WorldWideScience

Sample records for chrome violet

  1. The CHROME Honors Program

    Science.gov (United States)

    Wilson, Eleanor

    2002-01-01

    The CHROME Honors Program was designed as a two-week residential program for 9th and 1Oth grade students participating in CHROME clubs. The curriculum focused on the health sciences with instruction from: (1) the science and health curriculum of the Dozoretz National Program for Minorities in Applied Sciences (DNIMAS) Program of Norfolk State University (NSU); (2) the humanities curriculum of the NSU Honors Program; (3) NASA-related curriculum in human physiology. An Advisory Committee was formed to work with the Project Coordinator in the design of the summer program.

  2. ALTERNATIVE TO CHROME ETCHING PROCESSES FOR METALS

    Science.gov (United States)

    Several industries, including the National Center for Manufacturing Science have initiated programs for chrome abatement. The programs, however, generally focus on chrome reduction by use of existing technologies and do not address the elimination of chrome in pretreatment proces...

  3. Refinement of Aluminum Thermal Chrome

    International Nuclear Information System (INIS)

    Refinement of aluminum thermal chrome of the X98.5 mark by a high-temperature annealing in high vacuum is explored experimentally. It is shown that at the temperature of annealing 1150 C during 1...6 hours the content of such interstitial impurity as nitrogen is essentially depressed in chrome, and also the content of aluminum and iron admixtures is noticeably moderated

  4. Low-Chrome/Chrome Free Refractories for Slagging Gasifiers

    International Nuclear Information System (INIS)

    Gasifiers are containment vessels used to react carbon-containing materials with oxygen and water, producing syngas (CO and H2) that is used in chemical and power production. It is also a potential source of H2 in a future hydrogen economy. Air cooled slagging gasifiers are one type of gasifier, operating at temperatures from 1275-1575 C and at pressures of 400 psi or higher. They typically use coal or petroleum coke as the carbon source, materials which contain ash impurities that liquefy at the gasification temperatures, producing liquid slag in quantities of 100 or more tons/day, depending on the carbon fed rate and the percent ash present in the feedstock. The molten slag is corrosive to refractory linings, causing chemical dissolution and spalling. The refractory lining is composed of chrome oxide, alumina, and zirconia; and is replaced every 3-24 months. Gasifier users would like greater on-line availability and reliability of gasifier liners, something that has impacted gasifier acceptance by industry. Research is underway at NETL to improve refractory service life and to develop a no-chrome or low-chrome oxide alternative refractory liner. Over 250 samples of no- or low-chrome oxide compositions have been evaluated for slag interactions by cup testing; with potential candidates for further studies including those with ZrO2, Al2O3, and MgO materials. The development of improved liner materials is necessary if technologies such as IGCC and DOE's Near Zero Emissions Advanced Fossil Fuel Power Plant are to be successful and move forward in the marketplace

  5. Chrome - Free Aluminum Coating System

    Science.gov (United States)

    Bailey, John H.; Gugel, Jeffrey D.

    2010-01-01

    This slide presentation concerns the program to qualify a chrome free coating for aluminum. The program was required due to findings by OSHA and EPA, that hexavalent chromium, used to mitigate corrosion in aerospace aluminum alloys, poses hazards for personnel. This qualification consisted of over 4,000 tests. The tests revealed that a move away from Cr+6, required a system rather than individual components and that the maximum corrosion protection required pretreatment, primer and topcoat.

  6. Streamlining Book Requests with Chrome

    OpenAIRE

    Dr. Rachel Schulkins; Joseph Schulkins

    2015-01-01

    This article starts by examining why a Chrome Extension was desired and how we saw it making the workflow for requesting new items both easier and more accurate. We then go on to outline how we constructed our extension, looking at the folder structure, third party scripts and services that combine to make this achievable. Finally, the article looks at how the extension is regulated and plans for future development.

  7. Streamlining Book Requests with Chrome

    Directory of Open Access Journals (Sweden)

    Dr. Rachel Schulkins

    2015-10-01

    Full Text Available This article starts by examining why a Chrome Extension was desired and how we saw it making the workflow for requesting new items both easier and more accurate. We then go on to outline how we constructed our extension, looking at the folder structure, third party scripts and services that combine to make this achievable. Finally, the article looks at how the extension is regulated and plans for future development.

  8. Viscoelasticity Studies for Chrome-Free Leather

    Science.gov (United States)

    Chrome-free leather such as glutaraldehyde-tanned leather behaves very differently from chrome-tanned leather. Information regarding its viscoelasticity has not been reported. Hysteresis and stress relaxation are two essential properties associated with viscoelasticity. We have designed a cyclic ...

  9. Hex Chrome Free Coatings for Electronics Overview

    Science.gov (United States)

    Kessel, Kurt

    2013-01-01

    The overall objective of the Hex Chrome Free Coatings for Electronics project is to evaluate and test pretreatment coating systems not containing hexavalent chrome in avionics and electronics housing applications. This objective will be accomplished by testing strong performing coating systems from prior NASA and DoD testing or new coating systems as determined by the stakeholders.

  10. Le chrome en milieu marin

    OpenAIRE

    Chiffoleau, Jean-francois

    1994-01-01

    Le présent document constitue une synthèse des connaissances sur le cycle biogéochimique du chrome. Les sources naturelles et anthropiques sont étudiées, les échanges entre les différents compartiments géochimiques sont évalués, avec une attention particulière portée à la quantification des apports aussi bien des fleuves que de l'atmosphère au milieu marin. Les niveaux de concentration dans ces compartiments sont évalués, et montrent que l'on rencontre dans certaines régions des contamination...

  11. Chrome recycling from leather solid wastes

    International Nuclear Information System (INIS)

    Leather processing is one of the industrial activities that generate chromium bearing wastes in different forms, one of them is chrome shavings which contributes about 10% of the quantum raw skins /hides, and causes on burning dangerous human hazardous. Hydrolysis processes by different alkalis such as (LiOK KOH, NaOH) have been applied to recover chrome from solid wastes. The extent of hydrolysis was studied as a function of alkalis concentrations, in presence and absence of reducing agents, shaking time and temperature. Hydrolysis process exhibits 99%, 98% and 97%, chrome recovery for LiOH, KOH and NaOH respectively. The recovered chrome has been used in retaining process, examined through visual and mechanical tests of leather samples. The evaluation of the tanning process with recovered chrome gave acceptable results

  12. Thermal spray coatings replace hard chrome

    International Nuclear Information System (INIS)

    Hard chrome plating provides good wear and erosion resistance, as well as good corrosion protection and fine surface finishes. Until a few years ago, it could also be applied at a reasonable cost. However, because of the many environmental and financial sanctions that have been imposed on the process over the past several years, cost has been on a consistent upward trend, and is projected to continue to escalate. Therefore, it is very important to find a coating or a process that offers the same characteristics as hard chrome plating, but without the consequent risks. This article lists the benefits and limitations of hard chrome plating, and describes the performance of two thermal spray coatings (tungsten carbide and chromium carbide) that compared favorably with hard chrome plating in a series of tests. It also lists three criteria to determine whether plasma spray or hard chrome plating should be selected

  13. Reclamation treatment of the chrome leather scrap

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A novel method to extract protein and Cr(III) from the chrome leather scrap discarded by leather industry is described.Chrome leather scarp was hydrolyzed under basic condition to remove chromium compound and extract protein. The extracted protein was mixed with substrate and used as feed protein after being dried and ground. The basic residue was treated with sulfuric acid to obtain chrome(III) sulfate which can be used as tanning agent again after adjusting pH with base. The acidic residue was processed and used as flower fertilizer. The safety of the protein powder produced has been by toxicology and nutriology test. This reclamation method has been industrialized.

  14. Ion beams replace chrome plating

    International Nuclear Information System (INIS)

    Metal ion implantation is the process of altering surface properties by bombarding with high-energy metal ions. Because the process does not produce a coating, dimensions and bulk properties of the part remain unchanged, and implanted surfaces have no problems with adhesion, residual stress, or poor microstructure. Implanted surfaces can provide wear and/or corrosion resistance comparable with, or superior to, chrome plating. Furthermore, it is a relatively low-temperature process, which enables treatment of materials such as plastics, aluminum, and low-alloy steel. Furthermore, the performance of coatings can be improved by bombarding with ions during or after the coating process. Specifically, high-energy ions applied during deposition have been shown to reduce the required temperature for physical vapor deposition (PVD) systems, overcoming one of the major obstacles to replacing chromium plating with PVD coatings. This article will review the latest advances in metal-ion implantation equipment, with particular reference to economics and applications

  15. Vacuum ultra violet monochromators

    International Nuclear Information System (INIS)

    The general field of spectrometers for the ultra violet has been covered at great length in the past and much invaluable material is on record. Here we limit our attention to monochromators rather than spectrographs and consider only those which are of use in the vacuum ultra violet region (say 10 to 1800 A) for Synchrotron Radiation work. We further restrict our consideration to those which use reflection gratings although it is clear that the traditional domination of the field by these devices is being increasingly challenged by the development of transmission gratings of various kinds. Even with these limitations the number of different optical arrangements that have been used is still very large so we well make some attempt to see how the general classes of Rowland circle, plane grating and the new Toroidal grating monochromators (TGM's) have succeeded in the past. We then make some fairly subjective evaluations of which approaches hold the best promise for the future and discuss in more detail the basis of these approaches and how they might be implemented

  16. Hexavalent-Chrome Free Coatings Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The replacement of hexavalent chrome [Cr (VI)] in the processing of aluminum for high-reliability electronics applications in the aviation and aerospace sector...

  17. 21 CFR 73.2775 - Manganese violet.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Manganese violet. 73.2775 Section 73.2775 Food and... ADDITIVES EXEMPT FROM CERTIFICATION Cosmetics § 73.2775 Manganese violet. (a) Identity. The color additive manganese violet is a violet pigment obtained by reacting phosphoric acid, ammonium...

  18. Spectrophotometric determination of zirconium with Chrome Azurol s in aqueous streams of nuclear fuel reprocessing

    International Nuclear Information System (INIS)

    A sensitive and reproducible spectrophotometric method for the determination of zirconium is developed. The method is based on the formation of stable bluish violet colour complex with Chrome Azurol S (CAS) with maximum absorption at 598 nm. The complex formed obeys Beer's law in the range of 1-7 μg/mL. Under optimum conditions, the sensitivity of the proposed method, (i.e. the detection limit), molar absorptivity and Sandell's sensitivity values are 2.42 μg/mL, 3.93 x103 L.Mol-1.cm-1 and 2.54 x 10-4 μg/cm2 respectively. Relative standard deviation is less than 2% and correlation coefficient is 0.997. The present method is highly sensitive, selective, rapid and simple. It can be applied for the direct determination of zirconium in environmental, industrial, water and nuclear reprocessing samples. (author)

  19. Ultrasound assisted chrome tanning: Towards a clean leather production technology.

    Science.gov (United States)

    Mengistie, Embialle; Smets, Ilse; Van Gerven, Tom

    2016-09-01

    Nowadays, there is a growing demand for a cleaner, but still effective alternative for production processes like in the leather industry. Ultrasound (US) assisted processing of leather might be promising in this sense. In the present paper, the use of US in the conventional chrome tanning process has been studied at different pH, temperature, tanning time, chrome dose and US exposure time by exposing the skin before tanning and during tanning operation. Both prior exposure of the skin to US and US during tanning improves the chrome uptake and reduces the shrinkage significantly. Prior exposure of the skin to US increase the chrome uptake by 13.8% or reduces the chrome dose from 8% to 5% (% based on skin weight) and shorten the process time by half while US during tanning increases the chrome uptake by 28.5% or reduces the chrome dose from 8% to 4% (half) and the tanning time to one third compared to the control without US. Concomitantly, the resulting leather quality (measured as skin shrinkage) improved from 5.2% to 3.2% shrinkage in the skin exposed to US prior tanning and to 1.3% in the skin exposed to US during the tanning experiment. This study confirms that US chrome tanning is an effective and eco-friendly tanning process which can produce a better quality leather product in a shorter process time with a lower chromium dose. PMID:27150762

  20. PHOTOTHERMAL DEGRADATION OF BLACK CHROME - A POSSIBLE CONTRIBUTING FACTOR

    OpenAIRE

    Driver, P.; Mccormick, P.

    1981-01-01

    By a review of the electrochemistry of the electrodeposition of black chrome, it has been possible to identify a previously unrecognised factor which is almost certain to contribute to the photothermal degradation of black chrome. Methods have been proposed for reducing or eliminating the effects of these photothermally sensitive constituents.

  1. Hexavalent Chrome Free Coatings for Electronics Applications: Joint Test Report

    Science.gov (United States)

    Rothgeb, Matt; Kessel, Kurt

    2013-01-01

    The overall objective of the Hexavalent Chrome Free Coatings for Electronics Applications project is to evaluate and test pretreatments not containing hexavalent chrome in avionics and electronics housing applications. This objective will be accomplished by testing strong performing coating systems from prior NASA and DoD testing or new coating systems as determined by the stakeholders.

  2. NASA TEERM Hexavalent Chrome Alternatives Projects

    Science.gov (United States)

    Kessel, Kurt R.; Rothgeb, Matthew

    2011-01-01

    The overall objective of the Hex Chrome Free Coatings for Electronics project is to evaluate and test pretreatment coating systems not containing hexavalent chrome in avionics and electronics housing applications. This objective will be accomplished by testing strong performing coating systems from prior NASA and DoD testing or new coating systems as determined by the stakeholders. The technical stakeholders have agreed that this protocol will focus specifically on Class 3 coatings. Original Equipment Manufacturers (OEMs), depots, and support contractors have to be prepared to deal with an electronics supply chain that increasingly provides parts with lead-free finishes, some labeled no differently and intermingled with their SnPb counterparts. Allowance of lead-free components presents one of the greatest risks to the reliability of military and aerospace electronics. The introduction of components with lead-free terminations, termination finishes, or circuit boards presents a host of concerns to customers, suppliers, and maintainers of aerospace and military electronic systems such as: 1. Electrical shorting due to tin whiskers 2. Incompatibility of lead-free processes and parameters (including higher melting points of lead-free alloys) with other materials in the system 3. Unknown material properties and incompatibilities that could reduce solder joint reliability

  3. 40 CFR 415.340 - Applicability; description of the chrome pigments production subcategory.

    Science.gov (United States)

    2010-07-01

    ... chrome pigments production subcategory. 415.340 Section 415.340 Protection of Environment ENVIRONMENTAL... SOURCE CATEGORY Chrome Pigments Production Subcategory § 415.340 Applicability; description of the chrome... introduction of pollutants into publicly owned treatment works resulting from the production of chrome pigments....

  4. Percolation-type behavior in black chrome selective solar films

    International Nuclear Information System (INIS)

    The optical constants (n and k) and dc resistivity have been measured for black chrome particulate solar absorbing coatings for the purpose of defining the applicability of various inhomogeneous medium theories in the description of the black chrome optical response. It has been shown that percolation-type behavior does exist in the films and hence of the various theories, only those exhibiting percolation at the 0.3 packing fraction value determined for the black chrome films are applicable. The two valid approaches are an effective medium theory first proposed by Bruggeman and a modified Maxwell Garnett theory which includes a particle shape distribution

  5. Lung cancer in Yorkshire chrome platers, 1972-97

    OpenAIRE

    Sorahan, T; Harrington, J

    2000-01-01

    OBJECTIVES—To investigate mortality from lung cancer in chrome platers, a group exposed to chromic acid.
METHODS—The mortality of a cohort of 1087 chrome platers (920 men, 167 women) from 54 plants situated in the West Riding of Yorkshire, United Kingdom, was investigated for the period 1972-97. All subjects were employed as chrome platers for ⩾3 months and all were alive on 31 May 1972. Mortality data were also available for a cohort of 1163 comparison workers with no known occupational expo...

  6. Quality Improvement of Chrome-Diamond Coatings on Flowing Chrome Plating

    Science.gov (United States)

    Belyaev, V. N.; Koslyuk, A. Yu; Lobunets, A. V.; Andreyev, A. S.

    2016-04-01

    The research results of the process of flowing chrome plating of internal surfaces of long-length cylindrical articles with the usage of electrolyte with ultra-dispersed diamonds when continuous article rotation, while chromium-plating, are presented. During experiments the following varying technological parameters: electrolyte temperature and article frequency rotation were chosen, and experimental samples were obtained. Estimation of porosity, micro-hardness, thickness of chrome coatings and uniformity were performed as well as the precipitation structure by the method of scanning electron microscopy. The results showed that the use of ultra-dispersed diamonds and realization of the scheme with rotation of detail-cathode when flowing chromium-plating allows one to increase servicing characteristics of the coating due to the decrease of grains size of chrome coating and porosity, and due to the increase of micro-hardness, so confirming the efficiency of using the suggested scheme of coating application and the given type of ultra-dispersed fillers when chromium-plating.

  7. Molecular spectroscopic study for suggested mechanism of chrome tanned leather

    Science.gov (United States)

    Nashy, Elshahat H. A.; Osman, Osama; Mahmoud, Abdel Aziz; Ibrahim, Medhat

    2012-03-01

    Collagen represents the structural protein of the extracellular matrix, which gives strength of hides and/or skin under tanning process. Chrome tan is the most important tanning agent all over the world. The methods for production of leather evolved over several centuries as art and engineering with little understanding of the underlying science. The present work is devoted to suggest the most probable mechanistic action of chrome tan on hide proteins. First the affect of Cr upon hide protein is indicated by the studied mechanical properties. Then the spectroscopic characterization of the hide protein as well as chrome tanned leather was carried out with Horizontal Attenuated Total Reflection (HATR) FT-IR. The obtained results indicate how the chromium can attached with the active sites of collagen. Molecular modeling confirms that chromium can react with amino as well as carboxylate groups. Four schemes were obtained to describe the possible interactions of chrome tan with hide proteins.

  8. Don’t let Chrome expose your passwords

    CERN Multimedia

    Computer Security Team

    2013-01-01

    Do you still struggle with remembering your password? Is this despite our many attempts to help you: “Train your Brain: Don't put your password on paper!" (article here), “Creativity@CERN” (article here) and “Maths to the rescue!" (article here)? Then you might have considered the “save your password” features in Chrome, Firefox or Internet Explorer… these features remember your Facebook, CERN, Twitter, Amazon and ebay passwords. But be careful: it might be easy for someone to read them!   If enabled, Chrome, Firefox, Internet Explorer and others can remember the password of specific sites after you’ve logged in to those sites the first time. As the passwords are, however, stored in plain text, they can still be read out by anyone with access to that computer. In Chrome, just type “chrome://settings/passwords” and click the password you want to reveal. Or in F...

  9. CAPSULE REPORT: HARD CHROME FUME SUPPRESSANTS & CONTROL TECHNOLOGIES

    Science.gov (United States)

    All existing information which includes the information extrapolated from the Hard Chrome Pollution Prevention Demonstration Project(s) and other sources derived from plating facilities and industry contacts, will be condensed and featured in this document. At least five chromium...

  10. Chromatographic characterization of products isolated from chrome shavings

    OpenAIRE

    Edivaldo E Garcia; Cláudia C.M Kimura; Ariovaldo C Martins; Gisele O Rocha; Jorge Nozaki

    1999-01-01

    Gel permeation chromatography and high performance liquid chromatography were employed for separation and chemical characterization of products isolated from chrome shavings. After enzymatic hydrolysis, the products isolated were peptides of higher molecular weight. Peptides of lower molecular weight and free aminoacids were the main products using sulfuric acid in chrome shavings solubilization. Glycine (17%) , glutamic acid (10.6%) , alanine (9.2%) , and arginine (8.2%) were the principal a...

  11. Chrome-plating of titanium alloys and their performance

    International Nuclear Information System (INIS)

    The impact of technological parameters by electrochemical chrome-plating of titanium alloys on their mechanical properties, wear resistance, fatigue resistance, antifriction characteristics, hydridation and hydrogen distribution in the base and coating is studied. The evaluation of the alloys and coatings overgrowing with microorganisms is given. The rational compositions of solutions and regimes of titanium alloys treatment by their multiple (up to 6 times) chrome-plating are determined

  12. LABORATORY STUDY FOR THE REDUCTION OF CHROME (VI) TO CHROME (III) USING SODIUM METABISULFITE UNDER ACIDIC CONDITIONS

    International Nuclear Information System (INIS)

    This report describes the results from RPP-PLAN-32738, 'Test Plan for the Effluent Treatment Facility to Reduce Chrome(VI) to Chrome(I1I) in the Secondary Waste Stream', using sodium metabisulfite. Appendix A presents the report as submitted by the Center for Laboratory Sciences (CLS) to CH2M HILL Hanford Group, Inc. The CLS carried out the laboratory effort under Contract Number 21065, release Number 30. This report extracts the more pertinent aspects of the laboratory effort

  13. Biodegradation of crystal violet by Agrobacterium radiobacter.

    Science.gov (United States)

    Parshetti, G K; Parshetti, S G; Telke, A A; Kalyani, D C; Doong, R A; Govindwar, S P

    2011-01-01

    Agrobacterium radiobacter MTCC 8161 completely decolorized the Crystal Violet with 8 hr (10 mg/L) at static anoxic conditions. The decreased decolorization capability by A. radiobacter was observed, when the Crystal Violet concentration was increased from 10 to 100 mg/L. Semi-synthetic medium containing 1% yeast extract and 0.1% NH4C1 has shown 100% decolorization of Crystal Violet within 5 hr. A complete degradation of Crystal Violet by A. radiobacter was observed up to 7 cycles of repeated addition (10 mg/L). When the effect of increasing inoculum concentration on decolorization of Crystal Violet (100 mg/L) was studied, maximum decolorization was observed with 15% inoculum concentration. A significant increase in the activities of laccase (184%) and aminopyrine N-demethylase (300%) in cells obtained after decolorization indicated the involvement of these enzymes in decolorization process. The intermediates formed during the degradation of Crystal Violet were analyzed by gas chromatography and mass spectroscopy (GC/MS). It was detected the presence of N,N,N',N"-tetramethylpararosaniline, [N, N-dimethylaminophenyl] [N-methylaminophenyl] benzophenone, N, N-dimethylaminobenzaldehyde, 4-methyl amino phenol and phenol. We proposed the hypothetical metabolic pathway of Crystal Violet biodegradation by A. radiobacter. Phytotoxicity and microbial toxicity study showed that Crystal Violet biodegradation metabolites were less toxic to bacteria (A. radiobacter, P. aurugenosa and A. vinelandii) contributing to soil fertility and for four kinds of plants (Sorghum bicolor Vigna radiata, Lens culinaris and Triticum aestivum) which are most sensitive, fast growing and commonly used in Indian agriculture. PMID:22128547

  14. The coating layer structure of commercial chrome plates

    International Nuclear Information System (INIS)

    Highlights: • AES and XPS depth profiling analysis were used in the experiment. • The detailed coating layer structure of the commercial chrome plate was obtained. • Peak fitting method was used to investigate the chemical states of Cr in the coating. - Abstract: The surface and cross-sectional morphologies of the commercial chrome plate coating layer with the thickness of dozens of nanometers have been observed. To investigate the detailed structure of the coating layer, Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) combined with the low energy Ar+ sputtering technique have been employed. Through careful analysis of experimental data, it can be obtained that the coating layer of commercial chrome plates is composed of four layers from top to bottom with different compositions

  15. The coating layer structure of commercial chrome plates

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Sheng, E-mail: chen_sheng@baosteel.com

    2015-07-15

    Highlights: • AES and XPS depth profiling analysis were used in the experiment. • The detailed coating layer structure of the commercial chrome plate was obtained. • Peak fitting method was used to investigate the chemical states of Cr in the coating. - Abstract: The surface and cross-sectional morphologies of the commercial chrome plate coating layer with the thickness of dozens of nanometers have been observed. To investigate the detailed structure of the coating layer, Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) combined with the low energy Ar{sup +} sputtering technique have been employed. Through careful analysis of experimental data, it can be obtained that the coating layer of commercial chrome plates is composed of four layers from top to bottom with different compositions.

  16. GSDO Program Hexavalent Chrome Alternatives: Final Pretreatments Test Report

    Science.gov (United States)

    Kessel, Kurt

    2013-01-01

    Hexavalent chrome free pretreatments should be considered for use on Ground Support Equipment (OSE) and Electrical Ground Support Equipment (EOSE). Both of the hexavalent chrome free pretreatments (Metalast TCP HF and SurTec 650C) evaluated by this project met, and in some instances exceeded, the requirements ofMIL-DTL-5541 "Chemical Conversion Coatings on Aluminum and Aluminum Alloys". For DC resistance measurements, both Metalast TCP HF and SurTec (!50C met initial requirements following assembly and in many cases continued to maintain passing readings for the duration of testing.

  17. Biodegradation of Crystal Violet by Agrobacterium radiobacter

    DEFF Research Database (Denmark)

    Parshetti, G.K.; Parshetti, S.G.; Telke, A.A.;

    2011-01-01

    containing 1% yeast extract and 0.1% NH4C1 has shown 100% decolorization of Crystal Violet within 5 hr. A complete degradation of Crystal Violet by A. radiobacter was observed up to 7 cycles of repeated addition (10 mg/L). When the effect of increasing inoculum concentration on decolorization of Crystal......) contributing to soil fertility and for four kinds of plants (Sorghum bicolor, Vigna radiata, Lens culinaris and Triticum aestivum) which are most sensitive, fast growing and commonly used in Indian agriculture....

  18. Analytical and electrochemical evaluation of the in vitro corrosion behavior of nickel-chrome and cobalt-chrome casting alloys for metal-ceramic restorations.

    Science.gov (United States)

    Yfantis, Constaninos; Yfantis, Dimitrios; Anastassopoulou, Jane; Theophanides, Theophilos

    2007-03-01

    In this study we examined the hypothesis based on relevant literature survey that the in vitro corrosion behavior of a Cobalt-chrome dental casting alloy for metal-ceramic restorations is better than that of a Nickel-chrome dental casting alloy. The corrosion released metal ions were analysed by Inductively Coupled Plasma-Atomic Emission Spectroscopy. Moreover, the specimens were electrochemically tested by linear polarization. The statistical analysis of the results showed statistically significant differences in corrosion rates of Nickel-chrome alloy and Cobalt-chrome alloy calculated by analytical and electrochemical measurements. The hypothesis was confirmed and the results showed that the corrosion rates of the Cobalt-chrome alloy were lower than that of the Nickel-chrome alloy. PMID:17378457

  19. Refinement in black chrome for use as a solar selective coating

    Science.gov (United States)

    Mcdonald, G. E.

    1974-01-01

    Black chrome is significant as a solar selective coating because the current extensive use of black chrome in the electroplating industry as a durable decorative finish makes black chrome widely available on a commercial scale and potentially low in cost as a solar selective coating. Black-chrome deposits were modified by underplating with dull nickel or by being plated on rough surfaces. Both of these procedures increased the visible absorptance. There was no change in the infrared reflectance for the dull-nickel - black-chrome combination from that reported for the bright-nickel - black-chrome combination. However, the bright-nickel - black-chrome coating plated on rough surfaces indicated a slight decrease in infrared reflectance. As integrated over the solar spectrum for air mass 2, the reflectance of the dull-nickel - black-chrome coating was 0.077, of the bright-nickel - black-chrome coating plated on a 0.75-micron (30-microinch) surface was 0.070, of the bright-nickel - black-chrome coating plated on a 2.5 micron (100-microinch) surface was 0.064. The corresponding values for the bright-nickel - black-chrome coating on a 0.0125-micron (0.5-microinch) surface, two samples of black nickel, and two samples of Nextrel black paint were 0.132, 0.123, 0.133, and 0.033, respectively.

  20. Chrome induced nasal septal perforation-An occupational hazard

    OpenAIRE

    Krishna, N. Joshi

    2004-01-01

    86 patients, working in a chemical factory dealing with Chrome manufacturing job, were referred by Health Inspectai to F S 1 S Hospital O PD 32 patients out of above were found to be having Nasal septal perforation and were recommended to Medical Board for consideration of compensation as cases of Occupational hazard

  1. Photometric determination of molybdenum in standard chrome-plating electrolyte

    International Nuclear Information System (INIS)

    A method of photometric determination of molybdenum is considered regarding the chrome-plating electrolytes (Cr-Mo coverage). The following features are found to underlie the method: the ability of molybdenum (unlike chromium) to escape codeposition with Mg(OH)2 residue, reduction of Mo(6) to Mo(5) and Mo(4) and formation of colored thiocyanate complexes. 5 refs

  2. PROCESSING CHROME TANNERY EFFLUENT TO MEET BEST AVAILABLE TREATMENT STANDARDS

    Science.gov (United States)

    To satisfy stream discharge requirements at its Winchester, N.H., chrome tan shearling tannery, the A. C. Lawrence Leather Co., Inc. selected primary and secondary systems that are unique as applied to tannery effluent treatment in the United States. Primary clarification is acco...

  3. Study of the reasons of chrome-plated steel embrittlement

    International Nuclear Information System (INIS)

    To study the reasons of embrittement, the mechanical characteristics and hydrogen content in high-strength steel (tensile strength approximately 2O0 kgf/mm2) during electrolytic chrome-plating from a standard electrolyte (60 μm), heating (200 deg, 2 hrs) and aging (20 deg, 7 days) of the chrome-plated samples have been tested. The hydrogen content in the steel base after chromium removal is measured using the method of vacuum extraction at a temperature of 400 deg. The results obtained permit to describe the mechanism of the decrease in service characteristics of chrome-plated steel. The presence of brittle and low-tensile chromium on the sample surface results in the formation of cracks in it under loading. The cracks are concentrators of strains, i.e. in the presence of chromium the work of crack initiation decreases. Therefore, mechanical characteristics of samples with chromium on the surface turn out to be lower than those in the chromium absence. Hydrogen accumulation in the steel base reduces the work of crack propagation the greater the lower hydrogen content is. Hence, mechanical characteristics of chrome-plated samples have the least magnitude at the highest hydrogen content in the steel base

  4. A systematic investigation of solar collector chrome black surfaces

    International Nuclear Information System (INIS)

    A study has been made of a series of mild steel samples electroplated with a chrome black surface. The technique of Rutherford backscatterng of alpha particles in the 2.5 mev range was used to try to further elucidate the findings of recent workers concerning the actual structure of the surface and to determine the Cr-O ratios with depth

  5. REACTIONS OF CHROME TANNERY SLUDGE WITH ORGANIC AND MINERAL SOILS

    Science.gov (United States)

    Chrome tannery sludge applied to agricultural land may have benefits in terms of added N for crop growth. An experiment was designed to compare tannery waste with commercial N fertilizer and investigate the potential of the waste as an alternative or supplement to commercial fert...

  6. Violet stimulated luminescence: geo- or thermochronometer?

    DEFF Research Database (Denmark)

    Ankjærgaard, Christina; Guralnik, Benny; Porat, N.;

    2015-01-01

    The method of quartz optically stimulated luminescence (OSL) dating is widely used, but generally limited to the past ~0.1 million years (Ma) due to early saturation of the desired signal. Violet stimulated luminescence (VSL) of quartz has previously been shown as a promising alternative, with a...

  7. High Temperature Brush Seal Tuft Testing of Selected Nickel-Chrome and Cobalt-Chrome Superalloys

    Science.gov (United States)

    Fellenstein, James A.; DellaCorte, Christopher; Moore, Kenneth D.; Boyes, Esther

    1997-01-01

    The tribology of brush seals is of considerable interest to turbine engine designers because bristle wear continues to limit long term seal performance and life. To provide better materials characterization and foster the development of improved seals, NASA Lewis has developed a brush seal tuft tester. In this test, a 'paintbrush' sample tuft is loaded under constant contact pressure against the outside diameter of a rotating journal. With this configuration, load and friction are directly measured and accurate wear measurements are possible. Previously reported research using this facility showed excellent data repeatability and wear morphology similar to published seal data and dynamic rig tests. This paper is an update of the ongoing research into the tribology of brush seals. The effects of wire materials processing on seal wear and the tribological results for three journal coatings are discussed. Included in the materials processing were two nickel-chrome superalloys each processed to two different yield strengths. The results suggest that seal wear is dependent more on material composition than processing conditions.

  8. Ultra Violet Imaging Telescope (UVIT) on ASTROSAT

    CERN Document Server

    Kumar, Amit; Hutchings, J; Kamath, P U; Kathiravan, S; Mahesh, P K; Murthy, J; S, Nagbhushana; Pati, A K; Rao, M N; Rao, N K; Sriram, S; Tandon, S N

    2012-01-01

    Ultra Violet Imaging Telescope on ASTROSAT Satellite mission is a suite of Far Ultra Violet (FUV 130 to 180 nm), Near Ultra Violet (NUV 200 to 300 nm) and Visible band (VIS 320 to 550nm) imagers. ASTROSAT is the first multi wavelength mission of INDIA. UVIT will image the selected regions of the sky simultaneously in three channels and observe young stars, galaxies, bright UV Sources. FOV in each of the 3 channels is about 28 arc-minute. Targeted angular resolution in the resulting UV images is better than 1.8 arc-second (better than 2.0 arc-second for the visible channel). Two identical co-aligned telescopes (T1, T2) of Ritchey-Chretien configuration (Primary mirror of 375 mm diameter) collect celestial radiation and feed to the detector system via a selectable filter on a filter wheel mechanism; gratings are available in filter wheels of FUV and NUV channels for slit-less low resolution spectroscopy. The detector system for each of the 3 channels is generically identical. One of the telescopes images in the...

  9. Micropropagation of African violet (Saintpaulia ionantha Wendl.).

    Science.gov (United States)

    Shukla, Mukund; Sullivan, J Alan; Jain, Shri Mohan; Murch, Susan J; Saxena, Praveen K

    2013-01-01

    Micropropagation is an important tool for rapid multiplication and the creation of genetic variability in African violets (Saintpaulia ionantha Wendl.). Successful in vitro propagation depends on the specific requirements and precise manipulation of various factors such as the type of explants used, physiological state of the mother plant, plant growth regulators in the culture medium, and growth conditions. Development of cost-effective protocols with a high rate of multiplication is a crucial requirement for commercial application of micropropagation. The current chapter describes an optimized protocol for micropropagation of African violets using leaf explants obtained from in vitro grown plants. In this process, plant regeneration occurs via both somatic embryogenesis and shoot organogenesis simultaneously in the explants induced with the growth regulator thidiazuron (TDZ; N-phenyl-N'-1,2,3-thidiazol-5-ylurea). The protocol is simple, rapid, and efficient for large-scale propagation of African violet and the dual routes of regeneration allow for multiple applications of the technology from simple clonal propagation to induction or selection of variants to the production of synthetic seeds. PMID:23179707

  10. The synthesis of thermite chrome-silicon steels

    OpenAIRE

    Жигуц, Юрій Юрійович

    2013-01-01

    The present paper shows the basic solutions of the problem of obtaining chrome-silicon steels examines the use of thermite steels, the benefits of combining thermite steels with metallotermic methods of getting materials. The advantages of metallotermic synthesis methods include: autonomy of processes, independence of energy sources and simplicity of equipment, high-performance process and easy transition from experimental research to industrial production. The need to develop the technology ...

  11. Effect of gamma radiation on chrome-tanned sheepskin

    International Nuclear Information System (INIS)

    Effect of 60 γ-radiation on chrome-tanned, blue-stock sheepskin was investigated. Radiation was applied between 0.35-10.5 Mrad and the resultant physical and mechanical changes were observed. Radiation did not change the water adsorption capability of leather but caused significant reductions in shrinkage temperature and tensile strength. The correlations between dose and radiation hazards were determined. (author)

  12. Tribology; Cold rolling mill roll; Hard chrome; Surface texturing.

    Directory of Open Access Journals (Sweden)

    José Lucio Gonçalves Junior

    2012-12-01

    Full Text Available The present work analyzes the tribological behavior of surface modifications often used in cold rolling mill rolls. Different surface modifications were carried out on samples produced from a fragment of the rolling mill roll: i texturing; ii chromium plating; iii texturing with subsequent hard chrome plating; iv and hard chrome plating with subsequent texturing. Before the surface modifications the samples were heat treated and ground on both faces. Wear tests were performed using a reciprocating movement of a ball over flat configuration under a load of 9.8 N. It is observed that there is no significant change in the coefficient of friction as a function of surface modification. Surface texturing increases the wear of the counter body, while the hard chromium coating reduces it. The addition of hard chromium coating promotes the formation of a tribolayer on the counter body consisting of chromium and oxygen. On the other hand, for the samples without hard chrome coating, the tribolayer consists of iron and oxygen

  13. Syndeformation Chrome Spinels Inclusions in the Plastically Deformed Olivine Aggregates (Kraka Ophiolites, the Southern Urals)

    OpenAIRE

    D. E. Saveliev; I. A. Blinov

    2015-01-01

    This article presents the results of structural, petrographic, mineralogical and chemical studies of dunite veinlets in spinel peridotite from the Kraka ophiolites. It is demonstrated that plastic deformation of polycrystalline olivine, which form dunite, was accompanied by precipitation of impurities (aluminum and chrome) as newly formed chrome spinels. The thinnest acicular inclusions of 0.3-0.5 micron thick are aligned in olivine grains along [010] axis. Bigger elongated irregular chrome s...

  14. Black chrome on commercially electroplated tin as a solar selecting coating

    Science.gov (United States)

    Mcdonald, G. E.

    1977-01-01

    The reflectance properties of black chrome electroplated on commercially electroplated tin were measured for various black chrome plating times for both the solar and infrared spectrum. The values of absorptance and emittance were calculated from the measured reflectance values. The results indicate that the optimum combination of the highest absorptance in the solar region and the lowest emittance in the infrared of the black chrome plated on commercially electroplated tin is obtained for a black chrome plating time of between one and two minutes.

  15. Treatments to enhance properties of chrome-free (wet white) leather

    Science.gov (United States)

    Production of chrome-free or wet white leather, predominantly for upholstery leather, is fast approaching that which has been traditionally tanned with chrome. Recycling of auto parts, specifically the car seats, is driving the momentum towards this type of leather. Wet white leathers are sometime...

  16. Selective coating for solar panels. [using black chrome and black nickel

    Science.gov (United States)

    Mcdonald, G. E. (Inventor)

    1977-01-01

    The energy absorbing properties of solar heating panels are improved by depositing a black chrome coating of controlled thickness on a specially prepared surface of a metal substrate. The surface is prepared by depositing a dull nickel on the substrate, and the black chrome is plated on this low emittance surface to a thickness between 0.5 micron and 2.5 microns.

  17. Green route for the utilization of chrome shavings (chromium-containing solid waste) in tanning industry.

    Science.gov (United States)

    Rao, Jonnalagadda Raghava; Thanikaivelan, Palanisamy; Sreeram, Kalarical Janardhanan; Nair, Balachandran Unni

    2002-03-15

    Chromium-containing wastes from various industrial sectors are under critical review. Leather processing is one such industrial activity that generates chromium-bearing wastes in different forms. One of them is chrome shavings, and this contributes to an extent of 10% of the quantum of raw skins/hides processed, amounting to 0.8 million ton globally. In this study, the high protein content of chrome shavings has been utilized for reduction of chromium(VI) in the preparation of chrome tanning agent. This approach has been exploited for the development of two products: one with chrome shavings alone as reducing agent and the other with equal proportion of chrome shavings and molasses. The developed products exhibit more masking due to the formation of intermediate organic oligopeptides. This has been corroborated through the spectral, hydrolysis, and species-wise distribution studies. The formation of these organic masking agents helps in chrome tanning by shifting the precipitation point of chromium to relatively higher pH levels. Hence, the developed products find use as chrome tanning agents for leather processing, thus providing a means for better utilization of chrome shaving wastes. PMID:11944695

  18. Hysteresis and Stress Relaxation Studies for a Fibrous Collagen Material: Chrome-free Leather

    Science.gov (United States)

    Animal hides are the most valuable coproduct of the meat industry, and most of those hides are converted into leather. Due to concerns over the use and disposal of chrome-tanned leather, the leather industry is now facing increasing scrutiny over its use of chrome as a tanning agent. The use of no...

  19. FINAL REPORT FOR THE REDUCTION OF CHROME (VI) TO CHROME (III) IN THE SECONDARY WASTE STREAM OF THE EFFLUENT TREATMENT FACILITY

    Energy Technology Data Exchange (ETDEWEB)

    DUNCAN JB; GUTHRIE MD

    2008-08-29

    This report documents the laboratory results of RPP-PLAN-35958, Test Plan for the Effluent Treatment Facility to Reduce Chrome (VI) to Chrome (III) in the Secondary Waste Stream With the exception of the electrochemical corrosion scans, all work was carried out at the Center for Laboratory Science (CLS) located at the Columbia Basin College. This document summarizes the work carried out at CLS and includes the electrochemical scans and associated corrosion rates for 304 and 316L stainless steel.

  20. The effect of chrome adhesion layer on quartz resonator aging.

    Energy Technology Data Exchange (ETDEWEB)

    Wessendorf, Kurt O.; Ohlhausen, James Anthony

    2011-03-01

    This SAND report documents a late start LDRD designed to determine the possible aging effects of a quartz resonator gold adhesion layer. Sandia uses quartz resonators for applications. These applications require a very stable frequency source with excellent aging (low drift) characteristics. These parts are manufactured by one of our qualified vendors outside Sandia Laboratories, Statek Corp. Over the years we, Sandia and the vendor, have seen aging variations that have not been completely explained by the typical mechanisms known in the industry. One theory was that the resonator metallization may be contributing to the resonator aging. This LDRD would allow us to test and analyze a group of resonators with known differentiating metallization and via accelerated aging determine if a chrome adhesion layer used to accept the final gold plating may contribute to poor aging. We worked with our main vendor to design and manufacture a set of quartz resonators with a wide range of metallization thickness ratios between the chrome and gold that will allow us determine the cause of this aging and which plating thickness ratios provide the best aging performance while not degrading other key characteristics.

  1. Acylated delphinidin glycosides from violet and violet-blue flowers of Clematis cultivars and their coloration.

    Science.gov (United States)

    Sakaguchi, Keisuke; Kitajima, Junichi; Iwashina, Tsukasa

    2013-11-01

    Three new acylated delphinidin glycosides, delphinidin 3-O-beta-[(2"-trans-caffeoylglucopyranosyl)-(1 --> 2)-(6"-succinylgalactopyranoside)]-7-O-beta-glucopyranoside (1), delphinidin 3-O-beta-[(2"-trans-caffeoylglucopyranosyl)-(1 --> 2)-(6"-trans-caffeoyl-tartaroyl-malonylgalactopyranoside)]-7-O-beta-glucopyranoside (2), and delphinidin 3-O-beta-[(2"-trans-caffeoylglucopyranosyl)-(1 --> 2)-(6"-trans-caffeoyl-tartaroyl-malonylgalactopyranoside)]-3'-O-beta-glucuronopyranoside (3), were isolated from the violet and violet-blue sepals of Clematis cultivars 'Jackmanii Superba' and 'Fujimusume'. The chemical structures of the isolated anthocyanins were determined by LC-MS, characterization of hydrolyzates, and UV, 1H and 13C NMR spectroscopy. The visible absorption spectra of these anthocyanins were compared with those of fresh sepals and crude extracts in pH 5.1 buffer solution. In addition, the co-pigment effect with some kaempferol glycosides and caffeoylglucose was examined. PMID:24427942

  2. Photodetector of ultra-violet radiation

    International Nuclear Information System (INIS)

    The invention relates to photodetectors on the semiconductors base, in particular, to photodetectors of ultra-violet radiation and can be used in the optoelectronics systems for determining the intensity and dose of ultraviolet radiation emitted by the Sun and other sources. In the structure of the photodetector of ultraviolet radiation with a superficial potential barrier formed of semiconductors A3B5 with the prohibited power width Eg1, solid solutions thereof with the prohibited power width Eg2 and SnO2 or ITO, in the semiconductors A3B5 at a surface distance less than the absorption length of the visible radiation it is formed an isotype heterojunction between the semiconductors A3B5 and solid solutions thereof with the prohibited power width Eg2 > Eg1. The technical result consists in manufacturing of a photodetector sensitive solely to the ultraviolet radiation

  3. Safety study on ultra-violet radiation

    International Nuclear Information System (INIS)

    Ultra-violet radiation (UVR) falls under category of non-ionising radiation (NIR). Excessive exposure to ultra-violet radiation (UVR) may cause significant health hazard to human beings. The sun is the main source of UVR which produce the radiation in the form of solar radiation. Due to its ability to cause hazard, a study of UV solar radiation exposure was conducted around Bangi, Selangor. For this preliminary study, selected measurement location were around Universiti Kebangsaan Malaysia (UKM) and MINT. The study was carried out by direct measurement of the radiation quantitatively with due consideration given on variation of time, cloud and weather condition. Research radiometer model IL 1700 with three different sensors were used for measurement of UV-A, UV-B and UV-C and they were connected to Laptop with LabView software for data analysis. The results were compared with the permissible exposure limits recommended by IRPA/ICNIRP. In addition to assessment of direct exposure to UVR the study also look into the effectiveness of absorption for some material such as tinted glass and different kind of clothing. The results showed that UV-A, UV-B and UV-C emitted directly from the sun around UKM and MINT were below the permissible limit recommended by IRPA/ICNIRP for members of public (30 J/m2 or 1mWm-2). Besides that, they study found that tinted glass was effective to protect us from excessive exposure to UVR . For clothing we found that the silk fabric with light colour is more applicable for filtering UV radiation, compare to the other type of fabric. (Author)

  4. Preparation of high exhaust chrome from leather shavings and hydrocarbons with its application in leather processing for green tanning technology

    International Nuclear Information System (INIS)

    The use of chrome in tanning has made the remarkable advances to achieve the best quality and quantity of leather. But the chrome tanning process is associated with the generation of heavy metal containing solid wastes and toxic effluents. To solve the environmental issues we emphasized on the development of high exhaust chrome complex from chrome containing leather wastes that could minimize the toxic effluents up to negligible limit. Therefore in the synthetic process of chrome tanning material, the chrome shavings and the hydrocarbons have been utilized as a reductant as well as the potential masking intermediates. These chrome tanning materials have been prepared using leather shavings alone in product A, partial replacement of shavings by hydrocarbons for product B and then replacement of hydrocarbons by molasses for product C. The materials have been employed for the tanning of goat skins parallel to the commercial basic chromium sulfate (BCS). (author)

  5. Performance evaluation of two black nickel and two black chrome solar collectors

    Science.gov (United States)

    Losey, R.

    1977-01-01

    The test program was based on the evaluation of four unique solar collectors described below: (1) black nickel collector surface with a desiccant drying bed, (2) black nickel collector surface without a desiccant drying bed, (3) black chrome collector surface with a dessicant drying bed, and (4) black chrome collector surface without a desiccant drying bed. The test program included three distinct phases: Initial performance evaluation, natural environmental aging, and post-aging performance evaluation. Results of Phase III testing conclusively indicated a higher normalized efficiency for Black Chrome surfaces when compared to Black Nickel.

  6. Spectrophotometric determination of uranium(VI) with chrome azurol S and benzyldimethyllaurylammonium bromide

    International Nuclear Information System (INIS)

    Trace quantities of uranium are often determined by spectrophotometric methods based on the reaction of uranyl ions with triphenylmethane dyes, e.g. with chrome azurol S, eriochrome cyanine R, aluminone, or methyl blue. Sensitivity of the methods in which chrome azurol S was used appeared to be 3x104 l.mol-1.cm-1. We have observed that benzyldimethyllaurylammonium bromide (Sterinol ST) is a good reagent, improving the sensitivity in the U(VI) determination by means of chrome azurol S. Previously we had successfully used this reagent for the determination of trace amounts of Be, Al, In and V(IV). (orig./EF)

  7. The PL "violet shift" of cerium dioxide on silicon

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    CeO2 thin film was fabricated by dual ion beam epitaxial technique. The phenomenon of PL violet shift at room temperature was observed, and the distance of shift was about 65 nm. After the analysis of crystal structure and valence in the compound were carried out by XRD and XPS technique, it was concluded that the PL shift was related with valence of cerium ion in the oxides. When the valence of cerium ion varied from tetravalence to trivalence, the PL peak position would move from blue region to violet region and the phenomenon of "violet shift" was observed.

  8. Hard chrome and molybdenum coatings produced by physical vapour deposition

    International Nuclear Information System (INIS)

    Coatings of solid solutions of carbon or nitrogen in chromium or molybdenum were prepared by cathodic magnetron sputtering. Carbon or nitrogen was introduced either through the gas phase by reactive sputtering or by direct sputtering of sintered composite targets. Chemical and structural analyses of films revealed the formation of supersaturated solid solutions for carbon or nitrogen concentrations of up to several weight per cent. The nitride and carbide phases predicted from the binary diagrams were not observed. The Cr-C and Mo-C coatings showed hardnesses of up to 2500 HV. The hardnesses of Mo-N and Cr-N reached 3000 HV. The wear and corrosion resistance of these coatings, which showed a dense structure, was superior to that of electrolytic hard chrome. (Auth.)

  9. Spectrophotometric determination of beryllium in bronzes with chrome azurol S

    International Nuclear Information System (INIS)

    Some remarks on the spectrophotometric determination of beryllium in bronzes using Chrome Azurol S (CAS) are given. The determination was performed at pH=6.5 and 10.0 using hexamethylene-tetramine and ammoniacal buffers, respectively. It was demonstrated that the determination of Be with CAS at pH=10.0 is slightly less sensitive, but it has two advantages which are important in obtaining reliable results. First, is the shorter time to reach the equilibrium between Be and CAS, and second, is lower pH sensitivity so that a better precision of the results at pH=10.0 overcompensate the slightly lower sensitivity at this pH in comparison with that at pH=6.5. (Author)

  10. Failure Mechanisms in High Chrome Oxide Gasifier Refractories

    Science.gov (United States)

    Bennett, James P.; Kwong, Kyei-Sing

    2011-04-01

    Gasification is a high-temperature, high-pressure chemical process used to convert a carbon feedstock into CO and H2 (syngas) for use in power generation and the production of chemicals. It is also a leading candidate as a source of hydrogen in a hydrogen economy and is one of several technologies expected to see increased use in advanced fossil fuel power systems in the future. Gasification is being evaluated because of its high efficiency, its ability to capture CO2 for sequestration or reuse in other applications, and its potential for carbon feedstock fuel flexibility. At the heart of the gasification process is a gasifier, a high pressure chemical reaction vessel used to contain the interactions between carbon and water in a shortage of oxygen, producing syngas. The gasifier is lined with high chrome oxide materials to protect the containment vessel. Gasifiers are complex systems, and failure of the refractories used to line them was identified by industry as a limitation to their reliability and availability and to their increased use. NETL researchers have examined spent high-Cr2O3 (over 90 pct Cr2O3) refractories from numerous gasifiers to determine in-service failure mechanisms. This analysis revealed that premature failure of the high chrome oxide refractories was related to ash in the carbon feedstock, which liquefies during gasification and interacts with the refractories, leading to wear by chemical dissolution or spalling (structural and chemical). A discussion of this postmortem wear of spent refractory materials and of thermodynamic modeling used to explain microstructural changes leading to wear are explained in this article. This information will serve the basis to develop improved performance refractory materials.

  11. Study on Microstructure and Slag Corrosion Mechanism of High Chrome Bricks for Gasifier

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Research was focused on slag corrosion mechanism of high chrome bricks used for different types of gasifier by comparing the structure of high chrome bricks for petroleum coke gasifier and water-coal slurry gasifier with slag corroded testing brick and water coal slurry gasifier through Scanning Electron Microscope (SEM) examination and X-ray diffraction. Results show that for high chrome brick used for petroleum coke gasifier, corrosion is mainly caused by Cr2O3 in the brick and V2O5 in molten slag and liquid phase generation at low temperature; for high chrome brick used for water-coal slurry gasifier, corrosion is caused by dissolution of Cr2O3 in molten slag and corrosion of ZrO2. For LIRR-HK95 brick, it performs better petroleum coke corrosion resistance than the others due to the optimal composition and structure.

  12. Magnetic microphases in chrome-spinels from alpine-type ultramafic rocks, Central Urals

    Science.gov (United States)

    Sherendo, T. A.; Mitrofanov, V. Ya.; Martyshko, P. S.; Vazhenin, V. A.; Pamyatnykh, L. A.; Alekseev, A. V.

    2014-05-01

    The ore and accessory chrome-spinels from metamorphosed dunites of the Cr-bearing Klyuchevskoi alpine-type ultramafic massif are studied. As a result of use of thermomagnetic analysis in the range of 4-900 K, magnetic resonance spectroscopy, and magnetic-force microscopy, secondary magnetic Fe3+-enriched microphases chaotically distributed in the primary nonmagnetic mineral were revealed for the first time in accessory chrome-spinels. It was established that the metamorphosed accessory chrome-spinels produce the magnetic properties of the host rocks and the primary nonmagnetic chrome-spinels forming ore bodies remains almost unaltered. This originates the contrast of magnetic properties between the ore body and host rocks and provides the geomagnetic anomaly in the ore-hosting zone.

  13. The elements sorption of chrome sub-group with iron hydroxide (III)

    International Nuclear Information System (INIS)

    For the conditions determination of elements apportionment and concentration of chrome sub-group was investigated their sorption with iron hydroxide (III) in dependence from ph solution and from concentration of those metals

  14. Application of Nuclear methods in the chrome bed prospecting from Casimba sector, Pinares de Mayari

    International Nuclear Information System (INIS)

    A study for chrome determination in Casimba sector, Pinares de Mayari, was carried out using nuclear geophysical methods: and spectrometry neutron-gamma capture. For this purpose Cs 137 and Am-Be sources were used

  15. The (Un)Reliability of NVD Vulnerable Versions Data: an Empirical Experiment on Google Chrome Vulnerabilities

    OpenAIRE

    Nguyen, Viet Hung; Massacci, Fabio

    2013-01-01

    NVD is one of the most popular databases used by researchers to conduct empirical research on data sets of vulnerabilities. Our recent analysis on Chrome vulnerability data reported by NVD has revealed an abnormally phenomenon in the data where almost vulnerabilities were originated from the first versions. This inspires our experiment to validate the reliability of the NVD vulnerable version data. In this experiment, we verify for each version of Chrome that NVD claims vulnerable is actually...

  16. Syndeformation Chrome Spinels Inclusions in the Plastically Deformed Olivine Aggregates (Kraka Ophiolites, the Southern Urals

    Directory of Open Access Journals (Sweden)

    D. E. Saveliev

    2015-12-01

    Full Text Available This article presents the results of structural, petrographic, mineralogical and chemical studies of dunite veinlets in spinel peridotite from the Kraka ophiolites. It is demonstrated that plastic deformation of polycrystalline olivine, which form dunite, was accompanied by precipitation of impurities (aluminum and chrome as newly formed chrome spinels. The thinnest acicular inclusions of 0.3-0.5 micron thick are aligned in olivine grains along [010] axis. Bigger elongated irregular chrome spinel grains usually occur along grain and sub-grain olivine boundaries, and, occasionally, inside the grains along [100] axis. Alteration from the fine xenomorphic grains of chrome spinels to the bigger idiomorphic crystals was observed. Analogically to dynamic ageing (dispersion hardening in metals, the structural and chemical alterations in dunites are interpreted as deformation induced segregation of impurities. It is suggested that the euhedral chrome spinel grains typical for ophiolitic dunites were formed by coalescence and spheroidization. This process may be a key factor in the formation of ophiolitic chrome ore deposits.

  17. Nondestructive detection of lead chrome green in tea by Raman spectroscopy.

    Science.gov (United States)

    Li, Xiao-Li; Sun, Chan-Jun; Luo, Liu-Bin; He, Yong

    2015-01-01

    Raman spectroscopy was first adopted for rapid detecting a hazardous substance of lead chrome green in tea, which was illegally added to tea to disguise as high-quality. 160 samples of tea infusion with different concentrations of lead chrome green were prepared for Raman spectra acquirement in the range of 2804 cm(-1)-230 cm(-1) and the spectral intensities were calibrated with relative intensity standards. Then wavelet transformation (WT) was adopted to extract information in different time and frequency domains from Raman spectra, and the low-frequency approximation signal (ca4) was proved as the most important information for establishment of lead chrome green measurement model, and the corresponding partial least squares (PLS) regression model obtained good performance in prediction with Rp and RMSEP of 0.936 and 0.803, respectively. To further explore the important wavenumbers closely related to lead chrome green, successive projections algorithm (SPA) was proposed. Finally, 8 characteristic wavenumbers closely related to lead chrome green were obtained and a more convenient and fast model was also developed. These results proved the feasibility of Raman spectroscopy for nondestructive detection of lead chrome green in tea quality control. PMID:26508516

  18. High exhaust chrome complex using chrome tanned tannery, solid wastes and common hydrocarbons as reductants and masking agents to minimize the liquid and solid wastes: tanning and environmental impact studies

    International Nuclear Information System (INIS)

    Still no alternate of chrome tanning has been found to achieve the best quality and quantity of leather. But the chrome tanning process is associated with the generation of very toxic liquid and solid wastes. Therefore we emphasized to develop an efficient process for the synthesis of high exhaust chrome complex that could minimize the both liquid and solid wastes up to very low limit. In this research, chrome shavings and raw organic compounds have beneficially utilized as a reductant as well as potential masking agents providing a comprehensive close loop. Two chrome tanning materials have been developed using leather shavings with molasses in product A and replacement of molasses by other organic compounds for chrome complex B. These materials have also been employed for the tanning of goatskins parallel to the commercial BCS from the market. The comparative studies revealed that, the quality of leather made from product B is either better or comparable with the conventional tanning material. The chrome contents in leather have been increased with the simultaneous decreased in spent chrome liquor. Hence the exhaustion rate of chrome complex B has been noted up to 95%. While the physical characteristics of resulted leather from product A and B have been found comparable to that of conventional tanned leather. Therefore this methodology would not only reduce liquid and solid wastes but also provide quality leather and economically multi benefits. (author)

  19. Study of skin and mucous membrane disorders among workers engaged in the sodium dichromate manufacturing industry and chrome plating industry

    OpenAIRE

    Vijay Kumar Singhal; Balbir Singh Deswal; Bachu Narayan Singh

    2015-01-01

    Background: Inhalation of dusts and fumes arising during the manufacture of sodium dichromate from chrome ore, chromic acid mist emitted during electroplating, and skin contact with chromate produce hazards to workers. Objectives:(1) To elucidate the prevalence of skin and mucous membrane disorders among the workers engaged in the sodium dichromate manufacturing industry and chrome plating industry. (2) To know the relationship of prevalence with the duration of exposure to chrome mist, dust,...

  20. Characterisation of chrome-spinel grains in ilmenite concentrates using combined EPMA imaging and analysis methods

    International Nuclear Information System (INIS)

    Full text: The production of clean ilmenite concentrates from some mineral sands deposits is hampered by the presence of chromium-containing minerals. The majority of the chromium occurs in separate chrome-spinel grains, so in principal they can be separated from ilmenite grains by physical concentration procedures. However, in practice, the separation is difficult because the physical properties of the chrome-spinel grains, such as specific gravity, conductivity and magnetic susceptibility, are similar to those of ilmenite grains. The situation is further complicated by a) the chrome-spinels have a relatively wide range of compositions due to varying amounts of Mg, Al, Fe and Cr in solid solution, and, b) chemical weathering of both the ilmenite and chrome spinels in the deposits, which involves oxidation and leaching of iron. Both these factors modify the composition ranges of the minerals and influence their subsequent separation characteristics. In mineral sands deposits in which the chrome-spinel population falls into chemically and magnetically 'tight' populations, effective separation treatments have been developed. These usually involve roasting under various conditions to increase the magnetic susceptibility of Fe2O3-FeTiO3 solid solutions, enabling the removal of chromium-bearing spinel from ilmenite concentrates through magnetic separation. In areas such as the Murray Basin region of Eastern Australia however, previous characterisation testwork by CSIRO Minerals have demonstrated that the chrome-spinel populations are highly variable often exhibiting a broad range of composition. Individual chrome-spinel grain types can span the entire compositional spectrum from close to ideal chromite (FeCr2O4) to almost pure MgAl2O4. The effect of various roasting regimes on the magnetic separation characteristics of these complex spinels is largely unknown. In this paper we describe the application of EPMA imaging techniques developed at CSIRO Minerals to quantify

  1. SUPERFUND TREATABILITY CLEARINGHOUSE: SOIL STABILIZATION PILOT STUDY, UNITED CHROME NPL SITE PILOT STUDY AND HEALTH AND SAFETY PROGRAM, UNITED CHROME NPL SITE PILOT STUDY

    Science.gov (United States)

    This document is a project plan for a pilot study at the United Chrome NPL site, Corvallis, Oregon and includes the health and safety and quality assurance/quality control plans. The plan reports results of a bench-scale study of the treatment process as iieasured by the ...

  2. Recycling of Chrome Tanned Leather Dust in Acrylonitrile Butadiene Rubber

    Science.gov (United States)

    El-Sabbagh, Salwa H.; Mohamed, Ola A.

