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Sample records for clean cast steel

  1. Clean Cast Steel Technology, Phase IV

    Energy Technology Data Exchange (ETDEWEB)

    Charles E. Bates

    2003-02-24

    The objective of the Clean Cast Steel Technology Program was to improve casting product quality by removing or minimizing oxide defects and to allow the production of higher integrity castings for high speed machining lines. Previous research has concentrated on macro-inclusions that break, chip, or crack machine tool cutters and drills and cause immediate shutdown of the machining lines. The overall goal of the project is to reduce the amount of surface macro-inclusions and improve the machinability of steel castings. Macro-inclusions and improve the machinability of steel castings. Macro-inclusions have been identified by industrial sponsors as a major barrier to improving the quality and marketability of steel castings.

  2. Clean cast steel technology. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Bates, C.E.; Griffin, J.A.

    1998-06-01

    This report documents the results obtained from the Clean Cast Steel Technology Program financially supported by the DOE Metal Casting Competitiveness Research Program and industry. The primary objective of this program is to develop technology for delivering steel free of oxide macroinclusions to mold cavities. The overall objective is to improve the quality of cast steel by developing and demonstrating the technology for substantially reducing surface and sub-surface oxide inclusions. Two approaches are discussed here. A total of 23 castings were produced by submerge pouring along with sixty conventionally poured castings. The submerged poured castings contained, on average, 96% fewer observable surface inclusions (11.9 vs 0.4) compared to the conventionally poured cast parts. The variation in the population of surface inclusions also decreased by 88% from 5.5 to 0.7. The machinability of the casting was also improved by submerged pouring. The submerge poured castings required fewer cutting tool changes and less operator intervention during machining. Subsequent to these trials, the foundry has decided to purchase more shrouds for continued experimentation on other problem castings where submerge pouring is possible. An examination of melting and pouring practices in four foundries has been carried out. Three of the four foundries showed significant improvement in casting quality by manipulating the melting practice. These melting practice variables can be grouped into two separate categories. The first category is the pouring and filling practice. The second category concerns the concentration of oxidizable elements contained in the steel. Silicon, manganese, and aluminum concentrations were important factors in all four foundries. Clean heats can consistently be produced through improved melting practice and reducing exposure of the steel to atmospheric oxygen during pouring and filling.

  3. Clean Cast Steel Technology - Machinability and Technology Transfer

    Energy Technology Data Exchange (ETDEWEB)

    C. E. Bates; J. A. Griffin

    2000-05-01

    There were two main tasks in the Clean Cast Steel Technology - Machinability and Technology Transfer Project. These were (1) determine the processing facts that control the machinability of cast steel and (2) determine the ability of ladle stirring to homogenize ladle temperature, reduce the tap and pouring temperatures, and reduce casting scrap.

  4. Tundish Technology for Casting Clean Steel: A Review

    Science.gov (United States)

    Sahai, Yogeshwar

    2016-08-01

    With increasing demand of high-quality clean steel, cleanliness is of paramount importance in steel production and casting. Tundish plays an important role in controlling the continuously cast steel quality as it links a batch vessel, ladle, to a continuous casting mold. Tundish is also the last vessel in which metal flows before solidifying in mold. For controlling the quality of steel, flow and temperature control of the melt are critical, and these are presented in this paper. Use of proper flux, design of flow control devices, and gas injection in tundish become important factors in casting clean steel. Recycling of hot tundish, centrifugal flow tundish, H-shaped tundish, etc. are some of the developments which were implemented to cast clean steel and these are discussed.

  5. Clean cast steel technology. Determination of transformation diagrams for duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Chumbley, S. L. [Iowa State Univ., Ames, IA (United States)

    2005-09-01

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as sigma ( can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling- transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe 22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ( formation were analyzed using the Johnson-Mehl-Avrami (JMA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations, The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities, a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, was stabilized with increasing Cr addition and by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in DSS can be affected by local

  6. Energy Saving Melting and Revert Reduction Technology (Energy-SMARRT): Clean Steel Casting Production

    Energy Technology Data Exchange (ETDEWEB)

    Kuyucak, Selcuk [CanmetMATERIALS; Li, Delin [CanmetMATERIALS

    2013-12-31

    Inclusions in steel castings can cause rework, scrap, poor machining, and reduced casting performance, which can obviously result in excess energy consumption. Significant progress in understanding inclusion source, formation and control has been made. Inclusions can be defined as non-metallic materials such as refractory, sand, slag, or coatings, embedded in a metallic matrix. This research project has focused on the mold filling aspects to examine the effects of pouring methods and gating designs on the steel casting cleanliness through water modeling, computer modeling, and melting/casting experiments. Early in the research project, comprehensive studies of bottom-pouring water modeling and low-alloy steel casting experiments were completed. The extent of air entrainment in bottom-poured large castings was demonstrated by water modeling. Current gating systems are designed to prevent air aspiration. However, air entrainment is equally harmful and no prevention measures are in current practice. In this study, new basin designs included a basin dam, submerged nozzle, and nozzle extension. The entrained air and inclusions from the gating system were significantly reduced using the new basin method. Near the end of the project, there has been close collaboration with Wescast Industries Inc., a company manufacturing automotive exhaust components. Both computer modeling using Magma software and melting/casting experiments on thin wall turbo-housing stainless steel castings were completed in this short period of time. Six gating designs were created, including the current gating on the pattern, non-pressurized, partially pressurized, naturally pressurized, naturally pressurized without filter, and radial choke gating without filter, for Magma modeling. The melt filling velocity and temperature were determined from the modeling. Based on the simulation results, three gating designs were chosen for further melting and casting experiments on the same casting pattern using

  7. Clean Cast Steel Technology: Effect of Micro-porosity on Tensile and Charpy Properties of Four Cast Steels

    Energy Technology Data Exchange (ETDEWEB)

    Griffin, John, A.; Bates, Charles, E.

    2005-09-19

    The effect of these large shrink cavities on mechanical properties could be easily calculated using well established engineering formulas. Over the years, increases in computational and metallurgical resources have allowed the modeler to improve accuracy and increase the complexity of numerical predictors. An accurate prediction of micro-porosity, not observable using conventional radiographic techniques, and an engineering understanding of the effect on mechanical properties would give a designer confidence in using a more efficient casting design and a lower safety factor. This will give castings an additional design advantage. The goal of this project is to provide current and future modelers/designers with a tensile and Charpy property dataset for validation of micro-porosity predictors. The response of ultimate strength, elongation, and reduction in area to micro-porosity was very similar in all four alloys. Ultimate strength was largely unaffected by tensile fracture surface porosity until values of about 25% were reached and decreased linearly with increasing values. Elongation and reduction in area decreased sharply after less than 5% fracture surface porosity. Niyama values of about 0.7 were produced sound material and acceptable tensile properties. Ultrasonic velocities of 0.233 in/usec and higher produced acceptable tensile properties. Metallographic examination revealed a ratio of 4-6 to 1 in fracture surface porosity to metallographic porosity. Charpy impact properties were largely unaffected by the microporosity concentrations examined in this study and did not correlate to either Niyama values, fracture surface porosity, or metallographic porosity.

  8. Clean Metal Casting

    Energy Technology Data Exchange (ETDEWEB)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05

    The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

  9. Strip casting of stainless steels

    OpenAIRE

    Raabe, D.

    1997-01-01

    FLAT PRODUCTS OF STAINLESS STEELS ARE CONVENTIONALLY MANUFACTURED BY CONTINUOUS CASTING, HOT ROLLING, HOT BAND ANNEALING, PICKLING, COLD ROLLING AND RECRYSTALLISATION. IN THE LAST YEARS STRIP CASTING HAS INCREASINGLY ATTRACTED ATTENTION. IT OFFERS THREE IMPROVEMENTS IN COMPARISON TO THE CONVENTIONAL METHOD.1.) IT ALLOWS TO CAST STEEL SHEETS WITH THE SAME THICKNESS AND WIDTH AS THOSE PRODUCED BY HOT ROLLING. THIS MEANS THAT THE HOT ROLLING PROCESSIS BYPASSED. 2.) THE STRIP CAST STEEL REVEALS A...

  10. Fracture Mechanisms in Steel Castings

    Directory of Open Access Journals (Sweden)

    Z. Stradomski

    2013-07-01

    Full Text Available The investigations were inspired with the problem of cracking of steel castings during the production process. A single mechanism of decohesion - the intergranular one - occurs in the case of hot cracking, while a variety of structural factors is decisive for hot cracking initiation, depending on chemical composition of the cast steel. The low-carbon and low-alloyed steel castings crack due to the presence of the type II sulphides, the cause of cracking of the high-carbon tool cast steels is the net of secondary cementite and/or ledeburite precipitated along the boundaries of solidified grains. Also the brittle phosphor and carbide eutectics precipitated in the final stage solidification are responsible for cracking of castings made of Hadfield steel. The examination of mechanical properties at 1050°C revealed low or very low strength of high-carbon cast steels.

  11. Clean ferrous casting technology research. Final technical report, September 29, 1993--December 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Piwonka, T.S. [ed.

    1996-01-01

    This report details results of a 30-month program to develop methods of making clean ferrous castings, i.e., castings free of inclusions and surface defects. The program was divided into 3 tasks: techniques for producing clean steel castings, electromagnetic removal of inclusions from ferrous melts, and study of causes of metal penetration in sand molds in cast iron.

  12. Bimetallic layered castings alloy steel – carbon cast steel

    Directory of Open Access Journals (Sweden)

    T. Wróbel

    2011-01-01

    Full Text Available In paper is presented technology of bimetallic layered castings based on founding method of layer coating directly in cast processso-called method of mould cavity preparation. Prepared castings consist two fundamental parts i.e. bearing part and working part (layer. The bearing part of bimetallic layered casting is typical foundry material i.e. ferritic-pearlitic carbon cast steel, whereas working part (layer is plate of austenitic alloy steel sort X10CrNi 18-8. The ratio of thickness between bearing and working part is 8:1. The quality of the bimetallic layered castings was evaluated on the basis of ultrasonic NDT (non-destructive testing, structure and macro- and microhardness researches.

  13. Clean steels for fusion

    Energy Technology Data Exchange (ETDEWEB)

    Gelles, D.S.

    1995-03-01

    Fusion energy production has an inherent advantage over fission: a fuel supply with reduced long term radioactivity. One of the leading candidate materials for structural applications in a fusion reactor is a tungsten stabilized 9% chromium Martensitic steel. This alloy class is being considered because it offers the opportunity to maintain that advantage in the reactor structure as well as provide good high temperature strength and radiation induced swelling and embrittlement resistance. However, calculations indicate that to obtain acceptable radioactivity levels within 500 years after service, clean steel will be required because the niobium impurity levels must be kept below about 2 appm and nickel, molybdenum, nitrogen, copper, and aluminum must be intentionally restricted. International efforts are addressing the problems of clean steel production. Recently, a 5,000 kg heat was vacuum induction melted in Japan using high purity commercial raw materials giving niobium levels less than 0.7 appm. This paper reviews the need for reduced long term radioactivity, defines the advantageous properties of the tungsten stabilized Martensitic steel class, and describes the international efforts to produce acceptable clean steels.

  14. The heat treatment of Fermanal cast steel

    OpenAIRE

    F. Binczyk; A. Smoliński; J. Szymszal

    2007-01-01

    The study discloses the results of microstructural examinations, testing of magnetic properties and hardness measurements as cast and after heat treatment conducted on the Fermanal cast steel. A characteristic feature of this cast steel is its density lower by about 10% than the density of carbon cast steel [4]. It has been proved that the factor deciding about the composition of microstructure (fraction of ferrite and austenite) is the content of aluminium. The matrix totally austenitic is p...

  15. Fillability of Thin-Wall Steel Castings

    Energy Technology Data Exchange (ETDEWEB)

    Robert C. Voigt; Joseph Bertoletti; Andrew Kaley; Sandi Ricotta; Travis Sunday

    2002-07-30

    The use of steel components is being challenged by lighter nonferrous or cast iron components. The development of techniques for enhancing and ensuring the filability of thin-wall mold cavities is most critical for thinner wall cast steel production. The purpose of this research was to develop thin-wall casting techniques that can be used to reliably produce thin-wall castings from traditional gravity poured sand casting processes. The focus of the research was to enhance the filling behavior to prevent misrunds. Experiments were conducted to investigate the influence of various foundry variables on the filling of thin section steel castings. These variables include casting design, heat transfer, gating design, and metal fluidity. Wall thickness and pouring temperature have the greatest effect on casting fill. As wall thickness increases the volume to surface area of the casting increases, which increases the solidification time, allowing the metal to flow further in thicker sect ions. Pouring time is another significant variable affecting casting fill. Increases or decreases of 20% in the pouring time were found to have a significant effect on the filling of thin-wall production castings. Gating variables, including venting, pouring head height, and mold tilting also significantly affected thin-wall casting fill. Filters offer less turbulent, steadier flow, which is appropriate for thicker castings, but they do not enhance thin-wall casting fill.

  16. Process development of thin strip steel casting

    Energy Technology Data Exchange (ETDEWEB)

    Sussman, R.C.; Williams, R.S.

    1990-12-01

    An important new frontier is being opened in steel processing with the emergence of thin strip casting. Casting steel directly to thin strip has enormous benefits in energy savings by potentially eliminating the need for hot reduction in a hot strip mill. This has been the driving force for numerous current research efforts into the direct strip casting of steel. The US Department of Energy initiated a program to evaluate the development of thin strip casting in the steel industry. In earlier phases of this program, planar flow casting on an experimental caster was studied by a team of engineers from Westinghouse Electric corporation and Armco Inc. A subsequent research program was designed as a fundamental and developmental study of both planar and melt overflow casting processes. This study was arranged as several separate and distinct tasks which were often completed by different teams of researchers. An early task was to design and build a water model to study fluid flow through different designs of planar flow casting nozzles. Another important task was mathematically modeling of melt overflow casting process. A mathematical solidification model for the formation of the strip in the melt overflow process was written. A study of the material and conditioning of casting substrates was made on the small wheel caster using the melt overflow casting process. This report discusses work on the development of thin steel casting.

  17. Weldability of a high purity offshore cast steel

    Energy Technology Data Exchange (ETDEWEB)

    Koivula, J.; Katila, R.; Liimatainen, J.; Martikainen, H.

    1989-01-01

    High purity, high strength cast steels with excellent weldability have been developed for offshore components with wall thicknesses up to 200 mm. The three new steel grades developed were given the designations OS 340, OS 540, and OS 690 according to their respective guaranteed yield strengths. The strengthening of OS steels is based mainly on solid solution hardening. Microalloying is not used because of weldability requirements. As a result of the ultra-low impurity content and low carbon contents the grain boundaries are clean of carbides, segregated impurities, and non-metallic inclusions, which contribute to the excellent toughness of these steels. (author).

  18. The heat treatment of Fermanal cast steel

    Directory of Open Access Journals (Sweden)

    F. Binczyk

    2007-12-01

    Full Text Available The study discloses the results of microstructural examinations, testing of magnetic properties and hardness measurements as cast and after heat treatment conducted on the Fermanal cast steel. A characteristic feature of this cast steel is its density lower by about 10% than the density of carbon cast steel [4]. It has been proved that the factor deciding about the composition of microstructure (fraction of ferrite and austenite is the content of aluminium. The matrix totally austenitic is present in cast steel containing from 0,8 to 0,9% C, from 22 to 24% Mn, and from 4,5 to 5,5% Al. The magnetic properties examined on samples of the Fermanal cast steel were determined by spectroscopy of the Mössbauer effect with isotope 57Fe. The magnetic properties represented by a mean value of the hyperfine magnetic field Bhf and relative magnetic permeability were determined. It has been stated that the level of magnetic properties of the Fermanal cast steel depends on the content of ferrite. The effect of the parameters of solutioning and ageing on the cast steel microstructure and hardness after modification with additions of B, Ti and Nb was investigated.

  19. Clean Production of Steel and Refractories in China's Steel Industry

    Institute of Scientific and Technical Information of China (English)

    SU Tiansen

    2002-01-01

    The paper describes the importance of clean production of steel and the relationships amongst sustaining development of steel industry, environment protection and the role of refractories in the clean production of steel. The main achievements and main shortcomings in the clean production of China' s steel industry have been reviewed together with the introduction of the policy supporting system and the future development of clean production in China' s steel industry.

  20. 46 CFR 59.20-1 - Carbon-steel or alloy-steel castings.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Carbon-steel or alloy-steel castings. 59.20-1 Section 59... BOILERS, PRESSURE VESSELS AND APPURTENANCES Welding Repairs to Castings § 59.20-1 Carbon-steel or alloy-steel castings. Defects in carbon-steel or alloy-steel castings may be repaired by welding. The...

  1. Clean ferrous casting technology research. Final technical report, September 29, 1993--December 31, 1995

    Energy Technology Data Exchange (ETDEWEB)

    Bates, C.E.; Griffin, J.; Giese, S.R.; Lane, A.M. [and others

    1996-01-31

    This is the final report covering work performed on research into methods of attaining clean ferrous castings. In this program methods were developed to minimize the formation of inclusions in steel castings by using a variety of techniques which decreased the tendency for inclusions to form during melting, casting and solidification. In a second project, a reaction chamber was built to remove inclusions from molten steel using electromagnetic force. Finally, a thorough investigation of the causes of sand penetration defects in iron castings was completed, and a program developed which predicts the probability of penetration formation and indicates methods for avoiding it.

  2. Clean Ferrous Casting Technology Research. Annual report, September 29, 1993--September 28, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Stefanescu, D.M.; Lane, A.M.; Giese, S.R.; Pattabhi, R.; El-Kaddah, N.H.; Griffin, J.; Bates, C.E.; Piwonka, T.S.

    1994-10-01

    This annual report covers work performed in the first year of research on Clean Ferrous Casting Technology Research. During this year the causes of penetration of cast iron in sand molds were defined and a program which predicts the occurrence of penetration was written and verified in commercial foundries. Calculations were made to size a reaction chamber to remove inclusions from liquid steel using electromagnetic force and the chamber was built. Finally, significant progress was made in establishing pouring practices which avoid re-oxidation of steel during pouring application of revised pouring practices have led to reduced inclusion levels in commercially poured steel castings.

  3. Cracks in high-manganese cast steel

    Directory of Open Access Journals (Sweden)

    A. Chojecki

    2009-10-01

    Full Text Available The reasons which account for the formation of in service cracks in castings made from Hadfield steel were discussed. To explain the source of existence of the nuclei of brittle fractures, the properties of cast steel were examined within the range of solidification temperatures, remembering that feeding of this material is specially difficult, causing microporosity in hot spots. This creates conditions promoting the formation of microcracks which tend to propagate during service conditions involving high dynamic stresses, and explains why the cracks are mainly characterized by a brittle nature. The reason for crack formation in service are micro-porosities formed during casting solidification.

  4. Rare Earth Additions in Continuously Cast Steel

    Science.gov (United States)

    Wilson, William G.; Heaslip, L. J.; Sommerville, I. D.

    1985-09-01

    Rare earth (lanthanide metals) addiiions to continuously cast steel are particularly advantageous because of their ability to refine as-cast structures, reduce segregation and increase hot ductility at temperatures just below that of solidification. The complete shape control of sulfides in steels containing Rare Earth Metals (REM), whether continuously cast or ingot cast, is primarily responsible for improvements in ductility related mechanical properties, weldability, fatigue resistance and resistance to hydrogen damage. Complete sulfide shape control can be obtained with REM additions at sulfur levels as high as.020%. The greatest improvements, however, are obtained with REM additions to low sulfur steels. However, to achieve full operational advantages afforded by REM, nozzle blockage problems must be circumvented. Water model studies indicate a possible solution.

  5. The World's Largest Steel Casting Poured Successfully

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ The world's largest steel casting -- the upper beam (or the top head) for free forging oil hydraulic press with a 18,000-ton force capacity, was poured successfully by CITIC Heavy Machinery Co., Ltd. (CITICHM) on May 22, 2008. This head piece is 11.95 meters long, 3.8 meters wide, 4.59 meters high and about 520 tons in gross weight. Pouring is the most important and critical step during its manufacturing process. The production of this huge casting requires about 830 tons of refined molten steel from 10 smelting furnaces and pouring with six ladles into the mold cavity at one time, which made it currently the world's largest steel casting poured and the most one-time molten steel organized.

  6. The quality of the joint between alloy steel and unalloyed cast steel in bimetallic layered castings

    Directory of Open Access Journals (Sweden)

    T. Wróbel

    2012-01-01

    Full Text Available In paper is presented technology of bimetallic layered castings based on founding method of layer coating directly in cast process so-called method of mould cavity preparation. Prepared castings consist two fundamental parts i.e. bearing part and working part (layer. The bearing part of bimetallic layered casting is typical foundry material i.e. ferritic-pearlitic unalloyed cast steel, whereas working part (layer is plate of austenitic alloy steel sort X2CrNi 18-9. The ratio of thickness between bearing and working part is 8:1. The aim of paper was assessed the quality of the joint between bearing and working part in dependence of pouring temperature and carbon concentration in cast steel. The quality of the joint in bimetallic layered castings was evaluated on the basis of ultrasonic non-destructive testing, structure and microhardness researches.

  7. Yield Improvement in Steel Casting (Yield II)

    Energy Technology Data Exchange (ETDEWEB)

    Richard A. Hardin; Christoph Beckermann; Tim Hays

    2002-02-18

    This report presents work conducted on the following main projects tasks undertaken in the Yield Improvement in Steel Casting research program: Improvement of Conventional Feeding and Risering Methods, Use of Unconventional Yield Improvement Techniques, and Case Studies in Yield Improvement. Casting trials were conducted and then simulated using the precise casting conditions as recorded by the participating SFSA foundries. These results present a statistically meaningful set of experimental data on soundness versus feeding length. Comparisons between these casting trials and casting trials performed more than forty years ago by Pellini and the SFSA are quite good and appear reasonable. Comparisons between the current SFSA feeding rules and feeding rules based on the minimum Niyama criterion reveal that the Niyama-based rules are generally less conservative. The niyama-based rules also agree better with both the trials presented here, and the casting trails performed by Pellini an d the SFSA years ago. Furthermore, the use of the Niyama criterion to predict centerline shrinkage for horizontally fed plate sections has a theoretical basis according to the casting literature reviewed here. These results strongly support the use of improved feeding rules for horizontal plate sections based on the Niyama criterion, which can be tailored to the casting conditions for a given alloy and to a desired level of soundness. The reliability and repeatability of ASTM shrinkage x-ray ratings was investigated in a statistical study performed on 128 x-rays, each of which were rated seven different times. A manual ''Feeding and Risering Guidelines for Steel Castings' is given in this final report. Results of casting trials performed to test unconventional techniques for improving casting yield are presented. These use a stacked arrangement of castings and riser pressurization to increase the casting yield. Riser pressurization was demonstrated to feed a casting up to

  8. Aging degradation of cast stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, O.K.; Chung, H.M.

    1985-10-01

    A program is being conducted to investigate the significance of in-service embrittlement of cast-duplex stainless steels under light-water reactor operating conditions. Data from room-temperature Charpy-impact tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 450/sup 0/C are presented and compared with results from other studies. Microstructures of cast-duplex stainless steels subjected to long-term aging either in the laboratory or in reactor service have been characterized. The results indicate that at least two processes contribute to the low-temperature embrittleent of duplex stainless steels, viz., weakening of the ferrite/austenite phase boundary by carbide precipitation and embrittlement of ferrite matrix by the formation of additional phases such as G-phase, Type X, or the ..cap alpha..' phase. Carbide precipitation has a significant effect on the onset of embrittlement of CF-8 and -8M grades of stainless steels aged at 400 or 450/sup 0/C. The existing correlations do not accurately represent the embrittlement behavior over the temperature range 300 to 450/sup 0/C. 18 refs., 13 figs.

  9. Fabrication and ageing of cast austenitic steels

    International Nuclear Information System (INIS)

    An investigation has been undertaken to determine the magnitude of any reduction in properties which may occur in cast duplex stainless steels and weldments during long term exposure to reactor operating conditions. Test panels were fabricated in CF3 stainless steel by a manual metal arc (MMA) process using 19.9.L (Type 308L) consumables. The mechanical properties and intergranular corrosion resistance of parent material and weldments were measured following accelerated ageing at 3750 and 4000C for up to 10,000 hours. Both the impact energy and J/sub R/ fracture toughness properties of the cast austenitic/ferritic stainless steel were reduced following aging at 4000C for 10,000 hours, whereas austenitic stainless steel MMA weld metals exhibited a reduction in J/sub R/ fracture toughness but no change in impact energy. Even in the unaged state, MMA weld metals were shown to have a much lower resistance to stable crack growth than the parent cast steel, and, following aging, there is a further reduction in the ductile tearing resistance of such weld metals. Therefore, in any assessment of the structural integrity of the reactor coolant pump bowl for a pressurized water reactor (PWR), the weld metal fracture properties during service are likely to be of considerable importance

  10. Aging degradation of cast stainless steel

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast-duplex stainless steels under light-water reactor operating conditions. Data from room-temperature Charpy-impact tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 4500C are presented and compared with results from other studies. Microstructures of cast-duplex stainless steels subjected to long-term aging either in the laboratory or in reactor service have been characterized. The results indicate that at least two processes contribute to the low-temperature embrittleent of duplex stainless steels, viz., weakening of the ferrite/austenite phase boundary by carbide precipitation and embrittlement of ferrite matrix by the formation of additional phases such as G-phase, Type X, or the α' phase. Carbide precipitation has a significant effect on the onset of embrittlement of CF-8 and -8M grades of stainless steels aged at 400 or 4500C. The existing correlations do not accurately represent the embrittlement behavior over the temperature range 300 to 4500C. 18 refs., 13 figs

  11. Aging degradation of cast stainless steel

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. Microstructures of cast materials subjected to long-term aging either in reactor service or in the laboratory have been characterized by TEM, SANS, and APFIM techniques. Two precipitate phases, i.e., the Cr-rich α' and Ni- and Si-rich G phase, have been identified in the ferrite matrix of the aged steels. The results indicate that the low-temperature embrittlement is primarily caused by α' precipitates which form by spinodal decomposition. The relative contribution of G phase to loss of toughness is now known. Microstructural data also indicate that weakening of ferrite/austenite phase boundary by carbide precipitates has a significant effect on the onset and extent of embrittlement of the high-carbon CF-8 and CF-8M grades of stainless steels, particularly after aging at 400 or 4500C. Data from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 4500C are presented and correlated with the microstructural results. Thermal aging of the steels results in an increase in tensile strength and a decrease in impact energy, J/sub IC/, and tearing modulus. The fracture toughness results show good agreement with the Charpy-impact data. The effects of compositional and metallurgical variables on loss of toughness are discussed

  12. Steel castings Ultrasonic examination, Part 2: Steel castings for highly stressed components

    CERN Document Server

    International Organization for Standardization. Geneva

    2004-01-01

    This European Standard specifies the requirements for the ultrasonic examination of steel castings (with ferritic structure) for highly stressed components and the methods for determining internal discontinuities by the pulse echo technique. This European Standard applies to the ultrasonic examination of steel castings which have usually received a grain refining heat treatment and which have wall thicknesses up to and including 600 mm. For greater wall thicknesses, special agreements apply with respect to test procedure and recording levels. This European Standard does not apply to austenitic steels and joint welds.

  13. Theoretical Model of Steel Continuous Casting Technology

    Institute of Scientific and Technical Information of China (English)

    C Gheorghies; I Crudu; C Teletin; C Spanu

    2009-01-01

    A theoretical model adapted for studying steel continuous casting technology was proposed.The model based on system theory contained input/output,command,and control parameters.The process was divided into five stages,i.e.,tundish,mold,guiding system,guiding-drawing system,and guiding-drawing-soft reduction system.The model can be used to describe the physicoehemical processes,thermal processes,chemical processes,and characteristics of the cast material according to the above-mentioned stages.It can also be applied to other metallurgical technologies and even to other industries (chemistry,food,etc.).

  14. Tensile-property characterization of thermally aged cast stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Michaud, W.F.; Toben, P.T.; Soppet, W.K.; Chopra, O.K. [Argonne National Lab., IL (United States)

    1994-02-01

    The effect of thermal aging on tensile properties of cast stainless steels during service in light water reactors has been evaluated. Tensile data for several experimental and commercial heats of cast stainless steels are presented. Thermal aging increases the tensile strength of these steels. The high-C Mo-bearing CF-8M steels are more susceptible to thermal aging than the Mo-free CF-3 or CF-8 steels. A procedure and correlations are presented for predicting the change in tensile flow and yield stresses and engineering stress-vs.-strain curve of cast stainless steel as a function of time and temperature of service. The tensile properties of aged cast stainless steel are estimated from known material information, i.e., chemical composition and the initial tensile strength of the steel. The correlations described in this report may be used for assessing thermal embrittlement of cast stainless steel components.

  15. Phase Transformation in Cast Superaustenitic Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Lee Phillips, Nathaniel Steven [Iowa State Univ., Ames, IA (United States)

    2006-01-01

    Superaustenitic stainless steels constitute a group of Fe-based alloys that are compositionally balanced to have a purely austenitic matrix and exhibit favorable pitting and crevice corrosion resistant properties and mechanical strength. However, intermetallic precipitates such as sigma and Laves can form during casting or exposure to high-temperature processing, which degrade the corrosion and mechanical properties of the material. The goal of this study was to accurately characterize the solid-solid phase transformations seen in cast superaustenitic stainless steels. Heat treatments were performed to understand the time and temperature ranges for intermetallic phase formations in alloys CN3MN and CK3MCuN. Microstructures were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy and wavelength dispersive spectroscopy (EDS, WDS). The equilibrium microstructures, composed primarily of sigma and Laves within purely austenitic matrices, showed slow transformation kinetics. Factors that determine the extent of transformation, including diffusion, nucleation, and growth, are discussed.

  16. Solidification control in continuous casting of steel

    Indian Academy of Sciences (India)

    S Mazumdar; S K Ray

    2001-02-01

    An integrated understanding of heat transfer during solidification, friction/lubrication at solid-liquid interface, high temperature properties of the solidifying shell etc. is necessary to control the continuous casting process. The present paper elaborates upon the knowledge developed in the areas of initial shell formation, mode of mould oscillation, and lubrication mechanism. The effect of these issues on the caster productivity and the quality of the product has been discussed. The influence of steel chemistry on solidification dynamics, particularly with respect to mode of solidification and its consequence on strength and ductility of the solidifying shell, has been dealt with in detail. The application of these basic principles for casting of stainless steel slabs and processing to obtain good quality products have been covered.

  17. Effect of cast steel production metallurgy on the emergence of casting defects

    Directory of Open Access Journals (Sweden)

    L. Čamek

    2016-10-01

    Full Text Available The paper documents metallurgical possibilities of high alloy cast steel production in open induction medium frequency furnaces and an electric arc furnace in a gravity die casting foundry. The observation was focused on the emergence of gas defects in steel castings. The content of gases achieved during the metallurgical processes was evaluated for every unit of the production equipment and the casting ladle before casting into disposable sand moulds. The sand mould area was considered to be constant. The aim was to evaluate the current metallurgical possibilities of affecting the content of gases in high alloy cast steel in the current technical conditions of the foundry.

  18. Aging degradation of cast stainless steel

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. Microstructures of cast materials subjected to long-term aging either in reactor service or in the laboratory have been characterized by TEM, SANS, and APFIM techniques. Two precipitate phases, i.e., the Cr-rich α' phase and the Ni- and Si-rich G phase, have been identified in the ferrite matrix of the aged steels. The results indicate that the low-temperature embrittlement is primarily caused by α' precipitates which form by spinodal decomposition. The relative contribution of the G phase to loss of toughness is now known. Microstructural data also indicate that weakening of the ferrite/austenite phase boundary by carbide precipitates has a significant effect on the onset and extent of embrittlement of the high-carbon CF-8 and CF-8M grades of stainless steels, particularly after aging at 400 or 4500C. Data from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 4500C are presented and correlated with the microstructural results. Thermal aging of the steels results in an increase in tensile strength and a decrease in impact energy, J/sub IC/, and tearing modulus. The fracture toughness results show good agreement with the Charpy-impact data. The effects of compositional and metallurgical variables on loss of toughness are discussed

  19. Prediction of quenched and tempered steel and cast steel properties

    Directory of Open Access Journals (Sweden)

    B. Smoljan

    2011-12-01

    Full Text Available Purpose: The influence of processing parameters, such as pouring temperature and cooling rate during the casting, as well as application of hot working and pre-heat treatment, on strength and toughness of quenched and tempered steel was investigated.Design/methodology/approach: Strength and toughness were presented by yield strength and Charpy-V notch toughness, respectively. Experimental procedure of material properties optimization was done using the 25-2 factor experiment.Findings: It was found out that yield strength is insensitive on differences between applied manufacturing processes, but by application of hot working and with appropriate pouring temperature the Charpy-V notch toughness is increased. Also, Charpy-V notch toughness is increased by interactive effect of the appropriate cooling rate during the casting and application of hot working.Research limitations/implications: The research was focused mainly on Charpy-V notch toughness of carbon and low alloyed heat treatable steels.Practical implications: The established algorithms can be used for prediction of tensile strength, yield strength and Charpy-V notch toughness in heat treating practice.Originality/value: Original relation for prediction of quenched and tempered steel and cast steel Charpy-V notch toughness are developed.

  20. Prediction of quenched and tempered steel and cast steel properties

    OpenAIRE

    B. Smoljan; D. Iljkić; H. Novak

    2011-01-01

    Purpose: The influence of processing parameters, such as pouring temperature and cooling rate during the casting, as well as application of hot working and pre-heat treatment, on strength and toughness of quenched and tempered steel was investigated.Design/methodology/approach: Strength and toughness were presented by yield strength and Charpy-V notch toughness, respectively. Experimental procedure of material properties optimization was done using the 25-2 factor experiment.Findings: It was ...

  1. Phase Transformations in Cast Duplex Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Yoon-Jun Kim

    2004-12-19

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as {sigma} and {chi} can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ({sigma} + {chi}) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, {sigma} was stabilized with increasing Cr addition and {chi} by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in

  2. Phase transformations in cast duplex stainless steels

    Science.gov (United States)

    Kim, Yoon-Jun

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as sigma (sigma) and chi (chi) can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase (sigma + chi) formation were analyzed using the Johnson-Mehl-Avrami (JMA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities, a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, a was stabilized with increasing Cr addition and chi by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in

  3. Assessment of thermal embrittlement of cast stainless steels

    International Nuclear Information System (INIS)

    A procedure and correlations are presented for assessing thermal embrittlement and predicting Charpy-impact energy and fracture toughness J-R curve of cast stainless steel components under Light Water Reactor operating conditions from known material information. The ''saturation'' impact strength and fracture toughness of a specific cast stainless steel, i.e., the minimum value that would be achieved for the material after long-term service, is estimated from the chemical composition of the steel. Fracture properties as a function of time and temperature of reactor service are estimated from the kinetics of embrittlement, which are also determined from chemical composition. A common ''predicted lower-bound'' J-R curve for cast stainless steels of unknown chemical composition is also defined for a given grade of steel, ferrite content, and temperature. Examples of estimating fracture toughness of cast stainless steel components during reactor service are presented

  4. Heat Treatment Procedure Qualification for Steel Castings

    Energy Technology Data Exchange (ETDEWEB)

    Mariol Charles; Nicholas Deskevich; Vipin Varkey; Robert Voigt; Angela Wollenburg

    2004-04-29

    Heat treatment practices used by steel foundries have been carefully studied as part of comprehensive heat treatment procedure qualification development trials. These studies highlight the relationships between critical heat treatment process control parameters and heat treatment success. Foundry heat treatment trials to develop heat treatment procedure qualifications have shed light on the relationship between heat treatment theory and current practices. Furnace load time-temperature profiles in steel foundries exhibit significant differences depending on heat treatment equipment, furnace loading practice, and furnace maintenance. Time-temperature profiles of furnace control thermocouples can be very different from the time-temperature profiles observed at the center of casting loads in the furnace. Typical austenitization temperatures and holding times used by steel foundries far exceed what is required for transformation to austenite. Quenching and hardenability concepts were also investigated. Heat treatment procedure qualification (HTPQ) schema to demonstrate heat treatment success and to pre-qualify other alloys and section sizes requiring lesser hardenability have been developed. Tempering success is dependent on both tempering time and temperature. As such, furnace temperature uniformity and control of furnace loading during tempering is critical to obtain the desired mechanical properties. The ramp-up time in the furnace prior to the establishment of steady state heat treatment conditions contributes to the extent of heat treatment performed. This influence of ramp-up to temperature during tempering has been quantified.

  5. Effect of annealing on mechanical properties of ledeburitic cast steel

    Directory of Open Access Journals (Sweden)

    E. Rożniata

    2007-01-01

    Full Text Available Purpose: The paper presents evaluation of influence of grain normalization (refinement as a result of repeatedaustenitizing, and the inclination to precipitate the hypereutectoid cementite in Widmannstätten structure inG200CrMoNi4-6-3 cast steel. Four temperatures of heat refining have been applied.Design/methodology/approach: Basic research of G200CrMoNi4-6-3 cast steel included metallographicanalysis, and hardness and impact strength tests. The heat treatment has been planned on the basis of CCTdiagram prepared for that alloy cast steel.Findings: The test material has been G200CrMoNi4-6-3 hypereutectoid cast steel. The evaluation has beencarried out for four annealing temperatures, i.e. 850°C, 900°C, 950°C and 1050°C. At all annealing temperaturesin the structure of cast steel the precipitation of hypereutectoid cementite along grain boundaries of formeraustenite took place. At the temperature of 850°C one may observe the coagulated hypereutectoid cementiteprecipitates inside of primary grains of austenite. Whereas beginning from the temperature of 900°C thecementite in G200CrMoNi4-6-3 cast steel forms distinct „subgrains” inside of primary grains of austenite.Research limitations/implications: Research financed by the Ministry of Scientific Research and InformationTechnology, grant No. 3 T08B 057 29.Practical implications: G200CrMoNi4-6-3 cast steel of ledeburite class is used mainly for rolls production.Any data related to the structure and mechanical properties of that cast steel are precious for the manufacturersand users of the mill rolls.Originality/value: The new heat treatment of G200CrMoNi4-6-3 cast steel

  6. Investigations of Protective Coatings for Castings of High-manganese Cast Steels

    Directory of Open Access Journals (Sweden)

    M. Holtzer

    2013-01-01

    Full Text Available When cast steel castings are made in moulding sands on matrices of high-silica sand, which has a low fire resistance the problem of theso-called chemical penetration is distinctly visible. Whereas this effect appears to a small degree only when moulding sand matrices are of chromite, zircon or olivine sands. Therefore in case of making castings of high-manganese cast steel (e.g. Hadfield steel sands not containing free silica should be applied (e.g. olivine sand or in case of a high-silica matrix protective coatings for moulds and cores should be used. Two protective coatings, magnesite alcoholic (marked as coating 1 and coating 2 originated from different producers and intended for moulds for castings of the Hadfield steel, were selected for investigations. Examinations of the basic properties were performed for these coatings: viscosity, thermal analysis, sedimentation properties, wear resistance. In order to estimate the effectiveness of protective coatings the experimental castings were prepared. When applying coating 1, the surface quality of the casting was worse and traces of interaction between the casting material (cast steel and the coating were seen. When protective coating 2 was used none interactions were seen and the surface quality was better.

  7. Energy Saving Melting and Revert Reduction (E-SMARRT): Precision Casting of Steel

    Energy Technology Data Exchange (ETDEWEB)

    Dr. Von L. Richards

    2011-09-30

    This project addresses improvements in metal casting processes by reducing scrap and reducing the cost of production, due to scrap reduction from investment casting and yield improvement offered by lost foam casting as compared to no-bake or green sand molding. The objectives for the investment casting portion of the subtask are to improve knowledge of fracture toughness of mold shells and the sources of strength limiting flaws and to understand the effects of wax reclamation procedures on wax properties. Applying 'clean steel' approaches to pouring technology and cleanliness in investment casting of steel are anticipated to improve incoming materials inspection procedures as they affect the microstructure and toughness of the shell. This project focused on two areas of study in the production of steel castings to reduce scrap and save energy: (1) Reducing the amount of shell cracking in investment cast steel production; (2) Investigate the potential of lost foam steel casting The basic findings regarding investment casting shell cracking were: (1) In the case of post pouring cracking, this could be related to phase changes in silica upon cooling and could be delayed by pouring arrangement strategies that maintained the shell surface at temperature for longer time. Employing this delay resulted in less adherent oxidation of castings since the casting was cooler at the time o fair exposure. (2) A model for heat transfer through water saturated shell materials under steam pressure was developed. (3) Initial modeling result of autoclave de-waxing indicated the higher pressure and temperature in the autoclave would impose a steeper temperature gradient on the wax pattern, causing some melt flow prior to bulk expansion and decreasing the stress on the green shell. Basic findings regarding lost foam casting of steel at atmospheric pressure: (1) EPS foam generally decomposes by the collapse mode in steel casting. (2) There is an accumulation of carbon pick-up at

  8. Simulation of continuous cast steel product solidification

    Directory of Open Access Journals (Sweden)

    Ardelean, E.

    2007-06-01

    Full Text Available Primary cooling – inside the tundish – has a great impact over the thickness of the solidified steel crust. If on exiting the tundish the crust is too thin, it can punch and break, as a result of the ferrostatic pressure exerted from the inside by the liquid steel as well as because of the weight of the molten steel. The parameters that influence the amount of dissipated heat depend on the cooling water flow of the tundish, on the pressure and temperature of the cooling water but also on the overheating of the continuously cast steel. The secondary cooling takes place at the exit of the semi-finished product from the tundish, when the solidification is supposed to take place all along the cross section of the strand. In order to achieve it, in addition to a correctly managed primary cooling, it is necessary to obtain the proper correlation of the factors that influence the secondary cooling as well: the water flow rate long the three zones of the installation and its pressure in the secondary circuit. All these have in view a proper solidification length; an intense cooling can generate cracks due to the thermal stress, while a too slow cooling can generate a partial solidification of the strand up to the cropping machine area. The paper presents a mathematical simulation of the continuously cast steel solidification.

    El enfriamiento primario del cristalizador tiene una gran importancia sobre el espesor de la costra de acero solidificado. Si al salir del cristalizador, esta costra es demasiado sutil, bajo la acción de la presión ferro estática ejercitada por el acero líquido del interior y gracias el peso propio del hilo, ésta, puede perforar resultando su rompimiento. Los parámetros que influenyen sobre la cantidad de calor cedida dependen del agua de enfriamiento del catalizador, de la presión y de la temperatura de agua de enfriamiento, pero también del sobrecalentamiento del acero fundido continuamente. A la salida del

  9. Clean Production of Steel and Refractories in China′s Steel Industry

    Institute of Scientific and Technical Information of China (English)

    SUTiansen

    2002-01-01

    The paper describes the importance of clean production of steel and the relationships amongst sustaining development of steel industry,environment protection and the role of refractories in the clean production of steel. The main achievements and main shortcomings in the clean production of China′s steel industry have been reviewed together with the introduction of the policy supporting system and the future development of clean production in China′s steel industry.

  10. Wear Property of Cast Steel Wheel Material in Rail Truck

    Institute of Scientific and Technical Information of China (English)

    MI Guo-fa; LIU Yan-lei; ZHANG Bin; FU Xiu-qin; ZHANG Hong; SONG Guo-xiang

    2009-01-01

    Wear property of material plays a key role in the service time of workpiece.A major objective in the development of new wheel materials is to improve the wear performance.The wear property of B and B+ grade cast steel materials was reported.The results showed that B+ grade cast steel material exhibited better wear property than the B grade material.Carbon content related to the hardness match was the principal factor affecting the wear properties.

  11. Yield improvement and defect reduction in steel casting

    Energy Technology Data Exchange (ETDEWEB)

    Kent Carlson

    2004-03-16

    This research project investigated yield improvement and defect reduction techniques in steel casting. Research and technology development was performed in the following three specific areas: (1) Feeding rules for high alloy steel castings; (2) Unconventional yield improvement and defect reduction techniques--(a) Riser pressurization; and (b) Filling with a tilting mold; and (3) Modeling of reoxidation inclusions during filling of steel castings. During the preparation of the proposal for this project, these areas were identified by the High Alloy Committee and Carbon and Low Alloy Committee of the Steel Founders' Society of America (SFSA) as having the highest research priority to the steel foundry industry. The research in each of the areas involved a combination of foundry experiments, modeling and simulation. Numerous SFSA member steel foundries participated in the project through casting trials and meetings. The technology resulting from this project will result in decreased scrap and rework, casting yield improvement, and higher quality steel castings produced with less iteration. This will result in considerable business benefits to steel foundries, primarily due to reduced energy and labor costs, increased capacity and productivity, reduced lead-time, and wider use and application of steel castings. As estimated using energy data provided by the DOE, the technology produced as a result of this project will result in an energy savings of 2.6 x 10{sup 12} BTU/year. This excludes the savings that were anticipated from the mold tilting research. In addition to the energy savings, and corresponding financial savings this implies, there are substantial environmental benefits as well. The results from each of the research areas listed above are summarized.

  12. Advanced manufacturing technologies of large martensitic stainless steel castings with ultra low carbon and high cleanliness

    Directory of Open Access Journals (Sweden)

    Lou Yanchun

    2010-11-01

    Full Text Available The key manufacturing technologies associated with composition, microstructure, mechanical properties, casting quality and key process control for large martensitic stainless steel castings are involved in this paper. The achievements fully satisfied the technical requirements of the large 700 MW stainless steel hydraulic turbine runner for the Three Gorges Hydropower Station, and become the major technical support for the design and manufacture of the largest 700 MW hydraulic turbine generator unit in the world developed through our own efforts. The characteristics of a new high yield to tensile strength (Rp0.2/Rm ratio and high obdurability martensitic stainless steel with ultra low carbon and high cleanliness are also described. Over the next ten years, the large martensitic stainless steel castings and advanced manufacturing technologies will see a huge demand in clean energy industry such as nuclear power, hydraulic power at home and abroad. Therefore, the new high yield o tensile strength (Rp0.2/Rm ratio and high obdurability martensitic stainless steel materials, the fast and flexible manufacturing technologies of large size castings, and new environment friendly sustainable process will face new challenges and opportunities.

  13. Embrittlement of cast stainless steels in LWR systems

    International Nuclear Information System (INIS)

    Mechanical property data from Charpy-impact and J-R curve tests are presented for several experimental and commercial heats, as well as reactor-aged material of CF-3, CF-8, and CF-8M grades of cast stainless steel. The effects of material variables on the embrittlement of cast stainless steels are evaluated. The chemical composition and ferrite morphology have a strong effect on the extent and kinetics of embrittlement. The data are analyzed to establish the mechanisms of embrittlement. The procedure and correlations for predicting the impact strength and fracture toughness of cast components during reactor service are described. The lower bound values of impact strength and fracture toughness for low-temperature aged cast stainless steel are defined. 13 refs., 13 figs., 3 tabs

  14. Aging of maraging steel welds during aluminium alloy die casting

    OpenAIRE

    Klobčar, Damjan; Pleterski, Matej; Taljat, Boštjan; Kosec, Ladislav; Tušek, Janez

    2015-01-01

    The aim of this study is to evaluate precipitation annealing of 18% Ni maraging steel repair welds during aluminium die casting and to predict the prolonged in-service tool life. The emphasis of this study is the influence ofpost-weld precipitation annealing heat treatment and aluminium die casting thermal cycling on metallurgical and mechanical properties. A series of specimens of 1.2344 tool steel is prepared to which 1.6356 maraging steel is GTA weld cladded. Analysis of weld microstructur...

  15. Development of Refractories for Continuous Casting

    Institute of Scientific and Technical Information of China (English)

    TIAN Shouxin; JIN Congjin; YAO Jinfu; LI Zeya

    2004-01-01

    The paper introduces refractories for continuous casting, especially, refractories for continuous casting for clean steel in baosteel. Developing direction of refractories for continuous casting has been pointed out to satisfy the new metallurgical operating practice.

  16. Development of a thin steel strip casting process. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Williams, R.S.

    1994-04-01

    This is a comprehensive effort to develop direct strip casting to the point where a pilot scale program for casting carbon steel strip could be initiated. All important aspects of the technology were being investigated, however the program was terminated early due to a change in the business strategy of the primary contractor, Armco Inc. (focus to be directed at specialty steels, not low carbon steel). At termination, the project was on target on all milestones and under budget. Major part was casting of strip at the experiment casting facility. A new caster, capable of producing direct cast strip of up to 12 in. wide in heats of 1000 and 3000 lb, was used. A total of 81 1000-1200 lb heats were cast as well as one test heat of 3000 lb. Most produced strip of from 0.016 to 0.085 in. thick. Process reliability was excellent for short casting times; quality was generally poor from modern hot strip mill standards, but the practices necessary for good surface quality were identified.

  17. Computational algorithms to simulate the steel continuous casting

    Science.gov (United States)

    Ramírez-López, A.; Soto-Cortés, G.; Palomar-Pardavé, M.; Romero-Romo, M. A.; Aguilar-López, R.

    2010-10-01

    Computational simulation is a very powerful tool to analyze industrial processes to reduce operating risks and improve profits from equipment. The present work describes the development of some computational algorithms based on the numerical method to create a simulator for the continuous casting process, which is the most popular method to produce steel products for metallurgical industries. The kinematics of industrial processing was computationally reproduced using subroutines logically programmed. The cast steel by each strand was calculated using an iterative method nested in the main loop. The process was repeated at each time step (Δ t) to calculate the casting time, simultaneously, the steel billets produced were counted and stored. The subroutines were used for creating a computational representation of a continuous casting plant (CCP) and displaying the simulation of the steel displacement through the CCP. These algorithms have been developed to create a simulator using the programming language C++. Algorithms for computer animation of the continuous casting process were created using a graphical user interface (GUI). Finally, the simulator functionality was shown and validated by comparing with the industrial information of the steel production of three casters.

  18. INCREASING OF MECHANICAL PROPERTIES OF CAST GRAPHITIZED STEEL

    Directory of Open Access Journals (Sweden)

    I. V. Akimov

    2015-06-01

    Full Text Available Purpose. Due to the presence of many essential properties (low prime cost, high manufacturability and damping ability, heat conductivity, fluidity and others,the graphitized cast irons are widely applied for parts operating under the conditions of static and cyclic loads, wear at dry friction and aggressive media at elevated temperatures. At the same time because of significant content of the graphite phase in the structure, the cast irons possess relatively low mechanical properties. Thereby the attention is drawn to graphitized steels, the peculiarity of which consists in the presence of graphite inclusions in the structure, which appoints specific cast iron's properties to these materials. But unlike cast irons, the graphite content in them is in 2…3 times lower and it affects positively on mechanical and service properties indices. This work deals with the optimization of the composition of cast graphitized steel, which has high mechanical properties indices. Methodology. The experimental design technique was used in this work. Alloys prototypes were smelted and their mechanical properties were investigated on the basis of these techniques. Findings were exposed to regression processing, and the dependences of the alloys components influence on its properties were obtained. By means of graphical optimization the optimal composition of steel with high mechanical properties indices has been determined. Findings.Ithasbeenestablishedthat carbon and silicon have the most significant influence on the strength and cyclic endurance of graphitized steels. The chemical composition of the cast graphitized steel with high static and cyclic strength indices was suggested in this work. Originality. With the use of mathematical experimental design techniques the dependences describing the influence of carbon, silicon and copper on the static and cyclic strength indices were obtained. They allow optimizing compositions of graphitized steels. Practical

  19. Diffusion of C and Cr During Creation of Surface Layer on Cast Steel Casting

    Directory of Open Access Journals (Sweden)

    Szajnar J.

    2014-10-01

    Full Text Available In paper a method of improvement in utility properties of unalloyed cast steel casting in result of diffusion of C and Cr in process of creation of surface layer is presented. The aim of paper was determination of diffusion range of basic elements of alloyed surface layer. Moreover a quantitative analysis of carbides phase strengthens alloyed surface layer of casting was carried out. The results of studies shown that important factors of surface layer creation are maximal temperature Tmax on granular insert – cast steel boundary dependent of pouring temperature, granularity Zw of Fe-Cr-C alloy insert and thickness of casting wall gśo. On the basis of obtained results was affirmed that with increase of thickness of casting wall increases range of diffusion in solid state in Fe-Cr-C grains and in liquid state. Moreover the range of Tmax = 13001500oC favours creation of the proper alloyed surface layers on cast steel.

  20. Thermodynamic Modeling as a Strategy for Casting High Alloy Steels

    Institute of Scientific and Technical Information of China (English)

    Peri Reddy V; S Raman Sankaranarayanan

    2009-01-01

    Strategies based on thermodynamic calculations can be used to overcome the problems associated with oxides encountered in steel plant operations, which can lead to certain difficulties in the process such as clogging of submerged entry nozzle during continuous casting. Approaches to producing high alloy steels by continuous casting have been taken. One of the strategies to avoid the oxidation of chromium is to add a small amount of other elements (subject to other constraints), which do not cause subsequent problems. The problem has been studied using the Thermo-CalcR software, with related databases; and the results obtained for different process conditions or generic com-positions have been presented.

  1. Development status of ultrasonic test techniques for cast stainless steel

    International Nuclear Information System (INIS)

    Ultrasonic testing has been thought to be difficult to apply to cast stainless steel which is used as the material for the main coolant pipes in pressurized water reactors (PWRs). An ultrasonic testing technique using large aperture twin crystal transducers was developed in INSS for application to inspection of the main coolant pipes. The method was evaluated in an application to detect circumferential and axial defects in the cast stainless steel pipes. It was found that (1) the defects could be detected which had a depth that was so small that their evaluation was not required; and (2) depth sizing and length sizing of detected defects were also possible. (author)

  2. Shrinkage Prediction for the Investment Casting of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Sabau, Adrian S [ORNL

    2007-01-01

    In this study, the alloy shrinkage factors were obtained for the investment casting of 17-4PH stainless steel parts. For the investment casting process, unfilled wax and fused silica with a zircon prime coat were used for patterns and shell molds, respectively. Dimensions of the die tooling, wax pattern, and casting were measured using a Coordinate Measurement Machine in order to obtain the actual tooling allowances. The alloy dimensions were obtained from numerical simulation results of solidification, heat transfer, and deformation phenomena. The numerical simulation results for the shrinkage factors were compared with experimental results.

  3. Aging of cast duplex stainless steels in LWR systems

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. The existing data are evaluated to determine the expected embrittlement of cast components during the operating lifetime of reactors and to define the objectives and scope of the investigation. This presentation describes the status of the program. Data for the metallurgical characterization of the various cast stainless steels used in the investigation are presented. Charpy impact tests on short-term aged material indicate that CF-3 stainless steels are less susceptible to embrittlement than CF-8 or CF-8M stainless steels. Microstructural characterization of cast stainless steels that were obtained from Georg Fischer Co. and aged for up to 70,000 h at 300, 350, and 4000C reveals the formation of four different types of precipitates that are not α'. Embrittlement of the ferrite phase is primarily due to pinning of the dislocations by two of these precipitates, designated as Type M and Type X. The ferrite phase is embrittled after approx. 8 y at 3000C and shows cleavage fracture. Examination of the fracture surfaces of the impact-test specimens indicates that the toughness of the long-term aged material is determined by the austenite phase. 8 figures, 3 tables

  4. Development of Continuous Electrical Steel and Casting Technology of New Products

    Institute of Scientific and Technical Information of China (English)

    WANG Li-tao; DENG Chen-hong; DONG Mei; SHI Li-fa; ZHANG Jian-ping

    2012-01-01

    The development of continuous casting technology of electrical steel was analyzed. The technologies and products characteristics of conventional continuous casting, thin slab continuous casting and rolling, middle thin slab continuous casting and rolling and twin-roll thin strip were compared. Conventional continuous casting technology was widely adopted in producing electrical steel, thin slab continuous casting and rolling and middle thin slab contin- uous casting and roiling technology industrialized electrical steel~ and study of twin-roll thin strip casting technology was focused on fundamental experiments.

  5. Mechanical characteristics of fused cast basalt tube encased in steel pipe for protecting steel surface

    Institute of Scientific and Technical Information of China (English)

    Jee-Seok WANG; Jong-Do KIM; Hee-Jong YOON

    2009-01-01

    Because of the various excellent characteristics of cast basalt materials, such as, anti-corrosion, anti-wearing, good hardness, high chemical stability, of which steel may not possess, the steel-basalt composite pipes are used in severe environments for compensating the defects of steel. The limit of bending moment with which steel-basalt composite pipe may safely endure was calculated and the limit curvature of the composite pipe in the safe range was presented. The application temperature of steel-basalt pipe was examined due to a different coefficient among basalt, mortar and mild steel.

  6. Development of Cast Alumina-Forming Austenitic Stainless Steels

    Science.gov (United States)

    Muralidharan, G.; Yamamoto, Y.; Brady, M. P.; Walker, L. R.; Meyer, H. M., III; Leonard, D. N.

    2016-09-01

    Cast Fe-Ni-Cr chromia-forming austenitic stainless steels with Ni levels up to 45 wt.% are used at high temperatures in a wide range of industrial applications that demand microstructural stability, corrosion resistance, and creep strength. Although alumina scales offer better corrosion protection at these temperatures, designing cast austenitic alloys that form a stable alumina scale and achieve creep strength comparable to existing cast chromia-forming alloys is challenging. This work outlines the development of cast Fe-Ni-Cr-Al austenitic stainless steels containing about 25 wt.% Ni with good creep strength and the ability to form a protective alumina scale for use at temperatures up to 800-850°C in H2O-, S-, and C-containing environments. Creep properties of the best alloy were comparable to that of HK-type cast chromia-forming alloys along with improved oxidation resistance typical of alumina-forming alloys. Challenges in the design of cast alloys and a potential path to increasing the temperature capability are discussed.

  7. Hot ductility of continuously cast structural steels

    Energy Technology Data Exchange (ETDEWEB)

    Pytel, S.M. [Materials Science and Technology Institute, Cracow University of Technology, Cracow (Poland)

    1995-12-31

    The objective of this investigation was to explain the hot ductility of the structural steels characterized by different amount of carbon and morphology of sulfides. Two different rolling processes were simulated under computer controlled, high temperature deformation MTS system. Results of this study show that morphology of sulfides as well as temperature and amount of deformation are responsible for level of hot ductility of the steel tested. (author). 7 refs, 5 refs, 4 tabs.

  8. Aging degradation of cast stainless steels: Effects on mechanical properties

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water operating conditions. Mechanical property data are presented from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 450, 400, 350, 320, and 2900C. The results indicate that thermal aging increases the tensile strength and decreases the impact energy, J/sub IC/, and tearing modulus of the steels. Also, the ductile-to-brittle transition curve shifts to higher temperatures. The fracture toughness results are consistent with the Charpy-impact data, i.e., the relative reduction in J/sub IC/ is similar to the relative decrease in impact energy. The ferrite content and concentration of C in the steel have a strong effect on the overall process of low-temperature embrittlement. The low-carbon CF-3 steels are the most resistant and Mo-containing CF-8M steels are most susceptible to embrittlement. Weakening of the ferrite/austenite phase boundaries by carbide precipitates has a significant effect on the kinetics and extent of embrittlement of the high-carbon CF-8 and CF-8M steels, particularly after aging at temperatures ≥4000C. The influence of N content and distribution of ferrite on loss of toughness are discussed. The data also indicate that existing correlations do not accurately represent the embrittlement behavior over the temperature range 280 to 4500C, i.e., extrapolation of high-temperature data to reactor temperatures may not be valid for some compositions of cast stainless steel

  9. Characterization of Bimetallic Castings with an Austenitic Working Surface Layer and an Unalloyed Cast Steel Base

    Science.gov (United States)

    Wróbel, Tomasz

    2014-05-01

    The paper presents the technology of bimetallic castings based on the founding method of layer coating directly in the cast process of the so-called method of mold cavity preparation. The prepared castings consist of two fundamental parts, i.e., the base and the working surface layer. The base part of the bimetallic casting is typical foundry material, i.e., unalloyed cast steel, whereas the working layer is a plate of austenitic alloy steel sort X2CrNi 18-9. The quality of the joint between the base part and the working layer was evaluated on the basis of ultrasonic non-destructive testing and structure examinations containing metallographic macro- and microscopic studies with the use of a light microscope (LOM) with microhardness measurements and a scanning electron microscope (SEM) with microanalysis of the chemical composition (energy dispersive spectroscopy—EDS). On the basis of the obtained results it was confirmed that the decisive phenomena needed to create a permanent joint between the two components of the bimetallic casting are carbon and heat transport in the direction from the high-carbon and hot base material which was poured into the mold in the form of liquid metal to the low-carbon and cold material of the working layer which was placed in the mold cavity in the form of a monolithic insert.

  10. Study of Influence of Heat Treatment on Cyclic Properties of L21HMF Cast Steel

    Science.gov (United States)

    Mroziński, Stanisław; Golański, Grzegorz

    2016-07-01

    This work presents the results of studies of CrMoV cast steel after long-term service and after regenerative heat treatment (RHT). The cast steel was investigated in the conditions of static and changeable load. The tests were carried out at room temperature and 550 °C. The fatigue lifetime curves were determined and described using the Basquin-Manson-Coffin relationship. It has been shown that the cast steel after RHT is characterized by smaller range of plastic strain and bigger range of stress amplitude, with the same value of total strain, compared with the cast steel after service. For the cast steel after RHT, the observed fatigue properties were different in comparison with the cast steel after service at small and large strains. At room temperature (20 °C) and at elevated temperature (550 °C), there is an increase in the life of samples of the cast steel after RHT in comparison with the samples of the cast steel after service only in the area of large strains ( ɛ ac > 1.2%). For small strains ɛ ac life of the cast steel after RHT at the examined temperatures is shorter than that of the cast steel after service. The paper shows that regardless of an explicit improvement in the strength properties (the static and cyclic ones), as a result of the performed RHT, a complete improvement in the fatigue properties of the cast steel does not occur.

  11. Phase characterization in two centrifugally cast HK stainless steel tubes

    International Nuclear Information System (INIS)

    The petrochemical industry has been using 25% Cr - 20% Ni centrifugally cast stainless steel since the early 1960s in reformer and pyrolysis furnaces. This class of material has replaced the traditional superalloys showing similar creep behavior, with substantial reduction in costs. The use of the centrifugal casting technique for tube production has also contributed to better quality in these components. During the past two decades, several studies have been conducted concerning the improvement in the performance of this material at high temperatures. Some of them were related to failure analysis and life prediction, while others were related to the chemical composition balance and to new alloying procedures. As a consequence, a new generation of centrifugally cast steels has been developed in the form of niobium-modified HK and HP steels. The creep resistance of these alloys appears to be dependent on the composition, morphology, and distribution of carbides that form within them. The purpose of the study reported herein is to characterize the precipitation effects occurring during long- term service in two HK-type steels, one being of basic HK composition and the other a niobium-modified alloy

  12. PROBLEMS OF MODIFICATION STEEL CASTINGS BY NANOPARTICLES

    OpenAIRE

    V. Kovalevskij; A. Zhuk; A. Kovalevskaja; S. Grigor’ev; K. Zhuk

    2015-01-01

    It is suggested to use steel shot with the structure of tempered martensite for smelt modifying in the capacity of carriermodifier. It was applied barrier nickel layer and then wolfram nano-coating (over 200 nm) along with protective cobalt layer, which prevents interreaction of oxygen with wolfram surface. Introduction of the modifier creates subcooling zone. When it interreacts with smelt the process of active mixing of the modifier with the smelt takes place. Subsequent crystallization car...

  13. Non-metallic Inclusions in Continuously Cast Aluminum Killed Steels

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    In aluminum killed steels, the size, shape, quantity and formation of non-metallic inclusions in ladle steel (before and after RH vacuum treatment) and in tundish as well as in slabs were studied by EPMA (Electron Probe Microanalysis) and by analyzing the total oxygen. The results showed that in the slabs the total oxygen was quite low and the inclusions discovered were mainly small-sized angular alumina inclusions. This indicates that most inclusions have been removed by floating out during the continuous casting process. In addition, the countermeasures were discussed to decrease the alumina inclusions in the slabs further.

  14. Description Of Alloy Layer Formation On A Cast Steel Substrate

    Directory of Open Access Journals (Sweden)

    Szajnar J.

    2015-09-01

    Full Text Available A description of alloy layer formation on a steel substrate is presented. Two types of formation are considered: diffusion of carbon and chromium into the solid from the pad in the direction of the cast steel within the FeCrC (grains and diffusion in a layer of liquid chromium cast iron formed in a preceding step. The influence of silicon in the pad on the pad’s transformation into the liquid is also examined. Solidus and liquidus temperatures of high carbon ferrochromium are determined. The larger the content of Si is used in the experiment, the lower the solidus temperature of the FeCrC alloy is observed. This results from the higher intensity of the elements’ diffusion and faster formation of the liquid.

  15. Porosity Defect Remodeling and Tensile Analysis of Cast Steel

    OpenAIRE

    Linfeng Sun; Ridong Liao; Wei Lu; Sibo Fu

    2016-01-01

    Tensile properties on ASTM A216 WCB cast steel with centerline porosity defect were studied with radiographic mapping and finite element remodeling technique. Non-linear elastic and plastic behaviors dependent on porosity were mathematically described by relevant equation sets. According to the ASTM E8 tensile test standard, matrix and defect specimens were machined into two categories by two types of height. After applying radiographic inspection, defect morphologies were mapped to the mid-s...

  16. Mechanism of Oscillation Mark Formation in Continuous Casting of Steel

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A new mechanism of oscillation mark formation has been suggested based on the deep investigation of meniscus behavior in continuous casting of steel. It's confirmed that the meniscus form is important to oscillation mark formation. The factors related to the formation of oscillation mark are discussed in detail. The longer the solid shell existed at the root of meniscus and the smaller the contact angle between meniscus and mold wall, the deeper the oscillation mark.

  17. Occupational risk assessment in the process of continuous steel casting

    OpenAIRE

    D. Szewieczek; T. Karkoszka

    2007-01-01

    Purpose: of the presented paper aimed at motivating the necessity of the implementation of Occupational Health and Safety Management System and showing the possibility of usage the estimation of threats to occupational health and safety and results of threats; in this case in the process of continuous steel casting.Design/methodology/approach: used for the research has covered the occupational health and safety risk assessment including the identification and classification of the threats, oc...

