Two- and three-nucleon chiral interactions in quantum Monte Carlo calculations for nuclear physics
Energy Technology Data Exchange (ETDEWEB)
Lynn, Joel [Institut fuer Kernphysik, Technische Universitaet Darmstadt, 64289 Darmstadt (Germany); Tews, Ingo [Institute for Nuclear Theory, University of Washington, Seattle, Washington 98195 (United States); Carlson, Joseph; Gandolfi, Stefano [Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Gezerlis, Alexandros [Department of Physics, University of Guelph, Guelph, Ontario, N1G 2W1 (Canada); Schmidt, Kevin [Department of Physics, Arizona State University, Tempe, Arizona 85287 (United States); Schwenk, Achim [Institut fuer Kernphysik, Technische Universitaet Darmstadt, 64289 Darmstadt (Germany); ExtreMe Matter Institute EMMI, GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany)
2016-07-01
I present our recent work on Green's function Monte Carlo calculations of light nuclei using local two- and three-nucleon interactions derived from chiral effective field theory up to next-to-next-to-leading order (N{sup 2}LO). I discuss the choice of observables we make to fit the two low-energy constants which enter in the three-nucleon sector at N{sup 2}LO: the {sup 4}He binding energy and n-α elastic scattering P-wave phase shifts. I then show some results for light nuclei. I also show our results for the energy per neutron in pure neutron matter using the auxiliary-field diffusion Monte Carlo method and discuss regulator choices. Finally I discuss some exciting future projects which are now possible.
Symbolic computation of the Hartree-Fock energy from a chiral EFT three-nucleon interaction at N2LO
International Nuclear Information System (INIS)
Gebremariam, B.; Bogner, S.K.; Duguet, T.
2010-01-01
We present the first of a two-part Mathematica notebook collection that implements a symbolic approach for the application of the density matrix expansion (DME) to the Hartree-Fock (HF) energy from a chiral effective field theory (EFT) three-nucleon interaction at N 2 LO. The final output from the notebooks is a Skyrme-like energy density functional that provides a quasi-local approximation to the non-local HF energy. In this paper, we discuss the derivation of the HF energy and its simplification in terms of the scalar/vector-isoscalar/isovector parts of the one-body density matrix. Furthermore, a set of steps is described and illustrated on how to extend the approach to other three-nucleon interactions. Program summary: Program title: SymbHFNNN; Catalogue identifier: AEGC v 1 0 ; Program summary URL: http://cpc.cs.qub.ac.uk/summaries/AEGC_v1_0.html; Program obtainable from: CPC Program Library, Queen's University, Belfast, N. Ireland; Licensing provisions: Standard CPC licence, http://cpc.cs.qub.ac.uk/licence/licence.html; No. of lines in distributed program, including test data, etc.: 96 666; No. of bytes in distributed program, including test data, etc.: 378 083; Distribution format: tar.gz; Programming language: Mathematica 7.1; Computer: Any computer running Mathematica 6.0 and later versions; Operating system: Windows Xp, Linux/Unix; RAM: 256 Mb; Classification: 5, 17.16, 17.22; Nature of problem: The calculation of the HF energy from the chiral EFT three-nucleon interaction at N 2 LO involves tremendous spin-isospin algebra. The problem is compounded by the need to eventually obtain a quasi-local approximation to the HF energy, which requires the HF energy to be expressed in terms of scalar/vector-isoscalar/isovector parts of the one-body density matrix. The Mathematica notebooks discussed in this paper solve the latter issue. Solution method: The HF energy from the chiral EFT three-nucleon interaction at N 2 LO is cast into a form suitable for an automatic
Three-nucleon scattering by using chiral perturbation theory potential
International Nuclear Information System (INIS)
Kamata, Hiroyuki
2003-01-01
Three-nucleon scattering problems are studied by using two-nucleon and three-nucleon potentials derived from chiral perturbation theory. The three-nucleon term is shown to appear in the effective potential of the rank of next-to-next-to-leading order (NNLO). New three-nucleon forces are taken into consideration in addition to the conventional Fujita-Miyazawa (FM) type three-nucleon potential. Two-nucleon potential of the chiral perturbation theory is as precise as the conventional ones in low energy region. The FM type three-nucleon force which explains Sagara discrepancy in high energy region is introduced automatically. Concerning the Ay puzzle, the results seems to behave as if the puzzle has been solved at the level of NLO, but at the NNLO (without three-nucleon force) level the result is similar to the cases of conventional potential indicating the need of three-nucleon force. In contrast to the FM type three-nucleon force, five free parameters exist in the new D and E type three-nucleon forces introduced by the NNLO, but they are reduced to two independent parameters by antisymmetrization, which are found to be sensitive to the coupling energy of tritons and to the nd scattering length (spin doublet state). Parameters determined from them cannot give satisfactory answer to the A y puzzle. It seems, however, too hasty to conclude that A y puzzle cannot be solved by the chiral perturbation theory. (S. Funahashi)
Three nucleon interaction and nuclear composition
International Nuclear Information System (INIS)
Pandharipande, V.R.
1983-01-01
The author discusses results of some of the calculations carried out by J. Carlson, I. Lagaris, J. Lomnitz-Adler, R.A. Smith, R.B. Wiringa and himself to study the three nucleon interaction. The group has attempted to calculate the wavefunctions and binding energies of 3 H, 3 He, 4 He and nuclear matter, with the variational method, from a nonrelativistic Hamiltonian. Only nucleon degrees of freedom are retained in this Hamiltonian; the effects of other degrees of freedom are implicit in the two and three nucleon potentials. The author discusses further the calculations carried out, in collaboration with B. Friman, and R.B. Wiringa, to study the composition of nuclei. Nucleons interact by many processes including exchange of pions with or without excitation to isobar (Δ) states. Thus the nucleus contains pions being exchanged, and some nucleons in the Δ state. The group attempts to calculate the number and momentum distribution of these exchanged pions, and the fraction of time a nucleon in the nucleus is in the Δ state. 21 references, 4 figures
Chiral three-nucleon forces and the evolution of correlations along the oxygen isotopic chain
Cipollone, A.; Barbieri, C.; Navrátil, P.
2015-07-01
Background: Three-nucleon forces (3NFs) have nontrivial implications on the evolution of correlations at extreme proton-neutron asymmetries. Recent ab initio calculations show that leading-order chiral interactions are crucial to obtain the correct binding energies and neutron driplines along the O, N, and F chains [A. Cipollone, C. Barbieri, and P. Navrátil, Phys. Rev. Lett. 111, 062501 (2013), 10.1103/PhysRevLett.111.062501]. Purpose: Here we discuss the impact of 3NFs along the oxygen chain for other quantities of interest, such has the spectral distribution for attachment and removal of a nucleon, spectroscopic factors, and radii. The objective is to better delineate the general effects of 3NFs on nuclear correlations. Methods: We employ self-consistent Green's function (SCGF) theory which allows a comprehensive calculation of the single-particle spectral function. For the closed subshell isotopes, 14O, 16O, 22O, 24O, and 28O, we perform calculations with the Dyson-ADC(3) method, which is fully nonperturbative and is the state of the art for both nuclear physics and quantum chemistry applications. The remaining open-shell isotopes are studied using the newly developed Gorkov-SCGF formalism up to second order. Results: We produce complete plots for the spectral distributions. The spectroscopic factors for the dominant quasiparticle peaks are found to depend very little on the leading-order (NNLO) chiral 3NFs. The latter have small impact on the calculated matter radii, which, however, are consistently obtained smaller than experiment. Similarly, single-particle spectra tend to be too spread with respect to the experiment. This effect might hinder, to some extent, the onset of correlations and screen the quenching of calculated spectroscopic factors. The most important effect of 3NFs is thus the fine tuning of the energies for the dominant quasiparticle states, which governs the shell evolution and the position of driplines. Conclusions: Although present chiral
Di-nucleon structures in homogeneous nuclear matter based on two- and three-nucleon interactions
Energy Technology Data Exchange (ETDEWEB)
Arellano, Hugo F. [University of Chile, Department of Physics - FCFM, Santiago (Chile); CEA, DAM, DIF, Arpajon (France); Isaule, Felipe [University of Chile, Department of Physics - FCFM, Santiago (Chile); Rios, Arnau [University of Surrey, Department of Physics, Faculty of Engineering and Physical Sciences, Guildford (United Kingdom)
2016-09-15
We investigate homogeneous nuclear matter within the Brueckner-Hartree-Fock (BHF) approach in the limits of isospin-symmetric nuclear matter (SNM) as well as pure neutron matter at zero temperature. The study is based on realistic representations of the internucleon interaction as given by Argonne v{sub 18}, Paris, Nijmegen I and II potentials, in addition to chiral N{sup 3}LO interactions, including three-nucleon forces up to N{sup 2}LO. Particular attention is paid to the presence of di-nucleon bound states structures in {sup 1}S{sub 0} and {sup 3}SD{sub 1} channels, whose explicit account becomes crucial for the stability of self-consistent solutions at low densities. A characterization of these solutions and associated bound states is discussed. We confirm that coexisting BHF single-particle solutions in SNM, at Fermi momenta in the range 0.13-0.3 fm{sup -1}, is a robust feature under the choice of realistic internucleon potentials. (orig.)
Toyokawa, Masakazu; Yahiro, Masanobu; Matsumoto, Takuma; Kohno, Michio
2018-02-01
An important current subject is to clarify the properties of chiral three-nucleon forces (3NFs) not only in nuclear matter but also in scattering between finite-size nuclei. Particularly for elastic scattering, this study has just started and the properties are not understood for a wide range of incident energies (E_in). We investigate basic properties of chiral 3NFs in nuclear matter with positive energies by using the Brueckner-Hartree-Fock method with chiral two-nucleon forces at N3LO and 3NFs at NNLO, and analyze the effects of chiral 3NFs on 4He elastic scattering from targets ^{208}Pb, ^{58}Ni, and ^{40}Ca over a wide range of 30 ≲ E_in/A_P ≲ 200 MeV by using the g-matrix folding model, where A_P is the mass number of the projectile. In symmetric nuclear matter with positive energies, chiral 3NFs make the single-particle potential less attractive and more absorptive. The effects mainly come from the Fujita-Miyazawa 2π-exchange 3NF and become slightly larger as E_in increases. These effects persist in the optical potentials of 4He scattering. As for the differential cross sections of 4He scattering, chiral-3NF effects are large for E_in/A_P ≳ 60 MeV and improve the agreement of the theoretical results with the measured ones. Particularly for E_in/A_P ≳ 100 MeV, the folding model reproduces measured differential cross sections pretty well. Cutoff (Λ) dependence is investigated for both nuclear matter and 4He scattering by considering two cases of Λ=450 and 550 MeV. The uncertainty coming from the dependence is smaller than chiral-3NF effects even at E_in/A_P=175 MeV.
Hupin, Guillaume; Quaglioni, Sofia; Navrátil, Petr
2015-05-29
We provide a unified ab initio description of the ^{6}Li ground state and elastic scattering of deuterium (d) on ^{4}He (α) using two- and three-nucleon forces from chiral effective field theory. We analyze the influence of the three-nucleon force and reveal the role of continuum degrees of freedom in shaping the low-lying spectrum of ^{6}Li. The calculation reproduces the empirical binding energy of ^{6}Li, yielding an asymptotic D- to S-state ratio of the ^{6}Li wave function in the d+α configuration of -0.027, in agreement with a determination from ^{6}Li-^{4}He elastic scattering, but overestimates the excitation energy of the 3^{+} state by 350 keV. The bulk of the computed differential cross section is in good agreement with data. These results endorse the application of the present approach to the evaluation of the ^{2}H(α,γ)^{6}Li radiative capture, responsible for the big-bang nucleosynthesis of ^{6}Li.
International Nuclear Information System (INIS)
Pandharipande, V.R.; Phillips, D.R.; Kolck, U. van
2005-01-01
We consider the relationship between p-wave πN scattering and the strength of the p-wave two-pion-exchange three-nucleon interaction (TPE3NI). We explain why effective theories that do not contain the Delta resonance as an explicit degree of freedom tend to overestimate the strength of the TPE3NI. The overestimation can be remedied by higher-order terms in these 'Delta-less' theories, but such terms are not yet included in state-of-the-art chiral effective field theory calculations of the nuclear force. This suggests that these calculations can predict the strength of the TPE3NI only to an accuracy of ±25%
The effect of including tensor forces in nucleon-nucleon interaction on three-nucleon binding energy
International Nuclear Information System (INIS)
Osman, A.; Ramadan, S.
1986-01-01
Separable two-body interactions are used in considering the three-nucleon problem. The nucleon-nucleon potentials are taken to include attraction and repulsion as well as tensor forces. The separable approximation is used in order to investigate the effect of the tensor forces. The separable expansion is introduced in the three-nucleon problem, by which the Faddeev equations are reduced to a well-behaved set of coupled integral equations. Numerical calculations are carried out for the obtained integral equations using potential functions of the Yamaguchi, Gaussian, Takabin, Mongan and Reid forms. The present calculated values of the binding energies of the 3 H and 3 He nuclei are in good agreement with the experimental values. The effect of including the tensor forces in the nucleon-nucleon interactions is found to improve the three-nucleon binding energy by about 4.490% to 8.324%. 37 refs., 2 tabs. (author)
Few-Nucleon Research at TUNL: Probing Two- and Three-Nucleon Interactions with Neutrons
Howell, C. R.; Tornow, W.; Witała, H.
2016-03-01
The central goal of few-nucleon research at the Triangle Universities Nuclear Laboratory (TUNL) is to perform measurements that contribute to advancing ab-initio calculations of nuclear structure and reactions. The program aims include evaluating theoretical treatments of few-nucleon reaction dynamics through strategically comparing theory predictions to data, determining properties of the neutron-neutron interaction that are not accessible in two-nucleon reactions, and searching for evidence of longrange features of three-nucleon interactions, e.g., spin and isospin dependence. This paper will review studies of three- and four-nucleon systems at TUNL conducted using unpolarized and polarized neutron beams. Measurements of neutron-induced reactions performed by groups at TUNL over the last six years are described in comparison with theory predictions. The results are discussed in the context of the program goals stated above. Measurements of vector analyzing powers for elastic scattering in A=3 and A=4 systems, differential cross sections for neutron-deuteron elastic scattering and neutrondeuteron breakup in several final-state configurations are described. The findings from these studies and plans for the coming three years are presented in the context of worldwide activities in this front, in particular, research presented in this session.
Few-Nucleon Research at TUNL: Probing Two- and Three-Nucleon Interactions with Neutrons
Directory of Open Access Journals (Sweden)
Howell C.R.
2016-01-01
Full Text Available The central goal of few-nucleon research at the Triangle Universities Nuclear Laboratory (TUNL is to perform measurements that contribute to advancing ab-initio calculations of nuclear structure and reactions. The program aims include evaluating theoretical treatments of few-nucleon reaction dynamics through strategically comparing theory predictions to data, determining properties of the neutron-neutron interaction that are not accessible in two-nucleon reactions, and searching for evidence of longrange features of three-nucleon interactions, e.g., spin and isospin dependence. This paper will review studies of three- and four-nucleon systems at TUNL conducted using unpolarized and polarized neutron beams. Measurements of neutron-induced reactions performed by groups at TUNL over the last six years are described in comparison with theory predictions. The results are discussed in the context of the program goals stated above. Measurements of vector analyzing powers for elastic scattering in A=3 and A=4 systems, differential cross sections for neutron-deuteron elastic scattering and neutrondeuteron breakup in several final-state configurations are described. The findings from these studies and plans for the coming three years are presented in the context of worldwide activities in this front, in particular, research presented in this session.
Weak interaction in a three nucleon system: search for an asymmetry in radiative capture n-d
International Nuclear Information System (INIS)
Avenier, M.
1982-01-01
Experimental determination of the weak interaction rate in a three nucleon neutron-deuteron system: this weak interaction is observed through pseudoscalar parameters such as the asymetric angular distribution of the capture photon in relation with the system polarization. Orientation of the system is achieved by use of a polarized cold neutron beam. This phenomena is explained as a result of weak coupling between nucleons and mesons. Measurements of the gamma asymmetries observed when tests are conducted with or without heavy water and effects of depolarization are discussed [fr
International Nuclear Information System (INIS)
Osman, A.; Ramadan, S.
1989-01-01
Faddeev equations of bound three-nucleon system are presented as a set of integral equations. To solve them, a sutable form of the nucleon-nucleon interactions is used: with the exchange of a scalar meson, a pseudoscalar meson and a massless vector meson. Higher orders of these different meson exchanges in the nucleon-nucleon interactions have been taken into account. With these nuclear forces and nucleon-nucleon interactions, the three-nucleon binding energy is calculated by solving the Faddeev integral equations. The obtained value of the three-nucleon binding energy is 8.441 MeV. The inclusion of the higher order terms of the different meson exchange in the nuclear nucleon-nucleon interaction is found to affect the three-nucleon binding by about 3.92%. 3 figs., 16 refs
International Nuclear Information System (INIS)
Sauer, P.U.
2014-01-01
In this paper, the role of three-nucleon forces in ab initio calculations of nuclear systems is investigated. The difference between genuine and induced many-nucleon forces is emphasized. Induced forces arise in the process of solving the nuclear many-body problem as technical intermediaries toward calculationally converged results. Genuine forces make up the Hamiltonian. They represent the chosen underlying dynamics. The hierarchy of contributions arising from genuine two-, three- and many-nucleon forces is discussed. Signals for the need of the inclusion of genuine three-nucleon forces are studied in nuclear systems, technically best under control, especially in three-nucleon and four-nucleon systems. Genuine three-nucleon forces are important for details in the description of some observables. Their contributions to observables are small on the scale set by two-nucleon forces. (author)
Qualitative treatment of three-nucleon properties
International Nuclear Information System (INIS)
Efimov, V.
1981-01-01
An attempt is made at consistent qualitative treatment of the three-nucleon system. The approach used is based on the physical concept of effective three-nucleon long-range interaction resulting from the existence of the deuteron and the virtual singlet deuteron. Within the framework of the approach, a qualitative treatment of the triton properties, nucleon-deuteron scattering, and triton-disintegration reactions is carried out. The following topics are dealt with: the Phillips line, the triton D-wave admixture, the doublet effective range of the n-d scattering, the triton virtual state, the anomaly of the n-d elastic cross section near the three-body threshold, and the partial cross sections of the inelastic n-d scattering and of the triton photo- and electrodisintegration. The discussion of these topics includes the evaluation of three-nucleon parameters and the qualitative interpretation of experimental data and calculation results; some predictions are also made. The results of our analysis lead to the conclusion that the concept of effective three-nucleon long-range interaction can indeed serve as grounds for consistent qualitative treatment of the three-nucleon phenomena. (orig.)
Properties of Nuclei up to A =16 using Local Chiral Interactions
Lonardoni, D.; Carlson, J.; Gandolfi, S.; Lynn, J. E.; Schmidt, K. E.; Schwenk, A.; Wang, X. B.
2018-03-01
We report accurate quantum Monte Carlo calculations of nuclei up to A =16 based on local chiral two- and three-nucleon interactions up to next-to-next-to-leading order. We examine the theoretical uncertainties associated with the chiral expansion and the cutoff in the theory, as well as the associated operator choices in the three-nucleon interactions. While in light nuclei the cutoff variation and systematic uncertainties are rather small, in O 16 these can be significant for large coordinate-space cutoffs. Overall, we show that chiral interactions constructed to reproduce properties of very light systems and nucleon-nucleon scattering give an excellent description of binding energies, charge radii, and form factors for all these nuclei, including open-shell systems in A =6 and 12.
Evaluation of the three-nucleon analyzing power puzzle
International Nuclear Information System (INIS)
Tornow, W.; Witala, H.
1998-01-01
The current status of the three-nucleon analyzing power puzzle is reviewed. Applying tight constraints on the allowed deviations between calculated predictions and accepted values for relevant nucleon-nucleon observables reveals that energy independent correction factors applied to the 3 P j nucleon-nucleon interactions can not solve the puzzle. Furthermore, using the same constraints, charge-independence breaking in the 3 P j nucleon-nucleon interactions can be ruled out as a possible tool to improve the agreement between three-nucleon calculations and data. The study of the energy dependence of the three-nucleon analyzing power puzzle gives clear evidence that the 3 P j nucleon-nucleon interaction obtained from phase-shift analyses and used in potential models are correct above about 25 MeV, i.e., the 3 P j nucleon-nucleon interactions have to be modified only at lower energies in order to solve the three-nucleon analyzing power puzzle, unless new three-nucleon forces can be found that account for the three-nucleon analyzing power puzzle without destroying the beautiful agreement between rigorous three-nucleon calculations and a large body of accurate three-nucleon data. (orig.)
Evaluation of the three-nucleon analyzing power puzzle
Energy Technology Data Exchange (ETDEWEB)
Tornow, W. [Duke Univ., Durham, NC (United States). Dept. of Physics]|[Triangle Univ. Nuclear Lab., Durham, NC (United States); Witala, H. [Uniwersytet Jagiellonski, Cracow (Poland). Inst. Fizyki
1998-07-20
The current status of the three-nucleon analyzing power puzzle is reviewed. Applying tight constraints on the allowed deviations between calculated predictions and accepted values for relevant nucleon-nucleon observables reveals that energy independent correction factors applied to the {sup 3}P{sub j} nucleon-nucleon interactions can not solve the puzzle. Furthermore, using the same constraints, charge-independence breaking in the {sup 3}P{sub j} nucleon-nucleon interactions can be ruled out as a possible tool to improve the agreement between three-nucleon calculations and data. The study of the energy dependence of the three-nucleon analyzing power puzzle gives clear evidence that the {sup 3}P{sub j} nucleon-nucleon interaction obtained from phase-shift analyses and used in potential models are correct above about 25 MeV, i.e., the {sup 3}P{sub j} nucleon-nucleon interactions have to be modified only at lower energies in order to solve the three-nucleon analyzing power puzzle, unless new three-nucleon forces can be found that account for the three-nucleon analyzing power puzzle without destroying the beautiful agreement between rigorous three-nucleon calculations and a large body of accurate three-nucleon data. (orig.) 18 refs.
Δ-excitations and the three-nucleon force
International Nuclear Information System (INIS)
Epelbaum, E.; Krebs, H.; Meissner, Ulf-G.
2008-01-01
We study the three-nucleon force in chiral effective field theory with explicit Δ-resonance degrees of freedom. We show that up to next-to-next-to-leading order, the only contribution to the isospin symmetric three-nucleon force involving the spin-3/2 degrees of freedom is given by the two-pion-exchange diagram with an intermediate delta, frequently called the Fujita-Miyazawa force. We also analyze the leading isospin-breaking corrections due to the delta. For that, we give the first quantitative analysis of the delta quartet mass splittings in chiral effective field theory including the leading electromagnetic corrections. The charge-symmetry breaking three-nucleon force due to an intermediate delta excitation is small, of the order of a few keV
International Nuclear Information System (INIS)
Tornow, W.; Howell, C.R.; Walter, R.L.; Slaus, I.
1992-01-01
Comparison of data for neutron-deuteron and proton-deuteron analyzing power A y for elastic scattering has become crucial for investigating charge-symmetry breaking in the 3 P nucleon-nucleon interactions. We extended this comparison down to 5 MeV and find that the relative difference between n-d and p-d scattering at the A y maximum near 120 degree increases with decreasing energy. By applying a straightforward Coulomb ''correction'' to the p-d data, we account for most of the difference, suggesting that the Coulomb force, rather than charge-symmetry breaking, is responsible for most of the observed difference
Quantum Monte Carlo calculations with chiral effective field theory interactions
Energy Technology Data Exchange (ETDEWEB)
Tews, Ingo
2015-10-12
The neutron-matter equation of state connects several physical systems over a wide density range, from cold atomic gases in the unitary limit at low densities, to neutron-rich nuclei at intermediate densities, up to neutron stars which reach supranuclear densities in their core. An accurate description of the neutron-matter equation of state is therefore crucial to describe these systems. To calculate the neutron-matter equation of state reliably, precise many-body methods in combination with a systematic theory for nuclear forces are needed. Chiral effective field theory (EFT) is such a theory. It provides a systematic framework for the description of low-energy hadronic interactions and enables calculations with controlled theoretical uncertainties. Chiral EFT makes use of a momentum-space expansion of nuclear forces based on the symmetries of Quantum Chromodynamics, which is the fundamental theory of strong interactions. In chiral EFT, the description of nuclear forces can be systematically improved by going to higher orders in the chiral expansion. On the other hand, continuum Quantum Monte Carlo (QMC) methods are among the most precise many-body methods available to study strongly interacting systems at finite densities. They treat the Schroedinger equation as a diffusion equation in imaginary time and project out the ground-state wave function of the system starting from a trial wave function by propagating the system in imaginary time. To perform this propagation, continuum QMC methods require as input local interactions. However, chiral EFT, which is naturally formulated in momentum space, contains several sources of nonlocality. In this Thesis, we show how to construct local chiral two-nucleon (NN) and three-nucleon (3N) interactions and discuss results of first QMC calculations for pure neutron systems. We have performed systematic auxiliary-field diffusion Monte Carlo (AFDMC) calculations for neutron matter using local chiral NN interactions. By
Chiral interaction and biomolecular evolution
International Nuclear Information System (INIS)
Gilat, G.
1992-01-01
Recent developments in the concept of chiral interaction open now new options and dynamical possibilities for biomolecules which have so far been overlooked. A few of these possibilities are mentioned, such as the control mechanism of enzymatic activity and the role played by non-ergodicity in evolutionary processes. It is shown that chiral interaction, being a surface phenomenon, does not obey Barron's symmetry constraints, which are suitable for force fields present in bulk interactions. In particular, the situation at the ocean-air surface in the prebiotic era is described, as well as the possible role played by chiral interaction in conjunction with the terrestrial magnetic field normal to the ocean surface, which could have lead to a process of deracernization at the ocean-air interface. (author)
Three-Nucleon Forces and Triplet Pairing in Neutron Matter
Papakonstantinou, P.; Clark, J. W.
2017-12-01
The existence of superfluidity of the neutron component in the core of a neutron star, associated specifically with triplet P-wave pairing, is currently an open question that is central to interpretation of the observed cooling curves and other neutron-star observables. Ab initio theoretical calculations aimed at resolving this issue face unique challenges in the relevant high-density domain, which reaches beyond the saturation density of symmetrical nuclear matter. These issues include uncertainties in the three-nucleon (3N) interaction and in the effects of strong short-range correlations—and more generally of in-medium modification of nucleonic self-energies and interactions. A survey of existing solutions of the gap equations in the triplet channel demonstrates that the net impact on the gap magnitude of 3N forces, coupled channels, and mass renormalization shows extreme variation dependent on specific theoretical inputs, in some cases even pointing to the absence of a triplet gap, thus motivating a detailed analysis of competing effects within a well-controlled model. In the present study, we track the effects of the 3N force and in-medium modifications in the representative case of the ^3P_2 channel, based on the Argonne v_{18} two-nucleon (2N) interaction supplemented by 3N interactions of the Urbana IX family. Sensitivity of the results to the input interaction is clearly demonstrated. We point out consistency issues with respect to the simultaneous treatment of 3N forces and in-medium effects, which warrant further investigation. We consider this pilot study as the first step toward a systematic and comprehensive exploration of coupled-channel ^3P F_2 pairing using a broad range of 2N and 3N interactions from the current generation of refined semi-phenomenological models and models derived from chiral effective field theory.
Quark cluster model in the three-nucleon system
International Nuclear Information System (INIS)
Osman, A.
1986-11-01
The quark cluster model is used to investigate the structure of the three-nucleon systems. The nucleon-nucleon interaction is proposed considering the colour-nucleon clusters and incorporating the quark degrees of freedom. The quark-quark potential in the quark compound bag model agrees with the central force potentials. The confinement potential reduces the short-range repulsion. The colour van der Waals force is determined. Then, the probability of quark clusters in the three-nucleon bound state systems are numerically calculated using realistic nuclear wave functions. The results of the present calculations show that quarks cluster themselves in three-quark systems building the quark cluster model for the trinucleon system. (author)
The 20th anniversary of the three-nucleon analyzing power puzzle - a personal recollection
International Nuclear Information System (INIS)
Tornow, W. . Author
2008-01-01
The history of the three-nucleon analyzing power puzzle is described by an experimentalist who has been collaborating with few-body theoreticians in trying to unravel the physics of this long-standing phenomenon. Although surprising effects have been discovered along the way, the puzzle is still unexplained. Hopefully, some of the long-range three-nucleon force terms predicted by chiral effective field theory in N 3 LO will eventually solve the puzzle. Presented at the 20th Few-Body Conference, Pisa, Italy, 10-14 September 2007. (author)
Comparative study of three-nucleon potentials in nuclear matter
Lovato, Alessandro; Benhar, Omar; Fantoni, Stefano; Schmidt, Kevin E.
2012-02-01
A new generation of local three-body potentials providing an excellent description of the properties of light nuclei, as well as of the neutron-deuteron doublet scattering length, has been recently derived. We have performed a comparative analysis of the equations of state of both pure neutron matter (PNM) and symmetric nuclear matter (SNM) at zero temperature obtained using these models of three-nucleon forces. In particular, we have carried out both variational and auxiliary field diffusion Monte Carlo calculations of the equation of state of PNM, while in the case of SNM we have only the variational approach has been considered. None of the considered potentials simultaneously explains the empirical equilibrium density and binding energy of symmetric nuclear matter. However, two of them provide reasonable values of the saturation density. The ambiguity concerning the treatment of the contact term of the chiral inspired potentials is discussed.
Potentials of the inverse scattering problem in the three-nucleon problem
International Nuclear Information System (INIS)
Pushkash, A.M.; Simenog, I.V.; Shapoval, D.V.
1993-01-01
Possibilities of using the method of the inverse scattering problem for describing simultaneously the two-nucleon and the low-energy three-nucleon data in the S-interaction approximation are examined. 20 refs., 3 figs., 1 tab
Relativistic origin of three-nucleon force
International Nuclear Information System (INIS)
Haberzettl, H.; Parke, W.C.
1995-01-01
Based on the manifestly covariant cluster-dynamical formalism recently proposed by Haberzettl, the three-body forces entering three-nucleon equations are discussed. It is shown that there exist additional contributions to the (nonrelativistic) three-body force, not taken into account in the usual treatments, arising from the proper nonrelativistic limits of higher-order meson-exchange Feynman diagrams. Using the Paris potential, a five-channel triton bound-state calculation results in additional binding of about 0.6 MeV due to this new mechanism. copyright 1995 American Institute of Physics
Three-nucleon forces and their importance in three-nucleon sys- tems and heavier nuclei
Kalantar-Nayestanaki, N.
2014-01-01
Abstract In the past two decades, several laboratories have produced a large amount of data for cross sections, analyzing powers, and other spin observables from various reactions in the three-nucleon system. The experimental results are moderately described by only using the two-nucleon potentials
International Nuclear Information System (INIS)
Ducharme, C.
1969-01-01
This work is related to the interpretation of the results concerning the three nucleon experiment, D(n,nnp), at 14.5 MeV, carried out by double time-of-flight spectrometry. The present work consists in the simulation of the main parasitic events using the Monte-Carlo method for extracting them from the experimental distribution around the n-n pole. (author) [fr
Three-nucleon forces and the trinucleon bound states
International Nuclear Information System (INIS)
Friar, J.L.; Frois, B.
1986-04-01
A summary of the bound-state working group session of the ''International Symposium on the Three-Body Force in the Three-Nucleon System'' is presented. The experimental evidence for three-nucleon forces has centered on two ground state properties: the tritium binding energy and the trinucleon form factors. Both are discussed
Three-nucleon problem with phase equivalent potentials
International Nuclear Information System (INIS)
Pushkash, O.M.; Shapoval, D.V.; Simenog, I.V.
1991-01-01
The effect of the t-matrix off-shell variations with nonlocal phase equivalent N-N potentials on the three-nucleon parameters is studied. The variations, which lower or increase the tritium binding energy, are revealed. We show that under certain conditions, the three-nucleon low-energy observables are almost insensitive to the high energy behaviour of the negative parts of the scattering phase shifts. The inverse problem method is applied to reconstruct simple S-wave potentials which to provide a unified description of the two-nucleon and low-energy three-nucleon data. 22 refs.; 6 figs. (author)
Three-nucleon force contribution in the distorted-wave theory of (d ,p ) reactions
Timofeyuk, N. K.
2018-05-01
The distorted-wave theory of A (d ,p )B reactions, widely used to analyze experimental data, is based on a Hamiltonian that includes only two-nucleon interactions. However, numerous studies of few-nucleon systems and many modern developments in nuclear structure theory show the importance of the three-nucleon (3 N ) force. The purpose of this paper is to study the contribution of the 3 N force of the simplest possible form to the A (d ,p )B reaction amplitude. This contribution is given by a new term that accounts for the interaction of the neutron and proton in the incoming deuteron with one of the target nucleons. This term involves a new type of nuclear matrix elements containing an infinite number of target excitations in addition to the main part associated with the traditional overlap function between A and B . The nuclear matrix elements are calculated for double-closed shell targets within a mean field theory where target excitations are shown to be equivalent to exchanges between valence and core nucleons. These matrix elements can be readily incorporated into available reaction codes if the 3 N interaction has a spin-independent zero-range form. Distorted-wave calculations are presented for a contact 3 N force with the volume integral fixed by the chiral effective field theory at the next-to-next-to-leading order. For this particular choice, the 3 N contribution is noticeable, especially at high deuteron incident energies. No 3 N effects are seen for incident energies below the Coulomb barrier. The finite range can significantly affect the 3 N contribution to the (d ,p ) cross sections. Finite-range studies require new formal developments and, therefore, their contribution is preliminarily assessed within the plane-wave Born approximation, together with sensitivity to the choice of the deuteron model.
Kistryn, St.; Stephan, E.; Kalantar-Nayestanaki, N.; Biegun, A.; Bodek, K.; Ciepal, I.; Deltuva, A.; Epelbaum, E.; Fonseca, A. C.; Gloeckle, W.; Golak, J.; Kamada, H.; Kis, M.; Klos, B.; Kozela, A.; Nogga, A.; Mahjour-Shafiei, M.; Micherdzinska, A.; Sauer, P. U.; Skibinski, R.; Sworst, R.; Witala, H.; Zejma, J.; Zipper, W.
2008-01-01
The three-nucleon system is the simplest non-trivial testing ground in which the quality of modern nucleon-nucleon interaction models, as well as additional dynamical ingredients referred to as three-nucleon forces, can be probed quantitatively by means of a rigorous technique of solving the Faddeev
Maeda, Katsuhiro; Yashima, Eiji
2017-08-01
Construction of predominantly one-handed helical polyacetylenes with a desired helix sense utilizing noncovalent chiral interactions with nonracemic chiral guest compounds based on a supramolecular approach is described. As with the conventional dynamic helical polymers possessing optically active pendant groups covalently bonded to the polymer chains, this noncovalent helicity induction system can show significant chiral amplification phenomena, in which the chiral information of the nonracemic guests can transfer with high cooperativity through noncovalent bonding interactions to induce an almost single-handed helical conformation in the polymer backbone. An intriguing "memory effect" of the induced macromolecular helicity is observed for some polyacetylenes, which means that the helical conformations induced in dynamic helical polyacetylene can be transformed into metastable static ones by tuning their helix-inversion barriers. Potential applications of helical polyacetylenes with controlled helix sense constructed by the "noncovalent helicity induction and/or memory effect" as chiral materials are also described.
International Nuclear Information System (INIS)
Gebremariam, B.; Bogner, S.K.; Duguet, T.
2011-01-01
The density matrix expansion (DME) of Negele and Vautherin is a convenient tool to map finite-range physics associated with vacuum two- and three-nucleon interactions into the form of a Skyrme-like energy density functional (EDF) with density-dependent couplings. In this work, we apply the improved formulation of the DME proposed recently in (arXiv:0910.4979) by Gebremariam et al. to the non-local Fock energy obtained from chiral effective field theory (EFT) two-nucleon (NN) interactions at next-to-next-to-leading-order (N 2 LO). The structure of the chiral interactions is such that each coupling in the DME Fock functional can be decomposed into a coupling constant arising from zero-range contact interactions and a coupling function of the density arising from the universal long-range pion exchanges. This motivates a new microscopically-guided Skyrme phenomenology where the density-dependent couplings associated with the underlying pion-exchange interactions are added to standard empirical Skyrme functionals, and the density-independent Skyrme parameters subsequently refit to data. A link to a downloadable Mathematica notebook containing the novel density-dependent couplings is provided.
Ciofi degli Atti, Claudio; Mezzetti, Chiara Benedetta; Morita, Hiko
2017-04-01
Background: Two-nucleon (2 N ) short-range correlations (SRC) in nuclei have been recently thoroughly investigated, both theoretically and experimentally and the study of three-nucleon (3 N ) SRC, which could provide important information on short-range hadronic structure, is underway. Novel theoretical ideas concerning 2 N and 3 N SRC are put forward in the present paper. Purpose: The general features of a microscopic one-nucleon spectral function which includes the effects of both 2 N and 3 N SRC and its comparison with ab initio spectral functions of the three-nucleon systems are illustrated. Methods: A microscopic and parameter-free one-nucleon spectral function expressed in terms of a convolution integral involving ab initio relative and center-of-mass (c.m.) momentum distributions of a 2 N pair and aimed at describing two- and three-nucleon short-range correlations, is obtained by using: (i) the two-nucleon momentum distributions obtained within ab initio approaches based upon nucleon-nucleon interactions of the Argonne family; (ii) the exact relation between one- and two-nucleon momentum distributions; (iii) the fundamental property of factorization of the nuclear wave function at short internucleon ranges. Results: The comparison between the ab initio spectral function of 3He and the one based upon the convolution integral shows that when the latter contains only two-nucleon short-range correlations the removal energy location of the peaks and the region around them exhibited by the ab initio spectral function are correctly predicted, unlike the case of the high and low removal energy tails; the inclusion of the effects of three-nucleon correlations brings the convolution model spectral function in much better agreement with the ab initio one; it is also found that whereas the three-nucleon short-range correlations dominate the high energy removal energy tail of the spectral function, their effects on the one-nucleon momentum distribution are almost one
Renormalization of NN Interaction with Relativistic Chiral Two Pion Exchange
Energy Technology Data Exchange (ETDEWEB)
Higa, R; Valderrama, M Pavon; Arriola, E Ruiz
2007-06-14
The renormalization of the NN interaction with the Chiral Two Pion Exchange Potential computed using relativistic baryon chiral perturbation theory is considered. The short distance singularity reduces the number of counter-terms to about a half as those in the heavy-baryon expansion. Phase shifts and deuteron properties are evaluated and a general overall agreement is observed.
Total disintegration of three-nucleon nuclei in charged-pion photo-production
International Nuclear Information System (INIS)
Dzhibuti, R.I.; Kezerashvili, R.Y.
1984-01-01
The total disintegration of three-nucleon nuclei in charged-pion photo-production is studied within the framework of the microscopic approach based on the method of hyperspherical functions. The initial and final nuclear states are described using the same NN potentials. The differential and total cross sections are calculated using various NN potentials. It is shown that the cross sections are sensitive to the form of the NN interaction and to the final-state interaction of the three nucleons. It is found that the cross section for π - meson production is systematically larger than the cross section for π + meson production. The importance of an experimental investigation of these reactions is shown
Three-nucleon system dynamics studied via deuteron-proton breakup
International Nuclear Information System (INIS)
Kistryn, S.
2011-01-01
Nucleon-nucleon (NN) interaction is a basis for vast fields of fundamental nuclear physics and its application, therefore a detailed knowledge of the dynamics of few-nucleon systems has been a subject of intensive quest over several decades. Modern NN potential models can be probed quantitatively in the three-nucleon environment by comparing predictions based on rigorous solutions of the Faddeev equations with the measured observables. Proper description of the experimental data can be achieved only if the dynamical models include subtle effects of suppressed degrees of freedom, effectively introduced by means of genuine three-nucleon forces. A large set of high precision, exclusive cross-section data for the "1H(d,pp)n breakup reaction at 130 MeV, acquired in a first new-generation experiment at KVI Groningen, contributes significantly to constrain the physical assumptions underlying the theoretical interaction models. Comparison of nearly 1800 cross-section data points with the predictions using nuclear interactions generated in various ways, allowed to establish for the first time a clear evidence of importance of the three-nucleon forces in the breakup process. Moreover, the results, supplemented by a set of cross-sections from another dedicated experiment at FZ Juelich, confirmed predictions of sizable Coulomb force influences in this reaction. Following further, comparably rich and precise data sets, encompassing also polarization observables, will form a database to validate the theoretical models of few-nucleon system dynamics. (author)
Off-energy-shell variations of two-nucleon transition matrix and three-nucleon problem
International Nuclear Information System (INIS)
Stingl, M.; Sauer, P.U.
1975-01-01
For a schematic three-nucleon problem, approximate analytic expressions are derived for the functional derivatives of measurable three-particle quantities with respect to off-shell variations of the triplet-s two-nucleon transition matrix. Those quantities include neutron-deuteron scattering lengths, trinucleon binding energies, and the 3 He charge form-factor minimum; correlations between off-shell changes in the latter two are discussed. An indication is given how results of this kind may be to decide whether or not a given set of discrepancies between calculated and experimental three-nucleon observables can be reconciled in terms of off-shell variations of a nonretarded hermitean two-nucleon interaction. The treatment is not restricted to special classes of phase-shift equivalent potentials or phase-shift preserving transformations but instead makes use of a systematic parameterization of off-shell variations in terms of symmetric rational approximants of increasing order
Hadronic interactions from effective chiral Lagrangians of quarks and gluons
International Nuclear Information System (INIS)
Krein, G.
1996-06-01
We discuss the combined used of the techniques of effective chiral field theory and the field theoretic method known as Fock-Tani representation to derive effective hadron interactions. The Fock-Tani method is based on a change of representation by means of a unitary transformation such that the composite hadrons are redescribed by elementary-particle field operators. Application of the unitary transformation on the microscopic quark-quark interaction derived from a chiral effective Lagrangian leads to chiral effective interactions describing all possible processes involving hadrons and their constituents. The formalism is illustrated by deriving the one-pion-exchange potential between the nucleons using the quark-gluon effective chiral Lagrangian of Manohar and Georgi. We also present the results of a study of the saturation properties of the nuclear matter using this formalism. (author). 9 refs., 2 figs
Leading order relativistic chiral nucleon-nucleon interaction
Ren, Xiu-Lei; Li, Kai-Wen; Geng, Li-Sheng; Long, Bingwei; Ring, Peter; Meng, Jie
2018-01-01
Motivated by the successes of relativistic theories in studies of atomic/molecular and nuclear systems and the need for a relativistic chiral force in relativistic nuclear structure studies, we explore a new relativistic scheme to construct the nucleon-nucleon interaction in the framework of covariant chiral effective field theory. The chiral interaction is formulated up to leading order with covariant power counting and a Lorentz invariant chiral Lagrangian. We find that the relativistic scheme induces all six spin operators needed to describe the nuclear force. A detailed investigation of the partial wave potentials shows a better description of the {}1S0 and {}3P0 phase shifts than the leading order Weinberg approach, and similar to that of the next-to-leading order Weinberg approach. For the other partial waves with angular momenta J≥slant 1, the relativistic results are almost the same as their leading order non-relativistic counterparts. )
Three-body force in the three-nucleon system
International Nuclear Information System (INIS)
Gibson, B.F.
1986-01-01
A brief summary of the symposium is presented. Three-nucleon force models are discussed, including the two-pion exchange potential, NN-ΔN coupled-channels model, and phenomenological parametrization. Relevant experimental data and model calculations are discussed including form factors, binding energies, charge radii, and charge density for 3 H and 3 He. A calculation of the EMC effect for 3 He is also made using Sasakawa's wave function and compared to experimental data obtained at SLAC. The paper ends with discussions of proton-deuteron scattering, investigations at intermediate energies, and QCD efforts to understand the three-body problem
The Sendai triton calculation with three-nucleon potentials
International Nuclear Information System (INIS)
Sasakawa, T.
1986-01-01
Where can we see the effects of quarks remains a fundamental question in nuclear theory physics. A bold approach is to try to reproduce physical quantities theoretically by utilizing a quark picture with imagination. A conservative but safer approach may be to study the triton as thoroughly as possible using realistic two- and three-nucleon potentials. We are taking the latter approach. In fact, our calculation of the EMC effect, which was one thought to be a realization of the quark-gluon picture of nuclei, suggests that we might not have to make recourse to this picture. The calculation was done for 3 He, while experimental data for 4 He are shown. We hope that an experiment for 3 He is done soon, to check whether our conservative approach actually works for the EMC effect. (orig./WL)
Configuration space methods in the three-nucleon problem
International Nuclear Information System (INIS)
Friar, J.L.
1985-01-01
The assumptions underlying the formulation and solution of the Schroedinger equation for three nucleons in configuration space are reviewed. Those qualitative aspects of the two-nucleon problem which play an important role in the trinucleon are discussed. The geometrical aspects of the problem are developed, and the importance of the angular momentum barrier is demonstrated. The Faddeev-Noyes formulation of the Schroedinger equation is motivated, and the boundary conditions for various three-body problems is reviewed. The method of splines is shown to provide a particularly useful numerical modelling technique for solving the Faddeev-Noyes equation. The properties of explicit trinucleon solutions for various two-body force models are discussed, and the evidence for three-body forces is reviewed. The status of calculations of trinucleon observables is discussed, and conclusions are presented. 40 refs., 14 figs
Meson-baryon interactions in unitarized chiral perturbation theory
International Nuclear Information System (INIS)
Garcia Recio, G.; Nieves, J.; Ruiz Arriola, E.; Vicente Vacas, M.
2003-01-01
Meson-Baryon Interactions can be successfully described using both Chiral Symmetry and Unitarity. The s-wave meson-baryon scattering amplitude is analyzed in a Bethe-Salpeter coupled channel formalism incorporating Chiral Symmetry in the potential. Two body coupled channel unitarity is exactly preserved. The needed two particle irreducible matrix amplitude is taken from lowest order Chiral Perturbation Theory in a relativistic formalism. Off-shell behavior is parameterized in terms of low energy constants. The relation to the heavy baryon limit is discussed. The position of the complex poles in the second Riemann sheet of the scattering amplitude determine masses and widths baryonic resonances of the N(1535), N(1670), Λ(1405) and Λ(1670) resonances which compare well with accepted numbers
Studies of the Three-Nucleon System Dynamics in the Deuteron-Proton Breakup Reaction
Ciepał, I.; Kłos, B.; Stephan, E.; Kistryn, St.; Biegun, A.; Bodek, K.; Deltuva, A.; Epelbaum, E.; Eslami-Kalantari, M.; Fonseca, A. C.; Golak, J.; Jha, V.; Kalantar-Nayestanaki, N.; Kamada, H.; Khatri, G.; Kirillov, Da.; Kirillov, Di.; Kliczewski, St.; Kozela, A.; Kravcikova, M.; Machner, H.; Magiera, A.; Martinska, G.; Messchendorp, J.; Nogga, A.; Parol, W.; Ramazani-Moghaddam-Arani, A.; Roy, B. J.; Sakai, H.; Sekiguchi, K.; Sitnik, I.; Siudak, R.; Skibiński, R.; Sworst, R.; Urban, J.; Witała, H.; Zejma, J.
2014-03-01
One of the most important goals of modern nuclear physics is to contruct nuclear force model which properly describes the experimental data. To develop and test predictions of current models the breakup 1H(overrightarrow d, pp)n reaction was investigated experimentally at 100 and 130 MeV deuteron beam energies. Rich set of data for cross section, vector and tensor analyzing powers was obtained with the use of the SALAD and BINA detectors at KVI and Germanium Wall setup at FZ-Jülich. Results are compared with various theoretical approaches which describe the three-nucleon (3N) system dynamics. For correct description of the cross section data both, three-nucleon force (3NF) and Coulomb force, have to be included into calculations and influence of those ingredients is seizable at specific parts of the phase space. In case of the vector analyzing powers very low sensitivity to any effects beyond nucleon-nucleon interaction was found. At 130 MeV, the Axy data are not correctly described when 3NF models are included into calculations.
Three-nucleon hadronic and electromagnetic reactions with Δ-isobar excitation
International Nuclear Information System (INIS)
Deltuva, A.; Adam, J. Jr.; Fonseca, A.C.; Sauer, P.U.
2005-01-01
Three-nucleon hadronic and electromagnetic reactions are described. The description uses the purely nucleonic charge-dependent CD-Bonn potential and its coupled-channel extension CD-Bonn + Δ. Exact solutions of three-particle equations are employed for the initial and final states of the reactions. The Δ-isobar excitation yields an effective three-nucleon force and effective two- and three-nucleon currents beside other Δ-isobar effects; they are mutually consistent
Electromagnetic properties of the three-nucleon ground state
International Nuclear Information System (INIS)
Strueve, W.
1985-01-01
The electromagnetic form factors of the three-nucleon ground state are calculated on the base of an exact solution of the Faddeev equations. In a Hilbert space of nucleons and a possible Δ-isobar the effects of a non-perturbative description of the Δ-isobar on the magnetic form factors are studied. Pure nucleonic current operators with two- and three-particle character can be described in the extended Hilbert space by simpler one-body operators. Additionally nonrelativistic meson-exchange corrections due to π and ρ exchange are calculated consistently with the requirements of current conservation. Further relativistic corrections are estimated on selected examples. The calculations yield a total magnetic contribution of the Δ-isobar which is smaller than hitherto assumed, a static approximation of the Δ propagation is proved as inadmissible and must be rejected. Together with the meson-exchange corrections a well agreement with the experimental data at low momentum transfers results. Especially the magnetic moments and magnetization radii can be explained. For higher momentum transfers the results show the importance of further corrections. The regard of selected relativistic corrections leads to a good description of the experimental magnetic form factors. Also by this way the position of the minimum and the height of the second maximum in the 3 He charge form factor can be explained. The comparison with the latest experimental results reveals furthermore unresolved problems in the description of the 3 H charge form factor. (orig.) [de
Chiral helimagnetic state in a Kondo lattice model with the Dzyaloshinskii-Moriya interaction
Okumura, Shun; Kato, Yasuyuki; Motome, Yukitoshi
2018-05-01
Monoaxial chiral magnets can form a noncollinear twisted spin structure called the chiral helimagnetic state. We study magnetic properties of such a chiral helimagnetic state, with emphasis on the effect of itinerant electrons. Modeling a monoaxial chiral helimagnet by a one-dimensional Kondo lattice model with the Dzyaloshinskii-Moriya interaction, we perform a variational calculation to elucidate the stable spin configuration in the ground state. We obtain a chiral helimagnetic state as a candidate for the ground state, whose helical pitch is modulated by the model parameters: the Kondo coupling, the Dzyaloshinski-Moriya interaction, and electron filling.
Chirality dependent interaction of ammonia with carbon nanotubes
Talukdar, Keka; Shantappa, Anil
2018-04-01
For the specific structure and extraordinary properties, carbon nanotubes (CNTs) have many applications in diversified fields. The interaction of CNTs with ammonia is a very interesting matter to study as it is related to the application of CNTs as ammonia sensor. Here the interaction of single walled zigzag, armchair and chiral carbon nanotubes is studied in respect of the change in energies before and after binding with ammonia by molecular dynamics simulation. Their deformation after simulation is modeled. The change of thermal conductivity of the CNTs is also found by simulation. The potential energy before and after absorption of ammonia gives useful information of the system. Thermal conductivities of the ammonia bound CNTs are changed considerably. It is observed that the potential energy and thermal conductivity both are changing for the interaction with ammonia and hence they are sensitive to ammonia binding.
One, two or three-nucleon photo- absorption in 3He
International Nuclear Information System (INIS)
Tamas, G.
1986-08-01
Pion production and photodisintegration of 3 He are studied in the δ resonance region to try to separate the various photon absorption mechanism by one, two or three nucleons. The results are compared to the existing models
Analysis of Three-Nucleon Forces Effects in the A = 3 System
International Nuclear Information System (INIS)
Kievsky, A.
2011-01-01
Using modern nucleon-nucleon interactions in the description of the A = 3, 4 nuclear systems the χ 2 per datum results to be much bigger than one. In particular it is not possible to reproduce the three- and four-nucleon binding energies and the n .d scattering length simultaneously. This is one manifestation of the necessity of including a three-nucleon force in the nuclear Hamiltonian. In this paper we perform an analysis of some, widely used, three-nucleon force models.We analyze their capability to describe the aforementioned quantities and, to improve their description, we propose modifications in the parametrization of the models. The effects of these new parametrizations are studied in some polarization observables at low energies. Due to the fact that some of the widely used TNF models do not reproduce simultaneously the triton and 4 He binding energies and the n -d doublet scattering length, possible modifications of their parametrizations have been analyzed. To this end we have used the AV18 as the reference NN interaction and we have analyze possible modifications of the URIX model. We have modified the regularization of the profile functions Y (r ) and T (r ) at the origin and we have introduced the Z 0 (r ) function in the central repulsive E-term. We have used one-parameter functions that have been chosen to match the short-range behavior of the corresponding functions in the N2LOL model. Furthermore the strengths of the b-, d-terms and E-terms have been fixed to reproduce the triton binding energy and 2 a nd . Then the predictions for some selected scattering observables in p - d scattering at 3 MeV have been compared to the results of the original model and the experimental data. We can observe that the description using the new parametrizations has the same quality of the original model. However, with the proposed parametrizations, the AV18+URIX model describes correctly B( 3 H) and 2 a nd . This analysis can be consider as a preliminary step in a
Pionic retardation effects in two-pion-exchange three-nucleon forces
International Nuclear Information System (INIS)
Coon, S.A.; Friar, J.L.
1986-01-01
Those two-pion-exchange three-nucleon forces which arise from nuclear processes that involve only pions and nucleons are calculated. Among the processes which contribute are pion seagulls (e.g., nucleon-antinucleon pair terms) and overlapping, retarded pion exchanges. The resulting potential is shown to be a (v/c) 2 relativistic correction, and satisfies nontrivial constraints from special relativity. The relativistic ambiguities found before in treatments of relativistic corrections to the one-pion-exchange nuclear charge operator and two-body potential are also present in the three-nucleon potential. The resulting three-nucleon force differs from the original Tucson-Melbourne potential only in the presence of several new nonlocal terms, and in the specification of the choice of ambiguity parameters in the latter potential
Pionic retardation effects in two-pion-exchange three-nucleon forces
Coon, S. A.; Friar, J. L.
1986-09-01
Those two-pion-exchange three-nucleon forces which arise from nuclear processes that involve only pions and nucleons are calculated. Among the processes which contribute are pion seagulls (e.g., nucleon-antinucleon pair terms) and overlapping, retarded pion exchanges. The resulting potential is shown to be a (v/c)2 relativistic correction, and satisfies nontrivial constraints from special relativity. The relativistic ambiguities found before in treatments of relativistic corrections to the one-pion-exchange nuclear charge operator and two-body potential are also present in the three-nucleon potential. The resulting three-nucleon force differs from the original Tucson-Melbourne potential only in the presence of several new nonlocal terms, and in the specification of the choice of ambiguity parameters in the latter potential.
Pionic retardation effects in two-pion-exchange three-nucleon forces
Energy Technology Data Exchange (ETDEWEB)
Coon, S.A.; Friar, J.L.
1986-09-01
Those two-pion-exchange three-nucleon forces which arise from nuclear processes that involve only pions and nucleons are calculated. Among the processes which contribute are pion seagulls (e.g., nucleon-antinucleon pair terms) and overlapping, retarded pion exchanges. The resulting potential is shown to be a (v-italic/c-italic)/sup 2/ relativistic correction, and satisfies nontrivial constraints from special relativity. The relativistic ambiguities found before in treatments of relativistic corrections to the one-pion-exchange nuclear charge operator and two-body potential are also present in the three-nucleon potential. The resulting three-nucleon force differs from the original Tucson-Melbourne potential only in the presence of several new nonlocal terms, and in the specification of the choice of ambiguity parameters in the latter potential.
General operator form of the non-local three-nucleon force
Energy Technology Data Exchange (ETDEWEB)
Topolnicki, K. [Jagiellonian University, M. Smoluchowski Institute of Physics, Krakow (Poland)
2017-09-15
This paper describes a procedure to obtain the general form of the three-nucleon force. The result is an operator form where the momentum space matrix element of the three-nucleon potential is written as a linear combination of 320 isospin-spin-momentum operators and scalar functions of momenta. Any spatial and isospin rotation invariant three-nucleon force can be written in this way and in order for the potential to be Hermitian, symmetric under parity inversion, time reversal and particle exchange, the scalar functions must have definite transformation properties under these discrete operations. A complete list of the isospin-spin-momentum operators and scalar function transformation properties is given. (orig.)
P-matrix approach and three-nucleon problem
International Nuclear Information System (INIS)
Babenko, V.A.; Petrov, N.M.; Teneva, G.N.
1993-01-01
The paper deals with the P-matrix approach application to the three strongly interacting particles systems description. On the basis of the obtained off-energy-shell scattering amplitude separable expansion in the P-matrix approach the low-energy three-particle quantities were calculated in the case of square-well potential. The results of calculations show good convergence of the calculated three-particle quantities. (author). 12 refs., 1 tab
A new twist to the long-standing three-nucleon analyzing power puzzle
Energy Technology Data Exchange (ETDEWEB)
Neidel, E.M.; Tornow, W.; Gonzalez Trotter, D.E.; Howell, C.R.; Crowell, A.S.; Macri, R.A.; Walter, R.L.; Weisel, G.J.; Esterline, J.; Witala, H.; Crowe, B.J.; Pedroni, R.S.; Markoff, D.M
2003-01-16
New results for the neutron-deuteron analyzing power A{sub y}({theta}) at E{sub n}=1.2 and 1.9 MeV and their comparison to proton-deuteron data reveal a sizeable and unexpected difference which increases with decreasing center-of-mass energy. This finding calls for the theoretical treatment of a subtle electromagnetic effect presently not incorporated in rigorous three-nucleon scattering calculations, before it is justified to invoke charge-dependent three-nucleon forces and/or other new physics.