    2010-06-01

    Concerns on environmental waste problem caused by chrome tanned leather wastes in huge amount have caused an increasing interest in developing this wastes in many composite formation. This leather dust was used as filler in acrylonitrile butadiene rubber (NBR) before treatment and after treatment with ammonia solution and sod. formate. Different formulations of NBR/ leather dust (untreated-treated with ammonia solution—treated with sod. formate) composites are prepared. The formed composite exhibit a considerable improvement in some of their properties such as rheometric characteristics especially with composites loaded with treated leather dust. Tensile strength, modulus at 100% elongation, hardness and youngs modulus were improved then by further loading start to be steady or decrease. Cross linking density in toluene were increased by incorporation of leather dust treated or untreated resulting in decreases in equilibrium swelling. Distinct increase in the ageing coefficient of both treated and untreated leather with drop in NBR vulcanizates without leather dust. Addition of leather dust treated or untreated exhibit better thermal stability.

  3. Crystal Violet Assay for Determining Viability of Cultured Cells.

    Science.gov (United States)

    Feoktistova, Maria; Geserick, Peter; Leverkus, Martin

    2016-01-01

    Adherent cells detach from cell culture plates during cell death. This characteristic can be used for the indirect quantification of cell death and to determine differences in proliferation upon stimulation with death-inducing agents. One simple method to detect maintained adherence of cells is the staining of attached cells with crystal violet dye, which binds to proteins and DNA. Cells that undergo cell death lose their adherence and are subsequently lost from the population of cells, reducing the amount of crystal violet staining in a culture. This protocol describes a quick and reliable screening method that is suitable for the examination of the impact of chemotherapeutics or other compounds on cell survival and growth inhibition. However, characterization of the cause of reduced crystal violet staining requires additional methods detailed elsewhere. PMID:27037069

  4. Hexavalent Chrome Free Coatings for Electronics: Electromagnetic Interference (EMI) Shielding Effectiveness (SE)

    Science.gov (United States)

    Kessel, Kurt R.

    2016-01-01

    Determine the suitability of trivalent chromium conversion coatings that meet the requirements of MIL-DTL-5541, Type II, for use in applications where high-frequency electrical performance is important. Evaluate the ability of hexavalent chrome free pretreated aluminum to form adequate EMI seals, and maintain that seal while being subjected to harsh environmental conditions. Assess the performance of trivalent chromium pretreatments against a known control hexavalent chrome pretreatment before and after they have been exposed to a set of environmental conditions. It is known that environmental testing causes a decrease in shielding effectiveness when hexavalent chrome pretreatments are used (Alodine 1200s). Need to determine how shielding effectiveness will be affected with the use of hexavalent chrome free pretreatments. Performance will be assessed by evaluating shielding effectiveness (SE) test data from a variety of test samples comprised of different aluminum types and/or conversion coatings. The formation of corrosion will be evaluated between the mating surfaces and gasket to assess the corrosion resistant properties of the pretreatments, comparing the hexavalent control to the hexavalent chrome free pretreatments.

  5. Inline detection of Chrome degradation on binary 193nm photomasks

    Science.gov (United States)

    Dufaye, Félix; Sippel, Astrid; Wylie, Mark; García-Berríos, Edgardo; Crawford, Charles; Hess, Carl; Sartelli, Luca; Pogliani, Carlo; Miyashita, Hiroyuki; Gough, Stuart; Sundermann, Frank; Brochard, Christophe

    2013-09-01

    193nm binary photomasks are still used in the semiconductor industry for the lithography of some critical layers for the nodes 90nm and 65nm, with high volumes and over long periods. However, these 193nm binary photomasks can be impacted by a phenomenon of chrome oxidation leading to critical dimensions uniformity (CDU) degradation with a pronounced radial signature. If not detected early enough, this CDU degradation may cause defectivity issues and lower yield on wafers. Fortunately, a standard cleaning and repellicle service at the mask shop has been demonstrated as efficient to remove the grown materials and get the photomask CD back on target.Some detection methods have been already described in literature, such as wafer CD intrafield monitoring (ACLV), giving reliable results but also consuming additional SEM time with less precision than direct photomask measurement. In this paper, we propose another approach, by monitoring the CDU directly on the photomask, concurrently with defect inspection for regular requalification to production for wafer fabs. For this study, we focused on a Metal layer in a 90nm technology node. Wafers have been exposed with production conditions and then measured by SEM-CD. Afterwards, this photomask has been measured with a SEM-CD in mask shop and also inspected on a KLA-Tencor X5.2 inspection system, with pixels 125 and 90nm, to evaluate the Intensity based Critical Dimension Uniformity (iCDU) option. iCDU was firstly developed to provide feed-forward CDU maps for scanner intrafield corrections, from arrayed dense structures on memory photomasks. Due to layout complexity and differing feature types, CDU monitoring on logic photomasks used to pose unique challenges.The selection of suitable feature types for CDU monitoring on logic photomasks is no longer an issue, since the transmitted intensity map gives all the needed information, as shown in this paper. In this study, the photomask was heavily degraded after more than 18,000 300

  6. Photo-oxidation. Of the system chrome hexavalent-4-chlorophenol

    International Nuclear Information System (INIS)

    As a proposal to eliminate highly toxic chemical components derived from industrial waste, the researchers study the behavior of the compound hexavalent chromium / 4-chlorophenol system when subjected to photo degradation in a photo-reactor compound parabolic cylinder (CPC) to scale pilot. The effect is analyzed in order to determine the operation conditions to reach the highest degradation levels possible. The analyzed variables were pH, concentration of catalyst (TiO2), time of recirculation and the relation of initial concentrations among polluting agents. The factor that most influences the levels of removal reached is the pH, which has a different effect for each of the pollutants. This implies that, theoretically, you cannot adopt a unique group of operation parameters to favor the degradation of both however, in the practice; high levels of degradation of both pollutants are obtained in the optimal point of operation of the chrome. It is also observed that the catalyst concentration does not influence the degradation of the polluting agents significantly, at least for the initial concentrations studied. The recirculation time is closely related to the kinetics of degradation of each polluting agent. Elevated degradation levels are reached in a short time for 4-chlorophenol, while more prolonged recirculation times are required for hexavalent chromium. The relation of initial concentrations of the polluting agents also exerts an opposite effect on the degradation levels reached for each polluting agent; the hexavalent chromium reduction is favored with high initial concentrations of 4-chlorophenol, whereas the oxidation of 4-chlorophenol is favored with high initial hexavalent chromium concentrations, which suggests some synergy between the oxidation-reduction reactions of 4-chlorophenol and hexavalent chromium. Finally, a 97% hexavalent chromium reduction and a 94.9% oxidation of 4-chlorophenol were obtained

  7. Development of technology of complex aluminum-silicon-chrome alloy with utilization of off grade raw materials

    OpenAIRE

    A. Mekhtiev; Ye. Shabanov; А. Issagulov; S. Baissanov; А. Baissanov; D. Issagulova

    2015-01-01

    Experimental studies on obtaining a complex aluminum-silicon-chrome alloy (FASCh) from Karaganda high-ash coals and high-carbon ferrochromefines were carried out. A method for smelting low-carbon ferrochrome using aluminum-silicon-chrome alloy as a reductant is suggested.

  8. 40 CFR 425.20 - Applicability; description of the hair save, chrome tan, retan-wet finish subcategory.

    Science.gov (United States)

    2010-07-01

    ... save, chrome tan, retan-wet finish subcategory. 425.20 Section 425.20 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS LEATHER TANNING AND FINISHING POINT SOURCE CATEGORY Hair Save, Chrome Tan, Retan-Wet Finish Subcategory § 425.20...

  9. 40 CFR 425.10 - Applicability; description of the hair pulp, chrome tan, retan-wet finishing subcategory.

    Science.gov (United States)

    2010-07-01

    ... pulp, chrome tan, retan-wet finishing subcategory. 425.10 Section 425.10 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) EFFLUENT GUIDELINES AND STANDARDS LEATHER TANNING AND FINISHING POINT SOURCE CATEGORY Hair Pulp, Chrome Tan, Retan-Wet Finish Subcategory § 425.10...

  10. Preliminary Results on the Use of Leather Chrome Shavings for Air Passive Sampling

    Directory of Open Access Journals (Sweden)

    D. Sanjuán-Herráez

    2012-01-01

    Full Text Available A new passive sampler based on low-density polyethylene (LDPE layflat tube filled with chrome shavings from tannery waste residues was evaluated to determine volatile organic compounds (VOCs in indoor and outdoor areas. VOCs were directly determined by head space-gas chromatography-mass spectrometry (HS-GC-MS without any pretreatment of the sampler and avoiding the use of solvents. Limit of detection values ranging from 20 to 75 ng sampler−1 and good repeatability values were obtained for VOCs under study with relative standard deviation values from 2.8 to 9.6% except for carbon disulfide for which it was 22.5%. The effect of the amount of chrome shavings per sampler was studied and results were compared with those obtained using empty LDPE tubes, to demonstrate the capacity of chrome shavings to adsorb VOCs.

  11. Improvement of uptake of chrome tan on hide protein by basic oxides

    International Nuclear Information System (INIS)

    Three basic oxides were used to improve uptake of chrome tan as well as shrinkage temperature of the tanned leather. In addition, the skin quality is one of the most important factors taking into consideration. Three basic oxides, named magnesium oxide, manganese oxide and sodium bicarbonate. The process was optimized taking into the account the shaking rate, chrome concentration (%), initial ph, basic oxides concentration, temperature and contact time. The optimum conditions for exhaustion, fixation, shrinkage temperature as well as skin quality showed that agitation rate of 150 rpm, chrome concentration of 16%, initial ph of 2.5, basic oxide concentration of 4% magnesium oxide, temperature of 35 degree C and contact time of 24 hr. The best results obtained are 88% exhaustion, 90.03% fixation and 109 degree C shrinkage temperature in aqueous medium

  12. Fatigue and deformation of HVOF sprayed WC-Co coatings and hard chrome plating

    International Nuclear Information System (INIS)

    A challenge facing the finishing industry is to replace chrome plating since this technology has negative environmental and health effects. In the case of tungsten carbide and chrome carbide coatings, HVOF and detonation spray technologies have proven to be cleaner and more effective. In this paper, the results of a comparative investigation involve a detailed analysis of fatigue and deformation of two groups of AISI 4340 steel specimens. One group sprayed with HVOF WC-Co coating and the other group was plated with hard chrome. Rotating beam fatigue tests were performed on the coated and uncoated specimens. Optical and SEM microscopy were used to evaluate the fracture morphology. The fatigue life distributions of coated AISI 4340 steel specimens demonstrated that the HVOF coated specimens exhibited higher fatigue lives compared to the uncoated specimens

  13. CHROME MINING COMPETITIVENESS ANALYSIS OF TURKEY IN TERMS OF STRATEGIC MANAGEMENT: SECTORAL STRENGTHS, PROBLEMS AND SOLUTIONS

    Directory of Open Access Journals (Sweden)

    Ali Rıza İNCE

    2012-12-01

    Full Text Available In this study, Chrome mining which has an important place in the Turkish mining industry, analyzed and determined features that can provide a competitive advantage, and also aimed to identifing the existing problems.İn this study qualititive study has done.İn this context, literatüre review was done and descriptive method is used.The first section reviews recent discussions about strategic management approach and its features. The second section includes competetion and competitiveness.İn the context, swot analysis technique, the most preferred method, was utilized for assesing the competetion.And then, swot analysis is done chrome mining lastly, strategic evaluation is done in the context of assesments and analysis for chrome mining and various suppestions have been made about the strategic sense.

  14. Fatigue and deformation of HVOF sprayed WC-Co coatings and hard chrome plating

    Energy Technology Data Exchange (ETDEWEB)

    Ibrahim, A. [State University of New York at Farmingdale, Farmingdale, Route 110, Lupton Hall, Room 182, Farmingdale, NY 11735 (United States)], E-mail: ahmed.ibrahim@farmingdale.edu; Berndt, C.C. [James Cook University, School of Engineering, Townsville, Qld 4811 (Australia)

    2007-05-15

    A challenge facing the finishing industry is to replace chrome plating since this technology has negative environmental and health effects. In the case of tungsten carbide and chrome carbide coatings, HVOF and detonation spray technologies have proven to be cleaner and more effective. In this paper, the results of a comparative investigation involve a detailed analysis of fatigue and deformation of two groups of AISI 4340 steel specimens. One group sprayed with HVOF WC-Co coating and the other group was plated with hard chrome. Rotating beam fatigue tests were performed on the coated and uncoated specimens. Optical and SEM microscopy were used to evaluate the fracture morphology. The fatigue life distributions of coated AISI 4340 steel specimens demonstrated that the HVOF coated specimens exhibited higher fatigue lives compared to the uncoated specimens.

  15. 40 CFR 425.30 - Applicability; description of the hair save or pulp, non-chrome tan, retan-wet finish subcategory.

    Science.gov (United States)

    2010-07-01

    ... save or pulp, non-chrome tan, retan-wet finish subcategory. 425.30 Section 425.30 Protection of... FINISHING POINT SOURCE CATEGORY Hair Save or Pulp, Non-Chrome Tan, Retan-Wet Finish Subcategory § 425.30 Applicability; description of the hair save or pulp, non-chrome tan, retan-wet finish subcategory....

  16. Study of skin and mucous membrane disorders among workers engaged in the sodium dichromate manufacturing industry and chrome plating industry

    Directory of Open Access Journals (Sweden)

    Vijay Kumar Singhal

    2015-01-01

    . All workers were washing hands with soap in both the processes. 48.48% and 90.52% of the workers were using hand gloves in the sodium dichromate manufacturing and chrome plating industry, respectively. Only 27.27% and 37.50% of the workers were using masks in the sodium dichromate manufacturing industry and chrome plating industry, respectively. No worker was using protective clothing or barrier cream in the sodium dichromate manufacturing industry. 40.65% and 12.50% workers were using protective clothing and barrier cream in the chrome plating industry. Conclusion: Workers engaged in sodium dichromate manufacturing and chrome plating are at a great risk of skin and mucous membrane disorders including chrome holes and nasal septum perforation. Protective measures and awareness of the management and workers about the exposure hazards and safeguarding against them will be useful public measures to prevent these occupational hazards among workers engaged in these processes.

  17. MERCURY, LEAD, CADMIUM AND CHROME CONCENTRATION LEVELS IN FISH FOR PUBLIC CONSUMPTION

    OpenAIRE

    Imer Haziri; Muhamed Zogaj; Fatgzim Latifi; Jetmira Abeshi; Dorjana Beqiraj; Luljeta Dhaskali; Enkelejda Ozuni

    2011-01-01

    A total of seventy cultured fish from the local market of Tirana were sampled and the concentration level of mercury, lead, cadmium and chrome was evaluated. Their concentration always resulted below the maximum permitted level for human consumption set by EC (Hg- 1.0 mg/kg, Pb – 0.30 mg/kg, Cd – 0.05 mg/kg and Cr -8 mg/kg). Heavy metal concentration varied among the muscle tissue of different fish species. The concentration level of mercury, lead, cadmium and chrome ranged between 0.002-0.21...

  18. Application of molecular simulation to investigate chrome(III)-crosslinked collagen problems

    International Nuclear Information System (INIS)

    Molecular dynamics simulation with a modified CHARMM (Chemistry at Harvard Macromolecular Mechanics) force field was carried out to investigate the properties of chrome-tanned collagen in comparison with chrome-free collagen under hydrated and dehydrated conditions. An attempt has been made to explain the microcosmic origins of the various properties of the chromium(III)-crosslinked collagen. The present simulation describes the clear crosslinking topology of polychromiums to peptide chains, identifies the linking site and the capacity of the linkage, explains why the efficiency is not 100% in a practical tanning process and provides a new viewpoint on the crosslinking of the polychromium with the side chains of the collagen. (paper)

  19. Optimization of two-low salt chrome tanning processes without float

    OpenAIRE

    Morera Prat, Josep Maria; Bacardit Dalmases, Anna; Ollé Otero, Lluís; Costa, Jose; Banaszak, S.

    2007-01-01

    The aim of this study was to develop at pilot plant level two systems of pickle-tanning that would reduce both the amount of waste water and its content in chrome and chlorides while obtaining leathers that are commercially acceptable. In the first one, the effect of the variation of the final tanning temperature as well as the system of adding the basificant in the formulation of a chrome tanning without float were studied. A 87 percent reduction of the residual float was obtained with this ...

  20. Research Status of Chrome-free Tanning%铬鞣剂的研究现状

    Institute of Scientific and Technical Information of China (English)

    陶亮亮; 李鹏; 侯宏波; 李宁宁; 陈磊; 李琛

    2011-01-01

    介绍了无铬金属鞣剂、植物鞣剂、改性戊二醛鞣剂、嗯唑烷鞣剂、有机膦鞣剂、纳米鞣剂等无铬鞣剂的研究现状和应用前景。%The chrome-free tanning agents, such as inorganic compounds tanning agent, vegetable tanning agent, modified glutaraldehyde tanning agent, oxzaolidine tanning agent, organic phosphonium tanning agents and nano-tanning agents, were introduced in this paper. And, the current research and application prospect of chrome-free tanning agent were discussed.

  1. Non-destructive evaluation for high chrome Fe-based steels by using a magnetic sensor

    International Nuclear Information System (INIS)

    This paper presents a non-destructive evaluation for high chrome Fe-based steels by using a magnetic sensor. In order to make clear the fundamental magnetic properties related to tensile strain damage and fatigue damage, the magnetic measurement apparatus, which can measure the magnetic flux density and the magnetic field strength by B-coil and H-coil, was developed. And then the relationships between the damages and the measured magnetic properties are shown to discuss the capability of a non-destructive testing for high chrome Fe-based steels. (author)

  2. Nondestructive detection of lead chrome green in tea by Raman spectroscopy

    OpenAIRE

    Xiao-Li Li; Chan-Jun Sun; Liu-Bin Luo; Yong He

    2015-01-01

    Raman spectroscopy was first adopted for rapid detecting a hazardous substance of lead chrome green in tea, which was illegally added to tea to disguise as high-quality. 160 samples of tea infusion with different concentrations of lead chrome green were prepared for Raman spectra acquirement in the range of 2804 cm−1–230 cm−1 and the spectral intensities were calibrated with relative intensity standards. Then wavelet transformation (WT) was adopted to extract information in different time and...

  3. Spectrophotometric determination of beryllium in air by a sensitised chrome azurol S reaction

    International Nuclear Information System (INIS)

    Although many spectrophotometric reagents for beryllium are known, their sensitivities do not approach that provided by the fluorimetric method using morin. A spectrophotometric method of comparable sensitivity is reported wherein addition of cetylpyridinium bromide considerably enhances the colour intensity of the beryllium - Chrome Azurol S complex. EDTA serves as a suitable masking agent for eliminating interferences from commonly associated ions. The results obtained are compared with those obtained with the morin method. Similar sensitisation of the beryllium - Chrome Azurol S system by polyoxyethylene dodecylamine and poly(vinyl alcohol) has been reported. (author)

  4. Desenvolupament d'un plugin per a Chrome per xifrar/desxifrar correus utilitzant Gmail

    OpenAIRE

    Martín Toral, Boris

    2016-01-01

    L'objecte del treball final de carrera és desenvolupar un plugin o extensió per a Chrome per a poder xifrar/desxifrar missatges utilitzant el correu web de Gmail. S'adjunta memòria, presentació virtual i codi font de l'extensió desenvolupada.

  5. CHROME: An Approach to Teaching the Concept of Inter-Functional Cooperation in Services Organizations

    Science.gov (United States)

    Johnson, Lester W.

    2010-01-01

    When teaching a services course (e.g., Services Marketing) it is essential that students understand that marketing/management, operations and human resource management within the service organization be fully coordinated. One useful acronym used to remind students of this need is "CHROME", standing for Communications, Human Resources,…

  6. Selection of the Chrome Reduction Bacteria in the Waste of Tanning Leather Industries by Ozonization Method

    International Nuclear Information System (INIS)

    Selection of the chrome reduction bacteria in the waste of tanning leather industries by ozonization method has been done. The objectives of this research was to obtain isolate bacteria from the waste with chrome contain, so that expected can be used for chrome bioremediation agent for arrange to improved the waste treatment for tanning leather industries. Selection of bacteria in the waste was carried out by ozonization method with time variation 0 to 210 minutes by time interval 15 minutes. Isolation bacteria was carried out was grown on the BHI media for 24 hours at 37°C temperature. So be inoculated by streak plate method on the TBX, MC, EA, CTM and BP media. Characterization of bacteria was done by saw the colonies morphology, sel morphology and biochemical characterization. So, identification of isolate bacteria by matching profile method. The result of this research can be obtained 5 isolate bacteria BCR1, BCR2, BCR3, BCR4 and BCR5 with the different phenotypic character. From the five isolate can be selected resistance ozon isolate until 180 minutes time ozonization were BCR 2, were identified belong to the genus of Bacillus. The examination results showed that the isolate bacteria be able to reduction of the chrome concentration in the waste of tanning leather industries by 71.03 %. Efficiency. (author)

  7. Study on creep-fatigue evaluation of chrome-molybdenum steel

    International Nuclear Information System (INIS)

    Though chrome-molybdenum steel has quite different basic material properties from austenitic stainless steel, the life fraction rule based on an advanced ductility exhaustion theory proposed for SUS304 is able to give proper prediction for creep-fatigue life of chrome-molybdenum steel. The applicability of the present evaluation method to chrome-molybdenum steel is validated by both mechanical study and micro-structural observation. The mechanism of creep-fatigue failure of Mod.9Cr-1Mo(NT) is one of the most controversial subjects among researchers. However, it is clarified in this report that creep-fatigue damage of this material under actual loading conditions is dominated by creep-cavitation of grain boundaries as same way as that of austenitic stainless steel. Furthermore, for the life reduction of low cycle fatigue of chrome-molybdenum steel with compression-side strain hold, both effects of mean stress and oxide-wedge are denied and it is insisted that the acceleration of fatigue-crack propagation is occurred by oxide-progress location and its thickness. (author)

  8. Spectrophotometric study of the reaction of zirconium with chrome Azurol S and fluoride

    International Nuclear Information System (INIS)

    A relatively simple and convenient procedure for the determination of small amounts of fluoride has been established. It is based on the decrease in absorbance when fluoride is added to a solution of the zirconium-Chrome Azurol S complex. Microgram amounts of fluoride can be determined with an error of better than about 2%. Some practical applications are presented. (author)

  9. Different degradation behaviors of InGaN/GaN MQWs blue and violet LEDs

    International Nuclear Information System (INIS)

    InGaN/GaN multiple quantum wells (MQWs) blue and violet light-emitting diodes (LEDs) were stressed under the injection current density of 26.5 A/cm2 for about 400 h at room temperature. Degradation behaviors of blue and violet LEDs were compared. Two stages of degradation were identified in the blue and violet LEDs. At the initial stage, the violet LEDs degraded very fast, but the blue LEDs degraded relatively slow. At later stage, both blue and violet LEDs showed similar degradation rates. Analyses of the L-I and I-V characteristics revealed that the increase of effective nonradiative recombination centers in the active regions was responsible for both blue and violet LED degradations. Rapid degradation of violet LEDs at early stage resulted from dramatical increase of the effective nonradiative centers. More indium in the MQWs might be helpful for better reliability performance of blue LEDs.

  10. Photoporation and cell transfection using a violet diode laser

    Science.gov (United States)

    Paterson, L.; Agate, B.; Comrie, M.; Ferguson, R.; Lake, T. K.; Morris, J. E.; Carruthers, A. E.; Brown, C. T. A.; Sibbett, W.; Bryant, P. E.; Gunn-Moore, F.; Riches, A. C.; Dholakia, Kishan

    2005-01-01

    The introduction and subsequent expression of foreign DNA inside living mammalian cells (transfection) is achieved by photoporation with a violet diode laser. We direct a compact 405 nm laser diode source into an inverted optical microscope configuration and expose cells to 0.3 mW for 40 ms. The localized optical power density of ~1200 MW/m2 is six orders of magnitude lower than that used in femtosecond photoporation (~104 TW/m2). The beam perforates the cell plasma membrane to allow uptake of plasmid DNA containing an antibiotic resistant gene as well as the green fluorescent protein (GFP) gene. Successfully transfected cells then expand into clonal groups which are used to create stable cell lines. The use of the violet diode laser offers a new and simple poration technique compatible with standard microscopes and is the simplest method of laser-assisted cell poration reported to date.

  11. Removal of crystal violet from wastewater using micellar enhanced ultrafiltration

    International Nuclear Information System (INIS)

    Micellar enhanced ultrafiltration (MEUF) is a separation technique which can be used to remove metals ions or dissolved organics from water. In this study MEUF has been carried out to investigate the retention of crystal violet (CV) (molecular weight 407.98), a cationic dye, from aqueous stream. Regenerated cellulose membrane of molecular weight cut-off 10 kDa was used in a cross-flow ultrafiltration unit. Sodium dodecylsulfate (SDS) and NaCl were used as surfactant and electrolyte, respectively. The removal of CV and permeate flux were studied as a function of dye and surfactant concentrations, ionic strength and pH. The ultrafiltration experiments showed that anionic surfactant SDS allowed retention of crystal violet in the order of 99 pour cent in the whole range of dye and surfactant concentrations considered. High retention was also obtained at pH range from 2 to 12. Permeate flux decreases when surfactant concentration or ionic strength increases.

  12. RECHERCHE DES MECANISMES MICROSTRUCTURAUX QUI REGISSENT LES PROPRIETES MACROSCOPIQUES DE DEPOTS DE CHROME : INFLUENCE DES PARAMETRES D'ELABORATION

    OpenAIRE

    Durut, Frédéric

    1999-01-01

    DES REVETEMENTS SONT EFFECTUES A PARTIR D'UN BAIN DE CHROME HEXAVALENT STANDARD (250 G/L CRO 3, 2,5 G/L H 2SO 4) A DENSITE DE COURANT CONSTANTE (40 A/DM 2), LA TEMPERATURE DE CHROMAGE VARIANT ENTRE 25 ET 75\\C. LES DEPOTS DE CHROME SONT CARACTERISES D'UN POINT DE VUE MICROSTRUCTURAL, MORPHOLOGIQUE ET MECANIQUE. AU-DESSOUS DE 40\\C, LE CHROME SE DEPOSE PAR GERMINATION CONTINUE, LA STRUCTURE EST EQUIAXE NON TEXTUREE. AU-DESSUS DE 40\\C, DES NANOGRAINS SE DEVELOPPENT PAR CROISSANCE DE GERMES. C'EST...

  13. Ultra-violet Behavior of Bosonic Quantum Membranes

    OpenAIRE

    Kaku, Michio

    1999-01-01

    We treat the action for a bosonic membrane as a sigma model, and then compute quantum corrections by integrating out higher membrane modes. As in string theory, where the equations of motion of Einstein's theory emerges by setting $\\beta = 0$, we find that, with certain assumptions, we can recover the equations of motion for the background fields. Although the membrane theory is non-renormalizable on the world volume by power counting, the investigation of the ultra-violet behavior of membran...

  14. Substoichiometric radiochemical determination of molybdenum with crystal violet

    International Nuclear Information System (INIS)

    An isotopic dilution method for the determination of traces of molybdenum has been developed. The method consists of the complexation Mo(V)-SCN with substoichiometric quantities of crystal violet, and its subsequent extraction into chloroform. This procedure was successfully tested for the determination of molybdenum in the range of 0.5 to 20 μg. (author) 2 refs.; 2 figs.; 1 tab

  15. Bordetella bronchiseptica phase variation induced by crystal violet.

    OpenAIRE

    Ishikawa, H.; Isayama, Y

    1986-01-01

    A method for effective induction of phase variation in Bordetella bronchiseptica by treatment with crystal violet (CV) is presented. When grown in CV-broth, phase I cells dissociated into three serial phases. Appearance of variant cells was observed simultaneously with the beginning of cell multiplication. The maximum effect of CV was obtained at a concentration of 8 micrograms/ml, when the proportion of variants in the population reached 100%. The main factors which affected phase variation ...

  16. Kinetic analysis of crystal violet adsorption on to bottom ash

    OpenAIRE

    NIDHEESH, Puthiya Veetil; Gandhimathi, Rajan

    2012-01-01

    The adsorption behavior of crystal violet (CV) from aqueous solution onto bottom ash was investigated under various experimental conditions. The parameters studied included contact time, initial CV concentration, particle size, and ionic strength. The kinetic experimental data were analyzed by different models. The experimental adsorption data showed good correlation with the kinetic models and suggested a multimechanism sorption process. The adsorption mechanisms follow pseudo-sec...

  17. Crystal violet staining to quantity Candida adhesion to epithelial cells

    OpenAIRE

    Negri, M.; Gonçalves, Vera M.; Silva, Sónia Carina; Henriques, Mariana; Azeredo, Joana; Oliveira, Rosário

    2010-01-01

    In vitro studies of adhesion capability are essential to characterise the virulence of Candida species. However, the assessment of adhesion by traditional methods is timeconsuming. The aim of the present study is the development of a simple methodology using crystal violet staining to quantify in vitro adhesion of different Candida species to epithelial cells. The experiments are performed using Candida albicans (ATCC 90028), C. glabrata (ATCC 2001), C. parapsilosis (ATCC 22019) and C. tropic...

  18. Tests and calibration on ultra violet imaging telescope (UVIT)

    Science.gov (United States)

    Kumar, Amit; Ghosh, S. K.; Kamath, P. U.; Postma, Joe; Kathiravan, S.; Mahesh, P. K.; Nagbhushana, S.; Navalgund, K. H.; Rajkumar, N.; Rao, M. N.; Sarma, K. S.; Sriram, S.; Stalin, C. S.; Tandon, S. N.

    2012-09-01

    Ultra Violet Imaging Telescope on ASTROSAT Satellite mission is a suite of Far Ultra Violet (FUV; 130 - 180 nm), Near Ultra Violet (NUV; 200 - 300 nm) and Visible band (VIS; 320-550nm) imagers. ASTROSAT is a first multi wavelength mission of INDIA. UVIT will image the selected regions of the sky simultaneously in three channels & observe young stars, galaxies, bright UV Sources. FOV in each of the 3 channels is ~ 28 arc-minute. Targeted angular resolution in the resulting UV images is better than 1.8 arc-second (better than 2.0 arc-second for the visible channel). Two identical co-aligned telescopes (T1, T2) of Ritchey-Chretien configuration (Primary mirror of ~375 mm diameter) collect the celestial radiation and feed to the detector system via a selectable filter on a filter wheel mechanism; gratings are available in the filter wheels of FUV and NUV channels for slit-less low resolution spectroscopy. The detector system for each of the 3 channels is generically identical. One telescope images in the FUV channel, and other images in NUV and VIS channels. One time open-able mechanical cover on each telescope also works as Sun-shield after deployment. We will present the optical tests and calibrations done on the two telescopes. Results on vibrations test and thermo-vacuum tests on the engineering model will also be presented.

  19. Tests & Calibration on Ultra Violet Imaging Telescope (UVIT)

    CERN Document Server

    Kumar, Amit; Kamath, P U; Postma, Joe; Kathiravan, S; Mahesh, P K; S, Nagbhushana; Navalgund, K H; Rajkumar, N; Rao, M N; Sarma, K S; Sriram, S; Stalin, C S; Tandon, S N

    2012-01-01

    Ultra Violet Imaging Telescope on ASTROSAT Satellite mission is a suite of Far Ultra Violet (FUV; 130 to 180 nm), Near Ultra Violet (NUV; 200 to 300 nm) and Visible band (VIS; 320 to 550nm) imagers. ASTROSAT is a first multi wavelength mission of INDIA. UVIT will image the selected regions of the sky simultaneously in three channels & observe young stars, galaxies, bright UV Sources. FOV in each of the 3 channels is about 28 arc-minute. Targeted angular resolution in the resulting UV images is better than 1.8 arc-second (better than 2.0 arc-second for the visible channel). Two identical co-aligned telescopes (T1, T2) of Ritchey-Chretien configuration (Primary mirror of 375 mm diameter) collect the celestial radiation and feed to the detector system via a selectable filter on a filter wheel mechanism; gratings are available in the filter wheels of FUV and NUV channels for slit-less low resolution spectroscopy. The detector system for each of the 3 channels is generically identical. One telescope images in ...

  20. Violet and visual flux problems in red giant stars

    International Nuclear Information System (INIS)

    Red giant stars are sites of many astrophysically interesting processes and are important links to late stages of stellar evolution and the chemical history of the galaxy. Much of what is known about stars comes from their spectra, which are formed in the outer layers (atmospheres). Unfortunately the low temperatures in red giant atmospheres promote the formation of many molecules, and the resultant complexity of the spectra has slowed progress in obtaining good models of these objects and leaves many unanswered questions. Several of these problems are investigated. Spectra of red giants provide a natural classification according to composition: M stars are oxygen rich, C stars are carbon rich, while S stars are intermediate. One long standing problem with C stars has been the explanation of the severe lack of energy flux in the violet and near ultraviolet part of their spectrum, generally attributed to an unusual opacity. Results show that one source, SiC, is untenable, while the case for the other, C3, is severely weakened. Synthetic spectra from atmospheric models are compared to spectra of TX Psc, a C star, to show that the contribution of thousands of atomic lines are probably responsible for the violet and ultraviolet flux deficiency. The agreement between the synthetic spectra and observations is very good. K and M type stars also have a violet flux deficiency, though it is less severe than with carbon stars

  1. CASTING OF DETAILS OF WEAR-RESISTANT CHROME CAST IRONS FOR CHROMIC MILLS IN COMBINED MOLDS AND CHILLS

    Directory of Open Access Journals (Sweden)

    K. E. Baranovskij

    2009-01-01

    Full Text Available Relative wear resistance of chrome cast irons of eutectic composition is determined in laboratory and industry conditions. Complex alloyed eutectic cast iron with increased wear resistance and mechanical characteristics is developed.

  2. Study of the effect of temperature, relative humidity and UV radiation on chrome-tanned leather ageing

    OpenAIRE

    Bacardit Dalmases, Anna; Jorba, Montse; Font Vallès, Joaquim; Ollé Otero, Lluís

    2012-01-01

    Since leather is strongly affected by three main environmental parameters: temperature, relative humidity and UV radiation, this piece of research focuses on the effect that these three factors have on chrome-tanned leather ageing. Chrome tanned leathers were exposed to weathering effects in a climatic chamber in order to identify the most important variables affecting this weathering process and also to check for any possible interactions. Both a multilevel centralized factorial experimental...

  3. Adsorption of methyl violet from aqueous solutions by the biochars derived from crop residues.

    Science.gov (United States)

    Xu, Ren-kou; Xiao, Shuang-cheng; Yuan, Jin-hua; Zhao, An-zhen

    2011-11-01

    The adsorption of methyl violet by the biochars from crop residues was investigated with batch and leaching experiments--adsorption capacity varied with their feedstock in the following order: canola straw char>peanut straw char>soybean straw char>rice hull char. This order was generally consistent with the amount of negative charge of the biochars. Zeta potentials and Fourier transform infrared photoacoustic spectroscopy, combined with adsorption isotherms and effect of ionic strength, indicated that adsorption of methyl violet on biochars involved electrostatic attraction, specific interaction between the dye and carboxylate and phenolic hydroxyl groups on the biochars, and surface precipitation. Leaching experiments showed that 156 g of rice hull char almost completely removed methyl violet from 18.2 L of water containing 1.0 mmol/L of methyl violet. The biochars had high removal efficiency for methyl violet and could be effective adsorbents for removal of methyl violet from wastewater. PMID:21924897

  4. Characteristics of the chrome-tanned sheep leather treated by radiation-induced graft of BA

    International Nuclear Information System (INIS)

    The characteristics of the chrome-tanned sheep leather treated by radiation-induced graft of BA is presented. Using the method of radiation-induced graft of BA instead of the chrome-retanning, the leather has been obviously improved not only in the surface, such as the brightness, fullness, uniformity of the thickness but also in the physical characteristics such as retaining of tensile strength, decreasing of water absorption after being immersed in water for 2h, and 24h, enhancement of tearing strength and stitch tear strength. Although the air permeability and water vapor permeability are a bit worse than the control, however is still in the range of the standard issued by Light Industry Ministry of China

  5. Condensation locale de l'hydrogène dans le chrome

    OpenAIRE

    P. PERETTO; Teisseron, G.; Berthier, J.

    1983-01-01

    Des expériences de corrélation angulaire perturbées effectuées sur des noyaux de hafnium actifs dilués dans une matrice de chrome montrent que la sonde peut piéger plusieurs atomes d'hydrogène. Cet effet est expliqué par l'influence de l'impureté de hafnium qui transforme localement le caractère répulsif des interactions entre atomes d'hydrogène dissous dans le chrome en une interaction très attractive. L'amas d'hydrogène subit une transformation à la température T ≃ 550 K. La transition est ...

  6. Use of nuclear techniques in the characterization of chrome black solar absorber surfaces

    International Nuclear Information System (INIS)

    A set of electrodeposited chrome black solar absorbers has been subjected to ion beam analysis in an attempt to determine the concentration depth profiles of the major elemental constituents. Chromium distributions were obtained using the 52Cr(p,γ)53Mn nuclear reaction, which is resonant at E = 1005.2 keV. The possibility was investigated of inferring oxygen distributions from the γ-ray lineshapes (measured with a Ge(Li) detector) of the direct capture reaction 16O(p,γ)17F. Concentration profiles were also obtained for fluorine and sodium contaminants in some chrome blacks. Complete experimental details are given of the various nuclear techniques used. The results of these measurements are discussed in terms of the microscopic physical features of the selective surfaces and are related to the known photothermal properties of the surfaces

  7. Microstructure and properties of high chrome steel roller after laser surface melting

    International Nuclear Information System (INIS)

    Laser surface melting of high chrome steels was achieved by a 5 kW continuous wave CO2 laser. The microstructure of the laser surface-melted steels was investigated by scanning electron microscopy, transmission electron microscopy and X-ray diffractometry, and the hardness profiles were determined by a Vickers hardness tester. The corrosion behavior in 3.5% NaCl solution was studied by electrochemical corrosion equipment. The large carbides of high chrome steels are completely dissolved and ultrafine dendrites of austenite with submicroscopic M23C6 carbides precipitation are formed in the melted zone. The austenite in the melted zone has a high tempering stability. The corrosion resistance of the laser surface-melted steels is significantly improved due to the dissolution of carbides and the increase of the alloying elements in the solid solution as well as the large amount of austenite.

  8. Penetration and dissolution of refractory of magnetite - chrome by fayalite slag

    International Nuclear Information System (INIS)

    Magnesium-chrome refractory have been used with success at high temperatures in different metallurgist processes, such as iron and steel, cement industry and non ferrous pyro metallurgist processes. In particular in the smelting, in the processes of reforming of raffinate of copper. Those materials have good characteristics in relation with the use and the requirements of heat shock resistance. However, they represent an important problem for the environment. The aim of this research was to investigate the interactions between the slag generated in the converter Peirce-Smith in copper and Magnesium-chrome refractory bricks. The infiltration events and chemical attacks in the refractory material caused by the slag formed during the copper conversion process have been studied by means of the development of the different laboratory tests at temperatures of until 1300 celsius degrade.

  9. NASA and ESA Collaboration on Hexavalent Chrome Alternatives: Pretreatments Only Final Test Report

    Science.gov (United States)

    Kessel, Kurt R.

    2015-01-01

    Hexavalent chromium (hex chrome or CR(VI)) is a widely used element within applied coating systems because of its self-healing and corrosion-resistant properties. The replacement of hex chrome in the processing of aluminum for aviation and aerospace applications remains a goal of great significance. Aluminum is the major manufacturing material of structures and components in the space flight arena. The National Aeronautics and Space Administration (NASA) and the European Space Agency (ESA) are engaged in a collaborative effort to test and evaluate alternatives to hexavalent chromium containing corrosion coating systems. NASA and ESA share common risks related to material obsolescence associated with hexavalent chromium used in corrosion-resistant coatings.

  10. Study of the weathering variables on chrome-tanned leather ageing

    OpenAIRE

    Bacardit Dalmases, Anna; Jorba, Montse; Castell, Joan Carles; Font Vallès, Joaquim; Ollé Otero, Lluís

    2011-01-01

    Since upholstery leather is considered a very high-tech product, a long service life is expected by the costumer. However, this type of leather can undergo extreme environmental conditions that may cause premature ageing. This work deals with the study of the effect of temperature, relative humidity, and UV radiation on leather ageing. Leathers with chrome tannage were exposed to weathering effects using a climatic chamber in order to identify the most important variables affecting this we...

  11. Quantitative chemical microdetermination of beryllium with chrome azurol by the ring-oven technique

    International Nuclear Information System (INIS)

    A method for determination of beryllium in minerals and rocks is described. Because of the toxicity of beryllium the method is designed for determination of 1-10 ng of Be. The sample is fused with sodium carbonate and sodium tetraborate. Interfering metals are masked with EDTA. Be is determined by the Weisz ring-oven method with Chrome Azurol. The relative error is 10%. (Author)

  12. Analytical properties of gaize- and silicate glue-based xerogels modified with Chrome Azurol S

    International Nuclear Information System (INIS)

    A method was proposed for the synthesis of silicic acid xerogels based on opoka aluminosilicate (Gaize) and silicate glue. The physicochemical properties of xerogels were studied. The complexation of Be(II) with immobilized Chrome Azurol S was studied by electronic absorption and diffuse-reflection spectrometry and solid-phase spectrophotometry. Test procedures were developed for determining Be(II) and Al(III) in waters and soils

  13. Radiation-initiated graft polymerization of methyl acrylate onto chrome-tanned sheepskin

    International Nuclear Information System (INIS)

    Radiation grafting method was applied to obtain leather-polymer composite. Grafting of methyl acrylate onto chrome-tanned, bluestock sheepskin was investigated under the initiatory effect of 60Co radiation of 0.20 11.50 Mrad. The percent of grafting was determined and water adsorption and shrinkage temperature measurements were carried out. It was shown that 2-4 Mrad is convenient to produce leather-polymer composite. (author)

  14. A simple method for the use of gallocyanin-chrome alum as an electron strain.

    Science.gov (United States)

    Sandritter, W; Riede, U; Kiefer, G

    1981-03-01

    A method has been elaborated for the demonstration of DNA in the electron microscope. The method uses glutaraldehyde fixed tissue pieces from which RNA has been removed by incubation with RNase. DNA is stained by gallocyanin-chrome alum in the tissue block. Embedding and cutting is done in the usual manner. The method is based on histochemical observations at the light microscope level which show sufficient specificity and a good stoichiometry of the staining reaction. PMID:6163861

  15. MERCURY, LEAD, CADMIUM AND CHROME CONCENTRATION LEVELS IN FISH FOR PUBLIC CONSUMPTION

    Directory of Open Access Journals (Sweden)

    Imer Haziri

    2011-12-01

    Full Text Available A total of seventy cultured fish from the local market of Tirana were sampled and the concentration level of mercury, lead, cadmium and chrome was evaluated. Their concentration always resulted below the maximum permitted level for human consumption set by EC (Hg- 1.0 mg/kg, Pb – 0.30 mg/kg, Cd – 0.05 mg/kg and Cr -8 mg/kg. Heavy metal concentration varied among the muscle tissue of different fish species. The concentration level of mercury, lead, cadmium and chrome ranged between 0.002-0.21 mg/kg (Hg; 0.01-0.16 mg/kg (Pb; nd - 0.002 (Cd, and 0.01-0.03 (Cr mg/kg wet weight. The results collected from this monitoring process revealed that these groups of cultivated fish species show low levels of contaminants, such as mercury (Hg, lead (Pb, cadmium (Cd and chrome (Cr. This monitoring process is very important to safeguard the health of Tirana consumers.

  16. Comparison of wet and dry chrome etching with the CORE-2564

    Science.gov (United States)

    Buck, Peter D.; Grenon, Brian J.

    1994-02-01

    Chrome masks have traditionally been wet etched in an acidic solution of cerric ammonium nitrate. The etchant is commonly sprayed on the mask while the mask is slowly rotated, using an APT-914 or equivalent processor. While this process is well-understood, relatively trouble- free and inexpensive, the isotropic nature of wet etching results in an undercut of the chrome relative to the resist etch mask of approximately equals 150 nm per edge. Compensation for the undercut, in order to maintain control of the mean critical dimension (CD), is done by adjusting the printed feature size such that the undercut grows the printed feature to the desired final size. This sizing can be performed by manipulating the computer aided design database, which can be expensive and time consuming. In this paper, we present a comparison of wet and dry chrome etch processes using plates printed with the CORE-2564 in OCG-895 i resist. The differences in CD performance and resolution are illustrated.

  17. Ni–Mo–Co ternary alloy as a replacement for hard chrome

    Energy Technology Data Exchange (ETDEWEB)

    Srivastava, Meenu, E-mail: meenu_srivas@yahoo.co.uk; Anandan, C.; Grips, V.K. William

    2013-11-15

    Hard chrome is the most extensively used electroplated coating in the aerospace and automotive industries due to its attractive properties such as high hardness and excellent wear resistance. However, due to the health risks associated with the use of hexavalent chromium baths during electroplating, there is a need to identify an alternative to this coating. In this study a nickel–molybdenum alloy with cobalt as the alloying element has been developed. The coating was characterized for its micro hardness, wear resistance, coefficient of friction and corrosion resistance. The coating was also subjected to heat treatment at temperatures in the range of 200°–600 °C. It was observed that the micro hardness of Ni–Mo–Co (730 KHN) alloy coating under optimized conditions is apparently quiet similar to that of the most probable substitute Co–P (745 VHN) and hard chrome (800 VHN) coatings. The tribological properties like the wear rate and coefficient of friction of the 400 °C heat treated Ni–Mo–Co coating were noticed to be better compared to hard chrome coating. The electrochemical impedance and polarization studies showed that the corrosion resistance of heat treated Ni–Mo–Co alloy was better than as-deposited Ni–Mo–Co and Ni–Mo coating.

  18. Comparative statistical analysis of chrome and vegetable tanning effluents and their effects on related soil

    Energy Technology Data Exchange (ETDEWEB)

    Tariq, Saadia R. [Department of Chemistry, Lahore College for Women University, Lahore (Pakistan); Shah, Munir H., E-mail: munir_qau@yahoo.com [Department of Chemistry, Quaid-i-Azam University, Islamabad 45320 (Pakistan); Shaheen, Nazia [Department of Chemistry, Quaid-i-Azam University, Islamabad 45320 (Pakistan)

    2009-09-30

    Two tanning units of Pakistan, namely, Kasur and Mian Channun were investigated with respect to the tanning processes (chrome and vegetable, respectively) and the effects of the tanning agents on the quality of soil in vicinity of tanneries were evaluated. The effluent and soil samples from 16 tanneries each of Kasur and Mian Channun were collected. The levels of selected metals (Na, K, Ca, Mg, Fe, Cr, Mn, Co, Cd, Ni, Pb and Zn) were determined by using flame atomic absorption spectrophotometer under optimum analytical conditions. The data thus obtained were subjected to univariate and multivariate statistical analyses. Most of the metals exhibited considerably higher concentrations in the effluents and soils of Kasur compared with those of Mian Channun. It was observed that the soil of Kasur was highly contaminated by Na, K, Ca and Mg emanating from various processes of leather manufacture. Furthermore, the levels of Cr were also present at much enhanced levels than its background concentration due to the adoption of chrome tanning. The levels of Cr determined in soil samples collected from the vicinity of Mian Channun tanneries were almost comparable to the background levels. The soil of this city was found to have contaminated only by the metals originating from pre-tanning processes. The apportionment of selected metals in the effluent and soil samples was determined by a multivariate cluster analysis, which revealed significant differences in chrome and vegetable tanning processes.

  19. High temperature brush seal tuft testing of metallic bristles versus chrome carbide

    Science.gov (United States)

    Fellenstein, James A.; DellaCorte, Christopher; Moore, Kenneth D.; Boyes, Esther

    1996-01-01

    The tribology of brush seals is of considerable interest to turbine engine designers because bristle wear continues to limit long term seal performance and life. To provide better materials characterization and foster the development of improved seals, NASA Lewis has developed a brush seal tuft tester. In this test, a 'paintbrush' sample tuft is loaded under constant contact pressure against the outside diameter of a rotating journal. With this configuration a direct measurement of load and friction is made. Accurate wear rate measurements are possible due to the known contact pressure. Previously reported baseline research using this facility showed good data repeatability and wear morphology similar to published seal data. This paper extends and expands the database for candidate brush seal materials. A series of tuft tests were completed to evaluate the performance of five high temperature superalloy wires sliding against plasma sprayed nichrome-bonded chrome carbide. Wire materials were either nickel-chrome or cobalt-chrome based superalloys. Good corroboration of the tuft results with dynamic seal rig tests was observed; giving additional confidence in the tuft test as a screening and development tool.

  20. Ni–Mo–Co ternary alloy as a replacement for hard chrome

    International Nuclear Information System (INIS)

    Hard chrome is the most extensively used electroplated coating in the aerospace and automotive industries due to its attractive properties such as high hardness and excellent wear resistance. However, due to the health risks associated with the use of hexavalent chromium baths during electroplating, there is a need to identify an alternative to this coating. In this study a nickel–molybdenum alloy with cobalt as the alloying element has been developed. The coating was characterized for its micro hardness, wear resistance, coefficient of friction and corrosion resistance. The coating was also subjected to heat treatment at temperatures in the range of 200°–600 °C. It was observed that the micro hardness of Ni–Mo–Co (730 KHN) alloy coating under optimized conditions is apparently quiet similar to that of the most probable substitute Co–P (745 VHN) and hard chrome (800 VHN) coatings. The tribological properties like the wear rate and coefficient of friction of the 400 °C heat treated Ni–Mo–Co coating were noticed to be better compared to hard chrome coating. The electrochemical impedance and polarization studies showed that the corrosion resistance of heat treated Ni–Mo–Co alloy was better than as-deposited Ni–Mo–Co and Ni–Mo coating.

  1. Comparative statistical analysis of chrome and vegetable tanning effluents and their effects on related soil

    International Nuclear Information System (INIS)

    Two tanning units of Pakistan, namely, Kasur and Mian Channun were investigated with respect to the tanning processes (chrome and vegetable, respectively) and the effects of the tanning agents on the quality of soil in vicinity of tanneries were evaluated. The effluent and soil samples from 16 tanneries each of Kasur and Mian Channun were collected. The levels of selected metals (Na, K, Ca, Mg, Fe, Cr, Mn, Co, Cd, Ni, Pb and Zn) were determined by using flame atomic absorption spectrophotometer under optimum analytical conditions. The data thus obtained were subjected to univariate and multivariate statistical analyses. Most of the metals exhibited considerably higher concentrations in the effluents and soils of Kasur compared with those of Mian Channun. It was observed that the soil of Kasur was highly contaminated by Na, K, Ca and Mg emanating from various processes of leather manufacture. Furthermore, the levels of Cr were also present at much enhanced levels than its background concentration due to the adoption of chrome tanning. The levels of Cr determined in soil samples collected from the vicinity of Mian Channun tanneries were almost comparable to the background levels. The soil of this city was found to have contaminated only by the metals originating from pre-tanning processes. The apportionment of selected metals in the effluent and soil samples was determined by a multivariate cluster analysis, which revealed significant differences in chrome and vegetable tanning processes.

  2. Vitrification of high chrome oxide nuclear waste in iron phosphate glasses

    International Nuclear Information System (INIS)

    A simulated high level waste (HLW) containing 4 mass% chrome oxide, whose overall composition is representative of the high chrome oxide wastes at Hanford WA USA, was easily vitrified in a phosphate glass at temperatures ranging from 1150 deg. C, for waste loadings of 55 mass%, to 1250 deg. C for waste loadings of 75 mass%. Even at these high waste loadings, these wasteforms had an excellent chemical durability. The best chemical durability was achieved when the O/(Si + P) atomic ratio was between 3.5 and 3.8. These wasteforms were also resistant to crystallization although trace amounts of crystalline Cr2O3 were present in wasteforms containing more than 70 mass% HLW. It is concluded that up to 45 mass% of the total HLW at Hanford, especially that containing as high as 4.5 mass% chrome oxide, could be directly vitrified into an iron phosphate glass, that meets all of the current chemical durability requirements by simply adding 25-35 mass% P2O5 to the waste and melting the mixture at 1150-1250 deg. C for a few (<6) hours

  3. Wastage characteristics of high-chrome steels under sodium-water reaction

    International Nuclear Information System (INIS)

    For the development of a once-through unit type steam generator for an FBR, materials having a high mechanical strength at elevated temperatures and resistivity against stress corrosion cracking are needed for its heat transfer tubes. Although high-chrome steels meet these requirements, their durability under sodium-water reaction was not clear. The present experimental study was conducted to clarify this. The experiment simulated the micro-leak and the small leak events under the accidental conditions. In the micro-leak experiment, a test section with an artificial hole was installed under sodium, and steam was ejected from the hole. A self-wastage rate was determined from the time required to leak hole enlargement. In the small leak experiment, steam was ejected from a hole of one tube toward a target tube. A wastage rate was determined from the time required to the penetration of the target tube. The results reveal that the high-chrome steels have durability equivalent to or better than that of the steels currently being adopted for the heat transfer tubes of the steam generators. No appreciable difference was found among three high-chrome steels studied. (author)

  4. Ultra-violet Behavior of Bosonic Quantum Membranes

    CERN Document Server

    Kaku, M

    2000-01-01

    We treat the action for a bosonic membrane as a sigma model, and then compute quantum corrections by integrating out higher membrane modes. As in string theory, where the equations of motion of Einstein's theory emerges by setting equations of motion for the background fields. Although the membrane theory is non-renormalizable on the world volume by power counting, the investigation of the ultra-violet behavior of membranes may give us insight into the supersymmetric case, where we hope to obtain higher order M-theory corrections to 11 dimensional supergravity.

  5. A stabilised blue-violet LED for VPT photocathode evaluation

    CERN Document Server

    Hobson, Peter R

    2000-01-01

    A highly stable blue-violet light source ( peak wavelength 430 nm) based on the IPL 10630PAL self-monitoring LED is described. A thermoelectric cooler has been used to stabilise the 10630PAL device and the external LED current-control electronics to +- 0.1% K. The light intensity was measured to be stable to +- 0.03% for five hours, the repeatability was +- 0.1% The output spectrum of the LED is a good match to the scintillation emission of PbWO4, and this source will be used to evaluate the spatial and angular uniformity of VPT photocathodes for the endcap calorimeter.

  6. In situ electrocatalytic oxidation of acid violet 12 dye effluent.

    Science.gov (United States)

    Mohan, N; Balasubramanian, N

    2006-08-21

    Electrochemical treatment of organic pollutants is a promising treatment technique for substances which are recalcitrant to biodegradation. Experiments were carried out to treat acid violet 12 dye house effluent using electrochemical technique for removal color and COD reduction covering wide range in operating conditions. Ruthenium/lead/tin oxide coated titanium and stainless steel were used as anode and cathode, respectively. The influence of effluent initial concentration, pH, supporting electrolyte and the electrode material on rate of degradation has been critically examined. The results indicate that the electrochemical method can be used to treat dye house effluents. PMID:16730894

  7. 76 FR 24855 - Carbazole Violet Pigment 23 From India: Rescission of Administrative Review

    Science.gov (United States)

    2011-05-03

    ... Antidumping Duty Order: Carbazole Violet Pigment 23 From India, 69 FR 77988 (December 29, 2004). On January 28... order. See Initiation of Antidumping and Countervailing Duty Administrative Reviews, 76 FR 5137 (January... International Trade Administration Carbazole Violet Pigment 23 From India: Rescission of Administrative...

  8. 75 FR 27815 - Carbazole Violet Pigment 23 From China and India; Determinations

    Science.gov (United States)

    2010-05-18

    ... (74 FR 56663) and determined on February 5, 2010 that it would conduct expedited reviews (75 FR 14468... COMMISSION [Investigation Nos. 701-TA-437 and 731-TA-1060 and 1061 (Review) Carbazole Violet Pigment 23 From... on carbazole violet pigment 23 from India would be likely to lead to continuation or recurrence...

  9. 21 CFR 500.29 - Gentian violet for use in animal feed.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Gentian violet for use in animal feed. 500.29... (CONTINUED) ANIMAL DRUGS, FEEDS, AND RELATED PRODUCTS GENERAL Specific Administrative Rulings and Decisions § 500.29 Gentian violet for use in animal feed. The Food and Drug Administration has determined...

  10. Investigation of adsorption of the dyestuff astrazon red violet 3rn (basic violet 16 on montmorillonite clay

    Directory of Open Access Journals (Sweden)

    B. A. Fil

    2014-03-01

    Full Text Available In this study, color removal by absorption from synthetically prepared wastewater was investigated using montmorillonite clay by adsorption. As dyestuff Astrazon Red Violet 3RN (Basic Violet 16 was used. Experimental parameters selected were pH, temperature, agitation speed, initial dyestuff concentration, adsorbent dosage and ionic strength. It was established that adsorption rate increased with increasing pH, temperature, dye concentration and agitation speed, but decreased with increased ionic strength and adsorbent dosage. Adsorption equilibrium data obtained by a series of experiments carried out in a water bath were employed with common isotherm equations such as Langmuir, Freundlich, Temkin, Elovich and Dubinin-Radushkevich. It was found that the Langmuir equation appears to fit the equilibrium data better than the other models. Furthermore, the fit of the kinetic data to common kinetic models such as the pseudo-first-order, second-order, Elovich and intraparticle diffusion models was tested to elucidate the adsorption mechanism. Kinetic data conformed to the pseudo-second-order model, indicating chemisorptions. In addition, the thermodynamic parameters activation energy, Ea, enthalpy ΔH*, entropy, ΔS*, and free energy change, ΔG*, were calculated. The values of the calculated parameters indicated that physical adsorption of ARV on the clay was dominant and that the adsorption process was endothermic.

  11. Synthesis of Citric-Acrylate Oligomer and its in-Situ Reaction with Chrome Tanned Collagen (hide powder)

    International Nuclear Information System (INIS)

    The purpose of this study was to formulate the new combined system of acrylic and citric acids, which has been prepared by free radical polymerization and esterification reaction at the same time to form citric acrylate (CAC) oligomer through ester linkage and low molecular weight (Mw 2241), in compared with polyacrylic acid. The chemical structure and the reaction mechanism of this oligomer were confirmed by different spectroscopic tools (1H, 13C-NMR, ATR-IR), gel permeation chromatography and thermogravimetric analysis (TGA/DTA). The problem of the effect of the masking agents in the chrome tanning of the collagen and the pickling of the hide has been approached from the study of the hydrothermal and mechanical properties, using this new eco-friendly oligomer, which was carried out in-situ treated/grafted chrome tanned collagen (hide powder), and pickled hide. The microemulsion grafting copolymerization of (CAC) using 2.2-azo-bis isobutyronitrile (ABIN), via direct coupling reaction, onto the chrome tanned collagen showed that the free amino groups of the collagen were considered to be a potential site for the in-situ reaction with (CAC) oligomer. Also, using of citric-acrylate (CAC) oligomer, during chrome tanning of leather, instead of the traditional strong acids (sulfuric, hydrochloric and formic) resulted in significant improvement in chrome exhaustion and physical properties

  12. Peculiarities of solvent extraction of rhenium by crystal violet

    International Nuclear Information System (INIS)

    Formation of ionic perrhenate associate with crystal violet (CV) in sulfate solutions at pH 1.0-4.0 is studied. The dependence of optical density on reagent and rhenium concentrations at constant value of one of them, as well as isomolar diagrams of the perrhenate-CV system indicate that there are two forms of ionic associates caused by formation of two-charge reagent form. The method of photometric determination of rhenium in waste tailings of formation with relatively low molybdenum content is developed. The determined concentration range is 1.0-60 μg Re in 10 ml of benzene extract. The relative standard deviation is 0.06. Comparable quantities of Mo, V, W and more than 50-fold quantities of Cu hinder determination

  13. Transient transfection of mammalian cells using a violet diode laser

    Science.gov (United States)

    Torres-Mapa, Maria Leilani; Angus, Liselotte; Ploschner, Martin; Dholakia, Kishan; Gunn-Moore, Frank J.

    2010-07-01

    We demonstrate the first use of the violet diode laser for transient mammalian cell transfection. In contrast to previous studies, which showed the generation of stable cell lines over a few weeks, we develop a methodology to transiently transfect cells with an efficiency of up to ~40%. Chinese hamster ovary (CHO-K1) and human embryonic kidney (HEK293) cells are exposed to a tightly focused 405-nm laser in the presence of plasmid DNA encoding for a mitochondrial targeted red fluorescent protein. We report transfection efficiencies as a function of laser power and exposure time for our system. We also show, for the first time, that a continuous wave laser source can be successfully applied to selective gene silencing experiments using small interfering RNA. This work is a major step towards an inexpensive and portable phototransfection system.

  14. Soybean plant growth study conducted using purified protein hydrolysate-based fertilizer made from chrome-tanned leather waste.

