Sample records for clay water systems

  1. Water Absorbing Plantation Clay for Vertical Greenery System

    Directory of Open Access Journals (Sweden)

    Yu Lih-Jiun


    Full Text Available With the arises of environmental conscious, the usage of vertical garden system has become more popular in urban cities. Citizens can enjoys the benefits of energy and cost saving besides ornamental effect. More investigations have been conducted on green facades led to the cities ecological enhancement.However, limited plants species can be planted for green facades systems as this system does not provide sufficient soil and nutrients for common plants. Alternative plantation methods such as planted box and felt system required additional maintenance attention. The idea of using clay composite which consists of nutritious soil, water absorbing polymer and flexible cement clay potentially become alternative vertical greenery systems that offers economic and sustainable plantation platform for more variety of plants.The fabricating of clay composite involved three processes, they are: mixing, moulding and drying. Physical properties characterisation (density, pH, compression test, aging test and water immersion test were tested on the dried fabricated clay composite to ensure their sustainability in tropical climate. The results showed that clay composite with 1.5 wt% of cement and 0.3 wt% superabsorbent polymer shows optimum water absorbing properties. This system are expected to enable more agriculture activities in urban living.

  2. Structural Investigation of Alkali Activated Clay Minerals for Application in Water Treatment Systems (United States)

    Bumanis, G.; Bajare, D.; Dembovska, L.


    Alkali activation technology can be applied for a wide range of alumo-silicates to produce innovative materials with various areas of application. Most researches focuse on the application of alumo-silicate materials in building industry as cement binder replacement to produce mortar and concrete [1]. However, alkali activation technology offers high potential also in biotechnologies [2]. In the processes where certain pH level, especially alkaline environment, must be ensured, alkali activated materials can be applied. One of such fields is water treatment systems where high level pH (up to pH 10.5) ensures efficient removal of water pollutants such as manganese [3]. Previous investigations had shown that alkali activation technology can be applied to calcined clay powder and aluminium scrap recycling waste as a foam forming agent to create porous alkali activated materials. This investigation focuses on the structural investigation of calcined kaolin and illite clay alkali activation processes. Chemical and mineralogical composition of both clays were determined and structural investigation of alkali activated materials was made by using XRD, DTA, FTIR analysis; the microstructure of hardened specimens was observed by SEM. Physical properties of the obtained material were determined. Investigation indicates the essential role of chemical composition of the clay used in the alkali activation process, and potential use of the obtained material in water treatment systems.

  3. Probing the water interactions in clay

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    Powell, D.H. [Lausanne Univ., Lausanne (Switzerland); Fischer, H.E. [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France); Skipper, N.T. [Univ. College, London (United Kingdom)


    Clays, the microscopic mineral fraction of soils, are probably the most important substrate for interactions between water, the mineral world and the biosphere. A knowledge of the structuring of water and hydrated metal ions near clays surfaces is of importance in environmental science, including toxic and radioactive waste disposal, and in the industrial application of clays. The smectite clays, with their large hydrated internal surface areas represent excellent model systems for the interactions of aqueous phases with solid surface. We present the results of neutron diffraction experiments using isotopic substitutions to probe the structure in the aqueous interlayer region of Li-montmorillonite. (authors) 6 refs., 3 figs.

  4. Active containment systems incorporating modified pillared clays

    Energy Technology Data Exchange (ETDEWEB)

    Lundie, P. [Envirotech (Scotland) Ltd., Aberdeen (United Kingdom)]|[Environmental Resource Industries Disposal Pty Ltd., Perth (Australia); McLeod, N. [Envirotreat Ltd., Kingswinford (United Kingdom)


    The application of treatment technologies in active containment systems provides a more advanced and effective method for the remediation of contaminated sites. These treatment technologies can be applied in permeable reactive walls and/or funnel and gate systems. The application of modified pillared clays in active containment systems provides a mechanism for producing permeable reactive walls with versatile properties. These pillared clays are suitably modified to incorporate reactive intercalatants capable of reacting with both a broad range of organic pollutants of varying molecular size, polarity and reactivity. Heavy metals can be removed from contaminated water by conventional ion-exchange and other reactive processes within the clay structure. Complex contamination problems can be addressed by the application of more than one modified clay on a site specific basis. This paper briefly describes the active containment system and the structure/chemistry of the modified pillared clay technology, illustrating potential applications of the in-situ treatment process for contaminated site remediation.

  5. Nitrogen and Phosphorus Removal in the Recirculating Aquaculture System with Water Treatment Tank containing Baked Clay Beads and Chinese Cabbage

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    Aeknarin Thanakitpairin


    Full Text Available This research aims to describe the nitrogen and phosphorus removal in Recirculating Aquaculture System (RAS by crop plants biomass production. The 3 experiment systems consisted of 1 treatment (fish tank + baked clay beads + Chinese cabbage and 2 controls as control-1 (fish tank only and control-2 (fish tank + baked clay beads, were performed. With all experimental RAS, Nile tilapia (Oreochromis niloticus was cultured at 2 kg/m3 density. The baked clay beads (8-16 mm in diameter were filled as a layer of 10 cm in the water treatment tank of control-2. While in the treatment tank, Chinese cabbage (Brassica pekinensis was planted at 334 plants/m2 in baked clay beads layer. During 35 days of experiment, the average fish wet-weight in control-1, control-2 and treatment systems increased from 16.31±1.49, 15.18±1.28 and 11.31±1.49 g to 29.43±7.06, 28.65±3.12 and 27.20±6.56 g, respectively. It was found that the growth rate of 0.45±0.15 g-wet weight/day in a treatment tank was higher than in those 2 controls, which were rather similar at 0.37±0.16 and 0.38±0.05 g-wet weight/day, respectively. The fish survival rate of all experimental units was 100%. The average Chinese cabbage wet-weight in treatment system increased from 0.15±0.02 g to 1.00±0.38 g. For water quality, all parameters were within the acceptable range for aquaculture. The assimilation inorganic nitrogen in a treatment tank showed a slower rate and lower nitrite accumulation relative to those in control tanks. The nitrogen and phosphorus balance analysis illustrated that most of the nitrogen and phosphorus input in all systems was from feed (82-87% and 21-87% while at the final day of experiments, nitrogen and phosphorus in tilapia culture revealed at 15-19% and 4-13%. The accumulation of nitrogen and phosphorus in the water, up to 56% and 70%, was found in control-1 while water in the tank with baked clay beads had substantial lower nitrogen and phosphorus concentration. The

  6. A possible role of fluctuating clay-water systems in the production of ordered prebiotic oligomers (United States)

    Lahav, N.; White, D. H.


    A model is proposed for the intermediate stages of prebiotic evolution, based on the characteristics of the adsorption and condensation of amino acids and nucleotides on the surface area of clay minerals in a fluctuating environment. Template replication and translation of adsorbed oligonucleotides and catalytic effects by peptide products on further condensation are proposed, due to specific properties of hypohydrous clay surfaces as well as the biomolecules themselves. Experimental evidence supports some of the proposed interactions, and all of them can be tested experimentally.

  7. Water balance of an earth fill built of organic clay

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    Birle Emanuel


    Full Text Available The paper presents investigations on the water balance of an earth fill built of organic clay in humid climate. As the organic soil used for the fill contains geogenetically elevated concentrations of arsenic, particular attention is paid on the seepage flow through the fill. The test fill is 5 m high, 30 m long and 25 m wide. The fill consists of the organic clay compacted at water contents wet and dry of Proctor Optimum covered by a drainage mat and a 60 cm thick top layer. For the determination of the water balance extensive measuring systems were installed. The seepage at the bottom measured so far was less than 2 % of the precipitation. The interflow in the drainage mat above the compacted organic clay was of similar magnitude. The estimated evapotranspiration reached approx. 84 % of the precipitation. According to these measurements the percolation is much lower than the percolation of many landfill covers in humid climates.

  8. Water Retention Curves of Opalinus Clay

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    Villar, M. V.; Romero, F. J.


    The water retention curve of Opalinus clay samples was determined under different conditions: total and matric suction, stress or no-stress conditions, wetting and drying paths. Through the fitting of these results to the van Genuchten expression the P parameter, related to the air entry value (AEV), was obtained. The AEV is the suction value above which air is able to enter the pores of the sample, and consequently, above which 2-phase flow can take place in the soil pore structure. The samples used in this research came from two different boreholes, BHT-1 and BHG-D1, but the behaviour of them did not depend on their location, what was probably due to the fact that both were drilled in the shay facies of the Opalinus clay. There was not a distinct difference between the results obtained under total or matric suctions. In the drying paths, both the water contents and the degrees of saturation tended to be higher when total suction was applied, however the reverse trend was observed for the water contents reached in wetting paths. As well, no clear difference was observed in the water retention curves obtained in odometers under matric and total suctions, what points to the osmotic component of suction in Opalinus clay not being significant. Overall, the water contents were lower and the degrees of saturation higher when suction was applied under vertical stress, what would indicate that the water retention capacity was lower under 8 MPa vertical stress than under free volume conditions. This vertical stress value is slightly higher than the maximum in situ stress. Also, the samples showed hysteresis according to the expected behaviour, i.e. the water contents for a given suction were higher during a drying path than during a wetting path. The P values obtained were between 6 and 34 MPa, and tended to be higher for the samples tested under stress, in drying paths and when total suction was used. The air entry value calculated from the mercury intrusion porosimetry

  9. The systems containing clays and clay minerals from modified drug release: a review. (United States)

    Rodrigues, Luís Alberto de Sousa; Figueiras, Ana; Veiga, Francisco; de Freitas, Rivelilson Mendes; Nunes, Lívio César Cunha; da Silva Filho, Edson Cavalcanti; da Silva Leite, Cleide Maria


    Clays are materials commonly used in the pharmaceutical industry, either as ingredients or as active ingredients. It was observed that when they are administered concurrently, they may interact with drugs reducing their absorption. Therefore, such interactions can be used to achieve technological and biopharmaceutical advantages, regarding the control of release. This review summarizes bibliographic (articles) and technological (patents) information on the use of systems containing clays and clay minerals in modified drug delivery. In this area, formulations such natural clay, commercial clay, synthetic clay, composites clay-polymers, nanocomposites clay-polymers, films and hidrogels composites clay-polymers are used to slow/extend or vectorize the release of drugs and consequently they increase their bioavailability. Finally, this review summarizes the fields of technology and biopharmaceutical applications, where clays are applied.

  10. Sorption and desorption of carbamazepine from water by smectite clays. (United States)

    Zhang, Weihao; Ding, Yunjie; Boyd, Stephen A; Teppen, Brian J; Li, Hui


    Carbamazepine is a prescription anticonvulsant and mood stabilizing pharmaceutical administered to humans. Carbamazepine is persistent in the environment and frequently detected in water systems. In this study, sorption and desorption of carbamazepine from water was measured for smectite clays with the surface negative charges compensated with K+, Ca2+, NH4+, tetramethylammonium (TMA), trimethylphenylammonium (TMPA) and hexadecyltrimethylammonium (HDTMA) cations. The magnitude of sorption followed the order: TMPA-smectite≥HDTMA-smectite>NH4-smectite>K-smectite>Ca-smectite⩾TMA-smectite. The greatest sorption of carbamazepine by TMPA-smectite is attributed to the interaction of conjugate aromatic moiety in carbamazepine with the phenyl ring in TMPA through π-π interaction. Partitioning process is the primary mechanism for carbamazepine uptake by HDTMA-smectite. For NH4-smectite the urea moiety in carbamazepine interacts with exchanged cation NH4+ by H-bonding hence demonstrating relatively higher adsorption. Sorption by K-, Ca- and TMA-smectites from water occurs on aluminosilicate mineral surfaces. These results implicate that carbamazepine sorption by soils occurs primarily in soil organic matter, and soil mineral fractions play a secondary role. Desorption of carbamazepine from the sorbents manifested an apparent hysteresis. Increasing irreversibility of desorption vs. sorption was observed for K-, Ca-, TMA-, TMPA- and HDTMA-clays as aqueous carbamazepine concentrations increased. Desorption hysteresis of carbamazepine from K-, Ca-, NH4-smectites was greater than that from TMPA- and HDTMA-clays, suggesting that the sequestrated carbamazepine molecules in smectite interlayers are more resistant to desorption compared to those sorbed by organic phases in smectite clays.

  11. Boom clay borehole water, home of a diverse bacterial community

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    Wouters, Katinka; Moors, Hugo; Leys, Natalie [Belgian Nuclear Research Centre (SCK-CEN), Mol (Belgium)


    For over two decades, Boom Clay has been studied in the framework of geological disposal of nuclear waste thereby mainly addressing its geochemical properties. Today, also the microbiological properties and the possibility of microbes interacting with radionuclides or repository components including the waste form, in a host formation like Boom Clay are considered [2,3]. In the past, a reference composition for synthetic Boom Clay pore water (BCPW) was derived, based on interstitial water sampled from different layers within the Boom clay [1]. Similarly, the primary aim of this microbiological study was to determine the core BCPW bacterial community and identify representative water samples for future microbial directed lab experiments. In this respect, BCPW was sampled from different Boom Clay layers using the Morpheus piezometer and subsequently analysed by microscopy and molecular techniques, in search for overall shared and abundant micro-organisms. (authors)

  12. The influence of clay type on reduction of water repellency by applied clays: a review of some West Australian work (United States)

    McKissock, I.; Walker, E. L.; Gilkes, R. J.; Carter, D. J.


    In Western Australia water repellency mostly occurs in soils with sandy texture; the severity of water repellency is influenced by very small changes in clay content. Additions of 1-2% clay can prevent water repellency and for some time clay amendments have been used by farmers to overcome water repellency. The aim of this study was to assess the effectiveness of clays in ameliorating water repellency. Clays were assessed for effectiveness in reducing water repellency by mixing with water repellent sands and measuring water drop penetration time (WDPT) on the resultant mixtures. WDPT was measured on the initial mixtures, a wetting and drying cycle was imposed and WDPT measured again. Two sets of clays were assessed: four simple clays containing kaolinite (2) or smectite (2) group minerals and a group of clayey subsoil materials which had been collected by farmers. For the simple clays, clay mineral type was the most significant factor in determining response. Kaolin was much more effective than smectite. Imposition of a wetting and drying cycle greatly reduced water repellency. The dominant exchangeable cation of the clays (sodium or calcium) had little effect on the ability of the clays to reduce water repellency. The factor that was most predictive of the effectiveness of clayey subsoils materials in reducing water repellency was texture: clay content ( r2=0.18) or clay+silt content ( r2=0.23). These properties were more predictive of water repellency values after the wetting and drying cycle treatment ( r2=0.36, r2=0.44). The proportion of the clay fraction that consisted of kaolinite was next most predictive in determining effectiveness which is again indicative of kaolin group minerals being more effective than smectite group minerals. The exchangeable sodium percentage and clay dispersibility had no systematic effect on the ability of these clays to reduce water repellency. These results provide a basis for developing a practical field procedure to enable

  13. Water diffusion through compacted clays analyzed by neutron scattering and tracer experiments

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    Gonzalez Sanchez, F


    Clay minerals are aluminium phyllosilicates, mostly products of the chemical alteration and mechanical breakdown of igneous and metamorphic rocks. Their physical and chemical properties can be directly related to their layered, fine-grained (large surface area) structure. These properties such as large water retention, low hydraulic conductivity, heat resistance and ionic exchange capacities, make clays ideal for many different applications, e.g. as sealing material for the underground disposal of radioactive waste. The long-term disposal of radioactive waste in an underground geological repository is based on a multibarrier concept. In the barrier of highly compacted clay, water is intercalated and confined between the clay layers. The narrow pores are responsible that under natural hydraulic gradients, molecular diffusion through water is the dominant transport mechanism for released radionuclides. The properties of water at the water-clay interface differ from that of bulk water. Therefore, a good and deep understanding of the water structure and dynamics in compacted clay systems is fundamental. This knowledge is the base for the progressing research about transport of pollutants through the compacted clays and argillaceous rock of radioactive waste barriers. This study focusses on four different types of pure clays, two of them charged, namely montmorillonite and illite (both in a Na and Ca form), and two uncharged, namely kaolinite and pyrophyllite. Their structural differences result in a significantly different behaviour in contact with water. In case of montmorillonite, water is located in between particles and in the interlayer space. In illite, water is found only in between particles, because the interlayer surfaces are tightly linked by potassium cations. The layers of kaolinite and pyrophyllite are uncharged and, consequently, water is located only in between particles. The clay powders were compacted to reach a high bulk dry density of about 1.9 g

  14. Networking and rheology of concentrated clay suspensions "matured" in mineral medicinal water. (United States)

    Aguzzi, Carola; Sánchez-Espejo, Rita; Cerezo, Pilar; Machado, José; Bonferoni, Cristina; Rossi, Silvia; Salcedo, Inmaculada; Viseras, César


    This work studied the influence of "maturation" conditions (time and agitation) on aggregation states, gel structure and rheological behaviour of a special kind of pharmaceutical semisolid products made of concentrated clay suspensions in mineral medicinal water. Maturation of the samples was carried out in distilled and sulphated mineral medicinal water, both in static conditions (without agitation) and with manual stirring once a week, during a maximum period of three months. At the measured pH interval (7.5-8.0), three-dimensional band-type networks resulting from face/face contacts were predominant in the laminar (disc-like) clay suspensions, whereas the fibrous (rod-like) particles formed micro-aggregates by van der Waals attractions. The high concentration of solids in the studied systems greatly determined their behaviour. Rod-like sepiolite particles tend to align the major axis in aggregates promoted by low shearing maturation, whereas aggregates of disc-like smectite particles did not have a preferential orientation and their complete swelling required long maturation time, being independent of stirring. Maturation of both kinds of suspensions resulted in improved rheological properties. Laminar clay suspensions became more structured with time, independently from static or dynamic maturation conditions, whereas for fibrous clay periodic agitation was also required. Rheological properties of the studied systems have been related to aggregation states and networking mechanisms, depending on the type of clay minerals constituents. Physical stability of the suspensions was not impaired by the specific composition of the Graena medicinal water.

  15. Water diffusion through compacted clays analyzed by neutron scattering and tracer experiments

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Sanchez, F


    Clay minerals are aluminium phyllosilicates, mostly products of the chemical alteration and mechanical breakdown of igneous and metamorphic rocks. Their physical and chemical properties can be directly related to their layered, fine-grained (large surface area) structure. These properties such as large water retention, low hydraulic conductivity, heat resistance and ionic exchange capacities, make clays ideal for many different applications, e.g. as sealing material for the underground disposal of radioactive waste. The long-term disposal of radioactive waste in an underground geological repository is based on a multibarrier concept. In the barrier of highly compacted clay, water is intercalated and confined between the clay layers. The narrow pores are responsible that under natural hydraulic gradients, molecular diffusion through water is the dominant transport mechanism for released radionuclides. The properties of water at the water-clay interface differ from that of bulk water. Therefore, a good and deep understanding of the water structure and dynamics in compacted clay systems is fundamental. This knowledge is the base for the progressing research about transport of pollutants through the compacted clays and argillaceous rock of radioactive waste barriers. This study focusses on four different types of pure clays, two of them charged, namely montmorillonite and illite (both in a Na and Ca form), and two uncharged, namely kaolinite and pyrophyllite. Their structural differences result in a significantly different behaviour in contact with water. In case of montmorillonite, water is located in between particles and in the interlayer space. In illite, water is found only in between particles, because the interlayer surfaces are tightly linked by potassium cations. The layers of kaolinite and pyrophyllite are uncharged and, consequently, water is located only in between particles. The clay powders were compacted to reach a high bulk dry density of about 1.9 g

  16. Effect of clay aggregation on water diffusivity using low field NMR. (United States)

    Guichet, Xavier; Fleury, Marc; Kohler, Eric


    Water diffusivity D measured by using NMR techniques in Na-smectite suspensions decreases with increasing smectite fraction (up to 50 wt%), but increases with increasing salinity (NaCl or CaCl(2) aqueous solutions) at a fixed clay fraction. The increase, larger for CaCl(2) solutions, is explained by aggregation of clay particles when high salinities are reached. Macroscopic organisation of dense mixtures of clay and aqueous solutions can be inferred by T(2) transverse NMR relaxation times which are sensitive to the volume to surface ratio. Dispersed suspensions exhibit mono-modal T(2) distributions, whereas bimodal T(2) distributions are observed for flocculated systems. The bimodal T(2) distributions are interpreted as a measurement of the spacing between clay particles within aggregates and between aggregates. Finally, the diffusion data can be gathered in an unique curve using the Debye length and the measured spacing between particles. When the thickness of the electro-diffuse layer (Debye length) is of the same order as the spacing between clay particles, the water diffusivity decreases. Otherwise it is constant at about 2.22+/-0.25x10(-9) m(2)/s. This last result illustrates clearly the effect of electro-chemical properties of smectite on water diffusivity.

  17. Relation between Quick Clay Formation by Salt Leaching and Pore-water Ion Composition


    安部, 宏; ヘ, パニー; 大坪, 政美; 東, 孝寛; 金山, 素平


    Several studies have reported that quick clay can be formed artificially by salt-leaching treatment on undisturbed Ariake clay. In the present study, however, artificial salt-leaching on the undisturbed clay taken from a site in Shiroishi-cho of Saga Prefecture failed to produce quick clay. To identify the cause, pore-water chemistry of the clay was assessed and the predominance of divalent cation in pore water was found to be responsible for the poor development of quick clay. Assuming that ...

  18. Harnessing Water and Resources from Clay Minerals on Mars and Planetary Bodies (United States)

    Bishop, J. L.


    Clay minerals provide a source of water, metals, and cations that can be harvested to provide resources for human exploration on Mars, asteroids, etc. Planning how to access these resources from clays could be a vital component of human exploration.

  19. Modelling unfrozen water content in a silty clay permafrost deposit

    DEFF Research Database (Denmark)

    Agergaard, Frederik Ancker; Ingeman-Nielsen, Thomas


    The mechanical properties of both unfrozen soils and permafrost soils are influenced by the amount of unfrozen water in the pore space. When dealing with foundation engineering in permafrost areas it is essential to estimate the unfrozen water content (wu). This paper deals with the establishing...... of a calibration equation for determining the unfrozen water content of a Greenlandic silty clay permafrost deposit. Calibration experiments have been conducted for water contents in the interval 0 – 10 % at both 5 °C and 22 °C. Calibration equations are verified against permittivity data from a permafrost core...... of material properties similar to the test soil. The calibration for 5°C is seen to make a good fit to the permafrost core data. Further experiments should be performed in order to extend the range of water contents tested and hence the range of validity of the calibration equation....

  20. Change of microstructure of clays due to the presence of heavy metal ions in pore water

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    Saiyouri N.


    Full Text Available The compressibility of engineered barrier clays is, to a large extent, controlled by microstructure change due to the presence of chemical ions in clay-water system. This paper aims to investigate the change of microstructure of clays due to the presence of heavy metal ions in pore water. We use two pure clays (kaolinite and bentonite in the study. One-dimensional consolidation tests were performed on reconstituted samples, which are prepared with distilled water and three types of heavy metal solutions (Pb(NO32, Cu(NO32, Zn(NO32,. In order to better understand the impact of chemical pore fluid on microstructure of the two clays, following the consolidation test, scanning electron microscope (SEM observations and mercury intrusion pore size distribution measurements (MIP were conducted. Due to the measurement range of MIP, which is only allowed to measure the minimal pore size 20 Å, BET method by gas sorption, whose measurement pore size range is from 3.5 Å to 500 Å, is used to measure the micropore size distribution. By this method, specific surface area of the soils can be also determined. It can be employed to demonstrate the difference of creep performance between the soils. Furthermore, a series of batch equilibrium tests were conducted to better understand the physical-chemical interactions between the particles of soils and the heavy metal ions. With the further consideration of the interparticle electrical attractive and repulsive force, an attempt has been made to predict the creep behaviour by using the modified Gouy-Chapman double layer theory. The results of calculation were compared with that of tests. The comparison shows that the prediction of compressibility of the clays according to the modified double diffuse layer theory can be reasonably agreement with the experimental data.

  1. Geology, Surficial - CLAY_ILITH_IN: Total Thickness of Clay in Indiana, Derived from the iLITH Water-Well Database (Indiana Geological Survey, Grid) (United States)

    NSGIC GIS Inventory (aka Ramona) — CLAY_ILITH_IN is a grid that shows total thickness of clay, as derived from logs of water wells in the state of Indiana. (It presents the same data as shown in a...

  2. Geology, Surficial - CLAY_ILITH_PTS_IN: Total Thickness of Clay in Indiana, Derived from the iLITH Water-Well Database (Indiana Geological Survey, Point Shapefile) (United States)

    NSGIC GIS Inventory (aka Ramona) — CLAY_ILITH_PTS_IN is a point shapefile that shows total thickness of clay, as derived from logs of water wells in the state of Indiana. (It presents the source data...

  3. Magnetic orientation of nontronite clay in aqueous dispersions and its effect on water diffusion. (United States)

    Abrahamsson, Christoffer; Nordstierna, Lars; Nordin, Matias; Dvinskikh, Sergey V; Nydén, Magnus


    The diffusion rate of water in dilute clay dispersions depends on particle concentration, size, shape, aggregation and water-particle interactions. As nontronite clay particles magnetically align parallel to the magnetic field, directional self-diffusion anisotropy can be created within such dispersion. Here we study water diffusion in exfoliated nontronite clay dispersions by diffusion NMR and time-dependant 1H-NMR-imaging profiles. The dispersion clay concentration was varied between 0.3 and 0.7 vol%. After magnetic alignment of the clay particles in these dispersions a maximum difference of 20% was measured between the parallel and perpendicular self-diffusion coefficients in the dispersion with 0.7 vol% clay. A method was developed to measure water diffusion within the dispersion in the absence of a magnetic field (random clay orientation) as this is not possible with standard diffusion NMR. However, no significant difference in self-diffusion coefficient between random and aligned dispersions could be observed.

  4. An Aquifer Reflections on Deep Clay Conditions for Water Quantity Assessments

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    Sabariah Musa


    Full Text Available This study aims to evaluate the on-site testing of deep clay area through the well response and aquifer reflection analysis. The analysis was conducted using AQTESOLV software on pumping and recovery data to determine the well responses and aquifer characteristics of deep clay area. A simple experimental model was installed at the site using deep well of REWES (Recharge Well System model assists with four monitoring wells around the model. The monitoring wells were located at 4m, 10m, 20m and 35m from the model. The site has been identified identified to have the unconfined aquifer with deep compacted clay. Due to flatten and low flow, pumping analysis and ground water response were used to evaluate water quantity and potential prospective of circulate water cycle for urban stormwater management. As reflection on water cycle, almost 20% from withdrawal capacity able to refill the ground system with limited space. It was found that the available storage, S and hydraulic conductivity, K  of the clayey area are 0.001 and 32 m/day respectively. Therefore, the response on water cycle indicate some potential space to restore and withdrawal at peak time and thus, the  water can be used in safely conditions.

  5. Modeling and Simulation of Virtual Clay Pigeon shooter Training System

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    Jin Yanxia


    Full Text Available As a popular sports event, clay pigeon uses real guns and bullets as its tools. To improve the training effect, reduce its cost and danger, the development of a real-time interactive and perceptive virtual training system by using simulation technology becomes urgent. This system uses Visual C++、Vega、Creator as its development platform to conduct modeling and simulation of clay pigeon’s and grapeshot ‘s flying path and the collision effect of the two objects.  

  6. Preparation of nanocomposites polyurethane water bone with clay montmorillonite sodica and organophilic clay;Preparacao de nanocompositos a base de dispersoes aquosas de poliuretano com argilas hidrofilica e organofilica

    Energy Technology Data Exchange (ETDEWEB)

    Garcia, Claudia P. [Sunchemical do Brasil Ltda., Rio de Janeiro, RJ (Brazil); Delpech, Marcia C.; Coutinho, Fernanda M.B.; Mello, Ivana L. [Universidade do Estado do Rio de Janeiro (IQ/UERJ), RJ (Brazil). Inst. de Quimica


    Nanocomposites based on water bone polyurethane (NWPU's) were synthesized based on poli(propylene glycol), dimethylolpropionic acid (DMPA), isophorone diisocyanate (IPDI) and hydrazine (HYD), as chain extender. Two kinds of clays were employed: hydrophilic and organophilic. The nanocomposites were characterized by infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electronic microscopy (SEM) and the mechanical properties were evaluated. The FTIR results showed the presence of specific groups of clay and the XRD suggested that occurred their intercalation/exfoliation through polyurethane matrix. The mechanical resistance of the systems showed significant increase when compared to water dispersions synthesized without clay. (author)

  7. Evaluation of the Efficiency of Clay Pots in Removal of Water Impurities

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    K Naddafi , AH Mahvi, S Nasseri, M Mokhtari, H Zeraati


    Full Text Available Recently, inexpensive technologies for drinking water supply in small communities are highly considered in developing countries. One of these technologies is the application of ceramic filters that are usually made of diatomaceous earth or clay soil. This research was carried out to determine the efficiency of clay pots (as a filter in removing water impurities. Pilot and the related clay parts were manufactured and its efficiency in removing TDS, hardness, NO3-, color and turbidity was measured by passing water through the clay pipes. The results showed that the clay filters had not the potential to remove hardness, EC, TDS and nitrate of water. However, they showed excellent efficiency in turbidity removal (≥ 90% and could significantly decrease the color of the water (≥ 60%.

  8. Impact factors on the structuration and the rheological behavior of the clay-water system for smectite dispersions; Facteurs determinant l'organisation et la rheologie du systeme argile-eau pour des suspensions de smectites

    Energy Technology Data Exchange (ETDEWEB)

    Paumier, S


    Smectite are swelling clays widely used in industry. Their mechanical properties are unequal according to their mineralogical and physico-chemical characteristics. The aim of this study is to improve the knowledge of the interlayer cation impact on the structure built by the smectite-water system according to the concentration. Homo-ionic (Na{sup +} et Ca{sup 2+}) and bi-ionic systems are observed. This study cross checks mineralogical methods, physicochemical analysis and broad range of rheometric tests. At low concentration (less than 60 g/l) the calcium dispersions are shear thinning and few viscous due to the layer association in huge deformable flocks. The sodium smectite layers are dispersed; the dispersions are highly viscous. The lowest viscosity is detected for mix of 20 % of sodium smectite and 80 % of calcium smectite. At higher concentration (60 to 100 g/l), the yield stress and viscoelastic properties are studied by creep-recovery tests, oscillatory tests and imposed shear step. At the liquid state, the flow is first heterogeneous with a shear banding effect then homogeneous. The results make it possible to define the concentration area characteristic of each mechanical behavior (viscosity, shear thinning and yield stress) according to the saturation cation. The thixotropic properties are characterized with de-structuring-restructuring tests. Two kinetics are determined. Finally we realize a data base with 12 natural and industrial bentonite. The rheograms would be efficient to differentiate the natural calcium bentonite (Newtonian law), natural sodium bentonite (Herschel-Bulkley law) and activated calcium bentonite (Bingham law). (author)

  9. Gas equilibration and pore water sampling experiment in the opalinus clay at the Mont Terri rock laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Vinsot, A. [Agence Nationale pour la Gestion des Dechets Radioactifs (ANDRA), Lab. de recherche souterrain 92 - Chatenay Malabry (France); Fierz, T. [Solexperts, Schwerzenbach (Switzerland); Cailteau, C.; Donato, P. de [Institut National Polytechnique, LEM, UMR 7569 CNRS, ENSG/INPL, 54 - Vandoeuvre-les-Nancy (France); Cailteau, C.; Pironon, J. [G2R-CREGU (UMR 7566 CNRS), 54 - Vandoeuvre-les-Nancy (France); Pepa, S. [Metro Mesures, 91 - Mennecy (France); Wersin, P. [National Cooperative for the Disposal of Radioactive Waste (NAGRA), Wettingen (Switzerland); Canniere, P. de [SCK-CEN, Mol (Belgium); Gubler, H.E. [Bundesanstalt fur Geowissenschaften und Rohstoffe (BGR), Hannover (Germany); Badertscher, N. [Geotechnical Institute, St-Ursanne (Switzerland); Eichinger, L. [Hydroisotop, Schweitenkirchen (Germany)


    The study of the mechanisms governing the composition of the interstitial fluids in clay formations with very low permeability constitutes a part of the scientific programmes associated with the feasibility analyses of deep repositories for the geological disposal of long-lived radioactive waste. Several in-situ geochemical experiments have been performed since 1996 in the Mont Terri Rock Laboratory to develop methods for studying these mechanisms in the Opalinus Clay formation. These experiments enabled to build a conceptual model of the interstitial water in the Opalinus Clay. The main uncertainties of this model deal with the carbonate system and the redox state of the water. Consecutively, the PC-C experiment was initiated in 2003 to reduce these uncertainties using: i) a gas equilibration, and, ii) isobar water sampling. (authors)

  10. Suitable Types and Constituent Ratios for Clay-Pot Water Filters to Improve the Physical and Bacteriological Quality of Drinking Water

    Directory of Open Access Journals (Sweden)

    Watcharaporn Wongsakoonkan


    Full Text Available This study aimed to investigate suitable types and ratios of materials for making clay-pots, and their performance to improve the physical and bacteriological quality of drinking water. Synthetic water was prepared and used to select suitable types and ratios for clay-pot water filters. The clay-pots were prepared by combining clay with sand, coconut-shell charcoal, and rice-husk charcoal, at various ratios. The results indicated that all types and ratios could remove 100% of coliform bacteria and Escherichia coli, and were thus suitable for treating drinking water. However, for practical use, the system should have real-world application. Therefore, filtration rate/inner surface area/time was used as a criterion to determine suitable types and ratios. Different types of clay-plot water filter yielded significantly different filtration rates (p 0.01. A ratio with a maximal filtration rate of 60:40(0.38 ± 0.28 mL/cm2/hr was found to be suitable. The quality of filtered water was acceptable in terms of turbidity, coliform bacteria level, and Escherichia coli, according to WHO drinking-water quality guidelines.

  11. Translational diffusion of water and its dependence on temperature in charged and uncharged clays: A neutron scattering study. (United States)

    González Sánchez, Fátima; Jurányi, Fanni; Gimmi, Thomas; Van Loon, Luc; Unruh, Tobias; Diamond, Larryn W


    The water diffusion in four different, highly compacted clays [montmorillonite in the Na- and Ca-forms, illite in the Na- and Ca-forms, kaolinite, and pyrophyllite (bulk dry density rho(b)=1.85+/-0.05 gcm(3))] was studied at the atomic level by means of quasielastic neutron scattering. The experiments were performed on two time-of-flight spectrometers and at three different energy resolutions [FOCUS at SINQ, PSI (3.65 and 5.75 A), and TOFTOF at FRM II (10 A)] for reliable data analysis and at temperatures between 27 and 95 degrees C. Two different jump diffusion models were used to describe the translational motion. Both models describe the data equally well and give the following ranking of diffusion coefficients: Na-montmorillonitewaterwater due to their hydrophobic surfaces. The time between jumps, tau(t), follows the sequence: Ca-montmorillonite>or=Na-montmorillonite>Ca-illite>Na-illite>or=kaolinite>pyrophyllite>or=water, in both jump diffusion models. For clays with a permanent layer charge (montmorillonite and illite) a reduction in the water content by a factor of 2 resulted in a decrease in the self-diffusion coefficients and an increase in the time between jumps as compared to the full saturation. The uncharged clay kaolinite exhibited no change in the water mobility between the two hydration states. The rotational relaxation time of water was affected by the charged clay surfaces, especially in the case of montmorillonite; the uncharged clays presented a waterlike behavior. The activation energies for translational diffusion were calculated from the Arrhenius law, which adequately describes the systems in the studied temperature range. Na- and Ca-montmorillonite (approximately 11-12 kJmol), Na-illite (approximately 13 kJmol), kaolinite and pyrophyllite (approximately 14 kJmol), and Ca-illite (approximately 15 kJmol) all had lower activation energies than bulk water (approximately 17 kJmol in this study). This may originate from the reduced number and

  12. Nondestructive Measurement of Water Content and Moisture Migration of Unsaturated Red Clays in South China

    Directory of Open Access Journals (Sweden)

    Junhui Zhang


    Full Text Available To reveal the moisture migration mechanism of the unsaturated red clays, which are sensitive to water content change and widely distributed in South China, and then rationally use them as a filling material for highway embankments, a method to measure the water content of red clay cylinders using X-ray computed tomography (CT was proposed and verified. Then, studies on the moisture migrations in the red clays under the rainfall and ground water level were performed at different degrees of compaction. The results show that the relationship between dry density, water content, and CT value determined from X-ray CT tests can be used to nondestructively measure the water content of red clay cylinders at different migration time, which avoids the error reduced by the sample-to-sample variation. The rainfall, ground water level, and degree of compaction are factors that can significantly affect the moisture migration distance and migration rate. Some techniques, such as lowering groundwater table and increasing degree of compaction of the red clays, can be used to prevent or delay the moisture migration in highway embankments filled with red clays.

  13. Acidities of confined water in interlayer space of clay minerals

    NARCIS (Netherlands)

    Liu, X.; Lu, X.; Wang, R.; Meijer, E.J.; Zhou, H.


    The acid chemistry of confined waters in smectite interlayers have been investigated with first principles molecular dynamics (FPMD) simulations. Aiming at a systematic picture, we establish the model systems to take account of the three possible controlling factors: layer charge densities (0 e, 0.5

  14. Evaluation of Water Vapor Sorption Hysteresis in Soils: The Role of Organic Matter and Clay

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Tuller, Markus; Moldrup, Per


    Hysteresis of the soil water characteristic (SWC) has been extensively studied for matric potentials between zero and −1.5 MPa. However, little information is available on how to quantify, evaluate, and identify the causes of hysteresis at potentials below −10 MPa where vapor sorption plays...... an important role. It is clear that modeling physical and biological soil processes is more accurate when SWC hysteresis is considered, particularly at low potentials where small differences in water content are associated with large changes in potential energy. The objectives of the presented study were to......: (i) evaluate and compare recently developed methods (MBET-n, Dh and SPN) for quantifying hysteresis in soils and pure clays, and (ii) investigate the role of organic matter (OM) and clay content and type on hysteresis. Five pure clays and two sets of soils with gradients in organic matter and clay...

  15. Integrated modelling of the glass-iron-clay system

    Energy Technology Data Exchange (ETDEWEB)

    Bildstein, O


    This report summarizes the results of integrated calculations on the near-field evolution in the VHLW/steel/bentonite/clay system. The calculations of the near-field evolution include different components: the vitrified waste packages, the steel container, the bentonite-based EBS (optional), the EDZ and the geological medium. Coupled reaction-transport (X-T) is used to simulate the corrosion of the steel canister and the glass alteration phase in presence of corrosion products (CPs), looking at mass transfer for chemical elements, especially iron and silica, pH, and porosity change. Calculations as performed give actual parameters for PA calculations: rate of glass alteration (through the calculated pH) as a function of time, extension of altered zone for iron-clay interactions with their own transport parameters, nature of CPs, effect on porosity distribution. According to the operational model currently used at the CEA and the calculations performed on the glass-iron-clay system, the alteration rate of glass and the evolution of the system strongly depend on the timing of CPs saturation with respect to silica sorption. The fate of silica which can be sorbed or precipitate is crucial to the lifetime of glass and to the overall evolution of the system. The other process that might influence the glass is the porosity decrease due to the precipitation of CPs and silica rich phases. However, it is difficult to assign a safety functions to clogging. It is scarcely observed in experiments, either because the conditions are not met for clogging or because the timescale of experiments does not allow for observable clogging. Moreover, the effect of mechanical stress in the NF has to be accounted for in the assessment of the effect of porosity changes. (author)

  16. Bioremediating oil spills in nutrient poor ocean waters using fertilized clay mineral flakes: some experimental constraints. (United States)

    Warr, Laurence N; Friese, André; Schwarz, Florian; Schauer, Frieder; Portier, Ralph J; Basirico, Laura M; Olson, Gregory M


    Much oil spill research has focused on fertilizing hydrocarbon oxidising bacteria, but a primary limitation is the rapid dilution of additives in open waters. A new technique is presented for bioremediation by adding nutrient amendments to the oil spill using thin filmed minerals comprised largely of Fullers Earth clay. Together with adsorbed N and P fertilizers, filming additives, and organoclay, clay flakes can be engineered to float on seawater, attach to the oil, and slowly release contained nutrients. Our laboratory experiments of microbial activity on weathered source oil from the Deepwater Horizon spill in the Gulf of Mexico show fertilized clay treatment significantly enhanced bacterial respiration and consumption of alkanes compared to untreated oil-in-water conditions and reacted faster than straight fertilization. Whereas a major portion (up to 98%) of the alkane content was removed during the 1 month period of experimentation by fertilized clay flake interaction; the reduced concentration of polyaromatic hydrocarbons was not significantly different from the non-clay bearing samples. Such clay flake treatment could offer a way to more effectively apply the fertilizer to the spill in open nutrient poor waters and thus significantly reduce the extent and duration of marine oil spills, but this method is not expected to impact hydrocarbon toxicity.

  17. Bioremediating Oil Spills in Nutrient Poor Ocean Waters Using Fertilized Clay Mineral Flakes: Some Experimental Constraints

    Directory of Open Access Journals (Sweden)

    Laurence N. Warr


    Full Text Available Much oil spill research has focused on fertilizing hydrocarbon oxidising bacteria, but a primary limitation is the rapid dilution of additives in open waters. A new technique is presented for bioremediation by adding nutrient amendments to the oil spill using thin filmed minerals comprised largely of Fullers Earth clay. Together with adsorbed N and P fertilizers, filming additives, and organoclay, clay flakes can be engineered to float on seawater, attach to the oil, and slowly release contained nutrients. Our laboratory experiments of microbial activity on weathered source oil from the Deepwater Horizon spill in the Gulf of Mexico show fertilized clay treatment significantly enhanced bacterial respiration and consumption of alkanes compared to untreated oil-in-water conditions and reacted faster than straight fertilization. Whereas a major portion (up to 98% of the alkane content was removed during the 1 month period of experimentation by fertilized clay flake interaction; the reduced concentration of polyaromatic hydrocarbons was not significantly different from the non-clay bearing samples. Such clay flake treatment could offer a way to more effectively apply the fertilizer to the spill in open nutrient poor waters and thus significantly reduce the extent and duration of marine oil spills, but this method is not expected to impact hydrocarbon toxicity.

  18. Simulation of Water-Resistance of a Clay Layer During Mining: Analysis of a Safe Water Head

    Institute of Scientific and Technical Information of China (English)

    DONG Qing-hong; CAI Rong; YANG Wei-feng


    Given previous research and prototypical geological conditions of a mining workface, we simulated fissure development in clay layers at the bottom of Quaternary strata and above bedrock, sand and water inrush during mining by model experiments. The results show that V-shaped fissures usually occur in the bottom clay layer at the front top of the active face and that the position of these fissures changes periodically with ground pressure intervals. These fissures occur exactly in the area where the horizontal strain is concentrated. The results also demonstrate that the permeability coefficient of the cracked clay decreases while fissures tend to close. The permeability of the cracked bottom clay layer increases rapidly after a turning point in the permeability coefficient-water head curve (K-H curve) under a certain vertical load. Under static water pressure, the permeability coefficient of cracked clay decreases when load increases. A turning point in the K-H curve showed up and can be seen as a cutoff point to decide water inrush under a certain load level. Under an instantaneous water head, the greatest ability of the cracked clay to avoid drastic water inflow is a little higher than that under static conditions.

  19. Influence of Water Content on the Mechanical Behaviour of Limestone: Role of the Clay Minerals Content (United States)

    Cherblanc, F.; Berthonneau, J.; Bromblet, P.; Huon, V.


    The mechanical characteristics of various sedimentary stones significantly depend on the water content, where 70 % loss of their mechanical strengths can be observed when saturated by water. Furthermore, the clay fraction has been shown to be a key factor of their hydro-mechanical behaviour since it governs for instance the hydric dilation. This work aims at investigating the correlations between the clay mineral content and the mechanical weakening experienced by limestones when interacting with water. The experimental characterization focuses on five different limestones that exhibit very different micro-structures. For each of them, we present the determination of clay mineral composition, the sorption isotherm curve and the dependences of tensile and compressive strengths on the water content. It emerges from these results that, first, the sorption behaviour is mainly governed by the amount of smectite layers which exhibit the larger specific area and, second, the rate of mechanical strength loss depends linearly on the sorption capacity. Indeed, the clay fraction plays the role of a retardation factor that delays the appearance of capillary bridges as well as the mechanical weakening of stones. However, no correlation was evidenced between the clay content and the amplitude of weakening. Since the mechanisms whereby the strength decreases with water content are not clearly established, these results would help to discriminate between various hypothesis proposed in the literature.

  20. Sequential energy and electron transfer in a three-component system aligned on a clay nanosheet. (United States)

    Fujimura, Takuya; Ramasamy, Elamparuthi; Ishida, Yohei; Shimada, Tetsuya; Takagi, Shinsuke; Ramamurthy, Vaidhyanathan


    To achieve the goal of energy transfer and subsequent electron transfer across three molecules, a phenomenon often utilized in artificial light harvesting systems, we have assembled a light absorber (that also serves as an energy donor), an energy acceptor (that also serves as an electron donor) and an electron acceptor on the surface of an anionic clay nanosheet. Since neutral organic molecules have no tendency to adsorb onto the anionic surface of clay, a positively charged water-soluble organic capsule was used to hold neutral light absorbers on the above surface. A three-component assembly was prepared by the co-adsorption of a cationic bipyridinium derivative, cationic zinc porphyrin and cationic octaamine encapsulated 2-acetylanthracene on an exfoliated anionic clay surface in water. Energy and electron transfer phenomena were monitored by steady state fluorescence and picosecond time resolved fluorescence decay. The excitation of 2-acetylanthracene in the three-component system resulted in energy transfer from 2-acetylanthracene to zinc porphyrin with 71% efficiency. Very little loss due to electron transfer from 2-acetylanthracene in the cavitand to the bipyridinium derivative was noticed. Energy transfer was followed by electron transfer from the zinc porphyrin to the cationic bipyridinium derivative with 81% efficiency. Analyses of fluorescence decay profiles confirmed the occurrence of energy transfer and subsequent electron transfer. Merging the concepts of supramolecular chemistry and surface chemistry we realized sequential energy and electron transfer between three hydrophobic molecules in water. Exfoliated transparent saponite clay served as a matrix to align the three photoactive molecules at a close distance in aqueous solutions.

  1. Glass transition and relaxation dynamics of propylene glycol-water solutions confined in clay (United States)

    Elamin, Khalid; Björklund, Jimmy; Nyhlén, Fredrik; Yttergren, Madeleine; Mârtensson, Lena; Swenson, Jan


    The molecular dynamics of aqueous solutions of propylene glycol (PG) and propylene glycol methylether (PGME) confined in a two-dimensional layer-structured Na-vermiculite clay has been studied by broadband dielectric spectroscopy and differential scanning calorimetry. As typical for liquids in confined geometries the intensity of the cooperative α-relaxation becomes considerably more suppressed than the more local β-like relaxation processes. In fact, at high water contents the calorimetric glass transition and related structural α-relaxation cannot even be observed, due to the confinement. Thus, the intensity of the viscosity related α-relaxation is dramatically reduced, but its time scale as well as the related glass transition temperature Tg are for both systems only weakly influenced by the confinement. In the case of the PGME-water solutions it is an important finding since in the corresponding bulk system a pronounced non-monotonic concentration dependence of the glass transition related dynamics has been observed due to the growth of hydrogen bonded relaxing entities of water bridging between PGME molecules [J. Sjöström, J. Mattsson, R. Bergman, and J. Swenson, Phys. Chem. B 115, 10013 (2011)]. The present results suggest that the same type of structural entities are formed in the quasi-two-dimensional space between the clay platelets. It is also observed that the main water relaxation cannot be distinguished from the β-relaxation of PG or PGME in the concentration range up to intermediate water contents. This suggests that these two processes are coupled and that the water molecules affect the time scale of the β-relaxation. However, this is most likely true also for the corresponding bulk solutions, which exhibit similar time scales of this combined relaxation process below Tg. Finally, it is found that at higher water contents the water relaxation does not merge with, or follow, the α-relaxation above Tg, but instead crosses the

  2. Preparation of thermally stable well-dispersed water-soluble CdTe quantum dots in montmorillonite clay host media. (United States)

    Cao, Yuan-Cheng


    In this work, a method to prepare a thermally stable QDs/clay powder is reported. First, several water soluble CdTe QDs characterised by different size-dependent emission wavelengths were synthesised through wet chemistry. Montmorillonite-Na(+) clay in water was dispersed into a muddy suspension by sonication. Then, the clay-water suspension was used as the host media for CdTe QDs to prepare the QDs/clay powder by freeze drying. The experiments showed that QDs/clay powder could be re-dispersed in water without changing the luminescent property of the QDs; this process was reversible. EDX showed that Cd and Te elements existed in the QDs/clay powder and the XRD tests showed that the clay [001] reflection peaks for raw clay, QDs (λ(em)=514 nm)/clay and QDs (λ(em)=560 nm)/clay were the same, namely 2θ=7.4°. Finally, QDs/clay powder was applied to the HDPE polymer extrusion process at 200 °C to produce thin films; the resultant QDs-polymer nanocomposite film exhibited strong fluorescence.

  3. Subsurface water and clay mineral formation during the early history of Mars. (United States)

    Ehlmann, Bethany L; Mustard, John F; Murchie, Scott L; Bibring, Jean-Pierre; Meunier, Alain; Fraeman, Abigail A; Langevin, Yves


    Clay minerals, recently discovered to be widespread in Mars's Noachian terrains, indicate long-duration interaction between water and rock over 3.7 billion years ago. Analysis of how they formed should indicate what environmental conditions prevailed on early Mars. If clays formed near the surface by weathering, as is common on Earth, their presence would indicate past surface conditions warmer and wetter than at present. However, available data instead indicate substantial Martian clay formation by hydrothermal groundwater circulation and a Noachian rock record dominated by evidence of subsurface waters. Cold, arid conditions with only transient surface water may have characterized Mars's surface for over 4 billion years, since the early-Noachian period, and the longest-duration aqueous, potentially habitable environments may have been in the subsurface.

  4. Modified Liu-Carter Compression Model for Natural Clays with Various Initial Water Contents

    Directory of Open Access Journals (Sweden)

    Sen Qian


    Full Text Available The initial water content has a significant effect on the compression behaviour of reconstituted clays. This effect has to be considered in the Liu-Carter model to ensure the addition voids ratio only related to soil structure. A modified Liu-Carter compression model is proposed by introducing the empirical equations for reconstituted clays at different initial water contents into the Liu-Carter model. The proposed model is verified against the experimental results from the literature. The simulations by the proposed method are also compared with that by old method where the influence of initial water content is not considered. The results show that the predicted virgin compression curves of natural clays are similar, but the values of b and Δey may be very different.

  5. The effect of very low water content on the complex dielectric permittivity of clays, sand-clay and sand rocks (United States)

    Belyaeva, T. A.; Bobrov, P. P.; Kroshka, E. S.; Lapina, A. S.; Rodionova, O. V.


    The results of measurements of complex relative permittivity of bentonite and clayey sandstone with different degrees of salinity with low moisture are given in the range of temperatures -20° to  +105 °C at frequencies from 25 Hz to 1 GHz. It is shown, that even a small amount of water in sandy and sandy-argillaceous rocks causes an increase of the real part of complex relative permittivity at frequencies below 100 Hz. The explanation by linearly-broken dependence of refractive index on moisture is given at its small values. By a dielectric method it is shown that in the process of water film formation on the surface of a mineral, the water molecules binding energy changes. Big distinctions in low-frequency dielectric relaxation times testify to the change of binding energy of molecules of water on the surface of a mineral. Also dependences of relaxation times on temperature are various. The results of dielectric measurements showed a strong influence of the salt on the dielectric permittivity of the clay and clayey sandstone even at a low moisture level.

  6. Removal of Chromate Ions from Water by Anionicc CLAYS (United States)

    Houri, B.; Legrouri, A.; Barroug, A.; Forano, C.; Besse, J.-P.


    The removal of chromate ions from aqueous solutions by [Mg-Al-Cl], [Zn-Al-Cl] and [Zn-Cr-Cl] anionic clays was investigated. The solids, prepared by coprecipitation at constant pH, were found to be pure upon characterisation by X-ray diffraction and Fourier-transform infrared spectroscopy. The interaction of the solid materials with CrO42- ions has been studied by UV-visible spectroscopy. The treatment of solutions containing 15 to 300 ppm of CrO42- was successful. The sorption capacities of the anionic clays for the CrO42- ions are close to 1 mmol/g. L'élimination des ions chromate de solutions aqueuses par les argiles anioniques [Mg-Al-Cl], [Zn-Al-Cl] et [Zn-Cr-Cl] a été étudiée. Les solides, préparés par coprécipitation à pH constant, ont été caractérisés par diffraction des rayons X et spectroscopie infrarouge à transformée de Fourier. L'interaction de ces matériaux avec les ions CrO42- a été suivie par spectroscopie UV-visible. Le traitement de solutions contenant de 15 à 300 ppm de CrO42- a donné de bons résultats. La capacité d'élimination de ces argiles anioniques pour les ions CrO42- est d'environ 1 mmol/g. .

  7. Water movement and isoproturon behaviour in a drained heavy clay soil: 1. Preferential flow processes (United States)

    Haria, A. H.; Johnson, A. C.; Bell, J. P.; Batchelor, C. H.


    The processes and mechanisms that control pesticide transport from drained heavy clay catchments are being studied at Wytham Farm (Oxford University) in southern England. In the first field season field-drain water contained high concentrations of pesticide. Soil studies demonstrated that the main mechanism for pesticide translocation was by preferential flow processes, both over the soil surface and through the soil profile via a macropore system that effectively by-passed the soil matrix. This macropore system included worm holes, shrinkage cracks and cracks resulting from ploughing. Rainfall events in early winter rapidly created a layer of saturation in the A horizon perched above a B horizon of very low hydraulic conductivity. Drain flow was initiated when the saturated layer in the A horizon extended into the upper 0.06m of the soil profile; thereafter water moved down slope via horizontal macropores possibly through a band of incorporated straw residues. These horizontal pathways for water movement connected with the fracture system of the mole drains, thus feeding the drains. Overland flow occurred infrequently during the season.

  8. Water adsorption constrained Frenkel-Halsey-Hill adsorption activation theory: Montmorillonite and illite clays (United States)

    Hatch, C. D.; Greenaway, A.; Christie, M. J.; Baltrusaitis, J.


    Recently, fresh, unprocessed mineral aerosol has been found to contribute to the number of available cloud condensation nuclei (CCN) and cloud droplets in the atmosphere due to the effect of water adsorption on CCN activation. The work described here uses experimental water adsorption measurements on montmorillonite and illite clay to determine empirical adsorption parameters for a recently derived theoretical framework (Frenkel-Halsey-Hill Activation Theory, FHH-AT) used to calculate CCN activities of clay minerals. Upon fitting the Frenkel-Halsey-Hill (FHH) adsorption model to experimental water adsorption measurements, we find FHH adsorption parameters, AFHH and BFHH, to be 98×22 and 1.79×0.11 for Na-montmorillonite and 75×17 and 1.77×0.11 for illite, respectively. The AFHH and BFHH values obtained for these clays are significantly different from FHH adsorption parameters derived from CCN activation measurements reported previously for similar clay minerals. Differences in FHH adsorption parameters were attributed to the different approaches used, the hydratable nature of the clays and the relative difficulty in measuring CCN activation of hydratable clays due to relatively long adsorption and desorption equilibration times. However, despite these differences, the calculated CCN activities of montmorillonite and illite are quite similar and are in excellent agreement with experimental CCN activation measurements reported previously for similar clays. The different FHH adsorption parameters, however, translate to lower sc-Ddry CCN activation curve exponents (xFHH = -0.61 and -0.64 for montmorillonite and illite, respectively) than have been reported previously. The lower exponent suggests that the CCN activity of hydratable clay aerosol is less sensitive to changes in dry particle diameter (Ddry) and the hygroscopicity parameter exhibits a broader variability with Ddry compared to more soluble aerosols. This study illustrates that FHH-AT using adsorption

  9. Unaffected microscopic dynamics of macroscopically arrested water in dilute clay gels (United States)

    Seydel, Tilo; Wiegart, Lutz; Juranyi, Fanni; Struth, Bernd; Schober, Helmut


    Adequate clay minerals considerably affect the macroscopic mechanical behavior of water even at concentrations of a few percent. Thus when 2wt.% laponite clay mineral nanoparticles are added to water, the resulting colloidal suspension after some time takes on the semisolid characteristics of a jellylike material at room temperature. Cold neutron time-of-flight spectroscopy data are in agreement with the assumption that notwithstanding this macroscopic change, the mobility of the water molecules on intermolecular and intramolecular length scales remains largely unaffected. This observation is discussed in the context of the properties and the role of water in different more or less dilute ionic environments. The result contributes to the ongoing debate of the properties and role of water in living cells.

  10. Effects of clay amendment on adsorption and desorption of copper in water repellent soils

    NARCIS (Netherlands)

    Xiong, X.; Stagnitti, F.; Allinson, G.; Turoczy, N.; Li, P.; LeBlanc, M.; Cann, M.A.; Doerr, S.H.; Steenhuis, M.M.; Parlange, J.Y.; Rooij, de G.; Ritsema, C.J.; Dekker, L.W.


    Copper is an important micronutrient and trace amounts are essential for crop growth. However, high concentrations of copper will produce toxic effects. Australia is increasingly developing production of crops in water repellent soils. Clay amendment, a common amelioration techniques used in Austral

  11. Geomechanical and water vapor absorption characteristics of clay-bearing soft rocks at great depth

    Institute of Scientific and Technical Information of China (English)

    Zhang Na; Liu Longbiao; Hou Dongwen; He Manchao; Liu Yilei


    The geological and physico-mechanical properties characterization of deep soft rocks is one of the critical scientific issues for deep soft rock engineering. In the present study, X-ray diffraction (XRD) analysis, scanning electron microscope (SEM), and mercury intrusion porosimetry experiments were carried out to investigate the mineral compositions, microstructure and porosity characteristics of the 13 clay-bearing soft rock samples collected from a deep coal mine in China. Water vapor absorption and uniaxial compressive experiments were also performed to examine water absorption characteristics and water-induced strength degradation effect of the investigated deep soft rock samples. The results show that the dominant mineral components in mudstone, coarse sandstone and fine sandstone samples were calcite, quartz and clay respectively. The contents of clay minerals in all samples were relatively high and ranged from 12.3% (N-4) to 56.5% (XS-1). Water vapor absorption processes of all the soft rock samples follow an exponential law which is very similar to the water vapor absorption behavior of conglomerate samples reported in our earlier study. Correlation analyses also suggested that there were good positive correlation relationships between water absorptivity and clay minerals for both mudstone and sandstone samples. Furthermore, it was found that vapor absorption was not correlated with the porosity for mudstone, however, positive correlation relationship was found between them for sand-stone. Correlation analysis between UCS, modulus of elasticity and water content demonstrated that both of them tend to decrease with the increase of their water content due to water absorption.

  12. Premiminary tests on modified clays for electrolyte contaminated drilling fluids


    den Hamer, Davina; Di Emidio, Gemmina; Bezuijen, Adam; Verastegui Flores, Daniel


    The quality of a bentonite suspension declines in aggressive systems like brackish or saline pore water. An engineered clay (HYPER clay) was developed for sealing materials with enhanced resistance to aggressive conditions. The modified clay is produced by treating a sodium activated bentonite with a cellulose polymer following the HYPER clay process method. This study investigates the suitability of the modified clay for electrolyte contaminated drilling fluids. Drilling fluids become contam...

  13. Study of the Effect of Clay Particles on Low Salinity Water Injection in Sandstone Reservoirs

    Directory of Open Access Journals (Sweden)

    Sina Rezaei Gomari


    Full Text Available The need for optimal recovery of crude oil from sandstone and carbonate reservoirs around the world has never been greater for the petroleum industry. Water-flooding has been applied to the supplement primary depletion process or as a separate secondary recovery method. Low salinity water injection is a relatively new method that involves injecting low salinity brines at high pressure similar to conventional water-flooding techniques, in order to recover crude oil. The effectiveness of low salinity water injection in sandstone reservoirs depends on a number of parameters such as reservoir temperature, pressure, type of clay particle and salinity of injected brine. Clay particles present on reservoir rock surfaces adsorb polar components of oil and modify wettability of sandstone rocks to the oil-wet state, which is accountable for the reduced recovery rates by conventional water-flooding. The extent of wettability alteration caused by three low salinity brines on oil-wet sandstone samples containing varying clay content (15% or 30% and type of clay (kaolinite/montmorillonite were analyzed in the laboratory experiment. Contact angles of mica powder and clay mixture (kaolinite/montmorillonite modified with crude oil were measured before and after injection with three low salinity sodium chloride brines. The effect of temperature was also analyzed for each sample. The results of the experiment indicate that samples with kaolinite clay tend to produce higher contact angles than samples with montmorillonite clay when modified with crude oil. The highest degree or extent of wettability alteration from oil-wet to intermediate-wet state upon injection with low salinity brines was observed for samples injected with brine having salinity concentration of 2000 ppm. The increase in temperature tends to produce contact angles values lying in the higher end of the intermediate-wet range (75°–115° for samples treated at 50 °C, while their corresponding

  14. Simulation of Soil Water Content Variability in a Heavy Clay Soil under Contrasting Soil Managements (United States)

    Pedrera, A.; Vanderlinden, K.; Martínez, G.; Espejo, A. J.; Giráldez, J. V.


    Soil water content (SWC) is a key variable for numerous physical, chemical and biological processes that take place at or near the soil surface. Understanding the spatial and temporal variability of SWC at the field scale is of prime importance for implementing efficient measurement strategies in applications. The aim of this study was to characterize the spatial and temporal variation of gravimetric SWC in a heavy clay soil, in a wheat-sunflower-legume rotation under conventional (CT) and no-till (NT) using a simple water balance model. An experimental field in SW Spain, where conventional (CT) and no-till (NT) management of a heavy clay soil are being compared since 1983, was sampled for gravimetric SWC on 38 occasions during 2008 and 2009. Topsoil clay content across the six plots was on average 55%, with a standard deviation of 2.7%. The soil profile was sampled at 54 locations, evenly distributed over the three CT and NT plots, at depths of 0-10, 25-35, and 55-65 cm. Topsoil water retention curves (SWRC) were determined in the laboratory on undisturbed soil samples from each of the 54 locations. A weather station recorded daily precipitation and evapotranspiration, as calculated by the Penman-Monteith FAO equation. The water balance was calculated using the Thornthwaite-Mather model with a daily time step. Three parameters, water holding capacity, and water evaporation corrector coefficients for each of the two years, were inversely estimated at the 54 SWC observation points and probability density functions were identified. Spatial variability of SWC was estimated using a Monte Carlo approach, and simulated and observed variability were compared. This Monte Carlo scheme, using a simple water balance model with only three parameters, was found to be useful for evaluating the influence of soil management on the variability of SWC in heavy clay soils.

  15. An Aquifer Reflections on Deep Clay Conditions for Water Quantity Assessments


    Sabariah Musa; Nor Azazi Zakaria; Lau Tze Liang


    This study aims to evaluate the on-site testing of deep clay area through the well response and aquifer reflection analysis. The analysis was conducted using AQTESOLV software on pumping and recovery data to determine the well responses and aquifer characteristics of deep clay area. A simple experimental model was installed at the site using deep well of REWES (Recharge Well System) model assists with four monitoring wells around the model. The monitoring wells were located at 4m, 10m, 20m an...

  16. Experimental Evidence for Hyperfiltration of Saline Water through Compacted Clay Aquitard in the Hebei Plain

    Institute of Scientific and Technical Information of China (English)

    Ying Wang; Zongyu Chen; Baoqian Duan; Jingli Shao


    It becomes an increasing concern that groundwater quality in exploited deep confined aquifer may deteriorate due to brackish water leakage from its overlying saline aquifer in Hebei Plain. However, the monitoring data show that the TDS does not significantly change in the exploited aquifer. Some physics or chemistry processes must have taken place in aquitards during brackish leakage. The semi-permeable membrane function of clay aquitard during the process of hyperfiltration (reverse os-mosis) should be one of the most important processes. To confirm and test this hyperfiltration mecha-nism, a series of experiments were performed in which NaCl solutions were hydraulically forced through different clay sampled from aquitard. The solution 7 g/L in NaCl was forced through at 20 °C by a fluid pressure of 0.5 kN. The results show that hyperfiltration indeed happens in caly aquitard. Semi-permeability is quantified by the reflection coefficientσ. The mean rejection coefficients (σ) for clay samples #1, #2 and #3 were estimated to be 0.063, 0.164 and 0.040, respectively. This behavior of clay was well explained with the theory of the diffuse double layer. The hyperfiltration effect is to the great extent responsible for the chemical process in the aquitard.

  17. Radionuclide interaction with clays in dilute and heavily compacted systems: a critical review. (United States)

    Miller, Andrew W; Wang, Yifeng


    Given the unique properties of clays (i.e., low permeability and high ion sorption/exchange capacity), clays or clay formations have been proposed either as an engineered material or as a geologic medium for nuclear waste isolation and disposal. A credible evaluation of such disposal systems relies on the ability to predict the behavior of these materials under a wide range of thermal-hydrological-mechanical-chemical (THMc) conditions. Current model couplings between THM and chemical processes are simplistic and limited in scope. This review focuses on the uptake of radionuclides onto clay materials as controlled by mineral composition, structure, and texture (e.g., pore size distribution), and emphasizes the connections between sorption chemistry and mechanical compaction. Variable uptake behavior of an array of elements has been observed on various clays as a function of increasing compaction due to changes in pore size and structure, hydration energy, and overlapping electric double layers. The causes for this variability are divided between "internal" (based on the fundamental structure and composition of the clay minerals) and "external" (caused by a force external to the clay). New techniques need to be developed to exploit known variations in clay mineralogy to separate internal from external effects.

