WorldWideScience

Sample records for chromates

  1. Low chromate diet in dermatology

    Directory of Open Access Journals (Sweden)

    Sharma Ashimav

    2009-01-01

    Full Text Available Chromium is an essential trace element found in soil, water, air, and in the biosphere. It is the fourth most common element in the earth′s crust, mostly used to manufacture stainless steel and other alloys. Chromate allergy is not uncommon and its prevalence rate is reported to be 6%. Once developed, it tends to persist for a long time. Chromate is present in most of the dietary items. Chromate content in food often varies considerably from place to place. However, certain foods are routinely high in chromate content. Chromate in the diet of a chromate-sensitive person can provoke dermatitis. Careful selection of food with relatively low chromate concentration can bring a reduction in the total dietary intake of chromate per day. This can influence outcome of the disease, especially chronic vesicular hand eczema due to chromate sensitivity, and can benefit a chromate-sensitive patient.

  2. Chromatic functors of graphs

    OpenAIRE

    Yoshinaga, Masahiko

    2015-01-01

    Finite graphs that have a common chromatic polynomial have the same number of regular $n$-colorings. A natural question is whether there exists a natural bijection between regular $n$-colorings. We address this question using a functorial formulation. Let $G$ be a simple graph. Then for each set $X$ we can associate a set of $X$-colorings. This defines a functor, "chromatic functor" from the category of sets with injections to itself. The first main result verifies that two finite graphs dete...

  3. Cleaning of Chromate Manufacture Process

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Sodium chromate solubility is determined in the range of NaOH concentrations from 450 to 810 g/L and solution temperatures from 30 to 110 ℃. The optimized conditions to separate sodium chromate from NaOH in leached solution are resolved. It is first found the method to efficiently separate sodium chromate from NaOH and sodium aluminate in crude sodium chromate. Bench-scale studies on the separating are performed. Finally, good separation results are achieved.

  4. Chromatic polynomials for simplicial complexes

    DEFF Research Database (Denmark)

    Møller, Jesper Michael; Nord, Gesche

    2016-01-01

    In this note we consider s s -chromatic polynomials for finite simplicial complexes. When s=1 s=1 , the 1 1 -chromatic polynomial is just the usual graph chromatic polynomial of the 1 1 -skeleton. In general, the s s -chromatic polynomial depends on the s s -skeleton and its value at r r is the n...

  5. Camera processing with chromatic aberration.

    Science.gov (United States)

    Korneliussen, Jan Tore; Hirakawa, Keigo

    2014-10-01

    Since the refractive index of materials commonly used for lens depends on the wavelengths of light, practical camera optics fail to converge light to a single point on an image plane. Known as chromatic aberration, this phenomenon distorts image details by introducing magnification error, defocus blur, and color fringes. Though achromatic and apochromatic lens designs reduce chromatic aberration to a degree, they are complex and expensive and they do not offer a perfect correction. In this paper, we propose a new postcapture processing scheme designed to overcome these problems computationally. Specifically, the proposed solution is comprised of chromatic aberration-tolerant demosaicking algorithm and post-demosaicking chromatic aberration correction. Experiments with simulated and real sensor data verify that the chromatic aberration is effectively corrected.

  6. Pupillary responses to chromatic stimulus

    Science.gov (United States)

    Suaste-Gomez, Ernesto; Rodriguez Guzman, M. C. Ma. Dolores A.; Druzgalski, Christopher

    2000-06-01

    Pupillary responses of the subjects under chromatic visual stimulation were filmed with video-oculography systems (VOG). Specifically, programmable chromatic visual stimuli were displayed on the monitor of a personal computer (PC) and responses tested in several normal subjects and those with ophthalmic pathologic conditions. Visual excitation utilized a reversal stimulus checkerboard pattern. Image processing techniques were applied in order to evaluate the pupil variations due to chromatic stimulation. In particular, the studies determined a relationship between pupillary response (PR) and steady-state retinal sensitivity (photopic vision). Finally, the retinal illuminance in trolands (td), as a product of the pupil area in mm2 and luminance in cd/m2 to full-field chromatic stimulation (FFCS) and checkerboard pattern reversal chromatic stimulation (CPRCS) was determined.

  7. Optimizing Chromatic Coupling Measurement in the LHC

    CERN Document Server

    Persson, Tobias

    2016-01-01

    Optimizing chromatic coupling measurement in the LHC Chromatic coupling introduces a dependency of transverse coupling with energy. LHC is equipped with skew sextupoles to compensate the possible adverse effects of chromatic coupling. In 2012 a beam-based correction was calculated and applied successfully for the fist time. However, the method used to reconstruct the chromatic coupling was dependent on stable tunes and equal chromaticities between the horizontal and vertical planes. In this article an improved method to calculate the chromatic coupling without these constraints is presented.

  8. Chromatic roots and hamiltonian paths

    DEFF Research Database (Denmark)

    Thomassen, Carsten

    2000-01-01

    We present a new connection between colorings and hamiltonian paths: If the chromatic polynomial of a graph has a noninteger root less than or equal to t(n) = 2/3 + 1/3 (3)root (26 + 6 root (33)) + 1/3 (3)root (26 - 6 root (33)) = 1.29559.... then the graph has no hamiltonian path. This result...

  9. Bacterial chromate reduction and product characterization

    Energy Technology Data Exchange (ETDEWEB)

    Mehlhorn, R.J. [Lawrence Berkeley Lab., CA (United States); Buchanan, B.B.; Leighton, T. [California Univ., Berkeley, CA (United States)

    1992-11-01

    Bacillus subtilis reduced hexavalent chromate to trivalent chromium under either aerobic or anaerobic conditions. Reduction of CR(VI) and appearance of extracellular Cr(III) were demonstrated by electron spin resonance and spectrophotometry. Chromate reduction was stimulated more than five-fold by freeze-thawing, indicating that intracellular reductases or chemical reductants reduce chromate more rapidly than do intact cells. Moderately concentrated cells (10% pellet volume after centrifugation) reduced approximately 40 {mu}M chromate/min (2 mg Cr/1-min) when exposed to 100 {mu}M chromate (5 mg Cr/1). Highly concentrated cells (70% pellet volume) reduced more than 99.8% of 2 mM chromate (100 mg Cr/1) within 15 min. This rate of chromate reduction was of the same order of magnitude as the rate of respiration in aerobic cells. A substantial fraction of the reduction product (ca. 75%) was extracellular Cr(M), which could readily be separated from the cells by centrifugation. At high chromate concentrations, some fraction of reduced CR(VI) appeared to be taken up by cells, consistent with a detection of intracellular paramagnetic products. At low chromate concentrations, undefined growth medium alone reduced Cr(VI), but at a slow rate, relative to cells. Under appropriate conditions, B. subtilis appears to be an organism of choice for detoxifying chromate-contaminated soil and water.

  10. Atom lens without chromatic aberrations

    CERN Document Server

    Efremov, Maxim A; Schleich, Wolfgang P

    2012-01-01

    We propose a lens for atoms with reduced chromatic aberrations and calculate its focal length and spot size. In our scheme a two-level atom interacts with a near-resonant standing light wave formed by two running waves of slightly different wave vectors, and a far-detuned running wave propagating perpendicular to the standing wave. We show that within the Raman-Nath approximation and for an adiabatically slow atom-light interaction, the phase acquired by the atom is independent of the incident atomic velocity.

  11. Connections between the matching and chromatic polynomials

    Directory of Open Access Journals (Sweden)

    E. J. Farrell

    1992-01-01

    Full Text Available The main results established are (i a connection between the matching and chromatic polynomials and (ii a formula for the matching polynomial of a general complement of a subgraph of a graph. Some deductions on matching and chromatic equivalence and uniqueness are made.

  12. CIRCULAR CHROMATIC NUMBER AND MYCIELSKI GRAPHS

    Institute of Scientific and Technical Information of China (English)

    Liu Hongmei

    2006-01-01

    For a general graph G, M(G) denotes its Mycielski graph. This article gives a number of new sufficient conditions for G to have the circular chromatic number xc (M(G))equals to the chromatic number x(M(G)), which have improved some best sufficient conditions published up to date.

  13. On chromatic and geometrical calibration

    DEFF Research Database (Denmark)

    Folm-Hansen, Jørgen

    1999-01-01

    of non-uniformity of the illumination of the image plane. Only the image deforming aberrations and the non-uniformity of illumination are included in the calibration models. The topics of the pinhole camera model and the extension to the Direct Linear Transform (DLT) are described. It is shown how......The main subject of the present thesis is different methods for the geometrical and chromatic calibration of cameras in various environments. For the monochromatic issues of the calibration we present the acquisition of monochrome images, the classic monochrome aberrations and the various sources...... the DLT can be extended with non-linear models of the common lens aberrations/errors some of them caused by manufacturing defects like decentering and thin prism distortion. The relation between a warping and the non-linear defects are shown. The issue of making a good resampling of an image by using...

  14. Chromatic aberration measurement for transmission interferometric testing.

    Science.gov (United States)

    Seong, Kibyung; Greivenkamp, John E

    2008-12-10

    A method of chromatic aberration measurement is described based on the transmitted wavefront of an optical element obtained from a Mach-Zehnder interferometer. The chromatic aberration is derived from transmitted wavefronts measured at five different wavelengths. Reverse ray tracing is used to remove induced aberrations associated with the interferometer from the measurement. In the interferometer, the wavefront transmitted through the sample is tested against a plano reference, allowing for the absolute determination of the wavefront radius of curvature. The chromatic aberrations of a singlet and a doublet have been measured.

  15. Chromate conversion coatings and their current application

    Directory of Open Access Journals (Sweden)

    P. Pokorny

    2016-04-01

    Full Text Available This paper describes formation, composition and possible production technologies of application chromate coatings. Summation of common examples of applications of these coatings in corrosion protection of metals and alloys is provided. Individual chromate coatings are divided by their dominant anions either with CrVI or CrIII. Restrictions of chromate coatings with dominantly CrVI and related toxicity of hexavalent chromium is discussed in detail. In conclusion, examples of both chromium and other, alternative coatings are summed up. Application of these coatings as a protection for concrete hot-dip galvanized reinforcement is also reviewed.

  16. Diffractive elements performance in chromatic confocal microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Garzon, J; Duque, D; Alean, A; Toledo, M [Grupo de Optica y EspectroscopIa, Centro de Ciencia Basica, Universidad Pontificia Bolivariana. Medellin (Colombia); Meneses, J [Laboratorio de Optica y Tratamiento de Senales, Instituto de Fisica, Universidad Industrial de Santander, Bucaramanga (Colombia); Gharbi, T, E-mail: jgarzonr10@une.net.co [Laboratoire d' Optique P. M. Duffieux, UMR-6603 CNR/Universite de Franche-Comte. 16 route de Gray, 25030 Besancon Cedex (France)

    2011-01-01

    The Confocal Laser Scanning Microscopy (CLSM) has been widely used in the semiconductor industry and biomedicine because of its depth discrimination capability. Subsequent to this technique has been developed in recent years Chromatic Confocal Microscopy. This method retains the same principle of confocal and offers the added advantage of removing the axial movement of the moving system. This advantage is usually accomplished with an optical element that generates a longitudinal chromatic aberration and a coding system that relates the axial position of each point of the sample with the wavelength that is focused on each. The present paper shows the performance of compact chromatic confocal microscope when some different diffractive elements are used for generation of longitudinal chromatic aberration. Diffractive elements, according to the process and manufacturing parameters, may have different diffraction efficiency and focus a specific wavelength in a specific focal position. The performance assessment is carried out with various light sources which exhibit an incoherent behaviour and a broad spectral width.

  17. On topological relaxations of chromatic conjectures

    CERN Document Server

    Simonyi, Gábor

    2010-01-01

    There are several famous unsolved conjectures about the chromatic number that were relaxed and already proven to hold for the fractional chromatic number. We discuss similar relaxations for the topological lower bound(s) of the chromatic number. In particular, we prove that such a relaxed version is true for the Behzad-Vizing conjecture and also discuss the conjectures of Hedetniemi and of Hadwiger from this point of view. For the latter, a similar statement was already proven in an earlier paper of the first author with G. Tardos, our main concern here is that the so-called odd Hadwiger conjecture looks much more difficult in this respect. We prove that the statement of the odd Hadwiger conjecture holds for large enough Kneser graphs and Schrijver graphs of any fixed chromatic number.

  18. Chromatic effects in long periodic transport channels

    Energy Technology Data Exchange (ETDEWEB)

    Litvinenko V. N.; Hao, Y.; Jing, Y.

    2015-05-03

    Long periodic transport channels are frequently used in accelerator complexes and suggested for using in high-energy ERLs for electron-hadron colliders. Without proper chromaticity compensation, such transport channels exhibit high sensitivity to the random orbit errors causing significant emittance growth. Such emittance growth can come from both the correlated and the uncorrelated energy spread. In this paper we present results of our theoretical and numerical studies of such effects and develop a criteria for acceptable chromaticity in such channels.

  19. Toward a unified chromatic induction model.

    Science.gov (United States)

    Otazu, Xavier; Parraga, C Alejandro; Vanrell, Maria

    2010-10-01

    In a previous work (X. Otazu, M. Vanrell, & C. A. Párraga, 2008b), we showed how several brightness induction effects can be predicted using a simple multiresolution wavelet model (BIWaM). Here we present a new model for chromatic induction processes (termed Chromatic Induction Wavelet Model or CIWaM), which is also implemented on a multiresolution framework and based on similar assumptions related to the spatial frequency and the contrast surround energy of the stimulus. The CIWaM can be interpreted as a very simple extension of the BIWaM to the chromatic channels, which in our case are defined in the MacLeod-Boynton (lsY) color space. This new model allows us to unify both chromatic assimilation and chromatic contrast effects in a single mathematical formulation. The predictions of the CIWaM were tested by means of several color and brightness induction experiments, which showed an acceptable agreement between model predictions and psychophysical data.

  20. Preliminary studies of a chromaticity tracker

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Cheng-Yang; /Fermilab

    2006-03-01

    A chromaticity tracker based on a method by D. McGinnis is proposed. This method starts with the slow modulation of the accelerating RF which causes the beam to respond to it. This beam modulation can be detected transversely with a Schottky pickup which after phase demodulation, the chromaticity can be calculated from it. However, to perform phase demodulation, the carrier frequency which is the betatron tune needs to be identified. The identification of the carrier frequency falls naturally onto the phase locked loop tune tracker which when locked to the betatron tune outputs this value in real time.

  1. Total dominator chromatic number of a graph

    Directory of Open Access Journals (Sweden)

    Adel P. Kazemi

    2015-06-01

    Full Text Available Given a graph $G$, the total dominator coloring problem seeks a proper coloring of $G$ with the additional property that every vertex in the graph is adjacent to all vertices of a color class. We seek to minimize the number of color classes. We initiate to study this problem on several classes of graphs, as well as finding general bounds and characterizations. We also compare the total dominator chromatic number of a graph with the chromatic number and the total domination number of it.

  2. A bivariate chromatic polynomial for signed graphs

    CERN Document Server

    Beck, Matthias

    2012-01-01

    We study Dohmen--P\\"onitz--Tittmann's bivariate chromatic polynomial $c_\\Gamma(k,l)$ which counts all $(k+l)$-colorings of a graph $\\Gamma$ such that adjacent vertices get different colors if they are $\\le k$. Our first contribution is an extension of $c_\\Gamma(k,l)$ to signed graphs, for which we obtain an inclusion--exclusion formula and several special evaluations giving rise, e.g., to polynomials that encode balanced subgraphs. Our second goal is to derive combinatorial reciprocity theorems for $c_\\Gamma(k,l)$ and its signed-graph analogues, reminiscent of Stanley's reciprocity theorem linking chromatic polynomials to acyclic orientations.

  3. Structure and Growth Mechanism of Lanthanum Chromate

    Institute of Scientific and Technical Information of China (English)

    Li Shengli; Liu Weiming; Ling Ziyu; Sun Liangcheng; Ao Qing; Fu Guifu

    2005-01-01

    The unit cell of lanthanum chromate was constructed by calculating equivalent points. By means of calculation of the hole octahedrally surrounded by O2- ions, it was considered that the sintered property of lanthanum chromate and the stability of Cr-O octahedron might be promoted by mixing a little Ca2+ ions. The growth mechanism was discussed in terms of structural ledge observed by SEM, the surfaces of the structural ledges parallel to (001), (010) and (110) planes, respectively. The misfit between (110) and (001) planes is only 0.0021 on common atomic plane, and the interconnection of the structured ledge may occur during crystal growth.

  4. The chromatic polynomial and list colorings

    DEFF Research Database (Denmark)

    Thomassen, Carsten

    2009-01-01

    We prove that, if a graph has a list of k available colors at every vertex, then the number of list-colorings is at least the chromatic polynomial evaluated at k when k is sufficiently large compared to the number of vertices of the graph.......We prove that, if a graph has a list of k available colors at every vertex, then the number of list-colorings is at least the chromatic polynomial evaluated at k when k is sufficiently large compared to the number of vertices of the graph....

  5. On the Star Chromatic Number of Graph Products

    Institute of Scientific and Technical Information of China (English)

    XU Chuan-liang; WANG Yi-ju

    2001-01-01

    The star chromatic number of a graph was introduced by A. Vince, which is a natural generalization of the chromatic number of a graph. In this paper, the star chromatic numbers of graph products G (×) H are discussed in some special cases.

  6. Anti-forensics of chromatic aberration

    Science.gov (United States)

    Mayer, Owen; Stamm, Matthew C.

    2015-03-01

    Over the past decade, a number of information forensic techniques have been developed to identify digital image manipulation and falsification. Recent research has shown, however, that an intelligent forger can use anti-forensic countermeasures to disguise their forgeries. In this paper, an anti-forensic technique is proposed to falsify the lateral chromatic aberration present in a digital image. Lateral chromatic aberration corresponds to the relative contraction or expansion between an image's color channels that occurs due to a lens's inability to focus all wavelengths of light on the same point. Previous work has used localized inconsistencies in an image's chromatic aberration to expose cut-and-paste image forgeries. The anti-forensic technique presented in this paper operates by estimating the expected lateral chromatic aberration at an image location, then removing deviations from this estimate caused by tampering or falsification. Experimental results are presented that demonstrate that our anti-forensic technique can be used to effectively disguise evidence of an image forgery.

  7. Chromatic Dispersion Estimation in Digital Coherent Receivers

    DEFF Research Database (Denmark)

    Soriano, Ruben Andres; Hauske, Fabian N.; Guerrero Gonzalez, Neil;

    2011-01-01

    Polarization-diverse coherent demodulation allows to compensate large values of accumulated linear distortion by digital signal processing. In particular, in uncompensated links without optical dispersion compensation, the parameter of the residual chromatic dispersion (CD) is vital to set the ac...

  8. Sorting chromatic sextupoles for easily and effectively correcting second order chromaticity in the Relativistic Heavy Ion Collider

    Energy Technology Data Exchange (ETDEWEB)

    Luo,Y.; Tepikian, S.; Fischer, W.; Robert-Demolaize, G.; Trbojevic, D.

    2009-01-02

    Based on the contributions of the chromatic sextupole families to the half-integer resonance driving terms, we discuss how to sort the chromatic sextupoles in the arcs of the Relativistic Heavy Ion Collider (RHIC) to easily and effectively correct the second order chromaticities. We propose a method with 4 knobs corresponding to 4 pairs of chromatic sextupole families to online correct the second order chromaticities. Numerical simulation justifies this method, showing that this method reduces the unbalance in the correction strengths of sextupole families and avoids the reversal of sextupole polarities. Therefore, this method yields larger dynamic apertures for the proposed RHIC 2009 100GeV polarized proton run lattices.

  9. Neural network correction of astrometric chromaticity

    CERN Document Server

    Gai, M

    2005-01-01

    In this paper we deal with the problem of chromaticity, i.e. apparent position variation of stellar images with their spectral distribution, using neural networks to analyse and process astronomical images. The goal is to remove this relevant source of systematic error in the data reduction of high precision astrometric experiments, like Gaia. This task can be accomplished thanks to the capability of neural networks to solve a nonlinear approximation problem, i.e. to construct an hypersurface that approximates a given set of scattered data couples. Images are encoded associating each of them with conveniently chosen moments, evaluated along the y axis. The technique proposed, in the current framework, reduces the initial chromaticity of few milliarcseconds to values of few microarcseconds.

  10. The chromatic number of comparability 3-hypergraphs

    OpenAIRE

    2014-01-01

    Beginning with the concepts of orientation for a 3-hypergraph and transitivity for an oriented 3-hypergraph, it is natural to study the class of comparability 3-hypergraphs (those that can be transitively oriented). In this work we show three different behaviors in respect to the relationship between the chromatic number and the clique number of a comparability 3-hypergraph, this is in contrast with the fact that a comparability simple graph is a perfect graph.

  11. Schottky signal analysis: tune and chromaticity computation

    CERN Document Server

    Chanon, Ondine

    2016-01-01

    Schottky monitors are used to determine important beam parameters in a non-destructive way. The Schottky signal is due to the internal statistical fluctuations of the particles inside the beam. In this report, after explaining the different components of a Schottky signal, an algorithm to compute the betatron tune is presented, followed by some ideas to compute machine chromaticity. The tests have been performed with offline and/or online LHC data.

  12. Improved step-by-step chromaticity compensation method for chromatic sextupole optimization

    CERN Document Server

    Liu, Gang-Wen; Jia, Qi-Ka; Li, Wei-Min; Wang, Lin

    2015-01-01

    The step-by-step chromaticity compensation method for chromatic sextupole optimization and dynamic aperture increase was proposed by E. Levichev and P. Piminov (E. Levichev and P. Piminov, 2006 [1]). Although this method can be used to enlarge the dynamic aperture of storage ring, it has some drawbacks. In this paper, we combined this method with evolutionary computation algorithms, and proposed an improved version of this method. In the improved method, the drawbacks are avoided, and thus better optimization results can be obtained.

  13. Chromatic polynomials of graphs from Kac-Moody algebras

    OpenAIRE

    Venkatesh, R.; Viswanath, Sankaran

    2013-01-01

    We give a new interpretation of the chromatic polynomial of a simple graph G in terms of the Kac-Moody Lie algebra with Dynkin diagram G. We show that the chromatic polynomial is essentially the q-Kostant partition function of this Lie algebra evaluated on the sum of the simple roots. Applying the Peterson recurrence formula for root multiplicities, we obtain a new realization of the chromatic polynomial as a weighted sum of paths in the bond lattice of G.

  14. Calibration and removal of lateral chromatic aberration in images

    OpenAIRE

    Mallon, John; Whelan, Paul F.

    2007-01-01

    This paper addresses the problem of compensating for lateral chromatic aberration in digital images through colour plane realignment. Two main contributions are made: the derivation of a model for lateral chromatic aberration in images, and the subsequent calibration of this model from a single view of a chess pattern. These advances lead to a practical and accurate alternative for the compensation of lateral chromatic aberrations. Experimental results validate the proposed models and calibra...

  15. An Application of Chromatic Prototypes for a Universal Information System

    CERN Document Server

    McCool, Matthew

    2007-01-01

    This paper presents research on color prototypes, categories, and the neuropsychology of color. These data suggest that chromatic prototypes may be useful for thematically organizing information systems.

  16. Reexploring the upper bound for the chromatic number of graphs

    Institute of Scientific and Technical Information of China (English)

    LI Shuchao; MAO Jingzhong

    2004-01-01

    The upper bound of the chromatic number of simple graphs is explored. Its original idea comes from Coffman, Hakimi and Schmeichel, who recently studied the chromatic number of graphs with strong conditions. In this paper, corresponding conditions are weakened and the result proves that of Ershov and Kozhukhin's.

  17. On the chromatic number of general Kneser hypergraphs

    DEFF Research Database (Denmark)

    Alishahi, Meysam; Hajiabolhassan, Hossein

    2015-01-01

    In a break-through paper, Lovász [20] determined the chromatic number of Kneser graphs. This was improved by Schrijver [27], by introducing the Schrijver subgraphs of Kneser graphs and showing that their chromatic number is the same as that of Kneser graphs. Alon, Frankl, and Lovász [2] extended ...

  18. Linear and chromatic optics measurements at RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Aiba, M.; Calaga, R.; Aiba, M.; Tomas, R.; Vanbavinkove, G.

    2010-05-23

    Measurements of chromatic beta-beating were carried out for the first time in the RHIC accelerator during Run 2009. The analysis package developed for the LHC was used to extract the off-momentum optics for injection and top energy. Results from the beam experiments and compassion to the optics model are presented. The primary goal of the RHIC experiments were execute an on-line measurement of the optics using the tools developed for the LHC. Turn-by-turn BPM trajectories (typically 1000 turns) acquired immediately after an external dipole kick are numerically analyzed to determine the optical parameters at the location of the beam position monitors (BPMs). For chromatic optics, a similar analysis, but on a beam with finite momentum offset(s). Each optical measurement typically is calculated from multiple data sets to capture statistical variations and ensure reproducibility. The procedure of measurement and analysis is detailed in ref [1, 2]. Two dedicated experiments were performed at RHIC with protons during Run 2009. The first at injection energy and optics and the other at 250 GeV and squeezed optics. The basic RHIC parameters relevant for the two experiments are listed in Table 1.

  19. Chromatic control in coextruded layered polymer microlenses

    CERN Document Server

    Crescimanno, Michael; Andrews, James H; Zhou, Chuanhong; Petrus, Joshua B; Merlo, Cory; Bagheri, Cameron; Hetzel, Connor; Tancabel, James; Singer, Kenneth D; Baer, Eric

    2015-01-01

    We describe the formation, characterization and theoretical understanding of microlenses comprised of alternating polystyrene and polymethylmethacrylate layers produced by multilayer coextrusion. These lenses are fabricated by photolithography, using a grayscale mask followed by plasma etching, so that the refractive index alternation of the bilayer stack appears across the radius of the microlens. The alternating quarter-wave thick layers form a one-dimensional photonic crystal whose dispersion augments the material dispersion, allowing one to sculpt the chromatic dispersion of the lens by adjusting the layered structure. Using Huygen's principle, we model our experimental measurements of the focal length of these lenses across the reflection band of the multilayer polymer film from which the microlens is fashioned. For a 56 micron diameter multilayered lens of focal length 300 microns, we measured a nearly 25 percent variation in the focal length across a shallow, 50 nm-wide reflection band.

  20. Molybdate based Alternatives to Chromating as a Passivation Treatment for Zinc

    DEFF Research Database (Denmark)

    Tang, Peter Torben; Bech-Nielsen, G.; Møller, Per

    1994-01-01

    in chromating. The corrosion protection provided by the process on zinc-plated parts is comparable to chromates. Depending on test conditions, especially pH value, the molybdate/phosphate process was found to be better than chromate at low pH values, equal to chromates in outdoor exposure tests and prohesion...

  1. Chromatic Polynomials Of Some (m,l-Hyperwheels

    Directory of Open Access Journals (Sweden)

    Julian A. Allagan

    2014-03-01

    Full Text Available In this paper, using a standard method of computing the chromatic polynomial of hypergraphs, we introduce a new reduction theorem which allows us to find explicit formulae for the chromatic polynomials of some (complete non-uniform $(m,l-$hyperwheels and non-uniform $(m,l-$hyperfans. These hypergraphs, constructed through a ``join" graph operation, are some generalizations of the well-known wheel and fan graphs, respectively. Further, we revisit some results concerning these graphs and present their chromatic polynomials in a standard form that involves the Stirling numbers of the second kind.

  2. Abnormal pupillary light reflex with chromatic pupillometry in Gaucher disease

    Science.gov (United States)

    Narita, Aya; Shirai, Kentarou; Kubota, Norika; Takayama, Rumiko; Takahashi, Yukitoshi; Onuki, Takanori; Numakura, Chikahiko; Kato, Mitsuhiro; Hamada, Yusuke; Sakai, Norio; Ohno, Atsuko; Asami, Maya; Matsushita, Shoko; Hayashi, Anri; Kumada, Tomohiro; Fujii, Tatsuya; Horino, Asako; Inoue, Takeshi; Kuki, Ichiro; Asakawa, Ken; Ishikawa, Hitoshi; Ohno, Koyo; Nishimura, Yoko; Tamasaki, Akiko; Maegaki, Yoshihiro; Ohno, Kousaku

    2014-01-01

    The hallmark of neuronopathic Gaucher disease (GD) is oculomotor abnormalities, but ophthalmological assessment is difficult in uncooperative patients. Chromatic pupillometry is a quantitative method to assess the pupillary light reflex (PLR) with minimal patient cooperation. Thus, we investigated whether chromatic pupillometry could be useful for neurological evaluations in GD. In our neuronopathic GD patients, red light-induced PLR was markedly impaired, whereas blue light-induced PLR was relatively spared. In addition, patients with non-neuronopathic GD showed no abnormalities. These novel findings show that chromatic pupillometry is a convenient method to detect neurological signs and monitor the course of disease in neuronopathic GD. PMID:25356393

  3. CHROMATIC-AREA EFFECT ON HOMOGENEOUS COLOR OF A ROOM FLOOR IN NATURAL INDOOR ENVIRONMENT

    OpenAIRE

    2009-01-01

    Chromatic-area effect is a phenomenon by which color appearance of chromatic surface changes when a size (visual angle) of increases without any physical change of the surface. Lightness and saturation of a large chromatic area generally increase compared to a smaller chromatic area. We investigated this chromatic-area effect on homogeneous color of a room floor under light environment in the day (white daylight) and in the night (a fluorescent lamp). Observes performed color matching between...

  4. Chromatic Shadow Detection and Tracking for Moving Foreground Segmentation

    DEFF Research Database (Denmark)

    Huerta, Ivan; Holte, Michael Boelstoft; Moeslund, Thomas B.;

    2015-01-01

    chromatic moving cast shadow regions and those regions detected as moving objects. In essence, those regions corresponding to potential shadows are detected based on edge partitioning and colour statistics. Subsequently (i) temporal similarities between textures and (ii) spatial similarities between...

  5. Measuring chromatic aberrations in imaging systems using plasmonic nanoparticles

    Science.gov (United States)

    Gennaro, Sylvain D.; Roschuk, Tyler R.; Maier, Stefan A.; Oulton, Rupert F.

    2016-04-01

    Chromatic aberration in optical systems arises from the wavelength dependence of a glass's refractive index. Polychromatic rays incident upon an optical surface are refracted at slightly different angles and in traversing an optical system follow distinct paths creating images displaced according to color. Although arising from dispersion, it manifests as a spatial distortion correctable only with compound lenses with multiple glasses and accumulates in complicated imaging systems. While chromatic aberration is measured with interferometry, simple methods are attractive for their ease of use and low cost. In this letter we retrieve the longitudinal chromatic focal shift of high numerical aperture (NA) microscope objectives from the extinction spectra of metallic nanoparticles within the focal plane. The method is accurate for high NA objectives with apochromatic correction, and enables rapid assessment of the chromatic aberration of any complete microscopy systems, since it is straightforward to implement

  6. Chromatic $k$-Mean Clustering in High Dimensional Space

    CERN Document Server

    Ding, Hu

    2012-01-01

    In this paper, we study a new type of clustering problem, called {\\em Chromatic Clustering}, in high dimensional space. Chromatic clustering seeks to partition a set of colored points into groups (or clusters) so that no group contains points with the same color and a certain objective function is optimized. In this paper, we focus on $k$-mean clustering, and investigate its hardness and approximation solutions. The additional coloring requirement destroys some key properties used in existing $k$-mean clustering techniques (for the ordinary clustering problem), and significantly complicates the problem. There is no FPTAS for the chromatic clustering problem, even if $k=2$. Based on several new geometric observations and an interesting sphere peeling approach, we show that a near linear time (on $n$ and $d$) $(1+\\epsilon)$-approximation is, however, still achievable for the chromatic clustering problem.

  7. Chromatic and Dispersive Effects in Nonlinear Integrable Optics

    CERN Document Server

    Webb, Stephen D; Valishev, Alexander; Nagaitsev, Sergei N; Danilov, Viatcheslav V

    2015-01-01

    Proton accumulator rings and other circular hadron accelerators are susceptible to intensity-driven parametric instabilities because the zero-current charged particle dynamics are characterized by a single tune. Landau damping can suppress these instabilities, which requires energy spread in the beam or introducing nonlinear magnets such as octupoles. However, this approach reduces dynamic aperture. Nonlinear integrable optics can suppress parametric instabilities independent of energy spread in the distribution, while preserving the dynamic aperture. This novel approach promises to reduce particle losses and enable order-of-magnitude increases in beam intensity. In this paper we present results, obtained using the Lie operator formalism, on how chromaticity and dispersion affect particle orbits in integrable optics. We conclude that chromaticity in general breaks the integrability, unless the vertical and horizontal chromaticities are equal. Because of this, the chromaticity correcting magnets can be weaker ...

  8. All-fiber interferometer for chromatic dispersion measurements

    OpenAIRE

    Thévenaz, Luc; Pellaux, J. P.; Von der Weid, J. P.

    1988-01-01

    An all-fiber interferometric method for chromatic dispersion measurements in meter-length single-mode fibers is presented. In a Michelson setup the physical length of a reference fiber was varied so as to obtain adjustable optical delay. Time resolution, ease of manipulation, and mechanical isolation are considerably improved with respect to conventional interferometers. Resolution of group delay measurement and chromatic dispersion over the full 1100-1700-nm spectral range are better than 5 ...

  9. Wide-angle chromatic aberration corrector for the human eye.

    Science.gov (United States)

    Benny, Yael; Manzanera, Silvestre; Prieto, Pedro M; Ribak, Erez N; Artal, Pablo

    2007-06-01

    The human eye is affected by large chromatic aberration. This may limit vision and makes it difficult to see fine retinal details in ophthalmoscopy. We designed and built a two-triplet system for correcting the average longitudinal chromatic aberration of the eye while keeping a reasonably wide field of view. Measurements in real eyes were conducted to examine the level and optical quality of the correction. We also performed some tests to evaluate the effect of the corrector on visual performance.

  10. FCC-ee final focus with chromaticity correction

    CERN Document Server

    Garcia, H; Tomás, R

    2014-01-01

    A 100 km circular electron-positron collider is considered as one of the possible future high energy facilities. In order to achieve a high luminosity, strong beam focusing at the Interaction Point (IP) is used requiring the correction of the chromatic aberrations. In this paper we study preliminary designs of a Final Focus System (FFS) for the FCC-ee collider with chromatic correction. Beam orbit stability and dynamic aperture calculations are also presented.

  11. Studies on biological reduction of chromate by Streptomyces griseus

    Energy Technology Data Exchange (ETDEWEB)

    Poopal, Ashwini C. [Division of Biochemical Sciences, National Chemical Laboratory, Dr Homi Bhabha Road, Pune 411008 (India); Laxman, R. Seeta, E-mail: rseetalaxman@yahoo.co.in [Division of Biochemical Sciences, National Chemical Laboratory, Dr Homi Bhabha Road, Pune 411008 (India)

    2009-09-30

    Chromium is a toxic heavy metal used in various industries and leads to environmental pollution due to improper handling. The most toxic form of chromium Cr(VI) can be converted to less toxic Cr(III) by reduction. Among the actinomycetes tested for chromate reduction, thirteen strains reduced Cr(VI) to Cr(III), of which one strain of Streptomyces griseus (NCIM 2020) was most efficient showing complete reduction within 24 h. The organism was able to use a number of carbon sources as electron donors. Sulphate, nitrate, chloride and carbonate had no effect on chromate reduction during growth while cations such as Cd, Ni, Co and Cu were inhibitory to varying degrees. Chromate reduction was associated with the bacterial cells and sonication was the best method of cell breakage to release the enzyme. The enzyme was constitutive and did not require presence of chromate during growth for expression of activity. Chromate reduction with cell free extract (CFE) was observed without added NADH. However, addition of NAD(P)H resulted in 2-3-fold increase in activity. Chromate reductase showed optimum activity at 28 deg. C and pH 7.

  12. Chick eyes compensate for chromatic simulations of hyperopic and myopic defocus: Evidence that the eye uses longitudinal chromatic aberration to guide eye-growth

    OpenAIRE

    Rucker, Frances J.; Wallman, Josh

    2009-01-01

    Longitudinal chromatic aberration (LCA) causes short wavelengths to be focused in front of long wavelengths. This chromatic signal is evidently used to guide ocular accommodation. We asked whether chick eyes exposed to static gratings simulating the chromatic effects of myopic or hyperopic defocus would “compensate” for the simulated defocus.

  13. Chromate Binding and Removal by the Molybdate-Binding Protein ModA.

    Science.gov (United States)

    Karpus, Jason; Bosscher, Michael; Ajiboye, Ifedayo; Zhang, Liang; He, Chuan

    2017-02-02

    Effective and cheap methods and techniques for the safe removal of hexavalent chromate from the environment are in increasingly high demand. High concentrations of hexavalent chromate have been shown to have numerous harmful effects on human biology. We show that the E. coli molybdate-binding protein ModA is a genetically encoded tool capable of removing chromate from aqueous solutions. Although previously reported to not bind chromate, we show that ModA binds chromate tightly and is capable of removing chromate to levels well below current US federal standards.

  14. Chromatically unique 6-bridge graph theta(a,a,a,b,b,c

    Directory of Open Access Journals (Sweden)

    N.S.A. Karim

    2016-04-01

    Full Text Available For a graph $G$, let $P(G,\\lambda$ denote the chromatic polynomial of $G$. Two graphs $G$ and $H$ are chromatically equivalent if they share the same chromatic polynomial. A graph $G$ is chromatically unique if for any graph chromatically equivalent to $G$ is isomorphic to $G$. In this paper, the chromatically unique of a new family of 6-bridge graph $\\theta(a,a,a,b,b,c$ where $2\\le a\\le b\\le c$ is investigated.

  15. Color constancy through inverse-intensity chromaticity space

    Science.gov (United States)

    Tan, Robby T.; Nishino, Ko; Ikeuchi, Katsushi

    2004-03-01

    Existing color constancy methods cannot handle both uniformly colored surfaces and highly textured surfaces in a single integrated framework. Statistics-based methods require many surface colors and become error prone when there are only a few surface colors. In contrast, dichromatic-based methods can successfully handle uniformly colored surfaces but cannot be applied to highly textured surfaces, since they require precise color segmentation. We present a single integrated method to estimate illumination chromaticity from single-colored and multicolored surfaces. Unlike existing dichromatic-based methods, the proposed method requires only rough highlight regions without segmenting the colors inside them. We show that, by analyzing highlights, a direct correlation between illumination chromaticity and image chromaticity can be obtained. This correlation is clearly described in ``inverse-intensity chromaticity space,'' a novel two-dimensional space that we introduce. In addition, when Hough transform and histogram analysis is utilized in this space, illumination chromaticity can be estimated robustly, even for a highly textured surface.

  16. Correcting the Chromatic Aberration in Barrel Distortion of Endoscopic Images

    Directory of Open Access Journals (Sweden)

    Y. M. Harry Ng

    2003-04-01

    Full Text Available Modern endoscopes offer physicians a wide-angle field of view (FOV for minimally invasive therapies. However, the high level of barrel distortion may prevent accurate perception of image. Fortunately, this kind of distortion may be corrected by digital image processing. In this paper we investigate the chromatic aberrations in the barrel distortion of endoscopic images. In the past, chromatic aberration in endoscopes is corrected by achromatic lenses or active lens control. In contrast, we take a computational approach by modifying the concept of image warping and the existing barrel distortion correction algorithm to tackle the chromatic aberration problem. In addition, an error function for the determination of the level of centroid coincidence is proposed. Simulation and experimental results confirm the effectiveness of our method.

  17. Chromatic effects of the atmosphere on astronomical adaptive optics.

    Science.gov (United States)

    Devaney, Nicholas; Goncharov, Alexander V; Dainty, J Christopher

    2008-03-10

    The atmosphere introduces chromatic errors that may limit the performance of adaptive optics (AO) systems on large telescopes. Various aspects of this problem have been considered in the literature over the past two decades. It is necessary to revisit this problem in order to examine the effect on currently planned systems, including very high-order AO on current 8-10 m class telescopes and on future 30-42 m extremely large telescopes. We review the literature on chromatic effects and combine an analysis of all effects in one place. We examine implications for AO and point out some effects that should be taken into account in the design of future systems. In particular we show that attention should be paid to chromatic pupil shifts, which may arise in components such as atmospheric dispersion compensators.

  18. Longitudinal chromatic aberration of the human infant eye.

    Science.gov (United States)

    Wang, Jingyun; Candy, T Rowan; Teel, Danielle F W; Jacobs, Robert J

    2008-09-01

    Although the longitudinal chromatic aberration (LCA) of the adult eye has been studied, there are no data collected from the human infant eye. A chromatic retinoscope was used to measure cyclopleged infant and adult refractions with four pseudomonochromatic sources (centered at 472, 538, 589, and 652 nm) and with polychromatic light. The LCA of the infant eyes between 472 and 652 nm was a factor of 1.7 greater than the LCA found in the adult group: infant mean=1.62 D, SD+/- 0.14 D; adult mean=0.96 D, SD+/- 0.17 D. The elevated level of LCA in infant eyes is consistent with the greater optical power of the immature eye and indicates similar chromatic dispersion in infant and adult eyes. The implications for visual performance, defocus detection, and measurement of refraction are discussed.

  19. Dynamic compensation of chromatic aberration in a programmable diffractive lens.

    Science.gov (United States)

    Millán, María S; Otón, Joaquín; Pérez-Cabré, Elisabet

    2006-10-02

    A proposal to dynamically compensate chromatic aberration of a programmable phase Fresnel lens displayed on a liquid crystal device and working under broadband illumination is presented. It is based on time multiplexing a set of lenses, designed with a common focal length for different wavelengths, and a tunable spectral filter that makes each sublens work almost monochromatically. Both the tunable filter and the sublens displayed by the spatial light modulator are synchronized. The whole set of sublenses are displayed within the integration time of the sensor. As a result the central order focalization has a unique location at the focal plane and it is common for all selected wavelengths. Transversal chromatic aberration of the polychromatic point spread function is reduced by properly adjusting the pupil size of each sublens. Longitudinal chromatic aberration is compensated by making depth of focus curves coincident for the selected wavelengths. Experimental results are in very good agreement with theory.

  20. Low chromatic aberration hexapole for molecular state selection

    Science.gov (United States)

    Ke, Yi; Deng, Xiao-Bing; Hu, Zhong-Kun

    2016-01-01

    In molecular beam state-selection experiments, the electrostatic hexapole acts as an optical lens, imaging molecules from the source to the focus. The molecular longitudinal velocity spread induces the phenomenon of chromatic aberration, which will reduce the state-selection purity. We propose a scheme which can effectively reduce the chromatic aberration by changing the hexapole voltage operating manner. The hexapole is already charged before molecules arrive at the entrance of the hexapole. When molecules are completely inside the hexapole, the voltage is switched off rapidly at an appropriate time. In this manner, faster molecules travel a longer hexapole focusing region than slower molecules. Therefore the focusing positions of molecules with different velocities become close. Numerical trajectory simulations of molecular state selection are carried out, and the results show that this low chromatic aberration hexapole can significantly improve the state purity from 46.2% to 87.0%.

  1. Fabrication of anodic aluminum oxide with incorporated chromate ions

    Science.gov (United States)

    Stępniowski, Wojciech J.; Norek, Małgorzata; Michalska-Domańska, Marta; Bombalska, Aneta; Nowak-Stępniowska, Agata; Kwaśny, Mirosław; Bojar, Zbigniew

    2012-10-01

    The anodization of aluminum in 0.3 M chromic acid is studied. The influence of operating conditions (like anodizing voltage and electrolyte's temperature) on the nanoporous anodic aluminum oxide geometry (including pore diameter, interpore distance, the oxide layer thickness and pores density) is thoroughly investigated. The results revealed typical correlations of the anodic alumina nanopore geometry with operating conditions, such as linear increase of pore diameter and interpore distance with anodizing voltage. The anodic aluminum oxide is characterized by a low pores arrangement, as determined by Fast Fourier transforms analyses of the FE-SEM images, which translates into a high concentration of oxygen vacancies. Moreover, an optimal experimental condition where chromate ions are being successfully incorporated into the anodic alumina walls, have been determined: the higher oxide growth rate the more chromate ions are being trapped. The trapped chromate ions and a high concentration of oxygen vacancies make the anodic aluminum oxide a promising luminescent material.

  2. The investigation of chromatic aberration correction for digital eye fundus images

    OpenAIRE

    Jakstys, V.; Marcinkevicius, V.; Treigys, P.

    2016-01-01

    This paper focuses on the lateral chromatic aberration correction in images captured with Optomed SmartScope M5 camera. This portable non-mydriatic eye fundus orbital camera does not have chromatic lenses. When photo camera system is designed without chromatic lenses, it is necessary to apply image processing algorithms for lateral chromatic aberration effect correction. These algorithms try to scale the fringed colour channels so that all channels spatially overlap each other ...

  3. RECURSIVE FORMULA FOR CALCULATING THE CHROMATIC POLYNOMIAL OF A GRAPH BY VERTEX DELETION

    Institute of Scientific and Technical Information of China (English)

    许进

    2004-01-01

    A new recursive vertex-deleting formula for the computation of the chromatic polynomial of a graph is obtained in this paper. This algorithm is not only a good tool for further studying chromatic polynomials but also the fastest among all the algorithms for the computation of chromatic polynomials.

  4. Electrochemical reduction of dilute chromate solutions on carbon felt electrodes

    NARCIS (Netherlands)

    Frenzel, Ines; Holdik, Hans; Barmashenko, Vladimir; Stamatialis, Dimitrios F.; Wessling, Matthias

    2006-01-01

    Carbon felt is a potential material for electrochemical reduction of chromates. Very dilute solutions may be efficiently treated due to its large specific surface area and high porosity. In this work, the up-scaling of this technology is investigated using a new type of separated cell and once-throu

  5. CHROMATIC NUMBER OF SQUARE OF MAXIMAL OUTERPLANAR GRAPHS

    Institute of Scientific and Technical Information of China (English)

    Luo Xiaofang

    2007-01-01

    Let χ(G2) denote the chromatic number of the square of a maximal outerplanar graph G and Q denote a maximal outerplanar graph obtained by adding three chords and χ(G2) = Δ + 2 if and only if G is Q, where Δ represents the maximum degree of G.

  6. Chromatic-Spatial Vision of the Aging Eye

    Science.gov (United States)

    Werner, John S.; Delahunt, Peter B.; Hardy, Joseph L.

    2004-07-01

    The human visual system undergoes continuous anatomical, physiological and functional changes throughout the life span. There is also continuous change in the spectral distribution and intensity of light reaching the retina from infancy through senescence, primarily due to changes in the absorption of short-wave light by the lens. Despite these changes in the retinal stimulus and the signals leaving the retina for perceptual analysis, color appearance is relatively stable during aging as measured by broadband reflective or self-luminous samples, the wavelengths of unique blue and yellow, and the achromatic locus. Measures of ocular media density for younger and older observers show, indeed, that color appearance is independent of ocular media density. This may be explained by a renormalization process that was demonstrated by measuring the chromaticity of the achromatic point before and after cataract surgery. There was a shift following cataract surgery (removal of a brunescent lens) that was initially toward yellow in color space, but over the course of months, drifted back in the direction of the achromatic point before surgery. The spatial characteristics of color mechanisms were quantified for younger and older observers in terms of chromatic perceptive fields and the chromatic contrast sensitivity functions. Younger and older observers differed with small spots or with chromatic spatial gratings near threshold, but there were no significant differences with larger spots or suprathreshold spatial gratings.

  7. Refractive and diffractive neutron optics with reduced chromatic aberration

    DEFF Research Database (Denmark)

    Poulsen, Stefan Othmar; Poulsen, Henning Friis; Bentley, P.M.

    2014-01-01

    by the use of optics for focusing and imaging. Refractive and diffractive optical elements, e.g. compound refractive lenses and Fresnel zone plates, are attractive due to their low cost, and simple alignment. These optical elements, however, suffer from chromatic aberration, which limit their effectiveness...

  8. Chromatic Enumeration for Singular Maps on the Klein Bottle

    Institute of Scientific and Technical Information of China (English)

    李赵祥; 刘彦佩

    2002-01-01

    A map is singular if each edge is on the same face on a surface (i.e.,it has only one face on a surface).In this paper we present the chromatic enumeration for rooted singular maps on the Klein bottle.

  9. THE LIST CHROMATIC NUMBERS OF SOME PLANAR GRAPHS

    Institute of Scientific and Technical Information of China (English)

    LǖEnyue; ZhangKemin

    1999-01-01

    In this paper, the choosability of outerplanar graphs, 1-tree and strong 1-outerplanargraphs have been described completely. A precise upper bound of the list chromatic number of 1-outerplanar graphs is given, and that every 1-outerplanar graph with girth at least 4 is 3-choosable is proved.

  10. Detection of Perturbation in Chromatic and Luminance-Defined Lines and Square-Waves

    Directory of Open Access Journals (Sweden)

    R.J Sharman

    2014-08-01

    Full Text Available The composition of a stimulus may affect how cues are combined. A thin luminance ring surrounding a uniform chromatic test facilitates contrast detection as much as a uniform luminance pedestal (Cole, Stromeyer & Kronauer, 1990, JOSA A, 7(1, 128-140. This could suggest that there is a specific facilitatory relationship between luminance lines and chromatic edges that is not present in other combinations. Therefore, combining luminance lines and chromatic edges could also improve performance in edge detection tasks. Here we use a novel task, perturbation detection, target gratings were sinusoidally perturbed in space and subjects were asked to detect which of two stimuli was not straight. Perturbation thresholds, were measured for chromatic and luminance defined line and square-wave gratings alone and in combination. The introduction of a line mask produced increased thresholds in all conditions. However, the introduction of a chromatic square-wave mask improved perception of perturbation in luminance lines, whereas the introduction of a luminance defined square-wave mask has little effect on the perturbation thresholds for chromatic lines. This could suggest that when a luminance line is presented with a chromatic edge, such as the chromatic boundaries in a square-wave grating, the chromatic information becomes ‘tied’ to the luminance information. The perceived location of the chromatic edge may be determined by the location of the luminance line.

  11. Chromatic aberration control for tunable all-silicone membrane microlenses.

    Science.gov (United States)

    Waibel, Philipp; Mader, Daniel; Liebetraut, Peter; Zappe, Hans; Seifert, Andreas

    2011-09-12

    Tunable multi-chamber microfluidic membrane microlenses with achromaticity over a given focal length range are demonstrated. In analogy to a fixed-focus achromatic doublet lens, the multi-lens system is based on a stack of microfluidic cavities filled with optically optimized liquids with precisely defined refractive index and Abbe number, and these are independently pneumatically actuated. The membranes separating the cavities form the refractive optical surfaces, and the curvatures as a function of pressure are calculated using a mechanical model for deformation of flexible plates. The results are combined with optical ray tracing simulations of the multi-lens system to yield chromatic aberration behavior, which is verified experimentally. A focal length tuning range of 5-40 mm and reduction in chromatic aberration of over 30% is demonstrated, limited by the availability of optical fluids.

  12. Filtering chromatic aberration for wide acceptance angle electrostatic lenses.

    Science.gov (United States)

    Fazekas, Ádám; Tóth, László

    2014-07-01

    Chromatic aberration is a major issue for imaging mainly with large acceptance angle electrostatic lenses. Its correction is necessary to take advantage of the outstanding spatial and angular resolution that these lenses provide. We propose a method to eliminate the effect of chromatic aberration on the measured images by determining the impact resulting from higher and lower kinetic energies. Based on a spectral image sequence and a matrix, which describes the transmission function of the lens, a system of linear equations is solved to approximate the 2D spectral intensity distribution of the sample surface. We present the description of our method and preliminary test results, which show significant contrast and image quality improvement. The presented algorithm can also be applied as a software-based energy analyzer.

  13. Chromatic Dispersion Monitoring Method Based on Phase Shift Technique

    Institute of Scientific and Technical Information of China (English)

    L(U) Chengang; WU Xing; ZENG Lizhu; QIN Yifan; ZU Peng; HU Zhixiong; GE Chunfeng

    2007-01-01

    The modulation phase shift method was used to measure chromatic dispersion in a standard single mode fiber for telecommunication. The modulation phase difference of the transmitted light at the wavelength of 1 532. 16 nm modulated by a radio frequency signal was measured, relative to the transmitted light at the wavelength of 1 549.33 nm modulated by the same signal. By introducing a reference light at the wavelength of 1 310 nm, a 1 310/1 550 nm wavelength division multiplexing was used instead of the high cost dense wavelength division multiplexing. In the experiment, two testing lights were coupled with the reference light to the fiber spools of different lengths, respectively. By finite difference method, the chromatic dispersion between the two testing lights was measured, and the fixed errors generated during transmission were less than 0.5 ps/(nm·km).

  14. Towards Bio-Inspired Chromatic Behaviours in Surveillance Robots

    Directory of Open Access Journals (Sweden)

    Sampath Kumar Karutaa Gnaniar

    2016-09-01

    Full Text Available The field of Robotics is ever growing at the same time as posing enormous challenges. Numerous works has been done in biologically inspired robotics emulating models, systems and elements of nature for the purpose of solving traditional robotics problems. Chromatic behaviours are abundant in nature across a variety of living species to achieve camouflage, signaling, and temperature regulation. The ability of these creatures to successfully blend in with their environment and communicate by changing their colour is the fundamental inspiration for our research work. In this paper, we present dwarf chameleon inspired chromatic behaviour in the context of an autonomous surveillance robot, “PACHONDHI”. In our experiments, we successfully validated the ability of the robot to autonomously change its colour in relation to the terrain that it is traversing for maximizing detectability to friendly security agents and minimizing exposure to hostile agents, as well as to communicate with fellow cooperating robots.

  15. The total chromatic number of regular graphs of high degree

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The total chromatic number χT (G) of a graph G is the minimum number of colors needed to color the edges and the vertices of G so that incident or adjacent elements have distinct colors. We show that if G is a regular graph and d(G) 32 |V (G)| + 263 , where d(G) denotes the degree of a vertex in G, then χT (G) d(G) + 2.

  16. Bounds for the harmonious chromatic number of a graph

    OpenAIRE

    Krasikov, I.; Y. Roditty

    1994-01-01

    The upper bound for the harmonious chromatic number of a graph given by Zhikang Lu and by C. McDiarmid and Luo Xinhua, independently (Journal of Graph Theory, 1991, pp. 345-347 and 629-636) and the lower bound given by D. G. Beane, N. L. Biggs, and B. J. Wilson (Journal of Graph Theory, 1989, pp. 291-298) are improved.

  17. Manipulation of spatiotemporal photon distribution via chromatic aberration.

    Science.gov (United States)

    Li, Yuelin; Chemerisov, Sergey

    2008-09-01

    We demonstrate a spatiotemporal laser-pulse-shaping scheme that exploits the chromatic aberration in a dispersive lens. This normally harmful effect transforms the phase modulation into a beam-size modulation at the focal plane. In combination with the intricate diffraction effect via beam apodization, this method provides a spatiotemporal control of photon distribution with an accuracy of diffraction limit on a time scale of femtoseconds.

  18. "Tilt" in color space: Hue changes induced by chromatic surrounds.

    Science.gov (United States)

    Klauke, Susanne; Wachtler, Thomas

    2015-01-01

    The perceived color of a chromatic stimulus is influenced by the chromaticity of its surround. To investigate these influences along the dimension of hue, we measured hue changes induced in stimuli of different hues by isoluminant chromatic surrounds. Generally, induced hue changes were directed in color space away from the hue of the inducing surround and depended on the magnitude on the hue difference between stimulus and surround. With increasing difference in hue between stimulus and surround, induced hue changes increased up to a maximum and then decreased for larger differences. This qualitative pattern was similar for different inducers, but quantitatively, induction was weaker along some directions in cone-opponent color space than along other directions. The strongest induction effects were found along an oblique, blue-yellow axis that corresponds to the daylight axis. The overall pattern of the induction effect shows similarities to the well-known tilt effect, where shifts in perceived angle of oriented stimuli are induced by oriented surrounds. This suggests analogous neural representations and similar mechanisms of contextual processing for different visual features such as orientation and color.

  19. Correcting chromatic offset in multicolor super-resolution localization microscopy.

    Science.gov (United States)

    Erdelyi, Miklos; Rees, Eric; Metcalf, Daniel; Schierle, Gabriele S Kaminski; Dudas, Laszlo; Sinko, Jozsef; Knight, Alex E; Kaminski, Clemens F

    2013-05-06

    Localization based super-resolution microscopy techniques require precise drift correction methods because the achieved spatial resolution is close to both the mechanical and optical performance limits of modern light microscopes. Multi-color imaging methods require corrections in addition to those dealing with drift due to the static, but spatially-dependent, chromatic offset between images. We present computer simulations to quantify this effect, which is primarily caused by the high-NA objectives used in super-resolution microscopy. Although the chromatic offset in well corrected systems is only a fraction of an optical wavelength in magnitude (super-resolution methods is impossible without appropriate image correction. The simulated data are in excellent agreement with experiments using fluorescent beads excited and localized at multiple wavelengths. Finally we present a rigorous and practical calibration protocol to correct for chromatic optical offset, and demonstrate its efficacy for the imaging of transferrin receptor protein colocalization in HeLa cells using two-color direct stochastic optical reconstruction microscopy (dSTORM).

  20. Chromate Reduction in Serratia marcescens Isolated from Tannery Effluent and Potential Application for Bioremediation of Chromate Pollution

    Directory of Open Access Journals (Sweden)

    M.A. Mondaca

    2002-01-01

    Full Text Available Pollution of aquatic systems by heavy metals has resulted in increasing environmental concern because they cannot be biodegraded. One metal that gives reason for concern due to its toxicity is chromium. Cr(VI and Cr(III are the principal forms of chromium found in natural waters. A chromate-resistant strain of the bacterium S. marcescens was isolated from tannery effluent. The strain was able to reduce Cr(VI to Cr(III, and about 80% of chromate was removed from the medium. The reduction seems to occur on the cell surface. Transmission electron microscopic examination of cells revealed that particles were deposited on the outside of bacterial cells. A stable biofilm was formed in less than 10 h, reaching around 1010 cfu attached per milligram of activated carbon. These findings demonstrate that immobilized S. marcescens might be used in industrial waste treatment processes.

  1. A FrFT based method for measuring chromatic dispersion and SPM in optical fibers

    Science.gov (United States)

    Yang, Aiying; Liu, Xiang; Chen, Xiaoyu

    2017-03-01

    A fractional Fourier transformation based method is proposed to blindly estimate the chromatic dispersion and self phase modulation in optical fibers. The experimental results demonstrate that up to 20,000 ps/nm accumulative chromatic dispersion of a fiber link is measured with the error less than 0.8%. If the chromatic dispersion is compensated by multiplying an opposite chromatic dispersion function in frequency domain, the 1st order chirp parameter caused by SPM in an optical fiber communication system can be measured by fractional Fourier transformation based method, i.e. the accumulative SPM of a fiber link can be quantitatively measured. The results of equalizing chromatic dispersion and self phase modulation in an optical fiber communication system demonstrated that the FrFT based method is promising to blindly monitor and equalize the chromatic dispersion and SPM of the fiber link in an optical network with dynamical routing function.

  2. A method of dynamic chromatic aberration correction in low-voltage scanning electron microscopes.

    Science.gov (United States)

    Khursheed, Anjam

    2005-07-01

    A time-of-flight concept that dynamically corrects for chromatic aberration effects in scanning electron microscopes (SEMs) is presented. The method is predicted to reduce the microscope's chromatic aberration by an order of magnitude. The scheme should significantly improve the spatial resolution of low-voltage scanning electron microscopes (LVSEMs). The dynamic means of correcting for chromatic aberration also allows for the possibility of obtaining high image resolution from electron guns that have relatively large energy spreads.

  3. Chromatic Sums of Biloopless Nonseparable Near-Triangulations on the Projective Plane

    Institute of Scientific and Technical Information of China (English)

    Zhao-xiang Li; Yan-pei Liu; Bing-feng Si

    2013-01-01

    In this paper,the chromatic sum functions of rooted biloopless nonseparable near-triangulations on the sphere and the projective plane are studied.The chromatic sum function equations of such maps are obtained.From the chromatic sum equations of such maps,the enumerating function equations of such maps are derived.An asymptotic evaluation and some explicit expression of enumerating functions are also derived.

  4. Removal of chromate in a permeable reactive barrier using zero-valent iron

    DEFF Research Database (Denmark)

    Kjeldsen, Peter; Locht, T

    2002-01-01

    Chromate is a commonly found groundwater contaminant. Permeable reactive barriers containing zero-valent iron as iron filings are able to remove the chromate by a combined reduction/precipitation reaction. However, due to the passivation of the reduction capability of the iron surfaces by the pre......Chromate is a commonly found groundwater contaminant. Permeable reactive barriers containing zero-valent iron as iron filings are able to remove the chromate by a combined reduction/precipitation reaction. However, due to the passivation of the reduction capability of the iron surfaces...

  5. Definition and measurement of the beam propagation factor M2 for chromatic laser beams

    Institute of Scientific and Technical Information of China (English)

    Tao Fang; Xin Ye; Jinfu Niu; Jianqiu Xu

    2006-01-01

    The concept of the beam propagation factor M2 is extended for chromatic laser beams. The definition of the beam propagation factor can be generalized with the weighted effective wavelength. Using the new definition of factor M2, the propagation of chromatic beams can be analyzed by the beam propagation factor M2 as same as that of monochromatic beams. A simple method to measure the chromatic beam factor M2 is demonstrated. The chromatic factor M2 is found invariable while the laser beam propagates through the dispersion-free ABCD system.

  6. Performance Comparison of Steam-Based and Chromate Conversion Coatings on Aluminum Alloy 6060

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Jellesen, Morten Stendahl; Ambat, Rajan

    2015-01-01

    In this study, oxide layers generated on aluminum alloy 6060(UNS A96060) using a steam-based process were compared with conventional chromate and chromate-phosphate conversion coatings. Chemical composition and microstructure of the conversion coatings were investigated and their corrosion...... performance was evaluated using potentio dynamic polarization, acetic acid salt spray, and filiform corrosion testing of powder coated specimens. The steam-based process resulted in homogenous growth of oxide layer and superior coverageover intermetallic particles when compared to chromate-based conversion...... coatings. The coating formed by steam showed improved corrosion resistance, while adhesion to powder coatingand filiform corrosion was comparable with chromate conversion coatings....

  7. Chromatic Sums of Nonseparable Near-Triangulations on the Projective Plane

    Institute of Scientific and Technical Information of China (English)

    Zhao Xiang LI; Wei HE

    2012-01-01

    In this paper,we study the chromatic sum functions of rooted nonseparable neartriangulations on the sphere and the projective plane.The chromatic sum function equations of such maps are obtained.From the chromatic sum equations of such maps,the enumerating function equations of such maps are derived.Applying chromatic sum theory,the enumerating problem of different sorts maps can be studied,and a new method of enumeration can be obtained.Moreover,an asymptotic evaluation and some explicit expression of enumerating functions are also derived.

  8. Some Aspects of Visual Processing Under Chromatic Adaptation.

    Science.gov (United States)

    Wilson, Julie Ann Frances

    Available from UMI in association with The British Library. This thesis describes the results of experimental investigations into three types of visual processing, namely, displacement thresholds for motion detection, speed and motion detection, and rod-cone interaction effects. Each of these topics is described separately. The overall conclusions and summary of this work with an emphasis on chromatic processes are presented in the last chapter. The introductory chapter of the thesis deals mostly with the anatomical and theoretical aspects of vision and the development of a system for the standardization of colour. Equations for the CIE colour and colour difference specifications are described. Equipment, optical apparatus and general calibration procedures for all the investigations are covered in Chapter Two. Displacement thresholds for motion detection under conditions of chromatic adaptation are the subject of Chapter Three. The smallest, continuous target displacement sufficient to cause a sensation of movement was measured under conditions of chromatic adaptation. The experiments were carried out for test target and background field wavelengths which selectively isolated the activity of the colour mechanisms of the human eye. In Chapter Four, two mechanisms capable of speed discrimination and motion detection are proposed. Experimental data are reported which suggest that the visual system employs both schemes. A small circular target of high retinal illuminance level can have a comet-like appearance when presented moving continuously with a speed as low as 0.2 deg/s. Data on the parametric properties of the 'comet effect' are presented in Chapter Five. Measurement of the target spectral irradiance levels sufficient to yield the 'comet effect' suggests that the lengthening of the circular target reflects a rod-cone interaction and therefore it may be due to unsuppressed, saturated rod responses at high retinal illuminance levels. Computational methods are

  9. Automated selection of LEDs by luminance and chromaticity coordinate

    CERN Document Server

    Fischer, Ulrich H P; Reinboth, Christian

    2010-01-01

    The increased use of LEDs for lighting purposes has led to the development of numerous applications requiring a pre-selection of LEDs by their luminance and / or their chromaticity coordinate. This paper demonstrates how a manual pre-selection process can be realized using a relatively simple configuration. Since a manual selection service can only be commercially viable as long as only small quantities of LEDs need to be sorted, an automated solution suggests itself. This paper introduces such a solution, which has been developed by Harzoptics in close cooperation with Rundfunk Gernrode. The paper also discusses current challenges in measurement technology as well as market trends.

  10. Removing lateral chromatic aberration in bright field optical microscopy.

    Science.gov (United States)

    Guzmán-Altamirano, Miguel; Gutiérrez-Medina, Braulio

    2015-06-01

    We present an efficient alternative to remove lateral chromatic aberration (LCA) in bright field light microscopy images. Our procedure is based on error calibration using time-sequential acquisition at different wavelengths, and error correction through digital image warping. Measurement of the displacements of fiducial marks in the red and green images relative to blue provide calibration factors that are subsequently used in test images to realign color channels digitally. We demonstrate quantitative improvement in the position and boundaries of objects in target slides and in the color content and morphology of specimens in stained biological samples. Our results show a reduction of LCA content below the 0.1% level.

  11. Miniaturized modules for light sheet microscopy with low chromatic aberration.

    Science.gov (United States)

    Bruns, T; Bauer, M; Bruns, S; Meyer, H; Kubin, D; Schneckenburger, H

    2016-12-01

    Two miniaturized fibre-coupled modules for light sheet-based microscopy are described and compared with respect to image quality, chromatic aberration and beam alignment. Whereas in one module the light sheet is created by an achromatic cylindrical lens, reflection by a spherical mirror and concomitant astigmatic distortion are used to create the light sheet in the second module. Test experiments with fluorescent dyes in solution and multicellular tumour spheroids are reported, and some details on construction are given for both systems. Both modules are optimized for imaging individual cell layers of 3D biological samples and can be adapted to fit commercial microscopes.

  12. Chromatic Dispersion Compensation Using Photonic Crystal Fibers with Hexagonal Distribution

    Directory of Open Access Journals (Sweden)

    Erick E. Reyes-Vera

    2013-11-01

    Full Text Available In this paper we show various configurations of photonic crystal fiber with hexagonal holes distribution for compensation of chromatic dispersion in optical communications links. The vectorial finite element method with scattering boundary condition was used for the analysis of the fibers. From these results it was estimated variation of the dispersion and the dispersion slope with respect to change in the diameter of the holes in the microstructure. With the above was possible to obtain values of dispersion in the C and L bands of telecommunications close to -850 ps / nm * km, with confinement losses 10-3 dB / km

  13. Adaptive dispersion formula for index interpolation and chromatic aberration correction.

    Science.gov (United States)

    Li, Chia-Ling; Sasián, José

    2014-01-13

    This paper defines and discusses a glass dispersion formula that is adaptive. The formula exhibits superior convergence with a minimum number of coefficients. Using this formula we rationalize the correction of chromatic aberration per spectrum order. We compare the formula with the Sellmeier and Buchdahl formulas for glasses in the Schott catalogue. The six coefficient adaptive formula is found to be the most accurate with an average maximum index of refraction error of 2.91 × 10(-6) within the visible band.

  14. Conditioned Poisson distributions and the concentration of chromatic numbers

    CERN Document Server

    Hartigan, John; Tatikonda, Sekhar

    2011-01-01

    The paper provides a simpler method for proving a delicate inequality that was used by Achlioptis and Naor to establish asymptotic concentration for chromatic numbers of Erdos-Renyi random graphs. The simplifications come from two new ideas. The first involves a sharpened form of a piece of statistical folklore regarding goodness-of-fit tests for two-way tables of Poisson counts under linear conditioning constraints. The second idea takes the form of a new inequality that controls the extreme tails of the distribution of a quadratic form in independent Poissons random variables.

  15. Effects of Chromate and Non-Chromate Coating Systems on Environmentally Assisted Fatigue of an Aluminum Alloy

    Science.gov (United States)

    Schubbe, Joel J.; Westmoreland, Sophoria N.

    2014-10-01

    Fatigue crack growth testing of 2024-T3 Aluminum plate was performed using compact tension (CT) specimens with chromate and non-chromate primer paint systems to evaluate the effects of the coatings on fatigue crack growth rates. The tests were conducted in lab air and sea water environments for each of the coating systems. Standard E399 CT specimens were tested to determine the influence level of environmentally assisted cracking (corrosion fatigue) on crack growth rates and cyclic count to prescribed pre-crack and final crack lengths. Increasing stress range (Δ K) tests were conducted at 10 Hz in the range of 6.5 to 26.5 MPa. It was determined that the coated specimens exhibited a 12% shorter total life, on average, than the bare specimens for the lab air cases. In the case of salt water exposure, the coated specimens exhibited approximately 10% life increase over the bare specimens. The number of cycles to the 2.54 mm pre-crack length for the coated specimens was all less than the cycle count for the bare tests. In each case (coated or bare), there was an increased growth rate at the lower stress ranges in the salt water environment, with the chromate system case displaying the smallest change (increase). It can be concluded that the coated specimens initiate cracks and propagate faster than the bare specimens for short cracks at low stress range, but the environmental influence on the specimens is quickly overshadowed as the cracks elongate and the rate of growth increases. The coated specimens exhibited a higher total life cycle count to final crack length for this testing.

  16. Fluctuations in the prevalence of chromate allergy in Denmark and exposure to chrome-tanned leather

    DEFF Research Database (Denmark)

    Carøe, Caroline; Andersen, Klaus E; Thyssen, Jacob P;

    2010-01-01

    A recent Danish study showed a significant increase in the prevalence of chromate contact allergy after the mid-1990s, probably as a result of exposure to leather products.......A recent Danish study showed a significant increase in the prevalence of chromate contact allergy after the mid-1990s, probably as a result of exposure to leather products....