    Science.gov (United States)

    Pati, Anupama; Chaudhary, Rubina

    2015-12-01

    Leather processing discharges enormous amount of chrome containing leather solid waste which creates a major disposal problem. Chrome-tanned leather solid waste is a complex of collagen and chromium. The presence of chromium limits protein application in fertilizer industry. The purified protein hydrolysate with zero chromium could be used as a nitrogen source for fertilizer formulation. In this study, an attempt has been made to employ purified protein hydrolysate derived from chrome-tanned leather shavings (CTLS) in formulation of fertilizer. The formulated fertilizer (1–3 t ha(-1)) is employed as nitrogen source in production of soybean. Plant growth study demonstrates that formulated fertilizer dosage 3 t ha(-1) produced similar effects of commercial fertilizer-treated plants. Application of formulated fertilizer yielded higher seed in plant than commercial fertilizer. PMID:26498969

  15. Effect of chrome plating on coupling losses in a Nb3Sn cable-in-conduit conductor

    International Nuclear Information System (INIS)

    Time constant of decay of coupling current was measured on cable-in-conduit conductors which consist of twelve Nb3Sn strands with chrome plating. The time constant measurement was performed by observing exponential decrease of induced coupling current in conductors. The measured time constant of conductor composed of bare strands was 4.5 times larger than that of the single strand, in case that a void fraction of conductor was 30%. However, the time constant of conductor composed of strands with chrome plating of more than 2 μm thickness was equal to that of the single strand. These results show that chrome plating on strands is effective for decrease of coupling losses in Nb3Sn cable-in-conduit conductors. (author)

  16. The preparation of cervical scrape material for automated cytology using gallocyanin chrome-alum stain.

    Science.gov (United States)

    Eason, P J; Tucker, J H

    1979-01-01

    A method is described for preparing cervical scrape specimens for automated analysis on the Cerviscan prescreening system. In order to reduce the cellular clumping found in cervical scrape material, cells are collected in suspension, syringed to disaggregate the cell clumps, and then pipetted onto a glass to give a monolayer of cells. The cells are then stained with gallocyanin chrome-alum to give the required quantitation of nucleic acid content, using a rapid staining procedure. Experimental results are given which show that specimens prepared by this method are more suitable for automated analysis than the conventional Papanicolaou stained preparation. PMID:86562

  17. CHROME MINING COMPETITIVENESS ANALYSIS OF TURKEY IN TERMS OF STRATEGIC MANAGEMENT: SECTORAL STRENGTHS, PROBLEMS AND SOLUTIONS

    OpenAIRE

    Ali Rıza İNCE; Yücel EROL

    2012-01-01

    In this study, Chrome mining which has an important place in the Turkish mining industry, analyzed and determined features that can provide a competitive advantage, and also aimed to identifing the existing problems.İn this study qualititive study has done.İn this context, literatüre review was done and descriptive method is used.The first section reviews recent discussions about strategic management approach and its features. The second section includes competetion and competitiveness.İn the...

  18. Interstitial pneumonia caused by inhalation of fumes of nickel and chrome.

    Science.gov (United States)

    Hisatomi, Keiko; Ishii, Hiroshi; Hashiguchi, Koji; Seki, Masafumi; Ide, Mioko; Sugiyama, Kanako; Ishimoto, Hiroshi; Nakayama, Seiko; Mukae, Hiroshi; Kohno, Shigeru

    2006-11-01

    Two male industrial painters were admitted to hospital with dry cough and dyspnoea on exertion following a tank coating operation using a high-temperature spray paint consisting of a nickel-chromium alloy. Both patients showed hypoxaemia, peripheral leukocytosis, high levels of serum cytokines and bilateral ground-glass opacities on a chest CT scan. They were diagnosed with interstitial pneumonia caused by inhalation of nickel and chrome fumes and successfully treated with corticosteroid. These are rare cases of interstitial pneumonia associated with nickel/chromium inhalation. PMID:17052314

  19. Chrome-tanned leather shavings as a filler of butadiene-acrylonitrile rubber.

    Science.gov (United States)

    Przepiórkowska, A; Chrońska, K; Zaborski, M

    2007-03-01

    The noxious wastes from the tanning industry such as chrome-tanned leather shavings were used as the only filler of rubber mixes containing carboxylated butadiene-acrylonitrile rubber (XNBR) or butadiene-acrylonitrile rubber (NBR), and a dispersing agent Limanol PEV (Schill & Seilacher). The best form addition of leather powder to the rubber mixes is mixed the waste protein with zinc oxide. The leather powder added to the rubber mixes improves the mechanical properties: tensile strength (T(s)), elongation at break (epsilon(b)) and increase the cross-linking density of carboxylated XNBR and NBR rubber mixes. Satisfactory results of these studies are presented in this work. PMID:16942836

  20. Selection and application of C18200 chrome copper for the OHTE confinement test helical coil

    International Nuclear Information System (INIS)

    The selection and qualification of copper for the OHTE confinement test helical coil (H-coil) was a crucial step in the success of this new experiment. Previous problems encountered at General Atomic Company with close tolerance machined parts made from high strength copper were identified. The design criteria included selecting a material with minimal warpage during machining, an electrical conductivity >80% IACS, and a yield strength of at least 241 Mpa (35 ksi). The investigation of candidate materials and testing samples led to selection of a material that fully met all requirements. The C18200 chrome copper forged plates were supplied by the Ampco Metal Division of Ampco-Pittsburgh Corporation

  1. Preliminary Results on the Use of Leather Chrome Shavings for Air Passive Sampling

    OpenAIRE

    D. Sanjuán-Herráez; L. Chabaane; Tahiri, S.; A. Pastor; de la Guardia, M.

    2012-01-01

    A new passive sampler based on low-density polyethylene (LDPE) layflat tube filled with chrome shavings from tannery waste residues was evaluated to determine volatile organic compounds (VOCs) in indoor and outdoor areas. VOCs were directly determined by head space-gas chromatography-mass spectrometry (HS-GC-MS) without any pretreatment of the sampler and avoiding the use of solvents. Limit of detection values ranging from 20 to 75 ng sampler−1 and good repeatability values were obtained for ...

  2. Phase stability of chrome-carbide Ni--Cr coatings in low-oxygen environments

    International Nuclear Information System (INIS)

    The thermal stability of the phases in chrome-carbide-based, wear-resistant coatings, applied by plasma and detonation gun (D-gun) devices, was investigated for applications in low-oxygen environments. It was found that current coatings using the Cr3C2 carbide in a Ni--Cr binder decomposed to lower carbides, and consumed Cr from the binder upon long-term exposure at elevated temperature. Two new coatings based on the Cr23C6 carbide were found to have excellent thermal stability, as well as excellent wear properties

  3. Four Station Knee Simulator Wear Testing Comparing Titanium Niobium Nitride with Cobalt Chrome

    OpenAIRE

    Blunn GW, M. R. M.

    2013-01-01

    A new non-destructive method was applied in order to assess bone integrity. The method is based on measurement of bHypersensitivity to an orthopaedic implant was first published in 1966 and since then, in sensitive patients, is known to cause serious problems in joint replacement surgery. Titanium niobium nitride (TiNbN) can act as a surface coat for knee arthroplasty to “hide” the cobalt chrome (CoCr) femoral component beneath, therefore affording an immunoprivileged state. The aim of this s...

  4. RESEARCH OF PROCESS OF AN ALLOYING OF THE FUSED COATINGS RECEIVED FROM THE SUPERFICIAL ALLOYED WIRE BY BORON WITH IN ADDITIONALLY APPLIED ELECTROPLATED COATING OF CHROME AND COPPER

    Directory of Open Access Journals (Sweden)

    V. A. Stefanovich

    2015-11-01

    Full Text Available Researches on distribution of chrome and copper in the fused coating received from the superficial alloyed wire by boron with in additionally applied electroplated coating of chrome and copper were executed. The structure of the fused coating consists of dendrites on which borders the boride eutectic is located. It is established that the content of chrome in dendrites is 1,5– 1,6 times less than in the borid; distribution of copper on structure is uniformed. Coefficients of digestion of chrome and copper at an argon-arc welding from a wire electrode with electroplated coating are established. The assimilation coefficient for chrome is equal to 0,9–1,0; for copper – 0,6–0,75.

  5. Non-destructive evaluation for creep damage of high-chrome steels by using a magnetic sensor

    International Nuclear Information System (INIS)

    This paper presents a non-destructive evaluation of creep damage for high-chrome steels by using a magnetic sensor. The developed magnetic sensor, which can measure the magnetic flux density, B, and the magnetic field strength, H, by B-coil and H-coil, is applied to make clear magnetic properties related to material changes with creep damage. The measured magnetic properties show the material changes of creep damages, and these results are discussed for the capability of a non-destructive evaluation for high-chrome steels. (author)

  6. Radiation induced graft copolymerization of methyl methacrylate onto chrome-tanned pig skins

    International Nuclear Information System (INIS)

    Graft copolymerization of methyl methacrylate (MMA) onto chrome-tanned pig skins was carried out by irradiation with 60Co γ-rays. The grafted polymethyl methacrylate (PMMA) chains were isolated by acid hydrolysis of the collagen backbone in order to characterize the graft copolymers. Proof of grafting was obtained through the detection of amino acid endgroups in the isolated grafts by reaction with ninhydrin. The grafting yield of MMA in aqueous emulsion was found to be higher than that for pure MMA and MMA in acetone. The degree of grafting increases with increasing monomer concentration in emulsion and reaches maximum at radiation dose ca 15 kGy. The yield of grafting is very high. The present paper reports the physical properties of chrome-tanned pig skins after graft polymerization with MMA in emulsion. Modified leathers are more resistant against water absorption and abrasion in comparison with unmodified ones. They have more uniform structure over the whole surface, greater thickness and stiffness. The mechanism of some of the processes occurring during radiation grafting of MMA in water emulsion on tanned leathers has been also suggested and discussed. (author)

  7. Spectrophotometric determination of Sc in eriochrome cyanine R(chrome azurol S) - phosphatidyl choline system

    International Nuclear Information System (INIS)

    Eriochrome cyanine R(chrome azurol S) is used as a color reagent to determine Sc in the presence of phosphatidyl choline, eta = 3.7 * 104 (4.5 * 104). This method has been connected to extraction separation to determine Sc in the presence of rare earth elements, and good results have been obtained. Phosphatidyl choline(PC) is a biochemical reagent, which can be used as a surfactant. It has been reported that chrome azurol S(CAS) can be used to determine Be in the presence of PC but it has not been reported that eriochrome cyanine R(ECR) and CAS can been used to determine Sc in the presence of PC. This paper has put forward a method by which Sc can be determined. ECR (CAS) has been used as a color reagent and PC as a surfactant. Conditional experiments have been made and this method has been connected to extraction separation. Tributyl phosphate (TBP) extracts Sc from rare earth elements to make a determination and good results have been obtained

  8. Waste Treatment of Chrome Residue of Chromium Recovery Process Using Calcium Carbonate

    International Nuclear Information System (INIS)

    The aim of the research was to apply the precipitation technology for the treatment of aqueous wastes of leather tanning industries. The chrome liquid wastes taken was the effluent from the residue of the chromium recovery process using magnesium oxide. The precipitant used was calcium carbonate. The experiments was performed by adjusting the concentration of calcium carbonate from 50 ppm, 100 ppm, 150 ppm, 200 ppm, 250 ppm, 300 ppm, 350 ppm to 400 ppm. The stirring speed was varied from 50 rpm, 75 rpm, 100 rpm, 125 rpm, 150 rpm, 175 rpm to 200 rpm. The time of mixing was varied from 30 minutes, 60 minutes, 90 minutes, 120 minutes, 150 minutes, 175 minutes and 200 minutes. The result from the experiments lead to the best condition obtained were the concentration of precipitant was 300 ppm, flow rates of mixing was 125 rpm and time of mixing was 60 minutes. At this condition the separations efficiency of chrome obtained was 99.985%. (author)

  9. Removal of Azo Dyes (Violet B and Violet 5R from Aqueous Solution Using New Activated Carbon Developed from Orange Peel

    Directory of Open Access Journals (Sweden)

    Saeedeh Hashemian

    2013-01-01

    Full Text Available Activated carbon developed from agricultural waste orange peel (COP was prepared. COP was characterized using Fourier infrared spectroscopy (FTIR, X-ray powder diffraction (XRD, scanning electron microscopy (SEM, and BET. COP has surface area and mean pore diameter of 225.6 m2 g−1 and 22.40 nm, respectively. The removal of violet B (VB and violet 5R (V5R from aqueous solutions by COP was investigated. The effect of operational parameters such as contact time, pH, initial dye concentration, and adsorbent dosage on the adsorption of dyes was investigated. Maximum dye was removed within 30 min of contact time at pH > 7. Two common models, the Langmuir and Freundlich isotherms, were used to investigate the interaction of dye and COPs. The isotherm evaluations revealed that the Langmuir model provides better fit to the experimental data than the Freundlich model. The adsorption of VB and V5R onto COP was followed by pseudo-second-order kinetic model with a good correlation (R2>0.99. Activation energies 5.47 and 29.7 KJ mol−1 were determined for violet B and violet 5R, respectively. The rate of adsorption of violet 5R was faster than that of violet B (kV5R>kVB. The prepared COP could thus be used as promising adsorbent for removal of organic dyes, especially azo dye, from polluted water. The solid COP could be conveniently regenerated after adsorption.

  10. Effect of current imbalance on stability of a cable-in-conduit conductor consisting of chrome-plated strands

    International Nuclear Information System (INIS)

    The effect of an unbalanced current distribution in a conductor consisting of chrome plated strands on stability was investigated using a cable-in-conduit conductor (CICC) consisting of 27 NbTi chrome-plated strands. In addition, the quench behavior when a non-uniform current distribution was produced in the conductor was studied from the experimental results. Moreover, impedance of the chrome-plated strands was measured using the sample conductor. The results show that the stability is determined by the largest strand current when it is sufficiently large otherwise by the transport current when it is not high enough. It was found that it took a long time to make the conductor quench from the onset of the normal transition of the strand carrying the large current. This is explained by the good diffusivity of the coolant temperature in the conductor's cross section. Since the ramp-rate limitation cannot probably take place if the coolant temperature is diffused well in the conductor's cross section, it is expected the ramp-rate limitation can be prevented using this effect. It is also shown that the chrome-plated strands come into contact with one another with uniform transverse conductance on the order of 103 S/m. (author)

  11. Crystal Violet and XTT Assays on Staphylococcus aureus Biofilm Quantification.

    Science.gov (United States)

    Xu, Zhenbo; Liang, Yanrui; Lin, Shiqi; Chen, Dingqiang; Li, Bing; Li, Lin; Deng, Yang

    2016-10-01

    Staphylococcus aureus (S. Aureus) is a common food-borne pathogenic microorganism. Biofilm formation remains the major obstruction for bacterial elimination. The study aims at providing a basis for determining S. aureus biofilm formation. 257 clinical samples of S. aureus isolates were identified by routine analysis and multiplex PCR detection and found to contain 227 MRSA, 16 MSSA, 11 MRCNS, and 3 MSCNS strains. Two assays for quantification of S. aureus biofilm formation, the crystal violet (CV) assay and the XTT (tetrazolium salt reduction) assay, were optimized, evaluated, and further compared. In CV assay, most isolates formed weak biofilm 74.3 %), while the rest formed moderate biofilm (23.3 %) or strong biofilm (2.3 %). However, most isolates in XTT assay showed weak metabolic activity (77.0 %), while the rest showed moderate metabolic activity (17.9 %) or high metabolic activity (5.1 %). In this study, we found a distinct strain-to-strain dissimilarity in terms of both biomass formation and metabolic activity, and it was concluded from this study that two assays were mutual complementation rather than being comparison. PMID:27324342

  12. Retrospective dosimetry using violet thermoluminescence from natural quartz in soil

    International Nuclear Information System (INIS)

    The violet thermoluminescence (VTL)-retrospective dosimetry was developed and was then confirmed to be effectual method in emergency situation using quartz extracts from surface soil collected around Tokai, Ibaraki, Japan. All of the measurements were undertaken by VTL measurement condition using modified single aliquot regenerative-dose protocol. An on-line automatic spectrometric system installed with a small spectrometer and a CCD camera unit was developed for weak and changeable TL-spectrum measurement with rising temperature for application to natural quartz. From spectrometry of the TL, two emission peaks, consisting of 400 nm and 620 nm, were revealed. In this paper, 400 nm were only investigated. The accumulated γ-doses of quartz extracts from surface soils which were 10 m from radiation source at gamma field at the Institution of Radiation Breeding (IRB), National Institute of Agrobiological Sciences (NIAS), were evaluated to be 0.8-0.9 Gy using VTL measurement, concordant with the value measured by the commercial pocket dosimeter. In addition, the dose of quartz extracted from surface soils set at 20 m was evaluated to be 0.2 Gy, agreeable to the value calculated from the pocked dosimeter's value. Conclusively, the VTL-retrospective dosimetry was recommended for the quartz extracts from surface soils in the emergency situation. (author)

  13. What drives the ultra-violet colours of passive galaxies?

    CERN Document Server

    Smith, Russell J; Carter, David

    2012-01-01

    We present and analyse optical and ultra-violet colours for passive and optically-red Coma cluster galaxies for which we have spectroscopic age and element abundance estimates. Our sample of 150 objects covers a wide range in mass, from giant ellipticals to the bright end of the dwarf-galaxy regime. We focus on the colours FUV-i, NUV-i, FUV-NUV, u*-g and g-i. We find that all of these colours are correlated with both luminosity and velocity dispersion at the >5 sigma level, with FUV-i and FUV-NUV becoming bluer with increasing `mass' while the other colours become redder. We perform an empirical analysis to assess what fraction of the variation in each colour can be accounted for by variations in the average stellar populations, as traced by the optical spectra. For u*-g and g-i, most of the observed scatter (~80% after allowing for measurement errors and for systematic errors in u*-g) is attributable to stellar population variations, with colours becoming redder with increasing age and metallicity (Mg/H). Th...

  14. Responses of macaque ganglion cells to far violet lights

    International Nuclear Information System (INIS)

    In a sample of 487 colour-opponent ganglion cells recorded in the central retina of the rhesus and cynomolgus monkeys, 9% of these neurones were found to have responses with the same sign at both ends of the visible spectrum mediated by red-sensitive cones and mid-spectral responses of opposite sign mediated by green-sensitive cones. Selective chromatic adaptation showed that the responses to far violet lights (400 to 420 nm) were due to input from red- and not blue-sensitive cones. These responses were enhanced by backgrounds depressing the sensitivity of blue- and green-sensitive cones and they were depressed by backgrounds depressing the sensitivity of red-sensitive cones; the sensitivity of these responses was yoked to that of responses to far red lights. The relative incidence of these ganglion cells was maximal at the foveal region and decreased towards the peripheral retina. The properties of these cells are consistent with some psychophysical observations of human vision at the short wave-lengths. (author)

  15. Fenton Oxidation of Methyl Violet in Aqueous Solution

    Directory of Open Access Journals (Sweden)

    Saeedeh Hashemian

    2013-01-01

    Full Text Available In this study, oxidative discoloration of methyl violet (MV dye in aqueous solution has been studied using Fenton (Fe2+/H2O2 process. The parameters such as concentration of Fe2+, H2O2, MV, temperature, and Cl− and ions that affected of discoloration in Fenton process were investigated. The rate of degradation is dependent on initial concentration of Fe2+ ion, initial concentration of H2O2, and pH of media. Discoloration of MV was increased by increasing the temperature of reaction. Optimized condition was determined and it was found that the obtained efficiency was about 95.5% after 15 minutes of reaction at pH 3. TOC of dye sample, before and after the oxidation process, was determined. TOC removal indicates partial and significant mineralization of MV dye. The results of experiments showed that degradation of MV dye in Fenton oxidation can be described with a pseudo-irst-order kinetic model. The thermodynamic constants of the Fenton oxidation process were evaluated. The results implied that the oxidation process was feasible, spontaneous, and endothermic.

  16. New Treatment for Infection of the NIPRO LVAD Cannula Site: Nihon University Crystal Violet Method.

    Science.gov (United States)

    Sezai, Akira; Niino, Tetsuya; Osaka, Shunji; Yaoita, Hiroko; Arimoto, Munehito; Hata, Hiroaki; Shiono, Motomi

    2016-01-01

    Driveline and cannula site infections are still a frequent adverse event in patients with a ventricular assist device (VAD), and it is important to treat and prevent them because the spread of local infection may cause sepsis in some cases. We report our experience with a patient in whom infection of the NIPRO LVAD cannula site after implantation of an extracorporeal VAD was controlled by treatment with crystal violet Solbase (Nihon University crystal violet method). PMID:26694275

  17. Photo Inactivation of Streptococcus mutans Biofilm by Violet-Blue light.

    Science.gov (United States)

    Gomez, Grace F; Huang, Ruijie; MacPherson, Meoghan; Ferreira Zandona, Andrea G; Gregory, Richard L

    2016-09-01

    Among various preventive approaches, non-invasive phototherapy/photodynamic therapy is one of the methods used to control oral biofilm. Studies indicate that light at specific wavelengths has a potent antibacterial effect. The objective of this study was to determine the effectiveness of violet-blue light at 380-440 nm to inhibit biofilm formation of Streptococcus mutans or kill S. mutans. S. mutans UA159 biofilm cells were grown for 12-16 h in 96-well flat-bottom microtiter plates using tryptic soy broth (TSB) or TSB with 1 % sucrose (TSBS). Biofilm was irradiated with violet-blue light for 5 min. After exposure, plates were re-incubated at 37 °C for either 2 or 6 h to allow the bacteria to recover. A crystal violet biofilm assay was used to determine relative densities of the biofilm cells grown in TSB, but not in TSBS, exposed to violet-blue light. The results indicated a statistically significant (P < 0.05) decrease compared to the non-treated groups after the 2 or 6 h recovery period. Growth rates of planktonic and biofilm cells indicated a significant reduction in the growth rate of the violet-blue light-treated groups grown in TSB and TSBS. Biofilm viability assays confirmed a statistically significant difference between violet-blue light-treated and non-treated groups in TSB and TSBS. Visible violet-blue light of the electromagnetic spectrum has the ability to inhibit S. mutans growth and reduce the formation of S. mutans biofilm. This in vitro study demonstrated that violet-blue light has the capacity to inhibit S. mutans biofilm formation. Potential clinical applications of light therapy in the future remain bright in preventing the development and progression of dental caries. PMID:27278805

  18. A Micro Blue-violet Laser by Frequency Doubling of Semiconductor Laser

    Institute of Scientific and Technical Information of China (English)

    JIN Jie1; GUO Shuguang; LU Fuyun; ZHANG Guangyin; JIAO Qiang; FANG Xiaojun; YAO Jianquan

    2001-01-01

    In this paper, a micro blue-violet laser by frequency doubling of a semiconductor laser with a new nonlinear organometallic complex cadmium mercury thiocyanate crystal (CMTC) is reported. At room temperature, the blue-violet laser output of 11.8 mW at 404 nm and the conversion4efficiency of the second harmonic generation (SHG) of 0. 60% were obtained with a 1. 98 W, 808 nm semiconductor laser and a 4 mm crystal.

  19. RESEARCH OF PROCESS OF AN ALLOYING OF THE FUSED COATINGS RECEIVED FROM THE SUPERFICIAL ALLOYED WIRE BY BORON WITH IN ADDITIONALLY APPLIED ELECTROPLATED COATING OF CHROME AND COPPER

    OpenAIRE

    V. A. Stefanovich; Borisov, S. V.; A. V. Stefanovich

    2015-01-01

    Researches on distribution of chrome and copper in the fused coating received from the superficial alloyed wire by boron with in additionally applied electroplated coating of chrome and copper were executed. The structure of the fused coating consists of dendrites on which borders the boride eutectic is located. It is established that the content of chrome in dendrites is 1,5– 1,6 times less than in the borid; distribution of copper on structure is uniformed. Coefficients of digestion of chro...

  20. Determination of europium(3) in the presence of Chrome Azurol S by alternating-current polarography

    International Nuclear Information System (INIS)

    The behavior of Eu(3) ions are studied by alternating-current polarography in the presence of a triphenylmethane dye Chrome Azurol S (CAS) in an ammonia buffer solution in a wide range of pH and concentrations. The mechanism of CAS reduction at a dropping mercury electrode is suggested. The studies performed by the saturation curve method and by the method of isomolar series indicate that the ratio of components in the complex formed is 1 : 1. The determination limit for Eu(3) in a 0.1 M NH4Cl solution (pH 7.0) in the presence of CAS is 2.2 x 10-6 M

  1. Structural and mechanical properties of nanostructured metalloceramic coatings on cobalt chrome alloys

    International Nuclear Information System (INIS)

    A functionally graded nanocrystalline metalloceramic coating on cobalt-chrome alloys was investigated with thin-film x-ray diffraction (XRD), nanoindentation, and scratch adhesion testing. The gradual transition in bonding from metallic to predominantly covalent along with a nanocrystalline grain structure provides a unique material system with excellent strength, toughness, and adhesion properties. XRD analysis of the (CrTiN) coating suggests a cubic sodium chloride phase structure with a=4.2169±0.0035 Aa. Nanoindentation measurements of the coating result in a hardness of 27 GPa and Young's modulus of 320 GPa. The graded metallic/covalent nature of the coating with high plasticity also results in excellent film/substrate adhesion as shown by an average critical force of 44±5 N in scratch testing

  2. NASA and ESA Collaboration on Hexavalent Chrome Alternatives Pretreatments Only Interim Test Report

    Science.gov (United States)

    Kessel, Kurt R.

    2015-01-01

    NASA and ESA continue to search for an alternative to hexavalent chromium in coatings applications that meet their performance requirements in corrosion protection, cost, operability, and health and safety, while typically specifying that performance must be equal to or greater than existing systems. The overall objective of the collaborative effort between NASA TEERM and ESA is to test and evaluate coating systems (pretreatments, pretreatments with primer, and pretreatments with primer and topcoat) as replacements for hexavalent chrome coatings in aerospace applications. This objective will be accomplished by testing promising coatings identified from previous NASA, ESA, Department of Defense (DOD), and other project experience. Additionally, several new materials will be analyzed according to ESA-identified specifications.

  3. A comparative analysis of five chrome green pigments based on different spectroscopic techniques

    International Nuclear Information System (INIS)

    A detailed study of five chrome-based green pigments belonging to a large pigment collection at the Academy of Fine Arts in Vienna, Austria has been performed. The samples were analyzed and compared using the two X-ray methods--X-ray fluorescence and X-ray diffraction, and the two optical methods--Raman spectroscopy and infrared spectroscopy. The composition differences between the similarly denoted samples of the collection were determined and the significant sensitivity differences of the investigated methods to specific compounds have been established. This relative discrepancy of the obtained results depending on the technique used proved once again the need of a combined use of the investigated methods

  4. Investigation of neodymium complex with acid chrome blue K by beta-correction spectrophotometry

    International Nuclear Information System (INIS)

    The neodymium complex with acid chrome blue K (ACBK) at pH 10 has been studied in detail by beta-correction spectrophotometry. The cationic surfactant, cetyltrimethylammonium bromide (CTAB) is useful for increasing the sensitivity and solubility of ligand and complex. The characteristic factors of complex are calculated, for example, complex ratio and stability constant. Results show that Nd(ACBK)3 is formed and its real not apparent molar absorptivity is the first to be determined as follows : ε520 Nd(ACBK)3 = 5.54 x 104 dm3 mol-1 cm-1 at pH 10. In addition, the cumulative stability constant of complex Nd(ACBK)3 is still computed to be 1.72 x 1016 in ionic strength 0.1 M and at temperature 15 deg. (author)

  5. Determination of hexavalent chromium in exhaled breath condensate and environmental air among chrome plating workers

    International Nuclear Information System (INIS)

    Chromium speciation has attracted attention because of the different toxicity of Cr(III), which is considered relatively non-toxic, and Cr(VI), which can cross cell membranes mainly as a chromate anion and has been classified as a class I human carcinogen. The aims of the present study were to measure soluble Cr(VI) levels in environmental samples, to develop a simple method of quantifying Cr(VI) in exhaled breath condensate (EBC), and to follow the kinetics of EBC Cr(VI) in chrome plating workers. Personal air samples were collected from 10 chrome platers; EBC was collected from the same workers immediately after the work shift on Tuesday and before the work shift on the following Wednesday. Environmental and EBC Cr(VI) levels were determined by means of colorimetry and electrothermal absorption atomic spectrometry, respectively. The method of detecting Cr(VI) in environmental air was based on the extraction of the Cr(VI)-diphenylcarbazide (Cr(VI)-DPC) complex in 1-butanol, whereas EBC Cr(VI) was determined using a solvent extraction of Cr(VI) as an ion pair with tetrabutylammonium ion, and subsequent direct determination of the complex (Cr(VI)-DPC) in EBC. Kinetic data showed that airborne Cr(VI) was reduced by 50% in airway lining fluid sampled at the end of exposure and that there was a further 50% reduction after about 15 h. The persistence of Cr(VI) in EBC supports the use of EBC in assessing target tissue levels of Cr(VI)

  6. Biosorption of aniline violet from aqueous solution on moringa oleifera saw dust (abstract)

    International Nuclear Information System (INIS)

    Batch adsorption studies were carried out to evaluate the potential of Moringa Oleifera wood saw dust for the removal of aniline violet dye from aqueous solution by optimizing different parameters such as effect of shaking time, adsorbent dose, initial adsorbate concentration etc. The experimental data was subjected to different types of linearized isotherm models such as Freundlich, Langmuir and Dubinin-Radushkevich. The Freundlich isotherm was fitted well with the data. The maximum adsorption capacity of 8.92 m mol./g of aniline violet has been observed through Freundlich isotherm by using the optimized parameters of 50 mg of adsorbent, 5 minutes of shaking time at room temperature of 25 deg. C. The sorption mean free energy from Dubinin-Radushkevich isotherm is 13.36 kJ mol 1 indicating chemisorption. Pseudo-first and Pseudo-second order kinetics models were tested for the adsorption of 1.23 X 10/sup -5) mol L/sup -1) of aniline violet onto Moringa Oleifera wood saw dust. The experimental data fitted well for Pseudo-second order model with coefficient of correlation R/sup 2/ greater or equal to 0.999. The uptake of aniline violet was also studied with the rise in temperature. Thermodynamic parameters have been evaluated and the adsorption process seems to be endothermic. The results indicate that the Moringa Oleifera wood saw dust is an efficient adsorbent for aniline violet from aqueous solutions. (author)

  7. Molecular simulation study of the effects of inorganic anions on the properties of chrome-crosslinked collagen

    International Nuclear Information System (INIS)

    A molecular dynamics (MD) simulation with a modified CHARMM force field was performed to study the effects of various anions (ClO4−, Cl−, HPO42−, SO42−, CNS− and HCOO−) on the structure, stability and crosslinking properties of chrome-crosslinked collagen. Calculated results clearly indicate that the crosslinking quality can be improved through selecting the right kind of anion. The utilization of polychromiums could be fine tuned by varying the type of anion. Perchlorate ions can further stabilize chrome-tanned collagen by hydrogen-bonding interactions. The considerable numbers of hydrogen bonds formed from the sulfate ions and the hydroxyl bridges of polychromium effectively stabilize the four chromium-olation structure during the crosslinking process. (paper)

  8. CHANGE OF MORPHOLOGY OF THE CARBON CHROME-MOLYBDENUM STEEL STRUCTURE UNDER THE INFLUENCE OF THERMAL TREATMENT

    Directory of Open Access Journals (Sweden)

    V. A. Lutsenko

    2010-01-01

    Full Text Available Influence of temperature-temporal parameters of thermal treatment on changing of structure and characteristics of carbon chrome-molybdenum steel is studied. It is shown that there are considerable areas with granular morphology of cementite in metal structure after high-temperature tempering, what provides lowering of microhardness of steel by 25%, and after medium-temperature tempering there are no essential structural changes.

  9. CHANGE OF MORPHOLOGY OF THE CARBON CHROME-MOLYBDENUM STEEL STRUCTURE UNDER THE INFLUENCE OF THERMAL TREATMENT

    OpenAIRE

    V. A. Lutsenko; N. I. Anelkin; T. N. Golubenko; Shcherbakov, V. I.; O. V. Lutsenko; L. A. Drobyshevskij

    2016-01-01

    Influence of temperature-temporal parameters of thermal treatment on changing of structure and characteristics of carbon chrome-molybdenum steel is studied. It is shown that there are considerable areas with granular morphology of cementite in metal structure after high-temperature tempering, what provides lowering of microhardness of steel by 25%, and after medium-temperature tempering there are no essential structural changes.

  10. Underwater current leakage between encapsulated NiChrome tracks: Implications for strain-gauges and other implantable devices

    OpenAIRE

    Vanhoestenberghe, A.; Bickerton, S.; Taylor, S. J. G.; Donaldson, N. D. N.

    2014-01-01

    We present the results of experiments aimed at identifying a suitable polymer for the encapsulation of thin-film strain gauges for underwater applications (with a view of using it in an instrumented bone fusion nail). The leakage currents across grooves cut (using a laser) in thin films of NiChrome over borosilicate glass were studied for encapsulated samples, immersed in water at 37 °C. The selected encapsulants were five silicone rubbers (of both medical and engineering grades), produced by...

  11. Spectrophotometric Microdetermination of Thorium(IV) and Uranium(VI) with Chrome Azurol-S in Presence of Cationic Surfactant

    OpenAIRE

    Upase, A. B.; A. B. Zade; P. P. Kalbende

    2011-01-01

    Cationic surfactant, cetyldimethylethylammonium bromide (CDMEAB), sensitize the color reactions of Th(IV) and U(VI) with chrome azurol-S(CRAS). Formation of water soluble deeply colored ternary complexes of metal ions show large bathochromic shift. Same stoichiometric composition of ternary complexes with 1:2:4 molar ratio (M-CRAS-CDMEAB) have been observed for both the metal ions and are responsible for enhancement in molar absorptivities and sensitivities at shifted wavelength. The ternary ...

  12. Elevated Frequencies of Micronuclei and other Nuclear Abnormalities of Chrome Plating Workers Occupationally Exposed to Hexavalent Chromium

    OpenAIRE

    2011-01-01

    Background Biomonitoring provides a useful tool to estimate the genetic risk from exposure to genotoxic agents. The aim of this study was to assess the potential cytogenetic damage associated with occupational exposure to hexavalent chromium by using micronuclei (MN) as a biomarker. Methods This was a cross-sectional study and all participants were males. Both the exposed and control individuals were selected from Coimbatore, Southern India. Exfoliated buccal cells from 44 chrome plating work...

  13. ESR investigations of radiation grafting of methyl methacrylate in aqueous emulsion onto chrome-tanned pig skin

    International Nuclear Information System (INIS)

    Upon γ-irradiation at 77 K of the aqueous emulsions of methyl methacrylate embedded into chrome-tanned pig skins there are formed only the radicals of collagen and of 2-el-2-methylopropionic acid methyl ester. The presence of water in the system increases markedly the radiation yield of collagen radicals. During gradual heating up the polymerization reactions start and the macro-radical of growing polymer is observed. Chromium does not participate in the processes of initiation and grafting. (author)

  14. Employing fly ash and FCC catalyser waste in recovering chrome (III) from liquid effluent emitted by tanneries

    OpenAIRE

    Jeceny Amaya; Andrés Tristancho; Francisco José Sánchez Castellanos

    2010-01-01

    The present work studies the possibility of using two solid industrial wastes TERMOPAIPA's fly ash and ECOPETROL's alkaline hydrothermal treatments for obtaining zeolytic structures having better propierties; waste catalyser was calcined for eliminatin surface coke. Solids were characterised following treatment including DRX, BET area and CEC. A colorimetric method was standardised for determining chrome in solution; a response surface experimental design was implemented for finding optimum r...

  15. Post-Katrina Fecal Contamination in Violet Marsh near New Orleans

    Directory of Open Access Journals (Sweden)

    Margaret Richmond

    2007-06-01

    Full Text Available Fecal material entrained in New Orleans flood waters was pumped into the local environment. Violet Marsh received water pumped from St. Bernard Parish and the Lower Ninth Ward. Sediment core samples were collected from canals conducting water from these areas to pump stations and from locations within Violet Marsh. Viable indicator bacteria and fecal sterols were used to assess the levels of fecal material in sediment deposited after the levee failures and deeper sediments deposited before. Most of the cores had fecal coliform levels that exceed the biosolids criterion. All of the cores had fecal sterols that exceeded the suggested environmental quality criterion. Our data show both a long history of fecal contamination in Violet Marsh and an increase in fecal loading corresponding to the failure of the levee system. The work was performed as part of the Interagency Performance Evaluation Task Force investigation into the consequences of the failures of the New Orleans levee system.

  16. Oxidation kinetics of crystal violet by potassium permanganate in acidic medium

    Science.gov (United States)

    Khan, Sameera Razi; Ashfaq, Maria; Mubashir; Masood, Summyia

    2016-05-01

    The oxidation kinetics of crystal violet (a triphenylmethane dye) by potassium permanganate was focused in an acidic medium by the spectrophotometric method at 584 nm. The oxidation reaction of crystal violet by potassium permanganate is carried out in an acidic medium at different temperatures ranging within 298-318 K. The kinetic study was carried out to investigate the effect of the concentration, ionic strength and temperature. The reaction followed first order kinetics with respect to potassium permanganate and crystal violet and the overall rate of the reaction was found to be second order. Thermodynamic activation parameters like the activation energy ( E a), enthalpy change (Δ H*), free energy change (Δ G*), and entropy change (Δ S*) have also been evaluated.

  17. Green chemistry approaches to leather tanning process for making chrome-free leather by unnatural amino acids.

    Science.gov (United States)

    Krishnamoorthy, G; Sadulla, S; Sehgal, P K; Mandal, Asit Baran

    2012-05-15

    In the present study, green and sustainable method or eco-friendly approaches to tanning process based on unnatural D-amino acids (D-AA)-aldehyde (Ald) as a substitute for chrome-free tanning has been attempted. The distribution of optically active D-AA in tanned leather, the hydrothermal stability, the mechanical properties and resistance to collagenolytic activity of tanned leather, the evaluation of eco-friendly characteristics were investigated. Scanning electron microscopic (SEM) and Atomic force microscopic (AFM) analyses indicate the surface morphology and roughness, respectively, of the tanned leather collagen matrix. Shrinkage and Differential scanning calorimetric (DSC) analyses shows that the shrinkage temperature (T(s)) and denaturation temperature (T(d)) of tanned leather are related to the content of D-AA+Ald present in the leather matrix. It has been found that the T(s) of D-AA tanned leather is more than that of Ald tanned leather and also more or less equal to chrome tanned leather. Environmental impact assessment (EIA) shows that the developed process results in significant reduction in total solids content (TSC) and improves better biodegradability of organic compound present in the effluent compared to chrome tanning. PMID:22421341

  18. Dynamic material property of the sinter-forged Cu-Cr alloys with the variation of chrome content

    International Nuclear Information System (INIS)

    Vacuum interrupters are used in various switch-gear components such as circuit breakers, distribution switches, contactors. The electrodes of a vacuum interrupter are manufactured of sinter-forged Cu-Cr material for good electrical and mechanical characteristics. Since the closing velocity is 1∼2m/s and impact deformation of the electrode depends on the strain-rate at the given velocity, the dynamic material property of the sinter-forged Cu-Cr alloy is important to design the vacuum interrupter reliably and to identify the impact characteristics of a vacuum interrupter accurately. This paper is concerned with the dynamic material properties of sinter-forged Cu-Cr alloy for various strain rates. The amount of chrome is varied from 10 wt% to 30 wt% in order to investigate the influence of the chrome content on the dynamic material property. The high speed tensile test machine is utilized in order to identify the dynamic property of the Cu-Cr alloy at the intermediate strain-rate and the split Hopkinson pressure bar is used at the high strain-rate. Experimental results from both the quasi-static and the high strain-rate up to the 5000 /sec are interpolated with respect to the amount of chrome in order to construct the Johnson-Cook and the modified Johnson-Cook model as the constitutive relation that should be applied to numerical simulation of the impact behavior of electrodes

  19. Employing fly ash and FCC catalyser waste in recovering chrome (III from liquid effluent emitted by tanneries

    Directory of Open Access Journals (Sweden)

    Jeceny Amaya

    2010-04-01

    Full Text Available The present work studies the possibility of using two solid industrial wastes TERMOPAIPA's fly ash and ECOPETROL's alkaline hydrothermal treatments for obtaining zeolytic structures having better propierties; waste catalyser was calcined for eliminatin surface coke. Solids were characterised following treatment including DRX, BET area and CEC. A colorimetric method was standardised for determining chrome in solution; a response surface experimental design was implemented for finding optimum removal conditions. The most efficient adsorbent was fly ash treated with increased NaOH concentration; optimum condictions for removing chrome were: 58 minutes at 36ºC, 5.9 pH and 31% w/v solid removal. When reused, it was found that the two batches of treated fly ash became saturated following 6 cycles of use, whilst original ash and FCC Catalyser became saturated the second time they were used. Four de-absorbent agents were used for recovering chrome from adsorbent product H2SO4 0.6M being the best. Field trials showed that removal efficiency became reduced by the effect of other contaminantsm depending on the solution's initial concentration.

  20. Interactions between crystal violet and AOT in aqueous solutions and in AOT/isooctane/water microemulsions

    Institute of Scientific and Technical Information of China (English)

    HAO Xiaojuan; AN Xueqin; CHEN Zhiyun; SHEN Weiguo

    2004-01-01

    The absorbance of crystal violet (CV) in a series of aqueous solutions and a series of sodium bis(2-ethyl- hexyl) sulfosuccinate (AOT)/isooctane/water microemulsions has been determined. Association models have been used to analyse the experimental data to obtain the association constants of CV and AOT in the above two media. It was found that about up to 57% CV was associated by AOT in AOT/ isooctane/water microemulsions, which reduced the reaction rate of alkaline fading of crystal violet in the microemulsions.

  1. 75 FR 29718 - Carbazole Violet Pigment 23 From India and the People's Republic of China: Continuation of...

    Science.gov (United States)

    2010-05-27

    ... Five-Year (``Sunset'') Review, 74 FR 56593 (November 2, 2009); See also Carbazole Violet Pigment 23 From China and India, 74 FR 56663 (November 2, 2009). \\1\\ On December 29, 2004, the Department... 2010). See also Carbazole Violet Pigment 23 from China and India; Determinations, 75 FR 27815 (May...

  2. 75 FR 26716 - Carbazole Violet Pigment 23 from India: Extension of Time Limit for Final Results of...

    Science.gov (United States)

    2010-05-12

    ... International Trade Administration Carbazole Violet Pigment 23 from India: Extension of Time Limit for Final... FR 977 (January 7, 2010). This administrative review covers the period January 1, 2007 through... administrative review of the countervailing duty order on carbazole violet pigment 23 (CVP-23) from India....

  3. 75 FR 23239 - Carbazole Violet Pigment 23 From India: Extension of Time Limit for Final Results of Antidumping...

    Science.gov (United States)

    2010-05-03

    ... administrative review of the antidumping duty order on CVP 23 from India. See Carbazole Violet Pigment 23 from India: Preliminary Results of Antidumping Duty Administrative Review, 74 FR 68038 (December 22, 2009... International Trade Administration Carbazole Violet Pigment 23 From India: Extension of Time Limit for...

  4. Mid-term survivorship and clinical outcomes of cobalt-chrome and oxidized zirconium on highly crosslinked polyethylene

    Science.gov (United States)

    Petis, Stephen M.; Vasarhelyi, Edward M.; Lanting, Brent A.; Howard, James L.; Naudie, Douglas D.R.; Somerville, Lyndsay E.; McCalden, Richard W.

    2016-01-01

    Background The choice of bearing articulation for total hip arthroplasty in younger patients is amenable to debate. We compared mid-term patient-reported outcomes and survivorship across 2 different bearing articulations in a young patient cohort. Methods We reviewed patients with cobalt-chrome or oxidized zirconium on highly crosslinked polyethylene who were followed prospectively between 2004 and 2012. Kaplan–Meier analysis was used to determine predicted cumulative survivorship at 5 years with all-cause and aseptic revisions as the outcome. We compared patient-reported outcomes, including the Harris hip score (HHS), Western Ontario and McMaster University Osteoarthritis Index (WOMAC) and Short-form 12 (SF-12) scores. Results A total of 622 patients were followed during the study period. Mean follow-up was 8.2 (range 2.0–10.6) years for cobalt-chrome and 7.8 (range 2.1–10.7) years for oxidized zirconium. Mean age was 54.9 ± 10.6 years for cobalt-chrome and 54.8 ± 10.7 years for oxidized zirconium. Implant survivorship was 96.0% (95% confidence interval [CI] 94.9%–97.1%) for cobalt-chrome and 98.7% (95% CI 98.0%–99.4%) for oxidized zirconium on highly crosslinked polyethylene for all-cause revisions, and 97.2% (95% CI 96.2%–98.2%) for cobalt-chrome and 99.0% (95% CI 98.4%–99.6%) for oxidized zirconium for aseptic revisions. An age-, sex- and diagnosis-matched comparison of the HHS, WOMAC and SF-12 scores demonstrated no significant changes in clinical outcomes across the groups. Conclusion Both bearing surface couples demonstrated excellent mid-term survivorship and outcomes in young patient cohorts. Future analyses on wear and costs are warranted to elicit differences between the groups at long-term follow-up. PMID:26812409

  5. Investigation of the interaction of chrome compounds with blue-green microalgae Spirulina platensis

    International Nuclear Information System (INIS)

    The interaction of CrIII with the cells of blue-green microalgae Spirulina platensis in course of cultivation in a nutrient medium loaded with corresponding chrome compounds is studied. It is shown that the rate of absorption of CrVI ions by spirulina biomass from the nutrient medium is approximately two orders of magnitude lower as compared to that of CrIII ions. At the same time the presence of CrVI in a nutrient medium is accompanied by a significant decrease in the cell growth rate and by deteriorating the quality of spirulina biomass. It is established that at endogenous insertion of CrIII into the biocomplex of spirulina no change in the valence state of chromium in the nutrient medium is observed and the natural properties of the biomass do not change. On the basis of the obtained concentration dependences, the recommended doses of CrIII in the preparation 'Cr-Spirulina' within the ranges of 30-100 μg/g as a food addition, and 200-250 μg/g for a medical preventive treatment are determined. (author)

  6. Salt effects on the surfactant-sensitized spectrophotometric determination of beryllium with Chrome Azurol S

    International Nuclear Information System (INIS)

    The effects of added electrolytes on the spectrophotometric determination of beryllium by absorbance of its complex with Chrome Azurol S (CAS) in the presence of aqueous hexadecyltrimethylammonium bromide (CTAB) were explored. The molar absorptivity increased with the addition of salt, in the order no salt 2SO4 3. Variation of cation (Li+, Na+, K+, NH4+) of added chloride salts produced no effect lambda/sub max/ was red shifted 12-14 nm for all salts. The exact magnitude of this shift depended on beryllium concentration. Increasing the concentration of the added electrolyte resulted in increasing absorbances which leveled off at salt concentrations greater than 0.2 M. Thus, addition of salts at high concentrations swamped out their interferences and lowered the detection limit for the determination of beryllium by the surfactant-sensitized technique to 2.0 x 10-7 M. The results suggest that ion-exchange processes at the micellar surface may be involved in the mechanism of the salt effect

  7. High temperature properties of an iron phosphate melt containing high chrome nuclear waste

    International Nuclear Information System (INIS)

    Iron phosphate glasses are of interest for immobilizing high level nuclear waste (HLW). The high temperature viscosity and AC electrical conductivity of an iron phosphate melt containing 2.8 mass% chrome oxide were investigated in this work. The viscosity of this melt varied from 10 to 50 poise from 1350 to 1150 deg. C, respectively, while the activation energy for viscous flow was 82 and 126 kJ/mol during heating and cooling the melt, respectively. The viscosity of the melt at 1250 deg. C increased with time due to the reduction of Fe3+ to Fe2+. The AC electrical conductivity of the melt varied from 45 to 65 S/m at 1050 and 1350 deg. C, respectively. The activation energy for AC electrical conductivity was 28 and 18 kJ/mol during heating and cooling, respectively. The weight loss rate of the melt at 1250 deg. C after 20 h was only 5 x 10-4 g/cm2/h

  8. Comparison of micronucleus frequencies in poly chrome erythrocytes of mouse fetal liver induced by tritiated water

    International Nuclear Information System (INIS)

    Female 10-12 week old mice of NIH strain were exposed on 10 day gestation to β-rays from tritiated water (HTO) or 60Co gamma rays at constant doses for three days. The pregnant mice were killed by cervical dislocation at 12 h after exposure to THO and 60Co. The fetal liver was removed and slides were made. Micronuclei of poly chrome erythrocytes (PCE) were scored under a binocular microscope. The experimental results showed that the total accumulative doses from β-rays of HTO in the three days were 0, 0.047, 0.093, 0.282, 0.564, 0.846 and 1.270 Gy, and the frequencies of micronuclei of PCE in the fetal liver were 1.64, 2.30, 6.81, 8.43, 12.37, 14.46 and 18.52 per mille respectively. The total accumulative doses from 60Co gamma rays in the three days were 0, 0.10, 0.25, 0.50, 0.75, 1.00, 1.25, and 1.50 Gy, and the frequencies of micronuclei of PCE in the fetal liver were 1.64, 4.7, 5.5, 6.4, 6.9, 6.7 and 8.3 per mille, respectively. The RBE of beta rays from HTO at dose range of 0.4-0.1 Gy were 5.5-3.5

  9. Discussion on Wear Mechanism of High Chrome Brick Used in Coal Slurry Gasifier

    Institute of Scientific and Technical Information of China (English)

    QIXiaoqing; CHENRenpin

    2004-01-01

    The microstructure and phase composition of high chrome brick used in coal slurry gasifier has been analyzed by means of SEM and Energy Spectrum. The results indicate that the used brick can be divided into different zones as slag-adhered zone, reaction zone, penetration zone and unaltered zone. The phase composition and microstructure are different and cracks occurred in different degree at these zones. A dense ring belt was formed with complex spinel ( Mg, Fe)( Cr,Al, Fe2O4) in the reaction zone near the hot face. The wear mechanism of the brick during its employment has been discussed. It is considered that the reaction and penetration of coal slag and strong reduetant bring about the composition change of the brick and destroys its original network inlayed structure and consequently result in its structure spalling and weakening strength, which is the main wear mechanism of the brick and followed by temperature fluctuation and high mechanical im-pact of flowing fluid with high-speed.

  10. Discussion on Wear Mechanism of High Chrome Brick Used in Coal Slurry Gasifier

    Institute of Scientific and Technical Information of China (English)

    QI Xiaoqing; CHEN Renpin

    2004-01-01

    The microstructure and phase composition of high chrome brick used in coal slurry gasifier has been analyzed by means of SEM and Energy Spectrum. The results indicate that the used brick can be divided into different zones as slag-adhered zone, reaction zone, penetration zone and unaltered zone. The phase composition and microstructure are different and cracks occurred in different degree at these zones. A dense ring belt was formed with complex spinel ( Mg, Fe)( Cr,Al, Fe2O4) in the reaction zone near the hot face. The wear mechanism of the brick during its employment has been discussed. It is considered that the reaction and penetration of coal slag and strong reductant bring about the composition change of the brick and destroys its original network inlayed structure and consequently result in its structure spalling and weakening strength,which is the main wear mechanism of the brick and followed by temperature fluctuation and high mechanical impact of flowing fluid with high-speed.

  11. 75 FR 38076 - Carbazole Violet Pigment 23 from India: Final Results of Antidumping Duty Administrative Review

    Science.gov (United States)

    2010-07-01

    ... Pigment 23 from India: Preliminary Results of Antidumping Duty Administrative Review, 74 FR 68038... Value and Antidumping Duty Order: Carbazole Violet Pigment 23 From India, 69 FR 77988 (December 29, 2004...: Assessment of Antidumping Duties, 68 FR 23954 (May 6, 2003). The Department intends to issue...

  12. 75 FR 34699 - Carbazole Violet Pigment 23 from India: Rescission of Countervailing Duty Administrative Review

    Science.gov (United States)

    2010-06-18

    ... Investigation; Opportunity To Request Administrative Review, 74 FR 62743 (December 1, 2009). On December 31... Initiation of Administrative Review, 75 FR 4770 (January 29, 2010). Rescission of Countervailing Duty... International Trade Administration Carbazole Violet Pigment 23 from India: Rescission of Countervailing...

  13. 75 FR 977 - Carbazole Violet Pigment 23 From India: Preliminary Results of Countervailing Duty Administrative...

    Science.gov (United States)

    2010-01-07

    ... Pigment 23 from India, 69 FR 77995 (December 29, 2004) (CVP-23 Order). On December 1, 2008, the Department... Pigment 23 from India, 69 FR 67321 (November 17, 2004), and accompanying Issues and Decision Memorandum... Affirmative Countervailing Duty Determination: Carbazole Violet Pigment 23 From India, 69 FR at 67321....

  14. 75 FR 25209 - Carbazole Violet Pigment 23 from India: Rescission of Administrative Review

    Science.gov (United States)

    2010-05-07

    ... in Part, and Deferral of Initiation of Administrative Review, 75 FR 4770 (January 29, 2010... Review, 75 FR 10759 (March 9, 2010). In this notice we indicated that we would be conducting the changed... International Trade Administration A-533-838 Carbazole Violet Pigment 23 from India: Rescission...

  15. 75 FR 29719 - Carbazole Violet Pigment 23 From India: Continuation of Countervailing Duty Order

    Science.gov (United States)

    2010-05-27

    .... See Notice of Countervailing Duty Order: Carbazole Violet Pigment 23 From India, 69 FR 77995 (December... Pigment 23 from China and India; Determinations, 75 FR 27815 (May 18, 2010). Scope of the Order The... (the Act). See Initiation of Five-Year (``Sunset'') Reviews, 74 FR 56593 (November 2, 2009). As...

  16. 75 FR 33243 - Carbazole Violet Pigment 23 From India: Final Results of Countervailing Duty Administrative Review

    Science.gov (United States)

    2010-06-11

    ... India: Preliminary Results of Countervailing Duty Administrative Review, 75 FR 977 (January 7, 2010... Administrative Review, 75 FR 26716 (May 12, 2010). Scope of the Order The merchandise covered by this order is... International Trade Administration Carbazole Violet Pigment 23 From India: Final Results of Countervailing...

  17. Detection of low concentration of malachite green and crystal violet in water

    Czech Academy of Sciences Publication Activity Database

    Šafařík, Ivo; Šafaříková, Miroslava

    2002-01-01

    Roč. 36, - (2002), s. 196-200. ISSN 0043-1354 R&D Projects: GA ČR GA203/98/1145 Institutional research plan: CEZ:AV0Z6087904 Keywords : magnetic particles * crystal violet Subject RIV: EH - Ecology, Behaviour Impact factor: 1.611, year: 2002

  18. Color-Pure Violet-Light-Emitting Diodes Based on Layered Lead Halide Perovskite Nanoplates.

    Science.gov (United States)

    Liang, Dong; Peng, Yuelin; Fu, Yongping; Shearer, Melinda J; Zhang, Jingjing; Zhai, Jianyuan; Zhang, Yi; Hamers, Robert J; Andrew, Trisha L; Jin, Song

    2016-07-26

    Violet electroluminescence is rare in both inorganic and organic light-emitting diodes (LEDs). Low-cost and room-temperature solution-processed lead halide perovskites with high-efficiency and color-tunable photoluminescence are promising for LEDs. Here, we report room-temperature color-pure violet LEDs based on a two-dimensional lead halide perovskite material, namely, 2-phenylethylammonium (C6H5CH2CH2NH3(+), PEA) lead bromide [(PEA)2PbBr4]. The natural quantum confinement of two-dimensional layered perovskite (PEA)2PbBr4 allows for photoluminescence of shorter wavelength (410 nm) than its three-dimensional counterpart. By converting as-deposited polycrystalline thin films to micrometer-sized (PEA)2PbBr4 nanoplates using solvent vapor annealing, we successfully integrated this layered perovskite material into LEDs and achieved efficient room-temperature violet electroluminescence at 410 nm with a narrow bandwidth. This conversion to nanoplates significantly enhanced the crystallinity and photophysical properties of the (PEA)2PbBr4 samples and the external quantum efficiency of the violet LED. The solvent vapor annealing method reported herein can be generally applied to other perovskite materials to increase their grain size and, ultimately, improve the performance of optoelectronic devices based on perovskite materials. PMID:27336850

  19. Differential inheritance of pepper (capsicum annum) fruit pigments results in black to violet fruit color

    Science.gov (United States)

    Color and appearance of fruits and vegetables are critical determinants of product quality and may afford high-value market opportunities. Exploiting the rich genetic diversity in Capsicum, we characterized the inheritance of black and violet immature fruit color and chlorophyll, carotenoid and ant...

  20. Strong violet emission from zinc oxide dumbbell-like microrods and nanowires

    International Nuclear Information System (INIS)

    ZnO of different morphologies with controlled size and aspect ratio (l/d) such as dumbbell-like microrods, thick nanowires and thin nanowires were prepared by a hydrothermal method. Possible mechanisms for the formation of ZnO crystals with the different morphologies were discussed. Strong violet photoluminescence bands at∼413 nm (3.0 eV) without band edge emission were observed from the dumbbell-like ZnO microrods and thick nanowires. Correspondingly, the thin nanowires showed a weak shoulder UV photoluminescence band at∼390 nm. Such result indicates that the photoluminescence properties could be improved by the morphologies or aspect ratio (l/d) and the potential fabrication violet-light-emitting devices. - Research highlights: ► ZnO crystals were prepared by hydrothermal method. ► The mechanisms for the formation of ZnO crystals were discussed. ► Violet photoluminescence bands were observed from ZnO crystals. ► Violet emission corresponds to the electron transition from the level of interstitial Zn to the valence band.

  1. Batch study of liquid-phase adsorption of Crystal Violet using Posidonia oceanica L. fibers

    International Nuclear Information System (INIS)

    This paper presents a study on the batch adsorption of crystal violet dye from aqueous solution onto Posidonia oceanica L. fibers in order to explore their potential use as low cost adsorbents for wastewater dye removal. A series of batch tests were conducted and the influence of contact time, initial dye concentration, pH of the solution and adsorbent dosage on crystal violet removal was investigated. FT-IR spectroscopy analysis of the Posidonia oceanica L. fibers before and after dye sorption was also investigated to confirm the mechanism of the removal of crystal violet. Results indicate that crystal violet uptake increased with increased initial dye concentration and decreased with increased pH values. The results showed that the highest dye adsorption capacity (11.75 mg/g) was found at pH = 6, for an adsorbent dosage of 5 g/L, initial dye concentration of 60 mg/L, under a constant temperature of 23±02 degree, and the equilibrium state was reached within 10 min of exposure time. The relatively low cost and high capabilities of Posidonia oceanica L. fibers make them potentially attractive options for dye removal from dilute industrial effluents.

  2. Reaction mechanisms in the reduction of Winterveld chrome spinel with graphite and carbon

    International Nuclear Information System (INIS)

    The reduction of mixtures of various sizes of gangue-free Winterveld chrome spinel and graphite under an argon atmosphere at 1300 degrees Celsius was studied by use of a recording thermobalance. The partially reduced material was examined by scanning electron microscopy, and the observations were analysed in terms of reaction mechanism. A four-stage sequence was deduced, as follows. In the first stage, the ferric iron is reduced to ferrous iron with no metallization. This stage is inherently variable and is controlled by the random packing of particles of reducing agent round the chromite. The second stage starts with a burst of metal nucleation, which is also inherently variable. This is followed by the reaction of carbon monoxide with the relatively highly reducible oxide at the perimeters of the metal nuclei, and is controlled by the regeneration of carbon monoxide by the Boudouard reaction. The second stage merges into the third, with no change in the form of the product until the removal of iron decreases the reducibility of the remaining oxide to such an extent that the activity of the carbon monoxide is not sufficient for reduction to proceed. Reduction is then accomplished by the carbon dissolved in the reduced metallic product, the rate of reduction being limited by the rate of carburization of the metal. The fourth stage is reached at a reduction of about 50 per cent. In that stage the rate is controlled by the diffusion of chromium ions in the oxide, and the reduced product becomes saturated with carbon as the mixed (Fe,Cr)7C3 carbide

  3. Quantitative mineralogical characterization of chrome ore beneficiation plant tailing and its beneficiated products

    Science.gov (United States)

    Das, S. K.

    2015-04-01

    Mineralogical characterization and liberation of valuable minerals are primary concerns in mineral processing industries. The present investigation focuses on quantitative mineralogy, elemental deportment, and locking-liberation characteristics of the beneficiation of tailings from a chrome ore beneficiation plant in the Sukinda region, Odisha; methods used for the study of the beneficiated tailings are QEMSCAN®, X-ray diffraction (XRD), and mineral chemistry by a scanning electron microscope equipped with an energy-dispersive spectrometer (SEM-EDS). The tailing sample was fine grained (69.48wt% below 45 μm size), containing 20.25wt% Cr2O3 and 39.19wt% Fe2O3, with a Cr:Fe mass ratio of 0.51. Mineralogical investigations using QEMSCAN studies revealed that chromite, goethite, and gibbsite are the dominant mineral phases with minor amounts of hematite, kaolinite, and quartz. The sample contained 34.22wt% chromite, and chromite liberation is more than 80% for grains smaller than 250 μm in size. Based on these results, it was predicted that liberated chromite and high-grade middling chromite particles could be separated from the gangue by various concentration techniques. The tailing sample was beneficiated by hydrocyclone, tabling, wet high-intensity magnetic separation (WHIMS), and flotation in order to recover the chromite. A chromite concentrate with 45.29wt% Cr2O3 and a Cr:Fe mass ratio of 1.85 can be produced from these low-grade chromite ore beneficiation plant rejects.

