry coal" system, the method of capturing the phase transition front at the difference mesh node was used. The results obtained from numerical modeling were used for determining the conditions and parameters characterizing the ignition of coal-water fuel particles under the conditions typically existing in the furnace space of boiler units. The extent to which radiant heat transfer influences the ignition delay time is determined. It is shown that radiant heat transfer plays a determining role in the thermal preparation of fuel for ignition.

  2. Development of a Solid Oxide Fuel Cell for the utilization of coal mine gas

    Science.gov (United States)

    Groß, B.; Blum, L.; de Haart, L. G. J.; Dengel, A.

    Apart from natural gas there is another important natural source of methane. The so-called coal mine gas is a by-product of the geochemical process of the carbonization of sediments from marsh woods of the Earth's Carboniferous Period. Methane evaporates from the coal and has to be removed out of the active mines where it represents one of the main safety risks. Methane also evaporates in abandoned coal mines. In the federal state Saarland in Germany exists above ground a more than 110 km pipeline for the drained coal mine gas from 12 different sources. The content of methane varies between 25 and 90%, the oxygen content (from air) is in the range up to 10%. This wide range or variation, respectively, of fuel and oxygen content, causes a lot of problems for the use in conventional engines. Therefore the company Evonik New Energies GmbH is interested in using SOFC with coal mine gas as efficient as possible to produce electric power. For that purpose at Forschungszentrum Jülich the available SOFC technology was adapted to the use with coal mine gas and a test facility was designed to operate an SOFC stack (approximately 2 kW electrical power output) together with a pre-reformer. This paper presents the results of the coal mine gas analysis and the effect on the pre-reformer and the fuel cell. The composition of the coal mine gas was determined by means of micro-gas chromatography. The results obtained from preliminary tests using synthetic and real coal mine gas on the pre-reformer and on the fuel cell are discussed.

  3. Schemes and New Developments in Combinations of Gasification with Fuel Gas Cleaning for Power Generation in Piston Gas Engines and Gas Turbines

    Czech Academy of Sciences Publication Activity Database

    Skoblia, S.; Beňo, Z.; Picek, I.; Pohořelý, Michael

    Prague: ICPF ASCR, v. v. i, 2013, s. 18-19. ISBN 978-80-86186-43-6. [Fecundus International Workshop New Procesess for Fuel Conversion, Gas Cleaning and CO2, Separation in FB and EF Gasification of Coal, Biomas and Waste. Prague (CZ), 12.06.2013-14.06.2013] Grant ostatní: TA ČR(CZ) TA01021279 Institutional support: RVO:67985858 Keywords : gasification * gas cleaning system * power generation Subject RIV: JP - Industrial Processing http://www.fecundus.cnr.it

  4. Inhibition of the Nitrification Process of Activated Sludge Micro-Organism by Scrubber Water from an Industrial Flue Gas Cleaning Process

    DEFF Research Database (Denmark)

    Thomsen, Jens Peter

    2007-01-01

    The microbial transformation of ammonia to nitrate, the nitrification, is a central process in the nitrogen biogeochemical cycle. In a modern wastewater treatment plant, the nitrification process is a key process in the removal of nitrogen and inhibitory compounds in sewage can seriously affect the...... nitrogen removal. A major sewage cleaning plant in the southern part of Denmark is a recipient of industrial sewage from a major fish meal industry. Severe nitrification inhibition was observed in scrubber water from an incineration of process air, and the processes that lead to the production were stopped...... using active sludge from the municipal wastewater cleaning plant. The investigation showed that it is possible to reduce the nitrification inhibition effect considerably by raising the incineration temperature from 800°C to 850°C and in some cases to 900°C. The investigation also showed that a further...

  5. Clean electricity from photovoltaics

    CERN Document Server

    Green, Martin A

    2015-01-01

    The second edition of Clean Electricity from Photovoltaics , first published in 2001, provides an updated account of the underlying science, technology and market prospects for photovoltaics. All areas have advanced considerably in the decade since the first edition was published, which include: multi-crystalline silicon cell efficiencies having made impressive advances, thin-film CdTe cells having established a decisive market presence, and organic photovoltaics holding out the prospect of economical large-scale power production. Contents: The Past and Present (M D Archer); Limits to Photovol

  6. Heterogeneous catalytic process for alcohol fuels from syngas

    Energy Technology Data Exchange (ETDEWEB)

    Minahan, D.M.; Nagaki, D.A.