  18. Simultaneous removal of multiple pesticides from water: effect of organically modified clays as coagulant aid and adsorbent in coagulation-flocculation process. (United States)

    Shabeer, T P Ahammed; Saha, Ajoy; Gajbhiye, V T; Gupta, Suman; Manjaiah, K M; Varghese, Eldho


    Contamination of drinking water sources with agrochemical residues became a major concern in the twenty-first century. Coagulation-flocculation is the most widely used water-treatment process, but the efficiency to remove pesticides and other organic pollutants are limited compared to adsorption process. Thus, simultaneous action of adsorption on normal bentonite or organo-modified montmorillonite clays [modified with octadecylamine (ODA-M) and octadecylamine + amino-propyltriethoxysilane (ODAAPS-M)] followed by coagulation-flocculation by alum and poly aluminium chloride has been evaluated for removal of 10 different pesticides, namely atrazine, lindane, metribuzin, aldrin, chlorpyriphos, pendimethalin, alpha-endosulphan, beta-endosulphan, p,p'-DDT, cypermethrin and two of its metabolites, endosulphan sulphate and p,p'-DDE, from water. The coagulation without integration of adsorption was less effective (removal % varies from 12 to 49) than the adsorption-coagulation integrated system (removal % varies from 71 to 100). Further, coagulation integrated with adsorption was more effective when organically modified montmorillonite was used as adsorbent compared to normal bentonite. The removal efficiency of organic clay depends upon the concentration of pesticides, doses of clay minerals, and efficiency was more for ODAAPS-M as compared to ODA-M. The combination of ODAAPS-M-clay with coagulants was also used efficiently for the removal of pesticides from natural and fortified natural water collected and the results exhibit the usefulness of this remediation technique for application in water decontamination and in treatment of industrial and agricultural waste waters.

  19. Field experiments of Controlled Drainage of agricultural clay soils show positive effects on water quantity (retention, runoff) and water quality (nitrate leaching). (United States)

    schipper, peter; stuyt, lodewijk; straat, van der, andre; schans, van der, martin


    Despite best management practices, agriculture is still facing major challenges to reduce nutrients leaching to the aquatic environment. In deltas, most of total nutrient losses from artificially drained agricultural soils are discharged via drains. Controlled drainage is a promising measure to prevent drainage of valuable nutrients, improve water quality and agricultural yield and adapt to climate change (reduce peak runoff, manage water scarcity and drought). In The Netherlands, this technique has attracted much attention by water managers and farmers alike, yet field studies to determine the expected (positive) effects for Dutch conditions were scarce. Recently, a field experiment was set up on clay soils. Research questions were: how does controlled, subsurface drainage perform on clay soils? Will deeper tile drains function just as well? What are the effects on drain water quality (especially with respect to nitrogen and salt) and crop yield? An agricultural field on clay soils was used to test different tile drainage configurations. Four types of tile drainage systems were installed, all in duplicate: eight plots in total. Each plot has its own outlet to a control box, where equipment was installed to control drain discharge and to measure the flow, concentrations of macro-ions, pH, nitrogen, N-isotopes and heavy metals. In each plot, groundwater observation wells and suction cups are installed in the saturated and vadose zones, at different depths, and crop yield is determined. Four plots discharge into a hydrologic isolated ditch, enabling the determination of water- and nutrient balances. Automatic drain water samplers and innovative nitrate sensors were installed in four plots. These enable identification and unravelling so-called first flush effects (changes in concentrations after a storm event). Water-, chloride- and nitrogen balances have been set up, and the interaction between groundwater and surface water has been quantified. The hydrological

  20. Water retention of rigid soils from a two-factor model for clay

    CERN Document Server

    Chertkov, V Y


    Water retention is one of the key soil characteristics. Available models of soil water retention relate to the curve-fitting type. The objective of this work is to suggest a physical model of water retention (drying branch) for soils with a rigid matrix. "Physical" means the prediction based on the a priori measured or estimated soil parameters with a clear physical meaning. We rely on the two-factor model of clay that takes into account the factors of capillarity and shrinkage. The key points of the model to be proposed are some weak pseudo shrinkage that the rigid soils demonstrate according to their experimental water retention curves, and some specific properties of the rigid grain matrix. The three input parameters for prediction of soil water retention with the rigid grain matrix include inter-grain porosity, as well as maximum and minimum grain sizes. The comparison between measured and predicted sand water retention curves for four different sands is promising.

  1. Effects of a thermal perturbation on mineralogy and pore water composition in a clay-rock: An experimental and modeling study (United States)

    Gailhanou, H.; Lerouge, C.; Debure, M.; Gaboreau, S.; Gaucher, E. C.; Grangeon, S.; Grenèche, J.-M.; Kars, M.; Madé, B.; Marty, N. C. M.; Warmont, F.; Tournassat, C.


    The physical and chemical properties of clay-rocks are, at least partly, controlled by the chemical composition of their pore water. In evaluating the concept of disposing of radioactive waste in clay-rock formations, determining pore water composition is an important step in predicting how a clay-rock will behave over time and as a function of external forces, such as chemical and thermal perturbations. This study aimed to assess experimental and modeling methodology to calculate pore water composition in a clay-rock as a function of temperature (up to 80 °C). Hydrothermal alteration experiments were carried out on clay-rock samples. We conducted comprehensive chemical and mineralogical characterization of the material before and after reaction, and monitored how the chemical parameters in the liquid and gas phases changed. We compared the experimental results with the a priori predictions made by various models that differed in their hypotheses on the reactivity of the minerals present in the system. Thermodynamic equilibrium could not be assessed unequivocally in these experiments and most of the predicted mineralogy changes were too subtle to be tracked quantitatively. However, from observing the neo-formation of minerals such as goethite we were able to assess the prominent role of Fe-bearing phases in the outcome of the experiments, especially for the measured pH and pCO2 values. After calibrating the amount of reacting Fe-bearing phases with our data, we proposed a thermodynamic model that was capable of predicting the chemical evolution of the systems under investigation as well as the evolution of other systems already published in the literature, with the same clay-rock material but with significant differences in experimental conditions.

  2. Prediction of clay content from water vapour sorption isotherms considering hysteresis and soil organic matter content

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Tuller, Markus; Moldrup, Per


    vapour sorption, which can be measured within a shorter period of time, have recently been developed. Such models are often based on single-point measurements of water adsorption and do not account for sorption hysteresis or organic matter content. The present study introduces regression relationships...... for estimating clay content from hygroscopic water at different relative humidity (RH) levels while considering hysteresis and organic matter content. Continuous adsorption/desorption vapour sorption isotherm loops were measured for 150 differently textured soils with a state-of-the-art vapour sorption analyser...

  3. Effect of Clay Content and Soil-water Potential On Mobilization and Leaching of Colloids In Unsaturated Macroporous Soil (United States)

    Kjaergaard, C.; de Jonge, L. W.; Moldrup, P.

    The transport of strongly sorbed environmental contaminants may be enhanced due to sorption to mobile soil colloids. The most common source of mobile colloids in soil is the in-situ release of water-dispersible colloids (WDC), however experimental investigations of colloid mobilization in unsaturated macroporous soil are scarce. An understanding of the arrangement of colloids in aggregates, and the influence of clay on the development of the soil fabric and pore-size distributions is essential for the in- terpretation of colloid mobilization in soils. This emphasizes the important role of clay content, when evaluating the susceptibility of soils to release colloids and associated contaminants. This study was conducted to determine the effect of clay content and initial soil- water potential on colloid mobilization and leaching. Intact soil cores were sampled from an arable field at six locations along a naturally occurring texture gradient. Soil dispersibility was investigated using capillary saturation and drainage of field-moist packed aggregates. The amount of WDC in the soil was measured for each com- bination of clay content and initial soil-water potential (-2.5, -98 and -15530 hPa). Mobilization and leaching of colloids was investigated from unsaturated intact soil cores. The soils were irrigated at low intensity (1 mm/h), and effluent sampling was conducted at 5 cm tension. The results showed that colloid dispersion was significantly affected by both clay con- tent and initial soil-water potential. With a soil-water potential of -15530 hPa the col- loid release was generally low and no variation occurred between the soils. With in- creasing soil-water potential there was an increase in the amount of WDC for all soils. The increase in WDC was negatively correlated with clay content. The leaching of colloids from intact soil cores also decreased with increasing clay content at an ini- tial soil-water potential of -98 and -2.5 hPa, and no difference between

  4. Low resistivity oil(gas)-bearing reservoir conductive model --Dual water clay matrix conductive model in the north area of Tarim Basin, Xinjiang, China

    Institute of Scientific and Technical Information of China (English)

    潘和平; 王家映; 樊政军; 马勇; 柳建华; 李明强


    Shaly sands reservoir is one of the most distributive types of the oil(gas)-bearing reservoirs discovered in China, and low resistivity oil(gas)-bearing reservoirs are mostly shaly sands reservoirs. Therefore, shaly sands reservoir conductive model is the key to evaluate low resistivity oil(gas)-bearing reservoirs using logging information. Some defects were found when we studied the clay distribution type conductive model, dual-water conductive model, conductive rock matrix model, etc. Some models could not distinguish the conductive path and nature of microporosity water and clay water and some models did not consider the clay distribution type and the mount of clay volume. So, we utilize the merits,overcome the defects of the above models, and put forward a new shaly sands conductive model-dual water clay matrix conductive model (DWCMCM) in which dual water is the free water and the microporosity water in shaly sands and the clay matrix(wet clay) is the clay grain containing water. DWCMCM is presented here, the advantages of which can tell the nature and conductive path from different water (microporosity water and freewater), in consid-eration of the clay distribution type and the mount of clay volume in shaly sands. So, the results of logging interpretation in the oil(gas)-bearing reservoirs in the north of Tarim Basin area, China with DWCMCM are better than those interpreted by the above models.

  5. Adsorption of phenthoate and acetochlor from water by clays and organoclays

    Institute of Scientific and Technical Information of China (English)

    LIAO Min; XIE Xiao-mei


    Adsorption of phenthoate and acetochlor onto kaolin, montmorillonite, bentonite clays and respective organoclays prepared by the exchange of quaternary ammonium as tetradecyltrimethyl ammonium bromide(TTAB), dodecyltrimethylammonium bromide(DTAB), and cetylpyridinium chloride(CPC) were studied. The adsorption equilibrium data points were fitted to Freundlich isotherm equations. The adsorption of phenthoate and acetochlor were significantly enhanced by surfactant treatment of the clays. The amount of both pesticides adsorbed per unit mass of organoclay followed the order of TTA-kaolin TTA(C14)-montmorillonite > DTA(C12)-montmorillonite. Phenthoate is adsorbed to greater extent than acetochlor by each adsorbent, which may be due to the higher hydrophobicity of phenthoate, indicating considerable hydrophobic interaction between adsorbent/adsorbate systems.

  6. Contact angles at the water-air interface of hydrocarbon-contaminated soils and clay minerals (United States)

    Sofinskaya, O. A.; Kosterin, A. V.; Kosterina, E. A.


    Contact angles at the water-air interface have been measured for triturated preparations of clays and soils in order to assess changes in their hydrophobic properties under the effect of oil hydrocarbons. Tasks have been to determine the dynamics of contact angle under soil wetting conditions and to reveal the effect of chemical removal of organic matter from soils on the hydrophilicity of preparations. The potentialities of static and dynamic drop tests for assessing the hydrophilic-hydrophobic properties of soils have been estimated. Clays (kaolinite, gumbrine, and argillite) have been investigated, as well as plow horizons of soils from the Republic of Tatarstan: heavy loamy leached chernozem, medium loamy dark gray forest soil, and light loamy soddy-calcareous soil. The soils have been contaminated with raw oil and kerosene at rates of 0.1-3 wt %. In the uncontaminated and contaminated chernozem, capillary water capacity has been maintained for 250 days. The contact angles have been found to depend on the degree of dispersion of powdered preparation, the main type of clay minerals in the soil, the presence and amount of oxidation-resistant soil organic matter, and the soil-water contact time. Characteristic parameters of mathematical models for drop behavior on triturated preparations have been calculated. Contamination with hydrocarbons has resulted in a reliable increase in the contact angles of soil preparations. The hydrophobization of soil surface in chernozem is more active than in soils poorer in organic matter. The complete restoration of the hydrophilic properties of soils after hydrocarbon contamination is due to the oxidation of easily oxidizable organic matter at the low content of humus, or to wetting during several months in the absence of the mazut fraction.

  7. Effect of suction change on water content and total volume of an expansive clay

    Institute of Scientific and Technical Information of China (English)

    ZHAN Liang-tong; CHEN Ping; NG C.W.W.


    A laboratory study was carried out on both natural and compacted specimens to investigate the complex soil-water interaction in an unsaturated expansive clay. The laboratory study includes the measurement of soil-water characteristic curves, 1D free swelling tests, measurement of swelling pressure and shrinkage tests. The test results revealed that the air-entry value of the natural specimen was quite low due to cracks and fissures present. The hydraulic hysteresis of the natural specimen was relatively insignificant as compared with the compacted specimen. Within a suction range 0 to 500 kPa, a bilinear relationship between free swelling strain (or swelling pressure) and initial soil suction was observed for both the natural and compacted specimens. As a result of over-consolidation and secondary structures such as cementation and cracks, the natural specimens exhibited significant lower swelling (or swelling pressure) than the compacted specimen. The change of matric suction exerts a more significant effect on the water phase than on the soil skeleton for this expansive clay.

  8. Clay Generic Disposal System Model - Sensitivity Analysis for 32 PWR Assembly Canisters (+2 associated model files).

    Energy Technology Data Exchange (ETDEWEB)

    Morris, Edgar [Argonne National Lab. (ANL), Argonne, IL (United States)


    The Used Fuel Disposition Campaign (UFDC), as part of the DOE Office of Nuclear Energy’s (DOE-NE) Fuel Cycle Technology program (FCT) is investigating the disposal of high level radioactive waste (HLW) and spent nuclear fuela (SNF) in a variety of geologic media. The feasibility of disposing SNF and HLW in clay media has been investigated and has been shown to be promising [Ref. 1]. In addition the disposal of these wastes in clay media is being investigated in Belgium, France, and Switzerland. Thus, Argillaceous media is one of the environments being considered by UFDC. As identified by researchers at Sandia National Laboratory, potentially suitable formations that may exist in the U.S. include mudstone, clay, shale, and argillite formations [Ref. 1]. These formations encompass a broad range of material properties. In this report, reference to clay media is intended to cover the full range of material properties. This report presents the status of the development of a simulation model for evaluating the performance of generic clay media. The clay Generic Disposal System Model (GDSM) repository performance simulation tool has been developed with the flexibility to evaluate not only different properties, but different waste streams/forms and different repository designs and engineered barrier configurations/ materials that could be used to dispose of these wastes.

  9. Simulation of water movement and isoproturon behaviour in a heavy clay soil using the MACRO model

    Directory of Open Access Journals (Sweden)

    T. J. Besien


    Full Text Available In this paper, the dual-porosity MACRO model has been used to investigate methods of reducing leaching of isoproturon from a structured heavy clay soil. The MACRO model was applied to a pesticide leaching data-set generated from a plot scale experiment on a heavy clay soil at the Oxford University Farm, Wytham, England. The field drain was found to be the most important outflow from the plot in terms of pesticide removal. Therefore, this modelling exercise concentrated on simulating field drain flow. With calibration of field-saturated and micropore saturated hydraulic conductivity, the drain flow hydrographs were simulated during extended periods of above average rainfall, with both the hydrograph shape and peak flows agreeing well. Over the whole field season, the observed drain flow water budget was well simulated. However, the first and second drain flow events after pesticide application were not simulated satisfactorily. This is believed to be due to a poor simulation of evapotranspiration during a period of low rainfall around the pesticide application day. Apart from an initial rapid drop in the observed isoproturon soil residue, the model simulated isoproturon residues during the 100 days after pesticide application reasonably well. Finally, the calibrated model was used to show that changes in agricultural practice (deep ploughing, creating fine consolidated seed beds and organic matter applications could potentially reduce pesticide leaching to surface waters by up to 60%.

  10. Content and distribution of fluorine in rock, clay and water in fluorosis area Zhaotong, Yunnan Province

    Energy Technology Data Exchange (ETDEWEB)

    Luo, K.; Li, H.; Feng, F. (and others) [Chinese Academy of Sciences, Beijing (China)


    About 160 samples of coal, pyritic coal balls, coal seam gangue, clay, corn, capsicum and drinking water were collected from the endemic fluorosis area of Zhenxiong and Weixin county, China to determine the fluorine content, distribution pattern and source in this fluorosis area. The study shows that the average fluorine content in the coal samples collected from 3 coal mines of the Late Permian coals in Zhenxiong and Weixin county, Zhaotong City, which are the main mining coals there, is 77.13 mg/kg. The average fluorine content coals collected form thee typical fluorosis villages in 72.56 mg/kg. Both of them are close to the world average and little low than the Chinese average. The fluorine content of drinking water is lower than 0.35 mg/L, the clay used as an additive for coal-burning and as a binfer in briquette-making by local residents has a high content of fluorine, ranging from 367-2,435 mg/kg, with the majority higher than 600 mg/kg and an average of 1,084.2 mg/kg. 29 refs., 5 tabs.

  11. Effect of organic matter properties, clay mineral type and thermal maturity on gas adsorption in organic-rich shale systems (United States)

    Zhang, Tongwei; Ellis, Geoffrey S.; Ruppel, Stephen C.; Milliken, Kitty; Lewan, Mike; Sun, Xun; Baez, Luis; Beeney, Ken; Sonnenberg, Steve


    A series of CH4 adsorption experiments on natural organic-rich shales, isolated kerogen, clay-rich rocks, and artificially matured Woodford Shale samples were conducted under dry conditions. Our results indicate that physisorption is a dominant process for CH4 sorption, both on organic-rich shales and clay minerals. The Brunauer–Emmett–Teller (BET) surface area of the investigated samples is linearly correlated with the CH4 sorption capacity in both organic-rich shales and clay-rich rocks. The presence of organic matter is a primary control on gas adsorption in shale-gas systems, and the gas-sorption capacity is determined by total organic carbon (TOC) content, organic-matter type, and thermal maturity. A large number of nanopores, in the 2–50 nm size range, were created during organic-matter thermal decomposition, and they significantly contributed to the surface area. Consequently, methane-sorption capacity increases with increasing thermal maturity due to the presence of nanopores produced during organic-matter decomposition. Furthermore, CH4 sorption on clay minerals is mainly controlled by the type of clay mineral present. In terms of relative CH4 sorption capacity: montmorillonite ≫ illite – smectite mixed layer > kaolinite > chlorite > illite. The effect of rock properties (organic matter content, type, maturity, and clay minerals) on CH4 adsorption can be quantified with the heat of adsorption and the standard entropy, which are determined from adsorption isotherms at different temperatures. For clay-mineral rich rocks, the heat of adsorption (q) ranges from 9.4 to 16.6 kJ/mol. These values are considerably smaller than those for CH4 adsorption on kerogen (21.9–28 kJ/mol) and organic-rich shales (15.1–18.4 kJ/mol). The standard entropy (Δs°) ranges from -64.8 to -79.5 J/mol/K for clay minerals, -68.1 to -111.3 J/mol/K for kerogen, and -76.0 to -84.6 J/mol/K for organic-rich shales. The affinity of CH4 molecules for sorption on organic matter

  12. Considering Organic Carbon for Improved Predictions of Clay Content from Water Vapor Sorption

    DEFF Research Database (Denmark)

    Arthur, Emmanuel; Tuller, Markus; Moldrup, Per;


    to water vapor sorption isotherms that can be rapidly measured with a fully automated vapor sorption analyzer are a viable alternative. In this presentation we evaluate the performance of recently developed regression models based on comparison with standard CF measurements for soils with high organic...... carbon (OC) content and propose a modification to improve prediction accuracy. Evaluation of the CF prediction accuracy for 29 soils with clay contents ranging from 6 to 25% and with OC contents from 2.0 to 8.4% showed that the models worked reasonably well for all soils when the OC content was below 2.......4%. For soils with OC>2.4% and CFcontent. Based on 20 soils with CF between 3 and 15% and OC between 2.6 and 8.4%, we propose correction factors to account for the sorbed water content associated with OC. Evaluation of the OC...

  13. Cu(II adsorption on modified bentonitic clays: different isotherm behaviors in static and dynamic systems

    Directory of Open Access Journals (Sweden)

    Ambrósio Florêncio de Almeida Neto


    Full Text Available Cu (II removal equilibrium from aqueous solutions using calcined clays "Bofe" and "Verde-lodo" has been studied by batch and fixed-bed in static and dynamic systems, respectively. Analyses were performed for physicochemical characterization of clays using the techniques: X-ray fluorescence (XRF, thermogravimetry (TG, N2 adsorption (BET and Cationic Exchange Capacity (CEC. Batch experiments were performed at a constant temperature, adjusting the pH of the solution in contact with clays. Adsorption assays in fixed bed were conducted at the flow rate determined through mass transfer zone (MTZ. Langmuir and Freundlich models were adjusted to equilibrium data. The results of characterization indicated that the temperature of 500ºC is best suited for the calcination of the clays. The maximum adsorption capacity was higher for dynamic system than fixed bed compared to static system, enhancing from 0.0748 to 0.1371 and from 0.0599 to 0.22 mmol.g-1 of clay for "Bofe" and "Verde-lodo", respectively.

  14. Refinements of water parameters for molecular dynamics: Simulations of adsorption at the clay mineral/aqueous solution interface

    DEFF Research Database (Denmark)

    Schäfer, L.; Yu, C.; Teppen, B.J.;


    In the context of a long-term program involving molecular dynamics simulations of adsorption phenomena at the clay mineral/aqueous solution interface, we are testing the viability of combining a force field that we developed specificially for clays with other, independently derived potential...... parameters for molecular species which are important in clay adsorption. For the current study the importance of variations in the potential parameters of water were investigated and polarization effects on oxygen studied as a function of intermolecular interactions. For this purpose ab initio MP2/6-311GG...... atomic charges were determined for several oligomers of water and for the water dimer at different intermolecular separations. Charge variations of up to ~0.1 electron charge unit on oxygen are found and, together with changes in van der Waals constants, their significance for dynamics simulations...

  15. Synthesis and characterization of a PbO{sub 2}-clay nanocomposite: Removal of lead from water using montmorillonite

    Energy Technology Data Exchange (ETDEWEB)

    Aroui, L. [Laboratoire d' Energetique et Electrochimie du Solide (LEES), Faculte de Technologie, Universite Ferhat ABBAS, Setif 19000 (Algeria); Zerroual, L., E-mail: [Laboratoire d' Energetique et Electrochimie du Solide (LEES), Faculte de Technologie, Universite Ferhat ABBAS, Setif 19000 (Algeria); Boutahala, M. [Laboratoire de Genie des Procedes Chimiques (LGPC), Faculte de Technologie, Universite Ferhat ABBAS, Setif 19000 (Algeria)


    Graphical abstract: The replacement of Na by Pb in the interlayer space of the smectite leads to a decrease in the intensity of the the (0 0 1) reflection as the concentration of lead nitrate increases. A significant restructuring at the particle scale is observed leading probably to the exfoliation of the caly. In addition, the thermal behaviour of the montmorillonite samples with regard to their dehydration and dehydroxilation capacities is significantly influenced. This leads to a lowering of the water content and a decrease in the ionic conductivity of the clay. Highlights: Black-Right-Pointing-Pointer In the clay, Pb replaces Na ions and a significant restructuring at the particle scale is observed. Black-Right-Pointing-Pointer Pb influenced significantly the thermal behaviour of the clay with regard to its dehydration. Black-Right-Pointing-Pointer In the interlayer space, the exchange of Na by Pb leads to a decrease in the protonic conductivity. Black-Right-Pointing-Pointer A PbO{sub 2}-clay nanocomposite material with good conductivity is synthesized. -- Abstract: The aim of this paper is to present the results obtained with Pb(II) sorption on an Algerian Clay. The experiments were carried out using a batch process. Powder X-rays diffraction patterns (PXRD) prove that in the montmorillonite Pb replaces Na ions. A significant restructuring at the particle scale is observed leading to the disappearance of the d{sub 001} reflection of the clay at high concentrations of lead. The replacement of hydrated Na with Pb ions influenced significantly the thermal behaviour of the montmorillonite samples with regard to their dehydration and dehydroxilation capacities with a lowering of the water content. A PbO{sub 2}-clay composite material with good electrical conductivity is synthesized.

  16. Microwave-Assisted Preparation of Biodegradable Water Absorbent Polyacrylonitrile/Montmorillonite Clay Nanocomposite

    Directory of Open Access Journals (Sweden)

    Prafulla K. Sahoo


    Full Text Available Polyacrylonitrile (PAN/Montmorillonite (MMT clay nanocomposite was prepared in a microwave oven using a transition metal Co(III complex taking ammonium persulfate (APS as initiator with a motive of converting hydrophobic PAN into hydrophilic nanocomposite material via nanotechnology by the inclusion of MMT to the virgin polymer. UV-visible spectral analysis revealed various interactions between the developed complex with other reaction components. The formation of the PAN/MMT nanocomposites was characterized by FTIR. Furthermore, as evidenced by X-ray diffraction (XRD, transmission electron microscopy (TEM, the composite so obtained was found to have nano-order. XRD and TEM were suggesting that montmorillonite layers were exfoliated during the polymerization process. An increasing in the thermal stability for the developed nanocomposite was recorded by thermogravimetric analysis (TGA. The water absorption and biodegradation properties were carried out for its ecofriendly nature and better commercialization.

  17. Irrigation with saline-sodic water: effects on two clay soils

    Directory of Open Access Journals (Sweden)

    Giovanna Cucci


    Full Text Available The results of a 4-year experiment aimed at evaluating the effect of irrigation with saline-sodic water on the soil are reported. The research was carried out at the Campus of the Agricultural Faculty of Bari University (Italy on 2 clay soils (Bologna – T1 and Locorotondo – T2. The soils were cropped to borlotto bean (Phaseolus vulgaris L., capsicum (Capsicum annuum L., sunflower (Helianthus annuus L., wheat (Triticum durum Desf grown in succession; the crops were irrigated with 9 saline-sodic types of water and subjected to two different leaching fractions (10% and 20% of the watering volume. The 9 solutions were obtained dissolving in de-ionised water weighted amounts of sodium chloride (NaCl and calcium chloride (CaCl2, deriving from the combination of 3 saline concentrations and 3 sodicity levels. The crops were irrigated whenever the water lost by evapotranspiration from the soil contained in the pots was equal to 30% of the soil maximum available water. The results showed that, though the soils were leached during the watering period, they showed a high salt accumulation. Consequently, the saturated soil extract electrical conductivity increased from initial values of 0.65 and 0.68 dS m-1 to 11.24 and 13.61 dS m-1 at the end of the experiment, for the soils T1 and T2, respectively. The saline concentration increase in irrigation water caused in both soils a progressive increase in exchangeable sodium, and a decrease in exchangeable calcium and non-significant variations in exchangeable potassium (K and magnesium (Mg.

  18. Treatment with coated layer double hydroxide clays decreases the toxicity of copper-contaminated water. (United States)

    Blake, Deanne; Nar, Mangesh; D'Souza, Nandika Anne; Glenn, J Brad; Klaine, Stephen J; Roberts, Aaron P


    Copper is a common pollutant found in watersheds that exerts toxic effects on both invertebrates and vertebrates. Layer double hydroxide (LDH) clays are able to adsorb a wide range of contaminants through ion-exchange mechanisms. Coating LDH clays with various materials alters the aggregation of clay particles into the nano-size range, thus increasing relative surface area and offering great potential for contaminant remediation. The goal of this study was to determine if treatment with coated LDH clays decreases the toxicity of copper-containing solutions to Daphnia magna. Four LDH clays with different coatings used to alter hydrophobicity were as follows: used: Na(+) montmorillonite, Zn-Al LDH-nitrate, Zn-Al LDH-stearate, and Zn-Al LDH-carbonate. It was determined that coated LDH clays decreased copper toxicity by decreasing bioavailability and that smaller aggregate sizes decreased bioavailability the most. 96 h LC50 values increased by as much as 4.2 times with the treatment of the solutions with 100 mg/L LDH clay. Copper analysis of the clay and solutions indicated that the clays work by decreasing copper bioavailability by way of a binding mechanism. Coated LDH clays hold promise as a small-scale remediation tool or as an innovative tool for toxicity identification and evaluation characterization of metals.

  19. Formation of polygonal fault systems as a result of hydrodynamical instabilities in clay-rich deposits. (United States)

    Lopez, Teodolina; Antoine, Raphael; Rabinowicz, Michel; Baratoux, David; Darrozes, José; Kurita, Kei; D'Uston, Lionel


    Fine grained deposits as chalks and clays are characterised by the development of polygonal fault systems [1]. For the clay-rich deposits, two different environments are associated with their formation. First, on continents, dewatering leads to the development of polygonal desiccation cracks which have a centimetric to metric size [2]. Polygonal faults are also observed in sub-marine sedimentary deposits and here, can reach hectometric to kilometric size [3]. Since the giant polygons develop on basins with no clear evidences of tectonic stresses, the fracturing is attributed to stresses due to horizontal density variations generated during the basin subsidence. Several models have been proposed to explain the formation of the giant polygons and the two main hypotheses are the syneresis (spontaneous horizontal contraction) proposed by [4] and the low coefficient of friction of clay proposed by [5]. However, new understandings in the clay rheology and in the hydrodynamical instabilities, controlling the development of compaction in unconsolidated and consolidated clay deposits, permit us to propose an alternative hypothesis. We consider that the development of giant polygons results from the superposition of hydrodynamical instabilities leading to the formation of (i) mm-size agglomerates of clay particles while the deposit is unconsolidated [6], followed after by the consolidation of this layer, then (ii) hectometric to kilometric compaction spheres develop [7] and (iii) finally ends with the occurrence of hydrothermal and plastic convections. We show that the crucial conditions for the development of hectometric to kilometric size polygonal fault systems are: 1) the high permeability of the clay-rich deposit composed of mm-size agglomerates and 2) the dramatic increase of the strength of the clay as the deposit consolidates. [1] Dewhurst et al., (1999), Mar. Petr. Geol., 16 (8), 793-810. [2] Weinberger (1999), J. Struct. Geol., 21, 379-386. [3] Andresen and Huuse

  20. Stochastic modeling of filtrate alkalinity in water filtration devices: Transport through micro/nano porous clay based ceramic materials (United States)

    Clay and plant materials such as wood are the raw materials used in manufacture of ceramic water filtration devices around the world. A step by step manufacturing procedure which includes initial mixing, molding and sintering is used. The manufactured ceramic filters have numerous pores which help i...

  1. Non-selective oxidation of humic acid in heterogeneous aqueous systems: a comparative investigation on the effect of clay minerals. (United States)

    Kavurmaci, Sibel Sen; Bekbolet, Miray


    Application of photocatalysis for degradation of natural organic matter (NOM) has received wide interest during the last decades. Besides NOM, model compounds more specifically humic acids (HAs) were also studied. As a continuation of the previous research, TiO2 photocatalytic degradation of HA was investigated in the presence of clay minerals, i.e., montmorillonite (Mt) and kaolinite (Kt). Degradation of HA was expressed by the pseudo-first-order kinetic modelling of dissolved organic carbon (DOC) and UV-VIS parameters (Colour436 and UV254). A slight rate enhancement was attained for Colour436 and UV254 in the presence of either Mt or Kt. The presence of clay particles did not significantly change the DOC degradation rate of HA. The effect of ionic strength (Ca2+ loading from 5 x 10(-4) M to 5 x 1(-3) M) was also assessed for the photocatalytic degradation of sole HA and HA in the presence of either Mt or Kt. Following photocatalytic treatment, molecular size distribution profiles of HA were presented. Besides the effective removal of higher molecular size fractions (100 and 30 kDa fractions), transformation to lower molecular size fractions (clay minerals. Scanning electron microscopic images with the energy dispersive X-ray analysis confirmed the diversities in surface morphologies of the binary and ternary systems composed of HA, TiO2 and Mt or Kt both prior to and following photocatalysis. This study demonstrated that photocatalysis could be applicable for DOC degradation in the presence of clay minerals in natural waters.

  2. The use of lightweight expanded clay aggregate (LECA) as sorbent for PAHs removal from water. (United States)

    Nkansah, Marian Asantewah; Christy, Alfred A; Barth, Tanja; Francis, George William


    Lightweight expanded clay aggregate (LECA) has been explored as a sorbent for the removal of PAHs (phenanthrene, fluoranthene and pyrene) from water. The efficacy of LECA as a sorbent for PAHs was assessed using contact time, mass of sorbent and sorption isotherms in a series of batch experiments. Maximum (optimum) sorption was reached at 21 h after which the amount of PAHs sorbed remained almost constant. Batch experiments were conducted by shaking a 100ml solution mixture of individual PAHs (containing 0.02 mg/L) with LECA. The maximum sorption was 70.70, 70.82 and 72.12%, respectively for phenanthrene, fluoranthene and pyrene when a mass of 0.2 g of sorbent was used. There was an increase in sorption as a result of an increase in mass of sorbent until a maximum was reached at a mass of 4.0 g LECA with 92.61, 93.91 and 94.15% sorption of phenanthrene, fluoranthene and pyrene respectively. Sorption data were fitted to the linearised forms of the Freundlich and Langmuir isotherm models to determine the water-LECA partitioning coefficient. Physical sorption caused by the aromatic nature of the compounds was the main mechanism that governed the removal process while the hydrophobicity of the PAHs also influenced the sorption capacity. LECA can be used as an alternative method for aqueous PAHs removal.

  3. Error Analysis of Clay-Rock Water Content Estimation with Broadband High-Frequency Electromagnetic Sensors—Air Gap Effect (United States)

    Bore, Thierry; Wagner, Norman; Delepine Lesoille, Sylvie; Taillade, Frederic; Six, Gonzague; Daout, Franck; Placko, Dominique


    Broadband electromagnetic frequency or time domain sensor techniques present high potential for quantitative water content monitoring in porous media. Prior to in situ application, the impact of the relationship between the broadband electromagnetic properties of the porous material (clay-rock) and the water content on the frequency or time domain sensor response is required. For this purpose, dielectric properties of intact clay rock samples experimental determined in the frequency range from 1 MHz to 10 GHz were used as input data in 3-D numerical frequency domain finite element field calculations to model the one port broadband frequency or time domain transfer function for a three rods based sensor embedded in the clay-rock. The sensor response in terms of the reflection factor was analyzed in time domain with classical travel time analysis in combination with an empirical model according to Topp equation, as well as the theoretical Lichtenecker and Rother model (LRM) to estimate the volumetric water content. The mixture equation considering the appropriate porosity of the investigated material provide a practical and efficient approach for water content estimation based on classical travel time analysis with the onset-method. The inflection method is not recommended for water content estimation in electrical dispersive and absorptive material. Moreover, the results clearly indicate that effects due to coupling of the sensor to the material cannot be neglected. Coupling problems caused by an air gap lead to dramatic effects on water content estimation, even for submillimeter gaps. Thus, the quantitative determination of the in situ water content requires careful sensor installation in order to reach a perfect probe clay rock coupling. PMID:27096865

  4. Error Analysis of Clay-Rock Water Content Estimation with Broadband High-Frequency Electromagnetic Sensors—Air Gap Effect

    Directory of Open Access Journals (Sweden)

    Thierry Bore


    Full Text Available Broadband electromagnetic frequency or time domain sensor techniques present high potential for quantitative water content monitoring in porous media. Prior to in situ application, the impact of the relationship between the broadband electromagnetic properties of the porous material (clay-rock and the water content on the frequency or time domain sensor response is required. For this purpose, dielectric properties of intact clay rock samples experimental determined in the frequency range from 1 MHz to 10 GHz were used as input data in 3-D numerical frequency domain finite element field calculations to model the one port broadband frequency or time domain transfer function for a three rods based sensor embedded in the clay-rock. The sensor response in terms of the reflection factor was analyzed in time domain with classical travel time analysis in combination with an empirical model according to Topp equation, as well as the theoretical Lichtenecker and Rother model (LRM to estimate the volumetric water content. The mixture equation considering the appropriate porosity of the investigated material provide a practical and efficient approach for water content estimation based on classical travel time analysis with the onset-method. The inflection method is not recommended for water content estimation in electrical dispersive and absorptive material. Moreover, the results clearly indicate that effects due to coupling of the sensor to the material cannot be neglected. Coupling problems caused by an air gap lead to dramatic effects on water content estimation, even for submillimeter gaps. Thus, the quantitative determination of the in situ water content requires careful sensor installation in order to reach a perfect probe clay rock coupling.

  5. Error Analysis of Clay-Rock Water Content Estimation with Broadband High-Frequency Electromagnetic Sensors--Air Gap Effect. (United States)

    Bore, Thierry; Wagner, Norman; Lesoille, Sylvie Delepine; Taillade, Frederic; Six, Gonzague; Daout, Franck; Placko, Dominique


    Broadband electromagnetic frequency or time domain sensor techniques present high potential for quantitative water content monitoring in porous media. Prior to in situ application, the impact of the relationship between the broadband electromagnetic properties of the porous material (clay-rock) and the water content on the frequency or time domain sensor response is required. For this purpose, dielectric properties of intact clay rock samples experimental determined in the frequency range from 1 MHz to 10 GHz were used as input data in 3-D numerical frequency domain finite element field calculations to model the one port broadband frequency or time domain transfer function for a three rods based sensor embedded in the clay-rock. The sensor response in terms of the reflection factor was analyzed in time domain with classical travel time analysis in combination with an empirical model according to Topp equation, as well as the theoretical Lichtenecker and Rother model (LRM) to estimate the volumetric water content. The mixture equation considering the appropriate porosity of the investigated material provide a practical and efficient approach for water content estimation based on classical travel time analysis with the onset-method. The inflection method is not recommended for water content estimation in electrical dispersive and absorptive material. Moreover, the results clearly indicate that effects due to coupling of the sensor to the material cannot be neglected. Coupling problems caused by an air gap lead to dramatic effects on water content estimation, even for submillimeter gaps. Thus, the quantitative determination of the in situ water content requires careful sensor installation in order to reach a perfect probe clay rock coupling.

  6. Improving the Hydraulic Performance of Stormwater Infiltration Systems in Clay Tills

    DEFF Research Database (Denmark)

    Bockhorn, Britta

    D study was initiated with the objective to test and evaluate if the hydraulic performance of stormwater infiltration systems can be significantly improved if the site-specific geological heterogeneity is incorporated into the design and siting of such systems. The assessment is based on different field...... infiltration systems. Models employing standard soil physical parameters should be used with care as they do not always realistically describe site-specific hydrologic properties. A fourth study showed that the hydraulic performance of infiltration trenches was increased by a factor of two, when spear auger......Many cities of the Northern Hemisphere are covered by low permeable clay tills, which pose a challenge for stormwater infiltration practices. However, clay tills are amongst the most heterogeneous types of sediments and hydraulic conductivities can vary by several orders of magnitude. This Ph...

  7. The effect of phosphorus binding clay (Phoslock) in mitigating cyanobacterial nuisance: A laboratory study on the effects on water quality variables and plankton

    NARCIS (Netherlands)

    Oosterhout, J.F.X.; Lurling, M.


    This laboratory study examined the lanthanum modified clay Phoslock® for its effectiveness to bind soluble reactive phosphorus (SRP), release of nutrients from this modified clay, its influence on water quality variables (pH, oxygen saturation %, conductivity and turbidity), effects on phytoplankton

  8. Clay Play (United States)

    Rogers, Liz; Steffan, Dana


    This article describes how to use clay as a potential material for young children to explore. As teachers, the authors find that their dialogue about the potential of clay as a learning medium raises many questions: (1) What makes clay so enticing? (2) Why are teachers noticing different play and conversation around the clay table as compared to…

  9. The use of lightweight expanded clay aggregate (LECA) as sorbent for PAHs removal from water

    Energy Technology Data Exchange (ETDEWEB)

    Nkansah, Marian Asantewah, E-mail: [Department of Science, Faculty of Engineering and Science, University of Agder Service Box 422, No 4604, Kristiansand (Norway); Department of Chemistry, University of Bergen, Allegaten 41, N-5007 Bergen (Norway); Christy, Alfred A. [Department of Science, Faculty of Engineering and Science, University of Agder Service Box 422, No 4604, Kristiansand (Norway); Barth, Tanja; Francis, George William [Department of Chemistry, University of Bergen, Allegaten 41, N-5007 Bergen (Norway)


    Highlights: Black-Right-Pointing-Pointer Effect of contact time on sorption PAH by LECA. Black-Right-Pointing-Pointer Effect of mass of sorbent (LECA) on sorption of PAH. Black-Right-Pointing-Pointer Sorption Isotherms for PAH-LECA interaction. - Abstract: Lightweight expanded clay aggregate (LECA) has been explored as a sorbent for the removal of PAHs (phenanthrene, fluoranthene and pyrene) from water. The efficacy of LECA as a sorbent for PAHs was assessed using contact time, mass of sorbent and sorption isotherms in a series of batch experiments. Maximum (optimum) sorption was reached at 21 h after which the amount of PAHs sorbed remained almost constant. Batch experiments were conducted by shaking a 100 ml solution mixture of individual PAHs (containing 0.02 mg/L) with LECA. The maximum sorption was 70.70, 70.82 and 72.12%, respectively for phenanthrene, fluoranthene and pyrene when a mass of 0.2 g of sorbent was used. There was an increase in sorption as a result of an increase in mass of sorbent until a maximum was reached at a mass of 4.0 g LECA with 92.61, 93.91 and 94.15% sorption of phenanthrene, fluoranthene and pyrene respectively. Sorption data were fitted to the linearised forms of the Freundlich and Langmuir isotherm models to determine the water-LECA partitioning coefficient. Physical sorption caused by the aromatic nature of the compounds was the main mechanism that governed the removal process while the hydrophobicity of the PAHs also influenced the sorption capacity. LECA can be used as an alternative method for aqueous PAHs removal.

  10. Ball clay (United States)

    Virta, R.L.


    The article discusses the latest developments in the global ball clay mining industry, particularly in the U.S., as of June 2011. It cites several firms that are involved in ball clay mining in the U.S., including HC Spins Clay Co. Inc., the Imerys Group and Old Hickory Clay Co. Among the products made from ball clay are ceramic tiles, sanitaryware, as well as fillers, extenders and binders.

  11. Magnetic chitosan/clay beads: A magsorbent for the removal of cationic dye from water (United States)

    Bée, Agnès; Obeid, Layaly; Mbolantenaina, Rakotomalala; Welschbillig, Mathias; Talbot, Delphine


    A magnetic composite material composed of magnetic nanoparticles and clay encapsulated in cross-linked chitosan beads was prepared, characterized and used as a magsorbent for the removal of a cationic dye, methylene blue (MB), from aqueous solutions. The magnetic properties of these beads represent an advantage to recover them at the end of the depollution process. The optimal weight ratio R=clay:chitosan for the removal of MB in a large range of pH was determined. For beads without clay, the maximal adsorption capacity of MB occurs in the pH range [9-12], while for beads with clay, the pH range extends by increasing the amount of clay to reach [3-12] for R>0.5. Adsorption isotherms show that the adsorption capacity of magnetic beads is equal to 82 mg/g. Moreover, the kinetics of dye adsorption is relatively fast since 50% of the dye is removed in the first 13 min for an initial MB concentration equal to 100 mg/L. The estimation of the number of adsorption sites at a given pH shows that the main driving force for adsorption of MB in a large range of pH is the electrostatic interaction between the positively charged dye and the permanent negative charges of clay.

  12. Estimated ground-water use in Becker, Clay, Douglas, Grant, Otter Tail, and Wilkin Counties, Minnesota, for 2030 and 2050 (United States)

    Winterstein, Thomas A.


    The U.S. Department of the Interior, Bureau of Reclamation, is studying six alternatives for delivering water to the Red River of the North Valley in North Dakota and to the cities of Breckenridge, Moorhead, and East Grand Forks, Minnesota. In order to evaluate these alternatives the Bureau of Reclamation needs estimates of ground-water use for 2030 and 2050 for six counties in Minnesota: Becker, Clay, Douglas, Grant, Otter Tail, and Wilkin Counties. The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, conducted a study to estimate ground-water use in these counties for 2030 and 2050.

  13. Multi scale experimental study of water and ionic transport in porous charged media: clays; Etude experimentale multiechelle du transport ionique et aqueux en milieu poreux charge: argiles

    Energy Technology Data Exchange (ETDEWEB)

    Cadene, A


    Clays are porous media of industrial interest. Due to their retention capacities and low permeability to water, they are the principal candidate for the conception of engineered barriers radioactive waste disposal. The main interest of this study is the experimental determination of the cationic and water dynamics in montmorillonite and fluoro-hectorite at low water contents This latter synthetic smectite has been used as a model clay to help the interpretation of the results issued from the first natural one. After a summary on the clayey system, this work reports the many experimental techniques (Atomic Force Microscopy, Photo-Correlation Spectroscopy, Micro-calorimetry, Powder Diffraction) used during the preliminary study concerning structural characterisation of the samples. The study of the sodic form of smectites with the use of a combination of quasi-elastic neutron scattering techniques (Time of Flight and Spin Echo) succeeded to water diffusion coefficients but also to a discernment of the limits of such techniques. Experiments with montmorillonite samples are in agreement with the simulations, so tending to a validation of the models. Experimental data obtained from synthetic hectorites will be in the near future compared to simulations In the last part, this work shows the application of Broad Band Dielectric Spectroscopy for the investigation of ionic dynamic in these porous media. Many models have been developed for the interpretation of the experimental raw data obtained with this technique. (author)

  14. Mineral acquisition from clay by budongo forest chimpanzees

    NARCIS (Netherlands)

    Reynolds, Vernon; Lloyd, Andrew W.; English, Christopher J.; Lyons, Peter; Dodd, Howard; Hobaiter, Catherine; Newton-Fisher, Nicholas; Mullins, Caroline; Lamon, Noemie; Schel, Anne Marijke; Fallon, Brittany


    Chimpanzees of the Sonso community, Budongo Forest, Uganda were observed eating clay and drinking clay-water from waterholes. We show that clay, clay-rich water, and clay obtained with leaf sponges, provide a range of minerals in different concentrations. The presence of aluminium in the clay consum

  15. Clay hydration/dehydration in dry to water-saturated supercritical CO2: Implications for caprock integrity

    Energy Technology Data Exchange (ETDEWEB)

    Loring, John S.; Schaef, Herbert T.; Thompson, Christopher J.; Turcu, Romulus VF; Miller, Quin R.; Chen, Jeffrey; Hu, Jian Z.; Hoyt, David W.; Martin, Paul F.; Ilton, Eugene S.; Felmy, Andrew R.; Rosso, Kevin M.


    Injection of supercritical CO2 (scCO2) for the geologic storage of carbon dioxide will displace formation water, and the pore space adjacent to overlying caprocks could eventually be dominated by dry to water-saturated scCO2. Wet scCO2 is highly reactive and capable of carbonating and hydrating certain minerals, whereas anhydrous scCO2 can dehydrate water-containing minerals. Because these geochemical processes affect solid volume and thus porosity and permeability, they have the potential to affect the long-term integrity of the caprock seal. In this study, we investigate the swelling and shrinkage of an expandable clay found in caprock formations, montmorillonite (Ca-STx-1), when exposed to variable water-content scCO2 at 50 °C and 90 bar using a combination of in situ probes, including X-ray diffraction (XRD), in situ magic angle spinning nuclear magnetic resonance spectroscopy (MAS NMR), and in situ attenuated total reflection infrared spectroscopy (ATR-IR). We show that the extent of montmorillonite clay swelling/shrinkage is dependent not only on water hydration/dehydration, but also on CO2 intercalation reactions. Our results also suggest a competition between water and CO2 for interlayer residency where increasing concentrations of intercalated water lead to decreasing concentrations of intercalated CO2. Overall, this paper demonstrates the types of measurements required to develop fundamental knowledge that will enhance modeling efforts and reduce risks associated with subsurface storage of CO2.

  16. Efficient one-step melt-compounding of copolyetheramide/pristine clay nanocomposites using water-injection as intercalating/exfoliating aid

    Directory of Open Access Journals (Sweden)

    J. Soulestin


    Full Text Available Polyether-block-amide (PEBA /clay nanocomposites were prepared water-assisted by twin-screw extrusion. Both organomodified and pristine (i.e. purified but non-modified montmorillonite clays were used. A high-pressure differential scanning calorimetry analysis carried out in the processing conditions demonstrated that PEBA/water blend exhibits some miscibility and that amide blocks and water behave as a single phase. In addition to a significant decrease of the melting temperature, water injected into the melt plays a key role among the filler dispersion and prevents the matrix from degradation during melt-extrusion. This process enables the compounding of pristine clay-based nanocomposites whose dispersion state is high enough for the resulting mechanical performances in tension to be at least equivalent to what is reached with organomodified clay. Effects of the nanofiller dispersion onto the macromolecules’ mobility are detailed and fracture mechanisms are identified for the various structures.

  17. Modeling multi-component transport and enhanced anaerobic dechlorination processes in a single fracture-clay matrix system

    DEFF Research Database (Denmark)

    Chambon, Julie Claire Claudia; Broholm, Mette Martina; Binning, Philip John;


    and the contaminant flux out of the clay system are assessed for different distributions of microbial degradation. Results from a set of scenarios show that time to remove 90% of the initial mass is halved when dechlorination occurs in a 5 cm reaction zone in the clay at the fracture-matrix interface (from 419 to 195...... to the physical processes, mainly diffusion in the matrix, than to the biogeochemical processes, when dechlorination is assumed to take place in a limited reaction zone only. The inclusion of sequential dechlorination in clay fracture transport models is crucial, as the contaminant flux to the aquifer...... of a contaminant in a single fracture-clay matrix system coupled with a reactive model for anaerobic dechlorination. The model takes into account microbially driven anaerobic dechlorination, where sequential Monod kinetics with competitive inhibition is used to model the reaction rates, and degradation...

  18. Clay Houses (United States)

    Pedro, Cathy


    In this article, the author describes a project designed for fourth-graders that involves making clay relief sculptures of houses. Knowing the clay houses will become a family heirloom makes this lesson even more worth the time. It takes three classes to plan and form the clay, and another two to underglaze and glaze the final products.

  19. Rapid nutrient leaching to groundwater and surface water in clay soil areas

    NARCIS (Netherlands)

    Bronswijk, J.J.B.; Hamminga, W.; Oostindie, K.


    The mechanism and magnitude of nitrate leaching from grassland on a heavy clay soil were investigated by measuring nitrogen input, and nitrate concentrations in groundwater and drain discharge for two years. A bromide tracer was applied to study solute transport mechanisms. Nitrate transport in the

  20. Research and application of non-clay low damage temporary bridging drilling/completion fluids system

    Institute of Scientific and Technical Information of China (English)


    Following the basic theory of protecting gas-reservoirs from damage with the temporary bridging technology,inert calcium carbonate (CaCO3) particles,whose diameter is consistent with the size of pores or apertures in the reservoir,were selected as the bridging agent,and modified resolvable starch was selected as filtration loss reducing particles to form the non-clay low damage temporary bridging drilling/completion fluids system (NLTDFS). Under the simulated condition of the well bottom during real drillin...

  1. Viscosity and Plasticity of Latvian Illite Clays



    Due to viscosity and plasticity, clays and clay minerals are used in civil engineering, pottery and also in cosmetics and medicine as thickening agents and emulsion and suspension stabilizers. The rheological properties of clay suspensions are complex. Mostly it is an interaction between mineral composition, clay particle size and pH value and also depends on clay minerals. Clay-water suspension is non-Newtonian fluid showing thixotropic and pseudoplastic properties. Results showed that plast...

  2. Water and clay based drilling fluids: rheologic, filtration and lubricity behavior; Fluidos hidroargilosos: comportamento reologico, de filtracao e lubricidade

    Energy Technology Data Exchange (ETDEWEB)

    Amorim, Luciana V.; Pereira, Melquesedek S.; Ferreira, Heber C. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)


    The aim of this work is to provide continuity for UFCG studies presenting results of rheological, filtration and the lubricity behaviors obtained with fluids prepared with bentonite clays from Paraiba, in binary compositions, after treatment with lubricants agents. It was selected two samples of bentonite clays and four lubricants (Lub 1, Lub 2, Lub 3 and Lub 4). The results showed that: depending on the composition, the drilling fluids presented bingham and pseudo plastic rheological behaviors, and with the additives bingham behavior; among the rheological and filtration properties evaluated, the apparent viscosity, yield limiting and the water loss are the have changes with the addition of lubricants; the values of the lubricity coefficient (LC) of fluids without additives were next of 0.50, independent of the composition of the bentonite clay mixture; after addition of the lubricants, the LC of fluids reduced for values next to 0,11, independent of its concentration and lubricants the best-performing are the Lub 2 and Lub 4. (author)

  3. On The Thermal Consolidation Of Boom Clay

    CERN Document Server

    Delage, Pierre; Cui, Yu-Jun


    When a mass of saturated clay is heated, as in the case of host soils surrounding nuclear waste disposals at great depth, the thermal expansion of the constituents generates excess pore pressures. The mass of clay is submitted to gradients of pore pressure and temperature, to hydraulic and thermal flows, and to changes in its mechanical properties. In this work, some of these aspects were experimentally studied in the case of Boom clay, so as to help predicting the response of the soil, in relation with investigations made in the Belgian underground laboratory at Mol. Results of slow heating tests with careful volume change measurements showed that a reasonable prediction of the thermal expansion of the clay-water system was obtained by using the thermal properties of free water. In spite of the density of Boom clay, no significant effect of water adsorption was observed. The thermal consolidation of Boom clay was studied through fast heating tests. A simple analysis shows that the hydraulic and thermal trans...

  4. Ground-water quality and its relation to hydrogeology, land use, and surface-water quality in the Red Clay Creek basin, Piedmont Physiographic Province, Pennsylvania and Delaware (United States)

    Senior, Lisa A.


    The Red Clay Creek Basin in the Piedmont Physiographic Province of Pennsylvania and Delaware is a 54-square-mile area underlain by a structurally complex assemblage of fractured metamorphosed sedimentary and igneous rocks that form a water-table aquifer. Ground-water-flow systems generally are local, and ground water discharges to streams. Both ground water and surface water in the basin are used for drinking-water supply. Ground-water quality and the relation between ground-water quality and hydrogeologic and land-use factors were assessed in 1993 in bedrock aquifers of the basin. A total of 82 wells were sampled from July to November 1993 using a stratified random sampling scheme that included 8 hydrogeologic and 4 land-use categories to distribute the samples evenly over the area of the basin. The eight hydrogeologic units were determined by formation or lithology. The land-use categories were (1) forested, open, and undeveloped; (2) agricultural; (3) residential; and (4) industrial and commercial. Well-water samples were analyzed for major and minor ions, nutrients, volatile organic compounds (VOC's), pesticides, polychlorinated biphenyl compounds (PCB's), and radon-222. Concentrations of some constituents exceeded maximum contaminant levels (MCL) or secondary maximum contaminant levels (SMCL) established by the U.S. Environmental Protection Agency for drinking water. Concentrations of nitrate were greater than the MCL of 10 mg/L (milligrams per liter) as nitrogen (N) in water from 11 (13 percent) of 82 wells sampled; the maximum concentration was 38 mg/L as N. Water from only 1 of 82 wells sampled contained VOC's or pesticides that exceeded a MCL; water from that well contained 3 mg/L chlordane and 1 mg/L of PCB's. Constituents or properties of well-water samples that exceeded SMCL's included iron, manganese, dissolved solids, pH, and corrosivity. Water from 70 (85 percent) of the 82 wells sampled contained radon-222 activities greater than the proposed MCL of

  5. Hypoplastic model for simulation of compressibility characteristics of cement-admixed Bangkok soft clay at high water content (United States)

    Chattonjai, Piyachat


    The developed hypoplastic model for simulation of compressibility characteristics of cement-admixed Bangkok soft clay at high water content was proposed in this paper. By using unique equation, the model is able to predict the relationship between void ratio and vertical effective stress of different water and cement content of soil cement. For practically convenient utilization and understanding, the parameters of Q1 which represented to initial cement bonding of soil (the initial value of structure tensor at time = 0) and C2 which effected to the model stiffness on isotropic consolidation direction, at 45° for loading and 225° for unloading of stress response envelope, were proposed as the function of cement and water content by comparing with dry weight of soil. By numerical integration that satisfied one-dimensional settlement, the simulation results were directly compared with fifteen experimental results to verify the accuracy of the proposed model.

  6. Static and dynamic filtrations of different clay, electrolytes, polymer systems; Filtrations statiques et dynamiques de differents systemes argile, electrolytes, polymere

    Energy Technology Data Exchange (ETDEWEB)

    Li, Y.


    Filtration properties of model drilling fluids composed of water, clays, electrolytes and water soluble polymers have been studied in static and dynamic conditions on paper filters and rock slices. Filtration experiments combined with cake observations by cryo-S.E.M. and T.E.M., show the influence of the size shape of clay particles as well as their associating mode in suspension, on the texture of the cake, its permeability, and relaxation properties. These parameters depend on the nature of the electrolyte. The polymer reduces the cake permeability by enhancing the dispersion of the clay within the suspension, but mainly by plugging the porous network due its auto aggregation properties. The cake construction in dynamic conditions, is related to the state of aggregation of the initial suspension, its poly-dispersity, its sensitivity to shear rates, and also, to the permeability of the cake built at the beginning of the filtration. In all cases, the rate of thickening of the cake is slower and larger filtrate volumes are obtained compared to the static conditions. Shear rate has two effects: first, to dissociate the weak aggregates in suspension, second, to impose a size selection of the particles in the case of a poly-dispersed suspension. At high shear rates, a cake of constant thin thickness is quickly obtained. The thickness of this limiting cake depends on the fraction of small particles present in suspension, or that can be formed by dissociation of weak aggregates under shear rate. The permeability of this limiting cake formed in dynamic conditions is, as in static conditions, controlled by the size and the shape of the particles that form the cake or by the presence of a build loss reducer water soluble polymer. Filtrations carried out on Fontainebleau sandstones allow to visualize the internal cake and to precise the risks of formation damage by the drilling fluid. (author) 127 refs.

  7. Toward Accurate Adsorption Energetics on Clay Surfaces

    CERN Document Server

    Zen, Andrea; Cox, Stephen J; Hu, Xiao L; Sorella, Sandro; Alfè, Dario; Michaelides, Angelos


    Clay minerals are ubiquitous in nature, and the manner in which they interact with their surroundings has important industrial and environmental implications. Consequently, a molecular-level understanding of the adsorption of molecules on clay surfaces is crucial. In this regard computer simulations play an important role, yet the accuracy of widely used empirical force fields (FF) and density functional theory (DFT) exchange-correlation functionals is often unclear in adsorption systems dominated by weak interactions. Herein we present results from quantum Monte Carlo (QMC) for water and methanol adsorption on the prototypical clay kaolinite. To the best of our knowledge, this is the first time QMC has been used to investigate adsorption at a complex, natural surface such as a clay. As well as being valuable in their own right, the QMC benchmarks obtained provide reference data against which the performance of cheaper DFT methods can be tested. Indeed using various DFT exchange-correlation functionals yields...

  8. Clay at Nili Fossae (United States)


    , the small mesa -- a flat-topped hill -- at the center of the image is a remnant of an overlying rock layer that was eroded away. The greenish clay areas at the base of the hill were exposed by erosion of the overlying rock. The images at the upper right and lower left both show that the reddish-toned olivine occurs as sand dunes on top of the greenish clay deposits. The image at the lower right shows details of the clay-rich rock, including that they are extensively fractured into small, polygonal blocks just a few meters in size. Taken together, the CRISM and HiRISE data show that the clay-rich rocks are the oldest at the site, that they are exposed where overlying rock has been eroded away, and that the olivine is not part of the clay-rich rock. Rather it occurs in sand dunes blowing across the clay. Many more images of Nili Fossae and other clay-rich areas will be taken over the next two years. They will be used to try to understand the earliest climate of Mars that is recorded in the planet's rocks. The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) is one of six science instruments on NASA's Mars Reconnaissance Orbiter. Led by The Johns Hopkins University Applied Physics Laboratory, the CRISM team includes expertise from universities, government agencies and small businesses in the United States and abroad. CRISM's mission: Find the spectral fingerprints of aqueous and hydrothermal deposits and map the geology, composition and stratigraphy of surface features. The instrument will also watch the seasonal variations in Martian dust and ice aerosols, and water content in surface materials o leading to new understanding of the climate. NASA's Jet Propulsion Laboratory, a division of the Califonia Institute of Technology, Pasadena, manages the Mars Reconnaissance Orbiter for the NASA Science Mission Directorate, Washington. Lockheed Martin Space Systems, Denver, is the prime contractor and built the spacecraft.

  9. Factors affecting the design of slow release formulations of herbicides based on clay-surfactant systems. A methodological approach.

    Directory of Open Access Journals (Sweden)

    María Del Carmen Galán-Jiménez

    Full Text Available A search for clay-surfactant based formulations with high percentage of the active ingredient, which can yield slow release of active molecules is described. The active ingredients were the herbicides metribuzin (MZ, mesotrione (MS and flurtamone (FL, whose solubilities were examined in the presence of four commercial surfactants; (i neutral: two berols (B048, B266 and an alkylpolyglucoside (AG6202; (ii cationic: an ethoxylated amine (ET/15. Significant percent of active ingredient (a.i. in the clay/surfactant/herbicide formulations could be achieved only when most of the surfactant was added as micelles. MZ and FL were well solubilized by berols, whereas MS by ET/15. Sorption of surfactants on the clay mineral sepiolite occurred mostly by sorption of micelles, and the loadings exceeded the CEC. Higher loadings were determined for B266 and ET/15. The sorption of surfactants was modeled by using the Langmuir-Scatchard equation which permitted the determination of binding coefficients that could be used for further predictions of the sorbed amounts of surfactants under a wide range of clay/surfactant ratios. A possibility was tested of designing clay-surfactant based formulations of certain herbicides by assuming the same ratio between herbicides and surfactants in the formulations as for herbicides incorporated in micelles in solution. Calculations indicated that satisfactory FL formulations could not be synthesized. The experimental fractions of herbicides in the formulations were in agreement with the predicted ones for MS and MZ. The validity of this approach was confirmed in in vitro release tests that showed a slowing down of the release of a.i. from the designed formulations relative to the technical products. Soil dissipation studies with MS formulations also showed improved bioactivity of the clay-surfactant formulation relative to the commercial one. This methodological approach can be extended to other clay-surfactant systems for

  10. Linking the diffusion of water in compacted clays at two different time scales: tracer through-diffusion and quasielastic neutron scattering. (United States)

    González Sánchez, Fátima; Gimmi, Thomas; Jurányi, Fanni; Van Loon, Luc; Diamond, Larryn W


    Diffusion of water and solutes through compacted clays or claystones is important when assessing the barrier function of engineered or geological barriers in waste disposal. The shape and the connectivity of the pore network as well as electrostatic interactions between the diffusant and the charged clay surfaces or cations compensating negative surface charges affect the resistance of the porous medium to diffusion. Comparing diffusion measurements performed at different spatial or time scales allows identification and extraction of the different factors. We quantified the electrostatic constraint q for five different highly compacted clays (rhob = 1.85 +/- 0.05 g/cm3) using quasielastic neutron scattering (QENS) data. We then compared the QENS data with macroscopic diffusion data for the same clays and could derive the true geometric tortuosities G of the samples. Knowing the geometric and electrostatic factors for the different clays is essential when trying to predict diffusion coefficients for other conditions. We furthermore compared the activation energies Ea for diffusion at the two measurement scales. Because Ea is mostly influenced by the local, pore scale surroundings of the water, we expected the results to be similar at both scales. This was indeed the case for the nonswelling clays kaolinite and illite, which had Ea values lower than that of bulk water, but not for montmorillonite, which had values lower than that in bulk water at the microscopic scale, but larger at the macroscopic scale. The differences could be connected to the strongly temperature dependent mobility of the cations in the clays, which may act as local barriers in the narrow pores at low temperatures.

  11. Vulnerability of shallow ground water and drinking-water wells to nitrate in the United States: Model of predicted nitrate concentration in shallow, recently recharged ground water -- Input data set for clay sediment (gwava-s_clay) (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the amount of clay sediment in the soil, in percent times 1000, in the conterminous United States. The data set was used as an input data...

  12. The 1.7- to 4.2-micron spectrum of asteroid 1 Ceres - Evidence for structural water in clay minerals (United States)

    Lebofsky, L. A.; Feierberg, M. A.; Larson, H. P.; Johnson, J. R.; Tokunaga, A. T.


    A high-resolution Fourier spectrum (1.7-3.5 microns) and medium-resolution spectrophotometry (2.7-4.2 microns) were obtained for Asteroid 1 Ceres. The presence of the 3-micron absorption feature due to water of hydration was confirmed. The 3-micron feature is compared with the 3-micron bands due to water of hydration in clays and salts. It is concluded that the spectrum of Ceres shows a strong absorption at 2.7-2.8 microns due to structural OH groups in clay minerals. The dominant minerals on the surface of Ceres are therefore hydrated clay minerals structurally similar to terrestrial montmorillonites. There is also a narrow absorption feature at 3.1 microns which is attributable to a very small amount of water ice on Ceres. This is the first evidence for ice on the surface of an asteroid.

  13. Clays in natural and engineered barriers for radioactive waste confinement

    Energy Technology Data Exchange (ETDEWEB)



    The meeting covers all topics concerning natural argillaceous geological barriers and the clay material based engineered barrier systems, investigated by means of: laboratory experiments on clay samples (new analytical developments), in situ experiments in underground research laboratories, mock-up demonstrations, natural analogues, as well as numerical modelling and global integration approaches (including up-scaling processes and treatment of uncertainties). The works presented deal with: examples of broad research programs (national or international) on the role of natural and artificial clay barriers for radionuclide confinement; clay-based repository concepts: repository designs, including technological and safety issues related to the use of clay for nuclear waste confinement; geology and clay characterisation: mineralogy, sedimentology, paleo-environment, diagenesis, dating techniques, discontinuities in rock clay, fracturing, self sealing processes, role of organic matter and microbiological processes; geochemistry: pore water geochemistry, clay thermodynamics, chemical retention, geochemical modelling, advanced isotopic geochemistry; mass transfer: water status and hydraulic properties in low permeability media, pore space geometry, water, solute and gas transfer processes, colloid mediated transport, large scale movements, long-term diffusion; alteration processes: oxidation effects, hydration-dehydration processes, response to thermal stress, iron-clay interactions, alkaline perturbation; geomechanics: thermo-hydro-mechanical behaviour of clay, rheological models, EDZ characterisation and evolution, coupled behaviour and models (HM, THM, THMC). A particular interest is given to potential contributions coming from fields of activities other than radioactive waste management, which take advantage of the confinement properties of the clay barrier (oil and gas industries, gas geological storage, CO{sub 2} geological sequestration, chemical waste isolation

  14. Interaction between viruses and clays in static and dynamic batch systems. (United States)

    Syngouna, Vasiliki I; Chrysikopoulos, Constantinos V


    Bacteriophage MS2 and PhiX174 were used as surrogates for human viruses in order to investigate the interaction between viruses and clay particles. The selected phyllosilicate clays were kaolinite and bentonite (>90% montmorillonite). A series of static and dynamic experiments were conducted at two different temperatures (4 and 25 degrees C) to investigate the effect of temperature and agitation (dynamic experiments) on virus adsorption onto clays. Appropriate adsorption isotherms were determined. Electrokinetic features of bacteriophages and clays were quantified at different pH and ionic strength (IS). Moreover, interaction energies between viruses and clays were calculated for the experimental conditions (pH 7 and IS = 2 mM) by applying the DLVO theory. The experimental results shown that virus adsorption increases linearly with suspended virus concentration. The observed distribution coefficient (K(d)) was higher for MS2 than PhiX174. The observed K(d) values were higher for the dynamic than static experiments, and increased with temperature. The results of this study provided basic information for the effectiveness of clays to remove viruses by adsorption from dilute aqueous solutions. No previous study has explored the combined effect of temperature and agitation on virus adsorption onto clays.