  4. Lattice plane spacing change in hardened layer of chrome molybdenum steel after carburizing and quenching

    International Nuclear Information System (INIS)

    Block specimens of chrome molybdenum steel with 0.20 mass% C, SCM420, were carburized in carrier gas and quenched in oil bath. The hardness and carbon content gradients in the hardened layer were measured experimentally. The carburized surface of one block specimen was gradually removed by electrolytic polishing. Ten thin plates were cut from the total case depth of the other block specimen. An experimental method to determine the stress-free lattice plane spacing of the hardened layer was examined using x-ray and neutron radiations. As a result, the stress-free lattice plane spacing change in the hardened layer could be determined successfully by measuring neutron diffraction peaks from Fe-211 of the thin plates during rotating ±90deg around the specimen axis. Using x-ray, the stress-free lattice plane spacing at the carburized surface could be also determined by measuring the 2θ-sin2ψ diagrams of either removed surface of block specimen or thin plate. However, under the carburized surface, the Kα2 diffraction from the heat-treated eutectoid phase was superimposed on x-ray diffraction peak because the subsurface microstructure was composed of martensitic and heat-treated eutectoid phases. The stress-free lattice plane spacing under the carburized surface could not be determined using x-ray. Furthermore, the stress-free lattice plane spacing of Fe-211 was found to decrease with increasing the distance from the carburized surface and be expressed by the cubic function of the carbon content in the hardened layer. (author)

  5. Internal residual strain mapping in carburized chrome molybdenum steel after quenching by neutron strain scanning

    International Nuclear Information System (INIS)

    A hollow circular cylinder specimen with an annular U-notch of chrome molybdenum steel with 0.20 mass% C (SCM420) was carburized in carrier gas and quenched in oil bath. In order to determine the case depth, the specimen was cut off and carbon content and Vickers hardness gradients were measured experimentally near the carburized surface. The residual strain mapping in the interior of carburized cylinder was conducted nondestructively by neutron strain scanning. In this study, the neutron diffraction from Fe-211 plane was used for strain scanning. The neutron wavelength was tuned to 0.1654nm so that diffraction angle became about 90deg. Radial, hoop and axial residual strains were measured by scanning diffracting volume along the axial direction of cylinder specimen. Each residual strain was calculated from lattice spacing change. Unstressed lattice spacing was determined experimentally using reference coupon specimens that were cut from the interior of same carburized cylinder. As a result, the diffraction peak width at half height, FWHM, near the carburized surface was about 3.7 times wider than that of coupon specimens. On the other hand, the most peak widths in the interior equaled to that of coupon specimens. Peak width broadened slightly as the diffracting volume approached the carburized case layer. From the center to the quarter of cylinder specimen, the hoop and axial strains were tensile, and the radial one was compressive in the interior. From the quarter to the edge of the cylinder specimen, the hoop tensile strain increased, radial and axial strains changed to tensile and compressive, respectively. Therefore, the interior of the cylinder specimen was found to be deformed elastically to balance the existence of compressive residual stresses in the carburized case layer. (author)

  6. Poultry feed based on protein hydrolysate derived from chrome-tanned leather solid waste: creating value from waste.

    Science.gov (United States)

    Chaudhary, Rubina; Pati, Anupama

    2016-04-01

    Leather industry generates huge amount of chrome-containing leather solid waste which creates major environment problems to tanners worldwide. Chrome-tanned leather solid waste is primarily chromium complex of collagen protein. The presence of chromium limits its protein application in animal feed industry. The purified protein hydrolysate with zero chromium could be used in poultry feed. In this study, an attempt has been made to assess performance of poultry with purified protein hydrolysate as a feed derived from chrome-tanned leather waste as partial replacement of soyabean meal as a sole source of protein for growing broiler chickens. Growth study was conducted to evaluate the effect of feeding protein hydrolysate on performance and physiochemical characteristics of meat of broiler chickens. Two experimental diets containing various levels of protein hydrolysate (EI-20 % and EII-30 %) were evaluated. The comparative study was performed as control with soyabean meal. Daily feed intake, body weight gain and feed conversion ratio were measured from day 8 to day 35. At the end of the study, birds were randomly selected and slaughtered to evaluate for physiochemical characteristics of meat. Diet had significant effects on feed intake and body weight gain. Birds fed with 20 and 30 % protein hydrolysate consumed 9.5 and 17.5 % higher amount of feed and gained 6.5 and 16.6 % higher than soyabean meal-fed birds. The current study produced evidence that protein hydrolysate can replace up to 75 % of soyabean meal in broiler diets without affecting either growth performance or meat characteristics. PMID:26931657

  7. Green chemistry approaches to leather tanning process for making chrome-free leather by unnatural amino acids

    Energy Technology Data Exchange (ETDEWEB)

    Krishnamoorthy, G.; Sadulla, S.; Sehgal, P.K. [Central Leather Research Institute, Council of Scientific and Industrial Research (CSIR), Adyar, Chennai 600 020 (India); Mandal, Asit Baran, E-mail: abmandal@hotmail.com [Central Leather Research Institute, Council of Scientific and Industrial Research (CSIR), Adyar, Chennai 600 020 (India)

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Unnatural D-AA assisted tanned leathers found soft and full possessing tight grain. Black-Right-Pointing-Pointer Increased hydrothermal stability of collagen via intra and inter molecular crosslink. Black-Right-Pointing-Pointer D-Ly+Ald tanned leathers revealed a properly oriented with well aligned structure. Black-Right-Pointing-Pointer D-AA in collagen creates new topologies inaccessible to homo chiral molecules. Black-Right-Pointing-Pointer Improves conventional tanning process, and reduce the total solid and liquid wastes. - Abstract: In the present study, green and sustainable method or eco-friendly approaches to tanning process based on unnatural D-amino acids (D-AA)-aldehyde (Ald) as a substitute for chrome-free tanning has been attempted. The distribution of optically active D-AA in tanned leather, the hydrothermal stability, the mechanical properties and resistance to collagenolytic activity of tanned leather, the evaluation of eco-friendly characteristics were investigated. Scanning electron microscopic (SEM) and Atomic force microscopic (AFM) analyses indicate the surface morphology and roughness, respectively, of the tanned leather collagen matrix. Shrinkage and Differential scanning calorimetric (DSC) analyses shows that the shrinkage temperature (T{sub s}) and denaturation temperature (T{sub d}) of tanned leather are related to the content of D-AA+Ald present in the leather matrix. It has been found that the T{sub s} of D-AA tanned leather is more than that of Ald tanned leather and also more or less equal to chrome tanned leather. Environmental impact assessment (EIA) shows that the developed process results in significant reduction in total solids content (TSC) and improves better biodegradability of organic compound present in the effluent compared to chrome tanning.

  8. Green chemistry approaches to leather tanning process for making chrome-free leather by unnatural amino acids

    International Nuclear Information System (INIS)

    Highlights: ► Unnatural D-AA assisted tanned leathers found soft and full possessing tight grain. ► Increased hydrothermal stability of collagen via intra and inter molecular crosslink. ► D-Ly+Ald tanned leathers revealed a properly oriented with well aligned structure. ► D-AA in collagen creates new topologies inaccessible to homo chiral molecules. ► Improves conventional tanning process, and reduce the total solid and liquid wastes. - Abstract: In the present study, green and sustainable method or eco-friendly approaches to tanning process based on unnatural D-amino acids (D-AA)-aldehyde (Ald) as a substitute for chrome-free tanning has been attempted. The distribution of optically active D-AA in tanned leather, the hydrothermal stability, the mechanical properties and resistance to collagenolytic activity of tanned leather, the evaluation of eco-friendly characteristics were investigated. Scanning electron microscopic (SEM) and Atomic force microscopic (AFM) analyses indicate the surface morphology and roughness, respectively, of the tanned leather collagen matrix. Shrinkage and Differential scanning calorimetric (DSC) analyses shows that the shrinkage temperature (Ts) and denaturation temperature (Td) of tanned leather are related to the content of D-AA+Ald present in the leather matrix. It has been found that the Ts of D-AA tanned leather is more than that of Ald tanned leather and also more or less equal to chrome tanned leather. Environmental impact assessment (EIA) shows that the developed process results in significant reduction in total solids content (TSC) and improves better biodegradability of organic compound present in the effluent compared to chrome tanning.

  9. Evidence for Degradation of the Chrome Yellows in Van Gogh's Sunflowers: A Study Using Noninvasive In Situ Methods and Synchrotron-Radiation-Based X-ray Techniques.

    Science.gov (United States)

    Monico, Letizia; Janssens, Koen; Hendriks, Ella; Vanmeert, Frederik; Van der Snickt, Geert; Cotte, Marine; Falkenberg, Gerald; Brunetti, Brunetto Giovanni; Miliani, Costanza

    2015-11-16

    This paper presents firm evidence for the chemical alteration of chrome yellow pigments in Van Gogh's Sunflowers (Van Gogh Museum, Amsterdam). Noninvasive in situ spectroscopic analysis at several spots on the painting, combined with synchrotron-radiation-based X-ray investigations of two microsamples, revealed the presence of different types of chrome yellow used by Van Gogh, including the lightfast PbCrO4 and the sulfur-rich PbCr1-x Sx O4 (x≈0.5) variety that is known for its high propensity to undergo photoinduced reduction. The products of this degradation process, i.e., Cr(III) compounds, were found at the interface between the paint and the varnish. Selected locations of the painting with the highest risk of color modification by chemical deterioration of chrome yellow are identified, thus calling for careful monitoring in the future. PMID:26482035

  10. Preparation and formation mechanism of strong violet luminescent CdS quantum dots by using a ligand exchange strategy

    International Nuclear Information System (INIS)

    A simple and general method has been proposed for preparing strong violet emitting CdS quantum dots, in which a ligand exchange strategy was applied to surface passivation and functionalization with good reproducibility. The resulting quantum dots showed a visible violet luminescence with emission peak centered near 423 nm and photoluminescence quantum yields reached over 30%. Additionally, different mercapto-compounds used as ligands can make different functionalized surfaces, favoring quantum dots dispersion in different media and their further applications. It was observed that the band edge emission has the main contribution to the bright violet luminescence

  11. Room-temperature violet-blue emission for SrZrO3 nanocrystals synthesized by using the combustion method

    International Nuclear Information System (INIS)

    We investigated the photoluminescence property of SrZrO3 nanocrystals synthesized by the using combustion method and varying the degree of crystallinity by using high-temperature annealing. In contrast to the bulk case, the SrZrO3 nanocrystals were found to show a strong violet-blue emission even at room temperature. As the crystallinity was enhanced and the grain sizes of the nanocrystals were increased, the violet-blue emission was gradually suppressed. This behavior implies that crystalline disorder is the main origin of the violet-blue emission from SrZrO3 nanocrystals.

  12. Violet photoluminescence from shell layer of Zn/ZnO core-shell nanoparticles induced by laser ablation

    International Nuclear Information System (INIS)

    A strong violet photoluminescence (PL) band at 425 nm (2.92 eV) was observed from the ZnO shell layer of the Zn/ZnO core-shell nanoparticles prepared by laser ablation in liquid media. Such violet PL decreases with increase of the shell thickness or annealing temperature, showing good controllability. Based on the electron paramagnetic resonance measurements, the violet emission is attributed to the electronic transition from the defect level, corresponding to high-concentration zinc interstitials, to the valence band. This study is in favor to clarify the defect-related emissions and to extend the optical and electronic applications of nanostructured ZnO

  13. Radiological proofs of xenogeneity of the ''porphyric phenocrysts'' of olivine, purope and chrome-diopside in kimberlites

    International Nuclear Information System (INIS)

    In order to estimate the genesis of ''phenocrysts'' in kimberlites K-Ar method was used to determine the age of xenolites from some Yakut diamond pipes, the exact age of which is known. The results of estimation are presented. They confirm the mantle origin of xenolites of pyrope peridotites, eclogites and grospydites and their age, they also prove the mantle origin of ''porphyric phenocrysts'' of olivine, pyrope, chrome-diopside. The latter are the products of desintegration of mantle rocks and preserve relics of mantle argon and helium

  14. Fracturing of revision of a cobalt-chrome femoral head after fracturing of a ceramic femoral head, with diffuse metallosis. Case report

    Directory of Open Access Journals (Sweden)

    Pedro Miguel Dantas Costa Marques

    2013-04-01

    Full Text Available We presente a case of a fracture of a cobalt-chrome femoral head after revision of a hip total prosthesis with ceramic femoral head fracture. During surgery we found the cobalt-chrome femoral head fracture, wear of the polyethylene and massive metallosis in muscular and cartilaginous tissue. Both femoral stem and acetabular cup were stable and without apparent wearing. After surgical debridement, we promoted the substitution of the femoral head and the acetabular polyethylene by similar ones. After 12 months of follow-up, the patient has no pain complaints, function limit or systemic signs associated with malign metallosis

  15. Study on plasma-spraying Ni-Al-WC alloy layer on the surface of chrome cast iron and alloy layer's micro-structure and properties

    International Nuclear Information System (INIS)

    Plasma-spraying Ni-Al-WC alloy layer on the surface of chrome cast iron and alloy layer's micro-structure and properties are studied. The analysis items include chemical composition, phase structure, average microhardness, wear resistance and corrosion resistance. The experimental results indicate that metallurgical combination has been achieved completely between the spraying layer and the surface of chrome cast iron, and that the chemical composition and micro-structure in the surface layer of the sample have been changed basically, and that the microhardness, the wear resistance, the corrosion resistance in the surface layer are increased by a large margin

  16. Extraction spectrophotometric method for the determination of trace thorium using 8-hydroxyquinoline and ethyl violet

    International Nuclear Information System (INIS)

    A new highly sensitive colour system for thorium is developed. An association complex of thorium ion is formed with 8-hydroxyquinoline and ethyl violet having absorption maximum at 607 nm. The complex can be extracted into 10 ml of a mixture of benzene and MIBK (3:1) in 1 min. Its apparent ε value is 7.5 x 105 l·mol-1·cm-1 at 607 nm. Optimum conditions for the extraction have been found to be 3.5 x 10-3 mol/l sulfuric acid, 0.020 mol/l 8-hydroxyquinoline and 0.018% ethyl violet. Berr's law is obeyed for 0-4.5 μg of thorium per 10 ml. The colour of the extract is stable in 110 minutes at room temperature. The effects of 32 foreign ions and 4 complex reagents on the determination are discussed

  17. Removal of methyl violet dye by adsorption onto N-benzyltriazole derivatized dextran

    DEFF Research Database (Denmark)

    Cho, Eunae; Tahir, Muhammad Nazir; Kim, Hwanhee;

    2015-01-01

    In this work, N-benzyltriazole derivatized dextran was evaluated for its potential as a novel carbohydrate-based adsorbent for the removal of methyl violet dye from water. The modified dextran was synthesized by a click reaction of pentynyl dextran and benzyl azide, and the structure was...... characterized by nuclear magnetic resonance spectroscopy, elemental analysis, and scanning electron microscopy. Dextran was substituted with a triazole-linked benzyl group. For decolorization of the dye effluent, adsorption is a very effective treatment; here, the driving force is based on hydrogen bonding, pi...... stacking, and electrostatic interaction between the methyl violet dye and the N-benzyltriazole derivatized dextran. Batch experiments were carried out to investigate the required contact time and the effects of pH, initial dye concentrations, and temperature. The experimental data were analyzed with...

  18. Adsorption of Crystal Violet Dye from Aqueous Solution onto Zeolites from Coal Fly and Bottom Ashes

    OpenAIRE

    Tharcila Colachite Rodrigues Bertolini; Juliana C. Izidoro; Carina P. Magdalena; Denise A. Fungaro

    2013-01-01

    The adsorption of the cationic dye Crystal Violet (CV) over zeolites from coal fly ash (ZFA) and bottom ash (ZBA) was evaluated. The coal fly ash (CFA) and the coal bottom ash (CBA) used in the synthesis of the zeolites by alkaline hydrothermal treatment were collected in Jorge Lacerda coal-fired power plant located at Capivari de Baixo County, in Santa Catarina State, Brazil. The zeolitic materials were characterized predominantly as hydroxy-sodalite and X. The dye adsorption equilibrium was...

  19. Kinetic and Thermodynamic Studies of the Adsorption of Crystal Violet onto Used Black Tea Leaves

    OpenAIRE

    Mohammad Abul Hossain; Md T. al-Hassan

    2013-01-01

    This study presents the kinetic and thermodynamic investigation of the adsorption of crystal violet (CV) on used black tea leaves (UBTL) from aqueous solution to evaluate the feasibility of the process. The effects of concentration, solution pH and temperature on adsorption kinetics were carried out in batch process. Kinetic studies have shown that the adsorption data partially follow simple first order, second order and pseudo second order kinetic equations for different initial concentrati...

  20. Spectrophotometric determination of trace amount of cadmium with iodide and methyl violet

    International Nuclear Information System (INIS)

    A selective spectrophotometric method based on the interaction of an anionic iodo complex of cadmium with methyl violet has been described for the determination of trace amounts of cadmium. The developed method is precise, accurate and has been applied to determination of cadmium at trace levels (25 ppb) in sea water and high purity sample of indium and zinc materials. (author). 10 refs., 2 tabs

  1. One electron reduction and absorption characteristics of Cresyl violet in micellar medium

    International Nuclear Information System (INIS)

    Effect of surfactant micelles on absorption characteristics of Cresyl violet (CV) and on its redox reactions have been studied. Among the various surfactants investigated anionic surfactants particularly sodium lauryl sulfate (SLS) and sodium dodecyl benzene sulfonate (SDDBS) showed marked effect on these properties. Reactions of hydrated electron in these micellar media were studied using the technique of nanosecond pulse radiolysis. Results of other surfactants, viz.BSS, CTAB and TritonX-100 have also been presented. (author)

  2. Anatomical structure of african violet (Saintpaulia ionantha L.) vitro- and exvitroplantlets

    OpenAIRE

    Adriana PETRUŞ-VANCEA; Angela Monica ŞIPOŞ

    2010-01-01

    In this article we study the histo-anatomical structure of vegetative organs of African violet (Saintpaulia ionantha L.) vitro- and exvitroplantlets in comparison with similar aspects at the same organs of the greenhouse plants (control lot). The phytoinoculs vitroculture period was 120 days, the ex vitro acclimatization for the exvitroplantlets needed 30 days, and the greenhouse cultivar was 2 years old. Finally, we found that only rootlets of the vitroplantlets had a primary structure becau...

  3. Quantifying hydrogen peroxide in iron-containing solutions using leuco crystal violet

    OpenAIRE

    Schoonen Martin A; Pak Aimee; Strongin Daniel; Cohn Corey A

    2005-01-01

    Hydrogen peroxide is present in many natural waters and wastewaters. In the presence of Fe(II), this species decomposes to form hydroxyl radicals, that are extremely reactive. Hence, in the presence of Fe(II), hydrogen peroxide is difficult to detect because of its short lifetime. Here, we show an expanded use of a hydrogen peroxide quantification technique using leuco crystal violet (LCV) for solutions of varying pH and iron concentration. In the presence of the biocatalyst peroxidase, LCV ...

  4. Decolorization of reactive violet 5 dye in textile wastewater by electrocoagulation

    OpenAIRE

    Borislav N. Malinovic; MIOMIR G. PAVLOVIC

    2016-01-01

    The textile dyeing industry consumes large quantities of water and produces large volumes of wastewater from different steps in the dyeing and finishing processes. Wastewater from printing and dyeing units is often rich in color, containing residues of reactive dyes and chemicals, such as complex components. This study investigates the decolorization of synthetic dye wastewater containing textile dye Reactive Violet 5 (RV5) by electrocoagulation. A laboratory batch reactor was used to investi...

  5. Comparative of the Tribological Performance of Hydraulic Cylinders Coated by the Process of Thermal Spray HVOF and Hard Chrome Plating

    Directory of Open Access Journals (Sweden)

    R.M. Castro

    2014-03-01

    Full Text Available Due to the necessity of obtaining a surface that is resistant to wear and oxidation, hydraulic cylinders are typically coated with hard chrome through the process of electroplating process. However, this type of coating shows an increase of the area to support sealing elements, which interferes directly in the lubrication of the rod, causing damage to the seal components and bringing oil leakage. Another disadvantage in using the electroplated hard chromium process is the presence of high level hexavalent chromium Cr+6 which is not only carcinogenic, but also extremely contaminating to the environment. Currently, the alternative process of high-speed thermal spraying (HVOF - High Velocity Oxy-Fuel, uses composite materials (metal-ceramic possessing low wear rates. Research has shown that some mechanical properties are changed positively with the thermal spray process in industrial applications. It is evident that a coating based on WC has upper characteristics as: wear resistance, low friction coefficient, with respect to hard chrome coatings. These characteristics were analyzed by optical microscopy, roughness measurements and wear test.

  6. The fatigue life of contoured cobalt chrome posterior spinal fusion rods.

    Science.gov (United States)

    Nguyen, T-Q; Buckley, J M; Ames, C; Deviren, V

    2011-02-01

    Intraoperative contouring of posterior rods in lumbar arthrodesis constructs introduces stress concentrations that can substantially reduce fatigue life. The sensitivity of titanium (Ti) and stainless steel (SS) to intraoperative contouring has been established in the literature; however, notch sensitivity has yet to be quantified for cobalt chrome (CoCr), which is now being advocated for use in posterior arthrodesis constructs. The goal of this study is to evaluate the sensitivity of CoCr rods to intraoperative contouring for posterior lumbar screwrod arthrodesis constructs. In this paper lumbar bilateral vertebrectomy models are constructed based on ASTM F1717-01 with curved rods (26-30 degrees total curvature) and poly-axial pedicle screws. Three types of constructs are assembled: first, 5.5 mm SS rods with SS screws (6.5 x 35 mm), second, 6.0 mm Ti rods with Ti screws (7.5 x 35 mm), and third, 6.0 mm CoCr rods with Ti screws (7.5 x 35 mm). All specimens are tested at 4 Hz in dynamic axial compression-bending with a load ratio of ten and maximum load levels of 250, 400, and 700 N until run-out at 2 000 000 cycles. Results are presented that show that the fatigue life of CoCr constructs tend to be greater than Ti constructs at all levels. At the 400 N maximum loading, CoCr lasts an average of 350 000 cycles longer than the Ti constructs. The CoCr constructs are able to sustain the 250 N load until run-out at 2 000 000 cycles but they fail at high load levels (maximum 700 N). The CoCr constructs fail at the neck of the Ti screw at high loads whereas Ti screws fail at the notch induced by contouring. Since CoCr is compatible with magnetic resonance imaging and has high static strength characteristics, the results of this study suggest that it may be an appropriate substitute for Ti. PMID:21428153

  7. Effects of chronic gamma irradiation on adventitious plantlet formation of Saintpaulia ionantha (African violet) detached leaves

    International Nuclear Information System (INIS)

    Formation of adventitious plantlets on unrootedly detached leaves of two African violet (Saintpaulia ionantha) cultivars, pink and violet flowers, chronically gamma-irradiated in gamma room at The Gamma Irradiation Service and Nuclear Technology Research Center, Kasetsart University was compared. Detached leaves were immediately planted after detachment in plastic trays containing peat moss, 18 leaves per treatment with 3 replications. Three dose rates (rad/h) with 3 doses (rad)/dose rate, were applied to the irradiated samples while the controls were placed outside the gamma room. Three months after irradiation, the number of survived leaves, the number of leaves producing adventitious plantlets and the number of plantlets per leaf were recorded. After that, the young plantlets were transferred to the new pots for further observation on plant growth and mutation characters. The results revealed that the number of survived leaves, the number of leaves producing adventitious plantlets and the number of plantlets per leaf varied slightly with radiation doses but were not significantly different at different dose rates. Radiosensitivity was noticed to be higher in pink flower cultivar than the violet one. M 1 V 1 plantlets will be followed up for growth and mutation character observations

  8. Determination of optical constants and nonlinear optical coefficients of Violet 1-doped polyvinyl alcohol thin film

    Indian Academy of Sciences (India)

    Hussain A Badran; Alaa Y Al-Ahmad; Qusay M Ali Hassan; Chassib A Emshary

    2016-01-01

    The optical properties of Violet 1-doped polyvinyl alcohol (PVA) have been investigated using Wemble and Didomenico (WD) method. The optical constants such as refractive index , the dispersion energy , the oscillation energy 0, the lattice dielectric constant ∞, light frequency dielectric constant 0 and the ratio of carrier concentration to the effective mass /* have been determined using reflection spectra in the wavelength range 300–900 nm. The singlebeam Z-scan technique was used to determine the nonlinear optical properties of Violet 1:polyvinylalcohol (PVA) thin film. The experiments were performed using continuous wave (cw) laser with a wavelength of 635 nm. The calculated nonlinear refractive index of the film, $n_{2} = -2.79 \\times 10^{-7}$ cm2/Wand nonlinear absorption coefficient, $\\beta = 6.31\\times10^{−3}$ cm/W. Optical limiting characteristics of the dye-doped polymer film was studied. The result reveals that Violet 1 can be a promising material for optical limiting applications.

  9. Sensitive detection of malachite green and crystal violet by nonlinear laser wave mixing and capillary electrophoresis.

    Science.gov (United States)

    Maxwell, Eric J; Tong, William G

    2016-05-01

    An ultrasensitive label-free antibody-free detection method for malachite green and crystal violet is presented using nonlinear laser wave-mixing spectroscopy and capillary zone electrophoresis. Wave-mixing spectroscopy provides a sensitive absorption-based detection method for trace analytes. This is accomplished by forming dynamic gratings within a sample cell, which diffracts light to create a coherent laser-like signal beam with high optical efficiency and high signal-to-noise ratio. A cubic dependence on laser power and square dependence on analyte concentration make wave mixing sensitive enough to detect molecules in their native form without the use of fluorescent labels for signal enhancement. A 532nm laser and a 635nm laser were used for malachite green and crystal violet sample excitation. The use of two lasers of different wavelengths allows the method to simultaneously detect both analytes. Selectivity is obtained through the capillary zone electrophoresis separation, which results in characteristic migration times. Measurement in capillary zone electrophoresis resulted in a limit of detection of 6.9×10(-10)M (2.5×10(-19)mol) for crystal violet and 8.3×10(-11)M (3.0×10(-20)mol) for malachite green at S/N of 2. PMID:26998858

  10. A violet emission in ZnS:Mn,Eu: Luminescence and applications for radiation detection

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Lun; Chen, Wei, E-mail: weichen@uta.edu [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Jiang, Ke [Center for Biofrontiers Institute, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States); Liu, Xiao-tang [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Department of Applied Chemistry, College of Science, South China Agricultural University, Guangzhou 510642 (China)

    2014-03-14

    We prepared manganese and europium co-doped zinc sulfide (ZnS:Mn,Eu) phosphors and used them for radiation detection. In addition to the red fluorescence at 583 nm due to the d-d transition of Mn ions, an intense violet emission at 420 nm is newly observed in ZnS:Mn,Eu phosphors. The emission is related to Eu{sup 2+} doping but only appears at certain Eu{sup 2+} concentrations. It is found that the intensity of the 420 nm violet fluorescence is X-ray does-dependent, while the red fluorescence of 583 nm is not. The ratio of fluorescence intensities at 420 nm and 583 nm has been monitored as a function of X-ray doses that exposed upon the ZnS:Mn,Eu phosphors. Empirical formulas are provided to estimate the doses of applied X-ray irradiation. Finally, possible mechanisms of X-ray irradiation induced fluorescence quenching are discussed. The intense 420 nm emission not only provides a violet light for solid state lighting but also offers a very sensitive method for radiation detection.

  11. Dynamics of InGaN tandem blue-violet semiconductor lasers

    International Nuclear Information System (INIS)

    Full text: Blue-violet semiconductor lasers have received much attention because of their promise for high-density optical storage applications. In particular, blue-violet laser diodes operating at 400 nm are required for BD- systems and for use in medicine, biology, color printers and monitors, etc, In recent years, numerous fabrication methods have been proposed and developed for blue lasers with CW and self-pulsating operations and the lifetime of such lasers has been increased to over 15000 h. Recently, we have reported self-pulsation and excitable behaviour for an InGaN laser with a p-type saturable absorber, and SP in the frequency range from 1.6 to 2.9 GHz has been achieved with such lasers. In this paper, we present an investigation of the dynamics of tandem 400 nm blue-violet lasers with setup presented in Fig.1a. A particular feature of the devices is the connection of the contacts of the SA, to reduce the carrier lifetime in the SA with the intention of producing self-pulsation and excitability. We examine the laser dynamics in terms of bifurcation diagrams. A typical calculation of bifurcation for the periodic solution is shown in Fig. 1b. This figure shows the dependence of the peak of the photon number on the injected.

  12. A violet emission in ZnS:Mn,Eu: Luminescence and applications for radiation detection

    International Nuclear Information System (INIS)

    We prepared manganese and europium co-doped zinc sulfide (ZnS:Mn,Eu) phosphors and used them for radiation detection. In addition to the red fluorescence at 583 nm due to the d-d transition of Mn ions, an intense violet emission at 420 nm is newly observed in ZnS:Mn,Eu phosphors. The emission is related to Eu2+ doping but only appears at certain Eu2+ concentrations. It is found that the intensity of the 420 nm violet fluorescence is X-ray does-dependent, while the red fluorescence of 583 nm is not. The ratio of fluorescence intensities at 420 nm and 583 nm has been monitored as a function of X-ray doses that exposed upon the ZnS:Mn,Eu phosphors. Empirical formulas are provided to estimate the doses of applied X-ray irradiation. Finally, possible mechanisms of X-ray irradiation induced fluorescence quenching are discussed. The intense 420 nm emission not only provides a violet light for solid state lighting but also offers a very sensitive method for radiation detection

  13. Extraction-radiochemical study of the ion-association complex of antimony (V) with tetrazolium violet and its thermal behavior

    International Nuclear Information System (INIS)

    The optimum conditions for extraction of ion-associated complexes (IAS) formed from the tetrazolium salt - tetrazolium violet and Sb(V) in hydrochloric acid medium have been studied. An isotope of antimony (125Sb) was used for determination of the recovery factor (R%) and distribution ratio (DSb). The thermal behavior of the antimony complex with tetrazole violet was studied using differential thermal and thermogravimetric analysis. (author) 12 refs.; 3 figs

  14. Investigating the interaction of crystal violet probe molecules on sodium dodecyl sulfate micelles with hyper-Rayleigh scattering.

    Science.gov (United States)

    Revillod, Guillaume; Russier-Antoine, Isabelle; Benichou, Emmanuel; Jonin, Christian; Brevet, Pierre-François

    2005-03-24

    We report the use of the nonlinear optical technique of hyper-Rayleigh scattering to investigate the interaction of the cationic probe molecule crystal violet with micelles of sodium dodecyl sulfate. An absolute value of (847 +/- 80) x 10(-30) esu is measured at the fundamental wavelength of 870 nm for the molecular hyperpolarizability of crystal violet free in pure aqueous solutions. In aqueous solutions of sodium dodecyl sulfate, above and below the critical micelle concentration, the measured hyperpolarizability of crystal violet is weaker than in the solution free of sodium dodecyl sulfate. From the comparison with linear optical photoabsorption spectroscopy data, this difference is attributed to electrostatic interactions between the cationic crystal violet molecules and the negatively charged sodium dodecyl sulfate surfactant molecules present in excess. Polarization resolved hyper-Rayleigh scattering measurements are then performed to show that, below and above the critical micelle concentration, crystal violet molecules also undergo symmetry changes upon interaction with sodium dodecyl sulfate. Above the critical micelle concentration, the minimum fraction of micelles interacting with at least one CV molecule is estimated. For instance, for a crystal violet aqueous concentration of 150 microM, this fraction is larger than 7%. PMID:16863205

  15. Effects of alpha-tocopherol addition to polymeric coatings on the UV and heat resistance of a fibrous collagen material--chrome-free leather

    Science.gov (United States)

    UV and heat resistance are very important qualities of leather because most leather products are constantly exposed to outdoor environments. In recent years, we have focused on using environmentally friendly antioxidants that will improve the UV and heat resistance of chrome-free leather. Tocopher...

  16. TOXICITY BIOASSAY AND ELUATE HEAVY METALS ANALYSIS RESULTS OF THE BENCH SCALE STABILIZATION STUDY OF SOILS FROM THE UNITED CHROME SUPERFUND NFL SITE CORVALLIS, OREGON

    Science.gov (United States)

    In support of Environmental Protection Agency Region 10 and their United Chrome studies the staff at Environmental Research Laboratory-Corvallis performed toxicity bioassays and selected chemical analyses. Direct toxicity tests (i.e. using soil as the medium) and indirect toxicit...

  17. Nanoscale Investigation of the Degradation Mechanism of a Historical Chrome Yellow Paint by Quantitative Electron Energy Loss spectroscopy Mapping of Chromium Species

    OpenAIRE

    Tan, Haiyan; Tian, He; Verbeeck, Jo; Monico, Letizia; Janssens, Koen; Van Tendeloo, Gustaaf

    2013-01-01

    Abstract: Getting the picture: The investigation of 100 year old chrome yellow paint by transmission electron microscopy and spectroscopy has led to the identification of four types of coreshell particles. This nanoscale investigation has allowed a mechanism to be proposed for the darkening of some bright yellow colors in Van Gogh's paintings (e.g. in Falling leaves (Les Alyscamps), 1888).

  18. Thermodynamic Assessment of Chrome-Spinel Formation in Laser-Sintered Coatings with Cr2O3 Particles

    Science.gov (United States)

    Krivilyov, Mikhail; Kharanzhevskiy, Evgeny; Reshetnikov, Sergey; Beyers, Lesley J.

    2016-06-01

    Formation of a thin passive layer has been performed using short pulse laser dispersion of Cr2O3 particles in a C22 steel substrate. As a result, the coating's corrosion resistance is substantially improved compared to unprocessed samples. Microstructure analysis by TEM, XPS, and XRD showed that laser processing leads to dissolution of Cr2O3 with formation of Cr and Fe oxides, chrome-spinel, and metallic Cr dispersed in alpha and gamma Fe. Thermodynamic assessment revealed that the formation of pure chromium is caused by reduction of Cr2O3 and oxidation of iron. This reaction is promoted by shifting of chemical equilibrium at elevated temperatures in the molten zone under short pulse laser processing.

  19. A randomized controlled trial comparing Oxinium and cobalt-chrome on standard and cross-linked polyethylene.

    Science.gov (United States)

    Morison, Zachary A; Patil, Sunit; Khan, Habeeb A; Bogoch, Earl R; Schemitsch, Emil H; Waddell, James P

    2014-09-01

    The purpose of the investigation was to assess the clinical and radiographic outcomes in four bearing surfaces. Eighty patients (91 hips) undergoing total hip arthroplasty between 2004 and 2007 were randomized to one of four bearing surfaces: (1) cobalt-chrome (CoCr) and ultra-high molecular weight polyethylene (UHMWPE); (2) CoCr and XLPE; (3) Oxinium and UHMWPE; and (4) Oxinium and XLPE. The mean follow-up for this study was 6.8 years. There were no significant differences in clinical outcomes. The linear wear rates for the four groups were 0.241 mm/year, 0.076 mm/year, 0.238 mm/year and 0.061 mm/year respectively. HXLPE results in significantly less wear than UHMWPE. However, we found no significant reduction in wear rate by using Oxinium in place of CoCr femoral heads at early follow-up. PMID:24961892

  20. Determination of Cr2O3 in chrome-tanned leather by radionuclide-excited X-ray fluorescence analysis

    International Nuclear Information System (INIS)

    Preliminary results on the determination of Cr2O3 in chrome-tanned leather by measuring the content of Cr by means of radionuclide-excited XRF analysis are reported. For excitation a 3.7 GBq 238Pu source was used and the characteristic K X-rays of Cr were detected with a planar Si(Li) detector. Both smooth and rough sides of the leather were analyzed directly or with a pair of V/Ti balanced filters. A fairly good correlation was found between Cr Kx counts of the rough side and the Cr2O3 concentrations determined chemically in the range of 3.5 to 6.0% Cr2O3. The method renders possible a rapid and non-destructive determination of Cr2O3 in various leather samples. (author)

  1. Ségrégation et précipitation dans les alliages fer-chrome hors et sous irradiation

    OpenAIRE

    Senninger, Oriane

    2013-01-01

    Les alliages fer-chrome présentent des comportements thermodynamiques et cinétiques particuliers liés à leurs propriétés magnétiques. La décomposition de l’alliage par vieillissement thermique a été étudiée dans cette thèse. Pour cela, un modèle cinétique de la décomposition de l’alliage à l’échelle atomique a été développé en modélisant de façon détaillée les propriétés thermodynamiques et de diffusion des espèces chimiques dans l’alliage. L’évolution des propriétés de diffusion des éléments...

  2. The Evaluation of a Modified Chrome Oxide Based High Temperature Solid Lubricant Coating for Foil Gas Bearings

    Science.gov (United States)

    DellaCorte, Chris

    1998-01-01

    This paper describes the friction and wear performance of PS304, a modified chrome oxide based coating, for foil gas bearings. PS304 contains 60 wt% NiCr binder, 20 wt% Cr2O3 hardener, and 10 wt% each Ag, and BaF2/CaF2 lubricants. For evaluation, the coating is plasma spray deposited onto test journals which are slid against a superalloy partial arc foil bearing. The test load was 10 KPa (1.5 psi) and the bearings were run under start/stop cyclic conditions. The data show good wear performance of the bearing, especially at temperatures above 25 deg. C. Bearing friction was moderate (micron approx. or equal to 0.4) over the entire temperature range. Based upon the results obtained, the PS304 coating has promise for high temperature, oil-free turbomachinery applications.

  3. Adsorption of Crystal violet on raw and acid-treated montmorillonite, K10, in aqueous suspension.

    Science.gov (United States)

    Sarma, Gautam Kumar; Sen Gupta, Susmita; Bhattacharyya, Krishna G

    2016-04-15

    Crystal violet is used as a dye in cotton and silk textiles, paints and printing ink. The dye is hazardous and exposure to it may cause permanent injury to the cornea and conjunctiva including permanent blindness, and in severe cases, may lead to respiratory and kidney failure. The present work describes removal of Crystal violet from aqueous solution by adsorption on raw and acid-treated montmorillonite, K10. The clay mineral was treated with 0.25 and 0.50 M sulfuric acid and the resulting materials were characterized by XRD, zeta potential, SEM, FTIR, cation exchange capacity, BET surface area and pore volume measurements. The influences of pH, interaction time, adsorbent amount, and temperature on adsorption were monitored and explained on the basis of physico-chemical characteristics of the materials. Basic pH generally favors adsorption but considerable removal was possible even under neutral conditions. Adsorption was very rapid and equilibrium could be attained in 180 min. The kinetics conformed to second order model. Langmuir monolayer adsorption capacity of raw montmorillonite K10 was 370.37 mg g(-1) whereas 0.25 M and 0.50 M acid treated montmorillonite K10 had capacities of 384.62 and 400.0 mg g(-1) respectively at 303 K. Adsorption was exothermic and decreased in the temperature range of 293-323 K. Thermodynamically, the process was spontaneous with Gibbs energy decreasing with rise in temperature. The results suggest that montmorillonite K10 and its acid treated forms would be suitable for removing Crystal violet from aqueous solution. PMID:26866669

  4. Multiresidue method for the triphenylmethane dyes in fish: Malachite green, crystal (gentian) violet, and brilliant green

    International Nuclear Information System (INIS)

    Liquid chromatographic methods are presented for the quantitative and confirmatory determination of crystal violet (CV; also known as gentian violet), leucocrystal violet (LCV), brilliant green (BG), and leucobrilliant green (LBG) in catfish. LCV and LBG were oxidized to the chromic CV and BG by reaction with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone, and residues were measured as the combined CV ± LCV and BG ± LBG. These methods are extensions of published methods for malachite green (MG) analysis to allow simultaneous determination of MG, CV, and BG. Residues were extracted from muscle with ammonium acetate buffer and acetonitrile, and extracts cleaned up using dichloromethane partitioning and solid-phase extraction. Extracts were analyzed by liquid chromatography with visible detection (LC-VIS). The method was validated for catfish fortified with LCV over the range 0.25-10 ng g-1 and CV at 2 ng g-1. Average recoveries were 90.6% (±8.1% R.S.D., n = 45) for LCV and 84.4% (±4.2% R.S.D., n = 6) for CV. The average recovery for samples fortified with BG or LBG over the range 0.5-10 ng g-1 was 67.2% (±14.8% R.S.D., n = 31). CV and BG were confirmed in fish extracts by ion trap LC-mass spectrometry (LC-MSn) with no discharge-atmospheric pressure chemical ionization. Average LC-MSn recoveries were 96.5, 96.6, and 70.2% for samples fortified with CV, LCV, and BG or LBG. The limits of detection for CV, BG, and MG were in the range of 0.07-0.24 ng g-1 (ppb) for the two different instrumental methods. This methodology was applied to the analysis of catfish treated with CV and BG

  5. Spectrophotometric determination of boron by solvent extraction with hydrobenzoin and crystal violet

    International Nuclear Information System (INIS)

    A highly sensitive and simple method for the spectrophotometric determination of boron was developed. Boron was found to react with hydrobenzoin in weak alkaline medium to form a complex anion extractable into benzene with crystal violet, and the measurement of the absorbance of crystal violet in the extract at 600 nm enabled the determination of boron indirectly. The recommended procedure is as follows: Take an aliquot of the boron solution (2.0 x 10-4 mol l-1) into a 10-ml test tube. Add 1 ml of carbonate buffer solution (pH 9.4) and 0.25 ml of crystal violet solution (1.0 x 10-2 mol l-1), and dilute the mixed solution to 4 ml with deionized water. Shake the solution with 4 ml of benzene solution containing hydrobenzoin (2.0 x 10-2 mol l-1) for 2 min. Measure the absorbance of the organic phase at 600 nm using a 10-mm glass cell against benzene. The calibration curve obeyed Beer's law on the concentration range from 2.5 x 10-6 mol l-1 to 2.5 x 10-5 mol l-1 of boron, and the apparent molar absorptivity was 3.0 x 104 l mol-1 cm-1 at 200C. It was found that many kinds of co-existing ions interfered with the determination. However, this method was applicable to the determination of boron in sea water when chloride ion and cations such as Ca(II) and Mg(II) were previously eliminated by treating the sample solution with Ag2O and cation exchanger resin. The proposed method is a very simple and rapid one, because this method does not require apparatus other than common laboratories and the evaporation to dryness of sample or removal of the excess of reagent. (author)

  6. Chlorophyll Fluorescence as a Tool to Assess the Regeneration Potential of African Violet Leaf Explants

    Directory of Open Access Journals (Sweden)

    Norbert KEUTGEN

    2016-06-01

    Full Text Available Micropropagation of many ornamentals has enabled their efficient commercialisation and many problems have been solved by the elaboration of adequate culture protocols. Nevertheless, a non-destructive technique for monitoring the developmental progress of explants would be desirable. The present study focussed on the applicability of chlorophyll fluorescence in leaf explants of African violet (a Saintpaulia ionantha × confusa – hybrid explanted onto Murashige and Skoog basic medium. The explants that survived on the medium without additional phytohormones had the capacity to develop further into two different kinds of explants: light green explants, characterized by a non-regular size growth and stiffer appearance, and dark green explants capable of organogenesis. Compared to the source leaves of African violet plants, explants were characterized by reduced chlorophyll (Chl and carotenoid (Car contents as well as a tendency towards a higher Car/Chl ratio. The Chl a/b ratio decreased significantly in the light green explants. A reduction of maximum quantum efficiency of photosystem II (Fv/Fm accompanied by a high percentage (> 50% of thermal energy dissipation as a consequence of an elevated light intensity (800 µmol m-2 s-1 quanta indicated photoinhibition in the light green explants, whereas in the dark green explants the largest percentage (> 50% of the light energy was dissipated into the fraction of photon energy trapped by ‘closed’ photosystem II reaction centres. These results suggest that the capacity of organogenesis of leaf explants of African violet can be monitored using chlorophyll fluorescence, because it is related to modifications of the photosynthetic system.

  7. Removal of Cr(III) from chrome tanning wastewater by adsorption using two natural carbonaceous materials: Eggshell and powdered marble.

    Science.gov (United States)

    Elabbas, Saliha; Mandi, Laila; Berrekhis, Fatima; Pons, Marie Noelle; Leclerc, Jean Pierre; Ouazzani, Naaila

    2016-01-15

    In the present paper, eggshell and powdered marble, two carbonaceous materials, were used to remove Cr(III) ions from a real chrome tanning wastewater. The effects of initial effluent pH, adsorbent dose, contact time and temperature were studied. The maximum uptake of chromium ions was obtained at pH 5.0 with the dose 20 g L(-1) and 12 g L(-1) for eggshell and powdered marble respectively. Adsorption equilibrium was reached after 14 h contact time for eggshell and only after 30 min for powdered marble. Under these conditions, almost 99% Cr(III) was removed from chrome tanning wastewater having an initial concentration of chromium of 3.21 g L(-1). Kinetic data were satisfactorily described by a pseudo-second order chemical sorption model. The equilibrium rate constant was notably greater for powdered marble than for eggshell with 1.142·10(-3) (g mg(-1) min(-1)) and 0.041·10(-3) (g mg(-1) min(-1)) respectively. The adsorption isotherm were well described by a Langmuir model and showed that the interaction of chromium with the two adsorbents surface is a localized monolayer adsorption with a smaller energy constant for the powdered marble than for eggshell (0.020 (L mg(-1)) and 0.083 (L mg(-1)) respectively). The powdered marble was able to adsorb faster a large amount of Cr (III) in comparison to eggshell. The use of a standardized lettuce seed bioassay allowed evaluating a better effectiveness of the Cr adsorption on the powdered marble, removing up to 40% of the treated effluent toxicity than by eggshell 25%. The powdered marble could be considered as an effective, low cost carbonaceous material to be used for chromium removal from tanning wastewater. PMID:26598282

  8. Comparison of the results between polyethylene liners articulated with zirconia ceramic and cobalt-chrome femoral heads in vivo

    Institute of Scientific and Technical Information of China (English)

    Feng Liu; James P. Waddell

    2005-01-01

    Objective: The aseptic loosening of the implants is the main contributor to the long-term failure of hip arthroplasty.One of the alternatives is to choose ceramic head instead of the traditional CoCr head. This study is conducted to determine the clinicalefficacy of a zirconia ceramic head. Methods: Twenty-six cementless total hip arthroplasties in 24 patients were performed using a zirconiahead coupled with polyethylene. All hips were followed for an average of 9 years (range, 6-13 years). A matched group of 26 hips in 26patients using cobalt-chrome heads coupled with polyethylene were also followed for average of 10 years (range, 5-14 years). The twogroups of patients were evaluated clinically and radiographically respectively. Results: The average scores of functional hip according toHarris standard improved from 46 (preoperatively) to 86 (at the final follow-up) in the Zirconia group, and from 50 to 88 in the CrCogroup. The mean liner wear rate of zirconia-polyethylene coupling was 0. 118 mm/year (range, 0. 064-0. 175 mm/year), and the linearwear rate of CrCo-polyethylene was 0.113 mm/year (range, 0.056-0.190 mm/year). There were 10 hips (27%) revised due to looseningor extensive osteolysis of the.cup in the Zirconia group, and only 4 hips (11.5%) in CrCo group. Conclusion: Results of the studysuggest that a zirconia ceramic femoral head has little advantage over a cobalt-chrome head in decreasing polyethylene wear in vivo. Ourstudy demonstrates that although changes in designs and materials may offer theoretical advantages over current components, their effectsremain questionable in vivo.

  9. Towards dating Quaternary sediments using the quartz Violet Stimulated Luminescence (VSL) signal

    DEFF Research Database (Denmark)

    Ankjærgaard, C.; Jain, Mayank; Wallinga, J.

    2013-01-01

    Quartz optically stimulated luminescence (OSL) dating is widely used to determine the time of deposition and burial of Late Quaternary sediments. Application of the method is usually limited to the past 150,000 years due to early saturation of the OSL signal. Here we explore the potential to date...... Quaternary sediments using the violet (402 nm) stimulated luminescence (VSL) signal of quartz.We develop and test a new post-blue VSL single aliquot regenerative dose dating protocol, and demonstrate that the VSL signal originates from a deep trap at about 1.9 eV with a thermal lifetime of 1011 years at 10...

  10. Violet/blue photoluminescence from CeO2 thin film

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    CeO2 thin film was fabricated by dual ion beam epitaxial technique. The violet/blue PL at room temperature and lower temperature was observed from the CeO2 thin film. After the analysis of crystal structure and valence in the compound was carried out by the XRD and XPS technique, it was inferred that the origin of CeO2 PL was due to the electrons transition from Ce4f band to O2p band and the defect level to O2p band. And these defects levels were located in the range of 1 eV around Ce4f band.

  11. Extreme ultra-violet movie camera for imaging microsecond time scale magnetic reconnection

    International Nuclear Information System (INIS)

    An ultra-fast extreme ultra-violet (EUV) movie camera has been developed for imaging magnetic reconnection in the Caltech spheromak/astrophysical jet experiment. The camera consists of a broadband Mo:Si multilayer mirror, a fast decaying YAG:Ce scintillator, a visible light block, and a high-speed visible light CCD camera. The camera can capture EUV images as fast as 3.3 × 106 frames per second with 0.5 cm spatial resolution. The spectral range is from 20 eV to 60 eV. EUV images reveal strong, transient, highly localized bursts of EUV radiation when magnetic reconnection occurs

  12. Extreme ultra-violet movie camera for imaging microsecond time scale magnetic reconnection

    Energy Technology Data Exchange (ETDEWEB)

    Chai, Kil-Byoung; Bellan, Paul M. [Applied Physics, Caltech, 1200 E. California Boulevard, Pasadena, California 91125 (United States)

    2013-12-15

    An ultra-fast extreme ultra-violet (EUV) movie camera has been developed for imaging magnetic reconnection in the Caltech spheromak/astrophysical jet experiment. The camera consists of a broadband Mo:Si multilayer mirror, a fast decaying YAG:Ce scintillator, a visible light block, and a high-speed visible light CCD camera. The camera can capture EUV images as fast as 3.3 × 10{sup 6} frames per second with 0.5 cm spatial resolution. The spectral range is from 20 eV to 60 eV. EUV images reveal strong, transient, highly localized bursts of EUV radiation when magnetic reconnection occurs.

  13. Can Ultra-violet Mie Lidar Be an Effective Instrument During High Pollution Episode?

    Science.gov (United States)

    Liu, Qiaojun; Wang, Zhangjun; Du, Libin; Cheng, Andrew Yuk Sun; Meng, Xiangqian; Chen, Chao; Li, Xianxin; Liu, Xingtao

    2016-06-01

    Vertical profiles of particulates were measured by a 355 nm Mie scattering lidar during a dust-storm event. A high energy pulse laser was employed as the light source to detect the extinction coefficient in the altitude up to 6 km in the day and 9 km at night. The extinction profiles showed layers of high aerosol concentrations in good agreement with ground-based pollution measurements, which indicated that such ultra-violet lidar is a very useful remote sensing instrument for monitoring extinction profiles during extreme high aerosol loading and low visibility atmospheric conditions when low energy lidar systems cannot obtain effective results.

  14. Violet/blue emission from epitaxial cerium oxide films on silicon substrates

    International Nuclear Information System (INIS)

    Violet/blue photoluminescence was observed from epitaxial cerium oxide films on silicon substrates. The films were deposited on silicon (111) substrates under ultrahigh vacuum conditions using pulsed laser ablation of a cerium oxide target and treated by rapid thermal annealing in argon. High resolution transmission electron microscopy and x-ray diffraction measurements indicated the formation of a single crystal cerium oxide phase Ce6O11 different from CeO2 in the annealed films. The emission might be due to charge transfer transitions from the 4f band to the valence band of the oxide. copyright 1997 American Institute of Physics

  15. Effect of bisquaternary ammonium salts on complexing of metal ions with pyrocatechol violet

    International Nuclear Information System (INIS)

    Conditions for the improvement of contrast and sensitivity of reactions of high-charge ions of metals (Mo, W, La, Cd, Zr, Hf, Th) in the process of their photometric determination with pyrocatechol violet (PV), using bisquaternary ammonium salts (BQAS), have been studied. It is shown that in the systems investigated the BQAS play the role of ''shifting'' reagents, shifting bathochromically the absorption bands of different ligand complexes as compared with absorption bands of the Me-PV binary complexes. The effect of the BQAS on complexing with PV in aqueous and organic phases (chloroform) is studied and potential flotation of the compounds in the phase interface is considered

  16. Spectrophotometric study of ion associate of molybdotunqstophosphoric heteropoly acid with crystal violet

    International Nuclear Information System (INIS)

    The ion associates formed by molybdotungstophosphoric acid and Crystal Violet have been studied. The ratio of MTP:CV is 1:3 at P:W=1:1 and 1:4 at P:W=1:11. Conditions for the ion associate formation and flotation with butyl acetate have been found. The molar absorptivities are 2.78x105 and 4.17x105 respectively. A procedure has been developed of spectrophotometric determination of phosphorus in the presence of arsenic

  17. Exploring the temporally resolved electron density evolution in extreme ultra-violet induced plasmas

    Science.gov (United States)

    van der Horst, R. M.; Beckers, J.; Nijdam, S.; Kroesen, G. M. W.

    2014-07-01

    We measured the electron density in an extreme ultra-violet (EUV) induced plasma. This is achieved in a low-pressure argon plasma by using a method called microwave cavity resonance spectroscopy. The measured electron density just after the EUV pulse is 2.6 × 1016 m-3. This is in good agreement with a theoretical prediction from photo-ionization, which yields a density of 4.5 × 1016 m-3. After the EUV pulse the density slightly increases due to electron impact ionization. The plasma (i.e. electron density) decays in tens of microseconds.

  18. Removal of Crystal Violet Dye from Aqueous Solutions onto Date Palm Fiber by Adsorption Technique

    OpenAIRE

    2013-01-01

    The adsorption of crystal violet (CV) onto date palm fibers (DPFs) was examined in aqueous solution at 25°C. The experimental maximum adsorption capacity value was 0.66×10−6. Langmuir, Freundlich, Elovich and Temkin models were applied to describe the equilibrium isotherms. The influence of pH and temperature on dye removal was evaluated. The percentage removal of CV dye by adsorption onto DPF at different pH and temperatures showed that these factors play a role in the adsorption process. Th...

  19. A temperature response function for modeling leaf growth and development of the African violet (Saintpaulia ionantha Wendl.

    Directory of Open Access Journals (Sweden)

    Streck Nereu Augusto

    2004-01-01

    Full Text Available Response functions used in crop simulation models are usually different for different physiological processes and cultivars, resulting in many unknown coefficients in the response functions. This is the case of African violet (Saintpaulia ionantha Wendl., where a generalized temperature response for leaf growth and development has not been developed yet. The objective of this study was to develop a generalized nonlinear temperature response function for leaf appearance rate and leaf elongation rate in African violet. The nonlinear function has three coefficients, which are the cardinal temperatures (minimum, optimum, and maximum temperatures. These coefficients were defined as 10, 24, and 33ºC, based on the cardinal temperatures of other tropical species. Data of temperature response of leaf appearance rate and leaf elongation rate in African violet, cultivar Utah, at different light levels, which are from published research, were used as independent data for evaluating the performance of the nonlinear temperature response function. The results showed that a generalized nonlinear response function can be used to describe the temperature response of leaf growth and development in African violet. These results imply that a reduction in the number of input data required in African violet simulation models is possible.

  20. Chemical characterization and toxicologic evaluation of airborne mixtures: chemical characterization of combusted inventory red and violet smoke mixes

    International Nuclear Information System (INIS)

    Red and violet smoke grenades (Grenade, Hand, Smoke, M18) were combusted within canvas tents and the combustion products were sampled and analyzed. Uncombusted red and violet smoke mixes from the same lots used to fill the combusted grenades were also analyzed. Approximately ten percent of the major dye component of the red smoke mix, methylaminoanthraquinone (MAA) was converted to aminoanthraquinones (1-AA and 2-AA). The violet smoke mix was formulated to contain 1,4-diamino-2,3-dihydroanthraquinone (DAA) and MAA. Upon combustion the DAA was converted almost completely to diaminoanthraquinone (DAA) which was a minor constituent of the uncombusted mix. As in the combusted red smoke mix, it was found that MAA was partially converted to aminoanthraquinones

  1. Adsorption and desorption characteristics of crystal violet in bottom ash column

    Directory of Open Access Journals (Sweden)

    Puthiya Veetil Nidheesh

    2012-06-01

    Full Text Available This study described adsorption of Crystal Violet (CV by bottom ash in fixed-bed column mode. Equilibrium of adsorption was studied in batch mode for finding adsorption capacity of bottom ash. In fixed bed column adsorption, the effects of bed height, feed flow rate, and initial concentration were studied by assessing breakthrough curve. The slope of the breakthrough curve decreased with increasing bed height. The breakthrough time and exhaustion time were decreased with increasing influent CV concentration and flow rates. The effect of bed depth, flow rate and CV concentration on the adsorption column design parameters were analyzed. Bed depth service time (BDST model was applied for analysis of crystal violet adsorption in the column. The adsorption capacity of bottom ash was calculated at 10% breakthrough point for different flow rates and concentrations. Desorption studies reveals that recovery of CV from bottom ash was effective by using CH3COOH than H2SO4, NaOH, HCl and NaCl solutions.

  2. Stable violet cathodoluminescence of α-quartz after Ge+ implantation at elevated temperature

    International Nuclear Information System (INIS)

    Doping single-crystalline α-quartz with 120 keV Ge+-ion implantation under the conditions of dynamic solid phase epitaxial regrowth has been studied as function of ion fluence and substrate temperature. In particular, the light emitting properties possibly suitable for optoelectronic devices have been investigated by measuring cathodoluminescence spectra for implantation temperatures from 300 to 1223 K and for analyzing temperatures from 10-300 K. Rutherford backscattering channeling analysis showed that the Ge implantation produced amorphous layers varying in depth with temperature. At a fluence of 7x1014 Ge-ions/cm2 and an implantation temperature of 1073 K, Ge implantation is accompanied by a strong increase in the luminescence intensity of a violet band, which we associate with Ge-related defects or Ge clusters. This violet band is very stable and has a long lifetime of 6 μs. All the other bands observed are connected to known oxygen defect centers in the SiO2 network

  3. Quantifying hydrogen peroxide in iron-containing solutions using leuco crystal violet

    Directory of Open Access Journals (Sweden)

    Schoonen Martin A

    2005-06-01

    Full Text Available Hydrogen peroxide is present in many natural waters and wastewaters. In the presence of Fe(II, this species decomposes to form hydroxyl radicals, that are extremely reactive. Hence, in the presence of Fe(II, hydrogen peroxide is difficult to detect because of its short lifetime. Here, we show an expanded use of a hydrogen peroxide quantification technique using leuco crystal violet (LCV for solutions of varying pH and iron concentration. In the presence of the biocatalyst peroxidase, LCV is oxidized by hydrogen peroxide, forming a colored crystal violet ion (CV+, which is stable for days. The LCV method uses standard equipment and allows for detection at the low microM concentration level. Results show strong pH dependence with maximum LCV oxidation at pH 4.23. By chelating dissolved Fe(II with EDTA, hydrogen peroxide can be stabilized for analysis. Results are presented for hydrogen peroxide quantification in pyrite–water slurries. Pyrite–water slurries show surface area dependent generation of hydrogen peroxide only in the presence of EDTA, which chelates dissolved Fe(II. Given the stability of CV+, this method is particularly useful for field work that involves the detection of hydrogen peroxide.

  4. Studies on adsorption of crystal violet dye from aqueous solution onto coniferous pinus bark powder (CPBP)

    International Nuclear Information System (INIS)

    The present study shows that the coniferous pinus bark powder (CPBP) can be used as a potential adsorbent for the removal of crystal violet (basic dye) from aqueous solutions. Experiments were carried out as a function of contact time, concentration, temperature, pH and dosage. The amount of dye uptake was found to vary with increasing initial solution pH and maximum adsorption was observed at pH 8. The equilibrium was attained in 2 h. The amount of dye uptake (mg/g) was found to increase with increase in dye concentration and contact time. The % adsorption was found to decrease with increase in amount of adsorbent. The thermodynamic parameters were also calculated and the positive value of ΔHo indicates the endothermic nature of adsorption. The applicability of the three isotherm's model for the present data follows the order: Langmuir > Temkin > Freundlich. The kinetics of crystal violet on to the adsorbent can be described well by pseudo-second order > Elovich > pseudo-first order equation.

  5. An analysis on effecting factors of ultra-violet imaging appliance in corona discharge

    Science.gov (United States)

    Han, Xiao; Yang, Ning; Yuan, Shuai; Bi, Jiangang

    2014-11-01

    In this paper, the operating principle of daylight UV imagers was introduced first, emphasizing the SBUV(solar blind UV) technology, which utilizes the fact that ultra violet between 240nm~280nm is being absorbed by the ozone so that signals detected on earth in this spectral range originate on earth. And then several influencing factors were explained, including observation distance, observing angle, imager gain settings and environmental conditions. Experimental data measured in the UHV(ultra high-voltage) DC converter station in Changzhi, Shanxi, China were analyzed using SRA(single regression analysis) method, and mathematical equations with acceptable deviation were calculated, with simulating curves plotted. The results show that environmental conditions including humidity and temperature, observation distance and imager gain settings all contribute to the measuring result, exhibiting as exponential function and convex function respectively. Concluded from the above analysis and calculation, observing conditions of a clear observing angle at the same observation distance with mediate gain settings on days of low humidity were recommended. This conclusion may guide further ultra-violet imaging appliance in high-voltage electrical devices corona discharge sensing.