  17. Spatio-chromatic adaptation via higher-order canonical correlation analysis of natural images.

    Directory of Open Access Journals (Sweden)

    Michael U Gutmann

    Full Text Available Independent component and canonical correlation analysis are two general-purpose statistical methods with wide applicability. In neuroscience, independent component analysis of chromatic natural images explains the spatio-chromatic structure of primary cortical receptive fields in terms of properties of the visual environment. Canonical correlation analysis explains similarly chromatic adaptation to different illuminations. But, as we show in this paper, neither of the two methods generalizes well to explain both spatio-chromatic processing and adaptation at the same time. We propose a statistical method which combines the desirable properties of independent component and canonical correlation analysis: It finds independent components in each data set which, across the two data sets, are related to each other via linear or higher-order correlations. The new method is as widely applicable as canonical correlation analysis, and also to more than two data sets. We call it higher-order canonical correlation analysis. When applied to chromatic natural images, we found that it provides a single (unified statistical framework which accounts for both spatio-chromatic processing and adaptation. Filters with spatio-chromatic tuning properties as in the primary visual cortex emerged and corresponding-colors psychophysics was reproduced reasonably well. We used the new method to make a theory-driven testable prediction on how the neural response to colored patterns should change when the illumination changes. We predict shifts in the responses which are comparable to the shifts reported for chromatic contrast habituation.

  18. Chromatic dispersion of liquid crystal infiltrated capillary tubes and photonic crystal fibers

    DEFF Research Database (Denmark)

    Rasmussen, Per Dalgaard; Lægsgaard, Jesper; Bang, Ole

    2006-01-01

    We consider chromatic dispersion of capillary tubes and photonic crystal fibers infiltrated with liquid crystals. A perturbative scheme for inclusion of material dispersion of both liquid crystal and the surrounding waveguide material is derived. The method is used to calculate the chromatic disp...

  19. Chromatism compensation in wide-band nulling interferometry for exoplanet detection

    NARCIS (Netherlands)

    Spronck, J.; Pereira, S.F.; Braat, J.J.M.

    2006-01-01

    We introduce the concept of chromatism compensation in nulling interferometry that enables a high rejection ratio in a wide spectral band. Therefore the achromaticity condition considered in most nulling interferometers can be relaxed. We show that this chromatism compensation cannot be applied to a

  20. Chromatic settings and the structural color constancy index.

    Science.gov (United States)

    Roca-Vila, Jordi; Parraga, C Alejandro; Vanrell, Maria

    2013-03-11

    Color constancy is usually measured by achromatic setting, asymmetric matching, or color naming paradigms, whose results are interpreted in terms of indexes and models that arguably do not capture the full complexity of the phenomenon. Here we propose a new paradigm, chromatic setting, which allows a more comprehensive characterization of color constancy through the measurement of multiple points in color space under immersive adaptation. We demonstrated its feasibility by assessing the consistency of subjects' responses over time. The paradigm was applied to two-dimensional (2-D) Mondrian stimuli under three different illuminants, and the results were used to fit a set of linear color constancy models. The use of multiple colors improved the precision of more complex linear models compared to the popular diagonal model computed from gray. Our results show that a diagonal plus translation matrix that models mechanisms other than cone gain might be best suited to explain the phenomenon. Additionally, we calculated a number of color constancy indices for several points in color space, and our results suggest that interrelations among colors are not as uniform as previously believed. To account for this variability, we developed a new structural color constancy index that takes into account the magnitude and orientation of the chromatic shift in addition to the interrelations among colors and memory effects.

  1. Chromatic, Phenolic and Antioxidant Properties of Sorghum bicolor Genotypes

    Directory of Open Access Journals (Sweden)

    José Juan LÓPEZ-CONTRERAS

    2015-12-01

    Full Text Available Chromatic, phenolic and antioxidant properties were evaluated in ten sorghum genotypes grown in Nuevo León, México. Lightness, Chroma and hue angle ranged from 64 to 83, 12 to 20 and 61 to 82 respectively, indicating that colour of the samples were located in the gray orange-yellow zone of the hue circle. Based on these results, samples were classified in three colour groups being Very Soft Orange, Slightly Desaturated Orange and Grayish Orange. Results in phenolics ranged from 796 to 15,949, 175 to 12,674 and 193 to 25,780 µgCE g-1 in total phenolics by Folin-Ciocalteu, total flavonoids by Aluminum Chloride and condensed tannins by Vanillin-HCl respectively. On the other hand, antioxidant capacity ranged from 1.20 to 93.83, 30.25 to 156.08 and 2.62 to 98.50 μmolTE g-1 in 2,2-diphenyl-1-picrylhydrazyl, 3-ethyl-benzothiazoline-6-sulfonic acid and Ferric Reducing Antioxidant Power respectively. Significant differences (p≤0.05 were observed in statistical analysis for both individual and group colour samples in chromatic, phenolics and antioxidant activity evaluations, showing ‘Rox Orange’ genotype and Grayish Orange colour group the highest levels.

  2. Chromatic instabilities in cesium-doped tungsten bronze nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Adachi, Kenji, E-mail: kenji-adachi@ni.smm.co.jp; Ota, Yosuke; Tanaka, Hiroyuki; Okada, Mika; Oshimura, Nobumitsu; Tofuku, Atsushi [Ichikawa Research Laboratories, Sumitomo Metal Mining Co., Ltd., Ichikawa 272-8588 (Japan)

    2013-11-21

    Nanoparticles of alkali-doped tungsten bronzes are an excellent near-infrared shielding material, but exhibit slight chromatic instabilities typically upon applications of strong ultra-violet light or heating in humid environment, which acts detrimentally to long-life commercial applications. Origin of the chromatic instabilities in cesium-doped tungsten bronze has been investigated, and it has been found that the coloration and bleaching processes comprised electronic exchanges which accelerate or depress the polaron excitation and the localized surface plasmon resonance. Coloration on UV illumination is evidenced by electron diffraction as due to the formation of H{sub x}WO{sub 3}, which is considered to take place in the surface Cs-deficient WO{sub 3} region via the double charge injection mechanism. On the other hand, bleaching on heating in air and in humid environment is shown to accompany the extraction of Cs and electrons from Cs{sub 0.33}WO{sub 3} by X-ray photoelectron spectroscopy and X-ray diffraction analysis and is concluded to be an oxidation of Cs{sub 0.33}WO{sub 3} on the particle surface.

  3. The History of the Total Chromatic Number Conjecture

    CERN Document Server

    Shahmohamad, Hossein

    2011-01-01

    The total chromatic number conjecture which has appeared in a few hundred articles and in numerous books thus far is now one of the classic mathematical unsolved problems. It appears that many authors coincidentally have attributed it to Professor M. Behzad and/or to Professor V. G. Vizing. Eventually after four decades, Professor A. Soifer investigated the origin of this conjecture; published his findings in The Mathematical Coloring Book - 2009; and stated that, "In my opinion this unquestionably merits the joint credit to Vizing and Behzad." After checking all the arguments presented and the blames cited, I decided to investigate the controversy stated in this book on my own. My findings which are presented in this report specifically signify the following two points. - M. Behzad is the sole author of the Total Chromatic Number Conjecture. - The wrong referrals provided by numerous authors over the last forty four years, to indicate Vizing's authorship, must be brought to the attention of the authors and r...

  4. Chromatic instabilities in cesium-doped tungsten bronze nanoparticles

    Science.gov (United States)

    Adachi, Kenji; Ota, Yosuke; Tanaka, Hiroyuki; Okada, Mika; Oshimura, Nobumitsu; Tofuku, Atsushi

    2013-11-01

    Nanoparticles of alkali-doped tungsten bronzes are an excellent near-infrared shielding material, but exhibit slight chromatic instabilities typically upon applications of strong ultra-violet light or heating in humid environment, which acts detrimentally to long-life commercial applications. Origin of the chromatic instabilities in cesium-doped tungsten bronze has been investigated, and it has been found that the coloration and bleaching processes comprised electronic exchanges which accelerate or depress the polaron excitation and the localized surface plasmon resonance. Coloration on UV illumination is evidenced by electron diffraction as due to the formation of HxWO3, which is considered to take place in the surface Cs-deficient WO3 region via the double charge injection mechanism. On the other hand, bleaching on heating in air and in humid environment is shown to accompany the extraction of Cs and electrons from Cs0.33WO3 by X-ray photoelectron spectroscopy and X-ray diffraction analysis and is concluded to be an oxidation of Cs0.33WO3 on the particle surface.

  5. A local search algorithm based on chromatic classes for university course timetabling problem

    Directory of Open Access Journals (Sweden)

    Velin Kralev

    2016-12-01

    Full Text Available This paper presents a study for a local search algorithm based on chromatic classes for the university course timetabling problem. Several models and approaches to resolving the problem are discussed. The main idea of the approach is through a heuristic algorithm to specify the chromatic classes of a graph in which the events of the timetable correspond to the graph vertices and the set of the edges represents the possible conflicts between events. Then the chromatic classes should be sorted according to specific sort criteria (a total weight or a total count of events in each class, and finally the local search algorithm starts. The aim of the experiments is to determine the best criterion to sort chromatic classes. The results showed that the algorithm generates better solutions when the chromatic classes are sorted in a total weight criterion.

  6. Construction of special eye models for investigation of chromatic and higher-order aberrations of eyes.

    Science.gov (United States)

    Zhai, Yi; Wang, Yan; Wang, Zhaoqi; Liu, Yongji; Zhang, Lin; He, Yuanqing; Chang, Shengjiang

    2014-01-01

    An achromatic element eliminating only longitudinal chromatic aberration (LCA) while maintaining transverse chromatic aberration (TCA) is established for the eye model, which involves the angle formed by the visual and optical axis. To investigate the impacts of higher-order aberrations on vision, the actual data of higher-order aberrations of human eyes with three typical levels are introduced into the eye model along visual axis. Moreover, three kinds of individual eye models are established to investigate the impacts of higher-order aberrations, chromatic aberration (LCA+TCA), LCA and TCA on vision under the photopic condition, respectively. Results show that for most human eyes, the impact of chromatic aberration on vision is much stronger than that of higher-order aberrations, and the impact of LCA in chromatic aberration dominates. The impact of TCA is approximately equal to that of normal level higher-order aberrations and it can be ignored when LCA exists.

  7. Chromatically Corrected Imaging Systems for Charged-Particle Radiography

    CERN Document Server

    Blind, Barbara

    2005-01-01

    In proton radiography, imaging with systems consisting of quadrupole magnets is an established technique for viewing the material distribution and composition of objects, either statically or during fast events such as explosions. With the most favorable magnet configuration, the -I lens, chromatic aberrations generally dominate the image blur. Image resolution can be improved, and largely decoupled from the input-beam parameters, by using a second-order achromatic bend with some additional higher-order aberration correction. The aberration-correction approach is discussed. For a given resolution, such a bend allows use of much lower-energy imaging particles than a -I lens. Each bend design represents a set of equivalent systems; an 800-MeV proton design and its equivalent 40-MeV electron system are presented. The electron system is useful for imaging small objects. Magnet errors in the achromatic bends must be tightly controlled to preserve image quality, but not beyond feasibility of present technology. Sys...

  8. On the game chromatic number of sparse random graphs

    CERN Document Server

    Frieze, Alan; Lavrov, Mikhail

    2012-01-01

    Given a graph G and an integer k, two players take turns coloring the vertices of G one by one using k colors so that neighboring vertices get different colors. The first player wins iff at the end of the game all the vertices of $G$ are colored. The game chromatic number \\chi_g(G) is the minimum k for which the first player has a winning strategy. The paper \\cite{BFS} began the analysis of the asymptotic behavior of this parameter for a random graph G_{n,p}. This paper provides some further analysis for graphs with constant average degree i.e. np=O(1) and for random regular graphs.

  9. Chromatic perception of non-invasive lighting of cave paintings

    Science.gov (United States)

    Zoido, Jesús; Vazquez, Daniel; Álvarez, Antonio; Bernabeu, Eusebio; García, Ángel; Herraez, Juán A.; del Egido, Marian

    2009-08-01

    This work is intended to deal with the problems which arise when illuminanting Paleolithic cave paintings. We have carried out the spectral and colorimetric characterization of some paintings located in the Murcielagos (bats) cave (Zuheros, Córdoba, Spain). From this characterization, the chromatic changes produced under different lighting conditions are analysed. The damage function is also computed for the different illuminants used. From the results obtained, it is proposed an illuminant whose spectral distribution diminishes the damage by minimizing the absorption of radiation and optimises the color perception of the paintings in this cave. The procedure followed in this study can be applied to optimise the lighting systems used when illuminating any other art work

  10. Chromatic aftereffects associated with a night vision goggle simulation.

    Science.gov (United States)

    Moffitt, K; Rogers, S P; Cicinelli, J

    1988-02-01

    A visual perception experiment was conducted to determine the chromatic aftereffects of viewing a yellow-green field that simulated the display of current night vision goggles. Six females and two males served as subjects in a color-naming procedure. Subjects sequentially viewed an adaptation field, which was either yellow-green or white, and small colored targets presented on a CRT display. The time required to name the color of the targets was found to be dependent on the color of the adaptation field, the color of the target, and the interaction of these two variables. It was recommended that the effects of attenuation of the luminance of the night vision goggles be studied, and that color cockpit displays be redundantly coded whenever possible.

  11. The use of chromatic information for motion segmentation: differences between psychophysical and eye-movement measures.

    Science.gov (United States)

    Dobkins, Karen R; Sampath, Vanitha

    2008-01-01

    Previous psychophysical studies have shown that chromatic (red/green) information can be used as a segmentation cue for motion integration. We investigated the mechanisms mediating this phenomenon by comparing chromatic effects (and, for comparison, luminance effects) on motion integration between two measures: (i) directional eye movements with the notion that these responses are mediated mainly by low-level motion mechanisms, and (ii) psychophysical reports, with the notion that subjects' reports should employ higher-level (attention-based) mechanisms if available. To quantify chromatic (and luminance) effects on motion integration, coherent motion thresholds were obtained for two conditions, one in which the signal and noise dots were the same 'red' or 'green' chromaticity (or the same 'bright' or 'dark' luminance), referred to as homogeneous, and the other in which the signal and noise dots were of different chromaticities (or luminances), referred to as heterogeneous. 'Benefit ratios' (theta(HOM)/theta(HET)) were then computed, with values significantly greater than 1.0 indicating that chromatic (or luminance) information serves as a segmentation cue for motion integration. The results revealed a high and significant chromatic benefit ratio when the measure was based on psychophysical report, but not when it was based on an eye-movement measure. By contrast, luminance benefit ratios were roughly the same (and significant) for both measures. For comparison to adults, eye-movement data were also obtained from 3-month-old infants. Infants showed marginally significant benefit ratios in the luminance, but not in the chromatic, condition. In total, these results suggest that the use of chromatic information as a segmentation cue for motion integration relies on higher-level mechanisms, whereas luminance information works mainly through low-level motion mechanisms.

  12. Removal of Chromate Ions from Water by Anionicc CLAYS

    Science.gov (United States)

    Houri, B.; Legrouri, A.; Barroug, A.; Forano, C.; Besse, J.-P.

    1999-03-01

    The removal of chromate ions from aqueous solutions by [Mg-Al-Cl], [Zn-Al-Cl] and [Zn-Cr-Cl] anionic clays was investigated. The solids, prepared by coprecipitation at constant pH, were found to be pure upon characterisation by X-ray diffraction and Fourier-transform infrared spectroscopy. The interaction of the solid materials with CrO42- ions has been studied by UV-visible spectroscopy. The treatment of solutions containing 15 to 300 ppm of CrO42- was successful. The sorption capacities of the anionic clays for the CrO42- ions are close to 1 mmol/g. L'élimination des ions chromate de solutions aqueuses par les argiles anioniques [Mg-Al-Cl], [Zn-Al-Cl] et [Zn-Cr-Cl] a été étudiée. Les solides, préparés par coprécipitation à pH constant, ont été caractérisés par diffraction des rayons X et spectroscopie infrarouge à transformée de Fourier. L'interaction de ces matériaux avec les ions CrO42- a été suivie par spectroscopie UV-visible. Le traitement de solutions contenant de 15 à 300 ppm de CrO42- a donné de bons résultats. La capacité d'élimination de ces argiles anioniques pour les ions CrO42- est d'environ 1 mmol/g. .

  13. Repeated exposures to cobalt or chromate on the hands of patients with hand eczema and contact allergy to that metal

    DEFF Research Database (Denmark)

    Nielsen, N H; Kristiansen, J; Borg, L

    2000-01-01

    The present study aimed at evaluating the effects of daily repeated exposures to low cobalt or chromate concentrations on the hands of patients with hand eczema and cobalt or chromate allergy. For 2 weeks, the patients immersed a finger for 10 min daily into the appropriate metal salt solution...... in water. During the 1st week, this was a 10 or 50 mg/l cobalt concentration or a 10 mg/l chromate concentration, and, during the 2nd week, a 100 or 200 mg/l cobalt concentration or a 100 mg/l chromate concentration. This regimen elicited a flare of hand eczema only in the chromate-exposed chromate......-sensitive patients. During the exposure period, accumulation of cobalt or chromate in the nail was demonstrated. Standardization of chemical methods of quantification of skin exposure to allergens, combined with experimental exposure studies in patients with specific contact allergy, will increase the possibility...

  14. A Genetic Algorithm for Chromaticity Correction in Diffraction Limited Storage Rings

    CERN Document Server

    Ehrlichman, Michael

    2016-01-01

    An multi-objective genetic algorithm is developed for optimizing nonlinearities in diffraction limited storage rings. This algorithm determines sextupole and octupole strengths for chromaticity correction that deliver optimized dynamic aperture and beam lifetime. The algorithm makes use of dominance constraints to breed desirable properties into the early generations. The momentum aperture is optimized indirectly by constraining the chromatic tune footprint and optimizing the off-energy dynamic aperture. The result is an effective and computationally efficient technique for correcting chromaticity in a storage ring while maintaining optimal dynamic aperture and beam lifetime. This framework was developed for the Swiss Light Source (SLS) upgrade project.

  15. Measurement of chromatic aberration in STEM and SCEM by coherent convergent beam electron diffraction.

    Science.gov (United States)

    Zheng, C L; Etheridge, J

    2013-02-01

    A simple method is described for the accurate and precise measurement of chromatic aberration under electron-optical conditions pertinent to scanning transmission electron microscopy (STEM) and scanning confocal electron microscopy (SCEM). The method requires only the measurement of distances in a coherent CBED pattern and knowledge of the electron wavelength and the lattice spacing of a calibration specimen. The chromatic aberration of a spherical-aberration corrected 300 kV thermal field emission TEM is measured in STEM and SCEM operating modes and under different condenser lens settings. The effect of the measured chromatic aberrations on the 3 dimensional intensity distribution of the electron probe is also considered.

  16. Flat Supercontinuum Generated in a Single-Mode Optical Fibre with a New Chromatic Dispersion Profile

    Institute of Scientific and Technical Information of China (English)

    XU Yong-Zhao; REN Xiao-Min; ZHANG Xia; HUANG Yong-Qing; XU Wen-Cheng

    2005-01-01

    @@ A new chromatic dispersion profile of a single-mode opticalfibre is proposed for generating a supercontinuum with a flatly broadened spectrum. The chromatic dispersion D( λ, z) is a convex function of wavelengths and has no zero-dispersion wavelengths over the whole part of thefibre as D(λ, z) is negative. It is shown that the flat supercontinuum spectrum is obtained when the pump wavelength is set in the vicinity of the wavelength at which the peak chromatic dispersion is near zero and the strong residual pump component is eliminated.

  17. Explicit and probabilistic constructions of distance graphs with small clique numbers and large chromatic numbers

    Science.gov (United States)

    Kupavskii, A. B.

    2014-02-01

    We study distance graphs with exponentially large chromatic numbers and without k-cliques, that is, complete subgraphs of size k. Explicit constructions of such graphs use vectors in the integer lattice. For a large class of graphs we find a sharp threshold for containing a k-clique. This enables us to improve the lower bounds for the maximum of the chromatic numbers of such graphs. We give a new probabilistic approach to the construction of distance graphs without k-cliques, and this yields better lower bounds for the maximum of the chromatic numbers for large k.

  18. Characterization and genomic analysis of chromate resistant and reducing Bacillus cereus strain SJ1

    Directory of Open Access Journals (Sweden)

    He Minyan

    2010-08-01

    Full Text Available Abstract Background Chromium is a toxic heavy metal, which primarily exists in two inorganic forms, Cr(VI and Cr(III. Chromate [Cr(VI] is carcinogenic, mutational, and teratogenic due to its strong oxidizing nature. Biotransformation of Cr(VI to less-toxic Cr(III by chromate-resistant and reducing bacteria has offered an ecological and economical option for chromate detoxification and bioremediation. However, knowledge of the genetic determinants for chromate resistance and reduction has been limited so far. Our main aim was to investigate chromate resistance and reduction by Bacillus cereus SJ1, and to further study the underlying mechanisms at the molecular level using the obtained genome sequence. Results Bacillus cereus SJ1 isolated from chromium-contaminated wastewater of a metal electroplating factory displayed high Cr(VI resistance with a minimal inhibitory concentration (MIC of 30 mM when induced with Cr(VI. A complete bacterial reduction of 1 mM Cr(VI was achieved within 57 h. By genome sequence analysis, a putative chromate transport operon, chrIA1, and two additional chrA genes encoding putative chromate transporters that likely confer chromate resistance were identified. Furthermore, we also found an azoreductase gene azoR and four nitroreductase genes nitR possibly involved in chromate reduction. Using reverse transcription PCR (RT-PCR technology, it was shown that expression of adjacent genes chrA1 and chrI was induced in response to Cr(VI but expression of the other two chromate transporter genes chrA2 and chrA3 was constitutive. In contrast, chromate reduction was constitutive in both phenotypic and gene expression analyses. The presence of a resolvase gene upstream of chrIA1, an arsenic resistance operon and a gene encoding Tn7-like transposition proteins ABBCCCD downstream of chrIA1 in B. cereus SJ1 implied the possibility of recent horizontal gene transfer. Conclusion Our results indicate that expression of the chromate

  19. A single mechanism for both luminance and chromatic grating vernier tasks: evidence from temporal summation.

    Science.gov (United States)

    Sun, Hao; Lee, Barry B

    2004-01-01

    Vernier thresholds are determined by luminance rather than chromatic contrast when both are present in vernier targets. The role of luminance and chromatic mechanisms in vernier performance under equiluminant conditions remains uncertain. Temporal summation functions for vernier thresholds with luminance and red-green equiluminant gratings were compared to those for detection thresholds with similar stimuli. Vernier thresholds showed similar temporal summation for luminance and chromatic gratings, which is consistent with a single mechanism underlying vernier performance in the two conditions. However, detection thresholds showed a shorter temporal summation duration for luminance gratings than for chromatic gratings, which suggests that two different mechanisms underlie detection thresholds. Analysis of physiological data supports the hypothesis that the frequency-doubled response of ganglion cells in the magnocellular pathway can provide accurate spatiotemporal information for vernier performance at equiluminance.

  20. Achromatic-chromatic colorimetric sensors for on-off type detection of analytes.

    Science.gov (United States)

    Heo, Jun Hyuk; Cho, Hui Hun; Lee, Jin Woong; Lee, Jung Heon

    2014-12-21

    We report the development of achromatic colorimetric sensors; sensors changing their colors from achromatic black to other chromatic colors. An achromatic colorimetric sensor was prepared by mixing a general colorimetric indicator, whose color changes between chromatic colors, and a complementary colored dye with no reaction to the targeted analyte. As the color of an achromatic colorimetric sensor changes from black to a chromatic color, the color change could be much easily recognized than general colorimetric sensors with naked eyes. More importantly, the achromatic colorimetric sensors enable on-off type recognition of the presence of analytes, which have not been achieved from most colorimetric sensors. In addition, the color changes from some achromatic colorimetric sensors (achromatic Eriochrome Black T and achromatic Benedict's solution) could be recognized with naked eyes at much lower concentration ranges than normal chromatic colorimetric sensors. These results provide new opportunities in the use of colorimetric sensors for diverse applications, such as harsh industrial, environmental, and biological detection.

  1. Photographic simulation of off-axis blurring due to chromatic aberration in spectacle lenses.

    Science.gov (United States)

    Doroslovački, Pavle; Guyton, David L

    2015-02-01

    Spectacle lens materials of high refractive index (nd) tend to have high chromatic dispersion (low Abbé number [V]), which may contribute to visual blurring with oblique viewing. A patient who noted off-axis blurring with new high-refractive-index spectacle lenses prompted us to do a photographic simulation of the off-axis aberrations in 3 readily available spectacle lens materials, CR-39 (nd = 1.50), polyurethane (nd = 1.60), and polycarbonate (nd = 1.59). Both chromatic and monochromatic aberrations were found to cause off-axis image degradation. Chromatic aberration was more prominent in the higher-index materials (especially polycarbonate), whereas the lower-index CR-39 had more astigmatism of oblique incidence. It is important to consider off-axis aberrations when a patient complains of otherwise unexplained blurred vision with a new pair of spectacle lenses, especially given the increasing promotion of high-refractive-index materials with high chromatic dispersion.

  2. Measuring chromatic aberrations in imaging systems using plasmonic nano-particles

    CERN Document Server

    Gennaro, Sylvain D; Maier, Stefan A; Oulton, Rupert F

    2015-01-01

    Chromatic aberration in optical systems arises from the wavelength dependence of a glass's refractive index. Polychromatic rays incident upon an optical surface are refracted at slightly different angles and in traversing an optical system follow distinct paths creating images displaced according to color. Although arising from dispersion, it manifests as a spatial distortion correctable only with compound lenses with multiple glasses and accumulates in complicated imaging systems. While chromatic aberration is measured with interferometry, simple methods are attractive for their ease of use and low cost. In this letter we retrieve the longitudinal chromatic focal shift of high numerical aperture (NA) microscope objectives from the extinction spectra of metallic nanoparticles within the focal plane. The method is accurate for high NA objectives with apochromatic correction, and enables rapid assessment of the chromatic aberration of any complete microscopy systems, since it is straightforward to implement

  3. Reverse chromatic aberration and its numerical optimization in a metamaterial lens.

    Science.gov (United States)

    Capecchi, William J; Behdad, Nader; Volpe, Francesco A

    2012-04-09

    In planar metamaterial lenses, the focal point moves with the frequency. Here it is shown numerically that this movement can be controlled by properly engineering the dimensions of the metamaterial-based phase shifters that constitute the lens. In particular, such lenses can be designed to exhibit unusual chromatic aberration with the focal length increasing, rather than decreasing, with the frequency. It is proposed that such an artificial "reverse" chromatic aberration may optimize the transverse resolution of millimeter wave diagnostics of plasmas and be useful in compensating for the natural "ordinary" chromatic aberration of other components in an optical system. More generally, optimized chromatic aberration will allow for simultaneous focusing of several objects located at different distances and emitting or reflecting at different frequencies.

  4. Correction of chromatic aberrations at television registration of image through protective viewing systems

    Science.gov (United States)

    Kulyas, Oleg L.; Nikitin, Konstantin A.

    2016-03-01

    Ways of chromatic aberration in images are examined and analyzed which are generated at television supervision through protective glasses of a considerable thickness. The results of experimental check up of the given method of correction is introduced and described.

  5. MEASURING CHROMATICITY ALONG THE RAMP USING THE PLL TUNE METER IN RHIC.

    Energy Technology Data Exchange (ETDEWEB)

    TEPIKIAN,S.; AHRENS,L.; CAMERON,P.; SCHULTHEISS,C.

    2002-06-02

    Beam stability up the ramp requires the appropriate sign and magnitude of the chromaticity. We developed a way to measure the chromaticity using the PLL (Phase Locked Loop) tune-meter. Since, the accuracy of the PLL tune-meter with properly adjusted loop gain is better than {approx} 0.0001 in tune units, the radial loop needs only be changed by a small amount of 0.2mm at a 1Hz rate. Thus, we can achieve fast chromaticity measurements in 1 sec. Except during the very beginning of the ramp where there are snapback effects and the gamma changes very rapidly, we can have good chromaticcity measurements along the ramp. This leads to the possibility of correcting the chromaticity during the ramp using a feedback system.

  6. Reverse Chromatic Aberration and its Numerical Optimization in a Metamaterial Lens

    CERN Document Server

    Capecchi, W J; Volpe, F A; 10.1364/OE.20.008761

    2013-01-01

    In planar metamaterial lenses, the focal point moves with the frequency. Here it is shown numerically that this movement can be controlled by properly engineering the dimensions of the metamaterial-based phase shifters that constitute the lens. In particular, such lenses can be designed to exhibit unusual chromatic aberration with the focal length increasing, rather than decreasing, with the frequency. It is proposed that such an artificial "reverse" chromatic aberration may optimize the transverse resolution of millimeter wave diagnostics of plasmas and be useful in compensating for the natural "ordinary" chromatic aberration of other components in an optical system. More generally, optimized chromatic aberration will allow to simultaneously focus on several objects located at different distances and emitting or reflecting at different frequencies.

  7. Measurement of Stratospheric Chromatic Scintillation with the AMON-RA Balloonborne Spectrometer.

    Science.gov (United States)

    Renard, J B; Dalaudier, F; Hauchecorne, A; Robert, C; Lemaire, T; Pirre, M; Bertaux, J L

    2001-08-20

    The balloonborne instrument AMON (which is a French acronym for Absorption par les Minoritaires Ozone et NO(x)) has been modified to record chromatic scintillation during stellar occultation by the Earth's atmosphere. A 14-channel spectrophotometer with a sampling rate of 10 Hz was added, and the modified instrument, AMON-RA, performed successful measurements of the setting star Alnilam during the third European Stratospheric Experiment on Ozone (THESEO) project. Unambiguous records of the chromatic scintillation were obtained, to our knowledge for the first time from above the atmosphere, and some of its basic properties are reported. The properties of atmospheric structures that are responsible for this chromatic scintillation were found to be consistent with those of previous monochromatic measurements performed from space. A maximum chromatic delay of 2.5 s was observed for widely different wavelengths.

  8. Understanding the tune, coupling, and chromaticity dependence of the LHC on Landau octupole powering.

    CERN Document Server

    Maclean, E H; Persson, T; Tomas, R; Wenninger, J

    2013-01-01

    During the 2012 LHC run several observations were made of shifts to tune, coupling and chromaticity which were correlated with changes in the powering of Landau octupoles. Understanding the chromaticity dependence is of particular importance given its influence on instabilities. This note briefly summarizes the observations and describes our understanding to-date of the relationship between Q, Q′, |C−| and the Landau octupole powering.

  9. Reverse Chromatic Aberration and its Numerical Optimization in a Metamaterial Lens

    OpenAIRE

    Capecchi, W. J.; Behdad, N.; Volpe, F. A.

    2013-01-01

    In planar metamaterial lenses, the focal point moves with the frequency. Here it is shown numerically that this movement can be controlled by properly engineering the dimensions of the metamaterial-based phase shifters that constitute the lens. In particular, such lenses can be designed to exhibit unusual chromatic aberration with the focal length increasing, rather than decreasing, with the frequency. It is proposed that such an artificial "reverse" chromatic aberration may optimize the tran...

  10. Impact of dimming white LEDs: chromaticity shifts due to different dimming methods

    Science.gov (United States)

    Dyble, Marc; Narendran, Nadarajah; Bierman, Andrew; Klein, Terence

    2005-09-01

    The goal of this study was to characterize the chromaticity shift that mixed-color and phosphor-converted white LED systems undergo when dimmed. As light-emitting diodes continue to rapidly evolve as a viable light source for lighting applications, their color shift while being dimmed should meet the current requirements of traditional lighting sources. Currently, LED system manufacturers commonly recommend pulse-width-modulation or PWM dimming schemes for operation of LED systems. PWM has the ability to achieve lower intensity levels and more linear control of light intensity compared to continuous current dimming methods. However, little data has been published on the effect dimming has on chromaticity shift of white LED lighting systems. The primary objective of this study was to quantify chromaticity shifts in mixed-color and phosphor-converted white LED systems due to continuous current dimming and pulse-width-modulation dimming schemes. In this study, the light output of the LED system was reduced from 100% to 3% by means of continuous current reduction or PWM methods using a PC white LED system and a mixed-color RGB LED system. Experimental results from this study showed that the PC white LED system exhibited very little chromaticity shift (less than a 4-step MacAdam ellipse) when the light level was changed from 100% to 3% using both dimming schemes. Compared to PC white LEDs, the mixed-color RGB LED system tested in this study showed very large chromaticity shifts in a similar dimming range using both dimming schemes. If a mixed-color RGB system is required, then some active feedback system control must be incorporated to obtain non-perceivable chromaticity shift. In this regard the chromaticity shift caused by the PWM method is easier to correct than the chromaticity shift caused by the continuous current dimming method.

  11. CHROMATICITY COORDINATES EVALUATION OF TRIANGLE VERTICES GAMUT FOR DISPLAYS WITH MAXIMUM AREA OF COLOR REPRODUCTION

    Directory of Open Access Journals (Sweden)

    I. O. Zharinov

    2016-09-01

    Full Text Available We consider the problem of calculating chromaticity coordinates estimates of triangle vertices gamut for displays with maximum area of color reproduction. Initial data for the evaluation are tabulated data on the shape of the spectral locus interpolated by Bezier splines. Research results are chromaticity coordinates of the triangle vertices gamut maximum area specified on the color chart according to the standards of the International Commission on Illumination.

  12. Joint IQ Skew and Chromatic Dispersion Estimation for Coherent Optical Communication Receivers

    DEFF Research Database (Denmark)

    Medeiros Diniz, Júlio César; Porto da Silva, Edson; Piels, Molly

    2016-01-01

    A low-complexity scanning method for joint estimation of receiver IQ skew and chromatic dispersion is proposed. This method shows less than 1 ps skew error for a 1200-km 32-GBd DP-16QAM optical transmission experiment.......A low-complexity scanning method for joint estimation of receiver IQ skew and chromatic dispersion is proposed. This method shows less than 1 ps skew error for a 1200-km 32-GBd DP-16QAM optical transmission experiment....

  13. EVALUATION OF DISTRIBUTION HISTOGRAMS FOR INCREMENT OF CHROMATICITY COORDINATES IN DISPLAY TECHNOLOGIES

    Directory of Open Access Journals (Sweden)

    I. O. Zharinov

    2016-05-01

    Full Text Available We consider evaluation problem of chromaticity coordinates increment for an image displayed by indicating means (liquid crystal panels and etc.. Display device profile set by the weight matrix for components of primary colors serves as basic data for quantitative calculation. Research results have the form of mathematical expressions allowing calculation of increment values of chromaticity coordinates of the image displayed on indicating means and histograms of increment distribution.

  14. Protective effect of ginger against toxicity induced by chromate in rats.

    Science.gov (United States)

    Krim, Meriem; Messaadia, Amira; Maidi, Imen; Aouacheri, Ouassila; Saka, Saad

    2013-01-01

    The evaluation of the effect of ginger on the modulation of toxic effects induced by chromate is the objective of our study. 50 male rats Albinos Wistar were divided to five groups as follow: group I (T) is served as control, received a mineral water by gavage (per os); group II (G) received an experimental diet with 2% of ginger; group III (Cr) received an oral dose of potassium dichromate (15 mg/kg) and normal diet; group IV (CrG): received an oral dose of potassium dichromate (15 mg/kg) and an experimental diet containing 2% ginger; and group V (Cr(+)G) received an oral dose of potassium dichromate (25 mg/kg) and an experimental diet with 2% of ginger. The results of this study indicate that the chromate provoked a haematoxic effect (anemia), nephrotoxic, hepatotoxic, and also a perturbation in lipids profile. In addition, chromate has a pro-oxidant effect, which was indicated by decrease of reduced glutathione (GSH) levels in different tissues. However, the administration of ginger revealed a reduction of the intensity of oxidative stress induced by the chromate resulting in the decrease of the majority of the previous parameters concentrations. In conclusion we demonstrated that ginger has potent antioxidants activity, revealed by the amelioration of chromate's toxic effects. We can say that ginger has a protective effect towards damages induced by the chromate.

  15. Nanocomposites of Magnetite and Layered Double Hydroxide for Recyclable Chromate Removal

    Directory of Open Access Journals (Sweden)

    Gyeong-Hyeon Gwak

    2016-01-01

    Full Text Available Nanocomposites containing magnetic iron oxide (magnetite nanoparticles and layered double hydroxide (LDH nanosheets were prepared by two different methods, exfoliation-reassembly and coprecipitation, for aqueous chromate adsorbent. According to X-ray diffraction, scanning electron microscopy, and atomic force microscopy, both nanocomposites were determined to develop different nanostructures; LDH nanosheets well covered magnetite nanoparticles with house-of-cards-like structure in exfoliation-reassembly method, while coprecipitation resulted in LDH particle formation along with magnetite nanoparticles. Zeta-potential measurement also revealed that the magnetite surface was effectively covered by LDH moiety in exfoliation-reassembly compared with coprecipitation. Time, pH, concentration dependent chromate adsorption tests, and magnetic separation experiments exhibited that both nanocomposites effectively adsorb and easily collect chromate. However, exfoliation-reassembly nanocomposite was determined to be slightly effective in chromate removal by ~10%. Chromate adsorbed nanocomposites could be regenerated by treating with bicarbonate and the regenerated nanocomposites preserved ~80% of chromate adsorption efficacy after three times of recycling.

  16. A new class of chromatic filters for color image processing. Theory and applications.

    Science.gov (United States)

    Lucchese, Luca; Mitra, Sanjit K

    2004-04-01

    This paper advances a new framework for chromatic filtering of color images. The chromatic content of a color image is encoded in the CIE u'v' chromaticity coordinates whereas the achromatic content is encoded as CIE Y tristimulus value. Within the u'v' chromaticity diagram, colors are added according to the well-known center of gravity law of additive color mixtures, which is generalized here into a nonlinear filtering scheme for processing the two chromatic signals u' and v'. The achromatic channel Y can be processed with traditional filtering schemes, either linear or nonlinear, depending on the specific task at hand. The most interesting characteristics of the new filtering scheme are: 1) the elimination of color smearing effects along edges between bright and dark areas; 2) the possibility of processing chromatic components in a noniterative fashion through linear convolution operations; and 3) the consequent amenability to computationally efficient implementations with fast Fourier transform. The paper includes several examples with both synthetic and real images where the performance of the new filtering method is compared with that of other color image processing algorithms.

  17. Effects of various storage conditions and alterations of antioxidant contents on chromatic aberration of hydroquinone ointment.

    Science.gov (United States)

    Matsubayashi, Teruhisa; Sakaeda, Toshiyuki; Kita, Tomoko; Nakamura, Tsutomu; Kakumoto, Mikio; Funasaka, Yoko; Ichihashi, Masamitsu; Fujita, Takuya; Kamiyama, Fumio; Yamamoto, Akira; Nordlund, James J; Kaneko, Masafumi; Iida, Akira; Okumura, Katsuhiko

    2003-01-01

    Ointments of the skin depigmentation agent hydroquinone (HQ) have been prepared by extemporaneous nonsterile compounding in our hospital. The HQ ointments were highly effective in the treatment of various types of skin pigmentations; however, various problems have emerged including chromatic aberration of the ointments, a relatively large variability of efficacy, and mild side effects. Chromatic aberration is expected to induce non-compliance, and this may be the reason for the relatively large variability in efficacy. In this paper, the effects of various storage conditions on the chromatic aberration and HQ content of HQ ointments were evaluated, and it was suggested that the chromatic aberration was accelerated by exposure to high temperature, air and light, although these had no effect on the HQ content. In addition, various types of HQ ointments were prepared to find a formulation to minimize chromatic aberration, and it was found that the concentrations of antioxidants, Na(2)SO(3) and L(+)-ascorbic acid (AsA), seemed to be too high, and that the protective effect of AsA on chromatic aberration was mainly due to its acidifying effect.

  18. Pigment chromatic adaptation in Cyclotella caspia Grunow (Bacillariophyta

    Directory of Open Access Journals (Sweden)

    Donato Seiji Abe

    1991-01-01

    Full Text Available The diatom Cyclotella caspia Grunow, isolated from surface waters of the Ubatuba region (São Paulo State, Brazil was submitted to different light spectral distributions for examination of its adaptative response. Growth rate and the photosynthetic pigments chlorophyll a, chlorophyll c, carotenoids and phaeopigments were measured under white, blue and red light of the same intensity (8 and 20 µE.cm-2.s-1. Growth rate increased under blue light while red light increased chl a concentration. The relative proportion of chl a and carotenoids did not change, demonstrating the absence of complementary chromatic adaptation.A diatomácea Cyclotella caspia Grunow, isolada de águas superficiais da região de Ubatuba (Estado de São Paulo, Brasil, foi submetida a diferentes intervalos espectrais de luz com a finalidade de se examinar sua resposta adaptativa. Foram medidos a taxa de crescimento e os pigmentos fotossintéticos clorofila a, clorofila c, carotenóides e feopigmentos, sob luz branca, azul e vermelha de mesmas intensidades (8 e 20 µE.cm-2.s-1. A taxa de crescimento aumentou sob luz azul, sendo que a concentração de clorofila a aumentar sob luz vermelha. A proporção relativa de clα e carotenóides não variou, demonstrando a ausência de adapatação cromática complementar.

  19. The dependence of luminous efficiency on chromatic adaptation.

    Science.gov (United States)

    Stockman, Andrew; Jägle, Herbert; Pirzer, Markus; Sharpe, Lindsay T

    2008-12-15

    We investigated the dependence of luminous efficiency on background chromaticity by measuring 25-Hz heterochromatic flicker photometry (HFP) matches in six genotyped male observers on 21 different 1000-photopic-troland adapting fields: 14 spectral ones ranging from 430 to 670 nm and 7 bichromatic mixtures of 478 and 577 nm that varied in luminance ratio. Each function was analyzed in terms of the best-fitting linear combination of the long- (L) and middle- (M) wavelength sensitive cone fundamentals of A. Stockman and L. T. Sharpe (2000). Taking into account the adapting effects of both the backgrounds and the targets, we found that luminous efficiency between 603 and 535 nm could be predicted by a simple model in which the relative L- and M-cone weights are inversely proportional to the mean cone excitations produced in each cone type multiplied by a single factor, which was roughly independent of background wavelength (and may reflect relative L:M cone numerosity). On backgrounds shorter than 535 nm and longer than 603 nm, the M-cone contribution to luminous efficiency falls short of the proportionality prediction but most likely for different reasons in the two spectral regions.

  20. Refractive and diffractive neutron optics with reduced chromatic aberration

    Energy Technology Data Exchange (ETDEWEB)

    Poulsen, S.O., E-mail: stefan.poulsen@northwestern.edu [NEXMAP, Department of Physics, Technical University of Denmark, Anker Engelunds Vej 1, 2800 Kgs. Lyngby (Denmark); Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208 (United States); Poulsen, H.F. [NEXMAP, Department of Physics, Technical University of Denmark, Anker Engelunds Vej 1, 2800 Kgs. Lyngby (Denmark); Bentley, P.M. [European Spallation Source ESS AB, Box 176, 221 00 Lund (Sweden)

    2014-12-11

    Thermal neutron beams are an indispensable tool in physics research. The spatial and the temporal resolution attainable in experiments are dependent on the flux and collimation of the neutron beam which remain relatively poor, even for modern neutron sources. These difficulties may be mitigated by the use of optics for focusing and imaging. Refractive and diffractive optical elements, e.g. compound refractive lenses and Fresnel zone plates, are attractive due to their low cost, and simple alignment. These optical elements, however, suffer from chromatic aberration, which limit their effectiveness to highly monochromatic beams. This paper presents two novel concepts for focusing and imaging non-monochromatic thermal neutron beams with well-known optical elements: (1) a fast mechanical transfocator based on a compound refractive lens, which actively varies the number of individual lenses in the beam path to focus and image a time-of-flight beam, and (2) a passive optical element consisting of a compound refractive lens, and a Fresnel zone plate, which may focus and image both continuous and pulsed neutron beams.

  1. Perceived no reference image quality measurement for chromatic aberration

    Science.gov (United States)

    Lamb, Anupama B.; Khambete, Madhuri

    2016-03-01

    Today there is need for no reference (NR) objective perceived image quality measurement techniques as conducting subjective experiments and making reference image available is a very difficult task. Very few NR perceived image quality measurement algorithms are available for color distortions like chromatic aberration (CA), color quantization with dither, and color saturation. We proposed NR image quality assessment (NR-IQA) algorithms for images distorted with CA. CA is mostly observed in images taken with digital cameras, having higher sensor resolution with inexpensive lenses. We compared our metric performance with two state-of-the-art NR blur techniques, one full reference IQA technique and three general-purpose NR-IQA techniques, although they are not tailored for CA. We used a CA dataset in the TID-2013 color image database to evaluate performance. Proposed algorithms give comparable performance with state-of-the-art techniques in terms of performance parameters and outperform them in terms of monotonicity and computational complexity. We have also discovered that the proposed CA algorithm best predicts perceived image quality of images distorted with realistic CA.

  2. Chromatic visualization of reflectivity variance within hybridized directional OCT images

    Science.gov (United States)

    Makhijani, Vikram S.; Roorda, Austin; Bayabo, Jan Kristine; Tong, Kevin K.; Rivera-Carpio, Carlos A.; Lujan, Brandon J.

    2013-03-01

    This study presents a new method of visualizing hybridized images of retinal spectral domain optical coherence tomography (SDOCT) data comprised of varied directional reflectivity. Due to the varying reflectivity of certain retinal structures relative to angle of incident light, SDOCT images obtained with differing entry positions result in nonequivalent images of corresponding cellular and extracellular structures, especially within layers containing photoreceptor components. Harnessing this property, cross-sectional pathologic and non-pathologic macular images were obtained from multiple pupil entry positions using commercially-available OCT systems, and custom segmentation, alignment, and hybridization algorithms were developed to chromatically visualize the composite variance of reflectivity effects. In these images, strong relative reflectivity from any given direction visualizes as relative intensity of its corresponding color channel. Evident in non-pathologic images was marked enhancement of Henle's fiber layer (HFL) visualization and varying reflectivity patterns of the inner limiting membrane (ILM) and photoreceptor inner/outer segment junctions (IS/OS). Pathologic images displayed similar and additional patterns. Such visualization may allow a more intuitive understanding of structural and physiologic processes in retinal pathologies.

  3. TREATMENT TESTS FOR EX SITU REMOVAL OF CHROMATE & NITRATE & URANIUM (VI) FROM HANFORD (100-HR-3) GROUNDWATER FINAL REPORT

    Energy Technology Data Exchange (ETDEWEB)

    BECK MA; DUNCAN JB

    1994-01-03

    This report describes batch and ion exchange column laboratory scale studies investigating ex situ methods to remove chromate (chromium [VI]), nitrate (NO{sub 3}{sup -}) and uranium (present as uranium [VI]) from contaminated Hanford site groundwaters. The technologies investigated include: chemical precipitation or coprecipitation to remove chromate and uranium; and anion exchange to remove chromate, uranium and nitrate. The technologies investigated were specified in the 100-HR-3 Groundwater Treatability Test Plan. The method suggested for future study is anion exchange.

  4. ANION EXCHANGE CAPACITY OF CHROMATE ON MODIFIED ZEOLITE CLINOPTILOLITE WITH HDTMA-Br AND ITS REGENERATION

    Directory of Open Access Journals (Sweden)

    Widajanti Wibowo

    2011-04-01

    Full Text Available Zeolite Clinoptilolite from Lampung, located in South of Sumatra, had been modified with surfactanthexadecyltrimethylammonium bromide (HDTMA-Br as chromate anion exchanger. Surfactant modified zeolite (SMZClinoptilolite in particle size range of 1.5 - 2.0 mm, which contained 196.7 mmol HDTMA-Br/kg zeolite, was used foranion exchange of chromate at neutral pH. This experiment was conducted in a glass column filled with 5 gram SMZ.The breakthrough chromate exchange capacity was found 1.262 mg/g SMZ, while the total capacity was found 2.107mg/g SMZ. The regeneration of SMZ saturated with chromate was conducted using a mixed solutions of 0.28 MNa2CO3 and 0.5 M NaOH, compared with using a solution of 0.01 M Na2S2O4. The desorption of chromate achieved92% with the mixed solutions of Na2CO3 and NaOH and 90% with the Na2S2O4 solution. The regenerated SMZ withNa2CO3-NaOH solutions was prior washed with HCl solution to remove the carbonate from SMZ, before being used forchromate sorption again. Its breakthrough capacity was reduced to 1.074 mg/g SMZ, and to 0.724 mg/g SMZ whenregenerated with Na2S2O4 solution. These results indicated that regeneration of SMZ affected its exchange capacity foranion chromate. However, it is still could be acceptable, when Na2CO3/NaOH solutions were used for the regenerationof SMZ saturated with anion chromate.

  5. Effects of ocular transverse chromatic aberration on peripheral word identification.

    Science.gov (United States)

    Yang, Shun-Nan; Tai, Yu-chi; Laukkanen, Hannu; Sheedy, James E

    2011-11-01

    Transverse chromatic aberration (TCA) smears the retinal image of peripheral stimuli. We previously found that TCA significantly reduces the ability to recognize letters presented in the near fovea by degrading image quality and exacerbating crowding effect from adjacent letters. The present study examined whether TCA has a significant effect on near foveal and peripheral word identification, and whether within-word orthographic facilitation interacts with TCA effect to affect word identification. Subjects were briefly presented a 6- to 7-letter word of high or low frequency in each trial. Target words were generated with weak or strong horizontal color fringe to attenuate the TCA in the right periphery and exacerbate it in the left. The center of the target word was 1°, 2°, 4°, and 6° to the left or right of a fixation point. Subject's eye position was monitored with an eye-tracker to ensure proper fixation before target presentation. They were required to report the identity of the target word as soon and accurately as possible. Results show significant effect of color fringe on the latency and accuracy of word recognition, indicating existing TCA effect. Observed TCA effect was more salient in the right periphery, and was affected by word frequency more there. Individuals' subjective preference of color-fringed text was correlated to the TCA effect in the near periphery. Our results suggest that TCA significantly affects peripheral word identification, especially when it is located in the right periphery. Contextual facilitation such as word frequency interacts with TCA to influence the accuracy and latency of word recognition.

  6. Chromatic-achromatic perimetry in four clinic cases: Glaucoma and diabetes

    Directory of Open Access Journals (Sweden)

    Inmaculada Cabezos

    2015-01-01

    Full Text Available Background: Some diseases that affect the visual system may show loss of chromatic-achromatic sensitivity before obvious physical signs appear in the usual examination of the eye′s posterior segment. A perimetric study has been conducted with four typical patients with glaucoma and diabetes, at different stages of the disease. Materials and Methods: In addition to the standard white-on-white (standard automated perimetry [SAP], a test battery has been used to study patient′s contrast sensitivity, using stimuli with different chromatic, spatial, and temporal content (multichannel perimetry. The choice of stimuli tries to maximize the response of different visual mechanisms: Achromatic (parvocellular and magnocellular origin; chromatic red-green (parvocellular origin; and chromatic blue-yellow (koniocellular origin. Results: The results seem to indicate losses in the achromatic-parvocellular perimetry and both chromatic perimetry tests, undetected by conventional SAP. Conclusions: Our results illustrate that our patients without visible retinal alterations show signs of suspicion in multichannel perimetry.

  7. Spectral discrimination in color blind animals via chromatic aberration and pupil shape.

    Science.gov (United States)

    Stubbs, Alexander L; Stubbs, Christopher W

    2016-07-19

    We present a mechanism by which organisms with only a single photoreceptor, which have a monochromatic view of the world, can achieve color discrimination. An off-axis pupil and the principle of chromatic aberration (where different wavelengths come to focus at different distances behind a lens) can combine to provide "color-blind" animals with a way to distinguish colors. As a specific example, we constructed a computer model of the visual system of cephalopods (octopus, squid, and cuttlefish) that have a single unfiltered photoreceptor type. We compute a quantitative image quality budget for this visual system and show how chromatic blurring dominates the visual acuity in these animals in shallow water. We quantitatively show, through numerical simulations, how chromatic aberration can be exploited to obtain spectral information, especially through nonaxial pupils that are characteristic of coleoid cephalopods. We have also assessed the inherent ambiguity between range and color that is a consequence of the chromatic variation of best focus with wavelength. This proposed mechanism is consistent with the extensive suite of visual/behavioral and physiological data that has been obtained from cephalopod studies and offers a possible solution to the apparent paradox of vivid chromatic behaviors in color blind animals. Moreover, this proposed mechanism has potential applicability in organisms with limited photoreceptor complements, such as spiders and dolphins.

  8. Combined influences of chromatic aberration and scattering in depth-resolved two-photon fluorescence endospectroscopy.

    Science.gov (United States)

    Wu, Yicong; Li, Xingde

    2010-10-27

    The influence of chromatic aberration of an objective lens in two-photon fluorescence (TPF) endospectroscopy of scattering media has been systematically investigated through both experiments and numerical simulations. Experiments were carried out on a uniform 3D scattering gelatin phantom embedded with TiO(2) granules (to mimic tissue scattering) and fluorescein-tagged polystyrene beads. It was found that fluorescence spectral intensity and lineshape varied as a function of depth when measured with a gradient-index (GRIN) lens which has severe chromatic aberration. The spectral distortion caused by the chromatic aberration became diminishing as the imaging depth increased. Ray tracing analysis and Monte Carlo simulations were carried out to study the interplay of chromatic aberration and scattering in the depth-resolved TPF spectra. The simulation results suggest that the collected fluorescence signals from deeper layers included more out-of-focus photons that experienced a few or multiple scatterings, which diminish the influence of chromatic aberration on the measured TPF spectra. The simulated collection efficiencies of TPF at different wavelengths and depths can be used to properly recover the true depth-resolved TPF spectra of a relatively uniform scattering medium.

  9. The main injector chromaticity correction sextupole magnets: Measurements and operating schemes

    Energy Technology Data Exchange (ETDEWEB)

    Bhat, C.M.; Bogacz, A.; Brown, B.C.; Harding, D.J.; Fang, S.J.; Martin, P.S.; Glass, H.D.; Sim, J.

    1995-05-01

    The Fermilab Main Injector (FMI) is a high intensity proton synchrotron which will be used to accelerate protons and antiprotons from 8.9 GeV/c to 150 GeV/c. The natural chromaticities of the machine for the horizontal and the vertical Planes are {minus}33.6 and {minus}33.9 respectively. The {Delta}p/p of the beam at injection is about 0.002. The chromaticity requirements of the FMI, are primarily decided by the {Delta}p/p = 0.002 of the beam at injection. This limits the final chromaticity of the FMI to be {plus_minus}5 units. To correct the chromaticity in the FMI two families of sextupole magnets will be installed in the lattice, one for each plane. A sextupole magnet suitable for the FMI needs has been designed and a number of them are being built. New chromaticity compensation schemes have been worked out in the light of recently proposed faster acceleration ramps. On an R/D sextupole magnet the low current measurements have been carried out to determine the electrical properties. Also, using a Morgan coil, measurements have been performed to determine the higher ordered multipole components up to 18-poles. An overview of these result are presented here.

  10. Spectral discrimination in color blind animals via chromatic aberration and pupil shape

    Science.gov (United States)

    Stubbs, Alexander L.; Stubbs, Christopher W.

    2016-01-01

    We present a mechanism by which organisms with only a single photoreceptor, which have a monochromatic view of the world, can achieve color discrimination. An off-axis pupil and the principle of chromatic aberration (where different wavelengths come to focus at different distances behind a lens) can combine to provide “color-blind” animals with a way to distinguish colors. As a specific example, we constructed a computer model of the visual system of cephalopods (octopus, squid, and cuttlefish) that have a single unfiltered photoreceptor type. We compute a quantitative image quality budget for this visual system and show how chromatic blurring dominates the visual acuity in these animals in shallow water. We quantitatively show, through numerical simulations, how chromatic aberration can be exploited to obtain spectral information, especially through nonaxial pupils that are characteristic of coleoid cephalopods. We have also assessed the inherent ambiguity between range and color that is a consequence of the chromatic variation of best focus with wavelength. This proposed mechanism is consistent with the extensive suite of visual/behavioral and physiological data that has been obtained from cephalopod studies and offers a possible solution to the apparent paradox of vivid chromatic behaviors in color blind animals. Moreover, this proposed mechanism has potential applicability in organisms with limited photoreceptor complements, such as spiders and dolphins. PMID:27382180

  11. CLASSIFICATION OF COMPLETE 5-PARTITE GRAPHS AND CHROMATICITY OF 5-PARTITE GRAPHSWITH 5n VERTICES

    Institute of Scientific and Technical Information of China (English)

    ZhaoHaixing; LiuRuying; ZhangShenggui

    2004-01-01

    For a graph G,P(G,λ)denotes the chromatic polynomial of G. Two graphs G and H are said to be chromatically equivalent,denoted by G-H,if P(G,λ)=p(H,λ). Let[G]= {H|H-G}. If [G]={G},then G is said to be chromatically unique. For a complete 5-partite graph G with 5n vertices, define θ(G)=(a(G,6)-2n+1-2n-1+5)/2n-2,where a(G,6) denotes the number of 6-independent partitions of G. In this paper, the authors show that θ(G)≥0 and determine all graphs with θ(G)= 0, 1, 2, 5/2, 7/2, 4, 17/4. By using these results the chromaticity of 5-partite graphs of the form G-S with θ(G)=0,1,2,5/2,7/2,4,17/4 is investigated,where S is a set of edges of G. Many new chromatically unique 5-partite graphs are obtained.

  12. Luminance mechanisms mediate the motion of red-green isoluminant gratings: the role of "temporal chromatic aberration".

    Science.gov (United States)

    Mullen, Kathy T; Yoshizawa, Tatsuya; Baker, Curtis L

    2003-05-01

    In this paper we use a dynamic noise-masking paradigm to explore the nature of the mechanisms mediating the motion perception of drifting isoluminant red-green gratings. We compare contrast thresholds for the detection and direction discrimination of drifting gratings (1.5 cpd), over a range of temporal frequencies (0.5-9 Hz) in the presence of variable luminance or chromatic noise. In the first experiment, we used dynamic luminance noise to show that direction thresholds for red-green grating motion are masked by luminance noise over the entire temporal range tested, whereas detection thresholds are unaffected. This result indicates that the motion of nominally isoluminant red-green gratings is mediated by luminance signals. We suggest that stimulus-based luminance artifacts are not responsible for this effect because there is no masking of the detection thresholds. Instead we propose that chromatic motion thresholds for red-green isoluminant gratings are mediated by dynamic luminance artifacts that have an internal, physiological origin. We have termed these "temporal chromatic aberration". In the second experiment, we used dynamic chromatic noise masking to test for a chromatic contribution to red-green grating motion. We were unable to find conclusive evidence for a contribution of chromatic mechanisms to the chromatic grating motion, although a contribution at very high chromatic contrasts cannot be ruled out. Our results add to a growing body of evidence indicating the presence of dynamic, internal luminance artifacts in the motion of chromatic stimuli and we show that these occur even at very low temporal rates. Our results are compatible with our previous work indicating the absence of a chromatic mechanism for first order (quasi-linear) apparent motion [Vision Res. 40 (2000) 1993]. We conclude that previous conclusions based on the motion of chromatic red-green gratings should be reassessed to determine the contribution of dynamic luminance artifacts.

  13. Tune and Chromaticity Control During Snapback and Ramp in 2015 LHC Operation

    CERN Document Server

    Schaumann, Michaela; Lamont, Mike; Solfaroli Camillocci, Matteo; Todesco, Ezio; Wenninger, Jorg

    2016-01-01

    Because of current redistribution on the superconducting cables, the harmonic components of the magnetic fields of the superconducting magnets in the Large Hadron Collider (LHC) show decay during the low field injection plateau. This results in tune and chromaticity variations for the beams. In the first few seconds of the ramp the original hysteresis state of the magnetic field is restored - the field snaps back. These fast dynamic field changes lead to strong tune and chromaticity excursions that, if not properly controlled, induce beam losses and potentially trigger a beam dump. A feed-forward system applies predicted corrections during the injection plateau and to the first part of the ramp to avoid violent changes of beam conditions. This paper discusses the snapback of tune and chromaticity as observed in 2015, as well as the control of beam parameters during the ramp. It also evaluates the quality of the applied feed-forward corrections and their reproducibility.

  14. Limits on Foreground Subtraction from Chromatic Beam Effects in Global Redshifted 21 cm Measurements

    CERN Document Server

    Mozdzen, Thomas J; Monsalve, Raul A; Rogers, Alan E E

    2015-01-01

    Foreground subtraction in global redshifted 21 cm measurements is limited by frequency-dependent (chromatic) structure in antenna beam patterns. Chromatic beams couple angular structures in Galactic foreground emission to spectral structures that may not be removed by smooth functional forms. We report results for simulations based on two dipole antennas used by the Experiment to Detect the Global EoR Signature (EDGES). The residual levels in simulated foreground-subtracted spectra are found to differ substantially between the two antennas, suggesting that antenna design must be carefully considered. Residuals are also highly dependent on the right ascension and declination of the antenna pointing, with RMS values differing by as much as a factor of 20 across pointings. For EDGES and other ground-based experiments with zenith pointing antennas, right ascension and declination correspond directly to the local sidereal time and the latitude of the deployment site, hence chromatic beam effects should be taken in...

  15. Passive depth estimation using chromatic aberration and a depth from defocus approach.

    Science.gov (United States)

    Trouvé, Pauline; Champagnat, Frédéric; Le Besnerais, Guy; Sabater, Jacques; Avignon, Thierry; Idier, Jérôme

    2013-10-10

    In this paper, we propose a new method for passive depth estimation based on the combination of a camera with longitudinal chromatic aberration and an original depth from defocus (DFD) algorithm. Indeed a chromatic lens, combined with an RGB sensor, produces three images with spectrally variable in-focus planes, which eases the task of depth extraction with DFD. We first propose an original DFD algorithm dedicated to color images having spectrally varying defocus blurs. Then we describe the design of a prototype chromatic camera so as to evaluate experimentally the effectiveness of the proposed approach for depth estimation. We provide comparisons with results of an active ranging sensor and real indoor/outdoor scene reconstructions.

  16. Numerical analysis of low chromatic aberration of a gradient refractive index rod lens.

    Science.gov (United States)

    Lv, Hao; Liu, Aimei; Yi, Xunong; Li, Qianguang

    2009-01-20

    The oxide compositions (OCs) model is established for discussing the chromatic aberrations of a gradient refractive index rod lens. The chromatic aberrations for Na(+)/Li(+), K(+)/Cs(+), and K(+)/Tl(+) ion exchanges are discussed based on the OC model and the Huggins-Sun-Davis (HSD) model. Theoretical results indicate that the function value mainly depends on base glass properties and the nature of exchanging ion pairs, and rarely depends on the quantity of ion exchange. Experimental results show that the chromatic aberrations using the OC model have smaller errors than with the HSD model. The estimating average errors between the OC model and the HSD model are -0.051, -0.0067, and 0.0047 for the K(+)/Tl(+), Li(+)/Na(+), and K(+)/Cs(+) ion exchanges, respectively.

  17. Chromatic aberration of light focusing in hyperbolic anisotropic metamaterial made of metallic slit array.

    Science.gov (United States)

    Guo, Kai; Liu, Jianlong; Zhang, Yan; Liu, Shutian

    2012-12-17

    The dispersion of a hyperbolic anisotropic metamaterial (HAM) and the chromatic aberration of light focusing in this kind of HAM are studied. The HAM is formed by alternately stacking metal and dielectric layers. The rules of materials and filling factors affecting the optical property of HAM are given. The chromatic aberration of light focusing is demonstrated both theoretically and numerically. By comparing the theory with the simulation results, the factors influencing the focal length, including the heat loss of material and low spatial frequency modes, are discussed. The investigation emphasizes the anomalous properties, such as chromatic aberration and low spatial frequency modes influencing focus position, of HAM compared with that in conventional lens. Based on the analysis, the possibility of using HAM to focus light with two different wavelengths at the same point is studied.

  18. An XPS study of the adsorption of chromate on goethite ( α-FeOOH)

    Science.gov (United States)

    Abdel-Samad, Hesham; Watson, Philip R.

    1997-03-01

    The adsorption behavior of inorganic oxyanions on soil minerals is an important factor in the transport of subsurface environmental pollutants. We have studied the adsorption of chromate (CrO 42-) from aqueous solution on the surface of the mineral goethite ( α-FeOOH) as a function of pH and adsorbate concentration in 0.05 M NaNO 3 solution. Results obtained from the dried surface by X-ray photoelectron spectroscopy (XPS) are in good agreement with data from spectrophotometric analysis of chromate remaining in the supernatant liquid. Chromate adsorption increases with decreasing pH of the solution and eventually reaches a maximum at pH 6.5. The chromium XPS signal indicates that initially a small amount of chromium adsorbs in the +3 oxidation state via a redox reaction, but that the large majority of chromium remains in the +6 oxidation state.

  19. Versatile chromatic dispersion measurement of a single mode fiber using spectral white light interferometry.

    Science.gov (United States)

    Lee, Ji Yong; Kim, Dug Young

    2006-11-27

    We present a versatile and accurate chromatic dispersion measurement method for single mode optical fibers over a wide spectral range (200 nm) using a spectral domain white light interferometer. This technique is based on spectral interferometry with a Mach-Zehnder interferometer setup and a broad band light source. It takes less than a second to obtain a spectral interferogram for a few tens of centimeter length fiber sample. We have demonstrated that the relative group velocity, the chromatic dispersion and the dispersion slope of a sample fiber can be obtained very accurately regardless of the zero-dispersion wavelength (ZDW) of a sample after frequency dependent optical phase was directly retrieved from a spectral interferogram. The measured results with our proposed method were compared with those obtained with a conventional time-domain dispersion measurement method. A good agreement between those results indicates that our proposed method can measure the chromatic dispersion of a short length optical fiber with very high accuracy.

  20. Structure determination and functional analysis of a chromate reductase from Gluconacetobacter hansenii.

    Directory of Open Access Journals (Sweden)

    Hongjun Jin

    Full Text Available Environmental protection through biological mechanisms that aid in the reductive immobilization of toxic metals (e.g., chromate and uranyl has been identified to involve specific NADH-dependent flavoproteins that promote cell viability. To understand the enzyme mechanisms responsible for metal reduction, the enzyme kinetics of a putative chromate reductase from Gluconacetobacter hansenii (Gh-ChrR was measured and the crystal structure of the protein determined at 2.25 Å resolution. Gh-ChrR catalyzes the NADH-dependent reduction of chromate, ferricyanide, and uranyl anions under aerobic conditions. Kinetic measurements indicate that NADH acts as a substrate inhibitor; catalysis requires chromate binding prior to NADH association. The crystal structure of Gh-ChrR shows the protein is a homotetramer with one bound flavin mononucleotide (FMN per subunit. A bound anion is visualized proximal to the FMN at the interface between adjacent subunits within a cationic pocket, which is positioned at an optimal distance for hydride transfer. Site-directed substitutions of residues proposed to involve in both NADH and metal anion binding (N85A or R101A result in 90-95% reductions in enzyme efficiencies for NADH-dependent chromate reduction. In comparison site-directed substitution of a residue (S118A participating in the coordination of FMN in the active site results in only modest (50% reductions in catalytic efficiencies, consistent with the presence of a multitude of side chains that position the FMN in the active site. The proposed proximity relationships between metal anion binding site and enzyme cofactors is discussed in terms of rational design principles for the use of enzymes in chromate and uranyl bioremediation.

  1. UHF Signal Processing and Pattern Recognition of Partial Discharge in Gas-Insulated Switchgear Using Chromatic Methodology

    Science.gov (United States)

    Wang, Xiaohua; Li, Xi; Rong, Mingzhe; Xie, Dingli; Ding, Dan; Wang, Zhixiang

    2017-01-01

    The ultra-high frequency (UHF) method is widely used in insulation condition assessment. However, UHF signal processing algorithms are complicated and the size of the result is large, which hinders extracting features and recognizing partial discharge (PD) patterns. This article investigated the chromatic methodology that is novel in PD detection. The principle of chromatic methodologies in color science are introduced. The chromatic processing represents UHF signals sparsely. The UHF signals obtained from PD experiments were processed using chromatic methodology and characterized by three parameters in chromatic space (H, L, and S representing dominant wavelength, signal strength, and saturation, respectively). The features of the UHF signals were studied hierarchically. The results showed that the chromatic parameters were consistent with conventional frequency domain parameters. The global chromatic parameters can be used to distinguish UHF signals acquired by different sensors, and they reveal the propagation properties of the UHF signal in the L-shaped gas-insulated switchgear (GIS). Finally, typical PD defect patterns had been recognized by using novel chromatic parameters in an actual GIS tank and good performance of recognition was achieved. PMID:28106806

  2. Rare earth and silane as chromate replacers for corrosion protection on galvanized steel

    Institute of Scientific and Technical Information of China (English)

    PENG Tianlan; MAN Ruilin

    2009-01-01

    The present work aimed at using rare earth lanthanum salt and trimethoxy(viny)silance as chromate substitutes for galvanized steel passivation, in contrast to zinc coating samples treated with chromate. The corrosion resistance was assessed by electrochemical impedance spectroscopy (EIS) and neutral salt spray tests (NSS). Scanning electron microscopy (SEM) was used to characterize the sample surfaces. The organic coating adhesion on the panel was also investigated via varnishes-cross cut tests. The results indicated that rare earth and silane two-step treatment gave more effective anticorrosion performance than Cr, which also provided good paint adhesion. The coating formation mechanism was also discussed.

  3. On Chromatic no. of 3K1-free graphs and R(3, k)

    OpenAIRE

    Dhurandhar, Medha S.

    2012-01-01

    Here we prove that if G has independence no. 2 and clique size omega with omega less than or equal to 11, then (1) chromatic no. is less than or equal to (omega2+12omega-13)/8, if omega is odd, and (2) chromatic no. is less than or equal to (omega2+10omega)/8, if omega is even. We further conjecture that the results are true in general for all omega. We also conjecture that (A) if omega is odd and R(3, omega) is even, then R(3, omega) = (omega2+8omega-9)/4, (B) if omega and R(3, omega) are bo...

  4. Betatron Tune Spread Generation and Differential Chromaticity Control by Octupole at Tevatron

    CERN Document Server

    Ivanov, Petr M; Annala, Jerry; Lebedev, Valeri

    2005-01-01

    Application of octupoles for Landau damping of the unstable head-tail modes requires careful consideration at their combination into separate families to insure maximum effectiveness and avoid degradation of the dynamic aperture due to the non-linear magnetic fields. Existing octupolar magnets around the machine have been arranged into four functional families with individual power supplies. Two of these families generate betatron tune spreads in the vertical and horizontal planes whereas the other two control the differential chromaticity between the proton and antiproton helices. The calculated effect on tunes and chromaticity is compared with direct measurements. Analytical formulas for betatron tune spectral density functions are presented.