  18. PROBLEMS OF MODIFICATION STEEL CASTINGS BY NANOPARTICLES

    Directory of Open Access Journals (Sweden)

    V. Kovalevskij

    2015-01-01

    Full Text Available It is suggested to use steel shot with the structure of tempered martensite for smelt modifying in the capacity of carriermodifier. It was applied barrier nickel layer and then wolfram nano-coating (over 200 nm along with protective cobalt layer, which prevents interreaction of oxygen with wolfram surface. Introduction of the modifier creates subcooling zone. When it interreacts with smelt the process of active mixing of the modifier with the smelt takes place. Subsequent crystallization carries involving large number of crystallization centers, which leads to reduction in the structure graininess and velocity and plasticity increase by 2–3 times. 

  19. Erosion Effect of Molten Steel on Carbon Containing Refractories for Continuous Casting

    Institute of Scientific and Technical Information of China (English)

    LI Hongxia; YANG Bin; LIU Guoqi; CHENG Hepeng

    2007-01-01

    The erosion resistance of carbon containing refractories for continuous casting to molten steel was investigated by means of simulative erosion test and examining used refractories.Decolonization and reaction between molten steel and decolonization layer are main erosion process of carbon containing refractories by1 molten steel.The reactions between molten steel and oxide in refractories determine the thickness of decarbonization layer A dense layer formation on the working surface contacting with molten steel during casting will suppress decarbonization and erosion process.

  20. Analysis of the quality renovated continuous steel casting roller

    Indian Academy of Sciences (India)

    J Viňáš; J Brezinová; A Guzanová

    2013-06-01

    This paper presents the possibility of restoration of worn contact surfaces of rollers for continuous casting of steel. Permanent effort of steel producers to extend the lifespan of these components requires the implementation of new filler materials or modifying technological renovation processes to reduce the economic costs. This matter seems to be very important for the world leaders in steel production, e.g., ArcelorMittal, Tata Steel, but also for smaller concerns such as Magnitogorsk Iron and Steel Works, Salzgitter, etc. Renovation of continuous steel casting rollers, made of X12Cr13 EN 10088-1-97, was realised using submerged arc surfacing technology. Worn surface of roller was machined and surfaced using one interlayer and two cover layers. The quality of deposited layers was verified using non-destructive and destructive tests. The influence of filler material on the tribological properties of contact surfaces of deposited layers was analysed by abrasive wear test. Studies were made in the influence of surfacing parameters on cladding metal mixing (mixed) with base metal and also influence of heat introduced by welding using metallographic analysis. The experiments confirmed very good wear resistance of the applied filler metal due to dispersion strengthening caused by finely dispersed carbides and nitrides in the weld coating. The measures to be taken into account in renovation of rollers using hard surfacing, as well as the development of research in this area were also given. The experiments have confirmed that parameters used are suitable for studying filler materials.

  1. Microstructural evolution in a duplex cast steel after quench ageing process

    OpenAIRE

    Stradomski, Z.; D. Dyja

    2007-01-01

    Purpose: The effectiveness and usefulness of the quench ageing on the service properties of massive duplex cast steel was presented in this work. The mechanism of precipitation of a ε-Cu phase and its effect on the mechanical properties of the cast steel were investigated.Design/methodology/approach: The microscopic analysis of the cast steel was performed on a Zeiss Axiovert 25 optical microscope. The substructure of ferrite was examined on a JOEL JEM 3010 high-resolution transmission electr...

  2. Effects of Cr - Ni 18/9 Austenitic Cast Steel Modification by Mischmetal

    OpenAIRE

    Gajewski, M; J. Kasińska

    2012-01-01

    This paper presents the results of Cr - Ni 18/9 austenitic cast steel modifications by mischmetal. The study was conducted on industrial melts. Cast steel was melted in an electric induction furnace with a capacity of 2000 kg and a basic lining crucible. .The mischmetal was introduced into the ladle during tapping of the cast steel from the furnace. The effectiveness of modification was examined with the carbon content of 0.1% and the presence of δ ferrite in the structure of cast steel stabi...

  3. A study on centrifugal casting of high speed steel roll

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    High speed steel (HSS) rolls can replace traditional rolls such as alloyed cast iron rolls and powder metallurgical (PM) hard alloy rolls. The main reasons for the replacement are that the wear resistance of low-cost alloyed cast iron rolls is poor and the cost of high-quality PM hard alloy rolls is very high. By means of centrifugal casting, HSS rolls having excellent wear resistance have been manufactured. The hardness of the HSS roll is 65~ 67 HRC, the range of variation is smaller than 2 HRC and its impact toughness is 15 J/cm2. The wear rate of HSS rolls used in the pre-finishing stands of high-speed hot wire-rod rolling mill reaches 2.5 × 10-4 mm per ton steel. Furthermore, the manufacturing cost of HSS rolls is significantly lower than that of PM hard alloy rolls; it is only 30 percent of that of PM hard alloy rolls.

  4. Development of low-temperature high-strength integral steel castings for offshore construction by casting process engineering

    Science.gov (United States)

    Lim, Sang-Sub; Mun, Jae-Chul; Kim, Tae-Won; Kang, Chung-Gil

    2014-12-01

    In casting steels for offshore construction, manufacturing integral casted structures to prevent fatigue cracks in the stress raisers is superior to using welded structures. Here, mold design and casting analysis were conducted for integral casting steel. The laminar flow of molten metal was analyzed and distributions of hot spots and porosities were studied. A prototype was subsequently produced, and air vents were designed to improve the surface defects caused by the release of gas. A radiographic test revealed no internal defects inside the casted steel. Evaluating the chemical and mechanical properties of specimens sampled from the product revealed that target values were quantitatively satisfied. To assess weldability in consideration of repair welding, the product was machined with grooves and welded, after which the mechanical properties of hardness as well as tensile, impact, and bending strengths were evaluated. No substantive differences were found in the mechanical properties before and after welding.

  5. Long term thermal aging of cast duplex stainless steels

    International Nuclear Information System (INIS)

    Cast duplex stainless steels of CF8M and CF8 are used in major components because of their superior characteristics, such as corrosion resistance, weldability and so on. But, these stainless steels are known to have tendency of thermal aging embrittlement after long term service. Therefore, mechanical properties and metallurgical structure were investigated using materials aged at 290--400 C up to 30,000 hours. As the results show, effects of thermal aging on mechanical properties and metallurgical behavior were identified. In addition, prediction method for Charpy absorbed energy and fracture toughness was established. The following results have been obtained: (1) it was recognized that Charpy absorbed energy and fracture toughness tend to decrease and the tensile strength tend to increase with the increasing aging time; (2) it was confirmed that thermal aging embrittlement was caused by the phase separation in ferrite from the test results of APFIM; (3) in the degradation prediction model development the prediction model was applied to the material test data, including materials aged for 30,000 hours. As the results, the degradation prediction formulas for CVRT, CVHT, JIC and J6 were obtained. The toughness of cast duplex stainless steels during service could be estimated from chemical composition using this method

  6. Long term thermal aging of cast duplex stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Isao; Koyama, Masakuni [Japan Power Engineering and Inspection Corp., Tokyo (Japan); Kawaguchi, Seiichi [Mitsubishi Heavy Industries, Ltd., Takasago (Japan); Mimaki, Hidehito [Mitsubishi Heavy Industries, Ltd., Kobe (Japan); Akiyama, Mamoru; Mishima, Yoshitsugu [Univ. of Tokyo (Japan); Okubo, Tadatsune [Sophia Univ., Tokyo (Japan); Mager, T.R.

    1996-09-01

    Cast duplex stainless steels of CF8M and CF8 are used in major components because of their superior characteristics, such as corrosion resistance, weldability and so on. But, these stainless steels are known to have tendency of thermal aging embrittlement after long term service. Therefore, mechanical properties and metallurgical structure were investigated using materials aged at 290--400 C up to 30,000 hours. As the results show, effects of thermal aging on mechanical properties and metallurgical behavior were identified. In addition, prediction method for Charpy absorbed energy and fracture toughness was established. The following results have been obtained: (1) it was recognized that Charpy absorbed energy and fracture toughness tend to decrease and the tensile strength tend to increase with the increasing aging time; (2) it was confirmed that thermal aging embrittlement was caused by the phase separation in ferrite from the test results of APFIM; (3) in the degradation prediction model development the prediction model was applied to the material test data, including materials aged for 30,000 hours. As the results, the degradation prediction formulas for CVRT, CVHT, J{sub IC} and J{sub 6} were obtained. The toughness of cast duplex stainless steels during service could be estimated from chemical composition using this method.

  7. Research on Thermal Wear of Cast Hot Forging Die Steel Modified by Rare Earths

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Thermal wear of cast hot-forging die steel modified by rare earths(RE) was studied and compared with commercially used die steels. The function of RE and the mechanism of thermal wear of cast steel modified by RE were discussed. The results showed that with increasing content of RE, the wear rate of cast steel reduced at first and then increased. By adding 0.05%(mass fraction) RE, the cast hot-forging die steel with optimum thermal wear resistance was obtained, which was better than that of H13 and 3Cr2W8V. The large amount of coarse inclusions, (RE)2O2S, resulted from excessive RE, which obviously deteriorated thermal wear resistance. The mechanism of thermal wear of the modified cast die steel is oxidation wear and oxide fatigue delamination. The wear debris are lumps of Fe2O3 and Fe3O4.

  8. Thermal aging evaluation of casting stainless steel under BWR environment

    International Nuclear Information System (INIS)

    Effect of thermal aging under BWR condition on material properties of casting stainless steel were evaluated by such as Charpy impact test, using replaced BWR component material. Solution heat treatment was performed to the same material and the material properties were obtained. Comparing each material test results, impact value of thermal aging material was lower than solution heat treatment material. By the results, thermal aging effect on material properties under BWR condition was confirmed. The material properties were compared with model equation using PLM evaluation and conservativeness of model equation was confirmed. (author)

  9. Simulation of mechanical properties of forged and casted steel 42CrMo4 specimen

    Directory of Open Access Journals (Sweden)

    B. Smoljan

    2010-12-01

    Full Text Available Purpose: In this paper, the prediction of working stress of quenched and tempered shaft has been done. Prediction was done for two different manufacture processes. In the first manufacture process the shaft was made of steel and in second one the shaft was made of cast steel. The working stress was characterized by yield strength and impact toughness. The method of computer simulation of working stress was applied in workpiece of complex form.Design/methodology/approach: Hardness distribution of quenched and tempered workpiece of complex form was predicted by computer simulation of quenching using a finite volume method. Hardness of quenched and tempered steel can be expressed as function of maximal hardness of actual steel, hardness of steel with 50% of martensite in microstructure, according to the time and temperature of tempering. The algorithm of estimation of yield strength and impact energy was based on hardness, HV. Starting point in studying of the mechanical properties of steel castings can be the fact that the mechanical properties of steel castings are derived from the mechanical properties of ordinary steel metal matrix reduced by the influence of the typical as-cast structure, i.e. casting defects on those properties. Hardness and yield strength will be unaffected by most defects. The only effect will be that due to the reduction in area. Coarse as-cast microstructure of cast steel lowers ductility and toughness. Impact energy of quenched and tempered cast steel was predicted based on pouring temperature, temperature of mould during the pouring and fact that steel castings are not subjected to different metallurgical and mechanical processes of microstructure improvement in so far as wrought steels.Findings: It can be concluded that working stress of quenched and tempered shaft can be successfully predicted by proposed method.Practical implications: Estimation of hardness distribution can be based on time, relevant for structure

  10. Solidification Structure of Low Carbon Steel Strips with Different Phosphorus Contents Produced by Strip Casting

    Institute of Scientific and Technical Information of China (English)

    Na LI; Zhenyu LIU; Yiqing QIU; Zhaosen LIN; Xianghua LIU; Guodong WANG

    2006-01-01

    In the present paper, low carbon steel strips with different phosphorus contents were produced using a twin roll strip casting process. The solidification structure was studied and its features were analyzed in detail. It was found that the strips possessed a fine microstructure compared with the mould cast steels. With increasing phosphorus content more ferrite has been formed with finer grains.

  11. Study on Heterogeneous Nuclei in Cast H13 Steel Modified by Rare Earth

    Institute of Scientific and Technical Information of China (English)

    兰杰; 贺俊杰; 丁文江; 王渠东; 朱燕萍

    2001-01-01

    The dendrite segregation in cast H13 steel was weakened with RE modification treatment. Grain boundary carbide during quenching was also under control and impact toughness was improved greatly. By thermodynamic calculation, analysis of two-dimensional lattice misfitting and electron probe analysis, it is found that Ce2O3 may act as the heterogeneous nuclei of modified cast H13 steel.

  12. Aging degradation of cast stainless steel: status and program

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, O.K.; Ayrault, G.

    1983-10-01

    A program has been initiated to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. The existing data are reviewed to determine the critical parameters that control the aging behavior and to define the objectives and scope of the investigation. The test matrices for microstructural studies and mechanical property measurements are presented. The initial experimental effort is focussed on characterizing the microstructure of long-term, low-temperature aged material. Specimens from three heats of cast CF-8 and CF-8M stainless steel aged for up to 70,000 h at 300, 350, and 400/sup 0/C were obtained from George Fisher Ltd., of Switzerland. Initial analyses reveal the formation of three different types of precipitates which are not ..cap alpha..'. An FCC phase, similar to the M/sub 23/C/sub 6/ precipitates, was present in all the long-term aged material. 15 references, 10 figures, 2 tables.

  13. Porosity Defect Remodeling and Tensile Analysis of Cast Steel

    Directory of Open Access Journals (Sweden)

    Linfeng Sun

    2016-02-01

    Full Text Available Tensile properties on ASTM A216 WCB cast steel with centerline porosity defect were studied with radiographic mapping and finite element remodeling technique. Non-linear elastic and plastic behaviors dependent on porosity were mathematically described by relevant equation sets. According to the ASTM E8 tensile test standard, matrix and defect specimens were machined into two categories by two types of height. After applying radiographic inspection, defect morphologies were mapped to the mid-sections of the finite element models and the porosity fraction fields had been generated with interpolation method. ABAQUS input parameters were confirmed by trial simulations to the matrix specimen and comparison with experimental outcomes. Fine agreements of the result curves between simulations and experiments could be observed, and predicted positions of the tensile fracture were found to be in accordance with the tests. Chord modulus was used to obtain the equivalent elastic stiffness because of the non-linear features. The results showed that elongation was the most influenced term to the defect cast steel, compared with elastic stiffness and yield stress. Additional visual explanations on the tensile fracture caused by void propagation were also given by the result contours at different mechanical stages, including distributions of Mises stress and plastic strain.

  14. Occupational risk assessment in the process of continuous steel casting

    Directory of Open Access Journals (Sweden)

    D. Szewieczek

    2007-10-01

    Full Text Available Purpose: of the presented paper aimed at motivating the necessity of the implementation of Occupational Health and Safety Management System and showing the possibility of usage the estimation of threats to occupational health and safety and results of threats; in this case in the process of continuous steel casting.Design/methodology/approach: used for the research has covered the occupational health and safety risk assessment including the identification and classification of the threats, occupational risk assessment as well as calculation of its acceptabilityFindings: of the carried out researches are as follows: the realization of occupational health and safety policy using the occupational health and safety risk assessment leads to the improvement of the analyzed processes by the preventive actions, and in consequence - lowering of the occupational risk to the acceptable level. Practical implications: can refer to continuous steel casting processes and to the usage of occupational health and safety risk assessment, identification of the threats connected with physical factors in the sudden manner acting on worker as well as recommendation of the preventive actions in the form of the means of collective and individual protection and organizationaland procedural means.Originality/value: of the presented paper has the meaning both for the employees from the point of view of work in the safe and hygienic conditions, as well as for employers from the point of view of creation the proper work background and possibilities of legal and normative requirements fulfilling.

  15. Tearing resistance of aged cast austenitic stainless steels

    International Nuclear Information System (INIS)

    CF8 and CF8M type cast stainless steels containing about 10 to 25 % ferrite are used in the primary piping of light water reactors (PWRs and BWRs). It is now recognized that these materials are embrittled by thermal aging at the operating temperature (between 2900C and 3300C), mainly due to precipitation hardening of the ferrite by α', and other phases. Extensive research programs are under way in several countries to better understand the mechanisms of embrittlement and to determine the mechanical properties of components as a function of aging time and temperature. In earlier studies thermal aging embrittlement was mainly characterized by the evolutions of the tensile and Charpy impact properties. However the evaluation of reactor coolant circuit integrity through mechanical analyses requires the knowledge of fracture toughness properties. The first measurements of the tearing resistance of a CF8M type severely aged material were presented in 1983 by SLAMA, PETREQUIN and MAGER. Other contributions to the knowledge of the fracture toughness of aged materials were published, but were relative to medium or high toughness materials. The objective of this paper is to present the results of tearing resistance measurements made on a large spectrum of severely embrittled materials, which allow to give lower bound properties for aged CF8 and CF8M type cast stainless steels

  16. Optimizing casting parameters of steel ingot based on orthogonal method

    Institute of Scientific and Technical Information of China (English)

    张沛; 李学通; 臧新良; 杜凤山

    2008-01-01

    The influence and signification of casting parameters on the solidification process of steel ingot were discussed based on the finite element method (FEM) results by orthogonal experiment method. The range analysis, analysis of variance (ANOVA) and optimization project were used to investigate the FEM results. In order to decrease the ingot riser head and improve the utilization ratio of ingot, the casting parameters involved casting temperature, pouring velocity and interface heat transfer were optimized to decrease shrinkage pore and microporosity. The results show that the heat transfer coefficient between melt and heated board is a more sensitive factor. It is favor to decrease the shrinkage pore and microporosity under the conditions of low temperature, high pouring velocity and high heat transfer between melt and mold. If heat transfer in the ingot body is quicker than that in the riser, the position of shrinkage pore and microporosity will be closer to riser top. The results of optimization project show that few of shrinkage pore and microporosity reach into ingot body with the rational parameters, so the riser size can be reduced.

  17. Development of centrifugal casting high speed steel rolls

    Institute of Scientific and Technical Information of China (English)

    Hanguang Fu; Aimin Zhao; Jiandong Xing

    2003-01-01

    The present study aims at developing the high speed steel (HSS) as roll materials to replace the traditional roll materials such as the alloy cast iron and powder metallurgical (PM) hard alloy. The HSS roll billet was formed by centrifugal casting, and the billet was rough machined after soften annealing heat treatment, then it was quenched and tempered to get suitable hardness and toughness. After that the HSS roll was finish machined to the final dimension of φ285 mm in the outer diameter, φ160 mm in the inner diameter and 120 mm in width and its surface hardness was tested. Finally the HSS roll was used in high speed wire rod mill. The test results show that a high and homogeneous hardness can obtain on the work surface of HSS rolls, the surface hardness is 63-65HRC and its variation is smaller than 2HRC. The impact toughness of this kind of HSS is about 16 J/cra2. The results of on-line service investigation in high speed wire rod mill indicate that the HSS rolls have excellent wear resistance, the steel rolling quantity per mm of HSS rolls is 3120 t, the service life-span of HSS rolls is 4 times longer than that of high chromium cast iron rolls and it is close to that of the PM hard alloy rolls. The manufacturing burden of HSS rolls is obviously lower than that of the PM hard alloy rolls, it is only 25% of that of the PM hard alloy rolls.

  18. Effect of Carbon Properties on Melting Behavior of Mold Fluxes for Continuous Casting of Steels

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    During continuous casting of steel, the properties of mold fluxes strongly affect the casting performance,steel quality and environment of casting operation. The high temperature microscopy technique was used to investigate the melting behaviour of mold fluxes, and drip test method was used to determine their melting rate. The results showed that free carbon is a dominant factor in governing the melting behaviour of fluxes, and the melting rate is increased with increasing carbon reactivity and decreasing carbon content.

  19. Microstructure and mechanical properties of a new type of austempered boron alloyed high silicon cast steel

    OpenAIRE

    Chen Xiang; Li Yanxiang

    2013-01-01

    In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental results indicate that the boron alloyed high silicon cast steel comprises a dendritic matrix and interdendritic eutectic borides in as-cast condition. The dendritic matrix is made up of pearlite, ferrite, and the interdendritic eutectic boride is with a chemical formula of M2B (...

  20. Effect of thermal aging on mechanical properties of cast stainless steels

    International Nuclear Information System (INIS)

    A procedure and correlations are presented for predicting mechanical properties of cast stainless steels in service at temperatures <450 degrees C from known material information. The ''saturation'' fracture properties of a cast stainless steel, i.e., the minimum values that would be achieved for the material after long-term service, are estimated from the chemical composition of the steel. Fracture properties as a function of time and temperature of service are estimated from the kinetics of embrittlement, which are also determined from chemical composition. The correlations successfully predict fracture toughness, Charpy-impact, and tensile properties of cast stainless steels from the Shippingport-, Ringhals-, and Gundremmingen-reactor components

  1. MAGNESIA SLIDE GATE PLATES USED IN STEEL LADLES FOR CLEANER STEELS CONTINUOUS CASTING

    Directory of Open Access Journals (Sweden)

    Clenice Moreira Galinari

    2014-03-01

    Full Text Available The production of cleaner steel has been demand for a growing market in Brazil and worldwide; and for such steels with low level of inclusions, refinement with addition of calcium has been widely used. That addition leaves a remainder of calcium in steel which may form phases of low melting point with silica and alumina present in the refractory during the casting. The slide gate plates, typically aluminous, not resist a single heat at certain levels of calcium and conditions of casting steel. The alternative here is the use of non-aluminous materials such as zirconia insert; however, it is a raw material of high cost, which requires a complex manufacturing process. The big challenge for the magnesia or basic material to be used in ladles, was its low thermal shock resistance, with intense crack formation due to high expansion of MgO. In this paper, it is presented the development and improvement of Magnesia Slide Gate Plates, Basic Plates for ladles, including high capacity ladles, their characteristics and properties. Extensive industrial tests were performed in Brazilian Steel Industry with satisfactory results. Magnesia Plates showed the same performance of plates with zirconia insert, and better cost-benefit.

  2. Hypereutectoid cementite morphology and mechanical properties of Cr-Ni-Mo cast steel

    Directory of Open Access Journals (Sweden)

    E. Rożniata

    2006-04-01

    Full Text Available Purpose: The paper presents evaluation of the influence of grain normalization (refinement as a result of repeated austenitizing, cooling rate after repeated austenitizing on the morphology of hypereutectoid cementite and fracture toughness of G200CrMoNi4-6-3 cast steel. Moreover, the elimination of hypereutectoid cementite in structure of Widmannstätten type precipitates from the structure of investigated cast steel has been undertaken.Design/methodology/approach: Basic research of G200CrMoNi4-6-3 cast steel included metallographic analysis and fracture toughness research (impact strength, stress intensity factor KIc. The heat treatment has been planned on the basis of CCT diagram prepared for that cast steel.Findings: Heat treatment of investigated cast steel allows to refine the grain and eliminate from it’s structure the hypereutectoid cementite in structure of Widmannstätten type. At very low cooling rate the precipitates of hypereutectoid cementite become partially coagulated. The study of the influence of cooling rate on the mechanical properties of G200CrMoNi4-6-3 cast steel had proven that elimination of hypereutectoid cementite in structure of Widmannstätten type from the investigated cast steel structure to small degree increases it’s fracture toughness.Research limitations/implications: Research financed by the Ministry of Scientific Research and Information Technology, grant No. 3 T08B 057 29.Practical implications: G200CrMoNi4-6-3 cast steel of ledeburite class is used mainly for rolls production. Any data related to the structure and mechanical properties of that cast steel are precious for the manufacturers and users of the mill rolls.Originality/value: The new heat treatment of G200CrMoNi4-6-3 cast steel.

  3. The influence of calcium on technological properties and micropurity of steel castings

    Directory of Open Access Journals (Sweden)

    J. Hampl

    2016-07-01

    Full Text Available The paper analyzes the technological parameters, micro-purity and mechanical properties of castings of steel alloyed with calcium. The effect of calcium on the steel was analyzed on samples taken in the process of casting heavy castings and ingots of the weight of ranging from 40 000 to 60 000 kg. Samples for the determination of the liquidus temperature and the solidus temperature of cast steels were analysed using differential thermal analysis (DTA. The production of low alloyed steel grades was performed on the EAF - ASEA-SKF facilities and the production of highalloyed steels on the EAF - ASEA-SKF - SS-VOD facilities. The purity calcium was added into the steel by the injection of a stuffed profile.

  4. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Byun, Thak Sang; Yang, Ying; Overman, Nicole R.; Busby, Jeremy T.

    2016-02-28

    Cast stainless steels (CASSs) have been extensively used for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr–rich α'-phase by Spinodal decomposition of δ-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. An approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program and the results are used to describe the precipitation behaviors in duplex stainless steels. These results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  5. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    Science.gov (United States)

    Byun, T. S.; Yang, Y.; Overman, N. R.; Busby, J. T.

    2016-02-01

    Cast stainless steels (CASSs) have been extensively used for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr-rich α'-phase by Spinodal decomposition of δ-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR-relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. An approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, an equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program, and the results are used to describe the precipitation behaviors in duplex stainless steels. These results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  6. Microstructure and Abrasive Wear Resistance of 18Cr-4Ni-2.5Mo Cast Steel

    Directory of Open Access Journals (Sweden)

    B. Kalandyk

    2012-12-01

    Full Text Available An influence of a decreased Cr content on the microstructure of the highly alloyed Cr-Ni cast steel, duplex type, melted under laboratoryconditions, was characterized in the paper. The microstructure investigations were performed in the initial state and after the heat treatment (solution annealing at 1060C as well as the phase transformation kinetics at continuous cooling was measured. The wear resistance of the investigated cast steel was tested and compared with the 24%Cr-5%Ni-2.5%Mo cast steel.The Cr content decrease, in ferritic-austenitic cast steels (duplex, from 24-26%Cr to 18% leads to the changes of the castingsmicrostructure and eliminating of a brittle  phase. In dependence of the casting cooling rate, apart from ferrite and austenite, also fine martensite precipitates occur in the casting structure. It was shown that the investigated cast steel is characterised by a slightly lower wear resistance than the typical cast steel duplex grades.

  7. Fracture formation in austenitic cast steel during thermal fatigue

    Directory of Open Access Journals (Sweden)

    J. Tuleja

    2008-04-01

    Full Text Available In the paper are presented the results of numerical analyses of carburisation and thermal shock effect on fracture formation in stable austenitic cast steel of Fe–Ni–Cr–C type used in the charge–carrying elements of carburising furnaces. Using the method of finite element method, the distribution of stresses developing in carbides and their surrounding matrix were determined during rapid temperature changes. It was showed that very large tensile stresses developed in the carbides “out–coming” onto the alloy surface, regardless of the volume, type and anisotropy of properties, which could have led to their cracking as early as in the first cycles of heating and rapid cooling.

  8. Effects of Cr - Ni 18/9 Austenitic Cast Steel Modification by Mischmetal

    Directory of Open Access Journals (Sweden)

    M. Gajewski

    2012-12-01

    Full Text Available This paper presents the results of Cr - Ni 18/9 austenitic cast steel modifications by mischmetal. The study was conducted on industrial melts. Cast steel was melted in an electric induction furnace with a capacity of 2000 kg and a basic lining crucible. .The mischmetal was introduced into the ladle during tapping of the cast steel from the furnace. The effectiveness of modification was examined with the carbon content of 0.1% and the presence of δ ferrite in the structure of cast steel stabilized with titanium. The changes in the structure of cast steel and their effect on mechanical properties and intergranular corrosion were studied. It was found that rare earth metals decrease the sulfurcontent in cast steel and above all, they cause a distinct change in morphology of the δ ferrite and non-metallic inclusions. These changes have improved mechanical properties. R02, Rm, and A5 and toughness increased significantly. There was a great increase of the resistance to intergranular corrosion in the Huey test. The study confirmed the high efficiency of cast steel modification by mischmetal in industrial environments. The final effect of modification depends on the form and manner of placing mischmetal into the liquid metal and the melting technology, ie the degree of deoxidation and desulfurization of the metal in the furnace.

  9. Study on thermal aging mechanism of cast duplex stainless steel

    International Nuclear Information System (INIS)

    Cast duplex stainless steel is used for reactor coolant piping in pressurized water reactors. However, its toughness is reduced by aging after long time operation. R and D on non-destructive techniques for evaluating the level of aging during in-service inspections has been carried out. A practical technique to evaluate accuracy has not, however, been developed yet. This is because the relationship between microstructural changes and mechanical property changes has not been clearly identified. The aim of this study is to clarify the relationship between the microstructural and mechanical property changes due to aging by examining the process of generation of precipitates. The specimens used in this study were SCS 14 A centrifuged cast stainless steel with three different ferrite content types of 8, 15 and 23%. They were aged at temperatures of 350degC and 400degC for up to 10,000 hours. The mechanical properties were investigated with Charpy impact testing and Vickers hardness testing, and microstructural changes studied with a transmission electron microscope, atom probe analysis and Moessbauer spectroscopy. As a result, the Charpy impact value of the specimen with larger ferrite content decreased the most. The hardness of the austenite phase remained almost unchanged while the hardness of the ferrite phase significantly increased. The ferrite hardness increase and the phase decomposition rate were almost the same among the three specimens with different ferrite contents. G phase precipitation was observed for the ferrite materials of 15% and 23% after the long period of thermal aging. In conclusion, the thermal aging degradation can be evaluated by detecting the ferrite phase decomposition rate, the ferrite content and the G phase precipitation. (author)

  10. Mechanical properties of stainless steel castings at 4 K

    International Nuclear Information System (INIS)

    Ten heats of cast CF8M stainless steel, which is the casting equivalent of AISI 316, were produced by a commercial vendor. In five of the heats the chromium and nickel contents were varied to obtain different delta-ferritie contents, ranging from 1.1 to 28.5 percent. The other five heats all had approximately 8 percent delta-ferrite and the nitrogen content was varied from 0.02 to 0.20 percent. As was expected from previous data on weldments and wrought materials, an increase in either delta-ferrite or nitrogen content increases the yield strength. In the five heats with varying nitrogen content the increase in strength resulted in a corresponding decrease in fracture toughness. An increase in delta-ferrite content also gave a decrease in fracture toughness up to approximately 15 percent dela-ferrite. Above this level the fracture toughness remained constant with increasing delta-ferrite content. This has been shown, by metallographic and fractographic evidence, to be due to the establishment of a continuous delta-ferrite crack path, at approximately 15 percent delta-ferrite

  11. Characteristics of centrifugally cast GX25CrNiSi18-9 steel

    Directory of Open Access Journals (Sweden)

    R. Zapała

    2011-07-01

    Full Text Available The paper presents the results of microstructural examinations of the industrial heat-resistant centrifugally cast GX25CrNiSi18-9 steel characterised by increased content of Cu. The study included changes in the microstructure of base cast steel respective of the steel held at a temperature of 900 and 950°C for 48 hours. Based on the results obtained, an increase in microhardness of the examined cast steel matrix with increasing temperature was stated, which was probably caused by fine precipitates enriched in Cr, Mo, and C forming inside the matrix grains.The layer of scale formed on the tested cast steel oxidised in the atmosphere of air at 900 and 950°C was characterised by an increased tendency to degradation with increasing temperature of the conducted tests.

  12. Wearing Quality of Austenitic, Duplex Cast Steel, Gray and Spheroidal Graphite Iron

    Directory of Open Access Journals (Sweden)

    S. Pietrowski

    2012-04-01

    Full Text Available The current work presents the research results of abrasion wear and adhesive wear at rubbing and liquid friction of new austenitic, austenitic-ferritic (“duplex” cast steel and gray cast iron EN-GJL-250, spheroidal graphite iron EN-GJS-600-3, pearlitic with ledeburitic carbides and spheroidal graphite iron with ledeburitic carbides with a microstructure of the metal matrix: pearlitic, upper bainite, mixture of upper and lower bainite, martensitic with austenite, pearlitic-martensitic-bainitic-ausferritic obtained in the raw state. The wearing quality test was carried out on a specially designed and made bench. Resistance to abrasion wear was tested using sand paper P40. Resistance to adhesive wear was tested in interaction with steel C55 normalized, hardened and sulfonitrided. The liquid friction was obtained using CASTROL oil. It was stated that austenitic cast steel and “duplex” are characterized by a similar value of abrasion wear and adhesive wear at rubbing friction. The smallest decrease in mass was shown by the cast steel in interaction with the sulfonitrided steel C55. Austenitic cast steel and “duplex��� in different combinations of friction pairs have a higher wear quality than gray cast iron EN-GJL- 250 and spheroidal graphite iron EN-GJS-600-3. Austenitic cast steel and “duplex” are characterized by a lower wearing quality than the spheroidal graphite iron with bainitic-martensitic microstructure. In the adhesive wear test using CASTROL oil the tested cast steels and cast irons showed a small mass decrease within the range of 1÷2 mg.

  13. Si-STEEL Thin-Strip Prepared by Twin-Roll Continuous Casting

    Science.gov (United States)

    Yi, Yu; Zhou, Zehua; Wang, Zehua; Jiang, Shaoqun; Huang, Weidong

    The fabrication process of Si-steel thin-strip by twin-roll continuous casting was described and the quality of the obtained Si-steel thin-strip was measured. Si-steel strips with 0.5-6.5 wt.% Si content were successfully prepared, and proper parameters including pouring temperature, height of molten pool, casting speed and pouring head mode were optimized, and their mechanisms were discussed. The relationship between quality factors of Si-steel including cracks, strip thickness, impurity and process parameters such as Si content and so on were discussed. The morphologies of the strips with different Si content were studied.

  14. Influence of Trace Alloying Elements on Corrosive Resistance of Cast Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    DUAN Han-qiao; YAN Xiang; WEI Bo-kang; LIN Han-tong

    2005-01-01

    The influences of trace alloying elements niobium, vanadium and zirconium on the corrosive resistance of 18-8 type cast stainless steel have been studied in deta() orthogonal design experiments. The results show that zirconium is mainly in the form of compound inclusions, which is unfavorable to promote the corrosive resistance of the cast stainless steel. It can alleviate the disadvantageous influence of carbon addition on corrosive resistance when some elements such as vanadium and niobium exist in the steel, and niobium has a remarkable influence on the intergranular corrosive resistance but unobvious on the pitting corrosion, and vanadium has a slightly favorable influence on the corrosive resistance of the steel.

  15. Effect of Niobium on Microstructure of Cast AISI H13 Hot Work Tool Steel

    Institute of Scientific and Technical Information of China (English)

    Shahram Kheirandish; Ahmad Noorian

    2008-01-01

    The effect of niobium addition on the microstructure of cast AISI H13 hot work tool steel was evaluated by using EDX analyzer attached to the scanning electron microscope.The volume percent of eutectic area and eutectic cell size and also volume percent of different carbides of new steel,which is heat treated under different conditions,are also determined.The results show that the a niobium addition modifies the cast structure of Nb-alloyed hot work tool steel,and reduces the size and volume of eutectic cells,and increases the maximum hardness of the steel.

  16. INVESTIGATION OF PHYSICOCHEMICAL AND MECHANICAL CHARACTERISTICS OF STEEL AND CAST IRON CHIPS

    Directory of Open Access Journals (Sweden)

    O. M. Dyakonov

    2009-01-01

    Full Text Available The chemical and phase composition of steel and cast iron chips is studied, quantitative content of phases, including ferric oxides and other chemical elements chips, is determined.

  17. Final Report, Volume 1, Metallurgical Evaluation of Cast Duplex Stainless Steels and their Weldments

    Energy Technology Data Exchange (ETDEWEB)

    Wen, Songqing; Lundin, Carl, W.; Batten, Greg, W.

    2005-09-30

    Duplex stainless steels (DSS) are being specified for chloride containing environments due to their enhanced pitting and stress corrosion cracking resistance. They exhibit improved corrosion performance over the austenitic stainless steels. Duplex stainless steels also offer improved strength properties and are available in various wrought and cast forms. Selected grades of duplex stainless steel castings and their welds, in comparison with their wrought counterparts, were evaluated, regarding corrosion performance and mechanical properties and weldability. Multiple heats of cast duplex stainless steel were evaluated in the as-cast, solution annealed (SA) static cast and SA centrifugal cast conditions, while their wrought counterparts were characterized in the SA condition and in the form of as-rolled plate. Welding, including extensive assessment of autogenous welds and a preliminary study of composite welds (shielded metal arc weld (SMAW)), was performed. The evaluations included critical pitting temperature (CPT) testing, intergranular corrosion (IGC) testing, ASTM A923 (Methods A, B and C), Charpy impact testing, weldability testing (ASTM A494), ferrite measurement and microstructural evaluations. In the study, the corrosion performances of DSS castings were characterized and assessed, including the wrought counterparts for comparison. The evaluation filled the pore of lack of data for cast duplex stainless steels compared to wrought materials. A database of the pitting corrosion and IGC behavior of cast and wrought materials was generated for a greater depth of understanding for the behavior of cast duplex stainless steel. In addition, improved evaluation methods for DSS castings were developed according to ASTM A923, A262, G48 and A494. The study revealed that when properly heat treated according to the specification, (1) DSS castings have equal or better pitting and intergranular corrosion resistance than their wrought counterparts; (2) Welding reduces the

  18. Final Report, Volume 1, Metallurgical Evaluation of Cast Duplex Stainless Steels and their Weldments

    Energy Technology Data Exchange (ETDEWEB)

    Wen, Songqing; Lundin, Carl, W.; Batten, Greg, W.

    2005-09-30

    Duplex stainless steels (DSS) are being specified for chloride containing environments due to their enhanced pitting and stress corrosion cracking resistance. They exhibit improved corrosion performance over the austenitic stainless steels. Duplex stainless steels also offer improved strength properties and are available in various wrought and cast forms. Selected grades of duplex stainless steel castings and their welds, in comparison with their wrought counterparts, were evaluated, regarding corrosion performance and mechanical properties and weldability. Multiple heats of cast duplex stainless steel were evaluated in the as-cast, solution annealed (SA) static cast and SA centrifugal cast conditions, while their wrought counterparts were characterized in the SA condition and in the form of as-rolled plate. Welding, including extensive assessment of autogenous welds and a preliminary study of composite welds (shielded metal arc weld (SMAW)), was performed. The evaluations included critical pitting temperature (CPT) testing, intergranular corrosion (IGC) testing, ASTM A923 (Methods A, B and C), Charpy impact testing, weldability testing (ASTM A494), ferrite measurement and microstructural evaluations. In the study, the corrosion performances of DSS castings were characterized and assessed, including the wrought counterparts for comparison. The evaluation filled the pore of lack of data for cast duplex stainless steels compared to wrought materials. A database of the pitting corrosion and IGC behavior of cast and wrought materials was generated for a greater depth of understanding for the behavior of cast duplex stainless steel. In addition, improved evaluation methods for DSS castings were developed according to ASTM A923, A262, G48 and A494. The study revealed that when properly heat treated according to the specification, (1) DSS castings have equal or better pitting and intergranular corrosion resistance than their wrought counterparts; (2) Welding reduces the

  19. Estimation of fracture toughness of cast stainless steels in LWR systems

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the low-temperature embrittlement of cast duplex stainless steels under light water reactor (LWR) operating conditions and to evaluate possible remedies for the embrittlement problem in existing and future plants. The scope of the investigation includes the following goals: develop a methodology and correlations for predicting the toughness loss suffered by cast stainless steel components during normal and extended life of LWRs, validate the simulation of in-reactor degradation by accelerated aging, and establish the effects of key compositional and metallurgical variables on the kinetics and extent of embrittlement. Microstructural and mechanical property data are being obtained on 25 experimental heats (static-cast keel blocks and slabs) and 6 commercial heats (centrifugally cast pipes and a static-cast pump impeller and pump casing ring), as well as on reactor-aged material of CF-3, CF-8, and CF-8M grades of cast stainless steel. The ferrite content of the cast materials ranges from 3 to 30%. Charpy-impact, tensile, and J-R curve tests have been conducted on several experimental and commercial heats of cast stainless steel that were aged up to 30,000 h at temperatures of 290 to 400 degrees C. The results indicate that thermal aging at these temperatures increases the tensile strength and decreases the impact energy and fracture toughness of the steels. In general, the low-carbon CF-3 steels are the most resistant to embrittlement, and the molybdenum-containing high-carbon CF-8M steels are the least resistant. Ferrite morphology has a strong effect on the degree or extent of embrittlement, and the kinetics of embrittlement can vary significantly with small changes in the constituent elements of the cast material

  20. Quench ageing behaviour of duplex cast steel with nano-scale ε-Cu particles

    OpenAIRE

    D. Dyja; Stradomski, Z.

    2007-01-01

    Purpose: The aim of the study was to examine the effectiveness and usefulness of the quench ageing on theservice properties of massive duplex cast steel. The mechanism of precipitation of a ε-Cu phase and its effect onthe mechanical properties of the cast steel were investigated.Design/methodology/approach: The ferrite substructure was examined on a JOEL JEM HREM. The analysisof chemical composition of selected micro-regions was carried out using a scanning electron microscope. Theverificatio...

  1. Thermo-mechanical properties and cracking during solidification of thin slab cast steel

    OpenAIRE

    Santillana, M.B.

    2013-01-01

    Nowadays a vast majority of the steel produced worldwide is via the continuous casting process route because this is the most low-cost, efficient and high quality method to mass produce metal products in a variety of sizes and shapes. Most of the continuous casters are the initial manufacturing step of a product which is very close to the final shape, reducing the need for further finishing. During continuous casting the liquid steel is solidified under controlled conditions of heat extractio...

  2. Automated system of control and diagnostics of cast-steel defects in the mass production

    Science.gov (United States)

    Knyazev, S. V.; Usoltsev, A. A.; Skopich, D. V.; Fatyanova, E. A.; Dolgopolov, A. E.

    2016-09-01

    To solve the problem of efficient control over technological process in the foundry the mathematical model is required, that would connect the the input and output parameters of the object. To collect the data on cast-steels defects an automated system was developed that greatly simplifies the process of technical control and allows the problem of process parameters optimization to be solved using the criterion of defects minimization in the cast- steels.

  3. Effect of inter-critical quenching on mechanical properties of casting low-alloy steel

    OpenAIRE

    Liu Zhongli; Shang Yong

    2013-01-01

    For some casting low-alloy steels, traditional quenching and tempering heat treatments can improve the strength; however, sometimes the ductility is not satisfied. Therefore, some kind of effective heat treatment method seems necessary; one which could improve the ductility, but not seriously affect the strength. In this paper, the effect of inter-critical quenching (IQ) on the mechanical properties of casting low-alloy steel was studied. IQ was added between quenching and tempering heat trea...

  4. The high efficiency steel filters for nuclear air cleaning

    International Nuclear Information System (INIS)

    We have, in cooperation with industry, developed high-efficiency filters made from sintered stainless-steel fibers for use in several air-cleaning applications in the nuclear industry. These filters were developed to overcome the failure modes in present high-efficiency particulate air (HEPA) filters. HEPA filters are made from glass paper and glue, and they may fail when they get hot or wet and when they are overpressured. In developing our steel filters, we first evaluated the commercially available stainless-steel filter media made from sintered powder and sintered fiber. The sintered-fiber media performed much better than sintered-powder media, and the best media had the smallest fiber diameter. Using the best media, we then built prototype filters for venting compressed gases and evaluated them in our automated filter tester. 12 refs., 20 figs

  5. High efficiency steel filters for nuclear air cleaning

    International Nuclear Information System (INIS)

    The authors have, in cooperation with industry, developed high-efficiency filters made from sintered stainless-steel fibers for use in several air-cleaning applications in the nuclear industry. These filters were developed to overcome the failure modes in present high-efficiently particulate air (HEPA) filters. HEPA filters are made from glass paper and glue, and they may fail when they get hot or wet and when they are overpressured. In developing steel filters, they first evaluated the commercially available stainless-steel filter media made from sintered powder and sintered fiber. The sintered-fiber media performed much better than sintered-powder media, and the best media had the smallest fiber diameter. Using the best media, prototype filters were then built for venting compressed gases and evaluated in their automated filter tester

  6. Effect of V and N on the microstructure evolution during continuous casting of steel

    OpenAIRE

    Santillana, B; Eskin, DG; Boom, R; Katgerman, L

    2011-01-01

    Low Carbon (LC) steel is not expected to be sensitive to hot tearing and/or cracking while microalloyed steels are known for their high cracking sensitivity during continuous casting. Experience of the Direct Sheet Plant caster at Tata Steel in Ijmuiden (the Netherlands), seems to contradict this statement. It is observed that a LC steel grade has a high risk of cracking alias hot tearing, while a High Strength Low Alloyed (HSLA) steel has a very low cracking occurrence. Another HSLA steel gr...

  7. Microstructural evolution of aged heat-resistant cast steel following strain controlled fatigue

    Energy Technology Data Exchange (ETDEWEB)

    Golański, Grzegorz, E-mail: grisza@wip.pcz.pl [Institute of Materials Engineering, Czestochowa University of Technology, Armii Krajowej 19, 42-200 Częstochowa (Poland); Zielińska-Lipiec, Anna, E-mail: alipiec@agh.edu.pl [AGH University of Science and Technology, Mickiewicza 30, 30-059 Cracow (Poland); Mroziński, Stanisław, E-mail: stmpkm@utp.edu.pl [University of Technology and Life Sciences in Bydgoszcz, Al. Prof. S. Kaliskiego 7, 85-791 Bydgoszcz (Poland); Kolan, Cezary, E-mail: kolan@wip.pcz.pl [Institute of Materials Engineering, Czestochowa University of Technology, Armii Krajowej 19, 42-200 Częstochowa (Poland)

    2015-03-11

    The paper presents the results of research on the microstructure of high-chromium martensitic GX12CrMoVNbN9-1 (GP91) cast steel after the isothermal ageing process and fatigue process. The fatigue process was performed at room temperature and elevated temperature (600 °C), with the value of total strain amplitude ε{sub ac} amounting to 0.25% and 0.60%. Microstructural tests of GP91 cast steel were carried out by means of high-resolution transmission electron microscope. Quantitative study performed by means of TEM included the characteristics of changes in the dislocation substructure and morphology of M{sub 23}C{sub 6} carbides. Performed research has shown that the microstructure of the examined cast steel after ageing is characterized by partly remaining lath microstructure with numerous precipitations of the MX and M{sub 23}C{sub 6} type, as well as the Laves phase. It has been shown that the fatigue test at room temperature contributes to the process of dislocation strengthening of the examined cast steel. The increase of fatigue test temperature influences the degree of increase in the matrix softening. The degree of softening of the cast steel microstructure at elevated temperature depends also on the value of strain amplitude ε{sub ac}. The softening process of the examined cast steel was connected with the decrease of dislocation density and increase of subgrains.

  8. Submerged entry nozzle clogging during continuous casting of Al-killed steel

    Directory of Open Access Journals (Sweden)

    F. Tehovnik

    2015-04-01

    Full Text Available Nozzle clogging is a common problem in the production of continuously cast Al-killed steels. Clogging occurs when there are solid inclusions in molten steel at casting temperatures. SENs (Submerged entry nozzles from continuous casting of Al-killed low alloy steel grades with increased content of sulfur (0,020 to 0,035 % S were examined. The examinations revealed that the deposits are mainly alumina based, with spinel and sulfur inclusions and some entrapped steel melt. It was concluded that the process of clogging begins when the steel melt infiltrates the refractory and removes the protective zirconia surface, thus allowing the adhesion of fine solid aluminates, which form the deposits.

  9. Long-term embrittlement of cast duplex stainless steels in LWR systems

    International Nuclear Information System (INIS)

    This progress report summarizes work performed by Argonne National Laboratory on longterm thermal embrittlement of cast duplex stainless steels in LWR systems during the six months from April--September 1992. A procedure and correlations are presented for predicting Charpy-impact energy, tensile flow stress, fracture toughness J-R curve, tearing modulus, and JIC of aged cast stainless steels from known material information. The ''saturation'' impact strength and fracture toughness of a specific cast stainless steel, i.e., the minimum value that would be achieved for the material after long-term service, is estimated from the chemical composition of the steel. Mechanical properties as a function of time and temperature of reactor service are estimated from impact energy and flow stress of the unaged material and the kinetics of embrittlement, which are also determined from chemical composition. The JIC values are determined from the estimated J-R curve and flow stress. Examples of estimating mechanical properties of cast stainless steel components during reactor service are presented. A common ''lower-bound'' J-R curve for cast stainless steels of unknown chemical composition is also defined for a given grade of steel, ferrite content, and temperature

  10. Optimization of Heat Treatment in Aspect of Production’s Costs Reducing and Improving of Casting Quality from Duplex Cast Steel

    Directory of Open Access Journals (Sweden)

    D. Dyja

    2007-07-01

    Full Text Available The paper determines possibilities of cost optimisation in the production of GX2CrNiMoCu25-6-3-3 type duplex cast steel castings through selection of appropriate solution heat treatment temperature, which value depends on the content of alloying elements. Metallographic analysis was carried out for as-cast and heat treated cast steel. Hardness and impact strength of the cast steel were determined, which were correlated with the volume fraction of phases determined by means of ImagePro computer image analyser. It has been shown that increased carbon content creates a need to use higher treatment temperatures, thereby increasing the production cost. With increasing carbon content the cast steel hardness after solution heat treatment increases, however, crack resistance decreases

  11. Evaluation of aging of cast stainless steel components

    International Nuclear Information System (INIS)

    Cast stainless steel is used extensively in nuclear reactors for primary-pressure-boundary components such as primary coolant pipes, elbows, valves, pumps, and safe ends. These components are, however, susceptible to thermal aging embrittlement in light water reactors because of the segregation of Cr atoms from Fe and Ni by spinodal decomposition in ferrite and the precipitation of Cr-rich carbides on ferrite/austenite boundaries. A recent advance in understanding the aging kinetics is presented. Aging kinetics are strongly influenced by the synergistic effects of other metallurgical reactions that occur in parallel with spinodal decomposition, i.e., clustering of Ni, Mo, and Si solute atoms and the nucleation and growth of G-phase precipitates in the ferrite phase. A number of methods are outlined for estimating aging embrittlement under end-of-life of life-extension conditions, depending on several factors such as degree of permissible conservatism, availability of component archive material, and methods of estimating and verifying the activation energy of aging. 33 refs., 6 figs., 3 tabs

  12. Solidification microstructure of M2 high speed steel by different casting technologies

    Directory of Open Access Journals (Sweden)

    Zhou Xuefeng

    2011-08-01

    Full Text Available The present work investigated the solidification microstructure of AISI M2 high speed steel manufactured by different casting technologies, namely iron mould casting and continuous casting. The results revealed that the as-cast structure of the steel was composed of the iron matrix and the M2C eutectic carbide networks, which were greatly refined in the ingot made by continuous casting process, compared with that by the iron mould casting process. M2C eutectic carbides presented variation in their morphologies and growth characteristics in the ingots by both casting methods. In the ingot by iron mould casting, they have a plate-like morphology and grow anisotropically. However, in the ingot made by continuous casting, the carbides evolved into the fiber-like shape that exhibited little characteristics of anisotropic growth. It was noticed that the fiber-like M2C was much easier to decompose and spheroidize after heated, as a result, the carbides refined remarkably, compared with the case of plate-like carbides in the iron mould casting ingot.

  13. Rayleigh Number Criterion for Formation of A-Segregates in Steel Castings and Ingots

    DEFF Research Database (Denmark)

    Rad, M. Torabi; Kotas, Petr; Beckermann, C.

    2013-01-01

    A Rayleigh number-based criterion is developed for predicting the formation of A-segregates in steel castings and ingots. The criterion is calibrated using available experimental data for ingots involving 27 different steel compositions. The critical Rayleigh number above which A-segregates can...... be expected to form is found to be 17 ± 8. The primary source of uncertainty in this critical value is the dendrite arm spacing. The Rayleigh number criterion of the current study is implemented in a casting simulation code and used to predict A-segregates in three case studies involving steel sand castings......, the primary reason for this over-prediction is persumed to be the presence of a central zone of equiaxed grains in the casting sections. A-segregates do not form when the grain structure is equiaxed. © The Minerals, Metals & Materials Society and ASM International 2013...

  14. Influence of the cooling rate on the corrosion resistance of duplex cast steel

    Directory of Open Access Journals (Sweden)

    B. Kalandyk

    2013-01-01

    Full Text Available The results of the influence of the cooling rate of the casting made of the acid-resistant ferritic - austenitic cast steel on the microstructure and corrosion resistance are presented in the paper. Samples cut out from the walls of the casting being cooled at the cooling rate of 3,2 - 0,5 ºC/s were used in the study. Different cooling rates create favorable conditions for the segregation processes lowering properties of castings. It was found, that differences in the polarization curves occur only in the more aggressive corrosive environment. The reason of such behaviour of cast steel is the segregation of elements dissolved in austenite and the difference in the volume fraction of ferrite and austenite in the walls of the different thickness.

  15. Fracture toughness of CF8 stainless steel castings in liquid helium

    International Nuclear Information System (INIS)

    Fracture toughness measurements for CF8 stainless steel castings in liquid helium at 4 K are reported. Single-phase (austenite) and duplex (austenite + delta-ferrite) castings were tested. On the basis of estimates from J-integral data, the plane-strain fracture toughness (K/sub Ic/) of castings containing 3.2 to 14.5% delta-ferrite ranged from 84 to 179 MPa.m/sup 1/2/ at 4 K. In contrast, a fully austenitic casting (0% delta-ferrite) exhibited a K/sub Ic/ value of 331 MPa.m/sup 1/2/, which is nearly equivalent to the toughness of a wrought AISI 304 stainless steel of a similar strength. Optical and scanning electron microscopy studies indicate that the inferior toughness of castings containing delta-ferrite may be chiefly attributed to the brittlemenss of this body-centered-cubic phase at cryogenic temperatures and its distribution in the microstructure

  16. Suitability of maraging steel weld cladding for repair of die casting tooling Part II

    OpenAIRE

    Taljat, Boštjan; Klobčar, Damjan; Muhič, Mitja; Tušek, Janez; Kosec, Ladislav

    2015-01-01

    This study was done to evaluate precipitation annealing of 18% Ni maraging steel repair welds during aluminium alloy die casting and to predict the prolonged in-service tool life. The emphasis of this study was the influence of post-weld precipitation annealing heat treatment and aluminium die casting thermal cycling on metallurgical and mechanical properties. A series of specimens of 1.2344 tool steel was prepared to which 1.6356 maraging steel wasgas tungsten arc weld clad. Analysis of weld...

  17. An Informatics Based Approach to Reduce the Grain Size of Cast Hadfield Steel

    Science.gov (United States)

    Dey, Swati; Pathak, Shankha; Sheoran, Sumit; Kela, Damodar H.; Datta, Shubhabrata

    2016-04-01

    Materials Informatics concept using computational intelligence based approaches are employed to bring out the significant alloying additions to achieve grain refinement in cast Hadfield steel. Castings of Hadfield steels used for railway crossings, requires fine grained austenitic structure. Maintaining proper grain size of this component is very crucial in order to achieve the desired properties and service life. This work studies the important variables affecting the grain size of such steels which includes the compositional and processing variables. The computational findings and prior knowledge is used to design the alloy, which is subjected to a few trials to validate the findings.

  18. Research on Welding Test of Grey Cast Iron and Low-Carbon Steel

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Grey cast iron's welding itself is a complex proble m.So proper welding materials must be selected,complex welding techniques such as preheating before weldingslow cooling after welding etc,should be taken. However the carbon component in low-carbon steel is comparatively low,the carbo n of welded joint will diffuse to the low-carbon steel when it is welded with gr ey cast iron,which will cause the component of carbon greatly increased at the low-carbon steel side in HAZ,high carbon martensite and cracks ...

  19. Microstructural characterization of welded unions of cast refractory steels

    International Nuclear Information System (INIS)

    This work presents a microstructural study of welded unions of cast heat resistant (refractory) steels, type HC (29Cr-2Ni-0,4C) and HD (28Cr-5Ni-0,4C) using quantitative metallography and X-ray diffraction. Two series of alloys were prepared in an induction furnace and cast in sand molds with phenolic resin, in the classic 'Y' shape, with thicknesses of 12, 25 and 50 mm, following ASTM A395. These samples were chemically and micro structurally characterized, in order to verify their chemical composition and the presence and distribution of phases in the material. Test pieces were then cut from the test section of the 'Y' samples to produce the welded unions, which were done with a single and double bevel (X) butt, using a manual arc and one with electrodes AWS E 309 and AWS E 410. These unions were also submitted to thermal treatments of 780oC, in order to study the forced precipitation of the sigma phase, simulating service conditions in a production environment. The presence and distribution of phases in the fusion zone (welding cord) and in the thermally affected zones (TAZ) next to both sides of the cord were studied. They displayed a relatively low dilution compared to the composition of the electrodes. The presence of austenite in a ferritic matrix, with relatively small amounts of Cr23C6 and Cr7C3 carbides was shown together with an incipient presence of sigma phase. The annealing of the test pieces at temperatures close to those for the use of these materials, resulted in a new sigma precipitation, in different relative amounts, depending on the time of exposure to these temperatures. Sigma phase precipitates in low relative amounts simply from welding, but this event deserves more attention when the material is submitted to post-welding thermal treatments, or more intensely, to prolonged exposures to higher working temperatures. Quantitative metallographic techniques with contrast and coloring of phases can be used to quantify the micro-constituents; the

  20. Mathematical Modeling and Microstructure Analysis of Low Carbon Steel Strips Produced by Horizontal Single Belt Casting (HSBC)

    Science.gov (United States)

    Ge, Sa; Chang, Sheng; Wang, Tong; Calzado, Luis E.; Isac, Mihaiela; Kozinski, Janusz; Guthrie, Roderick I. L.

    2016-06-01

    The horizontal single belt casting (HSBC) process has been proposed as an efficient, economical, and environmentally friendly alternative approach to the production of ferrous alloys. Low carbon steel strips were cast using the HSBC simulator apparatus to study the characteristics and properties of the as-cast steel strips. Three-dimensional computational fluid dynamics simulations using ANSYS FLUENT 14.5 were also performed. Numerical predictions were validated against experimental casting results. Microstructural analyses and as-cast surface texture studies were conducted on low carbon steels.

  1. Microstructure and mechanical properties of a new type of austempered boron alloyed high silicon cast steel

    Directory of Open Access Journals (Sweden)

    Chen Xiang

    2013-05-01

    Full Text Available In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental results indicate that the boron alloyed high silicon cast steel comprises a dendritic matrix and interdendritic eutectic borides in as-cast condition. The dendritic matrix is made up of pearlite, ferrite, and the interdendritic eutectic boride is with a chemical formula of M2B (M represents Fe, Cr, Mn or Mo which is much like that of carbide in high chromium white cast iron. Pure ausferrite structure that consists of bainitic ferrite and retained austenite can be obtained in the matrix by austempering treatment to the cast steel. No carbides precipitate in the ausferrite structure and the morphology of borides remains almost unchanged after austempering treatments. Secondary boride particles precipitate during the course of austenitizing. The hardness and tensile strength of the austempered cast steel decrease with the increase of the austempering temperature, from 250 篊 to 400 篊. The impact toughness is 4-11 J昪m-2 at room temperature and the impact fracture fractogragh indicates that the fracture is caused by the brittle fracture of the borides.

  2. Methods of improvement in hardness of composite surface layer on cast steel

    Directory of Open Access Journals (Sweden)

    J. Szajnar

    2008-08-01

    Full Text Available The paper presents a method of usable properties of surface layers improvement of cast carbon steel 200–450, by put directly in founding process a composite surface layer on the basis of Fe-Cr-C alloy and next its remelting with use of welding technology TIG – Tungsten Inert Gas. Technology of composite surface layer guarantee mainly increase in hardness and abrasive wear resistance of cast steel castings on machine elements. This technology can be competition for generally applied welding technology (surfacing by welding and thermal spraying. However the results of studies show, that is possible to connection of both methods founding and welding of surface hardening of cast steel castings. In range of experimental plan was made test castings with composite surface layer, which next were remelted with energy 0,8 and 1,6 kJ/cm. Usability for industrial applications of test castings was estimated by criterion of hardness and abrasive wear resistance of type metal-mineral.

  3. Review of production status of heavy steel castings and key technologies for their manufacture in China

    Directory of Open Access Journals (Sweden)

    Liu Baicheng

    2008-02-01

    Full Text Available This paper expatiates on domestic status of heavy steel casting production, with a special focus on hydraulic turbine castings for Three Gorges Project. In China, there is magnificent demand for heavy castings with the rapid growth of the national economy in recent years and the expected high growth in the coming 10 to 20 years. Some heavy and large castings such as mill housing and hydraulic turbine runner crown, blade and band for Three Gorges Project have been successfully made. However, the domestic production capability is still far from meeting the gigantic requirements. The domestic capability still lags behind the world class level, and a lot of heavy castings still depend on import. The paper also gives a particular introduction of the key technologies in the manufacturing of heavy steel castings like metal melting, foundry technology, heat treatment technology and numerical simulation technique, etc. In addition, several case studies on the application of numerical simulation in the production of heavy steel castings are presented.

  4. Review of production status of heavy steel castings and key technologies for their manufacture in China

    Institute of Scientific and Technical Information of China (English)

    Kang Jinwu; Huang Tianyou; Liu Baicheng

    2008-01-01

    This paper expatiates on domestic status of heavy steel casting production, with a special focus on hydraulic turbine castings for Three Gorges Project. In China, there is magnificent demand for heavy castings with the rapid growth of the national economy in recent years and the expected high growth in the coming 10 to 20 years. Some heavy and large castings such as mill housing and hydraulic turbine runner crown, blade and band for Three Gorges Project have been successfully made. However, the domestic production capability is still far from meeting the gigantic requirements. The domestic capability still lags behind the world class level, and a lot of heavy castings still depend on import. The paper also gives a particular introduction of the key technologies in the manufacturing of heavy steel castings like metal melting, foundry technology, heat treatment technology and numerical simulation technique, etc.In addition, several case studies on the application of numerical simulation in the production of heavy steel castings are presented.

  5. Estimation of fracture toughness of cast stainless steels during thermal aging in LWR systems

    International Nuclear Information System (INIS)

    A procedure and correlations are presented for predicting the change in fracture toughness of cast stainless steel components due to thermal aging during service in light water rectors (LWRs) at 280--330 degrees C (535--625 degrees F). The fracture toughness J-R curve and Charpy-impact energy of aged cast stainless steels are estimated from known mineral in formation. Fracture toughness of a specific cast stainless steel is estimated from the extent and kinetics of thermal embrittlement. The extent of thermal embrittlement is characterized by the room-temperature ''normalized'' Charpy-impact energy. A correlation for the extent of embrittlement at ''saturation,'' i.e., the minimum impact energy that would be achieved for the material after long-term aging, is given in terms of a material parameter, Φ, which is determined from the chemical composition. The fracture toughness J-R curve for the material is then obtained from correlations between room-temperature Charpy-impact energy and fracture toughness parameters. Fracture toughness as a function of time and temperature of reactor service is estimated from the kinetics of thermal embrittlement, which is determined from chemical composition. A common ''lower-bound'' J-R curve for cast stainless steels with unknown chemical composition is also defined for a given material specification, ferrite content, and temperature. Examples for estimating impact strength and fracture toughness of cast stainless steel components during reactor service are describes. 24 refs., 39 figs., 2 tabs

  6. Corrosion resistance of various bio-films deposited on austenitic cast steel casted by lost-wax process and in gypsum mould

    Directory of Open Access Journals (Sweden)

    J. Gawroński

    2010-01-01

    Full Text Available This work is the next of a series concerning the improvement of austenitic cast steel utility predicted for use in implantology for complicated long term implants casted by lost-wax process and in gypsum mould. Austenitic cast steel possess chemical composition of AISI 316L medical steel used for implants. In further part of present work investigated cast steel indicated as AISI 316L medical steel. Below a results of electrochemical corrosion resistance of carbon layer and bi-layer of carbon/HAp deposited on AISI 316L researches are presented. Coatings were manufactured by RF PACVD and PLD methods respectively. Obtained results, unequivocally indicates on the improvement of this type of corrosion resistance by substrate material with as deposited carbon layer. While bi-layer of carbon/HAp are characterized by very low corrosion resistance.

  7. Effect of melting technology on the properties of G17CrMo5-5 steel for cast turbines

    Directory of Open Access Journals (Sweden)

    P. Mańkowski

    2010-10-01

    Full Text Available Two technologies of the G17CrMo 5-5 cast steel melting were compared, i.e. the so far used oxygen-recovery melting technology (electricarc furnace + ladle furnace – EAF + LF and a new recovery melting technology (electric induction furnace + ladle furnace - EIF + LF.The effect of the melting technology on the properties of cast steel for turbine parts was determined. The cast steel was evaluated in term of its metallurgical purity and mechanical properties. During melting of G17CrMo 5-5 steel in induction furnace, lower total content of oxygen in casting was reached, but nitrogen content was higher than it was in the cast steel from arc furnace. Metal refining in LF improved the steel desulphurising degree and contributed to modification of the non-metallic inclusions.

  8. Corrosion of two kinds of cast steels containing chromium in hot concentrated alkaline

    Institute of Scientific and Technical Information of China (English)

    LI Wei; LIU Jun-quan; TU Xiao-hui

    2007-01-01

    A typical hot concentrated alkaline corrosion environment exists in alumina metallurgical industry, so that steel materials with outstanding alkaline corrosion resistance are strongly demanded for its processing equipment. In this paper, the corrosion resistance of two kinds of martensitic cast steels containing chromium in static 303 g/L NaOH alkaline solution at 85℃ was studied through polarization and potential-time curves, corrosion weight loss and corrosion morphology analysis. Experimental results showed that protection effect by passive film of cast steel containing Cr was temporary. The low carbon steel without Cr content also exhibited chemical passivity in the same solution. The corrosion mode of the tested Cr-containing cast steel was composed of active dissolving corrosion and caustic embrittlement cracking. Dissolving corrosion was the primary mechanism for the induced weight loss, while severe caustic embrittlement cracking was secondary. With the increase of chromium content in the cast steel, the tendency of the caustic embrittlement cracking decreased, while the active dissolving corrosion increased.

