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Sample records for city hydrothermal field

  1. Interactions Between Serpentinization, Hydrothermal Activity and Microbial Community at the Lost City Hydrothermal Field

    Science.gov (United States)

    Delacour, A.; Frueh-Green, G. L.; Bernasconi, S. M.; Schaeffer, P.; Frank, M.; Gutjahr, M.; Kelley, D. S.

    2008-12-01

    Seafloor investigations of slow- and ultraslow-spreading ridges have reported many occurrences of exposed mantle peridotites and gabbroic rocks on the ocean floor. Along the Mid-Atlantic Ridge, these uplifted portions of oceanic crust host high-temperature black smoker-type hydrothermal systems (e.g., Rainbow, Logatchev, Saldanha), and the more distinct low-temperature Lost City Hydrothermal Field (LCHF). Built on a southern terrace of the Atlantis Massif, the LCHF is composed of carbonate-brucite chimneys that vent alkaline and low-temperature (40-90°C) hydrothermal fluids. These fluids are related to serpentinization of mantle peridotites, which together with minor gabbroic intrusions form the basement of the LCHF. Long-lived hydrothermal activity at Lost City led to extensive seawater-rock interaction in the basement rocks, as indicated by seawater-like Sr- and mantle to unradiogenic Nd-isotope compositions of the serpentinites. These high fluid fluxes in the southern part of the massif influenced the conditions of serpentinization and have obliterated the early chemical signatures in the serpentinites, especially those of carbon and sulfur. Compared to reducing conditions commonly formed during the first stages of serpentinization, serpentinization at Lost City is characterized by relatively oxidizing conditions resulting in a predominance of magnetite, the mobilization/dissolution and oxidation of igneous sulfides to secondary pyrite, and the incorporation of seawater sulfate, all leading to high bulk-rock S-isotope compositions. The Lost City hydrothermal fluids contain high concentrations in methane, hydrogen, and low-molecular weight hydrocarbons considered as being produced abiotically. In contrast, organic compounds in the serpentinites are dominated by the occurrences of isoprenoids (pristane, phytane, and squalane), polycyclic compounds (hopanes and steranes), and higher abundances of C16 to C20 n-alkanes indicative of a marine organic input. We

  2. Features of trace metal distribution in the components of the ecosystem of the Lost City hydrothermal vent field (North Atlantic)

    Science.gov (United States)

    Demina, L. L.; Lein, A. Yu.; Galkin, S. V.; Lisitzin, A. P.

    2015-12-01

    The biogeochemical features of the microelement distribution in the components of the ecosystem of the Lost City low-temperature field of the Mid-Atlantic Ridge are determined by the processes of serpentinization in ultrabasic rocks. In the Lost City biotope water, the concentration of trace metals (Fe, Mn, Zn, Cu, Cd, Ni, Cr, Pb, and As) is from n × 10 to 104 times higher than in the ocean water. The microelement content demonstrates a similar character of distribution in both types of calcite biominerals forming the carbonate matrix of the bivalve mussels Bathymodiolus and the scleractinian corals Anthozoa.

  3. Microbial Diversity of Carbonate Chimneys at the Lost City Hydrothermal Field: Implications for Life-Sustaining Systems in Peridotite Seafloor Environments

    Science.gov (United States)

    Schrenk, M. O.; Cimino, P.; Kelley, D. S.; Baross, J. A.

    2002-12-01

    The Lost City Hydrothermal Field (LCHF) is a novel peridotite-hosted vent environment discovered in Dec. 2000 at 30 N near the Mid-Atlantic Ridge. This field contains multiple large (up to 60 m), carbonate chimneys venting high pH (9-10), moderate temperature (45-75 C) fluids. The LCHF is unusual in that it is located on 1.5 my-old oceanic crust, 15 km from the nearest spreading axis. Hydrothermal flow in this system is believed to be driven by exothermic serpentinization reactions involving iron-bearing minerals in the underlying seafloor. The conditions created by such reactions, which include significant quantities of dissolved methane and hydrogen, create habitats for microbial communities specifically adapted to this unusual vent environment. Ultramafic, reducing hydrothermal environments like the LCHF may be analogous to geologic settings present on the early Earth, which have been suggested to be important for the emergence of life. Additionally, the existence of hydrothermal environments far away from an active spreading center expands the range of potential life-supporting environments elsewhere in the solar system. To study the abundance and diversity of microbial communities inhabiting the environments that characterize the LCHF, carbonate chimney samples were analyzed by microscopic and molecular methods. Cell densities of between 105 and 107 cells/g were observed within various samples collected from the chimneys. Interestingly, 4-11% of the microbial population in direct contact with vent fluids fluoresced with Flavin-420, a key coenzyme involved in methanogenesis. Enrichment culturing from chimney material under aerobic and anaerobic conditions yielded microorganisms in the thermophilic and mesophilic temperature regimes in media designed for methanogenesis, methane-oxidation, and heterotrophy. PCR analysis of chimney material indicated the presence of both Archaea and Eubacteria in the carbonate samples. SSU rDNA clone libraries constructed from the

  4. Metal ion effects on the kinetics of abiotic formation of glycylglycine and diketopiperazine under the simulated conditions of the Lost City hydrothermal field

    Science.gov (United States)

    Sakata, K.; Yabuta, H.

    2010-12-01

    Introduction: The Lost City hydrothermal field has been recently discovered in 2000 and known for its characteristic conditions that differs from the typical hydrothermal vents, such as alkaline pH, low temperature (> ~90°C), metal ion compositions [1, 2]. The hydrothermal system is suggested as a plausible environment for the origin and evolution of life in the early Earth [3]. In our previous study, it was revealed that the dimerization of glycine (Gly) in aqueous solution reached the maximum rate in alkaline solution at pH 9.8 [4], supporting the above hypothesis from the perspective of abiotic chemistry. In this study, the heating experiments of Gly were conducted under the conditions simulating the metal ion composition of the Lost City, in order to evaluate the effects of metal ions on the kinetics of the formation of glycylglycine (GlyGly) and diketopiperazine (DKP). Experimental: Eight milliliter of 100 mM aqueous solutions of Gly at pH 9.3 with MgCl2 : MgSO4 : CaCl2 : NaCl : NaOH concentration ratio (mM) of 9.4 : 4.6 : 23 : 35 : 470 (solution A) were put into Teflon bottles and heated at 120, 140, 160 and 180°C for 1 to 5 days. For comparison, 100 mM aqueous solutions of Gly at pH 9.3 with 32 mM NaOH (solution B) and at pH 6.0 without NaOH (solution C) were heated at 140°C for 14 days. After heating, each sample was diluted and analyzed by HPLC. In this experiment, the four reaction pathways were considered: 2 Gly → GlyGly (the second order), GlyGly → DKP (the first order), DKP → GlyGly (the first order), GlyGly → 2 Gly (the first order). The rate constants were determined by fitting the changes of the concentrations of Gly, GlyGly, and DKP with increasing heating time. Results and discussion: The concentration of GlyGly in solution A at equilibrium was 25 % lower than that in solution B, although the formation rates of GlyGly were similar values for solutions A and B, 1.25 ×10-9 and 0.93 ×10-9 l mol-1 s-1, respectively. This observation is

  5. Magnetic exploration of a low-temperature ultramafic-hosted hydrothermal site (Lost City, 30°N, MAR)

    Science.gov (United States)

    Szitkar, Florent; Tivey, Maurice A.; Kelley, Deborah S.; Karson, Jeffrey A.; Früh-Green, Gretchen L.; Denny, Alden R.

    2017-03-01

    A 2003 high-resolution magnetic survey conducted by the Autonomous Underwater Vehicle ABE over the low-temperature, ultramafic-hosted hydrothermal field Lost City reveals a weak positive magnetic anomaly. This observation is in direct contrast to recent observations of strong positive magnetic anomalies documented over the high-temperature ultramafic-hosted hydrothermal vents fields Rainbow and Ashadze, which indicates that temperature may control the production of magnetization at these sites. The Lost City survey provides a unique opportunity to study a field that is, to date, one of a kind, and is an end member of ultramafic-hosted hydrothermal systems. Our results highlight the key contribution of temperature on magnetite production resulting from serpentinization reactions. Whereas high temperature promotes significant production and partitioning of iron into magnetite, low temperature favors iron partitioning into various alteration phases, resulting in a magnetite-poor rock. Moreover, the distribution of magnetic anomalies confirms results of a previous geological survey indicating the progressive migration of hydrothermal activity upslope. These discoveries contribute to the results of 25 yrs of magnetic exploration of a wide range of hydrothermal sites, from low- to high-temperature and from basalt- to ultramafic-hosted, and thereby validate using high-resolution magnetics as a crucial parameter for locating and characterizing hydrothermal sites hosting unique chemosynthetic-based ecosystems and potentially mineral-rich deposits.

  6. Evolving patterns of the fluids within the TAG hydrothermal field

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The mixing of seawater/hydrothermal fluid within the large seafloor hydrothermal sulfide deposits plays a key role in the formation processes of the sulfide deposits.Some issues attract considerable attentions in the study of seafloor hydrothermal system in recent years,such as the relationships among different types of vent fluids,the characteristics of chemical compositions and mineral assemblages of the hydrothermal deposits and their governing factors.Combined with the measured data of hydrothermal fluid in the TAG field,the thermodynamic model of mixing processes of the heated seawater at different temperatures and the hydrothermal fluid is calculated to understand the precipitation mechanism of anhydrite and the genetic relationships between the black and white smoker fluids within the TAG mound.The results indicate that the heating of seawater and the mixing of hydrothermal fluid/seawater are largely responsible for anhydrite precipitation and the temperature of the heated seawater is not higher than 150 ℃ and the temperature of the end-member hydrothermal fluid is not lower than 400℃.Based on the simulated results,the evolving patterns of fluids within the TAG deposit are discussed.The mixed fluid of the end-member hydrothermal fluid and the seawater heated by wall rock undergoes conductive cooling during upflowing within the deposit and forms "White Smoker" eventually.In addition,the end-member hydrothermal fluid without mixed with seawater,but undergoing conductive cooling,vents out of the deposit and forms "Black Smoker".

  7. 230Th/238U dating of hydrothermal sulfides from Duanqiao hydrothermal field, Southwest Indian Ridge

    Science.gov (United States)

    Yang, Weifang; Tao, Chunhui; Li, Huaiming; Liang, Jin; Liao, Shili; Long, Jiangping; Ma, Zhibang; Wang, Lisheng

    2016-11-01

    Duanqiao hydrothermal field is located between the Indomed and Gallieni fracture zones at the central volcano, at 50°28'E in the ultraslow-spreading Southwest Indian Ridge (SWIR). Twenty-eight subsamples from a relict chimney and massive sulfides were dated using the 230Th/238U method. Four main episodes of hydrothermal activity were determined according to the restricted results: 68.9-84.3, 43.9-48.4, 25.3-34.8, and 0.7-17.3 kyrs. Hydrothermal activity of Duanqiao probably started about 84.3 (±0.5) kyrs ago and ceased about 0.737 (±0.023) kyrs ago. The periodic character of hydrothermal activity may be related to the heat source provided by the interaction of local magmatism and tectonism. The estimated mean growth rate of the sulfide chimney is Dragon Flag field is much more recent than that of Duanqiao or Mt. Jourdanne fields. The massive sulfides are younger than the sulfides from other hydrothermal fields such as Rainbow, Sonne and Ashadze-2. The preliminarily estimated reserves of sulfide ores of Duanqiao are approximately 0.5-2.9 million tons.

  8. Dodo Field and Solitaire Field: Newly Discovered Hydrothermal Fields at the Central Indian Ridge

    Science.gov (United States)

    Tamaki, K.; Shipboard Scientists Of Yk09-13 Leg1 Cruise

    2010-12-01

    In October 2009, we conducted seafloor reconnaissance by means of a manned deep-sea submersible vehicle (DSV) Shikai6500 in two regions of the Central Indian Ridge (CIR) 18 deg-20’S and successfully discovered two active hydrothermal sites; one is the Dodo field at the Dodo Great Lava Plain (CIR Segment 16 at 18 deg 20’S ) and the other is the Solitaire Field at the Roger Plateau (Segment 15 at 19 deg 33’S). The black smoker fluids in the Dodo field exhibit unusually high concentrations of H2 in spite of the slightly brine-enriched feature of the fluids. Chemosynthetic faunal communities in the Dodo field are emaciated in size and composition. The Solitaire field is characterized by extensive diffusing flows throughout the field, suggesting that the emission patterns of the hydrothermal fluids were atypical among the CIR hydrothermal systems known so far including the Dodo field. The most outstanding feature was the prosperous macrofaunal communities that potentially contained the almost entire members of macrofaunal genera found in the CIR hydrothermal environments and even previously unexplored animal members (e.g., Alvinellidae polychaetes). Moreover, a new morphotype of scaly foot gastropod, of which one type has been known only in the Kairei field in the world, dominated the chemosynthetic animal communities in the Solitaire field. These findings provide important insights into geochemical diversity of hydrothermal activity and biodiversity and biogeography of vent-endemic ecosystem in the Indian Ocean.

  9. Fluid mixing and the deep biosphere of a fossil Lost City-type hydrothermal system at the Iberia Margin.

    Science.gov (United States)

    Klein, Frieder; Humphris, Susan E; Guo, Weifu; Schubotz, Florence; Schwarzenbach, Esther M; Orsi, William D

    2015-09-29

    Subseafloor mixing of reduced hydrothermal fluids with seawater is believed to provide the energy and substrates needed to support deep chemolithoautotrophic life in the hydrated oceanic mantle (i.e., serpentinite). However, geosphere-biosphere interactions in serpentinite-hosted subseafloor mixing zones remain poorly constrained. Here we examine fossil microbial communities and fluid mixing processes in the subseafloor of a Cretaceous Lost City-type hydrothermal system at the magma-poor passive Iberia Margin (Ocean Drilling Program Leg 149, Hole 897D). Brucite-calcite mineral assemblages precipitated from mixed fluids ca. 65 m below the Cretaceous paleo-seafloor at temperatures of 31.7 ± 4.3 °C within steep chemical gradients between weathered, carbonate-rich serpentinite breccia and serpentinite. Mixing of oxidized seawater and strongly reducing hydrothermal fluid at moderate temperatures created conditions capable of supporting microbial activity. Dense microbial colonies are fossilized in brucite-calcite veins that are strongly enriched in organic carbon (up to 0.5 wt.% of the total carbon) but depleted in (13)C (δ(13)C(TOC) = -19.4‰). We detected a combination of bacterial diether lipid biomarkers, archaeol, and archaeal tetraethers analogous to those found in carbonate chimneys at the active Lost City hydrothermal field. The exposure of mantle rocks to seawater during the breakup of Pangaea fueled chemolithoautotrophic microbial communities at the Iberia Margin, possibly before the onset of seafloor spreading. Lost City-type serpentinization systems have been discovered at midocean ridges, in forearc settings of subduction zones, and at continental margins. It appears that, wherever they occur, they can support microbial life, even in deep subseafloor environments.

  10. Subseafloor fluid mixing and fossilized microbial life in a Cretaceous 'Lost City'-type hydrothermal system at the Iberian Margin

    Science.gov (United States)

    Klein, F.; Humphris, S. E.; Guo, W.; Schubotz, F.; Schwarzenbach, E. M.; Orsi, W.

    2015-12-01

    Subseafloor mixing of reduced hydrothermal fluids with seawater is believed to provide the energy and substrates needed to support autotrophic microorganisms in the hydrated oceanic mantle (serpentinite). Despite the potentially significant implications for the distribution of microbial life on Earth and other water-bearing planetary bodies, our understanding of such environments remains elusive. In the present study we examined fossilized microbial communities and fluid mixing processes in the subseafloor of a Cretaceous 'Lost City'-type hydrothermal system at the passive Iberia Margin (ODP Leg 149, Hole 897D). Brucite and calcite co-precipitated from mixed fluids ca. 65m below the Cretaceous palaeo-seafloor at temperatures of 32±4°C within steep chemical gradients (fO2, pH, CH4, SO4, ΣCO2, etc) between weathered, carbonate-rich serpentinite breccia and serpentinite. Mixing of oxidized seawater and strongly reducing hydrothermal fluid at moderate temperatures created conditions capable of supporting microbial activity within the oceanic basement. Dense microbial colonies are fossilized in brucite-calcite veins that are strongly enriched in organic carbon but depleted in 13C. We detected a combination of bacterial diether lipid biomarkers, archaeol and archaeal tetraethers analogous to those found in brucite-carbonate chimneys at the active Lost City hydrothermal field. The exposure of mantle rocks to seawater during the breakup of Pangaea fueled chemolithoautotrophic microbial communities at the Iberia Margin during the Cretaceous, possibly before the onset of seafloor spreading in the Atlantic. 'Lost City'-type serpentinization systems have been discovered at mid-ocean ridges, in forearc settings of subduction zones and at continental margins. It appears that, wherever they occur, they can support microbial life, even in deep subseafloor environments as demonstrated in the present study. Because equivalent systems have likely existed throughout most of Earth

  11. Hydrothermal alteration in oceanic ridge volcanics: A detailed study at the Galapagos Fossil Hydrothermal Field

    Science.gov (United States)

    Ridley, W.I.; Perfit, M.R.; Josnasson, I.R.; Smith, M.F.

    1994-01-01

    The Galapagos Fossil Hydrothermal Field is composed of altered oceanic crust and extinct hydrothermal vents within the eastern Galapagos Rift between 85??49???W and 85??55???W. The discharge zone of the hydrothermal system is revealed along scarps, thus providing an opportunity to examine the uppermost mineralized, and highly altered interior parts of the crust. Altered rocks collected in situ by the submersible ALVIN show complex concentric alteration zones. Microsamples of individual zones have been analysed for major/minor, trace elements, and strontium isotopes in order to describe the complex compositional details of the hydrothermal alteration. Interlayered chlorite-smectite and chlorite with disequilibrium compositions dominate the secondary mineralogy as replacement phases of primary glass and acicular pyroxene. Phenocrysts and matrix grains of plagioclase are unaffected during alteration. Using a modification of the Gresens' equation we demonstrate that the trivalent rare earth elements (REEs) are relatively immobile, and calculate degrees of enrichment and depletion in other elements. Strontium isotopic ratios increase as Sr concentrations decrease from least-altered cores to most-altered rims and cross-cutting veins in individual samples, and can be modeled by open system behaviour under low fluid-rock ratio (< 10) conditions following a period of lower-temperature weathering of volcanics within the rift zone. The complex patterns of element enrichment and depletion and strontium isotope variations indicate mixing between pristine seawater and ascending hot fluids to produce a compositional spectrum of fluids. The precipitation of base-metal sulfides beneath the seafloor is probably a result of fluid mixing and cooling. If, as suggested here, the discharge zone alteration occurred under relatively low fluid-rock ratios, then this shallow region must play an important role in determining the exit composition of vent fluids in marine hydrothermal systems

  12. Model approach to the management of the Tianjin hydrothermal field, China

    Energy Technology Data Exchange (ETDEWEB)

    Brandi, G.P.; Ceccarelli, A.; Di Paola, G.M.; Fengzhong, L.; Pizzi, G.

    1986-01-01

    The Tianjin hydrothermal field is located in the northeastern part of the North China basin, 130 km SE of Bejing, and covers an area of about 3500 km/sup 2/ including the city of Tianjin and its suburbs. The hot waters of the Tianjin field are contained in a four-acquifer/three-aquitary multilayered hydrothermal system. The quasi-three-dimensional finite element flow model of the field has been developed utilizing IGROSS (interconnected ground-water systems simulation program). The finite element grid network consists of 7514 triangular aquifer elements and 9160 linear aquitard elements. Steady-state model calibration was made with reference to the natural state of the system prior to its industrial exploitation (in 1970). Transient model calibration was made by reproducing the history of exploitation in the period 1970-82. The good quality of the field data permitted an accurate system identification. The most suitable future exploitation of the hydrothermal system has been selected from five different exploitation hypotheses simulated over the period 1982-2010.

  13. Constraints on the Lost City Hydrothermal System from borehole thermal data; 3-D models of heat flow and hydrothermal circulation in an oceanic core complex.

    Science.gov (United States)

    Titarenko, S.; McCaig, A. M.

    2014-12-01

    A perennial problem in near-ridge hydrothermal circulation is that the only directly measurable data to test models is often vent fluid temperature. Surface heat flow measurements may be available but without the underlying thermal structure it is not known if they are transient and affected by local hydrothermal flow, or conductive. The Atlantis Massif oceanic core complex at 30 °N on the mid-Atlantic Ridge, offers a unique opportunity to better constrain hydrothermal circulation models. The temperature profile in gabbroic rocks of IODP Hole 1309D was measured in IODPExpedition 340T, and found to be near-conductive, but with a slight inflexion at ~750 mbsf indicating downward advection of fluid above that level. The lack of deep convection is especially remarkable given that the long-lived Lost City Hydrothermal Field (LCHF) is located only 5km to the south. We have modelled hydrothermal circulation in the Massif using Comsol Multiphysics, comparing 2-D and 3-D topographic models and using temperature-dependent conductivity to give the best estimate of heatflow into the Massif. We can constrain maximum permeability in gabbro below 750 mbsf to 5e-17 m2. The thermal gradient in the upper part of the borehole can be matched with a permeability of 3e-14 m2 in a 750 m thick layer parallel to the surface of the massif, with upflow occurring in areas of high topography and downflow at the location of the borehole. However in 3-D the precise flow pattern is quite model dependent, and the thermal structure can be matched either by downflow centred on the borehole at lower permeability or centred a few hundred metres from the borehole at higher permeability. The borehole gradient is compatible with the longevity (>120 kyr) and outflow temperature (40-90 °C) of the LCHF either with a deep more permeable (1e-14 m2 to 1e-15 m2) domain beneath the vent site in 2-D or a permeable fault slot 500 to 1000m wide and parallel to the transform fault in 3-D. In both cases topography

  14. An authoritative global database for active submarine hydrothermal vent fields

    Science.gov (United States)

    Beaulieu, Stace E.; Baker, Edward T.; German, Christopher R.; Maffei, Andrew

    2013-11-01

    The InterRidge Vents Database is available online as the authoritative reference for locations of active submarine hydrothermal vent fields. Here we describe the revision of the database to an open source content management system and conduct a meta-analysis of the global distribution of known active vent fields. The number of known active vent fields has almost doubled in the past decade (521 as of year 2009), with about half visually confirmed and others inferred active from physical and chemical clues. Although previously known mainly from mid-ocean ridges (MORs), active vent fields at MORs now comprise only half of the total known, with about a quarter each now known at volcanic arcs and back-arc spreading centers. Discoveries in arc and back-arc settings resulted in an increase in known vent fields within exclusive economic zones, consequently reducing the proportion known in high seas to one third. The increase in known vent fields reflects a number of factors, including increased national and commercial interests in seafloor hydrothermal deposits as mineral resources. The purpose of the database now extends beyond academic research and education and into marine policy and management, with at least 18% of known vent fields in areas granted or pending applications for mineral prospecting and 8% in marine protected areas.

  15. Carbon geochemistry of serpentinites in the Lost City Hydrothermal System (30°N, MAR)

    Science.gov (United States)

    Delacour, Adélie; Früh-Green, Gretchen L.; Bernasconi, Stefano M.; Schaeffer, Philippe; Kelley, Deborah S.

    2008-08-01

    The carbon geochemistry of serpentinized peridotites and gabbroic rocks recovered at the Lost City Hydrothermal Field (LCHF) and drilled at IODP Hole 1309D at the central dome of the Atlantis Massif (Mid-Atlantic Ridge, 30°N) was examined to characterize carbon sources and speciation in oceanic basement rocks affected by long-lived hydrothermal alteration. Our study presents new data on the geochemistry of organic carbon in the oceanic lithosphere and provides constraints on the fate of dissolved organic carbon in seawater during serpentinization. The basement rocks of the Atlantis Massif are characterized by total carbon (TC) contents of 59 ppm to 1.6 wt% and δ 13C TC values ranging from -28.7‰ to +2.3‰. In contrast, total organic carbon (TOC) concentrations and isotopic compositions are relatively constant (δ 13C TOC: -28.9‰ to -21.5‰) and variations in δ 13C TC reflect mixing of organic carbon with carbonates of marine origin. Saturated hydrocarbons extracted from serpentinites beneath the LCHF consist of n-alkanes ranging from C 15 to C 30. Longer-chain hydrocarbons (up to C 40) are observed in olivine-rich samples from the central dome (IODP Hole 1309D). Occurrences of isoprenoids (pristane, phytane and squalane), polycyclic compounds (hopanes and steranes) and higher relative abundances of n-C 16 to n-C 20 alkanes in the serpentinites of the southern wall suggest a marine organic input. The vent fluids are characterized by high concentrations of methane and hydrogen, with a putative abiotic origin of hydrocarbons; however, evidence for an inorganic source of n-alkanes in the basement rocks remains equivocal. We propose that high seawater fluxes in the southern part of the Atlantis Massif likely favor the transport and incorporation of marine dissolved organic carbon and overprints possible abiotic geochemical signatures. The presence of pristane, phytane and squalane biomarkers in olivine-rich samples associated with local faults at the central

  16. Two hydrothermal fields found on the Southern Mid-Atlantic Ridge

    Institute of Scientific and Technical Information of China (English)

    TAO ChunHui; LEI JiJiang; WANG YeJian; DY115-21 Leg 4 Science Party; LI HuaiMing; YANG YaoMin; NI JianYu; CUI RuYong; CHEN YongShun; LI JiaBiao; HE YongHua; HUANG Wei

    2011-01-01

    In recent years,a series of cruises have been launched by China Ocean Mineral Resources Research and Development Association (COMRA) to conduct hydrothermal activity investigation at mid-ocean ridges (MOR).Since the first active hydrothermal field at 49.6°E Southwest Indian Ridge (SWIR) was found in 2007 by Chinese scientists on board R/V Dayangyihao,more hydrothermal fields have been found on the SWIR and equatorial East Pacific Rise (EPR)[1-4].From November to December 2009,two new hydrothermal fields were discovered at 13°-14°S South MidAtlantic Ridge (SMAR) during Cruise DYl15-21,representing the first discovery of hydrothermal fields on the MAR for China.They are also the southernmost hydrothermal fields known on the MAR at that time.

  17. Pathways for abiotic organic synthesis at submarine hydrothermal fields.

    Science.gov (United States)

    McDermott, Jill M; Seewald, Jeffrey S; German, Christopher R; Sylva, Sean P

    2015-06-23

    Arguments for an abiotic origin of low-molecular weight organic compounds in deep-sea hot springs are compelling owing to implications for the sustenance of deep biosphere microbial communities and their potential role in the origin of life. Theory predicts that warm H2-rich fluids, like those emanating from serpentinizing hydrothermal systems, create a favorable thermodynamic drive for the abiotic generation of organic compounds from inorganic precursors. Here, we constrain two distinct reaction pathways for abiotic organic synthesis in the natural environment at the Von Damm hydrothermal field and delineate spatially where inorganic carbon is converted into bioavailable reduced carbon. We reveal that carbon transformation reactions in a single system can progress over hours, days, and up to thousands of years. Previous studies have suggested that CH4 and higher hydrocarbons in ultramafic hydrothermal systems were dependent on H2 generation during active serpentinization. Rather, our results indicate that CH4 found in vent fluids is formed in H2-rich fluid inclusions, and higher n-alkanes may likely be derived from the same source. This finding implies that, in contrast with current paradigms, these compounds may form independently of actively circulating serpentinizing fluids in ultramafic-influenced systems. Conversely, widespread production of formate by ΣCO2 reduction at Von Damm occurs rapidly during shallow subsurface mixing of the same fluids, which may support anaerobic methanogenesis. Our finding of abiogenic formate in deep-sea hot springs has significant implications for microbial life strategies in the present-day deep biosphere as well as early life on Earth and beyond.

  18. A data processing method for MAPR hydrothermal plume tur-bidity data and its application in the Precious Stone Mountain hydrothermal field

    Institute of Scientific and Technical Information of China (English)

    CHEN Sheng; TAO Chunhui; LI Huaiming; CHEN Yongshun; ZHOU Jianping; WU Tao

    2014-01-01

    Hydrothermal plume is an important constituent of seabed hydrothermal circulation and is also one of the characteristics of active hydrothermal vents. Portable Miniature Autonomous Plume Recorders (MAPR) attached to a towed deep-sea instrument was used to search for hydrothermal plumes and hydrothermal vents. We introduced the basic principle of MAPR based on deep towing technology to detect plumes, then analyzed the factors affecting the quality of the MAPR data and presented a data correction method for MAPR, including instrument location correction, noise reduction processing, system error elimination and seawater background reduction. Finally we applied the method to analyze MAPR data obtained during the Chinese DY115-21 cruise on R/VDayang Iin the “Precious Stone Mountain” hydrothermal field on the Gala-pagos Microplate. The results provided a better understanding of the distribution of the hydrothermal activ-ity in this field, indicating the presence of a new hydrothermal vent.

  19. Hydrothermal Alteration in the PACMANUS Hydrothermal Field: Implications From Secondary Mineral Assemblages and Mineral Chemistry, OPD Leg 193

    Science.gov (United States)

    Lackschewitz, K. S.; Kummetz, M.; Kummetz, M.; Ackermand, D.; Botz, R.; Devey, C. W.; Singer, A.; Stoffers, P.

    2001-12-01

    Leg 193 of the Ocean Drilling Program investigated the subsurface nature of the active PACMANUS hydrothermal field in the Manus backarc basin near Papua New Guinea. Drilling in different areas on the felsic neovolcanic Pual Ridge, including the high-temperature black smoker complex of Roman Ruins and the low-temperature Snowcap site with diffusive discharge yielded a complex alteration history with a regional primary alteration being overprinted by a secondary mineralogy. The intense hydrothermal alteration at both sites shows significant differences in the secondary mineralogy. At Roman Ruins, the upper 25 m of hydrothermally altered rocks are characterized by a rapid change from secondary cristobalite to quartz, implying a high temperature gradient. From 10 to 120 mbsf the clay mineralogy is dominated by illite and chlorite. The chlorite formation temperature calculated from oxygen isotope data lies at 250° C in 116 mbsf which is similar to the present fluid outflow temperatures of 240-250° C (Douville et al., 1999, Geochim. Cosmochim. Acta, 63, 627-643). Drilling in the Snowcap field recovered evidence for several stages of hydrothermal alteration. Between 50 and 150 mbsf, cristobalite and chlorite are the most abundant alteration minerals while hydrothermal pyrophyllite becomes abundant in some places At 67 mbsf, the isotopic composition of pyrophyllite gives a temperature for ist formation at 260° C whereas at 77 and 116 mbsf the pyrophyllite displays the highest temperatures of formation (>300° C). These temperatures are close to the maximum measured borehole temperatures of 313° C. The appearance of assemblages of chlorite, chlorite-vermiculite, chlorite-vermiculite-smectite and illite-smectite as well as the local development of corrensite below 150 mbsf suggests that the alteration at Snowcap may be more complex than that beneath Roman Ruins. Detailed geochemical studies of the authigenic clay mineral phases will provide further insights into the

  20. Microbial carbon cycling in Lost City hydrothermal chimneys and other serpentinite-hosted ecosystems (Invited)

    Science.gov (United States)

    Brazelton, W. J.; Lang, S. Q.; Morrill, P. L.; Twing, K. I.; Crespo-Medina, M.; Morgan-Smith, D.; Früh-Green, G. L.; Schrenk, M. O.

    2013-12-01

    Ultramafic rocks formed in the Earth's mantle and uplifted into the crust represent an immense but poorly described reservoir of carbon. The biological availability of this rock-hosted carbon reservoir is unknown, but the set of geochemical reactions known as serpentinization can mobilize carbon from the subsurface and trigger the growth of dense microbial communities. Serpentinite-hosted ecosystems such as the chimney biofilms of the Lost City hydrothermal field can support dense populations of bacteria and archaea fueled by the copious quantities of H2 and methane (CH4) released by serpentinization (1-5). The metabolic pathways involved, however, remain unknown, and conventional interpretations of genomic and experimental data are complicated by the unusual carbon speciation in these environments. Carbon dioxide is scarce due to the highly reducing, high pH conditions. Instead, the predominant forms of carbon are CH4 and formate (5). Despite its natural abundance, however, direct evidence for CH4-derived biomass is lacking (1,4,5), and the role of formate is potentially significant but largely unexplored (1,5). To gain a more generalized perspective of carbon cycling in serpentinite-hosted ecosystems, we have recently investigated fluids and rocks collected from serpentinizing ophiolites in California, Canada, and Italy. Our results point to potentially H2-utilizing, autotrophic Betaproteobacteria thriving in shallow, oxic-anoxic transition zones and anaerobic Clostridia inhabiting anoxic, subsurface zones (1,6). The carbon sources utilized by the Clostridia are unknown, but preliminary metagenomic evidence is consistent with a fermentation-style metabolic strategy that may be conducive to an oxidant-limited, subsurface environment. Curiously, despite the abundance of H2 and CH4 in these continental springs, none of the geochemical, genomic, or experimental results obtained thus far contain any evidence for biological methanogenesis (1,6). This is in stark

  1. Petrology and Geochemistry of Hydrothermally Altered Volcanic Rocks in the Iheya North Hydrothermal Field, Middle Okinawa Trough

    Science.gov (United States)

    Yamasaki, T.

    2015-12-01

    The Iheya North hydrothermal field is located in the middle Okinawa Trough, a young and actively spreading back-arc basin extending behind the Ryukyu arc-trench system in the southeastern margin of the East China Sea. In this hydrothermal field, two scientific drilling expeditions (IODP Exp 331 and SIP CK14-04) were conducted using a deep-sea drilling vessel "Chikyu," and samples from a total of 27 holes were taken. Through these expeditions, Kuroko-type volcanogenic massive sulfide deposits (VMS), hydrothermally altered volcanic rocks, and pumiceous and pelagic sediments were recovered. The recovered core provided important information about the relationship between hydrothermal activity, alteration, and ore mineralization. Whole-rock major element composition and trace element (TE) patterns of pumices were very similar to those of rhyolites in the middle Okinawa Trough (RMO). However, pumices were relatively enriched in chalcophile elements Sr and Nb, which suggest incipient mineralization. Volcanic rock generally demonstrated strong silicification and was greenish pale gray in color. Regardless of severe alteration, some rock displayed major element composition broadly similar to the RMO. Alteration was evidenced by an increase in the content of SiO2 and MgO, and decrease in Al2O3, Na2O, and K2O content. The most striking geochemical feature of altered volcanic rock was the discordance between texture and the degree of modification of TEs. Some samples showed decussate texture occupied by petal-like quartz with severe silicification, but no prominent disturbance of concentration and patterns of TEs were observed. In contrast, samples with well-preserved igneous porphyritic texture showed very low TE content and modification of TE patterns. These results suggest that the modification of texture and composition of TEs, as well as silicification, do not occur by a uniform process, but several processes. This may reflect the differences in temperature and the

  2. Sulfur isotopic composition of seafloor hydrothermal sediment from the Jade hydrothermal field in the central Okinawa Trough and its geological significance

    Institute of Scientific and Technical Information of China (English)

    曾志刚; 李军; 蒋富清; 翟世奎; 秦蕴珊; 侯增谦

    2002-01-01

    --Eighteen samples of hydrothermal sediments from the Jade hydrotherrnal field in the central Okinawa Trough have been analyzed. Sulfur isotopic values for 10 sulfide samples vary from 5.2 ×10-3to 7.2× 10-3, δ34S valUes for 7 sulfate samples vary from 16.3 × 10-3 to 22.3 × 10-3, and 1 native sulphur sample has a δ34S value of 8.2 × 10-3. The major sources of sulfur for hydrothermal sediment are intermediate to acid volcanic rocks and sea water sulfate, and it is possible that the partial sulfur of hydrothermal sediment is from the pelagic sediment by the interaction between hydrothermal fluid and sediment. The reasons of causing the distinct differences in sulfur isotopic values for sulfide samples from hydrothermal sediment ( compared with other hydrothermal fields), are the differences in the sources of sulfur, the magmatic activity and the tectonic evolution in different hydrothermal fields. The sulfur evolution is a long and complex process in the seafloor hydrothermal system, involving the ascending of heating sea water, the interaction between fluid and volcanic rocks, the mixing of sea water sulfate and sulfur from intermediate to acid volcanic rocks, and the fluid/pelagic-sediment interaction. And the interaction between sea water and intermediate to acid volcanic rocks is an important mechanism for the sulfur evolution in the Jade hydrothermal field.

  3. Comparison of intact polar lipid with microbial community composition of vent deposits of the Rainbow and Lucky Strike hydrothermal fields

    NARCIS (Netherlands)

    Gibson, R.A.; van der Meer, M.T.J.; Hopmans, E.C.; Reysenbach, A.-L.; Schouten, S.; Sinninghe Damsté, J.S.

    2013-01-01

    The intact polar lipid (IPL) composition of twelve hydrothermal vent deposits from the Rainbow (RHF) and Lucky Strike hydrothermal fields (LSHF) has been investigated in order to assess its utility as a proxy for microbial community composition associated with deep-sea hydrothermal locations. Gene-b

  4. Petrophysical characteristics of rocks and sulfides from the SWIR hydrothermal field

    Institute of Scientific and Technical Information of China (English)

    TAO Chunhui; WU Tao; JIN Xiaobing; DOU Bingjun; LI Huaiming; ZHOU Jianping

    2013-01-01

    Study of petrophysical properties of rocks in seafloor hydrothermal fields has great significance for inves-tigation of seafloor hydrothermal activities, especially for polymetallic sulfides prospecting. In the present study, based on the current experimental conditions, we conducted systematic experiments to measure the magnetic susceptibility, electrical resistivity, porosity, density, as well as acoustic wave velocity of seafloor rocks and sulfides. Subsequently, we measured the physical characteristics of hydrothermal sulfides, basalts and peridotites which were collected from newly discovered seafloor hydrothermal fields at 49.6°E, 50.5°E, 51°E, 63.5°E, and 63.9°E of the Southwest Indian Ridge (SWIR). Previously available and newly collected data were combined to characterize the physical differences between polymetallic sulfides and rocks. We also discussed the impact of hydrothermal alteration on the bedrock and demonstrated how these petrophysical properties of rocks can help in geophysical prospecting of seafloor hydrothermal fields as indicators.

  5. Bacterial sulfur cycle shapes microbial communities in surface sediments of an ultramafic hydrothermal vent field

    DEFF Research Database (Denmark)

    Schauer, Regina; Røy, Hans; Augustin, Nico;

    2011-01-01

    The ultramafic-hosted Logatchev hydrothermal field (LHF) is characterized by vent fluids, which are enriched in dissolved hydrogen and methane compared with fluids from basalt-hosted systems. Thick sediment layers in LHF are partly covered by characteristic white mats. In this study, these sedime......The ultramafic-hosted Logatchev hydrothermal field (LHF) is characterized by vent fluids, which are enriched in dissolved hydrogen and methane compared with fluids from basalt-hosted systems. Thick sediment layers in LHF are partly covered by characteristic white mats. In this study...

  6. Macrofaunal communites at newly discovered hydrothermal fields in Central Indian Ridge

    Science.gov (United States)

    Miyazaki, J.; Takai, K.; Nakamura, K.; Watanabe, H.; Noguchi, T.; Matsuzaki, T.; Watsuji, T.; Nemoto, S.; Kawagucci, S.; Shibuya, T.; Okamura, K.; Mochizuki, M.; Orihashi, Y.; Marie, D.; Koonjul, M.; Singh, M.; Beedessee, G.; Bhikajee, M.; Tamaki, K.

    2010-12-01

    In YK09-13 Leg1 cruise targeted on the segment 15 and 16 in Central Indian Ridge (CIR), we have successfully discovered two hydrothermal fields, DODO field and Solitaire field. We expected that there were unique macrofaunal communities in these hydrothermal fields, because there was in Kairei field on the segment 1 in CIR. Particularly, a gastropod, “scaly-foot”, which has sclerites covered with iron-sulfide has only discovered in Kairei field. Therefore, it was interesting whether this unique scaly-foot only exists in Kairei fields or widely expands in CIR. In DODO fields, there were 10 to 15 active chimneys. However, very few hydrothermal vent-endemic faunas were observed. We observed only crabs and shrimps but we did not found shells. As opposed to in the Dodo field, biomass and composition of macrofaunal communities were highly prosperous in the Solitaire field, being equal to Kairei field. Although we have an only one dive to explore the Solitaire field, many predominant taxa were sampled and observed, for example, Alviniconcha, mussels, vanacles and so on. However, the most outstanding feature was the presence of a new morphotype of ‘scaly-foot’ gastropod. Discovery of this new-morphytpe ‘scary-foot” disproved our knowledge. In this conference, I will present these observations. Especially characterization of two types of scaly-foot (Kairei-type and Solitaire-type) will be focused.

  7. Modeling Seafloor Deformation at the TAG Hydrothermal Field: Feedbacks between Permeability and Poroelastic Fluid Flow?

    Science.gov (United States)

    Crone, T. J.; Sohn, R. A.; Barreyre, T.

    2014-12-01

    Recent measurements of ocean bottom pressure suggest that hydrothermal flow induces cm-scale periodic ground surface displacement (GSD) at the Trans-Atlantic Geotraverse (TAG) hydrothermal field on the Mid-Atlantic Ridge (Sohn et al., 2009). The pressure measurements contain spectral peaks and harmonics with periods ranging from 22 to 53 min, none of which can be attributed to oceanographic or Earth tide processes. It is hypothesized that GSD cycles in this system may result from a nonlinear feedback between pore pressure and permeability in the hydrothermal system. To test this hypothesis we have developed a poroelastic convection model representing the upper crustal section at TAG that includes a "switching" type pressure-permeability feedback in the stockwork zone of the hydrothermal system. In this zone, the permeability increases when the pressure reaches a critical high value, and decreases when it reaches a critical low value. This behavior simulates the opening and closing of cracks within the hydrothermal system, and is similar to mechanisms that have been proposed for dike propagation in magmatic systems (Buck et al., 2006). Our modeling suggests that this mechanism can generate GSD that are similar to those observed at TAG. We are currently using these models to explore the sensitivity of inflation and deflation rates to system properties such as the geometry of the stockwork zone, the temperature of fluid in the upflow zone, the elastic properties of the lithosphere, and the relationship between pore pressure and permeability.

  8. Hydrothermal alteration of sediments associated with surface emissions from the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Valette-Silver, J.N.; Esquer P., I.; Elders, W.A.; Collier, P.C.; Hoagland, J.R.

    1981-01-01

    A study of the mineralogical changes associated with these hydrothermal vents was initiated with the aim of developing possible exploration tools for geothermal resources. The Cerro Prieto reservoir has already been explored by extensive deep drilling so that relationships between surface manifestations and deeper hydrothermal processes could be established directly. Approximately 120 samples of surface sediments were collected both inside and outside of the vents. The mineralogy of the altered sediments studied appears to be controlled by the type of emission. A comparison between the changes in mineralogy due to low temperature hydrothermal activity in the reservoir, seen in samples from boreholes, and mineralogical changes in the surface emission samples shows similar general trends below 180 C: increase of quartz, feldspar and illite, with subsequent disappearance of kaolinite, montmorillonite, calcite and dolomite. These mineral assemblages seem to be characteristic products of the discharge from high intensity geothermal fields.

  9. Geochemistry of hydrothermal fluids from the PACMANUS, Northeast Pual and Vienna Woods hydrothermal fields, Manus Basin, Papua New Guinea

    Science.gov (United States)

    Reeves, Eoghan P.; Seewald, Jeffrey S.; Saccocia, Peter; Bach, Wolfgang; Craddock, Paul R.; Shanks, Wayne C.; Sylva, Sean P.; Walsh, Emily; Pichler, Thomas; Rosner, Martin

    2011-01-01

    Processes controlling the composition of seafloor hydrothermal fluids in silicic back-arc or near-arc crustal settings remain poorly constrained despite growing evidence for extensive magmatic-hydrothermal activity in such environments. We conducted a survey of vent fluid compositions from two contrasting sites in the Manus back-arc basin, Papua New Guinea, to examine the influence of variations in host rock composition and magmatic inputs (both a function of arc proximity) on hydrothermal fluid chemistry. Fluid samples were collected from felsic-hosted hydrothermal vent fields located on Pual Ridge (PACMANUS and Northeast (NE) Pual) near the active New Britain Arc and a basalt-hosted vent field (Vienna Woods) located farther from the arc on the Manus Spreading Center. Vienna Woods fluids were characterized by relatively uniform endmember temperatures (273-285 degrees C) and major element compositions, low dissolved CO2 concentrations (4.4 mmol/kg) and high measured pH (4.2-4.9 at 25 degrees C). Temperatures and compositions were highly variable at PACMANUS/NE Pual and a large, newly discovered vent area (Fenway) was observed to be vigorously venting boiling (358 degrees C) fluid. All PACMANUS fluids are characterized by negative delta DH2O values, in contrast to positive values at Vienna Woods, suggesting substantial magmatic water input to circulating fluids at Pual Ridge. Low measured pH (25 degrees C) values (~2.6-2.7), high endmember CO2 (up to 274 mmol/kg) and negative delta 34SH2S values (down to -2.7 permille) in some vent fluids are also consistent with degassing of acid-volatile species from evolved magma. Dissolved CO2 at PACMANUS is more enriched in 13C (-4.1 permille to -2.3 permille) than Vienna Woods (-5.2 permille to -5.7 permille), suggesting a contribution of slab-derived carbon. The mobile elements (e.g. Li, K, Rb, Cs and B) are also greatly enriched in PACMANUS fluids reflecting increased abundances in the crust there relative to the Manus

  10. Characterization and modeling of illite crystal particles and growth mechanisms in a zoned hydrothermal deposit, Lake City, Colorado

    Science.gov (United States)

    Bove, D.J.; Eberl, D.D.; McCarty, D.K.; Meeker, G.P.

    2002-01-01

    Mean thickness measurements and crystal-thickness distributions (CTDs) of illite particles vary systematically with changes in hydrothermal alteration type, fracture density, and attendant mineralization in a large acid-sulfate/Mo-porphyry hydrothermal system at Red Mountain, near Lake City, Colorado. The hydrothermal illites characterize an extensive zone of quartz-sericite-pyrite alteration beneath two deeply rooted bodies of magmatic-related, quartz-alunite altered rock. Nineteen illites from a 3000 ft vertical drill hole were analyzed by XRD using the PVP-10 intercalation method and the computer program MudMaster (Bertaut-Warren-Averbach technique). Mean crystallite thicknesses, as determined from 001 reflections, range from 5-7 nanometers (nm) at depths from 0-1700 ft, then sharply increase to 10-16 nm at depths between 1800-2100 ft, and decrease again to 4-5 nm below this level. The interval of largest particle thickness correlates strongly with the zone of most intense quartz-sericite-pyrite alteration (QSP) and attendant high-density stockwork fracturing, and with the highest concentrations of Mo within the drill core. CTD shapes for the illite particles fall into two main categories: asymptotic and lognormal. The shapes of the CTDs are dependent on conditions of illite formation. The asymptotic CTDs correspond to a nucleation and growth mechanism, whereas surface-controlled growth was the dominant mechanism for the lognormal CTDs. Lognormal CTDs coincide with major through-going fractures or stockwork zones, whereas asymptotic CTDs are present in wallrock distal to these intense fracture zones. The increase in illite particle size and the associated zone of intense QSP alteration and stockwork veining was related by proximity to the dacitic magma(s), which supplied both reactants and heat to the hydrothermal system. However, no changes in illite polytype, which in other studies reflect temperature transitions, were observed within this interval.

  11. Decline of a Hydrothermal Vent Field - Escanaba Trough 12 Years Later

    Science.gov (United States)

    Zierenberg, R. A.; Clague, D. A.; Davis, A. S.; Lilley, M. D.; McClain, J. S.; Olson, E. S.; Ross, S. L.; Von Damm, K. L.

    2001-12-01

    Hydrothermal venting was discovered in Escanaba Trough, the southern sediment-covered portion of the Gorda Ridge, in 1988. Large pyrrhotite-rich massive sulfide mounds are abundant at each of the volcanic/intrusive centers that have been investigated in Escanaba Trough, but the only area of known hydrothermal venting is the NESCA site along the ridge axis at 41\\deg N. Hydrothermal fluids venting at 217\\deg C and 108\\deg C were sampled in 1988 on two sulfide mounds separated by about 275 m. The end-member fluid compositions were indistinguishable within analytical errors. Several sulfide mounds were observed in 1988 which had diffusely venting low temperature (holes were drilled in the NESCA area in 1996 on ODP Leg 169, including Hole 1036I that penetrated to basaltic basement at 405 m below sea floor (mbsf). Surveys of the area using the drill string camera located only one area of active venting at the same mound where 217\\deg C vent fluids were sampled from two active vents in 1988. Drill hole 1036A was spudded between the two active vents on this sulfide mound (approximately 4 and 8 m away) and penetrated to 115 mbsf. The NESCA site was revisited in 2000 using MBARI's R/V Western Flyer and ROV Tiburon. The hydrothermal vents appeared essentially identical to observations made from the drill string camera in 1996 despite the presence of a drill hole within meters of the two vents. The maximum vent temperature measured in 2000 was 212\\deg C. Fluid samples have major element and isotopic compositions very similar to those collected in 1988. The vent fluids have higher methane ( ~19 mmol/kg) than those from the geologically similar Middle Valley vent field, but lower values than those at Guaymas Basin. Drill hole 1036A was weakly venting, but the diffuse hydrothermal fluids could not be sampled with the equipment available. The walls of the drill hole were colonized by palm worms, limpets, and snails. Four other drill holes showed no hydrothermal flow nor

  12. Characteristics of Sr, Nd and Pb isotopic compositions of hydrothermal Si-Fe-Mn-oxyhydroxides at the PACMANUS hydrothermal field, Eastern Manus Basin

    Institute of Scientific and Technical Information of China (English)

    YANG Baoju; ZENG Zhigang; WANG Xiaoyuan

    2015-01-01

    Si-Fe-Mn-oxyhydroxides dredged at the PACMANUS (Papua New Guinea–Australia–Canada–Manus) hydrothermal field, Eastern Manus Basin, have87Sr/86Sr=0.708 079–0.708 581;εNd=5.149 833–6.534 826;208Pb/204Pb=38.245–38.440;207Pb/204Pb=15.503–15.560;206Pb/204Pb=18.682–18.783.87Sr/86Sr isotope ratios are relatively homogeneous and close to the value of the surrounding seawater (0.709 16). The content of Sr in the samples contributed by seawater was estimated to be 76.7%–83.1% of total amount. The mixing temperature of hydrothermal fluids and seawater were ranging from 53.2°C to 72.2°C and the hydrothermal activities were unstable when the samples precipitated. TheεNd values of all the samples are positive, which differ from the values of ferromanganese nodules (crusts) with hydrogenic origin. Nd was mainly derived from substrate rocks leached by hydrothermal circulation and preserved the hydrothermal signature. Pb isotopic compositions of most samples show minor variability except Sample #9–2 that has relatively high values of Pb isotopes. The Pb may be derived from the Eastern Manus Basin rocks leached by the hydrothermal fluid. The slightly lower208Pb/204Pb and 207Pb/204Pb values of the samples indicated that the hydrothermal circulation in PACMANUS was not entire and sufficient, or that hydrothermal circulation had transient changes in the past. Si-Fe-Mn-oxyhydroxides in the samples preserved the heterogeneities of local rocks.

  13. On the global distribution of hydrothermal vent fields: One decade later

    Science.gov (United States)

    Beaulieu, S. E.; Baker, E. T.; German, C. R.

    2012-12-01

    Since the last global compilation one decade ago, the known number of active submarine hydrothermal vent fields has almost doubled. At the end of 2009, a total of 518 active vent fields was catalogued, with about half (245) visually confirmed and others (273) inferred active at the seafloor. About half (52%) of these vent fields are at mid-ocean ridges (MORs), 25% at volcanic arcs, 21% at back-arc spreading centers (BASCs), and 2% at intra-plate volcanoes and other settings. One third are in high seas, and the nations with the most known active vent fields within EEZs are Tonga, USA, Japan, and New Zealand. The increase in known vent fields reflects a number of factors, including increased national and commercial interests in seafloor hydrothermal deposits as mineral resources. Here, we have comprehensively documented the percentage of strike length at MORs and BASCs that has been systematically explored for hydrothermal activity. As of the end of 2009, almost 30% of the ~60,000 km of MORs had been surveyed at least with spaced vertical profiles to detect hydrothermal plumes. A majority of the vents discovered at MORs in the past decade occurred at segments with Antarctic Ridge, and the intermediate spreading Pacific-Antarctic Ridge. Although a greater percentage of the ~11,000 km of BASCs has been surveyed for hydrothermal activity, the discoveries at BASCs in the past decade were mainly at segments with intermediate to fast spreading rates. Using the same equation for F_s vs. u_s, we predicted 71 vent fields remaining to be discovered at BASCs, and most are likely to be found at ultra-slow and slow spreading segments (e.g., Andaman Basin, and central to northern Mariana Trough). With 2/3 of our overall predicted total vent fields at spreading ridges remaining to be discovered, we expect that the next decade of exploration will continue to yield new discoveries, leading to new insights into biogeography of vent fauna and the global impacts of fluxes of heat and

  14. Diffuse-flow hydrothermal field in an oceanic fracture zone setting, Northeast Pacific: Deposit composition

    Science.gov (United States)

    Hein, J.R.; Koski, R.A.; Embley, R.W.; Reid, J.; Chang, S.-W.

    1999-01-01

    This is the first reported occurrence of an active hydrothermal field in an oceanic fracture zone setting. The hydrothermal field occurs in a pull-apart basin within the Blanco Fracture Zone (BFZ), which has four distinct mineral deposit types: (1) barite mounds and chimneys, (2) barite stockwork breccia, (3) silica-barite beds, and (4) silica, barite, and Fe-Mn oxyhydroxide in sediments. All deposit types contain minor amounts of sulfides. In barite stockwork, silica-barite beds, and mineralized sediment, Ba, Ph, Ag, S, Au, Zn, Cu, Hg, TI, As, Mo, Sb, U, Cd, and Cu are enriched relative to unmineralized rocks and sediments of the BFZ. Fe and Mn are not enriched in the barite stockwork or silica-barite beds, but along with P, Co, and Mg are enriched in the mineralized sediments. Silver contents in deposits of the hydrothermal field range up to 86 ppm, gold to 0.7 ppm, zinc to 3.2%, copper to 0.8%, and barium to 22%. Mineralization occurred by diffuse, low to intermediate temperature (mostly Metallurgy and Petroleum. All rights reserved.

  15. Hydrothermal surface alteration in the Copahue Geothermal Field (Argentina)

    Energy Technology Data Exchange (ETDEWEB)

    Mas, Graciela R.; Mas, Luis C.; Bengochea, Leandro

    1996-01-24

    In the area of the Copahue Geothermal Field, there are five active geothermal manifestations, which mainly consist of fumaroles, hot springs and mud pots. Four of these manifestations are located in Argentina: Las Máquinas, Termas de Copahue, Las Maquinitas and El Anfiteatro, and the fifth on the Chilean side: Chancho Co. All of them present a strong acid sulfate country rock alteration, characterized by the assemblage alunite + kaolinite + quartz + cristobalite + pyrite + sulfur + jarosite, as the result of the base leaching by fluids concentrated in H2SO4 by atmospheric oxidation at the water table in a steam heated environment of H2S released by deeper boiling fluids. Another alteration zone in this area, called COP-2, is a fossil geothermal manifestation which shows characteristics of neutral to alkaline alteration represented mainly by the siliceous sinter superimposed over the acid alteration. The mineralogy and zoning of these alteration zones, and their relation with the hidrothermal solutions and the major structures of the area are analized.

  16. Bacterial and archaeal diversity in an iron-rich coastal hydrothermal field in Yamagawa, Kagoshima, Japan

    DEFF Research Database (Denmark)

    Kawaichi, Satoshi; Ito, Norihiro; Yoshida, Takashi;

    2013-01-01

    . The environmental settings of the coastal hydrothermal field were similar in some degree to those of deep-sea hydrothermal environments because of its emission of H2, CO2, and sulfide from the bottom of the hot spot. The results of clone analyses based on the 16S rRNA gene led us to speculate the presence...... of a chemo-synthetic microbial ecosystem, where chemolithoautotrophic thermophiles, primarily the bacterial order Aquificales, function as primary producers using H2 or sulfur compounds as their energy source and CO2 as their carbon source, and the organic compounds synthesized by them support the growth...... of chemoheterotrophic thermophiles, such as members of the order Thermales and the family Desulfurococcaceae. In addition, the dominance of members of the bacterial genus Herbaspirillum in the high temperature bottom layer led us to speculate the temporal formation of mesophilic zones where they can also function...

  17. Arsenic bioaccumulation and biotransformation in deep-sea hydrothermal vent organisms from the PACMANUS hydrothermal field, Manus Basin, PNG

    Science.gov (United States)

    Price, Roy E.; Breuer, Christian; Reeves, Eoghan; Bach, Wolfgang; Pichler, Thomas

    2016-11-01

    Hydrothermal vents are often enriched in arsenic, and organisms living in these environments may accumulate high concentrations of this and other trace elements. However, very little research to date has focused on understanding arsenic bioaccumulation and biotransformation in marine organisms at deep-sea vent areas; none to date have focused organisms from back-arc spreading centers. We present for the first time concentration and speciation data for As in vent biota from several hydrothermal vent fields in the eastern Manus basin, a back-arc basin vent field located in the Bismark Sea, western Pacific Ocean. The gastropods Alviniconcha hessleri and Ifremeria nautilei, and the mussel Bathymodiolus manusensis were collected from diffuse venting areas where pH was slightly lower (6.2-6.8), and temperature (26.8-10.5 °C) and arsenic concentrations (169.5-44.0 nM) were higher than seawater. In the tissues of these organisms, the highest total measured As concentrations were in the gills of A. hessleri (5580 mg kg-1), with 721 mg kg-1 and 43 mg kg-1 in digestive gland and muscle, respectively. I. nautilei contained 118 mg kg-1 in the gill, 108 mg kg-1 in the digestive gland and 22 mg kg-1 in the muscle. B. manusensis contained 15.7 mg kg-1 in the digestive gland, followed by 9.8 mg kg-1 and 4.5 mg kg-1 in its gill and muscle tissue, respectively. We interpret the decreasing overall total concentrations in each organism as a function of distance from the source of hydrothermally derived As. The high concentration of arsenic in A. hessleri gills may be associated with elemental sulfur known to occur in this organism as a result of symbiotic microorganisms. Arsenic extracted from freeze-dried A. hessleri tissue was dominated by AsIII and AsV in the digestive gland (82% and 16%, respectively) and gills (97% AsIII, 2.3% AsV), with only 1.8% and 0.2% arsenobetaine (As-Bet) in the digestive gland and gills, respectively. However, the muscle contained substantial amounts of

  18. Geology, sulfide geochemistry and supercritical venting at the Beebe Hydrothermal Vent Field, Cayman Trough

    Science.gov (United States)

    Webber, Alexander P.; Roberts, Stephen; Murton, Bramley J.; Hodgkinson, Matthew R. S.

    2015-09-01

    The Beebe Vent Field (BVF) is the world's deepest known hydrothermal system, at 4960 m below sea level. Located on the Mid-Cayman Spreading Centre, Caribbean, the BVF hosts high temperature (˜401°C) "black smoker" vents that build Cu, Zn and Au-rich sulfide mounds and chimneys. The BVF is highly gold-rich, with Au values up to 93 ppm and an average Au:Ag ratio of 0.15. Gold precipitation is directly associated with diffuse flow through "beehive" chimneys. Significant mass-wasting of sulfide material at the BVF, accompanied by changes in metal content, results in metaliferous talus and sediment deposits. Situated on very thin (2-3 km thick) oceanic crust, at an ultraslow spreading centre, the hydrothermal system circulates fluids to a depth of ˜1.8 km in a basement that is likely to include a mixture of both mafic and ultramafic lithologies. We suggest hydrothermal interaction with chalcophile-bearing sulfides in the mantle rocks, together with precipitation of Au in beehive chimney structures, has resulted in the formation of a Au-rich volcanogenic massive sulfide (VMS) deposit. With its spatial distribution of deposit materials and metal contents, the BVF represents a modern day analogue for basalt hosted, Au-rich VMS systems.

  19. He, Ne and Ar isotope compositions of fluid inclusions in hy-drothermal sulfides from the TAG hydrothermal field, Mid-Atlantic Ridge

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Helium, neon and argon isotope compositions of fluid inclusionshave been measured in hydrothermal sulfide samples from the TAG hydrothermal field at the Mid-Atlantic Ridge. Fluid-inclusion 3He/4He ratios are 2.2-13.3 times the air value (Ra), and with a mean of 7.2 Ra. Com-parison with the local vent fluids (3He/4He=7.5-8.2 Ra) and mid-ocean ridge basalt values (3He/4He=6-11 Ra) shows that the variation range of 3He/4He ratios from sulfide-hosted fluid inclu-sions is significantly large. Values for 20Ne/22Ne are from 10.2 to 11.4, which are significantly higher than the atmospheric ratio (9.8). And fluid-inclusion 40Ar/36Ar ratios range from 287 to 359, which are close to the atmospheric values (295.5). These results indicate that the noble gases of fluid inclu-sions in hydrothermal sulfides are a mixture of mantle- and seawater-derived noble gases; the partial mantle-derived components of trapped hydrothermal fluids may be from the lower mantle; the helium of fluid inclusions is mainly from upper mantle; and the Ne and Ar components are mainly from seawater.

  20. Testing of the recently developed tectonomagmatic discrimination diagrams from hydrothermally altered igneous rocks of 7 geothermal fields

    OpenAIRE

    PANDARINATH, Kailasa

    2014-01-01

    Recently developed multidimensional tectonomagmatic discrimination diagrams based on log-ratio variables of chemical elements, discordant outlier-free databases, and probability-based boundaries have been shown to work better than the earlier diagrams. Hydrothermally altered drilled well rock cuttings obtained from different depths of geothermal fields were used to test these diagrams to compare the inferred tectonic setting with the expected one. In spite of the hydrothermal alteration effec...

  1. He, Ne and Ar isotope compositions of fluid inclusions in hy-drothermal sulfides from the TAG hydrothermal field, Mid-Atlantic Ridge

    Institute of Scientific and Technical Information of China (English)

    ZENG; Zhigang; (

    2001-01-01

    [1]Rona, P. A. , Klinkhammer, G. , Nelsen, T. A. et al. , Black smokers, massive sulphides and vent biota at the Mid-Atlantic Ridge, Nature, 1986, 321: 33.[2]Edmonds, H. N. , German, C. R. , Green, D. R. H. et al. , Continuation of the hydrothermal fluid chemistry time series at TAG, and the effects of ODP drilling, Geophys. Res. Lett., 1996, 23: 3487.[3]Charlou, J. L. , Donval, J. P. , Jean-Baptiste, P. et al. , Gases and helium isotopes in high temperature solutions sampled before and after ODP Leg158 drilling at TAG hydrothermal field (26°N, MAR), Geophys. Res. Lett., 1996, 23: 3491. [4]Rudnicki, M. D. , Elderfield, H. , Helium, radon and manganese at the TAG and Snakepit hydrothermal vent fields, 26°and 23°N, Mid-Atlantic Ridge, Earth Planet. Sci. Lett., 1992, 113: 307. [5]Butterfield, D. A. , Massoth, G. J. , McDuff, R. E. et al. , Geochemistry of fluids from Axial Seamount hydrothermal emissions study vent field, Juan de Fuca Ridge: Subseafloor boiling and subsequent fluid-rock interaction, Journal of Geophysical Research, 1990, 95: 12895. [6]Baker, E. T. , Lupton, J. E. , Changes in submarine hydrothermal 3He/heat ratios as an indicator of magmatic/tectonic activity, Nature, 1990, 346: 556. [7]Jean-Baptiste, P. , Fouquet, Y. , Abundance and isotopic composition of helium in hydrothermal sulfides from the East Pacific Rise at 13°N, Geochimica et Cosmochimica Acta, 1996, 60: 87. [8]Stuart, F. M. , Turner, G. , Duckworth, R. C. et al. , Helium isotopes as tracers of trapped hydrothermal fluids in ocean-floor sulfides, Geology, 1994, 22: 823. [9]Stuart, F. M. , Duckworth, R. , Turner, G. et al. , Helium and sulfur isotopes in sulfide minerals from Middle Valley, Northern Juan de Fuca Ridge, Proceedings of the Ocean Drilling Program, Scientific Results, 1994, 139: 387. [10]Turner, G. , Stuart, F. , Helium/heat ratios and deposition temperatures of sulphides from the ocean floor, Nature, 1992, 357: 581.[11

  2. Field-emission stability of hydrothermally synthesized aluminum-doped zinc oxide nanostructures.

    Science.gov (United States)

    Hsieh, Tsang-Yen; Wang, Jyh-Liang; Yang, Po-Yu; Hwang, Chuan-Chou; Shye, Der-Chi

    2012-07-01

    The Al-doped ZnO (AZO) nanostructures field-emission arrays (FEAs) were hydrothermally synthesized on AZO/glass substrate. The samples with Al-dosage of 3 at.% show the morphology as nanowires vertically grown on the substrates and a structure of c-axis elongated single-crystalline wurtzite. The good field-emission (i.e., the large anode current and low fluctuation of 15.9%) can be found by AZO nanostructure FEAs with well-designed Al-dosage (i.e., 3 at.%) because of the vertical nanowires with the less structural defects and superior crystallinity. Moreover, the Full width at half maximum (FWHM) of near band-edge emission (NBE) decreased as the increase of annealing temperature, representing the compensated structural defects during oxygen ambient annealing. After the oxygen annealing at 500 degrees C, the hydrothermal AZO nanostructure FEAs revealed the excellent electrical characteristics (i.e., the larger anode current and uniform distribution of induced fluorescence) and enhanced field-emission stability (i.e., the lowest current fluctuation of 5.97%).

  3. High-resolution near-bottom vector magnetic anomalies over Raven Hydrothermal Field, Endeavour Segment, Juan de Fuca Ridge

    Science.gov (United States)

    Tivey, Maurice A.; Johnson, H. Paul; Salmi, Marie S.; Hutnak, Michael

    2014-10-01

    High-resolution, near-bottom vector magnetic data were collected by remotely operated vehicle Jason over the Raven hydrothermal vent field (47°57.3'N 129°5.75'W) located north of Main Endeavour vent field on the Endeavour segment of the Juan de Fuca Ridge. The survey was part of a comprehensive heat flow study of the Raven site using innovative thermal blanket technology to map the heat flux and crustal fluid pathways around a solitary hydrothermal vent field. Raven hydrothermal activity is presently located along the western axial valley wall, while additional inactive hydrothermal deposits are found to the NW on the upper rift valley wall. Magnetic inversion results show discrete areas of reduced magnetization associated with both active and inactive hydrothermal vent deposits that also show high conductive heat flow. Higher spatial variability in the heat flow patterns compared to the magnetization is consistent with the heat flow reflecting the currently active but ephemeral thermal environment of fluid flow, while crustal magnetization is representative of the static time-averaged effect of hydrothermal alteration. A general NW to SE trend in reduced magnetization across the Raven area correlates closely with the distribution of hydrothermal deposits and heat flux patterns and suggests that the fluid circulation system at depth is likely controlled by local crustal structure and magma chamber geometry. Magnetic gradient tensor components computed from vector magnetic data improve the resolution of the magnetic anomaly source and indicate that the hydrothermally altered zone directly beneath the Raven site is approximately 15 × 106 m3 in volume.

  4. Stable Electron Field Emission from CeO2 Nanowires by Hydrothermal Method

    Institute of Scientific and Technical Information of China (English)

    FU Xing-Qiu; FENG Ping; WANG Chong; WANG Tai-Hong

    2007-01-01

    @@ CeO2 nanowires are successful synthesized by hydrothermal method and their field emission (FE) properties are investigated. The turn-on electric field is 5.8 V/μm at an emitter-anode spacing of 700μm. The FE current is stable and the current fluctuations are less than 3% over 5 h. All the plotted Fowler-Nordheim curves yield straight lines, which are in agreement with the Fowler-Nordheim theory. The relationship between the field enhancement factorβ and the emitter-anode spacing d follows a universal equation. Our results imply that the CeO2 nanowires are promising materials for fabricating FE cathodes.

  5. Chemical and biological interactions in the Rose Garden hydrothermal vent field, Galapagos spreading center

    Science.gov (United States)

    Johnson, Kenneth S.; Childress, James J.; Hessler, Robert R.; Sakamoto-Arnold, Carole M.; Beehler, Carl L.

    1988-10-01

    The concentrations of a suite of redox reactive chemicals were measured in the Rose Garden hydrothermal vent field of the Galapagos spreading center. Sulfide, silicate, oxygen and temperature distributions were measured in situ with a submersible chemical analyser. In addition, 15 chemical species were measured in discrete samples. Variability in the slope of the temperature-silicate plots indicates that heat is lost from these relatively low temperatures (<15°C) solutions by conduction to the solid phase. Consumption of oxygen, sulfide and nitrate from the hydrothermal solution as it flows past the vent animals is apparent from the distributions measured in situ and in the discrete samples. The fraction of sulfide and nitrate removed from the solution by consumption appears to have increased between 1979-1985. Sulfide and oxygen appear to be consumed under different conditions: sulfide is removed primarily from the warmest solutions, and oxygen is consumed only from the cold seawater. This separation may be driven primarily by the increased gradients of each chemical under these conditions. There is no evidence for the consumption of significant amounts of manganese(II) by the vent organisms. The analysis of other data sets from this vent field indicate no significant consumption of methane by the vent organisms, as well.

  6. The Lost City hydrothermal system: Constraints imposed by vent fluid chemistry and reaction path models on subseafloor heat and mass transfer processes

    Science.gov (United States)

    Seyfried, W. E.; Pester, Nicholas J.; Tutolo, Benjamin M.; Ding, Kang

    2015-08-01

    Since the first reported discovery of the Lost City hydrothermal system in 2001, it was recognized that seawater alteration of ultramafic rocks plays a key role in the composition of the coexisting vent fluids. The unusually high pH and high concentrations of H2 and CH4 provide compelling evidence for this. Here we report the chemistry of hydrothermal fluids sampled from two vent structures (Beehive: ∼90-116 °C, and M6: ∼75 °C) at Lost City in 2008 during cruise KNOX18RR using ROV Jason 2 and R/V Revelle assets. The vent fluid chemistry at both sites reveals considerable overlap in concentrations of dissolved gases (H2, CH4), trace elements (Cs, Rb, Li, B and Sr), and major elements (SO4, Ca, K, Na, Cl), including a surprising decrease in dissolved Cl, suggesting a common source fluid is feeding both sites. The absence of Mg and relatively high concentrations of Ca and sulfate suggest solubility control by serpentine-diopside-anhydrite, while trace alkali concentrations, especially Rb and Cs, are high, assuming a depleted mantle protolith. In both cases, but especially for Beehive vent fluid, the silica concentrations are well in excess of those expected for peridotite alteration and the coexistence of serpentine-brucite at all reasonable temperatures. However, both the measured pH and silica values are in better agreement with serpentine-diopside-tremolite-equilibria. Geochemical modeling demonstrates that reaction of plagioclase with serpentinized peridotite can shift the chemical system away from brucite and into the tremolite stability field. This is consistent with the complex intermingling of peridotite and gabbroic bodies commonly observed within the Atlantis Massif. We speculate the existence of such plagioclase bearing peridotite may also account for the highly enriched trace alkali (Cs, Rb) concentrations in the Lost City vent fluids. Additionally, reactive transport modeling taking explicit account of temperature dependent rates of mineral

  7. Detection of methane plumes in the water column of Logatchev hydrothermal vent field, Mid-Atlantic Ridge

    Institute of Scientific and Technical Information of China (English)

    ZHOU HuaiYang; WU ZiJun; PENG XiaoTong; JIANG Lei; TANG Song

    2007-01-01

    During DY105-17 cruise onboard the R/V "Da Yang Yi Hao" in 2005, methane concentrations in the water column above Logachev hydrothermal vent field were measured by applying stripping/trapping-gas chromatographic (GC) and the distinct methane plumes were detected. Results show that the background methane concentration within the Logachev area is from 1.05 nmol/L to 1.68 nmol/L, significantly higher than the background level of the Atlantic abyssal plain of 0.4-0.5 nmol/L, suggesting that hydrothermal venting is a major source of dissolved methane to the ocean. The highest anomalies of methane concentrations in the water column range from 7.14 nmol/L to 113.9 nmol/L and occur just at 180-500 m above the seafloor. The distribution of methane concentration and the structural characteristics of hydrothermal plumes are strongly influenced by the supply of underlying hydrothermal fluids, the mixing process of ocean bottom currents and the microbial oxidation. Furthermore, the differences in distribution of methane plume between the station MAR-CTD3 and the other stations indicate a probable unknown hydrothermal vent site nearby. There occurs high concentration of methane along with temperature and nephelometry anomalies, which strongly confirms that the subtle measurement of methane concentration in water column is one of the effective ways to locate active sites of hydrothermal venting.

  8. Replacive sulfide formation in anhydrite chimneys from the Pacmanus hydrothermal field, Papua New Guinea

    Science.gov (United States)

    Los, Catharina; Bach, Wolfgang; Plümper, Oliver

    2016-04-01

    Hydrothermal flow within the oceanic crust is an important process for the exchange of energy and mass between the lithosphere, hydrosphere and biosphere. Infiltrated seawater heats up and interacts with wall rock, causing mineral replacement reactions. These play a large role in the formation of ore deposits; at the discharge zone, a hot, acidic and metal-rich potential ore fluid exits the crust. It mixes with seawater and forms chimneys, built up of sulfate minerals such as anhydrite (CaSO4), which are subsequently replaced by sulfide minerals. Sulfide formation is related to fluid pathways, defined by cracks and pores in the sulfate chimney. Over time, these systems might develop into massive sulfide deposits. The big question is then: how is sulfate-sulfide replacement related to the evolution of rock porosity? To address this question, sulfide-bearing anhydrite chimneys from the Pacmanus hydrothermal field (Manus Basin, Papua New Guinea) were studied using X-ray tomography, EMPA, FIB-SEM and -TEM. The apparently massive anhydrite turns out highly porous on the micro scale, with sulfide minerals in anhydrite cleavage planes and along grain boundaries. The size of the sulfide grains relates to the pores they grew into, suggesting a tight coupling between dissolution (porosity generation) and growth of replacive minerals. Some of the sulfide grains are hollow and apparently used the dissolving anhydrite as a substrate to start growth in a pore. Another mode of sulfide development is aggregates of euhedral pyrite cores surrounded by colloform chalcopyrite. This occurrence implies that fluid pathways have remained open for some time to allow several stages of precipitation during fluid evolution. To start the replacement and to keep it going, porosity generation is crucial. Our samples show that dissolution of anhydrite occurred along pathways where fluid could enter, such as cleavage planes and grain boundaries. It appears that fluids ascending within the inner

  9. Mapping the Piccard Hydrothermal Field - The World's Deepest Known Vent Area

    Science.gov (United States)

    Kinsey, J. C.; German, C. R.