    1995-12-31

    This project is focused on the discovery and evaluation of novel heterogeneous catalyst for the production of oxygenated fuel enhancers from synthesis gas. Catalysts have been studied and optimized for the production of methanol and isobutanol mixtures which may be used for the downstream synthesis of MTBE or related oxygenates. Higher alcohols synthesis (HAS) from syngas was studied; the alcohols that are produced in this process may be used for the downstream synthesis of MTBE or related oxygenates. This work has resulted in the discovery of a catalyst system that is highly selective for isobutanol compared with the prior art. The catalysts operate at high temperature (400{degrees}C), and consist of a spinel oxide support (general formula AB{sub 2}O{sub 4}, where A=M{sup 2+} and B = M{sup 3+}), promoted with various other elements. These catalysts operate by what is believed to be an aldol condensation mechanism, giving a product mix of mainly methanol and isobutanol. In this study, the effect of product feed/recycle (methanol, ethanol. n-propanol, isopropanol, carbon dioxide and water) on the performance of 10-DAN-55 (spinel oxide based catalyst) at 400{degrees}C, 1000 psi, GHSV = 12,000 and syngas (H{sub 2}/CO) ratio = 1:2 (alcohol addition) and 1:1 (carbon dioxide and water addition) was studied. The effect of operation at high temperatures and pressures on the performance of an improved catalyst formulation was also examined.

  7. Coupled flow and geomechanical processes during gas production from coal seams

    Energy Technology Data Exchange (ETDEWEB)

    Connell, L.D. [CSIRO Petroleum, Ian Wark Laboratory, Clayton, Victoria (Australia)

    2009-07-01

    Permeability in coal seams is sensitive to stress and pore pressure changes. An additional influence on this behaviour is the nature of the coal matrix to shrink with gas desorption and swell with adsorption. Concise relationships for permeability have been developed which incorporate these mechanisms, some of which are derived from a geomechanical basis such as the Shi-Durucan model and the Palmer-Mansoori model. While these expressions are attractive approaches for defining coal permeability during gas migration, the geomechanical behaviour has been simplified by assuming uni-axial strain and constant vertical stress. In this paper a coupled numerical model is developed and used to investigate the applicability of these geomechanical assumptions for gas drainage from coal seams. The modelling approach involved coupling the existing coal seam gas reservoir simulator, SIMED II, with the geomechanical simulator, FLAC3D. While SIMED II was used to simulate gas migration in a hypothetical coal seam and a series of production scenarios, FLAC3D simulated the geomechanical response of the coal and the adjacent non-coal geological formations to fluid pressure and gas content changes imported from SIMED II. The simulations, which considered a range of property values relevant to the San Juan basin, found that while the assumption of uni-axial strain introduced negligible discrepancy, the assumption of constant vertical stress leads to significant differences between the Shi-Durucan permeability estimate and that calculated from the SIMED-FLAC3D simulation, especially at early times during production. These differences were a result of the pressure and sorption strain changes induced by production leading to arching of stresses in the vicinity of the production well. The mechanism was shown to produce significant differences in the calculated gas rate particularly at early times during production. (author)

  8. Characterization and Recovery of Rare Earths from Coal and By-Products

    Energy Technology Data Exchange (ETDEWEB)

    Granite, Evan J. [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Roth, Elliot [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Alvin, Mary Anne [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

    2016-03-25

    Coal is a precious resource, both in the United States and around the world. The United States has a 250-year supply of coal, and generates between 30 - 40% of its electricity through coal combustion. Approximately 1 Gt of coal has been mined annually in the US, although the 2015 total will likely be closer to 900 Mt (http://www.eia.gov/coal/production/quarterly/). Most of the coal is burned for power generation, but substantial quantities are also employed in the manufacture of steel, chemicals, and activated carbons. Coal has a positive impact upon many industries, including mining, power, rail transportation, manufacturing, chemical, steel, activated carbon, and fuels. Everything that is in the earth’s crust is also present within coal to some extent, and the challenge is always to utilize abundant domestic coal in clean and environmentally friendly manners. In the case of the rare earths, these valuable and extraordinarily useful elements are present within the abundant coal and coal by-products produced domestically and world-wide. These materials include the coals, as well as the combustion by-products such as ashes, coal preparation wastes, gasification slags, and mining by-products. All of these materials can be viewed as potential sources of rare earth elements. Most of the common inorganic lanthanide compounds, such as the phosphates found in coal, have very high melting, boiling, and thermal decomposition temperatures, allowing them to concentrate in combustion and gasification by-products. Furthermore, rare earths have been found in interesting concentrations in the strata above and below certain coal seams. Much of the recent research on coal utilization in the United States has focused upon the capture of pollutants such as acid gases, particulates, and mercury, and the greenhouse gas carbon dioxide. The possible recovery of rare earth and other critical elements from abundant coal and by-products is an exciting new research area, representing a