  9. Estimation of mechanical properties of cast stainless steels during thermal aging in LWR systems

    International Nuclear Information System (INIS)

    A procedure and correlations are presented for predicting Charpy- impact energy, tensile flow stress, fracture toughness J-R curve, and JIC of aged cast stainless steels from known material information. The ''saturation'' impact strength and fracture toughness of a specific cast stainless steel, i.e., the minimum value that would be achieved for the material after long-term service, is estimated from the chemical composition of the steel. Mechanical properties as a function of time and temperature of reactor service are estimated from impact energy and flow stress of the unaged material and the kinetics of embrittlement, which are also determined from chemical composition. The JIC values are determined from the estimated J-R curve and flow stress. Examples of estimating mechanical properties of cast stainless steel components during reactor service are presented. A common ''lower-bound'' J-R curve for cast stainless steels of unknown chemical composition is also defined for a given grade of steel, ferrite content, and temperature

  10. Estimation of mechanical properties of cast stainless steels during thermal aging in LWR systems

    International Nuclear Information System (INIS)

    A procedure and correlations are presented for predicting Charpy-impact energy, tensile flow stress, fracture toughness J-R curve, and JIC of aged cast stainless steels from known material information. The ''saturation'' impact strength and fracture toughness of a specific cast stainless steel, i.e., the minimum value that would be achieved for the material after long-term service, is estimated from the chemical composition of the steel. Mechanical properties as a function of time and temperature of reactor service are estimated from impact energy and flow stress of the unaged material and the kinetics of embrittlement, which are also determined from chemical composition. The JIC values are determined from the estimated J-R curve and flow stress. Examples of estimating mechanical properties of cast stainless steel components during reactor service are presented. A common predicted lower-bound J-R curve for cast stainless steels of unknown chemical composition is also defined for a given grade of steel, ferrite content, and temperature

  11. Prediction of aging degradation of cast stainless steel components in LWR systems

    International Nuclear Information System (INIS)

    A procedure and correlations are presented for predicting Charpy-impact energy, tensile flow stress, fracture toughness J-R curve, and JIC of aged cast stainless steels from known material information. The ''saturation'' impact strength and fracture toughness of a specific cast stainless steel, i.e., the minimum value that would be achieved for the material after long-term service, is estimated from the chemical composition of the steel. Mechanical properties as a function of time and temperature of reactor service are estimated from impact energy and flow stress of the unaged material and the kinetics of embrittlement, which are also determined from chemical composition. The JIC values are determined from the estimated J-R curve and flow stress. Examples of estimating mechanical properties of of cast stainless steel components during reactor service are presented. A common ''predicted lower-bound' J-R curve for cast stainless steels of unknown chemical composition is also defined for a given grade of steel, ferrite content, and temperature

  12. Thermal aging of cast stainless steels in LWR systems: Estimation of mechanical properties

    International Nuclear Information System (INIS)

    A procedure and correlations are presented for predicting Charpy-impact energy, tensile flow stress, fracture toughness J-R curve, and JIC of aged cast stainless steels from known material information. The ''saturation'' impact strength and fracture toughness of a specific cast stainless steel, i.e., the minimum value that would be achieved for the material after long-term service, is estimated from the chemical composition of the steel. Mechanical properties as a function of time and temperature of reactor service are estimated from impact energy and flow stress of the unaged material and the kinetics of embrittlement, which are also determined from chemical composition. The JIC values are determined from the estimated J-R curve and flow stress. Examples of estimating mechanical properties of cast stainless steel components during reactor service are presented. A common ''lower-bound'' J-R curve for cast stainless steels of unknown chemical composition is also defined for a given grade of steel, ferrite content, and temperature

  13. Corrosion of two kinds of cast steels containing chromium in hot concentrated alkaline

    Directory of Open Access Journals (Sweden)

    LI Wei

    2007-02-01

    Full Text Available A typical hot concentrated alkaline corrosion environment exists in alumina metallurgical industry, so that steel materials with outstanding alkaline corrosion resistance are strongly demanded for its processing equipment. In this paper, the corrosion resistance of two kinds of martensitic cast steels containing chromium in static 303g/L NaOH alkaline solution at 85℃ was studied through polarization and potential-time curves, corrosion weight loss and corrosion morphology analysis. Experimental results showed that protection effect by passive film of cast steel containing Cr was temporary. The low carbon steel without Cr content also exhibited chemical passivity in the same solution. The corrosion mode of the tested Cr-containing cast steel was composed of active dissolving corrosion and caustic embrittlement cracking. Dissolving corrosion was the primary mechanism for the induced weight loss, while severe caustic embrittlement cracking was secondary. With the increase of chromium content in the cast steel, the tendency of the caustic embrittlement cracking decreased, while the active dissolving corrosion increased.

  14. Study on Type C Coal Fly ash as an Additive to Molding Sand for Steel Casting

    Science.gov (United States)

    Palaniappan, Jayanthi

    2016-05-01

    Study of physio-chemical properties studies such as granulometric analysis, moisture, X ray fluorescence etc. were performed with Type C coal—combustion fly ash to investigate their potential as a distinct option for molding sand in foundry, thereby reducing the dependency on latter. Technological properties study such as compressive strength, tensile strength, permeability and compaction of various compositions of fly ash molding sand (10, 20 and 30 % fly ash substitute to chemically bonded sand) were performed and compared with silica molding sand. Steel casting production using this fly ash molding sand was done and the casting surface finish and typical casting parameters were assessed. It was noted that a good quality steel casting could be produced using type C fly ash molding sand, which effectively replaced 20 % of traditional molding sand and binders thereby providing greater financial profits to the foundry and an effective way of fly ash utilization (waste management).

  15. The comparative studies of ADI versus Hadfield cast steel wear resistance

    Directory of Open Access Journals (Sweden)

    Mieczysław Kaczorowski

    2011-04-01

    Full Text Available The results of comparative studies of wear resistance of ADI versus high manganese Hadfield cast steel are presented. For evaluation ofwear resistance three type of ADI were chosen. Two of them were of moderate strength ADI with 800 and 1000MPa tensile strength whilethe third was 1400MPa tensile strength ADI. The specimens were cut from ADI test YII type casting poured and heat treated in Institute ofFoundry in Krakow. The pin on disc method was used for wear resistance experiment. The specimens had a shape of 40mm long rod withdiameter 6mm. The load and speed were 100N and 0,54m/s respectively. It was concluded that the wear resistance of ADI is comparablewith high manganese cast steel and in case of low tensile grade ADI and is even better for high strength ADI than Hadfield steel.

  16. Fabrication of plain carbon steel/high chromium white cast iron bimetal by a liquid-solid composite casting process

    Institute of Scientific and Technical Information of China (English)

    V Javaheri; H Rastegari; M Naseri

    2015-01-01

    High-chromium white cast iron (HCWCI) is one of the most widely used engineering materials in the mining and cement indus-tries. However, in some components, such as the pulverizer plates of ash mills, the poor machinability of HCWCI creates difficulties. The bimetal casting technique is a suitable method for improving the machinability of HCWCI by joining an easily machined layer of plain car-bon steel (PCS) to its hard part. In this study, the possibility of PCS/HCWCI bimetal casting was investigated using sand casting. The inves-tigation was conducted by optical and electron microscopy and non-destructive, impact toughness, and tensile tests. The hardness and chemical composition profiles on both sides of the interface were plotted in this study. The results indicated that a conventional and low-cost casting technique could be a reliable method for producing PCS/HCWCI bimetal. The interfacial microstructure comprised two distinct lay-ers:a very fine, partially spheroidized pearlite layer and a coarse full pearlite layer. Moreover, characterization of the microstructure revealed that the interface was free of defects.

  17. Numerical Simulation of Coupled Molten Steel Flow and Temperature Fields in Compact Strip Production Casting

    Institute of Scientific and Technical Information of China (English)

    LIU Xu-feng; ZHANG Jie-yu; DU Wei-dong; ZHAI Qi-jie; LI Qiang

    2007-01-01

    Based on the casting manufacture practice of steel slabs by CSP technology, the flow and the temperature fields of the funnel mould and the secondary cooling segment were simulated using the commercial code,CFX4. Compared with other physical investigations, the correlative data of the present simulation results are in good agreement with them. Therefore, a more comprehensive survey for metallurgy characteristic of the flow and the temperature fields in CSP continuous casting process can be achieved.

  18. Application of alcohol based spraying coating on green sand mould for steel casting

    Science.gov (United States)

    Xu, Z. L.; Wang, J.; Yang, S. S.; He, Q. L.; Xiong, H. Sh

    2015-12-01

    A kind of coating suitable for green sand steel casting was developed. The practical application showed that the strength of the coating was high enough with no crack and no peeling under room temperature after drying the spraying coating, the performance of the coating for anti-cracking was good under high temperature, and the gas evolution of the coating was low. Using the coating, the casting surfaces finish appeared very good.

  19. Long-term aging of cast stainless steels: Mechanisms and resulting properties

    International Nuclear Information System (INIS)

    Mechanical property data are presented from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 450, 400, 350, 320 and 290 deg. C. The results indicate that thermal aging increases the tensile strength and decreases the impact energy, JIC, and tearing modules of the steels. Also, the ductile-to-brittle transition curve shifts to higher temperatures. The ferrite content and concentration of carbon in the steel have a strong effect on the overall process of low-temperature embrittlement. The low-carbon CF-3 steels are the most resistant and the molybdenum-containing high-carbon CF-8M steels are the most susceptible to low-temperature embrittlement. Microstructural data indicate that three processes contribute to embrittlement of cast stainless steels, viz., Cr-rich α' and G-phase precipitation in the ferrite, and carbide precipitation on the austenite/ferrite phase boundary. The influence of nitrogen content and ferrite distribution on loss of toughness are discussed. The data also indicate that existing correlations do not accurately represent the embrittlement behavior over the temperature range 280-450 deg. C, i.e., extrapolation of high temperature data to reactor temperatures may not be valid for some compositions of cast stainless steel. (author)

  20. Simulation of Distortion and Residual Stress Development During Heat Treatment of Steel Castings

    Energy Technology Data Exchange (ETDEWEB)

    Beckermann, Christoph; Carlson, Kent

    2011-07-22

    Heat treatment and associated processing, such as quenching, are critical during high strength steel casting production. These processes must be managed closely to prevent thermal and residual stresses that may result in distortion, cracking (particularly after machining), re-work, and weld repair. The risk of casting distortion limits aggressive quenching that can be beneficial to the process and yield an improved outcome. As a result of these distortions, adjustments must be made to the casting or pattern design, or tie bars must be added. Straightening castings after heat treatments can be both time-consuming and expensive. Residual stresses may reduce a casting's overall service performance, possibly resulting in catastrophic failure. Stress relieving may help, but expends additional energy in the process. Casting software is very limited in predicting distortions during heat treatment, so corrective measures most often involve a tedious trial-and-error procedure. An extensive review of existing heat treatment residual stress and distortion modeling revealed that it is vital to predict the phase transformations and microstructure of the steel along with the thermal stress development during heat treatment. After reviewing the state-of-the-art in heat treatment residual stress and distortion modeling, an existing commercial code was selected because of its advanced capabilities in predicting phase transformations, the evolving microstructure and related properties along with thermal stress development during heat treatment. However, this software was developed for small parts created from forgings or machined stock, and not for steel castings. Therefore, its predictive capabilities for heat treatment of steel castings were investigated. Available experimental steel casting heat treatment data was determined to be of insufficient detail and breadth, and so new heat treatment experiments were designed and performed, casting and heat treating modified versions

  1. The influence of chemical constitution on abrasive wear of alloy cast steel Cr, Mo, V, Cu, Ni type

    International Nuclear Information System (INIS)

    In the work were presented some elements of a wide research programme of the influence of alloying element contents such as Cr, Mo, V on the abrasive wear of hot working cast steel. The dependence between the mass decrement quantity and the element contents on cast steel structure were shown. (author)

  2. Numerical simulation of stress field in inclusions of large rudder arm steel castings

    Institute of Scientific and Technical Information of China (English)

    Yang Dixin; Xie Jingpei; Zhang Kefeng; Liu Zongfa; Wang Aiqin; Wang Wenyan

    2009-01-01

    The influence of non-metallic inclusions on quality and performance of steel depends on not only the quantity of inclusions,but also the type,shape,size,distribution,and deformation behavior. In this paper,ANSYS finite element analysis software is used to simulate the stress field of inclusions appearing in heavy rudder arm steel castings,the effects of inclusion type,shape,distribution,and various loading conditions were studied. The micromechanics of inclusions in such castings were also analyzed. Such research provides further cladficetion on reaction mechanism of inclusions under complex loading conditions.

  3. The mechanism of the surface alloy layer creation for cast steel

    Directory of Open Access Journals (Sweden)

    A. Walasek

    2012-01-01

    Full Text Available The paper presents a detailed description of the process of creation of a surface alloy layer (using high-carbon ferrochromium on the cast steel casting. The mechanism of the surface alloy layer is based on the known theories [5,6]. The proposed course of formation of the layers has been extended to decarburization stage of steel. The research included proving the presence of carbon-lean zone. The experiment included the analysis of the distribution of elements and microhardness measurement.

  4. Influence of Vanadium and Cast Temperature on Nitrogen Solubility of Stainless Steel

    Directory of Open Access Journals (Sweden)

    Saeed Ghali

    2014-01-01

    Full Text Available Three stainless steel grades with different vanadium content were produced in open induction furnace. The base chemical composition of investigated stainless steel has contained 18.48–18.75% Cr, 5.17–5.62% Mn, 2.47–2.58% Mo, and 6.39–6.64% Ni. The vanadium contents of the three stainless steel grades were 0.009%, 0.112%, and 0.189%. The proposed stainless steels were casted at temperatures 1753 K and 1833 K. The nitrogen contents were determined for the produced steel grades at every cast temperature. The determined nitrogen contents were compared with those calculated from the developed equation of Grigorenko and Pomarin. The influence of cast temperature and vanadium content on nitrogen solubility was investigated. Interpretation between experimental and calculated nitrogen content was carried out. Increasing vanadium content and decreasing cast temperature were found to have positive significant effect on the nitrogen solubility. There were great deviations between experimental results and those calculated by Grigorenko and Pomarin equation.

  5. CHANGE OF CONNECTION BETWEEN MAGNETIC PARAMETERS OF CAST IRON IN COMPARISON WITH STEEL UNDER INFLUENCE OF INTERNAL DEMAGNETIZATION

    Directory of Open Access Journals (Sweden)

    S. G. Sandomirsky

    2014-01-01

    Full Text Available Connection of maximum magnetic permeability µm of cast irons with coercive force Нс and residual magnetism Мr is established in all size of changing of the magnetic characteristics of cast iron. Differences of this connection for steels and cast irons are revealed. Formula for calculation µm of steels by Нс and Мr is corrected for calculation µm of cast irons. As a result of correction the calculation error of cast irons µm is diminished. The results can be used in magnetic structural analysis instead of labor-consuming measurement µm.

  6. Steel-Making and Continuous/Ingot Casting Scheduling of Mixed Charging Plan Based on Batch Splitting Policy

    Institute of Scientific and Technical Information of China (English)

    LIU Wei; SUN Liang-liang

    2012-01-01

    For steel-making and continuous/ingot casting are the key processes of modern iron and steel enterprises, this paper proposes a batch splitting schedule policy to solve continuous and ingot casting schedule of mixed whole/ half charging plan for steel making. First establish the model of continuous and ingot casting schedule of mixed whole/half charging plan according to the complex constraints. Then solve this model by heuristic algorithm. Finally use actual data to prove the proposed algorithmrs validity and analyze the application result in steel plant.

  7. Lubricant for clean rolling: Escapee oil particles keep cold rolling steel mills lubricated

    NARCIS (Netherlands)

    Van De Graaf, A.

    2002-01-01

    One of the unique selling points of the Corus steel mills at IJmuiden is the quality of the steel they produce. The lubrication used during the last production stage is one of the factors that determine how clean and smooth the steel will emerge from the mill. The usual lubricant consists of an emul

  8. The thermal fatigue resistance of vermicular cast iron coupling with H13 steel units by cast-in process

    International Nuclear Information System (INIS)

    This paper focuses on improving the thermal fatigue resistance on the surface of vermicular cast iron coupling with inserted H13 steel blocks that had different cross sections, by cast-in processing. The microstructure of bionic units was examined by scanning electron microscope. Micro-hardness and thermal fatigue resistance of bionic samples with varied cross sections and spacings were investigated, respectively. Results show that a marked metallurgical bonding zone was produced at interface between the inserted H13 steel block and the parent material - a unique feature of the bionic structure in the vermicular cast iron samples. The micro-hardness of the bionic samples has been significantly improved. Thermal resistance of the samples with the circular cross section was the highest and the bionics sample with spacing of 2 mm spacing had a much longer thermal fatigue life, thus resulting in the improvement for the thermal fatigue life of the bionic samples, due to the efficient preclusion for the generation and propagation of crack at the interface of H13 block and the matrix.

  9. Fabrication of cast carbon steel with ultrafine TiC particles

    Institute of Scientific and Technical Information of China (English)

    Sang-Hoon LEE; Jin-Ju PARK; Sung-Mo HONG; Byoung-Sun HAN; Min-Ku LEE; Chang-Kyu RHEE

    2011-01-01

    The carbon steels dispersed with ultrafine TiC particles were fabricated by conventional casting method. The casting process is more economical than other available routes for metal matrix composite production, and the large sized components to be fabricated in short processing time. However, it is extremely difficult to obtain uniform dispersion of ultrafine ceramic particles in liquid metals due to the poor wettability and the specific gravity difference between the ceramic particle and metal matrix, In order to solve these problems, the mechanical milling (MM) and surface-active processes were introduced. As a result, Cu coated ultrafine TiC powders made by MM process using high energy ball milling machine were mixed with Sn powders as a surfactant to get better wettability by lowering the surface tension of carbon steel melt, The microstructural investigations by OM show that ultrafine TiC particles are distributed uniformly in carbon steel matrix. The grain sizes of the cast matrix with ultrafine TiC particles are much smaller than those without ultrafine TiC particles. This is probably due to the fact that TiC particles act as nucleation sites during solidification. The wear resistance of cast carbon steel composites added with MMed TiC/Cu-Sn powders is improved due to grain size refinement.

  10. Thermo-mechanical properties and cracking during solidification of thin slab cast steel

    NARCIS (Netherlands)

    Santillana, M.B.

    2013-01-01

    Nowadays a vast majority of the steel produced worldwide is via the continuous casting process route because this is the most low-cost, efficient and high quality method to mass produce metal products in a variety of sizes and shapes. Most of the continuous casters are the initial manufacturing step

  11. Heat treatment of long term serviced Cr – Mo cast steel

    Directory of Open Access Journals (Sweden)

    G. Golanski

    2010-01-01

    Full Text Available The paper presents results of research on the influence of heat treatment on the structure and properties of L20HM cast steel after long term operation at elevated temperature. Investigated cast steel was taken out from an outer frame of a steam turbine serviced for 167 424 hours at the temp. of 535 oC and pressure 12.75 MPa. In post-operating condition the investigated cast steel was characterized by mechanical properties below the required minimum and by high brittleness. Performed research on the influence of austenitizing parameters has revealed that the range of austenitizing temperatures for the examined cast steel: Ac3 + 30 ÷ 60 oC ensures obtaining of a fine austenite grain, homogeneous in size. It has been proved that tempering of bainititc – ferritic structure above 680 ÷ 690 oC causes an increase of impact energy along with a decrease of mechanical properties below the required minimum. Moreover, it has been noticed that applying of under-annealing instead of tempering, after full-annealing, guarantees the required impact energy of KV > 27J, with the mechanical properties similar to those after service.

  12. Modelling and simulation of A-segregates in steel castings using a thermal criterion function

    DEFF Research Database (Denmark)

    Kotas, Petr; Hattel, Jesper Henri

    2012-01-01

    simulation software package. It is then used for predicting A segregates inside a large steel casting, i.e. a forging ram. In part I, experimental data obtained from a foundry serve to validate the given criterion and to evaluate the critical value for A segregate initiation for one alloy composition...

  13. Effect of Alloying Elements on Thermal Wear of Cast Hot-Forging Die Steels

    Institute of Scientific and Technical Information of China (English)

    WANG Shu-qi; CHEN Kang-min; CUI Xiang-hong; JIANG Qi-chuan; HONG Bian

    2006-01-01

    The effect of main alloying elements on thermal wear of cast hot-forging die steels was studied. The wear mechanism was discussed. The results show that alloying elements have significant influences on the thermal wear of cast hot-forging die steels. The wear rates decrease with an increase in chromium content from 3% to 4% and molybdenum content from 2% to 3%, respectively. With further increase of chromium and molybdenum contents, chromium slightly reduces the wear resistance and molybdenum severely deteriorates the wear resistance with high wear rate. Lower vanadium/carbon ratio (1.5-2.5) leads to a lower wear resistance with higher wear rate. With an increase in vanadium/carbon ratio, the wear resistance of the cast steel substantially increases. When vanadium/carbon ratio is 3, the wear rate reaches the lowest value. The predominant mechanism of thermal wear of cast hot-forging die steels are oxidation wear and fatigue delamination. The Fe2O3 and Fe3O4 or lumps of brittle wear debris are formed on the wear surface.

  14. Estimation of fracture toughness of cast stainless steels in LWR [light water reactor] systems

    International Nuclear Information System (INIS)

    A procedure and correlations are presented for predicting fracture toughness J-R curves and impact strength of aged cast stainless steels from known material information. The ''saturation'' fracture toughness of a specific cast stainless steel, i.e., the minimum fracture toughness that would ever be achieved for the material after long-term service, is estimated from the degree of embrittlement at saturation. Degree of embrittlement is characterized in terms of room-temperature Charpy-impact energy. The variation of the impact energy at saturation for different materials is described in terms of a material parameter Φ, which is determined from the chemical composition and ferrite morphology. The fracture toughness J-R curve for the material is then obtained from correlations between room-temperature Charpy-impact energy and fracture toughness. Fracture toughness as a function of time and temperature of reactor service is estimated from the kinetics of embrittlement, which is determined from the chemical composition. Examples for estimating impact strength and fracture toughness of cast stainless steel components during reactor service are described. A common ''lower-bound'' J-R curve for cast stainless steels with unknown chemical composition is also defined. 15 refs., 19 figs., 3 tabs

  15. Electromagnetic stirring in the continuous casting of steel. Agitacion electromagnetica en la colada continua de acero

    Energy Technology Data Exchange (ETDEWEB)

    Alvarez de Toledo, G.; Campo, O.; Lainez, E. (Sidenor, Basauri (Spain))

    1995-01-01

    The electromagnetic stirring of steel in the machines for the continuous casting process has improved the internal quality of the cast product. Experimental work with stirrers situated at different positions of continuous casting machines of billets has been carried out. The in-mould stirrer is the one that produces a major modification of the billet internal structure, and also the biggest decrease of the central segregation. An in mould electromagnetic coil has been developed which allows the use of high stirring power without producing an undesirable movement of the liquid steel in the meniscus zone, therefore no mould powders entrapments are produced. It has been developed a method for determining the optimum electric frequency of the stirrer. (Author) 31 refs.

  16. Standard digital reference images for investment steel castings for aerospace applications

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 The digital reference images provided in the adjunct to this standard illustrate various types and degrees of discontinuities occurring in thin-wall steel investment castings. Use of this standard for the specification or grading of castings requires procurement of the adjunct digital reference images which illustrate the discontinuity types and severity levels. They are intended to provide the following: 1.1.1 A guide enabling recognition of thin-wall steel casting discontinuities and their differentiation both as to type and degree through digital radiographic examination. 1.1.2 Example digital radiographic illustrations of discontinuities and a nomenclature for reference in acceptance standards, specifications and drawings. 1.2 Two illustration categories are covered as follows: 1.2.1 Graded—Six common discontinuity types each illustrated in eight degrees of progressively increasing severity. 1.2.2 Ungraded—Twelve single illustrations of additional discontinuity types and of patterns and imper...

  17. Technical development of double-clad process for thin strip casting of carbon steel

    Energy Technology Data Exchange (ETDEWEB)

    Brown, H.L.; Forkel, C.E.; Knudson, D.L.

    1984-08-01

    This report documents the technical development for a patent disclosure of a double-clad process for the continuous casting of thin-strip carbon steel. The fundamental idea of the disclosure is to form a product strip by depositing molten steel between two, cooled, clad strips of the same material. The claimed benefits include: (a) the conservation of energy in steel making through the elimination of soaking pits and reheat cycles, and (b) an improved surface on both sides of the as-cast product such that it will be suitable for direct feed to a cold-reduction mill. However, the process as conceived is not necessarily limited to the casting of carbon steel, but may be also applied to other metals and alloys. The work is described under three headings as follows. Preliminary Considerations and Scoping Analysis presents the basic idea of the double-clad, thin-strip casting process; the energy conservation potential; scoping heat transfer calculations for the casting process; and independent review of this work. Thermal Analysis for Roller Configuration of Double-Clad Process, presents the development, results, and independent review of a finite-element thermal analysis for the casting process as originally conceived (using only chilled rollers in direct contact with the clad material of the product strip). Further Considerations for Belt Configuration of Double-Clad Process deals with a modified equipment design which interposes two product support belts, one on each side of the product, between the clad strip and the rollers. In addition to the process description, this section presents the preliminary mechanical calculations for the endless metal belts and the work scope and results for the computer model revision and thermal analysis for the modified concept.

  18. Flow of Steel in Mold Region During Continuous Casting

    Institute of Scientific and Technical Information of China (English)

    ZHANG Xing-guo; ZHANG Wen-xiao; JIN Jun-ze; J. W. Evans

    2007-01-01

    The particle image velocimetry (PIV) technique was used to study the fluid flow phenomena that occurred during continuous casting, using a water model with dimensions of 1 840 mm×280 mm. Two types of solidified shells, i.e., the smooth type and the coarse type, were used to characterize the dendrite in order to simulate different liquid-solid interfacial conditions. The influence of the nozzle angle and the immersion depth of nozzle, as well as the casting speed on the flow behavior was investigated quantitatively. The results were as follows: (1) There are two large recirculations above and below the fluid jet in the mold, respectively, under the smooth interface condition. However, in the case of the dendrite solidified shell, it was found that the flow velocity of the fluid decreased and more smaller vortices appeared in the upper region of the mold. (2) The angle and the immersion depth of nozzle are two important factors affecting the flow pattern, and they are also capable of bringing about the change in the flow direction. (3) The higher the casting speed, the higher are the jet stream and the impacting point on the narrow face. However, the high casting speed causes serious fluctuation of the meniscus, and correspondingly leads to various defects.

  19. EXPERIMENTAL RESEARCH AND NUMERICAL SIMULATION OF MOLD TEMPERATURE FIELD IN CONTINUOUS CASTING OF STEEL

    Institute of Scientific and Technical Information of China (English)

    X.S. Zheng; M.H. Sha; J.Z. Jin

    2006-01-01

    Mold is the heart of the continuous casting machine. Heat transfer and solidification in a watercooled mold are the most important factors during the continuous casting of steel. For studying the temperature distribution of a mold wall, a simulated apparatus of mold was designed and experiments were performed by it. The measured results indicated that the mold wall temperature approaches the temperature of cooling-water. An equivalent thermal-conductivity coefficient was proposed and deduced on the basis of the conclusion of the experiments. This coefficient was applied to solve the heat transfer between the melt and cooling water, and to characterize the heat transfer capacity of the mold. By this equivalent thermal-conductivity coefficient, it is very easy and convenient to numerically simulate the solidification process of continuous casting. And the calculation results are in agreement with the experiments. The effects of casting speed and water flow rate on the mold temperature field were also discussed.

  20. Progress of Production Technology of Clean Steel in Baosteel

    Institute of Scientific and Technical Information of China (English)

    CuiJian

    2005-01-01

    The progress in control technology of carbon, nitrogen, total oxygen, phosphorus, and stdphur as well as inclusions in steel is discussed at Baosteel. The purity obtained in IF steel and pipeline steel is introduced.

  1. Ferrite Measurement in Austenitic and Duplex Stainless Steel Castings - Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Lundin, C.D.; Zhou, G.; Ruprecht, W.

    1999-08-01

    The ability to determine ferrite rapidly, accurately and directly on a finished casting, in the solution annealed condition, can enhance the acceptance, save on manufacturing costs and ultimately improve service performance of duplex stainless steel cast products. If the suitability of a non-destructive ferrite determination methodology can be demonstrated for standard industrial measurement instruments, the production of cast secondary standards for calibration of these instruments is a necessity. With these concepts in mind, a series of experiments were carried out to demonstrate, in a non-destructive manner, the proper methodology for determining ferrite content. The literature was reviewed, with regard to measurement techniques and vagaries, an industrial ferrite measurement round-robin was conducted, the effects of casting surface finish, preparation of the casting surface for accurate measurement and the evaluation of suitable means for the production of cast secondary standards for calibration were systematically investigated. The data obtained from this research program provide recommendations to ensure accurate, repeatable, and reproducible ferrite measurement and qualifies the Feritscope for field use on production castings.

  2. Ferrite Measurement in Austenitic and Duplex Stainless Steel Castings - Literature Review

    Energy Technology Data Exchange (ETDEWEB)

    Lundin, C.D.; Zhou, G.; Ruprecht, W.

    1999-08-01

    The ability to determine ferrite rapidly, accurately and directly on a finished casting, in the solution annealed condition, can enhance the acceptance, save on manufacturing costs and ultimately improve service performance of duplex stainless steel cast products. If the suitability of a non-destructive ferrite determination methodology can be demonstrated for standard industrial measurement instruments, the production of cast secondary standards for calibration of these instruments is a necessity. With these concepts in mind, a series of experiments were carried out to demonstrate, in a non-destructive manner, the proper methodology for determining ferrite content. The literature was reviewed, with regard to measurement techniques and vagaries, an industrial ferrite measurement round-robin was conducted, the effects of casting surface finish, preparation of the casting surface for accurate measurement and the evaluation of suitable means for the production of cast secondary standards for calibration were systematically investigated. The data obtained from this research program provides recommendations to insure accurate, repeatable and reproducible ferrite measurement and qualifies the Feritscope for field use on production castings.

  3. Waste Characterization in Steel Casting and Recycling Opportunities in Europe

    OpenAIRE

    Silvia Fiore; Maria C. Zanetti; Barbara Ruffino

    2008-01-01

    The wastes coming from a steel foundry located in Italy, producing about 600,000 t/y of steel slabs, are considered in this work. The plant produces about 143,000 t/y of wastes, made of furnace and ladle slags (84%), pelletized dust (8%) and oxidised shaving (8%). The waste materials have been characterised by means of particle-size and chemical analyses, and some reuse/recycle possibilities are considered. The recycle as inert material of the slags was evaluated by means of several leaching ...

  4. Properties of High Basicity Mold Fluxes for Peritectic Steel Slab Casting

    Institute of Scientific and Technical Information of China (English)

    LONG Xiao; HE Sheng-ping; XU Jian-fei; HUO Xu-ling; WANG Qian

    2012-01-01

    In high speed continuous casting of peritectic steel slabs, mold fluxes with high basicity are required for less surface defect product. However, the basicity of remaining liquid slag film tends to decrease in casting process because of the crystallization of 3CaO ·2SiO2 · CaF2. Thus, a way is put forward to improve mold fluxesr properties by raising the original basicity. In order to confirm the possibility of this method, the effect of rising original basicity on the properties of mold fluxes is discussed. Properties of high fluorine based mold fluxes with different basicities and contents of CaF2 , Na2 O, and MgO were measured, respectively. Then, properties of higher basicity mold fluxes were discussed and compared with traditional ones. The results show that increasing the basicity index can improve the melting and flow property of mold fluxes. With the increasing basicity, crystallization rate of mold fluxes increases obviously and crystallization temperature tends to decrease when the basicity exceeds 1.35. The method presen- ted before is proved as a potential way to resolve the contradiction between horizontal heat transfer controlling and solidified shell lubricating for peritectic steel slab casting. But further study on improving the flow property of liquid slag is needed. This work can be used to guide mold fluxes design for high speed continuous casting of peritectic steel slabs.

  5. Adaptive neural network controller for the molten steel level control of strip casting processes

    International Nuclear Information System (INIS)

    The twin-roll strip casting process is a steel-strip production method which combines continuous casting and hot rolling processes. The production line from molten liquid steel to the final steel-strip is shortened and the production cost is reduced significantly as compared to conventional continuous casting. The quality of strip casting process depends on many process parameters, such as molten steel level in the pool, solidification position, and roll gap. Their relationships are complex and the strip casting process has the properties of nonlinear uncertainty and time-varying characteristics. It is difficult to establish an accurate process model for designing a model-based controller to monitor the strip quality. In this paper, a model-free adaptive neural network controller is developed to overcome this problem. The proposed control strategy is based on a neural network structure combined with a sliding-mode control scheme. An adaptive rule is employed to on-line adjust the weights of radial basis functions by using the reaching condition of a specified sliding surface. This surface has the on-line learning ability to respond to the system's nonlinear and time-varying behaviors. Since this model-free controller has a simple control structure and small number of control parameters, it is easy to implement. Simulation results, based on a semi experimental system dynamic model and parameters, are executed to show the control performance of the proposed intelligent controller. In addition, the control performance is compared with that of a traditional Pid controller

  6. The thermal fatigue behaviour of creep-resistant Ni-Cr cast steel

    Directory of Open Access Journals (Sweden)

    B. Piekarski

    2007-12-01

    Full Text Available The study gives a summary of the results of industrial and laboratory investigations regarding an assessment of the thermal fatigue behaviour of creep-resistant austenitic cast steel. The first part of the study was devoted to the problem of textural stresses forming in castings during service, indicating them as a cause of crack formation and propagation. Stresses are forming in carbides and in matrix surrounding these carbides due to considerable differences in the values of the coefficients of thermal expansion of these phases. The second part of the study shows the results of investigations carried out to assess the effect of carbon, chromium and nickel on crack resistance of austenitic cast steel. As a criterion of assessment the amount and propagation rate of cracks forming in the specimens as a result of rapid heating followed by cooling in running water was adopted. Tests were carried out on specimens made from 11 alloys. The chemical composition of these alloys was comprised in a range of the following values: (wt-%: 18-40 %Ni, 17-30 %Cr, 1.2-1.6%Si and 0.05-0.6 %C. The specimens were subjected to 75 cycles of heating to a temperature of 900oC followed by cooling in running water. After every 15 cycles the number of the cracks was counted and their length was measured. The results of the measurements were mathematically processed. It has been proved that the main factor responsible for an increase in the number of cracks is carbon content in the alloy. In general assessment of the results of investigations, the predominant role of carbon and of chromium in the next place in shaping the crack behaviour of creep-resistant austenitic cast steel should be stressed. Attention was also drawn to the effect of high-temperature corrosion as a factor definitely deteriorating the cast steel resistance to thermal fatigue.

  7. The comparative studies of ADI versus Hadfield cast steel wear resistance

    OpenAIRE

    Mieczysław Kaczorowski; Anna Krzyńska; Paweł Skoczylas

    2011-01-01

    The results of comparative studies of wear resistance of ADI versus high manganese Hadfield cast steel are presented. For evaluation ofwear resistance three type of ADI were chosen. Two of them were of moderate strength ADI with 800 and 1000MPa tensile strength whilethe third was 1400MPa tensile strength ADI. The specimens were cut from ADI test YII type casting poured and heat treated in Institute ofFoundry in Krakow. The pin on disc method was used for wear resistance experiment. The specim...

  8. The optimisation of the viscosity of lubricating slags used in the continuous casting of steel

    Science.gov (United States)

    Gheorghiu, Csaba Attila; Hepuť, Teodor; Popa, Erika

    2016-06-01

    In the steel continuous casting process, the mould lubrication has a very important technological role, with direct effects on the continuous cast blank quality. The lubrication process is directly influenced by the synthetic flux viscosity (slag thickness), which is determined on its turn by the chemical composition and the temperature. The researches made aimed to establish some correlation relationships between the viscosity, chemical composition and temperature, analytically and graphically expressed, by processing the data in the Matlab program. Based on these correlations the best chemical compositions of the lubrication fluxes are established.

  9. Abrasive Wear Behavior of High Chromium Cast Iron and Hadfield Steel-- A Comparison

    Institute of Scientific and Technical Information of China (English)

    Mehdi Mazar Atabaki; Sajjad Jafari; Hassan Abdollah-pour

    2012-01-01

    Wear properties of two different crushers used for grinding raw materials of cement industry are compared using pin-on-disk wear test.The wear test was carried out with different loads on a pin.Abrasive wear behavior of two alloys was evaluated by comparing mass loss,wear resistance,microhardness and friction coefficient.The microstructure of the specimens was detected using optical microscope.The results showed that abrasive wear of high chromium cast iron is lower than that of Hadfield steel.Due to the presence of M7C3 carbides on the high chromium cast iron matrix,impact crushers exhibited higher friction coefficient

  10. Contribution to the assessment of thermal ageing of stainless steel castings and welds

    International Nuclear Information System (INIS)

    Indentation tests are considered for measuring and verifying of thermal ageing of stainless steel castings and welds in service. Therefore, relations between indentation- and tensile diagrams were analyzed. Conventional tensile characteristics, deduced from the indentation diagram, should be used for fracture toughness prediction. Form of correlation of yield stress and tensile strength on one side and of fracture toughness on the other side was proposed, which is specific for austenitic-ferritic two-phase materials. Properties of castings and welds were compared and analyzed within the framework of a mesomechanical homogenization model with micromechanical effect of geometric slip distance. (author)

  11. Effect of aging on mechanical properties of austenitic stainless steel castings and welds

    International Nuclear Information System (INIS)

    Study of the influence of long time aging on the properties of the cast austenitic steel and associated welds or cladding in the components of the primary loop of nuclear plants: embrittlement by precipitation of α'(chromium rich) in ferrite islands (mostly for castings); precipitation hardens the ferrite wich breaks by cleavage. The impact energy and Isub(IC) value are lowered by this phenomenon. Low cycle fatigue properties and fatigue crack growth rates are not modified by aging. Study of correlation between KCU impact toughness at the end of the life of a component, chemical composition and ferrite content

  12. Microstructural evolution in a duplex cast steel after quench ageing process

    Directory of Open Access Journals (Sweden)

    Z. Stradomski

    2007-09-01

    Full Text Available Purpose: The effectiveness and usefulness of the quench ageing on the service properties of massive duplex cast steel was presented in this work. The mechanism of precipitation of a ε-Cu phase and its effect on the mechanical properties of the cast steel were investigated.Design/methodology/approach: The microscopic analysis of the cast steel was performed on a Zeiss Axiovert 25 optical microscope. The substructure of ferrite was examined on a JOEL JEM 3010 high-resolution transmission electron microscope. The analysis of chemical composition of selected micro-regions was carried out using a JEOL JSM 5400 scanning microscope equipped with an EDS microanalyzer. The verification of the metallographic examination results was done using the Thermo-Calc program.Findings: The formation of the ε-Cu phase during quench ageing causes an increase in hardness and drop in impact resistance. The ageing parameters have a substantial influence on the ferrite substructure and the degree of coherence, dispersion and amount of the ε-Cu phase. The ageing treatment at 480°C causes the precipitation of the ε-Cu phase coherent with the matrix. This temperature of quench ageing produce also the formation of a α’-Cr phase and an α-Fe phase.Practical implications: Duplex cast steels are becoming an irreplaceable material in the elements of equipment exposed to the simultaneous action of corrosive and erosive environment. In the case of massive elements like pumps and pipeline elements, the effect of quench ageing is much lower which is associated with the presence of a large amount of the incoherent ε-Cu phase in the cast steel after the solution heat treatment.Originality/value: The lower temperature of quench ageing duplex cast steels with copper addition should not be lower than 500°C because of the temperature of an undesirable spinodal decomposition of the ferrite in 480°C which is partially responsible for the slight increase in hardness and a drastic

  13. The development of high strength corrosion resistant precipitation hardening cast steels

    Science.gov (United States)

    Abrahams, Rachel A.

    Precipitation Hardened Cast Stainless Steels (PHCSS) are a corrosion resistant class of materials which derive their properties from secondary aging after a normalizing heat treatment step. While PHCSS materials are available in austenitic and semi-austenitic forms, the martensitic PHCSS are most widely used due to a combination of high strength, good toughness, and corrosion resistance. If higher strength levels can be achieved in these alloys, these materials can be used as a lower-cost alternative to titanium for high specific strength applications where corrosion resistance is a factor. Although wrought precipitation hardened materials have been in use and specified for more than half a century, the specification and use of PHCSS has only been recent. The effects of composition and processing on performance have received little attention in the cast steel literature. The work presented in these investigations is concerned with the experimental study and modeling of microstructural development in cast martensitic precipitation hardened steels at high strength levels. Particular attention is focused on improving the performance of the high strength CB7Cu alloy by control of detrimental secondary phases, notably delta ferrite and retained austenite, which is detrimental to strength, but potentially beneficial in terms of fracture and impact toughness. The relationship between age processing and mechanical properties is also investigated, and a new age hardening model based on simultaneous precipitation hardening and tempering has been modified for use with these steels. Because the CB7Cu system has limited strength even with improved processing, a higher strength prototype Fe-Ni-Cr-Mo-Ti system has been designed and adapted for use in casting. This prototype is expected to develop high strengths matching or exceed that of cast Ti-6Al-4V alloys. Traditional multicomponent constitution phase diagrams widely used for phase estimation in conventional stainless steels

  14. The characteristics of two-phase 22Cr-6Ni-2Mo-1,5Cu cast steel

    Directory of Open Access Journals (Sweden)

    B. Kalandyk

    2008-12-01

    Full Text Available The paper discusses the effect of the casting wall thickness on the segregation of alloying elements in two-phase (F-A 22Cr-6Ni-2Mo-1,5Cu cast steel. The values of the distribution coefficient k0 for Cr, Mo, Si, and Ni, Mn, Cu in the cast stepped test piece walls of three different thicknesses were determined. After solutioning, the values of Rm, R0,2, A5 and Z were measured in the wall of 45 mm thickness and were compared with the results obtained for austenitic cast steel of 18Cr-9Ni grade. In the examined cast steel also the content of δ ferrite and the value of PREN were determined.

  15. A Thermal Simulation Method for Solidification Process of Steel Slab in Continuous Casting

    Science.gov (United States)

    Zhong, Honggang; Chen, Xiangru; Han, Qingyou; Han, Ke; Zhai, Qijie

    2016-10-01

    Eighty years after the invention of continuous cast of steels, reproducibility from few mm3 samples in the laboratory to m3 product in plants is still a challenge. We have engineered a thermal simulation method to simulate the continuous casting process. The temperature gradient ( G L ) and dendritic growth rate ( v) of the slab were reproduced by controlling temperature and cooling intensity at hot and chill end, respectively, in our simulation samples. To verify that our samples can simulate the cast slab in continuous casting process, the heat transfer, solidification structure, and macrosegregation of the simulating sample were compared to those of a much larger continuous casting slab. The morphology of solid/liquid interface, solidified shell thickness, and dendritic growth rate were also investigated by in situ quenching the solidifying sample. Shell thickness ( δ) determined by our quenching experiment was related to solidification time ( τ) by equation: δ = 4.27 × τ 0.38. The results indicated that our method closely simulated the solidification process of continuous casting.

  16. A Thermal Simulation Method for Solidification Process of Steel Slab in Continuous Casting

    Science.gov (United States)

    Zhong, Honggang; Chen, Xiangru; Han, Qingyou; Han, Ke; Zhai, Qijie

    2016-07-01

    Eighty years after the invention of continuous cast of steels, reproducibility from few mm3 samples in the laboratory to m3 product in plants is still a challenge. We have engineered a thermal simulation method to simulate the continuous casting process. The temperature gradient (G L ) and dendritic growth rate (v) of the slab were reproduced by controlling temperature and cooling intensity at hot and chill end, respectively, in our simulation samples. To verify that our samples can simulate the cast slab in continuous casting process, the heat transfer, solidification structure, and macrosegregation of the simulating sample were compared to those of a much larger continuous casting slab. The morphology of solid/liquid interface, solidified shell thickness, and dendritic growth rate were also investigated by in situ quenching the solidifying sample. Shell thickness (δ) determined by our quenching experiment was related to solidification time (τ) by equation: δ = 4.27 × τ 0.38. The results indicated that our method closely simulated the solidification process of continuous casting.

  17. Properties of ABNT 41xx and 86xx cast steel modified with niobium; evaluation methodology and experimental preliminary results

    International Nuclear Information System (INIS)

    The experimental methodology to evaluate the mechanical properties of ABNT 41xx and 86xx steels modified with NB in the as cast and heat treated conditions and the first preliminary results obtained in a laboratory scale, are presented. (Author)

  18. Effect of RE-Al-N on Structures and Properties of M2 Cast High Speed Steel

    Institute of Scientific and Technical Information of China (English)

    符寒光; 杜建铭; 蒋志强; 邢建东

    2003-01-01

    M2 cast high speed steel was inoculated by addition of rare earth(RE)-Al-N, network eutectic carbides were eliminated, matrix microstructures were refined and the segregation of tungsten and molybdenum elements was relieved. In the condition that the hardness does not decrease, impact toughness obviously increases. Quenching at 1180 ℃ and three-times tempering at 560 ℃, the hardness of M2 cast high speed steel is 65~66 HRC, and impact toughness reaches 21.3 J*cm- 2. Modified M2 cast high speed steel has excellent thermal fatigue resistance and high temperature wear resistance. Roller made in modified M2 cast high speed steel has excellent service effect when it is used in slit rolling mill of hot rolling bar mill.

  19. Long-term aging of cast stainless steels: Mechanisms and resulting properties

    International Nuclear Information System (INIS)

    Mechanical property data are presented from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 450, 400, 350, 320, and 2900C. The results indicate that thermal aging increases the tensile strength and decreases the impactenergy, J/sub IC/ and tearing modulus of the steels. Also, the ductile-to-brittle transition curve shifts to higher temperatures. The low-carbon CF-3 steels were the most resistant and the molybdenum-containing high-carbon CF-8M steels were the most susceptible to low-temperature embrittlement. The influence of nitrogen content and distribution of ferrite on loss of toughness are discussed. Data also indicate that existing correlations do not accurately represent the embrittlement behavior over the temperature range 280 to 4500C, i.e., extrapolation of high-temperature data to reactor temperatures may not be valid for some compositions of cast stainless steels. 13 refs., 13 figs., 2 tabs

  20. Surface Segregation of B During Box Annealing of ConCast Steels

    Science.gov (United States)

    Biber, H. E.; Hudson, R. M.

    1987-03-01

    In this study, significant surface concentrations of boron and nitrogen (presumably present as boron nitride) were observed in Auger electron spectrometry (AES) analysis of steels that were continuously cast with a mold flux containing boron oxide and commercially box annealed with dry H2-N2 atmospheres. A review of the thermochemistry of boron in steel suggested that the surface enrichment in boron and nitrogen occurs by a reaction during annealing in dry atmospheres. Laboratory annealing trials demonstrated the effectiveness of high dew point H2-N2 annealing atmospheres in suppressing that reaction. AES analysis indicates that the surface enrichment is not uniform and may be a function of surface grain orientation.

  1. Transformation Behavior and Microstructure in a 40Cr2Ni2MoV Cast Steel

    Institute of Scientific and Technical Information of China (English)

    Cheng Liu; Zhenbo Zhao; Sanjiwan. D. Bhole1; Derek O. Northwood

    2004-01-01

    The transformation behavior of a 40Cr2Ni2MoV cast steel manufactured by electroslag remelting (ESR) has been investigated. Compared to a forged steel, the incubation periods for both the pearlite and bainite transformations are shorter, but the transformation times are longer. The austenite is easier to transform into martensite. Optical microscopy and TEM indicated that there were variations in microstructure during the super-cooled austenite transformation. This is attributed to an inhomogeneous austenite, resulting from the segregation of elements during the ESR solidification.

  2. Development of Forsterite Based Insulating Board for Alloy Steel Con—casting Tundish

    Institute of Scientific and Technical Information of China (English)

    ZHAOJi-zeng; ZHOULei; 等

    1994-01-01

    To meet the operation requirement of com-casting tundish for alloy steel.a forsterite based insulating board has been developed.The effects of binder ,fiber and other additives on the properties of the properties of the products have been described;the theoretial reason of assuring containing clear steel by using inorganic binder bonded forsterite based insulating board were also discussed;the mineral composition and microstructure of the products have been analyzed by means of XRD.SEM and microscope ,The results indicate that the forsteite based insulating board with excel-lent performance and dood application results has been obtained.

  3. Microstructure in cast stainless steel used for long-term in BWR environment

    International Nuclear Information System (INIS)

    Microstructure in a cast stainless steel used for a PLR pump casing cover in a BWR was investigated by atom probe tomography and nanoindentation testing. Ferrite phase decomposition and G-phase precipitation were not observed in the as-received PLRP casing cover. Thermal aging and solution treatment were carried out on the as-received PLRP casing cover and an unused model alloy of cast stainless steel. The ferrite phase decomposition and G-phase precipitates in the thermal aged model alloy disappeared after the solution treatment, and the nanoindentation hardness in the ferrite phase was recovered. Changes in the microstructures were almost the same between the PLRP casing cover and the model alloy after the thermal aging and the solution treatment. The effect of thermal aging on the as-received material was considered to be very little in service. (author)

  4. Plasma sprayed coatings on mild steel split moulds for uranium casting

    International Nuclear Information System (INIS)

    High velocity high temperature plasma jets are used to deposit metals and ceramics on metallic substrates for oxidation and corrosion protection applications. Plasma sprayed ceramic coatings on metallic substrates are also used to prevent its reaction with molten metals. Metal-alumina duplex coatings on mild steel split moulds have been developed and successfully used for casting of uranium. Techno-economics of the coated moulds against the conventional graphite moulds are a major advantage. Mild steel moulds of 600 mm long and 75 mm in diameter have been plasma spray coated with alumina over a bond coat of molybdenum. In-plant tests showed an increase in number of castings per mould compared to the commonly used graphite moulds. (author)

  5. Computer Simulation of the Formation of Non-Metallic Precipitates During a Continuous Casting of Steel

    Directory of Open Access Journals (Sweden)

    Kalisz D.

    2016-03-01

    Full Text Available The authors own computer software, based on the Ueshima mathematical model with taking into account the back diffusion, determined from the Wołczyński equation, was developed for simulation calculations. The applied calculation procedure allowed to determine the chemical composition of the non-metallic phase in steel deoxidised by means of Mn, Si and Al, at the given cooling rate. The calculation results were confirmed by the analysis of samples taken from the determined areas of the cast ingot. This indicates that the developed computer software can be applied for designing the steel casting process of the strictly determined chemical composition and for obtaining the required non-metallic precipitates.

  6. Influence of isothermal quenching of LAMC CrMnSi cast steel on impact toughness

    Institute of Scientific and Technical Information of China (English)

    JIN Bao-shi; HUANG Zhi-qiu; SHEN Da-dong

    2005-01-01

    The influence of isothermal quenching process of low-alloy and medium carbon (LAMC) CrMnSi cast steel on the impact toughness was investigated. The microstructure and mechanical property of LAMC CrMnSi cast steel were analyzed by the laser optical modulator, the scanning electron microscopy, the energy dispersive spectrometer, the hardness and impact tests. The experimental results show that the dual phases of bainite and residual austenite can be obtained by the severity isothermal quenching, the fractographies of specimens change from quasi-cleavage to dimple at 310 ℃ for 60 min, the impact toughness for specimens at the room temperature isothermally achieves 130 J/cm2, meantime and its hardness is more than 45(HRC).

  7. Development of 30Cr06A, a high strength cast steel and its welding ability

    Institute of Scientific and Technical Information of China (English)

    GAO You-jin

    2008-01-01

    High performance hydraulic supports have a high requirement in strength, toughness and welding ability of socket ma- terial. Targeting this problem, we analyzed the properties of the high strength socket material 30Cr06, used in high performance hydraulic supports both at home and abroad and developed a new kind of high strength cast steel 30Cr06A, by making use of an orthogonal experiment, which provided the design conditions for its optimal composition. The result shows that the strength and toughness of the newly developed high strength cast steel 30Cr06A is much better than that of 30Cr06. Theoretical calculations, mechanical property tests and hardness distribution tests of welded joints were carried out for a study of the welding ability of the new material, which is proved to be very good. Therefore, this 30Cr06A material has been successfully used in the socket of high performance hydraulic support.

  8. Research of estimation method of thermal aging embrittlement on cast austenitic stainless steel

    International Nuclear Information System (INIS)

    Thermal aging embrittlement of cast austenitic stainless steel components from the decommissioned Advanced Thermal prototype Reactor (ATR) Fugen power station has been characterized. Cast stainless steel materials were obtained from recirculation pump casing. The actual time at temperature for the materials was 138,000 h at 275°C. The Fugen serviced material show modest decrease in Charpy-impact properties and a small increase in micro-Vickers hardness in ferrite phase because of thermal aging at relatively low service temperatures. The fracture toughness prediction method (H3T model) predicts slightly lower values for Charpy-impact energy obtained from the Fugen material. The results from microstructural analysis suggest that the prediction method have the potential to provide higher accuracy by considering activation energy for embrittlement at low service temperatures. (author)

  9. Measurement and AFPS control of molten steel level in strip casting

    Institute of Scientific and Technical Information of China (English)

    Liye Zhu; Tihua Wu; Yuan Fang

    2005-01-01

    The measurement and control of the molten steel level are studied, which affect the quality of strip surface in strip casting.A system of molten steel measurement with a CCD (Charge Coupled Devices) sensor is designed, real-time measured data are given and its precision is analyzed. The level fluctuation model is derived, and an adaptive fuzzy-PID controller with supervisory control (AFPS) is proposed. The stability of the system is proved using Lyapunov theorem, and the simulation results are given when the model, the casting speed and the roll gap change. It is suggested that this kind of coupled nonlinear and time varying system is stable and robust using the designed AFPS controller.

  10. The anaerobic corrosion of carbon steel and cast iron in artificial groundwaters

    Energy Technology Data Exchange (ETDEWEB)

    Smart, N.R. [AEA Technology plc, Culham Science Centre (United Kingdom); Blackwood, D.J. [National Univ. of Singapore (Singapore); Werme, L. [Swedish Nuclear Fuel and Waste Management Co., Stockholm (Sweden)

    2001-07-01

    In Sweden, high level radioactive waste will be disposed of in a canister with a copper outer and a cast iron or carbon steel inner. If the iron insert comes into contact with anoxic geological water, anaerobic corrosion leading to the generation of hydrogen will occur. This paper presents a study of the anaerobic corrosion of carbon steel and cast iron in artificial Swedish granitic groundwaters. Electrochemical methods and gas collection techniques were used to assess the mechanisms and rates of corrosion and the associated hydrogen gas production over a range of conditions. The corrosion rate is high initially but is anodically limited by the slow formation of a duplex magnetite film. The effects of key environmental parameters such as temperature and ionic strength on the anaerobic corrosion rate are discussed.

  11. Application of digital radiography in evaluation of crack propagation rate in cast steel specimens

    OpenAIRE

    Sikora, R.; B. Piekarski; K. Świadek; R. Chylińska

    2009-01-01

    A technology that utilizes penetrating X-rays is one of the oldest non-destructive testing methods. Digital radiography combines modern digital image processing algorithms with traditional X-ray testing method. The following paper describes the present use of digital radiograms in flaw detection, and the use of identification and classification algorithms in detection of cracks that occur under the effect of thermal fatigue process in creep-resistant steel castings operating as structural ele...

  12. Quality control system for the process of continuous casting of steel

    OpenAIRE

    A. Gzieło; J. Koszkul; Kwiatkowski, D; Pietrzak, M.; H. Świerczyński

    2006-01-01

    Purpose: Purpose of this research was to create new quality control system.Design/methodology/approach: For the purpose of new quality control system, the base of technological parameters of the process of continuous casting of steel (CCS) has been programmed; it consists of 53 parameters. The optimal values for the technological parameters are necessary to proper functioning of databases and are essential element of quality control system. For each parameter, some target values have been emp...

  13. INVESTIGATION ON HOT DUCTILITY AND STRENGTH OF CONTINUOUS CASTING SLAB FOR AH32 STEEL

    Institute of Scientific and Technical Information of China (English)

    G.Y. Li; X.F. Li; L.G. Ao

    2006-01-01

    By means of Gleeble-1500 testing machine, the simulation of continuous casting process for AH32 steel was carried out and hot ductility and strength were determined. The cracking sensitivity was studied under the different temperatures and strain rates. The Precipitations of AlN at different temperatures and the fractures of high-temperature tensile samples were observed by using TEM (transmission electron microscope) and SEM (scanning electron microscope). The factors affecting the brittle temperature zone were discussed.

  14. Finite volume modeling of the solidification of an axial steel cast impeller

    OpenAIRE

    M. Copur; M. N. Eruslu

    2014-01-01

    In the foundry industry, obtaining the solidification contours in cast geometries are extremely important to know the last location(s) to solidify in order to define the correct feeding path and the number of risers. This paper presents three-dimensional simulation of transient conduction heat transfer within an axial impeller, made of AISI 1016 steel, poured and solidified in chemically bonded mold and core medium, by using FVM technique and ANSYS CFX. Specific heat, density and thermal cond...

  15. Hydrogen embrittlement of cast 13% Cr 6% NiMo steel

    International Nuclear Information System (INIS)

    A study of the hydrogen embrittlement resistance of cast 13Cr6NiMo steel after various alternative tempering treatment is reported. The threshold levels of the stress intensity factor are examined as they relate to the residual austenite content in the structure of lath martensite, the type of fracture found on the specimens and the surface segregation of phosphorus observed on them. (author)

  16. Ultrasonic detection and sizing of cracks in cast stainless steel samples

    International Nuclear Information System (INIS)

    The test consisted of 15 samples of cast stainless steel, each with a weld. Some of the specimens were provided with artificially made thermal fatique cracks. The inspection was performed with the P-scan method. The investigations showed an improvement of recognizability relative to earlier investigations. One probe, the dual type, longitudinal wave 45 degrees, low frequence 0.5-1 MHz gives the best results. (G.B.)

  17. Electrolytic surface hardening of steel,cast iron and aluminium-bronze

    Institute of Scientific and Technical Information of China (English)

    Suhas Keshav Paknikar

    2006-01-01

    Electrolytic hardening process was developed in USSR in the 1950s. The process was developed but was not commercially exploited. There is no evidence of work done on this process in India. The author has done this original work applied to different materials like steel,cast iron and aluminum-bronze. This paper gives details of microstructural transformations along with hardness value achieved. There is vital scope for this process to become viable for surface hardening and selective hardening of small components.

  18. Non-destructive evaluation of thermal aging of cast duplex stainless steel using thermoelectric power measurement

    International Nuclear Information System (INIS)

    Cast duplex stainless steel is frequently used in main coolant pipes of PWR (Pressurized water reactor) type nuclear power plants because of its excellent material strength, toughness and superior corrosion resistance. However, it is known that material deterioration referred to as thermal aging occurs when this material is exposed to temperatures over 300degC. As a result, the material toughness decreases. Therefore, in managing the components made of cast duplex stainless steel, it is necessary to evaluate non-destructively such deterioration. In this study, measurement of thermoelectric power, which is sensitive to micro-structural change in materials, was used for the evaluation of thermal aging. First, we investigated change in mechanical properties (hardness, tensile stress and notch toughness) due to thermal aging in cast duplex stainless steel. Secondly we measured thermoelectric power (TEP) and investigated change in TEP de to thermal aging and the effect of temperature of a specimen on TEP.Then the TEP was compared with the mechanical properties. As a result, TEP increases with aging time and the tendency becomes more remarkable as ferrite content increases. The increase in TEP of a specimen with 21.3% ferrite due to thermal aging (400degC-10000 h) is 0.61 μV/degC. The TEP slightly decreases with temperature of the specimen at a rate of about -0.009 μV/degC2. Finally we found good correlation between the TEP and ductile-brittle transition temperature, the TEP and notch toughness at 325degC. The correlation coefficients are respectively 0.886∼0.957 and -0.890∼ -0.978. Therefore, by using TEP measurement, material deterioration of cast duplex stainless steel due to thermal aging can be evaluated. (author)

  19. Estimation of fracture toughness of cast stainless steels during thermal aging in LWR systems-revision 1

    International Nuclear Information System (INIS)

    This report presents a revision of the procedure and correlations presented earlier in NUREG/CR-4513, ANL-90/42 (June 1991) for predicting the change in mechanical properties of cast stainless steel components due to thermal aging during service in light water reactors at 280-330 degrees C (535-625 degrees F). The correlations presented in this report are based on an expanded data base and have been optimized with mechanical-property data on cast stainless steels aged up to ∼58,000 h at 290-350 degrees C (554-633 degrees F). The fracture toughness J-R curve, tensile stress, and Charpy-impact energy of aged cast stainless steels are estimated from known material information. Mechanical properties of a specific cast stainless steel are estimated from the extent and kinetics of thermal embrittlement. Embrittlement of cast stainless steels is characterized in terms of room-temperature Charpy-impact energy. Charpy-impact energy as a function of time and temperature of reactor service is estimated from the kinetics of thermal embrittlement, which are also determined from the chemical composition. The initial impact energy of the unaged steel is required for these estimations. Initial tensile flow stress is needed for estimating the flow stress of the aged material. The fracture toughness J-R curve for the material is then obtained by correlating room-temperature Charpy-impact energy with fracture toughness parameters. The values of JIC are determined from the estimated J-R curve and flow stress. A common open-quotes predicted lower-boundclose quotes J-R curve for cast stainless steels of unknown chemical composition is also defined for a given grade of steel, range of ferrite content, and temperature. Examples of estimating mechanical properties of cast stainless steel components during reactor service are presented

  20. Non-destructive evaluation of thermal aging of cast duplex stainless steel

    International Nuclear Information System (INIS)

    Cast duplex stainless steel is frequently used in main coolant pipes and reactor coolant pump casings in nuclear power plants because of its excellent material strength, toughness and superior corrosion resistance. It is known, however, that thermal aging occurs when this material is exposed to temperatures over 300degC for extended periods of time. As a result, the material toughness decreases. It is necessary therefore to evaluate changes in the mechanical properties of this material caused by thermal aging using non-destructive methods for the maintenance and management of components made of cast duplex stainless steel. In order to develop a non-destructive technique for evaluating the toughness reduction of cast duplex stainless steel due to thermal aging, five types of non-destructive techniques were compared. These include ultrasonic sound velocity measurement, the thermoelectric power measurement the electric resistance method, the SQUID (Superconducting Quantum Interface Device) method, and the positron annihilation method. The thermal aging detectability of each technique was compared and examined in experiments using specimens on which accelerated thermal aging had been carried out. It was concluded that the thermoelectric power measurement was the most effective technique for evaluating thermal aging because the correlation coefficient between the non-destructive evaluation parameters and the mechanical properties of aged materials was high and the dispersion of measurements was small. (author)

  1. Waste Characterization in Steel Casting and Recycling Opportunities in Europe

    Directory of Open Access Journals (Sweden)

    Silvia Fiore

    2008-01-01

    Full Text Available The wastes coming from a steel foundry located in Italy, producing about 600,000 t/y of steel slabs, are considered in this work. The plant produces about 143,000 t/y of wastes, made of furnace and ladle slags (84%, pelletized dust (8% and oxidised shaving (8%. The waste materials have been characterised by means of particle-size and chemical analyses, and some reuse/recycle possibilities are considered. The recycle as inert material of the slags was evaluated by means of several leaching tests according to the Italian (UNI10802 test, equivalent to EN 12457/2 test, French (AFNOR X31-210 test, Danish and European Community (EN 12457/4 test regulations. The requirements of the above mentioned regulations were compared and discussed. The possibility of landfilling the materials as inert or not dangerous wastes according to Italian Law (DM 3/8/2005 and European Community regulation (Decision of European Community Council N°2003/33 was also considered.

  2. Microstructure analysis of AISI 304 stainless steel produced by twin-roll thin strip casting process

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The microstructure of AISI 304 austenite stainless steel fabricated by the thin strip casting process were investigated using optical microscope, scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray diffraction (XRD).The microstructures of the casting strips show a duplex structure consisting of delta ferrite and austenite. The volume fraction of the delta ferrite is about 9.74vol% at the center and 6.77vol% at the surface of the casting thin strip, in vermicular and band shapes. On account of rapid cooling and solidification in the continuous casting process, many kinds of inclusions and precipitates have been found. Most of the inclusions and precipitates are spherical complex compounds consisting of oxides, such as, SiO2, MnO, Al2O3,Cr2O3,and FeO or their multiplicity oxides of MnO·Al2O3,2FeO·SiO2, and 2MnO·SiO2. Many defects including dislocations and stacking faults have also formed during the rapid cooling and solidification process, which is helpful to improve the mechanical properties of the casting strips.

  3. Cast, heat-resistant austenitic stainless steels having reduced alloying element content

    Energy Technology Data Exchange (ETDEWEB)

    Muralidharan, Govindarajan [Knoxville, TN; Sikka, Vinod Kumar [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Pankiw, Roman I [Greensburg, PA

    2010-07-06

    A cast, austenitic steel composed essentially of, expressed in weight percent of the total composition, about 0.4 to about 0.7 C, about 20 to about 30 Cr, about 20 to about 30 Ni, about 0.5 to about 1 Mn, about 0.6 to about 2 Si, about 0.05 to about 1 Nb, about 0.05 to about 1 W, about 0.05 to about 1.0 Mo, balance Fe, the steel being essentially free of Ti and Co, the steel characterized by at least one microstructural component selected from the group consisting of MC, M.sub.23C.sub.6, and M(C, N).

  4. Cast, heat-resistant austenitic stainless steels having reduced alloying element content

    Energy Technology Data Exchange (ETDEWEB)

    Muralidharan, Govindarajan [Knoxville, TN; Sikka, Vinod Kumar [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Pankiw, Roman I [Greensburg, PA

    2011-08-23

    A cast, austenitic steel composed essentially of, expressed in weight percent of the total composition, about 0.4 to about 0.7 C, about 20 to about 30 Cr, about 20 to about 30 Ni, about 0.5 to about 1 Mn, about 0.6 to about 2 Si, about 0.05 to about 1 Nb, about 0.05 to about 1 W, about 0.05 to about 1.0 Mo, balance Fe, the steel being essentially free of Ti and Co, the steel characterized by at least one microstructural component selected from the group consisting of MC, M.sub.23C.sub.6, and M(C, N).

  5. Preliminary experimental research on friction characteristics of a thick gravitational casted babbit layer on steel substrate

    Science.gov (United States)

    Paleu, V.; Georgescu, S.; Baciu, C.; Istrate, B.; Baciu, E. R.

    2016-08-01

    The ability of the antifriction materials to withstand with no lubrication for a while can be a solution for the catastrophic failure of automotive journal bearings from the internal combustion engines in accidental breakdown of the oil pump. A thick layer of antifriction material (babbit) was deposited by gravitational casting on a steel disk substrate. Four tribological disk samples coated with babbit are tested against a steel shoe on Amsler tribometer at different speeds and loads in dry friction. The values of the friction coefficient versus speed and load are presented, the obtained results indicating a mild wear regime, recommending the new babbit as a possible coating for the bushes of the journal bearings in automotive internal combustion engines. Further tests must be dedicated to the establishment of the wear intensity of the steel shoe - babbit disk tribological pair, both for motor oil lubricated and dry friction conditions.