    2012-12-01

    We report the recent mapping and exploration of the Piccard Hydrothermal Field on the Mid-Cayman Rise. Two previous expeditions in 2009 and 2010 led to the discovery of the site, which at 5000m hosts the world's deepest known vents. The site was mapped and explored in January 2012 and the Piccard Field was found to be larger than previously appreciated. The site includes 3 separate currently active hydrothermal mounts together with 4 additional extinct depo-centers. The 3 active centers are the Beebe Vents, Beebe Woods, and Beebe Sea sites. Beebe Vents is an active black smoker system with maximum temperatures of 400-403 degrees Celsius. Beebe Woods contains a set of tall beehive smokers with temperatures of approximately 353 degrees Celsius. Beebe Sea, the largest sulfide mound in the field, contains diffuse venting together with numerous extinct chimneys that indicate significant past active focused flow. Observations of the 4 extinct mounds indicate differences in their apparent ages based on the texture and morphology of the extinct sulfides at the summit of each mound. The entire field is located on top of an axial volcanic ridge with extrusive pillow mounds prominent. A major fault traverses the mound along its long axis, from Southwest to Northeast. Beebe Woods, Beebe Sea, and extinct Beebe mound D abut this fault directly with an apparent monotonic age progression from youngest (Beebe Woods) in the SW to relict mound 'D' in the NE. Similarly, the Beebe Vents site and mound is located at the SW limit of a parallel set of mounds, offset from the fault by approximately 100m, which also ages progressively through extinct Beebe Mounds 'E', 'F' and 'G'. The major fault that bisects the axial volcanic ridge at Piccard evidently serves as a controlling mechanism for the mounds abutting that fault however the mechanism for the second line of mounds remains to be determined. Bathymetry suggests the presence of a second, smaller fault which may serve as the control

  10. Geophysical Images of the Shallow Hydrothermal Degassing at Solfatara (Phlegrean Fields, Italy)

    Science.gov (United States)

    Byrdina, S.; Vandemeulebrouck, J.; Cardellini, C.; Chiodini, G.; Legaz, A.; Camerlynck, C.; Lebourg, T.

    2014-12-01

    We present the results of an electric resistivity tomography (ERT) survey, combined with mappings of diffuse carbon dioxide flux, ground temperature and self-potential (SP) at Solfatara, the most active crater of Phlegrean Fields. Solfatara is characterized by an intense carbon dioxide degassing, fumarole activity, and ground deformation. This ensemble of methods is applied to image the hydrothermal system of Solfatara, to understand the geometry of the fluid circulation, and to define the extension of the hydrothermal plume at a high enough resolution for a quantitative modeling. ERT inversion results show Solfatara as a globally conductive structure, with resistivity in the range 1-200 Ohmm. Broad negative anomaly of self-potential in the inner part of Solfatara with a minimum in the area of Bocca Grande suggests a significant downward flow of condensing liquid water. Comparison between spatial variations of resistivity and gas flux indicates that resistivity changes at depth are related to gas saturation and fluid temperature. These variations delineate two plume structures: a liquid-dominated conductive plume below Fangaia mud-pool and a gas-dominated plume below Bocca Grande fumarole. The geometry of the Fangaia liquid-saturated plume is also imaged by a high resolution 3-D resistivity model. In order to estimate the permeability, we propose a 2-D axis-symmetric numerical model coupling Richards's equation for fluid flow in conditions of partial saturation with the resistivity calculation as function of saturation only. Alternatively, we apply the Dupuit equation to estimate the permeability of the shallow layer. Using these two approaches, we obtain the permeability of the shallow layer below Fangaia which ranges between (2 - 4) 10-14 m 2.

  11. Quantifying dispersal from hydrothermal vent fields in the western Pacific Ocean.

    Science.gov (United States)

    Mitarai, Satoshi; Watanabe, Hiromi; Nakajima, Yuichi; Shchepetkin, Alexander F; McWilliams, James C

    2016-03-15

    Hydrothermal vent fields in the western Pacific Ocean are mostly distributed along spreading centers in submarine basins behind convergent plate boundaries. Larval dispersal resulting from deep-ocean circulations is one of the major factors influencing gene flow, diversity, and distributions of vent animals. By combining a biophysical model and deep-profiling float experiments, we quantify potential larval dispersal of vent species via ocean circulation in the western Pacific Ocean. We demonstrate that vent fields within back-arc basins could be well connected without particular directionality, whereas basin-to-basin dispersal is expected to occur infrequently, once in tens to hundreds of thousands of years, with clear dispersal barriers and directionality associated with ocean currents. The southwest Pacific vent complex, spanning more than 4,000 km, may be connected by the South Equatorial Current for species with a longer-than-average larval development time. Depending on larval dispersal depth, a strong western boundary current, the Kuroshio Current, could bridge vent fields from the Okinawa Trough to the Izu-Bonin Arc, which are 1,200 km apart. Outcomes of this study should help marine ecologists estimate gene flow among vent populations and design optimal marine conservation plans to protect one of the most unusual ecosystems on Earth.

  12. Spectral reflectance analysis of hydrothermal alteration in drill chips from two geothermal fields, Nevada

    Science.gov (United States)

    Lamb, A. K.; Calvin, W. M.

    2010-12-01

    We surveyed drill chips with a lab spectrometer in the visible-near infrared (VNIR) and short-wave infrared (SWIR) regions, 0.35-2.5 μm, to evaluate hydrothermal alteration mineralogy of samples from two known geothermal fields in western Nevada. Rock is fractured into small pieces or “chips” during drilling and stored in trays by depth interval. The drill chips are used to determine subsurface properties such as lithology, structure, and alteration. Accurately determining alteration mineralogy in the geothermal reservoir is important for indicating thermal fluids (usually associated with fluid pathways such as faults) and the highest temperature of alteration. Hydrothermal minerals, including carbonates, iron oxides, hydroxides, sheet silicates, and sulfates, are especially diagnostic in the VNIR-SWIR region.. The strength of reflectance spectroscopy is that it is rapid and accurate for differentiating temperature-sensitive minerals that are not visually unique. We examined drill chips from two western Nevada geothermal fields: Hawthorne (two wells) and Steamboat Springs (three wells) using an ASD lab spectrometer with very high resolution. The Steamboat Hills geothermal field has produced electricity since 1988 and is well studied, and is believed to be a combination of extensional tectonics and magmatic origin. Bedrocks are Cretaceous granodiorite intruding into older metasediments. Hot springs and other surface expressions occur over an area of about 2.6 km2. In contrast, the Hawthorne geothermal reservoir is a ‘blind’ system with no surface expressions such as hot springs or geysers. The geothermal field is situated in a range front fault zone in an extensional area, and is contained in Mesozoic mixed granite and meta-volcanics. We collected spectra at each interval in the chip trays. Interval length varied between 10’ and 30’. - Endmember analysis and mineral identification were performed -using standard analysis approaches used to map mineralogy

  13. Field guide to hydrothermal alteration in the White River altered area and in the Osceola Mudflow, Washington

    Science.gov (United States)

    John, David A.; Rytuba, James J.; Ashley, Roger P.; Blakely, Richard J.; Vallance, James W.; Newport, Grant R.; Heinemeyer, Gary R.

    2003-01-01

    The Cenozoic Cascades arcs of southwestern Washington are the product of long-lived, but discontinuous, magmatism beginning in the Eocene and continuing to the present (for example, Christiansen and Yeats, 1992). This magmatism is the result of subduction of oceanic crust beneath the North American continent. The magmatic rocks are divided into two subparallel, north-trending continental-margin arcs, the Eocene to Pliocene Western Cascades, and the Quaternary High Cascades, which overlies, and is east of, the Western Cascades. Both arcs are calc-alkaline and are characterized by voluminous mafic lava flows (mostly basalt to basaltic andesite compositions) and scattered large stratovolcanoes of mafic andesite to dacite compositions. Silicic volcanism is relatively uncommon. Quartz diorite to granite plutons are exposed in more deeply eroded parts of the Western Cascades Arc (for example, Mount Rainier area and just north of Mt. St. Helens). Hydrothermal alteration is widespread in both Tertiary and Quaternary igneous rocks of the Cascades arcs. Most alteration in the Tertiary Western Cascades Arc resulted from hydrothermal systems associated with small plutons, some of which formed porphyry copper and related deposits, including copper-rich breccia pipes, polymetallic veins, and epithermal gold-silver deposits. Hydrothermal alteration also is present on many Quaternary stratovolcanoes of the High Cascades Arc. On some High Cascades volcanoes, this alteration resulted in severely weakened volcanic edifices that were susceptible to failure and catastrophic landslides. Most notable is the sector collapse of the northeast side of Mount Rainier that occurred about 5,600 yr. B.P. This collapse resulted in formation of the clay-rich Osceola Mudflow that traveled 120 km down valley from Mount Rainier to Puget Sound covering more than 200 km2. This field trip examines several styles and features of hydrothermal alteration related to Cenozoic magmatism in the Cascades arcs

  14. A seismic anisotropy study of the Dragon Flag hydrothermal field (49°39'E ) on the Southwest Indian Ridge

    Science.gov (United States)

    Zhang, J.; Zhao, M.; Tong, V. C. H.; Qiu, X.

    2015-12-01

    Dragon Flag hydrothermal field located at 49°39'E on the Southwest Indian Ridge contains the active hydrothermal vents firstly discovered on the ultraslow spreading ridge (Tao et al, 2012). Anisotropic study in this area will provide important information tectonic activities. 65634 traveltime residuals from the three-dimensional isotropic inversion (Zhao et al., 2013), were divided into three groups, which correspond to quasi ocean crustal Layer 2 (qL2), quasi ocean crustal Layer 3 (qL3) and quasi uppermost mantle (qUM), respectively. Traveltime residuals at different depths show that there are obvious cosine relationships between traveltime residuals and azimuth of qL2, qL3 and qUM, indicating anisotropy existed in both crust and mantle beneath Dragon Flag hydrothermal field. The best fitted cosine curves indicate that the fast directions (negative traveltime residuals) corresponding to the general trend of ridge axis of N104°E. According to these results, we propose that there may be prevalent cracks penetrating into lower crust or even uppermost mantle. We argue that the hydrothermal convection of Dragon Flag hydrothermal field not only occurs perpendicular to ridge axis, but also occurs parallel to ridge axis. We reveal for the first time anisotropic characteristics of the ultraslow spreading ridge, which has profound scientific significance for the future research on global ocean lithospheric anisotropy. This research was granted by the Natural Science Foundation of China (91028002, 41176053, 91428204). Keywords: ultraslow spreading ridge, Southwest Indian Ridge, Dragon Flag hydrothermal field, P wave traveltime residuals, anisotropy References: Tao C H, Lin J, Guo S, et al. First active hydrothermal vents on an ultraslow-spreading center: Southwest Indian Ridge. Geology, 2012, 40(1): 47~50. Zhao M H, Qiu X L, Li J B, et al. Three-dimensional seismic structure of the Dragon Flag oceanic core complex at the ultraslow spreading Southwest Indian Ridge (49°39

  15. Arsenic speciation in sinter mineralization from a hydrothermal channel of El Tatio geothermal field, Chile

    Science.gov (United States)

    Alsina, Marco A.; Zanella, Luciana; Hoel, Cathleen; Pizarro, Gonzalo E.; Gaillard, Jean-François; Pasten, Pablo A.

    2014-10-01

    El Tatio geothermal field is the principal natural source of arsenic for the Loa River, the main surface water resource in the hyper-arid Atacama Desert (Antofagasta Region, Northern Chile). Prior investigations by bulk X-ray absorption spectroscopy have identified hydrous ferric oxides as the principal arsenic-containing phase in sinter material from El Tatio, suggesting sorption as the main mechanism for arsenic scavenging by the solid phases of these hot spring environments. Here we examine siliceous sinter material sampled from a hydrothermal channel using synchrotron based X-ray micro-probe techniques, including As and Fe Kα X-ray fluorescence (μ-XRF), As K-edge X-ray absorption near edge structure (μ-XANES), and X-ray diffraction (μ-XRD). Least-squares linear fitting of μ-XANES spectra shows that arsenic is predominantly present as arsenate sorbed on hydrous ferric oxides (63% molar proportion), but we also identify nodular arsenide micro-mineralizations (37% molar proportion) similar to loellingite (FeAs2), not previously detected during bulk-scale analysis of the sinter material. Presence of arsenide mineralizations indicates development of anoxic environments on the surface of the siliceous sinter, and suggests a more complex biogeochemistry for arsenic than previously observed for circum-neutral pH brine hot spring environments.

  16. Temporal and spatial variation in temperature experienced by macrofauna at Main Endeavour hydrothermal vent field

    Science.gov (United States)

    Lee, Raymond W.; Robert, Katleen; Matabos, Marjolaine; Bates, Amanda E.; Juniper, S. Kim

    2015-12-01

    A significant focus of hydrothermal vent ecological studies has been to understand how species cope with various stressors through physiological tolerance and biochemical resistance. Yet, the environmental conditions experienced by vent species have not been well characterized. This objective requires continuous observations over time intervals that can capture environmental variability at scales that are relevant to animals. We used autonomous temperature logger arrays (four roughly parallel linear arrays of 12 loggers spaced every 10-12 cm) to study spatial and temporal variations in the thermal regime experienced by hydrothermal vent macrofauna at a diffuse flow vent. Hourly temperatures were recorded over eight months from 2010 to 2011 at Grotto vent in the Main Endeavour vent field on the Juan de Fuca Ridge, a focus area of the Ocean Networks Canada cabled observatory. The conspicuous animal assemblages in video footage contained Ridgeia piscesae tubeworms, gastropods (primarily Lepetodrilus fucensis), and polychaetes (polynoid scaleworms and the palm worm Paralvinella palmiformis). Two dimensional spatial gradients in temperature were generally stable over the deployment period. The average temperature recorded by all arrays, and in some individual loggers, revealed distinctive fluctuations in temperature that often corresponded with the tidal cycle. We postulate that this may be related to changes in bottom currents or fluctuations in vent discharge. A marked transient temperature increase lasting over a period of days was observed in April 2011. While the distributions and behavior of Juan de Fuca Ridge vent invertebrates may be partially constrained by environmental temperature and temperature tolerance, except for the one transient high-temperature event, observed fluid temperatures were generally similar to the thermal preferences for some species, and typically well below lethal temperatures for all species. Average temperatures of the four arrays

  17. Geochemical characteristics of sinking particles in the Tonga arc hydrothermal vent field, southwestern Pacific

    Science.gov (United States)

    Kim, Hyung Jeek; Kim, Jonguk; Pak, Sang Joon; Ju, Se-Jong; Yoo, Chan Min; Kim, Hyun Sub; Lee, Kyeong Yong; Hwang, Jeomshik

    2016-10-01

    Studies of sinking particles associated with hydrothermal vent fluids may help us to quantify mass transformation processes between hydrothermal vent plumes and deposits. Such studies may also help us understand how various types of hydrothermal systems influence particle flux and composition. However, the nature of particle precipitation out of hydrothermal vent plumes in the volcanic arcs of convergent plate boundaries has not been well studied, nor have the characteristics of such particles been compared with the characteristics of sinking particles at divergent boundaries. We examined sinking particles collected by sediment traps for about 10 days at two sites, each within 200 m of identified hydrothermal vents in the south Tonga arc of the southwestern Pacific. The total mass flux was several-fold higher than in the non-hydrothermal southwest tropical Pacific. The contribution of non-biogenic materials was dominant (over 72%) and the contribution of metals such as Fe, Mn, Cu, and Zn was very high compared to their average levels in the upper continental crust. The particle flux and composition indicate that hydrothermal authigenic particles are the dominant source of the collected sinking particles. Overall, our elemental ratios are similar to observations of particles at the divergent plate boundary in the East Pacific Rise (EPR). Thus, the nature of the hydrothermal particles collected in the south Tonga arc is probably not drastically different from particles in the EPR region. However, we observed consistent differences between the two sites within the Tonga arc, in terms of the contribution of non-biogenic material, the radiocarbon content of sinking particulate organic carbon, the ratios of iron to other metals (e.g. Cu/Fe and Zn/Fe), and plume maturity indices (e.g. S/Fe). This heterogeneity within the Tonga arc is likely caused by differences in physical environment such as water depth, phase separation due to subcritical boiling and associated sub

  18. Mineralizing Filamentous Bacteria from the Prony Bay Hydrothermal Field Give New Insights into the Functioning of Serpentinization-Based Subseafloor Ecosystems

    Science.gov (United States)

    Pisapia, Céline; Gérard, Emmanuelle; Gérard, Martine; Lecourt, Léna; Lang, Susan Q.; Pelletier, Bernard; Payri, Claude E.; Monnin, Christophe; Guentas, Linda; Postec, Anne; Quéméneur, Marianne; Erauso, Gaël; Ménez, Bénédicte

    2017-01-01

    Despite their potential importance as analogs of primitive microbial metabolisms, the knowledge of the structure and functioning of the deep ecosystems associated with serpentinizing environments is hampered by the lack of accessibility to relevant systems. These hyperalkaline environments are depleted in dissolved inorganic carbon (DIC), making the carbon sources and assimilation pathways in the associated ecosystems highly enigmatic. The Prony Bay Hydrothermal Field (PHF) is an active serpentinization site where, similar to Lost City (Mid-Atlantic Ridge), high-pH fluids rich in H2 and CH4 are discharged from carbonate chimneys at the seafloor, but in a shallower lagoonal environment. This study aimed to characterize the subsurface microbial ecology of this environment by focusing on the earliest stages of chimney construction, dominated by the discharge of hydrothermal fluids of subseafloor origin. By jointly examining the mineralogy and the microbial diversity of the conduits of juvenile edifices at the micrometric scale, we find a central role of uncultivated bacteria belonging to the Firmicutes in the ecology of the PHF. These bacteria, along with members of the phyla Acetothermia and Omnitrophica, are identified as the first chimneys inhabitants before archaeal Methanosarcinales. They are involved in the construction and early consolidation of the carbonate structures via organomineralization processes. Their predominance in the most juvenile and nascent hydrothermal chimneys, and their affiliation with environmental subsurface microorganisms, indicate that they are likely discharged with hydrothermal fluids from the subseafloor. They may thus be representative of endolithic serpentinization-based ecosystems, in an environment where DIC is limited. In contrast, heterotrophic and fermentative microorganisms may consume organic compounds from the abiotic by-products of serpentinization processes and/or from life in the deeper subsurface. We thus propose that

  19. Conditions of Formation of Secondary Quartz in Hydrothermally Altered, Subsurface Dacite beneath the Deep-Sea PACMANUS Hydrothermal Field, Manus Basin, Papua New Guinea

    Science.gov (United States)

    Vanko, D. A.; Wicker, S. G.; Binns, R. A.

    2006-05-01

    New fluid inclusion (FI) data from secondary quartz within the altered felsic rocks underlying the PACMANUS hydrothermal field provide additional constraints on the thermal conditions and fluid salinities accompanying hydrothermal alteration. PACMANUS, at a water depth of about 1650 to 1700 m on the summit of the neovolcanic Pual Ridge in the eastern part of the Manus backarc basin, is an active seafloor system situated in a felsic volcanic setting at a convergent plate boundary. Two sites of active venting - Roman Ruins, with high-temperature (220-276° C) sulfide chimneys, and Snowcap, which is an area of lower-temperature (6- 65° C) diffuse flow - were cored during Ocean Drilling Program Leg 193. Drilling reached sub-seafloor depths of 387 m at Snowcap and 206 m at Roman Ruins. At both Snowcap and Roman Ruins, fresh dacite/rhyodacite is underlain by highly to completely altered rocks with clays (illite, illite-smectite, chlorite, and mixed layer clays), disseminated pyrite, silica and late stage anhydrite. At shallow depths the silica is mostly cristobalite, whereas quartz is the polymorph at depth. Secondary quartz occurs in amygdules, alone or with accessory anhydrite and pyrite; in cm-scale granular nodules; and as tiny grains forming an open mosaic with interstitial clays and pore space. Scarce FI in secondary quartz are small (10-20μ), irregular, and contain liquid (L) plus vapor. Only a few are arrayed along healed fractures, and most are interpreted as primary. FI from Snowcap homogenize to L between 290° C and 390° C. Ice melting temperatures vary between about -10° C and -0.4° C, with most ice melting near -2.0° C. Thus, while most FI have near-seawater salinities, a significant number are much more saline, while others are much less saline, approaching fresh water. FI from Roman Ruins homogenize between 257° C and 370° C, and ice melting temperatures vary from about -14° C to -1.2° C. These data are best explained if the hydrothermal

  20. Morphology of cone-fields in SW Elysium Planitia - Traces of hydrothermal venting on Mars?

    Science.gov (United States)

    Lanz, J. K.; Saric, M. B.

    2008-09-01

    Introduction Small cone-shaped features with summit pits can be found in several regions on Mars; mainly in Isidis Planitia; Elysium Planitia; Amazonis Planitia; Acidalia Planitia; in the Cydonia Region; in Cerberus Planum; the Phlegra Montes and on several volcanic flanks. They vary greatly in size and morphology and have been compared to terrestrial features of various origins; namely (1) cinder cones (e.g. [1]), (2) tuff cones or tuff rings (e.g. [2]), (3) rootless cones (pseudocraters) (e.g. [3], [4]), (4) pingos (e.g. [5], [6]) and (5) mud volcanoes (e.g. [7]). They are often found near volcanic centers and large lava fields or cluster in regions where the volatile content of the Martian regolith was/is supposedly high. This has led to the assumption that (ground-) water or ground ice was a trigger or driving force of cone formation. They could therefore, be an important indicator of the history of water on the planet. We have studied an area in western Elysium Planitia, bordering the Aeolis Planum plateau, which exhibits a large number of pitted cones, ridges and dome-like structures. Their distribution and morphology differs strongly from pitted cones elsewhere in Elysium Planitia, which have mainly been interpreted as hydrovolcanic rootless cones, and from other regions on Mars. Based on our observations, we present an alternative model for cone formation in the study area that might hint towards hydrothermal processes in the Aeolis Planum region and possibly young igneous activity. Aeolis Planum Cones The Aeolis Planum pitted cones (referred to as APCs from now on) cluster along the southern edges of the broad shallow valley that borders the Aeolis Planum Formation (APF) to the north. Cones along the northern edges of the valley are rare and can only be found in association with APF remnants where they strongly resemble the cones in the south. Along the southern border the cone coverage is almost continuous, describing a narrow band approximately 2 to 3 km

  1. Hydrothermal Alteration in Submarine Basaltic Rocks from the Reykjanes Geothermal Field, Iceland. (Invited)

    Science.gov (United States)

    Zierenberg, R. A.; Schiffman, P.; Fowler, A. P.; Marks, N.; Fridleifsson, G.; Elders, W. A.

    2013-12-01

    The Iceland Deep Drilling Project (IDDP) is preparing to drill to 4-5 km in the Reykjanes Geothermal Field to sample geothermal fluids at supercritical temperature and pressure for power generation. The Reykjanes geothermal field is the on-land extension of the Reykjanes Ridge spreading center. The upper 1-2 kilometers drilled at Reykjanes are submarine basalts and basaltic sediments, hyalloclastites, and breccias, with an increasing proportion of basaltic intrusive rocks below 2 km depth. Geothermal fluids are evolved seawater with a composition similar to mid-ocean ridge hydrothermal systems. Zn- and Cu-rich sulfide scale, locally enriched in Au and Ag, are deposited in production pipes. The sulfide deposits are compositionally and isotopically similar to seafloor massive sulfides. In anticipation of deeper drilling, we have investigated the mineralogy and geochemistry of drill cuttings from a 3 km deep well (RN-17). The depth zoning of alteration minerals is similar to that described from other Icelandic geothermal fields, and is comparable to observed seafloor metamorphic gradients in ODP drill holes and ophiolites. Chlorite-epidote alteration occurs at depths >400 m and passes downhole through epidote-actinolite alteration and into amphibole facies (hornblende-calcic plagioclase) alteration below 2.5 km. Local zones of high temperature (>800°C), granoblastic-textured, pyroxene hornfels, are interpreted to form by contact metamorphism during dike/sill emplacement. Similar granoblasically altered basalts were recovered from the base of the sheeted dikes in IODP Hole 1256D. Downhole compositional variations of drill cuttings, collected every 50 m, suggest that rocks below ~ 2 km are little altered. Whole-rock oxygen isotope profiles are consistent with low water/rock ratios, but suggest that early stages of hydrothermal alteration included meteoric water-derived fluids. Strontium isotope profiles indicate more extensive exchange with seawater-derived fluids

  2. How Do Modern Extreme Hydrothermal Environments Inform the Identification of Martian Habitability? The Case of the El Tatio Geyser Field

    Directory of Open Access Journals (Sweden)

    Roberto Barbieri

    2014-11-01

    Full Text Available Despite the success in knowledge gained by the Mars missions in the last two decades, the search for traces of life on Mars is still in progress. The reconstruction of (paleo- environments on Mars have seen a dramatic increase, in particular with regard to the potentially habitable conditions, and it is now possible to recognize a significant role to subaerial hydrothermal processes. For this reason, and because the conditions of the primordial Earth—when these extreme environments had to be common—probably resembled Mars during its most suitable time to host life, research on terrestrial extreme hydrothermal habitats may assist in understanding how to recognize life on Mars. A number of geological and environmental reasons, and logistics opportunities, make the geothermal field of El Tatio, in the Chilean Andes an ideal location to study.

  3. Crustal magnetization and the subseafloor structure of the ASHES vent field, Axial Seamount, Juan de Fuca Ridge: Implications for the investigation of hydrothermal sites

    Science.gov (United States)

    Caratori Tontini, Fabio; Crone, Timothy J.; Ronde, Cornel E. J.; Fornari, Daniel J.; Kinsey, James C.; Mittelstaedt, Eric; Tivey, Maurice

    2016-06-01

    High-resolution geophysical data have been collected using the Autonomous Underwater Vehicle (AUV) Sentry over the ASHES (Axial Seamount Hydrothermal Emission Study) high-temperature (~348°C) vent field at Axial Seamount, on the Juan de Fuca Ridge. Multiple surveys were performed on a 3-D grid at different altitudes above the seafloor, providing an unprecedented view of magnetic data resolution as a function of altitude above the seafloor. Magnetic data derived near the seafloor show that the ASHES field is characterized by a zone of low magnetization, which can be explained by hydrothermal alteration of the host volcanic rocks. Surface manifestations of hydrothermal activity at the ASHES vent field are likely controlled by a combination of local faults and fractures and different lava morphologies near the seafloor. Three-dimensional inversion of the magnetic data provides evidence of a vertical, pipe-like upflow zone of the hydrothermal fluids with a vertical extent of ~100 m.

  4. Hydrothermal minerals

    Digital Repository Service at National Institute of Oceanography (India)

    Nath, B.N.

    in the Indian Ocean. In both fields, hydrothermalism has ceased between 11.000 and 13.000 years ago. The first occurrence (Sonne Field, 2850 m water depth) is located in the 4th segment of the Central Indian Ridge, north of the Rodriguez Triple Junction... structures are composed of sulfides arising out from deep beneath the Earth' crust. These minerals have been dissolved in hot water (350ºC) under great pressures and temperatures. When the water that flows out through the mantle ejects at the mid ocean...

  5. Microbial community structure of hydrothermal deposits from geochemically different vent fields along the Mid-Atlantic Ridge

    Energy Technology Data Exchange (ETDEWEB)

    Flores, Gilberto E [Portland State University; Campbell, James H [ORNL; Kirshtein, Julie D [United States Geological Survey, Reston, VA; Meneghin, Jennifer [Portland State University; Podar, Mircea [ORNL; Steinberg, Joshua [Oregon Episcopal School, Portland, OR; Seewald, Jeffrey S [Woods Hole Oceanographic Institution (WHOI), Woods Hole, MA; Tivey, Margaret Kingston [Woods Hole Oceanographic Institution (WHOI), Woods Hole, MA; Voytek, Mary A [United States Geological Survey & National Aeronautics and Space Administration; Reysenbach, Anna-Louise [Portland State University; Yang, Zamin Koo [ORNL

    2011-01-01

    To evaluate the effects of local fluid geochemistry on microbial communities associated with active hydrothermal vent deposits, we examined the archaeal and bacterial communities of 12 samples collected from two very different vent fields: the basalt-hosted Lucky Strike (37 17'N, 32 16.3'W, depth 1600-1750 m) and the ultramafic-hosted Rainbow (36 13'N, 33 54.1'W, depth 2270-2330 m) vent fields along the Mid-Atlantic Ridge (MAR). Using multiplexed barcoded pyrosequencing of the variable region 4 (V4) of the 16S rRNA genes, we show statistically significant differences between the archaeal and bacterial communities associated with the different vent fields. Quantitative polymerase chain reaction (qPCR) assays of the functional gene diagnostic for methanogenesis (mcrA), as well as geochemical modelling to predict pore fluid chemistries within the deposits, support the pyrosequencing observations. Collectively, these results show that the less reduced, hydrogen-poor fluids at Lucky Strike limit colonization by strict anaerobes such as methanogens, and allow for hyperthermophilic microaerophiles, like Aeropyrum. In contrast, the hydrogen-rich reducing vent fluids at the ultramafic-influenced Rainbow vent field support the prevalence of methanogens and other hydrogen-oxidizing thermophiles at this site. These results demonstrate that biogeographical patterns of hydrothermal vent microorganisms are shaped in part by large scale geological and geochemical processes.

  6. Microbial community structure of hydrothermal deposits from geochemically different vent fields along the Mid-Atlantic Ridge.

    Science.gov (United States)

    Flores, Gilberto E; Campbell, James H; Kirshtein, Julie D; Meneghin, Jennifer; Podar, Mircea; Steinberg, Joshua I; Seewald, Jeffrey S; Tivey, Margaret Kingston; Voytek, Mary A; Yang, Zamin K; Reysenbach, Anna-Louise

    2011-08-01

    To evaluate the effects of local fluid geochemistry on microbial communities associated with active hydrothermal vent deposits, we examined the archaeal and bacterial communities of 12 samples collected from two very different vent fields: the basalt-hosted Lucky Strike (37°17'N, 32°16.3'W, depth 1600-1750 m) and the ultramafic-hosted Rainbow (36°13'N, 33°54.1'W, depth 2270-2330 m) vent fields along the Mid-Atlantic Ridge (MAR). Using multiplexed barcoded pyrosequencing of the variable region 4 (V4) of the 16S rRNA genes, we show statistically significant differences between the archaeal and bacterial communities associated with the different vent fields. Quantitative polymerase chain reaction (qPCR) assays of the functional gene diagnostic for methanogenesis (mcrA), as well as geochemical modelling to predict pore fluid chemistries within the deposits, support the pyrosequencing observations. Collectively, these results show that the less reduced, hydrogen-poor fluids at Lucky Strike limit colonization by strict anaerobes such as methanogens, and allow for hyperthermophilic microaerophiles, like Aeropyrum. In contrast, the hydrogen-rich reducing vent fluids at the ultramafic-influenced Rainbow vent field support the prevalence of methanogens and other hydrogen-oxidizing thermophiles at this site. These results demonstrate that biogeographical patterns of hydrothermal vent microorganisms are shaped in part by large scale geological and geochemical processes.

  7. Microbial community structure of hydrothermal deposits from geochemically different vent fields along the Mid-Atlantic Ridge

    Science.gov (United States)

    Flores, Gilberto E.; Campbell, James H.; Kirshtein, Julie D.; Meneghin, Jennifer; Podar, Mircea; Steinberg, Joshua I.; Seewald, Jeffrey S.; Tivey, Margaret Kingston; Voytek, Mary A.; Yang, Zamin K.; Reysenbach, Anna-Louise

    2011-01-01

    To evaluate the effects of local fluid geochemistry on microbial communities associated with active hydrothermal vent deposits, we examined the archaeal and bacterial communities of 12 samples collected from two very different vent fields: the basalt-hosted Lucky Strike (37°17'N, 32°16.3'W, depth 1600-1750m) and the ultramafic-hosted Rainbow (36°13'N, 33°54.1'W, depth 2270-2330m) vent fields along the Mid-Atlantic Ridge (MAR). Using multiplexed barcoded pyrosequencing of the variable region 4 (V4) of the 16S rRNA genes, we show statistically significant differences between the archaeal and bacterial communities associated with the different vent fields. Quantitative polymerase chain reaction (qPCR) assays of the functional gene diagnostic for methanogenesis (mcrA), as well as geochemical modelling to predict pore fluid chemistries within the deposits, support the pyrosequencing observations. Collectively, these results show that the less reduced, hydrogen-poor fluids at Lucky Strike limit colonization by strict anaerobes such as methanogens, and allow for hyperthermophilic microaerophiles, like Aeropyrum. In contrast, the hydrogen-rich reducing vent fluids at the ultramafic-influenced Rainbow vent field support the prevalence of methanogens and other hydrogen-oxidizing thermophiles at this site. These results demonstrate that biogeographical patterns of hydrothermal vent microorganisms are shaped in part by large scale geological and geochemical processes.

  8. Tectonic background of a unique hydrogen-rich Kairei Hydrothermal Field, Central Indian Ridge: Results from Taiga Project

    Science.gov (United States)

    Okino, K.; Nakamura, K.; Morishita, T.; SATO, H.; Sato, T.; Mochizuki, N.; Okamura, K.; Fukuba, T.; Sunamura, M.

    2012-12-01

    The Central Indian Ridge (CIR) is slow~intermediate spreading systems and its southern end forms a R-R-R triple junction with SWIR and SEIR. The southern CIR shows slow-spreading morphology, where the axial valley develops along the ridge crest and an oceanic core complex has been reported near the triple junction. Kairei Hydrothermal Field (KHF) is unique hydrothermal system, located at the southern end of CIR. The fluids venting from the KHF are characterized by its high concentration of hydrogen with low methane/hydrogen ratio, and a hydrogen-based hyperthermophilic subsurface lithoautotrophic microbial ecosystem was confirmed (Takai et al., 2004). The KHF lies on basaltic lava area on the shoulder of ridge axial wall, being different from other hydrogen-rich hydrothermal fields hosted by ultramafic rocks. We selected this area as an integrated site for the Taiga Project, and conducted series of research cruises to characterize this unique system and to understand how the tectonic setting controls the fluid and ecosystem. We discover that the KHF itself is located above basaltic lava field but gabbro and ultramafic rocks are widely exhumed around the KHF. Besides a previously known oceanic core complex, small oceanic core complexes exist just east of the KHF (Kumagai et al., 2008) and the NTO massif north of the KHF shows peridotite exposure on its top. The unique fluid geochemistry of the KHF can be attributed to serpentinization of troctolites around or beneath the KHF and subsequent hydrothermal reactions with basaltic wall rocks (Nakamura et al., 2009). We also find several small hills where we collect deep crustal and mantle rocks. These hills suggesting melt-limited environment extend mainly along 2nd order segment boundary from the axial valley to 30km off-axis, i.e. ~1.7 Ma. The regional surface geophysical mapping and deep-tow magnetic profiling show high mantle Bouguer anomaly and prominent asymmetric spreading in the southernmost CIR segment. These

  9. Geothermal-energy files in computer storage: sites, cities, and industries

    Energy Technology Data Exchange (ETDEWEB)

    O' Dea, P.L.

    1981-12-01

    The site, city, and industrial files are described. The data presented are from the hydrothermal site file containing about three thousand records which describe some of the principal physical features of hydrothermal resources in the United States. Data elements include: latitude, longitude, township, range, section, surface temperature, subsurface temperature, the field potential, and well depth for commercialization. (MHR)

  10. Multidimensional Field Mapping of Gaseous C-H-O-S Species in Hydrothermal Systems: Distinguishing Potential Sites for Hydrocarbon Generation

    Science.gov (United States)

    Schwandner, F. M.; Dunn, E. E.; Shock, E. L.

    2005-12-01

    Organic compounds in hydrothermal gas emissions have been documented since the mid-1800's, yet their origin is still a matter of some debate. Thermal alteration such as maturation and cracking can produce thermogenic hydrocarbons from pre-existing organic matter in hydrothermal systems. Gas-phase radical reactions and catalytic hydrogenation reactions of CO2 and CO to methane and higher hydrocarbons have also been suggested as being responsible for observations of organic compounds in hydrothermal emissions. Recently published data indicated that some organic signatures in volcanic-hydrothermal systems cannot be explained by pre-existing organic matter alone, and more representative analyses are now required to shed light on this question. Choosing a representative site within a hydrothermal field for sampling is in itself a complicated task, and heterogeneities can be easily missed. Spatial analysis of the distribution of C-O-H-S species in the gas phase can potentially indicate possible sites of increased hydrocarbon generation potentials via the catalytic hydrogenation pathway. This approach offers the advantage of providing information in the field that can be used to judge appropriate sampling locations prior to the more complex and costly standard organic analyses of gaseous emissions. A portable multi-sensor system with electrochemical and infrared sensors can in a short time provide large spatial data sets that yield potential target areas for selectively sampling organic compounds. Statistical methods, including probability tests and spatial correlation of concentrations and fluxes of selected species, can be applied later to yield information on the number of populations as well as genetic relationships between different populations. This approach was tested at three acid-sulfate sites in Yellowstone National Park, USA. The chosen sites were the Greater Obsidian Pool area (GOPA, Mud Volcanoes hot spring group), the Sylvan Springs area, and the Washburn

  11. Rhythms and community dynamics of a hydrothermal tubeworm assemblage at main endeavour field - a multidisciplinary deep-sea observatory approach.

    Directory of Open Access Journals (Sweden)

    Daphne Cuvelier

    Full Text Available The NEPTUNE cabled observatory network hosts an ecological module called TEMPO-mini that focuses on hydrothermal vent ecology and time series, granting us real-time access to data originating from the deep sea. In 2011-2012, during TEMPO-mini's first deployment on the NEPTUNE network, the module recorded high-resolution imagery, temperature, iron (Fe and oxygen on a hydrothermal assemblage at 2186 m depth at Main Endeavour Field (North East Pacific. 23 days of continuous imagery were analysed with an hourly frequency. Community dynamics were analysed in detail for Ridgeia piscesae tubeworms, Polynoidae, Pycnogonida and Buccinidae, documenting faunal variations, natural change and biotic interactions in the filmed tubeworm assemblage as well as links with the local environment. Semi-diurnal and diurnal periods were identified both in fauna and environment, revealing the influence of tidal cycles. Species interactions were described and distribution patterns were indicative of possible microhabitat preference. The importance of high-resolution frequencies (<1 h to fully comprehend rhythms in fauna and environment was emphasised, as well as the need for the development of automated or semi-automated imagery analysis tools.

  12. How many vent fields? New estimates of vent field populations on ocean ridges from precise mapping of hydrothermal discharge locations

    Science.gov (United States)

    Baker, Edward T.; Resing, Joseph A.; Haymon, Rachel M.; Tunnicliffe, Verena; Lavelle, J. William; Martinez, Fernando; Ferrini, Vicki; Walker, Sharon L.; Nakamura, Koichi

    2016-09-01

    Decades of exploration for venting sites along spreading ridge crests have produced global datasets that yield estimated mean site spacings of ∼ 12- 220 km. This conclusion demands that sites where hydrothermal fluid leaks from the seafloor are improbably rare along the 66 000 km global ridge system, despite the high bulk permeability of ridge crest axes. However, to date, exploration methods have neither reliably detected plumes from isolated low-temperature, particle-poor, diffuse sources, nor differentiated individual, closely spaced (clustered within a few kilometers) sites of any kind. Here we describe a much lower mean discharge spacing of 3-20 km, revealed by towing real-time oxidation-reduction-potential and optical sensors continuously along four fast- and intermediate-rate (>55 mm/yr) spreading ridge sections totaling 1470 km length. This closer spacing reflects both discovery of isolated sites discharging particle-poor plumes (25% of all sites) and improved discrimination (at a spatial resolution of ∼1 km) among clustered discrete and diffuse sources. Consequently, the number of active vent sites on fast- and intermediate-rate spreading ridges may be at least a factor of 3-6 higher than now presumed. This increase provides new quantitative constraints for models of seafloor processes such as dispersal of fauna among seafloor and crustal chemosynthetic habitats, biogeochemical impacts of diffuse venting, and spatial patterns of hydrothermal discharge.

  13. Metagenomic comparison of two Thiomicrospira lineages inhabiting contrasting deep-sea hydrothermal environments.

    Directory of Open Access Journals (Sweden)

    William J Brazelton

    Full Text Available BACKGROUND: The most widespread bacteria in oxic zones of carbonate chimneys at the serpentinite-hosted Lost City hydrothermal field, Mid-Atlantic Ridge, belong to the Thiomicrospira group of sulfur-oxidizing chemolithoautotrophs. It is unclear why Thiomicrospira-like organisms thrive in these chimneys considering that Lost City hydrothermal fluids are notably lacking in hydrogen sulfide and carbon dioxide. METHODOLOGY/PRINCIPAL FINDINGS: Here we describe metagenomic sequences obtained from a Lost City carbonate chimney that are highly similar to the genome of Thiomicrospira crunogena XCL-2, an isolate from a basalt-hosted hydrothermal vent in the Pacific Ocean. Even though T. crunogena and Lost City Thiomicrospira inhabit different types of hydrothermal systems in different oceans, their genomic contents are highly similar. For example, sequences encoding the sulfur oxidation and carbon fixation pathways (including a carbon concentration mechanism of T. crunogena are also present in the Lost City metagenome. Comparative genomic analyses also revealed substantial genomic changes that must have occurred since the divergence of the two lineages, including large genomic rearrangements, gene fusion events, a prophage insertion, and transposase activity. CONCLUSIONS/SIGNIFICANCE: Our results show significant genomic similarity between Thiomicrospira organisms inhabiting different kinds of hydrothermal systems in different oceans, suggesting that these organisms are widespread and highly adaptable. These data also indicate genomic processes potentially associated with the adaptation of these lineages into strikingly different habitats.

  14. Stable isotope fractionation at a glacial hydrothermal field: implications for biogeochemistry and biosignatures on Mars

    Science.gov (United States)

    Cousins, C.; Bowden, R.; Fogel, M.; Cockell, C.; Crawford, I.; Gunn, M.; Karlsson, M. T.; Thorsteinsson, T.

    2012-12-01

    Hydrothermal environments that arise through the interaction between volcanogenic heat and glacial ice are ideal sites for understanding microbial biogeochemical processes on Earth, and also potentially on Mars where similar volcano-cryosphere interactions are thought to have occurred in the past. The Kverkfjöll subglacial basaltic volcano in central Iceland is geographically isolated, with little influence from flora, fauna, and human activity. Major environmental inputs include geothermal heat, meltwater from ice and snow, and outgassing of CO2, H2S, and SO2. Large physiochemical gradients exist, from steaming fumaroles and boiling hydrothermal pools, to frozen geothermal ground and glacial ice. Stable isotope measurements of total organic carbon, total sulphur, and total nitrogen were coupled with metagenomic analysis of the residing microbial communities, with the aim to identify biogeochemical relationships and processes operating within the Kverkfjöll geothermal environment, and also to identify any isotopic biosignatures that could be preserved within geothermal sediments. This study focused on a variety of samples taken along a hot spring stream that fed into a large ice-confined geothermal lake. Samples analysed range from unconsolidated hot spring sediments, well-developed microbial mats, and dissolved sulphate from hot spring fluids. From the anoxic spring source, the stream water increases in dissolved oxygen, decreases in temperature, yet maintains a pH of ~4. The spring environment is dominated by dissolved sulphate (~2.3 mM), with lower levels of nitrate (~50 μM), phosphorus (~5μM), and ammonium (~1.5 μM). Stable S isotope analysis reveals a fractionation of ~3.2 ‰ between sediment sulphide (as pyrite; δ34S ~0‰), and dissolved water sulphate (δ34S ~3.2 ‰) consistently along the hot spring stream, indicating the presence of an active sulphur cycle, although not one dominated by sulphate reduction (e.g. very negative sulphide δ34S). This

  15. Platelet-like hexagonal SrFe12O19 particles: Hydrothermal synthesis and their orientation in a magnetic field

    Science.gov (United States)

    Zhang, Tao; Peng, Xiaoling; Li, Jing; Yang, Yanting; Xu, Jingcai; Wang, Panfeng; Jin, Dingfeng; Jin, Hongxiao; Hong, Bo; Wang, Xinqing; Ge, Hongliang

    2016-08-01

    Platelet-like hexagonal SrFe12O19 particles were prepared by hydrothermal synthesis, and the effects of molar ratio of Fe/Sr (RFe/Sr) on the phase compositions, morphologies and magnetic properties of as-prepared samples were investigated. The optimum RFe/Sr is identified as 8:1. The hexagonal platelet-like particles are nano-scale in thickness and micro-scale in diameter. The low coercivity is a consequence of the large shape anisotropy of the as-synthesized particles. The platelet-like hexagonal SrFe12O19 particles were then dispersed in epoxy resin and formed ordered arrangement structure which took root in the curing epoxy matrix under an external magnetic field of 8000 Oe. The microstructures, morphologies and magnetic properties of the bulk samples orientated and nonaligned were studied. The platelet-like particles arrange with the platelet perpendicular to the magnetic field direction in the orientated samples. This demonstrates that the easy axis of the particle is perpendicular to the platelet, and that the magnetocrystalline anisotropy still plays a leading role in the changing effective anisotropy with the rapidly growing shape anisotropy. The remanence (Mr) of the bulk samples is changed obviously after orientation, while the coercivity nearly remains constant. That is, the maximum energy products (BH)max can be effectively adjusted by given a suitable magnetic field.

  16. Simple and effective monitoring of the electromagnetic field in the smart cities arena

    Science.gov (United States)

    Ares-Pena, Francisco J.; Franceschetti, Giorgio; Iodice, Antonio; Salas-Sánchez, Aarón A.

    2016-08-01

    A simple and economical method for monitoring the electromagnetic field intensity in built-up areas is presented. The method is based on the measurement of the field level over a limited number of points at street level in the city and their transmission to an operative control center, where the field values all over the city are correctly interpolated in real time. Citizens might obtain these values at their sites, via Internet, or by connecting with a dedicated call center. Numerical evaluations of the electromagnetic field intensity via the new developed model and confirming experimental results are finally presented.

  17. Environmental controls on biomineralization and Fe-mound formation in a low-temperature hydrothermal system at the Jan Mayen Vent Fields

    Science.gov (United States)

    Johannessen, Karen C.; Vander Roost, Jan; Dahle, Håkon; Dundas, Siv H.; Pedersen, Rolf B.; Thorseth, Ingunn H.

    2017-04-01

    Diffuse low-temperature hydrothermal vents on the seafloor host neutrophilic microaerophilic Fe-oxidizing bacteria that utilize the Fe(II) supplied by hydrothermal fluids and produce intricate twisted and branching extracellular stalks. The growth behavior of Fe-oxidizing bacteria in strongly opposing gradients of Fe(II) and O2 have been thoroughly investigated in laboratory settings to assess whether extracellular stalks and aligned biomineralized fabrics may serve as biosignatures of Fe-oxidizing bacteria and indications of palaeo-redox conditions in the rock record. However, the processes controlling the growth of biogenic Fe-oxyhydroxide deposits in natural, modern hydrothermal systems are still not well constrained. In this study, we aimed to establish how variations in the texture of stratified hydrothermal Fe-oxyhydroxide deposits are linked to the physicochemical conditions of the hydrothermal environment. We conducted 16S rRNA gene analyses, microscopy and geochemical analyses of laminated siliceous Fe-mounds from the Jan Mayen Vent Fields at the Arctic Mid-Ocean Ridge. Chemical analyses of low- and high-temperature hydrothermal fluids were performed to characterize the hydrothermal system in which the Fe-deposits form. Our results reveal synchronous inter-laminar variations in texture and major and trace element geochemistry. The Fe-deposits are composed of alternating porous laminae of mineralized twisted stalks and branching tubes, Mn-rich horizons with abundant detrital sediment, domal internal cavities and thin P- and REE-enriched lamina characterized by networks of ≪1 μm wide fibers. Zetaproteobacteria constitute one third of the microbial community in the surface layer of actively forming mounds, indicating that microbial Fe-oxidation is contributing to mound accretion. We suggest that Mn-oxide precipitation and detrital sediment accumulation take place during periodically low hydrothermal fluid discharge conditions. The elevated concentrations

  18. Correlation of wireline log characteristics with hydrothermal alteration and other reservoir properties of the Salton Sea and Westmorland geothermal fields, Imperial Valley, California, USA

    Energy Technology Data Exchange (ETDEWEB)

    Muramoto, F.S.; Elders, W.A.

    1984-05-01

    A detailed study of wireline logs from 11 wells in the Salton Sea and Westmorland geothermal systems was undertaken in order to determine the effects of hydrothermal alteration on the response of electrical and gamma-gamma density well logs. For the Salton Sea geothermal field, definite correspondence between log responses and hydrothermal mineralogy is evident, which in turn is related to the physical properties of the rocks. Three hydrothermal and one unaltered zone can be identified from log data on shales. These are: (1) the unaltered montmorillonite zone (<100/sup 0/ to 190/sup 0/C); (2) the illite zone (100/sup 0/ to 190/sup 0/C to 230/sup 0/ to 250/sup 0/C); (3) the chlorite zone (230/sup 0/ to 250/sup 0/C to 290/sup 0/ to 300/sup 0/C); and (4) the feldspar zone (>290/sup 0/ to 300/sup 0/C). The characteristic responses on well logs by which these zones are identified result primarily from changes in clay mineralogy of the shales and increases in density with progressive hydrothermal metamorphism. In the Westmorland geothermal field, differentiating mineral zones from log responses was only partially successful. However, analyses of both well log and petrologic data for wells Landers 1 and Kalin Farms 1 suggest that the former is heating up and the latter is cooling.

  19. Microbial community structure and nitrogenase gene diversity of sediment from a deep-sea hydrothermal vent field on the Southwest Indian Ridge

    Institute of Scientific and Technical Information of China (English)

    WU Yuehong; CAO Yi; WANG Chunsheng; WU Min; AHARON Oren; XU Xuewei

    2014-01-01

    A sediment sample was collected from a deep-sea hydrothermal vent field located at a depth of 2 951 m on the Southwest Indian Ridge. Phylogenetic analyses were performed on the prokaryotic community using polymerase chain reaction (PCR) amplification of the 16S rRNA and nifH genes. Within the Archaea, the dominant clones were from marine benthic group E (MBGE) and marine group I (MGI) belonging to the phyla Euryarchaeota and Thaumarchaeota, respectively. More than half of the bacterial clones belonged to the Proteobacteria, and most fell within the Gammaproteobacteria. No epsilonproteobacterial sequence was observed. Additional phyla were detected including the Actinobacteria, Bacteroidetes, Planctomycetes, Acidobacteria, Nitrospirae, Chloroflexi, Chlorobi, Chlamydiae, Verrucomicrobia, and candidate divisions OD1, OP11, WS3 and TM6, confirming their existence in hydrothermal vent environments. The detection of nifH gene suggests that biological nitrogen fixation may occur in the hydrothermal vent field of the South-west Indian Ridge. Phylogenetic analysis indicated that only Clusters I and III NifH were present. This is consistent with the phylogenetic analysis of the microbial 16S rRNA genes, indicating that Bacteria play the main role in nitrogen fixation in this hydrothermal vent environment.

  20. Hydrothermal mixing: Fuel for life in the deep-sea

    Science.gov (United States)

    Hentscher, M.; Bach, W.; Amend, J.; McCollom, T.

    2009-04-01

    Deep-sea hydrothermal vent systems show a wide range of fluid compositions and temperatures. They reach from highly alkaline and reducing, like the Lost City hydrothermal field, to acidic and reducing conditions, (e. g., the Logatchev hydrothermal field) to acidic and oxidizing conditions (e. g., island arc hosted systems). These apparently hostile vent systems are generally accompanied by high microbial activity forming the base of a food-web that often includes higher organisms like mussels, snails, or shrimp. The primary production is boosted by mixing of chemically reduced hydrothermal vent fluids with ambient seawater, which generates redox disequilibria that serve as energy source for chemolithoautotrophic microbial life. We used geochemical reaction path models to compute the affinities of catabolic (energy-harvesting) and anabolic (biosynthesis) reactions along trajectories of batch mixing between vent fluids and 2 °C seawater. Geochemical data of endmember hydrothermal fluids from 12 different vent fields (Lost City, Rainbow, Logatchev, TAG, EPR 21 °N, Manus Basin, Mariana Arc, etc.) were included in this reconnaissance study of the variability in metabolic energetics in global submarine vent systems. The results show a distinction between ultramafic-hosted and basalt-hosted hydrothermal systems. The highest energy yield for chemolithotrophic catabolism in ultramafic-hosted hydrothermal systems is reached at low temperature and under slightly aerobic to aerobic conditions. The dominant reactions, for example at Rainbow or Lost City, are the oxidation of H2, Fe2+ and methane. At temperatures >60 °C, anaerobic metabolic reactions, e. g., sulphate reduction and methanogenesis, become more profitable. In contrast, basalt-hosted systems, such as TAG and 21 °N EPR uniformly indicate H2S oxidation to be the catabolically dominant reaction over the entire microbial-relevant temperature range. Affinities were calculated for the formation of individual cellular

  1. Seismic structure at the Kairei Hydrothermal vent field near the Rodriguez Triple Junction in the Indian Ocean

    Science.gov (United States)

    Takata, H.; Sato, T.; Imai, Y.; Mori, T.; Noguchi, Y.; Kono, A.; Yamada, T.; Shinohara, M.

    2014-12-01

    Central Indian Ridge is located at the north of the Rodriguez Triple Junction and shows slow-intermediate spreading rate. The Kairei hydrothermal Field (KHF) was discovered in the first segment of Central Indian Ridge near the Rodriguez Triple Junction. The vent fluid which is extruding at the KHF has higher H2 content compared with other hydrothermal vent fluid in the world. Although The KHF itself exists above a basaltic rock massif, gabbro and mafic rocks were discovered on the seafloor around the KHF. These deep-seated rocks may contribute to the high H2concentration of the Kairei vent fluid .To understand how gabbro and mafic rocks are uplifted and exhumed on the seafloor, we conducted a seismic refraction/reflection survey using ocean bottom seismograms (OBSs). We conducted the seismic refraction/reflection survey from January 27 to March 19 in 2013 using S/V Yokosuka of Jamstec. In the experiment, we used 21 OBSs, an air gun (G.I.gun) and a single channel steamer cable. We obtained 5 survey lines NNW-SSE direction parallel to the ridge axis, 5 lines E-W direction and 5 lines NNE-SSW direction. In addition to these lines, we acquired other 5 lines passing through the point above the KHF or Yokoniwa Rise, which is the north of the KHF. In analysis of refraction data, firstly, we estimated 2D velocity model under survey lines, which are parallel to the ridge axis, using the progressive model development method developed by Sato and Kennett (2000). Then, we constructed a 3D initial model and run the 3D tomographic method developed by Zelt and Barton (1998). The 1D velocity profile of the KHF seems to be similar to that of mid ocean ridges such as Mid Atlantic Ridge, East Pacific Rise. Seismic velocities under the KHF and Yokoniwa Rise reach about 6km/s at depth of 1~2 km below seafloor, probably indicating uplift of deep-seated rocks. In this presentation we will show 3D seismic structure of this area.

  2. Chemical Variations in the Rocks of La Primavera Geothermal Field (Mexico) Related with Hydrothermal Alteration

    Energy Technology Data Exchange (ETDEWEB)

    Prol-Ledesma, R.M.; Hernandez-Lombardini, S.I.; Lozano-Santa Cruz, R.

    1995-01-01

    The origin and fate of the components dissolved in the geothermal fluids are of great importance in the study of epithermal deposits, and in the environmental considerations for exploitation of geothermal fields. The chemical study of La Primavera geothermal field in Mexico has environmental importance due to the high arsenic concentration observed in the thermal water and the possible contamination of aquifers in the area. The variations in the chemistry of all altered samples with respect to unaltered samples indicates depletion of manganese, and the alkalis; and enrichment in iron and magnesium. Most samples show an enrichment in aluminum and titanium, and depletion in silica and calcium. Trace elements follow different trends at various depths: shallow depths are more favorable for deposition of the analyzed trace elements than the surface or the deep part of the reservoir.

  3. Hydrothermal Synthesis and Field Enhancement Behavior of ZnO Nanorods Pattern

    Institute of Scientific and Technical Information of China (English)

    Jing Tang; Lin Du; Wen-hui Pang; Jing-jing Zheng; Xiao-chun Tian; Jin-liang Zhuang

    2011-01-01

    We provide a new way to prepare ZnO nanorods pattern from the solution composed of hexamethylenetetramine (HMT) and Zn(NO3)2.The substrate is ITO substrate covered by well ordered Au islands.Since Au and the underneath ITO substrate have two different nucleation rates in the initial stage of heterogeneous nucleation process,the subsequent ZnO growth on the quick nucleating area takes place under diffusion control and is able to confine the synthesis of ZnO nanorods to specific locations.The concentrations of zinc nitrate and HMT are well adjusted to show the possibility of the new route for the patterning of the ZnO nanorods.Furthermore,the nanorods pattern was characterized by X-ray diffraction and photoluminescence and the performance of field emission property from ZnO nanorod patterns was investigated.The ZnO nanorods pattern with a good alignment also shows a good field enhancement behavior with a high value of the field enhancement factor.

  4. Development And Application Of A Hydrothermal Model For The Salton Sea Geothermal Field, California

    Energy Technology Data Exchange (ETDEWEB)

    Kasameyer, P.; Younker, L.; Hanson, J.

    1984-01-01

    A simple lateral flow model adequately explains many of the features associated with the Salton Sea Geothermal Field. Earthquake swarms, a magnetic anomaly, and aspects of the gravity anomaly are all indirect evidence for the igneous activity which is the ultimate source of heat for the system. Heat is transferred from this area of intrusion by lateral spreading of hot water in a reservoir beneath an impermeable cap rock. A two dimensional analytic model encompassing this transport mechanism matches general features of the thermal anomaly and has been used to estimate the age of the presently observed thermal system. The age is calculated by minimizing the variance between the observed surface heat-flow data and the model. Estimates of the system age for this model range from 3,000 to 20,000 years.

  5. Field evaluation of biolarvicides in Surat city, India

    Directory of Open Access Journals (Sweden)

    S. Haq, R.M. Bhatt, K.G. Vaishnav & R.S. Yadav

    2004-09-01

    Full Text Available Background & objectives : Two bacterial larvicide (bio-larvicide formulations— Bacticide® and VectoBac® containing viable endospores and delta endotoxin of Bacillus thuringiensis var israelensisH-14 were evaluated in 2001 for their mosquito larvicidal efficacy under the operational conditions ofurban malaria control programme in Surat city, India.Methods : Larvicides were applied at the recommended dose in selected breeding habitats of Anopheles(An. stephensi, Aedes (Ae. aegypti and Culex (Cx. quinquefasciatus and reductions in thedensities of III and IV instars were compared with that of untreated matched controls.Results : At the construction sites in cemented tanks/chambers VectoBac produced reduction in thedensity of III and IV instar larvae of An. stephensi (98–100% and Ae. aegypti (100% in the first weekof application whereas Bacticide produced 71–100% reduction in An. stephensi and 100% in Ae.aegypti. Re-application of VectoBac on Day 10 caused better control up to Day 20 when comparedwith Bacticide. In stagnant water pools, VectoBac produced 27.6–85.3% reduction in the larvae of An.subpictus and 18.5–83.8% in those of Cx. quinquefasciatus whereas Bacticide produced 23.3–30.3%and 39–97.2% reduction in An. subpictus and Cx. quinquefasciatus larval densities in the first weekpost application, respectively. Bacticide application gave better impact on Cx. quinquefasciatuslarvae in the second week after re-application as compared to VectoBac. In storm water drains, Vecto-Bac caused respectively 6.2–100% and 6.4–97.6% reduction in An. subpictus and Cx. quinquefasciatuslarvae in the first week of application whereas Bacticide produced 100% and 13.3–98.8% reductionin An. subpictus and Cx. quinquefasciatus larval densities, respectively.Interpretation & conclusion : Both the formulations were equally effective on An. subpictus and Cx.quinquefasciatus larvae after a second application. The results showed that application of

  6. Surface heat flow and CO2 emissions within the Ohaaki hydrothermal field, Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Rissmann, C.; Christenson, B.; Werner, C.; Leybourne, M.; Cole, J.; Gravley, D.

    2012-01-01

    Carbon dioxide emissions and heat flow have been determined from the Ohaaki hydrothermal field, Taupo Volcanic Zone (TVZ), New Zealand following 20a of production (116MW e). Soil CO2 degassing was quantified with 2663 CO2 flux measurements using the accumulation chamber method, and 2563 soil temperatures were measured and converted to equivalent heat flow (Wm -2) using published soil temperature heat flow functions. Both CO2 flux and heat flow were analysed statistically and then modelled using 500 sequential Gaussian simulations. Forty subsoil CO 2 gas samples were also analysed for stable C isotopes. Following 20a of production, current CO2 emissions equated to 111??6.7T/d. Observed heat flow was 70??6.4MW, compared with a pre-production value of 122MW. This 52MW reduction in surface heat flow is due to production-induced drying up of all alkali-Cl outflows (61.5MW) and steam-heated pools (8.6MW) within the Ohaaki West thermal area (OHW). The drying up of all alkali-Cl outflows at Ohaaki means that the soil zone is now the major natural pathway of heat release from the high-temperature reservoir. On the other hand, a net gain in thermal ground heat flow of 18MW (from 25MW to 43.3??5MW) at OHW is associated with permeability increases resulting from surface unit fracturing by production-induced ground subsidence. The Ohaaki East (OHE) thermal area showed no change in distribution of shallow and deep soil temperature contours despite 20a of production, with an observed heat flow of 26.7??3MW and a CO 2 emission rate of 39??3T/d. The negligible change in the thermal status of the OHE thermal area is attributed to the low permeability of the reservoir beneath this area, which has limited production (mass extraction) and sheltered the area from the pressure decline within the main reservoir. Chemistry suggests that although alkali-Cl outflows once contributed significantly to the natural surface heat flow (~50%) they contributed little (99% of the original CO 2

  7. An Assessment of Changes in Kunzea ericoides var . microflora and Other Hydrothermal Vegetation at the Wairakei-Tauhara Geothermal Field, New Zealand

    Science.gov (United States)

    van Manen, Saskia M.; Reeves, Robert

    2012-10-01

    Hydrothermal ecosystems are of high conservation and scientific value, but they are sensitive to external perturbations that result from development. This study examines the composition of vegetation at four plots at the Wairakei-Tauhara geothermal field, New Zealand, using the Scott height-frequency method, ground temperatures at 0.1- and 1-m depth, soil pH, and photographic surveys. It highlights the response of plant communities, in particular that of Kunzea ericoides var. microflora, in terms of composition, structure, and biomass index values, measures changes in ground temperature, as well as provides baseline data against which to compare future changes. It was found that optimal growing conditions for K. ericoides var. microflora are at temperatures above background conditions with a slightly acidic pH. Plots with cooler, less acidic conditions support more diverse plant communities, which also promote the establishment of invasive species. This suggests that the largest threats to thermotolerant vegetation in New Zealand, including K. ericoides var. microflora, are further decreases in ground temperature because the establishment of invasive species may result in thermolerant vegetation being out-competed in hydrothermal ecosystems. Recognising and understanding the ecological diversity and dynamics of hydrothermal ecosystems, as well as acknowledging the competing interests between development and conservation, is key to the management and protection of these areas.

  8. Deposition of talc - kerolite-smectite - smectite at seafloor hydrothermal vent fields: Evidence from mineralogical, geochemical and oxygen isotope studies

    Science.gov (United States)

    Dekov, V.M.; Cuadros, J.; Shanks, Wayne C.; Koski, R.A.

    2008-01-01

    Talc, kerolite-smectite, smectite, chlorite-smectite and chlorite samples from sediments, chimneys and massive sulfides from six seafloor hydrothermal areas have been analyzed for mineralogy, chemistry and oxygen isotopes. Samples are from both peridotite- and basalt-hosted hydrothermal systems, and basaltic systems include sediment-free and sediment-covered sites. Mg-phyllosilicates at seafloor hydrothermal sites have previously been described as talc, stevensite or saponite. In contrast, new data show tri-octahedral Mg-phyllosilicates ranging from pure talc and Fe-rich talc, through kerolite-rich kerolite-smectite to smectite-rich kerolite-smectite and tri-octahedral smectite. The most common occurrence is mixed-layer kerolite-smectite, which shows an almost complete interstratification series with 5 to 85% smectitic layers. The smectite interstratified with kerolite is mostly tri-octahedral. The degree of crystal perfection of the clay sequence decreases generally from talc to kerolite-smectite with lower crystalline perfection as the proportion of smectite layers in kerolite-smectite increases. Our studies do not support any dependence of the precipitated minerals on the type/subtype of hydrothermal system. Oxygen isotope geothermometry demonstrates that talc and kerolite-smectite precipitated in chimneys, massive sulfide mounds, at the sediment surface and in open cracks in the sediment near seafloor are high-temperature (> 250????C) phases that are most probably the result of focused fluid discharge. The other end-member of this tri-octahedral Mg-phyllosilicate sequence, smectite, is a moderate-temperature (200-250????C) phase forming deep within the sediment (??? 0.8??m). Chlorite and chlorite-smectite, which constitute the alteration sediment matrix around the hydrothermal mounds, are lower-temperature (150-200????C) phases produced by diffuse fluid discharge through the sediment around the hydrothermal conduits. In addition to temperature, other two

  9. Mexico City basin wind circulation during the MCMA-2003 field campaign

    Directory of Open Access Journals (Sweden)

    B. de Foy

    2005-05-01

    Full Text Available MCMA-2003 was a major field campaign investigating the atmospheric chemistry of the Mexico City Metropolitan Area (MCMA in April of 2003. This paper describes the wind circulation patterns during the campaign both within the Mexico City basin and on the regional scale. ''Time roses'' are introduced to concisely analyze the diurnal wind patterns. Three episode types were identified that explain the conditions encountered: ''O3-South'', ''Cold Surge'' and ''O3-North''. These can be diagnosed from a combination of synoptic and basin observations based on whether the day was predominantly cloudy, or whether the O3 peak was in the north or south of the basin. O3-South days have weak synoptic forcing due to an anti-cyclone over the eastern Pacific. Strong solar heating leads to northerly flows in the basin and an evening shift due to a gap flow from the south-east. Peak ozone concentrations are in the convergence zone in the south of the city. Cold Surge days are associated with ''El Norte'' events, with strong surface northerlies bringing cold moist air and rain. Stable conditions lead to high concentrations of primary pollutants and peak ozone in the city center. O3-North days occur when the sub-tropical jet is closer to Mexico City. With strong westerlies aloft, the circulation pattern is the same as O3-South days except for a wind shift in the mid-afternoon leading to ozone peaks in the north of the city. This classification is proposed as a means of understanding pollutant transport in the Mexico City basin and as a basis for future meteorological and chemical analysis. Furthermore, model evaluation and design of policy recommendations will need to take into account the three episode types.

  10. Mexico City basin wind circulation during the MCMA-2003 field campaign

    Directory of Open Access Journals (Sweden)

    B. de Foy

    2005-01-01

    Full Text Available MCMA-2003 was a major field campaign investigating the atmospheric chemistry of the Mexico City Metropolitan Area (MCMA in April of 2003. This paper describes the wind circulation patterns during the campaign both within the Mexico City basin and on the regional scale. ''Time roses'' are introduced to concisely analyze the diurnal wind patterns. Three episode types were identified that explain the conditions encountered: ''O3-South'', ''Cold Surge'' and ''O3-North''. These can be diagnosed from a combination of synoptic and basin observations based on whether the day was predominantly cloudy, or whether the O3 peak was in the north or south of the basin. O3-South days have weak synoptic forcing due to an anti-cyclone over the eastern Pacific. Strong solar heating leads to northerly flows in the basin and an evening shift due to a gap flow from the south-east. Peak ozone concentrations are in the convergence zone in the south of the city. Cold Surge days are associated with ''El Norte'' events, with strong surface northerlies bringing cold moist air and rain. Stable conditions lead to high concentrations of primary pollutants and peak ozone in the city center. O3-North days occur when the sub-tropical jet is closer to Mexico City. With strong westerlies aloft, the circulation pattern is the same as O3-South days except for a wind shift in the mid-afternoon leading to ozone peaks in the north of the city. This classification is proposed as a means of understanding pollutant transport in the Mexico City basin and as a basis for future meteorological and chemical analysis. Furthermore, model evaluation and design of policy recommendations will need to take into account the three episode types.

  11. Microbial Community in a Sediment-Hosted CO2 Lake of the Southern Okinawa Trough Hydrothermal Field

    Science.gov (United States)

    Inagaki, F.; Kuypers, M. M.; Tsunogai, U.; Ishibashi, J.; Nakamura, K.; Treude, T.; Ohkubo, S.; Nakaseama, M.; Gena, K.; Chiba, H.; Hirayama, H.; Nunoura, T.; Takai, K.; Jorgensen, B. B.; Horikoshi, K.; Boetius, A.

    2006-12-01

    One-carbon assimilating (micro-)organisms play an important role for global carbon cycling; however, the increasing level of anthropogenic CO2 in the atmosphere has exceeded the capacity of natural biological feedback, hence as greenhouse gasses it is expected to cause climacteric change with negative effects on the earth's ecosystems and human society. To reduce CO2 emissions into the atmosphere, a variety of options have been discussed, including a disposal of CO2 into the deep ocean. However, the impact of CO2 disposal on deep-sea ecosystems as well as of the consequent microbiological feedback remains largely unknown. At the Yonaguni Knoll IV hydrothermal field, southern Okinawa Trough, we observed a natural liquid CO2 lake in sediments overlying elemental sulfur and CO2 hydrates at a water depth of 1380m. The liquid CO2 droplets were composed of 85% CO2 and 14% methane with hydrogen below the detection limit. We found high abundances (>109 cm-3) of microbial cells in sediment pavements above the CO2 lake, decreasing to strikingly low cell numbers (10&^{7} cm-3) at the liquid CO2/CO2-hydrate interface. Molecular ecological study based on the sequences of 16S rRNA genes showed that the key groups in these sediments were: (i) the anaerobic methanotrophic archaea ANME-2c and the Eel-2 group of Deltaproteobacteria, and (ii) sulfur-metabolizing chemolithotrophs within the Gamma- and Epsilonproteobacteria. The detection of functional genes (mcrA, cbbL) related to one- carbon assimilation as well as the presence of highly 13C-depleted archaeal and bacterial lipid biomarkers suggest that microorganisms assimilating CO2 and/or methane dominate the liquid CO2 and CO2-hydrate-bearing sediments. We propose that the Yonaguni Knoll is an exceptional natural laboratory for the study of consequences of CO2 disposal as well as of natural CO2 reservoirs as potential microbial habitats on early Earth and other celestial bodies.

  12. Hydrothermal processes above the Yellowstone magma chamber: Large hydrothermal systems and large hydrothermal explosions

    Science.gov (United States)

    Morgan, L.A.; Shanks, W.C. Pat; Pierce, K.L.

    2009-01-01

    Hydrothermal explosions are violent and dramatic events resulting in the rapid ejection of boiling water, steam, mud, and rock fragments from source craters that range from a few meters up to more than 2 km in diameter; associated breccia can be emplaced as much as 3 to 4 km from the largest craters. Hydrothermal explosions occur where shallow interconnected reservoirs of steam- and liquid-saturated fluids with temperatures at or near the boiling curve underlie thermal fields. Sudden reduction in confi ning pressure causes fluids to fl ash to steam, resulting in signifi cant expansion, rock fragmentation, and debris ejection. In Yellowstone, hydrothermal explosions are a potentially signifi cant hazard for visitors and facilities and can damage or even destroy thermal features. The breccia deposits and associated craters formed from hydrothermal explosions are mapped as mostly Holocene (the Mary Bay deposit is older) units throughout Yellowstone National Park (YNP) and are spatially related to within the 0.64-Ma Yellowstone caldera and along the active Norris-Mammoth tectonic corridor. In Yellowstone, at least 20 large (>100 m in diameter) hydrothermal explosion craters have been identifi ed; the scale of the individual associated events dwarfs similar features in geothermal areas elsewhere in the world. Large hydrothermal explosions in Yellowstone have occurred over the past 16 ka averaging ??1 every 700 yr; similar events are likely in the future. Our studies of large hydrothermal explosion events indicate: (1) none are directly associated with eruptive volcanic or shallow intrusive events; (2) several historical explosions have been triggered by seismic events; (3) lithic clasts and comingled matrix material that form hydrothermal explosion deposits are extensively altered, indicating that explosions occur in areas subjected to intense hydrothermal processes; (4) many lithic clasts contained in explosion breccia deposits preserve evidence of repeated fracturing

  13. Enhancement of zinc vacancies in room-temperature ferromagnetic Cr–Mn codoped ZnO nanorods synthesized by hydrothermal method under high pulsed magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Zhong, Min [Laboratory for Microstructures/School of Materials Science and Engineering, Shanghai University, 149 Yanchang Road, 200072 Shanghai (China); Li, Ying, E-mail: liying62@shu.edu.cn [Laboratory for Microstructures/School of Materials Science and Engineering, Shanghai University, 149 Yanchang Road, 200072 Shanghai (China); Hu, Yemin; Zhu, Mingyuan; Li, Wenxian; Jin, Hongmin; Wang, Shiwei [Laboratory for Microstructures/School of Materials Science and Engineering, Shanghai University, 149 Yanchang Road, 200072 Shanghai (China); Li, Yibing; Zhao, Huijun [Centre for Clean Environment and Energy, Griffith School of Environment, Griffith University, Gold Coast Campus, QLD 4222 (Australia)

    2015-10-25

    Room-temperature ferromagnetic Cr–Mn codoped ZnO diluted magnetic semiconductor was synthesized by pulse magnetic field-assisted hydrothermal method. X-ray diffraction and Raman spectra analysis reveal that all the samples have hexagonal wurtzite structure. High resolution transmission electron microscopy and Energy-dispersive spectroscopy measurements ensure that the Cr and Mn ions are incorporated into the wurtzite host matrix without any detectable impurity phase. X-ray photoelectron spectroscopy confirms that Mn and Cr ions are doped into the ZnO wurtzite host matrix with divalent states in the sample without magnetic field processing. Cr ions became trivalent states in ZnO synthesized with high pulsed magnetic field, while Mn keeps its divalent state. The presence of Cr{sup 3+} is attributed to hole doping in ZnO with zinc vacancies induced by the field. Magnetization measurements reveal the appearance of ferromagnetism for the magnetic field processed sample. Comparing with oxygen vacancies, zinc vacancies (hole doping) is more effectively to stabilized ferromagnetism in Mn-doped ZnO diluted magnetic semiconductors. - Graphical abstract: This figure shows the magnetization versus magnetic field curves for ZnO–Cr–Mn-0T and ZnO–Cr–Mn-4T at 290 K. The 4 T sample was well-defined hysteresis loops, which is indicative of room-temperature ferromagnetic behavior. But for 0 T sample, no ferromagnetic response at 290 K is observed. The hole doping enhanced by high pulsed magnetic field is crucial to stabilize ferromagnetism in Mn-doped ZnO diluted magnetic semiconductor. And the presence of Cr{sup 3+} in 4 T sample is a possible signature of hole doping induced by zinc vacancies. - Highlights: • Cr–Mn codoped ZnO nanorods were synthesized by hydrothermal method. • High pulsed magnetic field was applied during the hydrothermal method. • The valence state of doped elements was investigated by XPS. • High pulsed magnetic field enhances the

  14. Transfer function control strategy of Subak rice field land and agricultural development in Denpasar city

    Science.gov (United States)

    Lanya, Indayati; Netera Subadiyasa, N.; Sardiana, Ketut; Putu Ratna Adi, Gst.

