WorldWideScience

Sample records for chemistry technology exchange

  1. Chemistry Technology

    Data.gov (United States)

    Federal Laboratory Consortium — Chemistry technology experts at NCATS engage in a variety of innovative translational research activities, including:Design of bioactive small molecules.Development...

  2. Chemistry and nuclear technology

    International Nuclear Information System (INIS)

    De Wet, W.J.

    1977-01-01

    The underlying principles of nuclear sciece and technology as based on the two basic phenomena, namely, radioactivity and nuclear reactions, with their relatively large associated energy changes, are outlined. The most important contributions by chemists in the overall historical development are mentioned and the strong position chemistry has attained in these fields is indicated. It is concluded that chemistry as well as many other scientific discplines (apart from general benefits) have largely benefitted from these nuclear developments [af

  3. Radiation chemistry in nuclear technology

    International Nuclear Information System (INIS)

    Katsumura, Yosuke

    2006-01-01

    The importance of radiation chemistry in the field of nuclear technology including reactor chemistry, spent fuel reprocessing and radioactive high level waste repository, is summarized and, in parallel, our research activity will be briefly presented. (author)

  4. Carboxylic acid exchangers in analytical chemistry

    International Nuclear Information System (INIS)

    Venkateswarlu, Ch.

    1976-01-01

    The literature on the use of carboxylic acid exchangers in inorganic analytical chemistry is reviewed. It is classified under two heads, based on the ionic form in which the exchanger is employed, viz., the salt form and the acid form. In the salt form, the separations reported in the beginning are mostly carried out in alkaline medium, employing ammonia and its derivatives as complexing agents to hold cations in solution. This was followed by the use of ammonium ion as an eluent from heavy weakly or neutral solutions. There are a few separations reported making use of EDTA as eluent. It appears that separation of some anions from cations can be achieved with greater ease with these exchangers than with sulphonic acid type. Contary to the general belief, carboxylic acid exchangers are used in H + form to achieve some analytical separations of cations of interest. These exchangers exhibit better sorption of some cations in presence of complexing agents containing basic nitrogen as a donor. In fact, a careful study of these exchangers with different matrices might yield really selective exchangers, than the chelating ones known commercially. From the separation cited, carboxylic acid exchangers appear to have greater potentialities in their applications, than what is normally expected. (author)

  5. News: Green Chemistry & Technology

    Science.gov (United States)

    A series of 21 articles focused on different features of green chemistry in a recent issue of Chemical Reviews. Topics extended over a wide range to include the design of sustainable synthetic processes to biocatalysis. A selection of perspectives follows as part of this colu

  6. Ion exchange technology assessment report

    International Nuclear Information System (INIS)

    Duhn, E.F.

    1992-01-01

    In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW's. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team

  7. Technological aspects of the radiation chemistry

    International Nuclear Information System (INIS)

    Chmielewski, A.G.

    2006-01-01

    Main technological aspects of the radiation chemistry are reviewed: network formation in polymers and caoutchouc, production of the sterile hydrogels, sterilisation of the expendable medical equipment and the environmental protection technologies (e.g. purification of the combustion gases from the sulfur oxides). Achievements of the are reviewed Institute of Nuclear Chemistry and Technology, Warsaw (Poland) in these fields are presented

  8. Program Integration for International Technology Exchange

    International Nuclear Information System (INIS)

    Rea, J.L.

    1993-01-01

    Sandia National Laboratories (SNL), Albuquerque, New Mexico, supports the International Technology Exchange Division (ITED) through the integration of all international activities conducted within the DOE's Office of Environmental Management (EM)

  9. Application of online chemistry monitoring programs and technology

    International Nuclear Information System (INIS)

    Perkins, D.; Choi, S.; Haas, C.

    2010-01-01

    To fully understand the impact of chemistry changes, several plant parameters must be considered and reviewed with actual chemistry analyses and compared to plant operating parameters. In some cases, this requires the ability to rapidly correlate plant operational data with laboratory and chemistry data. An effective online monitoring system should be able to: Integrate and extract online data from the plant laboratory and operating information from various plant data sources continuously; Interrogate and extract laboratory data from manually entered data on predefined frequencies; Interact with multiple laboratories in multiple locations; Evaluate data against plant limits (calculated or static) and provide personnel with action level or notification of plant exceeding limits; and, Provide the ability to evaluate against a standard and site specific set of calculations. The nuclear power industry continues to refine and apply new technologies in an effort to notify operators of changes in chemical conditions, calculate complex high temperature results, and monitor system performance. EPRI developed software specifically focused on plant chemistry program optimization using power operation and shutdown data applied with plant equipment. This software evolved into the family of software referred to as EPRI ChemWorks™ applications. As technology changed and improved, the application of online monitoring was essential for plant personnel working offsite. These changes in technology prompted EPRI to the development of SMART ChemWorks™ using the EPRI ChemWorks™ plant chemistry simulator and MULTEQ applications as the backbone for these simulations and calculations. SMART ChemWorks™ is an online monitoring system that queries plant databases and continuously monitors plant and chemistry parameters. The system uses a real-time intelligence engine to perform virtual sensing, identify normal and off-normal conditions and compare in-line instrument output to grab

  10. Annual Report of Institute of Nuclear Chemistry and Technology 2002

    International Nuclear Information System (INIS)

    2003-06-01

    The INCT 2002 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology, Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics, nucleonic control systems and accelerators

  11. Annual Report of Institute of Nuclear Chemistry and Technology 2002

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-06-01

    The INCT 2002 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology, Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics, nucleonic control systems and accelerators.

  12. Post irradiation examination technology exchange

    International Nuclear Information System (INIS)

    Sozawa, Shizuo; Ito, Masayasu; Taguchi, Taketoshi; Nakagawa, Tetsuya; Lee, Hyung-Kwon

    2012-01-01

    Under the KAERI and JAEA agreement, in a part of the program 18 (Post Irradiation Examination (PIE) and Evaluation Technique of Irradiated Materials), an eddy current test was proposed as a round robin test, and it has been being progressed in both organizations in order to enhance the post irradiation examination technology. Up to now, several data are obtained by both PIE facilities. In this paper, the round robin test program is shown, and also shown obtained data with discussion from applicability as a nondestructive test in the hot cell. (author)

  13. Annual Report of Institute of Nuclear Chemistry and Technology 1997

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-10-01

    The report is the collection of short communications being the review of the scientific activity of Institute of Nuclear Chemistry and Technology - Warsaw in 1997. The papers are gathered in several branches as follows: radiation chemistry and physics; radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general; radiobiology; nuclear technologies and methods. The annual report of INCT-1997 contains also the general information about INCT as well as the full list of scientific papers being published by the staff in 1997

  14. Annual Report of Institute of Nuclear Chemistry and Technology 2001

    International Nuclear Information System (INIS)

    2002-06-01

    The INCT 2001 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology in Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics, nucleonic control systems and accelerators and nuclear analytical methods

  15. Annual Report of Institute of Nuclear Chemistry and Technology 1997

    International Nuclear Information System (INIS)

    1998-06-01

    The report is the collection of short communications being the review of the scientific activity of Institute of Nuclear Chemistry and Technology - Warsaw in 1997. The papers are gathered in several branches as follows: radiation chemistry and physics; radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general; radiobiology; nuclear technologies and methods. The annual report of INCT-1997 contains also the general information about INCT as well as the full list of scientific papers being published by the staff in 1997

  16. Annual Report 2004 of Institute of Nuclear Chemistry and Technology

    Energy Technology Data Exchange (ETDEWEB)

    Michalik, J; Smulek, W; Godlewska-Para, E [eds.

    2005-06-01

    The INCT 2004 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics, nucleonic control systems and accelerators, radiobiology and nuclear analytical methods.

  17. Annual Report of Institute of Nuclear Chemistry and Technology 2001

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2002-06-01

    The INCT 2001 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology in Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics, nucleonic control systems and accelerators and nuclear analytical methods.

  18. Annual Report of Institute of Nuclear Chemistry and Technology 1999

    International Nuclear Information System (INIS)

    2000-06-01

    The INCT 1999 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology, Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics and nucleonic control systems and accelerators

  19. Annual Report 2004 of Institute of Nuclear Chemistry and Technology

    International Nuclear Information System (INIS)

    Michalik, J.; Smulek, W.; Godlewska-Para, E.

    2005-06-01

    The INCT 2004 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics, nucleonic control systems and accelerators, radiobiology and nuclear analytical methods

  20. Annual Report of Institute of Nuclear Chemistry and Technology 1999

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-06-01

    The INCT 1999 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology, Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics and nucleonic control systems and accelerators.

  1. International Technology Exchange Division: 1993 Annual report

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    The Office of Technology Development (OTD) was established to ensure that reliable and acceptable technologies are available for implementation at DOE sites and that a technically trained work force is available to complete the EM mission by 2019. OTD established the International Technology Exchange Staff (ITES) to identify, evaluate, and acquire international technologies which can accelerate US DOE cleanup operations. ITES`s goal is to pursue international collaboration among government organizations, educational institutions, and private industry to identify world-wide needs and available technologies that will meet US environmental needs in general, and EM cleanup needs in particular; and establish mechanisms by which US government ER/WM technologies will be transferred to the US private sector for commercialization and export to international markets. ITES has developed the following strategic objectives to implement its international goals: develop and implement EM`s policy for international programs in accordance with DOE and US Government policies and regulations; establish efficient and predictable international technology transfer mechanisms; assist the US private sector in the commercialization and deployment of federally funded EM technologies and related knowledge in international markets; leverage US and non-US resources to accelerate international development and regulatory acceptance of EM technologies; contribute to the improvement of EM`s training of US students, scientists, and managers on international environmental issues. A summary and descriptions of program activities and accomplishments are given for 17 programs which comprise the four main areas of the ITES program: Activities with the Former Soviet Union, International Technology Transfer, International Cooperation, and Information Systems and Publications. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

  2. International Technology Exchange Division: 1993 Annual report

    International Nuclear Information System (INIS)

    1993-01-01

    The Office of Technology Development (OTD) was established to ensure that reliable and acceptable technologies are available for implementation at DOE sites and that a technically trained work force is available to complete the EM mission by 2019. OTD established the International Technology Exchange Staff (ITES) to identify, evaluate, and acquire international technologies which can accelerate US DOE cleanup operations. ITES's goal is to pursue international collaboration among government organizations, educational institutions, and private industry to identify world-wide needs and available technologies that will meet US environmental needs in general, and EM cleanup needs in particular; and establish mechanisms by which US government ER/WM technologies will be transferred to the US private sector for commercialization and export to international markets. ITES has developed the following strategic objectives to implement its international goals: develop and implement EM's policy for international programs in accordance with DOE and US Government policies and regulations; establish efficient and predictable international technology transfer mechanisms; assist the US private sector in the commercialization and deployment of federally funded EM technologies and related knowledge in international markets; leverage US and non-US resources to accelerate international development and regulatory acceptance of EM technologies; contribute to the improvement of EM's training of US students, scientists, and managers on international environmental issues. A summary and descriptions of program activities and accomplishments are given for 17 programs which comprise the four main areas of the ITES program: Activities with the Former Soviet Union, International Technology Transfer, International Cooperation, and Information Systems and Publications. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database

  3. Laser Processed Condensing Heat Exchanger Technology Development

    Science.gov (United States)

    Hansen, Scott; Wright, Sarah; Wallace, Sarah; Hamilton, Tanner; Dennis, Alexander; Zuhlke, Craig; Roth, Nick; Sanders, John

    2017-01-01

    The reliance on non-permanent coatings in Condensing Heat Exchanger (CHX) designs is a significant technical issue to be solved before long-duration spaceflight can occur. Therefore, high reliability CHXs have been identified by the Evolvable Mars Campaign (EMC) as critical technologies needed to move beyond low earth orbit. The Laser Processed Condensing Heat Exchanger project aims to solve these problems through the use of femtosecond laser processed surfaces, which have unique wetting properties and potentially exhibit anti-microbial growth properties. These surfaces were investigated to identify if they would be suitable candidates for a replacement CHX surface. Among the areas researched in this project include microbial growth testing, siloxane flow testing in which laser processed surfaces were exposed to siloxanes in an air stream, and manufacturability.

  4. Technological Criteria Technology-Environmental under a Systemic Approach: Chemistry Technology Transfer

    OpenAIRE

    Durán-García Martín Enrique

    2014-01-01

    Currently the transfer of chemical technology is a process that contributes to the technology policy of a country, an industry or an organization in general chemistry. This process requires the application of clear criteria for the proper development of the complex interrelations in the transfer of chemical technology. A group of criteria that are present, are those related to environmental technology which intrinsically define the technology and its impact to the environment. Therefore, the ...

  5. Annual Report of Institute of Nuclear Chemistry and Technology 1998

    International Nuclear Information System (INIS)

    1999-04-01

    Actual edition of Annual Report is a full review of scientific activities of the Institute of Nuclear Chemistry and Technology (INCT), Warsaw, in 1998. The abstracts are presented in the following group of subjects: radiation chemistry and physics, radiation technologies (26); radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general (25); radiobiology (11); nuclear technologies and methods - process engineering (5); material engineering, structural studies and diagnostics (9); nucleonic control systems (7). The edition also included the list of INCT scientific publications and patents as well as information on conferences organized or co-organized by the INCT in 1998

  6. Institute of Nuclear Chemistry and Technology annual report 1995

    International Nuclear Information System (INIS)

    1996-01-01

    The report is a collection of short communications being a review of scientific activity of the Institute of Nuclear Chemistry and Technology (INCT), Warsaw, in 1995. The papers are gathered in several branches as follows: radiation chemistry and physics (15); radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general (23); radiobiology (7); nuclear technologies and methods (21); nucleonic control systems (5). The Annual Report of INCT - 1995 contains also a general information about the staff and organization of the Institute, the full list of scientific publications and patents, conferences organized by INCT, thesis and list of projects granted by Polish and international organizations

  7. Institute of Nuclear Chemistry and Technology annual report 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    The report is a collection of short communications being a review of scientific activity of the Institute of Nuclear Chemistry and Technology (INCT), Warsaw, in 1995. The papers are gathered in several branches as follows: radiation chemistry and physics (15); radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general (23); radiobiology (7); nuclear technologies and methods (21); nucleonic control systems (5). The Annual Report of INCT - 1995 contains also a general information about the staff and organization of the Institute, the full list of scientific publications and patents, conferences organized by INCT, thesis and list of projects granted by Polish and international organizations.

  8. Institute of Nuclear Chemistry and Technology annual report 1995

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    The report is a collection of short communications being a review of scientific activity of the Institute of Nuclear Chemistry and Technology (INCT), Warsaw, in 1995. The papers are gathered in several branches as follows: radiation chemistry and physics (15); radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general (23); radiobiology (7); nuclear technologies and methods (21); nucleonic control systems (5). The Annual Report of INCT - 1995 contains also a general information about the staff and organization of the Institute, the full list of scientific publications and patents, conferences organized by INCT, thesis and list of projects granted by Polish and international organizations.

  9. Chemistry of nuclear resources, technology, and waste

    International Nuclear Information System (INIS)

    Keller, O.L. Jr.

    1978-01-01

    Chemistry is being called on today to obtain useful results in areas that have been found very difficult for it in the past, but new instrumentation and new theories are allowing much progress. The area of hydrolytic phenomena and colloid chemistry, as exemplified by the plutonium polymer problem, is clearly entering a new phase in which it can be studied in a much more controlled and understandable manner. The same is true of the little studied interfacial regions, where so much important chemistry occurs in solvent extraction and other systems. The studies of the adsorption phenomena on clays are an illustration of the new and useful modeling of geochemical phenomena that is now possible. And finally, the chemist is called upon to participate in the developement and evaluation of models for nuclear waste isolation requiring extrapolations of hundreds to hundreds of thousands of years into the future. It is shown that chemistry may be useful in keeping the extrapolations in the shorter time spans, and also in selecting the best materials for containment. 36 figures

  10. JPRS Report, Science & Technology, USSR: Chemistry.

    Science.gov (United States)

    1987-07-15

    dust and gas emissions from ferrous and nonferrous metallurgical facilities on vegetable crops of 42 collective farms within a 10-15 km radius...the dust and gas wastes were determined to have adverse effects on vegetable crops. Tables 3. 12172/12379 CSO: 1841/299 43 FERTILIZERS...academy’s Institute of physical-Organic Chemistry, head of the republic large-scale program " Membrana "] [Abstract] The author assesses progress in

  11. Water chemistry technology. One of the key technologies for safe and reliable nuclear power plant operation

    International Nuclear Information System (INIS)

    Uchida, Shunsuke; Katsumura, Yosuke

    2013-01-01

    Water chemistry control is one of the key technologies to establish safe and reliable operation of nuclear power plants. Continuous and collaborative efforts of plant manufacturers and plant operator utilities have been focused on optimal water chemistry control, for which, a trio of requirements for water chemistry should be simultaneously satisfied: (1) better reliability of reactor structures and fuel rods; (2) lower occupational exposure and (3) fewer radwaste sources. Various groups in academia have carried out basic research to support the technical bases of water chemistry in plants. The Research Committee on Water Chemistry of the Atomic Energy Society of Japan (AESJ), which has now been reorganized as the Division of Water Chemistry (DWC) of AESJ, has played important roles to promote improvements in water chemistry control, to share knowledge about and experiences with water chemistry control among plant operators and manufacturers and to establish common technological bases for plant water chemistry and then to transfer them to the next generation of plant workers engaged in water chemistry. Furthermore, the DWC has tried and succeeded arranging R and D proposals for further improvement in water chemistry control through roadmap planning. In the paper, major achievements in plant technologies and in basic research studies of water chemistry in Japan are reviewed. The contributions of the DWC to the long-term safe management of the damaged reactors at the Fukushima Daiichi Nuclear Power Plant until their decommissioning are introduced. (author)

  12. Surface chemistry: Key to control and advance myriad technologies

    Science.gov (United States)

    Yates, John T.; Campbell, Charles T.

    2011-01-01

    This special issue on surface chemistry is introduced with a brief history of the field, a summary of the importance of surface chemistry in technological applications, a brief overview of some of the most important recent developments in this field, and a look forward to some of its most exciting future directions. This collection of invited articles is intended to provide a snapshot of current developments in the field, exemplify the state of the art in fundamental research in surface chemistry, and highlight some possibilities in the future. Here, we show how those articles fit together in the bigger picture of this field. PMID:21245359

  13. Overview of technologies to reprocess ion-exchange resins

    International Nuclear Information System (INIS)

    Gavrish, V.M.; Chernikova, N.P.; Ivanets, V.G.

    2010-01-01

    The article deals with overview of technologies for reprocessing of ion-exchange resins and determining the most optimal solutions for Ukraine. The technologies for cementations, thermal reprocessing, bituminization and deep decontamination are considered.

  14. American Chemical Society. Division of Nuclear Chemistry and Technology

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    The meeting of the 201st American Chemical Society Division of Nuclear Chemistry and Technology was comprised from a variety of topics in this field including: nuclear chemistry, nuclear physics, and nuclear techniques for environmental studies. Particular emphasis was given to fundamental research concerning nuclear structure (seven of the nineteen symposia) and studies of airborne particle monitoring and transport (five symposia). 105 papers were presented

  15. EPR Studies of Spin-Spin Exchange Processes: A Physical Chemistry Experiment.

    Science.gov (United States)

    Eastman, Michael P.

    1982-01-01

    Theoretical background, experimental procedures, and analysis of experimental results are provided for an undergraduate physical chemistry experiment on electron paramagnetic resonance (EPR) linewidths. Source of line broadening observed in a spin-spin exchange process between radicals formed in aqueous solutions of potassium peroxylamine…

  16. Sustainable technological development in chemistry. Improving the quality of life through chemistry and agriculture

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-08-01

    The importance of agricultural products, their potential conversion to energy sources and their applications for fibre-reinforced construction materials is emphasized. Another potentially important technology is the conversion of sunlight into electricity such as occurs in the leaves of plants. Parallels with nature exist, even though conversions with inorganic materials have, until now, been promising. The ability to control chemical reactions is the subject throughout all the following chapters. The goal is to achieve high reaction efficiencies and to use fewer basic materials, both of which will lead to a reduction in environmental stress. Sustainable developments in chemistry can be described by two approaches: (1) Improvements in society, with challenges for chemistry; and (2) Improvement in the chemical sector itself. Both approaches are dealt with in this report. Five areas for development have been chosen in the discussions for `DTO-Chemie`: Integrated plant conversion (IPC), in particular Valorisation of plant parts for raw materials and energy; Biomass conversion (C1 Chemistry), in particular Technologies for (among others) C1-based chemicals and energy carriers; Photovoltaic cells (PSC), in particular Technologies for the conversion of solar light into electricity; Process Technology in Fine chemistry (PFC), in particular Methodology of manufacturing processes for Fine chemicals; and Sustainable Construction Materials (FRC); in particular Techniques for using fibre-reinforced composites in construction applications. These areas can be viewed as clusters of technologies, with a strong chemistry and agricultural component, which are necessary for achieving a sustainable future. Furthermore, it is important to recognise that technology requires a progressive development (technology lifecycle). The five areas of technology development are tested against a number of criteria: (1) Sustainability / leap / volume; (2) Horizon 2050; (3) Commitment from industry

  17. Annual report of Institute of Nuclear Chemistry and Technology 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-06-01

    The report is a collection of short communications being a review of the scientific activities of the Institute of Nuclear Chemistry and Technology, Warsaw in 1996. The papers are gathered in several branches as follows: radiation chemistry and physics (17); Radiochemistry, stable isotopes, nuclear analytical methods,chemistry in general (20); radiobiology (9); nuclear technologies and methods (28).The last and biggest chapter has been divided in four smaller groups; process engineering; material engineering,structural studies,diagnostics; radiation technologies; nucleonic control systems. The annual report of INCT-1996 contains also a general information of Institute, the full list of scientific publications and patents, conferences organized by INCT, Ph.D. and D.Sc. thesis, a list of projects granted by Polish Committee of Scientific Research and other organizations.

  18. Annual report of Institute of Nuclear Chemistry and Technology 1996

    International Nuclear Information System (INIS)

    1997-06-01

    The report is a collection of short communications being a review of the scientific activities of the Institute of Nuclear Chemistry and Technology, Warsaw in 1996. The papers are gathered in several branches as follows: radiation chemistry and physics (17); Radiochemistry, stable isotopes, nuclear analytical methods,chemistry in general (20); radiobiology (9); nuclear technologies and methods (28).The last and biggest chapter has been divided in four smaller groups; process engineering; material engineering,structural studies,diagnostics; radiation technologies; nucleonic control systems. The annual report of INCT-1996 contains also a general information of Institute, the full list of scientific publications and patents, conferences organized by INCT, Ph.D. and D.Sc. thesis, a list of projects granted by Polish Committee of Scientific Research and other organizations

  19. Handbook of green chemistry and technology

    Energy Technology Data Exchange (ETDEWEB)

    Clark, J.; MacQuarrie, D. (eds.)

    2002-05-15

    Sustainable development is now accepted as a necessary goal for achieving societal, economic and environmental objectives. Within this chemistry has a vital role to play. The chemical industry is successful but traditionally success has come at a heavy cost to the environment. The challenge for chemists and others is to develop new products, processes and services that achieve societal, economic and environmental benefits. This requires an approach that reduces the materials and energy intensity of chemical processes and products; minimises the dispersion of harmful chemicals in the environment; maximises the use of renewable resources and extends the durability and recyclability of products in a way that increases industrial competitiveness as well as improve its tarnished image. (author)

  20. Technology and Bloom's Taxonomy: Tools to Facilitate Higher-Level Learning in Chemistry

    National Research Council Canada - National Science Library

    Morgan, Matthew

    1997-01-01

    This research project ties together chemistry data acquisition technology, introductory chemistry laboratory experiments, and Bloom's Taxonomy of Educational Objectives into a unified learning model...

  1. Institute of Nuclear Chemistry and Technology annual report 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    This annual report is a collection of short communications being a review of scientific activity of the Institute of Nuclear Chemistry and Technology, Warsaw, Poland in 1994. The papers are gathered into several branches as follows: radiation chemistry and physics (16 papers); radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general (17 papers); radiobiology (6 papers); nuclear technologies and methods (30 papers). The annual report of INCT-1994 contains also a general information about the Institute, the full list of papers published in 1994, information about Nukleonika - the International Journal of Nuclear Research being edited in INCT, the list of patent granted and patent applications in 1994, information about conferences organized by the Institute, the list of Ph.D. and D.Sc. finished in 1994 as well as the list of research projects and contracts being realized in INCT during 1994.

  2. Institute of Nuclear Chemistry and Technology annual report 1994

    International Nuclear Information System (INIS)

    1995-01-01

    This annual report is a collection of short communications being a review of scientific activity of the Institute of Nuclear Chemistry and Technology, Warsaw, Poland in 1994. The papers are gathered into several branches as follows: radiation chemistry and physics (16 papers); radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general (17 papers); radiobiology (6 papers); nuclear technologies and methods (30 papers). The annual report of INCT-1994 contains also a general information about the Institute, the full list of papers published in 1994, information about Nukleonika - the International Journal of Nuclear Research being edited in INCT, the list of patent granted and patent applications in 1994, information about conferences organized by the Institute, the list of Ph.D. and D.Sc. finished in 1994 as well as the list of research projects and contracts being realized in INCT during 1994

  3. Institute of Nuclear Chemistry and Technology annual report 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-12-31

    This annual report is a collection of short communications being a review of scientific activity of the Institute of Nuclear Chemistry and Technology, Warsaw, Poland in 1994. The papers are gathered into several branches as follows: radiation chemistry and physics (16 papers); radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general (17 papers); radiobiology (6 papers); nuclear technologies and methods (30 papers). The annual report of INCT-1994 contains also a general information about the Institute, the full list of papers published in 1994, information about Nukleonika - the International Journal of Nuclear Research being edited in INCT, the list of patent granted and patent applications in 1994, information about conferences organized by the Institute, the list of Ph.D. and D.Sc. finished in 1994 as well as the list of research projects and contracts being realized in INCT during 1994.

  4. A Laboratory Course in Technological Chemistry.

    Science.gov (United States)

    Wiseman, P.

    1986-01-01

    Describes a laboratory course taught at the University of Manchester Institute of Science and Technology (United Kingdom) which focuses on the preparation, properties, and applications of end-use products of the chemical industry. Outlines laboratory experiments on dyes, fibers, herbicides, performance testing, antioxidants, and surface active…

  5. JPRS Report, Science & Technology USSR: Chemistry

    Science.gov (United States)

    1991-05-02

    microfiltration , including sterilizing filtration and ultrafiltration or diafiltration, and to develop a technological plan and arrangement of hard...ware for separation and purification of biological prep- arations. A plan is suggested for combined utilization of prefiltration, microfiltration ...linked polyurethane elastomers, segmented polyurethanes are characterized by creep and are not fully restored after cyclic loads. Reducing these

  6. Technological Criteria Technology-Environmental under a Systemic Approach: Chemistry Technology Transfer

    Directory of Open Access Journals (Sweden)

    Durán-García Martín Enrique

    2014-07-01

    Full Text Available Currently the transfer of chemical technology is a process that contributes to the technology policy of a country, an industry or an organization in general chemistry. This process requires the application of clear criteria for the proper development of the complex interrelations in the transfer of chemical technology. A group of criteria that are present, are those related to environmental technology which intrinsically define the technology and its impact to the environment. Therefore, the transfer of chemical technology requires technological-environmental criteria defining, in conjunction with other criteria, an adequate process for the selection, acquisition and incorporation of technology in a holistic perspective, so it provides feasible solutions the chemical industry in pursuit of their goals. Then the criterion becomes a benchmark for assessing an appropriate technology transfer process. We performed a theoretical analysis of the technological and environmental criteria, proposing thirty-six (36 technological-environmental criteria interrelated under a systemic approach in the process of transfer of chemical technology, focused on a methodological cycle first run, based primarily on the research-action method. Future research is expected to make a refinement of the criteria from the formulation and validation of metrics so that necessary adjustments are made to optimize the process of transfer of chemical technology.

  7. Recoil chemistry and solid state exchange in cobalt complexes : a new model

    International Nuclear Information System (INIS)

    Ramshesh, V.

    1981-01-01

    During the last thirty years considerable work has been done on various aspects of recoil chemistry and solid state exchange in cobalt complexes. Several interesting features such as 'oxygen effect', 'water of hydration effect', 'dilution with isomorphous materials', etc., have been observed. These data led workers to reject the older hypothesis based on 'fragmentation' and 'recombination' and suggest models based on exciton or electron induced exchange. However some recent data show that perhaps both the processes viz., thermal annealing in n-irradiated systems and solid state exchange are not bulk processes. This has led the author to propose a new model. In this model greater emphasis is placed on dissociation reactions followed by recombination and/or exchange reactions. (author)

  8. Chemistry programmes at a technological and nuclear centre

    International Nuclear Information System (INIS)

    Servian, J.L.

    1984-01-01

    The application of chemical principles and techniques have played a major role in the development of nuclear sciences and technology. The discovery of radioactivity, the isolation of radium and polonium, the discovery of artificial radioactivity and nuclear fission and the production of transuranium elements are historical landmarks that show the prominent role performed by chemistry. The purpose of this paper is to summarize the chemistry areas and experimental facilities for programmes of training, research and development, and service that might be designed for implementation at the Centre when appropriate. Though the areas are separately presented for analysis, they are closely related among themselves and also related to other activities of the Centre. (author)

  9. Progress in the medicinal chemistry of silicon: C/Si exchange and beyond.

    Science.gov (United States)

    Fujii, Shinya; Hashimoto, Yuichi

    2017-04-01

    Application of silyl functionalities is one of the most promising strategies among various 'elements chemistry' approaches for the development of novel and distinctive drug candidates. Replacement of one or more carbon atoms of various biologically active compounds with silicon (so-called sila-substitution) has been intensively studied for decades, and is often effective for alteration of activity profile and improvement of metabolic profile. In addition to simple C/Si exchange, several novel approaches for utilizing silicon in medicinal chemistry have been suggested in recent years, focusing on the intrinsic differences between silicon and carbon. Sila-substitution offers great potential for enlarging the chemical space of medicinal chemistry, and provides many options for structural development of drug candidates.

  10. The Chemistry of Atmosphere-Forest Exchange (CAFE Model – Part 1: Model description and characterization

    Directory of Open Access Journals (Sweden)

    G. M. Wolfe

    2011-01-01

    Full Text Available We present the Chemistry of Atmosphere-Forest Exchange (CAFE model, a vertically-resolved 1-D chemical transport model designed to probe the details of near-surface reactive gas exchange. CAFE integrates all key processes, including turbulent diffusion, emission, deposition and chemistry, throughout the forest canopy and mixed layer. CAFE utilizes the Master Chemical Mechanism (MCM and is the first model of its kind to incorporate a suite of reactions for the oxidation of monoterpenes and sesquiterpenes, providing a more comprehensive description of the oxidative chemistry occurring within and above the forest. We use CAFE to simulate a young Ponderosa pine forest in the Sierra Nevada, CA. Utilizing meteorological constraints from the BEARPEX-2007 field campaign, we assess the sensitivity of modeled fluxes to parameterizations of diffusion, laminar sublayer resistance and radiation extinction. To characterize the general chemical environment of this forest, we also present modeled mixing ratio profiles of biogenic hydrocarbons, hydrogen oxides and reactive nitrogen. The vertical profiles of these species demonstrate a range of structures and gradients that reflect the interplay of physical and chemical processes within the forest canopy, which can influence net exchange.

  11. Implications of WWW technologies for exchanging medical records

    Directory of Open Access Journals (Sweden)

    Maurice Dixon

    1999-09-01

    Full Text Available This article addresses some of the implications for medical record exchange of very recent developments in technology and tools that support the World Wide Web. It argues that XML (Extensible Mark-up Language is a very good enabling technology for medical record exchange. XML provides a much cheaper way of executing the exchange of medical information that circumvents the need for proprietary software. Use of XML can also simplify solutions to the problems associated with coping with the evolution of medical systems in time. However XML on its own does not resolve all the semantic heterogeneities.

  12. The role of cation exchange in controlling groundwater chemistry at Aspo, Sweden

    International Nuclear Information System (INIS)

    Viani, B.E.; Bruton, C.J.

    1995-01-01

    Construction-induced groundwater flow has resulted in the mixing of relatively dilute shallow groundwater with more concentrated groundwater at depth in the underground Hard Rock Laboratory (HRL) at Aespoe, Sweden. The observed compositional variation of the mixed groundwater cannot be explained using a conservative mixing model. The geochemical modeling package EQ3/6, to which a cation-exchange model was added, was used to simulate mixing between the two fluids. The results of modeling simulations suggest that cation exchange between groundwater and fracture-lining clays can explain the major element fluid chemistry observed in the HRL. The quantity of exchanger required to match simulated with observed fluid chemistry is reasonable and is consistent with the observed fracture mineralogy. This preliminary study establishes cation exchange as a viable mechanism for controlling the chemical evolution of groundwaters in a fracture-dominated dynamic flow system. This modeling study also strengthens their confidence in the ability to model the potential effects of fracture-lining minerals on the transport of radionuclides in a high level nuclear waste repository

  13. Chemistry and technology of radioactive waste management - the IAEA perspective

    International Nuclear Information System (INIS)

    Efremenkov, V.M.; )

    2003-01-01

    The paper refers the consideration of chemical composition of radioactive waste in selection of particular method and technology for waste treatment and conditioning, importance of physico-chemical parameters of waste processing techniques for optimisation of waste processing to produce waste form of appropriate quality. Consideration of waste chemistry is illustrated by several IAEA activities on radioactive waste management and by outlining the scope of some selected technical reports on different waste management subjects. Different components of the IAEA activities on radioactive waste management and on technology transfer are presented and discussed. (author)

  14. Contribution of microreactor technology and flow chemistry to the development of green and sustainable synthesis

    Directory of Open Access Journals (Sweden)

    Flavio Fanelli

    2017-03-01

    Full Text Available Microreactor technology and flow chemistry could play an important role in the development of green and sustainable synthetic processes. In this review, some recent relevant examples in the field of flash chemistry, catalysis, hazardous chemistry and continuous flow processing are described. Selected examples highlight the role that flow chemistry could play in the near future for a sustainable development.

  15. Contribution of microreactor technology and flow chemistry to the development of green and sustainable synthesis.

    Science.gov (United States)

    Fanelli, Flavio; Parisi, Giovanna; Degennaro, Leonardo; Luisi, Renzo

    2017-01-01

    Microreactor technology and flow chemistry could play an important role in the development of green and sustainable synthetic processes. In this review, some recent relevant examples in the field of flash chemistry, catalysis, hazardous chemistry and continuous flow processing are described. Selected examples highlight the role that flow chemistry could play in the near future for a sustainable development.

  16. Analytical chemistry in nuclear science and technology: a scientometric mapping

    International Nuclear Information System (INIS)

    Kademani, B.S.; Kumar, Anil; Kumar, Vijai

    2007-01-01

    This paper attempts to analyse quantitatively the growth and development of Analytical Chemistry research in Nuclear Science and Technology in terms of publication output as reflected in International Nuclear Information System (INIS) database (1970-2005). During 1970-2005 a total of 8224 papers were published. There were only seven papers published in 1970. Thereafter, a tremendous explosion of literature was observed in this area. The highest number of papers (636) were published in 1985. The average number of publications published per year was 228.44. United States topped the list with 1811 publications followed by USSR with 1688 publications, Germany with 777 publications, India with 730 publications and Hungary with 519 publications. Authorship and collaboration trend was towards multi-authored papers as 80.3 percent of the papers were collaborative is indicative of the multidisciplinary nature of research activity. The most prolific authors were: B. F. Myasoedov, AN SSSR Moscow Inst. Geokhimii I Analitisheskoi Khimii, Russian Federation with 84 publications, M. Sudersanan, Bhabha Atomic Research Centre, Mumbai, India with 67 publications, P.Vanura and V. Jedinakova Krizova both from Institute of Chemical Technology, Prague, Czech Republic with 54 publications each, S. Gangadharan, Bhabha Atomic Research Centre, Mumbai, India with 47 publications, V.M. Ivanova , M.V. Lomonosov Moscow State University, Russian Federation with 45 publications and Yu. A Zolotov Lomonosov Moscow State University, Russian Federation with 40 publications. The journals most preferred by the scientists for publication of papers were : Zhurnal Analiticheskoj Khimii with 713 papers, Journal of Radioanalytical and Nuclear Chemistry with 409 papers, Analytical Chemistry Washington with 364 papers, Fresenius' Journal of Analytical Chemistry with 324 papers, Indian Journal of Chemistry, Section A with 251 papers, and Journal of Analytical Chemistry of the USSR with 145 papers. The high

  17. Annual Report 2003 of the Institute of Nuclear Chemistry and Technology

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    The INCT 2003 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies, nucleonic control systems and accelerators.

  18. Annual Report 2003 of the Institute of Nuclear Chemistry and Technology

    International Nuclear Information System (INIS)

    2004-01-01

    The INCT 2003 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies, nucleonic control systems and accelerators

  19. Karlsruhe international conference on analytical chemistry in nuclear technology

    International Nuclear Information System (INIS)

    1985-01-01

    This volume presents 218 abstracts of contributions by researchers working in the analytical chemistry field of nuclear technology. The majority of the papers deal with analysis with respect to process control in fuel reprocessing plants, fission and corrosion product characterization throughout the fuel cycle as well as studies of the chemical composition of radioactive wastes. Great interest is taken in the development and optimization of methods and instrumentation especially for in-line process control. About 3/4 of the papers have been entered into the data base separately. (RB)

  20. Compact heat exchanger technologies for the HTRs recuperator application

    International Nuclear Information System (INIS)

    Thonon, B.; Breuil, E.

    2001-01-01

    Modern HTR nuclear power plants which are now under development (projects GT-MHR, PBMR) are based on the direct cycle concept. This concept leads to a more important efficiency compared to the steam cycle but requires the use of high performance components such as an helium/helium heat exchanger called recuperator to guarantee the cycle efficiency. Using this concept, a net plant efficiency of around 50% can be achieved in the case of an electricity generating plant. As geometric constraints are particularly important for such a gas reactor to limit the size of the primary vessels, compact heat exchangers operating at high pressure and high temperature are attractive potential solutions for the recuperator application. In this frame, Framatome and CEA have reviewed the various technologies of compact heat exchangers used in industry. The first part of the paper will give a short description of the heat exchangers technologies and their ranges of application. In a second part, a selection of potential compact heat exchangers technologies are proposed for the recuperator application. This selection will be based upon their capabilities to cope with the operating conditions parameters (pressure, temperature, flow rate) and with other parameters such as fouling, corrosion, compactness, weight, maintenance and reliability. (author)

  1. Safety technology for air-cooled heat exchangers

    International Nuclear Information System (INIS)

    Kawai, Masafumi; Miyamoto, Hitoshi

    2011-01-01

    The air-cooled heat exchanger is a device that enables a large amount of heat exchange (cooling) by utilizing the atmosphere as a stable and infinite heat sink. It is widely used in general industrial plants, and nowadays it is also utilized in nuclear facilities. This type of exchanger is advantageous in that it can be constructed in any location without having to be near the sea or rivers. It can be operated safely if a natural disaster, such as a tsunami or flood, occurs, thus contributing to the safety of the mother facility. IHI's air-cooled heat exchangers are designed to ensure safe operation and withstand a large earthquake or severe atmospheric conditions. This report describes the technologies used to establish these safety features and their performance. (author)

  2. Measurement and Characterization of Hydrogen-Deuterium Exchange Chemistry Using Relaxation Dispersion NMR Spectroscopy.

    Science.gov (United States)

    Khirich, Gennady; Holliday, Michael J; Lin, Jasper C; Nandy, Aditya

    2018-03-01

    One-dimensional heteronuclear relaxation dispersion NMR spectroscopy at 13 C natural abundance successfully characterized the dynamics of the hydrogen-deuterium exchange reaction occurring at the N ε position in l-arginine by monitoring C δ in varying amounts of D 2 O. A small equilibrium isotope effect was observed and quantified, corresponding to ΔG = -0.14 kcal mol -1 . A bimolecular rate constant of k D = 5.1 × 10 9 s -1 M -1 was determined from the pH*-dependence of k ex (where pH* is the direct electrode reading of pH in 10% D 2 O and k ex is the nuclear spin exchange rate constant), consistent with diffusion-controlled kinetics. The measurement of ΔG serves to bridge the millisecond time scale lifetimes of the detectable positively charged arginine species with the nanosecond time scale lifetime of the nonobservable low-populated neutral arginine intermediate species, thus allowing for characterization of the equilibrium lifetimes of the various arginine species in solution as a function of fractional solvent deuterium content. Despite the system being in fast exchange on the chemical shift time scale, the magnitude of the secondary isotope shift due to the exchange reaction at N ε was accurately measured to be 0.12 ppm directly from curve-fitting D 2 O-dependent dispersion data collected at a single static field strength. These results indicate that relaxation dispersion NMR spectroscopy is a robust and general method for studying base-catalyzed hydrogen-deuterium exchange chemistry at equilibrium.

  3. Physics and chemistry of plasma pollution control technology

    International Nuclear Information System (INIS)

    Chang, J S

    2008-01-01

    Gaseous pollution control technologies for acid gases (NO x , SO x , etc), volatile organic compounds, greenhouse gases, ozone layer depleting substances, etc have been commercialized based on catalysis, incineration and adsorption methods. However, non-thermal plasma techniques based on electron beams and corona discharges are becoming significant due to advantages such as lower costs, higher removal efficiency and smaller space volume. In order to commercialize this new technology, the pollution gas removal rate, energy efficiency of removal, pressure drop of reactors and useable by-product production rates must be improved and identification of major fundamental processes and optimizations of reactor and power supply for an integrated system must be investigated. In this work, the chemistry and physics of plasma pollution control are discussed and the limitation of this type of plasma is outlined based on the plasma parameters.

  4. Water chemistry - one of the key technologies for safe and reliable nuclear power plant operation

    International Nuclear Information System (INIS)

    Uchida, S.; Otoha, K.; Ishigure, K.

    2006-01-01

    Full text: Full text: Water chemistry control is one of the key technologies to establish safe and reliable operation of nuclear power plants. Continuous and collaborative efforts of plant manufacturers and plant operator utilities have been focused on optimal water chemistry control, for which, a trio of requirements for water chemistry, a) better reliability of reactor structures and fuels, b) lower occupational exposure, and c) fewer radwaste sources, should be simultaneously satisfied. The research committee related to water chemistry of the Atomic Energy Society of Japan has played important roles to enhance improvement in water chemistry control, to share knowledge and experience with water chemistry among plant operators and manufacturers, to establish common technological bases for plant water chemistry and then to transfer them to the next generation related to water chemistry. Furthermore, the committee has tried to contribute to arranging R and D proposals for further improvement in water chemistry control through road map planning

  5. F- and H-Area Seepage Basins Water Treatment System Process Optimization and Alternative Chemistry Ion Exchange/Sorbent Material Screening Clearwell Overflow Study

    Energy Technology Data Exchange (ETDEWEB)

    Serkiz, S.M.

    2000-08-30

    This study investigated alternative ion exchange/sorbent materials and polishing chemistries designed to remove specific radionuclides not removed during the neutralization/precipitation/clarification process.

  6. Effect of cation exchange of major cation chemistry in the large scale redox experiment at Aespoe. Revision 1

    International Nuclear Information System (INIS)

    Viani, B.E.; Bruton, C.J.

    1996-06-01

    Geochemical modeling was used to test the hypothesis that cation exchange with fracture-lining clays during fluid mixing in the Aespoe Hard Rock Laboratory can significantly affect major element chemistry. Conservative mixing models do not adequately account for changes in Na, Ca and Mg concentrations during mixing. Mixing between relatively dilute shallow waters and more concentrated waters at depth along fracture zones was modeled using the EQ3/6 geochemical modeling package. A cation exchange model was added to the code to describe simultaneously aqueous speciation, mineral precipitation/dissolution, and equilibration between a fluid and a cation exchanger. Fluid chemistries predicted to result from mixing were compared with those monitored from boreholes intersecting the fracture zone. Modeling results suggest that less than 0.1 equivalent of a smectite exchanger per liter of groundwater is necessary to account for discrepancies between predictions from a conservative mixing model and measured Na and Ca concentrations. This quantity of exchanger equates to an effective fracture coating thickness of 20 microm or less given a fracture aperture width of 1,000 microm or less. Trends in cation ratios in the fluid cannot be used to predict trends in cation ratios on the exchanger because of the influence of ionic strength on heterovalent exchange equilibrium. It is expected that Na for Ca exchange will dominate when shallow waters such as HBHO2 are mixed with deeper waters. In contrast, Na for Mg exchange will dominate mixing between deeper waters

  7. Annual Report of the Institute of Nuclear Chemistry and Technology 2000

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-06-01

    The INCT 2000 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics and nucleonic control systems and accelerators.

  8. Annual Report of the Institute of Nuclear Chemistry and Technology 2000

    International Nuclear Information System (INIS)

    2001-06-01

    The INCT 2000 Annual Report is the review of scientific activities in all branches being developed in the Institute of Nuclear Chemistry and Technology Warsaw. The studies are connected in general with the following fields: radiation chemistry and physics, radiation technologies, radiochemistry, stable isotopes, nuclear analytical methods, chemistry in general, radiobiology, process engineering, material engineering, structural studies and diagnostics and nucleonic control systems and accelerators

  9. Proceedings of the specialists' meeting on the chemistry and technology of actinide elements 2011

    International Nuclear Information System (INIS)

    Ikeda, Yasuhisa; Yamana, Hajimu

    2012-07-01

    This report contains the Proceedings of the 17th Specialists' Meeting on the Chemistry and Technology of Actinide Elements, which was held at Research Reactor Institute, Kyoto University, on February 15, 2012. This specialists' meeting has been held annually since 1994, and this is the 17th meeting for the fiscal year 2011. The accident of Fukushima Daiich Nuclear Power Plant, which occurred on March 11, 2011, showed the presence of defect in Japanese past approach to keep nuclear system safe. There is the need to improve existing technological and operational problems, as well as regulatory problems, but we should be aware of the significance of recovering social trust and peoples' peace of mind with the nuclear power. It should be noted that public's anxiety on the backend issue of nuclear system is remarkably big, and thus we must try to provide an understandable solution to them. In this meeting, we dealt with actinide chemistry and technology, which are related to the advanced nuclear fuel cycle development and the disposal of the HLW or TRU wastes. This is because, in the backend of the nuclear system, Actinide and TRU elements have substantial importance, because all of reprocessing, geologic disposal, and partitioning and transmutation depend significantly on the chemistry and technology of Actinides. Therefore, we have continued discussion and information exchange on the Actinide issues over 16 years, and this year's 17th meeting had a special meaning as the first one after the accident. In this context in this 17th meeting, we tried to return to the fundamentals of molten salt chemistry, which is the base of the dry reprocessing development. In addition, in order to expand our attitude by crossing over the fence of nuclear society, we tried to explore the potential of the adoption of molten salt chemistry to the general industry. This was a small new attempt in compliance with the recent tendency to nuclear power reduction in

  10. ORGANIZATIONAL, LEGAL AND TECHNOLOGICAL ASPECTS OF HEALTH INFORMATION EXCHANGE

    Directory of Open Access Journals (Sweden)

    N. A. Karasev

    2017-01-01

    Full Text Available The article discusses organizational and legal aspects of electronic health information exchange in developed countries, particularly, introduction of electronic medical records in the United States and Europe, as well as topical issues related to standardization of information technologies in health care. We briefly describe the most popular standards used in e-medicine, such as Digital Imaging and Communications in Medicine (DICOM, openEHR and HL7. The questions of syntactic and semantic interoperability in the exchange of electronic medical records and some aspects of the digital signature use are also considered. We suggest mechanisms for implementation of electronic document management and sharing of digital medical information, as one of the most important directions of information technologies in health care. It is noted that today, the main limiting factor in providing the digital exchange of health information in Russian Federation is unresolved legal issues, i.e. the absence of a legal framework of electronic medical records share. At the same time, the level of IT development in our country is quite sufficient to meet current challenges. It is stated that, despite the unresolved number of problems (for example, completeness of medical data on a patient, given to relatives in critical situations, the adoption of a single electronic card is able to bring medical care to a new level, especially in emergency and urgent medicine.

  11. Enabling Detailed Energy Analyses via the Technology Performance Exchange: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Studer, D.; Fleming, K.; Lee, E.; Livingood, W.

    2014-08-01

    One of the key tenets to increasing adoption of energy efficiency solutions in the built environment is improving confidence in energy performance. Current industry practices make extensive use of predictive modeling, often via the use of sophisticated hourly or sub-hourly energy simulation programs, to account for site-specific parameters (e.g., climate zone, hours of operation, and space type) and arrive at a performance estimate. While such methods are highly precise, they invariably provide less than ideal accuracy due to a lack of high-quality, foundational energy performance input data. The Technology Performance Exchange was constructed to allow the transparent sharing of foundational, product-specific energy performance data, and leverages significant, external engineering efforts and a modular architecture to efficiently identify and codify the minimum information necessary to accurately predict product energy performance. This strongly-typed database resource represents a novel solution to a difficult and established problem. One of the most exciting benefits is the way in which the Technology Performance Exchange's application programming interface has been leveraged to integrate contributed foundational data into the Building Component Library. Via a series of scripts, data is automatically translated and parsed into the Building Component Library in a format that is immediately usable to the energy modeling community. This paper (1) presents a high-level overview of the project drivers and the structure of the Technology Performance Exchange; (2) offers a detailed examination of how technologies are incorporated and translated into powerful energy modeling code snippets; and (3) examines several benefits of this robust workflow.