L-dependence in the 6Li induced three nucleon transfer excitation function
International Nuclear Information System (INIS)
Kraus, L.; Linck, I.
1980-01-01
The three nucleon transfer reactions induced by 6 Li on 12 C were studied from 5 to 9 MeV/n. The bell-shaped energy variation is used to select cluster states of progressively higher angular momentum. A modification to the Brink semi-classical model equations is proposed in order to reproduce the observed features
Hyperon-nucleon interactions - a chiral effective field theory approach
Polinder, H.; Haidenbauer, J.; Meissner, U.G.
2006-01-01
We construct the leading order hyperon–nucleon potential in chiral effective field theory. We show that a good description of the available data is possible and discuss briefly further improvements of this scheme
Chiral realization of the non-leptonic weak interactions
International Nuclear Information System (INIS)
Ecker, G.
1990-01-01
After a short introduction to chiral perturbation theory an attempt to relate the strong and the non-leptonic weak low-energy constants is reviewed. The weak deformation model is stimulated both by the geometrical structure of chiral perturbation theory and by phenomenological considerations. Applications to the radiative decays K → πγγ and K L → γe + e - are discussed. (Author) 38 refs., 4 figs
Chiral and color-superconducting phase transitions with vector interaction in a simple model
International Nuclear Information System (INIS)
Kitazawa, Masakiyo; Koide, Tomoi; Kunihiro, Teiji; Nemoto, Yukio
2002-01-01
We investigate effects of the vector interaction on chiral and color superconducting (CSC) phase transitions at finite density and temperature in a simple Nambu-Jona-Lasinio model. It is shown that the repulsive density-density interaction coming from the vector term, which is present in the effective chiral models but has been omitted, enhances the competition between the chiral symmetry breaking (χSB) and CSC phase transition, and thereby makes the thermodynamic potential have a shallow minimum over a wide range of values of the correlated chiral and CSC order parameters. We find that when the vector coupling is increased, the first order transition between the χSB and CSC phases becomes weaker, and the coexisting phase in which both the chiral and color-gauge symmetry are dynamically broken comes to exist over a wider range of the density and temperature. We also show that there can exist two endpoints, which are tricritical points in the chiral limit, along the critical line of the first order transition in some range of values of the vector coupling. Although our analysis is based on a simple model, the nontrivial interplay between the χSB and CSC phases induced by the vector interaction is expected to be a universal phenomenon and might give a clue to understanding results obtained with two-color QCD on the lattice. (author)
Investigation of the Three-Nucleon System Dynamics in the Deuteron-Proton Breakup Reaction
Ciepał, I.; Kłos, B.; Kistryn, St.; Stephan, E.; Biegun, A.; Bodek, K.; Deltuva, A.; Epelbaum, E.; Eslami-Kalantari, M.; Fonseca, A. C.; Golak, J.; Jha, V.; Kalantar-Nayestanaki, N.; Kamada, H.; Khatri, G.; Kirillov, Da.; Kirillov, Di.; Kliczewski, St.; Kozela, A.; Kravcikova, M.; Machner, H.; Magiera, A.; Martinska, G.; Messchendorp, J.; Nogga, A.; Parol, W.; Ramazani-Moghaddam-Arani, A.; Roy, B. J.; Sakai, H.; Sekiguchi, K.; Sitnik, I.; Siudak, R.; Skibiński, R.; Sworst, R.; Urban, J.; Witała, H.; Zejma, J.
2014-08-01
Precise and large sets of cross section, vector A x , A y and tensor A xx , A xy , A yy analyzing power data for the 1 H( d, pp) n breakup reactions were measured at 100 and 130 MeV deuteron beam energies with the SALAD and BINA detectors at KVI and the Germanium Wall setup at FZ-Jülich. Results are compared with various theoretical approaches which model the three-nucleon system dynamics. The cross section data reveal a sizable three-nucleon force (3NF) and Coulomb force influence. In case of the analyzing powers very low sensitivity to these effects was found and the data are well describe by 2N models only. For A xy at 130 MeV, serious disagreements were observed when 3NF models are included in the calculations.
International Nuclear Information System (INIS)
Tornow, W.; Kievsky, A.; Witala, H.
2002-01-01
Using the existing high-accuracy data for proton-deuteron and deuteron-proton elastic scattering, a phase-shift analysis has been performed in the laboratory proton energy range from E p = 4 to 10 MeV The AV 18-based proton-deuteron phase shifts were used as starting values in the phase-shift search procedure. The low-partial wave phase shifts, especially the 4 P j phase shifts have been determined very precisely, thus providing valuable guidance for theoretical approaches to tackle the quest for a successful description of three-nucleon bound-state and continuum observables in a more efficient and consistent way. Furthermore, it was found that the 4 P 1/2 phase shift and the mixing parameter ε 3/2 - determined in the present analysis cannot be generated by 3 P j nucleon-nucleon interactions which are consistent with two-nucleon analyzing power data. Therefore, three-nucleon forces must play an essential role in resolving the long-standing three-nucleon analyzing-power puzzle. Refs. 44 (author)
The chiral anomaly in non-leptonic weak interactions
International Nuclear Information System (INIS)
Bijnens, J.; Pich, A.; Ecker, G.
1992-01-01
The interplay between the chiral anomaly and the non-leptonic weak hamiltonian is studied. The structure of the corresponding effective lagrangian of odd intrinsic parity is established. It is shown that the factorizable contributions (leading in 1/N C ) to that lagrangian can be calculated without free parameters. As a first application, the decay K + →π + π 0 γ is investigated. (orig.)
Energy Technology Data Exchange (ETDEWEB)
Ducharme, C [Commissariat a l' Energie Atomique, Grenoble (France). Centre d' Etudes Nucleaires
1969-07-01
This work is related to the interpretation of the results concerning the three nucleon experiment, D(n,nnp), at 14.5 MeV, carried out by double time-of-flight spectrometry. The present work consists in the simulation of the main parasitic events using the Monte-Carlo method for extracting them from the experimental distribution around the n-n pole. (author) [French] Cette etude rentre dans le cadre de l'interpretation des resultats de l'experience a trois nucleons D(n,nnp) a 14.5 MeV effectuee par spectrometrie a double temps-de-vol. Le present travail consiste a simuler les evenements parasites principaux par une methode de Monte-Carlo pour les soustraire de la distribution experimentale autour du pole n-n. (auteur)
An upper bound on right-chiral weak interactions
International Nuclear Information System (INIS)
Stephenson, G.J.; Goldman, T.; Maltman, K.
1990-01-01
Weak vertex corrections to the quark-gluon vertex functions produce differing form-factor corrections for quarks of differing chiralities. These differences grow with increasing four-momentum transfer in the gluon leg. Consequently, inclusive polarized proton--proton scattering to a final state jet should show a large parity-violating asymmetry at high energies. The absence of large signals at sufficiently high energies can be interpreted as being due to balancing vertex corrections from a right-handed weak vector boson of limited mass, and limits on the strength of such signals can, in principle, give upper bounds on that mass. 2 refs
An upper bound on right-Chiral weak interactions
International Nuclear Information System (INIS)
Stephenson, G.J.; Goldman, T.; Maltman, K.
1990-01-01
Weak vertex corrections to the quark-gluon vertex functions produce differing form-factor corrections for quarks of differing chiralities. These differences grow with increasing four-momentum transfer in the gluon leg. Consequently, inclusive polarized proton-proton scattering to a final state jet should show a large parity-violating asymmetry at high energies. The absence of large signals at sufficiently high energies can be interpreted as being due to balancing vertex corrections from a right-handed weak vector boson of limited mass, and limits on the strength of such signals can, in principle, give upper bounds on that mass
Study of three nucleon mechanisms in the photodisintegration of 3 He
International Nuclear Information System (INIS)
Audit, G.; D'Hose, N.; Isbert, V.; Kerhoas, S.; Laget, J.M.; Mac Cormick, M.; Murphy, L.Y.; Tamas, G.; Panzeri, A.; Pinelli, T.; Ahrens, J.; Annand, J.R.M.; Crawford, R.; Hall, S.J.; Kellie, J.D.; Murphy, L.Y.
1996-01-01
The cross section of the 3 He (γ,pp)n reaction has been measured for the first time over a wide photon energy and proton angular range (200 MeV ≤ Eγ ≤ 800 MeV; 20 deg ≤ v lab p ≤ 160 deg) using the large acceptance detector DAPHNE at the tagged photon facility of the microtron in Mainz. The wide kinematical coverage of the measurement has allowed a detailed analysis of three nucleon absorption mechanisms. A model developed by Laget explains the main characteristics of the data in the Δ resonance region. (authors)
Three-Nucleon Force Effects in p-"3H and n-"3He Scattering
International Nuclear Information System (INIS)
Viviani, M.; Kievsky, A.; Girlanda, L.; Marcucci, L. E.
2017-01-01
We present a preliminary study of the effect of a three-nucleon force (3NF) in p-"3H and n-"3 He scattering at low energies. The used 3NF is derived from effective field theory at next-to-next-to-leading order. The four-nucleon scattering observables are calculated using the Kohn variational principle and the hyperspherical harmonics technique and the results are compared with available experimental data. We have found that the effect of introducing this type of 3NF is tiny, and sometimes worsens the agreement with the experimental data. (author)
Strangeness S = -2 baryon-baryon interactions using chiral effective field theory
Polinder, H.; Haidenbauer, J.; Meissner, U.G.
2007-01-01
We derive the leading order strangeness S =−2 baryon–baryon interactions in chiral effective field theory. The potential consists of contact terms without derivatives and of one-pseudoscalar-meson exchanges. The contact terms and the couplings of the pseudoscalar mesons to the baryons are related
Inhomogeneous chiral symmetry breaking in isospin-asymmetric strong-interaction matter
Energy Technology Data Exchange (ETDEWEB)
Nowakowski, Daniel
2017-07-01
In this thesis we investigate the effects of an isospin asymmetry on inhomogeneous chiral symmetry breaking phases, which are characterized by spatially modulated quarkantiquark condensates. In order to determine the relevance of such phases for the phase diagram of strong-interaction matter, a two-flavor Nambu-Jona-Lasinio model is used to study the properties of the ground state of the system. Confirming the presence of inhomogeneous chiral symmetry breaking in isospin-asymmetric matter for a simple Chiral Density Wave, we generalize the modulation of the quark-antiquark pairs to more complicated shapes and study the effects of different degrees of flavor-mixing on the inhomogeneous phase at non-zero isospin asymmetry. Then, we investigate the occurrence of crystalline chiral symmetry breaking phases in charge-neutral matter, from which we determine the influence of crystalline phases on a quark star by calculating mass-radius sequences. Finally, our model is extended through color-superconducting phases and we study the interplay of these phases with inhomogeneous chiral-symmetry breaking at non-vanishing isospin asymmetry, before we discuss our findings.
Directory of Open Access Journals (Sweden)
Ioseph L. Buchbinder
2018-01-01
Full Text Available We investigate cubic interactions between a chiral superfield and higher spin superfields corresponding to irreducible representations of the 4 D , N = 1 super-Poincaré algebra. We do this by demanding an invariance under the most general transformation, linear in the chiral superfield. Following Noether’s method we construct an infinite tower of higher spin supercurrent multiplets which are quadratic in the chiral superfield and include higher derivatives. The results are that a single, massless, chiral superfield can couple only to the half-integer spin supermultiplets ( s + 1 , s + 1 / 2 and for every value of spin there is an appropriate improvement term that reduces the supercurrent multiplet to a minimal multiplet which matches that of superconformal higher spins. On the other hand a single, massive, chiral superfield can couple only to higher spin supermultiplets of type ( 2 l + 2 , 2 l + 3 / 2 (only odd values of s, s = 2 l + 1 and there is no minimal multiplet. Furthermore, for the massless case we discuss the component level higher spin currents and provide explicit expressions for the integer and half-integer spin conserved currents together with a R-symmetry current.
Nucleon-nucleon interaction of a chiral σ-ω model at finite temperature
International Nuclear Information System (INIS)
Rukeng Su
1994-01-01
By using the imaginery time Green's function method, the nucleon-nucleon interaction of the chiral σ-ω model has been investigated under the one-loop approximation. The effective masses of the pion, σ-meson and ω-meson at finite temperature are given. We have found that the potential well of the nucleon-nucleon interaction becomes shallow as the temperature increases. At a critical temperature T c (70 MEV) the potential well disappears. (author)
Probing the three-nucleon force using nucleon-deuteron breakup reactions
International Nuclear Information System (INIS)
Howell, C.R.; Lambert, J.M.; Witala, H.
1995-01-01
Results of our recent kinematically complete cross-section measurements of the space-star and coplanar-star configurations in n-d breakup at 13.0 MeV are reported. The experimental setup and details of the analysis are described. The new data for the space-star configuration are in good agreement with previous n-d data but differ significantly from both ''exact'' n-d calculations and p-d data. In contrast, the new coplanar-star data are in fair agreement with the calculations but are in gross disagreement with previous n-d data. The implications of these data for three-nucleon forces are discussed. (orig.)
Probing the three-nucleon force using nucleon-deuteron breakup reactions
Energy Technology Data Exchange (ETDEWEB)
Howell, C.R. [Duke Univ., Durham, NC (United States). Dept. of Physics; Setze, H.R. [Duke Univ., Durham, NC (United States). Dept. of Physics; Braun, R.T. [Duke Univ., Durham, NC (United States). Dept. of Physics; Gonzalez Trotter, D.E. [Duke Univ., Durham, NC (United States). Dept. of Physics; Hussein, A.H. [Duke Univ., Durham, NC (United States). Dept. of Physics; Roper, C.D. [Duke Univ., Durham, NC (United States). Dept. of Physics; Salinas, F. [Duke Univ., Durham, NC (United States). Dept. of Physics; Slaus, I. [Duke Univ., Durham, NC (United States). Dept. of Physics; Tornow, W. [Duke Univ., Durham, NC (United States). Dept. of Physics; Vlahovic, B. [Duke Univ., Durham, NC (United States). Dept. of Physics; Walter, R.L. [Duke Univ., Durham, NC (United States). Dept. of Physics; Mertens, G. [Tuebingen Univ. (Germany); Lambert, J.M. [Department of Physics, Georgetown University, Washington, DC 20057 (United States); Witala, H. [Institute of Physics, Jagellonian University, Reymonta 4, PL-30059 Cracow (Poland)
1995-05-01
Results of our recent kinematically complete cross-section measurements of the space-star and coplanar-star configurations in n-d breakup at 13.0 MeV are reported. The experimental setup and details of the analysis are described. The new data for the space-star configuration are in good agreement with previous n-d data but differ significantly from both ``exact`` n-d calculations and p-d data. In contrast, the new coplanar-star data are in fair agreement with the calculations but are in gross disagreement with previous n-d data. The implications of these data for three-nucleon forces are discussed. (orig.).
Effects of second neighbor interactions on skyrmion lattices in chiral magnets
International Nuclear Information System (INIS)
Oliveira, E A S; Silva, R L; Silva, R C; Pereira, A R
2017-01-01
In this paper we investigate the influences of the second neighbor interactions on a skyrmion lattice in two-dimensional chiral magnets. Such a system contains the exchange and the Dzyaloshinskii–Moriya for the spin interactions and therefore, we analyse three situations: firstly, the second neighbor interaction is present only in the exchange coupling; secondly, it is present only in the Dzyaloshinskii–Moriya coupling. Finally, the second neighbor interactions are present in both exchange and Dzyaloshinskii–Moriya couplings. We show that such effects cause important modifications to the helical and skyrmion phases when an external magnetic field is applied. (paper)
Czech Academy of Sciences Publication Activity Database
Růžička, Martin; Koval, Dušan; Vávra, Jan; Reyes Gutierrez, Paul Eduardo; Teplý, Filip; Kašička, Václav
2016-01-01
Roč. 1467, Oct 7 (2016), s. 417-426 ISSN 0021-9673 R&D Projects: GA ČR(CZ) GA15-01948S; GA ČR GA13-32974S; GA ČR GA13-19213S Institutional support: RVO:61388963 Keywords : affinity capillary electrophoresis * binding constant * chiral separation * helquats * noncovalent interactions * partial filling Subject RIV: CB - Analytical Chemistry , Separation Impact factor: 3.981, year: 2016
Tornow, W; Witala, H
2002-01-01
Using the existing high-accuracy data for proton-deuteron and deuteron-proton elastic scattering, a phase-shift analysis has been performed in the laboratory proton energy range from E sub p = 4 to 10 MeV The AV 18-based proton-deuteron phase shifts were used as starting values in the phase-shift search procedure. The low-partial wave phase shifts, especially the sup 4 P sub j phase shifts have been determined very precisely, thus providing valuable guidance for theoretical approaches to tackle the quest for a successful description of three-nucleon bound-state and continuum observables in a more efficient and consistent way. Furthermore, it was found that the sup 4 P sub 1 sub / sub 2 phase shift and the mixing parameter epsilon sub 3 sub / sub 2 sub sup - determined in the present analysis cannot be generated by sup 3 P sub j nucleon-nucleon interactions which are consistent with two-nucleon analyzing power data. Therefore, three-nucleon forces must play an essential role in resolving the long-standing thre...
Directory of Open Access Journals (Sweden)
Oller J.A.
2010-04-01
Full Text Available We review on a novel chiral power counting scheme for in-medium chiral perturbation theory with nucleons and pions as degrees of freedom. It allows for a systematic expansion taking into account local as well as pion-mediated inter-nucleon interactions. Based on this power counting, one can identify classes of nonperturbative diagrams that require a resummation. As a method for performing those resummations we review on the techniques of Unitary Chiral Pertubation Theory for nucleon-nucleon interactions. We then apply both power counting and non-perturbative methods to the example of calculating the pion self-energy in asymmetric nuclear matter up-to-and-including next-to-leading order. It is shown that the leading corrections involving in-medium nucleon-nucleon interactions cancel between each other at given chiral orders.
Ahmed, Mohammad W.; Gao, Haiyan; Weller, Henry R.; Holstein, Barry
2007-10-01
of singular potentials and power counting / M.P. Valderrrama. The challenge of calculating Baryon-Baryon scattering from lattice QCD / S.R. Beane. Precise absolute np scattering cross section and the charged [Pie symbol] NN coupling constant / S. E. Vigdor. Probing hadronic parity violation using few nucleon systems / S.A. Page. Extracting the neutron-neutron scattering length from neutron-deuteron breakup / C.R. Howell. Extraction of [equationl] from [Pie symbol]-d --> [equation] / A. Grudestig. The three- and four-body system with large scattering length / L. Platter. 3N and 4N systems and the Ay puzzle / T. Clegg. Recent progress in nuclear lattice simulations with effective field theory / D. Lee. Few-body studies at KVI / J.G. Messchendorp. Results of three nucleon experiments from RIKEN / K. Sekiguchi. A new opportunity to measure the total photoabsorption cross section of helium / P. T. Debevec. Three-body photodisintegration of 3He with double polarizations / X. Zong. Large two-pion exchange contributions to the pp --> pp[Pie symbol]0 reaction / F. Myhrer. Towards a systematic theory of nuclear forces / E. Epelbaum. Ab initio calculations of eletromagnetic reactions in light nuclei / W. Leidemann. Electron scattering from a polarized deuterium target at BLAST / R. Fatemi. Neutron-neutron scattering length from the reaction [equation] / V. Lensky. Renormalization group analysis of nuclear current operators / S.X. Nakamura. Recent results and future plans at MAX-LAB / K.G. Fissum. Nucleon polarizabilities from deutron compton scattering, and its lessons for chiral power counting / H. W. Grie hammer. Compton scattering on HE-3 / D. Choudhury -- pt. D. Hadron structure and Meson-Baryon interactions. Summary of the working group on Hadron structure and Meson-Baryon interactions / G. Feldman and T.R. Hemmert. Finite volume effects: lattice meets CHPT / G. Schierholz. Lattice discretization errors in chiral effective field theories / B.C. Tiburzi. SU(3)-breaking
Chiral magnetic effect in the presence of electroweak interactions as a quasiclassical phenomenon
Dvornikov, Maxim; Semikoz, Victor B.
2018-03-01
We elaborate the quasiclassical approach to obtain the modified chiral magnetic effect (CME) in the case when the massless charged fermions interact with electromagnetic fields and the background matter by the electroweak forces. The derivation of the anomalous current along the external magnetic field involves the study of the energy density evolution of chiral particles in parallel electric and magnetic fields. We consider both the particle acceleration by the external electric field and the contribution of the Adler anomaly. The condition of the validity of this method for the derivation of the CME is formulated. We obtain the expression for the electric current along the external magnetic field, which appears to coincide with our previous results based on the purely quantum approach. Our results are compared with the findings of other authors.
Chiral symmetry and the nucleon--nucleon interaction
International Nuclear Information System (INIS)
Brown, G.E.
1977-01-01
The nucleon--nucleon interaction is understood in terms of a dynamic model, the sigma model. The anti NN → ππ helicity amplitudes are assumed to be physical data, and the dynamical model must reproduce these data, more or less. 14 references
Gelation induced supramolecular chirality: chirality transfer, amplification and application.
Duan, Pengfei; Cao, Hai; Zhang, Li; Liu, Minghua
2014-08-14
Supramolecular chirality defines chirality at the supramolecular level, and is generated from the spatial arrangement of component molecules assembling through non-covalent interactions such as hydrogen bonding, van der Waals interactions, π-π stacking, hydrophobic interactions and so on. During the formation of low molecular weight gels (LMWGs), one kind of fascinating soft material, one frequently encounters the phenomenon of chirality as well as chiral nanostructures, either from chiral gelators or even achiral gelators. A view of gelation-induced supramolecular chirality will be very helpful to understand the self-assembly process of the gelator molecules as well as the chiral structures, the regulation of the chirality in the gels and the development of the "smart" chiral materials such as chiroptical devices, catalysts and chiral sensors. It necessitates fundamental understanding of chirality transfer and amplification in these supramolecular systems. In this review, recent progress in gelation-induced supramolecular chirality is discussed.
Interaction of Individual Skyrmions in a Nanostructured Cubic Chiral Magnet
Du, Haifeng; Zhao, Xuebing; Rybakov, Filipp N.; Borisov, Aleksandr B.; Wang, Shasha; Tang, Jin; Jin, Chiming; Wang, Chao; Wei, Wensheng; Kiselev, Nikolai S.; Zhang, Yuheng; Che, Renchao; Blügel, Stefan; Tian, Mingliang
2018-05-01
We report direct evidence of the field-dependent character of the interaction between individual magnetic skyrmions as well as between skyrmions and edges in B 20 -type FeGe nanostripes observed by means of high-resolution Lorentz transmission electron microscopy. It is shown that above certain critical values of an external magnetic field the character of such long-range skyrmion interactions changes from attraction to repulsion. Experimentally measured equilibrium inter-skyrmion and skyrmion-edge distances as a function of the applied magnetic field shows quantitative agreement with the results of micromagnetic simulations. The important role of demagnetizing fields and the internal symmetry of three-dimensional magnetic skyrmions are discussed in detail.
Features of electron-phonon interactions in nanotubes with chiral symmetry in magnetic field
Kibis, O V
2001-01-01
Interaction of the electrons with acoustic phonons in the nanotube with chiral symmetry by availability of the magnetic field, parallel to the nanotube axis, is considered. It is shown that the electron energy spectrum is asymmetric relative to the electron wave vector inversion and for that reason the electron-phonon interaction appears to be different for similar phonons with mutually contrary directions of the wave vector. This phenomenon leads to origination of the electromotive force by the spatially uniform electron gas heating and to appearance of the quadrupole component in the nanotube volt-ampere characteristics
Thermodynamics of lattice QCD with massless quarks and chiral 4-fermion interactions
International Nuclear Information System (INIS)
Kogut, J. B.
1998-01-01
N f = 2 lattice QCD with massless quarks and a weak 4-fermion interaction appears to have the expected second order transition, at least for N t ≥ 6. More work is needed to clarify the N t = 4 case. With more statistics the N t = 6 simulations should produce an accurate determination of the critical exponent β m . Moving to finite mass at β = β c should allow an accurate determination of σ. Hadronic screening masses need further analysis. Other order parameters remain to be analyzed. Unfortunately, there is no obvious way to include 4-fermion interactions with full SU(2) x SU(2) chiral flavor symmetry
International Nuclear Information System (INIS)
St. Kistryn; E. Stephan; A. Biegun; K. Bodek; A. Deltuva; E. Epelbaum; K. Ermisch; W. Gloeckle; J. Golak; N. Kalantar-Nayestanaki; H. Kamada; M. Kis; B. Klos; A. Kozela; J. Kuros-Zolnierczuk; M. Mahjour-Shafiei; U.-G. Meissner; A. Micherdzinska; A. Nogga; P. U. Sauer; R. Skibinski; R. Sworst; H. Witala; J. Zejma; W. Zipper
2005-01-01
High precision cross-section data of the deuteron-proton breakup reaction at 130 MeV are presented for 72 kinematically complete configurations. The data cover a large region of the available phase space, divided into a systematic grid of kinematical variables. They are compared with theoretical predictions, in which the full dynamics of the three-nucleon (3N) system is obtained in three different ways: realistic nucleon-nucleon (NN) potentials are combined with model 3N forces (3NF's) or with an effective 3NF resulting from explicit treatment of the Delta-isobar excitation. Alternatively, the chiral perturbation theory approach is used at the next-to-next-to-leading order with all relevant NN and 3N contributions taken into account. The generated dynamics is then applied to calculate cross-section values by rigorous solution of the 3N Faddeev equations. The comparison of the calculated cross sections with the experimental data shows a clear preference for the predictions in which the 3NF's are included. The majority of the experimental data points is well reproduced by the theoretical predictions. The remaining discrepancies are investigated by inspecting cross sections integrated over certain kinematical variables. The procedure of global comparisons leads to establishing regularities in disagreements between the experimental data and the theoretically predicted values of the cross sections. They indicate deficiencies still present in the assumed models of the 3N system dynamics
Sk, Rejaul; Dhara, Barun; Miller, Joel; Deshpande, Aparna
Submolecular resolution scanning tunneling microscopy (STM) of copper octacyanophthalocyanine, CuPc(CN)8, at 77 K demonstrates that these achiral molecules form a two dimensional (2D) tetramer-based self-assembly upon evaporation onto an atomically flat Au(111) substrate. They assemble in two different structurally chiral configurations upon adsorption on Au(111). Scanning tunneling spectroscopy (STS),acquired at 77 K, unveils the HOMO and LUMO energy levels of this self-assembly. Voltage dependent STM images show that each molecule in both the structurally chiral configurations individually becomes chiral by breaking the mirror symmetry due to the enhanced intermolecular dipolar coupling interaction at the LUMO energy while the individual molecules remain achiral at the HOMO energy and within the HOMO-LUMO gap. At the LUMO energy, the handedness of the each chiral molecule is decided by the direction of the dipolar coupling interaction in the tetramer unit cell. This preference for LUMO energy indicates that this chirality is purely electronic in nature and it manifests on top of the organizational chirality that is present in the self-assembly independent of the orbital energy. Supported by IISER Pune and DAE-BRNS, India (Project No. 2011/20/37C/17/BRNS).
Chiral phase from three-spin interactions in an optical lattice
International Nuclear Information System (INIS)
D'Cruz, Christian; Pachos, Jiannis K.
2005-01-01
A spin-1/2 chain model that includes three-spin interactions can effectively describe the dynamics of two species of bosons trapped in an optical lattice with a triangular-ladder configuration. A perturbative theoretical approach and numerical study of its ground state is performed that reveals a rich variety of phases and criticalities. We identify phases with periodicity one, two, or three, as well as critical points that belong in the same universality class as the Ising or the three-state Potts model. We establish a range of parameters, corresponding to a large degeneracy present between phases with period 2 and 3, that nests a gapless incommensurate chiral phase
Three-nucleon transfer reactions and cluster structure in the A = 15 to A = 19 nuclei
International Nuclear Information System (INIS)
Martz, L.M.
1978-01-01
The ( 6 Li,t) and ( 6 Li, 3 He) reactions were studied on targets of 12 C, 13 C, 14 N, 15 N, and 16 O at E/sub Li/ approx. = 44 MeV and theta/sub lab/ approx. = 15 0 . A preferential population of final states was exhibited in spectra for the A = 15 to A = 19 nuclei. The strong forward peaking of angular distributions in the 13 C( 6 Li,t) 16 O and 13 C( 6 Li, 3 He) 16 N reactions can be reproduced by DWBA calculations but not by the Hauser-Feshbach model. Such indications of a primarily direct mechanism at forward angles suggest use of these three-nucleon-transfer reactions to identify candidates for 3p-nh states. A comparison with other multinucleon transfer data, e.g., those from ( 7 Li,α) and ( 7 Li,t) reactions on 13 C and 15 N targets, further tests dominant particle-hole configurations. The relationship between ( 6 Li,t) and ( 6 Li, 3 He) spectra reveals analog states, notably T = 1, T/sub z/ = 0 levels at high excitation in 16 O. Nuclear theory is used to investigate the role of triton clustering in such structure. The 2N + L = 6 band predicted by a folded-potential model of 18 O = 15 N + t shows an underlying correspondence to the experimental levels in triton-transfer data. Triton spectroscopic factors calculated from the SU(3) shell model further suggest the broad influence of clustering phenomena in this mass region. Experimental evidence of systematic behavior in the triton binding energies of proposed p/sup -n/(sd) 3 configurations was found
Chiral symmetry and chiral-symmetry breaking
International Nuclear Information System (INIS)
Peskin, M.E.
1982-12-01
These lectures concern the dynamics of fermions in strong interaction with gauge fields. Systems of fermions coupled by gauge forces have a very rich structure of global symmetries, which are called chiral symmetries. These lectures will focus on the realization of chiral symmetries and the causes and consequences of thier spontaneous breaking. A brief introduction to the basic formalism and concepts of chiral symmetry breaking is given, then some explicit calculations of chiral symmetry breaking in gauge theories are given, treating first parity-invariant and then chiral models. These calculations are meant to be illustrative rather than accurate; they make use of unjustified mathematical approximations which serve to make the physics more clear. Some formal constraints on chiral symmetry breaking are discussed which illuminate and extend the results of our more explicit analysis. Finally, a brief review of the phenomenological theory of chiral symmetry breaking is presented, and some applications of this theory to problems in weak-interaction physics are discussed
Nuclear electric dipole moments in chiral effective field theory
Energy Technology Data Exchange (ETDEWEB)
Bsaisou, J.; Vries, J. de [Institute for Advanced Simulation, Institut für Kernphysik, and Jülich Center for Hadron Physics,Forschungszentrum Jülich, D-52425 Jülich (Germany); Hanhart, C. [Institute for Advanced Simulation, Institut für Kernphysik, and Jülich Center for Hadron Physics,Forschungszentrum Jülich, D-52425 Jülich (Germany); JARA - Forces and Matter Experiments,Forschungszentrum Jülich, D-52425 Jülich (Germany); Liebig, S. [Institute for Advanced Simulation, Institut für Kernphysik, and Jülich Center for Hadron Physics,Forschungszentrum Jülich, D-52425 Jülich (Germany); Meißner, Ulf-G. [Institute for Advanced Simulation, Institut für Kernphysik, and Jülich Center for Hadron Physics,Forschungszentrum Jülich, D-52425 Jülich (Germany); JARA - Forces and Matter Experiments,Forschungszentrum Jülich, D-52425 Jülich (Germany); JARA - High Performance Computing,Forschungszentrum Jülich, D-52425 Jülich (Germany); Helmholtz-Institut für Strahlen- und Kernphysik and Bethe Center for Theoretical Physics,Universität Bonn,D-53115 Bonn (Germany); Minossi, D. [Institute for Advanced Simulation, Institut für Kernphysik, and Jülich Center for Hadron Physics,Forschungszentrum Jülich, D-52425 Jülich (Germany); Nogga, A.; Wirzba, A. [Institute for Advanced Simulation, Institut für Kernphysik, and Jülich Center for Hadron Physics,Forschungszentrum Jülich, D-52425 Jülich (Germany); JARA - Forces and Matter Experiments,Forschungszentrum Jülich, D-52425 Jülich (Germany)
2015-03-19
We provide a consistent and complete calculation of the electric dipole moments of the deuteron, helion, and triton in the framework of chiral effective field theory. The CP-conserving and CP-violating interactions are treated on equal footing and we consider CP-violating one-, two-, and three-nucleon operators up to next-to-leading-order in the chiral power counting. In particular, we calculate for the first time EDM contributions induced by the CP-violating three-pion operator. We find that effects of CP-violating nucleon-nucleon contact interactions are larger than those found in previous studies based on phenomenological models for the CP-conserving nucleon-nucleon interactions. Our results which apply to any model of CP violation in the hadronic sector can be used to test various scenarios of CP violation. As examples, we study the implications of our results on the QCD θ-term and the minimal left-right symmetric model.
Nuclear forces and chiral theories
International Nuclear Information System (INIS)
Friar, J.L.; Washington Univ., Seattle, WA
1995-01-01
Recent successes in ab initio calculations of light nuclei (A=2-6) will be reviewed and correlated with the dynamical consequences of chiral symmetry. The tractability of nuclear physics evinced by these results is evidence for that symmetry. The relative importance of three-nucleon forces, four-nucleon forces, multi-pion exchanges, and relativistic corrections will be discussed in the context of effective field theories and dimensional power counting. Isospin violation in the nuclear force will also be discussed in this context
Chiral-glass transition in a diluted dipolar-interaction Heisenberg system
International Nuclear Information System (INIS)
Zhang Kaicheng; Liu Guibin; Zhu Yan
2011-01-01
Recently, numerical simulations reveal that a spin-glass transition can occur in the three-dimensional diluted dipolar system. By defining the chirality of triple spins in a diluted dipolar Heisenberg spin glass, we study the chiral ordering in the system using parallel tempering algorithm and heat bath method. The finite-size scaling analysis reveals that the system undergoes a chiral-glass transition at finite temperature. - Highlights: → We define the chirality in a diluted dipolar Heisenberg system. → The system undergoes a chiral-glass transition at finite temperature. → We extract the critical exponents of the chiral-glass transition.
Helical chirality: a link between local interactions and global topology in DNA.
Directory of Open Access Journals (Sweden)
Youri Timsit
Full Text Available DNA supercoiling plays a major role in many cellular functions. The global DNA conformation is however intimately linked to local DNA-DNA interactions influencing both the physical properties and the biological functions of the supercoiled molecule. Juxtaposition of DNA double helices in ubiquitous crossover arrangements participates in multiple functions such as recombination, gene regulation and DNA packaging. However, little is currently known about how the structure and stability of direct DNA-DNA interactions influence the topological state of DNA. Here, a crystallographic analysis shows that due to the intrinsic helical chirality of DNA, crossovers of opposite handedness exhibit markedly different geometries. While right-handed crossovers are self-fitted by sequence-specific groove-backbone interaction and bridging Mg(2+ sites, left-handed crossovers are juxtaposed by groove-groove interaction. Our previous calculations have shown that the different geometries result in differential stabilisation in solution, in the presence of divalent cations. The present study reveals that the various topological states of the cell are associated with different inter-segmental interactions. While the unstable left-handed crossovers are exclusively formed in negatively supercoiled DNA, stable right-handed crossovers constitute the local signature of an unusual topological state in the cell, such as the positively supercoiled or relaxed DNA. These findings not only provide a simple mechanism for locally sensing the DNA topology but also lead to the prediction that, due to their different tertiary intra-molecular interactions, supercoiled molecules of opposite signs must display markedly different physical properties. Sticky inter-segmental interactions in positively supercoiled or relaxed DNA are expected to greatly slow down the slithering dynamics of DNA. We therefore suggest that the intrinsic helical chirality of DNA may have oriented the early
Measurements of the n->d scattering at 250 MeV and three-nucleon forces
International Nuclear Information System (INIS)
Maeda, Y.; Sakai, H.; Fujita, K.; Hatano, M.; Kamiya, J.; Kawabata, T.; Kuboki, H.; Hatanaka, K.; Okamura, H.; Saito, T.; Sakemi, Y.; Sasano, M.; Sekiguchi, K.; Shimizu, Y.; Suda, K.; Tameshige, Y.; Tamii, A.; Wakasa, T.; Yako, K.; Greenfield, M.B.; Kamada, H.; Witala, H.
2007-01-01
The differential cross sections and the vector analyzing powers for the nd elastic scattering at E n = 250 MeV have been measured for the study of the three-nucleon force (3NF) effects in the Coulomb-free system. To cover a wide angular region, the experiments were performed by using two different methods at the (n, p) facility and at the NTOF facility which constructed at the Research Center for Nuclear Physics (RCNP). The results were compared with theoretical predictions of the Faddeev calculations based on the modern nucleon-nucleon (NN) forces with the three-nucleon force (3NF). The inclusion of 3NFs leads to a good description of the cross section except for the backward angles. The results were also compared with the theoretical predictions with relativistic corrections. The direct data-to-data comparison of the cross sections of the nd and pd was performed
Directory of Open Access Journals (Sweden)
Shimizu Y.
2010-04-01
Full Text Available Measurements of a complete set of deuteron analyzing powers (iT11, T20, T21, T22 for elastic deuteron–proton scattering at 250 MeV/nucleon have been performed with polarized deuteron beams at RIKEN RI Beam Factory. The obtained data are compared with the Faddeev calculations based on the modern nucleon–nucleon forces together with the Tucson-Melbourne’99, and UrbanaIX three nucleon forces.
Chen, Ting; Li, Shu-Ying; Wang, Dong; Wan, Li-Jun
2017-11-01
Noncovalently introducing stereogenic information is a promising approach to embed chirality in achiral molecular systems. However, the interplay of the noncovalently introduced chirality with the intrinsic chirality of molecules or molecular aggregations has rarely been addressed. We report a competitive chiral expression of the noncovalent interaction-mediated chirality induction and the intrinsic stereogenic center-controlled chirality induction in a two-dimensional (2D) molecular assembly at the liquid/solid interface. Two enantiomorphous honeycomb networks are formed by the coassembly of an achiral 5-(benzyloxy)isophthalic acid (BIC) derivative and 1-octanol at the liquid/solid interface. The preferential formation of the globally homochiral assembly can be achieved either by using the chiral analog of 1-octanol, ( S )-6-methyl-1-octanol, as a chiral coadsorber to induce chirality to the BIC assembly via noncovalent hydrogen bonding or by covalently linking a chiral center in the side chain of BIC. Both the chiral coadsorber and the intrinsically chiral BIC derivative can act as a chiral seeds to induce a preferred handedness in the assembly of the achiral BIC derivatives. Furthermore, the noncovalent interaction-mediated chirality induction can restrain or even overrule the manifestation of the intrinsic chirality of the BIC molecule and dominate the handedness of the 2D molecular coassembly. This study provides insight into the interplay of intrinsically chiral centers and external chiral coadsorbers in the chiral induction, transfer, and amplification processes of 2D molecular assembly.
Chiral d -wave superconductivity in a triangular surface lattice mediated by long-range interaction
Cao, Xiaodong; Ayral, Thomas; Zhong, Zhicheng; Parcollet, Olivier; Manske, Dirk; Hansmann, Philipp
2018-04-01
Adatom systems on the Si(111) surface have recently attracted an increasing attention as strongly correlated systems with a rich phase diagram. We study these materials by a single band model on the triangular lattice, including 1 /r long-range interaction. Employing the recently proposed TRILEX method, we find an unconventional superconducting phase of chiral d -wave symmetry in hole-doped systems. Contrary to usual scenarios where charge and spin fluctuations are seen to compete, here the superconductivity is driven simultaneously by both charge and spin fluctuations and crucially relies on the presence of the long-range tail of the interaction. We provide an analysis of the relevant collective bosonic modes and predict how a cumulative charge and spin paring mechanism leads to superconductivity in doped silicon adatom materials.
Induction of axial chirality in divanillin by interaction with bovine serum albumin.
Directory of Open Access Journals (Sweden)
Diego Venturini
Full Text Available Vanillin is a plant secondary metabolite and has numerous beneficial health applications. Divanillin is the homodimer of vanillin and used as a taste enhancer compound and also a promissory anticancer drug. Here, divanillin was synthesized and studied in the context of its interaction with bovine serum albumin (BSA. We found that divanillin acquires axial chirality when complexed with BSA. This chiroptical property was demonstrated by a strong induced circular dichroism (ICD signal. In agreement with this finding, the association constant between BSA and divanillin (3.3 x 105 mol-1L was higher compared to its precursor vanillin (7.3 x 104 mol-1L. The ICD signal was used for evaluation of the association constant, demonstration of the reversibility of the interaction and determination of the binding site, revealing that divanillin has preference for Sudlow's site I in BSA. This property was confirmed by displacement of the fluorescent markers warfarin (site I and dansyl-L-proline (site II. Molecular docking simulation confirmed the higher affinity of divanillin to site I. The highest scored conformation obtained by docking (dihedral angle 242° was used for calculation of the circular dichroism spectrum of divanillin using Time-Dependent Density Functional Theory (TDDFT. The theoretical spectrum showed good similarity with the experimental ICD. In summary, we have demonstrated that by interacting with the chiral cavities in BSA, divanillin became a atropos biphenyl, i.e., the free rotation around the single bound that links the aromatic rings was impeded. This phenomenon can be explained considering the interactions of divanillin with amino acid residues in the binding site of the protein. This chiroptical property can be very useful for studying the effects of divanillin in biological systems. Considering the potential pharmacological application of divanillin, these findings will be helpful for researchers interested in the pharmacological
Lippert, Kai-Alexander; Mukherjee, Chandan; Broschinski, Jan-Philipp; Lippert, Yvonne; Walleck, Stephan; Stammler, Anja; Bögge, Hartmut; Schnack, Jürgen; Glaser, Thorsten
2017-12-18
Single-molecule magnets (SMMs) retain a magnetization without applied magnetic field for a decent time due to an energy barrier U for spin-reversal. Despite the success to increase U, the difficult to control magnetic quantum tunneling often leads to a decreased effective barrier U eff and a fast relaxation. Here, we demonstrate the influence of the exchange coupling on the tunneling probability in two heptanuclear SMMs hosting the same spin-system with the same high spin ground state S t = 21/2. A chirality-induced symmetry reduction leads to a switch of the Mn III -Mn III exchange from antiferromagnetic in the achiral SMM [Mn III 6 Cr III ] 3+ to ferromagnetic in the new chiral SMM RR [Mn III 6 Cr III ] 3+ . Multispin Hamiltonian analysis by full-matrix diagonalization demonstrates that the ferromagnetic interactions in RR [Mn III 6 Cr III ] 3+ enforce a well-defined S t = 21/2 ground state with substantially less mixing of M S substates in contrast to [Mn III 6 Cr III ] 3+ and no tunneling pathways below the top of the energy barrier. This is experimentally verified as U eff is smaller than the calculated energy barrier U in [Mn III 6 Cr III ] 3+ due to tunneling pathways, whereas U eff equals U in RR [Mn III 6 Cr III ] 3+ demonstrating the absence of quantum tunneling.
Scalar mesons and glueballs in a chiral U(3)xU(3) quark model with 't Hooft interaction
International Nuclear Information System (INIS)
Nagy, M.; Volkov, M.K.; Yudichev, V.L.
2000-01-01
In a U(3)xU(3) quark chiral model of the Nambu-Jona-Lasino (NJL) type with the 't Hooft interaction, the ground scalar isoscalar mesons and a scalar glueball are described. The glueball (dilaton) is introduced into the effective meson Lagrangian written in a chirally symmetric form on the basis of scale invariance. The singlet-octet mixing of scalar isoscalar mesons and their mixing with the glueball are taken into account. Mass spectra of the scalar mesons and glueball and their strong decays are described
Chauhan, B.; Kumar, S.; Malik, R. P.
2018-02-01
We derive the off-shell nilpotent (fermionic) (anti-)BRST symmetry transformations by exploiting the (anti-)chiral superfield approach (ACSA) to Becchi-Rouet-Stora-Tyutin (BRST) formalism for the interacting Abelian 1-form gauge theories where there is a coupling between the U(1) Abelian 1-form gauge field and Dirac as well as complex scalar fields. We exploit the (anti-)BRST invariant restrictions on the (anti-)chiral superfields to derive the fermionic symmetries of our present D-dimensional Abelian 1-form gauge theories. The novel observation of our present investigation is the derivation of the absolute anticommutativity of the nilpotent (anti-)BRST charges despite the fact that our ordinary D-dimensional theories are generalized onto the (D,1)-dimensional (anti-) chiral super-submanifolds (of the general (D,2)-dimensional supermanifold) where only the (anti-)chiral super expansions of the (anti-)chiral superfields have been taken into account. We also discuss the nilpotency of the (anti-)BRST charges and (anti-)BRST invariance of the Lagrangian densities of our present theories within the framework of ACSA to BRST formalism.
Lim, Yeunhwan; Holt, Jeremy W.
2017-06-01
We investigate the structure of neutron star crusts, including the crust-core boundary, based on new Skyrme mean field models constrained by the bulk-matter equation of state from chiral effective field theory and the ground-state energies of doubly-magic nuclei. Nuclear pasta phases are studied using both the liquid drop model as well as the Thomas-Fermi approximation. We compare the energy per nucleon for each geometry (spherical nuclei, cylindrical nuclei, nuclear slabs, cylindrical holes, and spherical holes) to obtain the ground state phase as a function of density. We find that the size of the Wigner-Seitz cell depends strongly on the model parameters, especially the coefficients of the density gradient interaction terms. We employ also the thermodynamic instability method to check the validity of the numerical solutions based on energy comparisons.
Energy Technology Data Exchange (ETDEWEB)
Krueger, Thomas
2016-10-19
The physics of neutron-rich systems is of great interest in nuclear and astrophysics. Precise knowledge of the properties of neutron-rich nuclei is crucial for understanding the synthesis of heavy elements. Infinite neutron matter determines properties of neutron stars, a final stage of heavy stars after a core-collapse supernova. It also provides a unique theoretical laboratory for nuclear forces. Strong interactions are determined by quantum chromodynamics (QCD). However, QCD is non-perturbative at low energies and one presently cannot directly calculate nuclear forces from it. Chiral effective field theory circumvents these problems and connects the symmetries of QCD to nuclear interactions. It naturally and systematically includes many-nucleon forces and gives access to uncertainty estimates. We use chiral interactions throughout all calculation in this thesis. Neutron stars are very extreme objects. The densities in their interior greatly exceed those in nuclei. The exact composition and properties of neutron stars is still unclear but they consist mainly of neutrons. One can explore neutron stars theoretically with calculations of neutron matter. In the inner core of neutron stars exist very high densities and thus maybe exotic phases of matter. To investigate whether there exists a phase transition to such phases even at moderate densities we study the chiral condensate in neutron matter, the order parameter of chiral symmetry breaking, and find no evidence for a phase transition at nuclear densities. We also calculate the more extreme system of spin-polarised neutron matter. With this we address the question whether there exists such a polarised phase in neutron stars and also provide a benchmark system for lattice QCD. We find spin-polarised neutron matter to be an almost non-interacting Fermi gas. To understand the cooling of neutron stars neutron pairing is of great importance. Due to the high densities especially triplet pairing is of interest. We
Density-dependent effective baryon–baryon interaction from chiral three-baryon forces
Energy Technology Data Exchange (ETDEWEB)
Petschauer, Stefan, E-mail: stefan.petschauer@ph.tum.de [Physik Department, Technische Universität München, D-85747 Garching (Germany); Haidenbauer, Johann [Institute for Advanced Simulation, Institut für Kernphysik and Jülich Center for Hadron Physics, Forschungszentrum Jülich, D-52425 Jülich (Germany); Kaiser, Norbert [Physik Department, Technische Universität München, D-85747 Garching (Germany); Meißner, Ulf-G. [Institute for Advanced Simulation, Institut für Kernphysik and Jülich Center for Hadron Physics, Forschungszentrum Jülich, D-52425 Jülich (Germany); Helmholtz-Institut für Strahlen- und Kernphysik, Universität Bonn, D-53115 Bonn (Germany); Bethe Center for Theoretical Physics, Universität Bonn, D-53115 Bonn (Germany); Weise, Wolfram [Physik Department, Technische Universität München, D-85747 Garching (Germany)
2017-01-15
A density-dependent effective potential for the baryon–baryon interaction in the presence of the (hyper)nuclear medium is constructed, based on the leading (irreducible) three-baryon forces derived within SU(3) chiral effective field theory. We evaluate the contributions from three classes: contact terms, one-pion exchange and two-pion exchange. In the strangeness-zero sector we recover the known result for the in-medium nucleon–nucleon interaction. Explicit expressions for the ΛN in-medium potential in (asymmetric) nuclear matter are presented. Our results are suitable for implementation into calculations of (hyper)nuclear matter. In order to estimate the low-energy constants of the leading three-baryon forces we introduce the decuplet baryons as explicit degrees of freedom and construct the relevant terms in the minimal non-relativistic Lagrangian. With these, the constants are estimated through decuplet saturation. Utilizing this approximation we provide numerical results for the effect of the three-body force in symmetric nuclear matter and pure neutron matter on the ΛN interaction. A moderate repulsion that increases with density is found in comparison to the free ΛN interaction.
Chirality invariance and 'chiral' fields
International Nuclear Information System (INIS)
Ziino, G.
1978-01-01
The new field model derived in the present paper actually gives a definite answer to three fundamental questions concerning elementary-particle physics: 1) The phenomenological dualism between parity and chirality invariance: it would be only an apparent display of a general 'duality' principle underlying the intrinsic nature itself of (spin 1/2) fermions and expressed by the anticommutativity property between scalar and pseudoscalar charges. 2) The real physical meaning of V - A current structure: it would exclusively be connected to the one (just pointed out) of chiral fields themselves. 3) The unjustified apparent oddness shown by Nature in weak interactions, for the fact of picking out only one of the two (left- and right-handed) fermion 'chiral' projections: the key to such a 'mystery' would just be provided by the consequences of the dual and partial character of the two fermion-antifermion field bases. (Auth.)
Boyd, Richard N.; Kajino, Toshitaka; Onaka, Takashi
2018-01-01
Abstract Previous work has suggested that the chirality of the amino acids could be established in the magnetic field of a nascent neutron star from a core-collapse supernova or massive collapsar. The magnetic field would orient the 14N nuclei, and the alignment of its nuclear spin with respect to those of the electron antineutrinos emitted from the collapsing star would determine the probability of destruction of the 14N nuclei by interactions with the antineutrinos. Subsequent work estimated the bulk polarization of the 14N nuclei in large rotating meteoroids in such an environment. The present work adds a crucial piece of this model by describing the details by which the selective 14N nuclear destruction would produce molecular chiral selectivity. The effects of the neutrino-induced interactions on the 14N nuclei bound in amino acids polarized in strong magnetic fields are studied. It is shown that electric fields in the reference frame of the nuclei modify the magnetic field at the nucleus, creating nuclear magnetizations that are asymmetric in chirality. The antineutrino cross sections depend on this magnetization, creating a selective destructive effect. The environmental conditions and sites in which such a selection mechanism could occur are discussed. Selective destruction of D-enantiomers results in enantiomeric excesses which may be sufficient to drive subsequent autocatalysis necessary to produce the few-percent enantiomeric excesses found in meteorites and subsequent homochirality. Molecular quantum chemical calculations were performed for alanine, and the chirality-dependent effects studied were included. A preference for left-handed molecules was found, and enantiomeric excesses as high as 0.02% were estimated for molecules in the electromagnetic conditions expected from a core-collapse supernova. Key Words: Amino acids—Supernovae—Antineutrinos—Enantiomeric excess—Chirality. Astrobiology 18, 190–206. PMID:29160728
Nuclear matter from chiral effective field theory
International Nuclear Information System (INIS)
Drischler, Christian
2017-01-01
Nuclear matter is an ideal theoretical system that provides key insights into the physics of different length scales. While recent ab initio calculations of medium-mass to heavy nuclei have demonstrated that realistic saturation properties in infinite matter are crucial for reproducing experimental binding energies and charge radii, the nuclear-matter equation of state allows tight constraints on key quantities of neutron stars. In the present thesis we take advantage of both aspects. Chiral effective field theory (EFT) with pion and nucleon degrees of freedom has become the modern low-energy approach to nuclear forces based on the symmetries of quantum chromodynamics, the fundamental theory of strong interactions. The systematic chiral expansion enables improvable calculations associated with theoretical uncertainty estimates. In recent years, chiral many-body forces were derived up to high orders, allowing consistent calculations including all many-body contributions at next-to-next-to-next-to-leading order (N 3 LO). Many further advances have driven the construction of novel chiral potentials with different regularization schemes. Here, we develop advanced methods for microscopic calculations of the equation of state of homogeneous nuclear matter with arbitrary proton-to-neutron ratio at zero temperature. Specifically, we push the limits of many-body perturbation theory (MBPT) considerations to high orders in the chiral and in the many-body expansion. To address the challenging inclusion of three-body forces, we introduce a new partial-wave method for normal ordering that generalizes the treatment of these contributions. We show improved predictions for the neutron-matter equation of state with consistent N 3 LO nucleon-nucleon (NN) plus three-nucleon (3N) potentials using MBPT up to third order and self-consistent Green's function theory. The latter also provides nonperturbative benchmarks for the many-body convergence. In addition, we extend the normal
Nuclear matter from chiral effective field theory
Energy Technology Data Exchange (ETDEWEB)
Drischler, Christian
2017-11-15
Nuclear matter is an ideal theoretical system that provides key insights into the physics of different length scales. While recent ab initio calculations of medium-mass to heavy nuclei have demonstrated that realistic saturation properties in infinite matter are crucial for reproducing experimental binding energies and charge radii, the nuclear-matter equation of state allows tight constraints on key quantities of neutron stars. In the present thesis we take advantage of both aspects. Chiral effective field theory (EFT) with pion and nucleon degrees of freedom has become the modern low-energy approach to nuclear forces based on the symmetries of quantum chromodynamics, the fundamental theory of strong interactions. The systematic chiral expansion enables improvable calculations associated with theoretical uncertainty estimates. In recent years, chiral many-body forces were derived up to high orders, allowing consistent calculations including all many-body contributions at next-to-next-to-next-to-leading order (N{sup 3}LO). Many further advances have driven the construction of novel chiral potentials with different regularization schemes. Here, we develop advanced methods for microscopic calculations of the equation of state of homogeneous nuclear matter with arbitrary proton-to-neutron ratio at zero temperature. Specifically, we push the limits of many-body perturbation theory (MBPT) considerations to high orders in the chiral and in the many-body expansion. To address the challenging inclusion of three-body forces, we introduce a new partial-wave method for normal ordering that generalizes the treatment of these contributions. We show improved predictions for the neutron-matter equation of state with consistent N{sup 3}LO nucleon-nucleon (NN) plus three-nucleon (3N) potentials using MBPT up to third order and self-consistent Green's function theory. The latter also provides nonperturbative benchmarks for the many-body convergence. In addition, we extend the
The nucleon-nucleon interaction from a realistic pseudoscalar-vector chiral lagrangian
International Nuclear Information System (INIS)
Kaiser, N.; Meissner, U.G.; Massachusetts Inst. of Tech., Cambridge
1990-01-01
We investigate the static nucleon-nucleon potential in the framework of a non-linear chiral meson theory. The model includes pions as well as the vector mesons ρ and ω. All parameters are fixed in the meson sector and predictions about the nucleon-nucleon interaction follow without adjusting any parameters. We use an S-matrix approach to calculate correlated two-pion exchange between two solitons. The most prominent feature of this two-pion exchange is that it leads very natural to attraction in the scalar-isoscalar channel. We also discuss the effect of πp correlations on the central potential, and present the spectral function related to the correlated two-pion exchange. Furthermore, we study the form factors of the nucleon sources related to the two-pion exchange and find that they are of dipole type with typical cutoff scales Λ D ≅ 700 MeV. We also discuss the destructive interference of π- and ρ-exchange in the isovector tensor potential. Altogether, we present a unified treatment of meson exchange phenomenology based on a serious model of the nucleon. Finally, we point out the limitations of the model and discuss some further applications. (orig.)
Jauffred, Liselotte; Munk Vejborg, Rebecca; Korolev, Kirill S; Brown, Stanley; Oddershede, Lene B
2017-01-01
From microbial biofilms to human migrations, spatial competition is central to the evolutionary history of many species. The boundary between expanding populations is the focal point of competition for space and resources and is of particular interest in ecology. For all Escherichia coli strains studied here, these boundaries move in a counterclockwise direction even when the competing strains have the same fitness. We find that chiral growth of bacterial colonies is strongly suppressed by the expression of extracellular features such as adhesive structures and pili. Experiments with other microbial species show that chiral growth is found in other bacteria and exclude cell wall biosynthesis and anisotropic shape as the primary causes of chirality. Instead, intimate contact with the substratum is necessary for chirality. Our results demonstrate that through a handful of surface molecules cells can fundamentally reorganize their migration patterns, which might affect intra- and interspecific competitions through colony morphology or other mechanisms. PMID:28362723
Three-body forces in nuclear matter from intermediate Δ-states in three-nucleon clusters
International Nuclear Information System (INIS)
Kouki, T.; Smulter, L.E.W.; Green, A.M.