  15. Results from an in-situ pore water chemistry experiment in opalinus clay: evidence of microbially mediated anaerobic redox processes

    Energy Technology Data Exchange (ETDEWEB)

    Wersin, P.; Mettler, S. [NAGRA - National Cooperative for the Disposal of Radioactive Waste, Wettingen (Switzerland); Canniere, P. de [SCK-CEN, Mol (Belgium); Pearson, F.J. [Ground-Water Geochemistry, New Bern (United States); Gaucher, E. [BRGM, 75 - Paris (France); Hohener, P. [BioRem, CH (Switzerland); Eichinger, L. [Hydroisotop, Schweitenkirchen (Germany); Mader, U. [Bern Univ., CH (Switzerland); Vinsot, A. [Agence Nationale pour la Gestion des Dechets Radioactifs (ANDRA), 92 - Chatenay Malabry (France); Gabler, H.E. [Federal Institute for Geosciences and Natural Resources (BGR), Hannover (Germany); Hama, K. [JNC - Japan Nuclear Cycle Development Institute (JNC) Horonobe (Japan); Hernan, P. [ENRESA, Madrid (Spain)


    Low permeability argillaceous rocks are considered potential host rocks for radioactive waste disposal in a number of countries. Characterisation of pore water chemistry is important for assessing radionuclide behaviour, but technically challenging because of intimate clay-water association. The application of different techniques, such as in-situ extraction, squeezing and leaching has led to improved understanding. However, because of potential experimental artefacts (e.g. degassing of CO{sub 2}, ingress of O{sub 2} ), significant uncertainties remain, especially with regard to pH/pCO{sub 2} and Eh conditions. Moreover, the pore water chemistry may be perturbed by the drilling procedure itself, thus leading to oxidation and biodegradation effects. In order to reduce uncertainties mentioned above and to gain deeper insight into geochemical processes regulating pH and Eh, the internationally supported Pore water Chemistry (PC) experiment was started at the Mont Terri Rock Laboratory in 2002. The basis of the study is an in-situ experiment employing the diffusive equilibration method. The field study was complemented with lab investigations which include chemical analyses for principal inorganic solutes, for reduced sulphur species and for a variety of specific organic compounds, gas measurements of core samples and a core infiltration study based on advective displacement. (authors)

  16. Water and solute transport in agricultural soils predicted by volumetric clay and silt contents (United States)

    Karup, Dan; Moldrup, Per; Paradelo, Marcos; Katuwal, Sheela; Norgaard, Trine; Greve, Mogens H.; de Jonge, Lis W.


    Solute transport through the soil matrix is non-uniform and greatly affected by soil texture, soil structure, and macropore networks. Attempts have been made in previous studies to use infiltration experiments to identify the degree of preferential flow, but these attempts have often been based on small datasets or data collected from literature with differing initial and boundary conditions. This study examined the relationship between tracer breakthrough characteristics, soil hydraulic properties, and basic soil properties. From six agricultural fields in Denmark, 193 intact surface soil columns 20 cm in height and 20 cm in diameter were collected. The soils exhibited a wide range in texture, with clay and organic carbon (OC) contents ranging from 0.03 to 0.41 and 0.01 to 0.08 kg kg- 1, respectively. All experiments were carried out under the same initial and boundary conditions using tritium as a conservative tracer. The breakthrough characteristics ranged from being near normally distributed to gradually skewed to the right along with an increase in the content of the mineral fines (particles ≤ 50 μm). The results showed that the mineral fines content was strongly correlated to functional soil structure and the derived tracer breakthrough curves (BTCs), whereas the OC content appeared less important for the shape of the BTC. Organic carbon was believed to support the stability of the soil structure rather than the actual formation of macropores causing preferential flow. The arrival times of 5% and up to 50% of the tracer mass were found to be strongly correlated with volumetric fines content. Predicted tracer concentration breakthrough points as a function of time up to 50% of applied tracer mass could be well fitted to an analytical solution to the classical advection-dispersion equation. Both cumulative tracer mass and concentration as a function of time were well predicted from the simple inputs of bulk density, clay and silt contents, and applied tracer

  17. Clay membrane made of natural high plasticity clay:

    DEFF Research Database (Denmark)

    Foged, Niels; Baumann, Jens


    Leachate containment in Denmark has throughout the years been regulated by the DIF Recommendation for Sanitary Landfill Liners (DS/R4669. It states that natural clay deposits may be used as membrane material provided the membrane and drainage system contains at least 95% of all leachate created...... into account advective ion transport as well as diffusion. Clay prospecting for clays rich in smectite has revealed large deposits of Tertiary clay of very high plasticity in the area around Rødbyhavn on the Danish island of Lolland. The natural clay contains 60-75% smectite, dominantly as a sodium......-type. The clay material has been evaluated using the standardized methods related to mineralogy, classification, compaction and permeability, and initial studies of diffusion properties have been carried out. Furthermore, at a test site the construction methods for establishing a 0.15-0.3 m thick clay membrane...

  18. Research and application of non-clay low damage temporary bridging drilling/completion fluids system

    Institute of Scientific and Technical Information of China (English)

    Xiang-zhe Jin; Zai-jun Chen; Bin Yang


    Following the basic theory of protecting gas-reservoirs from damage with the temporary bridging technology, inert calcium carbonate (CaCO3) particles, whose diameter is consistent with the size of pores or apertures in the reservoir, were selected as the bridging agent, and modified resolvable starch was selected as filtration loss reducing particles to form the non-clay low damage temporary bridging drilling/completion fluids system (NLTDFS). Under the simulated condition of the well bottom during real drilling, NLTDFS was used to conduct dynamic and static damage experiments of cores for 48 hours, respectively, and then the experimented cores were permeated with pure nitrogen from the undamaged end to the damaged one to measure their recovery of permeability. The results showed that the permeability recovery rate of the core reached 90% or so, and the damaged depth was less than 1 cm, which demonstrates that NL TDFS has higher temporary bridging effectiveness and lower damage to the gas-reservoir than other drilling fluids system. NLTDFS has been used to drill many horizontal wells, and four of them have obtained high yield of natural gas. The yield of natural gas of LPl well reached 85 X 104 m3/day after completion with the rump pipe. The formation of the stable well wall and smooth drilling led to an API loss less than 4 mL and an HTHP loss less than 15 mL.

  19. Lake responses following lanthanum-modified bentonite clay (Phoslock) application: an analysis of water column lanthanum data from 16 case study lakes

    NARCIS (Netherlands)

    Spears, B.M.; Lürling, M.F.L.L.W.; Yasseri, S.; Castro-Castellon, A.T.; Gibbs, M.; Meis, S.; McDonald, C.; McIntosh, J.; Sleep, D.; Oosterhout, van F.


    Phoslock is a lanthanum (La) modified bentonite clay that is being increasingly used as a geo-engineering tool for the control of legacy phosphorus (P) release from lake bed sediments to overlying waters. This study investigates the potential for negative ecological impacts from elevated La concentr

  20. NMR and Electrochemical Investigation of the Transport Properties of Methanol and Water in Nafion and Clay-Nanocomposites Membranes for DMFCs

    Directory of Open Access Journals (Sweden)

    Vincenzo Baglio


    Full Text Available Water and methanol transport behavior, solvents adsorption and electrochemical properties of filler-free Nafion and nanocomposites based on two smectite clays, were investigated using impedance spectroscopy, DMFC tests and NMR methods, including spin-lattice relaxation and pulsed-gradient spin-echo (PGSE diffusion under variable temperature conditions. Synthetic (Laponite and natural (Swy-2 smectite clays, with different structural and physical parameters, were incorporated into the Nafion for the creation of exfoliated nanocomposites. Transport mechanism of water and methanol appears to be influenced from the dimensions of the dispersed platelike silicate layers as well as from their cation exchange capacity (CEC. The details of the NMR results and the effect of the methanol solution concentration are discussed. Clays particles, and in particular Swy-2, demonstrate to be a potential physical barrier for methanol cross-over, reducing the methanol diffusion with an evident blocking effect yet nevertheless ensuring a high water mobility up to 130 °C and for several hours, proving the exceptional water retention property of these materials and their possible use in the DMFCs applications. Electrochemical behavior is investigated by cell resistance and polarization measurements. From these analyses it is derived that the addition of clay materials to recast Nafion decreases the ohmic losses at high temperatures extending in this way the operating range of a direct methanol fuel cell.

  1. Coupled modelling (transport-reaction) of the fluid-clay interactions and their feed back on the physical properties of the bentonite engineered clay barrier system; Modelisation couplee (transport - reaction) des interactions fluides - argiles et de leurs effets en retour sur les proprietes physiques de barrieres ouvragees en bentonite

    Energy Technology Data Exchange (ETDEWEB)

    Marty, N


    The originality of this work is to process feed back effects of mineralogical and chemical modifications of clays, in storage conditions, on their physical properties and therefore on their transport characteristics (porosity, molecular diffusion, permeability). These feed back effects are modelled using the KIRMAT code (Kinetic of Reaction and MAss Transfer) developed from the kinetic code KINDIS by adding the effect of water renewal in the mineral-solution reactive cells. KIRMAT resolves mass balance equations associated with mass transport together with the geochemical reactions in a 1D approach. After 100 000 years of simulated interaction at 100 C, with the fluid of the Callovo-Oxfordian geological level (COX) and with iron provided by the steel overpack corrosion, the montmorillonite of the clay barrier is only partially transformed (into illite, chlorite, saponite...). Only outer parts of the modelled profile seem to be significantly affected by smectite dissolution processes, mainly at the interface with the geological environment. The modifications of physical properties show a closure of the porosity at the boundaries of the barrier, by creating a decrease of mass transport by molecular diffusion, essentially at the interface with the iron. Permeability laws applied to this system show a decrease of the hydraulic conductivity correlated with the porosity evolution. Near the COX, the swelling pressure of the clays from the barrier decreases. In the major part of the modelled profile, the engineered clay barrier system seems to keep its initial physical properties (porosity, molecular diffusion, permeability, swelling pressure) and functionalities. (author)

  2. Permeameter studies of water flow through cement and clay borehole seals in granite, basalt and tuff

    Energy Technology Data Exchange (ETDEWEB)

    South, D.L.; Daemen, J.J.K.


    Boreholes near a repository must be sealed to prevent rapid migration of radionuclide-contaminated water to the accessible environment. The objective of this research is to assess the performance of borehole seals under laboratory conditions, particularly with regard to varying stress fields. Flow through a sealed borehole is compared with flow through intact rock. Cement or bentonite seals have been tested in granite, basalt, and welded tuff. The main conclusion is that under laboratory conditions, existing commercial materials can form high quality seals. Triaxial stress changes about a borehole do not significantly affect seal performance if the rock is stiffer than the seal. Temperature but especially moisture variations (drying) significantly degrade the quality of cement seals. Performance partially recovers upon resaturation. A skillfully sealed borehole may be as impermeable as the host rock. Analysis of the influence of relative seal-rock permeabilities shows that a plug with permeability one order of magnitude greater than that of the rock results in a flow increase through the hole and surrounding rock of only 1-1/2 times compared to the undisturbed rock. Since a borehole is only a small part of the total rock mass, the total effect is even less pronounced. The simplest and most effective way to decrease flow through a rock-seal system is to increase the seal length, assuming it can be guaranteed that no dominant by-pass flowpath through the rock exists.

  3. Geotechnical properties of Karwar marine clay

    Digital Repository Service at National Institute of Oceanography (India)

    Bhat, S.T.; Nayak, B.U.; Naik, R.L.

    Karwar marine clay possesses high plasticity characteristics with natural water content higher than the liquid limit. Liquidity index was as high as 1.7. Predominant clay mineral was kaolinite. Undrained shear strength showed an increasing trend...

  4. Purge water management system (United States)

    Cardoso-Neto, Joao E.; Williams, Daniel W.


    A purge water management system for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.

  5. Clay slurry and engineered soils as containment technologies for remediation of contaminated sites

    Energy Technology Data Exchange (ETDEWEB)

    Williams, J.R. [Reclamation Technology, Inc., Athens, GA (United States); Dudka, S.; Miller, W.P. [Univ. of Georgia, Athens, GA (United States); Johnson, D.O. [Argonne National Lab., IL (United States)


    Clay Slurry and Engineered Soils are containment technologies for remediation of waste disposal sites where leaching, groundwater plumes and surface runoff of contaminants are serious ecological hazards to adjacent environments. This technology is a patent-pending process which involves the use of conditioned clay materials mixed with sand and water to form a readily pourable suspension, a clay slurry, which is either placed into a trench barrier system or allowed to de-water to create Engineered Soils. The Engineered Soil forms a layer impervious to water and air, therefore by inhibiting both water and oxygen from penetrating through the soil the material. This material can be installed in layers and as a vertical barrier to create a surface barrier containment system. The clay percentage in the clay slurry and Engineered Soils varies depending on site characteristics and desired performance standards. For example Engineered Soils with 1-2% of clay (dry wt.) had a hydraulic conductivity (K) of 10{sup -8} to 10{sup -1} cm/sec. Tests of tailing materials from a kyanite and pyrite mine showed that the clay slurry was effective not only in reducing the permeability of the treated tailings, but also in decreasing their acidity due to the inherent alkalinity of the clay. The untreated tailings had pH values in the range of 2.4 - 3.1; whereas, the effluent from clay and tailings mixtures had pH values in a slightly alkaline range (7.7-7.9). Pug-mills and high volume slurry pumps can be readily adapted for use in constructing and placing caps and creating Engineered Soils. Moreover, material on site or from a local sand supply can be used to create clay slurries and engineered soils. Clay materials used in cap construction are likewise readily available commercially. As a result, the clay slurry system is very cost effective compared to other capping systems, including the commonly used High Density Polyethylene (HDPE) liner systems.

  6. Determination of water content in clay and organic soil using microwave oven (United States)

    Kramarenko, V. V.; Nikitenkov, A. N.; Matveenko, I. A.; Molokov, V. Yu; Vasilenko, Ye S.


    The article deals with the techniques of soil water content determination using microwave radiation. Its practical application would allow solving the problems of resource efficiency in geotechnical survey due to reduction of energy and resource intensity of laboratory analysis as well as its acceleration by means of decreasing labour intensity and, as a result, cost reduction. The article presents a detail analysis of approaches to soil water content determination and soil drying, considers its features and application. The study in soil of different composition, typical for Western Siberia including organic and organic-mineral ones, is a peculiarity of the given article, which makes it rather topical. The article compares and analyzes the results of the investigation into soil water content, which are obtained via conventional techniques and the original one developed by the authors, consisting in microwave drying. The authors also give recommendation on microwave technique application to dry soil.

  7. Imaging beneath the skin of large tropical rivers: Clay controls on system morphodynamics revealed by novel CHIRP sub-surface sonar and deep coring along the Fly and Strickland Rivers, Papua New Guinea (Invited) (United States)

    Aalto, R. E.; Grenfell, M.; Lauer, J. W.


    Tropical rivers dominate Earth’s fluvial fluxes for water, carbon, and mineral sediment. They are characterized by large channels and floodplains, old system histories (in comparison to many temperate rivers), frequent and prolonged periods of flooding, and a clay-dominated sediment flux transported above a sandy bed. However, limited insight is available regarding the underlying bed & floodplain strata -- material that underpins system mobility and morphodynamics. Available data commonly stems from “skin-deep” approaches such as GIS analysis of imagery, shallow sampling of a surface veneer, & topographic profiling during lower river stages. Given the large temporal & spatial scales of such systems, new approaches are needed to see below lag deposits on mobile sandy beds & deep into expansive floodbasins. Furthermore, such data are needed to test whether we can usefully interpret large tropical river morphology using direct analogies to observations from small temperate sytems. Systems responding to sea level rise, pending avulsions, or an increase/contrast in sediment load would provide especially valuable insight. We conducted a field campaign along the Fly and Strickland Rivers in Papua New Guinea (discharge ~ 5,400 CMS). Immediate results were obtained using a dual-frequency CHIRP sub-bottom profiler optimized for fluvial environments, with which we were able to image 10-20m below the river/lake bed. We were able to distinguish sandy deposits from harder clay and silt lenses and also collected bed grab samples to verify our sonar results. Deep borehole samples (5-15m), push cores, and cutbank profiles of material strength confirmed observations from the sonar profiling. We simultaneously collected side-scan sonar imagery plus DGPS water/bed elevations. Findings include: 1) The prevalence of hard clay beneath the bed at many locations along the Lower Fly and Strickland Rivers, retarding migration; 2) Unusual bed morphology along the lower Middle Fly River

  8. Advances in interaction mechanism of water (gas) on clay minerals in China

    Institute of Scientific and Technical Information of China (English)

    He Manchao; Sun Xiaoming; Zhao Jian


    Dealing with large-scale deformations in soft-rock tunnels is a very important issue in soft-rock tunnel engineering. The mechanism of this large-scale deformation is closely related to the physical and chem-ical properties of soft rock, interaction between soft rock and water, and interaction between soft rock and gas contained in soft rock. In order to gain a better predictive understanding of the governing prin-ciples associated with this phenomenon, we used experimental and theoretical methods to study the effects of point defect on physical and chemical properties of soft rock and mechanism of interaction between water (gas) and soft rock. Firstly, we calculated the impurity formation energies and transition energy levels of defects by using the first-principle calculation, the results showed the microscopic mech-anism of defects substitution in kaolinite and effects of defects on the structure of kaolinite. Moreover, comparing the experimental and theoretical results, we found the mechanism of interaction between water and soft rock. The results show that water is one of the most important factors which can induce various kinds of geological disasters. At last, the interaction between soft rock and surrounding gas as CO2, CH4 and CO is disused, the influence of surrounding gas on soft rock should not be ignored.

  9. Stable silicon isotope signatures of marine pore waters - Biogenic opal dissolution versus authigenic clay mineral formation (United States)

    Ehlert, Claudia; Doering, Kristin; Wallmann, Klaus; Scholz, Florian; Sommer, Stefan; Grasse, Patricia; Geilert, Sonja; Frank, Martin


    Dissolved silicon isotope compositions have been analysed for the first time in pore waters (δ30SiPW) of three short sediment cores from the Peruvian margin upwelling region with distinctly different biogenic opal content in order to investigate silicon isotope fractionation behaviour during early diagenetic turnover of biogenic opal in marine sediments. The δ30SiPW varies between +1.1‰ and +1.9‰ with the highest values occurring in the uppermost part close to the sediment-water interface. These values are of the same order or higher than the δ30Si of the biogenic opal extracted from the same sediments (+0.3‰ to +1.2‰) and of the overlying bottom waters (+1.1‰ to +1.5‰). Together with dissolved silicic acid concentrations well below biogenic opal saturation, our collective observations are consistent with the formation of authigenic alumino-silicates from the dissolving biogenic opal. Using a numerical transport-reaction model we find that approximately 24% of the dissolving biogenic opal is re-precipitated in the sediments in the form of these authigenic phases at a relatively low precipitation rate of 56 μmol Si cm-2 yr-1. The fractionation factor between the precipitates and the pore waters is estimated at -2.0‰. Dissolved and solid cation concentrations further indicate that off Peru, where biogenic opal concentrations in the sediments are high, the availability of reactive terrigenous material is the limiting factor for the formation of authigenic alumino-silicate phases.

  10. Removal of waterborne microorganisms by filtration using clay-polymer complexes. (United States)

    Undabeytia, Tomas; Posada, Rosa; Nir, Shlomo; Galindo, Irene; Laiz, Leonila; Saiz-Jimenez, Cesareo; Morillo, Esmeralda


    Clay-polymer composites were designed for use in filtration processes for disinfection during the course of water purification. The composites were formed by sorption of polymers based on starch modified with quaternary ammonium ethers onto the negatively charged clay mineral bentonite. The performance of the clay-polymer complexes in removal of bacteria was strongly dependent on the conformation adopted by the polycation on the clay surface, the charge density of the polycation itself and the ratio between the concentrations of clay and polymer used during the sorption process. The antimicrobial effect exerted by the clay-polymer system was due to the cationic monomers adsorbed on the clay surface, which resulted in a positive surface potential of the complexes and charge reversal. Clay-polymer complexes were more toxic to bacteria than the polymers alone. Filtration employing our optimal clay-polymer composite yielded 100% removal of bacteria after the passage of 3L, whereas an equivalent filter with granular activated carbon (GAC) hardly yielded removal of bacteria after 0.5L. Regeneration of clay-polymer complexes saturated with bacteria was demonstrated. Modeling of the filtration processes permitted to optimize the design of filters and estimation of experimental conditions for purifying large water volumes in short periods.

  11. Semianalytical Solutions for Transport in Aquifer and Fractured Clay Matrix System (United States)

    A three-dimensional mathematical model that describes transport of contaminant in a horizontal aquifer with simultaneous diffusion into a fractured clay formation is proposed. A group of analytical solutions is derived based on specific initial and boundary conditions as well as ...

  12. Effect of Application of Increasing Concentrations of Contaminated Water on the Different Fractions of Cu and Co in Sandy Loam and Clay Loam Soils

    Directory of Open Access Journals (Sweden)

    John Volk


    Full Text Available This study aimed to establish the fate of copper (Cu and cobalt (Co in sandy loam and clay loam soils that had been irrigated with increasing concentrations of contaminated water. A sequential extraction procedure was used to determine the fractions of Cu and Co in these soils. The concentration of bioavailable Cu and Co on clay loam was 1.7 times that of sandy loam soil. Cu on sandy loam soil was largely in the organic > residual > exchangeable > water-soluble > carbonate fractions, whereas on clay loam soil the element was largely in organic > exchangeable > residual > carbonate > water-soluble fractions. Co was largely observed in the exchangeable, water-soluble, and carbonate fractions, but with no particular trend observed in both soil types. When crops are grown on sandy soils that have a low capacity to hold heavy metals, the resulting effect would be high uptake of the heavy metals in crop plants. Because the predominant forms of Cu and Co vary in soils, it is expected that the metals will behave differently in the soils.

  13. Rocks, Clays, Water, and Salts: Highly Durable, Infinitely Rechargeable, Eminently Controllable Thermal Batteries for Buildings

    Directory of Open Access Journals (Sweden)

    Alan W. Rempel


    Full Text Available Materials that store the energy of warm days, to return that heat during cool nights, have been fundamental to vernacular building since ancient times. Although building with thermally rechargeable materials became a niche pursuit with the advent of fossil fuel-based heating and cooling, energy and climate change concerns have sparked new enthusiasm for these substances of high heat capacity and moderate thermal conductivity: stone, adobe, rammed earth, brick, water, concrete, and more recently, phase-change materials. While broadly similar, these substances absorb and release heat in unique patterns characteristic of their mineralogies, densities, fluidities, emissivities, and latent heats of fusion. Current architectural practice, however, shows little awareness of these differences and the resulting potential to match materials to desired thermal performance. This investigation explores that potential, illustrating the correspondence between physical parameters and thermal storage-and-release patterns in direct-, indirect-, and isolated-gain passive solar configurations. Focusing on heating applications, results demonstrate the superiority of water walls for daytime warmth, the tunability of granite and concrete for evening warmth, and the exceptional ability of phase-change materials to sustain near-constant heat delivery throughout the night.

  14. Defining an exposure-response relationship for suspended kaolin clay particulates and aquatic organisms: work toward defining a water quality guideline for suspended solids. (United States)

    Gordon, Andrew K; Palmer, Carolyn G


    Water quality guidelines for suspended solids generally rely on the percentage departure from reference condition, an approach that has been criticized. Attempts to develop a biological effects-base guideline have, however, been confounded by low data availability. Furthermore, the high biological response variability to suspended solids exposure suggests that organisms are responding not only to exposure concentration and duration but also to other mechanisms of effect associated with suspended particles (e.g., size, shape, and geochemical composition). An alternative option is to develop more situation and site specific guidelines by generating biological effects data to suspended particles of a particular geochemistry and restricted size range. With this in mind, aquatic organism responses to kaolin clay particle exposure were collated from the literature and incorporated into 2 exposure-response relationship approaches. The species sensitivity distribution approach produced a hazardous concentration affecting 5% of species estimate of 58 mg/L for mortality responses, and 36 mg/L for sublethal data. The severity-of-ill-effect approach produced similar estimates for lethal and sublethal data. These results suggest that aquatic organisms are slightly more tolerant of kaolin clay particles than particles from barite or bentonite clays, based on results from previous studies on these clay types. This type of information can enable better estimates of the risk faced by aquatic organisms exposed to suspended solids. For example, when the sediments of a particular water body are dominated by a particular type of clay particle, then the most appropriate exposure-response relationship can be applied.

  15. Viscous property of dried clay

    Institute of Scientific and Technical Information of China (English)

    XU Li-sheng; LI Jian-zhong


    One dimensional and triaxial compression tests of air-dried and oven-dried Fujinomori clay and Pisa clay were carried out. Water content is less than 4.5 % and 1.0% for air-dried and oven-dried clay specimens, respectively. In all tests, axial strain rate was changed stepwise many times and drained creep tests were performed several times during monotonic loading at a constant strain rate. Global unloading (and also reloading in some tests) was applied during which creep loading tests were performed several times. Cyclic loading with small stress amplitude and several cycles was also performed to calculate the modulus of elasticity of the clay in tests. Local displacement transducer was used in triaxial compression test to increase measuring accuracy of axial strain. The results show that air-dried and oven-dried clay have noticeable viscous properties; during global unloading, creep deformation changes from positive to negative, i.e. there exist neutral points (zero creep deformation or no creep deformation point) in global unloading part of strain-stress curve; viscous property of Fujinomori clay decreases when water content decreases, i.e. viscous property of air-dried Fujinomori clay is more significant than that of oven-dried Fujinomori clay.

  16. Diffusion and electromigration in clay bricks influenced by differences in the pore system resulting from firing

    DEFF Research Database (Denmark)

    Rörig-Dalgaard, Inge; Ottosen, Lisbeth M.; Hansen, Kurt Kielsgaard


    subdivided into three groups: bright, medium and dark colored bricks. The increasing color intensity is most probably caused by increasing firing temperatures.These three groups of bricks were investigated for saturation coefficient, open porosity, dry density and water absorption coefficient which revealed...... significant differences were encountered. The pore system was studied by using thin sections which demonstrated a change from relatively many fine pores to fewer wide pores with increasing brick firing temperatures. An additional significant difference in the pore system of each brick was found to be related...... to the distance to the surface.The influence of the pore system on ion transport through the water saturated pore system of the bricks was supported by measurements for calculation of the electrical resistance and an increasing resistance was found for increasing brick firing temperatures. The effective diffusion...

  17. Water Purification Systems (United States)


    Clearwater Pool Technologies employs NASA-developed silver/copper ionization to purify turtle and dolphin tanks, cooling towers, spas, water recycling systems, etc. The pool purifier consists of a microcomputer to monitor water conditions, a pair of metallic electrodes, and a rheostat controller. Ions are generated by passing a low voltage current through the electrodes; the silver ions kill the bacteria, and the copper ions kill algae. This technology has found broad application because it offers an alternative to chemical disinfectants. It was originally developed to purify water on Apollo spacecraft. Caribbean Clear has been using NASA's silver ionization technology for water purification for more than a decade. Two new products incorporate advancements of the basic technology. One is the AquaKing, a system designed for areas with no source of acceptable drinking water. Another is the Caribbean Clear Controller, designed for commercial pool and water park applications where sanitizing is combined with feedback control of pH and an oxidizer, chlorine or bromine. The technology was originally developed to purify water on Apollo spacecraft.

  18. Novel Anionic Clay Adsorbents for Boiler-Blow-Down Waters Reclaim and Reuse

    Energy Technology Data Exchange (ETDEWEB)

    Muhammad Sahimi; Theodore Tsotsis


    Arsenic (As) and Selenium (Se) are found in water in the form of oxyanions. Relatively high concentrations of As and Se have been reported both in power plant discharges, as well as, in fresh water supplies. The International Agency for Research on Cancer currently classifies As as a group 1 chemical, that is considered to be carcinogenic to humans. In Phase I of this project we studied the adsorption of As and Se by uncalcined and calcined layered double hydroxide (LDH). The focus of the present work is a systematic study of the adsorption of As and Se by conditioned LDH adsorbents. Conditioning the adsorbent significantly reduced the Mg and Al dissolution observed with uncalcined and calcined LDH. The adsorption rates and isotherms have been investigated in batch experiments using particles of four different particle size ranges. As(V) adsorption is shown to follow a Sips-type adsorption isotherm. The As(V) adsorption rate on conditioned LDH increases with decreasing adsorbent particle size; the adsorption capacity, on the other hand, is independent of the particle size. A homogeneous surface diffusion model (HSDM) and a bi-disperse pore model (BPM) - the latter viewing the LDH particles as assemblages of microparticles and taking into account bulk diffusion in the intraparticle pore space, and surface diffusion within the microparticles themselves - were used to fit the experimental kinetic data. The HSDM estimated diffusivity values dependent on the particle size, whereas the BPM predicted an intracrystalline diffusivity, which is fairly invariant with particle size. The removal of As(V) on conditioned LDH adsorbents was also investigated in flow columns, where the impact of important solution and operational parameters such as influent As concentration, pH, sorbent particle size and flow rate were studied. An early breakthrough and saturation was observed at higher flow rates and at higher influent concentrations, whereas a decrease in the sorbent particle

  19. Monitoring instream turbidity to estimate continuous suspended-sediment loads and yields and clay-water volumes in the upper North Santiam River Basin, Oregon, 1998-2000 (United States)

    Uhrich, Mark A.; Bragg, Heather M.


    Three real-time, instream water-quality and turbidity-monitoring sites were established in October 1998 in the upper North Santiam River Basin on the North Santiam River, the Breitenbush River, and Blowout Creek, the main tributary inputs to Detroit Lake, a large, controlled reservoir that extends from river mile 61 to 70. Suspended-sediment samples were collected biweekly to monthly at each station. Rating curves provided estimated suspended-sediment concentration in 30-minute increments from log transformations of the instream turbidity monitoring data. Turbidity was found to be a better surrogate than discharge for estimating suspended-sediment concentration. Daily and annual mean suspended-sediment loads were estimated using the estimated suspended-sediment concentrations and corresponding streamflow data. A laboratory method for estimating persistent (residual) turbidity from separate turbidity samples was developed. Turbidity was measured over time for each sample. Turbidity decay curves were derived as the suspended sediment settled. Each curve was used to estimate a turbidity value for a given settling time. Medium to fine clay particle (size clay particle persistent turbidity for each site. The monitored instream 30-minute turbidity values were converted to a calculated persistent turbidity value that would have resulted after 8.5 hours of settling in the laboratory. Persistent turbidities of 10 NTU and above were tabulated for each site. (Water of 10 NTU and above can interfere with or damage treatment filters and result in intake closures at drinking-water facilities.) A method was developed that used the persistent turbidity experiments, turbidity decay curves, and stream discharge to estimate the volume of water containing suspended clay that entered Detroit Lake from the three main tributaries. 'Suspended-clay water' was defined as water having a value of at least 10 NTU after settling the required 8.5 hours. The suspended-clay concentrations of 10

  20. Stiff clay masses: big storages of fossil and renewable energy (United States)

    Spilotro, Giuseppe; Fidelibus, Maria Dolores; Qeraxhiu, Lydra; Argentiero, Ilenia; Pellicani, Roberta


    The crystalline structure of the clay and its behaviour at the micro and macro scale have been and are still the object of studies in different fields of earth science: mineralogy, geotechnics, etc. It has been known for several decades that the volumetric equilibrium of a well-defined clay (mono mineralogical or mineralogical melange, with or without the mixing with other fines), depends on the salinity of the interstitial fluid (in terms of concentration of one or more kind of salts) under a stress field. The mechanism is very complex involving many chemical and physical topics, but may be easy to understand: the elementary structures of a two faced crystals are electrically negative charged with the interstitial fluid as the dielectric of a capacitor. Consequently, an electrical field is generated whose intensity depends on the electric charge and the properties of the dielectric. Such electric field can produce mechanical work, enlarging the faces of the capacitor, unless external forces prevent it. If external forces exceed the internal ones, the system behaves as a loaded spring, which stores energy of deformation to give back as soon as the external force weakens. The clay of marine sedimentation incorporates interstitial salt water of composition derived and similar to those of sea water. Such type of interstitial water chemically has high concentration of dissolved ions, mainly Na, which generates in the dielectric spaces a low electrical field, compared with that given in identical situation by low salt concentration in interstitial water. In nature, as well described in geoscience, the turning between the two interstitial water types is very common and driven by ion diffusion processes like, surface fresh water interacting with salt interstitial water of old marine clays. The latter, either by the overburden of younger sedimentary layers, but mainly by very strong capillary forces activated by surface drainage and EVT from sun and dry wind, undergo

  1. 1st International Conference on Calcined Clays for Sustainable Concrete

    CERN Document Server

    Favier, Aurélie


    This volume focuses on research and practical issues linked to Calcined Clays for Sustainable Concrete. The main subjects are geology of clays, hydration and performance of blended systems with calcined clays, alkali activated binders, economic and environmental impacts of the use of calcined clays in cement based materials. Topics addressed in this book include the influence of processing on reactivity of calcined clays, influence of clay mineralogy on reactivity, geology of clay deposits, Portland-calcined clay systems, hydration, durability, performance, Portland-calcined clay-limestone systems, hydration, durability, performance, calcined clay-alkali systems, life cycle analysis, economics and environmental impact of use of calcined clays in cement and concrete, and field applications. This book compiles the different contributions of the 1st International Conference on Calcined Clays for Sustainable Concrete, which took place in Lausanne, Switzerland, June, 23-25, 2015.The papers present the latest  res...

  2. In situ synthesis of nano clay filled polyethylene using polymer support metallocenes catalyst system

    Energy Technology Data Exchange (ETDEWEB)

    Murthy, Z.V.P.; Parikh, Parimal A., E-mail: [Sardar Vallabhbhai National Institute of Technology, Gujarat (India). Chemical Engineering Department; Rajesh, Smitha [Sardar Vallabhbhai National Institute of Technology, Gujarat (India). Sardar Vallabhbhai National Institute of Technology. Chemical Engineering Department


    In situ ethylene polymerizations were performed using bis(cyclopentadiene)titanium dichloride supported on poly ethersulfone as catalyst. The bis(cyclopentadiene)titanium dichloride supported on poly ethersulfone catalyst activity estimated by ethylene polymerization was 360 kg PE/mol Ti/h. During polymerization the fillers used were montmorillonite nano clays having surface modifications with 35-45 wt % dimethyl dialkyl(14-18)amine (FA) and 25-30 wt % trimethyl stearyl ammonium (FB). These fillers were pretreated with methylaluminoxine (MAO; co catalyst) for better dispersion onto the polymer matrix. The formation of polyethylene within the whole matrix was confirmed by FTIR studies. It was found that the nature of nano filler did not have any remarkable effect on the melting characteristics of the polymer. TGA study indicates that nano clay FB filled polyethylene has higher thermal stability than nano clay FA filled polyethylene. The melting temperature of the obtained polyethylenes was 142 degree C, which corresponds to that synthesized by the polyether sulfone supported catalyst. (author)


    Energy Technology Data Exchange (ETDEWEB)

    T.M. Whitworth; Liangxiong Li


    This report describes work performed during the first year of the project ''Modified Reverse Osmosis System for Treatment of Produced Waters.'' This research project has two objectives. The first objective is to test the use of clay membranes in the treatment of produced waters by reverse osmosis. The second objective is to test the ability of a system patented by the New Mexico Tech Research Foundation to remove salts from reverse osmosis waste streams as a solid. We performed 12 experiments using clay membranes in cross-flow experimental cells. We found that, due to dispersion in the porous frit used adjacent to the membrane, the concentration polarization layer seems to be completely (or nearly completely) destroyed at low flow rates. This observation suggests that clay membranes used with porous frit material many reach optimum rejection rates at lower pumping rates than required for use with synthetic membranes. The solute rejection efficiency decreases with increasing solution concentration. For the membranes and experiments reported here, the rejection efficiency ranged from 71% with 0.01 M NaCl solution down to 12% with 2.3 M NaCl solution. More compacted clay membranes will have higher rejection capabilities. The clay membranes used in our experiments were relatively thick (approximately 0.5 mm). The active layer of most synthetic membranes is only 0.04 {micro}m (0.00004 mm), approximately 1250 times thinner than the clay membranes used in these experiments. Yet clay membranes as thin as 12 {micro}m have been constructed (Fritz and Eady, 1985). Since Darcy's law states that the flow through a material of constant permeability is inversely proportional to it's the material's thickness, then, based on these experimental observations, a very thin clay membrane would be expected to have much higher flow rates than the ones used in these experiments. Future experiments will focus on testing very thin clay membranes. The

  4. Water Powered Bioassay System (United States)


    capillary micropump 27 Figure 30: Slow dripping/separation of a droplet from a capillary 4.1.5 Micro Osmotic Pumping Nano Droplet...stored and delivered fluidic pressure and, with a combination of pumps and valves, formed the basic micro fluidic processing unit. The addition of...System, Microvalve, Micro -Accumulator, Micro Dialysis Needle, Bioassay System, Water Activated, Micro Osmotic Pump 16. PRICE CODE 17. SECURITY

  5. Effects of clay dispersion on aquifer storage and recovery in coastal aquifers (United States)

    Konikow, L.F.; August, L.L.; Voss, C.I.


    Cyclic injection, storage, and withdrawal of freshwater in brackish aquifers is a form of aquifer storage and recovery (ASR) that can beneficially supplement water supplies in coastal areas. A 1970s field experiment in Norfolk, Virginia, showed that clay dispersion in the unconsolidated sedimentary aquifer occurred because of cation exchange on clay minerals as freshwater displaced brackish formation water. Migration of interstitial clay particles clogged pores, reduced permeability, and decreased recovery efficiency, but a calcium preflush was found to reduce clay dispersion and lead to a higher recovery efficiency. Column experiments were performed in this study to quantify the relations between permeability changes and clay mineralogy, clay content, and initial water salinity. The results of these experiments indicate that dispersion of montmorillonite clay is a primary contributor to formation damage. The reduction in permeability by clay dispersion may be expressed as a linear function of chloride content. Incorporating these simple functions into a radial, cross-sectional, variable-density, ground-water flow and transport model yielded a satisfactory simulation of the Norfolk field test - and represented an improvement over the model that ignored changes in permeability. This type of model offers a useful planning and design tool for ASR operations in coastal clastic aquifer systems.

  6. Relationship between specific surface area and the dry end of the water retention curve for soils with varying clay and organic carbon contents

    DEFF Research Database (Denmark)

    Resurreccion, Augustus C.; Møldrup, Per; Tuller, Markus;


    with ethylene glycol monoethyl ether (SA_EGME) only for organic soils with n > 10. A strong correlation between the ratio of the two surface area estimates and the Dexter number was observed and applied as an additional scaling function in the TO model to rescale the soil water retention curve at low water...... dominate over capillary forces, have also been used to estimate soil specific surface area (SA). In the present study, the dry end of the SWRC was measured with a chilled-mirror dew point psychrometer for 41 Danish soils covering a wide range of clay (CL) and organic carbon (OC) contents. The 41 soils were...

  7. Contact micromechanics in granular media with clay

    Energy Technology Data Exchange (ETDEWEB)

    Ita, Stacey Leigh [Univ. of California, Berkeley, CA (United States)


    Many granular materials, including sedimentary rocks and soils, contain clay particles in the pores, grain contacts, or matrix. The amount and location of the clays and fluids can influence the mechanical and hydraulic properties of the granular material. This research investigated the mechanical effects of clay at grain-to-grain contacts in the presence of different fluids. Laboratory seismic wave propagation tests were conducted at ultrasonic frequencies using spherical glass beads coated with Montmorillonite clay (SWy-1) onto which different fluids were adsorbed. For all bead samples, seismic velocity increased and attenuation decreased as the contact stiffnesses increased with increasing stress demonstrating that grain contacts control seismic transmission in poorly consolidated and unconsolidated granular material. Coating the beads with clay added stiffness and introduced viscosity to the mechanical contact properties that increased the velocity and attenuation of the propagating seismic wave. Clay-fluid interactions were studied by allowing the clay coating to absorb water, ethyl alcohol, and hexadecane. Increasing water amounts initially increased seismic attenuation due to clay swelling at the contacts. Attenuation decreased for higher water amounts where the clay exceeded the plastic limit and was forced from the contact areas into the surrounding open pore space during sample consolidation. This work investigates how clay located at grain contacts affects the micromechanical, particularly seismic, behavior of granular materials. The need for this work is shown by a review of the effects of clays on seismic wave propagation, laboratory measurements of attenuation in granular media, and proposed mechanisms for attenuation in granular media.

  8. Carbon sequestration in clay and silt fractions of Brazilian soils under conventional and no-tillage systems

    Directory of Open Access Journals (Sweden)

    Cecília Estima Sacramento dos Reis


    Full Text Available The capacity of soils to sequestrate carbon (C is mainly related to the formation of organo-mineral complexes. In this study, we investigated the influence of soil management systems on the C retention capacity of soil with an emphasis on the silt and clay fractions of two subtropical soils with different mineralogy and climate. Samples from a Humic Hapludox and a Rhodic Hapludox, clayey soils cultivated for approximately 30 years under no-tillage (NT and conventional tillage (CT were collected from six layers distributed within 100-cm soil depth from each site and from an adjacent native forest. After the removal of particulate organic matter (POM, the suspension (<53 µm was sonicated, the silt and clay fractions were separated in accordance with Stokes' law and the carbon content of whole soil and physical fractions was determined. In the Humic Hapludox, the clay and silt fractions under NT showed a higher maximum C retention (72 and 52 g kg-1, respectively in comparison to those under CT (54 and 38 g kg-1, respectively. Moreover, the C concentration increase in both fractions under NT occurred mainly in the topsoil (up to 5 cm. The C retention in physical fractions of Rhodic Hapludox varied from 25 to 32 g kg-1, and no difference was observed whether under an NT or a CT management system. The predominance of goethite and gibbsite in the Humic Hapludox, as well as its exposure to a colder climate, may have contributed to its greater C retention capacity. In addition to the organo-mineral interaction, a mechanism of organic matter self-assemblage, enhanced by longer periods of soil non-disturbance, seems to have contributed to the carbon stabilization in both soils.

  9. Using GPR early-time amplitude analysis to monitor variations in soil water content at a clay-rich agricultural site in response to irrigation (United States)

    Algeo, Jonathan; Van Dam, Remke; Slater, Lee


    Geophysical methods are increasingly used to analyze spatial variation in soil water content (SWC). Electrical resistivity (ER), ground-penetrating radar (GPR), and time-domain reflectometry (TDR) have all been applied to this problem. However, TDR is limited in terms of its ability to provide good spatial coverage over large areas, ER can be very time consuming depending on the survey, and GPR direct wave and reflection methods are ineffective in clay-rich environments. We employed a relatively new GPR methodology, early-time amplitude analysis, during an infiltration experiment conducted in a clay-rich agricultural field. The research took place at the Samford Ecological Research Facility, Queensland, Australia, with the goal of monitoring changes in SWC in response to irrigation. We hypothesize that early-time analysis can be used to detect and monitor infiltration in clay-rich soils where direct wave and reflection GPR fails, thus opening new avenues of hydrogeophysical research in the increasingly important field of water resource management. Initial field work showed that traditional methods of using GPR reflection surveys and ground wave velocity analysis were ineffective due to the excessive signal attenuation caused by the clay-rich soil at the site. GPR and TDR datasets were collected over a 20 meter by 15 meter section of the field. GPR datasets were collected once daily, at 10 am, and TDR measurements were collected once daily at 11 am from Thursday, August 28th, 2014 until Monday, September 1st, 2014. A sprinkler irrigation was carried out on the evening of Thursday, August 28th. The results suggest that the early-time GPR method is capable of monitoring the resulting changes in SWC due to infiltration in clayey soils despite the failure of reflection and ground wave velocity analysis. The early time GPR results are consistent with moisture content estimates from TDR and gravimetric analysis of soil cores taken in the field.

  10. Novel system for reducing leaching of the herbicide metribuzin using clay-gel-based formulations


    Maqueda Porras, Celia; Villaverde Capellán, J.; Sopeña Vázquez, F.; Undabeytia López, Tomás; Morillo González, Esmeralda


    Metribuzin is an herbicide widely used for weed control that has been identified as a groundwater pollutant. It contaminates the environment even when it is used according to the manufacturer's instructions. To reduce herbicide leaching and increase weed control, new controlled release formulations were developed by entrapping metribuzin within a sepiolite-gel-based matrix using two clay/herbicide proportions (0.5/0.2 and 1/0.2) (loaded at 28.6 and 16.7% a.i.) as a gel (G28, G16) or as a powd...

  11. Biogeochemical processes in a clay formation in situ experiment: Part A - Overview, experimental design and water data of an experiment in the Opalinus Clay at the Mont Terri Underground Research Laboratory, Switzerland

    Energy Technology Data Exchange (ETDEWEB)

    Wersin, P., E-mail: [NAGRA, Hardstrasse 73, 5430 Wettingen (Switzerland)] [Gruner Ltd., Gellertstrasse 55, 4020 Basel (Switzerland); Leupin, O.X. [NAGRA, Hardstrasse 73, 5430 Wettingen (Switzerland); Mettler, S. [NAGRA, Hardstrasse 73, 5430 Wettingen (Switzerland)] [Solexperts Ltd., Mettlenbachstrasse 25, 8617 Moenchaltorf (Switzerland); Gaucher, E.C. [BRGM, 3 avenue Claude Guillemin, B.P. 36009, 45060 Orleans Cedex 2 (France); Maeder, U. [University of Bern, Institute of Geological Sciences, Baltzerstrasse 3, CH-3012 Bern (Switzerland); De Canniere, P. [SCK.CEN, Waste and Disposal Project, Boeretang 200, 2400 Mol (Belgium); Vinsot, A. [ANDRA, Laboratoire de Recherche Souterrain de Meuse/Haute-Marne, RD960 BP9, 55290 Bure (France); Gaebler, H.E. [BGR, Stilleweg 2, 30655 Hannover (Germany); Kunimaro, T. [JAEA, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Kiho, K. [CRIEPI, 1646 Abiko, Abiko-city Chiba 270-1194 (Japan); Eichinger, L. [Hydroisotop, 85301 Schweitenkirchen (Germany)


    Highlights: > The composition was affected by the complex interplay of diffusion, mineral and surface reactions. > The {sup 13}C signals for carbon species showed significant variations which could only be partly explained. > The main cations remained remarkably constant during the experiment. > This underlines the strong buffering via cation exchange and carbonate dissolution/precipitation. - Abstract: An in situ test in the Opalinus Clay formation, termed porewater chemistry (PC) experiment, was carried out for a period of 5 years. It was based on the concept of diffusive equilibration whereby a traced water with a composition close to that expected in the formation was continuously circulated and monitored in a packed-off borehole. The main original focus was to obtain reliable data on the pH/pCO{sub 2} conditions of the porewater, but because of unexpected microbiologically-induced redox reactions, the objective was extended to elucidate the biogeochemical processes occurring in the borehole and to understand their impact on pH/pCO{sub 2} and porewater chemistry in the low permeability clay formation. The behaviour of the conservative tracers {sup 2}H and Br{sup -} could be explained by diffusive dilution in the clay and moreover the results showed that diffusive equilibration between the borehole water and the formation occurred within about 3 year's time. However, the composition and pH/pCO{sub 2} conditions differed considerably from those of the in situ porewater. Thus, pH was lower and pCO{sub 2} was higher than indicated by complementary laboratory investigations. The noted differences are explained by microbiologically-induced redox reactions occurring in the borehole and in the interfacial wall area which were caused by an organic source released from the equipment material. The degradation of this source was accompanied by sulfate reduction and - to a lesser extent - by methane generation, which induced a high rate of acetogenic reactions

  12. Evaluation of Turf-Grass and Prairie-Vegetated Rain Gardens in a Clay and Sand Soil, Madison, Wisconsin, Water Years 2004-08 (United States)

    Selbig, William R.; Balster, Nicholas


    The U.S. Geological Survey, in cooperation with a consortium of 19 cities, towns, and villages in Dane County, Wis., undertook a study to compare the capability of rain gardens with different vegetative species and soil types to infiltrate stormwater runoff from the roof of an adjacent structure. Two rain gardens, one planted with turf grass and the other with native prairie species, were constructed side-by-side in 2003 at two locations with different dominant soil types, either sand or clay. Each rain garden was sized to a ratio of approximately 5:1 contributing area to receiving area and to a depth of 0.5 foot. Each rain garden, regardless of vegetation or soil type, was capable of storing and infiltrating most of the runoff over the 5-year study period. Both rain gardens in sand, as well as the prairie rain garden in clay, retained and infiltrated 100 percent of all precipitation and snowmelt events during water years 2004-07. The turf rain garden in clay occasionally had runoff exceed its confining boundaries, but was still able to retain 96 percent of all precipitation and snowmelt events during the same time period. Precipitation intensity and number of antecedent dry days were important variables that influenced when the storage capacity of underlying soils would become saturated, which resulted in pooled water in the rain gardens. Because the rooftop area that drained runoff to each rain garden was approximately five times larger than the area of the rain garden itself, evapotranspiration was a small percentage of the annual water budget. For example, during water year 2005, the maximum evapotranspiration of total influent volume ranged from 21 percent for the turf rain garden in clay to 25 percent for the turf rain garden in sand, and the minimum ranged from 12 percent for the prairie rain garden in clay to 19 percent for the prairie rain garden in sand. Little to no runoff left each rain garden as effluent and a small percentage of runoff returned to the

  13. Simulation of streamflow and water quality in the White Clay Creek subbasin of the Christina River Basin, Pennsylvania and Delaware, 1994-98 (United States)

    Senior, Lisa A.; Koerkle, Edward H.


    The Christina River Basin drains 565 square miles (mi2) in Pennsylvania, Maryland, and Delaware. Water from the basin is used for recreation, drinking water supply, and to support aquatic life. The Christina River Basin includes the major subbasins of Brandywine Creek, White Clay Creek, and Red Clay Creek. The White Clay Creek is the second largest of the subbasins and drains an area of 108 mi2. Water quality in some parts of the Christina River Basin is impaired and does not support designated uses of the streams. A multi-agency water-quality management strategy included a modeling component to evaluate the effects of point and nonpoint-source contributions of nutrients and suspended sediment on stream water quality. To assist in non point-source evaluation, four independent models, one for each of the three major subbasins and for the Christina River, were developed and calibrated using the model code Hydrological Simulation Program?Fortran (HSPF). Water-quality data for model calibration were collected in each of the four main subbasins and in smaller subbasins predominantly covered by one land use following a nonpoint-source monitoring plan. Under this plan, stormflow and base- flow samples were collected during 1998 at two sites in the White Clay Creek subbasin and at nine sites in the other subbasins. The HSPF model for the White Clay Creek Basin simulates streamflow, suspended sediment, and the nutrients, nitrogen and phosphorus. In addition, the model simulates water temperature, dissolved oxygen, biochemical oxygen demand, and plankton as secondary objectives needed to support the sediment and nutrient simulations. For the model, the basin was subdivided into 17 reaches draining areas that ranged from 1.37 to 13 mi2. Ten different pervious land uses and two impervious land uses were selected for simulation. Land-use areas were determined from 1995 land-use data. The predominant land uses in the White Clay Creek Basin are agricultural, forested, residential

  14. Chemical and mineralogical characteristics of French green clays used for healing (United States)

    Williams, L.B.; Haydel, S.E.; Giese, R.F.; Eberl, D.D.


    The worldwide emergence of infectious diseases, together with the increasing incidence of antibiotic-resistant bacteria, elevate the need to properly detect, prevent, and effectively treat these infections. The overuse and misuse of common antibiotics in recent decades stimulates the need to identify new inhibitory agents. Therefore, natural products like clays, that display antibacterial properties, are of particular interest. The absorptive properties of clay minerals are well documented for healing skin and gastrointestinal ailments. However, the antibacterial properties of clays have received less scientific attention. French green clays have recently been shown to heal Buruli ulcer, a necrotic or 'flesh-eating' infection caused by Mycobacterium ulcerans. Assessing the antibacterial properties of these clays could provide an inexpensive treatment for Buruli ulcer and other skin infections. Antimicrobial testing of the two clays on a broad-spectrum of bacterial pathogens showed that one clay promotes bacterial growth (possibly provoking a response from the natural immune system), while another kills bacteria or significantly inhibits bacterial growth. This paper compares the mineralogy and chemical composition of the two French green clays used in the treatment of Buruli ulcer. Mineralogically, the two clays are dominated by 1Md illite and Fe-smectite. Comparing the chemistry of the clay minerals and exchangeable ions, we conclude that the chemistry of the clay, and the surface properties that affect pH and oxidation state, control the chemistry of the water used to moisten the clay poultices and contribute the critical antibacterial agent(s) that ultimately debilitate the bacteria. Copyright ?? 2008, The Clay Minerals Society.


    Energy Technology Data Exchange (ETDEWEB)

    T.M. Whitworth; Liangxiong Li


    This report describes work performed during the second year of the project ''Modified reverse osmosis system for treatment of produced waters.'' We performed two series of reverse osmosis experiments using very thin bentonite clay membranes compacted to differing degrees. The first series of 10 experiments used NaCl solutions with membranes that ranged between 0.041 and 0.064mm in thickness. Our results showed compaction of such ultra-thin clay membranes to be problematic. The thickness of the membranes was exceeded by the dimensional variation in the machined experimental cell and this is believed to have resulted in local bypassing of the membrane with a resultant decrease in solute rejection efficiency. In two of the experiments, permeate flow was varied as a percentage of the total flow to investigate results of changing permeate flow on solute rejection. In one experiment, the permeate flow was varied between 2.4 and 10.3% of the total flow with no change in solute rejection. In another experiment, the permeate flow was varied between 24.6 and 52.5% of the total flow. In this experiment, the solute rejection rate decreased as the permeate occupied greater fractions of the total flow. This suggests a maximum solute rejection efficiency for these clay membranes for a permeate flow of between 10.3 and 24.6% of the total; flow. Solute rejection was found to decrease with increasing salt concentration and ranged between 62.9% and 19.7% for chloride and between 61.5 and 16.8% for sodium. Due to problems with the compaction procedure and potential membrane bypassing, these rejection rates are probably not the upper limit for NaCl rejection by bentonite membranes. The second series of four reverse osmosis experiments was conducted with a 0.057mm-thick bentonite membrane and dilutions of a produced water sample with an original TDS of 196,250 mg/l obtained from a facility near Loco Hill, New Mexico, operated by an independent. These experiments

  16. Organic Control of Dioctahedral and Trioctahedral Clay Formation in an Alkaline Soil System in the Pantanal Wetland of Nhecolândia, Brazil (United States)

    Meunier, Jean-François; Martins-Silva, Elisângela R.; Furian, Sonia


    Recent studies have focused on the formation of authigenic clays in an alkaline soil system surrounding lakes of the Nhecolândia region, Pantanal wetland. The presence of trioctahedral Mg-smectites (stevensite and saponite types), which requires low Al and Fe contents in the soil solution for its formation, contrasts with the neoformation of dioctahedral Fe-mica (glauconite, and Fe-illite), which instead requires solutions relatively enriched in Al and Fe. This study aims to understand the conditions of co-existence of both, Mg-smectite and Fe-mica a common clay association in former or modern alkaline soil systems and sediments. The study was carried out along an alkaline soil catena representative of the region. The soil organization revealed that Mg-smectite occur in top soil close to the lake, whereas Fe-mica dominate in the clay fraction of deeper greenish horizons a few meters apart. We propose here that this spatial distribution is controlled by the lateral transfer of Fe and Al with organic ligands. Alkaline organic rich solutions (DOC up to 738 mg L-1) collected in the watertable were centrifuged and filtered through membranes of decreasing pore size (0.45 μm, 0.2 μm, 30 KDa, 10 KDa, 3 KDa) to separate colloidal and dissolved fractions. Fe, Al, Si, Mg and K were analysed for each fraction. Although the filtration had no influence on Si and K contents, almost 90% of Fe (up to 2.3 mg L-1) and Al (up to 7 mg L-1) are retained at the first cutoff threshold of 0.45μm. The treatment of the same solutions by oxygen peroxide before filtration shows that a large proportion of Fe and Al were bonded to organic colloids in alkaline soil solution at the immediate lake border, allowing Mg-smectite precipitation. The fast mineralization of the organic matter a few meters apart from the lake favors the release of Fe and Al necessary for Fe-mica neoformation. In comparison with chemical and mineralogical characteristics of alkaline environments described in the

  17. Organic Control of Dioctahedral and Trioctahedral Clay Formation in an Alkaline Soil System in the Pantanal Wetland of Nhecolândia, Brazil. (United States)

    Barbiero, Laurent; Berger, Gilles; Rezende Filho, Ary T; Meunier, Jean-François; Martins-Silva, Elisângela R; Furian, Sonia


    Recent studies have focused on the formation of authigenic clays in an alkaline soil system surrounding lakes of the Nhecolândia region, Pantanal wetland. The presence of trioctahedral Mg-smectites (stevensite and saponite types), which requires low Al and Fe contents in the soil solution for its formation, contrasts with the neoformation of dioctahedral Fe-mica (glauconite, and Fe-illite), which instead requires solutions relatively enriched in Al and Fe. This study aims to understand the conditions of co-existence of both, Mg-smectite and Fe-mica a common clay association in former or modern alkaline soil systems and sediments. The study was carried out along an alkaline soil catena representative of the region. The soil organization revealed that Mg-smectite occur in top soil close to the lake, whereas Fe-mica dominate in the clay fraction of deeper greenish horizons a few meters apart. We propose here that this spatial distribution is controlled by the lateral transfer of Fe and Al with organic ligands. Alkaline organic rich solutions (DOC up to 738 mg L-1) collected in the watertable were centrifuged and filtered through membranes of decreasing pore size (0.45 μm, 0.2 μm, 30 KDa, 10 KDa, 3 KDa) to separate colloidal and dissolved fractions. Fe, Al, Si, Mg and K were analysed for each fraction. Although the filtration had no influence on Si and K contents, almost 90% of Fe (up to 2.3 mg L-1) and Al (up to 7 mg L-1) are retained at the first cutoff threshold of 0.45μm. The treatment of the same solutions by oxygen peroxide before filtration shows that a large proportion of Fe and Al were bonded to organic colloids in alkaline soil solution at the immediate lake border, allowing Mg-smectite precipitation. The fast mineralization of the organic matter a few meters apart from the lake favors the release of Fe and Al necessary for Fe-mica neoformation. In comparison with chemical and mineralogical characteristics of alkaline environments described in the

  18. Transition metal modified and partially calcined inorganic-organic pillared clays for the adsorption of salicylic acid, clofibric acid, carbamazepine, and caffeine from water. (United States)

    Cabrera-Lafaurie, Wilman A; Román, Félix R; Hernández-Maldonado, Arturo J


    Pharmaceutical and Personal Care Products (PPCPs) are considered emerging contaminants, and their efficient removal from water is going to be a challenging endeavor. Microporous adsorbent materials, including pillared clays, could offer a potential solution if tailored properly. Although pillared clays have been employed previously for the removal of organics, the effective removal of PPCPs will only be possible if their surface and textural properties are manipulated from the bottom-up. This work presents the use of modified inorganic-organic pillared clays (IOCs) for the adsorption of salicylic acid, clofibric acid, carbamazepine, and caffeine. The IOCs have been modified with Co(2+), Cu(2+), or Ni(2+) to induce complexation-like adsorbate-adsorbent interactions at ambient conditions, in an attempt to provide an efficient and yet reversible driving force in the sub-ppm concentration range. Furthermore, the IOCs were partially calcined to increase effective surface area by an order of magnitude while preserving some hydrophobicity. In general, the Ni(2+) IOCs exhibited the greatest interaction with salicylic and clofibric acids, respectively, while the Co(2+) adsorbents excelled at adsorbing caffeine at low concentrations. All of the metal-modified IOCs showed comparable adsorption capacities for the case of carbamazepine, probably due to the lack of availability of particular functional groups in this adsorbate.

  19. Simulation of streamflow and water quality in the Red Clay Creek subbasin of the Christina River Basin, Pennsylvania and Delaware, 1994-98 (United States)

    Senior, Lisa A.; Koerkle, Edward H.


    (mi2) in Pennsylvania and Delaware and includes the major subbasins of Red Clay Creek, White Clay Creek, Brandywine Creek, and Christina River. The Red Clay Creek is the smallest of the subbasins and drains an area of 54 mi2. Streams in the Christina River Basin are used for recreation, drinking-water supply, and to support aquatic life. Water quality in some parts of the Christina River Basin is impaired and does not support designated uses of the stream. A multi-agency, waterquality management strategy included a modeling component to evaluate the effects of point and nonpointsource contributions of nutrients and suspended sediment on stream water quality. To assist in nonpointsource evaluation, four independent models, one for each of the four main subbasins of the Christina River Basin, were developed and calibrated using the model code Hydrological Simulation Program?Fortran (HSPF). Water-quality data for model calibration were collected in each of the four main subbasins and in smaller subbasins predominantly covered by one land use following a nonpoint-source monitoring plan. Under this plan, stormflow and base-flow samples were collected during 1998 at 1 site in the Red Clay Creek subbasin and at 10 sites elsewhere in the Christina River Basin. The HSPF model for the Red Clay Creek subbasin simulates streamflow, suspended sediment, and the nutrients, nitrogen and phosphorus. In addition, the model simulates water temperature, dissolved oxygen, biochemical oxygen demand, and plankton as secondary objectives needed to support the sediment and nutrient simulations. For the model, the basin was subdivided into nine reaches draining areas that ranged from 1.7 to 10 mi2. One of the reaches contains a regulated reservoir. Ten different pervious land uses and two impervious land uses were selected for simulation. Land-use areas were determined from 1995 land-use data. The predominant land uses in the Red Clay Creek subbasin are agricultural, forested, residential

  20. Public Water Supply Systems (PWS) (United States)

    Kansas Data Access and Support Center — This dataset includes boundaries for most public water supply systems (PWS) in Kansas (525 municipalities, 289 rural water districts and 13 public wholesale water...

  1. Simulation Of Enhanced Reductive Dechlorination For Remediation Of Tce In A Fractured Clay System: A New Model Approach And Application To Field Site

    DEFF Research Database (Denmark)

    Manoli, Gabriele; Chambon, Julie Claire Claudia; Christiansen, Camilla Maymann;


    with interspersed sand lenses and stringers. The transport model couples diffusion dominated transport in the clay matrix, with advective‐dispersive transport in the fractures and higher permeability sand lenses. The reactive model calculates sequential reductive dechlorination of TCE (trichloroethylene) to its...... a contamination of trichloroethylene located in a fractured clay till. The site is simulated using the model developed. Fracture geometry, site parameters and degradation rates are based on observations from the site and lab studies. The risk for drinking water is assessed and cleanup times are simulated using...

  2. Clay particle retention in small constructed wetlands. (United States)

    Braskerud, B C


    Constructed wetlands (CWs) can be used to mitigate non-point source pollution from arable fields. Previous investigations have shown that the relative soil particle retention in small CWs increases when hydraulic load increases. This paper investigates why this phenomenon occurs, even though common retention models predict the opposite, by studying clay and silt particle retention in two Norwegian CWs. Retention was measured with water flow proportional sampling systems in the inlet and outlet of the wetlands, and the texture of the suspended solids was analyzed. The surface area of the CWs was small compared to the watershed area (approximately 0.07%), giving high average hydraulic loads (1.1 and 2.0 md(-1)). One of the watersheds included only old arable land, whereas the other included areas with disturbed topsoil after artificial land leveling. Clay particle retention was 57% for the CW in the first watershed, and 22% for the CW in the disturbed watershed. The different behavior of the wetlands could be due to differences in aggregate size and stability of the particles entering the wetlands. Results showed that increased hydraulic loads did affect CW retention negatively. However, as runoff increased, soil particles/aggregates with higher sedimentation velocities entered the CWs (e.g., the clay particles behaved as silt particles). Hence, clay particle settling velocity is not constant as assumed in many prediction models. The net result was increased retention.

  3. Smart Water: Energy-Water Optimization in Drinking Water Systems (United States)

    This project aims to develop and commercialize a Smart Water Platform – Sensor-based Data-driven Energy-Water Optimization technology in drinking water systems. The key technological advances rely on cross-platform data acquisition and management system, model-based real-time sys...

  4. Content of arsenic, selenium, mercury in the coal, food, clay and drinking water on the Zhaotong fluorosis area, eastern Yunnan Province

    Energy Technology Data Exchange (ETDEWEB)

    Luo Kun-li; Li Hui-jie; Chen Tong-bin (and others) [Chinese Academy of Sciences, Beijing (China). Institute of Geographic Sciences and Natural Resources Research


    About 160 samples of coal, corn, capsicum and drinking water were collected from the endemic fluorosis area of Zhenxiong and Weixin County, Zhaotong City of Yunnan Province, to determine the arsenic (As), selenium (Se) and mercury (Hg) content by AAF-800. The study found that the As content in the main coal seam from the Late Permian coal mines in Zhaotong City is 8.84 mg/kg and some civil coal can reach 89.09 mg/kg. The Se and Hg in the coal samples of Late Permian is lower, but Se and Hg are more concentrated in the pyritic coal balls and the pyritic gangue of the coal seam. The As content in corn and capsicum dried by coal-burning is more than 0.7 mg/kg, the natural standard amount of arsenic content permitted in food by China. The Se and Hg content in corn dried by coal-burning is lower than the natural standard of Se and Hg content in food in China but the Se and Hg content of capsicum dried by coal-burning exceeds the amount permitted by the natural standard for food in China. Clay, used as an additive for the coal-burning process and as a binder in making briquettes, contains a high content of As, generally more than 16 mg/kg. However, the Se and Hg content of clay itself are low. The As, Se and Hg content of drinking water are lower than the natural standard of As, Se and Hg content in the drinking water. So, there is high-As content coal and high-As content dried corn and capsicum in the endemic fluorosis area of Zhaotong City of Yunnan Province. The high As content of the dried corn and capsicum might have originated from the high arsenic content of burnt coal and clay. 30 refs., 4 tabs.