  6. Toward the Extreme Ultra Violet Four Wave Mixing Experiments: From Table Top Lasers to Fourth Generation Light Sources

    Directory of Open Access Journals (Sweden)

    Riccardo Cucini

    2015-01-01

    Full Text Available Three different Transient Grating setups are presented, with pulsed and continuous wave probe at different wavelengths, ranging from infrared to the extreme ultra violet region. Both heterodyne and homodyne detections are considered. Each scheme introduces variations with respect to the previous one, allowing moving from classical table top laser experiments towards a new four wave mixing scheme based on free electron laser radiation. A comparison between the various setups and the first results from extreme ultra violet transient grating experiments is also discussed.

  7. Study on laser-cladding Ni-Al-WC alloy layer on the surface of chrome cast iron and alloy layer's micro-structure and properties

    International Nuclear Information System (INIS)

    Laser-cladding Ni-Al-WC alloy layer on the surface of chrome cast iron and alloy layer's micro-structure and properties are studied. The chemical composition, the phase structure, the average micro-hardness, the wear resistance and the corrosion resistance are analyzed for the Ni-Al-WC and the matrix, respectively. The results show that the metallurgical combination is achieved between the spray alloy layer and the surface of chrome cast iron, the chemical composition and micro-structure in the surface layer of the specimen are changed basically, and the micro-hardness, the wear resistance, the corrosion resistance in the surface layer are increased with a large range

  8. More than 50% reduction of wear in polyethylene liners with alumina heads compared to cobalt-chrome heads in hip replacements

    OpenAIRE

    Dahl, Jon; Snorrason, Finnur; Nordsletten, Lars; Röhrl, Stephan M

    2013-01-01

    Background and purpose Excessive wear of acetabular liners in hip replacements may lead to osteolysis and cup loosening. Different head materials are currently used. We measured differences in wear between alumina and cobalt-chrome heads with the same polyethylene liner. Patients and methods 39 patients (43 hips) with osteoarthritis were included in a study with 10-year follow-up. Wear was measured as proximal and 3D penetration of the head in the liner with radiostereometry (RSA). All the pa...

  9. Generation-channel interference of high-order harmonics of an anharmonic oscillator driven by bi-chrome laser fields and its mechanism

    International Nuclear Information System (INIS)

    A method to describe the generation channels of high-order harmonics is proposed. According to this method, the mechanism of generation-channel interference of high-order harmonics is revealed clearly. We take the anharmonic oscillator driven by bi-chrome fields as an example to illustrate that this method can be used to understand the effect of generation-channel interference. (atomic and molecular physics)

  10. 75 FR 25840 - Carbazole Violet Pigment 23 from the People's Republic of China: Extension of Time Limit for the...

    Science.gov (United States)

    2010-05-10

    ... Antidumping Duty Administrative Review, 74 FR 68780 (December 29, 2009) (Preliminary Results). The final... the Tariff Act of 1930, As Amended, 70 FR 24533 (May 10, 2005). This notice is published in accordance... International Trade Administration Carbazole Violet Pigment 23 from the People's Republic of China: Extension...

  11. 75 FR 36630 - Carbazole Violet Pigment 23 from the People's Republic of China: Final Results of Antidumping...

    Science.gov (United States)

    2010-06-28

    ... Administrative Review, 74 FR ] 68780 (December 29, 2009) (Preliminary Results). This administrative review covers...: Extension of Time Limit for the Final Results of Antidumping Duty Administrative Review, 75 FR 25840 (May 10... International Trade Administration A-570-892 Carbazole Violet Pigment 23 from the People's Republic of...

  12. 75 FR 13257 - Carbazole Violet Pigment 23 from India: Final Results of the Expedited Five-year (Sunset) Review...

    Science.gov (United States)

    2010-03-19

    ... Pigment 23 (CVP-23) ] from India pursuant to section 751(c) of the Tariff Act of 1930, as amended (the Act). See Initiation of Five-year (Sunset) Review, 74 FR 56593 (November 2, 2009) (Initiation Notice). On... International Trade Administration Carbazole Violet Pigment 23 from India: Final Results of the Expedited...

  13. 75 FR 10759 - Carbazole Violet Pigment 23 from India: Initiation of Antidumping Duty Changed-Circumstances Review

    Science.gov (United States)

    2010-03-09

    ... and Antidumping Duty Order: Carbazole Violet Pigment 23 From India, 69 FR 77988 (December 29, 2004... Order, Finding, or Suspended Investigation; Opportunity To Request Administrative Review, 74 FR 62743... Revocation in Part, and Deferral of Initiation of Administrative Review, 75 FR 4770 (January 29, 2010)....

  14. 75 FR 12497 - Carbazole Violet Pigment 23 from India and the People's Republic of China: Final Results of the...

    Science.gov (United States)

    2010-03-16

    ... China, 69 FR 77987 (December 29, 2004); Notice of Amended Final Determination of Sales at Less Than Fair Value and Antidumping Duty Order: Carbazole Violet Pigment 23 From India, 69 FR 77988 (December 29, 2004... 1930, as amended (the Act). See Initiation of Five-Year (``Sunset'') Review, 74 FR 56593 (November...

  15. 75 FR 62765 - Carbazole Violet Pigment 23 From India: Final Results of Antidumping Duty Changed-Circumstances...

    Science.gov (United States)

    2010-10-13

    ...-Circumstances Review, 75 FR 52930 (August 30, 2010). Although we gave interested parties an opportunity to... Antidumping Duty Administrative Review, 75 FR 38076 (July 1, 2010). Notification This notice serves as a... International Trade Administration Carbazole Violet Pigment 23 From India: Final Results of Antidumping...

  16. 77 FR 1463 - Carbazole Violet Pigment 23 From the People's Republic of China: Final Rescission of Antidumping...

    Science.gov (United States)

    2012-01-10

    ... Duty Administrative Review, 76 FR 55003 (September 6, 2011) (Preliminary Results). DATES: Effective... People's Republic of China: Rescission of Antidumping Duty Administrative Review, 76 FR 53408 (August 26... International Trade Administration Carbazole Violet Pigment 23 From the People's Republic of China:...

  17. Molecularly Imprinted Polymers for Selective Extraction of Crystal Violet from Natural Seawater coupled with High- Performance Liquid Chromatographic Determination

    Institute of Scientific and Technical Information of China (English)

    LIAN Ziru; WANG Jiangtao

    2014-01-01

    Molecularly imprinted polymers (MIPs) were prepared by the bulk polymerization using crystal violet as the template molecule, and the methacrylic acid and ethylene glycol dimetheacrylate as functional monomer and cross-linker, respectively. Sys-tematic investigations of synthetic conditions were conducted. The surface morphology and recognition mechanism of the obtained polymers were studied using scanning electron microscope and spectrophotometric analysis. MIPs showed high affinity to template molecule and were successfully applied as special solid-phase extraction sorbent for selective extraction of crystal violet from natural seawater. An off-line molecularly imprinted solid-phase extraction (MISPE) method followed by high-performance liquid chroma-tography with diodearray detection for the analysis of crystal violet was also established. MISPE columns have good recoveries for crystal violet standard solutions and good linearity was obtained over the concentration range of 0-200μg L-1 (R2>0.99). Finally, two natural seawater samples were investigated. The recoveries of spiked seawater on the MISPE columns were from 44.47% to 62.34%, the relative standard deviation (n=3) being in the range of 2.89%-5.96%.

  18. Terrific Trichomes (and Other Specialised Cells) in African Violets: How to Get a Lot from One Plant in the Classroom

    Science.gov (United States)

    Cottrell, Vicki M.

    2013-01-01

    African violet (genus "Saintpaulia") was identified as a particularly suitable genus for the study of specialised plant cells in the classroom using microscopes. The techniques described here involve simple preparation without staining. The cells and structures that can be investigated include: trichomes (hairs); stomata; guard cells and…

  19. Anthocyanins, colour and antioxidant properties of eggplant (Solanum melongena L.) and violet pepper (Capsicum annuum L.) peel extracts.

    Science.gov (United States)

    Sadilova, Eva; Stintzing, Florian C; Carle, Reinhold

    2006-01-01

    Acetone extracts from eggplant (Solanum melongena L.) and violet pepper (Capsicum annuum L.) peels both belonging to the Solanaceae plant family were characterized with respect to their anthocyanin profiles, colour qualities and antioxidant capacities. According to HPLC-DAD-MS3 analyses the major anthocyanin in eggplant was delphinidin-3-rutinoside, while the predominant pigment in violet pepper was assigned to delphinidin-3-trans-coumaroylrutinoside-5-glucoside. Since virtually all anthocyanins were delphinidin-based, the effect of acylation and glycosylation patterns on colour stability and antioxidant capacity could be assessed. Application of two in vitro-assays for antioxidant capacity assessment revealed that eggplant generally exhibited higher values compared to violet pepper which was ascribed to 3,5-diglycosylated structures predominating in the latter. The higher extent of acylation in violet pepper was reflected by a more purplish colour shade of the extracts, but did not translate into a higher stability against fading which again was attributed to additional glycosyl substitution at C5. These findings support the relevance of structure-related activities of anthocyanins both for understanding food colour and their particular nutritional value. PMID:16989312

  20. Insight into biosorption equilibrium, kinetics and thermodynamics of crystal violet onto Ananas comosus (pineapple) leaf powder

    Science.gov (United States)

    Chakraborty, Sagnik; Chowdhury, Shamik; Saha, Papita Das

    2012-06-01

    Biosorption performance of pineapple leaf powder (PLP) for removal of crystal violet (CV) from its aqueous solutions was investigated. To this end, the influence of operational parameters such as pH, biosorbent dose, initial dye concentration and temperature were studied employing a batch experimental setup. The biosorption process followed the Langmuir isotherm model with high correlation coefficients ( R 2 > 0.99) at different temperatures. The maximum monolayer biosorption capacity was found to be 78.22 mg g-1 at 293 K. The kinetic data conformed to the pseudo-second-order kinetic model. The activation energy of the system was calculated as 58.96 kJ mol- 1 , indicating chemisorption nature of the ongoing biosorption process. A thermodynamic study showed spontaneous and exothermic nature of the biosorption process. Owing to its low cost and high dye uptake capacity, PLP has potential for application as biosorbent for removal of CV from aqueous solutions.

  1. Synthesis and characterisation of potassium polytitanate for photocatalytic degradation of crystal violet.

    Science.gov (United States)

    Shahid, Mohammad; El Saliby, Ibrahim; McDonagh, Andrew; Tijing, Leonard D; Kim, Jong-Ho; Shon, Ho Kyong

    2014-11-01

    Potassium titanate nanostructures were synthesised by hydrothermal treatment of TiO2 (P25) in KOH and H2O2. As-produced powders were characterised by scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, X-ray diffraction, and nitrogen adsorption-desorption methods. Longitudinally-oriented-wire-like structures with a length up to several micrometres and diameters ranging from 10 to 30 nm were obtained. Larger size fibrous nanowires resulting from the hydrothermal treatment showed high affinity in adsorbing crystal violet (CV), which was mainly due to their high surface area. The photocatalytic bleaching of CV solution revealed that the wires are photoactive under ultraviolet light irradiation. Macroporous nanowires are considered as effective adsorbents of CV, capable of photocatalytic degradation, and they can be easily separated from the solution by settling. PMID:25458691

  2. Preconcentrafion/separation and determination of mercury using microcrystalline phenolphthalein modified by ethyl violet

    Institute of Scientific and Technical Information of China (English)

    LI Ying; LI Quanrnin; OUYANG Ruizhuo

    2007-01-01

    A novel method was developed for enrichment and separation of trace mercury using phenolphthalein modified by ethyl violet (EV).The effects of different parameters,such as stirring time, various metal ions and salts,and the amounts of phenolphthalein, NH4SCN,and EV on the extraction rate of mercury were studied,to select the experimental conditions.Under optimum conditions,mercury can be adsorbed on the surface of microcrystalline phenolphthalein by the intermolecular action strength.The possible reaction mechanism for the enrichment of mercury was discussed in detail.Hg(Ⅱ)could be completely separated from Fe(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Mn(Ⅱ),Cd(Ⅱ),Cr(Ⅲ), and Al(Ⅲ) in the solution.The proposed method has been successfully applied to the determination of trace mercury in industrial wastewater with the recoveries 1.4%,1.1%,and1.2%,respectively.The analytical results were very satisfactory.

  3. Extreme Ultra-Violet Spectroscopy of the Lower Solar Atmosphere During Solar Flares (Invited Review)

    Science.gov (United States)

    Milligan, Ryan O.

    2015-12-01

    The extreme ultra-violet (EUV) portion of the solar spectrum contains a wealth of diagnostic tools for probing the lower solar atmosphere in response to an injection of energy, particularly during the impulsive phase of solar flares. These include temperature- and density-sensitive line ratios, Doppler-shifted emission lines, nonthermal broadening, abundance measurements, differential emission measure profiles, continuum temperatures and energetics, among others. In this article I review some of the recent advances that have been made using these techniques to infer physical properties of heated plasma at footpoint and ribbon locations during the initial stages of solar flares. I primarily focus on studies that have utilised spectroscopic EUV data from Hinode/EUV Imaging Spectrometer (EIS) and Solar Dynamics Observatory/EUV Variability Experiment (SDO/EVE), and I also provide some historical background and a summary of future spectroscopic instrumentation.

  4. Study of ionic associate of scandium rhodanide complex with crystalline violet

    International Nuclear Information System (INIS)

    Spectrophotometric method is used to study ionic associate of scandium rhodanide complex with crystal violet (CV). Optimal conditions for associate formation are: pH 2.5-2.8, 55000-60000-fold rhodanide excess and 4-5-fold CV in relation to scandium. Methods of isomolar series and equilibrium shift are used to determine that depending on rhodanide concentration associates in which scandium, rhodanide and CV are in the ratio 1:3:1 and 1:4:1 are formed. Molar extinction coefficient is 8.05x104. On the basis of studied reaction method of photometric determination of scandium microquantities in rare earth oxides is developed. The relative error of scandium determination is 2-4.5%

  5. Sensitive method for the spectrophotometric determination of boron in plants and waters using crystal violet

    International Nuclear Information System (INIS)

    A sensitive and rapid spectrophotometric method for the determination of boron is described, which is based on the formation of a blue complex at pH 1 to 2 between the anionic complex of boric acid with 2,6-dihydroxybenzoic acid and crystal violet; the colour is stabilised with poly(vinyl alcohol). At 600 nm the calibration graph is linear in the range 0.3 to 4.5 μg of boron per 25 ml of final solution with a relative standard deviation of +- 2.6% for 0.069 μg ml-1 of boron. The molar absorptivity is 3.75 x 104 l mol-1 cm-1. The method has been applied to the determination of boron in plants and natural waters. (author)

  6. A novel vacuum ultra violet lamp for metastable rare gas experiments

    CERN Document Server

    Daerr, Heiner; Sahling, Peter; Tippenhauer, Sandra; Arabi-Hashemi, Ariyan; Becker, Christoph; Sengstock, Klaus; Kalinowski, Martin B

    2011-01-01

    We report on a new design of a vacuum ultra violet (VUV) lamp for direct optical excitation of high laying atomic states e.g. for excitation of metastable rare gas atoms. The lamp can be directly mounted to ultra high vacuum vessels (p <= 10^(-10) mbar). It is driven by a 2.45 GHz microwave source. For optimum operation it requires powers of approximately 20 W. The VUV light is transmitted through a magnesium fluoride window, which is known to have a decreasing transmittance for VUV photons with time. In our special setup, after a run-time of the VUV lamp of 550 h the detected signal continuously decreased to 25 % of its initial value. This corresponds to a lifetime increase of two orders of magnitude compared to previous setups or commercial lamps.

  7. Tunable violet-blue emission from 3 C-SiC nanowires

    Science.gov (United States)

    Zhu, J.; Wu, H.; Chen, H. T.; Wu, X. L.; Xiong, X.

    2009-04-01

    Bulk quantities of straight and curled cubic silicon carbide nanowires (3 C-SiC NWs) are synthesized from the mixture of ZnS, Si, and C powders. The 3 C-SiC NWs are wrapped by amorphous SiO 2 shells with very thin thicknesses of less than 2.0 nm. The deionized water suspension of the as-made NWs shows a photoluminescence (PL) band centered at 548 nm, and a tunable violet-blue photoluminescence is observed as the excitation wavelength increases from 300 to 375 nm after the SiO 2 shell is removed. The PL band at 548 nm relates to the SiO 2 shell. Careful microstructural observation suggests that the tunable PL originates from the quantum confinement effect of 3 C-SiC nanocrystallites with sizes of several nm at the turning of the curled NWs.

  8. Utilization of cocoa pod husk waste as potential adsorbents for Remazol Brilliant Violet 5R removal

    International Nuclear Information System (INIS)

    Removal of Remazol Brilliant Violet 5R (RBV5R) dye from aqueous solution by adsorption onto activated carbon produced from cocoa pod husk (CPH) waste was investigated. Adsorption isotherms were derived at 30 degree Celsius on the basis of batch analysis. Isotherm data were treated according to Langmuir and Freundlich models. Kinetics of adsorption was followed by in situ UV-spectroscopy and the data were treated according to pseudo-first-order and pseudo-second-order models. The fits of experimental data to these equations were examined. It was found that the adsorption process by RVB5R dye onto activated carbon (AC) follows the Freundlich and pseudo-first-order model. (author)

  9. Plant regeneration from petiole and leaf of African violet (Saintpaulia ionantha Wendl. cultured in vitro

    Directory of Open Access Journals (Sweden)

    Wichada Sunpui

    2002-07-01

    Full Text Available A regeneration procedure was developed for in vitro grown African violet (Saintpaulia ionantha Wendl.. Adventitious shoot regeneration was compared among petioles, leaves and stems cultured on MS basal medium. High frequency regeneration was obtained from leaves and petioles supplemented with plant growth regulators (BA, KN, 2,4-D, and NAA. Regeneration media that induced the highest number of shoots in petiole explants was either MS medium supplemented with 3 mg/l BA alone or 1 mg/l NAA plus 3 mg/l BA. Adventitious shoots were also regenerated from callus that was derived from leaf explants cultured on MS medium containing several concentrations of TDZ. Callus induced on medium with 0.5 mg/l TDZ showed the best shoot induction. Regenerated shoots could be rooted on 1/2 MS medium or MS medium supplemented with 3 mg/l IBA. Complete plantlets were acclimatized and successfully transplanted to glasshouse conditions.

  10. Application of ultra-violet spectrophotometry and gel permeation chromatography to the characterization of landfill leachates

    International Nuclear Information System (INIS)

    Twenty-five landfill leachates were subjected to physico-chemical analyses, UV spectrophotometry and gel permeation chromatography (GPC). Ultra-violet (UV) spectra of GPC fractions were acquired and compared to corresponding landfill leachate spectra. UV spectra of landfill leachates reflect the origin (household refuse or industrial wastes) of the samples and absorbance is to some extent linked to their polluting load. GPC chromatograms (absorbance at 220 and 260 nm of GPC fractions) show different zones corresponding to various compounds; the analysis of the UV spectrum of GPC fractions shows the existence of three main types of compounds for leachates from municipal solid wastes landfills. Leachates from industrial wastes landfills and their GPC fractions are characterized by specific spectra due to supernumerary compounds. Our results should be completed by analysis on more samples, but they show that UV absorptiometry is a promising tool for characterizing landfill leachates. (author)

  11. Techniques for the Improvement of Plastics by Ultra-Violet Light

    International Nuclear Information System (INIS)

    The use of ultraviolet light for crosslinking and surface grafting of polymers is described. It is pointed out that the energy emission from a small ultra- violet lamp is at least as great as that from a large accelerating machine and that that therefore the cost of irradiation using ultraviolet light should be quite low. The polymers are sensitised by the addition of certain carbonyl compounds such as benzophenone. It is found that the crosslinking of polyethylene in the presence of sensitisers gives a material having greatly improved tensile strength at elevated temperatures. Surface grafting of polyethylene with acrylamide was also carried out. The advantages of the technique lie in cost, speed and safety although lack of penetration may limit its use to thin films. (author)

  12. Detection of biological warfare agents using ultra violet-laser induced fluorescence LIDAR

    Science.gov (United States)

    Joshi, Deepti; Kumar, Deepak; Maini, Anil K.; Sharma, Ramesh C.

    This review has been written to highlight the threat of biological warfare agents, their types and detection. Bacterial biological agent Bacillus anthracis (bacteria causing the disease anthrax) which is most likely to be employed in biological warfare is being discussed in detail. Standoff detection of biological warfare agents in aerosol form using Ultra violet-Laser Induced Fluorescence (UV-LIF) spectroscopy method has been studied. Range-resolved detection and identification of biological aerosols by both nano-second and non-linear femto-second LIDAR is also discussed. Calculated received fluorescence signal for a cloud of typical biological agent Bacillus globigii (Simulants of B. anthracis) at a location of ˜5.0 km at different concentrations in presence of solar background radiation has been described. Overview of current research efforts in internationally available working UV-LIF LIDAR systems are also mentioned briefly.

  13. Time-energy properties of an attosecond extreme ultra-violet pulse

    International Nuclear Information System (INIS)

    The time-energy properties of high-order harmonic generation (HHG) are calculated for a linearly polarized 7-fs laser pulse with different carrier-envelope phases (CEPs). The quantum trajectory paths that contribute to an as (1 as=10−18 s) pulse in HHG are identified. The laser-duration dependence and the CEP dependence of HHG energy property are investigated. The study shows that an as extreme ultra-violet (XUV) pulse can be selected from HHG spectrum near cut-off energy with a bandpass optical filter. The theoretical prediction of the pulse duration is proportional to bandwidth. Analysis suggests that a measured narrowband as XUV pulse may consist of instantaneous shorter pulses each dependent on laser pulse duration, intensity, and CEP. These information can be used as references for producing, selecting, improving and manipulating (timing) as pulses. (atomic and molecular physics)

  14. Study on the violet LED-induced fluorescence spectra of thioredoxin reductase from human brain

    Institute of Scientific and Technical Information of China (English)

    Xiufeng Lan(兰秀风); Tao Yang(杨涛); Shumei Gao(高淑梅); Xiaosen Luo(骆晓森); Zhonghua Shen(沈中华); Jian Lu(陆建); Xiaowu Ni(倪晓武); Lin Xu(许琳)

    2003-01-01

    The technique of fluorescence spectroscopy is applied to study thioredoxin reductase (TrxR) in the ce;lsof human brain. Experimental results show that, by the violet light emitting diode (LED, λmax=407 nm)light irradiation, TrxR is able to emit three striking spectral bands (528 - 582 nm; 588 - 660 nm; 683 - 700nm). The fluorescence intensity is linear to the concentration of TrxR. The spectrum of denatured TrxR israther different from that of organized TrxR, which reflects the structure change between denatured TrxRand organized TrxR. Furthermore, physical and biochemical mechanisms of fluorescence production forLED light-induced TrxR spectra and its characteristics are analyzed. This paper may be useful to betterunderstand the structure of TrxR, and to provide new spectroscopic information to improve the resolutionfor this kind of biology structure.

  15. Controlled blue-violet photonic emission from human bodies by will in healing Qi Practice

    International Nuclear Information System (INIS)

    Photon emission from living bodies is one of the most interesting fields usually called as bioluminescence, including the study on firefly, jellyfish and the like. But, almost nothing is known about the emission possibility of human body, except the thermal infrared radiation. However, we have encountered signals from a photomultiplier tube (PMT) corresponding to emissions around blue-violet light during the holistic heeling practices such as qi (ch'i, qi-gong). Intensities of PMT output in the near-ultraviolet to visible regime (280-650 nm) have been observed to be modulated in on-off and oscillatory manners, responding to the call from outside the darkroom. The maximum signal intensity corresponds to emission of 3800 photons per mm2 per second, may be equivalent to 1 photoprotein about 5000 molecular sites at the palm, crudely assuming a simple special spreading of the emission towards the detector. (author)

  16. Decolorization of reactive violet 5 dye in textile wastewater by electrocoagulation

    Directory of Open Access Journals (Sweden)

    Borislav N. Malinovic

    2016-04-01

    Full Text Available The textile dyeing industry consumes large quantities of water and produces large volumes of wastewater from different steps in the dyeing and finishing processes. Wastewater from printing and dyeing units is often rich in color, containing residues of reactive dyes and chemicals, such as complex components. This study investigates the decolorization of synthetic dye wastewater containing textile dye Reactive Violet 5 (RV5 by electrocoagulation. A laboratory batch reactor was used to investigate the effect of various operating parameters using aluminium (Al, iron (Fe and stainless steel (SS anode. The effect of dye concentration, current density, supporting electrolyte, sup­porting electrolyte concentration, electrolysis duration, and material of anode of the systems were evaluated. Color removal efficiency was 22, 91.5 and 99.8 % in 15 minutes using Al, Fe and SS anode, respectively (j = 10 mA/cm2, cNaCl = 0.171 M.

  17. Removal of Basic Violet 14 from aqueous solution using sulphuric acid activated materials.

    Science.gov (United States)

    Suresh, S

    2016-01-01

    In this study the adsorption of Basic Violet, 14 from aqueous solution onto sulphuric acid activated materials prepared from Calophyllum inophyllum (CS) and Theobroma cacao (TS) shells were investigated. The experimental data were analysed by Langmuir, Freundlich and Temkin isotherm models. The results showed that CS has a superior adsorption capacity compared to the TS. The adsorption capacity was found to be 1416.43 mg/g for CS and 980.39 mg/g for TS. The kinetic data results at different concentrations were analysed using pseudo first-order and pseudo-second order model. Boyd plot indicates that the dye adsorption onto CS and TS is controlled by film diffusion. The adsorbents were characterised by scanning electron microscopy. The materials used in this study were economical waste products and hence can be an attractive alternative to costlier adsorbents for dye removal in industrial wastewater treatment processes. PMID:27330899

  18. Radiochromic leuco dye micelle hydrogels: II. Low diffusion rate leuco crystal violet gel

    Energy Technology Data Exchange (ETDEWEB)

    Babic, Steven; Battista, Jerry; Jordan, Kevin [Department of Physics and Engineering, London Regional Cancer Program at London Health Sciences Centre, 790 Commissioners Road East, London, Ontario, N6A 4L6 (Canada)

    2009-11-21

    Radiation-sensitive hydrogels offer the capability of verifying intricate dose distributions in three-dimensional (3D) space conveniently in a single measurement with sub-millimetre spatial resolution. In this study, a new radiochromic hydrogel called leuco crystal violet (LCV) micelle gel is introduced. Upon irradiation, LCV converts to crystal violet (CV{sup +}). Triton X-100 micelles are used to provide the required hybrid-interfacing environment to dissolve LCV. The diffusion coefficient of the LCV gel has been measured to be 0.036 {+-} 0.001 mm{sup 2} h{sup -1}, which is a factor of 25 times less than the standard radiochromic ferrous xylenol-orange (FX) gel; LCV gels without Triton X-100 micelles have a diffusion coefficient of 0.33 {+-} 0.02 mm{sup 2} h{sup -1}. The LCV gel formulation contains: 1 mM LCV, 25 mM trichloroacetic acid, 4 mM Triton X-100 and 4% w/w gelatin. The primary innovative feature of this 3D hydrogel is that the radiation-induced CV{sup +} dye is more soluble in the Triton X-100 micelles than in the surrounding water which consequently leads to more stable post-irradiation dose distributions. A dosimetric characterization revealed that the dose response is reproducible to within 1% over three separate batches, independent of energy, dose rate and dose fractionation but is affected by the temperature ({approx}4% per deg. C) during irradiation. LCV micelle gels scanned optically with a yellow light source are a promising system for 3D dose verification. They may prove to be, especially, useful for scanning large volume dosimeters (i.e. 20 cm) since they are easily manufactured, transparent and near colourless prior to irradiation.

  19. Surface microstructural features of scales in relation to toxic stress of Basic Violet-1.

    Science.gov (United States)

    Kaur, Kirandeep; Kaur, Ramandeep; Kaur, Arvinder

    2016-01-01

    The present work deals with scanning electron microscopic (SEM) studies of the scales of Labeo rohita on exposure to lethal and sublethal doses of Basic Violet-1 (an important textile and hair colorant). The dye induced loosening of the scales and caused breakage and disorganization of lepidonts. Erosion of lepidonts occurred mostly in the fish exposed to 0.20 and 0.40 mg/L dye, during acute exposure and to 0.0225 and 0.045 mg/L dye, during the subchronic exposure. However, lepidonts were sloughed off from their sockets in 0.60 and 0.80 mg/L dye during acute exposure and in 0.09 mg/L dye during the subchronic exposure. Circuli, the base that provides anchorage to the lepidonts, got damaged, and tubercles responsible for coloration of a fish became atrophied with an increase in the duration of exposure. The results of the present investigation clearly indicated that exposure to Basic Violet-1 (BV-1) even at a concentration as low as 0.0225 mg was responsible for deleterious changes in the scale morphology of the test fish after 150 days of exposure. Similar changes were observed in the scales of the dead fish also. It can thus be suggested that this noninvasive technique is very helpful for evaluating the health status of an aquatic body. At the same time, the changes in ultramorphology of scales can act as an early indicator of the stress of very minute doses of dyes and even the scales of a dead fish can act as indicators of the untoward changes that would have occurred in the environment of the fish before death. PMID:26432273

  20. A comparison of Staphylococcus aureus biofilm formation on cobalt-chrome and titanium-alloy spinal implants.

    Science.gov (United States)

    Patel, Shalin S; Aruni, Wilson; Inceoglu, Serkan; Akpolat, Yusuf T; Botimer, Gary D; Cheng, Wayne K; Danisa, Olumide A

    2016-09-01

    The use of cobalt chrome (CoCr) implants in spinal surgery has become increasingly popular. However, there have been no studies specifically comparing biofilm formation on CoCr with that of titanium-alloy spinal implants. The objective of this study was to compare the difference in propensity for biofilm formation between these two materials, as it specifically relates to spinal rods. Staphylococcus aureus subsp. Aureus (ATCC 6538) were incubated with two different types of spinal rods composed of either CoCr or titanium-alloy. The spinal rods were then subject to a trypsin wash to allow for isolation of the colonized organism and associated biofilms. The associated optical density values (OD) from the bacterial isolates were obtained and the bacterial solutions were plated on brain-heart infusion agar plates and the resultant colony-forming units (CFU) were counted. The OD values for the titanium-alloy rods were 1.105±0.096nm (mean±SD) and 1.040±0.026nm at 48hours and 96hours, respectively. In contrast, the OD values for the CoCr rods were 1.332±0.161nm and 1.115±0.207nm at 48 and 96hours, respectively (pbiofilm formation compared to titanium-alloy implants. PMID:27396378

  1. Indirect extraction-spectrophotometric determination of 2-(thiocyanomethylthiol)benzothiazole in chrome tanning liquors after its breakdown to 2-mercaptobenzothiazole.

    Science.gov (United States)

    Hinojosa Reyes, Laura; Wróbel, Katarzyna; Wróbel, Kazimierz

    2002-03-01

    The simple extraction-spectrophotometric procedure is proposed in this work for the determination of 2-(thiocyanomethylthiol)benzothiazole (TCMTB) in chrome tanning liquors after its breakdown to 2-mercaptobenzothiazole (MBT). The sample (50mul) was 4-fold diluted with deionized water and the conversion of TCMTB to MBT was obtained with cysteine (400 mul, 0.1 moll(-1)) in alkaline conditions (pH 10). After acidification to pH 2.5 (100 mul phosphoric acid, 2 moll(-1)), the extraction was carried out with 800 mul of ethyl acetate, containing 0.2% of beta-mercaptoethanol and absorbance was measured at 324 nm with the cut-off filter 295 nm. To avoid possible errors due to MBT presence in the sample, this same sample was taken for blank, but the reagents were added in form of one acid solution (omitting the conversion step). The calibration range was 10-120 mugml(-1) of TCMTB with the regression coefficient 0.9999, the quantitation limit was 2.80 mugml(-1) and the within day precision was 3.34 and 0.20%, respectively, for 10 and for 100 mugml(-1) of TCMTB. The results obtained in the analysis of the three industrial liquor samples by the proposed procedure were in a good agreement with the results obtained using liquid chromatography method. PMID:18968524

  2. A review on management of chrome-tanned leather shavings: a holistic paradigm to combat the environmental issues.

    Science.gov (United States)

    Pati, Anupama; Chaudhary, Rubina; Subramani, Saravanabhavan

    2014-10-01

    Raw hide/skins come to the tanners as a by-product of meat industry which is converted into value-added leather as product for fashion market. Leather manufacturing is a chemical process of natural biological matrix. It employs a huge quantity of water and inorganic and organic chemicals for processing and thereby discharges solid and liquid wastes into the environment. One of the potential solid wastes generated from leather industry is chrome-tanned leather shavings (CTLSs), and its disposal is increasingly becoming a huge challenge on disposal to tanners due to presence of heavy metal chromium. Hence, finding a sustainable solution to the CTLS disposal problem is a prime challenge for global tanners and researchers. This paper aims to the deeper review of various disposal methods on CTLS such as protein, chromium, and energy recovery processes and its utilization methodologies. Sustainable technologies have been developed to overcome CTLS solid wastes emanating from leather processing operations. Further, this review paper brings a broader classification of developed methodologies for treatment of CTLSs. PMID:24906828

  3. Polarographic and voltammetric study of the Sc(III)-acid chrome blue K complex and determination of trace scandium

    International Nuclear Information System (INIS)

    A new system using a polarographic adsorptive wave for determining trace scandium was proposed. In 0.2 mol/L NH4OAc, the Sc(III)-ACBK [1,8-dihydroxy-2-(2-hydroxy-5-sulfo-1-phenylazo)-3,6-disulfo-naphthalene, called acid chrome blue K] complex emerged a sensitive adsorptive complex wave (Ep' = -0.67V). The molar ratio of Sc(III) to ACBK in the complex was established as 1:2 and the apparent stability constant β2 = 2.7 x 1015. But for Y(III), the molar ratio was 1:1 and β=1.5 x 105. Because of the particularity of Sc complex, the sensitivity and the selectivity of determination Sc is much better than that of other rare earth ions. The detection limits is 1.1 x 10-7 mol/L for oscillopolarography and 2.0 x 10-8 mol/L for adsorptive stripping voltammetry

  4. Thermal behaviour of chrome shavings and of sludges recovered after digestion of tanned solid wastes with calcium hydroxide

    International Nuclear Information System (INIS)

    The thermal behaviour of chrome shavings and of sludges recovered after digestion of tanned wastes with Ca(OH)2 was studied. Ashes obtained after incineration of wastes at various temperatures were analysed by X-ray diffraction and EDX method. The main crystallized phases present in the ash obtained at 600 deg. C are Cr2O3 and NaCl. The diffractograms revealed an increase in the intensities of the chromium oxide peaks and a very notable decrease of the amount of sodium chloride at 1100 deg. C. EDX analysis revealed a total disappearance of the chlorine peak at this temperature. Scanning electron micrographs show that the waste lost its fibrous aspect when the temperature increases. Formation of aggregates was noted after 550 deg. C. Combustion of organic matters and decarbonation phenomenon are the main stages observed on GTA and DTA curves of sludges. These phenomena are, respectively, exothermic and endothermic. The diffractogram of sludges recorded at 550 deg. C, in the presence of a constant oxygen surplus, revealed the presence of CaCrO4 and CaCO3

  5. Spectrophotometric determination of lanthanoids and yttrium by flow injection analysis using Chrome Azurol S in the presence of cationic surfactants

    International Nuclear Information System (INIS)

    Solution of lanthanides (La, Ce, Pr, Nd, Tb, Ho, Sm, Er, Eu, Gd, Dy, Yb) and yttrium were prepared for experiments at concentrations of 0.01M. The interaction was studied of lanthanides and yttrium with Chrome Azurol S (CAS) in the presence of cationic surfactants CTMAB (hexadecyltrimethylammonium bromide), CPB (hexadecylpyridium bromide). Absorption spectra were measured of the system La/III/-CAS-CTMAB for different pH values (from 7.8 to 10.11) and different concentrations of La/III/. The dependence was defined of absorbance on pH for the system La/III/-CAS-CTMAB for different CTMAB concentrations. Absorption spectra were similarly measured of the La/III/-CAS-CPB system at different La/III/ concentrations and the dependence of absorption was measured on pH for La/III/-CAS-CPB for different CPB concentrations. A detailed description is presented of optimal experimental conditions and the results are discussed of all measured dependences. (E.S.). 8 figs., 1 tab., 19 refs

  6. Investigation of a modified gallocyanin chrome alum staining technique in cytology compared to thionine and haematoxylin as nuclear stains.

    Science.gov (United States)

    Schulte, E

    1988-01-01

    The present paper describes the staining characteristics of a modified Gallocyanin-chrome alum stain as compared to the original gallocyanin stain. Thionine, haematoxylin and the Feulgen reaction were used as controls. Tissue imprints of rabbit liver and spleen and smears of human venous blood were stained and controlled microscopically. Nuclear extinction was measured with the image analysis system IBAS 2000. Both GCA variants were examined by spectrophotometry and thin layer chromatography. The most striking difference between the GCA variants is the short staining time required for the modified stain (4 min) as compared to the original method (24 h). Both stains are stoichiometric for nucleic acids; the staining pattern, hue and intensity of nuclear colour and spectrophotometric and chromatographic data were absolutely consistent for both GCA-stains. These results and preliminary data from the analysis of the structure of the dye molecules seem to indicate that the molecular structure of the modified GCA is not changed by treatment with concentrated sulphuric acid. Differences in the staining kinetics might be due to differences in solubility. As nuclear chromatin texture after GCA staining is well appropriate for computerized image analysis the modified GCA-stain can be recommended as a simple and reproducible nuclear stain for automated feature extraction in cytology. PMID:2471227

  7. Experimental Investigation of Erosive Wear on the High Chrome Cast Iron Impeller of Slurry Disposal Pump Using Response Surface Methodology

    Directory of Open Access Journals (Sweden)

    Sunil Kumar

    2012-05-01

    Full Text Available Erosive wear occurs on the impeller and volute casing of the slurry disposal pump due to the impact of the ash particles on the impeller with a high velocity. Due to erosive wear, pump life become very short. The service life of centrifugal pump, handling slurry can be increased by reducing the erosive wear. In the present work, the experimental investigation of erosive wear has been carried out on the high speed slurry erosion tester to understand the effects of the ash concentration in slurry, rotational speed of the pump impeller and ash particle size on erosive wear. The erosive wear behavior of high chrome cast iron was investigated by Response surface methodology (RSM. Analysis of variance (ANOVA was used for statistical analysis and the modeled values for the response were obtained with the help of modeled equation. The result shows that the ash concentration in slurry and kinetic energy of the moving particles highly contributes to erosive wear of pump impeller as compared to the ash particle size.

  8. EXPERIMENTAL INVESTIGATION OF EROSIVE WEAR ON THE HIGH CHROME CAST IRON IMPELLER OF SLURRY DISPOSAL PUMP USING RESPONSE SURFACE METHODOLOGY

    Directory of Open Access Journals (Sweden)

    Jasbir Singh Ratol

    2012-07-01

    Full Text Available Erosive wear occurs on the impeller and volute casing of the slurry disposal pump due to the impact of the ash particles on the impeller with a high velocity. Due to erosive wear, pump life become very short. The service life of centrifugal pump, handling slurry can be increased by reducing the erosive wear. In the present work, the experimental investigation of erosive wear has been carried out on the high speed slurry erosion tester to understand the effects of the ash concentration in slurry, rotational speed of the pump impeller and ash particle size on erosive wear. The erosive wear behaviour of high chrome cast iron was investigated by Response surface methodology (RSM. Analysis of variance (ANOVA was used for statistical analysis and the modeled values for the response were obtained with the help of modeled equation. The result shows that the ash concentration in slurry and kinetic energy of the moving particles highly contributes to erosive wear of pump impeller as compared to the ash particle size.

  9. Kinetic Spectrophotometric Determination of Trace Titanium(Ⅳ) Based on Oxidation Discoloration of Acid Chrome Blue K with Hydrogen Peroxide

    Institute of Scientific and Technical Information of China (English)

    XIONG Yan; ZHOU Zhi-rong; WU Fu-hai

    2007-01-01

    A simple and sensitive kinetic spectrophotometric method for the determination of trace amounts of titanium(IV), based upon the catalytic effect of Ti(IV) on the oxidation of acid chrome blue K (ACBK) by hydrogen peroxide in 0.002 mol/L sulfuric acid, is described. The reaction rate is monitored spectrophotometrically by measuring the decrease in absorbance of ACBK at 524 nm. The detection limit of the method is 1.01×10-9 g/mL, and the linear range is 0-0.048 mg/L. The influence of acidity, concentration of reactants, reaction time, reaction temperature and for-eign ions is also discussed. The optimum reaction conditions were established and some kinetic parameters determined. The apparent activation energy of the catalytic reaction is 5.32 kJ/mol. The relative standard deviation for the determi-nation of titanium(IV) at the concentration of 0.048 mg/L is calculated to be 1.31% (n = 11). In combination with sol-vent extraction separation, the method has been successfully applied to the determination of trace titanium(IV) in human hair, plant matter, tea and rock samples. The results are in good agreement with the certified values with the relative standard deviations (RSD) of 1.4%-3.5%.

  10. Adsorption of Methyl Violet and Brilliant Blue onto Poly(vinyl alcohol) Membranes Grafted with N-Vinyl imidazol / Acrylic Acid

    International Nuclear Information System (INIS)

    Poly(vinyl alcohol) films were grafted with two monomers using gamma radiation, acrylic acid and N-vinyl imidazole. The ability of these membranes for the adsorption of methyl violet and brilliant blue has been investigated. The data show that untreated or alkali treated membranes adsorb methyl violet; but they did not absorb brilliant blue. In contrast, acidic treated membranes do adsorb brilliant blue, and did not adsorb methyl violet. This indicates that these membranes could be used for the separation of both dyes. Also it was found that the dye uptake increases with increasing the degree of grafting

  11. Measuring the Photocatalytic Breakdown of Crystal Violet Dye using a Light Emitting Diode Approach

    Science.gov (United States)

    Ryan, Robert E.; Underwood, Lauren W.; O'Neal, Duane; Pagnutti, Mary; Davis, Bruce A.

    2009-01-01

    A simple method to estimate the photocatalytic reactivity performance of spray-on titanium dioxide coatings for transmissive glass surfaces was developed. This novel technique provides a standardized method to evaluate the efficiency of photocatalytic material systems over a variety of illumination levels. To date, photocatalysis assessments have generally been conducted using mercury black light lamps. Illumination levels for these types of lamps are difficult to vary, consequently limiting their use for assessing material performance under a diverse range of simulated environmental conditions. This new technique uses an ultraviolet (UV) gallium nitride (GaN) light emitting diode (LED) array instead of a traditional black light to initiate and sustain photocatalytic breakdown. This method was tested with a UV-resistant dye (crystal violet) applied to a titanium dioxide coated glass slide. Experimental control is accomplished by applying crystal violet to both titanium dioxide coated slides and uncoated control slides. A slide is illuminated by the UV LED array, at various light levels representative of outdoor and indoor conditions, from the dye side of the slide. To monitor degradation of the dye over time, a temperature-stabilized white light LED, whose emission spectrum overlaps with the dye absorption spectrum, is used to illuminate the opposite side of the slide. Using a spectrometer, the amount of light from the white light LED transmitted through the slide as the dye degrades is monitored as a function of wavelength and time and is subsequently analyzed. In this way, the rate of degradation for photocatalytically coated versus uncoated slide surfaces can be compared. Results demonstrate that the dye absorption decreased much more rapidly on the photocatalytically coated slides than on the control uncoated slides, and that dye degradation is dependent on illumination level. For photocatalytic activity assessment purposes, this experimental configuration and

  12. Studies on the optimum flotation system for separation and spectrophotometric determination of ruthenium with Crystal Violet and Victoria Blue B

    International Nuclear Information System (INIS)

    The reaction of various chloride complexes of ruthenium with tin (II) chloride has been examined. Studies on the optimum conditions for separation of ruthenium from aqueous solutions after reaction with Crystal Violet (or Victoria Blue B) by flotation with weakly polar organic solvents have been carried out. A sensitive spectrophotometric method for determination of ruthenium based on the system: ruthenium-tin (II) chloride-Crystal Violet-toluene has been developed. Ruthenium is quantitatively floated in the form of a sparingly soluble precipitate. The separation of ruthenium is selective (simple salts of the dye are not floated). Acetone-aqueous solutions of the ion associate obey Beer's law in the 0.04 - 0.56 μg Ru/ml. The relative standard deviation is 1 - 4%. Osmium interfers with the determination of ruthenium

  13. Long-time rupture strength and creep behaviour of welded joints on heat-resistant CrMoV steels with 1 and 12% chrome

    International Nuclear Information System (INIS)

    Power plant components in the creep range are damaged frequently in the weld joint zones. The investigation concentrated therefore on the reliability of the information supplied by tests on small- and large-size samples. Creep rupture tests of dissimilar welded joints (1% with 12% chrome) with variations of heat input and weld metal have been conducted. At creep rupture times of about 104 h all joints failed in the outside heat affected zone of the weaker base metal. Large-size samples, proved in comparison at same stresses, showed distinctly longer times to rupture. (orig.)

  14. Synergistic and antagonistic effects in systems containing electrolytes and nonionic surfactant micelles on the photometric and analytical characteristics of chrome azurol S chelates

    International Nuclear Information System (INIS)

    The effects of strong electrolytes and surfactant micelles on the complexation of Chrome Azurol S with Be, Cu, Al, Sc, and Fe(3) ions were examined by spectrophotometry. Simultaneous addition of electrolytes and surfactant micelles caused a synergistic effect exhibited in a dramatic increase in the absorption intensity and the concentration of chelates with a maximum number of coordination ligands in the solution. An increase in the molar absorption coefficients of chelates, an improvement of the sensitivity of determination, and a decrease in the detection limits of metals by a factor of 2-10 resulted from this effect

  15. Spectrophotometric determination of trace uranium with Eriochrome Azurol B and Chrome Azurol S in the presence of the cationic surfactant Septonex

    International Nuclear Information System (INIS)

    Procedures for the spectrophotometric determination of UO22+ with Eriochrome Azurol B and Chrome Azurol S in the presence of the cationic surfactant Septonex have been developed from studies of the complex equilibria in solution, and simplex and single-factor optimization. They are suitable for the determination of UO22+ in drinking, surface and waste waters after prior separation with tri-n-octylamine in benzene or Freon 113 from 4M hydrochloric acid and stripping with 0.3M hydrochloric acid. (author)

  16. CN violet system spectrum used as a molecular pyrometer and the influence noise to signal ratio on the temperature values

    International Nuclear Information System (INIS)

    The CN violet system (B2Σ+ - X2Σ+) molecular emission spectrum is frequently observed in plasma sources containing hydrocarbons and nitrogen mixture. We have simulated the spectrum of (0,0) and (1,1) bands of this system for different rotational and vibrational temperatures. The influence of the noise to signal ratio has been studied, if the noise to signal ratio is about 10% we found an error of 6% at temperature 3000K and 10% at 6000K.

  17. Assay of crystal violet binding for rapid identification of virulent plasmid-bearing clones of Yersinia enterocolitica.

    OpenAIRE

    Bhaduri, S; Conway, L K; Lachica, R V

    1987-01-01

    A rapid, reliable, and simple method based on the binding of crystal violet (CV) is described for differentiating virulence-plasmid-bearing strains of Yersinia enterocolitica from their plasmidless derivatives. As with other plasmid-mediated properties of this organism, the binding of CV occurs at 37 degrees C but not at 25 degrees C. The CV-binding technique provides a simple and efficient means of screening Y. enterocolitica for virulence and for identifying individual plasmid-bearing colon...

  18. In Situ Disassembling Behavior of Composite Hydrogels for the Efficient Removal of Crystal Violet Dye from Aqueous Solution

    OpenAIRE

    Venkatesan Srinivasan; Sundaram Thiraviam; Kullagounder Subramani; Sibi Srinivasan; Pragathiswaran Chelliah; Stanley Anthuvan Babu

    2014-01-01

    A novel method for the disassembly of synthetic hydrogels in situ and thereby enhanced adsorption of crystal violet dye is reported. Silicon present in the husk ashes of Panicum miliare is used as the trigger for disassembly of poly(2-acrylamido-1-propane sulfonic acid-co-itaconic acid) hydrogels. Disassembling ability of the ash was determined by changing the temperature of the husk ash. Surface area and particle sizes of both the disassembled and assembled forms of the hydrogels were determ...

  19. Thermomechanical and Photophysical Properties of Crystal-Violet-Dye/H2O Based Dissolutions via the Pulsed Laser Photoacoustic Technique

    OpenAIRE

    Vicente Torres-Zúñiga; Rosalba Castañeda-Guzmán; Pérez-Ruiz, Santiago J.; Omar G. Morales-Saavedra

    2014-01-01

    Different thermoelastic parameters, for example, the acoustic attenuation and the speed of sound, are fundamental for instrumental calibration and quantitative characterization of organic-based dissolutions. In this work, these parameters as functions of the concentration of an organic dye (crystal-violet: CV) in distillated water (H2O) based dissolutions are investigated. The speed of sound was measured by the pulsed-laser photoacoustic technique (PLPA), which consists in the generation of a...

  20. Crystal Violet Lactone Salicylaldehyde Hydrazone Zn(II) Complex: a Reversible Photochromic Material both in Solution and in Solid Matrix

    OpenAIRE

    Kai Li; Yuanyuan Li; Jing Tao; Lu Liu; Lili Wang; Hongwei Hou; Aijun Tong

    2015-01-01

    Crystal violet lactone (CVL) is a classic halochromic dye which has been widely used as chromogenic reagent in thermochromic and piezochromic systems. In this work, a very first example of CVL-based reversible photochromic compound was developed, which showed distinct color change upon UV-visible light irradiation both in solution and in solid matrix. Moreover, metal complex of CVL salicylaldehyde hydrozone was facilely synthesized, exhibiting reversible photochromic properties with good fati...

  1. The adaptedness of the floral phenotype in a relict endemic, hawkmoth-pollinated violet. 1. Reproductive correlates of floral variation

    OpenAIRE

    Herrera, Carlos M.

    1990-01-01

    This paper examines the relationship between quantitative variation in floral morphology (sizes of petals, spur and peduncle) and maternal reproductive success (seed production) in Viola cazorlensic (Violaceae), a narrowly endemic violet of south-eastern Spain pollinated by day-flying hawkmoths (Sphingidae). This plant is characterized by broad intraspecific variation in size and proportions of floral parts. Floral morphology does not influence significantly the probability of fruit set. Amon...

  2. Examination on colour reaction of nicotinic acid-ethyl violet-uranyl ternary complex by solvent extraction spectrophotometry

    International Nuclear Information System (INIS)

    The test examination was made on solvent extraction colour reaction of the ternary complex formed by nicotinic acid, ethyl violet and uranyl in cyclohexane+MIBK (methyl isobutyl ketone) or benzene+MIBK. A difference was found between the published results and the authors'. It was shown that there is no chromomagnetic dependence with uranyl ion, but the approximate linear correlation is present with NO3- ion

  3. Differential Spectral Imaging of the CN Violet Band in Laser-Induced Plasmas on TNT Simulant Molecules

    International Nuclear Information System (INIS)

    Dual channel emission imaging of m-nitrobenzoic acid and benzoic acid was performed in order to visualize the morphology of the CN violet band emission of a TNT analogue. The CN channel was corrected for continuum emission using a simultaneously imaged background channel. Simultaneous dual channel imaging alleviated problems with shot to shot variation in the plasma morphology due to the friable substrates and showed differences between plasmas formed on the two targets

  4. REMOVAL OF SYNTHETIC DYE BASIC VIOLET 3 BY IMMOBILISED CANDIDA TROPICALIS GROWN ON SUGARCANE BAGASSE EXTRACT MEDIUM

    OpenAIRE

    CHARUMATHI D; NILANJANA DAS

    2010-01-01

    The removal of synthetic dye Basic Violet 3 using immobilised yeast Candida tropicalis grown on sugarcane bagasse extract medium was investigated. The various immobilization matrices viz. carboxymethyl cellulose, sodium alginate, agar, agarose and polyvinyl alcohol were tested and highest dye removal efficiency (99%) was noted in sodium alginate immobilised beads. The concentration of sodium alginate, bead size and cell concentration were optimized as 3%, 2mm and 3x 106 cells/g bead respectiv...

  5. Equilibrium and Kinetics Study of Adsorption of Crystal Violet onto the Peel of Cucumis sativa Fruit from Aqueous Solution

    OpenAIRE

    T Smitha; Thirumalisamy, S.; Manonmani, S.

    2012-01-01

    The use of low-cost, locally available, high efficiency and eco-friendly adsorbents has been investigated as an ideal alternative to the current expensive methods of removing dyes from wastewater. This study investigates the potential use of the peel of Cucumis sativa fruit for the removal of crystal violet (CV) dye from simulated wastewater. The effects of different system variables, adsorbent dosage, initial dye concentration, pH and contact time were investigated and optimal experimental c...

  6. Kinetic and Thermodynamic Studies of the Adsorption of Crystal Violet onto Used Black Tea Leaves

    Directory of Open Access Journals (Sweden)

    Mohammad Abul Hossain

    2013-11-01

    Full Text Available This study presents the kinetic and thermodynamic investigation of the adsorption of crystal violet (CV on used black tea leaves (UBTL from aqueous solution to evaluate the feasibility of the process. The effects of concentration, solution pH and temperature on adsorption kinetics were carried out in batch process. Kinetic studies have shown that the adsorption data partially follow simple first order, second order and pseudo second order kinetic equations for different initial concentrations at pH 2.0. The equilibrium amount adsorbed, equilibrium concentration and rate constant were calculated from better fitted pseudo second order kinetic plots for different initial concentrations. The equilibrium amount adsorbed (200 mg/g at 30 oC increased with the increase of temperature, indicated endothermic nature of the adsorption. The apparent activation energy of adsorption was determined from Arrhenius plot using pseudo second order rate constant and the value, Ea = 83.1 kJ/mol, revealed the process is chemisorption. Thermodynamic parameters: DHo, DGo and DSo, were determined from the equilibrium adsorption constant and the results obtained confirmed that the adsorption process was feasible, less spontaneous and endothermic. The equilibrium amount adsorbed was found to be increased with increase of solution pH from 2.0 to 6.0 indicating electrostatic interaction between cationic CV with anionic surface of UBTL dominated at higher pH due to the low zero point charge of pH of UBTL.

  7. Adsorption of Crystal Violet Dye from Aqueous Solution onto Zeolites from Coal Fly and Bottom Ashes

    Directory of Open Access Journals (Sweden)

    Tharcila Colachite Rodrigues Bertolini

    2013-11-01

    Full Text Available The adsorption of the cationic dye Crystal Violet (CV over zeolites from coal fly ash (ZFA and bottom ash (ZBA was evaluated. The coal fly ash (CFA and the coal bottom ash (CBA used in the synthesis of the zeolites by alkaline hydrothermal treatment were collected in Jorge Lacerda coal-fired power plant located at Capivari de Baixo County, in Santa Catarina State, Brazil. The zeolitic materials were characterized predominantly as hydroxy-sodalite and X. The dye adsorption equilibrium was reached after 10 min for ZFA and ZBA. The kinetics studies indicated that the adsorption followed the pseudo-second order kinetics and that surface adsorption and intraparticle diffusion were involved in the adsorption mechanism for both the adsorbents. The equilibrium data of ZFA was found to best fit to the Langmuir model, while ZBA was best explained by the Freundlich model. The maximum adsorption capacities were 19.6 mg g-1 for the CV/ZFA and 17.6 mg g-1 for the CV/ZBA.

  8. Leuco-crystal-violet micelle gel dosimeters: II. Recipe optimization and testing

    International Nuclear Information System (INIS)

    In this study, recipe optimization of Leuco Crystal Violet (LCV) micelle gels made with the surfactant Cetyl Trimethyl Ammonium Bromide (CTAB) and the chemical sensitizer 2,2,2-trichloroethanol (TCE) was aided by a two-level three-factor designed experiment. The optimized recipe contains 0.75 mM LCV, 17.0 mM CTAB, 120 mM TCE, 25.0 mM tri-chloro acetic acid (TCAA), 4 wt% gelatin and ∼96 wt% water. Dose sensitivity of the optimized gel is 1.5 times higher than that of Jordan’s standard LCV micelle gel. Spatial integrity of the 3D dose distribution information in 1L phantoms filled with this recipe is maintained for  >120 d. Unfortunately, phantoms made using the optimized recipe showed dose-rate dependence (14% difference in optical attenuation at the peak dose using electron beam irradiations at 100 and 400 MU min−1). Further testing suggests that the surfactant CTAB is the cause of this dose rate behaviour. (paper)

  9. Leuco-crystal-violet micelle gel dosimeters: I. Influence of recipe components and potential sensitizers

    International Nuclear Information System (INIS)

    Radiochromic leuco crystal violet (LCV) micelle gel dosimeters are promising three-dimensional radiation dosimeters because of their spatial stability and suitability for optical readout. The effects of surfactant type and surfactant concentration on dose sensitivity of LCV micelle gels are tested, demonstrating that dose sensitivity and initial colour of the gel increases with increasing Triton x-100 (Tx100) concentration. Using Cetyl Trimethyl Ammonium Bromide (CTAB) in place of Tx100 produces gels that are nearly colourless prior to irradiation, but reduces the dose sensitivity. The separate effects of Tri-chloro acetic acid concentration and pH are investigated, revealing that controlling the pH near 3.6 is crucial for achieving high dose sensitivity. The sensitizing effect of chlorinated species on dose sensitivity is tested using 2,2,2-trichloroethanol (TCE), chloroform, and 1,1,1-trichloro-2-methyl-2-propanol hemihydrate. TCE gives the largest improvement in dose sensitivity and is recommended for use in micelle gel dosimeters because it is less volatile and safer to use than chloroform. Preliminary experiments on a new gel containing CTAB as the surfactant and TCE show that this new gel gives a dose sensitivity that is 24% higher than that of previous LCV micelle gels and is nearly colourless prior to irradiation. (paper)

  10. Synthesis and Characterisation of Silica-Modified Titania for Photocatalytic Decolouration of Crystal Violet.

    Science.gov (United States)

    Shahid, Mohammad; El Saliby, Ibrahim; Tijing, Leonard D; McDonagh, Andrew; Park, Se Min; Lee, Kwang Young; Shon, Ho Kyong; Kim, Jong-Ho

    2015-07-01

    In the past few years, silica-modified titania has drawn increasing attention due to their special properties making them ideal candidates for a wide range of applications. In this study, we report a novel method for the synthesis of silica-modified titania by a sol-gel method using sodium silicate solution (1 M). The hydrolysis and condensation reactions of titanium dioxide (TiO2, Degussa Aeroxide® P25) in sodium silicate solution proceeded with citric acid (3 M) as a catalyst. The orbital shaking method was followed for the removal of sodium salt formed during the sol-gel process. Solvent exchange was carried out using methanol and hexane. Finally, chemical modification of the gel was conducted using trimethylchlorosilane followed by ambient pressure drying. The obtained silica-modified titania was characterised for nanostructural analysis using scanning electron microscopy and transmission electron microscopy. The nitrogen adsorption-desorption measurements were employed to investigate the BET surface area, pore structure and pore volume of specimens. Thermal gravimetric analysis showed exothermic peaks at temperature range of 90-190 °C representing the oxidation of organic groups from--Si-R network. The silica-modified titania showed high photocatalytic activity and an easy recovery using crystal violet as model water pollutant. PMID:26373134

  11. GaN-based violet laser diodes grown on free-standing GaN substrate

    International Nuclear Information System (INIS)

    A violet laser diode (LD) structure is grown on a free-standing c-plane GaN substrate and 4 μm×800 μm ridge waveguide LDs are fabricated. The electrical and the optical characteristics of LDs under different facet-coating and chip-mounting conditions are investigated under pulse mode operation. The active region temperatures of p-side up and p-side down mounted LDs are calculated with different injection currents. The calculated thermal resistances of p-side up and p-side down mounted LDs are 4.6 K/W and 3 K/W, respectively. The threshold current of the p-side down mounted LD is much lower than that of the p-side up mounted LD. The blue shift of the emission wavelength with increasing injection current is observed only for the LD with p-side down mounting configuration, due to the more efficient heat dissipation. (classical areas of phenomenology)

  12. Colorimetric growth assay for epidermal cell cultures by their crystal violet binding capacity.

    Science.gov (United States)

    Bonnekoh, B; Wevers, A; Jugert, F; Merk, H; Mahrle, G

    1989-01-01

    The application of a simple, rapid, and inexpensive colorimetric growth assay was tested for human epidermal cells subcultured in uncoated plastic dishes. Cell layers were incubated with a crystal violet (CV) solution (0.2% with ethanol 2% in 0.5 M Tris-Cl buffer, pH 7.8) for 10 min at room temperature. After rinsing with 0.5 M Tris-Cl (pH 7.8) the cell layer was dried and decolorized with a sodium-dodecylsulfate solution (0.5% with ethanol 50% in 0.5 M Tris-Cl, pH 7.8) for 60 min at 37 degrees C. The extinction of the supernatant was read at the absorption maximum of 586 nm. The protein content of attached cells as classical parameter for quantifying cell growth was strongly related to CV extinction with a correlation coefficient of r = 0.98. Furthermore, the subcellular protein binding qualities of CV were analyzed. The water-soluble protein fraction of cultured epidermal cells was separated by sodium-dodecylsulfate polyacrylamide gel electrophoresis and stained with CV. We found a staining pattern which was qualitatively very similar to that of Coomassie blue, however less intense. Keratin electrophoresis revealed an affinity of CV to the 48, 50, and 56 kD cytokeratins. In conclusion, this CV assay is a reliable and simple method for the monitoring of epidermal cell growth in cultures. PMID:2482013

  13. Application potential of grapefruit peel as dye sorbent: Kinetics, equilibrium and mechanism of crystal violet adsorption

    Energy Technology Data Exchange (ETDEWEB)

    Saeed, Asma, E-mail: asmadr@wol.net.pk [Environmental Biotechnology Group, Biotechnology and Food Research Centre, PCSIR Laboratories Complex, Ferozepur Road, Lahore 54600 (Pakistan); Sharif, Mehwish [School of Biological Sciences, University of the Punjab, Lahore 54590 (Pakistan); Iqbal, Muhammad [Environmental Biotechnology Group, Biotechnology and Food Research Centre, PCSIR Laboratories Complex, Ferozepur Road, Lahore 54600 (Pakistan)

    2010-07-15

    This study reports the sorption of crystal violet (CV) dye by grapefruit peel (GFP), which has application potential in the remediation of dye-contaminated wastewaters using a solid waste generated by the citrus fruit juice industry. Batch adsorption of CV was conducted to evaluate the effect of initial pH, contact time, temperature, initial dye concentration, GFP adsorbent dose, and removal of the adsorbate CV dye from aqueous solution to understand the mechanism of sorption involved. Sorption equilibrium reached rapidly with 96% CV removal in 60 min. Fit of the sorption experimental data was tested on the pseudo-first and pseudo-second-order kinetics mathematical equations, which was noted to follow the pseudo-second-order kinetics better, with coefficient of correlation {>=}0.992. The equilibrium process was well described by the Langmuir isotherm model, with maximum sorption capacity of 254.16 mg g{sup -1}. The GFP was regenerated using 1 M NaOH, with up to 98.25% recovery of CV and could be reused as a dye sorbent in repeated cycles. GFP was also shown to be highly effective in removing CV from aqueous solution in continuous-flow fixed-bed column reactors. The study shows that GFP has the potential of application as an efficient sorbent for the removal of CV from aqueous solutions.