  12. Learning How to Teach Chemistry with Technology: Pre-Service Teachers' Experiences with Integrating Technology into Their Learning and Teaching

    Science.gov (United States)

    Chittleborough, Gail

    2014-06-01

    The Australian Government initiative, Teaching Teachers for the Future (TTF), was a targeted response to improve the preparation of future teachers with integrating technology into their practice. This paper reports on TTF research involving 28 preservice teachers undertaking a chemistry curriculum studies unit that adopted a technological focus. For chemistry teaching the results showed that technological knowledge augmented the fundamental pedagogical knowledge necessary for teaching chemistry content. All the pre-service teachers demonstrated an understanding of the role of technology in teaching and learning and reported an increased skill level in a variety of technologies, many they had not used previously. Some students were sceptical about this learning when schools did not have technological resources available. This paper argues that teacher education courses should include technological skills that match those available in schools, as well as introduce new technologies to support a change in the culture of using technology in schools.

  13. Pressurized fluidized-bed combustion technology exchange workshop

    Energy Technology Data Exchange (ETDEWEB)

    ,

    1980-04-01

    The pressurized fluidized-bed combustion technology exchange workshop was held June 5 and 6, 1979, at The Meadowlands Hilton Hotel, Secaucus, New Jersey. Eleven papers have been entered individually into EDB and ERA. The papers include reviews of the US DOE and EPRI programs in this area and papers by Swedish, West German, British and American organizations. The British papers concern the joint program of the USA, UK and FRG at Leatherhead. The key factor in several papers is the use of fluidized bed combustors, gas turbines, and steam turbines in combined-cycle power plants. One paper examines several combined-cycle alternatives. (LTN)

  14. HEALTH INFORMATION TECHNOLOGY IN EXCHANGE OF HEALTH INFORMATION

    Directory of Open Access Journals (Sweden)

    Jordan Deliversky

    2016-06-01

    Full Text Available Health information technology involves the exchange of health information in an electronic environment. Data protection is comprised of many elements, including where the data resides, how it is used, and who has access to it. Individually identifiable health information should be protected with reasonable administrative, technical, and physical safeguards to ensure its confidentiality, integrity, and availability and to prevent unauthorized access, use, or disclosure. Health records are among the most sensitive records available containing information concerning an individual. The unauthorized disclosure of a medical condition or diagnosis could negatively impact an individual’s personal and professional life.

  15. Information Retrieval and Text Mining Technologies for Chemistry.

    Science.gov (United States)

    Krallinger, Martin; Rabal, Obdulia; Lourenço, Anália; Oyarzabal, Julen; Valencia, Alfonso

    2017-06-28

    Efficient access to chemical information contained in scientific literature, patents, technical reports, or the web is a pressing need shared by researchers and patent attorneys from different chemical disciplines. Retrieval of important chemical information in most cases starts with finding relevant documents for a particular chemical compound or family. Targeted retrieval of chemical documents is closely connected to the automatic recognition of chemical entities in the text, which commonly involves the extraction of the entire list of chemicals mentioned in a document, including any associated information. In this Review, we provide a comprehensive and in-depth description of fundamental concepts, technical implementations, and current technologies for meeting these information demands. A strong focus is placed on community challenges addressing systems performance, more particularly CHEMDNER and CHEMDNER patents tasks of BioCreative IV and V, respectively. Considering the growing interest in the construction of automatically annotated chemical knowledge bases that integrate chemical information and biological data, cheminformatics approaches for mapping the extracted chemical names into chemical structures and their subsequent annotation together with text mining applications for linking chemistry with biological information are also presented. Finally, future trends and current challenges are highlighted as a roadmap proposal for research in this emerging field.

  16. Effects of `Environmental Chemistry' Elective Course Via Technology-Embedded Scientific Inquiry Model on Some Variables

    Science.gov (United States)

    Çalik, Muammer; Özsevgeç, Tuncay; Ebenezer, Jazlin; Artun, Hüseyin; Küçük, Zeynel

    2014-06-01

    The purpose of this study is to examine the effects of `environmental chemistry' elective course via Technology-Embedded Scientific Inquiry (TESI) model on senior science student teachers' (SSSTs) conceptions of environmental chemistry concepts/issues, attitudes toward chemistry, and technological pedagogical content knowledge (TPACK) levels. Within one group pre-test-post-test design, the study was conducted with 117 SSSTs (68 females and 49 males—aged 21-23 years) enrolled in an `environmental chemistry' elective course in the spring semester of 2011-2012 academic-years. Instruments for data collection comprised of Environmental Chemistry Conceptual Understanding Questionnaire, TPACK survey, and Chemistry Attitudes and Experiences Questionnaire. Significant increases in the SSSTs' conceptions of environmental chemistry concepts/issues, attitudes toward chemistry, and TPACK levels are attributed to the SSSTs learning how to use the innovative technologies in the contexts of the `environmental chemistry' elective course and teaching practicum. The study implies that the TESI model may serve a useful purpose in experimental science courses that use the innovative technologies. However, to generalize feasibility of the TESI model, it should be evaluated with SSSTs in diverse learning contexts.

  17. Liquid Salt Heat Exchanger Technology for VHTR Based Applications

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, Mark; Sridhara, Kumar; Allen, Todd; Peterson, Per

    2012-10-11

    The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat transfer fluid; however, the tube size requirements and the power associated with pumping helium may not be economical. Recent work on liquid salts has shown tremendous potential to transport high-temperature heat efficiently at low pressures over long distances. This project has two broad objectives: To investigate the compatibility of Incoloy 617 and coated and uncoated SiC ceramic composite with MgCl2-KCl molten salt to determine component lifetimes and aid in the design of heat exchangers and piping; and, To conduct the necessary research on the development of metallic and ceramic heat exchangers, which are needed for both the helium-to-salt side and salt-to-process side, with the goal of making these heat exchangers technologically viable. The research will consist of three separate tasks. The first task deals with material compatibility issues with liquid salt and the development of techniques for on-line measurement of corrosion products, which can be used to measure material loss in heat exchangers. Researchers will examine static corrosion of candidate materials in specific high-temperature heat transfer salt systems and develop an in situ electrochemical probe to measure metallic species concentrations dissolved in the liquid salt. The second task deals with the design of both the intermediate and process side heat exchanger systems. Researchers will optimize heat exchanger design and study issues related to corrosion, fabrication, and thermal stresses using commercial and in-house codes. The third task focuses integral testing of flowing liquid salts in a heat transfer/materials loop to determine potential issues of using the salts and to capture realistic behavior of the salts in a

  18. Current status and future prospects for enabling chemistry technology in the drug discovery process.

    Science.gov (United States)

    Djuric, Stevan W; Hutchins, Charles W; Talaty, Nari N

    2016-01-01

    This review covers recent advances in the implementation of enabling chemistry technologies into the drug discovery process. Areas covered include parallel synthesis chemistry, high-throughput experimentation, automated synthesis and purification methods, flow chemistry methodology including photochemistry, electrochemistry, and the handling of "dangerous" reagents. Also featured are advances in the "computer-assisted drug design" area and the expanding application of novel mass spectrometry-based techniques to a wide range of drug discovery activities.

  19. Current status and future prospects for enabling chemistry technology in the drug discovery process

    Science.gov (United States)

    Djuric, Stevan W.; Hutchins, Charles W.; Talaty, Nari N.

    2016-01-01

    This review covers recent advances in the implementation of enabling chemistry technologies into the drug discovery process. Areas covered include parallel synthesis chemistry, high-throughput experimentation, automated synthesis and purification methods, flow chemistry methodology including photochemistry, electrochemistry, and the handling of “dangerous” reagents. Also featured are advances in the “computer-assisted drug design” area and the expanding application of novel mass spectrometry-based techniques to a wide range of drug discovery activities. PMID:27781094

  20. On Study of Teaching Reform of Organic Chemistry Course in Applied Chemical Industry Technology

    Science.gov (United States)

    Zhang, Yunshen

    2017-11-01

    with the implementation of new curriculum reform, the education sees great changes in teaching methods. Teaching reform is profound in organic chemistry course in applied chemical industry technology. However, many problems which have never been noticed before occur when reform programs are implemented which harm students’ ability for learning and enthusiasm in side face. This paper proposes reform measures like combining theory and practice, improving professional quality, supplementing professional needs and integrating teaching into life after analyzing organic chemistry course teaching in applied chemical industry technology currently, hoping to play a role of reference for organic chemistry course teaching reform in applied chemical industry technology.

  1. State of technology of direct contact heat exchanging

    Energy Technology Data Exchange (ETDEWEB)

    Vallario, R.W.; DeBellis, D.E.

    1984-05-01

    Specific objectives of this study were to assess the state of technology development and to identify and evaluate the constraints to wider use of direct contact heat exchanger (DCHE) technology in the U.S. The scope of this study is relatively broad; it includes many types of generic systems and end-use applications, both current and future. Domestic and foreign experience with DCHE technology are compared, although the primary focus is on domestic experience. Twenty-two distinct applications of DCHE technology were identified in this study and are examined in this report. The general format is to describe each system, explore its potential applications, discuss current and past research activities and identify major implementation barriers. Finally, as a result of discussions with principal users of DCHE systems and with other knowledgeable sources, generic and specific R and D needs to overcome specific implementation barriers have been identified. The following list of DCHE systems/concepts has been classified into four major end-uses; there is also a category for specialized (other) applications.

  2. People's Republic of China in the International Technology Exchange

    Directory of Open Access Journals (Sweden)

    Alexander Igorevich Salitskiy

    2015-12-01

    Full Text Available The authors investigate the current state of the S&T in China in the context of its historical development and national policy in the sphere. The evaluation of the Chinese scientific and technological potential is based on some indicators of foreign trade as well as patent activity - in international comparisons. The trends in Chinese S&T sector and its role in the international technology transfers are viewed in the context of internationalization of the global economy. Today’s globally recognized achievements of China in trade in technology-intensive goods and services are based on a long history of rational state policy in acquisition and diffusion of foreign technology and expertise. This policy have resulted in the build-up of S&T system - which is already remarkably productive and keeps growing. One important and specific feature of China’s role in international exchange of high-tech goods and knowledge-intensive services is a growing self-capacity, and a lowering dependence on foreign sources (in relative terms.

  3. Cement manufacture and the environment - Part I: Chemistry and technology

    Science.gov (United States)

    Van Oss, H. G.; Padovani, A.C.

    2002-01-01

    Hydraulic (chiefly portland) cement is the binding agent in concrete and mortar and thus a key component of a country's construction sector. Concrete is arguably the most abundant of all manufactured solid materials. Portland cement is made primarily from finely ground clinker, which itself is composed dominantly of hydraulically active calcium silicate minerals formed through high-temperature burning of limestone and other materials in a kiln. This process requires approximately 1.7 tons of raw materials perton of clinker produced and yields about 1 ton of carbon dioxide (CO2) emissions, of which calcination of limestone and the combustion of fuels each contribute about half. The overall level of CO2 output makes the cement industry one of the top two manufacturing industry sources of greenhouse gases; however, in many countries, the cement industry's contribution is a small fraction of that from fossil fuel combustion by power plants and motor vehicles. The nature of clinker and the enormous heat requirements of its manufacture allow the cement industry to consume a wide variety of waste raw materials and fuels, thus providing the opportunity to apply key concepts of industrial ecology, most notably the closing of loops through the use of by-products of other industries (industrial symbiosis). In this article, the chemistry and technology of cement manufacture are summarized. In a forthcoming companion article (part II), some of the environmental challenges and opportunities facing the cement industry are described. Because of the size and scope of the U.S. cement industry, the analysis relies primarily on data and practices from the United States.

  4. Roles of Bulk and Surface Chemistry in the Oxygen Exchange Kinetics and Related Properties of Mixed Conducting Perovskite Oxide Electrodes

    Directory of Open Access Journals (Sweden)

    Nicola H. Perry

    2016-10-01

    Full Text Available Mixed conducting perovskite oxides and related structures serving as electrodes for electrochemical oxygen incorporation and evolution in solid oxide fuel and electrolysis cells, respectively, play a significant role in determining the cell efficiency and lifetime. Desired improvements in catalytic activity for rapid surface oxygen exchange, fast bulk transport (electronic and ionic, and thermo-chemo-mechanical stability of oxygen electrodes will require increased understanding of the impact of both bulk and surface chemistry on these properties. This review highlights selected work at the International Institute for Carbon-Neutral Energy Research (I2CNER, Kyushu University, set in the context of work in the broader community, aiming to characterize and understand relationships between bulk and surface composition and oxygen electrode performance. Insights into aspects of bulk point defect chemistry, electronic structure, crystal structure, and cation choice that impact carrier concentrations and mobilities, surface exchange kinetics, and chemical expansion coefficients are emerging. At the same time, an understanding of the relationship between bulk and surface chemistry is being developed that may assist design of electrodes with more robust surface chemistries, e.g., impurity tolerance or limited surface segregation. Ion scattering techniques (e.g., secondary ion mass spectrometry, SIMS, or low energy ion scattering spectroscopy, LEIS with high surface sensitivity and increasing lateral resolution are proving useful for measuring surface exchange kinetics, diffusivity, and corresponding outer monolayer chemistry of electrodes exposed to typical operating conditions. Beyond consideration of chemical composition, the use of strain and/or a high density of active interfaces also show promise for enhancing performance.

  5. The Chemistry of Atmosphere-Forest Exchange (CAFE Model – Part 2: Application to BEARPEX-2007 observations

    Directory of Open Access Journals (Sweden)

    G. M. Wolfe

    2011-02-01

    Full Text Available In a companion paper, we introduced the Chemistry of Atmosphere-Forest Exchange (CAFE model, a vertically-resolved 1-D chemical transport model designed to probe the details of near-surface reactive gas exchange. Here, we apply CAFE to noontime observations from the 2007 Biosphere Effects on Aerosols and Photochemistry Experiment (BEARPEX-2007. In this work we evaluate the CAFE modeling approach, demonstrate the significance of in-canopy chemistry for forest-atmosphere exchange and identify key shortcomings in the current understanding of intra-canopy processes.

    CAFE generally reproduces BEARPEX-2007 observations but requires an enhanced radical recycling mechanism to overcome a factor of 6 underestimate of hydroxyl (OH concentrations observed during a warm (~29 °C period. Modeled fluxes of acyl peroxy nitrates (APN are quite sensitive to gradients in chemical production and loss, demonstrating that chemistry may perturb forest-atmosphere exchange even when the chemical timescale is long relative to the canopy mixing timescale. The model underestimates peroxy acetyl nitrate (PAN fluxes by 50% and the exchange velocity by nearly a factor of three under warmer conditions, suggesting that near-surface APN sinks are underestimated relative to the sources. Nitric acid typically dominates gross dry N deposition at this site, though other reactive nitrogen (NOy species can comprise up to 28% of the N deposition budget under cooler conditions. Upward NO2 fluxes cause the net above-canopy NOy flux to be ~30% lower than the gross depositional flux. CAFE under-predicts ozone fluxes and exchange velocities by ~20%. Large uncertainty in the parameterization of cuticular and ground deposition precludes conclusive attribution of non-stomatal fluxes to chemistry or surface uptake. Model-measurement comparisons of vertical concentration gradients for several emitted species suggests that the lower canopy airspace may be

  6. Chemistry of alkali cation exchanged faujasite and mesoporous NaX using alkyl halides and phosphates

    Science.gov (United States)

    Lee, Min-Hong

    The purpose of this work was to increase the reactivity of Faujasite X (NaX) zeolite toward the reactive decontamination of materials subject to nucleophilic attack by means of zeolite cation optimization and by means of the synthesis of mesoporous Faujasite X. Primary alkyl halides and trialkyl phosphates have been the test materials on which the cation-optimized and mesoporous zeolites have been tested. In the alkali cation optimization work, reactions of methyl iodide and 1-chloropropane with alkali metal cation exchanged Faujasite zeolite X were investigated at room temperature. The reactivity of the framework and the product formation were shown to depend on zeolite framework counter-cation. A quantitative study of zeolite product formation has been carried out, primarily using solid-state NMR spectroscopy. Large alkali cations showed preference toward substitution chemistry. In contrast, alkyl halide exposed LiX and NaX zeolites underwent both substitution and elimination. Subsequently introduced water molecules led to hydrolysis of framework species that was sensitive to framework counter-cation. The mesoporous NaX zeolites work undertakes to test whether an improvement in surface chemical reactivity can be achieved by introducing mesopores into the already reactive nucleophilic microporous NaX zeolite. Incorporation of the polydiallyl dimethyl ammonium chloride (PDADMAC) template and the formation of mesopores in Faujasite X zeolite (NaX) were successful and well-characterized. The mesopores are proposed to have occurred from incorporation of the cationic PDADMAC polymer into the zeolite by compensating zeolite framework charge. Subsequent sodium cation exchange of calcined mesoporous NaX was shown to restore the chemical reactivity characteristic of as-synthesized NaX. Trialkyl organophosphorous compounds underwent substitution reactions. The reactivity of both microporous and mesoporous Faujasite zeolite X and the product formation was shown to depend on

  7. Research on the development of green chemistry technology assessment techniques: a material reutilization case.

    Science.gov (United States)

    Hong, Seokpyo; Ahn, Kilsoo; Kim, Sungjune; Gong, Sungyong

    2015-01-01

    This study presents a methodology that enables a quantitative assessment of green chemistry technologies. The study carries out a quantitative evaluation of a particular case of material reutilization by calculating the level of "greenness" i.e., the level of compliance with the principles of green chemistry that was achieved by implementing a green chemistry technology. The results indicate that the greenness level was enhanced by 42% compared to the pre-improvement level, thus demonstrating the economic feasibility of green chemistry. The assessment technique established in this study will serve as a useful reference for setting the direction of industry-level and government-level technological R&D and for evaluating newly developed technologies, which can greatly contribute toward gaining a competitive advantage in the global market.

  8. [No exchange of information without technology : modern infrastructure in radiology].

    Science.gov (United States)

    Hupperts, H; Hermann, K-G A

    2014-01-01

    Modern radiology cannot accomplish the daily numbers of examinations without supportive technology. Even though technology seems to be becoming increasingly more indispensable, business continuity should be ensured at any time and if necessary even with a limited technical infrastructure by business continuity management. An efficient information security management system forms the basis. The early radiology information systems were islands of information processing. A modern radiology department must be able to be modularly integrated into an informational network of a bigger organization. The secondary use of stored data for clinical decision-making support poses new challenges for the integrity of the data or systems because medical knowledge is displayed and provided in a context of treatment. In terms of imaging the creation and distribution radiology services work in a fully digital manner which is often different for radiology reports. Legally secure electronic diagnostic reports require a complex technical infrastructure; therefore, diagnostic findings still need to be filed as a paper document. The internal exchange and an improved dose management can be simplified by systems which continuously and automatically record the doses and thus provide the possibility of permanent analysis and reporting. Communication between patient and radiologist will gain ongoing importance. Intelligent use of technology will convey this to the radiologist and it will facilitate the understanding of the information by the patient.

  9. INTERNATIONAL ENVIRONMENTAL TECHNOLOGY IDENTIFICATION, DEVELOPMENT, DEMONSTRATION, DEPLOYMENT AND EXCHANGE

    Energy Technology Data Exchange (ETDEWEB)

    Roy C. Herndon

    2001-02-28

    Cooperative Agreement (DE-FC21-95EW55101) between the U.S. Department of Energy (DOE) and the Florida State University's Institute for International Cooperative Environmental Research (IICER) was designed to facilitate a number of joint programmatic goals of both the DOE and the IICER related to international technology identification, development, demonstration and deployment using a variety of mechanisms to accomplish these goals. These mechanisms included: laboratory and field research; technology demonstrations; international training and technical exchanges; data collection, synthesis and evaluation; the conduct of conferences, symposia and high-level meetings; and other appropriate and effective approaches. The DOE utilized the expertise and facilities of the IICER at Florida State University to accomplish its goals related to this cooperative agreement. The IICER has unique and demonstrated capabilities that have been utilized to conduct the tasks for this cooperative agreement. The IICER conducted activities related to technology identification, development, evaluation, demonstration and deployment through its joint centers which link the capabilities at Florida State University with collaborating academic and leading research institutions in the major countries of Central and Eastern Europe (e.g., Czech Republic, Hungary, Poland) and Russia. The activities and accomplishments for this five-year cooperative agreement are summarized in this Final Technical Report.

  10. Development of Pre-Service Chemistry Teachers' Technological Pedagogical Content Knowledge

    Science.gov (United States)

    Cetin-Dindar, Ayla; Boz, Yezdan; Sonmez, Demet Yildiran; Celep, Nilgun Demirci

    2018-01-01

    In this study, a mixed-method design was employed to investigate pre-service chemistry teachers' Technological Pedagogical Content Knowledge (TPACK) development. For effective technology integration in instruction, knowledge about technology is not enough; teachers should have different knowledge types which are content, pedagogical, and…

  11. Surface defect chemistry and oxygen exchange kinetics in La2-xCaxNiO4+δ

    Science.gov (United States)

    Tropin, E. S.; Ananyev, M. V.; Farlenkov, A. S.; Khodimchuk, A. V.; Berenov, A. V.; Fetisov, A. V.; Eremin, V. A.; Kolchugin, A. A.

    2018-06-01

    Surface oxygen exchange kinetics and diffusion in La2-xCaxNiO4+δ (x = 0; 0.1; 0.3) have been studied by the isotope exchange method with gas phase equilibration in the temperature range of 600-800 °C and oxygen pressure range 0.13-2.5 kPa. Despite an enhanced electrical conductivity of La2-xCaxNiO4+δ theirs oxygen surface exchange (k*) and oxygen tracer diffusion (D*) coefficients were significantly lower in comparison with La2NiO4+δ. The rates of the elementary stages of oxygen exchange have been calculated. Upon Ca doping the change of the rate-determining stage was observed. The surface of the oxides was found to be inhomogeneous towards oxygen exchange process according to the recently developed model. The reasons of such inhomogeneity are discussed as well as Ca influence on the surface defect chemistry and oxygen surface exchange and diffusivity.

  12. Developing maintenance technologies for FBR's heat exchanger units by advanced laser processing

    International Nuclear Information System (INIS)

    Nishimura, Akihiko; Shimada, Yukihiro

    2011-01-01

    Laser processing technologies were developed for the purpose of maintenance of FBR's heat exchanger units. Ultrashort laser processing fabricated fiber Bragg grating sensor for seismic monitoring. Fiber laser welding with a newly developed robot system repair cracks on inner wall of heat exchanger tubes. Safety operation of the heat exchanger units will be improved by the advanced laser processing technologies. These technologies are expected to be applied to the maintenance for the next generation FBRs. (author)

  13. Effects of '"Environmental Chemistry" Elective Course via Technology-Embedded Scientific Inquiry Model on Some Variables

    Science.gov (United States)

    Çalik, Muammer; Özsevgeç, Tuncay; Ebenezer, Jazlin; Artun, Hüseyin; Küçük, Zeynel

    2014-01-01

    The purpose of this study is to examine the effects of "environmental chemistry" elective course via Technology-Embedded Scientific Inquiry (TESI) model on senior science student teachers' (SSSTs) conceptions of environmental chemistry concepts/issues, attitudes toward chemistry, and technological pedagogical content knowledge…

  14. Priority survey between indicators and analytic hierarchy process analysis for green chemistry technology assessment.

    Science.gov (United States)

    Kim, Sungjune; Hong, Seokpyo; Ahn, Kilsoo; Gong, Sungyong

    2015-01-01

    This study presents the indicators and proxy variables for the quantitative assessment of green chemistry technologies and evaluates the relative importance of each assessment element by consulting experts from the fields of ecology, chemistry, safety, and public health. The results collected were subjected to an analytic hierarchy process to obtain the weights of the indicators and the proxy variables. These weights may prove useful in avoiding having to resort to qualitative means in absence of weights between indicators when integrating the results of quantitative assessment by indicator. This study points to the limitations of current quantitative assessment techniques for green chemistry technologies and seeks to present the future direction for quantitative assessment of green chemistry technologies.

  15. Representational Technologies and Learner Problem-Solving Strategies in Chemistry

    Science.gov (United States)

    McCollum, Brett; Sepulveda, Ana; Moreno, Yuritzel

    2016-01-01

    Learning within the sciences is often considered through a quantitative lens, but acquiring proficiency with the symbolic representations in chemistry is arguably more akin to language learning. Representational competencies are central to successful communication of chemical information including molecular composition, structure, and properties.…

  16. Chemistry

    International Nuclear Information System (INIS)

    Ferris, L.M.

    1975-01-01

    The chemical research and development efforts related to the design and ultimate operation of molten-salt breeder reactor systems are concentrated on fuel- and coolant-salt chemistry, including the development of analytical methods for use in these systems. The chemistry of tellurium in fuel salt is being studied to help elucidate the role of this element in the intergranular cracking of Hastelloy N. Studies were continued of the effect of oxygen-containing species on the equilibrium between dissolved UF 3 and dissolved UF 4 , and, in some cases, between the dissolved uranium fluorides and graphite, and the UC 2 . Several aspects of coolant-salt chemistry are under investigation. Hydroxy and oxy compounds that could be formed in molten NaBF 4 are being synthesized and characterized. Studies of the chemistry of chromium (III) compounds in fluoroborate melts were continued as part of a systematic investigation of the corrosion of structural alloys by coolant salt. An in-line voltammetric method for determining U 4+ /U 3+ ratios in fuel salt was tested in a forced-convection loop over a six-month period. (LK)

  17. Water Chemistry Control Technology to Improve the Performance of Nuclear Power Plants for Extended Fuel Cycles

    International Nuclear Information System (INIS)

    Maeng, W. Y.; Na, J. W.; Lee, E. H.

    2010-07-01

    Ο To Develop the technology to manage the problems of AOA and radiation, corrosion as long term PWR operation. Ο To Establish the advanced water chemical operating systems. - Development of the proper water chemistry guidelines for long term PWR operation. AOA(Axial Offest Anomaly) has been reported in many PWR plants in the world, including Korea, especially in the plants of higher burn-up and longer cycle operation or power up-rate. A test loop has been designed and made by KAERI, in order to investigate and mitigate AOA problems in Korea. This project included the study of hydrodynamic simulation and the modeling about AOA. The analysis of radioactive crud was performed to investigate of NPPs primary water chemical effect on AOA and to reduce the radioactive dose rate. The high temperature measurement system was developed to on-line monitor of water chemistry in nuclear power plants. The effects of various environmental factors such as temperature, pressure, and flow rate on YSZ-based pH electrode were evaluated for ensuring the accuracy of high-temperature pH measurement. The inhibition technology for fouling and SCC of SG tube was evaluated to establish the water chemistry technology of corrosion control of nuclear system. The high temperature and high pressure crevice chemistry analysis test loop was manufactured to develop the water chemistry technology of crevice chemistry control

  18. An Exponential Increase in Regional Health Information Exchange With Collaborative Policies and Technologies.

    Science.gov (United States)

    Downing, N Lance; Lane, Steven; Eisenberg, Mathew; Sharp, Christopher; Palma, Jonathan; Longhurst, Christopher

    2015-01-01

    In the United States, the ability to securely exchange health information between organization has been limited by technical interoperability, patient identity matching, and variable institutional policies. Here, we examine the regional experience in a national health information exchange network by examining clinical data sharing between eleven Northern California organizations using the same health information exchange (HIE) platform between 2013-2014. We identify key policies and technologies that have led to a dramatic increase in health information exchange.

  19. A Unique Master's Program in Combined Nuclear Technology and Nuclear Chemistry at Chalmers University of Technology, Sweden

    International Nuclear Information System (INIS)

    Skarnemark, Gunnar; Allard, Stefan; Ekberg, Christian; Nordlund, Anders

    2009-01-01

    The need for engineers and scientists who can ensure safe and secure use of nuclear energy is large in Sweden and internationally. Chalmers University of Technology is therefore launching a new 2-year master's program in Nuclear Engineering, with start from the autumn of 2009. The program is open to Swedish and foreign students. The program starts with compulsory courses dealing with the basics of nuclear chemistry and physics, radiation protection, nuclear power and reactors, nuclear fuel supply, nuclear waste management and nuclear safety and security. There are also compulsory courses in nuclear industry applications and sustainable energy futures. The subsequent elective courses can be chosen freely but there is also a possibility to choose informal tracks that concentrate on nuclear chemistry or reactor technology and physics. The nuclear chemistry track comprises courses in e.g. chemistry of lanthanides, actinides and transactinides, solvent extraction, radioecology and radioanalytical chemistry and radiopharmaceuticals. The program is finished with a one semester thesis project. This is probably a unique master program in the sense of its combination of deep courses in both nuclear technology and nuclear chemistry.

  20. Chemistry of Stable Carbenes and «Green» Technologies

    Directory of Open Access Journals (Sweden)

    Korotkikh, N.I.

    2015-11-01

    Full Text Available Brief analysis of fundamental research in the chemistry of stable carbenes and applications in the field of «green» chemistry on their basis carried out at the L.M. Litvinenko Institute of Physical Organic & Coal Chemistry of NAS of Ukraine over the last decade is given. Carbene versions of ester Claisen condensation to form zwitterionic compounds, the Leuckart-Wallach reaction with the autoreduction of carbenoid azolium salts, Hofmann cleavage of aminocarbene insertion products, an induced tandem autotransformation of 1,2,4-triazol-5-ylidenes into 5-amidino-1,2,4-triazoles were found. New carbene reactions of ad dition, deesterification, oxidation and complexation were revealed. Effective methods of obtaining stable carbenes and carbenoids were suggested. New types of carbenes, namely benzimidazolylidenes, superstable conjugated biscarbenes and new types of carbenoids were synthesized. The existence of hypernucleophilic carbenes was theoretically predicted and experimentally confirmed. The prospects of the use of carbenes and their derivatives, in particular, carbene complexes of transition metals in catalysis of organic reactions and the search of biologically active compounds were shown.

  1. Development and Implementation of High School Chemistry Modules Using Touch-Screen Technologies

    Science.gov (United States)

    Lewis, Maurica S.; Zhao, Jinhui; Montclare, Jin Kim

    2012-01-01

    Technology was employed to motivate and captivate students while enriching their in-class education. An outreach program is described that involved college mentors introducing touch-screen technology into a high school chemistry classroom. Three modules were developed, with two of them specifically tailored to encourage comprehension of molecular…

  2. Incorporating Service-Learning, Technology, and Research Supportive Teaching Techniques into the University Chemistry Classroom

    Science.gov (United States)

    Saitta, E. K. H.; Bowdon, M. A.; Geiger, C. L.

    2011-01-01

    Technology was integrated into service-learning activities to create an interactive teaching method for undergraduate students at a large research institution. Chemistry students at the University of Central Florida partnered with high school students at Crooms Academy of Information Technology in interactive service learning projects. The…

  3. Cables, Sharks and Servers: Technology and the Geography of the Foreign Exchange Market

    OpenAIRE

    Eichengreen, Barry; Lafarguette, Romain; Mehl, Arnaud

    2016-01-01

    We analyze the impact of technology on production and trade in services, focusing on the foreign exchange market. We identify exogenous technological changes by the connection of countries to submarine fiber-optic cables used for electronic trading, but which were not laid for purposes related to the foreign exchange market. We estimate the impact of cable connections on the share of offshore foreign exchange transactions. Cable connections between local markets and matching servers in the ma...

  4. A review of boiling water reactor water chemistry: Science, technology, and performance

    International Nuclear Information System (INIS)

    Fox, M.J.

    1989-02-01

    Boiling water reactor (BWR) water chemistry (science, technology, and performance) has been reviewed with an emphasis on the relationships between BWR water quality and corrosion fuel performance, and radiation buildup. A comparison of Nuclear Regulatory Commission (NRC) Regulatory Guide 1.56, the Boiling Water Reactor Owners Group (BWROG) Water Chemistry Guidelines, and Plant Technical Specifications showed that the BWROG Guidelines are more stringent than the NRC Regulatory Guide, which is almost identical to Plant Technical Specifications. Plant performance with respect to BWR water chemistry has shown dramatic improvements in recent years. Up until 1979 BWRs experienced an average of 3.0 water chemistry incidents per reactor-year. Since 1979 the water chemistry technical specifications have been violated an average of only 0.2 times per reactor-year, with the most recent data from 1986-1987 showing only 0.05 violations per reactor-year. The data clearly demonstrate the industry-wide commitment to improving water quality in BWRs. In addition to improving water quality, domestic BWRs are beginning to switch to hydrogen water chemistry (HWC), a remedy for intergranular stress corrosion cracking. Three domestic BWRs are presently operating on HWC, and fourteen more have either performed HWC mini tests or are in various stages of HWC implementation. This report includes a detailed review of HWC science and technology as well as areas in which further research on BWR chemistry may be needed. 43 refs., 30 figs., 8 tabs

  5. Advanced chemistry of monolayers at interfaces trends in methodology and technology

    CERN Document Server

    Imae, Toyoko

    2007-01-01

    Advanced Chemistry of Monolayers at Interfaces describes the advanced chemistry of monolayers at interfaces. Focusing on the recent trends of methodology and technology, which are indispensable in monolayer science. They are applied to monolayers of surfactants, amphiphiles, polymers, dendrimers, enzymes, and proteins, which serve many uses.Introduces the methodologies of scanning probe microscopy, surface force instrumentation, surface spectroscopy, surface plasmon optics, reflectometry, and near-field scanning optical microscopy. Modern interface reaction method, lithographic tech

  6. Relating surface chemistry and oxygen surface exchange in LnBaCo2O(5+δ) air electrodes.

    Science.gov (United States)

    Téllez, Helena; Druce, John; Kilner, John A; Ishihara, Tatsumi

    2015-01-01

    The surface and near-surface chemical composition of electroceramic materials often shows significant deviations from that of the bulk. In particular, layered materials, such as cation-ordered LnBaCo2O(5+δ) perovskites (Ln = lanthanide), undergo surface and sub-surface restructuring due to the segregation of the divalent alkaline-earth cation. These processes can take place during synthesis and processing steps (e.g. deposition, sintering or annealing), as well as at temperatures relevant for the operation of these materials as air electrodes in solid oxide fuel cells and electrolysers. Furthermore, the surface segregation in these double perovskites shows fast kinetics, starting at temperatures as low as 400 °C over short periods of time and leading to a decrease in the transition metal surface coverage exposed to the gas phase. In this work, we use a combination of stable isotope tracer labeling and surface-sensitive ion beam techniques to study the oxygen transport properties and their relationship with the surface chemistry in ordered LnBaCo2O(5+δ) perovskites. Time-of-Flight Secondary-Ion Mass Spectrometry (ToF-SIMS) combined with (18)O isotope exchange was used to determine the oxygen tracer diffusion (D*) and surface exchange (k*) coefficients. Furthermore, Low Energy Ion Scattering (LEIS) was used for the analysis of the surface and near surface chemistry as it provides information from the first mono-atomic layer of the materials. In this way, we could relate the compositional modifications (e.g. cation segregation) taking place at the electrochemically-active surface during the exchange at high temperatures and the oxygen transport properties in double perovskite electrode materials to further our understanding of the mechanism of the surface exchange process.

  7. Creation of medicinal chemistry learning communities through enhanced technology and interdisciplinary collaboration.

    Science.gov (United States)

    Henriksen, Brian; Roche, Victoria

    2012-10-12

    Objectives. To build an integrated medicinal chemistry learning community of campus and distance pharmacy students though the use of innovative technology and interdisciplinary teaching.Design. Mechanisms were implemented to bring distance students into campus-based medicinal chemistry classrooms in real time, stimulate interaction between instructors and various student cohorts, and promote group work during class. Also, pharmacy clinician colleagues were recruited to contribute to the teaching of the 3 medicinal chemistry courses.Assessment. Student perceptions on the value of technology to build community and advance learning were gleaned from course evaluations, in class feedback, and conversations with class officers and student groups. Responses on a survey of second-year students confirmed the benefits of interdisciplinary content integration on engagement and awareness of the connection between drug chemistry and pharmacy practice. A survey of clinician colleagues who contributed to teaching the 3 medicinal chemistry courses found their views were similar to those of students.Conclusions. The purposeful use of technology united learners, fostered communication, and advanced content comprehension in 3 medicinal chemistry courses taught to campus and distance students. Teaching collaboration with pharmacy clinicians enhanced learner interest in course content and provided insight into the integrated nature of the profession of pharmacy.

  8. Chemistry

    International Nuclear Information System (INIS)

    Ferris, L.M.

    1976-01-01

    Research progress is reported in programs on fuel-salt chemistry, properties of compounds in the Li--Te system, Te spectroscopy UF 4 --H equilibria, porous electrode studies of molten salts, fuel salt-coolant salt reactions, thermodynamic properties of transition-metal fluorides, and properties of sodium fluoroborate. Developmental work on analytical methods is summarized including in-line analysis of molten MSBR fuel, analysis of coolant-salts for tritium, analysis of molten LiF--BeF 2 --ThF 4 for Fe and analysis of LiF--BeF--ThF 4 for Te

  9. Critical technologies: The role of chemistry and chemical engineering

    International Nuclear Information System (INIS)

    1992-01-01

    The purpose of this report is to identify and illustrate key contributions of chemical and chemical engineering research to the development of technologies that have been deemed critical to the economy, security, and well-being of our nation. The report surveys a wide range of vital technologies that are heavily reliant or even critically dependent on chemical or chemical engineering research. Examples were taken from the fields of materials, manufacturing, energy, transportation, public health, information and communications, and the environment. While loosely following the structure of the critical technologies report of the NCTP, our committee decided on a different approach, that of using examples backed up by extensive illustrations

  10. Chemistry and technology of radiation processed composite materials

    International Nuclear Information System (INIS)

    Czvikovszky, T.

    1985-01-01

    Composite materials of synthetics (based on monomers, oligomers and thermoplastics) and of natural polymers (wood and other fibrous cellulosics) prepared by radiation processing, offer valuable structural materials with enhanced coupling forces between the components. The applied polymer chemistry of such composites shows several common features with that of radiation grafting, e.g. the polymerization rate of oligomer-monomer mixtures in wood remains in most cases proportional to the square-root of the initiating dose-rate, just as in the simultaneous grafting, demonstrating that the chain termination kinetics remain regularly bimolecular in the corresponding dose-rate ranges. In the processing experiences of such composites, low dose requirement, easy process-control, and good technical feasibility have been found for composites of wood with oligomer-monomer mixtures, for coconut fibres with unsaturated polyesters and for pretreated wood fibre with polypropylene. (author)

  11. Highly dispersive ion exchangers in the analytical chemistry of uranium, particularly regarding separation methods

    International Nuclear Information System (INIS)

    Schoening, R.

    1975-01-01

    The reaction of water-insoluble polyvinyl pyrrolidon with uranium VI was investigated and a determination method for uranium was worked out in which the polyvinyl pyrrolidon was used as specific exchanger. Good separations of uranium from numerous transition metal ions were achieved here. The application of this exchanger for a fast and simple elution and determination method was of particular importance. A possible sorption mechanism was suggested based on the capacity curve of uranium with polyvinyl pyrrolidon and nitrogen and chloride content at maximum load. The sorption occurs by coordination of the carbonyl oxygen of single pyrrolidon rings with the protons of the complex acides and uranium. This assumption is supported by IR investigations. The sorbability of other inorganic acids was also investigated and possible structures were formulated for the sorption mechanism. In addition to this, ion exchangers were prepared based on cellulose by converting cellulose powder with aziridine and tris-1-aziridinyl-phosphine oxide. A polyethylene imine cellulose of high capacity was obtained in the conversion of cellulose powder with aziridine. This exchanger absorbs cobalt III very strongly. The exchanger loaded with cobalt III was used to separate the uranium as cyanato complex. The exchanger obtained in converting chlorated cellulose with tris-1-aziridinyl phosphine oxide also absorbs uranium VI very strongly. Thus a separation method of high specifity and selectivity was developed. (orig.) [de

  12. The application of synthetic inorganic ion exchangers to analytical chemistry, 2

    International Nuclear Information System (INIS)

    Abe, Mitsuo

    1974-01-01

    Regarding acidic salts, description is made on the general behaviour of the acidic salts of tetravalent metals and each of zirconium salts, titanium salts, stannic salts, cerium salts, thorium salts, chromium salts, and others. On heteropolyacid salts, ammonium 12-molybdophosphated and phosphorus wolframate are described. On insoluble ferrocyanides, the behaviour of various complex salts is explained. In the discussion on the general behaviour of the acidic salts of tetravalent metals, the ideality of ion exchange, the stability and solubility of the acidic salts, thermal stability and radiation resistance, the ion sieving effect of various acidic salts, and the selectivity of the acidic salts are stated. Zirconium gives a number of acidic salts, such as zirconium phosphate, crystalline zirconium phosphate, zirconium phrophosphate, various polyphosphates of zirconium, zirconium phosphate-silicate, zirconium arsenate, zirconium antimonate, zirconium molybdate, zirconium tungstate, etc. Useful titanium salts for ion exchange are titanium phosphate, titanium aresenate, titanium antimonate, titanium tungstate, titanium molybdate, titanium vanadate, and titanium selenate. The distribution coefficients of metal ions, inorganic-separation of various inorganic ion exchangers, the exchange characteristics of various elements on various ion exchangers, and the selectivity of various inorganic ion-exchangers are tabulated. (Fukutomi, T.)

  13. Scandium: its occurrence, chemistry, physics, metallurgy, biology, and technology

    International Nuclear Information System (INIS)

    Horovitz, C.T.

    1975-01-01

    This book describes the following aspects of scandium: discovery and history, occurrence in nature, geochemistry and mineralogy, chemical, physical and technological properties, fabrication and metallurgy, its biological significance and toxicology, and its uses. (Extensive references for each chapter)

  14. Chemistry and technology of Molten Salt Reactors - history and perspectives

    International Nuclear Information System (INIS)

    Uhlir, Jan

    2007-01-01

    Molten Salt Reactors represent one of promising future nuclear reactor concept included also in the Generation IV reactors family. This reactor type is distinguished by an extraordinarily close connection between the reactor physics and chemical technology, which is given by the specific features of the chemical form of fuel, representing by molten fluoride salt and circulating through the reactor core and also by the requirements of continuous 'on-line' reprocessing of the spent fuel. The history of Molten Salt Reactors reaches the period of fifties and sixties, when the first experimental Molten Salt Reactors were constructed and tested in ORNL (US). Several molten salt techniques dedicated to fresh molten salt fuel processing and spent fuel reprocessing were studied and developed in those days. Today, after nearly thirty years of discontinuance, a renewed interest in the Molten Salt Reactor technology is observed. Current experimental R and D activities in the area of Molten Salt Reactor technology are realized by a relatively small number of research institutions mainly in the EU, Russia and USA. The main effort is directed primarily to the development of separation processes suitable for the molten salt fuel processing and reprocessing technology. The techniques under development are molten salt/liquid metal extraction processes, electrochemical separation processes from the molten salt media, fused salt volatilization techniques and gas extraction from the molten salt medium

  15. Chemistry and technology of boron and its compounds

    International Nuclear Information System (INIS)

    Zhigach, A.F.; Parfenov, B.P.; Svitsyn, R.A.

    1995-01-01

    The results of research dealing with development of technologies of boron trichloride, boron hydride, aminoderivative boron hydrides, metal borohydrides, carboranes, carborane-containing polymers, carried out at the institute of organoelemental compounds, are presented. Physicochemical properties of the compounds have been studied and analytical methods have been developed. Data on toxicity and fire hazard of boron compounds are provided

  16. Adapting to Student Learning Styles: Engaging Students with Cell Phone Technology in Organic Chemistry Instruction

    Science.gov (United States)

    Pursell, David P.

    2009-01-01

    Students of organic chemistry traditionally make 3 x 5 in. flash cards to assist learning nomenclature, structures, and reactions. Advances in educational technology have enabled flash cards to be viewed on computers, offering an endless array of drilling and feedback for students. The current generation of students is less inclined to use…

  17. 8. Seminar of the IMP-IIE-ININ on technological specialties. Topic 9: Analytical Chemistry

    International Nuclear Information System (INIS)

    1996-01-01

    The document includes four papers considered within the INIS subject scope, which were presented at the 8th Seminar of the IMP-IIE-ININ on technological specialities (Section Analytical Chemistry), held on 26 June 1996 in Cuernavaca (Mexico). A separate abstract and indexing were provided for each paper

  18. Chemistry

    International Nuclear Information System (INIS)

    Ferris, L.M.

    1975-01-01

    Research and development activities dealing with the chemical problems related to design and ultimate operation of molten-salt reactor systems are described. An experimental test stand was constructed to expose metallurgical test specimens to Te 2 vapor at defined temperatures and deposition rates. To better define the chemistry of fluoroborate coolant, several aspects are being investigated. The behavior of hydroxy and oxy compounds in molten NaBF 4 is being investigated to define reactions and compounds that may be involved in corrosion and/or could be involved in methods for trapping tritium. Two corrosion products of Hastelloy N, Na 3 CrF 6 and Na 5 Cr 3 F 14 , were identified from fluoroborate systems. The evaluation of fluoroborate and alternate coolants continued. Research on the behavior of hydrogen and its isotopes is summarized. The solubilities of hydrogen, deuterium, and helium in Li 2 BeF 4 are very low. The sorption of tritium on graphite was found to be significant (a few milligrams of tritium per kilogram of graphite), possibly providing a means of sequestering a portion of the tritium produced. Development of analytical methods continued with emphasis on voltammetric and spectrophotometric techniques for the in-line analysis of corrosion products such as Fe 2+ and Cr 3+ and the determination of the U 3+ /U 4+ ratio in MSBR fuel salt. Similar studies were conducted with the NaBF 4 --NaF coolant salt. Information developed during the previous operation of the CSTF has been assessed and used to formulate plans for evaluation of in-line analytical methods in future CSTF operations. Electroanalytical and spectrophotometric research suggests that an electroactive protonic species is present in molten NaBF 4 --NaF, and that this species rapidly equilibrates with a volatile proton-containing species. Data obtained from the CSTF indicated that tritium was concentrated in the volatile species. (JGB)

  19. Preliminary findings of the Viking gas exchange experiment and a model for Martian surface chemistry

    International Nuclear Information System (INIS)

    Oyama, V.I.; Berdahl, B.J.; Carle, G.C.

    1977-01-01

    It is stated that O 2 and CO 2 were evolved from humidified Martian soil in the gas exchange experiment on Viking Lander 1. Small changes in N 2 gas were also recorded. A model of the morphology and a hypothesis of the mechanistics of the Martian surface are proposed. (author)

  20. Experiments probing the influence of air exchange rates on secondary organic aerosols derived from indoor chemistry

    DEFF Research Database (Denmark)

    Weschler, Charles J.; Shields, H.C.

    2003-01-01

    Reactions between ozone and terpenes have been shown to increase the concentrations of submicron particles in indoor settings. The present study was designed to examine the influence of air exchange rates on the concentrations of these secondary organic aerosols as well as on the evolution...

  1. Experiments probing the influence of air exchange rates on secondary organic aerosols derived from indoor chemistry

    DEFF Research Database (Denmark)

    Weschler, Charles J.; Shields, H.C.

    2003-01-01

    Reactions between ozone and terpenes have been shown to increase the concentrations of submicron particles in indoor settings. The present study was designed to examine the influence of air exchange rates on the concentrations of these secondary organic aerosols as well as on the evolution of the...

  2. Enabling Chemistry Technologies and Parallel Synthesis-Accelerators of Drug Discovery Programmes.

    Science.gov (United States)

    Vasudevan, A; Bogdan, A R; Koolman, H F; Wang, Y; Djuric, S W

    There is a pressing need to improve overall productivity in the pharmaceutical industry. Judicious investments in chemistry technologies can have a significant impact on cycle times, cost of goods and probability of technical success. This perspective describes some of these technologies developed and implemented at AbbVie, and their applications to the synthesis of novel scaffolds and to parallel synthesis. © 2017 Elsevier B.V. All rights reserved.

  3. Ion exchange technology in the nuclear fuel cycle

    International Nuclear Information System (INIS)

    1986-02-01

    The application of ion exchange has been expanded to various parts of the nuclear fuel cycle. Major applications are in uranium production facilities, nuclear power plants, spent fuel reprocessing and waste treatment. Furthermore, application to isotope separation has been under development. The appendix contains a compilation of resin data. A separate abstract was prepared for each of the 6 chapters in this technical document

  4. Mechanisms for international technology exchange, privatization, and transfer

    International Nuclear Information System (INIS)

    Mayfield, T.