  6. Longitudinal surface cracks on continuous casting slabs of P and Cu containing container steel

    Institute of Scientific and Technical Information of China (English)

    Xinhua Wang; Zhiyuan Zhu; Li Zhang; Guodong Xu

    2003-01-01

    The fact that the amount of the mold flux components differs at different locations on the cracking surface indicates that the longitudinal surface cracks are initially formed in the mold and are enlarged in the secondary cooling zone. Based on the hot ductility measurement of two typical container used steels, it is known that the steels are in severe embrittlement state in the temperature range of 825-775℃. By means of increasing Cr/Ni plating thickness on the upper part of the mold, reducing mold heat flux, adopting new secondary cooling pattern, etc., the occurrence of the surface longitudinal cracks on the steel CC (continuous casting) slabs has been significantly reduced.

  7. Simulation of Fluid Flow, Heat Transfer and Micro-Segregation in Twin-roll Strip Casting of Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    Xiaoming ZHANG; Zhengyi JIANG; Xianghua LIU; Guodong WANG

    2006-01-01

    In twin-roll strip casting process, metal flow and temperature distribution in the molten pool directly affect the stability of the process and the quality of products. In this paper, a 3D coupled thermal-flow fenite element modeling (FEM) simulation for twin-roll strip casting of stainless steel was performed. Influences of the pouring temperature and casting speed on the temperature fields were obtained from the numerical simulation. The micro-segregation of the solutes during the strip casting process of stainless steel was also simulated. A developed micro-segregation model was used to calculate the micro-segregation of solutes in twin-roll casting of stainless steel. The relationship between the solidus fraction in solidification and temperature was given,which was used to determine the LIT (liquid impermeable temperature), ZST (zero strength temperature) and ZDT (zero ductility temperature) in the period of non-equilibrium solidification. The effect of temperature on the micro-segregation was discussed. According to the computational results, the solidification completion temperature in the twin-roll strip casting of stainless steel was then determined, which can provide a basis for controlling the location of solidification completion temperature and analysing the crack of the casting strip.

  8. Effect of V and N on the microstructure evolution during continuous casting of steel

    Science.gov (United States)

    Santillana, B.; Eskin, D. G.; Boom, R.; Katgerman, L.

    2012-01-01

    Low Carbon (LC) steel is not expected to be sensitive to hot tearing and/or cracking while microalloyed steels are known for their high cracking sensitivity during continuous casting. Experience of the Direct Sheet Plant caster at Tata Steel in Ijmuiden (the Netherlands), seems to contradict this statement. It is observed that a LC steel grade has a high risk of cracking alias hot tearing, while a High Strength Low Alloyed (HSLA) steel has a very low cracking occurrence. Another HSLA steel grade, with a similar composition but less N and V is however very sensitive to hot tearing. An extreme crack results in a breakout. A previous statistical analysis of the breakout occurrence reveals a one and a half times higher possibility of a breakout for the HSLA grade compared to the LC grade. HSLA with extra N, V shows a four times smaller possibility of breakout than LC. This study assigns the unexpected effect of the chemical composition on the hot tearing sensitivity to the role of some alloying elements such as V and N as structure refiners.

  9. Austenite Grain Growth and the Surface Quality of Continuously Cast Steel

    Science.gov (United States)

    Dippenaar, Rian; Bernhard, Christian; Schider, Siegfried; Wieser, Gerhard

    2014-04-01

    Austenite grain growth does not only play an important role in determining the mechanical properties of steel, but certain surface defects encountered in the continuous casting industry have also been attributed to the formation of large austenite grains. Earlier research has seen innovative experimentation, the development of metallographic techniques to determine austenite grain size and the building of mathematical models to simulate the conditions pertaining to austenite grain growth during the continuous casting of steel. Oscillation marks and depressions in the meniscus region of the continuously casting mold lead to retarded cooling of the strand surface, which in turn results in the formation of coarse austenite grains, but little is known about the mechanism and rate of formation of these large austenite grains. Relevant earlier research will be briefly reviewed to put into context our recent in situ observations of the delta-ferrite to austenite phase transition. We have confirmed earlier evidence that very large delta-ferrite grains are formed very quickly in the single-phase region and that these large delta-ferrite grains are transformed to large austenite grains at low cooling rates. At the higher cooling rates relevant to the early stages of the solidification of steel in a continuously cast mold, delta-ferrite transforms to austenite by an apparently massive type of transformation mechanism. Large austenite grains then form very quickly from this massive type of microstructure and on further cooling, austenite transforms to thin ferrite allotriomorphs on austenite grain boundaries, followed by Widmanstätten plate growth, with almost no regard to the cooling rate. This observation is important because it is now well established that the presence of a thin ferrite film on austenite grain boundaries is the main cause of reduction in hot ductility. Moreover, this reduction in ductility is exacerbated by the presence of large austenite grains.

  10. Hot ductility and deformation behavior of C-Mn/Nb-microalloyed steel related to cracking during continuous casting

    OpenAIRE

    Lanjewar, Harishchandra; Tripathi, Pranavkumar; M Singhai; Patra, PK

    2014-01-01

    Hot ductility studies have been performed on C-Mn and C-Mn-Nb steels with an approach to simulate the effect of cooling conditions experienced by steel in secondary cooling zone during continuous casting. Thermal oscillations prior to tensile straining deteriorate hot ductility of steel by deepening and widening the hot ductility trough. C-Mn steels are found to exhibit ductility troughs in three distinct zones whereas C-Mn-Nb steel shows drop in ductility only at low temperature in the vicin...

  11. Heuristic algorithms for scheduling heat-treatment furnaces of steel casting industries

    Indian Academy of Sciences (India)

    M Mathirajan; V Chandru; A I Sivakumar

    2007-10-01

    This paper addresses a research problem of scheduling parallel, nonidentical batch processors in the presence of dynamic job arrivals, incompatible job-families and non-identical job sizes. We were led to this problem through a realworld application involving the scheduling of heat-treatment operations of steel casting. The scheduling of furnaces for heat-treatment of castings is of considerable interest as a large proportion of the total production time is the processing times of these operations. In view of the computational intractability of this type of problem, a few heuristic algorithms have been designed for maximizing the utilization of heat-treatment furnaces of steel casting manufacturing. Extensive computational experiments were carried out to compare the performance of the heuristics with the estimated optimal value (using the Weibull technique) and for relative effectiveness among the heuristics. Further, the computational experiments show that the heuristic algorithms proposed in this paper are capable of obtaining near (statistically estimated) optimal utilization of heat-treatment furnaces and are also capable of solving any large size real-life problems with a relatively low computational effort.

  12. Elimination of Hot Tears in Steel Castings by Means of Solidification Pattern Optimization

    Science.gov (United States)

    Kotas, Petr; Tutum, Cem Celal; Thorborg, Jesper; Hattel, Jesper Henri

    2012-06-01

    A methodology of how to exploit the Niyama criterion for the elimination of various defects such as centerline porosity, macrosegregation, and hot tearing in steel castings is presented. The tendency of forming centerline porosity is governed by the temperature distribution close to the end of the solidification interval, specifically by thermal gradients and cooling rates. The physics behind macrosegregation and hot tears indicate that these two defects also are dependent heavily on thermal gradients and pressure drop in the mushy zone. The objective of this work is to show that by optimizing the solidification pattern, i.e., establishing directional and progressive solidification with the help of the Niyama criterion, macrosegregation and hot tearing issues can be both minimized or eliminated entirely. An original casting layout was simulated using a transient three-dimensional (3-D) thermal fluid model incorporated in a commercial simulation software package to determine potential flaws and inadequacies. Based on the initial casting process assessment, multiobjective optimization of the solidification pattern of the considered steel part followed. That is, the multiobjective optimization problem of choosing the proper riser and chill designs has been investigated using genetic algorithms while simultaneously considering their impact on centerline porosity, the macrosegregation pattern, and primarily on hot tear formation.

  13. Effect of inter-critical quenching on mechanical properties of casting low-alloy steel

    Directory of Open Access Journals (Sweden)

    Liu Zhongli

    2013-07-01

    Full Text Available For some casting low-alloy steels, traditional quenching and tempering heat treatments can improve the strength; however, sometimes the ductility is not satisfied. Therefore, some kind of effective heat treatment method seems necessary; one which could improve the ductility, but not seriously affect the strength. In this paper, the effect of inter-critical quenching (IQ on the mechanical properties of casting low-alloy steel was studied. IQ was added between quenching and tempering heat treatment; and the microstructure and mechanical properties were compared to the same steel with the traditional quenching and tempering treatments. The experimental results show that the microstructure comprises small-size ferrite and martensite when the IQ is adopted; and that different temperatures can control the ferrite quantity and distribution, and, as a result, influence the mechanical properties. In the case of IQ, the tensile strength decreases just a little, but the ductility increases a lot; and the strength-ductility product (its value is the arithmetic product of elongation and tensile strength increases by between 6% and 10%, which means the IQ heat treatment can improve comprehensive mechanical properties.

  14. Effect of electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting

    Directory of Open Access Journals (Sweden)

    ZHOU Shu-cai

    2007-08-01

    Full Text Available An investigation on the influence of low frequency rotary electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting was experimentally conducted and carried out on an industrial trial basis. The results show that application of appropriate electromagnetic stirring parameters can obviously improve the macrostructure of austenitic stainless steel, in which both columnar and equiaxed grains can be greatly refined and shrinkage porosity or cavity zone along centerline can be remarkably decreased due to eliminating intracrystalline and enlarging equiaxed grains zone. The industrial trials verify that the electromagnetic stirring intensity of austenitic stainless steel should be higher than that of plain carbon steel. Electromagnetic stirring has somewhat affected the macrostructure of austenitic stainless steel even if the magnetic flux density of the electromagnetic stirring reaches 90 mT (amplitude reaches 141 mT in average at frequency f=3-4Hz, which provides a reference for the optimization of design and process parameters when applying the rotary electromagnetic stirrer.

  15. Effect of electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    An investigation on the influence of low frequency rotary electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting was experimentally conducted and carried out on an industrial trial basis. The results show that application of appropriate electromagnetic stirring parameters can obviously improve the macrostructure of austenitic stainless steel, in which both columnar and equiaxed grains can be greatly refined and shrinkage porosity or cavity zone along centerline can be remarkably decreased due to eliminating intracrystalline and enlarging equiaxed grains zone. The industrial trials verify that the electromagnetic stirring intensity of austenitic stainless steel should be higher than that of plain carbon steel. Electromagnetic stirring has somewhat affected the macrostructure of austenitic stainless steel even if the magnetic flux density of the electromagnetic stirring reaches 90 mT (amplitude reaches 141 mT ) in average at frequency f=3-4Hz, which provides a reference for the optimization of design and process parameters when applying the rotary electromagnetic stirrer

  16. Elimination of Hot Tears in Steel Castings by Means of Solidification Pattern Optimization

    DEFF Research Database (Denmark)

    Kotas, Petr; Tutum, Cem Celal; Thorborg, Jesper;

    2012-01-01

    the solidification pattern, i.e., establishing directional and progressive solidification with the help of the Niyama criterion, macrosegregation and hot tearing issues can be both minimized or eliminated entirely. An original casting layout was simulated using a transient three-dimensional (3-D) thermal fluid model...... of the solidification interval, specifically by thermal gradients and cooling rates. The physics behind macrosegregation and hot tears indicate that these two defects also are dependent heavily on thermal gradients and pressure drop in the mushy zone. The objective of this work is to show that by optimizing...... incorporated in a commercial simulation software package to determine potential flaws and inadequacies. Based on the initial casting process assessment, multiobjective optimization of the solidification pattern of the considered steel part followed. That is, the multiobjective optimization problem of choosing...

  17. Assessment of Crack Detection in Heavy-Walled Cast Stainless Steel Piping Welds Using Advanced Low-Frequency Ultrasonic Methods

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Michael T.; Crawford, Susan L.; Cumblidge, Stephen E.; Denslow, Kayte M.; Diaz, Aaron A.; Doctor, Steven R.

    2007-03-01

    Studies conducted at the Pacific Northwest National Laboratory in Richland, Washington, have focused on assessing the effectiveness and reliability of novel approaches to nondestructive examination (NDE) for inspecting coarse-grained, cast stainless steel reactor components. The primary objective of this work is to provide information to the U.S. Nuclear Regulatory Commission on the effectiveness and reliability of advanced NDE methods as related to the inservice inspection of safety-related components in pressurized water reactors (PWRs). This report provides progress, recent developments, and results from an assessment of low frequency ultrasonic testing (UT) for detection of inside surface-breaking cracks in cast stainless steel reactor piping weldments as applied from the outside surface of the components. Vintage centrifugally cast stainless steel piping segments were examined to assess the capability of low-frequency UT to adequately penetrate challenging microstructures and determine acoustic propagation limitations or conditions that may interfere with reliable flaw detection. In addition, welded specimens containing mechanical and thermal fatigue cracks were examined. The specimens were fabricated using vintage centrifugally cast and statically cast stainless steel materials, which are typical of configurations installed in PWR primary coolant circuits. Ultrasonic studies on the vintage centrifugally cast stainless steel piping segments were conducted with a 400-kHz synthetic aperture focusing technique and phased array technology applied at 500 kHz, 750 kHz, and 1.0 MHz. Flaw detection and characterization on the welded specimens was performed with the phased array method operating at the frequencies stated above. This report documents the methodologies used and provides results from laboratory studies to assess baseline material noise, crack detection, and length-sizing capability for low-frequency UT in cast stainless steel piping.

  18. Thermal Stress Cracking of Slide-Gate Plates in Steel Continuous Casting

    Science.gov (United States)

    Lee, Hyoung-Jun; Thomas, Brian G.; Kim, Seon-Hyo

    2016-04-01

    The slide-gate plates in a cassette assembly control the steel flow through the tundish nozzle, and may experience through-thickness cracks, caused by thermal expansion and/or mechanical constraint, leading to air aspiration and safety concerns. Different mechanisms for common and rare crack formation are investigated with the aid of a three-dimensional finite-element model of thermal mechanical behavior of the slide-gate plate assembly during bolt pretensioning, preheating, tundish filling, casting, and cooling stages. The model was validated with previous plant temperature measurements of a ladle plate during preheating and casting, and then applied to a typical tundish-nozzle slide-gate assembly. The formation mechanisms of different types of cracks in the slide-gate plates are investigated using the model and evaluated with actual slide-gate plates at POSCO. Common through-thickness radial cracks, found in every plate, are caused during casting by high tensile stress on the outside surfaces of the plates, due to internal thermal expansion. In the upper plate, these cracks may also arise during preheating or tundish filling. Excessive bolt tightening, combined with thermal expansion during casting may cause rare radial cracks in the upper and lower plates. Rare radial and transverse cracks in middle plate appear to be caused during tundish filling by impingement of molten steel on the middle of the middle plate that generates tensile stress in the surrounding refractory. The mechanical properties of the refractory, the bolt tightening conditions, and the cassette/plate design are all important to service life.

  19. Waste of cleaning emulsion sewage as inhibitors of steel corrosion

    Science.gov (United States)

    Fazullin, D. D.; Mavrin, G. V.; Shaikhiev, I. G.

    2016-06-01

    The article describes the corrosion test of steel of the brand 20 in the stratal water. To increase corrosion resistance as a corrosion inhibitor the concentrate waste emulsion of the mark "Incam- 1" was provided. The article presents studies of the corrosion rate with different dosages of corrosion inhibitor in the stratal water. Based on these research results are revealed that the degree of protection of steel is 27% at a dosage of 3.8 g / dm3.

  20. Effect of Rare Earths on Corrosion Resisting Properties of Carbon-Manganese Clean Steels

    Institute of Scientific and Technical Information of China (English)

    郭锋; 林勤; 孙学义

    2004-01-01

    Electrochemistry experiments were made on carbon-manganese clean steel with rare earths Ce and La respectively to observe corrosion parameters such as corrosion current icorr, and characteristic potential of pitting Eb. The results indicate that the rare earths have effect on corrosion resisting properties of carbon-manganese clean steel, and the optimum contents of La is about 0.011% (mass fraction) and Ce about 0.014% (mass fraction) respectively. The change of corrosion resistance is related to the action of rare earths on microstructure and effect on surface state of samples in the process of polarization.

  1. Čiščenje valjanega jekla s peskanjem: Cleaning of rolled steel with sandblasting:

    OpenAIRE

    Legat, Franc

    1997-01-01

    Sandblasting machines for cleaning of steel in rods and coils, the productivity and characteristics of different processes, the nature and the shape of surface modifications as well as the characteristics of different steel sands are described and discussed on the base of industrial experience. V članku so opisane naprave za peskanje jekla v palicah in kolobarjih, produktivnost raznih postopkov, značilnosti tehnologije, narava in oblika sprememb na površini peskanega jekla in značilnosti r...

  2. Autonomous Optimization of a Solidification Pattern and Its Effect on Porosity and Segregation in Steel Castings

    DEFF Research Database (Denmark)

    Kotas, Petr; Tutum, Cem Celal; Hattel, Jesper Henri

    2011-01-01

    and inadequacies. After this initial assessment, a new geometrical model was suggested with the redesigned gating system and rearranged chills to obtain better filling and solidification patterns. Based on the improved model, relevant optimization targets and constraints were defined. One multi......The present paper considers optimization of a solidification pattern of a gravity sand-cast steel part. That is, the choice of proper riser and chill designs has been investigated using genetic algorithms while simultaneously considering their impact on centerline porosity and macrosegregation...

  3. Quench ageing behaviour of duplex cast steel with nano-scale ε-Cu particles

    Directory of Open Access Journals (Sweden)

    D. Dyja

    2007-01-01

    Full Text Available Purpose: The aim of the study was to examine the effectiveness and usefulness of the quench ageing on theservice properties of massive duplex cast steel. The mechanism of precipitation of a ε-Cu phase and its effect onthe mechanical properties of the cast steel were investigated.Design/methodology/approach: The ferrite substructure was examined on a JOEL JEM HREM. The analysisof chemical composition of selected micro-regions was carried out using a scanning electron microscope. Theverification of the metallographic examination results was done using the Thermo-Calc program.Findings: Quench ageing causes an increase in hardness and drop in impact resistance, which results from theformation of the ε-Cu phase. The ageing parameters have a substantial influence on the ferrite substructure and thedegree of coherence, dispersion and amount of the ε-Cu phase. The ageing treatment at 480˚C causes, in additionto the precipitation of the ε-Cu phase coherent with the matrix, the formation of a α’-Cr phase and an α-Fe phase.Practical implications: Duplex cast steels are becoming an irreplaceable material in the elements of equipmentexposed to the simultaneous action of corrosive and erosive environment. In the case of massive elements, suchas pump (rotors and guide vanes and pipeline elements etc., which are operated in corrosive environments ofwater suspensions of solids of different type and gradation, the effect of ageing will be much lower than in smalllaboratory specimens, which is associated with the presence of a large amount of the incoherent ε-Cu phase inthe cast steel after the solution heat treatment.Originality/value: The lower limit of ageing temperature (480˚C coincide with the temperature of anundesirable spinodal decomposition of the ferrite, which is partially responsible for the slight increase inhardness and a drop in plastic properties. This is the indication that the lower temperature of ageing duplex caststeels with copper

  4. Microstructures of cast-duplex stainless steel after long-term aging

    Energy Technology Data Exchange (ETDEWEB)

    Chung, H.M.; Chopra, O.K.

    1985-10-01

    Microstructures of cast-duplex stainless steels subjected to long-term aging either in the laboratory or during in-reactor service have been characterized and compared by TEM, SEM, and optical microscopy. The microstructural characteristics have been correlated with the impact failure behavior of the material. G-phase, ', and an unidentified Type X precipitate were responsible for the ferrite-phase embrittlement. Precipitation of M23C6 carbides on austenite-ferrite boundaries further degraded the reactor-aged material.

  5. Mechanical properties of phase constituents in selected grades of cast steel

    OpenAIRE

    M. Garbiak; Zubko, P.

    2011-01-01

    The nanoindentation measurements performed on three cast steels of 0.3C-30Ni-18Cr type with various content of niobium and titanium were carried out.Mechanical propertiesofthe main phaseconstituents of the alloys, such as austenite, MC and M23C6 type carbides, were determined and analysed. The values of hardness (H) and Young modulus (E) for the austenite matrix were similar within the tested alloys. Essential differences (H=12 ÷ 24 GPa; E = 250 ÷ 400 GPa) were found between the carbide phase...

  6. Precipitation kinetics in austenitic 18Cr-30Ni-Nb cast steel

    OpenAIRE

    M. Garbiak; R. Chylińska

    2008-01-01

    The study presents the results of investigations on the precipitation kinetics in austenitic 18%Cr-30%Ni cast steel stabilised with an addition of 1.84 wt% niobium. Phase analysis of isolates extracted from the alloy subjected to annealing within the temperature range of 600–1000oC during 10–1000 h was made. The phase constitution of the isolates mainly comprised niobium carbides of the NbC type and complex chromium carbides of the Cr23C6 type. In specimens annealed within the temperature ran...

  7. Electric spark method cleaning the surface of steel 08G2S

    International Nuclear Information System (INIS)

    The process of spark cleaning the surface of steel 08G2S investigated. As a result of processing the oxide layer removed and contact resistance reduced. The intensity of the crater, which influences the magnitude of the roughness depends on the degree of overheating of the metal by increasing the density of craters. The multipass cleaning cause of cracking surface. Based on the results determined the most rational process settings. (authors)

  8. MICROSTRUCTURE AND TENSILE PROPERTY OF AN AS-CAST DUPLEX STAINLESS STEEL

    Institute of Scientific and Technical Information of China (English)

    P.L.Mao; K.Yang; G.Y.Su

    2001-01-01

    The effect of high temperature solution heat treatment on the microstructure and ten-sile property of as-cast 0Cr17Mn14Mo2N duplex stainless steel was investigated.Itwas found that the morphology ofδ-ferrite in the dual phases microstructures changedgradually from dendritic to lamellar and then to spheroidal,and its distribution be-came more uniform under appropriate treatment.When the treat temperature waslower than 1250C,the spheroidial ratio and the homogeneous distribution o fδ-ferriteincrease with increasing temperature,which corresponds to a better tensile property.In addition,when the treat temperature reached 1250~C and above,the microstructureconsists of coarse equiaxial δ-ferrite grains with the needle austenite at its boundaries,which results in a decrease of the tensile properties of the steel.

  9. Modelling of phenomena in solid state for the steel casting cooled by liquid

    Directory of Open Access Journals (Sweden)

    A. Kulawik

    2011-04-01

    Full Text Available In this paper a mathematical model of cooling process for steel castings is presented. Effect of convective motion of the coolant onmaterial structure after cooling process is investigated. Mathematical and numerical model based on Generalized Difference Method for axysimmertric elements is used. To solve the Navier-Stokes equation the characteristic based split scheme (CBS has been applied. The solution of the heat transport equation with the convective term has been obtained by a stabilized meshless method. To determine of the phase transformation the macroscopic model built on the basis of Time Temperature Transformation diagrams for continuous cooling of medium-carbon steel has been used. The temporary temperature fields, the phase transformation, thermal and structural strains for the cooled element and the fields of temperature and velocity for the coolant have been determined.

  10. Properties of cast Ti-stabilised stainless steel after long-term ageing

    International Nuclear Information System (INIS)

    Mechanical properties and microstructure are studied and compared for two kinds of specimens of cast Ti-stabilized stainless steel 08Kh18N10T used for manufacturing of valves and pumps in nuclear power plants. One set of specimens represents the main gate valve material after 106000 h (∼ 12 years) operation at 270 deg C. The comparison is made with reference specimens in as-fabricated state. The results of impact tests, hardness measurements and microscopic examination show that 12 year operation gives rise to the shift of ductile-brittle transition temperature to higher values (from - 68 deg C - 103 deg C). The microstructure of both materials is similar. The microhardness of δ-ferrite in the steel after long-term operation is slightly higher

  11. The PISC parametric study on the effect of the texture of cast austenitic stainless steel

    International Nuclear Information System (INIS)

    Within the framework of Action 4 (Austenitic Steel Testing) of PISC III, a parametric study was carried out on a set of centrifugally cast stainless steel samples, representative of the main coolant piping of pressurized water nuclear reactors. The samples are obtained from different manufacturers, and feature various grain textures and dimensions. Artificial and realistic flaws were used to assess the detection and sizing capability of ultrasonic examination techniques. The paper analyzes the data as a function of the metal structure and of the main parameter of the testing techniques, which include TRL contact probes and immersion focusing transducers. Guidelines are deduced as to the selection of inspection techniques, in relation with the metallurgical texture of each specimen. In addition, the influence of the presence of a weld across the wavepath is evaluated, as well as the similarity between the responses obtained from crack-like machined reflectors and mechanical fatigue cracks

  12. Low cycle fatigue of GX12CrMoVNbN9-1 cast steel at elevated temperature

    Directory of Open Access Journals (Sweden)

    S. Mroziński

    2011-11-01

    Full Text Available Purpose: The purpose of the paper is to characterize the low cycle fatigue of high - chromium martensitic GX12CrMoVNbN9-1 cast steel from the perspective of the strain and energy criterion.Design/methodology/approach: The tests of fatigue strength within the scope of small amount of cycles to failure at room temperature and elevated temperature (400, 550 and 600°C were carried out on GX12CrMoVNbN9-1 cast steel. The fatigue tests were run for five assumed levels of controlled amplitude of total strain εac (0.25; 0.30; 0.35; 0.50 and 0.60%. The loading applied in the experiment oscillated sinusoidally with the stress ratio R = -1 and frequency f = 0.2 Hz. The fatigue tests were performed by means of Instron 8501 hydropulser. Tests pieces for the fatigue tests were round and threaded.Findings: The examined cast steel during low cycle fatigue is subject to intense weakening. The period of stabilization was not revealed during the cyclic loading of the cast steel, neither at room temperature, nor elevated one. Moreover, it has been proved that the extent of changes in the cyclic properties is influenced by the level of strain and temperature.Practical implications: Obtained results of the tests are indispensable for the formulation of necessary characteristics of high-temperature creep resisting steels and cast steels.Originality/value: The paper presents the fatigue characteristics of GX12CrMoVNbN9-1 cast steel within the scope of small amount of cycles to failure. The fatigue characteristics of the examined cast steel was developed for both: room temperature and elevated temperature - 400, 550 and 600°C. Fatigue life of the investigated cast steel was described using the equations of Ramberg-Osgood and Manson-Coffin-Basquin, and presented from the perspective of the energy criterion.

  13. Influence of submerged entry nozzle clogging on the behavior of molten steel in continuously cast slab molds

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    The influence of submerged entry nozzle clogging on the behavior of molten steel in continuously cast slab molds was studied using commercial code CFX4.3. The results indicate that clogging at the top part of the nozzle port not only increases the velocity of molten steel, but also enhances the wall shear stress, F number and heat flux. This clogging has the greatest effect on the behavior of molten steel. However, clogging at the top 1/3 of the nozzle only increases the velocity of molten steel and has little influence. Clogging at the bottom of the nozzle almost has no influence.

  14. Chemical Homogenization Of Liquid Steel Flowed Through Continuous Casting Slab Tundish During Alloying Process

    Directory of Open Access Journals (Sweden)

    Cwudziński A.

    2015-06-01

    Full Text Available This paper presents the results of research on the behaviour of an alloy addition in steel flowing through the tundish used for casting slabs. The device under examination is a wedge-shaped single-nozzle tundish of a capacity of 30 Mg. Due to the complexity of alloy addition dissolution and dispersion in metallurgical processes, a decision was made to use the Species Model available within the Ansys-Fluent® program. For describing the turbulence, the Realizable k-ɛ model was chosen. By defining the heat losses on respective planes making up the virtual model, the non-isothermal conditions existing during the flow of liquid steel through the tundish were considered. From the performed numerical simulations, the fields of steel flow and steel temperature and alloy addition concentration in the tundish working space were obtained. In order to accurately illustrate the process of chemical homogenization in the tundish working space, mixing curves were recorded. Based on the obtained results (mixing curves, the mixing time needed for achieving the 95% level of chemical homogenization was calculated.

  15. A scheduling system for the steelmaking ? continuous casting process ? A case study from the steel-making industry

    OpenAIRE

    Missbauer, Hubert; Hauber, Wolfgang; Stadler, Werner

    2009-01-01

    Abstract This paper describes the models, algorithms and implementation results of a computerized scheduling system for the steelmaking ? continuous casting process of a steel plant in Austria. The basis for the scheduling task is a preliminary production schedule for the continuous casters (sequence of charges that must be consecutively cast and their allocation to the continuous casters). The scheduling task can be structured as four subproblems: (1) Scheduling the continuous ...

  16. Metadynamic Recrystallization Behavior of As-cast 904L Superaustenitic Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    Wei ZHANG; Jing ZHANG; Ying HAN; Rong LIU; De-ning ZOU; Guan-jun QIAO

    2016-01-01

    The metadynamic recrystallization (MDRX)behavior of as-cast 904L superaustenitic stainless steel was in-vestigated by double pass isothermal compression tests at temperatures of 950-1 150 ℃,strain rates of 0�05-5 s-1 and interval of 1-100 s.The effects of working parameters (deformation temperature,strain rate,pre-strain and in-terval time)on the flow curves and microstructural evolution were discussed.The MDRX fraction increased obvious-ly with the increase of deformation temperature,strain rate and interval time.The MDRX softening was controlled by the migration of grain boundary,annihilation of dislocation and dynamic recrystallization.Moreover,the kinetic model was established for the prediction of MDRX behavior of as-cast 904L superaustenitic stainless steel based on the experimental data.A good agreement between the predicted and the experimental values was achieved (correla-tion coefficient R2=0�98),indicating a satisfactory accuracy.

  17. Original position statistic distribution analysis study of low alloy steel continuous casting billet

    Institute of Scientific and Technical Information of China (English)

    WANG Haizhou; ZHAO Pei; CHEN Jiwen; LI Meiling; YANG Zhijun; WU Chao

    2005-01-01

    The homogeneity of low alloy steels continuous casting billet obtained under different technological conditions has been investigated by original position statistic distribution analysis technique. On the basis of systematic analysis of ten thousands primary optical signals at the corresponding original positions, the quantitative statistic distribution information of each element was obtained. The biggest degrees of segregation of low alloy steel continuous casting billet were calculated accurately according to the quantitative distribution maps of the contents. It was suggested that the weight ratio in a certain content range was used to judge the homogeneity of the materials, and the two models -- the total weight ratio of contents (the degree of statistic homogeneity, H) within the permissive content range (C0±R) and the median value confidence extension ratio (the degree of statistic segregation, S) at 95% of confidence limit of weight ratio -- were put forward. The two models reflect the composition and state distribution regularity of the metal materials in a large region. The difference between the sample with high columnar crystal and the sample with high equiaxed crystal has been studied by using the two models.

  18. Alloy Shrinkage factors for the investment casting of 17-4PH stainless steel parts

    Energy Technology Data Exchange (ETDEWEB)

    Sabau, Adrian S [ORNL; Porter, Wallace D [ORNL

    2008-01-01

    In this study, the alloy shrinkage factors were obtained for the investment casting of 17-4PH stainless steel parts. For the investment casting process, unfilled wax and fused silica with a zircon prime coat were used for patterns and shell molds, respectively. Dimensions of the die tooling, wax pattern, and casting were measured using a Coordinate Measurement Machine. For all the properties, the experimental data available in the literature did not cover the entire temperature range necessary for process simulation. A comparison between the predicted material property data measured property data is made. It was found that most material properties were accurately predicted over the most of the temperature range of the process. Several assumptions were made in order to obtain a complete set of mechanical property data at high temperatures. Thermal expansion measurements for the 17-4PH alloy were conducted at heating and cooling. As a function of temperature, the thermal expansion for both the alloy and shell mold materials showed different evolution at heating and cooling. Thus, one generic simulation were performed with thermal expansion obtained at heating and another one with thermal expansion obtained at cooling. The alloy dimensions were obtained from numerical simulation results of solidification, heat transfer, and deformation phenomena. As compared with experimental results, the numerical simulation results for the shrinkage factors were slightly over-predicted.

  19. Development of Stronger and More Reliable Cast Austenitic Stainless Steels (H-Series) Based on Scientific and Design Methodology

    Energy Technology Data Exchange (ETDEWEB)

    Pankiw, Roman I; Muralidharan, G. (Murali); Sikka, Vinod K.

    2006-06-30

    The goal of this project was to increase the high-temperature strength of the H-Series of cast austenitic stainless steels by 50% and the upper use temperature by 86 to 140 degrees fahrenheit (30 to 60 degrees celsius). Meeting this goal is expected to result in energy savings of 35 trillion Btu/year by 2020 and energy cost savings of approximately $230 million/year. The higher-strength H-Series cast stainless steels (HK and HP type) have applications for the production of ethylene in the chemical industry, for radiant burner tubes and transfer rolls for secondary processing of steel in the steel industry, and for many applications in the heat treating industry, including radiant burner tubes. The project was led by Duraloy Technologies, Inc., with research participation by Oak Ridge National Laboratory (ORNL) and industrial participation by a diverse group of companies.

  20. Chemical cleaning of porous stainless steel cross-flow filter elements for nuclear waste applications

    International Nuclear Information System (INIS)

    The Waste Treatment and Immobilization Plant (WTP) currently under construction for treatment of High-Level Waste (HLW) at the Hanford Site will rely on cross-flow ultrafiltration to provide solids-liquid separation as a core part of the treatment process. To optimize process throughput, periodic chemical cleaning of the porous stainless steel filter elements has been incorporated into the design of the plant. It is currently specified that chemical cleaning with nitric acid will occur after significant irreversible membrane fouling is observed. Irreversible fouling is defined as fouling that cannot be removed by backpulsing the filter. PNNL has investigated chemical cleaning processes as part of integrated tests with HLW simulants and with actual Hanford tank wastes. To quantify the effectiveness of chemical cleaning, the residual membrane resistance after cleaning was compared against the initial membrane resistance for each test in a series of long-term fouling tests. The impact of the small amount of residual resistance in these tests could not be separated from other parameters and the historical benchmark of >1 GPM/ft2 for clean water flux was determined to be an adequate metric for chemical cleaning. Using the results from these tests, a process optimization strategy is presented suggesting that for the simulant material under test, the value of chemical cleaning may be suspect. The period of enhanced filtration may not be enough to offset the down time required for chemical cleaning, without respect to the other associated costs.

  1. Chemical cleaning of porous stainless steel cross-flow filter elements for nuclear waste applications

    Energy Technology Data Exchange (ETDEWEB)

    Billing, Justin M.; Daniel, Richard C.; Hallen, Richard T.; Schonewill, Philip P.; Shimskey, Rick W.; Peterson, Reid A.

    2011-05-10

    The Waste Treatment and Immobilization Plant (WTP) currently under construction for treatment of High-Level Waste (HLW) at the Hanford Site will rely on cross-flow ultrafiltration to provide solids-liquid separation as a core part of the treatment process. To optimize process throughput, periodic chemical cleaning of the porous stainless steel filter elements has been incorporated into the design of the plant. It is currently specified that chemical cleaning with nitric acid will occur after significant irreversible membrane fouling is observed. Irreversible fouling is defined as fouling that cannot be removed by backpulsing the filter. PNNL has investigated chemical cleaning processes as part of integrated tests with HLW simulants and with actual Hanford tank wastes. To quantify the effectiveness of chemical cleaning, the residual membrane resistance after cleaning was compared against the initial membrane resistance for each test in a series of long-term fouling tests. The impact of the small amount of residual resistance in these tests could not be separated from other parameters and the historical benchmark of >1 GPM/ft2 for clean water flux was determined to be an adequate metric for chemical cleaning. Using the results from these tests, a process optimization strategy is presented suggesting that for the simulant material under test, the value of chemical cleaning may be suspect. The period of enhanced filtration may not be enough to offset the down time required for chemical cleaning, without respect to the other associated costs.

  2. Cleaning the magnesium oxide contaminated stainless steel system using a high temperature decontamination process

    International Nuclear Information System (INIS)

    A high pressure and high temperature (HTHP) system made of stainless steel-316, that simulates the reactor coolant systems of pressurized water reactors has been constructed for carrying out experimental investigations on power reactor water chemistry. After two months of operation at 280 C, magnesium was observed in the coolant. This was attributed to the failure of some heater pins that contained magnesium oxide as insulator. This magnesium oxide got distributed over the entire system. In order to remove the magnesium that had deposited and reacted over the oxide film formed over the stainless steel surfaces, the system was chemically cleaned using a mixture of nitrilo-tri-acetic-acid (NTA) and N2H4 at high temperature. The chromium containing oxide film formed over the stainless steel surfaces are normally removed using oxidizing pretreatment followed by treatment with reducing formulation. A minimum of three such cycles are required to complete the dissolution of contaminated oxide film. It has been proved elsewhere that chromium-containing oxides can be dissolved by simple chelating agents but at a relatively higher temperature (150-180 C) with NTA. Thus, NTA based process was tested for its capability to remove the magnesium contaminated oxide film formed over stainless steel. In addition to stainless steel, the system has few carbon steel areas. Hence, the compatibility of stainless steel and carbon steel to the NTA-N2H4 mixture was determined. Tests were carried out at different concentrations of NTA and at different pH. It was observed that carbon steel corrosion rates were quite high at low pH. With increasing pH, the corrosion rate decreased. The surface roughening observed at low pH was not observed at pH 8.0. Hence, it was decided to carry out the cleaning at pH 7.0 and with NTA concentration of 5 mM. Visual examination of the test flanges after the cleaning indicated complete removal of the oxide film. Results of chemical analysis indicated that

  3. Compatibility studies on carbon steel and Monel-400 in steam generator cleaning formulations

    International Nuclear Information System (INIS)

    EDTA based Steam Generator (SG) cleaning formulations are being used worldwide to remove the sludge accumulated on tubes, tube sheets and the baffle plates of the tubes in steam generators. In early Indian PHWRs, SG shells are made up of carbon steel and the tubes are made of Monel-400. Corrosion compatibility of carbon steel and Monel-400 in SG cleaning formulations were evaluated so as to assess the suitability of these formulations for cleaning the steam generators. SG cleaning iron formulation contains 10% EDTA at pH 6 (pH additive NH3) along with 1% hydrazine. These experiments were carried out at 95 degC under inert condition. The SG cleaning copper formulation consists of 5% EDTA at pH 9.5 (pH adjusted by EDA) and 2% hydrogen peroxide. These experiments were conducted at room temperature. Further, experiments were carried out to study the effect of oxygen, the effect of pH additives namely NH3, EDA and NaOH, effect of presence of Fe3+ ions, effect of roughening of the surface on corrosion rate of carbon steel. The role of hydrazine and effect of decomposed products of EDTA on corrosion of carbon steel were also studied. Elaborate study was done on specimens that were prepared by cold-rolling and hot-rolling. Inhibitors like Rodine-92B and some non-sulphur inhibitors such as 1,2,3 benzotriazole, hexynols etc. were tested to determine their inhibition efficiency on corrosion of carbon steel. Microscopic observations on the exposed specimens were done to observe any localised attack. (author)

  4. Fracture mechanics behaviour of ductile cast iron and martensitic steel at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Udoh, A.; Klenk, A.; Roos, E. [Stuttgart Univ. (Germany). MPA; Sasikala, G. [Indira Gandhi Centre for Atomic Research (IGCAR), Kalpakkam (India)

    2010-07-01

    Ductile cast iron is employed increasingly due to the advantages regarding foundry practice, design as well as economic advantages in the thermal machinery and power plant construction. It is employed preferably where higher toughness is required, e.g. in valves or thickwalled components of thermal or nuclear power plants. For this reason the safety and availability criteria for fracture mechanics assessment of components are necessary in addition to the conventional strength design. Alloys with silicon and molybdenum are developed for the application at higher temperatures. The increase in the thermal efficiency of fossil fired steam power plant that can be achieved by increasing the steam temperature and pressure has provided the incentive for development of the 9% chromium steels towards improved creep rupture strength. During the last twenty years, three such steels, P91 (9Cr-1Mo-VNb), E911 (9Cr-1Mo-1W-V-Nb) and P92 (9Cr-0,5Mo-1,8W-V-Nb), have been developed for commercial production. For application in piping systems and boiler construction sufficient reliable information concerning the long-term behaviour are necessary as well as knowledge about fracture mechanical behaviour in order to ensure integrity of components. Different methods to characterize fracture behaviour of ductile cast iron and martensitic steel at elevated temperature have been employed. The RBR method is a novel and simple method developed at IGCAR for characterizing the ductile fracture behaviour of materials from tensile tests of cylindrical specimens. Using the data evaluated at both institutes, a fracture mechanics characterisation by determining crack initiation and crack resistance by J{sub R}-curves and RBR parameters is presented. (orig.)

  5. Application of thermoelectricity to NDE of thermally aged cast duplex stainless steels and neutron irradiated ferritic steels

    International Nuclear Information System (INIS)

    The thermoelectric power (TEP) of an alloy depends mainly on its temperature, its chemical composition and its atomic arrangement. The TEP measurement technique is used in order to study and follow two degradation phenomena affecting some components of the primary loop of Pressurized Water Reactors (PWR). The first degradation phenomenon is the thermal aging of cast duplex stainless steel components. The de-mixing of the ferritic Fe-Cr-Ni slid solution is responsible for the decreasing of the mechanical characteristics. Laboratory studies have shown the sensitivity of TEP to the de-mixing phenomenon. TEP increases linearly with the ferrite content and with and Arrhenius-type aging parameter depending on time, temperature and activation energy. TEP is also correlated to mechanic characteristics. The second degradation phenomenon is the aging of ferritic steels due to neutron irradiation at about 290 deg C. In this case, the degradation mechanism is the formation of clusters of solute atoms and/or copper rich precipitates that causes the hardening of the material. As a first approach, a study of binary Fe-Cu alloys irradiated by electrons at 288 deg C has revealed the possibility of following the copper depletion of the ferritic matrix. Moreover, the recovery of the mechanical properties of the alloy by annealing can be monitored. Finally, a correlation between Vickers hardness and TEP has been established. (author)

  6. Segregation of phosphorus in Cr-Mo-V steel and cast steel after long time service at elevated temperature

    International Nuclear Information System (INIS)

    Steel and cast steel after long time service in the temperatures range 500-530oC have been investigated. In the areas close to the grain boundaries diffusion of phosphorus causes an occurrence the stable layers of ferrite enriched in phosphorus. The relation ship between the concentration of phosphorus in the alloy and the width of the enriched layers have been established.The width of the phosphorus enriched layers are independent of the grain size. The results suggest that diffusion of phosphorus is controlled by the bulk mechanism from the interior to the grain boundary and takes place only in the area near the grain boundary. Grain boundary etching method by using of picric acid is a useful as a technique analyzing grain boundary concentration of phosphorus. The good method of investigation is the measurement of the width of the etching grooves as the grain boundaries on the SEM microstructures. Segregation of phosphorus in the vicinity of grain boundaries drastically decreases the notch impact fracture toughness and increases the brittle fracture transition temperature of the alloy. Desegregation of phosphorus from the area close to the grain boundaries to the interior grains is long-time process and takes a few hours annealing in the temperature range 650-700oC. Desegregation of phosphorus from area close to the grain boundaries into the interior of grains there is observed an enrichment in the phosphorus of the ferrite around the interphase carbides/matrix boundaries. The notch impact fracture toughness of steel is related to the changes in time and temperature of phosphorus desegration process. (author)

  7. Final Report, Volume 2, The Development of Qualification Standards for Cast Duplex Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Russell, Steven, W.; Lundin, Carl, W.

    2005-09-30

    The scope of testing cast Duplex Stainless Steel (DSS) required testing to several ASTM specifications, while formulating and conducting industry round robin tests to verify and study the reproducibility of the results. ASTM E562 (Standard Test Method for Determining Volume Fraction by Systematic manual Point Count) and ASTM A923 (Standard Test Methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic/Ferritic Stainless Steels) were the specifications utilized in conducting this work. An ASTM E562 industry round robin, ASTM A923 applicability study, ASTM A923 industry round robin, and an ASTM A923 study of the effectiveness of existing foundry solution annealing procedures for producing cast DSS without intermetallic phases were implemented. In the ASTM E562 study, 5 samples were extracted from various cast austenitic and DSS in order to have varying amounts of ferrite. Each sample was metallographically prepared by UT and sent to each of 8 participants for volume fraction of ferrite measurements. Volume fraction of ferrite was measured using manual point count per ASTM E562. FN was measured from the Feritescope® and converted to volume fraction of ferrite. Results indicate that ASTM E562 is applicable to DSS and the results have excellent lab-to-lab reproducibility. Also, volume fraction of ferrite conversions from the FN measured by the Feritescope® were similar to volume fraction of ferrite measured per ASTM E562. In the ASTM A923 applicability to cast DSS study, 8 different heat treatments were performed on 3 lots of ASTM A890-4A (CD3MN) castings and 1 lot of 2205 wrought DSS. The heat treatments were selected to produce a wide range of cooling rates and hold times in order to study the suitability of ASTM A923 to the response of varying amounts on intermetallic phases [117]. The test parameters were identical to those used to develop ASTM A923 for wrought DSS. Charpy V-notch impact samples were extracted from the castings and wrought

  8. Final Report, Volume 2, The Development of Qualification Standards for Cast Duplex Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Russell, Steven, W.; Lundin, Carl, D.

    2005-09-30

    The scope of testing cast Duplex Stainless Steel (DSS) required testing to several ASTM specifications, while formulating and conducting industry round robin tests to verify and study the reproducibility of the results. ASTM E562 (Standard Test Method for Determining Volume Fraction by Systematic manual Point Count) and ASTM A923 (Standard Test Methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic/Ferritic Stainless Steels) were the specifications utilized in conducting this work. An ASTM E562 industry round robin, ASTM A923 applicability study, ASTM A923 industry round robin, and an ASTM A923 study of the effectiveness of existing foundry solution annealing procedures for producing cast DSS without intermetallic phases were implemented. In the ASTM E562 study, 5 samples were extracted from various cast austenitic and DSS in order to have varying amounts of ferrite. Each sample was metallographically prepared by UT and sent to each of 8 participants for volume fraction of ferrite measurements. Volume fraction of ferrite was measured using manual point count per ASTM E562. FN was measured from the Feritescope{reg_sign} and converted to volume fraction of ferrite. Results indicate that ASTM E562 is applicable to DSS and the results have excellent lab-to-lab reproducibility. Also, volume fraction of ferrite conversions from the FN measured by the Feritescope{reg_sign} were similar to volume fraction of ferrite measured per ASTM E562. In the ASTM A923 applicability to cast DSS study, 8 different heat treatments were performed on 3 lots of ASTM A890-4A (CD3MN) castings and 1 lot of 2205 wrought DSS. The heat treatments were selected to produce a wide range of cooling rates and hold times in order to study the suitability of ASTM A923 to the response of varying amounts on intermetallic phases [117]. The test parameters were identical to those used to develop ASTM A923 for wrought DSS. Charpy V-notch impact samples were extracted from the

  9. Corrosion Inhibiting Mechanism of Nitrite Ion on the Passivation of Carbon Steel and Ductile Cast Iron for Nuclear Power Plants

    Directory of Open Access Journals (Sweden)

    K. T. Kim

    2015-01-01

    Full Text Available While NaNO2 addition can greatly inhibit the corrosion of carbon steel and ductile cast iron, in order to improve the similar corrosion resistance, ca. 100 times more NaNO2 addition is needed for ductile cast iron compared to carbon steel. A corrosion and inhibition mechanism is proposed whereby NO2- ion is added to oxidize. The NO2- ion can be reduced to nitrogen compounds and these compounds may be absorbed on the surface of graphite. Therefore, since nitrite ion needs to oxidize the surface of matrix and needs to passivate the galvanic corroded area and since it is absorbed on the surface of graphite, a greater amount of corrosion inhibitor needs to be added to ductile cast iron compared to carbon steel. The passive film of carbon steel and ductile cast iron, formed by NaNO2 addition showed N-type semiconductive properties and its resistance, is increased; the passive current density is thus decreased and the corrosion rate is then lowered. In addition, the film is mainly composed of iron oxide due to the oxidation by NO2- ion; however, regardless of the alloys, nitrogen compounds (not nitrite were detected at the outermost surface but were not incorporated in the inner oxide.

  10. Solidification and casting

    CERN Document Server

    Cantor, Brian

    2002-01-01

    INDUSTRIAL PERSPECTIVEDirect chillcasting of aluminium alloysContinuous casting of aluminium alloysContinuous casting of steelsCastings in the automotive industryCast aluminium-silicon piston alloysMODELLING AND SIMULATIONModelling direct chill castingMold filling simulation of die castingThe ten casting rulesGrain selection in single crystal superalloy castingsDefects in aluminium shape castingPattern formation during solidificationPeritectic solidificationSTRUCTURE AND DEFECTSHetergeneous nucleation in aluminium alloysCo

  11. Improvement of Transfer Table for Cleaning Castings%清理铸件输送辊道的改进

    Institute of Scientific and Technical Information of China (English)

    李庆东; 毛国胜

    2012-01-01

    清理工序的铸件输送辊道,由于铸件型号及控制程序等原因造成辊道故障,严重影响生产效率。在分析辊道输送系统和故障原因的基础上,通过改进压紧气囊、光电开关、完善PLC程序等措施,彻底解决了翻转机铸件掉落的问题,有效改善了辊道堵塞,铸件碰伤、磨伤等状况。%The transfer table faults caused by casting type and control program in cleaning casting process affect the production efficiency seriously. The roller transport system and fault reasons were analyzed, and the compression air bag, optoelectronic switch and PLC program was improved. The problems, such as castings dropped out, roller jammed and castings damaged were solved effectively.

  12. Mechanical characterization of microconstituents in a cast duplex stainless steel by micropillar compression

    International Nuclear Information System (INIS)

    The mechanical properties of individual constituent in a cast austenitic–ferritic stainless steel were studied using uniaxial micropillar compression tests. The results of compression tests of the micropillars with the diameter ranging from 1 to 5 and 1 to 10 µm for ferrite and austenite, respectively, reveal that the strength of both austenite and ferrite increases with a decrease in sample size. The compression results also confirm that the strength of ferrite phase is higher than the austenite. The average yield stress value of ferrite is approximately 200 MPa higher than that of the austenite phase with the same sample size. The critical resolved shear stress (CRSS) was also calculated based on pillar compression and electron backscatter diffraction (EBSD) results

  13. Precipitation kinetics in austenitic 18Cr-30Ni-Nb cast steel

    Directory of Open Access Journals (Sweden)

    M. Garbiak

    2008-08-01

    Full Text Available The study presents the results of investigations on the precipitation kinetics in austenitic 18%Cr-30%Ni cast steel stabilised with an addition of 1.84 wt% niobium. Phase analysis of isolates extracted from the alloy subjected to annealing within the temperature range of 600–1000oC during 10–1000 h was made. The phase constitution of the isolates mainly comprised niobium carbides of the NbC type and complex chromium carbides of the Cr23C6 type. In specimens annealed within the temperature range of 700–900oC, a high-silicon G phase was additionally identified. The highest kinetics of the precipitation process was recorded after annealing at the temperatures of 800 and 900oC.

  14. Mechanical properties of phase constituents in selected grades of cast steel

    Directory of Open Access Journals (Sweden)

    M. Garbiak

    2011-07-01

    Full Text Available The nanoindentation measurements performed on three cast steels of 0.3C-30Ni-18Cr type with various content of niobium and titanium were carried out.Mechanical propertiesofthe main phaseconstituents of the alloys, such as austenite, MC and M23C6 type carbides, were determined and analysed. The values of hardness (H and Young modulus (E for the austenite matrix were similar within the tested alloys. Essential differences (H=12 ÷ 24 GPa; E = 250 ÷ 400 GPa were found between the carbide phases present in tested alloys. The nanoindentation measurement on small particles is affected by different effects. One of these effects was excluded using numerical simulation of impressing the phase constituent into the matrix during indentation. The values of H and E obtained from simulation were: 30/450 GPa for NbC; 50/580 GPa for TiC; and 19/320 GPa for Cr23C6 respectively

  15. Optimization of the process of steel strip perforation and nickel platting for the purpose of elimination of trichloroethylene from the cleaning process of perforated steel strip

    Directory of Open Access Journals (Sweden)

    Petrović Aleksandra B.

    2009-01-01

    Full Text Available In the production of pocket type electrodes for Ni-Cd batteries perforation of proper steel strips and then nickel platting of perforated steel strips were made. In the nickel platting process, the organic solvent, trichloroethylene, has previously been used for cleaning. Due to the carcinogenic nature of trichloroethylene and the many operations previously required during cleaning, it was considered to do cleaning of perforated steel strips without use of the mentioned organic solvent. In the purpose of elimination of trichloroethylene from the cleaning process of perforated steel strips, the tests of perforation of steel strips with use of oils of different viscosity were made. It was shown that there was no dysfunction during the work of the perforation plants, meaning there was no additional heating of the strips, deterring of the steel filings, nor excessive wearing of the perforation apparatus. The perforation percent was the same irrelevant of the viscosity of the used oil. Before being perforated using the oils with different viscosity, the nickel platting steel strips were cleaned in different degreasers (based on NaOH as well as on KOH. It was shown that efficient cleaning without the use of trichloroethylene is possible with the use of oil with smaller viscosity in the perforated steel strips process and the degreaser based on KOH in the cleaning process, before nickel platting. It also appeared that the alkali degreaser based on KOH was more efficient, bath corrections were made less often and the working period of the baths was longer, which all in summary means less quantity of chemicals needed for degreasing of perforated steel strips.

  16. Modeling of primary dendrite arm spacing variations in thin-slab casting of low carbon and low alloy steels

    Science.gov (United States)

    Mehrara, H.; Santillana, B.; Eskin, D. G.; Boom, R.; Katgerman, L.; Abbel, G.

    2012-01-01

    Solidification structure of a High Strength Low Alloy (HSLA) steel, in terms of dendrite arm spacing distribution across the shell thickness, is studied in a breakout shell from a thin-slab caster at Tata Steel in IJmuiden. Columnar dendrites were found to be the predominant morphology throughout the shell with size variations across the shell thickness. Primary Dendrite Arm Spacing (PDAS) increases by increasing the distance from meniscus or slab surface. Subsequently, a model is proposed to describe the variation of the PDAS with the shell thickness (the distance from slab surface) under solidifiction conditions experienced in the primary cooling zone of thin-slab casting. The proposed relationship related the PDAS to the shell thickness and, hence, can be used as a tool for predicting solidifcation structure and optimizing the thin-slab casting of low alloy steels.

  17. Thermal ageing of cast duplex stainless steel primary components. Overview of the research program conducted by EDF

    Energy Technology Data Exchange (ETDEWEB)

    Massoud, J.P.; Jayet-Gendrot, S.; Le Delliou, P.; Semete, P. [Electricite de France (EDF), 77 - Moret sur Loing (France). Direction des Etudes et Recherches; Churier-Bossenec, H.; Ignaccolo, S. [Electricite de France (EDF), 69 - Villeurbanne (France). Direction de l`Equipment, SEPTEN; Bezdikian, G. [Electricite De France (EDF), 92 - Paris la Defense (France)

    1997-04-01

    The integrity assessment of cast duplex stainless steel components from the primary circuit of the PWR units relies on several research and development studies: the ageing surveillance programme on test ingots (cast at the same time as components) and on special products cast for studies has enabled us to develop prediction formulas of end-of-life toughness properties applicable to every component; tests on large-sized elbows containing analytical notches have shown their satisfactory behaviour even in severe situations (low toughness an high loadings); the development of a numerical tool (called ASCOUF) aimed to easily perform 3-D calculations; tests on mock-ups containing casting defects have shown that the resistance of shrinkage cavities to fatigue and to ductile tearing is much higher than the resistance of the envelope notches that are considered in mechanical analyses. The research program aiming at investigating the above issues is overviewed. (author) 8 refs.

  18. Numerical simulation of flow and heat transfer of continous cast steel slab under traveling magnetic field

    Directory of Open Access Journals (Sweden)

    Gong Haijun

    2013-03-01

    Full Text Available A unified numerical model for simulating solidification transport phenomena (STP of steel slab in electromagnetic continuous casting (EMCC process was developed. In order to solve the multi-physics fields coupled problem conveniently, the complicated bidirectional coupled process between EM and STP was simplified as a unidirectional one, and a FEM/FVM-combined numerical simulation technique was adopted. The traveling magnetic fields (TMFs applied to the EMCC process were calculated using the ANSYS11.0 software, and then the EM-data output by ANSYS were converted to FVM-format using a data-format conversion program developed previously. Thereafter, the governing equations were solved using a pressure-based Direct-SIMPLE algorithm. The simulation results of the STP in CC-process show that, due to the influences of Lorentz force and Joule heat, the two strong circulating flows and the temperature field can be obviously damped and changed once TMF with one pair of poles (1-POPs or 2-POPs is applied, which would accordingly improve the quality of casting. It was found in the present research that the integrated actions of 2-POPs TMF are superior to 1-POPs. All the computations indicate that the present numerical model of EM-STP as well as the FEM/FVM-combined technique is successful.

  19. Microstructure and Mechanical Properties After Shock Wave Loading of Cast CrMnNi TRIP Steel

    Science.gov (United States)

    Eckner, Ralf; Krüger, L.; Ullrich, C.; Rafaja, D.; Schlothauer, T.; Heide, G.

    2016-10-01

    The mechanical response of shock wave-prestrained high-alloy Cr16-Mn7-Ni6 TRIP steel was investigated under compressive and tensile loading at room temperature. Previous shock wave loading was carried out using a flyer-plate assembly with different amounts of explosives in order to achieve shock pressures of 0.3, 0.6, 0.9, and 1.2 Mbar. A significant increase in hardness and strength was observed as compared with the initial as-cast condition. In contrast, a slight decrease in strain hardening rates was measured together with a decrease in fracture elongation in the tensile test. Microstructural analyses of the shock-loaded samples were performed by light optical and scanning electron microscopy. The microstructure revealed a high density of deformation bands consisting of separated stacking faults, ɛ-martensite, or twins. Significant amounts of deformation-induced α'-martensite were only present at the highest shock pressure of 1.2 Mbar. The thickness of the deformation bands and the number of martensite nuclei at their intersections increased with increasing shock pressure. In all shock-loaded specimens, pronounced phase transformation occurred during subsequent mechanical testing. Consequently, the amount of the deformation-induced α'-martensite in the shock-loaded specimens was higher than in the unshocked as-cast samples.

  20. Effect of microstructure on mechanical properties of a thin-walled cast duplex steel

    Energy Technology Data Exchange (ETDEWEB)

    Petzold, L.; Kreschel, T.; Peisker, D. [TU Bergakademie Freiberg, Institut fuer Eisen- und Stahltechnologie, Freiberg (Germany); Minnich, D. [Evosteel GmbH, Leipzig (Germany)

    2010-06-15

    The paper investigates the microstructure and the resulting mechanical properties of a duplex steel cast in sand dead-moulds. The chemical composition and the cooling rate are the main parameters affecting the properties. The chemical composition influences the thermodynamics of the phase transformation, the cooling rate determines the kinetics of formation of the microstructure. The latter varies with changes in wall thickness (investigated from 2 to 7 mm) and the position of the material within the casting. Through heat treatment, the composition of the microstructural components can be changed selectively afterwards, thereby the properties are improved. The correlation between microstructure and mechanical properties is explained quantitatively. Additionally to the austenite-ferrite ratio, the dispersion of microstructure has a large influence on the mechanical properties. Ranges of chemical composition and heat treatment parameters are identified where third phases, such as carbides and {sigma}-phase tend to occur. These influence the properties very sensitively even in small amounts. Finally, structural parameters are recognized that will lead to optimal combinations of properties. With an appropriate heat treatment technique, in particular the ductility properties are further increased. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  1. Castability control of high [ Al] steel 38CrMoAl during continuous casting%38CrMoAl高铝钢钢水可浇性控制

    Institute of Scientific and Technical Information of China (English)

    何生平; 张国兴; 曾建华; 王谦

    2011-01-01

    High [ Al] content in 38CrMoAl ([ Al] =0. 7% -1.1% ) is liable to cause nozzle blockage in continuous casting.Shape control of Al2 O3 inclusions is needed to ensure the castability of molten steel. The results of thermodynamic calculations and experiments demonstrate that high content [ Al] in the steel has strong reducibility to SiO2 in slag even with a small quantity, and Al2O3 with a higher melting point can be changed to spherical calcium aluminate inclusions with a lower melting point through slag infiltration during converter tapping instead of the conventional calcium wire feeding process. Meanwhile, the slag-steel reaction, which may cause an increase in the amount of inclusions, can be avoided by using tundish covering fluxes based on CaO-Al2O3 with low SiO2 content.The results of industrial tests show that the steel' s cleanness is higher and the castability of molten steel is better. The nozzle has no blockage after five heats of continuous casting steel.%38CrMoAl高铝钢由于Al含量较高([Al]=0.7%~1.1%,质量分数),在连铸过程中容易导致水口的堵塞,因此需要对钢中Al2O3夹杂物进行形态控制,保证钢水的可浇性.热力学计算和实验研究结果显示:钢中高含量的A1对渣中即使少量的SiO2都具有较强的还原性;不采用传统的精炼喂钙线工艺,而进行转炉出钢过程渣洗操作,能将高熔点的Al2O3转变为低熔点的球状钙铝酸盐夹杂.同时,采用CaO-Al2O3基中间包覆盖剂,以避免钢渣反应导致钢中夹杂物含量增加.工业性试验结果表明,钢水洁净度较高,可浇性好,连续浇注5炉后,水口内壁基本无结瘤现象.

  2. Simulation Using Realistic Spray Cooling for the Continuous Casting of Multi-component Steel

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    A three-dimensional heat transfer model for continuous steel slab casting has been developed with realistic spray cooling patterns and a coupled microsegregation solidification model that calculates the solidification path for multicomponent steels. Temperature and composition dependent properties are implemented in a database for 15 chemical species. Considerable effort is made to accurately model the spray cooling heat transfer. Each spray nozzle position and distribution is considered, including variations of the spray patterns with flow rate, and spray overlap. Nozzle type, layout, nozzle-to-slab distance, and spray span and flux are variable. Natural convection, thermal radiation and contact cooling of individual rolls are computed. The present model provides more comprehensive information and realistic slab surface temperatures than results from a model using the "averaged" treatment of boundary conditions.Cooling operating conditions and parameters of individual spray nozzles can be analyzed to optimize nozzle spray distribution, improve product quality, and troubleshoot issues such as nozzle clogging that may arise during production.One spray cooling correlation is used for the entire machine, achieving as good or better agreement with surface temperature measurements than was found previously for the model using an "averaged" treatment of boundary conditions and using three machine-segment-dependent correlations.

  3. Mathematical Modelling of Solidification in a Curved Strand During Continuous Casting of Steel

    Science.gov (United States)

    Maurya, Ambrish; Jha, Pradeep Kumar

    2016-06-01

    A two dimensional fluid flow, heat transfer and solidification model has been developed for a curved shape continuous steel slab caster. The strand has been divided in various sections depending upon cooling conditions in the mold and Secondary Cooling Zone (SCZ). The model was validated against the experimental results reported in the literature for solid shell thickness in the mold. CFD software ANSYS Fluent has been used for solving the differential equations of heat transfer and fluid flow. Surface temperature distribution has been predicted while; the thickness of solid shell formed in the mold and SCZ has been calculated by finding the liquid fraction of steel within the domain. Process parameters such as, casting speed and cooling rate has been varied to analyse their effects on metallurgical length and solid shell thickness at the mold exit. The analysis was based on keeping the shell thickness between 10 and 14 mm at mold exit and metallurgical length less than the cut-off length but having complete solidification after the straightening zone.

  4. Quality control system for the process of continuous casting of steel

    Directory of Open Access Journals (Sweden)

    A. Gzieło

    2006-04-01

    Full Text Available Purpose: Purpose of this research was to create new quality control system.Design/methodology/approach: For the purpose of new quality control system, the base of technological parameters of the process of continuous casting of steel (CCS has been programmed; it consists of 53 parameters. The optimal values for the technological parameters are necessary to proper functioning of databases and are essential element of quality control system. For each parameter, some target values have been empirically defined i.e. upper and lower bound, which assured proper functioning of a new process quality system for CCS.Findings: The author has modernized the loss function in such a way that it includes the whole range of technological parameters of CCS process.Practical implications: Having such an investigation material the scope and concept of a new quality system have been designed. The essentials component of the new quality system are the mathematical basis on which a modernized Taguchi’s loss function have been developed.Originality/value: On the basis of the performed investigations, a new quality system for concast slab of carbon steel which functions in industrial conditions has been developed.

  5. Finite volume modeling of the solidification of an axial steel cast impeller

    Directory of Open Access Journals (Sweden)

    M. Copur

    2014-04-01

    Full Text Available In the foundry industry, obtaining the solidification contours in cast geometries are extremely important to know the last location(s to solidify in order to define the correct feeding path and the number of risers. This paper presents three-dimensional simulation of transient conduction heat transfer within an axial impeller, made of AISI 1016 steel, poured and solidified in chemically bonded mold and core medium, by using FVM technique and ANSYS CFX. Specific heat, density and thermal conductivity of AISI 1016 steel, mold and Core materials are considered as functions of temperatures. In this transient thermal analysis, the convection heat transfer phenomenon is also considered at the outer surfaces of the mold. In order to shorten the run-time, the nonlinear transient analysis has been made for 600/3600 segment of the impeller, core and mold. The solidification contours of the impeller as well as isothermal lines in core and mold have been obtained in 3-D. The cooling curves of diff erent points are also shown in the result section.

  6. Transient Simulation of Mold Heat Transfer and Solidification Phenomena of Continuous Casting of Steel

    Science.gov (United States)

    El-Bealy, Mostafa Omar

    2016-10-01

    A comprehensive model of heat transfer and solidification phenomena has been developed including microstructure evolution and fluctuation macrosegregation in continuously cast steel slabs with an objective of evaluation of various mold cooling conditions. The study contains plant trials, metallographic examinations, and formulation of mathematical modeling. The plant trials involved sample collection from three slab casters in use at two different steel plants. The metallographic study combined measurements of dendrite arm spacings and macrosegregation analysis of collected samples. A one-dimensional mathematical model has been developed to characterize the thermal, solidification phases, microstructure evolution, interdendritic strain, and therefore, the macrosegregation distributions. Two cooling approaches were proposed in this study to evaluate the Newtonian heat transfer coefficient in various mold regions. The first approach is a direct estimation approach (DEA), whereas the second one is a coupled approach of the interfacial resistor model and direct estimation approach (CIR/DEA). The model predictions and standard analytical models as well as the previous measurements were compared to verify and to calibrate the model where good agreements were obtained. The comparison between the model predictions and the measurements of dendrite arm spacings and fluctuated carbon concentration profiles were performed to determine the model accuracy level with different cooling approaches. Good agreements were obtained by different accuracy levels with different cooling approaches. The model predictions of thermal parameters and isotherms were analyzed and discussed.