  14. Application potential of grapefruit peel as dye sorbent: Kinetics, equilibrium and mechanism of crystal violet adsorption

    International Nuclear Information System (INIS)

    This study reports the sorption of crystal violet (CV) dye by grapefruit peel (GFP), which has application potential in the remediation of dye-contaminated wastewaters using a solid waste generated by the citrus fruit juice industry. Batch adsorption of CV was conducted to evaluate the effect of initial pH, contact time, temperature, initial dye concentration, GFP adsorbent dose, and removal of the adsorbate CV dye from aqueous solution to understand the mechanism of sorption involved. Sorption equilibrium reached rapidly with 96% CV removal in 60 min. Fit of the sorption experimental data was tested on the pseudo-first and pseudo-second-order kinetics mathematical equations, which was noted to follow the pseudo-second-order kinetics better, with coefficient of correlation ≥0.992. The equilibrium process was well described by the Langmuir isotherm model, with maximum sorption capacity of 254.16 mg g-1. The GFP was regenerated using 1 M NaOH, with up to 98.25% recovery of CV and could be reused as a dye sorbent in repeated cycles. GFP was also shown to be highly effective in removing CV from aqueous solution in continuous-flow fixed-bed column reactors. The study shows that GFP has the potential of application as an efficient sorbent for the removal of CV from aqueous solutions.

  15. Studies on the synthesis and thermochromic properties of crystal violet lactone and its reversible thermochromic complexes

    International Nuclear Information System (INIS)

    In this article, a crucial compound, crystal violet lactone (CVL), was prepared by the reaction of N,N-dimethylaniline, p-dimethylanimobenzaldehyde and m-dimethylanimobenzoic acid. Taking alcohols or carboxylic acids as solvents, 15 novel reversible thermochromic complexes were prepared by means of chelation reaction between electron donor CVL and electron acceptor such as various phenols, aromatic amines, carboxylic acids, and Lewis acids, respectively. The structure of CVL is characterized by 1H NMR and MS. The reversible thermochromic behavior of these compounds are studied by DSC/TG, IR, and Raman spectrum. Results indicate that mechanism of these reversible thermochromic complexes is the lactone ring tautomerism when the temperature is low or high. Thermochromic color degree of these complexes is dependent on the acidity of electron acceptor and thermochromic temperature is dependent on the properties of solvent compounds. The properties of electron acceptor and solvent compounds also determined the thermochromic process of the complexes, which followed the first-order kinetic equation, and the values of energy of activity (Ea) of thermochromic process are correlated with the components of the complexes nearly. The stronger the acidity of phenols is, and the deeper the thermochromic color degree is, the higher the value of Ea is, when electron acceptors are phenols

  16. Crystal Violet and Methylene Green as Low-Dose Liquid Dosimetry Systems

    International Nuclear Information System (INIS)

    The ultimate aim of the present work is studying of the possibility of using some organic solutions for gamma radiation monitors and to evaluate and characterize the dosimetric properties of these compounds. Crystal violet (CV) and methylene green (MG) aqueous solutions with different concentrations have been prepared and irradiated to different absorbed doses. The solutions were readout using absorption spectrophotometry technique at λmax 592 nm and 614 nm for CV and MG respectively. The maximum useful dose range was investigated and found to be concentration dependent. It was found that the useful dose range was from 10-160 Gy for CV and from 10-200 Gy for MG. The radiation chemical yield, G-value, was calculated for the studied solutions. The ph effect and the effect of different additives, chloral hydrate and ethanol have been also investigated. The pre- and post- irradiation stabilities of these solutions under different storage conditions were studied and the results showed different significant dependence on the storage condition

  17. Visible photoluminescence in coloured Lithium Fluoride under ultra-violet continuous wave excitation

    International Nuclear Information System (INIS)

    The γ-coloured Lithium Fluoride crystals visible fluorescence at room temperature was measured under excitation with ultra-violet continuous wave light at λ = 244 nm from a frequency-doubled Ar+-ion laser. The excitation wavelength lies close to the peak of the F-centre absorption band for LiF, and the visible luminescence spectrum consists of two broad emission bands, assigned to F+3 and F2 centres in LiF. The luminescence spectrum changes in a short time after start of illumination. The main effect of 244 nm laser illumination is the observed change in the F2 emission band intensity, which is strongly and permanently bleached by the CW UV light at 244 nm as soon as it illuminates the crystal. The time evolution of the fluorescence signals can be measured, and the corresponding curves were fitted by a single exponential decay, resulting in characteristic time constants of ∼ 9 s and ∼ 30 s for the F2 and F+3 bands, respectively. The reported effects support previous work about UV laser illumination in the F-band absorption peak as an effective method to control the ratio of F2 to F+3 centres in LiF, due to permanent bleaching of the former ones.

  18. The First Swift Ultra-Violet/Optical Telescope GRB Afterglow Catalog

    CERN Document Server

    Roming, P W A; Oates, S R; Porterfield, B L; Berk, D E Vanden; Boyd, P T; Holland, S T; Hoversten, E A; Immler, S; Marshall, F E; Page, M J; Racusin, J L; Schneider, D P; Breeveld, A A; Brown, P J; Chester, M M; Cucchiara, A; De Pasquale, M; Gronwall, C; Hunsberger, S D; Kuin, N P M; Landsman, W B; Schady, P; Still, M

    2008-01-01

    We present the first Swift Ultra-Violet/Optical Telescope (UVOT) gamma-ray burst (GRB) afterglow catalog. The catalog contains data from over 64,000 independent UVOT image observations of 229 GRBs first detected by Swift, the High Energy Transient Explorer 2 (HETE2), the INTErnational Gamma-Ray Astrophysics Laboratory (INTEGRAL), and the Interplanetary Network (IPN). The catalog covers GRBs occurring during the period from 2005 Jan 17 to 2007 Jun 16 and includes ~86% of the bursts detected by the Swift Burst Alert Telescope (BAT). The catalog provides detailed burst positional, temporal, and photometric information extracted from each of the UVOT images. Positions for bursts detected at the 3-sigma-level are provided with a nominal accuracy, relative to the USNO-B1 catalog, of ~0.25 arcseconds. Photometry for each burst is given in three UV bands, three optical bands, and a 'white' or open filter. Upper limits for magnitudes are reported for sources detected below 3-sigma. General properties of the burst samp...

  19. Suburban immigrants to wildlands disrupt honest signaling in ultra-violet plumage

    Directory of Open Access Journals (Sweden)

    Angela Tringali

    2015-06-01

    Full Text Available Urbanization changes habitat in a multitude of ways, including altering food availability. Access to human-provided food can change the relationship between body condition and honest advertisements of fitness, which may result in changes to behavior, demography, and metapopulation dynamics. We compared plumage color, its relationship with body condition and feather growth, and use as signal of dominance between a suburban and a wildland population of Florida Scrub-Jay (Aphelocoma coerulescens. Although plumage color was not related to body condition at either site, suburban birds had plumage with a greater proportion of total reflectance in the ultra-violet (UV and peak reflectance at shorter wavelengths. Despite the use of plumage reflectance as a signal of dominance among individuals in the wildlands, we found no evidence of status signaling at the suburban site. However, birds emigrating from the suburban site to the wildland site tended to be more successful at acquiring breeder status but less successful at reproducing than were immigrants from an adjacent wildland site, suggesting that signaled and realized quality differ. These differences in signaling content among populations could have demographic effects at metapopulation scales and may represent an evolutionary trap whereby suburban immigrants are preferred as mates even though their reproductive success relative to effort is lower.

  20. Studies on the synthesis and thermochromic properties of crystal violet lactone and its reversible thermochromic complexes

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, C.F.; Wu, A.B

    2005-01-20

    In this article, a crucial compound, crystal violet lactone (CVL), was prepared by the reaction of N,N-dimethylaniline, p-dimethylanimobenzaldehyde and m-dimethylanimobenzoic acid. Taking alcohols or carboxylic acids as solvents, 15 novel reversible thermochromic complexes were prepared by means of chelation reaction between electron donor CVL and electron acceptor such as various phenols, aromatic amines, carboxylic acids, and Lewis acids, respectively. The structure of CVL is characterized by {sup 1}H NMR and MS. The reversible thermochromic behavior of these compounds are studied by DSC/TG, IR, and Raman spectrum. Results indicate that mechanism of these reversible thermochromic complexes is the lactone ring tautomerism when the temperature is low or high. Thermochromic color degree of these complexes is dependent on the acidity of electron acceptor and thermochromic temperature is dependent on the properties of solvent compounds. The properties of electron acceptor and solvent compounds also determined the thermochromic process of the complexes, which followed the first-order kinetic equation, and the values of energy of activity (E{sub a}) of thermochromic process are correlated with the components of the complexes nearly. The stronger the acidity of phenols is, and the deeper the thermochromic color degree is, the higher the value of E{sub a} is, when electron acceptors are phenols.

  1. Combination of Conventional and Ultra Violet Radiation for Surface Coating of Meranti (Shorea spp) Plywood

    International Nuclear Information System (INIS)

    Experiment 011 the combination of conventional and ultra violet (UV) radiation for surface coating of plywood has been done by using coating material with the trade name of overlon Base coating was conducted using water base acrylate emulsion Overlon-670 W through conventional method whereas top coating was conducted using epoxy acrylate Overlon- 731 L through UV curing method Coating process was conducted using roll coater. In case of UV-curing, the irradiation was carried out using a one lamp or 80 Watt/cm UV-source at conveyor speed of 2, 3,4 and 5 m/min. Parameters observed were pendulum hardness, glossy, adhesion and chemical, solvent and stain resistances. The separate measurements of top coat film itself e.g. gel fraction, tensile Strength, elongation at break, and flexibility were also evaluated. Experimental results showed that films on plywood surface have pendulum hardness of 21-38 sec, glossy of 32-46 %, good adhesion between base coat and top coat, and resistance to chemical, solvent and stain except for 10 % sodium hydroxide solution Key word: Plywood, water base system, emulsion acrylate, epoxy acrylate, UV Irradiation

  2. Studies on plant regeneration and somaclonal variation in Saintpaulia ionantha Wendl. (African violet).

    Science.gov (United States)

    Daud, Norhayati; Taha, Rosna Mat; Hasbullah, Nor Azlina

    2008-05-01

    Efficient plant regeneration of Saintpaulia ionantha (African violet) has been obtained in the present study. MS medium supplemented with 1.0 mg L(-1) IAA and 2.0 mg L(-1) Zeatin resulted in 100% shoot regeneration and induced the highest number of shoots (average 15.0 +/- 0.8 shoots per explant) after being cultured for 8 weeks. The above hormone combination was optimum for shoot regeneration. Most of Saintpaulia ionantha plantlets derived from tissue culture system could be hardened and transferred to the greenhouse conditions with 84.0 +/- 1.6% success rate. However, regenerated plantlets of Saintpaulia ionantha (even after 12-months-old) failed to flower. Morphological characters of regenerated plantlets of Saintpaulia ionantha were observed and compared with in vivo (intact) plants. Regenerated plantlets showed some differences in morphological characters, such as height and leaf size, texture and colour, but the plantlets showed no variation in leaf arrangement and leaf margin. However, the morphological characters of the regenerated plantlets were found to be unstable. PMID:18819532

  3. Anatomical structure of african violet (Saintpaulia ionantha L. vitro- and exvitroplantlets

    Directory of Open Access Journals (Sweden)

    Adriana PETRUŞ-VANCEA

    2010-11-01

    Full Text Available In this article we study the histo-anatomical structure of vegetative organs of African violet (Saintpaulia ionantha L. vitro- and exvitroplantlets in comparison with similar aspects at the same organs of the greenhouse plants (control lot. The phytoinoculs vitroculture period was 120 days, the ex vitro acclimatization for the exvitroplantlets needed 30 days, and the greenhouse cultivar was 2 years old. Finally, we found that only rootlets of the vitroplantlets had a primary structure because at stemlets level has been identified the cambium presence still the vitroculture period. The cortical parenchyma cells at vitro- and exvitroplantlets was larger and less compact in comparison with those of control lot. Also, in the vitroplantlet rootles and stemlets the report cortex:central cylinder was much higher and vascular bundle was very poorly represented that at exvitroplantlets, but especially in comparison with these aspects in the plants grown in natural conditions. The spongy parenchyma at leaflets from in vitro culture was composed of fewer cell layers which was larger and less compact in comparison with those of exvitroplantlet leaf homologous layers and with the same layers from the leaf of greenhouse plants. At in vitro leaflets the peryphloemic protective mechanical tissue was at an early forming stage. However, we consider these differences as being due to the plants normal ontogenetic development.

  4. World Space Observatory-UltraViolet: International Space Mission for the Nearest Future

    Science.gov (United States)

    Sachkov, M.; Gómez de Castro, A. I.; Pagano, I.; Torres, F.; Zaiko, Y.; Shustov, B.

    2009-03-01

    The World Space Observatory UltraViolet (WSO-UV) project is an international space observatory designed for observations in the ultraviolet domain where some of the most important astrophysical processes can be efficiently studied with unprecedented sensitivity. WSO-UV is a multipurpose observatory, consisting of a 170 cm aperture telescope, capable of high-resolution spectroscopy, long slit low-resolution spectroscopy, and deep UV and optical imaging. With a nominal mission life time of 5 years, and a planned extension to 10 years, from a geosynchronous orbit with an inclination of 51.8 degrees, the WSO-UV will provide observations that are of exceptional importance for the study of many astrophysical problems. WSO-UV is implemented in the framework of a collaboration between Russia (chair), China, Germany, Italy, Spain, and Ukraine. This article is the first of three papers in this proceedings dedicated to the WSO-UV project This paper gives general information on the WSO-UV project and its status.

  5. Removal and recovery of hazardous triphenylmethane dye, Methyl Violet through adsorption over granulated waste materials

    International Nuclear Information System (INIS)

    Bottom Ash a power plant waste material and De-Oiled Soya, an agricultural waste product have been successfully used for the removal and recovery of a hazardous triphenylmethane dye-Methyl Violet, from wastewaters. The characterization of each adsorbent has been carried out by I.R. and D.T.A. curves. Batch adsorption studies have been made by measuring effects of pH, sieve size, amount of adsorbent, contact time, temperature, concentration of the adsorbate solution, etc. Kinetic studies have been used to determine the nature of rate controlling step of the processes and confirm the applicability of the first order rate expression in the ongoing adsorption process. Various thermodynamic parameters have also been calculated by applying the linear forms of Langmuir and Freundlich adsorption isotherms. The linear nature of adsorption isotherms obtained shows the dependence of the processes on the Freundlich and Langmuir isotherm models. Furthermore, to ascertain the adsorption processes to be particle diffusion or film diffusion mechanism, Boyd and Reichenberg's expressions have been applied. For both the adsorbents, column operations have been carried out for the bulk removal of the dye. The adsorbed dye has been recovered by eluting hydrochloric acid of pH 3 through exhausted columns

  6. Adsorption of crystal violet with diatomite earth&carbon by a modification of hydrothermal carbonization process.

    Science.gov (United States)

    Zhang, Yanzhuo; Li, Jun; Chen, Guanghui; Bian, Wei; Lu, Yun; Li, Wenjing; Zheng, Zhaoming; Cheng, Xiaojie

    2016-01-01

    The high colority and difficulty of decolorization are the most important tasks on printing and dyeing wastewater. This study investigates the ability of diatomite earth&carbon (DE&C) as an adsorbent to removal crystal violet (CV) from aqueous solutions. Fourier transform infrared spectroscopy results indicate the importance of functional groups during the adsorption of CV. The obtained N2 adsorption-desorption isotherm values accord with well IUPAC type II. Our calculations determined a surface area of 73.15 m(2) g(-1) for DE&C and an average pore diameter of 10.56 nm. Equilibrium data of the adsorption process fitted very well to the Langmuir model (R(2) > 0.99). The results of kinetics study showed that the pseudo-second-order model fitted to the experimental data well. The thermodynamic parameters were also evaluated. ΔH° 0 and ΔG° dye. Furthermore the positive value of ΔS° reflected good affinity of the CV dye. PMID:27003089

  7. Intense, stable and excitation wavelength-independent photoluminescence emission in the blue-violet region from phosphorene quantum dots.

    Science.gov (United States)

    Ge, Shuaipeng; Zhang, Lisheng; Wang, Peijie; Fang, Yan

    2016-01-01

    Nanoscale phosphorene quantum dots (PQDs) with few-layer structures were fabricated by pulsed laser ablation of a bulk black phosphorus target in diethyl ether. An intense and stable photoluminescence (PL) emission of the PQDs in the blue-violet wavelength region is clearly observed for the first time, which is attributed to electronic transitions from the lowest unoccupied molecular orbital (LUMO) to the highest occupied molecular orbital (HOMO) and occupied molecular orbitals below the HOMO (H-1, H-2), respectively. Surprisingly, the PL emission peak positions of the PQDs are not red-shifted with progressively longer excitation wavelengths, which is in contrast to the cases of graphene and molybdenum disulphide quantum dots. This excitation wavelength-independence is derived from the saturated passivation on the periphery and surfaces of the PQDs by large numbers of electron-donating functional groups which cause the electron density on the PQDs to be dramatically increased and the band gap to be insensitive to the quantum size effect in the PQDs. This work suggests that PQDs with intense, stable and excitation wavelength-independent PL emission in the blue-violet region have a potential application as semiconductor-based blue-violet light irradiation sources. PMID:27265198

  8. Wearable device for monitoring momentary presence of intense x-ray and/or ultra-violet radiations

    International Nuclear Information System (INIS)

    A credit-card-size clear-plastic-encased device can be worn or carried by a person to warn him of the momentary presence of dangerous intensities of ultra-violet and/or x-ray radiations. A base lamina (e.g. of cardboard) is coated with a material (e.g. zinc-cadmium sulfide or lead-barium sulfate) which fluoresces under such radiations. Numerals, letters, words or symbols are printed over the fluorescent coat with a material inhibitory to said radiations so that a warning message in dark print will appear on a light background when dangerous intensities of said radiations are present. An x-ray-warning area is covered with an ultra-violet absorbing screen so that said area will glow only under x-rays (Which rays will also activate the remaining ultra-violet-responsive area). The colors of the laminas and the coats are so selected that the messages are not visible when dangerous radiations are not present. If desired, only the message can be printed with fluorescent material so as to glow on a darker background. Optionally, step-layer attenuation devices can be added to indicate degrees of radiation; and reflecting surfaces can underlie the fluorescent coat to increase efficiency and/or sensitively

  9. Intense, stable and excitation wavelength-independent photoluminescence emission in the blue-violet region from phosphorene quantum dots

    Science.gov (United States)

    Ge, Shuaipeng; Zhang, Lisheng; Wang, Peijie; Fang, Yan

    2016-06-01

    Nanoscale phosphorene quantum dots (PQDs) with few-layer structures were fabricated by pulsed laser ablation of a bulk black phosphorus target in diethyl ether. An intense and stable photoluminescence (PL) emission of the PQDs in the blue-violet wavelength region is clearly observed for the first time, which is attributed to electronic transitions from the lowest unoccupied molecular orbital (LUMO) to the highest occupied molecular orbital (HOMO) and occupied molecular orbitals below the HOMO (H-1, H-2), respectively. Surprisingly, the PL emission peak positions of the PQDs are not red-shifted with progressively longer excitation wavelengths, which is in contrast to the cases of graphene and molybdenum disulphide quantum dots. This excitation wavelength-independence is derived from the saturated passivation on the periphery and surfaces of the PQDs by large numbers of electron-donating functional groups which cause the electron density on the PQDs to be dramatically increased and the band gap to be insensitive to the quantum size effect in the PQDs. This work suggests that PQDs with intense, stable and excitation wavelength-independent PL emission in the blue-violet region have a potential application as semiconductor-based blue-violet light irradiation sources.

  10. Kinetic model of the thermal pyrolysis of chrome tanned leather treated with NaOH under different conditions using thermogravimetric analysis.

    Science.gov (United States)

    Bañón, E; Marcilla, A; García, A N; Martínez, P; León, M

    2016-02-01

    The thermal decomposition of chrome tanned leather before and after a soaking treatment with NaOH was studied using thermogravimetric analysis (TGA). The effect of the solution concentration (0.2M and 0.5M) and the soaking time (5min and 15min) was evaluated. TGA experiments at four heating rates (5, 10, 15 and 20°Cmin(-1)) were run in a nitrogen atmosphere for every treatment condition. A kinetic model was developed considering the effect of the three variables studied, i.e.: the NaOH solution concentration, the soaking time and the heating rate. The proposed model for chrome tanned leather pyrolysis involves a set of four reactions, i.e.: three independent nth order reactions, yielding the corresponding products and one of them undergoing a successive cero order reaction. The model was successfully applied simultaneously to all the experimental data obtained. The evaluation of the kinetic parameters obtained (activation energy, pre-exponential factor and reaction order) allowed a better understanding of the effect of the alkali treatment on these wastes. PMID:26603567

  11. An LED Approach for Measuring the Photocatalytic Breakdown of Crystal Violet Dye

    Science.gov (United States)

    Ryan, Robert E.; Underwood, Lauren W.; ONeal, Duane; Pagnutti, Mary; Davis, Bruce A.

    2009-01-01

    A simple technique to assess the reactivity of photocatalytic coatings sprayed onto transmissive glass surfaces was developed. This new method uses ultraviolet (UV) gallium nitride (GaN) light-emitting diodes (LEDs) to drive a photocatalytic reaction (the photocatalytic breakdown of a UV-resistant dye applied to a surface coated with the semiconductor titanium dioxide); and then a combination of a stabilized white light LED and a spectrometer to track the dye degradation as a function of time. Simple, standardized evaluation techniques that assess photocatalytic materials over a variety of environmental conditions, including illumination level, are not generally available and are greatly needed prior to in situ application of photocatalytic technologies. To date, much research pertaining to this aspect of photocatalysis has been limited and has focused primarily on laboratory experiments using mercury lamps. Mercury lamp illumination levels are difficult to control over large ranges and are temporally modulated by line power, limiting their use in helping to understand and predict how photocatalytic materials will behave in natural environmental settings and conditions. The methodology described here, using steady-state LEDs and time series spectroradiometric techniques, is a novel approach to explore the effect of UV light on the photocatalytic degradation of a UV resistant dye (crystal violet). GaN UV LED arrays, centered around 365 nm with an adjustable DC power supply, are used to create a small, spatially uniform light field where the steady state light level can be varied over three to four orders of magnitude. For this study, a set of glass microscope slides was custom coated with a thinly sprayed layer of photocatalytic titanium dioxide. Crystal violet was then applied to these titanium-dioxide coated slides and to uncoated control slides. The slides were then illuminated at various light levels from the dye side of the slide by the UV LED array. To monitor

  12. Is ultra-violet radiation the main force shaping molecular evolution of varicella-zoster virus?

    Directory of Open Access Journals (Sweden)

    Escobar-Gutiérrez Alejandro

    2011-07-01

    Full Text Available Abstract Background Varicella (chickenpox exhibits a characteristic epidemiological pattern which is associated with climate. In general, primary infections in tropical regions are comparatively less frequent among children than in temperate regions. This peculiarity regarding varicella-zoster virus (VZV infection among certain age groups in tropical regions results in increased susceptibility during adulthood in these regions. Moreover, this disease shows a cyclic behavior in which the number of cases increases significantly during winter and spring. This observation further supports the participation of environmental factors in global epidemiology of chickenpox. However, the underlying mechanisms responsible for this distinctive disease behavior are not understood completely. In a recent publication, Philip S. Rice has put forward an interesting hypothesis suggesting that ultra-violet (UV radiation is the major environmental factor driving the molecular evolution of VZV. Discussion While we welcomed the attempt to explain the mechanisms controlling VZV transmission and distribution, we argue that Rice's hypothesis takes lightly the circulation of the so called "temperate VZV genotypes" in tropical regions and, to certain degree, overlooks the predominance of such lineages in certain non-temperate areas. Here, we further discuss and present new information about the overwhelming dominance of temperate VZV genotypes in Mexico regardless of geographical location and climate. Summary UV radiation does not satisfactorily explain the distribution of VZV genotypes in different tropical and temperate regions of Mexico. Additionally, the cyclic behavior of varicella does not shown significant differences between regions with different climates in the country. More studies should be conducted to identify the factors directly involved in viral spreading. A better understanding of the modes of transmissions exploited by VZV and their effect on viral

  13. Studies on 405nm blue-violet diode laser with external grating cavity

    Science.gov (United States)

    Li, Bin; Gao, Jun; Zhao, Jun; Yu, Anlan; Luo, Shiwen; Xiong, Dongsheng; Wang, Xinbing; Zuo, Duluo

    2016-03-01

    Spectroscopy applications of free-running laser diodes (LD) are greatly restricted as its broad band spectral emission. And the power of a single blue-violet LD is around several hundred milliwatts by far, it is of great importance to obtain stable and narrow line-width laser diodes with high efficiency. In this paper, a high efficiency external cavity diode laser (ECDL) with high output power and narrow band emission at 405 nm is presented. The ECDL is based on a commercially available LD with nominal output power of 110 mW at an injection current of 100 mA. The spectral width of the free-running LD is about 1 nm (FWHM). A reflective holographic grating which is installed on a home-made compact adjustable stage is utilized for optical feedback in Littrow configuration. In this configuration, narrow line-width operation is realized and the effects of grating groove density as well as the groove direction related to the beam polarization on the performances of the ECDL are experimentally investigated. In the case of grating with groove density of 3600 g/mm, the threshold is reduced from 21 mA to 18.3 mA or 15.6 mA and the tuning range is 3.95 nm or 6.01 nm respectively when the grating is orientated in TE or TM polarization. In addition, an output beam with a line-width of 30 pm and output power of 92.7 mW is achieved in TE polarization. With these narrow line-width and high efficiency, the ECDL is capable to serve as a light source for spectroscopy application such as Raman scattering and laser induced fluorescence.

  14. Structural identification and bioactivities of red-violet pigments present in Basella alba fruits.

    Science.gov (United States)

    Lin, Shu-Mei; Lin, Bo-Hong; Hsieh, Wan-Mei; Ko, Huey-Jiun; Liu, Chi-Dong; Chen, Lih-Geeng; Chiou, Robin Y-Y

    2010-10-13

    Mature Basella alba L. fruit, with dark blue skin and deep red-violet flesh, is a potential source of natural colorants. Its pigment components and bioactivities deserve particular attention and investigation. In this study, fruit flesh was extracted with 80% methanol (containing 0.2% formic acid) and subjected to solid-phase extraction, semipreparative HPLC isolation, mass spectrophotometric analysis, and structural elucidation. The major red pigment was identified as gomphrenin I. Its quantity increased with the increase of fruit maturity. The gomphrenin I extract yield from ripe fruits was 36.1 mg/100 g of fresh weight. In addition to gomphrenin I, betanidin-dihexose and isobetanidin-dihexose were also detected. The antioxidant activities of gomphrenin I determined by Trolox equivalent antioxidant capacity (TEAC), α,α-diphenyl-β-picrylhydrazyl (DPPH) radical scavenging activity, reducing power, and antioxidative capacity assays were equivalent to 534 μM Trolox, 103 μM butylated hydroxytoluene (BHT), 129 μM ascorbic acid, and 68 μM BHT at 180, 23, 45, and 181 μM, respectively. The anti-inflammatory function was tested at concentrations of 25, 50, and 100 μM in murine macrophages stimulated with lipopolysaccharide (LPS). The results revealed that gomphrenin I suppressed LPS-induced nitric oxide (NO) production in a dose-dependent manner and decreased PGE(2) and IL-1β secretions at the highest concentration tested. The transcriptional inhibitory activities of gomphrenin I on the expression of inflammatory genes encoding iNOS, COX-2, IL-1β, TNF-α, and IL-6 were also observed. It is of merit to identify gomphrenin I as a principal pigment of B. alba fruits and as a potent antioxidant and inflammatory inhibitor. These findings suggest that B. alba fruit is a rich source of betalains and has value-added potential for use in the development of food colorants and nutraceuticals. PMID:20839771

  15. Microwave induced catalytic degradation of crystal violet in nano-nickel dioxide suspensions

    International Nuclear Information System (INIS)

    Nickel oxide catalyst was obtained by precipitation-oxidation method with the assistance of microwave irradiation. The samples were characterized by X-ray diffraction, Raman spectrophotometer, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, surface area and porosity analyzer. On the basis of the results, the as-prepared product was nano-NiO2 with OH group and active oxygen. The catalytic activity of the as-prepared product might be attributed to its microwave absorbing property and the role of active oxygen, OH group under microwave irradiation. The microwave induced catalytic degradation process (MICD) with as-prepared product was further applied to degrade triphenylmethane dye crystal violet (CV). 97% of a 100 mg L-1 sample of CV was rapidly degraded in 5 min with the corresponding 81% TOC removal. The main intermediates were separated and identified by LC-ESI-MS and GC-MS techniques. The LC-ESI-MS analytical results demonstrated that a series of N-de-methylation products were obtained in a stepwise manner, namely mono-, di-, tri-, tetra-, penta-, and hexa-de-methylated CV species. Nine organic acids with benzene ring and four low molecular acids were yielded with the assistance of GC-MS. The proposed degradation pathways were discussed in this study. The degradation processes might include N-de-methylation, destruction of conjugated structure and opening-benzene ring. MICD, as a potential technique with wide application perspective, can be used to purify triphenylmethane dye wastewater with nanosized nickel dioxide.

  16. An Ultra-Violet Tolerant Wild-Type Strain of Melanin-Producing Bacillus thuringiensis

    Directory of Open Access Journals (Sweden)

    Sansinenea

    2015-07-01

    Full Text Available Background Bacillus thuringiensis is the most successful biological control agent used in agriculture, forestry and mosquito control. However, the insecticidal activity of the B. thuringiensis formulation is not very stable and rapidly loses its biological activity under field conditions, due to the ultraviolet radiation in sunlight. Melanin is known to absorb radiation therefore photo protection of B. thuringiensis based on melanin has been extensively studied. Objectives The aim of this study was to find a wild type strain of naturally melanin-producing B. thuringiensis to avoid any mutation or manipulation that can affect the Cry protein content. Materials and Methods Bacillus thuringiensis strains were isolated from soils of different States of Mexico and pigment extraction was followed by lowering the pH to 2 using 1N HCl. Pigment was characterized by some chemical tests based on its solubility, bleaching by H2O2 and flocculation with FeCl3, and using an Infrared (IR spectrum. Ultraviolet (UV irradiation experiment was performed to probe the melanin efficacy. Results ELI52 strain of B. thuringiensis was confirmed to naturally produce melanin. The Cry protein analysis suggested that ELI52 is probably a B. thuringiensis subsp. israelensis strain with toxic activity against the Diptera order of insects. Ultra Violet protection efficacy of melanin was probed counting total viable colonies after UV radiation and comparing the results with the non-producing melanin strain L-DOPA (L-3, 4-dihydroxyphenylalanine was also detected in the culture. ELI52 strain showed an antagonistic effect over some common bacteria from the environment. Conclusions ELI52 wild-type strain of B. thuringiensis is a good bio-insecticide that produces melanin with UV-resistance that is probably toxic against the Diptera order of insects and can inhibit the growth of other environmental bacteria.

  17. Measuring SO2 ship emissions with an ultra-violet imaging camera

    Science.gov (United States)

    Prata, A. J.

    2013-11-01

    Over the last few years fast-sampling ultra-violet (UV) imaging cameras have been developed for use in measuring SO2 emissions from industrial sources (e.g. power plants; typical fluxes ~1-10 kg s-1) and natural sources (e.g. volcanoes; typical fluxes ~10-100 kg s-1). Generally, measurements have been made from sources rich in SO2 with high concentrations and fluxes. In this work, for the first time, a UV camera has been used to measure the much lower concentrations and fluxes of SO2 (typical fluxes ~0.01-0.1 kg s-1) in the plumes from moving and stationary ships. Some innovations and trade-offs have been made so that estimates of the fluxes and path concentrations can be retrieved in real-time. Field experiments were conducted at Kongsfjord in Ny Ålesund, Svalbard, where emissions from cruise ships were made, and at the port of Rotterdam, Netherlands, measuring emissions from more than 10 different container and cargo ships. In all cases SO2 path concentrations could be estimated and fluxes determined by measuring ship plume speeds simultaneously using the camera, or by using surface wind speed data from an independent source. Accuracies were compromised in some cases because of the presence of particulates in some ship emissions and the restriction of single-filter UV imagery, a requirement for fast-sampling (>10 Hz) from a single camera. Typical accuracies ranged from 10-30% in path concentration and 10-40% in flux estimation. Despite the ease of use and ability to determine SO2 fluxes from the UV camera system, the limitation in accuracy and precision suggest that the system may only be used under rather ideal circumstances and that currently the technology needs further development to serve as a method to monitor ship emissions for regulatory purposes.

  18. Indirect differential pulse voltammetric determination of aluminum by a pyrocatechol violet-modified electrode

    Energy Technology Data Exchange (ETDEWEB)

    Chen, G.; Bi, S.; Dai, L.; Cao, M.; Chen, Y. Wang, X. [Nanjing Univ. (China)

    1999-03-01

    Aluminum is one of the abundant elements in the earth`s crust. It has been considered to be a causative agent for various neurological disorders such as Alzheimer Senile, presenile dementia and amyotrophic lateral sclerosis. It is also very harmful to plants and aquatic organisms. Therefore, the determination of Al is very important. A Pyrocatechol Violet (PCV) modified electrode for the voltammetric determination of aluminum is reported. The modified electrode is simply prepared by dip-coating a pyrolytic graphite electrode in a NaAc-HAc buffer solution of PCV. Optimum experimental conditions for aluminum determination include a 0.2 mol/L NaAc-HAc buffer solution of pH 4.8, a PCV concentration of 0.02 mol/L used to modify the electrode and the use of differential-pulse mode for measurement. The peak currents of differential pulse voltammograms (DPV) decrease with the addition of Al into the buffer solution while the peak potentials remain the same. The decreasing value of peak current {Delta}i{sub p} is linear with Al concentration in the range of 1{times}10{sup {minus}8} to 1{times}10{sup {minus}7} mol/L and 1{times}10{sup {minus}7} to 1{times}10{sup {minus}6} mol/L. The detection limit is 5{times}10{sup {minus}9} mol/L and the relative standard deviation for 4{times}10{sup {minus}8} mol/L Al is 2.9% (n=8). The stability of this electrode is satisfactory. No serious interference is found. This method has been applied to determine Al in drinking water samples.

  19. Adsorption dynamics of methyl violet onto granulated mesoporous carbon: Facile synthesis and adsorption kinetics.

    Science.gov (United States)

    Kim, Yohan; Bae, Jiyeol; Park, Hosik; Suh, Jeong-Kwon; You, Young-Woo; Choi, Heechul

    2016-09-15

    A new and facile one-step synthesis method for preparing granulated mesoporous carbon (GMC) with three-dimensional spherical mesoporous symmetry is prepared to remove large molecular weight organic compounds in aqueous phase. GMC is synthesized in a single step using as-synthesized mesoporous carbon particles and organic binders through a simple and economical synthesis approach involving a simultaneous calcination and carbonization process. Characterization results obtained from SEM, XRD, as well as surface and porosity analysis indicate that the synthesized GMC has similar physical properties to those of the powdered mesoporous carbon and maintains the Brunauer-Emmett-Teller (BET) surface area and pore volume because the new synthesis method prevents the collapse of the pores during the granulation process. Batch adsorption experiments revealed GMC showed a substantial adsorption capacity (202.8 mg/g) for the removal of methyl violet as a target large molecular contaminant in aqueous phase. The mechanisms and dynamics modeling of GMC adsorption were also fully examined, which revealed that surface diffusion was rate limiting step on adsorption process of GMC. Adsorption kinetics of GMC enables 3 times faster than that of granular activated carbon in terms of surface diffusion coefficient. This is the first study, to the best of our knowledge, to synthesize GMC as an adsorbent for water purification by using facile granulation method and to investigate the adsorption kinetics and characteristics of GMC. This study introduces a new and simple method for the synthesis of GMC and reveals its adsorption characteristics for large molecular compounds in a water treatment. PMID:27262123

  20. Synthesis of SnO2-activated carbon fiber hybrid catalyst for the removal of methyl violet from water

    International Nuclear Information System (INIS)

    Graphical abstract: - Highlights: • A new biomass route for the synthesis of SnO2/ACF hybrid catalyst was proposed. • The original fibrous structure of kapok fiber was retained in the SnO2/ACF hybrid catalyst. • SnO2/ACF hybrid catalyst exhibited high BET surface area (647–897 m2/g) and large pore volume (0.36–0.56 cm3 g−1). • High microwave-induced catalytic activity for methyl violet degradation was obtained. - Abstract: SnO2/activated carbon fiber (ACF) hybrid catalyst was synthesized from kapok precursor via a two-step process involving pore-fabricating and self-assembly of SnO2 nanoparticles. The morphology and phase structure of the obtained samples were characterized by X-ray diffraction, field emission scanning electron microscope, high resolution transmission electron microscopy and N2 adsorption-desorption isotherm. These results demonstrated that the synthesized SnO2/ACF retained the hollow-fiber structure of kapok fibers. SnO2 nanoparticles dispersed uniformly over the ACF support. The obtained hybrid catalyst showed porous structure with high surface area (647–897 m2/g) and large pore volume (0.36–0.56 cm3 g−1). In addition, the catalytic activities of the obtained samples for methyl violet degradation under microwave irradiation were also evaluated. It was found that the SnO2/ACF catalyst exhibited high catalytic activity for methyl violet degradation due to the synergistic effect of microwave and SnO2/ACF catalyst

  1. Tuning emission in violet, blue, green and red in cubic GaN/InGaN/GaN quantum wells

    Science.gov (United States)

    Orozco Hinostroza, I. E.; Avalos-Borja, M.; Compeán García, V. D.; Zamora, C. Cuellar; Rodríguez, A. G.; López Luna, E.; Vidal, M. A.

    2016-02-01

    Light emission in the three primary colors was achieved in cubic GaN/InGaN/GaN heterostructures grown by molecular beam epitaxy on MgO substrates in a single growth process. A heterostructure with four quantum wells with a width of 10 nm was grown; this quantum wells width decrease the segregation effect of In. Photoluminescence emission produced four different emission signals: violet, blue, green-yellow and red. Thus, we were able to tune energy transitions in the visible spectrum modifying the In concentration in cubic InxGa1-xN ternary alloy.

  2. Crystal violet staining of Bordetella bronchiseptica colonies for differentiation of phase-I strains from variant strains in degraded phases.

    OpenAIRE

    Ishikawa, H.; Isayama, Y

    1997-01-01

    After 2 days of growth on Brain heart infusion agar (BHIA) at 38 degrees C, phase-I colonies and degraded-phase colonies of Bordetella bronchiseptica could be differentiated by their ability to take up crystal violet (CV). Phase-I colonies in X mode, but not colonies in degraded phases (phases II, III, and rough) bound CV. Phenotypically-altered C-mode colonies (grown at 32 degrees C or lower temperatures) also lacked this ability. CV staining offers an easy method for the recognition of diff...

  3. Double staining with crystal violet and methylene blue is appropriate for colonic endocytoscopy: An in vivo prospective pilot study

    OpenAIRE

    Ichimasa, Katsuro; Kudo, Shin-ei; Mori, Yuichi; Wakamura, Kunihiko; Ikehara, Nobunao; Kutsukawa, Makoto; Takeda, Kenichi; Misawa, Masashi; KUDO, TOYOKI; Miyachi, Hideyuki; Yamamura, Fuyuhiko; Ohkoshi, Shogo; Hamatani, Shigeharu; Inoue, Haruhiro

    2013-01-01

    Background and Aim Endocytoscopy (EC) at ultra-high magnification enables in vivo visualization of cellular atypia of gastrointestinal mucosae. Clear images are essential for precise diagnosis by EC. The aim of the present study was to evaluate the optimal staining method for EC in the colon. Methods Thirty prospectively enrolled patients were allocated 1:1:1 to three distinct staining methods: 0.05% crystal violet (CV) alone, 1% methylene blue (MB) alone, or CV + MB (CM double). Normal recta...

  4. Small particle reagent based on crystal violet dye for developing latent fingerprints on non-porous wet surfaces

    OpenAIRE

    Richa Rohatgi; G. S. Sodhi; Kapoor, A. K.

    2015-01-01

    Small particle reagent (SPR) is a widely used method for developing latent fingerprints on non-porous wet surfaces. SPR based on zinc carbonate hydroxide monohydrate, ZnCo3·2Zn(OH)2·H2O – also called basic zinc carbonate – has been formulated. The other ingredients of the formulation are crystal violet dye and a commercial liquid detergent. The composition develops clear, sharp and detailed fingerprints on non-porous items, after these were immersed separately in clean and dirty water for var...

  5. A new rapid colourimetric method for testing Mycobacterium tuberculosis susceptibility to isoniazid and rifampicin: a crystal violet decolourisation assay

    OpenAIRE

    Ahmet Yilmaz Coban

    2014-01-01

    The aim of this study was to investigate the performance of a new and accurate method for the detection of isoniazid (INH) and rifampicin (RIF) resistance among Mycobacterium tuberculosis isolates using a crystal violet decolourisation assay (CVDA). Fifty-five M. tuberculosis isolates obtained from culture stocks stored at -80ºC were tested. After bacterial inoculation, the samples were incubated at 37ºC for seven days and 100 µL of CV (25 mg/L stock solution) was then added to the control an...

  6. Induction of species-specific immunity against Schistosoma japonicum by exposure of rats to ultra-violet attenuated cercariae

    Energy Technology Data Exchange (ETDEWEB)

    Moloney, N.A.; Webbe, G.; Hinchcliffe, P.

    1987-02-01

    Single percutaneous immunizations of Fischer rats with 1000 ultra-violet attenuated Schistosoma japonicum cercariae induced 52-88% resistance to challenge 4 weeks later. Increasing this to 3 immunizations induced 90% resistance to challenge, and this level of protection remained undiminished for up to 40 weeks after vaccination. Rats vaccinated with gamma-irradiated S. mansoni cercariae were resistant to challenge with S. mansoni but not S. japonicum. Similarly rats vaccinated with u.v.-attenuated S. japonicum cercariae were not resistant to heterologous challenge. Thus irradiated vaccines are species-specific in both permissive and non-permissive hosts.

  7. The induction of species-specific immunity against Schistosoma japonicum by exposure of rats to ultra-violet attenuated cercariae

    International Nuclear Information System (INIS)

    Single percutaneous immunizations of Fischer rats with 1000 ultra-violet attenuated Schistosoma japonicum cercariae induced 52-88% resistance to challenge 4 weeks later. Increasing this to 3 immunizations induced 90% resistance to challenge, and this level of protection remained undiminished for up to 40 weeks after vaccination. Rats vaccinated with gamma-irradiated S. mansoni cercariae were resistant to challenge with S. mansoni but not S. japonicum. Similarly rats vaccinated with u.v.-attenuated S. japonicum cercariae were not resistant to heterologous challenge. Thus irradiated vaccines are species-specific in both permissive and non-permissive hosts. (author)

  8. UV-vis, IR and 1H NMR spectroscopic studies and characterization of ionic-pair crystal violet-oxytetracycline

    Science.gov (United States)

    Orellana, Sandra; Soto, César; Toral, M. Inés

    2010-01-01

    The present study shows the formation and characterization of the ionic-pair between the antibiotic oxytetracycline and the dye crystal violet in ammonia solution pH 9.0 ± 0.2 extracted into chloroform. The characterization was demonstrated using UV-vis spectrophotometry, 1H NMR, measurement of relaxation times T1 and IR spectroscopy, using a comparison between the signals of individual pure compounds with the signals with the mixture CV-OTC in different alkaline media. The formation of ionic-pair was also corroborated by new signals and chemical shifts. (2D) NMR spectroscopy experiments show that the interaction is electrostatic.

  9. Crystal Violet Lactone Salicylaldehyde Hydrazone Zn(II) Complex: a Reversible Photochromic Material both in Solution and in Solid Matrix

    Science.gov (United States)

    Li, Kai; Li, Yuanyuan; Tao, Jing; Liu, Lu; Wang, Lili; Hou, Hongwei; Tong, Aijun

    2015-09-01

    Crystal violet lactone (CVL) is a classic halochromic dye which has been widely used as chromogenic reagent in thermochromic and piezochromic systems. In this work, a very first example of CVL-based reversible photochromic compound was developed, which showed distinct color change upon UV-visible light irradiation both in solution and in solid matrix. Moreover, metal complex of CVL salicylaldehyde hydrozone was facilely synthesized, exhibiting reversible photochromic properties with good fatigue resistance. It was served as promising solid material for photo-patterning.

  10. Buffer and spectral characteristics of exyhemoglobin modified by guanidine hydrochloride and by long wave ultra violet radiation

    International Nuclear Information System (INIS)

    Studied are the buffer and spectral characteristics of oxyhemoglobin solutions, subjected to the action of guanidine hydrochloride and long wave ultra-violet radiation. The alkali buffer volume of protein is shown to increase at the action of 1-6 M guanidine, acidic buffer volume being decreased in the presence of 1 M guanidine. A conclusion is made that the quantity and states of ''binding centres'' of (H+) acid and (OH-) alkali and chromophore groups in oxyhemoglobin molecules in the result of modification by guanidine. Studied is the photosensitivity of conformative states of oxyhemoglobin arising under the guanidine effect

  11. Enhance Carrier Density Distributions between Double Quantum Wells Violet Ingan Laser Diode by Using Alingan as a Blocking Layer

    Energy Technology Data Exchange (ETDEWEB)

    Abdullah, Rafid A; Ibrahim, Kamarulazizi, E-mail: rafid_alabdali@yahoo.com, E-mail: kamarul@usm.my [Nano-Optoelectronics Research and Technology Laboratory (N.O.R), School of Physics, Universiti Sains Malaysia, 11800 Penang (Malaysia)

    2011-02-15

    Enhancement of carrier (electron and hole) density distributions between double quantum wells (QWs) violet InGaN laser diode (LD) has numerically been obtained by using quaternary AlInGaN as a blocking layer (BL) instead of conventional ternary AlGaN BL. Simulation results indicate that the quaternary BL has a higher refractive index and optical intensity inside the active region than the ternary BL which leads to reducing the threshold current of the LD from 16.42 mA with ternary BL to 13.67 mA with quaternary BL.

  12. 植物多酚与铬离子形成新型鞣剂的研究进展%Development of New Tanning Agent Made of Plant Polyphenols and Chrome Ions

    Institute of Scientific and Technical Information of China (English)

    潘红英; 王华; 陈武勇

    2009-01-01

    由于环保的要求,寻找一种替代纯铬鞣的新型鞣剂或鞣法显得极有必要,而植物鞣剂作为一种天然鞣剂能够满足要求.本文主要论述两种不同的方法使植鞣荆降解,然后进行植铬结合鞣.一种是植物鞣剂先酸化降解,因为酸化降解产物具有还原、蒙囿以及与金属离子络合的作用,与Cr(Ⅵ)发生氧化还原作用,形成新的铬鞣剂.另外一种是植物多酚被氧化降解改性,进行植铬结合鞣.通过这些方法既减少了铬的用量,又有较好的鞣革性能.%Due to the environmental requirements, searching for an alternative new tannage or method of tanning to the pure chrome is necessary. Vegetable tannin can meet the needs as a natural tannage. In this paper, primarily summarizes two different ways to modify vegetable tannin, then the modified products can be applied to the vegetable tannin-chrome combination tannage. Vegetable tannin is degraded by the acid. The degradation products have a better masking ability, and have good complex properties with the metal ions. Chromium (Ⅵ)can be reduced to produce chrome tanning agent by the product which can be obtained by hydrolyzing hydrolysable tannin . The plant polyphenols can be modified by the oxidization degradation. The oxidization degradation products can be applied to the vegetable tannin-chrome combination tannin. Using these methods can not only reduce the amount of chrome, but also have better tanned leather property.

  13. Parallel between steels alloyed with chrome-nickel and Fe-Mn-Al-C steels, in their response to fracture and wear (Review)

    International Nuclear Information System (INIS)

    The big worldwide demand for chrome-nickel alloy steels ('conventional steel') leads to the need for advanced materials for applications in different engineering systems that operate at high temperatures and in aggressive environmental conditions, favoring research and development in alternate alloys. In this technological race in search of these new materials, the FeMnAlC alloys ('new steels') have attracted attention for their excellent mechanical and tribological properties as well as for their good performance in corrosive-oxide environments, which make them similar to conventional steel. There are two important similarities between these two steels. First, an agent that causes the passive film to become stainless appears in both steels: chrome in the conventional steel, and aluminum in the FeMnAl alloy. The second similarity is that a stabilizing agent of the austenitic phase (FCC) appears in both, so that excellent mechanical properties can be obtained: nickel in the conventional steel, and manganese in the FeMnAl alloy. In certain sectors, such as aeronautics, conventional steel is rarely used because it is a very heavy material. This conventional steel is almost three times heavier that aluminum (7.85/2.7). Two advantages that the new FeMnAIC steels have compared to the conventional steels are that they are about 13% lighter in weight and they are less expensive. The FeMnAl also have excellent mechanical properties and good corrosion-oxidation resistance, which generates big expectations for their application in a broad scientific spectrum. This work reports the state of the information currently available about FeMnAlC alloys, comparing the mechanical and tribological behaviors of conventional alloy steels with chrome and nickel alloys, specifying the scopes of their application. A condition that favors the steels' fragility is the high speed of deformation and impact, where the FCC crystalline structure materials do not have a fragile ductile transition

  14. Structure and function of the liver in conditions of chrome-isoniazid-rifampicin affection of rats after applying of sorbex

    Directory of Open Access Journals (Sweden)

    N. I. Burmas

    2014-09-01

    Full Text Available The aim of this research was to assess the activity of marker enzymes of the liver and its biliary formation function in conditions of the affection of animals by hexavalent chromium compounds, isoniazid and rifampicin, after applying of sorbex. The experimental affection of rats of different age was carried in the conditions of combined injection of hexavalent chromium compounds (solution of potassium dichromate, 3 mg/kg, isoniazid (0.05 g/kg and rifampicin (0.25 g/kg during the 7th and 14th days, and sorbex enterosorbent was introduced in quantity of 150 mg/kg. The activity of marker enzymes of the liver was evaluated by the activity of alanine and aspartate aminotransferases (ALT and AST and alkaline phosphatase (ALP. The state of biliary formation function of the liver was evaluated by the content of total bilirubin (TB and bile acids (BA in blood. The most significant changes in ALT activity were observed in the liver of old animals by the combined effects of the abovementioned xenobiotics – the activity of ALT was decreased by the end of the experiment by 58% compared with the animals of intact control. Using of sorbex led to decreasing in blood serum and increasing in the liver of affected animals of the different age of ALT activity throughout the experiment. AST activity in blood serum increased, and it was the highest in old animals upon chrome-isoniazid-rifampicin affection on the 14th day of the research. With the use of sorbex, there was a tendency to normalization of this index in blood serum and liver of affected animals on the 7th day from the beginning of the experiment. It was found that the largest increase in ALP took place in blood serum of immature animals by the combined effects of toxicants. In the liver of affected animals the activity of ALP decreased throughout the experiment in all age groups of animals. Maximum corrective effect on the activity of ALP was shown by the enterosorbent in the liver of mature animals on

  15. Polyether Silicone Oil on Pre- fatliquoring in Chrome Tanning Process%铬鞣工艺中聚醚硅油的预加脂应用研究

    Institute of Scientific and Technical Information of China (English)

    常国勋; 郭晓琴; 高晓鸣; 陈磊; 张廷有; 李正军

    2012-01-01

    The pickled goatskin was pre- fatliquored with the polyether silicone oil and mechanical performance, such as the softness, smoothness, shrinkage temperature, specific surface area, etc. was measured. And the results indicate that polyether silicone leather fibers. before the chrome tanning. The physical water - vapor permeability, porosity and oil give the high soften performance to the leather fibers.%采用聚醚硅油预加脂处理浸酸皮后进行铬鞣,获得了高度柔软且质轻的铬鞣革,对革的感观性能、收缩温度、物理力学性能、透水汽性,以及孔隙率、比表面积等的检测结果表明,聚醚硅油对革纤维具有高效能柔软作用。

  16. Thidiazuron induces shoot organogenesis at low concentrations and somatic embryogenesis at high concentrations on leaf and petiole explants of African violet (Saintpaulia ionantha Wendl).

    Science.gov (United States)

    Mithila, J; Hall, J C; Victor, J M R; Saxena, P K

    2003-01-01

    Regeneration via shoot organogenesis and somatic embryogenesis was observed from thidiazuron (TDZ)-treated leaf and petiole explants of greenhouse- and in vitro-grown African violet plants. The response of cultures to other growth regulators over a range of 0.5 microM to 10 microM was 50% less than that observed with TDZ. A comparative study among several cultivars of African violet indicated that "Benjamin" and "William" had the highest regeneration potential. In "Benjamin", higher frequencies of shoot organogenesis (twofold) and somatic embryogenesis (a 50% increase) were observed from in vitro- and greenhouse-grown plants, respectively. At concentrations lower than 2.5 microM, TDZ induced shoot organogenesis, whereas at higher doses (5-10 microM) somatic embryos were formed. These findings provide the first report of simultaneous shoot organogenesis and somatic embryogenesis of African violet explants in response to TDZ. PMID:12789442

  17. A novel electrochemical sensor for the analysis of β-agonists: The poly(acid chrome blue K)/graphene oxide-nafion/glassy carbon electrode

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Xiaoyun [State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047 (China); Ni, Yongnian, E-mail: ynni@ncu.edu.cn [State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047 (China); Department of Chemistry, Nanchang University, Nanchang 330031 (China); Kokot, Serge, E-mail: s.kokot@qut.edu.au [School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology, Brisbane 4001 (Australia)

    2013-09-15

    Graphical abstract: A new modified electrode was constructed by the electro-polymerization of acid chrome blue K (ACBK) at a graphene-nafion modified glassy carbon electrode (GCE). The novel electrode was successfully employed for the analysis of eight β-agonist analytes with high sensitivity. -- Highlights: • Construction of the poly-ACBK/graphene-nafion/GCE. •The modified electrode showed high sensitivity for the analysis of the β-agonists. • A novel method was successfully developed for the analysis of clenbuterol in pork. • Research provided a new method of constructing electrodes for biological analysis. -- Abstract: A novel modified electrode was constructed by the electro-polymerization of 4,5-dihydroxy-3-[(2-hydroxy-5-sulfophenyl)azo]-2,7-naphthalenedisulfonic acid trisodium salt (acid chrome blue K (ACBK)) at a graphene oxide (GO)-nafion modified glassy carbon electrode (GCE). The characterization of an electrochemically synthesized poly-ACBK/GO-nafion film was investigated by electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), atomic force microscopy (AFM) and scanning electron microscopy (SEM) techniques, and the results were interpreted and compared at each stage of the electrode construction. Electrochemical oxidation of eight β-agonists – clenbuterol, salbutamol, terbutaline, ractopamine, dopamine, dobutamine, adrenaline, and isoprenaline, was investigated by CV at the different electrodes. At the poly-ACBK/GO-nafion/GCE, the linear sweep voltammetry peak currents of the eight β-agonists increased linearly with their concentrations in the range of 1.0–36.0 ng mL{sup −1}, respectively, and their corresponding limits of detection (LODs) were within the 0.58–1.46 ng mL{sup −1} range. This electrode showed satisfactory reproducibility and stability, and was used successfully for the quantitative analysis of clenbuterol in pork samples.

  18. A novel electrochemical sensor for the analysis of β-agonists: The poly(acid chrome blue K)/graphene oxide-nafion/glassy carbon electrode

    International Nuclear Information System (INIS)

    Graphical abstract: A new modified electrode was constructed by the electro-polymerization of acid chrome blue K (ACBK) at a graphene-nafion modified glassy carbon electrode (GCE). The novel electrode was successfully employed for the analysis of eight β-agonist analytes with high sensitivity. -- Highlights: • Construction of the poly-ACBK/graphene-nafion/GCE. •The modified electrode showed high sensitivity for the analysis of the β-agonists. • A novel method was successfully developed for the analysis of clenbuterol in pork. • Research provided a new method of constructing electrodes for biological analysis. -- Abstract: A novel modified electrode was constructed by the electro-polymerization of 4,5-dihydroxy-3-[(2-hydroxy-5-sulfophenyl)azo]-2,7-naphthalenedisulfonic acid trisodium salt (acid chrome blue K (ACBK)) at a graphene oxide (GO)-nafion modified glassy carbon electrode (GCE). The characterization of an electrochemically synthesized poly-ACBK/GO-nafion film was investigated by electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), atomic force microscopy (AFM) and scanning electron microscopy (SEM) techniques, and the results were interpreted and compared at each stage of the electrode construction. Electrochemical oxidation of eight β-agonists – clenbuterol, salbutamol, terbutaline, ractopamine, dopamine, dobutamine, adrenaline, and isoprenaline, was investigated by CV at the different electrodes. At the poly-ACBK/GO-nafion/GCE, the linear sweep voltammetry peak currents of the eight β-agonists increased linearly with their concentrations in the range of 1.0–36.0 ng mL−1, respectively, and their corresponding limits of detection (LODs) were within the 0.58–1.46 ng mL−1 range. This electrode showed satisfactory reproducibility and stability, and was used successfully for the quantitative analysis of clenbuterol in pork samples

  19. Steam generator with straight double-walled tube - Development of fabrication technologies of main structures made of high chrome steel-made -

    International Nuclear Information System (INIS)

    Steam generator (SG) with straight double-walled tube is adopted for the Japan Sodium-Cooled Fast Reactor (JSFR). This paper describes the research and development of the SG with straight double-walled tube. To improve reliability of the plant against sodium-water reaction caused by SG tube failure, the Double-walled tube is adopted. Double-walled tubes consist of inner and outer tubes, and they are mechanically contacted each other. They have small clearance between inner and outer tubes, and reduce penetration leakage (of pressurized water) due to high flow resistance across the clearance in the event that both inner and outer tube leak at different point. Using high chrome steel, which has high strength at elevated temperatures and has a high thermal conductivity, as the material for SG tubes reduces the area of heat-transfer surface. By adopting high chrome steel, which has also tolerance to stress corrosion cracking (SCC), the SG is designed as a once-through type generator, enabling a reduction in the component number. It is important to keep high reliability without incurring a performance penalty. Therefore we put a cap on the amount of clearance and design to keep contact in operating conditions. Since double-walled tube, welded joint between tube and tube sheet, etc. are special specification and shape, it is necessary to develop these fabrication technologies such as welder for narrow space. Double-walled tubes of 10m length were manufactured for trial,and processability, clearance size and so on were confirmed. About welded joint between tube and tube sheet, tests of welding and tube expansion against tube sheet were performed, and these works and strength data were acquired. Since Double-walled tube is thick for its small diameter, expansion is quite difficult. Therefore we are going to survey best condition for Double-walled tube

  20. Fixed-bed column studies on biosorption of crystal violet from aqueous solution by Citrullus lanatus rind and Cyperus rotundus

    Science.gov (United States)

    Bharathi, Kandaswamy Suyamboo; Ramesh, SriKrishna Perumal Thanga

    2013-12-01

    In this study, fixed-bed column experiments were performed to investigate the biosorption potential of two agricultural wastes, Citrullus lanatus rind and Cyperus rotundus to remove Crystal violet (CV) from aqueous solution. The experiments were conducted to study the effects of important parameters such as bed depth (10-30 cm), flow rate (10-20 mL min-1) and initial dye concentration (10-25 mg L-1). Different models like Bed Depth Service Time (BDST) model, Thomas model and Yoon-Nelson model were applied to the experimental sorption data. In the biosorption of Crystal violet by both the sorbents, the BDST model fitted well with the experimental data in the initial region of the breakthrough curve. Also, Yoon-Nelson model was found to show good agreement with the experimental kinetic results as compared to the Thomas model. The sorbents were found to be very potential, as it showed good sorption capacities of 46.68 and 54.24 mg g-1 for CV biosorption by Citrullus lanatus rind and Cyperus rotundus. Recovery of dye was made by eluting 1 N CH3COOH through the exhausted column in downward direction.