  5. Differential algebraic method for arbitrary order curvilinear-axis combined geometric-chromatic aberration analysis

    CERN Document Server

    Cheng Min; Lu Yi Long; Yao Zhen Hua

    2003-01-01

    The principle of differential algebra is applied to analyse and calculate arbitrary order curvilinear-axis combined geometric-chromatic aberrations of electron optical systems. Expressions of differential algebraic form of high order combined aberrations are obtained and arbitrary order combined aberrations can be calculated numerically. As an example, a typical wide electron beam focusing system with curved optical axes named magnetic immersion lens has been studied. All the second-order and third-order combined geometric-chromatic aberrations of the lens have been calculated, and the patterns of the corresponding geometric aberrations and combined aberrations have been given as well.

  6. Study on chromatic aberration in a population of Chinese myopic eyes by means of optical design.

    Science.gov (United States)

    He, Yuanqing; Wang, Yan; Wang, Zhaoqi; Fang, Chao; Liu, Yongji; Zhang, Lin; Zheng, Shaolin; Wang, Lu; Chang, Shengjiang

    2013-05-01

    Two kinds of individual eye models, involving and without involving the angle between visual axis and optical axis, are established by means of optical design. We use them to study the properties of the transverse chromatic aberration (TCA) and longitudinal chromatic aberration (LCA) over the visible spectrum. Then the effects of the LCA and TCA on the visual quality of human eyes are evaluated. The statistical averages of TCA and LCA over the visible spectrum for Chinese myopic eyes are obtained. Results show that both TCA and LCA restrict the visual performance, and LCA is more detrimental than TCA.

  7. Varying chromaticity: A damping mechanism for the transverse head-tail instability

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, W.; Wurtele, J.S. [Department of Physics, University of California at Berkeley, Berkeley, California 94720 (United States); Sessler, A.M.; Wurtele, J.S. [Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

    1997-10-01

    A detailed analytical and numerical study of the suppression of the transverse head-tail instability by modulating the chromaticity over a synchrotron period is presented. We find that a threshold can be developed, and it can be increased to a value larger than the strong head-tail instability threshold. The stability criterion derived agrees very well with the simulations. The underlying physical mechanisms of the damping scheme are rotation of the head-tail phase such that the instability does not occur, and Landau damping due to the incoherent betatron tune spread generated by the varying chromaticity. {copyright} {ital 1997} {ital The American Physical Society}

  8. Coded-subcarrier-aided chromatic dispersion monitoring scheme for flexible optical OFDM networks.

    Science.gov (United States)

    Tse, Kam-Hon; Chan, Chun-Kit

    2014-08-11

    A simple coded-subcarrier aided scheme is proposed to perform chromatic dispersion monitoring in flexible optical OFDM networks. A pair of coded label subcarriers is added to both edges of the optical OFDM signal spectrum at the edge transmitter node. Upon reception at any intermediate or the receiver node, chromatic dispersion estimation is performed, via simple direct detection, followed by electronic correlation procedures with the designated code sequences. The feasibility and the performance of the proposed scheme have been experimentally characterized. It provides a cost-effective monitoring solution for the optical OFDM signals across intermediate nodes in flexible OFDM networks.

  9. New chromaticity compensation approach and dynamic aperture increase in the SSRF storage ring

    Institute of Scientific and Technical Information of China (English)

    TIAN Shun-Qiang; HOU Jie; CHEN Guang-Ling; LIU Gui-Min

    2008-01-01

    Strong chromatic sextupoles used to compensate natural chromaticities in the third generation light source storage ring usually reduce dynamic aperture drastically.Many optimization methods can be used to find solutions that provide large dynamic apertures.This paper discusses a new optimization approach of sextupole strengths with step-by-step procedure,which is applied in the SSRF storage ring,and a better solution is obtained.Investigating driving terms generated by the sextupoles in every step can analyze their convergences and guide the weight setting among different terms in object function of the single resonance approach based on the perturbation theory.

  10. The oxygen isotope composition of dissolved chromate: a new tool for determining sources of chromium contamination in groundwater

    Science.gov (United States)

    Bullen, T.; Widory, D.

    2009-05-01

    Hexavalent chromium (Cr(VI)) is a widespread carcinogen in groundwater, derived from both anthropogenic and natural sources. A large range of chromium isotope composition has been demonstrated for dissolved Cr(VI) in groundwater, resulting from the large isotope fractionation accompanying reduction of Cr(VI) to trivalent chromium (Cr(III)). As a result, the isotopic composition of chromium in dissolved chromate is beginning to prove useful for determining the sources of chromium in contaminated groundwater, but considered alone can likewise be non-diagnostic due to overlapping compositional ranges of potential anthropogenic and natural sources. Based on the strong Cr-O bond in the chromate molecule implied by the large chromium isotope fractionation accompanying Cr(VI) reduction, we have proposed that oxygen will remain closely linked to chromium in the chromate molecule and thus can be used to better constrain chromate sources through a Cr-O "multi-tracer" approach. In a series of laboratory experiments using isotopically "enriched" water and "normal" chromate, we have demonstrated that there is insignificant isotopic exchange between oxygen in chromate and water for residence times as long as one year, and thus chromate will retain the oxygen isotope composition of its source during extended transport in groundwater. We have likewise demonstrated that sufficient chromate for oxygen isotope analysis can be successfully isolated from a chemically complex groundwater sample through a series of precipitation, ion exchange and heating procedures. Although our current approach of measuring 100 micromolar samples of chromate using TCEA- gas mass spectrometry is straightforward and robust, we are also developing a negative-ion thermal ionization mass spectrometry technique in order to greatly reduce the sample size requirement. We are currently applying this novel technique at an electric power facility in California and a metal plating facility in France in order to

  11. Chick eyes compensate for chromatic simulations of hyperopic and myopic defocus: evidence that the eye uses longitudinal chromatic aberration to guide eye-growth.

    Science.gov (United States)

    Rucker, Frances J; Wallman, Josh

    2009-07-01

    Longitudinal chromatic aberration (LCA) causes short wavelengths to be focused in front of long wavelengths. This chromatic signal is evidently used to guide ocular accommodation. We asked whether chick eyes exposed to static gratings simulating the chromatic effects of myopic or hyperopic defocus would "compensate" for the simulated defocus. We alternately exposed one eye of each chick to a sine-wave grating (5 or 2 cycle/deg) simulating myopic defocus ("MY defocus": image focused in front of retina; hence, red contrast higher than blue) and the other eye to a grating of the same spatial frequency simulating hyperopic defocus ("HY defocus": blue contrast higher than red). The chicks were placed in a drum with one eye covered with one grating, and then switched to another drum with the other grating with the other eye covered. To minimize the effects of altered eye-growth on image contrast, we studied only the earliest responses: first, we measured changes in choroidal thickness 45 min to 1 h after one 15-min episode in the drum, then we measured glycosaminoglycans (GAG) synthesis in sclera and choroid (by the incorporation of labeled sulfate in tissue culture) after a day of four 30-min episodes in the drum. The eyes compensated in the appropriate directions: The choroids of the eyes exposed to the HY simulation showed significantly more thinning (less thickening) over the course of the experiment than the choroids of the eyes exposed to the MY simulation (all groups mean:-17 microm; 5 c/d groups: -24 microm; paired t-test (one-tailed): p=0.0006). The rate of scleral GAG synthesis in the eye exposed to the HY simulation was significantly greater than in the eye exposed to the MY simulation (HY/MY ratio=1.20; one sample t-test (one-tailed): p=0.015). There was no significant interaction between the sign of the simulated defocus and either the spatial frequency or the presence of a +3 D lens used to compensate for the 33 cm distance of the drum. Although previous

  12. Effects of iron stress on chromatic adaptation by natural phytoplankton communities in the Southern Ocean

    NARCIS (Netherlands)

    van Leeuwe, M.A.; Timmermans, K.R.; Witte, H.J.; Kraay, G.W.; Veldhuis, M.J.W.; de Baar, H.J.W.

    1998-01-01

    Effects of iron stress on chromatic adaptation were studied in natural phytoplankton communities collected in the Pacific region of the Southern Ocean. Iron enrichment experiments (48 to 72 h) were performed, incubating plankton communities under white, green and blue light respectively, with and wi

  13. SIMULTANEOUS DTERMINATION OF CHROMATE AND AROMATIC HYDROCARBONS IN ENVIRONMENTAL SAMPLES BY CAPILLARY ELECTROPHORESIS

    Science.gov (United States)

    An analytical method was developed to determine simultaneously, the inorganic anion CrO2-4, and organic aromatic compounds including benzoate, 2-Cl-benzoate, phenol, m-cresol and o-/p-cresol by capillary electrophoresis (CE). Chromate and the aromatics were separated in a relativ...

  14. Perception of Chromatic cues during host location by the pupal parasitoid Pimpla turionellae (L.) (Hymenoptera: Ichneumonidae)

    NARCIS (Netherlands)

    Fischer, S.; Samietz, J.; Wäckers, F.L.; Dorn, S.

    2004-01-01

    Chromatic and achromatic plant cues are expected to be particularly important for parasitoids of endophytic pupal hosts, because these stages do not feed and therefore avoid volatile emission caused by plant tissue damage. Endophytic feeding can cause discoloration or desiccation, leading to changes

  15. Measurement of chromatic dispersion of microstructured polymer fibers by white-light spectral interferometry

    DEFF Research Database (Denmark)

    Hlubina, Petr; Ciprian, Dalibor; Frosz, Michael Henoch;

    2009-01-01

    of the method by measuring the wavelength dependence of the differential group refractive index of a pure silica fiber. We apply a five-term power series fit to the measured data and confirm by its differentiation that the chromatic dispersion of pure silica glass agrees well with theory. Second, we measure...

  16. A "Green" Passivation of Zinc containing surfaces as an alternative to chromate

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Maahn, Ernst emanuel; Møller, Per

    1996-01-01

    With view to a replacement for chromate passivation, Molyphos was developed under the Danish Materials Programme I (MUP I). In the Danish Materials Programme II(MUP II), the further development of Molyphos a molybdate phosphate conversion coating has been undertaken by application of a sealer...

  17. Delay differential models in multimode laser dynamics: taking chromatic dispersion into account

    Science.gov (United States)

    Vladimirov, A. G.; Huyet, G.; Pimenov, A.

    2016-04-01

    A set of differential equations with distributed delay is derived for modeling of multimode ring lasers with intracavity chromatic dispersion. Analytical stability analysis of continuous wave regimes is performed and it is demonstrated that sufficiently strong anomalous dispersion can destabilize these regimes.

  18. Chromatic variation of aberration: the role of induced aberrations and raytrace direction

    Science.gov (United States)

    Berner, A.; Nobis, T.; Shafer, D.; Gross, H.

    2015-09-01

    The design and optimization process of an optical system contains several first order steps. The definition of the appropriate lens type and the fixation of the raytrace direction are some of them. The latter can be understood as a hidden assumption rather than an aware design step. This is usually followed by the determination of the paraxial lens layout calculated for the primary wavelength. It is obvious, that for this primary wavelength the paraxial calculations are independent of raytrace direction. Today, most of the lens designs are specified not to work only for one wavelength, but in a certain wavelength range. Considering such rays of other wavelengths, one can observe that depending on the direction there will already occur differences in the first order chromatic aberrations and additionally in the chromatic variation of the third-order aberrations. The reason for this effect are induced aberrations emerging from one surface to the following surfaces by perturbed ray heights and ray angles. It can be shown, that the total amount of surface-resolved first order chromatic aberrations and the chromatic variation of the five primary aberrations can be split into an intrinsic part and an induced part. The intrinsic part is independent of the raytrace direction whereas the induced part is not.

  19. Experimental verification of the minimum number of diffractive zones for effective chromatic correction in the LWIR

    Science.gov (United States)

    Ramsey, J. L.; Walsh, K. F.; Smith, M.; Deegan, J.

    2016-05-01

    With the move to smaller pixel sizes in the longwave IR region there has been a push for shorter focal length lenses that are smaller, cheaper and lighter and that resolve lower spatial frequencies. As a result lenses must have better correction for both chromatic and monochromatic aberrations. This leads to the increased use of aspheres and diffractive optical elements (kinoforms). With recent developments in the molding of chalcogenide materials these aspheres and kinoforms are more cost effective to manufacture. Without kinoforms the axial color can be on the order of 15 μm which degrades the performance of the lens at the Nyquist frequency. The kinoforms are now on smaller elements and are correcting chromatic aberration which is on the order of the design wavelength. This leads to kinoform structures that do not require large phase changes and therefore have 1.5 to just over 2 zones. The question becomes how many zones are required to correct small amounts of chromatic aberration in the system and are they functioning as predicted by the lens design software? We investigate both the design performance and the as-built performance of two designs that incorporate kinoforms for the correction of axial chromatic aberration.

  20. Chromatic confocal microscopy for multi-depth imaging of epithelial tissue.

    Science.gov (United States)

    Olsovsky, Cory; Shelton, Ryan; Carrasco-Zevallos, Oscar; Applegate, Brian E; Maitland, Kristen C

    2013-05-01

    We present a novel chromatic confocal microscope capable of volumetric reflectance imaging of microstructure in non-transparent tissue. Our design takes advantage of the chromatic aberration of aspheric lenses that are otherwise well corrected. Strong chromatic aberration, generated by multiple aspheres, longitudinally disperses supercontinuum light onto the sample. The backscattered light detected with a spectrometer is therefore wavelength encoded and each spectrum corresponds to a line image. This approach obviates the need for traditional axial mechanical scanning techniques that are difficult to implement for endoscopy and susceptible to motion artifact. A wavelength range of 590-775 nm yielded a >150 µm imaging depth with ~3 µm axial resolution. The system was further demonstrated by capturing volumetric images of buccal mucosa. We believe these represent the first microstructural images in non-transparent biological tissue using chromatic confocal microscopy that exhibit long imaging depth while maintaining acceptable resolution for resolving cell morphology. Miniaturization of this optical system could bring enhanced speed and accuracy to endomicroscopic in vivo volumetric imaging of epithelial tissue.

  1. Measurement of chromatic aberration in STEM and SCEM by coherent convergent beam electron diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, C.L. [Monash Centre for Electron Microscopy, Monash University, Victoria 3800 (Australia); Etheridge, J., E-mail: joanne.etheridge@monash.edu [Monash Centre for Electron Microscopy, Monash University, Victoria 3800 (Australia); Department of Materials Engineering, Monash University, Victoria 3800 (Australia)

    2013-02-15

    A simple method is described for the accurate and precise measurement of chromatic aberration under electron-optical conditions pertinent to scanning transmission electron microscopy (STEM) and scanning confocal electron microscopy (SCEM). The method requires only the measurement of distances in a coherent CBED pattern and knowledge of the electron wavelength and the lattice spacing of a calibration specimen. The chromatic aberration of a spherical-aberration corrected 300 kV thermal field emission TEM is measured in STEM and SCEM operating modes and under different condenser lens settings. The effect of the measured chromatic aberrations on the 3 dimensional intensity distribution of the electron probe is also considered. - Highlights: ► A method is presented to measure chromatic aberration (C{sub c}) using coherent CBED. ► The C{sub c} of the probe and imaging lens systems in STEM and SCEM modes is measured in a C{sub 3}-corrected S/TEM. ► The effect of the measured C{sub c} on the depth resolution in STEM is simulated for different energy spreads.

  2. Segmentation of color images by chromaticity features using self-organizing maps

    Directory of Open Access Journals (Sweden)

    Farid García-Lamont

    2016-08-01

    Full Text Available Usually, the segmentation of color images is performed using cluster-based methods and the RGB space to represent the colors. The drawback with these methods is the a priori knowledge of the number of groups, or colors, in the image; besides, the RGB space issensitive to the intensity of the colors. Humans can identify different sections within a scene by the chromaticity of its colors of, as this is the feature humans employ to tell them apart. In this paper, we propose to emulate the human perception of color by training a self-organizing map (SOM with samples of chromaticity of different colors. The image to process is mapped to the HSV space because in this space the chromaticity is decoupled from the intensity, while in the RGB space this is not possible. Our proposal does not require knowing a priori the number of colors within a scene, and non-uniform illumination does not significantly affect the image segmentation. We present experimental results using some images from the Berkeley segmentation database by employing SOMs with different sizes, which are segmented successfully using only chromaticity features.

  3. Commissioning of the nonlinear chromaticity at injection for LHC Run II

    CERN Document Server

    AUTHOR|(CDS)2080608; Tomas Garcia, Rogelio; Carlier, Felix Simon; Langner, Andy Sven; Malina, Lukas; Persson, Tobias Hakan Bjorn; Coello De Portugal - Martinez Vazquez, Jaime Maria; Skowronski, Piotr Krzysztof; Garcia-Tabares Valdivieso, Ana; CERN. Geneva. ATS Department

    2016-01-01

    For the first time, correction of nonlinear chromaticity and amplitude detuning was included in the LHC commissioning for Run II. The corrections found during the nonlinear optics commissioning have been deployed operationally at injection in the LHC. This note summarizes the relevant measurements and corrections performed during the first commissioning of the LHC in Run II

  4. Experimental demonstration of the maximum likelihood-based chromatic dispersion estimator for coherent receivers

    DEFF Research Database (Denmark)

    Borkowski, Robert; Johannisson, Pontus; Wymeersch, Henk;

    2014-01-01

    We perform an experimental investigation of a maximum likelihood-based (ML-based) algorithm for bulk chromatic dispersion estimation for digital coherent receivers operating in uncompensated optical networks. We demonstrate the robustness of the method at low optical signal-to-noise ratio (OSNR) ...

  5. On the chromatic number of pentagon-free graphs of large minimum degree

    DEFF Research Database (Denmark)

    Thomassen, Carsten

    2007-01-01

    We prove that, for each fixed real number c > 0, the pentagon-free graphs of minimum degree at least cn (where n is the number of vertices) have bounded chromatic number. This problem was raised by Erdős and Simonovits in 1973. A similar result holds for any other fixed odd cycle, except the tria...

  6. Orbit, optics and chromaticity correction for PS2 negative momentum compaction lattices

    Energy Technology Data Exchange (ETDEWEB)

    Papaphilippou,Y.; Barranco, J.; Bartmann, W.; Benedikt, M.; Carli, C.; de Maria, R.; Peggs, S.; Trbojevic, D.

    2009-05-04

    The effect of magnet misalignments in the beam orbit and linear optics functions are reviewed and correction schemes are applied to the negative momentum compaction lattice of PS2. Chromaticity correction schemes are also proposed and tested with respect to off-momentum optics properties. The impact of the correction schemes in the dynamic aperture of the lattice is finally evaluated.

  7. 100-D Area In Situ Redox Treatability Test for Chromate-Contaminated Groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Mark D.; Vermeul, Vincent R.; Szecsody, James E.; Fruchter, Jonathan S.

    2000-10-12

    A treatability test was conducted for the In Situ Redox Manipulation (ISRM) technology at the 100 D Area of the U. S. Department of Energy's Hanford Site. The target contaminant was dissolved chromate in groundwater. The ISRM technology creates a permeable subsurface treatment zone to reduce mobile chromate in groundwater to an insoluble form. The ISRM permeable treatment zone is created by reducing ferric iron to ferrous iron within the aquifer sediments, which is accomplished by injecting aqueous sodium dithionite into the aquifer and then withdrawing the reaction products. The goal of the treatability test was to create a linear ISRM barrier by injecting sodium dithionite into five wells. Well installation and site characterization activities began in spring 1997; the first dithionite injection took place in September 1997. The results of this first injection were monitored through the spring of 1998. The remaining four dithionite injections were carried out in May through July of 1998.These five injections created a reduced zone in the Hanford unconfined aquifer approximately 150 feet in length (perpendicular to groundwater flow) and 50 feet wide. The reduced zone extended over the thickness of the unconfined zone. Analysis of post-emplacement groundwater samples showed concentrations of chromate, in the reduced zone decreased from approximately 1.0 mg/L before the tests to below analytical detection limits (<0.007 mg/L). Chromate concentrations also declined in downgradient monitoring wells to as low as 0.020 mg/L. These data, in addition to results from pre-test reducible iron characterization, indicate the barrier should be effective for 20 to 25 years. The 100-D Area ISRM barrier is being expanded to a length of up to 2,300 ft to capture a larger portion of the chromate plume.

  8. Modeling and design of a multichannel chromatic aberration compensated imaging system

    Science.gov (United States)

    Belay, Gebirie Y.; Ottevaere, Heidi; Vervaeke, Michael; Van Erps, Jürgen; Thienpont, Hugo

    2015-09-01

    Conventional multichannel imaging systems comprise of many optical channels having similar imaging properties, namely field-of-view (FOV) and angular resolution/magnification. We demonstrated that the different optical channels can be designed such that each optical channel captures a different FOV and angular resolution compared to its neighboring channels. We designed and experimentally demonstrated a three-channel multiresolution imaging system where the first optical channel has the narrowest FOV (7°) and highest angular resolution (0.0096°) and the third optical channel has the widest FOV (80°) and lowest angular resolution (0.078°)1. The second optical channel has intermediate properties. The performance of the demonstrated three-channel imaging system however was affected by chromatic aberrations as it was designed for a single wavelength of 587.6 nm. The first optical channel was largely influenced by longitudinal chromatic aberration while the third channel by lateral chromatic aberration. Therefore, we have replaced the aspherical refractive lenses by hybrid lenses, which contain diffractive structures on top of their refractive surfaces, in the three-channel multiresolution imaging system to reduce its chromatic aberrations. The performance of the three channels with hybrid lenses is compared with those of the corresponding channels without hybrid lenses. The longitudinal color aberration of the first optical channel has been reduced from 1.7 mm to 0.2 mm; whereas the lateral color aberration of the third optical channel has been reduced from 250 μm to 14 μm. In conclusion, the hybrid lenses have reduced the chromatic aberrations of the three channels and extended the operating spectral range of the imaging system in the visible wavelength range.

  9. Assessing chromate availability in tropical ultramafic soils using isotopic exchange kinetics

    Energy Technology Data Exchange (ETDEWEB)

    Garnier, Jeremie; Quantin, Cecile [Univ. Paris Sud CNRS, Orsay (France); Echevarria, Guillaume [ENSAIA-INPL-INRA, Vandoeuvre-les-Nancy (France); Becquer, Thierry [IRD - Univ. Paris VI and XII, Montpellier (France)

    2009-10-15

    Background, aim, and scope The presence of labile chromate in the soils is an environmental problem because of its high toxicity. The isotopic exchange kinetics (IEK) methods have been shown to be a useful tool to measure the phytoavailability of major (P, K) and trace elements (Cd, Zn, Ni, Pb) in soils. This study focused on the potential of applying IEK for chromate to characterize its availability in two tropical ultramafic Ferralsols. Materials and methods Two Ferralsols (NIQ II and NIQ III) of the ultramafic complex of Niquelandia (Goias, Brazil), known to have a high content of extractable chromate, were investigated. We adapted IEK for chromate in order to distinguish different pools of available chromate according to their rate of exchange kinetic. Results The extractable Cr(III) ranged from 9 to 132 mg kg{sup -1}, whereas extractable Cr(VI) ranged from 64 to 1,014 mg kg{sup -1}. The intensity factor, i.e., concentration of soluble Cr, ranged from 78 to 231 {mu}g L{sup -1} in profile NIQ II and from 6 to 141 {mu}g L{sup -1} in profile NIQ III. The highest concentrations were found in both topsoils and in the NIQ II-5 horizon. Most of the Cr(VI) was labile in short (E{sub 0-1} {sub min}) or medium-term (E{sub 1} {sub min-24} {sub h}) in both soils. The E{sub 0-1} {sub min} and E{sub 1} {sub min-24} {sub h} represented 39 to 83% of labile Cr (VI) in NIQ II and 69 to 80% in NIQ III. A high quantity of Cr(VI) was thus extremely labile and highly available, particularly in NIQ II. Moreover, both soils had a high buffering capacity of soluble Cr(VI) by labile pools. (orig.)

  10. Competitive sorption and diffusion of chromate and sulphate in a flow system with goethite in gel beads.

    Science.gov (United States)

    van Beinum, Wendy; Meeussen, Johannes C L; van Riemsdijk, Willem H

    2006-08-10

    Column experiments and model simulations were employed to evaluate the processes involved in multicomponent solute transport in a system with heterogeneous flow. Column experiments were performed with goethite embedded in polyacrylamide gel beads. The gel forms an immobile water region that can be accessed by diffusion. A two-region transport model with diffusion into spheres was combined with a surface complexation model to predict reactive transport in the goethite-gel bead system. Chromate and sulphate breakthrough curves were measured in a set of transport experiments, along with corresponding changes in the pH of the effluent. Sorption and transport of sulphate and chromate in separate columns were predicted from independently measured sorption parameters. The model overestimated the pH changes in the effluent, possibly because of proton buffering by the polyacrylamide gel. The effect of competitive sorption on transport was examined in experiments with both anions present. The model predicted the effect of competition very well in a system initially equilibrated with sulphate, followed by infiltration with chromate. However, when sulphate was infiltrated after equilibration with chromate, chromate desorption and sulphate adsorption were clearly overestimated by the transport model. The exchange between the more strongly bound chromate and the sulphate added subsequently may be too slow to cause a substantial chromate peak in the effluent. This suggests that the local equilibrium assumption was not applicable in this case.

  11. Simultaneous and independent adaptive correction of spherical and chromatic aberration using an electron mirror and lens combination.

    Science.gov (United States)

    Fitzgerald, J P S; Word, R C; Könenkamp, R

    2012-04-01

    We present a theoretical analysis of an electrostatic triode mirror combined with an einzel lens for the correction of spherical and chromatic aberration. We show that this device adaptively corrects spherical and chromatic aberration simultaneously and independently. Chromatic aberration can be compensated over a relative range of -38% to +100%, and spherical aberration over ±100% range. We compare the analytic calculation with a numerical simulation and show that the two descriptions agree to within 5% in the relevant operating regime of the device.

  12. METHOD OF SOFTWARE-BASED COMPENSATION OF TECHNOLOGICAL VARIATION IN CHROMATICITY COORDINATES OF LCD PANELS

    Directory of Open Access Journals (Sweden)

    I. O. Zharinov

    2015-05-01

    Full Text Available Subject of research. The problem of software-based compensation of technological variation in chromaticity coordinates of liquid crystal panels is considered. A method of software-based compensation of technological variation in chromaticity coordinates is proposed. The method provides the color reproduction characteristics of the series-produced samples on-board indication equipment corresponding to the sample equipment, which is taken as the standard. Method. Mathematical calculation of the profile is performed for the given model of the liquid crystal panel. The coefficients that correspond to the typical values of the chromaticity coordinates for the vertices of the triangle color coverage constitute a reference mathematical model of the plate LCD panel from a specific manufacturer. At the stage of incoming inspection the sample of the liquid crystal panel, that is to be implemented within indication equipment, is mounted on the lighting test unit, where Nokia-Test control is provided by the formation of the RGB codes for display the image of a homogeneous field in the red, green, blue and white. The measurement of the (x,y-chromaticity coordinates in red, green, blue and white colors is performed using a colorimeter with the known value of absolute error. Instead of using lighting equipment, such measurements may be carried out immediately on the sample indication equipment during customizing procedure. The measured values are used to calculate individual LCD-panel profile coefficients through the use of Grassman's transformation, establishing mutual relations between the XYZ-color coordinates and RGB codes to be used for displaying the image on the liquid crystal panel. The obtained coefficients are to be set into the memory of the graphics controller together with the functional software and then used for image displaying. Main results. The efficiency of the proposed method of software-based compensation for technological variation of

  13. Chromate Reductase YieF from Escherichia coli Enhances Hexavalent Chromium Resistance of Human HepG2 Cells

    Directory of Open Access Journals (Sweden)

    Xuan Liu

    2015-05-01

    Full Text Available Hexavalent chromium (Cr(VI is a serious environmental pollutant and human toxicant. Mammalian cells are very sensitive to chromate as they lack efficient chromate detoxifying strategy, e.g., chromate-reducing genes that are widely present in prokaryotes. To test whether introduction of prokaryotic chromate-reducing gene into mammalian cells could render higher chromate resistance, an Escherichia coli chromate-reducing gene yieF was transfected into human HepG2 cells. The expression of yieF was measured in stably transfected cells HepG2-YieF by quantitative RT-PCR and found up-regulated by 3.89-fold upon Cr(VI induction. In chromate-reducing ability test, HepG2-YieF cells that harbored the reductase showed significantly higher reducing ability of Cr(VI than HepG2 control cells. This result was further supported by the evidence of increased Cr(VI-removing ability of crude cell extract of HepG2-YieF. Moreover, HepG2-YieF demonstrated 10% higher viability and decreased expression of GSH synthesizing enzymes under Cr(VI stress. Subcellular localization of YieF was determined by tracing GFP-YieF fusion protein that was detected in both nucleus and cytoplasm by laser confocal microscopy. Altogether, this study successfully demonstrated that the expression of a prokaryotic Cr(VI-reducing gene yieF endowed mammalian cell HepG2 with enhanced chromate resistance, which brought new insight of Cr(VI detoxification in mammalian cells.

  14. Mutations in FMN Binding Pocket Diminish Chromate Reduction Rates for Gh-ChrR Isolated from Gluconacetobacter hansenii

    Energy Technology Data Exchange (ETDEWEB)

    Khaleel, Janin A.; Gong, Chunhong; Zhang, Yanfeng; Tan, Ruimin; Squier, Thomas C.; Jin, Hongjun

    2013-06-01

    A putative chromate ion binding site was identified proximal to a rigidly bound FMN from electron densities in the crystal structure of the quinone reductase from Gluconacetobacter hansenii (Gh-ChrR) (3s2y.pdb). To clarify the location of the chromate binding site, and to understand the role of FMN in the NADPH-dependent reduction of chromate, we have expressed and purified four mutant enzymes involving the site-specific substitution of individual side chains within the FMN binding pocket that form non-covalent bonds with the ribityl phosphate (i.e., S15A and R17A in loop 1 between β1 sheet and α1 helix) or the isoalloxanzine ring (E83A or Y84A in loop 4 between the β3 sheet and α4 helix). Mutations that selectively disrupt hydrogen bonds between either the N3 nitrogen on the isoalloxanzine ring (i.e., E83) or the ribitylphos- phoate (i.e., S15) respectively result in 50% or 70% reductions in catalytic rates of chromate reduction. In comparison, mutations that disrupt π-π ring stacking interactions with the isoal-loxanzine ring (i.e., Y84) or a salt bridge with the ribityl phosphate result in 87% and 97% inhibittion. In all cases there are minimal alterations in chromate binding affinities. Collectively, these results support the hypothesis that chromate binds proximal to FMN, and implicate a structural role for FMN positioning for optimal chromate reduction rates. As side chains proximal to the β3/α4 FMN binding loop 4 contribute to both NADH and metal ion binding, we propose a model in which structural changes around the FMN binding pocket couples to both chromate and NADH binding sites.

  15. Oxalic acid as an assisting agent for the electrodialytic remediation of chromated copper arsenate treated timber waste

    DEFF Research Database (Denmark)

    Ribeiro, Alexandra B.; Mateus, Eduardo P.; Ottosen, Lisbeth M.

    1999-01-01

    The electrodialytic process is proposed as a technique for the remediation of chromated copper arsenate treated timber waste, using oxalic acid as assisting agent. The method prowed succesfull 93% Cu, 95% Cr and 99% As was removed from the timber.......The electrodialytic process is proposed as a technique for the remediation of chromated copper arsenate treated timber waste, using oxalic acid as assisting agent. The method prowed succesfull 93% Cu, 95% Cr and 99% As was removed from the timber....

  16. Demonstration and Validation of a Replacement Alternative to the Chromate Wash Primer DOD-P-15328D

    Science.gov (United States)

    2006-04-01

    system. The current wash primer is a low-solids, solvent-based polyvinyl butyral that contains phosphoric acid and zinc chromate that promotes adhesion...prior to the application of an epoxy primer/polyurethane topcoat CARC system. The current wash primer is a low-solids, solvent-based polyvinyl ... butyral that contains phosphoric acid and zinc chromate that promotes adhesion and minimizes corrosion. This coating contains large amounts of volatile

  17. Single bunch transverse instability in a circular accelerator with chromaticity and space charge

    CERN Document Server

    Balbekov, V

    2015-01-01

    Transverse instability of a bunch in a circular accelerator is elaborated in this paper. New tree-modes model is proposed and developed to describe the most unstable modes of the bunch. The model includes chromaticity and space charge, and can be used with any bunch and wake forms. Dispersion relation for the bunch eigentunes is obtained in form of a third-order algebraic equation. Known head-tail and TMCI modes appear as the ultimate cases which are distinctly bounded at zero chromaticity only. It is shown that the instability parameters depend only slightly on the bunch model but are rather sensitive to the wake shape. Resistive wall wake is considered in detail including a comparison of single and collective effects. It is shown that space charge influence depends on sign of the wake function enhancing the stability with negative one.

  18. Thermal treatment of solid waste in view of recycling: Chromate and molybdate formation and leaching behaviour.

    Science.gov (United States)

    Verbinnen, Bram; Billen, Pieter; Vandecasteele, Carlo

    2014-06-01

    Elevated Cr and Mo concentrations are often found in leachates of thermally treated solid waste, but there is no general explanation for this so far. Therefore, we studied the leaching behaviour after thermal treatment as a function of heating temperature and residence time for two types of solid waste: contaminated sludge and bottom ash from municipal solid waste incineration. The leaching behaviour of both waste streams was compared with experiments on synthetic samples, allowing deduction of a general mechanism for Cr and Mo leaching. Cr and Mo showed a similar leaching behaviour: after an initial increase, the leaching decreased again at higher temperatures. Oxidation of these elements from their lower oxidation states to chromate and molybdate at temperatures up to 600 °C was responsible for the increased leaching. At higher temperatures, both Mo and Cr leaching decreased again owing to the formation of an amorphous phase, incorporating the newly formed chromate and molybdate salts, which prevents them from leaching.

  19. Design of macro-filter-lens with simultaneous chromatic and geometric aberration correction.

    Science.gov (United States)

    Prasad, Dilip K; Brown, Michael S

    2014-01-01

    A macro-filter-lens design that can correct for chromatic and geometric aberrations simultaneously while providing for a long focal length is presented. The filter is easy to fabricate since it involves two spherical surfaces and a planar surface. Chromatic aberration correction is achieved by making all the rays travel the same optical distance inside the filter element (negative meniscus). Geometric aberration is corrected for by the lens element (plano-convex), which makes the output rays parallel to the optic axis. This macro-filter-lens design does not need additional macro lenses and it provides an inexpensive and optically good (aberration compensated) solution for macro imaging of objects not placed close to the camera.

  20. Low-Beta Insertions inducing Chromatic Aberrations in Storage Rings and their Local and Global Correction

    CERN Document Server

    Fartoukh, S

    2010-01-01

    The chromatic aberrations induced by low-β insertions can seriously limit the performance of circular colliders. The impact is twofold: (1) a substantial off-momentum beta-beating wave traveling around the ring and leading to a net reduction of the mechanical aperture of the low-beta quadrupoles but also impacting on the hierarchy of the collimator and protection devices of the machine, (2) a huge non-linear chromaticity which, when combined with the magnetic imperfections of the machine, could substantially reduce the momentum acceptance of the ring by pushing slightly off-momentum particles towards non-linear resonances. These effects will be analyzed and illustrated in the framework of the LHC insertions upgrade Phase I [1] and a strategy for correction will be developed, requiring a deep modification of the LHC overall optics.

  1. Three dimensional analysis of chromatic aberration in diffractive elements with extended depth of focus.

    Science.gov (United States)

    Mas, D; Espinosa, J; Perez, J; Illueca, C

    2007-12-24

    The paper presents the polychromatic analysis of two diffractive optical elements with extended depth of focus: the linear axicon and the light sword optical element. Chromatic aberration produces axial displacement of the focal segment line. Thus, we explore the possibility of extending the focal depth of these elements to permit superposition of the chromatic foci. In the case of an axicon, we achieve an achromatic zone where focusing is produced. In the case of the light sword element, we show that the focusing segment is out of axis. Therefore a superposition of colors is produced, but not on axis overlapping. Instead, three colored and separated foci are simultaneously obtained in a single plane. Three dimensional structures of the propagated beams are analyzed in order to provide better understanding of the properties and applications of such elements.

  2. Investigating the influence of chromatic aberration and optical illumination bandwidth on fundus imaging in rats

    Science.gov (United States)

    Li, Hao; Liu, Wenzhong; Zhang, Hao F.

    2015-10-01

    Rodent models are indispensable in studying various retinal diseases. Noninvasive, high-resolution retinal imaging of rodent models is highly desired for longitudinally investigating the pathogenesis and therapeutic strategies. However, due to severe aberrations, the retinal image quality in rodents can be much worse than that in humans. We numerically and experimentally investigated the influence of chromatic aberration and optical illumination bandwidth on retinal imaging. We confirmed that the rat retinal image quality decreased with increasing illumination bandwidth. We achieved the retinal image resolution of 10 μm using a 19 nm illumination bandwidth centered at 580 nm in a home-built fundus camera. Furthermore, we observed higher chromatic aberration in albino rat eyes than in pigmented rat eyes. This study provides a design guide for high-resolution fundus camera for rodents. Our method is also beneficial to dispersion compensation in multiwavelength retinal imaging applications.

  3. Low-Beta insertions inducing chromatic aberrations in storage rings and their local and global correction

    CERN Document Server

    Fartoukh, S

    2010-01-01

    The chromatic aberrations induced by low-β insertions can seriously limit the performance of circular colliders. The impact is twofold: (1) a substantial off-momentum beta-beating wave traveling around the ring and leading to a net reduction of the mechanical aperture of the lowbeta quadrupoles but also impacting on the hierarchy of the collimator and protection devices of the machine, (2) a huge non-linear chromaticity which, when combined with the magnetic imperfections of the machine, could substantially reduce the momentum acceptance of the ring by pushing slightly off-momentum particles towards non-linear resonances. These effects will be analyzed and illustrated in the framework of the LHC insertions upgrade Phase I [1] and a strategy for correction will be developed, requiring a deep modification of the LHC overall optics.

  4. Spectral switches of partially coherent light focused by a filter-lens system with chromatic aberration.

    Science.gov (United States)

    Pu, Jixiong; Cai, Chao; Nemoto, Shojiro

    2004-06-01

    It is shown that when partially coherent polychromatic light is focused by a filter-lens system with chromatic aberration, a spectral shift exists in the focused field, and a spectral switch that is defined as a sharp transition of the spectral shift also takes place at some positions of the focused field. The influence of the chromatic aberration of the lens, the coherence of the partially coherent light in the filter (a circular aperture), the radius of the aperture, and the spectral width of the partially coherent light in the aperture on the spectral shift and the spectral switch are investigated in detail. The numerical results show that these parameters affect the spectral shift and the spectral switch significantly. Potential applications of the spectral shift and the spectral switch of the partially coherent light are discussed.

  5. Chromated copper arsenate–treated wood: a potential source of arsenic exposure and toxicity in dermatology

    Directory of Open Access Journals (Sweden)

    Amy Yuntzu-Yen Chen, MD

    2016-03-01

    Full Text Available Arsenic-contaminated drinking water presents a serious health hazard in certain geographic locations around the world. Chromated copper arsenate, a pesticide and preservative that was used to pressure treat residential lumber in the United States beginning in the 1940s and was banned by the Environmental Protection Agency in 2003, poses a potential source of arsenic exposure and toxicity. In this study, we review the clinical manifestations of arsenic intoxication with the focus on dermatologic manifestations. Dermatologists should be aware that although chromated copper arsenate-treated wood for residential use was banned in 2003, the exposure risk remains. Long-term follow up is necessary to detect arsenic induced cutaneous and visceral malignancy in patients with history of arsenic exposure.

  6. The detection of various color combinations under different chromatic ambient illuminations.

    Science.gov (United States)

    Neri, D F; Luria, S M; Kobus, D A

    1986-06-01

    Our purpose was to reveal the effects of ambient illumination color and various foreground/background color pairings on a choice reaction time task performed on a color CRT. Six men and two women with normal color vision served as observers in a four-alternative forced choice procedure. A small (18' visual angle) colored circle appeared in the center of one of the unmarked quadrants of the screen. The observer's task was to respond as quickly as possible to this target by pressing one of four buttons corresponding to its location. We found that target colors that were opponent to the background colors were most quickly detected. Detection was enhanced by maximizing both brightness and chromatic contrast, but brightness contrast was much more effective. Chromatic ambient lighting which was a log unit dimmer than the target luminance had no effect on performance.

  7. Discrimination of luminance and chromaticity differences by dichromatic and trichromatic monkeys.

    Science.gov (United States)

    Jacobs, G H

    1990-01-01

    Dichromatic and trichromatic representatives from two genera of platyrrhine monkeys that show widespread color vision polymorphism (Saguinus--tamarins, Saimiri--squirrel monkeys) were tested for their abilities to make increment-threshold and flicker discriminations based on luminance and chromaticity differences. The details of these tests were arranged to attempt to emphasize the relative contributions to visual behavior of non-opponent and spectrally-opponent neural mechanisms. The results indicate that dichromatic and trichromatic monkeys differ only trivially on tests where performance is based on the contributions of non-opponent mechanisms, that the contribution of spectrally opponent mechanisms to the "brightness signal" is very similar in trichromatic and dichromatic monkeys, and that in increment-threshold discriminations where there are both chromaticity and luminance cues some test wavelengths yield superior performance for trichromats while others appear to favor the dichromat.

  8. Psychophysical Evaluation of Achromatic and Chromatic Vision of Workers Chronically Exposed to Organic Solvents

    Directory of Open Access Journals (Sweden)

    Eliza Maria da Costa Brito Lacerda

    2012-01-01

    Full Text Available The purpose of this paper was to evaluate achromatic and chromatic vision of workers chronically exposed to organic solvents through psychophysical methods. Thirty-one gas station workers (31.5 ± 8.4 years old were evaluated. Psychophysical tests were achromatic tests (Snellen chart, spatial and temporal contrast sensitivity, and visual perimetry and chromatic tests (Ishihara's test, color discrimination ellipses, and Farnsworth-Munsell 100 hue test—FM100. Spatial contrast sensitivities of exposed workers were lower than the control at spatial frequencies of 20 and 30 cpd whilst the temporal contrast sensitivity was preserved. Visual field losses were found in 10–30 degrees of eccentricity in the solvent exposed workers. The exposed workers group had higher error values of FM100 and wider color discrimination ellipses area compared to the controls. Workers occupationally exposed to organic solvents had abnormal visual functions, mainly color vision losses and visual field constriction.

  9. The Coated-Wire Ion Selective Electrode (CWISE of Chromate Using PVC-Membrane Based on Chitosan as A Carrier

    Directory of Open Access Journals (Sweden)

    Dedeh Kurniasih

    2012-10-01

    Full Text Available A coated-wire ion selective electrode (CWISE based on chitosan as a carrier for detection of chromate, was developed. CWISE has easy measurement for field analysis, good selectivity and sensitivity. The CWISE’s membrane consist of mixture an active material of chitosan, aliquat 336-chromate, polyvinylchloride (PVC and dioctylphtalate (DOP as plasticizer = 4:0.5:35:60.5 (% w/w dissolved in tetrahydrofuran (THF solvent (1:3 w/v. The electrode exhibited a good Nernstian slope of 29.77±0.03 mV/decade and a linear concentration range from 10-6 to 10-1 M for chromate. The limit of detection was 1.862 x 10-6 M. It had response time of 20 – 40 sec, and could be used for 49 days. This chromate selective-electrode was found more selective towards the chromate ion than other anions, useable in pH range of 5.0 – 9.0 and temperature of 20 – 50 oC. It was applied as an electrode for direct determination of chromate in water samples and their result compared to standard spectrophotometric method.

  10. Chromatic error correction of diffractive optical elements at minimum etch depths

    Science.gov (United States)

    Barth, Jochen; Gühne, Tobias

    2014-09-01

    The integration of diffractive optical elements (DOE) into an optical design opens up new possibilities for applications in sensing and illumination. If the resulting optics is used in a larger spectral range we must correct not only the chromatic error of the conventional, refractive, part of the design but also of the DOE. We present a simple but effective strategy to select substrates which allow the minimum etch depths for the DOEs. The selection depends on both the refractive index and the dispersion.

  11. INFLUENCE OF CHROMATIC DISPERSION, DISPERSION SLOPE, DISPERSION CURVATURE ON MICROWAVE GENERATION USING TWO CASCADE MODULATORS

    OpenAIRE

    Mandeep Singh; S.K. Raghuwanshi

    2013-01-01

    This work presents a theoretical study of harmonic generation of microwave signals after detection of a modulated optical carrier in cascaded two electro-optic modulators. Dispersion is one of the major limiting factors for microwave generation in microwave photonics. In this paper, we analyze influence of chromatic dispersion, dispersion slope, dispersion curvature on microwave generation using two cascaded MZMs and it has been found that output intensity of photodetector reduces when disper...

  12. Seeing red: affect modulation and chromatic color responses on the Rorschach.

    Science.gov (United States)

    Malone, Johanna C; Stein, Michelle B; Slavin-Mulford, Jenelle; Bello, Iruma; Sinclair, S Justin; Blais, Mark A

    2013-01-01

    Psychoanalytic theories suggest that color perception on the Rorschach relates to affective modulation. However, this idea has minimal empirical support. Using a clinical sample, the authors explored the cognitive and clinical correlates of Rorschach color determinants and differences among four affective modulation subtypes: Controlled, Balanced, Under-Controlled, and Flooded. Subtypes were differentiated by measures of affective regulation, reality testing/confusion, and personality traits. Initial support for the relationship of chromatic color response styles and affective modulation was found.

  13. LHC IR upgrade dipole first with chromaticity and dynamic aperture issues

    CERN Document Server

    de Maria, R

    2007-01-01

    A dipole first layout for the LHC interaction region upgrade, while offering a potential reduction of the limitations due the long range beam-beam collisions, charged debris with respect to the quadrupole first layout, presents an enhancement of the chromatic and geometric aberration due large values in the triplet. These two effects are studied in the following for the dipole first option presented in [1].

  14. Errors in confocal fluorescence ratiometric imaging microscopy due to chromatic aberration.

    Science.gov (United States)

    Lin, Yuxiang; Gmitro, Arthur F

    2011-01-01

    Confocal fluorescence ratiometric imaging is an optical technique used to measure a variety of important biological parameters. A small amount of chromatic aberration in the microscope system can introduce a variation in the signal ratio dependent on the fluorophore concentration gradient along the optical axis and lead to bias in the measurement. We present a theoretical model of this effect. Experimental results and simulations clearly demonstrate that this error can be significant and should not be ignored.

  15. Nitration of phenolic compounds and oxidation of hydroquinones using tetrabutylammonium chromate and dichromate under aprotic conditions

    Indian Academy of Sciences (India)

    Ali Reza Pourali; Arezou Goli

    2011-01-01

    In this work, we have reported a mild, efficient and selective method for the mononitration of phenolic compounds using sodium nitrite in the presence of tetrabutylammonium dichromate (TBAD) and oxidation of hydroquinones to quinones with TBAD in CH2Cl2. Using this method, high yields of nitrophenols and quinones were obtained under neutral aprotic conditions. Tetrabutylammonium chromate (TBAC) can also be used as oxidant at same conditions.

  16. The chromatic number of a graph of girth 5 on a fixed surface

    DEFF Research Database (Denmark)

    Thomassen, Carsten

    2003-01-01

    We prove a color extension result implying that, for every fixed surface S, there are only finitely many 4-color-critical graphs of girth 5 on S. The result is best possible in the sense that there are infinitely many 4-color-critical graphs of girth 4 on S, except when S is the sphere......, As a consequence, the chromatic number of graphs of girth 5 on S can be found in polynomial time....

  17. A zero-free interval for chromatic polynomials of graphs with 3-leaf spanning trees

    DEFF Research Database (Denmark)

    Perrett, Thomas

    2016-01-01

    It is proved that if G is a graph containing a spanning tree with at most three leaves, then the chromatic polynomial of G has no roots in the interval (1,t1], where t1≈1.2904 is the smallest real root of the polynomial (t-2)6+4(t-1)2 (t-2)3-(t-1)4. We also construct a family of graphs containing...

  18. Application of chromatic confocal displacement sensor in measurement of tip clearance

    Science.gov (United States)

    Bi, Chao; Li, Di; Fang, Jianguo; Zhang, Bin

    2016-10-01

    In the field of aeronautics, the tip clearance of rotor exerts a crucial influence on the performance of the aero engine. As defined as the radial distance between the top of the blade and the inner wall of the casing, the tip clearance of too large or small size will adversely affect the normal running of the engine. In order to realize accurate measurement of the tip clearance in a simple way, a non-contact measuring method by the chromatic confocal displacement sensor is proposed in the paper. The sensor possesses the advantages such as small volume, good signal-to-noise ratio, high accuracy and response frequency etc., which make it be widely used in engineering and industry. For testing the performance and potential application of the sensor, a simulation testing platform is established. In the platform, a simulation blisk is installed on the air bearing spindle and a chromatic confocal displacement sensor is fixed on the platform to measure the displacement variation of the blade tip, which can be used to characterize the variation of the tip clearance. In the simulation experiments, both of single and continuous measurement of the tip clearance of the 36 blades on the blisk is executed. As the results of experiments show, the chromatic confocal displacement sensor can meet the requirements of measuring task, in which both of high measuring efficiency and accuracy could be achieved. Therefore, the measuring method proposed in the paper can be utilized in the actual assembling sites of the aero engine.

  19. Chromatic energy filter and characterization of laser-accelerated proton beams for particle therapy

    Science.gov (United States)

    Hofmann, Ingo; Meyer-ter-Vehn, Jürgen; Yan, Xueqing; Al-Omari, Husam

    2012-07-01

    The application of laser accelerated protons or ions for particle therapy has to cope with relatively large energy and angular spreads as well as possibly significant random fluctuations. We suggest a method for combined focusing and energy selection, which is an effective alternative to the commonly considered dispersive energy selection by magnetic dipoles. Our method is based on the chromatic effect of a magnetic solenoid (or any other energy dependent focusing device) in combination with an aperture to select a certain energy width defined by the aperture radius. It is applied to an initial 6D phase space distribution of protons following the simulation output from a Radiation Pressure Acceleration model. Analytical formula for the selection aperture and chromatic emittance are confirmed by simulation results using the TRACEWIN code. The energy selection is supported by properly placed scattering targets to remove the imprint of the chromatic effect on the beam and to enable well-controlled and shot-to-shot reproducible energy and transverse density profiles.

  20. Attentional shifts have little effect on the waveform of the chromatic onset VEP.

    Science.gov (United States)

    Highsmith, Jennifer; Crognale, Michael A

    2010-09-01

    Attention is important for sufficient performance on many visual tasks. This has been shown using achromatic steady-state and pattern-reversal VEPs. Waveform characteristics typically attenuate when attending to distractor stimuli and ignoring VEP stimuli. Chromatic pattern-onset responses have not been tested under conditions of selective attention: as they can be used in clinical settings to test color vision, it is important to know what effects attentional shifts would have on this response. In the present study chromatic pattern-onset VEPs were recorded using spatially divided and spatially contiguous VEP and distractor stimuli. VEP stimuli were 1 cycle.deg(-1) horizontal sine wave patterns (onset mode 100 ms on/400 ms off) used to selectively modulate the L-M and S-(L+M) visual pathways. Distracter stimuli were letters. Subjects attended to either the letters or the gratings and pressed a button when a predetermined stimulus appeared. In Experiment one, VEP and distractor stimuli were superimposed and spatially contiguous. In Experiment two, stimuli were presented to different hemifields. No significant changes in waveform amplitude and latency were found between VEP and distractor attention conditions for either visual pathway. For the chromatic pattern-onset response, modulation of attention does not change responses either with spatially contiguous or spatially separate selective attention manipulations. Consequently, it may not be necessary to monitor attention during recording of this response.

  1. Transient VEP and psychophysical chromatic contrast thresholds in children and adults.

    Science.gov (United States)

    Boon, Mei Ying; Suttle, Catherine M; Dain, Stephen J

    2007-07-01

    It has been found that humans are able to distinguish colours without luminance cues by about 2-4 months of age and that sensitivity to colour difference develops during childhood, reaching a peak around adolescence. This prolonged period of maturation is reflected by improvements in psychophysical threshold measures and by the VEP characteristics of morphology, latency and amplitude. An intra-individual comparison of VEP and psychophysical responses to isoluminant colour stimuli has not been made in children, however, and this was the aim of the present study. VEPs were recorded from 49 subjects, children (age range: 4.8-12.6 years) and adults (age range: 25.7-33.2 years). Psychophysical and VEP thresholds were both measured in 40 of those subjects. Nominally isoluminant chromatic (L-M) sinewave gratings were presented in onset-offset mode and identical stimuli were used for psychophysical and VEP recordings to allow comparison. In agreement with previous reports, morphology of the transient VEP in response to this stimulus differed considerably between children and adults. There was a significant difference between psychophysical and VEP thresholds in children, but not in adults. Our findings support and expand on previous work on maturation of the L-M chromatic pathway and indicate a larger discrepancy between VEP and psychophysical chromatic thresholds in children than in adults.

  2. Lead chromate detected as a source of atmospheric Pb and Cr (VI) pollution

    Science.gov (United States)

    Lee, Pyeong-Koo; Yu, Soonyoung; Chang, Hye Jung; Cho, Hye Young; Kang, Min-Ju; Chae, Byung-Gon

    2016-10-01

    Spherical black carbon aggregates were frequently observed in dust dry deposition in Daejeon, Korea. They were tens of micrometers in diameter and presented a mixture of black carbon and several mineral phases. Transmission electron microscopy (TEM) observations with energy-dispersive X-ray spectroscopy (EDS) and selected area diffraction pattern (SADP) analyses confirmed that the aggregates were compact and included significant amounts of lead chromate (PbCrO4). The compositions and morphologies of the nanosized lead chromate particles suggest that they probably originated from traffic paint used in roads and were combined as discrete minerals with black carbon. Based on Pb isotope analysis and air-mass backward trajectories, the dust in Daejeon received a considerable input of anthropogenic pollutants from heavily industrialized Chinese cities, which implies that long-range transported aerosols containing PbCrO4 were a possible source of the lead and hexavalent chromium levels in East Asia. Lead chromate should be considered to be a source of global atmospheric Pb and Cr(VI) pollution, especially given its toxicity.

  3. Integration of polarization and chromatic cues in the insect sky compass.

    Science.gov (United States)

    el Jundi, Basil; Pfeiffer, Keram; Heinze, Stanley; Homberg, Uwe

    2014-06-01

    Animals relying on a celestial compass for spatial orientation may use the position of the sun, the chromatic or intensity gradient of the sky, the polarization pattern of the sky, or a combination of these cues as compass signals. Behavioral experiments in bees and ants, indeed, showed that direct sunlight and sky polarization play a role in sky compass orientation, but the relative importance of these cues are species-specific. Intracellular recordings from polarization-sensitive interneurons in the desert locust and monarch butterfly suggest that inputs from different eye regions, including polarized-light input through the dorsal rim area of the eye and chromatic/intensity gradient input from the main eye, are combined at the level of the medulla to create a robust compass signal. Conflicting input from the polarization and chromatic/intensity channel, resulting from eccentric receptive fields, is eliminated at the level of the anterior optic tubercle and central complex through internal compensation for changing solar elevations, which requires input from a circadian clock. Across several species, the central complex likely serves as an internal sky compass, combining E-vector information with other celestial cues. Descending neurons, likewise, respond both to zenithal polarization and to unpolarized cues in an azimuth-dependent way.

  4. Psychophysical model of chromatic perceptual transparency based on substractive color mixture.

    Science.gov (United States)

    Faul, Franz; Ekroll, Vebjørn

    2002-06-01

    Variants of Metelli's episcotister model, which are based on additive color mixture, have been found to describe the luminance conditions for perceptual transparency very accurately. However, the findings in the chromatic domain are not that clear-cut, since there exist chromatic stimuli that conform to the additive model but do not appear transparent. We present evidence that such failures are of a systematic nature, and we propose an alternative psychophysical model based on subtractive color mixture. Results of a computer simulation revealed that this model approximately describes color changes that occur when a surface is covered by a filter. We present the results of two psychophysical experiments with chromatic stimuli, in which we directly compared the predictions of the additive model and the predictions of the new model. These results show that the color relations leading to the perception of a homogeneous transparent layer conform very closely to the predictions of the new model and deviate systematically from the predictions of the additive model.

  5. Characterisation of Vranec, Cabernet sauvignon and Merlot wines based on their chromatic and anthocyanin profiles

    Directory of Open Access Journals (Sweden)

    Dimitrovska Maja

    2013-01-01

    Full Text Available Wines of three different grape varieties, Vranec, Cabernet Sauvignon and Merlot were examined for their characterisation in terms of anthocyanin and chromatic profiles, total polyphenols and antioxidant potential. Total, monomeric, polymeric and copigmented anthocyanins were determined by spectrophotometry and the individual anthocyanin compounds were quantified using HPLC-DAD. Chromatic profile was evaluated according to colour density, hue, % red, % blue, % yellow and brilliance (% dA. The established data were submitted to analysis of variance and principle component analysis in order to evaluate their potential for differentiation of wines according to variety and vintage. Vranec wines have shown distinctive characteristics, with the highest content of anthocyanins and values of colour intensity, % red and % dA, compared to the other two studied varieties. The content of petunidin-3-glucoside, peonindin-3-glucoside and anthocyanin acetates were established as possible markers for differentiation of Vranec wines from Cabernet Sauvignon and Merlot wines. However, none of the assayed parameters could be used for differentiation of Cabernet Sauvignon from Merlot wines. It was observed that wine age limits successful classification of the wines by variety according to anthocyanins. The chromatic parameters allowed distinguishing of young (aged up to 1 year from old Vranec wines.

  6. Chromatic Aberration Correction for Atomic Resolution TEM Imaging from 20 to 80 kV

    Science.gov (United States)

    Linck, Martin; Hartel, Peter; Uhlemann, Stephan; Kahl, Frank; Müller, Heiko; Zach, Joachim; Haider, Max.; Niestadt, Marcel; Bischoff, Maarten; Biskupek, Johannes; Lee, Zhongbo; Lehnert, Tibor; Börrnert, Felix; Rose, Harald; Kaiser, Ute

    2016-08-01

    Atomic resolution in transmission electron microscopy of thin and light-atom materials requires a rigorous reduction of the beam energy to reduce knockon damage. However, at the same time, the chromatic aberration deteriorates the resolution of the TEM image dramatically. Within the framework of the SALVE project, we introduce a newly developed Cc/Cs corrector that is capable of correcting both the chromatic and the spherical aberration in the range of accelerating voltages from 20 to 80 kV. The corrector allows correcting axial aberrations up to fifth order as well as the dominating off-axial aberrations. Over the entire voltage range, optimum phase-contrast imaging conditions for weak signals from light atoms can be adjusted for an optical aperture of at least 55 mrad. The information transfer within this aperture is no longer limited by chromatic aberrations. We demonstrate the performance of the microscope using the examples of 30 kV phase-contrast TEM images of graphene and molybdenum disulfide, showing unprecedented contrast and resolution that matches image calculations.

  7. Depth position detection for fast moving objects in sealed microchannel utilizing chromatic aberration.

    Science.gov (United States)

    Lin, Che-Hsin; Su, Shin-Yu

    2016-01-01

    This research reports a novel method for depth position measurement of fast moving objects inside a microfluidic channel based on the chromatic aberration effect. Two band pass filters and two avalanche photodiodes (APD) are used for rapid detecting the scattered light from the passing objected. Chromatic aberration results in the lights of different wavelengths focus at different depth positions in a microchannel. The intensity ratio of two selected bands of 430 nm-470 nm (blue band) and 630 nm-670 nm (red band) scattered from the passing object becomes a significant index for the depth information of the passing object. Results show that microspheres with the size of 20 μm and 2 μm can be resolved while using PMMA (Abbe number, V = 52) and BK7 (V = 64) as the chromatic aberration lens, respectively. The throughput of the developed system is greatly enhanced by the high sensitive APDs as the optical detectors. Human erythrocytes are also successfully detected without fluorescence labeling at a high flow velocity of 2.8 mm/s. With this approach, quantitative measurement for the depth position of rapid moving objects inside a sealed microfluidic channel can be achieved in a simple and low cost way.

  8. Chromatic aberration short-wave infrared spectroscopy: nanoparticle spectra without a spectrometer.

    Science.gov (United States)

    Streit, Jason K; Bachilo, Sergei M; Weisman, R Bruce

    2013-02-05

    A new method is described for measuring the short-wave infrared (SWIR) emission wavelengths of numerous individual nanoparticles without using a dedicated spectrometer. Microscope objectives designed for use at visible wavelengths often show severe axial chromatic aberration in the SWIR. This makes coplanar objects emitting at different SWIR wavelengths appear to focus at different depths. After this aberration has been calibrated for a particular objective lens, the depth at which an emissive nanoparticle appears brightest and best focused can be used to deduce its peak emission wavelength. The method is demonstrated using a dilute, structurally polydisperse sample of single-walled carbon nanotubes deposited onto a microscope slide. Discrete emission centers in this sample have different peak wavelengths corresponding to specific nanotube structural species. A set of images was recorded at stepped focus settings and analyzed to find the sharpest focus depth of each nanotube. The chromatic aberration calibration curve converted these depths into peak emission wavelengths with a spectral resolution better than 3 nm, allowing identification of each nanotube's structure. Chromatic aberration spectroscopy is a practical tool for using existing microscopic equipment to extract significant spectral information on coplanar nanoparticle samples that emit or scatter light.

  9. Breaking the spherical and chromatic aberration barrier in transmission electron microscopy.

    Science.gov (United States)

    Freitag, B; Kujawa, S; Mul, P M; Ringnalda, J; Tiemeijer, P C

    2005-02-01

    Since the invention of transmission electron microscopy (TEM) in 1932 (Z. Physik 78 (1932) 318) engineering improvements have advanced system resolutions to levels that are now limited only by the two fundamental aberrations of electron lenses; spherical and chromatic aberration (Z. Phys. 101 (1936) 593). Since both aberrations scale with the dimensions of the lens, research resolution requirements are pushing the designs to lenses with only a few mm space in the pole-piece gap for the specimen. This is in conflict with the demand for more and more space at the specimen, necessary in order to enable novel techniques in TEM, such as He-cooled cryo electron microscopy, 3D-reconstruction through tomography (Science 302 (2003) 1396) TEM in gaseous environments, or in situ experiments (Nature 427 (2004) 426). All these techniques will only be able to achieve Angstrom resolution when the aberration barriers have been overcome. The spherical aberration barrier has recently been broken by introducing spherical aberration correctors (Nature 392 (1998) 392, 418 (2002) 617), but the correction of the remaining chromatic aberrations have proved to be too difficult for the present state of technology (Optik 57 (1980) 73). Here we present an alternative and successful method to eliminate the chromatic blur, which consists of monochromating the TEM beam (Inst. Phys. Conf. Ser. 161 (1999) 191). We show directly interpretable resolutions well below 1A for the first time, which is significantly better than any TEM operating at 200 KV has reached before.

  10. Accommodation with and without short-wavelength-sensitive cones and chromatic aberration.

    Science.gov (United States)

    Kruger, Philip B; Rucker, Frances J; Hu, Caitlin; Rutman, Hadassa; Schmidt, Nathan W; Roditis, Vasilios

    2005-05-01

    Accommodation was monitored while observers (23) viewed a square-wave grating (2.2 cycles/deg; 0.53 contrast) in a Badal optometer. The grating moved sinusoidally (0.2 Hz) to provide a stimulus between -1.00 D and -3.00 D during trials lasting 40.96 s. There were three illumination conditions: 1. Monochromatic 550 nm light to stimulate long-wavelength-sensitive cones (L-cones) and medium-wavelength-sensitive cones (M-cones) without chromatic aberration; 2. Monochromatic 550 nm light+420 nm light to stimulate long-, medium- and short-wavelength-sensitive cones (S-cones) with longitudinal chromatic aberration (LCA); 3. Monochromatic 550 nm light+420 nm light to stimulate L-, M- and S-cones viewed through an achromatizing lens. In the presence of LCA mean dynamic gain decreased (p=0.0003; ANOVA) and mean accommodation level was reduced (p=0.001; ANOVA). The reduction in gain and increased lag of accommodation in the presence of LCA could result from a blue-yellow chromatic signal or from a larger depth-of-focus.

  11. Chromatic Aberration Correction for Atomic Resolution TEM Imaging from 20 to 80 kV.

    Science.gov (United States)

    Linck, Martin; Hartel, Peter; Uhlemann, Stephan; Kahl, Frank; Müller, Heiko; Zach, Joachim; Haider, Max; Niestadt, Marcel; Bischoff, Maarten; Biskupek, Johannes; Lee, Zhongbo; Lehnert, Tibor; Börrnert, Felix; Rose, Harald; Kaiser, Ute

    2016-08-12

    Atomic resolution in transmission electron microscopy of thin and light-atom materials requires a rigorous reduction of the beam energy to reduce knockon damage. However, at the same time, the chromatic aberration deteriorates the resolution of the TEM image dramatically. Within the framework of the SALVE project, we introduce a newly developed C_{c}/C_{s} corrector that is capable of correcting both the chromatic and the spherical aberration in the range of accelerating voltages from 20 to 80 kV. The corrector allows correcting axial aberrations up to fifth order as well as the dominating off-axial aberrations. Over the entire voltage range, optimum phase-contrast imaging conditions for weak signals from light atoms can be adjusted for an optical aperture of at least 55 mrad. The information transfer within this aperture is no longer limited by chromatic aberrations. We demonstrate the performance of the microscope using the examples of 30 kV phase-contrast TEM images of graphene and molybdenum disulfide, showing unprecedented contrast and resolution that matches image calculations.

  12. Chromate and selenate hydrocalumite solid solutions and their applications in waste treatment

    Institute of Scientific and Technical Information of China (English)

    ZHANG Min; Eric J. Reardon

    2005-01-01

    Hydrocalumite, a calcium aluminate hydrate phase, consists of positively-charged structure units, and is therefore an ideal candidate for accommodating anionic contaminants. In this study, a series of batch experiments was carried out to examine the uptake of chromate and selenate by hydrocalumite. To determine the uptake capacity and long-term stability, hydrocalumite solid solutions between chromate/selenate and hydroxyl were synthesized over a reaction time of more than one year. At a ratio of water to initial solids added (CaAl2O4+CaO) of 75: 1, the maximum uptake capacities were over 77 and 114 g/kg for Cr and Se, respectively.These values are very close to the theoretical uptake capacities of chromate and selenate hydrocalumite end-members (81 and 118 g/kg, respectively). The oxyanion removal efficiency from solution was above 95%. Due to the high uptake capacity and anion removal efficiency of hydrocalumites, their application in wastewater treatment is promising. Hydrocalumites are also important hydration products of cementitious materials and the long-term stability of these phases is of significance for application in solidification/stabilization technology.

  13. Chromatic processing in the anterior optic tubercle of the honey bee brain.

    Science.gov (United States)

    Mota, Theo; Gronenberg, Wulfila; Giurfa, Martin; Sandoz, Jean-Christophe

    2013-01-02

    Color vision in honey bees (Apis mellifera) has been extensively studied at the behavioral level and, to a lesser degree, at the physiological level by means of electrophysiological intracellular recordings of single neurons. Few visual neurons have been so far characterized in the lateral protocerebrum of bees. Therefore, the possible implication of this region in chromatic processing remains unknown. We performed in vivo calcium imaging of interneurons in the anterior optic tubercle (AOTu) of honey bees upon visual stimulation of the compound eye to analyze chromatic response properties. Stimulation with distinct monochromatic lights (ultraviolet [UV], blue, and green) matching the sensitivity of the three photoreceptor types of the bee retina induced different signal amplitudes, temporal dynamics, and spatial activity patterns in the AOTu intertubercle network, thus revealing intricate chromatic processing properties. Green light strongly activated both the dorsal and ventral lobes of the AOTu's major unit; blue light activated the dorsal lobe more while UV light activated the ventral lobe more. Eye stimulation with mixtures of blue and green light induced suppression phenomena in which responses to the mixture were lower than those to the color components, thus concurring with color-opponent processing. These data provide evidence for a spatial segregation of color processing in the AOTu, which may serve for navigation purposes.

  14. The male blue crab, Callinectes sapidus, uses both chromatic and achromatic cues during mate choice.

    Science.gov (United States)

    Baldwin, Jamie; Johnsen, Sönke

    2012-04-01

    In the blue crab, Callinectes sapidus, claw color varies by sex, sexual maturity and individual. Males rely in part on color cues to select appropriate mates, and these chromatic cues may be perceived through an opponent interaction between two photoreceptors with maximum wavelength sensitivities at 440 and 508 nm. The range of color discrimination of this dichromatic visual system may be limited, however, and it is unclear whether male blue crabs are capable of discriminating the natural variations in claw color that may be important in mate choice. By testing males' innate color preferences in binary choice tests between photographs of red-clawed females and six variations of orange-clawed females, we examined both the chromatic (opponent interaction) and achromatic (relative luminance) cues used in male mate choice. Males significantly preferred red-clawed females to orange-clawed females, except when the test colors were similar in both opponency and relative luminance. Our results are unusual in that they indicate that male mate choice in the blue crab is not guided solely by achromatic or chromatic mechanisms, suggesting that both color and intensity are used to evaluate female claw color.

  15. Chromaticity and color saturation of ultraviolet irradiated poly(vinyl alcohol)-anthocyanin coatings

    Science.gov (United States)

    Mat Nor, N. A.; Aziz, N.; Mohd-Adnan, A. F.; Taha, R. M.; Arof, A. K.

    2016-06-01

    The purpose of this paper is to evaluate the chromaticity and color saturation of anthocyanin extraction from fruit pericarps of Ixora siamensis in a poly(vinyl alcohol) (PVA) matrix. The colored PVA matrix was exposed to UV-B irradiation for 93 days at UV intensity of 17.55 lux. Anthocyanin colorant has been extracted using methanol acidified with 0.5% trifluoroacetic acid (TFA). Different concentrations of ferulic acid (FA) (0, 1, 2, 3, 4 and 5 wt.%) have been added to the anthocyanin extractions before mixing with PVA to form a coating system. The PVA-anthocyanin-FA mixtures have been coated on glass slides and kept overnight in the dark for curing before exposure to UV-B irradiation. The FA-free sample undergoes more color degradation compared to samples containing FA. The coating with 2% FA has the most stable color with chromaticity of 41% and color saturation of 0.88 compared to other FA containing coats. The FA-free coat exhibits 29% chromaticity and color saturation of 0.38 at the end of the experiment.