    2017-01-01

    The success of tourism development in Bali gave a negative impact on Subak rice fields, especially on land convertion over 2579 ha year-1 (2002-2013) to the area awakened. Denpasar city has lost rice fields 185 ha year-1 and six Subak, as well as potentially losing 10 Subak, as a result of the allocation of space in the region in the Spatial Planing. UNESCO, in 2012 the establishment of Subak as a cultural heritage. Most Subak rice fields designated as an Urban Green Open Space ( UGOS). Satellite image Iconos 2002, World 2015 View Coverage of Denpasar, and ArcGIS 10.3 software used for mapping the balance of rice field and violation of land use in the area of UGOS. The control strategy over the convertion of spatial land-based environment is done through zoning map. Land conversion of rice fields for 13 years (2002-2015) in Denpasar (572.76 ha), comes standard acreage of rice fields in 2015. Denpasar city has experienced of food deficits, even in the UGOS has awakened 96.04 ha (24.04 ha year-1). A period of 50 years into the future, rice fields which needs to be protected 872.83 ha, buffer area 984.77 ha, and can be converted 499.81 ha.

  15. Hydrothermal systems in two areas of the Jemez volcanic field: Sulphur Springs and the Cochiti mining district

    Energy Technology Data Exchange (ETDEWEB)

    WoldeGabriel, G.

    1989-03-01

    K/Ar dates and oxygen isotope data were obtained on 13 clay separates (<2 ..mu..m) of thermally altered mafic and silicic rocks from the Cochiti mining district (SE Jemez Mountains) and Continental Scientific Drilling Project (CSDP) core hole VC-2A (Sulphur Springs, Valles caldera). Illite with K/sub 2/O contents of 6.68%--10.04% is the dominant clay in the silicic rocks, whereas interstratified illite/smectites containing 1.4%--5.74% K/sub 2/O constitute the altered andesites. Two hydrothermal alteration events are recognized at the Cochiti area (8.07 m.y., n = 1, and 6.5--5.6 m.y., n = 6). The older event correlates with the waning stages of Paliza Canyon Formation andesite volcanism (greater than or equal to13 to less than or equal to8.5 m.y.), whereas the younger event correlates with intrusions and gold- and silver-bearing quartz veins associated with the Bearhead Rhyolite (7.54--5.8 m.y.). The majority of K/Ar dates in the hydrothermally altered, caldera-fill rocks of core hole VC-2A (0.83--0.66 m.y., n = 4) indicate that hydrothermal alteration developed contemporaneously with resurgence and ring fracture Valles Rhyolite domes (0.89--0.54 m.y.). One date of 0 +- 0.10 m.y. in acid-altered landslide debris of postcaldera tuffs from the upper 13 m of the core hole probably correlates with Holocene hydrothermal activity possibly associated with the final phases of the Valles Rhyolite (0.13 m.y.).

  16. High connectivity of animal populations in deep-sea hydrothermal vent fields in the Central Indian Ridge relevant to its geological setting.

    Directory of Open Access Journals (Sweden)

    Girish Beedessee

    Full Text Available Dispersal ability plays a key role in the maintenance of species in spatially and temporally discrete niches of deep-sea hydrothermal vent environments. On the basis of population genetic analyses in the eastern Pacific vent fields, dispersal of animals in the mid-oceanic ridge systems generally appears to be constrained by geographical barriers such as trenches, transform faults, and microplates. Four hydrothermal vent fields (the Kairei and Edmond fields near the Rodriguez Triple Junction, and the Dodo and Solitaire fields in the Central Indian Ridge have been discovered in the mid-oceanic ridge system of the Indian Ocean. In the present study, we monitored the dispersal of four representative animals, Austinograea rodriguezensis, Rimicaris kairei, Alviniconcha and the scaly-foot gastropods, among these vent fields by using indirect methods, i.e., phylogenetic and population genetic analyses. For all four investigated species, we estimated potentially high connectivity, i.e., no genetic difference among the populations present in vent fields located several thousands of kilometers apart; however, the direction of migration appeared to differ among the species, probably because of different dispersal strategies. Comparison of the intermediate-spreading Central Indian Ridge with the fast-spreading East Pacific Rise and slow-spreading Mid-Atlantic Ridge revealed the presence of relatively high connectivity in the intermediate- and slow-spreading ridge systems. We propose that geological background, such as spreading rate which determines distance among vent fields, is related to the larval dispersal and population establishment of vent-endemic animal species, and may play an important role in controlling connectivity among populations within a biogeographical province.

  17. Microbial Diversity in Samples of High Temperature Vent Chimneys From the 71 °N Hydrothermal Fields at the Arctic Mid-Ocean Ridge

    Science.gov (United States)

    Steinsbu, B. O.; Daae, F.; Ovreaas, L.; Thorseth, I. H.; Pedersen, R. B.

    2007-12-01

    To get a first insight into the diversity of microorganisms present in the recently discovered active hydrothermal fields along the Mohns Ridge in the Norwegian-Greenland Sea, 16S rDNA clone libraries were constructed with DNA extracted from the walls of active smoker pipes from different locations. Enrichments targeting different physiological groups of microorganisms were prepared both under aerobic, micro-aerobic, and strictly anaerobic conditions. Different combinations of substrates and electron acceptors, pH, and temperatures were used. The enrichment cultures were monitored by use of PCR in combination with denaturing gradient gel electrophoresis (PCR-DGGE) and partial 16S rDNA sequencing. Species dominating in the enrichments were isolated, and their 16S rRNA genes were analyzed. The clones obtained from DNA amplified with primers specific for Archaea represented members of the orders Archaeoglobales, Thermococcales, Desulfurococcales, and Thermoproteales, as well as some unidentified groups. Three major fractions of the clones showed highest similarity to hyperthermophiles belonging to the families Pyrodictiaceae and Desulfurococcaceae, and an unidentified group which was given the name "Arctic Ridge Hydrothermal Vent Archaea" (ARHVA). The major fraction of the clones obtained by use of PCR primers specific for Bacteria affiliated with various genera of Aquificales. Clones representing Proteobacteria, Deferribacteres, Bacteroidetes, Deinococcus- Thermus, Chloroflexi and Firmicutes were also detected. Many clones were relatively distantly related to sequences in the GenBank database. Different types of both thermophiles and hyperthermophiles were enriched and isolated. The isolates were phylogenetically affiliated to Thermotogales, Thermales, Nautilales, Aquificales, Archaeoglobales, Thermococcales, and Desulfurococcales. The cultivation experiments documented the presence of microorganisms mediating various metabolic processes including fermentation

  18. Sustainable carbon materials from hydrothermal processes

    CERN Document Server

    Titirici, Maria-Magdalena

    2013-01-01

    The production of low cost and environmentally friendly high performing carbon materials is crucial for a sustainable future. Sustainable Carbon Materials from Hydrothermal Processes describes a sustainable and alternative technique to produce carbon from biomass in water at low temperatures, a process known as Hydrothermal Carbonization (HTC). Sustainable Carbon Materials from Hydrothermal Processes presents an overview of this new and rapidly developing field, discussing various synthetic approaches, characterization of the final products, and modern fields of application fo

  19. Multiple episodes of hydrothermal activity and epithermal mineralization in the southwestern Nevada volcanic field and their relations to magmatic activity, volcanism and regional extension

    Energy Technology Data Exchange (ETDEWEB)

    Weiss, S.I.; Noble, D.C.; Jackson, M.C. [Univ. of Nevada, Reno, NV (United States)] [and others

    1994-12-31

    Volcanic rocks of middle Miocene age and underlying pre-Mesozoic sedimentary rocks host widely distributed zones of hydrothermal alteration and epithermal precious metal, fluorite and mercury deposits within and peripheral to major volcanic and intrusive centers of the southwestern Nevada volcanic field (SWNVF) in southern Nevada, near the southwestern margin of the Great Basin of the western United States. Radiometric ages indicate that episodes of hydrothermal activity mainly coincided with and closely followed major magmatic pulses during the development of the field and together spanned more than 4.5 m.y. Rocks of the SWNVF consist largely of rhyolitic ash-flow sheets and intercalated silicic lava domes, flows and near-vent pyroclastic deposits erupted between 15.2 and 10 Ma from vent areas in the vicinity of the Timber Mountain calderas, and between about 9.5 and 7 Ma from the outlying Black Mountain and Stonewall Mountain centers. Three magmatic stages can be recognized: the main magmatic stage, Mountain magmatic stage (11.7 to 10.0 Ma), and the late magmatic stage (9.4 to 7.5 Ma).

  20. Carbon Species in Serpentinites and Gabbros Underlying the Lost City Hydrothermal Field, Southern Atlantis Massif (30°N, MAR)

    Science.gov (United States)

    Delacour, A.; Schaeffer, P.; Bernasconi, S. M.; Frueh-Green, G. L.

    2006-12-01

    Serpentinization of oceanic peridotites results in the production of volatile-rich (methane and hydrogen) fluids and other light hydrocarbons, and is characteristic of the low-temperature (squalane clearly indicate a biogenic origin, possibly incorporated into the serpentinites during fluid-rock interaction. Compound- specific C-isotope analyses show relatively constant compositions that overlap the bulk δ13CTOC values and are distinct from published values for methane in the LCHF fluids and experimental results for FTT synthesis of organic compounds. Our studies indicate that the ultramafic rocks of the LCHF may represent a significant reservoir of both abiogenic and biogenic carbon and that high seawater fluxes may greatly affect carbon speciation and budgets in these systems.

  1. Field Trip Guide to Serpentinite, Silica-Carbonate Alteration, and Related Hydrothermal Activity in the Clear Lake Region, California

    Energy Technology Data Exchange (ETDEWEB)

    Fraser Goff; George Guthrie

    1999-06-01

    This guide is designed to familiarize scientists with the geology, structure, alteration, and fluids typical of California serpentinites for purposes of carbon dioxide sequestration (Lackner et al., 1995). Goff et al. (1997) and Goff and Lackner (1998) describe the geology and geochemistry of some of the serpentinites from this area. Mechanisms of silica-carbonate alteration were outlined by Barnes et al. (1973). Donnelly-Nolan et al. (1993) most recently reviewed relations between regional hydrothermal alteration and Quarternary volcanic activity. Stanley et al. (1998) summarized geophysical characteristics of the region.

  2. Helium,neon and argon isotope compositions of fluid inclu-sions in massive sulfides from the Jade hydrothermal field,the Okinawa Trough

    Institute of Scientific and Technical Information of China (English)

    ZENG Zhigang; QIN Yunshan; ZHAI Shikui

    2004-01-01

    Helium, neon and argon isotope compositions of fluid inclusions have been measured in massive sulfide samples from the Jade hydrothermal field in the central Okinawa Trough. Huid-inclusion 3He/4He ratios are between 6.2 and 10.1 times the air value (Ra), and with a mean of 7.8Ra, which are consistent with the mid-ocean ridge basalt values [3He/4He≈(6Ra~11Ra)]. Values for 20Ne/22Ne are from 10.7 to 11.3, which are significantly higher than the atmospheric ratio (9.8).And the fluid-inclusion 40Ar/36Ar ratios range from 287 to 334, which are close to the atmosperic values (295.5). These results indicate that the noble gases of trapped hydrothermal fluids in massive sulfides are a mixture of mantle- and seawater-derived components, and the helium of fluid inclusions is mainly from mantle, the nelium and argon isotope compositions are mainly from seawater.

  3. Insights into life-history traits of Munidopsis spp. (Anomura: Munidopsidae) from hydrothermal vent fields in the Okinawa Trough, in comparison with the existing data

    Science.gov (United States)

    Nakamura, Masako; Chen, Chong; Mitarai, Satoshi

    2015-06-01

    Squat lobsters in the genus Munidopsis are commonly found at, and near, hydrothermal vents. However, the reproductive traits of most Munidopsis spp. are unknown. This study examined the reproductive features of two Munidopsis species sampled from hydrothermal vent fields in the southern Okinawa Trough in February 2014. Three ovigerous females were collected: two Munidopsis ryukyuensis at Irabu Knoll (1661-1675 m depth) and one M. longispinosa at Hatoma Knoll (1482 m depth). Carapace sizes and egg volumes were measured and compared with those of other Munidopsis species. The ovigerous M. ryukyuensis specimens had postorbital carapace lengths of 10.3 and 11.8 mm, without the rostrum, and carapace widths of 8.6 and 9.7 mm. Mean egg volumes of M. ryukyuensis and M. longispinosa were ~4 mm3. These results are consistent with early sexual maturity in M. ryukyuensis and lecithotrophic development in both species, as described in other species of the genus. These life-history traits may enable these vent species to maximize their reproductive and dispersive potential.

  4. Air Quality in Megacities: Lessons Learned from Mexico City Field Measurements

    Science.gov (United States)

    Molina, L. T.

    2014-12-01

    More than half of the world's population now lives in urban areas because of the opportunities for better jobs, access to city services, cultural and educational activities, and a desire for more stimulating human interaction. At the same time, many of these urban centers are expanding rapidly, giving rise to the phenomenon of megacities. In recent decades air pollution has become not only one of the most important environmental problems of megacities, but also presents serious consequences to human health and ecosystems and economic costs to society. Although the progress to date in combating air pollution problems in developed and some developing world megacities has been impressive, many challenges remain including the need to improve air quality while simultaneously mitigating climate change. This talk will present the results and the lessons learned from field measurements conducted in Mexico City Metropolitan Area - one of the world's largest megacities - over the past decade. While each city has its own unique circumstances, the need for an integrated assessment approach in addressing complex environmental problems is the same. There is no single strategy in solving air pollution problems in megacities; a mix of policy measures based on sound scientific findings will be necessary to improve air quality, protect public health, and mitigate climate change.

  5. Uncertainties in SOA simulations due to meteorological uncertainties in Mexico City during MILAGRO-2006 field campaign

    Science.gov (United States)

    Bei, N.; Li, G.; Molina, L. T.

    2013-05-01

    The purpose of the present study is to investigate the uncertainties in simulating secondary organic aerosol (SOA) in Mexico City metropolitan area (MCMA) due to meteorological initial uncertainties using the WRF-CHEM model through ensemble simulations. The simulated periods (24 and 29 March 2006) represent two typical meteorological episodes ("Convection-South" and "Convection-North", respectively) in the Mexico City basin during the MILAGRO-2006 field campaign. The organic aerosols are simulated using a non-traditional SOA model including the volatility basis-set modeling method and the contributions from glyoxal and methylglyoxal. Model results demonstrate that uncertainties in meteorological initial conditions have significant impacts on SOA simulations, including the peak time concentrations, the horizontal distributions, and the temporal variations. The ensemble spread of the simulated peak SOA at T0 can reach up to 4.0 μg m-3 during the daytime, which is around 35% of the ensemble mean. Both the basin wide wind speed and the convergence area affect the magnitude and the location of the simulated SOA concentrations inside the Mexico City basin. The wind speed, especially during the previous midnight and the following early morning, influences the magnitude of the peak SOA concentration through ventilation. The surface horizontal convergence zone generally determines the area with high SOA concentrations. The magnitude of the ensemble spreads may vary with different meteorological episodes but the ratio of the ensemble spread to mean does not change significantly.

  6. Hydrothermal activity in Tertiary Icelandic crust: Implication for cooling processes along slow-spreading mid-ocean ridges

    Science.gov (United States)

    Pałgan, D.; Devey, C. W.; Yeo, I. A.

    2015-12-01

    Known hydrothermal activity along the Mid-Atlantic Ridge is mostly high-temperature venting, controlled by volcano-tectonic processes confined to ridge axes and neotectonic zones ~15km wide on each side of the axis (e.g. TAG or Snake Pit). However, extensive exploration and discoveries of new hydrothermal fields in off-axis regions (e.g. Lost City, MAR) show that hydrothermalism may, in some areas, be dominated by off-axis venting. Little is known about nature of such systems, including whether low-temperature "diffuse" venting dominates rather than high-temperature black-smokers. This is particularly interesting since such systems may transport up to 90% of the hydrothermal heat to the oceans. In this study we use Icelandic hot springs as onshore analogues for off-shore hydrothermal activity along the MAR to better understand volcano-tectonic controls on their occurrence, along with processes supporting fluid circulation. Iceland is a unique laboratory to study how new oceanic crust cools and suggests that old crust may not be as inactive as previously thought. Our results show that Tertiary (>3.3 Myr) crust of Iceland (Westfjords) has widespread low-temperature hydrothermal activity. Lack of tectonism (indicated by lack of seismicity), along with field research suggest that faults in Westfjords are no longer active and that once sealed, can no longer support hydrothermal circulation, i.e. none of the hot springs in the area occur along faults. Instead, dyke margins provide open and permeable fluid migration pathways. Furthermore, we suggest that the Reykjanes Ridge (south of Iceland) may be similar to Westfjords with hydrothermalism dominated by off-axis venting. Using bathymetric data we infer dyke positions and suggest potential sites for future exploration located away from neotectonic zone. We also emphasise the importance of biological observations in seeking for low-temperature hydrothermal activity, since chemical or optical methods are not sufficient.

  7. Numerical analysis of magnetic field effects on hydro-thermal behavior of a magnetic nanofluid in a double pipe heat exchanger

    Science.gov (United States)

    Shakiba, Ali; Vahedi, Khodadad

    2016-03-01

    This study attempts to numerically investigate the hydro-thermal characteristics of a ferrofluid (water and 4 vol% Fe3O4) in a counter-current horizontal double pipe heat exchanger, which is exposed to a non-uniform transverse magnetic field with different intensities. The magnetic field is generated by an electric current going through a wire located parallel to the inner tube and between two pipes. The single phase model and the control volume technique have been used to study the flow. The effects of magnetic field have been added to momentum equation by applying C++ codes in Ansys Fluent 14. The results show that applying this kind of magnetic field causes kelvin force to be produced perpendicular to the ferrofluid flow, changing axial velocity profile and creating a pair of vortices which leads to an increase in Nusselt number, friction factor and pressure drop. Comparing the enhancement percentage of Nusselt number, friction factor and pressure drop demonstrates that the optimum value of magnetic number for Reff=50 is between Mn=1.33×106 and Mn=2.37×106. So applying non-uniform transverse magnetic field can control the flow of ferrofluid and improve heat transfer process of double pipe heat exchanger.

  8. The Arctic Gakkel Vents (AGAVE) Expedition: Technology Development and the Search for Deep-Sea Hydrothermal Vent Fields Under the Arctic Ice Cap

    Science.gov (United States)

    Reves-Sohn, R. A.; Singh, H.; Humphris, S.; Shank, T.; Jakuba, M.; Kunz, C.; Murphy, C.; Willis, C.

    2007-12-01

    Deep-sea hydrothermal fields on the Gakkel Ridge beneath the Arctic ice cap provide perhaps the best terrestrial analogue for volcanically-hosted chemosynthetic biological communities that may exist beneath the ice-covered ocean of Europa. In both cases the key enabling technologies are robotic (untethered) vehicles that can swim freely under the ice and the supporting hardware and software. The development of robotic technology for deep- sea research beneath ice-covered oceans thus has relevance to both polar oceanography and future astrobiological missions to Europa. These considerations motivated a technology development effort under the auspices of NASA's ASTEP program and NSF's Office of Polar Programs that culminated in the AGAVE expedition aboard the icebreaker Oden from July 1 - August 10, 2007. The scientific objective was to study hydrothermal processes on the Gakkel Ridge, which is a key target for global studies of deep-sea vent fields. We developed two new autonomous underwater vehicles (AUVs) for the project, and deployed them to search for vent fields beneath the ice. We conducted eight AUV missions (four to completion) during the 40-day long expedition, which also included ship-based bathymetric surveys, CTD/rosette water column surveys, and wireline photographic and sampling surveys of remote sections of the Gakkel Ridge. The AUV missions, which lasted 16 hours on average and achieved operational depths of 4200 meters, returned sensor data that showed clear evidence of hydrothermal venting, but for a combination of technical reasons and time constraints, the AUVs did not ultimately return images of deep-sea vent fields. Nevertheless we used our wireline system to obtain images and samples of extensive microbial mats that covered fresh volcanic surfaces on a newly discovered set of volcanoes. The microbes appear to be living in regions where reducing and slightly warm fluids are seeping through cracks in the fresh volcanic terrain. These discoveries

  9. Detection of active hydrothermal vent fields in the Pescadero Basin and on the Alarcon Rise using AUV multibeam and CTD data

    Science.gov (United States)

    Caress, D. W.; Troni, G.; Clague, D. A.; Paduan, J. B.; Martin, J. F.; Thomas, H. J.; Thompson, D.; Conlin, D.; Martin, E. J.; meneses-Quiroz, E.; Nieves-Cardoso, C.; Angel Santa Rosa del Rio, M.

    2015-12-01

    The MBARI AUV D. Allan B. collected high resolution bathymetry, sidescan, and subbottom profiles along the neovolcanic zone of the Alarcon Rise and across the southern Pescadero Basin during 2012 and 2015 MBARI expeditions to the Gulf of California (GOC). The combination of high resolution multibeam bathymetry and seawater temperature data has proven effective in identifying active high temperature vent fields, as validated by inspection and sampling during ROV dives. The AUV carries a 200 kHz multibeam sonar, 110 kHz chirp sidescan sonar, a 1-6 kHz chirp subbottom profiler, and a conductivity, temperature and depth (CTD) sensor for ~17-hour duration missions. Flying at 5.4 km/hr at 50 m altitude, the processed AUV bathymetry has a 0.1 m vertical precision and a 1 m lateral resolution. Chimneys taller than 1.5 m are sufficiently distinctive to allow provisional identification. The CTD temperature data have a nominal 0.002°C accuracy. Following calculation of potential temperature and correcting for average local variation of potential temperature with depth, anomalies greater than 0.05 °C can be reliably identified using a spike detection filter. MBARI AUV mapping surveys are typically planned using a 150 m survey line spacing, so the CTD data may be collected as much as 75 m away from any vent plume source. Five active high temperature vent fields were discovered in the southern GOC, with the Auka Field in the southern Pescadero Basin, and the Ja Sít, Pericú, Meyibó, and Tzab-ek Fields along the Alarcon Rise. In all five cases, hydrothermal vent chimneys are readily identifiable in the multibeam bathymetry, and temperature anomalies are observed above background variability. Other apparent hydrothermal chimneys were observed in the bathmetry that did not exhibit water temperature anomalies; most of these were visited during ROV dives and confirmed to be inactive sites. The maximum water column anomalies are 0.13°C observed above the Meyibó field and 0.25

  10. Relations between electrical resistivity, carbon dioxide flux, and self-potential in the shallow hydrothermal system of Solfatara (Phlegrean Fields, Italy)

    Science.gov (United States)

    Byrdina, S.; Vandemeulebrouck, J.; Cardellini, C.; Legaz, A.; Camerlynck, C.; Chiodini, G.; Lebourg, T.; Gresse, M.; Bascou, P.; Motos, G.; Carrier, A.; Caliro, S.

    2014-08-01

    We present the results of an electric resistivity tomography (ERT) survey, combined with mappings of diffuse carbon dioxide flux, ground temperature and self-potential (SP) at Solfatara, the most active crater of Phlegrean Fields. Solfatara is characterized by an intense carbon dioxide degassing, fumarole activity, and ground deformation. This ensemble of methods is applied to image the hydrothermal system of Solfatara, to understand the geometry of the fluid circulation, and to define the extension of the hydrothermal plume at a high enough resolution for a quantitative modeling. ERT inversion results show Solfatara as a globally conductive structure, with resistivity in the range 1-200 Ω m. Broad negative anomaly of self-potential in the inner part of Solfatara with a minimum in the area of Bocca Grande suggests a significant downward flow of condensing liquid water. Comparison between spatial variations of resistivity and gas flux indicates that resistivity changes at depth are related to gas saturation and fluid temperature. These variations delineate two plume structures: a liquid-dominated conductive plume below Fangaia mud-pool and a gas-dominated plume below Bocca Grande fumarole. The geometry of the Fangaia liquid-saturated plume is also imaged by a high resolution 3-D resistivity model. In order to estimate the permeability, we propose a 2-D axis-symmetric numerical model coupling Richards equation for fluid flow in conditions of partial saturation with the resistivity calculation as function of saturation only. Alternatively, we apply the Dupuit equation to estimate the permeability of the shallow layer. Using these two approaches we obtain the permeability of the shallow layer below Fangaia which ranges between (2-4) × 10- 14 m2.

  11. Using Acceleration Records as Diffuse Fields for Tomography of the Valley of Mexico City: Synthetic Results

    Science.gov (United States)

    Baena, M.; Perton, M.; Molina-Villegas, J. C.; Sanchez-Sesma, F. J.

    2013-12-01

    In order to improve the understanding of the seismic response of Mexico City Valley, we have proposed to perform a tomography study of the seismic wave velocities. For that purpose, we used a collection of acceleration seismograms (corresponding to earthquakes with magnitudes ranging from 4.5 to 8.1 and various epicentral distances to the City) recorded since 1985 in 83 stations distributed across the Valley. The H/V spectral ratios (obtained from average autocorrelations) strongly suggest these movements belong to a 3D generalized diffuse field. Thus, we interpret that cross-correlations between the signals of station pairs are proportional to the imaginary part of the corresponding Green function. Finally, the dispersion curves are constructed from the Green function which lead to the tomography. Other tomographies have already been made around the world using either the seismic coda or seismic noise. We used instead the ensemble of many earthquakes from distant sources that have undergone multiple scattering by the heterogeneities of the Earth and assume the wave fields are equipartitioned. The purpose of the present study is to describe the different steps of the data processing by using synthetic models. The wave propagation within an alluvial basin is simulated using the Indirect Boundary Element Method (IBEM) in 2D configuration for the propagation of P and SV waves. The theoretical Green function for a station pair is obtained by placing a unit force at one station and a receiver at the other. The valley illumination is composed by incoming waves which are simulated using distant independent sources and several diffractors. Data process is validated by the correct retrieval the theoretical Green function. We present here the in-plane Green function for the P-SV case and show the dispersion curves constructed from the cross-correlations compared with analytic results for a layer over a half-space. ACKNOWLEDGEMENTS. This study is partially supported by AXA

  12. Novel barite chimneys at the Loki´s Castle Vent Field shed light on key factors shaping microbial communities and functions in hydrothermal systems

    Directory of Open Access Journals (Sweden)

    Ida Helene eSteen

    2016-01-01

    Full Text Available In order to fully understand the cycling of elements in hydrothermal systems it is critical to understand intra-field variations in geochemical and microbiological processes in both focused, high-temperature and diffuse, low-temperature areas. To reveal important causes and effects of this variation, we performed an extensive chemical and microbiological characterization of a low-temperature venting area in the Loki’s Castle Vent Field (LCVF. This area, located at the flank of the large sulfide mound, is characterized by numerous chimney-like barite (BaSO4 structures (≤ 1m high covered with white cotton-like microbial mats. Results from geochemical analyses, microscopy (FISH, SEM, 16S rRNA gene amplicon-sequencing and metatranscriptomics were compared to results from previous analyses of biofilms growing on black smoker chimneys at LCVF. Based on our results, we constructed a conceptual model involving the geochemistry and microbiology in the LCVF. The model suggests that CH4 and H2S are important electron donors for microorganisms in both high-temperature and low-temperature areas, whereas the utilization of H2 seems restricted to high-temperature areas. This further implies that sub-seafloor processes can affect energy-landscapes, elemental cycling, and the metabolic activity of primary producers on the seafloor. In the cotton-like microbial mats on top of the active barite chimneys, a unique network of single cells of Epsilonproteobacteria interconnected by threads of extracellular polymeric substances (EPS was seen, differing significantly from the long filamentous Sulfurovum filaments observed in biofilms on the black smokers. This network also induced nucleation of barite crystals and is suggested to play an essential role in the formation of the microbial mats and the chimneys. Furthermore, it illustrates variations in how different genera of Epsilonproteobacteria colonize and position cells in different vent fluid mixing zones within

  13. Novel Barite Chimneys at the Loki's Castle Vent Field Shed Light on Key Factors Shaping Microbial Communities and Functions in Hydrothermal Systems.

    Science.gov (United States)

    Steen, Ida H; Dahle, Håkon; Stokke, Runar; Roalkvam, Irene; Daae, Frida-Lise; Rapp, Hans Tore; Pedersen, Rolf B; Thorseth, Ingunn H

    2015-01-01

    In order to fully understand the cycling of elements in hydrothermal systems it is critical to understand intra-field variations in geochemical and microbiological processes in both focused, high-temperature and diffuse, low-temperature areas. To reveal important causes and effects of this variation, we performed an extensive chemical and microbiological characterization of a low-temperature venting area in the Loki's Castle Vent Field (LCVF). This area, located at the flank of the large sulfide mound, is characterized by numerous chimney-like barite (BaSO4) structures (≤ 1 m high) covered with white cotton-like microbial mats. Results from geochemical analyses, microscopy (FISH, SEM), 16S rRNA gene amplicon-sequencing and metatranscriptomics were compared to results from previous analyses of biofilms growing on black smoker chimneys at LCVF. Based on our results, we constructed a conceptual model involving the geochemistry and microbiology in the LCVF. The model suggests that CH4 and H2S are important electron donors for microorganisms in both high-temperature and low-temperature areas, whereas the utilization of H2 seems restricted to high-temperature areas. This further implies that sub-seafloor processes can affect energy-landscapes, elemental cycling, and the metabolic activity of primary producers on the seafloor. In the cotton-like microbial mats on top of the active barite chimneys, a unique network of single cells of Epsilonproteobacteria interconnected by threads of extracellular polymeric substances (EPS) was seen, differing significantly from the long filamentous Sulfurovum filaments observed in biofilms on the black smokers. This network also induced nucleation of barite crystals and is suggested to play an essential role in the formation of the microbial mats and the chimneys. Furthermore, it illustrates variations in how different genera of Epsilonproteobacteria colonize and position cells in different vent fluid mixing zones within a vent field

  14. Atmospheric electric field effects of cosmic rays detected in Mexico City

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, L. X; Valdes-Galicia, J. F [Instituto de Geofisica, Universidad National Autonoma de Mexico, Mexico D.F(Mexico)

    2006-10-15

    We studied the possible effects of atmospheric electric fields, generated in thunderstorms, on the cosmic ray intensity detected at the Earth's surface by investigating the variations of the counting rates of the cosmic-ray nucleonic component, obtained from the neutron monitor installed in Mexico City, for thunderstorms during 1996 and 1997. These were years of minimum solar activity. We compare our experimental results with the general theory of cosmic ray meteorological effects by Dorman (1995). The observed intensity variation is about 0.2%. According to Dorman (1995), the effect should be between 0.27% and 0.81% on the counting rate of the neutron monitor when the atmospheric electric field intensities are around 100 to 300 Vcm-1.Our results show that either the electric field in Mexico City had less intensity than assumed by Dorman (1995), or the electric field is not uniform in time and height during the development of the thunderstorm. [Spanish] Estudiamos los posibles efectos de los campos electricos atmosfericos, generados en las tormentas electricas, sobre la intensidad de los rayos cosmicos detectados en la superficie terrestre, analizando las variaciones de las razones de conteo de la componente nucleonica de los rayos cosmicos, obtenidas por el monitor de neutrones instalado en la ciudad de Mexico, durante tormentas electricas ocurridas entre 1996 y 1997, anos del minimo solar. Comparamos nuestros resultados experimentales con la teoria general de los efectos meteorologicos en los rayos cosmicos, desarrollada por Dorman (1995). Se observo una variacion en la intensidad de alrededor de 0.2%. De acuerdo con Dorman (1995), el efecto puede estar entre 0.27 % y 0.81% en las razones de conteo del monitor de neutrones cuando las intensidades del campo electrico atmosferico se encuentran al rededor de 100 a 300 Vcm-1. Nuestros resultados muestran que los campos electricos en la ciudad de Mexico tuvieron menos intensidad que los campos electricos asumidos

  15. Hydrothermal Biogeochemistry

    Science.gov (United States)

    Shock, E.; Havig, J.; Windman, T.; Meyer-Dombard, D.; Michaud, A.; Hartnett, H.

    2006-12-01

    Life in hot spring ecosystems is confronted with diverse challenges, and the responses to those challenges have dynamic biogeochemical consequences over narrow spatial and temporal scales. Within meters along hot spring outflow channels at Yellowstone, temperatures drop from boiling, and the near-boiling conditions of hot chemolithotrophic communities, to those that permit photosynthesis and on down to conditions where nematodes and insects graze on the edges of photosynthetic mats. Many major and trace element concentrations change only mildly in the water that flows through the entire ecosystem, while concentrations of other dissolved constituents (oxygen, sulfide, ammonia, total organic carbon) increase or decrease dramatically. Concentrations of metals and micronutrients range from toxic to inadequate for enzyme synthesis depending on the choice of hot spring. Precipitation of minerals may provide continuous growth of microbial niches, while dissolution and turbulent flow sweeps them away. Consequently, microbial communities change at the meter scale, and even more abruptly at the photosynthetic fringe. Isotopic compositions of carbon and nitrogen in microbial biomass reflect dramatic and continuous changes in metabolic strategies throughout the system. Chemical energy sources that support chemolithotrophic communities can persist at abundant or useless levels, or change dramatically owing to microbial activity. The rate of temporal change depends on the selection of hot spring systems for study. Some have changed little since our studies began in 1999. Others have shifted by two or more units in pH over several years, with corresponding changes in other chemical constituents. Some go through daily or seasonal desiccation cycles, and still others exhibit pulses of changing temperature (up to 40°C) within minutes. Taken together, hydrothermal ecosystems provide highly manageable opportunities for testing how biogeochemical processes respond to the scale of

  16. Barite from the Saf'yanovka VMS deposit (Central Urals) and Semenov-1 and Semenov-3 hydrothermal sulfide fields (Mid-Atlantic Ridge): a comparative analysis of formation conditions

    Science.gov (United States)

    Safina, Nataliya P.; Melekestseva, Irina Yu.; Nimis, Paolo; Ankusheva, Nataliya N.; Yuminov, Anatoly M.; Kotlyarov, Vasily A.; Sadykov, Sergey A.

    2016-04-01

    Different genetic types of barite from colloform and clastic pyrite-rich ores from the weakly metamorphic Saf'yanovka volcanogenic massive sulfide (VMS) deposit (Central Urals) were studied in comparison with barite from the Semenov-1 and Semenov-3 seafloor hydrothermal fields (mid-Atlantic Ridge). Hydrothermal barite generally occurs as radial aggregates of tabular crystals in contrast to compact aggregates of tabular crystals with stylolite boundaries of anadiagenetic barite from the Saf'yanovka clastic ores. The Sr content in barite shows no relationship with the genetic types. The δ34S values of hydrothermal barite from both ancient and modern colloform sulfides match those of Silurian-Devonian and contemporary seawater, respectively. The lower δ34S (avg +19.6 ‰) of hydrothermal barite from the Semenov-3 clastic sulfides indicates light sulfur contribution from oxidation of fluid H2S. The higher δ34S (avg +28.1 ‰) of anadiagenetic barite from the Saf'yanovka clastic ores reflects partial thermochemical reduction of seawater sulfate. Hydrothermal barite from the Saf'yanovka and Semenov-1 colloform ores formed from low- to moderate- T (172-194 °C and 83-233 °C, respectively) relatively low salinity (1.6-4.5 and 0.6-3.8 wt% NaCleq, respectively) fluids, which underwent phase separation. Hydrothermal barite from Semenov-3 clastic sulfides associated with chalcopyrite crystallized from higher- T (266-335 °C) higher-salinity (4.8-9.2 wt% NaCleq.) fluids. The high salinity may indicate a contribution from a magmatic fluid. Anadiagenetic barite from Saf'yanovka was formed from moderate- T (140-180 °C), low- to moderate-salinity (1.4-5.4 wt% NaCleq) pore fluids. Combining our new data with those for other seafloor hydrothermal barite occurrences, the following systematics can be defined. Barite associated with pyrite-rich sulfides forms at relatively low to moderate temperatures (<230 °C), barite associated with polymetallic-rich sulfides forms at moderately

  17. Tectonophysical Features of the Hydrothermal Fields in the Middle Okinawa Trough%冲绳海槽中部热液活动区构造地球物理特征分析

    Institute of Scientific and Technical Information of China (English)

    栾锡武; 翟世奎; 干晓群

    2001-01-01

    Hydrothermal activity is widely occurring along the active plate boundaries and intraplate volcanic centers which is exchanging heat and material between the lithosphere and the oceans.Okinawa Trough is an important part of Ryuky T-A-ba system which is in the collision and subduction zone between a oceanic block and continental block and is reported to be in the early stage of back-arc spreading with a rift structure and an embryonic marginal basin,its origin and evolution may be one of the most interseting problems in geophysics and geology to day.Hydrothermal activity as a window and clue of studying the origin and evolut ion of Okinawa Trough has been explored through out the Trough by scientists all over the worlds.Several hydrothermal fields have been found in the middle part of Okinawa Trough.Tectonophysical features of topography,heatflow distribution,s eismicity and magnetic anomaly of three hydrothermal fields including southwest Amami hydrothermal field、Iheya deep hydrothermal field and Izena caldron hydroth ermal field in the middle Okinawa Trough were studied.The results show that all the hydrothermal fields distribute in the central graben and locate at the slope of caldera or of central ridge with high and vary heatflow distribution,active seismic activities and fluctuating magnetic anomaly.It is found that the hydroth ermal fields have close relationship with tectonic zoon.In the area of Ryukyu T -A-Ba system,the upwelling of mantal materials beneath the trough due to the subduction of Pacific Plate provides heat energy for the hydrothermal activity.The faults formation in the process of trough expending provides space for the hydrothermal activity.%对冲绳海槽中部南奄西、伊平屋、伊士名三个现代海底热液活动区的地形、热流分布、地震、地磁场特征进行了初步研究。结果表明,海槽中部的热液活动区都集中于海槽的中央地堑中,或位于火山口的侧坡上,或位于地堑中山脊

  18. Phase 2 and 3 Slim Hole Drilling and Testing at the Lake City, California Geothermal Field

    Energy Technology Data Exchange (ETDEWEB)

    Dick Benoit; David Blackwell; Joe Moore; Colin Goranson

    2005-10-27

    temperatures of 270 to 310 oF), intermediate (elevation 2800 to 3700 ft and temperatures 270 to 320 oF ) and deep (elevations < 1000 ft and temperatures 323 to 337 oF) components. In the south part of the field, near Phipps #2 the shallow and deep components are present. In the central part of the field, near OH-1 the shallow and intermediate components are present and presumably the deep component is also present. In the north part of the field, the intermediate and deep components are present. Most or all of the fractures in the core have dips between 45 degrees and vertical and no strong stratigraphic control on the resource has yet been demonstrated. Conceptually, the Lake City geothermal resource seems to be located along the north-south trending range front in a relatively wide zone of fractured rock. The individual fractures do not seem to be associated with any readily identifiable fault. In fact, no major hydraulically conductive faults were identified by the core drilling.

  19. Assessment of Human Exposure to Magnetic Field from Overhead High Voltage Transmission Lines in a City in South Western Nigeria

    OpenAIRE

    Ponnle Akinlolu; Adedeji Kazeem

    2015-01-01

    The increase in electricity consumption, population, and land use has now forced high voltage transmission lines (HVTLs) either to pass or be installed around or through urban cities. This increases the level of human exposure to electromagnetic field radiation as this field produced around the HVTLs extends outwards covering some distance. This may cause a number of health hazards. It is even dangerous to a human who touch any metallic object in proximity of the HVTL, as it may have an appre...

  20. Field Study of all GSM and WiFi Networks in Amman City from Geospatial Perspective

    Science.gov (United States)

    Hawarey, Mosab; Alibrahim, Mustafa; Jetto, Hamza; Salah Mahmoud, Firas

    2016-04-01

    A thorough field study over multiple months has been conducted in the streets of Amman, the capital city of Jordan, in order to collect massive amounts of GSM and WiFi data and analyze them from geospatial perspective. Some interesting realities have been detected; e.g. the North and West of Amman are much better served by GSM operators than the East, South, and Center. Also, the security measures taken to protect WiFi networks in the North and West are much better than those in the East, South, and Center. This has led to the recognition of an interesting pattern that groups the North and West together, while the East, South, and Center constitute another group. Extremely interesting finding was found; the GSM signals are so strong at certain locations that they constitute direct lethal threat to human health; it is scientifically documented that such strengths would lead to certain human cell mutations and cancer. The exact locations and contributors of such hazards will be disclosed in this paper for the first time. Many tabular and graphical presentations of the data will be presented.

  1. Dynamics of the Yellowstone hydrothermal system

    Science.gov (United States)

    Hurwitz, Shaul; Lowenstern, Jacob B.

    2014-01-01

    The Yellowstone Plateau Volcanic Field is characterized by extensive seismicity, episodes of uplift and subsidence, and a hydrothermal system that comprises more than 10,000 thermal features, including geysers, fumaroles, mud pots, thermal springs, and hydrothermal explosion craters. The diverse chemical and isotopic compositions of waters and gases derive from mantle, crustal, and meteoric sources and extensive water-gas-rock interaction at variable pressures and temperatures. The thermal features are host to all domains of life that utilize diverse inorganic sources of energy for metabolism. The unique and exceptional features of the hydrothermal system have attracted numerous researchers to Yellowstone beginning with the Washburn and Hayden expeditions in the 1870s. Since a seminal review published a quarter of a century ago, research in many fields has greatly advanced our understanding of the many coupled processes operating in and on the hydrothermal system. Specific advances include more refined geophysical images of the magmatic system, better constraints on the time scale of magmatic processes, characterization of fluid sources and water-rock interactions, quantitative estimates of heat and magmatic volatile fluxes, discovering and quantifying the role of thermophile microorganisms in the geochemical cycle, defining the chronology of hydrothermal explosions and their relation to glacial cycles, defining possible links between hydrothermal activity, deformation, and seismicity; quantifying geyser dynamics; and the discovery of extensive hydrothermal activity in Yellowstone Lake. Discussion of these many advances forms the basis of this review.

  2. The divided city: the territory of informality as an affective field

    Directory of Open Access Journals (Sweden)

    Mónica Aubán Borrell

    2016-10-01

    Full Text Available The contradictory nature of informal settlements open up a space to think about the complex implications of the contemporary city. This article proposes an affective reading which will enable a reconsideration of the negative conditions that de ne the informal city, with the aim of reorienting the research of effective transformations within these territories. An approach to the case of Rio de Janeiro will allow delving into the individual-territory relationship in order to relocate the subjective dimension of the city as a key factor in the socio-spatial articulation of informality.

  3. Natural hot spots for gain of multiple resistances: arsenic and antibiotic resistances in heterotrophic, aerobic bacteria from marine hydrothermal vent fields.

    Science.gov (United States)

    Farias, Pedro; Espírito Santo, Christophe; Branco, Rita; Francisco, Romeu; Santos, Susana; Hansen, Lars; Sorensen, Soren; Morais, Paula V

    2015-04-01

    Microorganisms are responsible for multiple antibiotic resistances that have been associated with resistance/tolerance to heavy metals, with consequences to public health. Many genes conferring these resistances are located on mobile genetic elements, easily exchanged among phylogenetically distant bacteria. The objective of the present work was to isolate arsenic-, antimonite-, and antibiotic-resistant strains and to determine the existence of plasmids harboring antibiotic/arsenic/antimonite resistance traits in phenotypically resistant strains, in a nonanthropogenically impacted environment. The hydrothermal Lucky Strike field in the Azores archipelago (North Atlantic, between 11°N and 38°N), at the Mid-Atlantic Ridge, protected under the OSPAR Convention, was sampled as a metal-rich pristine environment. A total of 35 strains from 8 different species were isolated in the presence of arsenate, arsenite, and antimonite. ACR3 and arsB genes were amplified from the sediment's total DNA, and 4 isolates also carried ACR3 genes. Phenotypic multiple resistances were found in all strains, and 7 strains had recoverable plasmids. Purified plasmids were sequenced by Illumina and assembled by EDENA V3, and contig annotation was performed using the "Rapid Annotation using the Subsystems Technology" server. Determinants of resistance to copper, zinc, cadmium, cobalt, and chromium as well as to the antibiotics β-lactams and fluoroquinolones were found in the 3 sequenced plasmids. Genes coding for heavy metal resistance and antibiotic resistance in the same mobile element were found, suggesting the possibility of horizontal gene transfer and distribution of theses resistances in the bacterial population.

  4. Field Calibration of the δ11B-pH Proxy in Corals and Calcified Algae at a Shallow Hydrothermal Vent and Adjacent Coral Reef

    Science.gov (United States)

    Day, R. D.; Christopher, S. J.; Young, C.; Brainard, R. E.; Butterfield, D. A.; Stewart, J.

    2015-12-01

    There is increasing interest in using the boron isotopic composition (δ11B) of biogenic carbonates as a proxy for seawater pH to better understand recent ocean acidification. The utility of this proxy hinges on the production of robust species-specific δ11B-pH calibrations; yet, challenges remain in the interpretation of boron isotope data due to biases introduced by physiological, environmental, and analytical factors. The shallow hydrothermal vents in the Maug Islands caldera (Marianas Islands) and the adjacent coral reefs exhibit a localized gradient > 1 pH unit. This gradient was used as a natural laboratory to assess the efficacy of using skeletal δ11B in a variety of corals (Porites spp., Pocillipora spp., Acropora spp.) and calcified algae (Halimeda spp. and Corallinales) as biosensors of seawater pH. Three sites were selected representing oceanic background, intermediate, and low pH zones, and direct seawater pH measurements were recorded for 3 months using SeaFETs. Corals and algae growing naturally in situ were collected from these 3 sites. In addition, corals and algae collected from a background location were stained and transplanted to these sites and allowed to grow for 3 months. Measurements of δ11B in skeletal material made by multi-collector inductively coupled mass spectrometry are compared to direct seawater pH measurements to assess the sensitivity and robustness of the δ11B proxy in these candidate biosensors in predicting ambient pH in the field. These data will inform ongoing efforts by the Archive of Coral Ecosystem Specimens (ACES) to collect marine carbonates for analysis and archival in the Marine Environmental Specimen Bank for broad-scale, long-term monitoring of ocean acidification and the associated impacts to coral reefs. Concurrent analyses of other trace elements, heavy metals, and isotopes in these samples will also be performed to assess their utility as biosensors for additional water chemistry parameters on coral reefs.

  5. Acoustic monitoring of co-seismic changes in gas bubble rupture rate in a hydrothermal reservoir: field evaluation of a possible precursor and mechanism for remote seismic triggering

    Science.gov (United States)

    Crews, J. B.

    2015-12-01

    Remotely triggered seismicity is a phenomenon in which an earthquake at one location triggers others over distances up to thousands of kilometers. The mechanism by which low-amplitude dynamic oscillations of the confining stress can produce such an effect, often after a time delay of minutes-to-days, is unclear, but a concentration of remotely triggered seismic events in carbon-dioxide-rich volcanic and geothermal regions suggests that an increase in pore fluid pressure associated with the nucleation and growth of carbon-dioxide gas bubbles may reduce the effective stress in critically loaded geologic faults. While this hypothesis has been tested in bench-scale laboratory experiments, field detection of seismically initiated gas bubble growth in groundwater may provide further evidence for this remote triggering mechanism. In the present study, a hydrophone continuously records the acoustic power spectrum in CH-10B, a hydrothermal well located in Long Valley Caldera, California - a site that is susceptible to remotely seismic triggering. This well exhibits co-seismic changes in water level in response to near and distant earthquakes, including every magnitude-six or greater at any location on Earth. Exploiting the inverse relationship between gas bubble radius and the peak acoustic frequency emitted when a gas bubble ruptures, this investigation seeks to detect changes in the acoustic power spectrum arising from a shift in the size-distribution or count rate of rupturing gas bubbles, coincident with a distant earthquake. By resolving the timing and intensity of the onset of a change in gas bubble rupture rate after the passage of seismic wave from a distant source, it may be possible to establish the extent to which seismically initiated gas bubble growth contributes to co-seismic borehole water level response, pore fluid pressure perturbations, and the onset of remotely triggered seismicity.

  6. Anhydrite Solubility and Ca Isotope Fractionation in the Vapor-Liquid Field of the NaCl-H2O System: Implications for Hydrothermal Vent Fluids at Mid-ocean Ridges

    Science.gov (United States)

    Scheuermann, P.; Syverson, D. D.; Higgins, J. A.; Seyfried, W. E., Jr.

    2015-12-01

    Hydrothermal experiments were performed at 410, 420 and 450°C between 180-450 bar to investigate anhydrite (CaSO4) solubility and Ca isotope fractionation in the liquid-vapor stability field of the NaCl-H2O system. Experiments were conducted in flexible gold reaction cells and a fixed volume Ti reactor to reach all pressures between the critical curve and three-phase boundary. During isothermal decompression at 410°C, anhydrite solubility in the liquid phase increases (1 to 9 mmol/kg Ca), whereas the solubility decreases in the vapor phase (130 to systems with implications for mass transfer reactions at/near the magma-hydrothermal boundary at mid-ocean ridges.

  7. Field Demonstration of Carbon Dioxide Miscible Flooding in the Lansing-Kansas City Formation, Central Kansas

    Energy Technology Data Exchange (ETDEWEB)

    Alan Byrnes; G. Paul Willhite; Don Green; Richard Pancake; JyunSyung Tsau; W. Lynn Watney; John Doveton; Willard Guy; Rodney Reynolds; Dave Murfin; James Daniels; Russell Martin; William Flanders; Dave Vander Griend; Eric Mork; Paul Cantrell

    2010-03-07

    A pilot carbon dioxide miscible flood was initiated in the Lansing Kansas City C formation in the Hall Gurney Field, Russell County, Kansas. The reservoir zone is an oomoldic carbonate located at a depth of about 2900 feet. The pilot consists of one carbon dioxide injection well and three production wells. Continuous carbon dioxide injection began on December 2, 2003. By the end of June 2005, 16.19 MM lb of carbon dioxide was injected into the pilot area. Injection was converted to water on June 21, 2005 to reduce operating costs to a breakeven level with the expectation that sufficient carbon dioxide was injected to displace the oil bank to the production wells by water injection. By March 7,2010, 8,736 bbl of oil were produced from the pilot. Production from wells to the northwest of the pilot region indicates that oil displaced from carbon dioxide injection was produced from Colliver A7, Colliver A3, Colliver A14 and Graham A4 located on adjacent leases. About 19,166 bbl of incremental oil were estimated to have been produced from these wells as of March 7, 2010. There is evidence of a directional permeability trend toward the NW through the pilot region. The majority of the injected carbon dioxide remains in the pilot region, which has been maintained at a pressure at or above the minimum miscibility pressure. Estimated oil recovery attributed to the CO2 flood is 27,902 bbl which is equivalent to a gross CO2 utilization of 4.8 MCF/bbl. The pilot project is not economic.

  8. Microbial community stratification controlled by the subseafloor fluid flow and geothermal gradient at the Iheya North hydrothermal field in the Mid-Okinawa Trough (Integrated Ocean Drilling Program Expedition 331).

    Science.gov (United States)

    Yanagawa, Katsunori; Breuker, Anja; Schippers, Axel; Nishizawa, Manabu; Ijiri, Akira; Hirai, Miho; Takaki, Yoshihiro; Sunamura, Michinari; Urabe, Tetsuro; Nunoura, Takuro; Takai, Ken

    2014-10-01

    The impacts of lithologic structure and geothermal gradient on subseafloor microbial communities were investigated at a marginal site of the Iheya North hydrothermal field in the Mid-Okinawa Trough. Subsurface marine sediments composed of hemipelagic muds and volcaniclastic deposits were recovered through a depth of 151 m below the seafloor at site C0017 during Integrated Ocean Drilling Program Expedition 331. Microbial communities inferred from 16S rRNA gene clone sequencing in low-temperature hemipelagic sediments were mainly composed of members of the Chloroflexi and deep-sea archaeal group. In contrast, 16S rRNA gene sequences of marine group I Thaumarchaeota dominated the microbial phylotype communities in the coarse-grained pumiceous gravels interbedded between the hemipelagic sediments. Based on the physical properties of sediments such as temperature and permeability, the porewater chemistry, and the microbial phylotype compositions, the shift in the physical properties of the sediments is suggested to induce a potential subseafloor recharging flow of oxygenated seawater in the permeable zone, leading to the generation of variable chemical environments and microbial communities in the subseafloor habitats. In addition, the deepest section of sediments under high-temperature conditions (∼90°C) harbored the sequences of an uncultivated archaeal lineage of hot water crenarchaeotic group IV that may be associated with the high-temperature hydrothermal fluid flow. These results indicate that the subseafloor microbial community compositions and functions at the marginal site of the hydrothermal field are highly affected by the complex fluid flow structure, such as recharging seawater and underlying hydrothermal fluids, coupled with the lithologic transition of sediments.

  9. Comment on 'Consequences of phase separation on the distribution of hydrothermal fluids at ASHES vent field, axial volcano, Juan de Fuca ridge' by Christopher G. Fox

    Science.gov (United States)

    Scholl, M. A.; Ingebritsen, S. E.; Essaid, H. I.

    1993-02-01

    Fox (1990), in order to explain observations during the Axial Seamount Hydrothermal Emissions Study (ASHES), proposed a conceptual model for a two-phase subsea hydrothermal system in which steam controlled flow patterns by blocking liquid flow. An attempt is made here to demonstrate with a very general model that relative permeability contrasts by themselves do not cause spatial isolation of phases in steam/liquid water systems and that density segregation, independent of relative permeability effects, should not be ruled out as an explanation for the observations at the ASHES site. Fox replies that density segregation is probably not the only mechanism at work.

  10. Assessment of Human Exposure to Magnetic Field from Overhead High Voltage Transmission Lines in a City in South Western Nigeria

    Directory of Open Access Journals (Sweden)

    Ponnle Akinlolu

    2015-05-01

    Full Text Available The increase in electricity consumption, population, and land use has now forced high voltage transmission lines (HVTLs either to pass or be installed around or through urban cities. This increases the level of human exposure to electromagnetic field radiation as this field produced around the HVTLs extends outwards covering some distance. This may cause a number of health hazards. It is even dangerous to a human who touch any metallic object in proximity of the HVTL, as it may have an appreciable voltage induced on it due to inductive, capacitive or resistive interference from the line. This paper evaluates the magnetic field produced at mid-span by a 132kV, and a 330kV, 50Hz adjacent HVTLs with horizontal and vertical configuration in Akure, a city in South Western Nigeria using analytical method from electromagnetic field theory. This is then compared to the recommended standard limit of public exposure to magnetic field. The results of the computation showed that currently, the general public exposure to the magnetic field along the HVTLs is safe. However, right of way (ROW along the power lines is being violated as buildings and work places exist within the ROW.

  11. Simulation of Mexico City plumes during the MIRAGE-Mex field campaign using the WRF-Chem model

    Directory of Open Access Journals (Sweden)

    X. Tie

    2009-07-01

    Full Text Available The quantification of tropospheric O3 production in the downwind of the Mexico City plume is a major objective of the MIRAGE-Mex field campaign. We used a regional chemistry-transport model (WRF-Chem to predict the distribution of O3 and its precursors in Mexico City and the surrounding region during March 2006, and compared the model with in-situ aircraft measurements of O3, CO, VOCs, NOx, and NOy concentrations. The comparison shows that the model is capable of capturing the timing and location of the measured city plumes, and the calculated variability along the flights is generally consistent with the measured results, showing a rapid increase in O3 and its precursors when city plumes are detected. However, there are some notable differences between the calculated and measured values, suggesting that, during transport from the surface of the city to the outflow plume, ozone mixing ratios are underestimated by about 0–25% during different flights. The calculated O3-NOx, O3-CO, and O3-NOz correlations generally agree with the measured values, and the analyses of these correlations suggest that photochemical O3 production continues in the plume downwind of the city (aged plume, adding to the O3 already produced in the city and exported with the plume. The model is also used to quantify the contributions to OH reactivity from various compounds in the aged plume. This analysis suggests that oxygenated organics (OVOCs have the highest OH reactivity and play important roles for the O3 production in the aging plume. Furthermore, O3 production per NOx molecule consumed (O3 production efficiency is more efficient in the aged plume than in the young plume near the city. The major contributor to the high O3 production efficiency in the aged plume is the

  12. Simulation of Mexico City plumes during the MIRAGE-Mex field campaign using the WRF-Chem model

    Directory of Open Access Journals (Sweden)

    X. Tie

    2009-04-01

    Full Text Available The quantification of tropospheric O3 production in the Mexico City outflow is a major objective of the MIRAGE-Mex field campaign. We used a regional chemistry-transport model (WRF-Chem to predict the distribution of O3 and its precursors in Mexico City and the surrounding region during March 2006, and compared with in-situ aircraft measurement of O3, CO, VOCs, NOx, and NOy concentrations. The comparison shows that the model is capable of capturing the timing/location of the measured city plumes, and the calculated variability along the flights is generally consistent with the measured results, showing a rapid enhancement of O3 and its precursors when city plumes are detected. However, there are some notable differences between the calculated and measured values, suggesting that, during transport from the surface of the city to the outflow plume, pollution levels are underestimated by about 0–25% during different flights. The calculated O3-NOx, O3-CO, and O3-NOz correlations generally agree with the measured values, and the analysis of these correlations suggest that photochemical O3 production continues in the plume downwind of the city (aged plume, adding to the O3 already produced in the city and exported with the plume. The model is also used to quantify the contributions to OH reactivity from various compounds in the aged plume. This analysis suggests that oxygenated organics (OVOCs have the highest OH reactivity and play important roles for the O3 production in the aging plume. Furthermore, O3 production per NOx molecule consumed (O3 production efficiency is more efficient in the aged plume than in the young plume near the city. The major contributor to the high O3 production efficiency in the aged plume is the reaction RO2+NO. By

  13. Boundary-Layer Structure Upwind and Downwind of Oklahoma City during the Joint Urban 2003 Field Study

    Energy Technology Data Exchange (ETDEWEB)

    De Wekker, Stephan; Berg, Larry K.; Allwine, K Jerry; Doran, J. C.; Shaw, William J.

    2004-08-25

    The Joint Urban 2003 field study in Oklahoma City in July 2003 provided a comprehensive data set that included measurements from sites upwind and downwind of Oklahoma City where sodars, radar wind profilers/RASSes, and radiosondes were deployed. Radiosonde measurements were taken during six daytime intensive observational periods (IOPs) and during four nighttime IOPs, while the sodars and radars operated almost continuously during the entire month of July. The upwind and downwind sites were located approximately 2 km south and 5 km north of downtown Oklahoma City, respectively. Boundary-layer heights and wind and temperature structure at both sites have been investigated and compared to determine effects of the urban area on mean boundary-layer structure. Initial results show that differences in boundary-layer structure between the upwind and downwind location are small, i.e., there is no detectable effect of downtown Oklahoma City on the mean boundary-layer structure 5 km downwind. These measurements are compared with a numerical model and simple analytical models such as those that predict the growth of an internal boundary layer after a roughness change, and an advective thermodynamic model used to determine mixing heights in an urban area.

  14. The Scaling of Geographic Space from the Perspective of City and Field Blocks and Using Volunteered Geographic Information

    CERN Document Server

    Jiang, Bin

    2012-01-01

    The scaling of geographic space refers to the fact that for a large geographic area its small constituents or units are much more common than the large ones. This paper develops a novel perspective to the scaling of geographic space using large street networks involving both cities and countryside. Given a street network of an entire country, we decompose the street network into individual blocks, each of which forms a minimum ring or cycle such as city blocks and field blocks. The block sizes demonstrate the scaling property, i.e., there are far more small blocks than large ones. Interestingly, and to our surprise, we find that the mean of all the block sizes can easily separate between small and large blocks- a high percentage (e.g., 90%) of smaller ones and a low percentage (e.g., 10%) of larger ones. Based on this regularity, termed as the head/tail division rule, we propose a natural way of delineating city boundaries by grouping the smaller blocks. The extracted city sizes for the three largest European...

  15. Hydrothermal organic synthesis experiments

    Science.gov (United States)

    Shock, Everett L.

    1992-01-01

    Ways in which heat is useful in organic synthesis experiments are described, and experiments on the hydrothermal destruction and synthesis of organic compounds are discussed. It is pointed out that, if heat can overcome kinetic barriers to the formation of metastable states from reduced or oxidized starting materials, abiotic synthesis under hydrothermal conditions is a distinct possibility. However, carefully controlled experiments which replicate the descriptive variables of natural hydrothermal systems have not yet been conducted with the aim of testing the hypothesis of hydrothermal organic systems.

  16. Fracture hydraulic conductivity in the Mexico City clayey aquitard: Field piezometer rising-head tests

    Science.gov (United States)

    Vargas, Carlos; Ortega-Guerrero, Adrián

    A regional lacustrine aquitard covers the main aquifer of the metropolitan area of Mexico City. The aquitard's hydraulic conductivity (K') is fundamental for evaluating the natural protection of the aquifer against a variety of contaminants present on the surface and its hydraulic response. This study analyzes the distribution and variation of K' in the plains of Chalco, Texcoco and Mexico City (three of the six former lakes that existed in the Basin of Mexico), on the basis of 225 field-permeability tests, in nests of existing piezometers located at depths of 2-85 m. Tests were interpreted using the Hvorslev method and some by the Bouwer-Rice method. Results indicate that the distribution of K' fits log-Gaussian regression models. Dominant frequencies for K' in the Chalco and Texcoco plains range between 1E-09 and 1E-08 m/s, with similar population means of 1.19E-09 and 1.7E-09 m/s, respectively, which are one to two orders of magnitude higher than the matrix conductivity. In the Mexico City Plain the population mean is near by one order of magnitude lower; K'=2.6E-10 m/s. The contrast between the measured K' and that of the matrix is attributed to the presence of fractures in the upper 25-40 m, which is consistent with the findings of previous studies on solute migration in the aquitard. Un imperméable régional d'origine lacustre recouvre le principal aquifère de la zone urbaine de la ville de Mexico. La conductivité hydraulique K' de cet imperméable est fondamentale pour évaluer la protection naturelle de l'aquifère, contre les différents contaminants présents en surface, et sa réponse hydraulique. Cette étude analyse et les variations de K' dans les plaines de Chalco, Texcoco et Mexico (trois des six anciens lacs qui existaient dans le Bassin de Mexico), sur la base de 225 essais de perméabilité sur le terrain, réalisés en grappes dans des piézomètres existants entre 2 et 85 m de profondeur. Les essais ont été interprétés avec la m

  17. Treated wastewater and Nitrate transport beneath irrigated fields near Dodge city, Kansas

    Science.gov (United States)

    Sophocleous, M.; Townsend, M.A.; Vocasek, F.; Ma, L.; Ashok, K.C.

    2010-01-01

    Use of secondary-treated municipal wastewater for crop irrigation south of Dodge City, Kansas, where the soils are mainly of silty clay loam texture, has raised a concern that it has resulted in high nitratenitrogen concentrations (10-50 mg/kg) in the soil and deeper vadose zone, and also in the underlying deep (20-45 m) ground water. The goal of this field-monitoring project was to assess how and under what circumstances nitrogen (N) nutrients under cultivated corn that is irrigated with this treated wastewater can reach the deep ground water of the underlying High Plains aquifer, and what can realistically be done to minimize this problem. We collected 15.2-m-deep cores for physical and chemical properties characterization; installed neutron moisture-probe access tubes and suction lysimeters for periodic measurements; sampled area monitoring, irrigation, and domestic wells; performed dye-tracer experiments to examine soil preferential-flow processes through macropores; and obtained climatic, crop, irrigation, and N-application rate records. These data and additional information were used in the comprehensive Root Zone Water Quality Model (RZWQM2) to identify key parameters and processes that influence N losses in the study area. We demonstrated that nitrate-N transport processes result in significant accumulations of N in the thick vadose zone. We also showed that nitrate-N in the underlying ground water is increasing with time and that the source of the nitrate is from the wastewater applications. RZWQM2 simulations indicated that macropore flow is generated particularly during heavy rainfall events, but during our 2005-06 simulations the total macropore flow was only about 3% of precipitation for one of two investigated sites, whereas it was more than 13% for the other site. Our calibrated model for the two wastewater-irrigated study sites indicated that reducing current levels of corn N fertilization by half or more to the level of 170 kg/ha substantially

  18. Hydrothermal Conditions and the Origin of Cellular Life.

    Science.gov (United States)

    Deamer, David W; Georgiou, Christos D

    2015-12-01

    The conditions and properties of hydrothermal vents and hydrothermal fields are compared in terms of their ability to support processes related to the origin of life. The two sites can be considered as alternative hypotheses, and from this comparison we propose a series of experimental tests to distinguish between them, focusing on those that involve concentration of solutes, self-assembly of membranous compartments, and synthesis of polymers. Key Word: Hydrothermal systems.

  19. High-pressure hydrogen respiration in hydrothermal vent samples from the deep biosphere

    Science.gov (United States)

    Morgan-Smith, D.; Schrenk, M. O.

    2013-12-01

    Cultivation of organisms from the deep biosphere has met with many challenges, chief among them the ability to replicate this extreme environment in a laboratory setting. The maintenance of in situ pressure levels, carbon sources, and gas concentrations are important, intertwined factors which may all affect the growth of subsurface microorganisms. Hydrogen in particular is of great importance in hydrothermal systems, but in situ hydrogen concentrations are largely disregarded in attempts to culture from these sites. Using modified Hungate-type culture tubes (Bowles et al. 2011) within pressure-retaining vessels, which allow for the dissolution of higher concentrations of gas than is possible with other culturing methods, we have incubated hydrothermal chimney and hydrothermally-altered rock samples from the Lost City and Mid-Cayman Rise hydrothermal vent fields. Hydrogen concentrations up to 15 mmol/kg have been reported from Lost City (Kelley et al. 2005), but data are not yet available from the recently-discovered Mid-Cayman site, and the elevated concentration of 30 mmol/kg is being used in all incubations. We are using a variety of media types to enrich for various metabolic pathways including iron and sulfur reduction under anoxic or microaerophilic conditions. Incubations are being carried out at atmospheric (0.1 MPa), in situ (9, 23, or 50 MPa, depending on site), and elevated (50 MPa) pressure levels. Microbial cell concentrations, taxonomic diversity, and metabolic activities are being monitored during the course of these experiments. These experiments will provide insight into the relationships between microbial activities, pressure, and gas concentrations typical of deep biosphere environments. Results will inform further culturing studies from both fresh and archived samples. References cited: Bowles, M.W., Samarkin, V.A., Joye, S.B. 2011. Improved measurement of microbial activity in deep-sea sediments at in situ pressure and methane concentration

  20. The Timber Mountain magmato-thermal event: An intense widespread culmination of magmatic and hydrothermal activity at the southwestern Nevada volcanic field

    Energy Technology Data Exchange (ETDEWEB)

    Jackson, M.R. Jr.

    1988-05-01

    Eruption of the Rainier Mesa and Ammonia Tanks Members Timber Mountain Tuff at about 11.5 and 11.3 Ma, respectively, resulted in formation of the timber Mountain (TM) caldera; new K-Ar ages show that volcanism within and around the TM caldera continued for about 1 m.y. after collapse. Some TM age magmatic activity took place west and southeast of the TM caldera in the Beatty -- Bullfrog Hills and Shoshone Mountain areas, suggesting that volcanic activity at the TM caldera was an intense expression of an areally extensive magmatic system active from about 11.5 to 10Ma. Epithermal Au-Ag, Hg and fluorite mineralization and hydrothermal alteration are found in both within and surrounding the Timber Mountain -- Oasis Valley caldera complex. New K-Ar ages date this hydrothermal activity between about 13 and 10 Ma, largely between about 11.5 and 10 Ma, suggesting a genetic relation of hydrothermal activity to the TM magmatic system.

  1. Geophysical imaging of shallow degassing in a Yellowstone hydrothermal system

    Science.gov (United States)

    Pasquet, S.; Holbrook, W. S.; Carr, B. J.; Sims, K. W. W.

    2016-12-01

    The Yellowstone Plateau Volcanic Field, which hosts over 10,000 thermal features, is the world's largest active continental hydrothermal system, yet very little is known about the shallow "plumbing" system connecting hydrothermal reservoirs to surface features. Here we present the results of geophysical investigations of shallow hydrothermal degassing in Yellowstone. We measured electrical resistivity, compressional-wave velocity from refraction data, and shear wave velocity from surface-wave analysis to image shallow hydrothermal degassing to depths of 15-30 m. We find that resistivity helps identify fluid pathways and that Poisson's ratio shows good sensitivity to saturation variations, highlighting gas-saturated areas and the local water table. Porosity and saturation predicted from rock physics modeling provide critical insight to estimate the fluid phase separation depth and understand the structure of hydrothermal systems. Finally, our results show that Poisson's ratio can effectively discriminate gas- from water-saturated zones in hydrothermal systems.

  2. Behavioural study of two hydrothermal crustacean decapods: Mirocaris fortunata and Segonzacia mesatlantica, from the Lucky Strike vent field (Mid-Atlantic Ridge)

    Science.gov (United States)

    Matabos, M.; Cuvelier, D.; Brouard, J.; Shillito, B.; Ravaux, J.; Zbinden, M.; Barthelemy, D.; Sarradin, P. M.; Sarrazin, J.

    2015-11-01

    Identifying the factors driving community dynamics in hydrothermal vent communities, and in particular biological interactions, is challenged by our ability to make direct observations and the difficulty to conduct experiments in those remote ecosystems. As a result, we have very limited knowledge on species' behaviour and interactions in these communities and how they in turn influence community dynamics. Interactions such as competition or predation significantly affect community structure in vent communities, and video time-series have successfully been used to gain insights in biological interactions and species behaviour, including responses to short-term changes in temperature or feeding strategies. In this study, we combined in situ and ex situ approaches to characterise the behaviour and interactions among two key species encountered along the Mid-Atlantic Ridge (MAR): the shrimp Mirocaris fortunata and the crab Segonzacia mesatlantica. In situ, species small-scale distribution, interactions and behaviour were studied using the TEMPO observatory module deployed on the seafloor at the base of the active Eiffel Tower edifice in the Lucky Strike vent field as part of the EMSO-Açores MoMAR observatory. TEMPO sampled 2 min of video four times a day from July 2011 to April 2012. One week of observations per month was used for 'long-term' variations, and a full video data set was analysed for January 2012. In addition, observations of crab and shrimp individuals maintained for the first time under controlled conditions in atmospheric pressure (classic tank) and pressurised (AbyssBox) aquaria allowed better characterisation and description of the different types of behaviour and interactions observed in nature. While the identified in situ spatial distribution pattern was stable over the nine months, both species displayed a significant preference for mussel bed and anhydrite substrata, and preferentially occupied the area located directly in the fluid flow axis

  3. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Rudolf, Andreas

    2011-01-01

    This article reviews the hydrothermal liquefaction of biomass with the aim of describing the current status of the technology. Hydrothermal liquefaction is a medium-temperature, high-pressure thermochemical process, which produces a liquid product, often called bio-oil or bi-crude. During...... the hydrothermal liquefaction process, the macromolecules of the biomass are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive and can recombine into larger ones. During this process, a substantial part of the oxygen in the biomass is removed...... by dehydration or decarboxylation. The chemical properties of bio-oil are highly dependent of the biomass substrate composition. Biomass constitutes of various components such as protein; carbohydrates, lignin and fat, and each of them produce distinct spectra of compounds during hydrothermal liquefaction...

  4. Vertical profiles of ozone, VOCs and meteorological parameters in within and outside of Mexico City during the MILAGRO field Campaign

    Science.gov (United States)

    Marquez, C.; Greenberg, J.; Bueno, E.; Bernabe, R.; Aguilar, J.; Blanco, S.; Wöhrnschimmel, H.; Guenther, A.; Cardenas, B.; Turnipseed, A.

    2007-05-01

    High ozone levels with maxima over 250 ppb have been an air quality problem in Mexico City for more than a decade. This ozone is produced in the daytime by photochemical reactions, initiated by its precursors, nitrogen oxides (NOx) and volatile organic compounds (VOCs) in the presence of solar ultraviolet radiation. The objective of this work is to contribute to the understanding of the evolution of these air pollutants at different heights of the boundary layer by means of vertical profile measurements. Ozone, VOCs and meteorological vertical profiles were determined in Northern Mexico City (T0 site) using a tethered balloon for 10 days during the MILAGRO field Campaign 2006, between 4 AM and 4 PM. Measurements were done up to 1000 meter above ground (ozone and meteorological parameters) and up to 200 m above ground for VOCs. VOCs samples were collected during 4 minutes in canisters and analyzed with GC-FID to identify 13 species (ethane, propane, propylene, butane, acetylene, pentane, hexane, heptane, benzene, octane, toluene, nonane and o-xylene). For 4 of the days, VOC integrated samples were also taken using personal pumps and absorbent cartridges at height between 200 and 1000 m. Sample cartridges were analyzed by GC-MS for volatile organic compounds (n-butane, i-pentane, n- pentane, benzene, toluene, ethyl-benzene, o-xylene, m&p-xylene, 1,2,4-tri-methyl-benzene and C3-benzenes). Ozone vertical profiles, frequently presented high concentrations above 400 m in the early morning. During the daytime, more homogeneous profiles indicate an increased vertical mixing. VOCs profiles show similar concentrations for all heights at dawn. In the morning, highest concentrations were determined at a height of about 100 meter, whereas at noon and in the afternoon concentrations decreased with height. Comparing VOC concentrations during the course of a day, highest values are measured in the morning. The highest VOC concentrations were propane, butane, and toluene. For some

  5. Heat and mass flux estimation of modern seafloor hydrothermal activity

    Institute of Scientific and Technical Information of China (English)

    ZHAI Shikui; WANG Xingtao; YU Zenghui

    2006-01-01

    Research on heat and mass flux yielded by modern seafloor hydrothermal activity is very important, because it is involved not only in the base of ocean environment research, but also in the historical evolution of seawater properties. Currently, estimating heat flux is based on the observation data of hydrothermal smokers, low-temperature diffusive flow and mid-ocean ridge mainly. But there are some faults, for example, there is lack of a concurrent conductive item in estimating the heat flux by smokers and the error between the half-space cooling model and the observation data is too large. So, three kinds of methods are applied to re-estimating the heat flux of hydrothermal activity resepectively, corresponding estimation is 97.359 GW by hydrothermal smoker and diffusive flow, 84.895 GW by hydrothermal plume, and 4.11 TW by exponential attenuation method put forward by this paper. Research on mass flux estimation is relatively rare, the main reason for this is insufficient field observation data. Mass fluxes of different elements are calculated using hydrothermal vent fluid data from the TAG hydrothermal area on the Mid-Atlantic Ridge for the first time. Difference of estimations by different methods reflects the researching extent of hydrothermal activity, and systematically in-situ observation will help to estimate the contribution of hydrothermal activity to ocean chemical environment, ocean circulation and global climate precisely.