    1993-01-01

    An environmental technology transfer business assistance program is needed to encourage collaboration and technology transfer within the international community. This program helped to find appropriate mechanisms to facilitate the transfer of these technologies for use by DOE environmental restoration and waste management (ER/WM) programs while assisting U.S. private industry (especially small and medium size business) in commercializing the technologies nationally and abroad

  5. Usage and applications of Semantic Web techniques and technologies to support chemistry research.

    Science.gov (United States)

    Borkum, Mark I; Frey, Jeremy G

    2014-01-01

    The drug discovery process is now highly dependent on the management, curation and integration of large amounts of potentially useful data. Semantics are necessary in order to interpret the information and derive knowledge. Advances in recent years have mitigated concerns that the lack of robust, usable tools has inhibited the adoption of methodologies based on semantics. THIS PAPER PRESENTS THREE EXAMPLES OF HOW SEMANTIC WEB TECHNIQUES AND TECHNOLOGIES CAN BE USED IN ORDER TO SUPPORT CHEMISTRY RESEARCH: a controlled vocabulary for quantities, units and symbols in physical chemistry; a controlled vocabulary for the classification and labelling of chemical substances and mixtures; and, a database of chemical identifiers. This paper also presents a Web-based service that uses the datasets in order to assist with the completion of risk assessment forms, along with a discussion of the legal implications and value-proposition for the use of such a service. We have introduced the Semantic Web concepts, technologies, and methodologies that can be used to support chemistry research, and have demonstrated the application of those techniques in three areas very relevant to modern chemistry research, generating three new datasets that we offer as exemplars of an extensible portfolio of advanced data integration facilities. We have thereby established the importance of Semantic Web techniques and technologies for meeting Wild's fourth "grand challenge".

  6. Synthesis of (+)-dumetorine and congeners by using flow chemistry technologies.

    Science.gov (United States)

    Riva, Elena; Rencurosi, Anna; Gagliardi, Stefania; Passarella, Daniele; Martinelli, Marisa

    2011-05-23

    An efficient total synthesis of the natural alkaloid (+)-dumetorine by using flow technology is described. The process entailed five separate steps starting from the enantiopure (S)-2-(piperidin-2-yl)ethanol 4 with 29% overall yield. Most of the reactions were carried out by exploiting solvent superheating and by using packed columns of immobilized reagents or scavengers to minimize handling. New protocols for performing classical reactions under continuous flow are disclosed: the ring-closing metathesis reaction with a novel polyethylene glycol-supported Hoveyda catalyst and the unprecedented flow deprotection/Eschweiler-Clarke methylation sequence. The new protocols developed for the synthesis of (+)-dumetorine were applied to the synthesis of its simplified natural congeners (-)-sedamine and (+)-sedridine. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Enabling technologies and green processes in cyclodextrin chemistry

    Directory of Open Access Journals (Sweden)

    Giancarlo Cravotto

    2016-02-01

    Full Text Available The design of efficient synthetic green strategies for the selective modification of cyclodextrins (CDs is still a challenging task. Outstanding results have been achieved in recent years by means of so-called enabling technologies, such as microwaves, ultrasound and ball mills, that have become irreplaceable tools in the synthesis of CD derivatives. Several examples of sonochemical selective modification of native α-, β- and γ-CDs have been reported including heterogeneous phase Pd- and Cu-catalysed hydrogenations and couplings. Microwave irradiation has emerged as the technique of choice for the production of highly substituted CD derivatives, CD grafted materials and polymers. Mechanochemical methods have successfully furnished greener, solvent-free syntheses and efficient complexation, while flow microreactors may well improve the repeatability and optimization of critical synthetic protocols.

  8. Inkjet printing for biosensor fabrication: combining chemistry and technology for advanced manufacturing.

    Science.gov (United States)

    Li, Jia; Rossignol, Fabrice; Macdonald, Joanne

    2015-06-21

    Inkjet printing is emerging at the forefront of biosensor fabrication technologies. Parallel advances in both ink chemistry and printers have led to a biosensor manufacturing approach that is simple, rapid, flexible, high resolution, low cost, efficient for mass production, and extends the capabilities of devices beyond other manufacturing technologies. Here we review for the first time the factors behind successful inkjet biosensor fabrication, including printers, inks, patterning methods, and matrix types. We discuss technical considerations that are important when moving beyond theoretical knowledge to practical implementation. We also highlight significant advances in biosensor functionality that have been realised through inkjet printing. Finally, we consider future possibilities for biosensors enabled by this novel combination of chemistry and technology.

  9. Proceedings of BARC golden jubilee year DAE-BRNS topical symposium on role of analytical chemistry in nuclear technology

    International Nuclear Information System (INIS)

    Swain, K.K.; Venkataramani, B.

    2007-01-01

    Among the various disciplines in Chemistry, Analytical Chemistry is unique, because it is an integral part of every aspect of technology- product and process development and deployment. In Nuclear Industry, the quality assurance criteria are very stringent. And truly, Analytical Chemistry has continued to play a pivotal role in the entire nuclear fuel cycle, since the beginning of the Indian Atomic Energy Programme. The conference covers invited talk, nuclear materials, reactor systems, thorium technology, alternate energy sources, biology, agriculture and environment, water technology, isotope, radiation and laser technology, development of analytical instruments, and reference materials and inter-comparison exercises. Papers relevant to INIS are indexed separately. (author)

  10. The present status and perspectives on the development of radiation chemistry and technology in Poland

    International Nuclear Information System (INIS)

    Kroh, J.; Rosiak, J.; Wolszczak, M.; Bobrowski, K.; Chmielewski, A. G.; Zimek, Z.; Forys, M.; Kalecinski, J.

    2001-01-01

    Having in mind the world research trends in the field of radiation chemistry and technology, the development of this domain in Poland has been discussed in this report. The condition of apparatus and man power at the Polish scientific institutions and academic centers acting in the above mentioned scientific and technological area has been analyzed. It has been shown that the basic research achievements of national institutions are placing them among the most advanced foreign centers. As to the implemented technological elaborations it may be said that is one of the few high-tech fields in which Poland can compete with the most advanced centers in the world. (author)

  11. International Symposium for the Promotion of APEC Environmental Technology Exchange; APEC kankyo gijutsu koryu sokushin symposium

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-11-11

    The International Symposium for the Promotion of APEC Environmental Technology Exchange was held under the theme `The function and role expected of the APEC Virtual Center,` with the objectives of clarifying the need for future intra-regional environmental technological exchange, defining the types of information and personnel exchange, and promoting the use of interactive character of the APEC Virtual Center for Environmental Technology Exchange by encouraging access to and participation in the Virtual Center project. It was held in the period of 11th and 12th, November in 1996, at the venue of Rinku International Convention Center in Osaka. The symposium was attended by 477 persons from nine countries, i.e., Australia, Canada, China, Indonesia, Korea, Philippines, Thailand, the US, and Japan, comprising staff members of intra-regional environment-related organizations. After the keynote speech, `Current status and tasks of environmental technology exchange`, and `Expected roles of the Virtual Center for Environmental Technology Exchange` were discussed. During the plenary session, the chairman summarized the symposium. This summary was carried on the Virtual Center homepage of the Internet

  12. Use of communication technologies in document exchange for the management of construction projects

    Science.gov (United States)

    Mesároš, Peter; Mandičák, Tomáš

    2016-06-01

    Information and communication technologies represent a set of people, processes, technical and software tools providing collection, transport, storage and processing of data for distribution and presentation of information. Particularly communication systems are the main tool for information exchange. Of the other part, these technologies have a broad focus and use. One of them is the exchange of documents in the management of construction projects. Paper discusses the issue of exploitation level of communication technologies in construction project management. The main objective of this paper is to analyze exploitation level of communication technologies. Another aim of the paper is to compare exploitation level or rate of document exchange by electronic communication devices and face-to-face communication.

  13. Use of communication technologies in document exchange for the management of construction projects

    Directory of Open Access Journals (Sweden)

    Mesároš Peter

    2016-06-01

    Full Text Available Information and communication technologies represent a set of people, processes, technical and software tools providing collection, transport, storage and processing of data for distribution and presentation of information. Particularly communication systems are the main tool for information exchange. Of the other part, these technologies have a broad focus and use. One of them is the exchange of documents in the management of construction projects. Paper discusses the issue of exploitation level of communication technologies in construction project management. The main objective of this paper is to analyze exploitation level of communication technologies. Another aim of the paper is to compare exploitation level or rate of document exchange by electronic communication devices and face-to-face communication.

  14. Manufacture of power station heat exchangers using modern production technology

    International Nuclear Information System (INIS)

    Genzlinger, W.; Hoffmann, J.; Ohlhaeuser, K.

    1986-01-01

    Heat exchangers of high quality and operational safety can only be fabricated economically if fabrication is as 'simple' as possible and can be controlled and if, through value analysis, the work flows can be mechanized and automated and the following requirements are met: use of materials that are easy to work with for the application considered, choice of product designs and wall thicknesses that offer favourable conditions for processing and non-destructive testing, placing of seams in such a way that good accessibility for welding and minimum residual welding stresses are assured, minimizing the number of welding seams, use of automatic welding machines for submerged-arc welding and electronically controlled sources of welding current - semi-automatic equipment for spatter-free interfaces (pulse technique), electronically controlled equipment for welding in rollers and pipes and CNC-controlled machining centres for drilling pipe galleries (deep-hole drilling) and baffle plates and for machining the sealing elements after welding. Continuous inspections in each phase of fabrication assures that heat exchangers are made which fully meet the requirements of nuclear power station operators. (orig.)

  15. Current status and future prospects for enabling chemistry technology in the drug discovery process [version 1; referees: 2 approved

    Directory of Open Access Journals (Sweden)

    Stevan W. Djuric

    2016-09-01

    Full Text Available This review covers recent advances in the implementation of enabling chemistry technologies into the drug discovery process. Areas covered include parallel synthesis chemistry, high-throughput experimentation, automated synthesis and purification methods, flow chemistry methodology including photochemistry, electrochemistry, and the handling of “dangerous” reagents. Also featured are advances in the “computer-assisted drug design” area and the expanding application of novel mass spectrometry-based techniques to a wide range of drug discovery activities.

  16. Incorporating Service-Learning, Technology, and Research Supportive Teaching Techniques into the University Chemistry Classroom

    Science.gov (United States)

    Saitta, E. K. H.; Bowdon, M. A.; Geiger, C. L.

    2011-12-01

    Technology was integrated into service-learning activities to create an interactive teaching method for undergraduate students at a large research institution. Chemistry students at the University of Central Florida partnered with high school students at Crooms Academy of Information Technology in interactive service learning projects. The projects allowed UCF students to teach newly acquired content knowledge and build upon course lecture and lab exercises. Activities utilized the web-conferencing tool Adobe Connect Pro to enable interaction with high school students, many of whom have limited access to supplemental educational opportunities due to low socioeconomic status. Seventy chemistry I students created lessons to clarify high school students' misconceptions through the use of refutational texts. In addition, 21 UCF students enrolled in the chemistry II laboratory course acted as virtual lab partners with Crooms students in an interactive guided inquiry experiment focused on chemical kinetics. An overview of project's design, implementation, and assessments are detailed in the case study and serve as a model for future community partnerships. Emerging technologies are emphasized as well as a suggested set of best practices for future projects.

  17. Development of a micro-heat exchanger with stacked plates using LTCC technology

    Directory of Open Access Journals (Sweden)

    E. Vásquez-Alvarez

    2010-09-01

    Full Text Available A green ceramic tape micro-heat exchanger was developed using Low Temperature Co-fired Ceramics technology (LTCC. The device was designed by using Computational Aided Design software and simulations were made using a Computational Fluid Dynamics package (COMSOL Multiphysics to evaluate the homogeneity of fluid distribution in the microchannels. Four geometries were proposed and simulated in two and three dimensions to show that geometric details directly affect the distribution of velocity in the micro-heat exchanger channels. The simulation results were quite useful for the design of the microfluidic device. The micro-heat exchanger was then constructed using the LTCC technology and is composed of five thermal exchange plates in cross-flow arrangement and two connecting plates, with all plates stacked to form a device with external dimensions of 26 x 26 x 6 mm³.

  18. History of establishment of scientific technology law focused on exchanges of Korea, China and Japan

    International Nuclear Information System (INIS)

    Lee, Gyeong Hui

    1990-10-01

    This book introduces science and technology promotion related law, industrial technology related law, resources and energy related law, nuclear energy related law, information and communication related law, intellectual property right related law, and environment related law. It explains process of development of 7 laws in threes countries and relations of three countries exchanges. It also covers special law for science and technology innovation, electric utility law, petroleum enterprise law, telecommunication related law, law of settlement of digital divide, and information-oriented law.

  19. Analysis of the Technological Parameters of the Heat Exchanger in the Heating Pipe

    Directory of Open Access Journals (Sweden)

    Knyazev Vladimir

    2017-01-01

    Full Text Available The main purpose of this article is to analyze the selecting of technological parameters for the heat exchanger to improve the heat transfer and reduce the noise during operation in the heating pipe, which is used in the different systems of the planes and helicopters. In result of this study, the best technical parameters are found, considering different variations of deformation cutting heat exchanger pipes.

  20. Numerical simulation of advective-dispersive multisolute transport with sorption, ion exchange and equilibrium chemistry

    Science.gov (United States)

    Lewis, F.M.; Voss, C.I.; Rubin, Jacob

    1986-01-01

    A model was developed that can simulate the effect of certain chemical and sorption reactions simultaneously among solutes involved in advective-dispersive transport through porous media. The model is based on a methodology that utilizes physical-chemical relationships in the development of the basic solute mass-balance equations; however, the form of these equations allows their solution to be obtained by methods that do not depend on the chemical processes. The chemical environment is governed by the condition of local chemical equilibrium, and may be defined either by the linear sorption of a single species and two soluble complexation reactions which also involve that species, or binary ion exchange and one complexation reaction involving a common ion. Partial differential equations that describe solute mass balance entirely in the liquid phase are developed for each tenad (a chemical entity whose total mass is independent of the reaction process) in terms of their total dissolved concentration. These equations are solved numerically in two dimensions through the modification of an existing groundwater flow/transport computer code. (Author 's abstract)

  1. U.S. Department of Energy national technology information exchange workshops

    International Nuclear Information System (INIS)

    Daub, G.J.; Earle, S.D.; Smibert, A.M.; Wight, E.H.

    1994-01-01

    The U.S. Department of Energy National Technology Information Exchange (TIE) Workshops bring together environmental restoration and technology development personnel to exchange and share problems, needs, technological solutions, ideas, and successes and failures from lessons learned at DOE sites. The success of this forum is measured by the knowledge gained, contacts made, and program dollars saved by the people who actually do the work in the field. TIE is a unique opportunity to unite the DOE community and allow individuals to listen and to learn about each others' problems and solutions. By using today's technologies better, the National TIE Workshops help identify and implement cost-effective and appropriate technologies to meet the needs of the DOE environmental restoration program

  2. Proton exchange membrane fuel cell technology for transportation applications

    Energy Technology Data Exchange (ETDEWEB)

    Swathirajan, S. [General Motors R& D Center, Warren, MI (United States)

    1996-04-01

    Proton Exchange Membrane (PEM) fuel cells are extremely promising as future power plants in the transportation sector to achieve an increase in energy efficiency and eliminate environmental pollution due to vehicles. GM is currently involved in a multiphase program with the US Department of Energy for developing a proof-of-concept hybrid vehicle based on a PEM fuel cell power plant and a methanol fuel processor. Other participants in the program are Los Alamos National Labs, Dow Chemical Co., Ballard Power Systems and DuPont Co., In the just completed phase 1 of the program, a 10 kW PEM fuel cell power plant was built and tested to demonstrate the feasibility of integrating a methanol fuel processor with a PEM fuel cell stack. However, the fuel cell power plant must overcome stiff technical and economic challenges before it can be commercialized for light duty vehicle applications. Progress achieved in phase I on the use of monolithic catalyst reactors in the fuel processor, managing CO impurity in the fuel cell stack, low-cost electrode-membrane assembles, and on the integration of the fuel processor with a Ballard PEM fuel cell stack will be presented.

  3. Simulacra, Symbolic Exchange and Technology in Michel Tournier's La Goutte d'Or

    Directory of Open Access Journals (Sweden)

    David W. Price

    1993-06-01

    Full Text Available In La Goutte d'Or , Michel Tournier offers a critique of Western culture by constructing a novel that reflects both Jean Baudrillard's theories of simulacra and the political economy of the sign and Martin Heidegger's meditations on technology. Tournier's novel explores the relationship between Heidegger's explanation of technology as an act of Enframing ( Ge-stell and Baudrillard's description of an economy based upon exchange-sign value. Thus, through La Goutte d 'Or , Michel Tournier depicts the violent confrontation between a symbolic exchange economy based on poietic acts and late capitalist economies of autonomized signs.

  4. Commercialization of proton exchange membrane (PEM) fuel cell technology

    International Nuclear Information System (INIS)

    Goel, N.; Pant, A.; Sera, G.

    1995-01-01

    The MCTTC performed a market assessment for PEM Fuel Cells for terrestrial applications for the Center for Space Power (CSP). The purpose of the market assessment was to gauge the market and commercial potential for PEM fuel cell technology. Further, the market assessment was divided into subsections of technical and market overview, competitive environment, political environment, barriers to market entry, and keys to market entry. The market assessment conducted by the MCTTC involved both secondary and primary research. The primary target markets for PEM fuel cells were transportation and utilities in the power range of 10 kW to 100 kW. The fuel cell vehicle market size was estimated under a pessimistic scenario and an optimistic scenario. The estimated size of the fuel cell vehicle market in dollar terms for the year 2005 is $17.3 billion for the pessimistic scenario and $34.7 billion for the optimistic scenario. The fundamental and applied research funded and conducted by the National Aeronautics and Space Administration (NASA) and DOE in the area of fuel cells presents an excellent opportunity to commercialize dual-use technology and enhance U.S. business competitiveness. copyright 1995 American Institute of Physics

  5. Advanced Heat/Mass Exchanger Technology for Geothermal and Solar Renewable Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    Greiner, Miles [Univ. of Nevada, Reno, NV (United States); Childress, Amy [Univ. of Nevada, Reno, NV (United States); Hiibel, Sage [Univ. of Nevada, Reno, NV (United States); Kim, Kwang [Univ. of Nevada, Reno, NV (United States); Park, Chanwoo [Univ. of Nevada, Reno, NV (United States); Wirtz, Richard [Univ. of Nevada, Reno, NV (United States)

    2014-12-16

    Northern Nevada has abundant geothermal and solar energy resources, and these renewable energy sources provide an ample opportunity to produce economically viable power. Heat/mass exchangers are essential components to any energy conversion system. Improvements in the heat/mass exchange process will lead to smaller, less costly (more efficient) systems. There is an emerging heat transfer technology, based on micro/nano/molecular-scale surface science that can be applied to heat/mass exchanger design. The objective is to develop and characterize unique coating materials, surface configurations and membranes capable of accommodating a 10-fold increase in heat/mass exchanger performance via phase change processes (boiling, condensation, etc.) and single phase convective heat/mass transfer.

  6. Recent advances in medicinal chemistry and pharmaceutical technology--strategies for drug delivery to the brain.

    Science.gov (United States)

    Denora, Nunzio; Trapani, Adriana; Laquintana, Valentino; Lopedota, Angela; Trapani, Giuseppe

    2009-01-01

    This paper provides a mini-review of some recent approaches for the treatment of brain pathologies examining both medicinal chemistry and pharmaceutical technology contributions. Medicinal chemistry-based strategies are essentially aimed at the chemical modification of low molecular weight drugs in order to increase their lipophilicity or the design of appropriate prodrugs, although this review will focus primarily on the use of prodrugs and not analog development. Recently, interest has been focused on the design and evaluation of prodrugs that are capable of exploiting one or more of the various endogenous transport systems at the level of the blood brain barrier (BBB). The technological strategies are essentially non-invasive methods of drug delivery to malignancies of the central nervous system (CNS) and are based on the use of nanosystems (colloidal carriers) such as liposomes, polymeric nanoparticles, solid lipid nanoparticles, polymeric micelles and dendrimers. The biodistribution of these nanocarriers can be manipulated by modifying their surface physico-chemical properties or by coating them with surfactants and polyethylene-glycols (PEGs). Liposomes, surfactant coated polymeric nanoparticles, and solid lipid nanoparticles are promising systems for delivery of drugs to tumors of the CNS. This mini-review discusses issues concerning the scope and limitations of both the medicinal chemistry and technological approaches. Based on the current findings, it can be concluded that crossing of the BBB and drug delivery to CNS is extremely complex and requires a multidisciplinary approach such as a close collaboration and common efforts among researchers of several scientific areas, particularly medicinal chemists, biologists and pharmaceutical technologists.

  7. The Atmospheric Chemistry and Canopy Exchange Simulation System (ACCESS: model description and application to a temperate deciduous forest canopy

    Directory of Open Access Journals (Sweden)

    R. D. Saylor

    2013-01-01

    Full Text Available Forest canopies are primary emission sources of biogenic volatile organic compounds (BVOCs and have the potential to significantly influence the formation and distribution of secondary organic aerosol (SOA mass. Biogenically-derived SOA formed as a result of emissions from the widespread forests across the globe may affect air quality in populated areas, degrade atmospheric visibility, and affect climate through direct and indirect forcings. In an effort to better understand the formation of SOA mass from forest emissions, a 1-D column model of the multiphase physical and chemical processes occurring within and just above a vegetative canopy is being developed. An initial, gas-phase-only version of this model, the Atmospheric Chemistry and Canopy Exchange Simulation System (ACCESS, includes processes accounting for the emission of BVOCs from the canopy, turbulent vertical transport within and above the canopy and throughout the height of the planetary boundary layer (PBL, near-explicit representation of chemical transformations, mixing with the background atmosphere and bi-directional exchange between the atmosphere and canopy and the atmosphere and forest floor. The model formulation of ACCESS is described in detail and results are presented for an initial application of the modeling system to Walker Branch Watershed, an isoprene-emission-dominated forest canopy in the southeastern United States which has been the focal point for previous chemical and micrometeorological studies. Model results of isoprene profiles and fluxes are found to be consistent with previous measurements made at the simulated site and with other measurements made in and above mixed deciduous forests in the southeastern United States. Sensitivity experiments are presented which explore how canopy concentrations and fluxes of gas-phase precursors of SOA are affected by background anthropogenic nitrogen oxides (NOx. Results from these experiments suggest that the

  8. Synthetics, mineral oils, and bio-based lubricants chemistry and technology

    CERN Document Server

    Rudnick, Leslie R

    2005-01-01

    As the field of tribology has evolved, the lubrication industry is also progressing at an extraordinary rate. Updating the author's bestselling publication, Synthetic Lubricants and High-Performance Functional Fluids, this book features the contributions of over 60 specialists, ten new chapters, and a new title to reflect the evolving nature of the field: Synthetics, Mineral Oils, and Bio-Based Lubricants: Chemistry and Technology. The book contains chapters on all major lubricant fluids used in a wide range of applications. For each type of lubricant, the authors discuss the historical develo

  9. Nanoinformatics: an emerging area of information technology at the intersection of bioinformatics, computational chemistry and nanobiotechnology

    Directory of Open Access Journals (Sweden)

    Fernando González-Nilo

    2011-01-01

    Full Text Available After the progress made during the genomics era, bioinformatics was tasked with supporting the flow of information generated by nanobiotechnology efforts. This challenge requires adapting classical bioinformatic and computational chemistry tools to store, standardize, analyze, and visualize nanobiotechnological information. Thus, old and new bioinformatic and computational chemistry tools have been merged into a new sub-discipline: nanoinformatics. This review takes a second look at the development of this new and exciting area as seen from the perspective of the evolution of nanobiotechnology applied to the life sciences. The knowledge obtained at the nano-scale level implies answers to new questions and the development of new concepts in different fields. The rapid convergence of technologies around nanobiotechnologies has spun off collaborative networks and web platforms created for sharing and discussing the knowledge generated in nanobiotechnology. The implementation of new database schemes suitable for storage, processing and integrating physical, chemical, and biological properties of nanoparticles will be a key element in achieving the promises in this convergent field. In this work, we will review some applications of nanobiotechnology to life sciences in generating new requirements for diverse scientific fields, such as bioinformatics and computational chemistry.

  10. Synthetic biology and biomimetic chemistry as converging technologies fostering a new generation of smart biosensors.

    Science.gov (United States)

    Scognamiglio, Viviana; Antonacci, Amina; Lambreva, Maya D; Litescu, Simona C; Rea, Giuseppina

    2015-12-15

    Biosensors are powerful tunable systems able to switch between an ON/OFF status in response to an external stimulus. This extraordinary property could be engineered by adopting synthetic biology or biomimetic chemistry to obtain tailor-made biosensors having the desired requirements of robustness, sensitivity and detection range. Recent advances in both disciplines, in fact, allow to re-design the configuration of the sensing elements - either by modifying toggle switches and gene networks, or by producing synthetic entities mimicking key properties of natural molecules. The present review considered the role of synthetic biology in sustaining biosensor technology, reporting examples from the literature and reflecting on the features that make it a useful tool for designing and constructing engineered biological systems for sensing application. Besides, a section dedicated to bioinspired synthetic molecules as powerful tools to enhance biosensor potential is reported, and treated as an extension of the concept of biomimetic chemistry, where organic synthesis is used to generate artificial molecules that mimic natural molecules. Thus, the design of synthetic molecules, such as aptamers, biomimetics, molecular imprinting polymers, peptide nucleic acids, and ribozymes were encompassed as "products" of biomimetic chemistry. Copyright © 2015 Elsevier B.V. All rights reserved.

  11. Capability of cation exchange technology to remove proven N-nitrosodimethylamine precursors.

    Science.gov (United States)

    Li, Shixiang; Zhang, Xulan; Bei, Er; Yue, Huihui; Lin, Pengfei; Wang, Jun; Zhang, Xiaojian; Chen, Chao

    2017-08-01

    N-nitrosodimethylamine (NDMA) precursors consist of a positively charged dimethylamine group and a non-polar moiety, which inspired us to develop a targeted cation exchange technology to remove NDMA precursors. In this study, we tested the removal of two representative NDMA precursors, dimethylamine (DMA) and ranitidine (RNTD), by strong acidic cation exchange resin. The results showed that pH greatly affected the exchange efficiency, with high removal (DMA>78% and RNTD>94%) observed at pHMg 2+ >RNTD + >K + >DMA + >NH 4 + >Na + . The partition coefficient of DMA + to Na + was 1.41±0.26, while that of RNTD + to Na + was 12.1±1.9. The pseudo second-order equation fitted the cation exchange kinetics well. Bivalent inorganic cations such as Ca 2+ were found to have a notable effect on NA precursor removal in softening column test. Besides DMA and RNTD, cation exchange process also worked well for removing other 7 model NDMA precursors. Overall, NDMA precursor removal can be an added benefit of making use of cation exchange water softening processes. Copyright © 2017. Published by Elsevier B.V.

  12. The impact of technological improvements on developing financial markets: The case of the Johannesburg Stock Exchange

    Directory of Open Access Journals (Sweden)

    Mehmet F. Dicle

    2013-07-01

    Full Text Available Can a significant technological improvement make an economically justifiable contribution to a financial market's development? The Johannesburg Stock Exchange (JSE incorporated the SETS system from the London Stock Exchange in 2002. It is certain that SETS is a technologically efficient trading system, and it would undoubtedly improve trading in the JSE. We test whether SETS represents a structural break by examining whether there was an increase in the JSE's liquidity, market efficiency and international integration after the introduction of SETS. While SETS is certainly a technological improvement with increased liquidity, it is not a sufficient factor to render it efficient. After the incorporation of SETS, the JSE has become more independent and it now offers better diversification opportunities for international investors.

  13. Identity Orientation, Social Exchange, and Information Technology Use in Interorganizational Collaborations

    DEFF Research Database (Denmark)

    Gal, Uri; Jensen, Tina Blegind; Lyytinen, Kalle

    2014-01-01

    Advances in information technologies (IT) are creating unprecedented opportunities for interorganizational collaboration, particularly in large-scale distributed projects. The use of advanced IT in such projects can foster new forms of social exchange among organizations and change the way...... identity orientations. To address this gap, we conduct multiple case studies that describe the changing use of two-dimensional computer-aided design technology and new three-dimensional modeling technologies by a leading metal fabrication company in the architecture, engineering, and construction industry...

  14. Radiation processing of polymers and semiconductors at the Institute of Nuclear Chemistry and Technology

    International Nuclear Information System (INIS)

    Zimek, Z.; Przybytniak, G.; Kaluska, I.

    2006-01-01

    R(and)D studies in the field of radiation technology in Poland are mostly concentrated at the Institute of Nuclear Chemistry and Technology (INCT). The results of the INCT works on polymer and semiconductor modification have been implemented in various branches of national economy, particularly in industry and medicine. Radiation technology for polymer modification was implemented in the middle of the 1970-ties. Among others, the processes of irradiation and heat shrinkable products expansion have been developed. The transfer of this technology to Polish industry was performed in the middle of the 1980-ties. The present study aims at the formulation of new PE composites better suited to new generation of heat shrinkable products, for example, a new generation of hot-melt adhesives has been developed to meet specific requirements of customers. Modified polypropylene was used for the production of medical devices sterilized by radiation, especially disposable syringes, to overcome the low radiation resistance of the basic material. Modified polypropylene (PP-M) has been formulated at the INCT to provide material suitable for medical application and radiation sterilization process. Modification of semiconductor devices by EB was applied on an industrial scale since 1978 when the INCT and the LAMINA semiconductor factory successfully adopted that technology to improve specific semiconductor devices. This activity is continued on commercial basis where the INCT facilities served to contract irradiation of certain semiconductor devices according to the manufacturing program of the Polish factory and customers from abroad. (author)

  15. Proceeding of the Scientific Meeting and Presentation on Basic Research of Nuclear Science and Technology: Book II. Nuclear Chemistry, Process Technology, and Radioactive Waste Processing and Environment

    International Nuclear Information System (INIS)

    1996-06-01

    The proceeding contains papers presented on Scientific Meeting and Presentation on on Basic Research of Nuclear Science and Technology, held in Yogyakarta, 25-27 April 1995. This proceeding is second part of two books published for the meeting contains papers on nuclear chemistry, process technology, and radioactive waste management and environment. There are 62 papers indexed individually. (ID)

  16. Electron beam facilities and technologies developed in the Institute of Nuclear Chemistry and Technology

    International Nuclear Information System (INIS)

    Chmielewski, A.G.; Walis, L.; Zimek, Z.

    1992-01-01

    The operation of the first electron accelerator has been started at Institute /former Institute for Nuclear Research/ in 1971. This LAE-13/9 accelerator is a two-section lineac with adjustable energy of electrons: 5 to 13 MeV and the beam power up to 9 kW. The main technologies developed on the basis of LAE-13/9 are: sterilization, manufacturing of thermoshrinkable materials and modification of semiconductors. The accelerator is operated 4000 hours per year and used for small scale production and services in these fields. The other problems investigated in laboratory scale are: food preservation and hygenization, hygenization of municipal sewage sludge, and bio-conversion of pig-farm wastes into animal fodder. The laboratory experiments are basis for pilot construction and other industrial applications. The mentioned technology of thermoshrinkable tube production was implemented in industrial scale at ZWUT Czluchow which factory is equipped in the accelerator ILU-6 /20 kW, 2 MeV/. On the basis of similar unit a technological installation was built at Institute. The plant is furnished with a conveyer and the rewinding machines for tubes and tapes manufacturing. This allows continuous production of these materials. The plant will start operation next year and linear accelerator /10 MeV, 15 kW/ for this purpose is already delivered. The pilot plant for food preservation and hygenization has been built. It is equipped in small pilot accelerator 10 MeV, 1 kW and will be furnished with 10 MeV, 10 kW lineac this year. Beside of this technological lines Institute is furnished in Van de Graff accelerator /2, MeV, 100 μA/ and another laboratory unit LAE-10 /10 MeV, 10-100 ns 2 us/ is under construction. (J.P.N.)

  17. 2D fluorescence spectroscopy for monitoring ion-exchange membrane based technologies - Reverse electrodialysis (RED).

    Science.gov (United States)

    Pawlowski, Sylwin; Galinha, Claudia F; Crespo, João G; Velizarov, Svetlozar

    2016-01-01

    Reverse electrodialysis (RED) is one of the emerging, membrane-based technologies for harvesting salinity gradient energy. In RED process, fouling is an undesirable operation constraint since it leads to a decrease of the obtainable net power density due to increasing stack electric resistance and pressure drop. Therefore, early fouling detection is one of the main challenges for successful RED technology implementation. In the present study, two-dimensional (2D) fluorescence spectroscopy was used, for the first time, as a tool for fouling monitoring in RED. Fluorescence excitation-emission matrices (EEMs) of ion-exchange membrane surfaces and of natural aqueous streams were acquired during one month of a RED stack operation. Fouling evolvement on the ion-exchange membrane surfaces was successfully followed by 2D fluorescence spectroscopy and quantified using principal components analysis (PCA). Additionally, the efficiency of cleaning strategy was assessed by measuring the membrane fluorescence emission intensity before and after cleaning. The anion-exchange membrane (AEM) surface in contact with river water showed to be significantly affected due to fouling by humic compounds, which were found to cross through the membrane from the lower salinity (river water) to higher salinity (sea water) stream. The results obtained show that the combined approach of using 2D fluorescence spectroscopy and PCA has a high potential for studying fouling development and membrane cleaning efficiency in ion exchange membrane processes. Copyright © 2015 Elsevier Ltd. All rights reserved.

  18. Reducing cognitive load in the chemistry laboratory by using technology-driven guided inquiry experiments

    Science.gov (United States)

    Hubacz, Frank, Jr.

    The chemistry laboratory is an integral component of the learning experience for students enrolled in college-level general chemistry courses. Science education research has shown that guided inquiry investigations provide students with an optimum learning environment within the laboratory. These investigations reflect the basic tenets of constructivism by engaging students in a learning environment that allows them to experience what they learn and to then construct, in their own minds, a meaningful understanding of the ideas and concepts investigated. However, educational research also indicates that the physical plant of the laboratory environment combined with the procedural requirements of the investigation itself often produces a great demand upon a student's working memory. This demand, which is often superfluous to the chemical concept under investigation, creates a sensory overload or extraneous cognitive load within the working memory and becomes a significant obstacle to student learning. Extraneous cognitive load inhibits necessary schema formation within the learner's working memory thereby impeding the transfer of ideas to the learner's long-term memory. Cognitive Load Theory suggests that instructional material developed to reduce extraneous cognitive load leads to an improved learning environment for the student which better allows for schema formation. This study first compared the cognitive load demand, as measured by mental effort, experienced by 33 participants enrolled in a first-year general chemistry course in which the treatment group, using technology based investigations, and the non-treatment group, using traditional labware, investigated identical chemical concepts on five different exercises. Mental effort was measured via a mental effort survey, a statistical comparison of individual survey results to a procedural step count, and an analysis of fourteen post-treatment interviews. Next, a statistical analysis of achievement was

  19. Development and analysis of educational technologies for a blended organic chemistry course

    Science.gov (United States)

    Evans, Michael James

    Blended courses incorporate elements of both face-to-face and online instruction. The extent to which blended courses are conducted online, and the proper role of the online components of blended courses, have been debated and may vary. What can be said in general, however, is that online tools for blended courses are typically culled together from a variety of sources, are often very large scale, and may present distractions for students that decrease their utility as teaching tools. Furthermore, large-scale educational technologies may not be amenable to rigorous, detailed study, limiting evaluation of their effectiveness. Small-scale educational technologies run from the instructor's own server have the potential to mitigate many of these issues. Such tools give the instructor or researcher direct access to all available data, facilitating detailed analysis of student use. Code modification is simple and rapid if errors arise, since code is stored where the instructor can easily access it. Finally, the design of a small-scale tool can target a very specific application. With these ideas in mind, this work describes several projects aimed at exploring the use of small-scale, web-based software in a blended organic chemistry course. A number of activities were developed and evaluated using the Student Assessment of Learning Gains survey, and data from the activities were analyzed using quantitative methods of statistics and social network analysis methods. Findings from this work suggest that small-scale educational technologies provide significant learning benefits for students of organic chemistry---with the important caveat that instructors must offer appropriate levels of technical and pedagogical support for students. Most notably, students reported significant learning gains from activities that included collaborative learning supported by novel online tools. For the particular context of organic chemistry, which has a unique semantic language (Lewis

  20. Technology Development Roadmap for the Advanced High Temperature Reactor Secondary Heat Exchanger

    Energy Technology Data Exchange (ETDEWEB)

    P. Sabharwall; M. McCllar; A. Siahpush; D. Clark; M. Patterson; J. Collins

    2012-09-01

    This Technology Development Roadmap (TDRM) presents the path forward for deploying large-scale molten salt secondary heat exchangers (MS-SHX) and recognizing the benefits of using molten salt as the heat transport medium for advanced high temperature reactors (AHTR). This TDRM will aid in the development and selection of the required heat exchanger for: power production (the first anticipated process heat application), hydrogen production, steam methane reforming, methanol to gasoline production, or ammonia production. This TDRM (a) establishes the current state of molten salt SHX technology readiness, (b) defines a path forward that systematically and effectively tests this technology to overcome areas of uncertainty, (c) demonstrates the achievement of an appropriate level of maturity prior to construction and plant operation, and (d) identifies issues and prioritizes future work for maturing the state of SHX technology. This study discusses the results of a preliminary design analysis of the SHX and explains the evaluation and selection methodology. An important engineering challenge will be to prevent the molten salt from freezing during normal and off-normal operations because of its high melting temperature (390°C for KF ZrF4). The efficient transfer of energy for industrial applications depends on the ability to incorporate cost-effective heat exchangers between the nuclear heat transport system and industrial process heat transport system. The need for efficiency, compactness, and safety challenge the capabilities of existing heat exchanger technology. The description of potential heat exchanger configurations or designs (such as printed circuit, spiral or helical coiled, ceramic, plate and fin, and plate type) were covered in an earlier report (Sabharwall et al. 2011). Significant future work, much of which is suggested in this report, is needed before the benefits and full potential of the AHTR can be realized. The execution of this TDRM will focuses

  1. Joint Thesaurus. Part I (A-L) + Part II (M-Z)[International Nuclear Information System. Energy Technology Data Exchange

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-04-01

    This is the 1st revision of the INIS/ETDE Joint Thesaurus. It contains 20 953 valid descriptors and 8 600 forbidden terms. It was last updated in December 2003. The Joint Thesaurus contains the controlled terminology for indexing all information within the subject scope of both INIS (International Nuclear Information System) and ETDE (Energy Technology Data Exchange) information systems. The terminology is intended for use in subject description for input or retrieval of information in those systems. The thesaurus is a terminological control device used in translating from the natural language of documents, indexers or users into a more constrained system language It is also a controlled and dynamic vocabulary of semantically and generically related terms which covers a specific domain of knowledge. The domain of knowledge covered by this Thesaurus includes physics (in particular, plasma physics, atomic and molecular physics, and especially nuclear and high-energy physics), chemistry, materials, earth sciences, radiation biology, radioisotope effects and kinetics, applied life sciences, radiology and nuclear medicine, isotope and radiation source technology, radiation protection, radiation applications, engineering, instrumentation, fossil fuels, synthetic fuels, renewable energy sources, advanced energy systems, fission and fusion reactor technology, safeguards and inspection, waste management, environmental aspects of the production and consumption of energy from nuclear and non-nuclear sources, energy efficiency and energy conservation, economics and sociology of energy production and use, energy policy, and nuclear law. The terms in the Thesaurus are listed alphabetically, and with each alphabetic entry a word block containing the terms associated with the particular entry is displayed. In the word block, terms that have a hierarchical relationship to the entry are identified by the symbols BT and NT, for Broader Term and Narrower Term. Those with an affinitive

  2. Technological aspects of vegetable oils epoxidation in the presence of ion exchange resins: a review

    Directory of Open Access Journals (Sweden)

    Milchert Eugeniusz

    2016-09-01

    Full Text Available A review paper of the technology basics of vegetable oils epoxidation by means of peracetic or performic acid in the presence of acidic ion exchange resins has been presented. The influence of the following parameters: temperature, molar ratio of acetic acid and hydrogen peroxide to ethylenic unsaturation, catalyst loading, stirring intensity and the reaction time on a conversion of ethylenic unsaturation, the relative percentage conversion to oxirane and the iodine number was discussed. Optimal technological parameters, mechanism of epoxidation by carboxylic peracids and the possibilities of catalyst recycling have been also discussed. This review paper shows the application of epoxidized oils.

  3. Assessing the role of cation exchange in controlling groundwater chemistry during fluid mixing in fractured granite at Aespoe, Sweden

    International Nuclear Information System (INIS)

    Viani, B.E.; Bruton, C.J.

    1996-06-01

    Geochemical modeling was used to simulate the mixing of dilute shallow groundwater with deeper more saline groundwater in the fractured granite of the Redox Zone at the Aespoe underground Hard Rock Laboratory (HRL). Fluid mixing simulations were designed to assess the role that cation exchange plays in controlling the composition of fluids entering the HRL via fracture flow. Mixing simulations included provision for the effects of mineral precipitation and cation exchange on fluid composition. Because the predominant clay mineral observed in fractures in the Redox Zone has been identified as illite or mixed layer illite smectite, an exchanger with the properties of illite was used to simulate cation exchange. Cation exchange on illite was modeled using three exchange sites, a planar or basal plane site with properties similar to smectite, and two edge sites that have very high affinities for K, Rb, and Cs. Each site was assumed to obey an ideal Vanselow exchange model, and exchange energies for each site were taken from the literature. The predicted behaviors of Na, Ca, and Mg during mixing were similar to those reported in a previous study in which smectite was used as the model for the exchanger. The trace elements Cs and Rb were predicted to be strongly associated with the illite exchanger, and the predicted concentrations of Cs in fracture fill were in reasonable agreement with reported chemical analyses of exchangeable Cs in fracture fill. The results of the geochemical modeling suggest that Na, Ca, and Sr concentrations in the fluid phase may be controlled by cation exchange reactions that occur during mixing, but that Mg appears to behave conservatively. There is currently not enough data to make conclusions regarding the behavior of Cs and Rb

  4. Proceedings of the Scientific Meeting and Presentation on Basic Researchin Nuclear Science and Technology part II: Nuclear Chemistry, Process Technology, Radioactive Waste Management and Environment

    International Nuclear Information System (INIS)

    Sukarsono, R.; Karmanto, Eko-Edy; Suradjijo, Ganang

    2000-01-01

    Scientific Meeting and Presentation on Basic Research in Nuclear Scienceand Technology is an annual activity held by Centre for Research and Development of Advanced Technology, National Nuclear Energy Agency, for monitoring research activities achieved by the Agency. The papers presented in the meeting were collected into proceedings. These are the second part of the proceedings that contain 71 articles in the fields of nuclear chemistry, process technology, radioactive waste management, and environment (PPIN).

  5. Green Chemistry Technology and Product Development. Final Report for Intermediary Biochemicals, Inc.

    Energy Technology Data Exchange (ETDEWEB)

    Zeikus, J. Gregory [Michigan State Univ., East Lansing, MI (United States). Dept. of Microbiology & Molecular Genetics

    2010-08-28

    The DOE funds in this award were applied to developing systems to cost effectively produce intermediate (1 dollar$-$1,000 dollars per kg) and fine ($1,000 per kg) chemicals from renewable feedstocks using environmentally responsible processes via collaboration with academic research laboratories to provide targeted technology and early product development. Specifically, development of a thermostable alkaline phosphatase overexpression system to provide supplies and reagents for improved biological test kits, creation of a microbial strain for the efficient production of aspartate from glucose (replacing oil-derived fumarate in aspartate production), and early development research for an electrochemical bioreactor for the conversion of glucose to mannitol were targeted by this research. Also, establishing this positive academic/industrial collaboration with Michigan State University Laboratories and fostering greater inter-laboratory collaboration would also support the strategy of efficiently transitioning academic green chemistry research into the commercial sector and open an avenue to low cost early product development coupled with scientific training.

  6. Joint research and development and exchange of technology on toxic material emergency response between LLNL and ENEA. 1985 progress report

    International Nuclear Information System (INIS)

    Dickerson, M.H.; Caracciolo, R.

    1986-01-01

    For the past six years, the US Department of Energy, LLNL, and the ENEA, Rome, Italy, have participated in cooperative studies for improving a systems approach to an emergency response following nuclear accidents. Technology exchange between LLNL and the ENEA was initially confined to the development, application, and evaluation of atmospheric transport and diffusion models. With the emergence of compatible hardware configurations between LLNL and ENEA, exchanges of technology and ideas for improving the development and implementation of systems are beginning to emerge. This report describes cooperative work that has occurred during the past three years, the present state of each system, and recommendations for future exchanges of technology

  7. The nature of science and technology for pre-service chemistry teacher: A case of techno-chemistry experiment "From Stannum Metalicum to conductive glass"

    Science.gov (United States)

    Mudzakir, A.; Widhiyanti, T.; Hernani, Arifin, M.; Lestari, A. N.; Jauhariansyah, S.

    2017-08-01

    The study was conducted to address the problems related to low Indonesian students' scientific literacy as revealed in the PISA (Program for International Student Assessment) since 2000-2015. Science teachers (e.g. chemistry teacher) must recognize the nature of science (NOS) to assist their students in preparing an explanation of a phenomenon scientifically correctly. Teachers also need to understand critically about nature of technology (NOT) and it relationship with science as well as society. To integrate those two kinds of knowledge (NOS and NOT), we can conduct a techno-science activity, which integrate the technology to science course in pre-service teacher education program, so that they can improve their knowledge about nature of science and technology (NOST) and pedagogical content knowledge related to NOST. The purpose of this study was to construct an inquiry based laboratory activity worksheet for making conductive glass so that the pre-service teacher could explain how the structure of the semiconductor Fluor doped Tin Oxide (SnO2.F) affect their performance. This study we conducted, described how to design a pre-service chemistry teacher education course that can improve recognizing view of NOST by using a framework called model of educational reconstruction (MER). The scientific activities in the course were guided inquiry based techno-chemistry experiments involving "From Stannum Metallicum to Conductive Glass". Conductive glasses are interesting subject research for several reason. The application of this technology could be found on solar cell, OLED, and display panel. The doped Tin dioxide has been deposited on glass substrate using the spray pyrolysis technique at 400-550°C substrate temperature, 4-5 times, 20 cm gap between glass and sprayer and 450 angle to form a thin film which will act as electrical contact. The resistivity is about 0.5 - 15Ω. The product resulted on this study was rated by several expert to find if the worksheet could

  8. International technology exchange in support of the Defense Waste Processing Facility wasteform production

    International Nuclear Information System (INIS)

    Kitchen, B.G.

    1989-01-01

    The nearly completed Defense Waste Processing Facility (DWPF) is a Department of Energy (DOE) facility at the Savannah River Site that is designed to immobilize defense high level radioactive waste (HLW) by vitrification in borosilicate glass and containment in stainless steel canisters suitable for storage in the future DOE HLW repository. The DWPF is expected to start cold operation later this year (1990), and will be the first full scale vitrification facility operating in the United States, and the largest in the world. The DOE has been coordinating technology transfer and exchange on issues relating to HLW treatment and disposal through bi-lateral agreements with several nations. For the nearly fifteen years of the vitrification program at Savannah River Laboratory, over two hundred exchanges have been conducted with a dozen international agencies involving about five-hundred foreign national specialists. These international exchanges have been beneficial to the DOE's waste management efforts through confirmation of the choice of the waste form, enhanced understanding of melter operating phenomena, support for paths forward in political/regulatory arenas, confirmation of costs for waste form compliance programs, and establishing the need for enhancements of melter facility designs. This paper will compare designs and schedules of the international vitrification programs, and will discuss technical areas where the exchanges have provided data that have confirmed and aided US research and development efforts, impacted the design of the DWPF and guided the planning for regulatory interaction and product acceptance

  9. Crisis, change and creativity in science and technology: chemistry in the aftermath of twentieth-century global wars.

    Science.gov (United States)

    Johnson, Jeffrey Allan

    2011-07-01

    This paper presents the organising ideas behind the symposium "Chemistry in the Aftermath of World Wars," held at the 23rd International Congress of History of Science and Technology, Budapest, 2009, whose theme was "Ideas and Instruments in Social Context." After first recounting the origins of the notion of "crisis" as a decisive turning point in general history as well as in the history of science, the paper presents war and its aftermath as a form of crisis that may affect science and technology, including chemistry, in a variety of contexts and leading to a variety of types of change. The twentieth-century world wars were exemplary forms of crisis, whose aftermaths shaped the contexts for decisive changes in modern chemistry, which continue to offer challenging opportunities for historical research. In discussing these, the paper cites selected current literature and briefly describes how the individual papers of the symposium, including the three papers published in this volume, approached these challenges.

  10. Chemistry Teacher Candidates' Acceptance and Opinions about Virtual Reality Technology for Molecular Geometry

    Science.gov (United States)

    Saritas, M. T.

    2015-01-01

    The meaningful knowledge creation about molecular geometry has always been the challenge of chemistry learning. In particular, microscopic world of chemistry science (example, atoms, molecules, structures) used in traditional two dimensional way of chemistry teaching can lead to such problem as students create misconceptions. In recent years,…

  11. 77 FR 43131 - Designation of the Center for Innovation and Technology Cooperation (CITC), Pentane Chemistry...

    Science.gov (United States)

    2012-07-23

    ... Cooperation (CITC), Pentane Chemistry Industries (PCI), and Hossein Tanideh Pursuant to Executive Order 13382... (CITC), Pentane Chemistry Industries (PCI), and Hossein Tanideh Pursuant to E.O. 13382. SUMMARY... Cooperation (CITC), Pentane Chemistry Industries (PCI), and Hossein Tanideh, have engaged, or attempted to...

  12. 78 FR 13142 - Designation of the Center for Innovation and Technology Cooperation (CITC), Pentane Chemistry...