1976-10-01
The three-body force contribution in nuclear matter is treated as a three-nucleon cluster, in which one of the nucleons becomes, in an intermediate state, a Δ(1236). All exchange diagrams are calculated and found to significantly reduce the energy per particle from the direct graph. This is contrary to earlier estimates of the exchanges, using more approximate approaches. The resulting attractive contribution is rather small, -1.1 MeV at ksub(F)=1.4 fm -1 , but the roughly linear density dependence has a crucial effect on the saturation properties. The sensitivity of the results to the correlations used, and to the two-body force spin structure, is displayed. The energy per particle from clusters with three intermediate Δ's is also estimated. (author)
Bag-model motivated NN potentials and the three-nucleon system
International Nuclear Information System (INIS)
Grach, I.L.; Narodetskij, I.M.
1986-01-01
Few examples are presented of the short-range energy-dependent NN potentials derived in the quark compound bag model which satisfy the classical causality condition and show that for the radii of the NN interactions b=1.35-1.40 fm these potentials reproduce the trinucleon binding energy
Tews, I.; Carlson, J.; Gandolfi, S.; Reddy, S.
2018-06-01
The dense matter equation of state (EOS) determines neutron star (NS) structure but can be calculated reliably only up to one to two times the nuclear saturation density, using accurate many-body methods that employ nuclear interactions from chiral effective field theory constrained by scattering data. In this work, we use physically motivated ansatzes for the speed of sound c S at high density to extend microscopic calculations of neutron-rich matter to the highest densities encountered in stable NS cores. We show how existing and expected astrophysical constraints on NS masses and radii from X-ray observations can constrain the speed of sound in the NS core. We confirm earlier expectations that c S is likely to violate the conformal limit of {c}S2≤slant {c}2/3, possibly reaching values closer to the speed of light c at a few times the nuclear saturation density, independent of the nuclear Hamiltonian. If QCD obeys the conformal limit, we conclude that the rapid increase of c S required to accommodate a 2 M ⊙ NS suggests a form of strongly interacting matter where a description in terms of nucleons will be unwieldy, even between one and two times the nuclear saturation density. For typical NSs with masses in the range of 1.2–1.4 M ⊙, we find radii between 10 and 14 km, and the smallest possible radius of a 1.4 M ⊙ NS consistent with constraints from nuclear physics and observations is 8.4 km. We also discuss how future observations could constrain the EOS and guide theoretical developments in nuclear physics.
Fürthauer, S; Strempel, M; Grill, S W; Jülicher, F
2012-09-01
Active processes in biological systems often exhibit chiral asymmetries. Examples are the chirality of cytoskeletal filaments which interact with motor proteins, the chirality of the beat of cilia and flagella as well as the helical trajectories of many biological microswimmers. Here, we derive constitutive material equations for active fluids which account for the effects of active chiral processes. We identify active contributions to the antisymmetric part of the stress as well as active angular momentum fluxes. We discuss four types of elementary chiral motors and their effects on a surrounding fluid. We show that large-scale chiral flows can result from the collective behavior of such motors even in cases where isolated motors do not create a hydrodynamic far field.
Recent results in the theory of the three-nucleon systems
International Nuclear Information System (INIS)
Friar, J.L.
1987-06-01
This paper concentrates on calculational results obtained by the Los Alamos-Iowa Faddeev group and on related calculations. Most of the interest of this group has centered on the Helium 3 and Hydrogen 3 ground states, including the effects of the Coulomb interactions between the two protons in Helium 3. Recent progress in treating the alpha particle is reported and zero energy n-d and p-d scattering and an improved understanding of the scattering lengths for these systems are also discussed. Simple physical pictures for these results are presented where possible. 54 refs., 9 figs
Bombaci, Ignazio; Logoteta, Domenico
2018-02-01
Aims: We report a new microscopic equation of state (EOS) of dense symmetric nuclear matter, pure neutron matter, and asymmetric and β-stable nuclear matter at zero temperature using recent realistic two-body and three-body nuclear interactions derived in the framework of chiral perturbation theory (ChPT) and including the Δ(1232) isobar intermediate state. This EOS is provided in tabular form and in parametrized form ready for use in numerical general relativity simulations of binary neutron star merging. Here we use our new EOS for β-stable nuclear matter to compute various structural properties of non-rotating neutron stars. Methods: The EOS is derived using the Brueckner-Bethe-Goldstone quantum many-body theory in the Brueckner-Hartree-Fock approximation. Neutron star properties are next computed solving numerically the Tolman-Oppenheimer-Volkov structure equations. Results: Our EOS models are able to reproduce the empirical saturation point of symmetric nuclear matter, the symmetry energy Esym, and its slope parameter L at the empirical saturation density n0. In addition, our EOS models are compatible with experimental data from collisions between heavy nuclei at energies ranging from a few tens of MeV up to several hundreds of MeV per nucleon. These experiments provide a selective test for constraining the nuclear EOS up to 4n0. Our EOS models are consistent with present measured neutron star masses and particularly with the mass M = 2.01 ± 0.04 M⊙ of the neutron stars in PSR J0348+0432.
Zhu, Hanyu; Yi, Jun; Li, Ming-yang; Xiao, Jun; Zhang, Lifa; Yang, Chih-Wen; Kaindl, Robert A.; Li, Lain-Jong; Wang, Yuan; Zhang, Xiang
2018-01-01
Chirality reveals symmetry breaking of the fundamental interaction of elementary particles. In condensed matter, for example, the chirality of electrons governs many unconventional transport phenomena such as the quantum Hall effect. Here we show that phonons can exhibit intrinsic chirality in monolayer tungsten diselenide. The broken inversion symmetry of the lattice lifts the degeneracy of clockwise and counterclockwise phonon modes at the corners of the Brillouin zone. We identified the phonons by the intervalley transfer of holes through hole-phonon interactions during the indirect infrared absorption, and we confirmed their chirality by the infrared circular dichroism arising from pseudoangular momentum conservation. The chiral phonons are important for electron-phonon coupling in solids, phonon-driven topological states, and energy-efficient information processing.
Zhu, Hanyu
2018-02-01
Chirality reveals symmetry breaking of the fundamental interaction of elementary particles. In condensed matter, for example, the chirality of electrons governs many unconventional transport phenomena such as the quantum Hall effect. Here we show that phonons can exhibit intrinsic chirality in monolayer tungsten diselenide. The broken inversion symmetry of the lattice lifts the degeneracy of clockwise and counterclockwise phonon modes at the corners of the Brillouin zone. We identified the phonons by the intervalley transfer of holes through hole-phonon interactions during the indirect infrared absorption, and we confirmed their chirality by the infrared circular dichroism arising from pseudoangular momentum conservation. The chiral phonons are important for electron-phonon coupling in solids, phonon-driven topological states, and energy-efficient information processing.
The η′N interaction from a chiral effective model and η′-N bound state
International Nuclear Information System (INIS)
Sakai, Shuntaro; Jido, Daisuke
2015-01-01
The η ′ mass reduction in the nuclear medium is expected owing to the degeneracy of the pseudoscalar-singlet and octet mesons in the restoration of the spontaneous chiral symmetry breaking. In this study, we investigate the η ′ N 2body interaction, which is the fundamental interaction of the in-medium η ′ properties, using the linear sigma model as a chiral effective model. The η ′ N interaction in the linear sigma model comes from the scalar meson exchange with U A (1) symmetry effect and is found to be fairly strong attraction. The transition amplitude of η ′ N to the ηN channel is relatively small compared to that of elastic channel. From the analysis of the η ′ N 2body system, we find a η ′ N bound state with the binding energy 12.3-3.3iMeV. We expect that this strongly attractive two body interaction leads to a deep and attractive optical potential
Cross Sections of the Deuteron-Proton Breakup at 130 MeV : A Probe of Three-Nucleon System Dynamics
Kistryn, St.; Stephan, E.; Kalantar-Nayestanaki, N.; Biegun, A.; Bodek, K.; Ciepal, I.; Deltuva, A.; Eslami-Kalantari, M.; Fonseca, A. C.; Kis, M.; Klos, B.; Kozela, A.; Mahjour-Shafiei, M.; Messchendorp, J.; Micherdzinska, A.; Parol, W.; Ramazani-Moghaddam-Arani, A.; Sworst, R.; Zejma, J.
Three-nucleon system dynamics can be investigated quantitatively by comparing observables calculated with the use of Faddeev equations with results of precise measurements. Proper description of the experimental data can be achieved only if the dynamical models include, in addition to the
Interacting fermions in rotation: chiral symmetry restoration, moment of inertia and thermodynamics
International Nuclear Information System (INIS)
Chernodub, M.N.; Gongyo, Shinya
2017-01-01
We study rotating fermionic matter at finite temperature in the framework of the Nambu-Jona-Lasinio model. In order to respect causality the rigidly rotating system must be bound by a cylindrical boundary with appropriate boundary conditions that confine the fermions inside the cylinder. We show the finite geometry with the MIT boundary conditions affects strongly the phase structure of the model leading to three distinct regions characterized by explicitly broken (gapped), partially restored (nearly gapless) and spontaneously broken (gapped) phases at, respectively, small, moderate and large radius of the cylinder. The presence of the boundary leads to specific steplike irregularities of the chiral condensate as functions of coupling constant, temperature and angular frequency. These steplike features have the same nature as the Shubnikov-de Haas oscillations with the crucial difference that they occur in the absence of both external magnetic field and Fermi surface. At finite temperature the rotation leads to restoration of spontaneously broken chiral symmetry while the vacuum at zero temperature is insensitive to rotation (“cold vacuum cannot rotate”). As the temperature increases the critical angular frequency decreases and the transition becomes softer. A phase diagram in angular frequency-temperature plane is presented. We also show that at fixed temperature the fermion matter in the chirally restored (gapless) phase has a higher moment of inertia compared to the one in the chirally broken (gapped) phase.
Interacting fermions in rotation: chiral symmetry restoration, moment of inertia and thermodynamics
Energy Technology Data Exchange (ETDEWEB)
Chernodub, M.N. [CNRS, Laboratoire de Mathématiques et Physique Théorique, Université de Tours,Tours (France); Laboratory of Physics of Living Matter, Far Eastern Federal University,Vladivostok (Russian Federation); Gongyo, Shinya [CNRS, Laboratoire de Mathématiques et Physique Théorique, Université de Tours,Tours (France); Theoretical Research Division, Nishina Center, RIKEN,Saitama (Japan)
2017-01-30
We study rotating fermionic matter at finite temperature in the framework of the Nambu-Jona-Lasinio model. In order to respect causality the rigidly rotating system must be bound by a cylindrical boundary with appropriate boundary conditions that confine the fermions inside the cylinder. We show the finite geometry with the MIT boundary conditions affects strongly the phase structure of the model leading to three distinct regions characterized by explicitly broken (gapped), partially restored (nearly gapless) and spontaneously broken (gapped) phases at, respectively, small, moderate and large radius of the cylinder. The presence of the boundary leads to specific steplike irregularities of the chiral condensate as functions of coupling constant, temperature and angular frequency. These steplike features have the same nature as the Shubnikov-de Haas oscillations with the crucial difference that they occur in the absence of both external magnetic field and Fermi surface. At finite temperature the rotation leads to restoration of spontaneously broken chiral symmetry while the vacuum at zero temperature is insensitive to rotation (“cold vacuum cannot rotate”). As the temperature increases the critical angular frequency decreases and the transition becomes softer. A phase diagram in angular frequency-temperature plane is presented. We also show that at fixed temperature the fermion matter in the chirally restored (gapless) phase has a higher moment of inertia compared to the one in the chirally broken (gapped) phase.
Energy Technology Data Exchange (ETDEWEB)
Yuanda, Wang; Xiuming, Bao; Zhiqiang, Mao; Rongfang, Yuan; Keling, Wen; Binyin, Huang; Zhifu, Wang; Shuming, Li; Jianan, Wang; Zuxun, Sun; others, and
1985-11-01
The differential cross sections are measured using 26.0 MeV ..cap alpha.. particle for /sup 58,62/Ni(..cap alpha.., ..cap alpha..) /sup 58,62/Ni and /sup 58,62/Ni(..cap alpha..,p) /sup 61,65/Cu reactions as well as 25.4 MeV ..cap alpha.. particle for /sup 60/Ni(..cap alpha.., ..cap alpha..)/sup 69/Ni and /sup 60/Ni(..cap alpha.., p)/sup 63/Cu reactions. Consistent calculations with optical model and ZR DWBA are made for (..cap alpha.., ..cap alpha..) and (..cap alpha.., p) reactions by using of single, two, three and four nucleon optical potential parameters. For elastic scattering due to the ..cap alpha.. optical potential ambiguities, all the above optical potential can reproduce the experimental angular distributions. However, the single, two and three nucleon potential, including the Baird's mass systematics and the Chang's energy systematics of ..cap alpha.. potentials, obviously can not provide a reasonable fitting with the (..cap alpha..,p) reaction experimental data. Only the results from the four nucleon potential is in good agreement with the (..cap alpha..,p) reaction experimental data. This reveals that in the ..cap alpha..-particle induced transfer reactions, the real depth of the ..cap alpha..-nucleus optical potential should be rather deep.
International Nuclear Information System (INIS)
Melde, T.; Canton, L.; Svenne, J.P.
2002-01-01
We formulate the three-body problem in one dimension in terms of the (Faddeev-type) integral equation approach. As an application, we develop a spinless, one-dimensional (1-D) model that mimics three-nucleon dynamics in one dimension. Using simple two-body potentials that reproduce the deuteron binding, we obtain that the three-body system binds at about 7.5 MeV. We then consider two types of residual pionic corrections in the dynamical equation; one related to the 2π-exchange three-body diagram, the other to the 1π-exchange three-body diagram. We find that the first contribution can produce an additional binding effect of about 0.9 MeV. The second term produces smaller binding effects, which are, however, dependent on the uncertainty in the off-shell extrapolation of the two-body t-matrix. This presents interesting analogies with what occurs in three dimensions. The paper also discusses the general three-particle quantum scattering problem, for motion restricted to the fall line. (author)
Neutron matter at next-to-next-to-next-to-leading order in chiral effective field theory.
Tews, I; Krüger, T; Hebeler, K; Schwenk, A
2013-01-18
Neutron matter presents a unique system for chiral effective field theory because all many-body forces among neutrons are predicted to next-to-next-to-next-to-leading order (N(3)LO). We present the first complete N(3)LO calculation of the neutron matter energy. This includes the subleading three-nucleon forces for the first time and all leading four-nucleon forces. We find relatively large contributions from N(3)LO three-nucleon forces. Our results provide constraints for neutron-rich matter in astrophysics with controlled theoretical uncertainties.
International Nuclear Information System (INIS)
Conte, E.; Pieralice, M.
1987-01-01
An investigation on the chirality of the positrons from 22 Na and on their asymmetrical interactions with D-, L-, and DL-alanines was carried out. By using nuclear gamma-spectroscopy, the asymmetrical interaction was proved to be induced with a distinguishably asymmetrical effect
Elastic nucleon-deuteron scattering and breakup with chiral forces
Directory of Open Access Journals (Sweden)
Witała Henryk
2016-01-01
Full Text Available Results on three-nucleon (3N elastic scattering and breakup below the pion production threshold are discussed. The large discrepancies found between a theory based on numerical solutions of 3N Faddeev equations with standard nucleon-nucleon (NN potentials only and data point to the need for three-nucleon forces (3NF’s. This notion is supported by the fact that another possible reason for the discrepancies in elastic nucleon-deuteron (Nd scattering, relativistic effects, turned out to be small. Results for a new generation of chiral NN forces (up to N4LO together with theoretical truncation errors are shown. They support conclusions obtained with standard NN potentials
Chiral recognition in separation science: an overview.
Scriba, Gerhard K E
2013-01-01
Chiral recognition phenomena play an important role in nature as well as analytical separation sciences. In separation sciences such as chromatography and capillary electrophoresis, enantiospecific interactions between the enantiomers of an analyte and the chiral selector are required in order to observe enantioseparations. Due to the large structural variety of chiral selectors applied, different mechanisms and structural features contribute to the chiral recognition process. This chapter briefly illustrates the current models of the enantiospecific recognition on the structural basics of various chiral selectors.
Tensor Fermi liquid parameters in nuclear matter from chiral effective field theory
Holt, J. W.; Kaiser, N.; Whitehead, T. R.
2018-05-01
We compute from chiral two- and three-body forces the complete quasiparticle interaction in symmetric nuclear matter up to twice nuclear matter saturation density. Second-order perturbative contributions that account for Pauli blocking and medium polarization are included, allowing for an exploration of the full set of central and noncentral operator structures permitted by symmetries and the long-wavelength limit. At the Hartree-Fock level, the next-to-next-to-leading order three-nucleon force contributes to all noncentral interactions, and their strengths grow approximately linearly with the nucleon density up to that of saturated nuclear matter. Three-body forces are shown to enhance the already strong proton-neutron effective tensor interaction, while the corresponding like-particle tensor force remains small. We also find a large isovector cross-vector interaction but small center-of-mass tensor interactions in the isoscalar and isovector channels. The convergence of the expansion of the noncentral quasiparticle interaction in Landau parameters and Legendre polynomials is studied in detail.
Kohno, M.
2018-03-01
Adopting hyperon-nucleon and hyperon-nucleon-nucleon interactions parametrized in chiral effective field theory, single-particle potentials of the Λ and Σ hyperons are evaluated in symmetric nuclear matter and in pure neutron matter within the framework of lowest-order Bruckner theory. The chiral NLO interaction bears strong Λ N -Σ N coupling. Although the Λ potential is repulsive if the coupling is switched off, the Λ N -Σ N correlation brings about the attraction consistent with empirical data. The Σ potential is repulsive, which is also consistent with empirical information. The interesting result is that the Λ potential becomes shallower beyond normal density. This provides the possibility of solving the hyperon puzzle without introducing ad hoc assumptions. The effects of the Λ N N -Λ N N and Λ N N -Σ N N three-baryon forces are considered. These three-baryon forces are first reduced to normal-ordered effective two-baryon interactions in nuclear matter and then incorporated in the G -matrix equation. The repulsion from the Λ N N -Λ N N interaction is of the order of 5 MeV at normal density and becomes larger with increasing density. The effects of the Λ N N -Σ N N coupling compensate the repulsion at normal density. The net effect of the three-baryon interactions on the Λ single-particle potential is repulsive at higher densities.
Sandratskii, L. M.
2017-07-01
The purpose of the paper is to gain deeper insight into microscopic formation of the Dzyaloshinskii-Moriya interaction (DMI). The paper aims at the development of the physical picture able to address apparently contradicting conclusions of recent studies concerning the location of the DMI energy in the real and reciprocal spaces as well as the relation between values of the atomic moments and the DMI strength. The main tools of our study are the first-principles calculations of the energies of the spiral magnetic states with opposite chiralities. We suggest a method of the calculation of the spiral structures with account for the spin-orbit coupling (SOC). It is based on the application of the generalized Bloch theorem and generalized Bloch functions and allows to reduce the consideration of arbitrary incommensurate spiral to small chemical unit cell. The method neglects the anisotropy in the plane orthogonal to the rotation axis of the spirals that does not influence importantly the DMI energy. For comparison, the supercell calculation with full account for the SOC is performed. The concrete calculations are performed for the Co/Pt bilayer. We consider the distribution of the DMI energy in both real and reciprocal spaces and the dependence of the DMI on the number of electrons. The results of the calculations reveal a number of energy compensations in the formation of the DMI. Thus, the partial atomic contributions as functions of the spiral wave vector q are nonmonotonic and have strongly varying slopes. However, in the total DMI energy these atom-related features compensate each other, resulting in a smooth q dependence. The reason for the peculiar form of the partial DMI contributions is a q -dependent difference in the charge distribution between q and -q spirals. The strongly q -dependent relation between atomic contributions shows that the real-space distribution of the DMI energy obtained for a selected q value cannot be considered as a general
Chirality in molecular collision dynamics
Lombardi, Andrea; Palazzetti, Federico
2018-02-01
Chirality is a phenomenon that permeates the natural world, with implications for atomic and molecular physics, for fundamental forces and for the mechanisms at the origin of the early evolution of life and biomolecular homochirality. The manifestations of chirality in chemistry and biochemistry are numerous, the striking ones being chiral recognition and asymmetric synthesis with important applications in molecular sciences and in industrial and pharmaceutical chemistry. Chiral discrimination phenomena, due to the existence of two enantiomeric forms, very well known in the case of interaction with light, but still nearly disregarded in molecular collision studies. Here we review some ideas and recent advances about the role of chirality in molecular collisions, designing and illustrating molecular beam experiments for the demonstration of chiral effects and suggesting a scenario for a stereo-directional origin of chiral selection.
International Nuclear Information System (INIS)
Musakhanov, M.M.
1980-01-01
The chiral bag model is considered. It is suggested that pions interact only with the surface of a quark ''bag'' and do not penetrate inside. In the case of a large bag the pion field is rather weak and goes to the linearized chiral bag model. Within that model the baryon mass spectrum, β decay axial constant, magnetic moments of baryons, pion-baryon coupling constants and their form factors are calculated. It is shown that pion corrections to the calculations according to the chiral bag model is essential. The obtained results are found to be in a reasonable agreement with the experimental data
Dai, Ling-Yun; Haidenbauer, Johann; Meißner, Ulf-G.
2017-07-01
Results for the antinucleon-nucleon (\\overline{N}N) interaction obtained at next-to-next-to-next-to-leading order in chiral effective field theory (EFT) are reported. A new local regularization scheme is used for the pion-exchange contributions that has been recently suggested and applied in a pertinent study of the N N force within chiral EFT. Furthermore, an alternative strategy for estimating the uncertainty is utilized that no longer depends on a variation of the cutoffs. The low-energy constants associated with the arising contact terms are fixed by a fit to the phase shifts and inelasticities provided by a phase-shift analysis of \\overline{p}p scattering data. An excellent description of the \\overline{N}N amplitudes is achieved at the highest order considered. Moreover, because of the quantitative reproduction of partial waves up to J = 3, there is also a nice agreement on the level of \\overline{p}p observables. Specifically, total and integrated elastic and charge-exchange cross sections agree well with the results from the partial-wave analysis up to laboratory energies of 300 MeV, while differential cross sections and analyzing powers are described quantitatively up to 200-250 MeV. The low-energy structure of the \\overline{N}N amplitudes is also considered and compared to data from antiprotonic hydrogen.
Scalar ΛN and ΛΛ interaction in a chiral unitary approach
International Nuclear Information System (INIS)
Sasaki, K.; Oset, E.; Vacas, M. J. Vicente
2006-01-01
We study the central part of the ΛN and ΛΛ potential by considering the correlated and uncorrelated two-meson exchange in addition to the ω exchange contribution. The correlated two-meson exchange is evaluated within a chiral unitary approach. We find that a short-range repulsion is generated by the correlated two-meson potential, which also produces an attraction in the intermediate-distance region. The uncorrelated two-meson exchange produces a sizable attraction in all cases that is counterbalanced by the ω exchange contribution
Collective excitations with chiral NN+3N interactions from coupled-cluster and in-medium SRG
International Nuclear Information System (INIS)
Trippel, Richard
2016-01-01
A broad variety of many-body methods exists for the investigation of ground-state properties, ranging from sophisticated ab initio approaches to traditional, phenomenological models. The description of low-lying excited states of medium-mass nuclei with ab initio methods has also become possible through recent progress in many-body theory. For collective modes at higher energies, however, these methods usually cannot be applied. Therefore, when describing collective excitations either completely phenomenological, macroscopic models are employed or microscopic models using phenomenological interactions. One of the microscopic models well suited for the calculation of collective properties is the random-phase approximation (RPA). In the past, the use of phenomenological interactions for RPA has shown promising results. However, the application of chiral NN interactions yielded transitions at significantly too high energies, far from agreement with experimental data. This thesis focuses on the description of collective modes using both RPA and its second-order extension, SRPA. In contrast to previous research endeavors, we employ chiral NN+3N interactions. The use of chiral interactions is an important first step for describing ground-state, excitation and collective properties on an equal foundation. We find that the inclusion of 3N terms is crucial for RPA calculations and the prediction for collective modes is drastically improved through the 3N terms. For SRPA we show first-ever results with chiral interactions, again leading to an improvement in the predictions. For a successful ab initio description of ground-state properties the inclusion of correlations is of paramount importance. Past RPA calculations have been performed using the quasi-boson approximation, effectively neglecting ground-state correlations. Using RPA, the next step along the path towards an ab initio description of collective properties will, therefore, be the inclusion of correlations. To
Collective excitations with chiral NN+3N interactions from coupled-cluster and in-medium SRG
Energy Technology Data Exchange (ETDEWEB)
Trippel, Richard
2016-12-19
A broad variety of many-body methods exists for the investigation of ground-state properties, ranging from sophisticated ab initio approaches to traditional, phenomenological models. The description of low-lying excited states of medium-mass nuclei with ab initio methods has also become possible through recent progress in many-body theory. For collective modes at higher energies, however, these methods usually cannot be applied. Therefore, when describing collective excitations either completely phenomenological, macroscopic models are employed or microscopic models using phenomenological interactions. One of the microscopic models well suited for the calculation of collective properties is the random-phase approximation (RPA). In the past, the use of phenomenological interactions for RPA has shown promising results. However, the application of chiral NN interactions yielded transitions at significantly too high energies, far from agreement with experimental data. This thesis focuses on the description of collective modes using both RPA and its second-order extension, SRPA. In contrast to previous research endeavors, we employ chiral NN+3N interactions. The use of chiral interactions is an important first step for describing ground-state, excitation and collective properties on an equal foundation. We find that the inclusion of 3N terms is crucial for RPA calculations and the prediction for collective modes is drastically improved through the 3N terms. For SRPA we show first-ever results with chiral interactions, again leading to an improvement in the predictions. For a successful ab initio description of ground-state properties the inclusion of correlations is of paramount importance. Past RPA calculations have been performed using the quasi-boson approximation, effectively neglecting ground-state correlations. Using RPA, the next step along the path towards an ab initio description of collective properties will, therefore, be the inclusion of correlations. To
Variational approach to chiral quark models
Energy Technology Data Exchange (ETDEWEB)
Futami, Yasuhiko; Odajima, Yasuhiko; Suzuki, Akira
1987-03-01
A variational approach is applied to a chiral quark model to test the validity of the perturbative treatment of the pion-quark interaction based on the chiral symmetry principle. It is indispensably related to the chiral symmetry breaking radius if the pion-quark interaction can be regarded as a perturbation.
A variational approach to chiral quark models
International Nuclear Information System (INIS)
Futami, Yasuhiko; Odajima, Yasuhiko; Suzuki, Akira.
1987-01-01
A variational approach is applied to a chiral quark model to test the validity of the perturbative treatment of the pion-quark interaction based on the chiral symmetry principle. It is indispensably related to the chiral symmetry breaking radius if the pion-quark interaction can be regarded as a perturbation. (author)
Chiral Responsive Liquid Quantum Dots.
Zhang, Jin; Ma, Junkai; Shi, Fangdan; Tian, Demei; Li, Haibing
2017-08-01
How to convert the weak chiral-interaction into the macroscopic properties of materials remains a huge challenge. Here, this study develops highly fluorescent, selectively chiral-responsive liquid quantum dots (liquid QDs) based on the hydrophobic interaction between the chiral chains and the oleic acid-stabilized QDs, which have been designated as (S)-1810-QDs. The fluorescence spectrum and liquidity of thermal control demonstrate the fluorescence properties and the fluidic behavior of (S)-1810-QDs in the solvent-free state. Especially, (S)-1810-QDs exhibit a highly chiral-selective response toward (1R, 2S)-2-amino-1,2-diphenyl ethanol. It is anticipated that this study will facilitate the construction of smart chiral fluidic sensors. More importantly, (S)-1810-QDs can become an attractive material for chiral separation. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Directory of Open Access Journals (Sweden)
Bratkovskaya E.L.
2018-01-01
Full Text Available The effect of the chiral symmetry restoration (CSR on observables from heavy-ion collisions is studied in the energy range sNN=3–20 GeV within the Parton-Hadron-String Dynamics (PHSD transport approach. The PHSD includes the deconfinement phase transition as well as essential aspects of CSR in the dense and hot hadronic medium, which are incorporated in the Schwinger mechanism for the hadronic particle production. We adopt different parametrizations of the nuclear equation of state from the non-linear σ - ω model, which enter in the computation of the quark scalar density for the CSR mechanism, in order to estimate the uncertainty in our calculations. For the pion-nucleon ∑-term we adopt ∑π ≈ 45 MeV which corresponds to a ’world average’. Our systematic studies show that chiral symmetry restoration plays a crucial role in the description of heavy-ion collisions at sNN=3–20 GeV, realizing an increase of the hadronic particle production in the strangeness sector with respect to the non-strange one. We identify particle abundances and rapidity spectra to be suitable probes in order to extract information about CSR, while transverse mass spectra are less sensitive ones. Our results provide a microscopic explanation for the "horn" structure in the excitation function of the K+/π+ ratio: the CSR in the hadronic phase produces the steep increase of this particle ratio up to sNN ≈ 7 GeV, while the drop at higher energies is associated to the appearance of a deconfined partonic medium.
Bratkovskaya, E. L.; Moreau, P.; Palmese, A.; Cassing, W.; Seifert, E.; Steinert, T.
2018-02-01
The effect of the chiral symmetry restoration (CSR) on observables from heavy-ion collisions is studied in the energy range =3-20 GeV within the Parton-Hadron-String Dynamics (PHSD) transport approach. The PHSD includes the deconfinement phase transition as well as essential aspects of CSR in the dense and hot hadronic medium, which are incorporated in the Schwinger mechanism for the hadronic particle production. We adopt different parametrizations of the nuclear equation of state from the non-linear σ - ω model, which enter in the computation of the quark scalar density for the CSR mechanism, in order to estimate the uncertainty in our calculations. For the pion-nucleon ∑-term we adopt ∑π ≈ 45 MeV which corresponds to a 'world average'. Our systematic studies show that chiral symmetry restoration plays a crucial role in the description of heavy-ion collisions at =3-20 GeV, realizing an increase of the hadronic particle production in the strangeness sector with respect to the non-strange one. We identify particle abundances and rapidity spectra to be suitable probes in order to extract information about CSR, while transverse mass spectra are less sensitive ones. Our results provide a microscopic explanation for the "horn" structure in the excitation function of the K+/π+ ratio: the CSR in the hadronic phase produces the steep increase of this particle ratio up to ≈ 7 GeV, while the drop at higher energies is associated to the appearance of a deconfined partonic medium.
Directory of Open Access Journals (Sweden)
Saeed Najafi
2016-09-01
Full Text Available Knots appear frequently in semiflexible (biopolymers, including double-stranded DNA, and their presence can affect the polymer’s physical and functional properties. In particular, it is possible and indeed often the case that multiple knots appear on a single chain, with effects which have only come under scrutiny in the last few years. In this manuscript, we study the interaction of two knots on a stretched semiflexible polymer, expanding some recent results on the topic. Specifically, we consider an idealization of a typical optical tweezers experiment and show how the bending rigidity of the chain—And consequently its persistence length—Influences the distribution of the entanglements; possibly more importantly, we observe and report how the relative chirality of the otherwise identical knots substantially modifies their interaction. We analyze the free energy of the chain and extract the effective interactions between embedded knots, rationalizing some of their pertinent features by means of simple effective models. We believe the salient aspect of the knot–knot interactions emerging from our study will be present in a large number of semiflexible polymers under tension, with important consequences for the characterization and manipulation of these systems—Be they artificial or biologica in origin—And for their technological application.
Exact calculation of three-body contact interaction to second order
International Nuclear Information System (INIS)
Kaiser, N.
2012-01-01
For a system of fermions with a three-body contact interaction the second-order contributions to the energy per particle anti E(k f ) are calculated exactly. The three-particle scattering amplitude in the medium is derived in closed analytical form from the corresponding two-loop rescattering diagram. We compare the (genuine) second-order three-body contribution to anti E(k f )∝k f 10 with the second-order term due to the density-dependent effective two-body interaction, and find that the latter term dominates. The results of the present study are of interest for nuclear many-body calculations where chiral three-nucleon forces are treated beyond leading order via a density-dependent effective two-body interaction. (orig.)
Kallin, Catherine; Berlinsky, John
2016-05-01
Chiral superconductivity is a striking quantum phenomenon in which an unconventional superconductor spontaneously develops an angular momentum and lowers its free energy by eliminating nodes in the gap. It is a topologically non-trivial state and, as such, exhibits distinctive topological modes at surfaces and defects. In this paper we discuss the current theory and experimental results on chiral superconductors, focusing on two of the best-studied systems, Sr2RuO4, which is thought to be a chiral triplet p-wave superconductor, and UPt3, which has two low-temperature superconducting phases (in zero magnetic field), the lower of which is believed to be chiral triplet f-wave. Other systems that may exhibit chiral superconductivity are also discussed. Key signatures of chiral superconductivity are surface currents and chiral Majorana modes, Majorana states in vortex cores, and the possibility of half-flux quantum vortices in the case of triplet pairing. Experimental evidence for chiral superconductivity from μSR, NMR, strain, polar Kerr effect and Josephson tunneling experiments are discussed.
Matching Pion-Nucleon Roy-Steiner Equations to Chiral Perturbation Theory
Hoferichter, Martin; Ruiz de Elvira, Jacobo; Kubis, Bastian; Meißner, Ulf-G.
2015-11-01
We match the results for the subthreshold parameters of pion-nucleon scattering obtained from a solution of Roy-Steiner equations to chiral perturbation theory up to next-to-next-to-next-to-leading order, to extract the pertinent low-energy constants including a comprehensive analysis of systematic uncertainties and correlations. We study the convergence of the chiral series by investigating the chiral expansion of threshold parameters up to the same order and discuss the role of the Δ (1232 ) resonance in this context. Results for the low-energy constants are also presented in the counting scheme usually applied in chiral nuclear effective field theory, where they serve as crucial input to determine the long-range part of the nucleon-nucleon potential as well as three-nucleon forces.
Energy Technology Data Exchange (ETDEWEB)
Roncaratti, L. F., E-mail: lz@fis.unb.br; Leal, L. A.; Silva, G. M. de [Instituto de Física, Universidade de Brasília, 70910 Brasília (Brazil); Pirani, F. [Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, 06123 Perugia (Italy); Aquilanti, V. [Dipartimento di Chimica, Biologia e Biotecnologie, Università di Perugia, 06123 Perugia (Italy); Instituto de Física, Universidade Federal da Bahia, 40210 Salvador (Brazil); Gargano, R. [Instituto de Física, Universidade de Brasília, 70910 Brasília (Brazil); Departments of Chemistry and Physics, University of Florida, Quantum Theory Project, Gainesville, Florida 32611 (United States)
2014-10-07
We consider the analytical representation of the potential energy surfaces of relevance for the intermolecular dynamics of weakly bound complexes of chiral molecules. In this paper we study the H{sub 2}O{sub 2}−Ng (Ng=He, Ne, Ar, Kr, and Xe) systems providing the radial and the angular dependence of the potential energy surface on the relative position of the Ng atom. We accomplish this by introducing an analytical representation which is able to fit the ab initio energies of these complexes in a wide range of geometries. Our analysis sheds light on the role that the enantiomeric forms and the symmetry of the H{sub 2}O{sub 2} molecule play on the resulting barriers and equilibrium geometries. The proposed theoretical framework is useful to study the dynamics of the H{sub 2}O{sub 2} molecule, or other systems involving O–O and S–S bonds, interacting by non-covalent forces with atoms or molecules and to understand how the relative orientation of the O–H bonds changes along collisional events that may lead to a hydrogen bond formation or even to selectivity in chemical reactions.
Chiral nanophotonics chiral optical properties of plasmonic systems
Schäferling, Martin
2017-01-01
This book describes the physics behind the optical properties of plasmonic nanostructures focusing on chiral aspects. It explains in detail how the geometry determines chiral near-fields and how to tailor their shape and strength. Electromagnetic fields with strong optical chirality interact strongly with chiral molecules and, therefore, can be used for enhancing the sensitivity of chiroptical spectroscopy techniques. Besides a short review of the latest results in the field of plasmonically enhanced enantiomer discrimination, this book introduces the concept of chiral plasmonic near-field sources for enhanced chiroptical spectroscopy. The discussion of the fundamental properties of these light sources provides the theoretical basis for further optimizations and is of interest for researchers at the intersection of nano-optics, plasmonics and stereochemistry. .
Energy Technology Data Exchange (ETDEWEB)
Floss, H.G. [Univ. of Washington, Seattle, WA (United States)
1994-12-01
This paper deals with compounds that are chiral-at least in part, due to isotope substitution-and their use in tracing the steric course of enzyme reaction in vitro and in vivo. There are other applications of isotopically chiral compounds (for example, in analyzing the steric course of nonenzymatic reactions and in probing the conformation of biomolecules) that are important but they will not be discussed in this context.
Chiral-model of weak-interaction form factors and magnetic moments of octet baryons
International Nuclear Information System (INIS)
Kubodera, K.; Kohyama, Y.; Tsushima, K.; Yamaguchi, T.
1989-01-01
For baryon spectroscopy, magnetic moments and weak interaction form factors provide valuable information, and the impressive amount of available experimental data on these quantities for the octet baryons invites detailed investigations. The authors of this paper have made extensive studies of the weak-interaction form factors and magnetic moments of the octet baryons within the framework of the volume-type cloudy-bag model (v-type CBM). The clouds of all octet mesons have been included. Furthermore, we have taken into account in a unified framework various effects that were so far only individually discussed in the literature. Thus, the gluonic effects, center-of-mass (CM0 corrections, and recoil corrections have been included). In this talk, after giving a brief summary of some salient features of the results, we discuss a very interesting application of our model to the problem of the spin content of nucleons
Chiral supramolecular organization from a sheet-like achiral gel: a study of chiral photoinduction.
Royes, Jorge; Polo, Víctor; Uriel, Santiago; Oriol, Luis; Piñol, Milagros; Tejedor, Rosa M
2017-05-31
Chiral photoinduction in a photoresponsive gel based on an achiral 2D architecture with high geometric anisotropy and low roughness has been investigated. Circularly polarized light (CPL) was used as a chiral source and an azobenzene chromophore was employed as a chiral trigger. The chiral photoinduction was studied by evaluating the preferential excitation of enantiomeric conformers of the azobenzene units. Crystallographic data and density functional theory (DFT) calculations show how chirality is transferred to the achiral azomaterials as a result of the combination of chiral photochemistry and supramolecular interactions. This procedure could be applied to predict and estimate chirality transfer from a chiral physical source to a supramolecular organization using different light-responsive units.
Chiral perturbation theory with nucleons
International Nuclear Information System (INIS)
Meissner, U.G.
1991-09-01
I review the constraints posed on the interactions of pions, nucleons and photons by the spontaneously broken chiral symmetry of QCD. The framework to perform these calculations, chiral perturbation theory, is briefly discussed in the meson sector. The method is a simultaneous expansion of the Greens functions in powers of external moments and quark masses around the massless case, the chiral limit. To perform this expansion, use is made of a phenomenological Lagrangian which encodes the Ward-identities and pertinent symmetries of QCD. The concept of chiral power counting is introduced. The main part of the lectures of consists in describing how to include baryons (nucleons) and how the chiral structure is modified by the fact that the nucleon mass in the chiral limit does not vanish. Particular emphasis is put on working out applications to show the strengths and limitations of the methods. Some processes which are discussed are threshold photopion production, low-energy compton scattering off nucleons, πN scattering and the σ-term. The implications of the broken chiral symmetry on the nuclear forces are briefly described. An alternative approach, in which the baryons are treated as very heavy fields, is touched upon
International Nuclear Information System (INIS)
Colanero, K.; Chu, M.-C.
2002-01-01
We study a dynamical chiral bag model, in which massless fermions are confined within an impenetrable but movable bag coupled to meson fields. The self-consistent motion of the bag is obtained by solving the equations of motion exactly assuming spherical symmetry. When the bag interacts with an external meson wave we find three different kinds of resonances: fermionic, geometric, and σ resonances. We discuss the phenomenological implications of our results
Chiral topological insulator of magnons
Li, Bo; Kovalev, Alexey A.
2018-05-01
We propose a magnon realization of 3D topological insulator in the AIII (chiral symmetry) topological class. The topological magnon gap opens due to the presence of Dzyaloshinskii-Moriya interactions. The existence of the topological invariant is established by calculating the bulk winding number of the system. Within our model, the surface magnon Dirac cone is protected by the sublattice chiral symmetry. By analyzing the magnon surface modes, we confirm that the backscattering is prohibited. By weakly breaking the chiral symmetry, we observe the magnon Hall response on the surface due to opening of the gap. Finally, we show that by changing certain parameters, the system can be tuned between the chiral topological insulator, three-dimensional magnon anomalous Hall, and Weyl magnon phases.
Cosmic chirality both true and false.
Barron, Laurence D
2012-12-01
The discrete symmetries of parity P, time reversal T, and charge conjugation C may be used to characterize the properties of chiral systems. It is well known that parity violation infiltrates into ordinary matter via an interaction between the nucleons and electrons, mediated by the Z(0) particle, that lifts the degeneracy of the mirror-image enantiomers of a chiral molecule. Being odd under P but even under T, this P-violating interaction exhibits true chirality and so may induce absolute enantioselection under all circumstances. It has been suggested that CP violation may also infiltrate into ordinary matter via a P-odd, T-odd interaction mediated by the (as yet undetected) axion. This CP-violating interaction exhibits false chirality and so may induce absolute enantioselection in processes far from equilibrium. Both true and false cosmic chirality should be considered together as possible sources of homochirality in the molecules of life. Copyright © 2012 Wiley Periodicals, Inc.
Weisel, G. J.; Tornow, W.; Esterline, J. H.
2015-08-01
We present measurements of n-d analyzing power, {A}y(θ ), at En = 21.0 MeV. The experiment produces neutrons via the 2H(d, n)3He reaction and uses a deuterated liquid-scintillator center detector and six pairs of liquid-scintillator neutron side detectors. Elastic neutron scattering events are identified by using time-of-flight techniques and by setting a gate in the center-detector pulse-height spectrum. Beam polarization is monitored by using a high-pressure helium gas scintillator. The n-d {A}y(θ ) data at 21.0 MeV show a significant discrepancy with the results of rigorous three-body calculations and are consistent with data taken previously by us at 19.0 and 22.5 MeV. We review the overall energy dependence of the three-nucleon analyzing power puzzle in neutron-deuteron elastic scattering, using the best data available. We find that the relative difference between calculations and data is nearly constant at 25% up to En = 22.5 MeV.
International Nuclear Information System (INIS)
Smits, J.W.; Siemssen, R.H.; Werf, S.Y. van der; Woude, A. van der
1979-01-01
The (p,α) reaction on the even-A nickel isotopes has been studied at an incident proton energy of 30 MeV. Between 14 and 26 states, or groups of states, were analysed for each of the residual cobalt isotopes. For these transitions angular distributions were determined from thetasub(lab) = 7.5 0 to 70 0 . In all reactions the proton-hole states (0fsub(7/2), 1ssub(1/2) and 0dsub(3/2)) stand out in the spectra. Also, states formed by the weak-coupling of the proton-holes to excitations of the neutron core were seen. Differences in the relative strengths of the positive-parity hole states between the proton pickup and the (p,α) data can be explained by a semi-microscopic model for three-nucleon transfer. Also the strength distribution of the transitions to the lowest weak-coupling quintuplet is correctly predicted. These results underline the importance of the inclusion of non-zero coupled neutron pairs into the description of (p, α) reactions. Several T> states are observed in the 58 Ni(p, α) 55 Co reactions
Photoexcitation circular dichroism in chiral molecules
Beaulieu, S.; Comby, A.; Descamps, D.; Fabre, B.; Garcia, G. A.; Géneaux, R.; Harvey, A. G.; Légaré, F.; Mašín, Z.; Nahon, L.; Ordonez, A. F.; Petit, S.; Pons, B.; Mairesse, Y.; Smirnova, O.; Blanchet, V.
2018-05-01
Chiral effects appear in a wide variety of natural phenomena and are of fundamental importance in science, from particle physics to metamaterials. The standard technique of chiral discrimination—photoabsorption circular dichroism—relies on the magnetic properties of a chiral medium and yields an extremely weak chiral response. Here, we propose and demonstrate an orders of magnitude more sensitive type of circular dichroism in neutral molecules: photoexcitation circular dichroism. This technique does not rely on weak magnetic effects, but takes advantage of the coherent helical motion of bound electrons excited by ultrashort circularly polarized light. It results in an ultrafast chiral response and the efficient excitation of a macroscopic chiral density in an initially isotropic ensemble of randomly oriented chiral molecules. We probe this excitation using linearly polarized laser pulses, without the aid of further chiral interactions. Our time-resolved study of vibronic chiral dynamics opens a way to the efficient initiation, control and monitoring of chiral chemical change in neutral molecules at the level of electrons.
Nuclear axial current operators to fourth order in chiral effective field theory
Energy Technology Data Exchange (ETDEWEB)
Krebs, H., E-mail: hermann.krebs@rub.de [Institut für Theoretische Physik II, Ruhr-Universität Bochum, D-44780 Bochum (Germany); Epelbaum, E., E-mail: evgeny.epelbaum@rub.de [Institut für Theoretische Physik II, Ruhr-Universität Bochum, D-44780 Bochum (Germany); Kavli Institute for Theoretical Physics, University of California, Santa Barbara, CA 93016 (United States); Meißner, U.-G., E-mail: meissner@hiskp.uni-bonn.de [Helmholtz-Institut für Strahlen- und Kernphysik and Bethe Center for Theoretical Physics, Universität Bonn, D-53115 Bonn (Germany); Institut für Kernphysik, Institute for Advanced Simulation, and Jülich Center for Hadron Physics, Forschungszentrum Jülich, D-52425 Jülich (Germany); JARA - High Performance Computing, Forschungszentrum Jülich, D-52425 Jülich (Germany)
2017-03-15
We present the complete derivation of the nuclear axial charge and current operators as well as the pseudoscalar operators to fourth order in the chiral expansion relative to the dominant one-body contribution using the method of unitary transformation. We demonstrate that the unitary ambiguity in the resulting operators can be eliminated by the requirement of renormalizability and by matching of the pion-pole contributions to the nuclear forces. We give expressions for the renormalized single-, two- and three-nucleon contributions to the charge and current operators and pseudoscalar operators including the relevant relativistic corrections. We also verify explicitly the validity of the continuity equation.
Enantioselective Biotransformation of Chiral Persistent Organic Pollutants.
Zhang, Ying; Ye, Jing; Liu, Min
2017-01-01
Enantiomers of chiral compounds commonly undergo enantioselective transformation in most biologically mediated processes. As chiral persistent organic pollutants (POPs) are extensively distributed in the environment, differences between enantiomers in biotransformation should be carefully considered to obtain exact enrichment and specific health risks. This review provides an overview of in vivo biotransformation of chiral POPs currently indicated in the Stockholm Convention and their chiral metabolites. Peer-reviewed journal articles focused on the research question were thoroughly searched. A set of inclusion and exclusion criteria were developed to identify relevant studies. We mainly compared the results from different animal models under controlled laboratory conditions to show the difference between enantiomers in terms of distinct transformation potential. Interactions with enzymes involved in enantioselective biotransformation, especially cytochrome P450 (CYP), were discussed. Further research areas regarding this issue were proposed. Limited evidence for a few POPs has been found in 30 studies. Enantioselective biotransformation of α-hexachlorocyclohexane (α-HCH), chlordane, dichlorodiphenyltrichloroethane (DDT), heptachlor, hexabromocyclododecane (HBCD), polychlorinated biphenyls (PCBs), and toxaphene, has been investigated using laboratory mammal, fish, bird, and worm models. Tissue and excreta distributions, as well as bioaccumulation and elimination kinetics after administration of racemate and pure enantiomers, have been analyzed in these studies. Changes in enantiomeric fractions have been considered as an indicator of enantioselective biotransformation of chiral POPs in most studies. Results of different laboratory animal models revealed that chiral POP biotransformation is seriously affected by chirality. Pronounced results of species-, tissue-, gender-, and individual-dependent differences are observed in in vivo biotransformation of chiral POPs
Matei, Iulia; Ionescu, Sorana; Hillebrand, Mihaela
2012-10-01
The experimental induced circular dichroism (ICD) and absorption spectra of the achiral flavonoid kaempferol upon binding to human serum albumin (HSA) were correlated to electronic CD and UV-vis spectra theoretically predicted by time-dependent density functional theory (TDDFT). The neutral and four anionic species of kaempferol in various conformations were considered in the calculations. The appearance of the experimental ICD signal was rationalized in terms of kaempferol binding to HSA in a distorted, chiral, rigid conformation. The comparison between the experimental and simulated spectra allowed for the identification of the kaempferol species that binds to HSA, namely the anion generated by deprotonation of the hydroxyl group in position 7. This approach constitutes a convenient method for evidencing the binding species and for determining its conformation in the binding pocket of the protein. Its main advantage over the UV-vis absorption method lays in the fact that only the bound ligand species gives an ICD signal.
International Nuclear Information System (INIS)
Plum, Eric; Zheludev, Nikolay I.
2015-01-01
Mirrors are used in telescopes, microscopes, photo cameras, lasers, satellite dishes, and everywhere else, where redirection of electromagnetic radiation is required making them arguably the most important optical component. While conventional isotropic mirrors will reflect linear polarizations without change, the handedness of circularly polarized waves is reversed upon reflection. Here, we demonstrate a type of mirror reflecting one circular polarization without changing its handedness, while absorbing the other. The polarization-preserving mirror consists of a planar metasurface with a subwavelength pattern that cannot be superimposed with its mirror image without being lifted out of its plane, and a conventional mirror spaced by a fraction of the wavelength from the metasurface. Such mirrors enable circularly polarized lasers and Fabry-Pérot cavities with enhanced tunability, gyroscopic applications, polarization-sensitive detectors of electromagnetic waves, and can be used to enhance spectroscopies of chiral media
Rho, Mannque
2008-01-01
This is the sequel to the first volume to treat in one effective field theory framework the physics of strongly interacting matter under extreme conditions. This is vital for understanding the high temperature phenomena taking place in relativistic heavy ion collisions and in the early Universe, as well as the high-density matter predicted to be present in compact stars. The underlying thesis is that what governs hadronic properties in a heat bath and/or a dense medium is hidden local symmetry which emerges from chiral dynamics of light quark systems and from the duality between QCD in 4D and
Energy Technology Data Exchange (ETDEWEB)
Rahaman, Anisur, E-mail: anisur.rahman@saha.ac.in
2015-10-15
The vector type of interaction of the Thirring–Wess model was replaced by the chiral type and a new model was presented which was termed as chiral Thirring–Wess model in Rahaman (2015). The model was studied there with a Faddeevian class of regularization. Few ambiguity parameters were allowed there with the apprehension that unitarity might be threatened like the chiral generation of the Schwinger model. In the present work it has been shown that no counter term containing the regularization ambiguity is needed for this model to be physically sensible. So the chiral Thirring–Wess model is studied here without the presence of any ambiguity parameter and it has been found that the model not only remains exactly solvable but also does not lose the unitarity like the chiral generation of the Schwinger model. The phase space structure and the theoretical spectrum of this new model have been determined in the present scenario. The theoretical spectrum is found to contain a massive boson with ambiguity free mass and a massless boson.
International Nuclear Information System (INIS)
Rahaman, Anisur
2015-01-01
The vector type of interaction of the Thirring–Wess model was replaced by the chiral type and a new model was presented which was termed as chiral Thirring–Wess model in Rahaman (2015). The model was studied there with a Faddeevian class of regularization. Few ambiguity parameters were allowed there with the apprehension that unitarity might be threatened like the chiral generation of the Schwinger model. In the present work it has been shown that no counter term containing the regularization ambiguity is needed for this model to be physically sensible. So the chiral Thirring–Wess model is studied here without the presence of any ambiguity parameter and it has been found that the model not only remains exactly solvable but also does not lose the unitarity like the chiral generation of the Schwinger model. The phase space structure and the theoretical spectrum of this new model have been determined in the present scenario. The theoretical spectrum is found to contain a massive boson with ambiguity free mass and a massless boson
Physics of chiral symmetry breaking
International Nuclear Information System (INIS)
Shuryak, E.V.
1991-01-01
This subsection of the 'Modeling QCD' Workshop has included five talks. E. Shuryak spoke on 'Recent Progress in Understanding Chiral Symmetry Breaking'; below it is split into two parts: (i) a mini-review of the field and (ii) a brief presentation of the status of the theory of interacting instantons. The next sections correspond to the following talks: (iii) K. Goeke et al., 'Chiral Restoration and Medium Corrections to Nucleon in the NJL Model'; (iv) M. Takizawa and K. Kubodera, 'Study of Meson Properties and Quark Condensates in the NJL Model with Instanton Effects'; (v) G. Klein and A. G. Williams, 'Dynamical Chiral Symmetry Breaking in Dual QCD'; and (vi) R. D. Ball, 'Skyrmions and Baryons.' (orig.)
Chirality and gravitational parity violation.
Bargueño, Pedro
2015-06-01
In this review, parity-violating gravitational potentials are presented as possible sources of both true and false chirality. In particular, whereas phenomenological long-range spin-dependent gravitational potentials contain both truly and falsely chiral terms, it is shown that there are models that extend general relativity including also coupling of fermionic degrees of freedom to gravity in the presence of torsion, which give place to short-range truly chiral interactions similar to that usually considered in molecular physics. Physical mechanisms which give place to gravitational parity violation together with the expected size of the effects and their experimental constraints are discussed. Finally, the possible role of parity-violating gravity in the origin of homochirality and a road map for future research works in quantum chemistry is presented. © 2015 Wiley Periodicals, Inc.
Training software for chiral separations in capillary electrophoresis
Reijenga, J.C.; Ingelse, B.A.; Everaerts, F.M.
1997-01-01
A previously published steady-state simulation program for CE was extended with a sub-menu for chiral interaction. The interaction was modelled with a hypothetical (neutral) selector with properties similar to cyclodextrins. A three-type chiral interaction model was implemented in such a way that it
Nuclear chiral dynamics and thermodynamics
Holt, Jeremy W.; Kaiser, Norbert; Weise, Wolfram
2013-11-01
This presentation reviews an approach to nuclear many-body systems based on the spontaneously broken chiral symmetry of low-energy QCD. In the low-energy limit, for energies and momenta small compared to a characteristic symmetry breaking scale of order 1 GeV, QCD is realized as an effective field theory of Goldstone bosons (pions) coupled to heavy fermionic sources (nucleons). Nuclear forces at long and intermediate distance scales result from a systematic hierarchy of one- and two-pion exchange processes in combination with Pauli blocking effects in the nuclear medium. Short distance dynamics, not resolved at the wavelengths corresponding to typical nuclear Fermi momenta, are introduced as contact interactions between nucleons. Apart from a set of low-energy constants associated with these contact terms, the parameters of this theory are entirely determined by pion properties and low-energy pion-nucleon scattering observables. This framework (in-medium chiral perturbation theory) can provide a realistic description of both isospin-symmetric nuclear matter and neutron matter, with emphasis on the isospin-dependence determined by the underlying chiral NN interaction. The importance of three-body forces is emphasized, and the role of explicit Δ(1232)-isobar degrees of freedom is investigated in detail. Nuclear chiral thermodynamics is developed and a calculation of the nuclear phase diagram is performed. This includes a successful description of the first-order phase transition from a nuclear Fermi liquid to an interacting Fermi gas and the coexistence of these phases below a critical temperature Tc. Density functional methods for finite nuclei based on this approach are also discussed. Effective interactions, their density dependence and connections to Landau Fermi liquid theory are outlined. Finally, the density and temperature dependences of the chiral (quark) condensate are investigated.
International Nuclear Information System (INIS)
Basar, Goekce; Dunne, Gerald V.; Kharzeev, Dmitri E.
2010-01-01
We argue that the presence of a very strong magnetic field in the chirally broken phase induces inhomogeneous expectation values, of a spiral nature along the magnetic field axis, for the currents of charge and chirality, when there is finite baryon density or an imbalance between left and right chiralities. This 'chiral magnetic spiral' is a gapless excitation transporting the currents of (i) charge (at finite chirality), and (ii) chirality (at finite baryon density) along the direction of the magnetic field. In both cases it also induces in the transverse directions oscillating currents of charge and chirality. In heavy ion collisions, the chiral magnetic spiral possibly provides contributions both to the out-of-plane and the in-plane dynamical charge fluctuations recently observed at BNL RHIC.
Introduction to Chiral Symmetry
Energy Technology Data Exchange (ETDEWEB)
Koch, Volker [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
2017-05-09
These lectures are an attempt to a pedagogical introduction into the elementary concepts of chiral symmetry in nuclear physics. We will also discuss some effective chiral models such as the linear and nonlinear sigma model as well as the essential ideas of chiral perturbation theory. We will present some applications to the physics of ultrarelativistic heavy ion collisionsd.
Introduction to chiral symmetry
International Nuclear Information System (INIS)
Koch, V.
1996-01-01
These lectures are an attempt to a pedagogical introduction into the elementary concepts of chiral symmetry in nuclear physics. Effective chiral models such as the linear and nonlinear sigma model will be discussed as well as the essential ideas of chiral perturbation theory. Some applications to the physics of ultrarelativistic heavy ion collisions will be presented
Chiral discotics; expression and amplification of chirality
Brunsveld, L.; Meijer, E.W.; Rowan, A.E.; Nolte, R.J.M.; Denmark, S.E.; Nolte, R.J.M.; Meijer, E.W.