  7. Transient Simulation of Mold Heat Transfer and Solidification Phenomena of Continuous Casting of Steel

    Science.gov (United States)

    El-Bealy, Mostafa Omar

    2016-07-01

    A comprehensive model of heat transfer and solidification phenomena has been developed including microstructure evolution and fluctuation macrosegregation in continuously cast steel slabs with an objective of evaluation of various mold cooling conditions. The study contains plant trials, metallographic examinations, and formulation of mathematical modeling. The plant trials involved sample collection from three slab casters in use at two different steel plants. The metallographic study combined measurements of dendrite arm spacings and macrosegregation analysis of collected samples. A one-dimensional mathematical model has been developed to characterize the thermal, solidification phases, microstructure evolution, interdendritic strain, and therefore, the macrosegregation distributions. Two cooling approaches were proposed in this study to evaluate the Newtonian heat transfer coefficient in various mold regions. The first approach is a direct estimation approach (DEA), whereas the second one is a coupled approach of the interfacial resistor model and direct estimation approach (CIR/DEA). The model predictions and standard analytical models as well as the previous measurements were compared to verify and to calibrate the model where good agreements were obtained. The comparison between the model predictions and the measurements of dendrite arm spacings and fluctuated carbon concentration profiles were performed to determine the model accuracy level with different cooling approaches. Good agreements were obtained by different accuracy levels with different cooling approaches. The model predictions of thermal parameters and isotherms were analyzed and discussed.

  8. Laser-induced breakdown spectroscopy of scaled steel samples taken from continuous casting blooms

    Science.gov (United States)

    Meinhardt, Christoph; Sturm, Volker; Fleige, Rüdiger; Fricke-Begemann, Cord; Noll, Reinhard

    2016-09-01

    To analyse continuous casting steel blooms a removal of non-representative surface layers is required prior to the analysis. In this work, an optimized process is developed to ablate such layers and to analyse the bulk material underneath with laser-induced breakdown spectroscopy (LIBS). A high ablation rate is crucial since the time slot for an inline analysis is limited, e.g. to measurements and cross-section polish methods. These studies show that the surface layers may consist both of oxides and metallic layers and typically have thicknesses from 200 μm to 600 μm each. The ablation behaviour of the oxide differs significantly from that of the metallic layers. An operation scheme for inline material identification is worked out to perform ablation and analysis with a single laser source. During the ablation phase and the subsequent measurement phase the laser source is operated with individually tailored parameters. A total penetration depth exceeding 1 mm in steel can be achieved within 20 s of ablation. Thereby the influence of non-representative surface layers on the following LIBS measurement can be suppressed to a large extent. For chromium, relative root mean square errors of predictions of less than 13% were achieved on high alloy samples with up to 16 m.-% Cr and on low alloy samples with Cr contents below 2 m.-%.

  9. Influence of stress relief annealing on the microstructure and properties of GX12CrMoVNbN9-1(GP91 cast steel

    Directory of Open Access Journals (Sweden)

    G. Golański

    2011-04-01

    Full Text Available The paper presents an effect of stress relief annealing, applied to casts after the repair by welding, on the microstructure and mechanical properties of quenched and tempered martensitic GX12CrMoVNbN9 – 1 cast steel (called GP91. The test pieces being the subject of research were taken out from a test coupon. Heat treatment of GP91 cast steel was carried out at the parameters of temperature and time appropriate for the treatment of multi-ton steel casts, while stress relief annealing was performed at the temperatures of 730 and 750oC.After quenching and tempering GP91 cast steel was characterized by the microstructure of high-tempered martensite with numerousprecipitations of carbides of diverse size. Mechanical properties of the investigated cast steel after heat treatment fulfilled the standard requirements. Stress relief annealing contributes to the processes of recovery and recrystallization of the matrix as well as the privileged precipitation of M23C6 carbides on grain boundaries. Changes in the microstructure of the examined cast steel cause deterioration in mechanical properties – the higher the temperature of stress relief annealing, the greater the deterioration.

  10. Interfacial morphology and corrosion resistance of Fe-B cast steel containing chromium and nickel in liquid zinc

    International Nuclear Information System (INIS)

    Highlights: → Fe-B steels containing Cr and Ni exhibit the best corrosion resistance in liquid zinc. → Surface layers show gamma-Fe3Zn10, delta-FeZn10, zeta-FeZn13 and eta-Zn. → Cr and Ni can enrich at the interface during the corrosion process. → Corrosion processes include leaching, formation of compounds and spalling of borides. - Abstract: The interfacial morphology and corrosion resistance of low carbon Fe-B cast steels in zinc bath at 520 deg. C were investigated. The results show Fe-B cast steel containing high Cr and Ni exhibits the best corrosion resistance to liquid zinc. The corrosion layers are composed of Γ-Fe3Zn10, δ-FeZn10, ξ-FeZn13 and η-Zn. The corrosion behaviour of Fe-B cast steels includes the following processes: the preferential leach and dissolution of Cr and Ni, the formation of Fe-Zn compounds controlled by zinc atom diffusion, and the spalling of borides without the supporting role of α-(Fe, Cr) matrix corroded by liquid zinc.

  11. Effect of cooling rate and forced convection on as-cast structure of 2205 duplex stainless steel

    OpenAIRE

    Cheng Zhang; Hong-gang Zhong; Cong-sen Wu

    2015-01-01

    To forecast the as-cast structure and ferrite-austenite phase ratio of 2205 duplex stainless steel (DSS), the effects of cooling rate and forced convection were observed in a high-vacuum resistance furnace in which the forced convection was created by the rotation of the crucible. The as-cast structure of all 2205 DSS samples is full equiaxed grains, and the microstructure consists of a great amount of desirable intra-granular austenite inside the continuous ferrite grain matrix, besides Widm...

  12. Alloy Design and Development of Cast Cr-W-V Ferritic Steels for Improved High-Temperature Strength for Power Generation Applications

    Energy Technology Data Exchange (ETDEWEB)

    Klueh, R L; Maziasz, P J; Vitek, J M; Evans, N D; Hashimoto, N

    2006-09-23

    Economic and environmental concerns demand that the power-generation industry seek increased efficiency for gas turbines. Higher efficiency requires higher operating temperatures, with the objective temperature for the hottest sections of new systems {approx} 593 C, and increasing to {approx} 650 C. Because of their good thermal properties, Cr-Mo-V cast ferritic steels are currently used for components such as rotors, casings, pipes, etc., but new steels are required for the new operating conditions. The Oak Ridge National Laboratory (ORNL) has developed new wrought Cr-W-V steels with 3-9% Cr, 2-3% W, 0.25% V (compositions are in wt.%), and minor amounts of additional elements. These steels have the strength and toughness required for turbine applications. Since cast alloys are expected to behave differently from wrought material, work was pursued to develop new cast steels based on the ORNL wrought compositions. Nine casting test blocks with 3, 9, and 11% Cr were obtained. Eight were Cr-W-V-Ta-type steels based on the ORNL wrought steels; the ninth was COST CB2, a 9Cr-Mo-Co-V-Nb cast steel, which was the most promising cast steel developed in a European alloy-development program. The COST CB2 was used as a control to which the new compositions were compared, and this also provided a comparison between Cr-W-V-Ta and Cr-Mo-V-Nb compositions. Heat treatment studies were carried out on the nine castings to determine normalizing-and-tempering treatments. Microstructures were characterized by both optical and transmission electron microscopy (TEM). Tensile, impact, and creep tests were conducted. Test results on the first nine cast steel compositions indicated that properties of the 9Cr-Mo-Co-V-Nb composition of COST CB2 were better than those of the 3Cr-, 9Cr-, and 11Cr-W-V-Ta steels. Analysis of the results of this first iteration using computational thermodynamics raised the question of the effectiveness in cast steels of the Cr-W-V-Ta combination versus the Cr

  13. Numerical Simulation of Stress and Deformation for a Duplex Stainless Steel Impeller during Casting and Heat Treatment Processes

    Institute of Scientific and Technical Information of China (English)

    Lugui CHEN; Yong LING; Xiuhong KANG; Lijun XIA; Dianzhong LI

    2008-01-01

    A large-scale, thin wall duplex stainless steel impeller with complex geometry was deformed severely and unpredictably during casting and heat treatment processes resulted in dimensional failure for the final part. In this paper, the distortion of the impeller during casting and heat treatment was calculated. A commercial software, Experto-ViewCast, was used to simulate the transient heat transfer, solidification and mechanical behaviors during the casting and the heat treatment process. The coupled set of governing differential equations for mass, energy and mechanical balance were solved by finite control volume and finite element method. A thermoelastic-visco-plastic rheological model was used to compute the constrained shrinkage of the casting. At each time increment, a coupling of the heat transfer and mechanics was performed. Comparison of the experimental measurements with the model predictions showed good agreement. From the calculated displacements of key points of the blade, the proper inverse displacements were determined to provide an optimum casting pattern and to achieve a uniform and reasonable machining allowance for both faces of the blade.

  14. Effect of residual Al content on microstructure and mechanical properties of Grade B+Steel for castings for locomotives

    Directory of Open Access Journals (Sweden)

    Wang Kaifeng

    2013-11-01

    Full Text Available The bogie made of Grade B+ steel is one of the most important parts of heavy haul trains. Some accidents were found to be the result of fracture failure of the bogies. It is very important to find the reason why the fracture failure occurred. Because Al was added for the final deoxidation during the smelting process of the Grade B+Steel, residual Al existed to some extent in the castings. High residual Al content in the bogie casting was presumed to be the reason for the fracture. In this work, the influence of residual Al content in the range of 0.015wt.% to 0.3wt.% on the microstructure and mechanical properties of the Grade B+ Steel was studied. The experimental results showed that when the residual Al content is between 0.02wt.% and 0.20wt.%, the mechanical properties of the steel meet the requirements of technical specification for heavy haul train parts, and the fracture is typical plastic fractures. If the residual Al content is less than 0.02wt.%, the microstructures are coarse, and the mechanical properties can not meet the demand of bogie steel castings. When the residual Al content is more than 0.2wt.%, the elongation, reduction of area, and low-temperature impact energy markedly deteriorate. The fracture mode then changes from plastic fracture to cleavage brittle fracture. Therefore, the amount of Al addition for the final deoxidation during the smelting process must be strictly controlled. The optimum addition amount needs to be controlled within the range of 0.02wt.% to 0.20wt.% for the Grade B+Steel.

  15. Impact Strength of Austenitic and Ferritic-Austenitic Cr-Ni Stainless Cast Steel in -40 and +20°C Temperature

    OpenAIRE

    Kalandyk B.; Zapała R.; Boroń Ł.; Solecka M.

    2014-01-01

    Studies described in this paper relate to common grades of cast corrosion resistant Cr-Ni steel with different matrix. The test materials were subjected to heat treatment, which consisted in the solution annealing at 1060°C followed by cooling in water. The conducted investigations, besides the microstructural characteristics of selected cast steel grades, included the evaluation of hardness, toughness (at a temperature of -40 and +20oC) and type of fracture obtained after breaking the specim...

  16. Effect of heat treatment on microstructure, mechanical properties and erosion resistance of cast 23-8-N nitronic steel

    International Nuclear Information System (INIS)

    Effects of heat treatment on microstructure, mechanical properties and erosion behavior of cast 23-8-N nitronic steel were studied. A series of heat treatments were carried out in the temperature range of 1180–1240 °C to observe the effect on microstructure. Optimum heat treatment cycle was obtained at 1220 °C for holding time of 150 min, which leads to dissolution of carbides, formation of equiaxed grains and twins. Heat treatment has shown improvement in tensile strength, toughness, impact strength and work hardening capacity, however at the cost of marginal reduction in hardness and yield strength. This resulted in improvement of erosion resistance of cast 23-8-N nitronic steel. The microstructures, fractured surfaces and phases were studied by optical microscopy, field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD) analysis respectively

  17. Effect of Ni Contents on the Microstructure and Mechanical Properties of Martensitic Stainless Steel Guide Roll by Centrifugal Casting

    Institute of Scientific and Technical Information of China (English)

    Villando Thursdiyanto; Eun-Jae Bae; Eung-Ryul Baek

    2008-01-01

    A novel process based on centrifugal casting was developed to produce martensitic stainless steel for guideroll materials. Centrifugal casting provides a lower production cost and less of the thermal cracking defects which normally occur in the overlaid welding process. In this study, the effects of Ni on the microstructure and mechanical properties of martensitic stainless steel were investigated. The results show that the addition of Ni resulted in a decrease in the volume fraction of delta ferrite and an increase in the volume fraction of the retained austenite, respectively. Moreover, a tensile strength of 1600 MPa with an elongation of 4% were obtained after tempering at 500℃ for 2 h. These values were higher than those obtained by using the conventional overlaid process.

  18. Predictive Capabilities of Multiphysics and Multiscale Models in Modeling Solidification of Steel Ingots and DC Casting of Aluminum

    Science.gov (United States)

    Combeau, Hervé; Založnik, Miha; Bedel, Marie

    2016-06-01

    Prediction of solidification defects, such as macrosegregation and inhomogeneous microstructures, constitutes a key issue for industry. The development of models of casting processes needs to account for several imbricated length scales and different physical phenomena. For example, the kinetics of the growth of microstructures needs to be coupled with the multiphase flow at the process scale. We introduce such a state-of-the-art model and outline its principles. We present the most recent applications of the model to casting of a heavy steel ingot and to direct chill casting of a large Al alloy sheet ingot. Their ability to help in the understanding of complex phenomena, such as the competition between nucleation and growth of grains in the presence of convection of the liquid and of grain motion is shown, and its predictive capabilities are discussed. Key issues for future developments and research are addressed.

  19. Influence of heat treatment on microstructure and properties of GX12CrMoVNbN9-1 cast steel

    Directory of Open Access Journals (Sweden)

    G. Golański

    2010-07-01

    Full Text Available The paper presents results of research on the influence of multistage heat treatment on microstructure and properties of high-chromiummartensitic GX12CrMoVNbN9 – 1 (GP91 steel. The material under investigation were samples taken out from a test coupon. Heattreatment of GP91 cast steel was performed at the parameters of temperature and time typical of treatment for multi-ton steel casts. The research has proved that in the as-received condition (as-cast state GP91 cast steel was characterized by a coarse grain, martensitic microstructure which provided the required standard mechanical properties. The heat treatment of GP91 cast steel contributed to obtainment of a fine grain microstructure of high tempered martensite with numerous precipitations of carbides of diverse size. The GP91 cast steel structure received through heat treatment made it possible to obtain high plastic properties, particularly impact strength, maintaining strength properties on the level of the required minimum.

  20. Long-term embrittlement of cast duplex stainless steels in LWR systems. Semiannual report, October 1991--March 1992: Volume 7, No.1

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, O.K. [Argonne National Lab., IL (United States)

    1993-05-01

    This progress report summarizes work performed by Argonne National Laboratory on long-term thermal embrittlement of cast duplex stainless steels in LWR systems during the six months from October 1991 to March 1992. Charpy-impact, tensile, and fracture toughness J-R curve data are presented for several heats of cast stainless steel that were aged 10,000-58,000 h at 290, 320, and 350{degree}C. The results indicate that thermal aging decreases the fracture toughness of cast stainless steels. In general, CF-3 steels are the least sensitive to thermal aging and CF-8M steels are the most sensitive. The values of fracture toughness J{sub IC} and tearing modulus for CF-8M steels can be as low as {approx}90 kJ/m{sup 2} and {approx}60, respectively. The fracture toughness data are consistent with the Charpy-impact results, i.e. unaged and aged steels that show low impact energy also exhibit lower fracture toughness. All steels reach a minimum saturation fracture toughness after thermal aging; the time to reach saturation depends on the aging temperature. The results also indicate that low-strength cast stainless steels are generally insensitive to thermal aging.

  1. Experimental und numerical investigations on cooling efficiency of Air-Mist nozzles on steel during continuous casting

    Science.gov (United States)

    Arth, G.; Taferner, M.; Bernhard, C.; Michelic, S.

    2016-07-01

    Cooling strategies in continuous casting of steel can vary from rapid cooling to slow cooling, mainly controlled by adjusting the amount of water sprayed onto the surface of the product. Inadequate adjustment however can lead to local surface undercooling or reheating, leading to surface and inner defects. This paper focuses on cooling efficiency of Air-Mist nozzles on casted steel and the experimental and numerical prediction of surface temperature distributions over the product width. The first part explains the determination of heat transfer coefficients (HTC) on laboratory scale, using a so called nozzle measuring stand (NMS). Based on measured water distributions and determined HTC's for air-mist nozzles using the NMS, surface temperatures are calculated by a transient 2D-model on a simple steel plate, explained in the second part of this paper. Simulations are carried out varying water impact density and spray water distribution, consequently influencing the local HTC distribution over the plate width. Furthermore, these results will be interpreted with regard to their consequence for surface and internal quality of the cast product. The results reveal the difficulty of correct adjustment of the amount of sprayed water, concurrent influencing water distribution and thus changing HTC distribution and surface temperature.

  2. Estimation of Charpy notch toughness for thermal aging specimens of cast duplex stainless steel using thermalelectric power measurement

    International Nuclear Information System (INIS)

    The material properties of cast duplex stainless steel, which is used for main coolant pipes of PWR (pressurized water reactor) type nuclear power plants, change due to thermal aging. Therefore it is advisable to evaluate these changes of material properties non-destructively for maintenance of the plant component. In order to establish a non-destructive evaluation procedure for the degree of thermal aging of cast duplex stainless steel, thermoelectric power (TEP) measurements were carried out with a newly made TEP meter for thermal aging specimens, with different ferrite contents, aging temperatures and aging periods. Then the relationship between TEP and notch toughness obtained by Charpy impact test was investigated. As the results: (1) TEP increases due to thermal aging. The higher ferrite content, the higher TEP. The higher aging temperature, the more rapidly TEP increases. (2) Because of the decrease of Charpy notch toughness and the increase of TEP due to the fluctuation of Cr concentration caused by the phase separation of the ferrite phase, TEP increases by thermal aging as the Charpy notch toughness decreases. (3) Regardless of the aging temperature, the specimens with the same ferrite content have the same relationship between Charpy notch toughness and TEP. (4) It is possible to estimate Charpy notch toughness with an error of 100 J/cm2 by TEP in the beginning of aging. Therefore, it can be concluded that we can estimate Charpy notch toughness for cast duplex stainless steel by TEP depending on the ferrite content regardless of the aging temperature. (author)

  3. 铸钢件与无缝钢管焊接技术%Cast Steel and Seamless Steel Pipe Welding Technology

    Institute of Scientific and Technical Information of China (English)

    臧盐龙

    2012-01-01

    结合京沪高速铁路镇江南站站房工程铸钢件同无缝钢管焊接施工中一些技术工作及相关经验,通过设计院的相关设计文件及现场焊接工艺的指导,经过权威专家的评审,最终根据焊接的成果总结出了在管桁架结构的现场安装中铸钢件同无缝钢管的焊接工艺及注意要点。%In combination with the steel castings with seamless steel pipe welding construction technology and related work experience of Beijing-Shanghai High Speed Railway Zhenjiang south railway station building engineering, through the design of the related design documents and field welding process guidance, through the assessment of experts, based on the final welding results, the paper summarized steel castings with seamless steel pipe welding process and points for attention in pipe truss structure installation.

  4. Numerical Simulation of Dendritic Growth of Continuously Cast High Carbon Steel

    Science.gov (United States)

    Wang, Weiling; Luo, Sen; Zhu, Miaoyong

    2015-01-01

    Considering the influence of the latent heat released during the solidification of high carbon liquid steel, a cellular automaton (CA) model coupled with the heat transfer was developed to investigate the growth of equiaxed dendrites which is controlled by the solute diffusion during the continuous casting process. Additionally, the growth of columnar dendrites and primary dendrite arm spacings were predicted and measured. The results show that the CA model is able to describe the growth behavior of equiaxed dendrites, especially at 5 K to 7 K melt undercoolings, and the approach adjusting the cooling medium temperature is reliable to keep the undercooling condition stable for equiaxed dendrites although its hysteresis is reinforced as the pre-set undercooling increases. With the increase of the melt undercooling, the growth of equiaxed dendrites becomes faster, and the thickness of dendritic arms increases slightly, however, the thickness of the diffusion layer in front of dendritic tips keeps constant. The growth of thin and tiny columnar dendrites will be confined due to the competition and absorbed by neighboring strong columnar dendrites, giving rise to the coarsening of columnar dendrites, which is observed both from the experimental observation and the numerical simulation. With the decrease of the cooling intensity, columnar dendrites get sparser, primary dendrite arm spacings increase, and secondary dendritic arms become undeveloped.

  5. Characteristics comparison of weld metal zones welded to cast and forged steels for piston crown material

    Science.gov (United States)

    Moon, Kyung-Man; Kim, Yun-Hae; Lee, Myeong-Hoon; Baek, Tae-Sil

    2015-03-01

    An optimum repair welding for the piston crown which is one of the engine parts exposed to the combustion chamber is considered to be very important to prolong the engine lifetime from an economical point of view. In this study, two types of filler metals such as 1.25Cr-0.5Mo, 0.5Mo were welded with SMAW method and the other two types of filler metals such as Inconel 625 and 718 were welded with GTAW method, respectively, and the used base metals were the cast and forged steels of the piston crown material. The weld metal zones welded with Inconel 625 and 718 filler metals exhibited higher corrosion resistance compared to 1.25Cr-0.5Mo and 0.5Mo filler metals. In particular, the weld metal zone welded with Inconel 718 and 0.5Mo, filler metals indicated the best and worst corrosion resistance, respectively. Consequently, it is suggested that the corrosion resistance of the weld metal zone surely depends on the chemical components of each filler metal and welding method irrespective of the types of piston crown material.

  6. Investigation of thermal aging damage mechanism of the Cast Duplex Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Wang Zhaoxi, E-mail: wangzx03@mails.tsinghua.edu.c [Applied Mechanics Laboratory, Tsinghua University, Beijing 100084 (China); Suzhou Nuclear Power Research Institute, Suzhou 215004 (China); Xue Fei; Guo Wenhai [Suzhou Nuclear Power Research Institute, Suzhou 215004 (China); Shi Huiji [Applied Mechanics Laboratory, Tsinghua University, Beijing 100084 (China); Zhang Guodong [Suzhou Nuclear Power Research Institute, Suzhou 215004 (China); School of Mechanical and Power Engineering, Nanjing University of Technology, Nanjing 210009 (China); Shu Guogang [Suzhou Nuclear Power Research Institute, Suzhou 215004 (China)

    2010-10-15

    Besides the macro-mechanical properties for thermal aging effect published in 'Thermal aging effect on Z3CN20.09M Cast Duplex Stainless Steel' (Nuclear Engineering and Design 239(2009) 2217-2223), the thermal aging damage mechanism is investigated in this paper through nano-indentation tests and micro-structures evolution examination. Numerical simulations were carried out with GTN continuum damage model to investigate the different crack propagation process for aging. The nano-indentation hardness values increase with aging time for both phases while the hardness values of the ferrite phase are much higher and increase much more. The nano-indentation energy indicating the toughness decreases for both phases with aging time. TEM results show that the Cr-enriched {alpha}' phase precipitates in the ferrite phase which is considered as the critical reason making the dislocation slip difficult and causing the increase of the strength and reduction of the toughness. The crack initiates from the ferrite phase instead of the austenite phase from the SEM observation and FEA simulation results, which reflects the change of the fracture mechanism for thermal aging.

  7. A study of fracture of cast duplex stainless steels embrittled by aging at 400 C

    International Nuclear Information System (INIS)

    This work deals in particular with the fracture at 20 C of a cast duplex stainless steel ZCND19-10M containing 20% of ferrite and aged at 400 C during 700 h in order to obtain a fracture criterion of a volume element, in the framework of the local approach to fracture. With tensile tests on axisymmetric coped test pieces it is possible to study the effect of the stresses triaxiality on ductility. The fracture mechanisms are studied on metallographic sections and of fracture surface analyses. Cleavage cracks are initiated in ferrite and end in austenite. They grow up by blunting in austenite, and then form a macro-crack by coalescence. These cleavage cracks are clustered together. A crystallographic study shows that they appear in austenite grains which deform with simple slide, the incompatibility stress between the two phases being higher in this case. At a superior scale, the mechanical analysis of the crack growth conditions, shows that it is controlled by the plastic deformation. Moreover, cracks appear progressively when the deformation increases. A Gurson porous material behaviour model has been used to simulate the ductile fracture of this material. With random selection of grains strongly damaged (crack clusters) in coped specimens and of finite element calculations of these same specimens, it has been shown that ductility is controlled by cluster fracture and that its great dispersion can be correctly reproduced. (O.M.)

  8. Technical Letter Report on the Cracking of Irradiated Cast Stainless Steels with Low Ferrite Content

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Y. [Argonne National Lab. (ANL), Argonne, IL (United States); Alexandreanu, B. [Argonne National Lab. (ANL), Argonne, IL (United States); Natesan, K. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2014-11-01

    Crack growth rate and fracture toughness J-R curve tests were performed on CF-3 and CF-8 cast austenite stainless steels (CASS) with 13-14% of ferrite. The tests were conducted at ~320°C in either high-purity water with low dissolved oxygen or in simulated PWR water. The cyclic crack growth rates of CF-8 were higher than that of CF-3, and the differences between the aged and unaged specimens were small. No elevated SCC susceptibility was observed among these samples, and the SCC CGRs of these materials were comparable to those of CASS alloys with >23% ferrite. The fracture toughness values of unirradiated CF-3 were similar between unaged and aged specimens, and neutron irradiation decreased the fracture toughness significantly. The fracture toughness of CF-8 was reduced after thermal aging, and declined further after irradiation. It appears that while lowering ferrite content may help reduce the tendency of thermal aging embrittlement, it is not very effective to mitigate irradiation-induced embrittlement. Under a combined condition of thermal aging and irradiation, neutron irradiation plays a dominant role in causing embrittlement in CASS alloys.

  9. Mechanical property and microstructural change by thermal aging of SCS14A cast duplex stainless steel

    International Nuclear Information System (INIS)

    The aging behavior, especially saturation, of JIS SCS14A cast duplex stainless steels was investigated on the basis of the mechanical properties and microstructural changes during accelerated aging at 350 oC and 400 oC. The aging behavior of the materials mainly proceeds via two stages. During the first stage, the generation and concentration of the iron-rich and chromium-enriched phase in ferrite occurs by phase decomposition. The first stage corresponds to aging times of up to 3000 h at 400 oC. During the first stage, the ferrite hardness achieved is approximately 600 VHN, and the Charpy impact energy is almost saturated. During the second stage, the precipitated chromium-enriched phase aggregates and coarsens, and the G phase precipitation also occurs. The second stage corresponds to the aging times range of 3000-30 000 h at 400 oC. During the second stage, the ferrite hardness achieved is about 800 VHN; however, further hardening exceeding 600 VHN does not influence the Charpy impact energy

  10. Temper embrittlement of cast duplex stainless steels after long-term aging

    International Nuclear Information System (INIS)

    Microstructural changes and fracture behavior in cast CF8M duplex stainless steel after aging at 300 to 450degC for 300 to 10000 h have been investigated. Both, optical microscopical and transmission electron microscopical analyses, hardness and ferrite content measurements have been carried out in this study. Strengthening and overaging phenomena of the ferrite phase have been identified by hardness measurements. Spinodal decomposition and heterogeneous precipitation of G-phase were found to be responsible for strengthening of the ferrite phase after aging with a temper parameter P in the range ca. 1.8 to 4.0. Homogeneous precipitation of noncoherent α'- and G-phases in ferrite, identified by both optical and transmission electron microscopical analyses for aging with P > 4.0 at 450degC, is associated with overaging phenomena. Three different fracture modes, dimples, cleavage and α/γ grain boundary separation, have been observed for Charpy V-notch and CT test specimens fractured at +20degC. (author)

  11. Technical Letter Report on the Cracking of Irradiated Cast Stainless Steels with Low Ferrite Content

    International Nuclear Information System (INIS)

    Crack growth rate and fracture toughness J-R curve tests were performed on CF-3 and CF-8 cast austenite stainless steels (CASS) with 13-14% of ferrite. The tests were conducted at ~320°C in either high-purity water with low dissolved oxygen or in simulated PWR water. The cyclic crack growth rates of CF-8 were higher than that of CF-3, and the differences between the aged and unaged specimens were small. No elevated SCC susceptibility was observed among these samples, and the SCC CGRs of these materials were comparable to those of CASS alloys with >23% ferrite. The fracture toughness values of unirradiated CF-3 were similar between unaged and aged specimens, and neutron irradiation decreased the fracture toughness significantly. The fracture toughness of CF-8 was reduced after thermal aging, and declined further after irradiation. It appears that while lowering ferrite content may help reduce the tendency of thermal aging embrittlement, it is not very effective to mitigate irradiation-induced embrittlement. Under a combined condition of thermal aging and irradiation, neutron irradiation plays a dominant role in causing embrittlement in CASS alloys.

  12. Cracking behavior of thermally aged and irradiated CF-8 cast austenitic stainless steel

    Science.gov (United States)

    Chen, Y.; Alexandreanu, B.; Chen, W.-Y.; Natesan, K.; Li, Z.; Yang, Y.; Rao, A. S.

    2015-11-01

    To assess the combined effect of thermal aging and neutron irradiation on the cracking behavior of CF-8 cast austenitic stainless steel, crack growth rate (CGR) and fracture toughness J-R curve tests were carried out on compact-tension specimens in high-purity water with low dissolved oxygen. Both unaged and thermally aged specimens were irradiated at ∼320 °C to 0.08 dpa. Thermal aging at 400 °C for 10,000 h apparently had no effect on the corrosion fatigue and stress corrosion cracking behavior in the test environment. The cracking susceptibility of CF-8 was not elevated significantly by neutron irradiation at 0.08 dpa. Transgranular cleavage-like cracking was the main fracture mode during the CGR tests, and a brittle morphology of delta ferrite was often seen on the fracture surfaces at the end of CGR tests. The fracture toughness J-R curve tests showed that both thermal aging and neutron irradiation can induce significant embrittlement. The loss of fracture toughness due to neutron irradiation was more pronounced in the unaged than aged specimens. After neutron irradiation, the fracture toughness values of the unaged and aged specimens were reduced to a similar level. G-phase precipitates were observed in the aged and irradiated specimens with or without prior aging. The similar microstructural changes resulting from thermal aging and irradiation suggest a common microstructural mechanism of inducing embrittlement in CF-8.

  13. Mathematical Analysis of Inclusion Removal from Liquid Steel by Gas Bubbling in a Casting Tundish

    Directory of Open Access Journals (Sweden)

    H. Arcos-Gutierrez

    2012-01-01

    Full Text Available The mechanism of inclusion removal from liquid steel by gas bubbling and bubble attachment in the tundish is complex due to the great number of variables involved, and it is even more difficult to study because of the turbulent flow conditions. The main objective of this work is to analyze and improve the understanding of the alumina inclusion removal rate by bubble attachment and by gas bubbling fluid dynamics effects. The results show that the inclusion collection probability mainly depends on the attachment mechanism by collision. This parameter was determined by calculating the induction time, which is shorter when the rupture time and the formation time of a stable three phases contact (particle/liquid/gas are ignored than when it is fully considered, affecting the attachment probability. In addition, to achieve acceptable inclusion removal, a smaller bubble diameter is required, such as 1 mm. This consideration is almost impossible to achieve during tundish operation; a more realistic bubble diameter around 10 mm is employed, resulting in a very inefficient inclusion removal process by bubble attachment. Nevertheless, in a real casting tundish the inclusion removal rate employing argon bubbling is efficient; is mainly due to the fluid flow pattern changes rather than bubble attachment. Consequently, it is imperative to consider the summation of both removal mechanisms to compute a better approximation of this important operation.

  14. Comparison of CFD Simulations with Experimental Measurements of Nozzle Clogging in Continuous Casting of Steels

    Science.gov (United States)

    Mohammadi-Ghaleni, Mahdi; Asle Zaeem, Mohsen; Smith, Jeffrey D.; O'Malley, Ronald

    2016-08-01

    Measurements of clog deposit thickness on the interior surfaces of a commercial continuous casting nozzle are compared with computational fluid dynamics (CFD) predictions of melt flow patterns and particle-wall interactions to identify the mechanisms of nozzle clogging. A submerged entry nozzle received from industry was encased in epoxy and carefully sectioned to allow measurement of the deposit thickness on the internal surfaces of the nozzle. CFD simulations of melt flow patterns and particle behavior inside the nozzle were performed by combining the Eulerian-Lagrangian approach and detached eddy simulation turbulent model, matching the geometry and operating conditions of the industrial test. The CFD results indicated that convergent areas of the interior cross section of the nozzle increased the velocity and turbulence of the flowing steel inside the nozzle and decreased the clog deposit thickness locally in these areas. CFD simulations also predicted a higher rate of attachment of particles in the divergent area between two convergent sections of the nozzle, which matched the observations made in the industrial nozzle measurements.

  15. Effect of heavy ion irradiation on microstructural evolution in CF8 cast austenitic stainless steel

    Science.gov (United States)

    Chen, Wei-Ying; Li, Meimei; Kirk, Marquis A.; Baldo, Peter M.; Lian, Tiangan

    2016-04-01

    The microstructural evolution in ferrite and austenitic in cast austenitic stainless steel (CASS) CF8, as received or thermally aged at 400 °C for 10,000 h, was followed under TEM with in situ irradiation of 1 MeV Kr ions at 300 and 350 °C to a fluence of 1.9 × 1015 ions/cm2 (∼3 dpa) at the IVEM-Tandem Facility. For the unaged CF8, the irradiation-induced dislocation loops appeared at a much lower dose in the austenite than in the ferrite. At the end dose, the austenite formed a well-developed dislocation network microstructure, while the ferrite exhibited an extended dislocation structure as line segments. Compared to the unaged CF8, the aged specimen appeared to have lower rate of damage accumulation. The rate of microstructural evolution under irradiation in the ferrite was significantly lower in the aged specimen than in the unaged. This difference is attributed to the different initial microstructures in the unaged and aged specimens, which implies that thermal aging and irradiation are not independent but interconnected damage processes.

  16. Improvement in creep-rupture life of 1Cr1Mo(1)/(4)V steel castings and their weld joints by addition of niobium

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Kulvir; Jaipal Reddy, G.; Reddy, K.S. [Corporate R and D, BHEL, Hyderabad (India). Metallurgy Dept.

    2008-07-01

    1Cr1Mo(1)/(4)V steel was cast with varying percentages of 0.04, 0.06 and 0.08% of niobium. The CrMoV cast steels having the above chemical composition, were subjected to a heat treatment by solutionising them to a temperature at 1040 C and subsequent cooling to room temperature, then, subjecting to a tempering at a temperature below the Ac1 point at 740 C. CrMoV electrodes were used for welding. Welding, as per the plant practices was carried out on the castings and weldability studies were conducted. Base metal and weld joint samples were subjected to hardness, impact, tensile, hot tensile and creep/ stress rupture testing. Creep/ stress rupture testing was carried out at 525, 550, 575 and 600 C and stresses varying from 100 - 300 MPa. Microstructural analysis including scanning and transmission electron microscopy was carried out on the as received as well as tested material. Room and high temperature tensile strength of 1Cr1Mo(1)/(4)V steel with Nb addition was higher than plain 1Cr1Mo(1)/(4)V steel. Among Nb added steels, creep-rupture and tensile strength of 0.06 and 0.08%Nb steel was found to be highest. The creep ductility of these casts is slightly lower than plain 1Cr1Mo(1)/(4)V steel but the cast with 0.08% Nb showed highest creep-rupture ductility. On the basis of creep-rupture test results on weld joint samples, the weld joints of steel with 0.08%Nb are found to be stronger than plain 1Cr1Mo(1)/(4)V steel as well as with 0.04 and 0.06%Nb. Creep-rupture ductility and impact strength of weld as well as HAZ region of 0.08% Nb steel were highest. 1Cr1Mo(1)/(4)V cast steel with Nb addition is envisaged to be used for steam turbine casing castings and valve castings. If turbine casings and valve castings are made of Nb containing steels, it is possible to increase the steam temperature and pressure and also the efficiency and reliability of the turbine. Substantial gains in terms of cost and life improvement can be made. (orig.)

  17. Inlfuence of carbon content on microstructure and mechanical properties of Mn13Cr2 and Mn18Cr2 cast steels

    Institute of Scientific and Technical Information of China (English)

    Lu Dingshan; Liu Zhongyi; Li Wei

    2014-01-01

    In this paper, a comparison study was carried out to investigate the inlfuence of carbon content on the microstructure, hardness, and impact toughness of water-quenched Mn13Cr2 and Mn18Cr2 cast steels. The study results indicate that both steels' water-quenched microstructures are composed of austenite and a smal amount of carbide. The study also found that, when the carbon contents are the same, there is less carbide in Mn18Cr2 steel than in Mn13Cr2 steel. Therefore, the hardness of Mn18Cr2 steel is lower than that of Mn13Cr2 steel but the impact toughness of Mn18Cr2 steel is higher than that of Mn13Cr2 steel. With increasing the carbon content, the hardness increases and the impact toughness decreases in these two kinds of steels, and the impact toughness of Mn18Cr2 steel substantialy exceeds that of Mn13Cr2 steel. Therefore, the water-quenched Mn18Cr2 steel with high carbon content could be applied to relatively high impact abrasive working conditions, while the as-cast Mn18Cr2 steel could be only used under working conditions of relatively low impact abrasive load due to lower impact toughness.

  18. COMPLEX RECONSTRUCTION OF THE CONTINUOUS CASTING MACHINES OF BELARUSIAN STEEL WORKS

    Directory of Open Access Journals (Sweden)

    A. A. Sotnikov

    2012-01-01

    Full Text Available Set of activities performed by the machine for continuous casting mill № 3 has enhanced its productivity and also master a new product - continuous casting round billet for seamless drawn pipes in tube-rolling shop

  19. Area Method Analysis and Thermodynamic Behavior of Nonmetallic Micro-Inclusions in Casting Slab of GCr15 Bearing Steel

    Institute of Scientific and Technical Information of China (English)

    WANG Hongli; MA Yitai; WANG Shuoming

    2009-01-01

    The distribution and characteristics of nonmetallic micro-inclusions of GCrI5 bearing steel were explored through metallographic area method in virtue of tracer method and electronic microscope.The results show that the micro-inclusions,of which the average value is 0.032%,are mainly the compounds formed via the adsorption/aggregation of multielement deoxidized compounds and secondarily deoxidized products on tundish liquid level.The micro-inclusions of diameters from 0 to 5 μm are 92.5% in total,which basically determines the characteristics of inclusions distribution in casting slab.The inclusions of diameters more than 10 μm only account for less than 1% in total,which have little influence on steel quality.The relationship between equilibrium compositions of the first deoxidation products and molten steel compositions was also calculated based on thermodynamic theory.

  20. Impact Strength of Austenitic and Ferritic-Austenitic Cr-Ni Stainless Cast Steel in -40 and +20°C Temperature

    Directory of Open Access Journals (Sweden)

    Kalandyk B.

    2014-10-01

    Full Text Available Studies described in this paper relate to common grades of cast corrosion resistant Cr-Ni steel with different matrix. The test materials were subjected to heat treatment, which consisted in the solution annealing at 1060°C followed by cooling in water. The conducted investigations, besides the microstructural characteristics of selected cast steel grades, included the evaluation of hardness, toughness (at a temperature of -40 and +20oC and type of fracture obtained after breaking the specimens on a Charpy impact testing machine. Based on the results of the measured volume fraction of ferrite, it has been found that the content of this phase in cast austenitic steel is 1.9%, while in the two-phase ferritic-austenitic grades it ranges from 50 to 58%. It has been demonstrated that within the scope of conducted studies, the cast steel of an austenitic structure is characterised by higher impact strength than the two-phase ferritic-austenitic (F-A grade. The changing appearance of the fractures of the specimens reflected the impact strength values obtained in the tested materials. Fractures of the cast austenitic Cr-Ni steel obtained in these studies were of a ductile character, while fractures of the cast ferritic-austenitic grade were mostly of a mixed character with the predominance of brittle phase and well visible cleavage planes.

  1. Behavior of surface residual stress in explosion hardened high manganese austenitic cast steel due to repeated impact loads

    International Nuclear Information System (INIS)

    Explosion hardened high manganese austenitic cast steel is being tried for rail crossing recently. From the previous studies, it became clear that high tensile residual stress was generated in the hardened surface layer by explosion and microcracks were observed. In this study, therefore, the behavior of surface residual stress in explosion hardened steel due to repeated impact loads was examined and compared with those of the original and shot peened steels. The results obtained are summarized as follows: (1) In the initial stage of the repetition of impact, high tensile surface residual stress in explosion hardened steel decreased rapidly with the repetition of impact, while those of the original and shot peened steels increased rapidly. This difference was attributed to the difference in depth of the work hardened layer in three testing materials. (2) Beyond 20 impacts the residual stress of three test specimens decreased gradually, and at more than 2000 impacts the compressive stress of about 500 MPa was produced regardless of the histories of working of testing materials. (3) The linear law in the second stage of residual stress fading was applicable to this case, and the range of the linear relationship was related to the depth of the work hardened layer of testing material. (4) From the changes in half-value breadth and peak intensity of diffraction X-ray, it was supposed that a peculiar microscopic strain exists in explosion hardened steel. (author)

  2. Attachment of Alumina on the Wall of Submerged Entry Nozzle During Continuous Casting of Al-Killed Steel

    Science.gov (United States)

    Deng, Zhiyin; Zhu, Miaoyong; Zhou, Yelian; Sichen, Du

    2016-06-01

    The mechanisms of the formation of different attachments on the walls of submerged entry nozzle (SEN) were studied for the processes of Al-killed steel (Ca-treated, HSLA) and ultra-low carbon Al-killed steel (ULC). To understand the mechanism, the types of inclusions in the steel taken in tundish and in bloom (or slab) were identified. In the case of ULC, the reoxidation product, micro-alumina particles were found to be the source of attachment on the inner wall of the SEN. To avoid reoxidation of the steel by the top slag, removal of the slag could be considered in order to improve the situation. No attached layer was found on the outer surface of the SEN after casting of the ULC steel. In the case of HSLA steel, an attached layer composed of plate-like alumina crystals was found in some trials. The entrainment of oxygen through the mold powder due to improper operation would be the reason for the formation of this type of attachment. The formation of the plate-like crystals was discussed with the help of CFD calculation.

  3. Evolution of recrystallization microstructure and texture during rapid annealing in strip-cast non-oriented electrical steels

    International Nuclear Information System (INIS)

    Non-oriented electrical steel as-cast strip was produced by twin roll strip casting process, and subsequently cold rolled and annealed at heating rates in the range of 3–450 °C/s with the aim to elucidate the effect of heating rate on the evolution of recrystallized microstructure and texture. The average grain size was rapidly increased when the heating rate was increased from 3 to 25 °C/s, and decreased when the heating rate was greater than 25 °C/s. The average grain size did not increase linearly with heating rate, which was related to different degree of nucleation and growth rate. The recrystallization texture exhibited pronounced improvement during rapid annealing. At high heating rate, the Goss and Cube had a higher probability of nucleation of shear bands with high stored energy, while the intensity of the γ-fiber texture was significantly reduced. The highest B50 value attained was 1.803 T at a heating rate of 300 °C/s. The study indicates that rapid heating has strong effect on the recrystallization behavior in non-oriented electrical steels, which facilitates optimization of microstructure and texture, especially in the coarse-grained structure. - Highlights: • The effects of heating rate on the microstructure and texture of non-oriented steel were investigated. • The average grain size did not change monotonically with heating rate. • Recrystallization texture exhibited pronounced improvement in the as-cast strip. • Superior magnetic properties were obtained in twin-rolled strip casting process

  4. Evolution of recrystallization microstructure and texture during rapid annealing in strip-cast non-oriented electrical steels

    Energy Technology Data Exchange (ETDEWEB)

    Fang, Feng [The State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110819 (China); Xu, Yun-Bo, E-mail: yunbo_xu@126.com [The State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110819 (China); Zhang, Yuan-Xiang; Wang, Yang; Lu, Xiang [The State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110819 (China); Misra, R.D.K [Laboratory for Excellence in Advanced Steel Research, Center for Structural and Functional Materials Research and Innovation and Department of Metallurgical and Materials Engineering, University of Texas at El Paso, 500W, University Avenue, El Paso, TX 79968 (United States); Wang, Guo-Dong [The State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110819 (China)

    2015-05-01

    Non-oriented electrical steel as-cast strip was produced by twin roll strip casting process, and subsequently cold rolled and annealed at heating rates in the range of 3–450 °C/s with the aim to elucidate the effect of heating rate on the evolution of recrystallized microstructure and texture. The average grain size was rapidly increased when the heating rate was increased from 3 to 25 °C/s, and decreased when the heating rate was greater than 25 °C/s. The average grain size did not increase linearly with heating rate, which was related to different degree of nucleation and growth rate. The recrystallization texture exhibited pronounced improvement during rapid annealing. At high heating rate, the Goss and Cube had a higher probability of nucleation of shear bands with high stored energy, while the intensity of the γ-fiber texture was significantly reduced. The highest B{sub 50} value attained was 1.803 T at a heating rate of 300 °C/s. The study indicates that rapid heating has strong effect on the recrystallization behavior in non-oriented electrical steels, which facilitates optimization of microstructure and texture, especially in the coarse-grained structure. - Highlights: • The effects of heating rate on the microstructure and texture of non-oriented steel were investigated. • The average grain size did not change monotonically with heating rate. • Recrystallization texture exhibited pronounced improvement in the as-cast strip. • Superior magnetic properties were obtained in twin-rolled strip casting process.

  5. (60)Co in cast steel matrix: A European interlaboratory comparison for the characterisation of new activity standards for calibration of gamma-ray spectrometers in metallurgy.

    Science.gov (United States)

    Tzika, Faidra; Burda, Oleksiy; Hult, Mikael; Arnold, Dirk; Marroyo, Belén Caro; Dryák, Pavel; Fazio, Aldo; Ferreux, Laurent; García-Toraño, Eduardo; Javornik, Andrej; Klemola, Seppo; Luca, Aurelian; Moser, Hannah; Nečemer, Marijan; Peyrés, Virginia; Reis, Mario; Silva, Lidia; Šolc, Jaroslav; Svec, Anton; Tyminski, Zbigniew; Vodenik, Branko; Wätjen, Uwe

    2016-08-01

    Two series of activity standards of (60)Co in cast steel matrix, developed for the calibration of gamma-ray spectrometry systems in the metallurgical sector, were characterised using a European interlaboratory comparison among twelve National Metrology Institutes and one international organisation. The first standard, consisting of 14 disc shaped samples, was cast from steel contaminated during production ("originally"), and the second, consisting of 15 similar discs, from artificially-contaminated ("spiked") steel. The reference activity concentrations of (60)Co in the cast steel standards were (1.077±0.019) Bqg(-1) on 1 January 2013 12h00 UT and (1.483±0.022) Bqg(-1) on 1 June 2013 12h00 UT, respectively.

  6. (60)Co in cast steel matrix: A European interlaboratory comparison for the characterisation of new activity standards for calibration of gamma-ray spectrometers in metallurgy.

    Science.gov (United States)

    Tzika, Faidra; Burda, Oleksiy; Hult, Mikael; Arnold, Dirk; Marroyo, Belén Caro; Dryák, Pavel; Fazio, Aldo; Ferreux, Laurent; García-Toraño, Eduardo; Javornik, Andrej; Klemola, Seppo; Luca, Aurelian; Moser, Hannah; Nečemer, Marijan; Peyrés, Virginia; Reis, Mario; Silva, Lidia; Šolc, Jaroslav; Svec, Anton; Tyminski, Zbigniew; Vodenik, Branko; Wätjen, Uwe

    2016-08-01

    Two series of activity standards of (60)Co in cast steel matrix, developed for the calibration of gamma-ray spectrometry systems in the metallurgical sector, were characterised using a European interlaboratory comparison among twelve National Metrology Institutes and one international organisation. The first standard, consisting of 14 disc shaped samples, was cast from steel contaminated during production ("originally"), and the second, consisting of 15 similar discs, from artificially-contaminated ("spiked") steel. The reference activity concentrations of (60)Co in the cast steel standards were (1.077±0.019) Bqg(-1) on 1 January 2013 12h00 UT and (1.483±0.022) Bqg(-1) on 1 June 2013 12h00 UT, respectively. PMID:27236833

  7. Constrained/unconstrained solidification within the massive cast steel/iron ingots

    Directory of Open Access Journals (Sweden)

    W. S. Wołczyński

    2010-04-01

    Full Text Available Some properties of the ingot and especially of the steel forging ingots depend on the ratio of a columnar structure area to an equiaxed structure area created during solidification. The C-E transition is fundamental phenomenon that can be applied to characterize massive cast steel ingots produced by the casting house. The mentioned ratio is created spontaneously due to the rate of heat transfer towards the ceramic mould and then to the environment. The ceramic mould operates as an isolator. So that the thickness of the mould together with a growing solid fraction control the heat transfer and finally the ratio of the columnar structure area to the equiaxed structure area. At first the increase of heat accumulation within the ceramic mould is observed. Next the stationary state for heat transfer is created and finally a gentle abatement of the mould temperature associated with the heat output to the environment is expected. The steep thermal gradients correspond to the increase of heat accumulation in the ceramic mould. The steep thermal gradients are required to promote the columnar structure formation. The full heat accumulation in the mould corresponds well with the C-E transformation while the appearance of the moderate thermal gradients is referred to the gentle temperature abatement within the ceramic mould. The equiaxed structure is expected within this period of heat transfer behavior. The steep thermal gradients involve the activity of viscosity gradient in the liquid. As the result a sedimentary cones are formed at the bottom of the ingot. The C-E transformation is associated with competition between columnar and equaixed structure formation. At the end of competition a fully equiaxed structure is formed. The viscosity gradient is replaced by the thermophoresis which is the driving force for the deposition of some equiaxed grain layers onto the surface of C+E zone. The convection together with the gravity allow the layers to be uniform

  8. Environmental fatigue behaviors of wrought and cast stainless steels in 310 .deg. C Deoxygenated Water

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Pyung Yeon

    2011-02-15

    Environmental fatigue behaviors of wrought type 316LN stainless steel and cast CF8M stainless steel were investigated. LCF tests were performed at fixed strain rate of 0.04%/s with 0.4%, 0.6%, 0.8%, 1.0% strain amplitudes in 310 .deg. C deoxygenated water environment. In addition, to analyze microstructure effect on fatigue behavior, low cycle fatigue tests in air environment were performed at fixed strain rate of 0.4%/s, 0.04%/s with 0.4%, 0.8% strain amplitudes. It was shown that the low cycle fatigue life of CF8M in a 310 .deg. C deoxygenated water environment was slightly longer than that of 316LN. On the other hand, the low cycle fatigue life of CF8M in a 310 .deg. C air environment was slightly shorter than that of 316LN or was similar with that of 316LN. Through OM observation and phase image analysis, it was confirmed that the ferrite content of CF8M tested in a 310 .deg. C deoxygenated water environment was larger than that of CF8M tested in a 310 .deg. C air environment. It was shown that the ferrite phase fraction of CF8M tested in 310 .deg. C deoxygenated water environment was approximately 26∼28% and that of CF8M tested in air environment was approximately 10∼12%. The difference of ferrite content in CF8M results in superior tensile properties as higher ferrite content. Furthermore, the difference of ferrite content in CF8M might be the cause of different result of fatigue life between CF8M and 316LN depending on environment. In this study, focused on CF8M having 26∼28% ferrite content, to understand the causes of these differences in a 310 .deg. C deoxygenated water environment, fracture surface and crack morphology were observed. And material factors like microstructure, mechanical properties factors like stress behavior during fatigue life, factors by environmentally assisted cracking (EAC) like hydrogen induced cracking (HIC) and chemical compositions of both materials were analyzed. Mainly in a 310 .deg. C deoxygenated water environment, the

  9. Machinability of clean thin-wall gray and ductile iron castings. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Bates, C.E.; Littleton, H.E.; Eleftheriou, E.; Griffin, R.D.; Dwyer, Z.B.; DelSorbo, C.; Sprague, J.

    1997-02-01

    First phase was to develop a laboratory technique for evaluating the machinability of gray and ductile iron; longer term goal is to learn how to modify the foundry process to produce castings meeting all specified mechanical properties while providing improved machining behavior. Microcarbides present in the irons were found to dominate the machinability of iron. Pearlitic irons with acceptable machinability contain 8.9 to 10.5 wt% microcarbides. The weight fraction microcarbides in the iron is influenced by carbide forming element concentrations, presence of elements that retard carbon diffusion, and cooling rate from the eutectic through the eutectoid temperature range. Tool wear rate increased at higher surface machining speeds and fraction microcarbides; all irons containing above 11.5% microcarbides had poor machinability. Graphite size, shape, distribution, etc. had a lesser effect on machinability. Reducing the addition of a foundry grade Ca and Al bearing 75% FeSi inoculant from 0.5 to 0.2% increased the tool life 100%. Inoculation test castings were also poured in a class 40 gray iron; laboratory analysis is currently underway. Exploratory studies were conducted to determine if tool force could be used to predict tool life: torque and feed forces were found to correlate with machinability.

  10. Tensile properties of strip casting 6.5 wt% Si steel at elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Li, Hao-Ze, E-mail: lhzqq83@163.com; Liu, Zhen-Yu, E-mail: zyliu@mail.neu.edu.cn

    2015-07-15

    Tensile behaviors of strip casting 6.5 wt% Si steel are tested at elevated temperatures ranging from 300 °C to 800 °C. A detailed study of the morphology of the fracture surface and the ordered phase at each deforming temperature is carried out by a scanning electron microscope and a transmission electron microscope. The results show that the deforming temperature rather than the ordered degree determines the tensile properties. As the deforming temperature increases, the stress level in the whole deforming stage continually decreases, whereas the elongation gradually increases. The ductile–brittle transition occurs around 350 °C. The elongation of 2% at 300 °C rapidly increases up to 16.4% at 350 °C and the corresponding fracture mode transforms from the complete cleavage fracture to the mixture of the very limited cleavage fracture, intergranular dimple fracture and the dimple fracture. Serrated flow is observed at 350 °C and 400 °C probably due to the occurrence of dynamic strain aging. Due to the gradually weakened grain boundary cohesion with the deforming temperature increasing, intergranular dimple pattern dominates the fracture surface at 600 °C and the elongation slowly increases from 16.4% at 350 °C to 22.8% at 600 °C. At 700 °C and 800 °C, the much more enhanced dynamic recovery, the substantially decreased stress levels which contribute to the inhibition of the intergranular dimple fracture, the much lower content of the B2 ordered phase at 700 °C, and the completely disordered state at 800 °C give rise to the dramatically improved elongations of 88.8% and 130.8%, respectively.

  11. Cleaning and prefilming of continuous casting closed circulating cooling water system%连铸密闭式循环冷却系统的清洗预膜处理

    Institute of Scientific and Technical Information of China (English)

    王伟; 金蕴智; 徐俊杰

    2011-01-01

    南通宝钢钢铁有限公司炼钢连铸单元的纯水循环水系统项目运行前进行设备、管道的清洗预膜处理,保证系统长期稳定运行.纯水密闭循环水系统经水力冲洗、化学清洗、预膜阶段,总历时168 h.通过控制过程指标,较好地完成清洗预膜工作,检测挂片出现明显色晕,腐蚀率满足GB 50050-2007《工业循环冷却水处理设计规范》要求.%In order to ensure the long-term stable operation of the pure water circulation system, the processes of cleaning and prefilming of the devices and pipelines of the said system in steelmaking and continuous casting unit of Baogang Group Nantong Steel Co., Ltd. Were carried out. The total time consumption of the phases: water washing, chemical cleaning and prefilming in pure water closed circulation system was 168 hours. Through the process index controlling, the work of cleaning and prefilming could be well completed; meanwhile, obvious haloing appeared on the hanging pieces for testing, the corrosion rate met the specification of GB 50050-2007 Code for Design of Inidustrial Recirculaling Cooling Water Treatment.

  12. Corrosion behaviour of some cast stainless steels and high alloy white irons in scrubber solutions of flue gas desulfurization plants

    International Nuclear Information System (INIS)

    Weight loss and electrochemical measurements have been used to determine the ranges of applicability of cast austenitic stainless steel Werkstoff No. 1.4408, of two special cast ferritic-austenitic stainless steels NORIDUR 9.4460 and NORICLOR NC 246 and of two high alloy Cr and CrMo white irons in scrubber solutions of Flue Gas Desulfurization (FGD) plants. Whereas the Werkstoff No. 1.4408 cannot be used due to its insufficient resistance to general and localized corrosion, NORIDUR 9.4460 can be used in scrubber solutions with pH > 2.5 and chloride concentrations up to 80 g/l, NORICLOR NC 246 with 5% Mo even in liquids with pH > 1.5 and chlorides up to 100 g/l. At lower pH-values both duplex stainless steels show active corrosion of either the austenite or the ferrite depending on the contents of hydrochloric acid in the solution. At higher chloride concentrations pitting occurs on the passive materials. The CrMo white iron NORILOY NL 252 with 25% Cr and 2% Mo can be used in scrubber liquids with pH > 3.5. As the ferritic matrix is cathodically protected by the precipitated carbides, there is no sensitivity of this alloy to chlorides. In liquids with pH < 3.5 there is selective corrosion of the ferritic matrix. For practical application of all these cast alloys the limits for purely corrosive attack have to be modified to assure resistance to a superposition of corrosion, erosion/abrasion and cavitation on parts exposed to real flow conditions in FGD scrubbers. (orig.)

  13. Effect of N addition on tensile and corrosion behaviors of CD4MCU cast duplex stainless steels

    Science.gov (United States)

    Son, Jinil; Kim, Sangshik; Lee, Jehyun; Choi, Byunghak

    2003-08-01

    The effect of N addition on the microstructure, tensile, and corrosion behaviors of CD4MCU (Fe-25Cr-5Ni-2.8Cu-2Mo) cast duplex stainless steel was examined in the present study. The slow strain rate tests were also conducted at a nominal strain rate of 1 × 10-6/s in air and 3.5 pct NaCl+5 pct H2SO4 solution for studying the stress corrosion cracking (SCC) behavior. It was observed that the volume fraction of austenitic phase in CD4MCU alloy varied from 38 to 59 pct with increasing nitrogen content from 0 to 0.27 wt. pct. The tensile behavior of CD4MCU cast duplex stainless steels, which tended to vary significantly with different N contents, appeared to be strongly related to the volume changes in ferritic and austenitic phases, rather than the intrinsic N effect. The improvement in the resistance to general corrosion in 3.5 pct NaCl+5 pct H2SO4 aqueous solution was notable with 0.13 pct N addition. The further improvement was not significant with further N addition. The resistance to SCC of CD4MCU cast duplex stainless steels in 3.5 pct NaCl+5 pct H2SO4 aqueous solution, however, increased continuously with increasing N content. The enhancement in the SCC resistance was believed to be related to the volume fraction of globular austenitic colonies, which tended to act as barriers for the development of initial pitting cracks in the ferritic phase into the sharp ones.

  14. Estimation of the residual life of L17HMF cast steel elements after long-term service

    OpenAIRE

    A. Zieliński; J. Dobrzański; G. Golański

    2009-01-01

    Purpose: of this paper is to present the changes of the mechanical properties and structure in material components of the power station boiler after long-term creep service made of G17CrMoV5-10 low-alloyed cast steel.Design/methodology/approach: The material of the research studies has been obtained from Polish power stations. Examined element has exceeded their assessed life of 105.000 hours. Mechanical properties and structure examinations were carried out on material after long-term servic...

  15. Displaying structural property and inheritance of cast iron surfacing on steel base

    Science.gov (United States)

    Shveev, I. A.

    2016-06-01

    Graphite inclusions heredity in deposited layer from remelted special cast iron billets was established. The possibility of controlling the structural state and the quality of the deposited layer due to technological parameters of welding and heat treatment of parts is shown. Ways of improving cast iron wear resistance durability are proposed.

  16. Numerical simulation of casting process to assist in defects reduction in complex steel tidal power component

    Science.gov (United States)

    Guo, E. J.; Zhao, S. C.; Wang, L. P.; Wu, T.; Xin, B. P.; Tan, J. J.; Jia, H. L.

    2016-03-01

    In order to reduce defects and improve casting quality, ProCAST software is performed to study the solidification process of discharge bowl. Simulated results of original casting process show that the hot tearing is serious at the intersection of blades and outer or inner rings. The shrinkage porosity appears at the bottom of discharge bowl and the transition area of wall thickness. Based on the formation mechanisms of the defects, the structure of chills attached on the outer surface of discharge bowl casting is optimized. The thickness of chills ranges from 25mm to 35mm. The positions of chills corresponded to the outer surface of the T-shaped parts. Compared to the original casting design (without chills), the hot tearing and shrinkage porosity of the discharge bowl are greatly improved with addition of chills.

  17. Cast Steels for Creep-resistant Parts Used in Heat Treatment Plants

    Directory of Open Access Journals (Sweden)

    A. Drotlew

    2012-12-01

    Full Text Available Creep-resistant parts of heat treatment furnaces are in most cases made from high-alloyed chromium-nickel and nickel-chromium ironalloys, both cast and wrought. This paper presents the types of casting alloys used for this particular purpose, since the majority of furnace components are made by the casting process. Standards were cited which give symbols of alloy grades used in technical specifications by the domestic industry. It has been indicated that castings made currently are based on a wider spectrum of the creep-resistant alloy grades than the number of alloys covered by the standards. Alloy grades recommended by the technical literature for individual parts of the furnace equipment were given. The recommendations reflect both the type of the technological process used and the technical tasks performed by individual parts of the furnace equipment. Comments were also made on the role of individual alloying elements in shaping the performance properties of castings.

  18. Phase-field modelling of microstructure formation during the solidification of continuously cast low carbon and HSLA steels

    Science.gov (United States)

    Böttger, B.; Apel, M.; Santillana, B.; Eskin, D. G.

    2012-07-01

    Cracking in continuous casting of steels has been one of the main problems for decades. Many of the cracks that occur during solidification are hot tears. To better understand the factors leading to this defect, microstructure formation is simulated for a low carbon (LCAK) and two high strength low alloyed (HSLA) steel grades during the initial stage of the process where the first solidified shell is formed inside the mould and where breakouts typically occur. 2D simulation is performed using the multiphase-field software MICRESS [1], which is coupled to the thermodynamic database TCFE6 [2] and the mobility database MOB2 [2], taking into account all elements which may have a relevant effect on the mechanical properties and structure formation during or subsequent to solidification. The use of a moving-frame boundary condition allows travelling through the entire solidification history starting from the slab surface, and tracking the morphology changes during growth of the shell. A heterogeneous nucleation model is included to permit the description of morphological transitions between the initial solidification and the subsequent columnar growth region. Furthermore, a macroscopic one-dimensional temperature solver is integrated to account for the transient and nonlinear temperature field during the initial stage of continuous casting. The external heat flux boundary conditions for this process were derived from thermal process data of the industrial slab caster. The simulation results for the three steel grades have been validated by thickness measurements of breakout shells and microstructure observation of the corresponding grades. Furthermore, the primary dendrite spacing has been measured across the whole thickness of the shell and compared with the simulated microstructures. Significant microstructure differences between the steel grades are discussed and correlated with their hot-cracking behavior.

  19. Energy Saving Melting and Revert Reduction (E-SMARRT): Optimization of Heat Treatments on Stainless Steel Castings for Improved Corrosion Resistance and Mechanical Properties

    Energy Technology Data Exchange (ETDEWEB)

    John N. DuPont; Jeffrey D. Farren; Andrew W. Stockdale; Brett M. Leister

    2012-06-30

    It is commonly believed that high alloy steel castings have inferior corrosion resistance to their wrought counterparts as a result of the increased amount of microsegregation remaining in the as-cast structure. Homogenization and dissolution heat treatments are often utilized to reduce or eliminate the residual microsegregation and dissolve the secondary phases. Detailed electron probe microanalysis (EPMA) and light optical microscopy (LOM) were utilized to correlate the amount of homogenization and dissolution present after various thermal treatments with calculated values and with the resultant corrosion resistance of the alloys.The influence of heat treatment time and temperature on the homogenization and dissolution kinetics were investigated using stainless steel alloys CN3MN and CK3MCuN. The influence of heat treatment time and temperature on the impact toughness and corrosion reistance of cast stainless steel alloys CF-3, CF-3M, CF-8, and CF-8M was also investigated.

  20. Rare earth metals influence on mechanical properties and crack resistance of GP240GH and G17CrMo5-5 cast steels

    Directory of Open Access Journals (Sweden)

    M. Gajewski

    2009-10-01

    Full Text Available This paper presents results of research on modification influence of REM on mechanical properties and crack resistance of GP240GH cast carbon steel and G17CrMo5-5 high-temperature cast steel. The tests have been performed on successive industrial melts. The rare earth metals were put into the ladle during tapping of heat melt from the furnace. Each time ca 2000 kg of liquid metals were modified. Because of this the amount of sulphur in the cast steel was decreased and the non-metallic inclusion morphology was significantly changed. There were tested mechanical properties (Re,Rm, plastic properties (A5,Z and impact strength (KV, and on the basis of the three-point bend test the KJC stress intensity factor was evaluated. It was noticed that the REM modification brings essential increase of impact strength as well as fracture toughness determined by KJC factor.