    Science.gov (United States)

    2013-02-26

    ... Cooperation (CITC), Pentane Chemistry Industries (PCI), and Hossein Tanideh Pursuant to Executive Order 13382... (CITC), Pentane Chemistry Industries (PCI), and Hossein Tanideh Pursuant to E.O. 13382. SUMMARY... Cooperation (CITC), Pentane Chemistry Industries (PCI), and Hossein Tanideh, have engaged, or attempted to...

  13. Gaseous anion chemistry. Hydrogen-deuterium exchange in mono- and dialcohol alkoxide ions: ionization reactions in dialcohols

    International Nuclear Information System (INIS)

    Lloyd, J.R.; Agosta, W.C.; Field, F.H.

    1980-01-01

    The subject of this work is H-D exchange in certain gaseous anions using D 2 as the exchanging agent. The anions involved are produced from ethylene glycol, 1,3-propanediol, 1,4-butanediol, ethanol, 1-propanol, and 1-butanol. Spectra and postulated ionization reactions for these mono- and dialcohols are given. Hydrogen-deuterium exchange occurs in the (M - 1) - and (2M - 1) - ions of ethylene glycol, 1,3-propanediol, and 1,4-butanediol. The amount of exchange occurring is 3-8 times greater in (2M - 1) - than in (M - 1) - . The amount of H-D exchange occurring in ethanol, 1-propanol, and 1-butanol is small or zero in the (2M - 1) - ions and in the (M - 1) - ion for 1-butanol [the only (M - 1) - ion which could be examined experimentally]. The amount of exchange occurring in the (2M - 1) - and (M - 1) - ions from ethylene glycol is not affected by the total pressure or composition of the reaction mixture in the ionization chamber of the mass spectrometer. A novel hydrogen-bridging mechanism is suggested to account for the observed exchange occurring in the dialcohols

  14. Effects of Information and Communication Technology (ICT) on Students' Academic Achievement and Retention in Chemistry at Secondary Level

    Science.gov (United States)

    Hussain, Ishtiaq; Suleman, Qaiser; ud Din, M. Naseer; Shafique, Farhan

    2017-01-01

    The current paper investigated the effects of information and communication technology on the students' academic achievement and retention in chemistry. Fifty students of 9th grade were selected randomly from Kohsar Public School and College Latamber Karak. The students were grouped into equivalent groups based on pretest score. In order to…

  15. High temperature heat exchanger application in power engineering and energy-technological processes

    International Nuclear Information System (INIS)

    Shpilrain, E.E.

    1986-01-01

    The possibilities for intensification of various processes in metallurgy and chemical technology, the prospects for enhancing power plant efficiency are often linked with temperature increase of reagents, heat carriers and working fluids. In some cases elevated temperatures give the opportunity to use new and principally different technologies, enhance capacities of power production units and technological apparatuses, improve their economical performance. The variety of problems where high temperature heat exchangers are or can be used are extremely wide. It is therefore impossible to overview all of them in one lecture. Therefore the author tries to consider only some examples which are typical and gives an impression of what kind of problems arise in these cases

  16. Progress report on nuclear science and technology in China (Vol.3). Proceedings of academic annual meeting of China Nuclear Society in 2013, No.4--Nuclear chemistry and radiation chemistry sub-volume

    International Nuclear Information System (INIS)

    2014-05-01

    Progress report on nuclear science and technology in China (Vol. 3) includes 24 articles which are communicated on the third national academic annual meeting of China Nuclear Society. There are 10 books totally. This is the fourth one, the content is about Nuclear chemistry and radiation chemistry sub-volume

  17. LITERATURE REVIEWS TO SUPPORT ION EXCHANGE TECHNOLOGY SELECTION FOR MODULAR SALT PROCESSING

    International Nuclear Information System (INIS)

    King, W.

    2007-01-01

    This report summarizes the results of literature reviews conducted to support the selection of a cesium removal technology for application in a small column ion exchange (SCIX) unit supported within a high level waste tank. SCIX is being considered as a technology for the treatment of radioactive salt solutions in order to accelerate closure of waste tanks at the Savannah River Site (SRS) as part of the Modular Salt Processing (MSP) technology development program. Two ion exchange materials, spherical Resorcinol-Formaldehyde (RF) and engineered Crystalline Silicotitanate (CST), are being considered for use within the SCIX unit. Both ion exchange materials have been studied extensively and are known to have high affinities for cesium ions in caustic tank waste supernates. RF is an elutable organic resin and CST is a non-elutable inorganic material. Waste treatment processes developed for the two technologies will differ with regard to solutions processed, secondary waste streams generated, optimum column size, and waste throughput. Pertinent references, anticipated processing sequences for utilization in waste treatment, gaps in the available data, and technical comparisons will be provided for the two ion exchange materials to assist in technology selection for SCIX. The engineered, granular form of CST (UOP IE-911) was the baseline ion exchange material used for the initial development and design of the SRS SCIX process (McCabe, 2005). To date, in-tank SCIX has not been implemented for treatment of radioactive waste solutions at SRS. Since initial development and consideration of SCIX for SRS waste treatment an alternative technology has been developed as part of the River Protection Project Waste Treatment Plant (RPP-WTP) Research and Technology program (Thorson, 2006). Spherical RF resin is the baseline media for cesium removal in the RPP-WTP, which was designed for the treatment of radioactive waste supernates and is currently under construction in Hanford, WA

  18. LITERATURE REVIEWS TO SUPPORT ION EXCHANGE TECHNOLOGY SELECTION FOR MODULAR SALT PROCESSING

    Energy Technology Data Exchange (ETDEWEB)

    King, W

    2007-11-30

    This report summarizes the results of literature reviews conducted to support the selection of a cesium removal technology for application in a small column ion exchange (SCIX) unit supported within a high level waste tank. SCIX is being considered as a technology for the treatment of radioactive salt solutions in order to accelerate closure of waste tanks at the Savannah River Site (SRS) as part of the Modular Salt Processing (MSP) technology development program. Two ion exchange materials, spherical Resorcinol-Formaldehyde (RF) and engineered Crystalline Silicotitanate (CST), are being considered for use within the SCIX unit. Both ion exchange materials have been studied extensively and are known to have high affinities for cesium ions in caustic tank waste supernates. RF is an elutable organic resin and CST is a non-elutable inorganic material. Waste treatment processes developed for the two technologies will differ with regard to solutions processed, secondary waste streams generated, optimum column size, and waste throughput. Pertinent references, anticipated processing sequences for utilization in waste treatment, gaps in the available data, and technical comparisons will be provided for the two ion exchange materials to assist in technology selection for SCIX. The engineered, granular form of CST (UOP IE-911) was the baseline ion exchange material used for the initial development and design of the SRS SCIX process (McCabe, 2005). To date, in-tank SCIX has not been implemented for treatment of radioactive waste solutions at SRS. Since initial development and consideration of SCIX for SRS waste treatment an alternative technology has been developed as part of the River Protection Project Waste Treatment Plant (RPP-WTP) Research and Technology program (Thorson, 2006). Spherical RF resin is the baseline media for cesium removal in the RPP-WTP, which was designed for the treatment of radioactive waste supernates and is currently under construction in Hanford, WA

  19. Evaluation of leachable behavior from ion exchange resins effects of organic impurities on BWR water chemistry. 1

    International Nuclear Information System (INIS)

    Igarashi, Hiroo; Nishimura, Yusaku; Ohsumi, Katsumi; Uchida, Shunsuke; Matsui, Tsuneo

    1999-01-01

    The elution rate of leachables from ion exchange resin, which is used in condensate demineralizers and is one of several major sources of organic compounds in BWR cooling water, was measured. Properties of the leachables and elution rate depended on the kind of ion exchange resin and the years of use. The organic compounds elution rate of cation exchange resin was constant for 5 years and the molecular weight of these leachables was low. After 5 years, the elution rate increased and leachables consisted of organic compounds of high molecular weights of several thousand. The elution rate of anion exchange resin decreased yearly. The difference in the elution behavior was attributed to a dependence on oxidation degradation promoted by transition metal catalysis. The cation exchange resin included absorbed transition metal, while the anion exchange resin did not. An empirical formula showing the time dependence of the elution rate of organic compounds was derived. The formula was judged to be appropriate based on simulations of an actual BWR plant and comparisons of impurity concentrations with actual reactor water data. (author)

  20. Proceeding of the Scientific Meeting and Presentation on Basic Research in Nuclear of the Scientific and Technology Part II : Nuclear Chemistry; Process Technology and Radioactive Waste Management; Environment

    International Nuclear Information System (INIS)

    Sudjatmoko; Karmanto, Eko Edy; Endang-Supartini

    1996-04-01

    Scientific Meeting and Presentation on Basic Research in Nuclear Science and Technology is a routine activity was held by Yogyakarta Nuclear Research Centre, National Atomic Energy Agency (BATAN) for monitoring the research activity which achieved in BATAN. The Proceeding contains a proposal about basic which has Nuclear Chemistry, Process Technology, Radioactive Waste Management and Environment. This proceeding is the second part from two part which published in series. There are 61 articles which have separated index

  1. Advances in processing technologies for titanium heat exchanger tubes of fossil and nuclear power plants

    Energy Technology Data Exchange (ETDEWEB)

    Likhareva, T.P.; Tchizhik, A.A.; Chavchanidze, N.N. [Polzanov Central Boiler and Turbine Institute, St. Petersburg (Russian Federation)

    1998-12-31

    The advances in processing technologies for titanium heat exchangers with rolled and welded tubes of fossil and nuclear power plants in Russia are presented. The special methodology of investigations with constant small strain rate have been used to study the effects of mixed corrosion and creep processes in condensers cooled by sea or synthetic sea waters. The results of corrosion creep tests and K1scc calculations are given. The Russian science activities concerning condensers manufactured from titanium show the possibilities for designing structures with very high level service reliability in different corrosion aggressive mediums with high total salt, Cl-ion and oxygen contents. (orig.)

  2. Advances in processing technologies for titanium heat exchanger tubes of fossil and nuclear power plants

    Energy Technology Data Exchange (ETDEWEB)

    Likhareva, T P; Tchizhik, A A; Chavchanidze, N N [Polzanov Central Boiler and Turbine Institute, St. Petersburg (Russian Federation)

    1999-12-31

    The advances in processing technologies for titanium heat exchangers with rolled and welded tubes of fossil and nuclear power plants in Russia are presented. The special methodology of investigations with constant small strain rate have been used to study the effects of mixed corrosion and creep processes in condensers cooled by sea or synthetic sea waters. The results of corrosion creep tests and K1scc calculations are given. The Russian science activities concerning condensers manufactured from titanium show the possibilities for designing structures with very high level service reliability in different corrosion aggressive mediums with high total salt, Cl-ion and oxygen contents. (orig.)

  3. Modern trends in contemporary chemistry

    International Nuclear Information System (INIS)

    Javed, H.; Pervez, H.; Qadeer, R.

    1993-01-01

    This publication contains a collection of papers presented at symposium on M odern Trends in Contemporary Chemistry , that was held in Islamabad, Pakistan, March 6-8, 1990. The symposium was divided into five sections for presentation of about 55 scientific and technical papers and 6 review papers. The contents of these papers were of good quality in the widespread concern in new trends of chemistry. The six reviews papers covered fields of ortho metallation reactions, evaluation of heterogeneous electron transfer rate contents, macro reticular ion-exchange resins, spectrochemical analytical techniques, liquid crystal-high technology materials for practical applications and trends in advanced ceramics. (A.B.)

  4. VII Russian annual conference of young scientists and postgraduate students Physical chemistry and technology of inorganic materials. Collection of materials

    International Nuclear Information System (INIS)

    Tsvetkov, Yu.V.

    2010-01-01

    The materials of the VII Russian annual conference of young scientists and postgraduate students Physical chemistry and technology of inorganic materials, held 8-11 November 2010 in Moscow, are presented. Structure and properties of high-strength nanostructured metal and composite materials, development of research methods and simulation of the structure and properties of materials and nanomaterials, functional ceramic and composite nanomaterials - in sight of the participants. The problems of physicochemical principles and processes for new technologies and forming powder materials and nanomaterials, physicochemical bases of production and processing of advanced inorganic materials, physical chemistry and technology of energy-, resource-saving and environmentally friendly processes for ferrous, non-ferrous and rare metals are under consideration. Promising composite coatings and nanostructured films of functional purposes, physicochemical bases of new processes of shaping and forming of materials and nanomaterials are discussed [ru

  5. A Novel RFID Sensing System Using Enhanced Surface Wave Technology for Battery Exchange Stations

    Directory of Open Access Journals (Sweden)

    Yeong-Lin Lai

    2014-01-01

    Full Text Available This paper presents a novel radio-frequency identification (RFID sensing system using enhanced surface wave technology for battery exchange stations (BESs of electric motorcycles. Ultrahigh-frequency (UHF RFID technology is utilized to automatically track and manage battery and user information without manual operation. The system includes readers, enhanced surface wave leaky cable antennas (ESWLCAs, coupling cable lines (CCLs, and small radiation patches (SRPs. The RFID sensing system overcomes the electromagnetic interference in the metallic environment of a BES cabinet. The developed RFID sensing system can effectively increase the efficiency of BES operation and promote the development of electric vehicles which solve the problem of air pollution as well as protect the environment of the Earth.

  6. Improvements on heavy water separation technology by isotopic water-hydrogen sulfide exchange

    International Nuclear Information System (INIS)

    Peculea, M.

    1987-01-01

    A series of possible variance is presented for the heavy water separation technology by isotopic H 2 O-H 2 S exchange at dual temperatures. The critical study of these variants, which are considered as characteristic quantities for the isotopes transport (production) and the extraction level is related to a dual temperature plant fed by liquid and cold column, which is the up-to-date technology employed in all heavy water production plants as variants of following plants are studied: dual temperature plant with double feeding; dual-temperature plant with equilibrium column (booster); dual-temperature-dual-pressure plant. Attention is paid to the variant with equilibration column (booster), executed and tested at the State Committee for Nuclear Energy and to the dual-temperature-dual pressure plant which presents the highest efficiency. (author)

  7. Data exchange technology based on handshake protocol for industrial automation system

    Science.gov (United States)

    Astafiev, A. V.; Shardin, T. O.

    2018-05-01

    In the article, questions of data exchange technology based on the handshake protocol for industrial automation system are considered. The methods of organizing the technology in client-server applications are analyzed. In the process of work, the main threats of client-server applications that arise during the information interaction of users are indicated. Also, a comparative analysis of analogue systems was carried out, as a result of which the most suitable option was chosen for further use. The basic schemes for the operation of the handshake protocol are shown, as well as the general scheme of the implemented application, which describes the entire process of interaction between the client and the server.

  8. Development of low temperature solid state joining technology of dissimilar for nuclear heat exchanger tube components

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2010-08-15

    By conventional fusion welding process (TIG), a realization of reliable and sound joints for the nuclear heat exchanger components is very difficult, especially for the parts comprising of the dissimilar metal couples (Ti-STS, Ti-Cu alloy etc.). This is mainly attributed to the formation of brittle intermetallics (Ti{sub x}Cu{sub y}, Ti{sub x}Fe{sub y}, Ti{sub x}Ni{sub y} etc.) and wide difference in physical properties. Moreover, it usually employs very high thermal input, so making it difficult to obtain sound joints due to generations of high residual stresses and degradation of the adjacent base metals, even for similar metal combinations. In this project, the low temperature solid-state joining technology was established by developing new alloy fillers, e.g. the multi-component eutectic based alloys or amorphous alloys, and thereby lowering the joining temperature down to {approx}800 .deg. C without affecting the structural properties of base metals. Based on a low temperature joining, the interlayer engineering technology was then developed to be able to eliminate the brittleness of the joints for strong Ti-STS dissimilar joints, and the diffusion brazing technology of Ti-Ti with a superior joining strength and corrosion-resistance comparable to those of base metal were developed. By using those developed technologies, the joining procedures feasible for the heat exchanger components were finally established for the dissimilar metal joints including Ti tube sheet to super STS tube, Ti tube sheet to super STS tube sheet, and the joints of the Ti tube to Ti tube sheet

  9. Application of Radiation Chemistry to Some Selected Technological Issues Related to the Development of Nuclear Energy.

    Science.gov (United States)

    Bobrowski, Krzysztof; Skotnicki, Konrad; Szreder, Tomasz

    2016-10-01

    The most important contributions of radiation chemistry to some selected technological issues related to water-cooled reactors, reprocessing of spent nuclear fuel and high-level radioactive wastes, and fuel evolution during final radioactive waste disposal are highlighted. Chemical reactions occurring at the operating temperatures and pressures of reactors and involving primary transients and stable products from water radiolysis are presented and discussed in terms of the kinetic parameters and radiation chemical yields. The knowledge of these parameters is essential since they serve as input data to the models of water radiolysis in the primary loop of light water reactors and super critical water reactors. Selected features of water radiolysis in heterogeneous systems, such as aqueous nanoparticle suspensions and slurries, ceramic oxides surfaces, nanoporous, and cement-based materials, are discussed. They are of particular concern in the primary cooling loops in nuclear reactors and long-term storage of nuclear waste in geological repositories. This also includes radiation-induced processes related to corrosion of cladding materials and copper-coated iron canisters, dissolution of spent nuclear fuel, and changes of bentonite clays properties. Radiation-induced processes affecting stability of solvents and solvent extraction ligands as well oxidation states of actinide metal ions during recycling of the spent nuclear fuel are also briefly summarized.

  10. Technology Candidates for Air-to-Air and Air-to-Ground Data Exchange

    Science.gov (United States)

    Haynes, Brian D.

    2015-01-01

    Technology Candidates for Air-to-Air and Air-to-Ground Data Exchange is a two-year research effort to visualize the U. S. aviation industry at a point 50 years in the future, and to define potential communication solutions to meet those future data exchange needs. The research team, led by XCELAR, was tasked with identifying future National Airspace System (NAS) scenarios, determining requirements and functions (including gaps), investigating technical and business issues for air, ground, & air-to-ground interactions, and reporting on the results. The project was conducted under technical direction from NASA and in collaboration with XCELAR's partner, National Institute of Aerospace, and NASA technical representatives. Parallel efforts were initiated to define the information exchange functional needs of the future NAS, and specific communication link technologies to potentially serve those needs. Those efforts converged with the mapping of each identified future NAS function to potential enabling communication solutions; those solutions were then compared with, and ranked relative to, each other on a technical basis in a structured analysis process. The technical solutions emerging from that process were then assessed from a business case perspective to determine their viability from a real-world adoption and deployment standpoint. The results of that analysis produced a proposed set of future solutions and most promising candidate technologies. Gap analyses were conducted at two points in the process, the first examining technical factors, and the second as part of the business case analysis. In each case, no gaps or unmet needs were identified in applying the solutions evaluated to the requirements identified. The future communication solutions identified in the research comprise both specific link technologies and two enabling technologies that apply to most or all specific links. As a result, the research resulted in a new analysis approach, viewing the

  11. Benefits from an exchange of knowledge in the treaty-related science and technologies: A personal perspective

    International Nuclear Information System (INIS)

    Marshall, P.D.

    1999-01-01

    This paper describes benefits from an exchange of knowledge in the non-proliferation treaty related science and technologies concerning science and technology development. Benefits to State Parties are concerned with non-treaty uses of seismic, hydro acoustic, infrasound and radionuclides data, their evaluation and measuring techniques

  12. Proceedings of the Scientific Meeting and Presentation on Basic Research in Nuclear of the Science and Technology part II : Nuclear Chemistry and Process Technology

    International Nuclear Information System (INIS)

    Kamsul Abraha; Yateman Arryanto; Sri Jauhari S; Agus Taftazani; Kris Tri Basuki; Djoko Sardjono, Ign.; Sukarsono, R.; Samin; Syarip; Suryadi, MS; Sardjono, Y.; Tri Mardji Atmono; Dwiretnani Sudjoko; Tjipto Sujitno, BA.

    2007-08-01

    The Scientific Meeting and Presentation on Basic Research in Nuclear Science and Technology is a routine activity held by Centre for Accelerator Technology and Material Process, National Nuclear Energy Agency, for monitoring the research activity which achieved in National Nuclear Energy Agency. The Meeting was held in Yogyakarta on July 10, 2007. The proceedings contains papers presented on the meeting about Nuclear Chemistry and Process Technology and there are 47 papers which have separated index. The proceedings is the second part of the three parts which published in series. (PPIN)

  13. NATO Advanced Study Institute on Fundamental and Technological Aspects of Organo-f-Element Chemistry

    CERN Document Server

    Fragalà, Ignazio

    1985-01-01

    The past decade has seen a dramatic acceleration of activity and interest in phenomena surrounding lanthanide and actinide organo­ metallic compounds. Around the world, active research in organo-f­ element synthesis, chemistry, catalysis, crystallography, and quantum chemistry is in progress. This activity has spanned a remarkably wide range of disciplines, from synthetic/mechanistic inorganic and organic chemistry to radiochemistry, catalytic chemistry, spectroscopy (vibra­ tional, optical, magnetic resonance, photoelectron, Mossbauer), X-ray and neutron diffraction structural analysis, as well as to crystal field and molecular orbital theoretical studies at the interface of chemistry and physics. These investigations have been motivated both by fundamental and applied goals. The evidence that f-element organo­ metallic compounds have unique chemical and physical properties which cannot be duplicated by organometallic compounds of d-block elements has suggested many new areas of endeavor and application....

  14. Joint thesaurus Part I (A-L) + II (M-Z)[International Nuclear Information System. Energy Technology Data Exchange

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-04-15

    This is the second revision of the ETDE/INIS Joint Thesaurus, including all updates up to September 2006. It contains 21 147 valid descriptors and 9 114 forbidden terms. The Joint Thesaurus contains the controlled terminology for indexing all information within the subject scopes of the International Nuclear Information System (INIS) and the Energy Technology Data Exchange (ETDE). The terminology is intended for use in subject descriptions for input or retrieval of information in these systems. The thesaurus is a terminological control device used in translating from the natural language of documents, indexers or users into a more constrained system language It is also a controlled and dynamic vocabulary of semantically and generically related terms which covers a specific domain of knowledge. The basic terminology in this thesaurus goes back to the 1969 edition of the EURATOM Thesaurus. The structure subsequently given to that terminology was the result of a systematic study performed by INIS subject specialists. Further expansion of the thesaurus terminology was done by ETDE to incorporate information on all forms of energy. The ETDE/INIS Joint Thesaurus is the result of continued editing, carried out in parallel to the processing of the INIS and ETDE databases. The domain of knowledge covered by the Joint Thesaurus includes physics (in particular, plasma physics, atomic and molecular physics, and especially nuclear and high-energy physics), chemistry, materials science, earth sciences, radiation biology, radioisotope effects and kinetics, applied life sciences, radiology and nuclear medicine, isotope and radiation source technology, radiation protection, radiation applications, engineering, instrumentation, fossil fuels, synthetic fuels, renewable energy sources, advanced energy systems, fission and fusion reactor technology, safeguards and inspection, waste management, environmental aspects of the production and consumption of energy from nuclear and non

  15. Technology, Incentives, or Both? Factors Related to Level of Hospital Health Information Exchange.

    Science.gov (United States)

    Lin, Sunny C; Everson, Jordan; Adler-Milstein, Julia

    2018-02-28

    To assess whether the level of health information exchange (HIE) in U.S. hospitals is related to technology capabilities, incentives to exchange, or both. A total of 1,812 hospitals attesting to stage 2 of Medicare's Meaningful Use Incentive Program through April 2016. Hospital-level, multivariate OLS regression with state fixed effects was used to analyze the relationship between technology capability and incentives measures, and percent of care transitions with summary of care records (SCRs) sent electronically to subsequent providers. Stage 2 hospitals reported sending SCRs electronically for an average of 41 percent (median = 33 percent) of transitions. HIE level is related to four capability measures, one incentive measure, and one measure that is related to both capability and incentive. Percent of transitions with SCRs sent electronically was 3 percentage points higher (95 percent CI: 0.1-5.1) for hospitals with a third-party HIE vendor, 3 percentage points higher (95 percent CI: 0.5-5.4) for hospitals with an EHR vendor as their HIE vendor, and 3 percentage points higher (95 percent CI: 0.4-5.4) for hospitals that automatically alert primary care providers. The direction and statistical significance of the relationships between specific EHR vendor and electronic SCR transmission level varied by vendor. Nonprofits and government hospitals performed 5 percentage points higher (95 percent CI: 1.5-9.1) and 8 percentage points higher (95 percent CI: 3.4-12.3) than for-profits. Hospitals in systems performed 3 percentage points higher (95 percent CI: 0.8-6.1). The overall level of HIE is low, with hospitals sending an SCR electronically for less than half of patient transitions. Specific hospital characteristics related to both technology capabilities and incentives were associated with higher levels of HIE. © Health Research and Educational Trust.

  16. Chemistry of sustainability-Part I: Carbon dioxide as an organic synthon and Part II: Study of thermodynamics of cation exchange reactions in semiconductor nanocrystals

    Science.gov (United States)

    Sathe, Ajay A.

    Sustainability is an important part of the design and development of new chemical and energy conversion processes. Simply put sustainability is the ability to meet our needs without sacrificing the ability of the next generations to meet theirs. This thesis describes our efforts in developing two orthogonal strategies for the fixation of CO2 by utilizing high energy intermediates which are generated via oxidative or reductive processes on common organic substrates and of thermochemical measurements of cation exchange reactions which will aid the development of new materials relevant for energy conversion and storage. The first chapter lays a background for the challenges and opportunities for the use of CO2 in organic synthesis. The rapidly growing field of continuous flow processing in organic synthesis is introduced, and its importance in the development of sustainable chemical conversions is highlighted. The second chapter describes the development of a novel route to alpha-amino acids via reductive carboxylation of imines. A mechanistic proposal is presented and the reaction is shown to proceed through the intermediacy of alpha-amino alkyl metal species. Possible strategies for designing catalytic and enantioselective variants of the reaction are presented. The third chapter describes the development of a catalytic oxidative carboxylation of olefins to yield cyclic carbonates. The importance of flow chemistry and membrane separation is demonstrated by allowing the combination of mutually incompatible reagents in a single reaction sequence. While the use of carbon dioxide for synthesis of organic fine chemicals is not expected to help reduce the atmospheric carbon dioxide levels, or tackle climate change, it certainly has the potential to reduce our dependence on non-sustainable carbon feedstocks, and help achieve a carbon neutral chemical life cycle. Having described the use of carbon dioxide and flow chemistry for sustainable chemical conversion, the fourth

  17. Chemistry of water and steam in power plants and related technologies. Glossary of terms and definitions English - German; German - English

    Energy Technology Data Exchange (ETDEWEB)

    Schmitz, H.P.; Teutenberg, U.

    2006-07-01

    This new edition of a technical dictionary is an evaluation of the technical terms found in the domestic and foreign literature and in information brochures of specialist firms, directives, guidelines, standards, etc. This dictionary contains more than 3,000 terms mainly with definitions with respect to the chemistry of water and steam in power plants along with the related types of water (untreated water, feedwater and boiler water, make-up water, waste water) and the water treatment processes (ion exchange, membrane process, etc.), water conditioning and chemical analysis, internal cleaning of steam generating plants (e.g. flushing, boiling-out, pre-operational and operational acid cleaning, steam blowing) as well as fundamentals of water chemistry. The technical knowledge of the authors, Heinz-Peter Schmitz, FDBR, with more than 25 years professional experience as translator/official in charge of documentation and Ulrich Teutenberg, Babcock/Hitachi with more than 30 years professional experience as senior consultant for water chemistry and commissioning is reflected in this dictionary. Part 1 contains the English-German version, Part 2 the German-English version. (orig.)

  18. Eddy current technology for heat exchanger and steam generator tube inspection

    Energy Technology Data Exchange (ETDEWEB)

    Obrutsky, L.; Lepine, B.; Lu, J.; Cassidy, R.; Carter, J. [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

    2004-07-01

    A variety of degradation modes can affect the integrity of both heat exchanger (HX) and balance of plant tubing, resulting in expensive repairs, tube plugging or replacement of tube bundles. One key component for ensuring tube integrity is inspection and monitoring for detection and characterization of the degradation. In-service inspection of HX and balance of plant tubing is usually carried out using eddy current (EC) bobbin coils, which are adequate for the detection of volumetric degradations. However, detection and quantification of additional modes of degradation such as pitting, intergranular attack (IGA), axial cracking and circumferential cracking require specialized probes. The need for timely, reliable detection and characterization of these modes of degradation is especially critical in Nuclear Generating Stations. Transmit-receive single-pass array probes, developed by AECL, offer high defect detectability in conjunction with fast and reliable inspection capabilities. They have strong directional properties, permitting probe optimization for circumferential or axial crack detection. Compared to impedance probes, they offer improved performance in the presence of variable lift-off. This EC technology can help resolve critical detection issues at susceptible areas, such as the rolled-joint transitions at the tubesheet, U-bends and tube-support intersections. This paper provides an overview of the operating principles and the capabilities of advanced ET inspection technology available for HX tube inspection. Examples of recent application of this technology in Nuclear Generating Stations (NGSs) are discussed. (author)

  19. Eddy current technology for heat exchanger and steam generator tube inspection

    International Nuclear Information System (INIS)

    Obrutsky, L.; Lepine, B.; Lu, J.; Cassidy, R.; Carter, J.

    2004-01-01

    A variety of degradation modes can affect the integrity of both heat exchanger (HX) and balance of plant tubing, resulting in expensive repairs, tube plugging or replacement of tube bundles. One key component for ensuring tube integrity is inspection and monitoring for detection and characterization of the degradation. In-service inspection of HX and balance of plant tubing is usually carried out using eddy current (EC) bobbin coils, which are adequate for the detection of volumetric degradations. However, detection and quantification of additional modes of degradation such as pitting, intergranular attack (IGA), axial cracking and circumferential cracking require specialized probes. The need for timely, reliable detection and characterization of these modes of degradation is especially critical in Nuclear Generating Stations. Transmit-receive single-pass array probes, developed by AECL, offer high defect detectability in conjunction with fast and reliable inspection capabilities. They have strong directional properties, permitting probe optimization for circumferential or axial crack detection. Compared to impedance probes, they offer improved performance in the presence of variable lift-off. This EC technology can help resolve critical detection issues at susceptible areas, such as the rolled-joint transitions at the tubesheet, U-bends and tube-support intersections. This paper provides an overview of the operating principles and the capabilities of advanced ET inspection technology available for HX tube inspection. Examples of recent application of this technology in Nuclear Generating Stations (NGSs) are discussed. (author)

  20. The strategic use of standardized information exchange technology in a university health system.

    Science.gov (United States)

    Cheng, Po-Hsun; Chen, Heng-Shuen; Lai, Feipei; Lai, Jin-Shin

    2010-04-01

    This article illustrates a Web-based health information system that is comprised of specific information exchange standards related to health information for healthcare services in National Taiwan University Health System. Through multidisciplinary teamwork, medical and informatics experts collaborated and studied on system scope definition, standard selection challenges, system implementation barriers, system management outcomes, and further expandability of other systems. After user requirement analysis and prototyping, from 2005 to 2008, an online clinical decision support system with multiple functions of reminding and information push was implemented. It was to replace its original legacy systems and serve among the main hospital and three branches of 180-200 clinics and 7,500-8,000 patient visits per day. To evaluate the effectiveness of this system, user surveys were performed, which revealed that the average score of user satisfaction increased from 2.80 to 3.18 on a 4-point scale. Among the items, especially e-learning for training service, courtesy communications for system requests, and courtesy communications for system operations showed statistically significant improvement. From this study, the authors concluded that standardized information exchange technologies can be used to create a brand new enterprise value and steadily obtain more competitive advantages for a prestige healthcare system.

  1. Design and technology parameters influence on durability for heat exchangers tube to tubesheet joints

    Science.gov (United States)

    Ripeanu, R. G.

    2017-02-01

    The main failures of heat exchangers are: corrosion of tubes and jacket, tubes blockage and failures of tube to tubesheet joints also by corrosion. The most critical zone is tube to tubesheet joints. Depending on types of tube to tubesheet joints, in order to better respect conditions of tension and compression, this paper analyses the tubesheet holes shapes, smooth and with a grove, on corrosion behavior. In the case of welding tubes with tubesheet, welding parameters modify corrosion behavior. Were realized welded joints by three welding regimes and tested at corrosion in two media, tap water and industrial water. Were tested also samples made of smooth tubes, finned tubes and tubes coated with a passive product as applied by a heat exchanger manufacturer. For all samples, the roughness parameters were measured, before and after the corrosion tests. The obtained corrosion rates show that stress values and their distribution along the joint modify the corrosion behavior. The optimum welding parameters were established in order to increase the joint durability. The paper has shown that passive product used is not proper chosen and the technology of obtaining rolled thread pipes diminishes tubes’ durability by increasing the corrosion rate.

  2. HEALTH RECORDS AND INFORMATION TECHNOLOGY IN SUPPORT OF EXCHANGE OF HEALTH INFORMATION

    Directory of Open Access Journals (Sweden)

    Jordan Deliversky

    2017-05-01

    Full Text Available The exchange of health information in conditions directly related to electronic environment is referred as health information technology. Usually the protection of personal health related data is comprised of various elements such as ways of information usage and access to sensitive health information. The protection of individually identifiable health information is possible with combination of measures. Protective measures include administrative, technical and physical elements. Through such protective measures is possible to ensure confidentiality, integrity and availability of the information, while at the same time could be guaranteed the prevention of unauthorized access. Sensitive records usually contain personal health information. Personal medical data requires high level of protection, as its content includes medical condition or diagnosis, where unauthorized access could have negative impact on one’s personal and professional life.

  3. FY 2000 report on the promotion projects by Research Institute of Innovative Technology for the Earth. Study on possibility of research exchanges; 2000 nendo chikyu kankyo sangyo gijutsu kaihatsu suishin jigyo seika hokokusho. Kenkyu koryu kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the results of the study on possibility of research exchanges, conducted by Research Institute of Innovative Technology for the Earth (RITE) in FY 2000. For development of thin-film catalysts, HTE, a venture developing combinatorial chemistry application to catalysts, is a potential partner for the exchanges. One of the technical problems involved in underground sequestration of CO2 relates to evaluation of the reactions between CO2 injected under pressure and the surrounding rocks. It is a less site-specific theme, and preferably pursued through international networks. The RITE delegates have visited the British Geological Survey, Canada's Alberta Research Council, and US's Pennsylvania State University, Rice University and Chevron Petroleum, finding research exchange possibilities in all of these organizations for broad technical themes related to underground sequestration of CO2. For energy conversion technologies using biomass resources as the source materials, the potential partners for the research exchanges include Swedish Royal Institute of Technology, Belgium's Catholic University of Louvain and Spain's University of Zaragona which leads researches in production of gases from wastes and biomass. (NEDO)

  4. Values exchange: using online technology to raise awareness of values and ethics in radiography education.

    Science.gov (United States)

    Mc Inerney, John; Lees, Amanda

    2018-03-01

    Ethics and values are increasingly significant aspects of patient-centred healthcare. While it is widely agreed that ethics and values are essential for healthcare delivery, there is also an acknowledgement that these are areas that are challenging to teach. The purpose of this study is to report a small-scale evaluative research project of a web-based technology with the educational potential to facilitate learning in relation to ethics, values, self-reflection and peer-based learning. Five diagnostic radiography students took part in a semi-structured focus group with the aim of exploring their experiences of using Values Exchange, an online ethical decision-making framework, to examine practice-based ethical issues. Transcripts were interrogated for key themes. From the thematic analysis three major themes emerged, understanding and appreciating others, addressing the theory-practice gap and delivering a safe and effective learning environment. Perceived limitations of the platform included students' fear of misinterpreted responses and possibility of poor group dynamics. There are varied approaches to how ethics and values are taught and assessed within health-related environments. Values Exchange is one such teaching tool and has been investigated and described positively by radiography students in this study. Online teaching tools can have a positive effect in helping students identify their own values but require skilled implementation to reap positive rewards. © 2018 The Authors. Journal of Medical Radiation Sciences published by John Wiley & Sons Australia, Ltd on behalf of Australian Society of Medical Imaging and Radiation Therapy and New Zealand Institute of Medical Radiation Technology.

  5. Modern Information Technologies in Chemical Education: Research, Analyses and Prospects for Chemistry Teachers Training [In Bulgarian

    Directory of Open Access Journals (Sweden)

    M. Kirova

    2012-12-01

    Full Text Available The present review paper describes the present state-of-art of two areas of the contemporary science education – the use of interactive media in teaching and learning chemistry in secondary schools and the competences of chemistry teachers for application of electronic education in these schools. A review of the current literature in those topics is presented in some details. The own contributions of the author in these areas are emphasized.

  6. Effect of Air Cleaning Technologies in Conjunction With the Use of Rotary Heat Exchangers in Residential Buildings

    DEFF Research Database (Denmark)

    Afshari, Alireza; Bergsøe, Niels Christian; Ekberg, Lars

    2013-01-01

    This study is part of a research project concerning the possibilities of applying efficient air cleaning technologies using rotary heat exchanger in residential buildings. The purpose of this project was to identify and adapt new air-cleaning technologies for implementation in HVAC systems...... with rotary air-to-air heat exchangers. For this purpose, a mechanical filter with low pressure drop and a 4 cm thick activated carbon filter were selected for testing in a laboratory environment. The measurements included testing of the filters, separately and combined, in a ductwork to study the efficiency...

  7. Advancement in reactor coolant chemistry management programs and related technology development in Taiwan

    International Nuclear Information System (INIS)

    Huang, C.S.; Lin, Chien C.

    2000-01-01

    Taiwan Power Company (TPC) has three nuclear power plants in operation with a total capacity of 51 GWe, contributing about 30% of electricity generation in Taiwan. The first two plants, Chinshan (CSNPP) and Kuosheng (KSNPP), are boiling water reactor plants, and the third one, Maanshan (MASNPP), is a pressurized water reactor plant. Each plant has two identical reactors. As many nuclear power plant operators worldwide, TPC is committed to operate the plants efficiently, economically, and safely. TPC has developed and implemented several chemistry improvement programs in recent years to improve the coolant chemistry in order to ( l ) protect structure materials from corrosion, (2) reduce radiation exposures to workers and (3) reduce radwaste production and radiation release to the environment. This paper describes TPC's experience in some water chemistry management, radwaste reduction and radiation exposure control programs. Future programs under planning, including implementation of hydrogen water chemistry (HWC) in BWRs, installation of condensate pre-filters, and development of on-line water chemistry monitoring system, are also be briefly discussed. In addition, some material related research and development programs will also be presented. (author)

  8. Factors related to the economic sustainability of two-year chemistry-based technology training programs

    Science.gov (United States)

    Backus, Bridgid A.

    Two-year chemistry-based technology training (CBTT) programs in the U.S. are important in the preparation of the professional technical workforce. The purpose of this study was to identify, examine, and analyze factors related to the economic sustainability of CBTT programs. A review of literature identified four clustered categories of 31 sub-factors related to program sustainability. Three research questions relating to program sustainability were: (1) What is the relative importance of the identified factors?, (2) What differences exist between the opinions of administrators and faculty?, and (3) What are the interrelationships among the factors? In order to answer these questions, survey data gathered from CBTT programs throughout the United States were analyzed statistically. Conclusions included the following: (1) Rank order of the importance to sustainability of the clustered categories was: (1) Partnerships, (2) Employer and Student Educational Goals, (3) Faculty and Their Resources, and (4) Community Perceptions and Marketing Strategies. (2) Significant correlations between ratings of sustainability and the sub-factors included: degree of partnering, college responsiveness, administration involvement in partnerships, experiential learning opportunities, employer input in curriculum development, use of skill standards, number of program graduates, student job placement, professional development opportunities, administrator support, presence of a champion, flexible scheduling, program visibility, perception of chemical technicians, marketing plans, and promotion to secondary students. (3) Faculty and administrators differed significantly on only two sub-factor ratings: employer assisted curriculum development, and faculty workloads. (4) Significant differences in ratings by small program faculty and administrators and large program faculty and administrators were indicated, with most between small program faculty and large program administrators. The study

  9. The Analysis and Structuring of the Causes Impeding the Introduction of Advanced Technologies for Exchange Grain Trading

    Directory of Open Access Journals (Sweden)

    Vinnychenko Olena V

    2015-03-01

    Full Text Available In the article the main causes impeding the development and introduction of advanced technologies for grain trading on commodity exchanges in Ukraine have been identified and structured. The generalization of existing shortcomings in operation of the domestic commodity exchanges has served the basis for the model, within which there were built: a directed graph of correlations between the above mentioned shortcomings in the operation of exchanges, the matrix of dependency and reachability. The causes have been identified and structured, the main ones being determined, which, in turn, makes it possible to carry out the correct sequence of actions and emphasize the primary issues requiring priority solutions at making management decisions in order to promote the grain exchange market. The suggested approach clearly shows the correlation between the existing causes and sequence of their elimination.

  10. Using digital technologies to enhance chemistry students' understanding and representational skills

    DEFF Research Database (Denmark)

    Hilton, Annette

    Abstract Chemistry students need to understand chemistry on molecular, symbolic and macroscopic levels. Students find it difficult to use representations on these three levels to interpret and explain data. One approach is to encourage students to use writing-to-learn strategies in inquiry settings...... to present and interpret their laboratory results. This paper describes findings from a study on the effects on students’ learning outcomes of creating multimodal texts to report on laboratory inquiries. The study involved two senior secondary school chemistry classes (n = 22, n = 27). Both classes completed...... representations to make explanations on the molecular level. Student interviews and classroom video-recordings suggested that using digital resources to create multimodal texts promoted knowledge transformation and hence deeper reflection on the meaning of data and representations. The study has implications...

  11. Chemistry for engineering students: A key factor for social and technological development

    Directory of Open Access Journals (Sweden)

    Juan Antonio Llorens Molina

    2014-12-01

    Full Text Available The peculiarity of Chemistry as a basic subject in Engineering Studies and its embedded potential difficulties are matters which are now common to universities worldwide. In particular, the learning of Chemistry in the new (post Bologna degrees of Engineering in Spain and other countries is facing several challenges. In other words, there is a need to deepen into research and innovation tasks aiming at improving such studies within this new educational paradigm. Not to mention, two crucial aspects which are very often neglected, namely, reaching maximum efficiency of all types of available resources and obtaining a “knock on effect” from students and teachers at Secondary school level. The latter playing a crucial role so as to increase students’ awareness of the importance that Chemistry has at this particular educational level. Not to mention, how this increases their motivation towards this subject in the Higher Education scenario.

  12. Newly available technologies present expanding opportunities for scientific and technical information exchange

    Science.gov (United States)

    Tolzman, Jean M.

    1993-01-01

    The potential for expanded communication among researchers, scholars, and students is supported by growth in the capabilities for electronic communication as well as expanding access to various forms of electronic interchange and computing capabilities. Increased possibilities for information exchange, collegial dialogue, collaboration, and access to remote resources exist as high-speed networks, increasingly powerful workstations, and large, multi-user computational facilities are more frequently linked and more commonly available. Numerous writers speak of the telecommunications revolution and its impact on the development and dissemination of knowledge and learning. One author offers the phrase 'Scholarly skywriting' to represent a new form of scientific communication that he envisions using electronic networks. In the United States (U.S.), researchers associated with the National Science Foundation (NSF) are exploring 'nationwide collaboratories' and 'digital collaboration.' Research supported by the U.S. National Aeronautics and Space Administration (NASA) points to a future where workstations with built-in audio, video monitors, and screen sharing protocols are used to support collaborations with colleagues located throughout the world. Instruments and sensors located worldwide will produce data streams that will be brought together, analyzed, and distributed as new findings. Researchers will have access to machines that can supply domain-specific information in addition to locator and directory assistance. New forms of electronic journals will emerge and provide opportunities for researchers and scientists to exchange information electronically and interactively in a range of structures and formats. Ultimately, the wide-scale use of these technologies in the dissemination of research results and the stimulation of collegial dialogue will change the way we represent and express our knowledge of the world. A new paradigm will evolve--perhaps a truly worldwide

  13. Health information exchange technology on the front lines of healthcare: workflow factors and patterns of use

    Science.gov (United States)

    Johnson, Kevin B; Lorenzi, Nancy M

    2011-01-01

    Objective The goal of this study was to develop an in-depth understanding of how a health information exchange (HIE) fits into clinical workflow at multiple clinical sites. Materials and Methods The ethnographic qualitative study was conducted over a 9-month period in six emergency departments (ED) and eight ambulatory clinics in Memphis, Tennessee, USA. Data were collected using direct observation, informal interviews during observation, and formal semi-structured interviews. The authors observed for over 180 h, during which providers used the exchange 130 times. Results HIE-related workflow was modeled for each ED site and ambulatory clinic group and substantial site-to-site workflow differences were identified. Common patterns in HIE-related workflow were also identified across all sites, leading to the development of two role-based workflow models: nurse based and physician based. The workflow elements framework was applied to the two role-based patterns. An in-depth description was developed of how providers integrated HIE into existing clinical workflow, including prompts for HIE use. Discussion Workflow differed substantially among sites, but two general role-based HIE usage models were identified. Although providers used HIE to improve continuity of patient care, patient–provider trust played a significant role. Types of information retrieved related to roles, with nurses seeking to retrieve recent hospitalization data and more open-ended usage by nurse practitioners and physicians. User and role-specific customization to accommodate differences in workflow and information needs may increase the adoption and use of HIE. Conclusion Understanding end users' perspectives towards HIE technology is crucial to the long-term success of HIE. By applying qualitative methods, an in-depth understanding of HIE usage was developed. PMID:22003156

  14. Role of protein-glutathione contacts in defining glutaredoxin-3 [2Fe-2S] cluster chirality, ligand exchange and transfer chemistry.

    Science.gov (United States)

    Sen, Sambuddha; Cowan, J A

    2017-10-01

    Monothiol glutaredoxins (Grx) serve as intermediate cluster carriers in iron-sulfur cluster trafficking. The [2Fe-2S]-bound holo forms of Grx proteins display cysteinyl coordination from exogenous glutathione (GSH), in addition to contact from protein-derived Cys. Herein, we report mechanistic studies that investigate the role of exogenous glutathione in defining cluster chirality, ligand exchange, and the cluster transfer chemistry of Saccharomyces cerevisiae Grx3. Systematic perturbations were introduced to the glutathione-binding site by substitution of conserved charged amino acids that form crucial electrostatic contacts with the glutathione molecule. Native Grx3 could also be reconstituted in the absence of glutathione, with either DTT, BME or free L-cysteine as the source of the exogenous Fe-S ligand contact, while retaining full functional reactivity. The delivery of the [2Fe-2S] cluster to Grx3 from cluster donor proteins such as Isa, Nfu, and a [2Fe-2S](GS) 4 complex, revealed that electrostatic contacts are of key importance for positioning the exogenous glutathione that in turn influences the chiral environment of the cluster. All Grx3 derivatives were reconstituted by standard chemical reconstitution protocols and found to transfer cluster to apo ferredoxin 1 (Fdx1) at rates comparable to native protein, even when using DTT, BME or free L-cysteine as a thiol source in place of GSH during reconstitution. Kinetic analysis of cluster transfer from holo derivatives to apo Fdx1 has led to a mechanistic model for cluster transfer chemistry of native holo Grx3, and identification of the likely rate-limiting step for the reaction.

  15. Analytical chemistry

    International Nuclear Information System (INIS)

    Anon.

    1985-01-01

    The division for Analytical Chemistry continued to try and develope an accurate method for the separation of trace amounts from mixtures which, contain various other elements. Ion exchange chromatography is of special importance in this regard. New separation techniques were tried on certain trace amounts in South African standard rock materials and special ceramics. Methods were also tested for the separation of carrier-free radioisotopes from irradiated cyclotron discs

  16. Exploring 3-D Virtual Reality Technology for Spatial Ability and Chemistry Achievement

    Science.gov (United States)

    Merchant, Z.; Goetz, E. T.; Keeney-Kennicutt, W.; Cifuentes, L.; Kwok, O.; Davis, T. J.

    2013-01-01

    We investigated the potential of Second Life® (SL), a three-dimensional (3-D) virtual world, to enhance undergraduate students' learning of a vital chemistry concept. A quasi-experimental pre-posttest control group design was used to conduct the study. A total of 387 participants completed three assignment activities either in SL or using…

  17. Efficient process intensification of fine chemical production: a new classification tool for flow chemistry technologies

    NARCIS (Netherlands)

    Lexmond, A.S.; Roelands, C.P.M.; Graaff, M.P. de; Bassett, J.M.

    2010-01-01

    The fine chemicals and pharmaceuticals industry needs to innovate to beat international competition and resolve environmental issues. Process intensification by flow chemistry is the most promising route for this change, as it can reduce raw material and energy consumption, waste production, lead

  18. Nuclear chemistry and geochemistry research. Carnegie Institute of Technology and Carnegie--Mellon University. Summary report

    International Nuclear Information System (INIS)

    Kohman, T.P.

    1976-01-01

    A summary is presented of the activities and results of research in nuclear chemistry, nuclear geochemistry, nuclear cosmochemistry, and other minor areas from 1950 to 1976. A complete listing is given of publications, doctoral dissertations, and reports resulting from the research. A chronological list provides an overview of the activities at any particular time

  19. Twenty-ninth ORNL/DOE conference on analytical chemistry in energy technology. Abstracts of papers

    International Nuclear Information System (INIS)

    1986-01-01

    This booklet contains separate abstracts of 55 individual papers presented at this conference. Different sections in the book are titled as follows: laser techniques; resonance ionization spectroscopy; laser applications; new developments in mass spectrometry; analytical chemistry of hazardous waste; and automation and data management

  20. Nuclear chemistry and geochemistry research. Carnegie Institute of Technology and Carnegie--Mellon University. Summary report

    Energy Technology Data Exchange (ETDEWEB)

    Kohman, T.P.

