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Sample records for chromated copper arsenate-treated

  1. Oxalic acid as an assisting agent for the electrodialytic remediation of chromated copper arsenate treated timber waste

    DEFF Research Database (Denmark)

    Ribeiro, Alexandra B.; Mateus, Eduardo P.; Ottosen, Lisbeth M.

    1999-01-01

    The electrodialytic process is proposed as a technique for the remediation of chromated copper arsenate treated timber waste, using oxalic acid as assisting agent. The method prowed succesfull 93% Cu, 95% Cr and 99% As was removed from the timber.......The electrodialytic process is proposed as a technique for the remediation of chromated copper arsenate treated timber waste, using oxalic acid as assisting agent. The method prowed succesfull 93% Cu, 95% Cr and 99% As was removed from the timber....

  2. Oxalic acid as an assisting agent for the electrodialytic remediation of chromated copper arsenate treated timber waste

    DEFF Research Database (Denmark)

    Ribeiro, Alexandra B.; Mateus, Eduardo P.; Ottosen, Lisbeth M.

    1999-01-01

    The electrodialytic process is proposed as a technique for the remediation of chromated copper arsenate treated timber waste, using oxalic acid as assisting agent. The method prowed succesfull 93% Cu, 95% Cr and 99% As was removed from the timber.......The electrodialytic process is proposed as a technique for the remediation of chromated copper arsenate treated timber waste, using oxalic acid as assisting agent. The method prowed succesfull 93% Cu, 95% Cr and 99% As was removed from the timber....

  3. Chromated copper arsenate–treated wood: a potential source of arsenic exposure and toxicity in dermatology

    Directory of Open Access Journals (Sweden)

    Amy Yuntzu-Yen Chen, MD

    2016-03-01

    Full Text Available Arsenic-contaminated drinking water presents a serious health hazard in certain geographic locations around the world. Chromated copper arsenate, a pesticide and preservative that was used to pressure treat residential lumber in the United States beginning in the 1940s and was banned by the Environmental Protection Agency in 2003, poses a potential source of arsenic exposure and toxicity. In this study, we review the clinical manifestations of arsenic intoxication with the focus on dermatologic manifestations. Dermatologists should be aware that although chromated copper arsenate-treated wood for residential use was banned in 2003, the exposure risk remains. Long-term follow up is necessary to detect arsenic induced cutaneous and visceral malignancy in patients with history of arsenic exposure.

  4. Isolating metal-tolerant bacteria capable of removing copper, chromium, and arsenic from treated wood

    Science.gov (United States)

    Carol A. Clausen

    2000-01-01

    Bioremediation of chromated copper arsenate-treated waste wood with one or more metal-tolerant bacteria is a potential method of naturally releasing metals from treated wood fibre. Sampling eight environments with elevated levels of copper, chromium, and arsenic resulted in the isolation of 28 bacteria with the capability of releasing one or more of the components from...

  5. LEACHING MECHANISM OF CHROMATED COPPER ARSENATE (CCA WOOD PRESERVATIVE

    Directory of Open Access Journals (Sweden)

    Engin Derya Gezer

    2004-04-01

    Full Text Available In recent years, the increase demand on wooden raw materials and destroyed forest area (i.e clear cutting led to pressure on forest resources. Thus, Wood used in outdoor applications should be treated with preservatives to extent service life. in our country, although there is no regulations or any standards to be obeyed to preserve wood materials, averagely, 400.000 m3 /per year utility poles manufactured from softwood species and 30.000 m3/per year rail road slippers produced from either hardwood species or softwood species have been impregnated with wood preservatives. Chromated copper arsenic (CCA is commonly used wood preservatives to preserve utility poles in our country. According to data taken from Turkish Electricity Transmission Company (TEDAS 208.000 utility poles are used in Trabzon city area, 180.000 utility poles are in Rize city area, 121.000 utility poles are used in Artvin. Roughly 17.000 utility poles are replaced every year in three cities. Determining leaching factors of treated wood is important for explaining the short service life of utility poles treated with CCA used in Black Sea area. Factors such as preservative formulation, fixation temperature, post-treatment handling, wood dimensions, leaching media, pH, salinity and temperature have been shown to effect leaching of CCA treated wood.

  6. Effect of weathering on chromated copper arsenate (CCA) treated wood : leaching of metal salts and change in water repellency

    Science.gov (United States)

    R. Sam Williams; Stan Lebow; Patricia Lebow

    2003-01-01

    Wood pressure-treated with chromated copper arsenate (CCA) wood preservative is commonly used for outdoor construction. Oxides of arsenic, copper, and chromium are bound in the wood by a complex series of chemical reactions, but a small percentage of these compounds are gradually released by leaching and weathering. Recent studies suggest that the release of these...

  7. Rapid microwave-assisted acid extraction of southern pine waste wood to remove metals from chromated copper arsenate (CCA) treatment

    Science.gov (United States)

    Chung-Yun Hse; Todd F. Shupe; Bin Yu

    2013-01-01

    Recovery of metals from chromated copper arsenate (CCA)-treated southern pine wood particles was investigated by extraction in a microwave reactor with binary combinations of acetic acid (AA), oxalic acid (OxA), and phosphoric acid (PhA). Use of OxA was not successful, as insoluble copper oxalate complexes impeded copper removal. The combination of OxA and AA also had...

  8. Determination of chromated copper arsenate (CCA) in treated wood of Eucalyptus

    Energy Technology Data Exchange (ETDEWEB)

    Parreira, Paulo S., E-mail: parreira@uel.b [Universidade Estadual de Londrina (UEL), PR (Brazil). Dept. de Fisica. Lab.de Fisica Nuclear Aplicada; Vendrametto, Guilherme R.; Cunha, Magda E.T., E-mail: grvendrametto@gmail.co [Universidade Norte do Parana, Arapongas, PR (Brazil). Centro de Ciencias Humanas, da Saude, Exatas e Tecnologicas-A

    2009-07-01

    This work deals with the possible application of a portable energy dispersive handmade system (PXRF-LFNA-02) for the determination of Chromium, Copper and Arsenic in the preservative solution used to protect commercial wood of Eucalyptus, which are employed as wood fence, posts, contention fences, railroad sleepers, etc. It was prepared five body-of-proof made of eucalyptus alburnum with different concentrations for each element varying from 0.0061 to 0.0180 (g/g) for CrO{sub 3}, 0.0024 to 0.0070 (g/g) for CuO and 0.0044 to 0.0129 (g/g) for As{sub 2}O{sub 5}. Four of them were used for calibration curves and one used as reference sample. It was used a commercial CCA (Chromated Copper Arsenate ) solution to prepare the samples. The results show a good linear regression between concentrations and X-rays intensities, after applied the multiple linear regression methodology for interelemental corrections. The values obtained with this methodology were 3.01(kg/m{sup 3}), 1.18 (kg/m{sup 3}) e 2.21 (kg/m{sup 3}) for CrO{sub 3}, CuO and As{sub 2}O{sub 5}, respectively, while the nominal values are 2.90 (kg/m{sup 3}) for CrO{sub 3}, 1.13 (kg/m{sup 3}) for CuO and 2.07 (kg/m{sup 3}) for As{sub 2}O{sub 5}. The ED-XRF (Energy Dispersive X-Rays Fluorescence) is a well established technique with high-speed of analytical procedure and its portable configuration allowing a multielemental, simultaneous and non destructive analyses besides in situ application. (author)

  9. Arsenic and chromium partitioning in a podzolic soil contaminated by chromated copper arsenate

    Energy Technology Data Exchange (ETDEWEB)

    Nico, Peter; Hopp, Luisa; Nico, Peter S.; Marcus, Matthew A.; Peiffer, Stefan

    2008-06-01

    This research combined the use of selective extractions and x-ray spectroscopy to examine the fate of As and Cr in a podzolic soil contaminated by chromated copper arsenate (CCA). Iron was enriched in the upper 30 cm due to a previous one-time treatment of the soil with Fe(II). High oxalate-soluble Al concentrations in the Bs horizon of the soil and micro-XRD data indicated the presence of short-range ordered aluminosilicates (i.e. proto-imogolite allophane, PIA). In the surface layers, Cr, as Cr(III), was partitioned between a mixed Fe(III)/Cr(III) solid phase that formed upon the Fe(II) application (25-50%) and a recalcitrant phase (50-75%) likely consisting of organic material such as residual CCA-treated wood. Deeper in the profile Cr appeared to be largely in the form of extractable (hydr)oxides. Throughout the soil, As was present as As(V). In the surface layers a considerable fraction of As was also associated with a recalcitrant phase, probably CCA-treated woody debris, and the remainder was associated with (hydr)oxide-like solid phases. In the Bs horizon, however, XAS and XRF findings strongly pointed to the presence of PIA acting as an effective adsorbent for As. This research shows for the first time the relevance of PIA for the adsorption of As in natural soils.

  10. Effect of chromated copper arsenate structures on adjacent soil arsenic concentrations.

    Science.gov (United States)

    Patch, Steven C; Scheip, Katherine; Brooks, Billy

    2011-06-01

    Structures made of chromated copper arsenic (CCA) have been shown to leach arsenic into the surrounding soil. Soil cores were taken adjacent to six CCA decks at 0, 15, 60 and 300 cm from the deck at depths of 0-10, 10-20, and 20-30 cm, and were analyzed for soil arsenic concentrations. Median soil arsenic concentrations ranged from 1.8 μg/g at a depth of 10-20 cm and a distance of 300 cm to 34.5 μg/g at a depth of 0-10 cm and a distance of 30 cm. Soil arsenic concentrations taken at depths of 0-10 and 10-20 cm decreased as distance from the deck increased. Soil arsenic concentrations close to the deck were higher at lower soil depths and at homes with greater deck wipe arsenic concentrations. Age of deck and slope of land had significant effects on the differences in arsenic concentrations between samples taken at different distances when evaluated in models by themselves, but not in models adjusting for deck wipe concentrations. Size of deck and bulk density of soil did not have significant effects on soil arsenic concentrations.

  11. Soil pollution assessment and identification of hyperaccumulating plants in chromated copper arsenate (CCA) contaminated sites, Korea.

    Science.gov (United States)

    Usman, Adel R A; Lee, Sang Soo; Awad, Yasser M; Lim, Kyoung Jae; Yang, Jae E; Ok, Yong Sik

    2012-05-01

    In recent decades, heavy metal contamination in soil adjacent to chromated copper arsenate (CCA) treated wood has received increasing attention. This study was conducted to determine the pollution level (PL) based on the concentrations of Cr, Cu and As in soils and to evaluate the remediative capacity of native plant species grown in the CCA contaminated site, Gangwon Province, Korea. The pollution index (PI), integrated pollution index (IPI), bioaccumulation factors (BAF(shoots) and BAF(roots)) and translocation factor (TF) were determined to ensure soil contamination and phytoremediation availability. The 19 soil samples from 10 locations possibly contaminated with Cr, Cu and As were collected. The concentrations of Cr, Cu and As in the soil samples ranged from 50.56-94.13 mg kg(-1), 27.78-120.83 mg kg(-1), and 0.13-9.43 mg kg(-1), respectively. Generally, the metal concentrations decreased as the distance between the CCA-treated wood structure and sampling point increased. For investigating phytoremediative capacity, the 19 native plant species were also collected in the same area with soil samples. Our results showed that only one plant species of Iris ensata, which presented the highest accumulations of Cr (1120 mg kg(-1)) in its shoot, was identified as a hyperaccumulator. Moreover, the relatively higher values of BAF(shoot) (3.23-22.10) were observed for Typha orientalis, Iris ensata and Scirpus radicans Schk, suggesting that these plant species might be applicable for selective metal extraction from the soils. For phytostabilization, the 15 plant species with BAF(root) values>1 and TF values<1 were suitable; however, Typha orientalis was the best for Cr. Copyright © 2012 Elsevier Ltd. All rights reserved.

  12. Exergy analysis of the Chartherm process for energy valorization and material recuperation of chromated copper arsenate (CCA) treated wood waste.

    Science.gov (United States)

    Bosmans, A; Auweele, M Vanden; Govaerts, J; Helsen, L

    2011-04-01

    The Chartherm process (Thermya, Bordeaux, France) is a thermochemical conversion process to treat chromated copper arsenate (CCA) impregnated wood waste. The process aims at maximum energy valorization and material recuperation by combining the principles of low-temperature slow pyrolysis and distillation in a smart way. The main objective of the exergy analysis presented in this paper is to find the critical points in the Chartherm process where it is necessary to apply some measures in order to reduce exergy consumption and to make energy use more economic and efficient. It is found that the process efficiency can be increased with 2.3-4.2% by using the heat lost by the reactor, implementing a combined heat and power (CHP) system, or recuperating the waste heat from the exhaust gases to preheat the product gas. Furthermore, a comparison between the exergetic performances of a 'chartherisation' reactor and an idealized gasification reactor shows that both reactors destroy about the same amount of exergy (i.e. 3500kWkg(wood)(-1)) during thermochemical conversion of CCA-treated wood. However, the Chartherm process possesses additional capabilities with respect to arsenic and tar treatment, as well as the extra benefit of recuperating materials.

  13. Evaluation of the toxic effects of arsenite, chromate, cadmium, and copper using a battery of four bioassays

    Energy Technology Data Exchange (ETDEWEB)

    Ko, Kyung-Seok; Lee, Pyeong-Koo [Korea Institute of Geoscience and Mineral Resources (KIGAM), Daejeon (Korea, Republic of). Geologic Environment Div.; Kong, In Chul [Yeungnam Univ., Kyungbuk (Korea, Republic of). Dept. of Environmental Engineering

    2012-09-15

    The sensitivities of four different kinds of bioassays to the toxicities of arsenite, chromate, cadmium, and copper were compared. The different bioassays exhibited different sensitivities, i.e., they responded to different levels of toxicity of each of the different metals. However, with the exception of the {alpha}-glucosidase enzyme activity, arsenite was the most toxic compound towards all the tested organisms, exhibiting the highest toxic effect on the seeds of Lactuca, with an EC{sub 50} value of 0.63 mg/L. The sensitivities of Lactuca and Raphanus were greater than the sensitivities of two other kinds of seeds tested. Therefore, these were the seeds appropriate for use in a seed germination assay. A high revertant mutagenic ratio (5:1) of Salmonella typhimurium was observed with an arsenite concentration of 0.1 {mu}g/plate, indicative of a high possibility of mutagenicity. These different results suggested that a battery of bioassays, rather than one bioassay alone, is needed as a more accurate and better tool for the bioassessment of environmental pollutants. (orig.)

  14. Chromate (CrO(4)(2-)) and copper (Cu2+) adsorption by dual-functional ion exchange resins made from agricultural by-products.

    Science.gov (United States)

    Marshall, Wayne E; Wartelle, Lynda H

    2006-07-01

    Ion exchange resins commonly have a single functionality for either cations or anions. Resins that have a dual functionality for both cations and anions are uncommon. The objective of this study was to create dual-functional ion exchange resins derived from soybean hulls, sugarcane bagasse and corn stover. Dual-functional resins were prepared by two separate two-step processes. In the first two-step process, by-products were reacted with a solution of citric acid in order to impart additional negative charge, and then reacted with the cross-linking reagent dimethyloldihydroxyethylene urea (DMDHEU) and a quaternary amine (choline chloride) to add positive charge to the lignocellulosic material. In the second two-step process, the order of reaction was reversed, with positive charge added first, followed by the addition of negative charge. These combined reactions added both cationic and anionic character to the by-products as evidenced by the increased removal from solution of copper (Cu(2+)) cation and the chromate (CrO(4)(2-)) anion compared to unmodified by-products. The order of reaction appeared to slightly favor the functionality that was added last. That is, if negative charge was added last, the resulting resin sequestered more copper ion than a comparable resin where the negative charge was added first and vice-versa. Cu(2+) and CrO(4)(2-) were used as marker ions in a solution that contained both competing cations and anions. The dual-functional resins adsorbed as much as or more of the marker ions compared to commercial cation or anion exchange resins used for comparison. None of the commercial resins exhibited dual-functional properties to the same extent as the by-product-based resins.

  15. Fractionation of heavy metals in liquefied chromated copper arsenate 9-treated wood sludge using a modified BCR-sequential extraction procedure.

    Science.gov (United States)

    Pan, Hui; Hse, Chung-Yun; Gambrell, Robert; Shupe, Todd F

    2009-09-01

    Chromated copper arsenate (CCA)-treated wood was liquefied with polyethylene glycol/glycerin and sulfuric acid. After liquefaction, most CCA metals (98% As, 92% Cr, and 83% Cu) were removed from liquefied CCA-treated wood by precipitation with calcium hydroxide. The original CCA-treated wood and liquefied CCA-treated wood sludge were fractionated by a modified Community Bureau of Reference (BCR) sequential extraction procedure. The purpose of the BCR-sequential extraction used in this study was to examine the availability of CCA metals in treated wood for reuse. Both As and Cr had a slightly higher concentration in the sludge sample than in original CCA-treated wood. The sequential extraction showed that As and Cr were principally existed in an oxidizable fraction (As, 67%; Cr, 88%) in original CCA-treated wood. Only 1% of both As and Cr were extracted by hot nitric acid with the last extraction step. The distribution of As and Cr changed markedly in liquefied CCA-treated wood sludge. The amount of As in the exchangeable/acid extractable fraction increased from 16% to 85% while the amount of Cr increased from 3% to 54%. Only about 3% of As was present in the oxidizable fraction. However, there was still about 34% of Cr in the same fraction. Based on these results from sequential extraction procedures, it can be concluded that the accessibilities of CCA metals increase markedly by the liquefaction-precipitation process.

  16. The Colors and Chromatic Charts of Gold -Silver -Copper Carat Alloys%Au-Ag-Cu系开金合金的颜色与色度图

    Institute of Scientific and Technical Information of China (English)

    宁远涛

    2012-01-01

    颜色和色度坐标是珠宝饰品设计与制造的重要因素与参数.Au- Ag-Cu系合金是最重要的颜色开金饰品合金.文章评述了Ag、Cu对Au和Au基合金的光反射率和颜色的影响;介绍了Au- Ag-Cu系合金的色度图、金合金色泽标准及某些标准颜色合金成分;讨论了某些合金化元素对Au- Ag-Cu系合金颜色的影响.通过调整Ag、Cu组元含量比例和添加其它合金化元素,Au-Ag - Cu系开金合金可以获得丰富多彩的颜色,对于设计与控制珠宝饰品的颜色有重要意义.%Au - Ag - Cu system alloys are the most important color jewelry alloys. The colors of Au - Ag - Cu alloys depend on the composition and the content of the alloying components. The influences of Ag and Cu components on the reflectivity and color of gold and gold - based alloys were reviewed. The chromatic charts of gold - silver - copper carat alloys, color standard of carat alloys and the compositions of some standard color gold alloys were introduced. The effects of some other alloying elements on the color of gold alloys were also discussed. Au - Ag - Cu carat alloys can develop rich and varied colors through regulating the ratio of the contents of Ag and Cu in alloys and adding other alloying elements, which is the basis for designing and controlling colors of carat alloys based on gold.

  17. Classification of waste wood treated with chromated copper arsenate and boron/fluorine preservatives; Classificacao de residuos de madeira tratada com preservativos a base de arseniato de cobre cromatado e de boro/fluor

    Energy Technology Data Exchange (ETDEWEB)

    Ferrarini, Suzana Frighetto; Santos, Heldiane Souza dos; Miranda, Luciana Gampert; Azevedo, Carla M.N.; Pires, Marcal J.R., E-mail: suzana.ferrarini@gmail.com [Faculdade de Quimica, Pontificia Universidade Catolica do Rio Grande do Sul, Porto Alegre, RS (Brazil); Maia, Sandra Maria [Instituto de Quimica, Universidade Federal do Rio Grande do Sul, Porto Alegre, RS (Brazil)

    2012-07-01

    Classification of waste wood treated with chromated copper arsenate (CCA) and boron/fluorine preservatives, according to NBR 10004, was investigated. The leaching test (ABNT NBR 10005) for As and Cr, and solubilization test (ABNT NBR 10006) for F, were applied to out-of-service wooden poles. Concentrations of As and Cr in leachates were determined by ICP-MS and of F by ESI. Values for As were higher than 1 mg L{sup -1} classifying the waste as hazardous material (Class I) whereas values for F (> 1.5 mg L{sup -1}) were non-hazardous but indicated non-inert material (Class IIA). (author)

  18. Low chromate diet in dermatology

    Directory of Open Access Journals (Sweden)

    Sharma Ashimav

    2009-01-01

    Full Text Available Chromium is an essential trace element found in soil, water, air, and in the biosphere. It is the fourth most common element in the earth′s crust, mostly used to manufacture stainless steel and other alloys. Chromate allergy is not uncommon and its prevalence rate is reported to be 6%. Once developed, it tends to persist for a long time. Chromate is present in most of the dietary items. Chromate content in food often varies considerably from place to place. However, certain foods are routinely high in chromate content. Chromate in the diet of a chromate-sensitive person can provoke dermatitis. Careful selection of food with relatively low chromate concentration can bring a reduction in the total dietary intake of chromate per day. This can influence outcome of the disease, especially chronic vesicular hand eczema due to chromate sensitivity, and can benefit a chromate-sensitive patient.

  19. Comparative study of Nd:YAG laser-induced breakdown spectroscopy and transversely excited atmospheric CO2 laser-induced gas plasma spectroscopy on chromated copper arsenate preservative-treated wood.

    Science.gov (United States)

    Khumaeni, Ali; Lie, Zener Sukra; Niki, Hideaki; Lee, Yong Inn; Kurihara, Kazuyoshi; Wakasugi, Motoomi; Takahashi, Touru; Kagawa, Kiichiro

    2012-03-01

    Taking advantage of the specific characteristics of a transversely excited atmospheric (TEA) CO(2) laser, a sophisticated technique for the analysis of chromated copper arsenate (CCA) in wood samples has been developed. In this study, a CCA-treated wood sample with a dimension of 20 mm × 20 mm and a thickness of 2 mm was attached in contact to a nickel plate (20 mm × 20 mm × 0.15 mm), which functions as a subtarget. When the TEA CO(2) laser was successively irradiated onto the wood surface, a hole with a diameter of approximately 2.5 mm was produced inside the sample and the laser beam was directly impinged onto the metal subtarget. Strong and stable gas plasma with a very large diameter of approximately 10 mm was induced once the laser beam had directly struck the metal subtarget. This gas plasma then interacted with the fine particles of the sample inside the hole and finally the particles were effectively dissociated and excited in the gas plasma region. By using this technique, high precision and sensitive analysis of CCA-treated wood sample was realized. A linear calibration curve of Cr was successfully made using the CCA-treated wood sample. The detection limits of Cr, Cu, and As were estimated to be approximately 1, 2, and 15 mg/kg, respectively. In the case of standard LIBS using the Nd:YAG laser, the analytical intensities fluctuate and the detection limit was much lower at approximately one-tenth that of TEA CO(2) laser. © 2012 Optical Society of America

  20. Chromatic polynomials for simplicial complexes

    DEFF Research Database (Denmark)

    Møller, Jesper Michael; Nord, Gesche

    2016-01-01

    In this note we consider s s -chromatic polynomials for finite simplicial complexes. When s=1 s=1 , the 1 1 -chromatic polynomial is just the usual graph chromatic polynomial of the 1 1 -skeleton. In general, the s s -chromatic polynomial depends on the s s -skeleton and its value at r r is the n...

  1. Cleaning of Chromate Manufacture Process

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Sodium chromate solubility is determined in the range of NaOH concentrations from 450 to 810 g/L and solution temperatures from 30 to 110 ℃. The optimized conditions to separate sodium chromate from NaOH in leached solution are resolved. It is first found the method to efficiently separate sodium chromate from NaOH and sodium aluminate in crude sodium chromate. Bench-scale studies on the separating are performed. Finally, good separation results are achieved.

  2. Chromatic functors of graphs

    OpenAIRE

    Yoshinaga, Masahiko

    2015-01-01

    Finite graphs that have a common chromatic polynomial have the same number of regular $n$-colorings. A natural question is whether there exists a natural bijection between regular $n$-colorings. We address this question using a functorial formulation. Let $G$ be a simple graph. Then for each set $X$ we can associate a set of $X$-colorings. This defines a functor, "chromatic functor" from the category of sets with injections to itself. The first main result verifies that two finite graphs dete...

  3. Chromatic analysis and possible local chromatic correction in RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Y.; Fischer, W.; Gu, X.; Trbojevic, D.

    2011-03-28

    In this article we will answer the following questions for the RHIC polarized proton (p-p) and Au-Au run lattices: (1) what are the sources of second order chromaticities? (2) what is the dependence of second order chromaticity on the on-momentum {beta}-beat? (3) what is the dependence of second order chromaticity on {beta}* at IP6 and IP8? To answer these questions, we use the perturbation theory to numerically calculate the contributions of each quadrupole and sextupole to the first, second, and third order chromaticities. Possible local methods to reduce chromatic effects in RHIC ring are shortly discussed.

  4. Effect of post-treatment processing on copper migration from Douglas-fir lumber treated with ammoniacal copper zinc arsenate.

    Science.gov (United States)

    Ye, Min; Morrell, Jeffrey J

    2015-04-01

    Migration of heavy metals into aquatic environments has become a concern in some regions of the world. Many wood preservatives are copper based systems that have the potential to migrate from the wood and into the surrounding environment. Some wood treaters have developed "best management practices" (BMPs) that are designed to reduce the risk of migration, but there are few comparative studies assessing the efficacy of these processes. The potential for using various heating combinations to limit copper migration was assessed using ammoniacal coper zinc arsenate treated Douglas-fir lumber. Kiln drying and air drying both proved to be the most effective methods for limiting copper migration, while post-treatment steaming or hot water immersion produced more variable results. The results should provide guidance for improving the BMP processes.

  5. Roots of the Chromatic Polynomial

    DEFF Research Database (Denmark)

    Perrett, Thomas

    a tight lower bound on the smallest non-trivial chromatic root of a graph admitting a spanning tree with at most three leaves. Here, non-trivial means different from 0 or 1. This extends a theorem of Thomassen on graphs with Hamiltonian paths. We also prove similar lower bounds on the chromatic roots...... of several graph families. In particular, we show that the chromatic roots of planar graphs are dense in the interval (3; 4), except for a small interval around _ + 2 _ 3:618, where _ denotes the golden ratio. We also investigate the chromatic roots of related minor-closed classes of graphs and bipartite...

  6. Poisoned Playgrounds: Arsenic in "Pressure-Treated" Wood.

    Science.gov (United States)

    Sharp, Renee; Walker, Bill

    This study of 180 pressure-treated wood samples shows that treated wood is a much greater source of arsenic exposure for children than arsenic-contaminated drinking water. The report determines that an average 5-year-old, playing less than 2 weeks on a chromated-copper-arsenate-treated (CCA) wood play set would exceed the lifetime cancer risk…

  7. Electrodialytic remediation of CCA treated waste wood in pilot scale

    DEFF Research Database (Denmark)

    Pedersen, Anne Juul; Christensen, Iben Vernegren; Ottosen, Lisbeth M.

    2005-01-01

    When CCA (Chromated Copper Arsenate) treated wood is removed from service and turns into waste, the contents of Cu, Cr and As is still high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA treated waste wood is ...

  8. Camera processing with chromatic aberration.

    Science.gov (United States)

    Korneliussen, Jan Tore; Hirakawa, Keigo

    2014-10-01

    Since the refractive index of materials commonly used for lens depends on the wavelengths of light, practical camera optics fail to converge light to a single point on an image plane. Known as chromatic aberration, this phenomenon distorts image details by introducing magnification error, defocus blur, and color fringes. Though achromatic and apochromatic lens designs reduce chromatic aberration to a degree, they are complex and expensive and they do not offer a perfect correction. In this paper, we propose a new postcapture processing scheme designed to overcome these problems computationally. Specifically, the proposed solution is comprised of chromatic aberration-tolerant demosaicking algorithm and post-demosaicking chromatic aberration correction. Experiments with simulated and real sensor data verify that the chromatic aberration is effectively corrected.

  9. Pupillary responses to chromatic stimulus

    Science.gov (United States)

    Suaste-Gomez, Ernesto; Rodriguez Guzman, M. C. Ma. Dolores A.; Druzgalski, Christopher

    2000-06-01

    Pupillary responses of the subjects under chromatic visual stimulation were filmed with video-oculography systems (VOG). Specifically, programmable chromatic visual stimuli were displayed on the monitor of a personal computer (PC) and responses tested in several normal subjects and those with ophthalmic pathologic conditions. Visual excitation utilized a reversal stimulus checkerboard pattern. Image processing techniques were applied in order to evaluate the pupil variations due to chromatic stimulation. In particular, the studies determined a relationship between pupillary response (PR) and steady-state retinal sensitivity (photopic vision). Finally, the retinal illuminance in trolands (td), as a product of the pupil area in mm2 and luminance in cd/m2 to full-field chromatic stimulation (FFCS) and checkerboard pattern reversal chromatic stimulation (CPRCS) was determined.

  10. Chromatic polynomials of random graphs

    Science.gov (United States)

    Van Bussel, Frank; Ehrlich, Christoph; Fliegner, Denny; Stolzenberg, Sebastian; Timme, Marc

    2010-04-01

    Chromatic polynomials and related graph invariants are central objects in both graph theory and statistical physics. Computational difficulties, however, have so far restricted studies of such polynomials to graphs that were either very small, very sparse or highly structured. Recent algorithmic advances (Timme et al 2009 New J. Phys. 11 023001) now make it possible to compute chromatic polynomials for moderately sized graphs of arbitrary structure and number of edges. Here we present chromatic polynomials of ensembles of random graphs with up to 30 vertices, over the entire range of edge density. We specifically focus on the locations of the zeros of the polynomial in the complex plane. The results indicate that the chromatic zeros of random graphs have a very consistent layout. In particular, the crossing point, the point at which the chromatic zeros with non-zero imaginary part approach the real axis, scales linearly with the average degree over most of the density range. While the scaling laws obtained are purely empirical, if they continue to hold in general there are significant implications: the crossing points of chromatic zeros in the thermodynamic limit separate systems with zero ground state entropy from systems with positive ground state entropy, the latter an exception to the third law of thermodynamics.

  11. Optimizing Chromatic Coupling Measurement in the LHC

    CERN Document Server

    Persson, Tobias

    2016-01-01

    Optimizing chromatic coupling measurement in the LHC Chromatic coupling introduces a dependency of transverse coupling with energy. LHC is equipped with skew sextupoles to compensate the possible adverse effects of chromatic coupling. In 2012 a beam-based correction was calculated and applied successfully for the fist time. However, the method used to reconstruct the chromatic coupling was dependent on stable tunes and equal chromaticities between the horizontal and vertical planes. In this article an improved method to calculate the chromatic coupling without these constraints is presented.

  12. Binocular measurements of chromatic adaptation.

    Science.gov (United States)

    Troost, J M; Wei, L; de Weert, C M

    1992-10-01

    In this paper we present asymmetric matching data that were obtained with a binocular presentation method. Our main motivation was the question whether chromatic adaptation, one of the important mechanisms that contribute to colour constancy, has evolved towards a better performance in the range of colours that are present in the natural image. For the eye adapted to a bluish illuminant for example the presence of an object with a deep yellow colour is very unlikely. So, it was expected that the colour difference between adapting light and target has an influence on the extent of chromatic adaptation. It was found that the colour shift in the observers' matches that can be attributed to chromatic adaptation indeed has a maximum. The location of the maximum, however, was unexpected, i.e. colour differences between target and adapting light that lie around 0.05 u'v'-chromaticity units. Additionally, several models for chromatic adaptation were fitted to our data. It was found that, except for the simple von Kries model, Retinex Theory and difference contrast, a number of models gave good predictions for the L-wave and M-wave fundamental systems, but that predictions for the S-wave system were less accurate.

  13. Comparison of CIE chromaticity values

    CSIR Research Space (South Africa)

    Van Tonder, N

    1999-02-02

    Full Text Available grey 0.4490 0.4097 Deep pink 0.5569 0.3579 Red 0.6606 0.3259 Orange 0.5881 0.3933 Bright yellow 0.5238 0.4530 Green 0.3785 0.4779 Difference green 0.3846 0.4826 Cyan 0.2929 0.3650 Deep blue 0.2906 0.2282 Table 2 The CSIR/NML x and y CIE chromaticity....4831 Green 0.2703 0.4071 Difference green 0.2776 0.4195 Cyan 0.1965 0.2261 Deep blue 0.1929 0.1082 Table 3 The CSIR/NML x and y CIE chromaticity values for illuminant D65 and 28 observer Chromaticity values xy Pale grey 0.3129 0.3304 Mid grey 0.3120 0...

  14. Source of second order chromaticity in RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Y.; Gu, X.; Fischer, W.; Trbojevic, D.

    2011-01-01

    In this note we will answer the following questions: (1) what is the source of second order chromaticities in RHIC? (2) what is the dependence of second order chromaticity on the on-momentum {beta}-beat? (3) what is the dependence of second order chromaticity on {beta}* at IP6 and IP8? To answer these questions, we use the perturbation theory to numerically calculate the contributions of each quadrupole and sextupole to the first, second, and third order chromaticities.

  15. Chromatic roots and hamiltonian paths

    DEFF Research Database (Denmark)

    Thomassen, Carsten

    2000-01-01

    We present a new connection between colorings and hamiltonian paths: If the chromatic polynomial of a graph has a noninteger root less than or equal to t(n) = 2/3 + 1/3 (3)root (26 + 6 root (33)) + 1/3 (3)root (26 - 6 root (33)) = 1.29559.... then the graph has no hamiltonian path. This result...

  16. Performance of copper-based wood preservatives in soil bed exposures

    Science.gov (United States)

    Stan T. Lebow; Thomas Nilsson; Jeffrey J. Morrell

    Copper-based biocides are widely used to protect wood from biological attack in a variety of environments. Chromated copper arsenate (CCA) is the dominant copper-based preservative for wood protection (J. T. MICKLEWRIGHT, 1989). First developed in India in the 1930s, CCA contains a very effective combination of materials. Copper provides protection against most...

  17. Bacterial chromate reduction and product characterization

    Energy Technology Data Exchange (ETDEWEB)

    Mehlhorn, R.J. [Lawrence Berkeley Lab., CA (United States); Buchanan, B.B.; Leighton, T. [California Univ., Berkeley, CA (United States)

    1992-11-01

    Bacillus subtilis reduced hexavalent chromate to trivalent chromium under either aerobic or anaerobic conditions. Reduction of CR(VI) and appearance of extracellular Cr(III) were demonstrated by electron spin resonance and spectrophotometry. Chromate reduction was stimulated more than five-fold by freeze-thawing, indicating that intracellular reductases or chemical reductants reduce chromate more rapidly than do intact cells. Moderately concentrated cells (10% pellet volume after centrifugation) reduced approximately 40 {mu}M chromate/min (2 mg Cr/1-min) when exposed to 100 {mu}M chromate (5 mg Cr/1). Highly concentrated cells (70% pellet volume) reduced more than 99.8% of 2 mM chromate (100 mg Cr/1) within 15 min. This rate of chromate reduction was of the same order of magnitude as the rate of respiration in aerobic cells. A substantial fraction of the reduction product (ca. 75%) was extracellular Cr(M), which could readily be separated from the cells by centrifugation. At high chromate concentrations, some fraction of reduced CR(VI) appeared to be taken up by cells, consistent with a detection of intracellular paramagnetic products. At low chromate concentrations, undefined growth medium alone reduced Cr(VI), but at a slow rate, relative to cells. Under appropriate conditions, B. subtilis appears to be an organism of choice for detoxifying chromate-contaminated soil and water.

  18. Non-Chromate Aluminum Pretreatments

    Science.gov (United States)

    2012-03-01

    chromated areas of the two tail-only demonstrations was Turco AccelagoldTM. All aircraft were deoxidized using Turco 3003 TWATM. All test aircraft...was washed with Turco 5948RTM mildly alkaline cleaner, and then deoxidized with Turco 3003 TWA. During both of these cycles, white Scotch BrightTM...cleaner. ( Turco 4215 NC LTTM – 120 F) Solution was scrubbed lightly onto the components with Scotch-Brite pads. Figure 5.5 shows the cleaning of a

  19. Chromatic Properties of the Pancake Graphs

    Directory of Open Access Journals (Sweden)

    Konstantinova Elena

    2017-08-01

    Full Text Available Chromatic properties of the Pancake graphs Pn, n ⩾ 2, that are Cayley graphs on the symmetric group Symn generated by prefix-reversals are investigated in the paper. It is proved that for any n ⩾ 3 the total chromatic number of Pn is n, and it is shown that the chromatic index of Pn is n − 1. We present upper bounds on the chromatic number of the Pancake graphs Pn, which improve Brooks’ bound for n ⩾ 7 and Katlin’s bound for n ⩽ 28. Algorithms of a total n-coloring and a proper (n − 1-coloring are given.

  20. Chromate reduction by rabbit liver aldehyde oxidase

    Energy Technology Data Exchange (ETDEWEB)

    Banks, R.B.; Cooke, R.T. Jr.

    1986-05-29

    Chromate was reduced during the oxidation of 1-methylnicotinamide chlorine by partially purified rabbit liver aldehyde oxidase. In addition to l-methylnicotinamide, several other electron donor substrates for aldehyde oxidase were able to support the enzymatic chromate reduction. The reduction required the presence of both enzyme and the electron donor substrate. The rate of the chromate reduction was retarded by inhibitors or aldehyde oxidase but was not affected by substrates or inhibitors of xanthine oxidase. These results are consistent with the involvement of aldehyde oxidase in the reduction of chromate by rabbit liver cytosolic enzyme preparations.

  1. Atom lens without chromatic aberrations

    CERN Document Server

    Efremov, Maxim A; Schleich, Wolfgang P

    2012-01-01

    We propose a lens for atoms with reduced chromatic aberrations and calculate its focal length and spot size. In our scheme a two-level atom interacts with a near-resonant standing light wave formed by two running waves of slightly different wave vectors, and a far-detuned running wave propagating perpendicular to the standing wave. We show that within the Raman-Nath approximation and for an adiabatically slow atom-light interaction, the phase acquired by the atom is independent of the incident atomic velocity.

  2. Chromatic Polynomials of Mixed Hypercycles

    Directory of Open Access Journals (Sweden)

    Allagan Julian A.

    2014-08-01

    Full Text Available We color the vertices of each of the edges of a C-hypergraph (or cohypergraph in such a way that at least two vertices receive the same color and in every proper coloring of a B-hypergraph (or bihypergraph, we forbid the cases when the vertices of any of its edges are colored with the same color (monochromatic or when they are all colored with distinct colors (rainbow. In this paper, we determined explicit formulae for the chromatic polynomials of C-hypercycles and B-hypercycles

  3. Connections between the matching and chromatic polynomials

    Directory of Open Access Journals (Sweden)

    E. J. Farrell

    1992-01-01

    Full Text Available The main results established are (i a connection between the matching and chromatic polynomials and (ii a formula for the matching polynomial of a general complement of a subgraph of a graph. Some deductions on matching and chromatic equivalence and uniqueness are made.

  4. On chromatic and flow polynomial unique graphs

    National Research Council Canada - National Science Library

    Duan, Yinghua; Wu, Haidong; Yu, Qinglin

    2008-01-01

    ... research on graphs uniquely determined by their chromatic polynomials and more recently on their Tutte polynomials, but rather spotty research on graphs uniquely determined by their flow polynomials or the combination of both chromatic and flow polynomials. This article is an initiation of investigation on graphs uniquely determin...

  5. CIRCULAR CHROMATIC NUMBER AND MYCIELSKI GRAPHS

    Institute of Scientific and Technical Information of China (English)

    Liu Hongmei

    2006-01-01

    For a general graph G, M(G) denotes its Mycielski graph. This article gives a number of new sufficient conditions for G to have the circular chromatic number xc (M(G))equals to the chromatic number x(M(G)), which have improved some best sufficient conditions published up to date.

  6. On chromatic and geometrical calibration

    DEFF Research Database (Denmark)

    Folm-Hansen, Jørgen

    1999-01-01

    of non-uniformity of the illumination of the image plane. Only the image deforming aberrations and the non-uniformity of illumination are included in the calibration models. The topics of the pinhole camera model and the extension to the Direct Linear Transform (DLT) are described. It is shown how......The main subject of the present thesis is different methods for the geometrical and chromatic calibration of cameras in various environments. For the monochromatic issues of the calibration we present the acquisition of monochrome images, the classic monochrome aberrations and the various sources...... the DLT can be extended with non-linear models of the common lens aberrations/errors some of them caused by manufacturing defects like decentering and thin prism distortion. The relation between a warping and the non-linear defects are shown. The issue of making a good resampling of an image by using...

  7. Chromatic aberration measurement for transmission interferometric testing.

    Science.gov (United States)

    Seong, Kibyung; Greivenkamp, John E

    2008-12-10

    A method of chromatic aberration measurement is described based on the transmitted wavefront of an optical element obtained from a Mach-Zehnder interferometer. The chromatic aberration is derived from transmitted wavefronts measured at five different wavelengths. Reverse ray tracing is used to remove induced aberrations associated with the interferometer from the measurement. In the interferometer, the wavefront transmitted through the sample is tested against a plano reference, allowing for the absolute determination of the wavefront radius of curvature. The chromatic aberrations of a singlet and a doublet have been measured.

  8. Chromatic polynomials, Potts models and all that

    Science.gov (United States)

    Sokal, Alan D.

    2000-04-01

    The q-state Potts model can be defined on an arbitrary finite graph, and its partition function encodes much important information about that graph, including its chromatic polynomial, flow polynomial and reliability polynomial. The complex zeros of the Potts partition function are of interest both to statistical mechanicians and to combinatorists. I give a pedagogical introduction to all these problems, and then sketch two recent results: (a) Construction of a countable family of planar graphs whose chromatic zeros are dense in the whole complex q-plane except possibly for the disc | q-1|chromatic polynomial (or antiferromagnetic Potts-model partition function) in terms of the graph's maximum degree.

  9. Measurement of chromatic X-Y coupling

    Science.gov (United States)

    Ohnishi, Y.; Ohmi, K.; Koiso, H.; Masuzawa, M.; Morita, A.; Mori, K.; Oide, K.; Seimiya, Y.; Zhou, D.

    2009-09-01

    We have measured and corrected chromatic X-Y coupling at an interaction point to improve the luminosity of KEKB. We have measured the beam position of betatron oscillations induced by the kicker using turn-by-turn beam position monitors. A phase space structure reconstructed by the beam position provides us not only the Twiss parameters but also information regarding X-Y coupling. We have also determined chromatic X-Y coupling using the measured X-Y coupling at each momentum deviation from the designed beam energy. Skew sextupole magnets are used to correct the chromatic X-Y coupling.

  10. Chromate conversion coatings and their current application

    Directory of Open Access Journals (Sweden)

    P. Pokorny

    2016-04-01

    Full Text Available This paper describes formation, composition and possible production technologies of application chromate coatings. Summation of common examples of applications of these coatings in corrosion protection of metals and alloys is provided. Individual chromate coatings are divided by their dominant anions either with CrVI or CrIII. Restrictions of chromate coatings with dominantly CrVI and related toxicity of hexavalent chromium is discussed in detail. In conclusion, examples of both chromium and other, alternative coatings are summed up. Application of these coatings as a protection for concrete hot-dip galvanized reinforcement is also reviewed.

  11. On topological relaxations of chromatic conjectures

    CERN Document Server

    Simonyi, Gábor

    2010-01-01

    There are several famous unsolved conjectures about the chromatic number that were relaxed and already proven to hold for the fractional chromatic number. We discuss similar relaxations for the topological lower bound(s) of the chromatic number. In particular, we prove that such a relaxed version is true for the Behzad-Vizing conjecture and also discuss the conjectures of Hedetniemi and of Hadwiger from this point of view. For the latter, a similar statement was already proven in an earlier paper of the first author with G. Tardos, our main concern here is that the so-called odd Hadwiger conjecture looks much more difficult in this respect. We prove that the statement of the odd Hadwiger conjecture holds for large enough Kneser graphs and Schrijver graphs of any fixed chromatic number.

  12. Diffractive elements performance in chromatic confocal microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Garzon, J; Duque, D; Alean, A; Toledo, M [Grupo de Optica y EspectroscopIa, Centro de Ciencia Basica, Universidad Pontificia Bolivariana. Medellin (Colombia); Meneses, J [Laboratorio de Optica y Tratamiento de Senales, Instituto de Fisica, Universidad Industrial de Santander, Bucaramanga (Colombia); Gharbi, T, E-mail: jgarzonr10@une.net.co [Laboratoire d' Optique P. M. Duffieux, UMR-6603 CNR/Universite de Franche-Comte. 16 route de Gray, 25030 Besancon Cedex (France)

    2011-01-01

    The Confocal Laser Scanning Microscopy (CLSM) has been widely used in the semiconductor industry and biomedicine because of its depth discrimination capability. Subsequent to this technique has been developed in recent years Chromatic Confocal Microscopy. This method retains the same principle of confocal and offers the added advantage of removing the axial movement of the moving system. This advantage is usually accomplished with an optical element that generates a longitudinal chromatic aberration and a coding system that relates the axial position of each point of the sample with the wavelength that is focused on each. The present paper shows the performance of compact chromatic confocal microscope when some different diffractive elements are used for generation of longitudinal chromatic aberration. Diffractive elements, according to the process and manufacturing parameters, may have different diffraction efficiency and focus a specific wavelength in a specific focal position. The performance assessment is carried out with various light sources which exhibit an incoherent behaviour and a broad spectral width.

  13. Chromatic Dispersion Estimation in Digital Coherent Receivers

    DEFF Research Database (Denmark)

    Soriano, Ruben Andres; Hauske, Fabian N.; Guerrero Gonzalez, Neil

    2011-01-01

    Polarization-diverse coherent demodulation allows to compensate large values of accumulated linear distortion by digital signal processing. In particular, in uncompensated links without optical dispersion compensation, the parameter of the residual chromatic dispersion (CD) is vital to set...

  14. Chromatic effects in long periodic transport channels

    Energy Technology Data Exchange (ETDEWEB)

    Litvinenko V. N.; Hao, Y.; Jing, Y.

    2015-05-03

    Long periodic transport channels are frequently used in accelerator complexes and suggested for using in high-energy ERLs for electron-hadron colliders. Without proper chromaticity compensation, such transport channels exhibit high sensitivity to the random orbit errors causing significant emittance growth. Such emittance growth can come from both the correlated and the uncorrelated energy spread. In this paper we present results of our theoretical and numerical studies of such effects and develop a criteria for acceptable chromaticity in such channels.

  15. Toward a unified chromatic induction model.

    Science.gov (United States)

    Otazu, Xavier; Parraga, C Alejandro; Vanrell, Maria

    2010-10-01

    In a previous work (X. Otazu, M. Vanrell, & C. A. Párraga, 2008b), we showed how several brightness induction effects can be predicted using a simple multiresolution wavelet model (BIWaM). Here we present a new model for chromatic induction processes (termed Chromatic Induction Wavelet Model or CIWaM), which is also implemented on a multiresolution framework and based on similar assumptions related to the spatial frequency and the contrast surround energy of the stimulus. The CIWaM can be interpreted as a very simple extension of the BIWaM to the chromatic channels, which in our case are defined in the MacLeod-Boynton (lsY) color space. This new model allows us to unify both chromatic assimilation and chromatic contrast effects in a single mathematical formulation. The predictions of the CIWaM were tested by means of several color and brightness induction experiments, which showed an acceptable agreement between model predictions and psychophysical data.

  16. Release of copper-amended particles from micronized copper-pressure-treated wood during mechanical abrasion

    OpenAIRE

    Civardi, Chiara; Schlagenhauf, Lukas; Kaiser, Jean-Pierre; Hirsch, Cordula; Mucchino, Claudio; Wichser, Adrian; Wick, Peter; Schwarze, Francis W. M. R.

    2016-01-01

    Background We investigated the particles released due to abrasion of wood surfaces pressure-treated with micronized copper azole (MCA) wood preservative and we gathered preliminary data on its in vitro cytotoxicity for lung cells. The data were compared with particles released after abrasion of untreated, water (0% MCA)-pressure-treated, chromated copper (CC)-pressure-treated wood, and varnished wood. Size, morphology, and composition of the released particles were analyzed. Results Our resul...

  17. Two results on the digraph chromatic number

    CERN Document Server

    Harutyunyan, Ararat

    2011-01-01

    It is known (Bollob\\'{a}s (1978); Kostochka and Mazurova (1977)) that there exist graphs of maximum degree $\\Delta$ and of arbitrarily large girth whose chromatic number is at least $c \\Delta / \\log \\Delta$. We show an analogous result for digraphs where the chromatic number of a digraph $D$ is defined as the minimum integer $k$ so that $V(D)$ can be partitioned into $k$ acyclic sets, and the girth is the length of the shortest cycle in the corresponding undirected graph. It is also shown, in the same vein as an old result of Erdos (1962), that there are digraphs with arbitrarily large chromatic number where every large subset of vertices is 2-colorable.

  18. Spectrally multiplexed chromatic confocal multipoint sensing.

    Science.gov (United States)

    Hillenbrand, Matthias; Lorenz, Lucia; Kleindienst, Roman; Grewe, Adrian; Sinzinger, Stefan

    2013-11-15

    We present a concept for chromatic confocal distance sensing that employs two levels of spectral multiplexing for the parallelized evaluation of multiple lateral measurement points; at the first level, the chromatic confocal principle is used to encode distance information within the spectral distribution of the sensor signal. For lateral multiplexing, the total spectral bandwidth of the sensor is split into bands. Each band is assigned to a different lateral measurement point by a segmented diffractive element. Based on this concept, we experimentally demonstrate a chromatic confocal three-point sensor that is suitable for harsh production environments, since it works with a single-point spectrometer and does not require scanning functionality. The experimental system has a working distance of more than 50 mm, a measurement range of 9 mm, and an axial resolution of 50 μm.

  19. Preliminary studies of a chromaticity tracker

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Cheng-Yang; /Fermilab

    2006-03-01

    A chromaticity tracker based on a method by D. McGinnis is proposed. This method starts with the slow modulation of the accelerating RF which causes the beam to respond to it. This beam modulation can be detected transversely with a Schottky pickup which after phase demodulation, the chromaticity can be calculated from it. However, to perform phase demodulation, the carrier frequency which is the betatron tune needs to be identified. The identification of the carrier frequency falls naturally onto the phase locked loop tune tracker which when locked to the betatron tune outputs this value in real time.

  20. Structure and Growth Mechanism of Lanthanum Chromate

    Institute of Scientific and Technical Information of China (English)

    Li Shengli; Liu Weiming; Ling Ziyu; Sun Liangcheng; Ao Qing; Fu Guifu

    2005-01-01

    The unit cell of lanthanum chromate was constructed by calculating equivalent points. By means of calculation of the hole octahedrally surrounded by O2- ions, it was considered that the sintered property of lanthanum chromate and the stability of Cr-O octahedron might be promoted by mixing a little Ca2+ ions. The growth mechanism was discussed in terms of structural ledge observed by SEM, the surfaces of the structural ledges parallel to (001), (010) and (110) planes, respectively. The misfit between (110) and (001) planes is only 0.0021 on common atomic plane, and the interconnection of the structured ledge may occur during crystal growth.

  1. Total dominator chromatic number of a graph

    Directory of Open Access Journals (Sweden)

    Adel P. Kazemi

    2015-06-01

    Full Text Available Given a graph $G$, the total dominator coloring problem seeks a proper coloring of $G$ with the additional property that every vertex in the graph is adjacent to all vertices of a color class. We seek to minimize the number of color classes. We initiate to study this problem on several classes of graphs, as well as finding general bounds and characterizations. We also compare the total dominator chromatic number of a graph with the chromatic number and the total domination number of it.

  2. A bivariate chromatic polynomial for signed graphs

    CERN Document Server

    Beck, Matthias

    2012-01-01

    We study Dohmen--P\\"onitz--Tittmann's bivariate chromatic polynomial $c_\\Gamma(k,l)$ which counts all $(k+l)$-colorings of a graph $\\Gamma$ such that adjacent vertices get different colors if they are $\\le k$. Our first contribution is an extension of $c_\\Gamma(k,l)$ to signed graphs, for which we obtain an inclusion--exclusion formula and several special evaluations giving rise, e.g., to polynomials that encode balanced subgraphs. Our second goal is to derive combinatorial reciprocity theorems for $c_\\Gamma(k,l)$ and its signed-graph analogues, reminiscent of Stanley's reciprocity theorem linking chromatic polynomials to acyclic orientations.

  3. The chromatic polynomial and list colorings

    DEFF Research Database (Denmark)

    Thomassen, Carsten

    2009-01-01

    We prove that, if a graph has a list of k available colors at every vertex, then the number of list-colorings is at least the chromatic polynomial evaluated at k when k is sufficiently large compared to the number of vertices of the graph.......We prove that, if a graph has a list of k available colors at every vertex, then the number of list-colorings is at least the chromatic polynomial evaluated at k when k is sufficiently large compared to the number of vertices of the graph....

  4. On the Star Chromatic Number of Graph Products

    Institute of Scientific and Technical Information of China (English)

    XU Chuan-liang; WANG Yi-ju

    2001-01-01

    The star chromatic number of a graph was introduced by A. Vince, which is a natural generalization of the chromatic number of a graph. In this paper, the star chromatic numbers of graph products G (×) H are discussed in some special cases.

  5. Anti-forensics of chromatic aberration

    Science.gov (United States)

    Mayer, Owen; Stamm, Matthew C.

    2015-03-01

    Over the past decade, a number of information forensic techniques have been developed to identify digital image manipulation and falsification. Recent research has shown, however, that an intelligent forger can use anti-forensic countermeasures to disguise their forgeries. In this paper, an anti-forensic technique is proposed to falsify the lateral chromatic aberration present in a digital image. Lateral chromatic aberration corresponds to the relative contraction or expansion between an image's color channels that occurs due to a lens's inability to focus all wavelengths of light on the same point. Previous work has used localized inconsistencies in an image's chromatic aberration to expose cut-and-paste image forgeries. The anti-forensic technique presented in this paper operates by estimating the expected lateral chromatic aberration at an image location, then removing deviations from this estimate caused by tampering or falsification. Experimental results are presented that demonstrate that our anti-forensic technique can be used to effectively disguise evidence of an image forgery.

  6. Effect of Interior Chromaticness on Space Brightness

    Directory of Open Access Journals (Sweden)

    Hidenari Takada

    2011-05-01

    Full Text Available To design a lighting environment, horizontal illuminance is generally used as the brightness of a room. But it is reported that a subjective brightness does not always match the horizontal illuminance. For example, the room furnished with high saturated colored objects is perceived brighter than the room furnished with achromatic objects, even though the horizontal illuminance is the same. To investigate a effect of interior chromaticness on space brightness, we conducted the experiment in four miniature rooms that were different in terms of chromaticness of interior decorating surfaces, but kept lightness of surfaces constant. Subjects were asked to set the illuminance of reference room, that is furnished with achromatic objects, to equate the brightness of the test room, that is with chromatic objects. Four of seven subjects needed less illuminance to get the equality of space brightness if the test room had a saturated objects. The illuminance ratio of test to reference room was about 1.4. Other three subjects set the illuminance of reference room almost equal to test room. Thus, there are differences between individuals so further work would be needed to estimate the quantitative effect of interior chromaticness on space brightness.

  7. Chromatic Dispersion Estimation in Digital Coherent Receivers

    DEFF Research Database (Denmark)

    Soriano, Ruben Andres; Hauske, Fabian N.; Guerrero Gonzalez, Neil;

    2011-01-01

    Polarization-diverse coherent demodulation allows to compensate large values of accumulated linear distortion by digital signal processing. In particular, in uncompensated links without optical dispersion compensation, the parameter of the residual chromatic dispersion (CD) is vital to set the ac...

  8. Mechanisms of chromate adsorption on boehmite.

    Science.gov (United States)

    Johnston, Chad P; Chrysochoou, Maria

    2015-01-08

    Adsorption reactions play an important role in the transport behavior of groundwater contaminants. Molecular-scale information is needed to elucidate the mechanisms by which ions coordinate to soil mineral surfaces. In this study, we characterized the mechanisms of chromate adsorption on boehmite (γ-AlOOH) using a combination of extended X-ray absorption fine structure (EXAFS) measurements, in situ attenuated total reflectance Fourier transform infrared spectroscopy, and quantum chemical calculations. The effects of pH, ionic strength, and aqueous chromate concentration were investigated. Our overall findings were that chromate primarily forms outer-sphere complexes on boehmite over a broad range of pH and aqueous concentrations. Additionally, a small fraction of monodentate and bidentate inner-sphere complexes are present under acidic conditions, as evidenced by two sets of chromate stretching vibrations at approximately 915, 870, and 780cm(-1), and 940, 890, 850, and 780cm(-1), respectively. The bidentate complex is supported by a best-fit CrAl distance in the EXAFS of 3.2Å. Results from DFT also support the formation of monodentate and bidentate complexes, which are predicted to results in Gibbs energy changes of -140.4 and -62.5kJmol(-1), respectively. These findings are consistent with the intermediate binding strength of chromate with respect to similar oxyanions such as sulfate and selenite. Overall, the surface species identified in this work can be used to develop a more accurate stoichiometric framework in mechanistic adsorption models. Copyright © 2014 Elsevier B.V. All rights reserved.

  9. Sorting chromatic sextupoles for easily and effectively correcting second order chromaticity in the Relativistic Heavy Ion Collider

    Energy Technology Data Exchange (ETDEWEB)

    Luo,Y.; Tepikian, S.; Fischer, W.; Robert-Demolaize, G.; Trbojevic, D.

    2009-01-02

    Based on the contributions of the chromatic sextupole families to the half-integer resonance driving terms, we discuss how to sort the chromatic sextupoles in the arcs of the Relativistic Heavy Ion Collider (RHIC) to easily and effectively correct the second order chromaticities. We propose a method with 4 knobs corresponding to 4 pairs of chromatic sextupole families to online correct the second order chromaticities. Numerical simulation justifies this method, showing that this method reduces the unbalance in the correction strengths of sextupole families and avoids the reversal of sextupole polarities. Therefore, this method yields larger dynamic apertures for the proposed RHIC 2009 100GeV polarized proton run lattices.

  10. Neural network correction of astrometric chromaticity

    CERN Document Server

    Gai, M

    2005-01-01

    In this paper we deal with the problem of chromaticity, i.e. apparent position variation of stellar images with their spectral distribution, using neural networks to analyse and process astronomical images. The goal is to remove this relevant source of systematic error in the data reduction of high precision astrometric experiments, like Gaia. This task can be accomplished thanks to the capability of neural networks to solve a nonlinear approximation problem, i.e. to construct an hypersurface that approximates a given set of scattered data couples. Images are encoded associating each of them with conveniently chosen moments, evaluated along the y axis. The technique proposed, in the current framework, reduces the initial chromaticity of few milliarcseconds to values of few microarcseconds.

  11. A molecular understanding of complementary chromatic adaptation.

    Science.gov (United States)

    Grossman, Arthur R

    2003-01-01

    Photosynthetic activity and the composition of the photosynthetic apparatus are strongly regulated by environmental conditions. Some visually dramatic changes in pigmentation of cyanobacterial cells that occur during changing nutrient and light conditions reflect marked alterations in components of the major light-harvesting complex in these organisms, the phycobilisome. As noted well over 100 years ago, the pigment composition of some cyanobacteria is very sensitive to ambient wavelengths of light; this sensitivity reflects molecular changes in polypeptide constituents of the phycobilisome. The levels of different pigmented polypeptides or phycobiliproteins that become associated with the phycobilisome are adjusted to optimize absorption of excitation energy present in the environment. This process, called complementary chromatic adaptation, is controlled by a bilin-binding photoreceptor related to phytochrome of vascular plants; however, many other regulatory elements also play a role in chromatic adaptation. My perspectives and biases on the history and significance of this process are presented in this essay.

  12. The chromatic number of comparability 3-hypergraphs

    OpenAIRE

    2014-01-01

    Beginning with the concepts of orientation for a 3-hypergraph and transitivity for an oriented 3-hypergraph, it is natural to study the class of comparability 3-hypergraphs (those that can be transitively oriented). In this work we show three different behaviors in respect to the relationship between the chromatic number and the clique number of a comparability 3-hypergraph, this is in contrast with the fact that a comparability simple graph is a perfect graph.