2003-01-01
In this contribution, chirality and discotic liquid crystals are discussed as a tool for studying the self-assembly of these molecules, both in solution and in the solid state. Therefore, the objective of this chapter is to summarize and elucidate how molecular chirality can be expressed in discotic
Chirality detection of enantiomers using twisted optical metamaterials
Zhao, Yang; Askarpour, Amir N.; Sun, Liuyang; Shi, Jinwei; Li, Xiaoqin; Alù, Andrea
2017-01-01
Many naturally occurring biomolecules, such as amino acids, sugars and nucleotides, are inherently chiral. Enantiomers, a pair of chiral isomers with opposite handedness, often exhibit similar physical and chemical properties due to their identical functional groups and composition, yet show different toxicity to cells. Detecting enantiomers in small quantities has an essential role in drug development to eliminate their unwanted side effects. Here we exploit strong chiral interactions with plasmonic metamaterials with specifically designed optical response to sense chiral molecules down to zeptomole levels, several orders of magnitude smaller than what is typically detectable with conventional circular dichroism spectroscopy. In particular, the measured spectra reveal opposite signs in the spectral regime directly associated with different chiral responses, providing a way to univocally assess molecular chirality. Our work introduces an ultrathin, planarized nanophotonic interface to sense chiral molecules with inherently weak circular dichroism at visible and near-infrared frequencies. PMID:28120825
Lodahl, Peter; Mahmoodian, Sahand; Stobbe, Søren; Rauschenbeutel, Arno; Schneeweiss, Philipp; Volz, Jürgen; Pichler, Hannes; Zoller, Peter
2017-01-25
Advanced photonic nanostructures are currently revolutionizing the optics and photonics that underpin applications ranging from light technology to quantum-information processing. The strong light confinement in these structures can lock the local polarization of the light to its propagation direction, leading to propagation-direction-dependent emission, scattering and absorption of photons by quantum emitters. The possibility of such a propagation-direction-dependent, or chiral, light-matter interaction is not accounted for in standard quantum optics and its recent discovery brought about the research field of chiral quantum optics. The latter offers fundamentally new functionalities and applications: it enables the assembly of non-reciprocal single-photon devices that can be operated in a quantum superposition of two or more of their operational states and the realization of deterministic spin-photon interfaces. Moreover, engineered directional photonic reservoirs could lead to the development of complex quantum networks that, for example, could simulate novel classes of quantum many-body systems.
Intelligent Chiral Sensing Based on Supramolecular and Interfacial Concepts
Directory of Open Access Journals (Sweden)
Hironori Izawa
2010-07-01
Full Text Available Of the known intelligently-operating systems, the majority can undoubtedly be classed as being of biological origin. One of the notable differences between biological and artificial systems is the important fact that biological materials consist mostly of chiral molecules. While most biochemical processes routinely discriminate chiral molecules, differentiation between chiral molecules in artificial systems is currently one of the challenging subjects in the field of molecular recognition. Therefore, one of the important challenges for intelligent man-made sensors is to prepare a sensing system that can discriminate chiral molecules. Because intermolecular interactions and detection at surfaces are respectively parts of supramolecular chemistry and interfacial science, chiral sensing based on supramolecular and interfacial concepts is a significant topic. In this review, we briefly summarize recent advances in these fields, including supramolecular hosts for color detection on chiral sensing, indicator-displacement assays, kinetic resolution in supramolecular reactions with analyses by mass spectrometry, use of chiral shape-defined polymers, such as dynamic helical polymers, molecular imprinting, thin films on surfaces of devices such as QCM, functional electrodes, FET, and SPR, the combined technique of magnetic resonance imaging and immunoassay, and chiral detection using scanning tunneling microscopy and cantilever technology. In addition, we will discuss novel concepts in recent research including the use of achiral reagents for chiral sensing with NMR, and mechanical control of chiral sensing. The importance of integration of chiral sensing systems with rapidly developing nanotechnology and nanomaterials is also emphasized.
On chiral and non chiral 1D supermultiplets
Energy Technology Data Exchange (ETDEWEB)
Toppan, Francesco, E-mail: toppan@cbpf.b [Centro Brasileiro de Pesquisas Fisicas (TEO/CBPF), Rio de Janeiro, RJ (Brazil). Coordenacao de Fisica Teorica
2011-07-01
In this talk I discuss and clarify some issues concerning chiral and non chiral properties of the one-dimensional supermultiplets of the N-extended supersymmetry. Quaternionic chirality can be defined for N = 4, 5, 6, 7, 8. Octonionic chirality for N = 8 and beyond. Inequivalent chiralities only arise when considering several copies of N = 4 or N = 8 supermultiplets. (author)
On chiral and non chiral 1D supermultiplets
International Nuclear Information System (INIS)
Toppan, Francesco
2011-01-01
In this talk I discuss and clarify some issues concerning chiral and non chiral properties of the one-dimensional supermultiplets of the N-extended supersymmetry. Quaternionic chirality can be defined for N = 4, 5, 6, 7, 8. Octonionic chirality for N = 8 and beyond. Inequivalent chiralities only arise when considering several copies of N = 4 or N = 8 supermultiplets. (author)
Low-energy meson physics (chiral theory)
International Nuclear Information System (INIS)
Volkov, M.K.; Pervushin, V.N.
1976-01-01
A quantum chiral theory which allows to obtain low-energy expansions of various hadron processes without introducing arbitrary parameters into the theory with the exception of hadron masses and interaction constants is presented. A hypothesis about the dynamic symmetry of strong interactions is suggested. The interaction lagrangian is derived which satisfies conditions of the dynamic symmetry. Examples of the use of the quantum chiral theory for describing low-energy processes of meson interaction are given. It is noted that the results obtained reproduce the actual qualitative pattern of various physical processes and in most cases result in good quantitative agreement with experiments
International Nuclear Information System (INIS)
Shibuya, Taira; Matsuura, Hiroyasu; Ogata, Masao
2016-01-01
We study a microscopic derivation and the properties of the Dzyaloshinskii-Moriya interaction (DMI) between local magnetic moments in ferromagnet/heavy metal heterostructures. First, we derive DMI by Ruderman-Kittel-Kasuya-Yosida interaction through electrons in a heavy metal with Rashba spin orbit interaction (SOI). Next, we study the dependences of the DMI on the Rashba SOI, lattice constant, and chemical potential. We find that the DMI amplitude increases linearly when the Rashba SOI is small, has a maximum when the Rashba SOI is comparable to the hopping integral, and decreases when the Rashba SOI is large. The sign of the DMI not only changes depending on the sign of the Rashba SOI but also the lattice constants and the chemical potential of the heavy metal. The implications of the obtained results for experiments are discussed. (author)
Mechanical separation of chiral dipoles by chiral light
International Nuclear Information System (INIS)
Canaguier-Durand, Antoine; Hutchison, James A; Genet, Cyriaque; Ebbesen, Thomas W
2013-01-01
We calculate optical forces and torques exerted on a chiral dipole by chiral light fields and reveal genuine chiral forces in combining the chiral contents of both light field and dipolar matter. Here, the optical chirality is characterized in a general way through the definition of optical chirality density and chirality flow. We show, in particular, that both terms have mechanical effects associated, respectively, with reactive and dissipative components of the chiral forces. Remarkably, these chiral force components are directly related to standard observables: optical rotation for the reactive component and circular dichroism for the dissipative one. As a consequence, the resulting forces and torques are dependent on the enantiomeric form of the chiral dipole. This suggests promising strategies for using chiral light forces to mechanically separate chiral objects according to their enantiomeric form. (paper)
Photonic chiral current and its anomaly in a gravitational field
International Nuclear Information System (INIS)
Dolgov, A.D.; Khriplovich, I.B.; Vajnshtejn, A.I.; Zakharov, V.I.
1988-01-01
The notion of chirality for electromagnetic field which is conserved in interactions with gravitons is formulated. The correponding chiral current is the one-particle-state analogue of the Pauli-Lubansky vector. The anomaly of this current in an external gravitational field is found. The results obtained are used for the calculation of the electromagnetic radiative correction to the fermionic chiral anomaly in a gravitational field
A chiral aluminum solvating agent (CASA) for 1H NMR chiral analysis of alcohols at low temperature.
Seo, Min-Seob; Jang, Sumin; Kim, Hyunwoo
2018-03-16
A chiral aluminum solvating agent (CASA) was demonstrated to be a general and efficient reagent for 1H NMR chiral analysis of alcohols. The sodium salt of the CASA (CASA-Na) showed a complete baseline peak separation of the hydroxyl group for various chiral alcohols including primary, secondary, and tertiary alcohols with alkyl and aryl substituents in CD3CN. Due to the weak intermolecular interaction, 1H NMR measurement at low temperature (-40 to 10 °C) was required.
Bose-Einstein condensation and chiral phase transition in linear sigma model
International Nuclear Information System (INIS)
Shu Song; Li Jiarong
2005-01-01
With the linear sigma model, we have studied Bose-Einstein condensation and the chiral phase transition in the chiral limit for an interacting pion system. A μ-T phase diagram including these two phenomena is presented. It is found that the phase plane has been divided into three areas: the Bose-Einstein condensation area, the chiral symmetry broken phase area and the chiral symmetry restored phase area. Bose-Einstein condensation can occur either from the chiral symmetry broken phase or from the restored phase. We show that the onset of the chiral phase transition is restricted in the area where there is no Bose-Einstein condensation
Partition function of a chiral boson on a 2-torus from the Floreanini–Jackiw Lagrangian
International Nuclear Information System (INIS)
Chen, Wei-Ming; Ho, Pei-Ming; Kao, Hsien-chung; Khoo, Fech Scen; Matsuo, Yutaka
2014-01-01
We revisit the problem of quantizing a chiral boson on a torus. The conventional approach is to extract the partition function of a chiral boson from the path integral of a non-chiral boson. Instead we compute it directly from the chiral boson Lagrangian of Floreanini and Jackiw modified by topological terms involving an auxiliary field. A careful analysis of the gauge-fixing condition for the extra gauge symmetry reproduces the correct results for the free chiral boson, and has the advantage of being applicable to a wider class of interacting chiral boson theories
Kehr, Nermin Seda; Jose, Joachim
2017-12-01
We demonstrate the organic molecules loaded and chiral polymers coated periodic mesoporous organosilica (PMO) to generate chiral nanocarriers that we used to study chirality-dependent cellular uptake in serum and serum-free media and the subsequent delivery of different amounts of organic molecules into cells. Our results show that the amount of internalized PMO and thus the transported amount of organic molecules by nanocarrier PMO into cells was chirality dependent and controlled by hard/soft protein corona formation on the PMO surfaces. Therefore, this study demonstrate that chiral porous nanocarriers could potentially be used as advanced drug delivery systems which are able to use the specific chiral surface-protein interactions to influence/control the amount of (bio)active molecules delivered to cells in drug delivery and/or imaging applications.
Laminar and Turbulent Dynamos in Chiral Magnetohydrodynamics. I. Theory
Energy Technology Data Exchange (ETDEWEB)
Rogachevskii, Igor; Kleeorin, Nathan [Department of Mechanical Engineering, Ben-Gurion University of the Negev, P.O. Box 653, Beer-Sheva 84105 (Israel); Ruchayskiy, Oleg [Discovery Center, Niels Bohr Institute, Blegdamsvej 17, DK-2100 Copenhagen (Denmark); Boyarsky, Alexey [Instituut-Lorentz for Theoretical Physics, Universiteit Leiden, Niels Bohrweg 2, 2333 CA Leiden (Netherlands); Fröhlich, Jürg [Institute of Theoretical Physics, ETH Hönggerberg, CH-8093 Zurich (Switzerland); Brandenburg, Axel; Schober, Jennifer, E-mail: gary@bgu.ac.il [Nordita, KTH Royal Institute of Technology and Stockholm University, Roslagstullsbacken 23, SE-10691 Stockholm (Sweden)
2017-09-10
The magnetohydrodynamic (MHD) description of plasmas with relativistic particles necessarily includes an additional new field, the chiral chemical potential associated with the axial charge (i.e., the number difference between right- and left-handed relativistic fermions). This chiral chemical potential gives rise to a contribution to the electric current density of the plasma ( chiral magnetic effect ). We present a self-consistent treatment of the chiral MHD equations , which include the back-reaction of the magnetic field on a chiral chemical potential and its interaction with the plasma velocity field. A number of novel phenomena are exhibited. First, we show that the chiral magnetic effect decreases the frequency of the Alfvén wave for incompressible flows, increases the frequencies of the Alfvén wave and of the fast magnetosonic wave for compressible flows, and decreases the frequency of the slow magnetosonic wave. Second, we show that, in addition to the well-known laminar chiral dynamo effect, which is not related to fluid motions, there is a dynamo caused by the joint action of velocity shear and chiral magnetic effect. In the presence of turbulence with vanishing mean kinetic helicity, the derived mean-field chiral MHD equations describe turbulent large-scale dynamos caused by the chiral alpha effect, which is dominant for large fluid and magnetic Reynolds numbers. The chiral alpha effect is due to an interaction of the chiral magnetic effect and fluctuations of the small-scale current produced by tangling magnetic fluctuations (which are generated by tangling of the large-scale magnetic field by sheared velocity fluctuations). These dynamo effects may have interesting consequences in the dynamics of the early universe, neutron stars, and the quark–gluon plasma.
Laminar and Turbulent Dynamos in Chiral Magnetohydrodynamics. I. Theory
International Nuclear Information System (INIS)
Rogachevskii, Igor; Kleeorin, Nathan; Ruchayskiy, Oleg; Boyarsky, Alexey; Fröhlich, Jürg; Brandenburg, Axel; Schober, Jennifer
2017-01-01
The magnetohydrodynamic (MHD) description of plasmas with relativistic particles necessarily includes an additional new field, the chiral chemical potential associated with the axial charge (i.e., the number difference between right- and left-handed relativistic fermions). This chiral chemical potential gives rise to a contribution to the electric current density of the plasma ( chiral magnetic effect ). We present a self-consistent treatment of the chiral MHD equations , which include the back-reaction of the magnetic field on a chiral chemical potential and its interaction with the plasma velocity field. A number of novel phenomena are exhibited. First, we show that the chiral magnetic effect decreases the frequency of the Alfvén wave for incompressible flows, increases the frequencies of the Alfvén wave and of the fast magnetosonic wave for compressible flows, and decreases the frequency of the slow magnetosonic wave. Second, we show that, in addition to the well-known laminar chiral dynamo effect, which is not related to fluid motions, there is a dynamo caused by the joint action of velocity shear and chiral magnetic effect. In the presence of turbulence with vanishing mean kinetic helicity, the derived mean-field chiral MHD equations describe turbulent large-scale dynamos caused by the chiral alpha effect, which is dominant for large fluid and magnetic Reynolds numbers. The chiral alpha effect is due to an interaction of the chiral magnetic effect and fluctuations of the small-scale current produced by tangling magnetic fluctuations (which are generated by tangling of the large-scale magnetic field by sheared velocity fluctuations). These dynamo effects may have interesting consequences in the dynamics of the early universe, neutron stars, and the quark–gluon plasma.
Siegel's chiral boson and the chiral Schwinger model
International Nuclear Information System (INIS)
Berger, T.
1992-01-01
In this paper Siegel's proposal for a Lagrangian formulation of a chiral boson is analyzed by applying recent results on 2d chiral quantum gravity. A model is derived whose solution consists of a massive scalar and two massless chiral scalars. Therefore it is a minimally bosonized two-fermion chiral Schwinger model
Preface to the Special Issue: Chiral Symmetry in Hadrons and Nuclei
International Nuclear Information System (INIS)
Geng, Lisheng; Meng, Jie; Zhao, Qiang; Zou, Bingsong
2014-01-01
The recent past years have seen a remarkable progress towards a unified description of nonperturbative strong interaction phenomena based on the fundamental theory of the strong interaction, quantum chromodynamics, and effective field theories. The papers collected in this special issue focus on the recent progress in hadron and nuclear physics related to the chiral symmetry. They are written based on presentations at the Seventh International Symposium on Chiral Symmetry in Hadron and Nuclei which took place at Beihang University, Beijing, 27-30 October 2013. The sub-topics discussed in these papers include chiral and heavy-quark spin symmetry; chiral dynamics of few-body hadron systems; chiral symmetry and hadrons in a nuclear medium; chiral dynamics in nucleon-nucleon interaction and atomic nuclei; chiral symmetry in rotating nuclei; hadron structure and interactions; exotic hadrons, heavy flavor hadrons and nuclei; mesonic atoms and nuclei
Molecular-level Design of Heterogeneous Chiral Catalysts
Energy Technology Data Exchange (ETDEWEB)
Gellman, Andrew John [Carnegie Mellon University; Sholl, David S. [Georgia Institute of Technology; Tysoe, Wilfred T. [University of Wisconsin - Milwaukee; Zaera, Francisco [University of California at Riverside
2013-04-28
Understanding and controlling selectivity is one of the key challenges in heterogeneous catalysis. Among problems in catalytic selectivity enantioselectivity is perhaps the most the most challenging. The primary goal of the project on “Molecular-level Design of Heterogeneous Chiral Catalysts” is to understand the origins of enantioselectivity on chiral heterogeneous surfaces and catalysts. The efforts of the project team include preparation of chiral surfaces, characterization of chiral surfaces, experimental detection of enantioselectivity on such surfaces and computational modeling of the interactions of chiral probe molecules with chiral surfaces. Over the course of the project period the team of PI’s has made some of the most detailed and insightful studies of enantioselective chemistry on chiral surfaces. This includes the measurement of fundamental interactions and reaction mechanisms of chiral molecules on chiral surfaces and leads all the way to rationale design and synthesis of chiral surfaces and materials for enantioselective surface chemistry. The PI’s have designed and prepared new materials for enantioselective adsorption and catalysis. Naturally Chiral Surfaces • Completion of a systematic study of the enantiospecific desorption kinetics of R-3-methylcyclohexanone (R-3-MCHO) on 9 achiral and 7 enantiomeric pairs of chiral Cu surfaces with orientations that span the stereographic triangle. • Discovery of super-enantioselective tartaric acid (TA) and aspartic acid (Asp) decomposition as a result of a surface explosion mechanism on Cu(643)R&S. Systematic study of super-enantiospecific TA and Asp decomposition on five enantiomeric pairs of chiral Cu surfaces. • Initial observation of the enantiospecific desorption of R- and S-propylene oxide (PO) from Cu(100) imprinted with {3,1,17} facets by L-lysine adsorption. Templated Chiral Surfaces • Initial observation of the enantiospecific desorption of R- and S-PO from Pt(111) and Pd(111
Chiral Spirals from Discontinuous Chiral Symmetry
Kojo, Toru
2014-09-01
Recently phases of the inhomongeneous chiral condensates (IChC) attract renewed attentions in quark matter context. A number of theoretical studies have suggested that in some domain of moderate quark density the IChC phases are energetically more favored than the normal, chiral symmetric phase. In particular, the NJL-type model studies indicate that the phase of IChCs may mask the usual 1st order chiral phase transition line and its critical end point, and might change the conventional wisdom. In this talk, I will discuss characteristic features of the IChC phases and their potential impacts on the compact star physics. In particular, some of the IChC phases open gaps near the quark Fermi surface, suppressing back-reaction from the quark to gluon sectors. This mechanism delays the chiral restoration in the strange quark sector, forbids the emergence of the large bag constant, and as a consequence, makes the quark matter EOS very stiff. Recently phases of the inhomongeneous chiral condensates (IChC) attract renewed attentions in quark matter context. A number of theoretical studies have suggested that in some domain of moderate quark density the IChC phases are energetically more favored than the normal, chiral symmetric phase. In particular, the NJL-type model studies indicate that the phase of IChCs may mask the usual 1st order chiral phase transition line and its critical end point, and might change the conventional wisdom. In this talk, I will discuss characteristic features of the IChC phases and their potential impacts on the compact star physics. In particular, some of the IChC phases open gaps near the quark Fermi surface, suppressing back-reaction from the quark to gluon sectors. This mechanism delays the chiral restoration in the strange quark sector, forbids the emergence of the large bag constant, and as a consequence, makes the quark matter EOS very stiff. NSF Grants PHY09-69790, PHY13-05891.
Geometrical approach to central molecular chirality: a chirality selection rule
Capozziello, S.; Lattanzi, A.
2004-01-01
Chirality is of primary importance in many areas of chemistry and has been extensively investigated since its discovery. We introduce here the description of central chirality for tetrahedral molecules using a geometrical approach based on complex numbers. According to this representation, for a molecule having n chiral centres, it is possible to define an index of chirality. Consequently a chirality selection rule has been derived which allows the characterization of a molecule as achiral, e...
Chirality conservation in the lattice gauge theory
International Nuclear Information System (INIS)
Peskin, M.E.
1978-01-01
The derivation of conservation laws corresponding to chiral invariance in quantum field theories of interacting quarks and gluons are studied. In particular there is interest in observing how these conservation laws are constrained by the requirement that the field theory be locally gauge invariant. To examine this question, a manifestly gauge-invariant definition of local operators in a quantum field theory is introduced, a definition which relies in an essential way on the use of the formulation of gauge fields on a lattice due to Wilson and Polyakov to regulate ultraviolet divergences. The conceptual basis of the formalism is set out and applied to a long-standing puzzle in the phenomenology of quark-gluon theories: the fact that elementary particle interactions reflect the conservation of isospin-carrying chiral currents but not of the isospin-singlet chiral current. It is well known that the equation for the isospin-singlet current contains an extra term, the operator F/sub mu neu/F/sup mu neu/, not present in the other chirality conservation laws; however, this term conventionally has the form of a total divergence and so still allows the definition of a conserved chiral current. It is found that, when the effects of maintaining gauge invariance are properly taken into account, the structure of this operator is altered by renormalization effects, so that it provides an explicit breaking of the unwanted chiral invariance. The relation between this argument, based on renormaliztion, is traced to a set of more heuristic arguments based on gauge field topology given by 't Hooft; it is shown that the discussion provides a validation, through short-distance analysis, of the picture 'Hooft has proposed. The formal derivation of conservation laws for chiral currents are set out in detail
Magnetic fields and chiral asymmetry in the early hot universe
International Nuclear Information System (INIS)
Sydorenko, Maksym; Shtanov, Yuri; Tomalak, Oleksandr
2016-01-01
In this paper, we study analytically the process of external generation and subsequent free evolution of the lepton chiral asymmetry and helical magnetic fields in the early hot universe. This process is known to be affected by the Abelian anomaly of the electroweak gauge interactions. As a consequence, chiral asymmetry in the fermion distribution generates magnetic fields of non-zero helicity, and vice versa. We take into account the presence of thermal bath, which serves as a seed for the development of instability in magnetic field in the presence of externally generated lepton chiral asymmetry. The developed helical magnetic field and lepton chiral asymmetry support each other, considerably prolonging their mutual existence, in the process of 'inverse cascade' transferring magnetic-field power from small to large spatial scales. For cosmologically interesting initial conditions, the chiral asymmetry and the energy density of helical magnetic field are shown to evolve by scaling laws, effectively depending on a single combined variable. In this case, the late-time asymptotics of the conformal chiral chemical potential reproduces the universal scaling law previously found in the literature for the system under consideration. This regime is terminated at lower temperatures because of scattering of electrons with chirality change, which exponentially washes out chiral asymmetry. We derive an expression for the termination temperature as a function of the chiral asymmetry and energy density of helical magnetic field.
Influence of Chirality in Ordered Block Copolymer Phases
Prasad, Ishan; Grason, Gregory
2015-03-01
Block copolymers are known to assemble into rich spectrum of ordered phases, with many complex phases driven by asymmetry in copolymer architecture. Despite decades of study, the influence of intrinsic chirality on equilibrium mesophase assembly of block copolymers is not well understood and largely unexplored. Self-consistent field theory has played a major role in prediction of physical properties of polymeric systems. Only recently, a polar orientational self-consistent field (oSCF) approach was adopted to model chiral BCP having a thermodynamic preference for cholesteric ordering in chiral segments. We implement oSCF theory for chiral nematic copolymers, where segment orientations are characterized by quadrupolar chiral interactions, and focus our study on the thermodynamic stability of bi-continuous network morphologies, and the transfer of molecular chirality to mesoscale chirality of networks. Unique photonic properties observed in butterfly wings have been attributed to presence of chiral single-gyroid networks, this has made it an attractive target for chiral metamaterial design.
Magnetic fields and chiral asymmetry in the early hot universe
Energy Technology Data Exchange (ETDEWEB)
Sydorenko, Maksym; Shtanov, Yuri [Bogolyubov Institute for Theoretical Physics, 03680 Kiev (Ukraine); Tomalak, Oleksandr, E-mail: maxsydorenko@gmail.com, E-mail: tomalak@uni-mainz.de, E-mail: shtanov@bitp.kiev.ua [Institut für Kernphysik, Johannes Gutenberg Universität, 55128 Mainz (Germany)
2016-10-01
In this paper, we study analytically the process of external generation and subsequent free evolution of the lepton chiral asymmetry and helical magnetic fields in the early hot universe. This process is known to be affected by the Abelian anomaly of the electroweak gauge interactions. As a consequence, chiral asymmetry in the fermion distribution generates magnetic fields of non-zero helicity, and vice versa. We take into account the presence of thermal bath, which serves as a seed for the development of instability in magnetic field in the presence of externally generated lepton chiral asymmetry. The developed helical magnetic field and lepton chiral asymmetry support each other, considerably prolonging their mutual existence, in the process of 'inverse cascade' transferring magnetic-field power from small to large spatial scales. For cosmologically interesting initial conditions, the chiral asymmetry and the energy density of helical magnetic field are shown to evolve by scaling laws, effectively depending on a single combined variable. In this case, the late-time asymptotics of the conformal chiral chemical potential reproduces the universal scaling law previously found in the literature for the system under consideration. This regime is terminated at lower temperatures because of scattering of electrons with chirality change, which exponentially washes out chiral asymmetry. We derive an expression for the termination temperature as a function of the chiral asymmetry and energy density of helical magnetic field.
Arthurs, Ross A; Ismail, Muhammad; Prior, Christopher C; Oganesyan, Vasily S; Horton, Peter N; Coles, Simon J; Richards, Christopher J
2016-02-24
Reaction of [IrCp*Cl2 ]2 with ferrocenylimines (Fc=NAr, Ar=Ph, p-MeOC6 H4 ) results in ferrocene C-H activation and the diastereoselective synthesis of half-sandwich iridacycles of relative configuration Sp *,RIr *. Extension to (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline gave highly diastereoselective control over the new elements of planar chirality and metal-based pseudo-tetrahedral chirality, to give both neutral and cationic half-sandwich iridacycles of absolute configuration Sc ,Sp ,RIr . Substitution reactions proceed with retention of configuration, with the planar chirality controlling the metal-centred chirality through an iron-iridium interaction in the coordinatively unsaturated cationic intermediate. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Applications of chiral symmetry
International Nuclear Information System (INIS)
Pisarski, R.D.
1995-03-01
The author discusses several topics in the applications of chiral symmetry at nonzero temperature. First, where does the rho go? The answer: up. The restoration of chiral symmetry at a temperature T χ implies that the ρ and a 1 vector mesons are degenerate in mass. In a gauged linear sigma model the ρ mass increases with temperature, m ρ (T χ ) > m ρ (0). The author conjectures that at T χ the thermal ρ - a 1 , peak is relatively high, at about ∼1 GeV, with a width approximately that at zero temperature (up to standard kinematic factors). The ω meson also increases in mass, nearly degenerate with the ρ, but its width grows dramatically with temperature, increasing to at least ∼100 MeV by T χ . The author also stresses how utterly remarkable the principle of vector meson dominance is, when viewed from the modern perspective of the renormalization group. Secondly, he discusses the possible appearance of disoriented chiral condensates from open-quotes quenchedclose quotes heavy ion collisions. It appears difficult to obtain large domains of disoriented chiral condensates in the standard two flavor model. This leads to the last topic, which is the phase diagram for QCD with three flavors, and its proximity to the chiral critical point. QCD may be very near this chiral critical point, and one might thereby generated large domains of disoriented chiral condensates
Energy Technology Data Exchange (ETDEWEB)
Bourget, Antoine; Troost, Jan [Laboratoire de Physique Théorique, École Normale Supérieure, 24 rue Lhomond, 75005 Paris (France)
2016-03-23
We construct a covariant generating function for the spectrum of chiral primaries of symmetric orbifold conformal field theories with N=(4,4) supersymmetry in two dimensions. For seed target spaces K3 and T{sup 4}, the generating functions capture the SO(21) and SO(5) representation theoretic content of the chiral ring respectively. Via string dualities, we relate the transformation properties of the chiral ring under these isometries of the moduli space to the Lorentz covariance of perturbative string partition functions in flat space.
Spectral signatures of chirality
DEFF Research Database (Denmark)
Pedersen, Jesper Goor; Mortensen, Asger
2009-01-01
We present a new way of measuring chirality, via the spectral shift of photonic band gaps in one-dimensional structures. We derive an explicit mapping of the problem of oblique incidence of circularly polarized light on a chiral one-dimensional photonic crystal with negligible index contrast...... to the formally equivalent problem of linearly polarized light incident on-axis on a non-chiral structure with index contrast. We derive analytical expressions for the first-order shifts of the band gaps for negligible index contrast. These are modified to give good approximations to the band gap shifts also...
Transport properties of chiral fermions
Energy Technology Data Exchange (ETDEWEB)
Puhr, Matthias
2017-04-26
Anomalous transport phenomena have their origin in the chiral anomaly, the anomalous non-conservation of the axial charge, and can arise in systems with chiral fermions. The anomalous transport properties of free fermions are well understood, but little is known about possible corrections to the anomalous transport coefficients that can occur if the fermions are strongly interacting. The main goal of this thesis is to study anomalous transport effects in media with strongly interacting fermions. In particular, we investigate the Chiral Magnetic Effect (CME) in a Weyl Semimetal (WSM) and the Chiral Separation Effect (CSE) in finite-density Quantum Chromodynamics (QCD). The recently discovered WSMs are solid state crystals with low-energy excitations that behave like Weyl fermions. The inter-electron interaction in WSMs is typically very strong and non-perturbative calculations are needed to connect theory and experiment. To realistically model an interacting, parity-breaking WSM we use a tight-binding lattice Hamiltonian with Wilson-Dirac fermions. This model features a non-trivial phase diagram and has a phase (Aoki phase/axionic insulator phase) with spontaneously broken CP symmetry, corresponding to the phase with spontaneously broken chiral symmetry for interacting continuum Dirac fermions. We use a mean-field ansatz to study the CME in spatially modulated magnetic fields and find that it vanishes in the Aoki phase. Moreover, our calculations show that outside of the Aoki phase the electron interaction has only a minor influence on the CME. We observe no enhancement of the magnitude of the CME current. For our non-perturbative study of the CSE in QCD we use the framework of lattice QCD with overlap fermions. We work in the quenched approximation to avoid the sign problem that comes with introducing a finite chemical potential on the lattice. The overlap operator calls for the evaluation of the sign function of a matrix with a dimension proportional to the volume
Chiral near-fields around chiral dolmen nanostructure
International Nuclear Information System (INIS)
Fu, Tong; Wang, Tiankun; Chen, Yuyan; Wang, Yongkai; Qu, Yu; Zhang, Zhongyue
2017-01-01
Discriminating the handedness of the chiral molecule is of great importance in the field of pharmacology and biomedicine. Enhancing the chiral near-field is one way to increase the chiral signal of chiral molecules. In this paper, the chiral dolmen nanostructure (CDN) is proposed to enhance the chiral near-field. Numerical results show that the CDN can increase the optical chirality of the near-field by almost two orders of magnitude compared to that of a circularly polarized incident wave. In addition, the optical chirality of the near-field of the bonding mode is enhanced more than that of the antibonding mode. These results provide an effective method for tailoring the chiral near-field for biophotonics sensors. (paper)
Chiral Gold Nanoclusters: Atomic Level Origins of Chirality.
Zeng, Chenjie; Jin, Rongchao
2017-08-04
Chiral nanomaterials have received wide interest in many areas, but the exact origin of chirality at the atomic level remains elusive in many cases. With recent significant progress in atomically precise gold nanoclusters (e.g., thiolate-protected Au n (SR) m ), several origins of chirality have been unveiled based upon atomic structures determined by using single-crystal X-ray crystallography. The reported chiral Au n (SR) m structures explicitly reveal a predominant origin of chirality that arises from the Au-S chiral patterns at the metal-ligand interface, as opposed to the chiral arrangement of metal atoms in the inner core (i.e. kernel). In addition, chirality can also be introduced by a chiral ligand, manifested in the circular dichroism response from metal-based electronic transitions other than the ligand's own transition(s). Lastly, the chiral arrangement of carbon tails of the ligands has also been discovered in a very recent work on chiral Au 133 (SR) 52 and Au 246 (SR) 80 nanoclusters. Overall, the origins of chirality discovered in Au n (SR) m nanoclusters may provide models for the understanding of chirality origins in other types of nanomaterials and also constitute the basis for the development of various applications of chiral nanoparticles. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
SU(3) chiral symmetry for baryons
International Nuclear Information System (INIS)
Dmitrasinovic, V.
2011-01-01
Three-quark nucleon interpolating fields in QCD have well-defined SU L (3)xSU R (3) and U A (1) chiral transformation properties, viz. [(6,3)+(3,6)], [(3,3-bar)+(3-bar,3)], [(8,1)+(1,8)] and their 'mirror' images. It has been shown (phenomenologically) in Ref. [2] that mixing of the [(6,3)+(3,6)] chiral multiplet with one ordinary ('naive') and one 'mirror' field belonging to the [(3,3-bar)+(3-bar,3)], [(8,1)+(1,8)] multiplets can be used to fit the values of the isovector (g A (3) ) and the flavor-singlet (isoscalar) axial coupling (g A (0) ) of the nucleon and then predict the axial F and D coefficients, or vice versa, in reasonable agreement with experiment. In an attempt to derive such mixing from an effective Lagrangian, we construct all SU L (3)xSU R (3) chirally invariant non-derivative one-meson-baryon interactions and then calculate the mixing angles in terms of baryons' masses. It turns out that there are (strong) selection rules: for example, there is only one non-derivative chirally symmetric interaction between J 1/2 fields belonging to the [(6,3)+(3,6)] and the [(3,3-bar)+(3-bar,3)] chiral multiplets, that is also U A (1) symmetric. We also study the chiral interactions of the [(3,3-bar)+(3-bar,3)] and [(8,1)+(1,8)] nucleon fields. Again, there are selection rules that allow only one off-diagonal non-derivative chiral SU L (3)xSU R (3) interaction of this type, that also explicitly breaks the U A (1) symmetry. We use this interaction to calculate the corresponding mixing angles in terms of baryon masses and fit two lowest lying observed nucleon (resonance) masses, thus predicting the third (J = 1/2, I = 3/2)Δ resonance, as well as one or two flavor-singlet Λ hyperon(s), depending on the type of mixing. The effective chiral Lagrangians derived here may be applied to high density matter calculations.
Poladian, L; Straton, M; Docherty, A; Argyros, A
2011-01-17
We investigate the properties of optical fibres made from chiral materials, in which a contrast in optical activity forms the waveguide, rather than a contrast in the refractive index; we refer to such structures as pure chiral fibres. We present a mathematical formulation for solving the modes of circularly symmetric examples of such fibres and examine the guidance and polarisation properties of pure chiral step-index, Bragg and photonic crystal fibre designs. Their behaviour is shown to differ for left- and right-hand circular polarisation, allowing circular polarisations to be isolated and/or guided by different mechanisms, as well as differing from equivalent non-chiral fibres. The strength of optical activity required in each case is quantified.
Relativistic Chiral Kinetic Theory
International Nuclear Information System (INIS)
Stephanov, Mikhail
2016-01-01
This very brief review of the recent progress in chiral kinetic theory is based on the results of Refs. [J.-Y. Chen, D. T. Son, M. A. Stephanov, H.-U. Yee, Y. Yin, Lorentz Invariance in Chiral Kinetic Theory, Phys. Rev. Lett. 113 (18) (2014) 182302. doi: (10.1103/PhysRevLett.113.182302); J.-Y. Chen, D. T. Son, M. A. Stephanov, Collisions in Chiral Kinetic Theory, Phys. Rev. Lett. 115 (2) (2015) 021601. doi: (10.1103/PhysRevLett.115.021601); M. A. Stephanov, H.-U. Yee, The no-drag frame for anomalous chiral fluid, Phys. Rev. Lett. 116 (12) (2016) 122302. doi: (10.1103/PhysRevLett.116.122302)].
Relativistic Chiral Kinetic Theory
Energy Technology Data Exchange (ETDEWEB)
Stephanov, Mikhail
2016-12-15
This very brief review of the recent progress in chiral kinetic theory is based on the results of Refs. [J.-Y. Chen, D. T. Son, M. A. Stephanov, H.-U. Yee, Y. Yin, Lorentz Invariance in Chiral Kinetic Theory, Phys. Rev. Lett. 113 (18) (2014) 182302. doi: (10.1103/PhysRevLett.113.182302); J.-Y. Chen, D. T. Son, M. A. Stephanov, Collisions in Chiral Kinetic Theory, Phys. Rev. Lett. 115 (2) (2015) 021601. doi: (10.1103/PhysRevLett.115.021601); M. A. Stephanov, H.-U. Yee, The no-drag frame for anomalous chiral fluid, Phys. Rev. Lett. 116 (12) (2016) 122302. doi: (10.1103/PhysRevLett.116.122302)].
Energy Technology Data Exchange (ETDEWEB)
Becher,
2002-08-08
After contrasting the low energy effective theory for the baryon sector with one for the Goldstone sector, I use the example of pion nucleon scattering to discuss some of the progress and open issues in baryon chiral perturbation theory.
Vortex in the chiral quark model
Hadasz, Leszek
1995-02-01
We construct the classical vortex solution in the model of chiral field interacting with the non-Abelian SU(2) gauge field. This solution is topologically nontrivial and well localized. We discuss its relevance for effective hadron models based on the flux-tube picture and the possibility of its extension to the higher symmetry gauge groups SU(N).
Generalized chiral perturbation theory
International Nuclear Information System (INIS)
Knecht, M.; Stern, J.
1994-01-01
The Generalized Chiral Perturbation Theory enlarges the framework of the standard χPT (Chiral Perturbation Theory), relaxing certain assumptions which do not necessarily follow from QCD or from experiment, and which are crucial for the usual formulation of the low energy expansion. In this way, experimental tests of the foundations of the standard χPT become possible. Emphasis is put on physical aspects rather than on formal developments of GχPT. (author). 31 refs
Generalized chiral membrane dynamics
International Nuclear Information System (INIS)
Cordero, R.; Rojas, E.
2003-01-01
We develop the dynamics of the chiral superconducting membranes (with null current) in an alternative geometrical approach. Besides of this, we show the equivalence of the resulting description with the one known Dirac-Nambu-Goto (DNG) case. Integrability for chiral string model is obtained using a proposed light-cone gauge. In a similar way, domain walls are integrated by means of a simple Ansatz. (Author)
Disoriented chiral condensate: Theory and phenomenology
International Nuclear Information System (INIS)
Bjorken, J.D.
1997-12-01
These notes are an abbreviated version of lectures given at the 1997 Zakopane School. They contain two topics. The first is a description in elementary terms of the basic ideas underlying the speculative hypothesis that pieces of strong-interaction vacuum with a rotated chiral order parameter, disoriented chiral condensate or DCC, might be produced in high energy elementary particle collisions. The second topic is a discussion of the phenomenological techniques which may be applied to data in order to experimentally search for the existence of DCC
International Nuclear Information System (INIS)
Sharpe, S.R.
1992-04-01
I develop a diagrammatic method for calculating chiral logarithms in the quenched approximation. While not rigorous, the method is based on physically reasonable assumptions, which can be tested by numerical simulations. The main results are that, at leading order in the chiral expansion, (a) there are no chiral logarithms in quenched f π m u = m d ; (b) the chiral logarithms in B K and related kaon B-parameters are, for m d = m s the same in the quenched approximation as in the full theory (c) for m π and the condensate, there are extra chiral logarithms due to loops containing the η', which lead to a peculiar non-analytic dependence of these quantities on the bare quark mass. Following the work of Gasser and Leutwyler, I discuss how there is a predictable finite volume dependence associated with each chiral logarithm. I compare the resulting predictions with numerical results: for most quantities the expected volume dependence is smaller than the errors. but for B V and B A there is an observed dependence which is consistent with the predictions
Broken chiral symmetry and the structure of hadrons
International Nuclear Information System (INIS)
Spence, W.L.
1982-01-01
The spontaneous breaking of chiral symmetry plays a decisive role in the structure of hadrons composed of light quarks. The formalism by which the dynamics of chiral symmetry breaking and its implications for hadronic structure can be explored in a simplified world in which fully relativistic zero-bare-mass quarks interact through a chirally symmetric instantaneous confining potential is presented. By thus modeling the essentials of the chiral limit-N/sub c/ infinity limit of QCD contact is made with the successes of existent semiphenomenological models of hadrons but post assumptions which explicitly violate chiral symetry are avoided. This revised approach then makes possible a unification of the dynamics of hadron structure with the mechanism of spontaneous chiral breaking and guarantees the appearance of the correct Goldstone excitations. The chiral breaking order parameter (absolute value anti psi psi), effective quark mass, and Goldstone boson wave function are obtainable by solving a single non-linear integral equation once a potential has been prescribed. The stability of the chiral asymmetric vacuum must then be established by studying the linear eigenvalue problem which determines the spectrum of states with vacuum quantum numbers. The nature of the instability of the chiral symmetric vacuum that leads to spontaneous symmetry breaking is explained and its apparent contingency on details of the dynamics is emphasized. It is argued that a single massless fermion in a chirally symmetric potential does form bound states for which a semi-classical description is given. Coupling to vacuum pairs of such bound states occasions the possibility of chiral symmetry breakdown
Chiral charge erasure via thermal fluctuations of magnetic helicity
International Nuclear Information System (INIS)
Long, Andrew J.; Sabancilar, Eray
2016-01-01
We consider a relativistic plasma of fermions coupled to an Abelian gauge field and carrying a chiral charge asymmetry, which might arise in the early Universe through baryogenesis. It is known that on large length scales, λ≳1/(αμ_5), the chiral anomaly opens an instability toward the erasure of chiral charge and growth of magnetic helicity. Here the chemical potential μ_5 parametrizes the chiral asymmetry and α is the fine-structure constant. We study the process of chiral charge erasure through the thermal fluctuations of magnetic helicity and contrast with the well-studied phenomenon of Chern-Simons number diffusion. Through the fluctuation-dissipation theorem we estimate the amplitude and time scale of helicity fluctuations on the length scale λ, finding δ H∼λT and τ∼αλ"3T"2 for a relativistic plasma at temperature T. We argue that the presence of a chiral asymmetry allows the helicity to grow diffusively for a time t∼T"3/(α"5μ_5"4) until it reaches an equilibrium value H∼μ_5T"2/α, and the chiral asymmetry is partially erased. If the chiral asymmetry is small, μ_5< T/α, this avenue for chiral charge erasure is found to be slower than the chiral magnetic effect for which t∼T/(α"3μ_5"2). This mechanism for chiral charge erasure can be important for the hypercharge sector of the Standard Model as well as extensions including U(1) gauge interactions, such as asymmetric dark matter models.
Attosecond-resolved photoionization of chiral molecules.
Beaulieu, S; Comby, A; Clergerie, A; Caillat, J; Descamps, D; Dudovich, N; Fabre, B; Géneaux, R; Légaré, F; Petit, S; Pons, B; Porat, G; Ruchon, T; Taïeb, R; Blanchet, V; Mairesse, Y
2017-12-08
Chiral light-matter interactions have been investigated for two centuries, leading to the discovery of many chiroptical processes used for discrimination of enantiomers. Whereas most chiroptical effects result from a response of bound electrons, photoionization can produce much stronger chiral signals that manifest as asymmetries in the angular distribution of the photoelectrons along the light-propagation axis. We implemented self-referenced attosecond photoelectron interferometry to measure the temporal profile of the forward and backward electron wave packets emitted upon photoionization of camphor by circularly polarized laser pulses. We measured a delay between electrons ejected forward and backward, which depends on the ejection angle and reaches 24 attoseconds. The asymmetric temporal shape of electron wave packets emitted through an autoionizing state further reveals the chiral character of strongly correlated electronic dynamics. Copyright © 2017 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.
Hidden QCD in Chiral Gauge Theories
DEFF Research Database (Denmark)
Ryttov, Thomas; Sannino, Francesco
2005-01-01
The 't Hooft and Corrigan-Ramond limits of massless one-flavor QCD consider the two Weyl fermions to be respectively in the fundamental representation or the two index antisymmetric representation of the gauge group. We introduce a limit in which one of the two Weyl fermions is in the fundamental...... representation and the other in the two index antisymmetric representation of a generic SU(N) gauge group. This theory is chiral and to avoid gauge anomalies a more complicated chiral theory is needed. This is the generalized Georgi-Glashow model with one vector like fermion. We show that there is an interesting...... phase in which the considered chiral gauge theory, for any N, Higgses via a bilinear condensate: The gauge interactions break spontaneously to ordinary massless one-flavor SU(3) QCD. The additional elementary fermionic matter is uncharged under this SU(3) gauge theory. It is also seen that when...
Chiral crossover transition in a finite volume
Shi, Chao; Jia, Wenbao; Sun, An; Zhang, Liping; Zong, Hongshi
2018-02-01
Finite volume effects on the chiral crossover transition of strong interactions at finite temperature are studied by solving the quark gap equation within a cubic volume of finite size L. With the anti-periodic boundary condition, our calculation shows the chiral quark condensate, which characterizes the strength of dynamical chiral symmetry breaking, decreases as L decreases below 2.5 fm. We further study the finite volume effects on the pseudo-transition temperature {T}{{c}} of the crossover, showing a significant decrease in {T}{{c}} as L decreases below 3 fm. Supported by National Natural Science Foundation of China (11475085, 11535005, 11690030, 51405027), the Fundamental Research Funds for the Central Universities (020414380074), China Postdoctoral Science Foundation (2016M591808) and Open Research Foundation of State Key Lab. of Digital Manufacturing Equipment & Technology in Huazhong University of Science & Technology (DMETKF2015015)
Transfer of chirality from light to a Disperse Red 1 molecular glass surface.
Mazaheri, Leila; Lebel, Olivier; Nunzi, Jean-Michel
2017-12-01
Chiral structures and materials interact with light in well-documented ways, but light can also interact with achiral materials to generate chirality by inscribing its asymmetric configuration on photoresponsive materials, such as azobenzene derivatives. While it is thus possible to generate both two-dimensional (2D) and three-dimensional (3D) chirality, 2D chirality is especially attractive because of its non-reciprocity. Herein, 2D chirality is induced on the surface of a glass-forming Disperse Red 1 derivative by irradiation with a single laser beam, yielding crossed spontaneous surface relief gratings with different pitches. Azimuth rotations up to 10° have been observed, and the absence of 3D chirality has been confirmed. This method thus allows generating non-reciprocal planar chiral objects by a simple, single irradiation process on a thin film of a material that can easily be processed over large areas or onto small objects.
The role of resonances in chiral perturbation theory
International Nuclear Information System (INIS)
Ecker, G.; Rafael, E. de
1988-09-01
The strong interactions of low-lying meson resonances (spin ≤ 1) with the octet of pseudoscalar mesons (π,Κ,η) are considered to lowest order in the derivative expansion of chiral SU(3). The resonance contributions to the coupling constants of the O(p 4 ) effective chiral lagrangian involving pseudoscalar fields only are determined. These low-energy coupling constants are found to be dominated by the resonance contributions. Although we do not treat the vector and axial-vector mesons as gauge bosons of local chiral symmetry, vector meson dominance emerges as a prominent result of our analysis. As a further application of chiral resonance couplings, we calculate the electromagnetic pion mass difference to lowest order in chiral perturbation theory with explicit resonance fields. 29 refs., 2 figs., 5 tabs. (Author)
Asymmetric Michael Addition Mediated by Chiral Ionic Liquids
Suzuki, Yumiko
2018-01-01
Chiral ionic liquids with a focus on their applications in asymmetric Michael additions and related reactions were reviewed. The examples were classified on the basis of the mode of asymmetric induction (e.g., external induction/non-covalent interaction or internal induction/covalent bond formation), the roles in reactions (as a solvent or catalyst), and their structural features (e.g., imidazolium-based chiral cations, other chiral oniums; proline derivatives). Most of the reactions with high chiral induction are Michael addition of ketones or aldehydes to chalcones or nitrostyrenes where proline-derived chiral ionic liquids catalyze the reaction through enamine/ iminium formation. Many reports demonstrate the recyclability of ionic liquid-tagged pyrrolidines. PMID:29861702
Asymmetric Michael Addition Mediated by Chiral Ionic Liquids.
Suzuki, Yumiko
2018-06-01
Chiral ionic liquids with a focus on their applications in asymmetric Michael additions and related reactions were reviewed. The examples were classified on the basis of the mode of asymmetric induction (e.g., external induction/non-covalent interaction or internal induction/covalent bond formation), the roles in reactions (as a solvent or catalyst), and their structural features (e.g., imidazolium-based chiral cations, other chiral oniums; proline derivatives). Most of the reactions with high chiral induction are Michael addition of ketones or aldehydes to chalcones or nitrostyrenes where proline-derived chiral ionic liquids catalyze the reaction through enamine/ iminium formation. Many reports demonstrate the recyclability of ionic liquid-tagged pyrrolidines.
Chiral Recognition by Fluorescence: One Measurement for Two Parameters
Directory of Open Access Journals (Sweden)
Shanshan Yu
2014-01-01
Full Text Available This outlook describes two strategies to simultaneously determine the enantiomeric composition and concentration of a chiral substrate by a single fluorescent measurement. One strategy utilizes a pseudoenantiomeric sensor pair that is composed of a 1,1′-bi-2-naphthol-based amino alcohol and a partially hydrogenated 1,1′-bi-2-naphthol-based amino alcohol. These two molecules have the opposite chiral configuration with fluorescent enhancement at two different emitting wavelengths when treated with the enantiomers of mandelic acid. Using the sum and difference of the fluorescent intensity at the two wavelengths allows simultaneous determination of both concentration and enantiomeric composition of the chiral acid. The other strategy employs a 1,1′-bi-2-naphthol-based trifluoromethyl ketone that exhibits fluorescent enhancement at two emission wavelengths upon interaction with a chiral diamine. One emission responds mostly to the concentration of the chiral diamine and the ratio of the two emissions depends on the chiral configuration of the enantiomer but independent of the concentration, allowing both the concentration and enantiomeric composition of the chiral diamine to be simultaneously determined. These strategies would significantly simplify the practical application of the enantioselective fluorescent sensors in high-throughput chiral assay.
Autoamplification of molecular chirality through the induction of supramolecular chirality
van Dijken, Derk Jan; Beierle, John M.; Stuart, Marc C. A.; Szymanski, Wiktor; Browne, Wesley R.; Feringa, Ben L.
2014-01-01
The novel concept for the autoamplification of molecular chirality, wherein the amplification proceeds through the induction of supramolecular chirality, is presented. A solution of prochiral, ring-open diarylethenes is doped with a small amount of their chiral, ring-closed counterpart. The
Algebraic study of chiral anomalies
Indian Academy of Sciences (India)
Chiral anomalies; gauge theories; bundles; connections; quantum ﬁeld ... The algebraic structure of chiral anomalies is made globally valid on non-trivial bundles by the introduction of a ﬁxed background connection. ... Current Issue : Vol.
Silver Films with Hierarchical Chirality.
Ma, Liguo; Cao, Yuanyuan; Duan, Yingying; Han, Lu; Che, Shunai
2017-07-17
Physical fabrication of chiral metallic films usually results in singular or large-sized chirality, restricting the optical asymmetric responses to long electromagnetic wavelengths. The chiral molecule-induced formation of silver films prepared chemically on a copper substrate through a redox reaction is presented. Three levels of chirality were identified: primary twisted nanoflakes with atomic crystal lattices, secondary helical stacking of these nanoflakes to form nanoplates, and tertiary micrometer-sized circinates consisting of chiral arranged nanoplates. The chiral Ag films exhibited multiple plasmonic absorption- and scattering-based optical activities at UV/Vis wavelengths based on their hierarchical chirality. The Ag films showed chiral selectivity for amino acids in catalytic electrochemical reactions, which originated from their primary atomic crystal lattices. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Chiral anomalies and differential geometry
International Nuclear Information System (INIS)
Zumino, B.
1983-10-01
Some properties of chiral anomalies are described from a geometric point of view. Topics include chiral anomalies and differential forms, transformation properties of the anomalies, identification and use of the anomalies, and normalization of the anomalies. 22 references
Li, Li; Hu, Chuanjiang; Shi, Bo; Wang, Yong
2016-05-10
A new host-guest system is formed between a benzene tricarboxamide linked zinc trisporphyrinate and a chiral monoalcohol (1-phenylethylalcohol). CD spectra show the chirality induction and inversion processes, which are controlled by the corresponding 1 : 1 and 1 : 2 coordination complexes. The binding constants calculated by UV-vis and CD spectral data are much larger than that for [Zn(TPP)] (TPP = tetraphenylporphyrin). The crystallographic structure of the host-guest complex reveals that multiple intramolecular hydrogen bonds and π-π interactions could contribute to its high binding affinity to 1-phenylethylalcohol. The DFT calculations suggest that the spatial orientations of porphyrin moieties change from the 1 : 1 complex to the 1 : 2 complex. The chirality induction and inversion processes are rationalized by the summation of pairwise interactions among multichromophores according to pairwise additivity.
Chiral Synthons in Pesticide Syntheses
Feringa, Bernard
1988-01-01
The use of chiral synthons in the preparation of enantiomerically pure pesticides is described in this chapter. Several routes to chiral synthons based on asymmetric synthesis or on natural products are illustrated. Important sources of chiral building blocks are reviewed. Furthermore the
Holographic Chiral Magnetic Spiral
International Nuclear Information System (INIS)
Kim, Keun-Young; Sahoo, Bindusar; Yee, Ho-Ung
2010-06-01
We study the ground state of baryonic/axial matter at zero temperature chiral-symmetry broken phase under a large magnetic field, in the framework of holographic QCD by Sakai-Sugimoto. Our study is motivated by a recent proposal of chiral magnetic spiral phase that has been argued to be favored against previously studied phase of homogeneous distribution of axial/baryonic currents in terms of meson super-currents dictated by triangle anomalies in QCD. Our results provide an existence proof of chiral magnetic spiral in strong coupling regime via holography, at least for large axial chemical potentials, whereas we don't find the phenomenon in the case of purely baryonic chemical potential. (author)
Tian, Xin; Meng, Fanbin; Meng, Fanchen; Chen, Xiangnan; Guo, Yifan; Wang, Ying; Zhu, Wenjun; Zhou, Zuowan
2017-05-10
In this study, we designed a dual-chirality hierarchical structure to achieve a synergistically enhanced effect in microwave absorption via the hybridization of nanomaterials. Herein, polyaniline (PANi) nanorods with tunable chirality are grown on helical carbon nanotubes (HCNTs), a typical nanoscale chiral structure, through in situ polymerization. The experimental results show that the hierarchical hybrids (PANi@HCNTs) exhibit distinctly dual chirality and a significant enhancement in electromagnetic (EM) losses compared to those of either pure PANi or HCNTs. The maximum reflection loss of the as-prepared hybrids can reach -32.5 dB at 8.9 GHz. Further analysis demonstrates that combinations of chiral acid-doped PANi and coiled HCNTs with molecular and nanoscale chirality lead to synergistic effects resulting from the dual chirality. The so-called cross-polarization may result in additional interactions with induced EM waves in addition to multiscaled relaxations from functional groups and interfacial polarizations, which can benefit EM absorption.
International Nuclear Information System (INIS)
Ecker, G.
1996-06-01
After a general introduction to the structure of effective field theories, the main ingredients of chiral perturbation theory are reviewed. Applications include the light quark mass ratios and pion-pion scattering to two-loop accuracy. In the pion-nucleon system, the linear σ model is contrasted with chiral perturbation theory. The heavy-nucleon expansion is used to construct the effective pion-nucleon Lagrangian to third order in the low-energy expansion, with applications to nucleon Compton scattering. (author)
International Nuclear Information System (INIS)
Cuypers, F.
1990-01-01
Chiral colour is considered in a general framework where the coupling constants associated with each SU(3) component are allowed to be different. To reproduce QCD at low energy, gluons and axigluons cannot then be maximally mixed. Present data form e + e - colliders contrains the axigluon mass to values between 50 GeV and 375 GeV whilst the mixing angle is bounded by 13deg and 45deg. The lower limit of the axigluon mass is a definite bound at 90% C.L., whereas the upper limit only applies if chiral colour is to explain the anomalously high rates of hadron production at TRISTAN. (orig.)
Chirality: from QCD to condensed matter
International Nuclear Information System (INIS)
Kharzeev, D.
2015-01-01
This lecture is about chirality and consists of 4 parts. In the first part a general introduction of chirality is given and its implementation in nuclear and particle physics, in particular the chiral magnetic effect, as well as Chirality in quantum materials (CME, optoelectronics, photonics) are discussed. The 2nd lecture is about the chiral magnetic effect. The 3rd lecture deals with the chiral magnetic effect and hydrodynamics and the last part with chirality and light. (nowak)
Chiral algebras for trinion theories
International Nuclear Information System (INIS)
Lemos, Madalena; Peelaers, Wolfger
2015-01-01
It was recently understood that one can identify a chiral algebra in any four-dimensional N=2 superconformal theory. In this note, we conjecture the full set of generators of the chiral algebras associated with the T n theories. The conjecture is motivated by making manifest the critical affine module structure in the graded partition function of the chiral algebras, which is computed by the Schur limit of the superconformal index for T n theories. We also explicitly construct the chiral algebra arising from the T 4 theory. Its null relations give rise to new T 4 Higgs branch chiral ring relations.