    1976-05-28

    A summary is presented of the activities and results of research in nuclear chemistry, nuclear geochemistry, nuclear cosmochemistry, and other minor areas from 1950 to 1976. A complete listing is given of publications, doctoral dissertations, and reports resulting from the research. A chronological list provides an overview of the activities at any particular time. (JSR)

  1. Contributions for the chemistry, physics and technology of the elementary carbon in various states for the Carbon '76

    International Nuclear Information System (INIS)

    Delle, W.W.

    1976-07-01

    This report is the compilation of a number of papers prepared by KFA Juelich for the 2nd International Carbon Conference CARBON '76 at Baden-Baden, June 28th - July 2nd, 1976. The presentations deal with objectives of chemistry, physics and technology of the elementary carbon in various states including irradiation induced effects on graphite and pyrolytic carbon. The work was partly sponsored by the Bundesministerium fuer Forschung und Technologie of the Federal Republic of Germany as well as by the Government of North-Rhine-Westfalia. (orig.) [de

  2. Coordination Chemistry inside Polymeric Nanoreactors: Metal Migration and Cross-Exchange in Amphiphilic Core-Shell Polymer Latexes

    Directory of Open Access Journals (Sweden)

    Si Chen

    2016-01-01

    Full Text Available A well-defined amphiphilic core-shell polymer functionalized with bis(p-methoxy-phenylphosphinophenylphosphine (BMOPPP in the nanogel (NG core has been obtained by a convergent RAFT polymerization in emulsion. This BMOPPP@NG and the previously-reported TPP@NG (TPP = triphenylphosphine and core cross-linked micelles (L@CCM; L = TPP, BMOPPP having a slightly different architecture were loaded with [Rh(acac(CO2] or [RhCl(COD]2 to yield [Rh(acac(CO(L@Pol] or [RhCl(COD(L@Pol] (Pol = CCM, NG. The interparticle metal migration from [Rh(acac(CO(TPP@NG] to TPP@NG is fast at natural pH and much slower at high pH, the rate not depending significantly on the polymer architecture (CCM vs. NG. The cross-exchange using [Rh(acac(CO(BMOPPP@Pol] and [RhCl(COD(TPP@Pol] (Pol = CCM or NG as reagents at natural pH is also rapid (ca. 1 h, although slower than the equivalent homogeneous reaction on the molecular species (<5 min. On the other hand, the subsequent rearrangement of [Rh(acac(CO(TPP@Pol] and [RhCl(COD(TPP@Pol] within the TPP@Pol core and of [Rh(acac(CO(BMOPPP@Pol] and [RhCl(COD(BMOPPP@Pol] within the BMOPPP@Pol core, leading respectively to [RhCl(CO(TPP@Pol2] and [RhCl(CO(BMOPPP@Pol2], is much more rapid (<30 min than on the corresponding homogeneous process with the molecular species (>24 h.

  3. Chemistry and Nanoscience Research | NREL

    Science.gov (United States)

    Chemistry and Nanoscience Center at NREL investigates materials and processes for converting renewable and new technologies. NREL's primary research in the chemistry and nanoscience center includes the Electrochemical Engineering and Materials Chemistry Providing a knowledge base in materials science covering

  4. Production technology readiness assessment of surfactant in the research center for Chemistry-Indonesian Institute of Sciences

    Science.gov (United States)

    Setiawan, Arief Ameir Rahman; Sulaswatty, Anny

    2017-11-01

    The common problem faced by the institution working on research, innovation and technology development is lack of quantitative measures to determine the technology readiness of research. No common communication language between R & D Institutions and industry about the level of preparedness of a research resulting a barrier to technology diffusion interaction. This lack of connection between R & D institutes with industry may lead to "sluggishness" occurs in innovating. For such circumstance, assessing technology readiness of research is very important. One of wide spread methods for the assessment is Technology Readiness Level (TRL, also known as Technometer), which is introduced by NASA (National Aeronautics and Space Administration). TRL is a general guide that provides an overview of maturity level of a technology. This study aims to identify and demonstrate the implementation of TRL to assess a number of surfactant researches in the Research Center for Chemistry, Indonesian Institute of Sciences. According to the assessment, it has been obtained the surfactant recommended for further development towards commercialization of R & D results, i.e. Glycerol Mono Stearate (GMS), which has reached the level of TRL 7.

  5. Education of radiochemistry and radiation chemistry at a college of medical technology

    International Nuclear Information System (INIS)

    Asano, Takeyoshi

    2005-01-01

    The present report aims at introducing my creative textbook on the subject. The contents start from the history of the 20th century on discovery and use of radiation and radioisotope''. In the study of the history the students can aware of their position in a future profession as a medical radiation worker. In addition, own originality for the textbook was shown in the descriptions of (1) Auger effect of EC decay nuclide used remarkably in nuclear medicine, (2) the relation between isotope, isotone and isobar and the kind of nuclear reaction, (3) the distinction of the use of isotope dilution method in substoichiometry and radioimmunoassay, (4) nuclear reactor chemistry (nuclear fuel cycle and disposal of high level radioactive waste), (5) fundamental constants used in radioisotope techniques and (6) the exposure dose in taking a side view of the radiation chemistry. A questionnaire survey after the closing the lesson showed that the students took an interest in 60% of the contents in the textbook of radiochemistry and radiation chemistry. (author)

  6. The Case of Middle and High School Chemistry Teachers Implementing Technology: Using the Concerns-Based Adoption Model to Assess Change Processes

    Science.gov (United States)

    Gabby, Shwartz; Avargil, Shirly; Herscovitz, Orit; Dori, Yehudit Judy

    2017-01-01

    An ongoing process of reforming chemical education in middle and high schools in our country introduced the technology-enhanced learning environment (TELE) to chemistry classes. Teachers are encouraged to integrate technology into pedagogical practices in meaningful ways to promote 21st century skills; however, this effort is often hindered by…

  7. The role of IAEA in coordinating research and transferring technology in radiation chemistry and processing of polymers

    Energy Technology Data Exchange (ETDEWEB)

    Haji-Saeid, M. [International Atomic Energy Agency (IAEA), Wagramer Strasse 5, A-1400 Vienna (Austria)], E-mail: M.Haji-Saeid@iaea.org; Sampa, M.H.; Ramamoorthy, N. [International Atomic Energy Agency (IAEA), Wagramer Strasse 5, A-1400 Vienna (Austria); Gueven, O. [Hacettepe University, Department of Chemistry, Ankara (Turkey); Chmielewski, A.G. [Faculty of Chemical and Process Engineering, Warsaw University of Technology, Warsaw (Poland)

    2007-12-15

    The IAEA has been playing a significant role in fostering developments in radiation technology in general and radiation processing of polymers in particular, among its Member States (MS) and facilitate know-how/technology transfer to developing MS. The former is usually achieved through coordinated research projects (CRP) and thematic technical meetings, while the latter is mainly accomplished through technical cooperation (TC) projects. Coordinated research projects encourage research on, and development and practical application of, radiation technology to foster exchange of scientific and technical information. The technical cooperation (TC) programme helps Member States to realize their development priorities through the application of appropriate radiation technology. The IAEA has implemented several coordinated research projects (CRP) recently, including one on-going project, in the field of radiation processing of polymeric materials. The CRPs facilitated the acquisition and dissemination of know-how and technology for controlling of degradation effects in radiation processing of polymers, radiation synthesis of stimuli-responsive membranes, hydrogels and absorbents for separation purposes and the use of radiation processing to prepare biomaterials for applications in medicine. The IAEA extends cooperation to well-known international conferences dealing with radiation technology to facilitate participation of talented scientists from developing MS and building collaborations. The IAEA published technical documents, covering the findings of thematic technical meetings (TM) and coordinated research projects have been an important source of valuable practical information.

  8. The role of IAEA in coordinating research and transferring technology in radiation chemistry and processing of polymers

    International Nuclear Information System (INIS)

    Haji-Saeid, M.; Sampa, M.H.; Ramamoorthy, N.; Gueven, O.; Chmielewski, A.G.

    2007-01-01

    The IAEA has been playing a significant role in fostering developments in radiation technology in general and radiation processing of polymers in particular, among its Member States (MS) and facilitate know-how/technology transfer to developing MS. The former is usually achieved through coordinated research projects (CRP) and thematic technical meetings, while the latter is mainly accomplished through technical cooperation (TC) projects. Coordinated research projects encourage research on, and development and practical application of, radiation technology to foster exchange of scientific and technical information. The technical cooperation (TC) programme helps Member States to realize their development priorities through the application of appropriate radiation technology. The IAEA has implemented several coordinated research projects (CRP) recently, including one on-going project, in the field of radiation processing of polymeric materials. The CRPs facilitated the acquisition and dissemination of know-how and technology for controlling of degradation effects in radiation processing of polymers, radiation synthesis of stimuli-responsive membranes, hydrogels and absorbents for separation purposes and the use of radiation processing to prepare biomaterials for applications in medicine. The IAEA extends cooperation to well-known international conferences dealing with radiation technology to facilitate participation of talented scientists from developing MS and building collaborations. The IAEA published technical documents, covering the findings of thematic technical meetings (TM) and coordinated research projects have been an important source of valuable practical information

  9. Proceedings of the 17. Annual Meeting of the Brazilian Chemistry Society; 7. National Symposium on Inorganic Chemistry. Abstracts

    International Nuclear Information System (INIS)

    1994-01-01

    These 17. Annual Meeting of the Brazilian Chemistry Society and 7. National Symposium on Inorganic Chemistry present several subjects of different interests for the participants, including sections about inorganic chemistry; organic chemistry; environmental chemistry; technological chemistry; electrochemistry; physical chemistry; photochemistry; chemical education; natural products; analytical chemistry and biological chemistry. (C.G.C.)

  10. XIII International science and technology conference High-tech chemical technologies-2010 with elements of Scientific school for young people Innovations in chemistry: achievements and prospects. Summaries of reports

    International Nuclear Information System (INIS)

    2010-01-01

    Materials of the XIII International science and technology conference High-tech chemical technologies-2010 with elements of Scientific school for young people Innovations in chemistry: achievements and prospects (29 June-2 July 2010, Ivanovo) are presented. During the conference the following areas: theoretical aspects of chemical technology; technology of deep oil refining and the production of organic substances; technology of drugs and biologically active substances; technology of inorganic materials, polymers and composites based on them - the technological principles and methods of synthesis, modification, and processing; environmental and economic problems of chemical technologies and their solutions are considered [ru

  11. Workshop on APEC virtual center for environmental technology exchange; APEC kankyo gijutsu koryu virtual center workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    At the 'policy maker workshop of the virtual center of APEC technology exchange' held in November 1997 in Osaka, Japan, it was agreed to organize study groups to discuss the scope of information provided by the virtual center, and to make common the classification systems and retrieval functions. In addition, the necessity was confirmed on international cooperation to promote establishment of virtual centers in different countries and territories. On the first day, Professor Ueda at the Kyoto University gave the basic lecture entitled 'global environment preservation and environmental technology transfer: problems and prospects'. Mr. Dan, the workshop manager gave the basic proposal entitled 'the future directionality of environmental technology exchange inside the APEC territories by using Internet'. Based on the basic proposal made on the first day, reports and discussions were given in the following sessions, where confirmation was made on the future directions. S1: establishment of the virtual centers in other countries and territories; S2: assurance of interchangeability of classification systems and retrieval functions in providing information, and S3: presentation of examples of inter-territorial exchange and the future directionality. (NEDO)

  12. Ion Exchange Technology Development in Support of the Urine Processor Assembly Precipitation Prevention Project for the International Space Station

    Science.gov (United States)

    Mitchell, Julie L.; Broyan, James L.; Pickering, Karen D.; Adam, Niklas; Casteel, Michael; Callahan, Michael; Carrier, Chris

    2012-01-01

    In support of the Urine Processor Assembly Precipitation Prevention Project (UPA PPP), multiple technologies were explored to prevent CaSO4 2H2O (gypsum) precipitation during the on-orbit distillation process. Gypsum precipitation currently limits the water recovery rate onboard the International Space Station (ISS) to 70% versus the planned 85% target water recovery rate. Due to its ability to remove calcium cations in pretreated augmented urine (PTAU), ion exchange was selected as one of the technologies for further development by the PPP team. A total of 13 ion exchange resins were evaluated in various equilibrium and dynamic column tests with solutions of dissolved gypsum, urine ersatz, PTAU, and PTAU brine at 85% water recovery. While initial evaluations indicated that the Purolite SST60 resin had the highest calcium capacity in PTAU (0.30 meq/mL average), later tests showed that the Dowex G26 and Amberlite FPC12H resins had the highest capacity (0.5 meq/mL average). Testing at the Marshall Spaceflight Center (MSFC) integrates the ion exchange technology with a UPA ground article under flight-like pulsed flow conditions with PTAU. To date, no gypsum precipitation has taken place in any of the initial evaluations.

  13. Workshop on APEC virtual center for environmental technology exchange; APEC kankyo gijutsu koryu virtual center workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-07-01

    At the 'policy maker workshop of the virtual center of APEC technology exchange' held in November 1997 in Osaka, Japan, it was agreed to organize study groups to discuss the scope of information provided by the virtual center, and to make common the classification systems and retrieval functions. In addition, the necessity was confirmed on international cooperation to promote establishment of virtual centers in different countries and territories. On the first day, Professor Ueda at the Kyoto University gave the basic lecture entitled 'global environment preservation and environmental technology transfer: problems and prospects'. Mr. Dan, the workshop manager gave the basic proposal entitled 'the future directionality of environmental technology exchange inside the APEC territories by using Internet'. Based on the basic proposal made on the first day, reports and discussions were given in the following sessions, where confirmation was made on the future directions. S1: establishment of the virtual centers in other countries and territories; S2: assurance of interchangeability of classification systems and retrieval functions in providing information, and S3: presentation of examples of inter-territorial exchange and the future directionality. (NEDO)

  14. International exchange project for the engineer exchange project (in coal mine technology area) in fiscal 1998. Overseas workshop; 1998 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Kaigai workshop

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The international exchange project for the engineer exchange project (in coal mine technology area) in fiscal 1998, the 'Overseas workshop' has performed exchange in technologies with Australian coal mine engineers. The project refers to the Australian technological levels and needs in coal production, safety control and environment, as well as transfer of the Japanese coal mine technologies. This report summarizes the result of a survey on the engineer exchange project in the coal mine technology area and the possibility of joint researches. The 'overseas workshop' was held in November 1998 for two days in Brisbane City in QLD Province as the 'Japan-Australia coal technology workshop'. The 'Japan-Australia coal technology workshop' gave lectures in five sessions (the basic lecture, Japan-Australia high-speed excavation project, coal mine gas control project, exploration and resources, and development and experience of Japan). It also discussed two themes (mine safety management and rules, and greenhouse effect gases and coal mining). Two coal mines were visited thereafter to deepen the exchange with the Australian coal mine engineers. (NEDO)

  15. International exchange project for the engineer exchange project (in coal mine technology area) in fiscal 1998. Overseas workshop; 1998 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Kaigai workshop

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The international exchange project for the engineer exchange project (in coal mine technology area) in fiscal 1998, the 'Overseas workshop' has performed exchange in technologies with Australian coal mine engineers. The project refers to the Australian technological levels and needs in coal production, safety control and environment, as well as transfer of the Japanese coal mine technologies. This report summarizes the result of a survey on the engineer exchange project in the coal mine technology area and the possibility of joint researches. The 'overseas workshop' was held in November 1998 for two days in Brisbane City in QLD Province as the 'Japan-Australia coal technology workshop'. The 'Japan-Australia coal technology workshop' gave lectures in five sessions (the basic lecture, Japan-Australia high-speed excavation project, coal mine gas control project, exploration and resources, and development and experience of Japan). It also discussed two themes (mine safety management and rules, and greenhouse effect gases and coal mining). Two coal mines were visited thereafter to deepen the exchange with the Australian coal mine engineers. (NEDO)

  16. Expectations and realities in the nuclear technology exchanges with the USSR

    Energy Technology Data Exchange (ETDEWEB)

    Lewin, J.

    1980-01-01

    A nontechnical, subjective account is given of some of the experiences and personal encounters in the US-USSR technical exchange visit programs. Some notes are given on the growth of nuclear power in the two countries. (DLC)

  17. Proceedings of the 1st JAEA/KAERI information exchange meeting on HTGR and nuclear hydrogen technology

    International Nuclear Information System (INIS)

    Sato, Hiroyuki; Sakaba, Nariaki; Nishihara, Tetsuo; Yan, Xing L.; Hino, Ryutaro

    2007-03-01

    Japan Atomic Energy Agency (JAEA) has completed an implementation with Korea Atomic Energy Research Institute (KAERI) on HTGR and nuclear hydrogen technology, 'The Implementation of Cooperative Program in the Field of Peaceful Uses of Nuclear Energy between KAERI and JAEA. 'To facilitate efficient technology development on HTGR and nuclear hydrogen by the IS process, an information exchange meeting was held at the Oarai Research and Development Center of JAEA on August 28-30, 2006 under Program 13th of the JAEA/KAERI Implementation, 'Development of HTGR and Nuclear Hydrogen Technology'. JAEA and KAERI mutually showed the status and future plan of the HTTR (High-Temperature Engineering Test Reactor) project in Japan and of the NHDD (Nuclear Hydrogen Development and Demonstration) project in Korea, respectively, and discussed collaboration items. This proceedings summarizes all materials of presented technical discussions on HTGR and hydrogen production technology as well as the meeting briefing including collaboration items. (author)

  18. Measuring ocean acidification: new technology for a new era of ocean chemistry.

    Science.gov (United States)

    Byrne, Robert H

    2014-05-20

    Human additions of carbon dioxide to the atmosphere are creating a cascade of chemical consequences that will eventually extend to the bottom of all the world's oceans. Among the best-documented seawater effects are a worldwide increase in open-ocean acidity and large-scale declines in calcium carbonate saturation states. The susceptibility of some young, fast-growing calcareous organisms to adverse impacts highlights the potential for biological and economic consequences. Many important aspects of seawater CO2 chemistry can be only indirectly observed at present, and important but difficult-to-observe changes can include shifts in the speciation and possibly bioavailability of some life-essential elements. Innovation and invention are urgently needed to develop the in situ instrumentation required to document this era of rapid ocean evolution.

  19. Analytical chemistry instrumentation

    International Nuclear Information System (INIS)

    Laing, W.R.

    1986-01-01

    In nine sections, 48 chapters cover 1) analytical chemistry and the environment 2) environmental radiochemistry 3) automated instrumentation 4) advances in analytical mass spectrometry 5) fourier transform spectroscopy 6) analytical chemistry of plutonium 7) nuclear analytical chemistry 8) chemometrics and 9) nuclear fuel technology

  20. 7. Seminar of the IIE-IMP-ININ on technological specialities. Topic 8: Analytical Chemistry

    International Nuclear Information System (INIS)

    1994-01-01

    With the purpose to give continuity to the exchange of experiences and to impel the development of common specialties among IIE-ININ-IMP, the VII Seminary was held in Mexico City on September 7, 1994. In the event were present 163 researchers of the three participant Institutions as well as representative persons of invited institutions. The objective of this Seminary was to relate the researchers of a common branch, with the idea that the specialists made an exchange of experiences, in order to establish cooperation routes. The event was arranged in 11 working tables, with a total of 111 papers: 43 of these papers were from IIE, 42 from IMP, 22 from ININ and 4 from invited entities. During the Seminary, the 11 working tables has sessions simultaneously, and each one of the papers were discussed at the time that possible future cooperating inter institutional actions were examined. The conclusions of the Seminary were exposed in a plenary session, in the presence of the directing boards of the three participant Institutions

  1. Incorporating spectroscopy and measurement technology into the high school chemistry laboratory

    Science.gov (United States)

    Harbert, Emily Ann

    Science and technology are becoming increasingly important in maintaining a healthy economy at home and a competitive edge on the world stage, though that is just one facet affected by inadequate science education in the United States. Engaging students in the pursuit of knowledge and giving them the skills to think critically are paramount. One small way to assist in achieving these goals is to increase the quality and variety of technology-rich activities conducted in high school classrooms. Incorporating more laboratory measurement technology into high schools may incite more student interest in the processes and practices of science and may allow students to learn to think more critically about their data and what it represents. The first objective of the work described herein was to determine what measurement technology is being used in schools and to what extent, as well as to determine other teacher needs and preferences. Second, the objective was to develop a new program to provide incoming freshmen (or rising seniors) with measurement technology training they did not receive in high school, and expose them to new research and career opportunities in science. The final objective was to create a technology-rich classroom laboratory activity for use in high schools.

  2. Biomimetic surface modification of polypropylene by surface chain transfer reaction based on mussel-inspired adhesion technology and thiol chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Niu, Zhijun; Zhao, Yang; Sun, Wei; Shi, Suqing, E-mail: shisq@nwu.edu.cn; Gong, Yongkuan

    2016-11-15

    Highlights: • Biomimetic surface modification of PP was successfully conducted by integrating mussel-inspired technology, thiol chemistry and cell outer membranes-like structures. • The resultant biomimetic surface exhibits good interface and surface stability. • The obvious suppression of protein adsorption and platelet adhesion is also achieved. • The residue thoil groups on the surface could be further functionalized. - Abstract: Biomimetic surface modification of polypropylene (PP) is conducted by surface chain transfer reaction based on the mussel-inspired versatile adhesion technology and thiol chemistry, using 2-methacryloyloxyethylphosphorylcholine (MPC) as a hydrophilic monomer mimicking the cell outer membrane structure and 2,2-azobisisobutyronitrile (AIBN) as initiator in ethanol. A layer of polydopamine (PDA) is firstly deposited onto PP surface, which not only offers good interfacial adhesion with PP, but also supplies secondary reaction sites (-NH{sub 2}) to covalently anchor thiol groups onto PP surface. Then the radical chain transfer to surface-bonded thiol groups and surface re-initiated polymerization of MPC lead to the formation of a thin layer of polymer brush (PMPC) with cell outer membrane mimetic structure on PP surface. X-ray photoelectron spectrophotometer (XPS), atomic force microscopy (AFM) and water contact angle measurements are used to characterize the PP surfaces before and after modification. The protein adsorption and platelet adhesion experiments are also employed to evaluate the interactions of PP surface with biomolecules. The results show that PMPC is successfully grafted onto PP surface. In comparison with bare PP, the resultant PP-PMPC surface exhibits greatly improved protein and platelet resistance performance, which is the contribution of both increased surface hydrophilicity and zwitterionic structure. More importantly, the residue thiol groups on PP-PMPC surface create a new pathway to further functionalize such

  3. Biomimetic surface modification of polypropylene by surface chain transfer reaction based on mussel-inspired adhesion technology and thiol chemistry

    International Nuclear Information System (INIS)

    Niu, Zhijun; Zhao, Yang; Sun, Wei; Shi, Suqing; Gong, Yongkuan

    2016-01-01

    Highlights: • Biomimetic surface modification of PP was successfully conducted by integrating mussel-inspired technology, thiol chemistry and cell outer membranes-like structures. • The resultant biomimetic surface exhibits good interface and surface stability. • The obvious suppression of protein adsorption and platelet adhesion is also achieved. • The residue thoil groups on the surface could be further functionalized. - Abstract: Biomimetic surface modification of polypropylene (PP) is conducted by surface chain transfer reaction based on the mussel-inspired versatile adhesion technology and thiol chemistry, using 2-methacryloyloxyethylphosphorylcholine (MPC) as a hydrophilic monomer mimicking the cell outer membrane structure and 2,2-azobisisobutyronitrile (AIBN) as initiator in ethanol. A layer of polydopamine (PDA) is firstly deposited onto PP surface, which not only offers good interfacial adhesion with PP, but also supplies secondary reaction sites (-NH 2 ) to covalently anchor thiol groups onto PP surface. Then the radical chain transfer to surface-bonded thiol groups and surface re-initiated polymerization of MPC lead to the formation of a thin layer of polymer brush (PMPC) with cell outer membrane mimetic structure on PP surface. X-ray photoelectron spectrophotometer (XPS), atomic force microscopy (AFM) and water contact angle measurements are used to characterize the PP surfaces before and after modification. The protein adsorption and platelet adhesion experiments are also employed to evaluate the interactions of PP surface with biomolecules. The results show that PMPC is successfully grafted onto PP surface. In comparison with bare PP, the resultant PP-PMPC surface exhibits greatly improved protein and platelet resistance performance, which is the contribution of both increased surface hydrophilicity and zwitterionic structure. More importantly, the residue thiol groups on PP-PMPC surface create a new pathway to further functionalize such

  4. Unraveling the mysteries of microwave chemistry using silicon carbide reactor technology.

    Science.gov (United States)

    Kappe, C Oliver

    2013-07-16

    In the past few years, the use of microwave energy to heat chemical reactions has become an increasingly popular theme in the scientific community. This nonclassical heating technique has slowly progressed from a laboratory curiosity to an established method commonly used both in academia and in industry. Because of its efficiency, microwave heating dramatically reduces reaction times (from days and hours to minutes and seconds) and improves product purities or material properties among other advantages. Since the early days of microwave chemistry, researchers have observed rate-accelerations and, in some cases, altered product distributions as compared with reactions carried out using classical oil-bath heating. As a result, researchers have speculated that so-called specific or nonthermal microwave effects could be responsible for these differences. Much of the debate has centered on the question of whether the electromagnetic field can exert a direct influence on a chemical transformation outside of the simple macroscopic change in bulk reaction temperature. In 2009, our group developed a relatively simple "trick" that allows us to rapidly evaluate whether an observed effect seen in a microwave-assisted reaction results from a purely thermal phenomenon, or involves specific or nonthermal microwave effects. We use a microwave reaction vessel made from silicon carbide (SiC) ceramic. Because of its high microwave absorptivity, the vessel shields its contents from the electromagnetic field. As a result, we can easily mimic a conventionally heated autoclave experiment inside a microwave reactor under carefully controlled reaction conditions. The switch from an almost microwave transparent glass (Pyrex) to a strongly microwave absorbing SiC reaction vial under otherwise identical reaction conditions (temperature profiles, pressure, stirring speed) then allows us to carefully evaluate the influence of the electromagnetic field on the particular chemical transformation

  5. Fundamentals of nuclear chemistry

    International Nuclear Information System (INIS)

    Majer, V.

    1982-01-01

    The author of the book has had 25 years of experience at the Nuclear Chemistry of Prague Technical University. In consequence, the book is intended as a basic textbook for students of this field. Its main objectives are an easily understandable presentation of the complex subject and in spite of the uncertainty which still characterizes the definition and subjects of nuclear chemistry - a systematic classification and logical structure. Contents: 1. Introduction (history and definition); 2. General nuclear chemistry (physical fundamentals, hot atom chemistry, interaction of nuclear radiation with matter, radioactive elements, isotope effects, isotope exchange, chemistry of radioactive trace elements); 3. Methods of nuclear chemistry of nuclear chemistry (radiochemical methods, activation, separation and enrichment chemistry); 4. Preparative nuclear chemistry (isotope production, labelled compounds); 5. Analytival nuclear chemistry; 6. Applied nuclear chemistry (isotope applications in general physical and analytical chemistry). The book is supplemented by an annex with tables, a name catalogue and a subject index which will facilitate access to important information. (RB) [de

  6. Thirty-seventh ORNL/DOE conference on analytical chemistry in energy technology: Abstracts of papers

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-31

    Abstracts only are given for papers presented during the following topical sessions: Opportunities for collaboration: Industry, academic, national laboratories; Developments in sensor technology; Analysis in containment facilities; Improving the quality of environmental data; Process analysis; Field analysis; Radiological separations; Interactive analytical seminars; Measurements and chemical industry initiatives; and Isotopic measurements and mass spectroscopy.

  7. Cellulose fibers: bio- and nano-polymer composites ; green chemistry and technology

    National Research Council Canada - National Science Library

    Kalia, Susheel; Kaith, B. S; Inderjeet Kaur

    2011-01-01

    ... on eco-friendly materials, and the steps taken in this direction will lead toward GreenScience and Green-Technology. Cellulosics account for about half of the dry weight of plant biomass and approximately half of the dry weight of secondary sources of waste biomass. At this crucial moment, cellulose fibers are pushed due to their "gr...

  8. The Chemistry and Technology of Furfural Production in Modern Lignocellulose-Feedstock Biorefineries

    NARCIS (Netherlands)

    Marcotullio, G.

    2011-01-01

    This dissertation deals with biorefinery technology development, i.e. with the development of sustainable industrial methods aimed at the production of chemicals, fuels, heat and power from lignocellulosic biomass. This work is particularly focused on the production of furfural from

  9. Combined electrolysis and catalytic exchange (CECE) technology - an economical alternative for heavy water upgraders using water distillation

    International Nuclear Information System (INIS)

    Ryland, D.K.; Sadhankar, R.R.

    2003-01-01

    Heavy water upgrading is a unique and crucial part of a CANDU power station. Water distillation (DW) systems are used for heavy water upgrading in all CANDU stations. The DW upgrader is designed to take advantage of the difference in relative volatility (a measure of separation of isotopes) between H 2 O and D 2 O. However, the low relative volatility of the H 2 O/D 2 O system requires large number of stages (long columns) and large reflux ratios (large reboiler loads) - thus resulting in significant capital and operating costs. Atomic Energy of Canada Limited (AECL) developed the Combined Electrolysis and Catalytic Exchange (CECE) technology as an economical alternative to the DW system. CECE-based upgraders have been demonstrated in pilot scale facilities at AECL Chalk River Laboratories and in Hamilton, Ontario. This design is based on catalytic hydrogen isotope exchange between water and hydrogen gas. (author)

  10. Engineer exchanging project on coal mine technology field in fiscal 1999. International information exchanging project (the overseas workshop in Vietnam); 1999 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Kaigai workshop (Vietnam)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Technical information exchange was performed with Vietnamese engineers related to coal mine technologies through the overseas workshop and the technical tour. At the same time, investigations were executed on the production technology levels and needs in Vietnam, and on possibilities of transfer of Japanese technologies. The 'Overseas workshop (Vietnam)' was held on September 28, 1999 with the 'trends and problems in coal production technologies' as the main theme. Lectures were given in the session related to coal production technologies by Vietnamese coal technology experts, each from VINACOAL and IMSAT, and by two Japanese coal technology experts. A comprehensive discussion was also executed, and items of technical information were exchanged on the coal production technologies. The number of persons actually participated in the workshop counted 58, with the proceedings presented by them distributed. The Mao Khe and Duong Huy coal mines in Quang Ninh Province were visited as the technical tour, whereas the coal mine sites were inspected and opinions were exchanged with the site engineers. Gas analysis was performed in the Mao Khe mine from the viewpoint of a gas control technology, and site investigation was carried out on lock bolts in the Duong Huy mine from the viewpoint of a roof control technology. (NEDO)

  11. DOE fundamentals handbook: Chemistry

    International Nuclear Information System (INIS)

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids)

  12. The Role of IAEA in Coordinating Research and Transferring Technology in Radiation Chemistry and Processing of Polymers

    International Nuclear Information System (INIS)

    Haji Saeid, M.

    2006-01-01

    The IAEA has been playing a significant role in fostering developments in radiation technology in general and radiation processing of polymers in particular, among its Member States (MS) and facilitate know-how/technology transfer to developing MS. The former is usually achieved through coordinated research projects (CRP) and thematic technical meetings, while the latter is mainly accomplished through Technical Cooperation (TC) projects. Coordinated research projects encourage research on, and development and practical application of, radiation technology to foster exchange of scientific and technical information. The CRP brings together typically 10 - 15 groups of participants to share and complement core competencies and work on specific areas of development needed to benefit from an emerging radiation technique and its applications. The technical cooperation (TC) programme helps Member States realize their development priorities through the application of appropriate radiation technology. TC builds national capacities through training, expert advice and delivery of equipment. The impact of the IAEA's efforts is visible by the progress noticeable in adoption of radiation technology and/or growth in the range of activities in several MS in different regions. The IAEA has implemented several coordinated research projects (CRP) recently, including one on-going project, in the field of radiation processing of polymeric materials. The CRPs facilitated the acquisition and dissemination of know-how and technology for controlling of degradation effects in radiation processing of polymers, radiation synthesis of stimuli-responsive membranes, hydrogels and absorbents for separation purposes and the use of radiation processing to prepare biomaterials for applications in medicine. A number of technical cooperation projects have been implemented in this field to strengthen the capability of developing Member States and to create awareness in the industries about the technical

  13. An overview of heat exchanger technology in the Canadian nuclear program

    International Nuclear Information System (INIS)

    Carlucci, L.N.; Dalrymple, D.G.; Ko, P.L.; Pathania, R.; Pettigrew, M.I.; Scott, D.A.

    1981-06-01

    This paper provides an overview of the Canadian approach to the reliability and serviceability of heat exchange equipment used in nuclear power stations and heavy water plants. Current work in vibration and fretting predictions, thermal-hydraulic analyses, and corrosion research is described. Procedures developed for in-service inspection, in situ tube replacment and chemical cleaning of corrosion products are also outlined

  14. Examining the Use of Adaptive Technologies to Increase the Hands-On Participation of Students with Blindness or Low Vision in Secondary-School Chemistry and Physics

    Science.gov (United States)

    Supalo, Cary A.; Humphrey, Jennifer R.; Mallouk, Thomas E.; Wohlers, H. David; Carlsen, William S.

    2016-01-01

    To determine whether a suite of audible adaptive technologies would increase the hands-on participation of high school students with blindness or low vision in chemistry and physics courses, data were examined from a multi-year field study conducted with students in mainstream classrooms at secondary schools across the United States. The students…

  15. Contextualizing Technology in the Classroom via Remote Access: Using Space Exploration Themes and Scanning Electron Microscopy as Tools to Promote Engagement in Geology/Chemistry Experiments

    Science.gov (United States)

    Rodriguez, Brandon; Jaramillo, Veronica; Wolf, Vanessa; Bautista, Esteban; Portillo, Jennifer; Brouke, Alexandra; Min, Ashley; Melendez, Andrea; Amann, Joseph; Pena-Francesch, Abdon; Ashcroft, Jared

    2018-01-01

    A multidisciplinary science experiment was performed in K-12 classrooms focusing on the interconnection between technology with geology and chemistry. The engagement and passion for science of over eight hundred students across twenty-one classrooms, utilizing a combination of hands-on activities using relationships between Earth and space rock…

  16. Improving Chemistry Education by Offering Salient Technology Training to Preservice Teachers: A Graduate-Level Course on Using Software to Teach Chemistry

    Science.gov (United States)

    Tofan, Daniel C.

    2009-01-01

    This paper describes an upper-level undergraduate and graduate-level course on computers in chemical education that was developed and offered for the first time in Fall 2007. The course provides future chemistry teachers with exposure to current software tools that can improve productivity in teaching, curriculum development, and education…

  17. Radiation chemistry

    International Nuclear Information System (INIS)

    Rodgers, F.; Rodgers, M.A.

    1987-01-01

    The contents of this book include: Interaction of ionizing radiation with matter; Primary products in radiation chemistry; Theoretical aspects of radiation chemistry; Theories of the solvated electron; The radiation chemistry of gases; Radiation chemistry of colloidal aggregates; Radiation chemistry of the alkali halides; Radiation chemistry of polymers; Radiation chemistry of biopolymers; Radiation processing and sterilization; and Compound index

  18. The Unsuspected Roles of Chemistry in Nuclear Power Plants: Special Chemical Technologies for Enhanced Safety and Increased Performance

    International Nuclear Information System (INIS)

    Sempere Belda, Luis

    2008-01-01

    The plant's chemists main responsibility is the establishment and monitoring of an adequate water chemistry to minimize corrosion and in PWRs, to control the neutron flux. But this is by no means the only way in which chemical applications contribute to the performance and safety of a NPP during its entire life: The use of special coatings and treatment protects the plant's components from aggressive environmental conditions. The chemical scale removal in steam generators improves the power output of aging plants, helping even to achieve permissions for NPP life extension. The use of special adhesives can replace welding in complicated or high-dose areas, even underwater. And chemical decontamination is used to remove activity from the components of the primary circuit prior to maintenance or replacement works in order to decrease the radiation exposure of the plant's personnel, employing revolutionary methods of waste minimization to limit the amount of generated radioactive waste to a minimum. The AREVA Group, in its pursue of excellence in all stages of the nuclear cycle, has devoted years of research and development to be able to provide the most advanced technological solutions in this field. The awareness of the existing possibilities will help present and future nuclear professionals, chemists and non-chemists alike, to benefit from the years of experience and continuous development in chemical technologies at the service of the nuclear industry. (authors)

  19. The Unsuspected Roles of Chemistry in Nuclear Power Plants: Special Chemical Technologies for Enhanced Safety and Increased Performance

    Energy Technology Data Exchange (ETDEWEB)

    Sempere Belda, Luis [AREVA NP GmbH, An AREVA and SIEMENS Company, P.O. Box 1109, Erlangen (Germany)

    2008-07-01

    The plant's chemists main responsibility is the establishment and monitoring of an adequate water chemistry to minimize corrosion and in PWRs, to control the neutron flux. But this is by no means the only way in which chemical applications contribute to the performance and safety of a NPP during its entire life: The use of special coatings and treatment protects the plant's components from aggressive environmental conditions. The chemical scale removal in steam generators improves the power output of aging plants, helping even to achieve permissions for NPP life extension. The use of special adhesives can replace welding in complicated or high-dose areas, even underwater. And chemical decontamination is used to remove activity from the components of the primary circuit prior to maintenance or replacement works in order to decrease the radiation exposure of the plant's personnel, employing revolutionary methods of waste minimization to limit the amount of generated radioactive waste to a minimum. The AREVA Group, in its pursue of excellence in all stages of the nuclear cycle, has devoted years of research and development to be able to provide the most advanced technological solutions in this field. The awareness of the existing possibilities will help present and future nuclear professionals, chemists and non-chemists alike, to benefit from the years of experience and continuous development in chemical technologies at the service of the nuclear industry. (authors)

  20. WikiHyperGlossary (WHG): an information literacy technology for chemistry documents.

    Science.gov (United States)

    Bauer, Michael A; Berleant, Daniel; Cornell, Andrew P; Belford, Robert E

    2015-01-01

    The WikiHyperGlossary is an information literacy technology that was created to enhance reading comprehension of documents by connecting them to socially generated multimedia definitions as well as semantically relevant data. The WikiHyperGlossary enhances reading comprehension by using the lexicon of a discipline to generate dynamic links in a document to external resources that can provide implicit information the document did not explicitly provide. Currently, the most common method to acquire additional information when reading a document is to access a search engine and browse the web. This may lead to skimming of multiple documents with the novice actually never returning to the original document of interest. The WikiHyperGlossary automatically brings information to the user within the current document they are reading, enhancing the potential for deeper document understanding. The WikiHyperGlossary allows users to submit a web URL or text to be processed against a chosen lexicon, returning the document with tagged terms. The selection of a tagged term results in the appearance of the WikiHyperGlossary Portlet containing a definition, and depending on the type of word, tabs to additional information and resources. Current types of content include multimedia enhanced definitions, ChemSpider query results, 3D molecular structures, and 2D editable structures connected to ChemSpider queries. Existing glossaries can be bulk uploaded, locked for editing and associated with multiple social generated definitions. The WikiHyperGlossary leverages both social and semantic web technologies to bring relevant information to a document. This can not only aid reading comprehension, but increases the users' ability to obtain additional information within the document. We have demonstrated a molecular editor enabled knowledge framework that can result in a semantic web inductive reasoning process, and integration of the WikiHyperGlossary into other software technologies, like

  1. Chemogenomics: a discipline at the crossroad of high throughput technologies, biomarker research, combinatorial chemistry, genomics, cheminformatics, bioinformatics and artificial intelligence.

    Science.gov (United States)

    Maréchal, Eric

    2008-09-01

    Chemogenomics is the study of the interaction of functional biological systems with exogenous small molecules, or in broader sense the study of the intersection of biological and chemical spaces. Chemogenomics requires expertises in biology, chemistry and computational sciences (bioinformatics, cheminformatics, large scale statistics and machine learning methods) but it is more than the simple apposition of each of these disciplines. Biological entities interacting with small molecules can be isolated proteins or more elaborate systems, from single cells to complete organisms. The biological space is therefore analyzed at various postgenomic levels (genomic, transcriptomic, proteomic or any phenotypic level). The space of small molecules is partially real, corresponding to commercial and academic collections of compounds, and partially virtual, corresponding to the chemical space possibly synthesizable. Synthetic chemistry has developed novel strategies allowing a physical exploration of this universe of possibilities. A major challenge of cheminformatics is to charter the virtual space of small molecules using realistic biological constraints (bioavailability, druggability, structural biological information). Chemogenomics is a descendent of conventional pharmaceutical approaches, since it involves the screening of chemolibraries for their effect on biological targets, and benefits from the advances in the corresponding enabling technologies and the introduction of new biological markers. Screening was originally motivated by the rigorous discovery of new drugs, neglecting and throwing away any molecule that would fail to meet the standards required for a therapeutic treatment. It is now the basis for the discovery of small molecules that might or might not be directly used as drugs, but which have an immense potential for basic research, as probes to explore an increasing number of biological phenomena. Concerns about the environmental impact of chemical industry

  2. Constitutional dynamic chemistry: bridge from supramolecular chemistry to adaptive chemistry.

    Science.gov (United States)

    Lehn, Jean-Marie

    2012-01-01

    Supramolecular chemistry aims at implementing highly complex chemical systems from molecular components held together by non-covalent intermolecular forces and effecting molecular recognition, catalysis and transport processes. A further step consists in the investigation of chemical systems undergoing self-organization, i.e. systems capable of spontaneously generating well-defined functional supramolecular architectures by self-assembly from their components, thus behaving as programmed chemical systems. Supramolecular chemistry is intrinsically a dynamic chemistry in view of the lability of the interactions connecting the molecular components of a supramolecular entity and the resulting ability of supramolecular species to exchange their constituents. The same holds for molecular chemistry when the molecular entity contains covalent bonds that may form and break reversibility, so as to allow a continuous change in constitution by reorganization and exchange of building blocks. These features define a Constitutional Dynamic Chemistry (CDC) on both the molecular and supramolecular levels.CDC introduces a paradigm shift with respect to constitutionally static chemistry. The latter relies on design for the generation of a target entity, whereas CDC takes advantage of dynamic diversity to allow variation and selection. The implementation of selection in chemistry introduces a fundamental change in outlook. Whereas self-organization by design strives to achieve full control over the output molecular or supramolecular entity by explicit programming, self-organization with selection operates on dynamic constitutional diversity in response to either internal or external factors to achieve adaptation.The merging of the features: -information and programmability, -dynamics and reversibility, -constitution and structural diversity, points to the emergence of adaptive and evolutive chemistry, towards a chemistry of complex matter.

  3. Atom-at-a-time chemistry

    International Nuclear Information System (INIS)

    Nagame, Yuichiro

    2009-01-01

    Several techniques of the analytical chemistry in 'Atom-at-a-time chemistry' for transactinide elements have been developed. In this report a representative example in these techniques is introduced with the results. The contents are the single-atom chemistry, the chemical experiments on transactinide elements, liquid phase chemistry (the ion exchange behavior of Rutherfordium), gas phase chemistry (the chemistry of atomic No.112 element), and future development. (M.H.)

  4. Capsicum--production, technology, chemistry, and quality. Part IV. Evaluation of quality.

    Science.gov (United States)

    Govindarajan, V S; Rajalakshmi, D; Chand, N

    1987-01-01

    Capsicum fruits are popular worldwide and are used in the cuisines of both the developing and the developed countries. With its different varieties, forms, and uses, the spice capsicum contributes to the entire gamut of sensory experience--color as finely ground paprika powder or extract in sausages, goulash, cheese, and snacks; both pungency and color as the many varieties of chillies used in Mexican, African, Indian, and southeast Asian cuisines; color, aroma, and mild pungency as the fresh green chillies used in many of the growing countries; and appearance, color, aroma, and texture as fresh fruit in salads and as a pickled and canned product. In three earlier parts in this series, the varieties, cultivation, and primary processing; the processed products, world production, and trade; and the chemistry of the color, aroma, and pungency stimuli have been reviewed. In this part, the evaluation of quality through instrumental determination of the causal components and the sensory evaluation of color, aroma, and pungency are discussed. Several methods for quantitative determination of the stimuli and the sensory evaluation of the responses to the stimuli are reviewed. The problems of sensory evaluation of color, aroma, and pungency, the dominant attributes for validation of the instrumentally determined values for carotenoids, volatiles, or particular fractions, and total and individual capsaicinoids are specifically discussed. Summarized details of selected instrumental methods for evaluating the stimuli, which are either validated by correlation to sensorily perceived responses or to adopted standards, are given along with representative data obtained for discussing the adequacy and reliability of the methods. Pungency as a specific gustatory perception and the many methods proposed to evaluate this quality are discussed. A recommended objective procedure for obtaining reproducible values is discussed, and a method for relating different panel results is shown

  5. Project to promote exchange of international information on environmental technologies; Kankyo gijutsu kokusai joho koryu sokushin jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Mutual information exchange at international levels is important for practical application of global environment preservation technologies, whereas the APEC Virtual Center was established in fiscal 1997. Fiscal 1998 has discussed the future functions of the Virtual Center, and carried out the following matters to improve the functions and achieve its stable operation. Discussions were given on common use with the centers of other countries and regions of the specifications of classification systems for information areas and provided information that are provided by the Virtual Center. Visits were made to sub-managing countries and regions for smooth operation of the study groups, and opinions were exchanged. Visits were made to coordinators and contact points established in each country and region when the Center was founded in fiscal 1997. A visit was made to the U.S. Environmental Protection Agency to exchange opinions on coordination measures with the Cleaner Production Strategy of the U.S.A. being a project similar to the subject project. In order to strengthen the Japan's Center, attempts were made to expand the linking information to wider scope. Special pages publishing concentratedly the items of information that the users are interested were prepared as part of the information provision. (NEDO)

  6. Enhancement of international cooperation and experience exchange: international and regional cooperation in nuclear technology

    International Nuclear Information System (INIS)

    Henderson, R.R.

    1987-01-01

    This paper will explore methods that have been effective in accomplishing broad-based technology transfer relationships between international commercial nuclear organizations, and have enhanced the benefits from such relationships through mutual participation in the development of new technology. The factors involved in accomplishing technology transfer will be examined based on the 25 years of Westinghouse experience in establishing successful nuclear technology relationships with over 20 different associates world-wide. This will include information pertaining to organization, training, consultation, technical information transmission, and other important aspects of technology transfer. Additionally, the methodology of enhancing and increasing the benefits of technology transfer through cooperative development programs as produced and promoted by Weatinghouse with its associates will be examined. This will include reviews of several significant copperative programs, such as the programs for the Advanced Pressurized Water Reactor and the Integrated Protection and Control Systems for future plants. (author)

  7. Enhancement of international cooperation and experience exchange - international and regional cooperation in nuclear technology

    International Nuclear Information System (INIS)

    Henderson, R.R.

    1988-01-01

    This paper will explore methods that have been effective in accomplishing broad-based technology transfer relationships between international commercial nuclear organizations, and have enhanced the benefits from such relationships through mutual participation in the development of new technology. The factors involved in accomplishing technology transfer will be examined based on the 25 years of Westinghouse experience in establishing successful nuclear technology relationships with over 20 different associates world-wide. This will include information pertaining to organization, training, consultation, technical information transmission, and other important aspects of technology transfer. Additionally, the methodology of enhancing and increasing the benefits of technology transfer through cooperative development programs as produced and promoted by Westinghouse with its associates will be examined. This will include reviews of several significant cooperative programs, such as the programs for the Advanced Pressurized Water Reactor and the Integrated Protection and Control Systems for future plants

  8. Rapid exchange ultra-thin microcatheter using fibre-optic sensing technology for measurement of intracoronary fractional flow reserve.

    Science.gov (United States)

    Diletti, Roberto; Van Mieghem, Nicolas M; Valgimigli, Marco; Karanasos, Antonis; Everaert, Bert R C; Daemen, Joost; van Geuns, Robert-Jan; de Jaegere, Peter P; Zijlstra, Felix; Regar, Evelyn

    2015-08-01

    The present report describes a novel coronary fractional flow reserve (FFR) system which allows FFR assessment using a rapid exchange microcatheter (RXi). The RXi microcatheter is compatible with standard 0.014" coronary guidewires facilitating lesion negotiation and FFR assessment in a wide range of coronary anatomies. In case of serial lesions, a microcatheter would have the important advantage of allowing multiple pullbacks while maintaining wire access to the vessel. The RXi is a fibre-optic sensor technology-based device. This technology might allow reduction in signal drift. The RXi microcatheter's fibre-optic sensor is located 5 mm from the distal tip. The microcatheter profile at the sensor site is 0.027"0.036". The segment of the catheter which is intended to reside within the target lesion is proximal to the sensor and has dimensions decreased to 0.020"0.025"; these dimensions are comparable to a 0.022" circular-shaped wire. The RXi microcatheter FFR system represents a novel technology that could allow easier lesion negotiation, maintaining guidewire position, facilitating pullbacks for assessment of serial lesions and simplifying the obtainment of post-intervention FFR measurements. The optical sensing technology could additionally result in less signal drift. Further investigations are required to evaluate the clinical value of this technology fully.