  1. Effect of long-term thermal aging on the mechanical properties of casting duplex stainless steels

    International Nuclear Information System (INIS)

    Highlights: ► The micro-hardness change tendency of ferrite and austenite by aging was studied. ► Embrittlement behavior of Z3CN20-09M CDSSs by aging was investigated by SP test. ► The crack propagation energy Wt − Wiu slightly changes with the thermal aging time. ► Spinodal decomposition and spinodally coarsening take place in ferrite by aging. ► Z3CN20-09M CDSSs become embrittlement after long-term thermal aging treatment. - Abstract: Casting duplex stainless steels (CDSSs) used for pressurized water reactor (PWR) pipes are susceptible to thermal aging brittleness during long-term service at its working temperature from 288 °C to 327 °C. In order to investigate its thermal aging behavior, Z3CN20-09M CDSSs have been thermally aged at 400 °C up to 15,000 h. The micro-hardness of austenite and ferrite phases, conventional tensile properties, impact properties and SPT properties at different aging duration have been measured. The results show that the micro-hardness in ferrite gradually increases with increase of long thermal aging time, while the effect of the long aging time on the micro-hardness in austenite is negligible. The tensile strength and yield strength progressively and slightly increase with the long aging time, respectively. The impact property test confirms that there is the same change tendency as the percentage of elongation which decreases with the long aging time. The changes of SPT ultimate strength, SPT yield strength and SPT specific fracture energy by aging individually show that there is an almost same tendency as the tensile strength, the yield strength and the percentage of elongation with the thermal aging time. All above the mechanical properties changes of Z3CN20-09M CDSSs are associated with the changes of the dislocation configurations in austenite, the precipitation of G-phase on the dislocation line and in ferrite phase, the spinodal decomposition and the coarsening of the spinodally decomposed structure in ferrite

  2. Thermal-aging evaluation of on site aged cast duplex stainless steel

    International Nuclear Information System (INIS)

    Cast duplex stainless steel was widely used for main coolant pipe in pressurized water reactors, they can suffer a loss of toughness after long-term thermal-aging. To evaluate mechanical properties of such as thermal-aged materials was investigated in laboratory using accelerated aged materials. In addition, to investigate the degradation mechanism, micro-structural behaviors were also investigated. According to such as laboratory data, main cause of degradation of these materials was considered ferrite hardening by spinodal decomposition and G-phase precipitation in the ferrite phase. In this study, thermal-aging evaluation has been performed using service aged elbow pipe in PWR plant, aged at 320℃ for 196,500h. Thermal-aging were evaluated using atom-probe analysis, scanning transmission electron microscope, and micro-Vickers hardness measurement. And then those parameters were compared accelerated thermal-aged materials. As a result, micro Vickers hardness of ferrite in service material (SCS14A), HV(0.025) was 616-630. Since micro Vickers hardness of un-aged ferrite phase is about HV(0.025)=300 in commercial SCS14A, the increasing of ferrite hardness during aging was 300. Cr-rich and Fe-rich regions were observed in the ferrite phase using Atom-probe analysis. In addition, Ni, Si and Mo clustering were also observed in the ferrite phase. So the ferrite phase was hardened caused by these micro-structural changes. Micro Vickers hardness of austenite phase, HV (0.025) was 155-180. Since micro Vickers hardness of un-aged austenite phase is about HV (0.025)=180-200, and no micro-structural change was observed in the austenite phase, so no change was observed in the austenite phase during aging. To compare the micro Vickers hardness of ferrite in service and accelerated materials using activation energy, Q=100kJ/mol, the ferrite hardness of in service material was very low rather than predictive line. This seems the activation energy was too conservative. (author)

  3. Evolution of recrystallization microstructure and texture during rapid annealing in strip-cast non-oriented electrical steels

    Science.gov (United States)

    Fang, Feng; Xu, Yun-Bo; Zhang, Yuan-Xiang; Wang, Yang; Lu, Xiang; Misra, R. D. K.; Wang, Guo-Dong

    2015-05-01

    Non-oriented electrical steel as-cast strip was produced by twin roll strip casting process, and subsequently cold rolled and annealed at heating rates in the range of 3-450 °C/s with the aim to elucidate the effect of heating rate on the evolution of recrystallized microstructure and texture. The average grain size was rapidly increased when the heating rate was increased from 3 to 25 °C/s, and decreased when the heating rate was greater than 25 °C/s. The average grain size did not increase linearly with heating rate, which was related to different degree of nucleation and growth rate. The recrystallization texture exhibited pronounced improvement during rapid annealing. At high heating rate, the Goss and Cube had a higher probability of nucleation of shear bands with high stored energy, while the intensity of the γ-fiber texture was significantly reduced. The highest B50 value attained was 1.803 T at a heating rate of 300 °C/s. The study indicates that rapid heating has strong effect on the recrystallization behavior in non-oriented electrical steels, which facilitates optimization of microstructure and texture, especially in the coarse-grained structure.

  4. Determination for the Entrapment Criterion of Non-metallic Inclusions by the Solidification Front During Steel Centrifugal Continuous Casting

    Science.gov (United States)

    Wang, Qiangqiang; Zhang, Lifeng

    2016-06-01

    In the current study, the three-dimensional fluid flow, heat transfer, and solidification in steel centrifugal continuous casting strands were simulated. The volume of fluid model was used to solve the multiphase phenomena between the molten steel and the air. The entrapment and final distribution of inclusions in the solidified shell were studied with the discussion on the effect of rotation behavior of the caster system. Main results indicate that after applying the rotation of the shell, the fluid flow transformed from a recirculation flow to a rotation flow in the mold region and was driven to flow around in the casting direction. As the distance below the meniscus increased, the distribution of the tangential speed of the flow and the centrifugal force along one diameter of the strand became symmetrical gradually. The jet flow from the nozzle hardly impinged on the same location on the shell due to the rotation of the shell during solidification. Thus, the shell thickness on the same height was uniform around, and the thinning shell and a hot spot on the surface of shell were avoided. Both of the measurement and the calculation about the distribution of oxide inclusions along the radial direction indicated the number of inclusions at the side and the center was more than that at the quarter on the cross section of billet. With a larger diameter, inclusions tended to be entrapped toward the center area of the billet.

  5. Effect of rolling deformation and solution treatment on microstructure and mechanical properties of a cast duplex stainless steel

    Indian Academy of Sciences (India)

    S K Ghosh; D Mahata; R Roychaudhuri; R Mondal

    2012-10-01

    The present study deals with the effect of rolling deformation and solution treatment on the microstructure and mechanical properties of a cast duplex stainless steel. Cast steel reveals acicular/Widmanstätten morphology as well as island of austenite within the -ferrite matrix. Hot rolled samples exhibit the presence of lower volume percent of elongated band of -ferrite (∼40%) and austenite phase which convert into finer and fragmented microstructural constituents after 30% cold deformation. By the solution treatment, the elongated and broken crystalline grains recrystallize which leads to the formation of finer grains (<10 m) of austenite. X-ray diffraction analysis has corroborated well with the above-mentioned microstructural investigation. Enhancement in hardness, yield strength and tensile strength values as well as drop in percent elongation with cold deformation increases its suitability for use in thinner sections. 30% cold rolled and solution treated sample reveals attractive combination of strength and ductility (25.22 GPa%). The examination of fracture surface also substantiates the tensile results. The sub-surface micrographs provide the potential sites for initiation of microvoids.

  6. Morphology and Precipitation Kinetics of MnS in Low-Carbon Steel During Thin Slab Continuous Casting Process

    Institute of Scientific and Technical Information of China (English)

    YU Hao; KANG Yong-lin; ZHAO Zheng-zhi; SUN Hao

    2006-01-01

    The morphology of manganese sulfide formed during thin slab continuous casting process in low-carbon steel produced by compact strip production (CSP) technique was investigated. Using transmission electron microscopy analysis, it was seen that a majority of manganese sulfides precipitated at austenite grain boundaries, the morphologies of which were spherical or close to the spherical shape and the size of MnS precipitates ranged from 30 nm to 100 nm. A mathematical model of the manganese sulfide precipitation in this process was developed based on classical nucleation theory. Under the given conditions, the starting and finishing precipitation temperatures of MnS in the continuous casting thin slab of the studied low-carbon steel are 1 189 ℃ and 1 171 ℃, respectively, and the average diameter of MnS precipitates is about 48 nm within this precipitation temperature range. The influences of chemical components and thermo-mechanical processing conditions on the precipitation behavior of MnS in the same process were also discussed.

  7. Effects of nonstandard heat treatment temperatures on tensile and Charpy impact properties of carbon-steel casting repair welds

    International Nuclear Information System (INIS)

    This report discusses carbon steel castings which are used for a number of different components in nuclear power plants, including valve bodies and bonnets. Components are often repaired by welding processes, and both welded components and the repair welds are subjected to a variety of postweld heat treatments (PWHT) with temperatures as high as 899 degrees C (1650 degrees F), well above the normal 593 to 677 degrees C (1100 to 1250 degrees F) temperature range. The temperatures noted are above the A1 transformation temperature for the materials used for these components. A test program was conducted to investigate the potential effects of such ''nonstandard'' PWHTs on mechanical properties of carbon steel casting welds. Four weldments were fabricated, two each with the shielded-metal-arc (SMA) and flux-cored-arc (FCA) processes,with a high-carbon and low-carbon filler metal in each case. All four welds were sectioned and given simulated PWHTs at temperatures from 621 to 899 degrees C (1150 to 1650 degrees F) in increments of 56 degrees C (100 degrees F) and for times of 5, 10, 20, and 40 h at each temperature. Hardness, tensile, and Charpy V-notch (CVN) impact tests were conducted for the as-welded and heat-treated conditions

  8. Heat treatment of investment cast PH 13-8 Mo stainless steel: Part II. Isothermal aging kinetics

    Science.gov (United States)

    Robino, C. V.; Cieslak, M. J.; Hochanadel, P. W.; Edwards, G. R.

    1994-04-01

    The hardening response of investment cast PH 13-8 Mo stainless steel has been evaluated by hardness measurements following aging in the temperature range normally specified for this alloy (510 °C to 593 °C). A new relationship between fraction transformed and hardness was developed, and analysis of the data in terms of the kinetics of precipitation, in a manner similar to that frequently applied to other precipitation-hardenable martensitic steels, yielded low time exponents and a low value for the apparent activation energy. The values of the time exponents were 0.49, 0.37, 0.56, and 0.53 at 510 °C, 538 °C, 566 °C, and 593 °C, respectively, and that for the apparent activation energy was 139 kJ/mole. As has been proposed for other maraging type steels, these estimates suggest that Β-NiAl precipitates along or near dislocations and that growth of the precipitates is dominated by dislocation pipe diffusion. However, these predictions were neither supported nor refuted by transmission electron microscopy (TEM) because of difficulties in imaging the Β-NiAl precipitates at the aging times and temperatures used. Further, analysis of the data using the formalism of Wert and Zener for the growth of precipitates with interfering diffusion fields indicated that the estimates of fraction transformed from hardness data are not fully appropriate for maraging type steels. Consideration of the nature of the Avrami analysis and the electron microscopy results suggests that other phenomena, including dislocation recovery and reversion of martensite to austenite, occur at rates sufficient to convolute the Avrami analysis. It is further suggested that these results cast doubt on the fundamental implications of previous analyses of precipitation kinetics in age-hardening martensitic steels. Although the Avrami analysis was found not to provide a tenable description of the precipitation kinetics, it does provide a reasonable methodology for portrayal of the hardening response

  9. Influence of formwork surface on the orientation of steel fibres within self-compacting concrete and on the mechanical properties of cast structural elements

    DEFF Research Database (Denmark)

    Svec, Oldrich; Zirgulis, Giedrius; Bolander, John E.;

    2014-01-01

    tomography, indicate that fibres tend to orient according to the flow patterns during casting, but such tendencies are suppressed near rough formwork surfaces. Fibre orientation, in turn, affects the mechanical properties of the concrete as demonstrated by the load testing of beams extracted from the cast......The influences of formwork surface on the final orientation of steel fibres immersed in self-compacting concrete and on the resulting mechanical response of the cast structural elements are investigated. Experimental observations of fibre orientation within cast slabs, obtained via computed...... slabs. These processes and results are simulated using a computational fluid dynamics model of the casting process, in tandem with a lattice model of the fracture of the beam specimens. The computational fluid dynamics model determines the coordinates of each fibre within the concrete, which serve...

  10. Comparative analysis of the behavior to corrosion of forged and cast austenitic stainless steel when used in a surgical prosthesis

    International Nuclear Information System (INIS)

    The selection of a material to be used in implants involves tests that cover aspects relative to its resistance to corrosion and its bio-compatibility. Testing the material implanted in the human body is a very difficult process or it is impossible via direct electrochemistry. Because of this laboratory tests have been developed that simulate the natural setting of the material in the organism using saline solutions that are kept at 37oC and pH 7.4. The material that is to be used should be resistant to corrosion in the body so that ions are not released into the organism and the device should maintain its integrity in service and not to suffer degradation. This work compares the behavior to corrosion of samples of a cast prosthesis (lower tibia, made of stainless steel ACI CF 3M) and a forged prosthesis (femorals, made of stainless steel ASTM F 621) with laminated bars of the same quality (stainless steel ASTM F 138). The samples were characterized with physical and electrochemical tests under three different thermal conditions: solubilized, annealed and forged or cast. The test pieces were submitted to electrochemical direct current tests during their immersion in a 0.9% deoxygenated NaCl solution and thermostatisized at 37oC. The Cr and Fe content in solution at the end of the electrochemical test was evaluated together with the micro hardness of the material and the characterization of the final stage of the material was carried out by optic microscopy and sweep electronics (CW)

  11. Selection of Heat Treatment Process and Wear Mechanism of High Wear Resistant Cast Hot-Forging Die Steel

    Institute of Scientific and Technical Information of China (English)

    WEI Min-xian; WANG Shu-qi; WANG Lan; CUI Xiang-hong; CHEN Kang-min

    2012-01-01

    Dry sliding wear tests of a Cr-Mo-V cast hot-forging die steel was carried out within a load range of 50--300 N at 400℃ by a pin-on-disc high temperature wear machine. The effect of heat treatment process on wear resistance was systematically studied in order to select heat treatment processes of the steel with high wear resistance. The morphology, structure and composition were analyzed using scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS) ; wear mechanism was also discussed. Tribo-oxide layer was found to form on worn surfaces to reduce wear under low loads, but appear inside the matrix to increase wear under high loads. The tribo-oxides were mainly consisted of Fe3O4 and Fe2O3, FeO only appeared under a high load. Oxidative mild wear, transition of mild-severe wear in oxidative wear and extrusive wear took turns to operate with increasing the load. The wear resistance strongly depended on the selection of heat treatment processes or microstructures. It was found that bainite presented a better wear resistance than martensite plus bainite duplex structure, martensite structure was of the poorest wear resistance. The wear resistance increased with increasing austenizing temperature in the range of 920 to 1 120 ℃, then decreased at up to 1 220 ℃. As for tempering temperature and microstructure, the wear resistance increased in following order: 700℃ (tempered sorbite), 200 ℃ (tempered martensite), 440 to 650 ℃ (tempered troostite). An appropriate combination of hardness, toughness, microstructural thermal stability was re- quired for a good wear resistance in high-temperature wear. The optimized heat treatment process was suggested for the cast hot-forging steel to be austenized at 1020 to 1 120 ℃, quenched in oil, then tempered at 440 to 650℃ for 2 h.

  12. The abrasive wear dependence research on chemical constitution, hardness and resistance of alloy cast steel Cr-Mo-V-Cu-Ni type

    International Nuclear Information System (INIS)

    In the work there are research program elements, alloying elements contents influence on abrasive wear for hot work. The aim of research is to define the hardness influence, resistance and contents of Cr, Mo, V on alloy cast steel abrasive wear Cr-Mo-V-Cu-Ni. (author)

  13. Investigation of weldability and property changes of high pressure heat-resistant cast stainless steel tubes used in pyrolysis furnaces after a five-year service

    International Nuclear Information System (INIS)

    Highlights: → To investigate the weldability and property changes of high pressure heat-resistant cast stainless steel (HP) tubes. → Welding was done by gas-tungsten arc welding (GTAW) process. → Composition of precipitates was characterized by means of SEM and EDS analyses. → The solution treatment was used to recover the properties of tubes. → To investigate mechanical strength of specimens, tensile tests were carried out at room temperature. -- Abstract: High pressure heat-resistant cast stainless steel (HP steel) tubes produced by centrifugal casting are used in petrochemical industries for pyrolysis furnaces. They have appropriate ductility and weldability in as-cast conditions. These steels lose their ductility and weldability after being used in service and, hence, require repair. In the present study, the effect of metallurgical changes on weldability and ductility was investigated. The life span of the studied tubes was 5 years. Using electrodes with a chemical composition close to the base metal analysis, welding was done by gas-tungsten arc welding (GTAW) process. Solution treatment was used to recover the properties of tubes which can be useful, depending on metallurgical changes.

  14. Problems of phase identification in high-nitrogen chromium-manganese cast steel

    OpenAIRE

    Z. Pirowski

    2008-01-01

    An atzcrnpt has been madc to offcr an intcrprctation of ihc rnicrostructurc of chromium-mangancx cast stccl aftcr adding to 1his stccla targc amount of nitrogcn as an alloying clcrncnr. Nitropcn was addcd 10 rhc cast stccl by two mcthods: rhc first mcthod consistcrl inadding a nitridcd fcrrornangancsc, the second method in rcmclting thc nitrogen-rscc alloy undcr rhc atrnosphcrc of nitrogen maintaininghigh N1 prcssurc abovc the mctal meSt (33 MPa).Somc imponant diffcrcnces in the microstructur...

  15. Development of Centrifugal Cast High Speed Steel Roll with High Wear Resistance for Pre-Finishing Stands of a Hot Rod-Wire Mill

    Institute of Scientific and Technical Information of China (English)

    JIANG Zhi-qiang; FENG Xi-lan; FU Han-guang; SHA Quan-you

    2004-01-01

    The present study aims at developing high speed steel ( HSS ) as roll materials to replace traditional roll materials such as the alloy cast iron and powder metallurgical (PM) hard alloy, because lowcost alley cast iron rolls have poor wear resistance and the cost of high-quality PM hard alloy rolls is too high to be accepted by some users. By means of a centrifugal casting method, HSS rolls with excellent wear resistance have been developed. Its hardness is 65 ~ 67HRC, and its variation is smaller than 2HRC ; its impact toughness excels 15J/cm2. Using pre-finishing stands of a high-speed hot wire-rod rolling mill, the wear raze of HSS rolls per one thousand ton of steel is 0. 25mm. However, the manufacturing burden of HSS rolls is obviously lower than that of PM hard alloy rolls; it is only 30% of that of PM hard alloy rolls.

  16. The shaping of zinc coating on surface steels and ductile iron casting

    OpenAIRE

    D. Kopyciński

    2010-01-01

    The studies aimed at an analysis of the formation and growth kinetics of zinc coating on reactive silicon-killed steels in a zinc bath. The growth kinetics of the produced zinc coatings was evaluated basing on the power-law growth equation. As regards galvanizing of the surface of products, investigation was done for various steel grades and ductile iron (DI) taking into account the quality and thickness of coating. It has been proved that the chemical constitution of basis significantly infl...

  17. Influence of Vanadium and Boron Additions on the Microstructure, Fracture Toughness, and Abrasion Resistance of Martensite-Carbide Composite Cast Steel

    Directory of Open Access Journals (Sweden)

    Waleed Elghazaly

    2016-01-01

    Full Text Available High chromium cast steel alloys are being used extensively in many industrial services where dry or wet abrasion resistance is required. Such steel castings are demanded for cement, stoneware pipes, and earth moving industries. In this research, five steel heats were prepared in 100 kg and one-ton medium frequency induction furnaces and then sand cast in both Y-block and final impact arm spare parts, respectively. Vanadium (0.5–2.5% and boron (120–150 ppm were added to the 18Cr-1.9C-0.5Mo steel heats to examine their effects on the steel microstructure, mechanical properties especially impact, fracture toughness and abrasion resistance. Changes in the phase transformation after heat treatment were examined using inverted, SEM-EDX microscopy; however, the abrasion resistance was measured in dry basis using the real tonnage of crushed and milled stoneware clay to less than 0.1 mm size distribution.

  18. Field Evaluations of Low-Frequency SAFT-UT on Cast Stainless Steel and Dissimilar Metal Weld Components

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, Aaron A.; Harris, R. V.; Doctor, Steven R.

    2008-11-01

    This report documents work performed at the Pacific Northwest National Laboratory (PNNL) in Richland, Washington, and at the Electric Power Research Institute's (EPRI) Nondestructive Examination (NDE) Center in Charlotte, North Carolina, on evalutating a low frequency ultrasonic inspection technique used for examination of cast stainless steel (CSS) and dissimilar metal (DMW) reactor piping components. The technique uses a zone-focused, multi-incident angle, low frequency (250-450 kHz) inspection protocol coupled with the synthetic aperture focusing technique (SAFT). The primary focus of this work is to provide information to the United States Nuclear Regulatory Commission on the utility, effectiveness and reliability of ultrasonic testing (UT) inspection techniques as related to the inservice ultrasonic inspection of coarse grained primary piping components in pressurized water reactors (PWRs).

  19. Additional grain refinement in recrystallization controlled rolling of Ti-microalloyed steels processed by near-net-shape casting technology

    International Nuclear Information System (INIS)

    This paper analyzes the recrystallization kinetics in Ti-microalloyed steels processed using 'beam blank' casting technology. The faster solidification rates associated with this technology brings a finer precipitation of TiN particles which are very effective in controlling austenite grain growth during hot working. Furthermore, these small precipitates have been shown to delay static and dynamic recrystallization. The finer the precipitates the higher the delay in recrystallization. Nevertheless, beyond particle size and distribution, the level of delay is very dependent on microstructure (above all austenite grain size) and deformation conditions (strain and temperature). This paper studies the effects of this recrystallization delay on the microstructure evolution during hot rolling. Special attention was paid to the study of the occurrence of partial recrystallization during the final stages of rolling, which could lead to the presence of mixed microstructures before transformation. The possibility of achieving an additional austenite grain size refinement prior to transformation was evaluated

  20. Microstructure and Eutectic Carbide Morphology of the High Speed Steel Strips Produced by Twin Roll Strip Casting Process

    Institute of Scientific and Technical Information of China (English)

    Hongshuang DI; Xiaoming ZHANG; Guodong WANG; Xianghua LIU

    2003-01-01

    The M2 high-speed steel strip was produced by using the laboratory scale twin roll strip caster. The microstructureand eutectic carbide morphology of thus produced products were observed and analyzed, and the comparison ofthose with conventional products was carried out. The effects of the processing parameters such as the meltingtemperature, the pouring temperature, rolling speed and separating force on the microstructure and eutectic carbidemorphology and their distribution were analyzed. The spheroidizing process of the strips in the annealing process wasinvestigated. The relations between the growth and spheroidizing of the eutectic carbide and the annealing technologywere obtained, and the mechanism of the twin roll strip casting process improving the eutectic carbide spheroidizingwas discussed. The theoretical instruction for determining the subsequent treatment process was provided.

  1. Additional grain refinement in recrystallization controlled rolling of Ti-microalloyed steels processed by near-net-shape casting technology

    Energy Technology Data Exchange (ETDEWEB)

    Arribas, M.; Lopez, B. [CEIT and Tecnun (University of Navarra), Po M. Lardizabal 15, 20018 San Sebastian, Basque Country (Spain); Rodriguez-Ibabe, J.M. [CEIT and Tecnun (University of Navarra), Po M. Lardizabal 15, 20018 San Sebastian, Basque Country (Spain)], E-mail: jmribabe@ceit.es

    2008-06-25

    This paper analyzes the recrystallization kinetics in Ti-microalloyed steels processed using 'beam blank' casting technology. The faster solidification rates associated with this technology brings a finer precipitation of TiN particles which are very effective in controlling austenite grain growth during hot working. Furthermore, these small precipitates have been shown to delay static and dynamic recrystallization. The finer the precipitates the higher the delay in recrystallization. Nevertheless, beyond particle size and distribution, the level of delay is very dependent on microstructure (above all austenite grain size) and deformation conditions (strain and temperature). This paper studies the effects of this recrystallization delay on the microstructure evolution during hot rolling. Special attention was paid to the study of the occurrence of partial recrystallization during the final stages of rolling, which could lead to the presence of mixed microstructures before transformation. The possibility of achieving an additional austenite grain size refinement prior to transformation was evaluated.

  2. The Effects of Austenitizing Conditions on the Microstructure and Wear Resistance of a Centrifugally Cast High-Speed Steel Roll

    Science.gov (United States)

    Kang, Minwoo; Lee, Young-Kook

    2016-07-01

    The influences of austenitizing conditions on the microstructure and wear resistance of a centrifugally cast high-speed steel roll were investigated through thermodynamic calculation, microstructural analysis, and high-temperature wear tests. When the austenitizing temperature was between 1323 K and 1423 K (1050 °C and 1150 °C), coarse eutectic M2C plates were decomposed into a mixture of MC and M6C particles. However, at 1473 K (1200 °C), the M2C plates were first replaced by both new austenite grains and MC particles without M6C particles, and then remaining M2C particles were dissolved during the growth of MC particles. The wear resistance of the HSS roll was improved with increasing austenitizing temperature up to 1473 K (1200 °C) because the coarse eutectic M2C plates, which are vulnerable to crack propagation, changed to disconnected hard M6C and MC particles.

  3. Effects of Thermocapillary Forces during Welding of 316L-Type Wrought, Cast and Powder Metallurgy Austenitic Stainless Steels

    CERN Document Server

    Sgobba, Stefano

    2003-01-01

    The Large Hadron Collider (LHC) is now under construction at the European Organization for Nuclear Research (CERN). This 27 km long accelerator requires 1248 superconducting dipole magnets operating at 1.9 K. The cold mass of the dipole magnets is closed by a shrinking cylinder with two longitudinal welds and two end covers at both extremities of the cylinder. The end covers, for which fabrication by welding, casting or Powder Metallurgy (PM) was considered, are dished-heads equipped with a number of protruding nozzles for the passage of the different cryogenic lines. Structural materials and welds must retain high strength and toughness at cryogenic temperature. AISI 316L-type austenitic stainless steel grades have been selected because of their mechanical properties, ductility, weldability and stability of the austenitic phase against low-temperature spontaneous martensitic transformation. 316LN is chosen for the fabrication of the end covers, while the interconnection components to be welded on the protrud...

  4. Effect of delta-ferrite on the mechanical properties of CF8M stainless steel castings at 4 K

    International Nuclear Information System (INIS)

    A series of five CF8M stainless steel castings, with varying delta-ferrite contents, has been tensile and fracture toughness tested at 4 K. Tensile tests were conducted in the low strain region to establish the initial strain hardening behavior for comparison with two phase deformation theory. It was found that the tensile behavior of the duplex austenite/delta-ferrite structure fits very well with the two phase deformation theory proposed by Ashby. The initial strain hardening rate is determined by the mean-free-path between delta-ferrite particles. Fracture toughness results at 4 K show a decrease in fracture toughness with increasing delta-ferrite content up to approximately 15%; at this point a continuous delta-ferrite crack path is established, and the fracture toughness remains constant with increasing delta-ferrite

  5. The effects of reversion heat treatment on the recovery of thermal aging embrittlement of CF8M cast stainless steels

    International Nuclear Information System (INIS)

    The thermal aging embrittlement of cast stainless steels (CASSs) is one of the key material property degradation that would limit the long-term operation nuclear power plants. In this study, we investigated the recovery behaviors of thermal aging embrittlement of cast stainless steels (CASSs) by the reversion heat treatment. Two heats of CF8M with different ferrite contents were used and the degree of aging embrittlement was measured by the micro-hardness of ferrite phases. It was found that the micro-hardness values of ferrites in the aged CF8M were significantly reduced after the reversion heat treatment at 550 °C for 30 min. Meanwhile, those of the un-aged CF8M were slightly increased by the reversion heat treatment. Also, the re-aging embrittlement behaviors of the recovered CF8M were similar to the initial aging behaviors. Finally, if the reversion heat treatment was applied to the un-aged CF8M, the degree of the embrittlement was reduced during the thermal aging heat treatment. These changes in the micro-hardness values were explained in view of the dissolution of the Cr-rich region formed during spinodal decomposition and the formation of Mo-rich precipitates in the ferrite phases during the reversion heat treatment. - Highlights: • Reversion heat treatment (R-HT) was used to recover thermal aging of CF8M. • During the R-HT, Cr-rich phases dissolved but Mo-rich phases precipitated in ferrites. • After the R-HT, the rate of re-embrittlement was similar to that of previous aging. • Pre-application of the R-HT reduced the degree of aging embrittlement of CF8M

  6. Evolution of microstructure, texture and inhibitor along the processing route for grain-oriented electrical steels using strip casting

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hai-Tao, E-mail: liuht@ral.neu.edu.cn [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China); Institute of Research of Iron and Steel, Shasteel, Zhangjiagang 215625, Jiangsu (China); Yao, Sheng-Jie [School of Materials Science and Engineering, Harbin Institute of Technology at Weihai, 264209 (China); Sun, Yu; Gao, Fei; Song, Hong-Yu; Liu, Guo-Huai [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China); Li, Lei; Geng, Dian-Qiao [Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110819 (China); Liu, Zhen-Yu; Wang, Guo-Dong [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China)

    2015-08-15

    In the present work, a regular grade GO sheet was produced successively by strip casting, hot rolling, normalizing annealing, two-stage cold rolling with intermediate annealing, primary recrystallization annealing, secondary recrystallization annealing and purification. The aim of this paper was to characterize the evolution of microstructure, texture and inhibitor along the new processing route by comprehensive utilization of optical microscopy, X-ray diffraction and transmission electron microscopy. It was found that a fine microstructure with the ferrite grain size range of 7–12 μm could be obtained in the primary recrystallization annealed sheet though a very coarse microstructure was produced in the initial as-cast strip. The main finding was that the “texture memory” effect on Goss texture started on the through-thickness intermediate annealed strip after first cold rolling, which was not similar to the “texture memory” effect on Goss texture starting on the surface layers of the hot rolled strip in the conventional production route. As a result, the origin of Goss nuclei capable of secondary recrystallization lied in the grains already presented in Goss orientation in the intermediate annealed strip after first cold rolling. Another finding was that fine and dispersive inhibitors (mainly AlN) were easy to be produced in the primary recrystallization microstructure due to the initial rapid solidification during strip casting and the subsequent rapid cooling, and the very high temperature reheating usually used before hot rolling in the conventional production route could be avoided. - Highlights: • A regular grade grain-oriented electrical steel was produced. • Evolution of microstructure, texture and inhibitor was characterized. • Origin of Goss nuclei lied in the intermediate annealed strip. • A fine primary recrystallization microstructure could be produced. • Effective inhibitors were easy to be obtained in the new processing route.

  7. Evolution of microstructure, texture and inhibitor along the processing route for grain-oriented electrical steels using strip casting

    International Nuclear Information System (INIS)

    In the present work, a regular grade GO sheet was produced successively by strip casting, hot rolling, normalizing annealing, two-stage cold rolling with intermediate annealing, primary recrystallization annealing, secondary recrystallization annealing and purification. The aim of this paper was to characterize the evolution of microstructure, texture and inhibitor along the new processing route by comprehensive utilization of optical microscopy, X-ray diffraction and transmission electron microscopy. It was found that a fine microstructure with the ferrite grain size range of 7–12 μm could be obtained in the primary recrystallization annealed sheet though a very coarse microstructure was produced in the initial as-cast strip. The main finding was that the “texture memory” effect on Goss texture started on the through-thickness intermediate annealed strip after first cold rolling, which was not similar to the “texture memory” effect on Goss texture starting on the surface layers of the hot rolled strip in the conventional production route. As a result, the origin of Goss nuclei capable of secondary recrystallization lied in the grains already presented in Goss orientation in the intermediate annealed strip after first cold rolling. Another finding was that fine and dispersive inhibitors (mainly AlN) were easy to be produced in the primary recrystallization microstructure due to the initial rapid solidification during strip casting and the subsequent rapid cooling, and the very high temperature reheating usually used before hot rolling in the conventional production route could be avoided. - Highlights: • A regular grade grain-oriented electrical steel was produced. • Evolution of microstructure, texture and inhibitor was characterized. • Origin of Goss nuclei lied in the intermediate annealed strip. • A fine primary recrystallization microstructure could be produced. • Effective inhibitors were easy to be obtained in the new processing route

  8. Characterization of precipitates in strip-cast 2.7%Si steel under different heat treatment conditions

    Directory of Open Access Journals (Sweden)

    Mou Junsheng

    2015-01-01

    Full Text Available A 1.5mm thickness as-cast Fe-2.7%Si strip was produced by twin-roll strip casting and the precipitates under different isothermal holding time (0.5 min–30 min and cooling rates (1∘/s–20 ∘C/s were investigated by thermal simulation experiment technology and electron probe micro-analyzer. The main precipitates in all specimens are AlN-MnS complex with a structure of core-edge. During isothermal holding, the number density of relatively large precipitates (≥ 0.3 μm decrease with increase in time and the mean size of the small precipitates (≤150 nm increases gradually. It can be attributed to the complicated interactions of dissolve, precipitation and coarsening behavior. For precipitates in strips cooling from 1380 ∘C to 20 ∘C, the mean size decreases continuously with increase in cooling rate because the corresponding growth rate and time of precipitates decrease. These results indicate that isothermal holding time and cooling rate have an important influence on size of precipitates in strip, which will be of great importance in optimizing properties of silicon steel.

  9. Fabrication of high permeability non-oriented electrical steels by increasing recrystallization texture using compacted strip casting processes

    Science.gov (United States)

    Liu, Hai-Tao; Schneider, J.; Li, Hua-Long; Sun, Yu; Gao, Fei; Lu, Hui-Hu; Song, Hong-Yu; Li, Lei; Geng, Dian-Qiao; Liu, Zhen-Yu; Wang, Guo-Dong

    2015-01-01

    In this paper we will report on the application of the twin-roll casting technique to get a 2 mm thick material of Fe-3.2%Si alloy, which was finally hot rolled, cold rolled and annealed. After a mild hot rolling to a thickness of 1 mm and a mild cold rolling to a thickness of 0.35 mm, we obtained a high intensity of λ-fiber (|| ND) and η-fiber (|| RD) texture concentrated on cube ({0 0 1}) component and a diminishing intensity of the γ-fiber (|| ND) texture, and a large average grain size in the final processed material. The experimental results for the evolution of the microstructure and texture along the used processing routes were described within the paper in detail. The formation mechanism for the desired recrystallization textures were explained in terms of oriented nucleation, micro-growth selection, accumulated deformation stored energy, geometric softening and orientation pinning. It will be demonstrated that this new processing route using the compact strip casting offers the possibility to fabricate high permeability non-oriented electrical steels without additional fabrication steps like hot band annealing or two step cold rolling with intermediate annealing as in the case of conventional processing route.

  10. Temperature effects on the static and dynamic fracture behaviors of low-silicon CA-15 tempered stainless steel castings

    Science.gov (United States)

    Hsu, Cheng-Hsun; Teng, Hwei-Yuan

    2005-04-01

    In this research we studied the effect of testing temperature on both static and dynamic fracturing behaviors of low-silicon CA-15 martensitic stainless steel (MSS) castings after austenitizing and tempering treatments. The results showed that the material's microstructure was influenced by heat treatment and various testing temperatures would cause different fracturing mechanisms. In static tensile tests, the 573-673 K tempered specimens occurred secondary strengthening at 423 K and 298 K testing temperatures. However, there is a contrast of weakening occurred at 123 K for the same type of tempered samples. The phenomenon was mainly triggered by local cracking at the ferrite/martensitic interface and incoherent precipitate site in the materials because of the existence of shrinkage stress under subzero temperature. In the dynamic strain-rate tests, impact embrittlement occurred in the 573-673 K tempered samples as a result of the tempered martensite embrittlement (TME) phenomenon. The ductile-to-brittle transition temperature (DBTT) of the tempered material was obviously lower than that of the as-cast material. Also, optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were performed to correlate the properties attained to the microstructural observation.

  11. Microstructure and local strain fields in a high-alloyed austenitic cast steel and a steel-matrix composite material after in situ tensile and cyclic deformation

    Energy Technology Data Exchange (ETDEWEB)

    Weidner, A.; Biermann, H. [Institute of Materials Engineering, Technische Universitaet Bergakademie Freiberg (Germany); Yanina, A.; Guk, S.; Kawalla, R. [Institute of Metal Forming, Technische Universitaet Bergakademie Freiberg (Germany)

    2011-09-15

    The tensile and cyclic deformation behaviour of a new metastable austenitic stainless cast TRIP (TRansformation Induced Plasticity) steel and a composite material consisting of austenitic steel matrix (AISI 304) with 5% MgO partially stabilized ZrO{sub 2} (MgO-PSZ) was studied in-situ in a scanning electron microscope (SEM). In-situ tests in the SEM show the evolution of the microstructure with the strain for uniaxial deformation and the number of cycles during fatigue, respectively. Initially, deformation bands develop. In these bands, the face-centred cubic austenite transforms into the hexagonal {epsilon}-martensite and subsequently to the body-centred cubic {alpha}'- martensite. This evolution was studied by different SEM techniques. Electron backscatter diffraction (EBSD) was applied for phase and orientation identification. The dislocation arrangement was investigated applying the electron channelling contrast imaging (ECCI) technique to different deformation stages. The studies are completed with measurements of local displacement fields using digital image correlation (DIC). (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  12. Development of Stronger and More Reliable Cast Austenitic Stainless Steels (H-Series) Based on Scientific Design Methodology

    Energy Technology Data Exchange (ETDEWEB)

    Muralidharan, G.; Sikka, V.K.; Pankiw, R.I.

    2006-04-15

    The goal of this program was to increase the high-temperature strength of the H-Series of cast austenitic stainless steels by 50% and upper use temperature by 86 to 140 F (30 to 60 C). Meeting this goal is expected to result in energy savings of 38 trillion Btu/year by 2020 and energy cost savings of $185 million/year. The higher strength H-Series of cast stainless steels (HK and HP type) have applications for the production of ethylene in the chemical industry, for radiant burner tubes and transfer rolls for secondary processing of steel in the steel industry, and for many applications in the heat-treating industry. The project was led by Duraloy Technologies, Inc. with research participation by the Oak Ridge National Laboratory (ORNL) and industrial participation by a diverse group of companies. Energy Industries of Ohio (EIO) was also a partner in this project. Each team partner had well-defined roles. Duraloy Technologies led the team by identifying the base alloys that were to be improved from this research. Duraloy Technologies also provided an extensive creep data base on current alloys, provided creep-tested specimens of certain commercial alloys, and carried out centrifugal casting and component fabrication of newly designed alloys. Nucor Steel was the first partner company that installed the radiant burner tube assembly in their heat-treating furnace. Other steel companies participated in project review meetings and are currently working with Duraloy Technologies to obtain components of the new alloys. EIO is promoting the enhanced performance of the newly designed alloys to Ohio-based companies. The Timken Company is one of the Ohio companies being promoted by EIO. The project management and coordination plan is shown in Fig. 1.1. A related project at University of Texas-Arlington (UT-A) is described in Development of Semi-Stochastic Algorithm for Optimizing Alloy Composition of High-Temperature Austenitic Stainless Steels (H-Series) for Desired

  13. Study on wear resistant cast B-containing 1Cr18Ni9Ti stainless steel

    Institute of Scientific and Technical Information of China (English)

    Kuang Jiacai; Jiang Zhiqiang; Zhang Shiyin; Ye Chang; Liu Qicheng

    2009-01-01

    The developed 1Cr18Ni9Ti austenitic stainless steel containing 1.63 wt.%B have been characterized by X-ray diffraction (XRD), electron probe microanalyzer (EPMA), optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and Vickers microhardness measurement. The microstructural evolution and property of high boron stainless steel after solution treatment at the temperature of 1050℃ are also investigated. The results show that the main compositions of borides are Fe, Cr and B, and with small amount of Ni, Mn and C elements. Silicon is insoluble in the borides. The hardness of borides is over 1,500 HV. It has been found that borides do not decompose during solution treatment, but part of borides dissolves into the matrix. The effect of increasing the solubility of boron element in the austenitic matrix favours the hardness enhancement by 8.54%. High boron stainless steel has excellent wear resistance in corrosive environment. Lifetime of transfer pipe made of high boron-containing stainless steel is 1.5-1.8 times longer than that of boron-free 1Cr18Ni9Ti stainless steel.

  14. Simulation of macrosegregation in a large vertical continuous casting of steel

    Science.gov (United States)

    Zheng, Y.; Wu, M.; Kharicha, A.; Ludwig, A.

    2016-07-01

    A three-phase mixed columnar-equiaxed solidification model considering fluid flow, heat and solute transport is applied to simulate the solidification in a vertical continuous casting. The key features of solidification phenomena in this process, such as evolution of columnar phase, evolution and floatation/sedimentation of equi- axed crystals, thermal solutal convection of the melt and the flow caused by crystal sedimentation, development of as-cast structure, the columnar-to-equiaxed transition (CET), and formation of macrosegregation, are simulated. It is predicted that there is an equiaxed zone in the central part of the strand, and the rest section is filled with columnar phase (or dominant with columnar phase). A relatively strong negative segregation in the equiaxed zone and a mostly neutral concentration in the columnar region are found. Near the CET, there is a so-called middle radius positive segregation band. Formation mechanisms of this segregation pattern are discussed.

  15. High temperature corrosion of cast heat resisting steels in CO + CO2 gas mixtures

    OpenAIRE

    Xu, Nan; Monceau, Daniel; Young, David; Furtado, Jader

    2008-01-01

    Two commercial variants of the cast heat resistant grade HP40Nb (Fe–25Cr–35Ni, Nb modified) were exposed to CO/CO2 gases at 982 and 1080 C in order to simulate exposure to the carbon and oxygen potentials realised in steam reformers under normal and overheated conditions. Both alloys developed external chromium-rich oxide scales, intradendritic silica precipitates and interdendritic oxide protrusions where primary, interdendritic carbides were oxidised in situ. Surprisingly, the lower silicon...

  16. Improvement of Structure and Properties of Cast Ferrite-Pearlite Steels for Freight Railway Cars

    Directory of Open Access Journals (Sweden)

    A. Rabinovich

    2008-03-01

    Full Text Available As it i s known For increasing of propcnics (YTS 2 380 MPa of cast stcds i t is c f k ~ i v tco incrcasc conlcnt o f alhsti~uiionaal lloyingclcrncnts, (Si, Mn, Cr, Ni. 1 lowevcr it lcads to rising in pricc olstccl ton. lncrcasing of Si and Mn conrcnl only is limitcd hy decreasing o lductility and weld nhility. As a rule silicon contcnt at ~hcsca ccls is not highcr than 0.4-0.67'0 and Si:Mn ratio is not highcr khan 1:2. Nowfor grain rcfincmcnt ~wc sin oculation of stcct by nitrogcn and clcincnrs with high chcmical affinity to nltmgcn. Mostly vanadium i s usd.howcvcr niobium sornctime is uscd. Dissldvantagcs of this arc high cost of alloying clcmcnrs and low thcrrnodynamic stability OFvanadium and niobium nitridcs. Parlicles of V(C,N and Nh(C.N dissolvc during hcating fnr licnt trcatmcnt or during wclding. It [cads lodccrcasing of grain refinement elfcc!.Adaptat ion or this microalloying stratcgy Tor casts producing For rrcight mil way cars let cstirnatc possibility of application thcsc casts in ancw gcnerazion freight railway cars.

  17. The effects of novel surface treatments on the wear and fatigue properties of steel and chilled cast iron

    Science.gov (United States)

    Carroll, Jason William

    Contact fatigue driven wear is a principal design concern for gear and camshaft engineering of power systems. To better understand how to engineer contact fatigue resistant surfaces, the effects of electroless nickel and hydrogenated diamond-like-carbon (DLC) coatings on the fatigue life at 108 cycles of SAE 52100 steel were studied using ultrasonic fatigue methods. The addition of DLC and electroless nickel coatings to SAE 52100 bearing steel had no effect on the fatigue life. Different inclusion types were found to affect the stress intensity value beyond just the inclusion size, as theorized by Murakami. The difference in stress intensity values necessary to propagate a crack for Ti (C,N) and alumina inclusions was due to the higher driving force for crack extension at the Ti (C,N) inclusions and was attributed to differences in the shape of the inclusion: rhombohedral for the Ti (C,N) versus spherical for the oxides. A correction factor was added to the Murakami equation to account for inclusion type. The wear properties of DLC coated SAE 52100 and chilled cast iron were studied using pin-on-disk tribometry and very high cycle ultrasonic tribometry. A wear model that includes sliding thermal effects as well as thermodynamics consistent with the wear mechanism for DLCs was developed based on empirical results from ultrasonic wear testing to 108 cycles. The model fit both ultrasonic and classic tribometer data for wear of DLCs. Finally, the wear properties of laser hardened steels - SAE 8620, 4140, and 52100 - were studied at high contact pressures and low numbers of cycles. A design of experiments was conducted to understand how the laser processing parameters of power, speed, and beam size, as well as carbon content of the steel, affected surface hardness. A hardness maximum was found at approximately 0.7 wt% carbon most likely resulting from increased amounts of retained austenite. The ratcheting contact fatigue model of Kapoor was found to be useful in

  18. Effect of Al2O3 on the Crystallization of Mold Flux for Casting High Al Steel

    Science.gov (United States)

    Zhou, Lejun; Wang, Wanlin; Zhou, Kechao

    2015-06-01

    In order to lower the weight of automotive bodies for better fuel-efficiency and occupant safety, the demand for high Al-containing advanced high strength steel, such as transformation-induced plasticity and twinning-induced plasticity steel, is increasing. However, high aluminum content in steels would tend to significantly affect the properties of mold flux during the continuous casting process. In this paper, a kinetic study of the effect of Al2O3 content on the crystallization behavior of mold flux was conducted by using the single hot thermocouple technique and the Johnson-Mehl-Avrami model combined with the Arrhenius Equation. The results suggested that Al2O3 behaves as an amphoteric oxide in the crystallization process of mold flux. The precipitated phases of mold flux change from cuspidine (Ca4Si2O7F2) into nepheline (NaAlSiO4) and CaF2, and then into gehlenite (Ca2Al2SiO7) with the increase of Al2O3 content. The kinetics study of the isothermal crystallization process indicated that the effective crystallization rate ( k) and Avrami exponent ( n) also first increased and then decreased with the increase of Al2O3 content. The values for the crystallization activation energy of mold flux with different Al2O3 contents were E R0.8A7 = 150.76 ± 17.89 kJ/mol, E R0.8A20 = 136.43 ± 6.48 kJ/mol, E R0.8A30 = 108.63 ± 12.25 kJ/mol and E R0.8A40 = 116.15 ± 8.17 kJ/mol.

  19. Effects of chills on the solidification pattern of an axial steel cast impeller

    OpenAIRE

    Copur, M.; Turan, A; Eruslu, M. N.

    2015-01-01

    This paper presents three-dimensional simulation of transient conduction heat transfer within an axial impeller (AISI 1016), two different sizes of chills (AISI 1016), core (green sand) and mold (green sand) by using Ansys CFX. Specific heat, density and thermal conductivity of AISI 1016 steel, mold and Core materials are considered as functions of temperatures

  20. An evaluation of depth sizing ability of ultrasonic testing by the large aperture transducer for axial crack in cast stainless steel pipe weld

    International Nuclear Information System (INIS)

    Ultrasonic testing is difficult for cast stainless steel which is used as the material of main coolant pipes in pressurized water reactors, because of the large attenuation and scattering of ultrasonic waves caused by its macro structure. Ultrasonic testing for the axial fatigue crack on welding area in the test piece of the cast stainless pipe was performed, using the double large aperture ultrasonic probes. In this study, depth sizing of defects was performed under the positive result of the detection of defects in former study. As a result, sizing of defects with over 20mm target depth for the specimen thickness 69mm is highly possible. (author)

  1. A study on NDE method of thermal aging of cast duplex stainless steels

    International Nuclear Information System (INIS)

    To maintain the integrity of applications of the duplex stainless steels currently in service, a study was conducted to develop a method to nondestructively estimate their Charpy-impact energy at room temperature. It was found that hardness of the ferrite phase is a reliable indicator of the process of embrittlement during long-term heating of duplex stainless steels. However, further information on the ferrite phase and the austenite phase is required for the estimation of Charpy-impact energy. An equation composed of the hardness values of ferrite and austenite phases, the ferrite content and the average spacing of ferrite phase islands was presented as a method applicable to the nondestructive estimation of Charpy-impact energy at room temperature. (orig.)

  2. Auburn Steel Company radioactive contamination incident

    International Nuclear Information System (INIS)

    On February 21, 1983, workers at the Auburn Steel Company, Auburn, New York discovered that about 120 tons of steel poured that day had become contaminated with 60Co. In addition to the steel, the air cleaning system and portions of the mill used in casting the steel were contaminated. Approximately 25 curies of 60Co were involved. Decontamination and disposal of the contamination cost in excess of $2,200,000. This report details the discovery of the contamination, decontamination of the plant and disposal of the contamination

  3. Types of greenhouse gas emissions in the production of cast iron and steel

    Science.gov (United States)

    Lisienko, V. G.; Chesnokov, Yu N.; Lapteva, A. V.; Noskov, V. Yu

    2016-09-01

    Types of carbon dioxide emissions in iron and steel production are indicated. Production processes have been classified according to mechanisms of carbon dioxide formation. Mathematical models for calculation of carbon dioxide emissions for each type of process are found. Calculations results of carbon dioxide emissions of coke (BF + EAF) and cokeless processes (Corex, Midrex, HyL-3, Romelt) in combination with EAF are provided.

  4. 钢骨架喷砂后清洗除尘工艺研究%Research on Technology of Cleaning Dust of Steel Skeleton after Sandblasting

    Institute of Scientific and Technical Information of China (English)

    谢彦飞; 彭拓; 王林; 曹广如; 李斌

    2014-01-01

    The effects of different types of cleaning agents and cleaning conditions on the surface of steel skeleton after sandblasting and the adhesive properties of steel-NR was investigated.The clean-ing agent of PRIME240 was determined.The best cleaning condition of PRIME240:cleaning time 5min ,dring time 4 min.With this condition treated steel skeleton ,the steel-NR adhesive property was superior to steel skeleton with the high pressure air treated.%探讨了不同种类清洗剂及清洗条件对钢骨架喷砂后表面清洁状态及钢-NR粘合性能的影响,确定清洗剂种类为PRIME240,清洗条件为:清洗时间5min,干燥时间4min,采用该工艺条件处理的钢-NR粘合性能要优于高压空气工艺方法。

  5. Effect of cooling rate and forced convection on as-cast structure of 2205 duplex stainless steel

    Directory of Open Access Journals (Sweden)

    Cheng Zhang

    2015-01-01

    Full Text Available To forecast the as-cast structure and ferrite-austenite phase ratio of 2205 duplex stainless steel (DSS, the effects of cooling rate and forced convection were observed in a high-vacuum resistance furnace in which the forced convection was created by the rotation of the crucible. The as-cast structure of all 2205 DSS samples is full equiaxed grains, and the microstructure consists of a great amount of desirable intra-granular austenite inside the continuous ferrite grain matrix, besides Widmanstatten austenite and grain boundary austenite. The ferrite grain size decreases gradually with the increase in the cooling rates (20 to 60 ìC·min-1 or the forced convection, while the ferrite grains of the samples solidified with a strong convection are barely changed when the cooling rate is below 50 ìC·min-1. Moreover, a small grain size is beneficial for the austenite formation but the influence is not very obvious under the cooling rates in the range of 5 to 50 ìC·min-1. Compared with grain size, the cooling rate has a greater influence on the final ferrite content. A model based on the experimental results is established to predict the ferrite content, which could be approximated by ヤ(%=20.5·exp(c/80.0+0.34d+34.1, where c is the cooling rate in ìC·min-1 and d is the grain size in mm. By using this model, the dependence of the final ferrite content on cooling rate and grain size is well described.

  6. Atmospheric corrosion rate expressed as a function of time. Effects of atmospheric conditions and alloying elements on corrosion resistance of steels and cast irons

    International Nuclear Information System (INIS)

    On the basis of function describing a change in atmospheric corrosion rate (K) in time (t) the published results of long-standing corrosion tests of a great number of cast irons and steels were statistically processed. The effect of chloride - ions, sulfur dioxide, alloying elements (Cu, Ni, Cr, Mn, Si, V, C) on the rate of initial corrosion on the active surface (K0), passivation properties (α0) of corrosion products and corrosion resistance (α0/K0) of iron-carbonic alloys in different climatic areas was revealed. The data permit further investigation of the mechanism of alloying element effect on atmopsheric corrosion of steels

  7. An evaluation of detection ability of ultrasonic testing with a large aperture transducer for axial cracks in cast stainless steel pipe welds

    International Nuclear Information System (INIS)

    Ultrasonic testing is difficult to apply to cast stainless steel which is the material of the main coolant pipes in pressurized water reactors, because of the large attenuation and scattering of ultrasonic waves caused by its macro structure. In this study, ultrasonic testing for progression of axial fatigue cracks of a welded area in the test piece of cast stainless steel pipe was performed using double big-size ultrasonic probes which were formerly developed in INSS. It was found that detection of defects that were over 6% of the target depth for the specimen thickness of 69mm is possible, and detection of defects with over 10% of the target depth is possible for all test conditions. (author)

  8. An assessment of the linear damage summation method for creep-fatigue failure with reference to a cast of type 316 stainless steel tested at 570 deg. C

    International Nuclear Information System (INIS)

    This paper presents preliminary results from the programme for hold period tests on a cast BQ of type 316 stainless steel at 570 deg. C. The results of tensile hold period tests on a relatively low ductility cast of type 316 stainless steel have indicated that the failure mechanism changes from a creep-fatigue interaction failure to a creep dominated failure at low strain levels. An assessment of the linear damage summation approach for failure prediction indicates that it is inappropriate for creep-fatigue interaction failures. For creep dominated fracture, failure occurs when the accumulation relaxation strain exhausts the material ductility i.e. Nsub(f epsilon R)=D. The failure criterion based on a creep summation in terms of time to fracture underestimates life

  9. Evaluation of material properties considering thermal embrittlement for accelerated aged CF-8M and CF-8A cast austenitic stainless steel

    International Nuclear Information System (INIS)

    Cast austenitic stainless steel have been widely used for primary coolant piping in light water reactors. This material is subject to thermal embrittlement at reactor operating temperature. CF-8M and CF-8A cast austenitic stainless steel is used for several components, such as primary coolant piping, elbow, pump casing, and valve bodies in light water reactors. Thermal embrittlement results in spinodal decomposition of delta-ferrite leading to decreased fracture toughness. In this study, the specimens were prepared using an accelerated aging method. The measurement of ferrite content, Charpy impact test and J-R test were performed to verify the predicting equation for aged material properties. In case of above 25% ferrite content, predicted result of J-R curve might be non-conservative

  10. Ultrasonic Characterization of Cast Austenitic Stainless Steel Microstructure: Discrimination between Equiaxed- and Columnar-Grain Material – An Interim Study

    Energy Technology Data Exchange (ETDEWEB)

    Ramuhalli, Pradeep; Good, Morris S.; Diaz, Aaron A.; Anderson, Michael T.; Watson, Bruce E.; Peters, Timothy J.; Dixit, Mukul; Bond, Leonard J.

    2009-10-27

    Ultrasonic nondestructive evaluation (NDE) and inspection of cast austenitic stainless steel (CASS) components used in the nuclear power industry is neither as effective nor reliable as is needed due to detrimental effects upon the interrogating ultrasonic beam and interference from ultrasonic backscatter. The root cause is the coarse-grain microstructure inherent to this class of materials. Some ultrasonic techniques perform better for particular microstructural classifications and this has led to the hypothesis that an ultrasonic inspection can be optimized for a particular microstructural class, if a technique exists to reliably classify the microstructure for feedback to the inspection. This document summarizes scoping experiments of in-situ ultrasonic methods for classification and/or characterization of the material microstructures in CASS components from the outside surface of a pipe. The focus of this study was to evaluate ultrasonic methods and provide an interim report that documents results and technical progress. An initial set of experiments were performed to test the hypothesis that in-service characterization of cast austenitic stainless steel (CASS) is feasible, and that, if reliably performed, such data would provide real-time feedback to optimize in-service inspections in the field. With this objective in mind, measurements for the experiment were restricted to techniques that should be robust if carried forward to eventual field implementation. Two parameters were investigated for their ability to discriminate between different microstructures in CASS components. The first parameter was a time-of-flight ratio of a normal incidence shear wave to that of a normal incidence longitudinal wave (TOFRSL). The ratio removed dependency on component thickness which may not be accurately reported in the field. The second parameter was longitudinal wave attenuation. The selected CASS specimens provided five equiaxed-grain material samples and five columnar

  11. The effect of clustering on the mobility of dislocations during aging in Nb-microalloyed strip cast steels: In situ heating TEM observations

    International Nuclear Information System (INIS)

    Cluster-strengthened Nb-microalloyed strip cast steels are of interest as clustering during aging leads to an enhancement in strength without compromising ductility, resulting in desirable mechanical properties. However, the precise strengthening mechanism is not well understood. Using in situ heating transmission electron microscopy, clustering was found to impede the movement of dislocations during aging. The attractive combination of ductility and strength was attributed to the effects of recovery and the restricted movement of dislocations through clustering

  12. Change in thermoelectric power of cast duplex stainless steel due to fluctuation of Cr concentration in ferrite phase caused by thermal aging

    International Nuclear Information System (INIS)

    Cast duplex stainless steel is frequently used in main coolant pipes of PWR (Pressurized water reactor) type nuclear power plants because of its excellent material strength, toughness and superior corrosion resistance. However, it is known that Cr concentration fluctuation in ferrite phase occurs due to thermal aging when this material is exposed to temperature over 300degC. As a result, the toughness decreases. In previous studies, it has been shown that thermoelectric power (TEP) is an effective parameter in non-destructive evaluation for thermal aging of cast duplex stainless steel. In this study, mechanisms of increase in TEP due to Cr concentration fluctuation caused by thermal aging were investigated. Referring to Cr concentration fluctuation in ferrite phase of thermal aged cast duplex stainless steel measured by 3D-atom prove, Fe-Cr-Ni alloys with different Cr concentrations, which represented local area Cr fluctuated, were prepared. Then, TEP, electrical conductivity and thermal conductivity of the alloys were measured, and the relationships between these values and Cr concentration were determined. Using the relationships and the Cr concentration fluctuations, TEP of thermal aged cast duplex steel were composed in the case when each Cr-fluctuated area acted in series connection and in parallel connection. Then, the changes in TEP due to thermal aging were simulated, and compared with that in experimentally measured TEP. As a result, recurrence curves of Cr concentration to TEP, electrical conductivity and thermal conductivity were downward convex parabolas. Therefore, it was found that, by means of creation of high and low Cr area in ferrite phase due to thermal aging, TEP, electrical conductivity and thermal conductivity of the whole material increased. When each Cr fluctuated area acted in parallel connections, increase in TEP due to thermal aging became larger and the change in the composed TEP came close to that in the experimentally measured TEP

  13. Improvements in Low-Frequency, Ultrasonic Phased-Array Evaluation for Thick Section Cast Austenitic Stainless Steel Piping Components

    International Nuclear Information System (INIS)

    Research is being conducted for the U.S. Nuclear Regulatory Commission (NRC) at the Pacific Northwest National Laboratory (PNNL) to assess the effectiveness and reliability of advanced nondestructive examination (NDE) methods for the inspection of light water reactor (LWR) components. A primary objective of this work is to evaluate various NDE methods to assess their ability to detect, localize, and size cracks in coarse-grained steel components. This particular study focused on the evaluation of custom-designed, low-frequency (500 kHz) phased-array (PA) probes for examining welds in thick-section cast austenitic stainless steel (CASS) piping. In addition, research was conducted to observe ultrasonic sound field propagation effects from known coarse-grained microstructures found in parent CASS material. The study was conducted on a variety of thick-wall, coarse-grained CASS specimens that were previously inspected by an older generation 500-kHz PA-UT probe and acquisition instrument configuration. This comparative study describes the impact of the new PA probe design on flaw detection and sizing in a low signal-to-noise environment. The set of Pressurized Water Reactor Owners Group (PWROG) CASS specimens examined in this study are greater than 50.8-mm (2.0-in.) thick with documented flaws and microstructures. These specimens are on loan to PNNL from the Electric Power Research Institute (EPRI) NDE Center in Charlotte, North Carolina. The flaws contained within these specimens are thermal fatigue cracks (TFC) or mechanical fatigue cracks (MFC) and range from 13% to 42% in through-wall extent. In addition, ultrasonic signal continuity was evaluated on two CASS parent material ring sections by examining the edge-of-pipe response (corner geometry) for regions of signal loss.

  14. Evaluation of the recovery of thermal aging embrittlement of CF8M cast stainless steels after reversion heat treatments

    International Nuclear Information System (INIS)

    The degradation of mechanical properties caused by the thermal aging embrittlement of cast stainless steels (CASSs) is considered one of the key issues that should be resolved for the continued operation of nuclear power plants. In this study, the effects of reversion heat treatments on the mechanical properties of CF8M were evaluated by tensile and small punch tests. The reversion heat treatments were performed at 550 °C and 600 °C for two heats of CF8M containing 11% and 32% of ferrites. After the reversion heat treatments (R-HT), the ductility and small punch energy of the aged CF8Ms were effectively recovered. The re-aging embrittlement behaviors of the recovered CF8M were less severe than the initial aging behaviors. Furthermore, the application of the R-HT to the as-received CF8M also reduced the degree of thermal aging embrittlement. The fracture surface analyses also confirmed the observed changes in mechanical properties. Finally, the optimum reversion heat treatment condition for the recovery of thermal aging embrittlement of CF8M was proposed

  15. Modeling of ultrasonic propagation in heavy-walled centrifugally cast austenitic stainless steel based on EBSD analysis.

    Science.gov (United States)

    Chen, Yao; Luo, Zhongbing; Zhou, Quan; Zou, Longjiang; Lin, Li

    2015-05-01

    The ultrasonic inspection of heavy-walled centrifugally cast austenitic stainless steel (CCASS) is challenging due to the complex metallurgical structure. Numerical modeling could provide quantitative information on ultrasonic propagation and plays an important role in developing advanced and reliable ultrasonic inspection techniques. But the fundamental obstacle is the accurate description of the complex metallurgical structure. To overcome this difficulty, a crystal orientation map of a CCASS specimen in the 96 mm × 12 mm radial-axial cross section was acquired based on the electron backscattered diffraction (EBSD) technique and it was used to describe the coarse-grained structure and grain orientation. A model of ultrasonic propagation for CCASS was built according to the EBSD map. The ultrasonic responses of the CCASS sample were also tested. Some experimental phenomena such as structural noise and signal distortion were reproduced. The simulated results showed a good consistence with the experiments. The modeling method is expected to be effective for the precise interpretation of ultrasonic propagation in the polycrystalline structures of CCASS. PMID:25670411

  16. Microstructures and mechanical properties of cast austenite stainless steels after long-term thermal aging at low temperature

    International Nuclear Information System (INIS)

    Highlights: ► The primary circuit piping materials from Ling Ao Nuclear Power Plant was thermally aged for as long as 20,000 h. ► G-phase precipitation was characterized by HRTEM. ► Hardness in ferrite and austenite, tensile properties and impact behaviors of the long-term aged materials were studied. ► The mechanism of thermal aging embrittlement was proposed. - Abstract: The cast austenite stainless steels were investigate in order to understand the microstructural evolution and mechanical properties in the long-term thermal aging at 400 °C for up to 20,000 h. Spinodal decomposition and G-phase precipitation in ferrite after long-term thermal aging lead to the degradation of mechanical properties. Ferrite hardness increases with aging time, but the austenite hardness does not change. Tensile strength is not strongly affected by aging time, but the plasticity has a significant decrease after long-term aging. Under impact with high strain rate, the ferrite phases deform by the way of deformation twinning. High stress concentration on the phase boundaries cause the phase boundary separating and the austenite’s tearing off

  17. In situ TEM study of G-phase precipitates under heavy ion irradiation in CF8 cast austenitic stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Wei-Ying [Argonne National Laboratory, Argonne, IL 60439 (United States); University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Li, Meimei; Zhang, Xuan; Kirk, Marquis A.; Baldo, Peter M. [Argonne National Laboratory, Argonne, IL 60439 (United States); Lian, Tiangan [Electric Power Research Institute, Palo Alto, CA 94304 (United States)

    2015-09-15

    Thermally-aged cast austenitic stainless steels (CASS) CF8 was irradiated with 1 MeV Kr ions at 300, 350 and 400 °C to 1.88 × 10{sup 19} ions/m{sup 2} (∼3 dpa) at the IVEM-Tandem Facility at the Argonne National Laboratory. Before irradiation, the distribution of G-phase precipitates in the ferrite showed spatial variations, and both their size and density were affected by the ferrite–austenite phase boundary and presence of M{sub 23}C{sub 6} carbides. Under 300 °C irradiation, in situ TEM observation showed G-phase precipitates were relatively unchanged in the vicinity of the phase boundary M{sub 23}C{sub 6} carbides, while the density of G-phase precipitates increased with increasing dose within the ferrite matrix. Coarsening of G-phase precipitates was observed in the vicinity of phase boundary M{sub 23}C{sub 6} carbides at 350 °C and 400 °C.

  18. Heat treatment of investment cast PH 13-8 Mo stainless steel: Part I. Mechanical properties and microstructure

    Science.gov (United States)

    Hochanadel, P. W.; Edwards, G. R.; Robino, C. V.; Cieslak, M. J.

    1994-04-01

    The microstructure of investment cast PH 13-8 Mo stainless steel heat-treated to various conditions was studied using light and electron microscopy, electron probe microanalysis, and Mössbauer spectroscopy. The mechanical properties were investigated by using uniaxial tensile testing, hardness testing, and Charpy impact testing. The Β-NiAl strengthening precipitates, though detectable by electron diffraction, were difficult to resolve by transmission electron microscopy (TEM) in specimens aged at low temperatures (566 °C and below). A high dislocation density was observed in the lath martensitic structure. The higher strength and lower ductility observed at low aging temperatures was attributed to both the high dislocation density and the precipitation of Β-NiAl. When samples were aged at high temperatures (> 566 °C), a lower dislocation density and a reverted austenite fraction on the order of 15 pct were observed. Spherical Β-NiAl precipitates were observed in the overaged condition. The decrease in strength and corresponding increase in ductility observed in samples aged at temperatures above 566 °C were attributed to the reverted austenite and recovery. Mechanical properties were improved when the homogenizing temperature and time were increased. Electron probe microanalysis quantified the increased homogeneity realized by increasing homogenizing temperature and time. Elimination of the refrigeration step, which normally follows the solution treatment, did not degrade the mechanical properties. Mössbauer spectroscopy showed only minor decreases in the fraction of retained austenite when refrigeration followed the solution treatment.