  13. Chromaticity correction for a muon collider optics

    Energy Technology Data Exchange (ETDEWEB)

    Alexahin, Y.; Gianfelice-Wendt, E.; Kapin, V.; /Fermilab

    2011-03-01

    Muon Collider (MC) is a promising candidate for the next energy frontier machine. However, in order to obtain peak luminosity in the 10{sup 34} cm{sup 2}s{sup -1} range the collider lattice designmust satisfy a number of stringent requirements. In particular the expected large momentum spread of the muon beam and the very small {beta}* call for a careful correction of the chromatic effects. Here we present a particular solution for the interaction region (IR) optics whose distinctive feature is a three-sextupole local chromatic correction scheme. The scheme may be applied to other future machines where chromatic effects are expected to be large. The expected large muon energy spread requires the optics to be stable over a wide range of momenta whereas the required luminosity calls for {beta}* in the mm range. To avoid luminosity degradation due to hour-glass effect, the bunch length must be comparatively small. To keep the needed RF voltage within feasible limits the momentum compaction factor must be small over the wide range of momenta. A low {beta}* means high sensitivity to alignment and field errors of the Interaction Region (IR) quadrupoles and large chromatic effects which limit the momentum range of optics stability and require strong correction sextupoles, which eventually limit the Dynamic Aperture (DA). Finally, the ring circumference should be as small as possible, luminosity being inversely proportional to the collider length. A promising solution for a 1.5 TeV center of mass energy MC with {beta}* = 1 m in both planes has been proposed. This {beta}* value has been chosen as a compromise between luminosity and feasibility based on the magnet design and energy deposition considerations. The proposed solution for the IR optics together with a new flexible momentum compaction arc cell design allows to satisfy all requirements and is relatively insensitive to the beam-beam effect.

  14. Schottky signal analysis: tune and chromaticity computation

    CERN Document Server

    Chanon, Ondine

    2016-01-01

    Schottky monitors are used to determine important beam parameters in a non-destructive way. The Schottky signal is due to the internal statistical fluctuations of the particles inside the beam. In this report, after explaining the different components of a Schottky signal, an algorithm to compute the betatron tune is presented, followed by some ideas to compute machine chromaticity. The tests have been performed with offline and/or online LHC data.

  15. Chromatic Adaptation in an Immersive Viewing Environment

    OpenAIRE

    MacDonald, L. W.; Roque, T.

    2013-01-01

    A hollow fibreglass sphere of 750 mm diameter was used to create an immersive mesopic viewing environment. Light was projected through a series of 20nm-bandwidth filters to illuminate the interior of the sphere with a near-monochromatic adapting field. The task of the observer was to set a target to appear neutral grey, using two interactive slider controls. The results suggest that chromatic adaptation is continuing even after an hour, suggesting the influence of retinal mechanisms with a ve...

  16. Calibration and removal of lateral chromatic aberration in images

    OpenAIRE

    Mallon, John; Whelan, Paul F.

    2007-01-01

    This paper addresses the problem of compensating for lateral chromatic aberration in digital images through colour plane realignment. Two main contributions are made: the derivation of a model for lateral chromatic aberration in images, and the subsequent calibration of this model from a single view of a chess pattern. These advances lead to a practical and accurate alternative for the compensation of lateral chromatic aberrations. Experimental results validate the proposed models and calibra...

  17. Chromatic polynomials of graphs from Kac-Moody algebras

    OpenAIRE

    Venkatesh, R.; Viswanath, Sankaran

    2013-01-01

    We give a new interpretation of the chromatic polynomial of a simple graph G in terms of the Kac-Moody Lie algebra with Dynkin diagram G. We show that the chromatic polynomial is essentially the q-Kostant partition function of this Lie algebra evaluated on the sum of the simple roots. Applying the Peterson recurrence formula for root multiplicities, we obtain a new realization of the chromatic polynomial as a weighted sum of paths in the bond lattice of G.

  18. Improved step-by-step chromaticity compensation method for chromatic sextupole optimization

    CERN Document Server

    Liu, Gang-Wen; Jia, Qi-Ka; Li, Wei-Min; Wang, Lin

    2015-01-01

    The step-by-step chromaticity compensation method for chromatic sextupole optimization and dynamic aperture increase was proposed by E. Levichev and P. Piminov (E. Levichev and P. Piminov, 2006 [1]). Although this method can be used to enlarge the dynamic aperture of storage ring, it has some drawbacks. In this paper, we combined this method with evolutionary computation algorithms, and proposed an improved version of this method. In the improved method, the drawbacks are avoided, and thus better optimization results can be obtained.

  19. The b-chromatic number of power graphs

    Directory of Open Access Journals (Sweden)

    Brice Effantin

    2003-06-01

    Full Text Available The b-chromatic number of a graph G is defined as the maximum number k of colors that can be used to color the vertices of G, such that we obtain a proper coloring and each color i, with 1 ≤ i≤ k, has at least one representant x i adjacent to a vertex of every color j, 1 ≤ j ≠ i ≤ k. In this paper, we discuss the b-chromatic number of some power graphs. We give the exact value of the b-chromatic number of power paths and power complete binary trees, and we bound the b-chromatic number of power cycles.

  20. An Application of Chromatic Prototypes for a Universal Information System

    CERN Document Server

    McCool, Matthew

    2007-01-01

    This paper presents research on color prototypes, categories, and the neuropsychology of color. These data suggest that chromatic prototypes may be useful for thematically organizing information systems.

  1. Spatio-Chromatic Adaptation via Higher-Order Canonical Correlation Analysis of Natural Images: e86481

    National Research Council Canada - National Science Library

    Michael U Gutmann; Valero Laparra; Aapo Hyvärinen; Jesús Malo

    2014-01-01

    .... In neuroscience, independent component analysis of chromatic natural images explains the spatio-chromatic structure of primary cortical receptive fields in terms of properties of the visual environment...

  2. PSB Chromaticity Correction in both Planes

    CERN Document Server

    Bartosik, Hannes; CERN. Geneva. ATS Department

    2017-01-01

    In view of the LHC injector upgrade program (LIU[1]), all LHC pre-accelerators and in particular the CERN Booster (PSB) are being reviewed for potential lattice optics and equipment optimizations. The option to correct the chromaticity in both planes would be very helpful for a better control of the beam in the presence of both non-linearities and space charge. Moreover, one could reduce decoherence phenomena that otherwise limit the usefulness of resonance measurement techniques based on a turn-by-turn BPM system.

  3. Chromatic Image Analysis For Quantitative Thermal Mapping

    Science.gov (United States)

    Buck, Gregory M.

    1995-01-01

    Chromatic image analysis system (CIAS) developed for use in noncontact measurements of temperatures on aerothermodynamic models in hypersonic wind tunnels. Based on concept of temperature coupled to shift in color spectrum for optical measurement. Video camera images fluorescence emitted by phosphor-coated model at two wavelengths. Temperature map of model then computed from relative brightnesses in video images of model at those wavelengths. Eliminates need for intrusive, time-consuming, contact temperature measurements by gauges, making it possible to map temperatures on complex surfaces in timely manner and at reduced cost.

  4. Histopathological study on changes of bronchial epithelium among chromate workers

    Energy Technology Data Exchange (ETDEWEB)

    Mikami, H.

    1982-09-01

    There have been many reports on lung cancer among chromate workers. Chromate compounds are thought to be a carcinogen and lung cancer among chromate workers is considered one of the occupational lung cancers. Recently, it is debated that metaplastic and hyperplastic changes of bronchial epithelium are revealed or not to the development of bronchogenic carcinoma. Histopathological study on changes of bronchial epithelium among chromate workers was performed in order to clarify the effect of chromate compounds to bronchial epithelium. The subjects were 14 cases of lung cancer among chromate workers. As a control, 18 cases of non cancer among chromate workers. Lung tissue which was obtained at necropsy or surgery was fixed by formalin and was produced cross-sections and was stained on Haematoxylin-Eosin. The results were as follows. Of examined 235 cross-sections, basal cell hyperplasia of bronchial epithelium was found in 13 percent. Squamous metaplasia was found in 29 percent, on the contrary, atypical metaplastic changes were observed in 34 percent. Of four cases of carcinoma in situ and two cases of small invasive carcinoma, four cases revealed development from atypical squamous metaplasia to precancerous changes. These cases developed invasive carcinoma from atypical squamous metaplasia for a long period, of which were found by successive exfoliative cytology of sputum. From these findings, it was concluded that inhalation of chromate dust affected bronchial epithelium and caused highly atypical squamous metaplasia which developed to carcinoma in situ and finally to invasive carcinoma.

  5. Histopathological study on changes of bronchial epithelium among chromate workers

    Energy Technology Data Exchange (ETDEWEB)

    Mikami, H.

    1982-09-01

    There have been many reports on lung cancer among chromate workers. Chromate compounds are thought to be a carcinogen and lung cancer among chromate workers is considered one of the occupational lung cancers. Recently, it is debated that metaplastic and hyperplastic changes of bronchial epithelium are revealed or not to the development of bronchogenic carcinoma. Histopathological study on changes of bronchial epithelium among chromate workers was performed in order to clarify the effect of chromate compounds to bronchial epithelium. The subjects were 14 cases of lung cancer among chromate workers. As a control, 18 cases of non cancer among chromate workers. Lung tissue which was obtained at necropsy or surgery was fixed by formalin and was produced cross-sections and was stained on Haematoxylin-Eosin. The results were as follows. 1. Of examined 235 cross-sections, basal cell hyperplasia of bronchial epithelium was found in 13 per cent. Squamous metaplasia was found in 29 per cent, on the contrary, atypical metaplastic changes were observed in 34 per cent. 2. Of four cases of carcinoma in situ and two cases of small invasive carcinoma, four cases revealed development from atypical squamous metaplasia to precancerous changes. 3. These cases developed invasive carcinoma from atypical squamous metaplasia for a long period, of which were found by successive exfoliative cytology of sputum. From these findings, it was concluded that inhalation of chromate dust affected bronchial epithelium and caused highly atypical squamous metaplasia which developed to carcinoma in situ and finally to invasive carcinoma.

  6. On the chromatic number of general Kneser hypergraphs

    DEFF Research Database (Denmark)

    Alishahi, Meysam; Hajiabolhassan, Hossein

    2015-01-01

    In a break-through paper, Lovász [20] determined the chromatic number of Kneser graphs. This was improved by Schrijver [27], by introducing the Schrijver subgraphs of Kneser graphs and showing that their chromatic number is the same as that of Kneser graphs. Alon, Frankl, and Lovász [2] extended ...

  7. Reexploring the upper bound for the chromatic number of graphs

    Institute of Scientific and Technical Information of China (English)

    LI Shuchao; MAO Jingzhong

    2004-01-01

    The upper bound of the chromatic number of simple graphs is explored. Its original idea comes from Coffman, Hakimi and Schmeichel, who recently studied the chromatic number of graphs with strong conditions. In this paper, corresponding conditions are weakened and the result proves that of Ershov and Kozhukhin's.

  8. Luminance-dependent long-term chromatic adaptation.

    Science.gov (United States)

    Vincent, Joris; Kale, Alex M; Buck, Steven L

    2016-03-01

    There is theoretical and empirical support for long-term adaptation of human vision to chromatic regularities in the environment. The current study investigates whether relationships of luminance and chromaticity in the natural environment could drive chromatic adaptation independently and differently for bright and dark colors. This is motivated by psychophysical evidence of systematic difference shifts in red-green chromatic sensitivities between contextually bright- versus dark-colored stimuli. For some broad classes of scene content, consistent shifts in chromaticity are found between high and low light levels within images. Especially in those images in which sky and terrain are juxtaposed, this shift has direction and magnitude consistent with the observed psychophysical shifts in the red-green balance between bright and dark colors. Taken together, these findings suggest that relative weighting of M- and L-cone signals could be adapted, in a luminance-dependent fashion, to regularities in the natural environment.

  9. Linear and chromatic optics measurements at RHIC

    Energy Technology Data Exchange (ETDEWEB)

    Aiba, M.; Calaga, R.; Aiba, M.; Tomas, R.; Vanbavinkove, G.

    2010-05-23

    Measurements of chromatic beta-beating were carried out for the first time in the RHIC accelerator during Run 2009. The analysis package developed for the LHC was used to extract the off-momentum optics for injection and top energy. Results from the beam experiments and compassion to the optics model are presented. The primary goal of the RHIC experiments were execute an on-line measurement of the optics using the tools developed for the LHC. Turn-by-turn BPM trajectories (typically 1000 turns) acquired immediately after an external dipole kick are numerically analyzed to determine the optical parameters at the location of the beam position monitors (BPMs). For chromatic optics, a similar analysis, but on a beam with finite momentum offset(s). Each optical measurement typically is calculated from multiple data sets to capture statistical variations and ensure reproducibility. The procedure of measurement and analysis is detailed in ref [1, 2]. Two dedicated experiments were performed at RHIC with protons during Run 2009. The first at injection energy and optics and the other at 250 GeV and squeezed optics. The basic RHIC parameters relevant for the two experiments are listed in Table 1.

  10. Copper hypersensitivity.

    Science.gov (United States)

    Fage, Simon W; Faurschou, Annesofie; Thyssen, Jacob P

    2014-10-01

    The world production of copper is steadily increasing. Although humans are widely exposed to copper-containing items on the skin and mucosa, allergic reactions to copper are only infrequently reported. To review the chemistry, biology and accessible data to clarify the implications of copper hypersensitivity, a database search of PubMed was performed with the following terms: copper, dermatitis, allergic contact dermatitis, contact hypersensitivity, contact sensitization, contact allergy, patch test, dental, IUD, epidemiology, clinical, and experimental. Human exposure to copper is relatively common. As a metal, it possesses many of the same qualities as nickel, which is a known strong sensitizer. Cumulative data on subjects with presumed related symptoms and/or suspected exposure showed that a weighted average of 3.8% had a positive patch test reaction to copper. We conclude that copper is a very weak sensitizer as compared with other metal compounds. However, in a few and selected cases, copper can result in clinically relevant allergic reactions.

  11. Molybdate based Alternatives to Chromating as a Passivation Treatment for Zinc

    DEFF Research Database (Denmark)

    Tang, Peter Torben; Bech-Nielsen, G.; Møller, Per

    1994-01-01

    in chromating. The corrosion protection provided by the process on zinc-plated parts is comparable to chromates. Depending on test conditions, especially pH value, the molybdate/phosphate process was found to be better than chromate at low pH values, equal to chromates in outdoor exposure tests and prohesion...

  12. Effects of chromatic image statistics on illumination induced color differences.

    Science.gov (United States)

    Lucassen, Marcel P; Gevers, Theo; Gijsenij, Arjan; Dekker, Niels

    2013-09-01

    We measure the color fidelity of visual scenes that are rendered under different (simulated) illuminants and shown on a calibrated LCD display. Observers make triad illuminant comparisons involving the renderings from two chromatic test illuminants and one achromatic reference illuminant shown simultaneously. Four chromatic test illuminants are used: two along the daylight locus (yellow and blue), and two perpendicular to it (red and green). The observers select the rendering having the best color fidelity, thereby indirectly judging which of the two test illuminants induces the smallest color differences compared to the reference. Both multicolor test scenes and natural scenes are studied. The multicolor scenes are synthesized and represent ellipsoidal distributions in CIELAB chromaticity space having the same mean chromaticity but different chromatic orientations. We show that, for those distributions, color fidelity is best when the vector of the illuminant change (pointing from neutral to chromatic) is parallel to the major axis of the scene's chromatic distribution. For our selection of natural scenes, which generally have much broader chromatic distributions, we measure a higher color fidelity for the yellow and blue illuminants than for red and green. Scrambled versions of the natural images are also studied to exclude possible semantic effects. We quantitatively predict the average observer response (i.e., the illuminant probability) with four types of models, differing in the extent to which they incorporate information processing by the visual system. Results show different levels of performance for the models, and different levels for the multicolor scenes and the natural scenes. Overall, models based on the scene averaged color difference have the best performance. We discuss how color constancy algorithms may be improved by exploiting knowledge of the chromatic distribution of the visual scene.

  13. Non-Chromate Passivation of Zinc

    DEFF Research Database (Denmark)

    Tang, Peter Torben; Bech-Nielsen, G.

    1993-01-01

    . There is no known environmental or health risk involved using the treatments mentioned above. All components used in the baths are non toxic compared to Cr(VI). Alloy coatings such as zinc/nickel, zinc/cobalt, zinc/tin and all types of pure zinc coating (from cyanide, acidic or alkaline baths) have been treated...... successfully. The corrosion resistance against white rust on zinc and zinc alloys is just as good as that of yellow chromate, although the result de-pends on the corrosion test method as well as on the nature of the zinc substrate pas-sivated. The passivation procedure is simply a dip for approxi-mately 2...

  14. Chromatic control in coextruded layered polymer microlenses

    CERN Document Server

    Crescimanno, Michael; Andrews, James H; Zhou, Chuanhong; Petrus, Joshua B; Merlo, Cory; Bagheri, Cameron; Hetzel, Connor; Tancabel, James; Singer, Kenneth D; Baer, Eric

    2015-01-01

    We describe the formation, characterization and theoretical understanding of microlenses comprised of alternating polystyrene and polymethylmethacrylate layers produced by multilayer coextrusion. These lenses are fabricated by photolithography, using a grayscale mask followed by plasma etching, so that the refractive index alternation of the bilayer stack appears across the radius of the microlens. The alternating quarter-wave thick layers form a one-dimensional photonic crystal whose dispersion augments the material dispersion, allowing one to sculpt the chromatic dispersion of the lens by adjusting the layered structure. Using Huygen's principle, we model our experimental measurements of the focal length of these lenses across the reflection band of the multilayer polymer film from which the microlens is fashioned. For a 56 micron diameter multilayered lens of focal length 300 microns, we measured a nearly 25 percent variation in the focal length across a shallow, 50 nm-wide reflection band.

  15. Chromatic Polynomials Of Some (m,l-Hyperwheels

    Directory of Open Access Journals (Sweden)

    Julian A. Allagan

    2014-03-01

    Full Text Available In this paper, using a standard method of computing the chromatic polynomial of hypergraphs, we introduce a new reduction theorem which allows us to find explicit formulae for the chromatic polynomials of some (complete non-uniform $(m,l-$hyperwheels and non-uniform $(m,l-$hyperfans. These hypergraphs, constructed through a ``join" graph operation, are some generalizations of the well-known wheel and fan graphs, respectively. Further, we revisit some results concerning these graphs and present their chromatic polynomials in a standard form that involves the Stirling numbers of the second kind.

  16. Abnormal pupillary light reflex with chromatic pupillometry in Gaucher disease

    Science.gov (United States)

    Narita, Aya; Shirai, Kentarou; Kubota, Norika; Takayama, Rumiko; Takahashi, Yukitoshi; Onuki, Takanori; Numakura, Chikahiko; Kato, Mitsuhiro; Hamada, Yusuke; Sakai, Norio; Ohno, Atsuko; Asami, Maya; Matsushita, Shoko; Hayashi, Anri; Kumada, Tomohiro; Fujii, Tatsuya; Horino, Asako; Inoue, Takeshi; Kuki, Ichiro; Asakawa, Ken; Ishikawa, Hitoshi; Ohno, Koyo; Nishimura, Yoko; Tamasaki, Akiko; Maegaki, Yoshihiro; Ohno, Kousaku

    2014-01-01

    The hallmark of neuronopathic Gaucher disease (GD) is oculomotor abnormalities, but ophthalmological assessment is difficult in uncooperative patients. Chromatic pupillometry is a quantitative method to assess the pupillary light reflex (PLR) with minimal patient cooperation. Thus, we investigated whether chromatic pupillometry could be useful for neurological evaluations in GD. In our neuronopathic GD patients, red light-induced PLR was markedly impaired, whereas blue light-induced PLR was relatively spared. In addition, patients with non-neuronopathic GD showed no abnormalities. These novel findings show that chromatic pupillometry is a convenient method to detect neurological signs and monitor the course of disease in neuronopathic GD. PMID:25356393

  17. Copper transport.

    Science.gov (United States)

    Linder, M C; Wooten, L; Cerveza, P; Cotton, S; Shulze, R; Lomeli, N

    1998-05-01

    In adult humans, the net absorption of dietary copper is approximately 1 mg/d. Dietary copper joins some 4-5 mg of endogenous copper flowing into the gastrointestinal tract through various digestive juices. Most of this copper returns to the circulation and to the tissues (including liver) that formed them. Much lower amounts of copper flow into and out of other major parts of the body (including heart, skeletal muscle, and brain). Newly absorbed copper is transported to body tissues in two phases, borne primarily by plasma protein carriers (albumin, transcuprein, and ceruloplasmin). In the first phase, copper goes from the intestine to the liver and kidney; in the second phase, copper usually goes from the liver (and perhaps also the kidney) to other organs. Ceruloplasmin plays a role in this second phase. Alternatively, liver copper can also exit via the bile, and in a form that is less easily reabsorbed. Copper is also present in and transported by other body fluids, including those bathing the brain and central nervous system and surrounding the fetus in the amniotic sac. Ceruloplasmin is present in these fluids and may also be involved in copper transport there. The concentrations of copper and ceruloplasmin in milk vary with lactational stage. Parallel changes occur in ceruloplasmin messenger RNA expression in the mammary gland (as determined in pigs). Copper in milk ceruloplasmin appears to be particularly available for absorption, at least in rats.

  18. CHROMATIC-AREA EFFECT ON HOMOGENEOUS COLOR OF A ROOM FLOOR IN NATURAL INDOOR ENVIRONMENT

    OpenAIRE

    2009-01-01

    Chromatic-area effect is a phenomenon by which color appearance of chromatic surface changes when a size (visual angle) of increases without any physical change of the surface. Lightness and saturation of a large chromatic area generally increase compared to a smaller chromatic area. We investigated this chromatic-area effect on homogeneous color of a room floor under light environment in the day (white daylight) and in the night (a fluorescent lamp). Observes performed color matching between...

  19. CHROMATIC-AREA EFFECT ON HOMOGENEOUS COLOR OF A ROOM FLOOR IN NATURAL INDOOR ENVIRONMENT

    OpenAIRE

    篠森, 敬三; 船江, 彰

    2009-01-01

    Chromatic-area effect is a phenomenon by which color appearance of chromatic surface changes when a size (visual angle) of increases without any physical change of the surface. Lightness and saturation of a large chromatic area generally increase compared to a smaller chromatic area. We investigated this chromatic-area effect on homogeneous color of a room floor under light environment in the day (white daylight) and in the night (a fluorescent lamp). Observes performed color matching between...

  20. Copper hypersensitivity

    DEFF Research Database (Denmark)

    Fage, Simon W; Faurschou, Annesofie; Thyssen, Jacob P

    2014-01-01

    hypersensitivity, a database search of PubMed was performed with the following terms: copper, dermatitis, allergic contact dermatitis, contact hypersensitivity, contact sensitization, contact allergy, patch test, dental, IUD, epidemiology, clinical, and experimental. Human exposure to copper is relatively common...

  1. Chromatic $k$-Mean Clustering in High Dimensional Space

    CERN Document Server

    Ding, Hu

    2012-01-01

    In this paper, we study a new type of clustering problem, called {\\em Chromatic Clustering}, in high dimensional space. Chromatic clustering seeks to partition a set of colored points into groups (or clusters) so that no group contains points with the same color and a certain objective function is optimized. In this paper, we focus on $k$-mean clustering, and investigate its hardness and approximation solutions. The additional coloring requirement destroys some key properties used in existing $k$-mean clustering techniques (for the ordinary clustering problem), and significantly complicates the problem. There is no FPTAS for the chromatic clustering problem, even if $k=2$. Based on several new geometric observations and an interesting sphere peeling approach, we show that a near linear time (on $n$ and $d$) $(1+\\epsilon)$-approximation is, however, still achievable for the chromatic clustering problem.

  2. Measuring chromatic aberrations in imaging systems using plasmonic nanoparticles

    Science.gov (United States)

    Gennaro, Sylvain D.; Roschuk, Tyler R.; Maier, Stefan A.; Oulton, Rupert F.

    2016-04-01

    Chromatic aberration in optical systems arises from the wavelength dependence of a glass's refractive index. Polychromatic rays incident upon an optical surface are refracted at slightly different angles and in traversing an optical system follow distinct paths creating images displaced according to color. Although arising from dispersion, it manifests as a spatial distortion correctable only with compound lenses with multiple glasses and accumulates in complicated imaging systems. While chromatic aberration is measured with interferometry, simple methods are attractive for their ease of use and low cost. In this letter we retrieve the longitudinal chromatic focal shift of high numerical aperture (NA) microscope objectives from the extinction spectra of metallic nanoparticles within the focal plane. The method is accurate for high NA objectives with apochromatic correction, and enables rapid assessment of the chromatic aberration of any complete microscopy systems, since it is straightforward to implement

  3. Chromatic and Dispersive Effects in Nonlinear Integrable Optics

    CERN Document Server

    Webb, Stephen D; Valishev, Alexander; Nagaitsev, Sergei N; Danilov, Viatcheslav V

    2015-01-01

    Proton accumulator rings and other circular hadron accelerators are susceptible to intensity-driven parametric instabilities because the zero-current charged particle dynamics are characterized by a single tune. Landau damping can suppress these instabilities, which requires energy spread in the beam or introducing nonlinear magnets such as octupoles. However, this approach reduces dynamic aperture. Nonlinear integrable optics can suppress parametric instabilities independent of energy spread in the distribution, while preserving the dynamic aperture. This novel approach promises to reduce particle losses and enable order-of-magnitude increases in beam intensity. In this paper we present results, obtained using the Lie operator formalism, on how chromaticity and dispersion affect particle orbits in integrable optics. We conclude that chromaticity in general breaks the integrability, unless the vertical and horizontal chromaticities are equal. Because of this, the chromaticity correcting magnets can be weaker ...

  4. Wide-angle chromatic aberration corrector for the human eye.

    Science.gov (United States)

    Benny, Yael; Manzanera, Silvestre; Prieto, Pedro M; Ribak, Erez N; Artal, Pablo

    2007-06-01

    The human eye is affected by large chromatic aberration. This may limit vision and makes it difficult to see fine retinal details in ophthalmoscopy. We designed and built a two-triplet system for correcting the average longitudinal chromatic aberration of the eye while keeping a reasonably wide field of view. Measurements in real eyes were conducted to examine the level and optical quality of the correction. We also performed some tests to evaluate the effect of the corrector on visual performance.

  5. FCC-ee final focus with chromaticity correction

    CERN Document Server

    Garcia, H; Tomás, R

    2014-01-01

    A 100 km circular electron-positron collider is considered as one of the possible future high energy facilities. In order to achieve a high luminosity, strong beam focusing at the Interaction Point (IP) is used requiring the correction of the chromatic aberrations. In this paper we study preliminary designs of a Final Focus System (FFS) for the FCC-ee collider with chromatic correction. Beam orbit stability and dynamic aperture calculations are also presented.

  6. All-fiber interferometer for chromatic dispersion measurements

    OpenAIRE

    Thévenaz, Luc; Pellaux, J. P.; Von der Weid, J. P.

    1988-01-01

    An all-fiber interferometric method for chromatic dispersion measurements in meter-length single-mode fibers is presented. In a Michelson setup the physical length of a reference fiber was varied so as to obtain adjustable optical delay. Time resolution, ease of manipulation, and mechanical isolation are considerably improved with respect to conventional interferometers. Resolution of group delay measurement and chromatic dispersion over the full 1100-1700-nm spectral range are better than 5 ...

  7. SERDP-ESTCP Depot Cd/Chromate Replacement Initiative

    Science.gov (United States)

    2014-11-18

    ESTCP SERDP Environmental Technology Development Process Office of the Deputy Under Secretary of Defense - Installations and Environment 4...SERDP-ESTCP Depot Cd/ Chromate Replacement Initiative Robin Nissan Weapons Systems and Platforms Program Manager ASETSDefense 18 November 2014...NOV 2014 2. REPORT TYPE 3. DATES COVERED 00-00-2014 to 00-00-2014 4. TITLE AND SUBTITLE SERDP-ESTCP Depot Cd/ Chromate Replacement Initiative 5a

  8. Studies on biological reduction of chromate by Streptomyces griseus

    Energy Technology Data Exchange (ETDEWEB)

    Poopal, Ashwini C. [Division of Biochemical Sciences, National Chemical Laboratory, Dr Homi Bhabha Road, Pune 411008 (India); Laxman, R. Seeta, E-mail: rseetalaxman@yahoo.co.in [Division of Biochemical Sciences, National Chemical Laboratory, Dr Homi Bhabha Road, Pune 411008 (India)

    2009-09-30

    Chromium is a toxic heavy metal used in various industries and leads to environmental pollution due to improper handling. The most toxic form of chromium Cr(VI) can be converted to less toxic Cr(III) by reduction. Among the actinomycetes tested for chromate reduction, thirteen strains reduced Cr(VI) to Cr(III), of which one strain of Streptomyces griseus (NCIM 2020) was most efficient showing complete reduction within 24 h. The organism was able to use a number of carbon sources as electron donors. Sulphate, nitrate, chloride and carbonate had no effect on chromate reduction during growth while cations such as Cd, Ni, Co and Cu were inhibitory to varying degrees. Chromate reduction was associated with the bacterial cells and sonication was the best method of cell breakage to release the enzyme. The enzyme was constitutive and did not require presence of chromate during growth for expression of activity. Chromate reduction with cell free extract (CFE) was observed without added NADH. However, addition of NAD(P)H resulted in 2-3-fold increase in activity. Chromate reductase showed optimum activity at 28 deg. C and pH 7.

  9. Chick eyes compensate for chromatic simulations of hyperopic and myopic defocus: Evidence that the eye uses longitudinal chromatic aberration to guide eye-growth

    OpenAIRE

    Rucker, Frances J.; Wallman, Josh

    2009-01-01

    Longitudinal chromatic aberration (LCA) causes short wavelengths to be focused in front of long wavelengths. This chromatic signal is evidently used to guide ocular accommodation. We asked whether chick eyes exposed to static gratings simulating the chromatic effects of myopic or hyperopic defocus would “compensate” for the simulated defocus.

  10. BIOAVAILABILITY OF ARSENIC, CHROMIUM, AND COPPER FROM CCA CONTAMINATED SOILS AND DUSTS

    Science.gov (United States)

    It is estimated that 70% of single family homes have pressure-treated wood decks or porches and 14% of playground equipment uses pressure-treated wood. This popular form of wood contains chromated copper arsenate (CCA), which is an antimicrobial pesticide and is currently underg...

  11. BIOAVAILABILITY OF ARSENIC, CHROMIUM, AND COPPER FOR CCA CONTAMINATED SOILS AND DUST

    Science.gov (United States)

    It is estimated that 70% of single family homes have pressure-treated wood decks or porches and 14% of playground equipment uses pressure-treated wood. This popular form of wood contains chromated copper arsenate (CCA), which is an antimicrobial pesticide and is currently underg...

  12. Chromatic polynomials of planar triangulations, the Tutte upper bound and chromatic zeros

    Science.gov (United States)

    Shrock, Robert; Xu, Yan

    2012-02-01

    Tutte proved that if Gpt is a planar triangulation and P(Gpt, q) is its chromatic polynomial, then |P(Gpt, τ + 1)| ⩽ (τ - 1)n - 5, where \\tau =(1+\\sqrt{5} \\, )/2 and n is the number of vertices in Gpt. Here we study the ratio r(Gpt) = |P(Gpt, τ + 1)|/(τ - 1)n - 5 for a variety of planar triangulations. We construct infinite recursive families of planar triangulations Gpt, m depending on a parameter m linearly related to n and show that if P(Gpt, m, q) only involves a single power of a polynomial, then r(Gpt, m) approaches zero exponentially fast as n → ∞. We also construct infinite recursive families for which P(Gpt, m, q) is a sum of powers of certain functions and show that for these, r(Gpt, m) may approach a finite nonzero constant as n → ∞. The connection between the Tutte upper bound and the observed chromatic zero(s) near to τ + 1 is investigated. We report the first known graph for which the zero(s) closest to τ + 1 is not real, but instead is a complex-conjugate pair. Finally, we discuss connections with the nonzero ground-state entropy of the Potts antiferromagnet on these families of graphs.

  13. Chromatically unique 6-bridge graph theta(a,a,a,b,b,c

    Directory of Open Access Journals (Sweden)

    N.S.A. Karim

    2016-04-01

    Full Text Available For a graph $G$, let $P(G,\\lambda$ denote the chromatic polynomial of $G$. Two graphs $G$ and $H$ are chromatically equivalent if they share the same chromatic polynomial. A graph $G$ is chromatically unique if for any graph chromatically equivalent to $G$ is isomorphic to $G$. In this paper, the chromatically unique of a new family of 6-bridge graph $\\theta(a,a,a,b,b,c$ where $2\\le a\\le b\\le c$ is investigated.

  14. Chromate Binding and Removal by the Molybdate-Binding Protein ModA.

    Science.gov (United States)

    Karpus, Jason; Bosscher, Michael; Ajiboye, Ifedayo; Zhang, Liang; He, Chuan

    2017-04-04

    Effective and cheap methods and techniques for the safe removal of hexavalent chromate from the environment are in increasingly high demand. High concentrations of hexavalent chromate have been shown to have numerous harmful effects on human biology. We show that the E. coli molybdate-binding protein ModA is a genetically encoded tool capable of removing chromate from aqueous solutions. Although previously reported to not bind chromate, we show that ModA binds chromate tightly and is capable of removing chromate to levels well below current US federal standards. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Determination of the distribution of copper and chromium in partly remediated CCA-treated pine wood using SEM and EDX analyses

    DEFF Research Database (Denmark)

    Christensen, Iben Vernegren; Ottosen, Lisbeth M.; Melcher, Eckhard;

    2005-01-01

    Soaking in different acids and electrodialytic remediation (EDR) were applied for removing copper and chromium from freshly Chromated Copper Arsenate (CCA) impregnated EN 113 pine wood samples. After remedial treatments, AAS analyses revealed that the concentration of copper (Cu) and chromium (Cr...... large amounts of Cu and no Cr. Cr was most effectively removed after soaking in oxalic acid and subsequent EDR treatment or dual soaking in phosphoric acid and oxalic acid with and without subsequent EDR....

  16. Separating monocular and binocular neural mechanisms mediating chromatic contextual interactions.

    Science.gov (United States)

    D'Antona, Anthony D; Christiansen, Jens H; Shevell, Steven K

    2014-04-17

    When seen in isolation, a light that varies in chromaticity over time is perceived to oscillate in color. Perception of that same time-varying light may be altered by a surrounding light that is also temporally varying in chromaticity. The neural mechanisms that mediate these contextual interactions are the focus of this article. Observers viewed a central test stimulus that varied in chromaticity over time within a larger surround that also varied in chromaticity at the same temporal frequency. Center and surround were presented either to the same eye (monocular condition) or to opposite eyes (dichoptic condition) at the same frequency (3.125, 6.25, or 9.375 Hz). Relative phase between center and surround modulation was varied. In both the monocular and dichoptic conditions, the perceived modulation depth of the central light depended on the relative phase of the surround. A simple model implementing a linear combination of center and surround modulation fit the measurements well. At the lowest temporal frequency (3.125 Hz), the surround's influence was virtually identical for monocular and dichoptic conditions, suggesting that at this frequency, the surround's influence is mediated primarily by a binocular neural mechanism. At higher frequencies, the surround's influence was greater for the monocular condition than for the dichoptic condition, and this difference increased with temporal frequency. Our findings show that two separate neural mechanisms mediate chromatic contextual interactions: one binocular and dominant at lower temporal frequencies and the other monocular and dominant at higher frequencies (6-10 Hz).

  17. Color constancy through inverse-intensity chromaticity space

    Science.gov (United States)

    Tan, Robby T.; Nishino, Ko; Ikeuchi, Katsushi

    2004-03-01

    Existing color constancy methods cannot handle both uniformly colored surfaces and highly textured surfaces in a single integrated framework. Statistics-based methods require many surface colors and become error prone when there are only a few surface colors. In contrast, dichromatic-based methods can successfully handle uniformly colored surfaces but cannot be applied to highly textured surfaces, since they require precise color segmentation. We present a single integrated method to estimate illumination chromaticity from single-colored and multicolored surfaces. Unlike existing dichromatic-based methods, the proposed method requires only rough highlight regions without segmenting the colors inside them. We show that, by analyzing highlights, a direct correlation between illumination chromaticity and image chromaticity can be obtained. This correlation is clearly described in ``inverse-intensity chromaticity space,'' a novel two-dimensional space that we introduce. In addition, when Hough transform and histogram analysis is utilized in this space, illumination chromaticity can be estimated robustly, even for a highly textured surface.

  18. Longitudinal chromatic aberration of the human infant eye.

    Science.gov (United States)

    Wang, Jingyun; Candy, T Rowan; Teel, Danielle F W; Jacobs, Robert J

    2008-09-01

    Although the longitudinal chromatic aberration (LCA) of the adult eye has been studied, there are no data collected from the human infant eye. A chromatic retinoscope was used to measure cyclopleged infant and adult refractions with four pseudomonochromatic sources (centered at 472, 538, 589, and 652 nm) and with polychromatic light. The LCA of the infant eyes between 472 and 652 nm was a factor of 1.7 greater than the LCA found in the adult group: infant mean=1.62 D, SD+/- 0.14 D; adult mean=0.96 D, SD+/- 0.17 D. The elevated level of LCA in infant eyes is consistent with the greater optical power of the immature eye and indicates similar chromatic dispersion in infant and adult eyes. The implications for visual performance, defocus detection, and measurement of refraction are discussed.

  19. Dynamic compensation of chromatic aberration in a programmable diffractive lens.

    Science.gov (United States)

    Millán, María S; Otón, Joaquín; Pérez-Cabré, Elisabet

    2006-10-02

    A proposal to dynamically compensate chromatic aberration of a programmable phase Fresnel lens displayed on a liquid crystal device and working under broadband illumination is presented. It is based on time multiplexing a set of lenses, designed with a common focal length for different wavelengths, and a tunable spectral filter that makes each sublens work almost monochromatically. Both the tunable filter and the sublens displayed by the spatial light modulator are synchronized. The whole set of sublenses are displayed within the integration time of the sensor. As a result the central order focalization has a unique location at the focal plane and it is common for all selected wavelengths. Transversal chromatic aberration of the polychromatic point spread function is reduced by properly adjusting the pupil size of each sublens. Longitudinal chromatic aberration is compensated by making depth of focus curves coincident for the selected wavelengths. Experimental results are in very good agreement with theory.

  20. Low chromatic aberration hexapole for molecular state selection

    Science.gov (United States)

    Ke, Yi; Deng, Xiao-Bing; Hu, Zhong-Kun

    2016-01-01

    In molecular beam state-selection experiments, the electrostatic hexapole acts as an optical lens, imaging molecules from the source to the focus. The molecular longitudinal velocity spread induces the phenomenon of chromatic aberration, which will reduce the state-selection purity. We propose a scheme which can effectively reduce the chromatic aberration by changing the hexapole voltage operating manner. The hexapole is already charged before molecules arrive at the entrance of the hexapole. When molecules are completely inside the hexapole, the voltage is switched off rapidly at an appropriate time. In this manner, faster molecules travel a longer hexapole focusing region than slower molecules. Therefore the focusing positions of molecules with different velocities become close. Numerical trajectory simulations of molecular state selection are carried out, and the results show that this low chromatic aberration hexapole can significantly improve the state purity from 46.2% to 87.0%.

  1. Fabrication of anodic aluminum oxide with incorporated chromate ions

    Science.gov (United States)

    Stępniowski, Wojciech J.; Norek, Małgorzata; Michalska-Domańska, Marta; Bombalska, Aneta; Nowak-Stępniowska, Agata; Kwaśny, Mirosław; Bojar, Zbigniew

    2012-10-01

    The anodization of aluminum in 0.3 M chromic acid is studied. The influence of operating conditions (like anodizing voltage and electrolyte's temperature) on the nanoporous anodic aluminum oxide geometry (including pore diameter, interpore distance, the oxide layer thickness and pores density) is thoroughly investigated. The results revealed typical correlations of the anodic alumina nanopore geometry with operating conditions, such as linear increase of pore diameter and interpore distance with anodizing voltage. The anodic aluminum oxide is characterized by a low pores arrangement, as determined by Fast Fourier transforms analyses of the FE-SEM images, which translates into a high concentration of oxygen vacancies. Moreover, an optimal experimental condition where chromate ions are being successfully incorporated into the anodic alumina walls, have been determined: the higher oxide growth rate the more chromate ions are being trapped. The trapped chromate ions and a high concentration of oxygen vacancies make the anodic aluminum oxide a promising luminescent material.

  2. Chromatic effects of the atmosphere on astronomical adaptive optics.

    Science.gov (United States)

    Devaney, Nicholas; Goncharov, Alexander V; Dainty, J Christopher

    2008-03-10

    The atmosphere introduces chromatic errors that may limit the performance of adaptive optics (AO) systems on large telescopes. Various aspects of this problem have been considered in the literature over the past two decades. It is necessary to revisit this problem in order to examine the effect on currently planned systems, including very high-order AO on current 8-10 m class telescopes and on future 30-42 m extremely large telescopes. We review the literature on chromatic effects and combine an analysis of all effects in one place. We examine implications for AO and point out some effects that should be taken into account in the design of future systems. In particular we show that attention should be paid to chromatic pupil shifts, which may arise in components such as atmospheric dispersion compensators.

  3. Correcting the Chromatic Aberration in Barrel Distortion of Endoscopic Images

    Directory of Open Access Journals (Sweden)

    Y. M. Harry Ng

    2003-04-01

    Full Text Available Modern endoscopes offer physicians a wide-angle field of view (FOV for minimally invasive therapies. However, the high level of barrel distortion may prevent accurate perception of image. Fortunately, this kind of distortion may be corrected by digital image processing. In this paper we investigate the chromatic aberrations in the barrel distortion of endoscopic images. In the past, chromatic aberration in endoscopes is corrected by achromatic lenses or active lens control. In contrast, we take a computational approach by modifying the concept of image warping and the existing barrel distortion correction algorithm to tackle the chromatic aberration problem. In addition, an error function for the determination of the level of centroid coincidence is proposed. Simulation and experimental results confirm the effectiveness of our method.

  4. The investigation of chromatic aberration correction for digital eye fundus images

    OpenAIRE

    Jakstys, V.; Marcinkevicius, V.; Treigys, P.

    2016-01-01

    This paper focuses on the lateral chromatic aberration correction in images captured with Optomed SmartScope M5 camera. This portable non-mydriatic eye fundus orbital camera does not have chromatic lenses. When photo camera system is designed without chromatic lenses, it is necessary to apply image processing algorithms for lateral chromatic aberration effect correction. These algorithms try to scale the fringed colour channels so that all channels spatially overlap each other ...

  5. Chromatic correction in the SLC bunch length compressors

    Energy Technology Data Exchange (ETDEWEB)

    Adolphsen, C.E.; Emma, P.J.; Fieguth, T.H.; Spence, W.L.

    1991-06-01

    The SLC Ring to Linac (RTL) transport lines employ intense bending and strong transverse focusing to produce the momentum compaction needed for bunch length compression prior to S-band acceleration. In the presence of the large rf induced energy spread needed for compression the consequent chromatic effects -- viz. the variation with energy of residual output dispersion and of the RTL transfer matrix, threaten to destroy the small emittances produced by the damping rings. We report on the tuning methods that have been developed and used to implement the sextupole based chromatic correction scheme. 6 refs., 4 figs.

  6. RECURSIVE FORMULA FOR CALCULATING THE CHROMATIC POLYNOMIAL OF A GRAPH BY VERTEX DELETION

    Institute of Scientific and Technical Information of China (English)

    许进

    2004-01-01

    A new recursive vertex-deleting formula for the computation of the chromatic polynomial of a graph is obtained in this paper. This algorithm is not only a good tool for further studying chromatic polynomials but also the fastest among all the algorithms for the computation of chromatic polynomials.

  7. Electrochemical reduction of dilute chromate solutions on carbon felt electrodes

    NARCIS (Netherlands)

    Frenzel, Ines; Holdik, Hans; Barmashenko, Vladimir; Stamatialis, Dimitrios F.; Wessling, Matthias

    2006-01-01

    Carbon felt is a potential material for electrochemical reduction of chromates. Very dilute solutions may be efficiently treated due to its large specific surface area and high porosity. In this work, the up-scaling of this technology is investigated using a new type of separated cell and once-throu

  8. The operator $\\Psi$ for the Chromatic Number of a Graph

    NARCIS (Netherlands)

    N. Gvozdenovic (Nebojsa); M. Laurent (Monique)

    2007-01-01

    textabstractWe investigate hierarchies of semidefinite approximations for the chromatic number $\\chi(G)$ of a graph $G$. We introduce an operator $\\Psi$ mapping any graph parameter $\\beta(G)$, nested between the stability number $\\alpha(G)$ and $\\chi\\left( {\\ol G} \\right)$, to a new graph parameter

  9. The operator $\\Psi$ for the Chromatic Number of a Graph

    NARCIS (Netherlands)

    N. Gvozdenovic (Nebojsa); M. Laurent (Monique)

    2008-01-01

    textabstractWe investigate hierarchies of semidefinite approximations for the chromatic number $\\chi(G)$ of a graph $G$. We introduce an operator $\\Psi$ mapping any graph parameter $\\beta(G)$, nested between the stability number $\\alpha(G)$ and $\\chi\\left( {\\ol G} \\right)$, to a new graph parameter

  10. Chromatic-Spatial Vision of the Aging Eye

    Science.gov (United States)

    Werner, John S.; Delahunt, Peter B.; Hardy, Joseph L.

    2004-07-01

    The human visual system undergoes continuous anatomical, physiological and functional changes throughout the life span. There is also continuous change in the spectral distribution and intensity of light reaching the retina from infancy through senescence, primarily due to changes in the absorption of short-wave light by the lens. Despite these changes in the retinal stimulus and the signals leaving the retina for perceptual analysis, color appearance is relatively stable during aging as measured by broadband reflective or self-luminous samples, the wavelengths of unique blue and yellow, and the achromatic locus. Measures of ocular media density for younger and older observers show, indeed, that color appearance is independent of ocular media density. This may be explained by a renormalization process that was demonstrated by measuring the chromaticity of the achromatic point before and after cataract surgery. There was a shift following cataract surgery (removal of a brunescent lens) that was initially toward yellow in color space, but over the course of months, drifted back in the direction of the achromatic point before surgery. The spatial characteristics of color mechanisms were quantified for younger and older observers in terms of chromatic perceptive fields and the chromatic contrast sensitivity functions. Younger and older observers differed with small spots or with chromatic spatial gratings near threshold, but there were no significant differences with larger spots or suprathreshold spatial gratings.

  11. THE LIST CHROMATIC NUMBERS OF SOME PLANAR GRAPHS

    Institute of Scientific and Technical Information of China (English)

    LǖEnyue; ZhangKemin

    1999-01-01

    In this paper, the choosability of outerplanar graphs, 1-tree and strong 1-outerplanargraphs have been described completely. A precise upper bound of the list chromatic number of 1-outerplanar graphs is given, and that every 1-outerplanar graph with girth at least 4 is 3-choosable is proved.

  12. Pupillary response to direct and consensual chromatic light stimuli

    DEFF Research Database (Denmark)

    Traustason, Sindri; Brondsted, Adam Elias; Sander, Birgit

    2016-01-01

    PURPOSE: To assess whether the direct and consensual postillumination (ipRGC-driven) pupil light responses to chromatic light stimuli are equal in healthy subjects. METHODS: Pupil responses in healthy volunteers were recorded using a prototype binocular chromatic pupillometer (IdeaMedical, Copenh......PURPOSE: To assess whether the direct and consensual postillumination (ipRGC-driven) pupil light responses to chromatic light stimuli are equal in healthy subjects. METHODS: Pupil responses in healthy volunteers were recorded using a prototype binocular chromatic pupillometer (Idea......Medical, Copenhagen), which is capable of both direct and consensual pupillometry measurements. The device uses a pair of dual monochromatic narrow bandwidth LED light sources, red (660 nm) and blue (470 nm). Pupil light responses were recorded with infrared video cameras and analysed using custom-made circuitry...... was slightly larger during consensual illumination compared to direct illumination (0.54 and 0.52, respectively, p = 0.027, paired Wilcoxon's test, n = 12), while no differences were found for CAmax or the PIPR. CONCLUSIONS: No difference was found between direct and consensual pupil response to either red...

  13. Strong oriented chromatic number of planar graphs without short cycles

    Directory of Open Access Journals (Sweden)

    Mickaël Montassier

    2008-01-01

    Full Text Available Let M be an additive abelian group. A strong oriented coloringof an oriented graph G is a mapping φ from V(G to M such that (1 φ(u ≠ φ(v whenever uv is an arc in G and (2 φ(v - φ(u ≠ -(φ(t - φ(z whenever uv and zt are two arcs in G. We say that G has a M-strong-oriented coloring. The strong oriented chromatic number of an oriented graph, denoted by χ s (G, is the minimal order of a group M, such that G has M-strong-oriented coloring. This notion was introduced by Nešetřil and Raspaud. In this paper, we pose the following problem: Let i ≥ 4 be an integer. Let G be an oriented planar graph without cycles of lengths 4 to i. Which is the strong oriented chromatic number of G ? Our aim is to determine the impact of triangles on the strong oriented coloring. We give some hints of answers to this problem by proving that: (1 the strong oriented chromatic number of any oriented planar graph without cycles of lengths 4 to 12 is at most 7, and (2 the strong oriented chromatic number of any oriented planar graph without cycles of length 4 or 6 is at most 19.

  14. Chromatic Enumeration for Singular Maps on the Klein Bottle

    Institute of Scientific and Technical Information of China (English)

    李赵祥; 刘彦佩

    2002-01-01

    A map is singular if each edge is on the same face on a surface (i.e.,it has only one face on a surface).In this paper we present the chromatic enumeration for rooted singular maps on the Klein bottle.

  15. CHROMATIC NUMBER OF SQUARE OF MAXIMAL OUTERPLANAR GRAPHS

    Institute of Scientific and Technical Information of China (English)

    Luo Xiaofang

    2007-01-01

    Let χ(G2) denote the chromatic number of the square of a maximal outerplanar graph G and Q denote a maximal outerplanar graph obtained by adding three chords and χ(G2) = Δ + 2 if and only if G is Q, where Δ represents the maximum degree of G.

  16. Functionalized granular activated carbon and surface complexation with chromates and bi-chromates in wastewater.

    Science.gov (United States)

    Singha, Somdutta; Sarkar, Ujjaini; Luharuka, Pallavi

    2013-03-01

    Cr(VI) is present in the aqueous medium as chromate (CrO4(2-)) and bi-chromate (HCrO4(-)). Functionalized granular activated carbons (FACs) are used as adsorbents in the treatment of wastewaters containing hexavalent chromium. The FACs are prepared by chemical modifications of granular activated carbons (GACs) using functionalizing agents like HNO3, HCl and HF. The Brunauer, Emmett and Teller surface areas of FAC-HCl (693.5m(2)/g), FAC-HNO3 (648.8m(2)/g) and FAC-HF (726.2m(2)/g) are comparable to the GAC (777.7m(2)/g). But, the adsorption capacity of each of the FAC-HNO3, FAC-HCl and FAC-HF is found to be higher than the GAC. The functional groups play an important role in the adsorption process and pH has practically no role in this specific case. The FACs have hydrophilic protonated external surfaces in particular, along with the functional surface sites capable to make complexes with the CrO4(2-) and HCrO4(-) present. Surface complex formation is maximized in the order FAC-HNO3>FAC-HF>FAC-HCl, in proportion to the total surface acidity. This is also confirmed by the well-known pseudo second-order kinetic model. Physi-sorption equilibrium isotherms are parameterized by using standard Freundlich and Langmuir models. Langmuir fits better. The formation of surface complexes with the functional groups and hexavalent chromium is also revealed in the images of field emission scanning electron micrograph; energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy analysis after adsorption. The intra-particle diffusion is not the only rate-controlling factor. The Boyd's film diffusion model fits very well with R(2) as high as 98.1% for FAC-HNO3. This result demonstrates that the functionalization of the GAC by acid treatments would increase the diffusion rate, predominantly with a boundary layer diffusion effect. Copyright © 2013 Elsevier B.V. All rights reserved.

  17. Detection of Perturbation in Chromatic and Luminance-Defined Lines and Square-Waves

    Directory of Open Access Journals (Sweden)

    R.J Sharman

    2014-08-01

    Full Text Available The composition of a stimulus may affect how cues are combined. A thin luminance ring surrounding a uniform chromatic test facilitates contrast detection as much as a uniform luminance pedestal (Cole, Stromeyer & Kronauer, 1990, JOSA A, 7(1, 128-140. This could suggest that there is a specific facilitatory relationship between luminance lines and chromatic edges that is not present in other combinations. Therefore, combining luminance lines and chromatic edges could also improve performance in edge detection tasks. Here we use a novel task, perturbation detection, target gratings were sinusoidally perturbed in space and subjects were asked to detect which of two stimuli was not straight. Perturbation thresholds, were measured for chromatic and luminance defined line and square-wave gratings alone and in combination. The introduction of a line mask produced increased thresholds in all conditions. However, the introduction of a chromatic square-wave mask improved perception of perturbation in luminance lines, whereas the introduction of a luminance defined square-wave mask has little effect on the perturbation thresholds for chromatic lines. This could suggest that when a luminance line is presented with a chromatic edge, such as the chromatic boundaries in a square-wave grating, the chromatic information becomes ‘tied’ to the luminance information. The perceived location of the chromatic edge may be determined by the location of the luminance line.

  18. Chromatic aberration control for tunable all-silicone membrane microlenses.

    Science.gov (United States)

    Waibel, Philipp; Mader, Daniel; Liebetraut, Peter; Zappe, Hans; Seifert, Andreas

    2011-09-12

    Tunable multi-chamber microfluidic membrane microlenses with achromaticity over a given focal length range are demonstrated. In analogy to a fixed-focus achromatic doublet lens, the multi-lens system is based on a stack of microfluidic cavities filled with optically optimized liquids with precisely defined refractive index and Abbe number, and these are independently pneumatically actuated. The membranes separating the cavities form the refractive optical surfaces, and the curvatures as a function of pressure are calculated using a mechanical model for deformation of flexible plates. The results are combined with optical ray tracing simulations of the multi-lens system to yield chromatic aberration behavior, which is verified experimentally. A focal length tuning range of 5-40 mm and reduction in chromatic aberration of over 30% is demonstrated, limited by the availability of optical fluids.

  19. Filtering chromatic aberration for wide acceptance angle electrostatic lenses.

    Science.gov (United States)

    Fazekas, Ádám; Tóth, László

    2014-07-01

    Chromatic aberration is a major issue for imaging mainly with large acceptance angle electrostatic lenses. Its correction is necessary to take advantage of the outstanding spatial and angular resolution that these lenses provide. We propose a method to eliminate the effect of chromatic aberration on the measured images by determining the impact resulting from higher and lower kinetic energies. Based on a spectral image sequence and a matrix, which describes the transmission function of the lens, a system of linear equations is solved to approximate the 2D spectral intensity distribution of the sample surface. We present the description of our method and preliminary test results, which show significant contrast and image quality improvement. The presented algorithm can also be applied as a software-based energy analyzer.

  20. Chromatic Dispersion Monitoring Method Based on Phase Shift Technique

    Institute of Scientific and Technical Information of China (English)

    L(U) Chengang; WU Xing; ZENG Lizhu; QIN Yifan; ZU Peng; HU Zhixiong; GE Chunfeng

    2007-01-01

    The modulation phase shift method was used to measure chromatic dispersion in a standard single mode fiber for telecommunication. The modulation phase difference of the transmitted light at the wavelength of 1 532. 16 nm modulated by a radio frequency signal was measured, relative to the transmitted light at the wavelength of 1 549.33 nm modulated by the same signal. By introducing a reference light at the wavelength of 1 310 nm, a 1 310/1 550 nm wavelength division multiplexing was used instead of the high cost dense wavelength division multiplexing. In the experiment, two testing lights were coupled with the reference light to the fiber spools of different lengths, respectively. By finite difference method, the chromatic dispersion between the two testing lights was measured, and the fixed errors generated during transmission were less than 0.5 ps/(nm·km).

  1. Detection and Removal of Chromatic Moving Shadows in Surveillance Scenarios

    DEFF Research Database (Denmark)

    Casado, Ivan Huerta; Holte, Michael Boelstoft; Moeslund, Thomas B.

    2009-01-01

      Segmentation in the surveillance domain has to deal with shadows to avoid distortions when detecting moving objects. Most segmentation approaches dealing with shadow detection are typically restricted to penumbra shadows. Therefore, such techniques cannot cope well with umbra shadows....... Consequently, umbra shadows are usually detected as part of moving objects. In this paper we present a novel technique based on gradient and colour models for separating chromatic moving cast shadows from detected moving objects. Firstly, both a chromatic invariant colour cone model and an invariant gradient...... model are built to perform automatic segmentation while detecting potential shadows. In a second step, regions corresponding to potential shadows are grouped by considering "a bluish effect" and an edge partitioning. Lastly, (i) temporal similarities between textures and (ii) spatial similarities...

  2. Towards Bio-Inspired Chromatic Behaviours in Surveillance Robots

    Directory of Open Access Journals (Sweden)

    Sampath Kumar Karutaa Gnaniar

    2016-09-01

    Full Text Available The field of Robotics is ever growing at the same time as posing enormous challenges. Numerous works has been done in biologically inspired robotics emulating models, systems and elements of nature for the purpose of solving traditional robotics problems. Chromatic behaviours are abundant in nature across a variety of living species to achieve camouflage, signaling, and temperature regulation. The ability of these creatures to successfully blend in with their environment and communicate by changing their colour is the fundamental inspiration for our research work. In this paper, we present dwarf chameleon inspired chromatic behaviour in the context of an autonomous surveillance robot, “PACHONDHI”. In our experiments, we successfully validated the ability of the robot to autonomously change its colour in relation to the terrain that it is traversing for maximizing detectability to friendly security agents and minimizing exposure to hostile agents, as well as to communicate with fellow cooperating robots.

  3. Manipulation of spatiotemporal photon distribution via chromatic aberration.

    Science.gov (United States)

    Li, Yuelin; Chemerisov, Sergey

    2008-09-01

    We demonstrate a spatiotemporal laser-pulse-shaping scheme that exploits the chromatic aberration in a dispersive lens. This normally harmful effect transforms the phase modulation into a beam-size modulation at the focal plane. In combination with the intricate diffraction effect via beam apodization, this method provides a spatiotemporal control of photon distribution with an accuracy of diffraction limit on a time scale of femtoseconds.

  4. Bounds for the harmonious chromatic number of a graph

    OpenAIRE

    Krasikov, I.; Y. Roditty

    1994-01-01

    The upper bound for the harmonious chromatic number of a graph given by Zhikang Lu and by C. McDiarmid and Luo Xinhua, independently (Journal of Graph Theory, 1991, pp. 345-347 and 629-636) and the lower bound given by D. G. Beane, N. L. Biggs, and B. J. Wilson (Journal of Graph Theory, 1989, pp. 291-298) are improved.

  5. The total chromatic number of regular graphs of high degree

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The total chromatic number χT (G) of a graph G is the minimum number of colors needed to color the edges and the vertices of G so that incident or adjacent elements have distinct colors. We show that if G is a regular graph and d(G) 32 |V (G)| + 263 , where d(G) denotes the degree of a vertex in G, then χT (G) d(G) + 2.

  6. Correcting chromatic offset in multicolor super-resolution localization microscopy.

    Science.gov (United States)

    Erdelyi, Miklos; Rees, Eric; Metcalf, Daniel; Schierle, Gabriele S Kaminski; Dudas, Laszlo; Sinko, Jozsef; Knight, Alex E; Kaminski, Clemens F

    2013-05-06

    Localization based super-resolution microscopy techniques require precise drift correction methods because the achieved spatial resolution is close to both the mechanical and optical performance limits of modern light microscopes. Multi-color imaging methods require corrections in addition to those dealing with drift due to the static, but spatially-dependent, chromatic offset between images. We present computer simulations to quantify this effect, which is primarily caused by the high-NA objectives used in super-resolution microscopy. Although the chromatic offset in well corrected systems is only a fraction of an optical wavelength in magnitude (super-resolution methods is impossible without appropriate image correction. The simulated data are in excellent agreement with experiments using fluorescent beads excited and localized at multiple wavelengths. Finally we present a rigorous and practical calibration protocol to correct for chromatic optical offset, and demonstrate its efficacy for the imaging of transferrin receptor protein colocalization in HeLa cells using two-color direct stochastic optical reconstruction microscopy (dSTORM).

  7. "Tilt" in color space: Hue changes induced by chromatic surrounds.