  9. Surface chemistry essentials

    CERN Document Server

    Birdi, K S

    2013-01-01

    Surface chemistry plays an important role in everyday life, as the basis for many phenomena as well as technological applications. Common examples range from soap bubbles, foam, and raindrops to cosmetics, paint, adhesives, and pharmaceuticals. Additional areas that rely on surface chemistry include modern nanotechnology, medical diagnostics, and drug delivery. There is extensive literature on this subject, but most chemistry books only devote one or two chapters to it. Surface Chemistry Essentials fills a need for a reference that brings together the fundamental aspects of surface chemistry w

  10. Interpreting chemistry and technology of lime binders and implementing it in the conservation field

    Directory of Open Access Journals (Sweden)

    Georgia Zacharopoulou

    2009-01-01

    Full Text Available The objective of the paper is the compilation, review and dissemination of updated scientific knowledge on lime theory and technology in the field of heritage conservation. The strong evidence of the last decade's research on the positive effect of the - not demonstrable by a chemical equation – 'key' missing link of the maturation process is highlighted. It is demonstrated that the exceptional perfor -mance characteristics of durable lime based mortars predominately rely on the capacity for rapid, efficient and extensive carbonation of the air-hardening phase of limes, in particular when matured (nanoparticle wet slaked lime putties are used; and on the chemical and mechanical stability of the strength components (principally CSHs of the hydraulic phase of limes, which is higher in their more crystalline forms of historical lime-pozzolan mixtures than in their amorphous forms of modern cements. Hence, physicochemical adhesion and cohesion bonds both at the lime matrix and at the binder/aggregate interfaces are ensured imparting minimization of cracks and durability to lime based mortars and historic masonries. The comprehensive documentation of the former leads to optimal materials and procedures to preserve our cultural heritage.

  11. Ion Exchange Technology Development in Support of the Urine Processor Assembly

    Science.gov (United States)

    Mitchell, Julie; Broyan, James; Pickering, Karen

    2013-01-01

    The urine processor assembly (UPA) on the International Space Station (ISS) recovers water from urine via a vacuum distillation process. The distillation occurs in a rotating distillation assembly (DA) where the urine is heated and subjected to sub-ambient pressure. As water is removed, the original organics, salts, and minerals in the urine become more concentrated and result in urine brine. Eventually, water removal will concentrate the urine brine to super saturation of individual constituents, and precipitation occurs. Under typical UPA DA operating conditions, calcium sulfate or gypsum is the first chemical to precipitate in substantial quantity. During preflight testing with ground urine, the UPA achieved 85% water recovery without precipitation. However, on ISS, it is possible that crewmember urine can be significantly more concentrated relative to urine from ground donors. As a result, gypsum precipitated in the DA when operating at water recovery rates at or near 85%, causing the failure and subsequent re14 NASA Tech Briefs, September 2013 placement of the DA. Later investigations have demonstrated that an excess of calcium and sulfate will cause precipitation at water recovery rates greater than 70%. The source of the excess calcium is likely physiological in nature, via crewmembers' bone loss, while the excess sulfate is primarily due to the sulfuric acid component of the urine pretreatment. To prevent gypsum precipitation in the UPA, the Precipitation Prevention Project (PPP) team has focused on removing the calcium ion from pretreated urine, using ion exchange resins as calcium removal agents. The selectivity and effectiveness of ion exchange resins are determined by such factors as the mobility of the liquid phase through the polymer matrix, the density of functional groups, type of functional groups bound to the matrix, and the chemical characteristics of the liquid phase (pH, oxidation potential, and ionic strength). Previous experience with ion

  12. Evaluation of a hybrid ion exchange-catalyst treatment technology for nitrate removal from drinking water.

    Science.gov (United States)

    Bergquist, Allison M; Choe, Jong Kwon; Strathmann, Timothy J; Werth, Charles J

    2016-06-01

    Ion exchange (IX) is the most common approach to treating nitrate-contaminated drinking water sources, but the cost of salt to make regeneration brine, as well as the cost and environmental burden of waste brine disposal, are major disadvantages. A hybrid ion exchange-catalyst treatment system, in which waste brine is catalytically treated for reuse, shows promise for reducing costs and environmental burdens of the conventional IX system. An IX model with separate treatment and regeneration cycles was developed, and ion selectivity coefficients for each cycle were separately calibrated by fitting experimental data. Of note, selectivity coefficients for the regeneration cycle required fitting the second treatment cycle after incomplete resin regeneration. The calibrated and validated model was used to simulate many cycles of treatment and regeneration using the hybrid system. Simulated waste brines and a real brine obtained from a California utility were also evaluated for catalytic nitrate treatment in a packed-bed, flow-through column with 0.5 wt%Pd-0.05 wt%In/activated carbon support (PdIn/AC). Consistent nitrate removal and no apparent catalyst deactivation were observed over 23 d (synthetic brine) and 45 d (real waste brine) of continuous-flow treatment. Ion exchange and catalyst results were used to evaluate treatment of 1 billion gallons of nitrate-contaminated source water at a 0.5 MGD water treatment plant. Switching from a conventional IX system with a two bed volume regeneration to a hybrid system with the same regeneration length and sequencing batch catalytic reactor treatment would save 76% in salt cost. The results suggest the hybrid system has the potential to address the disadvantages of a conventional IX treatment systems. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. Ion exchange technology in the remediation of uranium contaminated groundwater at Fernald

    International Nuclear Information System (INIS)

    Sutton, Chris; Glassmeyer, Cathy; Bozich, Steve

    2000-01-01

    Using pump and treat methodology, uranium contaminated groundwater is being removed from the Great Miami Aquifer at the Fernald Environmental Management Project (FEMP) per the FEMP Record of Decision (ROD) that defines groundwater cleanup. Standard extraction wells pump about 3900 gallons-per-minute (gpm) from the aquifer through five ion exchange treatment systems. The largest treatment system k the Advanced Wastewater Treatment (AWWT) Expansion System with a capacity of 1800 gpm, which consists of three trains of two vessels. The trains operate in parallel treating 600 gpm each, The two vessels in each train operate in series, one in lead and one in lag. Treated groundwater is either reinfected back into the aquifer to speed up the aquifer cleanup processor discharged to the Great Miami River. The uranium regulatory ROD limit for discharge to the river is 20 parts per billion (ppb), and the FEMP uranium administrative action level for reinfection is 10 ppb. Spent (i.e., a resin that no longer adsorbs uranium) ion exchange resins must either be replaced or regenerated. The regeneration of spent ion exchange resins is considerably more cost effective than their replacement. Therefore, a project was undertaken to learn how best to regenerate the resins in the groundwater vessels. At the outset of this project, considerable uncertainty existed as to whether a spent resin could be regenerated successfully enough so that it performed as well as new resin relative to achieving very low uranium concentrations in the effluent. A second major uncertain y was whether the operational lifetime of a regenerated resin would be similar to that of a new resin with respect to uranium loading capacity and effluent concentration behavior. The project was successful in that a method for regenerating resins has been developed that is operationally efficient, that results in regenerated resins yielding uranium concentrations much lower than regulatory limits, and that results in

  14. Fiscal 1999 engineer exchange project (field of coal mining technology), international exchange project. Domestic workshop; 1999 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Kokunai workshop

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The domestic workshop invites Japanese engineers and engineers from coal producing countries for the exchange of coal mining technologies and aims to substantiate and facilitate the dispatching and receiving of engineers under training programs. The main subject of the Asia-Pacific coal technology workshop was 'Coal for the 21st century - resources and technology,' and there were two sessions held on September 8, titled 'Trends and tasks of coal resources exploitation' and 'Coal resources and production technology.' Lectures were delivered by five overseas and five Japanese coal engineering experts. On September 9, nine essays were presented concerning 'Coal resources and security problems' and 'Coal resources and environmental problems.' In addition, a panel discussion was held, titled 'Coal resources assessment and technology.' Importance was emphasized of the correct assessment of the magnitude of resources, development of probing technologies to collect more detailed information, improvement of digging speeds applicable to faces for large and high-efficiency mining, development of coal mining technologies for increased recovery, etc. Information was exchanged on various occasions and partnership was enhanced between the participants to the advantage of engineer exchanging projects in the future. (NEDO)

  15. Bio nitrate Project: a new technology for water nitrate elimination by means of ionic exchange resins

    International Nuclear Information System (INIS)

    Arellano Ortiz, J.

    2009-01-01

    The use of ion exchange resins for nitrate elimination from water generates a waste containing a sodium chloride mixture plus the retained nitrates. this waste must be correctly disposed. In this project, the resin ionic form is modified to be regenerated with other compounds, different from the common salt, which are interesting because of the presence of mineral nutrition. So, with Bio nitrate Project, nitrates are recovered and the regeneration waste is apt to be use as fertilizer, for agricultural uses, or as complementary contribution of nutrients in biological water treatment. (Author) 27 refs.

  16. Development of Technological and Pedagogical Content Knowledge of the Chemistry by Teachers in Training Through the Reflection of PaP-eRs and Videos

    Directory of Open Access Journals (Sweden)

    Boris Fernando Candela

    2018-01-01

    Full Text Available This article described how trainee teachers identified and developed some elements of the Technological and Pedagogical Knowledge of Chemistry Content (CTPC, along the course of educational and pedagogical context by "reflective orientation". The methodological perspective was qualitative by case study, which was configured by two interwoven areas of reflection, namely: (a reflecting on the opinions of experts about the teaching of a content, through the readings proposed in the training programs; and (b reflecting on the teaching carried out by experienced teachers through case videos and the Repertoire of Professional and Pedagogical Experiences (PaP-eRs. This heuristic reduced the complexity of teaching in a manageable story located in a specific context, so that teachers could identify and reflect on their theories about the teaching and learning of chemistry. This study showed that teachers in training identified and developed the following elements of the CTPC of chemistry: general pedagogy, language as a learning tool, difficulties and alternative conceptions, knowledge of technology as an instrument to represent the contents and manage the chemistry classroom, and the formative evaluation. Definitely, the reflection of the critical events of the PaP-eRs and videos of cases was considered an appropriate heuristic that allowed the future teachers to articulate the knowledge coming from the literature in education in chemistry, with the virtual experiences of teaching-learning of a real context. Of course, this reflection was mediated by reading, discussing and reflecting on the intelligent actions of an exemplary teacher when guiding singular students from a sociocultural perspective, with the purpose of beginning to refine their theories of teaching and learning chemistry.

  17. Mobile Technology in Science Classrooms: Using iPad-Enabled Constructivist Learning to Promote Collaborative Problem Solving and Chemistry Learning

    Science.gov (United States)

    Ting, Melodie Mirth G.

    Most recently, there has been a noticeable rise in the push for use of technology in the classroom. The advancement in digital science has increased greatly the capacity to explore animations, models, and interesting apps. that should substantially enhance science cognition. At the same time, there is a great need to increase collaboration in the science classroom. There is a concern that the collaborative experience will be lost with the use of technology in the classroom. This study seeks to explore the use of iPads in conjunction with a constructivist learning approach to promote student collaboration. The participants in this study included two sections of 11 th grade AP Chemistry students. Data was generated from different sources such as teacher observations of classroom interactions patterned after Gilles (2004). In order to gauge student perception of working in groups with the use of the iPad, survey questions adapted from Knezek, Mills and Wakefield (2012) and group interviews were used (Galleta, 2013). Learning outcomes were assessed using methods adapted from a study by Lord and Baviskar (2007). Findings of this study showed high percentages of evidence for increased community, productive student group communication, effective feedback through use of the iPads, and value of the interactive apps., but it also showed that students still preferred face-to-face interactions over virtual interactions for certain learning situations. The study showed good content learning outcomes, as well as favorable opinions among the students for the effectiveness of the use of iPads in collaborative settings in the classroom.

  18. Antiparallel Dynamic Covalent Chemistries.

    Science.gov (United States)

    Matysiak, Bartosz M; Nowak, Piotr; Cvrtila, Ivica; Pappas, Charalampos G; Liu, Bin; Komáromy, Dávid; Otto, Sijbren

    2017-05-17

    The ability to design reaction networks with high, but addressable complexity is a necessary prerequisite to make advanced functional chemical systems. Dynamic combinatorial chemistry has proven to be a useful tool in achieving complexity, however with some limitations in controlling it. Herein we introduce the concept of antiparallel chemistries, in which the same functional group can be channeled into one of two reversible chemistries depending on a controllable parameter. Such systems allow both for achieving complexity, by combinatorial chemistry, and addressing it, by switching from one chemistry to another by controlling an external parameter. In our design the two antiparallel chemistries are thiol-disulfide exchange and thio-Michael addition, sharing the thiol as the common building block. By means of oxidation and reduction the system can be reversibly switched from predominantly thio-Michael chemistry to predominantly disulfide chemistry, as well as to any intermediate state. Both chemistries operate in water, at room temperature, and at mildly basic pH, which makes them a suitable platform for further development of systems chemistry.

  19. High temperature technological heat exchangers and steam generators with helical coil assembly tube bundle

    International Nuclear Information System (INIS)

    Korotaev, O.J.; Mizonov, N.V.; Nikolaevsky, V.B.; Nazarov, E.K.

    1990-01-01

    Analysis of thermal hydraulics characteristics of nuclear steam generators with different tube bundle arrangements and waste heat boilers for ammonia production units was performed on the basis of operating experience results and research and development data. The present report involves the obtained information. The estimations of steam generator performances and repair-ability are given. The significant temperature profile of the primary and secondary coolant flows are attributed to all steam generator designs. The intermediate mixing is found to be an effective means of temperature profile overcoming. At present the only means to provide an effective mixing in heat exchangers of the following types: straight tubes, field tubes, platen tubes and multibank helical coil tubes (with complicated bend distribution along their length) are section arrangements in series in conjunction with forced and natural mixing in connecting lines. Development of the unificated system from mini helical coil assemblies allows to design and manufacture heat exchangers and steam generators within the wide range of operating conditions without additional expenses on the research and development work

  20. The development of pedagogical content knowledge in science teachers: New opportunities through technology-mediated reflection and peer-exchange

    Science.gov (United States)

    Madeira, M. Cheryl-Ann

    This design-based research study investigates the development of pedagogical content knowledge among nine teacher-participants (N = 9) in three design phases. PCK is a particular type of teacher knowledge that addresses not only the teacher's understanding of the content to be instructed, but also ways of how to teach that content effectively. This knowledge has been well documented over several decades, and is seen as central to teacher expertise. However, its actual development has been difficult for researchers to investigate. This study offers a detailed perspective on how teachers developed PCK with their engagement in lesson planning and enactment of a project-based technology-enhanced lesson. The study includes two specific interventions designed to enhance teachers' development of PCK: (1) scaffolded reflection that occurs throughout the practices; and (2) peer-exchange of lesson plans, enactment ideas, and completed reflections. The findings demonstrate that teachers improve their planning and enactment of project-based technology-enhanced lessons with scaffolded reflection and peer exchange. Positive correlations were seen between teachers' engagement in the reflections and the quality of their lesson planning. Teachers who participated more deeply in the scaffolded reflections were able to understand how their lesson plans and enactment patterns fostered student understanding of relevant science concepts. Positive correlations were also seen between community influence and teacher lesson plans and enactment. Additionally, positive correlations were confirmed between teachers' level of participation in the peer exchange activities and the quality of their lesson planning and enactments. Teachers who contributed more deeply within the online and face-to-face peer community meetings benefited from the different perspectives of their peers about student learning and the best ways to succeed with project-based instruction. This study allowed some insight into

  1. Finding the Connections between a High-School Chemistry Curriculum and Nano-Scale Science and Technology

    Science.gov (United States)

    Blonder, Ron; Sakhnini, Sohair

    2017-01-01

    The high-school chemistry curriculum is loaded with many important chemical concepts that are taught at the high-school level and it is therefore very difficult to add modern contents to the existing curriculum. However, many studies have underscored the importance of integrating modern chemistry contents such as nanotechnology into a high-school…

  2. Engineer exchanging project (coal mine technology field) in fiscal 1999. International information exchanging project (advance survey on Russia); 1999 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Jizen chosa (Roshia)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This advance survey on Russia has performed visiting surveys and information collection at coal related organizations inside Japan and in overseas countries on production technology levels, trends and technology exchange needs in overseas coal producing countries. The project is intended to serve for improvement in the contents of and smooth execution of the engineer exchange project in the 'coal mine technology field. It was carried out by expertise people as the site surveys and the engineer reception and exchange surveys. Because of the economic crisis that has hit Russia in 1998, unprofitable coal mines were closed one after another under the coal mine scrap and build policy under the initiative of the World Bank. This situation is giving serious impacts on coal mines in the Far East Russia and the coastal areas. However, the importance of coal as the primary energy source has not been changed at all in the Far East Russia. Thus, the areas have fallen into a situation that they must rely on a great amount of introduced and imported coals as a result of weakening in coal mines in the Far Eastern area on the other hand. This paper reports mainly the situation in which the coal industries in the coastal areas are placed, and the possibilities of technology exchange. (NEDO)

  3. On-Line Ion Exchange Liquid Chromatography as a Process Analytical Technology for Monoclonal Antibody Characterization in Continuous Bioprocessing.

    Science.gov (United States)

    Patel, Bhumit A; Pinto, Nuno D S; Gospodarek, Adrian; Kilgore, Bruce; Goswami, Kudrat; Napoli, William N; Desai, Jayesh; Heo, Jun H; Panzera, Dominick; Pollard, David; Richardson, Daisy; Brower, Mark; Richardson, Douglas D

    2017-11-07

    Combining process analytical technology (PAT) with continuous production provides a powerful tool to observe and control monoclonal antibody (mAb) fermentation and purification processes. This work demonstrates on-line liquid chromatography (on-line LC) as a PAT tool for monitoring a continuous biologics process and forced degradation studies. Specifically, this work focused on ion exchange chromatography (IEX), which is a critical separation technique to detect charge variants. Product-related impurities, including charge variants, that impact function are classified as critical quality attributes (CQAs). First, we confirmed no significant differences were observed in the charge heterogeneity profile of a mAb through both at-line and on-line sampling and that the on-line method has the ability to rapidly detect changes in protein quality over time. The robustness and versatility of the PAT methods were tested by sampling from two purification locations in a continuous mAb process. The PAT IEX methods used with on-line LC were a weak cation exchange (WCX) separation and a newly developed shorter strong cation exchange (SCX) assay. Both methods provided similar results with the distribution of percent acidic, main, and basic species remaining unchanged over a 2 week period. Second, a forced degradation study showed an increase in acidic species and a decrease in basic species when sampled on-line over 7 days. These applications further strengthen the use of on-line LC to monitor CQAs of a mAb continuously with various PAT IEX analytical methods. Implementation of on-line IEX will enable faster decision making during process development and could potentially be applied to control in biomanufacturing.

  4. TRU-waste decontamination and size reduction review, June 1983, US DOE/PNC technology exchange

    International Nuclear Information System (INIS)

    Becker, G.W. Jr.

    1983-01-01

    A review of transuranic (TRU) noncombustible waste decontamination and size reduction technology is presented. Electropolishing, vibratory cleaning, and spray decontamination processes developed at Battelle Pacific Northwest Laboratory (PNL) and Savannah River Laboratory (SRL) are highlighted. TRU waste size reduction processes at (PNL), Los Alamos National Laboratory (LANL), the Rocky Flats Plant (RFP), and SRL are also highlighted

  5. FY 2000 international exchange project on exchanges of engineers - Coal mine technology field. Overseas workshop (China); 2000 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Kaigai workshop (Chugoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of making technical exchanges with coal mine related engineers in China and surveying levels of coal production technology and the needs in China and possibilities of technology transfer from Japan, workshop was held and technical tours were made. On December 13, 2000, a workshop was held in China which was named 'Japan-China Joint Coal Project Workshop: Environment/Production/Security.' Participants were 112 including 16 from Japan and 96 from China. Subjects were as follows: subjects on coal resource and technical strategy in the 21st century, technical exchange project and technical development, Japan-China technical cooperation project, report on the operational situation of China Coal Industry Environmental Preservation Safety Training Center, Japan-China Joint Project on spontaneous combustion prevention technology, CMG recovery/utilization system joint demonstration project, Japan-China joint coal exploration project, Japan-China coal field geology joint exploration project, etc. (NEDO)

  6. Modelling technological process of ion-exchange filtration of fluids in porous media

    Science.gov (United States)

    Ravshanov, N.; Saidov, U. M.

    2018-05-01

    Solution of an actual problem related to the process of filtration and dehydration of liquid and ionic solutions from gel particles and heavy ionic compounds is considered in the paper. This technological process is realized during the preparation and cleaning of chemical solutions, drinking water, pharmaceuticals, liquid fuels, products for public use, etc. For the analysis, research, determination of the main parameters of the technological process and operating modes of filter units and for support in managerial decision-making, a mathematical model is developed. Using the developed model, a series of computational experiments on a computer is carried out. The results of numerical calculations are illustrated in the form of graphs. Based on the analysis of numerical experiments, the conclusions are formulated that serve as the basis for making appropriate managerial decisions.

  7. Information exchange on HTGR and nuclear hydrogen technology between JAEA and INET in 2008

    International Nuclear Information System (INIS)

    Fujimoto, Nozomu; Tachibana, Yukio; Sun Yuliang

    2009-07-01

    The worldwide interests in the HTGR (High Temperature Gas-cooled Reactor) have been growing because the high temperature heat produced by the reactor can be utilized not only for efficient power generation but also for broad process heat applications, especially for thermo-chemical hydrogen production to fuel a prospective hydrogen economy in future. Presently only two HTGR reactors are operational in the world, including the HTTR (High Temperature Engineering Test Reactor) in Japan Atomic Energy Agency (JAEA) and the HTR-10 in the Institute of Nuclear and New Energy Technology (INET) of Tsinghua University in China. JAEA and INET have cooperated since 1986 in the field of HTGR development, particularly on the HTTR and HTR-10 projects. This report describes the cooperation activities on HTGR and nuclear hydrogen technology between JAEA and INET in 2008. (author)

  8. Information exchange on HTGR and nuclear hydrogen technology between JAEA and INET in 2009

    International Nuclear Information System (INIS)

    Fujimoto, Nozomu; Wang Hong

    2010-07-01

    The worldwide interests in the HTGR (High Temperature Gas-cooled Reactor) have been growing because the high temperature heat produced by the reactor can be utilized not only for efficient power generation but also for broad process heat applications, especially for thermo-chemical hydrogen production to fuel a prospective hydrogen economy in future. Presently only two HTGR reactors are operational in the world, including the HTTR (High Temperature Engineering Test Reactor) in Japan Atomic Energy Agency (JAEA) and the HTR-10 in the Institute of Nuclear and New Energy Technology (INET) of Tsinghua University in China. JAEA and INET have cooperated since 1986 in the field of HTGR development, particularly on the HTTR and HTR-10 projects. This report describes the cooperation activities on HTGR and nuclear hydrogen technology between JAEA and INET in 2009. (author)

  9. Using contemporary liquid chromatography theory and technology to improve capillary gradient ion-exchange separations.

    Science.gov (United States)

    Wouters, Bert; Broeckhoven, Ken; Wouters, Sam; Bruggink, Cees; Agroskin, Yury; Pohl, Christopher A; Eeltink, Sebastiaan

    2014-11-28

    The gradient-performance limits of capillary ion chromatography have been assessed at maximum system pressure (34.5 MPa) using capillary columns packed with 4.1 μm macroporous anion-exchange particles coated with 65 nm positively-charged nanobeads. In analogy to the van-Deemter curve, the gradient performance was assessed applying different flow rates, while decreasing the gradient time inversely proportional to the increase in flow rate in order to maintain the same retention properties. The gradient kinetic-performance limits were determined at maximum system pressure, applying tG/t0=5, 10, and 20. In addition, the effect of retention on peak width was assessed in gradient mode for mono-, di-, and trivalent inorganic anions. The peak width of late-eluting ions can be significantly reduced by using concave gradient, resulting in better detection sensitivity. A signal enhancement factor of 8 was measured for a late-eluting ion when applying a concave instead of a linear gradient. For the analysis of a complex anion mixture, a coupled column with a total length of 1.05 m was operated at the kinetic-performance limit applying a linear 250 min gradient (tG/t0=10). The peak capacity varied between 200 and 380 depending on analyte retention, and hence on charge and size of the ion. Copyright © 2014 Elsevier B.V. All rights reserved.

  10. Technology and Policy Challenges in the Adoption and Operation of Health Information Exchange Systems.

    Science.gov (United States)

    Ji, Hyerim; Yoo, Sooyoung; Heo, Eun-Young; Hwang, Hee; Kim, Jeong-Whun

    2017-10-01

    This study aimed to identify problems and issues that arise with the implementation of online health information exchange (HIE) systems in a medical environment and to identify solutions to facilitate the successful operation of future HIE systems in primary care clinics and hospitals. In this study, the issues that arose during the establishment and operation of an HIE system in a hospital were identified so that they could be addressed to enable the successful establishment and operation of a standard-based HIE system. After the issues were identified, they were reviewed and categorized by a group of experts that included medical information system experts, doctors, medical information standard experts, and HIE researchers. Then, solutions for the identified problems were derived based on the system development, operation, and improvement carried out during this work. Twenty-one issues were identified during the implementation and operation of an online HIE system. These issues were then divided into four categories: system architecture and standards, documents and data items, consent of HIE, and usability. We offer technical and policy recommendations for various stakeholders based on the experiences of operating and improving the online HIE system in the medical field. The issues and solutions identified in this study regarding the implementation and operate of an online HIE system can provide valuable insight for planners to enable them to successfully design and operate such systems at a national level in the future. In addition, policy support from governments is needed.

  11. Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology

    Science.gov (United States)

    Cornelius, Christopher J [Albuquerque, NM

    2006-04-04

    A new class of hybrid organic-inorganic materials, and methods of synthesis, that can be used as a proton exchange membrane in a direct methanol fuel cell. In contrast with Nafion.RTM. PEM materials, which have random sulfonation, the new class of materials have ordered sulfonation achieved through self-assembly of alternating polyimide segments of different molecular weights comprising, for example, highly sulfonated hydrophilic PDA-DASA polyimide segment alternating with an unsulfonated hydrophobic 6FDA-DAS polyimide segment. An inorganic phase, e.g., 0.5 5 wt % TEOS, can be incorporated in the sulfonated polyimide copolymer to further improve its properties. The new materials exhibit reduced swelling when exposed to water, increased thermal stability, and decreased O.sub.2 and H.sub.2 gas permeability, while retaining proton conductivities similar to Nafion.RTM.. These improved properties may allow direct methanol fuel cells to operate at higher temperatures and with higher efficiencies due to reduced methanol crossover.

  12. Proceedings of the workshop for exchange of technology for CWC inspections

    Energy Technology Data Exchange (ETDEWEB)

    McGuire, R.R.

    1993-04-01

    With the signing of the Chemical Weapons Convention (CWC), the work of the Preparatory Commission in defining the modalities of on-site verification inspections will begin early in 1993. One of the methods for increasing the effectiveness of inspections is the collection of samples for chemical analysis. The CWC allows for this analysis to be performed either at the site of the inspection or in a dedicated off-site laboratory. The decision as to where samples are to be analyzed in any specific instance may involve a consideration of the threat, real or perceived, to the compromise of legitimate sensitive host-party information. The ability to perform efficient chemical analysis at the inspection site, where samples remain in joint (host-inspector) custody and the analytical procedures can be observed by the host, can alleviate much of the concern over possible loss of confidential information in both government and industry. This workshop was designed to encourage the exchange of information among participants with experience in the use of analytical equipment for on-site sample collection and analysis. Individual projects are processed separately for the databases.

  13. Heat exchanger technologies for the global environment. PWR-Vol. 25

    International Nuclear Information System (INIS)

    Maurer, J.R.

    1994-01-01

    This is the Committee's largest compilation of papers in the fourteen years that ASME has sponsored one or more sessions at the Joint Power Generation Conference. In addition to the twenty-two papers offered at the conference, one session contained a panel discussion during which five industry specialists related their experiences and interpretations. Many of the presentations of the past few years have been made by authors from foreign lands as the conference has expanded to an international forum. This years' theme of global impact is included in the heat exchanger presentations from the USA and abroad. In addition, ASME has encouraged authors to make the subjects of their presentations more apropos to current concerns. New concepts and designs, particularly with PC programs in mind, is one specific area that is addressed. Other topics such as materials selection, coatings to extend performance life, minimizing the effects of microbiologically influenced corrosion, zebra mussel control and new approaches to heat transfer design are some of the subjects covered at the conference and in this volume. Nineteen papers have been processed separately for inclusion in the appropriate data bases

  14. U.S.-MEXICO TECHNOLOGY TRANSFER; BILATERAL TECHNICAL EXCHANGES FOR SUSTAINABLE ECONOMIC GROWTH IN THE BORDER REGION

    Energy Technology Data Exchange (ETDEWEB)

    Jimenez, Richard, D., Dr.

    2007-10-01

    The U.S. Department of Energy (DOE) maintains a strong commitment to transfer the results of its science and technology programs to the private sector. The intent is to apply innovative and sometimes advanced technologies to address needs while simultaneously stimulating new commercial business opportunities. Such focused “technology transfer” was evident in the late 1990s as the results of DOE investments in environmental management technology development led to new tools for characterizing and remediating contaminated sites as well as handling and minimizing the generation of hazardous wastes. The Department’s Office of Environmental Management was attempting to reduce the cost, accelerate the schedule, and improve the efficacy of clean-up efforts in the nuclear weapons complex. It recognized that resulting technologies had broader world market applications and that their commercialization would further reduce costs and facilitate deployment of improved technology at DOE sites. DOE’s Albuquerque Operations Office (now part of the National Nuclear Security Administration) began in 1995 to build the foundation for a technology exchange program with Mexico. Initial sponsorship for this work was provided by the Department’s Office of Environmental Management. As part of this effort, Applied Sciences Laboratory, Inc. (ASL) was contracted by the DOE Albuquerque office to identify Mexico’s priority environmental management needs, identify and evaluate DOE-sponsored technologies as potential solutions for those needs, and coordinate these opportunities with decision makers from Mexico’s federal government. That work led to an improved understanding of many key environmental challenges that Mexico faces and the many opportunities to apply DOE’s technologies to help resolve them. The above results constituted, in large part, the foundation for an initial DOE-funded program to apply the Department’s technology base to help address some of Mexico

  15. Technology assessment: Chlorine chemistry

    International Nuclear Information System (INIS)

    Wolff, H.; Alwast, H.; Buttgereit, R.

    1994-01-01

    Chlorine is not just one of many chemical feedstocks which is used in a few definitely harmful products like PVC or CFC but is irrelevant in all other respects. Just the opposite is true: There is hardly any product line of the chemical industry that can do without chlorine, from herbicides and pesticides to dyes, plastics, pharmaceuticals, photographic atricles, and cosmetics. Chlorine is not only a key element of chemical production but also an ubiquitous element of everyday life in civilisation. There are even many who would agree that the volume of chlorine production is an indicator of the competitive strength and national wealth of a modern society. By now, however, it has become evident that the unreflected use of chlorine is no longer ecologically acceptable. The consequences of a chlorine phase-out as compared to the continued chlorine production at the present level were investigated scientifically by a PROGNOS team. They are presented in this book. (orig.) [de

  16. Report on International Symposium for the Promotion of APEC Environmental Technology Exchange and Experts; APEC kankyogijutsu koryusokushin kokusai shinpojium jisshi hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The above event took place at Nagoya City, Japan, on December 5, 2000. Taken up were the response of developing nations to the problem of environmental protection, their needs for environmental technologies, examples of the transfer of environmental technologies carried out by Japan's environment related businesses or organizations, introduction of technologies Japan was able to present, and so forth. Introduced also were the current state and future outlook of such activities as the exchange of environmental technologies and business through the utilization of the virtual center for APEC (Asia-Pacific Economic Cooperation Conference) environmental technology exchange now in service, and so forth. At the symposium, a keynote address entitled Toward the Realization of Sustainable Society was delivered by Professor Yamamoto of the Institute of Industrial Science of the University of Tokyo. Panel discussions were held on the exchange of environmental technologies and business making use of the international network APEC-VC (virtual center) at Session 1, on some front-line cases of environmental technology transfer at Session 2, and on the transfer of technologies useful for developing nations as it ought to be at Session 3. (NEDO)

  17. Fundamentals of ion exchange

    International Nuclear Information System (INIS)

    Townsend, R.P.

    1993-01-01

    In this paper the fundamentals of ion exchange mechanisms and their thermodynamics are described. A range of ion exchange materials is considered and problems of communication and technology transfer between scientists working in the field are discussed. (UK)

  18. Green chemistry

    International Nuclear Information System (INIS)

    Warner, John C.; Cannon, Amy S.; Dye, Kevin M.

    2004-01-01

    A grand challenge facing government, industry, and academia in the relationship of our technological society to the environment is reinventing the use of materials. To address this challenge, collaboration from an interdisciplinary group of stakeholders will be necessary. Traditionally, the approach to risk management of materials and chemicals has been through inerventions intended to reduce exposure to materials that are hazardous to health and the environment. In 1990, the Pollution Prevention Act encouraged a new tact-elimination of hazards at the source. An emerging approach to this grand challenge seeks to embed the diverse set of environmental perspectives and interests in the everyday practice of the people most responsible for using and creating new materials--chemists. The approach, which has come to be known as Green Chemistry, intends to eliminate intrinsic hazard itself, rather than focusing on reducing risk by minimizing exposure. This chapter addresses the representation of downstream environmental stakeholder interests in the upstream everyday practice that is reinventing chemistry and its material inputs, products, and waste as described in the '12 Principles of Green Chemistry'

  19. Analytical Chemistry Division, annual report for the year 1973

    International Nuclear Information System (INIS)

    1974-01-01

    Research and development activities of the Analytical Chemistry Division of the Bhabha Atomic Research Centre, Bombay (India), for the year 1973 are reported. From the point of view of nuclear science and technology, the following are worth mentioning: (1) radiochemical analysis of mercury in marine products (2) rapid anion exchange separation and spectrophotometric determination of gadolinium in uranium dioxide-gadolinium oxide blend and (3) neutron activation analysis for forensic purpose. (M.G.B.)

  20. Bad chemistry

    OpenAIRE

    Petsko, Gregory A

    2004-01-01

    General chemistry courses haven't changed significantly in forty years. Because most basic chemistry students are premedical students, medical schools have enormous influence and could help us start all over again to create undergraduate chemistry education that works.

  1. Report on investigation in fiscal 2000 of industrial technology exchange with international networking organizations; 2000 nendo kokusaitekina network gata soshiki tono sangyo gijutsu koryu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With an objective to promote exchange of industrial technologies, investigations and analyses were made on identification of the current status of networking organizations in different countries working as windows for industrial technology exchange, and on the actual status of technology commercialization methods in overseas incubators. Activities were taken in the following three fields: 1) the current status of networking organizations and incubators in different countries, 2) typology of technology commercialization, technical fields, and success factors, and 3) possibility of the use of technology information in the networking organizations. In Item 1), investigations were performed on the current status and actual activity status of the networking organizations including research parks and individual incubators intended of information exchange, mainly in the United States, UK, and Finland. In Item 2), considerations are given on the points related to technology incubation based on the information about the networking organizations and incubators in each country, and the way the industry-academia cooperation should be. In Item 3), discussions were given on the roles of the networking organizations and the possibility of utilization of technological information in the networking organizations in Japan. (NEDO)

  2. Progress report, Chemistry and Materials Division, October 1 to December 31, 1975

    International Nuclear Information System (INIS)

    1976-01-01

    Interim research results are reported in solid state science (ion penetration, electron microscopy, radiation damage and metal physics, nuclear methods of analysis), general chemistry (analytical chemistry, hydrogen-water exchange, radioactivity measurements, electrochemistry), physical chemistry (radiation and isotope chemistry), materials science (surface chemistry and metal physics), and university research (deuterium exchange and zirconium alloy properties). (E.C.B.)

  3. Fiscal 1999 international engineer exchange project (Coal mining technology field). Overseas workshop (Australia); 1999 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Kaigai workshop (Goshu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This report summarizes the technology exchange with Australian coal mining engineers, the technical levels and needs on coal production, safety and environment in Australia, and the FS result on transfer of Japanese technologies, engineer exchange and joint research in a coal mining technology field. The overseas workshop (Australia) was held on Nov. 9, 1999 (Tues.) in Brisbane, Queensland. The Australia-Japan Technology Exchange Workshop on coal resources and coal mining technology includes 5 sessions (keynote address, trends and issues of coal resource development, coal resources and production technology, coal resources and safety technology, coal resources and environmental problems), and the open forum discussion on innovative technologies for coal mining. 6 Japanese specialists and 11 Australian specialists read papers. After the workshop, the participants visited Liddell Mine in New South Wales to master natural conditions, and production and safety technology levels of Australian coal mines, and to exchange various information with Australian coal mining engineers. (NEDO)

  4. 现代信息技术在无机化学实验中的应用%The Application of Modern Information Technology in Inorganic Chemistry Experiment

    Institute of Scientific and Technical Information of China (English)

    张海蓉

    2012-01-01

    传统的无机化学实验的教学模式已不能适应当代大学生的需要,为充分发挥无机实验教学在化学专业课程教学中的基础作用,培养适应社会需求的"创新型"、"应用型"人才,本文探讨了现代信息技术在无机化学实验教学上的应用,研究了多媒体技术和网络资源在无机化学实验教学中的应用。%The traditional teaching mode of Inorganic Chemistry Experiment can't meet the needs of university students.In order to make full use of the basic function of Inorganic Chemistry Experiment teaching in chemical professional teaching,and train innovative and practical talents,whom the social needs,the application of the modern information technology including multimedia technology and cyber source in teaching of Inorganic Chemistry Experiment were studied.

  5. Diffusion bonding in compact heat exchangers

    International Nuclear Information System (INIS)

    Southall, David

    2009-01-01

    Heatric's diffusion bonding process is a solid-state joining technology that produces strong, compact, all-metal heat exchanger cores. Diffusion bonding allows for a large quantity of joints to be made in geometries that would normally be inaccessible for conventional welding techniques. Since Heatric's diffusion bonding process uses no interlayer or braze alloy, the resulting heat exchanger core has consistent chemistry throughout and, under carefully controlled conditions, a return to parent metal strength can be reached. This paper will provide an overview of the diffusion bonding process and its origins, and also its application to compact heat exchanger construction. The paper will then discuss recent work that has been done to compare mechanical properties of Heatric's diffusion bonded material with material that has been conventionally welded, as well as with material tested in the as-received condition. (author)

  6. Computational Material Modeling of Hydrated Cement Paste Calcium Silicate Hydrate (C-S-H) Chemistry Structure - Influence of Magnesium Exchange on Mechanical Stiffness: C-S-H Jennite

    Science.gov (United States)

    2015-04-27

    MODELING OF C-S-H Material chemistry level modeling following the principles and techniques commonly grouped under Computational Material Science is...Henmi, C. and Kusachi, I. Monoclinic tobermorite from fuka, bitchu-cho, Okoyama Perfecture. Japan J. Min. Petr. Econ . Geol. (1989)84:374-379. [22...31] Liu, Y. et al. First principles study of the stability and mechanical properties of MC (M=Ti, V, Zr, Nb, Hf and Ta) compounds. Journal of Alloys and Compounds. (2014) 582:500-504. 10

  7. Complex chemistry

    International Nuclear Information System (INIS)

    Kim, Bong Gon; Kim, Jae Sang; Kim, Jin Eun; Lee, Boo Yeon

    2006-06-01

    This book introduces complex chemistry with ten chapters, which include development of complex chemistry on history coordination theory and Warner's coordination theory and new development of complex chemistry, nomenclature on complex with conception and define, chemical formula on coordination compound, symbol of stereochemistry, stereo structure and isomerism, electron structure and bond theory on complex, structure of complex like NMR and XAFS, balance and reaction on solution, an organo-metallic chemistry, biology inorganic chemistry, material chemistry of complex, design of complex and calculation chemistry.

  8. Conference 'Chemistry of hydrides' Proceedings

    International Nuclear Information System (INIS)

    1991-07-01

    This collection of thesis of conference of Chemistry hydrides presents the results of investigations concerning of base questions of chemistry of nonorganic hydrides, including synthesis questions, studying of physical and chemical properties, thermodynamics, analytical chemistry, investigation of structure, equilibriums in the systems of metal-hydrogen, behaviour of nonorganic hydrides in non-water mediums and applying investigations in the chemistry area and technology of nonorganic hydrides

  9. MEXICO loop provides essential technology for MYRRHA. SCK•CEN investigates the chemistry of lead-bismuth

    International Nuclear Information System (INIS)

    2014-01-01

    In the MYRRHA facility, Lead-Bismuth Eutectic (LBE) alloy will act as the primary coolant. There are different experimental lead-bismuth loops in the world. Most have been designed to study steel corrosion in LBE or the thermohydraulics of LBE. The article discusses the MEXICO test loop, which has been developed by SCK-CEN to investigate the chemistry of leadbismuth.

  10. Mathematical Chemistry

    OpenAIRE

    Trinajstić, Nenad; Gutman, Ivan

    2002-01-01

    A brief description is given of the historical development of mathematics and chemistry. A path leading to the meeting of these two sciences is described. An attempt is made to define mathematical chemistry, and journals containing the term mathematical chemistry in their titles are noted. In conclusion, the statement is made that although chemistry is an experimental science aimed at preparing new compounds and materials, mathematics is very useful in chemistry, among other things, to produc...

  11. Project to promote the development of global environmental industry technology. Feasibility study of research exchanges; Chikyu kankyo sangyo gijutsu kaihatsu suishin jigyo. Kenkyu koryu kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    In fiscal 1995, three teams were organized to study the following subjects: plant genetic and cellular engineering in relation to drought stress; simulation models of global environment for accurate assessment and prediction; the APEC Virtual Center for environmental technology exchange. The team studying plant genetic and cellular engineering in relation to drought stress visited the Department of Botany, Hebrew University of Jerusalem, Israel, the Jacob Blaustein Institute for Desert Research, Ben-Grunion University, Israel, the Department of Biochemistry and the Office of Arid Lands Studies, Arizona University, the U.S. to survey the present and future trend of the study and feasibility of research exchanges. The team studying simulation models of global environment for accurate assessment and prediction visited Yale University, Massachusetts Institute of Technology, Electric Power Research Institute, and Battle Research Institute in the U.S. to survey feasibility of research exchanges. The team studying the APEC Virtual Center for environmental technology exchange visited institutes in ASEAN countries to survey needs for the Virtual Center. 312 refs., 74 figs., 17 tabs.

  12. Progress in liquid ion exchangers

    International Nuclear Information System (INIS)

    Nakagawa, Genkichi

    1974-01-01

    Review is made on the extraction with anion exchangers and the extraction with liquid cation exchangers. On the former, explanation is made on the extraction of acids, the relation between anion exchange and the extraction of metals, the composition of the metallic complexes that are extracted, and the application of the extraction with anion exchangers to analytical chemistry. On the latter, explanation is made on the extraction of metals and its application to analytical chemistry. The extraction with liquid ion exchangers is suitable for the operation in chromatography, because the distribution of extracting agents into aqueous phase is small, and extraction equilibrium is quickly reached, usually within 1 to several minutes. The separation by means of anion exchangers is usually made from hydrochloric acid solution. For example, Brinkman et al. determined Rf values for more than 50 elements by thin layer chromatography. Tables are given for showing the structure of the liquid ion exchangers and the polymerized state of various amines. (Mori, K.)

  13. Promotion project to develop the global environment related industrial technology. Investigation on the possibility of research exchange; Chikyu kankyo sangyo gijutsu kaihatsu suishin jigyo. Kenkyu koryu kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    Through visits to US universities and research institutes, investigation was made on the trend of global environment-related research and possibility of their exchanging the result of research with the RITE (Research Institute of Innovative Technology for the Earth). To investigate the process technology to utilize microbes harmoniously with the environment, the visit was paid to Cornell University, Battelle Memorial Institute and Risk Reduction Engineering Laboratory, where the investigation was made on the environmental bioremediation with microbial functions and clean process production without by-producing substances to load the environment. To investigate the technical measures against the global warming, the visit was paid to Brookhaven National Laboratory, Massachusetts Institute of Technology, California University, Hawaii University and Pacific International Center for High Technology Research, where the investigation was made, through discussion and exchange of research information and opinion with researchers and engineers, on the possibility of their exchanging the result of research with the RITE. Judging from the investigation of this time, the research which is mutually complementary between Japan and USA is easy to promote, because their respective advanced fields do not overlap with each other. 88 refs., 11 figs., 6 tabs.

  14. Chemistry Notes

    Science.gov (United States)

    School Science Review, 1976

    1976-01-01

    Described are eight chemistry experiments and demonstrations applicable to introductory chemistry courses. Activities include: measure of lattice enthalpy, Le Chatelier's principle, decarboxylation of soap, use of pocket calculators in pH measurement, and making nylon. (SL)

  15. Chemistry Dashboard

    Science.gov (United States)

    The Chemistry Dashboard is part of a suite of dashboards developed by EPA to help evaluate the safety of chemicals. The Chemistry Dashboard provides access to a variety of information on over 700,000 chemicals currently in use.

  16. Combinatorial chemistry

    DEFF Research Database (Denmark)

    Nielsen, John

    1994-01-01

    An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds.......An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds....

  17. Aquatic Chemistry

    International Nuclear Information System (INIS)

    Kim, Dong Yeun; Kim, Oh Sik; Kim, Chang Guk; Park, Cheong Gil; Lee, Gwi Hyeon; Lee, Cheol Hui

    1987-07-01

    This book deals aquatic chemistry, which treats water and environment, chemical kinetics, chemical balance like dynamical characteristic, and thermodynamics, acid-base chemistry such as summary, definition, kinetics, and PH design for mixture of acid-base chemistry, complex chemistry with definition, and kinetics, precipitation and dissolution on summary, kinetics of precipitation and dissolution, and balance design oxidation and resolution with summary, balance of oxidation and resolution.

  18. Positronium chemistry

    CERN Document Server

    Green, James

    1964-01-01

    Positronium Chemistry focuses on the methodologies, reactions, processes, and transformations involved in positronium chemistry. The publication first offers information on positrons and positronium and experimental methods, including mesonic atoms, angular correlation measurements, annihilation spectra, and statistical errors in delayed coincidence measurements. The text then ponders on positrons in gases and solids. The manuscript takes a look at the theoretical chemistry of positronium and positronium chemistry in gases. Topics include quenching, annihilation spectrum, delayed coincidence

  19. Dictionary of heat exchanger technology. English-German, German-English. Woerterbuch der Waermeaustauschertechnik. Englisch-Deutsch, Deutsch-Englisch

    Energy Technology Data Exchange (ETDEWEB)

    Schmitz, H P [comp.

    1989-01-01

    This dictionary contains more than 6,000 terms and numerous explanations and comprises all types of shell-and-tube and tubular heat exchangers including condensers, feedwater heaters, air heaters, evaporators, vaporizers, steam generators, steam boilers as well as plate-and-frame heat exchangers, cooling towers, and special designs, and the related technical fields such as thermal and mass transfer, thermodynamics, fluids engineering, and strength calculation. Part 1 contains the English-German version, Part 2 the German-English version and Annex 1 the figures for explaining the most important heat exchanger designs. (orig.).

  20. Forensic Chemistry

    Science.gov (United States)

    Bell, Suzanne

    2009-07-01

    Forensic chemistry is unique among chemical sciences in that its research, practice, and presentation must meet the needs of both the scientific and the legal communities. As such, forensic chemistry research is applied and derivative by nature and design, and it emphasizes metrology (the science of measurement) and validation. Forensic chemistry has moved away from its analytical roots and is incorporating a broader spectrum of chemical sciences. Existing forensic practices are being revisited as the purview of forensic chemistry extends outward from drug analysis and toxicology into such diverse areas as combustion chemistry, materials science, and pattern evidence.

  1. Peer exchange May 3-5, 2016 : Alaska Department of Transportation and Public Facilities : research development & technology transfer.

    Science.gov (United States)

    2016-01-01

    Members of the Peer Exchange Team identified actions Alaska should consider to : improve effectiveness of the research program: : 1. Conduct Research Strategic Visioning Workshop with Staff and Research : Advisory Board in Fall, 2016 : 2. Develop a T...

  2. Report on a survey in fiscal 1999. Survey on research exchange possibility; 1999 nendo kenkyu koryu kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This survey deals with research institutions of governmental organizations, universities, and business entities for the purpose of discussing the possibility of research exchange standing on a long-term point of view to serve for solving global environment problems, and the way the exchange should be. The research exchange shall cover the areas of trends in research and development of global environment related technologies, themes for the research and development, institutions for the research and development, and exchange of researchers and information with these research organizations. In fiscal 1999, three survey missions were dispatched to cover the following three areas: (1) surveys on research possibility of catalyst development by means of combinatorial chemistry, (2) surveys on research exchange possibility for thermo-chemical solar hybrid fuel production technologies, and (3) surveys on research exchange possibility for structuring function improving technologies of the 21st century type. Each survey mission has visited research institutions of the world to survey the trends in researches related to global environment, and the possibility of exchanging researches with RITE. The visits presented the following conclusions and findings: (1) the research on the combinatorial chemistry in the U.S.A. is still in the initial stage; (2) important findings were obtained when surveys were made on methane reformation utilizing solar heat, and coal gasification technologies in Europe; and (3) surveys were made on pioneering researches on plant molecule physiology in Europe. (NEDO)

  3. Ion exchange phenomena

    Energy Technology Data Exchange (ETDEWEB)

    Bourg, I.C.; Sposito, G.