Chiral forces and molecular dissymmetry
International Nuclear Information System (INIS)
Mohan, R.
1992-01-01
Chiral molecules leading to helical macromolecules seem to preserve information and extend it better. In the biological world RNA is the very paradigm for self-replication, elongation and autocatalytic editing. The nucleic acid itself is not chiral. It acquires its chirality by association with D-sugars. Although the chiral information or selectivity put in by the unit monomer is no longer of much interest to the biologists - they tend to leave it to the Darwinian selection principle to take care of it as illustrated by Frank's model - it is vital to understand the origin of chirality. There are three different approaches for the chiral origin of life: (1) Phenomenological, (2) Electromagnetic molecular and Coriolis forces and (3) Atomic or nuclear force, the neutral weak current. The phenomenological approach involves spontaneous symmetry breaking fluctuations in far for equilibrium systems or nucleation and crystallization. Chance plays a major role in the chiral molecule selected
Antikaon induced Ξ production from a chiral model at NLO
Directory of Open Access Journals (Sweden)
Feijoo A.
2014-01-01
Full Text Available We study the meson-baryon interaction in the strangeness S = −1 sector using a chiral unitary approach, paying particular attention to the K̄N → KΞ reaction, especially important for constraining the next-to-leading order chiral terms, and considering also the effect of high spin hyperonic resonances. We also present results for the production of Ξ hyperons in nuclei
Chiral phase transition in a covariant nonlocal NJL model
International Nuclear Information System (INIS)
General, I.; Scoccola, N.N.
2001-01-01
The properties of the chiral phase transition at finite temperature and chemical potential are investigated within a nonlocal covariant extension of the NJL model based on a separable quark-quark interaction. We find that for low values of T the chiral transition is always of first order and, for finite quark masses, at certain end point the transition turns into a smooth crossover. Our predictions for the position of this point is similar, although somewhat smaller, than previous estimates. (author)
Insight into the chiral induction in supramolecular stacks through preferential chiral salvation
George, S.J.; Tomovic, Z.; Schenning, A.P.H.J.; Meijer, E.W.
2011-01-01
Preferred handedness in the supramolecular chirality of self-assembled achiral oligo(p-phenylenevinylene) (OPV) derivatives is induced by chiral solvents and spectroscopic probing provides insight into the mechanistic aspects of this chiral induction through chiral solvation
Homochiral Evolution in Self-Assembled Chiral Polymers and Block Copolymers.
Wen, Tao; Wang, Hsiao-Fang; Li, Ming-Chia; Ho, Rong-Ming
2017-04-18
The significance of chirality transfer is not only involved in biological systems, such as the origin of homochiral structures in life but also in man-made chemicals and materials. How the chiral bias transfers from molecular level (molecular chirality) to helical chain (conformational chirality) and then to helical superstructure or phase (hierarchical chirality) from self-assembly is vital for the chemical and biological processes in nature, such as communication, replication, and enzyme catalysis. In this Account, we summarize the methodologies for the examination of homochiral evolution at different length scales based on our recent studies with respect to the self-assembly of chiral polymers and chiral block copolymers (BCPs*). A helical (H*) phase to distinguish its P622 symmetry from that of normal hexagonally packed cylinder phase was discovered in the self-assembly of BCPs* due to the chirality effect on BCP self-assembly. Enantiomeric polylactide-containing BCPs*, polystyrene-b-poly(l-lactide) (PS-PLLA) and polystyrene-b-poly(d-lactide) (PS-PDLA), were synthesized for the examination of homochiral evolution. The optical activity (molecular chirality) of constituted chiral repeating unit in the chiral polylactide is detected by electronic circular dichroism (ECD) whereas the conformational chirality of helical polylactide chain can be explicitly determined by vibrational circular dichroism (VCD). The H* phases of the self-assembled polylactide-containing BCPs* can be directly visualized by 3D transmission electron microscopy (3D TEM) technique at which the handedness (hierarchical chirality) of the helical nanostructure is thus determined. The results from the ECD, VCD, and 3D TEM for the investigated chirality at different length scales suggest the homochiral evolution in the self-assembly of the BCPs*. For chiral polylactides, twisted lamellae in crystalline banded spherulite can be formed by dense packing scheme and effective interactions upon helical
International Nuclear Information System (INIS)
Lyubovitskij, V.E.; Gutsche, Th.; Faessler, Amand; Mau, R. Vinh
2002-01-01
We apply the perturbative chiral quark model to the study of the low-energy πN interaction. Using an effective chiral Lagrangian we reproduce the Weinberg-Tomozawa result for the S-wave πN scattering lengths. After inclusion of the photon field we give predictions for the electromagnetic O(p 2 ) low-energy couplings of the chiral perturbation theory effective Lagrangian that define the electromagnetic mass shifts of nucleons and first-order (e 2 ) radiative corrections to the πN scattering amplitude. Finally, we estimate the leading isospin-breaking correction to the strong energy shift of the π - p atom in the 1s state, which is relevant for the experiment 'pionic hydrogen' at PSI
Inversion of Supramolecular Chirality by Sonication-Induced Organogelation
Maity, Sibaprasad; Das, Priyadip; Reches, Meital
2015-01-01
Natural helical structures have inspired the formation of well-ordered peptide-based chiral nanostructures in vitro. These structures have drawn much attention owing to their diverse applications in the area of asymmetric catalysts, chiral photonic materials, and nanoplasmonics. The self-assembly of two enantiomeric fluorinated aromatic dipeptides into ordered chiral fibrillar nanostructures upon sonication is described. These fibrils form organogels. Our results clearly indicate that fluorine-fluorine interactions play an important role in self-assembly. Circular dichroism analysis revealed that both peptides (peptides 1 and 2), containing two fluorines, depicted opposite cotton effects in their monomeric form compared with their aggregated form. This shows that supramolecular chirality inversion took place during the stimuli-responsive self-aggregation process. Conversely, peptide 3, containing one fluorine, did not exhibit chirality inversion in sonication-induced organogelation. Therefore, our results clearly indicate that fluorination plays an important role in the organogelation process of these aromatic dipeptides. Our findings may have broad implications regarding the design of chiral nanostructures for possible applications such as chiroptical switches, asymmetric catalysis, and chiral recognitions. PMID:26553508
DEFF Research Database (Denmark)
Contini, G.; Turchini, S.; Sanna, Simone
2012-01-01
Studies of self-assembled chiral molecules on achiral metallic surfaces have mostly focused on the determination of the geometry of adsorbates and their electronic structure. The aim of this paper is to provide direct information on the chirality character of the system and on the chirality...... transfer from molecules to substrate by means of circular dichroism in the angular distribution of valence photoelectrons for the extended domain of the chiral self-assembled molecular structure, formed by alaninol adsorbed on Cu(100). We show, by the dichroic behavior of a mixed molecule–copper valence...... state, that the presence of molecular chiral domains induces asymmetry in the interaction with the substrate and locally transfers the chiral character to the underlying metal atoms participating in the adsorption process; combined information related to the asymmetry of the initial electronic state...
Goldstone bosons in a crystalline chiral phase
Energy Technology Data Exchange (ETDEWEB)
Schramm, Marco
2017-07-24
The phase diagram of strong interaction matter is expected to exhibit a rich structure. Different models have shown, that crystalline phases with a spatially varying chiral condensate can occur in the regime of low temperatures and moderate densities, where they replace the first-order phase transition found for spatially constant order parameters. We investigate this inhomogeneous phase, where in addition to the chiral symmetry, translational and rotational symmetry are broken as well, in a two flavor Nambu--Jona-Lasinio model. The main goal of this work is to describe the Goldstone bosons in this phase, massless excitations that occur for spontaneously broken symmetries. We take one of the simplest possible modulations, the chiral density wave, and show how to derive the quark propagator of the theory analytically, by means of transformations in chiral and momentum space. We apply this to a test case for the gap equation. We show the derivation of Nambu-Goldstone modes in the inhomogeneous phase and find, that for our case only three different modes have to be taken into account. We proceed to calculate the Goldstone boson related to the breaking of spatial symmetry, which can be related to the neutral pion. By evaluating a Bethe-Salpeter equation, we can show, that we have indeed found a Goldstone boson and give its dispersion relation in terms of momenta perpendicular, as well as parallel to the mass modulation.
Chiral damping of magnetic domain walls
Jué , Emilie; Safeer, C. K.; Drouard, Marc; Lopez, Alexandre; Balint, Paul; Buda-Prejbeanu, Liliana; Boulle, Olivier; Auffret, Stephane; Schuhl, Alain; Manchon, Aurelien; Miron, Ioan Mihai; Gaudin, Gilles
2015-01-01
Structural symmetry breaking in magnetic materials is responsible for the existence of multiferroics1, current-induced spin–orbit torques2, 3, 4, 5, 6, 7 and some topological magnetic structures8, 9, 10, 11, 12. In this Letter we report that the structural inversion asymmetry (SIA) gives rise to a chiral damping mechanism, which is evidenced by measuring the field-driven domain-wall (DW) motion in perpendicularly magnetized asymmetric Pt/Co/Pt trilayers. The DW dynamics associated with the chiral damping and those with Dzyaloshinskii–Moriya interaction (DMI) exhibit identical spatial symmetry13, 14, 15, 16, 17, 18, 19. However, both scenarios are differentiated by their time reversal properties: whereas DMI is a conservative effect that can be modelled by an effective field, the chiral damping is purely dissipative and has no influence on the equilibrium magnetic texture. When the DW motion is modulated by an in-plane magnetic field, it reveals the structure of the internal fields experienced by the DWs, allowing one to distinguish the physical mechanism. The chiral damping enriches the spectrum of physical phenomena engendered by the SIA, and is essential for conceiving DW and skyrmion devices owing to its coexistence with DMI (ref. 20).
Goldstone bosons in a crystalline chiral phase
International Nuclear Information System (INIS)
Schramm, Marco
2017-01-01
The phase diagram of strong interaction matter is expected to exhibit a rich structure. Different models have shown, that crystalline phases with a spatially varying chiral condensate can occur in the regime of low temperatures and moderate densities, where they replace the first-order phase transition found for spatially constant order parameters. We investigate this inhomogeneous phase, where in addition to the chiral symmetry, translational and rotational symmetry are broken as well, in a two flavor Nambu--Jona-Lasinio model. The main goal of this work is to describe the Goldstone bosons in this phase, massless excitations that occur for spontaneously broken symmetries. We take one of the simplest possible modulations, the chiral density wave, and show how to derive the quark propagator of the theory analytically, by means of transformations in chiral and momentum space. We apply this to a test case for the gap equation. We show the derivation of Nambu-Goldstone modes in the inhomogeneous phase and find, that for our case only three different modes have to be taken into account. We proceed to calculate the Goldstone boson related to the breaking of spatial symmetry, which can be related to the neutral pion. By evaluating a Bethe-Salpeter equation, we can show, that we have indeed found a Goldstone boson and give its dispersion relation in terms of momenta perpendicular, as well as parallel to the mass modulation.
Chiral damping of magnetic domain walls
Jué, Emilie
2015-12-21
Structural symmetry breaking in magnetic materials is responsible for the existence of multiferroics1, current-induced spin–orbit torques2, 3, 4, 5, 6, 7 and some topological magnetic structures8, 9, 10, 11, 12. In this Letter we report that the structural inversion asymmetry (SIA) gives rise to a chiral damping mechanism, which is evidenced by measuring the field-driven domain-wall (DW) motion in perpendicularly magnetized asymmetric Pt/Co/Pt trilayers. The DW dynamics associated with the chiral damping and those with Dzyaloshinskii–Moriya interaction (DMI) exhibit identical spatial symmetry13, 14, 15, 16, 17, 18, 19. However, both scenarios are differentiated by their time reversal properties: whereas DMI is a conservative effect that can be modelled by an effective field, the chiral damping is purely dissipative and has no influence on the equilibrium magnetic texture. When the DW motion is modulated by an in-plane magnetic field, it reveals the structure of the internal fields experienced by the DWs, allowing one to distinguish the physical mechanism. The chiral damping enriches the spectrum of physical phenomena engendered by the SIA, and is essential for conceiving DW and skyrmion devices owing to its coexistence with DMI (ref. 20).
Anion-π Catalysts with Axial Chirality.
Wang, Chao; Matile, Stefan
2017-09-04
The idea of anion-π catalysis is to stabilize anionic transition states by anion-π interactions on aromatic surfaces. For asymmetric anion-π catalysis, π-acidic surfaces have been surrounded with stereogenic centers. This manuscript introduces the first anion-π catalysts that operate with axial chirality. Bifunctional catalysts with tertiary amine bases next to π-acidic naphthalenediimide planes are equipped with a bulky aromatic substituent in the imide position to produce separable atropisomers. The addition of malonic acid half thioesters to enolate acceptors is used for evaluation. In the presence of a chiral axis, the selective acceleration of the disfavored but relevant enolate addition was much better than with point chirality, and enantioselectivity could be observed for the first time for this reaction with small-molecule anion-π catalysts. Enantioselectivity increased with the π acidity of the π surface, whereas the addition of stereogenic centers around the aromatic plane did not cause further improvements. These results identify axial chirality of the active aromatic plane generated by atropisomerism as an attractive strategy for asymmetric anion-π catalysis. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Realization of chiral symmetry in the ERG
International Nuclear Information System (INIS)
Echigo, Yoshio; Igarashi, Yuji
2011-01-01
We discuss within the framework of the ERG how chiral symmetry is realized in a linear σ model. A generalized Ginsparg-Wilson relation is obtained from the Ward-Takahashi identities for the Wilson action assumed to be bilinear in the Dirac fields. We construct a family of its non-perturbative solutions. The family generates the most general solutions to the Ward-Takahashi identities. Some special solutions are discussed. For each solution in this family, chiral symmetry is realized in such a way that a change in the Wilson action under non-linear symmetry transformation is canceled with a change in the functional measure. We discuss that the family of solutions reduces via a field redefinition to a family of the Wilson actions with some composite object of the scalar fields which has a simple transformation property. For this family, chiral symmetry is linearly realized with a continuum analog of the operator extension of γ 5 used on the lattice. We also show that there exist some appropriate Dirac fields which obey the standard chiral transformations with γ 5 in contrast to the lattice case. Their Yukawa interaction with scalars, however, becomes non-linear. (author)
Detecting the chirality for coupled quantum dots
International Nuclear Information System (INIS)
Cao Huijuan; Hu Lian
2008-01-01
We propose a scheme to detect the chirality for a system consisting of three coupled quantum dots. The chirality is found to be determined by the frequency of the transition between chiral states under the chiral symmetry broken perturbation. The results are important to construct quantum gates and to demonstrate chiral entangle states in the triangle spin dots
Chiral fermions in asymptotically safe quantum gravity.
Meibohm, J; Pawlowski, J M
2016-01-01
We study the consistency of dynamical fermionic matter with the asymptotic safety scenario of quantum gravity using the functional renormalisation group. Since this scenario suggests strongly coupled quantum gravity in the UV, one expects gravity-induced fermion self-interactions at energies of the Planck scale. These could lead to chiral symmetry breaking at very high energies and thus to large fermion masses in the IR. The present analysis which is based on the previous works (Christiansen et al., Phys Rev D 92:121501, 2015; Meibohm et al., Phys Rev D 93:084035, 2016), concludes that gravity-induced chiral symmetry breaking at the Planck scale is avoided for a general class of NJL-type models. We find strong evidence that this feature is independent of the number of fermion fields. This finding suggests that the phase diagram for these models is topologically stable under the influence of gravitational interactions.
Pattern production through a chiral chasing mechanism
Woolley, Thomas E.
2017-09-01
Recent experiments on zebrafish pigmentation suggests that their typical black and white striped skin pattern is made up of a number of interacting chromatophore families. Specifically, two of these cell families have been shown to interact through a nonlocal chasing mechanism, which has previously been modeled using integro-differential equations. We extend this framework to include the experimentally observed fact that the cells often exhibit chiral movement, in that the cells chase, and run away, at angles different to the line connecting their centers. This framework is simplified through the use of multiple small limits leading to a coupled set of partial differential equations which are amenable to Fourier analysis. This analysis results in the production of dispersion relations and necessary conditions for a patterning instability to occur. Beyond the theoretical development and the production of new pattern planiforms we are able to corroborate the experimental hypothesis that the global pigmentation patterns can be dependent on the chirality of the chromatophores.
Deracemization of bilirubin as the marker of the chirality of micellar aggregates.
Sorrenti, Alessandro; Altieri, Barbara; Ceccacci, Francesca; Di Profio, Pietro; Germani, Raimondo; Giansanti, Luisa; Savelli, Gianfranco; Mancini, Giovanna
2012-01-01
The deracemization of bilirubin in micellar aggregates of structurally correlated chiral surfactants was studied by circular dichroism experiments and exploited as the marker of the expression of chirality of the aggregates. The obtained results suggest that the hydrophobic interactions control the transfer of chirality from the monomers to the aggregates, and that different regions of the same aggregate might feature opposite enantiorecognition capabilities. Copyright © 2011 Wiley-Liss, Inc.
Deep-Subwavelength Resolving and Manipulating of Hidden Chirality in Achiral Nanostructures.
Zu, Shuai; Han, Tianyang; Jiang, Meiling; Lin, Feng; Zhu, Xing; Fang, Zheyu
2018-04-24
The chiral state of light plays a vital role in light-matter interactions and the consequent revolution of nanophotonic devices and advanced modern chiroptics. As the light-matter interaction goes into the nano- and quantum world, numerous chiroptical technologies and quantum devices require precise knowledge of chiral electromagnetic modes and chiral radiative local density of states (LDOS) distributions in detail, which directly determine the chiral light-matter interaction for applications such as chiral light detection and emission. With classical optical techniques failing to directly measure the chiral radiative LDOS, deep-subwavelength imaging and control of circular polarization (CP) light associated phenomena are introduced into the agenda. Here, we simultaneously reveal the hidden chiral electromagnetic mode and acquire its chiral radiative LDOS distribution of a single symmetric nanostructure at the deep-subwavelength scale by using CP-resolved cathodoluminescence (CL) microscopy. The chirality of the symmetric nanostructure under normally incident light excitation, resulting from the interference between the symmetric and antisymmetric modes of the V-shaped nanoantenna, is hidden in the near field with a giant chiral distribution (∼99%) at the arm-ends, which enables the circularly polarized CL emission from the radiative LDOS hot-spot and the following active helicity control at the deep-subwavelength scale. The proposed V-shaped nanostructure as a functional unit is further applied to the helicity-dependent binary encoding and the two-dimensional display applications. The proposed physical principle and experimental configuration can promote the future chiral characterization and manipulation at the deep-subwavelength scale and provide direct guidelines for the optimization of chiral light-matter interactions for future quantum studies.
Chiral Lagrangians and quark condensate in nuclei
International Nuclear Information System (INIS)
Delorme, J.; Chanfray, G.; Ericson, M.
1996-03-01
The evolution of density of quark condensate in nuclear medium with interacting nucleons, including the short range correlations is examined. Two chiral models are used, the linear sigma model and the non-linear one. It is shown that the quark condensate, as other observables, is independent on the variant selected. The application to physical pions excludes the linear sigma model as a credible one. The non-linear models restricted to pure s-wave pion-nucleon scattering are examined. (author)
Dynamics of chiral oscillations: a comparative analysis with spin flipping
International Nuclear Information System (INIS)
Bernardini, A E
2006-01-01
Chiral oscillation as well as spin flipping effects correspond to quantum phenomena of fundamental importance in the context of particle physics and, in particular, of neutrino physics. From the point of view of first quantized theories, we are specifically interested in pointing out the differences between chirality and helicity by obtaining their dynamic equations for a fermionic Dirac-type particle (neutrino). We also identify both effects when the non-minimal coupling with an external (electro)magnetic field in the neutrino interacting Lagrangian is taken into account. We demonstrate that, however, there is no constraint between chiral oscillations, when it takes place in vacuum, and the process of spin flipping related to the helicity quantum number, which does not take place in vacuum. To conclude, we show that the origin of chiral oscillations (in vacuum) can be interpreted as projections of very rapid oscillations of position onto the longitudinal direction of momentum
Non-uniform chiral phase in effective chiral quark models
International Nuclear Information System (INIS)
Sadzikowski, M.; Broniowski, W.
2000-01-01
We analyze the phase diagram in effective chiral quark models (the Nambu-Jona-Lasinio model, the σ-model with quarks) and show that at the mean-field level a phase with a periodically-modulated chiral fields separates the usual phases with broken and restored chiral symmetry. A possible signal of such a phase is the production of multipion jets travelling in opposite directions, with individual pions having momenta of the order of several hundred MeV. This signal can be interpreted in terms of disoriented chiral condensates. (author)
Chiral Floquet Phases of Many-Body Localized Bosons
Directory of Open Access Journals (Sweden)
Hoi Chun Po
2016-12-01
Full Text Available We construct and classify chiral topological phases in driven (Floquet systems of strongly interacting bosons, with finite-dimensional site Hilbert spaces, in two spatial dimensions. The construction proceeds by introducing exactly soluble models with chiral edges, which in the presence of many-body localization (MBL in the bulk are argued to lead to stable chiral phases. These chiral phases do not require any symmetry and in fact owe their existence to the absence of energy conservation in driven systems. Surprisingly, we show that they are classified by a quantized many-body index, which is well defined for any MBL Floquet system. The value of this index, which is always the logarithm of a positive rational number, can be interpreted as the entropy per Floquet cycle pumped along the edge, formalizing the notion of quantum-information flow. We explicitly compute this index for specific models and show that the nontrivial topology leads to edge thermalization, which provides an interesting link between bulk topology and chaos at the edge. We also discuss chiral Floquet phases in interacting fermionic systems and their relation to chiral bosonic phases.
Chiral magnetic effect of light
Hayata, Tomoya
2018-05-01
We study a photonic analog of the chiral magnetic (vortical) effect. We discuss that the vector component of magnetoelectric tensors plays a role of "vector potential," and its rotation is understood as "magnetic field" of a light. Using the geometrical optics approximation, we show that "magnetic fields" cause an anomalous shift of a wave packet of a light through an interplay with the Berry curvature of photons. The mechanism is the same as that of the chiral magnetic (vortical) effect of a chiral fermion, so that we term the anomalous shift "chiral magnetic effect of a light." We further study the chiral magnetic effect of a light beyond geometric optics by directly solving the transmission problem of a wave packet at a surface of a magnetoelectric material. We show that the experimental signal of the chiral magnetic effect of a light is the nonvanishing of transverse displacements for the beam normally incident to a magnetoelectric material.
International Nuclear Information System (INIS)
Cuypers, F.
1989-01-01
The authors studies the phenomenological implications of the Chiral Colour model which allow him to derive experimental bounds on the axigluon mass or to predict deviations from the Standard Model. After a short introduction to the theory, the author examines the way it modifies the standard decay of quarkonium. Comparison with the observed lifetime of the upsilon allows him to exclude the existence of axigluons lighter than 9 GeV. (Others have since extended the work and were able to increase this limit to 25 GeV.) He then studies the Chiral Colour contribution to the hadronic cross-section in the electron-positron scattering and derive a conservative lower bound of 50 GeV for the axigluon mass. Finally, he predicts observable enhancements of the lifetime and rare decay channels of the Z O in the presence of light axigluons
Emergent chirality in the electric polarization texture of titanate superlattices.
Shafer, Padraic; García-Fernández, Pablo; Aguado-Puente, Pablo; Damodaran, Anoop R; Yadav, Ajay K; Nelson, Christopher T; Hsu, Shang-Lin; Wojdeł, Jacek C; Íñiguez, Jorge; Martin, Lane W; Arenholz, Elke; Junquera, Javier; Ramesh, Ramamoorthy
2018-01-30
Chirality is a geometrical property by which an object is not superimposable onto its mirror image, thereby imparting a handedness. Chirality determines many important properties in nature-from the strength of the weak interactions according to the electroweak theory in particle physics to the binding of enzymes with naturally occurring amino acids or sugars, reactions that are fundamental for life. In condensed matter physics, the prediction of topologically protected magnetic skyrmions and related spin textures in chiral magnets has stimulated significant research. If the magnetic dipoles were replaced by their electrical counterparts, then electrically controllable chiral devices could be designed. Complex oxide BaTiO 3 /SrTiO 3 nanocomposites and PbTiO 3 /SrTiO 3 superlattices are perfect candidates, since "polar vortices," in which a continuous rotation of ferroelectric polarization spontaneously forms, have been recently discovered. Using resonant soft X-ray diffraction, we report the observation of a strong circular dichroism from the interaction between circularly polarized light and the chiral electric polarization texture that emerges in PbTiO 3 /SrTiO 3 superlattices. This hallmark of chirality is explained by a helical rotation of electric polarization that second-principles simulations predict to reside within complex 3D polarization textures comprising ordered topological line defects. The handedness of the texture can be topologically characterized by the sign of the helicity number of the chiral line defects. This coupling between the optical and novel polar properties could be exploited to encode chiral signatures into photon or electron beams for information processing.
Chiral Biomarkers in Meteorites
Hoover, Richard B.
2010-01-01
The chirality of organic molecules with the asymmetric location of group radicals was discovered in 1848 by Louis Pasteur during his investigations of the rotation of the plane of polarization of light by crystals of sodium ammonium paratartrate. It is well established that the amino acids in proteins are exclusively Levorotary (L-aminos) and the sugars in DNA and RNA are Dextrorotary (D-sugars). This phenomenon of homochirality of biological polymers is a fundamental property of all life known on Earth. Furthermore, abiotic production mechanisms typically yield recemic mixtures (i.e. equal amounts of the two enantiomers). When amino acids were first detected in carbonaceous meteorites, it was concluded that they were racemates. This conclusion was taken as evidence that they were extraterrestrial and produced by abiologically. Subsequent studies by numerous researchers have revealed that many of the amino acids in carbonaceous meteorites exhibit a significant L-excess. The observed chirality is much greater than that produced by any currently known abiotic processes (e.g. Linearly polarized light from neutron stars; Circularly polarized ultraviolet light from faint stars; optically active quartz powders; inclusion polymerization in clay minerals; Vester-Ulbricht hypothesis of parity violations, etc.). This paper compares the measured chirality detected in the amino acids of carbonaceous meteorites with the effect of these diverse abiotic processes. IT is concluded that the levels observed are inconsistent with post-arrival biological contamination or with any of the currently known abiotic production mechanisms. However, they are consistent with ancient biological processes on the meteorite parent body. This paper will consider these chiral biomarkers in view of the detection of possible microfossils found in the Orgueil and Murchison carbonaceous meteorites. Energy dispersive x-ray spectroscopy (EDS) data obtained on these morphological biomarkers will be
International Nuclear Information System (INIS)
Bastianelli, F.
1991-01-01
We examine the bosonization of chiral fermions in a gravitational background, using a path integral approach. The bosonic model is given by an action proposed some time ago by Floreanini and Jackiw, suitably coupled to gravity. We use a regulator for the path integral measure obtained from the general construction of Diaz, Hatsuda, Troost, van Nieuwenhuizen and Van Proeyen. We show that the effective actions are identical. (orig.)
Tailoring the chirality of light emission with spherical Si-based antennas.
Zambrana-Puyalto, Xavier; Bonod, Nicolas
2016-05-21
Chirality of light is of fundamental importance in several enabling technologies with growing applications in life sciences, chemistry and photodetection. Recently, some attention has been focused on chiral quantum emitters. Consequently, optical antennas which are able to tailor the chirality of light emission are needed. Spherical nanoresonators such as colloids are of particular interest to design optical antennas since they can be synthesized at a large scale and they exhibit good optical properties. Here, we show that these colloids can be used to tailor the chirality of a chiral emitter. To this purpose, we derive an analytic formalism to model the interaction between a chiral emitter and a spherical resonator. We then compare the performances of metallic and dielectric spherical antennas to tailor the chirality of light emission. It is seen that, due to their strong electric dipolar response, metallic spherical nanoparticles spoil the chirality of light emission by yielding achiral fields. In contrast, thanks to the combined excitation of electric and magnetic modes, dielectric Si-based particles feature the ability to inhibit or to boost the chirality of light emission. Finally, it is shown that dual modes in dielectric antennas preserve the chirality of light emission.
Identifying chiral bands in real nuclei
International Nuclear Information System (INIS)
Shirinda, O.; Lawrie, E.A.
2012-01-01
The application of the presently used fingerprints of chiral bands (originally derived for strongly broken chirality) is investigated for real chiral systems. In particular the chiral fingerprints concerning the B(M1) staggering patterns and the energy staggering are studied. It is found that both fingerprints show considerable changes for real chiral systems, a behaviour that creates a significant risk for misinterpretation of the experimental data and can lead to a failure to identify real chiral systems. (orig.)
Wang, Chen; Sun, Zuo-Bang; Xu, Qing-Wen; Zhao, Cui-Hua
2016-11-14
It is a challenging issue to achieve propeller chirality for triarylboranes owing to the low transition barrier between the P and M forms of the boron center. Herein, we report a new strategy to achieve propeller chirality of triarylboranes. It was found that the chirality relay from axially chiral 1,1'-binaphthyl to propeller chirality of the trivalent boron center can be realized when a Me 2 N and a Mes 2 B group (Mes=mesityl) are introduced at the 2,2'-positions of the 1,1'-binaphthyl skeleton (BN-BNaph) owing to the strong π-π interaction between the Me 2 N-bonded naphthyl ring and the phenyl ring of one adjacent Mes group, which not only exerts great steric hindrance on the rotation of the two Mes groups but also gives unequal stability to the two configurations of the boron center for a given configuration of the binaphthyl moiety. The stereostructures of the boron center were fully characterized through 1 H NMR spectroscopy, X-ray crystal analyses, and theoretical calculations. Detailed comparisons with the analog BN-Ph-BNaph, in which the Mes 2 B group is separated from 1,1'-binaphthyl by a para-phenylene spacer, confirmed the essential role of π-π interaction for the successful chirality relay in BN-BNaph. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Baryon mass splittings in chiral perturbation theory
International Nuclear Information System (INIS)
Banerjee, M.K.; Milana, J.
1995-01-01
Baryon masses are calculated in chiral perturbation theory at the one-loop O(p 3 ) level in chiral expansion and to leading order in the heavy baryon expansion. Ultraviolet divergences occur requiring the introduction of counterterms. Despite this necessity, no knowledge of the counterterms is required to determine the violations of the Gell-Mann--Okubo mass relation for the baryon octet or of the decuplet equal-mass-spacing rule, as all divergences cancel exactly at this order. For the same reason all references to an arbitrary scale μ are absent. Neither of these features continue to higher powers in the chiral expansion. We also discuss critically the absolute necessity of simultaneously going beyond the leading-order heavy baryon expansion, if one goes beyond the one-loop O(p 3 ) level. We point out that these corrections in 1/M B generate new divergences ∝m 4 /M 10 . These divergences together with the divergences occurring in one-loop O(p 4 ) graphs of chiral perturbation theory are taken care of by the same set of counterterms. Because of these unknown counterterms one cannot predict the baryon mass splittings at the one-loop O(p 4 ) level even if the parameters of all scrL 1 πN terms are known. We point out another serious problem of going to the one-loop O(p 4 ) level. When the decuplet is off its mass shell there are additional πNΔ and πΔΔ interaction terms. These interactions contribute to the divergent terms ∝(m 4 /M 10 ), and also to nonanalytic terms such as ∝(m 4 /M 10 )ln(m/M 10 ). Without knowledge of the coupling constants appearing in these interactions, one cannot carry out a consistent one-loop O(p 4 ) level calculation
Beem, Christopher; Rastelli, Leonardo; van Rees, Balt C.
2015-01-01
Four-dimensional N=2 superconformal field theories have families of protected correlation functions that possess the structure of two-dimensional chiral algebras. In this paper, we explore the chiral algebras that arise in this manner in the context of theories of class S. The class S duality web implies nontrivial associativity properties for the corresponding chiral algebras, the structure of which is best summarized in the language of generalized topological quantum field theory. We make a number of conjectures regarding the chiral algebras associated to various strongly coupled fixed points.
Algebraic diagrammatic construction formalism with three-body interactions
Raimondi, Francesco; Barbieri, Carlo
2018-05-01
Background: Self-consistent Green's function theory has recently been extended to the basic formalism needed to account for three-body interactions [Carbone, Cipollone, Barbieri, Rios, and Polls, Phys. Rev. C 88, 054326 (2013), 10.1103/PhysRevC.88.054326]. The contribution of three-nucleon forces has so far been included in ab initio calculations on nuclear matter and finite nuclei only as averaged two-nucleon forces. Purpose: We derive the working equations for all possible two- and three-nucleon terms that enter the expansion of the self-energy up to the third order, thus including the interaction-irreducible (i.e., not averaged) diagrams with three-nucleon forces that have been previously neglected. Methods: We employ the algebraic diagrammatic construction up to the third order as an organization scheme for generating a nonperturbative self-energy, in which ring (particle-hole) and ladder (particle-particle) diagrams are resummed to all orders. Results: We derive expressions of the static and dynamic self-energy up to the third order, by taking into account the set of diagrams required when either the skeleton or nonskeleton expansions of the single-particle propagator are assumed. A hierarchy of importance among different diagrams is revealed, and a particular emphasis is given to a third-order diagram [see Fig. 2(c)] that is expected to play a significant role among those featuring an interaction-irreducible three-nucleon force. Conclusion: A consistent formalism to resum at infinite order correlations induced by three-nucleon forces in the self-consistent Green's function theory is now available and ready to be implemented in the many-body solvers.
Chiral symmetry restoration and quasi-elastic electron-nucleus scattering
International Nuclear Information System (INIS)
Henley, E.M.; Krein, G.
1989-01-01
Chiral symmetry is known to be an important concept in hadronic interactions. It holds in QCD, but is known to be broken at low energies. It is therefore useful to study chiral symmetry and its breaking together with its consequences in nuclear physics. It is the latter phenomena we consider here. It is difficult to study nonperturbative QCD at low energies and models are needed. The Nambu-Jona-Lasinio (NJL) model fits this category; it incorporates chiral symmetry and its breaking, and allows one to study its effects in nucleons and nuclei. In particular, the constituent quark mass varies with density (ρ) and temperature (T). At high ρ and T chiral symmetry is restored. It is the ρ dependence which yields important effects in electron scattering due to partial restoration of chiral symmetry in nuclei. We begin with the NJL model with a small chiral symmetry breaking
Wang, Fang; Feng, Chuan-Liang
2018-02-01
To control supramolecular chirality of the co-assembled nanostructures, one of the remaining issues is how stoichiometry of the different molecules involved in co-assembly influence chiral transformation. Through co-assembly of achiral 1,4-bis(pyrid-4-yl)benzene and chiral phenylalanine-glycine derivative hydrogelators, stoichiometry is found to be an effective tool for controlling supramolecular chirality inversion processes. This inversion is mainly mediated by a delicate balance between intermolecular hydrogen bonding interactions and π-π stacking of the two components, which may subtly change the stacking of the molecules, in turn, the self-assembled nanostructures. This study exemplifies a simplistic way to invert the handedness of chiral nanostructures and provide fundamental understanding of the inherent principles of supramolecular chirality. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Simplified chiral superfield propagators for chiral constant mass superfields
International Nuclear Information System (INIS)
Srivastava, P.P.
1983-01-01
Unconstrained superfield potentials are introduced to derive Feynman rules for chiral superfields following conventional procedure which is easy and instructive. Propagators for the case when the mass parameters are constant chiral superfields are derived. The propagators reported here are very simple compared to those available in literature and allow a manageable calculation of higher loops. (Author) [pt
A primer for Chiral Perturbative Theory
International Nuclear Information System (INIS)
Scherer, Stefan; Schindler, Matthias R.; George Washington Univ., Washington, DC
2012-01-01
Chiral Perturbation Theory, as effective field theory, is a commonly accepted and well established working tool, approximating quantum chromodynamics at energies well below typical hadron masses. This volume, based on a number of lectures and supplemented with additional material, provides a pedagogical introduction for graduate students and newcomers entering the field from related areas of nuclear and particle physics. Starting with the the Lagrangian of the strong interactions and general symmetry principles, the basic concepts of Chiral Perturbation Theory in the mesonic and baryonic sectors are developed. The application of these concepts is then illustrated with a number of examples. A large number of exercises (81, with complete solutions) are included to familiarize the reader with helpful calculational techniques. (orig.)
Chiral charge flux and electroweak baryogenesis
Energy Technology Data Exchange (ETDEWEB)
Funakubo, Koichi [Saga Univ. (Japan). Dept. of Physics; Kakuto, Akira; Otsuki, Shoichiro; Takenaga, Kazunori; Toyoda, Fumihiko
1995-06-01
By treating CP-violating interaction of the electroweak bubble wall as a perturbative term, chiral charge flux through the bubble wall is estimated. It is found that the absolute value of the flux F{sub Q} has a sharp peak at m{sub 0} - a - T with F{sub Q}/(uT{sup 3}) - 10{sup -3}(Q{sub L}-Q{sub R}){Delta}{theta}. Here m{sub 0} is the fermion mass, 1/a is the wall thickness, T is the temperature at which the bubbles are growing, u is the wall velocity, Q{sub L(R)} is the chiral charge of the relevant left (right)-handed fermion and {Delta}{theta} is the measure of CP violation. (author).
A primer for chiral perturbation theory
Scherer, Stefan
2012-01-01
Chiral Perturbation Theory, as effective field theory, is a commonly accepted and well established working tool, approximating quantum chromodynamics at energies well below typical hadron masses. This volume, based on a number of lectures and supplemented with additional material, provides a pedagogical introduction for graduate students and newcomers entering the field from related areas of nuclear and particle physics. Starting with the the Lagrangian of the strong interactions and general symmetry principles, the basic concepts of Chiral Perturbation Theory in the mesonic and baryonic sectors are developed. The application of these concepts is then illustrated with a number of examples. A large number of exercises (81, with complete solutions) are included to familiarize the reader with helpful calculational techniques.
Filippi, Antonello; Giardini, Anna; Marcantoni, Enrico; Paladini, Alessandra; Piccirillo, Susanna; Renzi, Gabriele; Rondino, Flaminia; Roselli, Graziella; Satta, Mauro; Speranza, Maurizio
2007-04-14
The R2PI-TOF spectra of supersonically expanded rare gas/chiral arene heteroclusters have been rationalized in terms of the distortion of the pi-electron density reflecting the different dipole and quadrupole momenta induced in the rare gas atoms by interaction with the opposite pi-faces of the chiral arene itself.
Chiral Cliffs: Investigating the Influence of Chirality on Binding Affinity.
Schneider, Nadine; Lewis, Richard A; Fechner, Nikolas; Ertl, Peter
2018-05-11
Chirality is understood by many as a binary concept: a molecule is either chiral or it is not. In terms of the action of a structure on polarized light, this is indeed true. When examined through the prism of molecular recognition, the answer becomes more nuanced. In this work, we investigated chiral behavior on protein-ligand binding: when does chirality make a difference in binding activity? Chirality is a property of the 3D structure, so recognition also requires an appreciation of the conformation. In many situations, the bioactive conformation is undefined. We set out to address this by defining and using several novel 2D descriptors to capture general characteristic features of the chiral center. Using machine-learning methods, we built different predictive models to estimate if a chiral pair (a set of two enantiomers) might exhibit a chiral cliff in a binding assay. A set of about 3800 chiral pairs extracted from the ChEMBL23 database was used to train and test our models. By achieving an accuracy of up to 75 %, our models provide good performance in discriminating chiral cliffs from non-cliffs. More importantly, we were able to derive some simple guidelines for when one can reasonably use a racemate and when an enantiopure compound is needed in an assay. We critically discuss our results and show detailed examples of using our guidelines. Along with this publication we provide our dataset, our novel descriptors, and the Python code to rebuild the predictive models. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Lattice regularized chiral perturbation theory
International Nuclear Information System (INIS)
Borasoy, Bugra; Lewis, Randy; Ouimet, Pierre-Philippe A.
2004-01-01
Chiral perturbation theory can be defined and regularized on a spacetime lattice. A few motivations are discussed here, and an explicit lattice Lagrangian is reviewed. A particular aspect of the connection between lattice chiral perturbation theory and lattice QCD is explored through a study of the Wess-Zumino-Witten term
Decay of bubble of disoriented chiral condensate
International Nuclear Information System (INIS)
Gani, V.A.; Kudryavtsev, A.E.; Belova, T.I.
1999-01-01
The space-time structure for the process of decay of a bubble of hypothetical phase -disoriented chiral condensate (DCC) i discussed. The evolution of the initial classical field configuration corresponding to the bubble of DCC is studied, both numerically and analytically. The decay of this initial configuration depends crucially on self-interaction of the pionic fields. It is shown that in some cases this self-interaction leads to the formation of sort of breather solution, formed from pionic fields situated in the center of the initial bubble of DCC. This breather looks like a long-lived source of pionic fields [ru
Two-chiral component microemulsion EKC - chiral surfactant and chiral oil. Part 2: diethyl tartrate.
Kahle, Kimberly A; Foley, Joe P
2007-08-01
In this second study on dual-chirality microemulsions containing a chiral surfactant and a chiral oil, a less hydrophobic and lower interfacial tension chiral oil, diethyl tartrate, is employed (Part 1, Foley, J. P. et al.., Electrophoresis, DOI: 10.1002/elps.200600551). Six stereochemical combinations of dodecoxycarbonylvaline (DDCV: R, S, or racemic, 2.00% w/v), racemic 2-hexanol (1.65% v/v), and diethyl tartrate (D, L, or racemic, 0.88% v/v) were examined as pseudostationary phases (PSPs) for the enantioseparation of six chiral pharmaceutical compounds: pseudoephedrine, ephedrine, N-methyl ephedrine, metoprolol, synephrine, and atenolol. Average efficiencies increased with the addition of a chiral oil to R-DDCV PSP formulations. Modest improvements in resolution and enantioselectivity (alpha(enant)) were achieved with two-chiral-component systems over the one-chiral-component microemulsion. Slight enantioselective synergies were confirmed using a thermodynamic model. Results obtained in this study are compared to those obtained in Part 1 as well as those obtained with chiral MEEKC using an achiral, low-interfacial-tension oil (ethyl acetate). Dual-chirality microemulsions with the more hydrophobic oil dibutyl tartrate yielded, relative to diethyl tartrate, higher efficiencies (100,000-134,000 vs. 80,800-94,300), but lower resolution (1.64-1.91 vs. 2.08-2.21) due to lower enantioselectivities (1.060-1.067 vs. 1.078-1.081). Atenolol enantiomers could not be separated with the dibutyl tartrate-based microemulsions but were partially resolved using diethyl tartrate microemulsions. A comparable single-chirality microemulsion based on the achiral oil ethyl acetate yielded, relative to diethyl tartrate, lower efficiency (78 300 vs. 91 600), higher resolution (1.99 vs. 1.83), and similar enantioselectivities.
Supramolecular Chirality: Solvent Chirality Transfer in Molecular Chemistry and Polymer Chemistry
Directory of Open Access Journals (Sweden)
Michiya Fujiki
2014-08-01
Full Text Available Controlled mirror symmetry breaking arising from chemical and physical origin is currently one of the hottest issues in the field of supramolecular chirality. The dynamic twisting abilities of solvent molecules are often ignored and unknown, although the targeted molecules and polymers in a fluid solution are surrounded by solvent molecules. We should pay more attention to the facts that mostly all of the chemical and physical properties of these molecules and polymers in the ground and photoexcited states are significantly influenced by the surrounding solvent molecules with much conformational freedom through non-covalent supramolecular interactions between these substances and solvent molecules. This review highlights a series of studies that include: (i historical background, covering chiral NaClO3 crystallization in the presence of d-sugars in the late 19th century; (ii early solvent chirality effects for optically inactive chromophores/fluorophores in the 1960s–1980s; and (iii the recent development of mirror symmetry breaking from the corresponding achiral or optically inactive molecules and polymers with the help of molecular chirality as the solvent use quantity.
Dirac operator, chirality and random matrix theory
International Nuclear Information System (INIS)
Pullirsch, R.
2001-05-01
Quantum Chromodynamics (QCD) is considered to be the correct theory which describes quarks and gluons and, thus, all strong interaction phenomena from the fundamental forces of nature. However, important properties of QCD such as the physical mechanism of color confinement and the spontaneous breaking of chiral symmetry are still not completely understood and under extensive discussion. Analytical calculations are limited, because in the low-energy regime where quarks are confined, application of perturbation theory is restricted due to the large gluon coupling. A powerful tool to investigate numerically and analytically the non-perturbative region is provided by the lattice formulation of QCD. From Monte Carlo simulations of lattice QCD we know that chiral symmetry is restored above a critical temperature. As the chiral condensate is connected to the spectral density of the Dirac operator via the Banks-Casher relation, the QCD Dirac spectrum is an interesting object for detailed studies. In search for an analytical expression of the infrared limit of the Dirac spectrum it has been realized that chiral random-matrix theory (chRMT) is a suitable tool to compare with the distribution and the correlations of the small Dirac eigenvalues. Further, it has been shown that the correlations of eigenvalues on the scale of mean level spacings are universal for complex physical systems and are given by random-matrix theory (Rm). This has been formulated as the Baghouse-Giannoni-Schmit conjecture which states that spectral correlations of a classically chaotic system are given by RMT on the quantum level. The aim of this work is to analyze the relationship between chiral phase transitions and chaos to order transitions in quantum field theories. We study the eigenvalues of the Dirac operator for Quantum Electrodynamics (QED) with compact gauge group U(1) on the lattice. This theory shows chiral symmetry breaking and confinement in the strong coupling region. Although being
Choi, Heekyoung; Cho, Kang Jin; Seo, Hyowon; Ahn, Junho; Liu, Jinying; Lee, Shim Sung; Kim, Hyungjun; Feng, Chuanliang; Jung, Jong Hwa
2017-12-13
Transfer and inversion of supramolecular chirality from chiral calix[4]arene analogs (3D and 3L) with an alanine moiety to an achiral bipyridine derivative (1) with glycine moieties in a coassembled hydrogel are demonstrated. Molecular chirality of 3D and 3L could transfer supramolecular chirality to an achiral bipyridine derivative 1. Moreover, addition of 0.6 equiv of 3D or 3L to 1 induced supramolecular chirality inversion of 1. More interestingly, the 2D-sheet structure of the coassembled hydrogels formed with 0.2 equiv of 3D or 3L changed to a rolled-up tubular structure in the presence of 0.6 equiv of 3D or 3L. The chirality inversion and morphology change are mainly mediated by intermolecular hydrogen-bonding interactions between the achiral and chiral molecules, which might be induced by reorientations of the assembled molecules, confirmed by density functional theory calculations.
Bagchi, Arjun; Basu, Rudranil; Detournary, Stéphane; Parekh, Pulastya
2018-05-01
We propose a holographic duality between a 2 dimensional (2d) chiral superconformal field theory and a certain theory of supergravity in 3d with flatspace boundary conditions that is obtained as a double scaling limit of a parity breaking theory of supergravity. We show how the asymptotic symmetries of the bulk theory reduce from the "despotic" super Bondi-Metzner-Sachs algebra (or equivalently the inhomogeneous super Galilean conformal algebra) to a single copy of the super-Virasoro algebra in this limit and also reproduce the same reduction from a study of null vectors in the putative 2d dual field theory.
Chiral magnetism of magnetic adatoms generated by Rashba electrons
Bouaziz, Juba; dos Santos Dias, Manuel; Ziane, Abdelhamid; Benakki, Mouloud; Blügel, Stefan; Lounis, Samir
2017-02-01
We investigate long-range chiral magnetic interactions among adatoms mediated by surface states spin-splitted by spin-orbit coupling. Using the Rashba model, the tensor of exchange interactions is extracted wherein a thepseudo-dipolar interaction is found, in addition to the usual isotropic exchange interaction and the Dzyaloshinskii-Moriya interaction. We find that, despite the latter interaction, collinear magnetic states can still be stabilized by the pseudo-dipolar interaction. The interadatom distance controls the strength of these terms, which we exploit to design chiral magnetism in Fe nanostructures deposited on a Au(111) surface. We demonstrate that these magnetic interactions are related to superpositions of the out-of-plane and in-plane components of the skyrmionic magnetic waves induced by the adatoms in the surrounding electron gas. We show that, even if the interatomic distance is large, the size and shape of the nanostructures dramatically impacts on the strength of the magnetic interactions, thereby affecting the magnetic ground state. We also derive an appealing connection between the isotropic exchange interaction and the Dzyaloshinskii-Moriya interaction, which relates the latter to the first-order change of the former with respect to spin-orbit coupling. This implies that the chirality defined by the direction of the Dzyaloshinskii-Moriya vector is driven by the variation of the isotropic exchange interaction due to the spin-orbit interaction.
Neuronal growth on L- and D-cysteine self-assembled monolayers reveals neuronal chiral sensitivity.
Baranes, Koby; Moshe, Hagay; Alon, Noa; Schwartz, Shmulik; Shefi, Orit
2014-05-21
Studying the interaction between neuronal cells and chiral molecules is fundamental for the design of novel biomaterials and drugs. Chirality influences all biological processes that involve intermolecular interaction. One common method used to study cellular interactions with different enantiomeric targets is the use of chiral surfaces. Based on previous studies that demonstrated the importance of cysteine in the nervous system, we studied the effect of L- and D-cysteine on single neuronal growth. L-Cysteine, which normally functions as a neuromodulator or a neuroprotective antioxidant, causes damage at elevated levels, which may occur post trauma. In this study, we grew adult neurons in culture enriched with L- and D-cysteine as free compounds or as self-assembled monolayers of chiral surfaces and examined the effect on the neuronal morphology and adhesion. Notably, we have found that exposure to the L-cysteine enantiomer inhibited, and even prevented, neuronal attachment more severely than exposure to the D-cysteine enantiomer. Atop the L-cysteine surfaces, neuronal growth was reduced and degenerated. Since the cysteine molecules were attached to the surface via the thiol groups, the neuronal membrane was exposed to the molecular chiral site. Thus, our results have demonstrated high neuronal chiral sensitivity, revealing chiral surfaces as indirect regulators of neuronal cells and providing a reference for studying chiral drugs.
Amino-acid- and peptide-directed synthesis of chiral plasmonic gold nanoparticles.
Lee, Hye-Eun; Ahn, Hyo-Yong; Mun, Jungho; Lee, Yoon Young; Kim, Minkyung; Cho, Nam Heon; Chang, Kiseok; Kim, Wook Sung; Rho, Junsuk; Nam, Ki Tae
2018-04-01
Understanding chirality, or handedness, in molecules is important because of the enantioselectivity that is observed in many biochemical reactions 1 , and because of the recent development of chiral metamaterials with exceptional light-manipulating capabilities, such as polarization control 2-4 , a negative refractive index 5 and chiral sensing 6 . Chiral nanostructures have been produced using nanofabrication techniques such as lithography 7 and molecular self-assembly 8-11 , but large-scale and simple fabrication methods for three-dimensional chiral structures remain a challenge. In this regard, chirality transfer represents a simpler and more efficient method for controlling chiral morphology 12-18 . Although a few studies 18,19 have described the transfer of molecular chirality into micrometre-sized helical ceramic crystals, this technique has yet to be implemented for metal nanoparticles with sizes of hundreds of nanometres. Here we develop a strategy for synthesizing chiral gold nanoparticles that involves using amino acids and peptides to control the optical activity, handedness and chiral plasmonic resonance of the nanoparticles. The key requirement for achieving such chiral structures is the formation of high-Miller-index surfaces ({hkl}, h ≠ k ≠ l ≠ 0) that are intrinsically chiral, owing to the presence of 'kink' sites 20-22 in the nanoparticles during growth. The presence of chiral components at the inorganic surface of the nanoparticles and in the amino acids and peptides results in enantioselective interactions at the interface between these elements; these interactions lead to asymmetric evolution of the nanoparticles and the formation of helicoid morphologies that consist of highly twisted chiral elements. The gold nanoparticles that we grow display strong chiral plasmonic optical activity (a dis-symmetry factor of 0.2), even when dispersed randomly in solution; this observation is supported by theoretical calculations and direct
Chiral analysis of baryon form factors
Energy Technology Data Exchange (ETDEWEB)
Gail, T.A.
2007-11-08
This work presents an extensive theoretical investigation of the structure of the nucleon within the standard model of elementary particle physics. In particular, the long range contributions to a number of various form factors parametrizing the interactions of the nucleon with an electromagnetic probe are calculated. The theoretical framework for those calculations is chiral perturbation theory, the exact low energy limit of Quantum Chromo Dynamics, which describes such long range contributions in terms of a pion-cloud. In this theory, a nonrelativistic leading one loop order calculation of the form factors parametrizing the vector transition of a nucleon to its lowest lying resonance, the {delta}, a covariant calculation of the isovector and isoscalar vector form factors of the nucleon at next to leading one loop order and a covariant calculation of the isoscalar and isovector generalized vector form factors of the nucleon at leading one loop order are performed. In order to perform consistent loop calculations in the covariant formulation of chiral perturbation theory an appropriate renormalization scheme is defined in this work. All theoretical predictions are compared to phenomenology and results from lattice QCD simulations. These comparisons allow for a determination of the low energy constants of the theory. Furthermore, the possibility of chiral extrapolation, i.e. the extrapolation of lattice data from simulations at large pion masses down to the small physical pion mass is studied in detail. Statistical as well as systematic uncertainties are estimated for all results throughout this work. (orig.)
Nanoscale chirality in metal and semiconductor nanoparticles.
Kumar, Jatish; Thomas, K George; Liz-Marzán, Luis M
2016-10-18
The field of chirality has recently seen a rejuvenation due to the observation of chirality in inorganic nanomaterials. The advancements in understanding the origin of nanoscale chirality and the potential applications of chiroptical nanomaterials in the areas of optics, catalysis and biosensing, among others, have opened up new avenues toward new concepts and design of novel materials. In this article, we review the concept of nanoscale chirality in metal nanoclusters and semiconductor quantum dots, then focus on recent experimental and theoretical advances in chiral metal nanoparticles and plasmonic chirality. Selected examples of potential applications and an outlook on the research on chiral nanomaterials are additionally provided.
International Nuclear Information System (INIS)
Harada, Masayasu
2009-01-01
Chiral perturbation theory has been used for great number of phenomenological analyses in low energy QCD as well as the lattice QCD analyses since the creation of the theory by Weinberg in 1979 followed by its consolidation by Gasser and Leutwyler in 1984 and 85. The theory is now the highly established one as the approach based on the effective field theory to search for Green function including quantum correlations in the frame of the systematic expansion technique using Lagrangian which includes all of the terms allowed by the symmetry. This review has been intended to describe how systematically physical quantities are calculated in the framework of the chiral symmetry. Consequently many of the various phenomenological analyses are not taken up here for which other reports are to be referred. Further views are foreseen to be developed based on the theory in addition to numbers of results reported up to the present. Finally π-π scattering is taken up to discuss to what energy scale the theory is available. (S. Funahashi)
Distinguishing standard model extensions using monotop chirality at the LHC
Energy Technology Data Exchange (ETDEWEB)
Allahverdi, Rouzbeh [Department of Physics and Astronomy, University of New Mexico,Albuquerque, NM 87131 (United States); Dalchenko, Mykhailo; Dutta, Bhaskar [Department of Physics and Astronomy,Mitchell Institute for Fundamental Physics and Astronomy, Texas A& M University,College Station, TX 77843-4242 (United States); Flórez, Andrés [Departamento de Física, Universidad de los Andes,Bogotá, Carrera 1 18A-10, Bloque IP (Colombia); Gao, Yu [Department of Physics and Astronomy,Mitchell Institute for Fundamental Physics and Astronomy, Texas A& M University,College Station, TX 77843-4242 (United States); Kamon, Teruki [Department of Physics and Astronomy,Mitchell Institute for Fundamental Physics and Astronomy, Texas A& M University,College Station, TX 77843-4242 (United States); Department of Physics, Kyungpook National University,Daegu 702-701 (Korea, Republic of); Kolev, Nikolay [Department of Physics, University of Regina,SK, S4S 0A2 (Canada); Mueller, Ryan [Department of Physics and Astronomy,Mitchell Institute for Fundamental Physics and Astronomy, Texas A& M University,College Station, TX 77843-4242 (United States); Segura, Manuel [Departamento de Física, Universidad de los Andes,Bogotá, Carrera 1 18A-10, Bloque IP (Colombia)
2016-12-13
We present two minimal extensions of the standard model, each giving rise to baryogenesis. They include heavy color-triplet scalars interacting with a light Majorana fermion that can be the dark matter (DM) candidate. The electroweak charges of the new scalars govern their couplings to quarks of different chirality, which leads to different collider signals. These models predict monotop events at the LHC and the energy spectrum of decay products of highly polarized top quarks can be used to establish the chiral nature of the interactions involving the heavy scalars and the DM. Detailed simulation of signal and standard model background events is performed, showing that top quark chirality can be distinguished in hadronic and leptonic decays of the top quarks.
Stardust, Supernovae and the Chirality of the Amino Acids
International Nuclear Information System (INIS)
Boyd, R.N.; Kajino, T.; Onaka, T.
2011-01-01
A mechanism for creating enantiomerism in the amino acids, the building blocks of the proteins, that involves global selection of one chirality by interactions between the amino acids and neutrinos from core-collapse supernovae is described. The selection involves the dependence of the interaction cross sections on the orientations of the spins of the neutrinos and the 14N nuclei in the amino acids, or in precursor molecules, which in turn couple to the molecular chirality. The subsequent chemical evolution and galactic mixing would ultimately populate the Galaxy with the selected species. The resulting amino acids could either be the source thereof on Earth, or could have triggered the chirality that was ultimately achieved for Earth's amino acids.
