WorldWideScience

Sample records for chobiryo kagaku busshitsu

  1. Fiscal 1997 report on the results of the international standardization R and D. Measurement of ultra-micro chemical substances and measuring methods of hormone effects; 1997 nendo seika hokokusho kokusai hyojun soseigata kenkyu kaihatsu. Chobiryo kagaku busshitsu no keisoku horumon eikyo sayo sokuteiho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Concerning the measurement system of ultra-micro hazardous chemical substances in the global environment, the paper examined the present situation of chemical substances such as dioxins, made an experimental study on the method to analyze dioxins in exhaust gas from an aspect of international consistency, and worked out a JIS draft. As to the standard measuring method of hormone effects of chemical substances, the paper developed the competitive bonding experiment system to measure bonding ability of chemical substances to homo sapiens estrogen receptor (ER). By measuring ER bonding ability of 78 kinds of chemical substances, the measuring method was developed. In the development of the assay system for detection of hormone-like compounds, the assay system with transfer activity via estrogen receptor as an index was established using cultured cells and yeast. Further, the development was made of a measuring method of receptor bonding activity of hormone-like substances. 33 refs., 151 figs., 66 tabs.

  2. Problem on environmental hormone (endocrine disturbing chemicals); Kankyo horumon (naibunpi kakuran kagaku busshitsu) mondai ni tsuite

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    Tawarada, T. [Kansai Electric Power Co. Inc., Osaka (Japan)

    2000-02-10

    This paper describes a problem on environmental hormone. Various chemicals discharged into environment act as hormone- like or anti-hormone-like substance. Since many such chemicals act as female hormone-like substance, those are called '(exogenous) endocrine disturbing chemicals' or 'environmental hormone'. Such chemicals include already regulated toxic PCB and dioxin, and a large amount of plastic raw materials, plasticizer and surfactant with no acute toxicity. The action mechanism of endocrine disturbing chemicals is as follows. Those bond with acceptors in place of hormone, and give incorrect directions to genes. Those may cause various disorders such as reproduction anomaly, development anomaly, immune toxicity and neuro-toxicity over several ages. For wild animals, some conceivable effects are being revealed. Since living organisms have various specificities and various experiments possible for animals are impossible for mankind, many obscure points remain unsolved. This paper presents various approaches in Japan. (NEDO)

  3. Analysis and evaluation methods for chemical contaminants in clean room air; Kagaku osen no bunseki hyokaho clean room kukichu no kagaku osen busshitsu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Fujimoto, T.

    1998-07-31

    As for, chemical contamination in a cleanroom air has taken up as a important problem. As the main source is building materials, after construction the execution of countermeasures is difficult. Out-gas evaluation and selection in building materials, chemical filters for removing specific organic matter and so on, are a large technical theme in the future and analytical techniques corresponding them become necessary. In this paper, analytical methods of airborne molecular contaminants (AMCs) are introduced. Main samples are AMCs in cleanroom atmosphere, on silicon wafer surface and out-gas from raw materials for cleanroom construction materials such as sealant, plastics and so on. Analytical methods consist of quantification of inorganic compounds, organic compounds and identification of abnormal spot with local/surface analysis. Various interesting findings with analytical data are obtained and investigated. 22 refs., 6 figs., 5 tabs.

  4. Preventive counterplan for chemical poisonings and the role of toxicology; Kagaku busshitsu chudoku jiko taisaku to dokubutsugaku

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, T. [Showa Univ., Tokyo (Japan). School of Pharmaceutical Sciences

    1996-02-10

    Some cases of poisoning by chemical substances are taken up, and counterplans are discussed. This report centers about the neurotoxic gas sarin incidents dealing with them as examples of acute poisoning caused by chemical substances. The important difference in terms of chemical structure between a neurotoxic gas and organo-phosphoric pesticide is that in the former phosphorus is directly bonded with carbon or halogen while, in the latter, bondage is represented by P-O-C, P-S-C, and the like, so bonded as to form the phosphoric acid, thiophosphoric acid, or dithiophosphoric acid. The result of the difference in chemical structure is that the neurotoxic gas easily gains access to the target enzyme and remains stable after bonding therewith while the organo-phosphoric pesticide is easily hydrolyzed by enzymes other than the target enzyme. Poisoning by neurotoxic gas or organo-phosphoric pesticide is clinically treated by the administration of atropine and 2-pyridine aldoxime methiodide which is an antidote. It is mandatory to let people clearly know beforehand the methods of analysis of chemical substances and their toxicity and to establish beforehand how to first-aid the victims and what emergency treatment can be executed. 11 refs., 2 figs., 2 tabs.

  5. Environmental endocrine disruptors and developmental abnormalities in wildlife; Kankyo horumon (gaiinsei naibunpi kakuran kagaku busshitsu) no kankyo seibutsu ni taisuru eikyo

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    Iguchi, T. [Yokohama City Univ., Yokohama (Japan)

    1998-04-15

    The environmental endocrine disruptor, or the so-called environmental hormone, is outlined. Hormones are secreted from endocrine glands in trace amounts, transported by blood, and exert influence on the target organs and distal cells, this to sustain constancy in living organisms. There are two types: peptide hormones which are rows of amino acids and steroid hormones which are composed of cholesterol. Endocrine disruptors are chemical substances discharged into the environment which, once taken into human organisms, disrupt endocrine systems, some acting like female sex hormones and others resisting male sex hormones. Many a wild animal are found affected by them. They are accumulating in human organisms too. Synthesized chemical substances such as DDT, PCB, dioxins, and alkylphenols present in the water system affect a fish by disrupting its endocrine, immunity, nerve, growth, and regeneration. Embryos and larvae are quite susceptible, easy to turn abnormal. Voices are high across the world for the study of environmental endocrine disruptors. Introduced in this report are some animal experiments, typical cases of impact on the ecosystem, and systems for detecting environmental endocrine disruptors. 36 refs., 1 tab.

  6. Fate models for chemical substances in exposure and risk assessment. Focused on estimation of atmospheric concentration; Bakuro{center_dot}risuku hyoka ni okeru kagaku busshitsu unmei yosoku moderu. Taikichu nodo suitei wo chushin toshite

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    Higashino, H. [National Inst. for Resources and Environment, Tsukuba (Japan)

    2000-09-20

    A fate model is one of the most effective tools in exposure and risk assessment of chemical substances. Two different type models are available for estimating the atmospheric concentration. One is unit box and multi compartment type model, the other is atmospheric dispersion model. These models should be used in different suitable situations because each model has both advantage and disadvantage. Estimation of the long-term average concentration in a comparatively wide region into which substances are continuously discharged should be required in the environmental assessment of chemical substances. We developed the model with which to estimate long-term average atmospheric concentrations of chemicals. The model validation was conducted for trichloroethylene and tetrachloroethylene concentrations in the atmosphere by comparing calculated values and observed values. Good agreement with the measured values was obtained for the monthly average concentration. The model is capable of estimating the long-term (such as monthly) average distribution of concentration of chemicals in a wide flat area such as the Kanto plain. (author)

  7. Report on achievements in fiscal 1999 on the project for research and development of an intellectual base creating and utilizing technology. Research and development of standard substances related to internal secretion disturbing chemical substances (researches on preservation stability and the valuing methods related to pure substance standard substances, mixed standard substances and composition type standard substances); 1999 nendo chiteki kiban sosei riyo gijutsu kenkyu kaihatsu seika hokokusho. Naibunpi kakuran kagaku busshitsu kanren hyojun busshitsu no kenkyu kaihatsu (junbusshitsu hyojun, kongo hyojun oyobi soseigata hyojun busshitsu ni kakawaru hozon anteisei, nezuke hoho nado ni tsuite no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This paper describes the achievements in fiscal 1999 on researching and developing standard substances related to internal secretion disturbing chemical substances. Environmental contamination due to environmental hormones has a large number of scientifically unclear points. These points are related to the basic conditions for the existence of living organisms, whereas serious impacts transcending the generations are feared. In addition, the environmental hormones have been observed in water quality, water bottom quality, and living environments for aquatic animals. Standardization in technologies to measure them, and arrangement of standard substances are demanded strongly. Based on these circumstances, evaluations were given on the following matters: determination of purity of the reference substances with regard to the standard solutions of di-2-ethyl hexyl phthalate, di-n-butyl phthalate, and diethyl phthalate among the standard substances required for the measurement, establishment of methods for measuring impurities and preparing the standard solutions, establishment of the methods to measure concentrations of the standard solutions, and the preservation stability of the standard solutions. As a result, standard solutions with accurate concentrations and excellent stability were developed. In addition, development was performed on the composition type standard substance for which a certified value was given to PCB in soil. (NEDO)

  8. FY 1998 annual report on the research on the possibility of introducing a usable chemical substance manufacturing system by utilizing natural gas containing CO2; CO{sub 2} gan'yu tennen gas den katsuyo ni yoru yuyo kagaku busshitsu seizo system donyu kanosei ni kansuru chosa kenkyu 1998 nendo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The trends of effective use of gas containing CO2 from natural gas fields are surveyed, and usable chemical substance manufacturing systems which utilize natural energy are investigated, evaluated and analyzed, to extract promising systems for effective use of CO2-containing natural gas and thereby to promote its effective use. Chapter 1 outlines possibility of integrated use of gas containing CO2 from natural gas fields and natural gas energy. Chapter 2 describes the research trends in the CO2 conversion reactions for using unexploited CO2 as the carbon source. Chapter 3 describes natural energy utilization technology applicable to gas containing CO2 from natural gas fields. Chapter 4 describes performance of chemical manufacturing systems utilizing natural gas containing CO2. The energy balances and CO2 emission coefficients are estimated, based on the above. The evaluation is implemented in the order of (1) conventional steam reforming, (2) steam reforming in which heat is supplied by a solar furnace, (3) examination of the exhaust gases from a methanol synthesis process, and (4) examination of CO2-mixed reforming. Chapter 5 describes summary and proposals. (NEDO)

  9. Material cycling solar system modeled ecosystem; Seitaikei wo model to shita busshitsu junkangata solar system

    Energy Technology Data Exchange (ETDEWEB)

    Sato, M. [Hachinohe Institute of Technology, Aomori (Japan)

    1996-10-27

    It is proposed to establish an integrated system close to a natural ecosystem for an industrial complex, taking that in Hachinohe City, Aomori Pref. as the conceptual site. It is a system in which materials are recycled by solar energy and industrial waste heat for a complex food industry. The conceptual site, although blessed with various marine products, are sometimes attacked by cold weather. Waste heat from a 250,000kW power plant, if transported by EHD heat pipes to the site, could provide roughly 400 times the heat required for production of agricultural and marine products, such as cabbages and fish meat. The waste heat, coupled with solar energy, should solve the problems resulting from hot waste water, if they could be utilized for the industrial purposes. The food industrial site that produces agricultural and marine products is considered to be suited as the center of the solar industrial complex incorporating farms. 5 refs., 3 figs.

  10. Microchemical device based on microscopic bilayer lipid membranes; Bisho 2 bunshimaku wo mochiiita maikuro kagaku debaisu

    Energy Technology Data Exchange (ETDEWEB)

    Yokoyama, H. [Electrotechnical Lab., Ibaraki (Japan)

    1996-04-01

    If an organism is regarded as a macromolecular system, the element device to construct the same is the molecular structure of nano meter scale formed by the functional protein existing in biomembranes. A lot of essential functions of organism such as the sense reception including vision, gustation, etc., photosynthesis, energy-substance production and so on are performed therein. In this paper, the structure, preparing process and the functions of the microchemical device using micro-bilipid membranes are described. The simulation of the sense receiving functions of organisms is tried by said microchemical device wherein, same as biomembranes, the base is bilayer lipid molecular membrane and the receptive protein for receiving signals from exterior and output molecules such as ion channels connected to said receptive protein and the like are incorporated in the membranes. Recently, it becomes possible to make a partial imaging of the bilayer lipid membranes fixed on porous membrane by the observation with scanning Maxwell-stress microscope. 4 refs., 3 figs.

  11. Anti-airborne-molecular-contamination technology in clean rooms; Kukichu no kagaku osen no teigen taisaku

    Energy Technology Data Exchange (ETDEWEB)

    Sakata, S.; Sato, K.; Takahashi, H.; Okada, T.

    1998-07-31

    As for, countermeasures for chemical contaminants in a cleanroom air, the technical development has progressed earnestly since T top phenomenon of photo-amplified resist with basic gas due to atmosphere was pointed out in 1991 by MacDonald. Airborne-Molecular-Contamination (AMC) is classified into acids, bases, condensables, and dopants. According to SEMATECH no 95052812A-TR, condensable are defined as silicones or hydrocarbons with a boiling point greater than or equal to 150 degC. Water-soluble gaseous contaminants in outdoor air coming into cleanrooms are removed with a water spray equipment. AMC originated from circulating air in cleanrooms are prevented using various chemical filters. Conventional chemical filters made of activated charcoal, however, have several defects. Ceramic chemical filters developed by the authors are nonflammable, and consist of inorganic materials without any volatile organic matters and without alkaline metal and so on, and they have high removal efficiencies of condensable. 15 refs., 12 figs., 3 tabs.

  12. Chemical Abstracts for chemical education. Kagaku kyoiku ni yakudatsu chemicalter dot abstracts

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    Tokizane, S. (Japan Association for International Chemical Information, Tokyo (Japan))

    1991-10-20

    The Chemical Abstracts, an information source indispensable for chemical researchers, is introduced with an explanation extended to specific procedure for the on-line retrieval. The Chemical Abstracts is an abstract journal for chemical theses, having a history of nearly 85 years, first published in 1907 for the purpose of introducing its members with advanced chemical researches in Europe. The journal is published weekly at the present, 52 volumes annually, with a large index volume. It collects all kinds of literatures and patents in the world relating to chemistry and engineerings, with many issues containing articles about chemical education. The issue number is divided into odd and even numbers, each issue being sectionalized. For example, the Section 20 in an odd number issue is classified as the History, Education and Documentation. The whole abstracts are retrievable on line even from Japan, with a system called CAS ONLINE available. 10 figs., 6 tabs.

  13. Process improvement technology for petrochemical plant; Sekiyu kagaku puranto ni okesu purosesu kaizen gijutsu

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    Yamada, Shin

    1999-05-05

    Before, GTC technology Co. was a manufacturer of the tray as a Greenwich technology. It is the subsidiary, which undertakes technology and licence of the engineering firm in U.S.A. at present. It carries out besides the technology licence support in the startup for the prolonged driving of technical service, operating condition of the plant of improvement and optimization and, etc. Has made separation and purification technology, which made extractive distillation to be a beginning good and has the process improvement technology to the PTA (high-pure terephthalic acid) from BTX (benzene toluene xylene) of petrochemical plant. (NEDO)

  14. Environmental problem and geochemistry of rabon. Radon to kankyo mondai (chikyu kagaku ni tsuite)

    Energy Technology Data Exchange (ETDEWEB)

    Kanai, Y. (Geological Survey of Japan, Tokyo (Japan))

    1991-10-01

    With Effects of radon (Rn) on human body'' installed as a central theme, a summary is explained on the dealings of Rn with human being, method for measuring Rn, origin of Rn, method for treationg Rn in residential housings, Rn and hot spring, and geochemistry of Rn. The U.S. Environmont Protection Agency announced that Rn has a high possibility of causing lung cancers in the living environment, and that among about 130,000 fatalities annually due to lung cancer, about 5,000 to 20,000 are for Rn. If an effective dose equivalent by Rn is assumed 1, that by the Rn daughter nucleus amount to 50, showing how large the latter {prime}s effect is. The life-time risk increment Rn of a lung cancer due to chronic indoor exposure to {sup 222} Rn daughter nuclei at a constant level of 10{sup 5}Bg.h.m{sup {minus}3} annually is 0.26%, the frequency increment is 36 cases, the life expectancy loss {Delta}L, due to this is 14 days. Rn is, however, not simply hazardous, it can present a benefit as in a radioactive hot spring containing Rn at 51-4909 nC,l. 31 refs., 15 figs., 5 tabs.

  15. Chemistry of environmental materials. 3. Substitutive materials of asbestos; Kankyo zairyo no kagaku. Asbesto daitai zairyo

    Energy Technology Data Exchange (ETDEWEB)

    Fujiki, Y. [Kubota Corp., Osaka (Japan)

    1996-03-01

    This paper outlines the synthesis and characteristics of substitutive materials of asbestos. Oxide system fibers are used as substitutes and classified into natural and synthetic fibers. As natural substitute, wollastonite fiber is used, while as synthetic substitute, silicate system, alumina system, zirconia system and potassium titanate system fibers are used. Wollastonite distributes in regional metamorphic rock and contact metamorphic zone between limestone and plutonic rock, and is used as heat insulator and adiabator. Silicate system fiber includes glass fiber, quartz fiber and silica fiber, while alumina system fiber includes alumina/silica fiber and alumina fiber. Glass fiber is composed of non-alkaline boro-silicate glass and classified into lint and staple. As fibers similar to glass staple, rock wool and slag wool are used. Only slag wool is produced in Japan because of its lower cost and higher qualitative stability than those of glass wool. Potassium titanate system fiber offers excellent heat resistance, thermal insulation and frictional resistance. 18 refs., 13 figs., 9 tabs.

  16. Chemical experiment through the microscope. II. ; Chemical garden. Kenbikyo wo shiyoshita kagaku jikken. II. ; Chemical garden

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    Ninomiya, A.

    1991-06-10

    This report describes the result of observation on chemical garden through the microscope. After putting some 2-3ml sodium silicate solution with fixed concentration into a cistern made of acrylic, various kinds of metallic salt with crystal size smaller than 2mm are added. The cistern is then placed on the stage of the microscope at an angle of 30{degree} to investigate buds growing from crystals of metallic salt specimens. Adopted concentrations of sodium silicate solution are 5%, 20%, and 50%. As a result, at the tips of growing buds, active motions of buds and increase of silicate in each kind of metal as reactive product are observed. In general, silicate concentration in the same metal increases conspicuously with lower concentration of sodium silicate solution. Moreover, it can be considered that the reason why chemical garden can be observed is not only because of difference in water pressure but also an important factor, the thickness of membranes at the tips of buds. 6 refs., 12 figs.