  5. Calcium-ammonium exchange experiments on clay minerals using a (45)Ca tracer technique in marine pore water. (United States)

    Ockert, Charlotte; Wehrmann, Laura M; Kaufhold, Stephan; Ferdelman, Tim G; Teichert, Barbara M A; Gussone, Nikolaus


    Understanding cation exchange processes is important for evaluating early diagenetic and synsedimentary processes taking place in marine sediments. To quantify calcium (Ca) exchange and Ca-ammonium exchange in a seawater environment, we performed experiments with a radioactive (45)Ca tracer on clay mineral standards (Fithian illite, montmorillonite and kaolinite) and marine sediments from the North Atlantic Integrated Ocean Drilling Program Site U1306A in artificial seawater (ASW). The results show that equilibrium during the initial attachment of Ca as well as the exchange of Ca by [Formula: see text] is attained in less than 2 min. On average 8-20% of the exchangeable sites of the clay minerals were occupied by Ca in a seawater medium. The conditional selectivity coefficient, describing the [Formula: see text] exchange in ASW is mineral specific and it was determined to be 0.07 for montmorillonite, 0.05 for a natural marine sediment and 0.013 for Fithian illite.

  6. Experimental study of Human Adenoviruses interactions with clays (United States)

    Bellou, Maria; Syngouna, Vasiliki; Paparrodopoulos, Spyros; Vantarakis, Apostolos; Chrysikopoulos, Constantinos


    Clays are used to establish low permeability liners in landfills, sewage lagoons, water retention ponds, golf course ponds, and hazardous waste sites. Human adenoviruses (HAdVs) are waterborne viruses which have been used as viral indicators of fecal pollution. The objective of this study was to investigate the survival of HAdV in static and dynamic clay systems. The clays used as a model were crystalline aluminosilicates: kaolinite and bentonite. The adsorption and survival of HAdVs onto these clays were characterized at two different controlled temperatures (4 and 25o C) under static and dynamic batch conditions. Control tubes, in the absence of clay, were used to monitor virus inactivation due to factors other than adsorption to clays (e.g. inactivation or sorption onto the tubes walls). For both static and dynamic batch experiments, samples were collected for a maximum period of seven days. This seven day time - period was determined to be sufficient for the virus-clay systems to reach equilibrium. To infer the presence of infectious HAdV particles, all samples were treated with Dnase and the extraction of viral nucleid acid was performed using a commercial viral RNA kit. All samples were analyzed by Real - Time PCR which was used to quantify viral particles in clays. Samples were also tested for virus infectivity by A549 cell cultures. Exposure time intervals in the range of seven days (0.50-144 hours) resulted in a load reduction of 0.74 to 2.96 logs for kaolinite and a reduction of 0.89 to 2.92 for bentonite. Furthermore, virus survival was higher onto bentonite than kaolinite (p

  7. General strategy, clay based disposal concepts and integration (GSI)

    Energy Technology Data Exchange (ETDEWEB)

    Keto, P.; Gunnarsson, G.; Johannesson, L.E.; Hansen, J.; Emmerich, K.; Kemper, G.; Nuesch, R.; Schuhmann, R.; Koniger, F.; Schlager, St.; Gruner, M.; Hofmann, M.; Nuesch, R.; Kobayashi, I.; Toida, M.; Sasakura, T.; Bernier, F.; Li, X.L.; Ileana Denisa, Nistor; Neculai, DoruMiron; Tudor, Sajin; Abdelkrim, Azzouz; Ilie, Siminiceanu; Viswanadham, B.V.S.; Rajesh, S.; Sengupta, S.S.; Panturu, E.; Radulescu, R.; Jinescu, C.; Panturu Razvann, Ioan; Autio, J.; Sanden, T.; Borgesson, L.; Svensson, D.; Eng, A.; Sellin, P.; Dixon, D.A.; Martino, J.B.; Vignal, B.; Fujita, T.; Wei-Hsing, Huang; Wen-Chuan, Chen; Shu-Rong, Yang; Dmitriev, S.; Prozorov, L.; Litinsky, Y.; Tkachenko, A.; Guskov, A.; Sanden, T.; Borgesson, L.; Camp, S.; Gourc, J.P.; Ple, O.; Kaelin, J.L.; Marchiol, A.; Round, C.; Johannesson, L.E.; Nilsson, U.; Adamcova, R.; Frankovska, J.; Durmekova, T.; Haasova, Z.; Gatabin, C.; Guyot, J.L.; Resnikow, S.; Karnland, O.; Nilsson, U.; Weber, H.; Wersin, P.; Gray, M.N.; Dixon, D.A.; Poulesquen, A.; Radwan, J.; Poinssot, C.; Ferry, C.; Weber, H.P.; Plotze, M


    This session gathers 20 articles (posters) dealing with: the assessment of backfill materials and methods for deposition tunnels; HTV-1: a semi technical scale testing of a multi-layer hydraulic shaft sealing system; the development of water content adjust method by mixing powdered-ice and chilled bentonite: application to the construction of bentonite engineered barriers by shot-clay method; repository design issues related to the thermal impact induced by heat emitting radioactive waste; pillared clays, using Romanian montmorillonite; the simulation of differential settlements of clay based engineered barrier systems in a geo-centrifuge; the critical issues regarding clay behaviour in the KBS-3H repository design; an alternative buffer material experiment; assessing the performance of a swelling clay tunnel seal and issues identified in the course of its operation; the activation of a Ca-bentonite as buffer material; a large diameter borehole type repository in the clays for radioactive waste long term storage; the erosion of backfill materials during the installation phase; the behaviour of the clay cover of a site for very low level nuclear waste: field flexion tests; the laboratory tests made on three different backfill candidates for the Swedish KBS- 3V concept; the engineering geological clay research for radioactive waste repository in Slovakia; the ESDRED project, module 1 - Design, fabrication, assembly, handling and packaging of buffer rings; the laboratory experiments on the sealing ability of bentonite pellets; the screening of bentonite resources for use as an engineered barrier component in deep geologic repositories; the assessment of the radionuclide release from the near-field environment of a spent nuclear fuel geological repository; and the emplacement tests with granular bentonite.




    Williams, Lynda B; Haydel, Shelley E; Giese, Rossman F; Eberl, Dennis D


    The worldwide emergence of infectious diseases, together with the increasing incidence of antibiotic-resistant bacteria, elevate the need to properly detect, prevent, and effectively treat these infections. The overuse and misuse of common antibiotics in recent decades stimulates the need to identify new inhibitory agents. Therefore, natural products like clays, that display antibacterial properties, are of particular interest.The absorptive properties of clay minerals are well documented for healing skin and gastrointestinal ailments. However, the antibacterial properties of clays have received less scientific attention. French green clays have recently been shown to heal Buruli ulcer, a necrotic or 'flesh-eating' infection caused by Mycobacterium ulcerans. Assessing the antibacterial properties of these clays could provide an inexpensive treatment for Buruli ulcer and other skin infections.Antimicrobial testing of the two clays on a broad-spectrum of bacterial pathogens showed that one clay promotes bacterial growth (possibly provoking a response from the natural immune system), while another kills bacteria or significantly inhibits bacterial growth. This paper compares the mineralogy and chemical composition of the two French green clays used in the treatment of Buruli ulcer.Mineralogically, the two clays are dominated by 1Md illite and Fe-smectite. Comparing the chemistry of the clay minerals and exchangeable ions, we conclude that the chemistry of the clay, and the surface properties that affect pH and oxidation state, control the chemistry of the water used to moisten the clay poultices and contribute the critical antibacterial agent(s) that ultimately debilitate the bacteria.

  10. Partitioning of Laponite Clay Platelets in Pickering Emulsion Polymerization. (United States)

    Brunier, Barthélémy; Sheibat-Othman, Nida; Chevalier, Yves; Bourgeat-Lami, Elodie


    Partitioning of laponite disklike clay platelets between polymer particles and bulk aqueous phase was investigated in Pickering surfactant-free emulsion polymerization of styrene. Adsorption of laponite clay platelets plays an important role in the stabilization of this system, influencing the particle size and the number of particles, and, hence, the reaction rate. Adsorption isotherms show that, while the laponite clay platelets are almost fully exfoliated in water, they form multilayers on the surface of the polymer particles by the end of polymerization, as confirmed by transmission electron microscopy (TEM). This observation is supported by quartz crystal microbalance, conductivity, and TEM measurements, which reveal interactions between the clay and polystyrene, as a function of the ionic strength. The strong adsorption of clay platelets leaves a low residual concentration in the aqueous phase that cannot cause further nucleation of polymer particles, as demonstrated during seeded emulsion polymerization experiments in the presence of a high excess of clay. A Brunauer-Emmett-Teller (BET)-type model for laponite adsorption on polystyrene particles matches the adsorption isotherms.

  11. CATSIUS CLAY PROJECT: Calculation and testing of behaviour of unsaturated clay as barrier in radioactive waste repositories: stage 3: validation exercises at a large in situ scale

    Energy Technology Data Exchange (ETDEWEB)

    Alonso, E. E.; Alcoverro, J.


    Stage 3 of CATSIUS CLAY Project: Validation Exercises at a Large in situ Scale includes two Benchmarks: Benchmark 3.1: In situ Hydration of Boom Clay Pellets (BACCHUS 2) and Benchmark 3.2: FEBEX Mock-up Test. The BACCHUS 2 in situ test was performed in the HADES underground laboratory (Mol, Belgium) to demonstrate and optimize an installation procedure for a clay based material and to study its hydration process. After drilling a vertical shaft (540 mm in diameter, 3.0 m in length) in the host Boom clay, a central filter (90 mm in diameter) was placed, the remaining space was filled with a mixture of clay pellets and clay powder and the assembly was sealed at the upper end by a resin plug (0.20 m in thickness) over which concrete was poured. The test was instrumented so that it could be used as a validation experiment. Total stress, pore water pressure and water content measurements were performed both in the backfill material and in the surrounding clay massif. Once the installation was complete, the natural hydration of the backfill material began (day 0). To accelerate the hydration process, on day 516 water was injected through the central filter. On day 624, after the saturation of the backfill was reached, the hydraulic circuit was closed and the undrained response of the system backfill-host clay was monitored until an overall steady state was reached. Partners were asked to provide predictions for the evolution of the pore water pressure and total pressure of various points where appropriate sensors are installed. This benchmark addresses the Hydro-Mechanical response of an unsaturated low density clay barrier under natural and artificial hydration. (Author)

  12. Thermostability of montmorillonitic clays

    Directory of Open Access Journals (Sweden)

    Petr Jelínek


    Full Text Available Bentonite is one of the most widespread used clays connected with various applications. In the case of foundry technology, bentonite is primarily used as a binder for mold manufacture. Thermal stability of bentonites is a natural property of clay minerals and it depends on the genesis, source and chemical composition of the clay. This property is also closely connected to bentonite structure. According to DTA analysis if only one peak of dehydroxylation is observed (about 600 ºC, the cis- isomerism of bentonite is expected, while two peaks of de-hydroxylation (about 550 and 850 ºC are expected in the trans- one. In this overview, the bentonite structure, the water – bentonite interaction and the swelling behavior of bentonite in connection with the general technological properties of bentonite molding mixture are summarized. Further, various types of methods for determination of bentonite thermostability are discussed, including instrumental analytical methods as well as methods that employ evaluation of various technological properties of bentonite binders and/or bentonite molding mixtures.

  13. Thermostability of montmorillonitic clays

    Institute of Scientific and Technical Information of China (English)

    Petr Jelnek; Stanisaw M.Dobosz; Jaroslav Beo; Katarzyna Major-Gabry


    Bentonite is one of the most widespread used clays connected with various applications. In the case of foundry technology, bentonite is primarily used as a binder for mold manufacture. Thermal stability of bentonites is a natural property of clay minerals and it depends on the genesis, source and chemical composition of the clay. This property is also closely connected to bentonite structure. According to DTA analysis if only one peak of dehydroxylation is observed (about 600 ºC), thecis- isomerism of bentonite is expected, while two peaks of de-hydroxylation (about 550 and 850 ºC) are expected in thetrans- one. In this overview, the bentonite structure, the water - bentonite interaction and the sweling behavior of bentonite in connection with the general technological properties of bentonite molding mixture are summarized. Further, various types of methods for determination of bentonite thermostability are discussed, including instrumental analytical methods as wel as methods that employ evaluation of various technological properties of bentonite binders and/or bentonite molding mixtures.

  14. Mars, clays and the origins of life (United States)

    Hartman, Hyman


    To detect life in the Martian soil, tests were designed to look for respiration and photosynthesis. Both tests (labeled release, LR, and pyrolytic release, PR) for life in the Martian soils were positive. However, when the measurement for organic molecules in the soil of Mars was made, none were found. The interpretation given is that the inorganic constituents of the soil of Mars were responsible for these observations. The inorganic analysis of the soil was best fitted by a mixture of minerals: 60 to 80 percent clay, iron oxide, quartz, and soluble salts such as halite (NaCl). The minerals most successful in simulating the PR and LR experiments are iron-rich clays. There is a theory that considers clays as the first organisms capable of replication, mutation, and catalysis, and hence of evolving. Clays are formed when liquid water causes the weathering of rocks. The distribution of ions such as aluminum, magnesium, and iron play the role of bases in the DNA. The information was stored in the distribution of ions in the octahedral and tetrahedral molecules, but that they could, like RNA and DNA, replicate. When the clays replicated, each sheet of clay would be a template for a new sheet. The ion substitutions in one clay sheet would give rise to a complementary or similar pattern on the clay synthesized on its surface. It was theorized that it was on the surface of replicating iron-rich clays that carbon dioxide would be fixed in the light into organic acids such as formic or oxalic acid. If Mars had liquid water during a warm period in its past, clay formation would have been abundant. These clays would have replicated and evolved until the liquid water was removed due to cooling of Mars. It is entirely possible that the Viking mission detected life on Mars, but it was clay life that awaits the return of water to continue its evolution into life based on organic molecules.

  15. Transport of inorganic compounds through compacted clay

    Energy Technology Data Exchange (ETDEWEB)

    Liao, W.P.


    Compacted clay liners are widely utilized as leachate barrier in landfills for waste. The main purpose of this research was to study the transport of inorganic compounds through compacted clay. The subjects of interest included the diffusional migration of chemicals at low flow rates, the effective porosity of fine-grained soils, the transport of solutes in unsaturated clays, and the effect of adsorption processes on the transport of reactive solutes. Two clay soils, kaolinite and Lufkin clay, were used in the laboratory column tests and subjected to constant hydraulic gradients of 1 to 50. Inorganic tracers (Cl{sup {minus}} Br{sup {minus}}, K{sup +}, and Zn{sup 2+}) were added to the permeating water as a step input. Conclusions are: (a) the experimental data from soil specimens subjected to various gradients showed that diffusional transport did affect the migration of the tracers in fine-grained media. At low gradients, hydrodynamic dispersion was almost solely related to molecular diffusion rather than mechanical mixing; (b) the breakthrough curves for kaolinite specimens showed that the ratios of effective porosity to total porosity were 0.25 to 1.0. The effect of low effective porosity on transport of the tracers was much greater than that of diffusion; (c) the soils that were not presoaked before tracers were introduced had lower effective porosity and greater dispersion of solutes that did the presoaked soils; (d) no evidence of the existence of a threshold gradient was observed; and (e) the retardation factors predicted from batch equilibrium tests matched the results from column tests poorly, probably due to hydrodynamic effects or geochemical differences between the two soil/solution systems.

  16. Structure, dynamics, and function of the hammerhead ribozyme in bulk water and at a clay mineral surface from replica exchange molecular dynamics. (United States)

    Swadling, Jacob B; Wright, David W; Suter, James L; Coveney, Peter V


    Compared with proteins, the relationship between structure, dynamics, and function of RNA enzymes (known as ribozymes) is far less well understood, despite the fact that ribozymes are found in many organisms and are often conceived as "molecular fossils" of the first self-replicating molecules to have arisen on Earth. To investigate how ribozymal function is governed by structure and dynamics, we study the full hammerhead ribozyme in bulk water and in an aqueous clay mineral environment by computer simulation using replica-exchange molecular dynamics. Through extensive sampling of the major conformational states of the hammerhead ribozyme, we are able to show that the hammerhead manifests a free-energy landscape reminiscent of that which is well known in proteins, exhibiting a "funnel" topology that guides the ribozyme into its globally most stable conformation. The active-site geometry is found to be closely correlated to the tertiary structure of the ribozyme, thereby reconciling conflicts between previously proposed mechanisms for the self-scission of the hammerhead. The conformational analysis also accounts for the differences reported experimentally in the catalytic activity of the hammerhead ribozyme, which is reduced when interacting with clay minerals as compared with bulk water.

  17. Soil-Water and Deformation Characteristics of Unsaturated Shanghai Soft Clays%非饱和上海软土的土-水和变形特性

    Institute of Scientific and Technical Information of China (English)

    陈振新; 孙德安


    使用压力板法和滤纸法测量非饱和上海软土的吸力,得到第②,③,④层上海原状土和第②,③层上海重塑土的土·水特征曲线,以及土体脱水干燥过程中吸力和孔隙比之间的关系.土-水特性试验结果表明:第②,③,④层上海原状土和第②,③层上海重塑土的进气值分别为150 ~180,220~250,650 ~ 800,260 ~310,550 ~ 600 kPa.干燥收缩试验结果表明:上海黏土的收缩过程可分为3个阶段,即弹性阶段、弹塑性阶段和缩限阶段.当基质吸力较小时,收缩变形较小,土体处于弹性阶段;当基质吸力增大到一定值时,收缩变形明显,土体处于弹塑性阶段;当土体变形基本不随基质吸力变化时,土体处于缩限阶段.%Using the methods of pressure plate and filter paper to measure soil suction, the soil-water characteristic curves and shrinkage deformation curves of undisturbed Shanghai soft clays (layers (2), (3) and (4)) and reconstituted Shanghai soft clays (layers (2) and (3)) are obtained from drying tests. It is found from the soil-water characteristic tests that the air-entering values of undisturbed Shanghai soft clays (layers (2),(3) and (4)) and reconstituted Shanghai soft clays (layers (2) and (3)) are 150-180, 220 ~ 250, 650 -800, 260 -310, and 550 -600 kPa, respectively. The process of soil shrinkage can be divided into three stages: elastic stage, elastoplastic stage and stage of shrinkage limit. When the imposed matric suction is small, the soil is at the elastic stage. When the large suction is applied, the shrinkage deformation becomes noticeable, and the soil is at the elastoplastic stage. At the stage of shrinkage limit, almost no deformation occurs during the increase of matric suction.

  18. Study on some rheological parameters of water and clay basis drilling fluids additivated with industrial sodium silicate; Estudo de alguns parametros reologicos de fluidos de perfuracao a base de agua e argila aditivados com silicato de sodio industrial

    Energy Technology Data Exchange (ETDEWEB)

    Amorim, Luciana Viana [Universidade Federal, Campina Grande, PB (Brazil). Engenharia de Processos]. E-mail:; Viana, Josiane Dantas; Farias, Kassie Vieira [Universidade Federal, Campina Grande, PB (Brazil). Dept. de Engenharia de Materiais]. E-mail:;; Franca, Kepler Borges; Lira, Helio de Lucena; Ferreira, Heber Carlos [Universidade Federal, Campina Grande, PB (Brazil). Dept. de Eng. Quimica]. E-mail:;;


    The aim of this work is to study some rheological parameters of water based oil well drilling fluids and bentonite clay from Boa Vista, PB, treated with industrial sodium silicate. It were selected there samples of natural polycationic bentonite clays and four industrial sodium bentonite clays. The natural clays were treated with concentrated Na{sub 2}CO{sub 3} solution. The drilling fluids were prepared with concentration of 4.86% w/w, according to PETROBRAS norms, and additivated with four different concentration of industrial sodium silicate. After 24 hours of cure, it were measured apparent viscosity (AV) and plastic viscosity (PV) by using a Fann 35A viscosimeter and water loss (WL) by using a Fann filter press. The results showed a change in the rheology of the drilling fluids. The drilling fluids prepared with industrialized clays showed a decrease in AV and an increase in WL. For the drilling fluids prepared with natural clays treated with Na{sub 2}CO{sub 3}, it was observed a decrease in AV and WL and an increase in PV. Also, it was observed a change in the drilling fluids state from flocculated-gel to a partially flocculated. (author)

  19. Planning of experimental removal of cadmium in finite bath system using the chocolate clay B as adsorbent; Caracterizacao de adsorvente (argila chocolate B) visando a remocao de cadmio

    Energy Technology Data Exchange (ETDEWEB)

    Mota, J.D.; Rodrigues, M.G.F.; Lima, W.S.; Souza, R.S., E-mail:, E-mail: [Universidade Federal de Campina Grande (LABNOV/UFCG), PB (Brazil). Unidade Academica de Engenharia Quimica. Lab. de Desenvolvimento de Novos Materiais


    The smectite clays are characterized by having a high cation exchange capacity and ability to remove metal ions. They have great industrial importance, for its abundance and low cost. The first part of this work was to characterize the clay called Chocolate B through the techniques of X-Ray Diffraction, X-Ray Spectroscopy and Energy Dispersive Physical Adsorption of Nitrogen. The second part of the work aims to evaluate the significance of the variables: pH and initial concentration on removal of cadmium in a batch system. In the experimental design used was a 2{sup 2} factorial analysis with the addition at the central point, and evaluated the percentage of removal (Rem%) and removal capacity (EQF). XRD results corroborating the chemical analysis (EDX), characterized as a B Chocolate smectite clays. Statistical analysis showed a strong influence of variable pH on the removal of cadmium. (author)

  20. Common clay and shale (United States)

    Virta, R.L.


    The article discusses the latest developments in the global common clay and shale industry, particularly in the U.S. It claims that common clay and shale is mainly used in the manufacture of heavy clay products like brick, flue tile and sewer pipe. The main producing states in the U.S. include North Carolina, New York and Oklahoma. Among the firms that manufacture clay and shale-based products are Mid America Brick & Structural Clay Products LLC and Boral USA.

  1. Mineral Acquisition from Clay by Budongo Forest Chimpanzees. (United States)

    Reynolds, Vernon; Lloyd, Andrew W; English, Christopher J; Lyons, Peter; Dodd, Howard; Hobaiter, Catherine; Newton-Fisher, Nicholas; Mullins, Caroline; Lamon, Noemie; Schel, Anne Marijke; Fallon, Brittany


    Chimpanzees of the Sonso community, Budongo Forest, Uganda were observed eating clay and drinking clay-water from waterholes. We show that clay, clay-rich water, and clay obtained with leaf sponges, provide a range of minerals in different concentrations. The presence of aluminium in the clay consumed indicates that it takes the form of kaolinite. We discuss the contribution of clay geophagy to the mineral intake of the Sonso chimpanzees and show that clay eaten using leaf sponges is particularly rich in minerals. We show that termite mound soil, also regularly consumed, is rich in minerals. We discuss the frequency of clay and termite soil geophagy in the context of the disappearance from Budongo Forest of a formerly rich source of minerals, the decaying pith of Raphia farinifera palms.

  2. Application of iron-rich natural clays in Camlica, Turkey for boron sorption from water and its determination by fluorimetric-azomethine-H method

    Energy Technology Data Exchange (ETDEWEB)

    Seyhan, Serap [Dokuz Eylul University, Faculty of Arts Sciences, Department of Chemistry, 35160 Buca, Izmir (Turkey); Seki, Yoldas [Dokuz Eylul University, Faculty of Arts Sciences, Department of Chemistry, 35160 Buca, Izmir (Turkey); Yurdakoc, Mueruevvet [Dokuz Eylul University, Faculty of Arts Sciences, Department of Chemistry, 35160 Buca, Izmir (Turkey)]. E-mail:; Merdivan, Melek [Dokuz Eylul University, Faculty of Arts Sciences, Department of Chemistry, 35160 Buca, Izmir (Turkey)


    In this study, iron-rich natural Camlica Bentonites, CB1 and CB2, were used for the sorption of boron in water samples. Boron was determined by newly progressed fluorimetric azomethine-H method. The optimum conditions found using factorial designs are pH 10, 45 deg. C, 0.250 g of clay and 20 mL of sample volume. It was found that 180 min is enough time for the equilibrium state to be reached in boron adsorption. At these conditions, boron sorption percentage was 80% for CB1 and 30% for CB2. The adsorption isotherms are well described by linear Freundlich model. Various geothermal waters in our country were also studied for boron sorption.

  3. Automated Water-Purification System (United States)

    Ahlstrom, Harlow G.; Hames, Peter S.; Menninger, Fredrick J.


    Reverse-osmosis system operates and maintains itself with minimal human attention, using programmable controller. In purifier, membranes surround hollow cores through which clean product water flows out of reverse-osmosis unit. No chemical reactions or phase changes involved. Reject water, in which dissolved solids concentrated, emerges from outer membrane material on same side water entered. Flow controls maintain ratio of 50 percent product water and 50 percent reject water. Membranes expected to last from 3 to 15 years.

  4. Systems Measures of Water Distribution System Resilience

    Energy Technology Data Exchange (ETDEWEB)

    Klise, Katherine A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Murray, Regan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Walker, La Tonya Nicole [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)


    Resilience is a concept that is being used increasingly to refer to the capacity of infrastructure systems to be prepared for and able to respond effectively and rapidly to hazardous events. In Section 2 of this report, drinking water hazards, resilience literature, and available resilience tools are presented. Broader definitions, attributes and methods for measuring resilience are presented in Section 3. In Section 4, quantitative systems performance measures for water distribution systems are presented. Finally, in Section 5, the performance measures and their relevance to measuring the resilience of water systems to hazards is discussed along with needed improvements to water distribution system modeling tools.

  5. Modified clay sorbents

    Energy Technology Data Exchange (ETDEWEB)

    Fogler, H.S.; Srinivasan, K.R.


    This patent describes a clay-based sorbent. It comprises a clay having an external surface and lamellar layers; and cationic surfactant ions having a hydrocarbon portion and a cationic head portion, the cationic surfactant ions being irreversibly bound to the external surface by the hydrocarbon portion. This patent also describes cetylpyridinium-aluminum hydroxy-montmorillonite; the clay-based sorbent wherein the clay is a non-expandable clay; and the clay-based sorbent wherein the cationic surfactant ions are selected from the group consisting of ionized cetylpyridinium chloride and cetylakonium chloride.

  6. Measurement and conceptual modelling of herbicide transport to field drains in a heavy clay soil with implications for catchment-scale water quality management. (United States)

    Tediosi, A; Whelan, M J; Rushton, K R; Thompson, T R E; Gandolfi, C; Pullan, S P


    Propyzamide and carbetamide are essential for blackgrass control in oilseed rape production. However, both of these compounds can contaminate surface waters and pose compliance problems for water utilities. The transport of propyzamide and carbetamide to an instrumented field drain in a small clay headwater tributary of the Upper Cherwell catchment was monitored over a winter season. Despite having very different sorption and dissipation properties, both herbicides were transported rapidly to the drain outlet in the first storm event after application, although carbetamide was leached more readily than propyzamide. A simple conceptual model was constructed to represent solute displacement from mobile pore water and preferential flow to drains. The model was able to reproduce the timing and magnitude of herbicide losses well, lending support to its conceptual basis. Measured losses in drainflow in the month following application were 1.1 and 8.1%, respectively, for propyzamide and carbetamide. Differences were due to a combination of differences in herbicide mobility and due to the fact that the monitoring period for carbetamide was hydrologically more active. For both compounds, losses were greater than those typically reported elsewhere for other herbicides. The data suggest that drainflow is the dominant pathway for the transfer of these herbicides to the catchment outlet, where water is abstracted for municipal supply. This imposes considerable constraints on the management options available to reduce surface water concentrations of herbicides in this catchment.

  7. Water quality management system; Suishitsu kanri system

    Energy Technology Data Exchange (ETDEWEB)

    Tsugura, H.; Hanawa, T.; Hatano, K.; Fujiu, M. [Meidensha Corp., Tokyo (Japan)


    Water quality management system designed in consideration of compliance with the environmental ISO is outlined. The water quality management system is positioned at the center, connected to water quality monitors that are deployed at various parts of the water supply facility, and performs the real-time display of information about water quality and the operating status of the water quality monitors for every one of the monitoring locations. The communication software run on this system supports 30 water quality monitors and performs uninterrupted surveillance using dedicated lines. It can also use public lines for periodic surveillance. Errors in communication if any are remedied automatically. A pipeline diagnosing/estimating function is provided, which utilizes water quality signals from received water quality monitors for estimating the degree of corrosion of pipelines in the pipeline network. Another function is provided of estimating water quality distribution throughout the pipeline network, which determines the residual chlorine concentration, conductivity, pH level, water temperature, etc., for every node in the pipeline network. A third function estimates water quality indexes, evaluating the trihalomethane forming power through measuring the amounts of low-concentration organic matters and utilizing signals from low-concentration UV meters in the water purification process. 3 refs., 7 figs.

  8. How mobile are sorbed cations in clays and clay rocks? (United States)

    Gimmi, T; Kosakowski, G


    Diffusion of cations and other contaminants through clays is of central interest, because clays and clay rocks are widely considered as barrier materials for waste disposal sites. An intriguing experimental observation has been made in this context: Often, the diffusive flux of cations at trace concentrations is much larger and the retardation smaller than expected based on their sorption coefficients. So-called surface diffusion of sorbed cations has been invoked to explain the observations but remains a controversial issue. Moreover, the corresponding surface diffusion coefficients are largely unknown. Here we show that, by an appropriate scaling, published diffusion data covering a broad range of cations, clays, and chemical conditions can all be modeled satisfactorily by a surface diffusion model. The average mobility of sorbed cations seems to be primarily an intrinsic property of each cation that follows inversely its sorption affinity. With these surface mobilities, cation diffusion coefficients can now be estimated from those of water tracers. In pure clays at low salinities, surface diffusion can reduce the cation retardation by a factor of more than 1000.

  9. Water Hydraulic Systems

    DEFF Research Database (Denmark)

    Conrad, Finn


    -going research projects on fluid power and mechatronics based on tap water hydraulic servovalves and linear servo actuators and rotary vane actuators for motion control and power transmission. Development and design a novel water hydraulic rotary vane actuator for robot manipulators. Proposed mathematical...... modelling, control and simulation of a water hydraulic rotary vane actuator applied to power and control a two-links manipulator and evaluate performance. The results include engineering design and test of the proposed simulation models compared with IHA Tampere University’s presentation of research...

  10. Study of smectite clays of the city Pedra Lavrada - PB for use in water-based drilling fluids; Estudo das argilas esmectiticas do municipio de Pedra Lavrada-PB para uso em fluidos de perfuracao base agua

    Energy Technology Data Exchange (ETDEWEB)

    Silva, I.A. da; Costa, J.M.R.; Cardoso, M.A.F.; Neves, G.A.; Ferreira, H.C., E-mail: [Universidade Federal de Campina Grande (UAEMa/CCT/UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais; Ferreira, H.S. [Universidade Federal da Paraiba (DEMAT/CT/UFPB), Joao Pessoa, PB (Brazil)


    Paraiba has large reserves of bentonite clays, with the largest deposits in Boa Vista, PB. Recently new deposits were discovered in the cities of Cubati and Pedra Lavrada-PB, creating great expectations for further expansion of reserves for industrial production. The aim of this work is the study of smectite clays from the city of Pedra Lavrada, PB for use in drilling fluids water based. The characterization was made by the diffraction of laser (AG), thermogravimetric and differential thermal analysis (TGA and DTA), chemical composition by X-ray fluorescence (EDX), X-ray diffraction (XRD), exchange capacity of cations (ECC) and surface area (SA). The results obtained so far showed that the samples presented at its mineral composition smectite, kaolinite and quartz. In relation to rheological properties showed that the bentonite clay sample Dark presents promising features for use in water based drilling fluids. (author)

  11. Water Treatment Technology - Distribution Systems. (United States)

    Ross-Harrington, Melinda; Kincaid, G. David

    One of twelve water treatment technology units, this student manual on distribution systems provides instructional materials for six competencies. (The twelve units are designed for a continuing education training course for public water supply operators.) The competencies focus on the following areas: types of pipe for distribution systems, types…

  12. Lake responses following lanthanum-modified bentonite clay (Phoslock®) application: an analysis of water column lanthanum data from 16 case study lakes. (United States)

    Spears, Bryan M; Lürling, Miquel; Yasseri, Said; Castro-Castellon, Ana T; Gibbs, Max; Meis, Sebastian; McDonald, Claire; McIntosh, John; Sleep, Darren; Van Oosterhout, Frank


    Phoslock(®) is a lanthanum (La) modified bentonite clay that is being increasingly used as a geo-engineering tool for the control of legacy phosphorus (P) release from lake bed sediments to overlying waters. This study investigates the potential for negative ecological impacts from elevated La concentrations associated with the use of Phoslock(®) across 16 case study lakes. Impact-recovery trajectories associated with total lanthanum (TLa) and filterable La (FLa) concentrations in surface and bottom waters were quantified over a period of up to 60 months following Phoslock(®) application. Both surface and bottom water TLa and FLa concentrations were waters between 0.026 mg L(-1)-2.30 mg L(-1) and 0.002 mg L(-1) to 0.14 mg L(-1), respectively. Results of generalised additive modelling indicated that recovery trajectories for TLa and FLa in surface and bottom waters in lakes were represented by 2nd order decay relationships, with time, and that recovery reached an end-point between 3 and 12 months post-application. Recovery in bottom water was slower (11-12 months) than surface waters (3-8 months), most probably as a result of variation in physicochemical conditions of the receiving waters and associated effects on product settling rates and processes relating to the disturbance of bed sediments. CHEAQS PRO modelling was also undertaken on 11 of the treated lakes in order to predict concentrations of La(3+) ions and the potential for negative ecological impacts. This modelling indicated that the concentrations of La(3+) ions will be very low (0.8 mEq L(-1)), but higher (up to 0.12 mg L(-1)) in lakes characterised by very low alkalinity. The effects of elevated La(3+) concentrations following Phoslock(®) applications in lakes of very low alkalinity requires further evaluation. The implications for the use of Phoslock(®) in eutrophication management are discussed.

  13. Electrolyte low concentrations effects on the the rheology of water and bentonitic clays basis drilling fluids; Efeito de baixas concentracoes de eletrolitos na reologia de fluidos de perfuracao a base de agua e argilas bentoniticas

    Energy Technology Data Exchange (ETDEWEB)

    Amorim, Luciana Viana [Universidade Federal, Campina Grande, PB (Brazil). Engenharia de Processos]. E-mail:; Viana, Josiane Dantas; Farias, Kassie Vieira; Lira, Helio de Lucena; Ferreira, Heber Carlos [Universidade Federal, Campina Grande, PB (Brazil). Dept. de Engenharia de Materiais]. E-mail:;;;; Franca, Kepler Borges [Universidade Federal, Campina Grande, PB (Brazil). Dept. de Engenharia Quimica]. E-mail:


    The aim of this work is to study the effect of low electrolytes concentration on the rheology of the water based oil well drilling fluids and bentonite clays from Boa Vista, PB. It were selected seven samples of bentonite clays (four from industry and three from natural polycationic clay treated with concentrated Na{sub 2}CO{sub 3} solution). The drilling fluids were prepared with a concentration of 4.86 % w/w, according to PETROBRAS norms and treated with different CaCl{sub 2} + MgCl{sub 2} concentration. After, the drilling fluids were submitted to a cure for 24 hours and measured apparent viscosity (AV), plastic viscosity (PV) and water loss (WL). To study the effect of the electrolyte on the rheology of the dispersions it was developed a factorial design 2{sup 2} + 3 test in the central point. The results showed that the addition of CaCl{sub 2} + MgCl{sub 2} caused a degradation of the drilling fluids prepared with industrialized clays, as showed by the decrease in AV and PV and great increase in WL. Also, it was observed an increase in AV and a decrease in PV in the drilling fluids prepared with natural clays treated with Na{sub 2}CO{sub 3}, conducting a flocculated-gel state. (author)

  14. The influence of natural organic matter on the speciation and solubility of Eu in Boom Clay pore water

    Energy Technology Data Exchange (ETDEWEB)

    Liu, D.J. [Belgian Nuclear Research Centre, SCK-CEN, Mol (Belgium); China Inst. of Atomic Energy, BJ (China); Bruggeman, C.; Maes, N. [Belgian Nuclear Research Centre, SCK-CEN, Mol (Belgium)


    The influence of natural organic matter (NOM) on the speciation and solubility of europium (Eu) was studied under geochemical conditions representative for the Boom Clay. Different organic matter types were used, and analysis was performed both after 0.45 {mu}m microfiltration and after 30 000 MWCO ultrafiltration to distinguish between larger colloids (assumed to be immobile under in situ conditions) and small dissolved species. Equilibrium was approached from undersaturation starting from synthesised Eu(OH){sub 3}(s), which, during the experiment, transformed into EuOHCO{sub 3}(s), in agreement with thermodynamic considerations. In the absence of NOM, the Eu solution concentrations after 0.45 {mu}m filtration exceeded the thermodynamic solubility of EuOHCO{sub 3}(s) by several orders of magnitude, indicating the presence of inorganic Eu colloids. In the presence of NOM, the Eu solubility increased with increasing NOM concentration as was expected, but, surprisingly, was dependent on the operational size cut-off: at an identical NOM concentration in the filtrate, the Eu solution concentration after 0.45 {mu}m filtration was consistently higher compared to the Eu concentration after 30 000 MWCO filtration. This latter observation necessitates detailed knowledge concerning the pore size cut-off of Boom Clay under in situ conditions in order to use the correct Eu-NOM complexation constant and/or maximum solubility in transport calculations. At higher NOM concentrations (TOC > 30 mg/L) the Eu solubility after 0.45 {mu}m filtration was seemingly independent of the NOM concentration. In contrast, after 30 000 MWCO ultrafiltration, the Eu solution increased linearly with increasing DOC, from the expected thermodynamic solubility ({proportional_to} 5 x 10{sup -7} mol L{sup -1}) at 0 mg L{sup -1} DOC to {proportional_to} 3 x 10{sup -5} mol L{sup -1} at 80 mg L{sup -1} DOC. All of the data sets were modelled using the Nagra/PSI database [1] for solubility, hydrolysis and

  15. Magnetic resonance imaging of clays: swelling, sedimentation, dissolution (United States)

    Dvinskikh, Sergey; Furo, Istvan


    While most magnetic resonance imaging (MRI) applications concern medical research, there is a rapidly increasing number of MRI studies in the field of environmental science and technology. In this presentation, MRI will be introduced from the latter perspective. While many processes in these areas are similar to those addressed in medical applications of MRI, parameters and experimental implementations are often quite different and, in many respects, far more demanding. This hinders direct transfer of existing methods developed for biomedical research, especially when facing the challenging task of obtaining spatially resolved quantitative information. In MRI investigation of soils, clays, and rocks, mainly water signal is detected, similarly to MRI of biological and medical samples. However, a strong variation of water mobility and a wide spread of water spin relaxation properties in these materials make it difficult to use standard MRI approaches. Other significant limitations can be identified as following: T2 relaxation and probe dead time effects; molecular diffusion artifacts; varying dielectric losses and induced currents in conductive samples; limited dynamic range; blurring artifacts accompanying drive for increasing sensitivity and/or imaging speed. Despite these limitations, by combining MRI techniques developed for solid and liquid states and using independent information on relaxation properties of water, interacting with the material of interest, true images of distributions of both water, material and molecular properties in a wide range of concentrations can be obtained. Examples of MRI application will be given in the areas of soil and mineral research where understanding water transport and erosion processes is one of the key challenges. Efforts in developing and adapting MRI approaches to study these kinds of systems will be outlined as well. Extensive studies of clay/water interaction have been carried out in order to provide a quantitative

  16. Operational Management System for Regulated Water Systems (United States)

    van Loenen, A.; van Dijk, M.; van Verseveld, W.; Berger, H.


    Most of the Dutch large rivers, canals and lakes are controlled by the Dutch water authorities. The main reasons concern safety, navigation and fresh water supply. Historically the separate water bodies have been controlled locally. For optimizating management of these water systems an integrated approach was required. Presented is a platform which integrates data from all control objects for monitoring and control purposes. The Operational Management System for Regulated Water Systems (IWP) is an implementation of Delft-FEWS which supports operational control of water systems and actively gives advice. One of the main characteristics of IWP is that is real-time collects, transforms and presents different types of data, which all add to the operational water management. Next to that, hydrodynamic models and intelligent decision support tools are added to support the water managers during their daily control activities. An important advantage of IWP is that it uses the Delft-FEWS framework, therefore processes like central data collection, transformations, data processing and presentation are simply configured. At all control locations the same information is readily available. The operational water management itself gains from this information, but it can also contribute to cost efficiency (no unnecessary pumping), better use of available storage and advise during (water polution) calamities.

  17. Water Supply Infrastructure System Surety

    Energy Technology Data Exchange (ETDEWEB)



    The executive branch of the United States government has acknowledged and identified threats to the water supply infrastructure of the United States. These threats include contamination of the water supply, aging infrastructure components, and malicious attack. Government recognition of the importance of providing safe, secure, and reliable water supplies has a historical precedence in the water works of the ancient Romans, who recognized the same basic threats to their water supply infrastructure the United States acknowledges today. System surety is the philosophy of ''designing for threats, planning for failure, and managing for success'' in system design and implementation. System surety is an alternative to traditional compliance-based approaches to safety, security, and reliability. Four types of surety are recognized: reactive surety; proactive surety, preventative surety; and fundamental, inherent surety. The five steps of the system surety approach can be used to establish the type of surety needed for the water infrastructure and the methods used to realize a sure water infrastructure. The benefit to the water industry of using the system surety approach to infrastructure design and assessment is a proactive approach to safety, security, and reliability for water transmission, treatment, distribution, and wastewater collection and treatment.

  18. Biodegradation behaviors and water adsorption of poly(vinyl alcohol)/starch/carboxymethyl cellulose/clay nanocomposites (United States)

    Taghizadeh, Mohammad Taghi; Sabouri, Narges


    The focus of this work is to study the effect of sodium montmorillonite (MMT-Na) clay content on the rate and extent of enzymatic hydrolysis polyvinyl alcohol (PVA)/starch (S)/carboxymethyl cellulose (CMC) blends using enzyme cellulase. The rate of glucose production from each nanocomposite substrates was most rapid for the substrate without MMT-Na and decreased with the addition of MMT-Na for PVA/S/CMC blend (51.5 μg/ml h), PVA/S/CMC/1% MMT (45.4 μg/ml h), PVA/S/CMC/3% MMT (42.8 μg/ml h), and PVA/S/CMC/5% MMT (39.2 μg/ml h). The results of this study have revealed that films with MMT-Na content at 5 wt.% exhibited a significantly reduced rate and extent of hydrolysis. Enzymatic degradation behavior of MMT-Na containing nanocomposites of PVA/S/CMC was based on the determinations of weight loss and the reducing sugars. The degraded residues have been characterized by various analytical techniques, such as Fourier transform infrared spectroscopy, scanning electronic microscopy, and UV-vis spectroscopy.

  19. Production Management Systems, Bricks or clay in the Hand of Social Actors?

    DEFF Research Database (Denmark)

    Koch, Christian


    Production Management Systems (PMS)is a technology developing in Denmark And Internationally. The chapter argues that technological development should be interpreted as a incremental process.It Discusses two danish cases and used the concept of the company specific social constitution to explain...


    Energy Technology Data Exchange (ETDEWEB)

    N.J. Hayden; P. Padgett; C. Farrell; J. Diebold; X. Zhou; M. Hood


    Alcohol flushing, also called cosolvent flushing, is a relatively new in-situ remediation technology that shows promise for removing organic solvents from the soil and groundwater. Soil and groundwater contamination from organic solvents and petroleum products is one of the most serious and widespread environmental problems of our time. Most of the DOE facilities and inactive sites are experiencing soil and groundwater contamination from organic solvents. These water immiscible solvents have entered the subsurface from leaking underground storage tanks and piping, and from past waste handling and disposal practices such as leaking lagoons, holding ponds and landfills. In many cases, they have traveled hundreds of feet down into the saturated zone. If left in the soil, these chemicals may pose a significant environmental and human health risk. Alcohol flushing has potential for application to spilled solvents located deep within the saturated zone which are difficult if not impossible to remove by current remediation strategies, thus, greatly expediting restoration time, reducing total remediation cost and reducing risk.

  1. Water in the Solar System (United States)

    Encrenaz, Thérèse


    Water is ubiquitous in the Universe, and also in the Solar System. By setting the snow line at its condensation level in the protosolar disk, water was responsible for separating the planets into the terrestrial and the giant ones. Water ice is a major constituent of the comets and the small bodies of the outer Solar System, and water vapor is found in the giant planets, both in their interiors and in the stratospheres. Water is a trace element in the atmospheres of Venus and Mars today. It is very abundant on Earth, mostly in liquid form, but it was probably also abundant in the primitive atmospheres of Venus and Mars. Water is found in different states on the three planets, as vapor on Venus and ice (or permafrost) on Mars. Most likely, this difference has played a major role in the diverging destinies of the three planets.

  2. Disturbance of water-extractable phosphorus determination by colloidal particles in a heavy clay soil from the Netherlands

    NARCIS (Netherlands)

    Koopmans, G.F.; Chardon, W.J.; Salm, van der C.


    Received for publication January 25, 2005. Water extraction methods are widely used to extract phosphorus (P) from soils for both agronomic and environmental purposes. Both the presence of soil colloids in soil water filtrates, and the contribution of colloidal P to the molybdate-reactive phosphorus

  3. Quantitative approach on SEM images of microstructure of clay soils

    Institute of Scientific and Technical Information of China (English)

    施斌; 李生林; M.Tolkachev


    The working principles of Videolab Image Processing System (VIPS), the examining methods of orientation of microstructural units of clay soils and analysing results on SEM images of some typical microstructures of clay soils using the VIPS are introduced.

  4. Reverse osmosis water purification system (United States)

    Ahlstrom, H. G.; Hames, P. S.; Menninger, F. J.


    A reverse osmosis water purification system, which uses a programmable controller (PC) as the control system, was designed and built to maintain the cleanliness and level of water for various systems of a 64-m antenna. The installation operates with other equipment of the antenna at the Goldstone Deep Space Communication Complex. The reverse osmosis system was designed to be fully automatic; with the PC, many complex sequential and timed logic networks were easily implemented and are modified. The PC monitors water levels, pressures, flows, control panel requests, and set points on analog meters; with this information various processes are initiated, monitored, modified, halted, or eliminated as required by the equipment being supplied pure water.

  5. Multi-scale modeling of the behaviour of water and ions clays; Modelisation multi-echelles du comportement de l'eau et des ions dans les argiles

    Energy Technology Data Exchange (ETDEWEB)

    Rotenberg, B


    Predicting the fate of radioactive waste stored in a clay formation requires a good understanding of the transport properties of water and ions in clays. Their diffusion in this charged porous medium is described by empirical parameters such as their partitioning coefficient Kd which accounts for the interactions with the mineral surfaces. The present work deals with the relevance of this concept and its definition based on microscopic grounds. We have first modeled the ionic contribution to the dielectric properties of clays and suggested an experimental determination of Kd from dielectric spectroscopy measurements. Using microscopic simulations (Monte-Carlo and Molecular Dynamics), we then have computed the Gibbs free energy and enthalpy for ionic exchange in the case of alkaline cations. They control the value of Kd and its evolution with the temperature. The results for cesium are in good agreement with both microcalorimetric measurements and the determination of Kd at different temperatures. We have participated in the development of a new lattice simulation method (Lattice Fokker-Planck), which we have then used to link explicitly the microscopic dynamics of ions to the diffusion-reaction model underlying the definition of Kd. Finally, we have used Molecular Dynamics to investigate the kinetics of exchange of water and ions between clay particles (interlayer) and the extra-particle porosity. The results confirm the generally admitted idea that water and ions can explore the whole porosity, whereas anions are excluded from the interlayers. (author)

  6. Clay membrane made of natural high plasticity clay

    DEFF Research Database (Denmark)

    Foged, Niels; Baumann, Jens


    Leachate containment in Denmark has through years been regulated by the DIF Recommendation for Sanitary Landfill Liners (DS/R 466). It states natural clay deposits may be used for membrane material provided the membrane and drainage system may contain at least 95% of all leachate created throughout...

  7. Water drilling fluids: evaluation of lubricity and clay swelling control; Fluidos de perfuracao a base de agua: avaliacao de lubricidade e controle de inchamento de argilas

    Energy Technology Data Exchange (ETDEWEB)

    Felix, Thiago de Freitas; Arruda, Jefferson Teixeira; Medeiros, Ana Catarina; Garcia, Rosangela Balaban [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)


    During the oil well drilling, drilling fluids are used in order to transport the cuttings until the surface. This fluid is also responsible for the mechanical sustentation of the well walls, the control of undesirable production of fluids in the formation, the lubricity and the cooling of the bit. The drilling fluids based on water are extensively applied due to their lower cost, thermal stability, biodegradability, easiness of pumping and treatment, resulting in smaller environmental impacts. However, some situations, such as hydrophilic shale drilling, request the use of additives to avoid the hydration of them and, consequently, the tool imprisonment or migration (filtration) of the drilling fluids into the rock. The goal of this work was to develop and test formulations of water-base drilling fluids with high capacity of inhibition of clay swelling and lubricity, obtaining drillings with larger penetration rate and calipers without enlargements. The results showed that the appropriate combination of commonly used commercial products can promote the obtaining of fluids with equal or better performance than those used by world companies. (author)

  8. Immobilization of fungal laccase onto a nonionic surfactant-modified clay material: application to PAH degradation. (United States)

    Chang, Yi-Tang; Lee, Jiunn-Fwu; Liu, Keng-Hua; Liao, Yi-Fen; Yang, Vivian


    Nonionic surfactant-modified clay is a useful absorbent material that effectively removes hydrophobic organic compounds from soil/groundwater. We developed a novel material by applying an immobilized fungal laccase onto nonionic surfactant-modified clay. Low-water-solubility polycyclic aromatic hydrocarbons (PAHs) (naphthalene/phenanthrene) were degraded in the presence of this bioactive material. PAH degradation by free laccase was higher than degradation by immobilized laccase when the surfactant concentration was allowed to form micelles. PAH degradation by immobilized laccase on TX-100-modified clay was higher than on Brij35-modified clay. Strong laccase degradation of PAH can be maintained by adding surfactant monomers or micelles. The physical adsorption of nonionic surfactants onto clay plays an important role in PAH degradation by laccase, which can be explained by the structure and molecular interactions of the surfactant with the clay and enzyme. A system where laccase is immobilized onto TX-100-monomer-modified clay is a good candidate bioactive material for in situ PAHs bioremediation.

  9. Brazilian clay organophilization aiming its use in oil / water removal; Organofilizacao de argila brasileira visando seu uso na remocao oleo/agua

    Energy Technology Data Exchange (ETDEWEB)

    Mota, M.F.; Lima, W.S.; Oliveira, G.C.; Silva, M.M.; Rodrigues, M.G.F., E-mail:, E-mail: [Universidade Federal de Campina Grande (LABNOV/UFCG), PB (Brazil). Unidade Academica de Engenharia Quimica. Lab. de Desenvolvimento de Novos Materiais


    Clays when subjected to modification with the addition of organic surfactant are called organoclays acquire hydrophobic character, they have an affinity for organic compounds. The organoclays can be used as adsorbents are considered promising agents in environmental control. The objective is to prepare organoclays clays from commercial use in order to remove organic contaminants. The clay used was gray, as polycationic, supplied by Süd-Chemie company and the quaternary ammonium salt was cetyltrimethylammonium bromide (Cetremide). The fresh samples and organoclay were characterized by the technique of X-ray diffraction (XRD), Cation Exchange Capacity, testing expansion and affinity with organic compounds: Swelling of Foster and adsorption capacity. The results showed appropriate conditions organophilic process. Through XRD confirmed the increase in basal spacing for the modified clay in relation to the clay in nature. (author)

  10. Modeling sorption and diffusion of organic sorbate in hexadecyltrimethylammonium-modified clay nanopores - a molecular dynamics simulation study. (United States)

    Zhao, Qian; Burns, Susan E


    Organoclays are highly sorptive engineered materials that can be used as amendments in barrier systems or geosynthetic liners. The performance of confining and isolating the nonpolar organic contaminants by those barrier/lining systems is essentially controlled by the process of organic contaminant mass transport in nanopores of organoclays. In this article, we use molecular dynamics (MD) simulations to study the sorption and diffusion of organic sorbates in interlayers of sodium montmorillonite and hexadecyltrimethylammonium (HDTMA(+))-modified montmorillonite clays. Simulated system consisted of the clay framework, interlayer organic cation, water, and organic sorbate. Their interactions were addressed by the combined force field of ClayFF, constant-valence force field, and SPC water model. Simulation results indicated that in HDTMA coated clay nanopores, diffusion of nonpolar species benzene was slowed because they were subjected to influence of both the pore wall and the HDTMA surfactant. This suggested the nonpolar organic compound diffusion in organophilic clays can be affected by molecular size of diffusive species, clay pore size, and organic surfactant loading. Additionally, a model that connected the diffusion rate of organic compounds in the bulk organoclay matrix with macropores and nanopores was established. The impact of intercalated organic cations on the diffusion dominated mass transport of organic compounds yielded insight into the prediction of the apparent diffusion behavior of organic compounds in organic-modified clays.

  11. Ultrapure Water System for Hemodialysis Therapy (United States)


    The Change of Biomarkers CRP, CBC With the Use of Ultra Pure Water System for; Hemodialysis.; The Rate of Adverse Events Such as Hypotension During Hemodialysis Therapy With Ultra Pure Water; System as Compared to Conventional Water System.

  12. Assessment on reliability of water quality in water distribution systems

    Institute of Scientific and Technical Information of China (English)

    伍悦滨; 田海; 王龙岩


    Water leaving the treatment works is usually of a high quality but its properties change during the transportation stage. Increasing awareness of the quality of the service provided within the water industry today and assessing the reliability of the water quality in a distribution system has become a major significance for decision on system operation based on water quality in distribution networks. Using together a water age model, a chlorine decay model and a model of acceptable maximum water age can assess the reliability of the water quality in a distribution system. First, the nodal water age values in a certain complex distribution system can be calculated by the water age model. Then, the acceptable maximum water age value in the distribution system is obtained based on the chlorine decay model. The nodes at which the water age values are below the maximum value are regarded as reliable nodes. Finally, the reliability index on the percentile weighted by the nodal demands reflects the reliability of the water quality in the distribution system. The approach has been applied in a real water distribution network. The contour plot based on the water age values determines a surface of the reliability of the water quality. At any time, this surface is used to locate high water age but poor reliability areas, which identify parts of the network that may be of poor water quality. As a result, the contour water age provides a valuable aid for a straight insight into the water quality in the distribution system.

  13. Changes in grain-size and sedimentation rate of the Neogene Red Clay deposits along the Chinese Loess Plateau and implications for the palaeowind system

    Institute of Scientific and Technical Information of China (English)

    WEN Lingjuan; LU Huayu; QIANG Xiaoke


    The wind system responsible for transporting dust onto the Chinese Loess Plateau during the late Miocene and Pliocene is still unknown and recent investigations highlight many controversies. This report aims to investigate spatiotemporal changes in grain-size and sedimentation rate of the Neogene Red Clay deposits in north China and to explore palaeoclimatic changes during the late Miocene and Pliocene, in particular the palaeowind system that transported dust. Samples were collected from eight Red Clay sections on the Loess Plateau. Measurement and analysis show that there is a clear southward decrease in the mean grain-size index and in the coarse particle fraction (>20 μm). At Jiaxian site on the northern Loess Plateau, the average mean grain-size is around 20 μm, while at Lantian site in the south, the mean is around 9 μm. The coarse particle fraction >20 μm makes up 24.4% and 5.6%, at the two sites respectively. This distinct diversity of grain-size in the aeolian Red Clay deposit between the north and south indicate that the palaeodust was transported mainly by northerly low-level winds. The grain-size variations in the Red Clay deposits can also be divided into three stages (the lower, the middle and the upper interval): grain-size of the lower stage is significantly coarser than that of the middle stage, but finer than that of the upper stage. As a consequence, the intensity of palaeowind and desiccation of the dust source region during the late Miocene and Pliocene can be divided into three stages: 6.2-5.4 Ma, 5.4-3.5 Ma and 3.5-2.6 Ma. Strength of the palaeowind during the middle stage (5.4-3.5 Ma) is weaker than that of the previous and subsequent stages and the intensity of palaeowind during the latest stage (3.5-2.6 Ma) is stronger than that of the early time (6.2-5.4 Ma). Variations in the sedimentation rate of the Red Clay deposit can also be divided into three stages: the earlier, the middle and the later interval. The sedimentation rate of the

  14. Automatic Water Sensor Window Opening System

    KAUST Repository

    Percher, Michael


    A system can automatically open at least one window of a vehicle when the vehicle is being submerged in water. The system can include a water collector and a water sensor, and when the water sensor detects water in the water collector, at least one window of the vehicle opens.

  15. Evaluation by design of experiments of active clay specimens behavior in the presence of distilled water, saline solutions and cationic inhibitors; Avaliacao por analise estatistica experimental do comportamento de corpos de prova de argila aditivada na presenca de agua destilada, solucoes salinas e inibidores cationicos

    Energy Technology Data Exchange (ETDEWEB)

    Vidal, Emanuella Layne Ferreira; Araujo, Bruno Alysson Barbosa Duarte; Borges, Mauricio Rodrigues; Garcia, Rosangela Balaban [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)


    During the drilling, in general, there are layers of clays which water absorption easily as smectites. In drilling with clays swelling when is applied water-base fluid there is necessary the use of the clay inhibitors to avoid the incorporation of the cutting to the drilling fluid. The most used chemical inhibitors in drilling fluids are sodium and potassium chlorides. However, the cationic inhibitors have been used as alternative form to increase the inhibition power of the drilling fluids. In this work was evaluated the behaviour of the activated clay test bodies in the presence of distilled water, aqueous solution potassium chlorides, and cationic inhibitors. The solutions were submitted at Capillary Suction Timer tests to evaluation the capacity of the water retention in activated clay samples. At the interpretation of the results was used Design of Experiments (DOE) by Response Surface Methodology (RSM), using Umetrics MODDE 7.0{sup TM} programme. It was observed that the clay samples when in contact with the solutions presented lower water retention than in the presence of distilled water only. This result indicates that the clay was inhibited. (author)

  16. Clay Mineral: Radiological Characterization (United States)

    Cotomácio, J. G.; Silva, P. S. C.; Mazzilli, B. P.


    Since the early days, clays have been used for therapeutic purposes. Nowadays, most minerals applied as anti-inflammatory, pharmaceutics and cosmetic are the clay minerals that are used as the active ingredient or, as the excipient, in formulations. Although their large use, few information is available in literature on the content of the radionuclide concentrations of uranium and thorium natural series and 40K in these clay minerals. The objective of this work is to determine the concentrations of 238U, 232Th, 226Ra, 228Ra, 210Pb and 40K in commercial samples of clay minerals used for pharmaceutical or cosmetic purposes. Two kinds of clays samples were obtained in pharmacies, named green clay and white clay. Measurement for the determination of 238U and 232Th activity concentration was made by alpha spectrometry and gamma spectrometry was used for 226Ra, 228Ra, 210Pb and 40K determination. Some physical-chemical parameters were also determined as organic carbon and pH. The average activity concentration obtained was 906±340 Bq kg-1 for 40K, 40±9 Bq kg-1 for 226Ra, 75±9 Bq kg-1 for 228Ra, 197±38 Bq kg-1 for 210Pb, 51±26 Bq kg-1 for 238U and 55±24 Bq kg-1 for 232Th, considering both kinds of clay.

  17. Clay Portrait Boxes (United States)

    Wilbert, Nancy Corrigan


    In an attempt to incorporate sculptural elements into her ceramics program, the author decided to try direct plaster casting of the face to make a plaster mold for clay. In this article, the author shares an innovative ceramics lesson that teaches students in making plaster casts and casting the face in clay. This project gives students the…

  18. Columns in Clay (United States)

    Leenhouts, Robin


    This article describes a clay project for students studying Greece and Rome. It provides a wonderful way to learn slab construction techniques by making small clay column capitols. With this lesson, students learn architectural vocabulary and history, understand the importance of classical architectural forms and their influence on today's…

  19. Siderophore sorption to clays. (United States)

    Maurice, Patricia A; Haack, Elizabeth A; Mishra, Bhoopesh


    Siderophores are low molecular weight organic ligands exuded by some aerobic organisms and plants to acquire Fe under Fe-limited conditions. The hydroxamate siderophores may sorb to aluminosilicate clays through a variety of mechanisms depending upon the nature of the clay and of the siderophore along with solution conditions such as pH, ionic strength, and presence of metal cations. They may also affect metal binding to clays. Here, we review previous studies of siderophore sorption to aluminosilicate clays; briefly discuss how the techniques of X-ray diffractometry, Fourier-transform infrared spectroscopy, and X-ray absorption spectroscopy may be applied to such studies; review effects of siderophores on metal sorption to clays; and highlight some areas for future research.

  20. Movimiento del agua en Argiudoles de la Pampa Ondulada con diferente mineralogía de arcillas Water movement in some Argiudolls of the rolling Pampa differing in their clay mineralogy

    Directory of Open Access Journals (Sweden)

    Mario Guillermo Castiglioni


    Full Text Available Los suelos zonales de la Pampa Ondulada son Argiudoles Típicos y Vérticos los cuales se diferencian en la composición mineralógica de su fracción arcilla. El objetivo del presente trabajo fue analizar las vinculaciones entre la tasa de movimiento del agua edáfica con algunos atributos relacionados con la composición mineralógica de la fracción arcilla, en distintos suelos representativos de la región mencionada. Se tomaron muestras de los horizontes A, BA/BE, Bt y BC de dos Argiudoles Típicos y de un Argiudol Vértico, realizando sobre las mismas determinaciones relacionadas con la cantidad y tipo de las arcillas presentes. A su vez mediante diferentes técnicas se evaluaron el sistema poroso del suelo y el movimiento de agua edáfica. En los horizontes Bt, aquellos parámetros que integran el tipo y el contenido de arcillas, como el COLE y la CIC, mostraron estar mejor vinculados con el movimiento de agua edáfica que cuando se consideró únicamente el porcentaje de arcilla. La distinta porosidad estructural generada dentro de los agregados de los horizontes Bt, originó diferencias en su difusividad y conductividad hidráulica no saturada, a contenidos de humedad por encima del 50% de saturación. En aquellos horizontes con mayor actividad biológica y menor contenido de arcilla, el movimiento de agua se realizó en forma independiente de las características de las arcillas presentes.Typic and Vertic Argiudolls, which differ in the composition of their clay fraction, are the zonal soils in the Rolling Pampa of Argentina. The aim of this work has been to analize the relationship between water movement and diverse soil properties in some representative soils of the Rolling Pampa, differing in their clay mineralogy. The A, BA/ BE, Bt and BC horizons of two Typic and one Vertic Argiudolls were sampled and a number of properties related with clay content and clay type were measured. Soil porosity and soil water movement were also

  1. Determination of water absorption and water holding capacities of different soil mixtures with MINIDRAIN system to enhance the plant growth (United States)

    Sudan Acharya, Madhu; Rauchecker, Markus; Wu, Wei


    Soil water holding capacity is the amount of water that a given soil can hold against the force of gravity. Soil texture and organic matter are the key components that determine soil water holding capacity. Soils with smaller particle sizes, such as silt and clay have larger surface area can hold more water compared to sand which has large particle sizes which results in smaller surface area. A study report showed that 1% increase in soil humus will result in a 4% increase in stored soil water (Morris, 2004) and 1 part humus holds 4 parts of water (Wheeler and Ward, 1998). Therefore, the more humus that can be added to the soil, the greater the water holding capacity of the soil. As the level of organic matter increases in a soil, the water holding capacity also increases due to the affinity of organic matter for water. The water holding capacity of the soil is determined by the amount of water held in the soil sample vs. the dry weight of the sample. MINIDRAIN is a patented system made of geo-fabric (fleece) or combination of geosynthetics and humus. MINIDRAIN and vegetation nets developed by the company ÖKO-TEX (Linz, Austria) will improve the distribution of water and air in the soils, increase the growth of vegetation and reduce the soil erosion. Depending on the physical configuration, there are four different combinations of MINIDRAIN systems developed by ÖKO-TEX. a) Geotextile (fleece) strips of different sizes (e.g. 5x10x250 mm) b) Net formed strips (drainage nets) of different sizes c) Multilayer geotextile mats with humus, seeds or compost of different sizes (e.g. 10x30x200 mm) d) Multilayer geotextile net formed mats with humus, seeds or compost This paper describes the experimental results of the water absorption and water holding capacity of different forms of MINIDRAIN under different soil mixes. In this experiment, potting soil, coarse sand and LECA (Light weight clay aggregates) balls are mixed with different proportion of MINIDRAIN systems and

  2. Metal corrosion and argillite transformation at the water-saturated, high-temperature iron-clay interface: A microscopic-scale study

    Energy Technology Data Exchange (ETDEWEB)

    Schlegel, Michel L. [Department of Physics and Chemistry, CEA - Laboratory for the Reactivity of Surfaces and Interfaces, DPC/SCP/LRSI, CEN Saclay, Bat. 391, F-91191 Gif-sur-Yvette Cedex (France); UMR 8587 ' LAMBE' , Universite d' Evry-Val d' Essonne, 91 025 Evry (France)], E-mail:; Bataillon, Christian [CEA - Laboratory for the Study of Aqueous Corrosion, DPC/SCCME/LECA, CEN Saclay, Bat. 458, F-91191 Gif-sur-Yvette Cedex (France); Benhamida, Keltoum; Blanc, Cecile; Menut, Denis; Lacour, Jean-Luc [Department of Physics and Chemistry, CEA - Laboratory for the Reactivity of Surfaces and Interfaces, DPC/SCP/LRSI, CEN Saclay, Bat. 391, F-91191 Gif-sur-Yvette Cedex (France)


    In this study, microscopic and spectroscopic techniques (scanning electron microscopy coupled with energy-dispersive X-ray analysis, Raman microspectroscopy, micro X-ray fluorescence spectroscopy, micro X-ray fine structure adsorption spectroscopy, and micro laser-induced breakdown spectroscopy) were combined to decipher the chemical and mineralogical properties of a saturated Fe-clay interface reacted at 90 deg. C and 50 bar for 8 months. The results collectively confirm the presence of a corrosion layer and a clay transformation layer. The corrosion layer is made of a magnetite-containing internal sublayer and a Fe-phyllosilicate external sublayer enriched in Na, with traces of goethite presumably resulting from sample reaction with air. The clay transformation layer is made of predominantly Ca-rich siderite (FeCO{sub 3}). It is depleted in Al and K, suggesting dissolution of rock-forming minerals. The corroded thickness determined from the amount of Fe in corrosion and transformation layers and assuming zero porosity equals 19 {+-} 9 {mu}m. These data indicate that the interfacial clay was transformed by dissolution of calcite and clay minerals and precipitation of siderite close to the original surface. Silica released upon clay dissolution diffused into the corrosion layer and coprecipitated with oxidized Fe to form Fe-phyllosilicate.