  1. Near-zone sizes and the rest frame extreme ultra-violet spectral index of the highest redshift quasars

    CERN Document Server

    Wyithe, Stuart

    2010-01-01

    The discovery of quasars with redshifts higher than six has prompted a great deal of discussion in the literature regarding the role of quasars, both as sources of reionization, and as probes of the ionization state of the IGM. However the extreme ultra-violet (EUV) spectral index cannot be measured directly for high redshift quasars owing to absorption at frequencies above the Lyman limit, and as a result, studies of the impact of quasars on the intergalactic medium during reionization must assume a spectral energy distribution in the extreme ultra-violet based on observations at low redshift, z<1. In this paper we use regions of high Ly-alpha transmission (near-zones) around the highest redshift quasars to measure the quasar EUV spectral index at z~6. We jointly fit the available observations for variation of near-zone size with both redshift and luminosity, and propose that the observed relation provides evidence for an EUV spectral index that varies with absolute magnitude in the high redshift quasar s...

  2. Acid violet 6B as a novel corrosion inhibitor for cold rolled steel in hydrochloric acid solution

    International Nuclear Information System (INIS)

    Research highlights: → Acid violet 6B (AV6B) is found to be a good inhibitor for the corrosion of CRS in 1.0 M HCl. → Effects of hydrochloric acid concentration (1.0 - 5.0 M) and immersion time (2 - 144 h) are discussed in detail. → The corrosion inhibition is satisfactorily discussed by both thermodynamic and kinetic parameters. → AV6B acts as a mixed-type inhibitor. → The adsorption of AV6B obeys Langmuir adsorption isotherm. - Abstract: The inhibition effect of acid violet 6B (AV6B) on the corrosion of cold rolled steel (CRS) in 1.0-5.0 M HCl solution was studied for the first time by weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) methods. The results show that AV6B is a very good inhibitor in 1.0 M HCl, and the adsorption of AV6B on CRS surface obeys Langmuir adsorption isotherm. Polarization curves reveal that AV6B behaves as a mixed-type inhibitor. EIS spectra exhibit one capacitive loop and confirm the inhibitive ability. Effects of immersion time and acid concentration on inhibition performance were also discussed.

  3. 2-Chlorophenol Removal of Aqueous Solution Using Advanced Oxidation Processes Resulting from Iron/ Persulfate and Ultra Violet/ Persulfate

    Directory of Open Access Journals (Sweden)

    Shokufeh Astereki

    2016-06-01

    Full Text Available Background: Advanced oxidation processes are used to remove toxic aromatic compounds with low biodegradability, such as 2-chlorophenol. This study investigated the use of sulfate (SO4- and persulfate (S2O82- radicals, as one of the advanced oxidation methods, to remove 2- chlorophenol from aquatic solutions. Methods: This experimental and pilot-scale study was carried out using two chemical batch reactors; one of the reactors equipped with UV lamps and the other was on the hot plate. In iron/ persulfate (Fe/S2O82- and ultra violet/ persulfate (UV/S2O82- processes different parameters were investigated. Results: Iron, UV, the initial pH of the solution, persulfate concentration have considerable effects on the elimination of 2-chlorophenol in both processes. In both processes, the maximum elimination occurred in acidic conditions. The elimination efficiency was increased by increasing the concentration of 2-chlorophenol and UV intensity, and also by decreasing the concentration of persulfate and iron. Accordingly, in iron/ persulfate and ultra violet/ persulfate processes 2-chlorophenol was eliminated with 99.96% and 99.58% efficiencies, respectively. Conclusion: Sulfate radicals produced from activated persulfate ions with hot-Fe ion and UV radiation have significant impact on the removal of 2-chlorophenol. Therefore, the processes of Fe/S2O82- and UV/S2O82- can be regarded as good choices for industrial wastewater treatment plants operators in the future.

  4. The relationship between the violet pigment PP-V production and intracellular ammonium level in Penicillium purpurogenum.

    Science.gov (United States)

    Kojima, Ryo; Arai, Teppei; Matsufuji, Hiroshi; Kasumi, Takafumi; Watanabe, Taisuke; Ogihara, Jun

    2016-12-01

    Penicillium purpurogenum is the fungus that produces an azaphilone pigment. However, details about the pigment biosynthesis pathway are unknown. The violet pigment PP-V is the one of the main pigments biosynthesized by this fungus. This pigment contains an amino group in a pyran ring as its core structure. We focused on this pigment and examined the relationship between intracellular ammonium concentration and pigment production using glutamine as a nitrogen source. The intracellular ammonium level decreased about 1.5-fold in conditions favoring PP-V production. Moreover, P. purpurogenum was transferred to medium in which it commonly produces the related pigment PP-O after cultivating it in the presence or absence of glutamine to investigate whether this fungus biosynthesizes PP-V using surplus ammonium in cells. Only mycelia cultured in medium containing 10 mM glutamine produced the violet pigment, and simultaneously intracellular ammonium levels decreased under this condition. From comparisons of the amount of PP-V that was secreted with quantity of surplus intracellular ammonium, it is suggested that P. purpurogenum maintains ammonium homeostasis by excreting waste ammonium as PP-V. PMID:27368914

  5. Evaluation of crystal violet decolorization assay for minimal inhibitory concentration detection of primary antituberculosis drugs against Mycobacterium tuberculosis isolates.

    Science.gov (United States)

    Coban, Ahmet Yilmaz; Akbal, Ahmet Ugur; Uzun, Meltem; Cayci, Yeliz Tanriverdi; Birinci, Asuman; Durupinar, Belma

    2016-06-10

    In this study we evaluated the crystal violet decolorization assay (CVDA) for detection of minimum inhibitory concentration (MIC) of antituberculosis drugs. 53 isolates were tested in this study and 13 of them were multidrug resistant (MDR) isolates. The antibiotics concentrations were 2-0.06 mg/L for isoniazid (INH) and rifampicin (RIF) and were 16-0.25 mg/L for streptomycin (STM) and ethambutol (EMB). Crystal violet (CV-25 mg/L) was added into the microwells on the seventh day of incubation and incubation was continued until decolorization. Decolorization of CV was the predictor of bacterial growth. Overall agreements for four drugs were detected as 98.1%, and the average time was detected as 9.5 ± 0.89 day after inoculation. One isolate for INH and two isolates for STM were determined resistant in the reference method, but susceptible by the CVDA. One isolate was susceptible to EMB by the reference method, but resistant by the CVDA. All results were concordant for RIF. This study shows that CVDA is a rapid, reliable and suitable for determination of MIC values of Mycobacterium tuberculosis. And it can be used easily especially in countries with limited-sources. PMID:27304025

  6. Adsorption of Acid Yellow-73 and Direct Violet-51 Dyes from Textile Wastewater by Using Iron Doped Corncob Charcoal

    International Nuclear Information System (INIS)

    The presence of synthetic dyes in textile industry wastewater lead to deterioration of precious fresh water resources, making the need to remove dyes crucial for environmental protection. Recently, different techniques have been employed to remove these dyes from water resources. Among them, biosorption has gained tremendous popularity due to its eco-friendly nature and inexpensive method. In this study, the removal potential of two acid dyes, i.e. yellow-73 and direct violet-51, was assessed from textile effluent samples using iron modified corncob charcoal. The adsorption efficiency ranged between 93.93 97.96 % and 92.2 - 95.4 % for acid yellow-73 and direct violet-51, respectively. Furthermore, study highlights optimum parameters for successful adsorption of these dyes, such as stirring time (numbers), pH (numbers), temperature (numbers), and adsorbent dosage (numbers). Keeping in consideration these findings, we recommend the use of Iron Doped Corncob Charcoal (IDCC) as a low-cost, efficient alternative for wastewater treatment, primarily minimizing the detrimental effects of hazardous dyes. (author)

  7. Reproductive biology of the violet-chested hummingbird in Venezuela and comparisons with other tropical and temperate hummingbirds

    Science.gov (United States)

    Fierro-Calderon, K.; Martin, T.E.

    2007-01-01

    We provide details on the breeding biology of the Violet-chested Hummingbird (Sternoclyta cyanopectus) based on 67 nests studied in Yacambu?? National Park, Venezuela, from 2002 through 2006. Clutch size was two white eggs, usually laid every other day. Fresh egg mass (0.95 ?? 0.14 g) was 15% of female mass. Incubation and nestling periods were 20.4 ?? 0.3 and 26.0 ?? 0.4 days, respectively. Nest attentiveness increased from 60% in early incubation to 68% in late incubation. The female spent 50% of her time brooding young nestlings, but ceased brooding by 13 days of age. Only the female fed the young, with a low rate of nest visitation (3.3 trips per hour) that did not increase with age of the young. Growth rate based on nestling mass (K = 0.28) was slow. Daily predation rates decreased across stages and were 0.064 ?? 0.044, 0.033 ?? 0.008, and 0.020 ?? 0.006 during the egg-laying, incubation, and nestling periods, respectively. Most, but not all, life history traits of the Violet-chested Hummingbird were similar to those reported for other tropical and temperate hummingbirds, providing further evidence that this family shows a relatively narrow range of life history variation. ?? The Cooper Ornithological Society 2007.

  8. Using violet laser-induced chlorophyll fluorescence emission spectra for crop yield assessment of cowpea (Vigna unguiculata (L) Walp) varieties

    Science.gov (United States)

    Anderson, Benjamin; Buah-Bassuah, Paul K.; Tetteh, Jonathan P.

    2004-07-01

    The use of violet laser-induced chlorophyll fluorescence (LICF) emission spectra to monitor the growth of five varieties of cowpea in the University of Cape Coast Botanical Garden is presented. Radiation from a continuous-wave violet laser diode emitting at 396 nm through a fibre is closely incident on in vivo leaves of cowpea to excite chlorophyll fluorescence, which is detected by an integrated spectrometer with CCD readout. The chlorophyll fluorescence spectra with peaks at 683 and 731 nm were used for growth monitoring of the cowpea plants over three weeks and analysed using Gaussian spectral functions with curve fitted parameters to determine the peak positions, area under the spectral curve and the intensity ratio F683/F731. The variation in the intensity ratio of the chlorophyll bands showed sensitive changes indicating the photosynthetic activity of the cowpea varieties. A discussion of the fluorescence result as compared to conventional assessment is presented with regard to discrimination between the cowpea varieties in terms of crop yield performance.

  9. Exposure to Crystal Violet, Its Toxic, Genotoxic and Carcinogenic Effects on Environment and Its Degradation and Detoxification for Environmental Safety.

    Science.gov (United States)

    Mani, Sujata; Bharagava, Ram Naresh

    2016-01-01

    Crystal Violet (CV), a triphenylmethane dye, has been extensively used in human and veterinary medicine as a biological stain, as a textile dye in textile processing industries and also used to provide a deep violet color to paints and printing ink. CV is also used as a mutagenic and bacteriostatic agent in medical solutions and antimicrobial agent to prevent the fungal growth in poultry feed. Inspite of its many uses, CV has been reported as a recalcitrant dye molecule that persists in environment for a long period and pose toxic effects in environment. It acts as a mitotic poison, potent carcinogen and a potent clastogene promoting tumor growth in some species of fish. Thus, CV is regarded as a biohazard substance. Although, there are several physico-chemical methods such as adsorption, coagulation and ion-pair extraction reported for the removal of CV, but these methods are insufficient for the complete removal of CV from industrial wastewaters and also produce large quantity of sludge containing secondary pollutants. However, biological methods are regarded as cost-effective and eco-friendly for the treatment of industrial wastewaters, but these methods also have certain limitations. Therefore, there is an urgent need to develop such eco-friendly and cost-effective biological treatment methods, which can effectively remove the dye from industrial wastewaters for the safety of environment, as well as human and animal health. PMID:26613989

  10. Ultra-violet radiation is responsible for the differences in global epidemiology of chickenpox and the evolution of varicella-zoster virus as man migrated out of Africa

    Directory of Open Access Journals (Sweden)

    Rice Philip S

    2011-04-01

    Full Text Available Abstract Background Of the eight human herpes viruses, varicella-zoster virus, which causes chickenpox and zoster, has a unique epidemiology. Primary infection is much less common in children in the tropics compared with temperate areas. This results in increased adult susceptibility causing outbreaks, for example in health-care workers migrating from tropical to temperate countries. The recent demonstration that there are different genotypes of varicella-zoster virus and their geographic segregation into tropical and temperate areas suggests a distinct, yet previously unconsidered climatic factor may be responsible for both the clinical and molecular epidemiological features of this virus infection. Presentation of the hypothesis Unlike other human herpes viruses, varicella-zoster virus does not require intimate contact for infection to occur indicating that transmission may be interrupted by a geographically restricted climatic factor. The factor with the largest difference between tropical and temperate zones is ultra-violet radiation. This could reduce the infectiousness of chickenpox cases by inactivating virus in vesicles, before or after rupture. This would explain decreased transmissibility in the tropics and why the peak chickenpox incidence in temperate zones occurs during winter and spring, when ultra-violet radiation is at its lowest. The evolution of geographically restricted genotypes is also explained by ultra-violet radiation driving natural selection of different virus genotypes with varying degrees of resistance to inactivation, tropical genotypes being the most resistant. Consequently, temperate viruses should be more sensitive to its effects. This is supported by the observation that temperate genotypes are found in the tropics only in specific circumstances, namely where ultra-violet radiation has either been excluded or significantly reduced in intensity. Testing the Hypothesis The hypothesis is testable by exposing

  11. In vitro cytotoxicity of Acanthamoeba spp. isolated from contact lens containers in Korea by crystal violet staining and LDH release assay

    OpenAIRE

    Shin, Ho-Joon; Cho, Myung-Soo; Jung, Suk-Yul; Kim, Hyung-Il; Im, Kyung-il

    2000-01-01

    In order to observe the cytotoxicity of Acanthamoeba spp., which were isolated from contact lens containers as ethiological agents for the probable amoebic keratitis in Korea, the crystal violet staining method and LDH release assay were carried out. In the crystal violet staining method, among eight contact lens container isolates, isolate 3 (Acanthamoeba KA/LS5) showed 83.6% and 81.8% of cytotoxicity, and isolate 7 (Acanthamoeba KA/LS37) showed 28.2% and 25.1% of cytotoxicity, in 1 mg/ml an...

  12. Comparison of staining of mitotic figures by haematoxylin and eosin-and crystal violet stains, in oral epithelial dysplasia and squamous cell carcinoma

    Directory of Open Access Journals (Sweden)

    Ankle Madhuri

    2007-01-01

    Full Text Available Mitosis of cells gives rise to tissue integrity. Defects during mitosis bring about abnormalities. Excessive proliferation of cells due to increased mitosis is one such outcome, which is the hallmark in precancer and cancer. The localization of proliferating cells or their precursors may not be obvious and easy. Establishing an easy way to distinguish these mitotic cells will help in grading and understanding their biological potential. Although immunohistochemistry is an advanced method in use, the cost and time factor makes it less feasible for many laboratories. Selective histochemical stains like toluidine blue, giemsa and crystal violet have been used in tissues including the developing brain, neural tissue and skin. Aim of the study: 1To compare the staining of mitotic cells in haematoxylin and eosin with that in crystal violet. 2To compare the number of mitotic figures present in normal oral mucosa, epithelial dysplasia and oral squamous cell carcinoma in crystal violet-stained sections with that in H and E-stained sections. Materials and Methods: Ten tissues of normal oral mucosa and 15 tissues each of oral epithelial dysplasia seen in tobacco-associated leukoplakia and squamous cell carcinoma were studied to evaluate the selectivity of 1% crystal violet for mitotic figures. The staining was compared with standard H and E staining. Statistical analysis was done using Man-Whitney U test. Results: A statistically significant increase in the mean mitotic count was observed in crystal violet-stained sections of epithelial dysplasia as compared to the H and E-stained sections ( p = 0.0327. A similar increase in the mitotic counts was noted in crystal violet-stained sections of oral squamous cell carcinoma as compared to the H and E-stained sections.( p = 0.0443. No significant difference was found in the mitotic counts determined in dysplasia or carcinoma by either the crystal violet ( p = 0.4429 or the H and E-staining techniques ( p = 0

  13. Continuous-wave violet generation at 373.5 nm by frequency-doubled power-scaled near-infrared emitting Pr:YAlO3 laser

    International Nuclear Information System (INIS)

    We report on a continuous-wave Pr:YAlO3 laser operating at a wavelength of 373.5 nm in a power-scaled resonator arrangement. Violet light generation has been achieved by intracavity frequency doubling of the near-infrared emitting Pr:YAP laser at a fundamental wavelength of 747 nm. For active medium pumping, two GaN laser diodes providing up to 1 W of output power each at 448 nm were used. By employing BBO crystal as a nonlinear medium, more than 46 mW of violet radiation has been obtained. (letter)

  14. Continuous-wave violet generation at 373.5 nm by frequency-doubled power-scaled near-infrared emitting Pr:YAlO3 laser

    Science.gov (United States)

    Fibrich, Martin; Jelínková, Helena

    2013-10-01

    We report on a continuous-wave Pr:YAlO3 laser operating at a wavelength of 373.5 nm in a power-scaled resonator arrangement. Violet light generation has been achieved by intracavity frequency doubling of the near-infrared emitting Pr:YAP laser at a fundamental wavelength of 747 nm. For active medium pumping, two GaN laser diodes providing up to 1 W of output power each at 448 nm were used. By employing BBO crystal as a nonlinear medium, more than 46 mW of violet radiation has been obtained.

  15. Ultra-Violet Light Treatment Lowers Numbers of Listeria monocytogenes on Raw Chicken Fillets without Changing Antibiotic Resistance or Meat Color

    Science.gov (United States)

    Listeria monocytogenes is an important foodborne pathogen and raw poultry meat has been shown to be a vector for its entrance into a poultry further-processing plant. Reduction of L. monocytogenes in these plants is a high priority for the industry. Ultra-violet (UV) light at a wavelength of 254 n...

  16. Ultraviolet/violet dual-color electroluminescence based on n-ZnO single crystal/p-GaN direct-contact light-emitting diode

    International Nuclear Information System (INIS)

    We have fabricated a fully transparent ultraviolet (UV)/violet dual-color electroluminescence (EL) device based on n-ZnO single crystal and p-GaN via a simple direct-contact method. The device presents dual-color EL under forward and reverse biases—an intense violet emission centered at 400 nm from ZnO and a sharp UV emission peaked at 365 nm from GaN, respectively. The reason for dual color emissions is proposed in terms of the energy band theory and the transmission spectra of ZnO single crystal and p-GaN. -- Highlights: ► A fully transparent LED based on n-ZnO SC and p-GaN is fabricated via the direct-contact method. ► The n-ZnO SC/p-GaN device shows UV/violet dual-color emission under electrically pumped. ► The device presents a violet emission 400 nm and a UV emission 365 nm under forward and reverse biases. ► The EL of the dual-color device displays good stability and reproducibility

  17. Fluorescence, Decay Time, and Structural Change of Laser Dye Cresyl Violet in Solution due to Microwave Irradiation at GSM 900/1800 Mobile Phone Frequencies

    Directory of Open Access Journals (Sweden)

    Fuat Bayrakceken

    2012-01-01

    Full Text Available Microwave irradiation at GSM 900/1800 MHz mobile phone frequencies affects the electronic structure of cresyl violet in solution. These changes are important because laser-dye cresyl violet strongly bonds to DNA- and RNA-rich cell compounds in nerve tissues. The irradiation effects on the electronic structure of cresyl violet and its fluorescence data were all obtained experimentally at room temperature. For most laser dyes, this is not a trivial task because laser dye molecules possess a relatively complex structure. They usually consist of an extended system of conjugated double or aromatic π-bonds with attached auxochromic (electron donating groups shifting the absorption band further towards longer wavelength. Because of the intrinsically high degree of conjugation, the vibrational modes of the molecular units couple strongly with each other. We found that the fluorescence quantum yield was increased from to due to intramolecular energy hopping of cresyl violet in solution which is exposed to microwave irradiation at mobile phone frequencies, and the photonic product cannot be used as a laser dye anymore.

  18. A High Power InGaN-Based Blue-Violet Laser Diode Array with a Broad-Area Stripe

    International Nuclear Information System (INIS)

    An array of high power InGaN/GaN multi-quantum-well laser diodes with a broad waveguide is fabricated. The laser diode structure is grown on a GaN substrate by metal-organic chemical vapor deposition. The laser diode array consists of five emitter stripes which share common electrodes on one laser chip. The electrical and optical characteristics of the laser diode array are investigated under the pulse current injection with 10kHz frequency and 100 ns pulse width. The laser diode array emits at the wavelength of 409 nm, which is located in the blue-violet region, and the threshold current is 2.9 A. The maximum output light peak power is measured to be 7.5 W at the wavelength of 411.8 nm under the current of 25 A

  19. Small particle reagent based on crystal violet dye for developing latent fingerprints on non-porous wet surfaces

    Directory of Open Access Journals (Sweden)

    Richa Rohatgi

    2015-12-01

    Full Text Available Small particle reagent (SPR is a widely used method for developing latent fingerprints on non-porous wet surfaces. SPR based on zinc carbonate hydroxide monohydrate, ZnCo3·2Zn(OH2·H2O – also called basic zinc carbonate – has been formulated. The other ingredients of the formulation are crystal violet dye and a commercial liquid detergent. The composition develops clear, sharp and detailed fingerprints on non-porous items, after these were immersed separately in clean and dirty water for variable periods of time. The ability of the present formulation to detect weak and faint chance prints not only enhances its utility, but also its potentiality in forensic case work investigations. The raw materials used to prepare the SPR are cost-effective and non-hazardous.

  20. Adsorption and subsequent partial photodegradation of methyl violet 2B on Cu/Al layered double hydroxides

    Science.gov (United States)

    Guzmán-Vargas, Ariel; Lima, Enrique; Uriostegui-Ortega, Gisselle A.; Oliver-Tolentino, Miguel A.; Rodríguez, Esaú E.

    2016-02-01

    Uncalcined Cu/Al LDH was studied as adsorbent and photocatalyst in the adsorption and subsequent photodegradation of methyl violet 2B dye (MV2B). Physicochemical characterization was carried out by XRD, FTIR, UV-vis, including photoactive properties, DSC/TGA and SEM. Kinetic and thermodynamic models showed great affinity and sorption capacity, the maximum adsorption capacity was 361.0 mg g-1 obtained by Langmuir model, in addition, the results showed that the dye was adsorbed on the LDH surface. Photocatalytic activity was evaluated in the MV2B dye photodegradation process, and it was confirmed by the presence rad OH radicals monitored by EPR spin trapping technique, additionally, COD and TOC parameters were measured, 13C NMR showed differences for the adsorbed and photodegraded samples.

  1. Separation of hydrogenated terphenyls by gas chromatography and interpretation of their infra-red and ultra-violet spectra

    International Nuclear Information System (INIS)

    In the separation of commercial mixtures of hydrogenated terphenyls (HB-40 (Monsanto) and OMP-H (Progil) satisfactory results were obtained, as regards the collection of fractions, using columns 2 m in length packed with 20 % Apiezon L on Chromosorb and, as regards total separation, using Apiezon L Macrogolay columns. The relative retentions, determined at temperatures between 185 and 300 deg. C, for the components of a mixture of triphenylmethane and anthracene were investigated in columns of Apiezon L, silicone SE-30, SE-31 and W-95, and silicone oil SF-96. The infra-red and ultra-violet spectra of the components were studied, the following structures being assigned to them in the order of their appearance in the chromatogram: o-terphenyl, o-phenylcyclohexylbenzene, m-dicyclohexylbenzene, phenylcyclohexylcyclohexane, p-dicyclohexylbenzene, m-phenylcyclohexylbenzene and p-phenylcyclohexylbenzene. (author)

  2. Violet stimulated luminescence dating of quartz from Luochuan (Chinese loess plateau): Agreement with independent chronology up to ∼600 ka

    DEFF Research Database (Denmark)

    Ankjærgaard, C.; Guralnik, B.; Buylaert, Jan-Pieter;

    2016-01-01

    ) and thermally transferred OSL (TT-OSL) signals. Since both the latter are associated with systematic uncertainties due to the potential (a)-thermal instability of these signals, a search continues for alternative, and demonstrably stable luminescence signals that can cover the entire Quaternary...... timescale. Here we explore the violet stimulated luminescence (VSL) signal at the Luochuan section, which provides a continuous archive of homogenous sediment with favourable luminescence characteristics and a solid independent age framework. By testing several VSL protocols and their associated performance......, we demonstrate that the Multi-Aliquot Additive-Dose (MAAD) protocol produces a VSL chronology at Luochuan which is in agreement with independent ages up to ∼0.6 Ma. For a more representative environmental dose rate of ∼2 Gy/ka (∼35% lower than at Luochuan), the documented range of MAAD...

  3. Study of vanadium complex with pyrocatechol violet and 1.10-phenanthroline in aqueous and organic media

    International Nuclear Information System (INIS)

    Spectrophotometrically it has been established that in an aqueous phase in the system of vanadium-pyrocatechol violet (PV)-phenanthroline (Phen) two complexes are formed with the V:PV:Phen ratio equal to 1:1:1 and 1:2:2. The complex with the ration of 1:2:2 is extracted with n-butyl alcohol. Extraction constant of the complex is 8x107. Nolar extinction coefficient of the complex is 1.72x104 (n-butyl alcohol) and 1.39x104 (water). An extraction-photometric method has been developed for determining vanadium in binary aluminium-vanadium alloys with the content of the components of 10 to 90 at.% without preliminary separation of aluminium

  4. Adsorption of methyl violet from aqueous solution using gum xanthan/Fe3O4 based nanocomposite hydrogel.

    Science.gov (United States)

    Mittal, H; Kumar, Vaneet; Saruchi; Ray, Suprakas Sinha

    2016-08-01

    This research paper reports the utilization of gum xanthan-grafted-polyacrylic acid and Fe3O4 magnetic nanoparticles based nanocomposite hydrogel (NCH) for the highly effective adsorption of methyl violet (MV) from aqueous solution. Synthesized NCH was characterized using various techniques, such as FTIR, XRD, SEM-EDS, TEM and BET. Adsorption behavior of NCH was studied for the adsorption of MV and it was found to remove 99% dye from the solution. Adsorption process followed Langmuir isotherm model (qe=642mg/g) and pseudo-second-order kinetics model. Thermodynamic studies suggested that the adsorption process was endothermic and spontaneous. Moreover, the adsorbent was successfully utilized for successive five cycles of adsorption-desorption. PMID:27106587

  5. Kinetic Approach to the Mechanism of Redox Reaction of Pyrocatechol Violet and Nitrite Ion in Aqueous Hydrochloric Acid

    Directory of Open Access Journals (Sweden)

    A. Adetoro

    2011-10-01

    Full Text Available The kinetics of the oxidation of Pyrocatechol violet (PCVH by nitrite ion (NO2- in aqueous acidic medium has been studied at 24±1ºC, I = 0.50 mol/dm3(NaCl, [H+] = 1.0×10-3 mol/dm3. The reaction is first order to [PCVH] and half order to [NO2-]. The redox reaction displayed a 1:1 stoichiometry and obeys the rate law: d[PCVH]/dt = (a + b[H+] [PCVH][NO2-]½. The second-order rate constant increases with increase in acid concentration and ionic strength. This system displayed positive salt effect while spectroscopic investigation and Michaelis-Menten plot showed evidence of intermediate complex formation in the course of the reaction. A plausible mechanism has been proposed for the reaction.

  6. DNA replication and repair in a human melanoma cell-line resistant to ultra-violet-radiation

    International Nuclear Information System (INIS)

    The effect of ultra-violet (U.V.)-irradiation on DNA replication was studied in a U.V.-resistant, human melanoma cell-line (MM96). Semi-conservative synthesis of DNA was decreased about five-fold by a U.V.-dose of 100 ergs/mm2. The size of DNA fragments synthesized in irradiated cells at short times after U.V. was smaller than those synthesized in unirradiated cells. Elongation of these fragments occurred with time, and 6 hours after irradiation cells synthesized DNA in fragments of the same size as obtained in unirradiated cells. In this post-replication repair process, elongation appeared to involve de novo synthesis and was not inhibited by theophylline. (author)

  7. Development of ultra-violet femtosecond pulse radiolysis system based on a photocathode rf electron-gun linac

    International Nuclear Information System (INIS)

    Two important radical species of alkyl radical (R·) and hydroxyl radicals (OH·) in nuclear fuel reprocessing or radiation cancer therapy have absorption bands around the 250 nm in Ultra-violet region. Despite the OH· and R· are important active species in the radiation chemistry, since those absorption coefficients are small and lack of time resolution of pulse radiolysis, a direct study of the reaction dynamics has been difficult until now. In order to elucidate the formation and reaction with solutes, measurable wavelength was extended to ultraviolet of the femtosecond pulse radiolysis system using a photocathode RF gun accelerator. Problems of ultraviolet femtosecond pulse radiolysis measurement, the time dependent behaviors of R· and OH· are reported. (author)

  8. Delineating the extent of anterior capsulorhexis with gentian violet using capsulorhexis marker: a preliminary study of efficacy and toxicity in an animal model

    Directory of Open Access Journals (Sweden)

    Hassaballa MA

    2011-06-01

    Full Text Available Mohamed Abdel Moneim Hassaballa, Amr Abd el-Latif OsmanDepartment of Ophthalmology, Faculty of Medicine, Cairo University, Cairo, EgyptBackground: The purpose of this study was to evaluate the efficacy and safety of a new instrument to optimize the size, shape, and centration of anterior capsulorhexis.Methods: The study was divided into two parts. The first part was done in 10 goats' eyes. A specially designed capsulorhexis marker was used. The lower edge of the instrument was stained by gentian violet and then applied to the anterior capsule to produce a circular mark of 5.5 mm. In five eyes, the gentian violet was applied to the marker using a corneal marking pen; in the remaining five eyes, the gentian violet was applied using a corneal marking pad. In the second part, the toxicity of gentian violet was tested as follows: ten albino rabbits received a gentian violet injection into the anterior chamber in one eye (experimental group and an equal volume of balanced salt solution in the fellow eye (control group. Five rabbits were sacrificed one day after surgery and the remaining five rabbits after one week.Results: In the first part, there was no difficulty in the introduction or removal of the instrument from all eyes. In the first two eyes, the circular mark was diffuse due to sliding of the marker on the surface of the anterior capsule. In the remaining eight eyes, there was a well-centered, rounded mark which was adequately stained. In the second part, there was no histopathological evidence of corneal toxicity in either group. There was loss of ganglion cells from the neurosensory retina one day after surgery in one eye from the experimental group. At one week, there was no evidence of retinal toxicity in any of the rabbits.Conclusion: This capsulorhexis marker can guide the surgeon to a better centration and proper sizing of anterior capsulorhexis using gentian violet staining. More refinement of the instrument is needed to be able to

  9. Aminoquinolone WR6026 as a feasible substitute for gentian violet in Chagas' disease prophylaxis in preserved blood for transfusional purposes

    Directory of Open Access Journals (Sweden)

    Moraes-Souza Helio

    2002-01-01

    Full Text Available The search for a colorless, nontoxic and efficient drug to prevent transfusion-associated Chagas' disease (TACD has been underway unsuccessfully since 1953 when gentian violet was preconized and to date is still being used as the only in vitro trypanocidal agent. The recent findings of aminoquinolone "WR6026" as a trypanocidal agent, led the authors to study the metabolism of red cells stored with this compound, the main objective of which was to define its applicability in TACD control. Ten units of human whole blood collected in CPDA-1 were divided into two equal satellite bags. One had "WR6026" (final concentration 62.5µg/mL added and the other was used as a control, both were stored at 4ºC. At baseline, day 7, 14, 21 and 28, samples were taken for the following measurements: adenosine triphosphate (ATP, hemoglobin, electrolytes (sodium and potassium, gases (pO2 and pCO2 and osmotic fragility. The results of tests and control were analyzed through parametric t-student test. The results were similar in both groups throughout the experiment except for the level of ATP on day 14, which presented significantly higher values in the tests when compared with the controls (p = 0.012. It was concluded that WR6026 does not interfere in the preservation and probably the viability of the erythrocytes also until day 28 of storage. Consequently the authors suggest that WR6026 could emerge as a colorless substitute for gentian violet in the control of TACD in endemic areas.

  10. 不浸酸铬鞣剂在牛皮工艺中的应用研究%Studies on application of chrome tannage without    pickling in cattle hide processing

    Institute of Scientific and Technical Information of China (English)

    陈占光; 陈武勇; 张兆生

    2001-01-01

    C-2000,a new type chrome tanning powder without pickling was used in cattle hide processing in small-scale and pilot test. Compared with coventional chrome tannage,chrome tannage without pickling could solve the problem of loose grain, increase the absorption of Cr, simplified the process and decrease pollution.%通过小试及中试,将不浸酸铬鞣剂C-2000用于牛皮的鞣制,并且与常规浸酸铬鞣方法做了对比。结果表明:在牛皮鞋面革的制造中,不浸酸鞣制方法可使成革的松面问题得到一定程度的改善,铬的吸收率得到明显的提高;同时工艺得到简化并且能显著降低铬和盐的污染。

  11. Stress Analysis on Single Cobalt/Chrome Prosthesis With a 15-mm Cantilever Placed Over 10/13/15-mm-length Implants: A Simulated Photoelastic Model Study.

    Science.gov (United States)

    Gastaldo, José Fábio Guastelli; Pimentel, Angélica Castro; Gomes, Maria Helena; Sendyk, Wilson Roberto; Laganá, Dalva Cruz

    2015-12-01

    The aim of study was to assess the stress around 10/13/15-mm implants in the mandibular area with a 15-mm cantilevered acrylic-resin-coated prostheses following the application force, using the photoelasticity method. Three photoelastic mandibular models were created containing 10-, 13-, and 15-mm implants in length and 3.75 mm in diameter. The implants had bore internal hex connections and were placed parallel to the intermental region. Abutments with 1-mm high cuffs were placed over the implants, and a single cobalt/chrome metallic prosthesis with a 15-mm cantilever, coated with thermoplastic acrylic resin, was placed on top. Loads of 1.0 and 3.0 bars were applied, and the images were photographed and assessed by photoelasticity method. The greatest stress levels were observed for the 10-mm implants. The stress pattern was the same regardless of implant length; only the magnitude of the stress along the implant body revealed changes. Increased implant length played a role in reducing stress on the investigated area of the model, and the 15-mm implants exhibited the best performance in regard to stress distribution. The highest stress levels were found in the implants closest to the cantilever and the central implant. The longest implants were more favorable in regard to the stress distribution on the peri-implant support structures in the 15-mm cantilevered prosthesis under loads. PMID:24914673

  12. Magnetic property variation in carbon steel and chrome-molybdenum steel as a function of uniaxial stress noncoaxial with the magnetic field (abstract)

    International Nuclear Information System (INIS)

    Magnescope1 magnetic measurements were made on carbon steel specimens ranging from 0.1--0.8 wt %C and on chrome-molybdenum steel specimens cut from electric power plant pipes previously in service. The carbon steel specimens were heat-treated using three procedures: (1) spheroidization, (2) quenching, and (3) quench and tempering. The specimens were subjected to uniaxial tension up to 40 ksi. The inspection head was aligned so that the magnetic field was oriented at different angles with respect to the stress axis. Magnetic properties (such as coercivity and maximum differential permeability) were extracted from digitized magnetic hysteresis loop measurements. Magnetic properties were studied as a function of stress at each angle of stress-field orientation. To our knowledge, such a comprehensive study of noncoaxial stress and field effects has never been accomplished before for such a wide variety of steel specimens. Results for the various materials are presented for different orientation angles and compared to numerical results from the noncoaxial magnetomechanical hysteresis model of Sablik et al.2

  13. Flow analysis methods for the direct ultra-violet spectrophotometric measurement of nitrate and total nitrogen in freshwaters

    International Nuclear Information System (INIS)

    Highlights: → Second derivative UV spectrophotometry has been used to determine nitrate and total N using flow analysis techniques. → A simple flow system with a single-reflection flow-through cell was used for the UV measurement of nitrate. → Total N was determined after on-line UV photooxidation with alkaline peroxodisulfate. → Analyses carried out using the developed flow systems show a high degree of agreement with comparative analyses. → This method requires no colorimetric reagents and eliminates the requirement for a toxic cadmium reduction column. - Abstract: Second derivative ultra-violet spectrophotometric methods are described for the measurement of nitrate and total nitrogen in freshwaters using flow analysis techniques. A simple flow system consisting of a peristaltic pump and a single-reflection flow-through cell was used for the measurement of nitrate. Quantification of total nitrogen using alkaline peroxodisulfate photo-digestion was achieved by incorporating an ultra-violet photo-reactor, a hollow-fibre filter and a debubbler into the flow system. The nitrate system featured a limit of detection of 0.04 mg N L-1, 0.4%RSD (1 mg N L-1 as nitrate, n = 10), a coefficient of determination (R2) of 0.9995 over the calibration range 0.0-2.0 mg N L-1, and a data acquisition time of 1.5 s per spectrum. The total nitrogen system featured a limit of detection of 0.05 mg N L-1, 1%RSD (1 mg N L-1 as ammonium chloride, n = 10), a coefficient of determination of 0.9989 over the calibration range 0.0-2.0 mg N L-1, and a throughput of 5 sample h-1 measured in triplicate. Digestions of five model nitrogen compounds returned recoveries of >88%. Determinations carried out using the developed systems show a high degree of agreement with data obtained using reference methods. These methods require no colorimetric reagents and eliminate the requirement for a toxic cadmium reduction column. The overlap of chloride and nitrate spectra in seawater is not eliminated

  14. Elimination of root-infecting pathogens in recirculation water from closed cultivation systems by ultra-violet radiation

    International Nuclear Information System (INIS)

    The development from growing in border soil to soilless cultures has not resulted in the disappearance of soil-borne diseases. Most root-infecting pathogens also occur in these new cultivation systems. Some pathogens such as Pythium, Phytophthora, cucumber green mottle mosaic virus and tomato mosaic virus are easily transmitted in recirculation water as is Olpidium, the vector of several viruses. To exclude any risk of dispersal of plant pathogens the water has to be sterilised before re-use. Rainwater collected from the glasshouse roof can also be contaminated with pathogens. When this rainwater is used for irrigation water it should be disinfected first. Currently water disinfection by heating or ozonisation is applied on some 450 nurseries. Initially ultra-violet(UV) radiation was not effective against plant pathogens. Only at a low capacity of 18 l h-1 and a high UV-dose of 430 mJ cm-2 could fungal spores be eliminated in nutrient solution. A low capacity however implies a poor turbulence in the water, resulting in varying UV-doses in the different water layers. Two new UV-installations with high capacities were tested for their efficacy against fungal and viral plant pathogens. One installation was equipped with a high-pressure and the other with a low-pressure mercury vapour lamp. In both installations a sandfilter first removed organic particles from the water. A UV-dose from the high-pressure lamp of 28 mJ cm-2 reduced the infectivity of conidia of Fusarium oxysporum f.sp lycopersici by 90 % resulting in a 99.9 % reduction at 84 mJ cm-2. The low-pressure lamp completely eliminated conidia of Fusarium at a UV-dose of 70 mJ cm-2. Tomato mosaic virus was reduced by 99 % using a UV-dose of 100 mJ cm-2 in both installations. Ultra-violet radiation can be effective against plant pathogens providing the dose under controlled conditions is sufficient. Numerous growers use UV-radiation for the disinfection of water in closed cultivation systems. (author)

  15. Cavity-enhanced frequency doubling from 795nm to 397.5nm ultra-violet coherent radiation with PPKTP crystals in the low pump power regime.

    Science.gov (United States)

    Wen, Xin; Han, Yashuai; Bai, Jiandong; He, Jun; Wang, Yanhua; Yang, Baodong; Wang, Junmin

    2014-12-29

    We demonstrate a simple, compact and cost-efficient diode laser pumped frequency doubling system at 795 nm in the low power regime. In two configurations, a bow-tie four-mirror ring enhancement cavity with a PPKTP crystal inside and a semi-monolithic PPKTP enhancement cavity, we obtain 397.5nm ultra-violet coherent radiation of 35mW and 47mW respectively with a mode-matched fundamental power of about 110mW, corresponding to a conversion efficiency of 32% and 41%. The low loss semi-monolithic cavity leads to the better results. The constructed ultra-violet coherent radiation has good power stability and beam quality, and the system has huge potential in quantum optics and cold atom physics. PMID:25607194

  16. Shock-Assisted Superficial Hexagonal-to-Cubic Phase Transition in GaN/Sapphire Interface Induced by Using Ultra-violet Laser Lift-Of Techniques

    International Nuclear Information System (INIS)

    Ultra-violet (KrF excimer laser, λ = 248 nm) laser lift-of (LLO) techniques have been operated to the GaN/sapphire structure to separate GaN from the sapphire substrate. Hexagonal to cubic phase transformation induced by the ultra-violet laser lift-of (UV-LLO) has been characterized by micro-Raman spectroscopy, micro-photoluminescence, along with high-resolution transmission electron microscopy (HRTEM). HRTEM indicates that UV-LLO induced phase transition takes place above the LLO interface, without phase transition under the LLO interface. The formed cubic GaN often exists as nanocrystal grains attaching on the bulk hexagonal GaN. The half-loop-cluster-like UV-LLO interface indicates that the LLO-induced shock waves has generated and played an assistant role in the decomposition of the hexagonal GaN and in the formation of cubic GaN grains at the LLO surface

  17. A case-control study of oral epithelial proliferative markers among Sudanese Toombak dippers using micronuclei assay, argyrophilic nucleolar organizer region, Papanicolaou and crystal violet methods

    OpenAIRE

    Anass M. Abbas; Hussain G. Ahmed

    2013-01-01

    The use of Toombak has been reported to play a major role in the etiology of oral cancer in Sudan. The cellular proliferative activity on the oral epithelium of 210 Toombak dippers was assessed by applying the micronuclei frequency, mean argyrophilic nucleolar organizer region (AgNOR) counts, Papanicolaou method, and 1% crystal violet stain. Participants were divided into 3 groups: 200 were apparently healthy individuals, 100 were Toombak users (cases), 100 were non-tobacco users (control) an...

  18. Living collections of botanic gardens as a means of ex situ conservation : A case study of African Violets (Saintpaulia) in Europe

    OpenAIRE

    Miranto, Mari

    2006-01-01

    In all plant conservation, the priority is to maintain wild populations in situ (on site), which means that plants are conserved within their natural environment. Sometimes, as in the case of severely endangered Saintpaulia H. Wendl. (African violets), this is however, no sufficient. In that case, ex situ (off site) conservation in the form of live and in vitro collections and seed banks is necessary. In recent years, the role of botanic gardens in conservation and reintroduction of threatene...

  19. Microwave treated Salvadora oleoides as an eco-friendly biosorbent for the removal of toxic methyl violet dye from aqueous solution--A green approach.

    Science.gov (United States)

    Din, Muhammad Imran; Hussain, Zaib; Munir, Hifza; Naz, Amber; Intisar, Azeem; Makshoof, M Nouman; Mirza, M Latif

    2016-01-01

    In the present study, microwave treated Salvadora oleoides (MW-SO) has been investigated as a potential biosorbent for the removal of toxic methyl violet dye. A batch adsorption method was experimented for biosorptive removal of toxic methyl violet dye from the aqueous solution. The effect of various operating variables, viz., adsorbent dosage, pH, contact time and temperature on the removal of the dye was studied and it was found that nearly 99% removal of the dye was possible under optimum conditions. Kinetic study revealed that a pseudo-second-order mechanism was predominant and the overall process of the dye adsorption involved more than one step. Hence, in order to investigate the rate determining step, intra-particle diffusion model was applied. Adsorption equilibrium study was made by analyzing Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) adsorption isotherm models and the biosorption data was found to be best represented by the Langmuir model. The biosorption efficiency of MW-SO was also compared with unmodified material, Salvadora oleoides (SO). It was found that the sorption capacity (qmax) increased from 58.5 mg/g to 219.7 mg/g on MW treatment. Determination of thermodynamic parameters such as free energy change (ΔG°), enthalpy change (ΔH°) and entropy change (ΔS°) confirmed the spontaneous, endothermic and feasible nature of the adsorption process. The preparation of MW-SO did not require any additional chemical treatment and a high percentage removal of methyl violet dye was obtained in much lesser time. Thus, it is in agreement with the principles of green chemistry. The results of the present research work suggest that MW-SO can be used as an environmentally friendly and economical alternative biosorbent for the removal of methyl violet dye from aqueous solutions. PMID:26588059

  20. Vacuum ultra-violet damage and damage mitigation for plasma processing of highly porous organosilicate glass dielectrics

    International Nuclear Information System (INIS)

    Porous organosilicate glass thin films, with k-value 2.0, were exposed to 147 nm vacuum ultra-violet (VUV) photons emitted in a Xenon capacitive coupled plasma discharge. Strong methyl bond depletion was observed, concomitant with a significant increase of the bulk dielectric constant. This indicates that, besides reactive radical diffusion, photons emitted during plasma processing do impede dielectric properties and therefore need to be tackled appropriately during patterning and integration. The detrimental effect of VUV irradiation can be partly suppressed by stuffing the low-k porous matrix with proper sacrificial polymers showing high VUV absorption together with good thermal and VUV stability. In addition, the choice of an appropriate hard-mask, showing high VUV absorption, can minimize VUV damage. Particular processing conditions allow to minimize the fluence of photons to the substrate and lead to negligible VUV damage. For patterned structures, in order to reduce VUV damage in the bulk and on feature sidewalls, the combination of both pore stuffing/material densification and absorbing hard-mask is recommended, and/or the use of low VUV-emitting plasma discharge

  1. Modeling the Effects of Star Formation Histories on Halpha and Ultra-Violet Fluxes in Nearby Dwarf Galaxies

    CERN Document Server

    Weisz, Daniel R; Johnson, L Clifton; Skillman, Evan D; Lee, Janice C; Kennicutt, Robert C; Calzetti, Daniela; van Zee, Liese; Bothwell, Matthew; Dalcanton, Julianne J; Dale, Daniel A; Williams, Benjamin F

    2011-01-01

    We consider the effects of non-constant star formation histories (SFHs) on Halpha and GALEX far ultra-violet (FUV) star formation rate (SFR) indicators. Under the assumption of a fully populated Chabrier IMF, we compare the distribution of Halpha-to-FUV flux ratios from ~ 1500 simple, periodic model SFHs with observations of 185 galaxies from the Spitzer Local Volume Legacy survey. We find a set of SFH models that are well matched to the data, such that more massive galaxies are best characterized by nearly constant SFHs, while low mass systems experience bursts amplitudes of ~ 30 (i.e., an increase in the SFR by a factor of 30 over the SFR during the inter-burst period), burst durations of tens of Myr, and periods of ~ 250 Myr; these SFHs are broadly consistent with the increased stochastic star formation expected in systems with lower SFRs. We analyze the predicted temporal evolution of galaxy stellar mass, R-band surface brightness, Halpha-derived SFR, and blue luminosity, and find that they provide a reas...

  2. A new rapid colourimetric method for testing Mycobacterium tuberculosis susceptibility to isoniazid and rifampicin: a crystal violet decolourisation assay

    Directory of Open Access Journals (Sweden)

    Ahmet Yilmaz Coban

    2014-04-01

    Full Text Available The aim of this study was to investigate the performance of a new and accurate method for the detection of isoniazid (INH and rifampicin (RIF resistance among Mycobacterium tuberculosis isolates using a crystal violet decolourisation assay (CVDA. Fifty-five M. tuberculosis isolates obtained from culture stocks stored at -80ºC were tested. After bacterial inoculation, the samples were incubated at 37ºC for seven days and 100 µL of CV (25 mg/L stock solution was then added to the control and sample tubes. The tubes were incubated for an additional 24-48 h. CV (blue/purple was decolourised in the presence of bacterial growth; thus, if CV lost its colour in a sample containing a drug, the tested isolate was reported as resistant. The sensitivity, specificity, positive predictive value, negative predictive value and agreement for INH were 92.5%, 96.4%, 96.1%, 93.1% and 94.5%, respectively, and 88.8%, 100%, 100%, 94.8% and 96.3%, respectively, for RIF. The results were obtained within eight-nine days. This study shows that CVDA is an effective method to detect M. tuberculosis resistance to INH and RIF in developing countries. This method is rapid, simple and inexpensive. Nonetheless, further studies are necessary before routine laboratory implementation.

  3. Ultra-violet Sensing Characteristic and Field Emission Properties of Vertically Aligned Aluminum Doped Zinc Oxide Nanorod Arrays

    International Nuclear Information System (INIS)

    Ultra-violet (UV) sensing behavior and field emission characteristic have been investigated on vertically aligned aluminum (Al) doped zinc oxide (ZnO) nanorod arrays prepared using sol-gel immersion method. Uniform and high coverage density of ZnO nanorod arrays have been successfully deposited on seeded-catalyst coated substrates. The synthesized nanorods have diameter sizes between 50 nm to 150 nm. The XRD spectra show Al doped ZnO nanorod array has high crystallinity properties with the dominancy of crystal growth along (002) plane or c-axis. UV photoresponse measurement indicates that Al doped ZnO nanorod array sensitively detects UV light as shown by conductance increment after UV illumination exposure. The nanorod array shows good field emission properties with low turn on field and threshold field at 2.1 V/μm and 5.6 V/μm, respectively. The result suggested that Al doped ZnO nanorod arrays prepared by low-cost sol-gel immersion method show promising result towards fabrication of multi applications especially in UV photoconductive sensor and field emission displays.

  4. Thermomechanical and Photophysical Properties of Crystal-Violet-Dye/H2O Based Dissolutions via the Pulsed Laser Photoacoustic Technique

    Directory of Open Access Journals (Sweden)

    Vicente Torres-Zúñiga

    2014-01-01

    Full Text Available Different thermoelastic parameters, for example, the acoustic attenuation and the speed of sound, are fundamental for instrumental calibration and quantitative characterization of organic-based dissolutions. In this work, these parameters as functions of the concentration of an organic dye (crystal-violet: CV in distillated water (H2O based dissolutions are investigated. The speed of sound was measured by the pulsed-laser photoacoustic technique (PLPA, which consists in the generation of acoustic-waves by the optical absorption of pulsed light in a given material (in this case a liquid sample. The thermally generated sound-waves traveling through a fluid are detected with two piezoelectric sensors separated by a known distance. An appropriate processing of the photoacoustic signals allows an adequate data analysis of the generated waves within the system, providing an accurate determination of the speed of sound as function of the dye-concentration. The acoustic attenuation was calculated based on the distance of the two PZT-microphones to an acoustic-source point and performing linear-fitting of the experimental data (RMS-amplitudes as function of the dye-concentration. An important advantage of the PLPA-method is that it can be implemented with poor or null optical transmitting materials permitting the characterization of the mechanical and concentration/aggregate properties of dissolved organic compounds.

  5. Violet-blue LEDs based on p-GaN/n-ZnO nanorods and their stability

    International Nuclear Information System (INIS)

    In this paper, we report a fabrication, characterization and stability study of p-GaN/n-ZnO nanorod heterojunction light-emitting devices (LEDs). The LEDs were assembled from arrays of n-ZnO vertical nanorods epitaxially grown on p-GaN. LEDs showed bright electroluminescence in blue (440 nm), although weaker violet (372 nm) and green-yellow (550 nm) spectral components were also observed. The device characteristics are generally stable and reproducible. The LEDs have a low turn-on voltage (∼5 V). The electroluminescence (EL) is intense enough to be noticed by the naked eye, at an injection current as low as ∼ 40 μA (2.1 x 10-2 A cm-2 at 7 V bias). Analysis of the materials, electrical and EL investigations point to the role of a high quality of p-n nano-heterojunction which facilitates a large rectification ratio (320) and a stable reverse current of 2.8 μA (1.4 x 10-3 A cm-2 at 5 V). Stability of EL characteristics was investigated in detail. EL intensity showed systematic degradation over a short duration when the LED was bias-stressed at 30 V. At smaller bias (<20 V) LEDs tend to show a stable and repeatable EL characteristic. Thus a simple low temperature solution growth method was successfully exploited to realize nanorod/film heterojunction LED devices with predictable characteristics.

  6. A statistical study of gamma-ray burst afterglows measured by the Swift Ultra-violet Optical Telescope

    CERN Document Server

    Oates, S R; Schady, P; de Pasquale, M; Koch, T S; Breeveld, A A; Brown, P J; Chester, M M; Holland, S T; Hoversten, E A; Kuin, N P M; Marshall, F E; Roming, P W A; Still, M; Berk, D E Vanden; Zane, S; Nousek, J A

    2009-01-01

    We present the first statistical analysis of 27 UVOT optical/ultra-violet lightcurves of GRB afterglows. We have found, through analysis of the lightcurves in the observer's frame, that a significant fraction rise in the first 500s after the GRB trigger, that all lightcurves decay after 500s, typically as a power-law with a relatively narrow distribution of decay indices, and that the brightest optical afterglows tend to decay the quickest. We find that the rise could either be produced physically by the start of the forward shock, when the jet begins to plough into the external medium, or geometrically where an off-axis observer sees a rising lightcurve as an increasing amount of emission enters the observers line of sight, which occurs as the jet slows. We find that at 99.8% confidence, there is a correlation, in the observed frame, between the apparent magnitude of the lightcurves at 400s and the rate of decay after 500s. However, in the rest frame a Spearman Rank test shows only a weak correlation of low ...

  7. Combinatorial fabrication and studies of 4,4'-bis(9-carbazolyl) biphenyl (CBP)-based UV-violet OLED arrays

    Science.gov (United States)

    Zou, L.; Savvate'ev, Vadim; Booher, J.; Kim, Chang-Hwan; Shinar, Joseph

    2002-02-01

    Arrays of UV-violet [indium tin oxide (ITO)]/[copper phthalocyanine (CuPc)]/[4,4'-bis(9- carbazolyl)biphenyl(CBP)]/[2-(4-biphenylyl)-5-(4-tert- butylphenyl)-1,3,4-oxadiazole(Bu-PBD)]/CsF/Al organic light- emitting devices (OLEDs), fabricated combinatorially using a sliding shutter technique, are described. Comparison of the electroluminescence spectrum with the photoluminescence spectrum of CBP indicates that the emission originates from the bulk of that layer. However, due to the high gap of CBP and the strong hole capture cross section of perylene contaminants, it was difficult to completely eliminate the emission from the latter. In arrays of devices in which the thickness of the CuPc and Bu-PBD were varied, but that of CBP was fixed at 50 nm, the optimal radiance R was obtained at CuPc and Bu-PBD thicknesses of 15 and 18 nm, respectively. At 10 mA/Cm2, R was 0.38 mW/cm2, i.e., the external quantum efficiency was 1.25%; R increased to ~1.2 mW/cm2 at 100 mA/cm2.

  8. Vacuum ultra-violet damage and damage mitigation for plasma processing of highly porous organosilicate glass dielectrics

    Energy Technology Data Exchange (ETDEWEB)

    Marneffe, J.-F. de, E-mail: marneffe@imec.be; Lukaszewicz, M.; Porter, S. B.; Vajda, F.; Rutigliani, V.; Verdonck, P.; Baklanov, M. R. [IMEC v.z.w., 3001 Leuven (Belgium); Zhang, L.; Heyne, M.; El Otell, Z.; Krishtab, M. [IMEC v.z.w., 3001 Leuven (Belgium); Department of Chemistry, KULeuven, 3001 Leuven (Belgium); Goodyear, A.; Cooke, M. [Oxford Instruments Plasma Technology, BS49 4AP Bristol (United Kingdom)

    2015-10-07

    Porous organosilicate glass thin films, with k-value 2.0, were exposed to 147 nm vacuum ultra-violet (VUV) photons emitted in a Xenon capacitive coupled plasma discharge. Strong methyl bond depletion was observed, concomitant with a significant increase of the bulk dielectric constant. This indicates that, besides reactive radical diffusion, photons emitted during plasma processing do impede dielectric properties and therefore need to be tackled appropriately during patterning and integration. The detrimental effect of VUV irradiation can be partly suppressed by stuffing the low-k porous matrix with proper sacrificial polymers showing high VUV absorption together with good thermal and VUV stability. In addition, the choice of an appropriate hard-mask, showing high VUV absorption, can minimize VUV damage. Particular processing conditions allow to minimize the fluence of photons to the substrate and lead to negligible VUV damage. For patterned structures, in order to reduce VUV damage in the bulk and on feature sidewalls, the combination of both pore stuffing/material densification and absorbing hard-mask is recommended, and/or the use of low VUV-emitting plasma discharge.

  9. Effect of heat shock on the chilling sensitivity of trichomes and petioles of African violet (Saintpaulia ionantha).

    Science.gov (United States)

    Saltveit, Mikal E.; Hepler, Peter K.

    2004-05-01

    Chilling at 6 degrees C caused an immediate cessation of protoplasmic streaming in trichomes from African violets (Saintpaulia ionantha), and a slower aggregation of chloroplasts in the cells. Streaming slowly recovered upon warming to 20 degrees C, reaching fairly stable rates after 4, 15, 25 and 35 min for tissue chilled for 2 min and for 2, 14 and 24 h, respectively. The rate of ion leakage from excised petioles into an isotonic 0.2 M mannitol solution increased after 12 h of chilling and reached a maximum after 3 days of chilling. A heat shock at 45 degrees C for 6 min reduced chilling-induced rates of ion leakage from excised 1-cm petiole segments by over 50%, namely to levels near that from non-chilled control tissue. Heat-shock treatments themselves had no effect on the rate of ion leakage from non-chilled petiole segments. Protoplasmic streaming was stopped by 1 min of heat shock at 45 degrees C, but slowly recovered to normal levels after about 30 min Chloroplasts aggregation was prevented by a 1 or 2 min 45 degrees C heat-shock treatment administered 1.5 h before chilling, but heat-shock treatments up to 6 min only slightly delayed the reduction in protoplasmic streaming caused by chilling. Tradescantia virginiana did not exhibit symptoms associated with chilling injury in sensitive species (i.e. cessation of protoplasmic streaming in stamen hairs and increased ion leakage from leaf tissue). PMID:15086815

  10. Plant regeneration and floral bud formation from intact floral parts of African violet (Saintpaulia ionantha H. Wendl.) cultured in vitro.

    Science.gov (United States)

    Daud, N; Taha, R M

    2008-04-01

    Intact immature flower buds of African violet (Saintpaulia ionantha H. Wendl.) were used as explant sources for in vitro studies. The effect of exogenous hormones, NAA and BAP on the indirect organogenesis of this species was observed. Callus was formed on the cut end (base) of pedicels of floral buds where they were in contact with the medium. When maintained on the same medium, callus was differentiated into adventitious shoots after 10 weeks in culture. MS media supplemented with 2.0 mg L(-1) NAA and 1.0 mg L(-1) BAP gave the highest number of sterile or vegetative floral buds from the surface of callus of the explants, but these buds failed to develop further. The floral buds were expanded as abnormal flowers. The floral structures were smaller in size compared to intact flowers. Petals (corolla) were white to purple in colour but did not form any reproductive organs, i.e., stamens or pistils. All sterile or vegetative floral buds and abnormal flowers survived for 3 months in culture but failed to reach anthesis. PMID:18810979

  11. Kinetics of the reaction of crystal violet with hydroxide ion in the critical solution of 2-butoxyethanol + water.

    Science.gov (United States)

    Du, Zhongyu; Mao, Shiyan; Chen, Zhiyun; Shen, Weiguo

    2013-01-17

    The kinetics of alkaline fading of crystal violet (CV) has been studied by UV spectrophotometry and microcalorimetry in the critical binary solution of 2-butoxyethanol + water at the initial reaction stage and various temperatures. It was found that the first-order rate constants obtained from these two methods are well accorded with each other, and the temperature dependence of the rate constant obeyed the Arrhenius equation in a temperature region far from the critical point. The critical slowing down was detected by both methods near the critical point. A simple empirical crossover model was proposed and used to analyze the experimental data to obtain the critical exponents, which were 0.158 ± 0.013 and 0.133 ± 0.012 from UV spectrophotometry and microcalorimetry, respectively, and the former was in good agreement with the theoretical prediction of 0.151. The slight lower value derived from microcalorimetry was attributed to the stirring in the microcalorimeter, which weakened the critical reduction of the diffusion coefficient. PMID:23276229

  12. Effect of organic media on growth and development of patiola F1 horned violet (Viola cornuta L.

    Directory of Open Access Journals (Sweden)

    Dorota Janicka

    2013-04-01

    Full Text Available The specificity of horticultural production makes it possible to use substrates based on compost from municipal and industrial waste, particularly in the cultivation of ornamental plants. Experiments were conducted in the years 2005–2007. Six horned violet cultivars (Viola cornuta  L. from Patiola F1 group and four substrates were used in them: I – sphagnum peat; II – substrate from peat and compost 1 (1:1 v/v; III – substrate from peat and compost 2 (1:1 v/v; IV – coconut fibre. Compost 1 was prepared using municipal sewage sludge (35%, potato pulp (35% and straw (30%. Compost 2 was prepared using municipal sewage sludge (35%, potato pulp (35% and sawdust (30%. Composts after 10 months of composting were used in the research. The addition of municipal sewage sludge composts did not cause observable adverse changes in plants grown. Composts made from municipal sewage sludge are rich in nutrients. Plants that are grown in substrates with the addition of composts and in a peat substrate grow and develop properly without the necessity of introducing top dressing.