  16. Post-column reaction for simultaneous analysis of chromatic and leuco forms of malachite green and crystal violet by high-performance liquid chromatography with photometric detection

    Science.gov (United States)

    Allen, J.L.; Meinertz, J.R.

    1991-01-01

    The chromatic and leuco forms of malachite green and crystal violet were readily separated and detected by a sensitive and selective high-performance liquid chromatographic procedure. The chromatic and leuco forms of the dyes were separated within 11 min on a C18 column with a mobile phase of 0.05 M sodium acetate and 0.05 M acetic acid in water (19%) and methanol (81%). A reaction chamber, containing 10% PbO2 in Celite 545, was placed between the column and the spectrophotometric detector to oxidize the leuco forms of the dyes to their chromatic forms. Chromatic and leuco malachite green were quantified by their absorbance at 618 nm; and chromatic and leuco Crystal Violet by their absorbance at 588 nm. Detection limits for chromatic and leuco forms of both dyes ranged from 0.12 to 0.28 ng. A linear range of 1 to 100 ng was established for both forms of the dyes.

  17. Corrosion Finishing/Coating Systems for DoD Metallic Substrates Based on Non-Chromate Inhibitors and UV Curable, Zero VOC Materials

    Science.gov (United States)

    2010-08-01

    number of brush or spray 30 deposition cycles. Figure 26. XRD spectra for coatings deposited using three, five, and seven 30 brush cycles...need PPSON-06-04. Chromate Conversion Coating Organic Top Coat Strontium Chromate Primer Metallic Substrate MUV Coating Non-Chromate...degrees) In te ns ity In te ns ity Figure 26. XRD spectra for coatings deposited using three, five, and seven brush cycles, and three and five spray

  18. The Further Results of the Chromatic Uniquenes s of Certain Bipartite Graphs K(m,n)-A

    Institute of Scientific and Technical Information of China (English)

    ZOU Hui-wen; ZHU Zhong-hua

    2008-01-01

    With its comprehensive applicatian in network information engineering (e.g.dynamic spectrum allocation tinder different distance comtraints) and in network combination optimization (e.g.safe storage of deleterious materials),the graphs'cloring theory and chromatic uniqueness theory have been the forward position of graph theory research.The later concerns the equlvaleat classification of graphs with their color polynomials and the determination of uniqueness of some equivalent classification under isomorphism. In this paper,by introducing the concept of chromatic nomality and comparing the manber of partitions of two chromatically equivalent graphs,a general numerical condition guareateeing that bipartite graphs K (m,n)-A (A(∈)E (K(m,n)) and |A|≥2) is chromatically unique was obtained and a lot of chromatic uniquoness graphs of bipartite graphs K (m,n)-A were determined.The results obtained in this paper were general.And the results cover and extend the majority of the relevant results obtained within the world.

  19. Reduction of chromate and carotene-synthesizing activity of selenite-resistant mutants of the yeast Xanthophyllomyces dendrorhous (Phaffia rhodozyma

    Directory of Open Access Journals (Sweden)

    Grzàdka M.

    2009-08-01

    Full Text Available Aim. The yeast P. rhodozyma is a perspective microbial producer of carotenoid pigment astaxanthin with a high antioxidant power. The aim of the work was to study the ability of the selenite-resistant strains of this yeast to reduce chrome(VI compounds, as well as to analyze the relations between synthesis of carotenoids, resistance to selenite and chromate-reducing activity of P. rhodozyma. Methods. The yeast cells were grown at standard conditions for this species. The residual chromate content in cultural liquid was determined colorimetrically using diphenylcarbazide. The carotenoid content was determined after extraction of the pigments from the previously permeabilized cells by organic solvents. Results. The selected selenite-resistant mutants of the yeast P. rhodozyma revealed the different combinations of the phenotypes related with tolerance/sensitivity to chromate and selenite, as well as ability to reduce chromate. Conclusions. The obtained results give reasons for suggesting that pathways of detoxification of chromate and selenite by the yeast P. rhodozyma are different, although run through a common reductive type. The isolated mutant strains would be served as the useful models to study relations between homeostasis of Se and Cr oxyanions and biosynthesis of carotenes.

  20. Frequency-Domain Chromatic Dispersion Equalization Using Overlap-Add Methods in Coherent Optical System

    CERN Document Server

    Xu, Tianhua; Popov, Sergei; Forzati, Marco; Martensson, Jonas; Mussolin, Marco; Li, Jie; Wang, Ke; Zhang, Yimo; Friberg, Ari T

    2016-01-01

    The frequency domain equalizers (FDEs) employing two types of overlap-add zero-padding (OLA-ZP) methods are applied to compensate the chromatic dispersion in a 112-Gbit/s non-return-to-zero polarization division multiplexed quadrature phase shift keying (NRZ-PDM-QPSK) coherent optical transmission system. Simulation results demonstrate that the OLA-ZP methods can achieve the same acceptable performance as the overlap-save method. The required minimum overlap (or zero-padding) in the FDE is derived, and the optimum fast Fourier transform length to minimize the computational complexity is also analyzed.

  1. A Light-Activated Olefin Metathesis Catalyst Equipped with a Chromatic Orthogonal Self-Destruct Function.

    Science.gov (United States)

    Sutar, Revannath L; Levin, Efrat; Butilkov, Danielle; Goldberg, Israel; Reany, Ofer; Lemcoff, N Gabriel

    2016-01-11

    A sulfur-chelated photolatent ruthenium olefin metathesis catalyst has been equipped with supersilyl protecting groups on the N-heterocyclic carbene ligand. The silyl groups function as an irreversible chromatic kill switch, thus decomposing the catalyst when it is irradiated with 254 nm UV light. Therefore, different types of olefin metathesis reactions may be started by irradiation with 350 nm UV light and prevented by irradiation with shorter wavelengths. The possibility to induce and impede catalysis just by using light of different frequencies opens the pathway for stereolithographic applications and novel light-guided chemical sequences.

  2. Theoretical estimates of spherical and chromatic aberration in photoemission electron microscopy.

    Science.gov (United States)

    Fitzgerald, J P S; Word, R C; Könenkamp, R

    2016-01-01

    We present theoretical estimates of the mean coefficients of spherical and chromatic aberration for low energy photoemission electron microscopy (PEEM). Using simple analytic models, we find that the aberration coefficients depend primarily on the difference between the photon energy and the photoemission threshold, as expected. However, the shape of the photoelectron spectral distribution impacts the coefficients by up to 30%. These estimates should allow more precise correction of aberration in PEEM in experimental situations where the aberration coefficients and precise electron energy distribution cannot be readily measured.

  3. Correcting lateral chromatic aberrations in non-monochromatic X-ray microscopy

    Science.gov (United States)

    Falch, Ken Vidar; Detlefs, Carsten; Di Michiel, Marco; Snigireva, Irina; Snigirev, Anatoly; Mathiesen, Ragnvald H.

    2016-08-01

    Lateral chromatic aberration in microscopy based on refractive optics may be reduced significantly by adjustments to the illumination scheme. By taking advantage of a broadened bandwidth illumination, the proposed scheme could open for x-ray microscopy with spatial resolution in the range 150-200 nm at millisecond frame rates. The scheme is readily implemented and is achievable using only standard refractive x-ray lenses, which has the advantage of high efficiency. It also maximizes the transmission and removes the spatial filtering effects associated with absorption in x-ray lenses.

  4. Possibility of decreasing the spherical and chromatic aberrations in plane combined axisymmetric magnetoelectrostatic lenses

    CERN Document Server

    Zhukov, V A; Nesterov, M M

    2001-01-01

    The possibility of decreasing by 6 times the coefficients of both spherical and chromatic aberrations in plane combined axisymmetric lenses in comparison with the purely magnetic lenses is demonstrated. This is provided for by a proper selection of the ratio of the geometric parameters of the electrodes dimensions and pole tags of the combined lens, the electric potentials on its electrodes and the ampere-turns in the excitation coil. Application of the combined lenses may prove to be perspective in the ion and electron projection and microprobe systems

  5. Eye-tracking technology for real-time monitoring of transverse chromatic aberration

    Science.gov (United States)

    Privitera, Claudio M.; Sabesan, Ramkumar; Winter, Simon; Tiruveedhula, Pavan; Roorda, Austin

    2017-01-01

    Objective measurements of transverse chromatic aberration (TCA) between two or more wavelengths with an adaptive optics scanning laser ophthalmoscope (AOSLO) are very accurate, but frequent measurements are impractical in many experimental settings. Here, we demonstrate a pupil-tracker that can accurately measure relative changes in TCA that are caused by small shifts in the pupil relative to the AOSLO imaging beam. Corrections for TCA caused by these shifts improve the measurement of TCA as a function of eccentricity, revealing a strong linear relationship. We propose that pupil tracking be integrated into AOSLO systems where robust and unobtrusive control of TCA is required. PMID:27082330

  6. Effect of ophthalmic filter thickness on predicted monocular dichromatic luminance and chromaticity discrimination.

    Science.gov (United States)

    Richer, S P; Little, A C; Adams, A J

    1984-11-01

    The majority of ophthalmic filters, whether they be in the form of spectacles or contact lenses, are absorbance type filters. Although color vision researchers routinely provide spectrophotometric transmission profiles of filters, filter thickness is rarely specified. In this paper, colorimetric tools and volume color theory are used to show that the color of a filter as well as its physical properties are altered dramatically by changes in thickness. The effect of changes in X-Chrom filter thickness on predicted monocular dichromatic luminance and chromaticity discrimination is presented.

  7. ELECTROPLATED Zn-Ni-SiO2 COMPOSITE COATINGS TREATED WITH A SILANE COUPLING AGENT TO REPLACE CHROMATING

    Institute of Scientific and Technical Information of China (English)

    M. Hino; M. Hiramatsu; K. Murakami; A. Saijo; T. Kanadani

    2005-01-01

    The fixing of a silane coupling agent to Zn-Ni-silica (SiO2) composite coatings was studied for the purpose of developing a coating process as an alternative to chromating. The corrosion resistance of Zn-Ni-silica composite coatings was remarkably improved by the silica nanoparticles in the composite, which were dispersed in the surface of this film. The silane coupling agent formed chemical bonds with the inorganic silica particles during the silane coupling treatment on these composite coatings. The treatment suppressed the formation of white corrosion products to the same extent as chromating, as measured in salt spray tests. It is concluded that treating Zn-Ni-silica composite coatings with silane coupling agents is a viable alternative technique to chromating.

  8. Evaluation of Corrosion Behavior of Galvanized Steel Treated with Conventional Conversion Coatings and a Chromate-Free Organic Inhibitor

    Directory of Open Access Journals (Sweden)

    Laura A. Hernandez-Alvarado

    2012-01-01

    Full Text Available Conventional weight loss tests and both DC and AC electrochemical techniques were used to study if an organic inhibitor containing an alkanolamine salt of a polycarboxylic acid can substitute toxic coatings as chromating and certain phosphating procedures in the protection of galvanized steel. The electrolyte used was a 0.5 M aerated NaCl solution. All tests gave concordant results, indicating that the chromate-free organic inhibitor does protect galvanized steel in this environment, even though the provided protection was less than that of the chromate conversion coating. It was observed that, after a moderate initial attack, the corrosion rate diminishes due to the appearance and growth of passivating corrosion products layers, mainly constituted by zinc hydroxychloride (Zn5(OH8CI2⋅H2O and two varieties of zinc hydroxide, among other crystalline compounds.

  9. Treatment tests for ex situ removal of chromate, nitrate, and uranium (VI) from Hanford (100-HR-3) groundwater. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Beck, M.A.; Duncan, J.B.

    1993-11-15

    This report describes batch and anion exchange column laboratory-scale studies investigating ex situ methods to remove chromate (chromium [VI]), nitrate (NO{sub 3}), and uranium (present as uranyl (uranium [VI]) carbonato anionic species) from contaminated Hanford Site groundwaters. The technologies investigated include chemical precipitation or coprecipitation to remove chromate and uranium, and anion exchange to remove chromate, uranium, and nitrate. The technologies investigated were specified in the 100-HR-3 Groundwater Treatability Test Plan (DOE-RL 1993). The goal of these tests was to determine the best method to remove selected contaminants to below the concentration of the project performance goals. The raw data and observations made during these tests can be found in the Westinghouse Hanford Company (WHC) laboratory notebooks (Beck 1992, Herting 1993). The method recommended for future study is anion exchange with Dowex 21K resin.

  10. Dissociation of equilibrium points for color-discrimination and color-appearance mechanisms in incomplete chromatic adaptation.

    Science.gov (United States)

    Sato, Tomoharu; Nagai, Takehiro; Kuriki, Ichiro; Nakauchi, Shigeki

    2016-03-01

    We compared the color-discrimination thresholds and supra-threshold color differences (STCDs) obtained in complete chromatic adaptation (gray) and incomplete chromatic adaptation (red). The color-difference profiles were examined by evaluating the perceptual distances between various color pairs using maximum likelihood difference scaling. In the gray condition, the chromaticities corresponding with the smallest threshold and the largest color difference were almost identical. In contrast, in the red condition, they were dissociated. The peaks of the sensitivity functions derived from the color-discrimination thresholds and STCDs along the L-M axis were systematically different between the adaptation conditions. These results suggest that the color signals involved in color discrimination and STCD tasks are controlled by separate mechanisms with different characteristic properties.

  11. Fourier transform Raman spectroscopy of sorbed HDTMA and the mechanism of chromate sorption to surfactant-modified clinoptilolite

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, E.J.; Bowman, R.S. [New Mexico Inst. of Mining and Technology, Socorro, NM (United States); Hunter, D.B. [Univ. of Georgia, Aiken, SC (United States). Savannah River Ecology Lab.

    1998-07-01

    Surfactant-modified zeolite (SMZ) has potential use as a sorbent for toxic compounds from contaminated waters, in subsurface permeable barriers, or in ex-situ water treatment systems. The authors examined sorption of the cationic surfactant hexadecyltrimethylammonium bromide (HDTMA) to clinoptilolite zeolite and the subsequent sorption of the chromate anion to surfactant-modified zeolite (SMZ). They used Fourier transform (FT) Raman spectroscopy and batch sorption methods to elucidate the structure of sorbed HDTMA and to determine the mechanisms of chromate sorption. At high HDTMA loading levels (above the zeolite`s external cation exchange capacity, ECEC), the Raman spectra indicated that sorbed HDTMA was similar in conformation to solution micelles and, thus, may contain anion exchange sites. Sorbed HDTMA showed less structuring of tail groups and a decrease in head group hydration. At lower loadings, the sorbed HDTMA tail groups tended to have more disorder, similar to solution monomers. When HDTMA loading rates were greater than 100% of the ECEC, chromate sorbed onto SMZ with near-equivalent Br{sup {minus}} counterion exchange. A peak in the Raman spectrum at 902 cm{sup {minus}1} indicated the presence of sorbed Cr{sub 2}O{sub 7}{sup 2{minus}}, although no bulk solution oligomerized chromate species should have been present at a solution pH of 7. A 30 cm{sup {minus}1} shift in the {nu}{sub 1} peak for sorbed versus solution chromate may indicate the surface-enhanced Lewis acid-base interactions were responsible for some chromate sorption in addition to the predominant anion-exchange mechanism.

  12. Estimating and controlling chromatic aberration losses for two-junction, two-terminal devices in refractive concentrator systems

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, S.R. [National Renewable Energy Lab., Golden, CO (United States); O`Neill, M.J. [ENTECH, Inc., Keller, TX (United States)

    1996-05-01

    Although previous studies have measured and calculated chromatic aberration losses and proposed methods for reducing these by modifying the optics, significant work remains to be done toward understanding how to quantity the losses and how various parameters affect this loss. This paper presents an analytical definition and calculation method for chromatic aberration losses. The effects of sheet resistance of the midlayers of the cell, total irradiance, incident spectrum, cell width, and diode quality factor are studied. A method for measuring the midlayer resistance in finished sells is described.

  13. Chromaticity decay due to superconducting dipoles on the injection plateau of the Large Hadron Collider

    CERN Document Server

    Aquilina, N; Sammut, N; Strzeclzyk, M; Todesco, E

    2012-01-01

    It is well known that in a superconducting accelerator a significant chromaticity drift can be induced by the decay of the sextupolar component of the main dipoles. In this paper we give a brief overview of what was expected for the Large Hadron Collider on the grounds of magnetic measurements of individual dipoles carried out during the production. According to this analysis, the decay time constants were of the order of 200 s: since the injection in the LHC starts at least 30 minutes after the magnets are at constant current, the dynamic correction of this effect was not considered to be necessary. The first beam measurements of chromaticity showed significant decay even after few hours. For this reason, a dynamic correction of decay on the injection plateau was implemented based on beam measurements. This means that during the injection plateau the sextupole correctors are powered with a varying current to cancel out the decay of the dipoles. This strategy has been implemented successfully. A similar pheno...

  14. Fast imaging with inelastically scattered electrons by off-axis chromatic confocal electron microscopy.

    Science.gov (United States)

    Zheng, Changlin; Zhu, Ye; Lazar, Sorin; Etheridge, Joanne

    2014-04-25

    We introduce off-axis chromatic scanning confocal electron microscopy, a technique for fast mapping of inelastically scattered electrons in a scanning transmission electron microscope without a spectrometer. The off-axis confocal mode enables the inelastically scattered electrons to be chromatically dispersed both parallel and perpendicular to the optic axis. This enables electrons with different energy losses to be separated and detected in the image plane, enabling efficient energy filtering in a confocal mode with an integrating detector. We describe the experimental configuration and demonstrate the method with nanoscale core-loss chemical mapping of silver (M4,5) in an aluminium-silver alloy and atomic scale imaging of the low intensity core-loss La (M4,5@840  eV) signal in LaB6. Scan rates up to 2 orders of magnitude faster than conventional methods were used, enabling a corresponding reduction in radiation dose and increase in the field of view. If coupled with the enhanced depth and lateral resolution of the incoherent confocal configuration, this offers an approach for nanoscale three-dimensional chemical mapping.

  15. Effect of Lossy JPEG Compression of an Image with Chromatic Aberrations on Target Measurement Accuracy

    Science.gov (United States)

    Matsuoka, R.

    2014-05-01

    This paper reports an experiment conducted to investigate the effect of lossy JPEG compression of an image with chromatic aberrations on the measurement accuracy of target center by the intensity-weighted centroid method. I utilized six images shooting a white sheet with 30 by 20 black filled circles in the experiment. The images were acquired by a digital camera Canon EOS 20D. The image data were compressed by using two compression parameter sets of a downsampling ratio, a quantization table and a Huffman code table utilized in EOS 20D. The experiment results clearly indicate that lossy JPEG compression of an image with chromatic aberrations would produce a significant effect on measurement accuracy of target center by the intensity-weighted centroid method. The maximum displacements of red, green and blue components caused by lossy JPEG compression were 0.20, 0.09, and 0.20 pixels respectively. The results also suggest that the downsampling of the chrominance components Cb and Cr in lossy JPEG compression would produce displacements between uncompressed image data and compressed image data. In conclusion, since the author consider that it would be unable to correct displacements caused by lossy JPEG compression, the author would recommend that lossy JPEG compression before recording an image in a digital camera should not be executed in case of highly precise image measurement by using color images acquired by a non-metric digital camera.

  16. FORMATION OF CHROMATE CONVERSION COATINGS ON ALUMINUM AND ITS ALLOYS: AN IN SITU XANES STUDY.

    Energy Technology Data Exchange (ETDEWEB)

    SASAKI,K.; ISAACS,H.S.; JAFFCOATE,C.S.; BUCHHAIT,R.; LEGAT,V.; LEE,H.; SRINIVASAMURTHI,V.

    2001-09-02

    We used in situ X-ray adsorption near-edge structure (XANES) to investigate the formation of chromate conversion coatings on pure Al, commercial Al alloys (AA 1100, AA2024, and AA7075), and a series of binary Al-Cu alloys. The method employed a new electrochemical cell that can determine the ratio of hexavalent chromium (Cr(VI)) to total chromium (Cr(total)) speciation in conversion coatings as a function of exposure time to a chromate solution. The spectra showed that the initial Cr(VI)/Cr(total) ratios are greater than later ones for pure Al and AA1100, but not for AA2024 and AA7075. Measurements with Al-Cu alloys demonstrated that the difference observed in AA2024 and AA7075 may not be due to Cu alloying. The proportion of Cr(VI) in the coatings becomes approximately constant after 180 s of exposure for all the specimens examined even though the coatings continue to grow.

  17. Investigating neuromagnetic brain responses against chromatic flickering stimuli by wavelet entropies.

    Directory of Open Access Journals (Sweden)

    Mayank Bhagat

    Full Text Available BACKGROUND: Photosensitive epilepsy is a type of reflexive epilepsy triggered by various visual stimuli including colourful ones. Despite the ubiquitous presence of colorful displays, brain responses against different colour combinations are not properly studied. METHODOLOGY/PRINCIPAL FINDINGS: Here, we studied the photosensitivity of the human brain against three types of chromatic flickering stimuli by recording neuromagnetic brain responses (magnetoencephalogram, MEG from nine adult controls, an unmedicated patient, a medicated patient, and two controls age-matched with patients. Dynamical complexities of MEG signals were investigated by a family of wavelet entropies. Wavelet entropy is a newly proposed measure to characterize large scale brain responses, which quantifies the degree of order/disorder associated with a multi-frequency signal response. In particular, we found that as compared to the unmedicated patient, controls showed significantly larger wavelet entropy values. We also found that Renyi entropy is the most powerful feature for the participant classification. Finally, we also demonstrated the effect of combinational chromatic sensitivity on the underlying order/disorder in MEG signals. CONCLUSIONS/SIGNIFICANCE: Our results suggest that when perturbed by potentially epileptic-triggering stimulus, healthy human brain manages to maintain a non-deterministic, possibly nonlinear state, with high degree of disorder, but an epileptic brain represents a highly ordered state which making it prone to hyper-excitation. Further, certain colour combination was found to be more threatening than other combinations.

  18. A Study of Gravitational Lens Chromaticity with the Hubble Space Telescope

    CERN Document Server

    Muñoz, José A; Kochanek, Christopher S; Falco, Emilio; Mosquera, Ana María

    2011-01-01

    We report Hubble Space Telescope observations of 6 gravitational lenses with the Advanced Camera for Surveys. We measured the flux ratios between the lensed images in 6 filters from 8140\\AA\\ to 2200\\AA. In 3 of the systems, HE0512$-$3329, B1600+434, and H1413+117, we were able to construct UV extinction curves partially overlapping the 2175\\AA\\ feature and characterize the properties of the dust relative to the Galaxy and the Magellanic Clouds. In HE1104$-$1804 we detect chromatic microlensing and use it to study the physical properties of the quasar accretion disk. For a Gaussian model of the disk $\\exp(-r^2/2 r_s^2)$, scaling with wavelength as $r_s \\propto \\lambda^p$, we estimate $r_s(\\lambda3363)=4^{+4}_{-2}$ ($7\\pm 4$) light-days and $p=1.1\\pm 0.6$ ($1.0\\pm 0.6$) for a logarithmic (linear) prior on $r_s$. The remaining two systems, FBQ0951+2635 and SBS1520+530, yielded no useful estimates of extinction or chromatic microlensing.

  19. Chromatic characterization of ion-exchanged glass binary phase plates for mode-division multiplexing.

    Science.gov (United States)

    Prieto-Blanco, Xesús; Montero-Orille, Carlos; Moreno, Vicente; Mateo, Eduardo F; Liñares, Jesús

    2015-04-10

    Mode-division multiplexing (MDM) in few-mode fibers is regarded as a promising candidate to increase optical network capacity. A fundamental element for MDM is a modal transformer to LP modes which can be implemented in a free-space basis by using multiregion phase plates, that is, LP plates. Likewise, several wavelengths have to be used due to wavelength multiplexing purposes, optical amplification tasks, and so on. In this work we show that efficient monolithic binary phase plates for different wavelengths can be fabricated by ion-exchange in glass and used for MDM tasks. We introduce an optical characterization method of the chromatic properties of such phase plates which combines the inverse Wentzel-Kramers-Brillouin (IWKB) together with Mach-Zehnder and Michelson-based interferometric techniques. The interferometric method provides a measurement of the phase step for several wavelengths, which characterizes the chromatic properties of the phase plate. Consequently, it is shown that the IWKB method allows us to design and characterize the phase plates in an easy and fast way.

  20. The Forel-Ule Scale Revisited Spectrally: Preparation Protocol, Transmission Measurements and Chromaticity

    Science.gov (United States)

    Novoa, S.; Wernand, M. R.; van der Woerd, H. J.

    2013-08-01

    The Forel-Ule colour comparator scale has been applied globally and intensively by oceanographers and limnologists since the 19th century,providing one of the oldest oceanographic data sets. Present and future Forel-Ule classifications of global oceanic, coastal and continentalwaters can facilitate the interpretation of these long-term ocean colour data series and provide a connection between the present and thepast that will be valuable for climate-related studies. Within the EC-funded project CITLOPS (Citizens' Observatory for Coast and Ocean Optical Monitoring), with its main goal to empower endusers,willing to employ community-based environmental monitoring, our aim is to digitalize the colours of the Forel-Ule scale to establishthe colour of natural waters through smartphone imaging. The objective of this study was to reproduce the Forel-Ule scale following theoriginal recipes, measure the transmission of the solutions and calculate the chromaticity coordinates of the scale as Wernand and Vander Woerd did in 2010, for the future development of a smartphone application. Some difficulties were encountered when producing thescale, so a protocol for its consistent reproduction was developed and is described in this study. Recalculated chromaticity coordinates arepresented and compared to measurements conducted by former scientists. An error analysis of the spectral and colourimetric informationshows negligible experimental errors.

  1. Differences in Brain Hemodynamics in Response to Achromatic and Chromatic Cards of the Rorschach

    Science.gov (United States)

    2016-01-01

    Abstract. In order to investigate the effects of color stimuli of the Rorschach inkblot method (RIM), the cerebral activity of 40 participants with no history of neurological or psychiatric illness was scanned while they engaged in the Rorschach task. A scanned image of the ten RIM inkblots was projected onto a screen in the MRI scanner. Cerebral activation in response to five achromatic color cards and five chromatic cards were compared. As a result, a significant increase in brain activity was observed in bilateral visual areas V2 and V3, parietooccipital junctions, pulvinars, right superior temporal gyrus, and left premotor cortex for achromatic color cards (p < .001). For the cards with chromatic color, significant increase in brain activity was observed in left visual area V4 and left orbitofrontal cortex (p < .001). Furthermore, a conjoint analysis revealed various regions were activated in responding to the RIM. The neuropsychological underpinnings of the response process, as described by Acklin and Wu-Holt (1996), were largely confirmed. PMID:28239255

  2. Multifocus optical-resolution photoacoustic microscopy using stimulated Raman scattering and chromatic aberration.

    Science.gov (United States)

    Hajireza, Parsin; Forbrich, Alexander; Zemp, Roger J

    2013-08-01

    In this Letter, multifocus optical-resolution photoacoustic microscopy is demonstrated using wavelength tuning and chromatic aberration for depth scanning. Discrete focal zones at several depth locations were created by refocusing light from a polarization-maintaining single-mode fiber pumped by a nanosecond fiber laser. The fiber and laser parameters were chosen to take advantage of stimulated Raman scattering (SRS) in the fiber to create a multiwavelength output that could then be bandpass filtered. The collimator lens and objective lens are chosen to take advantage of chromatic aberration in which each generated SRS wavelength peak focuses at a slightly different depth. The maximum amplitude of photoacoustic signals is mapped to form C-scan images. Additionally, all wavelength peaks fired simultaneously offers improved depth-of-field structural imaging at the cost of slight degradation of mainlobe-to-sidelobe ratios. Wavelength-tuned depth scanning over more than 440 μm is demonstrated, significantly greater than the ~100 μm depth of field predicted from our focused Gaussian beams. The improved depth of focus could be valuable for structural imaging of microvascular morphology without the need for mechanical scanning in the depth direction.

  3. Chromatic-aberration-corrected diffractive lenses for ultra-broadband focusing

    Science.gov (United States)

    Wang, Peng; Mohammad, Nabil; Menon, Rajesh

    2016-02-01

    We exploit the inherent dispersion in diffractive optics to demonstrate planar chromatic-aberration-corrected lenses. Specifically, we designed, fabricated and characterized cylindrical diffractive lenses that efficiently focus the entire visible band (450 nm to 700 nm) onto a single line. These devices are essentially pixelated, multi-level microstructures. Experiments confirm an average optical efficiency of 25% for a three-wavelength apochromatic lens whose chromatic focus shift is only 1.3 μm and 25 μm in the lateral and axial directions, respectively. Super-achromatic performance over the continuous visible band is also demonstrated with averaged lateral and axial focus shifts of only 1.65 μm and 73.6 μm, respectively. These lenses are easy to fabricate using single-step grayscale lithography and can be inexpensively replicated. Furthermore, these devices are thin (<3 μm), error tolerant, has low aspect ratio (<1:1) and offer polarization-insensitive focusing, all significant advantages compared to alternatives that rely on metasurfaces. Our design methodology offers high design flexibility in numerical aperture and focal length, and is readily extended to 2D.

  4. Chromatic aberration correction and deconvolution for UV sensitive imaging of fluorescent sterols in cytoplasmic lipid droplets.

    Science.gov (United States)

    Wüstner, Daniel; Faergeman, Nils J

    2008-08-01

    Intrinsically fluorescent sterols, like dehydroergosterol (DHE), mimic cholesterol closely and are therefore suitable to determine cholesterol transport by fluorescence microscopy. Disadvantages of DHE are its low quantum yield, rapid bleaching, and the fact that its excitation and emission is in the UV region of the spectrum. Thus, one has to deal with chromatic aberration and low signal-to-noise ratio. We developed a method to correct for chromatic aberration between the UV channel and the red/green channel in multicolor imaging of DHE compared with the lipid droplet marker Nile Red in living macrophage foam cells and in adipocytes. We used deconvolution microscopy and developed image segmentation techniques to assess the DHE content of lipid droplets in both cell types in an automated manner. Pulse-chase studies and colocalization analysis were performed to monitor the redistribution of DHE upon adipocyte differentiation. DHE is targeted to transferrin-positive recycling endosomes in preadipocytes but associates with droplets in mature adipocytes. Only in adipocytes but not in foam cells fluorescent sterol was confined to the droplet-limiting membrane. We developed an approach to visualize and quantify sterol content of lipid droplets in living cells with potential for automated high content screening of cellular sterol transport.

  5. Chromatic aberration correction of the human eye for retinal imaging in the near infrared.

    Science.gov (United States)

    Fernández, Enrique J; Unterhuber, Angelika; Povazay, Boris; Hermann, Boris; Artal, Pablo; Drexler, Woflgang

    2006-06-26

    An achromatizing lens has been designed for the human eye in the near infrared range, from 700 to 900 nm, for retinal imaging purposes. Analysis of the performance of the lens, including tolerance to misalignments, has been mathematically accomplished by using an existing eye model. The calculations have shown a virtually perfect correction of the ocular longitudinal chromatic aberration, while still keeping a high optical quality. Ocular aberrations in five subjects have been measured with and without the achromatizing lens by using a Hartmann-Shack wavefront sensor and a broad bandwidth femtosecond Ti:sapphire laser in the spectral range of interest with a set of interference filters, studying the benefits and limits in the use of the achromatizing lens. Ocular longitudinal chromatic aberration has been experimentally demonstrated to be fully corrected by the proposed lens, with no induction of any other parasitic aberration. The practical implementation of the achromatizing lens for Ophthalmoscopy, specifically for optical coherence tomography where the use of polychromatic light sources in the near infrared portion of the spectrum is mandatory, has been considered. The potential benefits of using this lens in combination with adaptive optics to achieve a full aberration correction of the human eye for retinal imaging have also been discussed.

  6. Eliminating chromatic aberration in Gauss-type lens design using a novel genetic algorithm.

    Science.gov (United States)

    Fang, Yi-Chin; Tsai, Chen-Mu; Macdonald, John; Pai, Yang-Chieh

    2007-05-01

    Two different types of Gauss lens design, which effectively eliminate primary chromatic aberration, are presented using an efficient genetic algorithm (GA). The current GA has to deal with too many targets in optical global optimization so that the performance is not much improved. Generally speaking, achromatic aberrations have a great relationship with variable glass sets for all elements. For optics whose design is roughly convergent, glass sets for optics will play a significant role in axial and lateral color aberration. Therefore better results might be derived from the optimal process of eliminating achromatic aberration, which could be carried out by finding feasible glass sets in advance. As an alternative, we propose a new optimization process by using a GA and involving theories of geometrical optics in order to select the best optical glass combination. Two Gauss-type lens designs are employed in this research. First, a telephoto lens design is sensitive to axial aberration because of its long focal length, and second, a wide-angle Gauss design is complicated by lateral color aberration at the extreme corners because Gauss design is well known not to deal well with wide-angle problems. Without numbers of higher chief rays passing the element, it is difficult to correct lateral color aberration altogether for the Gauss design. The results and conclusions show that the attempts to eliminate primary chromatic aberrations were successful.

  7. Ultrahigh-resolution optical coherence tomography with monochromatic and chromatic aberration correction.

    Science.gov (United States)

    Zawadzki, Robert J; Cense, Barry; Zhang, Yan; Choi, Stacey S; Miller, Donald T; Werner, John S

    2008-05-26

    We have developed an improved adaptive optics - optical coherence tomography (AO-OCT) system and evaluated its performance for in vivo imaging of normal and pathologic retina. The instrument provides unprecedented image quality at the retina with isotropic 3D resolution of 3.5 x 3.5 x 3.5 microm(3). Critical to the instrument's resolution is a customized achromatizing lens that corrects for the eye's longitudinal chromatic aberration and an ultra broadband light source (Delta lambda=112 nm lambda(0)= approximately 836 nm). The eye's transverse chromatic aberrations is modeled and predicted to be sufficiently small for the imaging conditions considered. The achromatizing lens was strategically placed at the light input of the AO-OCT sample arm. This location simplifies use of the achromatizing lens and allows straightforward implementation into existing OCT systems. Lateral resolution was achieved with an AO system that cascades two wavefront correctors, a large stroke bimorph deformable mirror (DM) and a micro-electromechanical system (MEMS) DM with a high number of actuators. This combination yielded diffraction-limited imaging in the eyes examined. An added benefit of the broadband light source is the reduction of speckle size in the axial dimension. Additionally, speckle contrast was reduced by averaging multiple B-scans of the same proximal patch of retina. The combination of improved micron-scale 3D resolution, and reduced speckle size and contrast were found to significantly improve visibility of microscopic structures in the retina.

  8. The reduction of chromate ions by Fe(II layered hydroxides

    Directory of Open Access Journals (Sweden)

    S. Loyaux-Lawniczak

    1999-01-01

    Full Text Available The reduction of chromate ions by Fe(OH2 and the iron (II-iron (III hydroxysulphate green rust, GR(SO42-, was studied to evaluate whether such synthetic layered hydroxides and the corresponding natural green rust mineral could be involved in the natural attenuation of contaminated environments. The resulting Cr (III bearing phases, which would govern the subsequent behaviour of chromium, were clearly characterised. Both compounds proved to be very reactive and oxidised instantaneously while chromate ions were reduced to Cr (III as evidenced by X-ray photoelectron spectroscopy. Mass balance (ICP-AES demonstrated that the Fe/Cr ratio inside the solid end product was equal to the initial Fe/Cr ratio. The solid phases, analysed by X-ray diffraction, Raman and Mossbauer spectroscopies were identified as Cr-substituted poorly crystallised iron (III oxyhydroxides in both cases, more precisely δ-FeOOH when starting with Fe(OH2 and ferrihydrite when starting with GR(SO42-.

  9. Laser weld process monitoring and control using chromatic filtering of thermal radiation from a weld pool

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Cheol Jung; Kim, Min Suk; Baik, Sung Hoon; Chung, Chin Man

    2000-06-01

    The application of high power Nd: YAG lasers for precision welding in industry has been growing quite fast these days in diverse areas such as the automobile, the electronics and the aerospace industries. These diverse applications also require the new developments for the precise control and the reliable process monitoring. Due to the hostile environment in laser welding, a remote monitoring is required. The present development relates in general to weld process monitoring techniques, and more particularly to improved methods and apparatus for real-time monitoring of thermal radiation of a weld pool to monitor a size variation and a focus shift of the weld pool for weld process control, utilizing the chromatic aberration of focusing lens or lenses. The monitoring technique of the size variation and the focus shift of a weld pool is developed by using the chromatic filtering of the thermal radiation from a weld pool. The monitoring of weld pool size variation can also be used to monitor the weld depth in a laser welding. Furthermore, the monitoring of the size variation of a weld pool is independent of the focus shift of a weld pool and the monitoring of the focus shift of a weld pool is independent of the size variation of a weld pool.

  10. Ponceau 6R dye decoloration and chromate reduction simultaneously in acid medium

    Directory of Open Access Journals (Sweden)

    Seddique M. Ahmed

    2015-07-01

    Full Text Available The degradation efficiency and kinetic degradation reaction of Ponceau 6R dye using potassium chromate have been investigated under various experimental conditions: different concentrations of H2SO4 and temperatures. The immediate change of the red coloration (λmax = 518 nm to colorless was observed after addition of inorganic oxidizing agent (K2CrO4 into the protonated form of Ponceau 6R dye after 48 h. This observation could be attributed to the highest oxidized form of this dye obtained (the quinoid one, which undergoes a hydrolysis reaction to produce p-hydroquinone (H2Q by a mechanism similar to Schiff-base hydrolysis. The cationic form of this matrix is a crucial feature for the hydrolysis process. A kinetic model for oxidation of Ponceau 6R by the combination of chromate was developed based on experimental results. The observed kinetic reaction coefficient was determined and correlated as a function of UV spectral intensity of Ponceau 6R at 518 nm. The degradation rate follows pseudo-first order kinetics with respect to dye concentration.

  11. Chromatic Mechanical Response in 2-D Layered Transition Metal Dichalcogenide (TMDs) based Nanocomposites

    Science.gov (United States)

    Rahneshin, Vahid; Khosravi, Farhad; Ziolkowska, Dominika A.; Jasinski, Jacek B.; Panchapakesan, Balaji

    2016-10-01

    The ability to convert photons of different wavelengths directly into mechanical motion is of significant interest in many energy conversion and reconfigurable technologies. Here, using few layer 2H-MoS2 nanosheets, layer by layer process of nanocomposite fabrication, and strain engineering, we demonstrate a reversible and chromatic mechanical response in MoS2-nanocomposites between 405 nm to 808 nm with large stress release. The chromatic mechanical response originates from the d orbitals and is related to the strength of the direct exciton resonance A and B of the few layer 2H-MoS2 affecting optical absorption and subsequent mechanical response of the nanocomposite. Applying uniaxial tensile strains to the semiconducting few-layer 2H-MoS2 crystals in the nanocomposite resulted in spatially varying energy levels inside the nanocomposite that enhanced the broadband optical absorption up to 2.3 eV and subsequent mechanical response. The unique photomechanical response in 2H-MoS2 based nanocomposites is a result of the rich d electron physics not available to nanocomposites based on sp bonded graphene and carbon nanotubes, as well as nanocomposite based on metallic nanoparticles. The reversible strain dependent optical absorption suggest applications in broad range of energy conversion technologies that is not achievable using conventional thin film semiconductors.

  12. Study of Gravitational Lens Chromaticity from Ground-based Narrow Band Photometry

    CERN Document Server

    Mosquera, Ana M; Mediavilla, Evencio; Kochanek, Christopher S

    2010-01-01

    We present observations of wavelength-dependent flux ratios for 4 gravitational lens systems (SDSS~J1650+4251, HE~0435$-$1223, FBQ 0951+2635, and Q~0142$-$100) obtained with the Nordic Optical telescope (NOT). The use of narrow band photometry, as well as the excellent seeing conditions during the observations, allow us to set good baselines to study their chromatic behavior. For SDSS~J1650+4251 we determine the extinction curve of the dust in the $z_L=0.58$ lens galaxy, and find that the 2175 \\AA \\ feature is absent. In the case of HE~0435$-$1223 we clearly detect chromatic microlensing. This allows us to estimate the wavelength dependent size of the accretion disk. We found an R-band disk size of $r^{R}_s=13\\pm5$ light days for a linear prior on $r^{R}_s$ and of $r^{R}_s=7\\pm6$ light days for a logarithmic prior. For a power law size-wavelength scaling of $r_s\\propto\\lambda^{p}$, we were able to constrain the value of the exponent to $p=1.3\\pm0.3$ for both $r^{R}_s$ priors, which is in agreement with the te...

  13. Chromatic aberration and the roles of double-opponent and color-luminance neurons in color vision

    NARCIS (Netherlands)

    Vladusich, Tony

    2007-01-01

    How does the visual cortex encode color? I summarize a theory in which cortical double-opponent color neurons perform a role in color constancy and a complementary set of color-luminance neurons function to selectively correct for color fringes induced by chromatic aberration in the eye. The theory

  14. Different temporal structure for form versus surface cortical color systems--evidence from chromatic non-linear VEP.

    Directory of Open Access Journals (Sweden)

    David P Crewther

    Full Text Available Physiological studies of color processing have typically measured responses to spatially varying chromatic stimuli such as gratings, while psychophysical studies of color include color naming, color and light, as well as spatial and temporal chromatic sensitivities. This raises the question of whether we have one or several cortical color processing systems. Here we show from non-linear analysis of human visual evoked potentials (VEP the presence of distinct and independent temporal signatures for form and surface color processing. Surface color stimuli produced most power in the second order Wiener kernel, indicative of a slowly recovering neural system, while chromatic form stimulation produced most power in the first order kernel (showing rapid recovery. We find end-spectral saturation-dependent signals, easily separable from achromatic signals for surface color stimuli. However physiological responses to form color stimuli, though varying somewhat with saturation, showed similar waveform components. Lastly, the spectral dependence of surface and form color VEP was different, with the surface color responses almost vanishing with yellow-grey isoluminant stimulation whereas the form color VEP shows robust recordable signals across all hues. Thus, surface and form colored stimuli engage different neural systems within cortex, pointing to the need to establish their relative contributions under the diverse chromatic stimulus conditions used in the literature.

  15. Different temporal structure for form versus surface cortical color systems--evidence from chromatic non-linear VEP.

    Science.gov (United States)

    Crewther, David P; Crewther, Sheila G

    2010-12-20

    Physiological studies of color processing have typically measured responses to spatially varying chromatic stimuli such as gratings, while psychophysical studies of color include color naming, color and light, as well as spatial and temporal chromatic sensitivities. This raises the question of whether we have one or several cortical color processing systems. Here we show from non-linear analysis of human visual evoked potentials (VEP) the presence of distinct and independent temporal signatures for form and surface color processing. Surface color stimuli produced most power in the second order Wiener kernel, indicative of a slowly recovering neural system, while chromatic form stimulation produced most power in the first order kernel (showing rapid recovery). We find end-spectral saturation-dependent signals, easily separable from achromatic signals for surface color stimuli. However physiological responses to form color stimuli, though varying somewhat with saturation, showed similar waveform components. Lastly, the spectral dependence of surface and form color VEP was different, with the surface color responses almost vanishing with yellow-grey isoluminant stimulation whereas the form color VEP shows robust recordable signals across all hues. Thus, surface and form colored stimuli engage different neural systems within cortex, pointing to the need to establish their relative contributions under the diverse chromatic stimulus conditions used in the literature.

  16. Quantitative Phase Microscopy of microstructures with extended measurement range and correction of chromatic aberrations by multiwavelength digital holography.

    Science.gov (United States)

    Ferraro, P; Miccio, L; Grilli, S; Paturzo, M; De Nicola, S; Finizio, A; Osellame, R; Laporta, P

    2007-10-29

    Quantitative Phase Microscopy (QPM) by interferometric techniques can require a multiwavelength configuration to remove 2pi ambiguity and improve accuracy. However, severe chromatic aberration can affect the resulting phase-contrast map. By means of classical interference microscope configuration it is quite unpractical to correct such aberration. We propose and demonstrate that by Digital Holography (DH) in a microscope configuration it is possible to clear out the QPM map from the chromatic aberration in a simpler and more effective way with respect to other approaches. The proposed method takes benefit of the unique feature of DH to record in a plane out-of-focus and subsequently reconstruct numerically at the right focal image plane. In fact, the main effect of the chromatic aberration is to shift differently the correct focal image plane at each wavelength and this can be readily compensated by adjusting the corresponding reconstruction distance for each wavelength. A procedure is described in order to determine easily the relative focal shift among different imaging wavelengths by performing a scanning of the numerical reconstruction along the optical axis, to find out the focus and to remove at the same time the chromatic aberration.

  17. Experimental demonstration of adaptive digital monitoring and compensation of chromatic dispersion for coherent DP-QPSK receiver

    DEFF Research Database (Denmark)

    Borkowski, Robert; Zhang, Xu; Zibar, Darko;

    2011-01-01

    We experimentally demonstrate a digital signal processing (DSP)-based optical performance monitoring (OPM) algorithm for inservice monitoring of chromatic dispersion (CD) in coherent transport networks. Dispersion accumulated in 40 Gbit/s QPSK signal after 80 km of fiber transmission is successfu...

  18. Iridophores and not carotenoids account for chromatic variation of carotenoid-based coloration in common lizards (Lacerta vivipara).

    Science.gov (United States)

    San-Jose, Luis M; Granado-Lorencio, Fernando; Sinervo, Barry; Fitze, Patrick S

    2013-03-01

    Abstract Carotenoids typically need reflective background components to shine. Such components, iridophores, leucophores, and keratin- and collagen-derived structures, are generally assumed to show no or little environmental variability. Here, we investigate the origin of environmentally induced variation in the carotenoid-based ventral coloration of male common lizards (Lacerta vivipara) by investigating the effects of dietary carotenoids and corticosterone on both carotenoid- and background-related reflectance. We observed a general negative chromatic change that was prevented by β-carotene supplementation. However, chromatic changes did not result from changes in carotenoid-related reflectance or skin carotenoid content but from changes in background-related reflectance that may have been mediated by vitamin A1. An in vitro experiment showed that the encountered chromatic changes most likely resulted from changes in iridophore reflectance. Our findings demonstrate that chromatic variation in carotenoid-based ornaments may not exclusively reflect differences in integumentary carotenoid content and, hence, in qualities linked to carotenoid deposition (e.g., foraging ability, immune response, or antioxidant capacity). Moreover, skin carotenoid content and carotenoid-related reflectance were related to male color polymorphism, suggesting that carotenoid-based coloration of male common lizards is a multicomponent signal, with iridophores reflecting environmental conditions and carotenoids reflecting genetically based color morphs.

  19. A Researchon Ancient Chromaticity Printing in China%中国古代套色印刷考略

    Institute of Scientific and Technical Information of China (English)

    薛慧芳

    2014-01-01

    The ancient chromaticity printing in China was another breakthrough after the invention of block printing and movable type printing. The ancient chromaticity printing began with watercolour block printing, which is one of the major printings that has upgraded chromaticity printing to an unprecedented degree. Engraving in this method is not only colorful and chromatic but also displays intensity of colors. The embossing printing makes the presswork exquisite aesthetic, which is one hundred and fifty years earlier than the thermograph in Germany.%套色印刷是中国古代继雕版印刷、活字印刷之后又一重大技术突破,“饾版”的发明开创了古代套色版画的先河,所印刷的版画不仅色彩绚丽,精美鲜艳,且能表现画面的深浅浓度,把套色技术提高到前所未有的程度。“拱版”技术的创新使印刷品更为美观精致,它比18世纪中叶德国第一次应用凹凸印刷技术要早150多年。

  20. On the Chromaticity of Complete 4-partite Graphs%完全四部图的色性

    Institute of Scientific and Technical Information of China (English)

    李占兰; 赵海兴

    2004-01-01

    Let G be a graph and P(G,λ) the chromatic polynomial of G.Graphs G and H are said to be chromatically equivalent,simply denoted by G~H,if P(G,λ)=P(H,λ).Let [G]={H|H~G}.Graph G is said to be chromatically unique if [G]={G}.We denote by K(n1,n2,n3,n4) complete 4-partite graphs with 2()k+2 and k(>)2,K(n-k,n,n,n) is chromatically unique.%设G是一个图,P(G,λ)是G的色多项式.若P(G,λ)=P(H,λ),则称G和H是色等价的,简单地用G~H表示.令[G]={H|H~G}.若[G]={G},称G是色唯一的.用G=K(n1,n2,n3,n4)表示完全四部图且2()k+2,k(>)2时,K(n-k,n,n,n)是色唯一的.

  1. Limitations in distance and frequency due to chromatic dispersion in fibre-optic microwave and millimeter-wave links

    DEFF Research Database (Denmark)

    Gliese, Ulrik Bo; Nielsen, Søren Nørskov

    1996-01-01

    Chromatic dispersion significantly limits the distance and/or frequency in fibre-optic microwave and millimeter-wave links based on direct detection due to a decrease of the carrier to noise ratio. The limitations in links based on coherent remote heterodyne detection, however, are far less...

  2. Structure and function of ferricyanide in the formation of chromate conversion coatings on aluminum aircraft alloy

    Energy Technology Data Exchange (ETDEWEB)

    Xia, L.; McCreery, R.L.

    1999-10-01

    Raman and infrared spectroscopy were used to determine the structure of Fe(CN){sup {minus}3}{sub 6} and its reaction products in chromate conversion coatings (CCCs) on AA 2024-T3 aluminum aircraft alloy. In addition, Raman spectroscopy was used to monitor CCC growth rates and their dependence on coating bath composition. The IR and Raman spectra of the air-dried CCC corresponded to those of Berlin green, a Fe{sup +3}-CN-FE{sup +3} polymer, and Fe(CN){sub 6}{sup {minus}3} physisorbed on Cr(OH){sub 3}. No other cyano-containing products were observed. When Fe(CN){sub 6}{sup {minus}3} was excluded from the coating bath, CCC formation rate greatly decreased. In addition, it was observed that Fe(CN){sub 6}{sup {minus}3} could rapidly oxidize AA 2024-T3, and Fe(CN){sub 6}{sup {minus}4} rapidly reduced Cr(VI) in bath conditions. These results indicate a redox mediation action for Fe(CN){sub 6}{sup {minus}3/{minus}4}, which greatly increases the reduction of Cr(VI) to Cr(III) by the alloy. This process is normally quite slow, and redox mediation by Fe(CN){sub 6}{sup {minus}3} is critical to CCC formation. IrCl{sub 6}{sup {minus}3}/{sup {minus}2} could substitute for Fe(CN){sub 6}{sup {minus}3/{minus}4} to produce a chromate film with properties very similar to a conventional CCC. The results establish redox mediation as the mechanism of acceleration of CCC formation, but provide no evidence for any additional role of Fe(CN){sub 6}{sup {minus}3/{minus}4} to produce a chromate film with properties very similar to a conventional CCC. The results establish redox mediation as the mechanism of acceleration of CCC formation, but provide no evidence for any additional role of Fe(CN){sub 6}{sup {minus}3/{minus}4} in corrosion protection.

  3. The influence of water repellent products on the chromatic modifications of the ceramic brick

    Directory of Open Access Journals (Sweden)

    Coronado Martin, J. A.

    2011-12-01

    Full Text Available Chromatic variation, colour and luminosity, undergone by the ceramic support protected by the incorporation of a treatment with water repellent products, is analysed. A new methodology is suggested, based on RGB model where quantifiable values from each ceramic sample are obtained through digital measurement of the colour (image histograms, taking as a base the same type of ceramics with no water repellents. Chromatic variation is determined by the type of water repellent and the base material, obtaining the following results: - All the water repellent studied cause variations in the shade and luminosity of the piece. - English red brick (R is the one presenting less variation of luminosity and shade since it’s been treated with water repellents. - The water repellent of siliconates component is the one which causes less chromatic variation in two of the three bricks studied, the dark brown (T and the English red (R one.

    Se analiza la variación cromática, color y luminosidad, que sufre el soporte cerámico protegido por la incorporación de un tratamiento con productos hidrofugantes. Se propone una metodología nueva, basada en el modelo RGB donde se obtienen valores cuantificables de cada muestra cerámica mediante medición digital del color (histogramas de imagen, tomándose como base el mismo tipo de cerámica sin hidrofugar. La variación cromática está determinada por el tipo de hidrofugante y por el material de base, obteniéndose los siguientes resultados: - Todos los hidrofugantes estudiados producen variación en la tonalidad y luminosidad de la pieza. - El ladrillo rojo ingles (R es el que presenta menor variación de luminosidad y tonalidad al ser tratado con hidrofugantes. - El hidrofugante de componente siliconatos es el que menor variación cromática produce en dos de los tres ladrillos estudiados, tostado (T y rojo inglés (R.

  4. Simultaneous speciation analysis of chromate, molybdate, tungstate and vanadate in welding fume alkaline extracts by HPLC-ICP-MS.

    Science.gov (United States)

    Ščančar, Janez; Berlinger, Balázs; Thomassen, Yngvar; Milačič, Radmila

    2015-09-01

    A novel analytical procedure was developed for the simultaneous speciation analysis of chromate, molybdate, tungstate and vanadate by anion-exchange high performance liquid chromatography hyphenated to inductively coupled plasma mass spectrometry (HPLC-ICP-MS). Linear gradient elution from 100% water to 100% 0.7 M NaCl was applied for chromatographic separation of metal species. In standard aqueous solution at neutral pH molybdate, tungstate and vanadate exist in several aqueous species, while chromate is present as a single CrO4(2-) species. Consequently, only chromate can be separated from this solution in a sharp chromatographic peak. For obtaining sharp chromatographic peaks for molybdate, tungstate and vanadate, the pH of aqueous standard solutions was raised to 12. At highly alkaline conditions single CrO4(2-), MoO4(2-) and WO4(2-) are present and were eluted in sharp chromatographic peaks, while VO4(3-) species, which predominates at pH 12 was eluted in slightly broaden peak. In a mixture of aqueous standard solutions (pH 12) chromate, molybdate, tungstate and vanadate were eluted at retention times from 380 to 420 s, 320 to 370 s, 300 to 350 s and 240 to 360 s, respectively. Eluted species were simultaneously detected on-line by ICP-MS recording m/z 52, 95, 182 and 51. The developed procedure was successfully applied to the analysis of leachable concentrations of chromate, molybdate, tungstate and vanadate in alkaline extracts (2% NaOH+3% Na2CO3) of manual metal arc (MMA) welding fumes loaded on filters. Good repeatability and reproducibility of measurement (RSD±3.0%) for the investigated species were obtained in both aqueous standard solutions (pH 12) and in alkaline extracts of welding fumes. Low limits of detection (LODs) were found for chromate (0.02 ng Cr mL(-1)), molybdate (0.1 ng Mo mL(-1)), tungstate (0.1 ng W mL(-1)) and vanadate (0.2 ng V mL(-1)). The accuracy of analytical procedure for the determination of chromate was checked by analysis of

  5. Cone photoreceptor sensitivities and unique hue chromatic responses: correlation and causation imply the physiological basis of unique hues.

    Directory of Open Access Journals (Sweden)

    Ralph W Pridmore

    Full Text Available This paper relates major functions at the start and end of the color vision process. The process starts with three cone photoreceptors transducing light into electrical responses. Cone sensitivities were once expected to be Red Green Blue color matching functions (to mix colors but microspectrometry proved otherwise: they instead peak in yellowish, greenish, and blueish hues. These physiological functions are an enigma, unmatched with any set of psychophysical (behavioral functions. The end-result of the visual process is color sensation, whose essential percepts are unique (or pure hues red, yellow, green, blue. Unique hues cannot be described by other hues, but can describe all other hues, e.g., that hue is reddish-blue. They are carried by four opponent chromatic response curves but the literature does not specify whether each curve represents a range of hues or only one hue (a unique over its wavelength range. Here the latter is demonstrated, confirming that opponent chromatic responses define, and may be termed, unique hue chromatic responses. These psychophysical functions also are an enigma, unmatched with any physiological functions or basis. Here both enigmas are solved by demonstrating the three cone sensitivity curves and the three spectral chromatic response curves are almost identical sets (Pearson correlation coefficients r from 0.95-1.0 in peak wavelengths, curve shapes, math functions, and curve crossover wavelengths, though previously unrecognized due to presentation of curves in different formats, e.g., log, linear. (Red chromatic response curve is largely nonspectral and thus derives from two cones. Close correlation combined with deterministic causation implies cones are the physiological basis of unique hues. This match of three physiological and three psychophysical functions is unique in color vision.

  6. Simultaneous chromatic dispersion, polarization-mode-dispersion and OSNR monitoring at 40Gbit/s.

    Science.gov (United States)

    Baker-Meflah, Lamia; Thomsen, Benn; Mitchell, John; Bayvel, Polina

    2008-09-29

    A novel method for independent and simultaneous monitoring of chromatic dispersion (CD), first-order PMD and OSNR in 40Gbit/s systems is proposed and demonstrated. This is performed using in-band tone monitoring of 5GHz, optically down-converted to a low intermediate-frequency (IF) of 10kHz. The measurement provides a large monitoring range with good accuracies for CD (4742+/-100ps/nm), differential group delay (DGD) (200+/-4ps) and OSNR (23+/-1dB), independently of the bit-rate. In addition, the use of electro-absorption modulators (EAM) for the simultaneous down-conversion of all channels and the use of low-speed detectors makes it cost effective for multi-channel operation.

  7. Feed-Forward Corrections for Tune and Chromaticity Injection Decay During 2015 LHC Operation

    CERN Document Server

    Solfaroli Camillocci, Matteo; Lamont, Mike; Schaumann, Michaela; Todesco, Ezio; Wenninger, Jorg

    2016-01-01

    After two years of shutdown, the Large Hadron Collider (LHC) has been operated in 2015 at 6.5 TeV, close to its designed energy. When the current is stable at low field, the harmonic components of the main circuits are subject to a dynamic variation induced by current redistribution on the superconducting cables. The Field Description of the LHC (FiDel) foresaw an increase of the decay at injection of tune (quadrupolar components) and chromaticity (sextupolar components) of about 50% with respect to LHC Run1 due to the higher operational current. This paper discusses the beam-based measurements of the decay during the injection plateau and the implementation and accuracy of the feed-forward corrections as present in 2015. Moreover, the observed tune shift proportional to the circulating beam intensity and it's foreseen feed-forward correction are covered.

  8. SPARCO : a semi-parametric approach for image reconstruction of chromatic objects

    CERN Document Server

    Kluska, J; Berger, J -P; Baron, F; Lazareff, B; Bouquin, J -B Le; Monnier, J D; Soulez, F; Thiébaut, E

    2014-01-01

    The emergence of optical interferometers with three and more telescopes allows image reconstruction of astronomical objects at the milliarcsecond scale. However, some objects contain components with very different spectral energy distributions (SED; i.e. different temperatures), which produces strong chromatic effects on the interferograms that have to be managed with care by image reconstruction algorithms. For example, the gray approximation for the image reconstruction process results in a degraded image if the total (u, v)-coverage given by the spectral supersynthesis is used. The relative flux contribution of the central object and an extended structure changes with wavelength for different temperatures. For young stellar objects, the known characteristics of the central object (i.e., stellar SED), or even the fit of the spectral index and the relative flux ratio, can be used to model the central star while reconstructing the image of the extended structure separately. Methods. We present a new method, c...

  9. Porous silicon optical template for determination of chromatic dispersion of transparent liquid mixture

    Science.gov (United States)

    Cafe, Arven I.; Lopez, Joybelle; Lopez, Lorenzo; Faustino, Maria Angela; Mabilangan, Arvin; Salvador, Arnel; Somintac, Armando

    2017-03-01

    Porous silicon was fabricated through electrochemical etching and is used as an optical template for liquid sensing application. Using reflectance spectroscopy, change in optical properties such as refractive index and reflectivity upon liquid introduction were obtained. Chromatic dispersion of porous silicon upon detection of transparent liquids such as absolute ethanol, methanol, 2-propanol and distilled water were determined for spectral range 450nm to 1100nm. Mixture of the organic transparent liquid and water was also tested. In this study, porosity and liquid's concentration were varied to establish the sensitivity of detection. Expected ideal values were also simulated for comparison and correction factor computation. Results provide calibration basis for water quality assessment, environmental monitoring, and diagnostic application.

  10. White organic light-emitting diodes with fine chromaticity tuning via ultrathin layer position shifting

    Science.gov (United States)

    Choukri, Hakim; Fischer, Alexis; Forget, Sébastien; Chénais, Sébastien; Castex, Marie-Claude; Adès, Dominique; Siove, Alain; Geffroy, Bernard

    2006-10-01

    Nondoped white organic light-emitting diodes using an ultrathin yellow-emitting layer of rubrene (5,6,11,12-tetraphenylnaphtacene) inserted on either side of the interface between a hole-transporting 4,4'-bis[N-(1-naphtyl)-N-phenylamino]biphenyl (α-NPB) layer and a blue-emitting 4,4'-bis(2,2'-diphenylvinyl)-1,1'-biphenyl (DPVBi) layer are described. Both the thickness and the position of the rubrene layer allow fine chromaticity tuning from deep blue to pure yellow via bright white with CIE coordinates (x =0.33, y =0.32), an ηext of 1.9%, and a color rendering index of 70. Such a structure also provides an accurate sensing tool to measure the exciton diffusion length in both DPVBi and NPB (8.7 and 4.9nm, respectively).

  11. Supersonic Fe beam source for chromatic aberration-free laser focusing of atoms

    CERN Document Server

    Bosch, R C M; Van der Straten, P; Leeuwen, K A H

    2002-01-01

    A monochromatic Fe beam is generated by heated supersonic expansion of argon seeded with Fe vapor. At a nozzle temperature of 1930 K and 800 torr argon inlet pressure the Fe beam has an axial velocity spread of 8% and intensity of 3 x 10 sup 1 sup 5 s sup - sup 1 sr sup - sup 1 , corresponding to a deposition rate of 10 nm/h at 150 mm from the nozzle. The two-chamber alumina crucibles are chemically stable for liquid Fe. With 400 mm sup 3 Fe we have operated for more than 200 hours without reloading. The power consumption at 1930 K is 750 W. Temperature stability at constant power (without feedback) is better than 30 K. The source is intended for deposition of nano-structures by laser focusing of the Fe beam. The small axial velocity spread virtually eliminates the increase in focal spot size due to chromatic aberration. (authors)

  12. Chromatic effects in beam wander correction for free-space quantum communications

    CERN Document Server

    Carrasco-Casado, Alberto; Fernandez, Veronica

    2016-01-01

    Beam wander caused by atmospheric turbulence can significantly degrade the performance of horizontal free-space quantum communication links. Classical beam wander correction techniques cannot be applied due to the stronger requirements of transmitting single photons. One strategy to overcome this limitation consists in using a separate wavelength from that of the quantum signal to analyze the beam wander and use this information for its correction. For this strategy to work adequately, both wavelengths should be affected equally by atmospheric turbulence, i.e. no chromatic effects should be originated from beam wander. In this letter, a series of experiments are performed to prove that this is the case for {\\lambda} ~ 850 nm as the quantum signal and {\\lambda} ~ 1550 nm as the tracking signal of a quantum communication system.

  13. Effect of chromatic aberration on atomic-resolved spherical aberration corrected STEM images.

    Science.gov (United States)

    Kuramochi, Koji; Yamazaki, Takashi; Kotaka, Yasutoshi; Ohtsuka, Masahiro; Hashimoto, Iwao; Watanabe, Kazuto

    2009-12-01

    The effect of the chromatic aberration (C(c)) coefficient in a spherical aberration (C(s))- corrected electromagnetic lens on high-resolution high-angle annular dark field (HAADF) scanning transmission electron microscope (STEM) images is explored in detail. A new method for precise determination of the C(c) coefficient is demonstrated, requiring measurement of an atomic-resolution one-frame through-focal HAADF STEM image. This method is robust with respect to instrumental drift, sample thickness, all lens parameters except C(c), and experimental noise. It is also demonstrated that semi-quantitative structural analysis on the nanometer scale can be achieved by comparing experimental C(s)- corrected HAADF STEM images with their corresponding simulated images when the effects of the C(c) coefficient and spatial incoherence are included.

  14. Information transfer in a TEM corrected for spherical and chromatic aberration.

    Science.gov (United States)

    Haider, M; Hartel, P; Müller, H; Uhlemann, S; Zach, J

    2010-08-01

    For the transmission electron aberration-corrected microscope (TEAM) initiative of five U.S. Department of Energy laboratories in the United States, a correction system for the simultaneous compensation of the primary axial aberrations, the spherical aberration Cs, and the chromatic aberration Cc has been developed and successfully installed. The performance of the resulting Cc /Cs-corrected TEAM instrument has been investigated thoroughly. A significant improvement of the linear contrast transfer can be demonstrated. The information about the instrument one obtains using Young's fringe method is compared for uncorrected, Cs-corrected, and Cc /Cs-corrected instruments. The experimental results agree well with simulations. The conclusions might be useful to others in understanding the process of image formation in a Cc /Cs-corrected transmission electron microscope.

  15. Chromatic polarization effects of swept waveforms in FDML lasers and fiber spools.

    Science.gov (United States)

    Wieser, Wolfgang; Palte, Gesa; Eigenwillig, Christoph M; Biedermann, Benjamin R; Pfeiffer, Tom; Huber, Robert

    2012-04-23

    We present detailed investigations of chromatic polarization effects, caused by fiber spools used in FDML lasers and buffering spools for rapidly wavelength swept lasers. We introduce a novel wavelength swept FDML laser source, specially tailored for polarization sensitive optical coherence tomography (OCT) which switches between two different linear polarization states separated by 45°, i.e. 90° on the Poincaré sphere. The polarization maintaining laser cavity itself generates a stable linear polarization state and uses an external buffering technique in order to provide alternating polarization states for successive wavelength sweeps. The design of the setup is based on a comprehensive analysis of the polarization output from FDML lasers, using a novel 150 MHz polarization analyzer. We investigate the fiber polarization properties related to swept source OCT for different fiber delay topologies and analyze the polarization state of different FDML laser sources.

  16. Engineering chromatic dispersion and effective nonlinearity in a dual-slot waveguide.

    Science.gov (United States)

    Liu, Yan; Yan, Jing; Han, Genquan

    2014-09-20

    In this paper, we propose a new dual slot based on rib-like structure, which exhibits a flat and near-zero dispersion over a 198 nm wide wavelength range. Chromatic dispersion of dual-slot silicon (Si) waveguide is mainly determined by waveguide dispersion due to the manipulating mode effective area rather than by the material dispersion. Moreover, the nonlinear coefficient and effective mode area of the waveguide are also explored in detail. A nonlinear coefficient of 1460/m/W at 1550 nm is achieved, which is 10 times larger than that of the Si rib waveguide. By changing different waveguide variables, both the dispersion and nonlinear coefficient can be tailored, thus enabling the potential for a highly nonlinear waveguide with uniform dispersion over a wide wavelength range, which could benefit the performance of broadband optical signal systems.

  17. INFLUENCE OF CHROMATIC DISPERSION, DISPERSION SLOPE, DISPERSION CURVATURE ON MICROWAVE GENERATION USING TWO CASCADE MODULATORS

    Directory of Open Access Journals (Sweden)

    Mandeep Singh

    2013-03-01

    Full Text Available This work presents a theoretical study of harmonic generation of microwave signals after detection of a modulated optical carrier in cascaded two electro-optic modulators. Dispersion is one of the major limiting factors for microwave generation in microwave photonics. In this paper, we analyze influence of chromatic dispersion, dispersion slope, dispersion curvature on microwave generation using two cascaded MZMs and it has been found that output intensity of photodetector reduces when dispersion term up to fifth order are added. We have used the two cascaded Mach-Zehnder Modulators for our proposed model and tried to show the dispersion effect with the help of modulation depth factor of MZM, which have been not discussed earlier.

  18. A new upper bound on the acyclic chromatic indices of planar graphs

    CERN Document Server

    Wang, Weifan; Wang, Yiqiao

    2012-01-01

    An acyclic edge coloring of a graph $G$ is a proper edge coloring such that no bichromatic cycles are produced. The acyclic chromatic index $a'(G)$ of $G$ is the smallest integer $k$ such that $G$ has an acyclic edge coloring using $k$ colors. It was conjectured that $a'(G)\\le \\Delta+2$ for any simple graph $G$ with maximum degree $\\Delta$. In this paper, we prove that if $G$ is a planar graph, then $a'(G)\\leq\\Delta +7$. This improves a result by Basavaraju et al. [{\\em Acyclic edge-coloring of planar graphs}, SIAM J. Discrete Math., 25 (2011), pp. 463-478], which says that every planar graph $G$ satisfies $a'(G)\\leq\\Delta +12$.

  19. Post treatment of silane and cerium salt as chromate replacers on galvanized steel

    Institute of Scientific and Technical Information of China (English)

    KONG Gang; LU Jintang; WU Haijiang

    2009-01-01

    A complex film on hot-dip galvanized steel sheet (HDG) was prepared by immersing the sheet in 0.1wt.% Ce(NO3)3 solution and 5vol.% silane solution in turn. The corrosion protection of the complex film was evaluated by potentiodynamic linear polarization(LPR), electrochemical impendence spectra (EIS) and natural salt spray (NSS) tests and compared with that of single cerium film and silane film. The results showed that, the presence of these films on the zinc coating hindered corrosion reaction by reducing the rate of both anodic and cathodic reaction in the corrosion process, and the corrosion protection of the complex film was much better than that of single cerium film or silane film and closed to that of chromate film, because the polarization resistance Rp and electrochemical impendence were increased markedly. Microstructure and chemical composition of these pretreated films were also investigated by scanning electron microscopy (SEM) and AES.

  20. Humidity sensing behaviour of polyaniline/magnesium chromate (MgCrO4) composite

    Indian Academy of Sciences (India)

    T Machappa; M V N Ambika Prasad

    2012-02-01

    ‘in situ’ polymerization of polyaniline (PANI) was carried out in the presence of magnesium chromate (MgCrO4) to synthesize PANI/ceramic (MgCrO4) composite. These prepared composites were characterized by XRD, FTIR and SEM, which confirm the presence of MgCrO4 in polyaniline matrix. The temperature dependent conductivity measurement shows the thermally activated exponential behaviour of PANI /MgCrO4 composites. The decrease in electrical resistance was observed when the polymer composites were exposed to the broad range of relative humidity (ranging between 20 and 95% RH). This decrease is due to increase in surface electrical conductivity resulting from moisture absorption and due to capillary condensation of water causing change in conductivity within the sensing materials. PANI / MgCrO4 composites are found to be sensitive to low humidity ranging from 20 to 50% RH.