  3. Water Districts - MO 2010 Active Public Drinking Water Systems (SHP) (United States)

    NSGIC GIS Inventory (aka Ramona) — This point layer represents active public drinking water systems. Each public drinking water system's distribution or service area is represented by a single point.

  4. Crystalline structure and morphological properties of porous cellulose/clay composites: The effect of water and ethanol as coagulants. (United States)

    Ahmadzadeh, Safoura; Desobry, Stephane; Keramat, Javad; Nasirpour, Ali


    In this study, cellulose foams incorporated with surface-modified montmorillonite (SM-MMT) were prepared following NaOH dissolution and regeneration into water and ethanol. According to the SEM images, the type of coagulating agent significantly affected the morphological properties of composite foams. The crystalline parameters were evaluated using wide-angle X-ray diffraction (WAXD), which showed an increase in crystal size as the effect of SM-MMT; however, the crystal size decreased for the samples treated with ethanol. The distribution of hydrogen bond types was also investigated using Fourier transform infrared (FTIR). Resolving the hydrogen-bonded OH stretching band at around 3340 into five bands indicated that presence of SM-MMT caused the shift of OH-stretching vibration band to lower wave number due to new hydrogen bonds between cellulose and SM-MMT. In general, the results indicated a change in the contents of the intra- and inter-molecular hydrogen bonds when the coagulant was changed or SM-MMT was incorporated.

  5. 描述黏粒含量对土-水特征曲线影响规律的分形模型%A fractal model describing the relation between clay content and soil-water characteristic curve

    Institute of Scientific and Technical Information of China (English)

    陶高梁; 张季如; 庄心善; 杨琳


    Clay content of soil has an important influence on soil-water characteristic curve. To establish a theoretical model describing the influence of clay content on soil-water characteristic curve, the relation be-tween the clay content and fractal dimension in terms of mass has been established by means of a fractal theory. This relation was verified by test data and used to explain the basic rule that the fractal dimension increases with the increase of clay content. On this basis, a fractal model which reflects the influence of clay content on soil-water characteristic curve was suggested based on the previous results. The results show that the soil-water characteristic curves predicted by the model are in good agreement with several tests data. The model was applied to predict the soil-water characteristic curves of some soils with different clay content and shows the influence of clay content on the soil-water characteristic curve, i.e., large clay content corresponds to large water content of volume in the case of same soil suction.%土体黏粒含量对土-水特征曲线有重要影响。为了建立描述黏粒含量对土-水特征曲线影响规律的理论模型,本文基于分形理论,建立了质量分维数与黏粒含量的关系式,利用已有试验数据验证了该式的合理性,并从理论上解释了质量分维数随黏粒含量增大的基本规律。在此基础上,结合已有的研究成果,建立了分形模型描述土体黏粒含量对土-水特征曲线影响规律,该模型预测的土-水特征曲线与已有不同土类样本的试验数据吻合较好,从而证明了该模型的有效性。最后,利用该模型同时预测了不同黏粒含量典型土体的土-水特征曲线,阐明了黏粒含量对土-水特征曲线影响的基本规律,即相同吸力条件下,黏粒含量越高,则体积含水率越高。

  6. Behavior of compacted clay-concrete interface

    Institute of Scientific and Technical Information of China (English)

    R.R. SHAKIR; Jungao ZHU


    Tests of interface between compacted clay and concrete were conducted systematically using interface simple shear test apparatus. The samples, having same dry density with different water content ratio, were prepared.Two types of concrete with different surface roughness, i.e., relatively smooth and relatively rough surface rough-ness, were also prepared. The main objectives of this paper are to show the effect of water content, normal stress and rough surface on the shear stress-shear displacement relationship of clay-concrete interface. The following were concluded in this study: 1) the interface shear sliding dominates the interface shear displacement behavior for both cases of relatively rough and smooth concrete surface except when the clay water content is greater than 16% for the case of rough concrete surface where the shear failure occurs in the body of the clay sample; 2) the results of interface shear strength obtained by direct shear test were different from that of simple shear test for the case of rough concrete surface; 3) two types of interface failure mechanism may change each other with different water content ratio; 4) the interface shear strength increases with increasing water content ratio especially for the case of clay-rough concrete surface interface.

  7. Study of adsorption of zinc in clay smectite type Bofe in system of finite bath; Estudo da adsorcao de zinco na argila esmectita do tipo Bofe em sistema de banho finito

    Energy Technology Data Exchange (ETDEWEB)

    Souza, R.S.; Mota, J.D.; Lima, W.S.; Rodrigues, M.G.F., E-mail:, E-mail: [Universidade Federal de Campina Grande (LABNOV//LABGER/UFCG), PB (Brazil). Unidade Academica de Engenharia Quimica. Lab. de Desenvolvimento de Novos Materiais e Lab. de Gestao Ambiental e Tratamento de Residuos


    Clays are demonstrably excellent adsorbents, both for their physical and chemical characteristics and the wide coverage and low cost. Among the various groups of clay minerals, the smectite are noted for having large surface areas. The initial objective of this study was to characterize the clay Bofe through the techniques of X-Ray Diffraction (XRD), X-Ray Spectrometry by Energy Dispersive (EDX) and nitrogen adsorption (BET). To evaluate the adsorption of metal ions zinc (synthetic sewage), we used a system in finite bath, following a factorial design 2{sup 2}, taking as input variables: pH and initial concentrations of zinc (Zn2 +) and output variables: percentage removal and removal capacity. The characterization results showed that Bofe clay belongs to the family of smectite and therefore has great potential for adsorption. (author)

  8. Drinking Water Temperature Modelling in Domestic Systems

    NARCIS (Netherlands)

    Moerman, A.; Blokker, M.; Vreeburg, J.; Van der Hoek, J.P.


    Domestic water supply systems are the final stage of the transport process to deliver potable water to the customers’ tap. Under the influence of temperature, residence time and pipe materials the drinking water quality can change while the water passes the domestic drinking water system. According

  9. Mobile surface water filtration system

    Directory of Open Access Journals (Sweden)

    Aashish Vatsyayan


    Full Text Available To design a mobile system for surface water filtrationMethodology: the filtration of surface impurities begins with their retraction to concentrated thickness using non ionising surfactants, then isolation using surface tension property and sedimentation of impurities in process chamber using electrocoagulation. Result:following studies done to determine the rate of spreading of crude oil on water a method for retraction of spread crude oil to concentrated volumes is developed involving addition of non -ionising surfactants in contrast to use of dispersants. Electrocoagulation process involves multiple processes taking place to lead to depositionof impurities such as oil, grease, metals. Studies of experiments conducted reveals parameters necessary for design of electrocoagulation process chamber though a holistic approach towards system designing is still required. Propeller theory is used in determining the required design of propeller and the desired thrust, the overall structure will finally contribute in deciding the choice of propeller.

  10. Permeability Features of Water-Resistant Clay Layer in Northern Shaanxi Province While Shallowly Buried Coal Mining%陕北浅埋煤层开采隔水土层渗透性变化特征

    Institute of Scientific and Technical Information of China (English)

    李涛; 李文平; 常金源; 都平平; 高颖


    In order to evaluate the effect of exploiting shallowly buried coal on the ground water and surface water in Shennan Mining Area of northern Shaanxi, we studied the water-resisting degrees of the key aquifuges in overlying soil strata under mining influence. Based on the geologic investigation in Shennan Mining Area, the results of water pressure tests, and the permeability coefficient of clays in Lishi and Bode Ground which are determined by medium-pressured triaxial servo with the process of clay loading and unloading, we proposed the effect of shallowly buried coal mining on the permeability coefficient of the clays. The results show that the shallowly buried coal mining results in thin bedrock roof falling completely, and the destabilization of clay strata results in a change of permeability coefficient of the clays with several orders in the connected fissures area. However, in the pull-apart area, the ground fissures make the permeability coefficient of clay in Lishi Ground largen. With the increase of pressure, the permeability coefficient of clay in Bode Ground becomes smaller, resulting in plastic deformation of the clay, giving a basis for calculating the phreatic level which determinates the possibility of water preserving for exploiting the shallowly buried coal seams.%为评价陕北神南矿区浅埋煤层开采对地下水及地表水的影响,对煤层上覆关键隔水土层的采动隔水性进行研究.在进行了神南矿区野外地质调查的基础上,采用中压三轴伺服仪测定神南矿区离石组黄土及保德组红土在三轴加载及卸载过程中的渗透系数,并结合采前、采后现场压水试验成果研究了浅埋煤层开采前后关键隔水黏土层渗透系数变化特征.试验结果表明:浅埋煤层开采引起薄层基岩整体切落,在贯通裂隙发育区上覆隔水土层失稳表现为渗透系数几个数量级的巨大增加;而在拉张区黏土层上部的离石黄土受地面裂缝影响渗透性

  11. A minimalistic microbial food web in an excavated deep subsurface clay rock. (United States)

    Bagnoud, Alexandre; de Bruijn, Ino; Andersson, Anders F; Diomidis, Nikitas; Leupin, Olivier X; Schwyn, Bernhard; Bernier-Latmani, Rizlan


    Clay rocks are being considered for radioactive waste disposal, but relatively little is known about the impact of microbes on the long-term safety of geological repositories. Thus, a more complete understanding of microbial community structure and function in these environments would provide further detail for the evaluation of the safety of geological disposal of radioactive waste in clay rocks. It would also provide a unique glimpse into a poorly studied deep subsurface microbial ecosystem. Previous studies concluded that microorganisms were present in pristine Opalinus Clay, but inactive. In this work, we describe the microbial community and assess the metabolic activities taking place within borehole water. Metagenomic sequencing and genome-binning of a porewater sample containing suspended clay particles revealed a remarkably simple heterotrophic microbial community, fueled by sedimentary organic carbon, mainly composed of two organisms: a Pseudomonas sp. fermenting bacterium growing on organic macromolecules and releasing organic acids and H2, and a sulfate-reducing Peptococcaceae able to oxidize organic molecules to CO(2). In Opalinus Clay, this microbial system likely thrives where pore space allows it. In a repository, this may occur where the clay rock has been locally damaged by excavation or in engineered backfills.

  12. Soil Water Repellency of Sands and Clay as Affected by Particle Size%砂土和黏土的颗粒差异对土壤斥水性的影响

    Institute of Scientific and Technical Information of China (English)

    杨松; 吴珺华; 董红艳; 张燕明


    斥水性土壤广泛存在于自然界中,并且对土壤环境和作物生长等有重要影响。建立理想化的土壤颗粒模型对砂土和黏土的斥水特性进行计算分析。结果表明:当接触角很小时,砂土中不存在斥水现象。随着接触角的增大,砂土斥水性与含水率密切相关,砂土的密实度对其斥水性也有重要影响,当砂土比较密实时,土壤的“亲水”与“斥水”特性对含水率特别敏感,随着含水率的变化,砂土可能由亲水性较好的土壤转变为斥水性土壤;当砂土比较松散时,土壤颗粒的斥水性对含水率并不敏感。当黏土接触角略小于90°且湿润半径b也较小时,黏土也存在斥水现象。如果黏土颗粒的接触角较小或接触角小于90°且湿润半径b较大,黏土总是亲水的。黏土含水率较大时,斥水特性由土壤颗粒的接触角决定。%Water-repellent soils,existing widely in nature,have some important effects on soil environment and crop growth. In order to analyze water repellency of sand and clay,models of sand and clay different in particle size were built. Results showed that no phenomenon of water repellency was found in sand soil when the contact angle of water with sand was small. Water repellency of sand soil was closely related to soil water content when the sand-water contact angle was big. Compactness of the soil was another important factor affecting soil water repellency. When the sand soil was highly compacted,whether the soil was hydrophilic or hydrophobic was very sensitive to water content,and it might switch from one state to another with changing soil water content. When the sand soil was quite loose,it was no longer sensitive to soil water content. In clay soil with soil-water contact angle being slightly less than 90°and wetting radius b being small,the phenomenon of water repellency was observed. But when the clay soil was much smaller than 90°in soil-water and

  13. Modelling iron clay interactions in deep geological disposal conditions (United States)

    Bildstein, O.; Trotignon, L.; Perronnet, M.; Jullien, M.

    In the context of deep geological disposal of high level radioactive wastes, the interactions between iron and clay-rich materials may lead to adverse transformations of clay minerals with a potential loss of confining properties such as swelling and capacity to exchange cations. Such transformations have been experimentally observed at temperatures starting at ca. 80 °C, where smectites contained in a mixture of bentonite and iron powder are transformed into iron-rich serpentine-type minerals. The reaction-transport code CRUNCH is used to investigate the iron-clay interactions at 50 °C over a period of 10,000 years, which are the conditions considered here to represent the mean temperature value and the expected timescale for the corrosion stage. The aim is to predict the nature and quantity of corrosion product, calculate the chemistry of water (essentially the pH) and the mineralogical transformation in the system containing the canister, an optional engineered barrier (bentonite) and the host-rock (argillite). The results of the calculations show that at the interface with the canister, where steel corrosion occurs, the iron is partly immobilized by the precipitation of iron oxides (essentially magnetite) and small amounts of siderite. The pH stabilizes at high values, between 10 and 11, at this location. In the bentonite or the argillite in contact with the container, the primary clay minerals are destabilized and iron-rich serpentine-like minerals precipitate as observed in the experiments (cronstedtite and berthierine). These minerals show low cation exchange and swelling capacities. The results also show that the interactions between iron and clay may lead to significant porosity changes in the system. A reduction of the porosity is predicted at the surface of the steel canister, due to the precipitation of iron oxides. Porosity increase is predicted in the clay material due to the dissolution of the primary clay minerals. The effect of these porosity

  14. Clay goes patchy

    NARCIS (Netherlands)

    Kegel, W.K.; Lekkerkerker, H.N.W.


    Empty liquids and equilibrium gels have so far been only theoretical possibilities, predicted for colloids with patchy interactions. But evidence of both has now been found in Laponite, a widely studied clay.

  15. EEC Round Robin test on the repository system simulation - clay option. Final report EEC research contract No. Fl 1W-0116-l

    Energy Technology Data Exchange (ETDEWEB)

    Cantale, C.; Castelli, S.; Donato, A.; Traverso, D.M.


    The objective of the 'Reporting System Simulation Test (RSST) was to define a test method for the evaluation of waste performances in various geological disposal scenarios, with the possibility to simulate various additional materials, like canister, backfilling, overpack and host rock. The test procedure for the clay-option needed to be developed, especially with reference to the solution preparation and Eh (redox potential) measurements. The necessity to work in an argon atmosphere glove box brings in some operational complications, mainly in the case of the Eh measurement, filtering and final volume determination. The reproducibility of the experimental data does not seem to be particularly good, probably due to the difficulties in standardizing the experimental procedure. An effort should be done to improve these aspects. The tightness of the container and the physical stability of the rock/backfill/grill with pins/synthetic interstitial claywater system are excellent. The leaching data reveal that the clay contribution to the final ionic concentration of the solution is not negligible and should be better evaluated. The overall data-set shows that the glass leach rate, as expressed by Boron mass loss, decreases with time.




    This paper assesses the stabilizing effect of powdered glass on clay soil. Broken waste glass was collected and ground into powder form suitable for addition to the clay soil in varying proportions namely 1%, 2%, 5%, 10% and 15% along with 15% cement (base) by weight of the soil sample throughout. Consequently, the moisture content, specific gravity, particle size distribution and Atterberg limits tests were carried out to classify the soil using the ASSHTO classification system. Based on the...

  17. California community water systems inventory dataset, 2010 (United States)

    California Environmental Health Tracking Program — This data set contains information about all Community Water Systems in California. Data are derived from California Office of Drinking Water (ODW) Water Quality...

  18. The role of clay in enhancing attenuation of trace organic contaminants during managed aquifer recharge (United States)

    Regnery, J.; Strasser, A.; Hake, E.; Wing, A.; Drewes, J. E.


    For more hydrophobic trace organic contaminants present in surface water or reclaimed water applied for managed aquifer recharge (MAR), sorption onto organic matter can play a major role in attenuation in subsurface systems as the retardation allows more time for biotransformation. In case of low organic matter, other sorptive processes such as interactions with mineral surfaces gain importance. Especially for positively charged molecules, sorption onto clay materials by cation exchange will play a significant role. However, if the cation exchange capacity is limited or sorption of trace organic contaminants to clay materials is reversible due to changes in geochemical conditions (i.e., pH, ion strength), this might not provide a sustainable removal pathway. The objective of this study is to investigate how sorption to clay can enhance the removal of trace organic contaminants during MAR with the goal of evaluating the feasibility (i.e., infiltration capacity) and benefit (i.e., retardation of recalcitrant compounds) of introducing clay materials as reactive barriers in MAR systems. Laboratory-scale soil column experiments and batch sorption experiments using well characterized soil mixtures with different clay percentages under abiotic conditions and spiked at environmentally relevant concentration levels were conducted to derive soil water distribution coefficients for a suite of 15 trace organic chemicals (i.e., pharmaceutical residues, personal care products, household chemicals) and to quantify their sorption/desorption potential. All clay materials used in this study were characterized by X-ray diffraction to obtain information regarding their sorption processes. Furthermore, results were compared with geochemical field data from a full-scale MAR site in Colorado where significant amounts of clay in the subsurface were present. Preliminary results indicated that certain clay materials bear a great potential to retain moderately hydrophobic compounds such as

  19. The Effects of High Salinity Groundwater on the Performance of Clay Barriers

    Energy Technology Data Exchange (ETDEWEB)

    Savage, David [Quintessa Ltd., Nottingham (United Kingdom)


    Potential changes in groundwater chemistry during the operational or post-closure periods of the Swedish repository for spent fuel could affect the performance of both the bentonite buffer and repository backfill. For example, the up-coning of saline groundwater could lead to decreased swelling pressures in both the bentonite buffer and tunnel backfills, and could also induce 'piping'. SKB is considering these issues as part of its 'SR-Can' safety assessment. This report reviews evidence for the behaviour of swelling clays in groundwaters of varying salinity with special relevance to the SKB programme. Smectite clays can absorb water into clay inter-layers with the most important parameters being: the surface density of charge of the clay; the charge and solvation behaviour of the inter-layer ions; and the electrolyte concentration or activity of water. Two categories of swelling are generally observed: innercrystalline swelling caused by the hydration of the exchangeable cations in the dry clay; and osmotic swelling, resulting from concentration gradients in ion concentrations between clay surfaces and pore water. Several models exist to interpret and predict the swelling behaviour of clays. SKB currently prefer an interpretation of clay swelling pressure where clay particles are viewed as 'macro-ions' and the entire clay-water system can be considered as a 'polyelectrolyte'. SKB use the term 'Donnan exclusion' to estimate the amount of introduced ions into the clay and hence the amount of reduced swelling pressure due to contact with a saline solution. Donnan exclusion is the process whereby the migration of anions through the narrow aqueous film surrounding clay platelets is restricted due to the repulsion by the negative charge of the clay platelets. SKB's experimental work shows that: There is an exponential relation between swelling pressure and mean basal interlamellar spacing of the clay. Ions from the

  20. Engineering property test of kaolin clay contaminated by diesel oil

    Institute of Scientific and Technical Information of China (English)

    刘志彬; 刘松玉; 蔡奕


    Engineering property of kaolin clay contaminated by diesel oil was studied through a series of laboratory experiments. Oil contents (mass fraction) of 4%, 8%, 12%, 16% and 20% were selected to represent different contamination degrees, and the soil specimens were manually prepared through mixing and static compaction method. Initial water content and dry density of the test kaolin clay were controlled at 10% and 1.58 g/cm3, respectively. Test results indicate that since part of the diesel oil will be released from soil by evaporation, the real water content should be derived through calibration of the quasi water content obtained by traditional test method. As contamination degree of the kaolin clay increases, both liquid limit and plastic limit decrease, but there’s only a slight increase for plasticity index. Swelling pressure of contaminated kaolin clay under confined condition will be lowered when oil-content gets higher. Unconfined compressive strength (UCS) of the oil-contaminated kaolin clay is influenced by not only oil content but also curing period. Increase of contamination degree will continually lower UCS of the kaolin clay specimen. In addition, electrical resistivity of the contaminated kaolin clay with given water content decreases with the increase of oil content. However, soil resistivity is in good relationship with oil content and UCS. Finally, oil content of 8% is found to be a critical value for engineering property of kaolin clay to transit from water-dominated towards oil-dominated characteristics.

  1. Calculation of the debris flow concentration based on clay content

    Institute of Scientific and Technical Information of China (English)

    CHEN Ningsheng; CUI Peng; LIU Zhonggang; WEI Fangqiang


    The debris flow clay content has very tremendous influence on its concentration (γC). It is reported that the concentration can be calculated by applying the relative polynomial based on the clay content. Here one polynomial model and one logarithm model to calculate the concentration based on the clay content for both the ordinary debris flow and viscous debris flow are obtained. The result derives from the statistics and analysis of the relationship between the debris flow concentrations and clay content in 45 debris flow sites located in the southwest of China. The models can be applied for the concentration calculation to those debris flows that are impossible to observe. The models are available to calculate the debris flow concentration, the principles of which are in the clay content affecting on the debris flow formation, movement and suspending particle diameter. The mechanism of the relationship of the clay content and concentration is clear and reliable. The debris flow is usually of micro-viscous when the clay content is low (<3%), by analyzing the developing tendency on the basics of the relationship between the clay content and debris flow concentration. Indeed, the less the clay content, the less the concentration for most debris flows. The debris flow tends to become the water rock flow or the hyperconcentrated flow with the clay content decrease. Through statistics it is apt to transform the soil into the viscous debris flow when the clay content of ranges is in 3%-18%. Its concentration increases with the increasing of the clay content when the clay content is between 5% and 10%. But the value decreases with the increasing of the clay content when the clay content is between 10% and 18%. It is apt to transform the soil into the mudflow, when the clay content exceeds 18%. The concentration of the mudflow usually decreases with the increase of the clay content, and this developing tendency reverses to that of the micro-viscous debris flow. There is

  2. Performance of polymeric films based thermoplastic starch and organophilic clay; Efeito da incorporacao de argila no desempenho de filmes de amido termoplastico/PEBD

    Energy Technology Data Exchange (ETDEWEB)

    Cipriano, P.B.; Costa, A.N.M.; Araujo, S.S.; Araujo, A.R.A.; Canedo, E.L.; Carvalho, L.H., E-mail: [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Dept. de Engenharia de Materiais


    The aim of this work was the development and investigation of the properties of flat films of LDPE/corn thermoplastic starch (TPS). A bentonite clay (Argel) was organophilized and characterized by XRD. This clay (1%) in both pristine and organophilic forms was added to the matrix (LDPE) and to LDPE/TPS systems with TPS contents varying from 5-20% w/w. The films manufactured (LDPE, LDPE/Clay, LDPE/TPS, LDPE/TPS/Clay) were characterized. Results indicate that water vapor permeability is dependent and increases with TPS content which was attributed to the higher affinity of water by TPS. TPS and Clay addition to LDPE led to significant changes in film properties with respect to the neat LDPE. In general,tensile and perforation forces increased with clay and TPS contents; the strength of thermo sealed films lowered with natural clay addition and increased with TPS and organoclay incorporation and, in general, dynamic friction coefficient decrease with organoclay and TPS addition. Best overall properties were obtained for the systems containing the organoclay and optimal properties were achieved for the 5%TPS10 LDPE1% ANO system. (author)

  3. Hydrogel membranes of PVAl/ clay by gamma radiation (United States)

    de Oliveira, M. J. A.; Parra, D. F.; Amato, V. S.; Lugão, A. B.


    In the last decades several studies concerning the new methods for drug delivery system have been investigated. A new field known as "smart therapy" involves devices and drug delivery systems to detect, identify and treat the site affected by the disease, not interfering with the biological system. Cutaneous Leishmaniasis is an endemic disease that is characterized by the development of single or multiple localized lesions on exposed areas of skin and one coetaneous treatment could be a potential solution. The aim of this study was to obtain polymeric hydrogel matrices of poly(vinylalcohol)(PVAl) and chitosan with inorganic nanoparticles, which can release a drug according to the need of the treatment of injury caused by leishmania on the skin. The hydrogels matrices were obtained with PVAl/ chitosan and PVAl/ chitosan 0.5; 1.0 and 1.5% laponite RD clay, crosslinked by ionizing gamma radiation with dose of 25 kGy. The techniques used for characterization were swelling, gel fraction, Fourier transform infrared spectroscopy (FTIR) and thermogravimetry (TGA). After synthesis, the samples were immersed in distilled water and weighed in periods of time until 60 h for the swelling determination. The obtained results have indicated that the swelling of the membranes increases with clay concentration, in consequence of ionic groups present in the clay.

  4. Joint project. Retention of radionuclides relevant for final disposal in natural clay rock and saline systems. Subproject 2. Geochemical behavior and transport of radionuclides in saline systems in the presence of repository-relevant organics. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Schmeide, Katja; Fritsch, Katharina; Lippold, Holger [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Inst. of Ressource Ecology; and others


    retention at these minerals could be attributed to surface-mediated reduction of Tc(VII) to Tc(IV). An influence of ionic strength was not observed. The influence of ionic strength (up to 3 mol/kg) and background electrolyte (NaCl, CaCl{sub 2}, MgCl{sub 2}) on U(VI) sorption onto montmorillonite was studied. The U(VI) sorption is influenced by the background electrolyte, the influence of ionic strength is small. Surface complexation modeling was performed applying the 2SPNE SC/CE model. Surface complexation constants were determined for the NaCl and CaCl{sub 2} system and were extrapolated to zero ionic strength. Surface complexation in mixed electrolytes can be modeled applying surface complexation constants derived for pure electrolytes. The influence of citrate on U(VI) diffusion in Opalinus Clay was studied using Opalinus Clay pore water as background electrolyte. The diffusion parameter values obtained for the HTO through-diffusion and the U(VI) in-diffusion in the absence of citric acid were in agreement with literature data. In the presence of citric acid, U(VI) diffusion was significantly retarded, which was attributed to a change in speciation, probably U(VI) was reduced to U(IV). Larger-scale heterogeneous material effects on diffusive transport were investigated with PET. Diffusion parameters were derived by optimum fit of a FEM-model to the measurement. These parameters are in accordance with the results from 1D-through-diffusion experiments. Deviations from the simple transversal-isotropic behavior, which are identified as residuals from the model, are indications for heterogeneous transport on the mm-scale. PET measurements were also conducted in order to display the improvement of the EDZ with waterglass injections. These experiments enable to draw conclusions on the complex reactive transport process and thus an estimation of the achieved improvement of the barrier function. The image reconstruction procedure was largely improved, mainly with the aid of

  5. Oscillatory shear response of moisture barrier coatings containing clay of different shape factor. (United States)

    Kugge, C; Vanderhoek, N; Bousfield, D W


    Oscillatory shear rheology of barrier coatings based on dispersed styrene-butadiene latex and clay of various shape factors or aspect ratio has been explored. Barrier performance of these coatings when applied to paperboard has been assessed in terms of water vapour transmission rates and the results related to shape factor, dewatering and critical strain. It has been shown that a system based on clay with high shape factor gives a lower critical strain, dewatering and water vapour transmission rate compared with clays of lower shape factor. The dissipated energy, as calculated from an amplitude sweep, indicated no attractive interaction between clay and latex implying a critical strain that appears to be solely dependent on the shape factor at a constant volume fraction. Particle size distribution was shown to have no effect on the critical strain while coatings of high elasticity exhibited high yield strains as expected. The loss modulus demonstrated strain hardening before the elastic to viscous transition. The loss modulus peak was identified by a maximum strain which was significantly lower for a coating based on clay with a high shape factor. The characteristic elastic time was found to vary between 0.6 and 1.3s. The zero shear viscosity of barrier dispersion coatings were estimated from the characteristic elastic time and the characteristic modulus to be of the order of 25-100 Pa s.

  6. Adsorption of dyes using different types of clay: a review (United States)

    Adeyemo, Aderonke Ajibola; Adeoye, Idowu Olatunbosun; Bello, Olugbenga Solomon


    Increasing amount of dyes in the ecosystem particularly in wastewater has propelled the search for more efficient low-cost adsorbents. The effective use of the sorption properties (high surface area and surface chemistry, lack of toxicity and potential for ion exchange) of different clays as adsorbents for the removal of different type of dyes (basic, acidic, reactive) from water and wastewater as potential alternatives to activated carbons has recently received widespread attention because of the environmental-friendly nature of clay materials. Insights into the efficiencies of raw and modified/activated clay adsorbents and ways of improving their efficiencies to obtain better results are discussed. Acid-modified clay resulted in higher rate of dye adsorption and an increased surface area and porosity (49.05 mm2 and 53.4 %). Base-modified clay has lower adsorption capacities, while ZnCl2-modified clay had the least rate of adsorption with a surface area of 44.3 mm2 and porosity of 43.4 %. This review also explores the grey areas of the adsorption properties of the raw clays and the improved performance of activated/modified clay materials with particular reference to the effects of pH, temperature, initial dye concentration and adsorbent dosage on the adsorption capacities of the clays. Various challenges encountered in using clay materials are highlighted and a number of future prospects for the adsorbents are proposed.

  7. Effective Removal of Heavy Metals from Wastewater Using Modified Clay. (United States)

    Song, Mun-Seon; Vijayarangamuthu, K; Han, EunJi; Jeon, Ki-Joon


    We report an economical and eco-friendly way to remove the heavy metal pollutant using modified clay. The modification of clay was done by calcining the natural clay from Kyushu region in Japan. Further, the removal efficiency for various pH and contact time was evaluated. The morphology of the clays was studied using the scanning electron microscopy (SEM). The structural and chemical analyses of modified clay were done by using X-ray diffraction (XRD), Raman spectroscopy, and Energy dispersion analysis (EDAX) to understand the properties related to the removal of heavy metal pollutant. Further, we studied the absorption efficiency of clay for various pH and contacting time using Ni polluted water. The modified clays show better removal efficiency for all pH with different saturation time. The adsorption follows pseudo-second order kinetics and the adsorption capacity of modified clay is 1.5 times larger than that of natural clay. The increase in the adsorption efficiency of modified clay was correlated to the increase in hematite phase along with increase in surface area due to surface morphological changes.

  8. Separation of components of a broad 1H-NMR composite signal by means of nutation experiments under low amplitude radiofrequency fields. Application to the water signal in synthetic clays; Developpement et mise en oeuvre d'une nouvelle methode fondee sur le phenomene de nutation pour la decomposition d'un signal composite de resonance magnetique nucleaire. Application au signal 1h de l'eau dans des argiles synthetiques

    Energy Technology Data Exchange (ETDEWEB)

    Trausch, G


    Nowadays, geologic nuclear waste storage is envisioned according to a multi-layer model which implies clays. The latter exhibit retention capacities and low permeability to water; that is why they are considered as a good candidate for engineered barriers to radioactive waste disposal. The present work here aims at studying transport phenomena which involve water molecules in three samples of synthetic clays (two of them exhibiting a Pake doublet) by means of Nuclear Magnetic Resonance (NMR). The first chapter describes structural properties of clays and presents the state-of-art of NMR and other experimental techniques used for such systems. The second chapter deals with the interpretation and the simulation of each conventional proton spectrum. These simulations allow us to evidence and to characterize a chemical exchange phenomenon. The third chapter is dedicated to original nutation experiments performed under low radiofrequency field in the case of broad NMR signal. It is shown that this type of NMR experiment can yield the number and the proportion of each species contributing to the whole signal. These results are exploited in the fourth chapter for processing relaxation and diffusion experiments. Finally, the diffusion coefficients obtained by NMR are divided by a factor 4 with respect to pure water while relaxation rates are two orders of magnitude greater. (author)

  9. 瘦西湖隧道下蜀黏土土水特征研究%Soil-water Characteristic of Xiashu Clay in Slender West Lake Tunnel

    Institute of Scientific and Technical Information of China (English)



    土水特征曲线(SWCC)作为表征非饱和土吸力与含水率关系的重要参数是研究非饱和土的关键,对于膨胀土而言,土水特征曲线又是分析其膨胀性能的重要指标。本文以扬州瘦西湖隧道下蜀黏土为研究对象,通过大尺寸渗析法和气相法两种方法测量了其土水特征曲线,在低吸力范围内(0~160 MPa)曲线存在明显回滞现象。结合3种不同数学模型对曲线进行拟合分析,发现 Fredlund and Xing 公式拟合最为准确。利用扫描电镜分析了不同含水率条件下的细观特征,试验表明:随着含水率的增加,下蜀黏土中的蒙脱石颗粒不断吸水膨胀,从而填充土体孔隙。%Soil-water characteristic curve (SWCC)is the key to reflect the relationship between matric suction and mois-ture content of unsaturated soil.As for expansive soil,SWCC is also an important indicator to represent its expansion per-formance.In this paper,SWCC of Xiashu clay in Slender West Lake Tunnel of Yangzhou is measured by large size osmotic method and vapor phase technique,it shows obvious hysteresis phenomenon during lower matric suction (0 ~160MPa). Fitting it with three kinds of mathematical model,Fredlund and Xing formula is found to be matched best.The meso-char-acteristics under different moisture conditions are analyzed through scanning electron microscope.Tests show that with the increase of moisture content,montmorillonite granules are continuously expanding and thus the soil pores between them can be filled.

  10. Water reactive hydrogen fuel cell power system (United States)

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael


    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  11. Electroporation System for Sterilizing Water (United States)

    Schlager, Kenneth J.


    A prototype of an electroporation system for sterilizing wastewater or drinking water has been developed. In electroporation, applied electric fields cause transient and/or permanent changes in the porosities of living cells. Electroporation at lower field strengths can be exploited to increase the efficiency of chemical disinfection (as in chlorination). Electroporation at higher field strengths is capable of inactivating and even killing bacteria and other pathogens, without use of chemicals. Hence, electroporation is at least a partial alternative to chlorination. The transient changes that occur in micro-organisms at lower electric-field strengths include significantly increased uptake of ions and molecules. Such increased uptake makes it possible to achieve disinfection at lower doses of chemicals (e.g., chlorine or ozone) than would otherwise be needed. Lower doses translate to lower costs and reduced concentrations of such carcinogenic chemical byproducts as trichloromethane. Higher electric fields cause cell membranes to lose semipermeability and thereby become unable to function as selective osmotic barriers between the cells and the environment. This loss of function is the cause of the cell death at higher electric-field intensities. Experimental evidence does not indicate cell lysis but, rather, combined leaking of cell proteins out of the cells as well as invasion of foreign chemical compounds into the cells. The concept of electroporation is not new: it has been applied in molecular biology and genetic engineering for decades. However, the laboratory-scale electroporators used heretofore have been built around small (400-microliter) cuvettes, partly because the smallness facilitates the generation of electric fields of sufficient magnitude to cause electroporation. Moreover, most laboratory- scale electroporators have been designed for testing static water. In contrast, the treatment cell in the present system is much larger and features a flow

  12. The effect of clay minerals on diasterane/sterane ratios (United States)

    van Kaam-Peters, Heidy M. E.; Köster, Jürgen; van der Gaast, Sjierk J.; Dekker, Marlèn; de Leeuw, Jan W.; Sinninghe Damsté, Jaap S.


    To examine the effect of clay minerals on diasterane/sterane ratios, the mineral compositions of three sample sets of sedimentary rocks displaying a wide range of diasterane/sterane ratios were analysed quantitatively. Diasterane/sterane ratios do not to correlate with clay content but depend on the amount of clay relative to the amount of organic matter (clay/TOC ratios). This correlation may explain the high diasterane/sterane ratios in crude oils and extracts derived from certain carbonate source rocks. Based on the concentrations of regular and rearranged steroids in the sample sets, it is proposed that diasterenes are partly reduced to diasteranes and partly degraded during diagenesis in a ratio largely determined by the availability of clay minerals. It is suggested that the hydrogen atoms required for reduction of the diasterenes originate from the water in the interlayers of clay minerals.

  13. Clay Minerals as Solid Acids and Their Catalytic Properties. (United States)

    Helsen, J.


    Discusses catalytic properties of clays, attributed to acidity of the clay surface. The formation of carbonium ions on montmorillonite is used as a demonstration of the presence of surface acidity, the enhanced dissociation of water molecules when polarized by cations, and the way the surface can interact with organic substances. (Author/JN)

  14. Modification and characterization of montmorillonite clay for the extraction of zearalenone (United States)

    Hue, Kerri-Ann Alicia

    Mycotoxins are secondary metabolites of organisms belonging to the fungus kingdom. The cost associated with mycotoxin contamination in the USA and Canada is approximately US $5 billion. Zearalenone (ZEN), a resorcylic acid lactone, is produced by various members of the genus Fusarium . These fungi often colonize a variety of foods and feedstuffs including, corn, sorghum, wheat, oats, barley, and other cereal grains. This metabolite has estrogenic effects in farm animals with pigs being the most sensitive. ZEN induces hyperestrogenism and can cause infertility, reduced sex drive, fetal mummification, and abortions. Clays have successfully been used in the animal feed industry as an adsorbent and binders for certain small, water soluble mycotoxins. These mycotoxins are attracted to the electrical imbalance between the layers of the clays caused by isomorphic substitution of structural atoms. The mycotoxins are sequestered in the clay layers and pass harmlessly through the animal. However, ZEN is water insoluble and is not extracted easily with aluminosilicate clays. Therefore the modification of hydrated sodium calcium aluminosilicate (HSCAS) clays with organic cations has been proposed to render the clays hydrophobic and increase the ZEN binding capacity. The goal of this study was to develop a safe and cost effective organophilic material able to bind and extract zearalenone, to investigate the factors most important to extraction, and to investigate the fundamental properties between the clay-surfactant-mycotoxin systems that lead to extraction. The clay was modified by cation exchange reactions with tricaprylmethylammonium (TCMA) chloride and generic corn oil. The organophilic clays were then characterized using XRD, FTIR, and TGA analytical techniques. These techniques were used to determine the change in fundamental clay properties that would lead to the extraction of ZEN. Desorption studies were performed to determine any increase in toxicity that might be

  15. Modernity and putty-clay (United States)

    Ganesh, Trichur Kailas

    This dissertation addresses issues arising out of the problems of capital accumulation, productivity growth and 'putty-clay' technology. The concept of economic modernity occupies a central place in the subject-matter studied here in that it expresses both the incessant drive for newness that characterizes economic reality and the persistence of dated techniques that successfully resist replacement. This study examines the way in which an expansive development-theoretic 'putty-clay' framework may be employed to explain the historical processes behind both the avalanche of newness (innovations) and the conservatism of technology in the U.S. economy. The guiding link is the fixity of investments in physical capital equipment over time and space. The dilemma of fixed capital is studied in the context of the constant entrepreneurial search for flexibility and liquidity. The thesis advanced is that a development (Entwicklung)-theoretic 'putty-clay' conceptualization of the economic system adequately addresses the recurring problems of fixity, flexibility, and liquidity, and thereby permits important insights into the enigma surrounding the persistent productivity growth slowdown and 'stagflation' of the late sixties and seventies and the related phenomena of physical 'capital obsolescence' and the financial or 'speculative explosions' of our times. The notion of 'putty-clay' used here is an innovative one in that it departs from the growth-theoretic literature to re-appear as a Schumpeterian theory of modernity modified by a Veblenite view of an economic system directed by the exigencies of the 'machine-process'. The empirical aptitude of a macroeconomic 'putty-clay' model to explain capital obsolescence mediated by the energy 'crises' (supply shocks) of the seventies and eighties is examined in a separate chapter with results that differ markedly from the standard (Berndt and Wood) conclusions for the U.S. economy. The final chapter in the dissertation reverts to the

  16. Final Report (BMWi Project No.: 02 E 10971): Joint project: Retention of radionuclides relevant for final disposal in natural clay rock and saline systems - Subproject 2: Geochemical behavior and transport of radionuclides in saline systems in the prese

    Energy Technology Data Exchange (ETDEWEB)

    Schmeide, Katja [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Fritsch, Katharina [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Lippold, Holger [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Poetsch, Maria [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Kulenkampff, Johannes [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Lippmann-Pipke, Johanna [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Jordan, Norbert [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Joseph, Claudia [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Moll, Henry [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Cherkouk, Andrea [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology; Bader, Miriam [Helmholtz-Zentrum Dresden, (Germany). Inst. of Resource Ecology


    The objective of this project was to study the influence of increased salinities on interaction processes in the system radionuclide – organics – clay – aquifer. For this, complexation, redox, sorption, and diffusion studies were performed under variation of the ionic strength (up to 4 mol kg-1) and the background electrolyte (NaCl, CaCl2, MgCl2).

  17. Geotechnical studies of Jaitapur marine clay

    Digital Repository Service at National Institute of Oceanography (India)

    Bhat, S.T.; Nayak, B.U.

    characterisEd. by high water content and high Atterberg limits. Undrained shear strength varied from 1.8 to 6 KPa. These were moderately sensitive clays. Carbonate content which varied from 3 to 27%, was found to influence engineering properties of the soil...

  18. Adhesion of E. coli to silver- or copper-coated porous clay ceramic surfaces (United States)

    Yakub, I.; Soboyejo, W. O.


    Porous ceramic water filters (CWFs), produced by sintering a mixture of clay and a combustible material (such as woodchips), are often used in point-of-use water filtration systems that occlude microbes by size exclusion. They are also coated with colloidal silver, which serves as a microbial disinfectant. However, the adhesion of microbes to porous clay surfaces and colloidal silver coated clay surfaces has not been studied. This paper presents the results of atomic force microscopy (AFM) measurements of the adhesion force between Escherichia coli bacteria, colloidal silver, and porous clay-based ceramic surfaces. The adhesion of silver and copper nanoparticles is also studied in control experiments on these alternative disinfectant materials. The adhesive force between the wide range of possible bi-materials was measured using pull-off measurements during force microscopy. These were combined with measurements of AFM tip radii/substrate roughness that were incorporated into adhesion models to obtain the adhesion energies for the pair wise interaction. Of the three antimicrobial metals studied, the colloidal silver had the highest affinity for porous ceramic surface (125 ± 32 nN and ˜0.29 J/m2) while the silver nanoparticles had the highest affinity for E. coli bacteria (133 ± 21 nN and ˜0.39 J/m2). The implications of the results are then discussed for the design of ceramic water filter that can purify water by adsorption and size exclusion.

  19. NEXAFS microscopy studies of the association of hydrocarbon thin films with fine clay particles

    Energy Technology Data Exchange (ETDEWEB)

    Covelli, Danielle [Department of Chemistry, University of Saskatchewan, Saskatoon, SK, S7N 5C9 (Canada); Hernandez-Cruz, Daniel [Brockhouse Institute for Material Research, McMaster University, Hamilton, ON, L8S 4M1 (Canada); Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 (United States); Haines, Brian M. [Department of Chemistry, University of Saskatchewan, Saskatoon, SK, S7N 5C9 (Canada); Munoz, Vincente; Omotoso, Oladipo; Mikula, Randy [CANMET Energy Technology Centre Natural Resources Canada, Devon, AB, T9G 1A8 (Canada); Urquhart, Stephen [Department of Chemistry, University of Saskatchewan, Saskatoon, SK, S7N 5C9 (Canada)], E-mail:


    The nature of organic species associated with clay minerals plays a significant role in several processes, from hydrocarbon recovery in oil sands to contaminated soil remediation and water treatment. In this work, we address the use of scanning transmission X-ray microscopy (STXM) in conjunction with near edge X-ray absorption fine structure (NEXAFS) spectroscopy to study the microstructure and chemistry of organic-clay associations in situ. A model system based on methylene blue and illite is used to explore the sensitivity of NEXAFS microscopy to these interactions, and to identify and resolve experimental challenges in these measurements. We find that sample contamination from X-ray induced photodeposition is a significant problem in STXM microscopy, but also that this problem can be substantially reduced with a liquid nitrogen cooled anticontaminator. With appropriate sample preparation and experimental procedures, we find that STXM microscopy is sensitive to thin carbon adsorbates on clay surfaces.

  20. Combined air and water pollution control system (United States)

    Wolverton, Billy C. (Inventor); Jarrell, Lamont (Inventor)


    A bioaquatic air pollution control system for controlling both water and atmospheric pollution is disclosed. The pollution control system includes an exhaust for directing polluted gases out of a furnace and a fluid circulating system which circulates fluid, such as waste water, from a source, past the furnace where the fluid flow entrains the pollutants from the furnace. The combined fluid and pollutants are then directed through a rock/plant/microbial filtering system. A suction pump pumps the treated waste water from the filter system past the exhaust to again entrain more pollutants from the furnace where they are combined with the fluid (waste water) and directed to the filter system.

  1. Geosynthetic clay liners shrinkage under simulated daily thermal cycles. (United States)

    Sarabadani, Hamid; Rayhani, Mohammad T


    Geosynthetic clay liners are used as part of composite liner systems in municipal solid waste landfills and other applications to restrict the escape of contaminants into the surrounding environment. This is attainable provided that the geosynthetic clay liner panels continuously cover the subsoil. Previous case histories, however, have shown that some geosynthetic clay liner panels are prone to significant shrinkage and separation when an overlying geomembrane is exposed to solar radiation. Experimental models were initiated to evaluate the potential shrinkage of different geosynthetic clay liner products placed over sand and clay subsoils, subjected to simulated daily thermal cycles (60°C for 8 hours and 22°C for 16 hours) modelling field conditions in which the liner is exposed to solar radiation. The variation of geosynthetic clay liner shrinkage was evaluated at specified times by a photogrammetry technique. The manufacturing techniques, the initial moisture content, and the aspect ratio (ratio of length to width) of the geosynthetic clay liner were found to considerably affect the shrinkage of geosynthetic clay liners. The particle size distribution of the subsoil and the associated suction at the geosynthetic clay liner-subsoil interface was also found to have significant effects on the shrinkage of the geosynthetic clay liner.

  2. 易盐渍区粘土夹层对土壤水盐运动的影响特征%Effect of clay interlayers on soil water-salt movement in easily-salinized regions

    Institute of Scientific and Technical Information of China (English)

    余世鹏; 杨劲松; 刘广明


    Large-scale soil column experiments for simulation water-salt movement in clay interlayers under normal growing conditions were carried out in an easily-salinized region for different textures of soils and groundwater conditions in the Huang-Huai-Hai alluvial plain of China. In this study, the 20-year measurement was analyzed to examine the effect of clay interlayers on soil water-salt movement in easily-salinized regions. Results show that the clay inter-layer has a significant positive effect on the water-holding capacity in the soil and acts as a filter obstructing the salinity infiltration. This is especially true for restraining the penetration of surface accumulated salts. The thicker the clay interlayer is, the greater the effect will be. The range of depth to groundwater is likely to be smaller in the area with surface accumulated salts and clay interlayers around 1.0 m than that with silt loam soils around 1.5 m. And in the latter case, the salinization of soils is easily induced when the groundwater level is lower than a threshold value of 2.5 m. The amount of accumulated salts is found to be higher in clay interlayers than that in silt loam soils. Thus, proper monitoring and measures are necessary to prevent the secondary salinization of soils in the practice of water resources management.%针对黄淮海冲积平原土壤剖面中粘土夹层普遍存在的现象,在典型易盐渍区开展模拟易盐农田常规种植条件下水盐运移的大型土柱实验,基于长达20年的长系列监测数据分析,系统研究易盐渍区不同土体构型和地下水位等代表性条件下的土壤水盐运移规律和粘土夹层的影响特征.研究结果表明:粘土层有良好的保水和隔盐能力,尤其对表土积盐的抑制效果显著,且抑盐效果随粘土层厚度增加而提升;含粘土夹层土体表土积盐的地下水埋深范围更小,表土积盐高峰出现在l m左右地下水埋深,全剖面粉砂壤土土体

  3. Magnificent Clay Murals (United States)

    Kirker, Sara Schmickle


    Each August, third grade artists at Apple Glen Elementary in Bentonville, Arkansas, start the school year planning, creating, and exhibiting a clay relief mural. These mural projects have helped students to acquire not only art knowledge and techniques, but an even more important kind of knowledge: what it means to plan and successfully complete a…

  4. 安哥拉本哥拉市膨胀性粉质粘土浸水试验研究%Field Water Immersion Test on Expansive Silty Clay in Benguela, Angola

    Institute of Scientific and Technical Information of China (English)

    廖燕宏; 唐国艺; 刘争宏


    The alluvial or diluvial silty clay around Benguela GRASA in Angola has the properties of swelling.Because of the very low water content,it is too dry to fetch the undisturbed sample,but the laboratory index from disturbed samples such as free swell and atterberg limits may distort the real fact~ So it is necessary and helpful to adopt field water immersion test for ascertaining the swelling properties.The results of the field test indicated that the laboratory results have limitations and mistakes to determine the swelling properties; the silty clay has a high potential of swelling because of low water content; while increasing the water content,the soil has high swelling deformation and expansive force; the deformation curve of the plate shows subsoil heave is sensitive with small fluctuation of moisture content; but,the strength would fall fast if the water content increase more,the Benguela silty clay has obvious sensitivity to water with the phenomena swelling and weakness during water content increasing.%本哥拉GRASA地区山前冲洪积成因的膨胀性粉质粘土因其含水率很小,难于取得原状土样,通过自由膨胀率、界限含水率等室内试验指标评价为非膨胀性土.但是现场浸水载荷试验结果表明:室内试验结果具有很大的局限性且存在误判的可能;本哥拉粉质粘土常年处于干燥低含水率状态,具有很大的膨胀潜势,浸水饱和后的膨胀量和膨胀力均很强烈;载荷板的变形过程揭示了土体遇水明显膨胀又容易发生地基破坏的性质,承载力在接近或达到饱和后,其强度又迅速大幅降低,粉质粘土具有明显遇水膨胀和增湿软化强烈的水敏特性.本哥拉粉质粘土的室内试验和现场试验具有显著的差异性,现场浸水载荷试验对于正确判定该类膨胀土的工程性质具有不可替代的作用.


    Directory of Open Access Journals (Sweden)



    Full Text Available Water management system include all activities and works which providing the administration of public domain of water, with local / national interest, and qualitative, quantitative and sustainable management of water resources. Hydrotechnical arrangements, consisting of a set of hydraulic structures, produce both a favorable and unfavorable influences on environment. Their different constructive and exploitation solutions exercise a significantly impact on the environment. Therefore the advantages and disadvantages of each solution must be weighed and determined to materialize one or other of them seriously argued.The optimization of water management systems is needed to meet current and future requirements in the field of rational water management in the context of integrated water resources management. Optimization process of complex water management systems includes several components related to environmental protection, technical side and the business side. This paper summarizes the main aspects and possibilities of optimization of existing water management systems and those that are to be achieved.

  6. Physical Properties of Latvian Clays



    Physical and chemical properties of clays mostly depends on its mineral and chemical composition, particle size and pH value. The mutual influence of these parameters is complex. Illite is the most abundant clay mineral in Latvia and usually used in building materials and pottery. The viscosity and plasticity of Latvian clays from several deposits were investigated and correlated with mineral composition, particle size and pH value. Fractionated and crude clay samples were used. The p...

  7. Bauxite washing for the removal of clay (United States)

    Ahmad, Ishaq; Hartge, Ernst-Ulrich; Werther, Joachim; Wischnewski, Reiner


    Clay impurities associated with bauxite negatively affect the Bayer process for alumina production. These impurities should be removed as far as possible by a beneficiation technique before the ore is used as feed for the Bayer process. In this current investigation, bauxite washing was conducted in the laboratory. Bauxite washing is a physical process that causes the disintegration and deagglomeration of the clay matrix, and bauxite is liberated from the clay (mainly rich in silica). Subsequently, separation occurs with the assistance of wet screening at a predetermined cut size. Three techniques were investigated in the laboratory: drum washing, water-jet washing, and ultrasonic washing. Various operating parameters were investigated for drum washing and water-jet washing, including materials retention time, drum rotation speed, solid concentration, water-jet spray duration, pressure, and height. We concluded that the retention time of bauxite inside the drum at a solid concentration of 55wt% and a drum rotation speed of 31 r/min is the dominant parameter for the removal of clay from the bauxite surface.

  8. Bauxite washing for the removal of clay

    Institute of Scientific and Technical Information of China (English)

    Ishaq Ahmad; Ernst-Ulrich Hartge; Joachim Werther; and Reiner Wischnewski


    Clay impurities associated with bauxite negatively affect the Bayer process for alumina production. These impurities should be removed as far as possible by a beneficiation technique before the ore is used as feed for the Bayer process. In this current investigation, bauxite washing was conducted in the laboratory. Bauxite washing is a physical process that causes the disintegration and deagglomeration of the clay matrix, and bauxite is liberated from the clay (mainly rich in silica). Subsequently, separation occurs with the assistance of wet screening at a predetermined cut size. Three techniques were investigated in the laboratory: drum washing, water-jet washing, and ultrasonic washing. Various operating parameters were investigated for drum washing and water-jet washing, including materials retention time, drum rotation speed, solid concentration, water-jet spray duration, pressure, and height. We concluded that the retention time of bauxite inside the drum at a solid concentration of 55wt% and a drum rotation speed of 31 r/min is the dominant parameter for the removal of clay from the bauxite surface.

  9. Clay Animals and Their Habitats (United States)

    Adamson, Kay


    Creating clay animals and their habitats with second-grade students has long been one of the author's favorite classroom activities. Students love working with clay and they also enjoy drawing animal homes. In this article, the author describes how the students created a diorama instead of drawing their clay animal's habitat. This gave students…

  10. Impact of the changes in the chemical composition of pore water on chemical and physical stability of natural clays. A review of natural cases and related laboratory experiments and the ideas on natural analogues for bentonite erosion/non-erosion

    Energy Technology Data Exchange (ETDEWEB)

    Puura, Erik (Eridicon OUe, Tartu (Estonia)); Kirsimaee, Kalle (Univ. of Tartu, Inst. of Ecology and Earth Sciences, Tartu (Estonia))


    A scientific literature survey was compiled with the specific objective to find information for smectite mobilization and/or retention in natural clay formations caused by contact with water with low ionic concentrations such as can be expected during and after an ice age. Evidence was sought if smectite particles are lost from the clay to the water and if accessory minerals that remain could form a growing filter slowing down or stopping further loss of smectite. Bentonites are present in geological layers for hundreds of millions of years. There is limited exchange with surrounding layers, eg K transported into the bentonite layer from surrounding shale layers leading to the increased illite % in smectite-illite of the bentonite. Another process is silicification of surrounding layers leading to lowered permeability of surrounding rocks. Geological literature data on historical bentonites do not consider colloid formation in low ionic strength water as relevant mechanism for smectite mobilization. However there are no studied cases where this could be a relevant mechanism (as proposed by colloid release scenario). Soil researchers have studied the mechanism of colloid release in laboratory experiments and have found that there has to be an abrupt change in infiltrating water quality leading to 'osmotic explosion'. Clogging the pores in the lower part of the soil column has followed, leading to dramatic decrease of hydraulic conductivity in vertical profile and increased surface runoff. So, although limited, there are literature evidences of clay colloids release from bentonites/smectites caused by low-ionic circumneutral water. The geological settings to look for natural analogue studies include (1) Bentonite/smectite similar to what is used in repository. (2) Water similar to the composition of glacial meltwater. (3) Scenario similar to what is proposed in the bentonite erosion project. The problem related to the study of historical bentonite profiles

  11. Biofilm formation in a hot water system

    DEFF Research Database (Denmark)

    Bagh, L.K.; Albrechtsen, Hans-Jørgen; Arvin, Erik


    The biofilm formation rate was measured in situ in a hot water system in an apartment building by specially designed sampling equipment, and the net growth of the suspended bacteria was measured by incubation of water samples with the indigeneous bacteria. The biofilm formation rate reached......, in the sludge, or in the water from the distribution system was negligible. This indicated that bacterial growth took place on the inner surfaces in the hot water system and biofilm formation and detachment of bacteria could account for most of the suspended bacteria actually measured in hot water. Therefore...

  12. CMC use as colloid protector in water and clay basis drilling fluids: part II; Uso do CMC como coloide protetor em fluidos de perfuracao a base de agua e argilas: parte II

    Energy Technology Data Exchange (ETDEWEB)

    Amorim, Luciana Viana [Universidade Federal, Campina Grande, PB (Brazil). Engenharia de Processos]. E-mail:; Viana, Josiane Dantas; Farias, Kassie Vieira; Lira, Helio de Lucena; Ferreira, Heber Carlos [Universidade Federal, Campina Grande, PB (Brazil). Dept. de Engenharia de Materiais]. E-mail:;;;; Franca, Kepler Borges [Universidade Federal, Campina Grande, PB (Brazil). Dept. de Eng. Quimica]. E-mail:


    The aim of this work is to study the protect effect of the low viscosity carboxymethyl cellulose (CMC) on water based oil well drilling fluids and bentonite clays treated with sodium, additivated with degrading agents. The drilling fluids were prepared with a concentration of 4.86% w/w, according to PETROBRAS norms. It was studied three samples of natural bentonite clays treated with Na{sub 2}CO{sub 3}, from Boa Vista, PB. The drilling fluids were treated with three different concentration of CMC and submitted to a cure for a period of 24 hours. After it were added degrading agents (CaCl{sub 2} + MgCl{sub 2}). Also, it was done the treatment in a reverse order, i.e., first the drilling fluids were treated with degrading agents and after with CMC. It was measured apparent viscosity (AV), plastic viscosity (PV) by using a Fann Viscosimeter and water loss (WL), by using a Fann filter press. The results showed that CMC protect the drilling fluids from the flocculating effect of calcium and magnesium and stop the damage caused by degrading agents. Also, the order of the treatment (degrading agent - CMC) does not present significant influence in the rheological properties of the studied drilling fluids. (author)

  13. Small Drinking Water Systems Research and Development (United States)

    In the United States, there are 152,002 public water systems (PWS) in operation. Of these, 97% are considered small systems under the Safe Drinking Water Act (SDWA)—meaning they serve 10,000 or fewer people. While many of these small systems consistently provide safe, relia...

  14. Incorporation of treated straw and wood fly ash into clay building brick

    DEFF Research Database (Denmark)

    Chen, Wan; Ottosen, Lisbeth M.; Jensen, Pernille Erland;


    in the treated ash, suggests the possibility of the ash reuse in sintered clay bricks. In this study, the straw and wood fly ash treated by washing and EDR was incorporated into yellow clay bricks at different substitution rates. The properties of the clay-ash bricks were studied in terms of shrinkage, water...... absorption, porosity, density, compressive strength and leaching behavior, and compared with the 100% clay bricks. It’s promising to use the treated ash as a secondary building material....

  15. Comparison Of Direct Simple Shear Confinement Methods On Clay And Silt Specimens (United States)


    125   Figure D-1 – KN 159 JPC 11 Gulf of Mexico Clay Core Info...first type of clay tested was a high plasticity clay from the Gulf of Mexico taken from a Jumbo Piston Core ( JPC -11). The sample was obtained in 1998 as...Plastic Limit (PL) of the Gulf of Mexico Clay in JPC -11. Index test results obtained in this study indicated that the water content ranged from 70

  16. Napa Earthquake impact on water systems (United States)

    Wang, J.


    South Napa earthquake occurred in Napa, California on August 24 at 3am, local time, and the magnitude is 6.0. The earthquake was the largest in SF Bay Area since the 1989 Loma Prieta earthquake. Economic loss topped $ 1 billion. Wine makers cleaning up and estimated the damage on tourism. Around 15,000 cases of lovely cabernet were pouring into the garden at the Hess Collection. Earthquake potentially raise water pollution risks, could cause water crisis. CA suffered water shortage recent years, and it could be helpful on how to prevent underground/surface water pollution from earthquake. This research gives a clear view on drinking water system in CA, pollution on river systems, as well as estimation on earthquake impact on water supply. The Sacramento-San Joaquin River delta (close to Napa), is the center of the state's water distribution system, delivering fresh water to more than 25 million residents and 3 million acres of farmland. Delta water conveyed through a network of levees is crucial to Southern California. The drought has significantly curtailed water export, and salt water intrusion reduced fresh water outflows. Strong shaking from a nearby earthquake can cause saturated, loose, sandy soils liquefaction, and could potentially damage major delta levee systems near Napa. Napa earthquake is a wake-up call for Southern California. It could potentially damage freshwater supply system.

  17. Water Desalination Systems Powered by Solar Energy (United States)

    Barseghyan, A.


    The supply of potable water from polluted rivers, lakes, unsafe wells, etc. is a problem of high priority. One of the most effective methods to obtain low cost drinking water is desalination. Advanced water treatment system powered by Solar Energy and based on electrodialysis for water desalination and purification, is suggested. Technological and economic evaluations and the benefits of the suggested system are discussed. The Advanced Water Treatment System proposed clears water not only from different salts, but also from some infections, thus decreasing the count of diseases which are caused by the usage of non-clear water. Using Solar Energy makes the system stand alone which is convenient to use in places where power supply is problem.

  18. Grey water treatment systems: A review

    NARCIS (Netherlands)

    Abu-Ghunmi, L.N.A.H.; Zeeman, G.; Fayyad, M.; Lier, van J.B.


    This review aims to discern a treatment for grey water by examining grey water characteristics, reuse standards, technology performance and costs. The review reveals that the systems for treating grey water, whatever its quality, should consist of processes that are able to trap pollutants with a sm


    Directory of Open Access Journals (Sweden)

    Kubetskiy Valeriy Leonidovich


    Full Text Available In the course of construction of Sangtudinsky hydropower plant-1 on the River Vakhsh, it was deemed necessary to identify clay swelling properties in the event of alterations of the humidity mode of fructured half-rock soils, or the Suzakh clay, that accommodated tunnel-shaped water outlets within a section that was 75 meters long. The depth of tunnels was about 100 m. Any interaction with swelling soils could lead to destruction of the tunnel lining. Suzakh clays demonstrated the following physical and mechanical properties: density of particles of soil ρ= 2,69 g/cm; soil density ρ = 2.40-2.47 g/cm; porosity of 8.2-10.8 %; ultimate resistance to uniaxial compression = 13.1-31.0 MPa. Water saturated clay samples disintegrated into cloddy fragments; the rate of a longitudinal ultrasonic wave in the area of unaltered soils was equal to = 2500 m/c; repulse coefficient k was equal to 15 MPa/m; solidity coefficient (according to Protodyakonov was equal to 1,5; modulus of deformation in the massif was equal to 0.23 х10 MPa. The author proposed a methodology and designed a pilot set of equipment units designated for the identification of the swelling properties of fractured half-rock soils. Results of the pilot unit operation are presented in the article. Swelling properties are based on the monolith testing results. The programme contemplated a set of experiments held in various limit states on the surface of monoliths. Dependence between the swelling pressure and the swelling deformation in the course of water saturation was identified. The experiment demonstrates that alterations of the humidity mode of free surface Suzakh clays cause the relative deformation of swelling up to 1.1 %, and if the lining is rigid, the swelling pressure can exceed 4 MPa.

  20. Water masers in the Saturnian system (United States)

    Pogrebenko, S. V.; Gurvits, L. I.; Elitzur, M.; Cosmovici, C. B.; Avruch, I. M.; Montebugnoli, S.; Salerno, E.; Pluchino, S.; Maccaferri, G.; Mujunen, A.; Ritakari, J.; Wagner, J.; Molera, G.; Uunila, M.


    Context: The presence of water has long been seen as a key condition for life in planetary environments. The Cassini spacecraft discovered water vapour in the Saturnian system by detecting absorption of UV emission from a background star. Investigating other possible manifestations of water is essential, one of which, provided physical conditions are suitable, is maser emission. Aims: We report detection of water maser emission at 22 GHz associated with several Kronian satellites using Earth-based radio telescopes. Methods: We searched for water maser emission in the Saturnian system in an observing campaign using the Metsähovi and Medicina radio telescopes. Spectral data were Doppler-corrected over orbital phase for the Saturnian satellites, yielding detections of water maser emission associated with the moons Hyperion, Titan, Enceladus, and Atlas. Results: The detection of Saturnian water molecules by remote astronomical observation can be combined with in situ spacecraft measurements to harmonise the physical model of the Saturnian system.

  1. 某泥塑殿消防设施方案选择分析%Analysis on the design plan of some clay hall's fire extinguishing system

    Institute of Scientific and Technical Information of China (English)



    Against the decision of fire extinguishing system for some clay hall of national key cultural relics protection units,choose 4 index including fire extinguishing effect,secondary disaster,difficulty of installation and maintain,quantity of structural renovation project,and use risk assessment and fuzzy mathematics to analyze 4 common fire extinguishing system.Results showed that the most suitable one is ABC fine dry powder fire extinguishing system,and then IG541 gas fire extinguishing system,automatic sprinkler system,and ordinary ABC dry powder fire extinguishing system.After considering the protection of cultural relics,decide to choose cabinet fine dry powder fire extinguishing system,and fire control methods were put forward.%针对某全国重点文物保护单位泥塑殿拟选用的灭火系统,选择灭火效果、灭火系统产生的次生灾害、安装维护难度、结构改造工程量4个指标,应用风险评价方法和模糊数学理论对4种常见灭火系统进行分析得知,最适用于大殿的灭火系统是ABC超细干粉灭火系统,其次是IG541气体灭火系统、自动喷水预作用系统、普通ABC干粉灭火系统.进一步考虑文物保护等因素,指出大殿宜选择柜式ABC超细干粉灭火装置,并提出了现阶段大殿火灾防控措施.

  2. Service Water System Inspection Locator (SWSIL)

    Energy Technology Data Exchange (ETDEWEB)

    Pytel, M.L.; Tang, S.S.; Carney, C.E.; Licina, G.J. (Structural Integrity Associates, Inc., San Jose, CA (United States))


    Inspection and maintenance of a service water system is a key to reliable system operation. As emphasized by NRC Generic Letter 89-13, service water system reliability in nuclear plants must by assured since the SWS may support safety related equipment The diversity of design, water chemistry, and operating regimens, coupled with the tremendous size of these systems (literally miles of piping and hundreds of heat exchangers) makes the selection of locations to be inspected a difficult chore. In cooperation with the Electric Power Research Institute (EPRI) and the New York Power Authority (NYPA), a Service Water System Inspection Locator (SWSIL) has been developed to explore the feasibility of using an expert system to evaluate the corrosion susceptibility of the thousands of locations and components associated with nuclear service water systems (SWS). Such an expert system provides utilities with a method for planning and prioritizing inspections. SWSIL, Version 1.0, has been applied to the emergency diesel generator service water cooling loop of the emergency service water (ESW) system of the James A. FitzPatrick plant. The feasibility demonstration described in this report provided a framework for applying SWSIL to a system of any size. The demonstration also showed that refinement of the plant data input interface and flow modeling are required. Applicability of SWSIL in its current configuration to large systems is limited and awaits these improvements.

  3. Mud peeling and horizontal crack formation in drying clays

    KAUST Repository

    Style, Robert W.