    2011-05-01

    Ion exchange phenomena involve the population of readily exchangeable ions, the subset of adsorbed solutes that balance the intrinsic surface charge and can be readily replaced by major background electrolyte ions (Sposito, 2008). These phenomena have occupied a central place in soil chemistry research since Way (1850) first showed that potassium uptake by soils resulted in the release of an equal quantity of moles of charge of calcium and magnesium. Ion exchange phenomena are now routinely modeled in studies of soil formation (White et al., 2005), soil reclamation (Kopittke et al., 2006), soil fertilitization (Agbenin and Yakubu, 2006), colloidal dispersion/flocculation (Charlet and Tournassat, 2005), the mechanics of argillaceous media (Gajo and Loret, 2007), aquitard pore water chemistry (Tournassat et al., 2008), and groundwater (Timms and Hendry, 2007; McNab et al., 2009) and contaminant hydrology (Chatterjee et al., 2008; van Oploo et al., 2008; Serrano et al., 2009).

  4. Proceeding of the Scientific Meeting and Presentation on Basic Research in Nuclear Science and Technology part II : Nuclear Chemistry, Process Technology, Radioactive Waste Management and Environment

    International Nuclear Information System (INIS)

    Sukarsono, R.; Ganang Suradjijo

    2002-01-01

    Scientific Meeting and Presentation on Basic Research in Nuclear Science and Technology is a routine activity held by Centre for Research and Development of Advanced Technology, National Nuclear Energy Agency, for monitoring the research activity which achieved in National Nuclear Energy Agency. This proceedings contains a proposal about basic research in nuclear technology which has environment. This proceedings is the second part of the two parts which published in series. There are 57 articles which have separated index. (PPIN)

  5. Scientific Information Analysis of Chemistry Dissertations Using Thesaurus of Chemistry

    Directory of Open Access Journals (Sweden)

    Taghi Rajabi

    2017-09-01

    Full Text Available : Concept maps of chemistry can be obtained from thesaurus of chemistry. Analysis of information in the field of chemistry is done at graduate level, based on comparing and analyzing chemistry dissertations by using these maps. Therefore, the use of thesaurus for analyzing scientific information is recommended. Major advantage of using this method, is that it is possible to obtain a detailed map of all academic researches across all branches of science. The researches analysis results in chemical science can play a key role in developing strategic research policies, educational programming, linking universities to industries and postgraduate educational programming. This paper will first introduce the concept maps of chemistry. Then, emerging patterns from the concept maps of chemistry will be used to analyze the trend in the academic dissertations in chemistry, using the data collected and stored in our database at Iranian Research Institute for Information Science and Technology (IranDoc over the past 10 years (1998-2009.

  6. Understanding of the structure activity relationship of PtPd bimetallic catalysts prepared by surface organometallic chemistry and ion exchange during the reaction of iso-butane with hydrogen

    KAUST Repository

    Al-Shareef, Reem A.; Harb, Moussab; Saih, Youssef; Ould-Chikh, Samy; Roldan, Manuel A.; Anjum, Dalaver H.; Guyonnet, Elodie Bile; Candy, Jean-Pierre; Jan, Deng-Yang; Abdo, Suheil F.; Aguilar-Tapia, Antonio; Proux, Olivier; Hazemann, Jean-Louis; Basset, Jean-Marie

    2018-01-01

    Well-defined silica supported bimetallic catalysts Pt100-x Pdx were prepared by Surface Organometallic Chemistry (SOMC) and Ionic-Exchange (IE) methods. For all investigated catalysts, iso-butane reaction with hydrogen under differential conditions led to the formation of methane and propane, n-butane, and traces of iso-butylene. The total reaction rate decreased with increasing the Pd loading for both catalysts series as a result of decreasing turnover rate of both isomerization and hydrogenolysis. In the case of Pt100-x Pdx(SOMC) catalysts, the experimental results in combination with DFT calculations suggested a selective coverage of Pt (1 0 0) surface by agglomerated Pd atoms like “islands”, assuming that each metal roughly keeps its intrinsic catalytic properties with relatively small electron transfer from Pt to Pd in the case of Pt-rich sample and from Pd to Pt in the case of Pd-rich sample. For the PtPd catalysts prepared by IE, the catalytic behavior could be explained by the formation of a surface alloy between Pt and Pd in the case of Pd-rich sample and by the segregation of a small amount of Pd on the surface in the case of Pt-rich sample, as demonstrated by TEM, EXAFS and DFT. The catalytic results were explained by a structure activity relationship based on the proposed mechanism of CH bond and CC bond activation and cleavage for iso-butane hydrogenolysis, isomerization, cracking and dehydrogenation.

  7. Understanding of the structure activity relationship of PtPd bimetallic catalysts prepared by surface organometallic chemistry and ion exchange during the reaction of iso-butane with hydrogen

    KAUST Repository

    Alshareef, Reem Abdul aziz Hamed

    2018-04-25

    Well-defined silica supported bimetallic catalysts Pt100-x Pdx were prepared by Surface Organometallic Chemistry (SOMC) and Ionic-Exchange (IE) methods. For all investigated catalysts, iso-butane reaction with hydrogen under differential conditions led to the formation of methane and propane, n-butane, and traces of iso-butylene. The total reaction rate decreased with increasing the Pd loading for both catalysts series as a result of decreasing turnover rate of both isomerization and hydrogenolysis. In the case of Pt100-x Pdx(SOMC) catalysts, the experimental results in combination with DFT calculations suggested a selective coverage of Pt (1 0 0) surface by agglomerated Pd atoms like “islands”, assuming that each metal roughly keeps its intrinsic catalytic properties with relatively small electron transfer from Pt to Pd in the case of Pt-rich sample and from Pd to Pt in the case of Pd-rich sample. For the PtPd catalysts prepared by IE, the catalytic behavior could be explained by the formation of a surface alloy between Pt and Pd in the case of Pd-rich sample and by the segregation of a small amount of Pd on the surface in the case of Pt-rich sample, as demonstrated by TEM, EXAFS and DFT. The catalytic results were explained by a structure activity relationship based on the proposed mechanism of CH bond and CC bond activation and cleavage for iso-butane hydrogenolysis, isomerization, cracking and dehydrogenation.

  8. Characterization of sodium stibogluconate by online liquid separation cell technology monitored by ICPMS and ESMS and computational chemistry

    DEFF Research Database (Denmark)

    Hansen, Helle Rusz; Hansen, Claus; Kepp, Kasper Planeta

    2008-01-01

    High-performance liquid chromatography (HPLC), mass spectrometry (MS), and computational chemistry has been applied to resolve the composition and structure of the Sb species present in dilutions of Pentostam, a first-line treatment drug against Leishmania parasites. Using HPLC-inductively coupled......(V)-glyconate complexes of various stoichiometry (1:1, 1:2, 1:3, 2:2, 2:3, 2:4, 3:3, 3:4). The 1:1 complex became the most abundant low molecular mass Sb(V) complex with dilution time. A novel mixed-mode chromatographic system was applied in order to separate complexes of various stoichiometry and isomers. Density...

  9. Ten key issues in modern flow chemistry.

    Science.gov (United States)

    Wegner, Jens; Ceylan, Sascha; Kirschning, Andreas

    2011-04-28

    Ten essentials of synthesis in the flow mode, a new enabling technology in organic chemistry, are highlighted as flashlighted providing an insight into current and future issues and developments in this field. © The Royal Society of Chemistry 2011

  10. Present address of cutting-edge chemistry in Korea

    International Nuclear Information System (INIS)

    2007-01-01

    This introduces the research center, company and chemistry department with excellent results. This book lists the name of those, which are organic molecule design laboratory by Sunmun university, intelligence Nano technology research center by Biotechnology, Ewha university, Nano chemistry laboratory by Department of chemistry, Yonsei university, science education research center by Haying university, solid chemistry laboratory by Department of Nano science, Ewha university, the center of innovation of chemistry industry with R and D by LG chemistry, Korea Research Institute of Chemical Technology, Department of Chemistry, Sogang university, Department of Chemistry, Busan university and Department of Chemistry, Dankook university.

  11. Organic chemistry

    International Nuclear Information System (INIS)

    2003-08-01

    This book with sixteen chapter explains organic chemistry on linkage isomerism such as alkane, cycloalkane, alkene, aromatic compounds, stereo selective isomerization, aromatic compounds, stereo selective isomerization, organic compounds, stereo selective isomerization, organic halogen compound, alcohol, ether, aldehyde and ketone, carboxylic acid, dicarboxylic acid, fat and detergent, amino, carbohydrate, amino acid and protein, nucleotide and nucleic acid and spectroscopy, a polymer and medical chemistry. Each chapter has introduction structure and characteristic and using of organic chemistry.

  12. Radiation chemistry

    Energy Technology Data Exchange (ETDEWEB)

    None

    1973-07-01

    Research progress is reported on radiation chemistry of heavy elements that includes the following topics: radiation chemistry of plutonium in nitric acid solutions (spectrophotometric analysis and gamma radiolysis of Pu(IV) and Pu(VI) in nitric acid solution); EPR studies of intermediates formed in radiolytic reactions with aqueous medium; two-phase radiolysis and its effect on the distribution coefficient of plutonium; and radiation chemistry of nitric acid. (DHM)

  13. Chinese Commission of Science Technology and Industry for National Defense Senior Vice Minister CHEN Qiufa exchanging gifts at luncheon and signing the Guest Book on 1st November 2007 with CERN Director-General R. Aymar.

    CERN Multimedia

    Maximilien Brice

    2007-01-01

    Chinese Commission of Science Technology and Industry for National Defense Senior Vice Minister CHEN Qiufa exchanging gifts at luncheon and signing the Guest Book on 1st November 2007 with CERN Director-General R. Aymar.

  14. Technetium chemistry

    International Nuclear Information System (INIS)

    Burns, C.; Bryan, J.; Cotton, F.; Ott, K.; Kubas, G.; Haefner, S.; Barrera, J.; Hall, K.; Burrell, A.

    1996-01-01

    Technetium chemistry is a young and developing field. Despite the limited knowledge of its chemistry, technetium is the workhorse for nuclear medicine. Technetium is also a significant environmental concern because it is formed as a byproduct of nuclear weapons production and fission-power generators. Development of new technetium radio-pharmaceuticals and effective environmental control depends strongly upon knowledge of basic technetium chemistry. The authors performed research into the basic coordination and organometallic chemistry of technetium and used this knowledge to address nuclear medicine and environmental applications. This is the final report of a three-year Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL)

  15. Development of long-lived radionuclide partitioning technology - Preparation of ion exchanges for selective separation of radioactive elements

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Si Joong; Jeong, Hae In; Shim, Min Sook [Korea University, Seoul (Korea, Republic of); Kim, Jeong [Seonam University, Namwon (Korea, Republic of)

    1995-07-01

    Ion exchanger contained nitrogen-oxygen donor macrocyclic units was synthesized, and immobilization process was carried out by adsorption of the exchanger to silica gel. The binding constants were measured with acid concentration. From the binding constants, selectivity for Pt(II) ion and acid concentration of eluents were determined. The most optimum conditions for the separation were also determined from investigating the effects of amount of immobile phase and column length. And liarit aza-crown ethers were synthesized and selectively separated Cs/Sr ion from mixed metal solution. 37= refs., 24 tabs., 40 figs. (author)

  16. Green” Technology and Ecologically Unequal Exchange: The Environmental and Social Consequences of Ecological Modernization in the World-System

    Directory of Open Access Journals (Sweden)

    Eric Bonds

    2015-08-01

    Full Text Available This paper contributes to understandings of ecologically unequal exchange within the world-systems perspective by offering a series of case studies of ecological modernization in the automobile industry. The case studies demonstrate that “green” technologies developed and instituted in core nations often require specific raw materials that are extracted from the periphery and semi-periphery. Extraction of such natural resources causes significant environmental degradation and often displaces entire communities from their land. Moreover, because states often use violence and repression to facilitate raw material extraction, the widespread commercialization of “green” technologies can result in serious human rights violations. These findings challenge ecological modernization theory, which rests on the assumption that the development and commercialization of more ecologically-efficient technologies is universally beneficial.

  17. Assessment of information needs: Production phase of the petroleum industry for an evaluaton of International Energy Agency Energy Technology Data Exchange

    Energy Technology Data Exchange (ETDEWEB)

    Linville, B.

    1989-09-01

    This survey was conducted to determine needs of the petroleum industry for information and data on petroleum production technology, including subjects of most interest and most difficult to obtain, and sources being used to acquire such information. Results of the survey will be used in evaluating the Energy Technology Data Exchange and Department of Energy common data base. A selected sample of world petroleum production specialists and petroleum information specialists and other related personnel were surveyed to learn about their problems in retrieving information and data on petroleum production. They were asked what topics and kinds of information are of current interest, what sources they are using to help resolve their technological problems, what petroleum-producing countries are of interest to them, and other related questions.

  18. 1995 national heat transfer conference: Proceedings. Volume 12: Falling films; Fundamentals of subcooled flow boiling; Compact heat exchanger technology for the process industry; HTD-Volume 314

    International Nuclear Information System (INIS)

    Sernas, V.; Boyd, R.D.; Jensen, M.K.

    1995-01-01

    The papers in the first section cover falling films and heat transfer. Papers in the second section address issues associated with heat exchangers, such as: plate-and-frame heat exchanger technology; thermal design issues; condensation; and single-phase flows. The papers in the third section deal with studies related to: the turbulent velocity field in a vertical annulus; the effects of curvature and a dissolved noncondensable gas on nucleate boiling heat transfer; the effects of flow obstruction on the onset of a Ledinegg-type flow instability; pool boiling from a large-diameter tube; and two-dimensional wall temperature distributions and convection in a single-sided heated vertical tube. Separate abstracts were prepared for most papers in this volume

  19. Catalysis and sustainable (green) chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Centi, Gabriele; Perathoner, Siglinda [Dipartimento di Chimica Industriale ed Ingegneria dei Materiali, University of Messina, Salita Sperone 31, 98166 Messina (Italy)

    2003-01-15

    Catalysis is a key technology to achieve the objectives of sustainable (green) chemistry. After introducing the concepts of sustainable (green) chemistry and a brief assessment of new sustainable chemical technologies, the relationship between catalysis and sustainable (green) chemistry is discussed and illustrated via an analysis of some selected and relevant examples. Emphasis is also given to the concept of catalytic technologies for scaling-down chemical processes, in order to develop sustainable production processes which reduce the impact on the environment to an acceptable level that allows self-depuration processes of the living environment.

  20. Chemistry in water reactors

    International Nuclear Information System (INIS)

    Hermansson, H.P.; Norring, K.

    1994-01-01

    The international conference Chemistry in Water Reactors was arranged in Nice 24-27/04/1994 by the French Nuclear Energy Society. Examples of technical program areas were primary chemistry, operational experience, fundamental studies and new technology. Furthermore there were sessions about radiation field build-up, hydrogen chemistry, electro-chemistry, condensate polishing, decontamination and chemical cleaning. The conference gave the impression that there are some areas that are going to be more important than others during the next few years to come. Cladding integrity: Professor Ishigure from Japan emphasized that cladding integrity is a subject of great concern, especially with respect to waterside corrosion, deposition and release of crud. Chemistry control: The control of the iron/nickel concentration quotient seems to be not as important as previously considered. The future operation of a nuclear power plant is going to require a better control of the water chemistry than achievable today. One example of this is solubility control via regulation in BWR. Trends in USA: means an increasing use of hydrogen, minimization of SCC/IASCC, minimization of radiation fields by thorough chemistry control, guarding fuel integrity by minimization of cladding corrosion and minimization of flow assisted corrosion. Stellite replacement: The search for replacement materials will continue. Secondary side crevice chemistry: Modeling and practical studies are required to increase knowledge about the crevice chemistry and how it develops under plant operation conditions. Inhibitors: Inhibitors for IGSCC and IGA as well for the primary- (zinc) as for the secondary side (Ti) should be studied. The effects and mode of operation of the inhibitors should be documented. Chemical cleaning: of heat transfer surfaces will be an important subject. Prophylactic cleaning at regular intervals could be one mode of operation

  1. Outlook for ion exchange

    International Nuclear Information System (INIS)

    Kunin, R.

    1977-01-01

    This paper presents the history and theory of ion exchange technology and discusses the usefulness of ion exchange resins which found broad applications in chemical operations. It is demonstrated that the theory of ion exchange technology seems to be moving away from the physical chemist back to the polymer chemist where it started originally. This but confronted the polymer chemists with some knotty problems. It is pointed out that one has still to learn how to use ion exchange materials as efficiently as possible in terms of the waste load that is being pumped into the environment. It is interesting to note that, whereas ion exchange is used for abating pollution, it is also a polluter. One must learn how to use ion exchange as an antipollution device, and at the same time minimize its polluting properties

  2. Density functional theory in quantum chemistry

    CERN Document Server

    Tsuneda, Takao

    2014-01-01

    This book examines density functional theory based on the foundation of quantum chemistry. Unconventional in approach, it reviews basic concepts, then describes the physical meanings of state-of-the-art exchange-correlation functionals and their corrections.

  3. The utilization of uranium industry technology and relevant chemistry to leach uranium from mixed-waste solids

    International Nuclear Information System (INIS)

    Mattus, A.J.; Farr, L.L.

    1991-01-01

    Methods for the chemical extraction of uranium from a number of refractory uranium-containing minerals found in nature have been in place and employed by the uranium mining and milling industry for nearly half a century. These same methods, in conjunction with the principles of relevant uranium chemistry, have been employed at the Oak Ridge National Laboratory (ORNL) to chemically leach depleted uranium from mixed-waste sludge and soil. The removal of uranium from what is now classified as mixed waste may result in the reclassification of the waste as hazardous, which may then be delisted. The delisted waste might eventually be disposed of in commercial landfill sites. This paper generally discusses the application of chemical extractive methods to remove depleted uranium from a biodenitrification sludge and a storm sewer soil sediment from the Y-12 weapons plant in Oak Ridge. Some select data obtained from scoping leach tests on these materials are presented along with associated limitations and observations which might be useful to others performing such test work. 6 refs., 2 tabs

  4. The utilization of uranium industry technology and relevant chemistry to leach uranium from mixed-waste solids

    Energy Technology Data Exchange (ETDEWEB)

    Mattus, A.J.; Farr, L.L.

    1991-01-01

    Methods for the chemical extraction of uranium from a number of refractory uranium-containing minerals found in nature have been in place and employed by the uranium mining and milling industry for nearly half a century. These same methods, in conjunction with the principles of relevant uranium chemistry, have been employed at the Oak Ridge National Laboratory (ORNL) to chemically leach depleted uranium from mixed-waste sludge and soil. The removal of uranium from what is now classified as mixed waste may result in the reclassification of the waste as hazardous, which may then be delisted. The delisted waste might eventually be disposed of in commercial landfill sites. This paper generally discusses the application of chemical extractive methods to remove depleted uranium from a biodenitrification sludge and a storm sewer soil sediment from the Y-12 weapons plant in Oak Ridge. Some select data obtained from scoping leach tests on these materials are presented along with associated limitations and observations which might be useful to others performing such test work. 6 refs., 2 tabs.

  5. Data processing technologies and diagnostics for water chemistry and corrosion control in nuclear power plants (DAWAC). Report of a coordinated research project 2001-2005

    International Nuclear Information System (INIS)

    2006-06-01

    This publication provides information on the current status and development trends in monitoring, diagnostics and control of water chemistry and corrosion of core and primary circuit materials in water cooled power reactors. It summarizes the results of an IAEA Coordinated Research Project and focuses on the methods for development, qualification and implementation of water chemistry expert systems at nuclear power plants. These systems are needed to have full benefit from using on-line sensors in real time mode when sensor signals, and other chemistry and operational data, are collected and continuously analysed with data acquisition and evaluation software. Technical knowledge was acquired in water chemistry control techniques (grab sampling, on-line monitoring, data collecting and processing, etc), plant chemistry and corrosion diagnostics, plant monitoring (corrosion, chemistry, activity) and plant chemistry improvement (analytical models and practices). This publication covers contributions from leading experts in water chemistry/corrosion, representing organizations from 16 countries with the largest nuclear capacities

  6. Augmentative and Alternative Communication in Autism: A Comparison of the Picture Exchange Communication System and Speech-Output Technology

    Science.gov (United States)

    Boesch, Miriam Chacon

    2011-01-01

    The purpose of this comparative efficacy study was to investigate the Picture Exchange Communication System (PECS) and a speech-generating device (SGD) in developing requesting skills, social-communicative behavior, and speech for three elementary-age children with severe autism and little to no functional speech. Requesting was selected as the…

  7. A Framework for Evaluating Science and Technology Electronic Reference Books: A Comparison of Five Platforms in Chemistry

    Science.gov (United States)

    Lafferty, Meghan

    2009-01-01

    This article examines what is desirable in online reference books in science and technology and outlines a framework for evaluating their interfaces. The framework considers factors unique to these subject areas like chemical structures and numerical data. Criteria in three categories, navigability, searchability, and results, were applied to five…

  8. Some progress on radiation chemistry of substances of biological interests and biological applications of radiation technology in China

    International Nuclear Information System (INIS)

    Wu Jilan; Fang Xingwang

    1995-01-01

    Studies in China on the detection method of irradiated food, mechanism of DNA damage induced by peroxidation, radiolysis of natural products and herbs are reviewed on the update open literature, and some progress on applications of radiation technology is summarized. (author)

  9. Research on XML-based Application Layer Data Exchange Technology%基于XML的应用层数据交换技术的研究

    Institute of Scientific and Technical Information of China (English)

    尹建璋

    2009-01-01

    目前,许多企业已着力建立各种计算机应用以助于商业运营.虽然这带来了效率的显著提高,但它并没有扩展到企业外部的业务.这些业务涵盖不同公司企业应用或商业运营的交换和交流.很多情况下企业与它们的商业伙伴、供货商和客户存在信息孤岛.企业间以及它们与其商业伙伴间的交流仍旧是依赖人工处理,因此效率很低.电子数据交换(EDI)被认为是这一问题的解决方案,而应用层数据交换技术是该方案的重中之重,因此,本文主要对电子数据交换技术中的XML应用层数据交换技术进行研究.%At present, many enterprises have been efforts to establish a variety of computer applications in order to help business operators. While that has had a significant improvement in the efficiency, but it does not extend to companies outside the business. These businesses cover a variety of companies applications or business operations of the exchange and communication. Many cases, enterprises and their business partners, suppliers and customers there are islands of information. Between enterprises and their business partners and their exchanges are still dependent on manual processing, so efficiency is very low. Electronic Data Interchange (EDI) is considered to be the solution to this problem, and the application layer data exchange technology is the top priority of the program, this paper studies the electronic data exchange technology in application-level XML data exchange technology.

  10. Current organic chemistry

    National Research Council Canada - National Science Library

    1997-01-01

    Provides in depth reviews on current progress in the fields of asymmetric synthesis, organometallic chemistry, bioorganic chemistry, heterocyclic chemistry, natural product chemistry, and analytical...

  11. Nuclear chemistry

    International Nuclear Information System (INIS)

    Vertes, A.; Kiss, I.

    1987-01-01

    This book is an introduction to the application of nuclear science in modern chemistry. The first group of chapters discuss the basic phenomena and concepts of nuclear physics with emphasis on their relation to chemical problems, including the main properties and the composition of atomic nuclei, nuclear reactions, radioactive decay and interactions of radiation with matter. These chapters provide the basis for understanding the following chapters which encompass the wide scope of nuclear chemistry. The methods of the investigation of chemical structure based on the interaction of nuclear radiation with matter including positronium chemistry and other exotic atoms is elaborated in particular detail. Separate chapters are devoted to the use of radioactive tracers, the chemical consequences of nuclear processes (i.e. hot atom chemistry), radiation chemistry, isotope effects and their applications, and the operation of nuclear reactors

  12. Nuclear chemistry

    International Nuclear Information System (INIS)

    Vertes, A.; Kiss, I.

    1987-01-01

    This book is an introduction to the application of nuclear science in modern chemistry. The first group of chapters discuss the basic phenomena and concepts of nuclear physics with emphasis on their relation to chemical problems, including the main properties and the composition of atomic nuclei, nuclear reactions, radioactive decay and interactions of radiation with matter. These chapters provide the basis for understanding the following chapters which encompass the wide scope of nuclear chemistry. The methods of the investigation of chemical structure based on the interaction of nuclear radiation with matter including positronium chemistry and other exotic atoms is elaborated in particular detail. Separate chapters are devoted to the use of radioactive tracers, the chemical consequences of nuclear processes (i.e. hot atom chemistry), radiation chemistry, isotope effects and their applications, and the operation of nuclear reactors. (Auth.)

  13. FY 2000 international exchange project on exchanges of engineers - Coal mine technology field. Overseas workshop (Indonesia); 2000 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Kaigai workshop (Indonesia)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    For the purpose of making effective technology exchanges and surveying levels of technology in Indonesia and the needs and possibilities of technology transfer from Japan, workshop was held in Jakarta city on March 1, 2001. Subjects were the following seven: subjects on coal resource and technical strategy in the 21st century, challenge in coal development in Indonesia, geological structure survey at Tanjung Enim coal mine, waste water treatment in Indonesia, outlook for underground mining coal mines, joint research on the centralized monitoring system, and introduction of the optimum high wall coal mining system into open pit mining coal mines in Indonesia. The coal production amount in Indonesia was 75 million tons, and the domestic demand was 22 million tons. Japan imported 14 million tons from Indonesia. In coal mines in Indonesia, most of the coal preparation plants have no waste water treatment facilities. Considering that waste water treatment facilities are necessary for the plants in future, the joint research was made on the simple coal preparation waste water treatment system. (NEDO)

  14. Advanced chemistry management system to optimize BWR chemistry control

    International Nuclear Information System (INIS)

    Maeda, K.; Nagasawa, K.

    2002-01-01

    BWR plant chemistry control has close relationships among nuclear safety, component reliability, radiation field management and fuel integrity. Advanced technology is required to improve chemistry control [1,3,6,7,10,11]. Toshiba has developed TACMAN (Toshiba Advanced Chemistry Management system) to support BWR chemistry control. The TACMAN has been developed as response to utilities' years of requirements to keep plant operation safety, reliability and cost benefit. The advanced technology built into the TACMAN allows utilities to make efficient chemistry control and to keep cost benefit. TACMAN is currently being used in response to the needs for tools those plant chemists and engineers could use to optimize and identify plant chemistry conditions continuously. If an incipient condition or anomaly is detected at early stage, root causes evaluation and immediate countermeasures can be provided. Especially, the expert system brings numerous and competitive advantages not only to improve plant chemistry reliability but also to standardize and systematize know-how, empirical knowledge and technologies in BWR chemistry This paper shows detail functions of TACMAN and practical results to evaluate actual plant. (authors)

  15. A New Adsorbent Composite Material Based on Metal Fiber Technology and Its Application in Adsorption Heat Exchangers

    Directory of Open Access Journals (Sweden)

    Ursula Wittstadt

    2015-08-01

    Full Text Available In order to achieve process intensification for adsorption chillers and heat pumps, a new composite material was developed based on sintered aluminum fibers from a melt-extraction process and a dense layer of silico-aluminophosphate (SAPO-34 on the fiber surfaces. The SAPO-34 layer was obtained through a partial support transformation (PST process. Preparation of a composite sample is described and its characteristic pore size distribution and heat conductivity are presented. Water adsorption data obtained under conditions of a large pressure jump are given. In the next step, preparation of the composite was scaled up to larger samples which were fixed on a small adsorption heat exchanger. Adsorption measurements on this heat exchanger element that confirm the achieved process intensification are presented. The specific cooling power for the adsorption step per volume of composite is found to exceed 500 kW/m3 under specified conditions.

  16. What Chemistry To Teach Engineers?

    Science.gov (United States)

    Hawkes, Stephen J.

    2000-01-01

    Examines possible general chemistry topics that would be most relevant and practical for engineering majors. Consults the Accreditation Board for Engineering and Technology (ABET), engineering textbooks, texts from other required subjects, and practicing engineers for recommendations. (Contains 24 references.) (WRM)

  17. Proceeding of the Scientific Meeting and Presentation on Basic Research of Nuclear Science and Technology: Book II. Nuclear Chemistry, Process Technology, and Radioactive Waste Processing and Environment; Pertemuan dan Presentasi Ilmiah Penelitian Dasar Ilmu Pengetahuan dan Teknologi Nuklir. Buku II. Kimia Nuklir, Teknologi Proses, dan Pengolahan Limbah Radioaktif dan Lingkungan

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-01

    The proceeding contains papers presented on Scientific Meeting and Presentation on on Basic Research of Nuclear Science and Technology, held in Yogyakarta, 25-27 April 1995. This proceeding is second part of two books published for the meeting contains papers on nuclear chemistry, process technology, and radioactive waste management and environment. There are 62 papers indexed individually. (ID)

  18. Fiscal 2000 report on result of project for promoting exchange of international environmental technology information; 2000 nendo kankyo gijutsu kokusai joho koryu sokushin jigyo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With the purpose of sharing environmental technology information of the APEC countries, the homepage structuring was commenced linking and systematizing the home pages owned by governments, institutions, enterprises, etc., as the APEC Virtual Center (APEC-VC) project, with the fiscal 2000 results reported. In creating the homepage contents, in order to disseminate more useful information for the developing countries, 'Environmental Technology Cooperation for Developing Countries' as the original contents was prepared. In building a search engine, for the purpose of improving convenience for website users of the Virtual Center, APEC VC Japan created a retrieval system on the site. In overseas investigation, the researchers visited local plants to grasp problems and the needs by enterprises and organizations on water-pollution, waste treatment and the like, with the purpose of reflecting the investigation result in the website. In addition, the researchers visited APEC VC coordinators and/or contact points to exchange opinions with the view of expanding the network. (NEDO)

  19. Quantum chemistry

    CERN Document Server

    Lowe, John P

    1993-01-01

    Praised for its appealing writing style and clear pedagogy, Lowe's Quantum Chemistry is now available in its Second Edition as a text for senior undergraduate- and graduate-level chemistry students. The book assumes little mathematical or physical sophistication and emphasizes an understanding of the techniques and results of quantum chemistry, thus enabling students to comprehend much of the current chemical literature in which quantum chemical methods or concepts are used as tools. The book begins with a six-chapter introduction of standard one-dimensional systems, the hydrogen atom,

  20. Future perspectives of radiation chemistry

    International Nuclear Information System (INIS)

    Hatano, Yoshihiko

    2009-01-01

    Future perspectives of radiation chemistry are discussed by the analysis of the related information in detail as obtained from our recent surveys of publications and scientific meetings in radiation chemistry and its neighboring research fields, giving some examples, and are summarized as follows. (1) Traditionally important core-parts of radiation chemistry should be activated more. The corresponding research programs are listed in detail. (2) Research fields of physics, chemistry, biology, medicine, and technology in radiation research should interact more among them with each other. (3) Basic research of radiation chemistry should interact more with its applied research. (4) Interface research fields with radiation chemistry should be produced more with mutually common viewpoints and research interests between the two. Interfaces are not only applied research but also basic one.

  1. Global medicinal chemistry and GPCR conference: interview with Stevan Djuric.

    Science.gov (United States)

    Djuric, Stevan

    2018-04-01

    Stevan Djuric speaks to Benjamin Walden, Commissioning Editor. Stevan Djuric is head of the global Medicinal Chemistry Leadership Team at AbbVie and is also Vice President of the Discovery Chemistry and Technology organization within their Discovery organization and chemistry outsourcing activities. He spoke at the Global-Medicinal-Chemistry and GPCR summit on the imperative to develop chemistry related technology that can reduce cycle time, cost of goods and improve probability of success. To this end, he discussed his efforts in the chemistry technology area with a focus on integrated synthesis-purification bioassay, and flow photochemistry and high temperature chemistry platforms.

  2. Smart Cities Will Need Chemistry

    Directory of Open Access Journals (Sweden)

    Alexandru WOINAROSCHY

    2016-06-01

    Full Text Available A smart city is a sustainable and efficient urban centre that provides a high quality of life to its inhabitants through optimal management of its resources. Chemical industry has a key role to play in the sustainable evolution of the smart cities. Additionally, chemistry is at the heart of all modern industries, including electronics, information technology, biotechnology and nano-technology. Chemistry can make the smart cities project more sustainable, more energy efficient and more cost effective. There are six broad critical elements of any smart city: water management systems; infrastructure; transportation; energy; waste management and raw materials consumption. In all these elements chemistry and chemical engineering are deeply involved.

  3. Materials Chemistry

    CERN Document Server

    Fahlman, Bradley D

    2011-01-01

    The 2nd edition of Materials Chemistry builds on the strengths that were recognized by a 2008 Textbook Excellence Award from the Text and Academic Authors Association (TAA). Materials Chemistry addresses inorganic-, organic-, and nano-based materials from a structure vs. property treatment, providing a suitable breadth and depth coverage of the rapidly evolving materials field. The 2nd edition continues to offer innovative coverage and practical perspective throughout. After briefly defining materials chemistry and its history, seven chapters discuss solid-state chemistry, metals, semiconducting materials, organic "soft" materials, nanomaterials, and materials characterization. All chapters have been thoroughly updated and expanded with, for example, new sections on ‘soft lithographic’ patterning, ‘click chemistry’ polymerization, nanotoxicity, graphene, as well as many biomaterials applications. The polymer and ‘soft’ materials chapter represents the largest expansion for the 2nd edition. Each ch...

  4. Analytical chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Jae Seong

    1993-02-15

    This book is comprised of nineteen chapters, which describes introduction of analytical chemistry, experimental error and statistics, chemistry equilibrium and solubility, gravimetric analysis with mechanism of precipitation, range and calculation of the result, volume analysis on general principle, sedimentation method on types and titration curve, acid base balance, acid base titration curve, complex and firing reaction, introduction of chemical electro analysis, acid-base titration curve, electrode and potentiometry, electrolysis and conductometry, voltammetry and polarographic spectrophotometry, atomic spectrometry, solvent extraction, chromatograph and experiments.

  5. Analytical chemistry

    International Nuclear Information System (INIS)

    Choi, Jae Seong

    1993-02-01

    This book is comprised of nineteen chapters, which describes introduction of analytical chemistry, experimental error and statistics, chemistry equilibrium and solubility, gravimetric analysis with mechanism of precipitation, range and calculation of the result, volume analysis on general principle, sedimentation method on types and titration curve, acid base balance, acid base titration curve, complex and firing reaction, introduction of chemical electro analysis, acid-base titration curve, electrode and potentiometry, electrolysis and conductometry, voltammetry and polarographic spectrophotometry, atomic spectrometry, solvent extraction, chromatograph and experiments.

  6. Analytical chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Chae, Myeong Hu; Lee, Hu Jun; Kim, Ha Seok

    1989-02-15

    This book give explanations on analytical chemistry with ten chapters, which deal with development of analytical chemistry, the theory of error with definition and classification, sample and treatment gravimetry on general process of gravimetry in aqueous solution and non-aqueous solution, precipitation titration about precipitation reaction and types, complexometry with summary and complex compound, oxidation-reduction equilibrium on electrode potential and potentiometric titration, solvent extraction and chromatograph and experiment with basic operation for chemical experiment.

  7. Analytical chemistry

    International Nuclear Information System (INIS)

    Chae, Myeong Hu; Lee, Hu Jun; Kim, Ha Seok

    1989-02-01

    This book give explanations on analytical chemistry with ten chapters, which deal with development of analytical chemistry, the theory of error with definition and classification, sample and treatment gravimetry on general process of gravimetry in aqueous solution and non-aqueous solution, precipitation titration about precipitation reaction and types, complexometry with summary and complex compound, oxidation-reduction equilibrium on electrode potential and potentiometric titration, solvent extraction and chromatograph and experiment with basic operation for chemical experiment.

  8. Green Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Collison, Melanie

    2011-05-15

    Green chemistry is the science of chemistry used in a way that will not use or create hazardous substances. Dr. Rui Resendes is working in this field at GreenCentre Canada, an offshoot of PARTEQ Innovations in Kingston, Ontario. GreenCentre's preliminary findings suggest their licensed product {sup S}witchable Solutions{sup ,} featuring 3 classes of solvents and a surfactant, may be useful in bitumen oil sands extraction.

  9. Engineer exchanging project on coal mine technology field in fiscal 1999. International information exchanging project (advance survey on North America); 1999 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) kokusai koryu jigyo. Jizen chosa (Hokubei)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    This project has been performed with an intention of making visiting surveys and information collection at coal related organizations in overseas coal producing countries on production technology levels and trends. The project is intended to serve for improvement in the contents of and smooth execution of the engineer exchange project in the 'coal mine technology field. It was carried out by the site surveys. The surveys revealed that the situation of the American coal industry is expected of stable increase in the demand and supply in the future, but the coal price is on the falling trend, and therefore, the industry is compelled to further increase the intensity and enhance the productivity. The industry is strongly influenced by the amended air pollution prevention act and nature destruction problems, hence further coal mine curtailment is estimated. Under such a background, it was found that the long-wall mining process progressing toward larger scale and higher productivity, and the high-wall mining process that provides higher productivity at lower cost and has less impact on the environmental problems can continue development in mountainous areas, particularly in the Appalachian area. The high-wall mining process mines coal at exposed facings on the side of a mountain by using a continuous miner, and transports the coal using machines. (NEDO)

  10. Mendeleev-2013. VII All-Russian conference of young scientists, postgraduate students and students with international participation on chemistry and nanomaterials. Book of abstracts. Section 4. Organic chemistry

    International Nuclear Information System (INIS)

    2013-01-01

    VII All-Russian conference of young scientists, postgraduate students and students with international participation on chemistry and nanomaterials was conducted on the Chemistry department of Saint-Petersburg University on April, 2-5, 2013. In the conference participants from 14 countries took part. There were five sections: Nanochemistry and nanomaterials, Analytic chemistry, Inorganic chemistry, Organic chemistry, Physical chemistry. In the collection (Section 2 - Organic chemistry) there are the abstracts concerning different aspects of organic chemistry: synthesis and study of properties of heterocyclic, organometallic, biologically active, medicinal compounds, new ion exchange materials, reagents for analytic chemistry, etc [ru

  11. NASA/University JOint VEnture (JOVE) Program. VIXEN(tm): Object-Oriented, Technology-Adaptive, Virtual Information Exchange Environment

    Science.gov (United States)

    Anyiwo, Joshua C.

    2000-01-01

    Vixen is a collection of enabling technologies for uninhibited distributed object computing. In the Spring of 1995 when Vixen was proposed, it was an innovative idea very much ahead of its time. But today the technologies proposed in Vixen have become standard technologies for Enterprise Computing. Sun Microsystems J2EE/EJB specifications, among others, are independently proposed technologies of the Vixen type. I have brought Vixen completely under the J2EE standard in order to maximize interoperability and compatibility with other computing industry efforts. Vixen and the Enterprise JavaBean (EJB) Server technologies are now practically identical; OIL, another Vixen technology, and the Java Messaging System (JMS) are practically identical; and so on. There is no longer anything novel or patentable in the Vixen work performed under this grant. The above discussion, notwithstanding, my independent development of Vixen has significantly helped me, my university, my students and the local community. The undergraduate students who worked with me in developing Vixen have enhanced their expertise in what has become the cutting edge technology of their industry and are therefore well positioned for lucrative employment opportunities in the industry. My academic department has gained a new course: "Multi-media System Development", which provides a highly desirable expertise to our students for employment in any enterprise today. The many Outreach Programs that I conducted during this grant period have exposed local Middle School students to the contributions that NASA is making in our society as well as awakened desires in many such students for careers in Science and Technology. I have applied Vixen to the development of two software packages: (a) JAS: Joshua Application Server - which allows a user to configure an EJB Server to serve a J2EE compliant application over the world wide web; (b) PCM: Professor Course Manager: a J2EE compliant application for configuring a

  12. Chemistry-Nuclear Chemistry Division. Progress report, October 1980-September 1981

    International Nuclear Information System (INIS)

    Ryan, R.R.

    1982-05-01

    This report describes major progress in the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory during FY 1981. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, medical radioisotopes research, element migration and fixation, nuclear waste isolation research, inorganic and structural chemistry, isotope separation, analysis and applications, the newly established Nuclear Magnetic Resonance Center, atomic and molecular collisions, molecular spectroscopy, nuclear cosmochemistry, nuclear structure and reactions, pion charge exchange, radiochemical separations, theoretical chemistry, and unclassified weapons research

  13. Chemistry-Nuclear Chemistry Division. Progress report, October 1980-September 1981

    Energy Technology Data Exchange (ETDEWEB)

    Ryan, R.R. (comp.)

    1982-05-01

    This report describes major progress in the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory during FY 1981. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, medical radioisotopes research, element migration and fixation, nuclear waste isolation research, inorganic and structural chemistry, isotope separation, analysis and applications, the newly established Nuclear Magnetic Resonance Center, atomic and molecular collisions, molecular spectroscopy, nuclear cosmochemistry, nuclear structure and reactions, pion charge exchange, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  14. Role of Exchange Equilibria in Structural Chemistry; Role des Equilibres d'Echange en Chimie Structurale; Rol' ravnovesiya obmena v strukturnoj khimii; Papel de los Equilibrios de Intercambio en Quimica Estructural

    Energy Technology Data Exchange (ETDEWEB)

    Van Wazer, J. R.; Moedritzer, K. [Monsanto Company, St. Louis, MI (United States)

    1965-10-15

    Although much of the past effort on the study of exchange reactions has been devoted to the scrambling of monofunctional substituents on a polyfunctional atom or moiety, complicated molecules may also undergo exchange of parts so as to give an equilibrium distribution of various molecular sizes and shapes. The use of high-resolution nuclear magnetic resonance (NMR) in investigating such equilibrated mixtures of compounds has been described in a number of 1964 and 1965 papers from the Monsanto Co. laboratory (see Refs [1-34] at the end of the abstracts). The systems thus studied include several new families of compounds; and the amounts and kinds of products resulting from the exchange reactions have been quantitatively described in terms of a small number of equilibrium constants. A new mathematical approach - that of stochastic graph theory [6] - has been employed to establish the form and the minimum number of equilibrium constants relating the non-cyclic structures and parts of molecular structures to each other. In addition, the equilibria between the cyclic and non-cyclic structures have been treated quantitatively. The emphasis in structural chemistry on the compounds of carbon (as evidenced by the division of descriptive chemistry into the organic and inorganic categories) is attributed to the fact that exchange reactions involving C-C bonds or bonds from carbon to any atom not exhibiting low-lying vacant bonding orbitals (e.g. Si, Ge, N, P, As. O, S, Se, F, Cl, Br) are exceedingly slow. On the other hand, there are vast areas of inorganic chemistry which have not previously been described because the molecules undergo such rapid exchange reactions that they cannot be separated. However, they can be identified and quantitatively assayed by means of physical methods (such as NMR) having short time constants, when the resulting data receive proper mathematical treatment - a procedure which is sufficiently involved to demand the use of a high-speed computer [6

  15. Leak Detection in Heat Exchangers and Underground Pipelines Using Radiotracers. Material for Education and On-The-Job Training for Practitioners of Radiotracer Technology

    International Nuclear Information System (INIS)

    2009-01-01

    The International Atomic Energy Agency plays a major role in facilitating the transfer of radiotracer technology to developing Member States. The use of radiotracer techniques is well established in many Member States; some hundred radiotracer and end user specialists have been trained in radiotracer techniques and their applications; nearly 50 radiotracer laboratories have been working in this field. The training of radiotracer practitioners is vital for the provision of quality services to industry. Leak detection using radiotracer techniques is probably one of the most widespread applications of radiotracers in industrial troubleshooting. Radiotracer techniques are the most competitive for online leak inspection of heat exchangers and buried pipelines. Radiotracers help in early detection of leaks in heat exchangers and underground transporting pipelines, thus saving money, reducing shutdown time, ensuring safe operation and protecting the environment from pollution. The training course series on leak detection in heat exchangers and underground pipelines using radiotracers addresses the needs of the radiotracer groups and their end users. Besides training purposes, this material will assist radiotracer groups in establishing their quality control and accreditation systems. This training course material is based on lecture notes and practical work delivered by many experts in IAEA-supported activities. In particular, the Technical Cooperation Projects implemented under the Regional Cooperative Agreement (RCA) of the IAEA Member States in the Asia and the Pacific Region have been successful in transferring and implementing radiotracer techniques for leak detection to many end users from oil and gas production, oil refineries and the petrochemical industry. The experience obtained in the RCA Region is presented in the training material illustrated with many case studies carried out in several RCA Member States. Lectures and case studies were reviewed by a number

  16. Fiscal 1997 technological survey report. Engineer exchange project - coal mine technological field (Advanced coal producing country survey - U.S.A. survey); 1997 nendo gijutsusha koryu jigyo (tanko gijutsu bun'ya) senshin santankoku chosa. Beikoku chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    While the introduction and adaptation of the Longwall excavation technology were carried forward for coal producing countries in the Pacific region, U.S.A. information was collected by making tours of coal mines in the West and Washington/Colorado/Utah States, with the intention of ascertaining technological trend so as to carry out efficient technological transfer, and for the purpose of replenishing the contents and contributing to the smooth implementation of the engineer exchange project in 'coal mine technological field'. The coal reserves are 400 billion tons, with 840 million tons produced and with 80 million tons exported; not less than 56% of the U.S. domestic electricity rests on coal. Production by open-pit mining is the majority while the output by underground mining is 38%; the Longwall method has increased as a digging method, taking 18% of all digging output. The productivity is 4.24 ton/person per day and ranks as the world highest. The coal mining technological trend in the U.S. can be summarized as follows. The coal mining output in the West is increasing, with the number of mines decreasing, so that the output per mine is increasing. With the output ratio by open-pit mining increasing, the digging method in the mine is being changed to the Longwall. (NEDO)

  17. (Environmental technology)

    Energy Technology Data Exchange (ETDEWEB)

    Boston, H.L.

    1990-10-12

    The traveler participated in a conference on environmental technology in Paris, sponsored by the US Embassy-Paris, US Environmental Protection Agency (EPA), the French Environmental Ministry, and others. The traveler sat on a panel for environmental aspects of energy technology and made a presentation on the potential contributions of Oak Ridge National Laboratory (ORNL) to a planned French-American Environmental Technologies Institute in Chattanooga, Tennessee, and Evry, France. This institute would provide opportunities for international cooperation on environmental issues and technology transfer related to environmental protection, monitoring, and restoration at US Department of Energy (DOE) facilities. The traveler also attended the Fourth International Conference on Environmental Contamination in Barcelona. Conference topics included environmental chemistry, land disposal of wastes, treatment of toxic wastes, micropollutants, trace organics, artificial radionuclides in the environment, and the use biomonitoring and biosystems for environmental assessment. The traveler presented a paper on The Fate of Radionuclides in Sewage Sludge Applied to Land.'' Those findings corresponded well with results from studies addressing the fate of fallout radionuclides from the Chernobyl nuclear accident. There was an exchange of new information on a number of topics of interest to DOE waste management and environmental restoration needs.

  18. Digital technology use among disadvantaged Australians: implications for equitable consumer participation in digitally-mediated communication and information exchange with health services.

    Science.gov (United States)

    Newman, Lareen; Biedrzycki, Kate; Baum, Fran

    2012-05-01

    To present research findings on access to, and use of, digital information and communication technologies (ICTs) by Australians from lower income and disadvantaged backgrounds to determine implications for equitable consumer access to digitally-mediated health services and information. Focus groups were held in 2008-09 with 80 residents from lower income and disadvantaged backgrounds in South Australia, predominantly of working- and family-formation age (25 to 55 years). Qualitative analysis was conducted on a-priori and emergent themes to describe dominant categories. Access to, and use of, computers, the Internet and mobile phones varied considerably in extent, frequency and quality within and across groups due to differences in abilities, resources and life experience. Barriers and facilitators included English literacy (including for native speakers), technological literacy, education, income, housing situation, social connection, health status, employment status, and trust. Many people gained ICT skills by trial and error or help from friends, and only a few from formal programs, resulting in varied skills. The considerable variation in ICT access and use within lower income and disadvantaged groups must be acknowledged and accommodated by health initiatives and services when delivering digitally-mediated consumer-provider interaction, online health information, or online self-management of health conditions. If services require consumers to participate in a digitally-mediated communication exchange, then we suggest they might support skills and technology acquisition, or provide non-ICT alternatives, in order to avoid exacerbating health inequities.

  19. General chemistry

    International Nuclear Information System (INIS)

    Kwon, Yeong Sik; Lee, Dong Seop; Ryu, Haung Ryong; Jang, Cheol Hyeon; Choi, Bong Jong; Choi, Sang Won

    1993-07-01

    The book concentrates on the latest general chemistry, which is divided int twenty-three chapters. It deals with basic conception and stoichiometry, nature of gas, structure of atoms, quantum mechanics, symbol and structure of an electron of ion and molecule, chemical thermodynamics, nature of solid, change of state and liquid, properties of solution, chemical equilibrium, solution and acid-base, equilibrium of aqueous solution, electrochemistry, chemical reaction speed, molecule spectroscopy, hydrogen, oxygen and water, metallic atom; 1A, IIA, IIIA, carbon and atom IVA, nonmetal atom and an inert gas, transition metals, lanthanons, and actinoids, nuclear properties and radioactivity, biochemistry and environment chemistry.