  17. Medical chemical engineering the research; Iyo kagaku kogaku ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Sakai, Kiyotaka [Waseda University, Tokyo (Japan)

    1999-03-05

    He taking the chemical-engineering technique as a weapon, it participates in research and education over the perennial in the field of medical chemical engineering, medical engineering, bioengineering, and the excellent research result has been raised. Moreover, leading research result is raised in these research field which are the interdisciplinary field between medicine and chemical engineering, and the considerable contribution in these fields has been done. He enables the new development of the dialysis technology by advancing the research first of all from the viewpoint of hemodialysis film, hemodialyzer and three of the patient pharmacokinetics, in respect of dialysis technology in the artificial kidney, and developing the original dialysis system enables optimum dialysis treatment. Next, he on the oxygen which is the feed which is the most important for the organism, it originally crosses, and the gas is run in figuring hollow yarn lattice in the hollow yarn inside, and it is clarified that the system for washing the blood outside is advantageous, and it has succeeded in the development of the more efficient artificial lung. And, the artificial gill is examined from the original idea, which takes in the oxygen by using of a film in the oxygen carrier (the substitution blood), as intermediary. Next, he some of the phenomenon in the blood plasma viscosity of patient with renal failure or are measured and the relationship between blood plasma viscosity and disease state is clarified, and the knowledge which is useful for the diagnosis has been obtained. And, it is examined that the quantity that the hydrophobic drug is adsorbed in the albumin differs in normal subject and dialysis patient, and the system for deciding chemical administration quantity to the dialysis patient is being found. Next, in research progress of the above, various measuring technique are devised, and remarkably the research advances. For example, the considerable contribution for measurement of diffuse transmission coefficient of hollow yarn dialysis membrane by the optical measurement technology, glucose using the electrochemiluminescence and immunisation center, this advance on development of the continuous measurement method of the endotoxin, etc. of the research of the direction more and more has been done. In the interdisciplinary field of medical chemical engineering and biochemistry engineering, chemical engineering such as the bioengineering as an importance, he will apply chemical-engineering technique, approach in future more and more, while the above, he make the chemical engineering association to be a basis of the activity, many-sided, and various creative research result have been raised, and the result has been evaluated high in domestic and overseas. (translated by NEDO)

  18. Properties of acid polysaccharides and their chemical modification; Sansei tato no seijo to kagaku shushoku

    Energy Technology Data Exchange (ETDEWEB)

    Kogamo, A. [Kitasato Univ., Tokyo (Japan)

    1997-03-25

    Polysaccharides are in presence throughout the kingdoms of animals, vegetables, and microbes, participating in biotic activities. It has been disclosed of late that they are closely related to biotic functions, and complex saccharides, such as glycosaminoglycan (CAG), which constitute the sugar chain are attracting attention above all. This report centers on CAG and discusses the properties of acid polysaccharides, their chemical modification, and applications. CAG in organisms combines with proteins such as collagen for the formation of connective tissues, and also combines in quantities in covalent bond with proteins that constitute thin and long high-molecular cores for the formation of gigantic molecules called proteoglycan. It is an acid sugar chain in which uronic acid and amino sugar having amino groups intertwine each other. The basic reactions to be utilized for the production of highly active saccharides on the basis of this structure are the lowering of molecular weight and sulfation. Activity against HIV (Human Immunodeficiency Virus) is observed in marine alga saccharide carageenan, and studies are under way for variously modifying it for development into medicine. 6 refs., 6 figs.

  19. Microalgal biotechnologies for recycling of pollutants; Tayona sorui kino wo kiban to suru seibutsuken busshitsu junkangata sogo saishigenka gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Miyamoto, K.; Nasu, M.; Hashimoto, C.; Tanaka, K.; Hirata, M. [Osaka University, Osaka (Japan). Faculty of Pharmaceutial Science; Fujita, M.; Takagi, M. [Osaka University, Osaka (Japan). Faculty of Engineering; Hirata, Y.; Taya, M. [Osaka University, Osaka (Japan). Faculty of Engineering Science; Yamanishi, H. [Osaka University, Osaka (Japan). Faculty of Medicine

    1997-02-01

    This paper describes the technology development by which biomass is produced by treatment of pollutants using microalgae, and is recycled. A bioreactor system has been developed, in which microalgal biomass can be obtained through the effective treatment of CO2 and NOx using microalgae having ability of increase under the severe condition with simultaneous flow of CO2 and NOx. A new method has been also developed for separating and recovering the microalgae. Materials, such as glucose, glycerol, acetic acid, and lactic acid, were produced from the obtained biomass through physico-chemical and biological treatments. These materials can be converted into ethanol and hydrogen. For this treatment and recycling system, functions as a part of natural material recycling were considered to be most significant. Development of an analysis and evaluation method of an impact of this system on the natural environment is also tried. 1 fig.

  20. Needs for intelligent field sensors in petrochemical plants. Sekiyu kagaku plant ni okeru intelligentter dot fieldter dot sensor eno needs

    Energy Technology Data Exchange (ETDEWEB)

    Tsukahara, T. (Idemitsu Kosan Co. Ltd., Tokyo (Japan))

    1990-08-05

    This report explains the process sensors used in petrochemical plants. To establish a safety and accident preventing systems, the function of a sensor to substitute the five senses of an operator is demanded. A man inspects using the senses of seeing, hearing, touch and smell, and takes measures judging from all factors, not from the state of one point. For a wide-range monitoring function, there is a need for a robot which is loaded with sensors of various intelligences and which moves freely at the field. When many sensors are configurated for the wide-range monitoring, the maintenance of system comes into question. The sensor with intelligent functions recently developed can contribute to the maintenance because it is highly accurate and it has the function of self-diagnosis. If it becomes possible to process data with the sensor at the field utilizing the intelligent function, the central control room will be miniaturized and automatization will be pushed forward remarkably. 3 refs., 2 figs.

  1. Survey on bio-chemical complex harmonized with global environment. 3; Kankyo chowagata seibutsu kagaku konbinato ni kansuru chosa. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    A survey was conducted of bio-chemical complex harmonized with the global environment for the purpose of constructing the material production process harmonized with the environment by the process fusion between biological conversion and chemical reaction. Palm oil was taken up as renewable raw material plant resource. The process utilizing bio-chemical reaction advances at normal temperature and pressure and is high in reaction specificity and selectivity. This is a recycling, circulation and environmental harmony type production technology which brings high yield, energy conservation, resource conservation, and low environmental loads. Waste water treatment and production of useful substances from sludge were thought as elementary technology. A possibility was studied of enzyme production by culturing solid waste, and the enzyme was applied to the hydrolysis process. The paper indicated trace components in the palm oil and the extraction method and proposed the production process of new derivatives for adding value to hydrolysate. A study was also made of the overall process flow which integrated these new processes and the material balance. The comprehensive evaluation of this new process was made from the aspect of the product structure, the market, construction cost, economical efficiency, and the environment. 133 refs., 65 figs., 56 tabs.

  2. Coal Liquefaction characteristics and chemical structure of product oil; Sekitan ekika hanno tokusei to seiseibutsu no kagaku kozo

    Energy Technology Data Exchange (ETDEWEB)

    Endo, H.; Sato, M.; Chiba, T.; Hattori, H. [Hokkaido University, Sapporo (Japan). Center for Advanced Research of Energy Technology; Sasaki, M. [Hokkaido National Industrial Research Institute, Sapporo (Japan)

    1996-10-28

    Through the hydrogenolysis of Wandoan coal and Tanito Harum coal which are used for the NEDOL process, differences of liquefaction characteristics between them were found. The purpose of this study is to grasp these differences as differences of chemical structures of oil fractions. The compound type analysis was conducted for oil fractions obtained at varied reaction temperature for varied reaction time. Coal liquefaction characteristics of these coals were discussed by relating oil yields and chemical structures. For Tanito Harum coal, yields of gas and oil were considered to be lower than those for Wandoan coal, which reflected that the contents of partially hydrogenated hydroaromatics in oil fraction from the former were lower than those from the latter, and that the remarkable change of composition did not occur with the progress of the reaction. For both the coals, the remarkable changes in the average molecular weight of oil fraction were not observed with the progress of the reaction. While, the content of methane gradually increased with the progress of the reaction, which suggested that oil was gradually dealkylated. 5 figs.

  3. Introduction of research and development in Image Information Science Laboratory; Image joho kagaku kenkyusho ni okeru kenkyu kaihatsu no shokai

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-10-10

    This paper introduces research and development at the Image Information Science Laboratory. This is a joint industry-university research institution for the purpose of making a computer recognize human non-language information, expressing and transmitting it, with the research conducted at two centers, Kanto and Kansai. The following studies are being made at the Kansai research center: man/machine interface making natural communication possible between a man and a machine, with emphasis placed on visual information; sensing technology for measuring human activity, technology for analyzing/forming human sensitivity, and technology of expression; technology by which a work is done by a computer in place of a man and reproduced on the computer, with the skill transferred to a man; and development of a spatial expression media system such as a three-dimensional display device. The Tokyo research center is participating in the following projects: committee for promoting joint industry-university research and development of virtual reality (VR); joint industry-university research, development and implementation project of advanced VR; survey on physiological psychological effect in VR system and the like; and research and development of human media. (NEDO)

  4. Glyco change of the vancomycin due to the chemical glycosylated; Kagaku gurikoshiruka ni yoru bankomaishin no tohenkaku

    Energy Technology Data Exchange (ETDEWEB)

    Fukuzawa, Seiketsu

    1999-09-01

    Glycopeptide antibiotic vancomycin is drawing attention of the organic composition chemist as a target of the composition from the peculiarity of that structure and the demand in medical treatment. I had the part of the aglycone, which consists of peptides made all the composition in 1997. However, effective activation isn`t shown, and the addition of the part of the sugar is indispensable only with an aglycone. The glycosylated of the part of the aglycone was done, and the re-composition was attained, and this completed all the formal composition. (NEDO)

  5. Measurement of organic carbon quantity at chemoautorophic bacterium; Kagaku dokuritsu eiyo saikin ni okeru yuki tansoryo no sokutei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Tsuda, I.; Kato, K.; Nozaki, K. [Electrotechnical Laboratory, Tsukuba (Japan); Kurokawa, K. [Tokyo University of Agriculture and Technology, Tokyo (Japan)

    1996-10-27

    Described herein is the method for analyzing quantity of organic carbon synthesized by chemoautotrophic bacterium. It is based on the combustion-infrared spectroscopy, which is normally adopted for quantitative analysis of organic carbon. The problems involved in the measurement of organic compounds synthesized by iron-oxidizing bacteria are noise by culture medium components, aging of gas analyzer and contamination with organic compounds from a silicon plug. The measures taken in this study against these problems include comparison of the results with a medium containing iron-oxidizing bacteria with those with a medium free of these bacteria, calibration with the standard solution for each measurement, and replacement of a silicone plug by a silicon cap. Organic carbon is measured by a TOC-5000 analyzer equipped with an automatic sample feeder ASI-5000. Biomass density is determined by the MPN method. It is confirmed that organic carbon quantity is almost in proportion to biomass density, a phenomenon which can be used to determine organic carbon quantity. 7 refs., 6 figs., 1 tab.

  6. Analysis of the pollutant in the environment using supercritical fluid chromatography (SFC); Chorinkai ryutai kuromatogurafui (SFC) wo mochiita kankyo chu no osen busshitsu no bunseki

    Energy Technology Data Exchange (ETDEWEB)

    Kakuchi, T.; Miura, Y. [Hokkaido Univ., Hokkaido (Japan)

    2000-02-05

    The analysis of the organic pollutant in the environment is carried out as the following procedure; the organic substance is extracted by using the organic solvent from a collected sample, an instrument analysis such as gas chromatography (GC) or high performance liquid chromatography (HPLC) are done after the clean up the sample by column chromatography. The analysis using supercritical fluid instead of the organic solvent in each stage is supercritical fluid extraction (SFE) or supercritical fluid chromatography (SFC). The supercritical fluid has a density and viscosity coefficient between gas and liquid, and the control of the dissolving power is possible by the change of temperature and pressure. Therefore, it has the advantage as follows: The material mobile speed is high and separation and extraction are rapid; It is easy to adjust the dissolving power and possible to carry out selective separation and extraction; The removal of solvent can be easily carried out since supercritical CO{sub 2} used is a gas in the normal pressure. In this paper, the analytical instrument in which the extraction is carried out in organic solvent and clean up was done in SFC was introduced. (NEDO)

  7. Survey of pollution-resistant plants and their cultivating techniques; Osen busshitsu taisei shokubutsu to sono shokusai gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The reduction of forests due to environmental pollution has been surveyed, to investigate the pollution-resistant plants and solid microorganisms. In Japan, the blight of needle-leaf trees (pine and momi fir) and of Japanese oak has occurred, and blight of some other trees, such as wild cherry trees, Japanese apricot trees, birch, Japanese cedar, cypress and bamboo, has been reported from various regions. In this article, plants reported to be resistant to pollutants are listed, and the physiological features of these plants are described. Furthermore, to develop pollution-resistant plants, reports relating to clarification of the mechanism of resistance development and the genes involved are reviewed. Microorganisms which symbioses for roots support these root functions. They also suppress the activity of pathogenic microorganisms and improve the environment around the roots, thus helping plants to grow normally. The roles played by symbiotic microorganisms and how to utilize these organisms are discussed. Their functions in coping with acid rain and heavy metal pollution, and how to utilize such functions are also discussed. 707 refs., 13 figs., 13 tabs.

  8. International symposium on environmental impacts of advanced alternative to CFC; CFC shinki daitai busshitsu no kankyo eikyo ni kansuru kokusai symposium hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-07

    The international symposium on environmental effects of new CFC substitutes was held in Tsukuba City, Ibaraki Pref. on February 7-9, 1996, and 19 papers were made public. In Session 1 (Plenary lecture), reports were made on Global warming and climate change: a review of recent studies; Stratospheric ozone, CFCs, and CFC-substitutes: an update, etc. In Session 2, Measurements of OH rate constants for advanced refrigerants as well as HCFCs and HFCs; The reaction rate of CFC alternatives with OH radical; Experimental and estimated rate constants: reactions of hydroxyl radicals with several halocarbons, etc. In Session 3, Measurement of uptake coefficients of some acetyl halides and fluorinated ethers into water; Mass transfer at the air/water interface: removal processes of halocarbonyl compounds; Heterogeneous reactions of fluorinated ethers on allophane or titanium dioxide, etc. In Session 4, papers were reported on model calculations relating to the global warming.

  9. Numerical simulation of emissions and depositions of acidic air pollutants in East Asia; Higashi ajia chiiki ni okeru taikiosen busshitsu no haishutsu to yuso simulation

    Energy Technology Data Exchange (ETDEWEB)

    Higashino, H. [Agency of Industrial Science and Technology, Tokyo (Japan)

    1997-12-01

    In order to consider how to cope with problems of great-sphere air pollution in the East Asia such as acid rain, etc., it is required to investigate the real conditions of emitted air pollutants and to develop a transfer model which clarify the relation between emissions and depositions. This paper describes the present state of studies on the amount of estimated air pollutive emissions in the East Asia and estimated depositions by transfer models. Typical studies on estimated grid-by-grid distribution of emissions in the East Asia are explained first and other estimated examples, i.e. data announced by the Chinese Government and etc., air also referred. The models developed for estimating acidic pollutants falling down in the East Asia are insufficient, however, acidic pollutant transfer models applied at present are introduced. The results of the author`s study are described and the subjects for a future study are referred. 27 refs., 5 figs., 4 tabs.

  10. Estimation for origin of coals on biomaker analysis; Jinko sekitan oyobi tennen sekitan no biomaker bunseki ni yoru sekitan kigen busshitsu no suitei

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Y. [Geological Survey of Japan, Tsukuba (Japan); Sugimoto, Y. [National Institute of Materials and Chemical Research, Tsukuba (Japan); Okada, K. [Coal Mining Research Center, Tokyo (Japan)

    1996-10-28

    In order to study coal production processes, an estimation study was carried out on coal originating materials by using biomaker analysis. Test samples are original coals collected directly from a mine in Hokkaido (not having been subjected cleaning). Mixing and solvent extraction were performed after pulverization, and then tests were given on saturated hydrocarbon components divided by using a silicagel column chromatograph for the present study. It can be known from n-alkane distribution in the coal that low molecular alkane increases with increasing degree of coalification. Artificial coal made by wet-heating Metasequoia leaves contains only little n-alkane. Diterpenoid compound exists in the Taiheiyo and Akabira coals. Tetra-cyclic diterpernoid is contained abundantly in subtropical coniferous trees, serving as a parameter for warm environment. The compound is contained also in the Fushun coal, but not in Indonesian coals. Hopanoid constitution shows very high similarity, but H/C atomic ratio may vary largely even if the coalification is at the same degree. This is likely to be caused from difference in originating materials. Hopanoids are bacteria attributed substances, whose activities are not affected by the originating materials. 2 figs., 1 tab.

  11. Occurrence and purification on microcystis species. Toxicology of blue-green algae toxins; Aoko/sono hassei to joka taisaku. Aoko no yudoku busshitsu no dokusei ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Kaya, K. [National Inst. for Environmental Studies, Tsukuba (Japan)

    1994-09-10

    In recent years the blue-green algae has occurred tremendously in the lakes at every places in the world, and therefore it has become a social problem. Especially in Australia and New Zealand, the damages not only on the cattles and the wild animals, they have commenced to develop up to the health problems of the residents. By a progress of the study of the blue-green algae toxins, a structure and toxicity of many blue-green algae toxins have been made clear. The microcystin which it one of them, is a hepatic toxin produced by the microcystis, anabaena and oscillatoria. By the way, because it was made clear recently by a study done by the National Cancer Center that it had a carcinogenesis promotion action, its action has been paid attention over again. In the blue-green algae toxins, besides the microcystin it is made clear that there are the nervus toxins such as the anatoxin-a and anatoxin-a (s) produced by anabaena, the aphantoxin produced by aphanizomenon and so forth. In this paper, as for the toxicity manifestation mechanism of the microcystin which is thought to become a point at issue in Japan, an information up to date is introduced. 17 refs., 2 figs.

  12. Antibiotics produced by marine bacteria and the evaluation of their activity; Kaiyo saikin no seisansuru kosei busshitsu to sono kassei hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Yoshikawa, K.

    1997-09-10

    Researches continue into physiologically active substances metabolized by marine bacteria and, in this report, some that exhibit antibacterial activity (antibiotics) are introduced. A detailed description is given of a new, peculiar antibiotic named Koromicin discovered in this project. Since a number of terrestrial bacteria have already been investigated, marine halophiles, especially those adhering to large seaweed in eutrophic environments, are taken up in this paper. This is because they are easy to culture. Many are collected in Japan and South-Sea islands, and some are selected for culture in view of their capability for producing active substances. Active compounds are extracted from them, refined, isolated, and their structures are determined. It is found that many of the thus-obtained compounds are those that have already been isolated from marine creatures in the past, but this verifies the effectiveness of selecting the marine bacteria as the source from which to collect physiologically active substances. Koromicin discovered in this process is unique in that it impedes the growth of marine Gram-negative bacteria only. 11 refs., 4 figs., 2 tabs.

  13. Report of the 8th International Symposium on the Observation of the Continental Crust Through Drilling; Dai 8 kai tairiku kagaku kussaku kokusai symposium ni sankashite

    Energy Technology Data Exchange (ETDEWEB)

    Yoshida, K. [Super Deep Core Drilling Study Group, Japan, Tokyo (Japan)

    1996-11-29

    This report relates to the 8th International Symposium on the Observation of the Continental Crust Through Drilling, convened at Agency of Industrial Science and Technology, Tsukuba City, on February 26, 1996. The symposium was represented by approximately 200 people from the U.S., Canada, Britain, Germany, France, Russia, China, and some others, who discussed active faults, drilling and logging, transfer of fluids and heat in the crust, history of the earth and climate, ICDP (International Continental Scientific Drilling Program) and international cooperation under this program in the future, etc. In reference to ultradeep drilling in the world, drillings by Germany`s KTB (Kontinentales Tiefbohrprogramm)(9,101m deep) and Russia at Kola Peninsula (l2,261m) were reviewed. Concerning the efforts of U.S. Continental Scientific Drilling Program during the previous 11-year period, it was reported that it had cost a total of $84,000,000; that investigations had been made into volcanos and geotherm, fault tectonics, sedimentary basins, holes due to meteorites, and metal ore deposits; and that 61 holes (total length: 31,310m and maximum depth: 3,510m) had been drilled and investigated. 6 figs., 3 tabs.