    Science.gov (United States)

    Klauke, Susanne; Wachtler, Thomas

    2015-01-01

    The perceived color of a chromatic stimulus is influenced by the chromaticity of its surround. To investigate these influences along the dimension of hue, we measured hue changes induced in stimuli of different hues by isoluminant chromatic surrounds. Generally, induced hue changes were directed in color space away from the hue of the inducing surround and depended on the magnitude on the hue difference between stimulus and surround. With increasing difference in hue between stimulus and surround, induced hue changes increased up to a maximum and then decreased for larger differences. This qualitative pattern was similar for different inducers, but quantitatively, induction was weaker along some directions in cone-opponent color space than along other directions. The strongest induction effects were found along an oblique, blue-yellow axis that corresponds to the daylight axis. The overall pattern of the induction effect shows similarities to the well-known tilt effect, where shifts in perceived angle of oriented stimuli are induced by oriented surrounds. This suggests analogous neural representations and similar mechanisms of contextual processing for different visual features such as orientation and color.

  8. A simple handheld pupillometer for chromatic Flicker studies

    Science.gov (United States)

    Bernabei, M.; Tinarelli, R.; Peretto, L.; Rovati, L.

    2014-02-01

    A portable pupillometer has been developed which is capable of performing accurate measurements of the pupil diameter during chromatic flicker stimulations. The handheld measuring system records the near-infrared image of the pupil at the rate of 25 fps and simultaneously stimulates the eye using a diffused flicker light generated by light emitting diodes (LEDs). Intensity, frequency and chromatic coordinates of the stimulus can be easily adjusted using a user-friendly graphical interface. Thanks to a chromatic monitoring of the stimulus close to the plane of the eye, photopically matched conditions can be easily achieved. The pupil diameter/area can be measured during flickering stimuli that are generated with frequency in a range of 0.1-20 Hz. The electronic unit, properly connected to the personal computer through a USB port, drives the optical unit, which can be easily held in a hand. The software interface controlling the system was developed in LabVIEW. This paper describes the instrument optical setup, front-end electronics and data processing. Moreover preliminary results obtained on a voluntary are reported.

  9. Chromate Reduction in Serratia marcescens Isolated from Tannery Effluent and Potential Application for Bioremediation of Chromate Pollution

    Directory of Open Access Journals (Sweden)

    M.A. Mondaca

    2002-01-01

    Full Text Available Pollution of aquatic systems by heavy metals has resulted in increasing environmental concern because they cannot be biodegraded. One metal that gives reason for concern due to its toxicity is chromium. Cr(VI and Cr(III are the principal forms of chromium found in natural waters. A chromate-resistant strain of the bacterium S. marcescens was isolated from tannery effluent. The strain was able to reduce Cr(VI to Cr(III, and about 80% of chromate was removed from the medium. The reduction seems to occur on the cell surface. Transmission electron microscopic examination of cells revealed that particles were deposited on the outside of bacterial cells. A stable biofilm was formed in less than 10 h, reaching around 1010 cfu attached per milligram of activated carbon. These findings demonstrate that immobilized S. marcescens might be used in industrial waste treatment processes.

  10. A FrFT based method for measuring chromatic dispersion and SPM in optical fibers

    Science.gov (United States)

    Yang, Aiying; Liu, Xiang; Chen, Xiaoyu

    2017-03-01

    A fractional Fourier transformation based method is proposed to blindly estimate the chromatic dispersion and self phase modulation in optical fibers. The experimental results demonstrate that up to 20,000 ps/nm accumulative chromatic dispersion of a fiber link is measured with the error less than 0.8%. If the chromatic dispersion is compensated by multiplying an opposite chromatic dispersion function in frequency domain, the 1st order chirp parameter caused by SPM in an optical fiber communication system can be measured by fractional Fourier transformation based method, i.e. the accumulative SPM of a fiber link can be quantitatively measured. The results of equalizing chromatic dispersion and self phase modulation in an optical fiber communication system demonstrated that the FrFT based method is promising to blindly monitor and equalize the chromatic dispersion and SPM of the fiber link in an optical network with dynamical routing function.

  11. A method of dynamic chromatic aberration correction in low-voltage scanning electron microscopes.

    Science.gov (United States)

    Khursheed, Anjam

    2005-07-01

    A time-of-flight concept that dynamically corrects for chromatic aberration effects in scanning electron microscopes (SEMs) is presented. The method is predicted to reduce the microscope's chromatic aberration by an order of magnitude. The scheme should significantly improve the spatial resolution of low-voltage scanning electron microscopes (LVSEMs). The dynamic means of correcting for chromatic aberration also allows for the possibility of obtaining high image resolution from electron guns that have relatively large energy spreads.

  12. Chromatic Sums of Biloopless Nonseparable Near-Triangulations on the Projective Plane

    Institute of Scientific and Technical Information of China (English)

    Zhao-xiang Li; Yan-pei Liu; Bing-feng Si

    2013-01-01

    In this paper,the chromatic sum functions of rooted biloopless nonseparable near-triangulations on the sphere and the projective plane are studied.The chromatic sum function equations of such maps are obtained.From the chromatic sum equations of such maps,the enumerating function equations of such maps are derived.An asymptotic evaluation and some explicit expression of enumerating functions are also derived.

  13. Spatio-Chromatic Adaptation via Higher-Order Canonical Correlation Analysis of Natural Images

    OpenAIRE

    Gutmann, Michael U.; Valero Laparra; Aapo Hyvärinen; Jesús Malo

    2014-01-01

    Independent component and canonical correlation analysis are two general-purpose statistical methods with wide applicability. In neuroscience, independent component analysis of chromatic natural images explains the spatio-chromatic structure of primary cortical receptive fields in terms of properties of the visual environment. Canonical correlation analysis explains similarly chromatic adaptation to different illuminations. But, as we show in this paper, neither of the two methods generalizes...

  14. Mixing of Chromatic and Luminance Retinal Signals in Primate Area V1

    OpenAIRE

    Li, X.; Chen, Y.; Lashgari, R.; Bereshpolova, Y.; Swadlow, H.; Lee, B; J. Alonso

    2014-01-01

    Vision emerges from activation of chromatic and achromatic retinal channels whose interaction in visual cortex is still poorly understood. To investigate this interaction, we recorded neuronal activity from retinal ganglion cells and V1 cortical cells in macaques and measured their visual responses to grating stimuli that had either luminance contrast (luminance grating), chromatic contrast (chromatic grating), or a combination of the two (compound grating). As with parvocellular or koniocell...

  15. A local search algorithm based on chromatic classes for university course timetabling problem

    OpenAIRE

    Velin Kralev; Radoslava Kraleva

    2016-01-01

    This paper presents a study for a local search algorithm based on chromatic classes for the university course timetabling problem. Several models and approaches to resolving the problem are discussed. The main idea of the approach is through a heuristic algorithm to specify the chromatic classes of a graph in which the events of the timetable correspond to the graph vertices and the set of the edges represents the possible conflicts between events. Then the chromatic classes should be sorted ...

  16. Chromatic Sums of Nonseparable Near-Triangulations on the Projective Plane

    Institute of Scientific and Technical Information of China (English)

    Zhao Xiang LI; Wei HE

    2012-01-01

    In this paper,we study the chromatic sum functions of rooted nonseparable neartriangulations on the sphere and the projective plane.The chromatic sum function equations of such maps are obtained.From the chromatic sum equations of such maps,the enumerating function equations of such maps are derived.Applying chromatic sum theory,the enumerating problem of different sorts maps can be studied,and a new method of enumeration can be obtained.Moreover,an asymptotic evaluation and some explicit expression of enumerating functions are also derived.

  17. Removal of chromate in a permeable reactive barrier using zero-valent iron

    DEFF Research Database (Denmark)

    Kjeldsen, Peter; Locht, T

    2002-01-01

    Chromate is a commonly found groundwater contaminant. Permeable reactive barriers containing zero-valent iron as iron filings are able to remove the chromate by a combined reduction/precipitation reaction. However, due to the passivation of the reduction capability of the iron surfaces by the pre......Chromate is a commonly found groundwater contaminant. Permeable reactive barriers containing zero-valent iron as iron filings are able to remove the chromate by a combined reduction/precipitation reaction. However, due to the passivation of the reduction capability of the iron surfaces...

  18. Definition and measurement of the beam propagation factor M2 for chromatic laser beams

    Institute of Scientific and Technical Information of China (English)

    Tao Fang; Xin Ye; Jinfu Niu; Jianqiu Xu

    2006-01-01

    The concept of the beam propagation factor M2 is extended for chromatic laser beams. The definition of the beam propagation factor can be generalized with the weighted effective wavelength. Using the new definition of factor M2, the propagation of chromatic beams can be analyzed by the beam propagation factor M2 as same as that of monochromatic beams. A simple method to measure the chromatic beam factor M2 is demonstrated. The chromatic factor M2 is found invariable while the laser beam propagates through the dispersion-free ABCD system.

  19. CHROMATED COPPER ARSENATE, OR CCA ADSORPTION ON AN IRON-OXIDE ADSORBENT. (R828772)

    Science.gov (United States)

    The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

  20. Paper-based chromatic toxicity bioassay by analysis of bacterial ferricyanide reduction.

    Science.gov (United States)

    Pujol-Vila, F; Vigués, N; Guerrero-Navarro, A; Jiménez, S; Gómez, D; Fernández, M; Bori, J; Vallès, B; Riva, M C; Muñoz-Berbel, X; Mas, J

    2016-03-03

    Water quality assessment requires a continuous and strict analysis of samples to guarantee compliance with established standards. Nowadays, the increasing number of pollutants and their synergistic effects lead to the development general toxicity bioassays capable to analyse water pollution as a whole. Current general toxicity methods, e.g. Microtox(®), rely on long operation protocols, the use of complex and expensive instrumentation and sample pre-treatment, which should be transported to the laboratory for analysis. These requirements delay sample analysis and hence, the response to avoid an environmental catastrophe. In an attempt to solve it, a fast (15 min) and low-cost toxicity bioassay based on the chromatic changes associated to bacterial ferricyanide reduction is here presented. E. coli cells (used as model bacteria) were stably trapped on low-cost paper matrices (cellulose-based paper discs, PDs) and remained viable for long times (1 month at -20 °C). Apart from bacterial carrier, paper matrices also acted as a fluidic element, allowing fluid management without the need of external pumps. Bioassay evaluation was performed using copper as model toxic agent. Chromatic changes associated to bacterial ferricyanide reduction were determined by three different transduction methods, i.e. (i) optical reflectometry (as reference method), (ii) image analysis and (iii) visual inspection. In all cases, bioassay results (in terms of half maximal effective concentrations, EC50) were in agreement with already reported data, confirming the good performance of the bioassay. The validation of the bioassay was performed by analysis of real samples from natural sources, which were analysed and compared with a reference method (i.e. Microtox). Obtained results showed agreement for about 70% of toxic samples and 80% of non-toxic samples, which may validate the use of this simple and quick protocol in the determination of general toxicity. The minimum instrumentation

  1. Some Aspects of Visual Processing Under Chromatic Adaptation.

    Science.gov (United States)

    Wilson, Julie Ann Frances

    Available from UMI in association with The British Library. This thesis describes the results of experimental investigations into three types of visual processing, namely, displacement thresholds for motion detection, speed and motion detection, and rod-cone interaction effects. Each of these topics is described separately. The overall conclusions and summary of this work with an emphasis on chromatic processes are presented in the last chapter. The introductory chapter of the thesis deals mostly with the anatomical and theoretical aspects of vision and the development of a system for the standardization of colour. Equations for the CIE colour and colour difference specifications are described. Equipment, optical apparatus and general calibration procedures for all the investigations are covered in Chapter Two. Displacement thresholds for motion detection under conditions of chromatic adaptation are the subject of Chapter Three. The smallest, continuous target displacement sufficient to cause a sensation of movement was measured under conditions of chromatic adaptation. The experiments were carried out for test target and background field wavelengths which selectively isolated the activity of the colour mechanisms of the human eye. In Chapter Four, two mechanisms capable of speed discrimination and motion detection are proposed. Experimental data are reported which suggest that the visual system employs both schemes. A small circular target of high retinal illuminance level can have a comet-like appearance when presented moving continuously with a speed as low as 0.2 deg/s. Data on the parametric properties of the 'comet effect' are presented in Chapter Five. Measurement of the target spectral irradiance levels sufficient to yield the 'comet effect' suggests that the lengthening of the circular target reflects a rod-cone interaction and therefore it may be due to unsuppressed, saturated rod responses at high retinal illuminance levels. Computational methods are

  2. Temporal analysis of the topographic ERG: chromatic versus achromatic stimulation.

    Science.gov (United States)

    Klistorner, A; Crewther, D P; Crewther, S G

    1998-04-01

    The topographic electroretinogram evoked by multi-focal exchange of black and white or red and green stimuli was analysed into linear and non-linear Wiener kernels. The first-order (temporally linear) response showed a biphasic waveform which inverted as the luminance ratio of the exchanged colours passed through unity (established both psychophysically and photometrically). A short latency non-linearity which was dependant on luminance contrast was observed in both chromatic and achromatic ERG. However, in the chromatic second-order response, a long-latency non-linearity, foveally prominent, with a distinct skew in power towards the nasal retina, appeared around the isoluminant point, between the points of silent substitution for the L and M-cone types. Modelling of the second-order responses showed that over a wide range of luminance ratios, the chromatic ERG is well described by a linear combination of the achromatic (contrast-dependent) component and the response at isoluminance. The difference in second-order response between coloured and black and white stimulation, at the same luminance contrast, showed that the long-latency non-linearity is recorded when the red and green cone types are operating out of phase and peaks in amplitude at a green/red luminance ratio of 0.8. This interpretation was confirmed by the lack of the long-latency non-linearity in colour-anomalous subjects (whether deficient in the L or the M-cone type). A marked similarity exists between the properties of the long-latency non-linearity and the frequency-doubled response generated in the ganglion cells of the magnocellular pathway.

  3. Removing lateral chromatic aberration in bright field optical microscopy.

    Science.gov (United States)

    Guzmán-Altamirano, Miguel; Gutiérrez-Medina, Braulio

    2015-06-01

    We present an efficient alternative to remove lateral chromatic aberration (LCA) in bright field light microscopy images. Our procedure is based on error calibration using time-sequential acquisition at different wavelengths, and error correction through digital image warping. Measurement of the displacements of fiducial marks in the red and green images relative to blue provide calibration factors that are subsequently used in test images to realign color channels digitally. We demonstrate quantitative improvement in the position and boundaries of objects in target slides and in the color content and morphology of specimens in stained biological samples. Our results show a reduction of LCA content below the 0.1% level.

  4. Miniaturized modules for light sheet microscopy with low chromatic aberration.

    Science.gov (United States)

    Bruns, T; Bauer, M; Bruns, S; Meyer, H; Kubin, D; Schneckenburger, H

    2016-12-01

    Two miniaturized fibre-coupled modules for light sheet-based microscopy are described and compared with respect to image quality, chromatic aberration and beam alignment. Whereas in one module the light sheet is created by an achromatic cylindrical lens, reflection by a spherical mirror and concomitant astigmatic distortion are used to create the light sheet in the second module. Test experiments with fluorescent dyes in solution and multicellular tumour spheroids are reported, and some details on construction are given for both systems. Both modules are optimized for imaging individual cell layers of 3D biological samples and can be adapted to fit commercial microscopes.

  5. Chromatic Dispersion Compensation Using Photonic Crystal Fibers with Hexagonal Distribution

    Directory of Open Access Journals (Sweden)

    Erick E. Reyes-Vera

    2013-11-01

    Full Text Available In this paper we show various configurations of photonic crystal fiber with hexagonal holes distribution for compensation of chromatic dispersion in optical communications links. The vectorial finite element method with scattering boundary condition was used for the analysis of the fibers. From these results it was estimated variation of the dispersion and the dispersion slope with respect to change in the diameter of the holes in the microstructure. With the above was possible to obtain values of dispersion in the C and L bands of telecommunications close to -850 ps / nm * km, with confinement losses 10-3 dB / km

  6. Adaptive dispersion formula for index interpolation and chromatic aberration correction.

    Science.gov (United States)

    Li, Chia-Ling; Sasián, José

    2014-01-13

    This paper defines and discusses a glass dispersion formula that is adaptive. The formula exhibits superior convergence with a minimum number of coefficients. Using this formula we rationalize the correction of chromatic aberration per spectrum order. We compare the formula with the Sellmeier and Buchdahl formulas for glasses in the Schott catalogue. The six coefficient adaptive formula is found to be the most accurate with an average maximum index of refraction error of 2.91 × 10(-6) within the visible band.

  7. Automated selection of LEDs by luminance and chromaticity coordinate

    CERN Document Server

    Fischer, Ulrich H P; Reinboth, Christian

    2010-01-01

    The increased use of LEDs for lighting purposes has led to the development of numerous applications requiring a pre-selection of LEDs by their luminance and / or their chromaticity coordinate. This paper demonstrates how a manual pre-selection process can be realized using a relatively simple configuration. Since a manual selection service can only be commercially viable as long as only small quantities of LEDs need to be sorted, an automated solution suggests itself. This paper introduces such a solution, which has been developed by Harzoptics in close cooperation with Rundfunk Gernrode. The paper also discusses current challenges in measurement technology as well as market trends.

  8. Conditioned Poisson distributions and the concentration of chromatic numbers

    CERN Document Server

    Hartigan, John; Tatikonda, Sekhar

    2011-01-01

    The paper provides a simpler method for proving a delicate inequality that was used by Achlioptis and Naor to establish asymptotic concentration for chromatic numbers of Erdos-Renyi random graphs. The simplifications come from two new ideas. The first involves a sharpened form of a piece of statistical folklore regarding goodness-of-fit tests for two-way tables of Poisson counts under linear conditioning constraints. The second idea takes the form of a new inequality that controls the extreme tails of the distribution of a quadratic form in independent Poissons random variables.

  9. Automated thermal mapping techniques using chromatic image analysis

    Science.gov (United States)

    Buck, Gregory M.

    1989-01-01

    Thermal imaging techniques are introduced using a chromatic image analysis system and temperature sensitive coatings. These techniques are used for thermal mapping and surface heat transfer measurements on aerothermodynamic test models in hypersonic wind tunnels. Measurements are made on complex vehicle configurations in a timely manner and at minimal expense. The image analysis system uses separate wavelength filtered images to analyze surface spectral intensity data. The system was initially developed for quantitative surface temperature mapping using two-color thermographic phosphors but was found useful in interpreting phase change paint and liquid crystal data as well.

  10. Chromatism compensation in wide-band nulling interferometry for exoplanet detection

    NARCIS (Netherlands)

    Spronck, J.; Pereira, S.F.; Braat, J.J.M.

    2006-01-01

    We introduce the concept of chromatism compensation in nulling interferometry that enables a high rejection ratio in a wide spectral band. Therefore the achromaticity condition considered in most nulling interferometers can be relaxed. We show that this chromatism compensation cannot be applied to a

  11. Purification to Homogeneity and Characterization of a Novel Pseudomonas putida Chromate Reductase

    Science.gov (United States)

    Park, C. H.; Keyhan, M.; Wielinga, B.; Fendorf, S.; Matin, A.

    2000-01-01

    Cr(VI) (chromate) is a widespread environmental contaminant. Bacterial chromate reductases can convert soluble and toxic chromate to the insoluble and less toxic Cr(III). Bioremediation can therefore be effective in removing chromate from the environment, especially if the bacterial propensity for such removal is enhanced by genetic and biochemical engineering. To clone the chromate reductase-encoding gene, we purified to homogeneity (>600-fold purification) and characterized a novel soluble chromate reductase from Pseudomonas putida, using ammonium sulfate precipitation (55 to 70%), anion-exchange chromatography (DEAE Sepharose CL-6B), chromatofocusing (Polybuffer exchanger 94), and gel filtration (Superose 12 HR 10/30). The enzyme activity was dependent on NADH or NADPH; the temperature and pH optima for chromate reduction were 80°C and 5, respectively; and the Km was 374 μM, with a Vmax of 1.72 μmol/min/mg of protein. Sulfate inhibited the enzyme activity noncompetitively. The reductase activity remained virtually unaltered after 30 min of exposure to 50°C; even exposure to higher temperatures did not immediately inactivate the enzyme. X-ray absorption near-edge-structure spectra showed quantitative conversion of chromate to Cr(III) during the enzyme reaction. PMID:10788340

  12. Purification to homogeneity and characterization of a novel Pseudomonas putida chromate reductase

    Energy Technology Data Exchange (ETDEWEB)

    Park, C.H.; Keyhan, M.; Wielinga, B.; Fendorf, S.; Matin, A.

    2000-05-01

    Cr(VI) (chromate) is a widespread environmental contaminant. Bacterial chromate reductases can convert soluble and toxic chromate to the insoluble and less toxic Cr(III). Bioremediation can therefore be effective in removing chromate from the environment, especially if the bacterial propensity for such removal is enhanced by genetic and biochemical engineering. To clone the chromate reductase-encoding gene, the authors purified to homogeneity and characterized a novel soluble chromate reductase from Pseudomonas putida, using ammonium sulfate precipitation, anion-exchange chromatography, chromatofocusing, and gel filtration. The enzyme activity was dependent on NADH or NADPH; the temperature and pH optima for chromate reduction were 80 C and 5, respectively; and the K{sub m} was 374 {micro}M, with a V{sub max} of 1.72 {micro}mol/min/mg of protein. Sulfate inhibited the enzyme activity noncompetitively. The reductase activity remained virtually unaltered after 30 min of exposure to 50 C; even exposure to higher temperatures did not immediately inactivate the enzyme. X-ray absorption near-edge-structure spectra showed quantitative conversion of chromate to Cr(III) during the enzyme reaction.

  13. Fluctuations in the prevalence of chromate allergy in Denmark and exposure to chrome-tanned leather

    DEFF Research Database (Denmark)

    Carøe, Caroline; Andersen, Klaus E; Thyssen, Jacob P;

    2010-01-01

    A recent Danish study showed a significant increase in the prevalence of chromate contact allergy after the mid-1990s, probably as a result of exposure to leather products.......A recent Danish study showed a significant increase in the prevalence of chromate contact allergy after the mid-1990s, probably as a result of exposure to leather products....

  14. Performance Comparison of Steam-Based and Chromate Conversion Coatings on Aluminum Alloy 6060

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Jellesen, Morten Stendahl; Ambat, Rajan

    2015-01-01

    In this study, oxide layers generated on aluminum alloy 6060(UNS A96060) using a steam-based process were compared with conventional chromate and chromate-phosphate conversion coatings. Chemical composition and microstructure of the conversion coatings were investigated and their corrosion perfor...

  15. Spatio-chromatic adaptation via higher-order canonical correlation analysis of natural images.

    Directory of Open Access Journals (Sweden)

    Michael U Gutmann

    Full Text Available Independent component and canonical correlation analysis are two general-purpose statistical methods with wide applicability. In neuroscience, independent component analysis of chromatic natural images explains the spatio-chromatic structure of primary cortical receptive fields in terms of properties of the visual environment. Canonical correlation analysis explains similarly chromatic adaptation to different illuminations. But, as we show in this paper, neither of the two methods generalizes well to explain both spatio-chromatic processing and adaptation at the same time. We propose a statistical method which combines the desirable properties of independent component and canonical correlation analysis: It finds independent components in each data set which, across the two data sets, are related to each other via linear or higher-order correlations. The new method is as widely applicable as canonical correlation analysis, and also to more than two data sets. We call it higher-order canonical correlation analysis. When applied to chromatic natural images, we found that it provides a single (unified statistical framework which accounts for both spatio-chromatic processing and adaptation. Filters with spatio-chromatic tuning properties as in the primary visual cortex emerged and corresponding-colors psychophysics was reproduced reasonably well. We used the new method to make a theory-driven testable prediction on how the neural response to colored patterns should change when the illumination changes. We predict shifts in the responses which are comparable to the shifts reported for chromatic contrast habituation.

  16. Spatio-chromatic adaptation via higher-order canonical correlation analysis of natural images.

    Science.gov (United States)

    Gutmann, Michael U; Laparra, Valero; Hyvärinen, Aapo; Malo, Jesús

    2014-01-01

    Independent component and canonical correlation analysis are two general-purpose statistical methods with wide applicability. In neuroscience, independent component analysis of chromatic natural images explains the spatio-chromatic structure of primary cortical receptive fields in terms of properties of the visual environment. Canonical correlation analysis explains similarly chromatic adaptation to different illuminations. But, as we show in this paper, neither of the two methods generalizes well to explain both spatio-chromatic processing and adaptation at the same time. We propose a statistical method which combines the desirable properties of independent component and canonical correlation analysis: It finds independent components in each data set which, across the two data sets, are related to each other via linear or higher-order correlations. The new method is as widely applicable as canonical correlation analysis, and also to more than two data sets. We call it higher-order canonical correlation analysis. When applied to chromatic natural images, we found that it provides a single (unified) statistical framework which accounts for both spatio-chromatic processing and adaptation. Filters with spatio-chromatic tuning properties as in the primary visual cortex emerged and corresponding-colors psychophysics was reproduced reasonably well. We used the new method to make a theory-driven testable prediction on how the neural response to colored patterns should change when the illumination changes. We predict shifts in the responses which are comparable to the shifts reported for chromatic contrast habituation.

  17. Chromatic dispersion of liquid crystal infiltrated capillary tubes and photonic crystal fibers

    DEFF Research Database (Denmark)

    Rasmussen, Per Dalgaard; Lægsgaard, Jesper; Bang, Ole

    2006-01-01

    We consider chromatic dispersion of capillary tubes and photonic crystal fibers infiltrated with liquid crystals. A perturbative scheme for inclusion of material dispersion of both liquid crystal and the surrounding waveguide material is derived. The method is used to calculate the chromatic disp...

  18. Effects of Chromate and Non-Chromate Coating Systems on Environmentally Assisted Fatigue of an Aluminum Alloy

    Science.gov (United States)

    Schubbe, Joel J.; Westmoreland, Sophoria N.

    2014-10-01

    Fatigue crack growth testing of 2024-T3 Aluminum plate was performed using compact tension (CT) specimens with chromate and non-chromate primer paint systems to evaluate the effects of the coatings on fatigue crack growth rates. The tests were conducted in lab air and sea water environments for each of the coating systems. Standard E399 CT specimens were tested to determine the influence level of environmentally assisted cracking (corrosion fatigue) on crack growth rates and cyclic count to prescribed pre-crack and final crack lengths. Increasing stress range (Δ K) tests were conducted at 10 Hz in the range of 6.5 to 26.5 MPa. It was determined that the coated specimens exhibited a 12% shorter total life, on average, than the bare specimens for the lab air cases. In the case of salt water exposure, the coated specimens exhibited approximately 10% life increase over the bare specimens. The number of cycles to the 2.54 mm pre-crack length for the coated specimens was all less than the cycle count for the bare tests. In each case (coated or bare), there was an increased growth rate at the lower stress ranges in the salt water environment, with the chromate system case displaying the smallest change (increase). It can be concluded that the coated specimens initiate cracks and propagate faster than the bare specimens for short cracks at low stress range, but the environmental influence on the specimens is quickly overshadowed as the cracks elongate and the rate of growth increases. The coated specimens exhibited a higher total life cycle count to final crack length for this testing.

  19. The structure of chromatic polynomials of planar triangulations and implications for chromatic zeros and asymptotic limiting quantities

    Science.gov (United States)

    Shrock, Robert; Xu, Yan

    2012-06-01

    We present an analysis of the structure and properties of chromatic polynomials P(G_{pt,\\vec{m}},q) of one-parameter and multi-parameter families of planar triangulation graphs G_{pt,\\vec{m}}, where {\\vec{m}} = (m_1,\\ldots ,m_p) is a vector of integer parameters. We use these to study the ratio of |P(G_{pt,\\vec{m}},\\tau +1)| to the Tutte upper bound (τ - 1)n - 5, where \\tau =(1+\\sqrt{5} \\ )/2 and n is the number of vertices in G_{pt,\\vec{m}}. In particular, we calculate limiting values of this ratio as n → ∞ for various families of planar triangulations. We also use our calculations to analyze zeros of these chromatic polynomials. We study a large class of families G_{pt,\\vec{m}} with p = 1 and p = 2 and show that these have a structure of the form P(G_{pt,m},q) = c_{{G_{pt}},1}\\lambda _1^m + c_{{G_{pt}},2}\\lambda _2^m + c_{{G_{pt}},3}\\lambda _3^m for p = 1, where λ1 = q - 2, λ2 = q - 3, and λ3 = -1, and P(G_{pt,\\vec{m}},q) = \\sum _{i_1=1}^3 \\sum _{i_2=1}^3 c_{{G_{pt}},i_1 i_2} \\lambda _{i_1}^{m_1}\\lambda _{i_2}^{m_2} for p = 2. We derive properties of the coefficients c_{{G_{pt}},\\vec{i}} and show that P(G_{pt,\\vec{m}},q) has a real chromatic zero that approaches (1/2)(3+\\sqrt{5} \\ ) as one or more of the mi → ∞. The generalization to p ⩾ 3 is given. Further, we present a one-parameter family of planar triangulations with real zeros that approach 3 from below as m → ∞. Implications for the ground-state entropy of the Potts antiferromagnet are discussed.

  20. Construction of special eye models for investigation of chromatic and higher-order aberrations of eyes.

    Science.gov (United States)

    Zhai, Yi; Wang, Yan; Wang, Zhaoqi; Liu, Yongji; Zhang, Lin; He, Yuanqing; Chang, Shengjiang

    2014-01-01

    An achromatic element eliminating only longitudinal chromatic aberration (LCA) while maintaining transverse chromatic aberration (TCA) is established for the eye model, which involves the angle formed by the visual and optical axis. To investigate the impacts of higher-order aberrations on vision, the actual data of higher-order aberrations of human eyes with three typical levels are introduced into the eye model along visual axis. Moreover, three kinds of individual eye models are established to investigate the impacts of higher-order aberrations, chromatic aberration (LCA+TCA), LCA and TCA on vision under the photopic condition, respectively. Results show that for most human eyes, the impact of chromatic aberration on vision is much stronger than that of higher-order aberrations, and the impact of LCA in chromatic aberration dominates. The impact of TCA is approximately equal to that of normal level higher-order aberrations and it can be ignored when LCA exists.

  1. A local search algorithm based on chromatic classes for university course timetabling problem

    Directory of Open Access Journals (Sweden)

    Velin Kralev

    2016-12-01

    Full Text Available This paper presents a study for a local search algorithm based on chromatic classes for the university course timetabling problem. Several models and approaches to resolving the problem are discussed. The main idea of the approach is through a heuristic algorithm to specify the chromatic classes of a graph in which the events of the timetable correspond to the graph vertices and the set of the edges represents the possible conflicts between events. Then the chromatic classes should be sorted according to specific sort criteria (a total weight or a total count of events in each class, and finally the local search algorithm starts. The aim of the experiments is to determine the best criterion to sort chromatic classes. The results showed that the algorithm generates better solutions when the chromatic classes are sorted in a total weight criterion.

  2. Corrosion inhibition mechanisms of aluminum alloy 2024-T3 by selected non-chromate inhibitors

    Science.gov (United States)

    Lopez-Garrity, Omar A.

    The pursuit to find a chromate-alternative has led to the development of several chromate-free aerospace primers and coating systems that offer good protection. However, fundamental understanding of the functionality of the chromate-free pigments that are embedded within these coating systems is lacking. The objective of this study was to understand the fundamental mechanism of corrosion inhibition of aluminum alloy 2024-T3 by molybdate (MoO 42-), silicate (SiO32-), and praseodymium (Pr3+) with the goal of developing the kind of understanding that was accomplished for chromate. Furthermore, since most inhibiting conversion coatings and pigments act by releasing soluble species into the local environment, it was of interest to understand the mechanism of inhibition in aqueous 0.1 M NaCl solution. The mechanism of inhibition of AA2024-T3 by the select non-chromate inhibitors was investigated using various electrochemical, microscopic and spectroscopic techniques. Naturally aerated polarization curves showed that molybdate provided mixed inhibition in near-neutral pH and at a threshold concentration of 0.1 M. The largest effect was a 250 mV increase in the breakdown potential associated with pitting and a 350 mV decrease in the open-circuit potential (OCP). In addition, electrochemical impedance indicated that the corrosion inhibition mechanism is oxygen-dependent owing to the protection afforded by Mo(VI) species. It was proposed that the corrosion inhibition of AA2024-T3 by molybdate may occur following a two-step process whereby molybdate is rapidly reduced to MoO.(OH)2 over the intermetallic particles and is subsequently oxidized to intermediate molybdenum oxides (e.g. Mo4O11) in the presence of oxygen which is reduced. This in turn may lead to a local acidification, promoting the condensation and polymerization of molybdate species in solution to form polymolybdate species (Mo7O24 6- and Mo8O264-). Furthermore, S-phase particle dissolution is decreased

  3. Chromatic instabilities in cesium-doped tungsten bronze nanoparticles

    Science.gov (United States)

    Adachi, Kenji; Ota, Yosuke; Tanaka, Hiroyuki; Okada, Mika; Oshimura, Nobumitsu; Tofuku, Atsushi

    2013-11-01

    Nanoparticles of alkali-doped tungsten bronzes are an excellent near-infrared shielding material, but exhibit slight chromatic instabilities typically upon applications of strong ultra-violet light or heating in humid environment, which acts detrimentally to long-life commercial applications. Origin of the chromatic instabilities in cesium-doped tungsten bronze has been investigated, and it has been found that the coloration and bleaching processes comprised electronic exchanges which accelerate or depress the polaron excitation and the localized surface plasmon resonance. Coloration on UV illumination is evidenced by electron diffraction as due to the formation of HxWO3, which is considered to take place in the surface Cs-deficient WO3 region via the double charge injection mechanism. On the other hand, bleaching on heating in air and in humid environment is shown to accompany the extraction of Cs and electrons from Cs0.33WO3 by X-ray photoelectron spectroscopy and X-ray diffraction analysis and is concluded to be an oxidation of Cs0.33WO3 on the particle surface.

  4. The History of the Total Chromatic Number Conjecture

    CERN Document Server

    Shahmohamad, Hossein

    2011-01-01

    The total chromatic number conjecture which has appeared in a few hundred articles and in numerous books thus far is now one of the classic mathematical unsolved problems. It appears that many authors coincidentally have attributed it to Professor M. Behzad and/or to Professor V. G. Vizing. Eventually after four decades, Professor A. Soifer investigated the origin of this conjecture; published his findings in The Mathematical Coloring Book - 2009; and stated that, "In my opinion this unquestionably merits the joint credit to Vizing and Behzad." After checking all the arguments presented and the blames cited, I decided to investigate the controversy stated in this book on my own. My findings which are presented in this report specifically signify the following two points. - M. Behzad is the sole author of the Total Chromatic Number Conjecture. - The wrong referrals provided by numerous authors over the last forty four years, to indicate Vizing's authorship, must be brought to the attention of the authors and r...

  5. Chromatic settings and the structural color constancy index.

    Science.gov (United States)

    Roca-Vila, Jordi; Parraga, C Alejandro; Vanrell, Maria

    2013-03-11

    Color constancy is usually measured by achromatic setting, asymmetric matching, or color naming paradigms, whose results are interpreted in terms of indexes and models that arguably do not capture the full complexity of the phenomenon. Here we propose a new paradigm, chromatic setting, which allows a more comprehensive characterization of color constancy through the measurement of multiple points in color space under immersive adaptation. We demonstrated its feasibility by assessing the consistency of subjects' responses over time. The paradigm was applied to two-dimensional (2-D) Mondrian stimuli under three different illuminants, and the results were used to fit a set of linear color constancy models. The use of multiple colors improved the precision of more complex linear models compared to the popular diagonal model computed from gray. Our results show that a diagonal plus translation matrix that models mechanisms other than cone gain might be best suited to explain the phenomenon. Additionally, we calculated a number of color constancy indices for several points in color space, and our results suggest that interrelations among colors are not as uniform as previously believed. To account for this variability, we developed a new structural color constancy index that takes into account the magnitude and orientation of the chromatic shift in addition to the interrelations among colors and memory effects.

  6. Chromatic, Phenolic and Antioxidant Properties of Sorghum bicolor Genotypes

    Directory of Open Access Journals (Sweden)

    José Juan LÓPEZ-CONTRERAS

    2015-12-01

    Full Text Available Chromatic, phenolic and antioxidant properties were evaluated in ten sorghum genotypes grown in Nuevo León, México. Lightness, Chroma and hue angle ranged from 64 to 83, 12 to 20 and 61 to 82 respectively, indicating that colour of the samples were located in the gray orange-yellow zone of the hue circle. Based on these results, samples were classified in three colour groups being Very Soft Orange, Slightly Desaturated Orange and Grayish Orange. Results in phenolics ranged from 796 to 15,949, 175 to 12,674 and 193 to 25,780 µgCE g-1 in total phenolics by Folin-Ciocalteu, total flavonoids by Aluminum Chloride and condensed tannins by Vanillin-HCl respectively. On the other hand, antioxidant capacity ranged from 1.20 to 93.83, 30.25 to 156.08 and 2.62 to 98.50 μmolTE g-1 in 2,2-diphenyl-1-picrylhydrazyl, 3-ethyl-benzothiazoline-6-sulfonic acid and Ferric Reducing Antioxidant Power respectively. Significant differences (p≤0.05 were observed in statistical analysis for both individual and group colour samples in chromatic, phenolics and antioxidant activity evaluations, showing ‘Rox Orange’ genotype and Grayish Orange colour group the highest levels.

  7. Chromatic instabilities in cesium-doped tungsten bronze nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Adachi, Kenji, E-mail: kenji-adachi@ni.smm.co.jp; Ota, Yosuke; Tanaka, Hiroyuki; Okada, Mika; Oshimura, Nobumitsu; Tofuku, Atsushi [Ichikawa Research Laboratories, Sumitomo Metal Mining Co., Ltd., Ichikawa 272-8588 (Japan)

    2013-11-21

    Nanoparticles of alkali-doped tungsten bronzes are an excellent near-infrared shielding material, but exhibit slight chromatic instabilities typically upon applications of strong ultra-violet light or heating in humid environment, which acts detrimentally to long-life commercial applications. Origin of the chromatic instabilities in cesium-doped tungsten bronze has been investigated, and it has been found that the coloration and bleaching processes comprised electronic exchanges which accelerate or depress the polaron excitation and the localized surface plasmon resonance. Coloration on UV illumination is evidenced by electron diffraction as due to the formation of H{sub x}WO{sub 3}, which is considered to take place in the surface Cs-deficient WO{sub 3} region via the double charge injection mechanism. On the other hand, bleaching on heating in air and in humid environment is shown to accompany the extraction of Cs and electrons from Cs{sub 0.33}WO{sub 3} by X-ray photoelectron spectroscopy and X-ray diffraction analysis and is concluded to be an oxidation of Cs{sub 0.33}WO{sub 3} on the particle surface.

  8. Chromatic alteration on marble surfaces analysed by molecular biology tools

    Directory of Open Access Journals (Sweden)

    Franco Palla

    2007-07-01

    Full Text Available The patina represents a superficial natural alteration of the constituting matter of the work of art. It emerges from the natural and usual stabilization process that the materials of the surface undergo because of the interaction with outdoor agents characterizing the surrounding environment. Besides, it is not linked to an obvious phenomenon of degradation that can be noticed through the change in the original colour of the matter. This is what we intend when we talk about biological patina usually generated by macro and/or micro-organic colonization (fungi, bacteria, alga which contributes to surface bio-deterioration and thus lead to the formation of orange, red or even brown and dark pigmented areas. The presence of chromatic alterations (rose-coloured areas, as a consequence of bacterial colonization, was most particularly pointed out in different sites, such as in the marble slabs on the facades of both the Cathedral of Siena (Duomo di Siena and the Certosa of Pavia. The present study shows an example of chromatic alteration of the surface of marble works due to bacterial colonization.

  9. Copper allergy from dental copper amalgam?

    Science.gov (United States)

    Gerhardsson, Lars; Björkner, Bert; Karlsteen, Magnus; Schütz, Andrejs

    2002-05-06

    A 65-year-old female was investigated due to a gradually increasing greenish colour change of her plastic dental splint, which she used to prevent teeth grinding when sleeping. Furthermore, she had noted a greenish/bluish colour change on the back of her black gloves, which she used to wipe her tears away while walking outdoors. The investigation revealed that the patient had a contact allergy to copper, which is very rare. She had, however, had no occupational exposure to copper. The contact allergy may be caused by long-term exposure of the oral mucosa to copper from copper-rich amalgam fillings, which were frequently used in childhood dentistry up to the 1960s in Sweden. The deposition of a copper-containing coating on the dental splint may be caused by a raised copper intake from drinking water, increasing the copper excretion in saliva, in combination with release of copper due to electrochemical corrosion of dental amalgam. The greenish colour change of the surface of the splint is probably caused by deposition of a mixture of copper compounds, e.g. copper carbonates. Analysis by the X-ray diffraction technique indicates that the dominant component is copper oxide (Cu2O and CuO). The corresponding greenish/bluish discoloration observed on the back of the patient's gloves may be caused by increased copper excretion in tears.

  10. Copper Products Capacity Expansion Stimulate the Copper Consumption

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    <正>The dramatic growth of copper consumption in China can directly be seen from the expansion of copper products capacity.According to sta- tistics,in the past 4 years,the improvement on the balance of trade on copper bar,copper,and copper alloy and copper wire & cable has driven the growth of copper consumption a lot.

  11. Antwerp Copper Plates

    DEFF Research Database (Denmark)

    Wadum, Jørgen

    1999-01-01

    In addition to presenting a short history of copper paintings, topics detail artists’ materials and techniques, as well as aspects of the copper industry, including mining, preparation and trade routes.......In addition to presenting a short history of copper paintings, topics detail artists’ materials and techniques, as well as aspects of the copper industry, including mining, preparation and trade routes....

  12. Molecular Dynamics of the Shewanella oneidensis Response to Chromate Stress

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Steven D [ORNL; Thompson, Melissa R [ORNL; Verberkmoes, Nathan C [ORNL; Chourey, Karuna [ORNL; Shah, Manesh B [ORNL; Zhou, Jizhong [ORNL; Hettich, Robert {Bob} L [ORNL; Thompson, Dorothea K [ORNL

    2006-01-01

    Temporal genomic profiling and whole-cell proteomic analyses were performed to characterize the dynamic molecular response of the metal-reducing bacterium Shewanella oneidensis MR-1 to an acute chromate shock. The complex dynamics of cellular processes demand the integration of methodologies that describe biological systems at the levels of regulation, gene and protein expression, and metabolite production. Genomic microarray analysis of the transcriptome dynamics of midexponential phase cells subjected to 1 mM potassium chromate (K2CrO4) at exposure time intervals of 5, 30, 60, and 90 min revealed 910 genes that were differentially expressed at one or more time points. Strongly induced genes included those encoding components of a TonB1 iron transport system (tonB1-exbB1-exbD1), hemin ATP-binding cassette transporters (hmuTUV), TonB-dependent receptors as well as sulfate transporters (cysP, cysW-2, and cysA-2), and enzymes involved in assimilative sulfur metabolism (cysC, cysN, cysD, cysH, cysI, and cysJ). Transcript levels for genes with annotated functions in DNA repair (lexA, recX, recA, recN, dinP, and umuD), cellular detoxification (so1756, so3585, and so3586), and two-component signal transduction systems (so2426) were also significantly upregulated (p < 0.05) in Cr(VI)-exposed cells relative to untreated cells. By contrast, genes with functions linked to energy metabolism, particularly electron transport (e.g. so0902-03-04, mtrA, omcA, and omcB), showed dramatic temporal alterations in expression with the majority exhibiting repression. Differential proteomics based on multidimensional HPLC-MS/MS was used to complement the transcriptome data, resulting in comparable induction and repression patterns for a subset of corresponding proteins. In total, expression of 2,370 proteins were confidently verified with 624 (26%) of these annotated as hypothetical or conserved hypothetical proteins. The initial response of S. oneidensis to chromate shock appears to

  13. Copper and copper proteins in Parkinson's disease.

    Science.gov (United States)

    Montes, Sergio; Rivera-Mancia, Susana; Diaz-Ruiz, Araceli; Tristan-Lopez, Luis; Rios, Camilo

    2014-01-01

    Copper is a transition metal that has been linked to pathological and beneficial effects in neurodegenerative diseases. In Parkinson's disease, free copper is related to increased oxidative stress, alpha-synuclein oligomerization, and Lewy body formation. Decreased copper along with increased iron has been found in substantia nigra and caudate nucleus of Parkinson's disease patients. Copper influences iron content in the brain through ferroxidase ceruloplasmin activity; therefore decreased protein-bound copper in brain may enhance iron accumulation and the associated oxidative stress. The function of other copper-binding proteins such as Cu/Zn-SOD and metallothioneins is also beneficial to prevent neurodegeneration. Copper may regulate neurotransmission since it is released after neuronal stimulus and the metal is able to modulate the function of NMDA and GABA A receptors. Some of the proteins involved in copper transport are the transporters CTR1, ATP7A, and ATP7B and the chaperone ATOX1. There is limited information about the role of those biomolecules in the pathophysiology of Parkinson's disease; for instance, it is known that CTR1 is decreased in substantia nigra pars compacta in Parkinson's disease and that a mutation in ATP7B could be associated with Parkinson's disease. Regarding copper-related therapies, copper supplementation can represent a plausible alternative, while copper chelation may even aggravate the pathology.

  14. The use of chromatic information for motion segmentation: differences between psychophysical and eye-movement measures.

    Science.gov (United States)

    Dobkins, Karen R; Sampath, Vanitha

    2008-01-01

    Previous psychophysical studies have shown that chromatic (red/green) information can be used as a segmentation cue for motion integration. We investigated the mechanisms mediating this phenomenon by comparing chromatic effects (and, for comparison, luminance effects) on motion integration between two measures: (i) directional eye movements with the notion that these responses are mediated mainly by low-level motion mechanisms, and (ii) psychophysical reports, with the notion that subjects' reports should employ higher-level (attention-based) mechanisms if available. To quantify chromatic (and luminance) effects on motion integration, coherent motion thresholds were obtained for two conditions, one in which the signal and noise dots were the same 'red' or 'green' chromaticity (or the same 'bright' or 'dark' luminance), referred to as homogeneous, and the other in which the signal and noise dots were of different chromaticities (or luminances), referred to as heterogeneous. 'Benefit ratios' (theta(HOM)/theta(HET)) were then computed, with values significantly greater than 1.0 indicating that chromatic (or luminance) information serves as a segmentation cue for motion integration. The results revealed a high and significant chromatic benefit ratio when the measure was based on psychophysical report, but not when it was based on an eye-movement measure. By contrast, luminance benefit ratios were roughly the same (and significant) for both measures. For comparison to adults, eye-movement data were also obtained from 3-month-old infants. Infants showed marginally significant benefit ratios in the luminance, but not in the chromatic, condition. In total, these results suggest that the use of chromatic information as a segmentation cue for motion integration relies on higher-level mechanisms, whereas luminance information works mainly through low-level motion mechanisms.

  15. Refractive and diffractive neutron optics with reduced chromatic aberration

    DEFF Research Database (Denmark)

    Poulsen, Stefan Othmar; Poulsen, Henning Friis; Bentley, P.M.

    2014-01-01

    by the use of optics for focusing and imaging. Refractive and diffractive optical elements, e.g. compound refractive lenses and Fresnel zone plates, are attractive due to their low cost, and simple alignment. These optical elements, however, suffer from chromatic aberration, which limit their effectiveness...... path to focus and image a time-of-flight beam, and (2) a passive optical element consisting of a compound refractive lens, and a Fresnel zone plate, which may focus and image both continuous and pulsed neutron beams....... to highly monochromatic beams. This paper presents two novel concepts for focusing and imaging non-monochromatic thermal neutron beams with well-known optical elements: (1) a fast mechanical transfocator based on a compound refractive lens, which actively varies the number of individual lenses in the beam...

  16. Toward the identification of DSLR lenses by chromatic aberration

    Science.gov (United States)

    Yu, Jun; Craver, Scott; Li, Enping

    2011-02-01

    While previous work on lens identification by chromatic aberration succeeded in distinguishing lenses of different model, the CA patterns obtained were not stable enough to support distinguishing different copies of the same lens. This paper discusses on how to eliminate two major hurdles in the way of obtaining a stable lens CA pattern. The first hurdle was overcome by using a white noise pattern as shooting target to supplant the conventional but misalignment-prone checkerboard pattern. The second hurdle was removed by the introduction of the lens focal distance, which had not received the attention it deserves. Consequently, we were able to obtain a stable enough CA pattern distinguishing different copies of the same lens. Finally, with a complete view of the lens CA pattern feature space, it is possible to fulfil lens identification among a large lens database.

  17. Chromatic aftereffects associated with a night vision goggle simulation.

    Science.gov (United States)

    Moffitt, K; Rogers, S P; Cicinelli, J

    1988-02-01

    A visual perception experiment was conducted to determine the chromatic aftereffects of viewing a yellow-green field that simulated the display of current night vision goggles. Six females and two males served as subjects in a color-naming procedure. Subjects sequentially viewed an adaptation field, which was either yellow-green or white, and small colored targets presented on a CRT display. The time required to name the color of the targets was found to be dependent on the color of the adaptation field, the color of the target, and the interaction of these two variables. It was recommended that the effects of attenuation of the luminance of the night vision goggles be studied, and that color cockpit displays be redundantly coded whenever possible.

  18. On the game chromatic number of sparse random graphs

    CERN Document Server

    Frieze, Alan; Lavrov, Mikhail

    2012-01-01

    Given a graph G and an integer k, two players take turns coloring the vertices of G one by one using k colors so that neighboring vertices get different colors. The first player wins iff at the end of the game all the vertices of $G$ are colored. The game chromatic number \\chi_g(G) is the minimum k for which the first player has a winning strategy. The paper \\cite{BFS} began the analysis of the asymptotic behavior of this parameter for a random graph G_{n,p}. This paper provides some further analysis for graphs with constant average degree i.e. np=O(1) and for random regular graphs.

  19. Chromatic perception of non-invasive lighting of cave paintings

    Science.gov (United States)

    Zoido, Jesús; Vazquez, Daniel; Álvarez, Antonio; Bernabeu, Eusebio; García, Ángel; Herraez, Juán A.; del Egido, Marian

    2009-08-01

    This work is intended to deal with the problems which arise when illuminanting Paleolithic cave paintings. We have carried out the spectral and colorimetric characterization of some paintings located in the Murcielagos (bats) cave (Zuheros, Córdoba, Spain). From this characterization, the chromatic changes produced under different lighting conditions are analysed. The damage function is also computed for the different illuminants used. From the results obtained, it is proposed an illuminant whose spectral distribution diminishes the damage by minimizing the absorption of radiation and optimises the color perception of the paintings in this cave. The procedure followed in this study can be applied to optimise the lighting systems used when illuminating any other art work

  20. Chromatically Corrected Imaging Systems for Charged-Particle Radiography

    CERN Document Server

    Blind, Barbara

    2005-01-01

    In proton radiography, imaging with systems consisting of quadrupole magnets is an established technique for viewing the material distribution and composition of objects, either statically or during fast events such as explosions. With the most favorable magnet configuration, the -I lens, chromatic aberrations generally dominate the image blur. Image resolution can be improved, and largely decoupled from the input-beam parameters, by using a second-order achromatic bend with some additional higher-order aberration correction. The aberration-correction approach is discussed. For a given resolution, such a bend allows use of much lower-energy imaging particles than a -I lens. Each bend design represents a set of equivalent systems; an 800-MeV proton design and its equivalent 40-MeV electron system are presented. The electron system is useful for imaging small objects. Magnet errors in the achromatic bends must be tightly controlled to preserve image quality, but not beyond feasibility of present technology. Sys...

  1. Responding to color: the regulation of complementary chromatic adaptation.

    Science.gov (United States)

    Kehoe, David M; Gutu, Andrian

    2006-01-01

    The acclimation of photosynthetic organisms to changes in light color is ubiquitous and may be best illustrated by the colorful process of complementary chromatic adaptation (CCA). During CCA, cyanobacterial cells change from brick red to bright blue green, depending on their light color environment. The apparent simplicity of this spectacular, photoreversible event belies the complexity of the cellular response to changes in light color. Recent results have shown that the regulation of CCA is also complex and involves at least three pathways. One is controlled by a phytochrome-class photoreceptor that is responsive to green and red light and a complex two-component signal transduction pathway, whereas another is based on sensing redox state. Studies of CCA are uncovering the strategies used by photosynthetic organisms during light acclimation and the means by which they regulate these responses.

  2. Chromatic Shadow Detection and Tracking for Moving Foreground Segmentation

    DEFF Research Database (Denmark)

    Huerta, Ivan; Holte, Michael Boelstoft; Moeslund, Thomas B.

    2015-01-01

    Advanced segmentation techniques in the surveillance domain deal with shadows to avoid distortions when detecting moving objects. Most approaches for shadow detection are still typically restricted to penumbra shadows and cannot cope well with umbra shadows. Consequently, umbra shadow regions...... are usually detected as part of moving objects, thus affecting the performance of the final detection. In this paper we address the detection of both penumbra and umbra shadow regions. First, a novel bottom-up approach is presented based on gradient and colour models, which successfully discriminates between...... chromatic moving cast shadow regions and those regions detected as moving objects. In essence, those regions corresponding to potential shadows are detected based on edge partitioning and colour statistics. Subsequently (i) temporal similarities between textures and (ii) spatial similarities between...

  3. Removal of Chromate Ions from Water by Anionicc CLAYS

    Science.gov (United States)

    Houri, B.; Legrouri, A.; Barroug, A.; Forano, C.; Besse, J.-P.

    1999-03-01

    The removal of chromate ions from aqueous solutions by [Mg-Al-Cl], [Zn-Al-Cl] and [Zn-Cr-Cl] anionic clays was investigated. The solids, prepared by coprecipitation at constant pH, were found to be pure upon characterisation by X-ray diffraction and Fourier-transform infrared spectroscopy. The interaction of the solid materials with CrO42- ions has been studied by UV-visible spectroscopy. The treatment of solutions containing 15 to 300 ppm of CrO42- was successful. The sorption capacities of the anionic clays for the CrO42- ions are close to 1 mmol/g. L'élimination des ions chromate de solutions aqueuses par les argiles anioniques [Mg-Al-Cl], [Zn-Al-Cl] et [Zn-Cr-Cl] a été étudiée. Les solides, préparés par coprécipitation à pH constant, ont été caractérisés par diffraction des rayons X et spectroscopie infrarouge à transformée de Fourier. L'interaction de ces matériaux avec les ions CrO42- a été suivie par spectroscopie UV-visible. Le traitement de solutions contenant de 15 à 300 ppm de CrO42- a donné de bons résultats. La capacité d'élimination de ces argiles anioniques pour les ions CrO42- est d'environ 1 mmol/g. .

  4. Measurement of chromatic aberration in STEM and SCEM by coherent convergent beam electron diffraction.

    Science.gov (United States)

    Zheng, C L; Etheridge, J

    2013-02-01

    A simple method is described for the accurate and precise measurement of chromatic aberration under electron-optical conditions pertinent to scanning transmission electron microscopy (STEM) and scanning confocal electron microscopy (SCEM). The method requires only the measurement of distances in a coherent CBED pattern and knowledge of the electron wavelength and the lattice spacing of a calibration specimen. The chromatic aberration of a spherical-aberration corrected 300 kV thermal field emission TEM is measured in STEM and SCEM operating modes and under different condenser lens settings. The effect of the measured chromatic aberrations on the 3 dimensional intensity distribution of the electron probe is also considered.

  5. Explicit and probabilistic constructions of distance graphs with small clique numbers and large chromatic numbers

    Science.gov (United States)

    Kupavskii, A. B.

    2014-02-01

    We study distance graphs with exponentially large chromatic numbers and without k-cliques, that is, complete subgraphs of size k. Explicit constructions of such graphs use vectors in the integer lattice. For a large class of graphs we find a sharp threshold for containing a k-clique. This enables us to improve the lower bounds for the maximum of the chromatic numbers of such graphs. We give a new probabilistic approach to the construction of distance graphs without k-cliques, and this yields better lower bounds for the maximum of the chromatic numbers for large k.

  6. Advances Towards the Measurement and Control of LHC Tune and Chromaticity

    CERN Document Server

    Cameron, P; Degen, C; Della Penna, A; Hoff, L T; Mead, J; Sikora, R

    2005-01-01

    Requirements for tune and chromaticity control in most superconducting hadron machines, and in particular the LHC, are stringent. In order to reach nominal operation, the LHC will almost certainly require feedback on both tune and chromaticity. Experience at RHIC has also shown that coupling control is crucial to successful tune feedback. A prototype baseband PLL tune measurement system, intended for the LHC, has recently been brought into operation at RHIC. We report on the performance of that system and compare it with the extensive accumulation of data from the RHIC 245MHz PLL. In addition the implementation of coupling and chromaticity feedback using PLL systems will be discussed.

  7. A Genetic Algorithm for Chromaticity Correction in Diffraction Limited Storage Rings

    CERN Document Server

    Ehrlichman, Michael

    2016-01-01

    An multi-objective genetic algorithm is developed for optimizing nonlinearities in diffraction limited storage rings. This algorithm determines sextupole and octupole strengths for chromaticity correction that deliver optimized dynamic aperture and beam lifetime. The algorithm makes use of dominance constraints to breed desirable properties into the early generations. The momentum aperture is optimized indirectly by constraining the chromatic tune footprint and optimizing the off-energy dynamic aperture. The result is an effective and computationally efficient technique for correcting chromaticity in a storage ring while maintaining optimal dynamic aperture and beam lifetime. This framework was developed for the Swiss Light Source (SLS) upgrade project.

  8. Very-long-term and short-term chromatic adaptation: Are their influences cumulative?

    OpenAIRE

    Belmore, Suzanne C.; Shevell, Steven K.

    2010-01-01

    Very-long-term (VLT) chromatic adaptation results from exposure to an altered chromatic environment for days or weeks. Color shifts from VLT adaptation are observed hours or days after leaving the altered environment. Short-term chromatic adaptation, on the other hand, results from exposure for a few minutes or less, with color shifts measured within seconds or a few minutes after the adapting light is extinguished; recovery to the pre-adapted state is complete in less than an hour. Here, bot...

  9. Flat Supercontinuum Generated in a Single-Mode Optical Fibre with a New Chromatic Dispersion Profile

    Institute of Scientific and Technical Information of China (English)

    XU Yong-Zhao; REN Xiao-Min; ZHANG Xia; HUANG Yong-Qing; XU Wen-Cheng

    2005-01-01

    @@ A new chromatic dispersion profile of a single-mode opticalfibre is proposed for generating a supercontinuum with a flatly broadened spectrum. The chromatic dispersion D( λ, z) is a convex function of wavelengths and has no zero-dispersion wavelengths over the whole part of thefibre as D(λ, z) is negative. It is shown that the flat supercontinuum spectrum is obtained when the pump wavelength is set in the vicinity of the wavelength at which the peak chromatic dispersion is near zero and the strong residual pump component is eliminated.