  6. Theoretical constraints of physical and chemical properties of hydrothermal fluids on variations in chemolithotrophic microbial communities in seafloor hydrothermal systems

    Science.gov (United States)

    Nakamura, Kentaro; Takai, Ken

    2014-12-01

    In the past few decades, chemosynthetic ecosystems at deep-sea hydrothermal vents have received attention as plausible analogues to the early ecosystems of Earth, as well as to extraterrestrial ecosystems. These ecosystems are sustained by chemical energy obtained from inorganic redox substances (e.g., H2S, CO2, H2, CH4, and O2) in hydrothermal fluids and ambient seawater. The chemical and isotope compositions of the hydrothermal fluid are, in turn, controlled by subseafloor physical and chemical processes, including fluid-rock interactions, phase separation and partitioning of fluids, and precipitation of minerals. We hypothesized that specific physicochemical principles describe the linkages among the living ecosystems, hydrothermal fluids, and geological background in deep-sea hydrothermal systems. We estimated the metabolic energy potentially available for productivity by chemolithotrophic microorganisms at various hydrothermal vent fields. We used a geochemical model based on hydrothermal fluid chemistry data compiled from 89 globally distributed hydrothermal vent sites. The model estimates were compared to the observed variability in extant microbial communities in seafloor hydrothermal environments. Our calculations clearly show that representative chemolithotrophic metabolisms (e.g., thiotrophic, hydrogenotrophic, and methanotrophic) respond differently to geological and geochemical variations in the hydrothermal systems. Nearly all of the deep-sea hydrothermal systems provide abundant energy for organisms with aerobic thiotrophic metabolisms; observed variations in the H2S concentrations among the hydrothermal fluids had little effect on the energetics of thiotrophic metabolism. Thus, these organisms form the base of the chemosynthetic microbial community in global deep-sea hydrothermal environments. In contrast, variations in H2 concentrations in hydrothermal fluids significantly impact organisms with aerobic and anaerobic hydrogenotrophic metabolisms

  7. Sulfur isotopic composition of modern seafloor hydrothermal sediment and its geological significance

    Institute of Scientific and Technical Information of China (English)

    曾志刚; 李军; 蒋富清; 秦蕴珊; 翟世奎

    2002-01-01

    A total of 1 264 sulfur isotopic values for modem seafloor hydrothermel sediments from different hydrothermal fidds have been collected. On this basis, combining our sulfur isotpic data for surface hydrothermal sediments from the Jade hydrohtermal field in the Okinawa Trough and the TAG hydrothermal field in the Mid-Atlantic Ridge, respectively, and comparing the sulfur isotopic compositions and analyzing their sources of sulfur in seafloor hydrothermal sediments from different geologic-tectonic setting, the results show that: ( 1 ) sulfur isotopic values of sulfides and sulfates in modern seafloor hydrothermal sediments are concentrated in a narrow range, δ34S values of sulfides vary from l × 10-3 to 9 × 10- 3, with a mean of 4.5 × 10- 3 ( n = 1 042), δ34S values of sulfates vary from 19 × 10- 3 to 24× 10-3, with a mean of 21.3× 10-3 (n =217); (2) comparing the sulfur isotopic compositions of hydrothermal sediments from the sediment-hosted hydrothermal fields, the range of sulfur isotopic values for hydrothermal sediments from the sediment-free hydrothermal fields is narrow relatively; (3) the differences of sulfur isotopic compositions in sulfides from different hydrothermal fields show the differences in the sources of sulfur. The sulfur of hydrothermal sulfides in the sediment-free mid-ocean ridges is mainly from mid-ocean ridge basalt, and partially from the reduced seawater sulfate, and it is the result of partially reduced seawater sulfate mixed with basaltic sulfur. In the sediment-hosted nid-ocean ridges and the back-arc basins, the volcanics, the sediments and the organic matters also can offer their sulfur for forming hydrothermal sulfides; (4) the variations of sulfur isotopic compositions and the different sources of sulfur for hydrothermal sediments may be attributed to the various physical-chemical characteristics of hydrothermal fluids, the magmatic evolution and the different geologic-tectonic settings of seafloor hydrothermal systems.

  8. Catalytic Hydrothermal Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Douglas C.

    2015-05-31

    The term “hydrothermal” used here refers to the processing of biomass in water slurries at elevated temperature and pressure to facilitate the chemical conversion of the organic structures in biomass into useful fuels. The process is meant to provide a means for treating wet biomass materials without drying and to access ionic reaction conditions by maintaining a liquid water processing medium. Typical hydrothermal processing conditions are 523-647K of temperature and operating pressures from 4-22 MPa of pressure. The temperature is sufficient to initiate pyrolytic mechanisms in the biopolymers while the pressure is sufficient to maintain a liquid water processing phase. Hydrothermal gasification is accomplished at the upper end of the process temperature range. It can be considered an extension of the hydrothermal liquefaction mechanisms that begin at the lowest hydrothermal conditions with subsequent decomposition of biopolymer fragments formed in liquefaction to smaller molecules and eventually to gas. Typically, hydrothermal gasification requires an active catalyst to accomplish reasonable rates of gas formation from biomass.

  9. Hydrothermal pretreatment of coal

    Energy Technology Data Exchange (ETDEWEB)

    Ross, D.S.

    1989-12-21

    We have examined changes in Argonne Premium samples of Wyodak coal following 30 min treatment in liquid water at autogenous pressures at 150{degrees}, 250{degrees}, and 350{degrees}C. In most runs the coal was initially dried at 60{degrees}C/1 torr/20 hr. The changes were monitored by pyrolysis field ionization mass spectrometry (py-FIMS) operating at 2.5{degrees}C/min from ambient to 500{degrees}C. We recorded the volatility patterns of the coal tars evolved over that temperature range, and in all cases the tar yields were 25%--30% of the starting coal on mass basis. There was essentially no change after the 150{degrees}C treatment. Small increases in volatility were seen following the 250{degrees}C treatment, but major effects were seen in the 350{degrees} work. The tar quantity remained unchanged; however, the volatility increased so the temperature of half volatility for the as-received coal of 400{degrees}C was reduced to 340{degrees}C. Control runs with no water showed some thermal effect, but the net effect from the presence of liquid water was clearly evident. The composition was unchanged after the 150{degrees} and 250{degrees}C treatments, but the 350{degrees} treatment brought about a 30% loss of oxygen. The change corresponded to loss of the elements of water, although loss of OH'' seemed to fit the analysis data somewhat better. The water loss takes place both in the presence and in the absence of added water, but it is noteworthy that the loss in the hydrothermal runs occurs at p(H{sub 2}O) = 160 atm. We conclude that the process must involve the dehydration solely of chemically bound elements of water, the dehydration of catechol is a specific, likely candidate.

  10. Field Measurements of Residential Energy Consumption and Indoor Thermal Environment in Six Chinese Cities

    Directory of Open Access Journals (Sweden)

    Jie Zhou

    2012-06-01

    Full Text Available The purpose of this study was to reveal the energy use and indoor environment characteristics of twelve households located in six cities in China, including daily use of gas and electricity, temperature and humidity throughout a year. The energy uses for district heating and hot water were not included. The investigated houses were separated into two groups, namely Group 1 with domestic heating, and Group 2 with district heating. The analysis showed that the energy use of Lighting and Audio visual & information for each house is not very different during the four seasons. Annual energy use varied from 13.3 to 32.4 GJ in Group 1. The energy use of House 05 was 32.4 GJ/year, which is the highest in Group 1, the space heating reached 18.5 GJ/year, accounting for 57% of the total. Energy use of House 01 increased in winter and summer, which is attributed to the use of heating in winter and cooling in summer, respectively. Annual energy use varied from 2.9 to 17.0 GJ in Group 2. Almost no change of energy use was found for the houses in Group 2 during the four seasons, but a big difference of average indoor temperature was found in the coldest days between the houses in Group 1 (around 10 °C and Group 2 (around 20 °C, while the difference was small in summer.

  11. Forests, fields, and the edge of sustainability at the ancient Maya city of Tikal.

    Science.gov (United States)

    Lentz, David L; Dunning, Nicholas P; Scarborough, Vernon L; Magee, Kevin S; Thompson, Kim M; Weaver, Eric; Carr, Christopher; Terry, Richard E; Islebe, Gerald; Tankersley, Kenneth B; Grazioso Sierra, Liwy; Jones, John G; Buttles, Palma; Valdez, Fred; Ramos Hernandez, Carmen E

    2014-12-30

    Tikal has long been viewed as one of the leading polities of the ancient Maya realm, yet how the city was able to maintain its substantial population in the midst of a tropical forest environment has been a topic of unresolved debate among researchers for decades. We present ecological, paleoethnobotanical, hydraulic, remote sensing, edaphic, and isotopic evidence that reveals how the Late Classic Maya at Tikal practiced intensive forms of agriculture (including irrigation, terrace construction, arboriculture, household gardens, and short fallow swidden) coupled with carefully controlled agroforestry and a complex system of water retention and redistribution. Empirical evidence is presented to demonstrate that this assiduously managed anthropogenic ecosystem of the Classic period Maya was a landscape optimized in a way that provided sustenance to a relatively large population in a preindustrial, low-density urban community. This landscape productivity optimization, however, came with a heavy cost of reduced environmental resiliency and a complete reliance on consistent annual rainfall. Recent speleothem data collected from regional caves showed that persistent episodes of unusually low rainfall were prevalent in the mid-9th century A.D., a time period that coincides strikingly with the abandonment of Tikal and the erection of its last dated monument in A.D. 869. The intensified resource management strategy used at Tikal-already operating at the landscape's carrying capacity-ceased to provide adequate food, fuel, and drinking water for the Late Classic populace in the face of extended periods of drought. As a result, social disorder and abandonment ensued.

  12. Characteristics of Hydrothermal Mineralization in Ultraslow Spreading Ridges

    Science.gov (United States)

    Zhou, H.; Yang, Q.; Ji, F.; Dick, H. J.

    2014-12-01

    Hydrothermal activity is a major component of the processes that shape the composition and structure of the ocean crust, providing a major pathway for the exchange of heat and elements between the Earth's crust and oceans, and a locus for intense biological activity on the seafloor and underlying crust. In other hand, the structure and composition of hydrothermal systems are the result of complex interactions between heat sources, fluids, wall rocks, tectonic controls and even biological processes. Ultraslow spreading ridges, including the Southwest Indian Ridge, the Gakkel Ridge, are most remarkable end member in plate-boundary structures (Dick et al., 2003), featured with extensive tectonic amagmatic spreading and frequent exposure of peridotite and gabbro. With intensive surveys in last decades, it is suggested that ultraslow ridges are several times more effective than faster-spreading ridges in sustaining hydrothermal activities. This increased efficiency could attributed to deep mining of heat and even exothermic serpentinisation (Baker et al., 2004). Distinct from in faster spreading ridges, one characteristics of hydrothermal mineralization on seafloor in ultraslow spreading ridges, including the active Dragon Flag hydrothermal field at 49.6 degree of the Southwest Indian Ridge, is abundant and pervasive distribution of lower temperature precipitated minerals ( such as Fe-silica or silica, Mn (Fe) oxides, sepiolite, pyrite, marcasite etc. ) in hydrothermal fields. Structures formed by lower temperature activities in active and dead hydrothermal fields are also obviously. High temperature precipitated minerals such as chalcopyrite etc. are rare or very limited in hydrothermal chimneys. Distribution of diverse low temperature hydrothermal activities is consistence with the deep heating mechanisms and hydrothermal circulations in the complex background of ultraslow spreading tectonics. Meanwhile, deeper and larger mineralization at certain locations along the

  13. The Lassen hydrothermal system

    Science.gov (United States)

    Ingebritsen, Steven E.; Bergfeld, Deborah; Clor, Laura; Evans, William C.

    2016-01-01

    The active Lassen hydrothermal system includes a central vapor-dominated zone or zones beneath the Lassen highlands underlain by ~240 °C high-chloride waters that discharge at lower elevations. It is the best-exposed and largest hydrothermal system in the Cascade Range, discharging 41 ± 10 kg/s of steam (~115 MW) and 23 ± 2 kg/s of high-chloride waters (~27 MW). The Lassen system accounts for a full 1/3 of the total high-temperature hydrothermal heat discharge in the U.S. Cascades (140/400 MW). Hydrothermal heat discharge of ~140 MW can be supported by crystallization and cooling of silicic magma at a rate of ~2400 km3/Ma, and the ongoing rates of heat and magmatic CO2 discharge are broadly consistent with a petrologic model for basalt-driven magmatic evolution. The clustering of observed seismicity at ~4–5 km depth may define zones of thermal cracking where the hydrothermal system mines heat from near-plastic rock. If so, the combined areal extent of the primary heat-transfer zones is ~5 km2, the average conductive heat flux over that area is >25 W/m2, and the conductive-boundary length system or owe to various geologic events such as the eruption of Lassen Peak at 27 ka, deglaciation beginning ~18 ka, the eruptions of Chaos Crags at 1.1 ka, or the minor 1914–1917 eruption at the summit of Lassen Peak. However, there is a rich record of intermittent hydrothermal measurement over the past several decades and more-frequent measurement 2009–present. These data reveal sensitivity to climate and weather conditions, seasonal variability that owes to interaction with the shallow hydrologic system, and a transient 1.5- to twofold increase in high-chloride discharge in response to an earthquake swarm in mid-November 2014.

  14. The history of the airport; from grass fields to giant cities

    NARCIS (Netherlands)

    Peterse, H.

    2011-01-01

    In the early days of aviation airports where nothing more than a simple grass field from which airplanes could take off. These days there are airports that are enormous in size, and fulfil many more functions than simply allowing aircraft to take-off and land. The airport has shown a remarkable revo

  15. New records of caridean shrimp (Crustacea: Decapoda) from hydrothermally influenced fields off Futuna Island, Southwest Pacific, with description of a new species assigned to the genus Alvinocaridinides Komai & Chan, 2010 (Alvinocarididae).

    Science.gov (United States)

    Komai, Tomoyuki; Menot, Lenaick; Segonzac, Michel

    2016-01-01

    Five species of caridean shrimp, including four Alvinocarididae Christoffersen, 1986 and one thorid species of the genus Lebbeus White, 1847, are reported from the recently discovered hydrothermal vent field off Futuna Island in the Southwest Pacific (depths 1418-1478 m): Alvinocaridinides semidentatus n. sp., Alvinocaris komaii Zelnio & Hourdez, 2009, Nautilocaris saintlaurentae Komai & Segonzac, 2004, Rimicaris variabilis (Komai & Tsuchida, 2015), and Lebbeus wera Ahyong, 2009. The new species, provisionally assigned to Alvinocaridinides Komai & Chan, 2010, is readily distinguished from the type species of the genus, A. formosa Komai & Chan, 2010, by the characteristic armature of the rostrum and of the propodi of the third and fourth pereopods and the possession of ischial spines on the third and fourth pereopods. Identification of R. variabilis has been confirmed by morphology and sequence comparison of mitochondrial COI gene. The geographical range of L. wera is extended to the north from the Brothers Caldera in the Kermadec Ridge.

  16. Complexing and hydrothermal ore deposition

    CERN Document Server

    Helgeson, Harold C

    1964-01-01

    Complexing and Hydrothermal Ore Deposition provides a synthesis of fact, theory, and interpretative speculation on hydrothermal ore-forming solutions. This book summarizes information and theory of the internal chemistry of aqueous electrolyte solutions accumulated in previous years. The scope of the discussion is limited to those aspects of particular interest to the geologist working on the problem of hydrothermal ore genesis. Wherever feasible, fundamental principles are reviewed. Portions of this text are devoted to calculations of specific hydrothermal equilibriums in multicompone

  17. Hydrothermal conversion of biomass

    NARCIS (Netherlands)

    Knezevic, Dragan

    2009-01-01

    This thesis presents research of hydrothermal conversion of biomass (HTC). In this process, hot compressed water (subcritical water) is used as the reaction medium. Therefore this technique is suitable for conversion of wet biomass/ waste streams. By working at high pressures, the evaporation of wat

  18. 500 Cities: City Boundaries

    Data.gov (United States)

    U.S. Department of Health & Human Services — This city boundary shapefile was extracted from Esri Data and Maps for ArcGIS 2014 - U.S. Populated Place Areas. This shapefile can be joined to 500 Cities...

  19. Hydrothermal Reactivity of Amines

    Science.gov (United States)

    Robinson, K.; Shock, E.; Hartnett, H. E.; Williams, L. B.; Gould, I.

    2013-12-01

    The reactivity of aqueous amines depends on temperature, pH, and redox state [1], all of which are highly variable in hydrothermal systems. Temperature and pH affect the ratio of protonated to unprotonated amines (R-NH2 + H+ = R-NH3+), which act as nucleophiles and electrophiles, respectively. We hypothesize that this dual nature can explain the pH dependence of reaction rates, and predict that rates will approach a maximum at pH = pKa where the ratio of protonated and unprotonated amines approaches one and the two compounds are poised to react with one another. Higher temperatures in hydrothermal systems allow for more rapid reaction rates, readily reversible reactions, and unique carbon-nitrogen chemistry in which water acts as a reagent in addition to being the solvent. In this study, aqueous benzylamine was used as a model compound to explore the reaction mechanisms, kinetics, and equilibria of amines under hydrothermal conditions. Experiments were carried out in anoxic silica glass tubes at 250°C (Psat) using phosphate-buffered solutions to observe changes in reaction rates and product distributions as a function of pH. The rate of decomposition of benzylamine was much faster at pH 4 than at pH 9, consistent with the prediction that benzylamine acts as both nucleophile and an electrophile, and our estimate that the pKa of benzylamine is ~5 at 250°C and Psat. Accordingly, dibenzylamine is the primary product of the reaction of two benzylamine molecules, and this reaction is readily reversible under hydrothermal conditions. Extremely acidic or basic pH can be used to suppress dibenzylamine production, which also suppresses the formation of all other major products, including toluene, benzyl alcohol, dibenzylimine, and tribenzylamine. This suggests that dibenzylamine is the lone primary product that then itself reacts as a precursor to produce the above compounds. Analog experiments performed with ring-substituted benzylamine derivatives and chiral

  20. Biosignatures in chimney structures and sediment from the Loki's Castle low-temperature hydrothermal vent field at the Arctic Mid-Ocean Ridge.

    Science.gov (United States)

    Jaeschke, Andrea; Eickmann, Benjamin; Lang, Susan Q; Bernasconi, Stefano M; Strauss, Harald; Früh-Green, Gretchen L

    2014-05-01

    We investigated microbial life preserved in a hydrothermally inactive silica–barite chimney in comparison with an active barite chimney and sediment from the Loki's Castle low-temperature venting area at the Arctic Mid-Ocean Ridge (AMOR) using lipid biomarkers. Carbon and sulfur isotopes were used to constrain possible metabolic pathways. Multiple sulfur (dδ34S, Δ33S) isotopes on barite over a cross section of the extinct chimney range between 21.1 and 22.5 % in δ34S, and between 0.020 and 0.034 % in Δ33S, indicating direct precipitation from seawater. Biomarker distributions within two discrete zones of this silica–barite chimney indicate a considerable difference in abundance and diversity of microorganisms from the chimney exterior to the interior. Lipids in the active and inactive chimney barite and sediment were dominated by a range of 13C-depleted unsaturated and branched fatty acids with δ13C values between -39.7 and -26.7 %, indicating the presence of sulfur-oxidizing and sulfate-reducing bacteria. The majority of lipids (99.5 %) in the extinct chimney interior that experienced high temperatures were of archaeal origin. Unusual glycerol monoalkyl glycerol tetraethers (GMGT) with 0–4 rings were the dominant compounds suggesting the presence of mainly (hyper-) thermophilic archaea. Isoprenoid hydrocarbons with δ13C values as low as -46 % also indicated the presence of methanogens and possibly methanotrophs.

  1. Free-living bacterial communities associated with tubeworm (Ridgeia piscesae) aggregations in contrasting diffuse flow hydrothermal vent habitats at the Main Endeavour Field, Juan de Fuca Ridge.

    Science.gov (United States)

    Forget, Nathalie L; Kim Juniper, S

    2013-04-01

    We systematically studied free-living bacterial diversity within aggregations of the vestimentiferan tubeworm Ridgeia piscesae sampled from two contrasting flow regimes (High Flow and Low Flow) in the Endeavour Hydrothermal Vents Marine Protected Area (MPA) on the Juan de Fuca Ridge (Northeast Pacific). Eight samples of particulate detritus were recovered from paired tubeworm grabs from four vent sites. Most sequences (454 tag and Sanger methods) were affiliated to the Epsilonproteobacteria, and the sulfur-oxidizing genus Sulfurovum was dominant in all samples. Gammaproteobacteria were also detected, mainly in Low Flow sequence libraries, and were affiliated with known methanotrophs and decomposers. The cooccurrence of sulfur reducers from the Deltaproteobacteria and the Epsilonproteobacteria suggests internal sulfur cycling within these habitats. Other phyla detected included Bacteroidetes, Actinobacteria, Chloroflexi, Firmicutes, Planctomycetes, Verrucomicrobia, and Deinococcus-Thermus. Statistically significant relationships between sequence library composition and habitat type suggest a predictable pattern for High Flow and Low Flow environments. Most sequences significantly more represented in High Flow libraries were related to sulfur and hydrogen oxidizers, while mainly heterotrophic groups were more represented in Low Flow libraries. Differences in temperature, available energy for metabolism, and stability between High Flow and Low Flow habitats potentially explain their distinct bacterial communities.

  2. The Speciation of Particulate Iron and Carbon in the East Pacific Rise 15oS Near-field Hydrothermal Plume and Underlying Sediments

    Science.gov (United States)

    Toner, B. M.; Lam, P. J.; Nicholas, S. L.; Ohnemus, D.; Hoffman, C. L.; Fitzsimmons, J. N.; Sherrell, R. M.; German, C. R.

    2014-12-01

    Particulate iron and carbon speciation were measured for water column and sediment samples collected at the East Pacific Rise ridge axis (15oS; Station 18) and approximately 80 km down-current (Station 20) during the US GEOTRACES Eastern Pacific Zonal Transect cruise. Water column particles were collected by in situ filtration (0.2 micron, polycarbonate) from above, within, and below the hydrothermal plume. Water column samples were handled in an anaerobic chamber and stored frozen under inert gas shipboard, and protected from ambient oxygen during analysis. The flocculant, top-layer of the sediments was sampled shipboard under ambient conditions and stored frozen until analysis. Iron and carbon speciation were measured using X-ray microprobe (10.3.2) and scanning transmission X-ray microscopy (STXM) instruments at the Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA, USA. Iron (1s and 2p) and carbon (1s) X-ray absorption near edge structure (XANES) spectroscopy and imaging for particles revealed that: (1) in comparison to the above plume sample, organic carbon is abundant in particles within and below the plume, as well as in surface sediments; (2) iron sulfides are not detectable in any water column sample investigated so far; (3) the fraction of non-sulfide reduced iron is highest in the below plume samples; and (4) the below plume sample is rich in free-living microbial cells.

  3. Lost City and the Search For Life

    Science.gov (United States)

    Kelley, D. S.

    2014-12-01

    Since their discovery in 1979, high-temperature hot springs fueled by submarine volcanoes have served as models in the search for life elsewhere in the solar system. The early recognition of hot microbial biospheres associated with active volcanism along global mid-ocean ridges fundamentally shifted concepts of how planets and life co-evolve. These metal-rich, acidic systems were thought to represent the most extreme conditions on Earth, hosting novel life based on chemosynthesis. In 2000, this paradigm was profoundly impacted by the discovery of the Lost City hydrothermal field, characterized by conditions never before seen. Here, 60 m-tall limestone chimneys vent pH 10-11, metal-poor, 90°C fluids rich in hydrogen and abiotically-produced methane and formate. The fluid chemistry is driven, not by volcanic heat, but by fluid-rock reactions in underlying ultramafic basement at up to ~ 200°C. These peridotite-hosted biotopes differ significantly from volcanic-hosted vent systems in which carbon dioxide is a dominant volatile species. Instead, serpentinzation reactions yield high hydrogen and low molecular-weight hydrocarbons that result in energy-rich habitats with cell concentrations that reach 109cells/gram carbonate. The absence of volcanism, and on-going serpentinization reactions result in a remarkably stable system with venting active for >150,000 years. With the discovery of Lost City, it is clear that high temperature volcanic activity is not a prerequisite for life. Exothermic serpentinization reactions occur under a wide-range of temperatures and can result in up to a 40% volume of expansion, which may both close and open fractures. Hence, Lost City may serve as a model in the search for life on other planets and moons with rocky, undifferentiated terranes and overlying oceans. Within such systems, interior cooling, coupled with tidally-induced heating may induce hydrothermal flow, and perhaps life-sustaining environments in the absence of volcanism.

  4. Anhydrite precipitation in seafloor hydrothermal systems

    Science.gov (United States)

    Theissen-Krah, Sonja; Rüpke, Lars H.

    2016-04-01

    The composition and metal concentration of hydrothermal fluids venting at the seafloor is strongly temperature-dependent and fluids above 300°C are required to transport metals to the seafloor (Hannington et al. 2010). Ore-forming hydrothermal systems and high temperature vents in general are often associated with faults and fracture zones, i.e. zones of enhanced permeabilities that act as channels for the uprising hydrothermal fluid (Heinrich & Candela, 2014). Previous numerical models (Jupp and Schultz, 2000; Andersen et al. 2015) however have shown that high permeabilities tend to decrease fluid flow temperatures due to mixing with cold seawater and the resulting high fluid fluxes that lead to short residence times of the fluid near the heat source. A possible mechanism to reduce the permeability and thereby to focus high temperature fluid flow are mineral precipitation reactions that clog the pore space. Anhydrite for example precipitates from seawater if it is heated to temperatures above ~150°C or due to mixing of seawater with hydrothermal fluids that usually have high Calcium concentrations. We have implemented anhydrite reactions (precipitation and dissolution) in our finite element numerical models of hydrothermal circulation. The initial results show that the precipitation of anhydrite efficiently alters the permeability field, which affects the hydrothermal flow field as well as the resulting vent temperatures. C. Andersen et al. (2015), Fault geometry and permeability contrast control vent temperatures at the Logatchev 1 hydrothermal field, Mid-Atlantic Ridge, Geology, 43(1), 51-54. M. D. Hannington et al. (2010), Modern Sea-Floor Massive Sulfides and Base Metal Resources: Toward an Estimate of Global Sea-Floor Massive Sulfide Potential, in The Challenge of Finding New Mineral Resources: Global Metallogeny, Innovative Exploration, and New Discoveries, edited by R. J. Goldfarb, E. E. Marsh and T. Monecke, pp. 317-338, Society of Economic Geologists

  5. Modeling ozone plumes observed downwind of New York City over the North Atlantic Ocean during the ICARTT field campaign

    Directory of Open Access Journals (Sweden)

    S.-H. Lee

    2011-07-01

    Full Text Available Transport and chemical transformation of well-defined New York City (NYC urban plumes over the North Atlantic Ocean were studied using aircraft measurements collected on 20–21 July 2004 during the ICARTT (International Consortium for Atmospheric Research on Transport and Transformation field campaign and WRF-Chem (Weather Research and Forecasting-Chemistry model simulations. The strong NYC urban plumes were characterized by carbon monoxide (CO mixing ratios of 350–400 parts per billion by volume (ppbv and ozone (O3 levels of about 100 ppbv near New York City on 20 July in the WP-3D in-situ and DC-3 lidar aircraft measurements. On 21 July, the two aircraft captured strong urban plumes with about 350 ppbv CO and over 150 ppbv O3 (~160 ppbv maximum about 600 km downwind of NYC over the North Atlantic Ocean. The measured urban plumes extended vertically up to about 2 km near New York City, but shrank to 1–1.5 km over the stable marine boundary layer (MBL over the North Atlantic Ocean. The WRF-Chem model reproduced ozone formation processes, chemical characteristics, and meteorology of the measured urban plumes near New York City (20 July and in the far downwind region over the North Atlantic Ocean (21 July. The quasi-Lagrangian analysis of transport and chemical transformation of the simulated NYC urban plumes using WRF-Chem results showed that the pollutants can be efficiently transported in (isentropic layers in the lower atmosphere (<2–3 km over the North Atlantic Ocean while maintaining a dynamic vertical decoupling by cessation of turbulence in the stable MBL. The O3 mixing ratio in the NYC urban plumes remained at 80–90 ppbv during nocturnal transport over the stable MBL, then grew to over 100 ppbv by daytime oxidation of nitrogen oxides (NOx = NO + NO2 with mixing ratios on the order of 1 ppbv. Efficient transport of reactive nitrogen species (NOy, specifically nitric

  6. Modeling ozone plumes observed downwind of New York City over the North Atlantic Ocean during the ICARTT field campaign

    Directory of Open Access Journals (Sweden)

    S.-H. Lee

    2011-05-01

    Full Text Available Transport and chemical transformation of well-defined New York City (NYC urban plumes over the North Atlantic Ocean were studied using aircraft measurements collected on 20–21 July 2004 during the ICARTT (International Consortium for Atmospheric Research on Transport and Transformation field campaign and WRF-Chem (Weather Research and Forecasting-Chemistry model simulations. The strong NYC urban plumes were characterized by carbon monoxide (CO mixing ratios of 350–400 parts per billion by volume (ppbv and ozone (O3 levels of about 100 ppbv near New York City on 20 July in the WP-3D in-situ and DC-3 lidar aircraft measurements. On 21 July, the two aircraft captured strong urban plumes with about 350 ppbv CO and over 150 ppbv O3 (~160 ppbv maximum about 600 km downwind of NYC over the North Atlantic Ocean. The measured urban plumes extended vertically up to about 2 km near New York City, but shrank to 1–1.5 km over the stable marine boundary layer (MBL over the North Atlantic Ocean. The WRF-Chem model reproduced ozone formation processes, chemical characteristics, and meteorology of the measured urban plumes near New York City (20 July and in the far downwind region over the North Atlantic Ocean (21 July. The quasi-Lagrangian analysis of transport and chemical transformation of the simulated NYC urban plumes using WRF-Chem results showed that the pollutants can be efficiently transported in (isentropic layers in the lower atmosphere (<2–3 km over the North Atlantic Ocean while maintaining a dynamic vertical decoupling by cessation of turbulence in the stable MBL. The O3 mixing ratio in the NYC urban plumes remained at 80–90 ppbv during nocturnal transport over the stable MBL, then grew to over 100 ppbv by daytime oxidation of nitrogen oxides (NOx = NO + NO2 with mixing ratios on the order of 1 ppbv. Efficient transport of reactive nitrogen species (NOy, specifically nitric

  7. A Comparative Field Based Study of Katz and Barthel Indices in North Indian City of Dehradun

    Directory of Open Access Journals (Sweden)

    Megha Luthra

    2016-03-01

    Full Text Available Background: Elderly persons are one of the most vulnerable groups of society and have more chances of disease and disabilities (restriction or lack of ability to perform an activity in the manner or within the range considered normal for a human being. It reflects how well an individual is able to function in general areas of life. Magnitude of disability has become an important indicator in measuring disease burden along with morbidity and mortality rates. Katz and Barthel Indices have been largely used to assess disability in activities of daily living among elderly people.Aim & objectives: This community-based cross-sectional study was conducted among persons aged 60 years and above in urban field practice area of SGRRIM&HS, Dehradun, Uttarakhand with the aim of comparing these two indices in community setting. The specific objectives were to find ADL dependence by both the indices, find the factors which significantly affect ADL dependence and to find the degree of agreement which is not by chance between Katz and Barthel Indices.Material methods: An interview schedule was developed and administered to participants in Hindi, by trained investigators. Information on age, marital status, living status education, occupation and economic dependence was recorded. House-to-house visits were conducted in the selected area to collect the data. All elderly persons residing in the selected area were included in the study.Results: Prevalence of ADL dependence was 8.23% as per Katz Index and 28.45% as per Barthel Index, taking a score of less than 20 for BI and less than 6 for KI as criterion for ADL dependence. That there is a moderate degree of agreement between Katz and Barthel Scores which is not by chance was estimated by Kappa Statistic.Conclusion: Katz Index is better suited for ADL estimation in a community setting.

  8. Architectural design and first results evaluation of the PowerMatching City field test

    Energy Technology Data Exchange (ETDEWEB)

    Kamphuis, I.G.; Roossien, B. [Unit Efficiency and Infrastructure, Energy research Centre of the Netherlands, Westerduinweg 3, P.O. Box 1, 1755 ZG Petten (Netherlands); Bliek, F.W.; Van den Noort, A. [KEMA/Gas Consultancy Services, Groningen (Netherlands); Van de Velde, J.; De Wit, J. [HUMIQ, Groningen (Netherlands)

    2011-01-15

    Starting from the beginning of 2010, in the EU FP6 Integral4 project, a large-scale SmartGrid field test with active participation of end-user installation nodes in the electricity network is running. A high-bandwidth dedicated ICTnetwork has been rolled-out to connect electricity supply and demand nodes and to collect data. In the test, the software agent based PowerMatcher technology is applied in a Virtual Power Plant (VPP) setting to satisfy a number of commercial and grid related optimization objectives. The VPP in the test consists of 25 heating devices in homes in Hoogkerk, nodes with PV and wind generated electricity, residential and mobile (full EV's) electricity storage nodes and intelligent home appliances. Primary process flexibility for the heating system's hybrid heat pumps and micro-CHP is enlarged by using hot water filled heat buffers. Additional gas burning heating capacity to be used in peak periods was added to the system configuration. Additional demand response flexibility is achieved by optimizing the charging strategy of the nodes with electricity storage and the operation of devices connected to demands like refrigerators and washing machines. In this way, on a real-time basis, the VPP has been shown to be usable for optimization to satisfy objectives for compensation of the variable output of renewables, for improving grid operation and functions for commercial operation. In this paper the architectural design and the application of the PowerMatcher approach is evaluated. The first results of operating the use cases are also presented.

  9. Voltammetric Investigation Of Hydrothermal Iron Speciation

    Directory of Open Access Journals (Sweden)

    Charlotte eKleint

    2016-05-01

    Full Text Available Hydrothermal vent fluids are highly enriched in iron (Fe compared to ambient seawater, and organic ligands may play a role in facilitating the transport of some hydrothermal Fe into the open ocean. This is important since Fe is a limiting micronutrient for primary production in large parts of the world`s surface ocean. We have investigated the concentration and speciation of Fe in several vent fluid and plume samples from the Nifonea vent field, Coriolis Troughs, New Hebrides Island Arc, South Pacific Ocean using competitive ligand exchange - adsorptive cathodic stripping voltammetry (CLE - AdCSV with salicylaldoxime (SA as the artificial ligand. Our results for total dissolved Fe (dFe in the buoyant hydrothermal plume samples showed concentrations up to 3.86 µM dFe with only a small fraction between 1.1% and 11.8% being chemically labile. Iron binding ligand concentrations ([L] were found in µM level with strong conditional stability constants up to log K[L],Fe3+ of 22.9. Within the non-buoyant hydrothermal plume above the Nifonea vent field, up to 84.7% of the available Fe is chemically labile and [L] concentrations up to 97 nM were measured. [L] was consistently in excess of Felab, indicating that all available Fe is being complexed, which in combination with high Felab values in the non-buoyant plume, signifies that a high fraction of hydrothermal dFe is potentially being transported away from the plume into the surrounding waters, contributing to the global oceanic Fe budget.

  10. On-Road Measurement of Vehichle VOC Emission Measurements During the 2003 Mexico City Metropolitan Area Field Campaign

    Science.gov (United States)

    Knighton, W. B.; Rogers, T.; Grimsrud, E.; Herndon, S.; Allwine, E.; Lamb, B.; Velasco, E.; Westberg, H.

    2004-12-01

    In the spring of 2003 (April 1-May 5), a multinational team of experts conducted an intensive, five-week field campaign in the Mexico City Metropolitan Area (MCMA). The overall goal of this effort was to contribute to the understanding of the air quality problem in megacities. As part of the campaign the Aerodyne Mobile Laboratory was equipped with state-of-the-art analytical instruments and deployed for measuring a variety of vehicle emissions in real time including CO2, NO2, NH3, HCHO, VOC's and volatile (at 600 °C) aerosol. The on-road measurement of vehicle VOC emissions were performed using a commercial version of the IONICON PTR-MS modified to operate onboard the mobile lab platform. A summary of the PTR-MS results from these and supporting laboratory experiments will be presented and discussed. In particular, selected chase events will be presented to illustrate the utility of the PTR-MS technique for characterizing vehicle VOC emission profiles in real time. VOC emission profiles for different vehicle engine types which include gasoline, diesel and compressed natural gas will be discussed and compared to the measurements from other high time response instruments deployed on the Aerodyne mobile van.

  11. Hydrothermal synthesis of hydroxyapatite

    Science.gov (United States)

    Earl, J. S.; Wood, D. J.; Milne, S. J.

    2006-02-01

    A hydrothermal method of synthesizing hydroxyapatite by heating a precipitate, formed by mixing Ca(NO3)2bold dot4H2O and (NH4)2HPO4 with distilled water, in a hydrothermal reactor at 200 °C for 24-72 hrs is described. A treatment time of 24 hrs produced single phase (as shown by XRD) hydroxyapatite powder, however for longer treatment times XRD patterns were indicative of the presence of a secondary phase, monetite (CaHPO4). SEM examination of the treated powders displayed particles of rod-like morphology with dimensions 100-500 nm in length and 10-60 nm in diameter. Preliminary results on the use of the particles for the infiltration of dentine tubules are presented.

  12. Hydrothermal synthesis of hydroxyapatite

    Energy Technology Data Exchange (ETDEWEB)

    Earl, J S; Wood, D J; Milne, S J [Institute for Materials Research, University of Leeds, Leeds, LS2 9JT (United Kingdom)

    2006-02-22

    A hydrothermal method of synthesizing hydroxyapatite by heating a precipitate, formed by mixing Ca(NO{sub 3}){sub 2}{center_dot}4H{sub 2}O and (NH{sub 4}){sub 2}HPO{sub 4} with distilled water, in a hydrothermal reactor at 200 deg. C for 24-72 hrs is described. A treatment time of 24 hrs produced single phase (as shown by XRD) hydroxyapatite powder, however for longer treatment times XRD patterns were indicative of the presence of a secondary phase, monetite (CaHPO{sub 4}). SEM examination of the treated powders displayed particles of rod-like morphology with dimensions 100-500 nm in length and 10-60 nm in diameter. Preliminary results on the use of the particles for the infiltration of dentine tubules are presented.

  13. Hydrothermal liquefaction of biomass

    DEFF Research Database (Denmark)

    Toor, Saqib; Rosendahl, Lasse; Hoffmann, Jessica

    2014-01-01

    Biomass is one of the most abundant sources of renewable energy, and will be an important part of a more sustainable future energy system. In addition to direct combustion, there is growing attention on conversion of biomass into liquid en-ergy carriers. These conversion methods are divided...... into liquid biofuels, with the aim of describing the current status and development challenges of the technology. During the hydrothermal liquefaction process, the biomass macromolecules are first hydrolyzed and/or degraded into smaller molecules. Many of the produced molecules are unstable and reactive...... into biochemical/biotechnical methods and thermochemical methods; such as direct combustion, pyrolysis, gasification, liquefaction etc. This chapter will focus on hydrothermal liquefaction, where high pressures and intermediate temperatures together with the presence of water are used to convert biomass...

  14. 声学法深海热液速度场测量重建算法研究%Reconstruction algorithm for acoustic measurement of velocity field of deep-sea hydrothermal vents

    Institute of Scientific and Technical Information of China (English)

    白燕; 毛洁; 樊炜; 潘华辰; 刘云峰

    2011-01-01

    介绍了利用声学法测量深海热液速度场的基本原理.利用往返飞渡时间差与流场速度的关系,应用反问题求解技术重建测量区域的速度场.应用最小二乘法对两种典型的热液口速度场模型进行了仿真重建,分析了换能器数量、实验测量误差以及换能器的布放对重建结果的影响,并对重建结果进行了流量分析.仿真重建的绝对误差、相对误差以及流量分析结果表明,最小二乘法具有较高重建精度,增加声学换能器及细化网格可提高重建精度,换能器对称分布时具有最优重建结果.最后对声学法深海热液温度场速度场测量系统进行了介绍和说明.深海热液速度场的测量重建可为热液热通量的测量奠定基础.%The basic theory of acoustic velocity field measurement in deep-sea hydrothermal vents was introduced.The time of flight (TOF) of acoustic signals through hydrothermal vents was dependent on temperature and velocity.The velocity field was reconstructed by inverse problem solving techniques based on the relationship between the round-trip TOF difference and velocity of flow. The reconstruction of velocity field using the least square method was presented. At the same time, flow flux of reconstruction results was analyzed. The results show that the least square method has good accuracy. Increase of the number of acoustic transducers and mesh density can improve the reconstruction accuracy effectively.

  15. State of the Art, Trends and Future of Bluetooth Low Energy, Near Field Communication and Visible Light Communication in the Development of Smart Cities.

    Science.gov (United States)

    Cerruela García, Gonzalo; Luque Ruiz, Irene; Gómez-Nieto, Miguel Ángel

    2016-11-23

    The current social impact of new technologies has produced major changes in all areas of society, creating the concept of a smart city supported by an electronic infrastructure, telecommunications and information technology. This paper presents a review of Bluetooth Low Energy (BLE), Near Field Communication (NFC) and Visible Light Communication (VLC) and their use and influence within different areas of the development of the smart city. The document also presents a review of Big Data Solutions for the management of information and the extraction of knowledge in an environment where things are connected by an "Internet of Things" (IoT) network. Lastly, we present how these technologies can be combined together to benefit the development of the smart city.

  16. State of the Art, Trends and Future of Bluetooth Low Energy, Near Field Communication and Visible Light Communication in the Development of Smart Cities

    Science.gov (United States)

    Cerruela García, Gonzalo; Luque Ruiz, Irene; Gómez-Nieto, Miguel Ángel

    2016-01-01

    The current social impact of new technologies has produced major changes in all areas of society, creating the concept of a smart city supported by an electronic infrastructure, telecommunications and information technology. This paper presents a review of Bluetooth Low Energy (BLE), Near Field Communication (NFC) and Visible Light Communication (VLC) and their use and influence within different areas of the development of the smart city. The document also presents a review of Big Data Solutions for the management of information and the extraction of knowledge in an environment where things are connected by an “Internet of Things” (IoT) network. Lastly, we present how these technologies can be combined together to benefit the development of the smart city. PMID:27886087

  17. Commercial real estate investment in Ho Chi Minh City: a level playing field for foreign and domestic investors?

    NARCIS (Netherlands)

    Nguyen, B.T.; Krabben, E. van der; Samsura, D.A.A.

    2014-01-01

    In Vietnam, similarly to other countries with the same system, transformation of the economy from one based on central planning into one founded on market principles, provides incomplete property rights in land and property markets. Nonetheless, cities like Ho Chi Minh City (HCMC) are experiencing s

  18. Elemental geochemical records of seafloor hydrothermal activities in the sediments from the Okinawa Trough

    Institute of Scientific and Technical Information of China (English)

    ZHAI Shikui; YU Zenghui; DU Tongjun

    2007-01-01

    The major and minor element contents in the sediment core H9 from the hydrothermal fields of the Okinawa Trough show a sharp change at the depth of 80 cm. The elements enriched in the upper 80 cm core are those enriched in the hydrothermal deposits and in the surface sediments recovered from the hydrothermal fields in the trough, which indicates the input of hydrothermal materials. Comparing with other hydrothermal sediments from Mid-ocean Ridges or the Lau Basin, the degree of the enrichment of elements iron, copper, cobalt, and nickel is relatively low. However, the enrichment of elements manganese, lead, arsenic, antimony and mercury is remarkable. The average contents of these elements in the upper 80 cm core sediments are three to six times those in the lower section, and 3 ~ 12 times those in the surface sediments which are not influenced by hydrothermal activities. Hydrothermal activities have contributed significant manganese, lead, arsenic, antimony and mercury to the sediments, and these elements are distinct indicators for the hydrothermal activity in the Okinawa Trough. The significant enrichment of these elements in Core H9 upward from the depth 80 cm indicates the start or the significant enhancing of the hydrothermal activity in this area at about 5 740 aB. P. The average accumulation rate of manganese during this period is about 40 461 μg/( cm2 · ka), which is similar to the hydrothermal sediments in the Lau Basin or the East Pacific Rise.

  19. Investigation of extractable organic compounds in deep-sea hydrothermal vent fluids along the Mid-Atlantic Ridge

    Science.gov (United States)

    McCollom, Thomas M.; Seewald, Jeffrey S.; German, Christopher R.

    2015-05-01

    The possibility that deep-sea hydrothermal vents may contain organic compounds produced by abiotic synthesis or by microbial communities living deep beneath the surface has led to numerous studies of the organic composition of vent fluids. Most of these studies have focused on methane and other light hydrocarbons, while the possible occurrence of more complex organic compounds in the fluids has remained largely unstudied. To address this issue, the presence of higher molecular weight organic compounds in deep-sea hydrothermal fluids was assessed at three sites along the Mid-Atlantic Ridge that span a range of temperatures (51 to >360 °C), fluid compositions, and host-rock lithologies (mafic to ultramafic). Samples were obtained at several sites within the Lucky Strike, Rainbow, and Lost City hydrothermal fields. Three methods were employed to extract organic compounds for analysis, including liquid:liquid extraction, cold trapping on the walls of a coil of titanium tubing, and pumping fluids through cartridges filled with solid phase extraction (SPE) sorbents. The only samples to consistently yield high amounts of extractable organic compounds were the warm (51-91 °C), highly alkaline fluids from Lost City, which contained elevated concentrations of C8, C10, and C12n-alkanoic acids and, in some cases, trithiolane, hexadecanol, squalene, and cholesterol. Collectively, the C8-C12 acids can account for about 15% of the total dissolved organic carbon in the Lost City fluids. The even-carbon-number predominance of the alkanoic acids indicates a biological origin, but it is unclear whether these compounds are derived from microbial activity occurring within the hydrothermal chimney proximal to the site of fluid discharge or are transported from deeper within the system. Hydrothermal fluids from the Lucky Strike and Rainbow fields were characterized by an overall scarcity of extractable dissolved organic compounds. Trace amounts of aromatic hydrocarbons including

  20. Metagenomic and PCR-Based Diversity Surveys of [FeFe]-Hydrogenases Combined with Isolation of Alkaliphilic Hydrogen-Producing Bacteria from the Serpentinite-Hosted Prony Hydrothermal Field, New Caledonia

    Science.gov (United States)

    Mei, Nan; Postec, Anne; Monnin, Christophe; Pelletier, Bernard; Payri, Claude E.; Ménez, Bénédicte; Frouin, Eléonore; Ollivier, Bernard; Erauso, Gaël; Quéméneur, Marianne

    2016-01-01

    High amounts of hydrogen are emitted in the serpentinite-hosted hydrothermal field of the Prony Bay (PHF, New Caledonia), where high-pH (~11), low-temperature (< 40°C), and low-salinity fluids are discharged in both intertidal and shallow submarine environments. In this study, we investigated the diversity and distribution of potentially hydrogen-producing bacteria in Prony hyperalkaline springs by using metagenomic analyses and different PCR-amplified DNA sequencing methods. The retrieved sequences of hydA genes, encoding the catalytic subunit of [FeFe]-hydrogenases and, used as a molecular marker of hydrogen-producing bacteria, were mainly related to those of Firmicutes and clustered into two distinct groups depending on sampling locations. Intertidal samples were dominated by new hydA sequences related to uncultured Firmicutes retrieved from paddy soils, while submarine samples were dominated by diverse hydA sequences affiliated with anaerobic and/or thermophilic submarine Firmicutes pertaining to the orders Thermoanaerobacterales or Clostridiales. The novelty and diversity of these [FeFe]-hydrogenases may reflect the unique environmental conditions prevailing in the PHF (i.e., high-pH, low-salt, mesothermic fluids). In addition, novel alkaliphilic hydrogen-producing Firmicutes (Clostridiales and Bacillales) were successfully isolated from both intertidal and submarine PHF chimney samples. Both molecular and cultivation-based data demonstrated the ability of Firmicutes originating from serpentinite-hosted environments to produce hydrogen by fermentation, potentially contributing to the molecular hydrogen balance in situ. PMID:27625634

  1. City 2020+

    Science.gov (United States)

    Schneider, C.; Buttstädt, M.; Merbitz, H.; Sachsen, T.; Ketzler, G.; Michael, S.; Klemme, M.; Dott, W.; Selle, K.; Hofmeister, H.

    2010-09-01

    several public transport units running all across the city. This is accompanied by an analysis of probability density functions (PDF) for heat waves based on recent climate data and climate projections. A dense net of 40 PM measurement sites is operated in order to obtain the spatial pattern of PM concentration as depending on meteorological condition and location. It is lined out how this climate related sub-projects interact with investigations on social networks, governance issues, buildings structure development and health outcome. Related to the later the chemical composition of PM is analyzed in more detail and related to the spatial patterns of health deficiencies. At a later stage City2020+ will propose new strategies based on cooperation from the fields of medicine, geography, sociology, history, civil engineering, and architecture for adapting the city for future needs. The Project CITY 2020+ is part of the interdisciplinary Project House HumTec (Human Sciences and Technology) at RWTH Aachen University funded by the Excellence Initiative of the German federal and state governments through the Deutsche Forschungsgemeinschaft (German Research Foundation, DFG).

  2. Free-living nematode species (Nematoda) dwelling in hydrothermal sites of the North Mid-Atlantic Ridge

    Science.gov (United States)

    Tchesunov, Alexei V.

    2015-12-01

    Morphological descriptions of seven free-living nematode species from hydrothermal sites of the Mid-Atlantic Ridge are presented. Four of them are new for science: Paracanthonchus olgae sp. n. (Chromadorida, Cyatholaimidae), Prochromadora helenae sp. n. (Chromadorida, Chromadoridae), Prochaetosoma ventriverruca sp. n. (Desmodorida, Draconematidae) and Leptolaimus hydrothermalis sp. n. (Plectida, Leptolaimidae). Two species have been previously recorded in hydrothermal habitats, and one species is recorded for the first time in such an environment. Oncholaimus scanicus (Enoplida, Oncholaimidae) was formerly known from only the type locality in non-hydrothermal shallow milieu of the Norway Sea. O. scanicus is a very abundant species in Menez Gwen, Lucky Strike and Lost City hydrothermal sites, and population of the last locality differs from other two in some morphometric characteristics. Desmodora marci (Desmodorida, Desmodoridae) was previously known from other remote deep-sea hydrothermal localities in south-western and north-eastern Pacific. Halomonhystera vandoverae (Monhysterida, Monhysteridae) was described and repeatedly found in mass in Snake Pit hydrothermal site. The whole hydrothermal nematode assemblages are featured by low diversity in comparison with either shelf or deep-sea non-hydrothermal communities. The nematode species list of the Atlantic hydrothermal vents consists of representatives of common shallow-water genera; the new species are also related to some shelf species. On the average, the hydrothermal species differ from those of slope and abyssal plains of comparable depths by larger sizes, diversity of buccal structures, presence of food content in the gut and ripe eggs in uteri.

  3. Hydrothermal iron flux variability following rapid sea level changes

    Science.gov (United States)

    Middleton, Jennifer L.; Langmuir, Charles H.; Mukhopadhyay, Sujoy; McManus, Jerry F.; Mitrovica, Jerry X.

    2016-04-01

    Sea level changes associated with Pleistocene glacial cycles have been hypothesized to modulate melt production and hydrothermal activity at ocean ridges, yet little is known about fluctuations in hydrothermal circulation on time scales longer than a few millennia. We present a high-resolution record of hydrothermal activity over the past 50 ka using elemental flux data from a new sediment core from the Mir zone of the TAG hydrothermal field at 26°N on the Mid-Atlantic Ridge. Mir sediments reveal sixfold to eightfold increases in hydrothermal iron and copper deposition during the Last Glacial Maximum, followed by a rapid decline during the sea level rise associated with deglaciation. Our results, along with previous observations from Pacific and Atlantic spreading centers, indicate that rapid sea level changes influence hydrothermal output on mid-ocean ridges. Thus, climate variability may discretize volcanic processing of the solid Earth on millennial time scales and subsequently stimulate variability in biogeochemical interactions with volcanic systems.

  4. Responsive City Lighting

    DEFF Research Database (Denmark)

    Poulsen, Esben Skouboe; Andersen, Hans Jørgen; Jensen, Ole B.

    This paper presents and discusses perspectives extracted from two interviews conducted during the experiments Urban Responsive Lighting. The two experts embody two different fields related to city lighting: architecture & public lighting industry. The representatives were invited to the test...... on applied technologies and responsive light design in the contemporary cities....

  5. Microbiological production and ecological flux of northwestern subduction hydrothermal systems

    Science.gov (United States)

    Sunamura, M.; Okamura, K.; Noguchi, T.; Yamamoto, H.; Fukuba, T.; Yanagawa, K.

    2012-12-01

    Deep-sea hydrothermal system is one of the most important sources for heat and chemical flux from the oceanic crust to the global ocean. The rich biological community around the hydrothermal vent shows chemolithoautotrophic microbial production are important in deep sea ecosystems. More than 99% of microbiological available chemical components in hydrothermal vent fluid, e.g. sulfide, methane, hydrogen, Fe2+, and Mn2+, is released into surrounding seawater to construct hydrothermal plume, suggesting that the chemolithoautotrophic-microbial primary production in the hydrothermal plume is huge and important in the whole hydrothermal ecosystems. To understand the impact of hydrothermal plume to a microbial ecosystem and a connectivity with zooplankton, we targeted and investigated a total of 16 hydrothermal fileds (7 sites in Okinawa trough, 3 sites in Ogasawara arc, and 6 sites in Mariana arc and back arc) and investigated in several cruises under the TAIGA project in Japan. Hydrothermal fluids in the subduction system are rich in sulfide. The hydrothermal fluids in the Okinawa trough, Ogasawara arc. and Mariana trough are characterized by rich in methane, poor in other reduced chemicals, and rich in iron, respectively. The major microbial composition was a potential sulfur oxidizing microbes SUP05 in the plume ecosystems, while an aerobic methanotrophic bacteria was secondary major member in methane-rich hydrothermal systems in Okinawa trough. Microbial quantitative and spatial distribution analyses of each plume site showed that the microbial population size and community structures are influenced by original chemical components of hydrothermal fluid, e.g. sulfide, methane and iron concentration. Microbial quantitative data indicated the removal/sedimentation of microbial cells from the plume and effect of phase separation in a same vent field through construction of gas-rich or gas-poor plumes. After the correlation of plume mixing effect, we estimates that the

  6. Where are the undiscovered hydrothermal vents on oceanic spreading ridges?

    Science.gov (United States)

    Beaulieu, Stace E.; Baker, Edward T.; German, Christopher R.

    2015-11-01

    In nearly four decades since the discovery of deep-sea vents, one-third of the length of global oceanic spreading ridges has been surveyed for hydrothermal activity. Active submarine vent fields are now known along the boundaries of 46 out of 52 recognized tectonic plates. Hydrothermal survey efforts over the most recent decade were sparked by national and commercial interests in the mineral resource potential of seafloor hydrothermal deposits, as well as by academic research. Here we incorporate recent data for back-arc spreading centers and ultraslow- and slow-spreading mid-ocean ridges (MORs) to revise a linear equation relating the frequency of vent fields along oceanic spreading ridges to spreading rate. We apply this equation globally to predict a total number of vent fields on spreading ridges, which suggests that ~900 vent fields remain to be discovered. Almost half of these undiscovered vent fields (comparable to the total of all vent fields discovered during 35 years of research) are likely to occur at MORs with full spreading rates less than 60 mm/yr. We then apply the equation regionally to predict where these hydrothermal vents may be discovered with respect to plate boundaries and national jurisdiction, with the majority expected to occur outside of states' exclusive economic zones. We hope that these predictions will prove useful to the community in the future, in helping to shape continuing ridge-crest exploration.

  7. Discussion About City Field Based on Econophysics%从经济物理学到城市场略论

    Institute of Scientific and Technical Information of China (English)

    张刚; 张爱英; 左大杰

    2016-01-01

    In recent years,many of the important theoretical achievements of physics have been used to econom-ic research,which have enormously promoted the development of economics.In this paper, the econophysics re-search method have been well adopted while the Theory of City Fields have been comparatively demonstrated based on Electromagnetic Fields Theory and Model,which have scientific rationality and have promoted and developed the vision and height of existing research field of interaction between cities.%经济物理学已经发展成为一门新的交叉学科,物理学的许多重要理论成果被运用到经济研究中,极大地促进了经济学的发展。经济系统与物理系统具有共同的基点,共同服从某种普适的规律,运用经济物理学的研究方法,以电磁场理论和模型为研究工具,构建城市场理论及其模型研究城市间相互作用的机理和效应,具有科学合理性,拓展和提升了现有研究的视野和高度。

  8. Inversion Approach For Thermal Data From A Convecting Hydrothermal System

    Energy Technology Data Exchange (ETDEWEB)

    Kasameyer, P.; Younker, L.; Hanson, J.

    1985-01-01

    Hydrothermal systems are often studied by collecting thermal gradient data and temperature depth curves. These data contain important information about the flow field, the evolution of the hydrothermal system, and the location and nature of the ultimate heat sources. Thermal data are conventionally interpreted by the ''forward'' method; the thermal field is calculated based on selected initial conditions and boundary conditions such as temperature and permeability distributions. If the calculated thermal field matches the data, the chosen conditions are inferred to be possibly correct. Because many sets of initial conditions may produce similar thermal fields, users of the ''forward'' method may inadvertently miss the correct set of initial conditions. Analytical methods for ''inverting'' data also allow the determination of all the possible solutions consistent with the definition of the problem. In this paper we suggest an approach for inverting thermal data from a hydrothermal system, and compare it to the more conventional approach. We illustrate the difference in the methods by comparing their application to the Salton Sea Geothermal Field by Lau (1980a) and Kasameyer, et al. (1984). In this particular example, the inverse method was used to draw conclusions about the age and total rate of fluid flow into the hydrothermal system.

  9. Image city

    DEFF Research Database (Denmark)

    2003-01-01

    Image city exhibition explores a condition of mediation, through a focus on image and sound narratives with a point of departure on a number of Asian cities.......Image city exhibition explores a condition of mediation, through a focus on image and sound narratives with a point of departure on a number of Asian cities....

  10. Porosity evolution in Icelandic hydrothermal systems

    Science.gov (United States)

    Thien, B.; Kosakowski, G.; Kulik, D. A.

    2014-12-01

    Mineralogical alteration of reservoir rocks, driven by fluid circulation in natural or enhanced hydrothermal systems, is likely to influence the long-term performance of geothermal power generation. A key factor is the change of porosity due to dissolution of primary minerals and precipitation of secondary phases. Porosity changes will affect fluid circulation and solute transport, which, in turn, influence mineralogical alteration. This study is part of the Sinergia COTHERM project (COmbined hydrological, geochemical and geophysical modeling of geotTHERMal systems, grant number CRSII2_141843/1) that is an integrative research project aimed at improving our understanding of the sub-surface processes in magmatically-driven natural geothermal systems. These are typically high enthalphy systems where a magmatic pluton is located at a few kilometers depth. These shallow plutons increase the geothermal gradient and trigger the circulation of hydrothermal waters with a steam cap forming at shallow depth. Field observations suggest that active and fossil Icelandic hydrothermal systems are built from a superposition of completely altered and completely unaltered layers. With help of 1D and 2D reactive transport models (OpenGeoSys-GEM code), we investigate the reasons for this finding, by studying the mineralogical evolution of protoliths with different initial porosities at different temperatures and pressures, different leaching water composition and gas content, and different porosity geometries (i.e. porous medium versus fractured medium). From this study, we believe that the initial porosity of protoliths and volume changes due to their transformation into secondary minerals are key factors to explain the different alteration extents observed in field studies. We also discuss how precipitation and dissolution kinetics can influence the alteration time scales.

  11. Chaotic thermohaline convection in low-porosity hydrothermal systems

    NARCIS (Netherlands)

    Schoofs, Stan; Spera, Frank J.; Hansen, Ulrich

    2001-01-01

    Fluids circulate through the Earth's crust perhaps down to depths as great as 5^15 km, based on oxygen isotope systematics of exhumed metamorphic terrains, geothermal fields, mesozonal batholithic rocks and analysis of obducted ophiolites. Hydrothermal flows are driven by both thermal and chemical b

  12. City of El Centro geothermal energy utility core field experiment. Final report, February 16, 1979-November 30, 1984

    Energy Technology Data Exchange (ETDEWEB)

    Province, S.G.; Sherwood, P.B.

    1984-11-01

    The City of El Centro was awarded a contract in late 1978 to cost share the development of a low to moderate temperature geothermal resource in the City. The resource would be utilized to heat, cool and provide hot water to the nearby Community Center. In December 1981, Thermal 1 (injector) was drilled to 3970 feet. In January 1982, Thermal 2 (producer) was drilled to 8510 feet. Before testing began, fill migrated into both wells. Both wells were cleaned out. A pump was installed in the producer, but migration of fill again into the injector precluded injection of produced fluid. A short term production test was undertaken and results analyzed. Based upon the analysis, DOE decided that the well was not useful for commercial production due to a low flow rate, the potential problems of continued sanding and gasing, and the requirement to lower the pump setting depth and the associated costs of pumping. There was no commercial user found to take over the wells. Therefore, the wells were plugged and abandoned. The site was restored to its original condition.

  13. Geophysical characterization of subaerial hydrothermal manifestations in Punta Banda, Baja California, Mexico.

    Science.gov (United States)

    Flores-Marquez, L.; Prol-Ledesma, R. M.; Arango, C.; Canet, C.

    2009-04-01

    Important growth of population in Baja California Peninsula has triggered the need for energy and fresh water. The most sustainable possibility for increasing the availability of fresh water is the use of renewable energy sources in desalination plants. The abundance of geothermal manifestations in the peninsula provides a reliable energy source for desalination purposes. Geothermal development of the Baja California Peninsula dates from the 70's, when the Cerro Prieto geothermal field started producing electricity. Two important cities, Tijuana and Ensenada, are located in the north-western area of Baja California. The city of Ensenada has a desalination plant that is due to be replaced and the geothermal resources of the area could be an option for the new desalination plant. Punta Banda, a region near Ensenada, was specially investigated to determine its geothermal potential. Subaerial springs and the submarine vents were sampled and studied in this work, also geological and geochemical studies were performed, moreover geoelectrical surveys were accomplished to characterize the hydrothermal system at depth. Even though saline intrusion is a severe problem in Ensenada (TDS higher than 3000), thermal springs away from the coast and coastal springs have salinities lower than sea water. According to the geoelectrical models obtained from profiles, the inferred conductive features can be related to thermal anomalies. The existence of hot springs located along a trend suggests that the dynamic of the thermal fluid is restricted by secondary faults.

  14. Hydrothermal Synthesis of Metal Silicates

    Institute of Scientific and Technical Information of China (English)

    Lii Kwang-Hwa

    2004-01-01

    Organically templated metal phosphates have been extensively studied because of interesting structural chemistry and potential applications in catalysis. However, in most cases the organic templates cannot be removed without collapse of the frameworks. This is in contrast to the high thermal stability and extensive applications of zeolites in refinery and petrochemical processes.Therefore, studies have been directed to the synthesis of transition metal silicates to produce more stable frameworks. Our synthetic methods are twofold, namely mild hydrothermal reactions in Teflon-lined autoclaves at 100-200 ℃ using organic amines as templates and high-temperature,high-pressure hydrothermal reactions in gold ampoules contained in a high-pressure reaction vessel at ca. 550 ℃ and 150 Mpa using alkali metal cations as templates. In this presentation I will report the high-temperature, high-pressure hydrothermal synthesis, crystal structures, and solid-state NMR spectroscopy of a number of new silicates of indium, uranium, and transition metals.

  15. Verification of a Mesoscale Data-Assimilation and Forecasting System for the Oklahoma City Area during the Joint Urban 2003 Field Project

    Science.gov (United States)

    Liu, Yubao; Chen, Fei; Warner, Thomas; Basara, Jeffrey

    2006-07-01

    The National Center for Atmospheric Research (NCAR) and the U.S. Army Test and Evaluation Command have developed a multiscale, rapid-cycling, real-time, four-dimensional data-assimilation and forecasting system that has been in operational use at five Army test ranges since 2001. This system was employed to provide operational modeling support for the Joint Urban 2003 (JU2003) Dispersion Experiment, conducted in Oklahoma City, Oklahoma, during July 2003. To better support this mission, modifications were made to the nonlocal boundary layer (BL) parameterization (known as the Medium Range Forecast scheme) of the fifth-generation Pennsylvania State University NCAR Mesoscale Model, in order to improve BL forecasts. The NCEP Oregon State University Air Force Hydrologic Research Laboratory land surface model was also improved to better represent urban forcing. Verification of the operational model runs and retrospectively simulated cases show 1) a significantly reduced low bias in the forecast surface wind speed and 2) more realistic daytime BL heights. During JU2003, the forecast urban heat island, urban dry bubble, and urban BL height agree reasonably well with observations and conceptual models. An analysis of three-dimensional atmospheric structures, based on model analyses for eight clear-sky days during the field program, reveals some interesting features of the Oklahoma City urban BL, including complex thermally induced circulations and associated convergence/divergence zones, a nocturnal thermal shadow downwind of the urban area, and the reduction of low-level jet wind speeds by more vigorous nocturnal mixing over the city.

  16. Hydrothermalism in the Mediterranean Sea

    Science.gov (United States)

    Dando, P. R.; Stüben, D.; Varnavas, S. P.

    1999-08-01

    Hydrothermalism in the Mediterranean Sea results from the collision of the African and European plates, with the subduction of the oceanic part of the African plate below Europe. High heat flows in the resulting volcanic arcs and back-arc extensional areas have set-up hydrothermal convection systems. Most of the known hydrothermal sites are in shallow coastal waters, <200 m depth, so that much of the reported fluid venting is of the gasohydrothermal type. The hydrothermal liquids are of varying salinities, both because of phase separation as a result of seawater boiling at the low pressures and because of significant inputs of rainfall into the hydrothermal reservoirs at some sites. The major component of the vented gas is carbon dioxide, with significant quantities of sulphur dioxide, hydrogen sulphide, methane and hydrogen also being released. Acid leaching of the underlying rocks leads to the mobilisation of heavy metals, many of which are deposited sub-surface although there is a conspicuous enrichment of metals in surficial sediments in venting areas. Massive polymetalic sulphides have been reported from some sites. No extant vent-specific fauna have been described from Mediterranean sites. There is a reduced diversity of fauna within the sediments at the vents. In contrast, a high diversity of epifauna has been reported and the vent sites are areas of settlement for exotic thermophilic species. Large numbers of novel prokaryotes, especially hyperthermophilic crenarchaeota, have been isolated from Mediterranean hydrothermal vents. However, their distribution in the subsurface biosphere and their role in the biogeochemistry of the sites has yet to be studied.

  17. Universities Scale Like Cities

    CERN Document Server

    van Raan, Anthony F J

    2012-01-01

    Recent studies of urban scaling show that important socioeconomic city characteristics such as wealth and innovation capacity exhibit a nonlinear, particularly a power law scaling with population size. These nonlinear effects are common to all cities, with similar power law exponents. These findings mean that the larger the city, the more disproportionally they are places of wealth and innovation. Local properties of cities cause a deviation from the expected behavior as predicted by the power law scaling. In this paper we demonstrate that universities show a similar behavior as cities in the distribution of the gross university income in terms of total number of citations over size in terms of total number of publications. Moreover, the power law exponents for university scaling are comparable to those for urban scaling. We find that deviations from the expected behavior can indeed be explained by specific local properties of universities, particularly the field-specific composition of a university, and its ...

  18. Beer City

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Shandong Province’s Qingdao is becoming China’s great beer city sicenically located on a peninsula over-looking the Pacific Ocean, Qingdao, |or Tsingtao, is a coastal city soaked in two kinds of foam. One floats in

  19. Survivability and condensation of amino acids in simulated submarine hydrothermal environments

    OpenAIRE

    Chandru, Balasanthiran Kuhan

    2013-01-01

    The discovery of hydrothermal systems in the late 70’s brought a new hypothesis to the origin of life. Previously, the Urey-Miller experiment had made waves in this new field, indicating that a reducing atmosphere could form amino acids from basic chemicals. The further discovery of hydrothermal systems with earth’s prebiotic conditions added another notion to the field. Since then, different kinds of simulation were conducted to test the hypothesis. Initially and autoclave was extensively us...

  20. [Evaluation of the levels of radiofrequency electromagnetic fields in the territory of the city of Bari in outside and inside environments].

    Science.gov (United States)

    L'Abbate, N; Pranzo, S; Martucci, V; Rella, C; Vitucci, L; Salamanna, S

    2004-01-01

    In this study we measured the levels of the high frequency field in the proximity of non-ionizing radiation sources (wireless transmitting stations for mobile telephones and radio and television transmitters) in nine districts of the city of Bari. The measurements were taken both inside and outside closed environments. For the indoor measurements we took into account electromagnetic field generating equipment (VDT, electric domestic appliances, mobile telephones) in working and non-working order and with the windows open and shut respectively. We carried out these measurements according to the methods laid down in the Italian regulation CEI ENV 50166-2 of May 1995, as shown in the enclosure to the Ministerial Decree of 10.9.98 n.381. The electromagnetic field levels near wireless transmitting stations for mobile telephones are certainly modest when we consider that they never exceeded the limits established by the aforesaid Ministerial Decree. On the contrary radio and television equipment creates a much greater source of exposure. The electromagnetic field levels are certainly superior to those of the wireless transmitting stations although they never exceed, except in one isolated case, the values established by the Ministerial Decree 381/98.

  1. Microwave Hydrothermal Synthesis PZT of Nanometer Crystal

    Institute of Scientific and Technical Information of China (English)

    Hongxing LIU; Hong DENG; Yan LI; Yanrong LI

    2004-01-01

    It was focused on the applications and developments of microwave hydrothermal synthesis piezoelectric ceramic powder. The microwave hydrothermal vessel was designed and manufactured. The microwave hydrothermal synthesis system was established and the PZT piezoelectric ceramic powder was synthesized. XRD and TEM have been used to characterize the products in detail. The diameter of the PZT powder particle is from 40 to 60 nm.

  2. Effect of hydrothermal heat treatment on magnetic properties of copper zinc ferrite rf sputtered films

    Directory of Open Access Journals (Sweden)

    Jasmeet Kaur

    2016-05-01

    Full Text Available The hydrothermal treatment to the nano-structured films can overcome the destruction of the films. The Cu-Zn Ferrite films were fabricated by RF-sputtering on quartz substrates. Subsequently, the as deposited films were heat treated using hydrothermal process. The X-ray diffraction pattern of the as-deposited and hydrothermal treated films indicate nano-crystalline cubic spinel structure. The amorphous nature of the films is removed after hydrothermal treatment with decreased crystallite size. The field emission scanning electron micrographs showed merged columnar growth for as deposited films, which changes to well define columns after hydrothermal heating. The homogeneous cluster distribution is observed in surface view of the hydrothermal treated films. Hydrothermal treated films show merging of in-plane and out of plane magnetization plots (M(H whereas the M(H plots of as deposited films show angular dependence. The strong angular dependence is observed in the FMR spectra due to the presence of a uniaxial anisotropy in the films. The ferromagnetic interactions decrease in hydrothermal heated films due to the reduced shape anisotropy and crystallite size.

  3. City PLANTastic

    DEFF Research Database (Denmark)

    The city is going green. From New York to Copenhagen vegetables are enthusiastically planted on city squares, and buildings are turning green everywhere . The word “plant” is on everyone’s lips, reflecting a growing desire to solve ecological, technical and social challenges in the city. Hovever,...... and urbanism, who reflect upon the multiple roles of plants in the future city through their most recent projects. The theme for the 2012 World in Denmark conference is City PLANTastic, which will also be explored by researchers through their works....

  4. Electricity generation from hydrothermal vents

    Science.gov (United States)

    Aryadi, Y.; Rizal, I. S.; Fadhli, M. N.

    2016-09-01

    Hydrothermal vent is a kind of manifestation of geothermal energy on seabed. It produces high temperature fluid through a hole which has a diameter in various range between several inches to tens of meters. Hydrothermal vent is mostly found over ocean ridges. There are some 67000 km of ocean ridges, 13000 of them have been already studied discovering more than 280 sites with geothermal vents. Some of them have a thermal power of up to 60 MWt. These big potential resources of energy, which are located over subsea, have a constraint related to environmental impact to the biotas live around when it becomes an object of exploitation. Organic Rankine Cycle (ORC) is a method of exploiting heat energy to become electricity using organic fluid. This paper presents a model of exploitation technology of hydrothermal vent using ORC method. With conservative calculation, it can give result of 15 MWe by exploiting a middle range diameter of hydrothermal vent in deep of 2000 meters below sea level. The technology provided here really has small impact to the environment. With an output energy as huge as mentioned before, the price of constructing this technology is low considering the empty of cost for drilling as what it should be in conventional exploitation. This paper also presents the comparison in several equipment which is more suitable to be installed over subsea.

  5. HYDROTHERMAL CRACKING OF RESIDUAL OILS

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The hydrothermal cracking of heavy oils, such as Canadian oil sand bitumen and Arabian heavy vacuum residue, as well as their model compound were performed over sulfided Ni/Al2O3 and NiMo/Al2O3 catalysts under 663~703 K and 6.0~8.0 MPa of hydrogen pressure in a batch autoclave reactor. According to the reaction mechanism of hydrothermal cracking, a small amount of free redical initiators, such as di-tert-peroxide, sulfur, etc., was added into the feed to generate free redicals at lower temperature, and obviously showed promotional effect on the conversion of hydrocarbons. The reaction mechanisms of hydrothermal cracking as well as the enhancing effect of initiators were studied by a probe reaction with 1-phenyldodecane as a model compound. The hydrothermal cracking of hydrocarbon proceeded via free redical mechanism and hydrogenating quench. The initiators might easily generate free redicals under reaction temperature, these redicals might abstract H from hydrocarbon molecule and reasonably initiate the chain reactions, therefore, promote the conversion of hydrocarbon even at lower reaction temperature.

  6. Hydrothermal precipitation of artificial violarite

    DEFF Research Database (Denmark)

    Jørgensen, W. H.; Toftlund, H.; Warner, T. E.

    2012-01-01

    The nonstoichiometric nickel-ore mineral, violarite, (Ni,Fe)3S4 was prepared as a phase-pure fine powder by a comparatively quick hydrothermal method from an aqueous solution of iron(II) acetate, nickel(II) acetate and DL-penicillamine in an autoclave at 130 °C for 45 h. Powder-XRD showed that th...

  7. Hydrothermal activity in the Lau back-arc basin: Sulfides and water chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Fouquet, Y.; Charlou, J.L.; Donval, J.P.; Foucher, J.P. (Institut Francais de Recherche et d' Exploitation de la Mer, Plouzane (France)); von Stackelberg, U.; Wiedicke, M. (Bundesanstalt fur Geowissenschaften und Rohstoffe, Hannover (Germany)); Erzinger, J. (Justus-Liebig-Universitat, Giessen (Germany)); Herzig, P. (Rheinish-Westfalische Technische Hochschule, Aachen (Germany)); Muhe, R. (Universitat Kiel (Germany)); Soakai, S. (Ministry of Lands Survey and Natural Resources, Nuku' Alofa (Tonga)); Whitechurch, H. (Ecole et Observatoire de Physique du Globe de Strasbourg (France))

    1991-04-01

    The submersible Nautile completed 22 dives during the Nautilau cruise (R/V Nadir, April 17-May 10, 1989) for a detailed investigation of the southern Lau basin near Tonga. The objective of the scientific team from France, Germany, and Tonga was to understand the process of sea-floor ore formation associated with hydrothermal circulation along the Valu Fa back-arc ridge behind the Tonga-Kermadec trench. The four diving areas, between lat21{degree}25'S and 22{degree}40'S in water{approximately}2000 m deep, were selected on the basis of results from cruises of the R/V Jean Charcot and R/V Sonne. The Nadir cruise provided proof of hydrothermal activity-in all for areas, over more than 100 km-as indicated by the widespread occurence of hydrothermal deposits and by heat flow, conductivity, and temperature measurements near the sea bottom. The most spectacular findings were high-temperature white and black smokers and associated fauna and ore deposits. Hydrothermal water chemistry and sulfide composition data presented here indicate that this hydrothermal field is very different from the hydrothermal fields in oceanic ridges. This difference is seen in water chemistry of the hydrothermal fluid (pH=2 and high metal content) and the chemical composition of sulfides (enrichment in Ba, As, and Pb).