  1. White Organic Light-Emitting Diodes with fine chromaticity tuning via ultrathin layer position shifting

    CERN Document Server

    Choukri, H; Forget, S; Chenais, S; Castex, M C; Ades, D; Siove, A; Geffroy, B; Choukri, Hakim; Fischer, Alexis; Forget, Sebastien; Chenais, Sebastien; Castex, Marie-Claude; Ades, Dominique; Siove, Alain; Geffroy, Bernard

    2006-01-01

    Non-doped white organic light-emitting diodes using an ultrathin yellow-emitting layer of rubrene (5,6,11,12-tetraphenylnaphtacene) inserted on either side of the interface between a hole-transporting NPB (4,4'-bis[N-(1-naphtyl)-N-phenylamino]biphenyl) layer and a blue-emitting DPVBi (4,4'-bis(2,2'-diphenylvinyl)-1,1'-biphenyl) layer are described. Both the thickness and the position of the rubrene layer allow fine chromaticity tuning from deep-blue to pure-yellow via bright-white with CIE coordinates (x= 0.33, y= 0.32), a external quantum efficiency of 1.9%, and a color rendering index of 70. Such a structure also provides an accurate sensing tool to measure the exciton diffusion length in both DPVBi and NPB (8.7 and 4.9 nm respectively).

  2. Streptococcus agalactiae vaginitis: nonhemolytic variant on the Liofilchem® Chromatic StreptoB.

    Science.gov (United States)

    Savini, Vincenzo; Marrollo, Roberta; D'Antonio, Marianna; D'Amario, Claudio; Fazii, Paolo; D'Antonio, Domenico

    2013-01-01

    Streptococcus agalactiae (group B Streptococcus, GBS) vaginal pathogenicity is not uniformly acknowledged throughout the literature; accordingly, in women, genital itching and burning, along with leukorrhea are commonly and almost exclusively referred to bacterial vaginosis, candidiasis and trichomoniasis. Conversely, GBS virulence for vagina was recognized in the past, as the organism has been observed to potentially cause local inflammation and discharge, as well as lactobacilli rarefaction. We depict here a case where a nonhemolytic (γ-hemolytic) GBS strain was found to be the etiologic agent of vaginal infection. Such uncommon S. agalactiae phenotypes are hard to be recognized and may be therefore responsible for misdiagnosing and underestimation of GBS vaginitis prevalence; here, we had the support of the Liofilchem(®) Chromatic StreptoB medium, that successfully detected such an atypical variant.

  3. Chromaticity of the lattice and beam stability in energy-recovery linacs

    Energy Technology Data Exchange (ETDEWEB)

    Litvinenko, V.N.

    2011-12-23

    Energy recovery linacs (ERLs) are an emerging generation of accelerators promising to revolutionize the fields of high-energy physics and photon sciences. These accelerators combine the advantages of linear accelerators with that of storage rings, and hold the promise of delivering electron beams of unprecedented power and quality. Use of superconducting radio-frequency (SRF) cavities converts ERLs into nearly perfect 'perpetuum mobile' accelerators, wherein the beam is accelerated to a desirable energy, used, and then gives the energy back to the RF field. One potential weakness of these devices is transverse beam break-up instability that could severely limit the available beam current. In this paper, I present a method of suppressing these dangerous effects using a natural phenomenon in the accelerators, viz., the chromaticity of the transverse motion.

  4. Production of a microcapsule agent of chromate-reducing Lysinibacillus fusiformis ZC1 and its application in remediation of chromate-spiked soil.

    Science.gov (United States)

    Huang, Jun; Li, Jingxin; Wang, Gejiao

    2016-01-01

    Lysinibacillus fusiformis ZC1 is an efficient Cr(VI)-reducing bacterium that can transform the toxic and soluble chromate [Cr(VI)] form to the less toxic and precipitated chromite form [Cr(III)]. As such, this strain might be applicable for bioremediation of Cr(VI) in soil by reducing its bioavailability. The study objective was to prepare a microcapsule agent of strain ZC1 for bioremediation of Cr(VI)-contaminated soil. Using a single-factor orthogonal array design, the optimal fermentation medium was obtained and consisted of 6 g/L corn flour, 12 g/L soybean flour, 8 g/L NH4Cl and 6 g/L CaCl2. After enlarged fermentation, the cell and spore densities were 5.9 × 10(9) and 1.7 × 10(8) cfu/mL, respectively. The fermentation products were collected and embedded with 1 % gum arabic and 1 % sorbitol as the microcapsule carriers and were subsequently spray-dried. Strain ZC1 exhibited viable cell counts of (3.6 ± 0.44) × 10(10) cfu/g dw after 50-day storage at room temperature. In simulated soil bioremediation experiments, 67 % of Cr(VI) was reduced in 5 days with the inoculation of this microcapsule agent, and the Cr(VI) concentration was below the soil Cr(VI) standard level. The results demonstrated that the microcapsule agent of strain ZC1 is efficient for bioremediation of Cr(VI)-contaminated soil.

  5. Corrosion inhibition mechanisms of aluminum alloy 2024-T3 by selected non-chromate inhibitors

    Science.gov (United States)

    Lopez-Garrity, Omar A.

    The pursuit to find a chromate-alternative has led to the development of several chromate-free aerospace primers and coating systems that offer good protection. However, fundamental understanding of the functionality of the chromate-free pigments that are embedded within these coating systems is lacking. The objective of this study was to understand the fundamental mechanism of corrosion inhibition of aluminum alloy 2024-T3 by molybdate (MoO 42-), silicate (SiO32-), and praseodymium (Pr3+) with the goal of developing the kind of understanding that was accomplished for chromate. Furthermore, since most inhibiting conversion coatings and pigments act by releasing soluble species into the local environment, it was of interest to understand the mechanism of inhibition in aqueous 0.1 M NaCl solution. The mechanism of inhibition of AA2024-T3 by the select non-chromate inhibitors was investigated using various electrochemical, microscopic and spectroscopic techniques. Naturally aerated polarization curves showed that molybdate provided mixed inhibition in near-neutral pH and at a threshold concentration of 0.1 M. The largest effect was a 250 mV increase in the breakdown potential associated with pitting and a 350 mV decrease in the open-circuit potential (OCP). In addition, electrochemical impedance indicated that the corrosion inhibition mechanism is oxygen-dependent owing to the protection afforded by Mo(VI) species. It was proposed that the corrosion inhibition of AA2024-T3 by molybdate may occur following a two-step process whereby molybdate is rapidly reduced to MoO.(OH)2 over the intermetallic particles and is subsequently oxidized to intermediate molybdenum oxides (e.g. Mo4O11) in the presence of oxygen which is reduced. This in turn may lead to a local acidification, promoting the condensation and polymerization of molybdate species in solution to form polymolybdate species (Mo7O24 6- and Mo8O264-). Furthermore, S-phase particle dissolution is decreased

  6. Polarization Studies on Inhibitory Effect of Chromates and Dichromates on Corrosion of Tin Coated Steel in 0.5M Monochloroacetic Acid

    Directory of Open Access Journals (Sweden)

    Sangita Sharma

    2008-01-01

    Full Text Available Chromates and Dichromates have been tested for its inhibitory effects towards tin coated steel in 0.5M monochloroacetic acid. The corrosion behaviour of potassium chromate, sodium chromate, potassium dichromate, sodium dichromate and ammonium dichromate was studied by polarization curves, Tafel parameters like Tafel slopes, extrapolation of cathodic Tafel line and intersection of cathodic and anodic line at open circuit potential in presence of inhibitors have been tabulated along with other electrochemical parameters and corrosion current have been calculated from Tafel lines. The efficiencies are calculated and compared reasonably well with those obtained from loss in weight data. All the inhibitors induce a significant increase of potential positive and direction accounts for cathodic polarization. The Icorr has also been calculated and that accounts well for cathodic reactions in presence of chromates and dichromates as inhibitors.

  7. Theoretical analysis and experimental verification of a cost-effective chromatic dispersion monitoring method in a 40-Gb/s optical fiber communication system

    Institute of Scientific and Technical Information of China (English)

    Yan Li; Jin Zhang; Jinlong Yu; Wencai Jing; Yimo Zhang; Ge Zhou

    2005-01-01

    A cost-effective technique for in-service chromatic dispersion monitoring in a 40-Gb/s optical communication system is proposed. Microwave devices are adopted to detect the electrical power of a specific frequency band. A simplified theoretical model is proposed and discussed focusing on the relationship between electrical power and chromatic dispersion at different frequency bands. The dynamic monitoring of chromatic dispersion is achieved using devices such as PIN detector, microwave amplifier, narrow-band microwave filter, and electrical power detector. The maximum detectable chromatic dispersion is 130 ps/nm and a resolution of 5.2 ps/nm/dB has been achieved in the frequency band centered at 12 GHz.

  8. 克莱茵瓶上奇异地图的色数%Chromatic Enumeration for Singular Maps on the Klein Bottle

    Institute of Scientific and Technical Information of China (English)

    李赵祥; 刘彦佩

    2002-01-01

    A map is singular if each edge is on the same face on a surface (i.e., ithas only one face on a surface). In this paper we present the chromatic enumerationfor rooted singular maps on the Klein bottle.

  9. Distortion-Less 610 fs Pulse Transmission over 160 km SSMF-DCF Using Wavelength Selective Switch for Compensation of Chromatic Dispersion

    DEFF Research Database (Denmark)

    Tologlou, G.; Mulvad, Hans Christian Hansen; Dalgaard, Kjeld;

    2011-01-01

    We demonstrate a nearly distortion-less transmission of 610 fs pulses over a 160 km standard-SMF span compensated by DCF, enabled by compensation of the residual higher order chromatic dispersion with a wavelength selective switch.......We demonstrate a nearly distortion-less transmission of 610 fs pulses over a 160 km standard-SMF span compensated by DCF, enabled by compensation of the residual higher order chromatic dispersion with a wavelength selective switch....

  10. New chromate-free passivation treatments for zinc, zinc alloy, and zinc-containing coatings and surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Smith, C. J. E.; King, J. E.; Wright, D. G.; Erricker, S. L.; Wilcox, G.; Treacy, G.; Hovestad, A.; Woodhead, T.; Buckland, J.; Lindsey, L.; Eruli, M.; Koelewijn, H.; Shropshire, I. [Defence Evaluation and Research Agency, Farnborough, Hampshire (United Kingdom)

    2001-07-01

    Results of a series of experiments to develop chromate-free treatments which provide the same level of corrosion protection and promote adhesion of surface coatings and paint films are discussed. The initial phase of the project identified two different treatments which prompted the investigation of pH, temperature and immersion time, as part of the effort to optimize the processes. When subjected to accelerated corrosion tests, one of the two processes (the PTA process) compared favourably with conventional chromate filming when applied to electrodeposited zinc-nickel coatings. Further investigation revealed that the process also works effectively on brass and nickel substrates and provides an appropriate substrate for the application of lacquer. Development of an effective treatment for zinc coatings, particularly hot dip galvanized zinc, is in progress. This paper discusses the results of toxicological and environmental studies conducted in conjunction with the two processes and reviews lessons learned and opportunities for exploiting the findings. 5 refs., 6 tabs.

  11. Generation of Flat Supercontinuum in a Single-mode Optical Fiber with a Convex Chromatic Dispersion Profile

    Institute of Scientific and Technical Information of China (English)

    XU Yong-zhao; WANG Hong-chen; ZHOU Shou-li

    2009-01-01

    A single-mode optical fiber with a convex chromatic dispersion profile is proposed for generating a flat supercontinuum(SC). The fiber has normal dispersion and the dispersion parameter D(λ,z) is a convex function of wavelengths. It is shown from the numerical results that the chromatic dispersion, the flatness of the dispersion curve and the pump conditions have significant effect on SC generation. A flat and broad SC without strong residual pump component can be obtained when the pump wavelength is set in the vicinity of the wavelength at which the fiber has small normal group-velocity dispersion(GVD) and small dispersion slope. The fiber with a smaller normal GVD, a flatter dispersion profile and a higher nonlinear coefficient are more suitable for broad SC generation.

  12. Improvement of the beam quality by chromaticity correction for wavelength shortening in the NIJI-IV FEL

    CERN Document Server

    Sei, N; Ohgaki, H; Litvinenko, V N; Mikado, T; Yamazaki, T

    1999-01-01

    Electron-beam qualities improved by chromaticity correction in the storage ring NIJI-IV were investigated at the beam energy of 309 MeV. Sextupole-quadrupole-sextupole (SQS) magnets, which were installed in all of the short-straight sections in NIJI-IV, perfectly corrected a horizontal and a vertical chromaticity. This improvement suppressed a head-tail instability, so that higher beam current (approx 30 mA) and higher peak-electron density (approx 6x10 sup 1 sup 6 m sup - sup 3) were available for FEL experiments. The maximum FEL gain was estimated to be about 2.5% at a wavelength of 240 nm. The lasing of an FEL around 300 nm was achieved in March 1998, and the lasing of an FEL at around 240 nm was successfully observed in May 1998. The shortest wavelength of FELs with the NIJI-IV FEL system was 228 nm.

  13. Analytical calculation of geometric and chromatic aberrations in a bi-potential electrostatic and bell-shaped magnetic combined lens

    CERN Document Server

    Ximen Ji Ye

    2000-01-01

    In the present paper, Gaussian optical property in the bi-potential electrostatic and the bell-shaped magnetic combined lens - a new theoretical model first proposed in electron optics - has been thoroughly studied. Meanwhile, based on electron optical canonical aberration theory, analytical formulas of third-order geometrical and first-order chromatic aberration coefficients and their computational results have first been derived for this bi-potential electrostatic and bell-shaped magnetic combined lens. It is to emphasized that this theoretical study can be used to estimate third-order geometric and first-order chromatic aberrations and to provide a theoretical criterion for numerical computation in a rotationally symmetric electromagnetic lens.

  14. Deciding the On-line Chromatic Number of a Graph with Pre-coloring is PSPACE-complete

    DEFF Research Database (Denmark)

    Kudahl, Christian

    2015-01-01

    In an on-line coloring, the vertices of a graph are revealed one by one. An algorithm assigns a color to each vertex after it is revealed. When a vertex is revealed, it is also revealed which of the previous vertices it is adjacent to. The on-line chromatic number of a graph, G, is the smallest...... number of colors an algorithm will need when on-line-coloring G. The algorithm may know G, but not the order in which the vertices are revealed. The problem of determining if the on-line chromatic number of a graph is less than or equal to k, given a pre-coloring, is shown to be PSPACE-complete....

  15. 类推广的Mycielski图的集合色数%The Set Chromatic Number of Similar Generalized Mycielski's Graph

    Institute of Scientific and Technical Information of China (English)

    王艳丽; 苗连英; 王敏

    2013-01-01

    In order to study the set chromatic number of graphs,a upper bound of similar generalized Mycielski' s graph was given by using the method of structure graph theory. Furthermore, the set chromatic numbers of complete graph, bipartite garph and fan graph of similar generalized Mycielski' s graphs were also put forward.%为深入研究图的集合色数,运用结构图论的方法给出任意图的类推广的Mycielski图的集合色数的上界及完全图,以及二部图和扇图的类推广的Mycielski图的集合色数.

  16. Influence of Pre- and Post-compensation of Chromatic Dispersion on Equalization Enhanced Phase Noise in Coherent Multilevel Systems

    CERN Document Server

    Jacobsen, Gunnar; Xu, Tianhua; Popov, Sergei; Friberg, Ari T; Zhang, Yimo

    2016-01-01

    In this paper we present a comparative study in order to specify the influence of equalization enhanced phase noise (EEPN) for pre- and post-compensation of chromatic dispersion in high capacity and high constellation systems. This is - to our knowledge - the first detailed study in this area for pre-compensation systems. Our main results show that the local oscillator phase noise determines the EEPN influence in post-compensation implementations whereas the transmitter laser determines the EEPN in pre-compensation implementations. As a result of significance for the implementation of practical longer-range systems it is to be emphasized that the use of chromatic dispersion equalization in the optical domain - e.g. by the use of dispersion compensation fibers - eliminates the EEPN entirely. Thus, this seems a good option for such systems operating at high constellations in the future.

  17. Strong chromatic microlensing in HE0047–1756 and SDSS1155+6346

    Energy Technology Data Exchange (ETDEWEB)

    Rojas, K.; Motta, V. [Instituto de Física y Astronomía, Universidad de Valparaíso, Avda. Gran Bretaña 1111, Playa Ancha, Valparaíso 2360102 (Chile); Mediavilla, E. [Instituto de Astrofísica de Canarias, Avda. Vía Lactea s/n, La Laguna, E-38200 Tenerife (Spain); Falco, E. [Whipple Observatory, Smithsonian Institution, 670 Mt. Hopkins Road, PO Box 6369, Amado, AZ 85645 (United States); Jiménez-Vicente, J. [Departamento de Física Teórica y del Cosmos, Universidad de Granada, Campus de Fuentenueva, E-18071 Granada (Spain); Muñoz, J. A., E-mail: karina.rojas@uv.cl, E-mail: veronica.motta@uv.cl, E-mail: emg@iac.es, E-mail: falco@cfa.harvard.edu, E-mail: jjimenez@ugr.es, E-mail: jmunoz@uv.es [Departamento de Astronomía y Astrofísica, Universidad de Valencia, Burjassot, E-46100 Valencia (Spain)

    2014-12-10

    We use spectra of the double-lensed quasars HE0047–1756 and SDSS1155+6346 to study their unresolved structure through the impact of microlensing. There is no significant evidence of microlensing in the emission line profiles except for the Lyα line of SDSS1155+6346, which shows strong differences in the shapes for images A and B. However, the continuum of the B image spectrum in SDSS1155+6346 is strongly contaminated by the lens galaxy, and these differences should be considered with caution. Using the flux ratios of the emission lines for image pairs as a baseline to remove macro-magnification and extinction, we have detected strong chromatic microlensing in the continuum measured by CASTLES (www.cfa.harvard.edu/castles/) in both lens systems, with amplitudes 0.09(λ16000) ≲ |Δm| ≲ 0.8(λ5439) for HE0047–1756, and 0.2(λ16000) ≲ |Δm| ≲ 0.8(λ5439) for SDSS1155+6346. Using magnification maps to simulate microlensing and modeling the accretion disk as a Gaussian source (I ∝ exp(–R {sup 2}/2r {sub s}{sup 2})) of size r {sub s} ∝ λ {sup p}, we find r {sub s} = 2.5{sub −1.4}{sup +3.0} √(M/0.3M{sub ⊙}) lt-day and p = 2.3 ± 0.8 at the rest frame for λ = 2045 for HE0047–1756 (log prior) and r {sub s} = 5.5{sub −3.3}{sup +8.2} √(M/0.3M{sub ⊙}) lt-day and p = 1.5 ± 0.6 at the rest frame of λ = 1398 for SDSS1155+6346 (log prior). Contrary to other studied lens systems, the chromaticity detected in HE0047–1756 and SDSS1155+6346 is large enough to fulfill the thin disk prediction. The inferred sizes, however, are very large compared to the predictions of this model, especially in the case of SDSS1155+6346.

  18. Exploration of chromatic aberration for multiplanar imaging: proof of concept with implications for fast, efficient autofocus.

    Science.gov (United States)

    Weinigel, Martin; Kellner, Albert L; Price, Jeffrey H

    2009-12-01

    Image-based autofocus determines focus directly from the specimen (as opposed to reflective surface positioning with an offset), but sequential acquisition of a stack of images to measure resolution/sharpness and find best focus is slower than reflective positioning. Simultaneous imaging of multiple focal planes, which is also useful for 3D imaging of live cells, is faster but requires complicated optics. With color CCD cameras and white light sources commonly available, we asked if axial chromatic aberration can be utilized to acquire multiple focal planes simultaneously, and if it can be controlled through a range sufficient for practical use. For proof of concept, we theoretically and experimentally explored the focal differences between three narrow wavelength bands on a 3-chip color CCD camera with and without glass inserts of various thicknesses and dispersions. Ray tracing yielded changes in foci of 0.65-0.9 microm upon insertion of 12.5-mm thick glass samples for green (G, 522 nm) vs. blue (B, 462 nm) and green vs. red (G-R, 604 nm). On a microscope: (1) With no glass inserts, the differences in foci were 2.15 microm (G-B) and 0.43 microm (G-R); (2) With glass inserts, the maximum change in foci for G vs. B was 0.44 microm and for G vs. R was 0.26 microm; and (3) An 11.3 mm thick N-BK7 glass insert shifted the foci 0.9 microm (R), 0.6 microm (G), and 0.35 microm (B), such that the B and R foci were farther apart (2.1 microm vs. 1.7 microm) and the R and G foci were closer together (0.25 microm vs. 0.45 microm). The slopes of the differences in foci were dependent on thickness, index of refraction, and dispersion. The measured differences in foci are comparable to the axial steps of 0.1-0.24 microm commonly used for autofocus, and focal plane separation can be altered by inserting optical elements of various dispersions and thicknesses. By enabling acquisition of multiple, axially offset images simultaneously, chromatic aberration, normally an imaging pariah

  19. Application of chitosan/polyacrylamide nanofibres for removal of chromate and phosphate in water

    Science.gov (United States)

    Nthumbi, Richard M.; Catherine Ngila, J.; Moodley, Brenda; Kindness, Andrew; Petrik, Leslie

    Water pollution is an intractable environmental problem in South Africa. Management of the water resource is vital in order to address the water scarcity issues. Research on remediation of contaminated water has focused mainly on the removal of heavy metals such as Pb, Cd, Zn, Hg and Cu and neglected other inorganic pollutants. In this work we focus on the removal of anions, namely chromate and phosphate. Chromium is extensively used in the textile, leather and metallurgy industries and contaminates surface water and groundwater when inadequately treated industrial effluents are discharged. Chromium has been associated with irregular sugar metabolism, nosebleeds and ulcers, and it is also carcinogenic. The phosphate ion is an essential micronutrient responsible for healthy plant growth. However, excess phosphate intake stimulates rapid growth of photosynthetic algae and cyanobacteria, resulting in eutrophication. This phenomenon (algal bloom) causes other organisms to die due to reduced oxygen in the water. In order to offer remediation measures, this study reports the use of electrospun nanofibres for the removal of chromate and phosphate anions. Adsorption experiments were carried out using nanofibres electrospun from chitosan and polyacrylamide polymer blends, cross-linked with glutaraldehyde. Quantification of chromium was done using ICP-OES while UV-Vis spectrophotometry was used for the determination of phosphates. Batch adsorption experiments were done to determine optimum adsorption parameters such as pH, contact time, temperature and initial analyte concentration. Removal of the ions using a flow-adsorption technique through a micro-column was performed. The experimental data obtained were analysed using Langmuir and Freundlich models to study the adsorption mechanisms. The nanofibres had an adsorption capacity for Cr(VI) and PO43- of 0.26 mg g-1 and 392 mg g-1, respectively, and removal efficiencies of 93% and 97.4%, in the same order, in synthetic water

  20. Paper-based chromatic toxicity bioassay by analysis of bacterial ferricyanide reduction.

    Science.gov (United States)

    Pujol-Vila, F; Vigués, N; Guerrero-Navarro, A; Jiménez, S; Gómez, D; Fernández, M; Bori, J; Vallès, B; Riva, M C; Muñoz-Berbel, X; Mas, J

    2016-03-03

    Water quality assessment requires a continuous and strict analysis of samples to guarantee compliance with established standards. Nowadays, the increasing number of pollutants and their synergistic effects lead to the development general toxicity bioassays capable to analyse water pollution as a whole. Current general toxicity methods, e.g. Microtox(®), rely on long operation protocols, the use of complex and expensive instrumentation and sample pre-treatment, which should be transported to the laboratory for analysis. These requirements delay sample analysis and hence, the response to avoid an environmental catastrophe. In an attempt to solve it, a fast (15 min) and low-cost toxicity bioassay based on the chromatic changes associated to bacterial ferricyanide reduction is here presented. E. coli cells (used as model bacteria) were stably trapped on low-cost paper matrices (cellulose-based paper discs, PDs) and remained viable for long times (1 month at -20 °C). Apart from bacterial carrier, paper matrices also acted as a fluidic element, allowing fluid management without the need of external pumps. Bioassay evaluation was performed using copper as model toxic agent. Chromatic changes associated to bacterial ferricyanide reduction were determined by three different transduction methods, i.e. (i) optical reflectometry (as reference method), (ii) image analysis and (iii) visual inspection. In all cases, bioassay results (in terms of half maximal effective concentrations, EC50) were in agreement with already reported data, confirming the good performance of the bioassay. The validation of the bioassay was performed by analysis of real samples from natural sources, which were analysed and compared with a reference method (i.e. Microtox). Obtained results showed agreement for about 70% of toxic samples and 80% of non-toxic samples, which may validate the use of this simple and quick protocol in the determination of general toxicity. The minimum instrumentation

  1. Removal of toxic ions (chromate, arsenate, and perchlorate) using reverse osmosis, nanofiltration, and ultrafiltration membranes

    KAUST Repository

    Yoon, Jaekyung

    2009-09-01

    Rejection characteristics of chromate, arsenate, and perchlorate were examined for one reverse osmosis (RO, LFC-1), two nanofiltration (NF, ESNA, and MX07), and one ultrafiltration (UF and GM) membranes that are commercially available. A bench-scale cross-flow flat-sheet filtration system was employed to determine the toxic ion rejection and the membrane flux. Both model and natural waters were used to prepare chromate, arsenate, and perchlorate solutions (approximately 100 μg L-1 for each anion) in mixtures in the presence of other salts (KCl, K2SO4, and CaCl2); and at varying pH conditions (4, 6, 8, and 10) and solution conductivities (30, 60, and 115 mS m-1). The rejection of target ions by the membranes increases with increasing solution pH due to the increasingly negative membrane charge with synthetic model waters. Cr(VI), As(V), and ClO4 - rejection follows the order LFC-1 (>90%) > MX07 (25-95%) ≅ ESNA (30-90%) > GM (3-47%) at all pH conditions. In contrast, the rejection of target ions by the membranes decreases with increasing solution conductivity due to the decreasingly negative membrane charge. Cr(VI), As(V), and ClO4 - rejection follows the order CaCl2 < KCl ≅ K2SO4 at constant pH and conductivity conditions for the NF and UF membranes tested. For natural waters the LFC-1 RO membrane with a small pore size (0.34 nm) had a significantly greater rejection for those target anions (>90%) excluding NO3 - (71-74%) than the ESNA NF membrane (11-56%) with a relatively large pore size (0.44 nm), indicating that size exclusion is at least partially responsible for the rejection. The ratio of solute radius (ri,s) to effective membrane pore radius (rp) was employed to compare ion rejection. For all of the ions, the rejection is higher than 70% when the ri,s/rp ratio is greater than 0.4 for the LFC-1 membrane, while for di-valent ions (CrO4 2 -, SO4 2 -, and HAsSO4 2 -) the rejection (38-56%) is fairly proportional to the ri,s/rp ratio (0.32-0.62) for the ESNA

  2. Chromatic aberration and the roles of double-opponent and color-luminance neurons in color vision.

    Science.gov (United States)

    Vladusich, Tony

    2007-03-01

    How does the visual cortex encode color? I summarize a theory in which cortical double-opponent color neurons perform a role in color constancy and a complementary set of color-luminance neurons function to selectively correct for color fringes induced by chromatic aberration in the eye. The theory may help to resolve an ongoing debate concerning the functional properties of cortical receptive fields involved in color coding.

  3. Proteogenomic and functional analysis of chromate reduction in Acidiphilium cryptum JF-5, an Fe(III)-respiring acidophile.

    Science.gov (United States)

    Magnuson, Timothy S; Swenson, Michael W; Paszczynski, Andrzej J; Deobald, Lee A; Kerk, David; Cummings, David E

    2010-12-01

    Acidiphilium cryptum JF-5, an acidophilic iron-respiring Alphaproteobacterium, has the ability to reduce chromate under aerobic and anaerobic conditions, making it an intriguing and useful model organism for the study of extremophilic bacteria in bioremediation applications. Genome sequence annotation suggested two potential mechanisms of Cr(VI) reduction, namely, a number of c-type cytochromes, and a predicted NADPH-dependent Cr(VI) reductase. In laboratory studies using pure cultures of JF-5, an NADPH-dependent chromate reductase activity was detected primarily in soluble protein fractions, and a periplasmic c-type cytochrome (ApcA) was also present, representing two potential means of Cr(VI) reduction. Upon further examination, it was determined that the NADPH-dependent activity was not specific for Cr(VI), and the predicted proteins were not detected in Cr(VI)-grown cultures. Proteomic data did show measureable amounts of ApcA in cells grown with Cr(VI). Purified ApcA is reducible by menadiol, and in turn can reduce Cr(VI), suggesting a means to obtain electrons from the respiratory chain and divert them to Cr(VI). Electrochemical measurements confirm that Cr reduction by ApcA is pH dependent, with low pH being favored. Homology modeling of ApcA and comparison to a known Cr(VI)-reducing c-type cytochrome structure revealed basic amino acids which could interact with chromate ion. From these studies, it can be concluded that A. cryptum has the physiologic and genomic capability to reduce Cr(VI) to the less toxic Cr(III). However, the expected chromate reductase mechanism may not be the primary means of Cr(VI) reduction in this organism.

  4. A Novel Mechanism for Color Vision: Pupil Shape and Chromatic Aberration Can Provide Spectral Discrimination for Color Blind Organisms.

    OpenAIRE

    Stubbs, Alexander L.; Stubbs, Christopher William

    2016-01-01

    We present a mechanism by which organisms with only a single photoreceptor, that have a monochromatic view of the world, can achieve color discrimination. The combination of an off axis pupil and the principle of chromatic aberration (where light of different colors focus at different distances behind a lens) can combine to provide color-blind animals with a way to distinguish colors. As a specific example we constructed a computer model of the visual system of cephalopods, (octopus, squid, a...

  5. Coupling of cerebral blood flow and oxygen metabolism is conserved for chromatic and luminance stimuli in human visual cortex.

    Science.gov (United States)

    Leontiev, Oleg; Buracas, Giedrius T; Liang, Christine; Ances, Beau M; Perthen, Joanna E; Shmuel, Amir; Buxton, Richard B

    2013-03-01

    The ratio of the changes in cerebral blood flow (CBF) and cerebral metabolic rate of oxygen (CMRO(2)) during brain activation is a critical determinant of the magnitude of the blood oxygenation level dependent (BOLD) response measured with functional magnetic resonance imaging (fMRI). Cytochrome oxidase (CO), a key component of oxidative metabolism in the mitochondria, is non-uniformly distributed in visual area V1 in distinct blob and interblob regions, suggesting significant spatial variation in the capacity for oxygen metabolism. The goal of this study was to test whether CBF/CMRO(2) coupling differed when these subpopulations of neurons were preferentially stimulated, using chromatic and luminance stimuli to preferentially stimulate either the blob or interblob regions. A dual-echo spiral arterial spin labeling (ASL) technique was used to measure CBF and BOLD responses simultaneously in 7 healthy human subjects. When the stimulus contrast levels were adjusted to evoke similar CBF responses (mean 65.4% ± 19.0% and 64.6% ± 19.9%, respectively for chromatic and luminance contrast), the BOLD responses were remarkably similar (1.57% ± 0.39% and 1.59% ± 0.35%) for both types of stimuli. We conclude that CBF-CMRO(2) coupling is conserved for the chromatic and luminance stimuli used, suggesting a consistent coupling for blob and inter-blob neuronal populations despite the difference in CO concentration.

  6. Now you see me, now you don't: iridescence increases the efficacy of lizard chromatic signals

    Science.gov (United States)

    Pérez i de Lanuza, Guillem; Font, Enrique

    2014-10-01

    The selective forces imposed by primary receivers and unintended eavesdroppers of animal signals often act in opposite directions, constraining the development of conspicuous coloration. Because iridescent colours change their chromatic properties with viewer angle, iridescence offers a potential mechanism to relax this trade-off when the relevant observers involved in the evolution of signal design adopt different viewer geometries. We used reflectance spectrophotometry and visual modelling to test if the striking blue head coloration of males of the lizard Lacerta schreibeiri (1) is iridescent and (2) is more conspicuous when viewed from the perspective of conspecifics than from that of the main predators of adult L. schreibeiri (raptors). We demonstrate that the blue heads of L. schreiberi show angle-dependent changes in their chromatic properties. This variation allows the blue heads to be relatively conspicuous to conspecific viewers located in the same horizontal plane as the sender, while simultaneously being relatively cryptic to birds that see it from above. This study is the first to suggest the use of angle-dependent chromatic signals in lizards, and provides the first evidence of the adaptive function of iridescent coloration based on its detectability to different observers.

  7. Effect of radiation on hydrotalcites with chromates; Efecto de la radiacion en hidrotalcitas con cromatos

    Energy Technology Data Exchange (ETDEWEB)

    Martinez G, S.; Bulbulian, S. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    2002-07-01

    Nowadays the generation of radioactive wastes is matter of several studies. In this work anion material, chromates, in hydrotalcite are retained which are anion exchangers. It was proposed to heat the hydrotalcite until temperature of 1200 C with the purpose to form the (MgAl{sub 2}O{sub 4}) spinel is very stable and in this way to immobilize strongly the anions. The effect of radiation on this compound and in particular the chromium lixiviation with solution 1N NaCl. It was found that in all case, the anions are strongly retained in the spinel formed. The radiation dose used for this was 100 Mrad, the samples were treated with NaCl 1N for studying the Cr lixiviation. The results show that for the calcined samples at 1200 C and irradiated there are not chromium escapes, which indicates that it is strongly retained in the spinel that is the formed structure after of the material calcination. (Author)

  8. Novel Chromatic Technique Based on Optical Absorbance in Characterizing Mineral Hydraulic Oil Degradation

    Directory of Open Access Journals (Sweden)

    C. V. Ossia

    2012-01-01

    Full Text Available A low cost, compact, real-time, and quick measurement optical device based on the absorbance of white light, which comprised of photodiodes in a 3-element color-sensor, feedback diodes, water and temperature sensing element, and so on, was developed and tested in low absorption mineral oil. The device, a deviation from conventional electrical, mechanical, and electrochemical techniques, uses color ratio (CR and total contamination index (TCI parameters based on transmitted light intensity in RGB wavelengths for oil condition monitoring. Test results showed that CR corroborated CIE chromaticity (- Coordinates and increased with oil degradation unlike Saturation and Hue . CR was found to be independent of the particulate contaminants of oil, but dependent on chemical degradation. TCI depended on both chemical degradation and particulate contaminants in oil, being most sensitive in the blue wavelength range and least in the green. Furthermore, results agreed with those of viscometry, total acid number (TAN, and UV-VIS photospectrometry. CR and TCI gave clearer indication of oil degradation than key monitoring parameters like TAN and were found to be effective criteria for characterizing the degradation of hydraulic mineral oils.

  9. Fiber over Wireless Chromatic Dispersion Compensation for a Better Quality of Service

    Directory of Open Access Journals (Sweden)

    Razzak M

    2006-01-01

    Full Text Available "Anywhere" and, in particular, "anyhow": these are the two best words that can describe an ad hoc wireless network that is due to the increasing demand for connectivity in such an information society. Ad hoc wireless networks can be described as dynamic multihop wireless networks with mobile nodes. However, the mobility condition can be relaxed, and we can consider an ad hoc wireless network as a reconfigurable network where all the nodes are connected to the local environment through wireless links, and where there is not a central or dominant node—as opposed to, for example, the case of cellular wireless networks where a base station is located in each cell. When ad hoc networks are backboned by fibers, distortion of the optical link presents one of the major issues. In this paper, we will be addressing one of the fundamental problems, namely, chromatic dispersion in the fiber optic prior reaching the access points. This will ensure an adequate quality of service (QoS.

  10. Color matrix display simulation based upon luminance and chromatic contrast sensitivity of early vision

    Science.gov (United States)

    Martin, Russel A.; Ahumada, Albert J., Jr.; Larimer, James O.

    1992-01-01

    This paper describes the design and operation of a new simulation model for color matrix display development. It models the physical structure, the signal processing, and the visual perception of static displays, to allow optimization of display design parameters through image quality measures. The model is simple, implemented in the Mathematica computer language, and highly modular. Signal processing modules operate on the original image. The hardware modules describe backlights and filters, the pixel shape, and the tiling of the pixels over the display. Small regions of the displayed image can be visualized on a CRT. Visual perception modules assume static foveal images. The image is converted into cone catches and then into luminance, red-green, and blue-yellow images. A Haar transform pyramid separates the three images into spatial frequency and direction-specific channels. The channels are scaled by weights taken from human contrast sensitivity measurements of chromatic and luminance mechanisms at similar frequencies and orientations. Each channel provides a detectability measure. These measures allow the comparison of images displayed on prospective devices and, by that, the optimization of display designs.

  11. Chromate enhanced visible light driven TiO₂ photocatalytic mechanism on Acid Orange 7 photodegradation.

    Science.gov (United States)

    Wang, Yeoung-Sheng; Shen, Jyun-Hong; Horng, Jao-Jia

    2014-06-15

    When hexavalent chromium (Cr(VI)) is added to a TiO2 photocatalytic reaction, the decolorization and mineralization efficiencies of azo dyes Acid Orange 7 (AO7) are enhanced even though the mechanism is unclear. This study used 5,5-dimethyl-l-pyrroline-N-oxide (DMPO) as the scavenger and the analysis of Electron Spin Resonance (ESR) to investigate this enhancement effect by observing the hydroxyl radical (OH) generation of the Cr(VI)/TiO2 system under UV and visible light (Vis) irradiation. With Cr(VI), the decolorization efficiencies were approximately 95% and 62% under UV and Vis, and those efficiencies were 25% less in the absence of Cr(VI). The phenomena of the DMPO-OH signals during the ESR analysis under Vis 405 and 550 nm irradiation were obviously the enhancement effects of Cr(VI) in aerobic conditions. In anoxic conditions, the catalytic effects of Cr(VI) could not be achieved due to the lack of a redox reaction between Cr(VI) and the adsorbed oxygen at the oxygen vacancy sites on the TiO2 surfaces. The results suggest that by introducing the agents of redox reactions such as chromate ions, we could lower the photoenergy of TiO2 needed and allow Vis irradiation to activate photocatalysis.

  12. Modeling oxyanion adsorption on ferralic soil, part 2: chromate, selenate, molybdate, and arsenate adsorption.

    Science.gov (United States)

    Pérez, Claudio; Antelo, Juan; Fiol, Sarah; Arce, Florencio

    2014-10-01

    High levels of oxyanions are found in the soil environment, often as a result of human activity. At high concentrations, oxyanions can be harmful to both humans and wildlife. Information about the interactions between oxyanions and natural samples is essential for understanding the bioavailability, toxicity, and transport of these compounds in the environment. In the present study, the authors investigated the reactivity of different oxyanions (AsO4 , MoO4 , SeO4 , and CrO4 ) at different pH values in 2 horizons of a ferralic soil. By combining available microscopic data on iron oxides with the macroscopic data obtained, the authors were able to use the charge distribution model to accurately describe the adsorption of these 4 oxyanions and thus to determine the surface speciation. The charge distribution model was previously calibrated and evaluated using phosphate adsorption/desorption data. The adsorption behavior on ferralic soil is controlled mainly by the natural iron oxides present, and it is qualitatively analogous to that exhibited by synthetic iron oxides. The highest adsorption was found for arsenate ions, whereas the lowest was found for selenate, with chromate and molybdate ions showing an intermediate behavior.

  13. Arsenic and chromate removal from water by iron chips-Effects of anions

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The purpose of this study is to estimate the removal efficiency of As and Cr (Ⅵ) by one kind of indus trial waste - iron chips,as well as to estimate the effects of typical inorganic anions (sulfate,phosphate,and nitrate),and typical organic anions (citrate,oxalate,and humate) on As or Cr (Ⅵ) removal.The results showed that 98% of As (Ⅴ) and 92% of As (Ⅲ) could be removed from aque ous phase by the iron chips within 60 min.Compared with As species,Cr (Ⅵ) was removed much more rapidly and efficiently with 97% of Cr (Ⅵ) being removed within 25 min.The removal efficiency for arsenic was in the order:As (Ⅲ) (sulfate),As (Ⅲ) (nitrate) or As (Ⅲ),As (Ⅲ) (humate),As (Ⅲ) (oxalate),As (Ⅲ) (citrate),As (Ⅲ)(phosphate),and for chromate was in the order:Cr (Ⅵ)(sulfate),Cr (Ⅵ) (phosphate) or Cr (Ⅵ) (nitrate) or Cr (Ⅵ) (oxalate),Cr (Ⅵ),Cr (Ⅵ) (citrate),Cr (Ⅵ) (humate).In all the treatments,pH level increased with time except for As (Ⅲ),the removal of which was either without anions or in the presence of humate or nitrate.

  14. Non-destructive forensic latent fingerprint acquisition with chromatic white light sensors

    Science.gov (United States)

    Leich, Marcus; Kiltz, Stefan; Dittmann, Jana; Vielhauer, Claus

    2011-02-01

    Non-destructive latent fingerprint acquisition is an emerging field of research, which, unlike traditional methods, makes latent fingerprints available for additional verification or further analysis like tests for substance abuse or age estimation. In this paper a series of tests is performed to investigate the overall suitability of a high resolution off-the-shelf chromatic white light sensor for the contact-less and non-destructive latent fingerprint acquisition. Our paper focuses on scanning previously determined regions with exemplary acquisition parameter settings. 3D height field and reflection data of five different latent fingerprints on six different types of surfaces (HDD platter, brushed metal, painted car body (metallic and non-metallic finish), blued metal, veneered plywood) are experimentally studied. Pre-processing is performed by removing low-frequency gradients. The quality of the results is assessed subjectively; no automated feature extraction is performed. Additionally, the degradation of the fingerprint during the acquisition period is observed. While the quality of the acquired data is highly dependent on surface structure, the sensor is capable of detecting the fingerprint on all sample surfaces. On blued metal the residual material is detected; however, the ridge line structure dissolves within minutes after fingerprint placement.

  15. Chromatic illumination discrimination ability reveals that human colour constancy is optimised for blue daylight illuminations.

    Directory of Open Access Journals (Sweden)

    Bradley Pearce

    Full Text Available The phenomenon of colour constancy in human visual perception keeps surface colours constant, despite changes in their reflected light due to changing illumination. Although colour constancy has evolved under a constrained subset of illuminations, it is unknown whether its underlying mechanisms, thought to involve multiple components from retina to cortex, are optimised for particular environmental variations. Here we demonstrate a new method for investigating colour constancy using illumination matching in real scenes which, unlike previous methods using surface matching and simulated scenes, allows testing of multiple, real illuminations. We use real scenes consisting of solid familiar or unfamiliar objects against uniform or variegated backgrounds and compare discrimination performance for typical illuminations from the daylight chromaticity locus (approximately blue-yellow and atypical spectra from an orthogonal locus (approximately red-green, at correlated colour temperature 6700 K, all produced in real time by a 10-channel LED illuminator. We find that discrimination of illumination changes is poorer along the daylight locus than the atypical locus, and is poorest particularly for bluer illumination changes, demonstrating conversely that surface colour constancy is best for blue daylight illuminations. Illumination discrimination is also enhanced, and therefore colour constancy diminished, for uniform backgrounds, irrespective of the object type. These results are not explained by statistical properties of the scene signal changes at the retinal level. We conclude that high-level mechanisms of colour constancy are biased for the blue daylight illuminations and variegated backgrounds to which the human visual system has typically been exposed.

  16. Restoration of distorted colour microscopic images from transverse chromatic aberration of imperfect lenses.

    Science.gov (United States)

    Wu, H-S; Murray, J; Morgello, S; Fiel, M I; Schiano, T; Kalir, T; Deligdisch, L; Gil, J

    2011-02-01

    An algorithm is presented for restoration of colour microscopic images with distortions from imperfect microscope lenses having transverse chromatic aberrations, resulting in a magnification that slightly varies with wavelengths or colours. The differential of each colour component image is computed as the difference between the component image and its slightly magnified version. The absolute values in the differential component images are generally higher at the edges where greater discontinuities occur. The two cross-correlation functions of the absolute differentials between red and green colours and between red and blue colours are then computed. The maximum in the two cross-correlation functions were sought, respectively, and the cross-correlation delays were then calculated. The two cross-correlation delays were used to determine dispersions and to realign the three colour components. Results of real microscopic images are provided. The restored image and the original are compared both visually and quantitatively in terms of the estimated entropies measured for the degree of concentrations using vector distributions.

  17. Transverse chromatic aberration across the visual field of the human eye.

    Science.gov (United States)

    Winter, Simon; Sabesan, Ramkumar; Tiruveedhula, Pavan; Privitera, Claudio; Unsbo, Peter; Lundström, Linda; Roorda, Austin

    2016-11-01

    The purpose of this study was to measure the transverse chromatic aberration (TCA) across the visual field of the human eye objectively. TCA was measured at horizontal and vertical field angles out to ±15° from foveal fixation in the right eye of four subjects. Interleaved retinal images were taken at wavelengths 543 nm and 842 nm in an adaptive optics scanning laser ophthalmoscope (AOSLO). To obtain true measures of the human eye's TCA, the contributions of the AOSLO system's TCA were measured using an on-axis aligned model eye and subtracted from the ocular data. The increase in TCA was found to be linear with eccentricity, with an average slope of 0.21 arcmin/degree of visual field angle (corresponding to 0.41 arcmin/degree for 430 nm to 770 nm). The absolute magnitude of ocular TCA varied between subjects, but was similar to the resolution acuity at 10° in the nasal visual field, encompassing three to four cones. Therefore, TCA can be visually significant. Furthermore, for high-resolution imaging applications, whether visualizing or stimulating cellular features in the retina, it is important to consider the lateral displacements between wavelengths and the variation in blur over the visual field.

  18. Effects of ocular transverse chromatic aberration on near foveal letter recognition.

    Science.gov (United States)

    Yang, Shun-nan; Tai, Yu-chi; Laukkanen, Hannu; Sheedy, James

    2009-11-01

    Transverse chromatic aberration (TCA) smears retinal images of peripheral stimuli. In reading, text information is extracted from both foveal and near fovea, where TCA magnitude is relatively small and variable. The present study investigated whether TCA significantly affects near foveal letter identification. Subjects were briefly presented a string of five letters centered one degree of visual angle to the left or right of fixation. They indicated whether the middle letter was the same as a comparison letter subsequently presented. Letter strings were rendered with a reddish fringe on the left edge of each letter and a bluish fringe on the right edge, consistent with expected left periphery TCA, or with the opposite fringe consistent with expected right periphery TCA. Effect of the color fringing on letter recognition was measured by comparing the response accuracy for fringed and non-fringed stimuli. Effects of lateral interference were examined by manipulating inter-letter spacing and similarity of neighboring letters. Results demonstrated significantly improved response accuracy with the color fringe opposite to the expected TCA, but decreased accuracy when consistent with it. Narrower letter spacing exacerbated the effect of the color fringe, whereas letter similarity did not. Our results suggest that TCA significantly reduces the ability to recognize letters in the near fovea by impeding recognition of individual letters and by enhancing lateral interference between letters.

  19. Correction of axial and lateral chromatic aberration with false color filtering.

    Science.gov (United States)

    Chang, Joonyoung; Kang, Hee; Kang, Moon Gi

    2013-03-01

    In this paper, we propose a chromatic aberration (CA) correction algorithm based on a false color filtering technique. In general, CA produces color distortions called color fringes near the contrasting edges of captured images, and these distortions cause false color artifacts. In the proposed method, a false color filtering technique is used to filter out the false color components from the chroma-signals of the input image. The filtering process is performed with the adaptive weights obtained from both the gradient and color differences, and the weights are designed to reduce the various types of color fringes regardless of the colors of the artifacts. Moreover, as preprocessors of the filtering process, a transient improvement (TI) technique is applied to enhance the slow transitions of the red and blue channels that are blurred by the CA. The TI process improves the filtering performance by narrowing the false color regions before the filtering process when severe color fringes (typically purple fringes) occur widely. Last, the CA-corrected chroma-signal is combined with the TI chroma-signal to avoid incorrect color adjustment. The experimental results show that the proposed method substantially reduces the CA artifacts and provides natural-looking replacement colors, while it avoids incorrect color adjustment.

  20. Multi-color Shallow Decay and Chromatic Breaks in the GRB 050319 Optical Afterglow

    CERN Document Server

    Huang, K Y; Kuo, P H; Ip, W H; Ioka, K; Aoki, T; Chen, C W; Chen, W P; Isogai, M; Lin, H C; Makishima, K; Mito, H; Miyata, T; Nakada, Y; Nishiura, S; Onda, K; Qiu, Y; Soyano, T; Tamagawa, T; Tarusawa, K; Tashiro, M; Yoshioka, T

    2006-01-01

    Multi-wavelength B, V, R, I observations of the optical afterglow of GRB 050319 were performed by the 1.05-m telescope at Kiso Observatory and the 1.0-m telescope at Lulin Observatory from 1.31 hours to 9.92 hours after the burst. Our R band lightcurves, combined with other published data, can be described by the smooth broken power-law function, with $\\alpha_1$ = -0.84 $\\pm$0.02 to $\\alpha_2$ = -0.48$\\pm$0.03, 0.04 days after the GRB. The optical lightcurves are characterized by shallow decays-- as was also observed in the X-rays-- which may have a similar origin, related to energy injection. However, our observations indicate that there is still a puzzle concerning the chromatic breaks in the R band lightcurve (at 0.04 days) and the X-ray lightcurve (at 0.004 days) that remains to be solved.

  1. Differences of Longitudinal Chromatic Aberration (LCA) between Eyes with Intraocular Lenses from Different Manufacturers.

    Science.gov (United States)

    Nakajima, Masashi; Hiraoka, Takahiro; Yamamoto, Toshiya; Takagi, Seiu; Hirohara, Yoko; Oshika, Tetsuro; Mihashi, Toshifumi

    2016-01-01

    Several researchers have studied the longitudinal chromatic aberration (LCA) of eyes implanted with an intraocular lens (IOL). We investigated the LCA of eyes implanted with yellow-colored IOLs from three different manufacturers: Alcon Inc., HOYA Corp., and AMO Inc. The number of subjects was 11, 16, and 16, respectively. The LCA of eyes implanted with SN60WF and SN60AT (Alcon Inc.), and with XY-1 (HOYA Corp.), was the same as that of phakic eyes. The LCA of eyes with ZCB00V (AMO Inc.) was smaller than that of phakic eyes. The LCA of eyes implanted with Alcon's and HOYA's IOLs, but not the LCA of eyes implanted with AMO's IOLs, was positively correlated with the powers of the IOLs. We also performed simulations to verify the impacts of LCA on visual performance for 4-mm pupil diameter; the simulations were a polychromatic modulation transfer function (MTF) and a visual Strehl ratio computed on the basis of an optical transfer function (VSOTF). We concluded that the differences between the LCA of different manufacturers do not affect visual performances when some extent of higher-order aberration (HOA) exists. The smaller HOA of AMO IOLs may enhance visual performance.

  2. Simultaneous removal of nitrate and chromate in groundwater by a spiral fiber based biofilm reactor.

    Science.gov (United States)

    Zhai, Siyuan; Zhao, Yinxin; Ji, Min; Qi, Wenfang

    2017-05-01

    A spiral fiber based biofilm reactor was developed to remove nitrate and chromate simultaneously. The denitrification and Cr(VI) removal efficiency was evaluated with synthetic groundwater (NO3(-)-N=50mg/L) under different Cr(VI) concentrations (0-1.0mg/L), carbon nitrogen ratios (C/N) (0.8-1.2), hydraulic retention times (HRT) (2-16h) and initial pHs (4-10). Nitrate and Cr(VI) were completely removed without nitrite accumulation when the Cr(VI) concentration was lower than 0.4mg/L. As Cr(VI) up to 1.0mg/L, the system was obviously inhibited, but it recovered rapidly within 6days due to the strong adaption and domestication of microorganisms in the biofilm reactor. The results demonstrated that high removal efficiency of nitrate (≥99%) and Cr(VI) (≥95%) were achieved at lower C/N=0.9, HRT=8h, initial pH=7, and Cr(VI)=1.0mg/L. The technology proposed in present study can be alternative for simultaneous removal of co-contaminants in groundwater.

  3. Chromatic and surface alterations in enamel subjected to brushing with desensitizing whitening toothpaste

    Directory of Open Access Journals (Sweden)

    Gabriela Queiroz de Melo Monteiro

    2016-01-01

    Full Text Available Aim: This study evaluated the chromatic and surface changes on enamel after toothbrushing with whitening and desensitizing toothpaste. Materials and Methods: Sixty enamel blocks were prepared, pigmented, and stratified according to initial Knoop microhardness and divided into six groups. The average roughness (Ra was determined from two readings. After 24 h in artificial saliva, 10,000 cycles of simulated brushing were applied. The Ra was measured after 5000 and 10,000 cycles, and tooth wear was determined. The mean roughness was evaluated, and tooth color was recorded before and after treatment. Results: Brushing with dentifrices increased the roughness of enamel in all groups. It was lower for Colgate Sensitive Pro-Relief + Bleaching, Colgate maximum protection anti-caries, and the control group. Greater roughness was observed in dentifrices containing silica. Greater wear was found with Sensodyne bleaching extra fresh and in the control group. The best bleaching effect was found with Colgate Sensitive Pro-Relief + Bleaching. Colgate Sensitive Whitening, Oral-B Pro-Health Whitening, and Sensodyne Whitening Extra Fresh showed major changes on surface roughness. Conclusion: The physical characteristics of the minerals of the toothpaste appear to be the major determinant of dental abrasion, not their quantity or whitening capacity, or rather their ability to remove enamel surface stains.

  4. Chromatic illumination discrimination ability reveals that human colour constancy is optimised for blue daylight illuminations.

    Science.gov (United States)

    Pearce, Bradley; Crichton, Stuart; Mackiewicz, Michal; Finlayson, Graham D; Hurlbert, Anya

    2014-01-01

    The phenomenon of colour constancy in human visual perception keeps surface colours constant, despite changes in their reflected light due to changing illumination. Although colour constancy has evolved under a constrained subset of illuminations, it is unknown whether its underlying mechanisms, thought to involve multiple components from retina to cortex, are optimised for particular environmental variations. Here we demonstrate a new method for investigating colour constancy using illumination matching in real scenes which, unlike previous methods using surface matching and simulated scenes, allows testing of multiple, real illuminations. We use real scenes consisting of solid familiar or unfamiliar objects against uniform or variegated backgrounds and compare discrimination performance for typical illuminations from the daylight chromaticity locus (approximately blue-yellow) and atypical spectra from an orthogonal locus (approximately red-green, at correlated colour temperature 6700 K), all produced in real time by a 10-channel LED illuminator. We find that discrimination of illumination changes is poorer along the daylight locus than the atypical locus, and is poorest particularly for bluer illumination changes, demonstrating conversely that surface colour constancy is best for blue daylight illuminations. Illumination discrimination is also enhanced, and therefore colour constancy diminished, for uniform backgrounds, irrespective of the object type. These results are not explained by statistical properties of the scene signal changes at the retinal level. We conclude that high-level mechanisms of colour constancy are biased for the blue daylight illuminations and variegated backgrounds to which the human visual system has typically been exposed.

  5. Effect of chromated copper arsenate structures on adjacent soil arsenic concentrations.

    Science.gov (United States)

    Patch, Steven C; Scheip, Katherine; Brooks, Billy

    2011-06-01

    Structures made of chromated copper arsenic (CCA) have been shown to leach arsenic into the surrounding soil. Soil cores were taken adjacent to six CCA decks at 0, 15, 60 and 300 cm from the deck at depths of 0-10, 10-20, and 20-30 cm, and were analyzed for soil arsenic concentrations. Median soil arsenic concentrations ranged from 1.8 μg/g at a depth of 10-20 cm and a distance of 300 cm to 34.5 μg/g at a depth of 0-10 cm and a distance of 30 cm. Soil arsenic concentrations taken at depths of 0-10 and 10-20 cm decreased as distance from the deck increased. Soil arsenic concentrations close to the deck were higher at lower soil depths and at homes with greater deck wipe arsenic concentrations. Age of deck and slope of land had significant effects on the differences in arsenic concentrations between samples taken at different distances when evaluated in models by themselves, but not in models adjusting for deck wipe concentrations. Size of deck and bulk density of soil did not have significant effects on soil arsenic concentrations.

  6. Construction of a Miniaturized Chromatic Acclimation Sensor from Cyanobacteria with Reversed Response to a Light Signal

    Science.gov (United States)

    Nakajima, Mitsuharu; Ferri, Stefano; Rögner, Matthias; Sode, Koji

    2016-11-01

    Cyanobacteria harbor unique photoreceptors, designated as cyanobacteriochromes (CBCRs). In this study, we attempted to engineer the chromatic acclimation sensor CcaS, a CBCR derived from the cyanobacterium Synechocystis sp. PCC 6803. The wild-type CcaS induces gene expression under green light illumination and represses it under red light illumination. We focused on the domain structure of CcaS, which consists of an N-terminal transmembrane helix; a GAF domain, which serves as the sensor domain; a linker region (L1); two PAS domains; a second linker region (L2); and a C-terminal histidine kinase (HK) domain. Truncated versions of the photoreceptor were constructed by removing the L1 linker region and the two PAS domains, and fusing the GAF and HK domains with a truncated linker region. Thus constructed “miniaturized CcaSs” were grouped into four distinct categories according to their responses toward green and red light illumination, with some showing improved gene regulation compared to the wild type. Remarkably, one of the miniaturized CcaSs induced gene expression under red light and repressed it under green light, a reversed response to the light signal compared to wild type CcaS. These characteristics of engineered photoreceptors were discussed by analyzing the CcaS structural model.

  7. Arsenic and chromium partitioning in a podzolic soil contaminated by chromated copper arsenate

    Energy Technology Data Exchange (ETDEWEB)

    Nico, Peter; Hopp, Luisa; Nico, Peter S.; Marcus, Matthew A.; Peiffer, Stefan

    2008-06-01

    This research combined the use of selective extractions and x-ray spectroscopy to examine the fate of As and Cr in a podzolic soil contaminated by chromated copper arsenate (CCA). Iron was enriched in the upper 30 cm due to a previous one-time treatment of the soil with Fe(II). High oxalate-soluble Al concentrations in the Bs horizon of the soil and micro-XRD data indicated the presence of short-range ordered aluminosilicates (i.e. proto-imogolite allophane, PIA). In the surface layers, Cr, as Cr(III), was partitioned between a mixed Fe(III)/Cr(III) solid phase that formed upon the Fe(II) application (25-50%) and a recalcitrant phase (50-75%) likely consisting of organic material such as residual CCA-treated wood. Deeper in the profile Cr appeared to be largely in the form of extractable (hydr)oxides. Throughout the soil, As was present as As(V). In the surface layers a considerable fraction of As was also associated with a recalcitrant phase, probably CCA-treated woody debris, and the remainder was associated with (hydr)oxide-like solid phases. In the Bs horizon, however, XAS and XRF findings strongly pointed to the presence of PIA acting as an effective adsorbent for As. This research shows for the first time the relevance of PIA for the adsorption of As in natural soils.

  8. Oxidation state of chromium associated with cell surfaces of Shewanella oneidensis during chromate reduction

    Energy Technology Data Exchange (ETDEWEB)

    Neal, Andrew L.; Lowe, Kristine; Daulton, Tyrone L.; Jones-Meehan, Joanne; Little, Brenda J

    2002-12-30

    Employing electron energy loss spectroscopy (EELS) and X-ray photoelectron spectroscopy (XPS), we demonstrate that in both aerobic and anaerobic culture Shewanella oneidensis cells are capable of chromate reduction. No Cr(VI) or Cr(V) species were identified at the cell surfaces in Cr 2p{sub 3/}ore photoelectron spectra. More chromium was associated with cell surfaces recovered from anaerobic medium than aerobic. Multiplet-splitting models derived for Cr(III) and Cr(IV) were employed to determine contributions from each ion to Cr 2p{sub 3/2} photopeaks collected from the various cell treatments. Whilst in all cases Cr(III) was the major ion associated with cell surfaces, a significant contribution was identified due to Cr(IV) in anaerobically grown cells. The Cr(IV) contribution was far less when cells were grown aerobically. Moreover, when anaerobically grown cells were exposed to oxygen very little re-oxidation of Cr-precipitates occurred, the precipitates were again identified as a mixture of Cr(III) and Cr(IV). A positive relationship was observed between amounts of chromium and phosphorous associated with cell surfaces resulting from the various treatments, suggesting the precipitates included Cr(III)-phosphate. The fact that Cr(IV) remained associated with precipitates following re-oxidation suggests that under anaerobic conditions the intermediate ion is afforded sufficient stability to be incorporated within the precipitate matrix and thus conferred a degree of protection from oxidation.

  9. Chromatic line-profile tomography to reveal exoplanetary atmospheres: application to HD 189733b

    CERN Document Server

    Borsa, Francesco; Poretti, Ennio

    2016-01-01

    Transmission spectroscopy can be used to constrain the properties of exoplanetary atmospheres. During a transit, the light blocked from the atmosphere of the planet leaves an imprint in the light coming from the star. This has been shown for many exoplanets with different techniques, with both photometry and spectroscopy. We aim at testing chromatic line-profile tomography as a new tool to investigate exoplanetary atmospheres. The signal imprinted on the cross-correlation function (CCF) by a planet transiting its star is dependent on the planet-to-star radius ratio. We want to verify if the precision reachable on the CCF obtained from a subset of the spectral orders of the HARPS spectrograph is enough to discriminate the radius of a planet at different wavelengths. Methods. We analyze HARPS archival data of three transits of HD 189733b. We divide the HARPS spectral range in 7 broadbands, calculating for each band the ratio between the area of the out-of-transit CCF and the area of the signal imprinted by the ...

  10. Compensation for longitudinal chromatic aberration in the eye of the firefly squid, Watasenia scintillans.

    Science.gov (United States)

    Kröger, Ronald H H; Gislén, Anna

    2004-01-01

    The camera eyes of fishes and cephalopods have come forth by convergent evolution. In a variety of vertebrates capable of color vision, longitudinal chromatic aberration (LCA) of the optical system is corrected for by the exactly tuned longitudinal spherical aberration (LSA) of the crystalline lens. The LSA leads to multiple focal lengths, such that several wavelengths can be focused on the retina. We investigated whether that is also the case in the firefly squid (Watasenia scintillans), a cephalopod species that is likely to have color vision. It was found that the lens of W. scintillans is virtually free of LSA and uncorrected for LCA. However, the eye does not suffer from LCA because of a banked retina. Photoreceptors sensitive to short and long wavelengths are located at appropriate distances from the lens, such that they receive well-focused images. Such a design is an excellent solution for the firefly squid because a large area of the retina is monochromatically organized and it allows for double use of the surface area in the dichromatically organized part of the retina. However, it is not a universal solution since compensation for LCA by a banked retina requires that eye size and/or spectral separation between photopigments is small.

  11. Fiber over Wireless Chromatic Dispersion Compensation for a Better Quality of Service

    Directory of Open Access Journals (Sweden)

    2006-01-01

    Full Text Available “Anywhere” and, in particular, “anyhow”: these are the two best words that can describe an ad hoc wireless network that is due to the increasing demand for connectivity in such an information society. Ad hoc wireless networks can be described as dynamic multihop wireless networks with mobile nodes. However, the mobility condition can be relaxed, and we can consider an ad hoc wireless network as a reconfigurable network where all the nodes are connected to the local environment through wireless links, and where there is not a central or dominant node—as opposed to, for example, the case of cellular wireless networks where a base station is located in each cell. When ad hoc networks are backboned by fibers, distortion of the optical link presents one of the major issues. In this paper, we will be addressing one of the fundamental problems, namely, chromatic dispersion in the fiber optic prior reaching the access points. This will ensure an adequate quality of service (QoS.

  12. Action spectra and chromatic mechanisms of cells in the median ocelli of dragonflies.

    Science.gov (United States)

    Chappell, R L; DeVoe, R D

    1975-04-01

    Spectral sensitivities were recorded intracellulary in median ocelli of Anax junius, Aeschnatuberculifera, and Libellulapulcella. All cells had peak sensitivities at 360 and 500 nm while UV-blue+green cells found only in Anax had a third peak sensitivity at 440 nm. Ratios of UV-to-green sensitivities varied from cell to cell in each ocellus, but no UV-only or green-only cells were recorded. Half of the cells tested had a reverse Purkinje shift: They were more sensitive in the green at low illuminations but more sensitive in the UV at high illuminations; their intensity-response curves at 370 and 520 nm crossed but became parallel for large responses. Wave-lengths 420 nm and shorter elicited a family of low intensity-response curves with one slope; wavelengths 440 nm and longer elicities a family of curves with another slope. Orange-adapting lights selectively adapted sensitivity in the green, but UV-adapting lights had little selective effect. Amounts of log-selective adaptation were proportional to log orange-adapting intensity. It is concluded that two spectral mechanisms can be recorded from each cell, possibly by coupling of UV and green cells or possibly because each cell contains two visual pigments. Selective chromatic adaptations may provide the ocellus with a kind of "authomatic color control," while the reverse Purkinje shift could extend the ocellus' sensitivity to prevailing skylight.

  13. Cr localization and speciation in roots of chromate fed Helianthus annuus L. seedlings using synchrotron techniques.

    Science.gov (United States)

    de la Rosa, Guadalupe; Castillo-Michel, Hiram; Cruz-Jiménez, Gustavo; Bernal-Alvarado, Jesús; Córdova-Fraga, Teodoro; López-Moreno, Laura; Cotte, Marine

    2014-01-01

    In order to gain knowledge on the potential use of Helianthus annuus L. for the remediation of Cr(VI) polluted waters, hydroponics experiments were set up to determine Cr uptake and tolerance in different Cr(VI)-sulfate conditions, and Cr biotransformations. Results indicated that Cr(VI) promoted seed germination, and plant tolerance was higher at younger plant stages. Cr uptake was dependent on sulfate concentrations. The highest Cr levels in roots and shoots (13,700 and 2,500 mg kg(-1) dry weight (DW), respectively) were obtained in 1 mM sulfate. The lowest Cr uptake in roots (10,600 mg kg(-1) DW) was observed in seedlings treated with no sulfate. In shoots, Cr concentration was of 1,500 mg kg(-1)DW for the 1 mM sulfate treatment, indicating a different level of interaction between chromate and sulfate in both tissues. For the first time, using micro X-ray florescence (muXRF), we demonstrated Cr reaches the root stele and is located in the walls of xylem vessels. Bulk and micro X-ray Absorption Near-Edge Structure (muXANES) results showed that Cr in the roots is mostly in the form of Cr(III) phosphate (80%), with the remainder complexed to organic acids. Our results suggest this plant species may serve for Cr(VI) rhizofiltration purposes.

  14. About maximal number of edges in hypergraph-clique with chromatic number 3

    CERN Document Server

    Cherkashin, Danila D

    2011-01-01

    Let $ H = (V,E) $ be a hypergraph. By the chromatic number of a hypergraph $ H = (V,E) $ we mean the minimum number $\\chi(H)$ of colors needed to paint all the vertices in $ V $ so that any edge $ e \\in E $ contains at least two vertices of some different colors. Finally, a hypergraph is said to form a clique, if its edges are pairwise intersecting. In 1973 Erd\\H{o}s and Lov\\'asz noticed that if an $n$-uniform hypergraph $ H = (V,E) $ forms a clique, then $ \\chi(H) \\in \\{2,3\\} $. They untoduced following quantity. $$ M(n) = \\max \\{|E|: \\exists {\\rm an} n-{\\rm uniform} {\\rm clique} H = (V,E) {\\rm with} \\chi(H) = 3\\}. $$ Obviously such definition has no sense in the case of $ \\chi(H) = 2 $. Theorem 1 (P. Erdos, L. Lovasz} The inequalities hold $$ n!(e-1) \\le M(n) \\le n^n. $$ Almost nothing better has been done during the last 35 years. At the same time, another quantity $ r(n) $ was introduced by Lovasz r(n) = \\max \\{|E|: ~ \\exists {\\rm an} ~ n-{\\rm uniform} ~ {\\rm clique} ~ H = (V,E) ~ {\\rm s.t.} ~ \\tau(H) = n...

  15. Crystalline perfection and optical properties of rapid grown KH2PO4 crystal with chromate additive

    Indian Academy of Sciences (India)

    Jianxu Ding; Bing Liu; Shenglai Wang; Xiaoming Mu; Shengjun Zhu; Guangxia Liu; Wenjie Liu; Yun Sun; Lin Liu; Duanliang Wang

    2013-10-01

    Potassium dihydrogen phosphate (KDP) crystals were grown in the presence of a series of chromate (CrO$^{2-}_{4}$) additive concentrations via rapid growth method. CrO$^{2-}_{4}$ made KDP crystals were coloured by yellowgreen, suggesting CrO$^{2-}_{4}$ had entered into the crystal lattice. The elemental analysis indicated that Cr element in KDP crystal was at ppm level. High resolution X-ray diffraction data revealed that the crystalline perfection of these as-grown KDP crystals was destroyed after CrO$^{2-}_{4}$ entered into crystal lattice, embedded in the full width at half maximum was broadened and satellite peaks appeared. Additionally, the extinction ratio was decreased with rise of CrO$^{2-}_{4}$ concentration. CrO$^{2-}_{4}$ introduced two absorption peaks centred at 360 and 280 nm and enhanced the intrinsic absorption near 220 nm, which were at the same band positions compared with the CrO$^{2-}_{4}$ or HCrO$^{-}_{4}$ transmittance spectra. Additionally, CrO$^{2-}_{4}$ could increase the size of light scattering, which was attributed to the point defects and microscopic defects by the replacement by CrO$^{2-}_{4}$ at PO$^{3-}_{4}$ position.