  14. Fiscal 1995 research investigation on chemical process technology using supercritical fluid; 1995 nendo chorinkai ryutai wo riyoshita kagaku process gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    With relation to the supercritical fluid utilization technology, conducted in fiscal 1995 were collection of basic data, extraction of R and D subjects and survey/analysis of application fields based on the literature survey and overseas field survey. From the research results, the following were selected as research subjects: as to the clean/recycling process technology, non-selection cascade treatment process of mixed waste plastics, hazardous waste treatment process, and radioactive waste treatment process. As to the unused resource utilization process technology, the supercritical submerged combustion power generation process, heavy hydrocarbon resource reutilization process, biomass synthetic utilization process, and carbon dioxide reutilization process. As to the next generation reaction process technology, the simple reaction process, de-organic solvent process, chemical materialization process for methane, and reaction separation combined process. As the innovative material process technology, the plastic forming process, high-functional materials, high-efficiency energy conversion materials, and heightening of function of solid wastes. 537 refs., 116 figs., 54 tabs.

  15. Chemistry for preserving the global environment. Part 5. Offensive odor; its present condition and control technique; Kankyo sozai no kagaku. 5. Akushu no genjo to taisaku gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Saiki, Y.

    1996-07-01

    Offensive odor substances belongs to a quite different field from the perfume inspire of the same sense of smell, and is a substance forming a lot of troubles which is formed in intimate resident environments such as manufacturing factories of the chemicals, incineration and decomposition treatment process of living body relating substances, stock raising facilities, restaurants and others. A material called the offensive odor substance is generally in very low concentration in the atmosphere, most of which is ppm order in its detection limit. And, the offensive odor intensity is proportional to logarithm of its concentration. For example, even removing 99.9% of the offensive odor substance from its forming source, there is remained its difficult countermeasuring problem of no removing as its offensive odor. At present, the offensive odor is severely regulated by means of laws and acts, research on its relating field is active, and its relating publications have become plenty. In this paper, outline on recent state of the offensive odor and its measuring technique was summarized. 14 refs., 6 figs., 8 tabs.

  16. Influence of hydrothermal flux on arsenic geochemical balance of seawater. Kaisuichu no hiso no chikyu kagaku balance ni taisuru nessui no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Shikazono, N. (Keio University, Tokyo (Japan). Faculty of Science and Technology)

    1993-11-05

    It was recently confirmed that a large quantity of hydrothermal solution has been gushing out at back-arc basins and ocean ridges. Therefore, effects of the hydrothermal solution on the seawater composition have been studied in many ways. In this report, balance of arsenic in seawater is investigated since arsenic has a higher concentration in hydrothermal solution than in seawater. Trial calculations are conducted based on the arsenic concentration in hydrothermal solution and the seawater/hydrothermal-solution circulation amount. As a result, it is assumed that the hydrothermal input flux from island-arc/back-arc basins into seawater is much higher than that from ocean ridges. The total hydrothermal input flux is (0.28-5.36) [times] 10[sup 11]g/year, which is equivalent to or higher than that of river flux. The total input flux of arsenic including input from volcanic gas is in the same order as the output flux of arsenic due to the pyrite formation within submarine sediment. It is estimated that the subduction flux into the depth of the crust is lower than the hydrothermal flux from island-arc/back-arc basins. Therefore, it is inferred that most of the arsenic subducted into the crust would be circulated in the ocean. 23 refs., 2 tabs.

  17. Explosion in a rotary dryer at a chemical factory. Eikoku kagaku koho no kaiten kansoki no bakuhatsu jiko (shiryo kenkazai no netsubunkai boso hanno)

    Energy Technology Data Exchange (ETDEWEB)

    Shioji, Y. (Nippon Oil Co. Ltd., Tokyo (Japan))

    1991-10-15

    This paper reports a dryer explosion and fire accident in the Dow Chemical {prime}s King {prime}s Lynn factory in Great Britain. Nine other accidents of dryers on the similar type are also reported to indicate the importance of advance evaluation on substances for their hazard. The subject accident occurred while a group leader was reporting a gushing sound and white smoke from the door of the dryer room at a little after 17:00 on June 27, 1976, an explosion bursted at 17:10 causing an immediate death of an operator due to a blast from the explosion. THE damage of the manufacturing equipment is estimated to have amounted to about 1.25 million pounds. The exolosion accident has occurred when the Zoalene (product name), a chicken feed additeve, has been left in a dryer in nearly a sealed condition for 27 hours after having been dried, its temperature was maintained at 120-130 {degree}C as a result of heat insulating effect of the insulators on the dryer. This caused a pyrolysis of the product, of which heat accelerated the pyrolysisand led to an explosion. One of the basic causes was that no safety evaluation technique has been established to predict danger of the drying operation. 2 refs., 5 figs.

  18. Investigation into the analysis method of total ecobalance in chemical industry products. 3; Kagaku kogyo seihin ni okeru total eko balance no bunseki shuho ni kansuru chosa. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    For the purpose of establishing a total life-cycle ecobalance analysis (LCA) method, the paper studied making of a general computer program for chemical industry products. The study has been made on general-purpose plastics (PET/PSP (polystyrene paper)) since fiscal 1993 aiming at making the CO2 emission computing program covering the entire process of production from extraction of raw materials through waste disposal. In fiscal 1995, the following were conducted for enhancement of generalization of the method: expansion of environmental load items and increase in validity of the concept, and expansion of database. Notice was taken of not only CO2 but SOx, NOx and water quality load items. The survey was made on the recycling situation in Japan and abroad and the PET recycling plant , and environmental load item data are collected to expand database. The program was verified by analyzing an example of reusing PET bottle to carpet, and one-step development can be made toward the establishment of the method. Moreover, an analysis was made for the environmental assessment of the related programs abroad, and a tentative original plan can be proposed for the standardization of environmental load analysis and the integrated assessment method. 39 refs., 130 figs., 76 tabs.

  19. Trend of the strategy of European and American chemical industry in the restructuring; Obei kagaku sangyo no saihen ni miru senryaku no doko

    Energy Technology Data Exchange (ETDEWEB)

    Niimi, M.; Yamabe, T.

    1999-12-01

    The business of life science is the cover products which connect directly with life such as medical supplies, functional food, nutriments, agricultural chemicals or seeds. The wave of the reorganization of enterprises in the life science field also spread to the integration of the medicine specialty enterprises, and new association trees mainly on medical supplies such as Novartis in Switzerland, Zeneca, Astra Zeneca and Glaxo Wellcome in England were born. Many major chemistry manufacturers are also agricultural chemical manufacturers. Though agricultural chemicals were being shifted to one which being effective at the low use owing to the environmental problems, with the advance of the popularization of gene recombination crops, sales decreased on the agricultural chemical business more, and participation and restructuring to the seed business were accelerated. In this paper, the outline of business restructuring and strengthening the basic strategy in the main chemistry enterprises in Europe and the U.S.A. are described. As a trend of the restructuring, some examples on Du Pont, Dow chemical, Monsanto, ICI, Akzo Nobel, Novartis, Shell Chemicals, BASF, Hoechst and Bayer are introduced. (NEDO)

  20. Investigations on an environment friendly chemical reaction process (eco-chemistry). 2; Kankyo ni yasashii kagaku hanno process (eko chemistry) ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    In order to structure a chemical reaction process that does not discharge a large amount of waste by-products or harmful chemical substances, or so-called environment friendly process, investigations and discussions were given based on the results derived in the previous fiscal year. A proposal was made to reduce environmental load on development of oxidized and dehydrogenated catalysts that can produce selectively ethylene, propylene and isobutylene in an oxidation process. In liquid phase oxidation, redox-based oxidation and solid catalyzation of automatic oxidation reaction were enumerated. In acid base catalyst reaction, development of ultra strong solid acid was described to structure no pollution discharging process. In the fine chemical and pharmaceutical fields, the optical active substance method and the position-selective aromatics displacement reaction were evaluated to reduce environmental load. A questionnaire survey performed on major chemical corporations inside and outside the country revealed the following processes as the ones that can cause hidden environmental problems: processes discharging large amount of wastes, processes treating dangerous materials, and processes consuming large amount of energy. Development of catalysts is important that can realize high yield, high selectivity and reactions under mild conditions as a future environment harmonizing chemical process. 117 refs., 23 figs., 22 tabs.

  1. Proceedings of the papers of the 33rd Coal Science Conference (1996); Dai 33 kai sekitan kagaku kaigi happyo ronbunshu (1996)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-10-28

    This is a proceedings of the papers made public in the 33rd (fiscal 1996) Coal Science Conference held by the Japan Institute of Energy. The number of the papers included is 82. The processes such as coal liquefaction, coal gasification and pyrolysis are largely influenced by reaction of the carbon compound in coal. However, coal, which is different in reaction characteristics depending on its producing area, is a comprehensive compound. Therefore, the trial has been made for clarifying the molecular structure and skeleton. In the sense, the following papers are taken notice of: Suzuki and others` Estimation for origin of coals by biomaker analysis; Sugimoto and others` Change of unit skeletons during the artificial coalification; Hirado and others` Study on the correlation between chemical and mineral composition of coal ashes; Okawa and others` Coal structure construction system with construction knowledge and partial energy evaluation; Kanbayashi and others` Analysis of the relationship between coal properties and liquefaction characteristics by using the coal database.

  2. Fiscal 1996 investigational research on the chemical process technology using supercritical fluids; 1996 nendo chorinkai ryutai wo riyoshita kagaku process gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Importance was studied of making a research on the chemical process technology using the supercritical fluid. As for its effect on global warming, the amount of CO2 emission was compared during the operation between the conventional process and the process using the supercritical fluid, the CO2 reduction rate and amount were trially calculated, and a CO2 reduction of a several ten thousand ton scale in carbon conversion was predicted. As to hazardous materials and the reaction of waste retrieval, it was made clear that the process using the supercritical fluid was valid also for objects for which the chemical process used to be impossible, which indicates a possibility of the widening field of application. Concerning its effect on the energy conservation, energy reduction of several ten thousand tons in heavy oil conversion was predicted by replacing all the existing processes with supercritical fluids. Relating to the recycling, with the use of supercritical fluids, the process is possible which produces higher quality and yield and fewer unnecessary products such as char than the conventional process. 197 refs., 102 figs., 71 tabs.

  3. Survey report on an environmental harmony type production system of chemical products; Kankyo chowagata kagaku seihin seizo system ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    As part of establishing an environmental harmony type production system of chemical products, study and survey were made on PET bottles. Using the life cycle analysis method (LCA), a study was made for proposing a material recycle (MR) method which is environmentally and economically excellent in the stage of recycling waste PET bottles. The total cost of recycling can be reduced by 34% supported by a decrease in equipment cost and improvement in yield if there is no mixture of foreign substances such as aluminum caps and PVC bottles. However, the ratio of the amount obtained from the reduction to the total production cost is small, and it is necessary to take measures from a viewpoint of the cost in a total production process and environmental loads. In a survey in Kawaguchi city, PET bottles discharged from the business sector occupied 41% of all the discharge amount. In a survey in Yokohama city, very important data were obtained on PET bottles appointed as the second type under the recycle law. The quality of PET bottles to be brought to the recycling plant is important for effectively processing PET bottles in MR method. For achievement of MR which is low in cost and small in environmental load, needed were cooperation by citizens, the shipping management system in autonomous government, and changes in design and material quality to be made by the industrial circle. 8 refs., 64 figs., 68 tabs.

  4. Fourth CANMET/ACI/JCI International Conference. Chemical admixture (5); CANMET/ACI/JCI dai 4 kai kokusai kaigi yori. Kagaku konwazai (5)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-05-10

    Coppola et al. (Italy) discussed the effect of SO3 in the gypsum in clinker phase on the behavior of high-fluidity concrete, and pointed out the SO3 affected slump loss and initial strength. Shoya et al. (Hachinohe Inst. of Technology) reported that they succeeded in improving the water sealing property of concrete without deteriorating mechanical properties of concrete by using water repellent admixture containing reactive silica fine powder. Torresan et al. (Italy) reported that they developed a new SP agent based on melamine sulphonic acid polymer, and found the improving effect of this agent on water reducing performance, giving high initial strength which is suitable for factory use. Kubo et al. (Kyoto Univ.) investigated the water repelling property of silane treatment and found the effectiveness of this method as a repairing method. (translated by NEDO)

  5. Effects of inhalation of and exposure to gaseous substances to genital organs, and sexual difference. (6). Gas jo busshitsu kyunyu bakuro ni yoru seishokuki eno eikyo oyobi seisa. (6)

    Energy Technology Data Exchange (ETDEWEB)

    Inoue, N.; Mori, K.; Fujishiro, K.; Hori, H. (Univ. of Occupational and Environmental Health, Kitakyushu (Japan). Institute of Industrial Ecological Science)

    1991-01-01

    Results of studies and knowledges therefrom are reported on intermediate materials used in the chemical industry and ethylene oxide used as a sterilizer for medical devices as to how their toxicity affects the different sexes and feminine genital organs. Male and female rats were subjected to inhalation of and exposure to ethylene oxide at a concentration of 250 ppm 6 hours a day, 5 days a week for 17 weeks (some of them for 10 weeks), and chronic toxicity of ethylene oxide was investigated on sexual difference and female genital organs. The female rats showed their estrous cycle extended, and an increase in ratio of the estrous periods accounting for in the entire cycles was idenfified. While no sexual difference was identified in the degree of disorders in peripheral nervous system, strong macrocytic normochromia anemia was observed in female rats. Activity of glutathione reductase in ovaries has decreased, and an increase in glutathione-S-transferase activity was observed. It was made clear from these facts that ethylene oxide affected also female genital organs. 15 refs., 7 figs., 10 tabs.

  6. Development of stereoselective analytical methods of chiral drugs and biological substances and application of hepatic local drug disposition; Yakubutsu oyobi biryo seiri kassei busshitsu no rittai sentakuteki bunri bunsekiho no kaihatsu to kanzo kyokusho dotai kaiseki eno oyo

    Energy Technology Data Exchange (ETDEWEB)

    Nakagawa, T. [Kyoto University, Kyoto (Japan). Faculty of Engineering

    1994-12-15

    With an objective to elucidate the structure recognizing ability possessed by living organisms, discussions were given on methods to analyze the bonds between optically active drugs and polymers, and methods to analyze drug disposition fluid-dynamically. Studies have been advanced on the following themes, and the results were obtained therefrom: development of an on-line system to quantify non-protein bonding type concentrations in drugs utilizing the high-performance fraction analysis (HPFA, using a restricted movement type HPLC column) that had been already developed, establishment of a method to analyze hepatic local drug disposition by using the MULTI (drug disposition analyzing) program, and studies on stereoselectivity by using NMR generated by interactions of local anesthetics and lipids. The following findings were obtained: using the above on-line system, a discussion was given on protein bonds between BOF-4272 (xanthine oxidase inhibitor) and serum albumins, and the discussion was found effective in analyzing the stereoselectivity in drugs with strong protein bond; and with the above analytic method, optical behavior of ketoprofen (KP) in rat liver perfusion was discussed, wherein the transfer of KP into liver tissues was estimated to have been caused by involvement of active transportation rather than physical diffusion. 7 refs., 6 figs., 4 tabs.

  7. FY 1998 annual report on the decomposition/removal of harmful compounds in the gaseous phase by porous membrane provided with a catalytic function; 1998 nendo shokubai kinotsuki fuyo takomaku ni yoru kisochu yugai busshitsu no bunkai jokyo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Harmful compounds, e.g., dioxins and nitrogen oxides, released into the air are causing severer environmental problems on a global scale. In order to solve these problems, it is necessary to efficiently remove the released compounds in the vicinity of the living environments, while preventing, as far as possible, their formation at the sources. An attempt has been made to develop porous membranes impregnated with composites of a variety of metallic oxides showing activities as photocatalysts and for dark reactions by the ion engineering method, in order to drastically solve the above problems. Described herein are the FY 1998 results. Thin films of various titanium oxide crystals (anatase, rutile, and their combinations) are formed on Si substrates by the ion engineering method, as the photocatalysts for decomposition of aldehyde and water (for hydrogen production), to validate the optimum crystalline structures for the photocatalysis. Porous bodies of Ni and carbon are also impregnated with anatase TiO{sub 2} for decomposition of harmful gaseous compounds and water, to validate the effects of the porous membranes provided with catalytic functions. (NEDO)

  8. Synthesis of (E)-9-Oxo-2-decenoic acid (the queen substance of honeybee) from methyl 3-formylpropionate; 3-horumiruporopion san mechiru wo mochiita (E)-9-okiso-2-desen san (Mitsubachi joo busshitsu) no gosei

    Energy Technology Data Exchange (ETDEWEB)

    Tsukasa, H. [Toyotama Koryo Co. Ltd., Tokyo (Japan)

    1997-05-20

    The queen substance, (E)-9-oxo-2-decenoic acid (1) is a pheromone secreted by queen honeybee (Apis mellifera) and inhibits reproductive ability of worker bees. Several synthesese have been reported. It was synthesized starting from methyl-3-formylpropionate this time. Methyl 7,7-ethylenedioxy-4-oxooctanoate was prepared by radical addition reaction from (2) and 2-methyl-2-vinyl-1,3-dioxolane and reduced to an ethyelenedioxy carboxylic acid with hydrazine and KOH. This compound was converted to an alcohol by reduction with sodium bis(2-methoxyethoxy)aluminum hydride, followed by oxidation with pyridinium chlorochromate to an acetal aldehyde, which was condensed with malonic acid and (1) was obtained after the hydrolysis with hydrochloric acid. 7 refs., 1 tab.

  9. Emission inventory of air pollutants in East Asia. Anthropogenic emissions of sulfur dioxide in China; Higashi Asia chiiki wo taishotoshita taiki osen busshitsu no haishutsuryo suikei. Chugoku ni okeru io sankabutsu no jin`i kigen haishutsuryo suikei

    Energy Technology Data Exchange (ETDEWEB)

    Higashino, H.; Tonooka, Y.; Yanagisawa, Y. [Research Institute of Innovative Technology for the Earth, Kyoto (Japan); Ikeda, Y. [University of Osaka Prefecture, Osaka (Japan). College of Engineering

    1995-11-10

    Anthropogenic emission of sulfur dioxide (SO2) in China was investigated to establish an emission inventory on air pollutants in East Asia. Major objectives of the study were to establish the emission inventory having the most detailed emission categories and regional resolution comparing with previous works, and being expandable to other air pollutants. Under popularization of desulfurization, conventional methodologies face to limitation of data quality, but in this work the contribution of SO2 removal by recent installation of desulfurization units was also taken into account. China was selected as the first subjective country because China has the largest emission sources of SO2 in East Asia, which contribute a significant portion of acid deposition in Japan. By our estimation total amounts of 21 Tg of SO2 were emitted in China in 1990. About 90% of the SO2 came from coal combustion, and power and heat generation part was responsible for over 30% of the total discharge. The total amounts of the SO2 emission were classified by provinces, major cities, and two grid systems such as 80{times}80 km square and 1{degree}{times}1{degree} resolution. Emissions in Sichian, Shandong and Jiangus provinces were ranked as the top three. Chongqing, Shanghai and Chengdu were selected to be major cities for the SO2 emission. 30 refs., 8 figs., 9 tabs.