  10. Characterization and genomic analysis of chromate resistant and reducing Bacillus cereus strain SJ1

    Directory of Open Access Journals (Sweden)

    He Minyan

    2010-08-01

    Full Text Available Abstract Background Chromium is a toxic heavy metal, which primarily exists in two inorganic forms, Cr(VI and Cr(III. Chromate [Cr(VI] is carcinogenic, mutational, and teratogenic due to its strong oxidizing nature. Biotransformation of Cr(VI to less-toxic Cr(III by chromate-resistant and reducing bacteria has offered an ecological and economical option for chromate detoxification and bioremediation. However, knowledge of the genetic determinants for chromate resistance and reduction has been limited so far. Our main aim was to investigate chromate resistance and reduction by Bacillus cereus SJ1, and to further study the underlying mechanisms at the molecular level using the obtained genome sequence. Results Bacillus cereus SJ1 isolated from chromium-contaminated wastewater of a metal electroplating factory displayed high Cr(VI resistance with a minimal inhibitory concentration (MIC of 30 mM when induced with Cr(VI. A complete bacterial reduction of 1 mM Cr(VI was achieved within 57 h. By genome sequence analysis, a putative chromate transport operon, chrIA1, and two additional chrA genes encoding putative chromate transporters that likely confer chromate resistance were identified. Furthermore, we also found an azoreductase gene azoR and four nitroreductase genes nitR possibly involved in chromate reduction. Using reverse transcription PCR (RT-PCR technology, it was shown that expression of adjacent genes chrA1 and chrI was induced in response to Cr(VI but expression of the other two chromate transporter genes chrA2 and chrA3 was constitutive. In contrast, chromate reduction was constitutive in both phenotypic and gene expression analyses. The presence of a resolvase gene upstream of chrIA1, an arsenic resistance operon and a gene encoding Tn7-like transposition proteins ABBCCCD downstream of chrIA1 in B. cereus SJ1 implied the possibility of recent horizontal gene transfer. Conclusion Our results indicate that expression of the chromate

  11. Measurement of Stratospheric Chromatic Scintillation with the AMON-RA Balloonborne Spectrometer.

    Science.gov (United States)

    Renard, J B; Dalaudier, F; Hauchecorne, A; Robert, C; Lemaire, T; Pirre, M; Bertaux, J L

    2001-08-20

    The balloonborne instrument AMON (which is a French acronym for Absorption par les Minoritaires Ozone et NO(x)) has been modified to record chromatic scintillation during stellar occultation by the Earth's atmosphere. A 14-channel spectrophotometer with a sampling rate of 10 Hz was added, and the modified instrument, AMON-RA, performed successful measurements of the setting star Alnilam during the third European Stratospheric Experiment on Ozone (THESEO) project. Unambiguous records of the chromatic scintillation were obtained, to our knowledge for the first time from above the atmosphere, and some of its basic properties are reported. The properties of atmospheric structures that are responsible for this chromatic scintillation were found to be consistent with those of previous monochromatic measurements performed from space. A maximum chromatic delay of 2.5 s was observed for widely different wavelengths.

  12. MEASURING CHROMATICITY ALONG THE RAMP USING THE PLL TUNE METER IN RHIC.

    Energy Technology Data Exchange (ETDEWEB)

    TEPIKIAN,S.; AHRENS,L.; CAMERON,P.; SCHULTHEISS,C.

    2002-06-02

    Beam stability up the ramp requires the appropriate sign and magnitude of the chromaticity. We developed a way to measure the chromaticity using the PLL (Phase Locked Loop) tune-meter. Since, the accuracy of the PLL tune-meter with properly adjusted loop gain is better than {approx} 0.0001 in tune units, the radial loop needs only be changed by a small amount of 0.2mm at a 1Hz rate. Thus, we can achieve fast chromaticity measurements in 1 sec. Except during the very beginning of the ramp where there are snapback effects and the gamma changes very rapidly, we can have good chromaticcity measurements along the ramp. This leads to the possibility of correcting the chromaticity during the ramp using a feedback system.

  13. Reverse chromatic aberration and its numerical optimization in a metamaterial lens.

    Science.gov (United States)

    Capecchi, William J; Behdad, Nader; Volpe, Francesco A

    2012-04-09

    In planar metamaterial lenses, the focal point moves with the frequency. Here it is shown numerically that this movement can be controlled by properly engineering the dimensions of the metamaterial-based phase shifters that constitute the lens. In particular, such lenses can be designed to exhibit unusual chromatic aberration with the focal length increasing, rather than decreasing, with the frequency. It is proposed that such an artificial "reverse" chromatic aberration may optimize the transverse resolution of millimeter wave diagnostics of plasmas and be useful in compensating for the natural "ordinary" chromatic aberration of other components in an optical system. More generally, optimized chromatic aberration will allow for simultaneous focusing of several objects located at different distances and emitting or reflecting at different frequencies.

  14. Correction of chromatic aberrations at television registration of image through protective viewing systems

    Science.gov (United States)

    Kulyas, Oleg L.; Nikitin, Konstantin A.

    2016-03-01

    Ways of chromatic aberration in images are examined and analyzed which are generated at television supervision through protective glasses of a considerable thickness. The results of experimental check up of the given method of correction is introduced and described.

  15. Reverse Chromatic Aberration and its Numerical Optimization in a Metamaterial Lens

    CERN Document Server

    Capecchi, W J; Volpe, F A; 10.1364/OE.20.008761

    2013-01-01

    In planar metamaterial lenses, the focal point moves with the frequency. Here it is shown numerically that this movement can be controlled by properly engineering the dimensions of the metamaterial-based phase shifters that constitute the lens. In particular, such lenses can be designed to exhibit unusual chromatic aberration with the focal length increasing, rather than decreasing, with the frequency. It is proposed that such an artificial "reverse" chromatic aberration may optimize the transverse resolution of millimeter wave diagnostics of plasmas and be useful in compensating for the natural "ordinary" chromatic aberration of other components in an optical system. More generally, optimized chromatic aberration will allow to simultaneously focus on several objects located at different distances and emitting or reflecting at different frequencies.

  16. Self-regulating genomic island encoding tandem regulators confers chromatic acclimation to marine Synechococcus

    National Research Council Canada - National Science Library

    Sanfilippo, Joseph E; Nguyen, Adam A; Karty, Jonathan A; Shukla, Animesh; Schluchter, Wendy M; Garczarek, Laurence; Partensky, Frédéric; Kehoe, David M

    2016-01-01

    ..., which are attached to antennae proteins called phycoerythrins. Many strains can alter phycoerythrin chromophore ratios to optimize photon capture in changing blue-green environments using type IV chromatic acclimation (CA4...

  17. A single mechanism for both luminance and chromatic grating vernier tasks: evidence from temporal summation.

    Science.gov (United States)

    Sun, Hao; Lee, Barry B

    2004-01-01

    Vernier thresholds are determined by luminance rather than chromatic contrast when both are present in vernier targets. The role of luminance and chromatic mechanisms in vernier performance under equiluminant conditions remains uncertain. Temporal summation functions for vernier thresholds with luminance and red-green equiluminant gratings were compared to those for detection thresholds with similar stimuli. Vernier thresholds showed similar temporal summation for luminance and chromatic gratings, which is consistent with a single mechanism underlying vernier performance in the two conditions. However, detection thresholds showed a shorter temporal summation duration for luminance gratings than for chromatic gratings, which suggests that two different mechanisms underlie detection thresholds. Analysis of physiological data supports the hypothesis that the frequency-doubled response of ganglion cells in the magnocellular pathway can provide accurate spatiotemporal information for vernier performance at equiluminance.

  18. Achromatic-chromatic colorimetric sensors for on-off type detection of analytes.

    Science.gov (United States)

    Heo, Jun Hyuk; Cho, Hui Hun; Lee, Jin Woong; Lee, Jung Heon

    2014-12-21

    We report the development of achromatic colorimetric sensors; sensors changing their colors from achromatic black to other chromatic colors. An achromatic colorimetric sensor was prepared by mixing a general colorimetric indicator, whose color changes between chromatic colors, and a complementary colored dye with no reaction to the targeted analyte. As the color of an achromatic colorimetric sensor changes from black to a chromatic color, the color change could be much easily recognized than general colorimetric sensors with naked eyes. More importantly, the achromatic colorimetric sensors enable on-off type recognition of the presence of analytes, which have not been achieved from most colorimetric sensors. In addition, the color changes from some achromatic colorimetric sensors (achromatic Eriochrome Black T and achromatic Benedict's solution) could be recognized with naked eyes at much lower concentration ranges than normal chromatic colorimetric sensors. These results provide new opportunities in the use of colorimetric sensors for diverse applications, such as harsh industrial, environmental, and biological detection.

  19. Photographic simulation of off-axis blurring due to chromatic aberration in spectacle lenses.

    Science.gov (United States)

    Doroslovački, Pavle; Guyton, David L

    2015-02-01

    Spectacle lens materials of high refractive index (nd) tend to have high chromatic dispersion (low Abbé number [V]), which may contribute to visual blurring with oblique viewing. A patient who noted off-axis blurring with new high-refractive-index spectacle lenses prompted us to do a photographic simulation of the off-axis aberrations in 3 readily available spectacle lens materials, CR-39 (nd = 1.50), polyurethane (nd = 1.60), and polycarbonate (nd = 1.59). Both chromatic and monochromatic aberrations were found to cause off-axis image degradation. Chromatic aberration was more prominent in the higher-index materials (especially polycarbonate), whereas the lower-index CR-39 had more astigmatism of oblique incidence. It is important to consider off-axis aberrations when a patient complains of otherwise unexplained blurred vision with a new pair of spectacle lenses, especially given the increasing promotion of high-refractive-index materials with high chromatic dispersion.

  20. Measuring chromatic aberrations in imaging systems using plasmonic nano-particles

    CERN Document Server

    Gennaro, Sylvain D; Maier, Stefan A; Oulton, Rupert F

    2015-01-01

    Chromatic aberration in optical systems arises from the wavelength dependence of a glass's refractive index. Polychromatic rays incident upon an optical surface are refracted at slightly different angles and in traversing an optical system follow distinct paths creating images displaced according to color. Although arising from dispersion, it manifests as a spatial distortion correctable only with compound lenses with multiple glasses and accumulates in complicated imaging systems. While chromatic aberration is measured with interferometry, simple methods are attractive for their ease of use and low cost. In this letter we retrieve the longitudinal chromatic focal shift of high numerical aperture (NA) microscope objectives from the extinction spectra of metallic nanoparticles within the focal plane. The method is accurate for high NA objectives with apochromatic correction, and enables rapid assessment of the chromatic aberration of any complete microscopy systems, since it is straightforward to implement

  1. CHROMATICITY COORDINATES EVALUATION OF TRIANGLE VERTICES GAMUT FOR DISPLAYS WITH MAXIMUM AREA OF COLOR REPRODUCTION

    Directory of Open Access Journals (Sweden)

    I. O. Zharinov

    2016-09-01

    Full Text Available We consider the problem of calculating chromaticity coordinates estimates of triangle vertices gamut for displays with maximum area of color reproduction. Initial data for the evaluation are tabulated data on the shape of the spectral locus interpolated by Bezier splines. Research results are chromaticity coordinates of the triangle vertices gamut maximum area specified on the color chart according to the standards of the International Commission on Illumination.

  2. Reverse Chromatic Aberration and its Numerical Optimization in a Metamaterial Lens

    OpenAIRE

    Capecchi, W. J.; Behdad, N.; Volpe, F. A.

    2013-01-01

    In planar metamaterial lenses, the focal point moves with the frequency. Here it is shown numerically that this movement can be controlled by properly engineering the dimensions of the metamaterial-based phase shifters that constitute the lens. In particular, such lenses can be designed to exhibit unusual chromatic aberration with the focal length increasing, rather than decreasing, with the frequency. It is proposed that such an artificial "reverse" chromatic aberration may optimize the tran...

  3. Joint IQ Skew and Chromatic Dispersion Estimation for Coherent Optical Communication Receivers

    DEFF Research Database (Denmark)

    Medeiros Diniz, Júlio César; Porto da Silva, Edson; Piels, Molly

    2016-01-01

    A low-complexity scanning method for joint estimation of receiver IQ skew and chromatic dispersion is proposed. This method shows less than 1 ps skew error for a 1200-km 32-GBd DP-16QAM optical transmission experiment.......A low-complexity scanning method for joint estimation of receiver IQ skew and chromatic dispersion is proposed. This method shows less than 1 ps skew error for a 1200-km 32-GBd DP-16QAM optical transmission experiment....

  4. Understanding the tune, coupling, and chromaticity dependence of the LHC on Landau octupole powering.

    CERN Document Server

    Maclean, E H; Persson, T; Tomas, R; Wenninger, J

    2013-01-01

    During the 2012 LHC run several observations were made of shifts to tune, coupling and chromaticity which were correlated with changes in the powering of Landau octupoles. Understanding the chromaticity dependence is of particular importance given its influence on instabilities. This note briefly summarizes the observations and describes our understanding to-date of the relationship between Q, Q′, |C−| and the Landau octupole powering.

  5. Impact of dimming white LEDs: chromaticity shifts due to different dimming methods

    Science.gov (United States)

    Dyble, Marc; Narendran, Nadarajah; Bierman, Andrew; Klein, Terence

    2005-09-01

    The goal of this study was to characterize the chromaticity shift that mixed-color and phosphor-converted white LED systems undergo when dimmed. As light-emitting diodes continue to rapidly evolve as a viable light source for lighting applications, their color shift while being dimmed should meet the current requirements of traditional lighting sources. Currently, LED system manufacturers commonly recommend pulse-width-modulation or PWM dimming schemes for operation of LED systems. PWM has the ability to achieve lower intensity levels and more linear control of light intensity compared to continuous current dimming methods. However, little data has been published on the effect dimming has on chromaticity shift of white LED lighting systems. The primary objective of this study was to quantify chromaticity shifts in mixed-color and phosphor-converted white LED systems due to continuous current dimming and pulse-width-modulation dimming schemes. In this study, the light output of the LED system was reduced from 100% to 3% by means of continuous current reduction or PWM methods using a PC white LED system and a mixed-color RGB LED system. Experimental results from this study showed that the PC white LED system exhibited very little chromaticity shift (less than a 4-step MacAdam ellipse) when the light level was changed from 100% to 3% using both dimming schemes. Compared to PC white LEDs, the mixed-color RGB LED system tested in this study showed very large chromaticity shifts in a similar dimming range using both dimming schemes. If a mixed-color RGB system is required, then some active feedback system control must be incorporated to obtain non-perceivable chromaticity shift. In this regard the chromaticity shift caused by the PWM method is easier to correct than the chromaticity shift caused by the continuous current dimming method.

  6. EVALUATION OF DISTRIBUTION HISTOGRAMS FOR INCREMENT OF CHROMATICITY COORDINATES IN DISPLAY TECHNOLOGIES

    Directory of Open Access Journals (Sweden)

    I. O. Zharinov

    2016-05-01

    Full Text Available We consider evaluation problem of chromaticity coordinates increment for an image displayed by indicating means (liquid crystal panels and etc.. Display device profile set by the weight matrix for components of primary colors serves as basic data for quantitative calculation. Research results have the form of mathematical expressions allowing calculation of increment values of chromaticity coordinates of the image displayed on indicating means and histograms of increment distribution.

  7. Effects of various storage conditions and alterations of antioxidant contents on chromatic aberration of hydroquinone ointment.

    Science.gov (United States)

    Matsubayashi, Teruhisa; Sakaeda, Toshiyuki; Kita, Tomoko; Nakamura, Tsutomu; Kakumoto, Mikio; Funasaka, Yoko; Ichihashi, Masamitsu; Fujita, Takuya; Kamiyama, Fumio; Yamamoto, Akira; Nordlund, James J; Kaneko, Masafumi; Iida, Akira; Okumura, Katsuhiko

    2003-01-01

    Ointments of the skin depigmentation agent hydroquinone (HQ) have been prepared by extemporaneous nonsterile compounding in our hospital. The HQ ointments were highly effective in the treatment of various types of skin pigmentations; however, various problems have emerged including chromatic aberration of the ointments, a relatively large variability of efficacy, and mild side effects. Chromatic aberration is expected to induce non-compliance, and this may be the reason for the relatively large variability in efficacy. In this paper, the effects of various storage conditions on the chromatic aberration and HQ content of HQ ointments were evaluated, and it was suggested that the chromatic aberration was accelerated by exposure to high temperature, air and light, although these had no effect on the HQ content. In addition, various types of HQ ointments were prepared to find a formulation to minimize chromatic aberration, and it was found that the concentrations of antioxidants, Na(2)SO(3) and L(+)-ascorbic acid (AsA), seemed to be too high, and that the protective effect of AsA on chromatic aberration was mainly due to its acidifying effect.

  8. Nanocomposites of Magnetite and Layered Double Hydroxide for Recyclable Chromate Removal

    Directory of Open Access Journals (Sweden)

    Gyeong-Hyeon Gwak

    2016-01-01

    Full Text Available Nanocomposites containing magnetic iron oxide (magnetite nanoparticles and layered double hydroxide (LDH nanosheets were prepared by two different methods, exfoliation-reassembly and coprecipitation, for aqueous chromate adsorbent. According to X-ray diffraction, scanning electron microscopy, and atomic force microscopy, both nanocomposites were determined to develop different nanostructures; LDH nanosheets well covered magnetite nanoparticles with house-of-cards-like structure in exfoliation-reassembly method, while coprecipitation resulted in LDH particle formation along with magnetite nanoparticles. Zeta-potential measurement also revealed that the magnetite surface was effectively covered by LDH moiety in exfoliation-reassembly compared with coprecipitation. Time, pH, concentration dependent chromate adsorption tests, and magnetic separation experiments exhibited that both nanocomposites effectively adsorb and easily collect chromate. However, exfoliation-reassembly nanocomposite was determined to be slightly effective in chromate removal by ~10%. Chromate adsorbed nanocomposites could be regenerated by treating with bicarbonate and the regenerated nanocomposites preserved ~80% of chromate adsorption efficacy after three times of recycling.

  9. Very-long-term and short-term chromatic adaptation: are their influences cumulative?

    Science.gov (United States)

    Belmore, Suzanne C; Shevell, Steven K

    2011-02-09

    Very-long-term (VLT) chromatic adaptation results from exposure to an altered chromatic environment for days or weeks. Color shifts from VLT adaptation are observed hours or days after leaving the altered environment. Short-term chromatic adaptation, on the other hand, results from exposure for a few minutes or less, with color shifts measured within seconds or a few minutes after the adapting light is extinguished; recovery to the pre-adapted state is complete in less than an hour. Here, both types of adaptation were combined. All adaptation was to reddish-appearing long-wavelength light. Shifts in unique yellow were measured following adaptation. Previous studies demonstrate shifts in unique yellow due to VLT chromatic adaptation, but shifts from short-term chromatic adaptation to comparable adapting light can be far greater than from VLT adaptation. The question considered here is whether the color shifts from VLT adaptation are cumulative with large shifts from short-term adaptation or, alternatively, does simultaneous short-term adaptation eliminate color shifts caused by VLT adaptation. The results show the color shifts from VLT and short-term adaptation together are cumulative, which indicates that both short-term and very-long-term chromatic adaptation affect color perception during natural viewing. Copyright © 2010 Elsevier Ltd. All rights reserved.

  10. Protective effect of ginger against toxicity induced by chromate in rats.

    Science.gov (United States)

    Krim, Meriem; Messaadia, Amira; Maidi, Imen; Aouacheri, Ouassila; Saka, Saad

    2013-01-01

    The evaluation of the effect of ginger on the modulation of toxic effects induced by chromate is the objective of our study. 50 male rats Albinos Wistar were divided to five groups as follow: group I (T) is served as control, received a mineral water by gavage (per os); group II (G) received an experimental diet with 2% of ginger; group III (Cr) received an oral dose of potassium dichromate (15 mg/kg) and normal diet; group IV (CrG): received an oral dose of potassium dichromate (15 mg/kg) and an experimental diet containing 2% ginger; and group V (Cr(+)G) received an oral dose of potassium dichromate (25 mg/kg) and an experimental diet with 2% of ginger. The results of this study indicate that the chromate provoked a haematoxic effect (anemia), nephrotoxic, hepatotoxic, and also a perturbation in lipids profile. In addition, chromate has a pro-oxidant effect, which was indicated by decrease of reduced glutathione (GSH) levels in different tissues. However, the administration of ginger revealed a reduction of the intensity of oxidative stress induced by the chromate resulting in the decrease of the majority of the previous parameters concentrations. In conclusion we demonstrated that ginger has potent antioxidants activity, revealed by the amelioration of chromate's toxic effects. We can say that ginger has a protective effect towards damages induced by the chromate.

  11. A new class of chromatic filters for color image processing. Theory and applications.

    Science.gov (United States)

    Lucchese, Luca; Mitra, Sanjit K

    2004-04-01

    This paper advances a new framework for chromatic filtering of color images. The chromatic content of a color image is encoded in the CIE u'v' chromaticity coordinates whereas the achromatic content is encoded as CIE Y tristimulus value. Within the u'v' chromaticity diagram, colors are added according to the well-known center of gravity law of additive color mixtures, which is generalized here into a nonlinear filtering scheme for processing the two chromatic signals u' and v'. The achromatic channel Y can be processed with traditional filtering schemes, either linear or nonlinear, depending on the specific task at hand. The most interesting characteristics of the new filtering scheme are: 1) the elimination of color smearing effects along edges between bright and dark areas; 2) the possibility of processing chromatic components in a noniterative fashion through linear convolution operations; and 3) the consequent amenability to computationally efficient implementations with fast Fourier transform. The paper includes several examples with both synthetic and real images where the performance of the new filtering method is compared with that of other color image processing algorithms.

  12. Application of a CCA-treated wood waste decontamination process to other copper-based preservative-treated wood after disposal

    Energy Technology Data Exchange (ETDEWEB)

    Janin, Amelie, E-mail: amelie.janin@ete.inrs.ca [University of Toronto, Faculty of Forestry, 33, Willcocks St., Toronto, ON, M5S 3B3 (Canada); Coudert, Lucie, E-mail: lucie.coudert@ete.inrs.ca [Institut national de la recherche scientifique (Centre Eau, Terre et Environnement), Universite du Quebec, 490 rue de la Couronne, Quebec, QC, G1K 9A9 (Canada); Riche, Pauline, E-mail: pauline.riche@ete.inrs.ca [Institut national de la recherche scientifique (Centre Eau, Terre et Environnement), Universite du Quebec, 490 rue de la Couronne, Quebec, QC, G1K 9A9 (Canada); Mercier, Guy, E-mail: guy_mercier@ete.inrs.ca [Institut national de la recherche scientifique (Centre Eau, Terre et Environnement), Universite du Quebec, 490 rue de la Couronne, Quebec, QC, G1K 9A9 (Canada); Cooper, Paul, E-mail: p.cooper@utoronto.ca [University of Toronto, Faculty of Forestry, 33, Willcocks St., Toronto, ON, M5S 3B3 (Canada); Blais, Jean-Francois, E-mail: blaisjf@ete.inrs.ca [Institut national de la recherche scientifique (Centre Eau, Terre et Environnement), Universite du Quebec, 490 rue de la Couronne, Quebec, QC, G1K 9A9 (Canada)

    2011-02-28

    Research highlights: {yields} This paper describes a process for the metal removal from treated (CA-, ACQ- or MCQ-) wood wastes. {yields} This sulfuric acid leaching process is simple and economic. {yields} The remediated wood could be recycled in the industry. - Abstract: Chromated copper arsenate (CCA)-treated wood was widely used until 2004 for residential and industrial applications. Since 2004, CCA was replaced by alternative copper preservatives such as alkaline copper quaternary (ACQ), copper azole (CA) and micronized copper quaternary (MCQ), for residential applications due to health concerns. Treated wood waste disposal is becoming an issue. Previous studies identified a chemical process for decontaminating CCA-treated wood waste based on sulfuric acid leaching. The potential application of this process to wood treated with the copper-based preservatives (alkaline copper quaternary (ACQ), copper azole (CA) and micronized copper quaternary (MCQ)) is investigated here. Three consecutive leaching steps with 0.1 M sulfuric acid at 75 deg, C for 2 h were successful for all the types of treated wood and achieved more than 98% copper solubilisation. The different acidic leachates produced were successively treated by coagulation using ferric chloride and precipitation (pH = 7) using sodium hydroxide. Between 94 and 99% of copper in leachates could be recovered by electrodeposition after 90 min using 2 A electrical current. Thus, the process previously developed for CCA-treated wood waste decontamination could be efficiently applied for CA-, ACQ- or MCQ-treated wood.

  13. The sandstone's chromatic alteration of the florentine cultural heritage

    Science.gov (United States)

    Vettori, S.; Pecchioni, E.; Cantisani, E.; Ricci, M.; Fratini, F.; Garzonio, C. A.

    2012-04-01

    Pietra Serena is one of the materials more used in Florentine architecture. It is a sandstone that outcrops in the hills north of the city in the municipality of Fiesole and it has been employed mainly for ornamental purposes. This litotype belongs to the the Macigno Formation (Oligocene Upper- Miocene Lower) which consists of beds of turbiditic sandstones separated by pelitic levels which are the finest components of each single turbidity layer. Petrographically, Pietra Serena can be defined as a medium-coarse-grained greywacke made of quartz, feldspars, micas, fragments of metamorphic and magmatic rocks. The clayey matrix is quite abundant, mainly composed by illite, kaolinite and chlorite-vermiculite (present only in some quarries). It is well known that the processes of decay of the sandstones are related to the type of matrix, the amount of cement, the kind of clay minerals and to the pore size distribution, which lead to water infiltrations, swelling of the clay minerals, separation of the clayey matrix, with resulting exfoliation and peeling of the stone artefacts. Pietra Serena has a bluish-grey colour in fresh cut, but many times it is easily oxidized acquiring an ochraceous-reddish brown colour on buildings. Such changes in colour, appear to be due in part to the oxidation of iron, proceeding very quickly from the surface to the inside, though the cohesion is not affected. It is possible to hypothesize that the chromatic changes not necessarily involve a progressive state of alteration of the artefact, but they may often to represents a natural patina acquired with the time. Nevertheless it is necessary to remember that the oxidized layer and its hardness could also be the result of treatments performed in the past. In Florence, several monuments and buildings are affected by such phenomenon, in particular it is possible to note an intense and diffuse reddish colouring on the Pietra Serena utilized for columns and for façade's decorations. In this work

  14. Characteristics of copper meshes coated with carbon nanotubes via electrophoretic deposition

    Science.gov (United States)

    Kim, Bu-Jong; Park, Jong-Seol; Hwang, Young-Jin; Park, Jin-Seok

    2016-09-01

    This study demonstrates the characteristics of a hybrid-type transparent electrode for touch screen panels, which was fabricated by coating carbon nanotubes (CNTs) via electrophoretic deposition (EPD) on copper (Cu)-meshes. The surface morphologies, visible-range transmittance and reflectance, and chromatic properties, such as yellowness and redness, of the fabricated CNTs-coated Cu mesh electrodes were characterized as functions of their dimensions (line-to-line spacing, line width, and electrode thickness) and compared with those of the Cu-mesh electrodes without coating of CNTs. The experimental results showed that the coating of CNTs substantially reduced the reflectance of the Cu-mesh electrodes and also improved their chromatic properties with their transmittance and sheet resistance only slightly changed, subsequently indicating that the CNTs-coated Cu-mesh electrodes possessed desirable characteristics for touch screen panels.

  15. [Copper pathology (author's transl)].

    Science.gov (United States)

    Mallet, B; Romette, J; Di Costanzo, J D

    1982-01-30

    Copper is an essential dietary component, being the coenzyme of many enzymes with oxidase activity, e.g. ceruloplasmin, superoxide dismutase, monoamine oxidase, etc. The metabolism of copper is complex and imperfectly known. Active transport of copper through the intestinal epithelial cells involves metallothionein, a protein rich in sulfhydryl groups which also binds the copper in excess and probably prevents absorption in toxic amounts. In hepatocytes a metallothionein facilitates absorption by a similar mechanism and regulates copper distribution in the liver: incorporation in an apoceruloplasmin, storage and synthesis of copper-dependent enzymes. Metallothioneins and ceruloplasmin are essential to adequate copper homeostasis. Apart from genetic disorders, diseases involving copper usually result from hypercupraemia of varied origin. Wilson's disease and Menkes' disease, although clinically and pathogenetically different, are both marked by low ceruloplasmin and copper serum levels. The excessive liver retention of copper in Wilson's disease might be due to increased avidity of hepatic metallothioneins for copper and decreased biliary excretion through lysosomal dysfunction. Menkes' disease might be due to low avidity of intestinal and hepatic metallothioneins for copper. The basic biochemical defect responsible for these two hereditary conditions has not yet been fully elucidated.

  16. Chromatic visualization of reflectivity variance within hybridized directional OCT images

    Science.gov (United States)

    Makhijani, Vikram S.; Roorda, Austin; Bayabo, Jan Kristine; Tong, Kevin K.; Rivera-Carpio, Carlos A.; Lujan, Brandon J.

    2013-03-01

    This study presents a new method of visualizing hybridized images of retinal spectral domain optical coherence tomography (SDOCT) data comprised of varied directional reflectivity. Due to the varying reflectivity of certain retinal structures relative to angle of incident light, SDOCT images obtained with differing entry positions result in nonequivalent images of corresponding cellular and extracellular structures, especially within layers containing photoreceptor components. Harnessing this property, cross-sectional pathologic and non-pathologic macular images were obtained from multiple pupil entry positions using commercially-available OCT systems, and custom segmentation, alignment, and hybridization algorithms were developed to chromatically visualize the composite variance of reflectivity effects. In these images, strong relative reflectivity from any given direction visualizes as relative intensity of its corresponding color channel. Evident in non-pathologic images was marked enhancement of Henle's fiber layer (HFL) visualization and varying reflectivity patterns of the inner limiting membrane (ILM) and photoreceptor inner/outer segment junctions (IS/OS). Pathologic images displayed similar and additional patterns. Such visualization may allow a more intuitive understanding of structural and physiologic processes in retinal pathologies.

  17. Refractive and diffractive neutron optics with reduced chromatic aberration

    Energy Technology Data Exchange (ETDEWEB)

    Poulsen, S.O., E-mail: stefan.poulsen@northwestern.edu [NEXMAP, Department of Physics, Technical University of Denmark, Anker Engelunds Vej 1, 2800 Kgs. Lyngby (Denmark); Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208 (United States); Poulsen, H.F. [NEXMAP, Department of Physics, Technical University of Denmark, Anker Engelunds Vej 1, 2800 Kgs. Lyngby (Denmark); Bentley, P.M. [European Spallation Source ESS AB, Box 176, 221 00 Lund (Sweden)

    2014-12-11

    Thermal neutron beams are an indispensable tool in physics research. The spatial and the temporal resolution attainable in experiments are dependent on the flux and collimation of the neutron beam which remain relatively poor, even for modern neutron sources. These difficulties may be mitigated by the use of optics for focusing and imaging. Refractive and diffractive optical elements, e.g. compound refractive lenses and Fresnel zone plates, are attractive due to their low cost, and simple alignment. These optical elements, however, suffer from chromatic aberration, which limit their effectiveness to highly monochromatic beams. This paper presents two novel concepts for focusing and imaging non-monochromatic thermal neutron beams with well-known optical elements: (1) a fast mechanical transfocator based on a compound refractive lens, which actively varies the number of individual lenses in the beam path to focus and image a time-of-flight beam, and (2) a passive optical element consisting of a compound refractive lens, and a Fresnel zone plate, which may focus and image both continuous and pulsed neutron beams.

  18. Perceived no reference image quality measurement for chromatic aberration

    Science.gov (United States)

    Lamb, Anupama B.; Khambete, Madhuri

    2016-03-01

    Today there is need for no reference (NR) objective perceived image quality measurement techniques as conducting subjective experiments and making reference image available is a very difficult task. Very few NR perceived image quality measurement algorithms are available for color distortions like chromatic aberration (CA), color quantization with dither, and color saturation. We proposed NR image quality assessment (NR-IQA) algorithms for images distorted with CA. CA is mostly observed in images taken with digital cameras, having higher sensor resolution with inexpensive lenses. We compared our metric performance with two state-of-the-art NR blur techniques, one full reference IQA technique and three general-purpose NR-IQA techniques, although they are not tailored for CA. We used a CA dataset in the TID-2013 color image database to evaluate performance. Proposed algorithms give comparable performance with state-of-the-art techniques in terms of performance parameters and outperform them in terms of monotonicity and computational complexity. We have also discovered that the proposed CA algorithm best predicts perceived image quality of images distorted with realistic CA.

  19. Pigment chromatic adaptation in Cyclotella caspia Grunow (Bacillariophyta

    Directory of Open Access Journals (Sweden)

    Donato Seiji Abe

    1991-01-01

    Full Text Available The diatom Cyclotella caspia Grunow, isolated from surface waters of the Ubatuba region (São Paulo State, Brazil was submitted to different light spectral distributions for examination of its adaptative response. Growth rate and the photosynthetic pigments chlorophyll a, chlorophyll c, carotenoids and phaeopigments were measured under white, blue and red light of the same intensity (8 and 20 µE.cm-2.s-1. Growth rate increased under blue light while red light increased chl a concentration. The relative proportion of chl a and carotenoids did not change, demonstrating the absence of complementary chromatic adaptation.A diatomácea Cyclotella caspia Grunow, isolada de águas superficiais da região de Ubatuba (Estado de São Paulo, Brasil, foi submetida a diferentes intervalos espectrais de luz com a finalidade de se examinar sua resposta adaptativa. Foram medidos a taxa de crescimento e os pigmentos fotossintéticos clorofila a, clorofila c, carotenóides e feopigmentos, sob luz branca, azul e vermelha de mesmas intensidades (8 e 20 µE.cm-2.s-1. A taxa de crescimento aumentou sob luz azul, sendo que a concentração de clorofila a aumentar sob luz vermelha. A proporção relativa de clα e carotenóides não variou, demonstrando a ausência de adapatação cromática complementar.

  20. The dependence of luminous efficiency on chromatic adaptation.

    Science.gov (United States)

    Stockman, Andrew; Jägle, Herbert; Pirzer, Markus; Sharpe, Lindsay T

    2008-12-15

    We investigated the dependence of luminous efficiency on background chromaticity by measuring 25-Hz heterochromatic flicker photometry (HFP) matches in six genotyped male observers on 21 different 1000-photopic-troland adapting fields: 14 spectral ones ranging from 430 to 670 nm and 7 bichromatic mixtures of 478 and 577 nm that varied in luminance ratio. Each function was analyzed in terms of the best-fitting linear combination of the long- (L) and middle- (M) wavelength sensitive cone fundamentals of A. Stockman and L. T. Sharpe (2000). Taking into account the adapting effects of both the backgrounds and the targets, we found that luminous efficiency between 603 and 535 nm could be predicted by a simple model in which the relative L- and M-cone weights are inversely proportional to the mean cone excitations produced in each cone type multiplied by a single factor, which was roughly independent of background wavelength (and may reflect relative L:M cone numerosity). On backgrounds shorter than 535 nm and longer than 603 nm, the M-cone contribution to luminous efficiency falls short of the proportionality prediction but most likely for different reasons in the two spectral regions.

  1. Molecular basis of chromatic adaptation in pennate diatom Phaeodactylum tricornutum.

    Science.gov (United States)

    Herbstová, Miroslava; Bína, David; Koník, Peter; Gardian, Zdenko; Vácha, František; Litvín, Radek

    2015-01-01

    The remarkable adaptability of diatoms living in a highly variable environment assures their prominence among marine primary producers. The present study integrates biochemical, biophysical and genomic data to bring new insights into the molecular mechanism of chromatic adaptation of pennate diatoms in model species Phaeodactylum tricornutum, a marine eukaryote alga possessing the capability to shift its absorption up to ~700 nm as a consequence of incident light enhanced in the red component. Presence of these low energy spectral forms of Chl a is manifested by room temperature fluorescence emission maximum at 710 nm (F710). Here we report a successful isolation of the supramolecular protein complex emitting F710 and identify a member of the Fucoxanthin Chlorophyll a/c binding Protein family, Lhcf15, as its key building block. This red-shifted antenna complex of P. tricornutum appears to be functionally connected to photosystem II. Phylogenetic analyses do not support relation of Lhcf15 of P. tricornutum to other known red-shifted antenna proteins thus indicating a case of convergent evolutionary adaptation towards survival in shaded environments. Copyright © 2015 Elsevier B.V. All rights reserved.

  2. Efficient chromaticity-preserving sharpening of RGB images

    Science.gov (United States)

    Kasson, James M.

    1995-04-01

    The conventional method of performing spatial filtering of RGB images is to subject each plane to the same processing, usually convolution with a filter kernel. Filtering is commonly used in the processing of photographic or photo-realistic images to sharpen or blur images, and to produce aesthetically-pleasing effects. For image sharpening, the technique of subjecting each plane to the same processing produces objectionable color errors in some circumstances, and that techniques which convert the image to a color space that separates luminance from chrominance and performing the filtering only on the luminance component can produce better results. The problem with this approach has been the computational cost of making the transformation, first to the luminance- chrominance space, and back to RGB. This paper presents an algorithm which operates on an RGB image and provides results which are free from chromaticity changes. It achieves these results with fewer computations than filtering the luminance component in a luminance-chrominance color space. In fact, the computations required are usually simpler than processing each RGB plane.

  3. [Copper IUDs (author's transl)].

    Science.gov (United States)

    Thiery, M

    1983-10-01

    Following initial development of the Grafenberg ring in the 1920's, IUDs fell into disuse until the late 1950s, when plastic devices inserted using new technology began to gain worldwide acceptance. Further research indicated that copper had a significant antifertility effect which increased with increasing surface area, and several copper IUDs were developed and adapted, including the Copper T 200, the Copper T 220C, and the Copper T 380 A, probably the most effective yet. The Gravigard and Multiload are 2 other copper devices developed according to somewhat different principles. Copper devices are widely used not so much because of their great effectiveness as because of their suitability for nulliparous patients and their ease of insertion, which minimizes risk of uterine perforation. Records of 2584 women using Copper IUDs for 7190 women-years and 956 women using devices without copper for 6059 women-years suggest that the copper devices were associated with greater effectiveness and fewer removals for complications. Research suggests that the advantages of copper IUDs become more significant with increased duration of use. Contraindications to copper devices include allergy to copper and hepatolenticular degeneration. No carcinogenic or teratogenic effect of copper devices has been found, but further studies are needed to rule out other undesirable effects. Significant modifications of copper devices in recent years have been developed to increase their effectiveness, prolong their duration of usefulness, facilitate insertion and permit insertion during abortion or delivery. The upper limit of the surface area of copper associated with increased effectiveness appears to be between 200-300 sq mm, and at some point increases in copper exposure may provoke expulsion of the IUD. The duration of fertility inhibition of copper IUDs is usually estimated at 2-3 years, but recent research indicates that it may be 6-8 years, and some devices may retain copper surface

  4. TREATMENT TESTS FOR EX SITU REMOVAL OF CHROMATE & NITRATE & URANIUM (VI) FROM HANFORD (100-HR-3) GROUNDWATER FINAL REPORT

    Energy Technology Data Exchange (ETDEWEB)

    BECK MA; DUNCAN JB

    1994-01-03

    This report describes batch and ion exchange column laboratory scale studies investigating ex situ methods to remove chromate (chromium [VI]), nitrate (NO{sub 3}{sup -}) and uranium (present as uranium [VI]) from contaminated Hanford site groundwaters. The technologies investigated include: chemical precipitation or coprecipitation to remove chromate and uranium; and anion exchange to remove chromate, uranium and nitrate. The technologies investigated were specified in the 100-HR-3 Groundwater Treatability Test Plan. The method suggested for future study is anion exchange.

  5. ANION EXCHANGE CAPACITY OF CHROMATE ON MODIFIED ZEOLITE CLINOPTILOLITE WITH HDTMA-Br AND ITS REGENERATION

    Directory of Open Access Journals (Sweden)

    Widajanti Wibowo

    2011-04-01

    Full Text Available Zeolite Clinoptilolite from Lampung, located in South of Sumatra, had been modified with surfactanthexadecyltrimethylammonium bromide (HDTMA-Br as chromate anion exchanger. Surfactant modified zeolite (SMZClinoptilolite in particle size range of 1.5 - 2.0 mm, which contained 196.7 mmol HDTMA-Br/kg zeolite, was used foranion exchange of chromate at neutral pH. This experiment was conducted in a glass column filled with 5 gram SMZ.The breakthrough chromate exchange capacity was found 1.262 mg/g SMZ, while the total capacity was found 2.107mg/g SMZ. The regeneration of SMZ saturated with chromate was conducted using a mixed solutions of 0.28 MNa2CO3 and 0.5 M NaOH, compared with using a solution of 0.01 M Na2S2O4. The desorption of chromate achieved92% with the mixed solutions of Na2CO3 and NaOH and 90% with the Na2S2O4 solution. The regenerated SMZ withNa2CO3-NaOH solutions was prior washed with HCl solution to remove the carbonate from SMZ, before being used forchromate sorption again. Its breakthrough capacity was reduced to 1.074 mg/g SMZ, and to 0.724 mg/g SMZ whenregenerated with Na2S2O4 solution. These results indicated that regeneration of SMZ affected its exchange capacity foranion chromate. However, it is still could be acceptable, when Na2CO3/NaOH solutions were used for the regenerationof SMZ saturated with anion chromate.

  6. Influence of Varying Tune width on the Robustness of the LHC Tune PLL and its Application for Continuous Chromaticity Measurement

    CERN Document Server

    Boccardi, A; Jones, R; Kasinski, KK; Steinhagen, R

    2007-01-01

    Tune and chromaticity measurement is an integral part of safe and reliable LHC operation. Tight tolerances on the maximum transverse beam excursions allow oscillation amplitudes of less than 30 μm. This leaves only a small margin for transverse beam and momentum excitations required for measuring tune and chromaticity. This contribution discusses a robust tune phase-locked-loop (PLL) operation in the presence of non-linearities and varying chromaticity. The loop design was tested at the SPS, using the LHC PLL prototype system. The system was also used to continuously measure tune width and chromaticity, using resonant transverse excitations of the tune side-slopes.

  7. Effects of ocular transverse chromatic aberration on peripheral word identification.

    Science.gov (United States)

    Yang, Shun-Nan; Tai, Yu-chi; Laukkanen, Hannu; Sheedy, James E

    2011-11-01

    Transverse chromatic aberration (TCA) smears the retinal image of peripheral stimuli. We previously found that TCA significantly reduces the ability to recognize letters presented in the near fovea by degrading image quality and exacerbating crowding effect from adjacent letters. The present study examined whether TCA has a significant effect on near foveal and peripheral word identification, and whether within-word orthographic facilitation interacts with TCA effect to affect word identification. Subjects were briefly presented a 6- to 7-letter word of high or low frequency in each trial. Target words were generated with weak or strong horizontal color fringe to attenuate the TCA in the right periphery and exacerbate it in the left. The center of the target word was 1°, 2°, 4°, and 6° to the left or right of a fixation point. Subject's eye position was monitored with an eye-tracker to ensure proper fixation before target presentation. They were required to report the identity of the target word as soon and accurately as possible. Results show significant effect of color fringe on the latency and accuracy of word recognition, indicating existing TCA effect. Observed TCA effect was more salient in the right periphery, and was affected by word frequency more there. Individuals' subjective preference of color-fringed text was correlated to the TCA effect in the near periphery. Our results suggest that TCA significantly affects peripheral word identification, especially when it is located in the right periphery. Contextual facilitation such as word frequency interacts with TCA to influence the accuracy and latency of word recognition.

  8. Spectral discrimination in color blind animals via chromatic aberration and pupil shape.

    Science.gov (United States)

    Stubbs, Alexander L; Stubbs, Christopher W

    2016-07-19

    We present a mechanism by which organisms with only a single photoreceptor, which have a monochromatic view of the world, can achieve color discrimination. An off-axis pupil and the principle of chromatic aberration (where different wavelengths come to focus at different distances behind a lens) can combine to provide "color-blind" animals with a way to distinguish colors. As a specific example, we constructed a computer model of the visual system of cephalopods (octopus, squid, and cuttlefish) that have a single unfiltered photoreceptor type. We compute a quantitative image quality budget for this visual system and show how chromatic blurring dominates the visual acuity in these animals in shallow water. We quantitatively show, through numerical simulations, how chromatic aberration can be exploited to obtain spectral information, especially through nonaxial pupils that are characteristic of coleoid cephalopods. We have also assessed the inherent ambiguity between range and color that is a consequence of the chromatic variation of best focus with wavelength. This proposed mechanism is consistent with the extensive suite of visual/behavioral and physiological data that has been obtained from cephalopod studies and offers a possible solution to the apparent paradox of vivid chromatic behaviors in color blind animals. Moreover, this proposed mechanism has potential applicability in organisms with limited photoreceptor complements, such as spiders and dolphins.

  9. Combined influences of chromatic aberration and scattering in depth-resolved two-photon fluorescence endospectroscopy.

    Science.gov (United States)

    Wu, Yicong; Li, Xingde

    2010-10-27

    The influence of chromatic aberration of an objective lens in two-photon fluorescence (TPF) endospectroscopy of scattering media has been systematically investigated through both experiments and numerical simulations. Experiments were carried out on a uniform 3D scattering gelatin phantom embedded with TiO(2) granules (to mimic tissue scattering) and fluorescein-tagged polystyrene beads. It was found that fluorescence spectral intensity and lineshape varied as a function of depth when measured with a gradient-index (GRIN) lens which has severe chromatic aberration. The spectral distortion caused by the chromatic aberration became diminishing as the imaging depth increased. Ray tracing analysis and Monte Carlo simulations were carried out to study the interplay of chromatic aberration and scattering in the depth-resolved TPF spectra. The simulation results suggest that the collected fluorescence signals from deeper layers included more out-of-focus photons that experienced a few or multiple scatterings, which diminish the influence of chromatic aberration on the measured TPF spectra. The simulated collection efficiencies of TPF at different wavelengths and depths can be used to properly recover the true depth-resolved TPF spectra of a relatively uniform scattering medium.

  10. Spectral discrimination in color blind animals via chromatic aberration and pupil shape

    Science.gov (United States)

    Stubbs, Alexander L.; Stubbs, Christopher W.

    2016-01-01

    We present a mechanism by which organisms with only a single photoreceptor, which have a monochromatic view of the world, can achieve color discrimination. An off-axis pupil and the principle of chromatic aberration (where different wavelengths come to focus at different distances behind a lens) can combine to provide “color-blind” animals with a way to distinguish colors. As a specific example, we constructed a computer model of the visual system of cephalopods (octopus, squid, and cuttlefish) that have a single unfiltered photoreceptor type. We compute a quantitative image quality budget for this visual system and show how chromatic blurring dominates the visual acuity in these animals in shallow water. We quantitatively show, through numerical simulations, how chromatic aberration can be exploited to obtain spectral information, especially through nonaxial pupils that are characteristic of coleoid cephalopods. We have also assessed the inherent ambiguity between range and color that is a consequence of the chromatic variation of best focus with wavelength. This proposed mechanism is consistent with the extensive suite of visual/behavioral and physiological data that has been obtained from cephalopod studies and offers a possible solution to the apparent paradox of vivid chromatic behaviors in color blind animals. Moreover, this proposed mechanism has potential applicability in organisms with limited photoreceptor complements, such as spiders and dolphins. PMID:27382180

  11. The main injector chromaticity correction sextupole magnets: Measurements and operating schemes

    Energy Technology Data Exchange (ETDEWEB)

    Bhat, C.M.; Bogacz, A.; Brown, B.C.; Harding, D.J.; Fang, S.J.; Martin, P.S.; Glass, H.D.; Sim, J.

    1995-05-01

    The Fermilab Main Injector (FMI) is a high intensity proton synchrotron which will be used to accelerate protons and antiprotons from 8.9 GeV/c to 150 GeV/c. The natural chromaticities of the machine for the horizontal and the vertical Planes are {minus}33.6 and {minus}33.9 respectively. The {Delta}p/p of the beam at injection is about 0.002. The chromaticity requirements of the FMI, are primarily decided by the {Delta}p/p = 0.002 of the beam at injection. This limits the final chromaticity of the FMI to be {plus_minus}5 units. To correct the chromaticity in the FMI two families of sextupole magnets will be installed in the lattice, one for each plane. A sextupole magnet suitable for the FMI needs has been designed and a number of them are being built. New chromaticity compensation schemes have been worked out in the light of recently proposed faster acceleration ramps. On an R/D sextupole magnet the low current measurements have been carried out to determine the electrical properties. Also, using a Morgan coil, measurements have been performed to determine the higher ordered multipole components up to 18-poles. An overview of these result are presented here.

  12. Chromator is required for proper microtubule spindle formation and mitosis in Drosophila.

    Science.gov (United States)

    Ding, Yun; Yao, Changfu; Lince-Faria, Mariana; Rath, Uttama; Cai, Weili; Maiato, Helder; Girton, Jack; Johansen, Kristen M; Johansen, Jørgen

    2009-10-01

    The chromodomain protein, Chromator, has been shown to have multiple functions that include regulation of chromatin structure as well as coordination of muscle remodeling during metamorphosis depending on the developmental context. In this study we show that mitotic neuroblasts from brain squash preparations from larvae heteroallelic for the two Chromator loss-of-function alleles Chro(71) and Chro(612) have severe microtubule spindle and chromosome segregation defects that were associated with a reduction in brain size. The microtubule spindles formed were incomplete, unfocused, and/or without clear spindle poles and at anaphase chromosomes were lagging and scattered. Time-lapse analysis of mitosis in S2 cells depleted of Chromator by RNAi treatment suggested that the lagging and scattered chromosome phenotypes were caused by incomplete alignment of chromosomes at the metaphase plate, possibly due to a defective spindle-assembly checkpoint, as well as of frayed and unstable microtubule spindles during anaphase. Expression of full-length Chromator transgenes under endogenous promoter control restored both microtubule spindle morphology as well as brain size strongly indicating that the observed mutant defects were directly attributable to lack of Chromator function.

  13. Mixing of Chromatic and Luminance Retinal Signals in Primate Area V1.

    Science.gov (United States)

    Li, Xiaobing; Chen, Yao; Lashgari, Reza; Bereshpolova, Yulia; Swadlow, Harvey A; Lee, Barry B; Alonso, Jose Manuel

    2015-07-01

    Vision emerges from activation of chromatic and achromatic retinal channels whose interaction in visual cortex is still poorly understood. To investigate this interaction, we recorded neuronal activity from retinal ganglion cells and V1 cortical cells in macaques and measured their visual responses to grating stimuli that had either luminance contrast (luminance grating), chromatic contrast (chromatic grating), or a combination of the two (compound grating). As with parvocellular or koniocellular retinal ganglion cells, some V1 cells responded mostly to the chromatic contrast of the compound grating. As with magnocellular retinal ganglion cells, other V1 cells responded mostly to the luminance contrast and generated a frequency-doubled response to equiluminant chromatic gratings. Unlike magnocellular and parvocellular retinal ganglion cells, V1 cells formed a unimodal distribution for luminance/color preference with a 2- to 4-fold bias toward luminance. V1 cells associated with positive local field potentials in deep layers showed the strongest combined responses to color and luminance and, as a population, V1 cells encoded a diverse combination of luminance/color edges that matched edge distributions of natural scenes. Taken together, these results suggest that the primary visual cortex combines magnocellular and parvocellular retinal inputs to increase cortical receptive field diversity and to optimize visual processing of our natural environment. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

  14. S-cone discrimination for stimuli with spatial and temporal chromatic contrast.

    Science.gov (United States)

    Cao, Dingcai; Zele, Andrew J; Smith, Vivianne C; Pokorny, Joel

    2008-01-01

    In the natural environment, color discriminations are made within a rich context of spatial and temporal variation. In classical laboratory methods for studying chromatic discrimination, there is typically a border between the test and adapting fields that introduces a spatial chromatic contrast signal. Typically, the roles of spatial and temporal contrast on chromatic discrimination are not assessed in the laboratory approach. In this study, S-cone discrimination was measured using stimulus paradigms that controlled the level of spatio-temporal S-cone contrast between the tests and adapting fields. The results indicate that S-cone discrimination of chromaticity differences between a pedestal and adapting surround is equivalent for stimuli containing spatial, temporal or spatial-and-temporal chromatic contrast between the test field and the surround. For a stimulus condition that did not contain spatial or temporal contrast, the visual system adapted to the pedestal instead of the surround. The data are interpreted in terms of a model consistent with primate koniocellular pathway physiology. The paradigms provide an approach for studying the effects of spatial and temporal contrast on discrimination in natural scenes.

  15. Chromatic-achromatic perimetry in four clinic cases: Glaucoma and diabetes

    Directory of Open Access Journals (Sweden)

    Inmaculada Cabezos

    2015-01-01

    Full Text Available Background: Some diseases that affect the visual system may show loss of chromatic-achromatic sensitivity before obvious physical signs appear in the usual examination of the eye′s posterior segment. A perimetric study has been conducted with four typical patients with glaucoma and diabetes, at different stages of the disease. Materials and Methods: In addition to the standard white-on-white (standard automated perimetry [SAP], a test battery has been used to study patient′s contrast sensitivity, using stimuli with different chromatic, spatial, and temporal content (multichannel perimetry. The choice of stimuli tries to maximize the response of different visual mechanisms: Achromatic (parvocellular and magnocellular origin; chromatic red-green (parvocellular origin; and chromatic blue-yellow (koniocellular origin. Results: The results seem to indicate losses in the achromatic-parvocellular perimetry and both chromatic perimetry tests, undetected by conventional SAP. Conclusions: Our results illustrate that our patients without visible retinal alterations show signs of suspicion in multichannel perimetry.

  16. CLASSIFICATION OF COMPLETE 5-PARTITE GRAPHS AND CHROMATICITY OF 5-PARTITE GRAPHSWITH 5n VERTICES

    Institute of Scientific and Technical Information of China (English)

    ZhaoHaixing; LiuRuying; ZhangShenggui

    2004-01-01

    For a graph G,P(G,λ)denotes the chromatic polynomial of G. Two graphs G and H are said to be chromatically equivalent,denoted by G-H,if P(G,λ)=p(H,λ). Let[G]= {H|H-G}. If [G]={G},then G is said to be chromatically unique. For a complete 5-partite graph G with 5n vertices, define θ(G)=(a(G,6)-2n+1-2n-1+5)/2n-2,where a(G,6) denotes the number of 6-independent partitions of G. In this paper, the authors show that θ(G)≥0 and determine all graphs with θ(G)= 0, 1, 2, 5/2, 7/2, 4, 17/4. By using these results the chromaticity of 5-partite graphs of the form G-S with θ(G)=0,1,2,5/2,7/2,4,17/4 is investigated,where S is a set of edges of G. Many new chromatically unique 5-partite graphs are obtained.

  17. Luminance mechanisms mediate the motion of red-green isoluminant gratings: the role of "temporal chromatic aberration".

    Science.gov (United States)

    Mullen, Kathy T; Yoshizawa, Tatsuya; Baker, Curtis L

    2003-05-01

    In this paper we use a dynamic noise-masking paradigm to explore the nature of the mechanisms mediating the motion perception of drifting isoluminant red-green gratings. We compare contrast thresholds for the detection and direction discrimination of drifting gratings (1.5 cpd), over a range of temporal frequencies (0.5-9 Hz) in the presence of variable luminance or chromatic noise. In the first experiment, we used dynamic luminance noise to show that direction thresholds for red-green grating motion are masked by luminance noise over the entire temporal range tested, whereas detection thresholds are unaffected. This result indicates that the motion of nominally isoluminant red-green gratings is mediated by luminance signals. We suggest that stimulus-based luminance artifacts are not responsible for this effect because there is no masking of the detection thresholds. Instead we propose that chromatic motion thresholds for red-green isoluminant gratings are mediated by dynamic luminance artifacts that have an internal, physiological origin. We have termed these "temporal chromatic aberration". In the second experiment, we used dynamic chromatic noise masking to test for a chromatic contribution to red-green grating motion. We were unable to find conclusive evidence for a contribution of chromatic mechanisms to the chromatic grating motion, although a contribution at very high chromatic contrasts cannot be ruled out. Our results add to a growing body of evidence indicating the presence of dynamic, internal luminance artifacts in the motion of chromatic stimuli and we show that these occur even at very low temporal rates. Our results are compatible with our previous work indicating the absence of a chromatic mechanism for first order (quasi-linear) apparent motion [Vision Res. 40 (2000) 1993]. We conclude that previous conclusions based on the motion of chromatic red-green gratings should be reassessed to determine the contribution of dynamic luminance artifacts.

  18. Handling of Copper and Copper Oxide Nanoparticles by Astrocytes.

    Science.gov (United States)

    Bulcke, Felix; Dringen, Ralf

    2016-02-01

    Copper is an essential trace element for many important cellular functions. However, excess of copper can impair cellular functions by copper-induced oxidative stress. In brain, astrocytes are considered to play a prominent role in the copper homeostasis. In this short review we summarise the current knowledge on the molecular mechanisms which are involved in the handling of copper by astrocytes. Cultured astrocytes efficiently take up copper ions predominantly by the copper transporter Ctr1 and the divalent metal transporter DMT1. In addition, copper oxide nanoparticles are rapidly accumulated by astrocytes via endocytosis. Cultured astrocytes tolerate moderate increases in intracellular copper contents very well. However, if a given threshold of cellular copper content is exceeded after exposure to copper, accelerated production of reactive oxygen species and compromised cell viability are observed. Upon exposure to sub-toxic concentrations of copper ions or copper oxide nanoparticles, astrocytes increase their copper storage capacity by upregulating the cellular contents of glutathione and metallothioneins. In addition, cultured astrocytes have the capacity to export copper ions which is likely to involve the copper ATPase 7A. The ability of astrocytes to efficiently accumulate, store and export copper ions suggests that astrocytes have a key role in the distribution of copper in brain. Impairment of this astrocytic function may be involved in diseases which are connected with disturbances in brain copper metabolism.

  19. Passive depth estimation using chromatic aberration and a depth from defocus approach.

    Science.gov (United States)

    Trouvé, Pauline; Champagnat, Frédéric; Le Besnerais, Guy; Sabater, Jacques; Avignon, Thierry; Idier, Jérôme

    2013-10-10

    In this paper, we propose a new method for passive depth estimation based on the combination of a camera with longitudinal chromatic aberration and an original depth from defocus (DFD) algorithm. Indeed a chromatic lens, combined with an RGB sensor, produces three images with spectrally variable in-focus planes, which eases the task of depth extraction with DFD. We first propose an original DFD algorithm dedicated to color images having spectrally varying defocus blurs. Then we describe the design of a prototype chromatic camera so as to evaluate experimentally the effectiveness of the proposed approach for depth estimation. We provide comparisons with results of an active ranging sensor and real indoor/outdoor scene reconstructions.

  20. Numerical analysis of low chromatic aberration of a gradient refractive index rod lens.

    Science.gov (United States)

    Lv, Hao; Liu, Aimei; Yi, Xunong; Li, Qianguang

    2009-01-20

    The oxide compositions (OCs) model is established for discussing the chromatic aberrations of a gradient refractive index rod lens. The chromatic aberrations for Na(+)/Li(+), K(+)/Cs(+), and K(+)/Tl(+) ion exchanges are discussed based on the OC model and the Huggins-Sun-Davis (HSD) model. Theoretical results indicate that the function value mainly depends on base glass properties and the nature of exchanging ion pairs, and rarely depends on the quantity of ion exchange. Experimental results show that the chromatic aberrations using the OC model have smaller errors than with the HSD model. The estimating average errors between the OC model and the HSD model are -0.051, -0.0067, and 0.0047 for the K(+)/Tl(+), Li(+)/Na(+), and K(+)/Cs(+) ion exchanges, respectively.

  1. Chromatic aberration of light focusing in hyperbolic anisotropic metamaterial made of metallic slit array.

    Science.gov (United States)

    Guo, Kai; Liu, Jianlong; Zhang, Yan; Liu, Shutian

    2012-12-17

    The dispersion of a hyperbolic anisotropic metamaterial (HAM) and the chromatic aberration of light focusing in this kind of HAM are studied. The HAM is formed by alternately stacking metal and dielectric layers. The rules of materials and filling factors affecting the optical property of HAM are given. The chromatic aberration of light focusing is demonstrated both theoretically and numerically. By comparing the theory with the simulation results, the factors influencing the focal length, including the heat loss of material and low spatial frequency modes, are discussed. The investigation emphasizes the anomalous properties, such as chromatic aberration and low spatial frequency modes influencing focus position, of HAM compared with that in conventional lens. Based on the analysis, the possibility of using HAM to focus light with two different wavelengths at the same point is studied.

  2. Limits on Foreground Subtraction from Chromatic Beam Effects in Global Redshifted 21 cm Measurements

    CERN Document Server

    Mozdzen, Thomas J; Monsalve, Raul A; Rogers, Alan E E

    2015-01-01

    Foreground subtraction in global redshifted 21 cm measurements is limited by frequency-dependent (chromatic) structure in antenna beam patterns. Chromatic beams couple angular structures in Galactic foreground emission to spectral structures that may not be removed by smooth functional forms. We report results for simulations based on two dipole antennas used by the Experiment to Detect the Global EoR Signature (EDGES). The residual levels in simulated foreground-subtracted spectra are found to differ substantially between the two antennas, suggesting that antenna design must be carefully considered. Residuals are also highly dependent on the right ascension and declination of the antenna pointing, with RMS values differing by as much as a factor of 20 across pointings. For EDGES and other ground-based experiments with zenith pointing antennas, right ascension and declination correspond directly to the local sidereal time and the latitude of the deployment site, hence chromatic beam effects should be taken in...