  16. Functionalization of micro- and nano-apertures with chromate-selective solvent polymeric membrane.

    Science.gov (United States)

    Rieck, Daniel C; Liu, Bingwen; Park, Bong-Jae; Moffett, David F; Kidwell, David A; Cheng, Gary J; Van Wie, Bernard J

    2010-02-05

    A new miniaturization approach to create micro- and nanoscale ion selective electrodes (ISEs) was demonstrated and the concept tested with an environmentally relevant chromate-selective membrane consisting of 7.7:62.2:31.1 wt % Aliquat336:2-NPOE:PVC. Apertures of 100 nM and 30 microM dimensions were made using MEMS fabrication techniques and functionalized through a macroscale application of solvent polymeric membrane. Performance studies for the microscale ISE showed a response slope of -58.6+/-5.6 mV decade(-1) and limit of detection (LOD) of 2.1 x 10(-5)+/-1.1 x 10(-5) M, versus -65.2+/-4.2 mV decade(-1) and 1.8 x 10(-5)+/-6 x 10(-6) M for the nanoscale ISE. This was consistent with control studies with carefully conditioned coated wire electrodes, which demonstrated a response slope of -61.7+/-2.4 mV decade(-1) and a LOD of 3.0 x 10(-6)+/-1 x 10(-6) M. Response times for the best micro- and nanoscale ISEs were in the 10-20 s timeframe. Electrical resistance measurements were in the GOmega range for the microscale ISEs and nanoscale ISEs. Appropriate ISE geometry was confirmed through AFM measurements and calculations based on electrical properties for micro- and nanoscale apertures. These micro- and nanoscale ISEs are expected to have significant impact in the field of microscale analytical processes.

  17. Deconvolution and chromatic aberration corrections in quantifying colocalization of a transcription factor in three-dimensional cellular space.

    Science.gov (United States)

    Abraham, Thomas; Allan, Sarah E; Levings, Megan K

    2010-08-01

    In the realm of multi-dimensional confocal microscopy, colocalization analysis of fluorescent emission signals has proven to be an invaluable tool for detecting molecular interactions between biological macromolecules at the subcellular level. We show here that image processing operations such as the deconvolution and chromatic corrections play a crucial role in the accurate determination of colocalization between biological macromolecules particularly when the fluorescent signals are faint, and when the fluorescent signals are in the blue and red emission regions. The cellular system presented here describes quantification of an activated forkhead box P3 (FOXP3) transcription factor in three-dimensional (3D) cellular space. 293T cells transfected with a conditionally active form of FOXP3 were stained for anti-FOXP3 conjugated to a fluorescent red dye (Phycoerythrin), and counterstained for DNA (nucleus) with fluorescent blue dye (Hoechst). Due to the broad emission spectra of these dyes, the fluorescent signals were collected only from peak regions and were acquired sequentially. Since the PE signal was weak, a confocal pinhole size of two Airy size was used to collect the 3D image data sets. The raw images supplemented with the spectral data show the preferential association of activated FOXP3 molecules with the nucleus. However, the PE signals were found to be highly diffusive and colocalization quantification from these raw images was not possible. In order to deconvolve the 3D raw image data set, point spread functions (PSFs) of these emissions were measured. From the measured PSF, we found that chromatic shifts between the blue and red colors were quite considerable. Followed by the applications of both the axial and lateral chromatic corrections, colocalization analysis performed on the deconvolved-chromatic corrected-3D image data set showed that 98% of DNA molecules were associated with FOXP3 molecules, whereas only 66% of FOXP3 molecules were colocalized

  18. EVALUATION OF CHROMATICITY COORDINATES SHIFT FOR IMAGE DISPLAYED ON LIQUID CRYSTAL PANELS WITH VARIOUS PROPERTIES ON COLOR REPRODUCTION

    Directory of Open Access Journals (Sweden)

    I. O. Zharinov

    2016-03-01

    Full Text Available Subject of Research.We consider the problem of evaluation of chromaticity coordinates shift for image displayed on liquid crystal panels with various properties on color reproduction. A mathematical model represents the color reproduction characteristics. The spread of the color characteristics of the screens has a statistical nature. Differences of color reproduction for screens are perceived by the observer in the form of different colors and shades that are displayed on the same type of commercially available screens. Color differences are characterized by numerical measure of the difference of colors and can be mathematically compensated. The solution of accounting problem of the statistical nature of the color characteristics spread for the screens has a particular relevance to aviation instrumentation. Method. Evaluation of chromaticity coordinates shift of the image is based on the application of the Grassmann laws of color mixing.Basic data for quantitative calculation of shift are the profiles of two different liquid crystal panels defined by matrixes of scales for components of primary colors (red, green, blue. The calculation is based on solving the system of equations and calculating the color difference in the XY-plane. In general, the calculation can be performed in other color spaces: UV, Lab. The statistical nature of the spread of the color characteristics for the screens is accounted for in the proposed mathematical model based on the interval setting of coordinate values of the color gamut triangle vertices on the set of commercially available samples. Main Results. Carried outresearches result in the mathematical expressions allowing to recalculate values of chromaticity coordinates of the image displayed on various samples of liquid crystal screens. It is shown that the spread of the color characteristics of the screens follows bivariate normal distribution law with the accuracy sufficient for practice. The results of

  19. Geochemical Characterization of Chromate Contamination in the 100 Area Vadose Zone at the Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Dresel, P. Evan; Qafoku, Nikolla; McKinley, James P.; Fruchter, Jonathan S.; Ainsworth, Calvin C.; Liu, Chongxuan; Ilton, Eugene S.; Phillips, J. L.

    2008-07-16

    of contaminant Cr travels fast through the sediments and appears as Cr(VI) in the effluents. The significance of this for groundwater concentrations would, however, depend on the mass flux of recharge to the water table. adsorption of Cr(VI) to sediments from spiked Cr(VI) solution is low; calculated retardation coefficients are close to one. Calcium polysulfide solutions readily reduced Cr(VI) to Cr(III) in column experiments. However a significant amount of the Cr(VI) was mobilized ahead of the polysulfide solution front. This has significant implications for in-situ reductive remediation techniques. The experiments suggest that it would be difficult to design a remedial measure using infiltration of liquid phase reductants without increasing transport of Cr(VI) toward the water table. The microscopic characterization results are consistent with the column studies. Cr(VI) is found as ubiquitous coatings on sediment grain surfaces. Small, higher concentration, chromium sites are associated with secondary clay mineral inclusions, with occasional barium chromate minerals, and reduced to Cr(III) in association with iron oxides that are most likely magnetite primary minerals. Within the restricted access domains of sediment matrix, ferrous iron could also diffuse from in situ, high-surface-area minerals to cause the reductive immobilization of chromate. This process may be favored at microscale geochemical zones where ferrous iron could be supplied. Once nucleated, micrometer-scale precipitates are favored as growing locales for further accumulation, causing the formation of discrete zones of Cr(III).

  20. Microbial Reduction of Chromate in the presence of Nitrate by Three Nitrate Respiring Organisms.

    Directory of Open Access Journals (Sweden)

    Peter eChovanec

    2012-12-01

    Full Text Available A major challenge for the bioremediation of toxic metals is the co-occurrence of nitrate, as it can inhibit metal transformation. Geobacter metallireducens, Desulfovibrio desulfuricans, and Sulfurospirillum barnesii are three soil bacteria that can reduce chromate (Cr(VI and nitrate, and may be beneficial for developing bioremediation strategies. All three organisms respire through dissimilatory nitrate reduction to ammonia (DNRA, employing different nitrate reductases but similar nitrite reductase (Nrf. G. metallireducens reduces nitrate to nitrite via the membrane bound nitrate reductase (Nar, while S. barnesii and D. desulfuricans strain 27774 have slightly different forms of periplasmic nitrate reductase (Nap. We investigated the effect of DNRA growth in the presence of Cr(VI in these three organisms and the ability of each to reduce Cr(VI to Cr(III, and each organisms responded differently. Growth of G. metallireducens on nitrate was completely inhibited by Cr(VI. Cultures of D. desulfuricans on nitrate media was initially delayed (48 h in the presence of Cr(VI, but ultimately reached comparable cell yields to the non-treated control. This prolonged lag phase accompanied the transformation of Cr(VI to Cr(III. Viable G. metallireducens cells could reduce Cr(VI, whereas Cr(VI reduction by D. desulfuricans during growth, was mediated by a filterable and heat stable extracellular metabolite. S. barnesii growth on nitrate was not affected by Cr(VI, and Cr(VI was reduced to Cr(III. However, Cr(VI reduction activity in S. barnesii, was detected in both the cell free spent medium and cells, indicating both extracellular and cell associated mechanisms. Taken together, these results have demonstrated that Cr(VI affects DNRA in the three organisms differently, and that each have a unique mechanism for Cr(VI reduction.

  1. Effects of organic amendments on the reduction and phytoavailability of chromate in mineral soil.

    Science.gov (United States)

    Bolan, N S; Adriano, D C; Natesan, R; Koo, B J

    2003-01-01

    In this study, seven organic amendments (biosolid compost, farm yard manure, fish manure, horse manure, spent mushroom, pig manure, and poultry manure) were investigated for their effects on the reduction of hexavalent chromium [chromate, Cr(VI)] in a mineral soil (Manawatu sandy soil) low in organic matter content. Addition of organic amendments enhanced the rate of reduction of Cr(VI) to Cr(III) in the soil. At the same level of total organic carbon addition, there was a significant difference in the extent of Cr(VI) reduction among the soils treated with organic amendments. There was, however, a significant positive linear relationship between the extent of Cr(VI) reduction and the amount of dissolved organic carbon in the soil. The effect of biosolid compost on the uptake of Cr(VI) from the soil, treated with various levels of Cr(VI) (0-1200 mg Cr kg(-1) soil), was examined with mustard (Brassica juncea L.) plants. Increasing addition of Cr(VI) increased Cr concentration in plants, resulting in decreased plant growth (i.e., phytotoxicity). Addition of the biosolid compost was effective in reducing the phytotoxicity of Cr(VI). The redistribution of Cr(VI) in various soil components was evaluated by a sequential fractionation scheme. In the unamended soil, the concentration of Cr was higher in the organic-bound, oxide-bound, and residual fractions than in the soluble and exchangeable fractions. Addition of organic amendments also decreased the concentration of the soluble and exchangeable fractions but especially increased the organic-bound fraction in soil.

  2. Phenolic and Chromatic Properties of Beibinghong Red Ice Wine during and after Vinification

    Directory of Open Access Journals (Sweden)

    Jin-Chen Li

    2016-04-01

    Full Text Available The phenolic and chromatic characteristics of a special red ice wine made from a Vitis amurensis × V. vinifera hybrid cultivar Beibinghong were studied. Results from two different vintages (2013 and 2014 showed that during vinification, the phenolic acid content increased, while the level of flavonoids (flavonols, flavan-3-ols, and anthocyanins reduced by a variable extent. The color intensity and red % decreased together with a decrease in anthocyanin content. This was accompanied by an increase in hue as well as yellow %. The final phenolic content was found to be between 119.54 and 180.93 mg/L, with anthocyanins as the predominant phenolic group (92.06%–93.03%, of which 3,5-O-diglucosidic anthocyanins made up 53.55%–79.04%. Phenolic acids were the primary non-anthocyanin phenolics at about 6.64%–7.5%. The phenolic contents and color parameters of Beibinghong dry red wine and several V. vinifera dry red wines of superior color quality were also used in an attempt to clarify the relationship between phenolics and color in the Beibinghong red ice wine. By using Pearson correlation analysis and principal component analysis (PCA, it was found that 3,5-O-diglucosidic anthocyanins and protocatechuic acid were the only characteristic phenolics that differentiated Beibinghong wines from the other selected red wines from more traditional varieties. They were also the main phenolics to be positively correlated with the hue and yellow % of the wine at the early stages leading into maturation. Their presence might, therefore, explain the relatively high hue and yellow % of Beibinghong ice wine.

  3. Determination of chromated copper arsenate (CCA) in treated wood of Eucalyptus

    Energy Technology Data Exchange (ETDEWEB)

    Parreira, Paulo S., E-mail: parreira@uel.b [Universidade Estadual de Londrina (UEL), PR (Brazil). Dept. de Fisica. Lab.de Fisica Nuclear Aplicada; Vendrametto, Guilherme R.; Cunha, Magda E.T., E-mail: grvendrametto@gmail.co [Universidade Norte do Parana, Arapongas, PR (Brazil). Centro de Ciencias Humanas, da Saude, Exatas e Tecnologicas-A

    2009-07-01

    This work deals with the possible application of a portable energy dispersive handmade system (PXRF-LFNA-02) for the determination of Chromium, Copper and Arsenic in the preservative solution used to protect commercial wood of Eucalyptus, which are employed as wood fence, posts, contention fences, railroad sleepers, etc. It was prepared five body-of-proof made of eucalyptus alburnum with different concentrations for each element varying from 0.0061 to 0.0180 (g/g) for CrO{sub 3}, 0.0024 to 0.0070 (g/g) for CuO and 0.0044 to 0.0129 (g/g) for As{sub 2}O{sub 5}. Four of them were used for calibration curves and one used as reference sample. It was used a commercial CCA (Chromated Copper Arsenate ) solution to prepare the samples. The results show a good linear regression between concentrations and X-rays intensities, after applied the multiple linear regression methodology for interelemental corrections. The values obtained with this methodology were 3.01(kg/m{sup 3}), 1.18 (kg/m{sup 3}) e 2.21 (kg/m{sup 3}) for CrO{sub 3}, CuO and As{sub 2}O{sub 5}, respectively, while the nominal values are 2.90 (kg/m{sup 3}) for CrO{sub 3}, 1.13 (kg/m{sup 3}) for CuO and 2.07 (kg/m{sup 3}) for As{sub 2}O{sub 5}. The ED-XRF (Energy Dispersive X-Rays Fluorescence) is a well established technique with high-speed of analytical procedure and its portable configuration allowing a multielemental, simultaneous and non destructive analyses besides in situ application. (author)

  4. Assessment of Systematic Chromatic Errors that Impact Sub-1% Photometric Precision in Large-Area Sky Surveys

    Energy Technology Data Exchange (ETDEWEB)

    Li, T. S. [et al.

    2016-05-27

    Meeting the science goals for many current and future ground-based optical large-area sky surveys requires that the calibrated broadband photometry is stable in time and uniform over the sky to 1% precision or better. Past surveys have achieved photometric precision of 1-2% by calibrating the survey's stellar photometry with repeated measurements of a large number of stars observed in multiple epochs. The calibration techniques employed by these surveys only consider the relative frame-by-frame photometric zeropoint offset and the focal plane position-dependent illumination corrections, which are independent of the source color. However, variations in the wavelength dependence of the atmospheric transmission and the instrumental throughput induce source color-dependent systematic errors. These systematic errors must also be considered to achieve the most precise photometric measurements. In this paper, we examine such systematic chromatic errors using photometry from the Dark Energy Survey (DES) as an example. We define a natural magnitude system for DES and calculate the systematic errors on stellar magnitudes, when the atmospheric transmission and instrumental throughput deviate from the natural system. We conclude that the systematic chromatic errors caused by the change of airmass in each exposure, the change of the precipitable water vapor and aerosol in the atmosphere over time, and the non-uniformity of instrumental throughput over the focal plane, can be up to 2% in some bandpasses. We compare the calculated systematic chromatic errors with the observed DES data. For the test sample data, we correct these errors using measurements of the atmospheric transmission and instrumental throughput. The residual after correction is less than 0.3%. We also find that the errors for non-stellar objects are redshift-dependent and can be larger than those for stars at certain redshifts.

  5. Filtering Chromatic Aberration for Wide Acceptance Angle Electrostatic Lenses II--Experimental Evaluation and Software-Based Imaging Energy Analyzer.

    Science.gov (United States)

    Fazekas, Ádám; Daimon, Hiroshi; Matsuda, Hiroyuki; Tóth, László

    2016-03-01

    Here, the experimental results of the method of filtering the effect of chromatic aberration for wide acceptance angle electrostatic lens-based system are described. This method can eliminate the effect of chromatic aberration from the images of a measured spectral image sequence by determining and removing the effect of higher and lower kinetic energy electrons on each different energy image, which leads to significant improvement of image and spectral quality. The method is based on the numerical solution of a large system of linear equations and equivalent with a multivariate strongly nonlinear deconvolution method. A matrix whose elements describe the strongly nonlinear chromatic aberration-related transmission function of the lens system acts on the vector of the ordered pixels of the distortion free spectral image sequence, and produces the vector of the ordered pixels of the measured spectral image sequence. Since the method can be applied not only on 2D real- and $k$ -space diffraction images, but also along a third dimension of the image sequence that is along the optical or in the 3D parameter space, the energy axis, it functions as a software-based imaging energy analyzer (SBIEA). It can also be applied in cases of light or other type of optics for different optical aberrations and distortions. In case of electron optics, the SBIEA method makes possible the spectral imaging without the application of any other energy filter. It is notable that this method also eliminates the disturbing background significantly in the present investigated case of reflection electron energy loss spectra. It eliminates the instrumental effects and makes possible to measure the real physical processes better.

  6. Influence of ocular chromatic aberration and pupil size on transverse resolution in ophthalmic adaptive optics optical coherence tomography.

    Science.gov (United States)

    Fernández, Enrique; Drexler, Wolfgang

    2005-10-03

    Optical coherence tomography (OCT) enables visualization of the living human retina with unprecedented high axial resolution. The transverse resolution of existing OCT approaches is relatively modest as compared to other retinal imaging techniques. In this context, the use of adaptive optics (AO) to correct for ocular aberrations in combination with OCT has recently been demonstrated to notably increase the transverse resolution of the retinal OCT tomograms. AO is required when imaging is performed through moderate and large pupil sizes. A fundamental difference of OCT as compared to other imaging techniques is the demand of polychromatic light to accomplish high axial resolution. In ophthalmic OCT applications, the performance is therefore also limited by ocular chromatic aberrations. In the current work, the effects of chromatic and monochromatic ocular aberrations on the quality of retinal OCT tomograms, especially concerning transverse resolution, sensitivity and contrast, are theoretically studied and characterized. The repercussion of the chosen spectral bandwidth and pupil size on the final transverse resolution of OCT tomograms is quantitatively examined. It is found that losses in the intensity of OCT images obtained with monochromatic aberration correction can be up to 80 %, using a pupil size of 8 mm diameter in combination with a spectral bandwidth of 120 nm full width at half maximum for AO ultrahigh resolution OCT. The limits to the performance of AO for correction of monochromatic aberrations in OCT are established. The reduction of the detected signal and the resulting transverse resolution caused by chromatic aberration of the human eye is found to be strongly dependent on the employed bandwidth and pupil size. Comparison of theoretical results with experimental findings obtained in living human eyes is also provided.

  7. Monitoring human lymphocytic DNA-protein cross-links as biomarkers of biologically active doses of chromate.

    Science.gov (United States)

    Costa, M; Zhitkovich, A; Toniolo, P; Taioli, E; Popov, T; Lukanova, A

    1996-10-01

    A simple and sensitive assay for DNA-protein cross-links has been used as a biomarker of chromate exposure and early carcinogenic effects. Pilot studies of DNA-protein cross-links in peripheral blood lymphocytes have been conducted with individuals who had higher exposure to chromate, including welders, and with individuals who had lower levels of exposure such as residents living in a chromium-contaminated area in Jersey City, New Jersey. Studies were also conducted in two Bulgarian cities (Jambol and Burgas) with different levels of air pollution and Cr(VI) exposure and in chrome platers in Bulgaria who had high exposure to chromate. DNA-protein cross-links in U.S. welders and in individuals living in Hudson County, New Jersey around chromium-contaminated areas were significantly higher compared to matched controls. Although blood and urinary levels of chromium were not extensively studied in these populations, we were able to obtain these measurements in the Bulgarian population. Chromium levels in red blood cells of controls living in Burgas were in the order of 1 to 2 ppb chromium, and these individuals had the lowest levels of DNA-protein cross-links. However, the chromium levels in Jambol ranged from about 2 to 7 ppb in red blood cells of city residents to about 22 ppb in chrome platers. DNA-protein cross-links were saturated at about 7 to 8 ppb chromium in the red blood cells, and cross-links correlated well only with chromium levels in red blood cells. Urinary chromium levels did not correlate well with either DNA-protein cross-links or chromium levels in with red blood cells.

  8. [Detection of sister chromatic exchange in workers exposed to coal tar pitch and to coke oven volatiles].

    Science.gov (United States)

    Wang, X; Chen, C; Wu, Y; Xu, Y

    1998-07-01

    In order to know the changes of genetic toxicological effects on workers occupationally exposed to polycyclic aromatic hydrocarbons (PAHs), sister chromatic exchange(SCE) was detected by the methods of peripheral lymphocyte culture in 23 workers exposed to coal tar pitch (CTP) and in 19 workers exposed to coke oven volatiles (COV) and 12 normal controls. The results suggested that the SCE in occupational workers was significantly higher than that in controls (11.31 vs 6.37, P 0.05). It is indicated that CTP and COV caused strong genetic toxicity and injury to chromosome.

  9. Analysis of transverse RMS emittance growth of a beam induced by spherical and chromatic aberration in a solenoidal field

    Energy Technology Data Exchange (ETDEWEB)

    Dash, Radhakanta, E-mail: radhakanta.physics@gmail.com [Homi Bhabha National Institute, Training School Complex, Anushakti Nagar, Mumbai 400094 (India); Accelerator and Pulse Power Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Nayak, Biswaranjan [Homi Bhabha National Institute, Training School Complex, Anushakti Nagar, Mumbai 400094 (India); Sharma, Archana; Mittal, Kailash C. [Homi Bhabha National Institute, Training School Complex, Anushakti Nagar, Mumbai 400094 (India); Accelerator and Pulse Power Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India)

    2016-01-21

    In a medium energy beam transport line transverse rms emittance growth associated with spherical aberration is analysed. An analytical expression is derived for beam optics in a solenoid field considering terms up to the third order in the radial displacement. Two important phenomena: effect of spherical aberrations in axial-symmetric focusing lens and influence of nonlinear space charge forces on beam emittance growth are discussed for different beam distributions. In the second part nonlinear effect associated with chromatic aberration that describes the growth of emittance and distortion of phase space area is discussed.

  10. Analysis of transverse RMS emittance growth of a beam induced by spherical and chromatic aberration in a solenoidal field

    Science.gov (United States)

    Dash, Radhakanta; Nayak, Biswaranjan; Sharma, Archana; Mittal, Kailash C.

    2016-01-01

    In a medium energy beam transport line transverse rms emittance growth associated with spherical aberration is analysed. An analytical expression is derived for beam optics in a solenoid field considering terms up to the third order in the radial displacement. Two important phenomena: effect of spherical aberrations in axial-symmetric focusing lens and influence of nonlinear space charge forces on beam emittance growth are discussed for different beam distributions. In the second part nonlinear effect associated with chromatic aberration that describes the growth of emittance and distortion of phase space area is discussed.

  11. Sulfate and chromate increased each other's uptake and translocation in As-hyperaccumulator Pteris vittata.

    Science.gov (United States)

    de Oliveira, Letúzia M; Gress, Julia; De, Jaysankar; Rathinasabapathi, Bala; Marchi, Giuliano; Chen, Yanshan; Ma, Lena Q

    2016-03-01

    We investigated the effects of chromate (CrVI) and sulfate on their uptake and translocation in As-hyperaccumulator Pteris vittata. Plants were exposed to 1) 0.1 mM CrVI and 0, 0.25, 1.25 or 2.5 mM sulfate or 2) 0.25 mM sulfate and 0, 0.5, 2.5 or 5.0 mM CrVI for 1 d in hydroponics. P. vittata accumulated 26 and 1261 mg kg(-1) Cr in the fronds and roots at CrVI0.1, and 2197 and 1589 mg kg(-1) S in the fronds and roots at S0.25. Increasing sulfate concentrations increased Cr root concentrations by 16-66% and helped CrVI reduction to CrIII whereas increasing CrVI concentrations increased frond sulfate concentrations by 3-27%. Increasing sulfate concentrations enhanced TBARS concentrations in the biomass, indicating oxidative stress caused lipid peroxidation in plant cell membranes. However, addition of 0.25-2.5 mM sulfate alleviated CrVI's toxic effects and decreased TBARS from 23.5 to 9.46-12.3 μmol g(-1) FW. Though CrVI was supplied, 78-96% of CrIII was in the biomass, indicating efficient CrVI reduction to CrIII by P. vittata. The data indicated the amazing ability of P. vittata in Cr uptake at 289 mg kg(-1) h(-1) with little translocation to the fronds. These results indicated that P. vittata had potential in Cr phytoremediation in contaminated sites but further studies are needed to evaluate this potential. The facts that CrVI and sulfate helped each other in uptake by P. vittata suggest that CrVI was not competing with sulfate uptake in P. vittata. However, the mechanisms of how sulfate and CrVI enhance each other's accumulation in P. vittata need further investigation.

  12. Review of Techniques to Characterize the Distribution of Chromate Contamination in the Vadose Zone of the 100 Areas at the Hanford Site

    Energy Technology Data Exchange (ETDEWEB)

    Dresel, P. Evan; Truex, Michael J.; Sweeney, Mark D.

    2007-09-01

    The purpose of this report is to identify and evaluate the state-of-the-art techniques for characteriza¬tion of chromate contamination in the vadose zone of the 100 Areas at the Hanford Site. The techniques include direct techniques for analysis of chromium in the subsurface as well as indirect techniques to identify contamination through geophysical properties, soil moisture, or co-contaminants. Characteri¬zation for the distribution of chromium concentration in the vadose zone is needed to assess potential sources for chromate contamination plumes in groundwater at the 100-D, 100-K, and 100-B/C Areas.

  13. A Comparison between Electrical and Optical Chromatic Dispersion Compensation in Wavelength Divison Multiplexing Network Regarding to Electrical Pulse Shapes

    Directory of Open Access Journals (Sweden)

    Mohammad S. Ab-Rahman

    2012-01-01

    Full Text Available Problem statement: Besides of some impairment that has been inherited form single channel, specialists confronted with new obstacles in WDM implementation which bared them for achieving desired performance. Although Chromatic Dispersion (CD exists in single channel too, it can worsens new nonlinearities which are occurs just in WDM systems. So CD compensation in WDM is even more vital than single channel one. Approach: A wide range of optical and electrical CD compensation techniques have been represented. In this study we evaluate the efficiency of feed Forward-Decision Feedback Equalizer (FFE-DFE as one type of electrical compensation methods and Dispersion Compensation Fiber as one type of optical compensator. Also we will look how electrical pulse shapes induced by pulse generator in transmitter, can impact on the performance of the either optical or electrical compensations. Results: After implementation, it was revealed that overall optical compensation with DCF gives us better performance than electrical equalizer and NRZ is more vulnerable than two other pulse shapes. Conclusion: Chromatic compensation was implemented with different pulse shapes and RZ pulse shape with optical compensation showed the best performance.

  14. Analysis of the influence of the aperture size on the differences of L *a *b chromatic coordinates in a spectrocolorimeter

    Science.gov (United States)

    Medina-Marquez, J.; Balderas-Mata, S. E.; Flores, Jorge L.

    2016-09-01

    The study of the influence of the aperture size over the measurements of the L*a*b chromatic coordinates in spectrocolorimeters, in particular, the Macbeth 7000A ® spectrocolorimeter with an illumination/detection geometry d/8°. This is of importance due to the fact that many industry laboratories use it. This study will give us an invaluable insight of the variations in the measurements of the chromatic coordinates in the visible spectrum range regarding to three different aperture sizes; 2,5cm (AL), 1cm (AM), and 0,5cm (AS). The measurements are carried out on 13 Reference Materials (RMs) or diffusers with different hue under the following metrics; including specular component (SCI), excluding ultraviolet component (UVex), D65 illuminant, and 2° observer. The analysis and quantification of the data were done by the use of statistical tools such as variance analysis and Mendel parameters. In this work the analysis of the latter measurements as well as the methodology that quantifies the accuracy and precision of the method, i.e., repeatability and reproducibility, are presented.

  15. Joint nonlinearity and chromatic dispersion pre-compensation for coherent optical orthogonal frequency-division multiplexing systems

    Institute of Scientific and Technical Information of China (English)

    Qiao Yao-Jun; Liu Xue-Jun; Ji Yue-Feng

    2011-01-01

    This paper introduces a joint nonlinearity and chromatic dispersion pre-compensation method for coherent optical orthogonal frequency-division multiplexing systems.The research results show that this method can reduce the walkoff effect and can therefore equalize the nonlinear impairments effectively. Compared with the only other existing nonlinearity pre-compensation method,the joint nonlinearity and chromatic dispersion pre-compensation method is not only suitable for low-dispersion optical orthogonal frequency-division multiplexing system,but also effective for highdispersion optical orthogonal frequency-division multiplexing transmission system with higher input power but without optical dispersion compensation.The suggested solution does not increase computation complexity compared with only nonlinearity pre-compensation method.For 40 Gbit/s coherent optical orthogonal frequency-division multiplexing 20 × 80 km standard single-mode fibre system,the suggested method can improve the nonlinear threshold (for Q > 10 dB) about 2.7,1.2 and 1.0 dB,and the maximum Q factor about 1.2,0.4 and 0.3 dB,for 2,8 and 16 ps/(nm·km) dispersion coefficients.

  16. Differences in Brain Hemodynamics in Response to Achromatic and Chromatic Cards of the Rorschach: A fMRI Study.

    Science.gov (United States)

    Ishibashi, Masahiro; Uchiumi, Chigusa; Jung, Minyoung; Aizawa, Naoki; Makita, Kiyoshi; Nakamura, Yugo; Saito, Daisuke N

    2016-01-01

    In order to investigate the effects of color stimuli of the Rorschach inkblot method (RIM), the cerebral activity of 40 participants with no history of neurological or psychiatric illness was scanned while they engaged in the Rorschach task. A scanned image of the ten RIM inkblots was projected onto a screen in the MRI scanner. Cerebral activation in response to five achromatic color cards and five chromatic cards were compared. As a result, a significant increase in brain activity was observed in bilateral visual areas V2 and V3, parietooccipital junctions, pulvinars, right superior temporal gyrus, and left premotor cortex for achromatic color cards (p < .001). For the cards with chromatic color, significant increase in brain activity was observed in left visual area V4 and left orbitofrontal cortex (p < .001). Furthermore, a conjoint analysis revealed various regions were activated in responding to the RIM. The neuropsychological underpinnings of the response process, as described by Acklin and Wu-Holt (1996), were largely confirmed.

  17. The role of short-wavelength sensitive cones and chromatic aberration in the response to stationary and step accommodation stimuli.

    Science.gov (United States)

    Rucker, Frances J; Kruger, Philip B

    2004-01-01

    The aim of the experiment was to test for a contribution from short-wavelength sensitive cones to the static and step accommodation response, to compare responses from short and long- plus middle-wavelength sensitive cone types, and to examine the contribution of a signal from longitudinal chromatic aberration to the accommodation response. Accommodation was monitored continuously (eight subjects) to a square-wave grating (2.2 c/d; 0.57 contrast) in a Badal optometer. The grating stepped (1.00 D) randomly towards or away from the eye from a starting position of 2.00 D. Five illumination conditions were used to isolate cone responses, and combine them with or without longitudinal chromatic aberration. Accuracy of the response before the step, step amplitude, latencies and time-constants, were compared between conditions using single factor ANOVA and t-test comparisons. Both S-cones and LM-cones mediated static and step accommodation responses. S-cone contrast drives "static" accommodation for near, but the S-cone response is too slow to influence step dynamics when LM-cones participate.

  18. Chromatic aberration-corrected tilt series transmission electron microscopy of nanoparticles in a whole mount macrophage cell.

    Science.gov (United States)

    Baudoin, Jean-Pierre; Jinschek, Joerg R; Boothroyd, Chris B; Dunin-Borkowski, Rafal E; de Jonge, Niels

    2013-08-01

    Transmission electron microscopy (TEM) in combination with electron tomography is widely used to obtain nanometer scale three-dimensional (3D) structural information about biological samples. However, studies of whole eukaryotic cells are limited in resolution and/or contrast on account of the effect of chromatic aberration of the TEM objective lens on electrons that have been scattered inelastically in the specimen. As a result, 3D information is usually obtained from sections and not from whole cells. Here, we use chromatic aberration-corrected TEM to record bright-field TEM images of nanoparticles in a whole mount macrophage cell. Tilt series of images are used to generate electron tomograms, which are analyzed to assess the spatial resolution that can be achieved for different vertical positions in the specimen. The uptake of gold nanoparticles coated with low-density lipoprotein (LDL) is studied. The LDL is found to assemble in clusters. The clusters contain nanoparticles taken up on different days, which are joined without mixing their nanoparticle cargo.

  19. Theory on Structure and Coloring of Maximal Planar Graphs (1)Recursion Formulae of Chromatic Polynomial and Four-Color Conjecture

    Institute of Scientific and Technical Information of China (English)

    XU Jin

    2016-01-01

    In this paper, two recursion formulae of chromatic polynomial of a maximal planar graphG are obtained: whend(G)=4, let4vW be a 4-wheel ofG with wheel-centerv and wheel-cyclev1v2v3v4v1, then 1324(,4)((){,},4)((){,},4)fGfGvvvfGvvv=-+-oo; whend(G)=5, let5vW a 5-wheel ofG with wheel-centerv and wheel-cyclev1v2v3v4v5v1, then1114132231353(,4)[(,4)({,},4)][(,4)({,},4)][(,4)fGfGfGvvvvfGfGvvvvfG=-+-+UU314({},4)]fGvv-U,()125{,}G=G-vovv,()()224335{,}, {,}G=G-vovvG=G-vovv, where“o”denotes the operation of vertex contraction. Moreover, the application of the above formulae to the proof of Four-Color Conjecture is investigated. By using these formulae, the proof of Four-Color Conjecture boils down to the study on a special class of graphs, viz., 4-chromatic-funnel pseudo uniquely-4-colorable maximal planar graphs.

  20. Effect of addition of commercial grape seed tannins on phenolic composition, chromatic characteristics, and antioxidant activity of red wine.

    Science.gov (United States)

    Neves, Ana C; Spranger, Maria I; Zhao, Yuqing; Leandro, Maria C; Sun, Baoshan

    2010-11-24

    The effect of addition of grape seed tannins on the phenolic composition, chromatic characteristics, and antioxidant activity of red wine was studied. Two highly pure commercial grape seed tannins (GSE100 and GSE300) were selected, and their phenolic compositions were determined. Two types of red wines were made with Castelão/Tinta Miúda (3/2, w/w) grapevine varieties by fermentation on skin using two different maceration times, which correspond to the wines rich and poor in polyphenols, respectively. Each of these wines was used for experimentation with the addition of GSE100 and GSE300 before and immediately after alcoholic fermentation. Phenolic composition, chromatic characteristics, and antioxidant activity of the finished red wines were analyzed by HPLC-DAD, CIElab 76 convention, and DPPH radical test, respectively. The results showed that the addition of grape seed tannins had obvious effects of increasing color intensity and antioxidant activity only in the wines poor in polyphenols. Although GSE300 contained much higher amounts of di- and trimer procyanidins and a lower amount of polymeric proanthocyanidins, it provided effects of increasing the color intensity and antioxidant activity of the wines poor in polyphenols similar to those of GSE100. Furthermore, GSE100 released more gallic acid to wines than GSE300, although no gallic acid was detected in GSE100. Tannins added after alcoholic fermentation had a better effect on phenolic composition of red wine than tannins added before alcoholic fermentation.

  1. The Chromatic Parameters and Color Grading of White Gold Alloys%白色开金的色度参数和白色分级

    Institute of Scientific and Technical Information of China (English)

    宁远涛

    2013-01-01

      评述了合金元素对Au的漂白效果和机制,介绍了白色开金的几种色度参数,如CIE-L a*b*色度参数和颜色盒,CIE-LAB-C-H-L米制色度参数和基于CIE-XYZ色度参数的ASTM D1925黄色指数YI,讨论了某些白色开金的色度参数与冶金学特征。基于金合金的漂白效应与合金成分的密切关系,ASTM D1925黄色指数YI为设计白色开金成分提供了基本的指南。%The bleaching effects and mechanism of alloying elements to gold were reviewed. The several chromatic parameters, such as CIE-L a*b* chromatic parameters, CIE-LAB-C-H-L metric chromatic parameters and ASTM D1925 Yellowness Indexes, for determining the whiteness of jewelry gold alloys were introduced. The chromatic parameters and metallurgical features were discussed. Based on the closer relations between the bleaching effects and alloying components, ASTM D1925 Yellowness Indexes could provide a basic guide for designing white jewelry carat gold alloys.

  2. Study of chromatic variations between metameres by varying the lighting in the painting "Boy in a turban holding a nosegay" by Michiel Sweerts

    Science.gov (United States)

    Vázquez, D.; Muñoz de Luna, J.; Alvarez, A.; Sánchez, A.; Sedano, U.

    2012-12-01

    When artificially lighting a restored painting, it is important to ensure consistency in the visual perception of original and restored areas. The current paper has worked out how chromatic difference varies between restored and original areas when modifying the lighting source. In colorimetry, metamerism is the matching of apparent color of objects with different spectral reflectance. The color of a surface is the value resulting from the product of the spectral reflectance curve of the material and the spectral emittance curve of the lighting source casting light on it. As a result, the color of surfaces depends on the lighting source used to illuminate them. This paper describes the work carried out to study the color difference between original and restored metameric areas of a painting with some chromatic reintegrated areas under different light sources. Firstly, based on an ultraviolet photograph from the painting, the areas with chromatic reintegration were identified. Secondly, using a PR-655 SpectraScan spectroradiometer as well as a calibrated lighting source and measuring geometry 0°/45°, the spectral reflectance was measured at four points of the same apparent color both next to original painting and in chromatic reintegrated areas. Finally, colorimetric calculations for a 2° CIE pattern observer were performed by using spectral measurements. The color difference between the original and the restored areas was estimated under different CIE pattern illuminants by using the CIE L*a*b color space.

  3. CALiPER Report 20.4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps Operated in Steady-State Conditions

    Energy Technology Data Exchange (ETDEWEB)

    none,

    2014-12-30

    This CALiPER report focuses on lumen maintenance, chromaticity maintenance, and catastrophic failure in 32 of the Series 20 LED PAR38 lamps and 8 benchmark lamps, which were monitored for nearly 14,000 hours at ambient temperatures between 44°C and 45°C.

  4. Evaluation of layered zinc hydroxide nitrate and zinc/nickel double hydroxide salts in the removal of chromate ions from solutions

    Science.gov (United States)

    de Oliveira, Henrique Bortolaz; Wypych, Fernando

    2016-11-01

    Layered zinc hydroxide nitrate (ZnHN) and Zn/Ni layered double hydroxide salts were synthesized and used to remove chromate ions from solutions at pH 8.0. The materials were characterized by many instrumental techniques before and after chromate ion removal. ZnHN decomposed after contact with the chromate solution, whereas the layered structure of Zn/Ni hydroxide nitrate (Zn/NiHN) and Zn/Ni hydroxide acetate (Zn/NiHA) remained their layers intact after the topotactic anionic exchange reaction, only changing the basal distances. ZnHN, Zn/NiHN, and Zn/NiHA removed 210.1, 144.8, and 170.1 mg of CrO42-/g of material, respectively. Although the removal values obtained for Zn/NiHN and Zn/NiHA were smaller than the values predicted for the ideal formulas of the solids (194.3 and 192.4 mg of CrO42-/g of material, respectively), the measured capacities were higher than the values achieved with many materials reported in the literature. Kinetic experiments showed the removal reaction was fast. To facilitate the solid/liquid separation process after chromium removal, Zn/Ni layered double hydroxide salts with magnetic supports were also synthesized, and their ability to remove chromate was evaluated.

  5. Draft Genome Sequence of "Halomonas chromatireducens" Strain AGD 8-3, a Haloalkaliphilic Chromate- and Selenite-Reducing Gammaproteobacterium.

    Science.gov (United States)

    Sharko, Fedor S; Shapovalova, Anna A; Tsygankova, Svetlana V; Komova, Anastasia V; Boulygina, Eugenia S; Teslyuk, Anton B; Gotovtsev, Pavel M; Namsaraev, Zorigto B; Khijniak, Tatiana V; Nedoluzhko, Artem V; Vasilov, Raif G

    2016-03-17

    Here, we report the complete genome sequence (3.97 Mb) of "Halomonas chromatireducens" AGD 8-3, a denitrifying bacterium capable of chromate and selenite reduction under extreme haloalkaline conditions. This strain was isolated from soda solonchak soils of the Kulunda steppe, Russian Federation.

  6. Draft Genome Sequence of “Halomonas chromatireducens” Strain AGD 8-3, a Haloalkaliphilic Chromate- and Selenite-Reducing Gammaproteobacterium

    Science.gov (United States)

    Sharko, Fedor S.; Shapovalova, Anna A.; Tsygankova, Svetlana V.; Komova, Anastasia V.; Boulygina, Eugenia S.; Teslyuk, Anton B.; Gotovtsev, Pavel M.; Namsaraev, Zorigto B.; Khijniak, Tatiana V.; Vasilov, Raif G.

    2016-01-01

    Here, we report the complete genome sequence (3.97 Mb) of “Halomonas chromatireducens” AGD 8-3, a denitrifying bacterium capable of chromate and selenite reduction under extreme haloalkaline conditions. This strain was isolated from soda solonchak soils of the Kulunda steppe, Russian Federation. PMID:26988058

  7. Geochemical Characterization of Chromate Contamination in the 100 Area Vadose Zone at the Hanford Site - Part 2

    Energy Technology Data Exchange (ETDEWEB)

    Qafoku, Nikolla; Dresel, P. Evan; McKinley, James P.; Ilton, Eugene S.; Um, Wooyong; Resch, Charles T.; Kukkadapu, Ravi K.; Petersen, Scott W.

    2011-01-04

    At the Hanford Site, chromate was used throughout the 100 Areas (100-B, 100-C, 100-D/DR, 100-F, 100-H, and 100 K) as a corrosion inhibitor in reactor cooling water. Chromate was delivered in rail cars, tanker trucks, barrels, and local pipelines as dichromate granular solid or stock solution. In many occasions, chromate was inevitably discharged to surface or near-surface ground through spills during handling, pipeline leaks, or during disposal to cribs. The composition of the liquids that were discharged is not known and it is quite possible that Cr(VI) fate and transport in the contaminated sediments would be a function of the chemical composition of the waste fluids. The major objectives of this investigation which was limited in scope by the financial resources available, were to 1) determine the leaching characteristics of hexavalent chromium [Cr(VI)] from contaminated sediments collected from 100-D Area spill sites; 2) elucidate possible Cr(VI) mineral and/or chemical associations that may be responsible for Cr(VI) retention in the Hanford Site 100 Areas through the use of macroscopic leaching studies, and microscale characterization of contaminated sediments; and 3) provide information to construct a conceptual model of Cr(VI) geochemistry in the Hanford 100 Area vadose zone that can be used for developing options for environmental remediation. The information gathered from this research effort will help to further improve our understanding of Cr(VI) behavior in the vadose zone and will also help in accelerating the 100 Area Columbia River Corridor cleanup by providing valuable information to develop remedial action based on a fundamental understanding of Cr(VI) vadose zone geochemistry. A series of column experiments were conducted with contaminated sediments to study Cr(VI) desorption patterns. Column experiments used the field size fraction of the sediment samples and a simulated Hanford Site groundwater solution. Periodic stop flow events were applied to

  8. Macroscopic and spectroscopic characterization of selenate, selenite, and chromate adsorption at the solid-water interface of gamma-Al(2)O(3).

    Science.gov (United States)

    Elzinga, Evert J; Tang, Yuanzhi; McDonald, Jason; DeSisto, Stephanie; Reeder, Richard J

    2009-12-15

    The interaction of selenate, selenite, and chromate with the hydrated surface of gamma-Al(2)O(3) was studied using a combination of macroscopic pH edge data, electrophoretic mobility measurements, and X-ray absorption spectroscopic analyses. The pH edge data show generally increased oxyanion adsorption with decreasing pH, and indicate ionic strength-(in)dependent adsorption of chromate and selenate across the pH range 4-9, and ionic strength-(in)dependent adsorption of selenite in this pH range. The adsorption of chromate peaks at pH 5.0, whereas for selenate and selenite no pH adsorption maxima are observed. Electrophoretic mobility measurements show that all three oxyanions decrease the zeta potential of gamma-Al(2)O(3) upon adsorption; however, only selenite decreased the pH(PZC) of the gamma-Al(2)O(3) sorbent. EXAFS data indicate that selenite ions are coordinated in a bridging bidentate fashion to surface AlO(6) octahedra, whereas no second-neighbor Al scattering was observed for adsorbed selenate ions. Combined, the results presented here show that pH is a major factor in determining the extent of adsorption of selenate, selenite, and chromate on hydrated gamma-Al(2)O(3). The results point to substantial differences between these anions as to the mode of adsorption at the hydrated gamma-Al(2)O(3) surface, with selenate adsorbing as nonprotonated outer-sphere complexes, chromate forming a mixture of monoprotonated and nonprotonated outer-sphere adsorption complexes, and selenite coordinating as inner-sphere surface complexes in bridging configuration.

  9. Atomic resolution imaging of YAlO3: Ce in the chromatic and spherical aberration corrected PICO electron microscope.

    Science.gov (United States)

    Jin, Lei; Barthel, Juri; Jia, Chun-Lin; Urban, Knut W

    2017-01-31

    The application of combined chromatic and spherical aberration correction in high-resolution transmission electron microscopy enables a significant improvement of the spatial resolution down to 50 pm. We demonstrate that such a resolution can be achieved in practice at 200kV. Diffractograms of images of gold nanoparticles on amorphous carbon demonstrate corresponding information transfer. The Y atom pairs in [010] oriented yttrium orthoaluminate are successfully imaged together with the Al and the O atoms. Although the 57 pm pair separation is well demonstrated separations between 55 pm and 80 pm are measured. This observation is tentatively attributed to structural relaxations and surface reconstruction in the very thin samples used. Quantification of the resolution limiting effective image spread is achieved based on an absolute match between experimental and simulated image intensity distributions.

  10. Assessment of Systematic Chromatic Errors that Impact Sub-1% Photometric Precision in Large-Area Sky Surveys

    CERN Document Server

    Li, T S; Marshall, J L; Tucker, D; Kessler, R; Annis, J; Bernstein, G M; Boada, S; Burke, D L; Finley, D A; James, D J; Kent, S; Lin, H; Marriner, J; Mondrik, N; Nagasawa, D; Rykoff, E S; Scolnic, D; Walker, A R; Wester, W; Abbott, T M C; Allam, S; Benoit-Lévy, A; Bertin, E; Brooks, D; Capozzi, D; Rosell, A Carnero; Kind, M Carrasco; Carretero, J; Crocce, M; Cunha, C E; D'Andrea, C B; da Costa, L N; Desai, S; Diehl, H T; Doel, P; Flaugher, B; Fosalba, P; Frieman, J; Gaztanaga, E; Goldstein, D A; Gruen, D; Gruendl, R A; Gutierrez, G; Honscheid, K; Kuehn, K; Kuropatkin, N; Maia, M A G; Melchior28, P; Miller, C J; Miquel, R; Mohr, J J; Neilsen, E; Nichol, R C; Nord, B; Ogando, R; Plazas, A A; Romer, A K; Roodman, A; Sako, M; Sanchez, E; Scarpine, V; Schubnell, M; Sevilla-Noarbe, I; Smith, R C; Soares-Santos, M; Sobreira, F; Suchyta, E; Tarle, G; Thomas, D; Vikram, V

    2016-01-01

    Meeting the science goals for many current and future ground-based optical large-area sky surveys requires that the calibrated broadband photometry is stable in time and uniform over the sky to 1% precision or better. Past surveys have achieved photometric precision of 1-2% by calibrating the survey's stellar photometry with repeated measurements of a large number of stars observed in multiple epochs. The calibration techniques employed by these surveys only consider the relative frame-by-frame photometric zeropoint offset and the focal plane position-dependent illumination corrections, which are independent of the source color. However, variations in the wavelength dependence of the atmospheric transmission and the instrumental throughput induce source color-dependent systematic errors. These systematic errors must also be considered to achieve the most precise photometric measurements. In this paper, we examine such systematic chromatic errors using photometry from the Dark Energy Survey (DES) as an example...

  11. Effects of Antenna Beam Chromaticity on Redshifted 21~cm Power Spectrum and Implications for Hydrogen Epoch of Reionization Array

    CERN Document Server

    Thyagarajan, Nithyanandan; DeBoer, David; Bowman, Judd; Ewall-Wice, Aaron; Neben, Abraham; Patra, Nipanjana

    2016-01-01

    Unaccounted for systematics from foregrounds and instruments can severely limit the sensitivity of current experiments from detecting redshifted 21~cm signals from the Epoch of Reionization (EoR). Upcoming experiments are faced with a challenge to deliver more collecting area per antenna element without degrading the data with systematics. This paper and its companions show that dishes are viable for achieving this balance using the Hydrogen Epoch of Reionization Array (HERA) as an example. Here, we specifically identify spectral systematics associated with the antenna power pattern as a significant detriment to all EoR experiments which causes the already bright foreground power to leak well beyond ideal limits and contaminate the otherwise clean EoR signal modes. A primary source of this chromaticity is reflections in the antenna-feed assembly and between structures in neighboring antennas. Using precise foreground simulations taking wide-field effects into account, we provide a framework to set cosmologica...

  12. Letter: A method for the chromatic aberration correction of a laser time of-flight mass analyzer.

    Science.gov (United States)

    Sysoeva, Elizaveta A; Sysoev, Alexander A

    2016-01-01

    The new ion-optical system of the laser time-of-flight (TOF) mass spectrometer on the basis of two tandem wedge-shape reflectors has been offered and implemented. A new method of correcting chromatic aberration by the ion energy was proposed that used a wire electrode unit with adjustable potentials. This unit allows one to adjust the local TOF of the ions in a narrow energy range ± (1-2)% within the total ion packet with an energy spread of ± 20%. The method reduces the duration of the ion packets by up to 1.5ns, which enables us to obtain the restriction of resolution at a level not worse than R ~ 10500 for a TOF ~35 µs. The aim of the project is to increase the separation of isobaric ions to improve the limit of detection of the laser TOF-MS for the analysis of high-purity samples.

  13. Zenith-Distance Dependence of Chromatic Shear Effect: A Limiting Factor for an Extreme Adaptive Optics System

    CERN Document Server

    Nakajima, T

    2006-01-01

    Consider a perfect AO system with a very fine wavefront sampling interval and a very small actuator interval. If this AO system senses wavefront at a wavelength, lambda_{WFS}, and does science imaging at another wavelength, lambda_{SCI}, the light paths through the turbulent atmosphere at these two wavelengths are slightly different for a finite zenith distance, z. The error in wavefront reconstruction of the science channel associated with this non-common path effect, or so-called chromatic shear, is uncorrectable and sets an upper bound of the system performance. We evaluate the wavefront variance, sigma^2(lambda_{WFS},lambda_{SCI},z) for a typical seeing condition at Mauna Kea and find that this effect is not negligible at a large z. If we require that the Strehl ratio be greater than 99 or 95%, z must be less than about 50 or 60 deg respectively, for the combination of visible wavefront sensing and infrared science imaging.

  14. Multi-chromatic narrow-energy-spread electron bunches from laser wakefield acceleration with dual color lasers

    CERN Document Server

    Zeng, Ming; Yu, Lu-Le; Mori, Warren B; Sheng, Zheng-Ming; Hidding, Bernhard; Jaroszynski, Dino; Zhang, Jie

    2014-01-01

    A method based on laser wakefield acceleration is proposed that can generate electron bunches with an energy spectrum containing multiple spikes each with very narrow energy spread. The method is demonstrated through multi-dimensional particle-in-cell simulations. The beating of bichromatic short pulse laser fields allows controlled ionization injection of electrons into an accelerating bucket. Due to the different dispersion of the two color pulses co-propagating in the background plasma, the peak amplitude of the combined laser field oscillates during the propagation. Ionization injection occurs when the peak amplitude exceeds an ionization threshold. The threshold is exceeded for limited durations at different propagation distances. Electrons from each injection duration produce separate electron bunches. This combined with an oscillating bubble in multi-dimensions produces an energy spectrum with multi-chromatic spikes, where each spike has an energy spread less than 1%. Such electron bunches could be use...

  15. Assessment of Systematic Chromatic Errors that Impact Sub-1% Photometric Precision in Large-area Sky Surveys

    Science.gov (United States)

    Li, T. S.; DePoy, D. L.; Marshall, J. L.; Tucker, D.; Kessler, R.; Annis, J.; Bernstein, G. M.; Boada, S.; Burke, D. L.; Finley, D. A.; James, D. J.; Kent, S.; Lin, H.; Marriner, J.; Mondrik, N.; Nagasawa, D.; Rykoff, E. S.; Scolnic, D.; Walker, A. R.; Wester, W.; Abbott, T. M. C.; Allam, S.; Benoit-Lévy, A.; Bertin, E.; Brooks, D.; Capozzi, D.; Carnero Rosell, A.; Carrasco Kind, M.; Carretero, J.; Crocce, M.; Cunha, C. E.; D'Andrea, C. B.; da Costa, L. N.; Desai, S.; Diehl, H. T.; Doel, P.; Flaugher, B.; Fosalba, P.; Frieman, J.; Gaztanaga, E.; Goldstein, D. A.; Gruen, D.; Gruendl, R. A.; Gutierrez, G.; Honscheid, K.; Kuehn, K.; Kuropatkin, N.; Maia, M. A. G.; Melchior, P.; Miller, C. J.; Miquel, R.; Mohr, J. J.; Neilsen, E.; Nichol, R. C.; Nord, B.; Ogando, R.; Plazas, A. A.; Romer, A. K.; Roodman, A.; Sako, M.; Sanchez, E.; Scarpine, V.; Schubnell, M.; Sevilla-Noarbe, I.; Smith, R. C.; Soares-Santos, M.; Sobreira, F.; Suchyta, E.; Tarle, G.; Thomas, D.; Vikram, V.; DES Collaboration

    2016-06-01

    Meeting the science goals for many current and future ground-based optical large-area sky surveys requires that the calibrated broadband photometry is both stable in time and uniform over the sky to 1% precision or better. Past and current surveys have achieved photometric precision of 1%-2% by calibrating the survey’s stellar photometry with repeated measurements of a large number of stars observed in multiple epochs. The calibration techniques employed by these surveys only consider the relative frame-by-frame photometric zeropoint offset and the focal plane position-dependent illumination corrections, which are independent of the source color. However, variations in the wavelength dependence of the atmospheric transmission and the instrumental throughput induce source color-dependent systematic errors. These systematic errors must also be considered to achieve the most precise photometric measurements. In this paper, we examine such systematic chromatic errors (SCEs) using photometry from the Dark Energy Survey (DES) as an example. We first define a natural magnitude system for DES and calculate the systematic errors on stellar magnitudes when the atmospheric transmission and instrumental throughput deviate from the natural system. We conclude that the SCEs caused by the change of airmass in each exposure, the change of the precipitable water vapor and aerosol in the atmosphere over time, and the non-uniformity of instrumental throughput over the focal plane can be up to 2% in some bandpasses. We then compare the calculated SCEs with the observed DES data. For the test sample data, we correct these errors using measurements of the atmospheric transmission and instrumental throughput from auxiliary calibration systems. The residual after correction is less than 0.3%. Moreover, we calculate such SCEs for Type Ia supernovae and elliptical galaxies and find that the chromatic errors for non-stellar objects are redshift-dependent and can be larger than those for

  16. N-butyl-2-cyanoacrylate, iso-amyl-2-cyanoacrylate andhypertonic glucose with 72% chromated glycerin in gastricvarices

    Institute of Scientific and Technical Information of China (English)

    Reda Elwakil; Mohamed Fawzy Montasser; Sara M Abdelhakam; Wesam A Ibrahim

    2015-01-01

    cyanoacrylate and a mixture of 72% chromated glycerinwith hypertonic glucose solution in management ofgastric varices.METHODS: Ninety patients with gastric varicespresented to Endoscopy Unit of Ain Shams UniversityHospital were included. They were randomly allocatedinto three groups; each group included 30 patients treatedwith intravariceal sclerosant injections in biweeklysessions till complete obturation of gastric varices;Group I (n-butyl-2-cyanoacrylate; Histoacryl?), GroupII (iso-amyl-2-cyanoacrylate; Amcrylate?) and GroupIII (mixture of 72% chromated glycerin; Scleremo?with glucose solution 25%). All the procedures wereperformed electively without active bleeding. Recruitedpatients were followed up for 3 mo.RESULTS: 26% of Scleremo group had bleeding duringpuncture vs 3.3% in each of the other two groups withsignificant difference, (P 〈 0.05). None of Scleremogroup had needle obstruction vs 13.3% in each of theother two groups with no significant difference, (P 〉0.05). Rebleeding occurred in 13.3% of Histoacryl andAmcrylate groups vs 0% in Scleremo group with nosignificant difference. The in hospital mortality was 6.6%in both Histoacryl and Amcrylate groups, while it was0% in Scleremo group with no significant difference. Inthe first and second sessions, the amount of Scleremoneeded for obturation was significantly high, while the amount of Histoacryl was significantly low. Scleremo was the less costly of the two treatments. CONCLUSION: All used sclerosant substances showed efficacy and success in management of gastric varices with no significant differences except in total amount,cost and bleeding during puncture.

  17. SPARCO : a semi-parametric approach for image reconstruction of chromatic objects. Application to young stellar objects

    Science.gov (United States)

    Kluska, J.; Malbet, F.; Berger, J.-P.; Baron, F.; Lazareff, B.; Le Bouquin, J.-B.; Monnier, J. D.; Soulez, F.; Thiébaut, E.

    2014-04-01

    Context. The emergence of optical interferometers with three and more telescopes allows image reconstruction of astronomical objects at the milliarcsecond scale. However, some objects contain components with very different spectral energy distributions (SED; i.e. different temperatures), which produces strong chromatic effects on the interferograms that have to be managed with care by image reconstruction algorithms. For example, the gray approximation for the image reconstruction process results in a degraded image if the total (u,v)-coverage given by the spectral supersynthesis is used. Aims: The relative flux contribution of the central object and an extended structure changes with wavelength for different temperatures. For young stellar objects, the known characteristics of the central object (i.e., stellar SED), or even the fit of the spectral index and the relative flux ratio, can be used to model the central star while reconstructing the image of the extended structure separately. Methods: We present a new method, called SPARCO (semi-parametric algorithm for the image reconstruction of chromatic objects), which describes the spectral characteristics of both the central object and the extended structure to consider them properly when reconstructing the image of the surrounding environment. We adapted two image-reconstruction codes ( Macim , Squeeze , and MiRA ) to implement this new prescription. Results: SPARCO is applied using Macim , Squeeze , and MiRA on a young stellar object model and also on literature data on HR 5999 in the near-infrared with the VLTI. We obtain smoother images of the modeled circumstellar emission and improve the χ2 by a factor 9. Conclusions: This method paves the way to improved aperture-synthesis imaging of several young stellar objects with existing datasets. More generally, the approach can be used on astrophysical sources with similar features, such as active galactic nuclei, planetary nebulae, and asymptotic giant branch

  18. APPLICATION OF THE LONGITUDINAL CHROMATIC ABERRATION EFFECT FOR DISTANCES MEASUREMENT ON THE BASIS OF A SINGLE PHOTO

    Directory of Open Access Journals (Sweden)

    M. A. Volkova

    2016-03-01

    Full Text Available Subject of Research. We propose a method for measuring the distances to the surfaces of photographed objects based on the effect of longitudinal chromatic aberration. According to this effect, the focal length of lens depends on the wavelength of refracted light, thus the defocus of image formed by lens depends not only on the distance from image plane to lens, but also on the wavelength of light the picture was taken for (red, green or blue color ranges. Method. The proposed method of distance measurement is based on comparison of image defocus for different wavelengths (e.g., red and blue. The comparison is performed in the spatial frequency domain and is based on analysis of image complex spectrograms (the Fourier spectrum calculated locally within a window scanning the image.The distance to each point of photographed surface is calculated in closed form by the analysis of local spatial spectrum with the use of Gaussian model of point spread function. Main Results. The working capacity of distance measurement technique is partially verified on the basis of image defocus imitation by different displacement of objective lens with respect to sensor matrix of camera. The presented analysis of chromatic parameters of traditionally applied optical materials also proves the physical realizability of proposed technique. A technology is also proposed for distance measuring based on really differing image defocus in different color channels applying a special calibration of electro-optical system. Practical Relevance. The proposed distance measurement technique could be practically useful in the cases where any active illumination of objects being photographed is prohibited. It is also worth to be applied in the inexpensive low-sized optical measuring devices like Kinect for Xbox-360.

  19. Corporate Communication Strategies in Restaurant Franchises. Chromatic Analysis of Visual Corporate Identity

    Directory of Open Access Journals (Sweden)

    Dr. Juan M. Monserrat Gauchi, Juan.Monserrat@ua.es

    2009-01-01

    Full Text Available The aim of this piece of research is to determine the interrelationships between the corporate image used by the main restaurant franchises operating in Spain and the colours used by them. Following Colour Theory and the studies on colour psychology that will be dealt with during the course of this paper, we have started with the principal hypothesis that red will be the predominant colour, together with yellow, due to the fact that these colours, because of their inherent connotations, are those best able to convey the activity and philosophy of fast food companies.The field of Visual Corporate Identity is an extremely wide one in which various elements are at work, such as brand, logo, symbol, typography, colour, different compositions or versions of the brand and the application of the brand to different support media. This means that when it comes to the comparative analysis, this piece of research will focus on the chromatic aspect of each sample analysed as it operates in the fast food sector and the Spanish market, based on the assumption that the way in which elements such as colour are used is not arbitrary.The methodology used in this research meant selecting a sector of activity from within the commercial system of fast food franchises and determining the samples to be analysed based on the following criteria: highest volume of invoicing and greatest number of franchises operating in Spain. To accomplish this, the authors have based their research upon qualitative methods and secondary sources. In conclusion, we have been able to demonstrate how the use of corporate identity and, more specifically, colour, is deliberate and undoubtedly forms part of, and is subordinated to, the corporate communication strategies defined by the company.La presente investigación trata de determinar las interrelaciones que se dan entre la imagen corporativa utilizada por las principales cadenas de franquicia de restauración operativas en España y los

  20. Estudo eletrorretinográfico de visão cromática Electroretinographic study of chromatic vision

    Directory of Open Access Journals (Sweden)

    Daniela Cavalcanti Ferrara de Almeida Cunha

    2006-12-01

    Full Text Available OBJETIVO: O objetivo deste estudo é descrever o traçado eletrorretinográfico no gambá sul-americano (Didelphis aurita obtido com estímulo cromático de comprimento de onda seletivo. O eletrorretinograma é o registro das variações de voltagem nas células retinianas, desencadeadas por estímulo luminoso. O eletrorretinograma representa a atividade elétrica combinada de diferentes células, e sofre variações dependendo da fisiologia retiniana e do método de exame. MÉTODOS: Foram registrados os eletrorretinogramas de seis animais em adaptação ao escuro utilizando filtros cromáticos Kodak Wratten®, e registrada a sensibilidade espectral para comprimentos de onda específicos nas faixas de cores do azul, verde, amarelo, laranja e vermelho. RESULTADOS: Os resultados eletrorretinográficos mais consistentes foram obtidos quando o animal foi estimulado por faixas espectrais seletivas, ao invés de luz branca; e são consistentes com a curva de absorbância das opsinas descritas em fotorreceptores de marsupiais. Estudos prévios sugeriram a tricromacia dos marsupiais por microespectrofotometria de opsinas e imuno-histoquímica de retina. Esse fundamento morfológico não tinha demonstração fisiológica eletrorretinográfica, até este estudo. CONCLUSÃO: O gambá sul-americano tem se mostrado interessante como animal experimental no estudo comparativo da fisiologia visual em mamíferos, especialmente no estudo filogenético da visão cromática. Os marsupiais apresentam um modelo retiniano que superpõe os sistemas fotópico e escotópico; e o gênero Didelphis conserva características encontradas em fósseis do período pleoceno. Portanto, o sistema visual de um marsupial resgata características dos primórdios da evolução dos mamíferos, até o desenvolvimento dos padrões retinianos modernos.PURPOSE: To describe the electroretinogram of the South-American opossum (Didelphis aurita obtained by chromatic stimulus of specific

  1. Analytical and numerical analysis of third-order geometric and first-order chromatic aberrations in a bi-potential electrostatic lens

    CERN Document Server

    Xi Men Jiye

    2000-01-01

    Glaser and Robl (Z. Angew. Math. Phys. 2 (1951) 444) first proposed a theoretical model for a bi-potential electrostatic lens, whose axial potential distribution satisfies the law of electrostatics and whose paraxial trajectory equation is soluble. In this paper, the Gaussian optical property in the bi-potential electrostatic lens has been thoroughly studied. Meanwhile, based on electron optical canonical aberration theory, analytical formulas of third-order geometrical and first-order chromatic aberration coefficients have first been derived and their computational results obtained for this bi-potential electrostatic lens. It is to be emphasized that this theoretical study can be used to estimate third-order geometric and first-order chromatic aberrations and to provide a theoretical criterion for numerical computation in a rotationally symmetric electrostatic immersion lens.

  2. Reduction of chromatic dispersion due to coupling for synchronized-router-based flat-passband filter using multiple-input arrayed waveguide grating.

    Science.gov (United States)

    Maru, Koichi; Fujii, Yusaku

    2009-11-23

    An approach to reducing the chromatic dispersion due to coupling between input waveguides before the input slab for a synchronized-router-based flat-passband filter using a multiple-input arrayed waveguide grating (AWG) is proposed. The proposed method uses phase compensation at the waveguide array of the AWG by correction of waveguide lengths. The characteristics of the flat-passband filter that consists of a multiple-input AWG combined with cascaded Mach-Zehnder interferometers (MZIs) are simulated using a theoretical model of the multiple-input AWG based on Fourier optics and the coupled-mode theory. The simulation result reveals that the chromatic dispersion within the passband can be significantly reduced by using phase compensation and additional dummy waveguides at the input just before the slab.

  3. Acyclic chromatic indices of K4-minor free graphs%没有K4-图子式的图的无圈边色数

    Institute of Scientific and Technical Information of China (English)

    王维凡; 舒巧君

    2011-01-01

    一个图G的无圈k-边染色是指G的一个正常的不产生双色圈的k-边染色.G的无圈边色数a1(G)定义为使得G有一个无圈k-边染色的最小的整数k.本文完全刻画了最大度不为4的没有K4-图子式的图的无圈边色数.%An acyclic edge coloring of a graph G is a proper edge coloring such that no Dichromatic cycles are produced. The acyclic chromatic index a'(G) of G is the smallest integer k such that G has an acyclic edge coloring using k colors. In this paper, we determine completely the acyclic chromatic indices of K4-minor free graphs with maximum degree not equal to 4.

  4. Transmission Experiment of 80-Gbit/s-Based WDM Signals Using an OPGW in the Field and In-service Chromatic Dispersion Monitering through Envelope Modulated WDM Signals

    Science.gov (United States)

    Yamashita, Ikuo; Oro, Kyoichi; Seikai, Shigeyuki

    A field experiment on transmission of 80-Gbit/s-based wavelength division multiplexing (WDM) signals is successfully carried out. In order to keep good transmission quality, technique of an in-service dispersion monitoring and an adaptive control of the chromatic dispersion are proposed. Difference of the propagation delay between channels caused by the chromatic dispersion of the transmission line is detected using signals superimposed on the envelope of the WDM pulses. Dispersion alteration of the transmission line is estimated from the measured delay in real-time. Accuracy of the method is clarified through a transmission experiment using wound fibers in an oven changing their temperature. The field experiment on 80Gbit/s × 8WDM transmission using an OPGW with 60km × 2spans is carried out and fine BER performances are obtained in all channels. Transmission properties are found to be stable owing to the dispersion control techniques throughout the field trial.

  5. Some results on circular chromatic number of a graph%图的圆色数的一些结果

    Institute of Scientific and Technical Information of China (English)

    吴建专; 林文松

    2008-01-01

    设k和d是2个互素的正整数且k≥2d.Gkd是一个图,它的顶点集合为{0,1,…,k一1},边集合为{ij|d≤|i-j|≤k0d,i,j=0,1,…,k-1}.图G的圆色数Xc(G)定义为使得图G与Gkd同态的2个正整数k和d的最小比值k/d.研究了Xc(G)和Xc(G-v)之间的关系,对任意顶点v求出了Xc(Gkd-v)的精确值,给出了具有对任意顶点Xc(G-v)=Xc(G)-1和其他特定性质的图类;并对图的圆色数的一些下界进行了探讨,给出了图的圆色数达到下界X-1+1/α的充要条件,这里X和α分别是图G的点色数和独立数.%For two integers k and d with (k, d) = 1 and k≥2d, letedge if and only if d ≤ | i -j |≤ k - d. The circular chromaticnumber Xc (G) of a graph G is the minimum of k/d for which Gadmits a homomorphism to Gkd. The relationship between Xc(G -v) and Xc (G)is investigated. In particular, the circular chromaticnumber of Gkd - v for any vertex v is determined. Some graphswith Xc ( G - v) =Xc (G) - 1 for any vertex v and with certainproperties are presented. Some lower bounds for the circularchromatic number of a graph are studied, and a necessary andsufficient condition under which the circular chromatic number ofa graph attains the lower bound X - 1 + 1/α is proved, where X isthe chromatic number of G and α is its independence number.

  6. Classes of Chromatically Normal Graphs of Bipartite Graphs K(m,n)-A%二部图K(m,n)-A中的色正规图类

    Institute of Scientific and Technical Information of China (English)

    邹辉文

    2000-01-01

    Let G be a simple graph and P(G,λ) denote the chromatic polynomial of G. Then two simple graphs H and G are said to be chromatically equivalent (in notation: H~G) if P(H,λ)=P(G,λ). A class of graphs L is said to be a class of chromatically normal graphs if for any graphs H,G∈L,H~G implies that H is isomorphic to G.Let K(m,n)-A denote the bipartite graph obtained by deleting a set of edges A from a complete bipartite graph K(m,n).Let L-s2={K(m,n)-A||A|=s,n≥m>s}.In this paper we prove that L-22,L-32 and L-42 are classes of chromatically normal graphs.%设P(G,λ)表示简单图G的色多项式.简单图H称为与G是色等价的(记作H∽G),如果P(H,λ)=P(G,λ).简单图类L称为色正规图类,若对任意H,G∈L使H∽G都有H与G同构.令K(m,n)-A表示从完全二部图K(m,n)中删去子边集A所得的二部图,L-s2={K(m,n)-A||A|=s,n≥m>s}.本文证明L-s2,s=2,3,4,均是色正规图类.

  7. The effects of longitudinal chromatic aberration and a shift in the peak of the middle-wavelength sensitive cone fundamental on cone contrast.