  10. Coliquefaction of coal, tar sand bitumen and plastic (interaction among coal, bitumen and plastic); Sekitan/tar sand bitumen/plastic no kyoekika ni okeru kyozon busshitsu no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Yamaguchi, H.; Okuyama, Y.; Matsubara, K. [NKK Corp., Tokyo (Japan); Kamo, T.; Sato, Y. [National Institute for Resources and Environment, Tsukuba (Japan)

    1996-10-28

    For the improvement of economy, coliquefaction of coal, tar sand bitumen and plastic was performed under low hydrogen pressure, to investigate the influence of interaction among these on the liquefaction characteristics. For comparison, coliquefaction was also performed under the hydrogen pressure same as the NEDOL process. In addition, for clarifying its reaction mechanism, coliquefaction of dibenzyl and plastic was performed as a model experiment, to illustrate the distribution of products and composition of oil, and to discuss the interaction between dibenzyl and various plastics, and between various plastics. Under direct coal liquefaction conditions, coprocessing of Tanito Harum coal, Athabasca tar sand and plastic was carried out under low hydrogen pressure with an autoclave. The observed value of oil yield was higher than the calculated value based on the values from separate liquefaction of coal and plastic, which suggested the interaction between coal and the mixed plastic. The results of coliquefaction of coal, tar sand bitumen and plastic could be explained from the obtained oil yield and its composition by the coliquefaction of dibenzyl and plastic. 2 refs., 3 tabs.

  11. Effect of surface active compounds on growth and adhesion of anchorage-dependent animal cells at liquid/liquid interface; Eki/ekikaimen ni okeru fuchaku izonsei dobutsu saibo no zoshoku oyobi fuchaku ni taisuru kaimen kassei busshitsu no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Shiba, Y.; Oshima, T.; Sato, M. [Gunma Univ., Kiryu (Japan). Faculty of Technology

    1998-03-01

    A cell cultivation using a liquid/liquid (culture medium/fluorocarbon) interface has been practiced as a novel culturing method for anchorage-dependent animal cells, and it is known that cell adhesion at the interface is dependent on the contaminants contained in the hydrophobic liquid. Substances effective for the adhesion and growth of cells are investigated using various surfactants. As a result of comparison of ionic and nonionic surfactants, cell adhesion is observed when ionic surfactant is used, indicating the importance of the electric charge of surfactant. Cell growth is better when ionic surfactant is added to fluorocarbon than when surfactant is added to the culture medium. The cell growth using fluorocarbon added with pentafluorobenzoyl chloride and perfluorooctanoyl chloride is similar to that of culturing using polystyrene, and the importance of surfactant addition to fluorocarbon is indicated. 7 refs., 4 figs.

  12. Survey report of FY 1997 on the feasibility of microbial biotechnology for reuse of environmental pollutants; 1997 nendo chosa hokokusho (kankyo osen busshitsu no shigenka no tame no biseibutsu bio technology no riyo kanosei chi kansuru chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    An investigation was conducted with the aim of elucidating the foundations for effective utilization of environmental pollutants or unused resources which are likely to be causal substances of environmental pollutants, as resources, using biotechnology. Composting of agricultural waste, production of microbial mycelium proteins and microbial fermentation materials were suggested as main examples of effective utilization of unused resources by microorganisms. Selection of active microorganisms in the livestock waste, clarification of the mechanism of action and the establishment of treatment conditions are essential to new developments in this field. In the field of marine products industry, it was pointed out that the recycling of waste using microorganisms and enzyme treatment is the most promising approach to the effective utilization of resources. In the field of food industry, applications as the culture media for mushrooms, for enzyme production and for the production of physiologically active materials as well as fuel were clarified. Was also pointed out the significance of studies on the microorganisms and enzymes in resources containing cellulose, hemicellulose and lignin, and the waste from these resources, lignocellulose. Were also proposed the composting of household waste, methane fermentation, and fermentative production of organic acid and hydrogen from waste. Possibility and significance of fermentative production of organic acid from sewage sludge were suggested. 314 refs., 46 figs., 33 tabs.

  13. New ion generation method with SF{sub 6} plasma. Direct ionization of refractory materials; SF{sub 6} purazuma wo mochiita atarashii ion seiseiho. koyuten busshitsu wo chokusetsu ion ka

    Energy Technology Data Exchange (ETDEWEB)

    Okoshi, K.; Saito, Y.; Tajima, S. [Japan Atomic Energy Research Institute, Tokyo (Japan)

    1999-11-01

    For many refractory materials, vapor pressures rise due to fluoridation. For example, a vapor pressure of B is almost zero at room temperature, whereas a vapor pressure of BF{sub 3} is 10{sup 5}Pa or greater. A SF{sub 6} plasma method is capable of directly generating a solid fluoride in an ion source and obtaining its plasma. In order to ionize refractory materials such as niobium, boron, silicon and the like, the present authors have developed a new ion generation method using a stable solid sample and SF{sub 6} gas. Further, the present method was employed to successfully and greatly extending the filament life of the ion source. The plasma method can be used widely not only for a Freeman ion source but also for an ion source using plasma such as electron cyclotron resonance (ECR) ion source. Since the refractory material ions can be stably supplied at a great intensity for a long time, they are expected to be used in corrosion-resistant materials or materials having new functions such as optical switching materials. (NEDO)

  14. Concurrently inhibitory and allelopathic effects of allelochemicals secreted by Myriophyllum spicatum on growth of blue-green algae; Hozakinofusamo ga hoshutsushita areropashi busshitsu no aisorui ni taisuru fukugo sayo oyobi areropashi koka no hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Nakai, S.; Inoue, Y.; Hosomi, M.; Murakami, A. [Tokyo Univ. of Agriculture and Technology, Tokyo (Japan)

    1998-10-10

    This paper describes effects of allelochemicals secreted by Myriophyllum spicatum on growth of blue-green algae. In order to propose an effective growth inhibitory method of blue-green algae with less impact on the ecosystem, biological interaction (allelopathy) between large aquatic plants and algae was investigated. Pyrogallic acid, gallic acid, catechin and ellagic acid secreted by M. spicatum provided growth inhibitory effects of blue-green algae (Microcyctis aeruginosa), individually. Complex interaction and allelopathic contribution of these four polyphenols were evaluated. By comparing the actual effects with the expected values, synergetic growth inhibitory effects were recognized by adding four polyphenols at the same time. Furthermore, growth inhibitory effects were evaluated for actual culture solution of M. spicatum and simulated culture solution made by four polyphenols. As a result, it was found that these four polyphenols relate to allelopathy of M. spicatum. 25 refs., 6 figs., 4 tabs.

  15. Fiscal 1998 research report. Study on the feasibility of microorganism biotechnology for effective use of environmental pollutants. Pt. 2; 1998 nendochosa hokokusho. Kankyo osen busshitsu no shigenka no tame no biseibutsu bio technology riyo kanosei ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Study was made on the feasibility of microorganism biotechnology for effective use of environmental pollutants and unused resources. Microorganisms and microorganism enzymes for decomposing lignocellulose were viewed, and uses of hydrolysis products were summarized. Production of microorganisms applicable to fodder, composting, and production of energy sources (methane, hydrogen, ethanol) were studied. Use of vegetable fiber residues such as beer lees as fungus cultivation medium and conversion to valuable substances were also studied. Microorganisms treatment (MT) of wastes in fats and oils industry was summarized. Effective use of MT of protein waste from marine products was studied. MT of manures with the greatest impact on environment as livestock waste was summarized. The necessity of separate collection of domestic wastes, and composting and methane fermentation of kitchen garbage were reported. The feasibility of MT of plastic wastes, and decomposition of halogenated methane with high toxicity were also studied. (NEDO)

  16. Characteristics of the fluorescent substances in the Yodo River system by three-dimensional excitation emission matrix spectroscopy; Sanjigen reiki/keiko kodoho ni yoru yodogawa suikeichu no keiko busshitsu no tokucho

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Y.; Nakaguchi, Y.; Hiraki, K.; Kudo, M.; Kimura, M.; Nagao, S. [Japan Atomic Energy Research Inst., Tokyo (Japan)

    1998-08-01

    Organic substances in the river water in Yodo River system were analyzed by three-dimensional excitation emission matrix spectroscopy. Fluorescent substances were taken as an index of organic substances. The amount of fluorescent substances varied widely depending on the environment of river basin. It is suggested that the fluorescent substances are composed of organic substances which is not directly originated from biological activity. It is suggested that the fluorescent substances were produced by leaching of river bottom sediment. The fluorescent substances in Yodo River system consists of fulvic acid-like substances and protein. The analysis of fluorescent substances in river water by three-dimensional excitation emission matrix spectroscopy can be useful means for estimation of variation and origin of fluorescent substances. For better understanding of features of fluorescent substances in the surface water into which various kinds of substances enter, it is necessary to determine the exact sampling points based on the consideration of different sources and to make a database of peak positions for identification of fluorescent substances from fluorescence intensity peak. 29 refs., 3 figs., 2 tabs.

  17. Application of resin lining system for countermeasures for preventing leakage from openings in low temperature materials storage; Teion busshitsu chozoji no ekimore oyobi reiki more taisaku toshite no kobunshikei zairyo no tekiyosei

    Energy Technology Data Exchange (ETDEWEB)

    Inada, Y. [Ehime Univ., Ehime (Japan). Faculty of Engineering; Seki, S.

    1996-12-21

    Recently, many of the low temperature materials such as LNG and LPG used as an energy substitution for petroleum were stored in the reclaimed land of the sea side district, however, it is necessary for those storage methods to enlarge sites. Therefore, it was considered to directly store the low temperature materials in openings excavated in the rock mountains. However, countermeasures for leakage of liquid and cold gas from cracks in openings would be an important subject. In this study, as a countermeasure for leakage of liquid and cold gas in the case in which low temperature materials were stored in openings in the rock mountains, the lining of resin materials on the surface of openings was proposed. Characteristics of strength and deformation and values of the thermal physical properties for the resin materials at the low temperature were obtained by experiments. This material was compared with granite supposed as a parent rock, and the thermal property of the resin materials was understood. Next, an analysis was conducted in the case of using the resin materials as a lining, the behavior of the surrounding rocks of the openings and the stability of the lining were investigated. 17 refs., 25 figs., 2 tabs.

  18. Entrapment of water soluble material into biodegradable microcapsule prepared by solvent evaporation; (W/O/W) fukugo emulsion no ekichu kansoho ni yoru seibunkaisei microcapsule eno suiyosei shin busshitsu no naiho tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Kiyoyama, S. [Miyakonojo National University, Miyazaki (Japan); Shiomori, K.; Kawano, Y. [Miyazaki University, Miyazaki (Japan); Hatate, Y. [Kagoshima University, Kagoshima (Japan)

    1998-09-05

    Preparation of biodegradable microcapsule using a poly lactic acid as wall material was performed by (W/O/W) emulsion solvent evaporation method. Fractional entrapment of the core material and the average diameter of the microcapsule are independent of the composition of the inner aqueous phase, such as salt concentration, pH and viscosity. On the other hand, by changing the salt concentration of the outer aqueous phase and the hold up of dispersion phase in the (W/O) emulsion, it is possible to increase the fractional entrapment of the core material with the increase in (W/O/W) emulsion stability and amount of wall material. The entmpment effect is controlled by preparation conditions. 9 refs., 9 figs.

  19. Report on the FY 1999 research survey on the industrial utilization/development of the biofilm formation mechanism and antifouling substances; 1999 nendo bio film keisei kiko oyobi sogai busshitsu no sangyoteki riyo kaihatsu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The paper described the results of the FY 1999 research on the fouling by marine aufwuchs. The survey is aimed at searching the nature world for active substances for biological antifouling. The fouling mechanism in the ocean is as follows. The adsorption of organisms called the conditioning film first occurs on the surface, and next, bacteria and diatom around the surface form biofilm and cover. After that, biological fouling by large aufwuchs occurs. Therefore, the control of biofilm formation was regarded as most important, and with this as a guidepost, the search was conducted. Using biofilm anti-formation activity and periphytic bacteria anti-growth activity as guideposts, some compounds were searched for. Being aimed at Porifera, in particular, new compounds were isolated from it. Since few of other organisms attaches on the surface of sponge, there is a great possibility of Porifera's producing any anti-fouling substances. Further, it is thought that symbiotic microorganisms of sponge (40% of the total weight) produce various biologically active substances. Synthetic phenethyl amine derivatives were also studied. (NEDO)

  20. Synthesis of inorganic mesopore materials and their application to control chemical reactions; Muki meso kukan zairyo no gosei to kagaku hannoba to shite no riyo gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Ohashi, F.; Tomura, S.; Maeda, M.; Inukai, K.; Suzuki, M.; Okazaki, M.; Konishi, Y.; Toriyama, K. [National Industrial Research Institute of Nagoya,Nagoya (Japan)

    2000-10-25

    Materials enabling 'intelligent humidity control' were synthesized by using fumed silica, tetraethylorthotitanate, and a surfactant (alkyltrimethylammonium bromides (C{sub n}H{sub 2n+1}(CH{sub 3}){sub 3}N{sup +} (center dot) Br{sup -}, n=10 - 16) as a liquid-crystal template) under a hydrothermal condition. A homogeneous hexagonal structure of SiO{sub 2}-TiO{sub 2} was confirmed from X-ray diffraction analysis and TEM observation. These products had a high BET surface area of 540-863m{sup 2}/g and auniform pore diameter of 1.5-3nm, both of which were controlled by varyingthe size of the organic template molecule. A sharp increase in water adsorption was observed when the relative pressure (P/Po) increased in the range 0.4 - 0.6. Over this region, the weight % of water came in the range 20 - 50mass%. The water vapor adsorption isotherm was classified as type V in the IUPAC notation, which is characteristic of an unusually large hysteresis. This large hysteresis can be explained from the fact that the contact angle depends on whether water is being adsorbed or desorbed. High durability in their humidity-control ability was confirmed from repeated observation of the isotherm. As a characteristic of the chemical structure upon titanium incorporation, a wider distributionof the Si-O-Si angles in the SiO{sub 4} tetrahedra was indicated from the broad Q{sup 4} {sup 29}Si-MAS/NMR spectra with a small peak shift. To clarify the formation process of these mesoporous materials in the template-synthesis, we accumulated the basic parameters of micelles from the product-yield-detected ESR observations. In addition, as a model of the chemical reaction in the mesoporous material, we observed the reaction dynamics in a spherical micelle with the same technique Based on these preliminary experiments we designed a column reactor packed with a me soporous material to control the liquid phase reaction. (author)

  1. Electrochemical impedance spectroscopy analysis on effect of steel fiber addition on corrosion of steel rod in mortar; Morutaruchu no tekkin no fushoku ni oyobosu suchiru fuaiba tenka no eikyo no denki kagaku inpidansu supekutorosukopi ni yoru kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    Sakashita, S.; Nakayama, T.; Hamasaki, Y.; Sugii, K. [Kobe Steel Ltd., Kobe (Japan); Sugimoto, K. [Tohoku University, Miyagi (Japan). Department of Metallurgy

    1999-11-15

    The effect of steel fiber (SF) addition to concrete on the corrosion behavior of steel reinforcement was studied by immersion corrosion tests in a 3 mass % NaCl solution for 363 day. The tests were conducted on steel rod/mortar specimens with different SF content (0-2 vol %), and corrosion potentials and electrochemical impedance of the specimens were measured during the tests. Corrosion potentials of the specimens were not so changed by the SF content. Electrochemical impedance measured at corrosion potentials was analyzed to get charge transfer resistance (R{sub ct}) using an equivalent electrical circuit with the R{sub ct}, Warburg impedance and a constant-phase element. The corrosion rate of steel rod in mortar estimated from the reciprocal of the R{sub ct} decreased with increasing of SF content in mortar, and correlated well with the rust area of steel rod measured after immersion corrosion tests. This shows that the electrochemical impedance measurement is the useful diagnosis method of corrosion of steel in concrete. The corrosion inhibition of steel rod in mortar by the SF addition was thought to be attributed to the consumption of dissolved oxygen by the corrosion of SF in mortar. (author)

  2. Occurrence and purification on microcystis species. Chemistry and analysis method for toxic peptides produced by cyanobacteria; Aoko/sono hassei to joka taisaku. Aoko ga seisansuru yudoku pepuchido no kagaku to bunsekiho

    Energy Technology Data Exchange (ETDEWEB)

    Harada, K. [Meijo Univ., Nagoya (Japan). Faculty of Pharmaceutical Science; Tsuji, K.; Kondo, F.

    1994-09-10

    The phenomena on a cacogenesis of the blue green algae in the lakes subjected to an eutrophication occur frequently at every places in the world, and therefore they become a serious environmental problem. Especially it is known that a part of the blue green algae produces a toxic compounds, and consequently the issues of this kind is made further complicated. One of the blue green algae occurring universally at every place in the world is the microcystis genus, and moreover it often produces the microcystin group which is a peptidic hepatic toxin. Because the microcystin was a strong hepatic toxin, the toxicity testes using the mice have been exclusively executed. However, because the constituents reached up to 50 items, and in addition a toxicity of each element is not necessarily same, it has been considered that a chemical analytical method to perform an accurate separation and a sure detection have been necessary. A high-performance liquid chromatography (HPLC) is currently the most much used for an analysis of the microcystin. In order to detect the microcystin, the ultraviolet rays (UV) near 240 nm being its absorption maximum are being frequently used. However, a toxicity manifestation mechanism of the microcystin and so forth has not yet been elucidated. 24 refs., 2 figs., 2 tabs.

  3. Overview of FY1997 human media technology R and D; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu seido Shin energy Sangyo Gijutsu sogo Kaihatsu Kiko itaku jigyo. Human media no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper reports a summary of results in fiscal 1997 of research and development of human media technology. Fiscal 1997 launched design and trial fabrication of the following items: interface to improve efficiency and safety of plant operators, accommodation of multimedia contents to aid Kansei design, city development design aiding technologies using contents retrieval and presentation technologies and virtual reality, and empirical evaluation technologies for safety, comfort and convenience. Specific study assignments were extracted on a virtual media technology, a Kansei media technology and a knowledge media technology being three elementary technologies for human media to make clear the research and development approaches to be taken in the coming fiscal years. In addition, a human media technology committee, a research and development working group, and an investigation working group were established. Also launched were investigations on research trends in the human media technology, and investigative researches on contacts of information needs in industries with human media. 59 refs., 114 figs., 24 tabs.

  4. The Reformation of Elementary School Science Education in Postwar Japan and the Translation and Publication of "Science for the Elementary School Teacher" and "Science in Childhood Education" Written by G. S. Craig

    OpenAIRE

    柴, 一実

    2000-01-01

    G. S. Craig's writings were most popular in the 1940s in America and he described the theory of the democratic science education in his books. In order to make use of reforming the elementary school science education in Occupied Japan, Craig's books were translated into Japanese. GHQ/SCAP carried out it in accordance with the CIE Translation Program as a part of the Cultural Exchange Programs. His versions, "Kagaku no kyoshitsu" (1949) and "Kagaku to kodomo no seikatsu" (1949), resulted in be...

  5. Diffusion of matter in the wall turbulent flow. 5th Report. Local similarity of the fluctuating concentration field of the plume from a wall point source in a turbulent pipe flow; Hekimen sendanryuchu no busshitsu kakusan no kenkyu. 5. Enkannai hekimen tengen kakusan no hendo nodoba no kyokusho sojisei

    Energy Technology Data Exchange (ETDEWEB)

    Miwa, M.; Sakai, Y.; Nakamura, I. [Nagoya University, Nagoya (Japan)

    1997-05-25

    In this report. we extend the similarity argument previously used to the mean square concentration fluctuation equation on the symmetrical plane of the wall point source plume in a turbulent pipe flow to find the similar solution for the mean square concentration fluctuation distribution. The main assumptions are the Lagrangean similar hypothesis and an appropriate eddy diffusivity distribution to the triple correlation term and the mixing length theory. It is found that the distribution of the similar solution shows good agreement with experimental data in a pipe flow. In the case of a wall point source in a turbulent boundary layer on a flat plate, the same argument is appliciable, and the similar solution obtained shows good agreement with the experimental data. And the budget of the fluctuating concentration intensity is investigated on the basis of the similar solution and the mean square concentration fluctuation equation. 16 refs., 8 figs.