  8. Coupled cycling of Fe and organic carbon in submarine hydrothermal systems: Impacts on Ocean Biogeochemistry?

    Science.gov (United States)

    German, Christopher; Sander, Sylvia; Legendre, Louis; Niquil, Nathalie; Working Group 135

    2014-05-01

    Submarine hydrothermal venting was first discovered in the late 1970s. For decades the potential impact that vent-fluxes could have on global ocean budgets was restricted to consideration of processes in hydrothermal plumes in which the majority of chemical species are incorporated into polymetallic sulfide and/or oxyhydroxide particles close to the ridge-crest and sink to the underlying seafloor. This restricted view of the role that hydrothermal systems might play in global-ocean budgets has been challenged, more recently, by the recognition that there might also be a significant flux of dissolved Fe from hydrothermal systems to the oceans that is facilitated through thermodynamically stable nanoparticles and organic complexation. The latest results from the recently completed US GEOTRACES program, which has traced high concentrations of dissolved Fe over long distances off-axis from the Southern East Pacific Rise near 15°S, only help to confirm the potential that such fluxes might be important at the global scale. In this paper we review field-based and modeling results, including investigations that we have carried out under the auspices of SCOR-InterRidge Working Group 135, that reveal potential relationships between organic carbon (Corg) and Fe in hydrothermal plumes and allow us to investigate the roles that hydrothermal systems may play in the global biogeochemical cycles of both Fe and Corg. Using the particularly well-studied EPR 9N hydrothermal system as our "type locality" - even though we recognize that no one site can adequately represent the diversity of all hydrothermal systems worldwide - our modeling efforts allow us to reach some significant conclusions concerning: the predicted partitioning of heat fluxes between focused and diffuse flow at ridge axes; and the recognition that while Corg fluxes associated with hydrothermal plume removal may be small on the global scale, they are likely to result in extremely pronounced fluxes, locally, to the

  9. Medición de Campos Electromagnéticos en la Ciudad de Cali, Colombia Electromagnetic Field Measurement in the City of Cali, Colombia

    Directory of Open Access Journals (Sweden)

    Carlos R Pinedo

    2007-01-01

    Full Text Available En este artículo se presenta una metodología de medición del campo electromagnético producido por instalaciones de radio y telecomunicaciones y se presentan los resultados obtenidos en la evaluación de 50 sitios en la ciudad de Cali-Colombia. Este trabajo se originó por la preocupación pública causada por la proliferación de estaciones base de telefonía celular en el ámbito urbano y por los temores acerca de los posibles efectos nocivos de los campos electromagnéticos en la salud. La evaluación de los sitios se realizó con el propósito de conocer y cuantificar los niveles de campo electromagnético existentes en el medio ambiente de la ciudad. En general, los valores encontrados fueron inferiores al 0.5% del límite establecido por la Comisión Internacional para la Protección de las Radiaciones No Ionizantes, ICNIRP (0.2 mW/cm². Sin embargo, en dos casos los niveles encontrados superaron dicho límite.This paper shows a measurement methodology of the electromagnetic field produced by radio and telecommunications installations and presents results obtained in the evaluation of 50 measurement sites in the city of Cali in Colombia. This work was done because people’s concern about proliferation of radio base stations in urban areas, and their fear about the possible dangerous effects of the electromagnetic fields on human health. The evaluation was carried out to determine and quantify the levels of electromagnetic field that exist in the environment of the city. In general, the values found were lower than 0.5% of the limit established by the International Commission for Non-Ionizing Radiation Protection, ICNIRP (0.2 mW/cm². However, in two sites the measured values exceeded this limit.

  10. The geothermal field below the city of Berlin, Germany: Results from structurally and parametrically improved 3D Models

    Science.gov (United States)

    Frick, Maximilian; Sippel, Judith; Cacace, Mauro; Scheck-Wenderoth, Magdalena

    2016-04-01

    The goal of this study was to quantify the influence of the geological structure and geophysical parametrization of model units on the geothermal field as calculated by 3D numerical simulations of coupled fluid and heat transport for the subsurface of Berlin, Germany. The study area is located in the Northeast German Basin which is filled with several kilometers of sediments. This sedimentary infill includes the clastic sedimentary units Middle Buntsandstein and Sedimentary Rotliegend which are of particular interest for geothermal exploration. Previous studies conducted in the Northeast German Basin have already shown the geometries and properties of the geological units majorly control the distribution of subsurface temperatures. In this study we followed a two-step approach, where we first improved an existing structural model by integrating newly available 57 geological cross-sections, well data and deep seismics (down to ~4 km). Secondly, we performed a sensitivity analysis investigating the effects of varying physical fluid and rock properties on the subsurface temperature field. The results of this study show, that the structural configuration of model units exerts the highest influence on the geothermal field (up to ± 23 K at 1000 m below sea level). Here, the Rupelian clay aquitard, displaying a heterogeneous thickness distribution, locally characterized by hydrogeological windows (i.e. domains of no thickness) enabling intra-aquifer groundwater circulation has been identified as major controlling factor. The new structural configuration of this unit (more continuous, less numerous hydrogeological windows) also leads to a reduction of the influence of different boundary conditions and heat transport mechanisms considered. Additionally, the models results show that calculated temperatures highly depend on geophysical properties of model units whereas the hydraulic conductivity of the Cenozoic succession was identified as most dominant, leading to changes

  11. Air temperature field distribution estimations over a Chinese mega-city using MODIS land surface temperature data: the case of Shanghai

    Science.gov (United States)

    Ma, Weichun; Zhou, Liguo; Zhang, Hao; Zhang, Yan; Dai, Xiaoyan

    2016-03-01

    The capability of obtaining spatially distributed air temperature data from remote sensing measurements is an improvement for many environmental applications focused on urban heat island, carbon emissions, climate change, etc. This paper is based on the MODIS/Terra and Aqua data utilized to study the effect of the urban atmospheric heat island in Shanghai, China. The correlation between retrieved MODIS land surface temperature (LST) and air temperature measured at local weather stations was initially studied at different temporal and spatial scales. Secondly, the air temperature data with spatial resolutions of 250 m and 1 km were estimated from MODIS LST data and in-situ measured air temperature. The results showed that there is a slightly higher correlation between air temperature and MODIS LST at a 250m resolution in spring and autumn on an annual scale than observed at a 1 km resolution. Although the distribution pattern of the air temperature thermal field varies in different seasons, the urban heat island (UHI) in Shanghai is characterized by a distribution pattern of multiple centers, with the central urban area as the primary center and the built-up regions in each district as the subcenters. This study demonstrates the potential not only for estimating the distribution of the air temperature thermal field from MODIS LST with 250 m resolution in spring and autumn in Shanghai, but also for providing scientific and effective methods for monitoring and studying UHI effect in a Chinese mega-city such as Shanghai.

  12. 苏州市麦田草害现状及防除对策%Current Status and Control Strategies of Weeds in Wheat Field of Suzhou City

    Institute of Scientific and Technical Information of China (English)

    张国彪; 沈晴

    2014-01-01

    加重江苏省苏州市麦田杂草发生的原因包括免耕栽培的推广、稻草全量还田、草相变化、除草剂使用不科学等。要实现控草目标,必须坚持综合治理,立足“一封一杀”的化除策略并科学把好麦田化除技术关。%Weed problems in wheat field of Suzhou City have become more serious in association with changes in the cul -tural practices , including the promotion of no -tillage cultivation , leaving all the straw in the field from rotational rice crop, weed population shifts , and improper use of herbicides .For effective weed control , farmers should adhere to inte-grated practices based on prevention and management , including the judicious use of chemical methods available in wheat .

  13. Geochemical Energy for Catabolism and Anabolism in Hydrothermal Systems

    Science.gov (United States)

    Amend, J. P.; McCollom, T. M.; Bach, W.

    2008-12-01

    Chemically reduced deep-sea vent fluids mixed with oxidized seawater can generate redox disequilibria that serve as energy sources for chemolithoautotrophic (catabolism) and biomass synthesis (anabolism) reactions. Numerical models can be used to evaluate Gibbs energies of such processes on the early Earth and in present-day systems. Here, geochemical data from compositionally diverse vent fluids (Lost City, Rainbow, Logatchev, TAG, 21 °N EPR) are combined with several seawater chemistries to yield a wide range of mixed hydrothermal solutions; this is the starting point for our thermodynamic calculations. In ultramafic-hosted hydrothermal systems, such as Rainbow or Lost City, aerobic chemolithotrophic catabolisms (oxidation of H2, FeII, CH4) are the most energy-yielding at low temperatures (catabolic reaction energetics can then be used to put constraints on the amount of primary biomass production. Under putative early Earth conditions, for example, the net chemoautotrophic synthesis of cellular building blocks is thermodynamically most favorable at moderate temperatures (~50°C), where the energy contributions from HCO3- and H+ in cool seawater coupled to the reducing power in hot vent fluid are optimized. At these conditions, and counter to conventional wisdom, the synthesis of amino acids may even yield small amounts of energy.

  14. Sin City?

    DEFF Research Database (Denmark)

    Svarer, Michael; Gautier, Pieter A.; Teulings, Coen n.

    s moving to the countryside a credible commitment device for couples? We investigate whether lowering the arrival rate of potential alternative partners by moving to a less populated area lowers the dissolution risk for a sample of Danish couples. We find that of the couples who married in the city......, the ones who stay in the city have significant higher divorce rates. Similarly, for the couples who married outside the city, the ones who move to the city are more likely to divorce. This correlation can be explained by both a causal and a sorting effect. We disentangle them by using the timing...

  15. Eating Cities

    DEFF Research Database (Denmark)

    Mikkelsen, Bent Egberg; Fisker, Anna Marie; Clausen, Katja Seerup

    2016-01-01

    This paper analyzed the development of a city based sustainable food strategy for the city of Aalborg. It’s based on 3 cases of food service: food for the elderly as operated by the Municipality, food the hospital patients as operated by the region and food for defense staff as operated by the st......This paper analyzed the development of a city based sustainable food strategy for the city of Aalborg. It’s based on 3 cases of food service: food for the elderly as operated by the Municipality, food the hospital patients as operated by the region and food for defense staff as operated...

  16. Contributing recharge areas, groundwater travel time, and groundwater water quality of the Missouri River alluvial aquifer near the City of Independence, Missouri, well field, 1997-2008

    Science.gov (United States)

    Kelly, Brian P.

    2011-01-01

    The City of Independence, Missouri, operates a well field in the Missouri River alluvial aquifer. Contributing recharge areas (CRA) were last determined for the well field in 1996. Since that time, eight supply wells have been installed in the area north of the Missouri River and well pumpage has changed for the older supply wells. The change in pumping has altered groundwater flow and substantially changed the character of the CRA and groundwater travel times to the supply wells. The U.S Geological Survey, in a cooperative study with the City of Independence, Missouri, simulated steady-state groundwater flow for 2007 well pumpage, average annual river stage, and average annual recharge. Particle-tracking analysis was used to determine the CRA for supply wells and monitoring wells, and the travel time from recharge areas to supply wells, recharge areas to monitoring wells, and monitoring wells to supply wells. The simulated CRA for the well field is elongated in the upstream direction and extends to both sides of the Missouri River. Groundwater flow paths and recharge areas estimated for monitoring wells indicate the origin of water to each monitoring well, the travel time of that water from the recharge area, the flow path from the vicinity of each monitoring well to a supply well, and the travel time from the monitoring well to the supply well. Monitoring wells 14a and 14b have the shortest groundwater travel time from their contributing recharge area of 0.30 years and monitoring well 29a has the longest maximum groundwater travel time from its contributing recharge area of 1,701 years. Monitoring well 22a has the shortest groundwater travel time of 0.5 day to supply well 44 and monitoring well 3b has the longest maximum travel time of 31.91 years to supply well 10. Water-quality samples from the Independence groundwater monitoring well network were collected from 1997 to 2008 by USGS personnel during ongoing annual sampling within the 10-year contributing

  17. Hydraulic characterization of hydrothermally altered Nopal tuff

    Energy Technology Data Exchange (ETDEWEB)

    Green, R.T.; Meyer-James, K.A. [Southwest Research Institute, San Antonio, TX (United States); Rice, G. [George Rice and Associates, San Antonio, TX (United States)

    1995-07-01

    Understanding the mechanics of variably saturated flow in fractured-porous media is of fundamental importance to evaluating the isolation performance of the proposed high-level radioactive waste repository for the Yucca Mountain site. Developing that understanding must be founded on the analysis and interpretation of laboratory and field data. This report presents an analysis of the unsaturated hydraulic properties of tuff cores from the Pena Blanca natural analog site in Mexico. The basic intent of the analysis was to examine possible trends and relationships between the hydraulic properties and the degree of hydrothermal alteration exhibited by the tuff samples. These data were used in flow simulations to evaluate the significance of a particular conceptual (composite) model and of distinct hydraulic properties on the rate and nature of water flow.

  18. Zinc stannate nanostructures: hydrothermal synthesis

    Directory of Open Access Journals (Sweden)

    Sunandan Baruah and Joydeep Dutta

    2011-01-01

    Full Text Available Nanostructured binary semiconducting metal oxides have received much attention in the last decade owing to their unique properties rendering them suitable for a wide range of applications. In the quest to further improve the physical and chemical properties, an interest in ternary complex oxides has become noticeable in recent times. Zinc stannate or zinc tin oxide (ZTO is a class of ternary oxides that are known for their stable properties under extreme conditions, higher electron mobility compared to its binary counterparts and other interesting optical properties. The material is thus ideal for applications from solar cells and sensors to photocatalysts. Among the different methods of synthesizing ZTO nanostructures, the hydrothermal method is an attractive green process that is carried out at low temperatures. In this review, we summarize the conditions leading to the growth of different ZTO nanostructures using the hydrothermal method and delve into a few of its applications reported in the literature.

  19. Antarctic marine biodiversity and deep-sea hydrothermal vents.

    Science.gov (United States)

    Chown, Steven L

    2012-01-01

    The diversity of many marine benthic groups is unlike that of most other taxa. Rather than declining from the tropics to the poles, much of the benthos shows high diversity in the Southern Ocean. Moreover, many species are unique to the Antarctic region. Recent work has shown that this is also true of the communities of Antarctic deep-sea hydrothermal vents. Vent ecosystems have been documented from many sites across the globe, associated with the thermally and chemically variable habitats found around these, typically high temperature, streams that are rich in reduced compounds and polymetallic sulphides. The animal communities of the East Scotia Ridge vent ecosystems are very different to those elsewhere, though the microbiota, which form the basis of vent food webs, show less differentiation. Much of the biological significance of deep-sea hydrothermal vents lies in their biodiversity, the diverse biochemistry of their bacteria, the remarkable symbioses among many of the marine animals and these bacteria, and the prospects that investigations of these systems hold for understanding the conditions that may have led to the first appearance of life. The discovery of diverse and unusual Antarctic hydrothermal vent ecosystems provides opportunities for new understanding in these fields. Moreover, the Antarctic vents south of 60°S benefit from automatic conservation under the Convention on the Conservation of Antarctic Marine Living Resources and the Antarctic Treaty. Other deep-sea hydrothermal vents located in international waters are not protected and may be threatened by growing interests in deep-sea mining.

  20. Air Pollution by Hydrothermal Volcanism and Human Pulmonary Function

    Directory of Open Access Journals (Sweden)

    Diana Linhares

    2015-01-01

    Full Text Available The aim of this study was to assess whether chronic exposure to volcanogenic air pollution by hydrothermal soil diffuse degassing is associated with respiratory defects in humans. This study was carried in the archipelago of the Azores, an area with active volcanism located in the Atlantic Ocean where Eurasian, African, and American lithospheric plates meet. A cross-sectional study was performed on a study group of 146 individuals inhabiting an area where volcanic activity is marked by active fumarolic fields and soil degassing (hydrothermal area and a reference group of 359 individuals inhabiting an area without these secondary manifestations of volcanism (nonhydrothermal area. Odds ratio (OR and 95% confidence intervals (CIs were adjusted for age, gender, fatigue, asthma, and smoking. The OR for restrictive defects and for exacerbation of obstructive defects (COPD in the hydrothermal area was 4.4 (95% CI 1.78–10.69 and 3.2 (95% CI 1.82–5.58, respectively. Increased prevalence of restrictions and all COPD severity ranks (mild, moderate, and severe was observed in the population from the hydrothermal area. These findings may assist health officials in advising and keeping up with these populations to prevent and minimize the risk of respiratory diseases.

  1. The first microbiological contamination assessment by deep-sea drilling and coring by the D/V Chikyu at the Iheya North hydrothermal field in the Mid-Okinawa Trough (IODP Expedition 331

    Directory of Open Access Journals (Sweden)

    Katsunori eYanagawa

    2013-11-01

    Full Text Available During the Integrated Ocean Drilling Program (IODP Expedition 331 at the Iheya North hydrothermal system in the Mid-Okinawa Trough by the D/V Chikyu, we conducted microbiological contamination tests of the drilling and coring operations. The contamination from the drilling mud fluids was assessed using both perfluorocarbon tracers (PFT and fluorescent microsphere beads. PFT infiltration was detected from the periphery of almost all whole round cores. By contrast, fluorescent microspheres were not detected in hydrothermally active core samples, possibly due to thermal decomposition of the microspheres under high-temperature conditions. Microbial contamination from drilling mud fluids to the core interior subsamples was further characterized by molecular-based evaluation. The microbial 16S rRNA gene phylotype compositions in the drilling mud fluids were mainly composed of sequences of Beta- and Gammaproteobacteria, and Bacteroidetes and not archaeal sequences. The phylotypes that displayed more than 97% similarity to the sequences obtained from the drilling mud fluids were defined as possible contaminants in this study and were detected as minor components of the bacterial phylotype compositions in 13 of 37 core samples. The degree of microbiological contamination was consistent with that determined by the PFT and/or microsphere assessments. This study suggests a constructive approach for evaluation and eliminating microbial contamination during riser-less drilling and coring operations by the D/V Chikyu.

  2. The first microbiological contamination assessment by deep-sea drilling and coring by the D/V Chikyu at the Iheya North hydrothermal field in the Mid-Okinawa Trough (IODP Expedition 331).

    Science.gov (United States)

    Yanagawa, Katsunori; Nunoura, Takuro; McAllister, Sean M; Hirai, Miho; Breuker, Anja; Brandt, Leah; House, Christopher H; Moyer, Craig L; Birrien, Jean-Louis; Aoike, Kan; Sunamura, Michinari; Urabe, Tetsuro; Mottl, Michael J; Takai, Ken

    2013-01-01

    During the Integrated Ocean Drilling Program (IODP) Expedition 331 at the Iheya North hydrothermal system in the Mid-Okinawa Trough by the D/V Chikyu, we conducted microbiological contamination tests of the drilling and coring operations. The contamination from the drilling mud fluids was assessed using both perfluorocarbon tracers (PFT) and fluorescent microsphere beads. PFT infiltration was detected from the periphery of almost all whole round cores (WRCs). By contrast, fluorescent microspheres were not detected in hydrothermally active core samples, possibly due to thermal decomposition of the microspheres under high-temperature conditions. Microbial contamination from drilling mud fluids to the core interior subsamples was further characterized by molecular-based evaluation. The microbial 16S rRNA gene phylotype compositions in the drilling mud fluids were mainly composed of sequences of Beta- and Gammaproteobacteria, and Bacteroidetes and not archaeal sequences. The phylotypes that displayed more than 97% similarity to the sequences obtained from the drilling mud fluids were defined as possible contaminants in this study and were detected as minor components of the bacterial phylotype compositions in 13 of 37 core samples. The degree of microbiological contamination was consistent with that determined by the PFT and/or microsphere assessments. This study suggests a constructive approach for evaluation and eliminating microbial contamination during riser-less drilling and coring operations by the D/V Chikyu.

  3. U-Pb-Th geochronology of monazite and zircon in albitite metasomatites of the Rožňava-Nadabula ore field (Western Carpathians, Slovakia): implications for the origin of hydrothermal polymetallic siderite veins

    Science.gov (United States)

    Hurai, V.; Paquette, J.-L.; Lexa, O.; Konečný, P.; Dianiška, I.

    2015-10-01

    Sodic metasomatites (albitites) occur around and within siderite veins in the southern part of the Gemeric tectonic unit of the Western Carpathians. Accessory minerals of the metasomatites represented by monazite, zircon, apatite, rutile, tourmaline and siderite are basically identical with the quartz-tourmaline stage of other siderite and stibnite veins of the tectonic unit. Statistical analysis of chemical Th-U(total)-Pb isochron method (CHIME) of monazite dating yielded Jurassic-Cretaceous ages subdivided into 3-4 modes, spreading over time interval between 78 and 185 Ma. In contrast, LA-ICPMS 206Pb/238U dating carried out on the same monazite grains revealed a narrow crystallization interval, showing ages of Th-poor cores with phengite inclusions identical within the error limit with Th-rich rims with cauliflower-like structure. The determined lower intercept at 139 ± 1 Ma overlapped the Vallanginian-Berriasian boundary, thus corroborating the model of formation of hydrothermal vein structures within an arcuate deformation front built up in the Variscan basement as a response to Early Cretaceous compression, folding and thrusting. In contrast, associated zircons are considerably older than the surrounding Early-Palaeozoic volcano-sedimentary rocks, showing Neoproterozoic ages. The zircon grains in albitite metasomatites are thus interpreted as fragments of Pan-African magmatic detritus incorporated in the vein structures by buoyant hydrothermal fluids.

  4. SDS-assisted hydrothermal synthesis of porous CdIn2S4 microspheres

    Science.gov (United States)

    Bai, X. F.; Li, J. S.; Wu, W.

    2017-02-01

    The porous CdIn2S4 microspheres were synthesized via a sodium dodecyl sulfate (SDS)-assisted hydrothermal technology. The as-prepared CdIn2S4 products were characterized by X-ray diffraction, field emission scanning electron microscopy and UV-Vis diffusive reflectance spectroscopy. The results showed that hydrothermal time and the surfactant addition had great effect on the structure, morphology and optical property of CdIn2S4 products.

  5. Tectonic and Hydrothermal Activities in Debagh, Guelma Basin (Algeria

    Directory of Open Access Journals (Sweden)

    Said Maouche

    2013-01-01

    Full Text Available Quaternary and Pliocene travertines, deposited from hot springs, can reveal much about neotectonic and hydrothermal activity. The aim of this work is the understanding of the actual tectonic activity in the Guelma Basin and in one of its spa structures. Gravity data were collected during a field study in the Hammam Debagh (HD area and then analyzed to better highlight the architecture of its subsurface underlying structures. This analysis was performed by means of a Bouguer anomaly, upward continuations, and residual and derivative maps. Comparison of gravity maps, field geology, geomorphic observations, and structural maps allowed us to identify the major structural features in the Hammam Debagh. As a result, we confirm the position of the Hammam Debagh active fault which is superimposed to the hydrothermal active source in the NW-SE direction characterized by a negative gravity anomaly.

  6. Evolution evidence of a basic fluid to an acid based in the analysis of hydrothermal alteration of the geothermic field of the Azufres, Michoacan; Evidencias de evolucion de un fluido basico a acido a partir del analisis de la alteracion hidrotermal del campo geotermico de los Azufres, Michoacan

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez Partida, Eduardo [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)

    2000-07-01

    Hydrothermal alteration at the Los Azufres geothermal field is mostly composed of calc-silicate minerals that define a propylitic alteration zone, which shows progressive dehydration with depth and temperature increase. A generalized zoning of the calc-silicate zone can be observed, with zeolites in the upper part and epidote-clinozoisite at the deepest levels. An argillic alteration zone overlies the calc-silicate zone and is the dominant surface manifestation of the hydrothermal alteration. In some parts, there is a mineral assemblage composed of kaolinite-alunite-native sulfur-quartz (advanced argillic zone) formed by the interaction of vapor and shallow groundwater. The proto-fluid at the Los Azufres geothermal system is related to a neutral sodium chlorine brine, which favors deep propyllitic alteration (productive zone). This zone is characterized by secondary permeability due to fracturing. At depth the geothermal field is dominated by a pressurized liquid, yielding to vapor at more shallow zone. The gradual change from a liquid to a vapor phase occurs through boiling at depths between 1,200 and 1,500 m, and is accompanied by changes in the hydrothermal alteration mineralogy. The type of alteration passes from proylitic to argillic by means of an oxidation-acidification process, which includes the participation of a gas, particularly CO{sub 2}. Considering the physicochemical characteristic of the brine and the evolution of the paragenetic sequence, the Los Azufres geothermal field could de considered a model for hydrothermal behavior at ore deposits which develop by boiling and oxidation of low sulfidation fossil hydrothermal fluids. [Spanish] En el campo geotermico de Los Azufres la zona de alteracion hidrotermal esta formada en su mayor parte por calcosilicatos (que definen una zona paragenetica del tipo propilitico), los cuales muestran una deshidratacion progresiva conforme se va profundizando e incrementandose la temperatura. Se puede generalizar un

  7. Universities scale like cities.

    Directory of Open Access Journals (Sweden)

    Anthony F J van Raan

    Full Text Available Recent studies of urban scaling show that important socioeconomic city characteristics such as wealth and innovation capacity exhibit a nonlinear, particularly a power law scaling with population size. These nonlinear effects are common to all cities, with similar power law exponents. These findings mean that the larger the city, the more disproportionally they are places of wealth and innovation. Local properties of cities cause a deviation from the expected behavior as predicted by the power law scaling. In this paper we demonstrate that universities show a similar behavior as cities in the distribution of the 'gross university income' in terms of total number of citations over 'size' in terms of total number of publications. Moreover, the power law exponents for university scaling are comparable to those for urban scaling. We find that deviations from the expected behavior can indeed be explained by specific local properties of universities, particularly the field-specific composition of a university, and its quality in terms of field-normalized citation impact. By studying both the set of the 500 largest universities worldwide and a specific subset of these 500 universities--the top-100 European universities--we are also able to distinguish between properties of universities with as well as without selection of one specific local property, the quality of a university in terms of its average field-normalized citation impact. It also reveals an interesting observation concerning the working of a crucial property in networked systems, preferential attachment.

  8. Atypical Cities

    Science.gov (United States)

    DiJulio, Betsy

    2011-01-01

    In this creative challenge, Surrealism and one-point perspective combine to produce images that not only go "beyond the real" but also beyond the ubiquitous "imaginary city" assignment often used to teach one-point perspective. Perhaps the difference is that in the "atypical cities challenge," an understanding of one-point perspective is a means…

  9. Mercury accumulation in hydrothermal vent mollusks from the southern Tonga Arc, southwestern Pacific Ocean.

    Science.gov (United States)

    Lee, Seyong; Kim, Se-Joo; Ju, Se-Jong; Pak, Sang-Joon; Son, Seung-Kyu; Yang, Jisook; Han, Seunghee

    2015-05-01

    We provide the mercury (Hg) and monomethylmercury (MMHg) levels of the plume water, sulfide ore, sediment, and mollusks located at the hydrothermal vent fields of the southern Tonga Arc, where active volcanism and intense seismic activity occur frequently. Our objectives were: (1) to address the potential release of Hg from hydrothermal fluids and (2) to examine the distribution of Hg and MMHg levels in hydrothermal mollusks (mussels and snails) harboring chemotrophic bacteria. While high concentrations of Hg in the sediment and Hg, As, and Sb in the sulfide ore indicates that their source is likely hydrothermal fluids, the MMHg concentration in the sediment was orders of magnitude lower than the Hg (<0.001%). It suggests that Hg methylation may have not been favorable in the vent field sediment. In addition, Hg concentrations in the mollusks were much higher (10-100 times) than in other hydrothermal vent environments, indicating that organisms located at the Tonga Arc are exposed to exceedingly high Hg levels. While Hg concentration was higher in the gills and digestive glands than in the mantles and residues of snails and mussels, the MMHg concentrations in the gills and digestive glands were orders of magnitude lower (0.004-0.04%) than Hg concentrations. In summary, our results suggest that the release of Hg from the hydrothermal vent fields of the Tonga Arc and subsequent bioaccumulation are substantial, but not for MMHg.

  10. Hydrothermal Synthesis of Ni/Al Layered Double Hydroxide Nanorods

    OpenAIRE

    Yun Zhao; Fenfei Xiao; Qingze Jiao

    2011-01-01

    Ni/Al layered double hydroxide (LDH) nanorods were successfully synthesized by the hydrothermal reaction. The crystal structure of the products was characterized by X-ray diffraction (XRD). The morphology of the products was observed using transmission electron microscopy (TEM) and field emission scanning electron microscopy (SEM). The influences of reaction time and pH value on the morphology of the Ni/Al LDHs were investigated. The result showed that the well-crystallized nanorods of Ni/Al ...

  11. INSTANT CITY

    DEFF Research Database (Denmark)

    Marling, Gitte; Kiib, Hans

    2013-01-01

    experiments are taking place in ‘the instant city’, and how can it be characterized? It also emphasizes the relation between city life, urban design, and the aesthetics of architecture and urban spaces. The question here is, in what way architecture and urban scenography are used as tools to support the goal...... of an experimental and social en- gaged city environment? The analysis shows that the specific city life at the instant city, Roskilde Festival, can be characterized by being ‘open minded’, ‘playful’ and ‘inclusive’, but also by ‘a culture of laughter’ that penetrates the aesthetics and the urban scenography.......This article analyses Roskilde Festival as an Instant City. For more than 40 years, Roskilde Festival has had many thousands participants for a weeklong festival on music, performances and cultural experiences in a layout designed as an urban environment. During the last ten years, in- creasing...

  12. Hydrothermal sulfide accumulation along the Endeavour Segment, Juan de Fuca Ridge

    Science.gov (United States)

    Jamieson, J. W.; Clague, D. A.; Hannington, M. D.

    2014-06-01

    Hydrothermal sulfide deposits that form on the seafloor are often located by the detection of hydrothermal plumes in the water column, followed by exploration with deep-towed cameras, side-scan sonar imaging, and finally by visual surveys using remotely-operated vehicle or occupied submersible. Hydrothermal plume detection, however, is ineffective for finding hydrothermally-inactive sulfide deposits, which may represent a significant amount of the total sulfide accumulation on the seafloor, even in hydrothermally active settings. Here, we present results from recent high-resolution, autonomous underwater vehicle-based mapping of the hydrothermally-active Endeavour Segment of the Juan de Fuca Ridge, in the Northeast Pacific Ocean. Analysis of the ridge bathymetry resulted in the location of 581 individual sulfide deposits along 24 km of ridge length. Hydrothermal deposits were distinguished from volcanic and tectonic features based on the characteristics of their surface morphology, such as shape and slope angles. Volume calculations for each deposit results in a total volume of 372,500 m3 of hydrothermal sulfide-sulfate-silica material, for an equivalent mass of ∼1.2 Mt of hydrothermal material on the seafloor within the ridge's axial valley, assuming a density of 3.1 g/cm3. Much of this total volume is from previously undocumented inactive deposits outside the main active vent fields. Based on minimum ages of sulfide deposition, the deposits accumulated at a maximum rate of ∼400 t/yr, with a depositional efficiency (proportion of hydrothermal material that accumulates on the seafloor to the total amount hydrothermally mobilized and transported to the seafloor) of ∼5%. The calculated sulfide tonnage represents a four-fold increase over previous sulfide estimates for the Endeavour Segment that were based largely on accumulations from within the active fields. These results suggest that recent global seafloor sulfide resource estimates, which were based mostly

  13. In situ Remediation of Petroleum Contaminated Groundwater by Permeable Reactive Barrier with Hydrothermal Palygorskite as Medium

    Institute of Scientific and Technical Information of China (English)

    ZHANG Sheng-yu; ZHANG Yu-ling; SU Xiao-si; ZHANG Ying

    2013-01-01

    The permeable reactive barrier(PRB) has proven to be a cost-effective technique to remediate the petroleum contaminated groundwater at a northeast field site in China.In this study,the geology,hydrogeology and contamination characterization of the field site were investigated and the natural hydrothermal palygorskite was chosen as a reactive medium.Furthermore,the adsorption of the total petroleum hydrocarbons(TPH) in the groundwater onto hydrothermal palygorskite and the adsorption kinetics were investigated.The results indicate that the removal rates of TPH,benzene,naphthalene and phenantharene could all reach up to 90% by hydrothermal palygorskite with a diameter of 0.25-2.00 mm that had been thermally pretreated at 140 ℃.The adsorption of TPH onto hydrothermal palygorskite after pretreatment followed a pseudo-second-order kinetic model and a Langmuir adsorption isotherm,suggesting that the theoretic adsorption capacity of hydrothermal palygorskite for adsorbate could be 4.2 g/g.Scanning electron microscopy(SEM),infrared spectroscopy(IR),X-ray diffraction(XRD) and X-ray fluorescence spectroscopy(XRF) were carried out to analyze the adsorption mechanism.The results reveal that hydrothermal palygorskite is a fibrous silicate mineral enriched in Mg and A1 with large surface area and porosity.The dense cluster acicular and fibrous crystal of hydrothermal palygorskite,and its effect polar group —OH played an important role in the physical and chemical adsorption processes of it for contaminants.This study has demonstrated hydrothermal palygorskite is a reliable reactive medium for in situ remediation of petroleum contaminated groundwater at field sites.

  14. Solar power generation test project at Mitsui Greenland (Arao city, Kumamoto prefecture); Mitsui green land taiyoko hatsuden field test jigyo (Kumamotoken Araoshi)

    Energy Technology Data Exchange (ETDEWEB)

    Kurata, M.

    1997-05-30

    Described herein are results of the solar power generation field tests conducted in fiscal 1996 at Mitsui Greenland, an amusement park in City of Arao, Kumamoto pref., where the test system, connected to the low-voltage power transmission line, was installed in 1996. It has a capacity of 30kW, and is used as the power source for air-conditioning of the restaurants and driving kitchen appliances, with an array configuration of 6 series and 34 parallel, directed to the due south at the angle of incidence of 20deg. A variety of data have been collected to demonstrate system applicability and safety. It is installed on an inclined plane on a hill in the amusement park extending over a wide area of some 250ha, attracting attention of many visitors. It easily allows to learn new energy. The management dreams to construct the pioneer amusement park working on new types of energy by further installing wind power and fuel cell systems. Analysis of the data allows to improve solar batteries and concretely plan expansion of the system. The system is producing better results than expected with respect to, in particular, solar radiation intensity, cell output and inverter efficiency. Some 1.5 million visitors in a year feel importance and advantages of new energies of the near future, friendly to the global environments

  15. Air temperature field distribution estimations over a Chinese mega-city using MODIS land surface temperature data: the case of Shanghai

    Institute of Scientific and Technical Information of China (English)

    Weichun MA; Liguo ZHOU; Hao ZHANG; Yan ZHANG; Xiaoyan DAI

    2016-01-01

    The capability of obtaining spatially distributed air temperature data from remote sensing measurements is an improvement for many environmental applications focused on urban heat island,carbon emissions,climate change,etc.This paper is based on the MODIS/Terra and Aqua data utilized to study the effect of the urban atmospheric heat island in Shanghai,China.The correlation between retrieved MODIS land surface temperature (LST) and air temperature measured at local weather stations was initially studied at different temporal and spatial scales.Secondly,the air temperature data with spatial resolutions of 250 m and 1 km were estimated from MODIS LST data and in-situ measured air temperature.The results showed that there is a slightly higher correlation between air temperature and MODIS LST at a 250 m resolution in spring and autumn on an annual scale than observed at a 1 km resolution.Although the distribution pattern of the air temperature thermal field varies in different seasons,the urban heat island (UHI) in Shanghai is characterized by a distribution pattern of multiple centers,with the central urban area as the primary center and the built-up regions in each district as the subcenters.This study demonstrates the potential not only for estimating the distribution of the air temperature thermal field from MODIS LST with 250 m resolution in spring and autumn in Shanghai,but also for providing scientific and effective methods for monitoring and studying UHI effect in a Chinese mega-city such as Shanghai.

  16. Hydrothermal activity along the slow-spreading Lucky Strike ridge segment (Mid-Atlantic Ridge): Distribution, heatflux, and geological controls

    Science.gov (United States)

    Escartin, J.; Barreyre, T.; Cannat, M.; Garcia, R.; Gracias, N.; Deschamps, A.; Salocchi, A.; Sarradin, P. M.; Ballu, V.

    2015-12-01

    We have reviewed available visual information from the seafloor, and recently acquired microbathymetry for several traverses across the Lucky Strike segment to evaluate the distribution of hydrothermal activity. The Lucky Strike segment hosts three active hydrothermal fields: Capelinhos, Ewan, and the known Main Lucky Strike Hydrothermal Field (MLSHF). Capelinhos is located 1.3 km E of the axis and the MLSHF, and consists of a ~20 m sulfide mound with black smoker vents. Ewan is located ~1.8 km south from the MLSHF along the axial graben, and displays only diffuse flow along and around scarps of collapse structures associated with fault scarps. At the MLSHF we have identified an inactive site, thus broadening the extent of this field. Heat flux estimates from these new sites are relatively low and correspond to ~10% of the heat flux estimated for the Main field, with an integrated heatflux of 200-1200 MW. Overall, most of the flux (up to 80-90%) is associated with diffuse outflow, with the Ewan site showing solely diffuse flow and Capelinhos mostly focused flow. Microbathymetry also reveals a large, off-axis (~2.4 km) hydrothermal field, similar to the TAG mound in size, on the flanks of a rifted volcano. The association of these fields to a central volcano, and the absence of indicators of hydrothermal activity along the ridge segment, suggest that sustained hydrothermal activity is maintained by the enhanced melt supply and the associated magma chamber(s) required to build central volcanoes. Hydrothermal outflow zones at the seafloor are systematically controlled by faults, indicating that hydrothermal circulation in the shallow crust exploits permeable fault zones. Central volcanoes are thus associated with long-lived hydrothermal activity, and these sites may play a major role in the distribution and biogeography of vent communities.

  17. Influence of permeability on hydrothermal circulation in the sediment-buried oceanic crust

    Institute of Scientific and Technical Information of China (English)

    WANG Xingtao; ZHAI Shikui; MENG Fanshun; LI Huaiming; YU Zenghui; SUN Ge; XUE Gang

    2006-01-01

    Hydrothermal convection in the upper oceanic crust has been inferred to be a common and important process. Under the simplified conditions of planar boundaries, permeability provides a strong constraint on the pattern of circulation, the dimensions of convective cells and flow field of hydrothermal circulation. By applying an advanced numerical modeling method, to our knowledge, it is the first time to investigate convection as it is influenced by different strata permeability structures,formational anisotropy, fracture zone and cooling intrusion. The simplified geological model is composed of 3 layers, sedimentary layer, high permeable basement layer and low permeable basement layer from top to bottom. When permeability in high permeable layer is 10 times larger than that in sedimentary layer, convection occurs in high permeable layer. The pattern of hydrothermal circulation and flow velocity of hydrothermal fluid are strongly influenced by strata permeability structures,changes of permeability in high permeable basement layer, fracture zone and cooling intrusion.However, formational anisotropy relatively exerts weak influence on hydrothermal circulation, with the ratio up to 1.5 of vertical permeability to lateral permeability in high permeable layer. Fracture zone existing in basement is the most important factor affecting the circulation field. The effects of a local intrusion are limited to convection intensity above the intrusion and have little impact on the fluid flow on a regional scale. As the result of numerical modelling, key factors affecting the hydrothermal circulation are good permeable zone and long-term heat source, not including fluid source.

  18. Investigation of Icelandic rift zones reveals systematic changes in hydrothermal outflow in concert with seismic and magmatic events: Implications for investigation of Mid-Ocean Ridge hydrothermal systems

    Science.gov (United States)

    Curewitz, D.; Karson, J. A.

    2010-12-01

    Co-registration of several generations of geological data was carried out for hydrothermal fields along active rift zones of the Iceland plate boundary zone. Significant short- and long-term changes in vent locations, flow rates and styles, and fluid characteristics over short periods take place in concert with recorded earthquakes, dike intrusions, and fissure eruptions. Higher resolution, more detailed analysis of the Icelandic hydrothermal sites will inform investigation of similar data from mid-ocean ridge hydrothermal systems along the RIDGE 2000 focus sites. Initial results from the Hengill and Krafla geothermal areas covering a time-span of nearly 40 years at ~10 year intervals reveal limited changes in the surface expression of fault populations, with the exception of local fault and fracture systems. The location and population density of individual vents and groups of vents underwent significant changes over the same time period, with either vents shifting location, or new vents opening and old vents closing. Registration of changes in vent fluid temperatures, vent field ground temperatures, fluid flow rates, and vent eruptive styles reveal changes in hydrothermal flow systematics in concert with the observed changes in vent location and vent population density. Significant local seismic and volcanological events (earthquakes, earthquake swarms, dike intrusions, eruptions, inflation/deflation) that are potential triggers for the observed changes take place in intervening years between production of successive maps. Changes in modeled stress intensities and local fracture/fault density and geometry associated with these tectono-magmatic events correspond well to inferred locations of increased or decreased shallow permeability thought to control hydrothermal outflow behavior. Recent seismic events are strongly linked to well-mapped changes in fracture/fault population and hydrothermal flow behavior in the Hveragerdi region, near Hengill, and provide higher

  19. City Streets

    Data.gov (United States)

    Minnesota Department of Natural Resources — This data set contains roadway centerlines for city streets found on the USGS 1:24,000 mapping series. In some areas, these roadways are current through the 2000...

  20. Flying Cities

    DEFF Research Database (Denmark)

    Herbelin, Bruno; Lasserre, Sebastien; Ciger, Jan

    2008-01-01

    Flying Cities is an artistic installation which generates imaginary cities from the speech of its visitors. Thanks to an original interactive process analyzing people's vocal input to create 3D graphics, a tangible correspondence between speech and visuals opens new possibilities of interaction. ...... and a potential application. We believe that it could become a new medium for creativity, and a way to visually perceive a vocal performance in the context of the rehabilitation of people with reduced mobility or language impairments....

  1. Model cities

    OpenAIRE

    Batty, M.

    2007-01-01

    The term ?model? is now central to our thinking about how weunderstand and design cities. We suggest a variety of ways inwhich we use ?models?, linking these ideas to Abercrombie?sexposition of Town and Country Planning which represented thestate of the art fifty years ago. Here we focus on using models asphysical representations of the city, tracing the development ofsymbolic models where the focus is on simulating how functiongenerates form, to iconic models where the focus is on representi...

  2. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, M.; Davis, R.; Jones, S.

    2013-03-01

    This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

  3. CityGML - Interoperable semantic 3D city models

    Science.gov (United States)

    Gröger, Gerhard; Plümer, Lutz

    2012-07-01

    CityGML is the international standard of the Open Geospatial Consortium (OGC) for the representation and exchange of 3D city models. It defines the three-dimensional geometry, topology, semantics and appearance of the most relevant topographic objects in urban or regional contexts. These definitions are provided in different, well-defined Levels-of-Detail (multiresolution model). The focus of CityGML is on the semantical aspects of 3D city models, its structures, taxonomies and aggregations, allowing users to employ virtual 3D city models for advanced analysis and visualization tasks in a variety of application domains such as urban planning, indoor/outdoor pedestrian navigation, environmental simulations, cultural heritage, or facility management. This is in contrast to purely geometrical/graphical models such as KML, VRML, or X3D, which do not provide sufficient semantics. CityGML is based on the Geography Markup Language (GML), which provides a standardized geometry model. Due to this model and its well-defined semantics and structures, CityGML facilitates interoperable data exchange in the context of geo web services and spatial data infrastructures. Since its standardization in 2008, CityGML has become used on a worldwide scale: tools from notable companies in the geospatial field provide CityGML interfaces. Many applications and projects use this standard. CityGML is also having a strong impact on science: numerous approaches use CityGML, particularly its semantics, for disaster management, emergency responses, or energy-related applications as well as for visualizations, or they contribute to CityGML, improving its consistency and validity, or use CityGML, particularly its different Levels-of-Detail, as a source or target for generalizations. This paper gives an overview of CityGML, its underlying concepts, its Levels-of-Detail, how to extend it, its applications, its likely future development, and the role it plays in scientific research. Furthermore, its

  4. Hydrothermal Fe cycling and deep ocean organic carbon scavenging: Model-based evidence for significant POC supply to seafloor sediments

    Science.gov (United States)

    German, C. R.; Legendre, L. L.; Sander, S. G.; Niquil, N.; Luther, G. W.; Bharati, L.; Han, X.; Le Bris, N.

    2015-06-01

    Submarine hydrothermal venting has recently been identified to have the potential to impact ocean biogeochemistry at the global scale. This is the case because processes active in hydrothermal plumes are so vigorous that the residence time of the ocean, with respect to cycling through hydrothermal plumes, is comparable to that of deep ocean mixing caused by thermohaline circulation. Recently, it has been argued that seafloor venting may provide a significant source of bio-essential Fe to the oceans as the result of a close coupling between Fe and organic carbon in hydrothermal plumes. But a complementary question remains to be addressed: does this same intimate Fe-Corg association in hydrothermal plumes cause any related impact to the global C cycle? To address this, SCOR-InterRidge Working Group 135 developed a modeling approach to synthesize site-specific field data from the East Pacific Rise 9°50‧ N hydrothermal field, where the range of requisite data sets is most complete, and combine those inputs with global estimates for dissolved Fe inputs from venting to the oceans to establish a coherent model with which to investigate hydrothermal Corg cycling. The results place new constraints on submarine Fe vent fluxes worldwide, including an indication that the majority of Fe supplied to hydrothermal plumes should come from entrainment of diffuse flow. While this same entrainment is not predicted to enhance the supply of dissolved organic carbon to hydrothermal plumes by more than ∼10% over background values, what the model does indicate is that scavenging of carbon in association with Fe-rich hydrothermal plume particles should play a significant role in the delivery of particulate organic carbon to deep ocean sediments, worldwide.

  5. Coupled cycling of Fe and organic carbon in submarine hydrothermal systems: Modelling approach

    Science.gov (United States)

    Legendre, Louis; German, Christopher R.; Sander, Sylvia G.; Niquil, Nathalie

    2014-05-01

    It has been recently proposed that hydrothermal plumes may be a significant source of dissolved Fe to the oceans. In order to assess this proposal, we investigated the fate of dissolved Fe released from hydrothermal systems to the overlying ocean using an approach that combined modelling and field values. We based our work on a consensus conceptual model developed by members of SCOR-InterRidge Working Group 135. The model was both complex enough to capture the main processes of dissolved Fe released from hydrothermal systems and chemical transformation in the hydrothermal plume, and simple enough to be parameterized with existing field data. It included the following flows: Fe, water and heat in the high temperature vent fluids, in the fluids diffusing around the vent, and in the entrained seawater in the buoyant plume; Fe precipitation in polymetallic sulphides near the vent; transport of Fe in the non-buoyant plume, and both its precipitation in particles onto the sea bottom away from the vent and dissolution into deep-sea waters. In other words, there were three Fe input flows into the buoyant hydrothermal plume (vent-fluids; entrained diffuse flow; entrained seawater) and three Fe output flows (sedimentation from the buoyant plume as polymetallic sulfides; sedimentation from the non-buoyant plume in particulate form; export to the deep ocean in dissolved or nanoparticulate form). The output flows balanced the input flows. We transformed the conceptual model into equations, and parameterized these with field data. To do so, we assumed that all hydrothermal systems, globally, can be represented by the circumstances that prevail at the EPR 9°50'N hydrothermal field, although we knew this assumption not to be accurate. We nevertheless achieved, by following this approach, two important goals, i.e. we could assemble into a coherent framework, for the first time, several discrete data sets acquired independently over decades of field work, and we could obtain model

  6. Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

    Directory of Open Access Journals (Sweden)

    Yao Zhang

    Full Text Available To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4 concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4 was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4 concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

  7. Nitrogen-doped hydrothermal carbons

    Energy Technology Data Exchange (ETDEWEB)

    Titirici, Maria-Magdalena; White, Robin J. [Max-Planck-Institute of Colloids and Interfaces, Potsdam (Germany). Dept. of Colloid Chemistry; Zhao, Li [Max-Planck-Institute of Colloids and Interfaces, Potsdam (Germany). Dept. of Colloid Chemistry; National Center for Nanoscience and Technology, Beijing (China)

    2012-07-01

    Nitrogen doped carbon materials are now playing an important role in cutting edge innovations for energy conversion and storage technologies such as supercapacitors and proton exchange membrane fuel cells as well as in catalytic applications, adsorption and CO{sub 2} capture. The production of such materials using benign aqueous based processes, mild temperatures and renewable precursors is of great promise in addressing growing environmental concerns for cleaner power sources at a time of increasing global demand for energy. In this perspective, we show that nitrogen doped carbons prepared using sustainable processes such as ''Hydrothermal Carbonisation'' has advantages in many applications over the conventional carbons. We also summarize an array of synthetic strategies used to create such nitrogen doped carbons, and discuss the application of these novel materials. (orig.)

  8. Soft Cities

    DEFF Research Database (Denmark)

    Brix, Anders; Yoneda, Akira; Nakamura, Kiyoshi

    2015-01-01

    This paper presents a project exploring sustainable ways of urban living. The project renders a scenario comprised of an array of simple conversions of existing urban spaces and buildings, in the attempt to tie strategies ranging from urban planning to interior design into a coherent vision...... of a sustainable future. The project is the result of a joint research study between Denmark and Japan. Taking as its example the city of Kyoto, the project investigates some possible strategies on how cities more generally may be transformed into liveable, healthy and ecologically sensible environments....

  9. Fun City

    DEFF Research Database (Denmark)

    Once the blues guitarist B.B. King sang that when he "didn't wanna live no more", he would go shopping instead. Now, however, shopping has become a lifestyle... The city of today has become "Disneyfied" and "Tivolized". It has become a scene for events. The aim of the book is to encircle and pin...... down the consquences of these developments, to elocidate the interplay between funscapes and fear culture, and to account for the meaning of new concepts and new phenomena such as "event culture", "urban scenography", "experience economy","city branding" and "cultural planning"....

  10. City Branding

    DEFF Research Database (Denmark)

    Frimann, Søren; Stigel, Jørgen

    2006-01-01

    Succesful corporate branding requires that questions related to communication, publicity, and organizational structures are adressed. An uncritical adoption of approaches known from tradition product branding will inevitable give problems as the properties of tangible commodities and services......, problems seem to multiply in what has becom known as city branding. This analysis of the communicational aspects of two Danish provincial towns´ branding efforts examines both their internally and externally directed communication. It demonstrates that an insufficient understanding of - or willingness...... to face - these differences will inevitably hamper such branding efforts because of the consequential inconsistencies. Finally, paths to more effective city branding are indicated...

  11. Ecology of deep-sea hydrothermal vent communities: A review

    Science.gov (United States)

    Lutz, Richard A.; Kennish, Michael J.

    1993-08-01

    Studies of the many active and inactive hydrothermal vents found during the past 15 years have radically altered views of biological and geological processes in the deep sea. The biological communities occupying the vast and relatively stable soft bottom habitats of the deep sea are characterized by low population densities, high species diversity, and low biomass. In contrast, those inhabiting the generally unstable conditions of hydrothermal vent environments exhibit high densities and biomass, low species diversity, rapid growth rates, and high metabolic rates. Biological processes, such as rates of metabolism and growth, in vent organisms are comparable to those observed in organisms from shallow-water ecosystems. An abundant energy source is provided by chemosynthetic bacteria that constitute the primary producers sustaining the lush communities at the hydrothermal sites. Fluxes in vent flow and fluid chemistry cause changes in growth rates, reproduction, mortality, and/or colonization of vent fauna, leading to temporal and spatial variation of the vent communities. Vent populations that cannot adapt to modified flow rates are adversely affected, as is evidenced by high mortality or lower rates of colonization, growth, or reproduction. Substantial changes in biota have been witnessed at several vents, and successional cycles have been proposed for the Galapagos vent fields. Dramatic temporal and spatial variations in vent community structure may also relate to variations in larval dispersal and chance recruitment, as well as biotic interactions.

  12. Catastrophic volcanic collapse: relation to hydrothermal processes.

    Science.gov (United States)

    López, D L; Williams, S N

    1993-06-18

    Catastrophic volcanic collapse, without precursory magmatic activity, is characteristic of many volcanic disasters. The extent and locations of hydrothermal discharges at Nevado del Ruiz volcano, Colombia, suggest that at many volcanoes collapse may result from the interactions between hydrothermal fluids and the volcanic edifice. Rock dissolution and hydrothermal mineral alteration, combined with physical triggers such as earth-quakes, can produce volcanic collapse. Hot spring water compositions, residence times, and flow paths through faults were used to model potential collapse at Ruiz. Caldera dimensions, deposits, and alteration mineral volumes are consistent with parameters observed at other volcanoes.

  13. Origin of magnetic highs at ultramafic hosted hydrothermal systems: Insights from the Yokoniwa site of Central Indian Ridge

    Science.gov (United States)

    Fujii, Masakazu; Okino, Kyoko; Sato, Taichi; Sato, Hiroshi; Nakamura, Kentaro

    2016-05-01

    High-resolution vector magnetic measurements were performed on an inactive ultramafic-hosted hydrothermal vent field, called Yokoniwa Hydrothermal Field (YHF), using a deep-sea manned submersible Shinkai6500 and an autonomous underwater vehicle r2D4. The YHF has developed at a non-transform offset massif of the Central Indian Ridge. Dead chimneys were widely observed around the YHF along with a very weak venting of low-temperature fluids so that hydrothermal activity of the YHF was almost finished. The distribution of crustal magnetization from the magnetic anomaly revealed that the YHF is associated with enhanced magnetization, as seen at the ultramafic-hosted Rainbow and Ashadze-1 hydrothermal sites of the Mid-Atlantic Ridge. The results of rock magnetic analysis on seafloor rock samples (including basalt, dolerite, gabbro, serpentinized peridotite, and hydrothermal sulfide) showed that only highly serpentinized peridotite carries high magnetic susceptibility and that the natural remanent magnetization intensity can explain the high magnetization of Yokoniwa. These observations reflect abundant and strongly magnetized magnetite grains within the highly serpentinized peridotite. Comparisons with the Rainbow and Ashadze-1 suggest that in ultramafic-hosted hydrothermal systems, strongly magnetized magnetite and pyrrhotite form during the progression of hydrothermal alteration of peridotite. After the completion of serpentinization and production of hydrogen, pyrrhotites convert into pyrite or nonmagnetic iron sulfides, which considerably reduces their levels of magnetization. Our results revealed origins of the magnetic high and the development of subsurface chemical processes in ultramafic-hosted hydrothermal systems. Furthermore, the results highlight the use of near-seafloor magnetic field measurements as a powerful tool for detecting and characterizing seafloor hydrothermal systems.

  14. Antarctic marine biodiversity and deep-sea hydrothermal vents.

    Directory of Open Access Journals (Sweden)

    Steven L Chown

    2012-01-01

    Full Text Available The diversity of many marine benthic groups is unlike that of most other taxa. Rather than declining from the tropics to the poles, much of the benthos shows high diversity in the Southern Ocean. Moreover, many species are unique to the Antarctic region. Recent work has shown that this is also true of the communities of Antarctic deep-sea hydrothermal vents. Vent ecosystems have been documented from many sites across the globe, associated with the thermally and chemically variable habitats found around these, typically high temperature, streams that are rich in reduced compounds and polymetallic sulphides. The animal communities of the East Scotia Ridge vent ecosystems are very different to those elsewhere, though the microbiota, which form the basis of vent food webs, show less differentiation. Much of the biological significance of deep-sea hydrothermal vents lies in their biodiversity, the diverse biochemistry of their bacteria, the remarkable symbioses among many of the marine animals and these bacteria, and the prospects that investigations of these systems hold for understanding the conditions that may have led to the first appearance of life. The discovery of diverse and unusual Antarctic hydrothermal vent ecosystems provides opportunities for new understanding in these fields. Moreover, the Antarctic vents south of 60°S benefit from automatic conservation under the Convention on the Conservation of Antarctic Marine Living Resources and the Antarctic Treaty. Other deep-sea hydrothermal vents located in international waters are not protected and may be threatened by growing interests in deep-sea mining.

  15. 济南市孔隙裂隙地热田热储特征及开发利用模式探讨%Discussion on Characteristics and Exploitation and Utilization Model of Pore crack Geothermal Fields in Jinan City

    Institute of Scientific and Technical Information of China (English)

    尹秀贞; 胡松涛; 潘春光; 寇薇; 陆凯; 赵辉

    2014-01-01

    Based on geological conditions of pore crack geothermal field in Ji'nan city,on the basis of grasping basic situation of geothermal exploration in Jinan city,characteristics of pore crack geothermal fields in Jinan city have been introduced.It is regarded that buried depth of Guantao geothermal reservoir is moderate and water abundance is strong.It belongs to the medium low temperature geothermal reser-voir.It is the most suitable mining layer in fracture pore reservoir area in Ji'nan city.Dongying geothermal reservoir is deeply buried,the distribution is not stable,and some areas are lack water.The suitability of single well is poor.According to characteristics and regional advantages of geothermal fields,exploitation and utilization of geothermal resources have been studied.%以济南市孔隙裂隙地热田地质条件为背景,在全面掌握济南市地热勘查情况的基础上,论述了济南市孔隙裂隙热储特征,认为馆陶组热储埋深适中,富水性较强,属于中低温热储,是济南市孔隙裂隙热储层区最为适宜的开采层;而东营组热储层埋藏较深且分布不稳定,部分地区缺失,富水性较差,目前单独成井开采适宜性较差。并根据热储特征及区位优势,对地热资源开发利用模式进行了探讨。

  16. Sustainable Cities

    DEFF Research Database (Denmark)

    Georg, Susse; Garza de Linde, Gabriela Lucía

    /assessment tool. The context for our study is urban regeneration in one Danish city, which had been suffering from industrial decline and which is currently investing in establishing a “sustainable city”. Based on this case study we explore how the insights and inspiration evoked in working with the tool...

  17. Excite City

    DEFF Research Database (Denmark)

    Marling, Gitte; Kiib, Hans; Jensen, Ole B.

    This paper takes its point of departure in the pressure of the experience economy on European cities - a pressure which in recent years has found its expression in a number of comprehensive transformations of the physical and architectural environments, and new eventscapes related to fun and cult...

  18. Vacant city

    NARCIS (Netherlands)

    Marzot, N.

    2013-01-01

    Abandoned places that the crisis has multiplied, unaware wrecks of a project of civilization that has consumed its thrust and life-giving function, are waiting for new desirable interpretations, they are an expression of a possible city in opposition to the existing, even if not recognized by any in

  19. Sin City?

    NARCIS (Netherlands)

    Gautier, Pieter A.; Svarer, Michael; Teulings, Coen N.

    2007-01-01

    Is moving to the countryside a credible commitment device for couples? We investigate whether lowering the arrival rate of potential alternative partners by moving to a less populated area lowers the dissolution risk for a sample of Danish couples. We find that of the couples who married in the city

  20. Geochemistry of vent fluid particles formed during initial hydrothermal fluid–seawater mixing along the Mid-Atlantic Ridge

    OpenAIRE

    Klevenz, Verena; Bach, Wolfgang; Schmidt, Katja; Hentscher, Michael; Koschinsky, Andrea; Petersen, Sven

    2011-01-01

    We present geochemical data of black smoker particulates filtered from hydrothermal fluids with seawater-dilutions ranging from 0–99%. Results indicate the dominance of sulphide minerals (Fe, Cu, and Zn sulphides) in all samples taken at different hydrothermal sites on the Mid-Atlantic Ridge. Pronounced differences in the geochemistry of the particles between Logatchev I and 5°S hydrothermal fields could be attributed to differences in fluid chemistry. Lower metal/sulphur ratios (Me/H2S < 1) ...

  1. Simulation of groundwater flow, effects of artificial recharge, and storage volume changes in the Equus Beds aquifer near the city of Wichita, Kansas well field, 1935–2008

    Science.gov (United States)

    Kelly, Brian P.; Pickett, Linda L.; Hansen, Cristi V.; Ziegler, Andrew C.

    2013-01-01

    The Equus Beds aquifer is a primary water-supply source for Wichita, Kansas and the surrounding area because of shallow depth to water, large saturated thickness, and generally good water quality. Substantial water-level declines in the Equus Beds aquifer have resulted from pumping groundwater for agricultural and municipal needs, as well as periodic drought conditions. In March 2006, the city of Wichita began construction of the Equus Beds Aquifer Storage and Recovery project to store and later recover groundwater, and to form a hydraulic barrier to the known chloride-brine plume near Burrton, Kansas. In October 2009, the U.S. Geological Survey, in cooperation with the city of Wichita, began a study to determine groundwater flow in the area of the Wichita well field, and chloride transport from the Arkansas River and Burrton oilfield to the Wichita well field. Groundwater flow was simulated for the Equus Beds aquifer using the three-dimensional finite-difference groundwater-flow model MODFLOW-2000. The model simulates steady-state and transient conditions. The groundwater-flow model was calibrated by adjusting model input data and model geometry until model results matched field observations within an acceptable level of accuracy. The root mean square (RMS) error for water-level observations for the steady-state calibration simulation is 9.82 feet. The ratio of the RMS error to the total head loss in the model area is 0.049 and the mean error for water-level observations is 3.86 feet. The difference between flow into the model and flow out of the model across all model boundaries is -0.08 percent of total flow for the steady-state calibration. The RMS error for water-level observations for the transient calibration simulation is 2.48 feet, the ratio of the RMS error to the total head loss in the model area is 0.0124, and the mean error for water-level observations is 0.03 feet. The RMS error calculated for observed and simulated base flow gains or losses for the

  2. COVIS Detects Interconnections Between Atmospheric, Oceanic and Geologic systems at a Deep Sea Hydrothermal Vent

    Science.gov (United States)

    Bemis, K. G.; Xu, G.; Lee, R.

    2015-12-01

    COVIS (Cabled Observatory Vent Imaging Sonar) is an innovative sonar system designed to quantitatively monitor focused and diffuse flows from deep-sea hydrothermal vent clusters. From 9/2010 to 9/2015, COVIS was connected to the NEPTUNE observatory at Grotto vent in the Main Endeavour Field, JdFR. COVIS monitored plumes and diffuse discharge by transmitting high-frequency (200-400 kHz), pulsed acoustic waves and recording the backscattered signals to yield time series of plume heat and volume transports, plume bending, and diffuse flow area. Temporal variations indicate the rate of hydrothermal plume mixing with the ambient seawater increases with the magnitude of ocean currents. Such current-driven entrainment links the dynamics of a deep-sea hydrothermal plume with oceanic and atmospheric processes. We estimate the direction and relative amplitude of the local bottom currents from the bending angles of the plumes. A comparison with currents from an ADCP (~80 m south of Grotto) reveals significant complexity in the mean bottom flow structure within a hydrothermal vent field. Diffuse flow area, temperature, and faunal densities vary periodically reflecting some combination of tidal pressure and current interactions. The heat transport time series suggests the heat source driving the plume remained relatively steady for 41 months. Local seismic data reveals that increased heat transport in 2000 followed seismic events in 1999 and 2000 and the steady heat flux from 10/2011 to 2/2015 coincided with quiescent seismicity. Such a correlation points to the close linkage of a seafloor hydrothermal system with geological processes. These findings demonstrate the intimate interconnections of seafloor hydrothermal systems with processes spanning the Earth's interior to the sea surface. Further, they (and the time-series acquired by COVIS) testify to the effectiveness and robustness of employing an acoustic-imaging sonar for long-term monitoring of a seafloor hydrothermal

  3. Hydrothermal system of Long Valley caldera, California

    Energy Technology Data Exchange (ETDEWEB)

    Sorey, M.L.; Lewis, R.E.; Olmsted, F.H.

    1978-01-01

    The geologic and hydrologic setting of the hydrothermal system are described. The geochemical and thermal characteristics of the system are presented. A mathematical model of the Long Valley caldera is analyzed. (MHR)

  4. Dissolubility of Hydroxyapatite Powder under Hydrothermal Condition

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The dissolubility of hydroxyapatite(HA) in the hydrothermal solution was investigated in Morey-type autoclave over a temperature range of 150 to 350 ℃ and the pH value range of 5 to 9. It is shown that the dissolubility of HA is determined as a function of temperature and time under a constant filling ratio of autoclave, and the temperature coefficient for the solubility of HA is positive. The equilibrium time attained in the hydrothermal solution is shortened with the increase of hydrothermal temperature, and the effect of temperature on the solubility is obviously stronger than that of pH value. The solubility data suggest that HA has higher dissolubility in the HA-H2O system under the hydrothermal condition than that under the normal temperature-pressure.

  5. Research Review of the Archives Work Issues under the Visual Field of Smart City%智慧城市视野下档案工作问题研究综述

    Institute of Scientific and Technical Information of China (English)

    步尧

    2015-01-01

    智慧城市视野下档案工作问题研究中期刊文献多,档案学期刊作用突出;学科交叉率高,研究水平高;上升趋势温和,总体平稳;高产作者发表文献数量近半,高校研究成果明显,研究主题集中。研究问题包括:智慧城市建设中的档案工作、智慧档案、面向智慧城市的档案信息化、智慧城市背景下的档案信息资源开发与共建共享、融入智慧城市的档案服务、智慧城市与城建档案。%The journal articles are much more in the study of the problems of archives work under the visual field of the smart city, to discusse the periodical function prominently;High rate of interdisciplinarity, the research level is high;Mild rising trend, overall smooth; Prolific authors published literature nearly half number of significant research findings in colleges and universities, research focus. Research questions included: smart in the urban construction archives work, smart archives and the smart city under the background of archives informatization, smart city archives information re-sources co-construction and sharing, and develop into smart city archives service, the smart city and urban construction archives.

  6. Hydrothermal Manganese Mineralization Near the Samoan Hotspot

    Science.gov (United States)

    Hein, J. R.; Staudigel, H.; Koppers, A.; Hart, S. R.; Dunham, R.

    2006-12-01

    The thickest beds of hydrothermal manganese oxides recovered to date from the global ocean were collected from a volcanic cone in the south Pacific. In April 2005, samples were dredged aboard the R.V. Kilo Moana from a volcanic cone on the lower flank of Tulaga seamount (about 2,700 m water depth; 14° 39.222' S; 170° 1.730' W), located 115 km SW of Vailulu'u, the volcanically and hydrothermally active center of the Samoan hotspot. Additional hydrothermal manganese samples were collected off Ofu Island (dredge Alia 107), 72 km to the WSW of Vailulu'u. Manganese-oxide beds up to 9 cm thick are composed of birnessite and 10 Å manganates. Some layers consist of Mn-oxide columnar structures 4 cm long and 1 cm wide, which have not been described previously. The mean Mn and Fe contents of 18 samples are 51 weight percent and 0.76 weight percent, respectively. Elevated concentrations of Li (mean 0.11 wt. percent) are indicators of a hydrothermal origin, and distinguishes these samples, along with the high Mn and low Fe contents, from hydrogenetic Fe-Mn crusts. Other enriched elements include Ba (mean 0.14 percent), Cu (249 ppm), Mo (451 ppm), Ni (400 ppm), Zn (394 ppm), V (214 ppm), and W (132 ppm). Chondrite-normalized REE patterns show large negative Ce anomalies and LREE enrichments, both characteristic of hydrothermal Mn deposits. Small negative Eu anomalies are not typical of hydrothermal deposits and can be explained either by the absence of leaching of plagioclase by the hydrothermal fluids or by the precipitation of Eu-rich minerals, such as barite and anhydrite, at depth. The high base-metal contents indicate that sulfides are not forming deeper in the hydrothermal system or that such deposits are being leached by the ascending fluids. Textures of the thickest Mn deposits indicate that the Mn oxides formed below the seabed from ascending fluids during multiple phases of waxing and waning hydrothermal pulses. The deposits were later exposed at the seafloor by

  7. Hydrothermal industrialization: direct heat development. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1982-05-01

    A description of hydrothermal resources suitable for direct applications, their associated temperatures, geographic distribution and developable capacity are given. An overview of the hydrothermal direct-heat development infrastructure is presented. Development activity is highlighted by examining known and planned geothermal direct-use applications. Underlying assumptions and results for three studies conducted to determine direct-use market penetration of geothermal energy are discussed.

  8. Simulation of groundwater flow, effects of artificial recharge, and storage volume changes in the Equus Beds aquifer near the city of Wichita, Kansas well field, 1935–2008

    Science.gov (United States)

    Kelly, Brian P.; Pickett, Linda L.; Hansen, Cristi V.; Ziegler, Andrew C.

    2013-01-01

    The Equus Beds aquifer is a primary water-supply source for Wichita, Kansas and the surrounding area because of shallow depth to water, large saturated thickness, and generally good water quality. Substantial water-level declines in the Equus Beds aquifer have resulted from pumping groundwater for agricultural and municipal needs, as well as periodic drought conditions. In March 2006, the city of Wichita began construction of the Equus Beds Aquifer Storage and Recovery project to store and later recover groundwater, and to form a hydraulic barrier to the known chloride-brine plume near Burrton, Kansas. In October 2009, the U.S. Geological Survey, in cooperation with the city of Wichita, began a study to determine groundwater flow in the area of the Wichita well field, and chloride transport from the Arkansas River and Burrton oilfield to the Wichita well field. Groundwater flow was simulated for the Equus Beds aquifer using the three-dimensional finite-difference groundwater-flow model MODFLOW-2000. The model simulates steady-state and transient conditions. The groundwater-flow model was calibrated by adjusting model input data and model geometry until model results matched field observations within an acceptable level of accuracy. The root mean square (RMS) error for water-level observations for the steady-state calibration simulation is 9.82 feet. The ratio of the RMS error to the total head loss in the model area is 0.049 and the mean error for water-level observations is 3.86 feet. The difference between flow into the model and flow out of the model across all model boundaries is -0.08 percent of total flow for the steady-state calibration. The RMS error for water-level observations for the transient calibration simulation is 2.48 feet, the ratio of the RMS error to the total head loss in the model area is 0.0124, and the mean error for water-level observations is 0.03 feet. The RMS error calculated for observed and simulated base flow gains or losses for the

  9. Microwave-assisted hydrothermal synthesis of lead zirconate fine powders

    Directory of Open Access Journals (Sweden)

    Apinpus Rujiwatra

    2011-01-01

    Full Text Available A rapid synthesis of lead zirconate fine powders by microwave-assisted hydrothermal technique is reported. The influences of type of lead precursor, concentration of potassium hydroxide mineraliser, applied microwave power and irradiation time are described. The synthesised powders were characterised by powder X-ray diffraction, field emission scanning electron microscopy, energy-dispersive X-ray spectroscopic microanalysis and light scattering technique. The merits of the microwave application in reducing reaction time and improving particle mono-dispersion and size uniformity as well as the drawbacks, viz. low purity of the desired phase and increasing demand of mineraliser, are discussed in relation to conventional heating method.

  10. Discovery of new hydrothermal activity and chemosynthetic fauna on the Central Indian Ridge at 18°-20° S.

    Directory of Open Access Journals (Sweden)

    Kentaro Nakamura

    Full Text Available Indian Ocean hydrothermal vents are believed to represent a novel biogeographic province, and are host to many novel genera and families of animals, potentially indigenous to Indian Ocean hydrothermal systems. In particular, since its discovery in 2001, much attention has been paid to a so-called 'scaly-foot' gastropod because of its unique iron-sulfide-coated dermal sclerites and the chemosynthetic symbioses in its various tissues. Despite increasing interest in the faunal assemblages at Indian Ocean hydrothermal vents, only two hydrothermal vent fields have been investigated in the Indian Ocean. Here we report two newly discovered hydrothermal vent fields, the Dodo and Solitaire fields, which are located in the Central Indian Ridge (CIR segments 16 and 15, respectively. Chemosynthetic faunal communities at the Dodo field are emaciated in size and composition. In contrast, at the Solitaire field, we observed faunal communities that potentially contained almost all genera found at CIR hydrothermal environments to date, and even identified previously unreported taxa. Moreover, a new morphotype of 'scaly-foot' gastropod has been found at the Solitaire field. The newly discovered 'scaly-foot' gastropod has similar morphological and anatomical features to the previously reported type that inhabits the Kairei field, and both types of 'scaly-foot' gastropods genetically belong to the same species according to analyses of their COI gene and nuclear SSU rRNA gene sequences. However, the new morphotype completely lacks an iron-sulfide coating on the sclerites, which had been believed to be a novel feature restricted to 'scaly-foot' gastropods. Our new findings at the two newly discovered hydrothermal vent sites provide important insights into the biodiversity and biogeography of vent-endemic ecosystems in the Indian Ocean.

  11. Drone City

    DEFF Research Database (Denmark)

    Jensen, Ole B.

    2016-01-01

    This paper address the phenomenon of drones and their potential relationship with the city from the point of view of the so-called “mobilities turn”. This is done in such a way that turns attention to a recent redevelopment of the “turn” towards design; so the emerging perspective of “mobilities ...... of being mobile, as well as profoundly altering the process and perspective of data collection and feedback to governments, businesses and citizens.......This paper address the phenomenon of drones and their potential relationship with the city from the point of view of the so-called “mobilities turn”. This is done in such a way that turns attention to a recent redevelopment of the “turn” towards design; so the emerging perspective of “mobilities...... for a new urban condition where cities are networked and connected (as well as disconnected) from the local block to global digital spheres. In the midst of many of the well-known data-creating devices (e.g. Bluetooth, radio-frequency identification (RFID), GPS, smartphone applications) there is a “new kid...

  12. For the Smarter Good of Cities? On Cities, Complexity and Slippages in the Smart City Discourse’

    DEFF Research Database (Denmark)

    Steiner, Henriette; Veel, Kristin Eva Albrechtsen

    2013-01-01

    Summary: Cities for Smart Environmental and Energy Futures presents works written by eminent international experts from a variety of disciplines including architecture, engineering and related fields. Due to the ever-increasing focus on sustainable technologies, alternative energy sources......, and global social and urban issues, interest in the energy systems for cities of the future has grown in a wealth of disciplines. Some of the special features of this book include new findings on the city of the future from the macro to the micro level. These range from urban sustainability to indoor...... urbanism, and from strategies for cities and global climate change to material properties. The book is intended for graduate students and researchers active in architecture, engineering, the social and computational sciences, building physics and related fields....

  13. Hydrothermal plume anomalies along the Central Indian Ridge

    Institute of Scientific and Technical Information of China (English)

    ZHU Jian; LIN Jian; GUO ShiQin; CHEN YongShun

    2008-01-01

    Water column turbidity and temperature were investigated along the Central Indian Ridge (CIR) from 25°19'S to 23°48'S during a December 2005 cruise on board Chinese P/V DayangYihao.Measurements were made using NOAA's MAPR (Miniature Autonomous Plume Recorder) sensors during CTD casts,TV grabber operations,and tow-yo profiles,yielding the following results on hydrothermal plume anomalies:(1) Strong hydrothermal turbidity and temperature anomalies were recorded over the pre-viously discovered Kairei (25°19.2'S,70°02.4'E) and Edmond (23°52.7'S,69°35.8"E) vent fields,with the plume anomalies concentrated at depths of 2150-2300 m and 2700-2900 m,respectively.The maxi-mum height of the turbidity anomalies near the Kairei vent field recorded in December 2005 was slightly below 2100 m,which is consistent with the plume depth measured in June 2001,indicating that the Kairei plume may have maintained its buoyancy flux in the intervening 4.5 years.(2) The water column beneath the Kairei plume has background anomalies of about 0.005△NTU,whereas no such back-ground turbidity anomalies were observed below the Edmond hydrothermal plume.(3) No visible tur-bidity anomalies were detected from 24°42'S to 24°12'S including the Knorr Seamount.Thus 24°12'S marks the southern end of the hydrothermal plume.(4) Significant turbidity anomalies were observed at four individual sections from 24°12'S to 23°56'S at the depth of 2500-3000 m along the eastern rift valley wall.Whether the individual sections of anomalies are connected is still unknown due to the absence of data at the intervening gaps.If the four sections are connected with each other and are linked to the Edmond vent field farther to the north,the total along-axis length of the plume anomaly would be more than 37 km,implying a plume incidence value Ph of 0.38,greater than the predicted Ph of 0.21-0.25 based on the spreading rate of the Central Indian Ridge.