  19. Standard reference radiographs for steel castings up to 2 in. (50.8 mm) in thickness

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 This practice describes accepted procedures for and factors that influence laboratory immersion corrosion tests, particularly mass loss tests. These factors include specimen preparation, apparatus, test conditions, methods of cleaning specimens, evaluation of results, and calculation and reporting of corrosion rates. This practice also emphasizes the importance of recording all pertinent data and provides a checklist for reporting test data. Other ASTM procedures for laboratory corrosion tests are tabulated in the Appendix. (Warning-In many cases the corrosion product on the reactive metals titanium and zirconium is a hard and tightly bonded oxide that defies removal by chemical or ordinary mechanical means. In many such cases, corrosion rates are established by mass gain rather than mass loss.) 1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only. This standard does not purport to address all of the safety concerns, if any, assoc...

  20. Microstructural evolution in austenitic heat-resistant cast steel 35Cr25Ni12NNbRE during long-term service

    International Nuclear Information System (INIS)

    The microstructural evolution of austenitic heat-resistant cast steel 35Cr25Ni12NNbRE during aging and long-term service was investigated using optical microscope (OM), X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). The microstructure of the as cast steel consists of the dendritic austenite, the block-like eutectic carbide M7C3 spreaded among austenitic dendrite, and a small quantity of M23C6 carbide. The microstructure of the steel aged at 600 deg. C consists of eutectic carbide M23C6 transformed from eutectic carbide M7C3 and dendritic austenite in which fine secondary carbide particles M23C6 precipitated. The precipitated carbide M23C6 kept a cubic-cubic orientation relationship (OR) with austenite matrix. There existed a carbide precipitation free zone (PFZ) around the eutectic carbide. For the long-term serviced samples, the secondary carbide precipitated in the austenite strikingly increased and the PFZ disappeared. Part of the M23C6 transformed into M6C, which always kept a twin OR, [114]M6C//[110]A//[110]M23C6, with the austenite and the M23C6 secondary carbide. In addition, a small quantity of σ phase FeCr and ε-Cr2N were also identified. The effects of alloy composition and service condition on the microstructural evolution of the steel were discussed.

  1. Effect of Nb, V and Ti additions on the yield strength of hot direct rolled thin slab cast low carbon steel

    International Nuclear Information System (INIS)

    Ingots of low carbon steels with additions of Nb, V and Ti were made in a manner that simulated thin slab casting, and were hot direct rolled. Mn and Si contents were kept constant at 1.4 wt% and 0.25 wt% respectively. Carbon contents were varied from 0.04-0.88 wt%, vanadium from 0.02-0.09 wt% and titanium from 0.007-0.025. The niobium content was kept constant i.e. 0.042 for all the ingots. A yield strength of 385 Mpa and a tensile strength of 470 MPa was achieved in the steel microalloyed only with Nb. It was shown that addition of vanadium alone and vanadium and titanium together to steel containing 0.042 wt% Nb did not increase yield or tensile strength further. (author)

  2. The temperature dependence and environmental enhancement mechanism of fatigue crack growth rates of A 351-CF8A cast stainless steel in LWR environment

    International Nuclear Information System (INIS)

    The fatigue crack growth rates for A 351-CF8A cast stainless steel were determined over a range of temperatures from 93 degC to 338 degC (200 degF to 640 degF). The waveform was 17 mHz sinusoidal and the load ratio was 0.2. The environment was borated and lithiated water with a dissolved oxygen content of approximately 1 ppb. The results show an easily measurable (factors of 2 to 8) increase in crack growth rates due to the environment. However, these rates are well within the known band of results for low-alloy pressure vessel and low-carbon piping steels in LWR environments. An extensive fractographic investigation shows fatigue fracture surfaces consisting of brittle morphology. This fracture morphology is similar to that of stress corrosion cracking of stainless steels, suggesting that there is a distinctive environmental assistance mechanism resulting in the increased crack growth rates. (author)

  3. (Continuous casting 1985)

    Energy Technology Data Exchange (ETDEWEB)

    Wilde, R.A.

    1985-06-12

    The report covers the Continuous Casting '85 Conference including informal discussions with conference attendees. In general, the papers presented at the conference concerned an overview of continuous steel casting worldwide, state-of-the-art aspects of steel continuous casting technology including caster startup problems, modifications, control system strategies, energy use profiles, quality control aspects, steel chemistry control, refractories, operational aspects of continuous casters, etc. No papers were presented in the development of thin section or thin strip casting of steel. Informal discussions were held with several conference attendees including (1) Bernard Trentini, Executive Director of the Association Technique De La Siderurgie Francaise in Paris, France (similar to the American Iron and Steel Institute); (2) Dr. Wolfgang Reichelt and Dr. Peter Voss-Spilker both of Mannesmann Demag Huttentechnik -a continuous casting and other steel making machine builder in-lieu of meeting at their plant in Duisburg, FRG on May 31; (3) Ewan C. Hewitt of Devote McKee Corp., Sheffield, England; (4) Wilfried Heinemann, head of R D Dept. at Concast Standard AG in Zurich, Switzerland; and (5) Hideo Ueno, engineer of melting section, Mitsubishi Steel Mfg. Co. Ltd, Tokyo Japan. A visit was made to the Teesside Laboratories of British Steel Corp. for discussions of their thin section casting research program in particular and R D program in general.

  4. Final Report, Volume 4, The Develpoment of Qualification Standards forCast Super Duplex Stainless Steel (2507 Wrought Equivalent)

    Energy Technology Data Exchange (ETDEWEB)

    Hariharan, Vasudevan; Lundin, Carl, D.

    2005-09-30

    The objective of the program is to determine the suitability of ASTM A923 Standard Test methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic-Ferritic Stainless Steels for 25 Cr Cast Super Duplex Stainless Steels (ASTM A890-5A). Different tests were carried out on the materials procured from various steel foundries as stated in the ASTM A923. The foundries were designated as Foundry A, B, C and D. All the materials were foundry solution annealed. Materials from Foundry D were solution heat treated at The University of Tennessee also and then they were subjected to heat treatment schedule which was derived from the testing of wrought DSS to establish the A923 specification. This was possible because the material from the same heat was sufficient for conducting the full scope of heat treatment. This was done prior to carrying out various other tests. Charpy samples were machined. The Ferrite content was measured in all the Charpy samples using Feritscope{reg_sign} and ASTM E562 Manual Point Count Method. After the ferrite content was measured the samples were sent to AMC-Vulcan, Inc. in Alabama to conduct the Charpy impact test based on ASTM A923 Test Method B. This was followed by etch testing and corrosion analysis based on ASTM A923 Test Methods A and C respectively at University of Tennessee. Hardness testing using Rockwell B and C was also carried out on these samples. A correlation was derived between all the three test methods and the best method for evaluating the presence of intermetallic in the material was determined. The ferrite content was correlated with the toughness values. Microstructural analysis was carried out on the etch test samples using Scanning Electron Microscopy in order to determine if intermetallic phases were present. The fracture surfaces from Charpy test specimens were also observed under SEM in order to determine the presence of any cracks and whether it was a brittle or a ductile fracture. A correlation

  5. Physical and Mathematical Modeling of Thin Steel Slab Continuous Casting Secondary Cooling Zone Air-Mist Impingement

    Science.gov (United States)

    de León B., Melecio; Castillejos E., A. Humberto

    2015-10-01

    This study is an attempt to unveil the fluid dynamic phenomena occurring during interaction of air-mists with the surface of the steel strand during its pass through the continuous casting secondary cooling system. Air-mists generated under conditions of practical interest are studied while impacting on a vertical wall at room temperature. Experimentally a spatial multiple-counting technique based on capturing instantaneous double-exposure shadowgraphs is used to visualize the internal structure of mists at distances between 0 and 4 mm from the wall. Analysis of single exposure images allows determination of size distributions of primary (impinging) and secondary (ejecting) drops and of fluctuating thickness of water films formed on the wall surface. Besides, examination of image pairs enables measurement of velocity and trajectory angles of both kinds of drops. These results aided in the formulation and validation of a transient, turbulent, 3D, multiphase fluid dynamic model for simulating impinging air-mists. The model is based on KIVA-3V and for simulating the airborne mist region it solves the continuity equations—mass, momentum, turbulence quantities—for the air coupled with the equation of motion for drops sampled randomly from distributions assumed to govern their size and volume flux at the nozzle orifice. While for the impingement region submodels are established to estimate the results of drop/wall interaction, i.e., the dynamics of secondary drops and water films formed by the impingement of primary drops. The model forecasts reasonably well the random distributions of diameters, velocities, trajectory angles, and Weber numbers of both kind of drops moving near the wall. Additionally, it predicts well the average thickness of the water film and the important effect that air nozzle pressure has on the normal impinging velocity of drops; high pressures result in large drop velocities favoring intimate contact with the surface.

  6. Some Metallurgical Issues Concerning Austenite Conditioning in Nb-Ti and Nb-Mo Microalloyed Steels Processed by Near-Net-Shape Casting and Direct Rolling Technologies

    Science.gov (United States)

    López, Beatriz; Rodriguez-Ibabe, Jose M.

    2016-08-01

    As thin slab direct rolling technologies are moving to the production of higher quality steel grades, chemical compositions based on Nb-Ti and Nb-Mo become a good option. However, with the use of multiple microalloying additions, the as-cast austenite conditioning becomes more complex. This paper analyzes some of the microstructural features that should be taken into account during the as-cast austenite conditioning in Nb-Ti and Nb-Mo microalloyed steel grades. In the case of Nb-Ti grades, it has been observed that the process parameters during solidification and post-solidification steps affect the austenite evolution during hot rolling. This is due to the differences in the size and volume fraction of TiN particles that can be formed. Fine TiN precipitates have been shown to be able to delay recrystallization kinetics. Moreover, the solute drag effect of Ti cannot be ignored in the case of hyperstoichiometric Ti/N ratios. It is observed that Nb-Ti grades tend to have lower non-recrystallization temperatures compared to Nb grades, which means that pancaking of the austenite is more difficult for these steels. The opposite is observed for the Nb-Mo grades, although in both cases the behavior is affected by the nominal content of Nb.

  7. Final Report, Volume 4, The Development of Qualification Standards for Cast Super Duplex Stainless Steel (2507 Wrought Equivalent)

    Energy Technology Data Exchange (ETDEWEB)

    Hariharan, Vasudevan; Lundin, Carl, W.

    2005-09-30

    The objective of the program is to determine the suitability of ASTM A923 Standard Test methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic-Ferritic Stainless Steels for 25 Cr Cast Super Duplex Stainless Steels (ASTM A890-5A). Different tests were carried out on the materials procured from various steel foundries as stated in the ASTM A923. The foundries were designated as Foundry A, B, C and D. All the materials were foundry solution annealed. Materials from Foundry D were solution heat treated at The University of Tennessee also and then they were subjected to heat treatment schedule which was derived from the testing of wrought DSS to establish the A923 specification. This was possible because the material from the same heat was sufficient for conducting the full scope of heat treatment. This was done prior to carrying out various other tests. Charpy samples were machined. The Ferrite content was measured in all the Charpy samples using Feritscope® and ASTM E562 Manual Point Count Method. After the ferrite content was measured the samples were sent to AMC-Vulcan, Inc. in Alabama to conduct the Charpy impact test based on ASTM A923 Test Method B. This was followed by etch testing and corrosion analysis based on ASTM A923 Test Methods A and C respectively at University of Tennessee. Hardness testing using Rockwell B and C was also carried out on these samples. A correlation was derived between all the three test methods and the best method for evaluating the presence of intermetallic in the material was determined. The ferrite content was correlated with the toughness values. Microstructural analysis was carried out on the etch test samples using Scanning Electron Microscopy in order to determine if intermetallic phases were present. The fracture surfaces from Charpy test specimens were also observed under SEM in order to determine the presence of any cracks and whether it was a brittle or a ductile fracture. A correlation was

  8. Final Report, Volume 4, The Develpoment of Qualification Standards forCast Super Duplex Stainless Steel (2507 Wrought Equivalent)

    Energy Technology Data Exchange (ETDEWEB)

    Hariharan, Vasudevan; Lundin, Carl, D.

    2005-09-30

    The objective of the program is to determine the suitability of ASTM A923 Standard Test methods for Detecting Detrimental Intermetallic Phase in Wrought Duplex Austenitic-Ferritic Stainless Steels for 25 Cr Cast Super Duplex Stainless Steels (ASTM A890-5A). Different tests were carried out on the materials procured from various steel foundries as stated in the ASTM A923. The foundries were designated as Foundry A, B, C and D. All the materials were foundry solution annealed. Materials from Foundry D were solution heat treated at The University of Tennessee also and then they were subjected to heat treatment schedule which was derived from the testing of wrought DSS to establish the A923 specification. This was possible because the material from the same heat was sufficient for conducting the full scope of heat treatment. This was done prior to carrying out various other tests. Charpy samples were machined. The Ferrite content was measured in all the Charpy samples using Feritscope{reg_sign} and ASTM E562 Manual Point Count Method. After the ferrite content was measured the samples were sent to AMC-Vulcan, Inc. in Alabama to conduct the Charpy impact test based on ASTM A923 Test Method B. This was followed by etch testing and corrosion analysis based on ASTM A923 Test Methods A and C respectively at University of Tennessee. Hardness testing using Rockwell B and C was also carried out on these samples. A correlation was derived between all the three test methods and the best method for evaluating the presence of intermetallic in the material was determined. The ferrite content was correlated with the toughness values. Microstructural analysis was carried out on the etch test samples using Scanning Electron Microscopy in order to determine if intermetallic phases were present. The fracture surfaces from Charpy test specimens were also observed under SEM in order to determine the presence of any cracks and whether it was a brittle or a ductile fracture. A correlation

  9. Creep Behavior at 1273 K (1000 °C) in Nb-Bearing Austenitic Heat-Resistant Cast Steels Developed for Exhaust Component Applications

    Science.gov (United States)

    Zhang, Yinhui; Li, Mei; Godlewski, Larry A.; Zindel, Jacob W.; Feng, Qiang

    2016-07-01

    A series of Nb-bearing austenitic heat-resistant cast steels with variations of N/C ratios were investigated, and the morphological change of Nb(C,N) from faceted blocks, mixed flake-blocks to "Chinese-script" was observed as N/C ratios decreased. The creep behavior of these alloys was studied at 1273 K (1000 °C), and the longest creep life and lowest creep rate occurred in model alloys with script Nb(C,N). Residual δ-ferrites and (Cr,Fe)23C6 were adverse to creep properties. This work indicates that the control of N/C ratio is required for the as-cast microstructural strengthening.

  10. Production of Steel Casts in Two-Layer Moulds with Alkaline Binders Part 2. Facing sand with the alkaline organic binder REZOLIT

    Directory of Open Access Journals (Sweden)

    M. Holtzer

    2011-04-01

    Full Text Available This paper constitutes the second part of the article concerning the implementation of the two-layer mould technology for steel casts inZ.M. POMET. The results of the laboratory examinations of the backing sand with the inorganic binder RUDAL were presented in thefirst part of the paper. Whereas in the second part the results of the laboratory testing of the facing sand with the alkaline resin REZOLITare given. The technology of two-layer moulds was already implemented in Z.M. POMET within the target project. Examples of castingsmade in this technology are shown in the final part of this paper.

  11. 宝钢耐候钢连铸实践%CONTINUOUS CASTING OF ATMOSPHERIC CORROSION-RESISTING STEEL AT BAOSTEEL

    Institute of Scientific and Technical Information of China (English)

    阮晓明

    2001-01-01

    Based on the practice of continuous casting of atmospheric corrosion-resisting steel at Baosteel,some problems in the production were analyzed,and corresponding countermeasures have been put forward.And it has been proved that the measures are effective to improve the slab quality.%根据宝钢耐候钢连铸生产实践,分析了生产中存在的问题,并提出了相应改进措施,取得了较好的效果。

  12. Effect of the Solution Annealing and Chemical Passivation Followed by Aging on the Corrosion of Shell Mold Cast CF8 Stainless Steel

    Science.gov (United States)

    Kim, Kuk-Jin; Ju, Heongkyu; Moon, Young-Dae; Hong, Jun Ho; Pak, Sung Joon

    2016-10-01

    The effects of solution annealing and passivation of shell mold cast CF8 stainless steels on Elbow pipe fittings with 2-month room temperature aging have been studied using a corrosion technique. The resistance of corrosion increased with 2-month room temperature aging combined with solid solution annealing and chemical passivation. The mode of corrosion was deeply related to the δ-ferrite content, permeability, and passivation. The corrosion probability decreased as both the δ-ferrite content and the permeability decreased. Therefore, it is considered that δ-ferrite content and passive film of Cr2O3 play an important role in corrosion resistance of CF8 Elbow pipe fittings due to the long-term aging with solid solution annealing and chemical passivation. This result shows that the corrosion resistance of CF8 fittings can be enhanced by the solid solution annealing and chemical passivation. Decreased ferrite phases and permeability improve IGC resistance in CF8 steel.

  13. The effect of coiling temperature on the microstructure and mechanical properties of a niobium–titanium microalloyed steel processed via thin slab casting

    Energy Technology Data Exchange (ETDEWEB)

    Challa, V.S.A.; Zhou, W.H. [Laboratory for Excellence in Advanced Steel Research, Center for Structural and Functional Materials, Institute for Material Research and Innovation, University of Louisiana at Lafayette, P.O. Box 44130, Lafayette, LA 70503 (United States); Misra, R.D.K., E-mail: dmisra@louisiana.edu [Laboratory for Excellence in Advanced Steel Research, Center for Structural and Functional Materials, Institute for Material Research and Innovation, University of Louisiana at Lafayette, P.O. Box 44130, Lafayette, LA 70503 (United States); O' Malley, R. [Nucor Decatur Sheet Mill, 4301 Iverson Blvd., Trinity, AL 35673 (United States); Jansto, S.G. [CBMM North America, 1000 Old Pond Road, Bridgeville, PA 15017 (United States)

    2014-02-10

    We describe here the influence of coiling temperature on the microstructure and mechanical properties, especially toughness, in a low carbon niobium microalloyed steel processed via thin slab casting. The objective is to elucidate the impact of coiling temperature on the nature and distribution of microstructural constituents (including different phases, precipitates, and dislocations) that contribute to variation in the strength–toughness relationship of these steels. In general, the microstructure primarily consisted of fine lath-type bainite and polygonal ferrite, and NbC, TiC and (Nb, Ti)C precipitates of size ∼2–10 nm in the matrix and at dislocations. However, the dominance of bainite and distribution of precipitates was a function of coiling temperature. The lower coiling temperature provided superior strength–toughness combination and is attributed to predominantly bainitic microstructure and uniform precipitation of NbC, TiC, and (Nb, Ti)C during the coiling process, consistent with continuous cooling transformation diagrams.

  14. Microstructure, texture evolution and magnetic properties of strip-casting non-oriented 6.5 wt.% Si electrical steel doped with cerium

    Energy Technology Data Exchange (ETDEWEB)

    Li, Hao-Ze, E-mail: lhzqq83@163.com; Liu, Hai-Tao; Liu, Zhen-Yu, E-mail: zyliu@mail.neu.edu.cn; Wang, Guo-Dong

    2015-05-15

    A 0.3 mm thick non-oriented 6.5 wt.% Si electrical steel sheet doped with cerium is produced by twin-roll strip casting, hot rolling, warm rolling and annealing. A detailed study of the cerium precipitates in the as-cast strip, microstructure and texture evolution at different processing stages is carried out by electron probe micro-analysis, optical microscopy, X-ray diffraction and electron backscattered diffraction analysis. Grain interior distributing precipitates identified as Ce-oxides, Ce-oxysulfides and Ce-phosphides, and boundary distributing Ce-oxides and Ce-phosphides are observed in the as-cast strip. The initial as-cast strip is characterized by a much finer solidification microstructure and dominated by obvious < 001 >//ND texture through the strip thickness. After hot and warm rolling, inhomogeneous microstructure containing large amounts of in-grain shear bands is characterized by mixed < 110 >//RD and < 111 >//ND textures. The texture of the annealed sheet with a relatively large average grain size is far more optimized by the domination of the beneficial cube, rotated cube, (001)< 120 > to (001)< 130 > and Goss texture components, and the elimination of the detrimental γ-fiber texture, leading to a superior magnetic induction and improved iron loss. - Highlights: • An Fe–6.5 wt.% Si as-cast strip doped with cerium was produced. • A thin warm rolled sheet with limited edge cracks was obtained. • Microstructure and texture evolution at each stage were investigated. • Strong λ-fiber and Goss recrystallization textures were formed. • The magnetic properties of the annealed sheet were significantly improved.

  15. Microstructure, texture evolution and magnetic properties of strip-casting non-oriented 6.5 wt.% Si electrical steel doped with cerium

    International Nuclear Information System (INIS)

    A 0.3 mm thick non-oriented 6.5 wt.% Si electrical steel sheet doped with cerium is produced by twin-roll strip casting, hot rolling, warm rolling and annealing. A detailed study of the cerium precipitates in the as-cast strip, microstructure and texture evolution at different processing stages is carried out by electron probe micro-analysis, optical microscopy, X-ray diffraction and electron backscattered diffraction analysis. Grain interior distributing precipitates identified as Ce-oxides, Ce-oxysulfides and Ce-phosphides, and boundary distributing Ce-oxides and Ce-phosphides are observed in the as-cast strip. The initial as-cast strip is characterized by a much finer solidification microstructure and dominated by obvious < 001 >//ND texture through the strip thickness. After hot and warm rolling, inhomogeneous microstructure containing large amounts of in-grain shear bands is characterized by mixed < 110 >//RD and < 111 >//ND textures. The texture of the annealed sheet with a relatively large average grain size is far more optimized by the domination of the beneficial cube, rotated cube, (001)< 120 > to (001)< 130 > and Goss texture components, and the elimination of the detrimental γ-fiber texture, leading to a superior magnetic induction and improved iron loss. - Highlights: • An Fe–6.5 wt.% Si as-cast strip doped with cerium was produced. • A thin warm rolled sheet with limited edge cracks was obtained. • Microstructure and texture evolution at each stage were investigated. • Strong λ-fiber and Goss recrystallization textures were formed. • The magnetic properties of the annealed sheet were significantly improved

  16. Microstructure and Mechanical Properties of High-Alloyed 23Cr-5Mn-2Ni-3Mo Cast Steel / Mikrostruktura I Właściwości Mechaniczne Wysokostopowego Staliwa 23Cr-5Mn-2Ni-3Mo

    Directory of Open Access Journals (Sweden)

    Kalandyk B.

    2015-12-01

    Full Text Available The article presents the microstructure and mechanical properties of cast duplex stainless steel type 23Cr-5Mn-2Ni-3Mo. It has been shown that the structure of the tested cast steel is composed of ferrite enriched in Cr, Mo and Si, and austenite enriched in Mn and Ni. In the initial state, at the interface, precipitates rich in Cr and Mo were present. A high carbon content (0.08%C in this cast steel indicates that probably those were complex carbides of the M23C6 type and/or σ phase. Studies have proved that the solution annealing conducted at 1060°C was not sufficient for their full dissolution, while at the solutioning temperature of 1150°C, the structure of the tested material was composed of ferrite and austenite.

  17. Effect of Tempering and Strain on Decomposition of Metastable Austenite in X210CrW12 Thixo-Cast Steel

    Science.gov (United States)

    Rogal, Ł.; Bonarski, J. T.; Bobrowski, P.

    2016-03-01

    Thixoforming of hot rolled X210CrW12tool steel led to the formation of globular austenitic grains (82.4 vol.%) surrounded by eutectic mixture (α-Fe and M7C3 carbides). The thixo-cast steel reached compression strength 4.8 GPa at plastic strain 34%. The analysis of pole figures after deformation indicated distinct texturization of microstructure in comparison with undeformed steel. Main texture components for austenite were {101}, , while ferrite did not reveal clearly formed orientation. DSC analysis confirmed that austenitic structure in the X210CrW12 steel was metastable and temperature of decomposition depended on the strain applied at 634 °C for the un-deformed sample and at 599 °C for sample compressed up to 4.8 GPa. Discontinuous transformation of austenite into perlite, that started mainly at grain boundaries and proceeded to the center, was the predominant mechanism responsible for the decomposition of globular grains in thixoformed X210CrW12 steel. The decomposition caused by tempering of supersaturated and severely strained steel led to obtaining characteristic product of transformation of higher hardness in comparison with only tempered sample. In the deformed sample the reaction started on slip bands and twins which revealed high density of defects, promoting precipitation of carbides, followed by local depletion in carbon as a result of α'- Fe formation. In contrast to non-deformed state they covered the area of grains. Two fronts of reaction α-Fe plate +M3C → mixture of α-Fe and M7C3 carbides were also observed.

  18. Mathematical Modeling of High-Temperature Constitutive Equations and Hot Processing Maps for As-Cast SA508-3 Steel

    Science.gov (United States)

    Sui, Dashan; Wang, Tao; Zhu, Lingling; Gao, Liang; Cui, Zhenshan

    2016-08-01

    The hot deformation behavior and hot workability characteristics of as-cast SA508-3 steel were studied by modeling the constitutive equations and developing hot processing maps. The isothermal compression experiments were carried out at temperatures of 950°C, 1050°C, 1150°C, and 1250°C and strain rates of 0.001 s-1, 0.01 s-1, 0.1 s-1, and 1 s-1 respectively. The two-stage flow stress models were established through the classical theories on work hardening and softening, and the solution of activation energy for hot deformation was 355.0 kJ mol-1 K-1. Based on the dynamic material model, the power dissipation and instability maps were developed separately at strains of 0.2, 0.4, 0.6 and 0.8. The power dissipation rate increases with both the increase of temperature and the decrease of strain rate, and the instable region mainly appears on the conditions of low temperature and high strain rate. The optimal hot working parameters for as-cast SA508-3 steel are 1050-1200°C/0.001-0.1 s-1, with about 25-40% peak efficiency of power dissipation.

  19. Status for cast stainless steel in older Swedish nuclear power plants, March 1996; Status foer gjutet rostfritt staal i aeldre svenska kaernkraftverk, mars 1996

    Energy Technology Data Exchange (ETDEWEB)

    Trolle, M.

    1996-04-01

    The purpose of this study is to compile what is known about larger cast components primarly in older BWR nuclear power plants with external circulation pumps. The work includes metallurgical data and a compilation on the material that the owner of Oskarshamn 1, OKG AB, has delivered to The Swedish Nuclear Power Inspectorate as a result of the investigation of these components. An overview of the investigations performed on the other Swedish plants of similar design during the annual outage 1995 is also described in this report. International experinece is also reported. The results from OKG AB show that there has been extensive cracking in both valves and pump casings and that they are probably resulting defects from the manufacturing process, but an environmental factor cannot be excluded. In order to get a complete picture of the situation in Swedish nuclear power plants a more extensive survey needs to be performed. Internationally the phenomenon of hot cracking in cast stainless steel is well known, but not as severe as in Oskarshamn 1. One question however that is discussed is the recommended amount of ferrite in these steels in order to avoid hot cracking without risking embrittlement of the ferrite phase. The Swedish utilities specify 3%, some European countries recommend 8%. Japan suggests ferrite contents up to 30%. 25 refs.

  20. Fabrication of high permeability non-oriented electrical steels by increasing 〈0 0 1〉 recrystallization texture using compacted strip casting processes

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hai-Tao, E-mail: liuht@ral.neu.edu.cn [State Key Laboratory of Rolling and Automation, Northeastern University, PO Box 105, Shenyang 110819 (China); Institute of Research of Iron and Steel, Shasteel, Zhangjiagang 215625, Jiangsu (China); Schneider, J. [Institut für Metallformung, Technische Universität Bergakademie Freiberg, Bernhard-von-Cotta-Str. 4, D-09596 Freiberg (Germany); Li, Hua-Long [Institute of Research of Iron and Steel, Shasteel, Zhangjiagang 215625, Jiangsu (China); Sun, Yu; Gao, Fei; Lu, Hui-Hu; Song, Hong-Yu [State Key Laboratory of Rolling and Automation, Northeastern University, PO Box 105, Shenyang 110819 (China); Li, Lei; Geng, Dian-Qiao [Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110819 (China); Liu, Zhen-Yu; Wang, Guo-Dong [State Key Laboratory of Rolling and Automation, Northeastern University, PO Box 105, Shenyang 110819 (China)

    2015-01-15

    In this paper we will report on the application of the twin-roll casting technique to get a 2 mm thick material of Fe-3.2%Si alloy, which was finally hot rolled, cold rolled and annealed. After a mild hot rolling to a thickness of 1 mm and a mild cold rolling to a thickness of 0.35 mm, we obtained a high intensity of λ-fiber (〈0 0 1〉|| ND) and η-fiber (〈0 0 1〉|| RD) texture concentrated on cube ({0 0 1}〈0 1 0〉) component and a diminishing intensity of the γ-fiber (〈1 1 1〉|| ND) texture, and a large average grain size in the final processed material. The experimental results for the evolution of the microstructure and texture along the used processing routes were described within the paper in detail. The formation mechanism for the desired recrystallization textures were explained in terms of oriented nucleation, micro-growth selection, accumulated deformation stored energy, geometric softening and orientation pinning. It will be demonstrated that this new processing route using the compact strip casting offers the possibility to fabricate high permeability non-oriented electrical steels without additional fabrication steps like hot band annealing or two step cold rolling with intermediate annealing as in the case of conventional processing route. - Highlights: • High permeability non-oriented electrical steel was fabricated by strip casting processes. • Hot band annealing or two step cold rolling with intermediate annealing was eliminated. • Prevailing of 〈0 0 1〉|| ND and 〈0 0 1〉|| RD textures over diminishing 〈1 1 1〉|| ND texture was realized. • Evolution of microstructure and texture along the used processing routes were described.

  1. Fabrication of high permeability non-oriented electrical steels by increasing 〈0 0 1〉 recrystallization texture using compacted strip casting processes

    International Nuclear Information System (INIS)

    In this paper we will report on the application of the twin-roll casting technique to get a 2 mm thick material of Fe-3.2%Si alloy, which was finally hot rolled, cold rolled and annealed. After a mild hot rolling to a thickness of 1 mm and a mild cold rolling to a thickness of 0.35 mm, we obtained a high intensity of λ-fiber (〈0 0 1〉|| ND) and η-fiber (〈0 0 1〉|| RD) texture concentrated on cube ({0 0 1}〈0 1 0〉) component and a diminishing intensity of the γ-fiber (〈1 1 1〉|| ND) texture, and a large average grain size in the final processed material. The experimental results for the evolution of the microstructure and texture along the used processing routes were described within the paper in detail. The formation mechanism for the desired recrystallization textures were explained in terms of oriented nucleation, micro-growth selection, accumulated deformation stored energy, geometric softening and orientation pinning. It will be demonstrated that this new processing route using the compact strip casting offers the possibility to fabricate high permeability non-oriented electrical steels without additional fabrication steps like hot band annealing or two step cold rolling with intermediate annealing as in the case of conventional processing route. - Highlights: • High permeability non-oriented electrical steel was fabricated by strip casting processes. • Hot band annealing or two step cold rolling with intermediate annealing was eliminated. • Prevailing of 〈0 0 1〉|| ND and 〈0 0 1〉|| RD textures over diminishing 〈1 1 1〉|| ND texture was realized. • Evolution of microstructure and texture along the used processing routes were described

  2. Long time thermal aging of static cast SA 351 grade CF8M austenitic stainless steel elbow from Beznau unit 2

    International Nuclear Information System (INIS)

    Due to the degradation of the Inconel steam generator tubing, NOK replaced steam generators (SGs) in both Beznau Units 1 and 2. Beznau Unit 1 SGs were replaced in 1993 after approximately 175,000 hours of operation. Beznau Unit 2 SGs were replaced in 1998 after approximately 207,000 hours of operation. During the replacement of the SGs, NOK also replaced the hot and crossover leg elbows directly attached to the SGs. Thus SA 351 Grade CF8M austenitic stainless steel material from the hot and cold leg elbows including the weld metal joining the elbows to piping were available for evaluation of thermal aging. Thermal embrittlement of cast duplex stainless steel, in the case of Beznau Units 1 and 2 SG elbows SA 351 Grade CF8M, can result in either cleavage of the ferrite or separation of the ferrite/austenite grain boundaries. Thermal aging of cast duplex stainless steel at operating temperatures of Pressurized Water Reactors (PWR) can lead to precipitation of phases in the ferrite. The temperature at which the precipitation of the additional phases in the ferrite is decreased in Mo-bearing CF8M steels. Testing of the thermally aged (175,000 hours) Beznau Unit 1 crossover leg elbow and hot leg elbow materials was completed in 1996. Both the crossover leg and hot leg elbows'material exhibited relatively high fracture toughness values after 175,000 hours of operation. This paper presents the fracture toughness and ferrite measurement test results from the thermally aged (207,000 hours) Beznau Unit 2 hot leg materials. The hot leg elbow static casting material (SA 351 Grade CF8M) exhibited relatively high fracture toughness properties, JIC and Tearing Modulus, after thermal aging for 207,000 hours at operating temperature. The test results of the fracture mechanics specimens showed that the degradation had saturated. Comparison of the fracture toughness values used in the Leak-Before Break (LBB) analysis with the fracture toughness values obtained for the Beznau Unit 2

  3. Numerical Solution of Heat Tranfer Problem with Flow and Solidification in Round Billet Continuous Casting of Steel

    Institute of Scientific and Technical Information of China (English)

    JiahongGUO; XinHong

    1999-01-01

    In this paper,two dimensional unsteady flow and energy equations are employed for simulation of the flow and heat transfer in round billet continuous casting A numerical method is developed,by using finite volume method and equivalent specific heat method to solve the equations of flow and heat transfer with solidification.The numerical result shows that the method of this paper is efficient for analyzing the flow and heat transfer with solidification of round billet continuous casting.

  4. Development of Cast Alumina-forming Austenitic Stainless Steel Alloys for use in High Temperature Process Environments

    Energy Technology Data Exchange (ETDEWEB)

    Muralidharan, Govindarajan [ORNL; Yamamoto, Yukinori [ORNL; Brady, Michael P [ORNL; Pint, Bruce A [ORNL; Pankiw, Roman [Duraloy Technologies Inc; Voke, Don [Duraloy Technologies Inc

    2015-01-01

    There is significant interest in the development of alumina-forming, creep resistant alloys for use in various industrial process environments. It is expected that these alloys can be fabricated into components for use in these environments through centrifugal casting and welding. Based on the successful earlier studies on the development of wrought versions of Alumina-Forming Austenitic (AFA) alloys, new alloy compositions have been developed for cast products. These alloys achieve good high-temperature oxidation resistance due to the formation of protective Al2O3 scales while multiple second-phase precipitation strengthening contributes to excellent creep resistance. This work will summarize the results on the development and properties of a centrifugally cast AFA alloy. This paper highlights the strength, oxidation resistance in air and water vapor containing environments, and creep properties in the as-cast condition over the temperature range of 750°C to 900°C in a centrifugally cast heat. Preliminary results for a laboratory cast AFA composition with good oxidation resistance at 1100°C are also presented.

  5. HYDRO-ABRASIVE JET CLEANING TECHNOLOGY OF STEEL SHEETS DESIGNED FOR LASER CUTTING

    Directory of Open Access Journals (Sweden)

    I. Kachanov

    2013-01-01

    Full Text Available Investigations executed by the BNTU “Shipbuilding and hydraulics” department have shown that rather efficient implementation of the requirements to the metal sheet surface designed for laser cutting can be achieved by using hydro-abrasive jet cleaning while applying water pump equipment with the range of pressure – 20–40 MPa. Type of working fluid plays a significant role for obtaining surface of the required quality. The conducted experiments have demonstrated that the efficient solution of the assigned problems can be ensured by using a working fluid containing bentonite clay, surface-active agent polyacrylamide, soda ash and the rest water.

  6. Influence of thermal aging on primary water stress corrosion cracking of cast duplex stainless steel (second report). Consideration on fractography after slow strain rate technique

    International Nuclear Information System (INIS)

    In order to evaluate the stress corrosion cracking (SCC) susceptibility of cast duplex stainless steel which is used for the main coolant pipe of pressurized water reactors (PWRs), the slow strain rate technique (SSRT) and the constant load test (CLT) of the materials were performed in simulated primary water at 360degC. The cast duplex stainless steel contains ferrite phase with ranging from 8 to 23% and its mechanical properties are affected by long time thermal aging. Therefore, we paid attention to the influence of its ferrite content and thermal aging on the SCC susceptibility of this unaged and aged stainless steel and prepared three kinds of specimen with different ferrite contents (23%, 15% and 8%). The brittle fracture of the unaged specimens after SSRT mainly consists of quasi-cleavage fracture in austenitic phase. After aging, it changes to a mixture of quasi-cleavage fracture in both austenitic and ferritic phases. Microcracks were observed on the unaged specimen surfaces and aged ones for 10,000 hours at 400degC after about 10,000 hours of the CLT under the load condition of 1.2∼2.0 times of yield strength. The crack initiation sites of CLT specimens are similar to SSRT fracture surfaces. The SCC susceptibility of this 23% ferrite material increases with aging time at 400degC. The SCC susceptibility of 15% and 23% ferrite materials are higher than that of 8% ferrite material with aging condition for 30,000h at 400degC. (author)

  7. Effects of cooling method after intercritical heat treatment on microstructural characteristics and mechanical properties of as-cast high-strength low-alloy steel

    International Nuclear Information System (INIS)

    Highlights: • The effect of cooling method after intercritical heat treatment on microstructure evolution was investigated. • Fracture mechanism of tensile and impact after different intercritical heat treatment has been analyzed. • The crack initiation and propagation after different intercritical heat treatment was compared in details. - Abstract: The effect of cooling method after intercritical heat treatment on the microstructures and mechanical properties of as-cast steel produced by electroslag casting was investigated. The microstructure characteristics were analyzed by optical microscope (OM), scanning electron microscope (SEM), transmission electron microscopy (TEM) and electron back scatter diffraction (EBSD). The mechanical performance was evaluated by tensile testing at ambient temperature and Charp V-notch impact tests at various temperatures (−40 °C, −20 °C, 20 °C). The tensile and impact fracture micromechanisms were discussed in details. The results of microstructure investigation indicated that water cooling after intercritical heat treatment led to a mixed microstructure of ferrite and tempered martensite, while a composite microstructure of ferrite and tempered bainite was obtained after air cooling. The carbides of Cr, Mo and Nb in matrix after water quenching were finer than the ones after air cooling. Compared with water cooling, a good balance of strength and toughness was obtained after air cooling. The crack propagation path in the steel after water cooling can propagate along the long axis direction of ferrite bands, directly across the intersecting banded ferrite and martensite as well as along the interfaces between ferrite and martensite. However, the crack propagation path in the steel after air cooling depends on the shape, size and distribution of M/A islands

  8. Mathematical Modeling on the Growth and Removal of Non-metallic Inclusions in the Molten Steel in a Two-Strand Continuous Casting Tundish

    Science.gov (United States)

    Ling, Haitao; Zhang, Lifeng; Li, Hong

    2016-10-01

    In the current study, mathematical models were developed to predict the transient concentration and size distribution of inclusions in a two-strand continuous casting tundish. The collision and growth of inclusions were considered. The contribution of turbulent collision and Stokes collision was evaluated. The removal of inclusions from the top surface was modeled by considering the properties of inclusions and the molten steel, such as the wettability, density, size, and interfacial tension. The effect of composition of inclusions on the collision of inclusions was included through the Hamaker constant. Meanwhile, the effect of the turbulent fluctuation velocity on the removal of inclusions at the top surface was also studied. Inclusions in steel samples were detected using automatic SEM Scanning so that the amount, morphology, size, and composition of inclusions were achieved. In the simulation, the size distribution of inclusions at the end steel refining was used as the initial size distribution of inclusions at tundish inlet. The equilibrium time when the collision and coalescence of inclusions reached the steady state was equal to 3.9 times of the mean residence time. When Stokes collision, turbulent collision, and removal by floating were included, the removal fraction of inclusions was 16.4 pct. Finally, the removal of solid and liquid inclusions, such as Al2O3, SiO2, and 12CaO·7Al2O3, at the interface between the molten steel and slag was studied. Compared with 12CaO·7Al2O3 inclusions, the silica and alumina inclusions were much easier to be removed from the molten steel and their removal fractions were 36.5 and 39.2 pct, respectively.

  9. Mathematical Modeling on the Growth and Removal of Non-metallic Inclusions in the Molten Steel in a Two-Strand Continuous Casting Tundish

    Science.gov (United States)

    Ling, Haitao; Zhang, Lifeng; Li, Hong

    2016-07-01

    In the current study, mathematical models were developed to predict the transient concentration and size distribution of inclusions in a two-strand continuous casting tundish. The collision and growth of inclusions were considered. The contribution of turbulent collision and Stokes collision was evaluated. The removal of inclusions from the top surface was modeled by considering the properties of inclusions and the molten steel, such as the wettability, density, size, and interfacial tension. The effect of composition of inclusions on the collision of inclusions was included through the Hamaker constant. Meanwhile, the effect of the turbulent fluctuation velocity on the removal of inclusions at the top surface was also studied. Inclusions in steel samples were detected using automatic SEM Scanning so that the amount, morphology, size, and composition of inclusions were achieved. In the simulation, the size distribution of inclusions at the end steel refining was used as the initial size distribution of inclusions at tundish inlet. The equilibrium time when the collision and coalescence of inclusions reached the steady state was equal to 3.9 times of the mean residence time. When Stokes collision, turbulent collision, and removal by floating were included, the removal fraction of inclusions was 16.4 pct. Finally, the removal of solid and liquid inclusions, such as Al2O3, SiO2, and 12CaO·7Al2O3, at the interface between the molten steel and slag was studied. Compared with 12CaO·7Al2O3 inclusions, the silica and alumina inclusions were much easier to be removed from the molten steel and their removal fractions were 36.5 and 39.2 pct, respectively.

  10. Effect of hot rolling reduction on microstructure, texture and ductility of strip-cast grain-oriented silicon steel with different solidification structures

    International Nuclear Information System (INIS)

    Grain-oriented silicon steel as-cast strips with the average ferrite grain sizes of 161 μm and 367 μm were produced by twin-roll strip casting. Then the as-cast strips were reheated and hot rolled with different reductions of 5–50%. The microstructure and texture evolution were investigated by optical microscopy, X-ray diffraction, and electron backscattered diffraction methods. The elongations of the hot rolled strips were examined by the tensile tests and the fracture surfaces were observed by scanning electron microscope. It was found that the microstructure of both as-cast strips consisted of ferrite and martensite. The microstructure of all the hot rolled strips was composed of ferrite and pearlite and it was gradually refined with increasing hot rolling reduction in spite of different initial solidification structures. The hot rolled fine-grained strips showed much finer microstructure at the same hot rolling reduction and thus gave rise to higher elongations. A total reduction of more than 30% was required for the fine-grained strips to achieve relatively good ductility, while that for the coarse-grained strips was as high as 50%. With increasing hot rolling reduction, α and γ fibre textures were gradually enhanced at the expense of initial {001}〈0vw〉 fibre texture in all the hot rolled strips. Relatively strong Goss texture only evolved in the 50% hot rolled strips in spite of the different initial solidification structures, though the 50% hot rolled coarse-grained strip showed much stronger Goss texture

  11. Effect of hot rolling reduction on microstructure, texture and ductility of strip-cast grain-oriented silicon steel with different solidification structures

    Energy Technology Data Exchange (ETDEWEB)

    Song, Hong-Yu; Liu, Hai-Tao, E-mail: liuht@ral.neu.edu.cn; Lu, Hui-Hu; Li, Hao-Ze; Liu, Wen-Qiang; Zhang, Xiao-Ming; Wang, Guo-Dong

    2014-05-01

    Grain-oriented silicon steel as-cast strips with the average ferrite grain sizes of 161 μm and 367 μm were produced by twin-roll strip casting. Then the as-cast strips were reheated and hot rolled with different reductions of 5–50%. The microstructure and texture evolution were investigated by optical microscopy, X-ray diffraction, and electron backscattered diffraction methods. The elongations of the hot rolled strips were examined by the tensile tests and the fracture surfaces were observed by scanning electron microscope. It was found that the microstructure of both as-cast strips consisted of ferrite and martensite. The microstructure of all the hot rolled strips was composed of ferrite and pearlite and it was gradually refined with increasing hot rolling reduction in spite of different initial solidification structures. The hot rolled fine-grained strips showed much finer microstructure at the same hot rolling reduction and thus gave rise to higher elongations. A total reduction of more than 30% was required for the fine-grained strips to achieve relatively good ductility, while that for the coarse-grained strips was as high as 50%. With increasing hot rolling reduction, α and γ fibre textures were gradually enhanced at the expense of initial {001}〈0vw〉 fibre texture in all the hot rolled strips. Relatively strong Goss texture only evolved in the 50% hot rolled strips in spite of the different initial solidification structures, though the 50% hot rolled coarse-grained strip showed much stronger Goss texture.

  12. Multi-layers castings

    Directory of Open Access Journals (Sweden)

    J. Szajnar

    2010-01-01

    Full Text Available In paper is presented the possibility of making of multi-layers cast steel castings in result of connection of casting and welding coating technologies. First layer was composite surface layer on the basis of Fe-Cr-C alloy, which was put directly in founding process of cast carbon steel 200–450 with use of preparation of mould cavity method. Second layer were padding welds, which were put with use of TIG – Tungsten Inert Gas surfacing by welding technology with filler on Ni matrix, Ni and Co matrix with wolfram carbides WC and on the basis on Fe-Cr-C alloy, which has the same chemical composition with alloy, which was used for making of composite surface layer. Usability for industrial applications of surface layers of castings were estimated by criterion of hardness and abrasive wear resistance of type metal-mineral.

  13. PECULIARITIES OF METALLOGRAPHIC RESEARCHES OF STRUCTURE OF CAST METAL FROM WASTE OF HIGH-SPEED STEEL P6M5

    Directory of Open Access Journals (Sweden)

    A. L. Valko

    2014-01-01

    Full Text Available Techniques metallographic researches of structure and definition of size of grain of tool steels are offered. The structure of the fast-cutting steel received by a method electroslag remelting from a waste of tool manufacture is investigated.

  14. Clean forming of stainless steel and titanium products by lubricious oxides

    DEFF Research Database (Denmark)

    Heikkilä, Irma; Wadman, Boel; Thoors, Håkan;

    2012-01-01

    to industrial forming processes. Preliminary evaluations show a beneficial influence of two oxides types, on stainless steel and on titanium. More work is needed to test the lubricating effect in other forming operations and to analyse the sustainability aspects for products manufactured with this alternative....... One possible method to overcome these problems is to use an oxide layer with optimised properties to reduce friction during forming, either as a substitute to lubricants, or acting as a conversion layer for environmental friendly lubricants. The most beneficial group of oxides for low friction...... is called lubricious oxides with a rutile crystal structure. Oxides of Ti, Mo, V, and Zn can build rutiles under certain contact temperatures during rolling and forming. The aim of this investigation is to evaluate if oxides designed on metal sheets display a lubricious effect under conditions similar...

  15. ELECTROCHEMICAL STUDIES ON THE CORROSION OF CARBON STEEL IN OXALIC ACID CLEANING SOLUTIONS

    Energy Technology Data Exchange (ETDEWEB)

    Wiersma, B; John Mickalonis, J

    2007-10-08

    The Savannah River Site (SRS) will disperse or dissolve precipitated metal oxides as part of radioactive waste tank closure operations. Previously SRS has utilized oxalic acid to accomplish this task. Since the waste tanks are constructed of carbon steel, a significant amount of corrosion may occur. Although the total amount of corrosion may be insignificant for a short contact time, a significant amount of hydrogen may be generated due to the corrosion reaction. Linear polarization resistance and anodic/cathodic polarization tests were performed to investigate the corrosion behavior during the process. The effect of process variables such as temperature, agitation, aeration, sample orientation, light as well as surface finish on the corrosion behavior were evaluated. The results of the tests provided insight into the corrosion mechanism for the iron-oxalic acid system.

  16. Oxidation of Slurry Aluminide Coatings on Cast Stainless Steel Alloy CF8C-Plus at 800oC in Water Vapor

    Energy Technology Data Exchange (ETDEWEB)

    Haynes, James A [ORNL; Armstrong, Beth L [ORNL; Dryepondt, Sebastien N [ORNL; Kumar, Deepak [ORNL; Zhang, Ying [Tennessee Technological University

    2013-01-01

    A new, cast austenitic stainless steel, CF8C-Plus, has been developed for a wide range of high temperature applications, including diesel exhaust components, turbine casings and turbocharger housings. CF8C-Plus offers significant improvements in creep rupture life and creep rupture strength over standard CF8C steel. However, at higher temperatures and in more aggressive environments, such as those containing significant water vapor, an oxidation-resistant protective coating will be necessary. The oxidation behavior of alloys CF8C and CF8C-Plus with various aluminide coatings were compared at 800oC in air plus 10 vol% water vapor. Due to their affordability, slurry aluminides were the primary coating system of interest, although chemical vapor deposition (CVD) and pack cementation coatings were also compared. Additionally, a preliminary study of the low cycle fatigue behavior of aluminized CF8C-Plus was conducted at 800oC. Each type of coating provided substantial improvements in oxidation behavior, with simple slurry aluminides showing very good oxidation resistance after 4,000 h testing in water vapor. Preliminary low cycle fatigue results indicated that thicker aluminide coatings degraded high temperature fatigue properties of CF8C-Plus, whereas thinner coatings did not. Results suggest that appropriately designed slurry aluminide coatings are a viable option for economical, long-term oxidation protection of austenitic stainless steels in water vapor.

  17. The influence of martensitic transformation on mechanical properties of cast high alloyed CrMnNi-steel under various strain rates and temperatures

    International Nuclear Information System (INIS)

    Metastable austenitic steels show excellent mechanical properties, such as high strength combined with excellent ductility and toughness due to martensitic transformation under mechanical loading (transformation induced plasticity effect). A good energy consumption, and, in the case of high-alloyed metastable austenitic steels, a high corrosion resistance, increase the potential of these materials for diverse applications, also in regard of safety requirements. Up to now, numerous wrought alloys were investigated concerning mechanical behaviour, TRIP-effect, martensitic transformation behaviour and modelling of transformation kinetics or stress-strain behaviour. New high alloyed cast CrMnNi-steels, developed at Technical University Bergakademie Freiberg, provide the chance to reduce processing steps, production time and costs. In order to understand the influence of temperature on the martensitic phase transformation behaviour and therefore on mechanical properties and failure, the mechanical response under tensile loading in a temperature range between -700C and 2000C was investigated. The mechanical behaviour under compressive loading was also examined in a wide range of strain rates between 10-4 s-1 and 103 s-1 to obtain information about the strain rate effect on stress-strain behaviour and microstructural changes.

  18. Analysis of Brittleness for Ferritic Stainless Steel 430 As-cast%430铁素体不锈钢铸件脆性分析

    Institute of Scientific and Technical Information of China (English)

    周灿旭; 师红旗; 陈育贵; 丁毅

    2009-01-01

    对430铸造铁素体不锈钢的脆性进行了分析,采用金相显微组织分析、力学性能测试、冲击断口宏观和SEM等技术手段探讨了430不锈钢发生脆化的原因.结果表明:430铸造铁素体不锈钢的脆性主要是由铸造过程中马氏体的生成引起的,通过700℃热处理水冷可以显著提高430铸造铁索体不锈钢的韧性,并同时改善其抗拉强度和塑性.%The brittleness of ferritic stainless steel 430 as-east was analyzed by metaUographic microscope, mechanical properties test, macroscope ffactography and SEM. The results show that the brittleness of ferritic stainless steel 430 as-cast is caused by martensite. The toughness of 430 ferritic stainless steel increases obviously through 700 ℃ heat treatment, while the tensile strength and ductility properties also improves.

  19. Penetration of tritium (as tritiated water vapour) into low carbon steel and remediation using abrasive cleaning

    International Nuclear Information System (INIS)

    The UKAEA Winfrith site is in a phase of accelerated decommissioning and de-licensing which will generate significant volumes of metal wastes some of which may be suitable for disposal as exempt wastes. If contamination is present, it is often confined within the surface layers of the metal. The UKAEA Winfrith site operates a shot-blast facility (WACM) that removes paint and surface contamination from low carbon steel enabling surface contaminated painted metal to be processed and therefore certified as exempt. A study was conducted to determine whether tritium (as tritiated water vapour) has penetrated into the metal to levels exceeding the Radioactive Substances Act (1993), Substances of Low Activity (SoLA) Exemption Order criteria, and whether processing via the WACM removes sufficient tritium contamination that the SoLA Exemption Order criteria can be met. The results of sampling and analysis show that the tritium is mainly held in the paint or outer 40 μm layer of the metal and that processing through the WACM removes these layers along with sufficient tritium to meet the SoLA Exemption Order criteria

  20. 华南地区浇筑式钢桥面铺装MA性能研究%PERFORMANCE STUDY ON CASTING-TYPE STEEL BRIDGE DECK MIXTURE MA

    Institute of Scientific and Technical Information of China (English)

    万涛涛

    2012-01-01

    浇筑式桥面铺装方案MA是当前钢桥面铺装应用较为广泛的一种铺装方案,然而该铺装方案在我国华南地区应用状况却不是很好.由于目前仍然没有标准的MA混合料设计规范,而MA由于其较小的孔隙率都具有较好的水稳定性.通过大量调查发现MA混凝土在我国华南地区应用的主要破坏形式是车辙和疲劳开裂.通过硬度值、马歇尔试验和车辙试验研究了MA的高温性能,采用四点弯曲试验研究了MA混合料的疲劳性能,结果表明通过调整MA混合料的级配可以改善MA的高温性能和疲劳性能,最后通过试验路段得到验证.%Casting type steel bridge deck pavement scheme MA is a wide range used plan Of the current steel bridge deck pavement, yet its application situation in China is not very well. According to the investigation of our country's steel bridge deck applications, the study found the main damage forms of south china steel bridge deck pavement is the rutting and fatigue cracking. Research the high temperature performance of MA through the hardness value test, Marshall test and rutting test. Research the fatigue performance of MA through four points bending test. The results show that by adjusting the MA mixture graded can improve the performance of high temperature and fatigue performance of MA.

  1. Modeling of primary dendrite arm spacing variations in thin-slab casting of low carbon and low alloy steels

    OpenAIRE

    Mehrara, H; Santillana, B; Eskin, DG; Boom, R; Katgerman, L; Abbel, G

    2011-01-01

    Solidification structure of a High Strength Low Alloy (HSLA) steel, in terms of dendrite arm spacing distribution across the shell thickness, is studied in a breakout shell from a thin-slab caster at Tata Steel in IJmuiden. Columnar dendrites were found to be the predominant morphology throughout the shell with size variations across the shell thickness. Primary Dendrite Arm Spacing (PDAS) increases by increasing the distance from meniscus or slab surface. Subsequently, a model is proposed to...

  2. Characterization of microstructure, texture and magnetic properties in twin-roll casting high silicon non-oriented electrical steel

    Energy Technology Data Exchange (ETDEWEB)

    Li, Hao-Ze; Liu, Hai-Tao, E-mail: liuht@ral.neu.edu.cn; Liu, Zhen-Yu, E-mail: zyliu@mail.neu.edu.cn; Lu, Hui-Hu; Song, Hong-Yu; Wang, Guo-Dong

    2014-02-15

    An Fe-6.5 wt.% Si-0.3 wt.% Al as-cast sheet was produced by twin-roll strip casting process, then treated with hot rolling, warm rolling and annealing. A detailed study of the microstructure and texture evolution at different processing stages was carried out by optical microscopy, X-ray diffraction and electron backscattered diffraction analysis. The initial as-cast strip showed strong columnar grains and pronounced < 001 >//ND texture. The hot rolled and warm rolled sheets were characterized by large amounts of shear bands distributed through the thickness together with strong < 110 >//RD texture and weak < 111 >//ND texture. After annealing, detrimental < 111 >//ND texture almost disappeared while beneficial (001)<210 >, (001)<010 >, (115)<5 − 10 1 > and (410) < 001 > recrystallization textures were formed, thus the magnetic induction of the annealed sheet was significantly improved. The recrystallization texture in the present study could be explained by preferred nucleation and grain growth mechanism. - Highlights: • A high silicon as-cast strip with columnar structure was produced. • A thin warm rolled sheet without large edge cracks was obtained. • Microstructure and texture evolution at each stage were investigated. • Beneficial (001)<210 >, (001)<010 >, (410)<001 > recrystallization textures were formed. • The magnetic induction of annealed sheet was significantly improved.

  3. Research on Wear Behavior of 3Cr3Mo2V Cast Steel and 3Cr13 Steel%3Cr3Mo2V铸钢和3Cr13钢磨损行为的研究

    Institute of Scientific and Technical Information of China (English)

    茅奕舒; 崔向红; 王树奇; 李冬生

    2012-01-01

    采用销盘式磨损试验机对3Cr3Mo2V铸钢和3Cr13钢在环境温度25℃和200℃下进行干滑动磨损试验,研究了显微组织和摩擦氧化物对3Cr3Mo2V铸钢和3Cr13钢磨损行为的影响,并探讨其磨损机制.结果表明:摩擦氧化物对25℃和200℃下的磨损行为和磨损机制有显著的影响,而摩擦氧化物的减磨作用取决于其数量和基体状态等,与钢的成分和显微组织密切相关.高的铬含量阻碍摩擦氧化物的形成,低硬度的回火索氏体加速氧化物剥落,故无摩擦氧化物的作用或作用降低.%Dry sliding wear tests were performed for 3Cr3Mo2V cast steel and 3Crl3 steel at 25℃ and 200 ℃ on a pin-on-disk wear tester. The effect of microstructures and tribo-oxides on the wear behavior of 3Cr3Mo2V cast steel and 3Cr13 steel was probed into and the wear mechanism was also discussed. The results show that tribo-oxides exert a significant influence on wear behavior and mechanism, and the wear reducing effect of tribo-oxides depends on their amount and substrate state that is closely related with the compositions and microstructures of the steel. High Cr content impedes the formation of tribo-oxides and tempered sorbite with low hardness accelerates the stripping of tribo-oxides, thus, the wear reducing effect of tribo-oxides is destroyed or reduced.

  4. Analysis on the Deflection Angle of Columnar Dendrites of Continuous Casting Steel Billets Under the Influence of Mold Electromagnetic Stirring

    Science.gov (United States)

    Wang, Xincheng; Wang, Shengqian; Zhang, Lifeng; Sridhar, Seetharaman; Conejo, Alberto; Liu, Xuefeng

    2016-11-01

    In the current study, the deflection angle of columnar dendrites on the cross section of steel billets under mold electromagnetic stirring (M-EMS) was observed. A mathematical model was developed to define the effect of M-EMS on fluid flow and then to analyze the relationship between flow velocities and deflection angle. The model was validated using experimental data that was measured with a Tesla meter on magnetic intensity. By coupling the numerical results with the experimental data, it was possible to define a relationship between the velocities of the fluid with the deflection angle of high-carbon steel. The deflection angle of high-carbon steel reached maximum values from 18 to 23 deg for a velocity from 0.35 to 0.40 m/s. The deflection angles of low-carbon steel under different EM parameters were discussed. The deflection angle of low-carbon steel was increased as the magnetic intensity, EM force, and velocity of molten steel increased.

  5. Sigma-phase formation in weldments of cast super duplex stainless steel; Formacion de fase sigma en uniones soldadas de acero inoxidable super duplex fundido

    Energy Technology Data Exchange (ETDEWEB)

    Garin, J. L.; Mannheim, R. L.; Camus, M. A.

    2011-07-01

    This paper describes the microstructural characteristics of weldments of cast super duplex stainless steel (J93404), being subjected to annealing processes to induce formation of sigma-phase at high temperatures. The influence of heating time at 1073 K, 1123 K and 1173 K upon precipitation of sigma in the heat affected zone, base metal and fusion zone of the weldments was analyzed. The experimental results revealed the formation of this intermetallic compound throughout decomposition of the ferritic phase into austenite and sigma. At earlier stages of the transformation the phase rapidly nucleates and growth along the ferrite-austenite grain boundaries, and then massively advances towards the bulk of the ferritic zone with greater effectiveness as temperature increases. The formation of sigma-phase in all weldments resembles the Johnson-Mehl-Avramis mechanism stated for nucleation and growth. (Author) 27 refs.

  6. 铸钢叉车用桥壳的质量控制%Quality Control of Folk Lifter Axle Housing Steel Casting

    Institute of Scientific and Technical Information of China (English)

    张奕麟; 刘伟

    2011-01-01

    针对叉车用铸钢桥壳的质量问题,如裂纹、气孔等缺陷,通过在配料和熔炼工艺,造型、制芯及合箱等方面加以控制,使得铸钢桥壳的质量大为改善。同时制定了铸钢桥壳缺陷允许焊补的条例,规范了铸件缺陷处理。%With the modification on molding, core making and mould assembling process, the quality of folk lifter axle housing steel casting has been improved especially for crack, porosity and other defects. The guideline of repair welding for axle housing also has been defined in to keep consistency of repairing.

  7. Impacts on CO{sub 2} emission allowance of EU emission trading scheme (ETS) in a Swedish steel plant by clean development mechanism (CDM)

    Energy Technology Data Exchange (ETDEWEB)

    Wang, C.; Dahl, J. [Lulea Univ. of Technology, Lulea (Sweden). Division of Energy Engineering; Larsson, M. [MEFOS, Lulea (Sweden). Metallurgical Research Institute AB; Yan, J. [Lulea Univ. of Technology, Lulea (Sweden). Division of Energy Engineering]|[Malarden Univ., Vesteras (Sweden). Dept. IST

    2005-07-01

    This study examined the optimum solutions for steel mills in the European Union Emission Trading Scheme (ETS) to meet their emission allowance with low reduction cost. The study developed a computer-based optimization model that was used as part of a case study in a Swedish steel plant. The model used three different scenarios, including internal changes in the steel plant, allowance purchases via the Emission Trading Scheme, and buying credits through the Kyoto Protocol's Clean Development Mechanism (CDM). The model was used to simulate carbon dioxide emission in order to determine which solution offers the lowest cost coupled with high emission reduction. It was concluded that internal changes and the CDM scenarios will both contribute to assisting the Swedish plant to meet the emission trading allowance and Kyoto Protocol commitments. It was also concluded that the plant will face a carbon dioxide emission reduction burden from the third year of ETC onward. 14 refs., 8 tabs., 4 figs.

  8. Effect of double quenching and tempering heat treatment on the microstructure and mechanical properties of a novel 5Cr steel processed by electro-slag casting

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Jian, E-mail: healygo@163.com; Yu, Hao, E-mail: yuhao@ustb.edu.cn; Zhou, Tao, E-mail: zhoutao130984@163.com; Song, Chenghao, E-mail: songchenghao28@126.com; Zhang, Kai, E-mail: zhangkai8901@126.com

    2014-12-01

    The effect of double quenching and tempering (DQT) treatment as well as conventional high temperature quenching and tempering (CQT) treatment on the microstructures and mechanical properties of low carbon 5Cr martensitic as cast steel produced by electroslag casting was investigated. The microstructure changes were characterized by optical microscope (OM), scanning electron microscope (SEM), electron back scatter diffraction (EBSD) and transmission electron microscopy (TEM). The characteristics of carbides precipitated during tempering were analyzed on both carbon extraction replica and thin foil samples by TEM. The mechanical performance was evaluated by Vickers hardness test, tensile test, and Charpy V-notch impact test at ambient temperature. The results of microstructure study indicated that DQT treatment led to a finer microstructure than that of CQT. The carbides of the tempered samples were identified as M{sub 7}C{sub 3}. The carbides along the prior austenite grain boundaries nucleated directly while those within the laths should be transformed from cementite which formed at the early tempering stage. Compared with CQT condition, yield strength slightly increased after DQT treatment, and impact toughness improved a lot. The strengthening mechanisms were analyzed and it was found that grain refining and precipitation strengthening were mainly responsible for the increase of strength. The superior toughness of DQT condition was attributed to the finer microstructure resulting in more frequent deflections of the cleavage crack and the smaller size of carbides along the prior austenite boundaries. EBSD analysis showed that both martensitic block and packet of low carbon 5Cr tempered martensitic steel could hinder crack propagation, while the latter was more effective.

  9. Effect of double quenching and tempering heat treatment on the microstructure and mechanical properties of a novel 5Cr steel processed by electro-slag casting

    International Nuclear Information System (INIS)

    The effect of double quenching and tempering (DQT) treatment as well as conventional high temperature quenching and tempering (CQT) treatment on the microstructures and mechanical properties of low carbon 5Cr martensitic as cast steel produced by electroslag casting was investigated. The microstructure changes were characterized by optical microscope (OM), scanning electron microscope (SEM), electron back scatter diffraction (EBSD) and transmission electron microscopy (TEM). The characteristics of carbides precipitated during tempering were analyzed on both carbon extraction replica and thin foil samples by TEM. The mechanical performance was evaluated by Vickers hardness test, tensile test, and Charpy V-notch impact test at ambient temperature. The results of microstructure study indicated that DQT treatment led to a finer microstructure than that of CQT. The carbides of the tempered samples were identified as M7C3. The carbides along the prior austenite grain boundaries nucleated directly while those within the laths should be transformed from cementite which formed at the early tempering stage. Compared with CQT condition, yield strength slightly increased after DQT treatment, and impact toughness improved a lot. The strengthening mechanisms were analyzed and it was found that grain refining and precipitation strengthening were mainly responsible for the increase of strength. The superior toughness of DQT condition was attributed to the finer microstructure resulting in more frequent deflections of the cleavage crack and the smaller size of carbides along the prior austenite boundaries. EBSD analysis showed that both martensitic block and packet of low carbon 5Cr tempered martensitic steel could hinder crack propagation, while the latter was more effective

  10. Influence of regenerative heat treatment on structure and properties of G20CrMo2 - 5 (L20HM cast steel

    Directory of Open Access Journals (Sweden)

    G. Golański

    2008-03-01

    Full Text Available Thc papcr prcscnts rcsuSts or rcscarch on thc influence of rcgcncratic hcat treatment on thc structurc and propcrtics [hardncss. impactcncrgy or L2O11M cnst stccl. Invcstipatcd material was taken from outer fmmc of a turbinc which was scrviccd for t 67 424 hours a! thctcmpcrauirc or 535 "C and prcssurc or 12.75 MPa. In psi-operating condition ~hicnv cstigntcd cast steel was cl~aracteri~cbdy low impactcncrpy of II I ant1 hart3ncss of 139HV30. Analysis uF the irlflue~~uuel ;lustcniriz;~ti on pariimctcrs (tcrnpcr;lturc and lime has rcvealcd rhntat thc tcinpcr;~turcr angc o f 895 + 955 "C (i-e. h3 - +I IO + 70 "C.fo r both 3 and 5 hours of holtl timc. rhc ohtaincd grain sizc amounls to 20+ 2511m. I has hccn pmved that tempcred bainitic-rcrri~ica nd remit ic-hainiric-pearlit ic stn~cturco f thc invcstigatcd cast stccl msurcs highimpact cncrgy, i.c. KV > 1001. as well a5 hardncss. i.e. 11Y30. just at thc tcrnpcmturc of OXl "C. 'I'crnpcmliirc or 7110 "C causcs i'~tnhcrincrclrsc of impact cncrgy along with a slight dccrcasc of hardncss. Morcovcr. it has hccn concludd that nppl ying oS under-annealinginstcad or tcmpcring. nflcr standardizalion. guarantees scquircd impact cncrgy of KY r 271.