  6. Fiscal 1998 industrial science and technology R and D theme (University coordination type). Research report on R and D of technologies for creating new bioaffinity molecules using submicron beads; 1998 nendo biryushi riyogata seitai ketsugo busshitsu nado sosei gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This report summarizes the fiscal 1998 result on the entrusted research 'R and D of technologies for creating new bioaffinity molecules using submicron beads' based on 'Industrial science and technology R and D system.' As for development of technologies for analyzing chemical- biomolecule complexes using submicron affinity beads, for molecule design of DNA to be connected with cisplatin, telomere DNA was employed as a target DNA of cisplatin, and cisplatin-modified DNA (Pt-DNA) was synthesized. Reaction condition for Pt-DNA connected beads was established, and affinity beads with Pt-DNA were prepared. As for development of organic receptor refining technology, proteins bound to cisplatin-DNA were preliminarily analyzed, showing that the Pt-DNA is a proper target chemical substance. It is the first evidence that certain proteins recognize cisplatin-damaged telomere DNA. In addition, introduction of the equipment for developing analysis technology of binding domains, development of technology to create organic receptors with new functions, and general research on the titled technologies were carried out. (NEDO)

  7. Report on achievements in fiscal 1999 on the project for research and development of an intellectual base creating and utilizing technology. Development of a screening test method with high accuracy for internal secretion disturbing substances; 1999 nendo chiteki kiban sosei riyo gijutsu kenkyu kaihatsu. Naibunpi kakuran busshitsu no koseido screening shiken hoho no kaihatsu oyobi data kiban seibi

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This paper describes the achievements in fiscal 1999 on developing a screening test method with high accuracy for internal secretion disturbing substances. Development was made in cooperation with the OECD on the screening method that uses as a parameter whether a chemical substance has a hormone-like activity. For the womb breeding assay method to evaluate a feminine hormone-like activity, a reproducibility and comparison test was performed on womb breeding in immature rats administered with ethinylestradiol, the administration routes, and animals used (young and weak rats, and rats whose ovaries have been extracted). In order to evaluate a masculine hormone-like activity, the basic data were collected to develop the Hershberger method, and participation was made in the OECD verification tests. Discussions were given on comparison on castrated and non-castrated rats when 17 {alpha}-methyltestosterone was administered, the administration period of time and reproducibility when immature rats were used. The Hershberger method reactivity was discussed on rats relative to estrogen. In a toxicity test using 28-day repetitive administration, bisphenol A gave impacts on the kidney, the stomach and intestine tubes. (NEDO)

  8. FY 2000 report on the R and D of the particulate utilization type creation technology of biological connective substances. Survey of the technical trend overseas; 2000 nendo biryushi riyogata seitai ketsugo busshitsu nado sosei gijutsu no kenkyu kaihatsu seika hokokusho. Kaigai gijutsu doko chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The paper summarized the reports on the results of Japanese engineers' participating in the related scientific meetings held overseas as a survey report on the trend of the overseas technology. The scientific meetings they participated in were: 1) Impact of Genomics on Medicine and Pharmacogenomics Europe (Amsterdam; May 15-26, 2000), 2) Drug Discovery Technology 2000 (Boston; August 10-20, 2000), 3) Biotechnology 2000 (Berlin; September 3-12, 2000), 4) PacificChem 2000 (Hawaii; December 14-21, 2000), 5) 4th Winter Conference on Medicinal and Bioorganic Chemistry (Seattle; January 27 - February 4, 2001). Impact of Genomics on Medicine was composed of the following five fields: microarrays, proteomics, functional genomics and target validation, genetic variation technology, and applications of SNP analysis (joint session). Pharmacogenomics Europe was composed of the following four fields: applications of SNP analysis (joint session), SNP assays, targets and compounds, and clinical applications. (NEDO)

  9. Report on achievements in fiscal 1999 on research and development of the technology to create biological bonding substances utilizing particulates under the industrial and scientific technology research and development theme [university collaborated type]. Research and development of the technology to create biological bonding substances utilizing particulates; 1999 nendo biryushi riyogata seitai ketsugo busshitsu nado sosei gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This paper describes the achievements in fiscal 1999 on development of the technology to create biological bonding substances utilizing particulates. In fixing ligands onto particulates, it is necessary that various compounds be fixed with their receptor bonding specificity maintained. Therefore, carboxylic acid, thiol and bromoacetyl groups were introduced into the particulates. Capping them by using methoxyacetyl was found capable of suppressing non-specific adsorption. Opioid compounds were synthesized for their fixation onto particulates for selection and separation. Carrying particulate bonding precursors in latex beads was realized. Synthesis will continue on opiod compounds in which amide groups are introduced into different positions to provide the particulate carrying ligands with diversity. Biological receptors for different compounds were obtained and refined by using compound fixing particulates. Refinement and acquisition were possible on FK506 bonded protein in a short time from cell extraction liquid by using the fixing particulates for the FK506 bonded protein. The paper also describes analysis of bonded domains, and position-specific fixation of the biological receptors. (NEDO)

  10. FY 2000 Industrial science and technology research and development themes - cooperative project with academic circles. Report on the results of research and development of technologies for creating new bioaffinity molecules using submicron beads (Development of technologies for rational use of energy); 2000 nendo biryushi riyogata seitai ketsugo busshitsu nado sosei gijutsu no kenkyu kaihatsu seika hokokusho. Energy shiyo gorika gijutsu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the FY 2000 results of the research and development for creating new bioaffinity molecules using submicron beads. The program for development of technology for analyzing chemical-biomolecule complexes using submicron affinity beads has developed a detachable linker which allows the complex, composed of ligand on the affinity latex particle surfaces and receptor bound thereto, to be detached directly from the particles, and also developed the prototype of magnetite-containing polymer particles with a diameter of submicron order, which facilitate recovery of the affinity latex. The program for development of technology to create chemical substances with new functions has successfully constructed the focused library composed of 400 compounds based on the split and pool method for FR225659 as a glucose modulator, chosen as the target material. It also has established the method of synthesizing opioid alkaloid as the target compound on the solid phase, and synthesized 39 opioid compounds with condensed indol rings, having diverse of several substituents. (NEDO)

  11. FY 2000 Industrial science and technology research and development themes - cooperative project with academic circles. Report on the results of research and development for creating new bioaffinity molecules using submicron beads (Research and development for creating new bioaffinity molecules using submicron beads); 2000 nendo biryushi riyogata seitai ketsugo busshitsu nado sosei gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the FY 2000 results of the research and development of technologies for creating new bioaffinity molecules using submicron beads, including those for organic receptor analysis and refining. The program for development and research of fixation technology develops immobilizing reaction and latex particle having cleavable linker, and synthesize small molecules for the identification of target receptors. The program for development of organic receptor refining technology directly refines cisplatin-telomere binding proteins from crude nuclear extracts of HeLa, and analyzes them; analyzes the functions of Ref-1 purified from Jurkat cell nuclear extracts as the binding protein for drug E3330 which specifically controls the transcriptive factor NF-{kappa}B; and studies LK6A having an MLR inhibiting activity, promoters for production of Alendronate, Taxol and leptin, D91-6092 as a promising anti-cancer agent, and antirheumatic, antiallergic, antitumor agents and FK506 as immunosuppressant agent. (NEDO)

  12. FY 1998 results of the intellectual basement project using functions of private companies (venture promotion type basement creation R and D project). Development of endocrine disrupter testing method and development of environmental assessment method; 1998 nendo naibunpi kakuran busshitsu ni taisuru shiken hoho kaihatsu oyobi eikyo hyoka shuho kaihatsu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of assessing the risk in relation to endocrine disrupting chemicals, the following were conducted: development of testing/assessment method for endocrine disrupting chemicals, survey of the actual exposure assessment, development of measuring method for the concentration in the environment. In the development of the testing method, the following were carried out: development of a high-throughput screening method for evaluating endocrine disrupting chemicals; as screening testing method using mammals, uterotrophic assay, Hershberger assay using castrated male rats, thyroid hormone assay in pubertal rats, enhanced OECD 407 test guideline for 28-day toxicity test; study on yeast two-hybrid assay for endocrine disrupter; sex-reversal assay for suspected endocrine disrupting chemicals using S-rR strain medaka. In the development of exposure assessment method, estrogenic potency of individual nonylphenol congeners isolated from technical mixtures; determination of endocrine disrupters and related chemicals from industry and nature origin in river water and sediment; research for the flow of industrial origin chemicals; reconstruction of pollution history of chemicals using sediment cores. (NEDO)

  13. International seminar in fiscal 1998 on the development and promotion of global environment-related industrial technologies. Report on International Workshops on CO{sub 2} Cycling and Metabolism in Coral Reef; 1998 nendo chikyu sangyo gijutsu kaihatsu suishin jigyo. 'Sangosho ni okeru busshitsu ido to tanso junkan' kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For the study of CO{sub 2} absorption and fixation in the marine ecosystem, studies of coral reefs by RITE (Research Institute of Innovative Technology for the Earth) were subjected to discussion at the above-named workshops. It is after the elapse of a long geological time on the earth that CO2 in the atmosphere has arrived at the current level of concentration thanks to fixation and calcification by living organisms and to dissolution into the seawater. In the formation of CaCO{sub 3} that constitutes the coral skeleton, 1 mol Ca combines with 2 mol bicarbonates for the production of 1 mol CaCO{sub 3} and 1 mol CO{sub 2}. The reaction may suggests a consequential increase of CO2 in the atmosphere but such CO{sub 2} is in reality consumed by being converted into organic substances in a photosynthetic process performed by symbiotic algae. Calculation was made for the whole of Bora Bay, Miyakojima Island, and the result was that 700kg-C/day comes to be stored in the form of organic matters in the community of coral reef organisms. In a coral reef, even when it emits CO2 into the atmosphere, there is organic matter production which exceeds the lost CO{sub 2}. Coral reefs fix carbon out of the seawater at the rate of 0.42Gt-C/year, which is the aggregate of 0.3Gt organic matters and 0.12Gt CaCO{sub 3}. (NEDO)

  14. Fiscal 1997 R and D project on industrial science and technology under a consignment from NEDO. R and D of the ultimate manipulation technology of atoms and molecules; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo gijutsu Sogo Kaihatsu Kiko itaku. Genshi bunshi kyokugen sosa gijutsu no kenkyu kaihatsu seika hokokusho (genshi bunshi kyokugen sosa gijutsu no kenkyu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper describes R and D of the ultimate manipulation technology of atoms and molecules (atom technology). The R and D aims at establishment of observation/manipulation technology of atoms and molecules as common basic technology in various industrial fields such as new material, electronics, bio-technology and chemistry. The R and D thus aims at establishment of observation/manipulation of solid surfaces and DNA organic molecules, formation of fine structures of atomic surface arrangement, and calculation/ simulation for predicting a reaction theorem of atom and molecule surfaces. In fiscal 1997, research was made on improvement and development of computer simulation environment, and description of an excited state of electrons by Green function. Establishment of a construction method and computation code is under investigation for pseudo- potential dependent on excitation energy. Survey was made on research trends of the atom technology by visiting overseas academic societies and institutions. International Symposium on Atom Technology was also held in Tokyo in Nov. 1997

  15. Fiscal 1998 research report on the R and D on industrial science and technology for creating new industries. R and D on intelligent material and structure systems (Development of practical technology for rational use of energy); 1998 nendo shinki sangyo soshutsugata sangyo kagaku gijutsu kenkyu kaihatsu seika hokokusho. Chiteki zairyo kozo system no kenkyu kaihatsu (energy shiyo gorika kankei gijutsu jitsuyoka kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    As a part of development of intelligent material/structure systems, study was made on practical technology for rational use of energy. For resource saving and energy saving (smartening) for large and complex machines and structure systems, light-weight long-life materials/structures are indispensable. Study was thus made on the basic technology of material/structure systems equipped with realtime defect detection function, structural integrity diagnosis function and control function of noise and vibration through information processing and control by integrating composite material/structure and fiber or film sensor material/device. For development of smartening technology, sensing technology was studied to detect the interior structure of composite material/structure compacts. The basic fabrication technology of ceramic actuator materials/devices, and shape memory alloy system actuators were put into development. Smooth connection and cooperation among groups were promoted through the technical committee and research on domestic and overseas trends for forming common knowledge. (NEDO)

  16. Fiscal 1997 report on the R and D result of industrial science and technology. R and D on super metal (R and D on innovative raw metal materials); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku seika hokokusho. Super metal no gijutsu kaihatsu (kakushinteki kinzoku sokei zairyo no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Study was made on the applicability of mechanical milling (MM) and mechanical alloying (MA) to Fe system alloys. Metastable austenitic stainless steels such as SUS316L and SUS304L form {alpha} phases by strain induced transformation due to MM, and are subjected to further plastic deformation. Nano-size fine structure was obtained through inverse transformation into austenite({gamma}) by heat treatment or high-temperature sintering of MM powder. Fine microduplex structure of 620nm in average crystal grain size was obtained for SUS316L. This material showed nearly 3.3 times higher 0.2% tensile proof stress, nearly 1.8 times higher tensile strength, and 35% higher elongation than conventional ingot steels. Solid solution powder of 12Cr-Mo-W ferritic steel was sintered by hot isostatic pressing (HIP) under low- temperature and ultrahigh-pressure conditions of 650degC and 588MPa. The as-HIP`ed sample and sample annealed at 800degC showed average {alpha} grain sizes of 33 and 50nm, respectively, and a strength twice as high as that of 12Cr steel. 97 refs., 60 figs., 18 tabs.

  17. Chemical and geochemical study on the hot spring. Affecting factor of pH and the origin of chemical constituents in Dogo spring; Onsen no chikyu kagakuteki kosatsu. Dogo onsen no pH chi kettei inshi to kagaku seibun no kigen ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Maki, T.; Ishimaru, T.; Tagashira, K.; Ono, C. [Ehime Prefectural Inst. of Public Health, Ehime (Japan)

    1994-12-31

    Dogo Spring is a non-volcanic hot spring (not a spring that gushes up in association with live volcanic activities) and located about 10 kilometers away from the coast line. Therefore, the spring water quality is not affected by these geological environments, allowing the interactions with the mother rock to be identified relatively easily. In order to investigate the relationship between chemical constituents in the hot spring and the mother rock, a leaching test was carried out on boring-cores and representative rocks existing in Ehime Prefecture. Considerations were given on the factors in the mother rock affecting the hot spring constituents, the high pH value in Dogo Spring, and the origin of the constituents. The result indicated that pH value in the leaching solution from the boring-cores taken from Dogo Spring is higher than that in the leaching solution from representative rocks in Ehime Prefecture; it suggested that the high pH value in Dogo Spring is correlated to the gushing mother rock (Ryoke granite); it also suggested that the Dogo Spring water has about the same concentration as in the dissolved constituents in the leaching solution from the Dogo Spring boring-cores, and the dissolved constituents in the Dogo Spring water is closely related with the composing mother rock (Ryoke granite). 12 refs., 9 figs., 6 tabs.

  18. Fiscal 1997 report on the results of the R and D of industrial scientific technology. R and D of synergistic ceramics (R and D of corrosion prevention technology for the petroleum production system); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu seika hokokusho. Synergy ceramics no kenkyu kaihatsu (sekiyu seisan system fushoku boshi gijutsu kenkyu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    To heighten durability and safety of materials/parts for undersea oil drilling, the development of ceramic base materials was made by developing function harmony type process technology which harmonizes on a high grade contrary characteristics and various functions. The paper summed up the fiscal 1997 results. In the design of system formation, computational simulation technology was developed to the composite process and the diploid system. The development of multifunction simultaneous manifestation materials was trially made by the higher nano structure process. A study was made of control of microstructures of porous materials and matrix filling by the gas phase precipitation control. Proposed were selective control of grain growth from species crystals and the columnar particle orientation laminated structure of simultaneous manifestation of strength and toughness. By composite precipitation reaction control, studied were simultaneous dispersion of whisker and increase in density of matrixes, and harmonization with long fibers. Silicon nitride was trially made with low lubrication/friction coefficients and high strength. A simulation method for crack progress behavior evaluation was developed using a testing notched specimen heterogeneous microstructures. Analyses were made of brittle fracture mechanics and reliability evaluation. 273 refs., 344 figs., 29 tabs.

  19. Fiscal 1996 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of technologies to invent original high-functional materials; 1996 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Technologies were described of creating original high-functional materials. The paper presented the following two as fields of technology on which importance is to be placed for the future R and D from technological and socioeconomic points of view. In the field of new materials of living organism imitation type, remarkably high-performance/high-functional new materials are invented by imitating the precise function manifestation mechanism of the ultimate living organism in which a great variety of matters are in harmony with each other and manifest complicated and high-level functions. In the field of structural control/synthesis process technology, the paper is aimed at manifestation of newer and higher functions/performance and innovation of the synthesis process, and also at developing technology to precisely control structure and process of materials including surface and interface in correspondence with atomic/molecular to macro levels. Up to the present, conducted were an examination of autonomous response materials (the subtheme is a R and D of polymer/composite multi-stimuli-responsive materials) and a R and D of precise polymerization (control) polymer materials. 239 refs., 129 figs., 49 tabs.

  20. FY 1996 R/D project of industrial and scientific technologies contracted with NEDO. Report on R/D of organosilicon polymers; 1996 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Keisokei kobunshi zairyo no kenkyu kaihatsu (Keisokei kobunshi zairyo no kenkyu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    Organosilicon polymers are highly innovative materials having high performance and novel functions, and they can be widely applied. The purpose of this study is to establish fundamental techniques for molecular design, synthesis, material processing and evaluation of organosilicon polymers having excellent electro- and photo-functions, and advanced heat-proof, fire-proof and mechanical properties. This R/D includes (1) R/D of electrical conducting materials by organosilicon polymers, (2) R/D of novel organosilicon polymers applicable to direct lithography, (3) R/D of new silicon-based polymer materials with electro-luminous function, and (4) R/D of silicon-based polymers for new photoconductive materials. In (1), synthesis of highly conjugated polymers is investigated. In (2), novel organosilicon polymeric materials have been developed, which would be applicable to direct lithography of electronic circuits, and which could contribute to simplification of the circuit formation process. In (3), the research aims at development of new silicon-based polymer materials with luminescent function which can be applied to the large size electro-luminescent display devices. In (4), new materials with visible light absorption have been synthesized through the molecular design and synthesis. The photo-carrier generation was observed. 107 refs., 86 figs., 23 tabs.

  1. Fiscal 1997 R and D project on industrial science technology under consignment from NEDO. Report on the R and D of nonlinear optoelectronic materials; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Hisenkei hikari denshi zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    As to the development of organic base materials, the paper is going ahead with an evaluation, higher performance and further use as materials of basic optical properties of quirale nonlinear materials and organic conjugate base materials which are promising among organic low molecular materials. As the development of orientation control crystal growth technology, grooves for orientation control were formed on the surface of the lead glass substrate, from which thin film single crystals were obtained. The nonlinear response was studied of the glass where semiconducting fine particles dispersed in matrix glass. Glass scattering base prototype materials were selected by the sol-gel method and ultra-low melting-point glass method. The glass dispersion base materials by the very fast cooling method was also studied. For the purpose of realizing a high speed switching characteristic, a processing technology was developed of ultra fine particle dispersing polymer light waveguide. As to the technology for super lattice, the optimum nonlinear performance materials were selected mainly with the optimum complex super lattice base. Moreover, the three-dimensional super structuring technology was constructed to improve nonlinear optical characteristics. The comprehensive investigational study was conducted for effective promotion of the research development. 177 refs., 260 figs., 27 tabs.