    Mud peeling is a common phenomenon whereby horizontal cracks propagate parallel to the surface of a drying clay. Differential stresses then cause the layer of clay above the crack to curl up to form a mud peel. By treating the clay as a poroelastic solid, we analyze the peeling phenomenon and show that it is caused by the gradient in tensile stress at the surface of the clay, analogously to the spalling of thermoelastic materials. For a constant water evaporation rate at the clay surface we derive equations for the depth of peeling and the time of peeling as functions of the evaporation rate. Our model predicts a simple relationship between the radius of curvature of a mud peel and the depth of peeling. The model predictions are in agreement with the available experimental data. Copyright 2011 by the American Geophysical Union.

  4. Kansas Water Quality Action Targeting System (KATS) (United States)

    Kansas Data Access and Support Center — This system is a revision of the original KATS system developed in 1990 as a tool to aid resource managers target Kansas valuable and vulnerable water resources for...

  5. Recyclable hydrotalcite clay catalysed Baylis-Hillman reaction

    Indian Academy of Sciences (India)

    Vivek Srivastava


    The Baylis-Hillman reaction using ionic liquid/hydrotalcite clay catalytic system has been observed to be more reactive in terms of yield and reaction rate than DABCO/acetonitrile system. During the process, the reactants enjoy ionic liquid/hydrotalcite clay catalytic system and gives corresponding Baylis-Hillman reaction products in good yield. The application of our catalytic system has been diversifying for the synthesis of lactone ceramide analogue from (S)-Garner aldehyde-methyl acrylate using Baylis-Hillman reaction. Recycling of ionic liquid/hydrotalcite clay catalytic system has also been demonstrated in this report.

  6. Systems modelling for effective mine water management

    Energy Technology Data Exchange (ETDEWEB)

    Cote, C.M.; Moran, C.J.; Hedemann, C.J.; Koch, C. [University of Queensland, Brisbane, Qld. (Australia)


    Concerns about the difficulties in securing water have led the Australian coal mining industry to seek innovative ways to improve its water management and to adopt novel strategies that will lead to less water being used and more water being reused. Simulation tools are essential to assess current water management performance and to predict the efficiency of potential strategies. As water systems on coal mines are complex and consist of various inter-connected elements, a systems approach was selected, which views mine site water management as a system that obtains water from various sources (surface, groundwater), provides sufficient water of suitable quality to the mining tasks (coal beneficiation, dust suppression, underground operations) and maintains environmental performance. In this paper, the model is described and its calibration is illustrated. The results of applying the model for the comparison of the water balances of 7 coal mines in the northern Bowen Basin (Queensland, Australia) are presented. The model is used to assess the impact of applying specific water management strategies. Results show that a simple systems model is an appropriate tool for assessing site performance, for providing guidance to improve performance through strategic planning, and for guiding adoption of site objectives.

  7. Defect and Innovation of Water Rights System

    Institute of Scientific and Technical Information of China (English)

    Zhou Bin


    The rare deposition of water resources conflicts with its limitless demand. This determined the existence of the water rights transaction system. The implementation of the water rights transaction system requires clarifying the definition of water re-source fight above all distinctly. At present, it is a kind of common right system arrangement which needs the Chinese government to dispose of water resources. Though a series of management sys-tems guaranteed the government's supply of water resource, it hindered the development of the water market seriously and caused the utilization of water resources to stay in the inefficient or low efficient state for a long time. Thus, we should change the government's leading role in the resource distribution and really rely on the market to carry on the water rights trade and transac-tion. In this way, the water rights could become a kind of private property right relatively, and circulate freely in the market. As a result of this, we should overcome the defects of common right, make its external performance internalized maximally and achieve the optimized water resource disposition and use it more effec-tively.

  8. A Study of Clay-Epoxy Nanocomposites Consisting of Unmodified Clay and Organo Clay

    Directory of Open Access Journals (Sweden)

    Graham Edward


    Full Text Available Clay-epoxy nanocomposites were synthesized from DGEBA resin and montmorillonite clay with an in-situ polymerization. One type of untreated clay and two types of organo clay were used to produce the nanocompsoites. The aims of this study were to examine the nanocomposite structure using different tools and to compare the results between the unmodified clay and modified clays as nanofillers. Although diffractogram in reflection mode did not show any apparent peak of both types of materials, the transmitted XRD (X-Ray Difraction graphs, DSC (Differential Scanning Calorimeter analysis and TEM (Transmission Electron Microscope images revealed that the modified clay-epoxy and unmodified clay-epoxy provides different results. Interestingly, the micrographs showed that some of the modified clay layers possessed non-exfoliated layers in the modified clay-epoxy nanocomposites. Clay aggregates and a hackle pattern were found from E-SEM images for both types of nanocomposite materials. It is shown that different tools should be used to determine the nanocomposite structure.

  9. Values Connecting Societies and Water Systems

    NARCIS (Netherlands)

    J.A. van Ast (Jacko); J.J. Bouma (Jan Jaap); M. Bal (Mansee)


    markdownabstract__Introduction__ Water systems such as rivers and lakes have many important values for ecosystems and human societies. Both economical, social-ecological, cultural and political values are met by the water systems, connecting different activities in human society and ecosystem

  10. Basics of Solar Heating & Hot Water Systems. (United States)

    American Inst. of Architects, Washington, DC.

    In presenting the basics of solar heating and hot water systems, this publication is organized from the general to the specific. It begins by presenting functional and operational descriptions of solar heating and domestic hot water systems, outlining the basic concepts and terminology. This is followed by a description of solar energy utilization…

  11. Clay Improvement with Burned Olive Waste Ash

    Directory of Open Access Journals (Sweden)

    Utkan Mutman


    Full Text Available Olive oil is concentrated in the Mediterranean basin countries. Since the olive oil industries are incriminated for a high quantity of pollution, it has become imperative to solve this problem by developing optimized systems for the treatment of olive oil wastes. This study proposes a solution to the problem. Burned olive waste ash is evaluated for using it as clay stabilizer. In a laboratory, bentonite clay is used to improve olive waste ash. Before the laboratory, the olive waste is burned at 550°C in the high temperature oven. The burned olive waste ash was added to bentonite clay with increasing 1% by weight from 1% to 10%. The study consisted of the following tests on samples treated with burned olive waste ash: Atterberg Limits, Standard Proctor Density, and Unconfined Compressive Strength Tests. The test results show promise for this material to be used as stabilizer and to solve many of the problems associated with its accumulation.


    Energy Technology Data Exchange (ETDEWEB)

    Robert L. Lee; Junghan Dong


    This final report of ''Modified Reverse Osmosis System for Treatment of Produced Water,'' DOE project No. DE-FC26-00BC15326 describes work performed in the third year of the project. Several good results were obtained, which are documented in this report. The compacted bentonite membranes were replaced by supported bentonite membranes, which exhibited the same salt rejection capability. Unfortunately, it also inherited the clay expansion problem due to water invasion into the interlayer spaces of the compacted bentonite membranes. We noted that the supported bentonite membrane developed in the project was the first of its kind reported in the literature. An {alpha}-alumina-supported MFI-type zeolite membrane synthesized by in-situ crystallization was fabricated and tested. Unlike the bentonite clay membranes, the zeolite membranes maintained stability and high salt rejection rate even for a highly saline solution. Actual produced brines from gas and oil fields were then tested. For gas fields producing brine, the 18,300 ppm TDS (total dissolved solids) in the produced brine was reduced to 3060 ppm, an 83.3% rejection rate of 15,240 ppm salt rejection. For oilfield brine, while the TDS was reduced from 181,600 ppm to 148,900 ppm, an 18% rejection rate of 32,700 ppm reduction, the zeolite membrane was stable. Preliminary results show the dissolved organics, mainly hydrocarbons, did not affect the salt rejection. However, the rejection of organics was inconclusive at this point. Finally, the by-product of this project, the {alpha}-alumina-supported Pt-Co/Na Y catalytic zeolite membrane was developed and demonstrated for overcoming the two-step limitation of nonoxidation methane (CH{sub 4}) conversion to higher hydrocarbons (C{sub 2+}) and hydrogen (H{sub 2}). Detailed experiments to obtain quantitative results of H{sub 2} generation for various conditions are now being conducted. Technology transfer efforts included five manuscripts submitted to

  13. Characterization of groundwater dynamics in landslides in varved clays

    Directory of Open Access Journals (Sweden)

    J. E. van der Spek


    Full Text Available Groundwater dynamics may play a significant role in landslides. A detailed model is developed of the groundwater dynamics in landslides in varved clays in the Trièves area in the French Alps. The varved clays consist of a sequence of alternating silt and clay layers, covered by a colluvium layer and cut through by fissures. The hydraulic conductivity of the clay layers is negligible compared to the silt layers. It is conceptualized that fissures form a hydraulic connection between the colluvium and the varved clays. Groundwater recharge flows through the colluvium into the fissures where water is exchanged horizontally between the fissure and the silt layers of the varved clays. Groundwater flow in the colluvium is simulated with the Boussinesq equation while flow in the silt layers of the varved clays is simulated with the Richards' equation. Longitudinal outflow from the fissure is simulated with a linear-reservoir model. Scattered data of relatively short monitoring periods is available for several landslides in the region. A good similarity between observed and simulated heads is obtained, especially when considering the lack of important physical parameters such as the fissure width and the distance between the monitoring point and the fissure. A simulation for the period 1959–2004 showed some correlation between peaks in the simulated heads and the recorded occurrence of landslides while the bottom of the varved clays remained saturated during the entire simulation period.

  14. Comparative assessment of water infiltration of soils under different tillage systems in eastern Botswana (United States)

    Moroke, T. S.; Dikinya, O.; Patrick, C.

    Water infiltration is an important component of water balance for improving crop production potential in dryland soil tillage systems in Botswana, particularly in the eastern region. Hardsetting soils common in arable lands of Botswana, often require some kind of tillage such as mouldboard ploughing, chiselling and ripping to improve waterharvesting and crop growth conditions. The objective of this study was to compare ponded cumulative infiltration, steady state infiltration rate and sorptivity of soils cultivated using deep ripping, single and double mouldboard ploughing. This study was conducted on Chromic Luvisols (sandy loam), Haplic Luvisols (sandy clay loam), Ferric Luvisols (clay loam), and Ferric Arenosols (sand). Infiltration was measured using double ring infiltrometer method for 4 h. Although infiltration was smaller on traffic line of deep ripping system at all sites, it was only significantly ( P 0.05) different under deep ripped. Cumulative and steady state infiltration rate was greater under sandy than loamy soils, smaller under double ploughing compared with single ploughed and deep ripped soils. Sorptivity was not significantly ( P > 0.05) different among tillage systems but was greater under sandy than sandy loam soils. Information on tillage and infiltration can improve implementation of waterharvesting technologies and crop production in Botswana.

  15. Wash water waste pretreatment system (United States)


    Investigations were completed on wash waters based on each candidate personal cleansing agent. Evaluations of coagulants, antifoam agents, and the effect of promising antifoams on the chemical precipitation were included. Based on these evaluations two candidate soaps as well as their companion antifoam agents were selected for further work. Operating parameters included the effect of soap concentration, ferric chloride concentration, duration of mixing, and pore size of depth filters on the degree of soap removal. The effect of pressure on water flow through filter cartridges and on the rate of decline of water flow was also investigated. The culmination of the program was the recommendation of a pretreatment concept based on chemical precipitation followed by pressure filtration.

  16. Preoperational test report, raw water system

    Energy Technology Data Exchange (ETDEWEB)

    Clifton, F.T.


    This represents the preoperational test report for the Raw Water System, Project W-030. Project W-030 provides a ventilation upgrade for the four Aging Waste Facility tanks. The system supplies makeup water to the W-030 recirculation evaporative cooling towers for tanks AY1O1, AY102, AZ1O1, AZ102. The Raw Water pipe riser and associated strainer and valving is located in the W-030 diesel generator building. The tests verify correct system operation and correct indications displayed by the central Monitor and Control System.

  17. Comparing specialised and mixed farming systems in the clay areas of the Netherlands under future policy scenarios : an optimisation approach

    NARCIS (Netherlands)

    Bos, J.F.F.P.


    Keywords: interdisciplinary analysis, mixed farming, linear programming, agricultural policy, environmental policyIncreasing attention for the sustainability concept also caused renewed interest in mixed farming systems in the Netherlands, which supposedly have some advantages over specialised farmi

  18. Active Water Explosion Suppression System (United States)


    efficient in eliminating the heat of detonation , thereby eliminating the heat of combustion and the associated burning of explosive by-products in the...efficiency in eliminating the heat of detonation . In any case, the net effect of the water absorbing the detonation energy of the explosive is a major

  19. Toxicological evaluation of clay minerals and derived nanocomposites: a review. (United States)

    Maisanaba, Sara; Pichardo, Silvia; Puerto, María; Gutiérrez-Praena, Daniel; Cameán, Ana M; Jos, Angeles


    Clays and clay minerals are widely used in many facets of our society. This review addresses the main clays of each phyllosilicate groups, namely, kaolinite, montmorillonite (Mt) and sepiolite, placing special emphasis on Mt and kaolinite, which are the clays that are more frequently used in food packaging, one of the applications that are currently exhibiting higher development. The improvements in the composite materials obtained from clays and polymeric matrices are remarkable and well known, but the potential toxicological effects of unmodified or modified clay minerals and derived nanocomposites are currently being investigated with increased interest. In this sense, this work focused on a review of the published reports related to the analysis of the toxicological profile of commercial and novel modified clays and derived nanocomposites. An exhaustive review of the main in vitro and in vivo toxicological studies, antimicrobial activity assessments, and the human and environmental impacts of clays and derived nanocomposites was performed. From the analysis of the scientific literature different conclusions can be derived. Thus, in vitro studies suggest that clays in general induce cytotoxicity (with dependence on the clay, concentration, experimental system, etc.) with different underlying mechanisms such as necrosis/apoptosis, oxidative stress or genotoxicity. However, most of in vivo experiments performed in rodents showed no clear evidences of systemic toxicity even at doses of 5000mg/kg. Regarding to humans, pulmonary exposure is the most frequent, and although clays are usually mixed with other minerals, they have been reported to induce pneumoconiosis per se. Oral exposure is also common both intentionally and unintentionally. Although they do not show a high toxicity through this pathway, toxic effects could be induced due to the increased or reduced exposure to mineral elements. Finally, there are few studies about the effects of clay minerals on

  20. Organic farming effects on clay dispersion in carbon-exhausted soils


    Schjønning, Per; de Jonge, Lis Wollesen; Olesen, Jørgen E.; Greve, Mogens Humlekrog


    Many Danish soils are depleted in organic matter (OM) after decades of intensive cereal cultivation (Schjønning et al., 2009). In this paper we show that clay particles (colloids) in soils that are low in OM content are easily dispersed in the soil water, which in turn has important effects on soil ecosystem functions and services. Organic farming systems generally tend to increase soil OM contents and may thus mitigate the negative effects.

  1. Characterization of clay minerals; Caracterizacion de minerales arcillosos

    Energy Technology Data Exchange (ETDEWEB)

    Diaz N, C.; Olguin, M.T.; Solache R, M.; Alarcon H, T.; Aguilar E, A. [Gerencia de Ciencias Basicas, Direccion de Investigacion Cientifica, Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)


    The natural clays are the more abundant minerals on the crust. They are used for making diverse industrial products. Due to the adsorption and ion exchange properties of these, a great interest for developing research directed toward the use of natural clays for the waste water treatment has been aroused. As part of such researches it is very important to carry out previously the characterization of the interest materials. In this work the results of the mineral and elemental chemical composition are presented as well as the morphological characteristics of clay minerals from different regions of the Mexican Republic. (Author)

  2. Integrated waste and water management system (United States)

    Murray, R. W.; Sauer, R. L.


    The performance requirements of the NASA Space Station have prompted a reexamination of a previously developed integrated waste and water management system that used distillation and catalytic oxydation to purify waste water, and microbial digestion and incineration for waste solids disposal. This system successfully operated continuously for 206 days, for a 4-man equivalent load of urine, feces, wash water, condensate, and trash. Attention is given to synergisms that could be established with other life support systems, in the cases of thermal integration, design commonality, and novel technologies.

  3. Preparation and characterization of bentonite organo clay; Preparacao de caracterizacao de argilas bentonitas organofilicas

    Energy Technology Data Exchange (ETDEWEB)

    Bertagnolli, C.; Almeida Neto, A.F. [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. de Engenharia Quimica. Lab. de Engenharia Ambiental; Silva, M.G.C., E-mail: meuris@feq.unicamp.b [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. de Engenharia Quimica


    Bentonite clays organically modified have great potential use for environmental remediation, especially in the separation of organic compounds from the water. The aim of this work was the preparation of organophilic clays from 'Verde-Lodo' bentonite clay with the quaternary ammonium salts cetyl-pyridinium chloride and benzalkonium chloride. The materials obtained were characterized by XRD, thermogravimetric analyses, Helium picnometry, SEM and energy dispersive X-ray techniques. The results show consistently successful synthesis of the organoclay through the increase in the basal spacing, as well as salt elimination picks and presence of carbon and chlorine in the modified clays; they are inexistent elements in the natural clay. (author)

  4. Shear Strength Behavior of Two Landfill Clay Liners

    Institute of Scientific and Technical Information of China (English)


    Direct shear tests were conducted to obtain both the shear strength of compacted clay liners (CCLs) specimens and the interface shear strength between compacted clay liner and base soil. These experiments were conducted under the conditions of five different water contents. The experimental results show that shear strength of both CCLs and CCLs/base interface decreases with the increase in the water content of CCLs and base soil. In addition, the considerate concentration of NaCl in leachate has no deteriorating effect on the shear strength of liners. Triaxial shear tests were also conducted on clay liner specimens to obtain total and effective shear strength under a fast compression. The shear strength c'=100 kPa for sand-bentonite, respectively. These results indicate that the compacted clay-bentonite shows normal consolidation, but that the compacted sand-bentonite exhibits over-consolidation.

  5. Cyclic Shearing Deformation Behavior of Saturated Clays

    Institute of Scientific and Technical Information of China (English)


    The apparatus for static and dynamic universal triaxial and torsional shear soil testing is employed to perform stress-controlled cyclic single-direction torsional shear tests and two-direction coupled shear tests under unconsolidated-undrained conditions. Through a series of tests on saturated clay, the effects of initial shear stress and stress reversal on the clay's strain-stress behavior are examined, and the behavior of pore water pressure is studied. The experimental results indicate that the patterns of stress-strain relations are distinctly influenced by the initial shear stress in the cyclic single-direction shear tests. When the initial shear stress is large and no stress reversal occurs, the predominant deformation behavior is characterized by an accumulative effect. When the initial shear stress is zero and symmetrical cyclic stress occurs, the predominant deformation behavior is characterized by a cyclic effect. The pore water pressure fluctuates around the confining pressure with the increase of cycle number. It seems that the fluctuating amplitude increases with the increase of the cyclic stress. But a buildup of pore water pressure does not occur. The deformations of clay samples under the complex initial and the cyclic coupled stress conditions include the normal deviatoric deformation and horizontal shear deformation, the average deformation and cyclic deformation. A general strain failure criterion taking into account these deformations is recommended and is proved more stable and suitable compared to the strain failure criteria currently used.

  6. Water masers in the Kronian system

    NARCIS (Netherlands)

    Pogrebenko, Sergei V.; Gurvits, Leonid I.; Elitzur, Moshe; Cosmovici, Cristiano B.; Avruch, Ian M.; Pluchino, Salvatore; Montebugnoli, Stelio; Salerno, Emma; Maccaferri, Giuseppe; Mujunen, Ari; Ritakari, Jouko; Molera, Guifre; Wagner, Jan; Uunila, Minttu; Cimo, Giuseppe; Schilliro, Francesco; Bartolini, Marco


    The presence of water has been considered for a long time as a key condition for life in planetary environments. The Cassini mission discovered water vapour in the Kronian system by detecting absorption of UV emission from a background star (Hansen et al. 2006). Prompted by this discovery, we starte

  7. 80 FR 65469 - NESHAP for Brick and Structural Clay Products Manufacturing; and NESHAP for Clay Ceramics... (United States)


    ... Clay Products Manufacturing; and NESHAP for Clay Ceramics Manufacturing; Final Rule #0;#0;Federal...; and NESHAP for Clay Ceramics Manufacturing AGENCY: Environmental Protection Agency (EPA). ACTION... NESHAP for Clay Ceramics Manufacturing. All major sources in these categories must meet...

  8. Improvement of Hydraulic System Blast Furnace Clay Gun%高炉泥炮液压系统改造

    Institute of Scientific and Technical Information of China (English)



    高炉泥炮是高炉生产的重点设备之一,本文介绍了高炉泥炮液压系统的构成及存在的问题。通过液压站静压导轨伸缩防护罩改造和位移传感器的定位优化,保证了高炉泥炮液压系统的正常运行,为高炉的稳定顺行创造了良好的条件。%Blast furnace mud gun was one of the key equipment of blast furnace.The paper introduced the composition of hydraulic system for blast furnace mud gun and the existing problems.Hydrostatic guide way telescopic protective cover positioning transformation and the displacement sensor was optimized through the hydraulic station to ensure the normal op-eration of the hydraulic system of blast furnace mud gun and create good conditions for the stable operation of blast furnace.

  9. Clays Can Decrease Gaseous Nutrient Losses from Soil-Applied Livestock Manures. (United States)

    Pratt, Chris; Redding, Matthew; Hill, Jaye; Brown, Grant; Westermann, Maren


    Clays could underpin a viable agricultural greenhouse gas (GHG) abatement technology given their affinity for nitrogen and carbon compounds. We provide the first investigation into the efficacy of clays to decrease agricultural nitrogen GHG emissions (i.e., NO and NH). Via laboratory experiments using an automated closed-vessel analysis system, we tested the capacity of two clays (vermiculite and bentonite) to decrease NO and NH emissions and organic carbon losses from livestock manures (beef, pig, poultry, and egg layer) incorporated into an agricultural soil. Clay addition levels varied, with a maximum of 1:1 to manure (dry weight). Cumulative gas emissions were modeled using the biological logistic function, with 15 of 16 treatments successfully fitted ( clay addition level compared with no clay addition, but this difference was not significant ( = 0.17). Nitrous oxide emissions were significantly lower (×3; clay addition level compared with no clay addition. When assessing manures individually, we observed generally decreasing trends in NH and NO emissions with increasing clay addition, albeit with widely varying statistical significance between manure types. Most of the treatments also showed strong evidence of increased C retention with increasing clay additions, with up to 10 times more carbon retained in treatments containing clay compared with treatments containing no clay. This preliminary assessment of the efficacy of clays to mitigate agricultural GHG emissions indicates strong promise.

  10. Outbursts of wet clays and the method of fighting them

    Energy Technology Data Exchange (ETDEWEB)

    Kesseru, Z.


    Under given stress conditions the fractured clay-bearing rocks may produce sudden rock displacements. The survey of experiences and the tests conducted concerning these types of water-rock interaction called wet clay outbursts are dealt with. A mechanical model developed for representing such phenomena as well as the laboratory tests preceding the model studies are described. Based on case studies the method of predetection and the choice of suitable methods of prevention are discussed.

  11. Surface Waters Information Management System (SWIMS) (United States)

    Kansas Data Access and Support Center — The Surface Waters Information Management System (SWIMS) has been designed to meet multi-agency hydrologic database needs for Kansas. The SWIMS project was supported...

  12. Water system microbial check valve development (United States)

    Colombo, G. V.; Greenley, D. R.; Putnam, D. F.


    A residual iodine microbial check valve (RIMCV) assembly was developed and tested. The assembly is designed to be used in the space shuttle potable water system. The RIMCV is based on an anion exchange resin that is supersaturated with an iodine solution. This system causes a residual to be present in the effluent water which provides continuing bactericidal action. A flight prototype design was finalized and five units were manufactured and delivered.

  13. Laboratory measurements of selected optical, physical, chemical, and remote-sensing properties of five water mixtures containing Calvert clay and a nonfluorescing dye (United States)

    Usry, J. W.; Whitlock, C. H.; Poole, L. R.; Witte, W. G., Jr.


    Total suspended solids concentrations ranged from 6.1 ppm to 24.3 ppm and sizes ranged between 1.5 micrometers and 10 micrometers with the most frequently occurring size less than 2 micrometers. Iron concentration was less than 1 percent of the total suspended solids. Nonfluorescing dye concentrations of the two mixtures were 20 ppm and 40 ppm. Attenuation coefficient for the five mixtures ranged from 4.8/m to 21.3/m. Variations in volume scattering function with phase angle were typical. Variations in attenuation and absorption coefficient with wavelength were similar for the mixtures without the dye. Attenuation coefficient of the mixtures with the dye increased for wavelengths less than 600 nm due to the dye's strong absorption peak near 500 nm. Reflectance increased as the concentration of Calvert clay increased and peaked near 600 nm. The nonfluorescent dye decreased the magnitude of the peak, but had practically no effect on the variation for wavelengths greater than 640 nm. At wavelengths less than 600 nm, the spectral variations of the mixtures with the dye were significantly different from those mixtures without the dye.

  14. Study on hydrodynamics associated with quality of water in water distribution system

    Institute of Scientific and Technical Information of China (English)

    李欣; 顾大明; 赵洪宾; 袁一星


    The quality of water in water distribution system may vary with both location and time. Water quality models were used to predict spatial and temporal variation of water quality throughout the water system. Before analyzing the variations of water quality, it is necessary to determine the hydrodynamics in water distribution system. Analytical methods for the flow path from water sources to the observed point and water age of every observed node are proposed. This paper makes a further study on water supply route of multi-sources water supply network system. These studies have been applied to an actual water distribution system.

  15. Modeling water uptake by a root system growing in a fixed soil volume

    CERN Document Server

    Albrieu, J L Blengino; Tarzia, D A


    The water uptake by roots of plants is examined for an ideal situation, with an approximation that resembles plants growing in pots, meaning that the total soil volume is fixed. We propose a coupled water uptake-root growth model. A one-dimensional model for water flux and water uptake by a root system growing uniformly distributed in the soil is presented, and the Van Genuchten model for the transport of water in soil is used. The governing equations are represented by a moving boundary model for which the root length, as a function of time, is prescribed. The solution of the model is obtained by front-fixing and finite element methods. Model predictions for water uptake by a same plant growing in loam, silt and clay soils are obtained and compared. A sensitivity analysis to determine relative effects on water uptake when system parameters are changed is also presented and shows that the model and numerical method proposed are more sensitive to the root growth rate than to the rest of the parameters. This se...

  16. A mechanism of basal spacing reduction in sodium smectitic clay materials in contact with DNAPL wastes. (United States)

    Ayral-Cinar, Derya; Otero-Diaz, Margarita; Demond, Avery H


    There has been concern regarding the possible attack of clays in aquitards, slurry walls and landfill liners by dense nonaqueous phase liquid (DNAPL) wastes, resulting in cracking. Despite the fact that a reduction in basal spacing in sodium smectitic clay materials has been linked to cracking, no plausible mechanism by which this reduction occurs in contact with waste DNAPLs has been formulated. To elucidate a mechanism, screening studies were conducted that showed that the combination of an anionic surfactant (AOT), a nonionic surfactant (TritonX-100) and a chlorinated solvent, tetrachloroethylene (PCE), could replicate the basal spacing reduction and cracking behavior of water-saturated bentonite caused by two waste DNAPLs obtained from the field. FTIR measurements of this system showed a displacement of the HOH bending band of water symptomatic of desiccation. Sorption measurements showed that the uptake of AOT by bentonite increased eight fold in the presence of TritonX-100 and PCE. The evidence presented here supports a mechanism of syneresis, involving the extraction of water from the interlayer space of the clay through the synergistic sorption of a nonionic and anionic surfactant mixture. It is speculated that the solvation of water in reverse micellar aggregates is the process driving the syneresis.

  17. Clay resources in the Netherlands

    NARCIS (Netherlands)

    Meulen, M.J. van der; Maljers, D.; Gessel, S.F. van; Gruijters, S.H.L.L.


    Clay is a common lithology in the Dutch shallow subsurface. It is used in earth constructions such as dikes, and as raw material for the fabricationof bricks, roof tiles etc. We present a new national assessment of Dutch clay resources, as part of a project that provides mineral-occurrenceinformatio

  18. Clay resources in the Netherlands

    NARCIS (Netherlands)

    Meulen, M.J. van der; Maljers, D.; Gessel, S.F. van; Gruijters, S.H.L.L.


    Clay is a common lithology in the Dutch shallow subsurface. It is used in earth constructions such as dikes, and as raw material for the fabrication of bricks, roof tiles etc. We present a new national assessment of Dutch clay resources, as part of a project that provides mineral-occurrence informat

  19. Clay minerals in pollution control

    Energy Technology Data Exchange (ETDEWEB)

    Tateo, F. [Consiglio Nazionale delle Ricerche, Istituto di Ricerca sulle Argille, Tito Scalo, PZ (Italy)


    Clay minerals are fundamental constituents of life, not only as possible actors in the development of life on the Earth (Cairns-Smith and Hartman, 1986), but mainly because they are essential constituents of soils, the interface between the solid planet and the continental biosphere. Many, many authors have devoted themselves to the study of clays and clay minerals since the publication of the early modern studies by Grim (1953, 1962) and Millot (1964). In those years two very important associations were established in Europe (Association Internationale pour l'Etude des Argiles, AIPEA) and in the USA (Clay Mineral Society, CMS). The importance of these societies is to put together people that work in very different fields (agronomy, geology, geochemistry, industry, etc.), but with a common language (clays), very useful in scientific work. Currently excellent texts are being published, but introductory notes are also available on the web (Schroeder, 1998).

  20. Hydro static water level systems at Fermilab

    Energy Technology Data Exchange (ETDEWEB)

    Volk, J.T.; Guerra, J.A.; Hansen, S.U.; Kiper, T.E.; Jostlein, H.; Shiltsev, V.; Chupyra, A.; Kondaurov, M.; Singatulin, S.


    Several Hydrostatic Water Leveling systems (HLS) are in use at Fermilab. Three systems are used to monitor quadrupoles in the Tevatron and two systems are used to monitor ground motion for potential sites for the International Linear Collider (ILC). All systems use capacitive sensors to determine the water level of water in a pool. These pools are connected with tubing so that relative vertical shifts between sensors can be determined. There are low beta quadrupoles at the B0 and D0 interaction regions of Tevatron accelerator. These quadrupoles use BINP designed and built sensors and have a resolution of 1 micron. All regular lattice superconducting quadrupoles (a total of 204) in the Tevatron use a Fermilab designed system and have a resolution of 6 microns. Data on quadrupole motion due to quenches, changes in temperature will be presented. In addition data for ground motion for ILC studies caused by natural and cultural factors will be presented.

  1. Development and Characterisation of Nanoclays from Indian Clays

    Directory of Open Access Journals (Sweden)

    S. Manocha


    Full Text Available Indian clays are known for their smecticity. One such clay sample collected from Bhuj (Gujaratwas characterised and modified by successive sedimentation processes for different time intervals.The non-plastic components of clay, viz., quartz, illite, iron oxide, CaO, MgO, and organic matterwere removed in different steps, as the heavy impurities in the clay-water suspensions, settledown during sedimentation. The free iron oxide present in clay suspension was reduced bygiving sodium citrate-bicarbonate-dithionite treatment and iron content was further reducedfrom 12Œ15 per cent to 5Œ7 per cent respectively. The organic matter was removed by sodiumacetate-H2O2 treatment. The modified clay so obtained was characterised by thermal analysis,FTIR, and XRD,  SEM and TEM. The cation exchange capacities of original and modified clayswere determined both by methylene blue method and ammonium acetate method. The cationex change capacity is found to enhance from 120Œ130 meq/100 g to 135Œ145 meq/100 g. Usingthe above procedure, 92 per cent smecticity was obtained. Organo philisation of purified clay(smectite was carried out by intercalation with alkyl ammonium salt. The  XRD  analysis show edenhancement of interlamellar spacing from 1.294 nm to 2.855 nm.Defence Science Journal, 2008, 58(4, pp.517-524, DOI:

  2. Preparation and properties of biodegradable starch–clay nanocomposites

    KAUST Repository

    Chung, Yi-Lin


    Well-dispersed starch-clay nanocomposites were prepared by adding a dilute clay dispersion to a solution of starch followed by coprecipitation in ethanol. The clay didn\\'t significantly influence the type of crystalline structure of starch molecules although the amount of crystallinity appears to be somewhat lower in the nanocomposites. The nanocomposites show improved modulus and strength without a decrease in elongation at break. The increase in modulus and strength is 65% and 30%, respectively for the nanocomposite containing 5 wt.% clay compared to the unfilled starch materials. Further increases in clay result in deterioration in properties most likely due to poorer clay dispersion and lower polymer crystallinity. As the amount of water increases, the modulus of both pure starch and starch nanocomposites decreases, although the change is less pronounced in the nanocomposites suggesting that the addition of clay to form nanocomposites can improve the stability of starch-based products during transportation and storage. © 2009 Elsevier Ltd. All rights reserved.

  3. Mineral resource of the Month: Clay (United States)

    Virta, Robert L.


    Clays were one of the first mineral commodities used by people. Clay pottery has been found in archeological sites that are 12,000 years old, and clay figurines have been found in sites that are even older.

  4. Tradeoffs of modifications of storm water managements systems for nitrogen loss pathways in semi-arid ecosystems (United States)

    Lohse, K. A.; Gallo, E. L.; Brooks, P. D.; Meixner, T.; McIntosh, J. C.


    Urbanization is altering hydrologic and nitrogen (N) inputs to streams that may substantially increase nitrogen-containing trace gas emissions to the atmosphere with regional and global consequences. In the semi-arid southwestern US, human modifications of ephemerally dry stream channels interact with hydrologic and nitrogen alterations to lead to extremely high fluxes of nitrous oxide (N2O). Cumulative N2O losses ranged from 0.04 to 0.97 mg N m-2 in 6 hr for rainfall compared to 22.5-59.3 mg N m-2 for flood pulse events. Impervious channels eliminated N trace gas losses but increased delivery of water and N to downstream ecosystems and areas of focused recharge by 6 fold compared to watersheds with greater pervious channel lengths. In contrast, importation of clay into channels increased total N trace gas losses by 8-32 fold relative to more natural sand dominated channels but this result depended on the degree of wetting. Our integrated findings suggest human modification of storm water management systems to impervious channels increases delivery of water and N to downstream navigable waters and areas of focused recharge whereas importation of clay materials leads to higher N trace gas losses and reduced delivery of nitrate. Management will need to address long-term challenges of balancing tradeoffs of greenhouse N gases and N in water supplies, intermediate scale issues of enhancing recharge, and short-term issues of removing water and preventing flooding.

  5. Transmission X-ray Microscopy—A New Tool in Clay Mineral Floccules Characterization

    Directory of Open Access Journals (Sweden)

    Ray L. Frost


    Full Text Available Effective flocculation and dewatering of mineral processing streams containing clays are microstructure dependent in clay-water systems. Initial clay flocculation is crucial in the design and for the development of a new methodology of gas exploitation. Microstructural engineering of clay aggregates using covalent cations and Keggin macromolecules have been monitored using the new state of the art Transmission X-ray Microscope (TXM with 60 nm tomography resolution installed in a Taiwanese synchrotron. The 3-D reconstructions from TXM images show complex aggregation structures in montmorillonite aqueous suspensions after treatment with Na+, Ca2+ and Al13 Keggin macromolecules. Na-montmorillonite displays elongated, parallel, well-orientated and closed-void cellular networks, 0.5–3 µm in diameter. After treatment by covalent cations, the coagulated structure displays much smaller, randomly orientated and openly connected cells, 300–600 nm in diameter. The average distances measured between montmorillonite sheets was around 450 nm, which is less than half of the cell dimension measured in Na-montmorillonite. The most dramatic structural changes were observed after treatment by Al13 Keggin; aggregates then became arranged in compacted domains of a 300 nm average diameter composed of thick face-to-face oriented sheets, which forms porous aggregates with larger intra-aggregate open and connected voids.

  6. Status of LANL investigations of temperature constraints on clay in repository environments

    Energy Technology Data Exchange (ETDEWEB)

    Caporuscio, Florie A [Los Alamos National Laboratory; Cheshire, Michael C [Los Alamos National Laboratory; Newell, Dennis L [Los Alamos National Laboratory; McCarney, Mary Kate [Los Alamos National Laboratory


    The Used Fuel Disposition (UFD) Campaign is presently evaluating various generic options for disposal of used fuel. The focus of this experimental work is to characterize and bound Engineered Barrier Systems (EBS) conditions in high heat load repositories. The UFD now has the ability to evaluate multiple EBS materials, waste containers, and rock types at higher heat loads and pressures (including deep boreholes). The geologic conditions now available to the U.S.A. and the international community for repositories include saturated and reduced water conditions, along with higher pressure and temperature (P, T) regimes. Chemical and structural changes to the clays, in either backfill/buffer or clay-rich host rock, may have significant effects on repository evolution. Reduction of smectite expansion capacity and rehydration potential due to heating could affect the isolation provided by EBS. Processes such as cementation by silica precipitation and authigenic illite could change the hydraulic and mechanical properties of clay-rich materials. Experimental studies of these repository conditions at high P,T have not been performed in the U.S. for decades and little has been done by the international community at high P,T. The experiments to be performed by LANL will focus on the importance of repository chemical and mineralogical conditions at elevated P,T conditions. This will provide input to the assessment of scientific basis for elevating the temperature limits in clay barriers.

  7. Gas and water flow in an excavation-induced fracture network around an underground drift: A case study for a radioactive waste repository in clay rock (United States)

    de La Vaissière, Rémi; Armand, Gilles; Talandier, Jean


    The Excavation Damaged Zone (EDZ) surrounding a drift, and in particular its evolution, is being studied for the performance assessment of a radioactive waste underground repository. A specific experiment (called CDZ) was designed and implemented in the Meuse/Haute-Marne Underground Research Laboratory (URL) in France to investigate the EDZ. This experiment is dedicated to study the evolution of the EDZ hydrogeological properties (conductivity and specific storage) of the Callovo-Oxfordian claystone under mechanical compression and artificial hydration. Firstly, a loading cycle applied on a drift wall was performed to simulate the compression effect from bentonite swelling in a repository drift (bentonite is a clay material to be used to seal drifts and shafts for repository closure purpose). Gas tests (permeability tests with nitrogen and tracer tests with helium) were conducted during the first phase of the experiment. The results showed that the fracture network within the EDZ was initially interconnected and opened for gas flow (particularly along the drift) and then progressively closed with the increasing mechanical stress applied on the drift wall. Moreover, the evolution of the EDZ after unloading indicated a self-sealing process. Secondly, the remaining fracture network was resaturated to demonstrate the ability to self-seal of the COx claystone without mechanical loading by conducting from 11 to 15 repetitive hydraulic tests with monitoring of the hydraulic parameters. During this hydration process, the EDZ effective transmissivity dropped due to the swelling of the clay materials near the fracture network. The hydraulic conductivity evolution was relatively fast during the first few days. Low conductivities ranging at 10-10 m/s were observed after four months. Conversely, the specific storage showed an erratic evolution during the first phase of hydration (up to 60 days). Some uncertainty remains on this parameter due to volumetric strain during the

  8. Diffusion of inorganic chemical wastes in compacted clay

    Energy Technology Data Exchange (ETDEWEB)

    Shackelford, C.D.


    The factors that were investigated included the water content/dry unit weight, the method of compaction, the mineralogy of the soil, and the concentration of the ions. The effective diffusion coefficients (D{asterisk}) of three anions (Cl{sup {minus}}, Br{sup {minus}}, and I{sup {minus}}) and three cations (K{sup +}, Cd{sup 2+}, and Zn{sup 2+}) in a simulated waste leachate were measured. Two clay soils (kaolinite and Lufkin clay) and a sand were used in the study. The clay samples were compacted and pre-soaked to minimize hydraulic gradients due to negative pore pressures. Mass balance calculations were performed to indicate possible sinks/sources in the diffusion system. The results of the diffusion tests were analyzed using two analytical solutions to Fick's second law and a commercially available semi-analytical solution. The D{asterisk} values for tests using high-concentration (0.04 N) leachate generally fell in the narrow range of about 4.0 {times} 10{sup {minus}6} to 2.0 {times} 10{sup {minus}5} cm{sup 2}/s, and were relatively insensitive to compaction water content/dry unit weight and to compaction method. The variability in the results from the tests with low-concentration (0.013 N) leachate precluded any definite conclusions from these tests. The values of D{asterisk} measured in this study were compared to values from previous studies, and the D{asterisk} values from this study were found to be slightly conservative (i.e., high). However, the results of the tests may be affected by several chemical and physical factors, and care should be taken to ensure that the soils used in the tests are representative of those used in the application of the test results. Recommendations are made for estimating D{asterisk} values for use in the design of compacted clay barriers for the containment of inorganic chemical wastes.

  9. The action of water films at Å-scales in the Earth: Implications for the Nankai subduction system (United States)

    Brown, Kevin M.; Poeppe, Dean; Josh, Matthew; Sample, James; Even, Emilie; Saffer, Demian; Tobin, Harold; Hirose, Takehiro; Kulongoski, J. T.; Toczko, Sean; Maeda, Lena


    Water properties change with confinement within nanofilms trapped between natural charged clay particles. We investigated nanofilm characteristics through high-stress laboratory compression tests in combination with analyses of expelled pore fluids. We utilized sediments obtained from deep drilling of the Nankai subduction zone at Site C0002 of the Integrated Ocean Drilling Program (IODP). We show that below 1-2 km, there should be widespread ultrafiltration of migrating fluids. Experiments to > ∼ 100 MPa normal compression collapse pores below a few ion monofilm thicknesses. A reduction towards a single condensing/dehydrating ion monofilm occurs as stresses rise >100-200 MPa and clay separations are reduced to water or the deep biosphere. The resulting semipermeable properties result in variable segregation of ions and charged isotopes and water during active flow. The ultrafiltration and ion dehydration processes are coupled in that both require the partial immobilization of ions between the charged clay surfaces. The general effect is to increase salinities in residual pore fluids at depth and freshen fluids expelled during consolidation. Cessation of nanofilm collapse to a near constant ∼17 Å below 2 km depth at Nankai supports the contention for the onset of substantial geopressuring on the deeper seismogenic fault. The properties of monofilm water, thus, have considerable implications for the deep water properties of subduction zones generating major tremor and Mw 8+ earthquakes. Indeed, the combined effects of advective flow, ultrafiltration, diffusion, and diagenesis could provide a unifying explanation for the origins of overpressuring and pore water geochemical signals observed in many natural systems.

  10. Influência da qualidade da água de irrigação na dispersão da argila de Latossolos Irrigation water quality influence on clay dispersive behavior of Oxisols

    Directory of Open Access Journals (Sweden)

    Onofre Barroca de Almeida Neto


    , proporcionaram diminuição no teor de argila dispersa (ADA-S nos solos LV e LVd.The phenomenon of dispersion of soil clay can be caused by the quality of irrigation water. This study investigated the effect of irrigation water with different electric conductivities (EC, combined with different Sodium Adsorption Relation (SAR values on clay dispersion in soil commonly found in the state of Minas Gerais, with different mineralogies. The samples were collected from the B horizon of three soils (Oxisols in Viçosa, Belo Horizonte and Barroso, respectively, with high levels of the clay minerals kaolinite, hematite, and gibbsite, and are classified as Yellow-Red Latosol, Red Latosol and dystroferric Red Latosol. The physical, chemical, and mineralogical properties of the soils were characterized. The treatments corresponded to percolation, through the three soils, of NaCl and CaCl2 solutions with six different EC values (20; 50; 100; 200; 400, and 800 mS m-1 and five SAR values (0, 5, 10, 20, and 40 mmol c L-1, in a randomized block design with three replications. The solutions were applied in vertical column and constant load permeameters. The solution was applied until the EC of the effluent approached that in the applied solution (C/C0 = 1.0. To evaluate the effect of the solutions applied to the soil structure, the contents of clay dispersed in water (CDW were quantified. The values of CDW in the soil materials percolated with the different sodic-saline solutions (CDW-S were related to EC and SAR of the percolated solutiona. The soil behavior was distinct regardint clay dispersion, which was ascribed to its mineralogy as well as to the degree of weathering. The Yellow-Red Latosol showed a non-dispersive pattern in all treatments. In general, all percolation solutions, especially those with highest EC, regardless of the SAR value, indicated reduced dispersed clay (CDW-S in the Red Latosol and dystroferric Red Latosol.

  11. Prions, Radionuclides and Clays: Impact of clay interlayer "acidity" on toxic compound speciation (United States)

    Charlet, L.; Hureau, C.; Sobolev, O.; Cuello, G.; Chapron, Y.


    The physical and chemical processes that are the basis of contaminant retardation in clay rich medium, such as soil or nuclear waste repository, have been studied at the molecular level by a combination of molecular dynamics (MD), electron paramagnetic spectroscopy (EPR) and neutron diffraction with isotopic substitution (NDIS). The speciation of contaminants such as Sm, a radionuclide analogue, and Cu, bound to Prion protein (PrP), has been studied upon adsorption in clay interlayers. We used as molecular probe the P5-Cu(II) complex, where the P5 pentapeptide(92-96 PrP residues) represents one of the five Cu(II) binding site present in PrP, the key protein involved in diseases known as transmissible spongiform encephalopathies. In both cases, the pH of the interlayer has been inferred from the metal ion coordination, here used as a molecular reporter. In circum neutral pH waters, samarium is present as Sm(OH)3° species and should not be adsorbed in clay interlayer by "cation exchange" unless its hydrolysis is altered. Samarium NDIS results indicate that whether the number of oxygen nearest neighbours varies only from 8.5 to 7, as Sm penetrates the interlayer, the number of hydrogen nearest neighbours drops from 12 to 6. The high affinity of clay for Sm shows that a change in Sm hydrolysis occurs in the clay interlayer, but is directly followed by the formation of a surface complex with montmorillonite siloxane plane functional groups which prevents the determination of a "local pH". Conversely, has been found to be a much more sensitive interlayer water pH probe. and this peptide domain is involved in the misfolding of the protein,a transconformation which may lead to the pathogenic PrPSc form. We have therefore studied by EPR spectroscopy the adsorption of Cu(II)-P5 complexes on montmorillonite, and found the clay to have a large and selective adsorption capacity for the various [Cu(P5)H-n](2-n)+ complexes where n is the number of deprotonated amido function

  12. Induced polarization of clay-sand mixtures. Experiments and modelling. (United States)

    Okay, G.; Leroy, P.


    The complex conductivity of saturated unconsolidated sand-clay mixtures was experimentally investigated using two types of clay minerals, kaolinite and smectite (mainly Na-Montmorillonite) in the frequency range 1.4 mHz - 12 kHz. The experiments were performed with various clay contents (1, 5, 20, and 100 % in volume of the sand-clay mixture) and salinities (distilled water, 0.1 g/L, 1 g/L, and 10 g/L NaCl solution). Induced polarization measurements were performed with a cylindrical four-electrode sample-holder associated with a SIP-Fuchs II impedance meter and non-polarizing Cu/CuSO4 electrodes. The results illustrate the strong impact of the CEC of the clay minerals upon the complex conductivity. The quadrature conductivity increases steadily with the clay content. We observe that the dependence on frequency of the quadrature conductivity of sand-kaolinite mixtures is more important than for sand-bentonite mixtures. For both types of clay, the quadrature conductivity seems to be fairly independent on the pore fluid salinity except at very low clay contents. The experimental data show good agreement with predicted values given by our SIP model. This complex conductivity model considers the electrochemical polarization of the Stern layer coating the clay particles and the Maxwell-Wagner polarization. We use the differential effective medium theory to calculate the complex conductivity of the porous medium constituted of the grains and the electrolyte. The SIP model includes also the effect of the grain size distribution upon the complex conductivity spectra.

  13. Validation of a kinetic-diffusive model to characterize pozzolanic reaction kinetics in sugar cane straw-clay ash/lime systems

    Directory of Open Access Journals (Sweden)

    Villar-Cociña, E.


    Full Text Available A kinetic-diffusive model proposed by the authors in previous papers to describe pozzolanic reaction kinetics in sugar cane straw-clay ash (SCSCA/calcium hydroxide (CH systems is validated in this study. Two different methods (direct and indirect for determining pozzolanic activity were applied and their effect on pozzolanic reaction rate kinetic constants evaluated. Determined by fitting a model to the data, these constants are used to quantitatively characterize pozzolanic activity. The values of the kinetic constants calculated with the model were similar for the two methods. Classic kinetic models, such as the Jander, modified Jander and Zhuravlev models, were also applied to the system studied and the results were compared to the figures calculated with the model proposed. The kinetic-diffusive approach proposed was found to be valid regardless of the method for determining pozzolanic activity used, and to be the most suitable model for describing pozzolanic reaction kinetics in the SCSCA/lime system.

    Se valida la aplicación de un modelo cinético-difusivo propuesto por los autores en trabajos anteriores para describir la cinética de reacción puzolánica en sistemas ceniza de paja de caña-arcilla (CPCAñúdróxido de calcio (CH. Se aplican 2 métodos diferentes de actividad puzolánica (directo e indirecto y se valora el efecto que pudieran tener los mismos sobre las constantes cinéticas de velocidad de reacción de la reacción puzolánica. Estas constantes cinéticas son determinadas en el proceso de ajuste del modelo y permiten caracterizar cuantitativamente la actividad puzolánica. Los resultados muestran la similitud de las constantes cinéticas de velocidad de reacción calculadas, aplicando el modelo a los resultados experimentales obtenidos por ambos métodos. Además, fueron aplicados al sistema estudiado modelos cinéticos el chicos como: modelo de Jander, modelo de Jander Modificado y el modelo de Zhuravlev y

  14. Biologically-Inspired Water Propulsion System

    Institute of Scientific and Technical Information of China (English)

    Andrzej Sioma


    Most propulsion systems of vehicles travelling in the aquatic environment are equipped with propellers.Observations of nature,however,show that the absolute majority of organisms travel through water using wave motion,paddling or using water jet power.Inspired by these observations of nature,an innovative propulsion system working in aquatic environment was developed.This paper presents the design of the water propulsion system.Particular attention was paid to the use of paddling techniques and water jet power.A group of organisms that use those mechanisms to travel through water was selected and analysed.The results of research were used in the design of a propulsion system modelled simultaneously on two methods of movement in the aquatic environment.A method for modelling a propulsion system using a combination of the two solutions and the result were described.A conceptual design and a prototype constructed based on the solution were presented.With respect to the solution developed,studies and analyses of selected parameters of the prototype were described.

  15. Elastic deformation behaviour of Palaeogene clay from Fehmarn Belt area

    DEFF Research Database (Denmark)

    Awadalkarim, Ahmed; Foged, Niels Nielsen; Fabricius, Ida Lykke


    clays. Elastic wave velocities are influenced by the elastic stiffness and the density of a material. We used geotechnical and elastic wave velocity data to model the elasticity and then to relate it to mineralogy and BET surface area. We measured the mineralogy, BET surface area, bulk density, porosity...... and of high to very high plasticity. Comprehensive and advanced laboratory tests were done by Fugro-McClelland (in Netherlands) and by Danish Geotechnical Institute (in Denmark) on Palaeogene clays. Some of their data are included in this study. Ten Palaeogene clay samples were selected and used in this study......, water content and saturation, elastic wave velocities, electrical resistivity and strain caused by mechanical loading. They were used together to interpret the geotechnical data. We aimed to see which physical property is a main controlling factor for the elasticity of the studied Palaeogene clay...

  16. Thermodynamically coupled mass transport processes in a saturated clay

    Energy Technology Data Exchange (ETDEWEB)

    Carnahan, C.L.


    Gradients of temperature, pressure, and fluid composition in saturated clays give rise to coupled transport processes (thermal and chemical osmosis, thermal diffusion, ultrafiltration) in addition to the direct processes (advection and diffusion). One-dimensional transport of water and a solute in a saturated clay subjected to mild gradients of temperature and pressure was simulated numerically. When full coupling was accounted for, volume flux (specific discharge) was controlled by thermal osmosis and chemical osmosis. The two coupled fluxes were oppositely directed, producing a point of stagnation within the clay column. Solute flows were dominated by diffusion, chemical osmosis, and thermal osmosis. Chemical osmosis produced a significant flux of solute directed against the gradient of solute concentration; this effect reduced solute concentrations relative to the case without coupling. Predictions of mass transport in clays at nuclear waste repositories could be significantly in error if coupled transport processes are not accounted for. 14 references, 8 figures, 1 table.

  17. Energy optimization of water distribution system

    Energy Technology Data Exchange (ETDEWEB)


    In order to analyze pump operating scenarios for the system with the computer model, information on existing pumping equipment and the distribution system was collected. The information includes the following: component description and design criteria for line booster stations, booster stations with reservoirs, and high lift pumps at the water treatment plants; daily operations data for 1988; annual reports from fiscal year 1987/1988 to fiscal year 1991/1992; and a 1985 calibrated KYPIPE computer model of DWSD`s water distribution system which included input data for the maximum hour and average day demands on the system for that year. This information has been used to produce the inventory database of the system and will be used to develop the computer program to analyze the system.

  18. Influence of Different Additives at Various Contents on the Properties of Pottery Clay Body

    Directory of Open Access Journals (Sweden)

    Kongdej LIMPAIBOON


    Full Text Available The preparation of clay body is a highly important step during the production of local decorative pottery, especially the local unglazed low-fired terracotta. In this study, sand (size < 178 mm and Bulrush pulp were employed as an additive blended with clay (size < 125 mm in the preparation of clay body. Various sand contents (2 - 18 wt% and pulp contents (1 - 14 wt% were tested. The properties of each clay body were evaluated in terms of shrinkage, water absorption and modulus of rupture. The results obtained showed that higher sand or pulp content gave higher water absorption and lower shrinkage of clay body. The dried MOR value of pulp-clay body was much higher than that of sand-clay body at the same content. The maximum fired MOR value of sand-clay body (84.51 kgf/cm2 at sand content of 2 wt% was a little higher than that of pulp-clay body (80.44 kgf/cm2 at pulp content of 4 wt%. However, at a sand content ranging between 2 and 14 % or a pulp content ranging between 1 and 5 %, the fired MOR values of clay bodies were enhanced above that of local pottery clay body (60.14 kgf/cm2. From these results the pulp could adequately be used as an additive as well. Finally, a suitable sand or pulp content for producing smooth clay bodies was between 2 and 14 wt% or between 1 and 4 wt%, respectively, due to clay bodies obtained having more smooth texture and higher strength than local pottery clay body.

  19. Guidelines for transient analysis in water transmission and distribution systems


    Pothof, Ivo; Karney, Bryan


    All water systems leak, and many supply systems do so considerably, with water losses typically of approximately 20% of the water production. The IWA Water Loss Task Force aims for a significant reduction of annual water losses by drafting documents to assist practitioners and others to prevent, monitor and mitigate water losses in water transmission and distribution systems. One of the causes of water losses are transient phenomena, caused by normal and accidental pump and valve operations. ...

  20. Preparation and characterization of biodegradable PLA/organosilylated clay nanocomposites (United States)

    Olivieri, R.; Di Maio, L.; Scarfato, P.; Incarnato, L.


    In this work a new organosilylated clay was successfully synthesized by functionalization of a natural sodium montmorillonite (MMT) by (3-glycidyloxypropyl)trimethoxysilane (GOPTMS). This organosilylated clay was used as nanofiller for preparation, by solvent casting, of poly(lactic acid) nanocomposite systems. Similar systems, containing as nanofiller the commercial Cloisite 30B (i.e. a natural sodium montmorillonite organically modified with alkylammonium salt), were also prepared for comparison. All the obtained nanocomposite films were characterized using several techniques (XRD, permeability and mechanical tensile tests). Obtained results pointed out that nanocomposite system containing the organosilylated clay showed a better intercalation of the polymer chains into the clay layers and a higher improvement of the oxygen barrier properties, when compared to both the neat PLA film and the PLA film loaded with Cloisite 30B.

  1. Characteristics of Trihalomethanes in Water Distribution System

    Institute of Scientific and Technical Information of China (English)

    ZHAO Ming; ZHANG Jie; ZHANG Xin-yu; ZHENG Shuang-ying; LI Xin


    To investigate the characteristics of disinfection by-products (DBPs) in an actual water distribution system using the raw water with high bromide ion concentration, the composition and concentration of trihalomethanes (THMs) formed by chlorination of the water in the presence of bromide ion were measured in a city water distribution system during one year. The results show that brominated THMs contributed a great part (83%89%) to the index for additive toxicity (ATI) and resulted in the ATI of most of the samples exceeding WHO guideline standard for total THMs (TTHMs), especially during the summer (rainy season). This indicates that the chlorination of water in the presence of bromide ion leaded to high ratios of brominated THMs to TTHMs. However, a visible increase in the concentration of THMs with increasing residence time in the distribution system was not observed. Additionally, based on alternatives analysis, packed tower aeration method is proposed to reduce THMs level of the finished water leaving the treatment plant.

  2. An Experimental Study on the Secondary Deformation of Boom Clay



    International audience; Boom clay formation, a deposit of slightly over-consolidated marine clay that belongs to the Oligocene series in the north east of Belgium, has been selected as a possible host material of nuclear waste disposal. In this context, the long-term deformation behaviour of Boom clay is of crucial importance in the performance assessment of the whole storage system. In this study, low and high pressure oedometer tests are carried out; the e-log σ'v (void ratio - logarithm of...

  3. Fluoride retention by kaolin clay

    DEFF Research Database (Denmark)

    Kau, P. M. H.; Smith, D. W.; Binning, Philip John


    To evaluate the potential effectiveness of kaolin clay liners in storage of fluoride contaminated waste, an experimental study of the sorption and desorption behaviour of fluoride in kaolin clay was conducted. The degree of fluoride sorption by kaolin was found to depend on solution p......H and available fluoride concentration with equilibrium being achieved within 24 h. A site activation process involving the uptake of fluoride was also observed at the initial stages of sorption. This behaviour was attributed to a layer expansion process of the clay during sorption. The maximum fluoride sorption...

  4. Air-water flow in subsurface systems (United States)

    Hansen, A.; Mishra, P.


    Groundwater traces its roots to tackle challenges of safe and reliable drinking water and food production. When the groundwater level rises, air pressure in the unsaturated Vadose zone increases, forcing air to escape from the ground surface. Abnormally high and low subsurface air pressure can be generated when the groundwater system, rainfall, and sea level fluctuation are favorably combined [Jiao and Li, 2004]. Through this process, contamination in the form of volatile gases may diffuse from the ground surface into residential areas, or possibly move into groundwater from industrial waste sites. It is therefore crucial to understand the combined effects of air-water flow in groundwater system. Here we investigate theoretically and experimentally the effects of air and water flow in groundwater system.

  5. AOIPS water resources data management system (United States)

    Merritt, E. S.; Shotwell, R. L.; Place, M. C.; Belknap, N. J.


    A geocoded data management system applicable for hydrological applications was designed to demonstrate the utility of the Atmospheric and Oceanographic Information Processing System (AOIPS) for hydrological applications. Within that context, the geocoded hydrology data management system was designed to take advantage of the interactive capability of the AOIPS hardware. Portions of the Water Resource Data Management System which best demonstrate the interactive nature of the hydrology data management system were implemented on the AOIPS. A hydrological case study was prepared using all data supplied for the Bear River watershed located in northwest Utah, southeast Idaho, and western Wyoming.

  6. Global resilience analysis of water distribution systems. (United States)

    Diao, Kegong; Sweetapple, Chris; Farmani, Raziyeh; Fu, Guangtao; Ward, Sarah; Butler, David


    Evaluating and enhancing resilience in water infrastructure is a crucial step towards more sustainable urban water management. As a prerequisite to enhancing resilience, a detailed understanding is required of the inherent resilience of the underlying system. Differing from traditional risk analysis, here we propose a global resilience analysis (GRA) approach that shifts the objective from analysing multiple and unknown threats to analysing the more identifiable and measurable system responses to extreme conditions, i.e. potential failure modes. GRA aims to evaluate a system's resilience to a possible failure mode regardless of the causal threat(s) (known or unknown, external or internal). The method is applied to test the resilience of four water distribution systems (WDSs) with various features to three typical failure modes (pipe failure, excess demand, and substance intrusion). The study reveals GRA provides an overview of a water system's resilience to various failure modes. For each failure mode, it identifies the range of corresponding failure impacts and reveals extreme scenarios (e.g. the complete loss of water supply with only 5% pipe failure, or still meeting 80% of demand despite over 70% of pipes failing). GRA also reveals that increased resilience to one failure mode may decrease resilience to another and increasing system capacity may delay the system's recovery in some situations. It is also shown that selecting an appropriate level of detail for hydraulic models is of great importance in resilience analysis. The method can be used as a comprehensive diagnostic framework to evaluate a range of interventions for improving system resilience in future studies.

  7. Study on Water Migration in Laboratory Test in the Freezing Process of Frozen Silty Clay by Manual Work%人工冻结粉质粘土正冻过程中水分迁移室内试验研究

    Institute of Scientific and Technical Information of China (English)

    何菲; 王旭


    For the purpose of studying water migration rule and temperature distribution character of silty clay,use one-way freezing water migration tester and low-temperature test chamber to conduct test for one-way freezing water migration indoor of Lanzhou silty clay.The test soil sample used man-made Lanzhou loess,which liquid limit is 33% and plastic limit 19.5%.The diameter of sample is 10 cm,the height 21 cm;the initial water content is 13.4%,18.1% and 24.6%,dry density is 1.27 g/cm3 ,1.40 g/cm3 and 1 .5 3 g/cm3 ,the different temperature difference 7 ℃,9 ℃ and 1 1 ℃.We conduct 7 test works under different boundary conditions,testing one-way freezing water migration and temperature distribution prop-erty of sample in close system.The result shows that,in some range,the inside wall exists crack which has ice lenticle.The freezing temperature difference has obvious effect on freezing depth of sample,and the big-ger the difference,the more water migration amount.As far as ice (water)content peak,when the differ-ence is little,the peak is big.The water migration amount is obvious and peak of ice (water)content is big when dry density is low.When initial water content is less than liquid limit,the more water migration,the higher the initial water content.%为研究粉质粘土在冻结过程中水分迁移规律及温度分布特性,采用单向冻结水分迁移试验仪及低温试验箱,对兰州粉质粘土进行了室内单向冻结水分迁移试验.试验土样采用人工制备兰州黄土,液限33.0%、塑限19.5%.试样直径为10 cm、高度21 cm;试样的初始含水率分别为13.4%、18.1%、24.6%,干密度分别为1.27 g/cm3、1.40 g/cm3、1.53 g/cm3,不同温度差为7℃、9℃、11℃.在不同边界条件下进行了7组试验工作,测试了试样在封闭系统中单向冻结水分迁移及温度分布特性.试验结果表明,试样一定范围内侧壁存在裂缝,裂缝处存在冰透镜体.冻结温度差对试样

  8. Element exchange in a water-and gas-closed biological life support system (United States)

    Gribovskaya, I. V.; Kudenko, Yu. A.; Gitelson, J. I.


    Liquid human wastes and household water used for nutrition of wheat made possible to realize 24% closure for the mineral exchange in an experiment with a 2-component version of ``Bios-3'' life support system (LSS) Input-output balances of revealed, that elements (primarily trace elements) within the system. The structural materials (steel, titanium), expanded clay aggregate, and catalytic furnace catalysts. By the end of experiment, the permanent nutrient solution, plants, and the human diet gradually built up Ni, Cr, Al, Fe, V, Zn, Cu, and Mo. Thorough selection and pretreatment of materials can substantially reduce this accumulation. To enhance closure of the mineral exchange involves processing of human- metabolic wastes and inedible biomes inside LSS. An efficient method to oxidize wastes by hydrogen peroxide in a quartz reactor at the temperature of 80 degC controlled electromagnetic field is proposed.

  9. Clays and Clay Minerals and their environmental application in Food Technology (United States)

    del Hoyo Martínez, Carmen; Cuéllar Antequera, Jorge; Sánchez Escribano, Vicente; Solange Lozano García, Marina; Cutillas Díez, Raul


    The clay materials have led to numerous applications in the field of public health (del Hoyo, 2007; Volzone, 2007) having been demonstrated its effectiveness as adsorbents of all contaminants. Some biodegradable materials are used for for adsorption of chemical contaminants: lignins (Valderrabano et al., 2008) and also clays and clay minerals, whose colloidal properties, ease of generating structural changes, abundance in nature, and low cost make them very suitable for this kind of applications. Among the strategies used at present to preserve the quality of the water and this way to diminish the environmental risk that supposes the chemical pollution, stands out the use of adsorbents of under cost, already they are natural or modified, to immobilize these compounds and to avoid the pollution of the water with the consequent reduction of environmental and economic costs Thanks to the development of the science and the technology of the nourishment in the last 50 years, there have revealed itself several new substances that can fulfill beneficial functions in the food, and these substances, named food additives, are today within reach of all. The food additives recover a very important role in the complex nourishing supply. The additives fulfill several useful functions in the food, which often we give for sat. Nevertheless the widespread use of food additives in the food production also influences the public health. The food industries, which are very important for the economy, spill residues proved from its activity that they have to be controlled to evaluate the environmental impact and to offer the necessary information about the quantitative evaluation of the chemical risk of the use of food additives for the public health. We have studied the adsorption of several contaminants by natural or modified clays, searching their interaction mechanisms and the possible recycling of these materials for environmental purposes and prevention of the health. References

  10. Constitutive model for overconsolidated clays

    Institute of Scientific and Technical Information of China (English)


    Based on the relationships between the Hvorslev envelope,the current yield sur-face and the reference yield surface,a new constitutive model for overconsolidated clays is proposed. It adopts the unified hardening parameter,to which the potential failure stress ratio and the characteristic state stress ratio are introduced. The model can describe many characteristics of overconsolidated clays,including stress-strain relationships,strain hardening and softening,stress dilatancy,and stress path dependency. Compared with the Cam-clay model,the model only re-quires one additional soil parameter which is the slope of the Hvorslev envelope. Comparisons with data from triaxial drained compression tests for Fujinomori clay show that the proposed model can rationally describe overconsolidated properties. In addition,the model is also used to predict the stress-strain relationship in the isotropic consolidation condition and the stress paths in the undrained triaxial compression tests.

  11. Colloidal gels: Clay goes patchy (United States)

    Kegel, Willem K.; Lekkerkerker, Henk N. W.


    Empty liquids and equilibrium gels have so far been only theoretical possibilities, predicted for colloids with patchy interactions. But evidence of both has now been found in Laponite, a widely studied clay.