    Science.gov (United States)

    Rucker, F J; Osorio, D

    2008-09-01

    Longitudinal chromatic aberration is a well-known imperfection of visual optics, but the consequences in natural conditions, and for the evolution of receptor spectral sensitivities are less well understood. This paper examines how chromatic aberration affects image quality in the middle-wavelength sensitive (M-) cones, viewing broad-band spectra, over a range of spatial frequencies and focal planes. We also model the effects on M-cone contrast of moving the M-cone fundamental relative to the long- and middle-wavelength (L- and M-cone) fundamentals, while the eye is accommodated at different focal planes or at a focal plane that maximizes luminance contrast. When the focal plane shifts towards longer (650 nm) or shorter wavelengths (420 nm) the effects on M-cone contrast are large: longitudinal chromatic aberration causes total loss of M-cone contrast above 10-20 c/d. In comparison, the shift of the M-cone fundamental causes smaller effects on M-cone contrast. At 10 c/d a shift in the peak of the M-cone spectrum from 560 to 460 nm decreases M-cone contrast by 30%, while a 10 nm blue-shift causes only a minor loss of contrast. However, a noticeable loss of contrast may be seen if the eye is focused at focal planes other than that which maximizes luminance contrast. The presence of separate long- and middle-wavelength sensitive cones therefore has a small, but not insignificant cost to the retinal image via longitudinal chromatic aberration. This aberration may therefore be a factor limiting evolution of visual pigments and trichromatic color vision.

  8. Ce对玻璃光谱曲线及色度指标的影响%Influence of Cerium on the Spectra and Chromaticity of Glass

    Institute of Scientific and Technical Information of China (English)

    代丽萍; 白晓华

    2011-01-01

    A golden glass was produced by combined coloration of CeO2 and TiO2. The amount of CeO2 additive and redox of the glass batch affect the optical properties and chromaticity of glass so that large chromatic - aberration appears. By changing Ce addition and redox agent in glass batch a splendid golden glass sample was obtained. The spectra and chromaticity analysis was carried out by using CARY500 spectrophotometer. Results indicate that the optical properties and chromaticity of this new golden yellow glass are highly dependent on those factors, such as, amount of colourants, oxidation -reduction of glass batch and addition of fluorite.%用CeO2及TiO2混合着色可以生产金黄色的玻璃,铈的用量及玻璃配合料氧化还原性都容易造成玻璃光学指标及色度指标的改变,使玻璃产生较大的色差.通过改变玻璃中铈的用量和氧化还原剂用量熔制玻璃样片,然后用CARY500分光光度计对玻璃样片进行光度及色度指标分析.结果表明:着色剂的用量、配合料的氧化还原性、萤石的添加量对玻璃的光学指标及色度指标都有较大影响.

  9. Ultrasonic assisted rapid synthesis of high uniform super-paramagnetic microspheres with core-shell structure and robust magneto-chromatic ability

    Science.gov (United States)

    Zhang, Wenyan; Chen, Jiahua; Wang, Wei; Lu, GongXuan; Hao, Lingyun; Ni, Yaru; Lu, Chunhua; Xu, Zhongzi

    2017-03-01

    Super-paramagnetic core-shell microspheres were synthesized by ultrasonic assisted routine under low ultrasonic irradiation powers. Compared with conventional routine, ultrasonic effect could not only improve the uniformity of the core-shell structure of Fe3O4@SiO2, but shorten the synthesis time in large scale. Owing to their hydrophilicity and high surface charge, the Fe3O4@SiO2 microspheres could be dispersed well in distilled water to form homogeneous colloidal suspension. The suspensions have favorable magneto-chromatic ability that they sensitively exhibit brilliant colorful ribbons by magnetic attraction. The colorful ribbons, which distributed along the magnetic lines, make morphology of the magnetic fields become "visible" to naked eyed. Those colorful ribbons originate from strong magnetic interaction between the microspheres and magnetic fields. Furthermore, the magneto-chromatic performance is reversible as the colorful ribbons vanished rapidly with the removing of magnetic fields. The silica layer effectively enhanced the acid resistance and surface-oxidation resistance of theFe3O4@SiO2 microspheres, so they could exhibit stable magnetic nature and robust magneto-chromatic property in acid environment.

  10. Influences of wide-angle and multi-beam interference on the chromaticity and efficiency of top-emitting white organic light-emitting diodes

    Energy Technology Data Exchange (ETDEWEB)

    Deng, Lingling; Zhou, Hongwei; Chen, Shufen, E-mail: iamsfchen@njupt.edu.cn; Liu, Bin; Wang, Lianhui [Key Laboratory for Organic Electronics and Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210023 (China); Shi, Hongying [Jiangsu-Singapore Joint Research Center for Organic/Bio- Electronics and Information Displays and Institute of Advanced Materials, Nanjing Tech University, Nanjing 211816 (China); Huang, Wei, E-mail: iamdirector@njupt.edu.cn [Key Laboratory for Organic Electronics and Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210023 (China); Jiangsu-Singapore Joint Research Center for Organic/Bio- Electronics and Information Displays and Institute of Advanced Materials, Nanjing Tech University, Nanjing 211816 (China)

    2015-02-28

    Wide-angle interference (WI) and multi-beam interference (MI) in microcavity are analyzed separately to improve chromaticity and efficiency of the top-emitting white organic light-emitting diodes (TWOLEDs). A classic electromagnetic theory is used to calculate the resonance intensities of WI and MI in top-emitting organic light-emitting diodes (TOLEDs) with influence factors (e.g., electrodes and exciton locations) being considered. The role of WI on the performances of TOLEDs is revealed through using δ-doping technology and comparing blue and red EML positions in top-emitting and bottom-emitting devices. The blue light intensity significantly increases and the chromaticity of TWOLEDs is further improved with the use of enhanced WI (the blue emitting layer moving towards the reflective electrode) in the case of a weak MI. In addition, the effect of the thicknesses of light output layer and carrier transport layers on WI and MI are also investigated. Apart from the microcavity effect, other factors, e.g., carrier balance and carrier recombination regions are considered to obtain TWOLEDs with high efficiency and improved chromaticity near white light equal-energy point.

  11. Improvement of depth resolution of ADF-SCEM by deconvolution: effects of electron energy loss and chromatic aberration on depth resolution.

    Science.gov (United States)

    Zhang, Xiaobin; Takeguchi, Masaki; Hashimoto, Ayako; Mitsuishi, Kazutaka; Tezuka, Meguru; Shimojo, Masayuki

    2012-06-01

    Scanning confocal electron microscopy (SCEM) is a new imaging technique that is capable of depth sectioning with nanometer-scale depth resolution. However, the depth resolution in the optical axis direction (Z) is worse than might be expected on the basis of the vertical electron probe size calculated with the existence of spherical aberration. To investigate the origin of the degradation, the effects of electron energy loss and chromatic aberration on the depth resolution of annular dark-field SCEM were studied through both experiments and computational simulations. The simulation results obtained by taking these two factors into consideration coincided well with those obtained by experiments, which proved that electron energy loss and chromatic aberration cause blurs at the overfocus sides of the Z-direction intensity profiles rather than degrade the depth resolution much. In addition, a deconvolution method using a simulated point spread function, which combined two Gaussian functions, was adopted to process the XZ-slice images obtained both from experiments and simulations. As a result, the blurs induced by energy loss and chromatic aberration were successfully removed, and there was also about 30% improvement in the depth resolution in deconvoluting the experimental XZ-slice image.

  12. Effect of the gamma radiation in hydrotalcite with chromates; Efecto de la Radiacion Gamma en Hidrotalcitas con Cromatos

    Energy Technology Data Exchange (ETDEWEB)

    Martinez G, S. [Facultad de Ciencias, Universidad Autonoma del Estado de Mexico, Instituto Literario No. 100 Col. Centro, 50000 Toluca, Estado de Mexico (Mexico); Bulbulian, S. [ININ, Carr. Mexico-Toluca Km. 36.5, 52045 Ocoyoacac, Estado de Mexico (Mexico)]. e-mail: soniakorn@yahoo.com

    2004-07-01

    At the moment the generation of radioactive wastes is topic of numerous studies. In this work was retained anionic material, chromates, in hydrotalcite that are anionic exchangers. It was proposed to warm the HT at different temperatures of 600 C up to 1200 C with the purpose of immobilizing the chromium inside the hydrotalcite. To high temperatures (1000 and 1200 C) it was formed one spinel (MgCr{sub 2}O{sub 4}) that is a very stable compound. It was found that when increasing the heating temperature, the anions are retained strongly. The immobilization of the Cr was determined through the chromium lixiviation with solutions 1N and 5N of NaCl. Also it was studied the effect of the radiation on the heated materials. The radiation dose used for it was of 1000 and 6000 kGy. The results show that for the calcined samples at 1000 and 1200 C irradiated or no irradiated, the chromium is strongly retained in form of spinels that is the structure formed after the calcination of the material. (Author)

  13. Organic solution-processible electroluminescent molecular glasses for non-doped standard red OLEDs with electrically stable chromaticity

    Energy Technology Data Exchange (ETDEWEB)

    Bi, Xiaoman; Zuo, Weiwei; Liu, Yingliang, E-mail: liuylxn@sohu.com; Zhang, Zhenru; Zeng, Cen; Xu, Shengang; Cao, Shaokui, E-mail: caoshaokui@zzu.edu.cn

    2015-10-15

    Highlights: • The D–A–D electroluminescent molecular glasses are synthesized. • Non-doped red electroluminescent film is fabricated by spin-coating. • Red OLED shows stable wavelength, luminous efficiency and chromaticity. • CIE1931 coordinate is in accord with standard red light in PAL system. - Abstract: Organic light-emitting molecular glasses (OEMGs) are synthesized through the introduction of nonplanar donor and branched aliphatic chain into electroluminescent emitters. The target OEMGs are characterized by {sup 1}H NMR, {sup 13}C NMR, IR, UV–vis and fluorescent spectra as well as elemental analysis, TG and DSC. The results indicated that the optical, electrochemical and electroluminescent properties of OEMGs are adjusted successfully by the replacement of electron-donating group. The non-doped OLED device with a standard red electroluminescent emission is achieved by spin-coating the THF solution of OEMG with a triphenylamine moiety. This non-doped red OLED device takes on an electrically stable electroluminescent performance, including the stable maximum electroluminescent wavelength of 640 nm, the stable luminous efficiency of 2.4 cd/A and the stable CIE1931 coordinate of (x, y) = (0.64, 0.35), which is basically in accord with the CIE1931 coordinate (x, y) = (0.64, 0.33) of standard red light in PAL system.

  14. Efficient top-emitting white organic light emitting device with an extremely stable chromaticity and viewing-angle

    Institute of Scientific and Technical Information of China (English)

    Shao Ming; Guo Xu; Chen Shu-Fen; Fan Qu-Li; Huang Wei

    2012-01-01

    In this paper,we report on the fabrication of a top-emitting electrophosphorescent p-i- n white organic lightemitting diode on the basis of a low-reflectivity Sm/Ag semi-transparent cathode together with a thickness-optimized ZnS out-coupling layer.With a 24-nm out-coupling layer,the reflectivity of the cathode is reduced to 8% at 492 nm and the mean reflectivity is 24% in the visible area. By introducing an efficient electron blocking layer tris(1-phenylpyrazolato,N,C2')iridium(III) (Ir(ppz)3) to confine the exciton recombination area,the current efficiency and the colour stability of the device are effectively improved.A white emission with the Ir(ppz)3 layer exhibits a maximum current efficiency of 9.8 cd/A at 8 V,and the Commission Internationale de L'Eclairage (CIE) chromaticity coordinates are almost constant during a large voltage change of 6 V-11 V.There is almost no viewing angular dependence in the spectrum when the viewing angle is no more than 45°,with a CIEx,y coordinate variation of only (±0.0025,±0.0008).Even at a large viewing angle (75°),the CIEx,y coordinate change is as small as (±0.0087,±0.0013).

  15. Evaluation of the toxic effects of arsenite, chromate, cadmium, and copper using a battery of four bioassays

    Energy Technology Data Exchange (ETDEWEB)

    Ko, Kyung-Seok; Lee, Pyeong-Koo [Korea Institute of Geoscience and Mineral Resources (KIGAM), Daejeon (Korea, Republic of). Geologic Environment Div.; Kong, In Chul [Yeungnam Univ., Kyungbuk (Korea, Republic of). Dept. of Environmental Engineering

    2012-09-15

    The sensitivities of four different kinds of bioassays to the toxicities of arsenite, chromate, cadmium, and copper were compared. The different bioassays exhibited different sensitivities, i.e., they responded to different levels of toxicity of each of the different metals. However, with the exception of the {alpha}-glucosidase enzyme activity, arsenite was the most toxic compound towards all the tested organisms, exhibiting the highest toxic effect on the seeds of Lactuca, with an EC{sub 50} value of 0.63 mg/L. The sensitivities of Lactuca and Raphanus were greater than the sensitivities of two other kinds of seeds tested. Therefore, these were the seeds appropriate for use in a seed germination assay. A high revertant mutagenic ratio (5:1) of Salmonella typhimurium was observed with an arsenite concentration of 0.1 {mu}g/plate, indicative of a high possibility of mutagenicity. These different results suggested that a battery of bioassays, rather than one bioassay alone, is needed as a more accurate and better tool for the bioassessment of environmental pollutants. (orig.)

  16. Effects of arsenate, chromate, and sulfate on arsenic and chromium uptake and translocation by arsenic hyperaccumulator Pteris vittata L.

    Science.gov (United States)

    de Oliveira, Letúzia Maria; Ma, Lena Q; Santos, Jorge A G; Guilherme, Luiz R G; Lessl, Jason T

    2014-01-01

    We investigated effects of arsenate (AsV), chromate (CrVI) and sulfate on As and Cr uptake and translocation by arsenic hyperaccumulator Pteris vittata (PV), which was exposed to AsV, CrVI and sulfate at 0, 0.05, 0.25 or 1.25 mM for 2-wk in hydroponic system. PV was effective in accumulating large amounts of As (4598 and 1160 mg/kg in the fronds and roots at 0.05 mM AsV) and Cr (234 and 12,630 mg/kg in the fronds and roots at 0.05 mM CrVI). However, when co-present, AsV and CrVI acted as inhibitors, negatively impacting their accumulation in PV. Arsenic accumulation in the fronds was reduced by 92% and Cr by 26%, indicating reduced As and Cr translocation. However, addition of sulfate increased uptake and translocation of As by 26-28% and Cr by 1.63 fold. This experiment demonstrated that As and Cr inhibited each other in uptake and translocation by PV but sulfate enhanced As and Cr uptake and translocation by PV.

  17. Analysis and Compensation for Lateral Chromatic Aberration in a Color Coding Structured Light 3D Measurement System.

    Science.gov (United States)

    Huang, Junhui; Xue, Qi; Wang, Zhao; Gao, Jianmin

    2016-09-03

    While color-coding methods have improved the measuring efficiency of a structured light three-dimensional (3D) measurement system, they decreased the measuring accuracy significantly due to lateral chromatic aberration (LCA). In this study, the LCA in a structured light measurement system is analyzed, and a method is proposed to compensate the error caused by the LCA. Firstly, based on the projective transformation, a 3D error map of LCA is constructed in the projector images by using a flat board and comparing the image coordinates of red, green and blue circles with the coordinates of white circles at preselected sample points within the measurement volume. The 3D map consists of the errors, which are the equivalent errors caused by LCA of the camera and projector. Then in measurements, error values of LCA are calculated and compensated to correct the projector image coordinates through the 3D error map and a tri-linear interpolation method. Eventually, 3D coordinates with higher accuracy are re-calculated according to the compensated image coordinates. The effectiveness of the proposed method is verified in the following experiments.

  18. Analysis and Compensation for Lateral Chromatic Aberration in a Color Coding Structured Light 3D Measurement System

    Directory of Open Access Journals (Sweden)

    Junhui Huang

    2016-09-01

    Full Text Available While color-coding methods have improved the measuring efficiency of a structured light three-dimensional (3D measurement system, they decreased the measuring accuracy significantly due to lateral chromatic aberration (LCA. In this study, the LCA in a structured light measurement system is analyzed, and a method is proposed to compensate the error caused by the LCA. Firstly, based on the projective transformation, a 3D error map of LCA is constructed in the projector images by using a flat board and comparing the image coordinates of red, green and blue circles with the coordinates of white circles at preselected sample points within the measurement volume. The 3D map consists of the errors, which are the equivalent errors caused by LCA of the camera and projector. Then in measurements, error values of LCA are calculated and compensated to correct the projector image coordinates through the 3D error map and a tri-linear interpolation method. Eventually, 3D coordinates with higher accuracy are re-calculated according to the compensated image coordinates. The effectiveness of the proposed method is verified in the following experiments.

  19. Chromatic dispersion mitigation in long-haul fiber-optic communication networks by sub-band partitioning.

    Science.gov (United States)

    Malekiha, Mahdi; Tselniker, Igor; Plant, David V

    2015-12-14

    We propose and experimentally demonstrate a novel sub-band multiplexed data architecture for chromatic dispersion (CD) mitigation. We have demonstrated 32 GBaud multi-sub-band (MSB) dual-polarization (DP) 16QAM transmission over 2400 km. Using this approach, the transmitted signal bandwidth is divided into multiple narrow-bandwidth sub-bands, each operating at a lower baud rate. Within each sub-band bandwidth, the CD frequency response can be approximated as a linear-phase band-pass filter, which can be considered as an analog delay that does not require compensation. Therefore, the resulting receiver digital signal processing (DSP) is simplified due to the removal of the CD compensation equalizer. In addition, this leads to efficient parallelization of DSP tasks by deploying multiple independent sub-band processors running at a lower clock rate. The proposed system reduces receiver computational complexity and offers 1 dB higher Kerr-nonlinearity tolerance and 2% extended transmission reach in comparison to the conventional single carrier systems.

  20. Effects of Antenna Beam Chromaticity on Redshifted 21 cm Power Spectrum and Implications for Hydrogen Epoch of Reionization Array

    Science.gov (United States)

    Thyagarajan, Nithyanandan; Parsons, Aaron R.; DeBoer, David R.; Bowman, Judd D.; Ewall-Wice, Aaron M.; Neben, Abraham R.; Patra, Nipanjana

    2016-07-01

    Unaccounted for systematics from foregrounds and instruments can severely limit the sensitivity of current experiments from detecting redshifted 21 cm signals from the Epoch of Reionization (EoR). Upcoming experiments are faced with a challenge to deliver more collecting area per antenna element without degrading the data with systematics. This paper and its companions show that dishes are viable for achieving this balance using the Hydrogen Epoch of Reionization Array (HERA) as an example. Here, we specifically identify spectral systematics associated with the antenna power pattern as a significant detriment to all EoR experiments which causes the already bright foreground power to leak well beyond ideal limits and contaminate the otherwise clean EoR signal modes. A primary source of this chromaticity is reflections in the antenna-feed assembly and between structures in neighboring antennas. Using precise foreground simulations taking wide-field effects into account, we provide a generic framework to set cosmologically motivated design specifications on these reflections to prevent further EoR signal degradation. We show that HERA will not be impeded by such spectral systematics and demonstrate that even in a conservative scenario that does not perform removal of foregrounds, HERA will detect the EoR signal in line-of-sight k-modes, {k}\\parallel ≳ 0.2 h Mpc-1, with high significance. Under these conditions, all baselines in a 19-element HERA layout are capable of detecting EoR over a substantial observing window on the sky.

  1. The Baroque monuments of Modica (Eastern Sicily): assessment of causes of chromatic alteration of stone building materials

    Science.gov (United States)

    Belfiore, Cristina M.; La Russa, Mauro F.; Pezzino, Antonino; Campani, Elisa; Casoli, Antonella

    2010-09-01

    The Baroque monuments of several cities in eastern Sicily, built of local calcarenitic stone, are often subjected to conservation treatments, since they undergo many forms of alteration and degradation which can cause significant damage. However, a recent study of these building materials (Barone et al. in Environ. Geol. 54:1501, 2008) has demonstrated that some protective products, once applied, cause irreversible chromatic alterations. The façades of the monuments of the historic city centre of Modica are typically creamy yellow in colour, sometimes varying slightly due to the use of various pigments, such as clayey and gypseous earths (La Russa et al. in Appl. Phys. A 92:185, 2008). However, in some cases, these nuances are lost due to the application of protective products. This work provides a petrographic and colorimetric characterisation of the calcarenitic stone used to create the façades of the churches of S. Pietro, S. Maria del Soccorso and S. Maria dell’Annunziata in Modica, also by comparisons with locally quarried samples. In addition, it aims to identify protective substances which may have been used during previous restoration work. Analytical techniques included polarising optical microscopy, spectrophotometric colorimetric tests, Fourier-transform infrared spectroscopy (FTIR) and gas chromatography coupled with mass spectrometry (GC-MS).

  2. Exergy analysis of the Chartherm process for energy valorization and material recuperation of chromated copper arsenate (CCA) treated wood waste.

    Science.gov (United States)

    Bosmans, A; Auweele, M Vanden; Govaerts, J; Helsen, L

    2011-04-01

    The Chartherm process (Thermya, Bordeaux, France) is a thermochemical conversion process to treat chromated copper arsenate (CCA) impregnated wood waste. The process aims at maximum energy valorization and material recuperation by combining the principles of low-temperature slow pyrolysis and distillation in a smart way. The main objective of the exergy analysis presented in this paper is to find the critical points in the Chartherm process where it is necessary to apply some measures in order to reduce exergy consumption and to make energy use more economic and efficient. It is found that the process efficiency can be increased with 2.3-4.2% by using the heat lost by the reactor, implementing a combined heat and power (CHP) system, or recuperating the waste heat from the exhaust gases to preheat the product gas. Furthermore, a comparison between the exergetic performances of a 'chartherisation' reactor and an idealized gasification reactor shows that both reactors destroy about the same amount of exergy (i.e. 3500kWkg(wood)(-1)) during thermochemical conversion of CCA-treated wood. However, the Chartherm process possesses additional capabilities with respect to arsenic and tar treatment, as well as the extra benefit of recuperating materials.

  3. Astaxanthin and papilioerythrinone in the skin of birds: a chromatic convergence of two metabolic routes with different precursors?

    Science.gov (United States)

    García-de Blas, Esther; Mateo, Rafael; Guzmán Bernardo, Francisco Javier; Rodríguez Martín-Doimeadios, Rosa Carmen; Alonso-Alvarez, Carlos

    2014-05-01

    Carotenoids are organic pigments involved in several important physiological functions and may serve as indicators of individual quality in animals. These pigments are only obtained by animals from the diet, but they can be later transformed into other carotenoids by specific enzymatic reactions. The diet of farm-reared and probably wild red-legged partridges ( Alectoris rufa) is mainly based on cereals that contain high levels of lutein and zeaxanthin. These two carotenoids are also predominant in internal tissues and blood of red-legged partridges. However, in their integuments, astaxanthin and papilioerythrinone (the last one identified in this work) are mainly present in their free form and esterified with fatty acids. According to available literature about carotenoid metabolism in animals, we propose that astaxanthin ( λ max = 478 nm) and papilioerythrinone ( λ max = 452-478 nm) are the result of a chromatic convergence of the transformation of dietary zeaxanthin and lutein, respectively. Moreover, the results obtained in this work provide the first identification by liquid chromatography coupled to accurate mass quadrupole time-of-flight mass spectrometer system of papilioerythrinone ( m/z 581.3989 [M + H]+) in the skin (i.e., not feathers) of a vertebrate. Astaxanthin and papilioerythrinone are very close in terms of chemical structure and coloration, and the combination of these two keto-carotenoids is responsible for the red color of the ornaments in red-legged partridges.

  4. High performance flexible top-emitting warm-white organic light-emitting devices and chromaticity shift mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Hongying; Deng, Lingling; Chen, Shufen, E-mail: iamsfchen@njupt.edu.cn, E-mail: wei-huang@njupt.edu.cn; Xu, Ying; Zhao, Xiaofei; Cheng, Fan [Key Laboratory for Organic Electronics and Information Displays (KLOEID) and Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, 210023 Nanjing (China); Huang, Wei, E-mail: iamsfchen@njupt.edu.cn, E-mail: wei-huang@njupt.edu.cn [Key Laboratory for Organic Electronics and Information Displays (KLOEID) and Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, 210023 Nanjing (China); Jiangsu-Singapore Joint Research Center for Organic/Bio- Electronics and Information Displays and Institute of Advanced Materials, Nanjing University of Technology, Nanjing 211816 (China)

    2014-04-15

    Flexible warm-white top-emitting organic light-emitting devices (TEOLEDs) are fabricated onto PET substrates with a simple semi-transparent cathode Sm/Ag and two-color phosphors respectively doped into a single host material TCTA. By adjusting the relative position of the orange-red EML sandwiched between the blue emitting layers, the optimized device exhibits the highest power/current efficiency of 8.07 lm/W and near 13 cd/A, with a correlated color temperature (CCT) of 4105 K and a color rendering index (CRI) of 70. In addition, a moderate chromaticity variation of (-0.025, +0.008) around warm white illumination coordinates (0.45, 0.44) is obtained over a large luminance range of 1000 to 10000 cd/m{sup 2}. The emission mechanism is discussed via delta-doping method and single-carrier device, which is summarized that the carrier trapping, the exciton quenching, the mobility change and the recombination zone alteration are negative to color stability while the energy transfer process and the blue/red/blue sandwiched structure are contributed to the color stability in our flexible white TEOLEDs.

  5. Influence of transition metals on Streptomyces coelicolor and S. sioyaensis and generation of chromate-reducing mutants.

    Science.gov (United States)

    Gren, Tetiana; Ostash, Bohdan; Hrubskyy, Yaroslav; Tistechok, Stepan; Fedorenko, Victor

    2014-03-01

    Bacteria-assisted bioremediation is widely recognized as a low-cost method to minimize the consequences of soil pollution with toxic metals originating from industrial sites. Strains used in bioremediation have to deal with high metal load via biosorption, reduction, bioprecipitation, metal sequestration, and/or chelation. Actinobacteria, and streptomycetes in particular, are considered a perspective group for bioremediation as natural soil inhabitants with extensive secondary metabolism. Nevertheless, there is no reference information on survival of the model streptomycetes in the presence of the most abundant metal pollutants. Also, there are no reports describing the selection approaches towards improvement of bioremediation properties. In this work, the resistance of Streptomyces coelicolor M145 and Streptomyces sioyaensis Lv81 to certain transition metals and their growth under different pH values are described for the first time. Spontaneous chromate-resistant S. sioyaensis Lv81-138 strain was selected in the course of this work. Strain Lv81-138 is the most efficient actinobacterial Cr(VI) reducer reported so far, capable of converting 12 mmol/L of Cr(VI) into Cr(III) in a medium supplemented with 50 mmol/L K2CrO4.

  6. Garnacha Tintorera-based sweet wines: chromatic properties and global phenolic composition by means of UV-Vis spectrophotometry.

    Science.gov (United States)

    Figueiredo-González, M; Cancho-Grande, B; Simal-Gándara, J

    2013-09-01

    Valdeorras (the N.W. corner of Spain) wants to promote the production and marketing of new sweet wines. The present work represents the first study on sweet wines manufactured with red grapes Vitis vinifera L. Garnacha Tintorera, a teinturier cultivar. Two different red sweet wines were elaborated: the first one was made with dried grapes; Vitis vinifera L. Garnacha Tintorera has excellent potential to produce wines from raisined grapes; the second one, a fortified sweet wine aged in oak barrels. Different red Garnacha Tintorera-based wines (a dry base wine, GBW; a naturally sweet wine, GNSW; and a fortified sweet wine, GFSW) were characterized. Chromatic characteristics and phenolic compounds were established by spectrophotometric methods in order to assess the technology of Garnacha Tintorera-based sweet wines. High molecular weight brown polymers, produced during the grape drying process and isolated from sweet wines by the dialysis process, were responsible for the brown colour of sweet wines. As a consequence, yellowness of sweet wines was also higher which was confirmed by colorimetric indexes. With respect to phenolic content, GFSW presented the lowest content because the maceration-alcoholic fermentation was stopped through the addition of alcohol before the diffusion of red pigments from skins to must was complete. GNSW presented the highest phenolic content due to the concentration effect resulting from evaporation of water from the grapes. Anthocyanins of sweet wines were polymerised in great extent. The percentage of polymerised tannins was sufficient to guarantee the aging process of sweet wines.

  7. Modification of Nanoclinoptilolite Zeolite with Hexadecyltrimethylammonium Surfactant as an Active Ingredient of Chromate-Selective Membrane Electrode

    Directory of Open Access Journals (Sweden)

    Alireza Nezamzadeh-Ejhieh

    2013-01-01

    Full Text Available A novel chromate selective PVC membrane electrode was constructed using a hexadecyltrimethylammonium-surfactant modified zeolite (SMZ. Nano particles of an Iranian clinoptilolite zeolite were prepared by a ball-mill mechanical method and characterized by FT-IR, SEM and XRD. Best performance was exhibited at the membrane composition of SMZ : PVC : dioctyl phthalate (DOP in the ratio of 4 : 32 : 64. This membrane worked well over a wide concentration range from to  mol L−1 of with a Nernstian slope of  mv per decade of concentration with detection limit of  mol L−1 in a wide pH range of 6.8–10.7. The response time of the sensor is 5–10 s over a period of 2 months with good reproducibility. The selectivity coefficients of the proposed electrode towards various interfering ions were determined by FIM and SSM methods. The sensor was successfully used as indicator electrode in the potentiometric titration of against Pb(II and determination of chromium in an electroplating wastewater sample.

  8. Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods. 4. Artificial aging of model samples of co-precipitates of lead chromate and lead sulfate.

    Science.gov (United States)

    Monico, Letizia; Janssens, Koen; Miliani, Costanza; Van der Snickt, Geert; Brunetti, Brunetto Giovanni; Cestelli Guidi, Mariangela; Radepont, Marie; Cotte, Marine

    2013-01-15

    Previous investigations about the darkening of chrome yellow pigments revealed that this form of alteration is attributable to a reduction of the original Cr(VI) to Cr(III), and that the presence of sulfur-containing compounds, most often sulfates, plays a key role during this process. We recently demonstrated that different crystal forms of chrome yellow pigments (PbCrO(4) and PbCr(1-x)S(x)O(4)) are present in paintings by Vincent van Gogh. In the present work, we show how both the chemical composition and the crystalline structure of lead chromate-based pigments influence their stability. For this purpose, oil model samples made with in-house synthesized powders of PbCrO(4) and PbCr(1-x)S(x)O(4) were artificially aged and characterized. We observed a profound darkening only for those paint models made with PbCr(1-x)S(x)O(4), rich in SO(4)(2-) (x ≥ 0.4), and orthorhombic phases (>30 wt %). Cr and S K-edge micro X-ray absorption near edge structure investigations revealed in an unequivocal manner the formation of up to about 60% of Cr(III)-species in the outer layer of the most altered samples; conversely, independent of the paint models' chemical composition, no change in the S-oxidation state was observed. Analyses employing UV-visible diffuse reflectance and Fourier transform infrared spectroscopy were performed on unaged and aged model samples in order to obtain additional information on the physicochemical changes induced by the aging treatment.

  9. Spectral sensitivity of the concave mirror eyes of scallops: potential influences of habitat, self-screening and longitudinal chromatic aberration.

    Science.gov (United States)

    Speiser, Daniel I; Loew, Ellis R; Johnsen, Sönke

    2011-02-01

    Scallop eyes contain two retinas, one proximal and one distal. Molecular evidence suggests that each retina expresses a different visual pigment. To test whether these retinas have different spectral sensitivities, we used microspectrophotometry to measure the absorption spectra of photoreceptors from the eyes of two different scallop species. Photoreceptors from the proximal and distal retinas of the sea scallop Placopecten magellanicus had absorption peak wavelengths (λ(max)) of 488 ± 1 nm (mean ± s.e.m.; N=20) and 513 ± 3 nm (N=26), respectively. Photoreceptors from the corresponding retinas of the bay scallop Argopecten irradians had λ(max) values of 506 ± 1 nm (N=21) and 535 ± 3 nm (N=14). Assuming that the proximal and distal receptors had equal absorption coefficients (k(D)=0.0067 microm(-1)), we found that self-screening within the scallop eye caused the proximal and distal receptors in P. magellanicus to have peak absorption at 490 and 520 nm, respectively, and the corresponding receptors in A. irradians to have peak absorption at 504 and 549 nm. We conclude that environment may influence the λ(max) of scallop visual pigments: P. magellanicus, generally found in blue oceanic water, has visual pigments that are maximally sensitive to shorter wavelengths than those found in A. irradians, which lives in greener inshore water. Scallop distal retinas may be sensitive to longer wavelengths of light than scallop proximal retinas to correct for either self-screening by the retinas or longitudinal chromatic aberration of the lens.

  10. Isolation and characterization of a chromium-resistant bacterium Serratia sp. Cr-10 from a chromate-contaminated site

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Kundi; Li, Fuli [Chinese Academy of Sciences, Qingdao (China). Qingdao Inst. of Bioenergy and Bioprocess Technology

    2011-05-15

    A novel bacterium, Cr-10, was isolated from a chromium-contaminated site and capable of removing toxic chromium species from solution by reducing hexavalent chromium to an insoluble precipitate. Sequence analysis of 16S rRNA gene of strain Cr-10 showed that it was most closely related to Serratia rubidaea JCM 1240{sup T} (97.68%). Physiological and chemotaxonomic data also supported that strain Cr-10 was identified as Serratia sp., a genus which was never specially reported chromate-resistant before. Serratia sp., Cr-10 was tolerant to a concentration of 1,500 mg Cr(VI) L{sup -1}, which was the highest level reported until now. The optimum pH and temperature for reduction of Cr(VI) by Serratia sp. Cr-10 were found to be 7.0 and 37 C, respectively. The Cr(VI) reduction was significantly influenced by additional carbon sources, and among them fructose and lactose offered maximum reduction, with a rate of 0.28 and 0.25 mg Cr(VI) L{sup -1} h{sup -1}, respectively. The cell-free extracts and filtrate of the culture were able to reduce Cr(VI) while concentration of total chromium remained stable in the process, indicating that the enzyme-catalyzed mechanism was applied in Cr(VI) reduction by the isolate. Additionally, it was found that there was hardly any chromium on the cell surface of the strain, further supporting that reduction, rather than bioadsorption, plays a major role in the Cr(VI) removal. (orig.)

  11. Removal of aqueous chromate [Cr(VI)] through photocatalysis by using TiO2-coated silica granules.

    Science.gov (United States)

    Saeki, Kazutoshi; Kadono, Mayumi; Nabeshima, Akiko

    2010-01-01

    The aim of this study was to determine the optimal conditions for the treatment of chromate [Cr(VI)]- contaminated water by UV photocatalysis using synthesized TiO(2)-coated silica granules (phi 1.7-4.0 mm) containing 12.4% of TiO(2) in a batch method. The effect of the volume of the solution on Cr(VI) removal was investigated in the photocatalysis process by using 10 g of TiO(2)-coated silica granules in water samples with a constant initial Cr(VI) concentration of 5 mg L(-1). In a 10-mL solution, Cr(VI) concentrations were observed to decrease below the detection limit (photocatalysis process to remove Cr(VI) using 10 g of TiO(2)-coated granules did not fluctuate with the solution volume for samples with a constant initial Cr(VI) concentration. The lower the initial pH of the solution, the greater was the amount of Cr(VI) removed from the solution. The addition of chloride ions to the solutions accelerated the removal of Cr(VI) by UV photocatalysis. Ten grams of TiO(2)-coated silica granules were repeatedly used to the 300-min treatment of the Cr(VI) solution (10 mL, 6 mg L(-1)) till seven cycles. After four cycles of UV photocatalysis, Cr(VI) was completely removed from all the solutions. After the fifth cycle, the Cr(VI) removal capacity of the UV photocatalysis process decreased with the repeated use of the catalyst.

  12. On non-invasive 2D and 3D Chromatic White Light image sensors for age determination of latent fingerprints.

    Science.gov (United States)

    Merkel, Ronny; Gruhn, Stefan; Dittmann, Jana; Vielhauer, Claus; Bräutigam, Anja

    2012-10-10

    The feasibility of 2D-intensity and 3D-topography images from a non-invasive Chromatic White Light (CWL) sensor for the age determination of latent fingerprints is investigated. The proposed method might provide the means to solve the so far unresolved issue of determining a fingerprints age in forensics. Conducting numerous experiments for an indoor crime scene using selected surfaces, different influences on the aging of fingerprints are investigated and the resulting aging variability is determined in terms of inter-person, intra-person, inter-finger and intra-finger variation. Main influence factors are shown to be the sweat composition, temperature, humidity, wind, UV-radiation, surface type, contamination of the finger with water-containing substances, resolution and measured area size, whereas contact time, contact pressure and smearing of the print seem to be of minor importance. Such influences lead to a certain experimental variability in inter-person and intra-person variation, which is higher than the inter-finger and intra-finger variation. Comparing the aging behavior of 17 different features using 1490 time series with a total of 41,520 fingerprint images, the great potential of the CWL technique in combination with the binary pixel feature from prior work is shown. Performing three different experiments for the classification of fingerprints into the two time classes [0, 5 h] and [5, 24 h], a maximum classification performance of 79.29% (kappa=0.46) is achieved for a general case, which is further improved for special cases. The statistical significance of the two best-performing features (both binary pixel versions based on 2D-intensity images) is manually shown and a feature fusion is performed, highlighting the strong dependency of the features on each other. It is concluded that such method might be combined with additional capturing devices, such as microscopes or spectroscopes, to a very promising age estimation scheme.

  13. Characterisation of the rare cadmium chromate pigment in a 19th century tube colour by Raman, FTIR, X-ray and EPR

    Science.gov (United States)

    Christiansen, Marie Bitsch; Sørensen, Mikkel Agerbæk; Sanyova, Jana; Bendix, Jesper; Simonsen, Kim Pilkjær

    2017-03-01

    In an investigation of the artists' materials used by P. S. Krøyer the contents of the tube colours found in Krøyer's painting cabinet were examined. In most cases, the results of the pigment analyses were as expected based on our knowledge of artists' colours used in the late 1800s and early 1900s. However, in one of the tube colours labelled "Jaune de Cadmium Citron" (cadmium lemon yellow) an extremely rare cadmium chromate pigment was found. The pigment was analysed and characterised by Raman microscopy (MRS), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS), attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), powder X-ray diffraction (PXRD), single-crystal X-ray crystallography, and electron paramagnetic resonance (EPR) spectroscopy. Cadmium chromate was synthesised by precipitation from an aqueous solution of cadmium nitrate and potassium chromate, and the resulting yellow crystals proved identical to the pigment found in the tube colour "Jaune de Cadmium Citron". The structure determined by single-crystal X-ray diffraction identified the pigment as 2CdCrO4·KOH·H2O or more accurately as KCd2(CrO4)2(H3O2) illustrating the μ-H3O2- species. The yellow colour of the paint sample taken from the tube had a greenish hue, which became even more prominent upon storage and drying. EPR analysis of the sample showed the presence of paramagnetic degradation products containing Cr(III) and Cr(V).

  14. Assessment of Fiber Chromatic Dispersion Based on Elimination of Second-Order Harmonics in Optical OFDM Single Sideband Modulation Using Mach Zehnder Modulator

    Science.gov (United States)

    Patel, Dhananjay; Singh, Vinay Kumar; Dalal, U. D.

    2016-07-01

    This work addresses the analytical and numerical investigations of the transmission performance of an optical Single Sideband (SSB) modulation technique generated by a Mach Zehnder Modulator (MZM) with a 90° and 120° hybrid coupler. It takes into account the problem of chromatic dispersion in single mode fibers in Passive Optical Networks (PON), which severely degrades the performance of the system. Considering the transmission length of the fiber, the SSB modulation generated by maintaining a phase shift of π/2 between the two electrodes of the MZM provides better receiver sensitivity. However, the power of higher-order harmonics generated due to the nonlinearity of the MZM is directly proportional to the modulation index, making the SSB look like a quasi-double sideband (DSB) and causing power fading due to chromatic dispersion. To eliminate one of the second-order harmonics, the SSB signal based on an MZM with a 120° hybrid coupler is simulated. An analytical model of conventional SSB using 90° and 120° hybrid couplers is established. The latter suppresses unwanted (upper/lower) first-order and second-order (lower/upper) sidebands. For the analysis, a varying quadrature amplitude modulation (QAM) Orthogonal Frequency Division Multiplexing (OFDM) signal with a data rate of 5 Gb/s is upconverted using both of the SSB techniques and is transmitted over a distance of 75 km in Single Mode Fiber (SMF). The simulation results show that the SSB with 120° hybrid coupler proves to be more immune to chromatic dispersion as compared to the conventional SSB technique. This is in tandem with the theoretical analysis presented in the article.

  15. Mechanochemical and Conventional Synthesis of Zn(II)/Cd(II) Luminescent Coordination Polymers: Dual Sensing Probe for Selective Detection of Chromate Anions and TNP in Aqueous Phase.

    Science.gov (United States)

    Parmar, Bhavesh; Rachuri, Yadagiri; Bisht, Kamal Kumar; Laiya, Ridhdhi; Suresh, Eringathodi

    2017-03-06

    Isostructural Zn(II)/Cd(II) mixed ligand coordination polymers (CPs) {[M(IPA)(L)]}n (CP1 and CP2) built from isophthalic acid (H2IPA) and 3-pyridylcarboxaldehyde nicotinoylhydrazone (L) were prepared using versatile synthetic routes: viz., diffusion of precursor solutions, conventional reflux methods, and green mechanochemical (grinding) reactions. Both robust CPs synthesized by different routes were characterized by various analytical methods, and their thermal and chemical stability as well as the phase purity was established. Crystallographic studies revealed that CP1 and CP2 are isostructural frameworks and feature a double-lined two-dimensional network composed of Zn(2+)/Cd(2+) nodes connected through IPA and pillared by the Schiff base ligand L with a double-walled edge. The photoluminescent (PL) properties of CP1 and CP2 have been exploited as dual detection fluorosensors for hexavalent chromate anions (CrO4(2-)/Cr2O7(2-)) and 2,4,6-trinitrophenol (TNP) because it was observed that the emission intensity of aqueous suspensions of CPs selectively quenches by chromate anions or TNP among large pools of different anions or nitro compounds, respectively. Competitive experiments in the presence of interfering anions/other nitro compounds also revealed no major effect in the quenching efficiency, suggesting the selective detection of hexavalent chromate anions as well as TNP by the LCPs. The limits of detection by CP1 for CrO4(2-)/Cr2O7(2-) and TNP are 4 ppm/4 ppm and 28 ppb, respectively, whereas the limits of detection by CP2 for the same analytes are 1 ppm/1 ppm and 14 ppb, respectively. A probable mechanism for the quenching phenomena is also discussed.

  16. 钛离子对低铬钝化膜的改性%Low-chromate passive film modified with Ti(Ⅳ) ions

    Institute of Scientific and Technical Information of China (English)

    卢燕平; 屈祖玉

    2001-01-01

    The corrosion resistance, composition and struc ture of Ti(Ⅳ) compound m odified passive films formed in low concentration of chromate solutio n were studied by means of polarization resistance measuring, neutral salt spray test and SEM, XRD, XPS, and the effect of Ti(Ⅳ) ion on the protective mechanism of l o w-chromate passive film was also discussed. The experimental results show tha t the Ti(Ⅳ) ions in the passive film can effectively improve the white rust-inhibit iv e capacity of low chromate passive film, and it is caused by adulteration effec t of Ti(Ⅳ)ions and hydrolysis redeposition effect of Ti(Ⅳ)compound in the pa ssive film.%通过采用极化阻力测量、 中性盐雾试验和SEM, XRD, XPS等手段研究了含Ti(Ⅳ)低铬钝 化膜的耐蚀性、 组成与结构, 探讨了钛离子对钝化膜防护机理的影响。 结果表明, 膜内 T i(Ⅳ)离子可以有效地提高镀锌低铬钝化膜的抗白锈能力, 这是由于膜内Ti(Ⅳ)离子的掺杂 效应和Ti(Ⅳ)化合物水解-再沉积作用所致。

  17. PMD and chromatic dispersion compensation in a 1.76-terabit/s (44 x 43 Gbit/s) optical transmission experiment over 600-km SMF

    Science.gov (United States)

    Rasmussen, Jens C.

    2004-10-01

    A simple, adaptive PMD compensator is demonstrated in a 1.76Terabit/s (44 x 43 Gbit/s) transmission experi- ment over 600km SMF with a mean PMD of 8 ps. The PMDC is composed of a LiNbO3 polarization-controller followed by a component with an adjustable differential group delay (DGD) in the range of 0-20 ps. Feedback control is provided by means of continuously monitoring and maximizing the degree of polarization (DOP). This PMDC is shown to automatically compensate well for 1st-order (0-28 ps) and one part - the depolarization - of 2nd-order (0-130 ps2) PMD. Polarization dependent chromatic dispersion (PCD), being the other part of 2nd-order PMD, is negligible as long transmission systems without a PMDC are considered. But in fact PCD plays a role when an optical PMDC is introduced. Because of the anyway tight tolerance of 40 Gbit/s optical signals to chromatic dispersion, the variable dispersion compensator VIPA (virtually imaged phased array) with a tuning range of +/-800 ps/nm is introduced besides the PMDC. Therefore, with VIPA not only residual chro- matic dispersion put also PCD is e«ectively compensated for. Using adaptive optical technologies compensating for PMD and chromatic dispersion, error-free transmission (BER< 10í15 with FEC, Q-margin=3 dB) of 44 x 43 Gbit/s (1.76 Tbit/s) over 600km of high PMD (8 ps) SMF is demonstrated.

  18. Longitudinal chromatic aberration of the human eye in the visible and near infrared from wavefront sensing, double-pass and psychophysics.

    Science.gov (United States)

    Vinas, Maria; Dorronsoro, Carlos; Cortes, Daniel; Pascual, Daniel; Marcos, Susana

    2015-03-01

    Longitudinal Chromatic Aberration (LCA) influences the optical quality of the eye. However, the reported LCA varies across studies, likely associated to differences in the measurement techniques. We present LCA measured in subjects using wavefront sensing, double-pass retinal images, and psychophysical methods with a custom-developed polychromatic Adaptive Optics system in a wide spectral range (450-950 nm), with control of subjects' natural aberrations. LCA measured psychophysically was significantly higher than that from reflectometric techniques (1.51 D vs 1.00 D in the 488-700 nm range). Ours results indicate that the presence of natural aberrations is not the cause for the discrepancies across techniques.

  19. Chromate enhanced visible light driven TiO{sub 2} photocatalytic mechanism on Acid Orange 7 photodegradation

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yeoung-Sheng; Shen, Jyun-Hong [Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology (YunTech), Douliou, Yunlin, Taiwan (China); Horng, Jao-Jia, E-mail: horngjj@gmail.com [Department of Safety, Health and Environmental Engineering, National Yunlin University of Science and Technology (YunTech), Douliou, Yunlin, Taiwan (China)

    2014-06-01

    Highlights: • Photocatalysis of Cr(VI) and TiO{sub 2} were studied by ESR analysis on DMPO-OH signals. • Mechanism of Cr(VI)-enhanced by visible light was different from that by UV. • O{sub 2} adsorbed on TiO{sub 2} surfaces could react with Cr(VI) to lower photoenergy needed. • Even by UV, no TiO{sub 2} photocatalysis was observed without O{sub 2} solution. • Visible light and Cr(VI) redox reaction could activate TiO{sub 2} and would yield ·OH. - Abstract: When hexavalent chromium (Cr(VI)) is added to a TiO{sub 2} photocatalytic reaction, the decolorization and mineralization efficiencies of azo dyes Acid Orange 7 (AO7) are enhanced even though the mechanism is unclear. This study used 5,5-dimethyl-L-pyrroline-N-oxide (DMPO) as the scavenger and the analysis of Electron Spin Resonance (ESR) to investigate this enhancement effect by observing the hydroxyl radical (·OH) generation of the Cr(VI)/TiO{sub 2} system under UV and visible light (Vis) irradiation. With Cr(VI), the decolorization efficiencies were approximately 95% and 62% under UV and Vis, and those efficiencies were 25% less in the absence of Cr(VI). The phenomena of the DMPO-OH signals during the ESR analysis under Vis 405 and 550 nm irradiation were obviously the enhancement effects of Cr(VI) in aerobic conditions. In anoxic conditions, the catalytic effects of Cr(VI) could not be achieved due to the lack of a redox reaction between Cr(VI) and the adsorbed oxygen at the oxygen vacancy sites on the TiO{sub 2} surfaces{sub .} The results suggest that by introducing the agents of redox reactions such as chromate ions, we could lower the photoenergy of TiO{sub 2} needed and allow Vis irradiation to activate photocatalysis.

  20. Performance analysis of digital cameras versus chromatic white light (CWL) sensors for the localization of latent fingerprints in crime scenes

    Science.gov (United States)

    Jankow, Mathias; Hildebrandt, Mario; Sturm, Jennifer; Kiltz, Stefan; Vielhauer, Claus

    2012-06-01

    In future applications of contactless acquisition techniques for latent fingerprints the automatic localization of potential fingerprint traces in crime scenes is required. Our goal is to study the application of a camera-based approach1 comparing with the performance of chromatic white light (CWL) techniques2 for the latent fingerprint localization in coarse and the resulting acquisition using detailed scans. Furthermore, we briefly evaluate the suitability of the camera-based acquisition for the detection of malicious fingerprint traces using an extended camera setup in comparison to Kiltz et al.3 Our experimental setup includes a Canon EOS 550D4 digital single-lens reflex (DSLR) camera and a FRT MicroProf2005 surface measurement device with CWL6002 sensor. We apply at least two fingerprints to each surface in our test set with 8 different either smooth, textured and structured surfaces to evaluate the detection performance of the two localization techniques using different pre-processing and feature extraction techniques. Printed fingerprint patterns as reproducible but potentially malicious traces3 are additionally acquired and analyzed on foil and compact discs. Our results indicate positive tendency towards a fast localization using the camera-based technique. All fingerprints that are located using the CWL sensor are found using the camera. However,the disadvantage of the camera-based technique is that the size of the region of interest for the detailed scan for each potential latent fingerprint is usually slightly larger compared to the CWL-based localization. Furthermore, this technique does not acquire 3D data and the resulting images are distorted due to the necessary angle between the camera and the surface. When applying the camera-based approach, it is required to optimize the feature extraction and classification. Furthermore, the required acquisition time for each potential fingerprint needs to be estimated to determine the time-savings of the

  1. Tuning the chromaticity of the emission color of the copolymers containing Eu(III), Tb(III), Be(II) ions based on colorimetric principle

    Science.gov (United States)

    Zhang, Aiqin; Yang, Yamin; Zhai, Guangmei; Jia, Husheng; Xu, Bingshe

    2016-02-01

    In this work, a method of tuning the chromaticity of the emission color of the copolymers containing Eu(III), Tb(III), Be(II) ions based on colorimetric principle was proposed. The technological route from coordination to copolymerization was employed to obtain the white light macromolecular phosphor. The three primary color monomers have been synthesized and their Commission Internationale de L'Eclairage (CIE) coordinates are respectively (0.540, 0.314), (0.231, 0.463), and (0.161, 0.054). The molar feed ratios of the three primary color monomers were calculated from the CIE coordinates based on colorimetric principle. Serial copolymers have been synthesized by free radical copolymerization of the three primary color monomers and methyl methacrylate. The quantum efficiency of the copolymers was higher than that of the complex monomers. The complexes were directly boned to the polymer chain, in which the energy transfer was reduced significantly compared to the doped-polymers. The experimental values of copolymers' CIE coordinates were located in the white light region in good agreement with theoretical values. The results indicate that the chromaticity of the emission color of the copolymers containing Eu(III), Tb(III), Be(II) ions could be tuned by theoretical calculation based on colorimetric principle.

  2. Hyperemic responses of the optic nerve head blood flow to chromatic equiluminant flicker are reduced by ocular hypertension and early glaucoma

    Science.gov (United States)

    Falsini, Benedetto; Riva, Charles E.; Salgarello, Tommaso; Logean, Eric; Colotto, Alberto; Giudiceandrea, Andrea

    2014-06-01

    We evaluated in ocular hypertension (OHT) and early glaucoma (EOAG) patients the optic nerve head (ONH) blood flow response (RF) to chromatic equiluminant flicker. This stimulus generates neural activity dominated by the parvo-cellular system. Eleven EOAG, 20 OHT patients, and 8 age-matched control subjects were examined. The blood flow (F) at the neuroretinal rim was continuously monitored by laser Doppler flowmetry before, during, and after a 60-s exposure to a 4 Hz, red-green equiluminant flicker stimulus (30 deg field). RF was expressed as percentage F-change during the last 20 s of flicker relative to baseline F. Responses were collected at a number of temporal sites. The highest RF value was used for subsequent analysis. As compared to controls, both OHT and EOAG patients showed a decrease (p<0.01) in mean RF. We conclude that RF elicited by chromatic equiluminant flicker is abnormally reduced in OHT and EOAG patients indicating an impairment of the parvo-cellular-mediated vasoactivity. This decrease of vascular response may occur independently of neural activity loss early in the disease process.

  3. Modeling corrosion inhibition efficacy of small organic molecules as non-toxic chromate alternatives using comparative molecular surface analysis (CoMSA).

    Science.gov (United States)

    Fernandez, Michael; Breedon, Michael; Cole, Ivan S; Barnard, Amanda S

    2016-10-01

    Traditionally many structural alloys are protected by primer coatings loaded with corrosion inhibiting additives. Strontium Chromate (or other chromates) have been shown to be extremely effectively inhibitors, and find extensive use in protective primer formulations. Unfortunately, hexavalent chromium which imbues these coatings with their corrosion inhibiting properties is also highly toxic, and their use is being increasingly restricted by legislation. In this work we explore a novel tridimensional Quantitative-Structure Property Relationship (3D-QSPR) approach, comparative molecular surface analysis (CoMSA), which was developed to recognize "high-performing" corrosion inhibitor candidates from the distributions of electronegativity, polarizability and van der Waals volume on the molecular surfaces of 28 small organic molecules. Multivariate statistical analysis identified five prototypes molecules, which are capable of explaining 71% of the variance within the inhibitor data set; whilst a further five molecules were also identified as archetypes, describing 75% of data variance. All active corrosion inhibitors, at a 80% threshold, were successfully recognized by the CoMSA model with adequate specificity and precision higher than 70% and 60%, respectively. The model was also capable of identifying structural patterns, that revealed reasonable starting points for where structural changes may augment corrosion inhibition efficacy. The presented methodology can be applied to other functional molecules and extended to cover structure-activity studies in a diverse range of areas such as drug design and novel material discovery.

  4. Corrosion and protection of heterogeneous cast Al-Si (356) and Al-Si-Cu-Fe (380) alloys by chromate adn cerium inhibitors

    Science.gov (United States)

    Jain, Syadwad

    In this study, the localized corrosion and conversion coating on cast alloys 356 (Al-7.0Si-0.3Mg) and 380 (Al-8.5Si-3.5Cu-1.6Fe) were characterized. The intermetallic phases presence in the permanent mold cast alloy 356 are primary-Si, Al5FeSi, Al8Si6Mg3Fe and Mg2Si. The die cast alloy 380 is rich in Cu and Fe elements. These alloying elements result in formation of the intermetallic phases Al 5FeSi, Al2Cu and Al(FeCuCr) along with primary-Si. The Cu- and Fe-rich IMPS are cathodic with respect to the matrix phase and strongly govern the corrosion behavior of the two cast alloys in an aggressive environment due to formation of local electrochemical cell in their vicinity. Results have shown that corrosion behavior of permanent mould cast alloy 356 is significantly better than the die cast aluminum alloy 380, primarily due to high content of Cu- and Fe-rich phases such as Al2Cu and Al 5FeSi in the latter. The IMPS also alter the protection mechanism of the cast alloys in the presence of inhibitors in an environment. The presence of chromate in the solution results in reduced cathodic activity on all the phases. Chromate provides some anodic inhibition by increasing pitting potentials and altering corrosion potentials for the phases. Results have shown that performance of CCC was much better on 356 than on 380, primarily due to inhomogeneous and incomplete coating deposition on Cu- and Fe- phases present in alloy 380. XPS and Raman were used to characterize coating deposition on intermetallics. Results show evidence of cyanide complex formation on the intermetallic phases. The presence of this complex is speculated to locally suppress CCC formation. Formation and breakdown of cerium conversion coatings on 356 and 380 was also analyzed. Results showed that deposition of cerium hydroxide started with heavy precipitation on intermetallic particles with the coatings growing outwards onto the matrix. Electrochemical analysis of synthesized intermetallics compounds in the

  5. Color evaluation of seventeen European unifloral honey types by means of spectrophotometrically determined CIE L*Cab*h(ab)° chromaticity coordinates.

    Science.gov (United States)

    Tuberoso, Carlo Ignazio Giovanni; Jerković, Igor; Sarais, Giorgia; Congiu, Francesca; Marijanović, Zvonimir; Kuś, Piotr Marek

    2014-02-15

    CIE (Commission Internationale de l'Eclairage) L(*)Cab(*)h(ab)° color coordinates for 305 samples of 17 unifloral honeys types (asphodel, buckwheat, black locust, sweet chestnut, citrus, eucalyptus, Garland thorn, honeydew, heather, lime, mint, rapeseed, sage, strawberry tree, sulla flower, savory and thistle) from different geographic locations in Europe were spectrophotometrically assessed and statistically evaluated. Preliminary separation of unifloral honeys was obtained by means of L(*)-C(ab)(*) color coordination correlation. Hierarchical Cluster Analysis (HCA) revealed an expected segregation of the honeys types according to their chromatic characteristics. Principal Component Analysis (PCA) allowed to obtain a more defined distinction of the 17 unifloral honey types, particularly when using 3D graphics. CIE L(*)C(ab)(*)hab(*) color coordinates were useful for the identification of several honey types. The proposed method represents a simple and efficient procedure that can be used as a basis for the authentication of unifloral honeys worldwide.

  6. 10.7 Gb/s electronic predistortion transmitter using commercial FPGAs and D/A converters implementing real-time DSP for chromatic dispersion and SPM compensation.

    Science.gov (United States)

    Waegemans, Robert; Herbst, Stefan; Holbein, Ludwig; Watts, Philip; Bayvel, Polina; Fürst, Cornelius; Killey, Robert I

    2009-05-11

    We present an experimental demonstration of simultaneous chromatic dispersion and self-phase modulation compensation at 10.7 Gb/s using real-time electronic digital signal processing. This was achieved using a pre-distorting transmitter based on commercially available field programmable gate arrays and 21.4 GS/s, 6-bit resolution digital-to-analog converters. The digital signal processing employed look-up tables stored in RAM. This resulted in the achievement of a BER of 10(-6) at an OSNR of 16 dB after transmission over a 450 km link of uncompensated standard single mode fiber with + 4 dBm launch power.

  7. 广义图K(n,m)的全色数%The total chromatic number of general graphs K(n,m)

    Institute of Scientific and Technical Information of China (English)

    王淑栋; 陈东灵; 庞善臣

    2001-01-01

    In 1965,M Behzad and Vizing presented the famous total coloring conjecture(TCC):for every simple graph G:XT(G) ≤△ + 2,where △ is the maximun degree of graph G. In this paper, we determine that the total chromatic number of general graphs K(n,m) of complete graph Kn and prove that Lm × Kn(M≥ 3) is type I using it.%1965年,M.Behzad和Vizing分别提出了著名的全着色猜想:即对于简单图G有:XT(G)≤△+2,其中△是图G的最大度.本文确定了完全图Kn的广义图K(n,m)的全色数,并利用它证明了Lm×Kn(m≥3)是第Ⅰ型的.

  8. Total Colors Maximal Cliques Chromatic Numbers of Several Classes of Graphs%若干图类的全色极大团色数

    Institute of Scientific and Technical Information of China (English)

    韩淑芹

    2015-01-01

    On the basis of the graph M(G) which is a Mycielski graph,a class of diagram Sm(G) that similar to the graph M(G) in structure were defined. The total colors maximal cliques chromatic numbers of the graph M(C3 ),a special sub-graph of graph M(G) and Sm(G) were obtained,where C3 represents 3 order circle.%在图 G 的 Mycielski 图 M(G)的基础上,定义了结构类似的一类图 Sm(G),研究了 M(C3),M(G)的一个特殊子图以及 Sm(G)的全色极大团染色,得到了相应的染色数,其中 C3表示3阶圈。

  9. Adjacent-vertex distinguishing total chromatic number on Ws∨Km,n%联图Ws∨Km,n的邻点可区别全色数

    Institute of Scientific and Technical Information of China (English)

    程辉; 姚兵; 张忠辅

    2007-01-01

    A conjecture about the concept of the adjacent-vertex distinguishing total colorings (AVDTC) on graphs is stated as this: For any simple graph G, then χat(G)≤Δ(G)+3. The AVDTC-chromatic number of a join graph Ws∨Km,n is determined in the form Δ(Ws∨Km,n)+1≤χat(Ws∨Km,n)≤Δ(Ws∨Km,n)+2.%图的邻点可区别全染色(AVDTC)数为χat(G),有猜想:χat(G)≤Δ(G)+3. 联图Ws∨Km,n的邻点可区别全色数被确定为χat(Ws∨Km,n)=Δ(Ws∨Km,n)+1或Δ(Ws∨Km,n)+2.

  10. The catalytic effect of sodium and lithium ions on coupled sorption-reduction of chromate at the biotite edge-fluid interface

    Science.gov (United States)

    Ilton, Eugene S.; Veblen, David R.; Moses, Carl O.; Raeburn, Stuart P.

    1997-09-01

    Large single crystals of biotite and near-endmember phlogopite were reacted with aqueous solutions bearing 20 μM Cr(VI) and different concentrations of NaCl, LiCl, RbCl, CsCl, NaClO 4, and Na 2SO 4. Solutions were maintained at 25 ± 0.5°C, 1 atm, and pH = 4.00 ± 0.02. Samples were extracted from the reaction chamber at 1, 3, 5, 10, and 20 h. The edges and basal planes of the reacted micas were analyzed by X-ray photoelectron spectroscopy (XPS) for major elements and Cr. XPS analyses of biotite show trivalent chromium on edge surfaces but no detectable chromium on the basal plane. XPS analyses of near-endmember phlogopites that were reacted in the same experiments as biotite showed no detectable Cr on either the basal plane or edge surfaces. Increasing Na and Li salt concentrations increased the rate of coupled sorption-reduction of chromate at the biotite edge-fluid interface, where the order of effectiveness was NaCl ˜ NaClO 4 > Na 2SO 4 > LiCl. In contrast, no Cr was detected on mica edges after reaction in RbCl and CsCl solutions. Comparison of equimolar NaCl and LiCl experiments indicate that the active agent is Na and Li, not ionic strength or the anion. Sulfate tends to block the reaction more so than chloride. We conclude that it is the substitution of hydrated cations for interlayer K in biotite that enhances the heterogeneous reduction of chromate at the biotite edge-fluid interface.

  11. The Total Chromatic Number of Schrijver Graph SG (2 k+2,k)%Schrijver 图 SG(2 k+2,k)的全色数

    Institute of Scientific and Technical Information of China (English)

    李志江; 卢建立

    2014-01-01

    A k-total coloring of a graph Ga proper coloring with k colors such that no adjacent vertices , no adjacent edges ,and no edge and its incident vertices are assigned the same color .T he total chromatic number χ″(G) of Gis the least number k for which Ghas ak-total coloring .For a simple graph Gwith max imum degree .Behzad and Vizing independently made the follwing conjeture :Δ+1≤ χ″(G)≤ Δ+2 .In this paper ,we determine the total chromatic number of Schrijver graph SG(2k+2 ,k)χ″(SG(2k+2 ,k))= Δ+1=k+3 ,where k≥2 .%图 G的一个k 全染色是用k种颜色对图G的顶点和边进行染色,使得任意相邻的边、相邻的顶点和相关联的顶点和边都染不同的颜色.图 G的全色数是图G的k 全染色中最小的k值,记为χ″(G).Behzad和Vizing分别独立地提出了著名的全染色猜想 TCC :Δ+1≤χ″(G)≤Δ+2,Δ表示图 G的最大度.研究了Schrijver图 SG (2k+2,k)的全色数问题,得到了χ″(SG (2k+2,k))=Δ+1= k+3,其中 k≥2.

  12. High-performance alternating current field-induced chromatic-stable white polymer electroluminescent devices employing a down-conversion layer

    Energy Technology Data Exchange (ETDEWEB)

    Xia, Yingdong; Chen, Yonghua; Smith, Gregory M. [Center for Nanotechnology and Molecular Materials, Department of Physics, Wake Forest University, Winston-Salem, NC 27105 (United States); Sun, Hengda; Yang, Dezhi [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Nie, Wanyi; Li, Yuan; Huang, Wenxiao [Center for Nanotechnology and Molecular Materials, Department of Physics, Wake Forest University, Winston-Salem, NC 27105 (United States); Ma, Dongge [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Carroll, David L., E-mail: carroldl@wfu.edu [Center for Nanotechnology and Molecular Materials, Department of Physics, Wake Forest University, Winston-Salem, NC 27105 (United States)

    2015-05-15

    In this work, a high-performance alternating current (AC) filed-induced chromatic-stable white polymer electroluminescence (WFIPEL) device was fabricated by combining a fluorophor Poly(9,9-dioctylfluorene) (PFO)-based blue device with a yellow down-conversion layer (YAG:Ce). A maximum luminance of this down-conversion FIPEL device achieves 3230 cd m{sup −2}, which is 1.41 times higher than the device without the down-conversion layer. A maximum current efficiency and power efficiency of the down-conversion WFIPEL device reach 19.7 cd A{sup −1} at 3050 cd m{sup −2} and 5.37 lm W{sup −1} at 2310 cd m{sup −2} respectively. To the best of our knowledge, the power efficiency is one of the highest reports for the WFIPEL up to now. Moreover, Commison Internationale de L’Eclairage (CIE) coordinates of (0.28, 0.30) is obtained by adjusting the thickness of the down-conversion layer to 30 μm and it is kept stable over the entire AC-driven voltage range. We believe that this AC-driven, down-conversion, WFIPEL device may offer an easy way towards future flat and flexible lighting sources. - Highlights: • A high-performance AC filed-induced chromatic-stable white polymer electroluminescence (WFIPEL) device was fabricated. • A maximum luminance, current efficiency, and power efficiency achieves 3230 cd m{sup −2}, 19.7 cd A{sup −1}, and 5.37 lm W{sup −1}, respectively. • The power efficiency is one of the highest reports for the WFIPEL up to now. • The EL spectrum kept very stable over the entire AC-driven voltage range.

  13. Influence of metal ion on the chromatic light of reactive dyes%金属离子对活性染料色光的影响

    Institute of Scientific and Technical Information of China (English)

    展义臻; 赵雪; 王炜

    2015-01-01

    Effects of Ca2+、Cu2+、Fe2+ on the chromatic light 13 different reactive dyes were investigated. The results show that Cu2+ offers great influence on the dyeing chromatic light of black reactive dyes, bright red, dark red, Navy, brilliant yellow and Yellow EX-D4R, but it shows little influence on that of Brilliant Blue R, Turquoise Blue G, and Yellow 3RS. Fe3+ has a litter influence on reactive dyes except for Bright Red GG, Brilliant Yellow 3G and Turquoise Blue G. Ca2+ has a little influence on reactive dyes.%探讨了Ca2+、Cu2+、Fe3+3种金属离子对常用的13只活性染料色光的影响,结果表明:Cu2+对黑色活性染料、黄色调的大红和蓝色调的深红、藏青、嫩黄和活性EX-D4R黄等影响较大,而对活性R艳蓝、活性G翠蓝、活性3RS黄等影响相对较小。除了艳色调的活性GG大红、活性3G嫩黄和活性G翠蓝,Fe3+对活性染料影响相对较小。Ca2+对活性染料总体影响较小。

  14. Variation in band gap of lanthanum chromate by transition metals doping LaCr{sub 0.9}A{sub 0.1}O{sub 3} (A:Fe/Co/Ni)

    Energy Technology Data Exchange (ETDEWEB)

    Naseem, Swaleha, E-mail: wasiamu@gmail.com; Khan, Wasi, E-mail: wasiamu@gmail.com; Saad, A. A., E-mail: wasiamu@gmail.com; Shoeb, M., E-mail: wasiamu@gmail.com; Ahmed, Hilal, E-mail: wasiamu@gmail.com; Naqvi, A. H. [Centre of Excellence in Materials Science (Nanomaterials), Department of Applied Physics, Z.H. College of Engg. and Technology, Aligarh Muslim University, Aligarh-202002 (India); Husain, Shahid [Department of Physics, Aligarh Muslim University, Aligarh-202002 (India)

    2014-04-24

    Transition metal (Fe, Co, Ni) doped lanthanum chromate (LaCrO{sub 3}) nanoparticles (NPs) were prepared by gel combustion method and calcinated at 800°C. Microstructural studies were carried by XRD and SEM/EDS techniques. The results of structural characterization show the formation of all samples in single phase without any impurity. Optical properties were studied by UV- visible and photoluminescence techniques. The energy band gap was calculated and the variation was observed with the doping of transition metal ions. Photoluminescence spectra show the emission peak maxima for the pure LaCrO{sub 3} at about 315 nm. Influence of Fe, Co, Ni doping was studied and compared with pure lanthanum chromate nanoparticles.

  15. 中国散裂中子源快循环同步加速器中色品校正及六极磁铁非线性效应%Chromatic correction for CSNS/RCS and nonlinear effects of chromaticity sextupoles

    Institute of Scientific and Technical Information of China (English)

    许守彦; 王生

    2013-01-01

    The rapid cycling synchrotron (RCS) of the China Spallation Neutron Source (CSNS) accumulates an 80 MeV injected beam,and accelerates 1.56 × 1013 particles to the design energy of 1.6 GeV,and extracts the high energy beam to the target.In order to keep low beam losses in the ring,it is necessary to control the chromaticity and to minimize the dependence of the optical properties on beam momentum spread.Three chromatic correction schemes are proposed and compared for CSNS/RCS in this paper.The combined effects of sextupole field and space charge are investigated by using the code SIMPSONS.The tune spread produced by chromaticity can be apparently reduced by using chromaticitysextupoles.However,the chromaticitysextupoles are non linear elements,and can introduce an amplitude dependent tuneshift.The combined effects ofsextupole field and space charge can induce some heam loss.%中国散裂中子源(CSNS)快循环同步加速器(RCS)把能量为80 MeV的束流储存并加速到1.6 GeV然后引出到靶站.为了减少RCS中的束流损失,有必要对RCS做色品校正,并减小动量偏移对束流光学的影响.尝试了多种色品校正方案并对不同色品校正方案做了比较.用三维跟踪程序SIMPSONS研究了色品校正六极铁与空间电荷效应对束流的影响.色品校正六极铁可以有效减小色品引起的频散,但是由于六极铁为非线性元件,导致不同振幅的粒子间有一定频散.模拟发现同时存在空间电荷效应和色品校正六极铁时,会有少量的束流损失.