  9. Current status of U.S. coal utilization and non-fuel uses of fossil fuels

    International Nuclear Information System (INIS)

    An understanding of the current situation is important for projecting the future direction of coal utilization. The world's annual consumption of coal in 1995 was 5104.01 million short tons (MST, 1 short ton = 0.907 metric ton). Coal plays a very important role in the US energy supply; US coal production in 1995 totaled 1033 MST, including 611.1 MST of bituminous coal, 328.4 MST of subbituminous coal, 86.1 MST of lignite, and 4.1 MST of anthracite. US coal consumption totaled 940.6 MST, with 88.1% in electric utilities, 3.5% in coke plants, 7.8% for other industrial uses, and only 0.6% in the residential and commercial sectors. The amount of fossil resources used for non-fuel purposes accounted for 8.4% of the total annual consumption in 1995. Non-fuel uses of fossil fuels particularly coal may become more important in the future. The demonstrated coal reserves in the world are large enough for consumption for over 220 years at the 1995 level, while proven oil reserves are only about 40 times the world's 1995 consumption level. Coal has several positive attributes when considered as a feedstock for aromatic chemicals, specialty chemicals, and carbon-based materials. Existing nonfuel uses of coals include (1) high temperature carbonization of bituminous and subbituminous coals to make metallurgical coke; (2) gasification of coal to make synthesis gases and other chemicals; (3) use of coal in manufacturing other materials such as activated carbons, carbon molecular sieves (CMS) and production of phosphorus (phosphoric acid); (4) the use of coal tars from carbonization and gasification for making aromatic and phenolic chemicals; (5) the use of coal tar pitch for making carbon fibers and activated carbon fibers; and (6) other non-fuel products derived from coal including combustion by-products. Coal may become more important both as an energy source and as the source of chemical feedstocks in the 21st century

  10. Comparison of coal/solid recovered fuel (SRF) with coal/refuse derived fuel (RDF) in a fluidised bed reactor.

    OpenAIRE

    Wagland, Stuart Thomas; Kilgallon, P.; Coveney, R.; Garg, A; Smith, Richard; Longhurst, Philip J.; Pollard, Simon J. T.; Simms, Nigel J

    2011-01-01

    An experimental study was undertaken to compare the differences between municipal solid waste (MSW) derived solid recovered fuel (SRF) (complying with CEN standards) and refuse derived fuel (RDF). Both fuels were co-combusted with coal in a 50kW fluidised bed combustor and the metal emissions were compared. Synthetic SRF was prepared in the laboratory by grinding major constituents of MSW such as paper, plastic, textile and wood. RDF was obtained from a local mechanical trea...

  11. Flotation process diagnostics and modelling by coal grain analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ofori, P; O' Brien, G.; Firth, B.; Jenkins, B. [CSIRO Energy Technology, Brisbane, Qld. (Australia)

    2006-05-15

    In coal flotation, particles of different components of the coal such as maceral groups and mineral matter and their associations have different hydrophobicities and therefore different flotation responses. By using a new coal grain analysis method for characterising individual grains, more detailed flotation performance analysis and modelling approaches have been developed. The method involves the use of microscopic imaging techniques to obtain estimates of size, compositional and density information on individual grains of fine coal. The density and composition partitioning of coal processed through different flotation systems provides an avenue to pinpoint the actual cause of poor process performance so that corrective action may be initiated. The information on grain size, density and composition is being used as input data to develop more detailed flotation process models to provide better predictions of process performance for both mechanical and column flotation devices. A number of approaches may be taken to flotation modelling such as the probability approach and the kinetic model approach or a combination of the two. In the work reported here, a simple probability approach has been taken, which will be further refined in due course. The use of grain data to map the responses of different types of coal grains through various fine coal cleaning processes provided a more advanced diagnostic capability for fine coal cleaning circuits. This enabled flotation performance curves analogous to partition curves for density separators to be produced for flotation devices.