  12. Wash water waste pretreatment system study (United States)


    The use of real wash water had no adverse effect on soap removal when an Olive Leaf soap based system was used; 96 percent of the soap was removed using ferric chloride. Numerous chemical agents were evaluated as antifoams for synthetic wash water. Wash water surfactants used included Olive Leaf Soap, Ivory Soap, Neutrogena and Neutrogena Rain Bath Gel, Alipal CO-436, Aerosol 18, Miranol JEM, Palmeto, and Aerosol MA-80. For each type of soapy wash water evaluated, at least one antifoam capable of causing nonpersistent foam was identified. In general, the silicones and the heavy metal ions (i.e., ferric, aluminum, etc.) were the most effective antifoams. Required dosage was in the range of 50 to 200 ppm.

  13. Carbonate cementation as related to the diagenesis of clay in a mixed siliciclastic-carbonate system: Examples from the Centerfield biostrome, east central Pennsylvania

    Energy Technology Data Exchange (ETDEWEB)

    Burns, C.D. (Univ. of North Carolina, Chapel Hill, NC (United States))


    The Middle Devonian Mahantango Formation consists of siliciclastic and mixed carbonate-siliciclastic sediment packages that pulse in and out of the stratigraphy. The formation crops out in several places throughout the folded rocks of eastern Pennsylvania and Maryland. The Centerfield Member is one of the mixed siliciclastic-carbonate packages in the Mahantango Fm. This member crops out in east central Pennsylvania. The Centerfield Mbr. has been interpreted as a series of biostromes and contain abundant rugosan corals, crinoids, bryozoans, and brachiopods. The biostromes have undergone a complex diagenetic history. Illite, smectite, chlorite and muscovite have been found with the use of powder x-ray diffraction and petrographic analysis. The smectite and some of the illite are depositional clays, while, the remaining illite, chlorite and muscovite represent recrystallization of the depositional clays. There are six phases of cement in the biostrome. The paragenetic sequence of the cements is as follows: non-ferroan low magnesian calcite (LMC), intermediate ferroan LMC, ferroan LMC, non-ferroan dolomite, ferroan baroque dolomite, and quartz cement in the form of chert and blocky cement. Staining shows that the iron content of the cement changes within individual crystals and between cement phases. Preliminary data suggest that the cements may be directly related to the steady release of ions during the diagenesis of the surrounding clays in the shale.

  14. Porosity Investigation of Kosova's Clay


    Makfire Sadiku; Naim Hasani; Altin Mele


    Problem statement: Acid activated clay minerals are used as catalysts in the desulphurization of crude oil or as catalyst carrier, as drilling mud, as bleaching earth. Approach: The efficiency of the acid activation can be described in two ways. As increase of the surface and as increase of the cumulative pore volume after the activation. Results: In different samples of the clay mineral the activation was done with different sulfuric acid concentrations for two and 3h. Afterwards the specifi...

  15. Clays in radioactive waste disposal


    Delage, Pierre; Cui, Yu-Jun; Tang, Anh-Minh


    Clays and argillites are considered in some countries as possible host rocks for nuclear waste disposal at great depth. The use of compacted swelling clays as engineered barriers is also considered within the framework of the multi-barrier concept. In relation to these concepts, various research programs have been conducted to assess the thermo-hydro-mechanical properties of radioactive waste disposal at great depth. After introducing the concepts of waste isolation developed in Belgium, Fran...

  16. Modelling water uptake efficiency of root systems (United States)

    Leitner, Daniel; Tron, Stefania; Schröder, Natalie; Bodner, Gernot; Javaux, Mathieu; Vanderborght, Jan; Vereecken, Harry; Schnepf, Andrea


    Water uptake is crucial for plant productivity. Trait based breeding for more water efficient crops will enable a sustainable agricultural management under specific pedoclimatic conditions, and can increase drought resistance of plants. Mathematical modelling can be used to find suitable root system traits for better water uptake efficiency defined as amount of water taken up per unit of root biomass. This approach requires large simulation times and large number of simulation runs, since we test different root systems under different pedoclimatic conditions. In this work, we model water movement by the 1-dimensional Richards equation with the soil hydraulic properties described according to the van Genuchten model. Climatic conditions serve as the upper boundary condition. The root system grows during the simulation period and water uptake is calculated via a sink term (after Tron et al. 2015). The goal of this work is to compare different free software tools based on different numerical schemes to solve the model. We compare implementations using DUMUX (based on finite volumes), Hydrus 1D (based on finite elements), and a Matlab implementation of Van Dam, J. C., & Feddes 2000 (based on finite differences). We analyse the methods for accuracy, speed and flexibility. Using this model case study, we can clearly show the impact of various root system traits on water uptake efficiency. Furthermore, we can quantify frequent simplifications that are introduced in the modelling step like considering a static root system instead of a growing one, or considering a sink term based on root density instead of considering the full root hydraulic model (Javaux et al. 2008). References Tron, S., Bodner, G., Laio, F., Ridolfi, L., & Leitner, D. (2015). Can diversity in root architecture explain plant water use efficiency? A modeling study. Ecological modelling, 312, 200-210. Van Dam, J. C., & Feddes, R. A. (2000). Numerical simulation of infiltration, evaporation and shallow

  17. Permeability, Strength and Filtration Performance for Uncoated and Titania-Coated Clay Wastewater Filters


    Masturi; Silvia,, Minetti; Mahardika P. Aji; Euis Sustini; Khairurrijal; Mikrajuddin Abdullah


    Problem statement: Wastewater problems continue to be a relevant issue, particularly in urban areas. One promising low-cost material for manufacturing porous ceramics as water filter is clay. Clays can be blended with other materials such as polymers to obtain functional ceramic materials. Approach: Ceramic wastewater filters were fabricated from clay using both sol-gel and simple mixing methods followed by hot-pressing and calcination. Polyethylene Glycol (PEG) was used as a pore-forming age...

  18. Water Treatment Systems for Long Spaceflights (United States)

    FLynn, Michael T.


    Space exploration will require new life support systems to support the crew on journeys lasting from a few days to several weeks, or longer. These systems should also be designed to reduce the mass required to keep humans alive in space. Water accounts for about 80 percent of the daily mass intake required to keep a person alive. As a result, recycling water offers a high return on investment for space life support. Water recycling can also increase mission safety by providing an emergency supply of drinking water, where another supply is exhausted or contaminated. These technologies also increase safety by providing a lightweight backup to stored supplies, and they allow astronauts to meet daily drinking water requirements by recycling the water contained in their own urine. They also convert urine into concentrated brine that is biologically stable and nonthreatening, and can be safely stored onboard. This approach eliminates the need to have a dedicated vent to dump urine overboard. These needs are met by a system that provides a contaminant treatment pouch, referred to as a urine cell or contaminant cell, that converts urine or another liquid containing contaminants into a fortified drink, engineered to meet human hydration, electrolyte, and caloric requirements, using a variant of forward osmosis (FO) to draw water from a urine container into the concentrated fortified drink as part of a recycling stage. An activated carbon pretreatment removes most organic molecules. Salinity of the initial liquid mix (urine plus other) is synergistically used to enhance the precipitation of organic molecules so that activated carbon can remove most of the organics. A functional osmotic bag is then used to remove inorganic contaminants. If a contaminant is processed for which the saline content is different than optimal for precipitating organic molecules, the saline content of the liquid should be adjusted toward the optimal value for that contaminant. A first urine

  19. What makes a natural clay antibacterial? (United States)

    Williams, Lynda B.; Metge, David W.; Eberl, Dennis D.; Harvey, Ronald W.; Turner, Amanda G.; Prapaipong, Panjai; Port-Peterson, Amisha T.


    Natural clays have been used in ancient and modern medicine, but the mechanism(s) that make certain clays lethal against bacterial pathogens has not been identified. We have compared the depositional environments, mineralogies, and chemistries of clays that exhibit antibacterial effects on a broad spectrum of human pathogens including antibiotic resistant strains. Natural antibacterial clays contain nanoscale (2+ solubility.

  20. Efeito da incorporação de lodo de ETA contendo alto teor de ferro em cerâmica argilosa Effect of addition of high iron content sludge from water treatment plant on a clay-based ceramic

    Directory of Open Access Journals (Sweden)

    L. C. C. Paixão


    Full Text Available Foram investigados os efeitos da adição de um lodo de estação de tratamento de água nas características físicas e mecânicas de uma cerâmica preparada com massa argilosa (cerâmica vermelha. O lodo "bruto" apresentou partículas grossas e angulares (tamanho médio ~200 µm, elevado teor de ferro (73,0% Fe2O3 para 12,6% SiO2, 8,6% Al2O3, 5,2% CaO e predominância de composto com estrutura amorfa. O lodo calcinado a 1000 °C transformou-se principalmente nas fases hematita e magnetita e as partículas mantiveram a forma original. O lodo bruto foi adicionado em uma massa cerâmica industrial em frações de 0 (controle, 2, 5 e 10% em peso. Os corpos prensados foram sinterizados a 950, 1000 e 1050 °C em forno elétrico. A adição de lodo causou diminuição da resistência à flexão do corpo seco, devido à redução da retração linear de secagem. A temperatura máxima de sinterização da cerâmica com lodo, para a não ocorrência de retração linear excessiva, foi diminuída para ~1000 °C. Até esta temperatura, a incorporação do lodo pouco afetou a retração linear da cerâmica, mas aumentou a absorção de água e diminuiu a resistência à flexão. Os efeitos deletérios da incorporação do lodo foram associados à formação de microtrincas ao redor das partículas do lodo, que pouco interagiu com a matriz argilosa. A calcinação ou a cominuição do lodo possibilitou aumentar a resistência à flexão, pela diminuição da severidade das microtrincas.The effect of addition of sludge from water treatment plant on the physical and mechanical properties of a structural clay ceramic (red tile was investigated. Raw sludge presented large and angular particles (average size of ~200 µm with high iron content (73.0% Fe2O3, 12.6% SiO2, 8.6% Al2O3, 5.2% CaO, and predominantly amorphous structure. After heating at 1000 °C the sludge presented hematite and magnetite as predominant phases, and the particles remained with original

  1. Statistical mechanics of the shallow water system

    CERN Document Server

    Chavanis, P H


    We extend the formalism of the statistical theory developed for the 2D Euler equation to the case of shallow water system. Relaxation equations towards the maximum entropy state are proposed, which provide a parametrization of sub-grid scale eddies in 2D compressible turbulence.

  2. Standing Rock Rural Water System NPDES Permit (United States)

    Under NPDES permit SD-0030996, the Standing Rock Rural Water System is authorized to discharge from its wastewater treatment facility in Corson County, South Dakota, to an unnamed tributary to Fisher Creek, a tributary to Oahe Reservoir on the Missouri R.

  3. Probing water motion in heterogeneous systems.

    NARCIS (Netherlands)

    Dusschoten, van D.


    In this Thesis a practical approach is presented to study water mobility in heterogeneous systems by a number of novel NMR sequences. The major part of this Thesis describes how the reliability of diffusion measurements can be improved using some of the novel NMR sequences. The reliability of the da

  4. Adsorption of chloroacetanilide herbicides on soil and its components Ⅲ. Influence of clay acidity, humic acid coating and herbicide structure on acetanilide herbicide adsorption on homoionic clays

    Institute of Scientific and Technical Information of China (English)


    Adsorption of chloroacetanilide herbicides on homoionic montmorillonite, soil humic acid, and their mixtures was studied by coupling batch equilibration and FT-IR analysis. Adsorption isotherms of acetochlor, alachlor, metolachlor and propachlor on Ca2 + -, Mg2 + -. Al3 + -and Fe3 + -saturated clays were well described by the Freundlich equation. Regardless of the type of exchange cations, Kf decreased in the order of metolachlor > acetolachlor > alachlor > propachlor on the same clay. FT-IR spectra showed that the carbonyl group of the herbicide molecule was involved in binding, probably via H-bond with water molecules in the clay interlayer. The type and position of substitutions around the carbonyl group may have affected the electronegativity of oxygen, thus influencing the relative adsorption of these herbicides. For the same herbicide, adsorption on clay increased in the order of Mg2+ < Ca2+ < Al3+ ≤ Fe3+ which coincided with the iucreasing aciditv of homoionic clays. Acidity of cations may have affected the protonation of water, and thus the strength of H-bond between the clay water and herbicide. Complexation of clay and humic acid resulted in less adsorption than that expected from independent adsorption by the individual constituents. The effect varied with herbicides, but the greatest decrease in adsorption occurred at a 60:40 clay-to-humic acid ratio for all the herbicides. Causes for the decreased adsorption need to be characterized to better understand adsorption mechanisms and predict adsorption from soil compositions.

  5. Wave liquefaction in soils with clay content

    DEFF Research Database (Denmark)

    Kirca, Özgür; Sumer, B. Mutlu; Fredsøe, Jørgen


    The paper presents the results of an experimental study of the influence of clay content (in silt-clay and sand-clay mixtures) on liquefaction beneath progressive waves. The experiments showed that the influence of clay content is very significant. Susceptibility of silt to liquefaction...... is increased with increasing clay content, up to 30%, beyond which the mixture of silt and clay is not liquefied. Sand may become prone to liquefaction with the introduction of clay, contrary to the general perception that this type of sediment is normally liquefaction resistant under waves....

  6. Evaluate the action of polymeric additives in protect and recover water and bentonite clay based drilling fluids contaminated by degradation agents; Analise da acao de aditivos polimericos na protecao e recuperacao de fluidos de perfuracao base agua e bentonita contaminados por sais

    Energy Technology Data Exchange (ETDEWEB)

    Campos, L.F.A.; Ferreira, H.S.; Amorim, L.V.; Franca, K.B.; Ferreira, H.C. [Universidade Federal de Campina Grande (UFCG), PB (Brazil)


    The aim of this paper is study influences of electrolytes and cellulose polymers on rheological and water loss properties of dispersions of bentonite compositions. Evaluate the action of degradation additives CaSO{sub 4}, MgCl{sub 2} and CaCl{sub 2} and polymeric additives to protect and recover water and clay based. The results show a negative effect of degradation additives the rheological and water loss properties of drilling fluids. The cellulose polymers can be successfully applied to protect and recover of the rheological properties and water loss of the dispersions contaminated. (author)

  7. Regional aquifer geochemistry below the Boom Clay (NE-Belgium): data analysis and modelling (United States)

    Vandersteen, Katrijn; Leterme, Bertrand


    For more than 35 years, SCK•CEN has been investigating the possibility of high-level and/or long-lived radioactive waste disposal in the Boom Clay in NE-Belgium, including the study of the regional hydrogeology and geochemistry of the aquifer systems surrounding the Boom Clay. This study presents the analysis and modelling of groundwater geochemistry in the confined aquifers below the Boom Clay in NE-Belgium. This so-called deep aquifer system includes, with increasing depth, parts of the Oligocene Aquifer System, The Bartoon Aquitard System and the Ledo-Paniselian-Brusselian Aquifer System. At the end of the Neogene period, during which several marine transgressions and regressions took place, the sea definitely drew back after having deposited shallow marine and estuarine sands and some clay. The original seawater in the pores of the sediments was in first instance gradually diluted as the aquifer was flushed by recharge (fresh) water. Afterwards, water-rock interactions, including cation exchange, began to play a role in the deep aquifer system. This led to changes in groundwater composition over time. Geochemical data (major ions, stable isotopes, radioactive isotopes, dissolved gases) have been collected at a regional scale from the piezometric network in the deep aquifer system. Several measurement campaigns have been performed between 1980 and 2010. Groundwater is currently mainly of Na-HCO3 to Na-Cl type water, and because of the low groundwater velocity, re-equilibration with the host formations generally occurs. The main geochemical indicators (salinity, stable isotopes) point to a mixture between saline water (to the NW) and fresh recharge water (from SE). SE-NW gradients of ion concentrations are observed and can be explained in agreement with the pattern of natural groundwater flow. Building on the concepts emerging from the geochemical data analysis and recent groundwater modelling, a geochemical model was developed in PhreeqC, using geochemical and

  8. Modification of clay-based waste containment materials

    Energy Technology Data Exchange (ETDEWEB)

    Adu-Wusu, K. [DuPont Central Research and Development, Newark, DE (United States); Whang, J.M. [DuPont Specialty Chemicals, Deepwater, NJ (United States); McDevitt, M.F. [DuPont Central Research and Development, Wilmington, DE (United States)


    Bentonite clays are used extensively for waste containment barriers to help impede the flow of water in the subsurface because of their low permeability characteristics. However, they do little to prevent diffusion of contaminants, which is the major transport mechanism at low water flows. A more effective way of minimizing contaminant migration in the subsurface is to modify the bentonite clay with highly sorptive materials. Batch sorption studies were conducted to evaluate the sorptive capabilities of organo-clays and humic- and iron-based materials. These materials proved to be effective sorbents for the organic contaminants 1,2,4-trichlorobenzene, nitrobenzene, and aniline in water, humic acid, and methanol solution media. The sorption capacities were several orders of magnitude greater than that of unmodified bentonite clay. Modeling results indicate that with small amounts of these materials used as additives in clay barriers, contaminant flux through walls could be kept very small for 100 years or more. The cost of such levels of additives can be small compared to overall construction costs.

  9. Iron-rich clay minerals on Mars - Potential sources or sinks for hydrogen and indicators of hydrogen loss over time (United States)

    Burt, D. M.


    Although direct evidence is lacking, indirect evidence suggests that iron-rich clay minerals or poorly-ordered chemical equivalents are widespread on the Martian surface. Such clays can act as sources or sinks for hydrogen ('hydrogen sponges'). Ferrous clays can lose hydrogen and ferric clays gain it by the coupled substitution Fe(3+)O(Fe(2+)OH)-1, equivalent to minus atomic H. This 'oxy-clay' substitution involves only proton and electron migration through the crystal structure, and therefore occurs nondestructively and reversibly, at relatively low temperatures. The reversible, low-temperature nature of this reaction contrasts with the irreversible nature of destructive dehydroxylation (H2O loss) suffered by clays heated to high temperatures. In theory, metastable ferric oxy-clays formed by dehydrogenation of ferrous clays over geologic time could, if exposed to water vapor, extract the hydrogen from it, releasing oxygen.

  10. Adsorption of diethyl phthalate ester to clay minerals. (United States)

    Wu, Yanhua; Si, Youbin; Zhou, Dongmei; Gao, Juan


    Phthalate esters are a group of plasticizers, which have been widely detected in China's agricultural and industrial soils. In this study, batch adsorption experiments were conducted to investigate the environmental effects on the adsorption of diethyl phthalate ester (DEP) to clay minerals. The results showed that DEP adsorption isotherms were well fitted with the Freundlich model; the interlayer spacing of K(+) saturated montmorillonite (K-mont) was the most important adsorption area for DEP, and di-n-butyl ester (DnBP) was limited to intercalate into the interlayer of K-mont due to the bigger molecular size; there was no significant effect of pH and ionic strength on DEP adsorption to K-mont/Ca-mont, but to Na-mont clay. The adsorption to kaolinite was very limited. Data of X-ray diffraction and FTIR spectra further proved that DEP molecules could intercalate into K-/Ca-mont interlayer, and might interact with clay through H-bonding between carbonyl groups and clay adsorbed water. Coated humic acid on clay surface would enhance DEP adsorption at low concentration, but not at high concentration (eg. Ce>0.26 mM). The calculated adsorption enthalpy (ΔHobs) and adsorption isotherms at varied temperatures showed that DEP could be adsorbed easier as more adsorbed. This study implied that clay type, compound structure, exchangeable cation, soil organic matter and temperature played important roles in phthalate ester's transport in soil.

  11. 81 FR 31234 - NESHAP for Brick and Structural Clay Products Manufacturing; and NESHAP for Clay Ceramics... (United States)


    ... AGENCY NESHAP for Brick and Structural Clay Products Manufacturing; and NESHAP for Clay Ceramics... Brick and Structural Clay Products (BSCP) Manufacturing and the final NESHAP for Clay Ceramics... No. EPA-HQ-OAR-2013-0290 for Clay Ceramics Manufacturing. All documents in the dockets are listed...

  12. Effect of clays on the fire-retardant properties of a polyethylenic copolymer containing intumescent formulation

    Directory of Open Access Journals (Sweden)

    Simone P S Ribeiro et al


    Full Text Available Organophilic clay particles were added to a standard intumescent formulation and, since the role of clay expansion or intercalation is still a matter of much controversy, several clays with varying degrees of interlayer distances were evaluated. The composites were obtained by blending the nanostructured clay and the intumescent system with a polyethylenic copolymer. The flame-retardant properties of the materials were evaluated by the limiting oxygen index (LOI, the UL-94 rating and thermogravimetric analysis (TGA. The results showed that the addition of highly expanded clays to the ammonium polyphosphate and pentaerythritol formulation does not significantly increase the flame retardancy of the mixture, when measured by the LOI and UL-94. However, when clays with smaller basal distances were added to the intumescent formulation, a synergistic effect was observed. In contrast, the simple addition of clays to the copolymer, without the intumescent formulation, did not increase the fire retardance of the materials.

  13. Effect of clays on the fire-retardant properties of a polyethylenic copolymer containing intumescent formulation

    Energy Technology Data Exchange (ETDEWEB)

    Ribeiro, Simone P S; Nascimento, Regina S V [Instituto de Quimica-DQO, UFRJ, CT Bloco A, 60 andar, Cidade Universitaria, Rio de Janeiro, RJ, CEP: 21941-590 (Brazil); Estevao, Luciana R M [Agencia Nacional do Petroleo, Gas Natural e BiocombustIveis-ANP, SCM, Av. Rio Branco 65, 170 andar, Centro, Rio de Janeiro, RJ, CEP: 20090-004 (Brazil)], E-mail:


    Organophilic clay particles were added to a standard intumescent formulation and, since the role of clay expansion or intercalation is still a matter of much controversy, several clays with varying degrees of interlayer distances were evaluated. The composites were obtained by blending the nanostructured clay and the intumescent system with a polyethylenic copolymer. The flame-retardant properties of the materials were evaluated by the limiting oxygen index (LOI), the UL-94 rating and thermogravimetric analysis (TGA). The results showed that the addition of highly expanded clays to the ammonium polyphosphate and pentaerythritol formulation does not significantly increase the flame retardancy of the mixture, when measured by the LOI and UL-94. However, when clays with smaller basal distances were added to the intumescent formulation, a synergistic effect was observed. In contrast, the simple addition of clays to the copolymer, without the intumescent formulation, did not increase the fire retardance of the materials.

  14. Fixation of Selenium by Clay Minerals and Iron Oxides

    DEFF Research Database (Denmark)

    Hamdy, A. A.; Nielsen, Gunnar Gissel


    In studying Se fixation, soil components capable of retaining Se were investigated. The importance of Fe hydrous oxides in the fixation of Se was established. The clay minerals common to soils, such as kaolinite, montmorillonite and vermiculite, all exhibited Se fixation, but greater fixation...... occurred with the 1:1 than the 2:1 clay type. Experiments with finely ground minerals showed that the pH of the systems greatly influenced the rate of fixation, reaching a maximum between pH 3 and 5 and decreasing rapidly as the pH increased. With the Fe2O3 system fixed Se was slightly reduced as the p......H was increased to over 8. The extractability of Se from the clay minerals indicated that 1:1 clay type minerals fix selenite more indissolubly than 2:1 clays and that selenite was adsorbed on the clays mainly by a surface exchange reaction. The major part of the selenite added to the Fe2O3 system was found...

  15. Water delivery in the Early Solar System

    CERN Document Server

    Dvorak, Rudolf; Süli, Áron; Sándor, Zsolt; Galiazzo, Mattia; Pilat-Lohinger, Elke


    As part of the national scientific network 'Pathways to Habitable Worlds' the delivery of water onto terrestrial planets is a key question since water is essential for the development of life as we know it. After summarizing the state of the art we show some first results of the transport of water in the early Solar System for scattered main belt objects. Hereby we investigate the questions whether planetesimals and planetesimal fragments which have gained considerable inclination due to the strong dynamical interactions in the main belt region around 2 AU can be efficient water transporting vessels. The Hungaria asteroid group is the best example that such scenarios are realistic. Assuming that the gas giants and the terrestrial planets are already formed, we monitor the collisions of scattered small bodies containing water (in the order of a few percent) with the terrestrial planets. Thus we are able to give a first estimate concerning the respective contribution of such bodies to the actual water content i...

  16. Performance Evaluation and Field Application of Red Clay Green Roof Vegetation Blocks for Ecological Restoration Projects

    Directory of Open Access Journals (Sweden)

    Hwang-Hee Kim


    Full Text Available In this study, for restoration of ecological systems in buildings, porous vegetation red clay green roof blocks were designed for performance evaluation. Blast furnace slag (BFS; fine aggregates (agg., coarse aggregates, polyvinyl alcohol (PVA fiber (hydrophilic fiber, and red clay (ecofriendly additive material were applied to the construction of the porous vegetation red clay green roof blocks. A decrease in cement use is one way of reducing carbon emissions. To increase the water retentivity and the efficiency of roof vegetation blocks, blast furnace slag aggregates with excellent water absorptivity and polyvinyl alcohol fiber with a water absorption rate above 20% were added. In particular, the addition of polyvinyl alcohol fiber prevents performance reduction of the green roof vegetation blocks during freezing and melting in winter. Compressive strength, void ratio, and unit-mass tests were conducted to evaluate the performance of the roof vegetation blocks. After their application to roof vegetation, the effect of water purification was evaluated. According to the experimental results, the mix that satisfies the target performance of green roof vegetation blocks (compression strength above 8 MPa, void ratio above 20%, unit mass 2.0 kg/cm3 or below is: cement = 128.95 kg/m3, BFS = 96.75 kg/m3, red clay = 96.75 kg/m3, water = 81.50 kg/m3, BFS agg. = 1450 kg/m3, PVA fiber = 1.26 kg/m3. The green roof vegetation blocks were designed using the mix that satisfied the target performance. To find the amount of attainable water due to rainfall, a rainfall meter was installed after application of the roof vegetation to measure daily rainfall and calculate the amount of attainable water. The results show that, for 1 mm of rainfall, it is possible to attain about 0.53 L of water per 1 m2. In addition, the water quality of effluents after application of roof vegetation was analyzed, and the results satisfied Class 4 of the River-life Environmental

  17. Developing Sustainable Spacecraft Water Management Systems (United States)

    Thomas, Evan A.; Klaus, David M.


    It is well recognized that water handling systems used in a spacecraft are prone to failure caused by biofouling and mineral scaling, which can clog mechanical systems and degrade the performance of capillary-based technologies. Long duration spaceflight applications, such as extended stays at a Lunar Outpost or during a Mars transit mission, will increasingly benefit from hardware that is generally more robust and operationally sustainable overtime. This paper presents potential design and testing considerations for improving the reliability of water handling technologies for exploration spacecraft. Our application of interest is to devise a spacecraft wastewater management system wherein fouling can be accommodated by design attributes of the management hardware, rather than implementing some means of preventing its occurrence.

  18. Uranyl adsorption at clay mineral surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Roesch, N. [Technische Univ. Muenchen (Germany). Fachgebiet Theoretische Chemie


    This first systematic survey of actinide adsorption at complex clay mineral surfaces, which provided new insights at the atomic level, is currently being extended to neptunyl NpO{sub 2}{sup +} and more complex minerals, like iron-substituted phyllosilicates. In this way we examine if the concepts developed so far can be applied more generally to support the interpretation of pertinent experiments. A further facet of these studies is to account also for the dynamic nature of the mineral/water interface by means of exemplary dynamic simulations.

  19. A Benchmarking System for Domestic Water Use

    Directory of Open Access Journals (Sweden)

    Dexter V. L. Hunt


    Full Text Available The national demand for water in the UK is predicted to increase, exacerbated by a growing UK population, and home-grown demands for energy and food. When set against the context of overstretched existing supply sources vulnerable to droughts, particularly in increasingly dense city centres, the delicate balance of matching minimal demands with resource secure supplies becomes critical. When making changes to "internal" demands the role of technological efficiency and user behaviour cannot be ignored, yet existing benchmarking systems traditionally do not consider the latter. This paper investigates the practicalities of adopting a domestic benchmarking system (using a band rating that allows individual users to assess their current water use performance against what is possible. The benchmarking system allows users to achieve higher benchmarks through any approach that reduces water consumption. The sensitivity of water use benchmarks are investigated by making changes to user behaviour and technology. The impact of adopting localised supplies (i.e., Rainwater harvesting—RWH and Grey water—GW and including "external" gardening demands are investigated. This includes the impacts (in isolation and combination of the following: occupancy rates (1 to 4; roof size (12.5 m2 to 100 m2; garden size (25 m2 to 100 m2 and geographical location (North West, Midlands and South East, UK with yearly temporal effects (i.e., rainfall and temperature. Lessons learnt from analysis of the proposed benchmarking system are made throughout this paper, in particular its compatibility with the existing Code for Sustainable Homes (CSH accreditation system. Conclusions are subsequently drawn for the robustness of the proposed system.

  20. Army Energy and Water Reporting System Assessment

    Energy Technology Data Exchange (ETDEWEB)

    Deprez, Peggy C.; Giardinelli, Michael J.; Burke, John S.; Connell, Linda M.


    There are many areas of desired improvement for the Army Energy and Water Reporting System. The purpose of system is to serve as a data repository for collecting information from energy managers, which is then compiled into an annual energy report. This document summarizes reported shortcomings of the system and provides several alternative approaches for improving application usability and adding functionality. The U.S. Army has been using Army Energy and Water Reporting System (AEWRS) for many years to collect and compile energy data from installations for facilitating compliance with Federal and Department of Defense energy management program reporting requirements. In this analysis, staff from Pacific Northwest National Laboratory found that substantial opportunities exist to expand AEWRS functions to better assist the Army to effectively manage energy programs. Army leadership must decide if it wants to invest in expanding AEWRS capabilities as a web-based, enterprise-wide tool for improving the Army Energy and Water Management Program or simply maintaining a bottom-up reporting tool. This report looks at both improving system functionality from an operational perspective and increasing user-friendliness, but also as a tool for potential improvements to increase program effectiveness. The authors of this report recommend focusing on making the system easier for energy managers to input accurate data as the top priority for improving AEWRS. The next major focus of improvement would be improved reporting. The AEWRS user interface is dated and not user friendly, and a new system is recommended. While there are relatively minor improvements that could be made to the existing system to make it easier to use, significant improvements will be achieved with a user-friendly interface, new architecture, and a design that permits scalability and reliability. An expanded data set would naturally have need of additional requirements gathering and a focus on integrating

  1. Influence of clay content on wave-induced liquefaction

    DEFF Research Database (Denmark)

    Kirca, V.S. Ozgur; Sumer, B. Mutlu; Fredsøe, Jørgen


    of measurements were carried out: (1) pore-water pressure measurements across the soil depth and (2) water-surface elevation measurements. These measurements were synchronized with video recordings of the liquefaction process from the side. The ranges of the various quantities in the experiments were wave height......:17 mmwas partially liquefied with CC as small as 2.9%. Remarks are made as to how to check for liquefaction of clayey soils exposed to waves in real-life situations......This paper presents the results of an experimental study of the influence of clay content (CC) on liquefaction of seabed beneath progressive waves. Experiments were, for the most part, conducted with silt and silt-clay mixtures; in supplementary tests, sand-clay mixtures were used. Two types...

  2. Soil Water and Temperature System (SWATS) Handbook

    Energy Technology Data Exchange (ETDEWEB)

    Bond, D


    The soil water and temperature system (SWATS) provides vertical profiles of soil temperature, soil-water potential, and soil moisture as a function of depth below the ground surface at hourly intervals. The temperature profiles are measured directly by in situ sensors at the Central Facility and many of the extended facilities of the SGP climate research site. The soil-water potential and soil moisture profiles are derived from measurements of soil temperature rise in response to small inputs of heat. Atmospheric scientists use the data in climate models to determine boundary conditions and to estimate the surface energy flux. The data are also useful to hydrologists, soil scientists, and agricultural scientists for determining the state of the soil.

  3. Property and performance amelioration of pelagic clay from the East Pacific

    Institute of Scientific and Technical Information of China (English)

    Peiping ZHANG; Shufeng LIU; Xuefa SHI; Huahua LU; Juanjuan LIU; Xiaoguo CHI


    To make use of the pelagic clay as polymer filling, the properties of clay sediments from the ocean investigation zone of China in the East Pacific were studied by the SSA, XRF, ICP/MAS, FHR, XRD, SEM, DTA/TG and granularity distributing etc. , and experiments were settled to improve the whiteness and activation of the clay based on these data. Compared with land clay, pelagic clay holds many particular features, such as fine particles and incompact accumulation, worse crystallization and more defects, high activity, complex mineral and chemical components, and low whiteness etc. Processing the purified pelagic clay with acids and zinc, then baked it at different temperatures, the whiteness of clay can be increased from 23.8% to 73.1%, and the optimized conditions is : consistency of vitriol 25%, ratio of clay to water 4:1, reaction time 4h, reaction temperature 90℃, dosage of zinc 2.0 g/L, and baking temperature 700℃. And the SSA of whited clay is increased too. Using the dry milling method to modify the pelagic clay with organic reagents, the optimized technique is KH550, concentration 1.5%, reaction time 20 min. XRD,FTIR and SEM testing indicate that the mechanism of organic activation was mainly surface absorbing and chemical combination secondly.

  4. Synthesis and characterization of nanocomposites based on polyurethane in aqueous dispersions with non-modified hydrophilic clays; Sintese e caracterizacao de nanocompositos a base de poliuretanos em dispersoes aquosas com argilas hidrofilicas nao-modificadas

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, G.S.; Delpechi, M.C.; Santo, W.L.E., E-mail: mcd@uerj.b [Universidade do Estado do Rio de Janeiro (UERJ), RJ (Brazil)


    Several studies involving the formation of polyurethane nanocomposites employing clays of montmorillonite modified. This involves the presence of quaternary ammonium salts, the cation exchange needed to increase the interlayer space of clays that incorporate more than one step to the process, generates a higher cost. In this paper the synthesis of nanocomposite polyurethanes dispersed in water allowed not only the production of materials less harmful to the environment, but also the incorporation of hydrophilic clays, calcium and sodium in nature, without any modifications. Dispersions produced from 0.5, 1.0 and 2.5% clay (on the mass of prepolymer) were characterized in terms of total solids content, the films obtained by casting were evaluated for adhesiveness, diffraction X-rays, scanning electron microscopy. Most systems showed intercalated and partially exfoliated structures. (author)

  5. Guidelines for transient analysis in water transmission and distribution systems

    NARCIS (Netherlands)

    Pothof, I.W.M.; Karney, B.W.


    All water systems leak, and many supply systems do so considerably, with water losses typically of approximately 20% of the water production. The IWA Water Loss Task Force aims for a significant reduction of annual water losses by drafting documents to assist practitioners and others to prevent, mon

  6. In situ interaction between different concretes and Opalinus Clay (United States)

    Jenni, A.; Mäder, U.; Lerouge, C.; Gaboreau, S.; Schwyn, B.

    Interactions between cementitious materials and claystone are driven by chemical gradients in pore water and might lead to mineralogical modifications in both materials. In the context of a radioactive waste repository, this alteration might influence safety-relevant clay properties like swelling pressure, permeability, or specific retention. In this study, interfaces of Opalinus Clay, a potential host-rock in Switzerland, and three concrete formulations emplaced in the Cement-Clay Interaction (CI) Experiment at the Mont Terri Underground Laboratory (St. Ursanne, Switzerland) were analysed after 2.2 years of interaction. Sampling techniques with interface stabilisation followed by inclined intersection drilling were developed. Element distribution maps of the concrete-clay interfaces show complex zonations like sulphur enrichment, zones depleted in Ca but enriched in Mg, strong Mg enrichment adjacent to the interface, or carbonation. Consistently, the carbonated zone shows a reduced porosity. Properties of the complex zonation strongly depend on cement properties like water content and pH (ordinary Portland cement vs. low-pH cement). An increased Ca or Mg content in the first 100 μm next to the interface is observed in Opalinus Clay. The cation occupancy of clay exchanger phases next to the ordinary Portland cement interface is depleted in Mg, but enriched in Na, whereas porosity shows no changes at all. The current data suggests migration of CO2/HCO3-, SO42-, and Mg species from clay into cement. pH decrease in the cement next to the interface leads to instability of ettringite, and the sulphate liberated diffuses towards higher pH regions (away from the interface), where additional ettringite can form.

  7. Biofouling and biocorrosion in industrial water systems. (United States)

    Coetser, S E; Cloete, T E


    Corrosion associated with microorganisms has been recognized for over 50 years and yet the study of microbiologically influenced corrosion (MIC) is relatively new. MIC can occur in diverse environments and is not limited to aqueous corrosion under submerged conditions, but also takes place in humid atmospheres. Biofouling of industrial water systems is the phenomenon whereby surfaces in contact with water are colonized by microorganisms, which are ubiquitous in our environment. However, the economic implications of biofouling in industrial water systems are much greater than many people realize. In a survey conducted by the National Association of Corrosion Engineers of the United States ten years ago, it was found that many corrosion engineer did not accept the role of bacteria in corrosion, and many of then that did, could not recognize and mitigate the problem. Biofouling can be described in terms of its effects on processes and products such as material degradation (bio-corossion), product contamination, mechanical blockages, and impedance of heat transfer. Microorganisms distinguish themselves from other industrial water contaminants by their ability to utilize available nutrient sources, reproduce, and generate intra- and extracellular organic and inorganic substances in water. A sound understanding of the molecular and physiological activities of the microorganisms involved is necessary before strategies for the long term control of biofouling can be format. Traditional water treatment strategies however, have largely failed to address those factors that promote biofouling activities and lead to biocorrosion. Some of the major developments in recent years have been a redefinition of biofilm architecture and the realization that MIC of metals can be best understood as biomineralization.

  8. Charm of Purple Clay A private museum in Wuxi is devoted to purple-clay art

    Institute of Scientific and Technical Information of China (English)


    Purple-clay art pieces will be on display in a museum opening soon in Wuxi, Jiangsu Province. The museum, named Shuaiyuan Purple Clay Museum, is part of the Shuaiyuan Purple Clay Art Exhibition Center

  9. Geotechnical variability of permafrozen glaciomarine clays in Sdr. Strømfjord in Greenland

    DEFF Research Database (Denmark)

    Foged, Niels Nielsen; Ingeman-Nielsen, Thomas; Belmonte, Louise Josefine


    -going in the area at Strømfjordshavn. The C14 datings of marine shells collected on the marine clay terraces at level 300kPa. Clay minerals were weathered causing moderate to high activity and plasticity despite the formation age of only 7000 years. (b) The "River Bank Erosion Cut" 2 km east of the Airport Terminal....... We studied a frozen marine clay deposit at +35 m with stratified ice layers under sandy gravel top layer. During laboratory analysis using fall cone testing a thawed clay sample was found to be quick (St>700) due to dilution of pore water salts. Multidisciplinary approach was necessary for this study....

  10. Prediction of Settlements of Soft Clay Subjected to Long-Term Dynamic Load

    Institute of Scientific and Technical Information of China (English)


    -Presented is the numerical analysis of settlements of soft soil by a 2-D dynamic effective stress FEM method. The model based on the results of cyclic triaxial tests on the reconstituted soft Ariake clay is used to predict the wave induced excess pore water pressure and residual strain of soft clay. The settlements of two types of breakwaters on the soft clay under ocean wave load, a low embankment subjected to traffic load and the tunnel surrounded by soft clay in Shanghai subjected to locomotive load are calculated as examples.

  11. Material Composition and Engineering Characteristics of Red Clay in Guigang,Guangxi

    Institute of Scientific and Technical Information of China (English)

    Xiao Minggui; Wang Jieguang; Chen Xuejun


    There is fine and uniform clay with aluminous and ferrous cementation in the red clay found in Guigang, Guangxi. It has the characteristics of shrinkage outwardly, rigid upper but soft lower and well-grown fissure. In addition there are engineering characteristics such as high water content, low compactness and low compressibility, high strength and high contractility but slight expansibility. This paper discusses the red clay's engineering characteristics and its change regulation with depth by analyzing changes in the red clay's grain size composition, mineralogical constitution, and chemical composition.

  12. Development of polymer nanocomposites with regional bentonite clay; Desenvolvimento de nanocompositos polimericos com argila bentonitica regional

    Energy Technology Data Exchange (ETDEWEB)

    Araujo, Edcleide M.; Leite, Amanda M.D.; Paz, Rene A. da; Medeiros, Keila M. de; Melo, Tomas J.A., E-mail: [Unidade Academica de Engenharia de Materiais da UFCG, Campina Grande, PB (Brazil); Barbosa, Josiane D.V. [SENAI/CIMATEC, Salvador, BA (Brazil); Barbosa, Renata [Universidade Federal do Piaui, UFPI, Teresina, PI (Brazil)


    nanocomposites with regional bentonite clay were prepared by melt intercalation technique. The clays were studied without modification and modified with four quaternary ammonium salts. It was evidenced by X-ray diffraction that salts were incorporated into the clay structure thus confirming its organophilization. The nanocomposites were evaluated by means of thermal mechanic and flammability tests where presented properties significantly improved their pure polymers. The process of biodegradation of obtained bio nanocomposites was accelerated by the presence of clay. The produced membranes from nanocomposites have potential in the oil-water separation. (author)

  13. Role of bentonite clays on cell growth. (United States)

    Cervini-Silva, Javiera; Ramírez-Apan, María Teresa; Kaufhold, Stephan; Ufer, Kristian; Palacios, Eduardo; Montoya, Ascención


    Bentonites, naturally occurring clays, are produced industrially because of their adsorbent capacity but little is known about their effects on human health. This manuscript reports on the effect of bentonites on cell growth behaviour. Bentonites collected from India (Bent-India), Hungary (Bent-Hungary), Argentina (Bent-Argentina), and Indonesia (Bent-Indonesia) were studied. All four bentonites were screened in-vitro against two human cancer cell lines [U251 (central nervous system, glioblastoma) and SKLU-1 (lung adenocarcinoma)] supplied by the National Cancer Institute (USA). Bentonites induced growth inhibition in the presence of U251 cells, and growth increment in the presence of SKLU-1 cells, showing that interactions between bentonite and cell surfaces were highly specific. The proliferation response for U251 cells was explained because clay surfaces controlled the levels of metabolic growth components, thereby inhibiting the development of high-grade gliomas, particularly primary glioblastomas. On the other hand, the proliferation response for SKLU-1 was explained by an exacerbated growth favoured by swelling, and concomitant accumulation of solutes, and their hydration and transformation via clay-surface mediated reactions.

  14. Operational cost minimization in cooling water systems

    Directory of Open Access Journals (Sweden)

    Castro M.M.


    Full Text Available In this work, an optimization model that considers thermal and hydraulic interactions is developed for a cooling water system. It is a closed loop consisting of a cooling tower unit, circulation pump, blower and heat exchanger-pipe network. Aside from process disturbances, climatic fluctuations are considered. Model constraints include relations concerning tower performance, air flowrate requirement, make-up flowrate, circulating pump performance, heat load in each cooler, pressure drop constraints and climatic conditions. The objective function is operating cost minimization. Optimization variables are air flowrate, forced water withdrawal upstream the tower, and valve adjustment in each branch. It is found that the most significant operating cost is related to electricity. However, for cooled water temperatures lower than a specific target, there must be a forced withdrawal of circulating water and further makeup to enhance the cooling tower capacity. Additionally, the system is optimized along the months. The results corroborate the fact that the most important variable on cooling tower performance is not the air temperature itself, but its humidity.

  15. Controlling suction by vapour equilibrium technique at different temperatures, application to the determination of the water retention properties of MX80 clay

    CERN Document Server

    Tang, Anh-Minh


    Problems related to unsaturated soils are frequently encountered in geotechnical or environmental engineering works. In most cases, for the purpose of simplicity, the problems are studied by considering the suction effects on volume change or shear strength under isothermal conditions. Under isothermal condition, very often, a temperature independent water retention curve is considered in the analysis, which is obviously a simplification. When the temperature changes are too significant to be neglected, it is necessary to account for the thermal effects. In this paper, a method for controlling suction using the vapour equilibrium technique at different temperatures is presented. First, calibration of various saturated saline solutions was carried out from temperature of 20 degrees C to 60 degrees C. A mirror psychrometer was used for the measurement of relative humidity generated by saturated saline solutions at different temperatures. The results obtained are in good agreement with the data from the literatu...

  16. Modelling the thermo-mechanical volume change behaviour of compacted expansive clays

    CERN Document Server

    Tang, Anh-Minh; 10.1680/geot.2009.59.3.185


    Compacted expansive clays are often considered as a possible buffer material in high-level deep radioactive waste disposals. After the installation of waste canisters, the engineered clay barriers are subjected to thermo-hydro-mechanical actions in the form of water infiltration from the geological barrier, heat dissipation from the radioactive waste canisters, and stresses generated by clay swelling under almost confined conditions. The aim of the present work is to develop a constitutive model that is able to describe the behaviour of compacted expansive clays under these coupled thermo-hydro-mechanical actions. The proposed model is based on two existing models: one for the hydro-mechanical behaviour of compacted expansive clays and another for the thermo-mechanical behaviour of saturated clays. The elaborated model has been validated using the thermo-hydro-mechanical test results on the compacted MX80 bentonite. Comparison between the model prediction and the experimental data show that this model is able...

  17. Nafion–clay hybrids with a network structure

    KAUST Repository

    Burgaz, Engin


    Nafion-clay hybrid membranes with a unique microstructure were synthesized using a fundamentally new approach. The new approach is based on depletion aggregation of suspended particles - a well-known phenomenon in colloids. For certain concentrations of clay and polymer, addition of Nafion solution to clay suspensions in water leads to a gel. Using Cryo-TEM we show that the clay particles in the hybrid gels form a network structure with an average cell size in the order of 500 nm. The hybrid gels are subsequently cast to produce hybrid Nafion-clay membranes. Compared to pure Nafion the swelling of the hybrid membranes in water and methanol is dramatically reduced while their selectivity (ratio of conductivity over permeability) increases. The small decrease of ionic conductivity for the hybrid membranes is more than compensated by the large decrease in methanol permeability. Lastly the hybrid membranes are much stiffer and can withstand higher temperatures compared to pure Nafion. Both of these characteristics are highly desirable for use in fuel cell applications, since a) they will allow the use of a thinner membrane circumventing problems associated with the membrane resistance and b) enable high temperature applications. © 2009 Elsevier Ltd. All rights reserved.

  18. Simulation and model comparison of unsaturated movement of pesticides from a large clay lysimeter.

    NARCIS (Netherlands)

    Vink, J.P.M.; Gottesbüren, B.; Diekkrüger, B.; Zee, van der S.E.A.T.M.


    A long-term (>10 months) leaching experiment was conducted with a large clay soil column and a rain simulator to study unsaturated transport of the nematicide aldicarb and the herbicide simazine in a cracked clay soil. Water retention and soil conductivity were derived from experimental outflow data

  19. Magnitude, modeling and significance of swelling and shrinkage processes in clay soils.

    NARCIS (Netherlands)

    Bronswijk, J.J.B.


    The dynamic process of swelling and shrinkage in clay soils has significant practical consequences, such as the rapid transport of water and solutes via shrinkage cracks to the subsoil, and the destruction of buildings and roads on clay soils. In order to develop measuring methods and computer simul

  20. 21 CFR 1240.86 - Protection of pier water system. (United States)


    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Protection of pier water system. 1240.86 Section... DISEASES Source and Use of Potable Water § 1240.86 Protection of pier water system. No vessel engaged in interstate traffic shall make a connection between its nonpotable water system and any pier potable...

  1. 21 CFR 1250.82 - Potable water systems. (United States)


    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Potable water systems. 1250.82 Section 1250.82... SANITATION Sanitation Facilities and Conditions on Vessels § 1250.82 Potable water systems. The following conditions must be met by vessel water systems used for the storage and distribution of water which has...

  2. AlFe层柱粘土催化剂催化甲苯在水中的降解%Toluene Degradation in Water Using AlFe-Pillared Clay Catalysts

    Institute of Scientific and Technical Information of China (English)

    Predrag BANKOVI(C); Aleksandra MILUTINOVI(C)-NIKOLI(C); Zorica MOJOVI(C); Aleksandra ROSI(C); (Z)eljko (C)UPI(C); Davor LON(C)AREVI(C); Du(s)an JOVANOVI(C)


    The catalytic wet peroxide oxidation (CWPO) of toluene on two bentonite-based AlFe-pillared clays (PILCs) with different iron contents was investigated. The PILCs were obtained using bentonite clay from Bogovina, Serbia. The change in chemical and phase composition and textural properties of the starting clay and synthesized catalysts was monitored using X-ray diffraction, inductively coupled plasma optical emission spectrometry, UV-Vis diffuse reflectance spectrometry, and physisorption of nitrogen. The catalytic performance was examined using gas chromatography. The Na-exchange process lowered the (001) smectite basal plane spacing, but the clay retained its swelling properties, while the pillaring process increased it. The surface areas of both synthesized pillared clays increased to similar values although their Fe content was different. At 37 ℃, both catalysts show significant toluene degradation, with the one richer in Fe having higher efficiency. The leaching of the active cations during reaction was negligible, and the catalysts were stable. AlFe-pillared clay catalysts can be used in CWPO for the elimination of BTEX compounds from plant effluent streams.

  3. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hui-Hai; Rutqvist, Jonny; Zheng, Liange; Sonnenthal, Eric; Houseworth, Jim; Birkholzer, Jens


    example, the excavation-damaged zone (EDZ) near repository tunnels can modify local permeability (resulting from induced fractures), potentially leading to less confinement capability (Tsang et al., 2005). Because of clay's swelling and shrinkage behavior (depending on whether the clay is in imbibition or drainage processes), fracture properties in the EDZ are quite dynamic and evolve over time as hydromechanical conditions change. To understand and model the coupled processes and their impact on repository performance is critical for the defensible performance assessment of a clay repository. Within the Natural Barrier System (NBS) group of the Used Fuel Disposition (UFD) Campaign at DOE's Office of Nuclear Energy, LBNL's research activities have focused on understanding and modeling such coupled processes. LBNL provided a report in this April on literature survey of studies on coupled processes in clay repositories and identification of technical issues and knowledge gaps (Tsang et al., 2010). This report will document other LBNL research activities within the natural system work package, including the development of constitutive relationships for elastic deformation of clay rock (Section 2), a THM modeling study (Section 3) and a THC modeling study (Section 4). The purpose of the THM and THC modeling studies is to demonstrate the current modeling capabilities in dealing with coupled processes in a potential clay repository. In Section 5, we discuss potential future R&D work based on the identified knowledge gaps. The linkage between these activities and related FEPs is presented in Section 6.

  4. Diverless pipeline repair system for deep water

    Energy Technology Data Exchange (ETDEWEB)

    Spinelli, Carlo M. [Eni Gas and Power, Milan (Italy); Fabbri, Sergio; Bachetta, Giuseppe [Saipem/SES, Venice (Italy)


    SiRCoS (Sistema Riparazione Condotte Sottomarine) is a diverless pipeline repair system composed of a suite of tools to perform a reliable subsea pipeline repair intervention in deep and ultra deep water which has been on the ground of the long lasting experience of Eni and Saipem in designing, laying and operating deep water pipelines. The key element of SiRCoS is a Connection System comprising two end connectors and a repair spool piece to replace a damaged pipeline section. A Repair Clamp with elastomeric seals is also available for pipe local damages. The Connection System is based on pipe cold forging process, consisting in swaging the pipe inside connectors with suitable profile, by using high pressure seawater. Three swaging operations have to be performed to replace the damaged pipe length. This technology has been developed through extensive theoretical work and laboratory testing, ending in a Type Approval by DNV over pipe sizes ranging from 20 inches to 48 inches OD. A complete SiRCoS system has been realised for the Green Stream pipeline, thoroughly tested in workshop as well as in shallow water and is now ready, in the event of an emergency situation.The key functional requirements for the system are: diverless repair intervention and fully piggability after repair. Eni owns this technology and is now available to other operators under Repair Club arrangement providing stand-by repair services carried out by Saipem Energy Services. The paper gives a description of the main features of the Repair System as well as an insight into the technological developments on pipe cold forging reliability and long term duration evaluation. (author)

  5. Water barrier properties of starch-clay nanocomposite films Propriedades de barreira à água de filmes de nanocompósitos de amido e argila

    Directory of Open Access Journals (Sweden)

    Aníbal Marcelo Slavutsky


    Full Text Available The functional properties of corn starch based films were improved by incorporating nanoclay (Montmorillonite. Nanoclay was incorporated in the polymer matrix using two different methodologies and the films were formed by casting. The effect of film preparation methodology and of the nanoclay concentration on the physicochemical properties of the films was studied. Depending on film preparation method used, intercalated or exfoliated nanocomposite films were obtained. The FTIR spectra showed a strong interaction between the montmorillonite and the starch molecules. Opacity was dependent on the nanoclay dispersion method used. Water vapor solubility and permeability decreased with increasing montmorillonite content and were affected by the dispersion method. Water diffusion was only dependent on the nanoclay content due to the increase in tortuosity of the diffusion path, caused by the nanoparticles. The results showed that the incorporation of 5% of montmorillonite using an adequate dispersion method, improved the water resistance and barrier properties of corn starch based films. Nanoparticles reduced the damage caused to the properties of these hydrophilic films by the increase in moisture content.As propriedades funcionais de filmes à base de amido de milho foram melhoradas pela incorporação de nanoargila (montmorilonita. Nanoargila foi incorporada na matriz polimérica por meio de duas metodologias diferentes e os filmes foram produzidos por casting. Os efeitos da metodologia de preparação e da concentração de nanoargila nas propriedades físico-químicas dos filmes foram estudados. Conforme os métodos de elaboração, filmes intercalados e esfoliados de nanocompósitos foram obtidos. Os espectros FTIR mostraram uma forte interação entre a argila montmorilonita e as moléculas de amido. A opacidade foi dependente do método utilizado para a dispersão da nanoargila. A solubilidade e a permeabilidade ao vapor de água diminu

  6. Water masers in the Kronian system (United States)

    Pogrebenko, Sergei V.; Gurvits, Leonid I.; Elitzur, Moshe; Cosmovici, Cristiano B.; Avruch, Ian M.; Pluchino, Salvatore; Montebugnoli, Stelio; Salerno, Emma; Maccaferri, Giuseppe; Mujunen, Ari; Ritakari, Jouko; Molera, Guifre; Wagner, Jan; Uunila, Minttu; Cimo, Giuseppe; Schilliro, Francesco; Bartolini, Marco

    The presence of water has been considered for a long time as a key condition for life in planetary environments. The Cassini mission discovered water vapour in the Kronian system by detecting absorption of UV emission from a background star (Hansen et al. 2006). Prompted by this discovery, we started an observational campaign for search of another manifestation of the water vapour in the Kronian system, its maser emission at the frequency of 22 GHz (1.35 cm wavelength). Observations with the 32 m Medicina radio telescope (INAF-IRA, Italy) started in 2006 using Mk5A data recording and the JIVE-Huygens software correlator. Later on, an on-line spectrometer was used at Medicina. The 14 m Metsähovi radio telescope (TKK-MRO, Finland) joined the observational campaign in 2008 using a locally developed data capture unit and software spectrometer. More than 300 hours of observations were collected in 2006-2008 campaign with the two radio telescopes. The data were analysed at JIVE using the Doppler tracking technique to compensate the observed spectra for the radial Doppler shift for various bodies in the Kronian system (Pogrebenko et al. 2009). Here we report the observational results for Hyperion, Titan, Enceladus and Atlas, and their physical interpretation. Encouraged by these results we started a campaign of follow up observations including other radio telescopes.

  7. Use of natural clays as sorbent materials for rare earth ions: Materials characterization and set up of the operative parameters. (United States)

    Iannicelli-Zubiani, Elena Maria; Cristiani, Cinzia; Dotelli, Giovanni; Gallo Stampino, Paola; Pelosato, Renato; Mesto, Ernesto; Schingaro, Emanuela; Lacalamita, Maria


    Two mineral clays of the montmorillonite group were tested as sorbents for the removal of Rare Earths (REs) from liquid solutions. Lanthanum and neodymium model solutions were used to perform uptake tests in order to: (a) verify the clays sorption capability, (b) investigate the sorption mechanisms and (c) optimize the experimental parameters, such as contact time and pH. The desorption was also studied, in order to evaluate the feasibility of REs recovery from waters. The adsorption-desorption procedure with the optimized parameters was also tested on a leaching solution obtained by dissolution of a dismantled NdFeB magnet of a hard-disk. The clays were fully characterized after REs adsorption and desorption by means of X-ray powder diffraction (XRPD) and X-ray photoelectron spectroscopy (XPS); the liquid phase was characterized via Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) analyses. The experimental results show that both clays are able to capture and release La and Nd ions, with an ion exchange mechanism. The best total efficiency (capture ≈ 50%, release ≈ 70%) is obtained when the uptake and release processes are performed at pH=5 and pH=1 respectively; in real leached scrap solutions, the uptake is around 40% but release efficiency is strongly decreased passing from a mono-ion system to a real system (from 80% to 5%). Furthermore, a strong matrix effect is found, with the matrix largely affecting both the uptake and the release of neodymium.

  8. 80 FR 75817 - NESHAP for Brick and Structural Clay Products Manufacturing; and NESHAP for Clay Ceramics... (United States)


    ... NESHAP for Clay Ceramics Manufacturing: Correction AGENCY: Environmental Protection Agency (EPA). ACTION...; and NESHAP for Clay Ceramics Manufacturing. These amendments make two technical corrections to...

  9. Synchrotron X-ray Scattering from Self-organized Soft Nanostructures in Clays (United States)

    Fossum, J. O.


    In the general context of self-organization of nanoparticles (in our case clay particles), and transitions in such structures, we study interconnected universal complex physical phenomena such as: (i) spontaneous gravitationally induced phase separation and nematic self-organization in systems of anisotropic clay nanoparticles in aqueous suspension, including studies of isotropic to nematic transitions [1,2] (ii) transitions from biaxial to uniaxial nematics by application of external magnetic field to self-organized systems of the same anisotropic (diamagnetic) clay nanoparticle systems [3,4] (iii) guided self-organization into chainlike structures of the same anisotropic clay nanoparticles in oil suspension when subjected to external electrical fields (electrorheological structures of polarized nanoparticles), and the stability of, and transitions of, such structures, when subjected to external mechanical stress [5,6] The experimental techniques used by us include synchrotron X-ray scattering, neutron scattering, rheometry. microscopy and magnetic resonance. We have demonstrated that clays may be used as good model systems for studies of universal physical phenomena and transitions in self-organized nanostructured soft and complex matter. Self-organization and related transitions in clay systems in particular, may have practical relevance for nano-patterning, properties of nanocomposites, and macroscopically anisotropic gels, among many other applications [7]. The synchrotron experiments have been performed at LNLS-Brazil, PLS- Korea, BNL-USA and ESRF-France. Acknowledgments: Collaborators, postdocs and students at NTNU-Norway, UiO-Norway, IFE-Norway, BNL-USA, LNLS-Brazil, UFPE-Brazil, UnB-Brazil, Univ. Amsterdam-Netherlands, Univ.Paris 7-France and other places. This research has been supported by the Research Council of Norway (RCN), through the NANOMAT, SUP and FRINAT Programs. References 1. J.O. Fossum, E. Gudding, D.d.M. Fonseca, Y. Meheust, E. DiMasi, T

  10. Hydrogeology in Clay Tills

    DEFF Research Database (Denmark)

    Kessler, Timo Christian; Klint, Knud Erik; Nilsson, Bertel;


    Low-permeability soils such as clayey tills constitute geological boundaries to underlying chalk aquifers that are commonly used as a drinking water resource. Fractures and sand lenses within till sequences represent hydraulic avenues with high hydraulic conductivites limiting the protective func...

  11. Lead removal from aqueous solutions by a Tunisian smectitic clay. (United States)

    Chaari, Islem; Fakhfakh, Emna; Chakroun, Salima; Bouzid, Jalel; Boujelben, Nesrine; Feki, Mongi; Rocha, Fernando; Jamoussi, Fakher


    The adsorption of Pb(2+) ions onto Tunisian smectite-rich clay in aqueous solution was studied in a batch system. Four samples of clay (AYD, AYDh, AYDs, AYDc) were used. The raw AYD clay was sampled in the Coniacian-Early Campanian of Jebel Aïdoudi in El Hamma area (South of Tunisia). AYDh and AYDs corresponds to AYD activated by 2.5 mol/l hydrochloric acid and 2.5 mol/l sulphuric acid, respectively. AYDc corresponds to AYD calcined at different temperatures (100, 200, 300, 400, 500 and 600 degrees C). The raw AYD clay was characterized by X-ray diffraction, chemical analysis, infrared spectroscopy and coupled DTA-TGA. Specific surface area of all the clay samples was determined from nitrogen adsorption isotherms. Preliminary adsorption tests showed that sulphuric acid and hydrochloric acid activation of raw AYD clay enhanced its adsorption capacity for Pb(2+) ions. However, the uptake of Pb(2+) by AYDs was very high compared to that by AYDh. This fact was attributed to the greater solubility of clay minerals in sulphuric acid compared to hydrochloric acid. Thermic activation of AYD clay reduced the Pb(2+) uptake as soon as calcination temperature reaches 200 degrees C. All these preliminary results were well correlated to the variation of the specific surface area of the clay samples. The ability of AYDs sample to remove Pb(2+) from aqueous solutions has been studied at different operating conditions: contact time, adsorbent amount, metal ion concentration and pH. Kinetic experiments showed that the sorption of lead ions on AYDs was very fast and the equilibrium was practically reached after only 20 min. The results revealed also that the adsorption of lead increases with an increase in the solution pH from 1 to 4.5 and then decreases, slightly between pH 4.5 and 6, and rapidly at pH 6.5 due to the precipitation of some Pb(2+) ions. The equilibrium data were analysed using Langmuir isotherm model. The maximum adsorption capacity (Q(0)) increased from 25 to 25

  12. Clay pot irrigation for tomato (Lycopersicon esculentum Mill production in the north east semiarid region of Ethiopia

    Directory of Open Access Journals (Sweden)

    Kebede Woldetsadik


    Full Text Available Water shortage is one of the major constraints for production of horticultural crops in arid and semiarid regions. A field experiment was conducted to determine irrigation water and fertilizer use efficiency, growth and yield of tomato under clay pot irrigation at the experimental site of Sekota Dryland Agricultural Research Center, Lalibela, Ethiopia in 2009/10. The experiment comprised of five treatments including furrow irrigated control and clay pot irrigation with different plant population and fertilization methods, which were arranged in Randomized Complete Block Design with three replications. The highest total and marketable fruit yields were obtained from clay pot irrigation combined with application of nitrogen fertilizer with irrigation water irrespective of difference in plant population. The clay pot irrigation had seasonal water use of up to 143.71 mm, which resulted in significantly higher water use efficiency (33.62 kg m-3 as compared to the furrow irrigation, which had a seasonal water use of 485.50 mm, and a water use efficiency of 6.67 kg m-3. Application of nitrogen fertilizer with irrigation water in clay pots improved fertilizer use efficiency of tomato by up to 52% than band application with furrow or clay pot irrigation. Thus, clay pot irrigation with 33,333 plants ha-1 and nitrogen fertilizer application with irrigation water in clay pots was the best method for increasing the yield of tomato while economizing the use of water and nitrogen fertilizer in a semiarid environment.

  13. Boron enrichment in martian clay.

    Directory of Open Access Journals (Sweden)

    James D Stephenson

    Full Text Available We have detected a concentration of boron in martian clay far in excess of that in any previously reported extra-terrestrial object. This enrichment indicates that the chemistry necessary for the formation of ribose, a key component of RNA, could have existed on Mars since the formation of early clay deposits, contemporary to the emergence of life on Earth. Given the greater similarity of Earth and Mars early in their geological history, and the extensive disruption of Earth's earliest mineralogy by plate tectonics, we suggest that the conditions for prebiotic ribose synthesis may be better understood by further Mars exploration.

  14. Strength Properties of Aalborg Clay

    DEFF Research Database (Denmark)

    Iversen, Kirsten Malte; Nielsen, Benjaminn Nordahl; Augustesen, Anders Hust

    resulted in many damaged buildings in Aalborg. To provide sufficient bearing capacity it is therefore necessary either to remove the fill or to construct the building on piles. Both methods imply that the strength of Aalborg Clay is important for the construction. This paper evaluates the strength...... of Aalborg Clay by use of triaxial tests from four different locations. Both the drained strength (c and ϕ) and the undrained strength (cu) are assessed through two different methods: one where the strength is assumed to vary with the effective stress and another where the strength is found to be constant....

  15. Nano sized clay detected on chalk particle surfaces

    DEFF Research Database (Denmark)

    Skovbjerg, Lone; Hassenkam, Tue; Makovicky, Emil


    that in calcite saturated water, both the polar and the nonpolar functional groups adhere to the nano sized clay particles but not to calcite. This is fundamentally important information for the development of conceptual and chemical models to explain wettability alterations in chalk reservoirs...

  16. Fine Structure of Starch-Clay Composites as Biopolymers (United States)

    Midsol 50 wheat starch and 5% Cloisite clay with or without the addition of glycerin were used to prepare biopolymers in a twin-screw extruder. Early trials of sectioning the unembedded biopolymer resulted in the immediate absorption of water and subsequent dissolution of the sample due to the the ...

  17. Derivation of in situ opalinus clay porewater compositions from experimental and geochemical modelling studies

    Energy Technology Data Exchange (ETDEWEB)

    Bradbury, M.H.; Baeyens, B. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)


    Many countries are considering argillaceous sedimentary rocks as potential formations for the disposal of high level radioactive waste. One of the main attractions of such formations from a waste management viewpoint are their generally low groundwater flow rates. However, porewater chemistry constitutes an important basic data set for performance assessment studies and the low transmissivities often mean that it is very difficult, or even impossible, to obtain good in situ water samples. This report describes procedures based on physico-chemical characterisation of whole rock samples and geochemical modelling which were developed as an additional tool for determining porewater compositions in low porosity/permeability clay rich systems. The methodology was applied to core samples of opalinus clay within the framework of an international investigation being carried out at Mt. Terri, Canton Jura, Switzerland. The calculated porewater compositions are described and discussed in relation to experimental data from the analyses of borehole seepage water and water samples obtained from squeezing tests. Because the latter two waters were clearly out of the equilibrium, only a comparison based on general aqueous features was attempted. In all three cases the groundwaters were high ionic strength Na-Cl types. The experimentally determined pH values were in the range 7.5-8 whereas for the modelled porewater a value near 6 was calculated. This discrepancy was explained by postulating that the sampled waters lost dissolved CO{sub 2} through out-gassing. (author) 5 figs., 11 tabs., refs.

  18. Bacteriological problems in water supply systems; Bakteriologische Probleme bei Wassersystemen

    Energy Technology Data Exchange (ETDEWEB)

    Kunz, P.