Supernovae, Neutrinos and the Chirality of Amino Acids
Directory of Open Access Journals (Sweden)
Toshitaka Kajino
2011-05-01
Full Text Available A mechanism for creating an enantioenrichment in the amino acids, the building blocks of the proteins, that involves global selection of one handedness by interactions between the amino acids and neutrinos from core-collapse supernovae is defined. The chiral selection involves the dependence of the interaction cross sections on the orientations of the spins of the neutrinos and the 14N nuclei in the amino acids, or in precursor molecules, which in turn couple to the molecular chirality. It also requires an asymmetric distribution of neutrinos emitted from the supernova. The subsequent chemical evolution and galactic mixing would ultimately populate the Galaxy with the selected species. The resulting amino acids could either be the source thereof on Earth, or could have triggered the chirality that was ultimately achieved for Earth’s proteinaceous amino acids.
Optical Chirality in Nonlinear Optics: Application to High Harmonic Generation.
Neufeld, Ofer; Cohen, Oren
2018-03-30
Optical chirality (OC)-one of the fundamental quantities of electromagnetic fields-corresponds to the instantaneous chirality of light. It has been utilized for exploring chiral light-matter interactions in linear optics, but has not yet been applied to nonlinear processes. Motivated to explore the role of OC in the generation of helically polarized high-order harmonics and attosecond pulses, we first separate the OC of transversal and paraxial beams to polarization and orbital terms. We find that the polarization-associated OC of attosecond pulses corresponds approximately to that of the pump in the quasimonochromatic case, but not in the multichromatic pump cases. We associate this discrepancy with the fact that the polarization OC of multichromatic pumps vary rapidly in time along the optical cycle. Thus, we propose new quantities, noninstantaneous polarization-associated OC, and time-scale-weighted polarization-associated OC, and show that these quantities link the chirality of multichromatic pumps and their generated attosecond pulses. The presented extension to OC theory should be useful for exploring various nonlinear chiral light-matter interactions. For example, it stimulates us to propose a tricircular pump for generation of highly elliptical attosecond pulses with a tunable ellipticity.
Optical Chirality in Nonlinear Optics: Application to High Harmonic Generation
Neufeld, Ofer; Cohen, Oren
2018-03-01
Optical chirality (OC)—one of the fundamental quantities of electromagnetic fields—corresponds to the instantaneous chirality of light. It has been utilized for exploring chiral light-matter interactions in linear optics, but has not yet been applied to nonlinear processes. Motivated to explore the role of OC in the generation of helically polarized high-order harmonics and attosecond pulses, we first separate the OC of transversal and paraxial beams to polarization and orbital terms. We find that the polarization-associated OC of attosecond pulses corresponds approximately to that of the pump in the quasimonochromatic case, but not in the multichromatic pump cases. We associate this discrepancy with the fact that the polarization OC of multichromatic pumps vary rapidly in time along the optical cycle. Thus, we propose new quantities, noninstantaneous polarization-associated OC, and time-scale-weighted polarization-associated OC, and show that these quantities link the chirality of multichromatic pumps and their generated attosecond pulses. The presented extension to OC theory should be useful for exploring various nonlinear chiral light-matter interactions. For example, it stimulates us to propose a tricircular pump for generation of highly elliptical attosecond pulses with a tunable ellipticity.
New remarks on chiral bosonization
International Nuclear Information System (INIS)
Souza Dutra, A. de
1992-01-01
We discuss a certain duality between the constraints appearing in ordinary Lagrangian density and its first order counterpart for the gauged Siegel chiral boson. It is demonstrated the equivalence, at the classical level, of the two versions of the gauged Siegel chiral boson to its corresponding gauged Floreanini-Jackiw chiral bosons. It is also argued that the most general constrained Lagrangian density, that leads to a bosonic field obeying a first order differential equation of motion and preserve simultaneously Lorentz invariance, is just the Floreanini-Jackiw one. (author)
Vector mesons and chiral symmetry
International Nuclear Information System (INIS)
Ecker, G.
1989-01-01
The ambiguities in the off-shell behaviour of spin-1 exchange can be resolved to O(p 4 ) in the chiral low-energy expansion if the asymptotic behaviour of QCD is properly incorporated. As a consequence, the chiral version of vector (and axial-vector) meson dominance is model independent. Additional high-energy constraints motivated by QCD determine the V,A resonance couplings uniquely. In particular, QCD in its effective chiral realization sucessfully predicts Γ(ρ→2π). 10 refs. (Author)
Nonlinear spectroscopic studies of chiral media
International Nuclear Information System (INIS)
Belkin, Mikhail Alexandrovich
2004-01-01
Molecular chirality plays an important role in chemistry, biology, and medicine. Traditional optical techniques for probing chirality, such as circular dichroism and Raman optical activity rely on electric-dipole forbidden transitions. As a result, their intrinsic low sensitivity limits their use to probe bulk chirality rather than chiral surfaces, monolayers or thin films often important for chemical or biological systems. Contrary to the traditional chirality probes, chiral signal in sum-frequency generation (SFG) is electric-dipole allowed both on chiral surface and in chiral bulk making it a much more promising tool for probing molecular chirality. SFG from a chiral medium was first proposed in 1965, but had never been experimentally confirmed until this thesis work was performed. This thesis describes a set of experiments successfully demonstrating that chiral SFG responses from chiral monolayers and liquids are observable. It shows that, with tunable inputs, SFG can be used as a sensitive spectroscopic tool to probe chirality in both electronic and vibrational resonances of chiral molecules. The monolayer sensitivity is feasible in both cases. It also discusses the relevant theoretical models explaining the origin and the strength of the chiral signal in vibrational and electronic SFG spectroscopies
Energy Technology Data Exchange (ETDEWEB)
Price, C E; Shepard, J R [Colorado Univ., Boulder (USA). Dept. of Physics
1991-04-18
We compute properties of the nucleon in a hybrid chiral model based on the linear {sigma}-model with quark degrees of freedom treated explicity. In contrast to previous calculations, we do not use the hedgehog ansatz. Instead we solve self-consistently for a state with well defined spin and isospin projections. We allow this state to be deformed and find that, although d- and g-state admixtures in the predominantly s-state single quark wave functions are not large, they have profound effects on many nucleon properties including magnetic moments and g{sub A}. Our best fit parameters provide excellent agreement with experiment but are much different from those determined in hedgehog calculations. (orig.).
Cook, Jamie E.
2012-01-01
Amino acids are among the most heavily studied organic compound class in carbonaceous chondrites. The abundance, distributions, enantiomeric compositions, and stable isotopic ratios of amino acids have been determined in carbonaceous chondrites fi'om a range of classes and petrographic types, with interesting correlations observed between these properties and the class and typc of the chondritcs. In particular, isomeric distributions appear to correlate with parent bodies (chondrite class). In addition, certain chiral amino acids are found in enantiomeric excess in some chondrites. The delivery of these enantiomeric excesses to the early Earth may have contributed to the origin of the homochirality that is central to life on Earth today. This talk will explore the amino acids in carbonaceous chondritcs and their relevance to the origin of life.
Chirality, nongauge couplings and compositeness
International Nuclear Information System (INIS)
Suzuki, Mahiko
1985-01-01
We study from a phenomenological viewpoint what constraints exist on a possible scale of compositeness for W, Z, leptons, and quarks. A few critical arguments are presented about excited fermions and spinless partners of W and Z. It is argued that irrespective of a compositeness scale, the coupling of an excited fermion to a ground state light fermion is likely to be maximally parity violating. Besides chirality breaking interactions of light fermions, gauge noninvariant, dimensionless, unrenormalizable couplings are specially interesting in many classes of composite theories. The deviation of the W magnetic moment from the standard theory (g = 2) is such an example. We relate the ''g-2'' of W to a compositeness scale through an unitarity argument and make a guess on its effect on the muon g-2 for a given compositeness scale. The present experimental data on the W-Z mass ratio is already accurate enough to indicate that if a compositeness scale is larger than 0(1 TeV), gauge noninvariant couplings of W and Z should be negligibly small and a composite theory is hardly distinguishable from an elementary particle theory at the electroweak energy scale (≅ 250 GeV). However, a compositeness scale close to the electroweak scale can not be ruled out for W and Z at present. (author)
Chiral fermions on the lattice
International Nuclear Information System (INIS)
Randjbar Daemi, S.; Strathdee, J.
1995-01-01
The overlap approach to chiral gauge theories on arbitrary D-dimensional lattices is studied. The doubling problem and its relation to chiral anomalies for D = 2 and 4 is examined. In each case it is shown that the doublers can be eliminated and the well known perturbative results for chiral anomalies can be recovered. We also consider the multi-flavour case and give the general criteria for the construction of anomaly free chiral gauge theories on arbitrary lattices. We calculate the second order terms in a continuum approximation to the overlap formula in D dimensions and show that they coincide with the bilinear part of the effective action of D-dimensional Weyl fermions coupled to a background gauge field. Finally, using the same formalism we reproduce the correct Lorentz, diffeomorphism and gauge anomalies in the coupling of a Weyl fermion to 2-dimensional gravitation and Maxwell fields. (author). 15 refs
Switching of chirality by light
Feringa, B.L.; Schoevaars, A.M; Jager, W.F.; de Lange, B.; Huck, N.P.M.
1996-01-01
Optically active photoresponsive molecules are described by which control of chirality is achieved by light. These chiroptical molecular switches are based on inherently dissymmetric overcrowded alkenes and the synthesis, resolution and dynamic stereochemical properties are discussed. Introduction
Chiral dynamics with (nonstrange quarks
Directory of Open Access Journals (Sweden)
Kubis Bastian
2017-01-01
Full Text Available We review the results and achievements of the project B.3. Topics addressed include pion photoproduction off the proton and off deuterium, three-flavor chiral perturbation theory studies, chiral symmetry tests in Goldstone boson decays, the development of unitarized chiral perturbation theory to next-to-leading order, the two-pole structure of the Λ(1405, the dynamical generation of the lowest S11 resonances, the theory of hadronic atoms and its application to various systems, precision studies in light-meson decays based on dispersion theory, the Roy–Steiner analysis of pion–nucleon scattering, a high-precision extraction of the elusive pion–nucleon σ-term, and aspects of chiral dynamics in few-nucleon systems.
Review of chiral perturbation theory
Indian Academy of Sciences (India)
Abstract. A review of chiral perturbation theory and recent developments on the comparison of its predictions with experiment is presented. Some interesting topics with scope for further elaboration are touched upon.
Need for spontaneous breakdown of chiral symmetry
International Nuclear Information System (INIS)
Salomone, A.; Schechter, J.; Tudron, T.
1981-01-01
The question of whether the chiral symmetry of the theory of strong interactions (with massless quarks) is required to be spontaneously broken is examined in the framework of a previously discussed effective Lagrangian for quantum chromodynamics. The assumption that physical masses of the theory be finite leads in a very direct way to the necessity of spontaneous breakdown. This result holds for all N/sub F/> or =2, where N/sub F/ is the number of different flavors of light quarks. The atypical cases N/sub F/ = 1,2 are discussed separately
Chiral symmetry and nucleon structure: Low energy aspects
International Nuclear Information System (INIS)
Weise, W.
1989-01-01
The symmetries and currents of QCD at low energy and long wavelength are realized in the form of mesons, rather than quarks and gluons. In this talk I summarize the merits, but also the limits, of chiral non-linear meson theories and their soliton solutions, in descriptions of nucleon structure and the nucleon-nucleon interaction. (orig.)
Chirality-controlled crystallization via screw dislocations.
Sung, Baeckkyoung; de la Cotte, Alexis; Grelet, Eric
2018-04-11
Chirality plays an important role in science from enantiomeric separation in chemistry to chiral plasmonics in nanotechnology. However, the understanding of chirality amplification from chiral building blocks to ordered helical superstructures remains a challenge. Here, we demonstrate that topological defects, such as screw dislocations, can drive the chirality transfer from particle to supramolecular structure level during the crystallization process. By using a model system of chiral particles, which enables direct imaging of single particle incorporation into growing crystals, we show that the crystallization kinetic pathway is the key parameter for monitoring, via the defects, the chirality amplification of the crystalline structures from racemic to predominantly homohelical. We provide an explanation based on the interplay between geometrical frustration, racemization induced by thermal fluctuations, and particle chirality. Our results demonstrate that screw dislocations not only promote the growth, but also control the chiral morphology and therefore the functionality of crystalline states.
Chiral thermodynamics of nuclear matter
Energy Technology Data Exchange (ETDEWEB)
Fiorilla, Salvatore
2012-10-23
The equation of state of nuclear matter is calculated at finite temperature in the framework of in-medium chiral perturbation theory up to three-loop order. The dependence of its thermodynamic properties on the isospin-asymmetry is investigated. The chiral quark condensate is evaluated for symmetric nuclear matter. Its behaviour as a function of density and temperature sets important nuclear physics constraints for the QCD phase diagram.
Homogenization of resonant chiral metamaterials
DEFF Research Database (Denmark)
Andryieuski, Andrei; Menzel, C.; Rockstuhl, Carsten
2010-01-01
Homogenization of metamaterials is a crucial issue as it allows to describe their optical response in terms of effective wave parameters as, e.g., propagation constants. In this paper we consider the possible homogenization of chiral metamaterials. We show that for meta-atoms of a certain size...... an analytical criterion for performing the homogenization and a tool to predict the homogenization limit. We show that strong coupling between meta-atoms of chiral metamaterials may prevent their homogenization at all....
Chiral thermodynamics of nuclear matter
International Nuclear Information System (INIS)
Fiorilla, Salvatore
2012-01-01
The equation of state of nuclear matter is calculated at finite temperature in the framework of in-medium chiral perturbation theory up to three-loop order. The dependence of its thermodynamic properties on the isospin-asymmetry is investigated. The chiral quark condensate is evaluated for symmetric nuclear matter. Its behaviour as a function of density and temperature sets important nuclear physics constraints for the QCD phase diagram.
International Nuclear Information System (INIS)
Cho, Nam Sook; Kim, Hyun Sook; Song, Mi Sook
2011-01-01
In contrast with optical methods, there is no need to characterize the pure enantiomers. Instead, the NMR method makes use of chiral reagents that convert a mixture of enantiomers into a mixture of diastereomeric complexes. Integration of the resulting NMR spectra yields a direct measurement of enantiomeric purity as long as there is a sufficiently large difference between the chemical shifts of the two diastereoisomeric complexes to produce baseline-resolved peaks. Absolute enantiomeric configurations can also be determined using this method. Chiral lanthanide shift reagents have been used since the 1970s to form addition complexes with various compounds through interactions with electron donor sites. Lanthanide-induced, pseudo-contact shifts (LIS) are a function of the distance, r, between the nuclei under observation and the lanthanide center, and the angle, θ, between the line connecting the metal ion with the observed nucleus and the line representing the CLSR magnetic axis
Chiral gravitational waves and baryon superfluid dark matter
Alexander, Stephon; McDonough, Evan; Spergel, David N.
2018-05-01
We develop a unified model of darkgenesis and baryogenesis involving strongly interacting dark quarks, utilizing the gravitational anomaly of chiral gauge theories. In these models, both the visible and dark baryon asymmetries are generated by the gravitational anomaly induced by the presence of chiral primordial gravitational waves. We provide a concrete model of an SU(2) gauge theory with two massless quarks. In this model, the dark quarks condense and form a dark baryon charge superfluid (DBS), in which the Higgs-mode acts as cold dark matter. We elucidate the essential features of this dark matter scenario and discuss its phenomenological prospects.
Scattering of decuplet baryons in chiral effective field theory
Energy Technology Data Exchange (ETDEWEB)
Haidenbauer, J. [Institut fuer Kernphysik, Institute for Advanced Simulation and Juelich Center for Hadron Physics, Juelich (Germany); Petschauer, S.; Kaiser, N.; Weise, W. [Technische Universitaet Muenchen, Physik Department, Garching (Germany); Meissner, Ulf G. [Institut fuer Kernphysik, Institute for Advanced Simulation and Juelich Center for Hadron Physics, Juelich (Germany); Universitaet Bonn, Helmholtz-Institut fuer Strahlen- und Kernphysik and Bethe Center for Theoretical Physics, Bonn (Germany)
2017-11-15
A formalism for treating the scattering of decuplet baryons in chiral effective field theory is developed. The minimal Lagrangian and potentials in leading-order SU(3) chiral effective field theory for the interactions of octet baryons (B) and decuplet baryons (D) for the transitions BB → BB, BB <-> DB, DB → DB, BB <-> DD, DB <-> DD, and DD → DD are provided. As an application of the formalism we compare with results from lattice QCD simulations for ΩΩ and NΩ scattering. Implications of our results pertinent to the quest for dibaryons are discussed. (orig.)
ZNxZN generalization of the chiral Potts model
International Nuclear Information System (INIS)
Bazhanov, V.V.; Kashaev, R.M.; Mangazeev, V.V.
1990-01-01
It is shown that the R-matrix which interwines two 3-by-N 2 state cyclic L-operators can be considered as a Boltzmann weight of four-spin box for a lattice model with two-spin interaction juct as the R-matrix of the checkerboard chiral Potts model. The rapidity variables lie on the same algebraiz curve as in the chiral Potts model. Factorization properties of the L-operator and its connection to the SOS models, are also discussed. 13 refs.; 11 figs
Quark propagator and the chiral condensate in an instanton vacuum
International Nuclear Information System (INIS)
D'yakonov, D.I.; Petrov, V.Yu.
1985-01-01
A new mechanism of spontaneous breaking of chiral symmetry of strong interactions in instanton vacuum of quantum chromodynamics is proposed. The mechanism is based on the collectivization of zero fermion modes of individual instantons in a medium of pseudoparticles. The quark propagator in an instanton medium is found, and it is shown that the massless pole of the free propagator cancels out and quark acquires an effective mass which depends on the momentum. By employjng the characteristics of the instanton medium which was found previously, the value of the chiral condensate and the effective mass of the quark is obtained which is in good agreement with the phenomenology
Quark propagator and chiral condensate in an instanton vacuum
International Nuclear Information System (INIS)
D'yakonov, D.I.; Petrov, V.Y.
1985-01-01
A new mechanism is proposed for the spontaneous breaking of chiral symmetry of strong interactions in the instanton vacuum of quantum chromodynamics. The mechanism is based on the collectivization of zero-fermion modes of individual instantons in a pseudoparticle medium. The quark propagator in an instanton medium is found, and it is shown that the massless pole of the free propagator cancels out, with the quark assuming a momentum-dependent effective mass. The parameters of the instanton medium found previously are used to obtain the value of the chiral condensate and the effective mass of the quark, which are in good agreement with phenomenology
Covariant meson-baryon scattering with chiral and large Nc constraints
International Nuclear Information System (INIS)
Lutz, M.F.M.; Kolomeitsev, E.E.
2001-05-01
We give a review of recent progress on the application of the relativistic chiral SU(3) Lagrangian to meson-baryon scattering. It is shown that a combined chiral and 1/N c expansion of the Bethe-Salpeter interaction kernel leads to a good description of the kaon-nucleon, antikaon-nucleon and pion-nucleon scattering data typically up to laboratory momenta of p lab ≅ 500 MeV. We solve the covariant coupled channel Bethe-Salpeter equation with the interaction kernel truncated to chiral order Q 3 where we include only those terms which are leading in the large N c limit of QCD. (orig.)
Macdonald index and chiral algebra
Song, Jaewon
2017-08-01
For any 4d N = 2 SCFT, there is a subsector described by a 2d chiral algebra. The vacuum character of the chiral algebra reproduces the Schur index of the corresponding 4d theory. The Macdonald index counts the same set of operators as the Schur index, but the former has one more fugacity than the latter. We conjecture a prescription to obtain the Macdonald index from the chiral algebra. The vacuum module admits a filtration, from which we construct an associated graded vector space. From this grading, we conjecture a notion of refined character for the vacuum module of a chiral algebra, which reproduces the Macdonald index. We test this prescription for the Argyres-Douglas theories of type ( A 1 , A 2 n ) and ( A 1 , D 2 n+1) where the chiral algebras are given by Virasoro and \\widehat{su}(2) affine Kac-Moody algebra. When the chiral algebra has more than one family of generators, our prescription requires a knowledge of the generators from the 4d.
Chiral perturbation theory approach to hadronic weak amplitudes
International Nuclear Information System (INIS)
Rafael, E. de
1989-01-01
We are concerned with applications to the non-leptonic weak interactions in the sector of light quark flavors: u, d and s. Both strangeness changing ΔS=1 and ΔS=2 non-leptonic transitions can be described as weak perturbations to the strong effective chiral Lagrangian; the chiral structure of the weak effective Lagrangian being dictated by the transformation properties of the weak non-leptonic Hamiltonian of the Standard Model under global SU(3) Left xSU(3) Right rotations of the quark-fields. These lectures are organized as follows. Section 2 gives a review of the basic properties of chiral symmetry. Section 3 explains the effective chiral realization of the non-leptonic weak Hamiltonian of the Standard Model to lowest order in derivatives and masses. Section 4 deals with non-leptonic weak transitions in the presence of electromagnetism. Some recent applications to radiative kaon decays are reviewed and the effect of the so called electromagnetic penguin like diagrams is also discussed. Section 5 explains the basic ideas of the QCD-hadronic duality approach to the evaluation of coupling constants of the non-leptonic chiral weak Lagrangian. (orig./HSI)
Ballistic rectification of vortex domain wall chirality at nanowire corners
Energy Technology Data Exchange (ETDEWEB)
Omari, K.; Bradley, R. C.; Broomhall, T. J.; Hodges, M. P. P.; Hayward, T. J. [Department of Materials Science and Engineering, University of Sheffield, Sheffield S1 3JD (United Kingdom); Rosamond, M. C.; Linfield, E. H. [School of Electronic and Electrical Engineering, University of Leeds, Leeds LS2 9JT (United Kingdom); Im, M.-Y. [Center for X-Ray Optics, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Daegu Gyeongbuk Institute of Science and Technology, Daegu 711-873 (Korea, Republic of); Fischer, P. [Materials Sciences Division, Lawrence Berkley National Laboratory, Berkeley, California 94720 (United States); Department of Physics, University of California, Santa Cruz, California 94056 (United States)
2015-11-30
The interactions of vortex domain walls with corners in planar magnetic nanowires are probed using magnetic soft X-ray transmission microscopy. We show that when the domain walls are propagated into sharp corners using applied magnetic fields above a critical value, their chiralities are rectified to either clockwise or anticlockwise circulation depending on whether the corners turn left or right. Single-shot focused magneto-optic Kerr effect measurements are then used to demonstrate how, when combined with modes of domain propagation that conserve vortex chirality, this allows us to dramatically reduce the stochasticity of domain pinning at artificial defect sites. Our results provide a tool for controlling domain wall chirality and pinning behavior both in further experimental studies and in future domain wall-based memory, logic and sensor technologies.
Chirality Quantum Phase Transition in Noncommutative Dirac Oscillator
International Nuclear Information System (INIS)
Wang Shao-Hua; Hou Yu-Long; Jing Jian; Wang Qing; Long Zheng-Wen
2014-01-01
The charged Dirac oscillator on a noncommutative plane coupling to a uniform perpendicular magnetic held is studied in this paper. We map the noncommutative plane to a commutative one by means of Bopp shift and study this problem on the commutative plane. We find that this model can be mapped onto a quantum optics model which contains Anti—Jaynes—Cummings (AJC) or Jaynes—Cummings (JC) interactions when a dimensionless parameter ζ (which is the function of the intensity of the magnetic held) takes values in different regimes. Furthermore, this model behaves as experiencing a chirality quantum phase transition when the dimensionless parameter ζ approaches the critical point. Several evidences of the chirality quantum phase transition are presented. We also study the non-relativistic limit of this model and find that a similar chirality quantum phase transition takes place in its non-relativistic limit. (physics of elementary particles and fields)
Chirality-selected phase behaviour in ionic polypeptide complexes
Perry, Sarah L.; Leon, Lorraine; Hoffmann, Kyle Q.; Kade, Matthew J.; Priftis, Dimitrios; Black, Katie A.; Wong, Derek; Klein, Ryan A.; Pierce, Charles F.; Margossian, Khatcher O.; Whitmer, Jonathan K.; Qin, Jian; de Pablo, Juan J.; Tirrell, Matthew
2015-01-01
Polyelectrolyte complexes present new opportunities for self-assembled soft matter. Factors determining whether the phase of the complex is solid or liquid remain unclear. Ionic polypeptides enable examination of the effects of stereochemistry on complex formation. Here we demonstrate that chirality determines the state of polyelectrolyte complexes, formed from mixing dilute solutions of oppositely charged polypeptides, via a combination of electrostatic and hydrogen-bonding interactions. Fluid complexes occur when at least one of the polypeptides in the mixture is racemic, which disrupts backbone hydrogen-bonding networks. Pairs of purely chiral polypeptides, of any sense, form compact, fibrillar solids with a β-sheet structure. Analogous behaviour occurs in micelles formed from polypeptide block copolymers with polyethylene oxide, where assembly into aggregates with either solid or fluid cores, and eventually into ordered phases at high concentrations, is possible. Chirality is an exploitable tool for manipulating material properties in polyelectrolyte complexation. PMID:25586861
High-quality two-nucleon potentials up to fifth order of the chiral expansion
Entem, D. R.; Machleidt, R.; Nosyk, Y.
2017-08-01
We present NN potentials through five orders of chiral effective field theory ranging from leading order (LO) to next-to-next-to-next-to-next-to-leading order (N4LO ). The construction may be perceived as consistent in the sense that the same power counting scheme as well as the same cutoff procedures are applied in all orders. Moreover, the long-range parts of these potentials are fixed by the very accurate π N low-energy constants (LECs) as determined in the Roy-Steiner equations analysis by Hoferichter, Ruiz de Elvira, and coworkers. In fact, the uncertainties of these LECs are so small that a variation within the errors leads to effects that are essentially negligible, reducing the error budget of predictions considerably. The NN potentials are fit to the world NN data below the pion-production threshold of the year 2016. The potential of the highest order (N4LO ) reproduces the world NN data with the outstanding χ2/datum of 1.15, which is the highest precision ever accomplished for any chiral NN potential to date. The NN potentials presented may serve as a solid basis for systematic ab initio calculations of nuclear structure and reactions that allow for a comprehensive error analysis. In particular, the consistent order by order development of the potentials will make possible a reliable determination of the truncation error at each order. Our family of potentials is nonlocal and, generally, of soft character. This feature is reflected in the fact that the predictions for the triton binding energy (from two-body forces only) converges to about 8.1 MeV at the highest orders. This leaves room for three-nucleon-force contributions of moderate size.
Consistent, high-quality two-nucleon potentials up to fifth order of the chiral expansion
Machleidt, R.
2018-02-01
We present N N potentials through five orders of chiral effective field theory ranging from leading order (LO) to next-to-next-to-next-to-next-to-leading order (N4LO). The construction may be perceived as consistent in the sense that the same power counting scheme as well as the same cutoff procedures are applied in all orders. Moreover, the long-range parts of these potentials are fixed by the very accurate πN low-energy constants (LECs) as determined in the Roy-Steiner equations analysis by Hoferichter, Ruiz de Elvira and coworkers. In fact, the uncertainties of these LECs are so small that a variation within the errors leads to effects that are essentially negligible, reducing the error budget of predictions considerably. The N N potentials are fit to the world N N data below pion-production threshold of the year of 2016. The potential of the highest order (N4LO) reproduces the world N N data with the outstanding χ 2/datum of 1.15, which is the highest precision ever accomplished for any chiral N N potential to date. The N N potentials presented may serve as a solid basis for systematic ab initio calculations of nuclear structure and reactions that allow for a comprehensive error analysis. In particular, the consistent order by order development of the potentials will make possible a reliable determination of the truncation error at each order. Our family of potentials is non-local and, generally, of soft character. This feature is reflected in the fact that the predictions for the triton binding energy (from two-body forces only) converges to about 8.1 MeV at the highest orders. This leaves room for three-nucleon-force contributions of moderate size.
Chiral plaquette polaron theory of cuprate superconductivity
Tahir-Kheli, Jamil; Goddard, William A., III
2007-07-01
Ab initio density functional calculations on explicitly doped La2-xSrxCuO4 find that doping creates localized holes in out-of-plane orbitals. A model for cuprate superconductivity is developed based on the assumption that doping leads to the formation of holes on a four-site Cu plaquette composed of the out-of-plane A1 orbitals apical Opz , planar Cud3z2-r2 , and planar Opσ . This is in contrast to the assumption of hole doping into planar Cudx2-y2 and Opσ orbitals as in the t-J model. Allowing these holes to interact with the d9 spin background leads to chiral polarons with either a clockwise or anticlockwise charge current. When the polaron plaquettes percolate through the crystal at x≈0.05 for La2-xSrxCuO4 , a Cudx2-y2 and planar Opσ band is formed. The computed percolation doping of x≈0.05 equals the observed transition to the “metallic” and superconducting phase for La2-xSrxCuO4 . Spin exchange Coulomb repulsion with chiral polarons leads to d -wave superconducting pairing. The equivalent of the Debye energy in phonon superconductivity is the maximum energy separation between a chiral polaron and its time-reversed partner. This energy separation is on the order of the antiferromagnetic spin coupling energy, Jdd˜0.1eV , suggesting a higher critical temperature. An additive skew-scattering contribution to the Hall effect is induced by chiral polarons and leads to a temperature dependent Hall effect that fits the measured values for La2-xSrxCuO4 . The integrated imaginary susceptibility, observed by neutron spin scattering, satisfies ω/T scaling due to chirality and spin-flip scattering of polarons along with a uniform distribution of polaron energy splittings. The derived functional form is compatible with experiments. The static spin structure factor for chiral spin coupling of the polarons to the undoped antiferromagnetic Cud9 spins is computed for classical spins on large two-dimensional lattices and is found to be incommensurate with a
Momiyama, Norie; Tabuse, Hideaki; Noda, Hirofumi; Yamanaka, Masahiro; Fujinami, Takeshi; Yamanishi, Katsunori; Izumiseki, Atsuto; Funayama, Kosuke; Egawa, Fuyuki; Okada, Shino; Adachi, Hiroaki; Terada, Masahiro
2016-09-07
A chiral Brønsted acid containing two different acidic sites, chiral carboxylic acid-monophosphoric acid 1a, was designed to be a new and effective concept in catalytic asymmetric hetero-Diels-Alder reactions of azopyridinecarboxylate with amidodienes. The multipoint hydrogen-bonding interactions among the carboxylic acid, monophosphoric acid, azopyridinecarboxylate, and amidodiene achieved high catalytic and chiral efficiency, producing substituted 1,2,3,6-tetrahydropyridazines with excellent stereocontrol in a single step. This constitutes the first example of regio-, diastereo-, and enantioselective azo-hetero-Diels-Alder reactions by chiral Brønsted acid catalysis.
Quantum Hall bilayers and the chiral sine-Gordon equation
International Nuclear Information System (INIS)
Naud, J.D.; Pryadko, Leonid P.; Sondhi, S.L.
2000-01-01
The edge state theory of a class of symmetric double-layer quantum Hall systems with interlayer electron tunneling reduces to the sum of a free field theory and a field theory of a chiral Bose field with a self-interaction of the sine-Gordon form. We argue that the perturbative renormalization group flow of this chiral sine-Gordon theory is distinct from the standard (non-chiral) sine-Gordon theory, contrary to a previous assertion by Renn, and that the theory is manifestly sensible only at a discrete set of values of the inverse period of the cosine interaction (β-circumflex). We obtain exact solutions for the spectra and correlation functions of the chiral sine-Gordon theory at the two values of β-circumflex at which electron tunneling in bilayers is not irrelevant. Of these, the marginal case (β-circumflex 2 =4) is of greatest interest: the spectrum of the interacting theory is that of two Majorana fermions with different, dynamically generated, velocities. For the experimentally observed bilayer 331 state at filling factor 1/2, this implies the trifurcation of electrons added to the edge. We also present a method for fermionizing the theory at the discrete points (β-circumflex 2 is an element of Z + ) by the introduction of auxiliary degrees of freedom that could prove useful in other problems involving quantum Hall multi-layers
Chirality in adsorption on solid surfaces.
Zaera, Francisco
2017-12-07
In the present review we survey the main advances made in recent years on the understanding of chemical chirality at solid surfaces. Chirality is an important topic, made particularly relevant by the homochiral nature of the biochemistry of life on Earth, and many chiral chemical reactions involve solid surfaces. Here we start our discussion with a description of surface chirality and of the different ways that chirality can be bestowed on solid surfaces. We then expand on the studies carried out to date to understand the adsorption of chiral compounds at a molecular level. We summarize the work published on the adsorption of pure enantiomers, of enantiomeric mixtures, and of prochiral molecules on chiral and achiral model surfaces, especially on well-defined metal single crystals but also on other flat substrates such as highly ordered pyrolytic graphite. Several phenomena are identified, including surface reconstruction and chiral imprinting upon adsorption of chiral agents, and the enhancement or suppression of enantioselectivity seen in some cases upon adsorption of enantiomixtures of chiral compounds. The possibility of enhancing the enantiopurity of adsorbed layers upon the addition of chiral seeds and the so-called "sergeants and soldiers" phenomenon are presented. Examples are provided where the chiral behavior has been associated with either thermodynamic or kinetic driving forces. Two main approaches to the creation of enantioselective surface sites are discussed, namely, via the formation of supramolecular chiral ensembles made out of small chiral adsorbates, and by adsorption of more complex chiral molecules capable of providing suitable chiral environments for reactants by themselves, via the formation of individual adsorbate:modifier adducts on the surface. Finally, a discussion is offered on the additional effects generated by the presence of the liquid phase often required in practical applications such as enantioselective crystallization, chiral
Chiral memory via chiral amplification and selective depolymerization of porphyrin aggregates
Helmich, F.A.; Lee, C.C.; Schenning, A.P.H.J.; Meijer, E.W.
2010-01-01
Chiral memory at the supramolecular level is obtained via a new approach using chiral Zn porphrins and achiral Cu porphyrins. In a "sergeant-and-soldiers" experiment, the Zn "sergeant" transfers its own chirality to Cu "soldiers" and, after chiral amplification, the "sergeant" is removed from the
Chiral Dynamics in Pion-Photon Reactions Habilitation
Friedrich, Jan Michael
As the lightest particle of the strong force, the pion plays a central role in the field of strong interactions, and understanding its properties is of prime relevance for understanding the strong interaction in general. The low-energy behaviour of pions is of particular interest. Although the quark-gluon substructure and their quantum chromodynamics is not apparent then, this specific inner structure causes the presence of approximate symmetries in pion-pion interactions and in pion decays, which gives rise to the systematic description of processes involving pions in terms of few low-energy constants. Specifically, the chiral symmetry and its spontaneous and explicit breaking, treated in chiral perturbation theory (ChPT), leads to firm predictions for low-energy properties of the pion. To those belong the electromagnetic polarisabilities of the pion, describing the leading-order structure effect in pion Compton scattering. The research presented in this work is concerned with the interaction of pions and ph...
Effects of chirality and surface stresses on the bending and buckling of chiral nanowires
International Nuclear Information System (INIS)
Wang, Jian-Shan; Shimada, Takahiro; Kitamura, Takayuki; Wang, Gang-Feng
2014-01-01
Due to their superior optical, elastic and electrical properties, chiral nanowires have many applications as sensors, probes, and building blocks of nanoelectromechanical systems. In this paper, we develop a refined Euler–Bernoulli beam model for chiral nanowires with surface effects and material chirality incorporated. This refined model is employed to investigate the bending and buckling of chiral nanowires. It is found that surface effects and material chirality significantly affect the elastic behaviour of chiral nanowires. This study is helpful not only for understanding the size-dependent behaviour of chiral nanowires, but also for characterizing their mechanical properties. (paper)
What's wrong with anomalous chiral gauge theory?
International Nuclear Information System (INIS)
Kieu, T.D.
1994-05-01
It is argued on general ground and demonstrated in the particular example of the Chiral Schwinger Model that there is nothing wrong with apparently anomalous chiral gauge theory. If quantised correctly, there should be no gauge anomaly and chiral gauge theory should be renormalisable and unitary, even in higher dimensions and with non-Abelian gauge groups. Furthermore, it is claimed that mass terms for gauge bosons and chiral fermions can be generated without spoiling the gauge invariance. 19 refs
Chirality: a relational geometric-physical property.
Gerlach, Hans
2013-11-01
The definition of the term chirality by Lord Kelvin in 1893 and 1904 is analyzed by taking crystallography at that time into account. This shows clearly that chirality is a relational geometric-physical property, i.e., two relations between isometric objects are possible: homochiral or heterochiral. In scientific articles the relational term chirality is often mistaken for the two valued measure for the individual (absolute) sense of chirality, an arbitrary attributive term. © 2013 Wiley Periodicals, Inc.
Extreme chirality in Swiss roll metamaterials
International Nuclear Information System (INIS)
Demetriadou, A; Pendry, J B
2009-01-01
The chiral Swiss roll metamaterial is a resonant, magnetic medium that exhibits a negative refractive band for one-wave polarization. Its unique structure facilitates huge chiral effects: a plane polarized wave propagating through this system can change its polarization by 90 deg. in less than a wavelength. Such chirality is at least 100 times greater than previous structures have achieved. In this paper, we discuss this extreme chiral behaviour with both numerical and analytical results.
Chiral dynamics of baryons in the perturbative chiral quark model
Energy Technology Data Exchange (ETDEWEB)
Pumsa-ard, K.
2006-07-01
In this work we develop and apply variants of a perturbative chiral quark model (PCQM) to the study of baryonic properties dominantly in the low-energy region. In a first step we consider a noncovariant form of the PCQM, where confinement is modelled by a static, effective potential and chiral corrections are treated to second order, in line with similar chiral quark models. We apply the PCQM to the study of the electromagnetic form factors of the baryon octet. We focus in particular on the low-energy observables such as the magnetic moments, the charge and magnetic radii. In addition, the electromagnetic N-delta transition is also studied in the framework of the PCQM. In the chiral loop calculations we consider a quark propagator, which is restricted to the quark ground state, or in hadronic language to nucleon and delta intermediate states, for simplicity. We furthermore include the low-lying excited states to the quark propagator. In particular, the charge radius of the neutron and the transverse helicity amplitudes of the N-delta transition are considerably improved by this additional effect. In a next step we develop a manifestly Lorentz covariant version of the PCQM, where in addition higher order chiral corrections are included. The full chiral quark Lagrangian is motivated by and in analogy to the one of Chiral Perturbation Theory (ChPT). This Lagrangian contains a set of low energy constants (LECs), which are parameters encoding short distance effects and heavy degrees of freedom. We evaluate the chiral Lagrangian to order O(p{sup 4}) and to one loop to generate the dressing of the bare quark operators by pseudoscalar mesons. In addition we include the vector meson degrees of freedom in our study. Projection of the dressed quark operators on the baryonic level serves to calculate the relevant matrix elements. In a first application of this scheme, we resort to a parameterization of the valence quark form factors in the electromagnetic sector. Constraints
Chiral measurements with the Fixed-Point Dirac operator and construction of chiral currents
International Nuclear Information System (INIS)
Hasenfratz, P.; Hauswirth, S.; Holland, K.; Joerg, T.; Niedermayer, F.
2002-01-01
In this preliminary study, we examine the chiral properties of the parametrized Fixed-Point Dirac operator D FP , see how to improve its chirality via the Overlap construction, measure the renormalized quark condensate Σ-circumflex and the topological susceptibility χ t , and investigate local chirality of near zero modes of the Dirac operator. We also give a general construction of chiral currents and densities for chiral lattice actions
Pion polarizability in a chiral quark model
International Nuclear Information System (INIS)
Volkov, M.K.; Ehbert, D.
1980-01-01
The pion polarizability is calculated in a chiral meson-quark model at the one-loop level. The results are in complete agreement with earlier ones obtained within a chiral meson-baryon theory. A critical discussion of a recent paper by Lanta and Tarrach is given. The results of the paper give evidence to the nonlinear chiral Lagrangian favour
Quenched Chiral Perturbation Theory to one loop
Colangelo, G.; Pallante, E.
The divergences of the generating functional of quenched Chiral Perturbation theory (qCHPT) to one loop are computed in closed form. We show how the quenched chiral logarithms can be reabsorbed in the renormalization of the B0 parameter of the leading order Lagrangian. Finally, we do the chiral
Chirality plays important roles in radiopharmaceuticals
International Nuclear Information System (INIS)
Shen Yumei
2006-01-01
The paper introduces the basic concept of chirality, target specific selectivity and their relationship in radiopharmaceuticals. If the ligands labeled by radionuclides have chiral center, the enantiomers must be separated, or the target specific selectivity will not be good. Chirality is one of the most important factors which must be considered in the study of the structure-activity relationship of radiopharmaceuticals. (authors)
Electroweak interactions on the lattice
International Nuclear Information System (INIS)
Kieu, T.D.
1994-07-01
It is shown that the lattice fermion doubling phenomenon is connected to the chiral anomaly which is unique to the electroweak interactions. The chiral anomaly is the breaking of chiral gauge symmetry at the quantum level due to the quantum fluctuations. Such breaking, however, is undesirable and to be avoided. The preservation of gauge symmetry imposes stringent constraints on acceptable chiral gauge theory. It is argued that the constraints are unnecessary because the conventional quantization of chiral gauge theory has missed out some crucial contributions of the chiral interactions. The corrected quantization yields consistent theory in which there is no gauge anomaly and in which various mass terms can be introduced with neither the loss of gauge invariance nor the need for the Higgs mechanism. The new quantization also provide a solution to the difficulty of how to model the electroweak interactions on the lattice. 9 refs. 1 fig
International Nuclear Information System (INIS)
Rho, M.
1982-01-01
As an aid to discussing the structure of nucleons and nuclei conceptual framework, heuristic arguments are presented which indicate that a hadron can be considered as a bag consisting of two different phases. The chiral structure of the phase outside the bag is discussed in terms of effective field theories and it is shown to what extent experiments in nuclei can constrain the structure of such theories. Results thus obtained are then combined to set up a set of equations for the bag structure of u and d hadrons, incorporating asymptotic freedom in the phase inside of the bag confinement of quarks and gluons by boundary conditions and spontaneously broken chiral symmetry in the outside. This set of equations which represent a chirally invariant generalization of the M.I.T. bag model is then solved. (U.K.)
Fusion rules of chiral algebras
International Nuclear Information System (INIS)
Gaberdiel, M.
1994-01-01
Recently we showed that for the case of the WZW and the minimal models fusion can be understood as a certain ring-like tensor product of the symmetry algebra. In this paper we generalize this analysis to arbitrary chiral algebras. We define the tensor product of conformal field theory in the general case and prove that it is associative and symmetric up to equivalence. We also determine explicitly the action of the chiral algebra on this tensor product. In the second part of the paper we demonstrate that this framework provides a powerful tool for calculating restrictions for the fusion rules of chiral algebras. We exhibit this for the case of the W 3 algebra and the N=1 and N=2 NS superconformal algebras. (orig.)
Coïsson, Marco; Barrera, Gabriele; Celegato, Federica; Manzin, Alessandra; Vinai, Franco; Tiberto, Paola
2016-01-01
Magnetic vortex chirality in patterned square dots has been investigated by means of a field-dependent magnetic force microscopy technique that allows to measure local hysteresis loops. The chirality affects the two loop branches independently, giving rise to curves that have different shapes and symmetries as a function of the details of the magnetisation reversal process in the square dot, that is studied both experimentally and through micromagnetic simulations. The tip-sample interaction is taken into account numerically, and exploited experimentally, to influence the side of the square where nucleation of the vortex preferably occurs, therefore providing a way to both measure and drive chirality with the present technique. PMID:27426442
International Nuclear Information System (INIS)
Zhang, J; Gu, Q; Lörscher, C; Klemm, R A
2014-01-01
We calculate the temperature T and angular (θ, ϕ) dependencies of the upper critical induction B c2 (θ, ϕ, T) for parallel-spin superconductors with an axially symmetric p-wave pairing interaction pinned to the lattice and a dominant ellipsoidal Fermi surface (FS). For all FS anisotropies, the chiral Scharnberg–Klemm (SK) state B c2 (θ, ϕ, T) exceeds that of the chiral Anderson–Brinkman–Morel (ABM) state and exhibits a kink at θ = θ * (T, ϕ), indicative of a first-order transition from its chiral, nodal-direction behavior to its non-chiral, antinodal-direction behavior. Applicabilities to Sr 2 RuO 4 , UCoGe and the candidate topological superconductor Cu x Bi 2 Se 3 are discussed. (fast track communication)
Chiral soliton models for baryons
International Nuclear Information System (INIS)
Weigel, H.
2008-01-01
This concise research monograph introduces and reviews the concept of chiral soliton models for baryons. In these models, baryons emerge as (topological) defects of the chiral field. The many applications shed light on a number of baryon properties, ranging from static properties via nucleon resonances and deep inelastic scattering to even heavy ion collisions. As far as possible, the theoretical investigations are confronted with experiment. Conceived to bridge the gap between advanced graduate textbooks and the research literature, this volume also features a number of appendices to help nonspecialist readers to follow in more detail some of the calculations in the main text. (orig.)
Surface defects and chiral algebras
Energy Technology Data Exchange (ETDEWEB)
Córdova, Clay [School of Natural Sciences, Institute for Advanced Study,1 Einstein Dr, Princeton, NJ 08540 (United States); Gaiotto, Davide [Perimeter Institute for Theoretical Physics,31 Caroline St N, Waterloo, ON N2L 2Y5 (Canada); Shao, Shu-Heng [School of Natural Sciences, Institute for Advanced Study,1 Einstein Dr, Princeton, NJ 08540 (United States)
2017-05-26
We investigate superconformal surface defects in four-dimensional N=2 superconformal theories. Each such defect gives rise to a module of the associated chiral algebra and the surface defect Schur index is the character of this module. Various natural chiral algebra operations such as Drinfeld-Sokolov reduction and spectral flow can be interpreted as constructions involving four-dimensional surface defects. We compute the index of these defects in the free hypermultiplet theory and Argyres-Douglas theories, using both infrared techniques involving BPS states, as well as renormalization group flows onto Higgs branches. In each case we find perfect agreement with the predicted characters.
Asymmetric Synthesis via Chiral Aziridines
DEFF Research Database (Denmark)
Tanner, David Ackland; Harden, Adrian; Wyatt, Paul
1996-01-01
A series of chiral bis(aziridines) has been synthesised and evaluated as chelating ligands for a variety of asymmetric transformations mediated by metals [Os (dihydroxylation), Pd (allylic alkylation) Cu (cyclopropanation and aziridination, Li (1,2-addition of organolithiums to imines)]. In the b......A series of chiral bis(aziridines) has been synthesised and evaluated as chelating ligands for a variety of asymmetric transformations mediated by metals [Os (dihydroxylation), Pd (allylic alkylation) Cu (cyclopropanation and aziridination, Li (1,2-addition of organolithiums to imines...
Chiral symmetry on the lattice
International Nuclear Information System (INIS)
Creutz, M.
1994-11-01
The author reviews some of the difficulties associated with chiral symmetry in the context of a lattice regulator. The author discusses the structure of Wilson Fermions when the hopping parameter is in the vicinity of its critical value. Here one flavor contrasts sharply with the case of more, where a residual chiral symmetry survives anomalies. The author briefly discusses the surface mode approach, the use of mirror Fermions to cancel anomalies, and finally speculates on the problems with lattice versions of the standard model
DNA Self-Assembly: From Chirality to Evolution
Directory of Open Access Journals (Sweden)
Youri Timsit
2013-04-01
Full Text Available Transient or long-term DNA self-assembly participates in essential genetic functions. The present review focuses on tight DNA-DNA interactions that have recently been found to play important roles in both controlling DNA higher-order structures and their topology. Due to their chirality, double helices are tightly packed into stable right-handed crossovers. Simple packing rules that are imposed by DNA geometry and sequence dictate the overall architecture of higher order DNA structures. Close DNA-DNA interactions also provide the missing link between local interactions and DNA topology, thus explaining how type II DNA topoisomerases may sense locally the global topology. Finally this paper proposes that through its influence on DNA self-assembled structures, DNA chirality played a critical role during the early steps of evolution.
Reversible optical transcription of supramolecular chirality into molecular chirality
Jong, Jaap J.D. de; Lucas, Linda N.; Kellogg, Richard M.; Esch, Jan H. van; Feringa, Bernard
2004-01-01
In nature, key molecular processes such as communication, replication, and enzyme catalysis all rely on a delicate balance between molecular and supramolecular chirality. Here we report the design, synthesis, and operation of a reversible, photoresponsive, self-assembling molecular system in which
Degenerate and chiral states in the extended Heisenberg model on the kagome lattice
Gómez Albarracín, F. A.; Pujol, P.
2018-03-01
We present a study of the low-temperature phases of the antiferromagnetic extended classical Heisenberg model on the kagome lattice, up to third-nearest neighbors. First, we focus on the degenerate lines in the boundaries of the well-known staggered chiral phases. These boundaries have either semiextensive or extensive degeneracy, and we discuss the partial selection of states by thermal fluctuations. Then, we study the model under an external magnetic field on these lines and in the staggered chiral phases. We pay particular attention to the highly frustrated point, where the three exchange couplings are equal. We show that this point can be mapped to a model with spin-liquid behavior and nonzero chirality. Finally, we explore the effect of Dzyaloshinskii-Moriya (DM) interactions in two ways: a homogeneous and a staggered DM interaction. In both cases, there is a rich low-temperature phase diagram, with different spontaneously broken symmetries and nontrivial chiral phases.
Oscillation damping of chiral string loops
International Nuclear Information System (INIS)
Babichev, Eugeny; Dokuchaev, Vyacheslav
2002-01-01
Chiral cosmic string loops tend to the stationary (vorton) configuration due to energy loss into gravitational and electromagnetic radiation. We describe the asymptotic behavior of near stationary chiral loops and their fading to vortons. General limits on the gravitational and electromagnetic energy losses by near stationary chiral loops are found. For these loops we estimate the oscillation damping time. We present solvable examples of gravitational radiation energy loss by some chiral loop configurations. The analytical dependence of string energy with time is found in the case of the chiral ring with small amplitude radial oscillations
Toy model for two chiral nonets
International Nuclear Information System (INIS)
Fariborz, Amir H.; Jora, Renata; Schechter, Joseph
2005-01-01
Motivated by the possibility that nonets of scalar mesons might be described as mixtures of 'two quark' and 'four quark' components, we further study a toy model in which corresponding chiral nonets (containing also the pseudoscalar partners) interact with each other. Although the 'two quark' and 'four quark' chiral fields transform identically under SU(3) L xSU(3) R transformations, they transform differently under the U(1) A transformation which essentially counts total (quark+antiquark) content of the mesons. To implement this, we formulate an effective Lagrangian which mocks up the U(1) A behavior of the underlying QCD. We derive generating equations which yield Ward identity type relations based only on the assumed symmetry structure. This is applied to the mass spectrum of the low lying pseudoscalars and scalars, as well as their 'excitations'. Assuming isotopic spin invariance, it is possible to disentangle the amount of 'two quark' vs 'four quark' content in the pseudoscalar π,K,η-type states and in the scalar κ-type states. It is found that a small 'four quark' content in the lightest pseudoscalars is consistent with a large 'four quark' content in the lightest of the scalar κ mesons. The present toy model also allows one to easily estimate the strength of a 'four quark' vacuum condensate. There seems to be a rich and interesting structure
8th International Workshop on Chiral Dynamics
2016-01-01
The International Workshop on Chiral Dynamics 2015, the eighth in a series which started in 1994 at MIT, and was later held in Mainz (1997), Jefferson Lab (2000 and 2012), Bonn (2003), Duke (2006) and Bern (2009), will take place in Pisa, from June 29 to July 3 2015, and will be jointly hosted by the Department of Physics of the University of Pisa and the Pisa branch of the Istituto Nazionale di Fisica Nucleare. The purpose of this workshop series is to bring physicists together who are active in this field, as well as those who are interested, to discuss and debate the most recent achievements and future developments. The workshop will have a near equal contribution from theorists and experimentalists and, as in the latest editions, a strong synergy with the lattice community will be present. Topics: Hadron structure Isospin breaking in hadronic systems Meson-meson and meson-baryon interaction Effective field theory and chiral perturbation theory Few-body physics Compton scattering and the polarizabilities o...
Chiral model for nucleon and delta
International Nuclear Information System (INIS)
Birse, M.C.; Banerjee, M.K.
1985-01-01
We propose a model of the nucleon and delta based on the idea that strong QCD forces on length scales approx.0.2--1 fm result in hidden chiral SU(2) x SU(2) symmetry and that there is a separation of roles between these forces which are also responsible for binding quarks in hadrons and the forces which produce absolute confinement. This leads us to study a linear sigma model describing the interactions of quarks, sigma mesons, and pions. We have solved this model in the semiclassical (mean-field) approximation for the hedgehog baryon state. We refer to this solution as a chiral soliton. In the semiclassical approximation the hedgehog state is a linear combination of N and Δ. We project this state onto states of good spin and isospin to calculate matrix elements of various operators in these states. Our results are in reasonable agreement with the observed properties of the nucleon. The mesonic contributions to g/sub A/ and sigma(πN) are about two to three times too large, suggesting the need for quantum corrections
Directing the phase behavior of polyelectrolyte complexes using chiral patterned peptides
Energy Technology Data Exchange (ETDEWEB)
Pacalin, Naomi M.; Leon, Lorraine; Tirrell, Matthew
2016-10-01
Polyelectrolyte complexes (PECs) have a broad range of promising applications as soft materials due to their self-assembly and diversity of structure and chemical composition. Peptide polymer PECs are highly biocompatible and biodegradable, making them particularly useful for encapsulation of food additives and flavors, micellar drug delivery, medical and underwater adhesives, fetal membrane patches, and scaffolds for cell growth in tissue engineering. While parameters affecting PEC formation and stability in regards to charge effects are well researched, little is known about the effects of van der Waals interactions, hydrogen bonding, and secondary structure in these materials. Peptide chirality provides a unique opportunity to manipulate PEC phase to modulate the amount of solid-like (precipitate) or liquid-like (coacervate) character by influencing hydrogen bonding interactions among peptide chains. In previous work, we showed that chiral peptides form solid complexes, while complexes with even one racemic peptide were fluid. This raised the interesting question of how long a homochiral sequence must be to result in solid phase formation. In this work, we designed chiral patterned peptides of polyglutamic acid and polylysine ranging from 50 to 90% L-chiral residues with increasing numbers of sequential L-chiral residues before a chirality change. These polymers were mixed together to form PECs. We observed that 8 or more sequential L-chiral residues are necessary to achieve both the appearance of a precipitate phase and sustained beta-sheets in the complex, as determined by optical imaging and FTIR Spectroscopy. Less homochiral content results in formation of a coacervate phase. Thus, we show that chiral sequence can be used to control the phase transition of PECs. Understanding how to manipulate PEC phase using chiral sequence as presented here may enable tuning of the material properties to achieve the desired mechanical strength for coatings and polymer
Directing the phase behavior of polyelectrolyte complexes using chiral patterned peptides
Pacalin, Naomi M.; Leon, Lorraine; Tirrell, Matthew
2016-10-01
Polyelectrolyte complexes (PECs) have a broad range of promising applications as soft materials due to their self-assembly and diversity of structure and chemical composition. Peptide polymer PECs are highly biocompatible and biodegradable, making them particularly useful for encapsulation of food additives and flavors, micellar drug delivery, medical and underwater adhesives, fetal membrane patches, and scaffolds for cell growth in tissue engineering. While parameters affecting PEC formation and stability in regards to charge effects are well researched, little is known about the effects of van der Waals interactions, hydrogen bonding, and secondary structure in these materials. Peptide chirality provides a unique opportunity to manipulate PEC phase to modulate the amount of solid-like (precipitate) or liquid-like (coacervate) character by influencing hydrogen bonding interactions among peptide chains. In previous work, we showed that chiral peptides form solid complexes, while complexes with even one racemic peptide were fluid. This raised the interesting question of how long a homochiral sequence must be to result in solid phase formation. In this work, we designed chiral patterned peptides of polyglutamic acid and polylysine ranging from 50 to 90% L-chiral residues with increasing numbers of sequential L-chiral residues before a chirality change. These polymers were mixed together to form PECs. We observed that 8 or more sequential L-chiral residues are necessary to achieve both the appearance of a precipitate phase and sustained β-sheets in the complex, as determined by optical imaging and FTIR Spectroscopy. Less homochiral content results in formation of a coacervate phase. Thus, we show that chiral sequence can be used to control the phase transition of PECs. Understanding how to manipulate PEC phase using chiral sequence as presented here may enable tuning of the material properties to achieve the desired mechanical strength for coatings and polymer
Chiral Recognition and Separation by Chirality-Enriched Metal-Organic Frameworks.