  14. Synthesis and Characterization of La(OH)3 Nanorods by Hydrothermal Microemulsion Method

    Institute of Scientific and Technical Information of China (English)

    Yi Dong YIN; Guang Yan HONG

    2005-01-01

    La(OH)3 nanorods with diameters of 20-40 nm and lengths of 200-300 nm were synthesized by a hydrothermal microemulsion method. The structure and morphology of the final products were characterized by X-ray powder diffraction (XRD), transmission electron microscopy(TEM), and field emission scanning electron microscope (FESEM).

  15. Wisdom City and“Wisdom Planning”-- Discuss the Conceptual Framework and Key Field of Planning of Urban and Rural under the View of Wisdom City%智慧城市与“智慧规划”--智慧城市视野下城乡规划展开研究的概念框架与关键领域探讨

    Institute of Scientific and Technical Information of China (English)

    熊雨箫

    2014-01-01

    目前,人类社会已经进入了信息化的高速发展时代。而信息化时代的到来,则为智慧城市的建设和发展提供了必要的条件。本文在对智慧城市理念进行介绍的基础上,对智慧城市中的城乡规划的概念框架与关键领域进行了研究与探讨。%At present, human society has entered the inf-ormation era with rapid development. The arrival of info-rmation age provides the necessary conditions to construct and develop the wisdom city. Based on the introduction to the concept of wisdom city, this paper studies and discusses conceptual framework and key field of planning of urban and rural under wisdom city.

  16. Web based hybrid volumetric visualisation of urban GIS data. Integration of 4D Temperature and Wind Fields with LoD-2 CityGML models

    Science.gov (United States)

    Congote, J.; Moreno, A.; Kabongo, L.; Pérez, J.-L.; San-José, R.; Ruiz, O.

    2012-10-01

    City models visualisation, buildings, structures and volumetric information, is an important task in Computer Graphics and Urban Planning. The different formats and data sources involved in the visualisation make the development of applications a big challenge. We present a homogeneous web visualisation framework using X3DOM and MEDX3DOM for the visualisation of these urban objects. We present an integration of different declarative data sources, enabling the utilization of advanced visualisation algorithms to render the models. It has been tested with a city model composed of buildings from the Madrid University Campus, some volumetric datasets coming from Air Quality Models and 2D layers wind datasets. Results show that the visualisation of all the urban models can be performed in real time on the Web. An HTML5 web interface is presented to the users, enabling real time modifications of visualisation parameters.

  17. [Body, disability, and stigma in the origins of the field of adapted sport in the city of Buenos Aires, 1950-1961: a mere interiorization of a devalued identity?].

    Science.gov (United States)

    Ferrante, Carolina

    2014-01-01

    Although adapted sport is considered the main integrator of people with disabilities, Disability Studies argues that it reinforces the oppression suffered by this group. However, these positions do not historically reconstruct the ethos constructed in sport. In order to contribute to this discussion, I analyze here the ways of thinking about and experiencing disability that were constructed in the origins of the field of adapted sport, in the city of Buenos Aires, from 1950 to 1961. Thus, I begin by analyzing the content of publications of the first clubs for people with disabilities and in-depth interviews with protagonists of the origins of adapted sport and local physiatry.

  18. Flying Cities

    DEFF Research Database (Denmark)

    Ciger, Jan

    2006-01-01

    of providing a tangible correspondence between the two spaces. This interaction mean has proved to suit the artistic expression well but it also aims at providing anyone with a pleasant and stimulating feedback from speech activity, a new medium for creativity and a way to visually perceive a vocal performance....... As the feedback we have received when presenting Flying Cities was very positive, our objective now is to cross the bridge between art and the potential applications to the rehabilitation of people with reduced mobility or for the treatment of language impairments....

  19. Phreatic and Hydrothermal Explosions: A Laboratory Approach

    Science.gov (United States)

    Scheu, B.; Dingwell, D. B.

    2010-12-01

    Phreatic eruptions are amongst the most common eruption types on earth. They might be precursory to another type of volcanic eruption but often they stand on their one. Despite being the most common eruption type, they also are one of the most diverse eruptions, in appearance as well as on eruption mechanism. Yet steam is the common fuel behind all phreatic eruptions. The steam-driven explosions occur when water beneath the ground or on the surface is heated by magma, lava, hot rocks, or fresh volcanic deposits (such as ignimbrites, tephra and pyroclastic-flow deposits) and result in crater, tuff rings and debris avalanches. The intense heat of such material may cause water to boil and flash to steam, thereby generating an explosion of steam, water, ash, blocks, and bombs. Another wide and important field affected by phreatic explosions are hydrothermal areas; here phreatic explosions occur every few months creating explosion craters and resemble a significant hazard to hydrothermal power plants. Despite of their hazard potential, phreatic explosions have so far been overlooked by the field of experimental volcanology. A part of their hazard potential in owned by the fact that phreatic explosions are hardly predictable in occurrence time and size as they have manifold triggers (variances in groundwater and heat systems, earthquakes, material fatigue, water level, etc..) A new set of experiments has been designed to focus on this phreatic type of steam explosion, whereas classical phreatomagmatic experiments use molten fuel-coolant interaction (e.g., Zimanowski, et al., 1991). The violent transition of the superheated water to vapour adds another degree of explosivity to the dry magmatic fragmentation, driven mostly by vesicle bursting due to internal gas overpressure. At low water fractions the fragmentation is strongly enforced by the mixture of these two effects and a large fraction of fine pyroclasts are produced, whereas at high water fraction in the sample the

  20. Peptide synthesis in early earth hydrothermal systems

    Science.gov (United States)

    Lemke, K.H.; Rosenbauer, R.J.; Bird, D.K.

    2009-01-01

    We report here results from experiments and thermodynamic calculations that demonstrate a rapid, temperature-enhanced synthesis of oligopeptides from the condensation of aqueous glycine. Experiments were conducted in custom-made hydrothermal reactors, and organic compounds were characterized with ultraviolet-visible procedures. A comparison of peptide yields at 260??C with those obtained at more moderate temperatures (160??C) gives evidence of a significant (13 kJ ?? mol-1) exergonic shift. In contrast to previous hydrothermal studies, we demonstrate that peptide synthesis is favored in hydrothermal fluids and that rates of peptide hydrolysis are controlled by the stability of the parent amino acid, with a critical dependence on reactor surface composition. From our study, we predict that rapid recycling of product peptides from cool into near-supercritical fluids in mid-ocean ridge hydrothermal systems will enhance peptide chain elongation. It is anticipated that the abundant hydrothermal systems on early Earth could have provided a substantial source of biomolecules required for the origin of life. Astrobiology 9, 141-146. ?? 2009 Mary Ann Liebert, Inc. 2009.

  1. Hydrothermal bitumen generated from sedimentary organic matter of rift lakes - Lake Chapala, Citala Rift, western Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Zarate del Valle, Pedro F. [Departamento de Quimica, Universidad de Guadalajara - CUCEI, Ap. Postal 4-021, Guadalajara, Jalisco CP 44410 (Mexico); Simoneit, Bernd R.T. [Environmental and Petroleum Geochemistry Group, College of Oceanic and Atmospheric Sciences, Oregon State University, Building 104, Corvallis, OR 97331-5503 (United States)]. E-mail: simoneit@coas.oregonstate.edu

    2005-12-15

    Lake Chapala is in the Citala Rift of western Mexico, which in association with the Tepic-Zacoalco and Colima Rifts, form the well-known neotectonic Jalisco continental triple junction. The rifts are characterized by evidence for both paleo- and active hydrothermal activity. At the south shore of the lake, near the Los Gorgos sublacustrine hydrothermal field, there are two tar emanations that appear as small islands composed of solid, viscous and black bitumen. Aliquots of tar were analyzed by GC-MS and the mixtures are comprised of geologically mature biomarkers and an UCM. PAH and n-alkanes are not detectable. The biomarkers consist mainly of hopanes, gammacerane, tricyclic terpanes, carotane and its cracking products, steranes, and drimanes. The biomarker composition and bulk C isotope composition ({delta} {sup 13}C = -21.4%) indicate an organic matter source from bacteria and algae, typical of lacustrine ecosystems. The overall composition of these tars indicates that they are hydrothermal petroleum formed from lacustrine organic matter in the deeper sediments of Lake Chapala exceeding 40 ka ({sup 14}C) in age and then forced to the lakebed by tectonic activity. The absence of alkanes and the presence of an UCM with mature biomarkers are consistent with rapid hydrothermal oil generation and expulsion at temperatures of 200-250 deg. C. The occurrence of hydrothermal petroleum in continental rift systems is now well known and should be considered in future energy resource exploration in such regions.

  2. Lithology and hydrothermal alteration determination from well logs for the Cerro Prieto Wells, Mexico

    Science.gov (United States)

    Ershaghi, I.; Ghaemian, S.; Abdassah, D.

    1981-10-01

    The characteristics of geophysical well logs are compared against the sand-shale series of the sedimentary column of the Cerro Prieto Geothermal Field, Mexico. It is shown that the changes in mineralogy of the rocks because of hydrothermal alteration are not easily detectable on the existing logs. However, if the behavior of clay minerals alone is monitored, the onset of the hydrothermally altered zones may be estimated from the well logs. The effective concentration of clay-exchange cations, Q/sub v/, is computed using the data available from conventional well logs. Zones indicating the disappearance of low temperature clays are considered hydrothermally altered formations with moderate to high permeability and temperature, and suitable for completion purposes.

  3. Influence of Hydrothermal Temperature on Phosphorus Recovery Efficiency of Porous Calcium Silicate Hydrate

    Directory of Open Access Journals (Sweden)

    Wei Guan

    2013-01-01

    Full Text Available Porous calcium silicate hydrate (PCSH was synthesized by carbide residue and white carbon black. The influence of hydrothermal temperature on phosphorus recovery efficiency was investigated by Field Emission Scanning Electron Microscopy (FESEM, Brunauer-Emmett-Teller (BET, and X-Ray Diffraction (XRD. Hydrothermal temperature exerted significant influence on phosphorus recovery performance of PCSH. Hydrothermal temperature 170°C for PCSH was more proper to recover phosphorus. PCSH could recover phosphorus with content of 18.51%. The law of Ca2+ and OH− release was the key of phosphorus recovery efficiency, and this law depended upon the microstructure of PCSH. When the temperature of synthesis reached to 170°C, the reactions between CaO and amorphous SiO2 were more efficient. Solubility of SiO2 was a limiting factor.

  4. A Palaeoproterozoic multi-stage hydrothermal alteration system at Nalunaq gold deposit, South Greenland

    Science.gov (United States)

    Bell, Robin-Marie; Kolb, Jochen; Waight, Tod Earle; Bagas, Leon; Thomsen, Tonny B.

    2017-03-01

    Nalunaq is an orogenic, high gold grade deposit situated on the Nanortalik Peninsula, South Greenland. Mineralisation is hosted in shear zone-controlled quartz veins, located in fine- and medium-grained amphibolite. The deposit was the site of Greenland's only operating metalliferous mine until its closure in 2014, having produced 10.67 t of gold. This study uses a combination of field investigation, petrography and U/Pb zircon and titanite geochronology to define a multi-stage hydrothermal alteration system at Nalunaq. A clinopyroxene-plagioclase-garnet(-sulphide) alteration zone (CPGZ) developed in the Nanortalik Peninsula, close to regional peak metamorphism and prior to gold-quartz vein formation. The ca. 1783-1762-Ma gold-quartz veins are hosted in reactivated shear zones with a hydrothermal alteration halo of biotite-arsenopyrite-sericite-actinolite-pyrrhotite(-chlorite-plagioclase-löllingite-tourmaline-titanite), which is best developed in areas of exceptionally high gold grades. Aplite dykes dated to ca. 1762 Ma cross-cut the gold-quartz veins, providing a minimum age for mineralisation. A hydrothermal calcite-titanite alteration assemblage is dated to ca. 1766 Ma; however, this alteration is highly isolated, and as a result, its field relationships are poorly constrained. The hydrothermal alteration and mineralisation is cut by several generations of ca. 1745-Ma biotite granodiorite accompanied by brittle deformation. A ca. 1745-Ma lower greenschist facies hydrothermal epidote-calcite-zoisite alteration assemblage with numerous accessory minerals forms halos surrounding the late-stage fractures. The contrasting hydrothermal alteration styles at Nalunaq indicate a complex history of exhumation from amphibolite facies conditions to lower greenschist facies conditions in an orogenic belt which resembles modern Phanerozoic orogens.

  5. A Palaeoproterozoic multi-stage hydrothermal alteration system at Nalunaq gold deposit, South Greenland

    Science.gov (United States)

    Bell, Robin-Marie; Kolb, Jochen; Waight, Tod Earle; Bagas, Leon; Thomsen, Tonny B.

    2016-07-01

    Nalunaq is an orogenic, high gold grade deposit situated on the Nanortalik Peninsula, South Greenland. Mineralisation is hosted in shear zone-controlled quartz veins, located in fine- and medium-grained amphibolite. The deposit was the site of Greenland's only operating metalliferous mine until its closure in 2014, having produced 10.67 t of gold. This study uses a combination of field investigation, petrography and U/Pb zircon and titanite geochronology to define a multi-stage hydrothermal alteration system at Nalunaq. A clinopyroxene-plagioclase-garnet(-sulphide) alteration zone (CPGZ) developed in the Nanortalik Peninsula, close to regional peak metamorphism and prior to gold-quartz vein formation. The ca. 1783-1762-Ma gold-quartz veins are hosted in reactivated shear zones with a hydrothermal alteration halo of biotite-arsenopyrite-sericite-actinolite-pyrrhotite(-chlorite-plagioclase-löllingite-tourmaline-titanite), which is best developed in areas of exceptionally high gold grades. Aplite dykes dated to ca. 1762 Ma cross-cut the gold-quartz veins, providing a minimum age for mineralisation. A hydrothermal calcite-titanite alteration assemblage is dated to ca. 1766 Ma; however, this alteration is highly isolated, and as a result, its field relationships are poorly constrained. The hydrothermal alteration and mineralisation is cut by several generations of ca. 1745-Ma biotite granodiorite accompanied by brittle deformation. A ca. 1745-Ma lower greenschist facies hydrothermal epidote-calcite-zoisite alteration assemblage with numerous accessory minerals forms halos surrounding the late-stage fractures. The contrasting hydrothermal alteration styles at Nalunaq indicate a complex history of exhumation from amphibolite facies conditions to lower greenschist facies conditions in an orogenic belt which resembles modern Phanerozoic orogens.

  6. Branding Cities, Changing Societies

    DEFF Research Database (Denmark)

    Ooi, Can-Seng

    Societal changes are seldom discussed in the literature on city branding. The time element is important because it highlights the fluctuating reality of society. The city brand message freezes the place but in fact, the city branding exercise is a continuous process. Society emerges too. City...... brands are supposed to accentuate the uniqueness of the city, be built from the bottom-up and reflect the city's identity. This paper highlights three paradoxes, pointing out that city branding processes can also make cities more alike, bring about societal changes and forge new city identities. A city...... branding campaign does not just present the city, it may change the city. The relationships between the branding exercise and the city are intertwined in the evolution of the place....

  7. Learning Cities as Healthy Green Cities: Building Sustainable Opportunity Cities

    Science.gov (United States)

    Kearns, Peter

    2012-01-01

    This paper discusses a new generation of learning cities we have called EcCoWell cities (Economy, Community, Well-being). The paper was prepared for the PASCAL International Exchanges (PIE) and is based on international experiences with PIE and developments in some cities. The paper argues for more holistic and integrated development so that…

  8. Hydrothermal treatment of electric arc furnace dust.

    Science.gov (United States)

    Yu, Bing-Sheng; Wang, Yuh-Ruey; Chang, Tien-Chin

    2011-06-15

    In this study, ZnO crystals were fabricated from electric arc furnace dust (EAFD) after alkaline leaching, purification and hydrothermal treatment. The effects of temperature, duration, pH, and solid/liquid ratio on ZnO crystal morphology and size were investigated. Results show a high reaction temperature capable of accelerating the dissolution of ZnO precursor, expediting the growth of 1D ZnO, and increasing the L/D ratio in the temperature range of 100-200°C. ZnO crystals with high purity can also be obtained, using the one-step hydrothermal treatment with a baffle that depends on the different solubility of zincite and franklinite in the hydrothermal conditions.

  9. Characterization of advanced preprocessed materials (Hydrothermal)

    Energy Technology Data Exchange (ETDEWEB)

    Rachel Emerson; Garold Gresham

    2012-09-01

    The initial hydrothermal treatment parameters did not achieve the proposed objective of this effort; the reduction of intrinsic ash in the corn stover. However, liquid fractions from the 170°C treatments was indicative that some of the elements routinely found in the ash that negatively impact the biochemical conversion processes had been removed. After reviewing other options for facilitating ash removal, sodium-citrate (chelating agent) was included in the hydrothermal treatment process, resulting in a 69% reduction in the physiological ash. These results indicated that chelation –hydrothermal treatment is one possible approach that can be utilized to reduce the overall ash content of feedstock materials and having a positive impact on conversion performance.

  10. Production of biofuels via hydrothermal conversion

    DEFF Research Database (Denmark)

    Biller, Patrick; Ross, Andrew

    2016-01-01

    Hydrothermal processing has evolved as an alternative processing technology for wet biomass and waste materials in recent years. Using hot-compressed water as a reaction medium at temperatures of 200–500°C, materials with increased energy density can be obtained. The technology is particularly......). Each of these hydrothermal routes results in energy densification by removal of oxygen to produce hydrochar (HTC), biocrude (HTL), or syngas (HTG). The process chemistry and reactions in hydrothermal media are described for each process. Suitable feedstocks and their considerations are reviewed...... as the quality of targeted biofuel is a function of feedstock and operating conditions. The quality of hydrochar influences its uses as a solid fuel while biocrude quality affects its use as a liquid fuel and feedstock for upgrading to drop-in replacement fuels, while HTG produces a syngas rich in either H2...

  11. Hydrothermal processing of radioactive combustible waste

    Energy Technology Data Exchange (ETDEWEB)

    Worl, L.A.; Buelow, S.J.; Harradine, D.; Le, L.; Padilla, D.D.; Roberts, J.H.

    1998-09-01

    Hydrothermal processing has been demonstrated for the treatment of radioactive combustible materials for the US Department of Energy. A hydrothermal processing system was designed, built and tested for operation in a plutonium glovebox. Presented here are results from the study of the hydrothermal oxidation of plutonium and americium contaminated organic wastes. Experiments show the destruction of the organic component to CO{sub 2} and H{sub 2}O, with 30 wt.% H{sub 2}O{sub 2} as an oxidant, at 540 C and 46.2 MPa. The majority of the actinide component forms insoluble products that are easily separated by filtration. A titanium liner in the reactor and heat exchanger provide corrosion resistance for the oxidation of chlorinated organics. The treatment of solid material is accomplished by particle size reduction and the addition of a viscosity enhancing agent to generate a homogeneous pumpable mixture.

  12. Depolymerization of sulfated polysaccharides under hydrothermal conditions.

    Science.gov (United States)

    Morimoto, Minoru; Takatori, Masaki; Hayashi, Tetsuya; Mori, Daiki; Takashima, Osamu; Yoshida, Shinichi; Sato, Kimihiko; Kawamoto, Hitoshi; Tamura, Jun-ichi; Izawa, Hironori; Ifuku, Shinsuke; Saimoto, Hiroyuki

    2014-01-30

    Fucoidan and chondroitin sulfate, which are well known sulfated polysaccharides, were depolymerized under hydrothermal conditions (120-180°C, 5-60min) as a method for the preparation of sulfated polysaccharides with controlled molecular weights. Fucoidan was easily depolymerized, and the change of the molecular weight values depended on the reaction temperature and time. The degree of sulfation and IR spectra of the depolymerized fucoidan did not change compared with those of untreated fucoidan at reaction temperatures below 140°C. However, fucoidan was partially degraded during depolymerization above 160°C. Nearly the same depolymerization was observed for chondroitin sulfate. These results indicate that hydrothermal treatment is applicable for the depolymerization of sulfated polysaccharides, and that low molecular weight products without desulfation and deformation of the initial glycan structures can be obtained under mild hydrothermal conditions.

  13. Hydrothermally reduced graphene oxide as a supercapacitor

    Science.gov (United States)

    Johra, Fatima Tuz; Jung, Woo-Gwang

    2015-12-01

    The supercapacitance behavior of hydrothermally reduced graphene oxide (RGO) was investigated for the first time. The capacitive behavior of RGO was characterized by using cyclic voltammetry and galvanostatic charge-discharge methods. The specific capacitance of hydrothermally reduced RGO at 1 A/g was 367 F/g in 1 M H2SO4 electrolyte, which was higher than that of RGO synthesized via the hydrazine reduction method. The RGO-modified glassy carbon electrode showed excellent stability. After 1000 cycles, the supercapacitance was 107.7% of that achieved in the 1st cycle, which suggests that RGO has excellent electrochemical stability as a supercapacitor electrode material. The energy density of hydrothermal RGO reached 44.4 W h/kg at a power density of 40 kW/kg.

  14. The BGU/CERN solar hydrothermal reactor

    CERN Document Server

    Bertolucci, Sergio; Caspers, Fritz; Garb, Yaakov; Gross, Amit; Pauletta, Stefano

    2014-01-01

    We describe a novel solar hydrothermal reactor (SHR) under development by Ben Gurion University (BGU) and the European Organization for Nuclear Research CERN. We describe in broad terms the several novel aspects of the device and, by extension, of the niche it occupies: in particular, enabling direct off-grid conversion of a range of organic feedstocks to sterile useable (solid, liquid) fuels, nutrients, products using only solar energy and water. We then provide a brief description of the high temperature high efficiency panels that provide process heat to the hydrothermal reactor, and review the basics of hydrothermal processes and conversion taking place in this. We conclude with a description of a simulation of the pilot system that will begin operation later this year.

  15. Near-bottom magnetic surveys around hydrothermal sites in the southern Mariana Trough

    Science.gov (United States)

    Nogi, Y.; Mochizuki, N.; Okino, K.; Asada, M.

    2011-12-01

    Near-bottom magnetic survey is an effective method to reveal detailed magnetic anomaly features of seafloor. The measurements of three-components of the geomagnetic field by using AUV "URASHIMA" were conducted during the YK-09-08 cruise in the southern Mariana Trough in order to detect signals of hydrothermally altered rocks. During the cruise, vector geomagnetic field are successfully obtained along the all dive tracks with the information of the vehicle's attitude. Total intensities of geomagnetic field by the overhauser magnetometer were also conducted, but the data are only collected along almost E-W oriented observation lines due to the sensitivity of the sensor. The distribution of crustal magnetization are estimated using downward component of magnetic anomalies by the inversion method. The distribution of low crustal magnetization are almost coincide with the area around hydrothermal vent sites from on ridge to off ridge area, and most likely indicate signs of hydrothermally altered rocks. The distribution of low crustal magnetization on ridge are almost parallel to the the strike of ridge axis implying tectonic control of hydrothermal vent sites.

  16. The influence of isotropic and anisotropic crustal permeability on hydrothermal flow at fast spreading ridges

    Science.gov (United States)

    Hasenclever, Jörg; Rüpke, Lars; Theissen-Krah, Sonja; Morgan, Jason

    2016-04-01

    We use 3-D numerical models of hydrothermal fluid flow to assess the magnitude and spatial distribution of hydrothermal mass and energy fluxes within the upper and lower oceanic crust. A better understanding of the hydrothermal flow pattern (e.g. predominantly on-axis above the axial melt lens vs. predominantly off-axis and ridge-perpendicular over the entire crustal thickness) is essential for quantifying the volume of oceanic crust exposed to high-temperature fluid flow and the associated leaching and redistribution of economically interesting metals. The initial setup of all 3-D models is based on our previous 2-D studies (Theissen-Krah et al., 2011), in which we have coupled numerical models for crustal accretion and hydrothermal fluid flow. One result of these 2-D calculations is a crustal permeability field that leads to a thermal structure in the crust that matches seismic tomography data at the East Pacific Rise. Our reference 3-D model for hydrothermal flow at fast-spreading ridges predicts the existence of a hybrid hydrothermal system (Hasenclever et al., 2014) with two interacting flow components that are controlled by different physical mechanisms. Shallow on-axis flow structures develop owing to the thermodynamic properties of water, whereas deeper off-axis flow is strongly shaped by crustal permeability, particularly the brittle-ductile transition. About ˜60% of the discharging fluid mass is replenished on-axis by warm (up to 300oC) recharge flow surrounding the hot thermal plumes. The remaining ˜40%, however, occurs as colder and broader recharge up to several kilometres away from the ridge axis that feeds hot (500-700oC) deep off-axis flow in the lower crust towards the ridge. Both flow components merge above the melt lens to feed ridge-centred vent sites. In a suite of 3-D model calculations we vary the isotropic crustal permeability to quantify its influence on on-axis vs. off-axis hydrothermal fluxes as well as on along-axis hydrothermal

  17. Hydrothermal Synthesis and Field Emission Performance of Single Crystalline TiO2 Nanowires Bundle Arrays%单晶TiO2纳米线束阵列的水热合成及场发射性能研究

    Institute of Scientific and Technical Information of China (English)

    葛增娴; 刘俊; 魏爱香; 赵旺

    2011-01-01

    Vertically aligned single-crystalline TiO2 nanowire bundles array were synthesized on transparent conductive fluorine-doped tin oxide (FTO) substrates by hydrothermal method using tetrabutyl titanate and hydrochloric acid as precursors. The nanowire bundles have flat tetragonal crystallographic planes with the section of 100-200 nm and the length of 3 μm. HRTEM indicate that each nanowire bundle is composed of 20-40 tiny nanowires. The tiny nanowires have the diameter of 4-6 nm. Field emission results of the TiO2 nanowire bundles show a turn-on field of 5.7 V/μm at a current density of 10 μA/cm2. The threshold field is 9.5 V/μm. The emission current is relatively stable. The low synthesis temperature and good field emission performance show that the TiO2 nanowire bundles have good potential apphcation in field emission cold cathode device.%采用水热合成技术,以钛酸丁酯、盐酸和去离子水作为前驱物,在透明导电玻璃(FTO)衬底上合成了垂直于衬底牛长的二氧化钛(TiO2)纳米线束阵列.纳米线束呈四方柱状结构,宽度100~200nm,长度约3μm.HRTEM表明每根纳米线束实际上是由20~40根直径约为4~6 nm的细小纳米线聚集在一起而形成的.系统研究了盐酸浓度对纳米线生长的影响,分析了盐酸在晶体生长中的作用.研究了TiO2纳米线束阵列的场致电子发射特性,其场发射开启电场为5.7 V/ μm(对应电流密度10μA/ cm2),阈值电场为9.5 V/ μm,同时表现出较好的场发射稳定性.低的合成温度和好的场发射性能表明TiO2纳米线束阵列在场发射冷阴极器件上具有良好的应用前景.

  18. The chemistry of hydrothermal magnetite: a review

    Science.gov (United States)

    Nadoll, Patrick; Angerer, Thomas; Mauk, Jeffrey L.; French, David; Walshe, John

    2014-01-01

    Magnetite (Fe3O4) is a well-recognized petrogenetic indicator and is a common accessory mineral in many ore deposits and their host rocks. Recent years have seen an increased interest in the use of hydrothermal magnetite for provenance studies and as a pathfinder for mineral exploration. A number of studies have investigated how specific formation conditions are reflected in the composition of the respective magnetite. Two fundamental questions underlie these efforts — (i) How can the composition of igneous and, more importantly, hydrothermal magnetite be used to discriminate mineralized areas from barren host rocks, and (ii) how can this assist exploration geologists to target ore deposits at greater and greater distances from the main mineralization? Similar to igneous magnetite, the most important factors that govern compositional variations in hydrothermal magnetite are (A) temperature, (B) fluid composition — element availability, (C) oxygen and sulfur fugacity, (D) silicate and sulfide activity, (E) host rock buffering, (F) re-equilibration processes, and (G) intrinsic crystallographic controls such as ionic radius and charge balance. We discuss how specific formation conditions are reflected in the composition of magnetite and review studies that investigate the chemistry of hydrothermal and igneous magnetite from various mineral deposits and their host rocks. Furthermore, we discuss the redox-related alteration of magnetite (martitization and mushketovitization) and mineral inclusions in magnetite and their effect on chemical analyses. Our database includes published and previously unpublished magnetite minor and trace element data for magnetite from (1) banded iron formations (BIF) and related high-grade iron ore deposits in Western Australia, India, and Brazil, (2) Ag–Pb–Zn veins of the Coeur d'Alene district, United States, (3) porphyry Cu–(Au)–(Mo) deposits and associated (4) calcic and magnesian skarn deposits in the southwestern United

  19. Comparative Test of Tomato Cultivars in Protected Fields in Tongliao City%通辽市保护地番茄品种比较试验

    Institute of Scientific and Technical Information of China (English)

    曹霞; 王春雷; 孙翠玲; 纪晓波; 唐艳梅

    2014-01-01

    We carried out the comparative test of fourteen introduced tomato cultivars in order to screen out suitable tomato cultivars for Tongliao city. The results showed that, five cultivars had strong comprehensive resistance, high yield, high soluble solid content and low fruit-cracking rate, and among them, the three cultivars Leiden, Victoria Lorna and Athena had orange-red fruits and excellent commercial characters, so they were suitable for cultivation in Tongliao city.%为筛选出适合通辽市种植的番茄品种,对引进的14个番茄品种进行了比较试验。试验结果表明,有5个品种表现综合抗性强、丰产、可溶性固形物含量高、裂果率低等特点,其中莱顿、维罗娜和雅典娜这3个品种果实橙红色、商品性好,适合在通辽市推广种植。

  20. Pittsburgh City Facilities

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — Pittsburgh City FacilitiesIncludes: City Administrative Buildings, Police Stations, Fire Stations, EMS Stations, DPW Sites, Senior Centers, Recreation Centers,...

  1. Pittsburgh City Facilities

    Data.gov (United States)

    Allegheny County / City of Pittsburgh / Western PA Regional Data Center — Pittsburgh City FacilitiesIncludes: City Administrative Buildings, Police Stations, Fire Stations, EMS Stations, DPW Sites, Senior Centers, Recreation Centers, Pool...

  2. Expats rank Chinese cities

    Institute of Scientific and Technical Information of China (English)

    By Lv Dong

    2012-01-01

    Beijing, April The results of the "2011 Amazing China- The Most Attractive Chinese Cities for Foreigners" election are released. Expats choose Beijing, Shanghai, Tianjin and other cities as Chinas 10 most attractive cities for foreigners.

  3. Towards Smart City Learning

    DEFF Research Database (Denmark)

    Rehm, Matthias; Stan, Catalin; Wøldike, Niels Peter

    2015-01-01

    We present an approach to geometry learning that is based on a didactic theory, which builds on play in order to discover and learn about geometry. Inspired by this theory, a mobile and location-aware game has been developed that aims at embodying geometric concepts in the real world. To this end......, the concept of smart city learning is exploited to situate learning about geometric shapes in concrete buildings and thus make them more accessible for younger children. In close collaboration with a local school a game for 3rd graders was developed and tested on a field trip and in class. A mixed measures...

  4. Formation of hydrothermal deposits at Kings Triple Junction, northern Lau back-arc basin, SW Pacific: The geochemical perspectives

    Digital Repository Service at National Institute of Oceanography (India)

    Paropkari, A.L.; Ray, D.; Balaram, V.; Prakash, L.S.; Mirza, I.H.; Satyanarayana, M.; Rao, T.G.; Kaisary, S.

    An inactive hydrothermal field was discovered near Kings Triple Junction (KTJ) in northern Lau back-arc basin during 19th cruise of R/V Akademik Mstislav Keldysh in 1990. The field consisted of a large elongated basal platform ‘the pedestal...

  5. Cities, Towns and Villages - City Limit (polygon)

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — Data available online through GeoStor at http://www.geostor.arkansas.gov. Arkansas Cities: This data set contains all of the city limit boundaries within the state...

  6. The green city guidelines : techniques for a healthy liveable city

    NARCIS (Netherlands)

    Roo, M.; Kuypers, V.H.M.; Lenzholzer, S.

    2011-01-01

    The Green City Guidelines is an international book that provides information on the social and economic advantages of green spaces in urban environments. The book focuses on decision-makers and people practically involved in the field concerned. It provides tips and advice on ways of using plants, t

  7. In situ chemical sensing for hydrothermal plume mapping and modeling

    Science.gov (United States)

    Fukuba, T.; Kusunoki, T.; Maeda, Y.; Shitashima, K.; Kyo, M.; Fujii, T.; Noguchi, T.; Sunamura, M.

    2012-12-01

    Detection, monitoring, and mapping of biogeochemical anomalies in seawater such as temperature, salinity, turbidity, oxidation-reduction potential, and pH are essential missions to explore undiscovered hydrothermal sites and to understand distribution and behavior of hydrothermal plumes. Utilization of reliable and useful in situ sensors has been widely accepted as a promised approach to realize a spatiotemporally resolved mapping of anomalies without water sampling operations. Due to remarkable progresses of sensor technologies and its relatives, a number of highly miniaturized and robust chemical sensors have been proposed and developed. We have been developed, evaluated, and operated a compact ISFET (Ion-Sensitive Field-Effect Transistor)-based chemical sensors for ocean environmental sensing purposes. An ISFET has advantages against conventional glass-based electrodes on its faster response, robustness, and potential on miniaturization, and thus variety of chemical sensors has been already on the market. In this study, ISFET-based standalone pH sensors with a solid-state Cl-ISE as a reference electrode were mounted on various platforms and operated to monitor the pH anomalies in deep-sea environment at the Kairei, Edmond, and surrounding hydrothermal sites in the southern Central Indian Ridge area during KH10-06 scientific cruise (Nov. 2010), supported by project TAIGA (Trans-crustal Advection and In situ biogeochemical processes of Global sub-seafloor Aquifer). Up to three pH sensors were mounted on a wire-lined CTD/RMS (Rosette Multiple Sampler), dredge sampler, a series of MTD plankton nets, and VMPS (Vertical Multiple-operating Plankton Sampler). A standalone temperature sensor was bundled and operated with the pH sensor when they were mounted on the dredge sampler, MTD plankton nets, and VMPS. An AUV equipped with the pH sensor was also operated for hydrothermal activity survey operations. As a result of Tow-Yo intersect operations of the CTD

  8. Measurements of aerosol absorption and scattering in the Mexico City Metropolitan Area during the MILAGRO field campaign: a comparison of results from the T0 and T1 sites

    Directory of Open Access Journals (Sweden)

    N. A. Marley

    2009-01-01

    Full Text Available In March 2006, a multiagency field campaign was undertaken in Mexico City called the Megacities Initiative: Local and Global Research Observations (MILAGRO. Two of the five field components of the MILAGRO study focused a major part of their efforts on atmospheric particulate emissions from the Mexico City basin and their effects on radiative balance as a function of time, location and processing conditions. As part of these two MILAGRO components, measurements of aerosol optical properties were obtained at a site located in the northern part of Mexico City (T0 and also at a site located 29 km northwest (T1 to estimate the regional effects of aerosol emissions from the basin.

    Measurements of aerosol absorption and scattering for fine mode aerosols were obtained at both sites. Aerosol absorption at 550 nm was similar at both sites, ranging from 7–107 Mm−1 at T0 and from 3–147 Mm−1 at T1. Aerosol scattering measured at 550 nm at T0 ranged from 16–344 Mm−1 while the aerosol scattering values at T1 were much lower than at T0 ranging from 2–136 Mm−1. Aerosol single scattering albedos (SSAs were calculated at 550 nm for the fine mode aerosols at both sites using these data. The SSAs at T0 ranged from 0.47–0.92 while SSAs at T1 ranged from 0.35–0.86. The presence of these highly absorbing fine aerosols in the lower atmosphere of the Mexico City area will result in a positive climate forcing and a local warming of the boundary layer in the region.

    Broadband UVB intensity was found to be higher at site T0, with an average of 64 μW/cm2 at solar noon, than at site T1, which had an average of 54 μW/cm2 at solar noon. Comparisons of clear-sky modeled UVB intensities with the simultaneous UVB measurements obtained at sites T0 and T1 for cloudless days indicate a larger diffuse radiation field at site T0 than at site T1. The determination of aerosol

  9. Formation of zirconia polymorphs under hydrothermal conditions

    Institute of Scientific and Technical Information of China (English)

    ZHENG; Yanqing(郑燕青); SHl; Erwei(施尔畏); Li; Wenjun(李汶军); CHEN; Zhizhan(陈之战); ZHONG; Weizhuo(仲维卓); HUXingfang(胡行方)

    2002-01-01

    Using zirconium oxychloride solution as precursor, monoclinic zirconia crystallites withnarrow distribution of nanosize were obtained in the hydrothermal reaction. However, when thereaction was in weak acidic medium or base medium, whether directly using the colloidal precipi-tate prepared from zirconium salt solutions with base solution as precursor added, or using theprecipitate after filtrating, washing and drying treatments as precursor, the product of the hydro-thermal reaction was the mixture of both monoclinic and tetragonal polymorphs. As the pH of themedium rises, the content of tetragonal phase in the product, the morphologies and size of thecrystallites all change. There are three types of formation mechanisms under hydrothermal condi-tion, which can be called as saturation-precipitation mechanism in homogeneous solution, dissolu-tion-crystallization mechanism and in-situ crystallization mechanism, respectively. The formationmechanism of crystallites varies with different hydrothermal conditions, such as the states of theprecursor and the pH of the medium, which lead to changes in the phases, morphologies andsizes of the resulting crystallites.

  10. City positioning theories and city core competencies

    Institute of Scientific and Technical Information of China (English)

    Xinquan; Zhu

    2007-01-01

    Gity positioning The Chinese city in a decision develops the topic of the destiny. Since the 90's of 20 centuries, the economic integral and globalization developed rapidly. The development make national boundary become not so important, the function of the city is increasingly outstanding. In other words, national competition ability is morally now on the city competition ability. At the same time, this development result that the industry is divided internationally and is divided in cities. Therefore, under the condition of globalization, if the city wants the superior development, it must take advantages and avoid shortage, to position the city accurately, establish the competition and development the strategy. The city positioning is clearly defined the city competition ability, more important it indicated the direction of the city development. Trough the analysis of the resource and environment of the city, decide an accurate position of the best function of the city, well configure the inner and outside resource, catch the opportunities,face the challenges, maximized the market share in order to maximized the wealth and city competition ability.

  11. Mexican-American Cooperative Program at the Cerro Prieto geothermal field: Analysis of the Nuevo Leon magnetic anomaly and its possible relation to the Cerro Prieto magmatic-hydrothermal system

    Science.gov (United States)

    Goldstein, N. E.; Wilt, M. J.; Corrigan, D. J.

    1982-10-01

    The broad dipolar magnetic anomaly whose positive peak is centered near Ejido Nuevo Leon, some 5 km east of the Cerro Prieto I Power Plant, has long been suspended to have a genetic relationship to the thermal source of the Cerro Prieto geothermal system. This suspicion was reinforced after several deep geothermal wells, drilled to depths of 3 to 3.5 km over the anomaly, intersected an apparent dike-sill complex consisting mainly of diabase but with minor rhyodacite. A detailed fit of the observed magnetic field to a computer model indicates that the source may be approximated by a tabular block 4 by 6 km in area, 3.7 km in depth, 2.3 km thick, and dipping slightly to the north. Mafic dike chips from one well, NL-1, were analyzed by means of electron microprobe analyses which showed them to contain a titanomagnetite that is paramagnetic at in-situ temperature conditions. As the dike mineralogy does not account for the magnetic anomaly, the magnetic source is believed to be a deeper, magnetite-rich assemblage of periodotite-gabbro plutons.

  12. Energy landscapes shape microbial communities in hydrothermal systems on the Arctic Mid-Ocean Ridge.

    Science.gov (United States)

    Dahle, Håkon; Økland, Ingeborg; Thorseth, Ingunn H; Pederesen, Rolf B; Steen, Ida H

    2015-07-01

    Methods developed in geochemical modelling combined with recent advances in molecular microbial ecology provide new opportunities to explore how microbial communities are shaped by their chemical surroundings. Here, we present a framework for analyses of how chemical energy availability shape chemotrophic microbial communities in hydrothermal systems through an investigation of two geochemically different basalt-hosted hydrothermal systems on the Arctic Mid-Ocean Ridge: the Soria Moria Vent field (SMVF) and the Loki's Castle Vent Field (LCVF). Chemical energy landscapes were evaluated through modelling of the Gibbs energy from selected redox reactions under different mixing ratios between seawater and hydrothermal fluids. Our models indicate that the sediment-influenced LCVF has a much higher potential for both anaerobic and aerobic methane oxidation, as well as aerobic ammonium and hydrogen oxidation, than the SMVF. The modelled energy landscapes were used to develop microbial community composition models, which were compared with community compositions in environmental samples inside or on the exterior of hydrothermal chimneys, as assessed by pyrosequencing of partial 16S rRNA genes. We show that modelled microbial communities based solely on thermodynamic considerations can have a high predictive power and provide a framework for analyses of the link between energy availability and microbial community composition.

  13. A novel large filamentous deltaproteobacterium on hydrothermally inactive sulfide chimneys of the Southern Mariana Trough

    Science.gov (United States)

    Kato, Shingo; Yamagishi, Akihiko

    2016-04-01

    Unusual large filamentous bacteria (LFB) have been found on the deep seafloor environments. They play a significant role in geochemical cycling in the dark environments. However, our knowledge of the spatial distribution and phylogenetic diversity of the LFB on the deep seafloor are still limited due to the inaccessibility to these environments. Here, we report the discovery of a novel LFB on a hydrothermally inactive sulfide chimney in a deep-sea hydrothermal field of the Southern Mariana Trough. Light and electron microscopic observation showed that the width and total length of the LFB were >8 μm and >100 μm, respectively, of which morphology was similar to that of other known LFB such as "cable bacteria" of the Desulfobulbaceae. Analyses of a 16S rRNA gene clone library and fluorescence in situ hybridization revealed that this LFB belongs to the Desulfobulbaceae. The 16S rRNA gene of the LFB showed 94% similarity to those of the reported cable bacteria and cultured deltaproteobacterial species, suggesting that the LFB is a novel cable bacterium of the Desulfobulbaceae. The novel LFB potentially play a role in sulfur cycling on sulfide chimneys at the hydrothermally ceasing or even ceased deep-sea hydrothermal fields.

  14. Hydrothermal activity on the summit of Loihi Seamount, Hawaii

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, H.; Tsubota, H.; Nakai, T.; Ishibashi, J.; Akagi, T.; Gamo, T.; Tilbrook, B.; Igarashi, G.; Kodera, M.; Shitashima, K.

    1987-01-01

    Loihi Seamount is located about 30km southeast of the Island of Hawaii; it rises from the sea floor at a depth of 4000m and reaches a maximum elevation of 1000m blow sea level. Oceanographic studies including CTD survey of warm sites and bottom photography confirmed several hydrothermal fields on the summit of the seamount. The summit is covered with hydrothermal plumes which are extremely rich in methane, helium, carbon dioxide, iron and manganese; the maximum concentration of helium is 91.8 n1/1, the highest so far reported for open-ocean water. The /sup 3/He//sup 4/He ratio of helium injected into seawater is 14 times the atmospheric level. The 3He/heat and CO/sub 2//heat ratios in the plumes are one to two orders of magnitude greater than those at oceanic spreading centers, implying a more primitive source region for hotspot volcanism. The plumes also show negative pH anomalies up to half a pH unit from ambient owing to the high injection rate of CO/sub 2/. (4 figs, 3 photos, 1 tab, 31 refs)

  15. Hydrothermal systems in small ocean planets.

    Science.gov (United States)

    Vance, Steve; Harnmeijer, Jelte; Kimura, Jun; Hussmann, Hauke; Demartin, Brian; Brown, J Michael

    2007-12-01

    We examine means for driving hydrothermal activity in extraterrestrial oceans on planets and satellites of less than one Earth mass, with implications for sustaining a low level of biological activity over geological timescales. Assuming ocean planets have olivine-dominated lithospheres, a model for cooling-induced thermal cracking shows how variation in planet size and internal thermal energy may drive variation in the dominant type of hydrothermal system-for example, high or low temperature system or chemically driven system. As radiogenic heating diminishes over time, progressive exposure of new rock continues to the current epoch. Where fluid-rock interactions propagate slowly into a deep brittle layer, thermal energy from serpentinization may be the primary cause of hydrothermal activity in small ocean planets. We show that the time-varying hydrostatic head of a tidally forced ice shell may drive hydrothermal fluid flow through the seafloor, which can generate moderate but potentially important heat through viscous interaction with the matrix of porous seafloor rock. Considering all presently known potential ocean planets-Mars, a number of icy satellites, Pluto, and other trans-neptunian objects-and applying Earth-like material properties and cooling rates, we find depths of circulation are more than an order of magnitude greater than in Earth. In Europa and Enceladus, tidal flexing may drive hydrothermal circulation and, in Europa, may generate heat on the same order as present-day radiogenic heat flux at Earth's surface. In all objects, progressive serpentinization generates heat on a globally averaged basis at a fraction of a percent of present-day radiogenic heating and hydrogen is produced at rates between 10(9) and 10(10) molecules cm(2) s(1).

  16. Element enrichment and U-series isotopic characteristics of the hydrothermal sulfides at Jade site in the Okinawa Trough

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The geochemical and U-series isotopic characteristics of hydrothermal sulfide samples from the Jade site (127°04.5′E, 27°15′N, water depth 1300-1450 m) at Jade site in the Okinawa Trough were analyzed. In the hydrothermal sulfide samples bearing sulfate (samples HOK1 and HOK2), the LREEs are relatively enriched. All the hydrothermal sulfide samples except HOK1 belong to Zn-rich hydrothermal sulfide. In comparison with Zn-rich hydrothermal sulfides from other fields, the contents of Zn, Pb, Ag, Cd, Au and Hg are higher, the contents of Fe, Al, Cr, Co, Ni, Sr, Te, Cs, Ti and U lower, and the 210Pb radioactivity ratios and 210Pb/Pb ratios very low. In the hydrothermal sulfide mainly composed of sphalerite, the correlations between rare elements Hf and U, and Hf and Mn as well as that between dispersive elements Ga and Zn, are strongly positive; also the contents of Au and Ag are related to Fe-sulfide, because the low temperature promotes enrichment of Au and Ag. Meanwhile, the positive correlations between Fe and Bi and between Zn and Cd are not affected by the change of mineral assemblage. Based on the 210Pb/Pb ratios of hydrothermal sulfide samples (3.99×10-5-5.42×10?5), their U isotopic composition (238U content 1.15-2.53 ppm, 238U activity 1.07-1.87 dpm/g, 234U activity 1.15-2.09 dpm/g and 234U/238U ratio 1.07-1.14) and their 232Th and 230Th contents are at base level, and the chronological age of hydrothermal sulfide at Jade site in the Okinawa Trough is between 200 and 2000 yr.

  17. Effects of hydrothermal unrest on stress and deformation: insights from numerical modeling and application to Vulcano Island (Italy)

    Science.gov (United States)

    Currenti, Gilda; Napoli, Rosalba; Coco, Armando; Privitera, Emanuela

    2017-04-01

    A numerical approach is proposed to evaluate stress and deformation fields induced by hydrothermal fluid circulation and its influence on volcano-flank stability. The numerical computations have been focused on a conceptual model of Vulcano Island, where geophysical, geochemical, and seismic signals have experienced several episodes of remarkable changes likely linked to the hydrothermal activity. We design a range of numerical models of hydrothermal unrest and computed the associated deformation and stress field arising from rock-fluid interaction processes related to the thermo-poroelastic response of the medium. The effects of model parameters on deformation and flank stability are explored considering different multilayered crustal structures constrained by seismic tomography and stratigraphy investigations. Our findings highlight the significant role of model parameters on the response of the hydrothermal system and, consequently, on the amplitudes and the timescale of stress and strain fields. Even if no claim is made that the model strictly applies to the crisis episodes at Vulcano, the numerical results are in general agreement with the pattern of monitoring observations, characterized by an enhancing of gas emission and seismic activity without significant ground deformation. The conceptual model points to a pressurization and heating of the shallow hydrothermal system (1-0.25 km bsl) fed by fluid of magmatic origin. However, for the assumed values of model material and source parameters (rate of injection, fluid composition, and temperature), the pressure and temperature changes do not affect significantly the flank stability, which is mainly controlled by the gravitational force.

  18. Description and validation of an automated methodology for mapping mineralogy, vegetation, and hydrothermal alteration type from ASTER satellite imagery with examples from the San Juan Mountains, Colorado

    Science.gov (United States)

    Rockwell, Barnaby W.

    2012-01-01

    The efficacy of airborne spectroscopic, or "hyperspectral," remote sensing for geoenvironmental watershed evaluations and deposit-scale mapping of exposed mineral deposits has been demonstrated. However, the acquisition, processing, and analysis of such airborne data at regional and national scales can be time and cost prohibitive. The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor carried by the NASA Earth Observing System Terra satellite was designed for mineral mapping and the acquired data can be efficiently used to generate uniform mineral maps over very large areas. Multispectral remote sensing data acquired by the ASTER sensor were analyzed to identify and map minerals, mineral groups, hydrothermal alteration types, and vegetation groups in the western San Juan Mountains, Colorado, including the Silverton and Lake City calderas. This mapping was performed in support of multidisciplinary studies involving the predictive modeling of surface water geochemistry at watershed and regional scales. Detailed maps of minerals, vegetation groups, and water were produced from an ASTER scene using spectroscopic, expert system-based analysis techniques which have been previously described. New methodologies are presented for the modeling of hydrothermal alteration type based on the Boolean combination of the detailed mineral maps, and for the entirely automated mapping of alteration types, mineral groups, and green vegetation. Results of these methodologies are compared with the more detailed maps and with previously published mineral mapping results derived from analysis of high-resolution spectroscopic data acquired by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) sensor. Such comparisons are also presented for other mineralized and (or) altered areas including the Goldfield and Cuprite mining districts, Nevada and the central Marysvale volcanic field, Wah Wah Mountains, and San Francisco Mountains, Utah. The automated

  19. Water changed the cities

    DEFF Research Database (Denmark)

    Elle, Morten; Jensen, Marina Bergen

    An improvement in water infrastructure and cleaning up the waters changed many harbour cities in Denmark at the beginning of the 90s. The harbour cities changed from drity, run-down industrial harbours to clean and attractive harbour dwelling creating new city centres and vital city areas...

  20. 40Ar/39Ar dating, geochemistry, and isotopic analyses of the quaternary Chichinautzin volcanic field, south of Mexico City: implications for timing, eruption rate, and distribution of volcanism

    Science.gov (United States)

    Arce, J. L.; Layer, P. W.; Lassiter, J. C.; Benowitz, J. A.; Macías, J. L.; Ramírez-Espinosa, J.

    2013-12-01

    Monogenetic structures located at the southern and western ends of the Chichinautzin volcanic field (Trans-Mexican Volcanic Belt, Central Mexico) yield 40Ar/39Ar ages ranging from 1.2 Ma in the western portion of the field to 1.0-0.09 Ma in the southern portion, all of which are older than the volcanic field. These new ages indicate: (1) an eruption rate of 0.47 km3/kyr, which is much lower than the 11.7 km3/kyr previously estimated; (2) that the Chichinautzin magmatism coexisted with the Zempoala (0.7 Ma) and La Corona (1.0 Ma) polygenetic volcanoes on the southern edge of Las Cruces Volcanic Range (Trans-Mexican Volcanic Belt); and confirm (3) that the drainage system between the Mexico and Cuernavaca basins was closed during early Pleistocene forming the Texcoco Lake. Whole-rock chemistry and Sr, Nd, and Pb isotopic data indicate heterogeneous magmatism throughout the history of Chichinautzin activity that likely reflects variable degrees of slab and sediment contributions to the mantle wedge, fractional crystallization, and crustal assimilation. Even with the revised duration of volcanism within the Chichinautzin Volcanic Field, its eruption rate is higher than most other volcanic fields of the Trans-Mexican Volcanic Belt and is comparable only to the Tacámbaro-Puruaran area in the Michoacán-Guanajuato Volcanic Field to the west. These variations in eruption rates among different volcanic fields may reflect a combination of variable subduction rates of the Rivera and Cocos plates along the Middle America Trench, as well as different distances from the trench, variations in the depth with respect to the subducted slab, or the upper plate characteristics.

  1. Thermophilic hydrogen-producing bacteria inhabiting deep-sea hydrothermal environments represented by Caloranaerobacter.

    Science.gov (United States)

    Jiang, Lijing; Xu, Hongxiu; Zeng, Xiang; Wu, Xiaobing; Long, Minnan; Shao, Zongze

    2015-11-01

    Hydrogen is an important energy source for deep-sea hydrothermal vent ecosystems. However, little is known about microbes and their role in hydrogen turnover in the environment. In this study, the diversity and physiological characteristics of fermentative hydrogen-producing microbes from deep-sea hydrothermal vent fields were described for the first time. Seven enrichments were obtained from hydrothermal vent sulfides collected from the Southwest Indian Ocean, East Pacific and South Atlantic. 16S rRNA gene analysis revealed that members of the Caloranaerobacter genus were the dominant component in these enrichments. Subsequently, three thermophilic hydrogen producers, strains H363, H53214 and DY22619, were isolated. They were phylogenetically related to species of the genus Caloranaerobacter. The H2 yields of strains H363, H53214, DY22619 and MV107, which was the type species of genus Caloranaerobacter, were 0.11, 1.21, 3.13 and 2.85 mol H2/mol glucose, respectively. Determination of the main soluble metabolites revealed that strains H363, H53214 and MV107 performed heterolactic fermentations, while strain DY22619 performed butyric acid fermentation, indicating distinct fermentation patterns among members of the genus. Finally, a diversity of forms of [FeFe]-hydrogenase with different modular structures was revealed based on draft genomic data of Caloranaerobacter strains. This highlights the complexity of hydrogen metabolism in Caloranaerobacter, reflecting adaptations to environmental conditions in hydrothermal vent systems. Collectively, results suggested that Caloranaerobacter species might be ubiquitous and play a role in biological hydrogen generation in deep-sea hydrothermal vent fields.

  2. Hydrothermal Growth and Hydrogen Selective Sensing of Nickel Oxide Nanowires

    Directory of Open Access Journals (Sweden)

    Thi Thanh Le Dang

    2015-01-01

    Full Text Available Low cost synthesis of nanostructured metal oxides for gas sensing application at low temperature is nowadays of crucial importance in many fields. Herein, NiO p-type semiconducting nanowires with polycrystalline structure were prepared by a facile and scalable hydrothermal method. Morphology and crystal structure of the NiO nanowires were investigated by scan electron microscopy, X-ray diffraction, and transmission electron microscopy. The nanostructured material was then tested as hydrogen sensor showing very good performance in terms of sensor response, stability, absence of drifts, and speed of response and recovery. The selectivity of the NiO sensor to hydrogen towards other gases (ethanol, ammonia, and liquefied petroleum gas was found to be good.

  3. Hydrothermal Synthesis of Ni/Al Layered Double Hydroxide Nanorods

    Directory of Open Access Journals (Sweden)

    Yun Zhao

    2011-01-01

    Full Text Available Ni/Al layered double hydroxide (LDH nanorods were successfully synthesized by the hydrothermal reaction. The crystal structure of the products was characterized by X-ray diffraction (XRD. The morphology of the products was observed using transmission electron microscopy (TEM and field emission scanning electron microscopy (SEM. The influences of reaction time and pH value on the morphology of the Ni/Al LDHs were investigated. The result showed that the well-crystallized nanorods of Ni/Al LDHs could be obtained when the pH value was about 10.0 with a long reaction time (12–18 h at 180°C.

  4. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Energy Technology Data Exchange (ETDEWEB)

    Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  5. The hydrothermal reaction kinetics of aspartic acid

    Science.gov (United States)

    Cox, Jenny S.; Seward, Terry M.

    2007-02-01

    Experimental data on the hydrothermal reaction kinetics of aspartic acid were acquired using a custom-built spectrophotometric reaction cell which permits in situ observation under hydrothermal conditions. The results of this study indicate that the reaction kinetics of dilute aspartic acid solutions are significantly different depending on the presence or absence of catalytic surfaces such as standard metal alloys. The spectroscopic data presented here represent the first direct observations, in situ and in real time, of an amino acid reacting in a hydrothermal solution. Quantitative kinetic information, including rate constants, concentration versus time profiles, and calculations of the individual component spectra, was obtained from the data using a chemometric approach based on factor analysis/principle component analysis which treats the rate expressions simultaneously as a system of differential algebraic equations (DAE) of index 1. Identification of the products was confirmed where possible by high pressure anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD). The reaction kinetics of aspartic acid under hydrothermal conditions was observed to be highly complex, in contrast to previous studies which indicated almost exclusively deamination. At lower temperatures (120-170 °C), several different reaction pathways were observed, including decarboxylation and polymerization, and the catalytic effects of reactor surfaces on the aspartic acid system were clearly demonstrated. At higher temperatures (above 170 °C), aspartic acid exhibited highly complex behaviour, with evidence indicating that it can simultaneously dimerize and cyclize, deaminate (by up to two pathways), and decarboxylate (by up to two pathways). These higher temperature kinetics were not fully resolvable in a quantitative manner due to the complexity of the system and the constraints of UV spectroscopy. The results of this study provide strong evidence that the reaction

  6. Hydrothermal synthesis of xonotlite from carbide slag

    Institute of Scientific and Technical Information of China (English)

    Jianxin Cao; Fei Liu; Qian Lin; Yu Zhang

    2008-01-01

    Carbide slag was used as the calcareous materials for the first time to prepare xonotlite via dynamic hydrothermal synthesis.The effects of influential factors including different calcination temperatures,pretreatment methods of the carbide slag and process param-eters of hydrothermal synthesis on the microstructure and morphology of xonotlite were explored using XRD and SEM techniques.The results indicate that the carbide slag after proper calcination could be used to prepare pure xonotlite;and different calcination tern-peratures have little effect on the crystallinity of synthesized xonotlitc,but have great impact on the morphology of secondary particles.The different pretreatment methods of the carbide slag pose great impact on the crystallinity and morphology of secondary particles of xonotlite.Xonotlite was also synthesized from pure CaO under the salne experimental conditions as that prepared from calcined carbide slag for comparison.Little amount of impurities in carbide slag has no effect on the mechanism of hydrothermal synthesizing xonotlite from carbide slag.

  7. Hydrothermal synthesis of zeolites from natural stellerite

    Institute of Scientific and Technical Information of China (English)

    李酽; 汪信; 董元彩; 朱俊武

    2002-01-01

    Y and P zeolites were synthesized hydrothermally from natural stellerite under different conditions and were characterized via XRD and FT-IR.The results show that the higher crystallinity of Y zeolite can be obtained in hydrothermal system with low alkalinity,low Ca2+/Na+ ratio,and high SiO2/Al2O3 ratio.The lattice space of the samples decreases as crystallization time increases.P Zeolite is prompted under condition of higher alkalinity and higher Ca2+/Na+ ratio.The intensity and number of bands in the range of 400 cm-1~900 cm-1 increases with reaction time.Bands at 680 cm-1,760 cm-1 and 860 cm-1 corresponding to Y zeolite appear during the crystallization stage.Most of these bands shift to higher wavenumbers when SiO2/Al2O3 ratio increases generally.In the hydrothermal system with reverse condition above,bands at 600 cm-1,420 cm-1~470 cm-1 hardly change as the crystallization time increases and the main crystal phase of P zeolite is obtained.

  8. Numerical simulation of magmatic hydrothermal systems

    Science.gov (United States)

    Ingebritsen, S.E.; Geiger, S.; Hurwitz, S.; Driesner, T.

    2010-01-01

    The dynamic behavior of magmatic hydrothermal systems entails coupled and nonlinear multiphase flow, heat and solute transport, and deformation in highly heterogeneous media. Thus, quantitative analysis of these systems depends mainly on numerical solution of coupled partial differential equations and complementary equations of state (EOS). The past 2 decades have seen steady growth of computational power and the development of numerical models that have eliminated or minimized the need for various simplifying assumptions. Considerable heuristic insight has been gained from process-oriented numerical modeling. Recent modeling efforts employing relatively complete EOS and accurate transport calculations have revealed dynamic behavior that was damped by linearized, less accurate models, including fluid property control of hydrothermal plume temperatures and three-dimensional geometries. Other recent modeling results have further elucidated the controlling role of permeability structure and revealed the potential for significant hydrothermally driven deformation. Key areas for future reSearch include incorporation of accurate EOS for the complete H2O-NaCl-CO2 system, more realistic treatment of material heterogeneity in space and time, realistic description of large-scale relative permeability behavior, and intercode benchmarking comparisons. Copyright 2010 by the American Geophysical Union.

  9. Surface roughened zirconia: towards hydrothermal stability.

    Science.gov (United States)

    Camposilvan, Erik; Flamant, Quentin; Anglada, Marc

    2015-07-01

    Surface roughness is needed in several yttria-stabilized zirconia components used in restorative dentistry for osseointegration or adhesion purposes. This can be achieved by different treatments, which may also modify the microstructure of the surface. Among them, sandblasting and chemical etching are widely used, but their effect on hydrothermal aging of zirconia is not fully understood. In the present work, the zirconia long-term stability of rough surfaces prepared by these techniques is analyzed and a method is proposed for preventing hydrothermal aging while maintaining the original surface appearance and mechanical properties. The method involves pressure infiltration of a Cerium salt solution on the roughened surfaces followed by a thermal treatment. The solution, trapped by surface defects and small pores, is decomposed during thermal treatment into Cerium oxide, which is diffused at high temperature, obtaining Ce co-doping in the near-surface region. In addition, the microstructural changes induced in the near-surface by sandblasting or chemical etching are removed by the thermal treatment together with surface defects. No color modification was observed and the final roughness parameters were in the range of existing implants of proved good osseointegration. The aging resistance of Ce co-doped materials was strongly enhanced, showing the absence of aging after artificial degradation, increasing in this way the surface mechanical integrity. The proposed treatment is easily applicable to the current manufacturing procedures of zirconia dental posts, abutments, crowns and dentures, representing a solution to hydrothermal aging in these and other biomedical applications.

  10. Hydrothermal Formation of Calcium Copper Tetrasilicate.

    Science.gov (United States)

    Johnson-McDaniel, Darrah; Comer, Sara; Kolis, Joseph W; Salguero, Tina T

    2015-12-01

    We describe the first hydrothermal synthesis of CaCuSi4 O10 as micron-scale clusters of thin platelets, distinct from morphologies generated under salt-flux or solid-state conditions. The hydrothermal reaction conditions are surprisingly specific: too cold, and instead of CaCuSi4 O10 , a porous calcium copper silicate forms; too hot, and calcium silicate (CaSiO3 ) forms. The precursors also strongly impact the course of the reaction, with the most common side product being sodium copper silicate (Na2 CuSi4 O10 ). Optimized conditions for hydrothermal CaCuSi4 O10 formation from calcium chloride, copper(II) nitrate, sodium silicate, and ammonium hydroxide are 350 °C at 3000 psi for 72 h; at longer reaction times, competitive delamination and exfoliation causes crystal fragmentation. These results illustrate that CaCuSi4 O10 is an even more unique material than previously appreciated.

  11. A survey on factors influencing city branding

    Directory of Open Access Journals (Sweden)

    Seyed Mohsen Mahmoudzadeh

    2014-10-01

    Full Text Available Nowadays, the issue of “globalization” is entering to all areas in the world. In addition to products and companies, cities and countries also have the opportunity to see themselves as important actors in international arena. Places define their positions in different fields like business, leisure and recreation, educational opportunities, living, etc. This paper presents an empirical study to introduce city branding as one of the solutions to join globalization process. The method of this research is based on the “descriptive-analytic” and utilize the available literature and experts’ opinions to prioritize the influencing factors of city branding. We use Delphi consensus methods and technique of analytical hierarchy process to evaluate the factors. Finally, the results of the study indicate that security, transportation and mental creativity are the weakest fields and business and shopping facilities are strong fields of city branding in metropolitan of Tehran.

  12. City health development planning.

    Science.gov (United States)

    Green, Geoff; Acres, John; Price, Charles; Tsouros, Agis

    2009-11-01

    The objective of this evaluation was to review the evolution and process of city health development planning (CHDP) in municipalities participating in the Healthy Cities Network organized by the European Region of the World Health Organization. The concept of CHDP combines elements from three theoretical domains: (a) health development, (b) city governance and (c) urban planning. The setting was the 56 cities which participated in Phase III (1998-2002) of the Network. Evidence was gathered from documents either held in WHO archives or made available from Network cities and from interviews with city representatives. CHDPs were the centrepiece of Phase III, evolving from city health plans developed in Phase II. They are strategic documents giving direction to municipalities and partner agencies. Analysis revealed three types of CHDP, reflecting the realpolitik of each city. For many cities, the process of CHDP was as important as the plan itself.

  13. Hydrothermal pretreatment of palm oil empty fruit bunch

    Science.gov (United States)

    Simanungkalit, Sabar Pangihutan; Mansur, Dieni; Nurhakim, Boby; Agustin, Astrid; Rinaldi, Nino; Muryanto, Fitriady, Muhammad Ariffudin

    2017-01-01

    Hydrothermal pretreatment methods in 2nd generation bioethanol production more profitable to be developed, since the conventional pretreatment, by using acids or alkalis, is associated with the serious economic and environmental constraints. The current studies investigate hydrothermal pretreatment of palm oil empty fruit bunch (EFB) in a batch tube reactor system with temperature and time range from 160 to 240 C and 15 to 30 min, respectively. The EFB were grinded and separated into 3 different particles sizes i.e. 10 mesh, 18 mesh and 40 mesh, prior to hydrothermal pretreatment. Solid yield and pH of the treated EFB slurries changed over treatment severities. The chemical composition of EFB was greatly affected by the hydrothermal pretreatment especially hemicellulose which decreased at higher severity factor as determined by HPLC. Both partial removal of hemicellulose and migration of lignin during hydrothermal pretreatment caused negatively affect for enzymatic hydrolysis. This studies provided important factors for maximizing hydrothermal pretreatment of EFB.

  14. Electromagnetic fields levels measurement in the vicinity of Vodafone's cellular base stations located in the cities of Tirana, Durres and Librazhd in Albania

    Energy Technology Data Exchange (ETDEWEB)

    Grillo, B.; Arapi, S. [Institute of Public Health, Tirana (Albania). Radiation Protection Office

    2004-07-01

    The instrument can record and store instantaneous, maximum and mean values of electric and magnetic field values. According to all European and international standards, the measured values in the frequency range 100 kHz - 10 GHz should be expressed in any 6 minute time period. In the measuring set up used, aquisition, storage and processing of the measurements data is controlled with portable pc via a double optical interface and a special software. (orig.)

  15. The Optical Properties of Crystalline Zn3Nb2O8 Nanomaterials Obtained by Hydrothermal Method

    OpenAIRE

    Mihaela Birdeanu; Mirela Vaida; Eugenia Fagadar-Cosma

    2015-01-01

    The present study is focused on the obtaining of the Zn3Nb2O8 nanomaterial using the hydrothermal method and its characterization through different techniques. X-ray diffraction at room temperature revealed that a novel crystalline form of the nanomaterial forms at 1100°C belonging to monoclinic space group C2/c. Field-emission scanning electron microscopy evidenced the columnar morphology of the particle’s agglomeration and the high resolution electron transmission microscopy confirms the me...

  16. Annex 1 to: Trace elements mobility in soils from the hydrothermal area of Nisyros (Greece

    Directory of Open Access Journals (Sweden)

    Kyriaki Daskalopoulou

    2015-03-01

    Full Text Available Nisyros Island, Greece, is a stratovolcano known for its intense hydrothermal activity. On June 2013, during a multidisciplinary field campaign, soil samples were collected in the caldera area to determinate the main mineralogical assemblages and to investigate the distribution of trace element concentrations and the possible relationship to the contribution of fluids of deep origin. Soil samples were analysed with XRD and for the chemical composition of their leachable (deionized water and pseudo total (microwave digestion  [...

  17. The Astrobiology Field Guide in World Wind

    Science.gov (United States)

    Scalice, D. M.

    2004-12-01

    In collaboration with the Australian Centre for Astrobiology (ACA), and NASA Learning Technologies (NLT), and utilizing the powerful visualization capabilities of their "World Wind" software, the NASA Astrobiology Institute (NAI) is crafting a prototype "Astrobiology Field Guide" to bring the field experiences and stories of astrobiology science to the public and classrooms around the world. The prototype focuses on one region in particular - The Pilbara in Western Australia. This first Field Guide "hotspot" is an internationally recognized area hosting the best known example of the earliest evidence of life on Earth - a stromatolitic chert precipitation in the 3.45 Ga Warrawoona Group. The goal of the Astrobiology Field Guide is to engage students of all ages with the ongoing field expeditions of today's astrobiologists as they explore the ends of the Earth searching for clues to life's origin, evolution, and distribution in the Universe. The NAI hopes to expand this Field Guide to include many more astrobiologically relevant areas across the globe such as Cuatro Cienegas in Mexico, the Rio Tinto in Spain, Yellowstone National Park in the US, and the Lost City hydrothermal vent field on the mid-Atlantic ridge - and possibly sites on Mars. To that end, we will be conducting feasibility studies and evaluations with informal and formal education contacts. The Astrobiology Field Guide is also serving as a cornerstone to educational materials being developed focused on the Pilbara region for use in classrooms in Australia, the UK, and potentially the US. These materials are being developed by the Australian Centre for Astrobiology, and the ICT Innovations Centre at Macquarie University in Sydney, in collaboration with the NAI and the Centre for Astronomy and Science Education at the University of Glamorgan in the UK.

  18. Statistical analysis of lake levels and field study of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015: Chapter A of Water levels and groundwater and surface-water exchanges in lakes of the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015

    Science.gov (United States)

    Jones, Perry M.; Trost, Jared J.; Diekoff, Aliesha L.; Rosenberry, Donald O.; White, Eric A.; Erickson, Melinda L.; Morel, Daniel L.; Heck, Jessica M.

    2016-10-19

    Water levels declined from 2003 to 2011 in many lakes in Ramsey and Washington Counties in the northeast Twin Cities Metropolitan Area, Minnesota; however, water levels in other northeast Twin Cities Metropolitan Area lakes increased during the same period. Groundwater and surface-water exchanges can be important in determining lake levels where these exchanges are an important component of the water budget of a lake. An understanding of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area has been limited by the lack of hydrologic data. The U.S. Geological Survey, in cooperation with the Metropolitan Council and Minnesota Department of Health, completed a field and statistical study assessing lake-water levels and regional and local groundwater and surface-water exchanges near northeast Twin Cities Metropolitan Area lakes. This report documents the analysis of collected hydrologic, water-quality, and geophysical data; and existing hydrologic and geologic data to (1) assess the effect of physical setting and climate on lake-level fluctuations of selected lakes, (2) estimate potential percentages of surface-water contributions to well water across the northeast Twin Cities Metropolitan Area, (3) estimate general ages for waters extracted from the wells, and (4) assess groundwater inflow to lakes and lake-water outflow to aquifers downgradient from White Bear Lake. Statistical analyses of lake levels during short-term (2002–10) and long-term (1925–2014) periods were completed to help understand lake-level changes across the northeast Twin Cities Metropolitan Area. Comparison of 2002–10 lake levels to several landscape and geologic characteristics explained variability in lake-level changes for 96 northeast Twin Cities Metropolitan Area lakes. Application of several statistical methods determined that (1) closed-basin lakes (without an active outlet) had larger lake-level declines than flow-through lakes with an outlet; (2

  19. Statistical analysis of lake levels and field study of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015: Chapter A of Water levels and groundwater and surface-water exchanges in lakes of the northeast Twin Cities Metropolitan Area, Minnesota, 2002 through 2015

    Science.gov (United States)

    Jones, Perry M.; Trost, Jared J.; Diekoff, Aliesha L.; Rosenberry, Donald O.; White, Eric A.; Erickson, Melinda L.; Morel, Daniel L.; Heck, Jessica M.

    2016-10-19

    Water levels declined from 2003 to 2011 in many lakes in Ramsey and Washington Counties in the northeast Twin Cities Metropolitan Area, Minnesota; however, water levels in other northeast Twin Cities Metropolitan Area lakes increased during the same period. Groundwater and surface-water exchanges can be important in determining lake levels where these exchanges are an important component of the water budget of a lake. An understanding of groundwater and surface-water exchanges in the northeast Twin Cities Metropolitan Area has been limited by the lack of hydrologic data. The U.S. Geological Survey, in cooperation with the Metropolitan Council and Minnesota Department of Health, completed a field and statistical study assessing lake-water levels and regional and local groundwater and surface-water exchanges near northeast Twin Cities Metropolitan Area lakes. This report documents the analysis of collected hydrologic, water-quality, and geophysical data; and existing hydrologic and geologic data to (1) assess the effect of physical setting and climate on lake-level fluctuations of selected lakes, (2) estimate potential percentages of surface-water contributions to well water across the northeast Twin Cities Metropolitan Area, (3) estimate general ages for waters extracted from the wells, and (4) assess groundwater inflow to lakes and lake-water outflow to aquifers downgradient from White Bear Lake. Statistical analyses of lake levels during short-term (2002–10) and long-term (1925–2014) periods were completed to help understand lake-level changes across the northeast Twin Cities Metropolitan Area. Comparison of 2002–10 lake levels to several landscape and geologic characteristics explained variability in lake-level changes for 96 northeast Twin Cities Metropolitan Area lakes. Application of several statistical methods determined that (1) closed-basin lakes (without an active outlet) had larger lake-level declines than flow-through lakes with an outlet; (2

  20. Heat flux measured acoustically at Grotto Vent, a hydrothermal vent cluster on the Endeavour Segment, Juan de Fuca Ridge

    Science.gov (United States)

    Xu, G.; Jackson, D. R.; Bemis, K. G.; Rona, P. A.

    2013-12-01

    Over the past several decades, quantifying the heat output has been a unanimous focus of studies at hydrothermal vent fields discovered around the global ocean. Despite their importance, direct measurements of hydrothermal heat flux are very limited due to the remoteness of most vent sites and the complexity of hydrothermal venting. Moreover, almost all the heat flux measurements made to date are snapshots and provide little information on the temporal variation that is expected from the dynamic nature of a hydrothermal system. The Cabled Observatory Vent Imaging Sonar (COVIS, https://sites.google.com/a/uw.edu/covis/) is currently connected to the Endeavour node of the NEPTUNE Canada observatory network (http://www.neptunecanada.ca) to monitor the hydrothermal plumes issuing from a vent cluster (Grotto) on the Endeavour Segment of the Juan de Fuca Ridge. COVIS is acquiring a long-term (20-months to date) time series of the vertical flow rate and volume flux of the hydrothermal plume above Grotto through the Doppler analysis of the acoustic backscatter data (Xu et al., 2013). We then estimate the plume heat flux from vertical flow rate and volume flux using our newly developed inverse method. In this presentation, we will briefly summarize the derivation of the inverse method and present the heat-flux time series obtained consequently with uncertainty quantification. In addition, we compare our heat-flux estimates with the one estimated from the plume in-situ temperatures measured using a Remotely Operative Vehicle (ROV) in 2012. Such comparison sheds light on the uncertainty of our heat flux estimation. Xu, G., Jackson, D., Bemis, K., and Rona, P., 2013, Observations of the volume flux of a seafloor hydrothermal plume using an acoustic imaging sonar, Geochemistry, Geophysics Geosystems, 2013 (in press).