  13. Electron spin ressonance of radicals produced by ultra-violet photolysis of KCL dopped with potassium cyanide and potassium cyanate

    International Nuclear Information System (INIS)

    The production of radicals by ultra-violet photolysis of KCL dopped with potassium cyanide and potassium cyanate is studied by electron spin resonance. Several new paramagnetic species are detected which are identified as HCNO-, NCN-/NCNO-, CNN-/CNON- and CNOsup(=) all giving isotropic spectra at 77 0K. The temperature dependence of the CNOsup(=) spectrum is investigated down to 1.6 0K. It is found that two different recrientation motions ocurr which freeze at different temperatures. The effect of this motion on the line width is analized using Anderson's theory of exchange narrowing. The electronic structure of the CNOsup(=) radical is discussed using the measured the carbon and nitrogen hfs constants. It is found that a bonding scheme similar to that accepted for the isoelectronic molecule NO2 is applicable, and a one electron molecular orbital scheme is given. Within this scheme a negative contribution to the nitrogen isotropic hfs constant is found which is assumed to originate from the polarization of the fully occupied ls orbitals

  14. Efficient functionalization of poly(styrene) beads immobilized metal nanoparticle catalysts for the reduction of crystal violet

    Indian Academy of Sciences (India)

    Eagambaram Murugan; Paramasivam Shanmugam

    2015-06-01

    Three types of new bead-shaped heterogeneous nanoparticle (NP) catalysts were synthesized by simplified procedures and studied for continuous reduction of crystal violet (CV) dye. The stabilizing agent, viz., 2-acryloxyethyltrimethyl ammonium chloride (PAC) was functionalized efficiently onto the surface of insoluble poly(styrene)-co-(vinyl benzyl chloride) beads (PS–PVBC) through surface-initiated atom transfer radical polymerization (SI-ATRP) to obtain insoluble bead matrix having intense surface functional groups labelled as PS–PVBC--PAC. These PS–PVBC–PAC beads in turn were used as a common matrix for individual immobilization of AgNPs, AuNPs and PdNPs by following the simple chemical reaction/reduction methods to yield the corresponding bead-shaped heterogeneous NP catalysts, viz., PS–PVBC--PAC–AgNPs, PS–PVBC--PAC–AuNPs and PS–PVBC--PAC–PdNPs. These catalysts were characterized by UV–Vis, FT-IR, SEM/EDAX and HRTEM techniques. The catalytic activity of these three types of catalysts were examined through the reduction of CV using NaBH4 as a reducing agent and it was observed that all these catalysts effectively accelerated the reaction. The superior catalyst, viz., PS–PVBC--PAC–AuNPs was again used for detail kinetic studies of the same reduction reaction.

  15. Effect of In incorporation parameters on the electroluminescence of blue-violet InGaN/GaN multiple quantum wells grown by metalorganic chemical vapor deposition

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, D.G., E-mail: dgzhao@red.semi.ac.cn [State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083 (China); Jiang, D.S.; Le, L.C.; Wu, L.L.; Li, L. [State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083 (China); Zhu, J.J.; Wang, H. [State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083 (China); Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215125 (China); Liu, Z.S. [State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083 (China); Zhang, S.M. [State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083 (China); Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215125 (China); Jia, Q.J. [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039 (China); Yang Hui [State Key Laboratory on Integrated Optoelectronics, Institute of Semiconductors, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083 (China); Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215125 (China)

    2012-11-05

    Highlights: Black-Right-Pointing-Pointer The interface roughness of InGaN/GaN MQWs are characterized by XRD. Black-Right-Pointing-Pointer Smooth interface is very important for the blue-violet InGaN/GaN MQWs. Black-Right-Pointing-Pointer EL of InGaN MQWs could be improved by controlling In incorporation parameters. - Abstract: The growth parameters which can modify In incorporation and affect electroluminescence (EL) properties of blue-violet InGaN/GaN multiple quantum wells (MQWs) during metalorganic chemical vapor deposition (MOCVD) are investigated. It is found that a suitable increase of trimethylindium (TMIn) flux during the growth of InGaN well can increase both EL intensity and EL peak wavelength. However, when the growth temperature of well decreases from 810 to 800 Degree-Sign C, the EL intensity decreases although the EL peak wavelength increases. X-ray diffraction results demonstrate that the interface roughness plays an important role in determining the EL intensity of InGaN/GaN MQWs. It is suggested to grow blue-violet MQWs with high structural quality by suitably increasing the TMIn flux and at a relatively high growth temperature.

  16. Effect of In incorporation parameters on the electroluminescence of blue–violet InGaN/GaN multiple quantum wells grown by metalorganic chemical vapor deposition

    International Nuclear Information System (INIS)

    Highlights: ► The interface roughness of InGaN/GaN MQWs are characterized by XRD. ► Smooth interface is very important for the blue–violet InGaN/GaN MQWs. ► EL of InGaN MQWs could be improved by controlling In incorporation parameters. - Abstract: The growth parameters which can modify In incorporation and affect electroluminescence (EL) properties of blue–violet InGaN/GaN multiple quantum wells (MQWs) during metalorganic chemical vapor deposition (MOCVD) are investigated. It is found that a suitable increase of trimethylindium (TMIn) flux during the growth of InGaN well can increase both EL intensity and EL peak wavelength. However, when the growth temperature of well decreases from 810 to 800 °C, the EL intensity decreases although the EL peak wavelength increases. X-ray diffraction results demonstrate that the interface roughness plays an important role in determining the EL intensity of InGaN/GaN MQWs. It is suggested to grow blue–violet MQWs with high structural quality by suitably increasing the TMIn flux and at a relatively high growth temperature.

  17. A fiber-optic violet sensor by using the surface grating formed by a photosensitive hybrid liquid crystal film on side-polished fiber

    International Nuclear Information System (INIS)

    A fiber-optic violet sensor is demonstrated by using the surface grating formed by a photosensitive liquid crystal (LC) hybrid film on the flat area of side-polished fiber (SPF). The surface grating is constructed through a periodic intensity illuminating the hybrid LC film, where the periodic intensity is created by a phase mask through which the violet light passes. Experiment shows that a loss peak appears in the transmission spectrum between 1520 and 1620 nm, and this loss peak shifts toward shorter wavelength as the 405 nm light power increases. The wavelength shift of the peak shows very good linearity with the irradiation power between 30 and 80 mW cm−2. The very high sensitivity of the light power sensor is measured to be 1.154 nm (mW cm−2)−1, which implies that the minimum change of power intensity that can be detected is 0.866 µW cm−2 for this sensor under the limited wavelength resolution of 0.001 nm of the optical spectrum analyzer. For UV light, much higher sensitivity will be further obtained, as the LC hybrid is more sensitive to UV light than to violet light. (paper)

  18. A Comparative Study of Cellulose Agricultural Wastes (Almond Shell, Pistachio Shell, Walnut Shell, Tea Waste And Orange Peel for Adsorption of Violet B Dye from Aqueous Solutions

    Directory of Open Access Journals (Sweden)

    Saeedeh Hashemian

    2014-12-01

    Full Text Available Adsorption of violet B azo dye from aqueous solutions was studied by different cellulose agriculturalwaste materials (almond shell (AS, pistachio shell (PS, walnut shell (WS, Tea waste (TW and orange peel (OP. Cellulose agricultural waste sorbents characterized by FTIR and SEM methods. The effects of different parameters such as contact time, pH, adsorbent dosage and initial dye concentration were studied.Maximum removal of dye was obtained at contact time of 90 min and pH 11.The adsorption of violet B was fitted by pseudo-second-order kinetic model.The Langmuir isotherm model was better fitted than Freundlichmodel. The results showed that the adsorption efficiency of violet B by cellulose agricultural waste materials is as followed: Almond shell > Orange peel > Pistachio shell > Tea waste> Walnut shell.The maximum adsorption capacity was obtained 96, 82, 71.4, 55.5 and 48.7 mg g−1 for AS, OP, PS, TW and WS, respectively.

  19. Enantioselective synthesis and olfactory evaluation of bicyclic alpha- and gamma-ionone derivatives: the 3D arrangement of key molecular features relevant to the violet odor of ionones.

    Science.gov (United States)

    Luparia, Marco; Legnani, Laura; Porta, Alessio; Zanoni, Giuseppe; Toma, Lucio; Vidari, Giovanni

    2009-09-18

    Violet smelling ionones 1-3, occurring in the headspace of different flowers, are well-known perfumery raw materials. With the goal to recognize the still ill-defined spatial arrangement of structural features relevant to the binding of ionones to olfactory G-protein coupled receptors, through B3LYP/6-31G(d) modeling studies we identified bicyclic compounds 7-9 as conformationally constrained 13-alkyl-substituted analogues of monocyclic alpha- and gamma-ionones. They were thus synthesized to evaluate the olfactory properties. The enantioselective syntheses of 7-9 entailed two common key steps: (i) a Diels-Alder reaction to construct the octalinic core and (ii) a Julia-Lythgoe olefination to install the alpha,beta-enone side chain. The odor thresholds of synthetic 7 and 9 were significantly lower than the corresponding parent ionones, and 9 showed the lowest threshold value among violet-smelling odorants examined so far. Modeling studies suggested a nearly identical spatial orientation of key hydrophobic and polar moieties of compounds 1, 3, and 4-9. Presumably, interaction of these moieties with ionone olfactory receptors (ORs) triggers a similar receptor code that is ultimately interpreted by the human brain as a pleasant woody-violet smell. These results open the way to studies aimed at identifying and modeling complementary binding sites on alpha-helical domains of ionone receptor proteins. PMID:19743882

  20. Fast Analysis of Water Samples for Trace Amount of Crystal Violet Dye Based on Solid Phase Extraction Using Nanoporous SBA-3 prior to Determination by Fiber Optic-Linear Array Detection Spectrophotometry

    OpenAIRE

    Azam Azarkohan; Farzaneh Shemirani; Mahrouz Alvand

    2013-01-01

    A solid phase preconcentration procedure using SBA-3 nanosorbent for the fast separation and preconcentration of crystal violet (CV) in water samples by fiber optic-linear array detection spectrophotometry (FO-LADS) is presented. Experimental parameters including pH, sample volume, amount of sorbent, type, volume, and concentration of eluent that affect the recovery of crystal violet have been optimized. Under optimized experimental conditions, analytical parameters including limit of detecti...

  1. Five-year comparison of wear using oxidised zirconium and cobalt-chrome femoral heads in total hip arthroplasty: a multicentre randomised controlled trial.

    Science.gov (United States)

    Jassim, S S; Patel, S; Wardle, N; Tahmassebi, J; Middleton, R; Shardlow, D L; Stephen, A; Hutchinson, J; Haddad, F S

    2015-07-01

    Oxidised zirconium (OxZi) has been developed as an alternative bearing surface for femoral heads in total hip arthroplasty (THA). This study has investigated polyethylene wear, functional outcomes and complications, comparing OxZi and cobalt-chrome (CoCr) as part of a three-arm, multicentre randomised controlled trial. Patients undergoing THA from four institutions were prospectively randomised into three groups. Group A received a CoCr femoral head and highly cross-linked polyethylene (XLPE) liner; Group B received an OxZi femoral head and XLPE liner; Group C received an OxZi femoral head and ultra-high molecular weight polyethylene (UHMWPE) liner. At five years, 368 patients had no statistically significant differences in short-form-36 (p = 0.176 mental, p = 0.756 physical), Western Ontario and McMaster Universities Osteoarthritis Index (p = 0.847), pain scores (p = 0.458) or complications. The mean rate of linear wear was 0.028 mm/year (standard deviation (SD) 0.010) for Group A, 0.023 mm/year (SD 0.010) for Group B, and 0.09 mm/year (SD 0.045) for Group C. Penetration was significantly higher in the UHMWPE liner group compared with both XLPE liner groups (p < 0.001) but no significant difference was noted between CoCr and OxZi when articulating with XLPE (p = 0.153). In this, the largest randomised study of this bearing surface, it appears that using a XLPE acetabular liner is more important in reducing THA component wear than the choice of femoral head bearing, at mid-term follow-up. There is a non-significant trend towards lower wear, coupling OxZi rather than CoCr with XLPE but long-term analysis is required to see if this observation changes with time and becomes significant. PMID:26130341

  2. Web Crawler System Based on Chrome Extension%基于Chrome扩展的爬虫系统设计与实现

    Institute of Scientific and Technical Information of China (English)

    魏少鹏; 夏小玲

    2016-01-01

    This article introduces a new crawler system based on Chromeextension in order to improve data collection effi‐ciency from web pages and reduce consumption of the system resource from crawler .This crawler system uses chrome browser to analysis web pages to prevent shielding of crawling object and asynchronous loading of web pages problems ,as well as the realization of structured data .Unattended active crawl can be achieved ,and information can be grabbed at the time when users are browsing Web pages by selecting the common user extension and server extension .Front and back is separated in the whole system ,and Program To Interface is used to cover it high expansibility .Finally ,verifying efficien‐cy and feasibility of the program by gaining premiership schedule from Sodasoccer website .%为了提高网页数据抓取效率,降低爬虫对系统资源的消耗,提出了一种基于Chrome扩展的爬虫系统。利用Chrome浏览器对网页进行解析,防止被爬取对象屏蔽和网页异步加载问题,并且实现数据结构化;通过选择普通用户版扩展和服务器版扩展,既可以实现无人值守主动抓取,也可以在用户浏览网页的同时抓取信息。整个系统前后端分离,并且采用面向接口编程,具有良好的扩展性。通过从搜达足球网站抓取英超赛程,验证了程序的高效可行性。

  3. Mechanical and fractographic characterization of the low activation chrome-steel F82H-mod in the brittle-ductile transition region

    International Nuclear Information System (INIS)

    The subject of this work is the examination of the basic applicability of the method of the Local Approach on low activation fusion reactor structural steels in the brittle-ductile transition region, by the example of the chrome-steel F82H-mod. Therefore series of differently notched and pre-cracked round specimen were destroyed at temperatures within the range -150 C to ambient temperature. The mechanical break parameters were determined, which are needed as input data for the parameter generation of the model. For the examination of the basic assumptions of the Local Approach, the fracture surfaces of the samples, as well as selected axial cross sections of broken specimens, were qualitatively and if possible also quantitatively evaluated by scanning electro microscopy (SEM). The numeric results show that the failure can be described by this method without problems only for samples with small notch radii (i.e. high stress-multi-axiality), at -150 C. On the basis of the mechanical and fractographic investigations is explainable, that only these samples fulfill all basic assumptions of the model and fail by pure cleavage fracture. For this effect a critical local stress at a characteristic weak point must be exceeded. On all other samples several different critical events leading to failure and accordingly to incompatible numeric results. For the same reason a transferability of the results of non-damaged structures to pre-cracked structures is likewise not possible. In order to apply the model to the examined steel even in the transition region, a modification is inevitable. (orig.)

  4. Effects of AS-cast and wrought cobalt-chrome-molybdenum and titanium-aluminium-vanadium alloys on cytokine gene expression and protein secretion in J774A.1 macrophages

    OpenAIRE

    S S Jakobsen; Larsen, A.; M Stoltenberg; J. M. Bruun; Soballe, K

    2007-01-01

    Insertion of metal implants is associated with a possible change in the delicate balance between pro- and anti-inflammatory proteins, probably leading to an unfavourable predominantly pro-inflammatory milieu. The most likely cause is an inappropriate activation of macrophages in close relation to the metal implant and wear-products. The aim of the present study was to compare surfaces of as-cast and wrought Cobalt-Chrome-Molybdenum (CoCrMo) alloys and Titanium-Aluminium-Vanadium (TiAlV) alloy...

  5. Caractérisation par MET de fissures de corrosion sous contrainte d'alliages à base de nickel : influence de la teneur en chrome et de la chimie du milieu

    OpenAIRE

    Delabrouille, Frédéric

    2004-01-01

    La corrosion sous contrainte (CSC) est un mode de dégradation qui affecte de nombreux alliages au sein des réacteurs à eau sous pression, notamment les alliages base nickel tubes des générateurs de vapeur (GV). La fissuration qu'elle engendre intervient tant du côté primaire que secondaire, en particulier dans des zones où la composition du milieu est mal définie. La sensibilité à la CSC des alliages base nickel dépend de leur teneur en chrome, ce qui a conduit au remplacement de l'alliage 60...

  6. Violet/blue chrysanthemums--metabolic engineering of the anthocyanin biosynthetic pathway results in novel petal colors.

    Science.gov (United States)

    Brugliera, Filippa; Tao, Guo-Qing; Tems, Ursula; Kalc, Gianna; Mouradova, Ekaterina; Price, Kym; Stevenson, Kim; Nakamura, Noriko; Stacey, Iolanda; Katsumoto, Yukihisa; Tanaka, Yoshikazu; Mason, John G

    2013-10-01

    Chrysanthemums (Chrysanthemum×morifolium Ramat.) are an important cut-flower and potted plant crop in the horticultural industry world wide. Chrysanthemums express the flavonoid 3'-hydroxylase (F3'H) gene and thus accumulate anthocyanins derived from cyanidin in their inflorescences which appear pink/red. Delphinidin-based anthocyanins are lacking due to the deficiency of a flavonoid 3', 5'-hydroxylase (F3'5'H), and so violet/blue chrysanthemum flower colors are not found. In this study, together with optimization of transgene expression and selection of the host cultivars and gene source, F3'5'H genes have been successfully utilized to produce transgenic bluish chrysanthemums that accumulate delphinidin-based anthocyanins. HPLC analysis and feeding experiments with a delphinidin precursor identified 16 cultivars of chrysanthemums out of 75 that were predicted to turn bluish upon delphinidin accumulation. A selection of eight cultivars were successfully transformed with F3'5'H genes under the control of different promoters. A pansy F3'5'H gene under the control of a chalcone synthase promoter fragment from rose resulted in the effective diversion of the anthocyanin pathway to produce delphinidin in transgenic chrysanthemum flower petals. The resultant petal color was bluish, with 40% of total anthocyanidins attributed to delphinidin. Increased delphinidin levels (up to 80%) were further achieved by hairpin RNA interference-mediated silencing of the endogenous F3'H gene. The resulting petal colors were novel bluish hues, not possible by hybridization breeding. This is the first report of the production of anthocyanins derived from delphinidin in chrysanthemum petals leading to novel flower color. PMID:23926066

  7. Determining the degradation efficiency and mechanisms of ethyl violet using HPLC-PDA-ESI-MS and GC-MS

    Directory of Open Access Journals (Sweden)

    Chung Wen-Hsin

    2012-06-01

    Full Text Available Abstract Background The discharge of wastewater that contains high concentrations of reactive dyes is a well-known problem associated with dyestuff activities. In recent years, semiconductor photocatalysis has become more and more attractive and important since it has a great potential to contribute to such environmental problems. One of the most important aspects of environmental photocatalysis is in the selection of semiconductor materials like ZnO and TiO2, which are close to being two of the ideal photocatalysts in several respects. For example, they are relatively inexpensive, and they provide photo-generated holes with high oxidizing power due to their wide band gap energy. In this work, nanostructural ZnO film on the Zn foil of the Alkaline-Manganese Dioxide-Zinc Cell was fabricated to degrade EV dye. The major innovation of this paper is to obtain the degradation mechanism of ethyl violet dyes resulting from the HPLC-PDA-ESI-MS analyses. Results The fabrication of ZnO nanostructures on zinc foils with a simple solution-based corrosion strategy and the synthesis, characterization, application, and implication of Zn would be reported in this study. Other objectives of this research are to identify the reaction intermediates and to understand the detailed degradation mechanism of EV dye, as model compound of triphenylmethane dye, with active Zn metal, by HPLC-ESI-MS and GC-MS. Conclusions ZnO nanostructure/Zn-foils had an excellent potential for future applications on the photocatalytic degradation of the organic dye in the environmental remediation. The intermediates of the degradation process were separated and characterized by the HPLC-PDA-ESI-MS and GC-MS, and twenty-six intermediates were characterized in this study. Based on the variation of the amount of intermediates, possible degradation pathways for the decolorization of dyes are also proposed and discussed.

  8. Influence of small dozes ultra-violet radiation on motion of dislocation in alkali-halide crystals

    Institute of Scientific and Technical Information of China (English)

    Victor; A.; Feodorov; Tatjana.; N.; Plushnikova; Andrey; V.; Chivanov; Margarita; V.Chemerkina; Roman; A.; Kirillov.

    2005-01-01

    The purpose of this work was research into influence of ultra-violet radiation on size of run of regional and screw dislocations in beams of dislocation sockets, formed at indentation surface of alkali-halide crystals. In experiments it was used crystals NaCl, with the quantitative maintenance of impurity 10-2 -10-3weight%, the wave length of UV-radiation λ=250 nanometers, the sizes of samples 10mm× 20mm× 2mm,temperature of samples was constant T=290 K.It is established that indentation and the simultaneous irradiation of samples a ultraviolet is increases size of run of head dispositions in dislocation sockets..It is marked, that influence UV-radiation nonequivalence for various times of an exposition. At small times (till 5 minutes) the size of run grows. The length of beams increases on ~ 50 %. At the further increase in time of influence of a ultraviolet the length of beams is reduced till the sizes corresponding stressing without an irradiation (Figs. 1, 2, 3). The effect is observed on dislocation beams of regional and screw orientations and most expressed at small loadings (in our experiments-10 grams) (Fig. 3).Observable effects are explained from positions dislocation-exciton interactions. At UV-radiation exciton cooperates with the charged step on a disposition, causing movement of a step along a disposition on one internuclear distance. Due to this interaction overcoming by a disposition of a grid of stoppers is facilitated.Big times of endurance cause a relaxation of pressure directly in a print that provides convertible movement of dispositions in area of a print and as consequence, reduction of length of beams of dislocation sockets.

  9. New technologies to enhance quality and safety of table eggs: ultra-violet treatment and modified atmosphere packaging

    Directory of Open Access Journals (Sweden)

    Frédérique Pasquali

    2014-12-01

    Full Text Available In the present study the effect of ultra-violet (UV treatment alone and in combination with 100% CO2 modified atmosphere packaging (MAP was evaluated both on the survival of naturally occurring bacteria, as well as on quality parameters of table eggs during 28 days of storage at 21°C. Table eggs were collected from the conveyor belt after the UV module, and placed on carton trays. A representative number of carton trays were packed in a high barrier multilayer pouch filled with 100% CO2. All eggs were stored at 21°C and analysed at 0, 1, 7, 14, 21 and 28 days of storage. Eggs not treated with UV and not packed were also included. On the eggshells total colony count, total coliforms and faecal coliforms counts, as well as the detection of Salmonella spp. were investigated. Moreover, chemical-functional parameters such as weight loss, albumen pH and Haugh Unit (HU were evaluated. The total colony count on UV treated table eggs was approximately 1 log10 CFU/g lower than untreated eggs (2.27 vs 3.29 log10 CFU/g. During storage, CO2 packed eggs maintained the initial values of HU, whereas the albumen pH decreased up to 1.5-2 points in comparison to unpacked eggs. The UV treatment was effective in reducing the total colony count on the surface of table eggs. MAP showed a great potential in maintaining/enhance the technological properties of egg constituents (higher foam stability of the albumen for meringue preparation without significantly impacting on the microbial load of table eggs.

  10. Strong violet-blue light photoluminescence emission at room temperature in SrZrO3: Joint experimental and theoretical study

    International Nuclear Information System (INIS)

    Ultrafine ordered and disordered SrZrO3 powders were prepared by the polymeric precursor method. The structural evolution from structural disorder to order was monitored by X-ray diffraction and X-ray absorption near-edge spectroscopy. Complex cluster vacancies [ZrO5.VOZ]and[SrO11.VOZ] (where VOZ=VOX, VO·andVO··) were proposed for disordered powders. The intense violet-blue light photoluminescence emission measured at room temperature in the disordered powders was attributed to complex cluster vacancies. High-level quantum mechanical calculations within the density functional theory framework were used to interpret the experimental results

  11. Extreme ultra-violet burst, particle heating, and whistler wave emission in fast magnetic reconnection induced by kink-driven Rayleigh-Taylor instability

    Science.gov (United States)

    Chai, Kil-Byoung; Zhai, Xiang; Bellan, Paul M.

    2016-03-01

    A spatially localized energetic extreme ultra-violet (EUV) burst is imaged at the presumed position of fast magnetic reconnection in a plasma jet produced by a coaxial helicity injection source; this EUV burst indicates strong localized electron heating. A circularly polarized high frequency magnetic field perturbation is simultaneously observed at some distance from the reconnection region indicating that the reconnection emits whistler waves and that Hall dynamics likely governs the reconnection. Spectroscopic measurement shows simultaneous fast ion heating. The electron heating is consistent with Ohmic dissipation, while the ion heating is consistent with ion trajectories becoming stochastic.

  12. Chemical characterization and toxicologic evaluation of airborne mixtures. Chemical characterization of Army colored smokes: inventory smoke mixes (red, violet, yellow, and green). Final report, 1980-1981

    Energy Technology Data Exchange (ETDEWEB)

    Rubin, I.B.; Buchanan, M.V.

    1983-06-01

    Red, violet, yellow, and green inventory smoke mixes were fractionated by vacuum sublimation, differential solubility and liquid chromatography. Two unique components, benzanthrone and dibenzochrysenedione, were purified by the same methods. Major components of the smoke mixes were isolated and identified by comparison to the pure dyes using a variety of instrumental techniques. A number of contaminants at very minor levels were identified by gas chromatography/mass spectroscopy. All of the smoke mixes contained relatively large quantities (10 to 25 percent) of chloroform insoluble or non-volatile undifferentiated carbonaceous material.

  13. Preparation of TiO2-SiO2 using Rice Husk Ash as Silica Source and The Kinetics Study as Photocatalyst in Methyl Violet Decolorization

    Directory of Open Access Journals (Sweden)

    Is Fatimah

    2015-03-01

    Full Text Available Preparation, characterization and utilization of TiO2-SiO2 as photocatalyst for methyl violet (MV decolorization has been conducted. In this research, preparation of TiO2-SiO2 was developed based on natural renewable silica source; rice husk ash (RHA via a sol-gel technique. The composite was formed by the dispersing of titanium isopropoxide as titania precursor into the gel of silica followed by aging, drying and calcination. The TiO2-SiO2 sample was characterized by powder X-ray diffraction (XRD, diffuse reflectance-UV Visible spectrophotometric analysis (DRUV-Vis, gas sorption analyzer and Scanning electron micrograph (SEM before its utilization as photocatalyst in methyl violet photooxidation. As comparison to the physicochemical character study, the synthesis of TiO2-SiO2 by using tetraethyl ortosilicate (TEOS was performed as a confirmation. Result showed that prepared TiO2-SiO2 has the character similar to TiO2-SiO2 as synthesized by TEOS precursor. The formation of crystalline titania in anatase and rutile phase was identified with increasing surface porosity data and the value of band gap energy which sufficiently contribute to a photocatalytic mechanism. The character data are in line with the kinetic data of methyl violet decolorization. From the compared photooxidation, photolysis, photocatalysis and adsorption process, it can be concluded that TiO2-SiO2 acts efficiently as a photocatalyst. © 2015 BCREC UNDIP. All rights reserved.Received: 23rd August 2014; Revised: 4th October 2014; Accepted: 20th October 2014 How to Cite: Fatimah, I., Said, A., Hasanah, U.A. (2015. Preparation of TiO2-SiO2 using Rice Husk Ash as Silica Source and The Kinetics Study as Photocatalyst in Methyl Violet Decolorization. Bulletin of Chemical Reaction Engineering & Catalysis, 10 (1: 43-49. (doi:10.9767/bcrec.10.1.7218.43-49Permalink/DOI: http://dx.doi.org/10.9767/bcrec.10.1.7218.43-49 

  14. Identificação e quantificação do cristal violeta em aguardentes de mandioca (tiquira Identification and characterization of crystal violet in cassava spirits (tiquira

    Directory of Open Access Journals (Sweden)

    Geraldino da Silva Santos

    2005-08-01

    Full Text Available Tiquira is a traditional homemade alcoholic distillate produced in the Maranhão State (Brazil, gotten from cassava (Manihot esculenta, Crantz.. It can be normally found on street markets. Due to the addition of tangerine leaves, the original tiquira has a bluish color. Samples of this beverage were acquired in the local trade and analyzed from the spectroanalytical point of view. The results indicated that these drinks had been adulterated by the addition of crystal violet, a potencialy hazardous compound. The identification and quantification of crystal violet in 10 spiked samples was accomplished by UV-Vis spectrophotometry through the standard addition method. In order to verify the efficiency of the proposed method, experiments on the quantification and recovery were carried out and the results indicated a content of crystal violet in the 10-6 to 10-7 mol L-1 range.

  15. Investigations on the growth, optical, thermal, dielectric, and laser damage threshold properties of crystal violet dye-doped potassium acid phthalate single crystal

    Science.gov (United States)

    Rao, G. Babu; Rajesh, P.; Ramasamy, P.

    2016-03-01

    Influence of crystal violet dye with different concentration on potassium acid phthalate single crystal grown by conventional method has been studied. No change has been observed in the structure, whereas changes have been observed in the external morphology of the crystal when the dyes are incorporated in the crystal lattice. Thermogravimetric and differential thermal analyses show the onset decomposition temperatures to be at 302, 285, 284, and 285 °C for pure, 0.1, 0.3, and 0.5 mol% crystal violet-doped potassium acid phthalate crystals, respectively. The dielectric measurement was carried out on the grown crystals as a function of frequency at various temperatures. In addition, strong luminescent emission bands at 638, 648, and 640 nm were observed in which the relative intensity was found to be reversed as a result of doping concentration. The laser damage threshold value significantly increased for dye-doped crystal in comparison with pure crystal which may make it suitable for the solid-state dye laser applications.

  16. Quantitative microscopical and histochemical study of the skin of mice under the effect of exposure to ultra violet rays type-B

    Directory of Open Access Journals (Sweden)

    Somaya H. Mohamed*, Fouad M. Badr*, Howayda Abed El-Aal,Rushdy W

    2003-09-01

    Full Text Available The modern industrial era, has benefits and also disadvantages. The main disadvantages are environmental pollution and ozone layer depletion. Ozone layer depletion leads to failure of absorption and prevention of harmful rays from penetration of earth atmosphere. The current work studied the effect of ultra violet-B rays on the skin of mice. Twenty-four mice were subjected to ultra violet-B rays in dose of 1.4J/cm2 for 15minutes every other day for 10weeks. Paraffin sections slides were prepared and stained with suitable histological stains to study the morphology, collagen and elastic fibers, mast cells and glycosaminoglycans materials in the skin. The study included quantitative morphometric analysis by image analyzer on some obtained data. The study revealed a statistically significant increase in the epidermal thickness (p<0.001, associated with necrotic cells, compact ortho-keratosis in the stratum corneum. A degenerated collagen fibers was observed in exposed dermal skin with statistically significant decrease in optical density of collagen fibers (p<0.001. There was a loss of elastic fibers fibrillary pattern. Also there was an increase in melanin pigments concentrations, mast cells, deposition of PAS positive materials in the basement membrane at dermo-epidermal junction, around blood vessels, sebaceous and sweat glands and hair follicles. The study concluded that there was a defined pathological change in the skin exposed to ultraviolet rays and adequate protective prophylactic application must be used to minimize the effect of ultraviolet radiations exposures.

  17. Low-loss optical waveguides for the near ultra-violet and visible spectral regions with Al2O3 thin films from atomic layer deposition

    International Nuclear Information System (INIS)

    In this work, we report low-loss single-mode integrated optical waveguides in the near ultra-violet and visible spectral regions with aluminum oxide (Al2O3) films using an atomic layer deposition (ALD) process. Alumina films were deposited on glass and fused silica substrates by the ALD process at substrate/chamber temperatures of 200 oC and 300 oC. Transmission spectra and waveguide measurements were performed in our alumina films with thicknesses in the range of 210-380 nm for the optical characterization. Those measurements allowed us to determine the optical constants (nw and kw), propagation loss, and thickness of the alumina films. The experimental results from the applied techniques show good agreement and demonstrate a low-loss optical waveguide. Our alumina thin-film waveguides are well transparent in the whole visible spectral region and also in an important region of the UV; the measured propagation loss is below 4 dB/cm down to a wavelength as short as 250 nm. The low propagation loss of these alumina guiding films, in particular in the near ultra-violet region which lacks materials with high optical performance, is extremely useful for several integrated optic applications.

  18. Application of Micro-cloud point extraction for spectrophotometric determination of Malachite green, Crystal violet and Rhodamine B in aqueous samples.

    Science.gov (United States)

    Ghasemi, Elham; Kaykhaii, Massoud

    2016-07-01

    A novel, green, simple and fast method was developed for spectrophotometric determination of Malachite green, Crystal violet, and Rhodamine B in water samples based on Micro-cloud Point extraction (MCPE) at room temperature. This is the first report on the application of MCPE on dyes. In this method, to reach the cloud point at room temperature, the MCPE procedure was carried out in brine using Triton X-114 as a non-ionic surfactant. The factors influencing the extraction efficiency were investigated and optimized. Under the optimized condition, calibration curves were found to be linear in the concentration range of 0.06-0.60mg/L, 0.10-0.80mg/L, and 0.03-0.30mg/L with the enrichment factors of 29.26, 85.47 and 28.36, respectively for Malachite green, Crystal violet, and Rhodamine B. Limit of detections were between 2.2 and 5.1μg/L. PMID:27085294

  19. Spectrophotometric determination of trace amounts of vanadium by formation of the vanadium-4-(2-pyridylazo) resorcinol (PAR) - crystal violet complex

    International Nuclear Information System (INIS)

    The anionic complex of vanadium with 4-(2-pyridylazo)resorcinol (PAR), obtained at pH 4.6 to 5.1, forms an ion pair with Crystal Violet. This ion pair can be extracted with benzene-isobutyl methyl ketone (3+2). In the extracted ion pair the proportions of vanadium to PAR to Crystal Violet are 1:1:1. The coloured extract gives an obsorption maximum at 585nm, and Beer's law is obeyed in the concentration range 0.05 to 0.5μgml-1 of vanadium. The molar absorptivity is equal to 1.1x105 lmol-1cm-1. The method was applied to the determination of trace amounts of vanadium in dried plant materials after wet washing of the sample and extraction of the vanadium as the N-benzoyl-N-phenyl-hydroxylamine complex. The results obtained for the determination of vanadium in serradella, rye straw and grain and trefoil showed a relative standard deviation of 8 to 15% at the 0.1 to 0.25p.p.m. level of vanadium and of about 25% at the 0.05p.p.m. level. (author)

  20. A case-control study of oral epithelial proliferative markers among Sudanese Toombak dippers using micronuclei assay, argyrophilic nucleolar organizer region, Papanicolaou and crystal violet methods

    Directory of Open Access Journals (Sweden)

    Anass M. Abbas

    2013-07-01

    Full Text Available The use of Toombak has been reported to play a major role in the etiology of oral cancer in Sudan. The cellular proliferative activity on the oral epithelium of 210 Toombak dippers was assessed by applying the micronuclei frequency, mean argyrophilic nucleolar organizer region (AgNOR counts, Papanicolaou method, and 1% crystal violet stain. Participants were divided into 3 groups: 200 were apparently healthy individuals, 100 were Toombak users (cases, 100 were non-tobacco users (control and 10 were patients with oral squamous cell carcinomas. Cytological atypia was identified among 4 (4%. Toombak users and was not found among the control group (P<0.04. The micronuclei frequencies were higher in Toombak users (1.026 than in the control group (0.356 (P<0.0001. The mean AgNOR counts in Toombak users (2.423 were higher than control group (1.303 (P<0.0001. Neither Toombak users nor control group showed mitotic figures in 1% crystal violet method. The results of this research showed that Toombak dipping is a high risk factor for increase in the cellular proliferation in the oral mucosa. The cytological proliferative marker methods used are useful for screening Toombak users.

  1. Generation of 3.5W high efficiency blue-violet laser by intracavity frequency-doubling of an all-solid-state tunable Ti:sapphire laser.

    Science.gov (United States)

    Ding, X; Wang, R; Zhang, H; Wen, W Q; Huang, L; Wang, P; Yao, J Q; Yu, X Y; Li, Z

    2008-03-31

    In this paper, we report a high power, high efficiency blue-violet laser obtained by intracavity frequency-doubling of an all-solid-state Q-switched tunable Ti:sapphire laser, which was pumped by a 532 nm intracavity frequency-doubled Nd:YAG laser. A beta-BaB2O4 (BBO) crystal was used for frequency-doubling of the Ti:sapphire laser and a V-shape folded three-mirror cavity was optimized to obtain high power high efficiency second harmonic generation (SHG). At an incident pump power of 22 W, the tunable output from 355 nm to 475 nm was achieved, involving the maximum average output of 3.5 W at 400 nm with an optical conversion efficiency of 16% from the 532 nm pump laser to the blue-violet output. The beam quality factor M(2) was measured to be Mx(2)=2.15, My(2)=2.38 for characterizing the tunable blue laser. PMID:18542555

  2. Low-cost nanoparticles sorbent from modified rice husk and a copolymer for efficient removal of Pb(II) and crystal violet from water.

    Science.gov (United States)

    Masoumi, Arameh; Hemmati, Khadijeh; Ghaemy, Mousa

    2016-03-01

    In this work, preparation of adsorbent nanoparticles based on treated low-value agricultural by-product rice husk (TARH), and poly(methylmethacrylate-co-maleic anhydride), poly(MMA-co-MA), is reported for the removal of Pb(II) ion and Crystal violet dye from water. The prepared adsorbent was characterized by FT-IR, SEM, AFM, DLS, BET and Zeta potential. The metal ion adsorption capability was determined for rice husk (RH), TARH, crosslinked poly(MMA-co-MA) (CNR), and CNR@TARH nanoparticles. Different factors affecting the adsorption of Pb(II) such as pH, contact time, initial metal ion concentration and also temperature were studied to investigate adsorption isotherms, kinetics and thermodynamics. For the four tested adsorption isotherm models, the equilibrium sorption data for CNR@TARH nanoparticles obeyed the Langmuir isotherm equation with maximum sorption capacity of 93.45 mg g(-1). The kinetic adsorption data fitted best the Lagergren pseudo-second order model. Regeneration of adsorbent was easily performed by adsorption/desorption experiments followed for 4 cycles. Finally, the ability of the nanoparticles to remove Crystal violet dye from aqueous solution was also investigated by varying the initial dye concentration, pH and immersion time and the adsorption mechanism followed the second-order kinetic model. PMID:26735725

  3. Parametric Evaluation of an Innovative Ultra-Violet PhotocatalyticOxidation (UVPCO) Air Cleaning Technology for Indoor Applications

    Energy Technology Data Exchange (ETDEWEB)

    Hodgson, Alfred T.; Sullivan, Douglas P.; Fisk, William J.

    2005-10-31

    An innovative Ultra-Violet Photocatalytic Oxidation (UVPCO) air cleaning technology employing a semitransparent catalyst coated on a semitransparent polymer substrate was evaluated to determine its effectiveness for treating mixtures of volatile organic compounds (VOCs) representative of indoor environments at low, indoor-relevant concentration levels. The experimental UVPCO contained four 30 by 30-cm honeycomb monoliths irradiated with nine UVA lamps arranged in three banks. A parametric evaluation of the effects of monolith thickness, air flow rate through the device, UV power, and reactant concentrations in inlet air was conducted for the purpose of suggesting design improvements. The UVPCO was challenged with three mixtures of VOCs. A synthetic office mixture contained 27 VOCs commonly measured in office buildings. A building product mixture was created by combining sources including painted wallboard, composite wood products, carpet systems, and vinyl flooring. The third mixture contained formaldehyde and acetaldehyde. Steady state concentrations were produced in a classroom laboratory or a 20-m{sup 3} chamber. Air was drawn through the UVPCO, and single-pass conversion efficiencies were measured from replicate samples collected upstream and downstream of the reactor. Thirteen experiments were conducted in total. In this UVPCO employing a semitransparent monolith design, an increase in monolith thickness is expected to result in general increases in both reaction efficiencies and absolute reaction rates for VOCs oxidized by photocatalysis. The thickness of individual monolith panels was varied between 1.2 and 5 cm (5 to 20 cm total thickness) in experiments with the office mixture. VOC reaction efficiencies and rates increased with monolith thickness. However, the analysis of the relationship was confounded by high reaction efficiencies in all configurations for a number of compounds. These reaction efficiencies approached or exceeded 90% for alcohols, glycol

  4. Effects of as-cast and wrought Cobalt-Chrome-Molybdenum and Titanium-Aluminium-Vanadium alloys on cytokine gene expression and protein secretion in J774A.1 macrophages

    DEFF Research Database (Denmark)

    Jakobsen, Stig Storgaard; Larsen, Agnete; Stoltenberg, Meredin;

    2007-01-01

    Insertion of metal implants is associated with a possible change in the delicate balance between pro- and anti-inflammatory proteins, probably leading to an unfavourable predominantly pro-inflammatory milieu. The most likely cause is an inappropriate activation of macrophages in close relation to...... the metal implant and wear-products. The aim of the present study was to compare surfaces of as-cast and wrought Cobalt-Chrome-Molybdenum (CoCrMo) alloys and Titanium-Aluminium-Vanadium (TiAlV) alloy when incubated with mouse macrophage J774A.1 cell cultures. Changes in pro- and anti...... asses the cell viability. Surface properties of the discs were characterised with a profilometer and with energy dispersive X-ray spectroscopy. We here report, for the first time, that the prosthetic material surface (non-phagocytable) of as-cast high carbon CoCrMo reduces the pro-inflammatory cytokine...

  5. The compatibility of chromium-aluminium steels with high pressure carbon dioxid at intermediate- temperatures; Compatibilite des aciers au chrome-aluminium avec le gaz carbonique sous pression aux temperatures moyennes

    Energy Technology Data Exchange (ETDEWEB)

    Leclercq, D.; Loriers, H.; David, R.; Darras, E. [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1964-07-01

    With a view to their use in the exchangers of nuclear reactors of the graphite-gas or heavy water-gas types, the behaviour of chromium-aluminium steels containing up to 7 per cent chromium and 1.5 per cent aluminium has been studied in the presence of high-pressure carbon dioxide at temperatures of between 400 and 700 deg. C. The two most interesting grades of steel (2 per cent Cr - 0.35 per cent Al - 0.35 per cent Mo and 7 per cent Cr - 1.5 per cent Al - 0.6 per cent Si) are still compatible with carbon dioxide up to 550 and 600 deg. C respectively. A hot dip aluminised coating considerably increases resistance to oxidation of the first grade and should make possible its use up to temperatures of at least 600 deg. C. (authors) [French] Dans l'optique de leur emploi dans les echangeurs de reacteurs nucleaires des filieres graphite-gaz ou eau lourde-gaz, le comportement en presence de gaz carbonique sous pression d'aciers au chrome-aluminium, contenant jusqu'a 7 pour cent de chrome et 1,5 pour cent d'aluminium a ete etudie entre 400 et 700 deg. C. Les deux nuances les plus interessantes (2 pour cent Cr - 0,35 pour cent Al - 0,35 pour cent Mo et 7 pour cent Cr - 1,5 pour cent Al - 0,6 pour cent Si) restent compatibles avec le gaz carbonique jusqu'a 550 et 600 deg. C respectivement. Un revetement d'aluminium, effectue par immersion dans un bain fondu, ameliore notablement la resistance a l'oxydation de la premiere et doit permettre son empioi jusqu'a 600 deg. C au moins. (auteurs)

  6. THE PERSPECTIVES OF THE APPLICATION AND THE DEVELOPMENT OF WELDING MATERIALS FOR THE WELDING OF AUSTENITIC STEEL WITH CHROME AND NICKEL IN ASSEMBLY CONDITIONS Перспективы применения и разработки сварочных материалов для сварки аустенитных хромоникелевых сталей в монтажных условиях

    OpenAIRE

    Gavrilov S. N.; Hitsov O. V.; Plomodyalo R. L.

    2013-01-01

    Existing welding materials for the welding of austenitic steel with chrome and nickel were examined in this article. We also gave the economic justification of the usage of cored wires when welding the austenitic steel with chrome and nickel in comparison with coated electrodes

  7. Effect of NaCl on the spectral and kinetic properties of cresyl violet (CV)-sodium dodecyl sulphate (SDS) complex

    Indian Academy of Sciences (India)

    K I Priyadarsini; Hari Mohan

    2003-08-01

    Effect of added NaCl on the spectral and kinetic properties of cationically charged dye (cresyl violet) and anionically charged surfactant (sodium dodecyl sulphate) were studied in the pre-micellar and micellar regions. Addition of 0.2M NaCl to dye-surfactant solution decreased the critical micellar concentration for the micellization of the dye in sodium dodecyl sulphate to 1.2 × 10-3 M. Time-resolved studies using a stopped-flow spectrometer showed that NaCl influences the dynamics of micellisation. Addition of NaCl during the dye-surfactant complex formation converted the complex into micellized form at NaCl concentration of 0.01 to 0.05 M. In contrast, much higher concentration of NaCl (2 M) is required for the salting-out effect of the dye-surfactant complex for conversion to the micellized form.

  8. Ultra-violet absorption induced modifications in bulk and nanoscale electrical transport properties of Al-doped ZnO thin films

    International Nuclear Information System (INIS)

    Using conductive atomic force microscopy and Kelvin probe force microscopy, we study local electrical transport properties in aluminum-doped zinc oxide (ZnO:Al or AZO) thin films. Current mapping shows a spatial variation in conductivity which corroborates well with the local mapping of donor concentration (∼1020 cm−3). In addition, a strong enhancement in the local current at grains is observed after exposing the film to ultra-violet (UV) light which is attributed to persistent photocurrent. Further, it is shown that UV absorption gives a smooth conduction in AZO film which in turn gives rise to an improvement in the bulk photoresponsivity of an n-AZO/p-Si heterojunction diode. This finding is in contrast to the belief that UV absorption in an AZO layer leads to an optical loss for the underneath absorbing layer of a heterojunction solar cell

  9. Ultra-violet wavelength shift for undoped CaF2 scintillation detector by two phase of liquid scintillator system in CANDLES

    International Nuclear Information System (INIS)

    CANDLES is a project to search for neutrinoless double beta decay of 48Ca with CaF2 scintillators. An effective 4π active shield is achieved by placing the CaF2 crystals in a liquid scintillator. Energy resolution is improved by converting the ultra-violet light of the CaF2 scintillator into the visible region with a wavelength shifter dissolved in the liquid scintillator. The newly developed technique, 'two phase system of liquid scintillator', is presented. It will be used to exploit the unique features of the CANDLES system. Experiments to determine liquid scintillator composition will be described. Performance of CANDLES will be demonstrated with prototype detectors. Obtained results indicate that the proposed two phase technique is effective for CANDLES system which will utilize several tons of CaF2 scintillators.

  10. Investigation on 447.3 nm blue-violet laser by extra-cavity frequency doubling of a diode-pumped cesium vapor laser

    Science.gov (United States)

    Xu, Dongdong; Chen, Fei; Guo, Jin; Shao, Mingzhen; Xie, Jijiang

    2016-09-01

    447.3 nm blue-violet lasers are investigated by extra-cavity single-pass second harmonic generation (SHG) of diode-pumped cesium vapor lasers (Cs-DPALs) using a LBO crystal. Two types of 894.6 nm Cs-DPAL are constructed, and the beam quality factors are Mx2=1.02, My2=1.13 and Mx2=2.13, Mx2=2.66, respectively. The maximum output powers for the two types of Cs-DPAL operating in pulsed mode are 0.692 W and 2.6 W, and the corresponding maximum second harmonics (SH) powers are 9.5 μW and 11.2 μW at optimal focusing parameter of 1.68, respectively. The relative insensitivity of SH power to the LBO crystal temperature and the influence of Cs laser beam quality on the SHG efficiency are analyzed qualitatively.

  11. Absolute atomic oxygen and nitrogen densities in radio-frequency driven atmospheric pressure cold plasmas: Synchrotron vacuum ultra-violet high-resolution Fourier-transform absorption measurements

    International Nuclear Information System (INIS)

    Reactive atomic species play a key role in emerging cold atmospheric pressure plasma applications, in particular, in plasma medicine. Absolute densities of atomic oxygen and atomic nitrogen were measured in a radio-frequency driven non-equilibrium plasma operated at atmospheric pressure using vacuum ultra-violet (VUV) absorption spectroscopy. The experiment was conducted on the DESIRS synchrotron beamline using a unique VUV Fourier-transform spectrometer. Measurements were carried out in plasmas operated in helium with air-like N2/O2 (4:1) admixtures. A maximum in the O-atom concentration of (9.1 ± 0.7)×1020 m−3 was found at admixtures of 0.35 vol. %, while the N-atom concentration exhibits a maximum of (5.7 ± 0.4)×1019 m−3 at 0.1 vol. %

  12. Efficient polymer light-emit ting diodes with violet blue emission based on blends of PSiF6-PPP and PSiFC6C6

    Institute of Scientific and Technical Information of China (English)

    TIAN Renyu; MO Yueqi; PENG Junbiao

    2006-01-01

    Efficient polymer light-emitting diodes (PLEDs) with violet blue emission were fabricated using blends of copolymers of paraphenylene-cosilafluorene (PSiF6-PPP) and polymer of poly (9,9'alkyl-3,6-silafluorene) (PSiFC6C6). The performances of the devices are sensitive to the blend ratio.When the mass ratio of PSiF6-PPP to PSiFC6C6 is 1.96% at luminance of 105 cd.m-2, its electroluminescent (EL) spectrum peaks at 398 nm and full width at half maximum is 67 nm. The improvements of the device performances were due to the energy transfer from PSiFC6C6 to PSiF6-PPP and the balanced injection of electrons and holes.

  13. Adsorption Properties of PVA/PAA/clay Composite Hydrogel Synthesized by Gamma Radiation and its Application in Removal of Crystal Violet Dye from Its Aqueous Solution

    International Nuclear Information System (INIS)

    Copolymer hydrogels composed of Poly vinyl alcohol (PVA) and Poly acrylic acid (PAA) were prepared by γ-irradiation in the presence of N,N’ methylene bis acrylamide (MBAM) as crosslinking agent or bentonite clay. The copolymers were characterized by FTIR and SEM. The dye adsorption experiments for Crystal Violet dye (CV) were carried out by using bath procedure. UV-visible absorption spectroscopy was used to determine the adsorption behavior. The effect of different copolymer composition, clay concentration, ph, contact time, adsorbent dose, initial dye concentration, and adsorption temperature were investigated to obtain the best experimental conditions. The adsorption equilibrium was attained after about 24h. of contact time. It was found that the adsorption process was correlated with Freundlich isotherm equation. Kinetic and thermodynamic studies of CV dye onto the prepared hydrogels were also evaluated

  14. Energy transfer in solid-state dye lasers based on methyl methacrylate co-doped with sulforhodamine B and crystal violet

    International Nuclear Information System (INIS)

    Laser action in methyl methacrylate (MMA) co-doped with sulforhodamine B and crystal violet dyes was investigated. The dye mixture was incorporated into a solid polymeric matrix and was pumped by a 532-nm Nd:YAG laser. Distributed feedback dye laser (DFDL) action was induced in the dye mixture using a prism arrangement both in the donor and acceptor regions by an energy transfer mechanism. Theoretically, the characteristics of acceptor and donor DFDLs, and the dependence of their pulse widths and output powers on acceptor—donor concentrations and pump power, were studied. Experimentally, the output energy of DFDL was measured at the emission peaks of donor and acceptor dyes for different pump powers and different acceptor—donor concentrations. Tuning of the output wavelength was achieved by varying the period of the gain modulation of the laser medium. The laser wavelength showed continuous tunability from 563 nm to 648 nm

  15. Ultra-violet absorption induced modifications in bulk and nanoscale electrical transport properties of Al-doped ZnO thin films

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Mohit; Basu, Tanmoy; Som, Tapobrata, E-mail: tsom@iopb.res.in [SUNAG Laboratory, Institute of Physics, Sachivalaya Marg, Bhubaneswar 751 005 (India)

    2015-08-07

    Using conductive atomic force microscopy and Kelvin probe force microscopy, we study local electrical transport properties in aluminum-doped zinc oxide (ZnO:Al or AZO) thin films. Current mapping shows a spatial variation in conductivity which corroborates well with the local mapping of donor concentration (∼10{sup 20 }cm{sup −3}). In addition, a strong enhancement in the local current at grains is observed after exposing the film to ultra-violet (UV) light which is attributed to persistent photocurrent. Further, it is shown that UV absorption gives a smooth conduction in AZO film which in turn gives rise to an improvement in the bulk photoresponsivity of an n-AZO/p-Si heterojunction diode. This finding is in contrast to the belief that UV absorption in an AZO layer leads to an optical loss for the underneath absorbing layer of a heterojunction solar cell.

  16. Raman study of different crystalline forms of PbCrO_{4} and PbCr_{1-x}S_{x}O_{4} solid solutions for the noninvasive identification of chrome yellows in paintings : a focus on works by Vincent van Gogh

    OpenAIRE

    Monico, Letizia; Janssens, Koen; Hendriks, Ella; Brunetti, Brunetto G.; Miliani, Costanza

    2014-01-01

    Abstract: Chrome yellows, a class of pigments frequently used by painters of the Impressionism and Post-impressionism period, are known for their different chemical stability; the latter depends on the chemical composition (PbCrO4, PbCr1-xSxO4) and crystalline structure (monoclinic or orthorhombic) of the material. The possibility to distinguish among different forms of this pigment is therefore relevant in order to extend knowledge on the corresponding degradation process that is observed on...

  17. 钴铬合金嵌体修复磨牙髓室底穿孔的体外研究%In vitro study of furcal perforation repaired with cobalt-chrome alloy inlays

    Institute of Scientific and Technical Information of China (English)

    王密; 尹仕海; 唐寅; 刘佳

    2011-01-01

    目的 探讨钴铬合金嵌体修复髓室底穿孔的操作步骤及修复效果.方法 收集新鲜拔除的人恒磨牙42颗:其中38颗用8号球钻在髓底中央制备直径2.1 mm的穿孔洞型,随机均分为A、B两个实验组;另外4颗为C组,只开髓不制备髓底穿孔,作阴性对照.A、B两组分别用钴铬合金嵌体和间接树脂嵌体修复髓底穿孔,并使用树脂加强型玻璃离子进行粘接.从2个实验组中各随机选4个用扫描电子显微镜观察粘接界面,其余15个样本用葡萄糖氧化酶-过氧化物酶法检测微渗漏.结果 A组微渗漏值在任意时间点均高于B组,但差异无统计学意义(P>0.05),A、B组均对根分叉的外形进行了良好的修复,但扫描电镜下,钴铬合金嵌体的界面宽度小于树脂嵌体.结论 在形态学和封闭性方面,钴铬合金嵌体修复磨牙髓室底穿孔效果良好.%Objective To evaluate the effect of furcal perforation treated with cobalt-chrome alloy inlays, including both morphologic and microleakage study. Methods 42 newly extracted human maxillary and mandibular molars were collected. 38 of them, perforations were made in the center of the pulp chamber floor by using the 8 high speed round bur, divided randomly into two experimental groups. The other intact 4 sample were used as the negative controls. In the experimental groups, group A were repaired by cobalt-chrome alloy inlays, group B were repaired by indirect composite inlay. Resin reinforced glass ionomer was used in all samples as cement. 4 of each group were evaluated under scanning electron microscope (SEM), and microleakage of others was measured by the concentration of leaked glucose with the oxidase-peroxidase method. Results Microleakage of group A was higher than group B, but no statistical difference (P>0.05). The two groups had reached a good furcafion shape.The gap width of group A was less than B group by SEM. Conclusion For repairing furcal perforation, the method of

  18. Enraizamento de estacas foliares de violeta-africana (Saintpaulia ionantha Wendl. em diferentes substratos Rooting of african violet (Saintpaulia ionantha Wendl. in different substrate

    Directory of Open Access Journals (Sweden)

    José Carlos Lopes

    2005-04-01

    Full Text Available O presente trabalho foi conduzido com objetivo de avaliar diferentes substratos no enraizamento de estacas foliares de violeta-africana (Saintpaulia ionantha Wendl. O trabalho foi desenvolvido em casa-de-vegetação, com tela de poliolefina 70%, no Centro de Ciências Agrárias da Universidade Federal do Espírito Santo, Alegre-ES. Utilizaram-se plantas adultas das cultivares New Mexico (flores lilás; Nancy (flores rosas; Stella (flores azuis e Mike (flores brancas, que foram aclimatadas; posteriormente, retiraram-se propágulos compostos por uma folha com pecíolo, reduzida a 2/3 do tamanho original, os quais foram esterilizados em solução de hipoclorito de sódio à concentração de 4%, durante três minutos. Foram utilizados cinco substratos: terra+areia+esterco, areia, pó de xaxim, vermiculita e água destilada, colocados em potes plásticos de 200 mL. O delineamento experimental empregado foi o de blocos ao acaso, com quatro repetições de 10 pecíolos cada. Pelos resultados evidenciou-se que a cultivar Nancy apresentou 100% de enraizamento em todos os substratos após 40 dias. A maior porcentagem de enraizamento foi obtida em estacas mantidas na água e o melhor desenvolvimento inicial no substrato de pó de xaxim.The present study was accomplished with the objective of evaluate different substrates on the rooting of african violet (Saintpaulia ionantha Wendl. The work was carried out in the greenhouse under a shading net (poliolefinas 70% in the Agrarian Science Center of Universidade Federal do Espírito Santo, in Alegre-ES. Were utilized acclimated plants of african violet (Saintpaulia ionantha Wendl, cultivar New Mexico (lilac flowers; Nancy (pink flowers; Stella (blue flowers e Mike (white flowers. The leaf stalks were reduced to 2/3 of the original size, sterilized with a 4% sodium hypochloride during three minutes. The substrates utilized were soil+sand+manure, sand, fern fiber dust, vermiculite and water in plastic pot (200 m

  19. FAST TRACK COMMUNICATION: Intense violet-blue emitting (CaCl2/SiO2) : Eu2+ phosphor powders for applications in UV-LED based phototherapy illuminators

    Science.gov (United States)

    Hao, Zhendong; Zhang, Jiahua; Zhang, Xia; Ren, Xinguang; Luo, Yongshi; Lu, Shaozhe; Wang, Xiaojun

    2008-09-01

    An intense violet-blue emitting (CaCl2/SiO2) : Eu2+ phosphor with a composition of 25% CaCl2 and 75% SiO2 is prepared by a solid state reaction. The phosphor emits at 427 nm with a narrow bandwidth of 21 nm. The photoluminescence (PL) intensities and fluorescence lifetimes are studied as a function of Eu2+ concentrations. It is observed that the PL intensity of (CaCl2/SiO2) : Eu2+ can be 30% higher than that of commercial Sr2P2O7 : Eu2+ phosphor under 395 nm excitation. (CaCl2/SiO2) : Eu2+ would be a promising new phosphor for converting near-ultraviolet radiation to violet-blue emission for a novel phototherapy illuminator using a near-ultraviolet (~395 nm) light emitting diode as the excitation source.

  20. A simple coordination complex exhibiting colour change on slight structural modification: Synthesis and crystal structures of violet and yellow forms of [NiII(opda)2(NCS)2] (opda = orthophenylenediamine)

    Indian Academy of Sciences (India)

    Sabbani Supriya; Samar K Das

    2010-09-01

    The violet-coloured compound [NiII(opda)2(NCS)2] (1) undergoes colour change to strawyellow colour retaining its molecular composition on standing over long period of time at room temperature in the solid state. Compound 1 (violet form) and its yellow-form [NiII(opda)2(NCS)2] (2) (opda = orthophenylenediammine) have been characterized by routine spectroscopic methods and single crystal X-ray diffraction analysis. Compound 1 crystallizes in monoclinic space group 21/ and its yellow form (compound 2) retains same space group. Their crystal structures show an intricate supramolecular network based on N-H$\\cdots$S hydrogen bonds, that involve amine and thiocyanate groups coordinated to nickel(II).