  3. Tune and Chromaticity Control During Snapback and Ramp in 2015 LHC Operation

    CERN Document Server

    Schaumann, Michaela; Lamont, Mike; Solfaroli Camillocci, Matteo; Todesco, Ezio; Wenninger, Jorg

    2016-01-01

    Because of current redistribution on the superconducting cables, the harmonic components of the magnetic fields of the superconducting magnets in the Large Hadron Collider (LHC) show decay during the low field injection plateau. This results in tune and chromaticity variations for the beams. In the first few seconds of the ramp the original hysteresis state of the magnetic field is restored - the field snaps back. These fast dynamic field changes lead to strong tune and chromaticity excursions that, if not properly controlled, induce beam losses and potentially trigger a beam dump. A feed-forward system applies predicted corrections during the injection plateau and to the first part of the ramp to avoid violent changes of beam conditions. This paper discusses the snapback of tune and chromaticity as observed in 2015, as well as the control of beam parameters during the ramp. It also evaluates the quality of the applied feed-forward corrections and their reproducibility.

  4. Versatile chromatic dispersion measurement of a single mode fiber using spectral white light interferometry.

    Science.gov (United States)

    Lee, Ji Yong; Kim, Dug Young

    2006-11-27

    We present a versatile and accurate chromatic dispersion measurement method for single mode optical fibers over a wide spectral range (200 nm) using a spectral domain white light interferometer. This technique is based on spectral interferometry with a Mach-Zehnder interferometer setup and a broad band light source. It takes less than a second to obtain a spectral interferogram for a few tens of centimeter length fiber sample. We have demonstrated that the relative group velocity, the chromatic dispersion and the dispersion slope of a sample fiber can be obtained very accurately regardless of the zero-dispersion wavelength (ZDW) of a sample after frequency dependent optical phase was directly retrieved from a spectral interferogram. The measured results with our proposed method were compared with those obtained with a conventional time-domain dispersion measurement method. A good agreement between those results indicates that our proposed method can measure the chromatic dispersion of a short length optical fiber with very high accuracy.

  5. An XPS study of the adsorption of chromate on goethite ( α-FeOOH)

    Science.gov (United States)

    Abdel-Samad, Hesham; Watson, Philip R.

    1997-03-01

    The adsorption behavior of inorganic oxyanions on soil minerals is an important factor in the transport of subsurface environmental pollutants. We have studied the adsorption of chromate (CrO 42-) from aqueous solution on the surface of the mineral goethite ( α-FeOOH) as a function of pH and adsorbate concentration in 0.05 M NaNO 3 solution. Results obtained from the dried surface by X-ray photoelectron spectroscopy (XPS) are in good agreement with data from spectrophotometric analysis of chromate remaining in the supernatant liquid. Chromate adsorption increases with decreasing pH of the solution and eventually reaches a maximum at pH 6.5. The chromium XPS signal indicates that initially a small amount of chromium adsorbs in the +3 oxidation state via a redox reaction, but that the large majority of chromium remains in the +6 oxidation state.

  6. Canine models of copper toxicosis for understanding mammalian copper metabolism

    OpenAIRE

    Fieten, Hille; Leegwater, Peter A. J.; Watson, Adrian L.; Rothuizen, Jan

    2011-01-01

    Hereditary forms of copper toxicosis exist in man and dogs. In man, Wilson’s disease is the best studied disorder of copper overload, resulting from mutations in the gene coding for the copper transporter ATP7B. Forms of copper toxicosis for which no causal gene is known yet are recognized as well, often in young children. Although advances have been made in unraveling the genetic background of disorders of copper metabolism in man, many questions regarding disease mechanisms and copper homeo...

  7. Structure determination and functional analysis of a chromate reductase from Gluconacetobacter hansenii.

    Directory of Open Access Journals (Sweden)

    Hongjun Jin

    Full Text Available Environmental protection through biological mechanisms that aid in the reductive immobilization of toxic metals (e.g., chromate and uranyl has been identified to involve specific NADH-dependent flavoproteins that promote cell viability. To understand the enzyme mechanisms responsible for metal reduction, the enzyme kinetics of a putative chromate reductase from Gluconacetobacter hansenii (Gh-ChrR was measured and the crystal structure of the protein determined at 2.25 Å resolution. Gh-ChrR catalyzes the NADH-dependent reduction of chromate, ferricyanide, and uranyl anions under aerobic conditions. Kinetic measurements indicate that NADH acts as a substrate inhibitor; catalysis requires chromate binding prior to NADH association. The crystal structure of Gh-ChrR shows the protein is a homotetramer with one bound flavin mononucleotide (FMN per subunit. A bound anion is visualized proximal to the FMN at the interface between adjacent subunits within a cationic pocket, which is positioned at an optimal distance for hydride transfer. Site-directed substitutions of residues proposed to involve in both NADH and metal anion binding (N85A or R101A result in 90-95% reductions in enzyme efficiencies for NADH-dependent chromate reduction. In comparison site-directed substitution of a residue (S118A participating in the coordination of FMN in the active site results in only modest (50% reductions in catalytic efficiencies, consistent with the presence of a multitude of side chains that position the FMN in the active site. The proposed proximity relationships between metal anion binding site and enzyme cofactors is discussed in terms of rational design principles for the use of enzymes in chromate and uranyl bioremediation.

  8. Repeated exposures to cobalt or chromate on the hands of patients with hand eczema and contact allergy to that metal

    DEFF Research Database (Denmark)

    Nielsen, N H; Kristiansen, J; Borg, L

    2000-01-01

    The present study aimed at evaluating the effects of daily repeated exposures to low cobalt or chromate concentrations on the hands of patients with hand eczema and cobalt or chromate allergy. For 2 weeks, the patients immersed a finger for 10 min daily into the appropriate metal salt solution in...

  9. UHF Signal Processing and Pattern Recognition of Partial Discharge in Gas-Insulated Switchgear Using Chromatic Methodology

    Science.gov (United States)

    Wang, Xiaohua; Li, Xi; Rong, Mingzhe; Xie, Dingli; Ding, Dan; Wang, Zhixiang

    2017-01-01

    The ultra-high frequency (UHF) method is widely used in insulation condition assessment. However, UHF signal processing algorithms are complicated and the size of the result is large, which hinders extracting features and recognizing partial discharge (PD) patterns. This article investigated the chromatic methodology that is novel in PD detection. The principle of chromatic methodologies in color science are introduced. The chromatic processing represents UHF signals sparsely. The UHF signals obtained from PD experiments were processed using chromatic methodology and characterized by three parameters in chromatic space (H, L, and S representing dominant wavelength, signal strength, and saturation, respectively). The features of the UHF signals were studied hierarchically. The results showed that the chromatic parameters were consistent with conventional frequency domain parameters. The global chromatic parameters can be used to distinguish UHF signals acquired by different sensors, and they reveal the propagation properties of the UHF signal in the L-shaped gas-insulated switchgear (GIS). Finally, typical PD defect patterns had been recognized by using novel chromatic parameters in an actual GIS tank and good performance of recognition was achieved. PMID:28106806

  10. Hair copper in intrauterine copper device users.

    Science.gov (United States)

    Thiery, M; Heyndrickx, A; Uyttersprot, C

    1984-03-01

    The antifertility effect of copper-bearing IUDs is based on continuous release of copper, which is a result of the reaction between the metal and the uterine secretions. Released cupric ions collect in the endometrium and in the uterine fluid but significant accumulation has not been found in the bloodstream or elsewhere. Following Laker's suggestion that hair be used for monitoring essential trace elements, e.g., copper, we checked the copper content of the hair of women wearing copper-bearing IUDs. Samples of untreated pubic hair removed by clipping before diagnostic curettage were obtained from 10 young (24-34 years old), white caucasian females who until then had been wearing an MLCu250 IUD for more than 1 year. Pubes from 10 comparable (sex, age, race) subjects who had never used a Cu-containing device served as controls. The unwashed material was submitted to the toxicology laboratory, where the copper content was assessed by flameless atomic absorption, a technique whose lower limit of measurement lies at a concentration of 0.05 mcg Cu/ml fluid (50 ppb). Hair samples were washed to remove extraneous traces of metal according to the prescriptions of the International Atomic Energy Agency, weighed, and mineralized, after which a small volume (10 mcl) of the diluted fluid was fed into the graphite furnace. Each sample (75-150 mg) was analyzed 4 times, both before and after washing. Since the cleaning procedure reduces the weight of the sample (mainly by the removal of fat, dust, etc.) this explains why the percentage copper content of washed hair is higher than that of unwashed hair belonging to the same subject. The results indicate that there was no significant difference (Mann-Whitney U test) between the mean copper levels of both unwashed and washed pubes from women who were using or had never used an MLCu250 IUD. We therefore conclude that the use of this copper-containing device is not associated with significant accumulation of copper in (pubic) hair.

  11. Varying chromaticity: A damping mechanism for the transverse head-tail instability

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, W.; Wurtele, J.S. [Department of Physics, University of California at Berkeley, Berkeley, California 94720 (United States); Sessler, A.M.; Wurtele, J.S. [Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

    1997-10-01

    A detailed analytical and numerical study of the suppression of the transverse head-tail instability by modulating the chromaticity over a synchrotron period is presented. We find that a threshold can be developed, and it can be increased to a value larger than the strong head-tail instability threshold. The stability criterion derived agrees very well with the simulations. The underlying physical mechanisms of the damping scheme are rotation of the head-tail phase such that the instability does not occur, and Landau damping due to the incoherent betatron tune spread generated by the varying chromaticity. {copyright} {ital 1997} {ital The American Physical Society}

  12. Differential algebraic method for arbitrary order curvilinear-axis combined geometric-chromatic aberration analysis

    CERN Document Server

    Cheng Min; Lu Yi Long; Yao Zhen Hua

    2003-01-01

    The principle of differential algebra is applied to analyse and calculate arbitrary order curvilinear-axis combined geometric-chromatic aberrations of electron optical systems. Expressions of differential algebraic form of high order combined aberrations are obtained and arbitrary order combined aberrations can be calculated numerically. As an example, a typical wide electron beam focusing system with curved optical axes named magnetic immersion lens has been studied. All the second-order and third-order combined geometric-chromatic aberrations of the lens have been calculated, and the patterns of the corresponding geometric aberrations and combined aberrations have been given as well.

  13. Study on chromatic aberration in a population of Chinese myopic eyes by means of optical design.

    Science.gov (United States)

    He, Yuanqing; Wang, Yan; Wang, Zhaoqi; Fang, Chao; Liu, Yongji; Zhang, Lin; Zheng, Shaolin; Wang, Lu; Chang, Shengjiang

    2013-05-01

    Two kinds of individual eye models, involving and without involving the angle between visual axis and optical axis, are established by means of optical design. We use them to study the properties of the transverse chromatic aberration (TCA) and longitudinal chromatic aberration (LCA) over the visible spectrum. Then the effects of the LCA and TCA on the visual quality of human eyes are evaluated. The statistical averages of TCA and LCA over the visible spectrum for Chinese myopic eyes are obtained. Results show that both TCA and LCA restrict the visual performance, and LCA is more detrimental than TCA.

  14. Betatron Tune Spread Generation and Differential Chromaticity Control by Octupole at Tevatron

    CERN Document Server

    Ivanov, Petr M; Annala, Jerry; Lebedev, Valeri

    2005-01-01

    Application of octupoles for Landau damping of the unstable head-tail modes requires careful consideration at their combination into separate families to insure maximum effectiveness and avoid degradation of the dynamic aperture due to the non-linear magnetic fields. Existing octupolar magnets around the machine have been arranged into four functional families with individual power supplies. Two of these families generate betatron tune spreads in the vertical and horizontal planes whereas the other two control the differential chromaticity between the proton and antiproton helices. The calculated effect on tunes and chromaticity is compared with direct measurements. Analytical formulas for betatron tune spectral density functions are presented.

  15. On Chromatic no. of 3K1-free graphs and R(3, k)

    OpenAIRE

    Dhurandhar, Medha S.

    2012-01-01

    Here we prove that if G has independence no. 2 and clique size omega with omega less than or equal to 11, then (1) chromatic no. is less than or equal to (omega2+12omega-13)/8, if omega is odd, and (2) chromatic no. is less than or equal to (omega2+10omega)/8, if omega is even. We further conjecture that the results are true in general for all omega. We also conjecture that (A) if omega is odd and R(3, omega) is even, then R(3, omega) = (omega2+8omega-9)/4, (B) if omega and R(3, omega) are bo...

  16. On Chromatic no. of 3K1-free graphs and R(3, k)

    OpenAIRE

    Dhurandhar, Medha S.

    2012-01-01

    Here we prove that if G has independence no. 2 and clique size omega with omega less than or equal to 11, then (1) chromatic no. is less than or equal to (omega2+12omega-13)/8, if omega is odd, and (2) chromatic no. is less than or equal to (omega2+10omega)/8, if omega is even. We further conjecture that the results are true in general for all omega. We also conjecture that (A) if omega is odd and R(3, omega) is even, then R(3, omega) = (omega2+8omega-9)/4, (B) if omega and R(3, omega) are bo...

  17. Rare earth and silane as chromate replacers for corrosion protection on galvanized steel

    Institute of Scientific and Technical Information of China (English)

    PENG Tianlan; MAN Ruilin

    2009-01-01

    The present work aimed at using rare earth lanthanum salt and trimethoxy(viny)silance as chromate substitutes for galvanized steel passivation, in contrast to zinc coating samples treated with chromate. The corrosion resistance was assessed by electrochemical impedance spectroscopy (EIS) and neutral salt spray tests (NSS). Scanning electron microscopy (SEM) was used to characterize the sample surfaces. The organic coating adhesion on the panel was also investigated via varnishes-cross cut tests. The results indicated that rare earth and silane two-step treatment gave more effective anticorrosion performance than Cr, which also provided good paint adhesion. The coating formation mechanism was also discussed.

  18. Modelling divergence in luminance and chromatic detection performance across measured divergence in surfperch (Embiotocidae) habitats.

    Science.gov (United States)

    Cummings, Molly E

    2004-05-01

    This study predicts target detection performance in species-specific habitats for six surfperch (Embiotocidae) living in optically variable California kelp forests. Using species-specific measurements of habitat irradiance and photoreceptor absorbance in a simple dichromatic model for luminance and chromatic detection, the estimated performance of species' measured photopigments was compared to the theoretical maximum for each habitat. Modelling results suggest that changes in peak photoreceptor absorbance (lambda(max)), photoreceptor optical density, and photic environment may affect detection performance. Estimated performances for luminance detection were consistently high, while chromatic detection varied by habitat and demonstrated substantial improvements with increasing optical density differences between cone classes.

  19. New chromaticity compensation approach and dynamic aperture increase in the SSRF storage ring

    Institute of Scientific and Technical Information of China (English)

    TIAN Shun-Qiang; HOU Jie; CHEN Guang-Ling; LIU Gui-Min

    2008-01-01

    Strong chromatic sextupoles used to compensate natural chromaticities in the third generation light source storage ring usually reduce dynamic aperture drastically.Many optimization methods can be used to find solutions that provide large dynamic apertures.This paper discusses a new optimization approach of sextupole strengths with step-by-step procedure,which is applied in the SSRF storage ring,and a better solution is obtained.Investigating driving terms generated by the sextupoles in every step can analyze their convergences and guide the weight setting among different terms in object function of the single resonance approach based on the perturbation theory.

  20. Coded-subcarrier-aided chromatic dispersion monitoring scheme for flexible optical OFDM networks.

    Science.gov (United States)

    Tse, Kam-Hon; Chan, Chun-Kit

    2014-08-11

    A simple coded-subcarrier aided scheme is proposed to perform chromatic dispersion monitoring in flexible optical OFDM networks. A pair of coded label subcarriers is added to both edges of the optical OFDM signal spectrum at the edge transmitter node. Upon reception at any intermediate or the receiver node, chromatic dispersion estimation is performed, via simple direct detection, followed by electronic correlation procedures with the designated code sequences. The feasibility and the performance of the proposed scheme have been experimentally characterized. It provides a cost-effective monitoring solution for the optical OFDM signals across intermediate nodes in flexible OFDM networks.

  1. Accelerated redox reaction between chromate and phenolic pollutants during freezing

    Energy Technology Data Exchange (ETDEWEB)

    Ju, Jinjung; Kim, Jaesung [Department of Environmental Sciences and Biotechnology, Hallym University, Chuncheon, Gangwon-do 24252 (Korea, Republic of); Vetráková, Ľubica [Department of Chemistry and Research Centre for Toxic Compounds in the Environment (RECETOX), Faculty of Science, Masaryk University, Kamenice 5, 625 00 Brno (Czech Republic); Seo, Jiwon [School of Urban and Environmental Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919 (Korea, Republic of); Heger, Dominik [Department of Chemistry and Research Centre for Toxic Compounds in the Environment (RECETOX), Faculty of Science, Masaryk University, Kamenice 5, 625 00 Brno (Czech Republic); Lee, Changha [School of Urban and Environmental Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919 (Korea, Republic of); Yoon, Ho-Il [Korea Polar Research Institute (KOPRI), Incheon 21990 (Korea, Republic of); Kim, Kitae, E-mail: ktkim@kopri.re.kr [Korea Polar Research Institute (KOPRI), Incheon 21990 (Korea, Republic of); Kim, Jungwon, E-mail: jwk@hallym.ac.kr [Department of Environmental Sciences and Biotechnology, Hallym University, Chuncheon, Gangwon-do 24252 (Korea, Republic of)

    2017-05-05

    Highlights: • Redox conversion of 4-CP/Cr(VI) was significantly accelerated during freezing. • Accelerated redox conversion in ice is ascribed to the freeze concentration effect. • 4-CP, Cr(VI), and protons are concentrated in the liquid brine by freezing. • Redox conversions of various phenolic pollutants/Cr(VI) were significant in ice. • Freezing-accelerated redox conversion was observed in real polluted water. - Abstract: The redox reaction between 4-chlorophenol (4-CP) and chromate (Cr(VI)) (i.e., the simultaneous oxidation of 4-CP by Cr(VI) and reduction of Cr(VI) by 4-CP) in ice (i.e., at −20 °C) was compared with the corresponding reaction in water (i.e., at 25 °C). The redox conversion of 4-CP/Cr(VI), which was negligible in water, was significantly accelerated in ice. This accelerated redox conversion of 4-CP/Cr(VI) in ice is ascribed to the freeze concentration effect occurring during freezing, which excludes solutes (i.e., 4-CP and Cr(VI)) and protons from the ice crystals and subsequently concentrates them in the liquid brine. The concentrations of Cr(VI) and protons in the liquid brine were confirmed by measuring the optical image and the UV–vis absorption spectra of cresol red (CR) as a pH indicator of frozen solution. The redox conversion of 4-CP/Cr(VI) was observed in water when the concentrations of 4-CP/protons or Cr(VI)/protons increased by 100/1000-fold. These results corroborate the freeze concentration effect as the reason for the accelerated redox conversion of 4-CP/Cr(VI) in ice. The redox conversion of various phenolic pollutants/Cr(VI) and 4-CP/Cr(VI) in real wastewater was successfully achieved in ice, which verifies the environmental relevance and importance of freezing-accelerated redox conversion of phenolic pollutants/Cr(VI) in cold regions.

  2. China Copper Processing Industry Focus

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    <正>1. Market Consumption The ’China Factor’ and Copper Price Fluctuation We all know China is an enormous consumer of copper,but the exact levels of consumption and where the copper has gone remains a mystery.

  3. Biogenic nanoparticles: copper, copper oxides, copper sulphides, complex copper nanostructures and their applications.

    Science.gov (United States)

    Rubilar, Olga; Rai, Mahendra; Tortella, Gonzalo; Diez, Maria Cristina; Seabra, Amedea B; Durán, Nelson

    2013-09-01

    Copper nanoparticles have been the focus of intensive study due to their potential applications in diverse fields including biomedicine, electronics, and optics. Copper-based nanostructured materials have been used in conductive films, lubrification, nanofluids, catalysis, and also as potent antimicrobial agent. The biogenic synthesis of metallic nanostructured nanoparticles is considered to be a green and eco-friendly technology since neither harmful chemicals nor high temperatures are involved in the process. The present review discusses the synthesis of copper nanostructured nanoparticles by bacteria, fungi, and plant extracts, showing that biogenic synthesis is an economically feasible, simple and non-polluting process. Applications for biogenic copper nanoparticles are also discussed.

  4. Copper and silver halates

    CERN Document Server

    Woolley, EM; Salomon, M

    2013-01-01

    Copper and Silver Halates is the third in a series of four volumes on inorganic metal halates. This volume presents critical evaluations and compilations for halate solubilities of the Group II metals. The solubility data included in this volume are those for the five compounds, copper chlorate and iodate, and silver chlorate, bromate and iodate.

  5. Coping with copper

    DEFF Research Database (Denmark)

    Nunes, Ines; Jacquiod, Samuel; Brejnrod, Asker

    2016-01-01

    Copper has been intensively used in industry and agriculture since mid-18(th) century and is currently accumulating in soils. We investigated the diversity of potential active bacteria by 16S rRNA gene transcript amplicon sequencing in a temperate grassland soil subjected to century-long exposure......, suggesting a potential promising role as bioindicators of copper contamination in soils....

  6. Chick eyes compensate for chromatic simulations of hyperopic and myopic defocus: evidence that the eye uses longitudinal chromatic aberration to guide eye-growth.

    Science.gov (United States)

    Rucker, Frances J; Wallman, Josh

    2009-07-01

    Longitudinal chromatic aberration (LCA) causes short wavelengths to be focused in front of long wavelengths. This chromatic signal is evidently used to guide ocular accommodation. We asked whether chick eyes exposed to static gratings simulating the chromatic effects of myopic or hyperopic defocus would "compensate" for the simulated defocus. We alternately exposed one eye of each chick to a sine-wave grating (5 or 2 cycle/deg) simulating myopic defocus ("MY defocus": image focused in front of retina; hence, red contrast higher than blue) and the other eye to a grating of the same spatial frequency simulating hyperopic defocus ("HY defocus": blue contrast higher than red). The chicks were placed in a drum with one eye covered with one grating, and then switched to another drum with the other grating with the other eye covered. To minimize the effects of altered eye-growth on image contrast, we studied only the earliest responses: first, we measured changes in choroidal thickness 45 min to 1 h after one 15-min episode in the drum, then we measured glycosaminoglycans (GAG) synthesis in sclera and choroid (by the incorporation of labeled sulfate in tissue culture) after a day of four 30-min episodes in the drum. The eyes compensated in the appropriate directions: The choroids of the eyes exposed to the HY simulation showed significantly more thinning (less thickening) over the course of the experiment than the choroids of the eyes exposed to the MY simulation (all groups mean:-17 microm; 5 c/d groups: -24 microm; paired t-test (one-tailed): p=0.0006). The rate of scleral GAG synthesis in the eye exposed to the HY simulation was significantly greater than in the eye exposed to the MY simulation (HY/MY ratio=1.20; one sample t-test (one-tailed): p=0.015). There was no significant interaction between the sign of the simulated defocus and either the spatial frequency or the presence of a +3 D lens used to compensate for the 33 cm distance of the drum. Although previous

  7. Segmentation of color images by chromaticity features using self-organizing maps

    Directory of Open Access Journals (Sweden)

    Farid García-Lamont

    2016-08-01

    Full Text Available Usually, the segmentation of color images is performed using cluster-based methods and the RGB space to represent the colors. The drawback with these methods is the a priori knowledge of the number of groups, or colors, in the image; besides, the RGB space issensitive to the intensity of the colors. Humans can identify different sections within a scene by the chromaticity of its colors of, as this is the feature humans employ to tell them apart. In this paper, we propose to emulate the human perception of color by training a self-organizing map (SOM with samples of chromaticity of different colors. The image to process is mapped to the HSV space because in this space the chromaticity is decoupled from the intensity, while in the RGB space this is not possible. Our proposal does not require knowing a priori the number of colors within a scene, and non-uniform illumination does not significantly affect the image segmentation. We present experimental results using some images from the Berkeley segmentation database by employing SOMs with different sizes, which are segmented successfully using only chromaticity features.

  8. Tunable high-harmonic generation by chromatic focusing of few-cycle laser pulses

    Science.gov (United States)

    Holgado, W.; Hernández-García, C.; Alonso, B.; Miranda, M.; Silva, F.; Varela, O.; Hernández-Toro, J.; Plaja, L.; Crespo, H.; Sola, I. J.

    2017-06-01

    In this work we study the impact of chromatic focusing of few-cycle laser pulses on high-order-harmonic generation (HHG) through analysis of the emitted extreme ultraviolet (XUV) radiation. Chromatic focusing is usually avoided in the few-cycle regime, as the pulse spatiotemporal structure may be highly distorted by the spatiotemporal aberrations. Here, however, we demonstrate it as an additional control parameter to modify the generated XUV radiation. We present experiments where few-cycle pulses are focused by a singlet lens in a Kr gas jet. The chromatic distribution of focal lengths allows us to tune HHG spectra by changing the relative singlet-target distance. Interestingly, we also show that the degree of chromatic aberration needed for this control does not degrade substantially the harmonic conversion efficiency, still allowing for the generation of supercontinua with the chirped-pulse scheme, demonstrated previously for achromatic focusing. We back up our experiments with theoretical simulations reproducing the experimental HHG results depending on diverse parameters (input pulse spectral phase, pulse duration, and focus position) and proving that, under the considered parameters, the attosecond pulse train remains very similar to the achromatic case, even showing cases of isolated attosecond pulse generation for near-single-cycle driving pulses.

  9. Coding gaze tracking data with chromatic gradients for VR Exposure Therapy

    DEFF Research Database (Denmark)

    Herbelin, Bruno; Grillon, Helena; De Heras Ciechomski, Pablo

    2007-01-01

    This article presents a simple and intuitive way to represent the eye-tracking data gathered during immersive virtual reality exposure therapy sessions. Eye-tracking technology is used to observe gaze movements during vir- tual reality sessions and the gaze-map chromatic gradient coding allows...

  10. Orbit, optics and chromaticity correction for PS2 negative momentum compaction lattices

    Energy Technology Data Exchange (ETDEWEB)

    Papaphilippou,Y.; Barranco, J.; Bartmann, W.; Benedikt, M.; Carli, C.; de Maria, R.; Peggs, S.; Trbojevic, D.

    2009-05-04

    The effect of magnet misalignments in the beam orbit and linear optics functions are reviewed and correction schemes are applied to the negative momentum compaction lattice of PS2. Chromaticity correction schemes are also proposed and tested with respect to off-momentum optics properties. The impact of the correction schemes in the dynamic aperture of the lattice is finally evaluated.

  11. Chromatic variation of aberration: the role of induced aberrations and raytrace direction

    Science.gov (United States)

    Berner, A.; Nobis, T.; Shafer, D.; Gross, H.

    2015-09-01

    The design and optimization process of an optical system contains several first order steps. The definition of the appropriate lens type and the fixation of the raytrace direction are some of them. The latter can be understood as a hidden assumption rather than an aware design step. This is usually followed by the determination of the paraxial lens layout calculated for the primary wavelength. It is obvious, that for this primary wavelength the paraxial calculations are independent of raytrace direction. Today, most of the lens designs are specified not to work only for one wavelength, but in a certain wavelength range. Considering such rays of other wavelengths, one can observe that depending on the direction there will already occur differences in the first order chromatic aberrations and additionally in the chromatic variation of the third-order aberrations. The reason for this effect are induced aberrations emerging from one surface to the following surfaces by perturbed ray heights and ray angles. It can be shown, that the total amount of surface-resolved first order chromatic aberrations and the chromatic variation of the five primary aberrations can be split into an intrinsic part and an induced part. The intrinsic part is independent of the raytrace direction whereas the induced part is not.

  12. Experimental verification of the minimum number of diffractive zones for effective chromatic correction in the LWIR

    Science.gov (United States)

    Ramsey, J. L.; Walsh, K. F.; Smith, M.; Deegan, J.

    2016-05-01

    With the move to smaller pixel sizes in the longwave IR region there has been a push for shorter focal length lenses that are smaller, cheaper and lighter and that resolve lower spatial frequencies. As a result lenses must have better correction for both chromatic and monochromatic aberrations. This leads to the increased use of aspheres and diffractive optical elements (kinoforms). With recent developments in the molding of chalcogenide materials these aspheres and kinoforms are more cost effective to manufacture. Without kinoforms the axial color can be on the order of 15 μm which degrades the performance of the lens at the Nyquist frequency. The kinoforms are now on smaller elements and are correcting chromatic aberration which is on the order of the design wavelength. This leads to kinoform structures that do not require large phase changes and therefore have 1.5 to just over 2 zones. The question becomes how many zones are required to correct small amounts of chromatic aberration in the system and are they functioning as predicted by the lens design software? We investigate both the design performance and the as-built performance of two designs that incorporate kinoforms for the correction of axial chromatic aberration.

  13. Chromatic confocal microscopy for multi-depth imaging of epithelial tissue.

    Science.gov (United States)

    Olsovsky, Cory; Shelton, Ryan; Carrasco-Zevallos, Oscar; Applegate, Brian E; Maitland, Kristen C

    2013-05-01

    We present a novel chromatic confocal microscope capable of volumetric reflectance imaging of microstructure in non-transparent tissue. Our design takes advantage of the chromatic aberration of aspheric lenses that are otherwise well corrected. Strong chromatic aberration, generated by multiple aspheres, longitudinally disperses supercontinuum light onto the sample. The backscattered light detected with a spectrometer is therefore wavelength encoded and each spectrum corresponds to a line image. This approach obviates the need for traditional axial mechanical scanning techniques that are difficult to implement for endoscopy and susceptible to motion artifact. A wavelength range of 590-775 nm yielded a >150 µm imaging depth with ~3 µm axial resolution. The system was further demonstrated by capturing volumetric images of buccal mucosa. We believe these represent the first microstructural images in non-transparent biological tissue using chromatic confocal microscopy that exhibit long imaging depth while maintaining acceptable resolution for resolving cell morphology. Miniaturization of this optical system could bring enhanced speed and accuracy to endomicroscopic in vivo volumetric imaging of epithelial tissue.

  14. Measurement of chromatic aberration in STEM and SCEM by coherent convergent beam electron diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, C.L. [Monash Centre for Electron Microscopy, Monash University, Victoria 3800 (Australia); Etheridge, J., E-mail: joanne.etheridge@monash.edu [Monash Centre for Electron Microscopy, Monash University, Victoria 3800 (Australia); Department of Materials Engineering, Monash University, Victoria 3800 (Australia)

    2013-02-15

    A simple method is described for the accurate and precise measurement of chromatic aberration under electron-optical conditions pertinent to scanning transmission electron microscopy (STEM) and scanning confocal electron microscopy (SCEM). The method requires only the measurement of distances in a coherent CBED pattern and knowledge of the electron wavelength and the lattice spacing of a calibration specimen. The chromatic aberration of a spherical-aberration corrected 300 kV thermal field emission TEM is measured in STEM and SCEM operating modes and under different condenser lens settings. The effect of the measured chromatic aberrations on the 3 dimensional intensity distribution of the electron probe is also considered. - Highlights: ► A method is presented to measure chromatic aberration (C{sub c}) using coherent CBED. ► The C{sub c} of the probe and imaging lens systems in STEM and SCEM modes is measured in a C{sub 3}-corrected S/TEM. ► The effect of the measured C{sub c} on the depth resolution in STEM is simulated for different energy spreads.

  15. Results of the LHC Prototype Chromaticity Measurement System Studies in the CERN-SPS

    CERN Document Server

    Steinhagen, R; Bohl, T; Gasior, M; Jones, O R; Kasinski, K K; Wenninger, J

    2008-01-01

    Tune and chromaticity control is an integral part of safe and reliable LHC operation. Tight tolerances on the maximum beam excursions allow excitation amplitudes of less than 30 $\\mu$m. This leaves only a small margin for transverse beam and momentum excitations, required for measuring tune and chromaticity. This contribution discusses the baseline LHC continuous chromaticity measurement with results from tests at the CERN-SPS. The system is based on continuous tracking of the tune using a Phase- Locked-Loop (PLL) while modulating the beam momentum. The high PLL tune resolution achieved, made it possible to detect chromaticity changes well below the nominally required 1 unit for relative momentum modulations of only $2·10^{-5}$. The sensitive tune measurement frontend employed allowed the PLL excitation and radial amplitudes to be kept below a few micrometers. These results show that this type of measurement can be considered as practically non-perturbative permitting its use even during nominal LHC operat...

  16. Chromatic temporal integration and retinal eccentricity: psychophysics, neurometric analysis and cortical pooling.

    Science.gov (United States)

    Swanson, William H; Pan, Fei; Lee, Barry B

    2008-11-01

    Psychophysical chromatic sensitivity deteriorates in peripheral retina, even after appropriate size scaling of targets. This decrease is more marked for stimuli targeted at the long- (L) to middle-wavelength (M) cone opponent system than for stimuli targeted at short-wavelength (S) pathways. Foveal chromatic mechanisms integrate over several hundred milliseconds for pulse detection. If the time course for integration were shorter in the periphery, this might account for sensitivity loss. Psychophysical chromatic temporal integration (critical duration) for human observers was estimated as a function of eccentricity. Critical duration decreased by a factor of 2 (from approximately 200 to approximately 100 ms) from the fovea to 20 degrees eccentricity. This partly (but not completely) accounts for the decrease in /L-M/ sensitivity in the periphery, but almost completely accounts for the decrease in S-cone sensitivity. Some loss of /L-M/I sensitivity thus has a cortical locus. In a physiological analysis, we consider how the /L-M/ cone parvocellular pathway integrates chromatic signals. Neurometric contrast sensitivities of individual retinal ganglion cells decreased with the square-root of stimulus duration (as expected from Poisson statistics of ganglion cell firing). In contrast, psychophysical data followed an inverse linear relationship (Bloch's law). Models of cortical pooling mechanisms incorporating uncertainty as to stimulus onset and duration can at least partially account for this discrepancy.

  17. Commissioning of the nonlinear chromaticity at injection for LHC Run II

    CERN Document Server

    AUTHOR|(CDS)2080608; Tomas Garcia, Rogelio; Carlier, Felix Simon; Langner, Andy Sven; Malina, Lukas; Persson, Tobias Hakan Bjorn; Coello De Portugal - Martinez Vazquez, Jaime Maria; Skowronski, Piotr Krzysztof; Garcia-Tabares Valdivieso, Ana; CERN. Geneva. ATS Department

    2016-01-01

    For the first time, correction of nonlinear chromaticity and amplitude detuning was included in the LHC commissioning for Run II. The corrections found during the nonlinear optics commissioning have been deployed operationally at injection in the LHC. This note summarizes the relevant measurements and corrections performed during the first commissioning of the LHC in Run II

  18. On the chromatic number of pentagon-free graphs of large minimum degree

    DEFF Research Database (Denmark)

    Thomassen, Carsten

    2007-01-01

    We prove that, for each fixed real number c > 0, the pentagon-free graphs of minimum degree at least cn (where n is the number of vertices) have bounded chromatic number. This problem was raised by Erdős and Simonovits in 1973. A similar result holds for any other fixed odd cycle, except the tria...

  19. SIMULTANEOUS DTERMINATION OF CHROMATE AND AROMATIC HYDROCARBONS IN ENVIRONMENTAL SAMPLES BY CAPILLARY ELECTROPHORESIS

    Science.gov (United States)

    An analytical method was developed to determine simultaneously, the inorganic anion CrO2-4, and organic aromatic compounds including benzoate, 2-Cl-benzoate, phenol, m-cresol and o-/p-cresol by capillary electrophoresis (CE). Chromate and the aromatics were separated in a relativ...

  20. Perception of Chromatic cues during host location by the pupal parasitoid Pimpla turionellae (L.) (Hymenoptera: Ichneumonidae)

    NARCIS (Netherlands)

    Fischer, S.; Samietz, J.; Wäckers, F.L.; Dorn, S.

    2004-01-01

    Chromatic and achromatic plant cues are expected to be particularly important for parasitoids of endophytic pupal hosts, because these stages do not feed and therefore avoid volatile emission caused by plant tissue damage. Endophytic feeding can cause discoloration or desiccation, leading to changes

  1. Effects of iron stress on chromatic adaptation by natural phytoplankton communities in the Southern Ocean

    NARCIS (Netherlands)

    van Leeuwe, M.A.; Timmermans, K.R.; Witte, H.J.; Kraay, G.W.; Veldhuis, M.J.W.; de Baar, H.J.W.

    1998-01-01

    Effects of iron stress on chromatic adaptation were studied in natural phytoplankton communities collected in the Pacific region of the Southern Ocean. Iron enrichment experiments (48 to 72 h) were performed, incubating plankton communities under white, green and blue light respectively, with and wi

  2. Experimental demonstration of the maximum likelihood-based chromatic dispersion estimator for coherent receivers

    DEFF Research Database (Denmark)

    Borkowski, Robert; Johannisson, Pontus; Wymeersch, Henk;

    2014-01-01

    We perform an experimental investigation of a maximum likelihood-based (ML-based) algorithm for bulk chromatic dispersion estimation for digital coherent receivers operating in uncompensated optical networks. We demonstrate the robustness of the method at low optical signal-to-noise ratio (OSNR) ...

  3. Implementation of fluidized granulated iron reactors in a chromate remediation process

    Energy Technology Data Exchange (ETDEWEB)

    Müller, P., E-mail: peter.mueller@ferrodecont.at [Department of Environmental and Energy Process Engineering, Chair of Waste Treatment Technologies and Landfilling, Montanuniversitaet Leoben, 8700 Leoben (Austria); Lorber, K.E., E-mail: avaw@unileoben.ac.at [Department of Environmental and Energy Process Engineering, Chair of Waste Treatment Technologies and Landfilling, Montanuniversitaet Leoben, 8700 Leoben (Austria); Mischitz, R. [Department of Environmental and Energy Process Engineering, Chair of Waste Treatment Technologies and Landfilling, Montanuniversitaet Leoben, 8700 Leoben (Austria); Weiß, C., E-mail: weissc@unileoben.ac.at [Department of Environmental and Energy Process Engineering, Chair of Process Technology and Industrial Environmental Protection, Montanuniversitaet Leoben, 8700 Leoben (Austria)

    2014-07-01

    A new approach concerning in-situ remediation on source (‘hot-spot’) decontamination of a chromate damage in connection with an innovative pump-and-treat-technique has been developed. Iron granulates show significant higher reduction rates, using fluidized bed conditions, than a literature study with a fixed bed installation of small-sized iron granules. First results from an abandoned tannery site concerning injections of sodium dithionite as a chromate reductant for the vadose zone in combination with a pump-and-treat-method, allying the advantages of granulated zero valent iron (ZVI), are reported. Reduction amounts of chromate have been found up to 88% compared with initial values in the soil after a soil water exchange of 8 pore volumes within 2.5 months. Chromate concentrations in the pumped effluent have been reduced to under the detection limit of 0.005 mg/L by treatment with ZVI in the pilot plant. - Highlights: • Fe-granules show high Cr(VI)-reduction rates using fluidized bed conditions. • No respective negligible passivation effects on the surface of the iron granulates. • P and T-method by using ZVI in a FBR is very effective for Cr(VI) remediation. • The process provides no increase in salinity of the treated effluent.

  4. Spatial and temporal aspects of chromatic adaptation and their functional significance for colour constancy.

    Science.gov (United States)

    Werner, Annette

    2014-11-01

    Illumination in natural scenes changes at multiple temporal and spatial scales: slow changes in global illumination occur in the course of a day, and we encounter fast and localised illumination changes when visually exploring the non-uniform light field of three-dimensional scenes; in addition, very long-term chromatic variations may come from the environment, like for example seasonal changes. In this context, I consider the temporal and spatial properties of chromatic adaptation and discuss their functional significance for colour constancy in three-dimensional scenes. A process of fast spatial tuning in chromatic adaptation is proposed as a possible sensory mechanism for linking colour constancy to the spatial structure of a scene. The observed middlewavelength selectivity of this process is particularly suitable for adaptation to the mean chromaticity and the compensation of interreflections in natural scenes. Two types of sensory colour constancy are distinguished, based on the functional differences of their temporal and spatial scales: a slow type, operating at a global scale for the compensation of the ambient illumination; and a fast colour constancy, which is locally restricted and well suited to compensate region-specific variations in the light field of three dimensional scenes. Copyright © 2014 Elsevier B.V. All rights reserved.

  5. Measurement of chromatic dispersion of microstructured polymer fibers by white-light spectral interferometry

    DEFF Research Database (Denmark)

    Hlubina, Petr; Ciprian, Dalibor; Frosz, Michael Henoch;

    2009-01-01

    of the method by measuring the wavelength dependence of the differential group refractive index of a pure silica fiber. We apply a five-term power series fit to the measured data and confirm by its differentiation that the chromatic dispersion of pure silica glass agrees well with theory. Second, we measure...

  6. On chromatic effects in observations of the Sun near the horizon

    Science.gov (United States)

    Devyatkin, A. V.; Slesarenko, V. Yu.

    2014-07-01

    The observability of the "green flash" in observations of the Sun near the horizon was calculated. The calculations were conducted with consideration for chromatic refraction, atmosphere transmission, spectral sensitivity of the eye, and image blurring due to the instability and inhomogeneity of the atmosphere.

  7. A "Green" Passivation of Zinc containing surfaces as an alternative to chromate

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Maahn, Ernst emanuel; Møller, Per

    1996-01-01

    With view to a replacement for chromate passivation, Molyphos was developed under the Danish Materials Programme I (MUP I). In the Danish Materials Programme II(MUP II), the further development of Molyphos a molybdate phosphate conversion coating has been undertaken by application of a sealer to ...

  8. Kunpeng Copper:The largest Copper Smelting Company of Sichuan

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>On September 9,Liangshan Mining Company’s 100,000 tons/year cathode copper project kicked off.It is another key project of the company following the successful launch of the 100,000 tons/year anode copper project.Based on ISA copper smelting technology of the largest open-cast copper mine in southwest China,

  9. Competitive sorption and diffusion of chromate and sulphate in a flow system with goethite in gel beads.

    Science.gov (United States)

    van Beinum, Wendy; Meeussen, Johannes C L; van Riemsdijk, Willem H

    2006-08-10

    Column experiments and model simulations were employed to evaluate the processes involved in multicomponent solute transport in a system with heterogeneous flow. Column experiments were performed with goethite embedded in polyacrylamide gel beads. The gel forms an immobile water region that can be accessed by diffusion. A two-region transport model with diffusion into spheres was combined with a surface complexation model to predict reactive transport in the goethite-gel bead system. Chromate and sulphate breakthrough curves were measured in a set of transport experiments, along with corresponding changes in the pH of the effluent. Sorption and transport of sulphate and chromate in separate columns were predicted from independently measured sorption parameters. The model overestimated the pH changes in the effluent, possibly because of proton buffering by the polyacrylamide gel. The effect of competitive sorption on transport was examined in experiments with both anions present. The model predicted the effect of competition very well in a system initially equilibrated with sulphate, followed by infiltration with chromate. However, when sulphate was infiltrated after equilibration with chromate, chromate desorption and sulphate adsorption were clearly overestimated by the transport model. The exchange between the more strongly bound chromate and the sulphate added subsequently may be too slow to cause a substantial chromate peak in the effluent. This suggests that the local equilibrium assumption was not applicable in this case.

  10. Modeling and design of a multichannel chromatic aberration compensated imaging system

    Science.gov (United States)

    Belay, Gebirie Y.; Ottevaere, Heidi; Vervaeke, Michael; Van Erps, Jürgen; Thienpont, Hugo

    2015-09-01

    Conventional multichannel imaging systems comprise of many optical channels having similar imaging properties, namely field-of-view (FOV) and angular resolution/magnification. We demonstrated that the different optical channels can be designed such that each optical channel captures a different FOV and angular resolution compared to its neighboring channels. We designed and experimentally demonstrated a three-channel multiresolution imaging system where the first optical channel has the narrowest FOV (7°) and highest angular resolution (0.0096°) and the third optical channel has the widest FOV (80°) and lowest angular resolution (0.078°)1. The second optical channel has intermediate properties. The performance of the demonstrated three-channel imaging system however was affected by chromatic aberrations as it was designed for a single wavelength of 587.6 nm. The first optical channel was largely influenced by longitudinal chromatic aberration while the third channel by lateral chromatic aberration. Therefore, we have replaced the aspherical refractive lenses by hybrid lenses, which contain diffractive structures on top of their refractive surfaces, in the three-channel multiresolution imaging system to reduce its chromatic aberrations. The performance of the three channels with hybrid lenses is compared with those of the corresponding channels without hybrid lenses. The longitudinal color aberration of the first optical channel has been reduced from 1.7 mm to 0.2 mm; whereas the lateral color aberration of the third optical channel has been reduced from 250 μm to 14 μm. In conclusion, the hybrid lenses have reduced the chromatic aberrations of the three channels and extended the operating spectral range of the imaging system in the visible wavelength range.

  11. 100-D Area In Situ Redox Treatability Test for Chromate-Contaminated Groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Mark D.; Vermeul, Vincent R.; Szecsody, James E.; Fruchter, Jonathan S.

    2000-10-12

    A treatability test was conducted for the In Situ Redox Manipulation (ISRM) technology at the 100 D Area of the U. S. Department of Energy's Hanford Site. The target contaminant was dissolved chromate in groundwater. The ISRM technology creates a permeable subsurface treatment zone to reduce mobile chromate in groundwater to an insoluble form. The ISRM permeable treatment zone is created by reducing ferric iron to ferrous iron within the aquifer sediments, which is accomplished by injecting aqueous sodium dithionite into the aquifer and then withdrawing the reaction products. The goal of the treatability test was to create a linear ISRM barrier by injecting sodium dithionite into five wells. Well installation and site characterization activities began in spring 1997; the first dithionite injection took place in September 1997. The results of this first injection were monitored through the spring of 1998. The remaining four dithionite injections were carried out in May through July of 1998.These five injections created a reduced zone in the Hanford unconfined aquifer approximately 150 feet in length (perpendicular to groundwater flow) and 50 feet wide. The reduced zone extended over the thickness of the unconfined zone. Analysis of post-emplacement groundwater samples showed concentrations of chromate, in the reduced zone decreased from approximately 1.0 mg/L before the tests to below analytical detection limits (<0.007 mg/L). Chromate concentrations also declined in downgradient monitoring wells to as low as 0.020 mg/L. These data, in addition to results from pre-test reducible iron characterization, indicate the barrier should be effective for 20 to 25 years. The 100-D Area ISRM barrier is being expanded to a length of up to 2,300 ft to capture a larger portion of the chromate plume.

  12. Assessing chromate availability in tropical ultramafic soils using isotopic exchange kinetics

    Energy Technology Data Exchange (ETDEWEB)

    Garnier, Jeremie; Quantin, Cecile [Univ. Paris Sud CNRS, Orsay (France); Echevarria, Guillaume [ENSAIA-INPL-INRA, Vandoeuvre-les-Nancy (France); Becquer, Thierry [IRD - Univ. Paris VI and XII, Montpellier (France)

    2009-10-15

    Background, aim, and scope The presence of labile chromate in the soils is an environmental problem because of its high toxicity. The isotopic exchange kinetics (IEK) methods have been shown to be a useful tool to measure the phytoavailability of major (P, K) and trace elements (Cd, Zn, Ni, Pb) in soils. This study focused on the potential of applying IEK for chromate to characterize its availability in two tropical ultramafic Ferralsols. Materials and methods Two Ferralsols (NIQ II and NIQ III) of the ultramafic complex of Niquelandia (Goias, Brazil), known to have a high content of extractable chromate, were investigated. We adapted IEK for chromate in order to distinguish different pools of available chromate according to their rate of exchange kinetic. Results The extractable Cr(III) ranged from 9 to 132 mg kg{sup -1}, whereas extractable Cr(VI) ranged from 64 to 1,014 mg kg{sup -1}. The intensity factor, i.e., concentration of soluble Cr, ranged from 78 to 231 {mu}g L{sup -1} in profile NIQ II and from 6 to 141 {mu}g L{sup -1} in profile NIQ III. The highest concentrations were found in both topsoils and in the NIQ II-5 horizon. Most of the Cr(VI) was labile in short (E{sub 0-1} {sub min}) or medium-term (E{sub 1} {sub min-24} {sub h}) in both soils. The E{sub 0-1} {sub min} and E{sub 1} {sub min-24} {sub h} represented 39 to 83% of labile Cr (VI) in NIQ II and 69 to 80% in NIQ III. A high quantity of Cr(VI) was thus extremely labile and highly available, particularly in NIQ II. Moreover, both soils had a high buffering capacity of soluble Cr(VI) by labile pools. (orig.)

  13. Degradation of azurite in mural paintings: distribution of copper carbonate, chlorides and oxalates by SRFTIR

    Science.gov (United States)

    Lluveras, A.; Boularand, S.; Andreotti, A.; Vendrell-Saz, M.

    2010-05-01

    This article illustrates the analysis by synchrotron micro-analytical techniques of an azurite painting presenting greenish chromatic degradation. The challenge of the experiments was to obtain the spatial distribution of the degradation products of azurite. Copper hydroxychlorides, carbonates and copper oxalates have been mapped by SR FTIR imaging of cross sections in transmission mode. To complement the information, Py/GC/MS and GC/MS techniques were applied in order to characterize the binding media and organic materials present as well as their degradation products. Results contribute to a better understanding of the decay of blue areas in ancient paintings not only from the particular point of view of azurite weathering, but also by adding information regarding the oxalates’ formation and their distribution in painting samples. Synchrotron radiation demonstrates its capability for the mapping in painting cross sections.

  14. Posttranslational regulation of copper transporters

    NARCIS (Netherlands)

    van den Berghe, P.V.E.

    2009-01-01

    The transition metal copper is an essential cofactor for many redox-active enzymes, but excessive copper can generate toxic reactive oxygen species. Copper homeostasis is maintained by highly conserved proteins, to balance copper uptake, distribution and export on the systemic and cellular level. Th

  15. Fabricating Copper Nanotubes by Electrodeposition

    Science.gov (United States)

    Yang, E. H.; Ramsey, Christopher; Bae, Youngsam; Choi, Daniel

    2009-01-01

    Copper tubes having diameters between about 100 and about 200 nm have been fabricated by electrodeposition of copper into the pores of alumina nanopore membranes. Copper nanotubes are under consideration as alternatives to copper nanorods and nanowires for applications involving thermal and/or electrical contacts, wherein the greater specific areas of nanotubes could afford lower effective thermal and/or electrical resistivities. Heretofore, copper nanorods and nanowires have been fabricated by a combination of electrodeposition and a conventional expensive lithographic process. The present electrodeposition-based process for fabricating copper nanotubes costs less and enables production of copper nanotubes at greater rate.

  16. Simultaneous and independent adaptive correction of spherical and chromatic aberration using an electron mirror and lens combination.

    Science.gov (United States)

    Fitzgerald, J P S; Word, R C; Könenkamp, R

    2012-04-01

    We present a theoretical analysis of an electrostatic triode mirror combined with an einzel lens for the correction of spherical and chromatic aberration. We show that this device adaptively corrects spherical and chromatic aberration simultaneously and independently. Chromatic aberration can be compensated over a relative range of -38% to +100%, and spherical aberration over ±100% range. We compare the analytic calculation with a numerical simulation and show that the two descriptions agree to within 5% in the relevant operating regime of the device.

  17. [Copper and the human body].

    Science.gov (United States)

    Krízek, M; Senft, V; Motán, J

    1997-11-19

    Copper is one of the essential trace elements. It is part of a number of enzymes. Deficiency of the element is manifested by impaired haematopoesis, bone metabolism, disorders of the digestive, cardiovascular and nervous system. Deficiency occurs in particular in patients suffering from malnutrition, malabsorption, great copper losses during administration of penicillamine. Sporadically copper intoxications are described (suicidal intentions or accidental ingestion of beverages with a high copper content). Acute exposure to copper containing dust is manifested by metal fume fever. Copper salts can produce local inflammations. Wilson's disease is associated with inborn impaired copper metabolism. In dialyzed patients possible contaminations of the dialyzate with copper must be foreseen as well as the possible release of copper from some dialyzation membranes. With the increasing amount of copper in the environment it is essential to monitor the contamination of the environment.

  18. COPPER, CHROMATE, AND ARSENATE ADSORPTION ON AN IRON-OXIDE ADSORBENT: (2) ADSORPTION MODELING. (R825689C025)

    Science.gov (United States)

    The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

  19. COPPER, CHROMATE, AND ARSENATE ADSORPTION ON AN IRON-OXIDE ADSORBENT: (1) ADSORPTION BEHAVIOR. (R825689C025)

    Science.gov (United States)

    The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Concl...

  20. Targeting copper in cancer therapy: 'Copper That Cancer'.

    Science.gov (United States)

    Denoyer, Delphine; Masaldan, Shashank; La Fontaine, Sharon; Cater, Michael A

    2015-11-01

    Copper is an essential micronutrient involved in fundamental life processes that are conserved throughout all forms of life. The ability of copper to catalyze oxidation-reduction (redox) reactions, which can inadvertently lead to the production of reactive oxygen species (ROS), necessitates the tight homeostatic regulation of copper within the body. Many cancer types exhibit increased intratumoral copper and/or altered systemic copper distribution. The realization that copper serves as a limiting factor for multiple aspects of tumor progression, including growth, angiogenesis and metastasis, has prompted the development of copper-specific chelators as therapies to inhibit these processes. Another therapeutic approach utilizes specific ionophores that deliver copper to cells to increase intracellular copper levels. The therapeutic window between normal and cancerous cells when intracellular copper is forcibly increased, is the premise for the development of copper-ionophores endowed with anticancer properties. Also under investigation is the use of copper to replace platinum in coordination complexes currently used as mainstream chemotherapies. In comparison to platinum-based drugs, these promising copper coordination complexes may be more potent anticancer agents, with reduced toxicity toward normal cells and they may potentially circumvent the chemoresistance associated with recurrent platinum treatment. In addition, cancerous cells can adapt their copper homeostatic mechanisms to acquire resistance to conventional platinum-based drugs and certain copper coordination complexes can re-sensitize cancer cells to these drugs. This review will outline the biological importance of copper and copper homeostasis in mammalian cells, followed by a discussion of our current understanding of copper dysregulation in cancer, and the recent therapeutic advances using copper coordination complexes as anticancer agents.

  1. METHOD OF SOFTWARE-BASED COMPENSATION OF TECHNOLOGICAL VARIATION IN CHROMATICITY COORDINATES OF LCD PANELS

    Directory of Open Access Journals (Sweden)

    I. O. Zharinov

    2015-05-01

    Full Text Available Subject of research. The problem of software-based compensation of technological variation in chromaticity coordinates of liquid crystal panels is considered. A method of software-based compensation of technological variation in chromaticity coordinates is proposed. The method provides the color reproduction characteristics of the series-produced samples on-board indication equipment corresponding to the sample equipment, which is taken as the standard. Method. Mathematical calculation of the profile is performed for the given model of the liquid crystal panel. The coefficients that correspond to the typical values of the chromaticity coordinates for the vertices of the triangle color coverage constitute a reference mathematical model of the plate LCD panel from a specific manufacturer. At the stage of incoming inspection the sample of the liquid crystal panel, that is to be implemented within indication equipment, is mounted on the lighting test unit, where Nokia-Test control is provided by the formation of the RGB codes for display the image of a homogeneous field in the red, green, blue and white. The measurement of the (x,y-chromaticity coordinates in red, green, blue and white colors is performed using a colorimeter with the known value of absolute error. Instead of using lighting equipment, such measurements may be carried out immediately on the sample indication equipment during customizing procedure. The measured values are used to calculate individual LCD-panel profile coefficients through the use of Grassman's transformation, establishing mutual relations between the XYZ-color coordinates and RGB codes to be used for displaying the image on the liquid crystal panel. The obtained coefficients are to be set into the memory of the graphics controller together with the functional software and then used for image displaying. Main results. The efficiency of the proposed method of software-based compensation for technological variation of

  2. Temporal analysis of the chromatic flash VEP--separate colour and luminance contrast components.

    Science.gov (United States)

    Klistorner, A; Crewther, D P; Crewther, S G

    1998-12-01

    Temporal analysis of the chromatic flash visual evoked potential (VEP) was studied in human subjects with normal and anomalous colour vision using a deterministic pseudo-random binary stimulus (VERIS). Five experiments were carried out on four normal subjects investigating heterochromatic red-green exchange and single colour/achromatic (either red/grey or green/grey) exchange over a wide range of luminance ratios for the two stimuli, the effects of lowered mean luminance on the chromatic VEP and the effects of colour desaturation at constant mean luminance and constant luminance contrast. Finally, the performance of three dichromats, a protanope and two deuteranopes, on heterochromatic exchange VEP and on colour desaturation were investigated. In contrast to the chromatic electroretinogram, which shows great symmetry with respect to luminance ratio on opposite sides of the isoluminant point, the chromatic VEP demonstrated a distinct asymmetry when the colours exchanged included red. On the red side of isoluminance (red more luminant than green), a wave with longer latency and altered waveform became dominant. The effects of green stimulation were indistinguishable from those of achromatic stimulation at the same luminance contrast over the whole range of chromatic contrast and for all levels of desaturation studied. Desaturation of red with constant luminance contrast (desaturated red/grey stimulation) resulted in a systematic alteration in the evoked waveform. Subtraction of the achromatic first- and second-order responses from responses recorded in the red desaturation series resulted in remarkably uniform waveforms, with peak amplitudes growing linearly with saturation. The absence of interaction between achromatic and coloured components for all (including the most intense colour) stimulus parameters used suggests that the generators of these components are separate. Recordings from the dichromats showed that the contrast response minimum shifted from the point

  3. LEP copper accelerating cavities

    CERN Multimedia

    Laurent Guiraud

    1999-01-01

    These copper cavities were used to generate the radio frequency electric field that was used to accelerate electrons and positrons around the 27-km Large Electron-Positron (LEP) collider at CERN, which ran from 1989 to 2000. The copper cavities were gradually replaced from 1996 with new superconducting cavities allowing the collision energy to rise from 90 GeV to 200 GeV by mid-1999.

  4. Rearing in different photic and spectral environments changes the optomotor response to chromatic stimuli in the cichlid fish Aequidens pulcher

    National Research Council Canada - National Science Library

    Kröger, Ronald H H; Knoblauch, Bettina; Wagner, Hans-Joachim

    2003-01-01

    .... Rearing blue acara (Aequidens pulcher; Cichlidae) under white lights of different intensities as well as deprivation of long wavelengths induced significant changes in the animals' responses to chromatic stimuli...

  5. Copper wire bonding

    CERN Document Server

    Chauhan, Preeti S; Zhong, ZhaoWei; Pecht, Michael G

    2014-01-01

    This critical volume provides an in-depth presentation of copper wire bonding technologies, processes and equipment, along with the economic benefits and risks.  Due to the increasing cost of materials used to make electronic components, the electronics industry has been rapidly moving from high cost gold to significantly lower cost copper as a wire bonding material.  However, copper wire bonding has several process and reliability concerns due to its material properties.  Copper Wire Bonding book lays out the challenges involved in replacing gold with copper as a wire bond material, and includes the bonding process changes—bond force, electric flame off, current and ultrasonic energy optimization, and bonding tools and equipment changes for first and second bond formation.  In addition, the bond–pad metallurgies and the use of bare and palladium-coated copper wires on aluminum are presented, and gold, nickel and palladium surface finishes are discussed.  The book also discusses best practices and re...

  6. Mutations in FMN Binding Pocket Diminish Chromate Reduction Rates for Gh-ChrR Isolated from Gluconacetobacter hansenii

    Energy Technology Data Exchange (ETDEWEB)

    Khaleel, Janin A.; Gong, Chunhong; Zhang, Yanfeng; Tan, Ruimin; Squier, Thomas C.; Jin, Hongjun

    2013-06-01

    A putative chromate ion binding site was identified proximal to a rigidly bound FMN from electron densities in the crystal structure of the quinone reductase from Gluconacetobacter hansenii (Gh-ChrR) (3s2y.pdb). To clarify the location of the chromate binding site, and to understand the role of FMN in the NADPH-dependent reduction of chromate, we have expressed and purified four mutant enzymes involving the site-specific substitution of individual side chains within the FMN binding pocket that form non-covalent bonds with the ribityl phosphate (i.e., S15A and R17A in loop 1 between β1 sheet and α1 helix) or the isoalloxanzine ring (E83A or Y84A in loop 4 between the β3 sheet and α4 helix). Mutations that selectively disrupt hydrogen bonds between either the N3 nitrogen on the isoalloxanzine ring (i.e., E83) or the ribitylphos- phoate (i.e., S15) respectively result in 50% or 70% reductions in catalytic rates of chromate reduction. In comparison, mutations that disrupt π-π ring stacking interactions with the isoal-loxanzine ring (i.e., Y84) or a salt bridge with the ribityl phosphate result in 87% and 97% inhibittion. In all cases there are minimal alterations in chromate binding affinities. Collectively, these results support the hypothesis that chromate binds proximal to FMN, and implicate a structural role for FMN positioning for optimal chromate reduction rates. As side chains proximal to the β3/α4 FMN binding loop 4 contribute to both NADH and metal ion binding, we propose a model in which structural changes around the FMN binding pocket couples to both chromate and NADH binding sites.