  1. The Mobility of Rare—Earth Elements During Hydrothermal Activity:A Review

    Institute of Scientific and Technical Information of China (English)

    熊永良; 翟裕生

    1991-01-01

    The mobility of the rare-earth elements(REE)during hydrothermal activities is increasingly documented.Geological and experimental evidence suggests that REE may be mobile in solutions rich in F-,Cl-,HCO3-,CO2- 3,HPO42-,PO43-,or in combinations of the above ligands,even though little has been known about which ligand or which combination is most effective in mobilizing REE. The fractionation of REE resulting from hydrothermal activities is inconsistent.One set of field data implies the prererential mobility of the light rare-earth elements(LREE).whereas another set of field observations indicates the dominant mobilization of the heavy rare earth elements(HREE),and some theoretical prediction is comtradictory to the field evidence.The Eu anomalies due to hydrothermal activities are complex and plausible explanation is not available.The existing experimental approaches dealing with REE are not adequate for explanation ofREE behaviour in aqueous solutions.Systematic experimental approaches are suggested.

  2. Hydrothermal alteration zones and present reservoir conditions: an approach to define production zones at the eastern portion of the Cerro Prieto geothermal field, BC; Zonas de alteracion hidrotermal y condiciones actuales del yacimiento: un enfoque para determinar zonas productoras al oriente del campo geotermico de Cerro Prieto, BC

    Energy Technology Data Exchange (ETDEWEB)

    Camacho Hernandez, Juan Manuel [Comision Federal de Electricidad, Residencia General de Cerro Prieto, Mexicali, Baja California (Mexico)]. E-mail: juan.camacho02@cfe.gob.mx

    2009-07-15

    Geological factors are as essential for locating new wells as they are for defining the production zones of these wells. At the Cerro Prieto geothermal field (CGCP), one of the most important geological factors is identification of the hydrothermal alteration zones (ZAH). These are divided into silica and epidote mineralogical zones (ZMSE), without CaCO{sub 3}, and silica and epidote mineralogical transition zones (ZTMSE), with CaCO{sub 3}. It has been observed that the continuous variation of reservoir thermodynamic conditions (temperature, pressure and enthalpy) is due mainly to the exploitation of geothermal resources. The presence of new thermodynamic conditions recorded at the reservoir has led to the re-location of production wells originally located during the drilling campaign of 2004 to 2006. At the geological sections on the eastern part of the CGCP, adjustments made to the well completions lie on the limits between the ZMSE and ZTMSE zones. In turn, this is related to the current, superior, thermodynamic reservoir conditions. Based on this, a new geologic approach is proposed to define possible production zones for new wells, relating the ZAH zones to current thermodynamic reservoir conditions. [Spanish] Los factores geologicos son determinantes, tanto para establecer nuevos sitios de perforacion como para determinar el intervalo productor de un pozo nuevo. En el campo geotermico de Cerro Prieto (CGCP) una de los factores mas importantes es la determinacion de las zonas de alteracion hidrotermal (ZAH) que se dividen en dos: zona mineralogica de silice y epidota (ZMSE), sin presencia de CaCO{sub 3}, y zona de transicion mineralogica de silice y epidota (ZTMSE), con presencia de CaCO{sub 3}. Por otra parte, tambien se ha constatado que la continua variacion de las condiciones termodinamicas del yacimiento (temperatura, presion y entalpia) es originada en buena medida por la explotacion del recurso geotermico. La ocurrencia de nuevas condiciones

  3. Simple model for fault-charged hydrothermal systems

    Energy Technology Data Exchange (ETDEWEB)

    Bodvarsson, G.S.; Miller, C.W.; Benson, S.M.

    1981-06-01

    A two-dimensional transient model of fault-charged hydrothermal systems has been developed. The model can be used to analyze temperature data from fault-charged hydrothermal systems, estimate the recharge rate from the fault, and determine how long the system has been under natural development. The model can also be used for theoretical studies of the development of fault-controlled hydrothermal systems. The model has been tentatively applied to the low-temperature hydrothermal system at Susanville, California. A resonable match was obtained with the observed temperature data, and a hot water recharge rate of 9 x 10{sup -6} m{sup 3}s/m was calculated.

  4. Geophysical characterization of hydrothermal systems and intrusive bodies, El Chichón volcano (Mexico)

    Science.gov (United States)

    Jutzeler, Martin; Varley, Nick; Roach, Michael

    2011-04-01

    The 1982 explosive eruptions of El Chichón volcano (Chiapas, Mexico) destroyed the inner dome and created a 1-km-wide and 180-m-deep crater within the somma crater. A shallow hydrothermal system was exposed to the surface of the new crater floor and is characterized by an acid crater lake, a geyser-like Cl-rich spring (soap pool), and numerous fumarole fields. Multiple geophysical surveys were performed to define the internal structure of the volcanic edifice and its hydrothermal system. We carried out a high-resolution ground-based geomagnetic survey in the 1982 crater and its surroundings and 38 very low frequency (VLF) transects around the crater lake. A 3-D inversion of the ground-based magnetic data set highlighted three high-susceptibility isosurfaces, interpreted as highly magnetized bodies beneath the 1982 crater floor. Inversion of a digitized regional aeromagnetic map highlighted four major deeply rooted cryptodomes, corresponding to major topographic highs and massive lava dome outcrops outside and on the somma rim. The intracrater magnetic bodies correspond closely to the active hydrothermal vents and their modeled maximum basal depth matches the elevation of the springs on the flanks of the volcano. Position, dip, and vertical extent of active and extinct hydrothermal vents identified by VLF-EM surveys match the magnetic data set. We interpret the shallow lake spring hydrothermal system to be mostly associated with buried remnants of the 550 BP dome, but the Cl-rich soap pool may be connected to a small intrusion emplaced at shallow depth during the 1982 eruption.

  5. City Car = The City Car / Andres Sevtshuk

    Index Scriptorium Estoniae

    Sevtshuk, Andres, 1981-

    2008-01-01

    Massachusettsi Tehnoloogiainstituudi (MIT) meedialaboratooriumi juures tegutseva Targa Linna Grupi (Smart City Group) ja General Motorsi koostööna sündinud kaheistmelisest linnasõbralikust elektriautost City Car. Nimetatud töögrupi liikmed (juht William J. Mitchell, töögruppi kuulus A. Sevtshuk Eestist)

  6. Characterization of on-road vehicle emissions in the Mexico City Metropolitan Area using a mobile laboratory in chase and fleet average measurement modes during the MCMA-2003 field campaign

    Science.gov (United States)

    Zavala, M.; Herndon, S. C.; Slott, R. S.; Dunlea, E. J.; Marr, L. C.; Shorter, J. H.; Zahniser, M.; Knighton, W. B.; Rogers, T. M.; Kolb, C. E.; Molina, L. T.; Molina, M. J.

    2006-11-01

    A mobile laboratory was used to measure on-road vehicle emission ratios during the MCMA-2003 field campaign held during the spring of 2003 in the Mexico City Metropolitan Area (MCMA). The measured emission ratios represent a sample of emissions of in-use vehicles under real world driving conditions for the MCMA. From the relative amounts of NOx and selected VOC's sampled, the results indicate that the technique is capable of differentiating among vehicle categories and fuel type in real world driving conditions. Emission ratios for NOx, NOy, NH3, H2CO, CH3CHO, and other selected volatile organic compounds (VOCs) are presented for chase sampled vehicles in the form of frequency distributions as well as estimates for the fleet averaged emissions. Our measurements of emission ratios for both CNG and gasoline powered "colectivos" (public transportation buses that are intensively used in the MCMA) indicate that - in a mole per mole basis - have significantly larger NOx and aldehydes emissions ratios as compared to other sampled vehicles in the MCMA. Similarly, ratios of selected VOCs and NOy showed a strong dependence on traffic mode. These results are compared with the vehicle emissions inventory for the MCMA, other vehicle emissions measurements in the MCMA, and measurements of on-road emissions in U.S. cities. We estimate NOx emissions as 100 600±29 200 metric tons per year for light duty gasoline vehicles in the MCMA for 2003. According to these results, annual NOx emissions estimated in the emissions inventory for this category are within the range of our estimated NOx annual emissions. Our estimates for motor vehicle emissions of benzene, toluene, formaldehyde, and acetaldehyde in the MCMA indicate these species are present in concentrations higher than previously reported. The high motor vehicle aldehyde emissions may have an impact on the photochemistry of urban areas.

  7. Characterization of on-road vehicle emissions in the Mexico City Metropolitan Area using a mobile laboratory in chase and fleet average measurement modes during the MCMA-2003 field campaign

    Directory of Open Access Journals (Sweden)

    M. Zavala

    2006-01-01

    Full Text Available A mobile laboratory was used to measure on-road vehicle emission ratios during the MCMA-2003 field campaign held during the spring of 2003 in the Mexico City Metropolitan Area (MCMA. The measured emission ratios represent a sample of emissions of in-use vehicles under real world driving conditions for the MCMA. From the relative amounts of NOx and selected VOC's sampled, the results indicate that the technique is capable of differentiating among vehicle categories and fuel type in real world driving conditions. Emission ratios for NOx, NOy, NH3, H2CO, CH3CHO, and other selected volatile organic compounds (VOCs are presented for chase sampled vehicles in the form of frequency distributions as well as estimates for the fleet averaged emissions. Our measurements of emission ratios for both CNG and gasoline powered "colectivos" (public transportation buses that are intensively used in the MCMA indicate that – in a mole per mole basis – have significantly larger NOx and aldehydes emissions ratios as compared to other sampled vehicles in the MCMA. Similarly, ratios of selected VOCs and NOy showed a strong dependence on traffic mode. These results are compared with the vehicle emissions inventory for the MCMA, other vehicle emissions measurements in the MCMA, and measurements of on-road emissions in U.S. cities. We estimate NOx emissions as 100 600±29 200 metric tons per year for light duty gasoline vehicles in the MCMA for 2003. According to these results, annual NOx emissions estimated in the emissions inventory for this category are within the range of our estimated NOx annual emissions. Our estimates for motor vehicle emissions of benzene, toluene, formaldehyde, and acetaldehyde in the MCMA indicate these species are present in concentrations higher than previously reported. The high motor vehicle aldehyde emissions may have an impact on the photochemistry of urban areas.

  8. Characterization of on-road vehicle emissions in the Mexico City Metropolitan Area using a mobile laboratory in chase and fleet average measurement modes during the MCMA-2003 field campaign

    Directory of Open Access Journals (Sweden)

    M. Zavala

    2006-06-01

    Full Text Available A mobile laboratory was used to measure on-road vehicle emission ratios during the MCMA-2003 field campaign held during the spring of 2003 in the Mexico City Metropolitan Area (MCMA. The measured emission ratios represent a sample of emissions of in-use vehicles under real world driving conditions for the MCMA. From the relative amounts of NOx and selected VOC's sampled, the results indicate that the technique is capable of differentiating among vehicle categories and fuel type in real world driving conditions. Emission ratios for NOx, NOy, NH3, H2CO, CH3CHO, and other selected volatile organic compounds (VOCs are presented for chase sampled vehicles and fleet averaged emissions. Results indicate that colectivos, particularly CNG-powered colectivos, are potentially significant contributors of NOx and aldehydes in the MCMA. Similarly, ratios of selected VOCs and NOy showed a strong dependence on traffic mode. These results are compared with the vehicle emissions inventory for the MCMA, other vehicle emissions measurements in the MCMA, and measurements of on-road emissions in US cities. Our estimates for motor vehicle emissions of benzene, toluene, formaldehyde, and acetaldehyde in the MCMA indicate these species are present in concentrations higher than previously reported. The high motor vehicle aldehyde emissions may have an impact on the photochemistry of urban areas.

  9. VentDB: A Global Online Synthesis Database of Seafloor Hydrothermal Spring Geochemistry

    Science.gov (United States)

    Mottl, M. J.; Lehnert, K. A.; Johansson, A. K.; Hsu, L.

    2011-12-01

    Chemical data for seafloor hydrothermal springs are fundamental to the study of mid-ocean ridge and seafloor processes, ocean water chemistry, and global geochemical cycles, as well as vent ecosystems and the sub-seafloor biosphere. So far, these data have been accessible only in the scientific literature or in online data catalogs where they are widely dispersed in individual data tables, and are often insufficiently documented for re-use. We have developed VentDB as an online data system for geochemical data for hydrothermal springs that will facilitate access and analysis of these data. VentDB uses the concept and architecture of the popular PetDB database for seafloor igneous and metamorphic rock geochemistry (www.petdb.org) to provide easy and fast access to a global synthesis of seafloor hydrothermal spring geochemical data. The VentDB database contains concentrations of major and trace species, dissolved gases, and radiogenic and isotopic ratios for hydrothermal vents on the seafloor. Further chemical or physical properties of hydrothermal springs can be included in the future if desired. The database comprises both the calculated hydrothermal end-member solution compositions as estimated by extrapolation of the concentrations of individual chemical species to a Mg concentration of zero, and the raw data for hydrothermal solution samples as collected, where available. Data quality is documented by including information for the raw analytical data about the analytical method, precision, and reference material measurements, and quality control parameters for end-member compositions including the lowest Mg measured in any sample, the number of samples and correlation coefficient of the linear regression, and the charge balance for the extrapolated zero-Mg composition. The database also includes information about the sampled locations (geospatial coordinates, vent or vent field names, names of other physiographic features), temperature, flow and vent type

  10. Challenging 'smart' in smart city strategies

    DEFF Research Database (Denmark)

    Sandvik, Kjetil; Knudsen, Jacob

    Smart city strategies concern the improvement of economic and political efficiency and the enabling of social, cultural and urban development (Hollands 2008) and covers a variety of fields from improving infrastructures, social and cultural development, resilience strategies (e.g. green energy......), improving schools, social welfare institutions, public and private institutions etc. The 'smart' in smart city strategies implies that these efforts are accomplished by the introduction and embedding of smart media technology into the very fabric of society. This is often done in a top-down and technology......-centric way (from city branding initiatives to the digitization of the public sector). This presentation will challenge this approach to smart city strategies by proposing that instead of a 'technology first' approach, we need to introduce the smart citizen in the center of smart city strategic planning...

  11. Photocatalytic Degradation of Rhodamine B Dye with High Purity Anatase Nano-TiO2 Synthesized by a Hydrothermal Method

    Institute of Scientific and Technical Information of China (English)

    SHI Xiaoliang; YANG Xingyong; WANG Shuwei; WANG Sheng; ZHANG Qiaoxin; WANG Yufu

    2011-01-01

    High purity anatase nano-TiO2 powders with high photocatalytic activity were prepared by a hydrothermal synthesis method.X-ray diffraction(XRD),field emission transmission electron microscopy (FETEM),ultraviolet-visible(UV-Vis)light absorption spectrum and photoluminescence(PL)spectrum were adopted to characterize the catalyst.Effects of temperature,time and sol concentration of hydrothermal synthesis on particle size and phases were investigated.Photocatalytic activities in the degradation of Rhodamine B Dye were studied.The experimental results indicated that photocatalytic activity of the nano-TiO2 powers was much higher than that of P25(Degussa).

  12. A Crowded City

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Over 4 million vehicles on road challenge Beijing’s city management Beijing, the city once known as the kingdom of bicycles, has become clogged with automobiles, the Beijing Municipal Government Publicity Office said on December 18.

  13. Build a Green City

    Institute of Scientific and Technical Information of China (English)

    XUYING; HAOXUE

    2005-01-01

    MA'ANSHAN,dubbed ""City of Iron and Steel,""is on the south bank of the Yangtze River in eastern Anhui Province, bordering Jiangsu Province. One of the city's most impressive features is its clean environment.

  14. The Origin of Life in Alkaline Hydrothermal Vents.

    Science.gov (United States)

    Sojo, Victor; Herschy, Barry; Whicher, Alexandra; Camprubí, Eloi; Lane, Nick

    2016-02-01

    Over the last 70 years, prebiotic chemists have been very successful in synthesizing the molecules of life, from amino acids to nucleotides. Yet there is strikingly little resemblance between much of this chemistry and the metabolic pathways of cells, in terms of substrates, catalysts, and synthetic pathways. In contrast, alkaline hydrothermal vents offer conditions similar to those harnessed by modern autotrophs, but there has been limited experimental evidence that such conditions could drive prebiotic chemistry. In the Hadean, in the absence of oxygen, alkaline vents are proposed to have acted as electrochemical flow reactors, in which alkaline fluids saturated in H2 mixed with relatively acidic ocean waters rich in CO2, through a labyrinth of interconnected micropores with thin inorganic walls containing catalytic Fe(Ni)S minerals. The difference in pH across these thin barriers produced natural proton gradients with equivalent magnitude and polarity to the proton-motive force required for carbon fixation in extant bacteria and archaea. How such gradients could have powered carbon reduction or energy flux before the advent of organic protocells with genes and proteins is unknown. Work over the last decade suggests several possible hypotheses that are currently being tested in laboratory experiments, field observations, and phylogenetic reconstructions of ancestral metabolism. We analyze the perplexing differences in carbon and energy metabolism in methanogenic archaea and acetogenic bacteria to propose a possible ancestral mechanism of CO2 reduction in alkaline hydrothermal vents. Based on this mechanism, we show that the evolution of active ion pumping could have driven the deep divergence of bacteria and archaea.

  15. Targeting organic molecules in hydrothermal environments on Mars

    Science.gov (United States)

    Parnell, J.; Bowden, S. A.; Lindgren, P.; Wilson, R.; Cooper, J. M.

    2008-09-01

    Hydrothermal deposits on Mars Hydrothermal systems are proposed as environments that could support organic synthesis, the evolution of life or the maintenance of life [1,2,3]. They have therefore been suggested as primary targets for exploration on Mars [1,2,4,].There is now confidence that hydrothermal deposits occur at the martian surface. This is based on a range of criteria that could point towards hydrothermal activity, including volcanic activity, magmatic-driven tectonism, impact cratering in icy terrains, hydrous alteration of minerals and typical hydrothermal mineralogies [4]. The proposals to search for evidence of life at martian hydrothermal sites have been focussed on seeking morphological evidence of microbial activity [5]. Here we discuss the potential to seek a chemical signature of organic matter in hydrothermal systems. Organics in terrestrial hydrothermal systems Terrestrial hydrothermal systems can have large quantities of organic matter because they intersect organic-rich sedimentary rocks or oil reservoirs. Thus the signatures that they contain reflect some preexisting concentration of fossil organic compounds, rather than life which was active in the hydrothermal system. If any extant life was incorporated in these hydrothermal systems, it is swamped by the fossil molecules. Examples of environments where organic materials may become entrained include subsurface hydrothermal mineral deposits, generation of hydrothermal systems by igneous intrusions, and hot fluid venting at the seafloor. Nevertheless, there is value in studying the interactions of hydrothermal systems with fossil organic matter, for information about the survivability of organic compounds, phase relationships between carbonaceous and noncarbonaceous materials, and where in hydrothermal deposits to find evidence of organic matter. Microbial colonization of hot spring systems is feasible at depth within the systems and at the surface where the hydrothermal waters discharge

  16. Development of micro-flow hydrothermal monitoring systems and their applications to the origin of life study on Earth.

    Science.gov (United States)

    Kawamura, Kunio

    2011-01-01

    Continuous extensive studies on thermophilic organisms have suggested that life emerged on hydrothermal systems on primitive Earth. Thus, it is well known that hydrothermal reactions are, therefore, very important to study fields deeply related to the origin-of-life study. Furthermore, the importance of hydrothermal and solvothermal systems is now realized in both fundamental and practical areas. Here, our recent investigations are described for the development of real-time and in situ monitoring systems for hydrothermal reactions. The systems were primarily developed for the origin-of-life study, but it was also applicable to fundamental and practical areas. The present techniques are based on the concept that a sample solution is injected to a narrow tubing flow reactor at high temperatures, where the sample is rapidly heated up in a very short time by exposure at to a high-temperature narrow tubing flow reactor with a very short time scale. This enables millisecond to second time-scale monitoring in real time and/or in situ at temperatures of up to 400°C. By using these techniques, a series of studies on the hydrothermal origin-of-life have been successfully carried out.

  17. Microbial control of silver mineralization at a sea-floor hydrothermal site on the northern Gorda Ridge

    Science.gov (United States)

    Zierenberg, R.A.; Schiffman, P.

    1990-01-01

    THE Sea Cliff hydrothermal field, on the northern Gorda Ridge, contains mounds and chimneys of hydrothermally precipitated sulphide and sulphate minerals typical of sea-floor hydrothermal vent sites1. In addition, large areas of the sea floor are covered by subhorizontal hydrothermal crusts. Samples of the crust recovered by submersible are composed of intensely altered fragments of basalt and basaltic hyaloclastite cemented by amorphous silica and chalcedony with less abundant barite, and minor amounts of base-metal sulphide minerals2. Some surfaces of the crust were formerly colonized by bacterial mats, which are locally preserved by replacement and overgrowth of the bacterial filaments by metal sulphide minerals and amorphous silica. The bacterial filaments are selectively replaced by prousite (Ag3AsS3), pearceite3 (Ag14.7-XCu1.3+xAs2S11), chalcopyrite (CuFeS2) and rarely by galena (PbS). Our observations suggest that bacterially mediated processes selectively precipitate silver, arsenic and copper, and that biological processes may contribute to precious-metal enrichment in some sea-floor hydrothermal base-metal sulphide deposits.

  18. Education and Human Capital Management in a World City: The Case of Singapore

    Science.gov (United States)

    Ho, K. C.; Ge, Yun

    2011-01-01

    There is considerable evidence to suggest that the human capital needs of the world city differ from what Robinson calls "ordinary cities" or what Markusen and associates term as "second tier cities". This path is blazed most notably in the field of world cities and the flow of skilled labour, in the work by Sassen and with…

  19. Effects of ionic conduction on hydrothermal hydrolysis of corn starch and crystalline cellulose induced by microwave irradiation.

    Science.gov (United States)

    Tsubaki, Shuntaro; Oono, Kiriyo; Onda, Ayumu; Yanagisawa, Kazumichi; Mitani, Tomohiko; Azuma, Jun-ichi

    2016-02-10

    This study investigated the effects of ionic conduction of electrolytes under microwave field to facilitate hydrothermal hydrolysis of corn starch and crystalline cellulose (Avicel), typical model biomass substrates. Addition of 0.1M NaCl was effective to improve reducing sugar yield by 1.61-fold at unit energy (kJ) level. Although Avicel cellulose was highly recalcitrant to hydrothermal hydrolysis, addition of 0.1M MgCl2 improved reducing sugar yield by 6.94-fold at unit energy (kJ). Dielectric measurement of the mixture of corn starch/water/electrolyte revealed that ionic conduction of electrolytes were strongly involved in facilitating hydrothermal hydrolysis of polysaccharides.

  20. The Creative Cities Network

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The Creative Cities Network, started by UNESCO in 2004, is one of the world’s highest-level non-governmental organizations in creative industry. The network focuses on the excellence of its member cities as its main product, and finds ways to maintain relevance in city life, local economy

  1. Revisiting city connectivity

    NARCIS (Netherlands)

    Mans, U.

    2014-01-01

    This article introduces a new perspective on city connectivity in order to analyze non-hub cities and their position in the world economy. The author revisits the different approaches discussed in the Global Commodity Chains (GCC), Global Production Networks (GPN) and World City Network (WCN) discou

  2. Hydrothermal synthesis of bismuth germanium oxide

    Energy Technology Data Exchange (ETDEWEB)

    Boyle, Timothy J.

    2016-12-13

    A method for the hydrothermal synthesis of bismuth germanium oxide comprises dissolving a bismuth precursor (e.g., bismuth nitrate pentahydrate) and a germanium precursor (e.g., germanium dioxide) in water and heating the aqueous solution to an elevated reaction temperature for a length of time sufficient to produce the eulytite phase of bismuth germanium oxide (E-BGO) with high yield. The E-BGO produced can be used as a scintillator material. For example, the air stability and radioluminescence response suggest that the E-BGO can be employed for medical applications.

  3. Hydrothermal Liquefaction Treatment Preliminary Hazard Analysis Report

    Energy Technology Data Exchange (ETDEWEB)

    Lowry, Peter P.; Wagner, Katie A.

    2015-08-31

    A preliminary hazard assessment was completed during February 2015 to evaluate the conceptual design of the modular hydrothermal liquefaction treatment system. The hazard assessment was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. This analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public.

  4. Smart Cities: A Survey on Security Concerns

    Directory of Open Access Journals (Sweden)

    Sidra Ijaz

    2016-02-01

    Full Text Available A smart city is developed, deployed and maintained with the help of Internet of Things (IoT. The smart cities have become an emerging phenomena with rapid urban growth and boost in the field of information technology. However, the function and operation of a smart city is subject to the pivotal development of security architectures. The contribution made in this paper is twofold. Firstly, it aims to provide a detailed, categorized and comprehensive overview of the research on security problems and their existing solutions for smart cities. The categorization is based on several factors such as governance, socioeconomic and technological factors. This classification provides an easy and concise view of the security threats, vulnerabilities and available solutions for the respective technologies areas that are proposed over the period 2010-2015. Secondly, an IoT testbed for smart cities architecture, i.e., SmartSantander is also analyzed with respect to security threats and vulnerabilities to smart cities. The existing best practices regarding smart city security are discussed and analyzed with respect to their performance, which could be used by different stakeholders of the smart cities.

  5. Resistivity structure and geochemistry of the Jigokudani Valley hydrothermal system, Mt. Tateyama, Japan

    Science.gov (United States)

    Seki, Kaori; Kanda, Wataru; Tanbo, Toshiya; Ohba, Takeshi; Ogawa, Yasuo; Takakura, Shinichi; Nogami, Kenji; Ushioda, Masashi; Suzuki, Atsushi; Saito, Zenshiro; Matsunaga, Yasuo

    2016-10-01

    This study clarifies the hydrothermal system of Jigokudani Valley near Mt. Tateyama volcano in Japan by using a combination of audio-frequency magnetotelluric (AMT) survey and hot-spring water analysis in order to assess the potential of future phreatic eruptions in the area. Repeated phreatic eruptions in the area about 40,000 years ago produced the current valley morphology, which is now an active solfatara field dotted with hot springs and fumaroles indicative of a well-developed hydrothermal system. The three-dimensional (3D) resistivity structure of the hydrothermal system was modeled by using the results of an AMT survey conducted at 25 locations across the valley in 2013-2014. The model suggests the presence of a near-surface highly conductive layer of < 50 m in thickness across the entire valley, which is interpreted as a cap rock layer. Immediately below the cap rock is a relatively resistive body interpreted as a gas reservoir. Field measurements of temperature, pH, and electrical conductivity (EC) were taken at various hot springs across the valley, and 12 samples of hot-spring waters were analyzed for major ion chemistry and H2O isotopic ratios. All hot-spring waters had low pH and could be categorized into three types on the basis of the Cl-/SO 42 - concentration ratio, with all falling largely on a mixing line between magmatic fluids and local meteoric water (LMW). The geochemical analysis suggests that the hydrothermal system includes a two-phase zone of vapor-liquid. A comparison of the resistivity structure and the geochemically inferred structure suggests that a hydrothermal reservoir is present at a depth of approximately 500 m, from which hot-spring water differentiates into the three observed types. The two-phase zone appears to be located immediately beneath the cap rock structure. These findings suggest that the hydrothermal system of Jigokudani Valley exhibits a number of factors that could trigger a future phreatic eruption.

  6. Comparative assessment of five potential sites for hydrothermal-magma systems: energy transport

    Energy Technology Data Exchange (ETDEWEB)

    Hardee, H.C.

    1980-09-01

    A comparative assessment of five sites is being prepared as part of a Continental Scientific Drilling Program (CSDP) review of thermal regimes for the purpose of scoping areas for future research and drilling activities. This background report: discusses the various energy transport processes likely to be encountered in a hydrothermal-magma system, reviews related literature, discusses research and field data needs, and reviews the sites from an energy transport viewpoint. At least three major zones exist in the magma-hydrothermal transport system: the magma zone, the hydrothermal zone, and the transition zone between the two. Major energy transport questions relate to the nature and existence of these zones and their evolution with time. Additional energy transport questions are concerned with the possible existence of critical state and super-critical state permeable convection in deep geothermal systems. A review of thermal transport models emphasizes the fact that present transport models and computational techniques far outweigh the scarcity and quality of deep field data.

  7. Hydrothermal Processes in the Archean - New Insights from Imaging Spectroscopy

    NARCIS (Netherlands)

    Ruitenbeek, F.J.A. van

    2007-01-01

    The aim of this research was to gain new insights in fossil hydrothermal systems using airborne imaging spectroscopy. Fossil submarine hydrothermal systems in Archean greenstone belts and other geologic terranes are important because of their relationship with volcanic massive sulfide (VMS) mineral

  8. PRACTICAL AND PREDICTIVE MODELLING OF ORE DEPOSITS IN HYDROTHERMAL SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    ZHAO Chong-bin; B.E.Hobbs; H.B.Muhlhaus; A.Ord

    2001-01-01

    @@ Over the past five years,we have been making efforts to develop a practical and predictive tool to explore for giant ore deposits in hydrothermal systems.Towards this goal,a significant progress has been made towards a better understanding of the basic physical and chemical processes behind ore body formation and mineralization in hydrothermal systems.

  9. PRACTICAL AND PREDICTIVE MODELLING OF ORE DEPOSITS IN HYDROTHERMAL SYSTEMS

    Institute of Scientific and Technical Information of China (English)

    ZHAO; Chong-bin; B.E.Hobbs; H.B.Muhlhaus; A.Ord

    2001-01-01

    Over the past five years,we have been making efforts to develop a practical and predictive tool to explore for giant ore deposits in hydrothermal systems.Towards this goal,a significant progress has been made towards a better understanding of the basic physical and chemical processes behind ore body formation and mineralization in hydrothermal systems.……

  10. Outdoor thermal environmental research of the mountainous city by GIS

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The study of urban outdoor thermal environment was carried out in one of the mountainous cities by using geography information system(GIS) technique which is connected with predicting and evaluating models for the outdoor thermal environment, monitoring data and simulating data. A prediction and evaluation system were set up.A typical mountainous city, i. e. , Yunyang city in Chongqing in China, was taken as an example, its urbanization trend and population growth was predicted and evaluated. The heat island intensity and its trend were simulated, the temperature field, velocity field and the humidity field were analyzed. The results show that GIS is an effective tool to deal with the outdoor thermal environment, especially for the mountainous cities with special geographical particularities. GIS can be used in the environmental management and the city planning especially for the mountainous cities.

  11. Biodiversity and biogeography of hydrothermal vent species in the western Pacific: a biological perspective of TAIGA project

    Science.gov (United States)

    Seo, M.; Watanabe, H.; Nakamura, M.; Sasaki, T.; Ogura, T.; Yahagi, T.; Takahashi, Y.; Ishibashi, J.; Kojima, S.

    2012-12-01

    Deep-sea hydrothermal vents are scientifically interesting environments where strong interactions of geology, chemistry, and biology can be observed. The hydrothermal vents are geologically controlled in association with magmatic activities while diversity of chemicals (such as hydrogen sulfide) contained in hydrothermal fluid is controlled by geochemical interaction between heated seawater and surrounding rocks. In addition to those geological and chemical characters of hydrothermal vents, high biomasses of chemosynthetic community have been known around many vents since the first discovery in the 1970s. To understand the unique system and diversity of biological communities associated with vents is highly valuable in geological, chemical, and biological sciences. As an activity of the research project "TAIGA (Trans-crustal Advection & In-situ bio-geochemical processes of Global sub-seafloor Aquifer)" (Representative: Tetsuro Urabe, Department of Earth & Planetary Science, the University of Tokyo), we analyzed population structures and connectivity as well as larval ecology of various hydrothermal vent species in the Okinawa Trough and the Mariana Trough in an attempt to estimate faunal transitional history associated with hydrothermal activities. The specimens analyzed in the present study were collected by R/V Yokosuka with manned submersible Shinkai6500 and R/V Natsushima with ROV Hyper-Dolphin during YK10-11 and NT11-20 cruises, respectively. In the Mariana Trough (YK10-11), benthic and planktonic faunas were investigated by multiple sampling and use of plankton samplers in three hydrothermal vents (Snail, Archaean, and Urashima-Pika fields). Faunal compositions were then compared as well as size compositions and genetic diversities of major vent species among local populations. In the Okinawa Trough (NT11-20), multiple quantitative sampling was made with simultaneous environmental measurements at more than two sites in five hydrothermal vents (Minami

  12. Me, the City

    Directory of Open Access Journals (Sweden)

    Konstantin Lidin

    2014-09-01

    Full Text Available The search for identity of cities looks rather urgent and attracts attention of many researchers. Addressing this issue, the article draws an analogy between a human person and a city. Like a city, a human being needs to comprehend his self-identity in order to resist depressive tendencies. It is shown that a person’s depressive symptoms are similar to those of cities. The city identity necessary to resist depression can be searched for both historically and geographically. The historical aspect consists of local myths and legends about the city and the citizens. The geographical aspect of identity comprises features of the terrain, climate, flora and fauna of the region where the city is located.

  13. BIMORPH-TYPE PIEZOELECTRIC THIN FILM BENDING ACTUATORS SYNTHESIZED BY HYDROTHERMAL METHOD

    Institute of Scientific and Technical Information of China (English)

    Du Liqun; Arai Fumihito; Fukuda Toshio; Kwon Guiryong

    2004-01-01

    Lead zirconate titanium solid-solution (PZT) thin films with various thickness are synthesized on titanium substrates by repeated hydrothermal treatments.Young modulus,electric-field- induced displacement and the density of the PZT film are measured respectively.Bimorph- type bending actuators are fabricated using these films.The model,which is used to analyze the driving ability of bimorph-type bending actuators by hydrothermal method,is set up.It can be seen that the driving ability of bimorph-type bending actuators can be greatly improved by optimizing the thickness of PZT thin film and substrate from the theoretical analysis results.The measured values are expected to agree with the theoretical values calculated by the above model.

  14. Hydrothermal synthesis of nanostructured titania; Sintese hidrotermica de ceramicas de titania nanoestruturada

    Energy Technology Data Exchange (ETDEWEB)

    Yoshito, W.K.; Ferreira, N.A.M.; Lazar, D.R.R.; Ussui, V., E-mail: wkyoshito@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Rumbao, A.C.S. [Universidade Presbiteriana Mackenzie (UPM), Sao Paulo, SP (Brazil)

    2011-07-01

    Titania ceramics have many applications due to its surface properties and, recently, its nanostructured compounds, prepared by hydrothermal treatments, have been described to improve these properties. In this work, commercial titanium dioxide was treated with 10% sodium hydroxide solution in a pressurized reactor at 150 deg C for 24 hours under vigorous stirring and then washed following two different procedures. The first one consisted of washing with water and ethanol and the second with water and hydrochloric acid solution (1%). Resulting powders were characterized by X-ray diffraction, N{sub 2} gas adsorption and field emission gun scanning and transmission electronic microscopy. Results showed that from an original starting material with mainly rutile phase, both anatase and H{sub 2}Ti{sub 3}O{sub 7} phase could be identified after the hydrothermal treatment. Surface area of powders presented a notable increase of one order of magnitude and micrographs showed a rearrangement on the microstructure of powders. (author)

  15. A super hydrophilic modification of poly(vinylidene fluoride) (PVDF) nanofibers: By in situ hydrothermal approach

    Science.gov (United States)

    Sheikh, Faheem A.; Zargar, Mohammad Afzal; Tamboli, Ashif H.; Kim, Hern

    2016-11-01

    Nanofibers fabricated from Poly(vinylidene fluoride) (PVDF) possesses potential applications in the field of filtrations, because of their excellent resistance towards harsh chemicals. However, the hydrophobicity restricts its further application. In this work, we focus on optimal parameters for post-electrospun tethering of Poly(vinyl alcohol) (PVA) as superhydrophilic domain onto each individual PVDF nanofibers by exploiting the in situ hydrothermal approach. The results indicated an increase in nanofiber diameters due to coating of PVA and improved surface wettability of PVDF nanofibers. The tensile tests of nanofibers indicated that mechanical properties of PVDF nanofibers could be sharply tuned from rigid to ductile. Furthermore, the studies strongly suggest that in situ hydrothermal treatment of post-electrospun nanofibers can improve the water contact angle and these nanofibers can be used in varied applications (e.g., in water purification systems).

  16. Assessment of rockfall hazard at Al-Noor Mountain, Makkah city (Saudi Arabia) using spatio-temporal remote sensing data and field investigation

    Science.gov (United States)

    Youssef, Ahmed M.; Pradhan, Biswajeet; Al-Kathery, Mohamed; Bathrellos, George D.; Skilodimou, Hariklia D.

    2015-01-01

    Rockfall is one of the major concerns along different urban areas and highways all over the world. Al-Noor Mountain is one of the areas that threaten rockfalls to the Al-Noor escarpment track road and the surrounding urban areas. Thousands of visitors and tourisms use the escarpment track road to visit Hira cave which is located at the top of Al-Noor Mountain. In addition, the surrounding urban areas of Al-Noor Mountain are continuously spreading over the recent years. The escarpment track road and the surrounding urban areas are highly vulnerable and suffers from recurrent rockfall mostly in the rainy season. The steep and highly jointed slope along the different faces of the mountain makes these zones prone to failure due to different actions such as weathering, erosion and anthropogenic effect. Therefore, an attempt has been made in this study to determine the Al-Noor cliff stability, by identifying the unstable areas, and to apply the rockfall simulations. A combination of remote sensing, field study and 2D computer simulation rockfall program were performed to assess surface characteristics of the cliff faces. Bounce height, total and translational kinetic energy, translational velocity, and number of blocks have been estimated. Different unstable zones along the Al-Noor Mountain and escarpment track road were determined using filed investigation and remote sensing based image analysis. In addition the rockfall simulation analysis indicated that rockfall in zone 1 and zone 2 of the Al-Noor Mountain may reach the urban areas, whereas rockfall in zone 3 will not reach the urban areas, and rockfalls along the Al-Noor escarpment track road will have highly impact on the tourists. Proper preventive measures are also suggested to arrest the movement of falling rocks before reaching the urban areas and the Al-Noor escarpment track road. If proper care is taken, then further uncertain rockfall hazards can be prevented.

  17. Weed Characteristics and Control Strategies in Wheat Fields in Yangzhou City%扬州市麦田草相特点及杂草防除对策

    Institute of Scientific and Technical Information of China (English)

    杨进; 刘学儒; 丁涛; 秦玉金; 焦骏森

    2014-01-01

    为了摸清扬州地区麦田杂草种类、分布状况,通过倒“W”形九点取样法调查,结果表明麦田杂草有26科81种,其中里下河地区优势种为日本看麦娘、牛繁缕、菵草等;沿江地区优势种为菵草、日本看麦娘、牛繁缕等;丘陵山区优势种为日本看麦娘、猪秧秧、野老鹳等;同时发现当前存在着杂草抗药性增强、防治技术不到位等方面问题,提出了强抓土壤封闭处理、合理选用除草剂及开展技术宣传培训等对策。%Weed species and their distribution in wheat fields in Yangzhou area were determined by sampling nine plots according to a“W” pattern.Weeds belonged to 81 species of 26 families.The dominant species in Lixiahe region and the area along the Yangtze River were Alopecurus japonicus Steud.,Malachium aquaticum ( L.) Fries., and Beckmannia syzigachne ( Steud.) Fernald, whereas A.japonicus Steud.,Galium aparine L.and Geranium carolinianum L.were dom-inant in hilly areas.Currently,problems with herbicide resistant weeds are becoming more serious and outdated control technologies must be improved.Therefore,a series of control strategies are proposed including improving the use of resid-ual soil applied herbicides,judicious selection of herbicides and carrying out technical outreach and training.

  18. Green Ocean Amazon 2014/15 High-Volume Filter Sampling: Atmospheric Particulate Matter of an Amazon Tropical City and its Relationship to Population Health Field Campaign Report

    Energy Technology Data Exchange (ETDEWEB)

    Machado, C. M. [Federal Univ. of Amazonas (Brazil); Santos, Erickson O. [Federal Univ. of Amazonas (Brazil); Fernandes, Karenn S. [Federal Univ. of Amazonas (Brazil); Neto, J. L. [Federal Univ. of Amazonas (Brazil); Souza, Rodrigo A. [Univ. of the State of Amazonas (Brazil)

    2016-08-01

    Manaus, the capital of the Brazilian state of Amazonas, is developing very rapidly. Its pollution plume contains aerosols from fossil fuel combustion mainly due to vehicular emission, industrial activity, and a thermal power plant. Soil resuspension is probably a secondary source of atmospheric particles. The plume transports from Manaus to the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility ARM site at Manacapuru urban pollutants as well as pollutants from pottery factories along the route of the plume. Considering the effects of particulate matter on health, atmospheric particulate matter was evaluated at this site as part of the ARM Facility’s Green Ocean Amazon 2014/15 (GoAmazon 2014/15) field campaign. Aerosol or particulate matter (PM) is typically defined by size, with the smaller particles having more health impact. Total suspended particulate (TSP) are particles smaller than 100 μm; particles smaller than 2.5 μm are called PM2.5. In this work, the PM2.5 levels were obtained from March to December of 2015, totaling 34 samples and TSP levels from October to December of 2015, totaling 17 samples. Sampling was conducted with PM2.5 and TSP high-volume samplers using quartz filters (Figure 1). Filters were stored during 24 hours in a room with temperature (21,1ºC) and humidity (44,3 %) control, in order to do gravimetric analyses by weighing before and after sampling. This procedure followed the recommendations of the Brazilian Association for Technical Standards local norm (NBR 9547:1997). Mass concentrations of particulate matter were obtained from the ratio between the weighted sample and the volume of air collected. Defining a relationship between particulate matter (PM2.5 and TSP) and respiratory diseases of the local population is an important goal of this project, since no information exists on that topic.

  19. Nutritional strategies of the hydrothermal ecosystem bivalves

    Science.gov (United States)

    Le Pennec, Marcel; Donval, Anne; Herry, Angèle

    Studies of deep-sea hydrothermal bivalves have revealed that the species, which are strictly dependent upon the interstitial fluid emissions, derive their food indirectly via symbiotic relationships with chemosynthetic bacteria present in their gill tissues. As the gill plays the main trophic role, structural and ultrastructural modifications occur in the digestive tract. Scanning and transmission electron microscope studies reveal that the digestive system of species belonging to the genera Calyptogena, Bathymodiolus and Bathypecten have anatomical differences. In Calyptogena, the reduction of several parts of the digestive tract and the stomach content which is either empty or full, according to the various species examined indicate that the digestive system is hardly if at all functional. In Bathymodiolus, the labial palps are well developed, the stomach is always full with particles and the two cellular types, digestive and secretory, are present in the digestive gland. All these characteristics indicate that the digestive system is functional. In Bathypecten, the digestive tract is well developed and it seems that it plays the main trophic role. We conclude that the nutritional strategies of the hydrothermal vents bivalves are quite varied. They range from a normal trophic process, through a mixotrophic diet, to one based purely on chemoautotrophic bacteria. The strategy of each species is adapted to and influences its distribution.

  20. Hydrothermal Liquefaction of Wastewater Treatment Plant Solids

    Energy Technology Data Exchange (ETDEWEB)

    Billing, Justin M.

    2016-10-16

    Feedstock cost is the greatest barrier to the commercial production of biofuels. The merits of any thermochemical or biological conversion process are constrained by their applicability to the lowest cost feedstocks. At PNNL, a recent resource assessment of wet waste feedstocks led to the identification of waste water treatment plant (WWTP) solids as a cost-negative source of biomass. WWTP solids disposal is a growing environmental concern [1, 2] and can account for up to half of WWTP operating costs. The high moisture content is well-suited for hydrothermal liquefaction (HTL), avoiding the costs and parasitic energy losses associated with drying the feedstock for incineration. The yield and quality of biocrude and upgraded biocrude from WWTP solids is comparable to that obtained from algae feedstocks but the feedstock cost is $500-1200 less per dry ton. A collaborative project was initiated and directed by the Water Environment & Reuse Foundation (WERF) and included feedstock identification, dewatering, shipping to PNNL, conversion to biocrude by HTL, and catalytic hydrothermal gasification of the aqueous byproduct. Additional testing at PNNL included biocrude upgrading by catalytic hydrotreatment, characterization of the hydrotreated product, and a preliminary techno-economic analysis (TEA) based on empirical results. This short article will cover HTL conversion and biocrude upgrading. The WERF project report with complete HTL results is now available through the WERF website [3]. The preliminary TEA is available as a PNNL report [4].

  1. Hydrothermal carbonization and torrefaction of grape pomace: a comparative evaluation.

    Science.gov (United States)

    Pala, Mehmet; Kantarli, Ismail Cem; Buyukisik, Hasan Baha; Yanik, Jale

    2014-06-01

    Grape pomace was treated by hydrothermal carbonization (sub-critical water, 175-275°C) and torrefaction (nitrogen atmosphere, 250 and 300°C), with mass yield of solid product (char) ranging between 47% and 78%, and energy densification ratio to 1.42-1.15 of the original feedstock. The chars were characterised with respect to their fuel properties, morphological and structural properties and combustion characteristics. The hydrothermal carbonization produced the char with greater energy density than torrefaction. The chars from torrefaction were found to be more aromatic in nature than that from hydrothermal carbonization. Hydrothermal carbonization process produced the char having high combustion reactivity. Most interesting was the finding that aqueous phase from hydrothermal carbonization had antioxidant activity. The results obtained in this study showed that HTC appears to be promising process for a winery waste having high moisture content.

  2. Macrofauna of shallow hydrothermal vents on the Arctic Mid-Ocean Ridge at 71N

    Science.gov (United States)

    Schander, C.; Rapp, H. T.; Pedersen, R. B.

    2007-12-01

    Deep-sea hydrothermal vents are usually associated with a highly specialized fauna and since their discovery in 1977, more than 400 species of animals have been described. Specialized vent fauna includes various animal phyla, but the most conspicuous and well known are annelids, mollusks and crustaceans. We have investigated the fauna collected around newly discovered hydrothermal vents on the Mohns Ridge north of Jan Mayen. The venting fields are located at 71°N and the venting takes place within two main areas separated by 5 km. The shallowest vent area is at 500-550 m water depth and is located at the base of a normal fault. This vent field stretches approximately 1 km along the strike of the fault, and it is composed of 10-20 major vent sites each with multiple chimney constructions discharging up to 260°C hot fluids. A large area of diffuse, low- temperature venting occurs in the area surrounding the high-temperature field. Here, partly microbial mediated iron-oxide-hydroxide deposits are abundant. The hydrothermal vent sites do not show any high abundance of specialized hydrothermal vent fauna. Single groups (i.e. Porifera and Mollusca) have a few representatives but groups otherwise common in hydrothermal vent areas (e.g. vestimentifera, Alvinellid worms, mussels, clams, galathaeid and brachyuran crabs) are absent. Up until now slightly more than 200 species have been identified from the vent area. The macrofauna found in the vent area is, with few exceptions, an assortment of bathyal species known in the area. One endemic, yet undescribed, species of mollusc has been found so far, an gastropod related to Alvania incognita Warén, 1996 and A. angularis Warén, 1996 (Rissoidae), two species originally described from pieces of sunken wood north and south of Iceland. It is by far the most numerous mollusc species at the vents and was found on smokers, in the bacterial mats, and on the ferric deposits. A single specimen of an undescribed tanaidacean has also

  3. Current state of the hydrothermal geochemistry studies at Cerro Prieto

    Energy Technology Data Exchange (ETDEWEB)

    Fausto L, J.J.; Jimenez S, M.E.; Esquer P, I.

    1981-01-01

    The current state of hydrothermal geochemistry studies being carried out at the field are reported. These studies are based on the results of chemical analysis of water samples collected during 1979 and 1980 at the geothermal wells of the area known as Cerro Prieto I, as well as from those located in the Cerro Prieto II and Cerro Prieto III areas, some of which have only recently started flowing. Data are presented on the chemical variations of the main chemical constituents dissolved in the waters, as well as on the Na/K and Na-K-Ca chemical relations and the temperatures calculated from them and from SiO/sub 2/. Fluid recharge into the reservoir and its direction of flow are interpreted from isotherm contour maps of the field prepared from Na/K and Na-K-Ca geothermometry and from concentration contour maps of some of the main chemical constituents. Well M-43 is discussed as an example of a well affected by well completion problems in its production casing. Its behavior is explained on the basis of the chemical characteristics of the produced water. The chemical changes that have taken place in some of the wells during production are explained by correlating the chemistry with the production mechanisms of the well (steam-water production rates).

  4. ConnectiCity, augmented perception of the city

    CERN Document Server

    Iaconesi, Salvatore

    2012-01-01

    As we move through cities in our daily lives, we are in a constant state of transformation of the spaces around us. The form and essence of urban space directly affects people's behavior, describing in their perception what is possible or impossible, allowed or prohibited, suggested or advised against. We are now able to fill and stratify space/time with digital information layers, completely wrapping cities in a membrane of information and of opportunities for interaction and communication. Mobile devices, smartphones, wearables, digital tags, near field communication devices, location based services and mixed/augmented reality have gone much further in this direction, turning the world into an essentially read/write, ubiquitous publishing surface. The usage of mobile devices and ubiquitous technologies alters the understanding of place. In this process, the definition of (urban) landscape powerfully shifts from a definition which is purely administrative (e.g.: the borders of the flower bed in the middle of...

  5. City Carbon Footprint Networks

    Directory of Open Access Journals (Sweden)

    Guangwu Chen

    2016-07-01

    Full Text Available Progressive cities worldwide have demonstrated political leadership by initiating meaningful strategies and actions to tackle climate change. However, the lack of knowledge concerning embodied greenhouse gas (GHG emissions of cities has hampered effective mitigation. We analyse trans-boundary GHG emission transfers between five Australian cities and their trading partners, with embodied emission flows broken down into major economic sectors. We examine intercity carbon footprint (CF networks and disclose a hierarchy of responsibility for emissions between cities and regions. Allocations of emissions to households, businesses and government and the carbon efficiency of expenditure have been analysed to inform mitigation policies. Our findings indicate that final demand in the five largest cities in Australia accounts for more than half of the nation’s CF. City households are responsible for about two thirds of the cities’ CFs; the rest can be attributed to government and business consumption and investment. The city network flows highlight that over half of emissions embodied in imports (EEI to the five cities occur overseas. However, a hierarchy of GHG emissions reveals that overseas regions also outsource emissions to Australian cities such as Perth. We finally discuss the implications of our findings on carbon neutrality, low-carbon city concepts and strategies and allocation of subnational GHG responsibility.

  6. The Guaymas Basin hiking guide to hydrothermal mounds, chimneys and microbial mats: complex seafloor expressions of subsurface hydrothermal circulation

    Directory of Open Access Journals (Sweden)

    Andreas eTeske

    2016-02-01

    Full Text Available The hydrothermal mats, mounds and chimneys of the southern Guaymas Basin are the surface expression of complex subsurface hydrothermal circulation patterns. In this overview we document the most frequently visited features of this hydrothermal area with photographs, temperature measurements, and selected geochemical data; many of these distinct habitats await characterization of their microbial communities and activities. Microprofiler deployments on microbial mats and hydrothermal sediments show their steep geochemical and thermal gradients at millimeter-scale vertical resolution. Mapping these hydrothermal features and sampling locations within the southern Guaymas Basin suggest linkages to underlying shallow sills and heatflow gradients. Recognizing the inherent spatial limitations of much current Guaymas Basin sampling calls for a wider survey of the entire spreading region.

  7. Urban Fields in the making

    DEFF Research Database (Denmark)

    Hovgesen, Henrik Harder; Nielsen, Thomas Alexander Sick

    A recent study of transportation and urban structure in a larger Danish city concludes that the location vis-à-vis attractions far beyond the city borders, has a detectable bearing on the inhabitants transport patterns inside the city. This indicates a high degree of functional integration between...... cities and accentuates the concept of the ?urban field? suggested by John Friedmann (1978). The concept of ?urban field? suggest that mobility has been democratizised and increased to a level where several cities can be part of the same functionally integrated urban field. As a consequence...... the significance of the single urban centre and the city as an entity will change markedly. This paper aims to analyse the development towards urban travel- and commuter fields in Denmark. The question asked is to what degree urban fields are emerging? ? And what is the speed of this development....

  8. Numerical Modeling of Multiphase Fluid Flow in Ore-Forming Hydrothermal Systems

    Science.gov (United States)

    Weis, P.; Driesner, T.; Coumou, D.; Heinrich, C. A.

    2007-12-01

    Two coexisting fluid phases - a variably saline liquid and a vapor phase - are ubiquitous in ore-forming and other hydrothermal systems. Understanding the dynamics of phase separation and the distinct physical and chemical evolution of the two fluids probably plays a key role in generating different ore deposit types, e.g. porphyry type, high and low sulfidation Cu-Mo-Au deposits. To this end, processes within hydrothermal systems have been studied with a refined numerical model describing fluid flow in transient porous media (CSP~5.0). The model is formulated on a mass, energy and momentum conserving finite-element-finite-volume (FEFV) scheme and is capable of simulating multiphase flow of NaCl-H20 fluids. Fluid properties are computed from an improved equation of state (SOWAT~2.0). It covers conditions with temperatures of up to 1000 degrees~C, pressures of up to 500 MPa, and fluid salinities of 0~to 100%~NaCl. In particular, the new set-up allows for a more accurate description of fluid phase separation during boiling of hydrothermal fluids into a vapor and a brine phase. The geometric flexibility of the FEFV-meshes allows for investigations of a large variety of geological settings, ranging from ore-forming processes in magmatic hydrothermal system to the dynamics of black smokers at mid-ocean ridges. Simulations demonstrated that hydrothermal convection patterns above cooling plutons are primarily controlled by the system-scale permeability structure. In porphyry systems, high fluid pressures develop in a stock rising from the magma chamber which can lead to rock failure and, eventually, an increase in permeability due to hydrofracturing. Comparisons of the thermal evolution as inferred from modeling studies with data from fluid inclusion studies of the Pb-Zn deposits of Madan, Bulgaria are in a strikingly good agreement. This indicates that cross-comparisons of field observations, analytical data and numerical simulations will become a powerful tool towards a

  9. Entropy Production in Convective Hydrothermal Systems

    Science.gov (United States)

    Boersing, Nele; Wellmann, Florian; Niederau, Jan

    2016-04-01

    Exploring hydrothermal reservoirs requires reliable estimates of subsurface temperatures to delineate favorable locations of boreholes. It is therefore of fundamental and practical importance to understand the thermodynamic behavior of the system in order to predict its performance with numerical studies. To this end, the thermodynamic measure of entropy production is considered as a useful abstraction tool to characterize the convective state of a system since it accounts for dissipative heat processes and gives insight into the system's average behavior in a statistical sense. Solving the underlying conservation principles of a convective hydrothermal system is sensitive to initial conditions and boundary conditions which in turn are prone to uncertain knowledge in subsurface parameters. There exist multiple numerical solutions to the mathematical description of a convective system and the prediction becomes even more challenging as the vigor of convection increases. Thus, the variety of possible modes contained in such highly non-linear problems needs to be quantified. A synthetic study is carried out to simulate fluid flow and heat transfer in a finite porous layer heated from below. Various two-dimensional models are created such that their corresponding Rayleigh numbers lie in a range from the sub-critical linear to the supercritical non-linear regime, that is purely conductive to convection-dominated systems. Entropy production is found to describe the transient evolution of convective processes fairly well and can be used to identify thermodynamic equilibrium. Additionally, varying the aspect ratio for each Rayleigh number shows that the variety of realized convection modes increases with both larger aspect ratio and higher Rayleigh number. This phenomenon is also reflected by an enlarged spread of entropy production for the realized modes. Consequently, the Rayleigh number can be correlated to the magnitude of entropy production. In cases of moderate

  10. Serpentinization-assisted deformation processes and characterization of hydrothermal fluxes at mid-ocean ridges

    Science.gov (United States)

    Genc, Gence

    Seafloor hydrothermal systems play a significantly important role in Earth’s energy and geochemical budgets and support the existence and development of complex biological ecosystems by providing nutrient and energy to microbial and macrafaunal ecosystems through geochemical fluxes. Heat output and fluid flow are key parameters which characterize hydrothermal systems at oceanic spreading centers by constraining models of hydrothermal circulation. Although integrated measurements of heat flux in plumes are critically important as well, quantification of heat flux at discrete sources (vent orifices versus patches of seafloor shimmering diffuse flow) from direct measurements is particularly essential for examining the partitioning of heat flow into focused and diffuse components of venting and determining geochemical fluxes from these two modes of flow. Hydrothermal heat output also constrains the permeability of young oceanic crust and thickness of the conductive boundary layer that separates magmatic heat source from overlying hydrothermal circulation. This dissertation will be fundamentally focused on three main inter-connected topics: (1) the design and development of direct high- or low-temperature heat flow measuring devices for hydrothermal systems, (2) the collection of new heat output results on four cruises between 2008 and 2010 at several distinct hydrothermal sites along mid-ocean ridges (MORs) to estimate total heat output from individual vent structures such as Dante, Hulk or the whole vent field (e.g., Main Endeavour Vent Field (MEF)), the partitioning between focused and diffuse hydrothermal venting in MEF, and determination of initial estimates of geochemical flux from diffuse hydrothermal fluids which may be influenced by the activity in subsurface biosphere and finally (3) the deformation and uplift associated with serpentinization at MORs and subduction zones. Despite extensive efforts spent for the last couple of decades on heat flow measurement

  11. Cities as development drivers

    DEFF Research Database (Denmark)

    Johnson, Bjørn; Poulsen, Tjalfe; Hansen, Jens Aage

    2011-01-01

    for innovative problem solving and potential spill-over effects, which may stimulate further economic growth and development. This paper discusses how waste problems of cities can be transformed to become part of new, more sustainable solutions. Two cases are explored: Aalborg in Denmark and Malmö in Sweden....... It is shown that the cities have the potential to significantly contribute to a more sustainable development through increased material recycling and energy recovery. Waste prevention may increase this potential. For example, instead of constituting 3% of the total greenhouse gas emission problem, it seems......There is a strong connection between economic growth and development of cities. Economic growth tends to stimulate city growth, and city economies have often shaped innovative environments that in turn support economic growth. Simultaneously, social and environmental problems related to city growth...

  12. Physical controls on mixing and transport within rising submarine hydrothermal plumes: A numerical simulation study

    Science.gov (United States)

    Jiang, Houshuo; Breier, John A.

    2014-10-01

    A computational fluid dynamics (CFD) model was developed to simulate the turbulent flow and species transport of deep-sea high temperature hydrothermal plumes. The model solves numerically the density weighted unsteady Reynolds-averaged Navier-Stokes equations and energy equation and the species transport equation. Turbulent entrainment and mixing is modeled by a k-ε turbulence closure model. The CFD model explicitly considers realistic vent chimney geometry, vent exit fluid temperature and velocity, and background stratification. The model uses field measurements as model inputs and has been validated by field data. These measurements and data, including vent temperature and plume physical structure, were made in the ABE hydrothermal field of the Eastern Lau Spreading Center. A parametric sensitivity study based on this CFD model was conducted to determine the relative importance of vent exit velocity, background stratification, and chimney height on the mixing of vent fluid and seawater. The CFD model was also used to derive several important scalings that are relevant to understanding plume impact on the ocean. These scalings include maximum plume rise height, neutrally buoyant plume height, maximum plume induced turbulent diffusivity, and total plume vertically transported water mass flux. These scaling relationships can be used for constructing simplified 1-dimensional models of geochemistry and microbial activity in hydrothermal plumes. Simulation results show that the classical entrainment assumptions, typically invoked to describe hydrothermal plume transport, only apply up to the vertical level of ~0.6 times the maximum plume rise height. Below that level, the entrainment coefficient remains relatively constant (~0.15). Above that level, the plume flow consists of a pronounced lateral spreading flow, two branches of inward flow immediately above and below the lateral spreading, and recirculation flanking the plume cap region. Both turbulent kinetic energy

  13. Tuning photoluminescence of organic rubrene nanoparticles through a hydrothermal process

    Directory of Open Access Journals (Sweden)

    Jung Hyunjung

    2011-01-01

    Full Text Available Abstract Light-emitting 5,6,11,12-tetraphenylnaphthacene (rubrene nanoparticles (NPs prepared by a reprecipitation method were treated hydrothermally. The diameters of hydrothermally treated rubrene NPs were changed from 100 nm to 2 μm, depending on hydrothermal temperature. Photoluminescence (PL characteristics of rubrene NPs varied with hydrothermal temperatures. Luminescence of pristine rubrene NPs was yellow-orange, and it changed to blue as the hydrothermal temperature increased to 180°C. The light-emitting color distribution of the NPs was confirmed using confocal laser spectrum microscope. As the hydrothermal temperature increased from 110°C to 160°C, the blue light emission at 464 to approximately 516 nm from filtered-down NPs was enhanced by H-type aggregation. Filtered-up rubrene NPs treated at 170°C and 180°C exhibited blue luminescence due to the decrease of intermolecular excimer densities with the rapid increase in size. Variations in PL of hydrothermally treated rubrene NPs resulted from different size distributions of the NPs.

  14. Hydrothermal carbonization of anaerobically digested maize silage.

    Science.gov (United States)

    Mumme, Jan; Eckervogt, Lion; Pielert, Judith; Diakité, Mamadou; Rupp, Fabian; Kern, Jürgen

    2011-10-01

    Hydrochars were prepared by hydrothermal carbonization (HTC) of maize silage previously treated at 55 °C in a two-stage solid-state reactor system. The HTC was carried out in a 1-L stirred pressure reactor with pH regulation by citric acid. The treated silage carbonized at relatively mild conditions (190 °C, 2 h), and the hydrochars showed mainly amorphous macro-size features with a carbon content of 59-79% (ash-free, dry) and a higher heating value of 25-36 MJ kg⁻¹. Temperature was the main influencing factor. The surface area according to Brunauer-Emmett-Teller (BET) analysis was highest at 190 °C (12.3 m²) g⁻¹). Based on these results, the hydrochars are potentially interesting for applications such as an alternative fuel or a soil conditioner.

  15. Hydrothermal pretreatment of biomass for pellet production

    Energy Technology Data Exchange (ETDEWEB)

    Tooyserkani, Z. [British Columbia Univ., Vancouver, BC (Canada). Clean Energy Research Centre, Biomass and Bioenergy Research Group

    2010-07-01

    This presentation discussed innovative technologies for the production of wood pellets using the hydrothermal pre-treatment of biomass. Conventional techniques use low-cost mill residues, such as saw dust and shavings, as feedstock to produce durable, low-ash pellets. However, mill residues are becoming less available as a result of fewer saw mills, increased pellet production, and increased competition for saw dust. Advanced techniques use mixed biomass such as logging residue as feedstock, creating pellets that are durable for handling and long-term storage, of a higher energy density for transport and mixing with coal for co-firing, and a choice feedstock for biofuels. Advanced pellet production uses steam explosion/pre-treatment in which biomass receives a short-term high-pressure steam treatment followed by sudden decompression. Mild torrefaction seems to have positive feedback, and steam-treated pellets are durable with superior hydrophobicity. 3 figs., 3 tabs.

  16. EU Smart City Governance

    Directory of Open Access Journals (Sweden)

    Carmela Gargiulo

    2013-11-01

    Full Text Available In recent years European Commission has developed a set of documents for Members States tracing, directly or indirectly, recommendations for the transformation of the European city. The paper wants to outline which future EU draws for the city, through an integrated and contextual reading of addresses and strategies contained in the last documents, a future often suggested as Smart City. Although the three main documents (Cohesion Policy 2014-2020 of European Community, Digital Agenda for Europe and European Urban Agenda face the issue of the future development of European cities from different points of view, which are respectively cohesion social, ICT and urban dimension, each of them pays particular attention to urban and territorial dimension, identified by the name of Smart City. In other words, the paper aims at drawing the scenario of evolution of Smart Cities that can be delineated through the contextual reading of the three documents. To this end, the paper is divided into three parts: the first part briefly describes the general contents of the three European economic plan tools; the second part illustrates the scenarios for the future of the European city contained in each document; the third part seeks to trace the evolution of the Smart Cities issue developed by the set of the three instruments, in order to provide the framework of European Community for the near future of our cities

  17. Different Creative Cities

    DEFF Research Database (Denmark)

    Lorenzen, Mark; Vaarst Andersen, Kristina

    2012-01-01

    and exhibits a tendency of congregating in major cities with diverse service and cultural offers and tolerance to non-mainstream lifestyles. However, we find that a range of smaller Danish cities also attract the creative class. Second, we undertake qualitative interviews that facilitate theory building. We...... suggest that many creatives are attracted by the smaller cities' cost advantages, specialized job offers, attractive work/life balances, and authenticity and sense of community. The article synthesizes its results into four stylized types of creative cities, and concludes by discussing the policy...

  18. Suburbs and Cities

    OpenAIRE

    William N. Goetzmann; Matthew I. Spiegel; Susan M. Wachter

    1996-01-01

    This paper addresses the issue of how closely the fortunes of suburbs are tied to the fortunes of the central city. We use similarities in residential housing price dynamics as a measure of how closely the economies of cities and suburbs are related. We develop housing price indices for most of the zip codes in California, and use these in a clustering procedure to see whether cities and suburbs naturally aggregate together, or whether they move separately. We find that central cities tend to...

  19. FY 2000 report on the results of the regional consortium R and D project - Regional consortium energy field. Second year report. Development of the energy saving manufacturing process of smart materials having electromagnetic wave absorbing function using the microwave-hydrothermal method; 2000 nendo chiiki consortium kenkyu kaihatsu jigyo - chiiki contortium energy bun'ya. Micro ha - suinetsuho wo riyoshita denjiha kyushu kino wo yusuru smart zairyo no sho energy gata seizo process no kaihatsu (dai 2 nendo) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The development was proceeded with of electromagnetic wave absorbing materials (board) which dispersed carbon fiber as conducting material and ferrite as magnetic material to matrices such as resin and cement. With the multi-layer structure as a basis, the material has wave absorbing ability in the area of 300MHz-60GHz band. The material is presumed to be applied to wall construction use materials and bodies of electronic equipment since it prevents the radio wave reflection caused by structures such as bridges. Ferrite was synthesized by microwave-hydrothermal method (500kPa, 2.54GHz). Further, carbon fiber was covered with ferrite for improvement of absorption characteristics. Studies were made in the following 5 fields: 1) design of smart materials and development of hybrid process technology; 2) study on the evaluation of wave absorbing function; 3) R and D of the manufacturing process of smart forming materials; 4) development of the fiber surface processing process using ocean resource; 5) comprehensive investigational study. In 1), study was conducted on relations among electromagnetic shielding characteristics of the ferrite-covering carbon fiber, fiber length and fiber content. (NEDO)

  20. Efficiencies of Power Plants Using Hydrothermal Oxidation

    Science.gov (United States)

    Hirosaka, Kazuma; Yuvamitra, Korakot; Ishikawa, Akira; Hasegawa, Tatsuya

    Wet biomass is hard to handle as a fuel for power plants because it contains high moisture and its drying process needs more energy input than it produces. Hydrothermal oxidation could be one of the promising technologies to overcome this problem because this process does not need drying process at all. We focus on recovery of thermal energy produced by hydrothermal oxidation of wet biomass. Two kinds of power plant are investigated, a direct type and an indirect type. In the direct type power plant, reactant is oxidized in a reactor and directly flowed into a turbine. In the indirect type power plant, reactant is oxidized in a reactor and the reaction heat is conveyed to the main water, which is flowed into a turbine. The amount of electric power and the energy conversion efficiency are calculated by using ethanol, glucose and peat solutions as reactants. In both type of power plant, one steam turbine is employed for generating electricity with the maximum turbine inlet temperature of 650 °C. As ethanol concentration increased, the amount of electric power and the energy conversion efficiency become higher. The maximum efficiency for the direct type power plant using ethanol solution is about 26.4 % for 17.6 wt% at the reactor pressure of 10 MPa. The efficiency of the indirect type power plant is much lower than that of the direct type, but by pressurizing main water up to 4 MPa, the efficiency becomes higher up to 20.9 %. For glucose solution, the maximum efficiency for the direct type is about 25.5 % for 34.5 wt% at the reactor pressure of 5 MPa. The maximum efficiency of the indirect type at the main water pressure of 4 MPa is about 21.1 % for 40.7 wt%. For peat solution, only the indirect type is investigated. The maximum efficiency at the main water pressure of 4 MPa is about 20.8 % for 36.8 wt%.

  1. Peptide synthesis under Enceladus hydrothermal condition

    Science.gov (United States)

    Fujishima, Kosuke; Takano, Yoshinori; Takai, Ken; Takahagi, Wataru; Adachi, Keito; Shibuya, Takazo; Tomita, Masaru

    2016-07-01

    Enceladus is one of the moons of Saturn, and it has been known to harbor interior ocean beneath the icy crust. The mass spectrometry data obtained by Cassini spacecraft indicates the presence of salty, and most likely alkaline ocean containing various organic compounds. While geochemical and other radiation related processes for in situ production of organics remain elusive, thermally unaltered carbonaceous chondrites, consisting the main body of Enceladus are known to be enriched with organic matters potentially including the building blocks of life (e.g., amino acids and amino acid precursors). Assuming that abiotic amino acids exist in the Enceladus alkaline seawater, we hypothesized that water-rock interaction may contribute to condensation of localized amino acids leading to peptide formation. In order to test this hypothesis, we have developed the Enceladus hydrothermal reactor based on the chemical constraints obtained through previous experimental and theoretical studies. We have added six different amino acids and introduced a thermal fluctuation system simulating the periodic tidal heating of the interior chondritic core. Total, eight sea water samples were obtained over the course of 147 days of experiment. While detection of peptide using Capillary Electrophoresis Time-of-Flight Mass Spectrometry (CE-TOF/MS) is still at the preliminary stage, so far pH monitoring and H2 and CO2 Gas Chromatography Mass Spectrometry (GC-MS) data clearly indicated the occurrence of serpentinization/carbonation reaction. Here, we discuss the interaction between aqueous alteration reactions and thermal cycling processes for the role of abiotic peptide formation under the Enceladus hydrothermal condition.

  2. Mechatronic integration and implementation of in situ multipoint temperature measurement for seafloor hydrothermal vent

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    In order to provide firsthand reference data for model building and analysis of temperature field of seafloor hydrothermal vent, a temperature measurement sys- tem is designed, which can be used to measure the temperature of seafloor hydrothermal vent. The system can implement in situ multipoint temperature measurement and work for 15 days on the seafloor, so low power consumption design principle of the integrated circuit board is adopted. To enable the system to endure the high pressure on the seafloor, mechanical structure of the system is designed in terms of design principle of pressure container. The pressure test ex- periment was performed in the authoritative institution, and the results indicated that the system was safe and could work reliably on the seafloor. In the first Sino-American Joint Dive Cruise, the instruments were carried to the seafloor to work by Alvin. The experiment in the sea was successful, and the results indicated that the system could survive in the high pressure and high temperature environ- ment and record the temperature activities of hydrothermal vents. About 710000 groups of temperature data were acquired, and these are of importance for further scientific researches.

  3. Synthesis and electrochemical performance of Ti3C2Tx with hydrothermal process

    Science.gov (United States)

    Wang, Libo; Zhang, Heng; Wang, Bo; Shen, Changjie; Zhang, Chuanxiang; Hu, Qianku; Zhou, Aiguo; Liu, Baozhong

    2016-09-01

    In this study, a simple hydrothermal method has been developed to prepare Ti3C2Tx from Ti3AlC2 as a high-performance electrode material for supercapacitors. This method is environmentally friendly and has a low level of danger. The morphology and structure of the Ti3C2Tx can be controlled by hydrothermal reaction time, temperature and NH4F amounts. The prepared Ti3C2Tx was characterized by X-ray diffraction, field emission scanning electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy and Brunauer-Emmet-Teller. The results show that the prepared Ti3C2Tx is terminated by O, OH, and F groups. The electrochemical properties of the Ti3C2Tx sample exhibit specific capacitance up to 141 Fcm-3 in 3 M KOH aqueous electrolyte, and even after 1000 cycles, no significant degradation of the volumetric capacitance was observed. These results indicate that the Ti3C2Tx material prepared by this hydrothermal method can be used in high performance supercapacitors.

  4. Controlled growth of well-aligned ZnO nanowire arrays using the improved hydrothermal method

    Institute of Scientific and Technical Information of China (English)

    Han Zhitao; Li Sisi; Chu Jinkui; Chen Yong

    2013-01-01

    Well-aligned ZnO nanowires were hydrothermally synthesized based on a facile method for preparing the ZnO seed layer which was derived from the combination of a sol-gel process and the spin-coating technique.The effect of the contents of growth solution and the growth duration on the morphology ofZnO nanowires has been investigated.The results indicated that long and vertically aligned ZnO nanowires could be obtained by adjusting the contents of ammonia and polyethyleneimine (PEI) in the growth solution.Under the optimized condition,the length of ZnO nanowires increased fast and almost linearly with the growth duration.After 10 h incubation,ZnO nanowires more than 25μm in length were obtained.By combining the conventional photolithographic method with this hydrothermal approach,long and well-aligned ZnO nanowire arrays were selectively grown on the substrate.In addition,the bottom fusion at the foot of the nanowires has been obviously improved.The results demonstrated that the improved hydrothermal process is favorable to synthesize long and well-aligned ZnO nanowires,and possesses good process compatibility with the conventional photolithographic technique for preparing ZnO nanowire arrays.So it has great potential in applications such as display and field emission devices.

  5. Biogeography of Persephonella in deep-sea hydrothermal vents of the Western Pacific.

    Directory of Open Access Journals (Sweden)

    Sayaka eMino

    2013-04-01

    Full Text Available Deep-sea hydrothermal vent fields are areas on the seafloor with high biological productivity fueled by microbial chemosynthesis. Members of the Aquificales genus Persephonella are obligately chemosynthetic bacteria, and appear to be key players in carbon, sulfur, and nitrogen cycles in high temperature habitats at deep-sea vents. Although this group of bacteria has cosmopolitan distribution in deep-sea hydrothermal ecosystem around the world, little is known about their population structure such as intraspecific genomic diversity, distribution pattern, and phenotypic diversity. We developed the multi-locus sequence analysis (MLSA scheme for their genomic characterization. Sequence variation was determined in five housekeeping genes and one functional gene of 36 P. hydrogeniphila strains originated from the Okinawa Trough and the South Mariana Trough. Although the strains share > 98.7% similarities in 16S rRNA gene sequences, MLSA revealed 35 different sequence types, indicating their extensive genomic diversity. A phylogenetic tree inferred from all concatenated gene sequences revealed the clustering of isolates according to the geographic origin. In addition, the phenotypic clustering pattern inferred from whole-cell matrix-assisted laser desorption ionization-time of flight mass spectrometry (MALDI-TOF/MS analysis can be correlated to their MLSA clustering pattern. This study represents the first MLSA combined with phenotypic analysis indicative of allopatric speciation of deep-sea hydrothermal vent bacteria.

  6. Physical properties and constraints of hydrothermal plumes on the Gakkel Ridge during AGAVE 2007

    Science.gov (United States)

    Winsor, P.; Liljebladh, B.; Edmonds, H. N.; Stranne, C.; Nakamura, K.; Reves-Sohn, R. A.; Tupper, G.; Upchurch, L.

    2007-12-01

    The unique hydrographic characteristics of the Arctic Ocean have important implications for the dynamical behavior of hydrothermal plumes. Some of the main issues include the weak density stratification of the deep bottom layer, topographical effects from a deep axial valley, and high-latitude tides. We address these issues using analytical and numerical models, and comparing the results to hydrographic water column plume data acquired during the Arctic Gakkel Vents Expedition (AGAVE) from July 1 to August 10, 2007. A total of 36 CTD casts were conducted from the icebreaker Oden at two main sites (85N 7E and 85N 85E), where different modes of hydrothermal circulation appear to generate different kinds of water column plumes. Several plume signals of varying thickness and rise height above the bottom were observed, which implies that several seafloor sources with distinct discharge characteristics were active during the surveys. We use our models to constrain the character of the seafloor sources, and discuss observational strategies for future field work aimed at locating and mapping hydrothermal sources in the deep Arctic.