  2. Industrial science and technology research and development business for fiscal 1998. Research and development achievement report on glycoconjugate production and utilization technologies (Development of technologies of glycoconjugate-aided CO{sub 2} fixation and utilization); 1998 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo. Fukugo toshitsu seisan riyo gijutsu no kenkyu kaihatsu seika hokokusho (fukugo toshitsu oyo nisanka tanso koteika yuko riyo gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Enzymatic and chemical methods were combined and methods were developed for synthesizing mucin type sugar chains and glycopeptides. The influence of sugar chain positions and structures on glycoconjugate stereo structures and physiological activities was analyzed, and glycopeptide structural activities and glycoconjugate remodelling were studied. To create an industrial advantage in a glycoprotein production system by use of zooblasts, sugar chain structure control through sugar transfase occurrence control was studied. For the production of man-adaptive sugar chains using yeast, new yeast variations were subjected to molecular breeding, and tested for the resultant improvement on productivity. Sugar chain marking and refining techniques and various responding mechanisms on the solid surface were elucidated, which enabled structure analyses using sugar chain recognition molecules such as lectins and antibodies. A database on interactions between sugar chains and sugar chain recognition molecules was constructed using the said findings. An analyzing program was also formulated tentatively. This paper also covers general surveys and studies on technologies of producing and utilizing glycoconjugates. (NEDO)

  3. Research report of FY 1997 on the industrial science and technology development. Technology development of super-metal (technology development of nano-amorphous structural control materials); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku seika hokokusho. Super metal no gijutsu kaihatsu (nano-amorphous kozo seigyo zairyo no gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Research and development of the innovative metals have been conducted, by which the weight reduction of members can be done by drastically improving the strength compared with conventional metals. For the high-rate cluster deposition and super plastic forming technologies, research and development of aluminum-based light-weight materials have been conducted, which provides excellent strength, toughness, and super plastic formability at room temperature. For the high-density energy utilization and control technology (amorphous-A), super-metals have been investigated as high dew point and corrosion resistance materials used for waste incinerators operated under the very severe conditions. These are expected to be applied to the apparatuses and equipment due to their excellent properties. For the controlled cooling technology (amorphous-B), super-metals with excellent soft magnetic characteristics and degree of shape freedom have been investigated for high performance and high efficiency devices including electric/electronic/communication devices, power transmission devices, and various industrial devices and parts. These are expected to contribute to the creation of new markets and the improvement of international competitive force. 123 refs., 160 figs., 33 tabs.

  4. FY 1997 R/D project of industrial and scientific technologies contracted with NEDO. Report on R/D of organosilicon polymers; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Keisokei kobunshi zairyo no kenkyu kaihatsu (keisokei kobunshi zairyo no kenkyu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The purpose of this study is to establish fundamental techniques for molecular design, synthesis, material processing and evaluation of organosilicon polymers having excellent electro- and photo-functions, and advanced heat-proof, fire-proof and mechanical properties. This R/D includes (1) R/D of electrical conducting materials by organosilicon polymers, (2) R/D of novel organosilicon polymers applicable to direct lithography, (3) R/D of new silicon-based polymer materials with electro-luminous function, and (4) R/D of silicon-based polymers for new photoconductive materials. In (1), synthesis method of regular polymers with a 3-D structure was developed. Non-volatile dopants were developed, and structures of polymer-dopant composites could be controlled. In (2), precise control of conductivity was examined. Material processing and evaluation techniques were also examined through stabilization of polysilane thin films, optimization of pattern forming conditions, and precision of patterns. In (3), new silicon-based polymers have been synthesized. In (4), two kinds of polymers have been synthesized for development of materials with high photo-carrier generation efficiency and high mobility. 72 refs., 71 figs., 22 tabs.

  5. Fiscal 1997 R and D project on industrial science and technology under a consignment form NEDO. R and D of the technology of accelerated formation of bio-functions; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Kasokugata seibutsu kino kochiku gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    As a part of the study on accelerated formation of bio- functions, analysis technology of experimental systems for in vitro evolution of protein molecules was studied. For the analysis, recognition of a fitness landscape is indispensable. Improvement of adaptive walk is possible through its analysis in an ordered space based on features of the landscape. By the last fiscal year, the knowledge of the fitness (heat-stability) landscape was obtained in the experimental system of PEP (prolyl endopeptidase) in which an adaptive walk mechanism was found to function effectively (mutated protein with a heat-stability effectively improved by adaptive walk was obtained). To obtain more general fitness landscape information, landscapes of various proteins to a fitness should be examined, and the effectiveness of approaches to efficient adaptive walk on the fitness other than a heat-stability should be clarified. The second experimental system using LOD (lactate oxidase) was thus constructed to examine the heat-stability landscape. In addition, the system of in vitro molecular evolution of proteinase inhibitor (Cystatin B) was constructed. 3 refs., 3 figs., 2 tabs.

  6. Fiscal 1998 R and D project on global environmental industrial technology. R and D result report on environment- friendly production technology (advanced chemical synthesis reactor); 1998 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo. Kankyo chowagata seisan gijutsu (kokino kagaku gosei bio reactor) kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For high-efficiency production of substances by bioreactor, study was made on a bio-control mechanism as its elementary technology. On the study of breeding technology by expression control, the structure design of a control region and development of new expression vectors had been finished, and study was made on breeding of high-efficiency recombinant production cells by using candidate expression vectors. On the study of breeding technology by multi-stage enzyme reaction control, the enzyme gene of a system synthesizing cysteine from glycerol was searched, and hydroxypyruvaldehyde hydrogenase gene was isolated as substance production model. Cysteine production Escherichia coli combined with serineacetyl transferase gene was also prepared. In addition, study started on cloning of hydroxyacetone oxidase gene. On development of reactor system technology, for conversion of serine to cysteine, study was made on optimization of a reaction condition by theory of enzyme reaction rate. (NEDO)

  7. Fiscal 1998 research report on the R and D on industrial science and technology for creating new industries. R and D on intelligent material and structure systems; 1998 nendo shinki sangyo soshutsugata sangyo kagaku gijutsu kenkyu kaihatsu seika hokokusho. Chiteki zairyo kozo system no kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This project aims at development of the basic technology of the structure system which has the same intelligent functions as living body such as perception, decision and response through information processing/control (brain) by integrating advanced complex material structure (skeleton), fiber or film sensor material/device (nerve) and actuator material/device (muscle). This report describes the fiscal 1998 research result. On health monitoring technology, study was made on development of high-performance sensors, and a damage detection and self-diagnosis system for structural integrity. On active adaptive structure technology, study was made on improvement of a quasi-elastic behavior model for shape memory alloys, and a candidate actuator for noise and vibration reduction. On actuator materials and devices, study was made on the relation between electronic properties and dielectric/electro-strictive characteristics of the latest advanced ceramic materials available. Creation of silent smart structure was also clarified. Smooth connection and cooperation among groups were promoted through the technical committee and research on domestic and overseas trends. (NEDO)

  8. Report on the surveys in fiscal 1999 on foundations for establishing industrial technology strategies. Technological strategies by fields (Field of nurturing human resources in chemical technologies); 1999 nendo sangyo gijutsu senryaku sakutei kiban chosa hokokusho. Bun'yabetsu senryaku (kagaku gijutsusha jinzai ikusei bun'ya)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This paper describes nurturing of human resources in chemical technologies, as part of the surveys in fiscal 1999 on foundations for establishing industrial technology strategies. In association with the progress in scientific technologies, convenience of living has been enhanced exceptionally. On the other hand, however, problems lie in a heap, such as in global environment, energy, resources and population. Safety of chemical substances is questioned. Industrial world is greeted with the times of bubble collapse, information orientation, internationalization, and great competition. Chemical industries are aiming at differentiation and power strengthening, but demanded of conversion into making more independent developments. A large number of problems difficult of solving must be overcome by progress of scientific technologies. The core of the progress is in innovation and creation of new chemical technologies. Since what shoulders the requirements is people, nurturing chemical engineers is the urgent and important issue. Chemical engineers are demanded of having knowledge and experience in environment and safety, and ethics to accomplish social responsibilities, not to speak of their specialty technologies. Human resource nurturing must be carried out effectively under collaboration and cooperation of universities and corporations, rather than they do it independently. This paper describes problems and solution ideas, such as institutions and programs, to achieve the goal. (NEDO)

  9. Research and development of utilization technology of solar thermal system for industrial and other use. Research and development of key technology (energy conversion on technology using chemical reactions); Sangyoyo nado solar system jitsuyoka gijutsu kaihatsu. Yoso gijutsu no kenkyu (kagaku energy henkan gijutsu no kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    Takita, M. [New Energy and Industrial Technology Development Organization, Tokyo (Japan)

    1994-12-01

    Described herein are the results of the FY1994 research program for energy conversion technology using chemical reactions by the aid of solar energy. The demonstration runs were conducted by a bench-scale unit, which was operated stably for 100h, to produce promising results. The catalyst exhibits stable performance, without showing a sign of deactivation. It is found that the heat pump system works well, without being interfered with accumulated by-products. A heat of approximately 2,100kcal/h is recovered. It is confirmed that steam of 150{degree}C and 200{degree}C is generated from hot water of 80{degree}C and 95{degree}C, respectively. The bench-scale runs show a thermal efficiency of around 10%, which is lower than the target level. However, the runs with hydrogen-occluding alloy attain a process thermal efficiency of 30%. The system in which solar collector and chemical heat pump units are combined is evaluated with respect to its economic efficiency and operability for its eventual commercialization. 6 figs., 2 tabs.

  10. Fiscal 1996 report on the R and D result of industrial science and technology. R and D synergy ceramics (R and D on synergy ceramics); 1996 nendo sangyo kagaku gijutsu kenkyu kaihatsu seika hokokusho. Synergy ceramics no kenkyu kaihatsu (synergy ceramics no kenkyu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper summarizes the general survey mainly conducted by FCRA (Fine Ceramics Research Association) in fiscal 1996, and the joint research results with some universities, from some R and D on synergy ceramics. Silicon nitride based ceramics expressed the same high thermal conductivity as metal by seed crystal addition, grain growth control and orientation control of sheet lamination. For its practical use, study was made on control factors of material, formation and sintering. Ca2Y2Si2O9 single crystal was prepared by float-zone method to determine its crystal structure. No volume change due to high-temperature phase transition as thermal expansion was found. In carbothermal reduction- nitridation of SiO2, addition of Si3N4 seed powder increased a reaction rate and formed uniform particles with an isotropic shape. An average particle size was dependent on the size and number of fine particles in seed powder. Addition of both Si3N4 and Fe compound could change a particle shape from a spherical grain to an elongated grain. A spherical Fe-Si metal grain was found on the tip of an elongated grain. 66 refs., 73 figs., 13 tabs.

  11. Report on the results of research and development under a consignment from NEDO on deca-nano quantum integrating transistor substrate technologies; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Deca-nano ryoshi shusekika soshi kiban gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Researches have been conducted on deca-nano quantum integrating transistor substrate technologies, and developments were made on a three-dimensional device simulator which can be used in deca-nano domains, and a circuit simulator to have quantifying function transistors coexist with silicon semiconductor integrated circuits. The researches were intended to develop a simulator capable of analyzing properties of very small silicon and compound semiconductor devices in deca-nano domains. The researches discussed the applicability of conventional simulators, calculated quantum levels in a three-dimensional hetero structure, and resulted in development of an electron wave propagation simulator in optional two-dimensional shapes, a quantum Monte Carlo simulator, and a three-dimensional semiconductor device simulator with quantum correction. On the other hand, in order to estimate characteristics of a hybrid circuit in which single electron transistors coexist with conventional transistors such as CMOS transistors, a single electron hybrid circuit simulator was developed. The development indicated that a CMOS-SET fused memory is promising as a future LSI memory. 22 refs., 116 figs., 3 tabs.

  12. Fiscal 1996 report on the results of the R and D under a consignment from NEDO of the environment friendly type production technology. High-functional chemical synthesis bioreactor (for public); 1996 nendo chikyu kankyo sangyo gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Kankyo chowagata seisan gijutsu (kokino kagaku gosei bioreactor) kenkyu kaihatsu seika hokokusho (kokaiyo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the purpose of developing production technology of chemical substances which are resource conservative, energy saving and less in environmental loads, a R and D was conducted of a high-functional chemical synthesis bioreactor. The paper reported the results of fiscal 1996. As for proliferation control breeding technology, relating to the switch control technology of proliferation related genes by regulatory factors, the effectiveness on an incubator level was demonstrated, and at the same time improvement of reactor performance in using this technology was studied on paper. As to the manifestation control breeding technology, the actual design of the development of manifestation promotion technology by bent DNA, etc. was proceeded with, and at the same time the following were commenced: selection of bent DNA, confirmation of bent characteristics, and work of vector construction using candidate bent DNA. Further, the simple assessment system of manifestation vectors was constructed. In the development of bioreactor system technology, the actual design was started of the two-stage culture continuance system which separated proliferation and enzyme production. 48 refs., 41 figs., 6 tabs.

  13. JPRS Report, Science & Technology, Japan, 28th Ceramics Science Discussion

    Science.gov (United States)

    2007-11-02

    Hiroshi Asakura, Hiroshi Yamamura] .............................. 59 Microstructure, Dielectric Properties of Tungsten Bronze -Type Ceramics [Yoji Ueda...of Strain 60 Microstructure, Dielectric Properties of Tungsten Bronze -Type Ceramics 906C7512 Tokyo SERAMIKKUSU KISO KAGAKU TORONKAI in Japanese 24 Jan...with different microstructures were produced for an oxide of the tungsten bronze type, Ba 0 . 5 Sr 0 . 5 Nb 20 6 , by varying the particle size and

  14. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of technologies to invent original high-functional materials (technical development of materials to heighten efficiency of power generation facilities); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu (hatsuden shisetsuyo koseinoka zairyo gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper described the fiscal 1997 results of the study of the condensation base precise structure control conducted as a technical development of materials to heighten efficiency of power generation facilities. Condensation base polymer is an important material which occupies most of the engineering plastics. The study is aimed at developing basic technologies on the molecular weight and regularity by which a remarkable improvement can be expected in performance of condensation polymerization/ring-opening polymerization polymer materials, polymerization catalyst which arbitarily controls the primary structure such as branch and end group structures, and development of the precision polymerization process. In the synthesis of ordered polymer by direct polycondensation, synthesis of ordered polyamide from asymmetric monomers is studied. In the synthesis of chemically selective polyamide by direct polymerization, polyamide with functional group is synthesized by polymerizing without protecting functional group the monomer with such functional group as causes side reaction in polymerization. In the synthesis of polyamide having the limited distribution of molecular weight, the molecular weight/distribution of polyamide are controlled by connectedly conducting polycondensation which is itself to be done successively. 91 refs., 72 figs., 43 tabs.

  15. FY 1999 report on the results of the project on the industrial science technology R and D. R and D of complex carbonhydrate production/utilization technology (Development of CO2 fixation/effective utilization technology by applying complex carbonhydrate); 1999 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo. Fukugo toushitsu seisan riyo gijutsu no kenkyu kaihatsu (Fukugo toushitsu oyo nisankatanso koteika yuko riyo gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    For the purpose of making an industrial use of complex carbonhydrate performing an important function in substance recognition, etc., which cannot be realized by only nucleic acid, protein and lipid, the R and D of the basic technology related to the production/utilization were conducted, and the FY 1999 results were reported. In the study of synthesis/utilization/remodeling technology of complex carbonhydrate using the chemical synthesis method, the R and D were made not only on the synthesis of sugar chain but for the synthesis method of the peptide added with sugar chain, that is, glycopeptide. Further, as to the reaction with the aim of the application, there was hope for large-quantity synthesis of milk oligosaccharide by the oxygen method. In the study of the design technology of complex carbonhydrate molecules, the systematical analysis using the model glycopeptide was conducted of effects of the sugar chain addition part and sugar chain structure on the 3D structure and physiological activity. Concerning the synthesis/utilization/remodeling technology of complex carbonhydrate using the biological method, study was made of the animal cell utilization, microorganism utilization, technology of structural analysis of complex carbonhydrate, etc. (NEDO)

  16. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of new software structuring models (R and D of micromachine cooperative control use software); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Shin software kozoka model no kenkyu kaihatsu (bisho kikai kyocho seigyoyo software no kenkyu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A R and D was conducted of software structuring models which ease the development and maintenance of software systems and meet diversification of needs. As for the study of the cooperative control use programming language, a R and D of agent oriented language Flage was carried out for expansion of language function, arrangement of network function, development of exercises, etc. As to the formulation of agent knowledge, proposed were processes to make a program from the specifications, and EVA, a mechanism in response to changes in the specifications of existing programs. In relation to the basic theory of cooperation system, a study was made mainly of object oriented attribute grammar OOAG as a model representing cooperative computation in software process as a rule group. Concerning the study of the situation recognition mechanism, researched were models of communication and reasoning among agents in cooperation. 187 refs., 107 figs., 23 tabs.

  17. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of technologies to invent original high-functional materials (development of precise structure control materials for enhancement of oil refining); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu (sekiyu seisei kodoka seimitsu kozo seigyo zairyo kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper described the R and D of technologies for creating original high-functional materials under the R and D system of industrial scientific technology. Japan chemical Innovation Institute (JCII) is conducting intensive joint researches under consignment from NEDO with private companies, universities and national research institutes. Among those, the paper reported the fiscal 1997 results of the following two researches conducted as development of precise structure control materials for enhancement of oil refining: precision catalytic polymerization and multi-dimensional space polymer. As to the precision catalytic polymerization, the paper is aimed at developing base technologies for the molecular weight and stereoregularity by which remarkable improvement in performance of addition polymerization type polymer can be expected, and on the development of a polymerization catalyst which arbitarily controls the primary structure such as end group structure and of a precision addition polymerization process. Subthemes are addition polymerization with limit and oriented catalytic polymerization. In relation to multi-dimensional space polymer, the paper is aimed at developing highly selective polymerization technology of aromatic compounds using enzyme related catalysts and synthesis technology of regular structure polymer, and synthesis technology of new polymer group having a new chain pattern except covalent bond/new polymer group having characteristics in three-dimensional space geometric structure. 244 refs,, 160 figs., 94 tabs.

  18. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of silicon-based polymeric materials (development of liquid methane fueled aircraft engine); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo / Shin energy Sangyo gijutsu Sogo Kaihatsu Kiko itaku. Keisokei kobunshi zairyo no kenkyu kaihatsu (methane nenryo kokukiyo engine kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This R and D aims at establishing the basic technology on the molecular design, synthesis, use as materials, and evaluation of silicon-based polymers, of which excellent electronic/optical functions, high heat-resistance/combustion-resistance/dynamic characteristic are expected. The paper introduced the results of the fiscal 1997 R and D of them. The themes are as follows: technology of synthesis of silicon-based polymeric materials with sea-island microstructures, interstitial type structure forming technology, composite materials with organometallic complexes and silicon-based polymers, silicon-based polymer structural materials with ring structures, optimization of the Wurtz`s synthesis method of silicon-based polymers, unsaturated and hypercoordinate organosilicic compounds, function of silicon-based polymers, synthesis and polymerization of new silicon-based monomers, development of a new synthesis method of polysilane and the function, development of new application of silicon-based polymers in imaging devices for recording/memory/display of information, molecular design of {pi}-conjugate and {sigma}-conjugate compounds including silicon, and conformation and electronic state of silicon-based polymeric materials. 186 refs., 141 figs., 68 tabs.