Das, Saikat; Xu, Shixian; Ben, Teng; Qiu, Shilun
2018-05-16
Endowed with chiral channels and pores, chiral metal-organic frameworks (MOFs) are highly useful; however, their synthesis remains a challenge given that most chiral building blocks are expensive. Although MOFs with induced chirality have been reported to avoid this shortcoming, no study providing evidence for the ee value of such MOFs has yet been reported. We herein describe the first study on the efficiency of chiral induction in MOFs using inexpensive achiral building blocks and fully recoverable chiral dopants to control the handedness of racemic MOFs. This method yielded chirality-enriched MOFs with accessible pores. The ability of the materials to form host-guest complexes was probed with enantiomers of varying size and coordination and in solvents with varying polarity. Furthermore, mixed-matrix membranes (MMMs) composed of chirality-enriched MOF particles dispersed in a polymer matrix demonstrated a new route for chiral separation. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
DEFF Research Database (Denmark)
Nuermaimaiti, Ajiguli; Bombis, Christian; Knudsen, Martin Markvard
2014-01-01
Molecular-level insights into chiral adsorption phenomena are highly relevant within the fields of asymmetric heterogeneous catalysis or chiral separation and may contribute to understand the origins of homochirality in nature. Here, we investigate chiral induction by the "sergeants and soldiers......" mechanism for an oligo(phenylene ethynylene) based chiral conformational switch by coadsorbing it with an intrinsically chiral seed on Au(111). Through statistical analysis of scanning tunneling microscopy (STM) data we demonstrate successful chiral induction with a very low concentration of seeding...... molecules down to 3%. The microscopic mechanism for the observed chiral induction is suggested to involve nucleation of the intrinsically chiral seeds, allowing for effective transfer and amplification of chirality to large numbers of soldier target molecules....
Chirality effect in disordered graphene ribbon junctions
International Nuclear Information System (INIS)
Long Wen
2012-01-01
We investigate the influence of edge chirality on the electronic transport in clean or disordered graphene ribbon junctions. By using the tight-binding model and the Landauer-Büttiker formalism, the junction conductance is obtained. In the clean sample, the zero-magnetic-field junction conductance is strongly chirality-dependent in both unipolar and bipolar ribbons, whereas the high-magnetic-field conductance is either chirality-independent in the unipolar or chirality-dependent in the bipolar ribbon. Furthermore, we study the disordered sample in the presence of magnetic field and find that the junction conductance is always chirality-insensitive for both unipolar and bipolar ribbons with adequate disorders. In addition, the disorder-induced conductance plateaus can exist in all chiral bipolar ribbons provided the disorder strength is moderate. These results suggest that we can neglect the effect of edge chirality in fabricating electronic devices based on the magnetotransport in a disordered graphene ribbon. (paper)
No chiral truncation of quantum log gravity?
Andrade, Tomás; Marolf, Donald
2010-03-01
At the classical level, chiral gravity may be constructed as a consistent truncation of a larger theory called log gravity by requiring that left-moving charges vanish. In turn, log gravity is the limit of topologically massive gravity (TMG) at a special value of the coupling (the chiral point). We study the situation at the level of linearized quantum fields, focussing on a unitary quantization. While the TMG Hilbert space is continuous at the chiral point, the left-moving Virasoro generators become ill-defined and cannot be used to define a chiral truncation. In a sense, the left-moving asymptotic symmetries are spontaneously broken at the chiral point. In contrast, in a non-unitary quantization of TMG, both the Hilbert space and charges are continuous at the chiral point and define a unitary theory of chiral gravity at the linearized level.
Feringa, Bernard
2001-01-01
One of the great mysteries in science is the homochirality (single handedness) of the essential molecules of life. Natural sugars are almost exclusively right-handed; natural amino acids are almost exclusively left-handed. Current life forms could not exist without the uniform chirality of these
Instantons and chiral symmetry breaking
International Nuclear Information System (INIS)
Carneiro, C.E.I.; McDougall, N.A.
1984-01-01
A detailed investigation of chiral symmetry breaking due to instanton dynamics is carried out, within the framework of the dilute gas approximation, for quarks in both the fundamental and adjoint representations of SU(2). The momentum dependence of the dynamical mass is found to be very similar in each representation. (orig.)
Instantons and chiral symmetry breaking
Energy Technology Data Exchange (ETDEWEB)
Carneiro, C.E.I.; McDougall, N.A. (Oxford Univ. (UK). Dept. of Theoretical Physics)
1984-10-22
A detailed investigation of chiral symmetry breaking due to instanton dynamics is carried out, within the framework of the dilute gas approximation, for quarks in both the fundamental and adjoint representations of SU(2). The momentum dependence of the dynamical mass is found to be very similar in each representation.
Status of chiral perturbation theory
International Nuclear Information System (INIS)
Ecker, G.
1996-10-01
A survey is made of semileptonic and nonleptonic kaon decays in the framework of chiral perturbation theory. The emphasis is on what has been done rather than how it was done. The theoretical predictions are compared with available experimental results. (author)
Principles of chiral perturbation theory
International Nuclear Information System (INIS)
Leutwyler, H.
1995-01-01
An elementary discussion of the main concepts used in chiral perturbation theory is given in textbooks and a more detailed picture of the applications may be obtained from the reviews. Concerning the foundations of the method, the literature is comparatively scarce. So, I will concentrate on the basic concepts and explain why the method works. (author)
Chiral symmetry in perturbative QCD
International Nuclear Information System (INIS)
Trueman, T.L.
1979-04-01
The chiral symmetry of quantum chromodynamics with massless quarks is unbroken in perturbation theory. Dimensional regularization is used. The ratio of the vector and axial vector renormalization constante is shown to be independent of the renormalization mass. The general results are explicitly verified to fourth order in g, the QCD coupling constant
Descendants of the Chiral Anomaly
Jackiw, R.
2000-01-01
Chern-Simons terms are well-known descendants of chiral anomalies, when the latter are presented as total derivatives. Here I explain that also Chern-Simons terms, when defined on a 3-manifold, may be expressed as total derivatives.
Topics in three flavor chiral dynamics
Energy Technology Data Exchange (ETDEWEB)
Nissler, Robin
2007-07-01
In this work, we investigate several processes in low-energy hadron physics by combining chiral perturbation theory (ChPT), the effective field theory of quantum chromodynamics (QCD) at low energies, with a unitarization method based on the Bethe-Salpeter equation. Such so-called chiral unitary approaches are capable of describing processes in the three flavor sector of the strong interaction which involve substantial effects from final-state interactions and the excitation of (subthreshold) resonances, a domain where the perturbative framework of ChPT is not applicable. In part I of this work we study {eta} and {eta}' decays which constitute a perfect tool to examine symmetries and symmetry breaking patterns of QCD being incorporated in a model-independent fashion in ChPT. In particular, these decays allow to investigate the breaking of isospin symmetry due to the light quark mass difference m{sub d}-m{sub u} as well as effects of anomalies stemming from the quantum nature of QCD. For these reasons the decays of {eta} and {eta}' have also attracted considerable experimental interest. They are currently under investigation at several facilities including KLOE rate at DA{phi}NE, Crystal Ball at MAMI, WASA-at-COSY, VES at IHEP, and CLEO at CESR. In part II we investigate low-energy meson-baryon scattering in the strangeness S=-1 sector which is dominated by the {lambda}(1405) resonance immediately below the anti KN threshold. The anti KN interaction below threshold is of relevance for the quest of possible deeply bound anti K-nuclear clusters and has recently received an additional tight constraint: the K{sup -}p scattering length as determined from kaonic hydrogen by the KEK and the DEAR collaborations. Apart from successfully describing a large amount of experimental data and furnishing predictions for yet unmeasured quantities, our calculations allow to interrelate different experimental observables providing important consistency tests of experiments. E
Three-dimensional plasmonic chiral tetramers assembled by DNA origami.
Shen, Xibo; Asenjo-Garcia, Ana; Liu, Qing; Jiang, Qiao; García de Abajo, F Javier; Liu, Na; Ding, Baoquan
2013-05-08
Molecular chemistry offers a unique toolkit to draw inspiration for the design of artificial metamolecules. For a long time, optical circular dichroism has been exclusively the terrain of natural chiral molecules, which exhibit optical activity mainly in the UV spectral range, thus greatly hindering their significance for a broad range of applications. Here we demonstrate that circular dichroism can be generated with artificial plasmonic chiral nanostructures composed of the minimum number of spherical gold nanoparticles required for three-dimensional (3D) chirality. We utilize a rigid addressable DNA origami template to precisely organize four nominally identical gold nanoparticles into a three-dimensional asymmetric tetramer. Because of the chiral structural symmetry and the strong plasmonic resonant coupling between the gold nanoparticles, the 3D plasmonic assemblies undergo different interactions with left and right circularly polarized light, leading to pronounced circular dichroism. Our experimental results agree well with theoretical predictions. The simplicity of our structure geometry and, most importantly, the concept of resorting on biology to produce artificial photonic functionalities open a new pathway to designing smart artificial plasmonic nanostructures for large-scale production of optically active metamaterials.
Spectral statistics in chiral-orthogonal disordered systems
International Nuclear Information System (INIS)
Evangelou, S N; Katsanos, D E
2003-01-01
We describe the singularities in the averaged density of states and the corresponding statistics of the energy levels in two- (2D) and three-dimensional (3D) chiral symmetric and time-reversal invariant disordered systems, realized in bipartite lattices with real off-diagonal disorder. For off-diagonal disorder of zero mean, we obtain a singular density of states in 2D which becomes much less pronounced in 3D, while the level-statistics can be described by a semi-Poisson distribution with mostly critical fractal states in 2D and Wigner surmise with mostly delocalized states in 3D. For logarithmic off-diagonal disorder of large strength, we find behaviour indistinguishable from ordinary disorder with strong localization in any dimension but in addition one-dimensional 1/ vertical bar E vertical bar Dyson-like asymptotic spectral singularities. The off-diagonal disorder is also shown to enhance the propagation of two interacting particles similarly to systems with diagonal disorder. Although disordered models with chiral symmetry differ from non-chiral ones due to the presence of spectral singularities, both share the same qualitative localization properties except at the chiral symmetry point E=0 which is critical
Spin-orbit beams for optical chirality measurement
Samlan, C. T.; Suna, Rashmi Ranjan; Naik, Dinesh N.; Viswanathan, Nirmal K.
2018-01-01
Accurate measurement of chirality is essential for the advancement of natural and pharmaceutical sciences. We report here a method to measure chirality using non-separable states of light with geometric phase-gradient in the circular polarization basis, which we refer to as spin-orbit beams. A modified polarization Sagnac interferometer is used to generate spin-orbit beams wherein the spin and orbital angular momentum of the input Gaussian beam are coupled. The out-of-phase interference between counter-propagating Gaussian beams with orthogonal spin states and lateral-shear or/and linear-phase difference between them results in spin-orbit beams with linear and azimuthal phase gradient. The spin-orbit beams interact efficiently with the chiral medium, inducing a measurable change in the center-of-mass of the beam, using the polarization rotation angle and hence the chirality of the medium are accurately calculated. Tunable dynamic range of measurement and flexibility to introduce large values of orbital angular momentum for the spin-orbit beam, to improve the measurement sensitivity, highlight the techniques' versatility.
Theory of Magnetic Edge States in Chiral Graphene Nanoribbons
Capaz, Rodrigo; Yazyev, Oleg; Louie, Steven
2011-03-01
Using a model Hamiltonian approach including electron Coulomb interactions, we systematically investigate the electronic structure and magnetic properties of chiral graphene nanoribbons. We show that the presence of magnetic edge states is an intrinsic feature of any smooth graphene nanoribbons with chiral edges, and discover a number of structure-property relations. Specifically, we describe how the edge-state energy gap, zone-boundary edge-state energy splitting, and magnetic moment per edge length depend on the nanoribbon width and chiral angle. The role of environmental screening effects is also studied. Our results address a recent experimental observation of signatures of magnetic ordering at smooth edges of chiral graphene nanoribbons and provide an avenue towards tuning their properties via the structural and environmental degrees of freedom. This work was supported by National Science Foundation Grant No. DMR10-1006184, the U.S. Department of Energy under Contract No. DE-AC02-05CH11231 and the ONR MURI program. RBC acknowledges financial support from Brazilian agencies CNPq, FAPERJ and INCT-Nanomateriais de Carbono.
Corradini, Roberto; Sforza, Stefano; Tedeschi, Tullia; Marchelli, Rosangela
2007-05-05
The understanding of the interaction of chiral species with DNA or RNA is very important for the development of new tools in biology and of new drugs. Several cases in which chirality is a crucial point in determining the DNA binding mode are reviewed and discussed, with the aim of illustrating how chirality can be considered as a tool for improving the understanding of mechanisms and the effectiveness of nucleic acid recognition. The review is divided into two parts: the former describes examples of chiral species interacting with DNA: intercalators, metal complexes, and groove binders; the latter part is dedicated to chirality in DNA analogs, with discussion of phosphate stereochemistry and chirality of ribose substitutes, in particular of peptide nucleic acids (PNAs) for which a number of works have been published recently dealing with the effect of chirality in DNA recognition. The discussion is intended to show how enantiomeric recognition originates at the molecular level, by exploiting the enormous progresses recently achieved in the field of structural characterization of complexes formed by nucleic acid with their ligands by crystallographic and spectroscopic methods. Examples of application of the DNA binding molecules described and the role of chirality in DNA recognition relevant for biotechnology or medicinal chemistry are reported. (c) 2007 Wiley-Liss, Inc.
A chiral covariant approach to ρρ scattering
Energy Technology Data Exchange (ETDEWEB)
Guelmez, D. [Universitaet Bonn, Helmholtz-Institut fuer Strahlen- und Kernphysik and Bethe Center for Theoretical Physics, Bonn (Germany); Meissner, U.G. [Universitaet Bonn, Helmholtz-Institut fuer Strahlen- und Kernphysik and Bethe Center for Theoretical Physics, Bonn (Germany); Institut fuer Kernphysik and Juelich Center for Hadron Physics, Institute for Advanced Simulation, Juelich (Germany); Oller, J.A. [Universidad de Murcia, Departamento de Fisica, Murcia (Spain)
2017-07-15
We analyze vector meson-vector meson scattering in a unitarized chiral theory based on a chiral covariant framework restricted to ρρ intermediate states. We show that a pole assigned to the scalar meson f{sub 0}(1370) can be dynamically generated from the ρρ interaction, while this is not the case for the tensor meson f{sub 2}(1270) as found in earlier work. We show that the generation of the tensor state is untenable due to the extreme non-relativistic kinematics used before. We further consider the effects arising from the coupling of channels with different orbital angular momenta which are also important. We suggest to use the formalism outlined here to obtain more reliable results for the dynamical generation of resonances in the vector-vector interaction. (orig.)
Reduction of the chiral order parameter by a nuclear medium
International Nuclear Information System (INIS)
Kienle, P.; Yamazaki, Toshimizu
2001-01-01
We propose a model independent procedure to deduce from the 1s-binding energy of heavy, neutron rich pionic atoms, the isovector scattering length b 1 of the pion nucleus interaction. It is related to the pion decay constant f π , the order parameter of spontaneous chiral symmetry breaking and thus to the value of the chiral quark condensate. Based on the results with pionic 205 Pb, we find with the assertion that only the isovector part of the pion-nucleus interaction be modified by a QCD effect, a reduction of the quark condensate by 30% in a 205 Pb nucleus. Forthcoming experiments to measure pionic 1s-binding energies in Sn-isotopes, including isotope shifts, will yield decisive information on the quark condensate without assertion. (orig.)
Timoshenko beam model for chiral materials
Ma, T. Y.; Wang, Y. N.; Yuan, L.; Wang, J. S.; Qin, Q. H.
2018-06-01
Natural and artificial chiral materials such as deoxyribonucleic acid (DNA), chromatin fibers, flagellar filaments, chiral nanotubes, and chiral lattice materials widely exist. Due to the chirality of intricately helical or twisted microstructures, such materials hold great promise for use in diverse applications in smart sensors and actuators, force probes in biomedical engineering, structural elements for absorption of microwaves and elastic waves, etc. In this paper, a Timoshenko beam model for chiral materials is developed based on noncentrosymmetric micropolar elasticity theory. The governing equations and boundary conditions for a chiral beam problem are derived using the variational method and Hamilton's principle. The static bending and free vibration problem of a chiral beam are investigated using the proposed model. It is found that chirality can significantly affect the mechanical behavior of beams, making materials more flexible compared with nonchiral counterparts, inducing coupled twisting deformation, relatively larger deflection, and lower natural frequency. This study is helpful not only for understanding the mechanical behavior of chiral materials such as DNA and chromatin fibers and characterizing their mechanical properties, but also for the design of hierarchically structured chiral materials.
Energy Technology Data Exchange (ETDEWEB)
Fu, Qifeng, E-mail: fuqifeng1990@163.com [Department of Medicinal Chemistry, Southwest Medical University, Luzhou 646000 (China); Zhang, Kailian; Gao, Die; Wang, Lujun [Department of Medicinal Chemistry, Southwest Medical University, Luzhou 646000 (China); Yang, Fengqing; Liu, Yao [School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030 (China); Xia, Zhining, E-mail: tcm_anal_cqu@163.com [Innovative Drug Research Centre and School of Pharmaceutical Sciences, Chongqing University, Chongqing 400030 (China); School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030 (China)
2017-05-29
Bacteria, the microorganism with intrinsic chirality, have numerous fascinating chiral phenomena such as various chirality-triggered biological processes and behaviors. Herein, bacteria were firstly explored as novel chiral stationary phases in open-tubular capillary electrochromatography (OT-CEC) for enantioseparation of fluoroquinolone enantiomers and simultaneous separation of six fluoroquinolone antibiotics. The model strain, i.e. non-pathogenic Escherichia coli (E. coli) DH5α, was adhered onto the inner surface of positively charged polyethyleneimine (PEI) modified capillaries based on the bacterial adhesion characteristics and strong electrostatic interaction. The morphology and thickness of the bacteria adhesive coatings in the capillary were characterized by field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM). Baseline separation of ofloxacin and partial separation of lomefloxacin enantiomers could be achieved by the E. coli coated columns. The preparation parameters including the coating time and concentration of bacteria that affecting the chiral resolution were intensively investigated. The electrophoretic parameters, including pH, buffer concentration and applied voltage, were also optimized. The developed method was validated (linearity, LOD, LOQ, intra-day, inter-day and column-to-column repeatability and recovery) and successfully utilized for the quantitative analysis of ofloxacin enantiomers in the ofloxacin tablets. Moreover, only a slight decrease in the separation efficiency was observed after 90 consecutive runs on the E. coli@capillary. These results demonstrated that bacteria are promising stationary phases for chiral separation in CEC. - Highlights: • Bacteria were firstly introduced in OT-CEC as a chiral stationary phase for chiral separation. • Enantioseparation of ofloxacin enantiomers was achieved on E. coli coated open tubular capillary column. • Bacterial stationary phases may be used to
Chiral phase transition in the soft-wall model of AdS/QCD
International Nuclear Information System (INIS)
Chelabi, Kaddour; Fang, Zhen; Huang, Mei; Li, Danning; Wu, Yue-Liang
2016-01-01
We investigate the chiral phase transition in the soft-wall model of AdS/QCD at zero chemical potential for two-flavor and three-flavor cases, respectively. We show that there is no spontaneous chiral symmetry breaking in the original soft-wall model. After detailed analysis, we find that in order to realize chiral symmetry breaking and restoration, both profiles for the scalar potential and the dilaton field are essential. The scalar potential determines the possible solution structure of the chiral condensate, except the mass term, it takes another quartic term for the two-flavor case, and for the three-flavor case, one has to take into account an extra cubic term due to the t’Hooft determinant interaction. The profile of the dilaton field reflects the gluodynamics, which is negative at a certain ultraviolet scale and approaches positive quadratic behavior at far infrared region. With this set-up, the spontaneous chiral symmetry breaking in the vacuum and its restoration at finite temperature can be realized perfectly. In the two-flavor case, it gives a second order chiral phase transition in the chiral limit, while the transition turns to be a crossover for any finite quark mass. In the case of three-flavor, the phase transition becomes a first order one in the chiral limit, while above sufficient large quark mass it turns to be a crossover again. This scenario agrees exactly with the current understanding on chiral phase transition from lattice QCD and other effective model studies.
International Nuclear Information System (INIS)
Fu, Qifeng; Zhang, Kailian; Gao, Die; Wang, Lujun; Yang, Fengqing; Liu, Yao; Xia, Zhining
2017-01-01
Bacteria, the microorganism with intrinsic chirality, have numerous fascinating chiral phenomena such as various chirality-triggered biological processes and behaviors. Herein, bacteria were firstly explored as novel chiral stationary phases in open-tubular capillary electrochromatography (OT-CEC) for enantioseparation of fluoroquinolone enantiomers and simultaneous separation of six fluoroquinolone antibiotics. The model strain, i.e. non-pathogenic Escherichia coli (E. coli) DH5α, was adhered onto the inner surface of positively charged polyethyleneimine (PEI) modified capillaries based on the bacterial adhesion characteristics and strong electrostatic interaction. The morphology and thickness of the bacteria adhesive coatings in the capillary were characterized by field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM). Baseline separation of ofloxacin and partial separation of lomefloxacin enantiomers could be achieved by the E. coli coated columns. The preparation parameters including the coating time and concentration of bacteria that affecting the chiral resolution were intensively investigated. The electrophoretic parameters, including pH, buffer concentration and applied voltage, were also optimized. The developed method was validated (linearity, LOD, LOQ, intra-day, inter-day and column-to-column repeatability and recovery) and successfully utilized for the quantitative analysis of ofloxacin enantiomers in the ofloxacin tablets. Moreover, only a slight decrease in the separation efficiency was observed after 90 consecutive runs on the E. coli@capillary. These results demonstrated that bacteria are promising stationary phases for chiral separation in CEC. - Highlights: • Bacteria were firstly introduced in OT-CEC as a chiral stationary phase for chiral separation. • Enantioseparation of ofloxacin enantiomers was achieved on E. coli coated open tubular capillary column. • Bacterial stationary phases may be used to
Highly efficient induction of chirality in intramolecular
Cossio; Arrieta; Lecea; Alajarin; Vidal; Tovar
2000-06-16
Highly stereocontrolled, intramolecular [2 + 2] cycloadditions between ketenimines and imines leading to 1,2-dihydroazeto[2, 1-b]quinazolines have been achieved. The source of stereocontrol is a chiral carbon atom adjacent either to the iminic carbon or nitrogen atom. In the first case, the stereocontrol stems from the preference for the axial conformer in the first transition structure. In the second case, the origin of the stereocontrol lies on the two-electron stabilizing interaction between the C-C bond being formed and the sigma orbital corresponding to the polar C-X bond, X being an electronegative atom. These models can be extended to other related systems for predicting the stereochemical outcome in this intramolecular reaction.
Chiral asymmetry in nuclear beta decay
International Nuclear Information System (INIS)
van Klinken, J.
1987-01-01
Nuclear β decay can be instrumental to electroweak unification studies by observation of the degree of longitudinal polarization of β rays from allowed Fermi and from allowed Gamow-Teller decays. Possible deviations from maximality of this polarization bear on a fundamental question: is there a manifest left-right symmetry, indicated by right-handed currents and V+A admixture to a dominant V-A interaction? Discussed are absolute β - and relative β + measurements. The β - measurements are of long-standing age; the β + measurements are recent and not yet fully analyzed. A striking consequence of the polarization may be an intimate relation with the origin of life: can it be that the chirality of biomolecules is determined by the longitudinal polarization of β rays? 20 references, 9 figures
Chiral solitons in spinor polariton rings
Zezyulin, D. A.; Gulevich, D. R.; Skryabin, D. V.; Shelykh, I. A.
2018-04-01
We consider theoretically one-dimensional polariton ring accounting for both longitudinal-transverse (TE-TM) and Zeeman splittings of spinor polariton states and spin-dependent polariton-polariton interactions. We present a class of solutions in the form of the localized defects rotating with constant angular velocity and analyze their properties for realistic values of the parameters of the system. We show that the effects of the geometric phase arising from the interplay between the external magnetic field and the TE-TM splitting introduce chirality in the system and make solitons propagating in clockwise and anticlockwise directions nonequivalent. This can be interpreted as a solitonic analog of the Aharonov-Bohm effect.
Kinetics of the chiral phase transition
Energy Technology Data Exchange (ETDEWEB)
Hees, Hendrik van [Johann-Wolfgang-Goethe-Universitaet Frankfurt, Institut fuer Theoretische Physik, Frankfurt (Germany); Frankfurt Institute for Advanced Studies (FIAS), Frankfurt (Germany); Wesp, Christian; Meistrenko, Alex; Greiner, Carsten [Johann-Wolfgang-Goethe-Universitaet Frankfurt, Institut fuer Theoretische Physik, Frankfurt (Germany)
2016-07-01
We simulate the kinetics of the chiral phase transition in hot and dense strongly interacting matter within a novel kinetic-theory approach. Employing an effective linear σ model for quarks, σ mesons, and pions we treat the quarks within a test-particle ansatz for solving the Boltzmann transport equation and the mesons in terms of classical fields. The decay-recombination processes like σ <-> anti q+q are treated using a kind of wave-particle dualism using the exact conservation of energy and momentum. After demonstrating the correct thermodynamic limit for particles and fields in a ''box calculation'' we apply the simulation to the dynamics of an expanding fireball similar to the medium created in ultrarelativistic heavy-ion collisions.
Evolved chiral Hamiltonians at the three-body level and beyond
Energy Technology Data Exchange (ETDEWEB)
Calci, Angelo
2014-07-14
Based on the fundamental symmetries of QCD, chiral effective field theory (EFT) provides two- (NN), three- (3N), four- (4N), and many-nucleon interactions in a consistent and systematic scheme. Recent developments to construct chiral NN+3N interactions at different chiral orders and regularizations enable exciting nuclear structure investigations as well as a quantification of the fundamental uncertainties resulting from the chiral expansion and regularization. We present the complete toolchain to employ the present and future chiral NN, 3N, and 4N interactions in nuclear structure calculations and emphasize technical developments in the three- and four-body space, such as the similarity renormalization group (SRG), the frequency conversion, and the transformation to the JT-coupled scheme. We study the predictions of the chiral NN+3N interactions in ab initio nuclear structure calculations with the importance-truncated no-core shell model and coupled-cluster approach. We demonstrate that the inclusion of chiral 3N forces improves the overall agreement with experiment for excitation energies of p-shell nuclei and it qualitatively reproduces the systematics of nuclear binding energies throughout the nuclear chart up to heavy tin isotopes. In this context it is necessary to introduce truncations in the three-body model space and we carefully analyze their impact and confirm the reliability of the reported results. The SRG evolution induces many-nucleon forces that generally cannot be included in the calculations and constitute a major limitation for the applicability of SRG-evolved chiral forces. We study the origin and effect of the induced many-nucleon forces and propose a modification of the interaction, which suppresses the induced beyond-3N forces. This enables applications of the chiral interactions far beyond the mid-p shell. Furthermore, we test alternative formulations of SRG generators aiming to prevent the induced many-body forces from the outset. The
Fermion masses in potential models of chiral symmetry breaking
International Nuclear Information System (INIS)
Jaroszewicz, T.
1983-01-01
A class of models of spontaneous chiral symmetry breaking is considered, based on the Hamiltonian with an instantaneous potential interaction of fermions. An explicit mass term mΨ-barΨ is included and the physical meaning of the mass parameter is discussed. It is shown that if the Hamiltonian is normal-ordered (i.e. self-energy omitted), then the mass m introduced in the Hamiltonian is not the current mass appearing in the current algebra relations. (author)
Tetraquarks in a chiral constituent-quark model
International Nuclear Information System (INIS)
Vijande, J.; Fernandez, F.; Valcarce, A.; Silvestre-Brac, B.
2004-01-01
We analyze the possibility of heavy-light tetraquark bound states by means of a chiral constituent-quark model. The study is done in a variational approach. Special attention is paid to the contribution given by the different terms of the interacting potential and also to the role played by the different color channels. We find a stable state for both qq anti c anti c and qq anti b anti b configurations. Possible decay modes of these structures are analyzed. (orig.)
Tetraquarks in a chiral constituent-quark model
Energy Technology Data Exchange (ETDEWEB)
Vijande, J.; Fernandez, F.; Valcarce, A. [Grupo de Fisica Nuclear, Universidad de Salamanca, E-37008, Salamanca (Spain); Silvestre-Brac, B. [Institut des Sciences Nucleaires, 53 Avenue des Martyrs, F-38026, Grenoble Cedex (France)
2004-03-01
We analyze the possibility of heavy-light tetraquark bound states by means of a chiral constituent-quark model. The study is done in a variational approach. Special attention is paid to the contribution given by the different terms of the interacting potential and also to the role played by the different color channels. We find a stable state for both qq anti c anti c and qq anti b anti b configurations. Possible decay modes of these structures are analyzed. (orig.)
Precision spectroscopy of pionic atoms and chiral symmetry in nuclei
International Nuclear Information System (INIS)
Itahashi, Kenta; Ahn, DeukSoon; Berg, Georg P.A.; Dozono, Masanori; Etoh, Daijiro; Fujioka, Hiroyuki; Fukuda, Naoki; Fukunishi, Nobuhisa; Geissel, Hans; Haettner, Emma; Hashimoto, Tadashi; Hayano, Ryugo S.; Hirenzaki, Satoru; Horii, Hiroshi; Ikeno, Natsumi; Inabe, Naoto; Iwasaki, Masahiko; Kameda, Daisuke; Kawase, Shouichiro; Kisamori, Keiichi; Kiyokawa, Yu; Kubo, Toshiyuki; Kusaka, Kensuke; Matsushita, Masafumi; Michimasa, Shin’ichiro; Mishima, Go; Miya, Hiroyuki; Murai, Daichi; Nagahiro, Hideko; Nishi, Takahiro; Ota, Shinsuke; Sakamoto, Naruhiko; Sekiguchi, Kimiko; Suzuki, Hiroshi; Suzuki, Ken; Takaki, Motonobu; Takeda, Hiroyuki; Tanaka, Yoshiki K.; Uesaka, Tomohiro; Wada, Yasumori; Watanabe, Yuni N.; Weick, Helmut; Yamakami, Hiroki; Yanagisawa, Yoshiyuki; Yoshida, Koichi
2016-01-01
We conduct an experimental project to make spectroscopy of deeply bound pionic atoms systematically over wide range of nuclei. We aim at studying the strong interaction in the low energy region, which has close connection to spontaneous chiral symmetry breaking and its partial restoration in nuclear matter. First experimental results show improved spectral resolution and much better statistical sensitivity than previous experiments. Present status of the experiment is reported.
International Nuclear Information System (INIS)
Belinsky, Moisey I.
2009-01-01
The spin chirality and spin structure of the Cu 3 and V 3 nanomagnets with the Dzialoshinsky-Moriya (DM) exchange interaction are analyzed. The correlations between the vector κ and the scalar χ chirality are obtained. The DM interaction forms the spin chirality which is equal to zero in the Heisenberg clusters. The dependences of the spin chirality on magnetic field and deformations are calculated. The cluster distortions reduce the spin chirality. The vector chirality is reduced partially and the scalar chirality vanishes in the transverse magnetic field. In the isosceles clusters, the DM exchange and distortions determine the sign and degree of the spin chirality κ. The correlations between the chirality parameters κ n and the intensities of the EPR and INS transitions are obtained. The vector chirality κ n describes the spin chirality of the Cu 3 and V 3 nanomagnets, the scalar chirality describes the pseudoorbital moment of the DM cluster. It is shown that in the consideration of the DM exchange, the spin states DM mixing and tunneling gaps at level crossing fields depend on the coordinate system of the DM model. The calculations in the DM exchange models in the right-handed and left-handed frame show opposite magnetic behavior at the level crossing field and allow to explain the opposite schemes of the tunneling gaps and levels crossing, which have been obtained in different treatments. The results of the DM model in the right-handed frame are consistent with the results of the group-theoretical analysis, whereas the results in the left-handed frame are inconsistent with that. The correlations between the spin chirality of the ground state and tunneling gaps at the level crossing field are obtained for the equilateral and isosceles nanoclusters.
Inexpensive chirality on the lattice
International Nuclear Information System (INIS)
Kamleh, W.; Williams, A.G.; Adams, D.
2000-01-01
Full text: Implementing lattice fermions that resemble as closely as possible continuum fermions is one of the main goals of the theoretical physics community. Aside from a lack of infinitely powerful computers, one of the main impediments to this is the Nielsen-Ninomiya No-Go theorem for chirality on the lattice. One of the consequences of this theorem is that exact chiral symmetry and a lack of fermion doublers cannot be simultaneously satisfied for fermions on the lattice. In the commonly used Wilson fermion formulation, chiral symmetry is explicitly sacrificed on the lattice to avoid fermion doubling. Recently, an alternative has come forward, namely, the Ginsparg-Wilson relation and one of its solutions, the Overlap fermion. The Ginsparg-Wilson relation is a statement of lattice-deformed chirality. The Overlap-Dirac operator is a member of the family of solutions of the Ginsparg-Wilson relation. In recent times, Overlap fermions have been of great interest to the community due to their excellent chiral properties. However, they are significantly more expensive to implement than Wilson fermions. This expense is primarily due to the fact that the Overlap implementation requires an evaluation of the sign function for the Wilson-Dirac operator. The sign function is approximated by a high order rational polynomial function, but this approximation is poor close to the origin. The less near-zero modes that the Wilson- Dirac operator possesses, the cheaper the Overlap operator will be to implement. A means of improving the eigenvalue properties of the Wilson-Dirac operator by the addition of a so-called 'Clover' term is put forward. Numerical results are given that demonstrate this improvement. The Nielsen-Ninomiya no-go theorem and chirality on the lattice are reviewed. The general form of solutions of the Ginsparg-Wilson relation are given, and the Overlap solution is discussed. Properties of the Overlap-Dirac operator are given, including locality and analytic
Chiral heat wave and mixing of magnetic, vortical and heat waves in chiral media
International Nuclear Information System (INIS)
Chernodub, M.N.
2016-01-01
We show that a hot rotating fluid of relativistic chiral fermions possesses a new gapless collective mode associated with coherent propagation of energy density and chiral density waves along the axis of rotation. This mode, which we call the Chiral Heat Wave, emerges due to a mixed gauge-gravitational anomaly. At finite density the Chiral Heat Wave couples to the Chiral Vortical Wave while in the presence of an external magnetic field it mixes with the Chiral Magnetic Wave. The coupling of the Chiral Magnetic and Chiral Vortical Waves is also demonstrated. We find that the coupled waves — which are coherent fluctuations of the vector, axial and energy currents — have generally different velocities compared to the velocities of the individual waves.
Static and dynamical anomalies caused by chiral soliton lattice in molecular-based chiral magnets
International Nuclear Information System (INIS)
Kishine, Jun-ichiro; Inoue, Katsuya; Kikuchi, Koichi
2007-01-01
Interplay of crystallographic chirality and magnetic chirality has been of great interest in both chemist's and physicist's viewpoints. Crystals belonging to chiral space groups are eligible to stabilize macroscopic chiral magnetic order. This class of magnetic order is described by the chiral XY model, where the transverse magnetic field perpendicular to the chiral axis causes the chiral soliton lattice (CSL) formation. As a clear evidence of the chiral magnetic order, the temperature dependence of the transverse magnetization exhibits sharp cusp just below the mean field ferrimagnetic transition temperature, indicating the formation of the CSL. In addition to the static anomaly, we expect the CSL formation also causes dynamical anomalies such as induction of the spin supercurrent
Novel Chiral Magnetic Domain Wall Structure in Fe/Ni/Cu(001) Films
Chen, G.; Zhu, J.; Quesada, A.; Li, J.; N'Diaye, A. T.; Huo, Y.; Ma, T. P.; Chen, Y.; Kwon, H. Y.; Won, C.; Qiu, Z. Q.; Schmid, A. K.; Wu, Y. Z.
2013-04-01
Using spin-polarized low energy electron microscopy, we discovered a new type of domain wall structure in perpendicularly magnetized Fe/Ni bilayers grown epitaxially on Cu(100). Specifically, we observed unexpected Néel-type walls with fixed chirality in the magnetic stripe phase. Furthermore, we find that the chirality of the domain walls is determined by the film growth order with the chirality being right handed in Fe/Ni bilayers and left handed in Ni/Fe bilayers, suggesting that the underlying mechanism is the Dzyaloshinskii-Moriya interaction at the film interfaces. Our observations may open a new route to control chiral spin structures using interfacial engineering in transition metal heterostructures.
International Nuclear Information System (INIS)
Li, Xiu-Hua; Zhang, Qi; Hu, Ping
2014-01-01
A multifunctional homochiral coordination polymer, [Co(H 2 O)(BDC)(4,4′-BPY)]∙3H 2 O (1) (H 2 BDC=1,2-benzenedicarboxylate and 4,4′-BPY=4,4′-bipyridine), has been successfully isolated from Co(II) ions and mixed ligands (1,2-benzenedicarboxylate and 4,4′-bipyridine). Complex 1, which exhibits spontaneous chirality resolution and weak ferromagnetism, is built by chiral helices interconnected via end-to-end 4,4′-BPY bridges into a two-dimensional (2D) layer structure. - Graphical abstract: A 2D cobalt coordination polymer compound showing spontaneous chirality resolution and weak ferromagnetism. - Highlights: • A new 2D cobalt mix-ligand coordination polymer complex has been synthesized. • The cobalt coordination polymer complex shows spontaneous chirality resolution in solid state. • The cobalt coordination polymer complex displays dominant and weak intrachain ferromagnetic interactions
QCD and the chiral critical point
International Nuclear Information System (INIS)
Gavin, S.; Gocksch, A.; Pisarski, R.D.
1994-01-01
As an extension of QCD, consider a theory with ''2+1'' flavors, where the current quark masses are held in a fixed ratio as the overall scale of the quark masses is varied. At nonzero temperature and baryon density it is expected that in the chiral limit the chiral phase transition is of first order. Increasing the quark mass from zero, the chiral transition becomes more weakly first order, and can end in a chiral critical point. We show that the only massless field at the chiral critical point is a σ meson, with the universality class that of the Ising model. Present day lattice simulations indicate that QCD is (relatively) near to the chiral critical point
Asymmetric synthesis using chiral-encoded metal
Yutthalekha, Thittaya; Wattanakit, Chularat; Lapeyre, Veronique; Nokbin, Somkiat; Warakulwit, Chompunuch; Limtrakul, Jumras; Kuhn, Alexander
2016-08-01
The synthesis of chiral compounds is of crucial importance in many areas of society and science, including medicine, biology, chemistry, biotechnology and agriculture. Thus, there is a fundamental interest in developing new approaches for the selective production of enantiomers. Here we report the use of mesoporous metal structures with encoded geometric chiral information for inducing asymmetry in the electrochemical synthesis of mandelic acid as a model molecule. The chiral-encoded mesoporous metal, obtained by the electrochemical reduction of platinum salts in the presence of a liquid crystal phase and the chiral template molecule, perfectly retains the chiral information after removal of the template. Starting from a prochiral compound we demonstrate enantiomeric excess of the (R)-enantiomer when using (R)-imprinted electrodes and vice versa for the (S)-imprinted ones. Moreover, changing the amount of chiral cavities in the material allows tuning the enantioselectivity.
Nucleon parton distributions in chiral perturbation theory
International Nuclear Information System (INIS)
Moiseeva, Alena
2013-01-01
Properties of the chiral expansion of nucleon light-cone operators have been studied. In the framework of the chiral perturbation theory we have demonstrated that convergency of the chiral expansion of nucleon parton distributions strongly depends on the value of the variable x. Three regions in x with essentially different analytical properties of the resulting chiral expansion for parton distributions were found. For each of the regions we have elaborated special power counting rules corresponding to the partial resummation of the chiral series. The nonlocal effective operators for the vector and the axial nucleon parton distributions have been constructed at the zeroth and the first chiral order. Using the derived nonlocal operators and the derived power counting rules we have obtained the second order expressions for the nucleon GPDs H(x,ξ,Δ 2 ), H(x,ξ,Δ 2 ),E(x,ξ,Δ 2 ) valid in the region x>or similar a 2 χ .
Bootstrapping N=2 chiral correlators
Lemos, Madalena; Liendo, Pedro
2016-01-01
We apply the numerical bootstrap program to chiral operators in four-dimensional N=2 SCFTs. In the first part of this work we study four-point functions in which all fields have the same conformal dimension. We give special emphasis to bootstrapping a specific theory: the simplest Argyres-Douglas fixed point with no flavor symmetry. In the second part we generalize our setup and consider correlators of fields with unequal dimension. This is an example of a mixed correlator and allows us to probe new regions in the parameter space of N=2 SCFTs. In particular, our results put constraints on relations in the Coulomb branch chiral ring and on the curvature of the Zamolodchikov metric.
Bootstrapping N=2 chiral correlators
Energy Technology Data Exchange (ETDEWEB)
Lemos, Madalena [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Liendo, Pedro [Humboldt-Univ. Berlin (Germany). IMIP
2015-12-15
We apply the numerical bootstrap program to chiral operators in four-dimensional N=2 SCFTs. In the first part of this work we study four-point functions in which all fields have the same conformal dimension. We give special emphasis to bootstrapping a specific theory: the simplest Argyres-Douglas fixed point with no flavor symmetry. In the second part we generalize our setup and consider correlators of fields with unequal dimension. This is an example of a mixed correlator and allows us to probe new regions in the parameter space of N=2 SCFTs. In particular, our results put constraints on relations in the Coulomb branch chiral ring and on the curvature of the Zamolodchikov metric.
Bootstrapping N=2 chiral correlators
Energy Technology Data Exchange (ETDEWEB)
Lemos, Madalena [DESY Hamburg, Theory Group,Notkestrasse 85, D-22607 Hamburg (Germany); Liendo, Pedro [IMIP, Humboldt-Universität zu Berlin, IRIS Adlershof,Zum Großen Windkanal 6, 12489 Berlin (Germany)
2016-01-07
We apply the numerical bootstrap program to chiral operators in four-dimensional N=2 SCFTs. In the first part of this work we study four-point functions in which all fields have the same conformal dimension. We give special emphasis to bootstrapping a specific theory: the simplest Argyres-Douglas fixed point with no flavor symmetry. In the second part we generalize our setup and consider correlators of fields with unequal dimension. This is an example of a mixed correlator and allows us to probe new regions in the parameter space of N=2 SCFTs. In particular, our results put constraints on relations in the Coulomb branch chiral ring and on the curvature of the Zamolodchikov metric.
Chiral Tunnelling in Twisted Graphene Bilayer
He, Wen-Yu; Chu, Zhao-Dong; He, Lin
2013-01-01
The perfect transmission in graphene monolayer and the perfect reflection in Bernal graphene bilayer for electrons incident in the normal direction of a potential barrier are viewed as two incarnations of the Klein paradox. Here we show a new and unique incarnation of the Klein paradox. Owing to the different chiralities of the quasiparticles involved, the chiral fermions in twisted graphene bilayer shows adjustable probability of chiral tunnelling for normal incidence: they can be changed fr...
Supersymmetry and the chiral Schwinger model
International Nuclear Information System (INIS)
Amorim, R.; Das, A.
1998-01-01
We have constructed the N= (1) /(2) supersymmetric general Abelian model with asymmetric chiral couplings. This leads to a N= (1) /(2) supersymmetrization of the Schwinger model. We show that the supersymmetric general model is plagued with problems of infrared divergence. Only the supersymmetric chiral Schwinger model is free from such problems and is dynamically equivalent to the chiral Schwinger model because of the peculiar structure of the N= (1) /(2) multiplets. copyright 1998 The American Physical Society
Probing chirality with a femtosecond reaction microscope
Directory of Open Access Journals (Sweden)
Janssen M. H. M.
2013-03-01
Full Text Available Detection of molecular chirality with high sensitivity and selectivity is important for many analytical and practical applications. Photoionization has emerged as a very sensitive probe of chirality in molecules. We show here that a table top setup with a femtosecond laser and a single imaging detector for both photoelectrons and photoions enables detection of chirality up to 3 orders of magnitude better than the existing conventional absorption based techniques.
A spectral route to determining chirality
DEFF Research Database (Denmark)
Pedersen, Jesper Goor; Mortensen, Asger
2009-01-01
We show how one-dimensional structured media can be used to measure chirality, via the spectral shift of the photonic band gap edges. Analytically, we show that a chiral contrast can, in some cases, be mapped unto an index contrast, thereby greatly simplifying the analysis of such structures. Using...... this mapping, we derive a first-order shift of the band gap edges with chirality. Potentially, this effect could be used for measuring enantiomeric excess....
Higher derivative regularization and chiral anomaly
International Nuclear Information System (INIS)
Nagahama, Yoshinori.
1985-02-01
A higher derivative regularization which automatically leads to the consistent chiral anomaly is analyzed in detail. It explicitly breaks all the local gauge symmetry but preserves global chiral symmetry and leads to the chirally symmetric consistent anomaly. This regularization thus clarifies the physics content contained in the consistent anomaly. We also briefly comment on the application of this higher derivative regularization to massless QED. (author)
Chiral anomaly, bosonization and fractional charge
International Nuclear Information System (INIS)
Mignaco, J.A.; Rego Monteiro, M.A. do.
1984-01-01
A method to evaluate the Jacobian of chiral rotations, regulating determinants through the proper time method and using Seeley's asymptotic expansion is presented. With this method the chiral anomaly ofr ν=4,6 dimensions is computed easily, bosonization of some massless two-dimensional models is discussed and the problem of charge fractionization is handled. Besides, the general validity of Fujikawa's approach to regulate the Jacobian of chiral rotations with non-hermitean operators is commented. (Author) [pt
The chirality operators for Heisenberg spin systems
International Nuclear Information System (INIS)
Subrahmanyam, V.
1994-01-01
The ground state of closed Heisenberg spin chains with an odd number of sites has a chiral degeneracy, in addition to a two-fold Kramers degeneracy. A non-zero chirality implies that the spins are not coplanar, and is a measure of handedness. The chirality operator, which can be treated as a spin-1/2 operator, is explicitly constructed in terms of the spin operators, and is given as commutator of permutation operators. (author). 3 refs
Chiral anomaly, bosonization, and fractional charge
International Nuclear Information System (INIS)
Mignaco, J.A.; Monteiro, M.A.R.
1985-01-01
We present a method to evaluate the Jacobian of chiral rotations, regulating determinants through the proper-time method and using Seeley's asymptotic expansion. With this method we compute easily the chiral anomaly for ν = 4,6 dimensions, discuss bosonization of some massless two-dimensional models, and handle the problem of charge fractionization. In addition, we comment on the general validity of Fujikawa's approach to regulate the Jacobian of chiral rotations with non-Hermitian operators
International Nuclear Information System (INIS)
Liriano, Melissa L.; Lewis, Emily A.; Murphy, Colin J.; Lawton, Timothy J.; Marcinkowski, Matthew D.; Therrien, Andrew J.; Sykes, E. Charles H.; Carrasco, Javier; Michaelides, Angelos
2016-01-01
The assembly of complex structures in nature is driven by an interplay between several intermolecular interactions, from strong covalent bonds to weaker dispersion forces. Understanding and ultimately controlling the self-assembly of materials requires extensive study of how these forces drive local nanoscale interactions and how larger structures evolve. Surface-based self-assembly is particularly amenable to modeling and measuring these interactions in well-defined systems. This study focuses on 2-butanol, the simplest aliphatic chiral alcohol. 2-butanol has recently been shown to have interesting properties as a chiral modifier of surface chemistry; however, its mode of action is not fully understood and a microscopic understanding of the role non-covalent interactions play in its adsorption and assembly on surfaces is lacking. In order to probe its surface properties, we employed high-resolution scanning tunneling microscopy and density functional theory (DFT) simulations. We found a surprisingly rich degree of enantiospecific adsorption, association, chiral cluster growth and ultimately long range, highly ordered chiral templating. Firstly, the chiral molecules acquire a second chiral center when adsorbed to the surface via dative bonding of one of the oxygen atom lone pairs. This interaction is controlled via the molecule’s intrinsic chiral center leading to monomers of like chirality, at both chiral centers, adsorbed on the surface. The monomers then associate into tetramers via a cyclical network of hydrogen bonds with an opposite chirality at the oxygen atom. The evolution of these square units is surprising given that the underlying surface has a hexagonal symmetry. Our DFT calculations, however, reveal that the tetramers are stable entities that are able to associate with each other by weaker van der Waals interactions and tessellate in an extended square network. This network of homochiral square pores grows to cover the whole Au(111) surface. Our
Energy Technology Data Exchange (ETDEWEB)
Liriano, Melissa L.; Lewis, Emily A.; Murphy, Colin J.; Lawton, Timothy J.; Marcinkowski, Matthew D.; Therrien, Andrew J.; Sykes, E. Charles H., E-mail: charles.sykes@tufts.edu [Department of Chemistry, Tufts University, Medford, Massachusetts 02155 (United States); Carrasco, Javier [CIC Energigune, Albert Einstein 48, 01510 Miñano, Álava (Spain); Michaelides, Angelos [Thomas Young Centre, London Centre for Nanotechnology and Department of Physics and Astronomy, University College London, London WC1E 6BT (United Kingdom)
2016-03-07
The assembly of complex structures in nature is driven by an interplay between several intermolecular interactions, from strong covalent bonds to weaker dispersion forces. Understanding and ultimately controlling the self-assembly of materials requires extensive study of how these forces drive local nanoscale interactions and how larger structures evolve. Surface-based self-assembly is particularly amenable to modeling and measuring these interactions in well-defined systems. This study focuses on 2-butanol, the simplest aliphatic chiral alcohol. 2-butanol has recently been shown to have interesting properties as a chiral modifier of surface chemistry; however, its mode of action is not fully understood and a microscopic understanding of the role non-covalent interactions play in its adsorption and assembly on surfaces is lacking. In order to probe its surface properties, we employed high-resolution scanning tunneling microscopy and density functional theory (DFT) simulations. We found a surprisingly rich degree of enantiospecific adsorption, association, chiral cluster growth and ultimately long range, highly ordered chiral templating. Firstly, the chiral molecules acquire a second chiral center when adsorbed to the surface via dative bonding of one of the oxygen atom lone pairs. This interaction is controlled via the molecule’s intrinsic chiral center leading to monomers of like chirality, at both chiral centers, adsorbed on the surface. The monomers then associate into tetramers via a cyclical network of hydrogen bonds with an opposite chirality at the oxygen atom. The evolution of these square units is surprising given that the underlying surface has a hexagonal symmetry. Our DFT calculations, however, reveal that the tetramers are stable entities that are able to associate with each other by weaker van der Waals interactions and tessellate in an extended square network. This network of homochiral square pores grows to cover the whole Au(111) surface. Our
Chen, Xingwu; Wang, Ling; Chen, Yinjie; Li, Chenyue; Hou, Guoyan; Liu, Xin; Zhang, Xiaoguang; He, Wanli; Yang, Huai
2014-01-21
A chiral nematic liquid crystal-photopolymerizable monomer-chiral azobenzene compound composite was prepared and then polymerized under UV irradiation. The reflection wavelength of the composite can be extended to cover the 1000-2400 nm range and also be adjusted to the visible light region by controlling the concentration of chiral compounds.
A gauge-invariant chiral unitary framework for kaon photo- and electroproduction on the proton
International Nuclear Information System (INIS)
Borasoy, B.; Bruns, P.C.; Nissler, R.; Meissner, U.G.
2007-01-01
We present a gauge-invariant approach to photoproduction of mesons on nucleons within a chiral unitary framework. The interaction kernel for meson-baryon scattering is derived from the chiral effective Lagrangian and iterated in a Bethe-Salpeter equation. Within the leading-order approximation to the interaction kernel, data on kaon photoproduction from SAPHIR, CLAS and CBELSA/TAPS are analyzed in the threshold region. The importance of gauge invariance and the precision of various approximations in the interaction kernel utilized in earlier works are discussed. (orig.)
Staggered chiral random matrix theory
International Nuclear Information System (INIS)
Osborn, James C.
2011-01-01
We present a random matrix theory for the staggered lattice QCD Dirac operator. The staggered random matrix theory is equivalent to the zero-momentum limit of the staggered chiral Lagrangian and includes all taste breaking terms at their leading order. This is an extension of previous work which only included some of the taste breaking terms. We will also present some results for the taste breaking contributions to the partition function and the Dirac eigenvalues.
Homogenization of resonant chiral metamaterials
Andryieuski, Andrei; Menzel, Christoph; Rockstuhl, Carsten; Malureanu, Radu; Lederer, Falk; Lavrinenko, Andrei
2010-01-01
Homogenization of metamaterials is a crucial issue as it allows to describe their optical response in terms of effective wave parameters as e.g. propagation constants. In this paper we consider the possible homogenization of chiral metamaterials. We show that for meta-atoms of a certain size a critical density exists above which increasing coupling between neighboring meta-atoms prevails a reasonable homogenization. On the contrary, a dilution in excess will induce features reminiscent to pho...
Chiral Lagrangians and the SSC
International Nuclear Information System (INIS)
Dawson, S.
1991-09-01
In the event that the SSC does not observe any resonances such as a Higgs boson or a techni-rho meson, we would like to know if the SSC can still discover something about the nature of the electroweak symmetry breaking. We will use chiral Lagrangian techniques to address this question and analyze their utility for studying events containing W and Z gauge bosons at the SSC. 20 refs., 4 figs
Is there chirality in atomic nuclei?
International Nuclear Information System (INIS)
Meng Jie
2009-01-01
Static chiral symmetries are common in nature, for example, the macroscopic spirals of snail shells, the microscopic handedness of certain molecules, and human hands. The concept of chirality in atomic nuclei was first proposed in 1997, and since then many efforts have been made to understand chiral symmetry and its spontaneous breaking in atomic nuclei. Recent theoretical and experimental progress in the verification of chirality in atomic nuclei will be reviewed, together with a discussion of the problems that await to be solved in the future. (authors)
Laser Writing of Multiscale Chiral Polymer Metamaterials
Directory of Open Access Journals (Sweden)
E. P. Furlani
2012-01-01
Full Text Available A new approach to metamaterials is presented that involves laser-based patterning of novel chiral polymer media, wherein chirality is realized at two distinct length scales, intrinsically at the molecular level and geometrically at a length scale on the order of the wavelength of the incident field. In this approach, femtosecond-pulsed laser-induced two-photon lithography (TPL is used to pattern a photoresist-chiral polymer mixture into planar chiral shapes. Enhanced bulk chirality can be realized by tuning the wavelength-dependent chiral response at both the molecular and geometric level to ensure an overlap of their respective spectra. The approach is demonstrated via the fabrication of a metamaterial consisting of a two-dimensional array of chiral polymer-based L-structures. The fabrication process is described and modeling is performed to demonstrate the distinction between molecular and planar geometric-based chirality and the effects of the enhanced multiscale chirality on the optical response of such media. This new approach to metamaterials holds promise for the development of tunable, polymer-based optical metamaterials with low loss.
Self-inductance of chiral conducting nanotubes
International Nuclear Information System (INIS)
Miyamoto, Yoshiyuki; Rubio, Angel; Louie, Steven G.; Cohen, Marvin L.
1998-01-01
Chiral conductivity in nanotubes has recently been predicted theoretically. The realization and application of chiral conducting nanotubes can be of great interest from both fundamental and technological viewpoints. These chiral currents, if they are realized, can be detected by measuring the self-inductance. We have treated Maxwell's equations for chiral conducting nanotubes (nanocoils) and find that the self-inductance and the resistivity of nanocoils should depend on the frequency of the alternating current even when the capacitance of the nanocoils is not taken into account. This is in contrast to elementary treatment of ordinary coils. This fact is useful to distinguish nanocoils by electrical measurements
van Elburg, P.A.; Honig, G.W.N.; Reinhoudt, David
1987-01-01
Chiral four-membered cyclic nitrones were synthesized by the asymmetric (4+2)-cycloaddition of nitroalkenes 1 and chiral ynamines 2. The subsequent stereoselective addition of nucleophiles to these nitrones enabled the synthesis of chiral N-hydroxyazetidines.
Kahle, Kimberly A; Foley, Joe P
2007-06-01
The first simultaneous use of a chiral surfactant and a chiral oil for microemulsion EKC (MEEKC) is reported. Six stereochemical combinations of dodecoxycarbonylvaline (DDCV: R, S, or racemic, 2.00% w/v), racemic 2-hexanol (1.65% v/v), and dibutyl tartrate (D, L, or racemic, 1.23% v/v) were examined as chiral pseudostationary phases (PSPs) for the separation of six pairs of pharmaceutical enantiomers: pseudoephedrine, ephedrine, N-methyl ephedrine, metoprolol, synephrine, and atenolol. Subtle differences were observed for three chromatographic figures of merit (alpha(enant), alpha(meth), k) among the chiral microemulsions; a moderate difference was observed for efficiency (N) and elution range. Dual-chirality microemulsions provided both the largest and smallest enantioselectivities, due to small positive and negative synergies between the chiral microemulsion components. For the ephedrine family of compounds, dual-chiral microemulsions with surfactant and oil in opposite stereochemical configurations provided higher enantioselectivities than the single-chiral component microemulsion (RXX), whereas dual-chiral microemulsions with surfactant and oil in the same stereochemical configurations provided lower enantioselectivities than RXX. Slight to moderate enantioselective synergies were confirmed using a thermodynamic model. Efficiencies observed with microemulsions comprised of racemic dibutyl tartrate or dibutyl-D-tartrate were significantly higher than those obtained with dibutyl-L-tartrate, with an average difference in plate count of about 25 000. Finally, one two-chiral-component microemulsion (RXS) provided significantly better resolution than the remaining one- and two-chiral-component microemulsions for the ephedrine-based compounds, but only slightly better or equivalent resolution for non-ephedrine compounds.