  12. Toxic Substances From Coal Combustion - Phase I Coal Selection and Chaacterization

    Energy Technology Data Exchange (ETDEWEB)

    A. Kolker; A. Sarofim; C.A. Palmer; C.L. Senior; F.E. Huggins; G.P. Huffman; I. Olmez; N. Shah; R. Finkelman; S. Crowley; T. Zeng

    1998-07-16

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. Over the past decade, a large database identifying the partitioning and emitted concentrations of several toxic metals on the list of HAPs has been developed. Laboratory data have also been generated to help define the general behavior of several elements in combustion systems. These data have been used to develop empirical and probabalistic models to predict emissions of trace metals from coal-fired power plants. While useful for providing average emissions of toxic species, these empirically based models fail when extrapolated beyond their supporting database. This represents a critical gap; over the coming decades, new fuels and combustion systems will play an increasing role in our nation's power generation system. For example, new fuels, such as coal blends or beneficiated fuels, new operating conditions, such as low-NO burners or staged combustion, or new power x systems, for example, those being developed under the DoE sponsored Combustion 2000 programs and integrated gasification combined cycle (IGCC) systems, are all expected to play a role in power generation in the next century. The need for new predictive tools is not limited to new combustion systems, however. Existing combustion systems may have to employ controls for HAPs, should regulations be imposed. Testing of new control methods, at pilot and full scale, is expensive. A sound under-standing of the chemical transformations of both organic and inorganic HAPs will promote the development of new control methods in a cost-effective manner. To ensure that coal-fired power generation proceeds in an environmentally benign fashion, methods for the prediction

  13. Gasification Characteristics of Coal/Biomass Mixed Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Mitchell, Reginald

    2013-09-30

    A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co- produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle

  14. Application of Derrick Corporation's stack sizer technology for slimes reduction in 6 inch clean coal hydrocyclone circuits

    Energy Technology Data Exchange (ETDEWEB)

    Brodzik, P.

    2009-04-15

    The article discusses the successful introduction of Derrick Corporation's Stack Sizer technology for removing minus 200 mesh slimes from 6-inch coal hydrocyclone underflow prior to froth flotation or dewatering by screen bowl centrifuges. In 2006, the James River Coal Company selected the Stack Sizer fitted with Derrick 150 micron and 100 micron urethane screen panels for removal of the minus 100 mesh high ash clay fraction from the clean coal spiral product circuits. After this application proved successful, Derrick Corporation introduced new 75 micron urethane screen panels for use on the Stack Sizer. Evaluation of feed slurry to flotation cells and screen bowl centrifuges showed significant amounts of minus 75 micron that could potentially be removed by efficient screening technology. Removal of the minus 75 micron fraction was sought to reduce ash and moisture content of the final clean coal product. Full-scale lab tests confirmed that the Stack Sizer fitted with Derrick 75 micron urethane screen panels consistently reduced the minus 75 micron percentage in coal slurry from 6-inch clean coal hydrocyclone underflow that is approximately 15 to 20% solid by-weight and 30 to 60% minus 75 micron to a clean coal fraction that is approximately 13 to 16% minus 75 micron. As a result total ash is reduced from approximately 36 to 38% in the hydrocyclone underflow to 14 to 16% in the oversize product fraction form the Stack Sizers. 1 fig., 2 tabs., 5 photos.

  15. A Low-cost, High-yield Process for the Direct Productin of High Energy Density Liquid Fuel from Biomass

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Rakesh

    2014-02-21

    The primary objective and outcome of this project was the development and validation of a novel, low-cost, high-pressure fast-hydropyrolysis/hydrodeoxygenation (HDO) process (H{sub 2}Bioil) using supplementary hydrogen (H{sub 2}) to produce liquid hydrocarbons from biomass. The research efforts under the various tasks of the project have culminated in the first experimental demonstration of the H2Bioil process, producing 100% deoxygenated >C4+ hydrocarbons containing 36-40% of the carbon in the feed of pyrolysis products from biomass. The demonstrated H{sub 2}Bioil process technology (i.e. reactor, catalyst, and downstream product recovery) is scalable to a commercial level and is estimated to be economically competitive for the cases when supplementary H{sub 2} is sourced from coal, natural gas, or nuclear. Additionally, energy systems modeling has revealed several process integration options based on the H{sub 2}Bioil process for energy and carbon efficient liquid fuel production. All project tasks and milestones were completed or exceeded. Novel, commercially-scalable, high-pressure reactors for both fast-hydropyrolysis and hydrodeoxygena