  19. Fiscal 1997 R and D project on industrial science and technology under a consignment from NEDO. R and D of the ultimate manipulation technology of atoms and molecules (R and D of the formation of advanced materials for power generation environment); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Genshi bunshi kyokugen sosa gijutsu no kenkyu kaihatsu seika hokokusho (hatsuden kankyoyo kokino sozai keisei gijutsu kaihatsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper describes R and D of the ultimate manipulation technology of atoms and molecules (atom technology). Ten nanoscale Ge islands were successfully formed in proper positions on an Si substrate surface by using mask technology of nanoscale atomic layers. Growth of less-defect ZnSe films on a GaAs(110) surface was possible under various conditions. The magnetic transfer mechanism of Mn oxide with huge reluctance was clarified. Through study on selective-area deposition of Si on plasma-oxidized ultrathin SiO2 mask layers patterned by direct electron-beam exposure and an idea of SiO2/SiNx bilayer mask, direct use of the ultrathin mask layer as insulating layer in device structure was achieved. The superior property as electron beam resist of methano- fullerene composed of fullerene C60 with side chains including oxygen was clarified. The initial oxidation process of an Si(100) surface was analyzed, and the observation result by SREM was theoretically explained. Development of a high-resolution spin polarization electron microscope was also mentioned. 48 refs., 145 figs., 20 tabs.

  20. Report on the results of research and development under a consignment from NEDO of glycoconjugate production utilizing technologies. Development of technologies to fix and effectively utilize carbon dioxide by applying glycoconjugates; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Fukugo toshitsu seisan riyo gijutsu no kenkyu kaihatsu (fukugo toshitsu oyo nisanka tanso koteika yuko riyo gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper reports research results in fiscal 1997 for the `research and development of glycoconjugate production utilizing technologies`. In synthesizing, utilizing and remodeling technologies for glycoconjugates by means of chemical synthesis, studies were performed on developing methods to synthesize Gal {beta}1-3Gal NA(c {alpha})1-0-Serine in preparative scale, synthesizing high mannose type sugars of natural type without protection groups, and linking GlcNA or GalNAc onto partial peptide of fibroblast growth factor (FGF). In synthesizing, utilizing and remodeling technologies for glycoconjugates by using biological methods, studies were carried out, with regard to glycoconjugate synthesizing, utilizing and remodeling technologies utilizing animal cells, on identifying sugar structures of IFN-{gamma} produced from CHO cell line, and isolating CHO cell lines introduced with genes of sugar transferred enzyme GnTIV and/or GnTV. Furthermore, studies were conducted on glycoconjugate synthesizing, utilizing and remodeling technologies utilizing microorganisms, and glycoconjugate structure analyzing technologies. In addition, overall investigation was made on glycoconjugate production utilizing technologies. 113 refs., 76 figs., 18 tabs.

  1. Fiscal 1997 R and D project on industrial science and technology under a consignment from NEDO. R and D of the superconducting material and device (technical development of the Josephson device hybrid system); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Chodendo zairyo chodendo soshi no kenkyu kaihatsu (Josephson soshi hybrid system no gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In order to establish basic technology for hybrid systems of superconducting and semiconducting devices, study was made on ultrahigh speed and low energy consumption properties of Josephson devices. As Josephson IC technology, a logical circuit, ring network, memory circuit, and oxide superconductor logical circuit were studied. As superconducting hybrid system technology, a Josephson device- semiconductor device interface, formation technology of signal transmission lines, and Josephson-MOS IC technology were developed. In fiscal 1997, as Josephson IC technology, switch motion of 4GHz in clock frequency was achieved by new high-density wiring process. Integration of some semiconducting processor elements, junction of surface- stabilized superconducting thin films, and motion of combination structure of some SQUIDs were also confirmed. On the hybrid system, voltage conversion operation of all interfaces was confirmed. Proper logical operation of the Josephson device hybrid circuit was also confirmed. 95 refs., 90 figs., 5 tabs.

  2. Fiscal 1997 R and D project on industrial science and technology under a consignment from NEDO. R and D of the technology of accelerated formation of bio-functions (R and D of the technology of creation of novel advanced enzymes); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Kasokugata seibutsu kino kochiku gijutsu no kenkyu kaihatsu (shingata kokino koso sosei gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper describes R and D on creation technique of novel advanced enzymes. In fiscal 1997, a novel mutagenesis technique was developed to obtain more kinds of mutational genes by shuffling between clonal genes as compared with the previous homogeneous recombination. A genotype- and phenotype-linking technology was developed by expressing random motifs (peptide as components of the active site of protein) on bacteria, and by developing a single-motif protein library. Study was made on a selection system for functional molecules of catalytic activities in a gene level, and a selection system for function of signal transduction. Analysis and evaluation study on vitro experimental technology can be efficiently promoted by recognizing the fitness landscape of target protein molecules. As a result, instead of the conventional method which needs several cycles of mutation and screening of 3-4 week/cycle, an efficient method possible to obtain multiple mutants was established. Research work was also promoted by various organizations to develop an accelerated formation technology of bio-functions. 68 refs., 51 figs., 14 tabs.

  3. Fiscal 1997 R and D project on industrial science and technology under a consignment from NEDO. R and D of the application technology of functional protein complex (R and D of the high-functional maintenance technology for power plants); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo gijutsu Sogo Kaihatsu Kiko itaku. Kinosei tanpakushitsu shugotai oyo gijutsu no kenkyu kaihatsu (hatsuden shisetsuyo kokino maintenance gijutsu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In order to develop advanced maintenance technology for power generation facilities, application technology of functional protein complexes is under investigation. On a light controllable enzymatic reaction system, construction of a light controllable bio-reactor by physico-chemical and bio- chemical techniques, and structure and functions of a photosynthetic protein complex using thermophilic cyanobacteria as material are under investigation. On a molecular mechanism for recognition and reaction of receptor proteins, structure analysis and engineering application of glutamate receptor channels of a synaptic transmission system, and basic study and material proteins for artificial structures using endocytic micromachinery, and a multi-enzyme system for synthesis of glycosphingolipids are under investigation. On a complex oxidation/reduction system by genetic engineering technique, construction of a high- efficiency stable system with functionally arranged oxidoreductase and electron transmission systems in biomembranes is in promotion. Research work was also made on molecular assemblies for a functional protein system. 166 refs., 91 figs., 9 tabs.

  4. Industrial and scientific technology research and development project in fiscal 1997 commissioned by the New Energy and Industrial Technology Development Organization. Research and development of superconducting materials and transistors (report on overall investigation of superconductive devices); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Chodendo zairyo chodendo soshi no kenkyu kaihatsu (chodendo soshika gijutsu kaihatsu seika hokokusho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper describes development of superconducting new function transistors. Fiscal 1997 as the final year of the project advanced improvement in such transistor-using processes as formation and micro-processing of superconducting thin films to show enhancement in characteristics of high-temperature superconducting transistors and possibility of their application utilizing their high speed motions. Furthermore, fundamental technologies were studied with an aim on junction transistors to be applied as circuits. For field effect transistors, evaluation was performed on critical current distribution of step-type particle boundary junction to make it possible to evaluate characteristics of hundreds of transistors. At the same time, a magnetic flux quantum parametron gate with three-layer structure was fabricated to identify its operation. In superconducting-base transistors, strong reflection was recognized on temperature dependence of permittivity of an Nb-doped strontium titanate substrate used for collectors, by which barrier height was reduced. In the junction transistor and circuit technology, isotropic ramp-edge junctions were fabricated, and so was a frequency divider circuit with single magnetic flux quantum mode operation for evaluating high-speed response characteristics. High time resolution current was observed successfully by using a high-temperature superconducting sampler system. 148 refs., 127 figs., 4 tabs.

  5. Au42: A possible ground-state noble metallic nanotube

    Science.gov (United States)

    Wang, Jing; Ning, Hua; Ma, Qing-Min; Liu, Ying; Li, You-Cheng

    2008-10-01

    A large hollow tubelike Au42 is predicted as a new ground-state configuration based on the scalar relativistic density functional theory. The shape of this new Au42 cluster is similar to a (5,5) single-wall gold nanotube, the two ends of which are capped by half of a fullerenelike Au32. In the same way, a series of Aun (n =37,42,47,52,57,62,67,72,…, Δn =5) tubelike structures has been constructed. The highest occupied molecular orbital-lowest unoccupied molecular orbital gaps suggested a significant semiconductor-conductor alternation in n ɛ[32,47]. Similar to the predictions and speculation of Daedalus [D. E. H. Jones, New Sci. 32, 245 (1966); E. Osawa, Superaromaticity (Kagaku, Kyoto, 1970), Vol. 25, pp. 854-863; Z. Yoshida and E. Osawa, Aromaticity Chemical Monograph (Kagaku Dojin, Kyoto, Japan, 1971), Vol. 22, pp. 174-176; D. A. Bochvar and E. G. Gal'pern, Dokl. Akad. Nauk SSSR 209, 610 (1973)], here a large hollow ground-state gold nanotube was predicted theoretically.

  6. Fiscal 1997 project on the R and D of industrial scientific technology under consignment form NEDO. Report on the results of the R and D of technologies to invent original high-functional materials (technical development of structure control materials / R and D of molecular harmonized materials); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu (kozo seigyo zairyo gijutsu kaihatsu) bunshi kyocho zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    By establishing microtechnology using molecular-level bottoming-up (molecular harmonization) by imitating the system of living organism, the paper described the R and D of molecular harmonized materials aiming at developing high-functional/high-performance materials such as high-performance catalyst, photo-information functional materials and sensing materials. Under consignment from NEDO, Japan Chemical innovation Institute started the 5-year plan in fiscal 1997. Self-assembled molecular films, in which organic molecules are orderly arranged by self-assembly, aim at developing new memory/optical/sensing materials. Mesophase materials which are such materials as liquid crystal showing the intermediate state between solid and liquid, develop optical/photoconductive materials using precise molecular orientation controllability. Macroporous materials are such substances as zeolite having molecular size micro pores. The paper aims at establishment of synthesis techniques of them and development of high-performance catalyst, etc. using them. In the comprehensive investigational research, conducted was a survey of the trend overseas in addition to a study of subjects in question. Further, the supporting basic study was reconsigned to universities, etc. 57 refs., 62 figs., 17 tabs.

  7. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO. Report on the results of the R and D of technologies to invent original high-functional materials (technical development of structure control materials / R and D of multi-stimuli-responsive materials); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Dokusoteki kokino zairyo sosei gijutsu no kenkyu kaihatsu (kozo seigyo zairyo gijutsu kaihatsu) kodo shigeki oto zairyo no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper described multi-stimuli-responsive materials out of the technology developments for creating original high-functional materials under the system of R and D of industrial scientific technologies. These are materials which repeatedly reproduce functions such as separation, penetration and movement in response to stimuli by imitating living organisms. In relation to polymer multi-stimuli-responsive materials, various copolymers were synthesized using N-acetyl (meta) acrylamide, of which the synthesis method was established in the previous fiscal year, as a main component, and thermal responsive polymer with upper critical solution temperature which becomes a base of separation functional materials was searched for. By immobilizing it with molecular recognition ligand, measured was thermal dependence of affinity of the immobilized matter to albumin. Also studied were molecular recognition cell adhesion/separation functional materials. Concerning composite multi-stimuli-responsive materials, with the use of silica microcapsule surface-immobilized with silane coupling agent, studied were the optimum conditions for immobilizing thermo-responsive polymer to the surface of the capsule. Using motion functional materials by ion exchange resin, obtained was motion functionality which is satisfactory at the state of practical use. 94 refs., 82 figs., 16 tabs.

  8. Industrial and scientific technology research and development project fiscal 1997 commissioned by the New Energy and Industrial Technology Development Organization. Report on research and development of a brain type computer architecture `trial fabrication and high-level evaluation on chips for a large-scale artificial neural system` and on results of evaluation studies on the chips; 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shin energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Nogata computer architecture no kenkyu kaihatsu `daikibo jinko shinkei kairo system yo chip no shisaku to kodo hyoka` chip hyoka kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In order to develop a brain type computer architecture, a brain mimic processor (BMP) has been developed (which was made in LSI in fiscal 1997), and studies are being made on developing its applications. Development has been made on an element in which linkage of one million cells with one thousand neural cells can be realized. Evaluation substrates mounted with the BMP, control software, and compilers were provided to 15 organizations including the National Research Institutes, universities, corporations, and other societies (for 19 themes) to evaluate capability of the LSI and its application development. All of the research organizations are using these items utilizing features of the LSI or the network for such purposes as learning, storage, recognition and control. The applicable theme may include infrared spectrum pattern recognition and domain division of document images using neural network functions. It can also include structural analysis of mass spectrum molecules, time series pattern recognition, location of corresponding points in images, estimation of moving images, satellite control, character recognition, short time storage, long-term association memory models, and invention process studies, all utilizing the functions of the BMP. 71 refs., 89 figs., 9 tabs.

  9. Fiscal 1997 project on the R and D of industrial scientific technology under consignment from NEDO (book on the handling / gas lift system). Report on the results of the R and D of the overall base technology of ocean resources (R and D of submarine oil drilling technology, etc.); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu jigyo Shine Energy Sangyo Gijutsu Sogo Kaihatsu Kiko itaku. Kaiyo shigen sogo kiban gijutsu no kenkyu kaihatsu (kaitei sekiyu kussaku gijutsu nado kenkyu kaihatsu) seika hokokusho (handling / gas lift system hen)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper conducted a R and D on the handling of drilling equipment in drilling/collecting of submarine oil and the gas lift of artificial oil extraction technology. As to each equipment of a barge style handling system, conducted were assembly/adjustment/trial run on land and pipe handling experiments on sea. In the experiment, confirmed were pipe transfer function, lifting function, fitting function, grasping function, etc. In the ocean experiment, studied were pipe bending stress, Karman vortex control effects, etc. Relating to the gas lift system, experiments were made on confirmation of fabrication/performance of air compressor. Moreover, a technique of air transportation to the blowing inlet of the gas lift pipe was established by developing an air blowing system and fabricating a long-distance flexible pipe. Concerning the gas/liquid/solid three-phase separator, a cyclone separator was developed, and improvement in lifting efficiency was confirmed. Helped by these, the problems of the gas lift system were almost solved, and a possibility of the commercial-base production system was obtained. 2 refs., 182 figs., 47 tabs.

  10. Association for Research in Vision and Ophthalmology (ARVO)--2010 Annual Meeting. For Sight: The Future of Eye and Vision Research--part 2.

    Science.gov (United States)

    Hookes, Livia

    2010-07-01

    The 2010 Annual Meeting of the Association for Research in Vision and Ophthalmology (ARVO), held in Fort Lauderdale, FL, USA, included topics covering new therapeutic developments in the field of eye and vision research. This conference report highlights selected presentations on the development of OT-440 (Othera Pharmaceuticals Inc) for the potential treatment of glaucoma, an extended-release implant of brimonidine (pSivida Corp) for ocular hypertension, AR-12286 (Aerie Pharmaceuticals Inc) for ocular hypertension or glaucoma, AC-8 (Calmune Corp/RiboVax Biotechnologies SA) for ocular diseases following HSV infection, and fidarestat (Sanwa Kagaku Kenkyusho Co Ltd) and the recombinant proteins NOV and NOVCter (INSERM/University Rene Descartes) for corneal neovascularization.

  11. Assessment of colonoscopy by use of magnetic endoscopic imaging

    DEFF Research Database (Denmark)

    Nerup, Nikolaj; Preisler, Louise; Svendsen, Morten Bo Søndergaard;

    2015-01-01

    BACKGROUND: Yield and safety of colonoscopy are highly dependent on operator competence. Existing tools for assessing competence is time-consuming and based on direct observation, making them prone for bias. There is a need for an easily accessible, reliable, and valid measure of endoscopic...... performance. OBJECTIVE: The aim of this study was to develop and explore the validity of an automated, unbiased assessment tool. DESIGN: We tested 10 experienced endoscopists and 11 trainees in colonoscopy on a physical simulator (Kagaku Colonoscope Training Model). Participants were tested with an easy...... and a difficult case. SETTING: Center for Clinical Education, Capital Region of Denmark. MAIN OUTCOME MEASUREMENTS: By using magnetic endoscopic imaging, we developed a colonoscopy progression score (CoPS). A pass/fail score was established by using the contrast-group method. RESULTS: We found significant...

  12. Fire proofing coatings%防火涂料

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    0502145 含硅酸钙的防火保护涂料组合物:WO2004-81 096[国际专利申请,英]/南非:(Olivier; Johannes David Prins);0502146 适于室内外用的不含卤素的防火组合物:JP2004-263 131[日本专利公开]/日本:Sankyo Kagaku K.K.(Miyamon,Kenichi等);0502147 含水玻璃的防火叠层釉:WO2004-82 933[国际专利申请,英]/英国:Pilkington Plc(Holden,David William等)。

  13. Clinical clerkship course for medical students on lumbar puncture using simulators.

    Science.gov (United States)

    Adachi, Koji; Yoshimura, Akinobu; Aso, Ryoko; Miyashita, Tsuguhiro; Yoshida, Daizo; Teramoto, Akira; Shimura, Toshiro

    2012-01-01

    Lumbar puncture is a medical technique that physicians must learn and is, therefore, considered a basic medical procedure. The lumbar puncture simulators Lumbar-Kun (Lumbar Puncture Simulator) and Lumbar-Kun II (Lumbar Puncture Simulator II) (Kyoto Kagaku, Kyoto, Japan) are teaching aids designed for practicing spinal insertions. We describe and results of a lumbar puncture clerkship course, provided to 5th-year medical students during clinical clerkship activity. The aim of this study was to evaluate the effectiveness of the lumbar puncture clerkship course in the medical education program. Comprehension, technical achievement, and satisfaction were scored by students and instructors using a 6-point Likert scale. Scores for both comprehension and technical achievement were high, but technical achievement scores tended to be higher than comprehension scores. In addition, the scores students gave themselves were higher than the scores they were given by instructors. Student satisfaction was high. The lumbar puncture simulators, Lumbar-Kun and Lumbar-Kun II, achieved excellent overall impressions and represent useful tools for training in lumbar puncture procedures. In addition to the simulators, an appropriate preparatory text and a short lecture before training seemed to increase the educational effect of this lumbar puncture clerkship course for medical students.

  14. Suppression of electrochemical decomposition of propylene carbonate (PC) on a graphite anode in PC base electrolyte with catechol carbonate; Catechol carbonate tenka denkaieki deno graphite fukyokujo ni okeru propylene carbonate no bunseki yokusei

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Congxiao; Nakamura, H. [Saga Univ. (Japan). Faculty of Science and Engineering; Noguchi, H.; Yoshio, M.; Yoshitake, H. [Ube Industries Ltd. (Japan)

    1998-03-05

    In this study, 0.5-2.0 wt.% of catechol carbonates were added to a 1MLiPF6/propylene carbonate (PC) - diethyl carbonate (DEC) electrolyte, and this addition could suppress the decomposition of PC on MCMB6-28 (graphitized meso-phase carbon manufactured by the Osaka, Gas Co., Ltd.). The catechol carbonate-added electrolyte proved effective in suppressing the decomposition of PC even on graphite, such as NG-7 (manufactured by the Kansai Netsu Kagaku Co, Ltd.), natural graphite produced in China and natural graphite produced in Madagascar. It is highly possible that catechol carbonates act as radical scavengers. It could be ascertained that, when this electrolyte was used for a LiCoO2/MCMB6-28 lithium ion secondary battery, the capacity was substantially the same as the calculated one, and a PC-based electrolyte can be used for a lithium ion secondary battery using a negative electrode of graphite. 13 refs., 10 figs., 2 tabs.