    This article takes a look at bacteriological problems in hot-water distribution system and, in particular looks at the situation concerning legionella bacteria which thrive in standing water at temperatures often encountered in domestic hot water systems. The article is based on experience gained in the analysis of over 1500 hot-water systems. Diseases caused by the inhalation of water droplets emanating from domestic hot-water systems are discussed and showers are mentioned as being a problem zone. An ecological thermal protective system is described. Problems that can be encountered in ventilation and air-conditioning systems and other potential sources are also mentioned.

  19. Manganese deposition in drinking water distribution systems

    Energy Technology Data Exchange (ETDEWEB)

    Gerke, Tammie L., E-mail: [Department of Geology, University of Cincinnati, Cincinnati, OH 45221-0013 (United States); Little, Brenda J., E-mail: [Naval Research Laboratory, Stennis Space Center, MS 39529 (United States); Barry Maynard, J., E-mail: [Department of Geology, University of Cincinnati, Cincinnati, OH 45221-0013 (United States)


    This study provides a physicochemical assessment of manganese deposits on brass and lead components from two fully operational drinking water distributions systems. One of the systems was maintained with chlorine; the other, with secondary chloramine disinfection. Synchrotron-based in-situ micro X-ray adsorption near edge structure was used to assess the mineralogy. In-situ micro X-ray fluorescence mapping was used to demonstrate the spatial relationships between manganese and potentially toxic adsorbed metal ions. The Mn deposits ranged in thickness from 0.01 to 400 μm. They were composed primarily of Mn oxides/oxhydroxides, birnessite (Mn{sup 3+} and Mn{sup 4+}) and hollandite (Mn{sup 2+} and Mn{sup 4+}), and a Mn silicate, braunite (Mn{sup 2+} and Mn{sup 4+}), in varying proportions. Iron, chromium, and strontium, in addition to the alloying elements lead and copper, were co-located within manganese deposits. With the exception of iron, all are related to specific health issues and are of concern to the U.S. Environmental Protection Agency (U.S. EPA). The specific properties of Mn deposits, i.e., adsorption of metals ions, oxidation of metal ions and resuspension are discussed with respect to their influence on drinking water quality. - Highlights: • Oxidation and deposition of Mn deposits in drinking water distribution pipes • In-situ synchrotron-based μ-XANES and μ-XRF mapping • Toxic metal sorption in Mn deposits.

  20. Spray Layer-by-Layer Assembled Clay Composite Thin Films as Selective Layers in Reverse Osmosis Membranes. (United States)

    Kovacs, Jason R; Liu, Chaoyang; Hammond, Paula T


    Spray layer-by-layer assembled thin films containing laponite (LAP) clay exhibit effective salt barrier and water permeability properties when applied as selective layers in reverse osmosis (RO) membranes. Negatively charged LAP platelets were layered with poly(diallyldimethylammonium) (PDAC), poly(allylamine) (PAH), and poly(acrylic acid) (PAA) in bilayer and tetralayer film architectures to generate uniform films on the order of 100 nm thick that bridge a porous poly(ether sulfone) support to form novel RO membranes. Nanostructures were formed of clay layers intercalated in a polymeric matrix that introduced size-exclusion transport mechanisms into the selective layer. Thermal cross-linking of the polymeric matrix was used to increase the mechanical stability of the films and improve salt rejection by constraining swelling during operation. Maximum salt rejection of 89% was observed for the tetralayer film architecture, with an order of magnitude increase in water permeability compared to commercially available TFC-HR membranes. These clay composite thin films could serve as a high-flux alternative to current polymeric RO membranes for wastewater and brackish water treatment as well as potentially for forward osmosis applications. In general, we illustrate that by investigating the composite systems accessed using alternating layer-by-layer assembly in conjunction with complementary covalent cross-linking, it is possible to design thin film membranes with tunable transport properties for water purification applications.

  1. Constitutive relationships for elastic deformation of clay rock: Data Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Liu, H.H.; Rutqvist, J.; Birkholzer, J.T.


    Geological repositories have been considered a feasible option worldwide for storing high-level nuclear waste. Clay rock is one of the rock types under consideration for such purposes, because of its favorable features to prevent radionuclide transport from the repository. Coupled hydromechanical processes have an important impact on the performance of a clay repository, and establishing constitutive relationships for modeling such processes are essential. In this study, we propose several constitutive relationships for elastic deformation in indurated clay rocks based on three recently developed concepts. First, when applying Hooke's law in clay rocks, true strain (rock volume change divided by the current rock volume), rather than engineering strain (rock volume change divided by unstressed rock volume), should be used, except when the degree of deformation is very small. In the latter case, the two strains will be practically identical. Second, because of its inherent heterogeneity, clay rock can be divided into two parts, a hard part and a soft part, with the hard part subject to a relatively small degree of deformation compared with the soft part. Third, for swelling rock like clay, effective stress needs to be generalized to include an additional term resulting from the swelling process. To evaluate our theoretical development, we analyze uniaxial test data for core samples of Opalinus clay and laboratory measurements of single fractures within macro-cracked Callovo-Oxfordian argillite samples subject to both confinement and water reduced swelling. The results from this evaluation indicate that our constitutive relationships can adequately represent the data and explain the related observations.

  2. Implications of Israeli Agricultural Water Price Sharing System to China

    Institute of Scientific and Technical Information of China (English)

    Yifan LI; Fusheng LIU


    This paper introduces Israeli agricultural water price sharing system. According to Israeli agricultural water cost composition,water price sharing by farmers as well as government subsidy and its forms,the financial subsidy-based agricultural water price system has been established on the basis of the farmers’ income in our country and reasonable water price sharing,thus to promote the development of water-saving agriculture in China.

  3. Freezing phenomena in ice-water systems

    Energy Technology Data Exchange (ETDEWEB)

    Akyurt, M.; Zaki, G.; Habeebullah, B. [Fakieh Center for Applied Research, Makkah Al-Mukarramah (Saudi Arabia); King Abdulaziz University, Jeddah (Saudi Arabia). Dept. of Mechanical Engineering


    The characteristics of solidification and melting are reviewed. The properties of water and ice and the phase diagram of water are discussed with special emphasis on ice density. A concise account of the freezing process and the Stefan problem is presented. To this end, the four stages of freezing are identified, supercooling, nucleation and the formation of dendritic ice, the growth of concentric rings of solid ice at 0{sup o}C and the final cooling of the solid ice are treated in some detail. The subject of bursting of pipes is given particular emphasis. Attention is drawn to a common misconception on pipe bursting and to misleading relationships for the computation of freezing time for ice blockage. Several current applications of melting and freezing systems are outlined. (author)

  4. Effects of polyethoxylate lauryl ether (Brij 35) addition on phenanthrene biodegradation in a soil/water system. (United States)

    Chang, Yi-T; Hung, Chun-H; Chou, Hsi-L


    Non-ionic surfactants usually are often selected for use in surfactant flushing technology, which is a process that can be used as part of PAH-contaminated soil bioremediation. Phenanthrene (PHE) biodegradation in the presence of polyethoxylate lauryl ether (Brij 35) was studied in two soil/water systems. The natural soil organic matter content (SOM) and the present of Brij 35, both above the critical micelle concentration (CMC) and below the CMC, changed the rate of PHE biodegradation in the presence of Brij 35. PHE biodegradation is different in the two different soil/water systems: PHE > PHE-Brij 35-Micelle > PHE-Brij 35-Monomer in the clay/water system; PHE-Brij 35-Micelle > PHE-Brij 35-Monomer > PHE in the natural soil/water system. Among the free-living species associated with PHE-Brij 35 biodegradation, Brevundimonas diminuta, Caulobacter spp., Mycoplana bullata, Acidovorax spp. and Pseudomonas aeruginosa accounted for 90.72% to 99.90% of the bacteria present. Specific hydrolytic enzymes, including esterases, glycosol-hydrolases and phosphatases, are expressed during PHE biodegradation. The information presented here will help the engineering design of more effective PAH bioremediation systems that use Brij 35 series flushing technology. In particular, micelles of Brij 35 can be used to accelerate the rate of remediation of PAH-contaminated soil in natural soil/water systems.

  5. Water Renew systems: wastewater polishing using renewable energy crops. (United States)

    Sugiura, A; Tyrrel, S F; Seymour, I; Burgess, P J


    Macronutrients concentrations were measured during the establishment year of short rotation coppice of Salix viminalis, Populus trichocarpa, Eucalyptus gunnii irrigated with secondary treated effluent. Twenty four plots of 12.25 m2 located in Cranfield, Bedfordshire, UK on heavy fine clay were drip-irrigated in order to maintain their soil moisture at field capacity. Soil water was sampled at 30 cm and 60 cm with soil water suction cup samplers fortnightly. Willow and eucalyptus received more than 900 mm of effluent corresponding to more than 290 kg-N/ha, 30 kg-P/ha and 220 kg-K/ha. Poplar and unplanted plots received less than 190 kg-N/ha, 17 kg-P/ha and 120 kg-K/ha. For soil water nitrogen concentrations as for potassium concentrations, there was an irrigation effect only on eucalyptus planted plots. On all plots, there was no significant effect of tree presence or species. There was no phosphorus measurable in soil water samples. Groundwater chemistry was unaffected by irrigation. Thus, intensive irrigation of short rotation coppice during the establishment year should not be considered as a major threat to groundwater quality. Willows and eucalyptus can absorb almost a third more effluent than poplar and unplanted plots without having any significant effect on soil water chemistry.

  6. Progress of the Water Cooling System for CYCIAE-100

    Institute of Scientific and Technical Information of China (English)

    LI; Zhen-guo; WU; Long-cheng; LIU; Geng-guo


    The water cooling system for CYCIAE-100 has achieved a significant progress in 2013,its progress can be summarized as follows:1)The deionized water production equipment and the main circulating water cooling unit are installed and tested.2)The circulating water cooling unit for high power target and circulating water cooling unit for vacuum helium compressor are installed and tested.

  7. Biodegradable Pectin/clay Aerogels (United States)

    Biodegradable, foamlike materials based on renewable pectin and sodium montmorillonite clay were fabricated through a simple, environmentally friendly freeze-drying process. Addition of multivalent cations (Ca2+ and Al3+) resulted in apparent crosslinking of the polymer, and enhancement of aerogel p...

  8. Picasso Masks: Cubism in Clay (United States)

    Daddino, Michelle


    This article describes an art project developed by the author which provides a way to further the children's understanding of Picasso's Cubism style in 3-D. Through this project, upper-elementary students learn a bit about the life and art of Picasso as they gain a firm understanding of the style of art known as Cubism, and apply clay techniques…


    Surfactants used to enhance remediation of soils by soil washing are often lost in the process. Neither the amount nor the cause of this loss is known. It is assumed that clays present in the soil are responsible for the loss of the surfactant. In this papere, adsorption prope...

  10. Analysis on Systematic Water Scarcity Based on Establishment of Water Scarcity Classification System

    Institute of Scientific and Technical Information of China (English)


    It would be very helpful for making countermeasures against complex water scarcity by analysis on systematic water scarcity.Based on the previous researches on water scarcity classification,a classification system of water scarcity was established according to contributing factors,which comprises three water scarcity categories caused by anthropic factors,natural factors and mixed factors respectively.Accordingly,the concept of systematic water scarcity was proposed,which can be defined as one type of water...

  11. Gas breakthrough and emission through unsaturated compacted clay in landfill final cover

    Energy Technology Data Exchange (ETDEWEB)

    Ng, C.W.W.; Chen, Z.K.; Coo, J.L. [Department of Civil and Environmental Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Chen, R., E-mail: [Shenzhen Key Laboratory of Urban and Civil Engineering for Disaster Prevention and Mitigation, Harbin Institute of Technology Shenzhen Graduate School, Shenzhen 518055 (China); Zhou, C. [Department of Civil and Environmental Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)


    Highlights: • Explore feasibility of unsaturated clay as a gas barrier in landfill cover. • Gas breakthrough pressure increases with clay thickness and degree of saturation. • Gas emission rate decreases with clay thickness and degree of saturation. • A 0.6 m-thick clay layer may be sufficient to meet gas emission rate limit. - Abstract: Determination of gas transport parameters in compacted clay plays a vital role for evaluating the effectiveness of soil barriers. The gas breakthrough pressure has been widely studied for saturated swelling clay buffer commonly used in high-level radioactive waste disposal facility where the generated gas pressure is very high (in the order of MPa). However, compacted clay in landfill cover is usually unsaturated and the generated landfill gas pressure is normally low (typically less than 10 kPa). Furthermore, effects of clay thickness and degree of saturation on gas breakthrough and emission rate in the context of unsaturated landfill cover has not been quantitatively investigated in previous studies. The feasibility of using unsaturated compacted clay as gas barrier in landfill covers is thus worthwhile to be explored over a wide range of landfill gas pressures under various degrees of saturation and clay thicknesses. In this study, to evaluate the effectiveness of unsaturated compacted clay to minimize gas emission, one-dimensional soil column tests were carried out on unsaturated compacted clay to determine gas breakthrough pressures at ultimate limit state (high pressure range) and gas emission rates at serviceability limit state (low pressure range). Various degrees of saturation and thicknesses of unsaturated clay sample were considered. Moreover, numerical simulations were carried out using a coupled gas–water flow finite element program (CODE-BRIGHT) to better understand the experimental results by extending the clay thickness and varying the degree of saturation to a broader range that is typical at different

  12. Effects of Fiber Reinforcement on Clay Aerogel Composites

    Directory of Open Access Journals (Sweden)

    Katherine A. Finlay


    Full Text Available Novel, low density structures which combine biologically-based fibers with clay aerogels are produced in an environmentally benign manner using water as solvent, and no additional processing chemicals. Three different reinforcing fibers, silk, soy silk, and hemp, are evaluated in combination with poly(vinyl alcohol matrix polymer combined with montmorillonite clay. The mechanical properties of the aerogels are demonstrated to increase with reinforcing fiber length, in each case limited by a critical fiber length, beyond which mechanical properties decline due to maldistribution of filler, and disruption of the aerogel structure. Rather than the classical model for reinforced composite properties, the chemical compatibility of reinforcing fibers with the polymer/clay matrix dominated mechanical performance, along with the tendencies of the fibers to kink under compression.

  13. Compressive Strength of Compacted Clay-Sand Mixes

    Directory of Open Access Journals (Sweden)

    Faseel Suleman Khan


    Full Text Available The use of sand to improve the strength of natural clays provides a viable alternative for civil infrastructure construction involving earthwork. The main objective of this note was to investigate the compressive strength of compacted clay-sand mixes. A natural clay of high plasticity was mixed with 20% and 40% sand (SP and their compaction and strength properties were determined. Results indicated that the investigated materials exhibited a brittle behaviour on the dry side of optimum and a ductile behaviour on the wet side of optimum. For each material, the compressive strength increased with an increase in density following a power law function. Conversely, the compressive strength increased with decreasing water content of the material following a similar function. Finally, the compressive strength decreased with an increase in sand content because of increased material heterogeneity and loss of sand grains from the sides during shearing.

  14. Nafion–clay nanocomposite membranes: Morphology and properties

    KAUST Repository

    Herrera Alonso, Rafael


    A series of Nafion-clay nanocomposite membranes were synthesized and characterized. To minimize any adverse effects on ionic conductivity the clay nanoparticles were H+ exchanged prior to mixing with Nafion. Well-dispersed, mechanically robust, free-standing nanocomposite membranes were prepared by casting from a water suspension at 180 °C under pressure. SAXS profiles reveal a preferential orientation of Nafion aggregates parallel to the membrane surface, or normal plane. This preferred orientation is induced by the platy nature of the clay nanoparticles, which tend to align parallel to the surface of the membrane. The nanocomposite membranes show dramatically reduced methanol permeability, while maintaining high levels of proton conductivity. The hybrid films are much stiffer and can withstand much higher temperatures compared to pure Nafion. The superior thermomechanical, electrochemical and barrier properties of the nanocomposite membranes are of significant interest for direct methanol fuel cell applications. © 2009 Elsevier Ltd. All rights reserved.

  15. Contamination Control and Monitoring of Tap Water as Fluid in Industrial Tap Water Hydraulic Systems

    DEFF Research Database (Denmark)

    Conrad, Finn; Adelstorp, Anders


    Presentation of results and methods addressed to contamination control and monitoring of tap water as fluid in tap water hydraulic systems.......Presentation of results and methods addressed to contamination control and monitoring of tap water as fluid in tap water hydraulic systems....

  16. Biological stability in drinking water distribution systems: A novel approach for systematic microbial water quality monitoring

    NARCIS (Netherlands)

    Prest, E.I.E.D.


    Challenges to achieve biological stability in drinking water distribution systems Drinking water is distributed from the treatment facility to consumers through extended man-made piping systems. The World Health Organization drinking water guidelines (2006) stated that “Water entering the distribut

  17. Sustainable Energy, Water and Environmental Systems

    DEFF Research Database (Denmark)

    Østergaard, Poul Alberg; Duic, Neven


    This issue presents research results from the 8th Conference on Sustainable Development of Energy, Water and Environment Systems – SDEWES - held in Dubrovnik, Croatia in 2013. Topics covered here include the energy situation in the Middle East with a focus in Cyprus and Israel, energy planning...... methodology with Ireland as a case and the applicability of energy scenarios modelling tools as a main focus, evaluation of energy demands in Italy and finally evaluation of underground cables vs overhead lines and lacking public acceptance of incurring additional costs for the added benefit of having...

  18. Interaction and transport of actinides in natural clay rock with consideration of humic substances and clay organics. Characterization and quantification of the influence of clay organics on the interaction and diffusion of uranium and americium in the clay. Joint project

    Energy Technology Data Exchange (ETDEWEB)

    Bernhard, Gert [Helmholtz-Zentrum Dresden-Rossendorf e.V. (Germany). Inst. of Radiochemistry; Schmeide, Katja; Joseph, Claudia; Sachs, Susanne; Steudtner, Robin; Raditzky, Bianca; Guenther, Alix


    The objective of this project was the study of basic interaction processes in the systems actinide - clay organics - aquifer and actinide - natural clay - clay organics - aquifer. Thus, complexation, redox, sorption and diffusion studies were performed. To evaluate the influence of nitrogen, phosphorus and sulfur containing functional groups of humic acid (HA) on the complexation of actinides in comparison to carboxylic groups, the Am(III) and U(VI) complexation by model ligands was studied by UV-Vis spectroscopy and TRLFS. The results show that Am(III) is mainly coordinated via carboxylic groups, however, probably stabilized by nitrogen groups. The U(VI) complexation is dominated by carboxylic groups, whereas nitrogen and sulfur containing groups play a minor role. Phosphorus containing groups may contribute to the U(VI) complexation by HA, however, due to their low concentration in HA they play only a subordinate role compared to carboxylic groups. Applying synthetic HA with varying sulfur contents (0 to 6.9 wt.%), the role of sulfur functionalities of HA for the U(VI) complexation and Np(V) reduction was studied. The results have shown that sulfur functionalities can be involved in U(VI) humate complexation and act as redox-active sites in HA for the Np(V) reduction. However, due to the low content of sulfur in natural HA, its influence is less pronounced. In the presence of carbonate, the U(VI) complexation by HA was studied in the alkaline pH range by means of cryo-TRLFS (-120 C) and ATR FT-IR spectroscopy. The formation of the ternary UO{sub 2}(CO{sub 3}){sub 2}HA(II){sup 4-} complex was detected. The complex formation constant was determined with log {beta}{sub 0.1} M = 24.57 {+-} 0.17. For aqueous U(VI) citrate and oxalate species, luminescence emission properties were determined by cryo-TRLFS and used to determine stability constants. The existing data base could be validated. The U(VI) complexation by lactate, studied in the temperature range 7 to 65 C

  19. Investigation of Four Different Laponite Clays as Stabilizers in Pickering Emulsion Polymerization. (United States)

    Brunier, Barthélémy; Sheibat-Othman, Nida; Chniguir, Mehdi; Chevalier, Yves; Bourgeat-Lami, Elodie


    Clay-armored polymer particles were prepared by emulsion polymerization in the presence of Laponite platelets that adsorb at the surface of latex particles and act as stabilizers during the course of the polymerization. While Laponite RDS clay platelets are most often used, the choice of the type of clay still remains an open issue that is addressed in the present article. Four different grades of Laponite were investigated as stabilizers in the emulsion polymerization of styrene. First, the adsorption isotherms of the clays, on preformed polystyrene particles, were determined by ICP-AES analysis of the residual clay in the aqueous phase. Adsorption of clay depended on the type of clay at low concentrations corresponding to adsorption as a monolayer. Adsorption of clay particles as multilayers was observed for all the grades above a certain concentration under the considered ionic strength (mainly due to the initiator ionic species). The stabilization efficiency of these clays was investigated during the polymerization reaction (free of any other stabilizer). The clays did not have the same effect on stabilization, which was related to differences in their compositions and in their adsorption isotherms. The different grades led to different polymer particles sizes and therefore to different polymerization reaction rates. Laponite RDS and S482 gave similar results, ensuring the best stabilization efficiency and the fastest reaction rate; the number of particles increased as the clay concentration increased. Stabilization with Laponite XLS gave the same particles size and number as the latter two clays at low clay concentrations, but it reached an upper limit in the number of nucleated polymer particles at higher concentrations indicating a decrease of stabilization efficiency at high concentrations. Laponite JS did not ensure a sufficient stability of the polymer particles, as the polymerization results were comparable to a stabilizer-free polymerization system.

  20. Chapter 12. Pure Tap Water Hydraulic Systems and Applications

    DEFF Research Database (Denmark)

    Conrad, Finn; Adelstorp, Anders


    Presentation of developed a modern pure tap water hydraulic components (Nessie), systems and industrial applications.......Presentation of developed a modern pure tap water hydraulic components (Nessie), systems and industrial applications....

  1. Chapter 13. Industrial Application of Tap Water Hydraulic Systems

    DEFF Research Database (Denmark)

    Conrad, Finn; Adelstorp, Anders


    Design and application of modern pure tap water components and systems in industries, in particular food processing industry.......Design and application of modern pure tap water components and systems in industries, in particular food processing industry....

  2. Desiccant Dewpoint Cooling System Independent of External Water Sources

    DEFF Research Database (Denmark)

    Bellemo, Lorenzo; Elmegaard, Brian; Markussen, Wiebke B.


    This paper presents a patent pending technical solution aiming to make desiccant cooling systems independent of external water sources, hence solving problems of water availability, cost and treatment that can decrease the system attractiveness. The solution consists in condensing water from the ...... to the desiccant dew-point system without water recovery, the required regeneration temperature increases and the system thermal efficiency decreases.......This paper presents a patent pending technical solution aiming to make desiccant cooling systems independent of external water sources, hence solving problems of water availability, cost and treatment that can decrease the system attractiveness. The solution consists in condensing water from...... the air that regenerates the desiccant dehumidifier, and using it for running the evaporative coolers in the system. A closed regeneration circuit is used for maximizing the amount of condensed water. This solution is applied to a system with a desiccant wheel dehumidifier and a dew point cooler, termed...

  3. Oxygen evolving reactions catalysed by manganese-oxo-complexes adsorbed on clays. (United States)

    Kurz, Philipp


    A series of dinuclear manganese-oxo-complexes was prepared and adsorbed on kaolinite and montmorillonite clays. As indicated by UV-Vis spectroscopy, immobilization of the manganese compounds greatly altered the electronic properties due to strong interactions with the clay surfaces. When studied for their ability to catalyze oxygen formation upon reactions with the strong oxygen-transferring oxidants H(2)O(2) and oxone, it was found that surface adsorption yielded catalysts of improved performance for oxygen formation in aqueous media. Both the rates of oxygen evolution and catalyst stabilities were significantly increased for the clay hybrids of most complexes in comparison to homogeneous solutions of the compounds. Additionally, four heterogeneous systems were also found to catalyze the evolution of O(2) in reactions with the non-oxygen transferring, single- electron oxidation agent Ce(IV)--a reaction not observed for any dinuclear manganese complex in homogeneous reaction. Implications of these observations concerning the mechanism of oxygen formation and the development of manganese-based water oxidation catalysts are discussed.

  4. Water use and water availability constraints to decarbonised electricity systems (United States)

    Byers, Edward; Qadrdan, Meysam; Hall, Jim; Amezaga, Jaime; Chaudry, Modassar; Kilsby, Chris; Martino, Tran; Alderson, David


    Analysis of numerous low carbon electricity strategies have been shown to have very divergent water requirements, normally needed for cooling of thermoelectric power stations. Our regional river-basin scale analysis of water use for future UK electricity strategies shows that, whilst in the majority of cases freshwater use is expected to decline, pathways with high levels of carbon capture and storage (CCS) will result in significantly elevated and concentrated water demands in a few key river basins. Furthermore, these growing demands are compared to both current water availability, and our expected regional water availability under the impacts of climate change. We identify key freshwater constraints to electricity strategies with high levels of CCS and show how these risks may be mitigated with higher levels of hybrid cooling and alternative cooling water sources.

  5. Hydro-mechanical coupling and permeability of an unsaturated swelling clay under hydrous and thermal stress: sorption curve and water permeability; Couplage hydromecanique et permeabilite d'une argile gonflante non saturee sous sollicitations hydriques et thermiques: courbe de sorption et permeabilite a l'eau

    Energy Technology Data Exchange (ETDEWEB)

    Olchitzky, E


    The use of swelling clay for engineered safety barriers of radioactive waste disposal require the understanding of its thermal-hydro-mechanical behaviour. This work concerns particularly the characterization and the modelling of the behaviour of one of these clays: the FoCa7 clay. The characteristics of the studied material are: the sorption (desorption) curve and the water permeability. For each of them, new experiments have allowed to acquire data in fields still few explored: in temperature (between 20 and 80 C) for the sorption curve and in the unsaturated field for the water permeability. The analysis of these results and of bibliographic data has allowed in one hand to estimate the importance of the hysteresis phenomenon and the temperature influence on the sorption curve and in another hand, to establish the requirement to introduce in the modelling of the sorption curve, a plastic parameter due to the irreversible deformations occurring during the compaction. Moreover, the tests carried out for data acquirement have been used too to give validation elements to the non linear behaviour laws proposed by O. Coussy and P. Dangla for the non saturated porous media. The particularity of these laws is to suppose the existence of an effective constraint in the non saturated field, this shows the importance of the validation elements presented here. (O.M.)

  6. Polyethylene/Clay Nanocomposites Produced by In Situ Polymerization with Zirconocene/MAO Catalyst

    Directory of Open Access Journals (Sweden)

    Pimpatima Panupakorn


    Full Text Available Two commercial nanoclays were used here as catalytic fillers for production of polyethylene (PE and linear low-density polyethylene (LLDPE nanocomposites via in situ polymerization with zirconocene/MAO catalyst. It was found that both types of nanoclays designated as clay A and clay B can improve thermal stability to the host polymers as observed from a thermal gravimetric analysis (TGA. The distribution of the clays inside the polymer matrices appeared good due to the in situ polymerization system into which the clays were introduced during the polymer forming reaction. Upon investigating the clays by X-ray diffractometer (XRD and Fourier transform infrared spectroscopy (FTIR, it was observed that the crucial differences between the two clays are the crystallite sizes (A < B and the amounts of amine group (A < B. The higher amount of amine group in clay B was supposed to be a major reason for the lower catalytic activity of the polymerization systems compared to clay A resulting from its deactivating effect on zirconocene catalyst. However, for both clays, increasing their contents in the polymerization systems reduced the catalytic activity due to the higher steric hindrance occurring.

  7. Origin of life and iron-rich clays (United States)

    Hartman, H. H.


    The premise that life began with self-replicating iron-rich clays is explored. In association with these clays and UV light, polar organic molecules, such as oxalic acid, were synthesized. The carbonaceous chondrites have both iron-rich clays and organic molecules. It is convenient to classify meteoritic organic matter into 3 categories: insoluble polymer, hydrocarbons and polar organics (soluble in water). Recent work on the delta D, delta N-15 and delta C-13 has made it clear that these three fractions have been made by three different mechanisms. A significant fraction of the insoluble polymer has a delta-D which suggests that it was made in an interstellar medium. The hydrocarbons seem to have been made on a parent body by a Fischer-Tropsch mechanism. The polar organics were probably synthesized in a mixture of carbonate (NH4)2CO3, Fe(++) ion and liquid water by radiolysis. In a set of experiments the radiolysis of (NH4)2CO3 in the presence and absence of Fe(++) ion has been examined. The synthesis of glycine in the presence of Fe(++) ion is 3-4 times that in the absence of ferrous ion. The effects of the addition of hydrocarbons to this mixture are explored. Iron-rich clays at low temperature and pressure are synthesized. So far the results are not sufficiently crystalline to look for replication. It should be noted that organic chelating agents such as oxalic acid do increase the crystallinity of the clays but not sufficiently. The hydrothermal synthesis of iron-rich clays is being examined.

  8. Can we map swelling clays with remote sensing? (United States)

    van der Meer, Freek

    Swelling soils are soils containing clay minerals that change volume with water content. The original volume of natural soils may change up to 150 percent with increasing water content, which creates major geological hazards that cause extensive damage worldwide. Current engineering practice for delineating areas of potential high swell builds on extensive laboratory analysis, including X-ray diffraction analysis for establishing clay mineralogy and Atterberg limits for deriving the swelling index. This is labour-intensive and thus expensive. Of key importance in assessing the swelling potential of soils is accurate mapping of clay mineralogy and amount (particularly of high swelling smectite and low swelling kaolinite-group minerals) and mapping of soil moisture. For applications related to slope instability processes, surface height and surface deformation need to be examined. Results from spectral analysis of clay mineral spectra presented in this paper show that careful examination of absorption bands allows the characterization and mapping of the clay mineralogy of the soil, which, in conjunction with spectral unmixing, may lead to surface fractions of the various clay minerals. This can potentially be empirically linked with current engineering tests. Remote sensing perspectives for spatial reproduction of these results are further examined in this paper. Imaging spectrometry ( ie, data acquisition in many narrow spectral bands that allow images of reflectance spectra to be derived) may provide insight in surface mineralogy, while microwave remote sensing could deliver soil moisture information. Interferometric SAR (InSAR) is one method of remotely sensed elevation mapping; other remote sensing approaches include radar and laser altimetry and the derivation of digital terrain data from stereoscopic imagery ( ie, Spot, MOMS, etc). This paper could form the basis for formulating a number of research projects within a framework of mapping swelling potential of

  9. Hydrodynamic erosion process of undisturbed clay

    NARCIS (Netherlands)

    Zhao, G.; Visser, P.J.; Vrijling, J.K.


    This paper describes the hydrodynamic erosion process of undisturbed clay due to the turbulent flow, based on theoretical analysis and experimental results. The undisturbed clay has the unique and complicated characteristics of cohesive force among clay particles, which are highly different from dis

  10. Clay Cuffman: A Cool, Calm, Relaxed Guy (United States)

    Booth, Gina


    This article describes Clay Cuffman, a simple clay-sculpture project that requires two or three sessions, and works for students from the upper-elementary level through high school. It takes about 1.5 pounds of clay per student--about the size of a small grapefruit. The Cuffman project is a great way for upper-elementary through high-school…

  11. A closed recirculated sea-water system (United States)


    Study of a virus disease in the chinook salmon (Oncorhynchus tshawytscha) necessitated the use of a marine environment to study the long range effects of the disease and to complete the life cycle of its etiologic agent. A closed recirculated sea-water system was designed for use under experimental laboratory conditions so that controlled studies of the disease could be made. As others may wish to do marine environment studies in the laboratory, the design and operation of our system are presented. Other systems currently in use have been described by Chin (1959), DeWitt and Salo (1960), McCrimmon and Berst (1966), and the authors of collected papers edited by Clark and Clark (1964). Preparatory to the design and construction of the system in use in this laboratory, visits were made to marine systems in use at the University of Washington's College of Fisheries, Seattle, -washington, and Friday Harbor Laboratory, San Juan Island, Washington; the Washington State Department of Fisheries' Point whitney Shellfish Laboratory, Brinnon, Washington; Humboldt State College, Arcata, California; and the Steinhart Aquarium of the California Academy of Science, San Francisco, California.

  12. In-Water Hull Cleaning & Filtration System (United States)

    George, Dan


    Dan George R & D Mining Technology LinkedIn GRD Franmarine have received the following prestigious awards in 2014 for their research & development of an in-water hull cleaning and filtration system "The Envirocart: Golden Gecko Award for Environmental Excellence; WA Innovator of the Year - Growth Sector; Department of Fisheries - Excellence in Marine Biosecurity Award - Innovation Category; Lloyd's List Asia Awards - Environmental Award; The Australian Innovation Challenge - Environment, Agriculture and Food Category; and Australian Shipping and Maritime Industry Award - Environmental Transport Award. The Envirocart developed and patented by GRD Franmarine is a revolutionary new fully enclosed capture and containment in-water hull cleaning technology. The Envirocart enables soft Silicon based antifouling paints and coatings containing pesticides such as Copper Oxide to be cleaned in situ using a contactless cleaning method. This fully containerised system is now capable of being deployed to remote locations or directly onto a Dive Support Vessel and is rated to offshore specifications. This is the only known method of in-water hull cleaning that complies with the Department of Agriculture Fisheries and Forestry (DAFF) and Department of Fisheries WA (DoF) Guidelines. The primary underwater cleaning tool is a hydraulically powered hull cleaning unit fitted with rotating discs. The discs can be fitted with conventional brushes for glass or epoxy based coatings or a revolutionary new patented blade system which can remove marine biofouling without damaging the antifouling paint (silicone and copper oxide). Additionally there are a patented range of fully enclosed hand cleaning tools for difficult to access niche areas such as anodes and sea chests, providing an innovative total solution that enables in-water cleaning to be conducted in a manner that causes no biological risk to the environment. In full containment mode or when AIS are present, material is pumped


    Institute of Scientific and Technical Information of China (English)

    马亢; 许强


    通过开展离心机动力试验,充分揭示在地震荷载的持续作用下,土体将发生一定程度的软化,表现为周期的持续增大;然而基础(筏板)周期和桩身弯矩包络图几乎不发生改变,说明整个桩-筏结构在地震作用下的行为不会类似于土体发生软化(恶化的现象),而是能持续保持稳定,其动力行为主要取决于自身特性如桩身刚度和上部结构传递给筏板的荷载水平(惯性)等,同时土体的动力软化效应对桩-筏结构的影响很小.为了验证试验结果的正确性和合理性,采用ABAQUS 6.9程序对试验结果进行计算分析,土体模型包括软件内嵌的Hypoelastic非线性模型和所开发的考虑动力降强效应的HyperMas用户子程序模型(UMAT).计算结果符合试验实测结果,尤其能准确地捕捉桩身最大弯矩值和周期等重要的工程设计参数.且有侧重于基础单元的地震响应分析,非降强模型和降强模型的计算差异很小,再次说明土体软化对既有桩-筏结构影响很小,但采用非降强模型计算更为快捷、高效.%By conducting dynamic centrifuge tests on the pile-raft-clay system, that soil softening will be taken place in both near field and far field clay in a great degree is investigated, which are manifested as an increase in the resonance periods of clay layers with the level of shaking and successive earthquakes, while this is not the case for the pile-raft foundation since resonance periods of raft and bending moment envelopes of the pile are hardly affected by earthquake loadings. Furthermore, pile-raft dynamic behavior is hardly affected by the stiffness degradation of surrounding clay and could keep stable in successive earthquakes process. Then centrifuge tests are back-analyzed by using ABAQUS 6.9. The results show that, which are conducted using Hypoelastic model embedded in ABAQUS and a developed constitutive relationship, gave reasonably good agreement with the

  14. Natural/mine water deep treatment modular system

    Energy Technology Data Exchange (ETDEWEB)

    Averin, G.V.; Biochenko, V. [Makeyevka Safety in Mines Research Institute, Makeyevka (Ukraine)


    Shortage of water of service and drinking standards is heavily felt in some industries and residential areas in Donetsk region. Modifications of a natural/mine water deep treatment modular system can be used: to produce service water from mine and natural water sources for further use in industry and household applications; to restore industrial waste waters to ecological standards; to provide tertiary treatment, producing the highest quality of drinking water. The system is briefly described and its specifications are given. Three modifications of modular design are expected to be made of the mine/natural water treatment system. 1 fig., 1 tab.

  15. Manganese deposition in drinking water distribution systems. (United States)

    Gerke, Tammie L; Little, Brenda J; Barry Maynard, J


    This study provides a physicochemical assessment of manganese deposits on brass and lead components from two fully operational drinking water distributions systems. One of the systems was maintained with chlorine; the other, with secondary chloramine disinfection. Synchrotron-based in-situ micro X-ray adsorption near edge structure was used to assess the mineralogy. In-situ micro X-ray fluorescence mapping was used to demonstrate the spatial relationships between manganese and potentially toxic adsorbed metal ions. The Mn deposits ranged in thickness from 0.01 to 400 μm. They were composed primarily of Mn oxides/oxhydroxides, birnessite (Mn(3+) and Mn(4+)) and hollandite (Mn(2+) and Mn(4+)), and a Mn silicate, braunite (Mn(2+) and Mn(4+)), in varying proportions. Iron, chromium, and strontium, in addition to the alloying elements lead and copper, were co-located within manganese deposits. With the exception of iron, all are related to specific health issues and are of concern to the U.S. Environmental Protection Agency (U.S. EPA). The specific properties of Mn deposits, i.e., adsorption of metals ions, oxidation of metal ions and resuspension are discussed with respect to their influence on drinking water quality.

  16. 21 CFR 876.5665 - Water purification system for hemodialysis. (United States)


    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Water purification system for hemodialysis. 876... SERVICES (CONTINUED) MEDICAL DEVICES GASTROENTEROLOGY-UROLOGY DEVICES Therapeutic Devices § 876.5665 Water purification system for hemodialysis. (a) Identification. A water purification system for hemodialysis is...

  17. Installation package for a sunspot cascade solar water heating system (United States)


    Solar water heating systems installed at Tempe, Arizona and San Diego, California are described. The systems consist of the following: collector, collector-tank water loop, solar tank, conventional tank, and controls. General guidelines which may be utilized in development of detailed installation plans and specifications are provided along with instruction on operation, maintenance, and installation of solar hot water systems.

  18. Installation package for a solar heating and hot water system (United States)


    Development and installation of two commercial solar heating and hot water systems are reported. The systems consist of the following subsystems: collector, storage, transport, hot water, auxiliary energy and controls. General guidelines are provided which may be utilized in development of detailed installation plans and specifications. In addition, operation, maintenance and repair of a solar heating and hot water system instructions are included.

  19. Advanced feed water distributing system for WWER 440 steam generators

    Energy Technology Data Exchange (ETDEWEB)

    Matal, O.; Klinga, J. [Energovyzkum Ltd, Brno (Switzerland); Grazl, K. [Vitkovice s.c., Ostrava (Switzerland); Tischler, J.; Mihalik, M. [SEP Atomove Elektrarne Bohunice (Slovakia)


    The original designed feed water distributing system was replaced by an advanced one. The characteristics of both feed water distributing systems have been measured and evaluated. The paper deals with the problems of measurement and evaluation of both feed water distributing system characteristics and comparison of statistical data obtained. (orig.). 3 refs.

  20. Artesian water supply control system in transient conditions

    Directory of Open Access Journals (Sweden)

    Костянтин Олегович Буравченко


    Full Text Available The paper describes an artesian water supply control system in the transition mode. The control system searches for the optimal performance trajectory of the water supply on the basis of a maximum return with a view to the fastest mode of stabilization. The analysis of artesian water supply control systems in transition mode and methods of improvement was conducted

  1. Thermal conductivity of unsaturated clay-rocks

    Directory of Open Access Journals (Sweden)

    D. Jougnot


    Full Text Available The parameters used to describe the electrical conductivity of a porous material can be used to describe also its thermal conductivity. A new relationship is developed to connect the thermal conductivity of an unsaturated porous material to the thermal conductivity of the different phases of the composite, and two electrical parameters called the first and second Archie's exponents. A good agreement is obtained between the new model and thermal conductivity measurements performed using packs of glass beads and core samples of the Callovo-Oxfordian clay-rocks at different saturations of the water phase. We showed that the three model parameters optimised to fit the new model against experimental data (namely the thermal conductivity of the solid phase and the two Archie's exponents are consistent with independent estimates. We also observed that the anisotropy of the effective thermal conductivity of the Callovo-Oxfordian clay-rock was mainly due to the anisotropy of the thermal conductivity of the solid phase.

  2. Can clays ensure nuclear waste repositories? (United States)

    Zaoui, A; Sekkal, W


    Research on argillite as a possible host rock for nuclear waste disposal is still an open subject since many issues need to be clarified. In the Underground Research Laboratories constructed for this purpose, a damaged zone around the excavation has been systematically observed and characterized by the appearance of micro-fissures. We analyse here -at nanoscale level- the calcite/clay assembly, the main constituents of argillite, under storage conditions and show the fragility of the montmorillonite with respect to calcite. Under anisotropic stress, we have observed a shear deformation of the assembly with the presence of broken bonds in the clay mineral, localised in the octahedral rather than the tetrahedral layers. The stress/strain curve leads to a failure strength point at 18.5 MPa. The obtained in-plane response of the assembly to perpendicular deformation is characterized by smaller perpendicular moduli Ez = 48.28 GPa compared to larger in-plane moduli Ex = 141.39 GPa and Ey = 134.02 GPa. Our calculations indicate the instability of the assembly without water molecules at the interface in addition to an important shear deformation.

  3. K West integrated water treatment system subproject safety analysis document

    Energy Technology Data Exchange (ETDEWEB)



    This Accident Analysis evaluates unmitigated accident scenarios, and identifies Safety Significant and Safety Class structures, systems, and components for the K West Integrated Water Treatment System.


    Presented within the report are cost data for construction and operation/maintenance of domestic water distribution and transmission pipelines, domestic water pumping stations, and domestic water storage reservoirs. To allow comparison of new construction with rehabilitation of e...

  5. Properties and organic activation of ocean clay in the East Pacific

    Institute of Scientific and Technical Information of China (English)

    Peiping Zhang; Xiaoguo Chi; Chunyan Tian; Baojun Wang; Huahua Lü; Xuefa Shi


    In order to make use of ocean clay reasonably and excavate its potential applications the properties of ocean clay in Chinese investigating area of the East Pacific have been tested with the chemical analysis, XRFS, ICP/MAS, granulometry and SSA, etc. The results show that the clay sediments of this area are rich in clay minerals, fine granularity, bigger SSA, bigger water absorbability and lower ion changing ability etc. To improve the adaptability of ocean clay and macromolecule materials, using the dry milling method with silane, aluminate, stearic acid coupling agents etc the properties of ocean clay are improved. The effect has been evaluated by testing the water absorbing of the modified ocean clay and their dispersing in paraffin liquid. The result is that KH550 is better than any other active reagents, and the best activation technics is that 1.5% (volume) of KH550 quantity, 20min of milling time. The DTA, XRD, SEM and IR analyses and SSA testing show that the organic activation can not change the mineral structure but can densify the structure of clay, and activation mechanism is chemical covered mainly and chemical combined secondly.

  6. Bentonite Clay Evolution at Elevated Pressures and Temperatures: An experimental study for generic nuclear repositories (United States)

    Caporuscio, F. A.; Cheshire, M.; McCarney, M.


    The Used Fuel Disposition Campaign is presently engaged in looking at various generic repository options for disposal of used fuel. Of interest are the disposal of high heat load canisters ,which may allow for a reduced repository footprint. The focus of this experimental work is to characterize Engineered Barrier Systems (EBS) conditions in repositories. Clay minerals - as backfill or buffer materials - are critical to the performance of the EBS. Experiments were performed in Dickson cells at 150 bar and sequentially stepped from 125 oC to 300 oC over a period of ~1 month. An unprocessed bentonite from Colony, Wyoming was used as the buffer material in each experiment. An K-Ca-Na-Cl-rich brine (replicating deep Stripa groundwater) was used at a 9:1 water:rock ratio. The baseline experiment contained brine + clay, while three other experiments contained metals that could be used as waste form canisters (brine +clay+304SS, brine+clay+316SS, brine+clay+Cu). All experiments were buffered at the Mt-Fe oxygen fugacity univarient line. As experiment temperature increased and time progressed, pH, K and Ca ion concentrations dropped, while Si, Na, and SO4 concentrations increased. Silicon was liberated into the fluid phase (>1000 ppm) and precipitated during the quenching of the experiment. The precipitated silica transformed to cristobalite as cooling progressed. Potassium was mobilized and exchanged with interlayer Na, transitioning the clay from Na-montmorillonite to K-smectite. Though illitization was not observed in these experiments, its formation may be kinetically limited and longer-term experiments are underway to evaluate the equilibrium point in this reaction. Clinoptilolite present in the starting bentonite mixture is unstable above 150 oC. Hence, the zeolite broke down at high temperatures but recrystallized as the quench event occurred. This was borne out in SEM images that showed clinoptilolite as a very late stage growth mineral. Both experimental runs

  7. Influence of Two Compatibilizers on Clay/PP Nanocomposites Properties

    DEFF Research Database (Denmark)

    Potarniche, Catalina-Gabriela; Vuluga, Zina; Christiansen, Jesper de Claville


    This article investigates the influence on mechanical properties of using a two compatibilizer system. Cloisite- Na Clay (ClNa) was organically modified in different ways with a polyethermonoamine and maleated polypropylene (MA-g-PP) added as a second compatibilizer. A corotating twin-screw extru......This article investigates the influence on mechanical properties of using a two compatibilizer system. Cloisite- Na Clay (ClNa) was organically modified in different ways with a polyethermonoamine and maleated polypropylene (MA-g-PP) added as a second compatibilizer. A corotating twin...

  8. Water distribution and water use assessment in rice cropping systems

    Directory of Open Access Journals (Sweden)

    S.M. Bockari-Gevao


    Full Text Available This study was carried out to analyze the ways of water distribution in a rice growing area during the pre-saturation and normal irrigation supply periods and to assess water use (WU. The analyses were conducted using field data collected at the Besut rice irrigation scheme located in the state of Terengganu, Malaysia. The scheme comprises two sub-schemes, which are further subdivided into compartments and blocks. Based on field water requirements during the pre-saturation and normal irrigation supply periods and available flows at the intake structures, canal simulation was performed using the CanalMan Model. Results have shown that pre-saturation should not be done continuously unless flow rates are 9.00 m3/sec and 3.00 m3/sec for the Besut and Angga Barrages, respectively. If the respective flow rates fall below these values, then pre-saturation should be done in two phases. However, when the flow rate is between 5.00 and 5.50 m3/sec at Besut Barrage, pre-saturation is recommended to be carried out over three phases. During normal irrigation supply period, flow rates of 5.00 m3/sec and 1.50 m3/sec for the Besut and Angga Barrages respectively, are to be maintained for the whole irrigation scheme. In irrigation block-wise, two WU-based performance indices, namely, adequacy (AI and water productivity (WPI were computed. The average water productivity was 0.31 kg/m3 and 0.25 kg/m3 during the main season and off-season, respectively. Two WU indices, WPI and AI, ranked the performance of the blocks and identified those having problems in water allocation and utilization. These indices revealed that the blocks using more water performed poorly in terms of water productivity. These indices could be used to rectify uneven distribution of water in the scheme.


    Energy Technology Data Exchange (ETDEWEB)

    V. King


    The Pool Water Treatment and Cooling System is located in the Waste Handling Building (WHB), and is comprised of various process subsystems designed to support waste handling operations. This system maintains the pool water temperature within an acceptable range, maintains water quality standards that support remote underwater operations and prevent corrosion, detects leakage from the pool liner, provides the capability to remove debris from the pool, controls the pool water level, and helps limit radiological exposure to personnel. The pool structure and liner, pool lighting, and the fuel staging racks in the pool are not within the scope of the Pool Water Treatment and Cooling System. Pool water temperature control is accomplished by circulating the pool water through heat exchangers. Adequate circulation and mixing of the pool water is provided to prevent localized thermal hotspots in the pool. Treatment of the pool water is accomplished by a water treatment system that circulates the pool water through filters, and ion exchange units. These water treatment units remove radioactive and non-radioactive particulate and dissolved solids from the water, thereby providing the water clarity needed to conduct waste handling operations. The system also controls pool water chemistry to prevent advanced corrosion of the pool liner, pool components, and fuel assemblies. Removal of radioactivity from the pool water contributes to the project ALARA (as low as is reasonably achievable) goals. A leak detection system is provided to detect and alarm leaks through the pool liner. The pool level control system monitors the water level to ensure that the minimum water level required for adequate radiological shielding is maintained. Through interface with a demineralized water system, adequate makeup is provided to compensate for loss of water inventory through evaporation and waste handling operations. Interface with the Site Radiological Monitoring System provides continuous

  10. Design package for solar domestic hot water system

    Energy Technology Data Exchange (ETDEWEB)



    Information used to evaluate the initial design of the Elcam, Inc., Solar Domestic Hot Water System is presented. Included are such items as the system performance specification, detailed design drawings and other information. Elcam, Inc., has developed two solar heated prototype hot water systems and two heat exchangers. The hot water systems consist of the following subsystems: collector, storage, control, transport, auxiliary energy, and government-furnished Site Data Acquisition. The two systems are installed at Tempe, Arizona, and San Diego, California.

  11. Modeling of residual chlorine in water distribution system

    Institute of Scientific and Technical Information of China (English)


    Water quality within water distribution system may vary with both location and time. Water quality models are used to predict the spatial and temporal variation of water quality throughout water system. A model of residual chlorine decay in water pipe has been developed,given the consumption of chlorine in reactions with chemicals in bulk water, bio-films on pipe wall, in corrosion process, and the mass transport of chlorine from bulk water to pipe wall. Analytical methods of the flow path from water sources to the observed point and the water age of every observed node were proposed. Model is used to predict the decay of residual chlorine in an actual distribution system. Good agreement between calculated and measured values was obtained.

  12. Water Resources Compound Systems: A Macro Approach to Analysing Water Resource Issues under Changing Situations

    Directory of Open Access Journals (Sweden)

    Wei Wang


    Full Text Available Water resource crises are an increasing threat to human survival and development. To reveal the nature of water resource issues under changing situations, the water resources system needs to be studied from a macro and systematic perspective. This report develops a water resources system into a water resources compound system that is constantly evolving under the combined action of the development, resistant, and coordination mechanisms. Additionally, the water quotient is defined as a quantitative representation of the sustainable development state of the water resources compound system. Four cities in China, Beijing, Fuzhou, Urumqi, and Lhasa, were selected as the study areas. The differences in the three types of mechanisms and the water quotient of the water resources compound system of each city in 2013 were compared. The results indicate that the different subsystems that comprise the compound system of a given area have different development mechanisms and resistant mechanisms. There are clear differences in the mechanisms and the water quotients for the water resources compound systems of different regions. Pertinent measures should be taken into account during integrated water resource management to improve the sustainable development status of regional water resources compound systems.

  13. Impact of iron on the performance of clay barriers in waste disposal systems. Report on the status of research and development

    Energy Technology Data Exchange (ETDEWEB)

    Wersin, Paul (National Cooperative for the Disposal of Radioactive Waste, Nagra, Wettingen (Switzerland)); Snellman, Margit (Saanio and Riekkola Oy, Helsinki (Finland))


    The interaction of iron components with swelling clay materials in the EBS has received relatively little attention so far in safety assessment studies. It is however widely recognised that such interaction processes (e.g. corrosion, mineral alteration) need to be considered since they have the potential to impair repository long-term safety. A workshop on this topic was held in 2006 in Basel and has shed some light on the current status and the remaining uncertainties of relevance for safety purposes. Also, the workshop highlighted that there is strong interest to continue research in this field. Notably, waste management organisations from France (Finland), Japan, Sweden and Switzerland showed interest to exchange information in this research area on a regular basis and, if possible, advance common projects. Following this workshop, it was decided by Posiva, SKB and Nagra to compile the status of research and development based on a pre-formatted questionnaire sent out to a number of research organisations. This report summarises the information obtained. This serves to identify the remaining knowledge gaps and to explore areas of common interest. Some ideas for common research studies and possibilities how to organise these are presented

  14. Wick wetting for water condensation systems

    Energy Technology Data Exchange (ETDEWEB)

    Hering, Susanne Vera; Spielman, Steven Russel; Lewis, Gregory Stephen; Kreisberg, Nathan Michael


    A system and method for particle enlargement with continuously wetted wicks includes a container into which a flow of particle-laden air is introduced in a laminar manner through an inlet and to an outlet. The container has a first section, a second section and a third section though which the particle-laden air flows between the inlet and the outlet. The temperature of the second section is warmer than that of the first section at the inlet and the third section at the outlet. In one embodiment, a continuous wick spanning an interior wall of the first second, second section and third section, said wick being capable of internally transporting liquid water along its length is provided.

  15. Porosity Investigation of Kosova's Clay

    Directory of Open Access Journals (Sweden)

    Makfire Sadiku


    Full Text Available Problem statement: Acid activated clay minerals are used as catalysts in the desulphurization of crude oil or as catalyst carrier, as drilling mud, as bleaching earth. Approach: The efficiency of the acid activation can be described in two ways. As increase of the surface and as increase of the cumulative pore volume after the activation. Results: In different samples of the clay mineral the activation was done with different sulfuric acid concentrations for two and 3h. Afterwards the specific surface was measured by means of nitrogen adsorption. All the measured isotherms belong to the pseudo-two kind. After the activation the surface enhanced from around 100-180 m2 g-1. The mesopore distribution is calculated out of the hysteresis between adsorption-desorption isotherms of the nitrogen. Conclusion: It is shown that the activation increases significantly the amount of mesopores which is reflected in the cumulative volume. The macrospore volume of the clay samples were measured by means of mercury intrusion porosimetry for pore sizes up to 320 nm. The volume of the macrospores results to an increase up to two times after the activation. The cumulative volume of all the pores is shown like a good parameter of the efficiency of the acid activation. The measurements were fulfilled in the newly equipped laboratory of the surface characterizations of the Tirana University. These analyses are of big interest for the industry in Albania and Kosove.

  16. Mitigating Fish-Killing Prymnesium parvum Algal Blooms in Aquaculture Ponds with Clay: The Importance of pH and Clay Type

    Directory of Open Access Journals (Sweden)

    Andreas Seger


    Full Text Available Clay minerals have previously been used to mitigate algal blooms because of their ability to flocculate algal cells or remove nutrients, but also offer considerable potential to remove ichthyotoxins. When a barramundi farm in tropical Australia suffered substantial fish mortalities due to a bloom of the ichthyotoxic haptophyte Prymnesium parvum, the farm manager decided to manipulate pond water N:P ratios through removal of phosphorus by the addition of lanthanum-modified bentonite clay (Phoslock™ to successfully mitigate ichthyotoxic effects. We conducted Prymnesium culture experiments under a range of N:P ratios, screening 14 different clays (two zeolites, four kaolins, six bentonites and two types of Korean loess at pH 7 and 9 for cell flocculation and removal of ichthyotoxicity assessed with the RTgill-W1 cell line assay. Application of Phoslock™ to cultures grown at different N:P effectively removed 60%–100% of water-soluble toxicity of live Prymnesium (dependent on nutritional status. While most clays efficiently flocculated Prymnesium cells (≥80% removal, cell removal proved a poor predictor of ichthyotoxin adsorption. Extensive clay screening revealed that at elevated pH, as commonly associated with dense algal blooms, most clays either exacerbated ichthyotoxicity or exhibited significantly reduced toxin adsorption. Interpretation of changes in clay zeta potential at pH 7 and 9 provided valuable insight into clay/ichthyotoxin interactions, yet further research is required to completely understand the adsorption mechanisms. Bentonite-type clays proved best suited for ichthyotoxin removal purposes (100% removal at ecologically relevant pH 9 and offer great potential for on-farm emergency response.

  17. Integrated water management system - Description and test results. [for Space Station waste water processing (United States)

    Elden, N. C.; Winkler, H. E.; Price, D. F.; Reysa, R. P.


    Water recovery subsystems are being tested at the NASA Lyndon B. Johnson Space Center for Space Station use to process waste water generated from urine and wash water collection facilities. These subsystems are being integrated into a water management system that will incorporate wash water and urine processing through the use of hyperfiltration and vapor compression distillation subsystems. Other hardware in the water management system includes a whole body shower, a clothes washing facility, a urine collection and pretreatment unit, a recovered water post-treatment system, and a water quality monitor. This paper describes the integrated test configuration, pertinent performance data, and feasibility and design compatibility conclusions of the integrated water management system.

  18. 40 CFR 257.22 - Ground-water monitoring systems. (United States)


    ... operator. When physical obstacles preclude installation of ground-water monitoring wells at the relevant... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Ground-water monitoring systems. 257... Waste Disposal Units Ground-Water Monitoring and Corrective Action § 257.22 Ground-water......


    Energy Technology Data Exchange (ETDEWEB)

    Bach, M; Michael Serrato, M; Eric Nelson, E


    The H-02 Wetland Treatment System (Figure 1) is used to remove heavy metals (e.g., copper and zinc) from the H-Area process and storm water discharge. Routine flow enters an equalization basin by inlets on either the east (Location 1) or west end (Location 2). The west end influent constitutes 75% of the average flow into the basin which has an average residence time of approximately 3 days at low pool (i.e., 120 gal/min. through a volume of 0.5 million gallons). The water then exits via the basin outlet on the east end. Next, the water flows to a splitter box (Location 3) which evenly separates the flow between two wetland cells for a design flow of 60 gal/min. per wetland cell with a residence time in the cell of approximately 2 days. The wetland effluent is then combined (Location 4) and flows through a spillway before reaching the National Pollution Discharge Elimination System (NPDES) measurement point near Road 4. During initial operation, it was observed that the pH of the water leaving the equalization basin was elevated compared to the influent pH. Furthermore, the elevated pH remained through the wetland cells so that there was an average pH of 10 leaving the wetland cells during the daytime which exceeds the upper NPDES limit of 8.5. The purpose of the current study was to evaluate the cause of the increase in pH within the equalization basin of the H-02 Wetland Treatment System. Possible mechanisms included algal activity and inorganic chemistry interactions (e.g., interactions with the clay and/or bentonite liner). Water quality parameters were evaluated throughout the H-02 Wetland Treatment system and over time in order to determine the cause of high pH values measured in the basin and wetland. Fluctuations in dissolved oxygen (DO) and accompanying changes in pH would be expected in systems where algae are an influencing factor. An unexpected increase or decrease in the concentration of inorganic substances may indicate operational changes or an

  20. Enhance decarboxylation reaction of carboxylic acids in clay minerals

    Energy Technology Data Exchange (ETDEWEB)

    Negron-Mendoza, A.; Ramos, S.; Albarran, G. [Instituto de Ciencias y Artes, Chiapas (Mexico). Escuela de Biologia


    Clay minerals are important constituents of the Earth`s crust. These minerals catalyze reactions in several ways: by energy transfer processes, redox reactions, stabilization of intermediates and by Broensted or Lewis acidity behavior. Important set of organic reactions can be improved in the precedence of clay minerals. Besides the properties of clays to catalyze chemical reactions, it is possible to enhance some of its reactions by using ionizing radiation. The phenomenon of radiation-induced catalysis may be connected with ionizing process in the solid and with the trapped non-equilibrium charge carriers. In this paper we are reporting the decarboxylation reaction of carboxylic acids catalyzed by clay and by irradiation of the system acid-clay. We studied the behaviour of several carboxylic acids and analyzed them by gas chromatography, X-ray and infrared spectroscopy. The results showed that decarboxylation of the target compound is the dominating pathway. The reaction is enhanced by gamma radiation in several orders of magnitude. (author).

  1. Model Predictive Control for Operational Water Management: A Case Study of the Dutch Water System

    NARCIS (Netherlands)

    Tian, X.


    Water is needed everywhere to satisfy domestic, agricultural and industrial water demands, to maintain navigation systems, and to preserve healthy and sustainable ecosystems. In order to protect us from floods and to reallocate water resources in a man-made environment, the 'hardware', water-related

  2. Alkali metal and ammonium chlorides in water and heavy water (binary systems)

    CERN Document Server

    Cohen-Adad, R


    This volume surveys the data available in the literature for solid-fluid solubility equilibria plus selected solid-liquid-vapour equilibria, for binary systems containing alkali and ammonium chlorides in water or heavy water. Solubilities covered are lithium chloride, sodium chloride, potassium chloride, rubidium chloride, caesium chloride and ammonium chloride in water and heavy water.

  3. 21 CFR 884.6170 - Assisted reproduction water and water purification systems. (United States)


    ... HUMAN SERVICES (CONTINUED) MEDICAL DEVICES OBSTETRICAL AND GYNECOLOGICAL DEVICES Assisted Reproduction Devices § 884.6170 Assisted reproduction water and water purification systems. (a) Identification... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Assisted reproduction water and water...

  4. Investigation of kinetics of Cr(VI)-fired brick clay interaction. (United States)

    Priyantha, Namal; Bandaranayaka, Anushka


    Fired brick clay is an excellent sorbent for the removal of heavy metal ions from waste water, owing to the availability of pores and interlayer spacing. Consequently, heat treatment of brick clay significantly affects the extent of interaction between the brick clay sorbent and adsorbates. The interaction between Cr(VI), available as Cr(2)O(7)(2-), and brick clay particles fired at temperatures between 200 °C and 600 °C follows pseudo second order kinetics, and the method of initial rates leads to the estimation of the average rate of the interaction process. Kinetics modeling suggests that the mass transfer of the interaction be mainly controlled by time-dependent intraparticle diffusion, as well as immobilization of Cr(VI) species within interlayer structure of the brick clay matrix and interparticle diffusion, both of which are time-independent.

  5. Fluoride exposure from burning coal-clay in Guizhou Province, China

    Energy Technology Data Exchange (ETDEWEB)

    Wu, D.S.; Zheng, B.S.; Wang, A.M.; Yu, G.Q. [Chinese Academy of Science, Guiyang (China)


    The very high prevalence of dental and skeletal fluorosis in relation to the fluorine content of local coal and clay was investigated in two rural regions with low water fluoride (Hualuo Village and Majianzhuang Village) of Guizhou Province, China. The fluorine content of coal in the two regions is considerably lower than the total fluorine content of the commonly used coal-clay (a mixture of coal and clay). The fluorine released from combustion of the coal itself accounts for less than 15% of the total fluorine emissions during the combustion of coal-clay, thereby indicating that the fluorine source that contaminates the food and air is mainly from the clay rather than the coal.

  6. Sulfonated poly(ether ether ketone)/clay-SO 3H hybrid proton exchange membranes for direct methanol fuel cells (United States)

    Fu, Tiezhu; Cui, Zhiming; Zhong, Shuangling; Shi, Yuhua; Zhao, Chengji; Zhang, Gang; Shao, Ke; Na, Hui; Xing, Wei

    A new type of sulfonated clay (clay-SO 3H) was prepared by the ion exchange method with the sulfanilic acid as the surfactant agent. The grafted amount of sulfanilic acid in clay-SO 3H was 51.8 mequiv. (100 g) -1, which was measured by thermogravimetric analysis (TGA). Sulfonated poly(ether ether ketone) (SPEEK)/clay-SO 3H hybrid membranes which composed of SPEEK and different weight contents of clay-SO 3H, were prepared by a solution casting and evaporation method. For comparison, the SPEEK/clay hybrid membranes were produced with the same method. The performances of hybrid membranes for direct methanol fuel cells (DMFCs) in terms of mechanical and thermal properties, water uptake, water retention, methanol permeability and proton conductivity were investigated. The mechanical and thermal properties of the SPEEK membranes had been improved by introduction of clay and clay-SO 3H, obviously. The water desorption coefficients of the SPEEK and hybrid membranes were studied at 80 °C. The results showed that the addition of the inorganic part into SPEEK membrane enhanced the water retention of the membrane. Both methanol permeability and proton conductivity of the hybrid membranes decreased in comparison to the pristine SPEEK membrane. However, it was worth noting that higher selectivity defined as ratio of proton conductivity to methanol permeability of the SPEEK/clay-SO 3H-1 hybrid membrane with 1 wt.% clay-SO 3H was obtained than that of the pristine SPEEK membrane. These results showed that the SPEEK/clay-SO 3H hybrid membrane with 1 wt.% clay-SO 3H had potential usage of a proton exchange membrane (PEM) for DMFCs.

  7. The effect of water purification systems on fluoride content of drinking water

    Directory of Open Access Journals (Sweden)

    Prabhakar A


    Full Text Available Objective: The purpose of the present study was to determine the effect of different water purification systems on the fluoride content of drinking water and to compare the efficacy of these water purification systems in reducing the fluoride content. Materials and Methods: Five different water purification systems were tested in this study. They were reverse osmosis, distillation, activated carbon, Reviva ® , and candle filter. The water samples in the study were of two types, viz, borewell water and tap water, these being commonly used by the people of Davangere City, Karnataka. The samples were collected before and after purification, and fluoride analysis was done using fluoride ion-specific electrode. Results: The results showed that the systems based on reverse osmosis, viz, reverse osmosis system and Reviva ® showed maximum reduction in fluoride levels, the former proving to be more effective than the latter; followed by distillation and the activated carbon system, with the least reduction being brought about by candle filter. The amount of fluoride removed by the purification system varied between the system and from one source of water to the other. Interpretation and Conclusion: Considering the beneficial effects of fluoride on caries prevention; when drinking water is subjected to water purification systems that reduce fluoride significantly below the optimal level, fluoride supplementation may be necessary. The efficacy of systems based on reverse osmosis in reducing the fluoride content of water indicates their potential for use as defluoridation devices.

  8. Cations extraction of sandy-clay soils from cavado valley, portugal, using sodium salts solutions

    Directory of Open Access Journals (Sweden)

    Silva João Eudes da


    Full Text Available Cases of contamination by metals in the water wells of the Cavado Valley in north-west Portugal can be attributed to the heavy leaching of clay soils due to an excess of nitrogen resulting from the intensive use of fertilisers in agricultural areas. This work focuses on the natural weathering characteristics of soils, particularly the clay material, through the study of samples collected near the River Cavado. Samples taken from various sites, after physico-chemical characterisation, were subjected to clay dissolution tests, using sodium salts of different ionic forces, to detect the relationship between certain physico-chemical parameters of water, such as pH, nitrate, chloride and sulphate content, in the dissolution of clay and the subsequent extraction of such cations as Al, Fe and K. In acidic sandy clay soils, the mineralogical composition of which was characterised by a predominance of quartz, micas, kaolinite and K-feldspars, decreases of the clay material/water pH ratio increases dissolution of the micaceous and K-feldspars phases. The presence of nitrates in the aqueous solution apparently advanced the extraction of all three cations Al, Fe and K. The specific surface area of the clay material showed a significant correlation with the main kinetic parameters of cation extraction.

  9. Effects of leachate infiltration and desiccation cracks on hydraulic conductivity of compacted clay

    Directory of Open Access Journals (Sweden)

    Jun HE


    Full Text Available Both cracks in clay liner and the complex composition of landfill leachate might have effects on the hydraulic conductivity of a compacted clay liner. In this study, the hydraulic conductivities of natural cl