  11. Production of Steel Casts in Two-Layer Moulds with Alkaline Binders Part 1. Backing sand with the alkaline inorganic binder RUDAL

    Directory of Open Access Journals (Sweden)

    M. Holtzer

    2011-04-01

    Full Text Available Steel casts in Z.N. POMET were produced in moulds made of the moulding sand Floster. This sand did not have good knocking outproperties, required a significant binder addition (4.5-5.0 parts by weight, and the casting surface quality gave rise to clients objections.Therefore a decision of implementing two-layer moulds, in which the facing sand would consist of the moulding sand with an alkalineorganic binder while the backing sand would be made of the moulding sand with an inorganic binder also of an alkaline character - wasundertaken. The fraction of this last binder in the moulding sand mass would be smaller than that of the binder used up to now (waterglass. The application of two moulding sands of the same chemical character (highly alkaline should facilitate the reclamation processand improve the obtained reclaimed material quality, due to which it would be possible to increase the reclaim fraction in the mouldingsand (up to now it was 50%. The results of the laboratory investigations of sands with the RUDAL binder are presented in the paper.

  12. Industrial application of stainless steel soft-contacting electromagnetic continuous casting%不锈钢软接触电磁连铸的工业试验

    Institute of Scientific and Technical Information of China (English)

    侯晓光; 王恩刚; 张永杰; 许秀杰; 邓安元

    2015-01-01

    The technology of soft-contacting electromagnetic continuous casting(SCEMCC)had been developed for sev-eral decades. However,it still needs to find a right point for commercial applications. throug analyzing the different of re-sistivity characteristics between stainless steel and carbon steels,and the pilot experimental results of 304 round billet SCEMCC,the feasibility of stainless steel SCEMCC was confirmed. Then,the new systems of round billet and square bil-let SCEMCC were developed respectively for industrial production experiments with different stainless steel grades and mold flux powders. The industrial production experimental result shows that the SCEMCC systems were effective and reli-able to reduce the depth of almost all billet oscillation marks from about 0.7 mm to near zero,under the condition of 150 kW output power to the electromagnetic casting mold. Using obtained SCEMCC billets for milling ϕ8 mm steel wire rod products,then processing with solution heat treatment and acid pickling,the material yield of end wire rod products can be increased more than 3%. Many times industrial continuous casting production experiments,in which the phenomenas of meniscus abnormal fluctuation and slag entrapped defects of billet macro structure were not being found,promoted SCEMCC taking a key step on business operation. Finally,the feasibility of SCEMCC from the billet section expending to the slab was discussed.%通过分析碳钢和不锈钢材质的电阻率差异性,以及304不锈钢软接触电磁连铸的中试试验结果,证实了不锈钢软接触电磁连铸的可行性。进而,在商业级规模铸机上分别开发了不锈钢圆坯和方坯软接触电磁连铸系统,进行了不同钢种、不同保护渣条件下的相关工业生产试验。结果表明,不锈钢圆坯和方坯软接触电磁连铸在不超过150 kW的电源输出功率条件下,均能获得较佳的振痕去除效果,改善铸坯表面质量。对获得的铸

  13. Development Tendency of the Refractories for Iron & Steel Industry in China

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    This paper introduces the developing tendency of refractories for iron and steel industry combined with the new metallurgical techniques applied in iron and steel industry in China. Refractories for blast furnace long service life, smelting reduction iron-making process, secondary refining metallurgies and clean steel making, near net shape continuous casting are described respectively. To meet the requirement of iron and steel industry, the high quality, multi-functions and environment-friendly refractories with long service life will be focused and developed in the future. In addition, high grade refractories in China have great developing space and potential market.

  14. Effects of warm temper rolling on microstructure, texture and magnetic properties of strip-casting 6.5 wt% Si electrical steel

    Energy Technology Data Exchange (ETDEWEB)

    Li, Hao-Ze [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Liu, Hai-Tao, E-mail: liuht@ral.neu.edu.cn [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Liu, Yi [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Liu, Zhen-Yu, E-mail: zyliu@mail.neu.edu.cn [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Cao, Guang-Ming [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Luo, Zhong-Han; Zhang, Feng-Quan; Chen, Sheng-Lin; Lyu, Li [National Engineering Research Center for Silicon Steel, Wuhan Iron and Steel (Group) Corp, Wuhan 430083 (China); Wang, Guo-Dong [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China)

    2014-12-15

    6.5 wt% Si electrical steel thin sheets were produced by a processing route including strip casting, hot rolling, warm rolling, intermediate annealing, warm temper rolling and final annealing, in which the warm temper rolling reduction varied from 2.7% to 14.4%. A detailed study of the microstructural and textural evolutions through the whole processing route was carried out by optical microscopy, X-ray diffraction and electron backscattered diffraction analysis. The findings revealed that the final recrystallization microstructure, texture and magnetic properties relied heavily on the warm temper rolling reduction. As the warm temper rolling reduction increased from 2.7% to 14.4%, the finally recrystallized microstructures were more homogeneous and the average grain size was decreased. At the warm temper rolling reduction lower than 7.0%, the occurrence of the exaggeratedly large annealing grains which dominated the whole sheet thickness resulted in strong 〈001〉//ND fiber, parallel α-fiber, 〈111〉//ND fiber and many other strong hard-magnetization texture components. By contrast, at the warm temper rolling reduction higher than 7.0%, the recrystallization textures were characterized by weak 〈001〉//ND fiber, parallel α-fiber, 〈111〉//ND texture, together with fewer and weak hard-magnetization texture components. The mechanism responsible for the finally microstructural and textural changes was explained by strain induced boundary migration. As warm temper rolling reduction increased, the magnetic properties at high frequency were gradually improved due to smaller grain sizes and more desirable textures. The highest magnetic inductions of 1.383 T (B{sub 8}), 1.484 T (B{sub 25}) and 1.571 T (B{sub 50}) in combination with the lowest iron losses at high frequencies of 19.11 W/Kg (W{sub 10/400}) and 3.824 W/Kg (W{sub 2/1000}) were obtained at 14.4% warm temper rolling reduction under the applied condition. - Highlights: • 6.5 wt% Si electrical steel

  15. The influence of chemical composition of the slags on the surface tension used in the continuous casting of steel

    Science.gov (United States)

    Gheorghiu, Csaba Attila; Ardelean, Erika; Heput, Teodor

    2016-06-01

    An important factor that can influence the surface quality of the continuous cast is the lubrication slag used in the crystallizer. The paper introduces the multiple 2nd degree correlations between the slags surface tension (dependent parameter) and its major oxides (independent parameters). The graphic correlations allow the determination of the variation limits for the independent parameters so as to range the values of the dependent parameters within a given domain.

  16. Characterisation of Q and T steel pole shoes manufactured by sand casting; Charakterisierung mit Sandguss hergestellter Polschuhe aus verguetetem Stahl

    Energy Technology Data Exchange (ETDEWEB)

    Asensio-Lozano, J.; Alvarez-Antolin, J.F. [Oviedo Univ. (Spain). Dept. of Materials Science and Metallurgical Engineering; Panta-Mesones, J.T. [National Univ. of Trujillo, La Libertad (Peru). Faculty of Mines, Metallurgy and Materials; Vander-Voort, G.F. [Buehler Ltd., Lake Bluff, IL (United States)

    2008-04-15

    This paper presents a study of the microstructural and mechanical characterization of the GS 35 CrMoV 10 4 alloy employed in the manufacture of sand-cast pole shoes for 4-pole synchronous electric power generators working at a frequency of 60 Hz. In addition, the most appropriate treatment for ensuring compliance with the technical specifications defined in DIN Standard No. 1.7755 has been designed. (orig.)

  17. Transient Two-Phase Flow in Slide-Gate Nozzle and Mold of Continuous Steel Slab Casting with and without Double-Ruler Electro-Magnetic Braking

    Science.gov (United States)

    Cho, Seong-Mook; Thomas, Brian G.; Kim, Seon-Hyo

    2016-10-01

    Transient mold flow could produce undesirable surface instabilities and slag entrainments, leading to the formation of defects during continuous slab casting of steel. In this work, two Large Eddy Simulations coupled with Discrete Phase Model are run, with and without MagnetoHydroDynamic model, to gain new insights into the surface variations of molten steel-argon gas flow with anisotropic turbulence in the slide-gate nozzle and the mold, with and without double-ruler Electro-Magnetic Braking (EMBr). The model calculations are validated with plant measurements, and applied to investigate the flow variations related to the slide gate on nozzle swirl, jet wobbling, and surface flow variations by quantifying the variations of velocity, horizontal angle, and vertical angle of the transient flow. Transient flow in the slide-gate nozzle bottom is almost always swirling, alternating chaotically between clockwise and counter-clockwise rotation. The clockwise swirl, caused by stronger flow down the same side of the nozzle as the open area near the Outside Radius side of the slide-gate middle plate, produces faster jet flow and higher velocity flow across the top surface of the mold. Counter-clockwise swirl produces slower jet and surface flow, but with more variations. The double-ruler EMBr decreases the asymmetry and duration of velocity variations during nozzle swirl flipping, resulting in less flow variations in the jet and across the surface in the mold.

  18. Transient Two-Phase Flow in Slide-Gate Nozzle and Mold of Continuous Steel Slab Casting with and without Double-Ruler Electro-Magnetic Braking

    Science.gov (United States)

    Cho, Seong-Mook; Thomas, Brian G.; Kim, Seon-Hyo

    2016-07-01

    Transient mold flow could produce undesirable surface instabilities and slag entrainments, leading to the formation of defects during continuous slab casting of steel. In this work, two Large Eddy Simulations coupled with Discrete Phase Model are run, with and without MagnetoHydroDynamic model, to gain new insights into the surface variations of molten steel-argon gas flow with anisotropic turbulence in the slide-gate nozzle and the mold, with and without double-ruler Electro-Magnetic Braking (EMBr). The model calculations are validated with plant measurements, and applied to investigate the flow variations related to the slide gate on nozzle swirl, jet wobbling, and surface flow variations by quantifying the variations of velocity, horizontal angle, and vertical angle of the transient flow. Transient flow in the slide-gate nozzle bottom is almost always swirling, alternating chaotically between clockwise and counter-clockwise rotation. The clockwise swirl, caused by stronger flow down the same side of the nozzle as the open area near the Outside Radius side of the slide-gate middle plate, produces faster jet flow and higher velocity flow across the top surface of the mold. Counter-clockwise swirl produces slower jet and surface flow, but with more variations. The double-ruler EMBr decreases the asymmetry and duration of velocity variations during nozzle swirl flipping, resulting in less flow variations in the jet and across the surface in the mold.

  19. Mold Simulator Study of the Initial Solidification of Molten Steel in Continuous Casting Mold: Part II. Effects of Mold Oscillation and Mold Level Fluctuation

    Science.gov (United States)

    Zhang, Haihui; Wang, Wanlin

    2016-04-01

    The surface quality of the continuous casting strands is closely related to the initial solidification of liquid steel in the vicinity of the mold meniscus, and thus the clear understanding of the behavior of molten steel initial solidification would be of great importance for the control of the quality of final slab. With the development of the mold simulator techniques, the complex interrelationship between the solidified shell surface profile, heat flux, shell thickness, mold level fluctuation, and the infiltrated slag film was well illustrated in our previous study. As the second part, this article investigated the effect of the mold oscillation frequency, stroke, and mold level fluctuation on the initial solidification of the molten steel through the conduction of five different experiments. Results suggested that in the case of the stable mold level, the oscillation marks (OMs) exhibit equally spaced horizon depressions on the shell surface, where the heat flux at the meniscus area raises rapidly during negative strip time (NST) period and the presence of each OMs on the shell surface is corresponding to a peak value of the heat flux variation rate. Otherwise, the shell surface is poorly defined by the existence of wave-type defects, such as ripples or deep depressions, and the heat flux variation is irregular during NST period. The rising of the mold level leads to the longer-pitch and deeper OMs formation; conversely, the falling of mold level introduces shorter-pitch and shallower OMs. With the increase of the mold oscillation frequency, the average value of the low-frequency heat flux at the meniscus increases; however, it decreases when the mold oscillation stroke increases. Additionally, the variation amplitude of the high-frequency temperature and the high-frequency heat flux decreases with the increase of the oscillation frequency and the reduction of the oscillation stroke.

  20. Effect of sigma phase precipitation on the mechanical and wear properties of Z3CN20.09M cast duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Y.Q.; Han, J.; Wu, H.C. [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology, Beijing (China); Yang, B., E-mail: byang@ustb.edu.cn [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology, Beijing (China); Wang, X.T. [State Key Laboratory for Advanced Metals and Materials, University of Science and Technology, Beijing (China)

    2013-06-15

    Highlights: ► The σ phase in the steel precipitated at a temperature range of 600–900 °C. ► The decomposition of α-ferrite into γ{sub 2} and σ phase in aged specimens is suggested. ► The tensile and yield strengths decreased first and then increased with aging time. ► The impact energy decreased slightly first but then drastically with aging time. ► The hardness and wear rates are not sensitive parameters to aged specimens. -- Abstract: The effect of sigma phase on the mechanical and wear properties of a Z3CN20.09M cast duplex stainless steel (CDSS) used in primary coolant pipe of nuclear power plants has been investigated. The experimental results showed that the sigma phase precipitated from ferrite at a temperature range of 600–900 °C. The tensile and yield strengths of the specimens aged at 700 °C decreased first and then increased with the increase of aging time. With increasing aging time, the impact energy of specimens decreased slightly before 4 h and then dropped drastically when aged a longer time more than 10 h. Fracture surface analysis showed that the hard and brittle sigma phase degraded the toughness of the aged steel. The hardness and wear resistance of the specimens aged for 1–4 h were lower than those of un-aged ones. However, the higher values of hardness and wear resistance were got in the specimens aged more than 10 h.

  1. Steel

    International Nuclear Information System (INIS)

    Composition of age hardening steel, % : Fe - (12.0-12.4) Cr - (2-2.7) Ni (0.5-0.6) Ti - (1.0-1.2) Mn - (0.03 - 0.04) C having high values of magnetoelastic internal friction and mechanical properties as well as an ability to operate under the conditions of alternating loadings are proposed. Damping properties of the steel permit to improve labour conditions. Data for the above steel on internal friction, impact strength and tensile properties are given

  2. Colour Metallography of Cast Iron

    Institute of Scientific and Technical Information of China (English)

    Zhou Jiyang; Liu Jincheng

    2010-01-01

    @@ Chapter 3 Spheroidal Graphite Cast Iron(I) Spheroidal Graphite Cast Iron, SG iron in short, refers to the cast iron in which graphite precipitates as spheroidal shape during solidification of liquid iron. The graphite in common commercial cast iron can only be changed from flake to spheroidal shape by spheroidising treatment. Since spheroidal graphite reduces the cutting effect of stress concentration, the metal matrix strength of SG iron can be applied around 70%-90%, thus the mechanical property of SG iron is significantly superior to other cast irons;even the tensile strength of SG iron is higher than that carbon steel.

  3. Research on strain fatigue behavior of ZG20SiMn cast steel%ZG20SiMn 铸钢的应变疲劳行为研究

    Institute of Scientific and Technical Information of China (English)

    李媛媛; 车欣; 李锋; 陈立佳

    2014-01-01

    为了深入理解 ZG20SiMn 铸钢在应变疲劳期间的循环变形及断裂行为,在应变控制模式下针对 ZG20SiMn 铸钢的疲劳行为进行了研究。结果表明,在应变控制的加载模式下,ZG20SiMn铸钢可表现为循环硬化和循环稳定特征,主要取决于外加总应变幅的高低,且其弹性应变幅、塑性应变幅与疲劳断裂时的载荷反向周次之间表现为单斜率线性行为。透射电镜分析结果表明, ZG20SiMn 的疲劳变形机制主要为波状滑移机制。扫描电镜分析结果表明,在不同的外加总应变幅下,疲劳裂纹均以穿晶方式萌生于 ZG20SiMn 铸钢试样表面,并以穿晶方式扩展。%In order to understand the cyclic deformation and fracture behaviors of ZG20SiMn cast steel,the fatigue behavior of ZG20SiMn cast steel was investigared under the strain-controlled mode.The experimental results show that under the strain-controlled loading mode,the ZG20SiMn cast steel can exhibit the cyclic strain hardening and cyclic stability,which mainly depends on the imposed total strain amplitude.For the ZG20SiMn cast steel,the relation between the reversals to failure and the elastic strain amplitude or plastic strain amplitude shows a single slope of linear behavior,respectively.The analysis results with transmission electron microscope (TEM)reveal that the fatigue deformation mechanism of ZG20SiMn cast steel is the wavy slip mechanism.The analysis results on the fatigue fracture surfaces of ZG20SiMn cast steel with scanning electron microscope (SEM)reveal that at different total strain amplitudes,the fatigue cracks initiate at the free surface of fatgiue specimen in a transgranular mode,and then propagate in a transgranular mode.

  4. Effect of inoculation on high temperature plastic properties of the centrifugally cast Cr-Ni-Nb steel

    Directory of Open Access Journals (Sweden)

    G. Tęcza

    2008-12-01

    Full Text Available From the centrifugally cast sleeve segments, in direction parallel to the axis, the specimens for mechanical tests were cut out in a way such as to get in one batch of the specimens a structure composed of columnar crystals and in another batch of the specimens a structure composed of equiaxial crystals. The specimens were subjected to a tensile test at the temperature of 820°C. It has been observed that the two zones of crystals differ quite considerably in the values of elongation, while preserving similar tensile strength levels.

  5. Effect of inoculation on high temperature plastic properties of the centrifugally cast Cr-Ni-Nb steel

    OpenAIRE

    G. Tęcza; Głownia, J.

    2008-01-01

    From the centrifugally cast sleeve segments, in direction parallel to the axis, the specimens for mechanical tests were cut out in a way such as to get in one batch of the specimens a structure composed of columnar crystals and in another batch of the specimens a structure composed of equiaxial crystals. The specimens were subjected to a tensile test at the temperature of 820°C. It has been observed that the two zones of crystals differ quite considerably in the values of elongation, while pr...

  6. Scheduling model of steelmaking-continuous casting processes in special steel plants%特殊钢厂炼钢-连铸调度模型

    Institute of Scientific and Technical Information of China (English)

    王闯; 刘青; 王彬; 王宝; 穆衍清; 谢飞鸣; 王柏琳; 卢新春; 张立强

    2013-01-01

    针对特殊钢厂的炼钢-连铸调度问题,建立了多目标调度模型.在模型求解过程中,对静态调度策略和动态调度策略进行了探讨.在静态调度部分,结合炼钢厂运行原则,并根据炼钢炉和连铸机作业周期的不同对应关系,对生产模式进行了分类,给出了相应的求解方法.在动态调度部分,给出了基于规则的动态调度策略以及具体的时间调整方法.最后,根据某转炉特殊钢厂的实际生产状况,在三台连铸机同时生产的情形下,对三个浇次的调度计划进行了仿真计算.通过与实际生产数据的比较,表明了所采用方法的有效性.%A multi-objective scheduling model was developed to solve the steelmaking-continuous casting scheduling problem of a special steel plant. Static scheduling and dynamic scheduling were investigated in the solving process of the model. The production modes in static scheduling were classified and the corresponding solving methods were formulated in combination with the running principles of steelmaking workshops and on the basis of the operation cycles of steelmaking furnaces and casters, while time-adjusting methods based on scheduling rules were described for the process of dynamic scheduling. A case in a BOF special steel plant, in which three casters are producing at the same time, was used to test the methods, and the scheduling plans of three casts were calculated and compared with actual production data. The comparison result indicates the validity of the methods.

  7. Casting Process Simulation and Optimization of High Manganese Steel Front Jockey Wheel%高锰钢前导轮铸造工艺模拟及优化

    Institute of Scientific and Technical Information of China (English)

    肖志霞; 郭建政; 董治中; 陈席国; 李萌蘖

    2013-01-01

    高锰钢前导轮内腔结构复杂,需要合理的铸造工艺以避免其内部产生铸造缺陷。为此,采用商业软件ProCAST对导轮轴孔处设一个明冒口的单冒口工艺(SR)和两个明冒口的双冒口工艺(DR)进行缺陷预测。计算发现,单冒口工艺(SR)的缺陷形成倾向低于双冒口的工艺(DR)。进而,通过调整单冒口工艺(SR)的冷铁形状、位置及增大轮缘处暗冒口体积,提出优化工艺M1;在M1基础上,通过减小轴孔处明冒口体积,并加大该处冒口保温砖厚度,提出优化工艺M2。模拟计算表明,采用M1和M2工艺均可消除导轮轮缘处的缩孔缩松缺陷;以M2的热裂倾向最小,热裂纹主要出现在前导轮内腔垂直拐角处和轴孔附近。%Casting process for high manganese steel front jockey wheel which has complicated inner chambers, shall be designed in reason to prevent casting defects in the chambers. Therefore, the casting processes, called SR (single riser) on one open riser and DR ( double riser) on two open risers on axle hole of front jockey wheel are simulated with casting software ProCAST in order to survey the defects. The simulation results indicate the defect-forming tendency of SR is lower than that of DR. Hence, basing on SR, a modified process, named M1 is proposed by adjusting the size and location of iron chills and increasing volume of blind riser around the wheel rim. Basing on M1, a further modified process named M2 is proposed by decreasing volume of open riser and increasing the wall thickness of insulating brick around the riser. The simulation shows both M1 and M2 can eliminate shrinkage porosities in front jockey wheel rim;in which M2 has the lowest heat cracking tendency. Heat cracks mainly appear at corner points in inner chambers and around axle hole of front jockey wheel.

  8. Usage of Thermodynamic Activity for Optimization of Power Expenses in Respect of Casting Process in Arc Steel-Melting Furnace

    Directory of Open Access Journals (Sweden)

    A. N. Chichko

    2006-01-01

    Full Text Available The equilibrium between carbon and oxygen has been investigated during oxidizing refining in an arc steel-melting furnace. It is shown that there is a possibility to apply an equilibrium thermodynamic. It has been established that during oxidizing refining FeO concentration in slag practically does not depend on C concentration in metal. It is demonstrated that in a number of cases metal carbon oxidation is characterized by the presence of a transit period that may be attributed to incomplete slag-formation process.

  9. Effects of V Addition on Microstructure and Hardness of Fe-C-B-Ni-V Hardfacing Alloys Cast on Steel Substrates

    Science.gov (United States)

    Rovatti, L.; Lemke, J. N.; Emami, A.; Stejskal, O.; Vedani, M.

    2015-12-01

    Fe-based hardfacing alloys containing high volume fraction of hard phases are a suitable material to be deposited as wear resistant thick coatings. In the case of alloys containing high amount of interstitial alloying elements, a key factor affecting the performance is dilution with the substrate induced by the coating process. The present research was focused on the analysis of V-bearing Fe-based alloys after calibrated carbon and vanadium additions (in the range from 3 to 5 wt.%) to a commercial Fe-C-B-Ni hardfacing alloy. Vanadium carbides with a petal-like morphology were observed in the high-V hypereutectic alloys allowing to reach hardness values above 700 HV. The solidification range shifted to higher temperatures with increasing amount of vanadium addition and in the case of hypereutectic alloys, the gap remains close to that of the original alloy. In the last step of the research, the microstructural evolution after dilution was analyzed by casting the V-rich alloys on a steel substrate. The dilution, caused by the alloying element diffusion and the local melting of the substrate, modified the microstructure and the hardness for a relevant volume fraction of the hardfacing alloys. In particular, the drop of interstitial elements induced the transition from the hypereutectic to the hypoeutectic microstructure and the formation of near-spherical V-rich carbides. Even after dilution, the hardness of the new alloys remained higher than that measured in the original Fe-C-B-Ni alloy.

  10. Microstructure of CrMnNi Cast Steel After Explosive-Driven Flyer-Plate Impact at Room Temperature and Below

    Science.gov (United States)

    Eckner, R.; Reichel, B.; Savinykh, A. S.; Krüger, L.; Razorenov, S. V.; Garkushin, G. V.

    2016-01-01

    A low-carbon metastable austenitic CrMnNi cast steel was investigated under shock conditions in a flyer-plate impact test. The samples were impacted by aluminum flyer-plates with impact velocities of 620 ± 30 m/s. Depending on deformation temperature and strain rate, the material exhibited different deformation mechanisms (dislocation glide, martensitic transformation, and mechanical twinning), which determined the microstructural evolution and mechanical behavior. Flyer-plate impact tests were carried out at 213 K and 293 K (-60 °C and +20 °C). A soft recovered sample revealed microstructural changes directly after impact. The subsequent microstructural investigations via light-optical microscopy and scanning electron microscopy revealed that transformation-induced plasticity (TRIP effect) was the primary deformation mechanism. Moreover, it was possible to quantify the martensite volume fraction by different methods and to identify the hcp ɛ-martensite phase as an intermediate transformation stage. A decrease in temperature also increased the driving force for the martensitic transformation.

  11. Hybrid Laser-Arc Welding of 10-mm-Thick Cast Martensitic Stainless Steel CA6NM: As-Welded Microstructure and Mechanical Properties

    Science.gov (United States)

    Mirakhorli, Fatemeh; Cao, Xinjin; Pham, Xuan-Tan; Wanjara, Priti; Fihey, Jean-Luc

    2016-07-01

    Cast CA6NM martensitic stainless steel plates, 10 mm in thickness, were welded using hybrid laser-arc welding. The effect of different welding speeds on the as-welded joint integrity was characterized in terms of the weld bead geometry, defects, microstructure, hardness, ultimate tensile strength, and impact energy. Significant defects such as porosity, root humping, underfill, and excessive penetration were observed at a low welding speed (0.5 m/min). However, the underfill depth and excessive penetration in the joints manufactured at welding speeds above 0.75 m/min met the specifications of ISO 12932. Characterization of the as-welded microstructure revealed untempered martensite and residual delta ferrite dispersed at prior-austenite grain boundaries in the fusion zone. In addition, four different heat-affected zones in the weldments were differentiated through hardness mapping and inference from the Fe-Cr-Ni ternary phase diagram. The tensile fracture occurred in the base metal for all the samples and fractographic analysis showed that the crack path is within the martensite matrix, along primary delta ferrite-martensite interfaces and within the primary delta ferrite. Additionally, Charpy impact testing demonstrated slightly higher fracture energy values and deeper dimples on the fracture surface of the welds manufactured at higher welding speeds due to grain refinement and/or lower porosity.

  12. Elemental segregation and subsequent precipitation during solidification of continuous cast Nb–V–Ti high-strength low-alloy steels

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Shuguo, E-mail: zhengsg@smm.neu.edu.cn [School of Materials and Metallurgy, Northeastern University, Shenyang 110819 (China); Davis, Claire; Strangwood, Martin [Department of Metallurgy and Materials, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

    2014-09-15

    In this study, elemental segregation during solidification and subsequent precipitation behaviour in a continuous cast Nb–V–Ti high-strength low-alloy steel was investigated by optical microscopy, scanning electron microscopy with energy dispersive X-ray spectroscopy and thermodynamic modelling. It is known that for steels with low carbon contents the pearlite that forms on slow cooling does so where the interdendritic liquid was present prior to final solidification. The alloying elements of Nb, Ti, Mn and V segregate into the interdendritic liquid during solidification, while Al preferentially segregates into the solidifying solid phase. The composition analysis on the slab samples verified the predicted element segregation behaviour, with a smaller difference in the concentrations of Mn and V in the pearlite and dendritic ferrite regions being observed compared to the Nb levels. Small (30–100 nm) spherical or irregular shaped Nb-rich precipitates (Nb(C, N) and (Nb, V)(C, N)) were mainly found in the pearlite regions, while angular Al-rich (60–300 nm) precipitates were found in the dendritic ferrite regions, in the form of AlN and complex AlN–V(C, N) precipitates. Small isolated ferrite regions surrounded by pearlite were observed in the microstructure and has two origins: one type is dendritic ferrite that appears as an isolated island due to a sectioning effect when observing the two-dimensional microstructure; the other is a ferrite idiomorph that forms in the interdendritic region due to the low carbon content of the steel. Accordingly, in these isolated ferrite islands two different precipitation behaviours are found; predominantly Al-rich particles in the dendritic regions or predominantly Nb-rich precipitates in the interdendritic ferrite idiomorphs. No Al-rich precipitates were observed in the interdendritic regions (pearlite or isolated ferrite idiomorphs) despite the Thermo-Calc predictions indicating a higher volume fraction of AlN in these

  13. Operational experience of stainless steels in seawater-cooled systems

    International Nuclear Information System (INIS)

    A study has been made of chiefly Swedish and Finnish operational experience of stainless steel in seawater and brackish water. A report is given on 23 typical cases, behind which in actual fact a considerably larger number of individual practical cases are concealed. The answer to the primary question why a standard steel of type SS 2343 (AISI 316) sometimes, contrary to expectation, remains unattacked by local corrosion is that there is usually spontaneous cathodic protection by other less noble components of carbon steel, cast iron or some copper alloy in direct contact with the stainless steel. The study confirms in other respects the adverse effect of residual oxides after welding and the beneficial of low temperature, high continuous waterflow and periodic cleaning, and of rinsing with fresh water during out-of service periods. It also verifies the additional advantages of the new high-alloy special steels which have begun to be marketed in recent years for seawater applications. (author)

  14. Thermal fatigue behavior of H-13 die steel for aluminum die casting with various ion sputtered coatings

    Science.gov (United States)

    Nieh, C. Y.; Wallace, J. F.

    1981-01-01

    Sputtered coatings of Mo, W, Pt, Ag, Au, Co, Cr, Ni, Ag + Cu, Mo + Pt, Si3N4, A1N, Cr3C2, Ta5Si3, and ZrO2 were applied to a 2-inch-square, 7-inch-long thermal fatigue test specimen which was then internally water cooled and alternately immersed in molten aluminum and cooled in air. After 15,000 cycles the thermal fatigue cracks at the specimen corners were measured. Results indicate that a significant improvement in thermal fatigue resistance was obtained with platinum, molybdenum, and tungsten coatings. Metallographic examination indicates that the improvement in thermal fatigue resistance resulted from protection of the surface of the die steel from oxidation. The high yield strength and ductility of molybdenum and tungsten contributed to the better thermal fatigue resistance.

  15. Effect of Temperature Reversion on Hot Ductility and Flow Stress-Strain Curves of C-Mn Continuously Cast Steels

    Science.gov (United States)

    Dong, Zhihua; Li, Wei; Long, Mujun; Gui, Lintao; Chen, Dengfu; Huang, Yunwei; Vitos, Levente

    2015-08-01

    The influence of temperature reversion in secondary cooling and its reversion rate on hot ductility and flow stress-strain curve of C-Mn steel has been investigated. Tensile specimens were cooled at various regimes. One cooling regime involved cooling at a constant rate of 100 °C min-1 to the test temperature, while the others involved temperature reversion processes at three different reversion rates before deformation. After hot tensile test, the evolution of mechanical properties of steel was analyzed at various scales by means of microstructure observation, ab initio prediction, and thermodynamic calculation. Results indicated that the temperature reversion in secondary cooling led to hot ductility trough occurring at higher temperature with greater depth. With increasing temperature reversion rate, the low temperature end of ductility trough extended toward lower temperature, leading to wider hot ductility trough with slightly reducing depth. Microstructure examinations indicated that the intergranular fracture related to the thin film-like ferrite and (Fe,Mn)S particles did not changed with varying cooling regimes; however, the Widmanstatten ferrite surrounding austenite grains resulted from the temperature reversion process seriously deteriorated the ductility. In addition, after the temperature reversion in secondary cooling, the peak stress on the flow curve slightly declined and the peak of strain to peak stress occurred at higher temperature. With increasing temperature reversion rate, the strain to peak stress slightly increased, while the peak stress showed little variation. The evolution of plastic modulus and strain to peak stress of austenite with varying temperature was in line with the theoretical prediction on Fe.

  16. Fundamental of Inclusion Removal from Molten Steel by Rising Bubble

    Institute of Scientific and Technical Information of China (English)

    WANG Li-tao; ZHANG Qiao-ying; LI Zheng-bang; XUE Zheng-liang

    2004-01-01

    The mechanism of inclusion removal by attachment to rising bubble was analyzed, and the movement behavior of inclusion, the mechanism of bubbles/inclusion interaction, collision probability and adhesion probability were discussed. A mathematical model of inclusion removal from molten steel by attachment to fine bubble was developed. The results of theoretical analysis and mathematical model showed that the optimum bubble diameter for inclusion removal is 1 to 2 mm. A new method that argon is injected into the shroud from ladle to tundish during continuous casting has been proposed to produce fine bubble. It provides theoretical guides for production of super clean steel.

  17. Technical Letter Report Assessment of Ultrasonic Phased Array Inspection Method for Welds in Cast Austenitic Stainless Steel Pressurizer Surge Line Piping JCN N6398, Task 1B

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, Aaron A.; Cinson, Anthony D.; Crawford, Susan L.; Mathews, Royce; Moran, Traci L.; Anderson, Michael T.

    2009-07-28

    Research is being conducted for the U.S. Nuclear Regulatory Commission (NRC) at the Pacific Northwest National Laboratory (PNNL) to assess the effectiveness and reliability of advanced nondestructive examination (NDE) methods for the inspection of light water reactor components. The scope of this research encompasses primary system pressure boundary materials including cast austenitic stainless steels (CASS); dissimilar metal welds; piping with corrosion-resistant cladding; weld overlays, inlays and onlays; and far-side examinations of austenitic piping welds. A primary objective of this work is to evaluate various NDE methods to assess their ability to detect, localize, and size cracks in coarse-grained steel components. In this effort, PNNL supports cooperation with Commissariat à l’Energie Atomique (CEA) to assess reliable inspection of CASS materials. The NRC Project Manager has established a cooperative effort with the Institut de Radioprotection et de Surete Nucleaire (IRSN). CEA, under funding from IRSN, are supporting collaborative efforts with the NRC and PNNL. Regarding its work on the NDE of materials, CEA is providing its modeling software (CIVA) in exchange for PNNL offering expertise and data related to phased-array detection and sizing, acoustic attenuation, and back scattering on CASS materials. This collaboration benefits the NRC because CEA performs research and development on CASS for Électricité de France (EdF). This technical letter report provides a summary of a technical evaluation aimed at assessing the capabilities of phased-array (PA) ultrasonic testing (UT) methods as applied to the inspection of welds in CASS pressurizer (PZR) surge line nuclear reactor piping. A set of thermal fatigue cracks (TFCs) was implanted into three CASS PZR surge-line specimens (pipe-to-elbow welds) that were fabricated using vintage CASS materials formed in the 1970s, and flaw responses from these cracks were used to evaluate detection and sizing

  18. 马氏体不锈钢水轮机叶片铸造缺陷修补工艺的研究%Study on Repairing Process of Casting Defects for Martensitic Stainless Steel Turbine Blade

    Institute of Scientific and Technical Information of China (English)

    李红霞; 柏长友; 杨保

    2015-01-01

    In view of the characteristics of ASTM A743 CA6NM martensitic stainless steel turbine blade casting, speciifc research and analysis have been carried out on welding repair technology for casting defects. E410NiMo-15 martensitic stainless steel was selected as welding material. welding process in strict accordance with the requirements was operated, and the heat treatment temperature was controlled reasonably. The results show that the welding repair process of the casting can meet the technical requirements, and the qualiifed rate of welding repair is more than 95%.%针对ASTM A743 CA6NM马氏体不锈钢水轮机叶片的铸件特点,对铸造缺陷的焊接修补工艺进行具体研究和分析。选用牌号为E410NiMo-15马氏体不锈钢作为焊接材料,严格按照焊接工艺要求进行操作并合理控制焊后热处理温度。结果表明,该铸件的焊接修补工艺达到技术要求,焊补合格率达到95%以上。

  19. Effects of rolling temperature on microstructure, texture, formability and magnetic properties in strip casting Fe-6.5 wt% Si non-oriented electrical steel

    Science.gov (United States)

    Liu, Hai-Tao; Li, Hao-Ze; Li, Hua-Long; Gao, Fei; Liu, Guo-Huai; Luo, Zhong-Han; Zhang, Feng-Quan; Chen, Sheng-Lin; Cao, Guang-Ming; Liu, Zhen-Yu; Wang, Guo-Dong

    2015-10-01

    Fe-6.5 wt% Si non-oriented electrical steel sheets with a thickness of 0.50 mm were produced by using a new processing route: strip casting followed by hot rolling, intermediate temperature (150-850 °C) rolling and final annealing. The present study focused on exploring the effects of rolling temperature varying from 150 to 850 °C on the microstructure and texture evolution, the formability and final magnetic properties. The microstructure and texture evolution at the various processing steps were investigated in detail by using OM, XRD, EBSD and TEM. It was found that the formability during rolling, the microstructure and texture before and after annealing and final magnetic properties highly depended on rolling temperature. The formability during rolling was gradually improved with increasing rolling temperature due to the slipping of dislocation. In particular, the rolling temperature dominated the formation of in-grain shear bands in the rolled microstructure, which played an important role in the development of final recrystallization microstructure and texture. In the case of lower temperature (150-450 °C) rolling, an inhomogeneous microstructure with a large amount of in-grain shear bands was formed in the rolled sheets, which finally resulted in a fine and inhomogeneous annealing microstructure dominated by mild λ-fiber texture composed of cube and {001} components and α*-fiber texture concentrated on {115} component. By contrast, in the case of higher temperature (650-850 °C) rolling, a relatively homogeneous microstructure without in-grain shear bands was formed instead in the rolled sheets, which finally led to a coarse and relatively homogeneous annealing microstructure characterized by strong α-fiber and γ-fiber texture. Accordingly, on the whole, both the magnetic induction (B8 and B50) and iron loss (P15/50 and P10/400) decreased with raising rolling temperature.

  20. Effects of warm temper rolling on microstructure, texture and magnetic properties of strip-casting 6.5 wt% Si electrical steel

    Science.gov (United States)

    Li, Hao-Ze; Liu, Hai-Tao; Liu, Yi; Liu, Zhen-Yu; Cao, Guang-Ming; Luo, Zhong-Han; Zhang, Feng-Quan; Chen, Sheng-Lin; Lyu, Li; Wang, Guo-Dong

    2014-12-01

    6.5 wt% Si electrical steel thin sheets were produced by a processing route including strip casting, hot rolling, warm rolling, intermediate annealing, warm temper rolling and final annealing, in which the warm temper rolling reduction varied from 2.7% to 14.4%. A detailed study of the microstructural and textural evolutions through the whole processing route was carried out by optical microscopy, X-ray diffraction and electron backscattered diffraction analysis. The findings revealed that the final recrystallization microstructure, texture and magnetic properties relied heavily on the warm temper rolling reduction. As the warm temper rolling reduction increased from 2.7% to 14.4%, the finally recrystallized microstructures were more homogeneous and the average grain size was decreased. At the warm temper rolling reduction lower than 7.0%, the occurrence of the exaggeratedly large annealing grains which dominated the whole sheet thickness resulted in strong //ND fiber, parallel α-fiber, //ND fiber and many other strong hard-magnetization texture components. By contrast, at the warm temper rolling reduction higher than 7.0%, the recrystallization textures were characterized by weak //ND fiber, parallel α-fiber, //ND texture, together with fewer and weak hard-magnetization texture components. The mechanism responsible for the finally microstructural and textural changes was explained by strain induced boundary migration. As warm temper rolling reduction increased, the magnetic properties at high frequency were gradually improved due to smaller grain sizes and more desirable textures. The highest magnetic inductions of 1.383 T (B8), 1.484 T (B25) and 1.571 T (B50) in combination with the lowest iron losses at high frequencies of 19.11 W/Kg (W10/400) and 3.824 W/Kg (W2/1000) were obtained at 14.4% warm temper rolling reduction under the applied condition.

  1. Effects of Two-Stage Cold Rolling Schedule on Microstructure and Texture Evolution of Strip Casting Grain-Oriented Silicon Steel with Extra-Low Carbon

    Science.gov (United States)

    Song, Hong-Yu; Liu, Hai-Tao; Liu, Wen-Qiang; Wang, Yin-Ping; Liu, Zhen-Yu; Wang, Guo-Dong

    2016-04-01

    A 0.27 mm-thick grain-oriented silicon steel sheet with extra-low carbon was successfully produced by a novel processing route including strip casting, normalizing, two-stage cold rolling with an intermediate annealing, primary annealing, and secondary recrystallization annealing. The evolutions of microstructure and texture along the whole processing route were investigated with a special emphasis on the effects of two-stage cold rolling schedule. It was found that Goss orientation originated in the first cold rolling due to shear banding and relatively strong Goss texture evolved through the whole thickness after intermediate annealing. This is significantly different from the results in conventional process in which the origin of Goss texture is in the hot rolling stage and Goss texture only develops below the sheet surface. Besides, it was found that cold rolling schedule had significant influences on microstructure homogeneity, evolution of λ-fiber texture in primary annealed state and, thus, on secondary recrystallization. In case of appropriate cold rolling schedule, a homogeneous microstructure with Goss texture, relatively strong γ-fiber texture and medium α-fiber texture was observed in the primary annealed strip. Although Goss texture in primary annealed state was much weaker than that in two-stage route in conventional process, a perfect secondary recrystallization microstructure was produced and the magnetic induction B8 was as high as 1.85 T. By contrast, when the cold rolling schedule was inappropriate, the primary annealed strips exhibited inhomogeneous microstructure, together with weak γ-fiber texture, medium α-fiber and λ-fiber texture. Finally, the sheets showed incomplete secondary recrystallization microstructure in which a large number of fine grains still existed.

  2. Improved Life of Die Casting Dies of H13 Steel by Attaining Improved Mechanical Properties and Distortion Control During Heat Treatment

    Energy Technology Data Exchange (ETDEWEB)

    J. F. Wallace; D. Schwam

    1998-10-01

    The ultimate goal of this project is to increase die casting die life by using fast enough quenching rates to obtain good toughness and fatigue resistance in premium grade H-13 steel dies. The main tasks of the project were to compile a database on physical and mechanical properties of H-13; conduct gas quenching experiments to determine cooling rates of dies in difference vacuum furnaces; measure the as-quenched distortion of dies and the residual stresses; generate finite element analysis models to predict cooling rates, distortion, and residual stress of gas quenched dies; and establish rules and create PC-based expert system for prediction of cooling rates, distortion, and residual stress in vacuum/gas quenched H-13 dies. Cooling curves during gas quenching of H-13 blocks and die shapes have been measured under a variety of gas pressure. Dimensional changes caused by the gas quenching processes have been determined by accurate mapping of all surfaces with coordinate measuring machines before and after the quench. Residual stresses were determined by the ASTM E837 hole-drilling strain gage method. To facilitate the computer modeling work, a comprehensive database of H-13 mechanical and physical properties has been compiled. Finite element analysis of the heat treated shapes has been conducted using the TRAST/ABAQUS codes. There is a good fit between the predicted and measured distortion contours. However, the magnitude of the predicted distortion and residual stresses does not match well the measured values. Further fine tuning of the model is required before it can be used to predict distortion and residual stress in a quantitative manner. This last step is a prerequisite to generating rules for a reliable expert system.

  3. Environmentally assisted cracking and irradiation embrittlement of CF-8 and CF-8M cast austenitic stainless steels in high-purity water

    International Nuclear Information System (INIS)

    Cast austenitic stainless steels (CASS) are used for components with complex geometries in the cooling system of light water reactors (LWRs). Due to both thermal ageing and irradiation embrittlement, the long-term performance of CASS materials is of concern. To assess the impact of thermal ageing and irradiation embrittlement on the cracking behaviour of CASS materials, crack growth rate and fracture toughness JR curve tests were carried out on CF-8 and CF-8M compact-tension specimens in high-purity water with low dissolved oxygen. The as-received and thermally aged CASS specimens were irradiated to 0.08 dpa to investigate the combined effect of thermal ageing and neutron irradiation. The crack growth rates of irradiated CASS materials were compared with previous results on unirradiated specimens. While no elevated cracking susceptibility was observed for the irradiated specimens at this dose level, a slightly better corrosion fatigue performance was found in the CF-8 than in CF-8M materials. Thermal ageing history had little effect on the crack growth behaviour in the test environment. Trans-granular cleavage-like cracking was the main fracture mode in the crack growth rate tests, and delta ferrite morphology could be seen in some areas on the fracture surfaces. Compared to thermal ageing, neutron irradiation had a dominant role in the fracture toughness JR curve tests. The loss of toughness due to neutron irradiation was much more significant in the as-received than in the thermally aged CASS specimens. The fracture toughness of CASS specimens was reduced to a similar level after neutron irradiation regardless of their thermal ageing history. This suggests a more rapid development of embrittlement in the as-received than in the thermally aged CASS specimens under neutron irradiation. (authors)

  4. Tensile behavior of CF8-CPF8-304H and CF8M-CPF8M-316H stainless steel static and centrifugal castings

    Energy Technology Data Exchange (ETDEWEB)

    McEnerney, J.W.; Sikka, V.K.; Booker, M.K.

    1981-10-01

    We have analyzed the tensile behavior of 11 heats of grades CF8-CPF8-304H and 13 heats of grades CF8M-CPF8M-316H static and centrifugal castings from room temperature to 650/sup 0/C. Except for anomalous conditions, the centrifugal castings exhibited uniform composition. All CPF8-304H centrifugal castings contained only radial columnar grains, but some CPF8M-316H castings had columnar, banded, or equiaxed structures. Ultimate tensile strength and total elongation were the properties in which castings showed the most inferiority to wrought material. With increasing ferrite content, 0.2% yield strength and ultimate tensile strength increased while uniform elongation, total elongation, and reduction of area decreased. Although centrifugal castings did not exhibit significant end-to-end variation in tensile behavior, the 0.2% yield strength displayed anisotropy, with axial and circumferential values being greater than radial.

  5. Study on the microstructure and mechanical properties of medium carbon Cr-Si-Mn-Mo-V steel for cast inserted dies

    Directory of Open Access Journals (Sweden)

    HAO Xiao-yan

    2005-11-01

    Full Text Available The microstructure and mechanical properties of cast inserted dies for automobile covering components were studied. The results show that the as-cast microstructures of cast inserted dies are composed of pearlite, martensite,bainite, and austenite; and that the annealed microstructure is granular pearlite. The mechanical properties of cast inserted dies approach that of forged inserted dies. The tensile strength is 855 MPa, the elongation is 16%, the impact toughness is 177 J/cm2, and the hardness after annealing and quenching are HRC 19 and HRC 60-62. In addition, the cast inserted dies have good hardenability. The depth of the hardening zone and the hardness after flame quenching satisfy the operating requirements. The cast inserted dies could completely replace the forged inserted dies for making the dies of automobile covering components.

  6. Effect of Si on Wear Resistance of Bainitic Cast Steel under High Stress Impact%硅对贝氏体铸钢高应力冲击磨损性能的影响

    Institute of Scientific and Technical Information of China (English)

    黄进峰; 方鸿生; 徐平光; 郑燕康

    2001-01-01

    The high stress-wear resistance and mechanism for bainitic cast steels with different Si content (0.7 %~2.4 %) have been studied systematically.The experiments have shown that the wear loss of high Si bainitic cast steels is only about 1/2 times as that of low Si baini tic cast steels, showing better wear resistance of the former under high stress impact.The reason is that the impact wear mechanism is different for low and hi gh Si bainitic cast steels.Low Si bainitic cast steel has poor wear resistance under high stress impact because of its low toughness, coarse dendrite and micro -segregation, etc.So the damage cracks are easily formed in the wear surface b efore formation of white layer, and propagate inside the deformation zone and ma trix, exhibiting mechanism of deformation zone and matrix delamination.The imp act toughness of high Si bainitic cast steels are improved apparently for the re ason that the brittle cementite is replaced by ductile retained austentite film, resulting in the brittle delamination of white layer.%研究了不同硅含量(0.7 %~2.4 %,质量分数,下 同)贝氏体铸钢的抗高应力磨损性能和失效机制。结果表明:高硅贝氏体铸钢的耐磨性能较 低硅钢显著提高,其磨损失重约是低硅贝氏体铸钢的1/2。这是因为硅使贝氏体铸钢在高应 力冲击磨损下表现出不同的失效机制。低硅(0.7 %)贝氏体铸钢由于韧性低、组织结构粗大 及树枝晶的微区成分偏析,故材料抵抗冲击的能力很低,常在表面还未形成强烈变形层(白 层)甚至变形层时,就在变形层和材料基体内产生裂纹并扩展,故低硅贝氏体铸钢的失效方 式为变形层和基体剥落机制。而硅含量为1.6 %~2.4 %的高硅贝氏体铸钢,因脆性的渗碳体 被韧性的残余奥氏体所代替,钢的韧性显著提高,失效方式表现为白层的剥落机制。

  7. 铸钢管道的电磁激励红外热像无损检测数值模拟研究%Numerical simulation study on NDT of cast steel pipe by electromagnetically excited thermography

    Institute of Scientific and Technical Information of China (English)

    方俊雅; 李国华; 高聚春; 胡宇; 林晓凤

    2012-01-01

    The cast steel pipe is often applied to petrochemical industry, and non-destructive testing has very important meaning in ensuring its product quality. According to the electromagnetic heat coupling analysis theory, a large-scale finite element analysis software ANSYS was used to conduct the simulation and calculation of the cast steel pipe so as to reduce the time and cost of non-destructive testing. The defect inspection laws such as the maximum temperature difference of defect surface, continuable defect inspec- tion duration, maximum detectable continuous defect length etc. was obtained by altering electromagnetic excited frequency, intensity of excited current and defect depth. The inspection results offered valuable ref- erences for non-destructive testing of cast steel pipe by electromagnetically excited thermography.%铸钢管道常用于石油化工工业中,无损检测是保障其质量的重要手段。为了减少无损检测的时间和成本,根据电磁热耦合分析原理,采用大型有限元分析软件ANSYS,对铸钢管道进行模拟仿真运算,通过改变电磁激励频率、激励电流强度和缺陷深度,得到缺陷表面的最大温差、缺陷可检测的持续时间、缺陷可检测的最大连续长度等缺陷规律检测,检测结果为铸钢电磁激励红外热像无损检测提供了有价值的参考。

  8. Model castings with composite surface layer - application

    Directory of Open Access Journals (Sweden)

    J. Szajnar

    2008-10-01

    Full Text Available The paper presents a method of usable properties of surface layers improvement of cast carbon steel 200–450, by put directly in foundingprocess a composite surface layer on the basis of Fe-Cr-C alloy. Technology of composite surface layer guarantee mainly increase inhardness and aberasive wear resistance of cast steel castings on machine elements. This technology can be competition for generallyapplied welding technology (surfacing by welding and thermal spraying. In range of studies was made cast steel test castings withcomposite surface layer, which usability for industrial applications was estimated by criterion of hardness and aberasive wear resistance of type metal-mineral and quality of joint cast steel – (Fe-Cr-C. Based on conducted studies a thesis, that composite surface layer arise from liquid state, was formulated. Moreover, possible is control of composite layer thickness and its hardness by suitable selection of parameters i.e. thickness of insert, pouring temperature and solidification modulus of casting. Possibility of technology application of composite surface layer in manufacture of cast steel slide bush for combined cutter loader is presented.

  9. Effects of rolling temperature on microstructure, texture, formability and magnetic properties in strip casting Fe-6.5 wt% Si non-oriented electrical steel

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hai-Tao, E-mail: liuht@ral.neu.edu.cn [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China); Institute of Research of Iron and Steel, Shasteel, Zhangjiagang 215625, Jiangsu (China); Li, Hao-Ze [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China); Li, Hua-Long [Institute of Research of Iron and Steel, Shasteel, Zhangjiagang 215625, Jiangsu (China); Gao, Fei; Liu, Guo-Huai [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China); Luo, Zhong-Han; Zhang, Feng-Quan; Chen, Sheng-Lin [National Engineering Research Center for Silicon Steel, Wuhan Iron & Steel (Group) Corp, Wuhan 430083 (China); Cao, Guang-Ming; Liu, Zhen-Yu; Wang, Guo-Dong [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China)

    2015-10-01

    Fe-6.5 wt% Si non-oriented electrical steel sheets with a thickness of 0.50 mm were produced by using a new processing route: strip casting followed by hot rolling, intermediate temperature (150–850 °C) rolling and final annealing. The present study focused on exploring the effects of rolling temperature varying from 150 to 850 °C on the microstructure and texture evolution, the formability and final magnetic properties. The microstructure and texture evolution at the various processing steps were investigated in detail by using OM, XRD, EBSD and TEM. It was found that the formability during rolling, the microstructure and texture before and after annealing and final magnetic properties highly depended on rolling temperature. The formability during rolling was gradually improved with increasing rolling temperature due to the slipping of dislocation. In particular, the rolling temperature dominated the formation of in-grain shear bands in the rolled microstructure, which played an important role in the development of final recrystallization microstructure and texture. In the case of lower temperature (150–450 °C) rolling, an inhomogeneous microstructure with a large amount of in-grain shear bands was formed in the rolled sheets, which finally resulted in a fine and inhomogeneous annealing microstructure dominated by mild λ-fiber texture composed of cube and {001}〈210〉 components and α*-fiber texture concentrated on {115}〈5–10 1〉 component. By contrast, in the case of higher temperature (650–850 °C) rolling, a relatively homogeneous microstructure without in-grain shear bands was formed instead in the rolled sheets, which finally led to a coarse and relatively homogeneous annealing microstructure characterized by strong α-fiber and γ-fiber texture. Accordingly, on the whole, both the magnetic induction (B{sub 8} and B{sub 50}) and iron loss (P{sub 15/50} and P{sub 10/400}) decreased with raising rolling temperature. - Highlights: • Fe−6

  10. 铸造奥氏体不锈钢的疲劳裂纹扩展%Fatigue crack growth of cast austenitic stainless steels

    Institute of Scientific and Technical Information of China (English)

    吕绪明; 李时磊; 王西涛; 王艳丽

    2015-01-01

    用紧凑拉伸试样研究了载荷比、单峰过载和两步高-低幅加载对Z3CN20-09M铸造奥氏体不锈钢疲劳裂纹扩展速率的影响。当应力强度因子范围相同时,疲劳裂纹扩展速率随载荷比的增大而增大。单峰过载使裂纹扩展速率先有短暂的增加后长距离的减速扩展,出现裂纹扩展迟滞现象。两步高-低幅加载时,若两步的最大载荷不同,第二步裂纹扩展也会出现迟滞现象。用两参数模型和Wheeler模型能够预测恒幅载荷和变幅载荷下的疲劳裂纹扩展行为。%The influences of stress ratio, single overload and high-low loading sequence on the fatigue crack growth of Z3CN20-09M cast austenitic stainless steels were studied with compact tension specimens. When the stress intensity factor range is identical, the fatigue crack growth rate increases with the increase of stress ratio. During single overload, the fatigue crack growth rate shows a short period of acceleration followed by a significant decrease, leading to subsequent crack growth retardation. Similarly, high-low loading sequence with the maximum load in the second step lower than that in the first loading step results in significant crack growth retardation in the second loading step. A two-parameter model and Wheeler’ s model are found to predict well the crack growth behav-ior under constant-amplitude loading and variable-amplitude loading, respectively.

  11. Effect of heat treatment and cleanness of ultra low carbon bainitic (ULCB) steel on its impact toughness

    International Nuclear Information System (INIS)

    The small variations in sulphur and carbon concentrations can have a major influence on the impact transition temperature (ITT) of ultra low carbon HSLA-100 steel which has been quenched in water and tempered (WQ and T). Since the average carbon concentration is very low thus sensitivity of ITT to heat treatment parameters depends also on the yield strength increase due to precipitation effect of εCu phase. The regression analysis has been used to establish equations taking into account those parameters. The properties of a mixed microstructure formed from partially austenitic regions have been also considered. The fine austenitic grains transform into more desirable fine bainitic ferrite phases with lower hardness values and higher toughness. On the other hand, if cooling rate is sufficiently large, then the carbon enriched austenite transforms partially into hard martensite and some of remaining untransformed austenite being retained to ambient temperature. Because hard martensite islands are located in much softer surroundings consisting of tempered ferrite, they do not cause a general reduction in impact toughness tests. Due to further grain refinement of microstructure the measured toughness on Charpy V specimens can be very high at low temperatures. The very detrimental effect of sulphur in ULCB steel has been confirmed by presented results. (author)

  12. Study on Heterogeneous Nuclei in Cast H13 Steel Modified by Rare Earths%变质CH13钢中Ce2O3异质核心作用的研究

    Institute of Scientific and Technical Information of China (English)

    兰杰; 贺俊杰; 丁文江; 王渠东; 朱燕萍

    2001-01-01

    The dendrite segregation in cast H13 steel is weakened with RE modification treatment. Carbide on grain boundary disappeared after quenching, and impact toughness improved greatly. By two-dimensional lattice misfitting calculation and analysis by electron probe, it is found that Ce2O3 may act as the heterogeneous nuclei of modified cast H13 steel.%采用变质处理大大减弱了CH13钢枝晶组织的元素偏析,使未变质CH13钢中的晶界碳化物得以消除, CH13钢的冲击韧性大大提高。通过热力学计算及二维点阵错配度计算,并采用电子探针定量分析等手段,证实Ce2O3型稀土夹杂物可作为CH13钢中初生奥氏体的异质核心,细化枝晶组织,减弱合金元素偏析。

  13. Dynamic schedule of steel making-continuous casting based on group adjustment orienting restrict%基于约束联动的炼钢-连铸动态调度

    Institute of Scientific and Technical Information of China (English)

    赵宁; 丁文英; 董绍华; 冯爱兰

    2011-01-01

    为了解决炼钢-连铸生产动态调度中调度约束繁杂、多变的问题,分析了炼钢-连铸动态调度约束集,提出了约束联动的方法来实现快速的人机交互动态调度,并在此基础上建立了约束联动的动态调度数学模型和调度算法,最后结合实例说明了约束联动动态调度方法的有效性.%In order to solve dynamic disturbance in steel making-continuous casting, the restrict muster of steel making-continuous casting was analyzed firstly. Group adjustment orienting restrict was built to ensure schedule result timely and correctness in interactive schedule. Dynamic schedule model and schedule algorithm were built orienting this method. Finally, an example was showed to prove the efficiency of group adjustment orienting restrict.

  14. 炼钢-连铸生产调度系统建模%Modeling of an Extended UML and for Steeling-Continuous Multi-Agent Scheduling System Casting Production

    Institute of Scientific and Technical Information of China (English)

    顾曦; 张鑫; 唐秋华

    2012-01-01

    针对炼钢-连铸生产调度,通过扩展UML对象和消息传递机制,形式化捕述每个Agent的知识,并提升其行为控制和模块通讯能力;基于多Agent分布式建模体系,构造出炼钢-连铸生产调度系统所需的各种Agent类的静态属性和方法,及各类之间的动态交互关系,完成调度表生成、信息收集及数据分析处理,实现生产的有效调度.%As for the steeling-continuous casting production scheduling, the paper described the knowledge of each agent in formalization and promoted its ability of action control and module communication through extending the object and communication mechanism of UML. On the basis of the multi-agent distributed modeling structure, the static properties and methods of each agent needed by the steeling-continuous cast- ing production scheduling system, as well as the dynamic interrelationship among agents were construc- ted. The production of the production scheduling generation, information collection and data analysis were also completed to achieve the production scheduling effectively.

  15. Imaging molten steel flow profiles

    Science.gov (United States)

    Binns, R.; Lyons, A. R. A.; Peyton, A. J.; Pritchard, W. D. N.

    2001-08-01

    Control of delivery of molten steel in continuous casting is critical in order to ensure stability of the meniscus and satisfactory mould flow patterns, which in turn are determinants of cleanness and surface quality of steel. Considerable effort has been expended over the last ten years on optimizing the design of the metal delivery system, particularly the pouring nozzle, in order to allow the consistent production of high quality steel at a high throughput. This paper looks forward to possible systems that are capable of tomographically imaging the distribution of molten steel flows in these applications. The paper will concentrate on the feasibility of using electromagnetic methods. The paper will present some initial results; an overview of the applied image reconstruction process will also be included. The paper will conclude with a discussion of possible future developments, such as the use of a tomographic or multi-frequency approach, future research on the reconstruction image procedures and the potential for visualization and flow measurement. There is a need for further research in this area and some priority areas for future work will be suggested.

  16. 开发纯净钢冶炼技术生产高强度钢丝绳用钢%Developing clean steel smelting technology to produce steel for high strength wire rope

    Institute of Scientific and Technical Information of China (English)

    王秉喜; 郭大勇

    2013-01-01

    According to the demands of developing high strength wire rope,adopting a series of high carbon clean steel smelting technology such as hot metal predesulphurization,slag-blocked tapping,LF furnace high basicity slag washing deep desulphurizing and vacuum degassing(VD) to produce the steel for high strength wire ropes.Mass fraction of S and P in steel are 100 millionth and 60 millionth respectively,the mass fraction of O and N are 15 millionth and 24 millionth respectively,the B and D class inclusions which harm wire drawing more are controlled at 1.0 class and 0.5 class respectively,the maximum inclusion size is 11.6 micron.The tensile strength of diameter 8.0 mm wire rod produced reach 1190 MPa,reduction of area is 40%,the tensile strength of diameter 2.4 mm galvanizing steel wire is over 1670 MPa,torsion is over 25 times,which satisfy the demands of GB/T 8919-1996 to produce 1670 ~ 1770 MPa class high strength galvanizing wire ropes.%根据钢丝绳向高强度发展的要求,采用铁水预脱硫、挡渣出钢、LF炉高碱度渣洗深脱硫及VD真空脱气精炼等一系列高碳纯净钢冶炼技术生产高强度钢丝绳用钢.钢中P,S质量分数分别为100×10-6和60×10-6,O,N质量分数分别为15×10-6和24×10-6,对拉拔生产危害较大的B,D类夹杂分别控制在1.0级和0.5级,夹杂物最大尺寸为11.6μm.生产的φ8.0 mm盘条抗拉强度达1190 MPa,断面收缩率为40%,φ2.4 mm镀锌钢丝抗拉强度超过1670MPa,扭转大于25次,完全满足GB/T 8919-1996生产1670~1770 MPa级高强度镀锌钢丝绳的要求.

  17. [The industrial environment in the electric-furnace steel smelting, converter and open-hearth furnace methods of manufacturing manganese-alloyed steels].

    Science.gov (United States)

    Karnaukh, N G; Petrov, G A; Gapon, V A; Poslednichenko, I P; Shmidt, S E

    1992-01-01

    Inspection of the environment in manganese-alloyed steel production showed inadequate hygienic conditions of the technological processes employed. Air was more polluted by manganese oxides during the oxygen-converter process though their highest concentrations, 38 times exceeding the MAS, appeared during the casting of steel. An electric furnace coated by dust-noise-proof material and gas cleaning is preferable from a hygienic point of view. The influence of unfavourable microclimate, intensive infrared irradiation and loud noise on workers necessitates automation and mechanization of the process in order to improve the working conditions.

  18. 大型不锈钢铸件粘砂及表面烧结机理研究与改进%Mechanisum and Prevention of Surface Burnning-on of Large Sized Stainness Steel Casting

    Institute of Scientific and Technical Information of China (English)

    扈广麒; 王培; 彭凡; 肖纳敏

    2011-01-01

    对采用呋喃树脂自硬铬矿砂生产高铬不锈钢水轮机叶片铸件表面易出现"釉化"涂料层、界面型砂"釉化"烧结和粘砂缺陷进行了研究,并提出了解决措施.铸件粘砂的主要原因为钢液透过涂料层渗入铬矿砂,在界面发生氧化还原反应,将铬铁矿砂的铁还原出来,还原出的铁和砂粒形成致密混合物,并附着在铸件表面形成"釉化"烧结层.还原出的铁和铬渣以及砂粒中的未反应物,形成了致密的机械混合物,和铸件金属直接相连,附着在铸件的表面,形成粘砂.锆英粉涂料本身也和高铬钢发生微弱的化学反应.用新型添加剂及复合涂料改进型砂和替代锆英粉涂料,提高了钢液和铬矿砂界面涂料层的致密度、化学稳定性和耐火性,可以有效地解决这类问题.%Some defects such as coating glazing, interface sand glazing and sintering and sand fusion always appear on surface of cast high-chromium stainless steel hydraulic turbine blade castings when using furan resin chromite sand. The main reason for these defects is the infiltration of liquid steel through the coating to chromite and the redox reaction took place which reduces iron out of chromite sand. First, the iron and sand are mixed together and become dense mixture, and then iron, sand and the un-reacted material in sand are mixed together to form dense mechanical mixtures attached to the surface of casting causing the sand burning. Second, a weak chemical reaction occurs between zircon powder coating and the high-chromium steel. According to the analyses, the powder coating with higher chemical stability and fire resistance was chosen instead of zircon powder coating. Additionally, the corundum powder coating can improve the coasting density at the interface of the molten steel and chromite sand. And this method is useful for solving such kind of problems.

  19. Cast heat-resistant austenitic steel with improved temperature creep properties and balanced alloying element additions and methodology for development of the same

    Energy Technology Data Exchange (ETDEWEB)

    Pankiw, Roman I; Muralidharan, Govindrarajan; Sikka, Vinod Kumar; Maziasz, Philip J

    2012-11-27

    The present invention addresses the need for new austenitic steel compositions with higher creep strength and higher upper temperatures. The new austenitic steel compositions retain desirable phases, such as austenite, M.sub.23C.sub.6, and MC in its microstructure to higher temperatures. The present invention also discloses a methodology for the development of new austenitic steel compositions with higher creep strength and higher upper temperatures.

  20. SPRAY CASTING

    OpenAIRE

    SALAMCI, Elmas

    2010-01-01

    ABSTRACT This paper is designed to provide a basic review of spray casting. A brief overview of the historical development of spray  casting and the description of plant and equipment have been given. Following metallurgical characteristics of spray formed alloys, process parameters and solidification mechanism of spray deposition have been discussed in detail. Finally, microstructure and mechanical properties of the selected spray cast Al-Zn-Mg-Cu alloys have been presented and compared...