Energy Technology Data Exchange (ETDEWEB)
Knippschild, Bastian
2012-03-05
Quantum Chromodynamics (QCD) is the theory of strong interactions, one of the four fundamental forces in our Universe. It describes the interaction of gluons and quarks which build up hadrons like protons and neutrons. Most of the visible matter in our universe is made of protons and neutrons. Hence, we are interested in their fundamental properties like their masses, their distribution of charge and their shape. The only known theoretical, non-perturbative and ab initio method to investigate hadron properties at low energies is lattice Quantum Chromodynamics (lattice QCD). However, up-to-date simulations (especially for baryonic quantities) do not achieve the accuracy of experiments. In fact, current simulations do not even reproduce the experimental values for the form factors. The question arises wether these deviations can be explained by systematic effects in lattice QCD simulations. This thesis is about the computation of nucleon form factors and other hadronic quantities from lattice QCD. So called Wilson fermions are used and the u- and d-quarks are treated fully dynamically. The simulations were performed using gauge ensembles with a range of lattice spacings, volumes and pion masses. First of all, the lattice spacing was set to be able to make contact between the lattice results and their experimental complement and to be able to perform a continuum extrapolation. The light quark mass has been computed and found to be m{sub ud}{sup MS}(2 GeV)=3.03(17)(38) MeV. This value is in good agreement with values from experiments and other lattice determinations. Electro-magnetic and axial form factors of the nucleon have been calculated. From these form factors the nucleon radii and the coupling constants were computed. The different ensembles enabled us to investigate systematically the dependence of these quantities on the volume, the lattice spacing and the pion mass. Finally we perform a continuum extrapolation and chiral extrapolations to the physical point
International Nuclear Information System (INIS)
Knippschild, Bastian
2012-01-01
Quantum Chromodynamics (QCD) is the theory of strong interactions, one of the four fundamental forces in our Universe. It describes the interaction of gluons and quarks which build up hadrons like protons and neutrons. Most of the visible matter in our universe is made of protons and neutrons. Hence, we are interested in their fundamental properties like their masses, their distribution of charge and their shape. The only known theoretical, non-perturbative and ab initio method to investigate hadron properties at low energies is lattice Quantum Chromodynamics (lattice QCD). However, up-to-date simulations (especially for baryonic quantities) do not achieve the accuracy of experiments. In fact, current simulations do not even reproduce the experimental values for the form factors. The question arises whether these deviations can be explained by systematic effects in lattice QCD simulations. This thesis is about the computation of nucleon form factors and other hadronic quantities from lattice QCD. So called Wilson fermions are used and the u- and d-quarks are treated fully dynamically. The simulations were performed using gauge ensembles with a range of lattice spacings, volumes and pion masses. First of all, the lattice spacing was set to be able to make contact between the lattice results and their experimental complement and to be able to perform a continuum extrapolation. The light quark mass has been computed and found to be m ud MS (2 GeV)=3.03(17)(38) MeV. This value is in good agreement with values from experiments and other lattice determinations. Electro-magnetic and axial form factors of the nucleon have been calculated. From these form factors the nucleon radii and the coupling constants were computed. The different ensembles enabled us to investigate systematically the dependence of these quantities on the volume, the lattice spacing and the pion mass. Finally we perform a continuum extrapolation and chiral extrapolations to the physical point. In
Chiral ferrocenes in asymmetric catalysis: synthesis and applications
National Research Council Canada - National Science Library
Dai, Li-Xin; Hou, Xue-Long
2010-01-01
.... It provides a thorough overview of the synthesis and characterization of different types of chiral ferrocene ligands, their application to various catalytic asymmetric reactions, and versatile chiral...
DEFF Research Database (Denmark)
Nazmutdinov, Renat R.; Bronshtein, Michael D.; Zinkicheva, Tamara T.
2016-01-01
We have studied electron transfer between cytochrome c and the chiral transition-metal complex pair Λ- and Δ-[Co(Ox)3]3− (Ox2− = oxalate) via strong ion-pair formation. Chirality was found in both ion-pair formation and electron transfer, with the Λ enantiomer the more strongly bound and faster r...... reacting. Investigations of the chirality using electron-transfer theory combined with quantum-chemical and statistical-mechanical calculations showed that chirality is solely in inter-reactant interaction and electronic overlap.......We have studied electron transfer between cytochrome c and the chiral transition-metal complex pair Λ- and Δ-[Co(Ox)3]3− (Ox2− = oxalate) via strong ion-pair formation. Chirality was found in both ion-pair formation and electron transfer, with the Λ enantiomer the more strongly bound and faster...
Chiral pion dynamics for spherical nucleon bags
International Nuclear Information System (INIS)
Vento, V.; Rho, M.; Nyman, E.M.; Jun, J.H.; Brown, G.E.; CEA Centre d'Etudes Nucleaires de Saclay, 91 - Gif-sur-Yvette
1980-01-01
A chirally symmetric quark-bag model for the nucleon is obtained by introducing an explicit, classical, pion field exterior to the bag. The coupling at the bag surface is determined by the requirement of a conserved axial-vector current. The pion field satisfies equations of motion corresponding to the non-linear sigma-model. We study on this paper the simplified case where the bag and the pion field are spherically symmetric. Corrections due to gluon exchange between the quarks are ignored along with other interactions which split the N- and Δ-masses. The equations of motion for the pion field are solved and we find a substantial pion pressure at the bag surface, along with an attractive contribution to the nucleon self-energy. The total energy of the system, bag plus meson cloud, turns out to be approximately Msub(n)c 2 for a wide range of bag radii, from 1.5 fm down to about 0.5 fm. Introduction of a form factor for the pion would extend the range of possible radii to even smaller values. We propose that the bag with the smallest allowed radius be identified with the 'little bag' discussed before. One surprising result of the paper is that as long as one restricts to spherically symmetric bags, restoring chiral symmetry to the bag model makes the axial-vector current coupling constant gsub(A) to be always too large compared with the experimental value for any bag radius, suggesting a deviation from spherical symmetry for the intrinsic bag wave functions of the 'ground-state' hadrons. (orig.)
Neutral pion electroproduction off light nuclei in chiral perturbation theory
International Nuclear Information System (INIS)
Lenkewitz, Mark
2013-01-01
Threshold pion electroproduction on tri-nucleon systems is investigated in the framework of baryon Chiral Perturbation Theory (ChPT) at next-to-leading one-loop order O(q 4 ) in the chiral expansion. To this order in small momenta, the production operator is a sum of one- and two-nucleon terms. While the one-nucleon terms resemble the impulse approximation, the two-nucleon contributions represent corrections due to the relevant nuclear interactions, e.g. pion-exchange interactions, which prove to be dominant, and due to recoil effects of the participating nucleons, which appear to be negligible. We calculate the expectation value of the production operator using chiral wave functions in a three-dimensional approach without partial wave expansion. The resulting integrals are evaluated using adaptive Monte Carlo integration, the VEGAS algorithm of Lepage. We obtain results for the threshold production multipoles E 0+ and L 0+ on 3 He and 3 H and comment on the sensitivity to the fundamental neutron amplitude E 0+ π 0 n . 3 He appears to be a particularly promising target to extract information about the neutron amplitude. This idea is usually invoked for spin-dependent quantities since the 3 He wave function is strongly dominated by the principal S-state component which suggests that its spin is largely driven by the one of the neutron.
International Nuclear Information System (INIS)
Ziino, G.
1989-01-01
We assume a strictly invariant definition of the Dirac parity operator under fermion ↔ antifermion exchange. We see that the opposite-intrinsic-parity condition then requires two opposite-mass Dirac equations for the fermion and the antifermion. This leads us to introduce an asymptotically left-handed (fermion) and right-handed (antifermion) chiral field, as just an alternative basis in the internal space spanned by the new pair of charge-conjugate Dirac fields. Hence a dual intrinsic model of a spin - 1/2 massive fermion is drawn: it predicts the coexistence of two anticommuting general varieties of conserved charges, namely a scalar variety, responsible for parity-invariant phenomenology, plus a pseudoscalar one, responsible for chiral phenomenology. In this light, CP-symmetry is seen to be nothing but P-symmetry; and a spontaneous CP-violation mechanism is also derived, that should work in any single process occurring via both scalar-and pseudoscalar-charge interactions. We show, at last, that our scheme automatically yields Weyl's one for a merely left-handed neutrino and a merely right-handed antineutrino, further assigning them the special meaning of pure pseudoscalar-charge objects. Some general consequences as regards magnetic monopoles are briefly discussed too
Chiral Thirring–Wess model with Faddeevian regularization
International Nuclear Information System (INIS)
Rahaman, Anisur
2015-01-01
Replacing vector type of interaction of the Thirring–Wess model by the chiral type a new model is presented which is termed here as chiral Thirring–Wess model. Ambiguity parameters of regularization are so chosen that the model falls into the Faddeevian class. The resulting Faddeevian class of model in general does not possess Lorentz invariance. However we can exploit the arbitrariness admissible in the ambiguity parameters to relate the quantum mechanically generated ambiguity parameters with the classical parameter involved in the masslike term of the gauge field which helps to maintain physical Lorentz invariance instead of the absence of manifestly Lorentz covariance of the model. The phase space structure and the theoretical spectrum of this class of model have been determined through Dirac’s method of quantization of constraint system
On integration over Fermi fields in chiral and supersymmetric theories
International Nuclear Information System (INIS)
Vainshtein, A.I.; Zakharov, V.I.
1982-01-01
Chiral and supersymmetric theories are considered which cannot be formulated directly in Euclidean space or regularized by means of massive fields in a manifestly gauge invariant fashion. In case of so called real representations a simple recipe is proposed which allows for unambiguous evaluation of the fermionic determinant circumventing the difficulties mentioned. As application of the general technique the effective fermionic interactions induced by instantons of small size within simplest chiral and supesymmetric theories are calculated (SU(2) as the gauge group and one doublet of Weyl spinors or a triplet of Majorana spinors, respectively). In the latter case the effective Lagrangian violates explicitly invariance under supersymmetric transformations on the fermionic and vector fields defined in standard way [ru
Thermoelectric figure of merit of chiral carbon nanotube
International Nuclear Information System (INIS)
Mensah, N.G.; Nkrumah-Buandoh, G.K.; Mensah, S.Y.; Allotey, F.K.A.; Twum, A.K.
2005-09-01
We have investigated the thermoelectrical properties of chiral carbon nanotube and numerically evaluated the figure of merit. We observed that the properties are highly anisotropic and depend on the geometric chiral angle (GCA) θ h , temperature and the overlapping integrals (exchange energy) for the jumps along the tubular axis Δ z and the base helix Δ s . The thermopower α exhibited giant values with the peak occurring between 100 K and 150 K. The electron thermal conductivity showed unusually high value with the peaks shifting towards high temperature. We attribute the high peak values to electron-phonon interactions. Finally we noted that by changing the Δ s and Δ z it is possible to get a figure of merit greater than 1. (author)
Parafermionic wires at the interface of chiral topological states
Santos, Luiz; Hughes, Taylor
We discuss a scenario where local interactions form one-dimensional gapped interfaces between a pair of distinct chiral two-dimensional topological states such that each gapped region terminates at a domain wall separating the chiral gapless edge states of these phases. We show that this type of T-junction supports point-like fractionalized excitations obeying parafermion statistics, thus implying that the one-dimensional gapped interface forms an effective topological parafermionic wire possessing a non-trivial ground state degeneracy. The physical properties of the anyon condensate that gives rise to the gapped interface are investigated. Remarkably, this condensate causes the gapped interface to behave as a type of anyon ``Andreev reflector'' in the bulk, whereby anyons from one phase, upon hitting the interface, can be transformed into a combination of reflected anyons and outgoing anyons from the other phase. Thus, we conclude that while different topological orders can be connected via gapped interfaces, the interfaces are themselves topological.
Color superconductivity from the chiral quark-meson model
Sedrakian, Armen; Tripolt, Ralf-Arno; Wambach, Jochen
2018-05-01
We study the two-flavor color superconductivity of low-temperature quark matter in the vicinity of chiral phase transition in the quark-meson model where the interactions between quarks are generated by pion and sigma exchanges. Starting from the Nambu-Gorkov propagator in real-time formulation we obtain finite temperature (real axis) Eliashberg-type equations for the quark self-energies (gap functions) in terms of the in-medium spectral function of mesons. Exact numerical solutions of the coupled nonlinear integral equations for the real and imaginary parts of the gap function are obtained in the zero temperature limit using a model input spectral function. We find that these components of the gap display a complicated structure with the real part being strongly suppressed above 2Δ0, where Δ0 is its on-shell value. We find Δ0 ≃ 40MeV close to the chiral phase transition.
arXiv Chiral Effective Theory of Dark Matter Direct Detection
Bishara, Fady
2017-02-03
We present the effective field theory for dark matter interactions with the visible sector that is valid at scales of O(1 GeV). Starting with an effective theory describing the interactions of fermionic and scalar dark matter with quarks, gluons and photons via higher dimension operators that would arise from dimension-five and dimension-six operators above electroweak scale, we perform a nonperturbative matching onto a heavy baryon chiral perturbation theory that describes dark matter interactions with light mesons and nucleons. This is then used to obtain the coefficients of the nuclear response functions using a chiral effective theory description of nuclear forces. Our results consistently keep the leading contributions in chiral counting for each of the initial Wilson coefficients.
International Nuclear Information System (INIS)
Truong, T.N.
1981-01-01
It is shown that discrepancies between soft pion current algebra (or chiral symmetry) calculations in Kl 4 and experiments are mostly due to the square root threshold singularity of the pion-pion interaction. For the same reason, chiral symmetry breaking calculations of the scalar Kl 3 form factor cannot be extended to the threshold of tau → Kπν decay. (orig.)
Bhaskararao, Bangaru; Sunoj, Raghavan B
2015-12-23
Accomplishing high diastereo- and enantioselectivities simultaneously is a persistent challenge in asymmetric catalysis. The use of two chiral catalysts in one-pot conditions might offer new avenues to this end. Chirality transfer from a catalyst to product gets increasingly complex due to potential chiral match-mismatch issues. The origin of high enantio- and diastereoselectivities in the reaction between a racemic aldehyde and an allyl alcohol, catalyzed by using axially chiral iridium phosphoramidites PR/S-Ir and cinchona amine is established through transition-state modeling. The multipoint contact analysis of the stereocontrolling transition state revealed how the stereodivergence could be achieved by inverting the configuration of the chiral catalysts that are involved in the activation of the reacting partners. While the enantiocontrol is identified as being decided in the generation of PR/S-Ir-π-allyl intermediate from the allyl alcohol, the diastereocontrol arises due to the differential stabilizations in the C-C bond formation transition states. The analysis of the weak interactions in the transition states responsible for chiral induction revealed that the geometric disposition of the quinoline ring at the C8 chiral carbon of cinchona-enamine plays an anchoring role. The quinolone ring is noted as participating in a π-stacking interaction with the phenyl ring of the Ir-π-allyl moiety in the case of PR with the (8R,9R)-cinchona catalyst combination, whereas a series of C-H···π interactions is identified as vital to the relative stabilization of the stereocontrolling transition states when PR is used with (8S,9S)-cinchona.
Pion polarizability in a chiral quark model
International Nuclear Information System (INIS)
Ebert, D.; Volkov, M.K.
1981-01-01
The pion polarizability is calculated in a chiral meson-quark model at the one-loop level. The results are in complete agreement with earlier ones obtained within a chiral meson-baryon theory. A critical discussion of a recent paper by Llanta and Tarrach is given. (orig.)
Pion polarizability in a chiral quark model
International Nuclear Information System (INIS)
Volkov, M.K.; Ehbert, D.
1981-01-01
The pion polarizability is calculated in a chiral meson- quark model at the one-loop level. The results are in complete agreement with earlier ones obtained within a chiral meson-baryon theory. A critical discussion of a recent paper by Llanta and Tarrach is given [ru
Pion polarizability in a chiral quark model
International Nuclear Information System (INIS)
Volkov, M.K.; Ebert, D.
1981-01-01
It is shown that the pion polarizability calculated in a chiral model with quark loops agrees exactly with the analogous quantity found in a chiral meson-baryon model. The results of a paper by Llanta and Tarrach are discussed critically
Massive states in chiral perturbation theory
Energy Technology Data Exchange (ETDEWEB)
Mallik, S [Saha Inst. of Nuclear Physics, Calcutta (India)
1995-08-01
It is shown that the chiral nonanalytic terms generated by {Delta}{sub 33} resonance in the nucleon self-energy is reproduced in chiral perturbation theory by perturbing appropriate local operators contained in the pion-nucleon effective Lagrangian itself. (orig.)
LINEARLY POLARIZED PROBES OF SURFACE CHIRALITY
VERBIEST, T; KAURANEN, M; MAKI, JJ; TEERENSTRA, MN; SCHOUTEN, AJ; NOLTE, RJM; PERSOONS, A
1995-01-01
We present a new nonlinear optical technique to study surface chirality. We demonstrate experimentally that the efficiency of second-harmonic generation from isotropic chiral surfaces is different for excitation with fundamental light that is +45 degrees and -45 degrees linearly polarized with
Pentaquarks in chiral color dielectric model
Indian Academy of Sciences (India)
Recent experiments indicate that a narrow baryonic state having strangeness +1 and mass of about 1540 MeV may be existing. Such a state was predicted in chiral model by Diakonov et al. In this work I compute the mass and width of this state in chiral color dielectric model. I show that the computed width is about 30 MeV.
Orientation-Dependent Handedness and Chiral Design
Directory of Open Access Journals (Sweden)
Efi Efrati
2014-01-01
Full Text Available Chirality occupies a central role in fields ranging from biological self-assembly to the design of optical metamaterials. The definition of chirality, as given by Lord Kelvin, associates chirality with the lack of mirror symmetry: the inability to superpose an object on its mirror image. While this definition has guided the classification of chiral objects for over a century, the quantification of handed phenomena based on this definition has proven elusive, if not impossible, as manifest in the paradox of chiral connectedness. In this work, we put forward a quantification scheme in which the handedness of an object depends on the direction in which it is viewed. While consistent with familiar chiral notions, such as the right-hand rule, this framework allows objects to be simultaneously right and left handed. We demonstrate this orientation dependence in three different systems—a biomimetic elastic bilayer, a chiral propeller, and optical metamaterial—and find quantitative agreement with chirality pseudotensors whose form we explicitly compute. The use of this approach resolves the existing paradoxes and naturally enables the design of handed metamaterials from symmetry principles.
Chiral gravity, log gravity, and extremal CFT
International Nuclear Information System (INIS)
Maloney, Alexander; Song Wei; Strominger, Andrew
2010-01-01
We show that the linearization of all exact solutions of classical chiral gravity around the AdS 3 vacuum have positive energy. Nonchiral and negative-energy solutions of the linearized equations are infrared divergent at second order, and so are removed from the spectrum. In other words, chirality is confined and the equations of motion have linearization instabilities. We prove that the only stationary, axially symmetric solutions of chiral gravity are BTZ black holes, which have positive energy. It is further shown that classical log gravity--the theory with logarithmically relaxed boundary conditions--has finite asymptotic symmetry generators but is not chiral and hence may be dual at the quantum level to a logarithmic conformal field theories (CFT). Moreover we show that log gravity contains chiral gravity within it as a decoupled charge superselection sector. We formally evaluate the Euclidean sum over geometries of chiral gravity and show that it gives precisely the holomorphic extremal CFT partition function. The modular invariance and integrality of the expansion coefficients of this partition function are consistent with the existence of an exact quantum theory of chiral gravity. We argue that the problem of quantizing chiral gravity is the holographic dual of the problem of constructing an extremal CFT, while quantizing log gravity is dual to the problem of constructing a logarithmic extremal CFT.
Chirality in nonlinear optics and optical switching
Meijer, E.W.; Feringa, B.L.
1993-01-01
Chirality in molecular opto-electronics is limited sofar to the use of optically active liquid crystals and a number of optical phenomena are related to the helical macroscopic structure obtained by using one enantiomer, only. In this paper, the use of chirality in nonlinear optics and optical
On infinite regular and chiral maps
Arredondo, John A.; Valdez, Camilo Ramírez y Ferrán
2015-01-01
We prove that infinite regular and chiral maps take place on surfaces with at most one end. Moreover, we prove that an infinite regular or chiral map on an orientable surface with genus can only be realized on the Loch Ness monster, that is, the topological surface of infinite genus with one end.
Chiral bosonization on a Riemann surface
International Nuclear Information System (INIS)
Eguchi, Tohru; Ooguri, Hirosi
1987-01-01
We point out that the basic addition theorem of θ-functions, Fay's identity, implies an equivalence between bosons and chiral fermions on Riemann surfaces with arbitrary genus. We present a rule for a bosonized calculation of correlation functions. We also discuss ghost systems of n and (1-n) tensors and derive formulas for their chiral determinants. (orig.)
Dual chiral density wave in quark matter
International Nuclear Information System (INIS)
Tatsumi, Toshitaka
2002-01-01
We prove that quark matter is unstable for forming a dual chiral density wave above a critical density, within the Nambu-Jona-Lasinio model. Presence of a dual chiral density wave leads to a uniform ferromagnetism in quark matter. A similarity with the spin density wave theory in electron gas and the pion condensation theory is also pointed out. (author)
DEVELOPMENT AND REGISTRATION OF CHIRAL DRUGS
WITTE, DT; ENSING, K; FRANKE, JP; DEZEEUW, RA
1993-01-01
In this review we describe the impact of chirality on drug development and registration in the United States, Japan and the European Community. Enantiomers may have differences in their pharmacological profiles, and, therefore, chiral drugs ask for special analytical and pharmacological attention
Chiralities of spiral waves and their transitions.
Pan, Jun-ting; Cai, Mei-chun; Li, Bing-wei; Zhang, Hong
2013-06-01
The chiralities of spiral waves usually refer to their rotation directions (the turning orientations of the spiral temporal movements as time elapses) and their curl directions (the winding orientations of the spiral spatial geometrical structures themselves). Traditionally, they are the same as each other. Namely, they are both clockwise or both counterclockwise. Moreover, the chiralities are determined by the topological charges of spiral waves, and thus they are conserved quantities. After the inwardly propagating spirals were experimentally observed, the relationship between the chiralities and the one between the chiralities and the topological charges are no longer preserved. The chiralities thus become more complex than ever before. As a result, there is now a desire to further study them. In this paper, the chiralities and their transition properties for all kinds of spiral waves are systemically studied in the framework of the complex Ginzburg-Landau equation, and the general relationships both between the chiralities and between the chiralities and the topological charges are obtained. The investigation of some other models, such as the FitzHugh-Nagumo model, the nonuniform Oregonator model, the modified standard model, etc., is also discussed for comparison.
Insights on some chiral smectic phases
Indian Academy of Sciences (India)
journal of. August 2003 physics pp. 285–295. Insights on some chiral ... Liquid crystals; smectics; chirality; frustrated phases; twist grain boundary phases. ... molecules are more or less packed in layers and smectic phases can be seen ..... (imaging plate or CCD camera) which was located at about 300 mm from the sample.
Nonleptonic decay of charmed mesons and chiral lagrangians
International Nuclear Information System (INIS)
Kalinovskij, Yu.L.; Pervushin, V.N.
1978-01-01
Nonleptonic decays of charmed mesons in chiral theory are considered. The lagrangian of strong interaction is taken to be invariant under the SU(4)xSU(4) group. Symmetry breaking is chosen according to the (4,4sup(*))+(4sup(*),4) simplest representation of the SU(4)xSU(4) group. The lagrangian of weak interaction is taken in the ''current x current'' form and satisfies exactly the rule probabilities of decays for D and F mesons are compared with available experimental data
The Baryon Number Two System in the Chiral Soliton Model
International Nuclear Information System (INIS)
Mantovani-Sarti, V.; Drago, A.; Vento, V.; Park, B.-Y.
2013-01-01
We study the interaction between two B = 1 states in a chiral soliton model where baryons are described as non-topological solitons. By using the hedgehog solution for the B = 1 states we construct three possible B = 2 configurations to analyze the role of the relative orientation of the hedgehog quills in the dynamics. The strong dependence of the inter soliton interaction on these relative orientations reveals that studies of dense hadronic matter using this model should take into account their implications. (author)
Andrews, D. L.
2018-03-01
To properly represent the interplay and coupling of optical and material chirality at the photon-molecule or photon-nanoparticle level invites a recognition of quantum facets in the fundamental aspects and mechanisms of light-matter interaction. It is therefore appropriate to cast theory in a general quantum form, one that is applicable to both linear and nonlinear optics as well as various forms of chiroptical interaction including chiral optomechanics. Such a framework, fully accounting for both radiation and matter in quantum terms, facilitates the scrutiny and identification of key issues concerning spatial and temporal parity, scale, dissipation and measurement. Furthermore it fully provides for describing the interactions of structured or twisted light beams with a vortex character, and it leads to the complete identification of symmetry conditions for materials to provide for chiral discrimination. Quantum considerations also lend a distinctive perspective to the very different senses in which other aspects of chirality are recognized in metamaterials. Duly attending to the symmetry principles governing allowed or disallowed forms of chiral discrimination supports an objective appraisal of the experimental possibilities and developing applications.
Chiral tunneling in a twisted graphene bilayer.
He, Wen-Yu; Chu, Zhao-Dong; He, Lin
2013-08-09
The perfect transmission in a graphene monolayer and the perfect reflection in a Bernal graphene bilayer for electrons incident in the normal direction of a potential barrier are viewed as two incarnations of the Klein paradox. Here we show a new and unique incarnation of the Klein paradox. Owing to the different chiralities of the quasiparticles involved, the chiral fermions in a twisted graphene bilayer show an adjustable probability of chiral tunneling for normal incidence: they can be changed from perfect tunneling to partial or perfect reflection, or vice versa, by controlling either the height of the barrier or the incident energy. As well as addressing basic physics about how the chiral fermions with different chiralities tunnel through a barrier, our results provide a facile route to tune the electronic properties of the twisted graphene bilayer.
Hadron properties in chiral sigma model
International Nuclear Information System (INIS)
Shen Hong
2005-01-01
The modification of hadron masses in nuclear medium is studied by using the chiral sigma model, which is extended to generate the omega meson mass by the sigma condensation in the vacuum in the same way as the nucleon mass. The chiral sigma model provides proper equilibrium properties of nuclear matter. It is shown that the effective masses of both nucleons and omega mesons decrease in nuclear medium, while the effective mass of sigma mesons increases oat finite density in the chiral sigma model. The results obtained in the chiral sigma model are compared with those obtained in the Walecka model, which includes sigma and omega mesons in a non-chiral fashion. (author)
Genetically programmed chiral organoborane synthesis
Kan, S. B. Jennifer; Huang, Xiongyi; Gumulya, Yosephine; Chen, Kai; Arnold, Frances H.
2017-12-01
Recent advances in enzyme engineering and design have expanded nature’s catalytic repertoire to functions that are new to biology. However, only a subset of these engineered enzymes can function in living systems. Finding enzymatic pathways that form chemical bonds that are not found in biology is particularly difficult in the cellular environment, as this depends on the discovery not only of new enzyme activities, but also of reagents that are both sufficiently reactive for the desired transformation and stable in vivo. Here we report the discovery, evolution and generalization of a fully genetically encoded platform for producing chiral organoboranes in bacteria. Escherichia coli cells harbouring wild-type cytochrome c from Rhodothermus marinus (Rma cyt c) were found to form carbon-boron bonds in the presence of borane-Lewis base complexes, through carbene insertion into boron-hydrogen bonds. Directed evolution of Rma cyt c in the bacterial catalyst provided access to 16 novel chiral organoboranes. The catalyst is suitable for gram-scale biosynthesis, providing up to 15,300 turnovers, a turnover frequency of 6,100 h-1, a 99:1 enantiomeric ratio and 100% chemoselectivity. The enantiopreference of the biocatalyst could also be tuned to provide either enantiomer of the organoborane products. Evolved in the context of whole-cell catalysts, the proteins were more active in the whole-cell system than in purified forms. This study establishes a DNA-encoded and readily engineered bacterial platform for borylation; engineering can be accomplished at a pace that rivals the development of chemical synthetic methods, with the ability to achieve turnovers that are two orders of magnitude (over 400-fold) greater than those of known chiral catalysts for the same class of transformation. This tunable method for manipulating boron in cells could expand the scope of boron chemistry in living systems.
Hyperons in nuclear matter from SU(3) chiral effective field theory
Energy Technology Data Exchange (ETDEWEB)
Petschauer, S.; Kaiser, N. [Technische Universitaet Muenchen, Physik Department, Garching (Germany); Haidenbauer, J. [Institut fuer Kernphysik, Forschungszentrum Juelich, Institute for Advanced Simulation, Juelich Center for Hadron Physics, Juelich (Germany); Meissner, Ulf G. [Institut fuer Kernphysik, Forschungszentrum Juelich, Institute for Advanced Simulation, Juelich Center for Hadron Physics, Juelich (Germany); Universitaet Bonn, Helmholtz-Institut fuer Strahlen- und Kernphysik and Bethe Center for Theoretical Physics, Bonn (Germany); Weise, W. [Technische Universitaet Muenchen, Physik Department, Garching (Germany); Villa Tambosi, ECT, Villazzano (Trento) (Italy)
2016-01-15
Brueckner theory is used to investigate the properties of hyperons in nuclear matter. The hyperon-nucleon interaction is taken from chiral effective field theory at next-to-leading order with SU(3) symmetric low-energy constants. Furthermore, the underlying nucleon-nucleon interaction is also derived within chiral effective field theory. We present the single-particle potentials of Λ and Σ hyperons in symmetric and asymmetric nuclear matter computed with the continuous choice for intermediate spectra. The results are in good agreement with the empirical information. In particular, our calculation gives a repulsive Σ-nuclear potential and a weak Λ-nuclear spin-orbit force. (orig.)
Baryonic forces and hyperons in nuclear matter from SU(3) chiral effective field theory
Energy Technology Data Exchange (ETDEWEB)
Petschauer, Stefan Karl
2016-02-12
In this work the baryon-baryon interaction is studied at next-to-leading order in SU(3) chiral effective field theory and applied to hyperon-nucleon scattering. The properties of hyperons in isospin-symmetric as well as asymmetric nuclear matter are calculated within the Bruecker-Hartree-Fock formalism. Moreover, the leading three-baryon interaction is derived and its low-energy constants are estimated from decuplet intermediate states. We conclude, that chiral effective field theory is a well-suited tool to describe the baryonic forces.
DEFF Research Database (Denmark)
da Providëncia, J.; Jalkanen, Karl J.; Bohr, Henrik
2013-01-01
relativistic fluid of elementary particles is studied. We find that the magnetic field of spin polarized matter with densities of 2 to 30, where 0 is the equilibrium density of nuclear matter, is rather huge, of the order of 1017 Gauss. Finally we look at the chiral nature of nuclear forces and interactions...... as they possibly relate to chirality of nuclei (atoms) in molecules as a source of chirality in amino acids and hence in life. Previous works have not investigated the nuclear forces as a possible bias which initiated the bias towards L-amino acids as the building blocks on proteins, and later life....
Principal chiral model on superspheres
International Nuclear Information System (INIS)
Mitev, V.; Schomerus, V.; Quella, T.
2008-09-01
We investigate the spectrum of the principal chiral model (PCM) on odd-dimensional superspheres as a function of the curvature radius R. For volume-filling branes on S 3 vertical stroke 2 , we compute the exact boundary spectrum as a function of R. The extension to higher dimensional superspheres is discussed, but not carried out in detail. Our results provide very convincing evidence in favor of the strong-weak coupling duality between supersphere PCMs and OSP(2S+2 vertical stroke 2S) Gross-Neveu models that was recently conjectured by Candu and Saleur. (orig.)
Chiral quarks and proton decay
International Nuclear Information System (INIS)
Chadha, S.; Daniel, M.; Gounaris, G.J.; Murphy, A.J.
1984-04-01
The authors calculate the hadronic matrix elements of baryon decay operators using a chiral effective Lagrangian with quarks, gluons and Goldstone boson fields. The cases where the ΔB=1 operators arise from supersymmetric SU(5) GUT as well as the minimal SU(5) GUT model are studied. In each model the results depend on two parameters. In particular there is a range of values for the two parameters, where the dominant decay modes in the minimal SU(5) GUT are: p→etae + and n→π - e + . (author)
Takahashi, Y.; Eby, P. B.
1985-01-01
Possibilities of observing abundances of phi mesons and narrow hadronic pairs, as results of QGP and Chiral transitions, are considered for nucleus-nucleus interactions. Kinematical requirements in forming close pairs are satisfied in K+K decays of S(975) and delta (980) mesons with small phi, and phi (91020) mesons with large PT, and in pi-pi decays of familiar resonance mesons only in a partially restored chiral symmetry. Gluon-gluon dominance in QGP can enhance phi meson production. High hadronization rates of primordial resonance mesons which form narrow hadronic pairs are not implausible. Past cosmic ray evidences of anomalous phi production and narrow pair abundances are considered.
Chiral discrimination in nuclear magnetic resonance spectroscopy
Lazzeretti, Paolo
2017-11-01
Chirality is a fundamental property of molecules whose spatial symmetry is characterized by the absence of improper rotations, making them not superimposable to their mirror image. Chiral molecules constitute the elementary building blocks of living species and one enantiomer is favoured in general (e.g. L-aminoacids and D-sugars pervade terrestrial homochiral biochemistry) because most chemical reactions producing natural substances are enantioselective. Since the effect of chiral chemicals and drugs on living beings can be markedly different between enantiomers, the quest for practical spectroscopical methods to scrutinize chirality is an issue of great importance and interest. Nuclear magnetic resonance (NMR) is a topmost analytical technique, but spectrometers currently used are ‘blind’ to chirality, i.e. unable to discriminate the two mirror-image forms of a chiral molecule, because, in the absence of a chiral solvent, the spectral parameters, chemical shifts and spin-spin coupling constants are identical for enantiomers. Therefore, the development of new procedures for routine chiral recognition would offer basic support to scientists. However, in the presence of magnetic fields, a distinction between true and false chirality is mandatory. The former epitomizes natural optical activity, which is rationalized by a time-even pseudoscalar, i.e. the trace of a second-rank tensor, the mixed electric dipole/magnetic dipole polarizability. The Faraday effect, magnetic circular dichroism and magnetic optical activity are instead related to a time-odd axial vector. The present review summarizes recent theoretical and experimental efforts to discriminate enantiomers via NMR spectroscopy, with the focus on the deep connection between chirality and symmetry properties under the combined set of fundamental discrete operations, namely charge conjugation, parity (space inversion) and time (motion) reversal.
Directory of Open Access Journals (Sweden)
María Martín-Rodríguez
2011-07-01
Full Text Available The synthesis of a GSK 2nd generation inhibitor of the hepatitis C virus, by enantioselective 1,3-dipolar cycloaddition between a leucine derived iminoester and tert-butyl acrylate, was studied. The comparison between silver(I and gold(I catalysts in this reaction was established by working with chiral phosphoramidites or with chiral BINAP. The best reaction conditions were used for the total synthesis of the hepatitis C virus inhibitor by a four step procedure affording this product in 99% ee and in 63% overall yield. The origin of the enantioselectivity of the chiral gold(I catalyst was justified according to DFT calculations, the stabilizing coulombic interaction between the nitrogen atom of the thiazole moiety and one of the gold atoms being crucial.
Synthesis and characterization of mixed ligand chiral nanoclusters
Guven, Zekiye P.
2016-06-22
Chiral mixed ligand silver nanoclusters were synthesized in the presence of a chiral and an achiral ligand. While the chiral ligand led mostly to the formation of nanoparticles, the presence of the achiral ligand drastically increased the yield of nanoclusters with enhanced chiral properties. © 2016 The Royal Society of Chemistry.
Synthesis and characterization of mixed ligand chiral nanoclusters
Guven, Zekiye P.; Ustbas, Burcin; Harkness, Kellen M.; Coskun, Hikmet; Joshi, Chakra Prasad; Besong, Tabot M.D.; Stellacci, Francesco; Bakr, Osman; Akbulut, Ozge
2016-01-01
Chiral mixed ligand silver nanoclusters were synthesized in the presence of a chiral and an achiral ligand. While the chiral ligand led mostly to the formation of nanoparticles, the presence of the achiral ligand drastically increased the yield of nanoclusters with enhanced chiral properties. © 2016 The Royal Society of Chemistry.
Nitrile ylides: diastereoselective cycloadditions using chiral oxazolidinones without Lewis acid.
Sibi, Mukund P; Soeta, Takahiro; Jasperse, Craig P
2009-12-03
Lewis acid complexation is generally required for chiral-auxiliary-controlled stereoselectivity, and chiral Lewis acid catalysis is frequently optimal for introducing asymmetry. In this work, we show that nitrile ylide cycloadditions to electron-poor acceptors attached to chiral auxiliaries proceed in high yield and stereoselectivity in the absence of Lewis acids. In contrast, chiral Lewis acids are inferior in these cycloadditions.
Chiral symmetry breaking and cooling in lattice QCD
International Nuclear Information System (INIS)
Woloshyn, R.M.; Lee, F.X.
1995-08-01
Chiral symmetry breaking is calculated as a function of cooling in quenched lattice QCD. A non-zero signal is found for the chiral condensate beyond one hundred cooling steps, suggesting that there is chiral symmetry breaking associated with instantons. Quantitatively, the chiral condensate in cooled gauge field configurations is small compared to the value without cooling. (author) 7 refs., 1 tab., 3 figs
A Review on Chiral Chromatography and its Application to the ...
African Journals Online (AJOL)
MoZarD
amounts of material and is for measuring the relative proportions of ... the stationary phase must themselves be made chiral, giving differing ... electrophoretic medium that change it to chiral mobile phase (Eliel, et ... column containing a chiral stationary phase is also called a chiral ... densitometry, and a TLC method for the.
Induction of Chirality in Two-Dimensional Nanomaterials: Chiral 2D MoS2 Nanostructures.
Purcell-Milton, Finn; McKenna, Robert; Brennan, Lorcan J; Cullen, Conor P; Guillemeney, Lilian; Tepliakov, Nikita V; Baimuratov, Anvar S; Rukhlenko, Ivan D; Perova, Tatiana S; Duesberg, Georg S; Baranov, Alexander V; Fedorov, Anatoly V; Gun'ko, Yurii K
2018-02-27
Two-dimensional (2D) nanomaterials have been intensively investigated due to their interesting properties and range of potential applications. Although most research has focused on graphene, atomic layered transition metal dichalcogenides (TMDs) and particularly MoS 2 have gathered much deserved attention recently. Here, we report the induction of chirality into 2D chiral nanomaterials by carrying out liquid exfoliation of MoS 2 in the presence of chiral ligands (cysteine and penicillamine) in water. This processing resulted in exfoliated chiral 2D MoS 2 nanosheets showing strong circular dichroism signals, which were far past the onset of the original chiral ligand signals. Using theoretical modeling, we demonstrated that the chiral nature of MoS 2 nanosheets is related to the presence of chiral ligands causing preferential folding of the MoS 2 sheets. There was an excellent match between the theoretically calculated and experimental spectra. We believe that, due to their high aspect ratio planar morphology, chiral 2D nanomaterials could offer great opportunities for the development of chiroptical sensors, materials, and devices for valleytronics and other potential applications. In addition, chirality plays a key role in many chemical and biological systems, with chiral molecules and materials critical for the further development of biopharmaceuticals and fine chemicals, and this research therefore should have a strong impact on relevant areas of science and technology such as nanobiotechnology, nanomedicine, and nanotoxicology.
Chiral lattice fermions, minimal doubling, and the axial anomaly
International Nuclear Information System (INIS)
Tiburzi, B. C.
2010-01-01
Exact chiral symmetry at finite lattice spacing would preclude the axial anomaly. In order to describe a continuum quantum field theory of Dirac fermions, lattice actions with purported exact chiral symmetry must break the flavor-singlet axial symmetry. We demonstrate that this is indeed the case by using a minimally doubled fermion action. For simplicity, we consider the Abelian axial anomaly in two dimensions. At finite lattice spacing and with gauge interactions, the axial anomaly arises from nonconservation of the flavor-singlet current. Similar nonconservation also leads to the axial anomaly in the case of the naieve lattice action. For minimally doubled actions, however, fine-tuning of the action and axial current is necessary to arrive at the anomaly. Conservation of the flavor nonsinglet vector current additionally requires the current to be fine-tuned. Finally, we determine that the chiral projection of a minimally doubled fermion action can be used to arrive at a lattice theory with an undoubled Dirac fermion possessing the correct anomaly in the continuum limit.
K- nuclear potentials from in-medium chirally motivated models
International Nuclear Information System (INIS)
Cieply, A.; Gazda, D.; Mares, J.; Friedman, E.; Gal, A.
2011-01-01
A self-consistent scheme for constructing K - nuclear optical potentials from subthreshold in-medium KN s-wave scattering amplitudes is presented and applied to analysis of kaonic atoms data and to calculations of K - quasibound nuclear states. The amplitudes are taken from a chirally motivated meson-baryon coupled-channel model, both at the Tomozawa-Weinberg leading order and at the next to leading order. Typical kaonic atoms potentials are characterized by a real part -Re V K - chiral =85±5 MeV at nuclear matter density, in contrast to half this depth obtained in some derivations based on in-medium KN threshold amplitudes. The moderate agreement with data is much improved by adding complex ρ- and ρ 2 -dependent phenomenological terms, found to be dominated by ρ 2 contributions that could represent KNN→YN absorption and dispersion, outside the scope of meson-baryon chiral models. Depths of the real potentials are then near 180 MeV. The effects of p-wave interactions are studied and found secondary to those of the dominant s-wave contributions. The in-medium dynamics of the coupled-channel model is discussed and systematic studies of K - quasibound nuclear states are presented.
Alternative method for determination of contaminated heparin using chiral recognition.
Szekely, J; Collins, M; Currie, C A
2014-05-15
Since 2008 a significant amount of work has focused on the development of methods to analyze contaminated heparin. This work focuses on utilizing heparin's ability to serve as a chiral selector as a means for determining contamination. Specifically, the effect of contamination on the separation of pheniramine and chloroquine enantiomers was explored. Separations were conducted using heparin contaminated with chondroitin sulfate at varying levels. For each pair of enantiomers, electrophoretic mobility and resolution were calculated. For pheniramine enantiomers, an increase in contamination leads to a decrease in the electrophoretic mobility and resolution. A linear relationship between contamination level and electrophoretic mobility of the pheniramine enantiomers was observed for the entire contamination range. A linear relationship was also found between contamination level and resolution of the enantiomers between 0 and 70 percent contamination. For the separation of chloroquine enantiomers, it was found that at low levels of contamination, the resolution of enantiomers was increased due to the secondary interaction between the chloroquine enantiomers and the chondroitin sulfate. Results of this study illustrate the potential of using chiral recognition as a means to determine heparin contamination as well as the improvement of the chiral resolution of chloroquine with the additional of low levels of chondroitin sulfate A. Copyright © 2014 Elsevier B.V. All rights reserved.
Nucleic acids, proteins, and chirality
Usher, D. A.; Profy, A. T.; Walstrum, S. A.; Needels, M. C.; Bulack, S. C.; Lo, K. M.
1984-01-01
The present investigation is concerned with experimental results related, in one case, to the chirality of nucleotides, and, in another case, to the possibility of a link between the chirality of nucleic acids, and that of peptides. It has been found that aminoacylation of the 'internal' hydroxyl group of a dinucleoside monophosphate can occur stereoselectively. However, this reaction has not yet been made a part of a working peptide synthesis scheme. The formation and cleavage of oligonucleotides is considered. In the event of the formation of a helical complex between the oligonucleotide and the polymer, 1-prime,5-prime-bonds in the oligomer are found to become more resistant towards cleavage. The conditions required for peptide bond formation are examined, taking into account the known structures of RNA and possible mechanisms for prebiotic peptide bond formation. The possibility is considered that the 2-prime,5-prime-internucleotide linkage could have played an important part in the early days of biological peptide synthesis.
Hierarchical chirality transfer in the growth of Towel Gourd tendrils
Wang, Jian-Shan; Wang, Gang; Feng, Xi-Qiao; Kitamura, Takayuki; Kang, Yi-Lan; Yu, Shou-Wen; Qin, Qing-Hua
2013-01-01
Chirality plays a significant role in the physical properties and biological functions of many biological materials, e.g., climbing tendrils and twisted leaves, which exhibit chiral growth. However, the mechanisms underlying the chiral growth of biological materials remain unclear. In this paper, we investigate how the Towel Gourd tendrils achieve their chiral growth. Our experiments reveal that the tendrils have a hierarchy of chirality, which transfers from the lower levels to the higher. The change in the helical angle of cellulose fibrils at the subcellular level induces an intrinsic torsion of tendrils, leading to the formation of the helical morphology of tendril filaments. A chirality transfer model is presented to elucidate the chiral growth of tendrils. This present study may help understand various chiral phenomena observed in biological materials. It also suggests that chirality transfer can be utilized in the development of hierarchically chiral materials having unique properties. PMID:24173107
Three nucleon results for one boson exchange potential
International Nuclear Information System (INIS)
Birrell, N.D.; Afnan, I.R.
1977-06-01
The binding energy of 3 H, percentage S-, S'-, and D-state probabilities and charge form factor of 3 He are calculated using the Adhikari-Sloan separable expansion (ASE) to the Holinde and Machleidt one boson exchange potential. The results show that the ASE has good convergence for the binding energy, and the lowest order ASE considered gives excellent results for the form factor. (Author)
Supersymmetric chiral electrodynamics as a renormalized theory
International Nuclear Information System (INIS)
Ansel'm, A.A.; Iogansen, A.A.
1991-01-01
It is well know that the QED of chiral fermions is a nonrenormalizable theory, inasmuch as the gauge current in it is not conserved because of the presence of an anomaly. It is evident that in this theory unitarity is also violated. The principal object of investigation in the present paper is supersymmetric chiral QED, supersymmetric QED is a renormalizable theory. This happens because the radiative corrections generate here a charged current of a chiral fermion that appears in the chiral (i.e., longitudinal) part of the vector supermultiplet. At first sight, the chiral part of the vector multiplet is unphysical and contains only supergauge degrees of freedom. However, this is valid only at the classical level, whereas, because of the anomaly, the radiative corrections lead to nonconservation of the gauge current, as a result of which the degrees of freedom associated with the chiral part of the vector multiplet become physical. On the other hand, owing to the nonconservation of the gauge charge, the apparently neutral fermion appearing int he chiral (longitudinal) part of the vector superfield becomes charged
Chiral polarization scale of QCD vacuum and spontaneous chiral symmetry breaking
International Nuclear Information System (INIS)
Alexandru, Andrei; Horv, Ivan
2013-01-01
It has recently been found that dynamics of pure glue QCD supports the low energy band of Dirac modes with local chiral properties qualitatively different from that of a bulk: while bulk modes suppress chirality relative to statistical independence between left and right, the band modes enhance it. The width of such chirally polarized zone – chiral polarization scale bigwedge ch – has been shown to be finite in the continuum limit at fixed physical volume. Here we present evidence that bigwedge ch remains non-zero also in the infinite volume, and is therefore a dynamical scale in the theory. Our experiments in N f = 2+1 QCD support the proposition that the same holds in the massless limit, connecting bigwedge ch to spontaneous chiral symmetry breaking. In addition, our results suggest that thermal agitation in quenched QCD destroys both chiral polarization and condensation of Dirac modes at the same temperature T ch > T c .
The paradigm of Pseudodual Chiral Models
International Nuclear Information System (INIS)
Zachos, C.K.; Curtright, T.L.
1994-01-01
This is a synopsis and extension of Phys. Rev. D49 5408 (1994). The Pseudodual Chiral Model illustrates 2-dimensional field theories which possess an infinite number of conservation laws but also allow particle production, at variance with naive expectations-a folk theorem of integrable models. We monitor the symmetries of the pseudodual model, both local and nonlocal, as transmutations of the symmetries of the (very different) usual Chiral Model. We refine the conventional algorithm to more efficiently produce the nonlocal symmetries of the model. We further find the canonical transformation which connects the usual chiral model to its fully equivalent dual model, thus contradistinguishing the pseudodual theory
Recent status of the chiral bag model
International Nuclear Information System (INIS)
Hosaka, Atsushi; Toki, Hiroshi.
1995-01-01
In this note, recent status of the chiral bag model is presented. As it combines the MIT quark bag model and the Skyrme model, the chiral bag model interpolates the two models smoothly as a function of the chiral bag radius R. The correct limit of R → ∞ is reproduced by including the higher order terms in the Ω expansion of the cranking method. It resolves the so-called small g A problem in a class of models where the semiclassical method is used. (author)
A nonlocal model of chiral dynamics
International Nuclear Information System (INIS)
Holdom, B.; Terning, J.; Verbeek, K.
1989-01-01
We consider a nonlocal generalization of the nonlinear σ model. Our chirally symmetric model couples quarks with self-energy Σ(p) to Goldstone bosons (GBs). By integrating out the quarks we obtain a chiral lagrangian, the parameters of which are finite integrals of Σ(p). We find that chiral symmetry is not sufficient to derive the well-known Pagels-Stokar formula for the GB decay constant. We reproduce the Wess-Zumino term and we illustrate the dependence of other four derivative coefficients on Σ(p). (orig.)
Fluxionally chiral DMAP catalysts: kinetic resolution of axially chiral biaryl compounds.
Ma, Gaoyuan; Deng, Jun; Sibi, Mukund P
2014-10-27
Can organocatalysts that incorporate fluxional groups provide enhanced selectivity in asymmetric transformations? To address this issue, we have designed chiral 4-dimethylaminopyridine (DMAP) catalysts with fluxional chirality. These catalysts were found to be efficient in promoting the acylative kinetic resolution of secondary alcohols and axially chiral biaryl compounds with selectivity factors of up to 37 and 51, respectively. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Thermal chiral vortical and magnetic waves: New excitation modes in chiral fluids
Energy Technology Data Exchange (ETDEWEB)
Kalaydzhyan, Tigran, E-mail: tigran@caltech.edu [Department of Physics, University of Illinois, 845 W Taylor Street, Chicago, IL 60607 (United States); Jet Propulsion Laboratory, 4800 Oak Grove Dr, M/S 298, Pasadena, CA 91109 (United States); Murchikova, Elena [TAPIR, California Institute of Technology, MC 350-17, Pasadena, CA 91125 (United States)
2017-06-15
In certain circumstances, chiral (parity-violating) medium can be described hydrodynamically as a chiral fluid with microscopic quantum anomalies. Possible examples of such systems include strongly coupled quark–gluon plasma, liquid helium {sup 3}He-A, neutron stars and the Early Universe. We study first-order hydrodynamics of a chiral fluid on a vortex background and in an external magnetic field. We show that there are two previously undiscovered modes describing heat waves propagating along the vortex and magnetic field. We call them the Thermal Chiral Vortical Wave and Thermal Chiral Magnetic Wave. We also identify known gapless excitations of density (chiral vortical and chiral magnetic waves) and transverse velocity (chiral Alfvén wave). We demonstrate that the velocity of the chiral vortical wave is zero, when the full hydrodynamic framework is applied, and hence the wave is absent and the excitation reduces to the charge diffusion mode. We also comment on the frame-dependent contributions to the obtained propagation velocities.
Thermal chiral vortical and magnetic waves: New excitation modes in chiral fluids
International Nuclear Information System (INIS)
Kalaydzhyan, Tigran; Murchikova, Elena
2017-01-01
In certain circumstances, chiral (parity-violating) medium can be described hydrodynamically as a chiral fluid with microscopic quantum anomalies. Possible examples of such systems include strongly coupled quark–gluon plasma, liquid helium "3He-A, neutron stars and the Early Universe. We study first-order hydrodynamics of a chiral fluid on a vortex background and in an external magnetic field. We show that there are two previously undiscovered modes describing heat waves propagating along the vortex and magnetic field. We call them the Thermal Chiral Vortical Wave and Thermal Chiral Magnetic Wave. We also identify known gapless excitations of density (chiral vortical and chiral magnetic waves) and transverse velocity (chiral Alfvén wave). We demonstrate that the velocity of the chiral vortical wave is zero, when the full hydrodynamic framework is applied, and hence the wave is absent and the excitation reduces to the charge diffusion mode. We also comment on the frame-dependent contributions to the obtained propagation velocities.
Thermal chiral vortical and magnetic waves: New excitation modes in chiral fluids
Directory of Open Access Journals (Sweden)
Tigran Kalaydzhyan
2017-06-01
Full Text Available In certain circumstances, chiral (parity-violating medium can be described hydrodynamically as a chiral fluid with microscopic quantum anomalies. Possible examples of such systems include strongly coupled quark–gluon plasma, liquid helium 3He-A, neutron stars and the Early Universe. We study first-order hydrodynamics of a chiral fluid on a vortex background and in an external magnetic field. We show that there are two previously undiscovered modes describing heat waves propagating along the vortex and magnetic field. We call them the Thermal Chiral Vortical Wave and Thermal Chiral Magnetic Wave. We also identify known gapless excitations of density (chiral vortical and chiral magnetic waves and transverse velocity (chiral Alfvén wave. We demonstrate that the velocity of the chiral vortical wave is zero, when the full hydrodynamic framework is applied, and hence the wave is absent and the excitation reduces to the charge diffusion mode. We also comment on the frame-dependent contributions to the obtained propagation velocities.
Determining chiral couplings at NLO
International Nuclear Information System (INIS)
Rosell, Ignasi
2007-01-01
We present a general method that allows to estimate the low-energy constants of Chiral Perturbation Theory up to next-to-leading corrections in the 1/N C expansion, that is, keeping full control of the renormalization scale dependence. As a first step we have determined L 8 and C 38 , the couplings related to the difference of the two-point correlation functions of two scalar and pseudoscalar currents, L 8 r (μ 0 ) = (0.6±0.4)·10 -3 and C 38 r (μ 0 ) = (2±6)·10 -6 , with μ 0 0.77 GeV. As in many effective approaches, one of the main ingredients of this method is the matching procedure: some comments related to this topic are presented here
Dynamics of inhomogeneous chiral condensates
Carlomagno, Juan Pablo; Krein, Gastão; Kroff, Daniel; Peixoto, Thiago
2018-01-01
We study the dynamics of the formation of inhomogeneous chirally broken phases in the final stages of a heavy-ion collision, with particular interest on the time scales involved in the formation process. The study is conducted within the framework of a Ginzburg-Landau time evolution, driven by a free energy functional motivated by the Nambu-Jona-Lasinio model. Expansion of the medium is modeled by one-dimensional Bjorken flow and its effect on the formation of inhomogeneous condensates is investigated. We also use a free energy functional from a nonlocal Nambu-Jona-Lasinio model which predicts metastable phases that lead to long-lived inhomogeneous condensates before reaching an equilibrium phase with homogeneous condensates.
Chiral equations and fiber bundles
International Nuclear Information System (INIS)
Mateos, T.; Becerril, R.
1992-01-01
Using the hypothesis g = g (lambda i ), the chiral equations (rhog, z g -1 ), z -bar + (rhog, z -barg -1 ), z = 0 are reduced to a Killing equation of a p-dimensional space V p , being lambda i lambda i (z, z-bar) 'geodesic' parameters of V p . Supposing that g belongs to a Lie group G, one writes the corresponding Lie algebra elements (F) in terms of the Killing vectors of V p and the generators of the subalgebra of F of dimension d = dimension of the Killing space. The elements of the subalgebras belong to equivalence classes which in the respective group form a principal fiber bundle. This is used to integrate the matrix g in terms of the complex variables z and z-bar ( Author)
Critical constraints on chiral hierarchies
International Nuclear Information System (INIS)
Chivukula, R.S.; Golden, M.; Simmons, E.H.
1993-01-01
Critical dynamics constrains models of dynamical electroweak symmetry breaking in which the scale of high-energy physics is far above 1 TeV. A big hierarchy requires the high-energy theory to have a second-order chiral phase transition, near which the theory is described by a low-energy effective Lagrangian with composite ''Higgs'' scalars. As scalar theories with more than one Φ 4 coupling can have a Coleman-Weinberg instability and a first-order transition, such dynamical EWSB models cannot always support a large hierarchy. If the large-N c Nambu--Jona-Lasinio model is a good approximation to the top-condensate and strong extended technicolor models, they will not produce acceptable EWSB
Axions from chiral family symmetry
International Nuclear Information System (INIS)
Chang, D.; Pal, P.B.; Maryland Univ., College Park; Senjanovic, G.
1985-01-01
We investigate the possibility that family symmetry, Gsub(F), is spontaneously broken chiral global symmetry. We classify the interesting cases when family symmetry can result in an automatic Peccei-Quinn symmetry U(1)sub(PQ) and thus provide a solution to the strong CP problem. The result disfavors having two or four families. For more than four families, U(1)sub(PQ) is in general automatic. In the case of three families, a unique Higgs sector allows U(1)sub(PQ) in the simplest case of Gsub(F)=[SU(3)] 3 . Cosmological consideration also puts strong constraint on the number of families. For Gsub(F)=[SU(N)] 3 cosmology singles out the three-family (N=3) case as a unique solution if there are three light neutrinos. Possible implication of decoupling theorem as applied to family symmetry breaking is also discussed. (orig.)
Algebraic structure of chiral anomalies
International Nuclear Information System (INIS)
Stora, R.
1985-09-01
I will describe first the algebraic aspects of chiral anomalies, exercising however due care about the topological delicacies. I will illustrate the structure and methods in the context of gauge anomalies and will eventually make contact with results obtained from index theory. I will go into two sorts of generalizations: on the one hand, generalizing the algebraic set up yields e.g. gravitational and mixed gauge anomalies, supersymmetric gauge anomalies, anomalies in supergravity theories; on the other hand most constructions applied to the cohomologies which characterize anomalies easily extend to higher cohomologies. Section II is devoted to a description of the general set up as it applies to gauge anomalies. Section III deals with a number of algebraic set ups which characterize more general types of anomalies: gravitational and mixed gauge anomalies, supersymmetric gauge anomalies, anomalies in supergravity theories. It also includes brief remarks on σ models and a reminder on the full BRST algebra of quantized gauge theories