  7. Direct Growth of Crystalline Tungsten Oxide Nanorod Arrays by a Hydrothermal Process and Their Electrochromic Properties

    Science.gov (United States)

    Lu, Chih-Hao; Hon, Min Hsiung; Leu, Ing-Chi

    2016-12-01

    Transparent crystalline tungsten oxide nanorod arrays for use as an electrochromic layer have been directly prepared on fluorine-doped tin oxide-coated glass via a facile tungsten film-assisted hydrothermal process using aqueous tungsten hexachloride solution. X-ray diffraction analysis and field-emission scanning electron microscopy were used to characterize the phase and morphology of the grown nanostructures. Arrays of tungsten oxide nanorods with diameter of ˜22 nm and length of ˜240 nm were obtained at 200°C after 8 h of hydrothermal reaction. We propose a growth mechanism for the deposition of the monoclinic tungsten oxide phase in the hydrothermal environment. The tungsten film was first oxidized to tungsten oxide to provide seed sites for crystal growth and address the poor connection between the growing tungsten oxide and substrate. Aligned tungsten oxide nanorod arrays can be grown by a W thin film-assisted heterogeneous nucleation process with NaCl as a structure-directing agent. The fabricated electrochromic device demonstrated optical modulation (coloration/bleaching) at 632.8 nm of ˜41.2% after applying a low voltage of 0.1 V for 10 s, indicating the potential of such nanorod array films for use in energy-saving smart windows.

  8. Geochemistry of the Koshelev Volcano-Hydrothermal System, Southern Kamchatka, Russia

    Science.gov (United States)

    Taran, Y.; Kalacheva, E.

    2015-12-01

    Koshelev is the southernmost volcano of the Kamchatkan volcanic front where magmatic plumbing systems of the Kamchatkan subduction zone cross a thick layer of the oil-gas-bearing Neogene sedimentary strata of Western Kamchatka. The volcanic massive hosts a powerful hydrothermal system, which has been drilled in early 1980s. Deep wells tapped a hot (ca. 300ºC) saline solution (up to 40 g/L of Cl), whereas the upper part of the system is a typical steam cap with temperature close to 240ºC. Two hydrothermal fields of the volcano (Upper and Lower) discharge saturated or super-heated (up to 150ºC) steam and are characterized by numerous hot pools and low flow-rate springs of steam-heated waters enriched in boron and ammonia. There is also a small lateral group of warm Na-Ca-Cl-SO4 springs (40ºC). We report here our data and review the literature geochemical data on the chemical and isotopic composition of waters and hydrothermal vapours of the Koshelev system. Data on the gas composition include He and C isotopes, as well as the chemical and isotopic composition of light hydrocarbons. Water geochemistry includes literature data on water isotopes of the deep brine and trace elements and REE of steam-heated waters. A conceptual model of the system is presented and discussed.

  9. Mechatronic integration and implementation of in situ multipoint temperature measurement for seafloor hydrothermal vent

    Institute of Scientific and Technical Information of China (English)

    WU HuaiChao; CHEN Ying; YANG CanJun; ZHANG JiaFan; ZHOU HuaiYang; PENG XiaoTong; JI FuWu

    2007-01-01

    In order to provide firsthand reference data for model building and analysis of temperature field of seafloor hydrothermal vent, a temperature measurement system is designed, which can be used to measure the temperature of seafloor hydrothermal vent. The system can implement in situ multipoint temperature measurement and work for 15 days on the seefloor, so Iow power consumption design principle of the integrated circuit board is adopted. To enable the system to endure the high pressure on the seafloor, mechanical structure of the system is designed in terms of design principle of pressure container. The pressure test experiment was performed in the authoritative institution, and the results indicated that the system was safe and could work reliably on the seafloor. In the first Sino-American Joint Dive Cruise, the instruments were carried to the seafloor to work by Alvin. The experiment in the sea was successful, and the results indicated that the system could survive in the high pressure and high temperature environment and record the temperature activities of hydrothermal vents. About 710000 groups of temperature data were acquired, and these are of importance for further scientific researches.

  10. Direct Growth of Crystalline Tungsten Oxide Nanorod Arrays by a Hydrothermal Process and Their Electrochromic Properties

    Science.gov (United States)

    Lu, Chih-Hao; Hon, Min Hsiung; Leu, Ing-Chi

    2017-04-01

    Transparent crystalline tungsten oxide nanorod arrays for use as an electrochromic layer have been directly prepared on fluorine-doped tin oxide-coated glass via a facile tungsten film-assisted hydrothermal process using aqueous tungsten hexachloride solution. X-ray diffraction analysis and field-emission scanning electron microscopy were used to characterize the phase and morphology of the grown nanostructures. Arrays of tungsten oxide nanorods with diameter of ˜22 nm and length of ˜240 nm were obtained at 200°C after 8 h of hydrothermal reaction. We propose a growth mechanism for the deposition of the monoclinic tungsten oxide phase in the hydrothermal environment. The tungsten film was first oxidized to tungsten oxide to provide seed sites for crystal growth and address the poor connection between the growing tungsten oxide and substrate. Aligned tungsten oxide nanorod arrays can be grown by a W thin film-assisted heterogeneous nucleation process with NaCl as a structure-directing agent. The fabricated electrochromic device demonstrated optical modulation (coloration/bleaching) at 632.8 nm of ˜41.2% after applying a low voltage of 0.1 V for 10 s, indicating the potential of such nanorod array films for use in energy-saving smart windows.

  11. Dissolved gases in hydrothermal (phreatic) and geyser eruptions at Yellowstone National Park, USA

    Science.gov (United States)

    Hurwitz, Shaul; Clor, Laura; McCleskey, R. Blaine; Nordstrom, D. Kirk; Hunt, Andrew G.; Evans, William C.

    2016-01-01

    Multiphase and multicomponent fluid flow in the shallow continental crust plays a significant role in a variety of processes over a broad range of temperatures and pressures. The presence of dissolved gases in aqueous fluids reduces the liquid stability field toward lower temperatures and enhances the explosivity potential with respect to pure water. Therefore, in areas where magma is actively degassing into a hydrothermal system, gas-rich aqueous fluids can exert a major control on geothermal energy production, can be propellants in hazardous hydrothermal (phreatic) eruptions, and can modulate the dynamics of geyser eruptions. We collected pressurized samples of thermal water that preserved dissolved gases in conjunction with precise temperature measurements with depth in research well Y-7 (maximum depth of 70.1 m; casing to 31 m) and five thermal pools (maximum depth of 11.3 m) in the Upper Geyser Basin of Yellowstone National Park, USA. Based on the dissolved gas concentrations, we demonstrate that CO2 mainly derived from magma and N2 from air-saturated meteoric water reduce the near-surface saturation temperature, consistent with some previous observations in geyser conduits. Thermodynamic calculations suggest that the dissolved CO2 and N2 modulate the dynamics of geyser eruptions and are likely triggers of hydrothermal eruptions when recharged into shallow reservoirs at high concentrations. Therefore, monitoring changes in gas emission rate and composition in areas with neutral and alkaline chlorine thermal features could provide important information on the natural resources (geysers) and hazards (eruptions) in these areas.

  12. Universal Predictability of Mobility Patterns in Cities

    CERN Document Server

    Yan, Xiao-Yong; Fan, Ying; Di, Zengru; Wang, Wen-Xu

    2013-01-01

    Despite the long history towards modeling human mobility, we continue to lack a highly accurate but low data requirement approach to predicting mobility patterns in cities. Here, we present a conduction-like stochastic process without adjustable parameter to capture the underlying driving force accounting for human mobility patterns at the city scale. We use various mobility data collected from a number of cities with different characteristics to demonstrate the predictive power of our model, finding that insofar as the spatial distribution of population is available, our model offers universal prediction of mobility patterns in good agreement with real observations, including distance distribution, destination travel constraints and flux. In contrast, the models quite successful in modeling mobility patterns in countries are not applicable in cities, suggesting the diversity of human mobility at different spatial scales. Our model has potential applications in many fields relevant to mobility behavior in cit...

  13. Hydrothermal growth of ZnO nanostructures - revew article

    Directory of Open Access Journals (Sweden)

    Sunandan Baruah and Joydeep Dutta

    2009-01-01

    Full Text Available One-dimensional nanostructures exhibit interesting electronic and optical properties due to their low dimensionality leading to quantum confinement effects. ZnO has received lot of attention as a nanostructured material because of unique properties rendering it suitable for various applications. Amongst the different methods of synthesis of ZnO nanostructures, the hydrothermal method is attractive for its simplicity and environment friendly conditions. This review summarizes the conditions leading to the growth of different ZnO nanostructures using hydrothermal technique. Doping of ZnO nanostructures through hydrothermal method are also highlighted.

  14. The Activity of Major Faults and the Hydrothermal Alteration Zone at Tianchi Volcano of Changbaishan

    Institute of Scientific and Technical Information of China (English)

    Liu Mingjun; Gu Menglin; Sun Zhenguo; Wei Haiquan; Jin Bolu

    2004-01-01

    It is found by field investigation that the near horizontal top surface of the brown or brick-red hydrothermal alteration zone varies obviously in elevation at different sections of the same layer on the caldera's inner wall of Tianchi, with that at the north section near the Tianwen Peak about 110 m higher than that at the south near the Jiangjun Peak in Korea. The top surface of the hydrothermal alteration zone can be taken as key horizon to tectonic movement. The difference indicates that the total uplift height of the NW wall of the Liudaogou-TianchiJingfengshan fault, the principal fault trending NE at Tianchi, is bigger than that of the SE wall ever since the occurrence of hydrothermal alteration. This also explains why the topography in the northwest side of Tianchi is steeper and with more developed river system than in the southeast. The uplifting of the northeastern wall is bigger than that of the southwest along the principal NW-trend fault, namely, the Baishanzhen-Tianchi-Jince fault. It is observed from characters of hydrothermal alteration and the palaeoresiduum, that the recent vertical movement rate along the principal NE-trend fault is larger than that of the principal NW-trend fault. The two faults intersect at Tianchi, dividing the volcano into 4 blocks, with the uplift magnitudes decreasing successively in the order of the north, the west, the east and the south block. The biggest uplift of the north block corresponds well to the shallow magma batch in the north of Tianchi observed by DSS and telluric electromagnetic sounding, and etc.and they may be related with the causes.

  15. The City at Stake:

    Directory of Open Access Journals (Sweden)

    Sophie Esmann Andersen

    2009-12-01

    Full Text Available Studies of the city have been addressed from many different approaches such as law, political science, art history and public administration, in which the eco-nomic, political and legal status of the city have played a major role. However, a new agenda for conceptualizing the city has emerged, in which the city assumes new roles. By using stakeholder theory as a framework for conceptualizing the city, we argue that the city assumes a political-economic agenda-setting role as well as providing a stage for identity constructions and relational performances for consumers, organizations, the media, politicians and other stakeholders. Stakeholder theory allows us to conceptualize the city as being constituted by stakes and relationships between stakeholders which are approached from three analytical positions (modern, postmodern and hypermodern, respectively, thereby allowing us to grasp different stakes and types of relationships, ranging from functional and contractual relationships to individualized and emotionally driven or more non-committal and fluid forms of relationships. In order to support and illustrate the analytical potentials of our framework for conceptualizing urban living, we introduce a project which aims to turn the city of Aarhus into a CO2-neutral city by the year 2030, entitled Aarhus CO2030. We conclude that applying stakeholder theory to a hyper-complex organization such as a city opens up for a reconceptualization of the city as a web of stakes and stakeholder relations. Stakeholder theory contributes to a nuanced and elaborate understanding of the urban complexity and web of both enforced and voluntary relationships as well as the different types of relationships that characterize urban life.

  16. Engineering carbon materials from the hydrothermal carbonization process of biomass.

    Science.gov (United States)

    Hu, Bo; Wang, Kan; Wu, Liheng; Yu, Shu-Hong; Antonietti, Markus; Titirici, Maria-Magdalena

    2010-02-16

    Energy shortage, environmental crisis, and developing customer demands have driven people to find facile, low-cost, environmentally friendly, and nontoxic routes to produce novel functional materials that can be commercialized in the near future. Amongst various techniques, the hydrothermal carbonization (HTC) process of biomass (either of isolated carbohydrates or crude plants) is a promising candidate for the synthesis of novel carbon-based materials with a wide variety of potential applications. In this Review, we will discuss various synthetic routes towards such novel carbon-based materials or composites via the HTC process of biomass. Furthermore, factors that influence the carbonization process will be analyzed and the special chemical/physical properties of the final products will be discussed. Despite the lack of a clear mechanism, these novel carbonaceous materials have already shown promising applications in many fields such as carbon fixation, water purification, fuel cell catalysis, energy storage, CO(2) sequestration, bioimaging, drug delivery, and gas sensors. Some of the most promising examples will also be discussed here, demonstrating that the HTC process can rationally design a rich family of carbonaceous and hybrid functional carbon materials with important applications in a sustainable fashion.

  17. CHONGQING, the Hot City

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    @@ Chongqing is a well-known city with a history of more than 3,000 years. It is a famous historical and cultural city in China. Chongqing is the birthplace of the Bayu Culture. At present, Chongqing is a municipality directly under the Central Government with the largest area, the most administrative districts and the largest population.

  18. City Improves State Enterprises

    Institute of Scientific and Technical Information of China (English)

    EnjoyceZhu

    2003-01-01

    As China's new leadership drafts measures to help ailing Stateowned enterprises(SOEs),Changchun,a strategic city in the Rust Belt,is reaping benefits unseen in more than a decade of SOE reform.Home to a large number of SOEs,Changchun has had its share of bureaucracy and stagnation.The city initiated a program called,“Saving SOEs

  19. City profile: Paramaribo

    NARCIS (Netherlands)

    Verrest, H.J.L.M.

    2010-01-01

    Paramaribo, the largest and only significant urban area in Suriname, is a typical primate city. The majority of the countries’ population resides here and the majority of political, social and economic functions is clustered in the urban zone. In the course of the 20th century, the city changed dram

  20. Making the Experience City

    DEFF Research Database (Denmark)

    Jensen, Ole B.

    2009-01-01

    This paper describes the latest research into cultural planning and architectural branding in Denmark based on the ‘Experience City' research project located at Aalborg University. The paper explores the implication of the turn towards culture and experience in the contemporary Danish city. It thus...

  1. Reflective cool cities

    NARCIS (Netherlands)

    Heidegger, V.

    2011-01-01

    This "designers' manual" is made during the TIDO-course AR0531 Smart & Bioclimatic Design. Our globe is heating, and cities are heating up much more. At the same time, cities are growing and green spaces are substituted by buildings and streets. These man-made surfaces are dark and tend to heat up

  2. Deer City Legend

    Institute of Scientific and Technical Information of China (English)

    LIUHUANZHI; LILIKUN

    2003-01-01

    MORE and more commodities,such as clothes,shoes,millinery,lighters and shavers,now bear the “Made in Wenzhou”mark.It woule appear that Wenzhou grooms the whole nation.Lucheng(deer city)District in central Wenzhou is the nucleus of the city's thriving light industry sector.

  3. Futures of cities

    DEFF Research Database (Denmark)

    2008-01-01

    Bogen dokumenterer resultater fra den internationale kongres Futures of Cities arrangeret af IFHP International Federation of Housing and Planning, Realdania, Kunstakademiets Arkitektskole og City of Copenhagen. Kongressen blev afholdt i september 2007 i Øksnehallen og på Kunstakademiets Arkitekt...

  4. The influence of Zihe Stream on the groundwater resources of the Dawu well field and on the discharge at the Heiwang iron mine, Zibo City area, Shandong Province, China

    Science.gov (United States)

    Zhu, Xue-Yu; Liu, Jian-Li; Qian, Xiao-Xing

    The Dawu well field, one of the largest in China, supplies most of the water for the Zibo City urban area in Shandong Province. The field yields 522,400-535,400m3/d from an aquifer in fractured karstic Middle Ordovician carbonate rocks. Much of the recharge to the aquifer is leakage of surface water from Zihe Stream, the major drainage in the area. Installation of the Taihe Reservoir in 1972 severely reduced the downstream flow in Zihe Stream, resulting in a marked reduction in the water table in the Dawu field. Since 1994, following the installation of a recharge station on Zihe Stream upstream from the well field that injects water from the Taihe Reservoir into the stream, the groundwater resources of the field have recovered. An average of 61.2×103m3/d of groundwater, mostly from the Ordovician aquifer, is pumped from the Heiwang iron mine, an open pit in the bed of Zihe Stream below the Taihe Reservoir. A stepwise regression equation, used to evaluate the role of discharge from the reservoir into the stream, confirms that reservoir water is one of the major sources of groundwater in the mine. Résumé Le champ captant de Dawu, l'un des plus importants de Chine, fournit l'essentiel de l'eau à la communauté urbaine de Zibo, dans la province de Shandong. Ce champ captant fournit entre 522,400 et 535,400m3/j à partir d'un aquifère fracturé karstique des carbonates de l'Ordovicien moyen. La plupart de la recharge de cet aquifère est assurée par des pertes d'eau de surface de la rivière Zihe, principal cours d'eau de la région. La mise en eau du réservoir de Taihe en 1972 a sévèrement réduit en aval l'écoulement de la Zihe, ce qui a provoqué une diminution nette du niveau de la nappe dans le champ captant de Dawu. Depuis 1974, après la mise en fonctionnement d'une station de recharge sur la rivière Zihe, injectant, en amont du champ captant, de l'eau du réservoir de Taihe dans la rivière, les ressources en eau souterraine ont été reconstitu

  5. The Flickering Global City

    Directory of Open Access Journals (Sweden)

    Eric Slater

    2015-08-01

    Full Text Available This article explores new dimensions of the global city in light of the correlation between hegemonic transition and the prominence of financial centers. It counterposes Braudel’s historical sequence of dominant cities to extant approaches in the literature, shifting the emphasis from a convergence of form and function to variations in history and structure. The marked increase of finance in the composition of London, New York and Tokyo has paralleled each city’s occupation of a distinct niche in world financial markets: London is the principal center of currency exchange, New York is the primary equities market, and Tokyo is the leader in international banking. This division expresses the progression of world-economies since the nineteenth century and unfolds in the context of the present hegemonic transition. By combining world-historical and city-centered approaches, the article seeks to reframe the global city and overcome the limits inherent in the paradigm of globalization.

  6. Great cities look small

    CERN Document Server

    Sim, Aaron; Barahona, Mauricio; Stumpf, Michael P H

    2015-01-01

    Great cities connect people; failed cities isolate people. Despite the fundamental importance of physical, face-to-face social-ties in the functioning of cities, these connectivity networks are not explicitly observed in their entirety. Attempts at estimating them often rely on unrealistic over-simplifications such as the assumption of spatial homogeneity. Here we propose a mathematical model of human interactions in terms of a local strategy of maximising the number of beneficial connections attainable under the constraint of limited individual travelling-time budgets. By incorporating census and openly-available online multi-modal transport data, we are able to characterise the connectivity of geometrically and topologically complex cities. Beyond providing a candidate measure of greatness, this model allows one to quantify and assess the impact of transport developments, population growth, and other infrastructure and demographic changes on a city. Supported by validations of GDP and HIV infection rates ac...

  7. A liveable city:

    DEFF Research Database (Denmark)

    Sommerlund, Julie

    2014-01-01

    There are over 20 cities world-wide with a population of over 10 million people. We have entered ‘The Millennium of the City’. The growth of urban populations has been accompanied by profound changes of the cities’ economic and social profile and of the cities themselves. The world economy...... is increas- ingly based in and on cities rather than nations, and cities compete for businesses, branding, tourists and talent. In the western world, urbanisation has happened simultane- ously to de-industrialisation, which has opened industrial neighbourhoods and harbours for new uses – often focus- ing...... on experience. We will argue for a human turn in the research on liveabil- ity and urbanisation, and debates the concept of liveability. We will take Copenhagen as our main case and compare with other cities from around the world....

  8. Marriage and the City

    DEFF Research Database (Denmark)

    Gautier, Pieter; Svarer, Michael; Teulings, Coen

    Do people move to cities because of marriage market considerations? In cities singles can meet more potential partners than in rural areas. Singles are therefore prepared to pay a premium in terms of higher housing prices. Once married, the marriage market benefits disappear while the housing...... premium remains. We extend the model of Burdett and Coles (1997) with a distinction between efficient (cities) and less efficient (non-cities) search markets. One implication of the model is that singles are more likely to move from rural areas to cities while married couples are more likely to make...... the reverse movement. A second prediction of the model is that attractive singles benefit most from a dense market (i.e. from being choosy). Those predictions are tested with a unique Danish dataset....

  9. Governing the City

    DEFF Research Database (Denmark)

    Kornberger, Martin

    2012-01-01

    Strategy frames the contemporary epistemological space of urbanism: major cities across the globe such as New York, London and Sydney invest time, energy and resources to craft urban strategies. Extensive empirical research projects have proposed a shift towards a strategic framework to manage...... cities. This theoretical curiosity is reflected in the rising interest in urban strategy from practice. For instance, the World Bank regularly organizes an Urban Strategy Speaker Series, while the powerful network CEOs for Cities lobbies for a strategic approach to urban development. Critical scholars...... such as Zukin diagnose not a shift in but a shift to strategic thinking in the contemporary city. This article poses the question: what makes strategy such an attractive ‘thought style’ in relation to imagining and managing cities? How can we understand the practice of urban strategy? And what are its intended...

  10. Whole Algae Hydrothermal Liquefaction: 2014 State of Technology

    Energy Technology Data Exchange (ETDEWEB)

    Jones, Susanne B.; Zhu, Yunhua; Snowden-Swan, Lesley J.; Anderson, Daniel; Hallen, Richard T.; Schmidt, Andrew J.; Albrecht, Karl O.; Elliott, Douglas C.

    2014-07-30

    This report describes the base case yields and operating conditions for converting whole microalgae via hydrothermal liquefaction and upgrading to liquid fuels. This serves as the basis against which future technical improvements will be measured.

  11. Direct use of hydrothermal energy: a review of environmental aspects

    Energy Technology Data Exchange (ETDEWEB)

    O' Banion, K.; Layton, D.

    1981-08-28

    The potential environmental impacts of the exploration, development, and production of hydrothermal geothermal energy for direct use applications are reviewed and evaluated. Mitigation strategies and research and development needs are included. (MHR)

  12. Methane production from hydrothermal transformation of siderite to magnetite

    Science.gov (United States)

    Muratbayev, T.; Schroeder, C.; Kappler, A.; Haderlein, S.

    2012-12-01

    Mumma et al. (2009) observed a methane (CH4) plume above the Nili Fossae region on Mars, a region rich in carbonate minerals. Morris et al. (2010) suggest this to be (Mg,Fe)-carbonate. McCollom (2003) demonstrated that the hydrothermal transformation of siderite (FeCO3), to magnetite (Fe3O4) produces CH4. This reaction may thus contribute to the formation of methane on Mars, but is also relevant in the context of such diverse topics as diagenesis of Precambrian banded iron formations, sources of prebiotic organic compounds on early Earth, oil and gas accumulations in Earth's crust, or geological sequestration and storage of CO2. However, neither the thermodynamics of this reaction nor the conditions of maximum CH4 yield have been investigated to date. In order to estimate how pressure and temperature influence CH4 yield we derived a thermodynamic model with a numerical solution implemented in MATLAB. We used the equation 12FeCO3 + 2H2O → 4Fe3O4 + 11CO2 + CH4 (Frost et al. 2007) and thermodynamic calculations of the stability field of FeCO3 by Thoms-Keprta et al. (2009) as a template. At 1 bar pressure, the Gibbs energy turns negative (favorable reaction conditions) at a temperature of 200°C. Increasing pressure to 1000 bar changes that temperature to 250°C. An increase in temperature has a larger effect on shifting the Gibbs energy to more negative values. We therefore chose ambient pressure and temperatures of 300°C, 400°C, and 500°C as experimental conditions. We added 100 mg of either natural or synthetic FeCO3 and 25 μL of MilliQ water into long tip Pasteur pipettes inside an anoxic glove box to avoid contamination by free oxygen. The Pasteur pipettes were sealed with butyl stoppers and then melted shut outside of the glove box. The glass capsules were heated for 48 hours in a muffle furnace at 300°C, 400 0C or 5000C. The composition of the gas phase and the formation of methane in particular were analyzed using gas chromatography with a flame

  13. Cities, Towns and Villages, City Limits of City of Dubuque, IA, Published in 2007, City of Dubuque.

    Data.gov (United States)

    NSGIC GIS Inventory (aka Ramona) — This Cities, Towns and Villages dataset, was produced all or in part from Published Reports/Deeds information as of 2007. It is described as 'City Limits of City of...

  14. 2008 City of Baltimore Lidar

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — In the spring of 2008, the City of Baltimore expressed an interest to upgrade the City GIS Database with mapping quality airborne LiDAR data. The City of Baltimore...

  15. Hydrothermal monitoring data from the Cascade Range, northwestern United States

    Science.gov (United States)

    Ingebritsen, Steven E.; Gelwick, Katrina D.; Randolph-Flagg, Noah G.; Crankshaw, Ilana M.; Lundstrom, Elizabeth A.; McCulloch, Callum L.; Murveit, Anna M.; Newman, Alice C.; Mariner, Robert H.; Bergfeld, D.; Tucker, Dave S.; Schmidt, Mariek E.; Spicer, Kurt R.; Mosbrucker, Adam; Evans, William C.

    2013-01-01

    This database serves as a repository for hydrothermal-monitoring data collected at 25 sites in the U.S. portion of the Cascade Range volcanic arc. These data are intended to quantify baseline hydrothermal variability at most (10 of 12) of the highest-risk volcanoes in the Cascades, as defined by the U.S. Geological Survey’s (USGS’) National Volcanic Early Warning System (NVEWS) report (Ewert and others, 2005).

  16. New insights into hydrothermal vent processes in the unique shallow-submarine arc-volcano, Kolumbo (Santorini), Greece.

    Science.gov (United States)

    Kilias, Stephanos P; Nomikou, Paraskevi; Papanikolaou, Dimitrios; Polymenakou, Paraskevi N; Godelitsas, Athanasios; Argyraki, Ariadne; Carey, Steven; Gamaletsos, Platon; Mertzimekis, Theo J; Stathopoulou, Eleni; Goettlicher, Joerg; Steininger, Ralph; Betzelou, Konstantina; Livanos, Isidoros; Christakis, Christos; Bell, Katherine Croff; Scoullos, Michael

    2013-01-01

    We report on integrated geomorphological, mineralogical, geochemical and biological investigations of the hydrothermal vent field located on the floor of the density-stratified acidic (pH ~ 5) crater of the Kolumbo shallow-submarine arc-volcano, near Santorini. Kolumbo features rare geodynamic setting at convergent boundaries, where arc-volcanism and seafloor hydrothermal activity are occurring in thinned continental crust. Special focus is given to unique enrichments of polymetallic spires in Sb and Tl (±Hg, As, Au, Ag, Zn) indicating a new hybrid seafloor analogue of epithermal-to-volcanic-hosted-massive-sulphide deposits. Iron microbial-mat analyses reveal dominating ferrihydrite-type phases, and high-proportion of microbial sequences akin to "Nitrosopumilus maritimus", a mesophilic Thaumarchaeota strain capable of chemoautotrophic growth on hydrothermal ammonia and CO2. Our findings highlight that acidic shallow-submarine hydrothermal vents nourish marine ecosystems in which nitrifying Archaea are important and suggest ferrihydrite-type Fe(3+)-(hydrated)-oxyhydroxides in associated low-temperature iron mats are formed by anaerobic Fe(2+)-oxidation, dependent on microbially produced nitrate.

  17. Impact of hydrothermalism on the ocean iron cycle

    Science.gov (United States)

    Tagliabue, Alessandro; Resing, Joseph

    2016-11-01

    As the iron supplied from hydrothermalism is ultimately ventilated in the iron-limited Southern Ocean, it plays an important role in the ocean biological carbon pump. We deploy a set of focused sensitivity experiments with a state of the art global model of the ocean to examine the processes that regulate the lifetime of hydrothermal iron and the role of different ridge systems in governing the hydrothermal impact on the Southern Ocean biological carbon pump. Using GEOTRACES section data, we find that stabilization of hydrothermal iron is important in some, but not all regions. The impact on the Southern Ocean biological carbon pump is dominated by poorly explored southern ridge systems, highlighting the need for future exploration in this region. We find inter-basin differences in the isopycnal layer onto which hydrothermal Fe is supplied between the Atlantic and Pacific basins, which when combined with the inter-basin contrasts in oxidation kinetics suggests a muted influence of Atlantic ridges on the Southern Ocean biological carbon pump. Ultimately, we present a range of processes, operating at distinct scales, that must be better constrained to improve our understanding of how hydrothermalism affects the ocean cycling of iron and carbon. This article is part of the themed issue 'Biological and climatic impacts of ocean trace element chemistry'.

  18. Effect of hydrothermal treatment of coal on its associative structure

    Energy Technology Data Exchange (ETDEWEB)

    Shui Heng-fu; Wang Zhi-cai; Wang Gao-qiang; Niu Min-feng [Anhui University of Technology, Maanshan (China). School of Chemistry & Chemical Engineering

    2006-10-15

    4 bituminous coals with different ranks were thermally and hydrothermally treated under different conditions, and the raw and treated coals were extracted with carbon disulfide/N-2-pyrrolidinone (CS{sub 2}/NMP) mixed solvent (1:1 by volume). It is found that the extraction yields of the thermal or hydrothermal treated coals at proper conditions increase in different extent. The increments of extraction yields for hydrothermal treated coals are higher than those of thermal treated coals. FT-IR shows that the adsorption peaks at 3410 cm{sup -1} attributed to OH group for the hydrothermal treated coals decrease, suggesting the dissociation of the coal aggregation structure due to the breakage of hydrogen bonds, resulting in the increase of extraction yields for the treated coals. For higher rank coal, the removal of minerals and the dissociation of {pi}-cation association after hydrothermal treatment of coal may be responsible for the increase of extraction yield. In addition, the mechanism of hydrothermal treatment of coal was discussed. 15 refs., 2 figs., 5 tabs.

  19. Opportunities at the Mathematics/Future Cities Interface

    CERN Document Server

    Grindrod, Peter; MacKay, Robert S

    2014-01-01

    We make the case for mathematicians and statisticians to stake their claim in the fast-moving and high-impact research field that is becoming known as Future Cities. After assessing the Future Cities arena, we provide some illustrative challenges where mathematical scientists can make an impact.

  20. Structure and enzymatic accessibility of leaf and stem from wheat straw before and after hydrothermal pretreatment

    DEFF Research Database (Denmark)

    Zhang, Heng; Thygesen, Lisbeth Garbrecht; Mortensen, Kell

    2014-01-01

    field nuclear magnetic resonance and infrared spectroscopy in combination with hydrogen-deuterium exchange. Results: Leaves were clearly more degradable by lignocellulolytic enzymes than stems, and it was demonstrated that xylose removal was more linked to glucose yield for stems than for leaves....... Hydrothermal pretreatment increased the accessibility towards water in stems but not in leaves. The results in this study indicate a correlation between the accessibility of glucan to water and to enzymes. Conclusions: Enzymatic degradability of wheat straw anatomical fractions can be indicated...

  1. Preparation and characterization of gadolinium hydroxide single-crystalline nanorods by a hydrothermal process

    Institute of Scientific and Technical Information of China (English)

    Yi Dong Yin; Guang Yan Hong; Bai Fu Xin

    2007-01-01

    The Gd(OH)3 nanorods with diameters of ca. 40-60 nm and lengths of more than 400-550 nm have been prepared by a novel hydrothermal technique. The structural features and chemical composition of the nanorods were investigated by X-ray diffraction(XRD), transmission electron microscopy (TEM), and field emission scanning electron microscope (FESEM), selected area electron diffraction (SAED), and high resolution transmission electron microscopy (HRTEM). The possible mechanism for the formation of Gd(OH)3 nanorods was proposed.

  2. 山东省泰安市28个桑园的土壤肥力数值化综合评价%Comprehensive Evaluation of Soil Nutrient Scalarization of 28 Mulberry Fields in Taian City of Shandong Province

    Institute of Scientific and Technical Information of China (English)

    赵凯; 黄露; 王彦文; 高绘菊; 王利; 牟志美

    2012-01-01

    In order to accurately evaluate soil fertility status of different mulberry fields, soil nutrient contents of 28 mulberry fields in Daiyue District of Taian City, Shandong Province, were determined by chemical analysis methods including colorimetry and atomic absorption spectrometry, and 15 indexes of soil fertility property of the 28 mulberry fields were analyzed by factor analysis, principal component analysis and cluster analysis by employing the model of comprehensive index evaluation in fuzzy mathematics. Based on these analyses, the soil fertility status of different mulberry fields was comprehensively assessed and graded. The results demonstrated that pH values of soil in 28 surveyed mulberry fields were suitable, and the contents of organic matter, nitrogen, phosphorus and potassium elements were low in most mulberry fields, while lack of other nutrient elements was found in a few mulberry fields. The minimum data set (MDS) contained 8 indexes, namely total nitrogen, pH value, alkalized nitrogen, available iron, available phosphorus, available potassium, organic matter and total phosphorus. The index weight was percentage of variance of each common factor. It was thus calculated that the average integrated soil fertility index of 28 surveyed mulberry fields was 0. 25 with a variation range of 0. 18 to 0. 34. The soil fertility was divided into four grades, namely the highest, higher, medium and low levels, and mulberry field of each grade accounted for 21. 4%, 25. 0%, 39. 3% and 14.3%, respectively. With the help of above comprehensive scalarization and analyses, comprehensive evaluation of soil fertility could be improved both quantitatively and scientifically, and the influence of subjective factors could be reduced in the evaluation process. In the future, the abundance and deficiency standards and the threshold values of membership function should be standardized according to the demand of mulberry growth, so as to form a more comprehensive, objective

  3. @City: technologising Barcelona

    Directory of Open Access Journals (Sweden)

    Rojas, Jesús

    2007-05-01

    Full Text Available This article is about the concept of the contemporary city - the influence that technology has when one thinks about, plans and lives in a city. The conjunction of technology and city reformulates customs and social practices; it can even determine the way one constitutes one's own identity. One can see how close the relation is between technology (specifically, TICS and the structures of the city in a wide variety of situations: in social interactions on the street, in transport, and in ways of buying, of working and entertainment. "@City" is a concept that very well reflects the emergent properties of a current city, that is, the coexistence of a physical and a virtual urban space. The "22@Barcelona" project attempts to bring together different types of spaces. By combining the physical with the virtual, 22@Barcelona, as a neighborhood of @City, creates an uncertain and blurred border between both spaces.The article also examines the impact that these spaces have on the psycho-social processes involved in the daily life of a traditionally working-class neighborhood, now strongly limited by technological boundaries.

  4. @City: technologising Barcelona

    Directory of Open Access Journals (Sweden)

    Jesús Rojas

    2007-05-01

    Full Text Available This article is about the concept of the contemporary city - the influence that technology has when one thinks about, plans and lives in a city. The conjunction of  technology and city reformulates customs and social practices; it can even determine the way one constitutes one's own identity. One can see how close the relation is between technology (specifically, TICS and the structures of the city in a wide variety of situations: in social interactions on the street, in transport, and in ways of buying, of working and entertainment. "@City" is a concept that very well reflects  the emergent properties of a current city, that is, the coexistence of a physical and a virtual urban space. The "22@Barcelona" project attempts to bring together different types of spaces. By combining the physical with the virtual, 22@Barcelona, as a neighborhood of @City,  creates an uncertain and blurred border between both spaces.The article also examines the impact that these spaces have on the psycho-social processes involved in the daily life of a traditionally working-class neighborhood, now strongly limited by technological boundaries.

  5. Hydrothermal model of the Momotombo geothermal system, Nicaragua

    Energy Technology Data Exchange (ETDEWEB)

    Verma, M.P.; Martinez, E.; Sanchez, M.; Miranda, K.; Gerardo, J.Y.; Araguas, L.

    1996-01-24

    The Momotombo geotherinal field is situated on the northern shore of Lake Managua at the foot of the active Momotombo volcano. The field has been producing electricity since 1983 and has an installed capacity of 70 MWe. The results of geological, geochemical and geophysical studies have been reported in various internal reports. The isotopic studies were funded by the International Atomic Energy Agency (IAEA), Vienna to develop a hydrothermal model of the geothermal system. The chemical and stable isotopic data (δ18O and δD) of the geothermal fluid suggest that the seasonal variation in the production characteristics of the wells is related to the rapid infiltration of local precipitation into the reservoir. The annual average composition of Na+, K+ and Mg2+ plotted on the Na- K-Mg triangular diagram presented by Giggenbach (1988) to identify the state of rock-water interaction in geothermal reservoirs, shows that the fluids of almost every well are shifting towards chemically immature water due to resenroir exploitation. This effect is prominent in wells Mt-2. Mt-12, Mt-22 and Mt-27. The local groundwaters including surface water from Lake Managua have much lower tritium concentrations than sonic of the geothermal well fluids, which have about 6 T.U. The high-tritium wells are located along a fault inferred froin a thermal anomaly. The tritium concentration is also higher in fluids from wells close to the lake. This could indicate that older local precipitation waters are stored in a deep layer within the lake and that they are infiltrating into the geothermal reservoir.

  6. Recent developments in healthy city design

    Institute of Scientific and Technical Information of China (English)

    StephenS.YLAU; K.W.CHAU; DanielC.W.HO

    2003-01-01

    This paper reviews the recent developments in programs and tools for healthy city design with special reference to densely populated cities. The research agenda that underpin the development of these programs and tools are also discussed. The review shows that progress in healthy city design must be built upon theories that explains the relationship between the hardware and software of city at all levels (such as urban landscape, planning, building design, development density, infrastructure, traffic management, building management etc) and the physical and mental well being of its citizens. Since data on the latter is often difficult to come by, observable factors that are known to have a direct bearing on human health conditions such as air quality, water quality, noise level, thermal comfort etc are used instead. The discovery of these theories requires knowledge from different fields and thus calls for a multidisciplinary approach. In addition, many recent programs and tools for healthy city design also aim at resolving implementation issues. Resolving these issues is often the key to building a healthy city.

  7. Pasadena City College SIGI Project Research Design.

    Science.gov (United States)

    Risser, John J.; Tulley, John E.

    The research design is presented for an evaluation of a computer based career guidance program, SIGI (System of Interactive Guidance and Information), designed by Educational Testing Service to assist community college students in improving their ability to make career decisions. The plan described is for the Pasadena City College field test--a…

  8. Hydrothermal Gasification for Waste to Energy

    Science.gov (United States)

    Epps, Brenden; Laser, Mark; Choo, Yeunun

    2014-11-01

    Hydrothermal gasification is a promising technology for harvesting energy from waste streams. Applications range from straightforward waste-to-energy conversion (e.g. municipal waste processing, industrial waste processing), to water purification (e.g. oil spill cleanup, wastewater treatment), to biofuel energy systems (e.g. using algae as feedstock). Products of the gasification process are electricity, bottled syngas (H2 + CO), sequestered CO2, clean water, and inorganic solids; further chemical reactions can be used to create biofuels such as ethanol and biodiesel. We present a comparison of gasification system architectures, focusing on efficiency and economic performance metrics. Various system architectures are modeled computationally, using a model developed by the coauthors. The physical model tracks the mass of each chemical species, as well as energy conversions and transfers throughout the gasification process. The generic system model includes the feedstock, gasification reactor, heat recovery system, pressure reducing mechanical expanders, and electricity generation system. Sensitivity analysis of system performance to various process parameters is presented. A discussion of the key technological barriers and necessary innovations is also presented.

  9. Complexation of Si in Hydrothermal Systems

    Institute of Scientific and Technical Information of China (English)

    樊文苓; 王声远; 田弋夫; 陈紫新

    2001-01-01

    The Au-SiO2 and Sn-SiO2 complexes have been experimentally calibrated at varying temperature, silica concentration and pH:Au+ + H3SiO4-=AuH3SiO4 lgK = - 1. 65436 + 9611.21/TSn4 + + 4H3SiO4-=Sn(H3SiO4)4 lgK200℃ = 42.73Compared with Au-Cl, Au-HS and Sn-OH complexes, AuH3SiO4 and Sn(H3SiO4)4 complexes can be recognized as the dominant transport forms in Si-bearing solutions under pH and Eh con ditions of general interest. The decrease of SiO2 concentration and oxygen fugacity would re verse the direction of dissolution-complexing reactions, resulting in the precipitation of gold and silica, as well as cassiterite and silica. This study illustrates the significance of SiO2-complexa tion in hydrothermal solutions for gold, tin and other metallizations.

  10. Smart city – future city? smart city 20 as a livable city and future market

    CERN Document Server

    Etezadzadeh, Chirine

    2016-01-01

    The concept of a livable smart city presented in this book highlights the relevance of the functionality and integrated resilience of viable cities of the future. It critically examines the progressive digitalization that is taking place and identifies the revolutionized energy sector as the basis of urban life. The concept is based on people and their natural environment, resulting in a broader definition of sustainability and an expanded product theory. Smart City 2.0 offers its residents many opportunities and is an attractive future market for innovative products and services. However, it presents numerous challenges for stakeholders and product developers.

  11. Cities and Refugees

    DEFF Research Database (Denmark)

    Katz, Bruce; Noring, Luise; Garrelts, Nantke

    institutions, it is municipalities across Europe in general and Germany in particular who are responsible for planning, delivering, and, in some cases, financing the housing, education, and full integration of new arrivals. “Cities and Refugees: The European Response” is a collaboration of the Brookings...... Centennial Scholar Initiative and the Foreign Policy program, with key research led by the Copenhagen Business School. It aims to show the extent to which cities are at the vanguard of this crisis and to deepen our understanding of the role and capacity of city governments and local networks in resettlement...... and long-term economic and social integration....

  12. Hydrothermal convection and mordenite precipitation in the cooling Bishop Tuff, California, USA

    Science.gov (United States)

    Randolph-Flagg, N. G.; Breen, S. J.; Hernandez, A.; Self, S.; Manga, M.

    2014-12-01

    We present field observations of erosional columns in the Bishop Tuff and then use laboratory results and numerical models to argue that these columns are evidence of relict convection in a cooling ignimbrite. Many square kilometers of the Bishop Tuff have evenly-spaced, vertical to semi-vertical erosional columns, a result of hydrothermal alteration. These altered regions are more competent than the surrounding tuff, are 0.1-0.7 m in diameter, are separated by ~ 1 m, and in some cases are more than 8 m in height. JE Bailey (U. of Hawaii, dissertation, 2005) suggested that similar columns in the Bandelier Tuff were formed when slumping allowed water to pool at the surface of the still-cooling ignimbrite. As water percolated downward it boiled generating evenly spaced convection cells similar to heat pipes. We quantify this conceptual model and apply it the Bishop Tuff to understand the physics within ignimbrite-borne hydrothermal systems. We use thin sections to measure changing porosity and use scanning electron microscope (SEM) and x-ray diffraction (XRD) analyses to show that pore spaces in the columns are cemented by the mineral mordenite, a low temperature zeolite that precipitates between 120-200 oC (Bish et al., 1982), also found in the Bandelier Tuff example. We then use scaling to show 1) that water percolating into the cooling Bishop Tuff would convect and 2) that the geometry and spacing of the columns is predicted by the ignimbrite temperature and permeability. We use the computer program HYDROTHERM (Hayba and Ingebritsen, 1994; Kipp et al., 2008) to model 2-phase convection in the Bishop Tuff. By systematically changing permeability, initial temperature, and topography we can identify the pattern of flows that develop when the ignimbrite is cooled by water from above. Hydrothermally altered columns in ignimbrite are the natural product of coupled heat, mass, and chemical transport and have similarities to other geothermal systems, economic ore deposits

  13. Towards Intelligently - Sustainable Cities?

    Directory of Open Access Journals (Sweden)

    Luca Salvati

    2013-04-01

    Full Text Available In the quest for achieving sustainable cities, Intelligent and Knowledge City Programmes (ICPs and KCPs represent cost-efficient strategies for improving the overall performance of urban systems. However, even though nobody argues on the desirability of making cities “smarter”, the fundamental questions of how and to what extent can ICPs and KCPs contribute to the achievement of urban sustainability lack a precise answer. In the attempt of providing a structured answer to these interrogatives, this paper presents a methodology developed for investigating the modalities through which ICPs and KCPs contribute to the achievement or urban sustainability. Results suggest that ICPs and KCPs efficacy lies in supporting cities achieve a sustainable urban metabolism through optimization, innovation and behavior changes.

  14. Ecological city planning

    Directory of Open Access Journals (Sweden)

    Salvador Rueda

    2013-07-01

    Full Text Available A territory, a city, a neighbourhood are all ecosystems; a mixture of chemico-physical and organic elements related to each other. That which defines an ecological system is the set of rules and characteristics which condition its relationships, and its duration in time is guaranteed by its efficiency and internal organization which applied to the city is translated in the reduction of the use of natural resources and in the increase of social organization. To increase the efficiency of the urban systems is the necessary condition for the formulation of ecological city planning favouring the maximum liveability of sites. Liveability is directly correlated to the optimization of numerous elements (public space, equipment, services, building techniques, innovative technology, social cohesion, biodiversity. To carry out such objectives, ecological city planning proposes a new model of town planning on three levels (subsoil, ground level, and upper level.

  15. OpenCities Project

    Data.gov (United States)

    US Agency for International Development — The Open Cities Project aims to catalyze the creation, management and use of open data to produce innovative solutions for urban planning and resilience challenges...

  16. Postsovkhoz City & Postsovkhoz Person

    Index Scriptorium Estoniae

    2001-01-01

    Põlvamaal Moostes mõtte- ja keskkonnakunstitalgud "Postsovkhoz City" ja "Postsovkhoz Person". Näha saab endistesse tööstushoonetesse ülespandud näitusi ja installatsioone. 11. VIII esinejad, ettekanded.

  17. Earthquakes in cities revisited

    CERN Document Server

    Wirgin, Armand

    2016-01-01

    During the last twenty years, a number of publications of theoretical-numerical nature have appeared which come to the apparently-reassuring conclusion that seismic motion on the ground in cities is smaller than what this motion would be in the absence of the buildings (but for the same underground and seismic load). Other than the fact that this finding tells nothing about the motion within the buildings, it must be confronted with the overwhelming empirical evidence (e.g, earthquakes in Sendai (2011), Kathmandu (2015), Tainan City (2016), etc.) that shaking within buildings of a city is often large enough to damage or even destroy these structures. I show, on several examples, that theory can be reconciled with empirical evidence, and suggest that the crucial subject of seismic response in cities is in need of more thorough research.

  18. Should Cities Regulate Graffiti?

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Graffiti, while still a new phenomenon to most Chinese, is becoming more familiar among teenagers in big cities like Beijing and Shanghai. A recent report by Xinhua News Agency discusses the trend. The report said a small

  19. WE LOVE THE CITY

    DEFF Research Database (Denmark)

    2011-01-01

    WE LOVE THE CITY Byen i bygningen, bygningen i byen Lasse Andersson, Ph.d., arkitekt maa, adjunkt ved Aalborg Universitet Med udstillingen WE LOVE THE CITY vil vi formidle mødet mellem urban design oog arkitektur. Disciplinen ’at bygge by’ har de seneste 20 år ikke tændt hjerterne hos...... fjern og ’usexet’ for unge arkitekter in spe. Det kan fremtidens by ikke være tjent med, og WE LOVE THE CITY vil derfor gerne vise alle, der færdes i byen og bruger dens arkitektur, at her er et potentiale. Med udstillingen WE LOVE THE CITY ønsker Utzon Centeret, LasseVegas Kontoret ApS og ADEPT...

  20. City sewer collectors biocorrosion

    Science.gov (United States)

    Ksiażek, Mariusz

    2014-12-01

    This paper presents the biocorrosion of city sewer collectors impregnated with special polymer sulphur binders, polymerized sulphur, which is applied as the industrial waste material. The city sewer collectors are settled with a colony of soil bacteria which have corrosive effects on its structure. Chemoautotrophic nitrifying bacteria utilize the residues of halites (carbamide) which migrate in the city sewer collectors, due to the damaged dampproofing of the roadway and produce nitrogen salts. Chemoorganotrophic bacteria utilize the traces of organic substrates and produce a number of organic acids (formic, acetic, propionic, citric, oxalic and other). The activity of microorganisms so enables the origination of primary and secondary salts which affect physical properties of concretes in city sewer collectors unfavourably.

  1. The potential hydrothermal systems unexplored in the Southwest Indian Ocean

    Science.gov (United States)

    Suo, Yanhui; Li, Sanzhong; Li, Xiyao; Zhang, Zhen; Ding, Dong

    2017-01-01

    Deep-sea hydrothermal vents possess complex ecosystems and abundant metallic mineral deposits valuable to human being. On-axial vents along tectonic plate boundaries have achieved prominent results and obtained huge resources, while nearly 90% of the global mid-ocean ridge and the majority of the off-axial vents buried by thick oceanic sediments within plates remain as relatively undiscovered domains. Based on previous detailed investigations, hydrothermal vents have been mapped along five sections along the Southwest Indian Ridge (SWIR) with different bathymetry, spreading rates, and gravity features, two at the western end (10°-16°E Section B and 16°-25°E Section C) and three at the eastern end (49°-52°E Section D, 52°-61°E Section E and 61°-70°E Section F). Hydrothermal vents along the Sections B, C, E and F with thin oceanic crust are hosted by ultramafic rocks under tectonic-controlled magmatic-starved settings, and hydrothermal vents along the Section D are associated with exceed magmatism. Limited coverage of investigations is provided along the 35°-47°E SWIR (between Marion and Indomed fracture zones) and a lot of research has been done around the Bouvet Island, while no hydrothermal vents has been reported. Analyzing bathymetry, gravity and geochemical data, magmatism settings are favourable for the occurrence of hydrothermal systems along these two sections. An off-axial hydrothermal system in the southern flank of the SWIR that exhibits ultra-thin oceanic crust associated with an oceanic continental transition is postulated to exist along the 100-Ma slow-spreading isochron in the Enderby Basin. A discrete, denser enriched or less depleted mantle beneath the Antarctic Plate is an alternative explanation for the large scale thin oceanic crust concentrated on the southern flank of the SWIR.

  2. Poroelastic response of mid-ocean ridge hydrothermal systems to ocean tidal loading: Implications for shallow permeability structure

    Science.gov (United States)

    Barreyre, Thibaut; Sohn, Robert A.

    2016-02-01

    We use the time delay between tidal loading and exit-fluid temperature response for hydrothermal vents to model the poroelastic behavior and shallow upflow zone (SUZ) effective permeability structure of three mid-ocean ridge (MOR) sites with different spreading rates. Hydrothermal vents at Lucky Strike field exhibit relatively small phase lags corresponding to high SUZ effective permeabilities of ≥ ~10-10 m2, with variations that we interpret as resulting from differences in the extrusive layer thickness. By contrast, vents at East Pacific Rise site exhibit relatively large phase lags corresponding to low SUZ effective permeabilities of ≤ ~10-13 m2. Vents at Main Endeavour field exhibit both high and low phase lags, suggestive of a transitional behavior. Our results demonstrate that tidal forcing perturbs hydrothermal flow across the global MOR system, even in places where the tidal amplitude is very low, and that the flow response can be used to constrain variations in SUZ permeability structure beneath individual vent fields.

  3. Numerical Modeling of Brine Formation and Serpentinization at the Rainbow Hydrothermal System

    Science.gov (United States)

    Sekhar, P.; Lowell, R. P.

    2015-12-01

    The Rainbow hydrothermal field on the Mid Atlantic Ridge is a high-temperature hydrothermal system hosted in peridotite. The vent fluids are rich in methane and hydrogen suggesting that serpentinization is occurring at depth in the system. Vent temperature of ~365°C, salinity of ~4.5 wt%, and heat output of ~500 MW suggest that Rainbow field is driven by a magmatic heat source and that phase separation is occurring at depth. To understand the origin of high salinity in the Rainbow hydrothermal fluid, we construct a 2D numerical model of two-phase hydrothermal circulation using the numerical simulator FISHES. This code uses the finite volume method to solve the conservation of mass, momentum, energy, and salt equations in a NaCl-H2O fluid. We simulate convection in an open top 2D box at a surface pressure of 23 MPa and seawater temperature of 10oC. The bottom and sides of the box are insulated and impermeable, and a fixed temperature distribution is maintained at the base to ensure phase separation. We first consider a homogeneous model with a permeability of 10-13 m2 and system depths of 2 and 1 km, respectively. The brine-derived fluid from the deeper system barely exceeds seawater, whereas the shallower system produces a short pulse of 9.0 wt% for 5 years. We then consider 1 km deep systems with a high permeability discharge zone of 5x10-13 m2 that corresponds to a fault zone, surrounded by recharge zones of 10-13, 10-14 and 10-15 m2, respectively. The model with recharge permeability of 10-14 m2 yields stable plumes that vent brine-derived fluid of 4.2 wt% for 150 years. Using the quasi- steady state of this model as a base, we estimate the rate of serpentinization along the fluid flow paths, and evolution of porosity and permeability. This analysis will indicate the extent to which serpentinization will affect the dynamics of the system and will provide insight into methane flux in the Rainbow vent field.

  4. Direct Measurements of Hydrothermal Heat Output at Juan de Fuca Ridge

    Science.gov (United States)

    Germanovich, L. N.; di Iorio, D.; Genc, G.; Hurt, R. S.; Lowell, R. P.; Holden, J. F.; Butterfield, D. A.; Olson, E. J.

    2009-12-01

    Heat output and fluid flow are key parameters for characterizing seafloor hydrothermal systems at oceanic spreading centers. In particular, they are essential for examining partition of heat and geochemical fluxes between discrete and diffuse flow components. Hydrothermal heat output also constrains permeability of young oceanic crust and thickness of the conductive boundary layer separating hydrothermal circulation from the underlying magmatic heat source. Over the past several years, we have deployed a number of relatively simple devices to make direct measurements of focused and diffuse flow. Most recently, we have used cup anemometer and turbine flow meters to measure fluid flow and heat flux at individual high-temperature vents and diffuse flow sites. The turbine flow meter (Figure 1) includes a titanium rotor assembly housed within a stainless steel tube and supported by sapphire bearings. The device can be used at different seafloor settings for measurements of both diffuse and focused flow. The spin of the rotor blades is videotaped to acquire the angular velocity, which is a function of the flow rate determined through calibration. We report data obtained during four cruises to the Main Endeavor and High Rise vent fields, Juan de Fuca Ridge (JdFR), between 2007 and 2009. Overall more than 50 successful measurements of heat flow have been made on a variety of high-, medium-, and low-temperature hydrothermal sites on the Endeavor, Mothra, and High Rise structures. For example, the velocity of diffuse flow at Endeavor ranged from ~1 to ~10 cm/sec. The flow velocity from black smokers varied from ~10 cm/sec to ~1 m/sec, which appears to be similar to EPR 9°N. Typical measurements of heat flux obtained at JdFR ranged from ~1 kW for diffuse flow to ~1 MW for black smokers. Although it is difficult to extrapolate the data and obtain the integrated heat output for a vent field on JdFR, the data are used to characterize the heat fluxes from individual vent

  5. Aging City Leads Way

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The northern city of Dalian has become a model of care for the elderly that other Chinese cities are following Chinese Minister of Civil Affairs Li Xueju has called upon civil affairs agencies in the nation to learn from Dalian’s diversified models for elderly care,ranging from running collectively owned and foreign-designed nursing homes to offering tax incentives to private households and companies serving the elderly

  6. Tectonic localization of multi-plume hydrothermal fluid flow in a segmented rift system, Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Rowland, J. V.; Downs, D. T.; Scholz, C.; de P. S. Zuquim, M.

    2013-05-01

    High-temperature (>250°C) multi-plume hydrothermal systems occur in a range of tectonic settings, though most are extensional or transtensional. A key feature of such settings is their tendency to partition into discrete structural elements that scale with the thickness of the seismogenic zone. The late Miocene to present record of arc magmatism and rifting in the North Island of New Zealand illustrates the importance of structural segmentation and reactivation of inherited basement fabrics on the localisation of hydrothermal upflow. The 15 My record of similarly-oriented magmatism, rifting and hydrothermal activity associated with subduction of the Pacific Plate beneath the North Island of New Zealand. Lateral migration of the locus of arc magmatism, concomitant with roll-back of the subducting slab, is supported by the SE-directed younging of: 1) volcanism; 2) fault-controlled rift basins; and 3) hydrothermal activity, represented by the distribution of epithermal mineralisation within the ~15-3 Ma Coromandel Volcanic Zone (CVZ), and geothermal activity within the TVZ. Currently the TVZ is extending in a NW-SE direction at a rate that varies from ~3 mm/yr to ~15 mm/yr from SW to NE, respectively. The TVZ is partitioned into discrete rift segments, comprising arrays of NE-striking normal faults of ~20 km in length, as expected on mechanical grounds for the 6-8 km-thick seismogenic zone. Transfer zones between rift segments coincide with N-to-NW-trending alignments of geothermal fields, spaced ~ 30 km apart can be recognized elsewhere within the CVZ. The most productive epithermal deposits to date are localised where these inferred transfer zones intersect arc-parallel fault arrays. A similar tectonic configuration occurs in the Deseado Massif, Argentinian Patagonia, where interplay between transfer and rift faults is inferred to have localized hydrothermal fluids in small pull-apart basins and arrays of extension veins for durations >30 My.

  7. City marketing: online communication plan for the city of Lisbon

    OpenAIRE

    Altrichter, Benjamin

    2011-01-01

    Mestrado em Marketing City Marketing represents marketing efforts of cities in order to attract more visitors. Today, we are confronted everyday with marketing campaigns in all different communication media promoting countries, cities or events. Cities are competing for visitors on a global scale, forcing them to adapt successful marketing strategies for gaining and retaining costumers. Yet, City Marketing still remains an unknown chapter for a big part of the general public an...

  8. Mapping deep-sea hydrothermal deposits with an in-loop transient electromagnetic method: Insights from 1D forward and inverse modeling

    Science.gov (United States)

    Jang, Hangilro; Kim, Hee Joon

    2015-12-01

    In transient electromagnetic (TEM) measurements, secondary fields that contain information on conductive targets such as hydrothermal mineral deposits in the seafloor can be measured in the absence of strong primary fields. A TEM system using a loop source is useful to the development of compact, autonomous instruments, which are well suited to submersible-based surveys. In this paper, we investigate the possibility of applying an in-loop TEM system to the detection of marine hydrothermal deposits through a one-dimensional modeling and inversion study. We examine step-off responses for a layered model and compare the characteristics of horizontal and vertical loop systems for detecting hydrothermal deposits. The feasibility study shows that TEM responses are very sensitive to a highly conductive layer. Time-domain target responses are larger and appear earlier in horizontal magnetic fields than in vertical ones, although the vertical field has 2-3 times larger magnitude than the horizontal one. An inverse problem is formulated with the Gauss-Newton method and solved with the damped and smoothness-constrained least-squares approach. The test example for a marine hydrothermal TEM survey demonstrated that the depth extent, conductivity and thickness of the highly conductive layer are well resolved.

  9. Iron-Oxidizing Bacteria Found at Slow-Spreading Ridge: a Case Study of Capelinhos Hydrothermal Vent (Lucky Strike, MAR 37°N)

    Science.gov (United States)

    Henri, P. A.; Rommevaux, C.; Lesongeur, F.; Emerson, D.; Leleu, T.; Chavagnac, V.

    2015-12-01

    Iron-oxidizing bacteria becomes increasingly described in different geological settings from volcanically active seamounts, coastal waters, to diffuse hydrothermal vents near seafloor spreading centers [Emerson et al., 2010]. They have been mostly identified and described in Pacific Ocean, and have been only recently found in hydrothermal systems associated to slow spreading center of the Mid-Atlantic Ridge (MAR) [Scott et al., 2015]. During the MoMARSAT'13 cruise at Lucky Strike hydrothermal field (MAR), a new hydrothermal site was discovered at about 1.5 km eastward from the lava lake and from the main hydrothermal vents. This active venting site, named Capelinhos, is therefore the most distant from the volcano, features many chimneys, both focused and diffuses. The hydrothermal end-member fluids from Capelinhos are different from those of the other sites of Lucky Strike, showing the highest content of iron (Fe/Mn≈3.96) and the lowest chlorinity (270 mmol/l) [Leleu et al., 2015]. Most of the chimneys exhibit rust-color surfaces and bacterial mats near diffuse flows. During the MoMARSAT'15 cruise, an active chimney, a small inactive one, and rust-color bacterial mat near diffuse flow were sampled at Capelinhos. Observations by SEM of the hydrothermal samples revealed the presence of iron oxides in an assemblage of tubular "sheaths", assembled "stalks", helical "stalks" and amorphous aggregates. These features are similar to those described from the Loihi iron-mats deposits and argue for the occurrence of iron-oxidizing bacteria. Cultures under micro-aerobic and neutral pH conditions allowed us to isolate strains from the small inactive chimney. Pyrosequencing of the 16S rRNA gene of the isolates and environmental samples will soon be performed, which should confirm the presence of iron-oxidizing bacteria and reveal the organization of bacterial communities in this original and newly discovered hydrothermal site of the slow spreading Mid-Atlantic Ridge. Emerson

  10. Sinking coastal cities

    Science.gov (United States)

    Erkens, G.; Bucx, T.; Dam, R.; de Lange, G.; Lambert, J.

    2015-11-01

    In many coastal and delta cities land subsidence now exceeds absolute sea level rise up to a factor of ten. A major cause for severe land subsidence is excessive groundwater extraction related to rapid urbanization and population growth. Without action, parts of Jakarta, Ho Chi Minh City, Bangkok and numerous other coastal cities will sink below sea level. Land subsidence increases flood vulnerability (frequency, inundation depth and duration of floods), with floods causing major economic damage and loss of lives. In addition, differential land movement causes significant economic losses in the form of structural damage and high maintenance costs for (infra)structure. The total damage worldwide is estimated at billions of dollars annually. As subsidence is often spatially variable and can be caused by multiple processes, an assessment of subsidence in delta cities needs to answer questions such as: what are the main causes? What is the current subsidence rate and what are future scenarios (and interaction with other major environmental issues)? Where are the vulnerable areas? What are the impacts and risks? How can adverse impacts be mitigated or compensated for? Who is involved and responsible to act? In this study a quick-assessment of subsidence is performed on the following mega-cities: Jakarta, Ho Chi Minh City, Dhaka, New Orleans and Bangkok. Results of these case studies will be presented and compared, and a (generic) approach how to deal with subsidence in current and future subsidence-prone areas is provided.

  11. Site-City Interaction through Modifications of Site Effects

    CERN Document Server

    Semblat, Jean-François; Guéguen, Philippe; Bard, Pierre-Yves; Duval, Anne Marie

    2009-01-01

    The analysis of seismic site effects generally disregards the influence of surface structures on the free field motion in densely urbanized areas. This paper aims at investigating this particular problem called site-city interaction especially by comparison to the "free-field" amplification process. Several evidences (experimental, analytical, numerical) of the site-city interaction phenomenon have been given in previous work (Gu\\'eguen, Bard, Semblat 2000). The influence of site city-interaction could be large for structures having eigenfrequencies close to that of the surface soil layers. Furthermore, the density of structures is also an important governing parameter of the problem. Considering a specific site (Nice, France) where site-city interaction is supposed to be significant, we start from detailed experimental and numerical studies of seismic site effects giving both amplification levels and occuring frequencies, as well as the location of the maximum amplification areas. The influence of site-city ...

  12. Fine-scale heat flow, shallow heat sources, and decoupled circulation systems at two sea-floor hydrothermal sites, Middle Valley, northern Juan de Fuca Ridge

    Energy Technology Data Exchange (ETDEWEB)

    Stein, J.S.; Fisher, A.T. [Univ. of California, Santa Cruz, CA (United States); Langseth, M.; Jin, W.; Iturrino, G. [Lamont-Doherty Earth Observatory, Palisades, NY (United States); Davis, E. [Geological Survey of Canada, Sidney, British Columbia (Canada). Pacific Geoscience Centre

    1998-12-01

    Fine-scale heat-flow patterns at two areas of active venting in Middle Valley, a sedimented rift on the northern Juan de Fuca Ridge, provide thermal evidence of shallow hydrothermal reservoirs beneath the vent fields. The extreme variability of heat flow is explained by conductive heating immediately adjacent to vents and shallow circulation within sediments above the reservoir. This secondary circulation is hydrologically separated from the deeper system feeding the vents by a shallow conductive lid within the sediments. A similar separation of shallow and deep circulation may also occur at sediment-free ridge-crest hydrothermal environments.

  13. A comparative study on heat dissipation, morphological and magnetic properties of hyperthermia suitable nanoparticles prepared by co-precipitation and hydrothermal methods

    Indian Academy of Sciences (India)

    Md Shariful Islam; Yoshihumi Kusumoto; Junichi Kurawaki; Md Abdulla-Al-Mamun; Hirotaka Manaka

    2012-12-01

    Magnetite (Fe3O4) nanoparticles were prepared by co-precipitation and hydrothermal methods and their phase transfer was done successfully to compare their performances in different aspects. Synthesized nanoparticles were characterized for XRD, FE–SEM, TEM, UV-Vis absorption (reflectance) spectra, magnetic hysteresis loops and a.c. magnetic field induced hyperthermia. The magnetic nanoparticles prepared by the co-precipitation method show superior performances in respect of heat dissipation capability, saturation of magnetization values and particle size when compared to those prepared by the hydrothermal method.

  14. Magnetic and Dielectric Investigations of Mn-Doped Ba Hexaferrite Nanoparticles by Hydrothermal Approach

    Science.gov (United States)

    Adeela, N.; Khan, U.; Iqbal, M.; Riaz, S.; Ali, H.; Maaz, K.; Naseem, S.

    2016-11-01

    A hydrothermal method followed by heat treatment was used to synthesize Mn-substituted Ba2Co2- x Mn x Fe12O22 nanoparticles with a nominal chemical composition of 0 ≤ x magnetic measurements. It was found that the sample at x = 0.9 is of particular interest due to its large coercivity and anisotropy. Later on, for x = 0.9, temperature-dependent magnetic analyses including hysteresis loops, zero-field-cooled, and field-cooled at a particular field of 100 Oe were performed. The decreasing trend in saturation magnetization with increase in temperature was estimated. On the other hand, first an increase and then decrease in coercivity values were observed. These loops also revealed dependence of coercivity on magneto-crystalline anisotropy and average crystallite size of nanoparticles. Dielectric measurements at x = 0.9 make it suitable for high frequency applications.

  15. Hydrothermal synthesis of pyrochlores and their characterization

    Science.gov (United States)

    Redkin, Alexander F.; Ionov, Andrey M.; Kotova, Nataliya P.

    2013-10-01

    Pyrochlores, microlites, and U-betafites of pyrochlore group minerals were obtained from mixing experiments of the corresponding oxides and fluorides by hydrothermal synthesis at T = 800 °C and P = 200 MPa in the solution of 1.0 M NaF. The presence of U4+ in pyrochlore does not affect the cell parameter, which for the phases of pyrochlore-microlite series is 10.42 ± 0.01 Å. In a system with an excess of UO2, pyrochlores and microlites, containing uranium up to 0.2-0.3 atoms per formula unit (apfu), are formed. In the uranium-free system of betafites composition, perovskites and Ti-bearing pyrochlores are formed. U-pyrochlores of betafite series, containing 2Ti = Nb + Ta in moles, have cubic cell parameters of 10.26 ± 0.02 Å and U4+ isomorphic capacity of 0.4-0.5 apfu. In the pyrochlore structure, U4+ may substitute for Ca2+ and Na+ cations in the eightfold site. In pyrochlores of pyrochlore-microlite series, Ca2+ is replaced by U4+, while in pyrochlores of betafite series, U4+ replaces Na+. Phases with pyrochlore structure, containing U5+ and U6+ in the sixfold site, usually occupied by Nb5+, Ta5+, and Ti4+, are formed under oxidizing conditions (Cu-Cu2O buffer). They are characterized by low content of Nb5+, Ta5+ (<0.1 apfu), and anomalous behavior of the crystal lattice (compression, instead of expansion). Under natural conditions, the formation of pyrochlores containing a significant amount of U5+ and U6+ is unlikely.

  16. Properties and degradability of hydrothermal carbonization products.

    Science.gov (United States)

    Eibisch, Nina; Helfrich, Mirjam; Don, Axel; Mikutta, Robert; Kruse, Andrea; Ellerbrock, Ruth; Flessa, Heinz

    2013-09-01

    Biomass carbonized via hydrothermal carbonization (HTC) yields a liquid and a carbon (C)-rich solid called hydrochar. In soil, hydrochars may act as fertilizers and promote C sequestration. We assumed that the chemical composition of the raw material (woodchips, straw, grass cuttings, or digestate) determines the properties of the liquid and solid HTC products, including their degradability. Additionally, we investigated whether easily mineralizable organic components adsorbed on the hydrochar surface influence the degradability of the hydrochars and could be removed by repetitive washing. Carbon mineralization was measured as CO production over 30 d in aerobic incubation experiments with loamy sand. Chemical analysis revealed that most nutrients were preferably enriched in the liquid phase. The C mineralization of hydrochars from woodchips (2% of total C added), straw (3%), grass (6%), and digestate (14%) were dependent on the raw material carbonized and were significantly lower (by 60-92%; < 0.05) than the mineralization of the corresponding raw materials. Washing of the hydrochars significantly decreased mineralization of digestate-hydrochar (up to 40%) but had no effect on mineralization rates of the other three hydrochars. Variations in C mineralization between different hydrochars could be explained by multiple factors, including differences in the O/C-H/C ratios, C/N ratios, lignin content, amount of oxygen-containing functional groups, and pH. In contrast to the solids, the liquid products were highly degradable, with 61 to 89% of their dissolved organic C being mineralized within 30 d. The liquids may be treated aerobically (e.g., for nutrient recovery).

  17. Submarine Hydrothermal Sites in Arc Volcanic-Back Arc Environment: Insight from Recent Marine Geophysical Investigations in the Southern Tyrrhenian Sea.

    Science.gov (United States)

    Cocchi, L.; Ligi, M.; Bortoluzzi, G.; Petersen, S.; Plunkett, S.; Muccini, F.; Canese, S.; Caratori Tontini, F.; Carmisciano, C.

    2014-12-01

    Hydrothermal alteration processes involve mineralogical and chemical changes, which are reflected in a major modification of potential field patterns observed over hydrothermal areas. Basalt-hosted hydrothermal sites exhibit characteristic responses with magnetic lows and minima of the gravity field. Near bottom AUV (Autonomous Underwater Vehicle) based potential field surveys have become a very effective technique in deep sea exploration. Here we present results of recent ship-borne and near seafloor magnetic and gravity investigations at deep (Marsili and Palinuro seamounts) and shallow (Panarea, Basiluzzo and Secca del Capo) hydrothermal sites in the Southern Tyrrhenian Sea including multibeam bathymetry, seafloor reflectivity and seismic profiles. At Marsili seamount, a large Fe-Mn-oxyhydroxides-rich chimney field is located at the summit (500 m depth). This site is correlated with pronounced magnetic and gravity lows (0 A/m and 2.0 g/cm3). Deep tow magnetic survey (Cruise MAVA11) revealed strong association between the complicated magnetization pattern and the main volcano-tectonic features of the ridge. Hydrothermal manifestations at Palinuro seamount occur mainly on the western sector within the rim of a caldera structure at depth of 600m. Recent AUV based magnetic surveys (Cruise POS442, 2012 using AUV "Abyss") detailed a magnetization low interpreted to represent the local distribution of subseafloor hydrothermal alteration (potentially massive sulfide deposits), and also mapped previously undiscovered inactive chimney fields. Hydrothermal sites observed at the arc-related volcanic islands (Panarea, Basiluzzo, Eolo and Secca del Capo) are confined to shallow depths (less then 300m) and associated with large ochreaceous mounds, vents and chimney fields such as those observed E of Basiluzzo Island. At this site a recent magnetic survey (Cruise PANA13_ASTREA) combined with Remote Operated Vehicle (ROV) investigations revealed that the submarine geothermal

  18. Mineralized iron oxidizing bacteria from hydrothermal vents: targeting biosignatures on Mars

    Science.gov (United States)

    Leveille, R. J.

    2010-12-01

    Putative hydrothermal systems have been identified on Mars based on orbital imagery and rover-based analyses. Based on Earth analogs, hydrothermal systems on Mars would be highly attractive for their potential for preserving organic and inorganic biosignatures. For example, iron oxidizing bacteria are ubiquitous in marine and terrestrial hydrothermal systems, where they often display distinctive cell morphologies and are commonly encrusted by minerals, especially bacteriogenic iron oxides and silica. Microfossils of iron oxidizing bacteria have been found in ancient Si-Fe deposits and iron oxidation may be an ancient and widespread metabolic pathway. In order to investigate mineralized iron oxidizing bacteria as a biosignature, we have examined samples collected from extinct hydrothermal vents along Explorer Ridge, NE Pacific Ocean. In addition, microaerophilic iron oxidizing bacteria, isolated from active Pacific hydrothermal vents, were grown in a Fe-enriched seawater medium at constant pH (6.5) and O2 concentration (5%) in a controlled bioreactor system. Samples and experimental products were examined with a combination of variable-pressure and field-emission scanning electron microscopy (SEM), in some cases by preparing samples with a focused ion beam (FIB) milling system. Light-toned seafloor samples display abundant filamentous forms resembling, in both size and shape (1-5 microns in diameter and up to several microns in length), the twisted stalks of Gallionella and the elongated filaments of Leptothrix. Some samples consist entirely of low-density masses of silica (>90% Si) encrusted filamentous forms. The presence of unmineralized filamentous matter rich in C and Fe suggests that these are the remains of iron oxidizing bacteria. Mineralized filaments sectioned by FIB show variable internal material within semi-hollow, tubular-like features. Silica encrustations also show pseudo-concentric growth bands. In the bioreactor runs, abundant microbial growth and

  19. Sinking Coastal Cities

    Science.gov (United States)

    Erkens, G.; Stuurman, R.; De Lange, G.; Bucx, T.; Lambert, J.

    2014-12-01

    In many coastal cities land subsidence now exceeds absolute sea level rise up to a factor of ten. Without action, parts of Jakarta, Ho Chi Minh City, Bangkok and numerous other coastal cities will continue to sink, even below sea level. The ever increasing industrial and domestic demand for water in these cities results in excessive groundwater extraction, causing severe subsidence. In addition, coastal cities are often faced with larger natural subsidence, as they are built on thick sequences of soft soil. The impacts of subsidence are further exacerbated by climate-induced sea level rise. Land subsidence results in two types damage: foremost it increases flood vulnerability (frequency, inundation depth and duration of floods), with floods causing major economic damage and loss of lives. Secondly, differential land movement causes significant economic losses in the form of structural damage and high maintenance costs of roads and transportation networks, sewage systems, buildings and foundations. The total damage worldwide is estimated at billions of dollars annually. To survey the extent of groundwater associated subsidence, we conducted a quick-assessment of subsidence in a series of mega-cities (Jakarta, Ho Chi Minh City, Dhaka, New Orleans and Bangkok). For each city research questions included: what are the main causes, how much is the current subsidence rate and what are predictions, where are the vulnerable areas, what are the impacts and risks, how can adverse impacts can be mitigated or compensated for, and what governmental bodies are involved and responsible to act? Using the assessment, this paper discusses subsidence modelling and measurement results from the selected cities. The focus is on the importance of delayed settlement after increases in hydraulic heads, the role of the subsurface composition for subsidence rates and best practice solutions for