  7. Demonstration and Validation of a Replacement Alternative to the Chromate Wash Primer DOD-P-15328D

    Science.gov (United States)

    2006-04-01

    system. The current wash primer is a low-solids, solvent-based polyvinyl butyral that contains phosphoric acid and zinc chromate that promotes adhesion...prior to the application of an epoxy primer/polyurethane topcoat CARC system. The current wash primer is a low-solids, solvent-based polyvinyl ... butyral that contains phosphoric acid and zinc chromate that promotes adhesion and minimizes corrosion. This coating contains large amounts of volatile

  8. Chromate Reductase YieF from Escherichia coli Enhances Hexavalent Chromium Resistance of Human HepG2 Cells

    Directory of Open Access Journals (Sweden)

    Xuan Liu

    2015-05-01

    Full Text Available Hexavalent chromium (Cr(VI is a serious environmental pollutant and human toxicant. Mammalian cells are very sensitive to chromate as they lack efficient chromate detoxifying strategy, e.g., chromate-reducing genes that are widely present in prokaryotes. To test whether introduction of prokaryotic chromate-reducing gene into mammalian cells could render higher chromate resistance, an Escherichia coli chromate-reducing gene yieF was transfected into human HepG2 cells. The expression of yieF was measured in stably transfected cells HepG2-YieF by quantitative RT-PCR and found up-regulated by 3.89-fold upon Cr(VI induction. In chromate-reducing ability test, HepG2-YieF cells that harbored the reductase showed significantly higher reducing ability of Cr(VI than HepG2 control cells. This result was further supported by the evidence of increased Cr(VI-removing ability of crude cell extract of HepG2-YieF. Moreover, HepG2-YieF demonstrated 10% higher viability and decreased expression of GSH synthesizing enzymes under Cr(VI stress. Subcellular localization of YieF was determined by tracing GFP-YieF fusion protein that was detected in both nucleus and cytoplasm by laser confocal microscopy. Altogether, this study successfully demonstrated that the expression of a prokaryotic Cr(VI-reducing gene yieF endowed mammalian cell HepG2 with enhanced chromate resistance, which brought new insight of Cr(VI detoxification in mammalian cells.

  9. Chromate Reductase YieF from Escherichia coli Enhances Hexavalent Chromium Resistance of Human HepG2 Cells.

    Science.gov (United States)

    Liu, Xuan; Wu, Gaofeng; Zhang, Yanli; Wu, Dan; Li, Xiangkai; Liu, Pu

    2015-05-26

    Hexavalent chromium (Cr(VI)) is a serious environmental pollutant and human toxicant. Mammalian cells are very sensitive to chromate as they lack efficient chromate detoxifying strategy, e.g., chromate-reducing genes that are widely present in prokaryotes. To test whether introduction of prokaryotic chromate-reducing gene into mammalian cells could render higher chromate resistance, an Escherichia coli chromate-reducing gene yieF was transfected into human HepG2 cells. The expression of yieF was measured in stably transfected cells HepG2-YieF by quantitative RT-PCR and found up-regulated by 3.89-fold upon Cr(VI) induction. In chromate-reducing ability test, HepG2-YieF cells that harbored the reductase showed significantly higher reducing ability of Cr(VI) than HepG2 control cells. This result was further supported by the evidence of increased Cr(VI)-removing ability of crude cell extract of HepG2-YieF. Moreover, HepG2-YieF demonstrated 10% higher viability and decreased expression of GSH synthesizing enzymes under Cr(VI) stress. Subcellular localization of YieF was determined by tracing GFP-YieF fusion protein that was detected in both nucleus and cytoplasm by laser confocal microscopy. Altogether, this study successfully demonstrated that the expression of a prokaryotic Cr(VI)-reducing gene yieF endowed mammalian cell HepG2 with enhanced chromate resistance, which brought new insight of Cr(VI) detoxification in mammalian cells.

  10. Standard Specification for Copper-Aluminum-Silicon-Cobalt Alloy, Copper-Nickel-Silicon-Magnesium Alloy, Copper-Nickel-Silicon Alloy, Copper-Nickel-Aluminum-Magnesium Alloy, and Copper-Nickel-Tin Alloy Sheet and Strip

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2015-01-01

    Standard Specification for Copper-Aluminum-Silicon-Cobalt Alloy, Copper-Nickel-Silicon-Magnesium Alloy, Copper-Nickel-Silicon Alloy, Copper-Nickel-Aluminum-Magnesium Alloy, and Copper-Nickel-Tin Alloy Sheet and Strip

  11. Discrimination of luminance and chromaticity differences by dichromatic and trichromatic monkeys.

    Science.gov (United States)

    Jacobs, G H

    1990-01-01

    Dichromatic and trichromatic representatives from two genera of platyrrhine monkeys that show widespread color vision polymorphism (Saguinus--tamarins, Saimiri--squirrel monkeys) were tested for their abilities to make increment-threshold and flicker discriminations based on luminance and chromaticity differences. The details of these tests were arranged to attempt to emphasize the relative contributions to visual behavior of non-opponent and spectrally-opponent neural mechanisms. The results indicate that dichromatic and trichromatic monkeys differ only trivially on tests where performance is based on the contributions of non-opponent mechanisms, that the contribution of spectrally opponent mechanisms to the "brightness signal" is very similar in trichromatic and dichromatic monkeys, and that in increment-threshold discriminations where there are both chromaticity and luminance cues some test wavelengths yield superior performance for trichromats while others appear to favor the dichromat.

  12. Design of macro-filter-lens with simultaneous chromatic and geometric aberration correction.

    Science.gov (United States)

    Prasad, Dilip K; Brown, Michael S

    2014-01-01

    A macro-filter-lens design that can correct for chromatic and geometric aberrations simultaneously while providing for a long focal length is presented. The filter is easy to fabricate since it involves two spherical surfaces and a planar surface. Chromatic aberration correction is achieved by making all the rays travel the same optical distance inside the filter element (negative meniscus). Geometric aberration is corrected for by the lens element (plano-convex), which makes the output rays parallel to the optic axis. This macro-filter-lens design does not need additional macro lenses and it provides an inexpensive and optically good (aberration compensated) solution for macro imaging of objects not placed close to the camera.

  13. Low-Beta Insertions inducing Chromatic Aberrations in Storage Rings and their Local and Global Correction

    CERN Document Server

    Fartoukh, S

    2010-01-01

    The chromatic aberrations induced by low-β insertions can seriously limit the performance of circular colliders. The impact is twofold: (1) a substantial off-momentum beta-beating wave traveling around the ring and leading to a net reduction of the mechanical aperture of the low-beta quadrupoles but also impacting on the hierarchy of the collimator and protection devices of the machine, (2) a huge non-linear chromaticity which, when combined with the magnetic imperfections of the machine, could substantially reduce the momentum acceptance of the ring by pushing slightly off-momentum particles towards non-linear resonances. These effects will be analyzed and illustrated in the framework of the LHC insertions upgrade Phase I [1] and a strategy for correction will be developed, requiring a deep modification of the LHC overall optics.

  14. Three dimensional analysis of chromatic aberration in diffractive elements with extended depth of focus.

    Science.gov (United States)

    Mas, D; Espinosa, J; Perez, J; Illueca, C

    2007-12-24

    The paper presents the polychromatic analysis of two diffractive optical elements with extended depth of focus: the linear axicon and the light sword optical element. Chromatic aberration produces axial displacement of the focal segment line. Thus, we explore the possibility of extending the focal depth of these elements to permit superposition of the chromatic foci. In the case of an axicon, we achieve an achromatic zone where focusing is produced. In the case of the light sword element, we show that the focusing segment is out of axis. Therefore a superposition of colors is produced, but not on axis overlapping. Instead, three colored and separated foci are simultaneously obtained in a single plane. Three dimensional structures of the propagated beams are analyzed in order to provide better understanding of the properties and applications of such elements.

  15. Investigating the influence of chromatic aberration and optical illumination bandwidth on fundus imaging in rats

    Science.gov (United States)

    Li, Hao; Liu, Wenzhong; Zhang, Hao F.

    2015-10-01

    Rodent models are indispensable in studying various retinal diseases. Noninvasive, high-resolution retinal imaging of rodent models is highly desired for longitudinally investigating the pathogenesis and therapeutic strategies. However, due to severe aberrations, the retinal image quality in rodents can be much worse than that in humans. We numerically and experimentally investigated the influence of chromatic aberration and optical illumination bandwidth on retinal imaging. We confirmed that the rat retinal image quality decreased with increasing illumination bandwidth. We achieved the retinal image resolution of 10 μm using a 19 nm illumination bandwidth centered at 580 nm in a home-built fundus camera. Furthermore, we observed higher chromatic aberration in albino rat eyes than in pigmented rat eyes. This study provides a design guide for high-resolution fundus camera for rodents. Our method is also beneficial to dispersion compensation in multiwavelength retinal imaging applications.

  16. Low-Beta insertions inducing chromatic aberrations in storage rings and their local and global correction

    CERN Document Server

    Fartoukh, S

    2010-01-01

    The chromatic aberrations induced by low-β insertions can seriously limit the performance of circular colliders. The impact is twofold: (1) a substantial off-momentum beta-beating wave traveling around the ring and leading to a net reduction of the mechanical aperture of the lowbeta quadrupoles but also impacting on the hierarchy of the collimator and protection devices of the machine, (2) a huge non-linear chromaticity which, when combined with the magnetic imperfections of the machine, could substantially reduce the momentum acceptance of the ring by pushing slightly off-momentum particles towards non-linear resonances. These effects will be analyzed and illustrated in the framework of the LHC insertions upgrade Phase I [1] and a strategy for correction will be developed, requiring a deep modification of the LHC overall optics.

  17. Spectral switches of partially coherent light focused by a filter-lens system with chromatic aberration.

    Science.gov (United States)

    Pu, Jixiong; Cai, Chao; Nemoto, Shojiro

    2004-06-01

    It is shown that when partially coherent polychromatic light is focused by a filter-lens system with chromatic aberration, a spectral shift exists in the focused field, and a spectral switch that is defined as a sharp transition of the spectral shift also takes place at some positions of the focused field. The influence of the chromatic aberration of the lens, the coherence of the partially coherent light in the filter (a circular aperture), the radius of the aperture, and the spectral width of the partially coherent light in the aperture on the spectral shift and the spectral switch are investigated in detail. The numerical results show that these parameters affect the spectral shift and the spectral switch significantly. Potential applications of the spectral shift and the spectral switch of the partially coherent light are discussed.

  18. The detection of various color combinations under different chromatic ambient illuminations.

    Science.gov (United States)

    Neri, D F; Luria, S M; Kobus, D A

    1986-06-01

    Our purpose was to reveal the effects of ambient illumination color and various foreground/background color pairings on a choice reaction time task performed on a color CRT. Six men and two women with normal color vision served as observers in a four-alternative forced choice procedure. A small (18' visual angle) colored circle appeared in the center of one of the unmarked quadrants of the screen. The observer's task was to respond as quickly as possible to this target by pressing one of four buttons corresponding to its location. We found that target colors that were opponent to the background colors were most quickly detected. Detection was enhanced by maximizing both brightness and chromatic contrast, but brightness contrast was much more effective. Chromatic ambient lighting which was a log unit dimmer than the target luminance had no effect on performance.

  19. Competitive adsorption of boric acid and chromate onto alumina in aqueous solutions.

    Science.gov (United States)

    Demetriou, A; Pashalidis, I

    2014-01-01

    The competitive adsorption of boric acid and chromate from aqueous solutions by alumina has been investigated by spectrophotometry at pH 8, ionic strength = 0.0, 0.1 and 1.0 M NaClO4, T = 22 ± 3 °C and under normal atmospheric conditions. The experimental data show that addition of excess boric acid in the system leads to the increase of Cr(VI) concentration in solution, indicating the replacement of adsorbed chromate by boron on the alumina surface. Data evaluation results in the determination of the competition reaction constant and the formation constant of the Cr(VI) surface complexes, which are logKCr(VI)-B(III) = -3.5 ± 0.2 and logβ*Cr = 7.6 ± 0.3, respectively.

  20. Thermal treatment of solid waste in view of recycling: Chromate and molybdate formation and leaching behaviour.

    Science.gov (United States)

    Verbinnen, Bram; Billen, Pieter; Vandecasteele, Carlo

    2014-06-01

    Elevated Cr and Mo concentrations are often found in leachates of thermally treated solid waste, but there is no general explanation for this so far. Therefore, we studied the leaching behaviour after thermal treatment as a function of heating temperature and residence time for two types of solid waste: contaminated sludge and bottom ash from municipal solid waste incineration. The leaching behaviour of both waste streams was compared with experiments on synthetic samples, allowing deduction of a general mechanism for Cr and Mo leaching. Cr and Mo showed a similar leaching behaviour: after an initial increase, the leaching decreased again at higher temperatures. Oxidation of these elements from their lower oxidation states to chromate and molybdate at temperatures up to 600 °C was responsible for the increased leaching. At higher temperatures, both Mo and Cr leaching decreased again owing to the formation of an amorphous phase, incorporating the newly formed chromate and molybdate salts, which prevents them from leaching.

  1. Dosage-Dependent Proteome Response of Shewanella oneidensis MR-1 to Chromate Insult

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, Melissa R.; VerBerkmoes, Nathan C.; Chourey, Karuna; Brown, Steven D.; Hettich, Robert L.; Thompson, Dorothea K.

    2006-04-05

    Shewanella oneidensis MR-1 is a gram-negative, facultatively anaerobic bacterium originally isolated from a freshwater lake. S. oneidensis MR-1 has the ability to reduce toxic metal ions [e.g., Cr(VI) and U(VI)] found in industrial and governmental waste sites. Cells were grown and exposed to three different metal concentrations in order to probe the dosage response of S. oneidensis MR-1 to Cr(VI) in the form of chromate. Protein fractions were digested with trypsin and analyzed with a multidimensional HPLC-NanoESIMS/MS protocol. The goal of this work is to identify protein components of pathways/mechanisms responsible for both detoxification and reduction of chromate.

  2. Psychophysical Evaluation of Achromatic and Chromatic Vision of Workers Chronically Exposed to Organic Solvents

    Science.gov (United States)

    Lacerda, Eliza Maria da Costa Brito; Lima, Monica Gomes; Rodrigues, Anderson Raiol; Teixeira, Cláudio Eduardo Correa; de Lima, Lauro José Barata; Ventura, Dora Fix; Silveira, Luiz Carlos de Lima

    2012-01-01

    The purpose of this paper was to evaluate achromatic and chromatic vision of workers chronically exposed to organic solvents through psychophysical methods. Thirty-one gas station workers (31.5 ± 8.4 years old) were evaluated. Psychophysical tests were achromatic tests (Snellen chart, spatial and temporal contrast sensitivity, and visual perimetry) and chromatic tests (Ishihara's test, color discrimination ellipses, and Farnsworth-Munsell 100 hue test—FM100). Spatial contrast sensitivities of exposed workers were lower than the control at spatial frequencies of 20 and 30 cpd whilst the temporal contrast sensitivity was preserved. Visual field losses were found in 10–30 degrees of eccentricity in the solvent exposed workers. The exposed workers group had higher error values of FM100 and wider color discrimination ellipses area compared to the controls. Workers occupationally exposed to organic solvents had abnormal visual functions, mainly color vision losses and visual field constriction. PMID:22220188

  3. Single bunch transverse instability in a circular accelerator with chromaticity and space charge

    CERN Document Server

    Balbekov, V

    2015-01-01

    Transverse instability of a bunch in a circular accelerator is elaborated in this paper. New tree-modes model is proposed and developed to describe the most unstable modes of the bunch. The model includes chromaticity and space charge, and can be used with any bunch and wake forms. Dispersion relation for the bunch eigentunes is obtained in form of a third-order algebraic equation. Known head-tail and TMCI modes appear as the ultimate cases which are distinctly bounded at zero chromaticity only. It is shown that the instability parameters depend only slightly on the bunch model but are rather sensitive to the wake shape. Resistive wall wake is considered in detail including a comparison of single and collective effects. It is shown that space charge influence depends on sign of the wake function enhancing the stability with negative one.

  4. Psychophysical Evaluation of Achromatic and Chromatic Vision of Workers Chronically Exposed to Organic Solvents

    Directory of Open Access Journals (Sweden)

    Eliza Maria da Costa Brito Lacerda

    2012-01-01

    Full Text Available The purpose of this paper was to evaluate achromatic and chromatic vision of workers chronically exposed to organic solvents through psychophysical methods. Thirty-one gas station workers (31.5 ± 8.4 years old were evaluated. Psychophysical tests were achromatic tests (Snellen chart, spatial and temporal contrast sensitivity, and visual perimetry and chromatic tests (Ishihara's test, color discrimination ellipses, and Farnsworth-Munsell 100 hue test—FM100. Spatial contrast sensitivities of exposed workers were lower than the control at spatial frequencies of 20 and 30 cpd whilst the temporal contrast sensitivity was preserved. Visual field losses were found in 10–30 degrees of eccentricity in the solvent exposed workers. The exposed workers group had higher error values of FM100 and wider color discrimination ellipses area compared to the controls. Workers occupationally exposed to organic solvents had abnormal visual functions, mainly color vision losses and visual field constriction.

  5. The Coated-Wire Ion Selective Electrode (CWISE of Chromate Using PVC-Membrane Based on Chitosan as A Carrier

    Directory of Open Access Journals (Sweden)

    Dedeh Kurniasih

    2012-10-01

    Full Text Available A coated-wire ion selective electrode (CWISE based on chitosan as a carrier for detection of chromate, was developed. CWISE has easy measurement for field analysis, good selectivity and sensitivity. The CWISE’s membrane consist of mixture an active material of chitosan, aliquat 336-chromate, polyvinylchloride (PVC and dioctylphtalate (DOP as plasticizer = 4:0.5:35:60.5 (% w/w dissolved in tetrahydrofuran (THF solvent (1:3 w/v. The electrode exhibited a good Nernstian slope of 29.77±0.03 mV/decade and a linear concentration range from 10-6 to 10-1 M for chromate. The limit of detection was 1.862 x 10-6 M. It had response time of 20 – 40 sec, and could be used for 49 days. This chromate selective-electrode was found more selective towards the chromate ion than other anions, useable in pH range of 5.0 – 9.0 and temperature of 20 – 50 oC. It was applied as an electrode for direct determination of chromate in water samples and their result compared to standard spectrophotometric method.

  6. The chromatic number of a graph of girth 5 on a fixed surface

    DEFF Research Database (Denmark)

    Thomassen, Carsten

    2003-01-01

    We prove a color extension result implying that, for every fixed surface S, there are only finitely many 4-color-critical graphs of girth 5 on S. The result is best possible in the sense that there are infinitely many 4-color-critical graphs of girth 4 on S, except when S is the sphere......, As a consequence, the chromatic number of graphs of girth 5 on S can be found in polynomial time....

  7. LHC IR upgrade dipole first with chromaticity and dynamic aperture issues

    CERN Document Server

    de Maria, R

    2007-01-01

    A dipole first layout for the LHC interaction region upgrade, while offering a potential reduction of the limitations due the long range beam-beam collisions, charged debris with respect to the quadrupole first layout, presents an enhancement of the chromatic and geometric aberration due large values in the triplet. These two effects are studied in the following for the dipole first option presented in [1].

  8. Errors in confocal fluorescence ratiometric imaging microscopy due to chromatic aberration.

    Science.gov (United States)

    Lin, Yuxiang; Gmitro, Arthur F

    2011-01-01

    Confocal fluorescence ratiometric imaging is an optical technique used to measure a variety of important biological parameters. A small amount of chromatic aberration in the microscope system can introduce a variation in the signal ratio dependent on the fluorophore concentration gradient along the optical axis and lead to bias in the measurement. We present a theoretical model of this effect. Experimental results and simulations clearly demonstrate that this error can be significant and should not be ignored.

  9. Chromatic error correction of diffractive optical elements at minimum etch depths

    Science.gov (United States)

    Barth, Jochen; Gühne, Tobias

    2014-09-01

    The integration of diffractive optical elements (DOE) into an optical design opens up new possibilities for applications in sensing and illumination. If the resulting optics is used in a larger spectral range we must correct not only the chromatic error of the conventional, refractive, part of the design but also of the DOE. We present a simple but effective strategy to select substrates which allow the minimum etch depths for the DOEs. The selection depends on both the refractive index and the dispersion.

  10. A zero-free interval for chromatic polynomials of graphs with 3-leaf spanning trees

    DEFF Research Database (Denmark)

    Perrett, Thomas

    2016-01-01

    It is proved that if G is a graph containing a spanning tree with at most three leaves, then the chromatic polynomial of G has no roots in the interval (1,t1], where t1≈1.2904 is the smallest real root of the polynomial (t-2)6+4(t-1)2 (t-2)3-(t-1)4. We also construct a family of graphs containing...

  11. Proteomics reveals a core molecular response of Pseudomonas putida F1 to acute chromate challenge

    Directory of Open Access Journals (Sweden)

    McCarthy Andrea T

    2010-05-01

    Full Text Available Abstract Background Pseudomonas putida is a model organism for bioremediation because of its remarkable metabolic versatility, extensive biodegradative functions, and ubiquity in contaminated soil environments. To further the understanding of molecular pathways responding to the heavy metal chromium(VI [Cr(VI], the proteome of aerobically grown, Cr(VI-stressed P. putida strain F1 was characterized within the context of two disparate nutritional environments: rich (LB media and minimal (M9L media containing lactate as the sole carbon source. Results Growth studies demonstrated that F1 sensitivity to Cr(VI was impacted substantially by nutrient conditions, with a carbon-source-dependent hierarchy (lactate > glucose >> acetate observed in minimal media. Two-dimensional HPLC-MS/MS was employed to identify differential proteome profiles generated in response to 1 mM chromate under LB and M9L growth conditions. The immediate response to Cr(VI in LB-grown cells was up-regulation of proteins involved in inorganic ion transport, secondary metabolite biosynthesis and catabolism, and amino acid metabolism. By contrast, the chromate-responsive proteome derived under defined minimal growth conditions was characterized predominantly by up-regulated proteins related to cell envelope biogenesis, inorganic ion transport, and motility. TonB-dependent siderophore receptors involved in ferric iron acquisition and amino acid adenylation domains characterized up-regulated systems under LB-Cr(VI conditions, while DNA repair proteins and systems scavenging sulfur from alternative sources (e.g., aliphatic sulfonates tended to predominate the up-regulated proteome profile obtained under M9L-Cr(VI conditions. Conclusions Comparative analysis indicated that the core molecular response to chromate, irrespective of the nutritional conditions tested, comprised seven up-regulated proteins belonging to six different functional categories including transcription, inorganic ion

  12. INFLUENCE OF CHROMATIC DISPERSION, DISPERSION SLOPE, DISPERSION CURVATURE ON MICROWAVE GENERATION USING TWO CASCADE MODULATORS

    OpenAIRE

    Mandeep Singh; S.K. Raghuwanshi

    2013-01-01

    This work presents a theoretical study of harmonic generation of microwave signals after detection of a modulated optical carrier in cascaded two electro-optic modulators. Dispersion is one of the major limiting factors for microwave generation in microwave photonics. In this paper, we analyze influence of chromatic dispersion, dispersion slope, dispersion curvature on microwave generation using two cascaded MZMs and it has been found that output intensity of photodetector reduces when disper...

  13. Nitration of phenolic compounds and oxidation of hydroquinones using tetrabutylammonium chromate and dichromate under aprotic conditions

    Indian Academy of Sciences (India)

    Ali Reza Pourali; Arezou Goli

    2011-01-01

    In this work, we have reported a mild, efficient and selective method for the mononitration of phenolic compounds using sodium nitrite in the presence of tetrabutylammonium dichromate (TBAD) and oxidation of hydroquinones to quinones with TBAD in CH2Cl2. Using this method, high yields of nitrophenols and quinones were obtained under neutral aprotic conditions. Tetrabutylammonium chromate (TBAC) can also be used as oxidant at same conditions.

  14. Durability to marine environment of innovative products for consolidation and chromatic reintegration of historical renders

    OpenAIRE

    Matos, Margarida; Borsoi, Giovanni; Veiga,Rosário; Faria, Paulina; Santos-Silva, António

    2014-01-01

    9th International Masonry Conference 2014, 7-9 July, Universidade do Minho, Guimarães A common degradation phenomenon in historical renders is the cohesion loss of the binder:aggregate system, which is often linked to the presence of soluble salts. Cohesion is recovered through the application of consolidant products, being inorganics preferred due to their compatibility and durability. The aesthetic function can be restored by chromatic reintegration. The aim of this paper is the as...

  15. Seeing red: affect modulation and chromatic color responses on the Rorschach.

    Science.gov (United States)

    Malone, Johanna C; Stein, Michelle B; Slavin-Mulford, Jenelle; Bello, Iruma; Sinclair, S Justin; Blais, Mark A

    2013-01-01

    Psychoanalytic theories suggest that color perception on the Rorschach relates to affective modulation. However, this idea has minimal empirical support. Using a clinical sample, the authors explored the cognitive and clinical correlates of Rorschach color determinants and differences among four affective modulation subtypes: Controlled, Balanced, Under-Controlled, and Flooded. Subtypes were differentiated by measures of affective regulation, reality testing/confusion, and personality traits. Initial support for the relationship of chromatic color response styles and affective modulation was found.

  16. Application of chromatic confocal displacement sensor in measurement of tip clearance

    Science.gov (United States)

    Bi, Chao; Li, Di; Fang, Jianguo; Zhang, Bin

    2016-10-01

    In the field of aeronautics, the tip clearance of rotor exerts a crucial influence on the performance of the aero engine. As defined as the radial distance between the top of the blade and the inner wall of the casing, the tip clearance of too large or small size will adversely affect the normal running of the engine. In order to realize accurate measurement of the tip clearance in a simple way, a non-contact measuring method by the chromatic confocal displacement sensor is proposed in the paper. The sensor possesses the advantages such as small volume, good signal-to-noise ratio, high accuracy and response frequency etc., which make it be widely used in engineering and industry. For testing the performance and potential application of the sensor, a simulation testing platform is established. In the platform, a simulation blisk is installed on the air bearing spindle and a chromatic confocal displacement sensor is fixed on the platform to measure the displacement variation of the blade tip, which can be used to characterize the variation of the tip clearance. In the simulation experiments, both of single and continuous measurement of the tip clearance of the 36 blades on the blisk is executed. As the results of experiments show, the chromatic confocal displacement sensor can meet the requirements of measuring task, in which both of high measuring efficiency and accuracy could be achieved. Therefore, the measuring method proposed in the paper can be utilized in the actual assembling sites of the aero engine.

  17. Chromate and selenate hydrocalumite solid solutions and their applications in waste treatment

    Institute of Scientific and Technical Information of China (English)

    ZHANG Min; Eric J. Reardon

    2005-01-01

    Hydrocalumite, a calcium aluminate hydrate phase, consists of positively-charged structure units, and is therefore an ideal candidate for accommodating anionic contaminants. In this study, a series of batch experiments was carried out to examine the uptake of chromate and selenate by hydrocalumite. To determine the uptake capacity and long-term stability, hydrocalumite solid solutions between chromate/selenate and hydroxyl were synthesized over a reaction time of more than one year. At a ratio of water to initial solids added (CaAl2O4+CaO) of 75: 1, the maximum uptake capacities were over 77 and 114 g/kg for Cr and Se, respectively.These values are very close to the theoretical uptake capacities of chromate and selenate hydrocalumite end-members (81 and 118 g/kg, respectively). The oxyanion removal efficiency from solution was above 95%. Due to the high uptake capacity and anion removal efficiency of hydrocalumites, their application in wastewater treatment is promising. Hydrocalumites are also important hydration products of cementitious materials and the long-term stability of these phases is of significance for application in solidification/stabilization technology.

  18. Chromatic processing in the anterior optic tubercle of the honey bee brain.

    Science.gov (United States)

    Mota, Theo; Gronenberg, Wulfila; Giurfa, Martin; Sandoz, Jean-Christophe

    2013-01-02

    Color vision in honey bees (Apis mellifera) has been extensively studied at the behavioral level and, to a lesser degree, at the physiological level by means of electrophysiological intracellular recordings of single neurons. Few visual neurons have been so far characterized in the lateral protocerebrum of bees. Therefore, the possible implication of this region in chromatic processing remains unknown. We performed in vivo calcium imaging of interneurons in the anterior optic tubercle (AOTu) of honey bees upon visual stimulation of the compound eye to analyze chromatic response properties. Stimulation with distinct monochromatic lights (ultraviolet [UV], blue, and green) matching the sensitivity of the three photoreceptor types of the bee retina induced different signal amplitudes, temporal dynamics, and spatial activity patterns in the AOTu intertubercle network, thus revealing intricate chromatic processing properties. Green light strongly activated both the dorsal and ventral lobes of the AOTu's major unit; blue light activated the dorsal lobe more while UV light activated the ventral lobe more. Eye stimulation with mixtures of blue and green light induced suppression phenomena in which responses to the mixture were lower than those to the color components, thus concurring with color-opponent processing. These data provide evidence for a spatial segregation of color processing in the AOTu, which may serve for navigation purposes.

  19. Chromatic Aberration Correction for Atomic Resolution TEM Imaging from 20 to 80 kV

    Science.gov (United States)

    Linck, Martin; Hartel, Peter; Uhlemann, Stephan; Kahl, Frank; Müller, Heiko; Zach, Joachim; Haider, Max.; Niestadt, Marcel; Bischoff, Maarten; Biskupek, Johannes; Lee, Zhongbo; Lehnert, Tibor; Börrnert, Felix; Rose, Harald; Kaiser, Ute

    2016-08-01

    Atomic resolution in transmission electron microscopy of thin and light-atom materials requires a rigorous reduction of the beam energy to reduce knockon damage. However, at the same time, the chromatic aberration deteriorates the resolution of the TEM image dramatically. Within the framework of the SALVE project, we introduce a newly developed Cc/Cs corrector that is capable of correcting both the chromatic and the spherical aberration in the range of accelerating voltages from 20 to 80 kV. The corrector allows correcting axial aberrations up to fifth order as well as the dominating off-axial aberrations. Over the entire voltage range, optimum phase-contrast imaging conditions for weak signals from light atoms can be adjusted for an optical aperture of at least 55 mrad. The information transfer within this aperture is no longer limited by chromatic aberrations. We demonstrate the performance of the microscope using the examples of 30 kV phase-contrast TEM images of graphene and molybdenum disulfide, showing unprecedented contrast and resolution that matches image calculations.

  20. Depth position detection for fast moving objects in sealed microchannel utilizing chromatic aberration.

    Science.gov (United States)

    Lin, Che-Hsin; Su, Shin-Yu

    2016-01-01

    This research reports a novel method for depth position measurement of fast moving objects inside a microfluidic channel based on the chromatic aberration effect. Two band pass filters and two avalanche photodiodes (APD) are used for rapid detecting the scattered light from the passing objected. Chromatic aberration results in the lights of different wavelengths focus at different depth positions in a microchannel. The intensity ratio of two selected bands of 430 nm-470 nm (blue band) and 630 nm-670 nm (red band) scattered from the passing object becomes a significant index for the depth information of the passing object. Results show that microspheres with the size of 20 μm and 2 μm can be resolved while using PMMA (Abbe number, V = 52) and BK7 (V = 64) as the chromatic aberration lens, respectively. The throughput of the developed system is greatly enhanced by the high sensitive APDs as the optical detectors. Human erythrocytes are also successfully detected without fluorescence labeling at a high flow velocity of 2.8 mm/s. With this approach, quantitative measurement for the depth position of rapid moving objects inside a sealed microfluidic channel can be achieved in a simple and low cost way.

  1. Chromatic aberration short-wave infrared spectroscopy: nanoparticle spectra without a spectrometer.

    Science.gov (United States)

    Streit, Jason K; Bachilo, Sergei M; Weisman, R Bruce

    2013-02-05

    A new method is described for measuring the short-wave infrared (SWIR) emission wavelengths of numerous individual nanoparticles without using a dedicated spectrometer. Microscope objectives designed for use at visible wavelengths often show severe axial chromatic aberration in the SWIR. This makes coplanar objects emitting at different SWIR wavelengths appear to focus at different depths. After this aberration has been calibrated for a particular objective lens, the depth at which an emissive nanoparticle appears brightest and best focused can be used to deduce its peak emission wavelength. The method is demonstrated using a dilute, structurally polydisperse sample of single-walled carbon nanotubes deposited onto a microscope slide. Discrete emission centers in this sample have different peak wavelengths corresponding to specific nanotube structural species. A set of images was recorded at stepped focus settings and analyzed to find the sharpest focus depth of each nanotube. The chromatic aberration calibration curve converted these depths into peak emission wavelengths with a spectral resolution better than 3 nm, allowing identification of each nanotube's structure. Chromatic aberration spectroscopy is a practical tool for using existing microscopic equipment to extract significant spectral information on coplanar nanoparticle samples that emit or scatter light.

  2. Breaking the spherical and chromatic aberration barrier in transmission electron microscopy.

    Science.gov (United States)

    Freitag, B; Kujawa, S; Mul, P M; Ringnalda, J; Tiemeijer, P C

    2005-02-01

    Since the invention of transmission electron microscopy (TEM) in 1932 (Z. Physik 78 (1932) 318) engineering improvements have advanced system resolutions to levels that are now limited only by the two fundamental aberrations of electron lenses; spherical and chromatic aberration (Z. Phys. 101 (1936) 593). Since both aberrations scale with the dimensions of the lens, research resolution requirements are pushing the designs to lenses with only a few mm space in the pole-piece gap for the specimen. This is in conflict with the demand for more and more space at the specimen, necessary in order to enable novel techniques in TEM, such as He-cooled cryo electron microscopy, 3D-reconstruction through tomography (Science 302 (2003) 1396) TEM in gaseous environments, or in situ experiments (Nature 427 (2004) 426). All these techniques will only be able to achieve Angstrom resolution when the aberration barriers have been overcome. The spherical aberration barrier has recently been broken by introducing spherical aberration correctors (Nature 392 (1998) 392, 418 (2002) 617), but the correction of the remaining chromatic aberrations have proved to be too difficult for the present state of technology (Optik 57 (1980) 73). Here we present an alternative and successful method to eliminate the chromatic blur, which consists of monochromating the TEM beam (Inst. Phys. Conf. Ser. 161 (1999) 191). We show directly interpretable resolutions well below 1A for the first time, which is significantly better than any TEM operating at 200 KV has reached before.

  3. Accommodation with and without short-wavelength-sensitive cones and chromatic aberration.

    Science.gov (United States)

    Kruger, Philip B; Rucker, Frances J; Hu, Caitlin; Rutman, Hadassa; Schmidt, Nathan W; Roditis, Vasilios

    2005-05-01

    Accommodation was monitored while observers (23) viewed a square-wave grating (2.2 cycles/deg; 0.53 contrast) in a Badal optometer. The grating moved sinusoidally (0.2 Hz) to provide a stimulus between -1.00 D and -3.00 D during trials lasting 40.96 s. There were three illumination conditions: 1. Monochromatic 550 nm light to stimulate long-wavelength-sensitive cones (L-cones) and medium-wavelength-sensitive cones (M-cones) without chromatic aberration; 2. Monochromatic 550 nm light+420 nm light to stimulate long-, medium- and short-wavelength-sensitive cones (S-cones) with longitudinal chromatic aberration (LCA); 3. Monochromatic 550 nm light+420 nm light to stimulate L-, M- and S-cones viewed through an achromatizing lens. In the presence of LCA mean dynamic gain decreased (p=0.0003; ANOVA) and mean accommodation level was reduced (p=0.001; ANOVA). The reduction in gain and increased lag of accommodation in the presence of LCA could result from a blue-yellow chromatic signal or from a larger depth-of-focus.

  4. Chromatic Aberration Correction for Atomic Resolution TEM Imaging from 20 to 80 kV.

    Science.gov (United States)

    Linck, Martin; Hartel, Peter; Uhlemann, Stephan; Kahl, Frank; Müller, Heiko; Zach, Joachim; Haider, Max; Niestadt, Marcel; Bischoff, Maarten; Biskupek, Johannes; Lee, Zhongbo; Lehnert, Tibor; Börrnert, Felix; Rose, Harald; Kaiser, Ute

    2016-08-12

    Atomic resolution in transmission electron microscopy of thin and light-atom materials requires a rigorous reduction of the beam energy to reduce knockon damage. However, at the same time, the chromatic aberration deteriorates the resolution of the TEM image dramatically. Within the framework of the SALVE project, we introduce a newly developed C_{c}/C_{s} corrector that is capable of correcting both the chromatic and the spherical aberration in the range of accelerating voltages from 20 to 80 kV. The corrector allows correcting axial aberrations up to fifth order as well as the dominating off-axial aberrations. Over the entire voltage range, optimum phase-contrast imaging conditions for weak signals from light atoms can be adjusted for an optical aperture of at least 55 mrad. The information transfer within this aperture is no longer limited by chromatic aberrations. We demonstrate the performance of the microscope using the examples of 30 kV phase-contrast TEM images of graphene and molybdenum disulfide, showing unprecedented contrast and resolution that matches image calculations.

  5. Luminance and chromatic signals interact differently with melanopsin activation to control the pupil light response.

    Science.gov (United States)

    Barrionuevo, Pablo A; Cao, Dingcai

    2016-09-01

    Intrinsically photosensitive retinal ganglion cells (ipRGCs) express the photopigment melanopsin. These cells receive afferent inputs from rods and cones, which provide inputs to the postreceptoral visual pathways. It is unknown, however, how melanopsin activation is integrated with postreceptoral signals to control the pupillary light reflex. This study reports human flicker pupillary responses measured using stimuli generated with a five-primary photostimulator that selectively modulated melanopsin, rod, S-, M-, and L-cone excitations in isolation, or in combination to produce postreceptoral signals. We first analyzed the light adaptation behavior of melanopsin activation and rod and cones signals. Second, we determined how melanopsin is integrated with postreceptoral signals by testing with cone luminance, chromatic blue-yellow, and chromatic red-green stimuli that were processed by magnocellular (MC), koniocellular (KC), and parvocellular (PC) pathways, respectively. A combined rod and melanopsin response was also measured. The relative phase of the postreceptoral signals was varied with respect to the melanopsin phase. The results showed that light adaptation behavior for all conditions was weaker than typical Weber adaptation. Melanopsin activation combined linearly with luminance, S-cone, and rod inputs, suggesting the locus of integration with MC and KC signals was retinal. The melanopsin contribution to phasic pupil responses was lower than luminance contributions, but much higher than S-cone contributions. Chromatic red-green modulation interacted with melanopsin activation nonlinearly as described by a "winner-takes-all" process, suggesting the integration with PC signals might be mediated by a postretinal site.

  6. The male blue crab, Callinectes sapidus, uses both chromatic and achromatic cues during mate choice.

    Science.gov (United States)

    Baldwin, Jamie; Johnsen, Sönke

    2012-04-01

    In the blue crab, Callinectes sapidus, claw color varies by sex, sexual maturity and individual. Males rely in part on color cues to select appropriate mates, and these chromatic cues may be perceived through an opponent interaction between two photoreceptors with maximum wavelength sensitivities at 440 and 508 nm. The range of color discrimination of this dichromatic visual system may be limited, however, and it is unclear whether male blue crabs are capable of discriminating the natural variations in claw color that may be important in mate choice. By testing males' innate color preferences in binary choice tests between photographs of red-clawed females and six variations of orange-clawed females, we examined both the chromatic (opponent interaction) and achromatic (relative luminance) cues used in male mate choice. Males significantly preferred red-clawed females to orange-clawed females, except when the test colors were similar in both opponency and relative luminance. Our results are unusual in that they indicate that male mate choice in the blue crab is not guided solely by achromatic or chromatic mechanisms, suggesting that both color and intensity are used to evaluate female claw color.

  7. Immobilization of chromate in hyperalkaline waste streams by green rusts and zero-valent iron.

    Science.gov (United States)

    Rogers, Christine M; Burke, Ian T; Ahmed, Imad A M; Shaw, Samuel

    2014-01-01

    Zero-valent iron (ZVI) and green rusts can be used as reductants to convert chromium from soluble, highly toxic Cr(VI) to insoluble Cr(III). This study compared the reduction rates of Cr(VI) by ZVI and two carbonate green rust phases in alkaline/hyperalkaline solutions. Batch experiments were carried out with synthetic chromate solutions at pH 7.7-12.3 and a chromite ore processing residue (COPR) leachate (pH approximately 12.2). Green rust removes chromate from high pH solutions (pH 10-12.5) very rapidly (<400 s). Chromate reduction rates for both green rust phases were consistently higher than for ZVI throughout the pH range studied; the surface area normalized rate constants were two orders of magnitude higher in the COPR leachate solution at pH 12.2. The performances of both green rusts were unaffected by changes in pH. In contrast, ZVI exhibited a marked decline in reduction rate with increasing pH to become almost ineffective above pH12.

  8. Integration of polarization and chromatic cues in the insect sky compass.

    Science.gov (United States)

    el Jundi, Basil; Pfeiffer, Keram; Heinze, Stanley; Homberg, Uwe

    2014-06-01

    Animals relying on a celestial compass for spatial orientation may use the position of the sun, the chromatic or intensity gradient of the sky, the polarization pattern of the sky, or a combination of these cues as compass signals. Behavioral experiments in bees and ants, indeed, showed that direct sunlight and sky polarization play a role in sky compass orientation, but the relative importance of these cues are species-specific. Intracellular recordings from polarization-sensitive interneurons in the desert locust and monarch butterfly suggest that inputs from different eye regions, including polarized-light input through the dorsal rim area of the eye and chromatic/intensity gradient input from the main eye, are combined at the level of the medulla to create a robust compass signal. Conflicting input from the polarization and chromatic/intensity channel, resulting from eccentric receptive fields, is eliminated at the level of the anterior optic tubercle and central complex through internal compensation for changing solar elevations, which requires input from a circadian clock. Across several species, the central complex likely serves as an internal sky compass, combining E-vector information with other celestial cues. Descending neurons, likewise, respond both to zenithal polarization and to unpolarized cues in an azimuth-dependent way.

  9. Psychophysical model of chromatic perceptual transparency based on substractive color mixture.

    Science.gov (United States)

    Faul, Franz; Ekroll, Vebjørn

    2002-06-01

    Variants of Metelli's episcotister model, which are based on additive color mixture, have been found to describe the luminance conditions for perceptual transparency very accurately. However, the findings in the chromatic domain are not that clear-cut, since there exist chromatic stimuli that conform to the additive model but do not appear transparent. We present evidence that such failures are of a systematic nature, and we propose an alternative psychophysical model based on subtractive color mixture. Results of a computer simulation revealed that this model approximately describes color changes that occur when a surface is covered by a filter. We present the results of two psychophysical experiments with chromatic stimuli, in which we directly compared the predictions of the additive model and the predictions of the new model. These results show that the color relations leading to the perception of a homogeneous transparent layer conform very closely to the predictions of the new model and deviate systematically from the predictions of the additive model.

  10. Characterisation of Vranec, Cabernet sauvignon and Merlot wines based on their chromatic and anthocyanin profiles

    Directory of Open Access Journals (Sweden)

    Dimitrovska Maja

    2013-01-01

    Full Text Available Wines of three different grape varieties, Vranec, Cabernet Sauvignon and Merlot were examined for their characterisation in terms of anthocyanin and chromatic profiles, total polyphenols and antioxidant potential. Total, monomeric, polymeric and copigmented anthocyanins were determined by spectrophotometry and the individual anthocyanin compounds were quantified using HPLC-DAD. Chromatic profile was evaluated according to colour density, hue, % red, % blue, % yellow and brilliance (% dA. The established data were submitted to analysis of variance and principle component analysis in order to evaluate their potential for differentiation of wines according to variety and vintage. Vranec wines have shown distinctive characteristics, with the highest content of anthocyanins and values of colour intensity, % red and % dA, compared to the other two studied varieties. The content of petunidin-3-glucoside, peonindin-3-glucoside and anthocyanin acetates were established as possible markers for differentiation of Vranec wines from Cabernet Sauvignon and Merlot wines. However, none of the assayed parameters could be used for differentiation of Cabernet Sauvignon from Merlot wines. It was observed that wine age limits successful classification of the wines by variety according to anthocyanins. The chromatic parameters allowed distinguishing of young (aged up to 1 year from old Vranec wines.

  11. Lead chromate detected as a source of atmospheric Pb and Cr (VI) pollution

    Science.gov (United States)

    Lee, Pyeong-Koo; Yu, Soonyoung; Chang, Hye Jung; Cho, Hye Young; Kang, Min-Ju; Chae, Byung-Gon

    2016-10-01

    Spherical black carbon aggregates were frequently observed in dust dry deposition in Daejeon, Korea. They were tens of micrometers in diameter and presented a mixture of black carbon and several mineral phases. Transmission electron microscopy (TEM) observations with energy-dispersive X-ray spectroscopy (EDS) and selected area diffraction pattern (SADP) analyses confirmed that the aggregates were compact and included significant amounts of lead chromate (PbCrO4). The compositions and morphologies of the nanosized lead chromate particles suggest that they probably originated from traffic paint used in roads and were combined as discrete minerals with black carbon. Based on Pb isotope analysis and air-mass backward trajectories, the dust in Daejeon received a considerable input of anthropogenic pollutants from heavily industrialized Chinese cities, which implies that long-range transported aerosols containing PbCrO4 were a possible source of the lead and hexavalent chromium levels in East Asia. Lead chromate should be considered to be a source of global atmospheric Pb and Cr(VI) pollution, especially given its toxicity.

  12. Multi-criteria analysis for optimization of sodium chromate production from chromic waste

    Energy Technology Data Exchange (ETDEWEB)

    Generowicz, Agnieszka [Institute of Water Supply and Environmental Protection, Cracow University of Technology, Warszawska, Cracow (Poland); Kowalski, Zygmunt; Makara, Agnieszka [Institute of Chemistry and Inorganic Technology, Cracow University of Technology, Warszawska, Cracow (Poland); Kulczycka, Joanna [Mineral and Energy Economy Research Institute, Polish Academy of Sciences, Wybickiego, Cracow (Poland)

    2011-07-15

    The proposal of application of multi-criteria analysis and technological quality method for optimization of technological processes on the case study of sodium chromate production variants from waste was presented. The research on the use of chromic waste for the production of sodium chromate made it possible to determine the optimal process parameters. Technological quality method was used to define the value of criterions for multi-criteria analysis while multi-criteria analysis allowed determining the impact of criterions weights for ranking variants of technological process. Both methods in a complex way evaluate the degree of modernization of technologies, describing them qualitatively within the area of environmental, technical, and the economic effects of the proposed technological variants. Based on the proposed evaluating criteria both methods yield comparable results. The most advantageous alternatives provided realization of the sodium chromate production process with the use of in-process recycling of chromic mud, off-site recycling of chromic tannery waste and on-site recycling of waste from the old chromic heaps. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  13. Chromaticity and color saturation of ultraviolet irradiated poly(vinyl alcohol)-anthocyanin coatings

    Science.gov (United States)

    Mat Nor, N. A.; Aziz, N.; Mohd-Adnan, A. F.; Taha, R. M.; Arof, A. K.

    2016-06-01

    The purpose of this paper is to evaluate the chromaticity and color saturation of anthocyanin extraction from fruit pericarps of Ixora siamensis in a poly(vinyl alcohol) (PVA) matrix. The colored PVA matrix was exposed to UV-B irradiation for 93 days at UV intensity of 17.55 lux. Anthocyanin colorant has been extracted using methanol acidified with 0.5% trifluoroacetic acid (TFA). Different concentrations of ferulic acid (FA) (0, 1, 2, 3, 4 and 5 wt.%) have been added to the anthocyanin extractions before mixing with PVA to form a coating system. The PVA-anthocyanin-FA mixtures have been coated on glass slides and kept overnight in the dark for curing before exposure to UV-B irradiation. The FA-free sample undergoes more color degradation compared to samples containing FA. The coating with 2% FA has the most stable color with chromaticity of 41% and color saturation of 0.88 compared to other FA containing coats. The FA-free coat exhibits 29% chromaticity and color saturation of 0.38 at the end of the experiment.

  14. Patterns of chromatic information processing in the lobula of the honeybee, Apis mellifera L.

    Science.gov (United States)

    Yang, En-Cheng; Lin, Hsiao-Chun; Hung, Yu-Shan

    2004-10-01

    The honeybee, Apis mellifera L., is one of the living creatures that has its colour vision proven through behavioural tests. Previous studies of honeybee colour vision has emphasized the relationship between the spectral sensitivities of photoreceptors and colour discrimination behaviour. The current understanding of the neural mechanisms of bee colour vision is, however, rather limited. The present study surveyed the patterns of chromatic information processing of visual neurons in the lobula of the honeybee, using intracellular recording stimulated by three light-emitting diodes, whose emission spectra approximately match the spectral sensitivity peaks of the honeybee. The recorded visual neurons can be divided into two groups: non-colour opponent cells and colour opponent cells. The non-colour opponent cells comprise six types of broad-band neurons and four response types of narrow-band neurons. The former might detect brightness of the environment or function as chromatic input channels, and the latter might supply specific chromatic input. Amongst the colour opponent cells, the principal neural mechanism of colour vision, eight response types were recorded. The receptive fields of these neurons were not centre surround as observed in primates. Some recorded neurons with tonic post-stimulus responses were observed, however, suggesting temporal defined spectral opponency may be part of the colour-coding mechanisms.

  15. Screening membrane interactions of pesticides by cells decorated with chromatic polymer nanopatches.

    Science.gov (United States)

    Mech, Agnieszka; Orynbayeva, Zulfiya; Irgebayev, Kaiyr; Kolusheva, Sofiya; Jelinek, Raz

    2009-01-01

    Elucidating the factors contributing to the cell toxicity of pesticides and other environmentally sensitive small molecules is critical for evaluation of their health impacts and for understanding the biological processes that they affect. Disruption and permeation of the plasma membrane, which constitutes the critical interface between the cell and its environment, are recognized initiators of cytotoxicity. We present a new approach for predicting pesticide cytotoxicity through rapid screening of membrane interactions of pesticides using a recently developed live-cell chromatic sensor. The sensing platform comprises living mammalian cells labeled with polydiacetylene (PDA), a chromatic polymer that undergoes intense fluorescence transformations induced by structural perturbations of the membrane bilayer. Within a short time after the addition of membrane-interacting tested compounds to the labeled cells, the PDA patches emit high fluorescence, which can be monitored by conventional spectroscopy and microscopy apparatuses. The chromatic technology facilitates rapid evaluation of membrane activity of pesticide compounds and is capable of distinguishing between toxic effects associated with membrane interactions vs intracellular mechanisms.

  16. Attentional shifts have little effect on the waveform of the chromatic onset VEP.

    Science.gov (United States)

    Highsmith, Jennifer; Crognale, Michael A

    2010-09-01

    Attention is important for sufficient performance on many visual tasks. This has been shown using achromatic steady-state and pattern-reversal VEPs. Waveform characteristics typically attenuate when attending to distractor stimuli and ignoring VEP stimuli. Chromatic pattern-onset responses have not been tested under conditions of selective attention: as they can be used in clinical settings to test color vision, it is important to know what effects attentional shifts would have on this response. In the present study chromatic pattern-onset VEPs were recorded using spatially divided and spatially contiguous VEP and distractor stimuli. VEP stimuli were 1 cycle.deg(-1) horizontal sine wave patterns (onset mode 100 ms on/400 ms off) used to selectively modulate the L-M and S-(L+M) visual pathways. Distracter stimuli were letters. Subjects attended to either the letters or the gratings and pressed a button when a predetermined stimulus appeared. In Experiment one, VEP and distractor stimuli were superimposed and spatially contiguous. In Experiment two, stimuli were presented to different hemifields. No significant changes in waveform amplitude and latency were found between VEP and distractor attention conditions for either visual pathway. For the chromatic pattern-onset response, modulation of attention does not change responses either with spatially contiguous or spatially separate selective attention manipulations. Consequently, it may not be necessary to monitor attention during recording of this response.

  17. Transient VEP and psychophysical chromatic contrast thresholds in children and adults.

    Science.gov (United States)

    Boon, Mei Ying; Suttle, Catherine M; Dain, Stephen J

    2007-07-01

    It has been found that humans are able to distinguish colours without luminance cues by about 2-4 months of age and that sensitivity to colour difference develops during childhood, reaching a peak around adolescence. This prolonged period of maturation is reflected by improvements in psychophysical threshold measures and by the VEP characteristics of morphology, latency and amplitude. An intra-individual comparison of VEP and psychophysical responses to isoluminant colour stimuli has not been made in children, however, and this was the aim of the present study. VEPs were recorded from 49 subjects, children (age range: 4.8-12.6 years) and adults (age range: 25.7-33.2 years). Psychophysical and VEP thresholds were both measured in 40 of those subjects. Nominally isoluminant chromatic (L-M) sinewave gratings were presented in onset-offset mode and identical stimuli were used for psychophysical and VEP recordings to allow comparison. In agreement with previous reports, morphology of the transient VEP in response to this stimulus differed considerably between children and adults. There was a significant difference between psychophysical and VEP thresholds in children, but not in adults. Our findings support and expand on previous work on maturation of the L-M chromatic pathway and indicate a larger discrepancy between VEP and psychophysical chromatic thresholds in children than in adults.

  18. Chromatic energy filter and characterization of laser-accelerated proton beams for particle therapy

    Science.gov (United States)

    Hofmann, Ingo; Meyer-ter-Vehn, Jürgen; Yan, Xueqing; Al-Omari, Husam

    2012-07-01

    The application of laser accelerated protons or ions for particle therapy has to cope with relatively large energy and angular spreads as well as possibly significant random fluctuations. We suggest a method for combined focusing and energy selection, which is an effective alternative to the commonly considered dispersive energy selection by magnetic dipoles. Our method is based on the chromatic effect of a magnetic solenoid (or any other energy dependent focusing device) in combination with an aperture to select a certain energy width defined by the aperture radius. It is applied to an initial 6D phase space distribution of protons following the simulation output from a Radiation Pressure Acceleration model. Analytical formula for the selection aperture and chromatic emittance are confirmed by simulation results using the TRACEWIN code. The energy selection is supported by properly placed scattering targets to remove the imprint of the chromatic effect on the beam and to enable well-controlled and shot-to-shot reproducible energy and transverse density profiles.

  19. Coupled nonlinear-diffusion color image sharpening based on the chromaticity-brightness model

    Science.gov (United States)

    Saito, Takahiro; Nosaka, Reina; Komatsu, Takashi

    2006-01-01

    Previously we have presented a selective image sharpening method based on the coupled nonlinear diffusion process composed of a nonlinear diffusion term, a fidelity term and an isotropic peaking term, and it can sharpen only blurred edges without increasing the noise visibility. Our previously presented prototypal color-image sharpening methods based on the coupled nonlinear-diffusion process have been formulated on the linear color models, namely, the channel-bychannel model and the 3D vectorial model. Our prototypal methods can sharpen blurred color step edges, but they do not necessarily enhance contrasts of signal variations in complex texture image regions so well as in simple step-edge regions. To remedy the drawback, this paper extends our coupled nonlinear-diffusion color-image sharpening method to the nonlinear non-flat color model, namely, the chromaticity-brightness model, which is known to be closely relating to human color perception. We modify our time-evolution PDE's for the non-flat space of the chromaticity vector and present its digital implementations. Through experimental simulations, we compare our new color-image sharpening method based on the chromaticity-brightness model with our prototypal color-image sharpening methods based on the linear color models.

  20. Field-scale leaching of arsenic, chromium and copper from weathered treated wood

    Energy Technology Data Exchange (ETDEWEB)

    Hasan, A. Rasem, E-mail: hasan@arij.or [Department of Civil, Architectural and Environmental Engineering, University of Miami, 1251 Memorial Dr., Coral Gables, FL 33124 (United States); Hu Ligang [Department of Chemistry and Biochemistry, Florida International University, 11200 SW 8th Street, University Park, Miami, FL 33199 (United States); Solo-Gabriele, Helena M., E-mail: hmsolo@miami.ed [Department of Civil, Architectural and Environmental Engineering, University of Miami, 1251 Memorial Dr., Coral Gables, FL 33124 (United States); Fieber, Lynne [Division of Marine Biology and Fisheries, Rosenstiel School of Marine and Atmospheric Science, University of Miami, 4600 Rickenbacker Causeway, Miami, FL 33149-1098 (United States); Cai Yong [Department of Chemistry and Biochemistry, Florida International University, 11200 SW 8th Street, University Park, Miami, FL 33199 (United States); Southeast Environmental Research Center, Florida International University, 11200 SW 8th Street, University Park, Miami, FL 33199 (United States); Townsend, Timothy G. [Department of Environmental Engineering Sciences, University of Florida, 217 A.P. Black Hall, Gainesville, FL 32611-6450 (United States)

    2010-05-15

    Earlier studies documented the loss of wood preservatives from new wood. The objective of this study was to evaluate losses from weathered treated wood under field conditions by collecting rainfall leachate from 5 different wood types, all with a surface area of 0.21 m{sup 2}. Wood samples included weathered chromate copper arsenate (CCA) treated wood at low (2.7 kg/m{sup 3}), medium (4.8 kg/m{sup 3}) and high (35.4 kg/m{sup 3}) retention levels, new alkaline copper quat (ACQ) treated wood (1.1 kg/m{sup 3} as CuO) and new untreated wood. Arsenic was found to leach at a higher rate (100 mg in 1 year for low retention) than chromium and copper (<40 mg) in all CCA-treated wood samples. Copper leached at the highest rate from the ACQ sample (670 mg). Overall results suggest that metals' leaching is a continuous process driven by rainfall, and that the mechanism of release from the wood matrix changes as wood weathers. - Metals leaching rates on a percent basis increase as treated wood weathers, although the mass released decreases.

  1. Copper and Copper Proteins in Parkinson’s Disease

    OpenAIRE

    Sergio Montes; Susana Rivera-Mancia; Araceli Diaz-Ruiz; Luis Tristan-Lopez; Camilo Rios

    2014-01-01

    Copper is a transition metal that has been linked to pathological and beneficial effects in neurodegenerative diseases. In Parkinson's disease, free copper is related to increased oxidative stress, alpha-synuclein oligomerization, and Lewy body formation. Decreased copper along with increased iron has been found in substantia nigra and caudate nucleus of Parkinson's disease patients. Copper influences iron content in the brain through ferroxidase ceruloplasmin activity; therefore decreased pr...

  2. Post-column reaction for simultaneous analysis of chromatic and leuco forms of malachite green and crystal violet by high-performance liquid chromatography with photometric detection

    Science.gov (United States)

    Allen, J.L.; Meinertz, J.R.

    1991-01-01

    The chromatic and leuco forms of malachite green and crystal violet were readily separated and detected by a sensitive and selective high-performance liquid chromatographic procedure. The chromatic and leuco forms of the dyes were separated within 11 min on a C18 column with a mobile phase of 0.05 M sodium acetate and 0.05 M acetic acid in water (19%) and methanol (81%). A reaction chamber, containing 10% PbO2 in Celite 545, was placed between the column and the spectrophotometric detector to oxidize the leuco forms of the dyes to their chromatic forms. Chromatic and leuco malachite green were quantified by their absorbance at 618 nm; and chromatic and leuco Crystal Violet by their absorbance at 588 nm. Detection limits for chromatic and leuco forms of both dyes ranged from 0.12 to 0.28 ng. A linear range of 1 to 100 ng was established for both forms of the dyes.

  3. Jiangxi Copper Plans to Increase its Refined Copper Output

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>According to news published on March 30th, China’s largest copper producer--Jiangxi Copper alleged in its 2010 Financial Report Statement that it plans to improve its output of refined copper by 4.4% in 2011, to increase from 900,000 tonnes last year to 940,000 tons.

  4. [Copper metabolism and genetic disorders].