  15. Determination of total selenium content in sediments and natural water by graphite furnace-atomic absorption spectroscopy after collection as a selenium(IV) complex on activated carbon.

    Science.gov (United States)

    Kubota, T; Suzuki, K; Okutani, T

    1995-07-01

    A trace level of Se was collected on activated carbon (AC) as the Se(IV)-3-phenyl-5-mercapto-1,3,4-thiadiazole-2(3H)-thione (Bismuthiol II) complex. The AC was directly introduced as an AC-suspension into the graphite tube atomizer and the Se concentration was determined by atomic absorption spectroscopy (T. Okutani, T. Kubota, N. Sugiyama and Y. Turuta, Nippon Kagaku Kaishi, (1991) 375). The amount of Se in heavily contaminated samples including sediment, lake water and seawater was determined using this method. The sediments were digested with HNO(3)HClO(4)HF and the interference from AlF(3) was removed using H(3)BO(3)HClO(4). Lake water and seawater were acidified with H(2)SO(4) and digested with KMnO(4). The Se concentrations of these samples were determined by this method with satisfactory results. The above method is simple, rapid and applicable to heavily contaminated samples.

  16. History of T-cain: a local anesthetic developed and manufactured in Japan.

    Science.gov (United States)

    Tobe, Masaru; Saito, Shigeru

    2015-10-01

    In many anesthesia textbooks written in English, lidocaine, tetracaine, bupivacaine, ropivacaine, and chloroprocaine are listed as useful local anesthetics for spinal anesthesia. In contrast, T-cain is not included in these lists, even though it has been reported to be suitable for spinal anesthesia in Japan. T-cain was developed as a local anesthetic in the early 1940s by Teikoku Kagaku Sangyo Inc. in Itami, Japan, by replacing a methyl group on tetracaine (Pantocaine(®)) with an ethyl group. T-cain was clinically approved for topical use in Japan in November 1949, and a mixture of dibucaine and T-cain (Neo-Percamin S(®)) was approved for spinal use in May 1950. Simply because of a lack of foreign marketing strategy, T-cain has never attracted global attention as a local anesthetic. However, in Japan, T-cain has been used topically or intrathecally (as Neo-Percamin S(®)) for more than 60 years. Other than the side effects generally known for all local anesthetics, serious side effects have not been reported for T-cain. In fact, several articles have reported that T-cain decreases the neurotoxicity of dibucaine. In this historical review, the characteristics of T-cain and its rise to become a major spinal anesthetic in Japan are discussed.

  17. Development and comparison of projection and image space 3D nodule insertion techniques

    Science.gov (United States)

    Robins, Marthony; Solomon, Justin; Sahbaee, Pooyan; Samei, Ehsan

    2016-04-01

    This study aimed to develop and compare two methods of inserting computerized virtual lesions into CT datasets. 24 physical (synthetic) nodules of three sizes and four morphologies were inserted into an anthropomorphic chest phantom (LUNGMAN, KYOTO KAGAKU). The phantom was scanned (Somatom Definition Flash, Siemens Healthcare) with and without nodules present, and images were reconstructed with filtered back projection and iterative reconstruction (SAFIRE) at 0.6 mm slice thickness using a standard thoracic CT protocol at multiple dose settings. Virtual 3D CAD models based on the physical nodules were virtually inserted (accounting for the system MTF) into the nodule-free CT data using two techniques. These techniques include projection-based and image-based insertion. Nodule volumes were estimated using a commercial segmentation tool (iNtuition, TeraRecon, Inc.). Differences were tested using paired t-tests and R2 goodness of fit between the virtually and physically inserted nodules. Both insertion techniques resulted in nodule volumes very similar to the real nodules (<3% difference) and in most cases the differences were not statistically significant. Also, R2 values were all <0.97 for both insertion techniques. These data imply that these techniques can confidently be used as a means of inserting virtual nodules in CT datasets. These techniques can be instrumental in building hybrid CT datasets composed of patient images with virtually inserted nodules.

  18. Ink and relative technique%油墨与相关技术

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    0502102 阳离子可聚合组合物和油墨:US2004-214 945[美国专利申请公开]/日本:Riso Kagaku Corporation(Uozumi,Shunsuke);0502103 对塑料膜附着性好的印刷油墨组合物:JP2004-285 245[日本专利公开]/日本:Dainippon Ink and Chemicals.Inc.(Matsuda,Takashi等);0502104 具有良好耐刮擦性能产生高质量图像的喷墨打印油墨:JP2004-250 530[日本专利公开]/日本:Canon Inc.(Tsuji,Itaru等);0502105 具有良好粘弹性、流动性和颜料分散性的用于平版印刷油墨的清漆组合物:JP2004-175 974[日本专利公开]/日本:Dainippon Ink and Chemicals,Inc.(Nunokawa,Yoko等)。

  19. [A phantom study for the evaluation of the effect of the high uptake in the liver on technetium-99m myocardial perfusion SPECT images].

    Science.gov (United States)

    Ohnishi, H; Masuda, K; Takada, M; Yamamoto, I; Morita, R

    1998-07-01

    The purpose of this study was to evaluate influences of the high hepatic uptake on parameters such as filtering, attenuation coefficient, and scatter correction at reconstructing of the myocardial SPECT images. Hepatic and cardiac spaces of a myocardial phantom (RH-2, Kyoto Kagaku), were filled with technetium-99m and a three-detector SPECT system (GCA 9300-DI, TOSHIBA) was used. The hepatic activity's influence was estimated from a qualitative percent regional scattering and the effects of attenuation and scatter correction were evaluated by a circumferential profile curve. Percent regional scattering increased in reverse to hepato-cardiac distance (HCD) and in proportion to hepatic to cardiac activity ratio (HCR). This tendency was observed the most significantly in the inferior region, followed by in the lateral, anterior and septal regions, declining in this order. An artifactual defect adjacent to the liver was observed when HCR is three and HCD is zero. However, when the Butterworth filter was used with small filtering-sizes and lower orders in combination with attenuation and scatter correction, the defects were decreased up to 15% at counts in the inferior region. This study showed that the hepatic to cardiac activity ratio, and the hepatocardiac distance should be considered for reconstruction of the SPECT images.

  20. A phantom study for the evaluation of the effect of the high uptake in the liver on technetium-99m myocardial perfusion SPECT images

    Energy Technology Data Exchange (ETDEWEB)

    Ohnishi, Hideo; Masuda, Kazutaka; Takada, Masahiko; Yamamoto, Itsuo; Morita, Rikushi [Shiga Univ., Otsu (Japan). Hospital

    1998-07-01

    The purpose of this study was to evaluate influences of the high hepatic uptake on parameters such as filtering, attenuation coefficient, and scatter correction at reconstructing of the myocardial SPECT images. Hepatic and cardiac spaces of a myocardial phantom (RH-2, Kyoto Kagaku), were filled with technetium-99m and a three-detector SPECT system (GCA 9300-DI, TOSHIBA) was used. The hepatic activity`s influence was estimated from a qualitative percent regional scattering and the effects of attenuation and scatter correction were evaluated by a circumferential profile curve. Percent regional scattering increased in reverse to hepato-cardiac distance (HCD) and in proportion to hepatic to cardiac activity ratio (HCR). This tendency was observed the most significantly in the inferior region, followed by in the lateral, anterior and septal regions, declining in this order. An artifactual defect adjacent to the liver was observed when HCR is three and HCD is zero. However, when the Butterworth filter was used with small filtering-sizes and lower orders in combination with attenuation and scatter correction, the defects were decreased up to 15% at counts in the inferior region. This study showed that the hepatic to cardiac activity ratio, and the hepato-cardiac distance should be considered for reconstruction of the SPECT images. (author)

  1. Contamination profiles of short-chain polychlorinated n-alkanes in foodstuff samples from Japan

    Energy Technology Data Exchange (ETDEWEB)

    Matsukami, Hidenori; Kurunthachalam, S.; Ohi, Etsumasa; Takasuga, Takumi [Shimadzu Techno Research, Inc., Kyoto (Japan); Iino, Fukuya; Nakanishi, Junko [National Inst. of Advanced Industrial Science and Technology, Tsukuba (Japan)

    2004-09-15

    Polychlorinated n-alkanes (PCAs) are group of chemicals manufactured by chlorination of liquid n-paraffin or paraffin wax that contain 30 to 70% chlorine by weight. Large amounts of PCAs are widely used as plasticizers for vinyl chloride, lubricants, paints, and flame retardants and number of other industrial applications. Annual global production of PCAs is approximately 300 kilo tones, with a majority having medium-carbon-chain (C14-C19) length. According to the investigation made by Kagaku Kogyo Nippon-Sha, the annual consumption of PCAs in Japan was about 83,000 tons in between 1986-2001. Short-carbon-chain (C10-C13) has been placed on the Priority Substance List under Canadian Environmental Protection Act and on the Environmental Protection Agency Toxic Release Inventory in the USA due to its potential to act as tumor promoters in mammals. Data on environment levels of PCAs is meager, nevertheless, PCAs have been measured at relatively high concentrations in biota from Sweden, biota, sediment from Canada and marine biota and human milk from the Canadian Arctic. In our earlier study, we reported concentrations of short-chain PCAs from sewage treatment plant (STP) collected from Tama River, Tokyo and river water and sediment from Tokyo and Osaka. STP influent water contained greater shortchain PCAs concentrations than STP effluent. In addition, some river water and sediment samples contained detectable concentrations of short-chain PCAs, which was similar to other industrial countries. However, there is no study conducted to explore the contamination profiles of short-chain PCAs in human foodstuff samples. In the present study, we analyzed eleven foodstuff samples that were purchased from various supermarkets in order to know the short-chain PCAs concentrations in the foodstuff and possible human total daily intake (TDI) amounts.

  2. CT x-ray tube voltage optimisation and image reconstruction evaluation using visual grading analysis

    Science.gov (United States)

    Zheng, Xiaoming; Kim, Ted M.; Davidson, Rob; Lee, Seongju; Shin, Cheongil; Yang, Sook

    2014-03-01

    The purposes of this work were to find an optimal x-ray voltage for CT imaging and to determine the diagnostic effectiveness of image reconstruction techniques by using the visual grading analysis (VGA). Images of the PH-5 CT abdomen phantom (Kagaku Co, Kyoto) were acquired by the Toshiba Aquillion One 320 slices CT system with various exposures (from 10 to 580 mAs) under different tube peak voltages (80, 100 and 120 kVp). The images were reconstructed by employing the FBP and the AIDR 3D iterative reconstructions with Mild, Standard and Strong FBP blending. Image quality was assessed by measuring noise, contrast to noise ratio and human observer's VGA scores. The CT dose index CTDIv was obtained from the values displayed on the images. The best fit for the curves of the image quality VGA vs dose CTDIv is a logistic function from the SPSS estimation. A threshold dose Dt is defined as the CTDIv at the just acceptable for diagnostic image quality and a figure of merit (FOM) is defined as the slope of the standardised logistic function. The Dt and FOM were found to be 5.4, 8.1 and 9.1 mGy and 0.47, 0.51 and 0.38 under the tube voltages of 80, 100 and 120 kVp, respectively, from images reconstructed by the FBP technique. The Dt and FOM values were lower from the images reconstructed by the AIDR 3D in comparison with the FBP technique. The optimal xray peak voltage for the imaging of the PH-5 abdomen phantom by the Aquillion One CT system was found to be at 100 kVp. The images reconstructed by the FBP are more diagnostically effective than that by the AIDR 3D but with a higher dose Dt to the patients.

  3. A stylized computational model of the head for the reference Japanese male.

    Science.gov (United States)

    Yamauchi, M; Ishikawa, M; Hoshi, M

    2005-01-01

    Computational models of human anatomy, along with Monte Carlo radiation transport simulations, have been used by Snyder et al. [MIRD Pamphlet No. 5, revised (The Society of Nuclear Medicine, New York, 1978)], Cristy and Eckerman [ORNL/TM-8381/VI, Oak Ridge National Laboratory, Oak Ridge, TN (1987)] and Zubal et al. [Med. Phys. 21, 299-302 (1994)] to estimate internal organ doses from internal and external radiation sources. These were created using physiological data from Caucasoid subjects but not from other races. There is a need for research to determine whether the obvious differences from the Caucasoid anatomy make these models unsuitable for estimating the absorbed dose in other races such as the Mongoloid. We used the cranial region of the adult Japanese male to represent the Mongoloid race. This region contains organs that are highly sensitive to radiation. The cranial region of a physical phantom produced by KYOTO KAGAKU Co., LTD. using numerical data from a Japanese Reference Man [Tanaka, Nippon Acta. Radiol. 48, 509-513 (1988)] was used to supply the data for the geometry of a stylized computational model. Our computational model was constructed with equations rather than voxel-based, in order to deal with as small a number of parameters as possible in the computer simulation experiment. The accuracy of our computational model was checked by comparing simulated experimental results obtained with MCNP4C with actual doses measured with thermoluminescence dosimeters (TLDs) inside the physical phantom from which our computational model was constructed. The TLDs, whose margin of error is less than +/-10%, were arranged at six positions. Co-60 was used as the radiation source. The irradiated dose was 2 Gy in terms of air kerma. In the computer simulation experiments, we used our computational model and Cristy's computational model, whose component data are those of the tissue substitute materials and of the human body as published in ICRU Report 46. The

  4. Amla (Emblica officinalis Gaertn.) attenuates age-related renal dysfunction by oxidative stress.

    Science.gov (United States)

    Yokozawa, Takako; Kim, Hyun Young; Kim, Hyun Ju; Tanaka, Takashi; Sugino, Hidetoshi; Okubo, Tsutomu; Chu, Djong-Chi; Juneja, Lekh Raj

    2007-09-19

    To investigate the effects of amla on renal dysfunction involved in oxidative stress during the aging process, we employed young (2 months old) and aged (13 months old) male rats and administered SunAmla (Taiyo Kagaku Co., Ltd., Japan) or an ethyl acetate (EtOAc) extract of amla, a polyphenol-rich fraction, at a dose of 40 or 10 mg/kg body weight/day for 100 days. The administration of SunAmla or EtOAc extract of amla reduced the elevated levels of serum creatinine and urea nitrogen in the aged rats. In addition, the tail arterial blood pressure was markedly elevated in aged control rats as compared with young rats, while the systolic blood pressure was significantly decreased by the administration of SunAmla or EtOAc extract of amla. Furthermore, the oral administration of SunAmla or EtOAc extract of amla significantly reduced thiobarbituric acid-reactive substance levels of serum, renal homogenate, and mitochondria in aged rats, suggesting that amla would ameliorate oxidative stress under aging. The increases of inducible nitric oxide synthase (iNOS) and cyclooxygenase (COX)-2 expression in the aorta of aging rats were also significantly suppressed by SunAmla extract or EtOAc extract of amla, respectively. Moreover, the elevated expression level of bax, a proapoptotic protein, was significantly decreased after oral administration of SunAmla or EtOAc extract of amla. However, the level of bcl-2, an antiapoptotic protein, did not show any difference among the groups. The expressions of renal nuclear factor-kappaB (NF-kappaB), inhibitory kappaB in cytoplasm, iNOS, and COX-2 protein levels were also increased with aging. However, SunAmla or EtOAc extract of amla reduced the iNOS and COX-2 expression levels by inhibiting NF-kappaB activation in the aged rats. These results indicate that amla would be a very useful antioxidant for the prevention of age-related renal disease.

  5. Quantitative comparison of commercial and non-commercial metal artifact reduction techniques in computed tomography.

    Directory of Open Access Journals (Sweden)

    Dirk Wagenaar

    Full Text Available Typical streak artifacts known as metal artifacts occur in the presence of strongly attenuating materials in computed tomography (CT. Recently, vendors have started offering metal artifact reduction (MAR techniques. In addition, a MAR technique called the metal deletion technique (MDT is freely available and able to reduce metal artifacts using reconstructed images. Although a comparison of the MDT to other MAR techniques exists, a comparison of commercially available MAR techniques is lacking. The aim of this study was therefore to quantify the difference in effectiveness of the currently available MAR techniques of different scanners and the MDT technique.Three vendors were asked to use their preferential CT scanner for applying their MAR techniques. The scans were performed on a Philips Brilliance ICT 256 (S1, a GE Discovery CT 750 HD (S2 and a Siemens Somatom Definition AS Open (S3. The scans were made using an anthropomorphic head and neck phantom (Kyoto Kagaku, Japan. Three amalgam dental implants were constructed and inserted between the phantom's teeth. The average absolute error (AAE was calculated for all reconstructions in the proximity of the amalgam implants.The commercial techniques reduced the AAE by 22.0±1.6%, 16.2±2.6% and 3.3±0.7% for S1 to S3 respectively. After applying the MDT to uncorrected scans of each scanner the AAE was reduced by 26.1±2.3%, 27.9±1.0% and 28.8±0.5% respectively. The difference in efficiency between the commercial techniques and the MDT was statistically significant for S2 (p=0.004 and S3 (p<0.001, but not for S1 (p=0.63.The effectiveness of MAR differs between vendors. S1 performed slightly better than S2 and both performed better than S3. Furthermore, for our phantom and outcome measure the MDT was more effective than the commercial MAR technique on all scanners.

  6. SU-E-I-22: Dependence On Calibration Phantom and Field Area of the Conversion Factor Used to Calculate Skin Dose During Neuro-Interventional Fluoroscopic Procedures

    Energy Technology Data Exchange (ETDEWEB)

    Rana, V K; Vijayan, S [Physiology and Biophysics, Toshiba Stroke and Vascular Research Center, University at Buffalo (State University of New York), Buffalo, NY (United States); Rudin, S R; Bednarek, D R [Department of Radiology, Physiology and Biophysics, Toshiba Stroke and Vascular Research Center, University at Buffalo (State University of New York), Buffalo, NY (United States)

    2014-06-01

    Purpose: To determine the appropriate calibration factor to use when calculating skin dose with our real-time dose-tracking system (DTS) during neuro-interventional fluoroscopic procedures by evaluating the difference in backscatter from different phantoms and as a function of entrance-skin field area. Methods: We developed a dose-tracking system to calculate and graphically display the cumulative skin-dose distribution in real time. To calibrate the DTS for neuro-interventional procedures, a phantom is needed that closely approximates the scattering properties of the head. We compared the x-ray backscatter from eight phantoms: 20-cm-thick solid water, 16-cm diameter water-filled container, 16-cm CTDI phantom, modified-ANSI head phantom, 20-cm-thick PMMA, Kyoto-Kagaku PBU- 50 head, Phantom-Labs SK-150 head, and RSD RS-240T head. The phantoms were placed on the patient table with the entrance surface at 15 cm tube-side from the isocenter of a Toshiba Infinix C-arm, and the entrance-skin exposure was measured with a calibrated 6-cc PTW ionization chamber. The measurement included primary radiation, backscatter from the phantom and forward scatter from the table and pad. The variation in entrance-skin exposure was also measured as a function of the skin-entrance area for a 30x30 cm by 20-cm-thick PMMA phantom and the SK-150 head phantom using four different added beam filters. Results: The entranceskin exposure values measured for eight different phantoms differed by up to 12%, while the ratio of entrance exposure of all phantoms relative to solid water showed less than 3% variation with kVp. The change in entrance-skin exposure with entrance-skin area was found to differ for the SK-150 head compared to the 20-cm PMMA phantom and the variation with field area was dependent on the added beam filtration. Conclusion: To accurately calculate skin dose for neuro-interventional procedures with the DTS, the phantom for calibration should be carefully chosen since different