  16. Examining the Effects of Chromatic Aberration, Object Distance, and Eye Shape on Image-Formation in the Mirror-Based Eyes of the Bay Scallop Argopecten irradians.

    Science.gov (United States)

    Speiser, Daniel I; Gagnon, Yakir Luc; Chhetri, Raghav K; Oldenburg, Amy L; Johnsen, Sönke

    2016-11-01

    The eyes of scallops form images using a concave spherical mirror and contain two separate retinas, one layered on top of the other. Behavioral and electrophysiological studies indicate that the images formed by these eyes have angular resolutions of about 2°. Based on previous ray-tracing models, it has been thought that the more distal of the two retinas lies near the focal point of the mirror and that the proximal retina, positioned closer to the mirror at the back of the eye, receives light that is out-of-focus. Here, we propose three mechanisms through which both retinas may receive focused light: (1) chromatic aberration produced by the lens may cause the focal points for longer and shorter wavelengths to fall near the distal and proximal retinas, respectively; (2) focused light from near and far objects may fall on the distal and proximal retinas, respectively; and (3) the eyes of scallops may be dynamic structures that change shape to determine which retina receives focused light. To test our hypotheses, we used optical coherence tomography (OCT), a method of near-infrared optical depth-ranging, to acquire virtual cross-sections of live, intact eyes from the bay scallop Argopecten irradians Next, we used a custom-built ray-tracing model to estimate the qualities of the images that fall on an eye's distal and proximal retinas as functions of the wavelengths of light entering the eye (400-700 nm), object distances (0.01-1 m), and the overall shape of the eye. When we assume 550 nm wavelength light and object distances greater than 0.01 m, our model predicts that the angular resolutions of the distal and proximal retinas are 2° and 7°, respectively. Our model also predicts that neither chromatic aberration nor differences in object distance lead to focused light falling on the distal and proximal retinas simultaneously. However, if scallops can manipulate the shapes of their eyes, perhaps through muscle contractions, we speculate that they may be able

  17. Charge deformation and orbital hybridization: intrinsic mechanisms on tunable chromaticity of Y3Al5O12:Ce3+ luminescence by doping Gd3+ for warm white LEDs.

    Science.gov (United States)

    Chen, Lei; Chen, Xiuling; Liu, Fayong; Chen, Haohong; Wang, Hui; Zhao, Erlong; Jiang, Yang; Chan, Ting-Shan; Wang, Chia-Hsin; Zhang, Wenhua; Wang, Yu; Chen, Shifu

    2015-07-15

    The deficiency of Y3Al5O12:Ce (YAG:Ce) luminescence in red component can be compensated by doping Gd(3+), thus lead to it being widely used for packaging warm white light-emitting diode devices. This article presents a systematic study on the photoluminescence properties, crystal structures and electronic band structures of (Y1-xGdx)3Al5O12: Ce(3+) using powerful experimental techniques of thermally stimulated luminescence, X-ray diffraction, X-ray absorption near edge structure (XANES), extended X-ray absorption fine structure (EXAFS) and ultraviolet photoelectron spectra (UPS) of the valence band, assisted with theoretical calculations on the band structure, density of states (DOS), and charge deformation density (CDD). A new interpretation from the viewpoint of compression deformation of electron cloud in a rigid structure by combining orbital hybridization with solid-state energy band theory together is put forward to illustrate the intrinsic mechanisms that cause the emission spectral shift, thermal quenching, and luminescence intensity decrease of YAG: Ce upon substitution of Y(3+) by Gd(3+), which are out of the explanation of the classic configuration coordinate model. The results indicate that in a rigid structure, the charge deformation provides an efficient way to tune chromaticity, but the band gaps and crystal defects must be controlled by comprehensively accounting for luminescence thermal stability and efficiency.

  18. The association between chromaticity, phenolics, carotenoids, and in vitro antioxidant activity of frozen fruit pulp in Brazil: an application of chemometrics.

    Science.gov (United States)

    Zielinski, Acácio Antonio Ferreira; Ávila, Suelen; Ito, Vivian; Nogueira, Alessandro; Wosiacki, Gilvan; Haminiuk, Charles Windson Isidoro

    2014-04-01

    A total of 19 Brazilian frozen pulps from the following fruits: açai (Euterpe oleracea), blackberry (Rubus sp.), cajá (Spondias mombin), cashew (Anacardium occidentale), cocoa (Theobroma cacao), coconut (Cocos nucifera), grape (Vitis sp.), graviola (Annona muricata), guava (Psidium guajava), papaya (Carica papaya), peach (Prunus persica), pineapple (Ananas comosus), pineapple and mint (A. comosus and Mentha spicata), red fruits (Rubus sp. and Fragaria sp.), seriguela (Spondias purpurea), strawberry (Fragaria sp.), tamarind (Tamarindus indica), umbu (Spondias tuberosa), and yellow passion fruit (Passiflora edulis) were analyzed in terms of chromaticity, phenolic compounds, carotenoids, and in vitro antioxidant activity using ferric reducing antioxidant power (FRAP) and 1,1-diphenyl-2-picrylhydrazyl (DPPH) assays. Data were processed using principal component analysis (PCA) and hierarchical cluster analysis (HCA). Antioxidant capacity was measured by DPPH and FRAP assays, which showed significant (P < 0.01) correlation with total phenolic compounds (r = 0.88 and 0.70, respectively), total flavonoids (r = 0.63 and 0.81, respectively), and total monomeric anthocyanins (r = 0.59 and 0.73, respectively). PCA explained 74.82% of total variance of data, and the separation into 3 groups in a scatter plot was verified. Three clusters also suggested by HCA, corroborated with PCA, in which cluster 3 was formed by strawberry, red fruits, blackberry, açaí, and grape pulps. This cluster showed the highest contents of total phenolic compounds, total flavonoids, and antioxidant activity.

  19. Charge deformation and orbital hybridization: intrinsic mechanisms on tunable chromaticity of Y3Al5O12:Ce3+ luminescence by doping Gd3+ for warm white LEDs

    Science.gov (United States)

    Chen, Lei; Chen, Xiuling; Liu, Fayong; Chen, Haohong; Wang, Hui; Zhao, Erlong; Jiang, Yang; Chan, Ting-Shan; Wang, Chia-Hsin; Zhang, Wenhua; Wang, Yu; Chen, Shifu

    2015-07-01

    The deficiency of Y3Al5O12:Ce (YAG:Ce) luminescence in red component can be compensated by doping Gd3+, thus lead to it being widely used for packaging warm white light-emitting diode devices. This article presents a systematic study on the photoluminescence properties, crystal structures and electronic band structures of (Y1-xGdx)3Al5O12: Ce3+ using powerful experimental techniques of thermally stimulated luminescence, X-ray diffraction, X-ray absorption near edge structure (XANES), extended X-ray absorption fine structure (EXAFS) and ultraviolet photoelectron spectra (UPS) of the valence band, assisted with theoretical calculations on the band structure, density of states (DOS), and charge deformation density (CDD). A new interpretation from the viewpoint of compression deformation of electron cloud in a rigid structure by combining orbital hybridization with solid-state energy band theory together is put forward to illustrate the intrinsic mechanisms that cause the emission spectral shift, thermal quenching, and luminescence intensity decrease of YAG: Ce upon substitution of Y3+ by Gd3+, which are out of the explanation of the classic configuration coordinate model. The results indicate that in a rigid structure, the charge deformation provides an efficient way to tune chromaticity, but the band gaps and crystal defects must be controlled by comprehensively accounting for luminescence thermal stability and efficiency.

  20. Chromatic thermometry used in ceramic sintering process%比色测温在陶瓷生产中的应用研究

    Institute of Scientific and Technical Information of China (English)

    陶伟; 吴国俊; 关云天

    2012-01-01

    The method of chromatic thermometry was introduced into the on-line thermometry of ceramic sintering. The thermometry system was designed according to Planck law. The calculation methods of key parameters, such as wavelength, emissivity, rate of conversion, were presented. The relation between wavelength and energy/sensitivity was comprehensively analyzed. The prototype was set up and tested according to the characteristics of ceramic sintering process, and the results indicated the metering error was less than 10 K during 1 300 K~2 000 K.%针对陶瓷制品烧结过程中的在线温度检测,引入了比色测温方法.根据比色测温的原理构建了比色测温系统.提出了系统关键参数比色波长、发射/转化率的确定方法,其中重点分析和推导了波长与能量、灵敏度的关系.根据陶瓷烧结过程特点搭建了样机,并进行了测试,结果表明在1 300 K~2 000 K范围内测温误差小于10 K.

  1. 双色测温在陶瓷烧结中的应用%The Research of Chromatic Thermometry Used in the Ceramic Sintering Process

    Institute of Scientific and Technical Information of China (English)

    吴国俊; 闫广州; 焦国华

    2012-01-01

    针对陶瓷制品烧结过程中的在线温度检测引入了双色测温方法.利用双色测温的原理构建了双色测温系统,同时提出了系统关键参数双色波长、发射/转化率的确定方法.对根据陶瓷烧结过程特点搭建的样机进行了测试,结果表明在1300~ 2000 K范围内测温误差小于10 K.%The method of chromatic thermometry was introduced into the on-line thermometry of the ceramic sintering. The thermometry system was designed according to planck rule. The calculational methods of key parameter such as wavelength, emissivity and rate of conversion was extracted. The experiment indicated the metering error was less than 10 K during 1300-2000 K.

  2. 铝黄铜仿金合金色度研究%Chromaticity of Brass Based Stimulant Gold Alloy with Al Additions

    Institute of Scientific and Technical Information of China (English)

    向雄志; 马松峰; 白晓军

    2011-01-01

    Based on CIELAB chromatic theory, effects of different Al and Zn content on chroma, anti-tarnish and anti-oxidation behavior of brass based stimulant gold alloy with 70% Cu content were investigated quantitatively. The results show that color-difference is enlarged between surface color of alloy and gold as a result of Al addition weakening the yellow color in surface color of the alloy, improving the anti-tarnish behavior and hardness of the alloy. The possible factors influencing anti-tarnish and anti-oxidation behavior of the alloy were approached.%基于CIELAB色度学知识,定量研究了Cu含量在70%时,Al和Zn的成分变化对合金的颜色值、抗变色性以及氧化性的影响.结果发现,Al的添加会导致合金表面颜色黄色的因素减弱,从而使合金表面颜色与黄金色差加大,从而提高了合金的抗变色性以及合金的硬度.另外,探讨了影响抗变色性和抗氧化性的可能因素.

  3. Preparation and characterization of nano structured Ba2SnO4 as a novel photocatalyst material for the chromate reduction

    Science.gov (United States)

    Omeiri, S.; Allalou, N.; Rekhila, G.; Bessekhouad, Y.; Trari, M.

    2013-11-01

    The photo-electrochemical properties of the layered perovskite Ba2SnO4, prepared by nitrate route are reported for the first time. The oxide exhibits a direct optical transition at 2.98 eV, attributed to the charge transfer O2-: 2p → Sn4+: 5s and possesses a chemical stability over the whole pH range. The Mott Schottky plot in acidic medium is characteristic of n type conductivity with a flat band potential E fb of -0.84 V SCE and an electron density N D of 1.14 × 1017 cm-3. The electrochemical impedance spectroscopy reveals the bulk and grain boundaries contributions. Ba2SnO4 is of interest for the environmental protection. At pH 2.5, its conduction band (CB, -0.86 V SCE) is below the HCrO4 - level, yielding a spontaneous reduction to Cr3+ under UV light. The reduction is optimized with respect to the Cr(VI) concentration. The photo reduction follows a pseudo-first-order kinetic and the data fit well the Langmuir-Hinshelwood (L-H) model with an apparent rate constant of 0.18 h-1 for an initial concentration of 50 ppm. The chromate reduction under solar light is studied under optimized conditions. In presence of oxalic acid, 73 % of initial concentration disappears after ~2 h of irradiation.

  4. Ab Initio Computational Study of Chromate Molecular Anion Adsorption on the Surfaces of Pristine and B- or N-Doped Carbon Nanotubes and Graphene

    Science.gov (United States)

    Hizhnyi, Yuriy; Nedilko, Sergii; Borysiuk, Viktor; Shyichuk, Andrii

    2017-01-01

    Density functional theory (DFT) computations of the electronic structures of undoped, B- and N-doped CNT(3,3), CNT(5,5) carbon nanotubes, and graphene with adsorbed chromate anions CrO4 2- were performed within molecular cluster approach. Relaxed geometries, binding energies, charge differences of the adsorbed CrO4 2- anions, and electronic wave function contour plots were calculated using B3LYP hybrid exchange-correlation functional. Oscillator strengths of electronic transitions of CrO4 2- anions adsorbed on the surfaces of studied carbon nanostructures were calculated by the TD-DFT method. Calculations reveal covalent bonding between the anion and the adsorbents in all studied adsorption configurations. For all studied types of adsorbent structures, doping with N strengthens chemical bonding with CrO4 2- anions, providing a 2-eV increase in binding energies comparatively to adsorption of the anion on undoped adsorbents. Additional electronic transitions of CrO4 2- anions appear in the orange-green spectral region when the anions are adsorbed on the N-doped low-diameter carbon nanotubes CNT(3,3) and CNT(5,5).

  5. Chromatic dispersion monitoring and adaptive compensation using pilot symbols in an 8 x 12.5 Gbit/s all-optical OFDM system.

    Science.gov (United States)

    Shimizu, Satoshi; Cincotti, Gabriella; Wada, Naoya

    2014-04-07

    We propose and experimentally demonstrate a novel technique for chromatic dispersion (CD) monitoring and adaptive compensation in an 8 x 12.5 Gbit/s all-optical orthogonal frequency-division multiplexing (AO-OFDM) system by using two pilot symbols and a virtually imaged phased array (VIPA) for a tunable CD compensator. The two pilot symbols are added to the first and the last sub-channels of the OFDM signal, and their relative time delay is detected and used for CD estimation at the CD monitoring circuit. The monitored CD value is fed to VIPA for CD compensation. In the experiments, the relative time delay between the two pilot symbols was successfully observed, and the adaptive CD compensation drastically improved the bit-error-rate (BER) from over 10(-5) to under 10(-9). The estimated CD values showed less than 10 ps/nm difference from the values measured by a photonic dispersion analyzer, which is accurate enough since the AO-OFDM system can keep BER<10(-9) upto 20 ps/nm residual CD.

  6. Chromate-free Passivation Technology for Electrodeposited Nickel Coating%电沉积镀镍层的无铬钝化工艺

    Institute of Scientific and Technical Information of China (English)

    堵艳艳; 潘勇; 周兆锋; 李玮; 惠建科

    2012-01-01

    采用正交试验法筛选了一种以植酸、钼酸钠和缓蚀添加剂为基本组成的无铬钝化液。通过电化学阻抗谱测试,确定了最佳成膜时间;通过5%CusO4。点滴试验、10%NaCl浸泡试验和极化曲线测试,对电沉积镀镍层无铬钝化后的耐蚀性能进行了研究。结果表明,采用本无铬钝化工艺后,镀镍层耐蚀性能良好。%In order to improve the corrosion resistance of electrodeposited nickel coating and subsititute the carcinogenic hexavalent chromium passivation, a new chromate free passivation solution was screened out by means of orthogonal analysis experiments. Fhe solution was composed of phytic acid, sodium molybdate and corrosion inhibitor. The optimal time for conversion film formation was determined by electrochemical impedance spectroscopy. The corrosion resistant properties of electrodeposited nickel coating were studied by dropping corrosion test in 5% CuSO4, immersion test in 10% NaC1 and polarization curves. The results showed that the film passivated by the technology has good anti-corrosion performance.

  7. Chromatic X-Ray imaging with a fine pitch CdTe sensor coupled to a large area photon counting pixel ASIC

    CERN Document Server

    Bellazzini, R; Brez, A; Minuti, M; Pinchera, M; Mozzo, P

    2012-01-01

    An innovative X-ray imaging sensor with intrinsic digital characteristics is presented. It is based on Chromatic Photon Counting technology. The detector is able to count individually the incident X-ray photons and to separate them according to their energy (two 'color' images per exposure). The energy selection occurs in real time and at radiographic imaging speed (GHz global counting rate). Photon counting, color mode and a very high spatial resolution (more than 10 l.p./mm at MTF50) allow to obtain an optimal ratio between image quality and absorbed dose. The individual block of the imaging system is a two-side buttable semiconductor radiation detector made of a thin pixellated CdTe crystal (the sensor) coupled to a large area VLSI CMOS pixel ASIC. 1, 2, 4, 8 tile units have been built. The 8 tiles unit has 25cm x 2.5cm sensitive area. Results and images obtained from in depth testing of several configurations of the system are presented. The X-Ray imaging system is the technological platform of PIXIRAD Im...

  8. 舌尖红色度值测量与分析%Determination and Analysis of Chromatic Value in Abnormal Red Tongue Tip

    Institute of Scientific and Technical Information of China (English)

    姚叙莹; 梁嵘; 陈东宁; 王召平; 李丹溪; 田丁; 王盛花

    2015-01-01

    Objective To measure the chromatic differences of the tongue tip and tongue side and provide quantitative evidence for tongue color diagnosis. Methods Totally 683 healthy people were recruited, and their tongue photos were taken. Then ICC specific documents were used for the correction of all tongue photos, and chromatic values (L*, a*, b*, C*and h°) of tongue tip and tongue side were obtained for further statistical analysis. CIEDE2000 was used for calculating the color differences. Results The average color difference of tongue tip and tongue side in normal pink tongue was 5.4. When pink tongue has abnormal red tongue tip, the average color difference of tongue tip and tongue side was 10.85. Compared with normal tongue tip, the average color difference of tongue tip and tongue side in abnormal color tongue with abnormal red tongue tip increased from 5.4-7.0 to 11.23. Conclusion Red tongue tip is a sensitive sign indicating abnormal heat in the body. Tongue tip quantitative diagnosis is valuable in the determination of heat sign in TCM preventive treatment of disease, and reveal the diagnosis meaning and scientific connotation of red tongue tip.%目的:测量舌尖与舌缘的色度值与色差,为舌尖红的量化诊断提供依据。方法对683名健康体检者进行舌诊,并拍摄舌图像。创建ICC色彩特性文件,对舌图像进行色彩校正。提取舌尖、舌缘的色度值参数(L*、a*、b*、C*、h°)进行统计分析。采用 CIEDE2000色差公式进行色差计算。结果正常淡红舌的舌尖与舌缘的平均色差为5.4;淡红舌伴有舌尖红时,舌尖与舌缘的平均色差为10.85;各种异常舌色伴有舌尖红时,与没有舌尖红时比较,其平均色差从5.4~7.0增至11.23。结论舌尖红是判断初始热证的灵敏指标。对舌尖红进行量化诊断,对中医“治未病”的热象辨识具有价值,并能进一步揭示舌尖红的诊断意义与科学内涵。

  9. Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of synchrotron X-ray spectromicroscopy and related methods. 2. Original paint layer samples.

    Science.gov (United States)

    Monico, Letizia; Van der Snickt, Geert; Janssens, Koen; De Nolf, Wout; Miliani, Costanza; Dik, Joris; Radepont, Marie; Hendriks, Ella; Geldof, Muriel; Cotte, Marine

    2011-02-15

    The darkening of the original yellow areas painted with the chrome yellow pigment (PbCrO(4), PbCrO(4)·xPbSO(4), or PbCrO(4)·xPbO) is a phenomenon widely observed on several paintings by Vincent van Gogh, such as the famous different versions of Sunflowers. During our previous investigations on artificially aged model samples of lead chromate, we established for the first time that darkening of chrome yellow is caused by reduction of PbCrO(4) to Cr(2)O(3)·2H(2)O (viridian green), likely accompanied by the presence of another Cr(III) compound, such as either Cr(2)(SO(4))(3)·H(2)O or (CH(3)CO(2))(7)Cr(3)(OH)(2) [chromium(III) acetate hydroxide]. In the second part of this work, in order to demonstrate that this reduction phenomenon effectively takes place in real paintings, we study original paint samples from two paintings of V. van Gogh. As with the model samples, in view of the thin superficial alteration layers that are present, high lateral resolution spectroscopic methods that make use of synchrotron radiation (SR), such as microscopic X-ray absorption near edge (μ-XANES) and X-ray fluorescence spectrometry (μ-XRF) were employed. Additionally, μ-Raman and mid-FTIR analyses were carried out to completely characterize the samples. On both paint microsamples, the local presence of reduced Cr was demonstrated by means of μ-XANES point measurements. The presence of Cr(III) was revealed in specific areas, in some cases correlated to the presence of Ba(sulfate) and/or to that of aluminum silicate compounds.

  10. Escherichia coli NemA is an efficient chromate reductase that can be biologically immobilized to provide a cell free system for remediation of hexavalent chromium.

    Directory of Open Access Journals (Sweden)

    Katherine J Robins

    Full Text Available Hexavalent chromium is a serious and widespread environmental pollutant. Although many bacteria have been identified that can transform highly water-soluble and toxic Cr(VI to insoluble and relatively non-toxic Cr(III, bacterial bioremediation of Cr(VI pollution is limited by a number of issues, in particular chromium toxicity to the remediating cells. To address this we sought to develop an immobilized enzymatic system for Cr(VI remediation. To identify novel Cr(VI reductase enzymes we first screened cell extracts from an Escherichia coli library of soluble oxidoreductases derived from a range of bacteria, but found that a number of these enzymes can reduce Cr(VI indirectly, via redox intermediates present in the crude extracts. Instead, activity assays for 15 candidate enzymes purified as His6-tagged proteins identified E. coli NemA as a highly efficient Cr(VI reductase (k(cat/K(M= 1.1×10(5 M(-1 s(-1 with NADH as cofactor. Fusion of nemA to the polyhydroxyalkanoate synthase gene phaC from Ralstonia eutropha enabled high-level biosynthesis of functionalized polyhydroxyalkanoate granules displaying stable and active NemA on their surface. When these granules were combined with either Bacillus subtilis glucose dehydrogenase or Candida boidinii formate dehydrogenase as a cofactor regenerating partner, high levels of chromate transformation were observed with only low initial concentrations of expensive NADH cofactor being required, the overall reaction being powered by consumption of the cheap sacrificial substrates glucose or formic acid, respectively. This system therefore offers promise as an economic solution for ex situ Cr(VI remediation.

  11. Chromatic analysis by monitoring unmodified silver nanoparticles reduction on double layer microfluidic paper-based analytical devices for selective and sensitive determination of mercury(II).

    Science.gov (United States)

    Meelapsom, Rattapol; Jarujamrus, Purim; Amatatongchai, Maliwan; Chairam, Sanoe; Kulsing, Chadin; Shen, Wei

    2016-08-01

    This study demonstrates chromatic analysis based on a simple red green blue (RGB) color model for sensitive and selective determination of mercury(II). The analysis was performed by monitoring the color change of a microfluidic Paper-based Analytical Device (µPAD). The device was fabricated by using alkyl ketene dimer (AKD)-inkjet printing and doped with unmodified silver nanoparticles (AgNPs) which were disintegrated when being exposed to mercury(II). The color intensity was detected by using an apparatus consisting of a digital camera and a homemade light box generating constant light intensity. A progressive increase in color intensity of the tested area on the µPAD (3.0mm) was observed with increasing mercury(II) concentration. The developed system enabled quantification of mercury(II) at low concentration with the detection limit of 0.001mgL(-1) (3 SD blank/slope of the calibration curve) and small sample volume uptake (2µL). The linearity range of the calibration curve in this technique was demonstrated from 0.05 to 7mgL(-1) (r(2)=0.998) with good precision (RSD less than 4.1%). Greater selectivity towards mercury(II) compared with potential interference ions was also observed. Furthermore, the percentage recoveries of spiked water samples were in an acceptable range which was in agreement with the values obtained from the conventional method utilizing cold vapor atomic absorption spectrometer (CVAAS). The proposed technique allows a rapid, simple, sensitive and selective analysis of trace mercury(II) in water samples.

  12. El léxico cromático y la ideología maya Chromatic lexic and Maya ideology

    Directory of Open Access Journals (Sweden)

    Sanja Savkic

    2011-01-01

    Full Text Available Para acercarse al campo semántico de los colores, de primera importancia son diversos diccionarios de las lenguas mayances. El objetivo es hacer una descripción preliminar del vocabulario cromático, compuesto de cinco términos referidos a colores básicos que en el maya yucateco se llaman sak, ek', chak, k'an y ya'ax y significan "blanco", "negro", "rojo", "amarillo" y "verde-azul", respectivamente. El mismo vocabulario remite a determinadas categorías extralingüísticas que la lengua es capaz de acumular, reflejar y comunicar. Éstas dependen de una cultura particular, por lo que el estudio se amplía con las informaciones de diferentes fuentes escritas redactadas durante la época colonial. La intención es detectar los múltiples usos que se hacían en todos los ámbitos de la vida de los colores, lo cual a su vez permite considerar estos últimos como conceptualizaciones articuladas en pares de oposición o agrupamientos tripartitos.To gain greater insight into the color semantic field, it is important to consult various Mayance language dictionaries, in order to assemble a preliminary chromatic vocabulary, composed of five basic color terms which in Yucatec Maya are sak, ek', chak, k'an and ya'ax, or "white", "black", "red", "yellow" and "green-blue", respectively. The very vocabulary addresses certain extra-linguistic categories that language is capable of accumulating, reflecting, and communicating. These categories depend on a particular culture; consequently this study is amplified with greater information from different sources written during the colonial period in order to shed light on the many uses that the colors had in the aspects of human life which, at the same time, can be seen in conceptualizations articulated in pairs of opposition or tripartite groupings.

  13. Physical and photoelectrochemical properties of Sb-doped SnO2 thin films deposited by chemical vapor deposition: application to chromate reduction under solar light

    Science.gov (United States)

    Outemzabet, R.; Doulache, M.; Trari, M.

    2015-05-01

    Sb-doped SnO2 thin films (Sb-SnO2) are prepared by chemical vapor deposition. The X-ray diffraction indicates a rutile phase, and the SEM analysis shows pyramidal grains whose size extends up to 200 nm. The variation of the film thickness shows that the elaboration technique needs to be optimized to give reproducible layers. The films are transparent over the visible region. The dispersion of the optical indices is evaluated by fitting the diffuse reflectance data with the Drude-Lorentz model. The refractive index ( n) and absorption coefficient ( k) depend on both the conditions of preparation and of the doping concentration and vary between 1.4 and 2.0 and 0.2 and 0.01, respectively. Tin oxide is nominally non-stoichiometric, and the conduction is dominated by thermally electrons jump with an electron mobility of 12 cm2 V-1 s-1 for Sb-SnO2 (1 %). The ( C 2- V) characteristic in aqueous electrolyte exhibits a linear behavior from which an electrons density of 4.15 × 1018 cm-3 and a flat-band potential of -0.83 V SCE are determined. The electrochemical impedance spectroscopy shows a semicircle attributed to a capacitive behavior with a low density of surface states. The center lies below the real axis with a depletion angle (12°), due to a constant phase element, i.e., a deviation from a pure capacitive behavior, presumably attributed to the roughness and porosity of the film. The straight line at low frequencies is attributed to the Warburg diffusion. The energy diagram reveals the photocatalytic feasibility of Sb-SnO2. As application, 90 % of the chromate concentration (20 mg L-1, pH ~3) disappears after 6 h of exposure to solar light.

  14. The Colors and Chromatic Charts of Gold -Silver -Copper Carat Alloys%Au-Ag-Cu系开金合金的颜色与色度图

    Institute of Scientific and Technical Information of China (English)

    宁远涛

    2012-01-01

    颜色和色度坐标是珠宝饰品设计与制造的重要因素与参数.Au- Ag-Cu系合金是最重要的颜色开金饰品合金.文章评述了Ag、Cu对Au和Au基合金的光反射率和颜色的影响;介绍了Au- Ag-Cu系合金的色度图、金合金色泽标准及某些标准颜色合金成分;讨论了某些合金化元素对Au- Ag-Cu系合金颜色的影响.通过调整Ag、Cu组元含量比例和添加其它合金化元素,Au-Ag - Cu系开金合金可以获得丰富多彩的颜色,对于设计与控制珠宝饰品的颜色有重要意义.%Au - Ag - Cu system alloys are the most important color jewelry alloys. The colors of Au - Ag - Cu alloys depend on the composition and the content of the alloying components. The influences of Ag and Cu components on the reflectivity and color of gold and gold - based alloys were reviewed. The chromatic charts of gold - silver - copper carat alloys, color standard of carat alloys and the compositions of some standard color gold alloys were introduced. The effects of some other alloying elements on the color of gold alloys were also discussed. Au - Ag - Cu carat alloys can develop rich and varied colors through regulating the ratio of the contents of Ag and Cu in alloys and adding other alloying elements, which is the basis for designing and controlling colors of carat alloys based on gold.

  15. Chromate (CrO(4)(2-)) and copper (Cu2+) adsorption by dual-functional ion exchange resins made from agricultural by-products.

    Science.gov (United States)

    Marshall, Wayne E; Wartelle, Lynda H

    2006-07-01

    Ion exchange resins commonly have a single functionality for either cations or anions. Resins that have a dual functionality for both cations and anions are uncommon. The objective of this study was to create dual-functional ion exchange resins derived from soybean hulls, sugarcane bagasse and corn stover. Dual-functional resins were prepared by two separate two-step processes. In the first two-step process, by-products were reacted with a solution of citric acid in order to impart additional negative charge, and then reacted with the cross-linking reagent dimethyloldihydroxyethylene urea (DMDHEU) and a quaternary amine (choline chloride) to add positive charge to the lignocellulosic material. In the second two-step process, the order of reaction was reversed, with positive charge added first, followed by the addition of negative charge. These combined reactions added both cationic and anionic character to the by-products as evidenced by the increased removal from solution of copper (Cu(2+)) cation and the chromate (CrO(4)(2-)) anion compared to unmodified by-products. The order of reaction appeared to slightly favor the functionality that was added last. That is, if negative charge was added last, the resulting resin sequestered more copper ion than a comparable resin where the negative charge was added first and vice-versa. Cu(2+) and CrO(4)(2-) were used as marker ions in a solution that contained both competing cations and anions. The dual-functional resins adsorbed as much as or more of the marker ions compared to commercial cation or anion exchange resins used for comparison. None of the commercial resins exhibited dual-functional properties to the same extent as the by-product-based resins.

  16. Experimental demonstration of low-complexity fiber chromatic dispersion mitigation for reduced guard-interval OFDM coherent optical communication systems based on digital spectrum sub-band multiplexing.

    Science.gov (United States)

    Malekiha, Mahdi; Tselniker, Igor; Nazarathy, Moshe; Tolmachev, Alex; Plant, David V

    2015-10-05

    We experimentally demonstrate a novel digital signal processing (DSP) structure for reduced guard-interval (RGI) OFDM coherent optical systems. The proposed concept is based on digitally slicing optical channel bandwidth into multiple spectrally disjoint sub-bands which are then processed in parallel. Each low bandwidth sub-band has a smaller delay-spread compared to a full-band signal. This enables compensation of both chromatic dispersion (CD) and polarization mode dispersion using a simple timing and one-tap-per-symbol frequency domain equalizer with a small cyclic prefix overhead. In terms of the DSP architecture, this allows for a highly efficient parallelization of DSP tasks performed over the received signal samples by deploying multiple processors running at a lower clock rate. It should be noted that this parallelization is performed in the frequency domain and it allows for flexible optical transceiver schemes. In addition, the resulting optical receiver is simplified due to the removal of the CD compensation equalizer compared to conventional RGI-OFDM systems. In this paper we experimentally demonstrate digital sub-banding of optical bandwidth. We test the system performance for different modulation formats (QPSK, 16QAM and 32QAM) over various transmission distances and optical launch powers using a 1.5% CP overhead in all scenarios. We also compare the proposed RGI-OFDM architecture performance against common single carrier modulation formats. At the same total data rate and signal bandwidth both systems have similar performance and transmission reach whereas the proposed method allows for a significant reduction of computational complexity due to removal of CD pre/post compensation equalizer.

  17. 具有5n个点的完全5部图的分类及5图部的色性%CLASSIFICATION OF COMPLETE 5-PARTITE GRAPHS AND CHROMATICITY OF 5-PARTITE GRAPHS WITH 5n VERTICES

    Institute of Scientific and Technical Information of China (English)

    赵海兴; 刘儒英; 张胜贵

    2004-01-01

    For a graph G,P(G, A)denotes the chromatic polynomial of G. Two graphs G and H are said to be chromatically equivalent,denoted by G~H,if P(G,λ) = p(H,λ). Let [G]= {H|H~G}.If [G] = {G} ,then G is said to be chromatically unique. For a complete 5-partite graph G with 5n vertices, define θ(G) = (a(G, 6) - 2n+1 - 2n-1 + 5)/2n-2, where a(G,6) denotes the number of 6-independent partitions of G. In this paper, the authors show that θ(G)≥0 and determine all graphs with θ(G) = 0, 1, 2, 5/2, 7/2, 4, 17/4. By using these results the chromaticity of 5-partite graphs of the form G -5 with θ(G) = 0, 1, 2, 5/2, 7/2, 4, 17/4 is investigated,where 5 is a set of edges of G. Many new chromatically unique 5-partite graphs are obtained.

  18. Selectivity of the adsorption process of modified zeolite rock with hexadecyl trimethylammonium bromide in front to chromates and dichromates; Selectividad del proceso de adsorcion de roca zeolitica modificada con bromuro de hexadeciltrimetilamonio frente a cromatos y dicromatos

    Energy Technology Data Exchange (ETDEWEB)

    Salgado G, N.

    2011-07-01

    In the present investigation natural zeolite (clinoptilolite) from the Chihuahua state, which was conditioned with sodium chloride solution and subsequently modified with a hexadecyl trimethylammonium bromide solution was used to evaluate the removal of Cr (Vi) from chromate or dichromate solutions. The zeolite materials were characterized by scanning electron microscopy and X-ray diffraction. The surface area was also determined. The experiments were performed in a batch system, the influence of ph, contact time between phases were investigated and during the adsorption process was calculated the concentration of chromium ion present in aqueous solution (CrO{sub 4}{sup 2-}, Cr{sub 2}O{sub 7}{sup 2-}). The quantification of chromium removed from the aqueous solution by atomic absorption spectrometry technique was done. In order to understand the behaviour of the adsorption kinetics the pseudo first and pseudo second order models were applied, and to determine the adsorption capacity of the zeolite materials for Cr the Langmuir, Freundlich and Langmuir-Freundlich models were chosen. It was found that the removal efficiency of chromium ion is influenced by ph and the chemical species present: chromate or dichromate. The chromate and dichromate sorption kinetic data were best fitted to the pseudo-second and pseudo-first order models, respectively; and the Langmuir and Langmuir-Freundlich models described adequately the isotherms data considering a mono component system. In a mixture of Cr (Vi) ad CrO{sub 4}{sup 2-} and Cr{sub 2}O{sub 7}{sup 2-}, the surfactant modified zeolite has a greater selectivity for Cr{sub 2}O{sub 7}{sup 2-} ion than CrO{sub 4}{sup 2-}. In this case the Langmuir-Freundlich model described the adsorption isotherm behavior. (Author)

  19. Analysis of Chromaticity Parameters of Life Complexion and Death Complexion Based on OLAP%基于OLAP技术的主生主死色色度学参数分析

    Institute of Scientific and Technical Information of China (English)

    石文娟; 赵文光; 曾常春; 陈铿; 倪栩生; 陈凤兰; 梁丽华

    2012-01-01

    Based on the principle of ancient books and colour CIE colour system and color measurement technology, makes exploration and research on the quantitative description of color diagnosis color, to realize color distinction through spectral analysis method. Uses CIE color system relat- ed formulas to calculate the chromaticity parameters, cube technology to master the main dead color chromaticity parameters for analysis and research, and it has the certain guiding signifi- cance for the application of clinical practice, can provide reference for analysis of diagnosis in TCM color chromaticity parameters, and in line with the quantitative color diagnosis require- ments that the traditional Chinese medicine modernization proposed.%借鉴古籍的原理和颜色CIE色度系统及颜色测量技术.对色诊颜色的定量描述做探索研究.对善恶色的区分通过光谱分析法来实现。利用CIE色度系统的相关公式计算出各色度学参数、多维数据集技术对主生主死色色度学参数进行分析与研究,对临床实际的应用有一定的指导意义.为分析中医色诊中色度学参数提供参考,符合中医色诊现代化提出的定量化要求。

  20. The Further Results of the Chromatic Uniqueness of Complete Tripartite Graphs K(m, n, r)%完全三部图K(m,n,r)的色唯一性的进一步结果

    Institute of Scientific and Technical Information of China (English)

    邹辉文; 朱忠华

    2001-01-01

    Let G be a simple graph and P(G,λ) denote the chromatic polynomial of G.A graph G is said to be chromatically unique if for any graph H, P(H,λ) = P(G,λ) implies that H is isomorphic to G.Iet K(m,n,r) denote a complete tripartite graph,it is proved that K (m , n , r ) (if m ≤ n ≤ r , O ≤ r - m ≤ 3 and m≥2) are all chromatically unique.%设G是简单图,用P(C,λ)表示图C的色多项式.若对任意简单图H使P(H,λ)=P(G,λ),都有H与C同构,则称C是色唯一图.令K(m,n,r)表示完全三部图,证明了 (1)设m≤n≤r,r-m=k≥0,若m>k+k2/3,则K(m,n,r)是色唯一图. (2)若k≥0,m>k2-2k+2(k2-k+1)1/2/3,则K(m,m+1,m+k)是色唯一图. (3)若k≥0,m>k2-3k+2+2(k2-2k+4)1/2/3,则K(m,m+2,m+k)是色唯一图. (4)设m≤n≤r,0≤r-m≤3,若m≥2,则K(m,n,r)是色唯一图.

  1. Classification of waste wood treated with chromated copper arsenate and boron/fluorine preservatives; Classificacao de residuos de madeira tratada com preservativos a base de arseniato de cobre cromatado e de boro/fluor

    Energy Technology Data Exchange (ETDEWEB)

    Ferrarini, Suzana Frighetto; Santos, Heldiane Souza dos; Miranda, Luciana Gampert; Azevedo, Carla M.N.; Pires, Marcal J.R., E-mail: suzana.ferrarini@gmail.com [Faculdade de Quimica, Pontificia Universidade Catolica do Rio Grande do Sul, Porto Alegre, RS (Brazil); Maia, Sandra Maria [Instituto de Quimica, Universidade Federal do Rio Grande do Sul, Porto Alegre, RS (Brazil)

    2012-07-01

    Classification of waste wood treated with chromated copper arsenate (CCA) and boron/fluorine preservatives, according to NBR 10004, was investigated. The leaching test (ABNT NBR 10005) for As and Cr, and solubilization test (ABNT NBR 10006) for F, were applied to out-of-service wooden poles. Concentrations of As and Cr in leachates were determined by ICP-MS and of F by ESI. Values for As were higher than 1 mg L{sup -1} classifying the waste as hazardous material (Class I) whereas values for F (> 1.5 mg L{sup -1}) were non-hazardous but indicated non-inert material (Class IIA). (author)

  2. Theoretical Calculation of System Performance of Fiber Optic Network with Chromatic Dispersion, Polarization Mode Dispersion, Polarization Dependent Loss, and Amplifier Spontaneous Emission Noise

    Science.gov (United States)

    Abuzariba, Suad Mohamed

    This thesis includes a theoretical study of the performance of an optical network system with linear impairments: chromatic dispersion (CD), polarization mode dispersion (PMD), polarization dependent loss (PDL), and amplified spontaneous emission (ASE) noise. Both the a-factor and bit error rate (BER) were used as performance parameters in this study. First, an analytical optical eye diagram evaluation for a system of highly mode coupled PMD/PDL fiber and lumped sections (up to fifteen sections) have been presented in this study. Based on this evaluation we found that with PDL considered as well as PMD, the a-factor of the output becomes higher than that of a Maxwellian fiber having the same total root mean-squared PMD and PDL values, when the mean-square PDL element of the lumped sections makes up the major portion of the total mean-square of the whole system. Whereas without considering PDL, the a-factor becomes higher as the mean-square PMD element of the Maxwellian fiber takes the major portion of the total mean-square PMD element of the whole system. Also the worst case for the a-factor occurred when the lumped sections were in the middle between two equivalent Maxwellian fibers, rether than if the lumped sections were followed by Maxwellian fiber or the Maxwellian fiber is followed by the lumped sections. We also note that two equivalent Maxwellian fibers connected in series will not give the same a-factor as a Maxwellian fiber equivalent calculated by concatenation rules unless they have the same values of PMD, PDL, and polarization direction correlation elements. Second, considering ASE-noise besides CD, PMD, and PDL, improved values of bit error rate (BER) were gotten using the moment generation function for the optical system in cases of ON-OFF modulation format and DPSK modulation format. We found that, even when considering the noise only without the signal, the probability density function of the output current was dependent on the output state of

  3. Change of brightness, chromatism and infra red spectra of compressed China fir wood during heat treatment%热处理过程中杉木压缩木材的材色及红外光谱

    Institute of Scientific and Technical Information of China (English)

    王洁瑛; 赵广杰; 中野隆人

    2001-01-01

    In this study the brightness, chromatism and infra red spectra ofcompressed China fir wood during heat treatment in air or heat treatment in vacuum are studied. The water-saturated and boiled specimens of China fir (Cunninghamia lanceolata) are hot pressed with the average compression rate of 50%. Then they are heat treated in a common oven or in a vacuum oven, with the temperatures of treatment of 140,160,180,200,220℃, respectively. Then the brightness, chromatism, infra red spectra of the specimens are measured and discussed. In addition, some relationships between brightness, chromatism and recovery, weight loss and anti-swelling efficiency are deduced and discussed. The results are: (1) The brightness of the specimens will decrease and the chromatism will increase with the prolongation of time of heat treatment. Compared to heat treatment in vacuum, the specimens have less brightness and more chromatism after being heat treated in air, under the conditions of same temperature and time of heat treatment. (2) As far as the relationships between brightness, chromatism and recovery are concerned, there is little difference between heat treatment in air and heat treatment in vacuum. The fixation degree of compression set is closely related to the change degree of color. (3) As far as the relationships between brightness, chromatism and weight loss, anti-swelling efficiency are concerned, the more the weight loss or anti-swelling efficiency is, the less the brightness is, or the more the chromatism is. (4) The infra red spectra of specimens show that there are evident changes of waves at the wavelength of 1743, 1660 and 1605cm-1 which are attributed to the change of C=O in wood. So it is clear that at least hemicellulose, even lignin in wood cell chemically changes during heat treatment of compressed wood of China fir.%为了探讨热处理过程中杉木压缩木材的材色变化规律,以及材色和木材化学主成分变化之间的关系,该

  4. Non-Chromate Aluminum Pretreatments

    Science.gov (United States)

    2012-03-01

    painted steel test stands using porcelain insulator stand-offs. The rack angle of the coupons is 30 degrees from horizontal. An “X” incision was...Components with TCP – NADEP CP, October 2000 5.1 – LCAC-26 Oily Waste Tank with TCP Test Patch 5.2 – Beachside Exposure Racks , Little Creek, VA 5.3...Hull Components – AA7039 5.22 – Headlight Guards 5.23 – Stowage Box Doors 5.24 – Floor Plate, Bilge Pump 5.25 – Driver’s Steering Yoke 5.26

  5. Study on chromatic visual evoked potential (VEP) of normal people and congenital color vision deficient%正常及先天性色觉异常者颜色视觉诱发电位的研究

    Institute of Scientific and Technical Information of China (English)

    刘虹; 郭静秋

    2001-01-01

    Objective This sutdy is to present the different color visual evoked potential (VEP) waves between normal and color vision deficient. The aim is to serve as criterion evaluating the vision function and analyzing color mechanism. Method Four kinds of reversal checkerboard patterns are simulated by the compute software technology as stimuli, including black-white, isoluminant red-white, green-white, red-green chromatic checkerboards. The transient VEP were measured in normal people and color vision deficient. Results (1) In normal people group the P1 latencies of 15 channel which were elicited with red-white, green-white checkerboard were longer, The P1 amplitudes of 10 channel which were elicited with chromatic checkerboards were lower. (2) The P1 latencies in four conditions were obtained and in terms of the length of latencies, the ordinal of P1 latencies is as follows: red-white <black-white <red-green <green-white. There were very significant differences among the four latencies. The P1 amplitudes elicited with the black-white were higher than those with chromatic ones. But, among the P1 amplitudes elicited with chromatic checkerboards there were no difference. (3) In color vision deficient group there were no significant differences in the P1 latencies and amplitudes elicited with the four stimuli. But P1 latencies elicited with black-white stimulus was shortest. Red-green blindness and deuteranopia had no response to green stimulus but did to red or red-green stimulus. (4) Between the two groups there were no differences in the P1 latencise, but the P1 amplitude of abnormal group elicited with the chromatic stimuli were obviously lower. Conclusion (1) it is feasible to use chromatic VEP for examining congenital color vision deficient, especially for red-green blindness and deuteranopia. (2) There are relatively main chromatic processing field in the visual cortex center. (3) The color and bringhtness may be dealt with in the same visual system, the

  6. CALiPER Retail Lamps Study RRL3.2 Lumen and Chromaticity Maintenance of LED A lamps Operated in Steady-State Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Royer, Michael P. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); McCullough, Jeffrey J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tucker, Joseph C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-12-01

    new technology trying to build a reputation with consumers. Beyond the observed parametric failures nearly half of the products failed to meet early-life thresholds for lumen maintenance, which were borrowed from ENERGY STAR specifications. That is, the lumen maintenance was sufficiently low at 6,000 hours that seven of the products are unlikely to have lumen maintenance above 70% at their rated lifetime (which was usually 25,000 hours). Given the methods used for this investigation—most notably continuous operation—the results should not be interpreted as indicative of a lamp’s performance in a typical environment. Likewise, these results are not directly relatable to manufacturer lifetime claims. This report is best used to understand the variation in LED product performance, compare the robustness of LED lamps and benchmark conventional lamps, and understand the characteristics of lumen and chromaticity change. A key takeaway is that the long-term performance of LED lamps can vary greatly from model to model (i.e., the technology is not homogenous), although the lamp-to-lamp consistency within a given model is relatively good. Further, operation of LED lamps in an enclosed luminaire (or otherwise in high ambient temperatures), can induce parametric failure of LEDs much earlier than their rated lifetime; manufacturer warnings about such conditions should be followed if performance degradation is unacceptable.

  7. Vaulted trans-bis(salicylaldiminato)platinum(II) crystals: heat-resistant, chromatically sensitive platforms for solid-state phosphorescence at ambient temperature.

    Science.gov (United States)

    Komiya, Naruyoshi; Okada, Minoru; Fukumoto, Kanako; Kaneta, Kenji; Yoshida, Atsushi; Naota, Takeshi

    2013-04-08

    The synthesis, structure, and solid-state emission of vaulted trans-bis(salicylaldiminato)platinum(II) complexes are described. A series of polymethylene (1: n=8; 2: n=9; 3: n=10; 4: n=11; 5: n=12; 6: n=13) and polyoxyethylene (7: m=2; 8: m=3; 9: m=4) vaulted complexes (R=H (a), 3-MeO (b), 4-MeO (c), 5-MeO (d), 6-MeO (e), 4-CF3O (f), 5-CF3O (g)) was prepared by treating [PtCl2(CH3CN)2] with the corresponding N,N'-bis(salicylidene)-1,ω-alkanediamines. The trans coordination, vaulted structures, and the crystal packing of 1-9 have been unequivocally established from X-ray diffraction studies. Unpredictable, structure-dependent phosphorescent emission has been observed for crystals of the complexes under UV excitation at ambient temperature, whereas these complexes are entirely nonemissive in the solution state under the same conditions. The long-linked complex crystals 4-6, 8, and 9 exhibit intense emission (Φ77K =0.22-0.88) at 77 K, whereas short-linked complexes 1-3 and 7 are non- or slightly emissive at the same temperature (Φ77K solid-state emission over the range of 98 nm can be performed simply by introducing MeO groups at different positions on the aromatic rings. Orange, yellow-green, red, and yellow emissions are observed in the glass and crystalline state upon 3-, 4-, 5-, and 6-MeO substitution, respectively, whereas those with CF3 O substituents have orange emission, irrespective of the substitution position. DFT calculations (B3LYP/6-31G*, LanL2DZ) showed that such chromatic variation is ascribed to the position-specific influence of the substituents on the highest-occupied molecular orbital (HOMO) and lowest-unoccupied molecular orbital (LUMO) levels of the trans-bis(salicylaldiminato)platinum(II) platform. The solid-state emission and its heat resistance have been discussed on the basis of X-ray diffraction studies. The planarity of the trans-coordination sites is strongly correlated to the solid-state emission intensities of crystals 1-9 at lower

  8. Initial development and chromatic value analysis of customized dental fluorosis shade guide%氟斑牙体瓷层比色板的初步研制及颜色分析

    Institute of Scientific and Technical Information of China (English)

    毛岭; 刘炜; 廖健; 吴兰; 王永

    2012-01-01

    目的 为解决个别牙缺失及缺损的氟斑牙患者烤瓷修复中的比色及颜色调配问题,定制氟斑牙金属基底体瓷层比色板来模拟氟斑牙的基色调.方法 采用牙本质修饰瓷和牙本质瓷粉按一定比例混合后烧制而成氟斑牙体瓷层比色板.分别模拟轻、中、重度氟斑牙基色调.采用松风Shade eye NCC电脑比色仪测定其色度学各要素(L*a*b*)值.结果 (1)比色板各组颜色分布具有一定规律性.(2)各组比色板色差及分布区域明显不同.(3)定制比色板的色度值范围绝大多数在氟斑牙色度值范围内,说明定制比色板的颜色能模拟一部分氟斑牙颜色.结论 定制氟斑牙金属基底体瓷层比色板对于临床氟斑牙比色有一定意义,但其精度有待于进一步提高.%Objective In order to resolve the problems of shade selection and color matching in porcelain for the patients with a-part of odontoptosis dental fluorosis. Customized dental fluorosis shade guide simulate dental fluorosis dentinal primary colour. Methods Vita dentinal porcelain powders and Vita dentine modifier porcelain powders were selected in special prescription to mix and shade guide tabs were made,Which simulate the lightly degree,the midrange degree and weight degree dental fluorosis dentinal primary color. Chromaticity element valueCL * , a * , b * ) were measured by a computer-aided Shade Eye NCC. Results (l)The color distribution in each group of customized dental fluorosis shade guide showed regular pattern. (2) The arrangement order of chroma of the each group color guide marked different color stage in chrome and diffeange. (3) The majority chromatic value rent ramplitude of customized shade guide was simulated the chromatic value amplitude of dental fluorosis. Conclusion The customized metal dental fluorosis shade guide have a special meaning in clinical dental fluorosis shade guide, but its precision need to be improved in the future.

  9. Effect of Cerium Chloride on Corrosion Resistance of Chromate Conversion Coatings on Aluminum Alloy 6061%氯化铈对铝合金铬酸盐转化膜防护性能的影响

    Institute of Scientific and Technical Information of China (English)

    张圣麟; 李维维; 张小麟; 马强; 遥远; 王圆圆

    2011-01-01

    The corrosion resistance of the chromate conversion coatings (CCCs) formed on AA6061 in chromate solutions with cerium chloride (0 ~ 60 mg/L) as additive was investigated by electrochemical measurement technology. The results of potentiodynamic polarization curves showed that the values of the pitting corrosion potential (Epit) and corrosion potential (Eoorr) of the CCCs raised greatly by adding a small amount of CeCl3 (20~40 rng/L). The electrochemical impedance spectroscopy (EIS) showed that the values of normalized Rp also greatly increased. The two tests indicate that an appropriate amount of CeCl3 (20~40 mg/L) can improve effectively the corrosion resistance of the CCCs, whereas an excessive CeCl3 (e. g 60 mg/L) may deteriorate the property of the CCCs.%采用电化学方法研究了6061铝合金在以CeCl3(0~60 mg/L)为添加剂的铬酸盐处理液中所得转化膜的防护性能.极化曲线测试结果表明,加入适量的CeCl3(20~40 mg/L),使电极的腐蚀电位Ecorr和点蚀电位Epit提高很多;电化学阻抗(EIS)测试结果表明,加入CeCl3后,膜层的阻抗大幅度增加.研究表明,加入适量的CeCl3可以有效改善膜层的防护性能,而过量的CeCl3(60 mg/L)却使其性能变差.

  10. Sentido cromático: tipos de defeitos e testes de avaliação clínica Chromatic sense: types of defects and clinical evaluation tests

    Directory of Open Access Journals (Sweden)

    Lígia Fernanda Bruni

    2006-10-01

    Full Text Available A avaliação do senso cromático tem grande valor na clínica oftalmológica, tanto para diagnóstico dos defeitos congênitos (daltonismo, como para diagnóstico e acompanhamento dos defeitos adquiridos. Diversos testes clínicos podem ser aplicados para esse fim. Porém, é necessário conhecermos a proposta e a sensibilidade de cada um deles, pois existem grandes variações de resultados, dependendo da doença que se procura diagnosticar, se congênita ou adquirida. Buscamos com este trabalho revisar os tipos de defeitos da sensibilidade cromática e fornecer informações sobre os principais testes utilizados, bem como sua melhor aplicação. Enfatizamos, ainda, a importância da padronização da iluminação do ambiente onde são aplicados esses testes.Evaluation of the chromatic sense has a great value in ophthalmic practice, both for diagnosis of the congenital defects (daltonism, as well as for diagnosis and follow-up of acquired defects. Many clinical tests are available to be used for this purpose. However it is necessary to know the details and sensitivity of each test, since there are many variations in the results, depending on the searched condition, if congenital or acquired pathologies. Our goal is to review the types of defects of the chromatic sense and provide information about the main current available tests and their best purpose. We further emphasize the importance of standard illumination procedure in the application of the tests.

  11. Schizophrenia spectrum participants have reduced visual contrast sensitivity to chromatic (red/green and luminance (light/dark stimuli: new insights into information processing, visual channel function and antipsychotic effects

    Directory of Open Access Journals (Sweden)

    Kristin Suzanne Cadenhead

    2013-08-01

    Full Text Available Background: Individuals with schizophrenia spectrum diagnoses have deficient visual information processing as assessed by a variety of paradigms including visual backward masking, motion perception and visual contrast sensitivity (VCS. In the present study, the VCS paradigm was used to investigate potential differences in magnocellular (M versus parvocellular (P channel function that might account for the observed information processing deficits of schizophrenia spectrum patients. Specifically, VCS for near threshold luminance (black/white stimuli is known to be governed primarily by the M channel, while VCS for near threshold chromatic (red/green stimuli is governed by the P channel. Methods: VCS for luminance and chromatic stimuli (counterphase-reversing sinusoidal gratings, 1.22 c/deg, 8.3 Hz was assessed in 53 patients with schizophrenia (including 5 off antipsychotic medication, 22 individuals diagnosed with schizotypal personality disorder and 53 healthy comparison subjects. Results: Schizophrenia spectrum groups demonstrated reduced VCS in both conditions relative to normals, and there was no significant group by condition interaction effect. Post-hoc analyses suggest that it was the patients with schizophrenia on antipsychotic medication as well as SPD participants who accounted for the deficits in the luminance condition. Conclusions: These results demonstrate visual information processing deficits in schizophrenia spectrum populations but do not support the notion of selective abnormalities in the function of subcortical channels as suggested by previous studies. Further work is needed in a longitudinal design to further assess VCS as a vulnerability marker for psychosis as well as the effect of antipsychotic agents on performance in schizophrenia spectrum populations.

  12. Estimativa indireta de teores de licopeno em frutos de genótipos de tomateiro via análise colorimétrica Indirect estimation of lycopene concentration in fruits of tomato genotypes via chromaticity values

    Directory of Open Access Journals (Sweden)

    Wesley Carvalho

    2005-07-01

    licopeno foi correlacionada com os resultados das relações a*/b* e (a*/b*², sendo que os valores de cromaticidade da polpa homogeneizada apresentaram novamente as mais elevadas correlações. Estes resultados confirmam que é possível estimar indiretamente e com relativa precisão, o teor de licopeno em frutos do tomateiro a partir de valores de cromaticidade. Esta metodologia pode ser empregada para seleção de genótipos com maiores teores de licopeno, de maneira mais simplificada, evitando o dispêndio e os problemas de descarte dos solventes orgânicos utilizados nos métodos espectrofotométricos.Lycopene (C40H56 is a red carotenoid pigment, which naturally accumulates in flowers, fruits and roots of some vegetable and fruit crops. The unique properties of the lycopene molecule make this pigment one of the most powerful antioxidants available. Tomato (Lycopersicon esculentum Mill. fruits and processed tomato products are the main sources of lycopene in the human diet. There is a growing amount of experimental data indicating that lycopene intake is associated with decreased risk of many types of degenerative and cardiovascular diseases as well as cancers in humans. In addition, lycopene concentration is associated with improved visual perception of tomato products. Therefore, there is a strong demand to increase the total amount of lycopene in tomato cultivars for either fresh market or processing. The development of cultivars for improved lycopene content is dependent upon the availability of simple yet accurate methodologies to quantify this carotene in tomato fruits and processed tomato products. The main objective of this work was to estimate the degree of correlation between the total lycopene content in tomato fruits measured spectrophotometrically and the chromaticity values (L*, a* and b* obtained using a tristimulus colorimeter. Colorimetric readings were taken using three sampling strategies: (1 external fruit wall; (2 internal fruit wall and (3 the

  13. Investigation of Color Discrimination Threshold Characteristics Under Different Chromatic Backgrounds%基于不同颜色背景的人眼辨色阈值特性研究

    Institute of Scientific and Technical Information of China (English)

    曾旺; 徐海松; 汪哲弘; M.Ronnier Luo

    2011-01-01

    In order to investigate the influence of different chromatic backgrounds on the color discrimination characteristics, the psychophysical experiment based on the interleaved staircase method is carried out on the CIE1976L * a * b* plane to obtain the color discrimination thresholds at the five CIE color centers under these five different background colors respectively. Detailed analysis on the fitted discrimination threshold ellipses indicates that the local visual uniformity, as a whole, is stable at the same color centre under different background colors, and the semi-axis ratios of individual chromatic ellipses at different color centers shows similar trends against the hues of background colors. The color discrimination sensitivity is highest when the colors of the center and the background are the same, which implies evidently the crispening effect. For the cases of red and blue centers or of yellow and blue backgrounds, the human color discrimination characteristics are less affected at the red-green direction than the yellow-blue direction.%为了研究不同颜色背景对人眼辨色阈值特性的影响,在CIE1976L*a*b*平面上,基于心理物理学的交叉阶梯法测得国际照明委员会(CIE)推荐的5个基本颜色中心分别在该五个颜色背景下的辨色阈值.通过对辨色阈值椭圆的详细分析表明,同一颜色中心的辨色阈值在不同颜色背景下的局部视觉均匀性总体上保持相对稳定,而不同颜色中心的色度椭圆其长短半轴之比与背景颜色的色调角之间存在着一致的趋势.当背景颜色与中心颜色相同时,视觉辨色灵敏度最高,存在明显的Crispening效应.对于红色和蓝色中心以及黄色和蓝色背景,人眼的视觉辨色特性在红-绿方向受到的影响均小于黄-蓝方向.

  14. Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods. Part 5. Effects of nonoriginal surface coatings into the nature and distribution of chromium and sulfur species in chrome yellow paints.

    Science.gov (United States)

    Monico, Letizia; Janssens, Koen; Vanmeert, Frederik; Cotte, Marine; Brunetti, Brunetto Giovanni; Van der Snickt, Geert; Leeuwestein, Margje; Salvant Plisson, Johanna; Menu, Michel; Miliani, Costanza

    2014-11-04

    The darkening of lead chromate yellow pigments, caused by a reduction of the chromate ions to Cr(III) compounds, is known to affect the appearance of several paintings by Vincent van Gogh. In previous papers of this series, we demonstrated that the darkening is activated by light and depends on the chemical composition and crystalline structure of the pigments. In this work, the results of Part 2 are extended and complemented with a new study aimed at deepening the knowledge of the nature and distribution of Cr and S species at the interface between the chrome yellow paint and the nonoriginal coating layer. For this purpose, three microsamples from two varnished paintings by Van Gogh and a waxed low relief by Gauguin (all originally uncoated) have been examined. Because nonoriginal coatings are often present in artwork by Van Gogh and contemporaries, the understanding of whether or not their application has influenced the morphological and/or physicochemical properties of the chrome yellow paint underneath is relevant in view of the conservation of these masterpieces. In all the samples studied, microscopic X-ray fluorescence (μ-XRF) and X-ray absorption near edge structure (μ-XANES) investigations showed that Cr(III)-based alteration products are present in the form of grains inside the coating (generally enriched of S species) and also homogeneously widespread at the paint surface. The distribution of Cr(III) species may be explained by the mechanical friction caused by the coating application by brush that picked up and redistributed the superficial Cr compounds, likely already present in the reduced state as result of the photodegradation process. The analysis of the XANES profiles allowed us to obtain new insights into the nature of the Cr(III) alteration products, that were identified as sulfate-, oxide-, organo-metal-, and chloride-based compounds. Building upon the knowledge acquired through the examination of original paint samples and from the

  15. Influence of Glass Components on Chromaticity and Properties of Green Glass-Ceramics%基础成分对绿色微晶玻璃色度及性能的影响

    Institute of Scientific and Technical Information of China (English)

    姜妍彦; 李振全; 王世凯; 刁云超

    2011-01-01

    以CaO-Al2O3-SiO2玻璃为基础,以CuO+Cr2O3为着色剂,通过烧结法制备了绿色微晶玻璃,采用X射线衍射、扫描电子显微镜、色度计、熟膨胀仪和硬度计研究了Al2O3、Na2O和ZnO含量对绿色微晶玻璃晶相结构、色度及性能的影响.结果表明:在所研究的成分范围内,Al2O3、ZnO和Na2O含量的变化不改变绿色微晶玻璃的主晶相,但随着Al2O3加入量的增加微晶相减少,熟膨胀系数和密度减小,显微硬度增大,颜色向褐绿色转变;随着Na2O含量的增加,微晶玻璃的颜色逐渐纯正,光泽度增加;随着ZnO含量的增加,微晶玻璃的色度不变,但表面光泽度降低.%Green glass-ceramics were prepared by sintering method based on CaO-Al2O3-SiO2 system glass, using CuO+Cr2O3 as colorants. Impact of the contents of A12O3, Na2O and ZnO in green glass-ceramics on crystal structure, chromaticity and properties was studied via X-ray diffraction, scanning electron microscope, colorimeter, dilatometer and hardness tester. The results indicate that the main crystal phase of green glass-ceramics doesn't change with the contents of A12O3, Na2O or ZnO in the range of the composition, but the microcrystalline phase, the thermal expansion coefficient decrease, micro-hardness increase, the color changes from bright green to brownish-green with the increasing of A12O3. The color of glass-ceramics gradually becomes bright green and the surface glossiness increases with the increasing of Na2O. The chromaticity of glass-ceramics doesn't change, but the surface glossiness decrease with the increasing of ZnO.

  16. 基于感兴趣点特征的彩色图像目标分类与识别%Chromatic image classification and recognition based on interest point features

    Institute of Scientific and Technical Information of China (English)

    赵文哲; 秦世引

    2011-01-01

    提出一种基于赋色尺度不变特征变换的特征提取方法,分析证明了该特征对平移、旋转、缩放、颜色漂移等因素的不变性.进而研究了基于该特征的彩色图像目标分类与识别的策略和实现技术,提出了相应的算法.通过运用阿姆斯特丹目标图片库中随机选择的50类对象进行分类识别的实验检验,识别正确率可达到100%.理论分析和实验结果表明,赋色尺度不变特征在彩色图像的分类识别中展示出优越的性能.%The color scaleinvariant feature transform (color SIFT) based feature extraction method is proposed, and the related invariance properties in translation, rotation, zooming, and color shifting are analyzed.Further, image classification strategy and algorithms based on this feature are studied. To test the proposed classification and recognition algorithms, 50 objects categories randomly chosen from the Amsterdam library of object images (ALOI) are employed for recognition, and results show that the correct rate of recognition is 100%. Both theoretical and experimental results validate that the color SIFT feature has a good performance in chromatic image classification and recognition.

  17. Analysis of second order harmonic distortion due to transmitter non-linearity and chromatic and modal dispersion of optical OFDM SSB modulated signals in SMF-MMF fiber links

    Science.gov (United States)

    Patel, Dhananjay; Singh, Vinay Kumar; Dalal, U. D.

    2017-01-01

    Single mode fibers (SMF) are typically used in Wide Area Networks (WAN), Metropolitan Area Networks (MAN) and also find applications in Radio over Fiber (RoF) architectures supporting data transmission in Fiber to the Home (FTTH), Remote Antenna Units (RAUs), in-building networks etc. Multi-mode fibers (MMFs) with low cost, ease of installation and low maintenance are predominantly (85-90%) deployed in-building networks providing data access in local area networks (LANs). The transmission of millimeter wave signals through the SMF in WAN and MAN, along with the reuse of MMF in-building networks will not levy fiber reinstallation cost. The transmission of the millimeter waves experiences signal impairments due to the transmitter non-linearity and modal dispersion of the MMF. The MMF exhibiting large modal dispersion limits the bandwidth-length product of the fiber. The second and higher-order harmonics present in the optical signal fall within the system bandwidth. This causes degradation in the received signal and an unwanted radiation of power at the RAU. The power of these harmonics is proportional to the non-linearity of the transmitter and the modal dispersion of the MMF and should be maintained below the standard values as per the international norms. In this paper, a mathematical model is developed for Second-order Harmonic Distortion (HD2) generated due to non-linearity of the transmitter and chromatic-modal dispersion of the SMF-MMF optic link. This is also verified using a software simulation. The model consists of a Mach Zehnder Modulator (MZM) that generates two m-QAM OFDM Single Sideband (SSB) signals based on phase shift of the hybrid coupler (90° and 120°). Our results show that the SSB signal with 120° hybrid coupler has suppresses the higher-order harmonics and makes the system more robust against the HD2 in the SMF-MMF optic link.

  18. Removing vanadium from sodium chromate neutral liquid by non­calcium roasting technology with chromium salt%铬盐无钙焙烧工艺铬酸钠中性液铁盐除钒

    Institute of Scientific and Technical Information of China (English)

    杨得军; 王少娜; 陈晓芳; 郑诗礼; 李世厚

    2014-01-01

    According to the current existing problem in the vanadium precipitating process in calcium salt by non­calcium roasting technology with chromium salt, such problems as large amount of calcium salt, repeatedly adjusting the pH value, slag containing calcium chromate and other issues, iron salts were used as precipitating agent to remove vanadium. The amount of iron salt added, pH value, temperature and other major factors on the impact of vanadium removal were investigated, the optimum conditions are that the vanadium concentration in final liquid is less than 0.08 g/L, which satisfies the follow­up process requirements. Utilizing iron salt to remove vanadium can be operated in wide pH range, without repeatedly adjusting the pH value. By analyzing, the slag phase is ferric hydroxide, which adsorbs vanadium, containing no chromium. And by further exploring against adsorption mechanism, vanadium is adsorbed on the surface of the iron hydroxide by inner layer complexation.%针对铬盐无钙焙烧工艺浸出液除钒现行钙盐沉钒法钙盐加入量大、需反复调节pH值、脱钒渣含铬酸钙等问题,提出采用铁盐作为沉钒剂进行除钒。考察铁盐加入量、pH 值和温度等主要因素对钒脱除的影响,得到了最佳工艺条件,且终液钒浓度低于0.08 g/L,满足后续工艺要求。铁盐除钒可在较宽的pH值范围内操作,不需反复调节溶液pH值。渣相分析表明:脱钒渣为吸附钒酸根的氢氧化铁,其中不含铬,进一步探讨氢氧化铁对钒的吸附机理,确定钒酸根通过内层络合方式吸附在氢氧化铁表面。

  19. Comparision on Determination of Sulfate in Drinking Water by Barium chromate spectrophotometry and Ion Chromatography%铬酸钡分光光度法与离子色谱法测定生活饮用水中硫酸盐的比较

    Institute of Scientific and Technical Information of China (English)

    卡林; 陈玉柱; 邱陆军; 丁长春

    2012-01-01

    为比较铬酸钡分光光度法与离子色谱法测定水中硫酸盐是否存在显著性差异,分别使用两种方法测定淮安市两个集中式生活饮用水水源地的地表水中的硫酸盐含量。其结果显示,两种方法的精密度、准确度和测定结果无显著性差异,均可作为测定生活饮用水中硫酸盐的方法。%To compare the Barium chromate spectrophotometry and Ion Chromatography method for determination of Sulfate,we collected 4 surface-water samples from 2 areas in drinking water of Huaian and detected he fluoride content.The results indicated that there not distinctive differences in the precision,accuracy and determination results of Barium chromate spectrophotometry and Ion Chromatography method.So Sulfate content in drinking water could be determined by the two method.

  20. Desenvolvimento e resultados preliminares de um sistema cromático de iluminação para oftalmoscópios indiretos Development and preliminary results of a chromatic illumination system for indirect ophthalmoscopes

    Directory of Open Access Journals (Sweden)

    Thiago Bellini Oliveira

    2009-04-01

    ção cromático, acreditamos que em uma próxima etapa possamos verificar as vantagens e/ou desvantagem desta técnica no diagnóstico de diferentes patologias da retina.PURPOSE: Chromatic contrast is a technique used in some areas of medicine to provide better visualization of biological tissues. Based on principles of color composition, a new illumination system was constructed using colored emitting diodes to reproduce the spectral range of visible light. This technique was devised to be used in indirect ophthalmoscopes to improve the visualization of the posterior segment of the eye. METHODS: The original illumination system of a general purpose indirect ophthalmoscope was substituted by a system of color-emitting diodes. RESULTS: Using an electronic interface it was possible to control the intensity of the color lights and therefore generate different wavelengths in the visible spectrum of the light. Preliminary tests undertaken in a mechanical model of the human eye generated very clear and homogenous colors. However in vivo examinations with patients were performed in our laboratory at the IFSC-USP and UNIFESP, and obtained the preliminary results show the possibilities of the chromatic contrast technique, and may represent in the future a differential in the analyses of the posterior segment of the eye. CONCLUSION: The use of color-emitting diodes to reproduce the spectral range of the visible light in indirect ophthalmoscopes seems to be a promising technological advance in the fundoscopy of the eye. This is an innovation that can yield better quality examinations with indirect ophthalmoscopes.