    Science.gov (United States)

    Shimizu, Norikazu

    2016-07-01

    Copper is one of essential trace elements. Copper deficiency lead to growth and developmental failure and/or neurological dysfunction. However, excess copper is also problems for human life. There are two disorders of inborn error of copper metabolism, Menkes disease and Wilson disease. Menkes disease is an X linked recessive disorder with copper deficiency and Wilson disease is an autosomal recessive disorder with copper accumulation. These both disorders result from the defective functioning of copper transport P-type ATPase, ATP7A of Menkes disease and ATP7B of Wilson disease. In this paper, the author describes about copper metabolism of human, and clinical feature, diagnosis and treatment of Menkes disease and Wilson disease.

  5. Chinese Copper Manufacturers Expand Overseas

    Institute of Scientific and Technical Information of China (English)

    2013-01-01

    <正>In 2012,China’s apparent copper consumption reached 8.84 million tons,accounting for 43%of the global total demand.Spurred by strong demand,China’s copper smelting capacity roars with annual average growth in domestic copper smelting capacity reaching approx-

  6. Fabrication and Characterization of Metallic Copper and Copper Oxide Nanoflowers

    Directory of Open Access Journals (Sweden)

    *H. S. Virk

    2011-12-01

    Full Text Available Copper nanoflowers have been fabricated using two different techniques; electro-deposition of copper in polymer and anodic alumina templates, and cytyltrimethal ammonium bromide (CTAB-assisted hydrothermal method. Scanning Electron Microscope (SEM images record some interesting morphologies of metallic copper nanoflowers. Field Emission Scanning Electron Microscope (FESEM has been used to determine morphology and composition of copper oxide nanoflowers. X-ray diffraction (XRD pattern reveals the monoclinic phase of CuO in the crystallographic structure of copper oxide nanoflowers. There is an element of random artistic design of nature, rather than science, in exotic patterns of nanoflowers fabricated in our laboratory.

  7. Copper and Copper Proteins in Parkinson’s Disease

    Directory of Open Access Journals (Sweden)

    Sergio Montes

    2014-01-01

    Full Text Available Copper is a transition metal that has been linked to pathological and beneficial effects in neurodegenerative diseases. In Parkinson’s disease, free copper is related to increased oxidative stress, alpha-synuclein oligomerization, and Lewy body formation. Decreased copper along with increased iron has been found in substantia nigra and caudate nucleus of Parkinson’s disease patients. Copper influences iron content in the brain through ferroxidase ceruloplasmin activity; therefore decreased protein-bound copper in brain may enhance iron accumulation and the associated oxidative stress. The function of other copper-binding proteins such as Cu/Zn-SOD and metallothioneins is also beneficial to prevent neurodegeneration. Copper may regulate neurotransmission since it is released after neuronal stimulus and the metal is able to modulate the function of NMDA and GABA A receptors. Some of the proteins involved in copper transport are the transporters CTR1, ATP7A, and ATP7B and the chaperone ATOX1. There is limited information about the role of those biomolecules in the pathophysiology of Parkinson’s disease; for instance, it is known that CTR1 is decreased in substantia nigra pars compacta in Parkinson’s disease and that a mutation in ATP7B could be associated with Parkinson’s disease. Regarding copper-related therapies, copper supplementation can represent a plausible alternative, while copper chelation may even aggravate the pathology.

  8. Industrial experiment of copper electrolyte purification by copper arsenite

    Institute of Scientific and Technical Information of China (English)

    ZHENG Ya-jie; XIAO Fa-xin; WANG Yong; LI Chun-hua; XU Wei; JIAN Hong-sheng; MA Yut-ian

    2008-01-01

    Copper electrolyte was purified by copper arsenite that was prepared with As2O3. And electrolysis experiments of purified electrolyte were carried out at 235 and 305 A/m2, respectively. The results show that the yield of copper arsenite is up to 98.64% when the molar ratio of Cu to As is 1.5 in the preparation of copper arsenite. The removal rates of Sb and Bi reach 74.11% and 65.60% respectively after copper arsenite is added in electrolyte. The concentrations of As, Sb and Bi in electrolyte nearly remain constant during electrolysis of 13 d. The appearances of cathode copper obtained at 235 and 305 A/m2 are slippery and even, and the qualification rate is 100% according to the Chinese standard of high-pure cathode copper(GB/T467-97).

  9. Precursors for formation of copper selenide, indium selenide, copper indium diselenide, and/or copper indium gallium diselenide films

    Energy Technology Data Exchange (ETDEWEB)

    Curtis, Calvin J; Miedaner, Alexander; Van Hest, Maikel; Ginley, David S

    2014-11-04

    Liquid-based precursors for formation of Copper Selenide, Indium Selenide, Copper Indium Diselenide, and/or copper Indium Galium Diselenide include copper-organoselenides, particulate copper selenide suspensions, copper selenide ethylene diamine in liquid solvent, nanoparticulate indium selenide suspensions, and indium selenide ethylene diamine coordination compounds in solvent. These liquid-based precursors can be deposited in liquid form onto substrates and treated by rapid thermal processing to form crystalline copper selenide and indium selenide films.

  10. The Effect of Copper

    African Journals Online (AJOL)

    higher (p<0.05) in the broodfish fed CSD0 and CSD1 diets than the other diets. Exposure of Clarias gariepinus fish to copper in water, at concentrations above 1.0mg CuSO4/g elicits adverse ... introduction of a toxicant to an aquatic system ..... Toxicity of four commonly used agrochemicals on. Oreochromis niloticus (L) fry.

  11. Presenilin promotes dietary copper uptake.

    Directory of Open Access Journals (Sweden)

    Adam Southon

    Full Text Available Dietary copper is essential for multicellular organisms. Copper is redox active and required as a cofactor for enzymes such as the antioxidant Superoxide Dismutase 1 (SOD1. Copper dyshomeostasis has been implicated in Alzheimer's disease. Mutations in the presenilin genes encoding PS1 and PS2 are major causes of early-onset familial Alzheimer's disease. PS1 and PS2 are required for efficient copper uptake in mammalian systems. Here we demonstrate a conserved role for presenilin in dietary copper uptake in the fly Drosophila melanogaster. Ubiquitous RNA interference-mediated knockdown of the single Drosophila presenilin (PSN gene is lethal. However, PSN knockdown in the midgut produces viable flies. These flies have reduced copper levels and are more tolerant to excess dietary copper. Expression of a copper-responsive EYFP construct was also lower in the midgut of these larvae, indicative of reduced dietary copper uptake. SOD activity was reduced by midgut PSN knockdown, and these flies were sensitive to the superoxide-inducing chemical paraquat. These data support presenilin being needed for dietary copper uptake in the gut and so impacting on SOD activity and tolerance to oxidative stress. These results are consistent with previous studies of mammalian presenilins, supporting a conserved role for these proteins in mediating copper uptake.

  12. The Further Results of the Chromatic Uniquenes s of Certain Bipartite Graphs K(m,n)-A

    Institute of Scientific and Technical Information of China (English)

    ZOU Hui-wen; ZHU Zhong-hua

    2008-01-01

    With its comprehensive applicatian in network information engineering (e.g.dynamic spectrum allocation tinder different distance comtraints) and in network combination optimization (e.g.safe storage of deleterious materials),the graphs'cloring theory and chromatic uniqueness theory have been the forward position of graph theory research.The later concerns the equlvaleat classification of graphs with their color polynomials and the determination of uniqueness of some equivalent classification under isomorphism. In this paper,by introducing the concept of chromatic nomality and comparing the manber of partitions of two chromatically equivalent graphs,a general numerical condition guareateeing that bipartite graphs K (m,n)-A (A(∈)E (K(m,n)) and |A|≥2) is chromatically unique was obtained and a lot of chromatic uniquoness graphs of bipartite graphs K (m,n)-A were determined.The results obtained in this paper were general.And the results cover and extend the majority of the relevant results obtained within the world.

  13. Reduction of chromate and carotene-synthesizing activity of selenite-resistant mutants of the yeast Xanthophyllomyces dendrorhous (Phaffia rhodozyma

    Directory of Open Access Journals (Sweden)

    Grzàdka M.

    2009-08-01

    Full Text Available Aim. The yeast P. rhodozyma is a perspective microbial producer of carotenoid pigment astaxanthin with a high antioxidant power. The aim of the work was to study the ability of the selenite-resistant strains of this yeast to reduce chrome(VI compounds, as well as to analyze the relations between synthesis of carotenoids, resistance to selenite and chromate-reducing activity of P. rhodozyma. Methods. The yeast cells were grown at standard conditions for this species. The residual chromate content in cultural liquid was determined colorimetrically using diphenylcarbazide. The carotenoid content was determined after extraction of the pigments from the previously permeabilized cells by organic solvents. Results. The selected selenite-resistant mutants of the yeast P. rhodozyma revealed the different combinations of the phenotypes related with tolerance/sensitivity to chromate and selenite, as well as ability to reduce chromate. Conclusions. The obtained results give reasons for suggesting that pathways of detoxification of chromate and selenite by the yeast P. rhodozyma are different, although run through a common reductive type. The isolated mutant strains would be served as the useful models to study relations between homeostasis of Se and Cr oxyanions and biosynthesis of carotenes.

  14. Comparative characteristics of copper, copper chloride, and copper bromide vapor lasers

    Energy Technology Data Exchange (ETDEWEB)

    Kazarian, M.A.; Petrash, G.G.; Trofimov, A.N.

    1980-03-01

    The paper reports the results of a comparative study of copper and copper halide vapor lasers emitting in a repetitively-pulsed regime. Copper chloride and copper bromide vapor lasers are found to have identical lasing characteristics under any excitation conditions. These characteristics are different from those of a copper vapor laser. An average lasing power of 13 W has been obtained for all lasers studied for an efficiency of 1%. It is shown that the choice of a laser will largely depend on the laser design suitability for a specific application.

  15. Chromaticity decay due to superconducting dipoles on the injection plateau of the Large Hadron Collider

    Directory of Open Access Journals (Sweden)

    N. Aquilina

    2012-03-01

    Full Text Available It is well known that in a superconducting accelerator a significant chromaticity drift can be induced by the decay of the sextupolar component of the main dipoles. In this paper we give a brief overview of what was expected for the Large Hadron Collider (LHC on the grounds of magnetic measurements of individual dipoles carried out during the production. According to this analysis, the decay time constants were of the order of 200 s: since the injection in the LHC starts at least 30 minutes after the magnets are at constant current, the dynamic correction of this effect was not considered to be necessary. The first beam measurements of chromaticity showed significant decay even after a few hours. For this reason, a dynamic correction of decay on the injection plateau was implemented based on beam measurements. This means that during the injection plateau the sextupole correctors are powered with a varying current to cancel out the decay of the dipoles. This strategy has been implemented successfully. A similar phenomenon has been observed for the dependence of the decay amplitude on the powering history of the dipoles: according to magnetic measurements, also in this case time constants are of the order of 200 s and therefore no difference is expected between a one hour or a ten hours flattop. On the other hand, the beam measurements show a significant change of decay for these two conditions. For the moment there is no clue of the origin of these discrepancies. We give a complete overview of the two effects, and the modifications that have been done to the field model parameters to be able to obtain a final chromaticity correction within a few units.

  16. Effect of ophthalmic filter thickness on predicted monocular dichromatic luminance and chromaticity discrimination.

    Science.gov (United States)

    Richer, S P; Little, A C; Adams, A J

    1984-11-01

    The majority of ophthalmic filters, whether they be in the form of spectacles or contact lenses, are absorbance type filters. Although color vision researchers routinely provide spectrophotometric transmission profiles of filters, filter thickness is rarely specified. In this paper, colorimetric tools and volume color theory are used to show that the color of a filter as well as its physical properties are altered dramatically by changes in thickness. The effect of changes in X-Chrom filter thickness on predicted monocular dichromatic luminance and chromaticity discrimination is presented.

  17. Theoretical estimates of spherical and chromatic aberration in photoemission electron microscopy.

    Science.gov (United States)

    Fitzgerald, J P S; Word, R C; Könenkamp, R

    2016-01-01

    We present theoretical estimates of the mean coefficients of spherical and chromatic aberration for low energy photoemission electron microscopy (PEEM). Using simple analytic models, we find that the aberration coefficients depend primarily on the difference between the photon energy and the photoemission threshold, as expected. However, the shape of the photoelectron spectral distribution impacts the coefficients by up to 30%. These estimates should allow more precise correction of aberration in PEEM in experimental situations where the aberration coefficients and precise electron energy distribution cannot be readily measured.

  18. Correcting lateral chromatic aberrations in non-monochromatic X-ray microscopy

    Science.gov (United States)

    Falch, Ken Vidar; Detlefs, Carsten; Di Michiel, Marco; Snigireva, Irina; Snigirev, Anatoly; Mathiesen, Ragnvald H.

    2016-08-01

    Lateral chromatic aberration in microscopy based on refractive optics may be reduced significantly by adjustments to the illumination scheme. By taking advantage of a broadened bandwidth illumination, the proposed scheme could open for x-ray microscopy with spatial resolution in the range 150-200 nm at millisecond frame rates. The scheme is readily implemented and is achievable using only standard refractive x-ray lenses, which has the advantage of high efficiency. It also maximizes the transmission and removes the spatial filtering effects associated with absorption in x-ray lenses.

  19. Possibility of decreasing the spherical and chromatic aberrations in plane combined axisymmetric magnetoelectrostatic lenses

    CERN Document Server

    Zhukov, V A; Nesterov, M M

    2001-01-01

    The possibility of decreasing by 6 times the coefficients of both spherical and chromatic aberrations in plane combined axisymmetric lenses in comparison with the purely magnetic lenses is demonstrated. This is provided for by a proper selection of the ratio of the geometric parameters of the electrodes dimensions and pole tags of the combined lens, the electric potentials on its electrodes and the ampere-turns in the excitation coil. Application of the combined lenses may prove to be perspective in the ion and electron projection and microprobe systems

  20. Eye-tracking technology for real-time monitoring of transverse chromatic aberration

    Science.gov (United States)

    Privitera, Claudio M.; Sabesan, Ramkumar; Winter, Simon; Tiruveedhula, Pavan; Roorda, Austin

    2017-01-01

    Objective measurements of transverse chromatic aberration (TCA) between two or more wavelengths with an adaptive optics scanning laser ophthalmoscope (AOSLO) are very accurate, but frequent measurements are impractical in many experimental settings. Here, we demonstrate a pupil-tracker that can accurately measure relative changes in TCA that are caused by small shifts in the pupil relative to the AOSLO imaging beam. Corrections for TCA caused by these shifts improve the measurement of TCA as a function of eccentricity, revealing a strong linear relationship. We propose that pupil tracking be integrated into AOSLO systems where robust and unobtrusive control of TCA is required. PMID:27082330

  1. A Light-Activated Olefin Metathesis Catalyst Equipped with a Chromatic Orthogonal Self-Destruct Function.

    Science.gov (United States)

    Sutar, Revannath L; Levin, Efrat; Butilkov, Danielle; Goldberg, Israel; Reany, Ofer; Lemcoff, N Gabriel

    2016-01-11

    A sulfur-chelated photolatent ruthenium olefin metathesis catalyst has been equipped with supersilyl protecting groups on the N-heterocyclic carbene ligand. The silyl groups function as an irreversible chromatic kill switch, thus decomposing the catalyst when it is irradiated with 254 nm UV light. Therefore, different types of olefin metathesis reactions may be started by irradiation with 350 nm UV light and prevented by irradiation with shorter wavelengths. The possibility to induce and impede catalysis just by using light of different frequencies opens the pathway for stereolithographic applications and novel light-guided chemical sequences.

  2. Joint assignment of frequency and polarization to minimize the chromatic number

    Directory of Open Access Journals (Sweden)

    Bon-Hong Koo

    2017-03-01

    Full Text Available In this letter, we propose graph theory-based heuristics for jointly assigning frequency and antenna polarization in a cluster-based tactical communication environment (e.g., military communications. In addition to considering the frequency assignment problem (which is an NP-hard problem, we also consider the polarization assignment issue. A practical antenna and a 3D ray tracing-based simulator are exploited to measure the interference. We show that the suggested heuristics are nearly optimal in terms of chromatics and their low complexity makes them suitable for practical usage.

  3. Frequency-Domain Chromatic Dispersion Equalization Using Overlap-Add Methods in Coherent Optical System

    CERN Document Server

    Xu, Tianhua; Popov, Sergei; Forzati, Marco; Martensson, Jonas; Mussolin, Marco; Li, Jie; Wang, Ke; Zhang, Yimo; Friberg, Ari T

    2016-01-01

    The frequency domain equalizers (FDEs) employing two types of overlap-add zero-padding (OLA-ZP) methods are applied to compensate the chromatic dispersion in a 112-Gbit/s non-return-to-zero polarization division multiplexed quadrature phase shift keying (NRZ-PDM-QPSK) coherent optical transmission system. Simulation results demonstrate that the OLA-ZP methods can achieve the same acceptable performance as the overlap-save method. The required minimum overlap (or zero-padding) in the FDE is derived, and the optimum fast Fourier transform length to minimize the computational complexity is also analyzed.

  4. Evaluation of Corrosion Behavior of Galvanized Steel Treated with Conventional Conversion Coatings and a Chromate-Free Organic Inhibitor

    Directory of Open Access Journals (Sweden)

    Laura A. Hernandez-Alvarado

    2012-01-01

    Full Text Available Conventional weight loss tests and both DC and AC electrochemical techniques were used to study if an organic inhibitor containing an alkanolamine salt of a polycarboxylic acid can substitute toxic coatings as chromating and certain phosphating procedures in the protection of galvanized steel. The electrolyte used was a 0.5 M aerated NaCl solution. All tests gave concordant results, indicating that the chromate-free organic inhibitor does protect galvanized steel in this environment, even though the provided protection was less than that of the chromate conversion coating. It was observed that, after a moderate initial attack, the corrosion rate diminishes due to the appearance and growth of passivating corrosion products layers, mainly constituted by zinc hydroxychloride (Zn5(OH8CI2⋅H2O and two varieties of zinc hydroxide, among other crystalline compounds.

  5. Treatment tests for ex situ removal of chromate, nitrate, and uranium (VI) from Hanford (100-HR-3) groundwater. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Beck, M.A.; Duncan, J.B.

    1993-11-15

    This report describes batch and anion exchange column laboratory-scale studies investigating ex situ methods to remove chromate (chromium [VI]), nitrate (NO{sub 3}), and uranium (present as uranyl (uranium [VI]) carbonato anionic species) from contaminated Hanford Site groundwaters. The technologies investigated include chemical precipitation or coprecipitation to remove chromate and uranium, and anion exchange to remove chromate, uranium, and nitrate. The technologies investigated were specified in the 100-HR-3 Groundwater Treatability Test Plan (DOE-RL 1993). The goal of these tests was to determine the best method to remove selected contaminants to below the concentration of the project performance goals. The raw data and observations made during these tests can be found in the Westinghouse Hanford Company (WHC) laboratory notebooks (Beck 1992, Herting 1993). The method recommended for future study is anion exchange with Dowex 21K resin.

  6. Dissociation of equilibrium points for color-discrimination and color-appearance mechanisms in incomplete chromatic adaptation.

    Science.gov (United States)

    Sato, Tomoharu; Nagai, Takehiro; Kuriki, Ichiro; Nakauchi, Shigeki

    2016-03-01

    We compared the color-discrimination thresholds and supra-threshold color differences (STCDs) obtained in complete chromatic adaptation (gray) and incomplete chromatic adaptation (red). The color-difference profiles were examined by evaluating the perceptual distances between various color pairs using maximum likelihood difference scaling. In the gray condition, the chromaticities corresponding with the smallest threshold and the largest color difference were almost identical. In contrast, in the red condition, they were dissociated. The peaks of the sensitivity functions derived from the color-discrimination thresholds and STCDs along the L-M axis were systematically different between the adaptation conditions. These results suggest that the color signals involved in color discrimination and STCD tasks are controlled by separate mechanisms with different characteristic properties.

  7. ELECTROPLATED Zn-Ni-SiO2 COMPOSITE COATINGS TREATED WITH A SILANE COUPLING AGENT TO REPLACE CHROMATING

    Institute of Scientific and Technical Information of China (English)

    M. Hino; M. Hiramatsu; K. Murakami; A. Saijo; T. Kanadani

    2005-01-01

    The fixing of a silane coupling agent to Zn-Ni-silica (SiO2) composite coatings was studied for the purpose of developing a coating process as an alternative to chromating. The corrosion resistance of Zn-Ni-silica composite coatings was remarkably improved by the silica nanoparticles in the composite, which were dispersed in the surface of this film. The silane coupling agent formed chemical bonds with the inorganic silica particles during the silane coupling treatment on these composite coatings. The treatment suppressed the formation of white corrosion products to the same extent as chromating, as measured in salt spray tests. It is concluded that treating Zn-Ni-silica composite coatings with silane coupling agents is a viable alternative technique to chromating.

  8. Production of ultrahigh purity copper using waste copper nitrate solution.

    Science.gov (United States)

    Choi, J Y; Kim, D S

    2003-04-25

    The production of ultrahigh purity copper (99.9999%) by electrolysis in the presence of a cementation barrier has been attempted employing a waste nitric copper etching solution as the electrolyte. The amount of copper deposited on the cathode increased almost linearly with electrolysis time and the purity of copper was observed to increase as the electrolyte concentration was increased. At some point, however, as the electrolyte concentration increased, the purity of copper decreased slightly. As the total surface area of cementation barrier increased, the purity of product increased. The electrolyte temperature should be maintained below 35 degrees C in the range of investigated electrolysis conditions to obtain the ultrahigh purity copper. Considering that several industrial waste solutions contain valuable metallic components the result of present study may support a claim that electrowinning is a very desirable process for their treatment and recovery.

  9. Fourier transform Raman spectroscopy of sorbed HDTMA and the mechanism of chromate sorption to surfactant-modified clinoptilolite

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, E.J.; Bowman, R.S. [New Mexico Inst. of Mining and Technology, Socorro, NM (United States); Hunter, D.B. [Univ. of Georgia, Aiken, SC (United States). Savannah River Ecology Lab.

    1998-07-01

    Surfactant-modified zeolite (SMZ) has potential use as a sorbent for toxic compounds from contaminated waters, in subsurface permeable barriers, or in ex-situ water treatment systems. The authors examined sorption of the cationic surfactant hexadecyltrimethylammonium bromide (HDTMA) to clinoptilolite zeolite and the subsequent sorption of the chromate anion to surfactant-modified zeolite (SMZ). They used Fourier transform (FT) Raman spectroscopy and batch sorption methods to elucidate the structure of sorbed HDTMA and to determine the mechanisms of chromate sorption. At high HDTMA loading levels (above the zeolite`s external cation exchange capacity, ECEC), the Raman spectra indicated that sorbed HDTMA was similar in conformation to solution micelles and, thus, may contain anion exchange sites. Sorbed HDTMA showed less structuring of tail groups and a decrease in head group hydration. At lower loadings, the sorbed HDTMA tail groups tended to have more disorder, similar to solution monomers. When HDTMA loading rates were greater than 100% of the ECEC, chromate sorbed onto SMZ with near-equivalent Br{sup {minus}} counterion exchange. A peak in the Raman spectrum at 902 cm{sup {minus}1} indicated the presence of sorbed Cr{sub 2}O{sub 7}{sup 2{minus}}, although no bulk solution oligomerized chromate species should have been present at a solution pH of 7. A 30 cm{sup {minus}1} shift in the {nu}{sub 1} peak for sorbed versus solution chromate may indicate the surface-enhanced Lewis acid-base interactions were responsible for some chromate sorption in addition to the predominant anion-exchange mechanism.

  10. Tongling:Copper Industry Giant Takes Shape

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>Centering on the strategic goal of building "World Copper Capital", Tongling constantly extends its product lines and improves the copper industry chain. Now, the copper industry with a production value of RMB 100 billion has taken shape.As the largest copper wire rod manufacturer in Asia, Tongling Quanwei Copper Technologies Co., Ltd., upon its moving into the local market,

  11. Estimating and controlling chromatic aberration losses for two-junction, two-terminal devices in refractive concentrator systems

    Energy Technology Data Exchange (ETDEWEB)

    Kurtz, S.R. [National Renewable Energy Lab., Golden, CO (United States); O`Neill, M.J. [ENTECH, Inc., Keller, TX (United States)

    1996-05-01

    Although previous studies have measured and calculated chromatic aberration losses and proposed methods for reducing these by modifying the optics, significant work remains to be done toward understanding how to quantity the losses and how various parameters affect this loss. This paper presents an analytical definition and calculation method for chromatic aberration losses. The effects of sheet resistance of the midlayers of the cell, total irradiance, incident spectrum, cell width, and diode quality factor are studied. A method for measuring the midlayer resistance in finished sells is described.

  12. A QM/MM study to investigate selectivity of nanoporous graphene membrane for arsenate and chromate removal from water

    Science.gov (United States)

    Riyaz, Mohd; Goel, Neetu

    2017-10-01

    Density functional calculations have been performed within the QM/MM approach to investigate the permeability and selectivity of N-passivated nanoporous graphene towards chromate and arsenate removal from water. The passage of three target molecules namely water, arsenate and chromate from the four different sized nanoporous sheet has been elucidated in detail by treating the porous area of the sheet within the formalism of DFT, while molecular mechanics has been applied to the remaining sheet. The selectivity of the nanoporous sheet towards the passage of target molecules has been measured in terms of their diffusion energy barrier.

  13. Chromaticity decay due to superconducting dipoles on the injection plateau of the Large Hadron Collider

    CERN Document Server

    Aquilina, N; Sammut, N; Strzeclzyk, M; Todesco, E

    2012-01-01

    It is well known that in a superconducting accelerator a significant chromaticity drift can be induced by the decay of the sextupolar component of the main dipoles. In this paper we give a brief overview of what was expected for the Large Hadron Collider on the grounds of magnetic measurements of individual dipoles carried out during the production. According to this analysis, the decay time constants were of the order of 200 s: since the injection in the LHC starts at least 30 minutes after the magnets are at constant current, the dynamic correction of this effect was not considered to be necessary. The first beam measurements of chromaticity showed significant decay even after few hours. For this reason, a dynamic correction of decay on the injection plateau was implemented based on beam measurements. This means that during the injection plateau the sextupole correctors are powered with a varying current to cancel out the decay of the dipoles. This strategy has been implemented successfully. A similar pheno...

  14. Study of Gravitational Lens Chromaticity from Ground-based Narrow Band Photometry

    CERN Document Server

    Mosquera, Ana M; Mediavilla, Evencio; Kochanek, Christopher S

    2010-01-01

    We present observations of wavelength-dependent flux ratios for 4 gravitational lens systems (SDSS~J1650+4251, HE~0435$-$1223, FBQ 0951+2635, and Q~0142$-$100) obtained with the Nordic Optical telescope (NOT). The use of narrow band photometry, as well as the excellent seeing conditions during the observations, allow us to set good baselines to study their chromatic behavior. For SDSS~J1650+4251 we determine the extinction curve of the dust in the $z_L=0.58$ lens galaxy, and find that the 2175 \\AA \\ feature is absent. In the case of HE~0435$-$1223 we clearly detect chromatic microlensing. This allows us to estimate the wavelength dependent size of the accretion disk. We found an R-band disk size of $r^{R}_s=13\\pm5$ light days for a linear prior on $r^{R}_s$ and of $r^{R}_s=7\\pm6$ light days for a logarithmic prior. For a power law size-wavelength scaling of $r_s\\propto\\lambda^{p}$, we were able to constrain the value of the exponent to $p=1.3\\pm0.3$ for both $r^{R}_s$ priors, which is in agreement with the te...

  15. A Study of Gravitational Lens Chromaticity with the Hubble Space Telescope

    CERN Document Server

    Muñoz, José A; Kochanek, Christopher S; Falco, Emilio; Mosquera, Ana María

    2011-01-01

    We report Hubble Space Telescope observations of 6 gravitational lenses with the Advanced Camera for Surveys. We measured the flux ratios between the lensed images in 6 filters from 8140\\AA\\ to 2200\\AA. In 3 of the systems, HE0512$-$3329, B1600+434, and H1413+117, we were able to construct UV extinction curves partially overlapping the 2175\\AA\\ feature and characterize the properties of the dust relative to the Galaxy and the Magellanic Clouds. In HE1104$-$1804 we detect chromatic microlensing and use it to study the physical properties of the quasar accretion disk. For a Gaussian model of the disk $\\exp(-r^2/2 r_s^2)$, scaling with wavelength as $r_s \\propto \\lambda^p$, we estimate $r_s(\\lambda3363)=4^{+4}_{-2}$ ($7\\pm 4$) light-days and $p=1.1\\pm 0.6$ ($1.0\\pm 0.6$) for a logarithmic (linear) prior on $r_s$. The remaining two systems, FBQ0951+2635 and SBS1520+530, yielded no useful estimates of extinction or chromatic microlensing.

  16. Multifocus optical-resolution photoacoustic microscopy using stimulated Raman scattering and chromatic aberration.

    Science.gov (United States)

    Hajireza, Parsin; Forbrich, Alexander; Zemp, Roger J

    2013-08-01

    In this Letter, multifocus optical-resolution photoacoustic microscopy is demonstrated using wavelength tuning and chromatic aberration for depth scanning. Discrete focal zones at several depth locations were created by refocusing light from a polarization-maintaining single-mode fiber pumped by a nanosecond fiber laser. The fiber and laser parameters were chosen to take advantage of stimulated Raman scattering (SRS) in the fiber to create a multiwavelength output that could then be bandpass filtered. The collimator lens and objective lens are chosen to take advantage of chromatic aberration in which each generated SRS wavelength peak focuses at a slightly different depth. The maximum amplitude of photoacoustic signals is mapped to form C-scan images. Additionally, all wavelength peaks fired simultaneously offers improved depth-of-field structural imaging at the cost of slight degradation of mainlobe-to-sidelobe ratios. Wavelength-tuned depth scanning over more than 440 μm is demonstrated, significantly greater than the ~100 μm depth of field predicted from our focused Gaussian beams. The improved depth of focus could be valuable for structural imaging of microvascular morphology without the need for mechanical scanning in the depth direction.

  17. Chromatic-aberration-corrected diffractive lenses for ultra-broadband focusing

    Science.gov (United States)

    Wang, Peng; Mohammad, Nabil; Menon, Rajesh

    2016-02-01

    We exploit the inherent dispersion in diffractive optics to demonstrate planar chromatic-aberration-corrected lenses. Specifically, we designed, fabricated and characterized cylindrical diffractive lenses that efficiently focus the entire visible band (450 nm to 700 nm) onto a single line. These devices are essentially pixelated, multi-level microstructures. Experiments confirm an average optical efficiency of 25% for a three-wavelength apochromatic lens whose chromatic focus shift is only 1.3 μm and 25 μm in the lateral and axial directions, respectively. Super-achromatic performance over the continuous visible band is also demonstrated with averaged lateral and axial focus shifts of only 1.65 μm and 73.6 μm, respectively. These lenses are easy to fabricate using single-step grayscale lithography and can be inexpensively replicated. Furthermore, these devices are thin (<3 μm), error tolerant, has low aspect ratio (<1:1) and offer polarization-insensitive focusing, all significant advantages compared to alternatives that rely on metasurfaces. Our design methodology offers high design flexibility in numerical aperture and focal length, and is readily extended to 2D.

  18. Chromatic aberration correction and deconvolution for UV sensitive imaging of fluorescent sterols in cytoplasmic lipid droplets.

    Science.gov (United States)

    Wüstner, Daniel; Faergeman, Nils J

    2008-08-01

    Intrinsically fluorescent sterols, like dehydroergosterol (DHE), mimic cholesterol closely and are therefore suitable to determine cholesterol transport by fluorescence microscopy. Disadvantages of DHE are its low quantum yield, rapid bleaching, and the fact that its excitation and emission is in the UV region of the spectrum. Thus, one has to deal with chromatic aberration and low signal-to-noise ratio. We developed a method to correct for chromatic aberration between the UV channel and the red/green channel in multicolor imaging of DHE compared with the lipid droplet marker Nile Red in living macrophage foam cells and in adipocytes. We used deconvolution microscopy and developed image segmentation techniques to assess the DHE content of lipid droplets in both cell types in an automated manner. Pulse-chase studies and colocalization analysis were performed to monitor the redistribution of DHE upon adipocyte differentiation. DHE is targeted to transferrin-positive recycling endosomes in preadipocytes but associates with droplets in mature adipocytes. Only in adipocytes but not in foam cells fluorescent sterol was confined to the droplet-limiting membrane. We developed an approach to visualize and quantify sterol content of lipid droplets in living cells with potential for automated high content screening of cellular sterol transport.

  19. Chromatic aberration correction of the human eye for retinal imaging in the near infrared.

    Science.gov (United States)

    Fernández, Enrique J; Unterhuber, Angelika; Povazay, Boris; Hermann, Boris; Artal, Pablo; Drexler, Woflgang

    2006-06-26

    An achromatizing lens has been designed for the human eye in the near infrared range, from 700 to 900 nm, for retinal imaging purposes. Analysis of the performance of the lens, including tolerance to misalignments, has been mathematically accomplished by using an existing eye model. The calculations have shown a virtually perfect correction of the ocular longitudinal chromatic aberration, while still keeping a high optical quality. Ocular aberrations in five subjects have been measured with and without the achromatizing lens by using a Hartmann-Shack wavefront sensor and a broad bandwidth femtosecond Ti:sapphire laser in the spectral range of interest with a set of interference filters, studying the benefits and limits in the use of the achromatizing lens. Ocular longitudinal chromatic aberration has been experimentally demonstrated to be fully corrected by the proposed lens, with no induction of any other parasitic aberration. The practical implementation of the achromatizing lens for Ophthalmoscopy, specifically for optical coherence tomography where the use of polychromatic light sources in the near infrared portion of the spectrum is mandatory, has been considered. The potential benefits of using this lens in combination with adaptive optics to achieve a full aberration correction of the human eye for retinal imaging have also been discussed.

  20. Eliminating chromatic aberration in Gauss-type lens design using a novel genetic algorithm.

    Science.gov (United States)

    Fang, Yi-Chin; Tsai, Chen-Mu; Macdonald, John; Pai, Yang-Chieh

    2007-05-01

    Two different types of Gauss lens design, which effectively eliminate primary chromatic aberration, are presented using an efficient genetic algorithm (GA). The current GA has to deal with too many targets in optical global optimization so that the performance is not much improved. Generally speaking, achromatic aberrations have a great relationship with variable glass sets for all elements. For optics whose design is roughly convergent, glass sets for optics will play a significant role in axial and lateral color aberration. Therefore better results might be derived from the optimal process of eliminating achromatic aberration, which could be carried out by finding feasible glass sets in advance. As an alternative, we propose a new optimization process by using a GA and involving theories of geometrical optics in order to select the best optical glass combination. Two Gauss-type lens designs are employed in this research. First, a telephoto lens design is sensitive to axial aberration because of its long focal length, and second, a wide-angle Gauss design is complicated by lateral color aberration at the extreme corners because Gauss design is well known not to deal well with wide-angle problems. Without numbers of higher chief rays passing the element, it is difficult to correct lateral color aberration altogether for the Gauss design. The results and conclusions show that the attempts to eliminate primary chromatic aberrations were successful.

  1. Ultrahigh-resolution optical coherence tomography with monochromatic and chromatic aberration correction.

    Science.gov (United States)

    Zawadzki, Robert J; Cense, Barry; Zhang, Yan; Choi, Stacey S; Miller, Donald T; Werner, John S

    2008-05-26

    We have developed an improved adaptive optics - optical coherence tomography (AO-OCT) system and evaluated its performance for in vivo imaging of normal and pathologic retina. The instrument provides unprecedented image quality at the retina with isotropic 3D resolution of 3.5 x 3.5 x 3.5 microm(3). Critical to the instrument's resolution is a customized achromatizing lens that corrects for the eye's longitudinal chromatic aberration and an ultra broadband light source (Delta lambda=112 nm lambda(0)= approximately 836 nm). The eye's transverse chromatic aberrations is modeled and predicted to be sufficiently small for the imaging conditions considered. The achromatizing lens was strategically placed at the light input of the AO-OCT sample arm. This location simplifies use of the achromatizing lens and allows straightforward implementation into existing OCT systems. Lateral resolution was achieved with an AO system that cascades two wavefront correctors, a large stroke bimorph deformable mirror (DM) and a micro-electromechanical system (MEMS) DM with a high number of actuators. This combination yielded diffraction-limited imaging in the eyes examined. An added benefit of the broadband light source is the reduction of speckle size in the axial dimension. Additionally, speckle contrast was reduced by averaging multiple B-scans of the same proximal patch of retina. The combination of improved micron-scale 3D resolution, and reduced speckle size and contrast were found to significantly improve visibility of microscopic structures in the retina.

  2. The reduction of chromate ions by Fe(II layered hydroxides

    Directory of Open Access Journals (Sweden)

    S. Loyaux-Lawniczak

    1999-01-01

    Full Text Available The reduction of chromate ions by Fe(OH2 and the iron (II-iron (III hydroxysulphate green rust, GR(SO42-, was studied to evaluate whether such synthetic layered hydroxides and the corresponding natural green rust mineral could be involved in the natural attenuation of contaminated environments. The resulting Cr (III bearing phases, which would govern the subsequent behaviour of chromium, were clearly characterised. Both compounds proved to be very reactive and oxidised instantaneously while chromate ions were reduced to Cr (III as evidenced by X-ray photoelectron spectroscopy. Mass balance (ICP-AES demonstrated that the Fe/Cr ratio inside the solid end product was equal to the initial Fe/Cr ratio. The solid phases, analysed by X-ray diffraction, Raman and Mossbauer spectroscopies were identified as Cr-substituted poorly crystallised iron (III oxyhydroxides in both cases, more precisely δ-FeOOH when starting with Fe(OH2 and ferrihydrite when starting with GR(SO42-.

  3. Fast imaging with inelastically scattered electrons by off-axis chromatic confocal electron microscopy.

    Science.gov (United States)

    Zheng, Changlin; Zhu, Ye; Lazar, Sorin; Etheridge, Joanne

    2014-04-25

    We introduce off-axis chromatic scanning confocal electron microscopy, a technique for fast mapping of inelastically scattered electrons in a scanning transmission electron microscope without a spectrometer. The off-axis confocal mode enables the inelastically scattered electrons to be chromatically dispersed both parallel and perpendicular to the optic axis. This enables electrons with different energy losses to be separated and detected in the image plane, enabling efficient energy filtering in a confocal mode with an integrating detector. We describe the experimental configuration and demonstrate the method with nanoscale core-loss chemical mapping of silver (M4,5) in an aluminium-silver alloy and atomic scale imaging of the low intensity core-loss La (M4,5@840  eV) signal in LaB6. Scan rates up to 2 orders of magnitude faster than conventional methods were used, enabling a corresponding reduction in radiation dose and increase in the field of view. If coupled with the enhanced depth and lateral resolution of the incoherent confocal configuration, this offers an approach for nanoscale three-dimensional chemical mapping.

  4. Laser weld process monitoring and control using chromatic filtering of thermal radiation from a weld pool

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Cheol Jung; Kim, Min Suk; Baik, Sung Hoon; Chung, Chin Man

    2000-06-01

    The application of high power Nd: YAG lasers for precision welding in industry has been growing quite fast these days in diverse areas such as the automobile, the electronics and the aerospace industries. These diverse applications also require the new developments for the precise control and the reliable process monitoring. Due to the hostile environment in laser welding, a remote monitoring is required. The present development relates in general to weld process monitoring techniques, and more particularly to improved methods and apparatus for real-time monitoring of thermal radiation of a weld pool to monitor a size variation and a focus shift of the weld pool for weld process control, utilizing the chromatic aberration of focusing lens or lenses. The monitoring technique of the size variation and the focus shift of a weld pool is developed by using the chromatic filtering of the thermal radiation from a weld pool. The monitoring of weld pool size variation can also be used to monitor the weld depth in a laser welding. Furthermore, the monitoring of the size variation of a weld pool is independent of the focus shift of a weld pool and the monitoring of the focus shift of a weld pool is independent of the size variation of a weld pool.

  5. Color correction for high dynamic range images using a chromatic adaptation method

    Science.gov (United States)

    Yun, Byoung-Ju; Park, Jinhyung; Kim, Seunghae; Kim, Hyun-Deok; Choi, Ho-Hyoung

    2013-01-01

    In the image capturing process using a camera, poor illumination has an influence on the image quality, especially in regards to the contrast and details in the dark regions. Generally, high dynamic range (HDR) imaging techniques are used to match the quality between the real scene and the displayed image. However, in images using the multi-exposure technique or regular photography, the images are limited by the veiling glare, which is scene-, exposure-, lens-, aperture-, and camera-dependent. This study mainly addressed images using the multi-exposure technique and developed a color correction scheme that uses a chromatic adaptation method. In the tone mapping using a Gaussian pyramid, the adaptation level is obtained based on a linear Gaussian filter. The resulting image is then processed through the developed tone-mapping function. This allows the chromatic adaptation method to address the mismatches between the real world and the displayed image. The experiment results show that the proposed method yields a better color correction performance compared to conventional methods.

  6. Chromatic Mechanical Response in 2-D Layered Transition Metal Dichalcogenide (TMDs) based Nanocomposites

    Science.gov (United States)

    Rahneshin, Vahid; Khosravi, Farhad; Ziolkowska, Dominika A.; Jasinski, Jacek B.; Panchapakesan, Balaji

    2016-10-01

    The ability to convert photons of different wavelengths directly into mechanical motion is of significant interest in many energy conversion and reconfigurable technologies. Here, using few layer 2H-MoS2 nanosheets, layer by layer process of nanocomposite fabrication, and strain engineering, we demonstrate a reversible and chromatic mechanical response in MoS2-nanocomposites between 405 nm to 808 nm with large stress release. The chromatic mechanical response originates from the d orbitals and is related to the strength of the direct exciton resonance A and B of the few layer 2H-MoS2 affecting optical absorption and subsequent mechanical response of the nanocomposite. Applying uniaxial tensile strains to the semiconducting few-layer 2H-MoS2 crystals in the nanocomposite resulted in spatially varying energy levels inside the nanocomposite that enhanced the broadband optical absorption up to 2.3 eV and subsequent mechanical response. The unique photomechanical response in 2H-MoS2 based nanocomposites is a result of the rich d electron physics not available to nanocomposites based on sp bonded graphene and carbon nanotubes, as well as nanocomposite based on metallic nanoparticles. The reversible strain dependent optical absorption suggest applications in broad range of energy conversion technologies that is not achievable using conventional thin film semiconductors.

  7. Chromatic characterization of ion-exchanged glass binary phase plates for mode-division multiplexing.

    Science.gov (United States)

    Prieto-Blanco, Xesús; Montero-Orille, Carlos; Moreno, Vicente; Mateo, Eduardo F; Liñares, Jesús

    2015-04-10

    Mode-division multiplexing (MDM) in few-mode fibers is regarded as a promising candidate to increase optical network capacity. A fundamental element for MDM is a modal transformer to LP modes which can be implemented in a free-space basis by using multiregion phase plates, that is, LP plates. Likewise, several wavelengths have to be used due to wavelength multiplexing purposes, optical amplification tasks, and so on. In this work we show that efficient monolithic binary phase plates for different wavelengths can be fabricated by ion-exchange in glass and used for MDM tasks. We introduce an optical characterization method of the chromatic properties of such phase plates which combines the inverse Wentzel-Kramers-Brillouin (IWKB) together with Mach-Zehnder and Michelson-based interferometric techniques. The interferometric method provides a measurement of the phase step for several wavelengths, which characterizes the chromatic properties of the phase plate. Consequently, it is shown that the IWKB method allows us to design and characterize the phase plates in an easy and fast way.

  8. Ponceau 6R dye decoloration and chromate reduction simultaneously in acid medium

    Directory of Open Access Journals (Sweden)

    Seddique M. Ahmed

    2015-07-01

    Full Text Available The degradation efficiency and kinetic degradation reaction of Ponceau 6R dye using potassium chromate have been investigated under various experimental conditions: different concentrations of H2SO4 and temperatures. The immediate change of the red coloration (λmax = 518 nm to colorless was observed after addition of inorganic oxidizing agent (K2CrO4 into the protonated form of Ponceau 6R dye after 48 h. This observation could be attributed to the highest oxidized form of this dye obtained (the quinoid one, which undergoes a hydrolysis reaction to produce p-hydroquinone (H2Q by a mechanism similar to Schiff-base hydrolysis. The cationic form of this matrix is a crucial feature for the hydrolysis process. A kinetic model for oxidation of Ponceau 6R by the combination of chromate was developed based on experimental results. The observed kinetic reaction coefficient was determined and correlated as a function of UV spectral intensity of Ponceau 6R at 518 nm. The degradation rate follows pseudo-first order kinetics with respect to dye concentration.

  9. Investigating neuromagnetic brain responses against chromatic flickering stimuli by wavelet entropies.

    Directory of Open Access Journals (Sweden)

    Mayank Bhagat

    Full Text Available BACKGROUND: Photosensitive epilepsy is a type of reflexive epilepsy triggered by various visual stimuli including colourful ones. Despite the ubiquitous presence of colorful displays, brain responses against different colour combinations are not properly studied. METHODOLOGY/PRINCIPAL FINDINGS: Here, we studied the photosensitivity of the human brain against three types of chromatic flickering stimuli by recording neuromagnetic brain responses (magnetoencephalogram, MEG from nine adult controls, an unmedicated patient, a medicated patient, and two controls age-matched with patients. Dynamical complexities of MEG signals were investigated by a family of wavelet entropies. Wavelet entropy is a newly proposed measure to characterize large scale brain responses, which quantifies the degree of order/disorder associated with a multi-frequency signal response. In particular, we found that as compared to the unmedicated patient, controls showed significantly larger wavelet entropy values. We also found that Renyi entropy is the most powerful feature for the participant classification. Finally, we also demonstrated the effect of combinational chromatic sensitivity on the underlying order/disorder in MEG signals. CONCLUSIONS/SIGNIFICANCE: Our results suggest that when perturbed by potentially epileptic-triggering stimulus, healthy human brain manages to maintain a non-deterministic, possibly nonlinear state, with high degree of disorder, but an epileptic brain represents a highly ordered state which making it prone to hyper-excitation. Further, certain colour combination was found to be more threatening than other combinations.

  10. A gene island with two possible configurations is involved in chromatic acclimation in marine Synechococcus.

    Science.gov (United States)

    Humily, Florian; Partensky, Frédéric; Six, Christophe; Farrant, Gregory K; Ratin, Morgane; Marie, Dominique; Garczarek, Laurence

    2013-01-01

    Synechococcus, the second most abundant oxygenic phototroph in the marine environment, harbors the largest pigment diversity known within a single genus of cyanobacteria, allowing it to exploit a wide range of light niches. Some strains are capable of Type IV chromatic acclimation (CA4), a process by which cells can match the phycobilin content of their phycobilisomes to the ambient light quality. Here, we performed extensive genomic comparisons to explore the diversity of this process within the marine Synechococcus radiation. A specific gene island was identified in all CA4-performing strains, containing two genes (fciA/b) coding for possible transcriptional regulators and one gene coding for a phycobilin lyase. However, two distinct configurations of this cluster were observed, depending on the lineage. CA4-A islands contain the mpeZ gene, encoding a recently characterized phycoerythrobilin lyase-isomerase, and a third, small, possible regulator called fciC. In CA4-B islands, the lyase gene encodes an uncharacterized relative of MpeZ, called MpeW. While mpeZ is expressed more in blue light than green light, this is the reverse for mpeW, although only small phenotypic differences were found among chromatic acclimaters possessing either CA4 island type. This study provides novel insights into understanding both diversity and evolution of the CA4 process.

  11. A gene island with two possible configurations is involved in chromatic acclimation in marine Synechococcus.

    Directory of Open Access Journals (Sweden)

    Florian Humily

    Full Text Available Synechococcus, the second most abundant oxygenic phototroph in the marine environment, harbors the largest pigment diversity known within a single genus of cyanobacteria, allowing it to exploit a wide range of light niches. Some strains are capable of Type IV chromatic acclimation (CA4, a process by which cells can match the phycobilin content of their phycobilisomes to the ambient light quality. Here, we performed extensive genomic comparisons to explore the diversity of this process within the marine Synechococcus radiation. A specific gene island was identified in all CA4-performing strains, containing two genes (fciA/b coding for possible transcriptional regulators and one gene coding for a phycobilin lyase. However, two distinct configurations of this cluster were observed, depending on the lineage. CA4-A islands contain the mpeZ gene, encoding a recently characterized phycoerythrobilin lyase-isomerase, and a third, small, possible regulator called fciC. In CA4-B islands, the lyase gene encodes an uncharacterized relative of MpeZ, called MpeW. While mpeZ is expressed more in blue light than green light, this is the reverse for mpeW, although only small phenotypic differences were found among chromatic acclimaters possessing either CA4 island type. This study provides novel insights into understanding both diversity and evolution of the CA4 process.

  12. Effect of Lossy JPEG Compression of an Image with Chromatic Aberrations on Target Measurement Accuracy

    Science.gov (United States)

    Matsuoka, R.

    2014-05-01

    This paper reports an experiment conducted to investigate the effect of lossy JPEG compression of an image with chromatic aberrations on the measurement accuracy of target center by the intensity-weighted centroid method. I utilized six images shooting a white sheet with 30 by 20 black filled circles in the experiment. The images were acquired by a digital camera Canon EOS 20D. The image data were compressed by using two compression parameter sets of a downsampling ratio, a quantization table and a Huffman code table utilized in EOS 20D. The experiment results clearly indicate that lossy JPEG compression of an image with chromatic aberrations would produce a significant effect on measurement accuracy of target center by the intensity-weighted centroid method. The maximum displacements of red, green and blue components caused by lossy JPEG compression were 0.20, 0.09, and 0.20 pixels respectively. The results also suggest that the downsampling of the chrominance components Cb and Cr in lossy JPEG compression would produce displacements between uncompressed image data and compressed image data. In conclusion, since the author consider that it would be unable to correct displacements caused by lossy JPEG compression, the author would recommend that lossy JPEG compression before recording an image in a digital camera should not be executed in case of highly precise image measurement by using color images acquired by a non-metric digital camera.

  13. FORMATION OF CHROMATE CONVERSION COATINGS ON ALUMINUM AND ITS ALLOYS: AN IN SITU XANES STUDY.

    Energy Technology Data Exchange (ETDEWEB)

    SASAKI,K.; ISAACS,H.S.; JAFFCOATE,C.S.; BUCHHAIT,R.; LEGAT,V.; LEE,H.; SRINIVASAMURTHI,V.

    2001-09-02

    We used in situ X-ray adsorption near-edge structure (XANES) to investigate the formation of chromate conversion coatings on pure Al, commercial Al alloys (AA 1100, AA2024, and AA7075), and a series of binary Al-Cu alloys. The method employed a new electrochemical cell that can determine the ratio of hexavalent chromium (Cr(VI)) to total chromium (Cr(total)) speciation in conversion coatings as a function of exposure time to a chromate solution. The spectra showed that the initial Cr(VI)/Cr(total) ratios are greater than later ones for pure Al and AA1100, but not for AA2024 and AA7075. Measurements with Al-Cu alloys demonstrated that the difference observed in AA2024 and AA7075 may not be due to Cu alloying. The proportion of Cr(VI) in the coatings becomes approximately constant after 180 s of exposure for all the specimens examined even though the coatings continue to grow.

  14. Differences in Brain Hemodynamics in Response to Achromatic and Chromatic Cards of the Rorschach

    Science.gov (United States)

    2016-01-01

    Abstract. In order to investigate the effects of color stimuli of the Rorschach inkblot method (RIM), the cerebral activity of 40 participants with no history of neurological or psychiatric illness was scanned while they engaged in the Rorschach task. A scanned image of the ten RIM inkblots was projected onto a screen in the MRI scanner. Cerebral activation in response to five achromatic color cards and five chromatic cards were compared. As a result, a significant increase in brain activity was observed in bilateral visual areas V2 and V3, parietooccipital junctions, pulvinars, right superior temporal gyrus, and left premotor cortex for achromatic color cards (p < .001). For the cards with chromatic color, significant increase in brain activity was observed in left visual area V4 and left orbitofrontal cortex (p < .001). Furthermore, a conjoint analysis revealed various regions were activated in responding to the RIM. The neuropsychological underpinnings of the response process, as described by Acklin and Wu-Holt (1996), were largely confirmed. PMID:28239255

  15. The Forel-Ule Scale Revisited Spectrally: Preparation Protocol, Transmission Measurements and Chromaticity

    Science.gov (United States)

    Novoa, S.; Wernand, M. R.; van der Woerd, H. J.

    2013-08-01

    The Forel-Ule colour comparator scale has been applied globally and intensively by oceanographers and limnologists since the 19th century,providing one of the oldest oceanographic data sets. Present and future Forel-Ule classifications of global oceanic, coastal and continentalwaters can facilitate the interpretation of these long-term ocean colour data series and provide a connection between the present and thepast that will be valuable for climate-related studies. Within the EC-funded project CITLOPS (Citizens' Observatory for Coast and Ocean Optical Monitoring), with its main goal to empower endusers,willing to employ community-based environmental monitoring, our aim is to digitalize the colours of the Forel-Ule scale to establishthe colour of natural waters through smartphone imaging. The objective of this study was to reproduce the Forel-Ule scale following theoriginal recipes, measure the transmission of the solutions and calculate the chromaticity coordinates of the scale as Wernand and Vander Woerd did in 2010, for the future development of a smartphone application. Some difficulties were encountered when producing thescale, so a protocol for its consistent reproduction was developed and is described in this study. Recalculated chromaticity coordinates arepresented and compared to measurements conducted by former scientists. An error analysis of the spectral and colourimetric informationshows negligible experimental errors.

  16. Digital halftoning methods for selectively partitioning error into achromatic and chromatic channels

    Science.gov (United States)

    Mulligan, Jeffrey B.

    1990-01-01

    A method is described for reducing the visibility of artifacts arising in the display of quantized color images on CRT displays. The method is based on the differential spatial sensitivity of the human visual system to chromatic and achromatic modulations. Because the visual system has the highest spatial and temporal acuity for the luminance component of an image, a technique which will reduce luminance artifacts at the expense of introducing high-frequency chromatic errors is sought. A method based on controlling the correlations between the quantization errors in the individual phosphor images is explored. The luminance component is greatest when the phosphor errors are positively correlated, and is minimized when the phosphor errors are negatively correlated. The greatest effect of the correlation is obtained when the intensity quantization step sizes of the individual phosphors have equal luminances. For the ordered dither algorithm, a version of the method can be implemented by simply inverting the matrix of thresholds for one of the color components.

  17. Direct Production of Copper

    Science.gov (United States)

    Victorovich, G. S.; Bell, M. C.; Diaz, C. M.; Bell, J. A. E.

    1987-09-01

    The use of commercially pure oxygen in flash smelting a typical chalcopyrite concentrate or a low grade comminuted matte directly to copper produces a large excess of heat. The heat balance is controlled by adjusting the calorific value of the solid feed. A portion of the sulfide material is roasted to produce a calcine which is blended with unroasted material, and the blend is then autogeneously smelted with oxygen and flux directly to copper. Either iron silicate or iron calcareous slags are produced, both being subject to a slag cleaning treatment. Practically all of the sulfur is contained in a continuous stream of SO2 gas, most of which is strong enough for liquefaction. A particularly attractive feature of these technologies is that no radically new metallurgical equipment needs to be developed. The oxygen smelting can be carried out not only in the Inco type flash furnace but in other suitable smelters such as cyclone furnaces. Another major advantage stems from abolishion of the ever-troublesome converter aisle, which is replaced with continuous roasting of a fraction of the copper sulfide feed.

  18. Geodesic chromaticity diagram based on variances of color matching by 14 normal observers.

    Science.gov (United States)

    Macadam, D L

    1971-01-01

    A nonlinear transformation of the CIE x,y chromaticity coordinates has been derived from the combined color-matching-variance data of 14 normal observers. In the resulting diagram, the series of equiluminous chromaticities entailing the least number of standard deviations of color matching (sigma-units) between any two-terminal, equiluminous chromaticities is the straight line drawn between the points that represent those terminal colors. The total number of sigma-unit differences between those terminal colors is the euclidean distance between those two points. According to Schrödinger's hypothesis, the loci of constant hue are the straight lines (geodesics) radiating from the point that represents hueless colors in this diagram. The horizontal coordinate in the geodesic chromaticity diagram is xi = 3751a(2) - 10a(4) - 520b(2) + 13295b(3) + 32327ab - 25491a(2)b - 41672ab(2) + 10a(3)b - 5227a((1/2)) + 2952(4)a((1/4)), where a = 10x/(2.4x + 34y + 1) and b = 10y/(2.4x + 34y + 1). The vertical coordinate in the geodesic chromaticity diagram is eta = 404b - 185b(2) + 52b(3) + 69a(1 - b(2)) - 3a(2)b + 30ab(2), where a = 10x/(4.2y - x + 1) and b = 10y/(4.2y - x + 1). These formulas were obtained by use of averages of data for two observers whose individual data were published in 1949 and the weighted averages for 12 young observers, which were published in 1957, together with the data for the single observer, PGN, whose data were published in 1942-45. On the basis of extensive studies of these data, the PGN data were assigned 30% weight in the derivation of the new xi,eta diagram. The 1949 data were assigned 44% weight, or 22% per observer, and the 1957 data were assigned 26%, or about 2.2% per observer. The best fit was found by assuming that the over-all mean of the standard deviation of color matching according to the 1949 data was 1.2 times as much as the standard deviation for PGN, and that the weighted-mean standard deviation for the 12 observers was 1.04 times the

  19. Mechanochemical reactions on copper-based compounds

    NARCIS (Netherlands)

    Castricum, H.L.; Bakker, H.; Poels, E.K.

    1999-01-01

    Mechanochemical reactions of copper and copper oxides with oxygen and carbon dioxide are discussed, as well as decomposition and reduction of copper compounds by mechanical milling under high-vacuum conditions.

  20. Oxidation Mechanism of Copper Selenide

    Science.gov (United States)

    Taskinen, Pekka; Patana, Sonja; Kobylin, Petri; Latostenmaa, Petri

    2014-09-01

    The oxidation mechanism of copper selenide was investigated at deselenization temperatures of copper refining anode slimes. The isothermal roasting of synthetic, massive copper selenide in flowing oxygen and oxygen - 20% sulfur dioxide mixtures at 450-550 °C indicate that in both atmospheres the mass of Cu2Se increases as a function of time, due to formation of copper selenite as an intermediate product. Copper selenide oxidises to copper oxides without formation of thick copper selenite scales, and a significant fraction of selenium is vaporized as SeO2(g). The oxidation product scales on Cu2Se are porous which allows transport of atmospheric oxygen to the reaction zone and selenium dioxide vapor to the surrounding gas. Predominance area diagrams of the copper-selenium system, constructed for selenium roasting conditions, indicate that the stable phase of copper in a selenium roaster gas with SO2 is the sulfate CuSO4. The cuprous oxide formed in decomposition of Cu2Se is further sulfated to CuSO4.

  1. Copper and copper-nickel-alloys - An overview

    Energy Technology Data Exchange (ETDEWEB)

    Klassert, Anton; Tikana, Ladji [Deutsches Kupferinstitut e.V. Am Bonneshof 5, 40474 Duesseldorf (Germany)

    2004-07-01

    With the increasing level of industrialization the demand for and the number of copper alloys rose in an uninterrupted way. Today, the copper alloys take an important position amongst metallic materials due to the large variety of their technological properties and applications. Nowadays there exist over 3.000 standardized alloys. Copper takes the third place of all metals with a worldwide consumption of over 15 millions tons per year, following only to steel and aluminum. In a modern industrial society we meet copper in all ranges of the life (electro-technology, building and construction industry, mechanical engineering, automotive, chemistry, offshore, marine engineering, medical applications and others.). Copper is the first metal customized by humanity. Its name is attributed to the island Cyprus, which supplied in the antiquity copper to Greece, Rome and the other Mediterranean countries. The Romans called it 'ore from Cyprus' (aes cyprium), later cuprum. Copper deposited occasionally also dapper and could be processed in the recent stone age simply by hammering. Already in early historical time copper alloys with 20 to 50 percent tin was used for the production of mirrors because of their high reflecting power. Although the elementary nickel is an element discovered only recently from a historical perspective, its application in alloys - without any knowledge of the alloy composition - occurred at least throughout the last 2.000 years. The oldest copper-nickel coin originates from the time around 235 B.C.. Only around 1800 AD nickel was isolated as a metallic element. In particular in the sea and offshore technology copper nickel alloys found a broad field of applications in piping systems and for valves and armatures. The excellent combination of characteristics like corrosion resistance, erosion stability and bio-fouling resistance with excellent mechanical strength are at the basis of this success. An experience of many decades supports the use

  2. Removal of copper from ferrous scrap

    Science.gov (United States)

    Blander, Milton; Sinha, Shome N.

    1990-01-01

    A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

  3. Variations of serum copper values in pregnancy

    OpenAIRE

    Vukelić Jelka; Kapamadžija Aleksandra; Petrović Đorđe; Grujić Zorica; Novakov-Mikić Aleksandra; Kopitović Vesna; Bjelica Artur

    2012-01-01

    Introduction. Copper is essential micronutrient and has an important role in the human body. The serum copper increases during pregnancy and is doubled at full term. Lower levels of serum copper in pregnancy are connected with some pathological conditions. Objective. The aim of this study was to estimate the levels of serum copper in normal and pathological pregnancies, comparing them with values of serum copper in non-pregnant women, to determine if serum copper is lower in some pathol...

  4. Nickel, copper and cobalt coalescence in copper cliff converter slag

    Directory of Open Access Journals (Sweden)

    Wolf A.

    2016-01-01

    Full Text Available The aim of this investigation is to assess the effect of various additives on coalescence of nickel, copper and cobalt from slags generated during nickel extraction. The analyzed fluxes were silica and lime while examined reductants were pig iron, ferrosilicon and copper-silicon compound. Slag was settled at the different holding temperatures for various times in conditions that simulated the industrial environment. The newly formed matte and slag were characterized by their chemical composition and morphology. Silica flux generated higher partition coefficients for nickel and copper than the addition of lime. Additives used as reducing agents had higher valuable metal recovery rates and corresponding partition coefficients than fluxes. Microstructural studies showed that slag formed after adding reductants consisted of primarily fayalite, with some minute traces of magnetite as the secondary phase. Addition of 5 wt% of pig iron, ferrosilicon and copper-silicon alloys favored the formation of a metallized matte which increased Cu, Ni and Co recoveries. Addition of copper-silicon alloys with low silicon content was efficient in copper recovery but coalescence of the other metals was low. Slag treated with the ferrosilicon facilitated the highest cobalt recovery while copper-silicon alloys with silicon content above 10 wt% resulted in high coalescence of nickel and copper, 87 % and 72 % respectively.

  5. Study of Copper Substitute in High Copper Price Market Environment

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>The high price of copper drives up industry cost,also it is difficult for terminal products to raise price to transfer the cost pressure brought by increase in copper price,as a result downstream consumption markets instead try to seek

  6. Fixation Property of Copper Triazole Wood Preservatives

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    According to AWPA E11-2006 standard,copper fixation rates of several copper-based formulations,such as ammoniacal copper,amine copper,and ammoniacal-ethanolamine copper,as well as alkaline copper quaternary(ACQ),were tested and compared in this paper.And the fixation rates of tebuconazole(TEB) and propiconazole(PPZ) in several formulations,such as copper azole,emulsified type and solvent type,were also compared.The determination of copper content in the leachate was analyzed by atomic absorption spectrom...

  7. INTERACTION OF COPPER BASED PRESERVATIVES WITH WOOD

    Directory of Open Access Journals (Sweden)

    Ali Temiz

    2004-11-01

    Full Text Available Copper is highly toxic to fungi and the element is widely used in many preservative formulations over 50 years. The interactions of wood and copper-based preservatives impact both the performance and the environment aspects of treated wood. Copper might be present in treated wood as coppercellulose complex, copper-lignin complex, and crystalline or amorphous inorganic/organic copper compounds. In this review; it was aimed to investigate the interactions of wood and copper-based preservatives, Copper Adsorpsion factors and copper forms in treated wood

  8. Electroleaching of Copper Waste with Recovery of Copper by Electrodialysis

    Directory of Open Access Journals (Sweden)

    Nuñez P.

    2013-04-01

    Full Text Available A new process to leach and recover copper from solid waste using electric fields was designed. The leaching with electro migration is presented as an alternative to traditional leaching. Preliminary data indicate that the copper ion migration is facilitated by using the electrical potential difference; therefore applying a potential difference in the processes of leaching facilitates the removal of copper. This is especially useful when mineral concentrations are very low. Different phenomena associated with transport of copper in solution are studied to generate a model able predict the state of the copper ion concentration in time. A kinetic model for the process was developed and fitted very well the experimental data.

  9. Synthesis of copper/copper oxide nanoparticles by solution plasma

    Science.gov (United States)

    Saito, Genki; Hosokai, Sou; Tsubota, Masakatsu; Akiyama, Tomohiro

    2011-07-01

    This paper describes the synthesis of copper/copper oxide nanoparticles via a solution plasma, in which the effect of the electrolyte and electrolysis time on the morphology of the products was mainly examined. In the experiments, a copper wire as a cathode was immersed in an electrolysis solution of a K2CO3 with the concentration from 0.001 to 0.50 M or a citrate buffer (pH = 4.8), and was melted by the local-concentration of current. The results demonstrated that by using the K2CO3 solution, we obtained CuO nanoflowers with many sharp nanorods, the size of which decreased with decreasing the concentration of the solution. Spherical particles of copper with/without pores formed when the citrate buffer was used. The pores in the copper nanoparticles appeared when the applied voltage changed from 105 V to 130 V, due to the dissolution of Cu2O.

  10. On the Chromaticity of Complete 4-partite Graphs%完全四部图的色性

    Institute of Scientific and Technical Information of China (English)

    李占兰; 赵海兴

    2004-01-01

    Let G be a graph and P(G,λ) the chromatic polynomial of G.Graphs G and H are said to be chromatically equivalent,simply denoted by G~H,if P(G,λ)=P(H,λ).Let [G]={H|H~G}.Graph G is said to be chromatically unique if [G]={G}.We denote by K(n1,n2,n3,n4) complete 4-partite graphs with 2()k+2 and k(>)2,K(n-k,n,n,n) is chromatically unique.%设G是一个图,P(G,λ)是G的色多项式.若P(G,λ)=P(H,λ),则称G和H是色等价的,简单地用G~H表示.令[G]={H|H~G}.若[G]={G},称G是色唯一的.用G=K(n1,n2,n3,n4)表示完全四部图且2()k+2,k(>)2时,K(n-k,n,n,n)是色唯一的.

  11. Chromatic aberration and the roles of double-opponent and color-luminance neurons in color vision

    NARCIS (Netherlands)

    Vladusich, Tony

    How does the visual cortex encode color? I summarize a theory in which cortical double-opponent color neurons perform a role in color constancy and a complementary set of color-luminance neurons function to selectively correct for color fringes induced by chromatic aberration in the eye. The theory

  12. Limitations in distance and frequency due to chromatic dispersion in fibre-optic microwave and millimeter-wave links

    DEFF Research Database (Denmark)

    Gliese, Ulrik Bo; Nielsen, Søren Nørskov

    1996-01-01

    Chromatic dispersion significantly limits the distance and/or frequency in fibre-optic microwave and millimeter-wave links based on direct detection due to a decrease of the carrier to noise ratio. The limitations in links based on coherent remote heterodyne detection, however, are far less...

  13. Quantitative Phase Microscopy of microstructures with extended measurement range and correction of chromatic aberrations by multiwavelength digital holography.

    Science.gov (United States)

    Ferraro, P; Miccio, L; Grilli, S; Paturzo, M; De Nicola, S; Finizio, A; Osellame, R; Laporta, P

    2007-10-29

    Quantitative Phase Microscopy (QPM) by interferometric techniques can require a multiwavelength configuration to remove 2pi ambiguity and improve accuracy. However, severe chromatic aberration can affect the resulting phase-contrast map. By means of classical interference microscope configuration it is quite unpractical to correct such aberration. We propose and demonstrate that by Digital Holography (DH) in a microscope configuration it is possible to clear out the QPM map from the chromatic aberration in a simpler and more effective way with respect to other approaches. The proposed method takes benefit of the unique feature of DH to record in a plane out-of-focus and subsequently reconstruct numerically at the right focal image plane. In fact, the main effect of the chromatic aberration is to shift differently the correct focal image plane at each wavelength and this can be readily compensated by adjusting the corresponding reconstruction distance for each wavelength. A procedure is described in order to determine easily the relative focal shift among different imaging wavelengths by performing a scanning of the numerical reconstruction along the optical axis, to find out the focus and to remove at the same time the chromatic aberration.

  14. A Researchon Ancient Chromaticity Printing in China%中国古代套色印刷考略

    Institute of Scientific and Technical Information of China (English)

    薛慧芳

    2014-01-01

    The ancient chromaticity printing in China was another breakthrough after the invention of block printing and movable type printing. The ancient chromaticity printing began with watercolour block printing, which is one of the major printings that has upgraded chromaticity printing to an unprecedented degree. Engraving in this method is not only colorful and chromatic but also displays intensity of colors. The embossing printing makes the presswork exquisite aesthetic, which is one hundred and fifty years earlier than the thermograph in Germany.%套色印刷是中国古代继雕版印刷、活字印刷之后又一重大技术突破,“饾版”的发明开创了古代套色版画的先河,所印刷的版画不仅色彩绚丽,精美鲜艳,且能表现画面的深浅浓度,把套色技术提高到前所未有的程度。“拱版”技术的创新使印刷品更为美观精致,它比18世纪中叶德国第一次应用凹凸印刷技术要早150多年。

  15. Iridophores and not carotenoids account for chromatic variation of carotenoid-based coloration in common lizards (Lacerta vivipara).

    Science.gov (United States)

    San-Jose, Luis M; Granado-Lorencio, Fernando; Sinervo, Barry; Fitze, Patrick S

    2013-03-01

    Abstract Carotenoids typically need reflective background components to shine. Such components, iridophores, leucophores, and keratin- and collagen-derived structures, are generally assumed to show no or little environmental variability. Here, we investigate the origin of environmentally induced variation in the carotenoid-based ventral coloration of male common lizards (Lacerta vivipara) by investigating the effects of dietary carotenoids and corticosterone on both carotenoid- and background-related reflectance. We observed a general negative chromatic change that was prevented by β-carotene supplementation. However, chromatic changes did not result from changes in carotenoid-related reflectance or skin carotenoid content but from changes in background-related reflectance that may have been mediated by vitamin A1. An in vitro experiment showed that the encountered chromatic changes most likely resulted from changes in iridophore reflectance. Our findings demonstrate that chromatic variation in carotenoid-based ornaments may not exclusively reflect differences in integumentary carotenoid content and, hence, in qualities linked to carotenoid deposition (e.g., foraging ability, immune response, or antioxidant capacity). Moreover, skin carotenoid content and carotenoid-related reflectance were related to male color polymorphism, suggesting that carotenoid-based coloration of male common lizards is a multicomponent signal, with iridophores reflecting environmental conditions and carotenoids reflecting genetically based color morphs.

  16. Chromatic aberration and the roles of double-opponent and color-luminance neurons in color vision

    NARCIS (Netherlands)

    Vladusich, Tony

    2007-01-01

    How does the visual cortex encode color? I summarize a theory in which cortical double-opponent color neurons perform a role in color constancy and a complementary set of color-luminance neurons function to selectively correct for color fringes induced by chromatic aberration in the eye. The theory

  17. Experimental demonstration of adaptive digital monitoring and compensation of chromatic dispersion for coherent DP-QPSK receiver

    DEFF Research Database (Denmark)

    Borkowski, Robert; Zhang, Xu; Zibar, Darko;

    2011-01-01

    We experimentally demonstrate a digital signal processing (DSP)-based optical performance monitoring (OPM) algorithm for inservice monitoring of chromatic dispersion (CD) in coherent transport networks. Dispersion accumulated in 40 Gbit/s QPSK signal after 80 km of fiber transmission is successfu...

  18. Chromatic aberration and the roles of double-opponent and color-luminance neurons in color vision

    NARCIS (Netherlands)

    Vladusich, Tony

    2007-01-01

    How does the visual cortex encode color? I summarize a theory in which cortical double-opponent color neurons perform a role in color constancy and a complementary set of color-luminance neurons function to selectively correct for color fringes induced by chromatic aberration in the eye. The theory

  19. Chromatic contrast sensitivity during optokinetic nystagmus, visually enhanced vestibulo-ocular reflex, and smooth pursuit eye movements.

    Science.gov (United States)

    Schütz, Alexander C; Braun, Doris I; Gegenfurtner, Karl R

    2009-05-01

    Recently we showed that sensitivity for chromatic- and high-spatial frequency luminance stimuli is enhanced during smooth-pursuit eye movements (SPEMs). Here we investigated whether this enhancement is a general property of slow eye movements. Besides SPEM there are two other classes of eye movements that operate in a similar range of eye velocities: the optokinetic nystagmus (OKN) is a reflexive pattern of alternating fast and slow eye movements elicited by wide-field visual motion and the vestibulo-ocular reflex (VOR) stabilizes the gaze during head movements. In a natural environment all three classes of eye movements act synergistically to allow clear central vision during self- and object motion. To test whether the same improvement of chromatic sensitivity occurs during all of these eye movements, we measured human detection performance of chromatic and luminance line stimuli during OKN and contrast sensitivity during VOR and SPEM at comparable velocities. For comparison, performance in the same tasks was tested during fixation. During the slow phase of OKN we found a similar enhancement of chromatic detection rate like that during SPEM, whereas no enhancement was observable during VOR. This result indicates similarities between slow-phase OKN and SPEM, which are distinct from VOR.

  20. Different temporal structure for form versus surface cortical color systems--evidence from chromatic non-linear VEP.

    Directory of Open Access Journals (Sweden)

    David P Crewther

    Full Text Available Physiological studies of color processing have typically measured responses to spatially varying chromatic stimuli such as gratings, while psychophysical studies of color include color naming, color and light, as well as spatial and temporal chromatic sensitivities. This raises the question of whether we have one or several cortical color processing systems. Here we show from non-linear analysis of human visual evoked potentials (VEP the presence of distinct and independent temporal signatures for form and surface color processing. Surface color stimuli produced most power in the second order Wiener kernel, indicative of a slowly recovering neural system, while chromatic form stimulation produced most power in the first order kernel (showing rapid recovery. We find end-spectral saturation-dependent signals, easily separable from achromatic signals for surface color stimuli. However physiological responses to form color stimuli, though varying somewhat with saturation, showed similar waveform components. Lastly, the spectral dependence of surface and form color VEP was different, with the surface color responses almost vanishing with yellow-grey isoluminant stimulation whereas the form color VEP shows robust recordable signals across all hues. Thus, surface and form colored stimuli engage different neural systems within cortex, pointing to the need to establish their relative contributions under the diverse chromatic stimulus conditions used in the literature.

  1. Different temporal structure for form versus surface cortical color systems--evidence from chromatic non-linear VEP.

    Science.gov (United States)

    Crewther, David P; Crewther, Sheila G

    2010-12-20

    Physiological studies of color processing have typically measured responses to spatially varying chromatic stimuli such as gratings, while psychophysical studies of color include color naming, color and light, as well as spatial and temporal chromatic sensitivities. This raises the question of whether we have one or several cortical color processing systems. Here we show from non-linear analysis of human visual evoked potentials (VEP) the presence of distinct and independent temporal signatures for form and surface color processing. Surface color stimuli produced most power in the second order Wiener kernel, indicative of a slowly recovering neural system, while chromatic form stimulation produced most power in the first order kernel (showing rapid recovery). We find end-spectral saturation-dependent signals, easily separable from achromatic signals for surface color stimuli. However physiological responses to form color stimuli, though varying somewhat with saturation, showed similar waveform components. Lastly, the spectral dependence of surface and form color VEP was different, with the surface color responses almost vanishing with yellow-grey isoluminant stimulation whereas the form color VEP shows robust recordable signals across all hues. Thus, surface and form colored stimuli engage different neural systems within cortex, pointing to the need to establish their relative contributions under the diverse chromatic stimulus conditions used in the literature.

  2. Studies of copper transport in mammalian cells using copper radioisotopes

    Energy Technology Data Exchange (ETDEWEB)

    Camakaris, J.; Voskoboinik, I.; Brooks, H.; Greenough, M. [University of Melbourne, Parkville, VIC (Australia). Department of Genetics; Smith, S. [Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW (Australia). Radiopharmaceuticals Division; Mercer, J. [Deakin University, Clayton, VIC (Australia). Centre of Cellular and Molecular Biology

    1998-12-31

    The trace element copper poses a major problem for all organisms. It is essential as a number of vital enzymes require it. Copper deficiency can lead to neurological disorders, osteoporosis and weakening of arteries. However Cu is also highly toxic and homeostatic mechanisms have evolved to maintain Cu at levels which satisfy requirements but do not cause toxicity. Toxicity is mediated by the oxidative capacity of Cu and its ability to generate toxic free radicals. There are several acquired and inherited diseases due to either Cu toxicity or Cu deficiency. The study of these diseases facilitates identification of genes and proteins involved in copper homeostasis, and this in turn will provide rational therapeutic approaches. Using the copper radioisotopes {sup 64}Cu (t1/2 = 12.8 hr) and {sup 67}Cu (t1/2 = 61 hr) we have developed a number of systems for studying copper transport in mammalian cells. These include investigation of copper uptake, copper efflux and ligand blot assays for Cu-binding proteins. Our studies have focused on Menkes disease which is an inherited and usually lethal copper deficiency disorder in humans. We have demonstrated that the Menkes protein is directly involved as a copper efflux pump in mammalian cells. Using cells overexpressing the Menkes protein we have provided the first biochemical evidence that this functions as a Cu translocating (across the membrane) P-type ATPase (Voskoboinik et al., FEBS Letters, in press). These studies were carried out using purified plasma membrane vesicles. We are now carrying out structure- function studies on this protein using targeted mutations and assaying using the radiocopper vesicle assay. Recently we have commenced studies on the role of amyloid precursor protein (APP) in copper transport and relationship of this to Alzheimers disease

  3. Structure and function of ferricyanide in the formation of chromate conversion coatings on aluminum aircraft alloy

    Energy Technology Data Exchange (ETDEWEB)

    Xia, L.; McCreery, R.L.

    1999-10-01

    Raman and infrared spectroscopy were used to determine the structure of Fe(CN){sup {minus}3}{sub 6} and its reaction products in chromate conversion coatings (CCCs) on AA 2024-T3 aluminum aircraft alloy. In addition, Raman spectroscopy was used to monitor CCC growth rates and their dependence on coating bath composition. The IR and Raman spectra of the air-dried CCC corresponded to those of Berlin green, a Fe{sup +3}-CN-FE{sup +3} polymer, and Fe(CN){sub 6}{sup {minus}3} physisorbed on Cr(OH){sub 3}. No other cyano-containing products were observed. When Fe(CN){sub 6}{sup {minus}3} was excluded from the coating bath, CCC formation rate greatly decreased. In addition, it was observed that Fe(CN){sub 6}{sup {minus}3} could rapidly oxidize AA 2024-T3, and Fe(CN){sub 6}{sup {minus}4} rapidly reduced Cr(VI) in bath conditions. These results indicate a redox mediation action for Fe(CN){sub 6}{sup {minus}3/{minus}4}, which greatly increases the reduction of Cr(VI) to Cr(III) by the alloy. This process is normally quite slow, and redox mediation by Fe(CN){sub 6}{sup {minus}3} is critical to CCC formation. IrCl{sub 6}{sup {minus}3}/{sup {minus}2} could substitute for Fe(CN){sub 6}{sup {minus}3/{minus}4} to produce a chromate film with properties very similar to a conventional CCC. The results establish redox mediation as the mechanism of acceleration of CCC formation, but provide no evidence for any additional role of Fe(CN){sub 6}{sup {minus}3/{minus}4} to produce a chromate film with properties very similar to a conventional CCC. The results establish redox mediation as the mechanism of acceleration of CCC formation, but provide no evidence for any additional role of Fe(CN){sub 6}{sup {minus}3/{minus}4} in corrosion protection.

  4. The influence of water repellent products on the chromatic modifications of the ceramic brick

    Directory of Open Access Journals (Sweden)

    Coronado Martin, J. A.

    2011-12-01

    Full Text Available Chromatic variation, colour and luminosity, undergone by the ceramic support protected by the incorporation of a treatment with water repellent products, is analysed. A new methodology is suggested, based on RGB model where quantifiable values from each ceramic sample are obtained through digital measurement of the colour (image histograms, taking as a base the same type of ceramics with no water repellents. Chromatic variation is determined by the type of water repellent and the base material, obtaining the following results: - All the water repellent studied cause variations in the shade and luminosity of the piece. - English red brick (R is the one presenting less variation of luminosity and shade since it’s been treated with water repellents. - The water repellent of siliconates component is the one which causes less chromatic variation in two of the three bricks studied, the dark brown (T and the English red (R one.

    Se analiza la variación cromática, color y luminosidad, que sufre el soporte cerámico protegido por la incorporación de un tratamiento con productos hidrofugantes. Se propone una metodología nueva, basada en el modelo RGB donde se obtienen valores cuantificables de cada muestra cerámica mediante medición digital del color (histogramas de imagen, tomándose como base el mismo tipo de cerámica sin hidrofugar. La variación cromática está determinada por el tipo de hidrofugante y por el material de base, obteniéndose los siguientes resultados: - Todos los hidrofugantes estudiados producen variación en la tonalidad y luminosidad de la pieza. - El ladrillo rojo ingles (R es el que presenta menor variación de luminosidad y tonalidad al ser tratado con hidrofugantes. - El hidrofugante de componente siliconatos es el que menor variación cromática produce en dos de los tres ladrillos estudiados, tostado (T y rojo inglés (R.

  5. Simultaneous speciation analysis of chromate, molybdate, tungstate and vanadate in welding fume alkaline extracts by HPLC-ICP-MS.

    Science.gov (United States)

    Ščančar, Janez; Berlinger, Balázs; Thomassen, Yngvar; Milačič, Radmila

    2015-09-01

    A novel analytical procedure was developed for the simultaneous speciation analysis of chromate, molybdate, tungstate and vanadate by anion-exchange high performance liquid chromatography hyphenated to inductively coupled plasma mass spectrometry (HPLC-ICP-MS). Linear gradient elution from 100% water to 100% 0.7 M NaCl was applied for chromatographic separation of metal species. In standard aqueous solution at neutral pH molybdate, tungstate and vanadate exist in several aqueous species, while chromate is present as a single CrO4(2-) species. Consequently, only chromate can be separated from this solution in a sharp chromatographic peak. For obtaining sharp chromatographic peaks for molybdate, tungstate and vanadate, the pH of aqueous standard solutions was raised to 12. At highly alkaline conditions single CrO4(2-), MoO4(2-) and WO4(2-) are present and were eluted in sharp chromatographic peaks, while VO4(3-) species, which predominates at pH 12 was eluted in slightly broaden peak. In a mixture of aqueous standard solutions (pH 12) chromate, molybdate, tungstate and vanadate were eluted at retention times from 380 to 420 s, 320 to 370 s, 300 to 350 s and 240 to 360 s, respectively. Eluted species were simultaneously detected on-line by ICP-MS recording m/z 52, 95, 182 and 51. The developed procedure was successfully applied to the analysis of leachable concentrations of chromate, molybdate, tungstate and vanadate in alkaline extracts (2% NaOH+3% Na2CO3) of manual metal arc (MMA) welding fumes loaded on filters. Good repeatability and reproducibility of measurement (RSD±3.0%) for the investigated species were obtained in both aqueous standard solutions (pH 12) and in alkaline extracts of welding fumes. Low limits of detection (LODs) were found for chromate (0.02 ng Cr mL(-1)), molybdate (0.1 ng Mo mL(-1)), tungstate (0.1 ng W mL(-1)) and vanadate (0.2 ng V mL(-1)). The accuracy of analytical procedure for the determination of chromate was checked by analysis of

  6. A Plasmodium falciparum copper-binding membrane protein with copper transport motifs

    OpenAIRE

    Choveaux David L; Przyborski Jude M; Goldring JP

    2012-01-01

    Abstract Background Copper is an essential catalytic co-factor for metabolically important cellular enzymes, such as cytochrome-c oxidase. Eukaryotic cells acquire copper through a copper transport protein and distribute intracellular copper using molecular chaperones. The copper chelator, neocuproine, inhibits Plasmodium falciparum ring-to-trophozoite transition in vitro, indicating a copper requirement for malaria parasite development. How the malaria parasite acquires or secretes copper st...

  7. Nanocrystalline copper based microcomposites

    OpenAIRE

    J.P. Stobrawa; Z.M. Rdzawski; W. Głuchowski; J. Domagała-Dubiel

    2012-01-01

    Purpose: The aim of this work was to investigate microstructure, mechanical properties and deformation behavior of copper microcomposites: Cu- Y2O3, Cu- ZrO2 and Cu-WC produced by powder metallurgy techniques.Design/methodology/approach: Tests were made with Cu-Y2O3, Cu-ZrO2 and Cu-WC microcomposites containing up to 2% of a strengthening phase. The materials were fabricated by powder metallurgy techniques, including milling of powders, followed by their compacting and sintering. The main mec...

  8. The Bauschinger Effect in Copper

    DEFF Research Database (Denmark)

    Pedersen, Ole Bøcker; Brown, L .M.; Stobbs, W. M.

    1981-01-01

    A study of the Bauschinger effect in pure copper shows that by comparison with dispersion hardened copper the effect is very small and independent of temperature. This suggests that the obstacles to flow are deformable. A simple composite model based on this principle accounts for the data semi...

  9. Nanostructured copper, chromium, and tin oxide multicomponent materials as catalysts for methanol decomposition: 11C-radiolabeling study.

    Science.gov (United States)

    Tsoncheva, Tanya; Sarkadi-Priboczki, Eva; Dimitrov, Momtchil; Genova, Izabela

    2013-01-01

    Copper and chromium modified tin oxide nanocomposites were obtained via incipient wetness impregnation of high surface area nanosized SnO(2) with the corresponding metal acetylacetonates and their further decomposition in air. Powder X-ray diffraction (XRD), Nitrogen physisorption, UV-Vis, and Temperature-programmed reduction (TPR) with hydrogen were applied for the samples characterization. The catalytic activity of the obtained materials was tested in methanol conversion. A new approach based on the selective coverage of the surface with (11)C-methanol was used for the characterization of the catalytic sites. It was demonstrated that the products distribution could be controlled by the surface coverage with methanol and the role of different active sites was discussed. The modification of SnO(2) with copper oxide increased the activity in methanol decomposition to CO(2)via dioxymethylene intermediates, but the catalyst suffered considerable loss of activity due to the reduction transformations by the reaction medium and formation of an inactive intermetallic alloy. The modification with chromium changed the acid-basic properties of SnO(2) by the formation of Cr(2)O(3) nanoparticles as well as anchored to the support chromate species. The former particles facilitated the formation of dimethyl ether (DME), while the latter species converted methanol predominantly to hydrocarbons. The fraction of chromate species increased in Cu-Cr-Sn oxide multicomponent nanocomposites and promoted the formation of hydrocarbons over DME at low temperatures, while at higher temperatures, the activity of the copper species leading to CO(2) formation was more pronounced.

  10. Cone photoreceptor sensitivities and unique hue chromatic responses: correlation and causation imply the physiological basis of unique hues.

    Directory of Open Access Journals (Sweden)

    Ralph W Pridmore

    Full Text Available This paper relates major functions at the start and end of the color vision process. The process starts with three cone photoreceptors transducing light into electrical responses. Cone sensitivities were once expected to be Red Green Blue color matching functions (to mix colors but microspectrometry proved otherwise: they instead peak in yellowish, greenish, and blueish hues. These physiological functions are an enigma, unmatched with any set of psychophysical (behavioral functions. The end-result of the visual process is color sensation, whose essential percepts are unique (or pure hues red, yellow, green, blue. Unique hues cannot be described by other hues, but can describe all other hues, e.g., that hue is reddish-blue. They are carried by four opponent chromatic response curves but the literature does not specify whether each curve represents a range of hues or only one hue (a unique over its wavelength range. Here the latter is demonstrated, confirming that opponent chromatic responses define, and may be termed, unique hue chromatic responses. These psychophysical functions also are an enigma, unmatched with any physiological functions or basis. Here both enigmas are solved by demonstrating the three cone sensitivity curves and the three spectral chromatic response curves are almost identical sets (Pearson correlation coefficients r from 0.95-1.0 in peak wavelengths, curve shapes, math functions, and curve crossover wavelengths, though previously unrecognized due to presentation of curves in different formats, e.g., log, linear. (Red chromatic response curve is largely nonspectral and thus derives from two cones. Close correlation combined with deterministic causation implies cones are the physiological basis of unique hues. This match of three physiological and three psychophysical functions is unique in color vision.

  11. Effects of copper(II) and copper oxides on THMs formation in copper pipe.

    Science.gov (United States)

    Li, Bo; Qu, Jiuhui; Liu, Huijuan; Hu, Chengzhi

    2007-08-01

    Little is known about how the growth of trihalomethanes (THMs) in drinking water is affected in copper pipe. The formation of THMs and chlorine consumption in copper pipe under stagnant flow conditions were investigated. Experiments for the same water held in glass bottles were performed for comparison. Results showed that although THMs levels firstly increased in the presence of chlorine in copper pipe, faster decay of chlorine as compared to the glass bottle affected the rate of THMs formation. The analysis of water phase was supplemented by surface analysis of corrosion scales using X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDX). The results showed the scales on the pipe surface mainly consisted of Cu(2)O, CuO and Cu(OH)(2) or CuCO(3). Designed experiments confirmed that the fast depletion of chlorine in copper pipe was mainly due to effect of Cu(2)O, CuO in corrosion scales on copper pipe. Although copper(II) and copper oxides showed effect on THMs formation, the rapid consumption of chlorine due to copper oxide made THM levels lower than that in glass bottles after 4h. The transformations of CF, DCBM and CDBM to BF were accelerated in the presence of copper(II), cupric oxide and cuprous oxide. The effect of pH on THMs formation was influenced by effect of pH on corrosion of copper pipe. When pH was below 7, THMs levels in copper pipe was higher as compared to glass bottle, but lower when pH was above 7.

  12. Programmable apodizer to compensate chromatic aberration effects using a liquid crystal spatial light modulator.

    Science.gov (United States)

    Márquez, A; Iemmi, C; Campos, J; Escalera, J; Yzuel, M

    2005-02-07

    Programmable apodizers written on a liquid crystal spatial light modulator (LCSLM) offer the possibility of modifying the point spread function (PSF) of an optical system in monochromatic light with a high degree of flexibility. Extension to polychromatic light has to take into account the liquid crystal response dependence on the wavelength. Proper control of the chromatic properties of the LCSLM in combination with the design of the correct apodizer is necessary for this new range of applications. In this paper we report a successful application of a programmable amplitude apodizer illuminated with polychromatic light. We use an axial apodizing filter to compensate the longitudinal secondary axial color (LSAC) effects of a refractive optical system on the polychromatic PSF. The configuration of the LCSLM has been optimized to obtain a good amplitude transmission in polychromatic light. Agreement between experimental and simulated results shows the feasibility of our proposal.

  13. Chromatic polarization effects of swept waveforms in FDML lasers and fiber spools.

    Science.gov (United States)

    Wieser, Wolfgang; Palte, Gesa; Eigenwillig, Christoph M; Biedermann, Benjamin R; Pfeiffer, Tom; Huber, Robert

    2012-04-23

    We present detailed investigations of chromatic polarization effects, caused by fiber spools used in FDML lasers and buffering spools for rapidly wavelength swept lasers. We introduce a novel wavelength swept FDML laser source, specially tailored for polarization sensitive optical coherence tomography (OCT) which switches between two different linear polarization states separated by 45°, i.e. 90° on the Poincaré sphere. The polarization maintaining laser cavity itself generates a stable linear polarization state and uses an external buffering technique in order to provide alternating polarization states for successive wavelength sweeps. The design of the setup is based on a comprehensive analysis of the polarization output from FDML lasers, using a novel 150 MHz polarization analyzer. We investigate the fiber polarization properties related to swept source OCT for different fiber delay topologies and analyze the polarization state of different FDML laser sources. © 2012 Optical Society of America

  14. Streptococcus agalactiae vaginitis: nonhemolytic variant on the Liofilchem® Chromatic StreptoB.

    Science.gov (United States)

    Savini, Vincenzo; Marrollo, Roberta; D'Antonio, Marianna; D'Amario, Claudio; Fazii, Paolo; D'Antonio, Domenico

    2013-01-01

    Streptococcus agalactiae (group B Streptococcus, GBS) vaginal pathogenicity is not uniformly acknowledged throughout the literature; accordingly, in women, genital itching and burning, along with leukorrhea are commonly and almost exclusively referred to bacterial vaginosis, candidiasis and trichomoniasis. Conversely, GBS virulence for vagina was recognized in the past, as the organism has been observed to potentially cause local inflammation and discharge, as well as lactobacilli rarefaction. We depict here a case where a nonhemolytic (γ-hemolytic) GBS strain was found to be the etiologic agent of vaginal infection. Such uncommon S. agalactiae phenotypes are hard to be recognized and may be therefore responsible for misdiagnosing and underestimation of GBS vaginitis prevalence; here, we had the support of the Liofilchem(®) Chromatic StreptoB medium, that successfully detected such an atypical variant.

  15. INFLUENCE OF CHROMATIC DISPERSION, DISPERSION SLOPE, DISPERSION CURVATURE ON MICROWAVE GENERATION USING TWO CASCADE MODULATORS

    Directory of Open Access Journals (Sweden)

    Mandeep Singh

    2013-03-01

    Full Text Available This work presents a theoretical study of harmonic generation of microwave signals after detection of a modulated optical carrier in cascaded two electro-optic modulators. Dispersion is one of the major limiting factors for microwave generation in microwave photonics. In this paper, we analyze influence of chromatic dispersion, dispersion slope, dispersion curvature on microwave generation using two cascaded MZMs and it has been found that output intensity of photodetector reduces when dispersion term up to fifth order are added. We have used the two cascaded Mach-Zehnder Modulators for our proposed model and tried to show the dispersion effect with the help of modulation depth factor of MZM, which have been not discussed earlier.

  16. Engineering chromatic dispersion and effective nonlinearity in a dual-slot waveguide.

    Science.gov (United States)

    Liu, Yan; Yan, Jing; Han, Genquan

    2014-09-20

    In this paper, we propose a new dual slot based on rib-like structure, which exhibits a flat and near-zero dispersion over a 198 nm wide wavelength range. Chromatic dispersion of dual-slot silicon (Si) waveguide is mainly determined by waveguide dispersion due to the manipulating mode effective area rather than by the material dispersion. Moreover, the nonlinear coefficient and effective mode area of the waveguide are also explored in detail. A nonlinear coefficient of 1460/m/W at 1550 nm is achieved, which is 10 times larger than that of the Si rib waveguide. By changing different waveguide variables, both the dispersion and nonlinear coefficient can be tailored, thus enabling the potential for a highly nonlinear waveguide with uniform dispersion over a wide wavelength range, which could benefit the performance of broadband optical signal systems.

  17. Effect of chromatic aberration on atomic-resolved spherical aberration corrected STEM images.

    Science.gov (United States)

    Kuramochi, Koji; Yamazaki, Takashi; Kotaka, Yasutoshi; Ohtsuka, Masahiro; Hashimoto, Iwao; Watanabe, Kazuto

    2009-12-01

    The effect of the chromatic aberration (C(c)) coefficient in a spherical aberration (C(s))- corrected electromagnetic lens on high-resolution high-angle annular dark field (HAADF) scanning transmission electron microscope (STEM) images is explored in detail. A new method for precise determination of the C(c) coefficient is demonstrated, requiring measurement of an atomic-resolution one-frame through-focal HAADF STEM image. This method is robust with respect to instrumental drift, sample thickness, all lens parameters except C(c), and experimental noise. It is also demonstrated that semi-quantitative structural analysis on the nanometer scale can be achieved by comparing experimental C(s)- corrected HAADF STEM images with their corresponding simulated images when the effects of the C(c) coefficient and spatial incoherence are included.

  18. Information transfer in a TEM corrected for spherical and chromatic aberration.

    Science.gov (United States)

    Haider, M; Hartel, P; Müller, H; Uhlemann, S; Zach, J

    2010-08-01

    For the transmission electron aberration-corrected microscope (TEAM) initiative of five U.S. Department of Energy laboratories in the United States, a correction system for the simultaneous compensation of the primary axial aberrations, the spherical aberration Cs, and the chromatic aberration Cc has been developed and successfully installed. The performance of the resulting Cc /Cs-corrected TEAM instrument has been investigated thoroughly. A significant improvement of the linear contrast transfer can be demonstrated. The information about the instrument one obtains using Young's fringe method is compared for uncorrected, Cs-corrected, and Cc /Cs-corrected instruments. The experimental results agree well with simulations. The conclusions might be useful to others in understanding the process of image formation in a Cc /Cs-corrected transmission electron microscope.

  19. Humidity sensing behaviour of polyaniline/magnesium chromate (MgCrO4) composite

    Indian Academy of Sciences (India)

    T Machappa; M V N Ambika Prasad

    2012-02-01

    ‘in situ’ polymerization of polyaniline (PANI) was carried out in the presence of magnesium chromate (MgCrO4) to synthesize PANI/ceramic (MgCrO4) composite. These prepared composites were characterized by XRD, FTIR and SEM, which confirm the presence of MgCrO4 in polyaniline matrix. The temperature dependent conductivity measurement shows the thermally activated exponential behaviour of PANI /MgCrO4 composites. The decrease in electrical resistance was observed when the polymer composites were exposed to the broad range of relative humidity (ranging between 20 and 95% RH). This decrease is due to increase in surface electrical conductivity resulting from moisture absorption and due to capillary condensation of water causing change in conductivity within the sensing materials. PANI / MgCrO4 composites are found to be sensitive to low humidity ranging from 20 to 50% RH.

  20. White Organic Light-Emitting Diodes with fine chromaticity tuning via ultrathin layer position shifting

    CERN Document Server

    Choukri, H; Forget, S; Chenais, S; Castex, M C; Ades, D; Siove, A; Geffroy, B; Choukri, Hakim; Fischer, Alexis; Forget, Sebastien; Chenais, Sebastien; Castex, Marie-Claude; Ades, Dominique; Siove, Alain; Geffroy, Bernard

    2006-01-01

    Non-doped white organic light-emitting diodes using an ultrathin yellow-emitting layer of rubrene (5,6,11,12-tetraphenylnaphtacene) inserted on either side of the interface between a hole-transporting NPB (4,4'-bis[N-(1-naphtyl)-N-phenylamino]biphenyl) layer and a blue-emitting DPVBi (4,4'-bis(2,2'-diphenylvinyl)-1,1'-biphenyl) layer are described. Both the thickness and the position of the rubrene layer allow fine chromaticity tuning from deep-blue to pure-yellow via bright-white with CIE coordinates (x= 0.33, y= 0.32), a external quantum efficiency of 1.9%, and a color rendering index of 70. Such a structure also provides an accurate sensing tool to measure the exciton diffusion length in both DPVBi and NPB (8.7 and 4.9 nm respectively).

  1. Post treatment of silane and cerium salt as chromate replacers on galvanized steel

    Institute of Scientific and Technical Information of China (English)

    KONG Gang; LU Jintang; WU Haijiang

    2009-01-01

    A complex film on hot-dip galvanized steel sheet (HDG) was prepared by immersing the sheet in 0.1wt.% Ce(NO3)3 solution and 5vol.% silane solution in turn. The corrosion protection of the complex film was evaluated by potentiodynamic linear polarization(LPR), electrochemical impendence spectra (EIS) and natural salt spray (NSS) tests and compared with that of single cerium film and silane film. The results showed that, the presence of these films on the zinc coating hindered corrosion reaction by reducing the rate of both anodic and cathodic reaction in the corrosion process, and the corrosion protection of the complex film was much better than that of single cerium film or silane film and closed to that of chromate film, because the polarization resistance Rp and electrochemical impendence were increased markedly. Microstructure and chemical composition of these pretreated films were also investigated by scanning electron microscopy (SEM) and AES.

  2. SPARCO : a semi-parametric approach for image reconstruction of chromatic objects

    CERN Document Server

    Kluska, J; Berger, J -P; Baron, F; Lazareff, B; Bouquin, J -B Le; Monnier, J D; Soulez, F; Thiébaut, E

    2014-01-01

    The emergence of optical interferometers with three and more telescopes allows image reconstruction of astronomical objects at the milliarcsecond scale. However, some objects contain components with very different spectral energy distributions (SED; i.e. different temperatures), which produces strong chromatic effects on the interferograms that have to be managed with care by image reconstruction algorithms. For example, the gray approximation for the image reconstruction process results in a degraded image if the total (u, v)-coverage given by the spectral supersynthesis is used. The relative flux contribution of the central object and an extended structure changes with wavelength for different temperatures. For young stellar objects, the known characteristics of the central object (i.e., stellar SED), or even the fit of the spectral index and the relative flux ratio, can be used to model the central star while reconstructing the image of the extended structure separately. Methods. We present a new method, c...

  3. Supersonic Fe beam source for chromatic aberration-free laser focusing of atoms

    CERN Document Server

    Bosch, R C M; Van der Straten, P; Leeuwen, K A H

    2002-01-01

    A monochromatic Fe beam is generated by heated supersonic expansion of argon seeded with Fe vapor. At a nozzle temperature of 1930 K and 800 torr argon inlet pressure the Fe beam has an axial velocity spread of 8% and intensity of 3 x 10 sup 1 sup 5 s sup - sup 1 sr sup - sup 1 , corresponding to a deposition rate of 10 nm/h at 150 mm from the nozzle. The two-chamber alumina crucibles are chemically stable for liquid Fe. With 400 mm sup 3 Fe we have operated for more than 200 hours without reloading. The power consumption at 1930 K is 750 W. Temperature stability at constant power (without feedback) is better than 30 K. The source is intended for deposition of nano-structures by laser focusing of the Fe beam. The small axial velocity spread virtually eliminates the increase in focal spot size due to chromatic aberration. (authors)

  4. Feed-Forward Corrections for Tune and Chromaticity Injection Decay During 2015 LHC Operation

    CERN Document Server

    Solfaroli Camillocci, Matteo; Lamont, Mike; Schaumann, Michaela; Todesco, Ezio; Wenninger, Jorg

    2016-01-01

    After two years of shutdown, the Large Hadron Collider (LHC) has been operated in 2015 at 6.5 TeV, close to its designed energy. When the current is stable at low field, the harmonic components of the main circuits are subject to a dynamic variation induced by current redistribution on the superconducting cables. The Field Description of the LHC (FiDel) foresaw an increase of the decay at injection of tune (quadrupolar components) and chromaticity (sextupolar components) of about 50% with respect to LHC Run1 due to the higher operational current. This paper discusses the beam-based measurements of the decay during the injection plateau and the implementation and accuracy of the feed-forward corrections as present in 2015. Moreover, the observed tune shift proportional to the circulating beam intensity and it's foreseen feed-forward correction are covered.

  5. A new upper bound on the acyclic chromatic indices of planar graphs

    CERN Document Server

    Wang, Weifan; Wang, Yiqiao

    2012-01-01

    An acyclic edge coloring of a graph $G$ is a proper edge coloring such that no bichromatic cycles are produced. The acyclic chromatic index $a'(G)$ of $G$ is the smallest integer $k$ such that $G$ has an acyclic edge coloring using $k$ colors. It was conjectured that $a'(G)\\le \\Delta+2$ for any simple graph $G$ with maximum degree $\\Delta$. In this paper, we prove that if $G$ is a planar graph, then $a'(G)\\leq\\Delta +7$. This improves a result by Basavaraju et al. [{\\em Acyclic edge-coloring of planar graphs}, SIAM J. Discrete Math., 25 (2011), pp. 463-478], which says that every planar graph $G$ satisfies $a'(G)\\leq\\Delta +12$.

  6. Simultaneous chromatic dispersion, polarization-mode-dispersion and OSNR monitoring at 40Gbit/s.

    Science.gov (United States)

    Baker-Meflah, Lamia; Thomsen, Benn; Mitchell, John; Bayvel, Polina

    2008-09-29

    A novel method for independent and simultaneous monitoring of chromatic dispersion (CD), first-order PMD and OSNR in 40Gbit/s systems is proposed and demonstrated. This is performed using in-band tone monitoring of 5GHz, optically down-converted to a low intermediate-frequency (IF) of 10kHz. The measurement provides a large monitoring range with good accuracies for CD (4742+/-100ps/nm), differential group delay (DGD) (200+/-4ps) and OSNR (23+/-1dB), independently of the bit-rate. In addition, the use of electro-absorption modulators (EAM) for the simultaneous down-conversion of all channels and the use of low-speed detectors makes it cost effective for multi-channel operation.

  7. Chromatic effects in beam wander correction for free-space quantum communications

    CERN Document Server

    Carrasco-Casado, Alberto; Fernandez, Veronica

    2016-01-01

    Beam wander caused by atmospheric turbulence can significantly degrade the performance of horizontal free-space quantum communication links. Classical beam wander correction techniques cannot be applied due to the stronger requirements of transmitting single photons. One strategy to overcome this limitation consists in using a separate wavelength from that of the quantum signal to analyze the beam wander and use this information for its correction. For this strategy to work adequately, both wavelengths should be affected equally by atmospheric turbulence, i.e. no chromatic effects should be originated from beam wander. In this letter, a series of experiments are performed to prove that this is the case for {\\lambda} ~ 850 nm as the quantum signal and {\\lambda} ~ 1550 nm as the tracking signal of a quantum communication system.

  8. Porous silicon optical template for determination of chromatic dispersion of transparent liquid mixture

    Science.gov (United States)

    Cafe, Arven I.; Lopez, Joybelle; Lopez, Lorenzo; Faustino, Maria Angela; Mabilangan, Arvin; Salvador, Arnel; Somintac, Armando

    2017-03-01

    Porous silicon was fabricated through electrochemical etching and is used as an optical template for liquid sensing application. Using reflectance spectroscopy, change in optical properties such as refractive index and reflectivity upon liquid introduction were obtained. Chromatic dispersion of porous silicon upon detection of transparent liquids such as absolute ethanol, methanol, 2-propanol and distilled water were determined for spectral range 450nm to 1100nm. Mixture of the organic transparent liquid and water was also tested. In this study, porosity and liquid's concentration were varied to establish the sensitivity of detection. Expected ideal values were also simulated for comparison and correction factor computation. Results provide calibration basis for water quality assessment, environmental monitoring, and diagnostic application.

  9. White organic light-emitting diodes with fine chromaticity tuning via ultrathin layer position shifting

    Science.gov (United States)

    Choukri, Hakim; Fischer, Alexis; Forget, Sébastien; Chénais, Sébastien; Castex, Marie-Claude; Adès, Dominique; Siove, Alain; Geffroy, Bernard

    2006-10-01

    Nondoped white organic light-emitting diodes using an ultrathin yellow-emitting layer of rubrene (5,6,11,12-tetraphenylnaphtacene) inserted on either side of the interface between a hole-transporting 4,4'-bis[N-(1-naphtyl)-N-phenylamino]biphenyl (α-NPB) layer and a blue-emitting 4,4'-bis(2,2'-diphenylvinyl)-1,1'-biphenyl (DPVBi) layer are described. Both the thickness and the position of the rubrene layer allow fine chromaticity tuning from deep blue to pure yellow via bright white with CIE coordinates (x =0.33, y =0.32), an ηext of 1.9%, and a color rendering index of 70. Such a structure also provides an accurate sensing tool to measure the exciton diffusion length in both DPVBi and NPB (8.7 and 4.9nm, respectively).

  10. Chromaticity of the lattice and beam stability in energy-recovery linacs

    Energy Technology Data Exchange (ETDEWEB)

    Litvinenko, V.N.

    2011-12-23

    Energy recovery linacs (ERLs) are an emerging generation of accelerators promising to revolutionize the fields of high-energy physics and photon sciences. These accelerators combine the advantages of linear accelerators with that of storage rings, and hold the promise of delivering electron beams of unprecedented power and quality. Use of superconducting radio-frequency (SRF) cavities converts ERLs into nearly perfect 'perpetuum mobile' accelerators, wherein the beam is accelerated to a desirable energy, used, and then gives the energy back to the RF field. One potential weakness of these devices is transverse beam break-up instability that could severely limit the available beam current. In this paper, I present a method of suppressing these dangerous effects using a natural phenomenon in the accelerators, viz., the chromaticity of the transverse motion.

  11. Copper: From neurotransmission to neuroproteostasis

    Directory of Open Access Journals (Sweden)

    Carlos M Opazo

    2014-07-01

    Full Text Available Copper is critical for the Central Nervous System (CNS development and function. In particular, different studies have shown the effect of copper at brain synapses, where it inhibits Long Term Potentation (LTP and receptor pharmacology. Paradoxically, according to recent studies copper is required for a normal LTP response. Copper is released at the synaptic cleft, where it blocks glutamate receptors, which explain its blocking effects on excitatory neurotransmission. Our results indicate that copper also enhances neurotransmission through the accumulation of PSD95 protein, which increase the levels of AMPA receptors located at the plasma membrane of the post-synaptic density. Thus, our findings represent a novel mechanism for the action of copper, which may have implications for the neurophysiology and neuropathology of the CNS. These data indicate that synaptic configuration is sensitive to transient changes in transition metal homeostasis. Our results suggest that copper increases GluA1 subunit levels of the AMPA receptor through the anchorage of AMPA receptors to the plasma membrane as a result of PSD-95 accumulation. Here, we will review the role of copper on neurotransmission of CNS neurons. In addition, we will discuss the potential mechanisms by which copper could modulate neuronal proteostasis (neuroproteostasis in the CNS with focus in the Ubiquitin Proteasome System, which is particularly relevant to neurological disorders such Alzheimer’s disease (AD where copper and protein dyshomeostasis may contribute to neurodegeneration. An understanding of these mechanisms may ultimately lead to the development of novel therapeutic approaches to control metal and synaptic alterations observed in AD patients.

  12. Normative values for a tablet computer-based application to assess chromatic contrast sensitivity.

    Science.gov (United States)

    Bodduluri, Lakshmi; Boon, Mei Ying; Ryan, Malcolm; Dain, Stephen J

    2017-04-14

    Tablet computer displays are amenable for the development of vision tests in a portable form. Assessing color vision using an easily accessible and portable test may help in the self-monitoring of vision-related changes in ocular/systemic conditions and assist in the early detection of disease processes. Tablet computer-based games were developed with different levels of gamification as a more portable option to assess chromatic contrast sensitivity. Game 1 was designed as a clinical version with no gaming elements. Game 2 was a gamified version of game 1 (added fun elements: feedback, scores, and sounds) and game 3 was a complete game with vision task nested within. The current study aimed to determine the normative values and evaluate repeatability of the tablet computer-based games in comparison with an established test, the Cambridge Colour Test (CCT) Trivector test. Normally sighted individuals [N = 100, median (range) age 19.0 years (18-56 years)] had their chromatic contrast sensitivity evaluated binocularly using the three games and the CCT. Games 1 and 2 and the CCT showed similar absolute thresholds and tolerance intervals, and game 3 had significantly lower values than games 1, 2, and the CCT, due to visual task differences. With the exception of game 3 for blue-yellow, the CCT and tablet computer-based games showed similar repeatability with comparable 95% limits of agreement. The custom-designed games are portable, rapid, and may find application in routine clinical practice, especially for testing younger populations.

  13. [Influence of background color on chromatic value of four all-ceramic system core materials].

    Science.gov (United States)

    Ma, Yong-gang; Zhang, Nian; Deng, Xu-liang

    2010-06-01

    To investigate the influence of post-core background color on chromatic value of four all-ceramic system core materials at clinically appropriate thicknesses. Disc specimens of 15 mm in diameter and 0.80 mm in thickness (Empress II: Group A), and 0.50 mm in thickness (In-Ceram Zirconia core: Group B; Cercon base color zirconia core: Group C; Cercon base zirconia core: Group D) were fabricated, five in each group. Au-Pt alloy, Ni-Cr alloy and visible light cured dental composite resin (A2 color) background were prepared. Samples were put on different background and their chromatic values were measured with colorimeter (CIE-1976-L(*)a(*)b(*)). Color differences of each specimen on different background material were calculated. The color differences among specimens of Group A on different background material were more than 1.5 (2.83 ± 0.70) which meant it could be noticeable to eyes. Those of zirconia were less than 1.5 [Group B: (0.14 ± 0.08); Group C: (0.90 ± 0.20); Group D: (0.99 ± 0.09)]. The influence of background color on Group A was noticeable to human eyes, and as a result, tooth-colored post should be used for this all-ceramic system. For the other three kinds of zirconia core materia1 system, the color differences among specimens on different background material were unnoticeable. Therefore the three all-ceramic systems have excellent color masking ability and can be used on all color background.

  14. Synthesis and optimization of Fe₂O₃ nanofibers for chromate adsorption from contaminated water sources.

    Science.gov (United States)

    Nalbandian, Michael J; Zhang, Miluo; Sanchez, Joel; Choa, Yong-Ho; Nam, Jin; Cwiertny, David M; Myung, Nosang V

    2016-02-01

    In this work, α-Fe2O3 nanofibers were synthesized via electrospinning and characterized to observe optimal morphological and dimensional properties towards chromate removal. The Fe2O3 nanofiber samples were tested in aqueous solutions containing chromate (CrO4(2-)) to analyze their adsorption capabilities and compare them with commercially-available Fe2O3 nanoparticles. Synthesized Fe2O3 nanofibers were observed with a variety of different average diameters, ranging from 23 to 63 nm, while having a constant average grain size at 34 nm, point zero charge at pH 7.1, and band gap at 2.2 eV. BET analysis showed an increase in specific surface area with decreasing average diameter, from 7.2 to 59.2 m(2)/g, due to the increased surface area-to-volume ratio with decreasing nanofiber size. Based on CrO4(2-) adsorption isotherms at pH 6, adsorption capacity of the Fe2O3 nanofibers increased with decreasing diameter, with the 23 nm sized nanofibers having an adsorption capacity of 90.9 mg/g, outperforming the commercially-available Fe2O3 nanoparticles by nearly 2-fold. Additionally, adsorption kinetics was also analyzed, increasing with decreasing nanofiber diameter. The enhanced performance of the nanofiber is suggested to be caused solely due to the increased surface area, in part by its size and morphology. Electrospun Fe2O3 nanofibers provide a promising solution for effective heavy metal removal through nanotechnology-integrated treatment systems. Copyright © 2015 Elsevier Ltd. All rights reserved.

  15. Spatial Organization of Chromatic Pathways in the Mouse Dorsal Lateral Geniculate Nucleus.

    Science.gov (United States)

    Denman, Daniel J; Siegle, Joshua H; Koch, Christof; Reid, R Clay; Blanche, Timothy J

    2017-02-01

    In both dichromats and trichromats, cone opsin signals are maintained independently in cones and combined at the bipolar and retinal ganglion cell level, creating parallel color opponent pathways to the central visual system. Like other dichromats, the mouse retina expresses a short-wavelength (S) and a medium-wavelength (M) opsin, with the S-opsin shifted to peak sensitivity in the ultraviolet (UV) range. Unlike in primates, nonuniform opsin expression across the retina and coexpression in single cones creates a mostly mixed chromatic signal. Here, we describe the visuotopic and chromatic organization of spiking responses in the dorsal lateral geniculate and of the local field potentials in their recipient zone in primary visual cortex (V1). We used an immersive visual stimulus dome that allowed us to present spatiotemporally modulated UV and green luminance in any region of the visual field of an awake, head-fixed mouse. Consistent with retinal expression of opsins, we observed graded UV-to-green dominated responses from the upper to lower visual fields, with a smaller difference across azimuth. In addition, we identified a subpopulation of cells (environments, color information is useful for guiding behavior. How small terrestrial mammals such as mice use graded expression of cone opsins to extract visual information from their environments is not clear, even as the use of mice for studying visually guided behavior grows. In this study, we examined the color signals that the retina sends to the visual cortex via the lateral geniculate nucleus of the thalamus. We found that green dominated responses in the lower and nasal visual field and ultraviolet dominated responses in the upper visual field. We describe a subset of cells that exhibit color opponent responses. Copyright © 2017 the authors 0270-6474/17/371102-15$15.00/0.

  16. Self-regulating genomic island encoding tandem regulators confers chromatic acclimation to marine Synechococcus.

    Science.gov (United States)

    Sanfilippo, Joseph E; Nguyen, Adam A; Karty, Jonathan A; Shukla, Animesh; Schluchter, Wendy M; Garczarek, Laurence; Partensky, Frédéric; Kehoe, David M

    2016-05-24

    The evolutionary success of marine Synechococcus, the second-most abundant phototrophic group in the marine environment, is partly attributable to this group's ability to use the entire visible spectrum of light for photosynthesis. This group possesses a remarkable diversity of light-harvesting pigments, and most of the group's members are orange and pink because of their use of phycourobilin and phycoerythrobilin chromophores, which are attached to antennae proteins called phycoerythrins. Many strains can alter phycoerythrin chromophore ratios to optimize photon capture in changing blue-green environments using type IV chromatic acclimation (CA4). Although CA4 is common in most marine Synechococcus lineages, the regulation of this process remains unexplored. Here, we show that a widely distributed genomic island encoding tandem master regulators named FciA (for type four chromatic acclimation island) and FciB plays a central role in controlling CA4. FciA and FciB have diametric effects on CA4. Interruption of fciA causes a constitutive green light phenotype, and interruption of fciB causes a constitutive blue light phenotype. These proteins regulate all of the molecular responses occurring during CA4, and the proteins' activity is apparently regulated posttranscriptionally, although their cellular ratio appears to be critical for establishing the set point for the blue-green switch in ecologically relevant light environments. Surprisingly, FciA and FciB coregulate only three genes within the Synechococcus genome, all located within the same genomic island as fciA and fciB These findings, along with the widespread distribution of strains possessing this island, suggest that horizontal transfer of a small, self-regulating DNA region has conferred CA4 capability to marine Synechococcus throughout many oceanic areas.

  17. Production of a microcapsule agent of chromate-reducing Lysinibacillus fusiformis ZC1 and its application in remediation of chromate-spiked soil.

    Science.gov (United States)

    Huang, Jun; Li, Jingxin; Wang, Gejiao

    2016-01-01

    Lysinibacillus fusiformis ZC1 is an efficient Cr(VI)-reducing bacterium that can transform the toxic and soluble chromate [Cr(VI)] form to the less toxic and precipitated chromite form [Cr(III)]. As such, this strain might be applicable for bioremediation of Cr(VI) in soil by reducing its bioavailability. The study objective was to prepare a microcapsule agent of strain ZC1 for bioremediation of Cr(VI)-contaminated soil. Using a single-factor orthogonal array design, the optimal fermentation medium was obtained and consisted of 6 g/L corn flour, 12 g/L soybean flour, 8 g/L NH4Cl and 6 g/L CaCl2. After enlarged fermentation, the cell and spore densities were 5.9 × 10(9) and 1.7 × 10(8) cfu/mL, respectively. The fermentation products were collected and embedded with 1 % gum arabic and 1 % sorbitol as the microcapsule carriers and were subsequently spray-dried. Strain ZC1 exhibited viable cell counts of (3.6 ± 0.44) × 10(10) cfu/g dw after 50-day storage at room temperature. In simulated soil bioremediation experiments, 67 % of Cr(VI) was reduced in 5 days with the inoculation of this microcapsule agent, and the Cr(VI) concentration was below the soil Cr(VI) standard level. The results demonstrated that the microcapsule agent of strain ZC1 is efficient for bioremediation of Cr(VI)-contaminated soil.

  18. Jiangxi Copper Corporation Builds 900,000-Ton Copper Production Capacity

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    <正>The Eastward Refined Copper Expansion Pro- ject of Guixi Smelting Plant under Jiangxi Copper Corporation has output its first lot of Copper cathode,marking the company’s pos- session of a 900,000-ton copper production ca- pacity.Thus the company further strengthens its position as the top 3 of the copper world.

  19. Secondary Copper Industry Entered Rapid Growth Period

    Institute of Scientific and Technical Information of China (English)

    2016-01-01

    In China’s copper output,secondary copper accounts for about 40%,for power cable industry,the usage percentage of secondary copper is about 50%.Under the favorable policy of the government to vigorously support recycling industry,secondary copper rod enterprises begin to expand,and are confident toward the industry’s potentials.

  20. Unravelling the Chemical Nature of Copper Cuprizone

    OpenAIRE

    Messori, L.; Casini, A.; C.Gabbiani; Sorace, L.; Muniz-Miranda, M.; Zatta, P

    2007-01-01

    During the last 50 years, formation of the highly chromogenic copper cuprizone complex has been exploited for spectrophotometric determinations of copper although the precise chemical nature of the resulting species has never been ascertained; we eventually show here, in contrast to current opinion, that copper cuprizone is a copper(III) complex.