  20. Radiation chemistry

    International Nuclear Information System (INIS)

    Swallow, A.J.

    1983-01-01

    The subject is covered in chapters, entitled: introduction (defines scope of article as dealing with the chemistry of reactive species, (e.g. excess electrons, excited states, free radicals and inorganic ions in unusual valency states) as studied using radiation with radiation chemistry in its traditional sense and with biological and industrial applications); gases; water and simple inorganic systems; aqueous metallo-organic compounds and metalloproteins; small organic molecules in aqueous solution; microheterogeneous systems; non-aqueous liquids and solutions; solids; biological macromolecules; synthetic polymers. (U.K.)

  1. Indoor Chemistry

    DEFF Research Database (Denmark)

    Weschler, Charles J.; Carslaw, Nicola

    2018-01-01

    This review aims to encapsulate the importance, ubiquity, and complexity of indoor chemistry. We discuss the many sources of indoor air pollutants and summarize their chemical reactions in the air and on surfaces. We also summarize some of the known impacts of human occupants, who act as sources...... and sinks of indoor chemicals, and whose activities (e.g., cooking, cleaning, smoking) can lead to extremely high pollutant concentrations. As we begin to use increasingly sensitive and selective instrumentation indoors, we are learning more about chemistry in this relatively understudied environment....

  2. Chemistry teacher professional development using the ...

    African Journals Online (AJOL)

    Chemistry teacher professional development using the technological pedagogical content knowledge(TPACK) framework. ... But with the advent of modern technologies, information and communication ... [AJCE 4(3), Special Issue, May 2014] ...

  3. Quo vadis, analytical chemistry?

    Science.gov (United States)

    Valcárcel, Miguel

    2016-01-01

    This paper presents an open, personal, fresh approach to the future of Analytical Chemistry in the context of the deep changes Science and Technology are anticipated to experience. Its main aim is to challenge young analytical chemists because the future of our scientific discipline is in their hands. A description of not completely accurate overall conceptions of our discipline, both past and present, to be avoided is followed by a flexible, integral definition of Analytical Chemistry and its cornerstones (viz., aims and objectives, quality trade-offs, the third basic analytical reference, the information hierarchy, social responsibility, independent research, transfer of knowledge and technology, interfaces to other scientific-technical disciplines, and well-oriented education). Obsolete paradigms, and more accurate general and specific that can be expected to provide the framework for our discipline in the coming years are described. Finally, the three possible responses of analytical chemists to the proposed changes in our discipline are discussed.

  4. Survey report of FY 1997 on the global environmental industry technology development promotion project. International research exchange project; 1997 nendo chosa hokokusho. Chikyu kankyo sangyo gijutsu kaihatsu suishin jigyo (kokusai kenkyu koryu jigyo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Exchange of personnel among foreign research organizations is significant for promoting research and development to create new research fields and to build new technological systems for the purpose of solving global environmental problems. For this purpose, researchers were sent/invited to/from international conferences and international symposiums related to global environmental technology and exchange of personnel with major foreign research organizations and universities was conducted under the cooperation of RITE and RITE-related researchers and related academic societies. Based on short-term invitation and sending of researchers as well as the feasibility study of researcher exchange, researchers were sent/invited on long- and mid-terms. As a result, exchange of personnel engaged in the latest research in Japan and overseas could be promoted. It was found that various researches are being conducted abroad in basic areas of global environmental technology. Since they are closely related to the research and development of industrial technology contributing to global environmental preservation promoted by RITE, it is important to establish a more efficient exchange system of researchers in the future. 91 refs., 38 figs., 14 tabs.

  5. Proton exchange membrane fuel cells for space and electric vehicle applications: From basic research to technology development

    Science.gov (United States)

    Srinivasan, Supramaniam; Mukerjee, Sanjeev; Parthasarathy, A.; CesarFerreira, A.; Wakizoe, Masanobu; Rho, Yong Woo; Kim, Junbom; Mosdale, Renaut A.; Paetzold, Ronald F.; Lee, James

    1994-01-01

    The proton exchange membrane fuel cell (PEMFC) is one of the most promising electrochemical power sources for space and electric vehicle applications. The wide spectrum of R&D activities on PEMFC's, carried out in our Center from 1988 to date, is as follows (1) Electrode Kinetic and Electrocatalysis of Oxygen Reduction; (2) Optimization of Structures of Electrodes and of Membrane and Electrode Assemblies; (3) Selection and Evaluation of Advanced Proton Conducting Membranes and of Operating Conditions to Attain High Energy Efficiency; (4) Modeling Analysis of Fuel Cell Performance and of Thermal and Water Management; and (5) Engineering Design and Development of Multicell Stacks. The accomplishments on these tasks may be summarized as follows: (1) A microelectrode technique was developed to determine the electrode kinetic parameters for the fuel cell reactions and mass transport parameters for the H2 and O2 reactants in the proton conducting membrane. (2) High energy efficiencies and high power densities were demonstrated in PEMFCs with low platinum loading electrodes (0.4 mg/cm(exp 2) or less), advanced membranes and optimized structures of membrane and electrode assemblies, as well as operating conditions. (3) The modeling analyses revealed methods to minimize mass transport limitations, particularly with air as the cathodic reactant; and for efficient thermal and water management. (4) Work is in progress to develop multi-kilowatt stacks with the electrodes containing low platinum loadings.

  6. In-Frame and Unmarked Gene Deletions in Burkholderia cenocepacia via an Allelic Exchange System Compatible with Gateway Technology.

    Science.gov (United States)

    Fazli, Mustafa; Harrison, Joe J; Gambino, Michela; Givskov, Michael; Tolker-Nielsen, Tim

    2015-06-01

    Burkholderia cenocepacia is an emerging opportunistic pathogen causing life-threatening infections in immunocompromised individuals and in patients with cystic fibrosis, which are often difficult, if not impossible, to treat. Understanding the genetic basis of virulence in this emerging pathogen is important for the development of novel treatment regimes. Generation of deletion mutations in genes predicted to encode virulence determinants is fundamental to investigating the mechanisms of pathogenesis. However, there is a lack of appropriate selectable and counterselectable markers for use in B. cenocepacia, making its genetic manipulation problematic. Here we describe a Gateway-compatible allelic exchange system based on the counterselectable pheS gene and the I-SceI homing endonuclease. This system provides efficiency in cloning homology regions of target genes and allows the generation of precise and unmarked gene deletions in B. cenocepacia. As a proof of concept, we demonstrate its utility by deleting the Bcam1349 gene, encoding a cyclic di-GMP (c-di-GMP)-responsive regulator protein important for biofilm formation. Copyright © 2015, American Society for Microbiology. All Rights Reserved.

  7. Blockchain Technology: A Data Framework to Improve Validity, Trust, and Accountability of Information Exchange in Health Professions Education.

    Science.gov (United States)

    Funk, Eric; Riddell, Jeff; Ankel, Felix; Cabrera, Daniel

    2018-06-12

    Health professions educators face multiple challenges, among them the need to adapt educational methods to new technologies. In the last decades multiple new digital platforms have appeared in the learning arena, including massive open online courses and social media-based education. The major critique of these novel methods is the lack of the ability to ascertain the origin, validity, and accountability of the knowledge that is created, shared, and acquired. Recently, a novel technology based on secured data storage and transmission, called blockchain, has emerged as a way to generate networks where validity, trust, and accountability can be created. Conceptually blockchain is an open, public, distributed, and secure digital registry where information transactions are secured and have a clear origin, explicit pathways, and concrete value. Health professions education based on the blockchain will potentially allow improved tracking of content and the individuals who create it, quantify educational impact on multiple generations of learners, and build a relative value of educational interventions. Furthermore, institutions adopting blockchain technology would be able to provide certification and credentialing of healthcare professionals with no intermediaries. There is potential for blockchain to significantly change the future of health professions education and radically transform how patients, professionals, educators, and learners interact around safe, valid, and accountable information.

  8. Food chemistry. 2. ed.

    International Nuclear Information System (INIS)

    Baltes, W.

    1989-01-01

    This second edition of the textbook deals with all essential aspects of food chemistry. The revision improved in particular the chapters on food preservation, including irradiation of food, food additives, and pollutants and residues, including radionuclides. The chapter on the German legal regime for foodstuffs has been updated to cover the recent amendments of the law, and the information on processes applied in food technology has been largely enhanced. (VHE) With 153 figs., 78 tabs [de

  9. Handbook of heterocyclic chemistry

    National Research Council Canada - National Science Library

    Katritzky, Alan R

    2010-01-01

    ... Heterocyclic Chemistry I (1984) Comprehensive Heterocyclic Chemistry II (1996) Comprehensive Heterocyclic Chemistry III (2008) Comprehensive Organic Functional Group Transformations I (1995) Compreh...

  10. Reinventing Chemistry

    OpenAIRE

    Whitesides, George McClelland

    2015-01-01

    Chemistry is in a period of change, from an era focused on molecules and reactions, to one in which manipulations of systems of molecules and reactions will be essential parts of controlling larger systems. This Essay traces paths from the past to possible futures.

  11. Chemistry Notes

    Science.gov (United States)

    School Science Review, 1972

    1972-01-01

    Short articles on the kinetics of the hydrogen peroxide-iodide ion reaction, simulation of fluidization catalysis, the use of Newman projection diagrams to represent steric relationships in organic chemistry, the use of synthetic substrates for proteolytic enzyme reactions, and two simple clock reactions"--hydrolysis of halogenoalkanes and…

  12. Water chemistry regimes for VVER-440 units: water chemistry influence on fuel cladding behaviour

    International Nuclear Information System (INIS)

    Zmitko, M.

    1999-01-01

    In this lecture next problems of water chemistry influence on fuel cladding behaviour for VVER-440 units are presented: primary coolant technologies; water chemistry specification and control; fuel integrity considerations; zirconium alloys cladding corrosion (corrosion versus burn-up; water chemistry effect; crud deposition; hydrogen absorption; axial offset anomaly); alternatives for the primary coolant regimes

  13. Promoting sustainability through green chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Kirchhoff, Mary M. [American Chemical Society, 1155 Sixteenth Street, NW, Washington, DC 20036 (United States)

    2005-06-15

    Green chemistry is an important tool in achieving sustainability. The implementation of green chemistry, the design of chemical products and processes that reduce or eliminate the use and generation of hazardous substances, is essential if the expanding global population is to enjoy an increased standard of living without having a negative impact on the health of the planet. Cleaner technologies will allow the chemical enterprise to provide society with the goods and services on which it depends in an environmentally responsible manner. Green chemistry provides solutions to such global challenges as climate change, sustainable agriculture, energy, toxics in the environment, and the depletion of natural resources. A collaborative effort by industry, academia, and government is needed to promote the adoption of the green chemistry technologies necessary to achieve a sustainable society.

  14. Organic decontamination by ion exchange

    International Nuclear Information System (INIS)

    Wilson, T.R.

    1994-01-01

    This study has successfully identified ion exchanger media suitable for decontaminating the 5500-gallon organic layer in Tank 241-C-103. Decontamination of radionuclides is necessary to meet shipping, incinerator site storage, and incineration feed requirements. The exchanger media were identified through a literature search and experiments at the Russian Institute for Physical Chemistry. The principal radionuclides addressed are Cs-137 and Sr-90. Recommendations for an experimental program plan conclude the discussion. The experimental program would provide the data necessary for plant design specifications for a column and for ion exchange media to be used in decontaminating the organic layer

  15. The Beginning Lecture and the Improvement of “Experiments in Innovative Chemistry” as an Entry Subjects at the Department of Biochemistry and Applied Chemistry in National College of Technology

    Science.gov (United States)

    Tsuda, Yusuke; Nakashima, Hiroyuki; Tsuji, Yutaka; Watanabe, Katsuhiro; Ooka, Hisako

    The beginning lecture and the improvement of “Experiments in Innovative Chemistry” as an entry subjects in the Department of Biochemistry and Applied Chemistry at Kurume National College of Technology has been performed for recent three years. Every experiment was selected to sustain the young student's interest. The questionnaires were performed after first two year's programs were finished, and some of projects were improved. This subject has a good reputation for students and teachers, and seems to be very effective for the first year students of national college of technology.

  16. Evaluation of the feasibility of security technologies in teleradiology as biometric fingerprint scanners for data exchange over a satellite WAN

    Science.gov (United States)

    Soegner, Peter I.; Helweg, Gernot; Holzer, Heimo; zur Nedden, Dieter

    2000-05-01

    We evaluated the feasibility of fingerprint-scanners in combination with smart cards for personal identification and transmission of encrypted TCP/IP-data-packages via satellite between the university-hospital of Innsbruck and the rural hospital of Reutte. The aim of our study was the proof of the userfriendliness of the SkymedTM technology for security purpose in teleradiology. We examined the time of the personal identification process, the time for the necessary training and the personal satisfaction. The images were sent from the local PACS in Reutte via a Data-Encryption-and-Transmission- Box via satellite from Reutte to Innsbruck. We used an asymmetric bandwidth of 512 kbit/s from Reutte to Innsbruck and 128 kbit/s in the opposite direction. Window NT 4.0- operating PCs were used for the electronical patient record, the medical inquiry of the referring physician and the final report of the radiologist. The images were reported on an UNIX-PACS viewing station. After identification through fingerprint-scanners in combination with the smart card the radiologist was able to open the electronic patient record (EPR) from Reutte and sign with his digital signature his confirmed final report before it was send back to Reutte. The used security technology enables encrypted communication over a WAN, which fulfill data-protection.

  17. The 10th Joint Meeting on Medicinal Chemistry (JMMC 2017) Held in Dubrovnik, Croatia.

    Science.gov (United States)

    Perković, Ivana; Stepanić, Višnja; Marković, Vesna Gabelica

    2018-01-08

    The Croatian Chemical Society was established in 1926 and has developed over the decades into a society that actively supports all chemical activities in Croatia. The Society has eight divisions, the youngest of which, the Division of Medicinal and Pharmaceutical Chemistry, was established in 2012 and immediately became a member of the European Federation of Medicinal Chemistry (EFMC). The mission of the Medicinal and Pharmaceutical Chemistry Division is the promotion and development of scientific, professional, and educational activities within the medicinal chemistry community in Croatia, as well as to build partnerships and collaborations with other primarily EU-based medicinal chemistry societies. In Croatia, medicinal chemistry research is ongoing at several institutes, including the University of Zagreb (Faculty of Science, Faculty of Pharmacy and Biochemistry, and Faculty of Chemical Engineering and Technology), national institutes of science (Ruđer Bošković Institute), and private-sector drug discovery companies (CRO Fidelta Ltd.). In order to effectively exchange knowledge, ideas, and scientific results, Croatian medicinal chemists meet twice annually. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Fiscal 2000 report on result of project for promoting exchange of international environmental technology information; 2000 nendo kankyo gijutsu kokusai joho koryu sokushin jigyo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With the purpose of sharing environmental technology information of the APEC countries, the homepage structuring was commenced linking and systematizing the home pages owned by governments, institutions, enterprises, etc., as the APEC Virtual Center (APEC-VC) project, with the fiscal 2000 results reported. In creating the homepage contents, in order to disseminate more useful information for the developing countries, 'Environmental Technology Cooperation for Developing Countries' as the original contents was prepared. In building a search engine, for the purpose of improving convenience for website users of the Virtual Center, APEC VC Japan created a retrieval system on the site. In overseas investigation, the researchers visited local plants to grasp problems and the needs by enterprises and organizations on water-pollution, waste treatment and the like, with the purpose of reflecting the investigation result in the website. In addition, the researchers visited APEC VC coordinators and/or contact points to exchange opinions with the view of expanding the network. (NEDO)

  19. Progress report, Chemistry and Materials Division, April 1 to June 30, 1978

    International Nuclear Information System (INIS)

    1978-07-01

    Provisional research results are reported in the general areas of ion beam-radiation interactions with metals, radiation chemistry, hydrogen isotope exchange, analytical chemistry, and zirconium alloy properties. (E.C.B.)

  20. Progress report, Chemistry and Materials Division, October 1 to December 31, 1977

    International Nuclear Information System (INIS)

    1978-01-01

    Research results are reported on the interaction of ion beams with solids, radiation chemistry, hydrogen isotope exchange, surface science, analytical chemistry, and properties of zirconium and its alloys. (E.C.B.)

  1. Heat exchanger

    International Nuclear Information System (INIS)

    Dostatni, A.W.; Dostatni, Michel.

    1976-01-01

    In the main patent, a description was given of a heat exchanger with an exchange surface in preformed sheet metal designed for the high pressure and temperature service particularly encountered in nuclear pressurized water reactors and which is characterised by the fact that it is composed of at least one exchanger bundle sealed in a containment, the said bundle or bundles being composed of numerous juxtaposed individual compartments whose exchange faces are built of preformed sheet metal. The present addendun certificate concerns shapes of bundles and their positioning methods in the exchanger containment enabling its compactness to be increased [fr

  2. Chemistry and physics

    International Nuclear Information System (INIS)

    Broerse, J.J.; Barendsen, G.W.; Kal, H.B.; Kogel, A.J. van der

    1983-01-01

    This book contains the extended abstracts of the contributions of the poster workshop sessions on chemistry and physics of the 7th international congress of radiation research. They cover the following main topics: primary processes in radiation physics and chemistry, general chemistry in radiation chemistry, DNA and model systems in radiation chemistry, molecules of biological interest in radiation chemistry, techniques in radiation chemistry, hot atom chemistry. refs.; figs.; tabs

  3. Fine chemistry

    International Nuclear Information System (INIS)

    Laszlo, P.

    1988-01-01

    The 1988 progress report of the Fine Chemistry laboratory (Polytechnic School, France) is presented. The research programs are centered on the renewal of the organic chemistry most important reactions and on the invention of new, highly efficient and highly selective reactions, by applying low cost reagents and solvents. An important research domain concerns the study and fabrication of new catalysts. They are obtained by means of the reactive sputtering of the metals and metal oxydes thin films. The Monte Carlo simulations of the long-range electrostatic interaction in a clay and the obtention of acrylamides from anhydrous or acrylic ester are summarized. Moreover, the results obtained in the field of catalysis are also given. The published papers and the congress communications are included [fr

  4. Radioanalytical chemistry

    International Nuclear Information System (INIS)

    1982-01-01

    The bibliography of Hungarian literature in the field of radioanalytical chemistry covers the four-year period 1976-1979. The list of papers contains 290 references in the alphabetical order of the first authors. The majority of the titles belongs to neutron activation analysis, labelling, separation and determination of radioactive isotopes. Other important fields like radioimmunoassay, environmental protection etc. are covered as well. (Sz.J.)

  5. Industrial chemistry engineering

    International Nuclear Information System (INIS)

    1993-01-01

    This book on industrial chemistry engineering is divided in two parts. The first part deals with industrial chemistry, inorganic industrial chemistry, organic industrial chemistry, analytical chemistry and practical questions. The last parts explain the chemical industry, a unit parts and thermodynamics in chemical industry and reference. It reveals the test subjects for the industrial chemistry engineering with a written examination and practical skill.

  6. Computational chemistry

    Science.gov (United States)

    Arnold, J. O.

    1987-01-01

    With the advent of supercomputers, modern computational chemistry algorithms and codes, a powerful tool was created to help fill NASA's continuing need for information on the properties of matter in hostile or unusual environments. Computational resources provided under the National Aerodynamics Simulator (NAS) program were a cornerstone for recent advancements in this field. Properties of gases, materials, and their interactions can be determined from solutions of the governing equations. In the case of gases, for example, radiative transition probabilites per particle, bond-dissociation energies, and rates of simple chemical reactions can be determined computationally as reliably as from experiment. The data are proving to be quite valuable in providing inputs to real-gas flow simulation codes used to compute aerothermodynamic loads on NASA's aeroassist orbital transfer vehicles and a host of problems related to the National Aerospace Plane Program. Although more approximate, similar solutions can be obtained for ensembles of atoms simulating small particles of materials with and without the presence of gases. Computational chemistry has application in studying catalysis, properties of polymers, all of interest to various NASA missions, including those previously mentioned. In addition to discussing these applications of computational chemistry within NASA, the governing equations and the need for supercomputers for their solution is outlined.

  7. Process chemistry related to hydrogen isotopes

    International Nuclear Information System (INIS)

    Iwasaki, Matae; Ogata, Yukio

    1991-01-01

    Hydrogen isotopes, that is, protium, deuterium and tritium, are all related deeply to energy in engineering region. Deuterium and tritium exist usually as water in extremely thin state. Accordingly, the improvement of the technology for separating these isotopes is a large engineering subject. Further, tritium is radioactive and its half-life period is 12.26 years, therefore, it is desirable to fix it in more stable form besides its confinement in the handling system. As the chemical forms of hydrogen, the molecular hydrogen with highest reactivity, metal hydride, carbon-hydrogen-halogen system compounds, various inorganic hydrides, most stable water and hydroxides are enumerated. The grasping of the behavior from reaction to stable state of these hydrogen compounds and the related materials is the base of process chemistry. The reaction of exchanging isotopes between water and hydrogen on solid catalyzers, the decomposition of ethane halide containing hydrogen, the behavior of water and hydroxides in silicates are reported. The isotope exchange between water and hydrogen is expected to be developed as the process of separating and concentrating hydrogen isotopes. (K.I.) 103 refs

  8. Current status and future perspectives of electron interactions with molecules, clusters, surfaces, and interfaces [Workshop on Fundamental challenges in electron-driven chemistry; Workshop on Electron-driven processes: Scientific challenges and technological opportunities

    Energy Technology Data Exchange (ETDEWEB)

    Becker, Kurt H.; McCurdy, C. William; Orlando, Thomas M.; Rescigno, Thomas N.

    2000-09-01

    This report is based largely on presentations and discussions at two workshops and contributions from workshop participants. The workshop on Fundamental Challenges in Electron-Driven Chemistry was held in Berkeley, October 9-10, 1998, and addressed questions regarding theory, computation, and simulation. The workshop on Electron-Driven Processes: Scientific Challenges and Technological Opportunities was held at Stevens Institute of Technology, March 16-17, 2000, and focused largely on experiments. Electron-molecule and electron-atom collisions initiate and drive almost all the relevant chemical processes associated with radiation chemistry, environmental chemistry, stability of waste repositories, plasma-enhanced chemical vapor deposition, plasma processing of materials for microelectronic devices and other applications, and novel light sources for research purposes (e.g. excimer lamps in the extreme ultraviolet) and in everyday lighting applications. The life sciences are a rapidly advancing field where the important role of electron-driven processes is only now beginning to be recognized. Many of the applications of electron-initiated chemical processes require results in the near term. A large-scale, multidisciplinary and collaborative effort should be mounted to solve these problems in a timely way so that their solution will have the needed impact on the urgent questions of understanding the physico-chemical processes initiated and driven by electron interactions.

  9. Chemistry in and from nuclear fusion

    International Nuclear Information System (INIS)

    Okamoto, M.

    1989-01-01

    The time, of the realization of nuclear fusion reactor is not clear even now. However, it is generally believed that the nuclear fusion is only one candidate of the big power source for humanbeing. We may be not able to, but our children or grandchildren would be able to see the nuclear fusion reactors. The nuclear fusion development may be the last and biggest technology program for us, so it will take so long leading time. Now, we are in the first stage of this leading time, I think. As being found in the history of every technology, chemistry is essential to develop the fusion nuclear technology. To assure the safety of the nuclear fusion system, chemistry should play the main role. There have been already not a few advanced chemistry initiated by the connected technologies with the nuclear fusion researches. The nuclear fusion needs chemistry and the nuclear fusion leads some of the new phases of chemistry. (author)

  10. Game Changing Development Program - Next Generation Life Support Project: Oxygen Recovery From Carbon Dioxide Using Ion Exchange Membrane Electrolysis Technology

    Science.gov (United States)

    Burke, Kenneth A.; Jiao, Feng

    2016-01-01

    This report summarizes the Phase I research and development work performed during the March 13, 2015 to July 13, 2016 period. The proposal for this work was submitted in response to NASA Research Announcement NNH14ZOA001N, "Space Technology Research, Development, Demonstration, and Infusion 2014 (SpaceTech-REDDI-2014)," Appendix 14GCD-C2 "Game Changing Development Program, Advanced Oxygen Recovery for Spacecraft Life Support Systems Appendix" The Task Agreement for this Phase I work is Document Control Number: GCDP-02-TA-15015. The objective of the Phase I project was to demonstrate in laboratories two Engineering Development Units (EDU) that perform critical functions of the low temperature carbon dioxide electrolysis and the catalytic conversion of carbon monoxide into carbon and carbon dioxide. The low temperature carbon dioxide electrolysis EDU was built by the University of Delaware with Dr. Feng Jiao as the principal investigator in charge of this EDU development (under NASA Contract NNC15CA04C). The carbon monoxide catalytic conversion EDU was built by the NASA Glenn Research Center with Kenneth Burke as the principal investigator and overall project leader for the development of both EDUs. Both EDUs were successfully developed and demonstrated the critical functions for each process. The carbon dioxide electrolysis EDU was delivered to the NASA Johnson Space Center and the carbon monoxide catalytic conversion EDU was delivered to the NASA Marshall Spaceflight Center.

  11. Amine chemistry. Update on impact on resin

    International Nuclear Information System (INIS)

    Bachman, Gregory; Kellogg, Douglas; Wilkes, Marty

    2012-01-01

    Impurity removal in the steam cycle and the associated prevention of corrosion and/or fouling of system components are the goals of ion exchange resins. However, in many instances (such as a switch to amine chemistry or a change in product specifications), resins do not remove, and, in fact, contribute impurities to the steam cycle. This paper reviews recent data compiled to determine the direct and indirect effects of amines on ion exchange resins used in the power industry. Water chemistries have improved in recent years, in large part due to changes in chemistry and resins, but it is necessary to continue to develop products, processes and techniques to reduce impurities and improve overall water chemistry in power plant systems. (orig.)

  12. Amine chemistry. Update on impact on resin

    Energy Technology Data Exchange (ETDEWEB)

    Bachman, Gregory; Kellogg, Douglas [Siemens Industry, Inc., Rockford, IL (United States). Technology and Lab Services; Wilkes, Marty [Siemens Industry, Inc., Rockford, IL (United States). Water Technologies Div.

    2012-03-15

    Impurity removal in the steam cycle and the associated prevention of corrosion and/or fouling of system components are the goals of ion exchange resins. However, in many instances (such as a switch to amine chemistry or a change in product specifications), resins do not remove, and, in fact, contribute impurities to the steam cycle. This paper reviews recent data compiled to determine the direct and indirect effects of amines on ion exchange resins used in the power industry. Water chemistries have improved in recent years, in large part due to changes in chemistry and resins, but it is necessary to continue to develop products, processes and techniques to reduce impurities and improve overall water chemistry in power plant systems. (orig.)

  13. Small Column Ion Exchange

    International Nuclear Information System (INIS)

    Huff, Thomas

    2010-01-01

    Small Column Ion Exchange (SCIX) leverages a suite of technologies developed by DOE across the complex to achieve lifecycle savings. Technologies are applicable to multiple sites. Early testing supported multiple sites. Balance of SRS SCIX testing supports SRS deployment. A forma Systems Engineering Evaluation (SEE) was performed and selected Small Column Ion Exchange columns containing Crystalline Silicotitanate (CST) in a 2-column lead/lag configuration. SEE considered use of Spherical Resorcinol-Formaldehyde (sRF). Advantages of approach at SRS include: (1) no new buildings, (2) low volume of Cs waste in solid form compared to aqueous strip effluent; and availability of downstream processing facilities for immediate processing of spent resin.

  14. Bubble and foam chemistry

    CERN Document Server

    Pugh, Robert J

    2016-01-01

    This indispensable guide will equip the reader with a thorough understanding of the field of foaming chemistry. Assuming only basic theoretical background knowledge, the book provides a straightforward introduction to the principles and properties of foams and foaming surfactants. It discusses the key ideas that underpin why foaming occurs, how it can be avoided and how different degrees of antifoaming can be achieved, and covers the latest test methods, including laboratory and industrial developed techniques. Detailing a variety of different kinds of foams, from wet detergents and food foams, to polymeric, material and metal foams, it connects theory to real-world applications and recent developments in foam research. Combining academic and industrial viewpoints, this book is the definitive stand-alone resource for researchers, students and industrialists working on foam technology, colloidal systems in the field of chemical engineering, fluid mechanics, physical chemistry, and applied physics.

  15. Acidic deposition: State of science and technology. Report 11. Historical changes in surface-water acid-base chemistry in response to acidic deposition. Final report

    International Nuclear Information System (INIS)

    Sullivan, T.J.; Small, M.J.; Kingston, J.C.; Bernert, J.A.; Thomas, D.R.

    1990-09-01

    The objectives of the analyses reported in the State of Science report are to: identify the lake and stream populations in the United States that have experienced chronic changes in biologically significant constituents of surface water chemistry (e.g. pH, Al) in response to acidic deposition; quantify biologically meaningful historical changes in chronic surface water chemistry associated with acidic deposition, with emphasis on ANC, pH, and Al; estimate the proportion of lakes nor acidic that were not acidic in pre-industrial times; estimate the proportional response of each of the major chemical constituents that have changed in response to acidic deposition using a subset of statistically selected Adirondack lakes for which paleolimnological reconstructions of pre-industrial surface water chemistry have been performed; evaluate and improve, where appropriate and feasible, empirical models of predicting changes in ANC; and evaluate the response of seepage lakes to acidic deposition

  16. Acidic deposition: State of science and technology. Report 14. Methods for projecting future changes in surface water acid-base chemistry. Final report

    International Nuclear Information System (INIS)

    Thornton, K.W.; Marmorek, D.; Ryan, P.F.; Heltcher, K.; Robinson, D.

    1990-09-01

    The objectives of the report are to: critically evaluate methods for projecting future effects of acidic deposition on surface water acid-base chemistry; review and evaluate techniques and procedures for analyzing projection uncertainty; review procedures for estimating regional lake and stream population attributes; review the U.S. Environmental Protection Agency (EPA) Direct/Delayed Response Project (DDRP) methodology for projecting the effects of acidic deposition on future changes in surface water acid-base chemistry; and present the models, uncertainty estimators, population estimators, and proposed approach selected to project the effects of acidic deposition on future changes in surface water acid-base chemistry in the NAPAP 1990 Integrated Assessment and discuss the selection rationale

  17. Theoretical chemistry periodicities in chemistry and biology

    CERN Document Server

    Eyring, Henry

    1978-01-01

    Theoretical Chemistry: Periodicities in Chemistry and Biology, Volume 4 covers the aspects of theoretical chemistry. The book discusses the stably rotating patterns of reaction and diffusion; the chemistry of inorganic systems exhibiting nonmonotonic behavior; and population cycles. The text also describes the mathematical modeling of excitable media in neurobiology and chemistry; oscillating enzyme reactions; and oscillatory properties and excitability of the heart cell membrane. Selected topics from the theory of physico-chemical instabilities are also encompassed. Chemists, mechanical engin

  18. PWR secondary water chemistry study

    International Nuclear Information System (INIS)

    Pearl, W.L.; Sawochka, S.G.

    1977-02-01

    Several types of corrosion damage are currently chronic problems in PWR recirculating steam generators. One probable cause of damage is a local high concentration of an aggressive chemical even though only trace levels are present in feedwater. A wide variety of trace chemicals can find their way into feedwater, depending on the sources of condenser cooling water and the specific feedwater treatment. In February 1975, Nuclear Water and Waste Technology Corporation (NWT), was contracted to characterize secondary system water chemistry at five operating PWRs. Plants were selected to allow effects of cooling water chemistry and operating history on steam generator corrosion to be evaluated. Calvert Cliffs 1, Prairie Island 1 and 2, Surry 2, and Turkey Point 4 were monitored during the program. Results to date in the following areas are summarized: (1) plant chemistry variations during normal operation, transients, and shutdowns; (2) effects of condenser leakage on steam generator chemistry; (3) corrosion product transport during all phases of operation; (4) analytical prediction of chemistry in local areas from bulk water chemistry measurements; and (5) correlation of corrosion damage to chemistry variation

  19. Solution chemistry

    Energy Technology Data Exchange (ETDEWEB)

    None

    1973-07-01

    Research progress is reported on studies in heavy element chemistry. Topics considered are: synergistic complexes of plutonyl ion; water uptake in synergistic systems; formation constants of some uranyl BETA -diketone complexes; thermodynamic acid dissociation constants of BETA -diketones; thermodynamic formation constants of uranyl BETA -diketonates; thiocyanate complexes of some trivalent lanthanides and actinides; stability constants of actinide complexes using dinonyl naphthalenesulfonic acid extraction; TBP extraction of actinides; stability constants of complexes of Pu(III) with 5- sulfosalicycllc acid; and solvent extraction behavior of Pu( VII). (DHM)

  20. Interstellar chemistry.

    Science.gov (United States)

    Klemperer, William

    2006-08-15

    In the past half century, radioastronomy has changed our perception and understanding of the universe. In this issue of PNAS, the molecular chemistry directly observed within the galaxy is discussed. For the most part, the description of the molecular transformations requires specific kinetic schemes rather than chemical thermodynamics. Ionization of the very abundant molecular hydrogen and atomic helium followed by their secondary reactions is discussed. The rich variety of organic species observed is a challenge for complete understanding. The role and nature of reactions involving grain surfaces as well as new spectroscopic observations of interstellar and circumstellar regions are topics presented in this special feature.

  1. Separations chemistry

    International Nuclear Information System (INIS)

    Anon.

    1976-01-01

    Results of studies on the photochemistry of aqueous Pu solutions and the stability of iodine in liquid and gaseous CO 2 are reported. Progress is reported in studies on: the preparation of macroporous bodies filled with oxides and sulfides to be used as adsorbents; the beneficiation of photographic wastes; the anion exchange adsorption of transition elements from thiosulfate solutions; advanced filtration applications of energy significance; high-resolution separations; and, the examination of the separation agents, octylphenylphosphoric acid (OPPA) and trihexyl phosphate (THP)

  2. Specific processes and scrambling in the dehydrogenation of ethane and the degenerate hydrogen exchange in the gas-phase ion chemistry of the Ni(C,H3,O)+/C2H6 couple

    Czech Academy of Sciences Publication Activity Database

    Schlangen, M.; Schwarz, H.; Schröder, Detlef

    2007-01-01

    Roč. 90, č. 5 (2007), s. 847-853 ISSN 0018-019X Institutional research plan: CEZ:AV0Z40550506 Keywords : alkoxides * C-H activation * gas-phase investigations * mass spectrometry * nicel Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.515, year: 2007

  3. Optimum coolant chemistry in BWRs

    International Nuclear Information System (INIS)

    Lin, C.C.; Cowan, R.L.; Kiss, E.

    2004-01-01

    LWR water chemistry parameters are directly or indirectly related to the plant's operational performance and for a significant amount of Operation and Maintenance (O and M) costs. Obvious impacts are the operational costs associated with water treatment, monitoring and associated radwaste generation. Less obvious is the important role water chemistry plays in the magnitude of drywell shutdown dose rates, fuel corrosion performance and, (probably most importantly) materials degradation such as from stress corrosion cracking of piping and Reactor Pressure Vessel (RPV) internal components. To improve the operational excellence of the BWR and to minimize the impact of water chemistry on O and M costs. General Electric has developed the concept of Optimum Water Chemistry (OWC). The 'best practices' and latest technology findings from the U.S., Asia and Europe are integrated into the suggested OWC Specification. This concept, together with cost effective ways to meet the requirement, are discussed. (author)

  4. Fiscal 2000 survey of geological structures overseas. Exchange of engineers with Indonesia (Coal mining technology); 2000 nendo kaigai chishitsu kozo nado chosa hokokusho. Gijutsusha koryu jigyo (tanko gijutsu bun'ya) Indonesia

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Indonesia rich in coal resources consumed 70-million tons of coal in 1999, which covered 17% of its total energy demand. It is estimated that as much as 120-million tons will be produced in 2005, and it is expected that underground mining will increase. Under such circumstances, Indonesia strongly desires that Japan's underground mining technologies be transferred to Indonesia. For the transfer of technologies especially involving production control and management out of Japan's underground mining technologies, Japan dispatched engineers to Indonesia under a mining engineer exchange project, and received and trained Indonesian engineers. Under the engineer exchange project, five engineers were dispatched to Indonesia and gave lectures and on-site training in the period July 9 through August 5, 2000. Japan received seven engineers, who were given lectures and training at the Ikeshima mining field of Matsushima Coal Mining Company in the period November 12 through December 12, 2000. (NEDO)

  5. Technical engineers exchange project (coal mine technology field). Training in China; Gijutsusha koryu jigyo (tanko gijutsu bun`ya). Chugoku no kenshu ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Adachi, T. [Japan Coal Energy Center, Tokyo (Japan)

    1998-07-01

    The paper described JCOAL`s project on the exchange of technical coal engineers of China. In the project on sending of engineers to China in the first term, coal mine engineers of Japan (Taiheiyo Coal Mine, Kushiro Works, Training Center) were sent to the Daitun coal-thermal power plant, Peixuan city, Jiangsu province, in September, 1997 to introduce the production control technology in Japan. They contributed to the heightening of productivity in coal mines in China. Eighteen Chinese participated in the training. Mechanization has been comparatively well in progress, and it was 83% in coal mining and 91% in drilling. The kind of coal is mostly a raw material coal. The stuff members are 30,000, and expert engineers are 4,200. The plant has an output of 130,000 kWh, owns its railroad, is run on the general multiple management, and is largely developing. The project on sending of engineers to China in the last term was carried out in February 1998 for tracing/confirming how the results of the training conducted in September are made the most of and if or not there is something bad and for obtaining the detailed data. A certain degree of promotion and effects were able to be confirmed. A project on training of the head, sub-head, etc. who were invited to Japan to lean production/management control was also carried out in November and December 1997. 1 tab.

  6. Industrial ecology: Environmental chemistry and hazardous waste

    Energy Technology Data Exchange (ETDEWEB)

    Manahan, S.E. [Univ. of Missouri, Columbia, MO (United States). Dept. of Chemistry

    1999-01-01

    Industrial ecology may be a relatively new concept -- yet it`s already proven instrumental for solving a wide variety of problems involving pollution and hazardous waste, especially where available material resources have been limited. By treating industrial systems in a manner that parallels ecological systems in nature, industrial ecology provides a substantial addition to the technologies of environmental chemistry. Stanley E. Manahan, bestselling author of many environmental chemistry books for Lewis Publishers, now examines Industrial Ecology: Environmental Chemistry and Hazardous Waste. His study of this innovative technology uses an overall framework of industrial ecology to cover hazardous wastes from an environmental chemistry perspective. Chapters one to seven focus on how industrial ecology relates to environmental science and technology, with consideration of the anthrosphere as one of five major environmental spheres. Subsequent chapters deal specifically with hazardous substances and hazardous waste, as they relate to industrial ecology and environmental chemistry.

  7. Radiation chemistry and bioradical chemistry

    International Nuclear Information System (INIS)

    Ferradini, C.

    1991-01-01

    Oxygen metabolism results, at the cellular level, in the formation of superoxyde radical O 2 - · and probably also of hydroxyl radical OH·. Other radical species can be produced from exogenous or endogenous molecules and nearly all of them have the possibility to react with oxygen giving peroxyradicals. Some of these transients play a role in various biological processes such as phagocytosis, inflammation or ischemy although the mechanisms invoked are poorly understood. Radiation chemistry is an invaluable tool for obtaining a quantitative view of these mechanisms. A description is given of this interaction [fr

  8. Abstracts of the 3. Brazilian Meeting on Analytical Chemistry

    International Nuclear Information System (INIS)

    1985-01-01

    Abstracts from experimental research works on analytical chemistry are presented. The following techniques were mainly used: differential pulse polarography, atomic absorption spectrophotometry, ion exchange chromatography and gamma spectroscopy. (C.L.B.) [pt

  9. Presidential Green Chemistry Challenge: 2012 Greener Reaction Conditions Award

    Science.gov (United States)

    Presidential Green Chemistry Challenge 2012 award winner, Cytec Industries, developed the MAX HT sodalite scale inhibitor for heat exchangers and pipes in the Bayer process, which converts bauxite into alumina.

  10. Fundamentals of nuclear chemistry

    International Nuclear Information System (INIS)

    Majer, K.

    1982-01-01

    The textbook is a Czech-to-German translation of the second revised edition and covers the subject under the headings: general nuclear chemistry, methods of nuclear chemistry, preparative nuclear chemistry, analytical nuclear chemistry, and applied chemistry. The book is especially directed to students

  11. Application of a weak base anion exchange resin for recovery of uranium at Uravan, Colorado, U.S.A

    International Nuclear Information System (INIS)

    Gardner, N.E.; Kunin, R.

    1976-01-01

    Resin ion-exchange technology has been used to recover uranium at the Uravan, Colorado plant for over 18 years; however, since the end of U.S. Atomic Energy Commission purchase of U 3 O 8 concentrate in 1970, it has become necessary to develop techniques for upgrading the product to meet the more stringent specifications of private sales. The standard gel type quaternary ammonium anion exchange resin had been used previously. The development of the tertiary amine anion exchange resin, Amberlite XE-299, led to an experimental program of laboratory and pilot plant work to evaluate the resin on actual plant solutions. General information on ion-exchange resin structure and chemistry is discussed. Summary data of specific test work on loading the resin, various elution schemes, resin regeneration and product purity from the pilot plant tests and comments on actual plant operation using Amberlite XE-299 resin are presented. (author)

  12. Educators Exchange: A Program Evaluation.

    Science.gov (United States)

    Armstrong, William B.

    The Educators Exchange Program (EEP) was established under a training and educational exchange agreement reached by California's San Diego Community College District (SDCCD) and the republic of Mexico. In the program, the District provided a 4-week technological training program to faculty at Centros de Capacitacion Tecnologica Industrial…

  13. Advances in BWR water chemistry

    International Nuclear Information System (INIS)

    Garcia, Susan E.; Giannelli, Joseph F.; Jarvis, Mary L.

    2012-09-01

    This paper reviews recent advances in Boiling Water Reactor (BWR) water chemistry control with examples of plant experiences at U.S. designed BWRs. Water chemistry advances provide some of the most effective methods for mitigating materials degradation, reducing fuel performance concerns and lowering radiation fields. Mitigation of stress corrosion cracking (SCC) of materials remains a high priority and improved techniques that have been demonstrated in BWRs will be reviewed, specifically hydrogen injection combined with noble metal chemical addition (NMCA) and the newer on-line noble metal application process (OLNC). Hydrogen injection performance, an important part of SCC mitigation, will also be reviewed for the BWR fleet, highlighting system improvements that have enabled earlier injection of hydrogen including the potential for hydrogen injection during plant startup. Water chemistry has been significantly improved by the application of pre-filtration and optimized use of ion exchange resins in the CP (condensate polishing) and reactor water cleanup (RWCU) systems. EPRI has monitored and supported water treatment improvements to meet water chemistry goals as outlined in the EPRI BWR Water Chemistry Guidelines, particularly those for SCC mitigation of reactor internals and piping, minimization of fuel risk due to corrosion and crud deposits and chemistry control for radiation field reduction. In recent years, a significant reduction has occurred in feedwater corrosion product input, particularly iron. A large percentage of plants are now reporting <0.1 ppb feedwater iron. The impacts to plant operation and chemistry of lower feedwater iron will be explored. Depleted zinc addition is widely practiced across the fleet and the enhanced focus on radiation reduction continues to emphasize the importance of controlling radiation source term. In addition, shutdown chemistry control is necessary to avoid excessive release of activated corrosion products from fuel

  14. School Chemistry: The Need for Transgression

    Science.gov (United States)

    Talanquer, Vicente

    2013-01-01

    Studies of the philosophy of chemistry over the past 15 years suggest that chemistry is a hybrid science which mixes scientific pursuits with technological applications. Dominant universal characterizations of the nature of science thus fail to capture the essence of the discipline. The central goal of this position paper is to encourage…

  15. American Chemical Society, Division of Environmental Chemistry

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    Separate abstracts were prepared for 161 papers of this divisional meeting for the US Department of Energy's Database. Main topics discussed included: acid rain mitigation - liming technologies and environmental considerations; biotechnology for wastewater treatment; environmental chemistry of lakes and reservoirs and pollution prevention and process analytical chemistry

  16. Cyclodextrin chemistry

    International Nuclear Information System (INIS)

    Khan, M.Z.; Chuaqui, C.A.

    1990-05-01

    The chemistry of cyclodextrins was studied. This study included synthesising some cyclodextrin derivatives, preparing selected inclusion complexes with cyclodextrin and investigating the effects of gamma irradiation on cyclodextrins and certain linear oligosaccharides. This report presents a brief review of the structure and properties of cyclodextrins, the synthesis of cyclodextrin derivatives, their complexation and applications. This is followed by a description of the synthesis of some cyclodextrin derivatives and the preparation of inclusion complexes of cyclodextrin with some organic compounds. Finally, the effects of gamma irradiation on cyclodextrins, some of their derivatives and certain structurally related carbohydrates are discussed. The gamma irradiation studies were carried out for two reasons: to study the effects of gamma irradiation on cyclodextrins and their derivatives; and to investigate selectivity during the gamma irradiation of cyclodextrin derivatives

  17. Astronomical chemistry.

    Science.gov (United States)

    Klemperer, William

    2011-01-01

    The discovery of polar polyatomic molecules in higher-density regions of the interstellar medium by means of their rotational emission detected by radioastronomy has changed our conception of the universe from essentially atomic to highly molecular. We discuss models for molecule formation, emphasizing the general lack of thermodynamic equilibrium. Detailed chemical kinetics is needed to understand molecule formation as well as destruction. Ion molecule reactions appear to be an important class for the generally low temperatures of the interstellar medium. The need for the intrinsically high-quality factor of rotational transitions to definitively pin down molecular emitters has been well established by radioastronomy. The observation of abundant molecular ions both positive and, as recently observed, negative provides benchmarks for chemical kinetic schemes. Of considerable importance in guiding our understanding of astronomical chemistry is the fact that the larger molecules (with more than five atoms) are all organic.

  18. Reburning chemistry

    International Nuclear Information System (INIS)

    Kilpin, P.; Hupa, M.; Glarborg, P.

    1992-01-01

    No reduction chemistry in natural gas (methane) reburning was studied using detailed kinetic modeling. A reaction set including 225 reversible elementary gas-phase reactions and 48 chemical species was applied to an ideal plug flow reactor, and the most important reactions leading to NO reduction were identified and quantified for a number of conditions relevant for natural gas reburning. In addition, the influence of different process parameters on the NO reduction was investigated in the reburn zone and burn-out zone, respectively. Further, comparison of the calculations to available laboratory-scale data on reburning is made. In this paper, the impact of various fluid dynamic, mixing, and chemical effects---not accounted for in the calculations---on the NO reduction and the optimum reburning conditions predicted is discussed

  19. Combustion chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Brown, N.J. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  20. Dynamic combinatorial chemistry with diselenides and disulfides in water

    DEFF Research Database (Denmark)

    Rasmussen, Brian; Sørensen, Anne; Gotfredsen, Henrik

    2014-01-01

    Diselenide exchange is introduced as a reversible reaction in dynamic combinatorial chemistry in water. At neutral pH, diselenides are found to mix with disulfides and form dynamic combinatorial libraries of diselenides, disulfides, and selenenylsulfides. This journal is......Diselenide exchange is introduced as a reversible reaction in dynamic combinatorial chemistry in water. At neutral pH, diselenides are found to mix with disulfides and form dynamic combinatorial libraries of diselenides, disulfides, and selenenylsulfides. This journal is...

  1. Heat exchanger

    International Nuclear Information System (INIS)

    Leigh, D.G.

    1976-01-01

    The arrangement described relates particularly to heat exchangers for use in fast reactor power plants, in which heat is extracted from the reactor core by primary liquid metal coolant and is then transferred to secondary liquid metal coolant by means of intermediate heat exchangers. One of the main requirements of such a system, if used in a pool type fast reactor, is that the pressure drop on the primary coolant side must be kept to a minimum consistent with the maintenance of a limited dynamic head in the pool vessel. The intermediate heat exchanger must also be compact enough to be accommodated in the reactor vessel, and the heat exchanger tubes must be available for inspection and the detection and plugging of leaks. If, however, the heat exchanger is located outside the reactor vessel, as in the case of a loop system reactor, a higher pressure drop on the primary coolant side is acceptable, and space restriction is less severe. An object of the arrangement described is to provide a method of heat exchange and a heat exchanger to meet these problems. A further object is to provide a method that ensures that excessive temperature variations are not imposed on welded tube joints by sudden changes in the primary coolant flow path. Full constructional details are given. (U.K.)

  2. The aqueous chemistry of oxides

    CERN Document Server

    Bunker, Bruce C

    2016-01-01

    The Aqueous Chemistry of Oxides is a comprehensive reference volume and special topics textbook that explores all of the major chemical reactions that take place between oxides and aqueous solutions. The book highlights the enormous impact that oxide-water reactions have in advanced technologies, materials science, geochemistry, and environmental science.

  3. Proceedings of the third international steam generator and heat exchanger conference

    International Nuclear Information System (INIS)

    1998-01-01

    The Third International Steam Generator and Heat Exchanger conference had the objective to present the state of knowledge of steam generator performance and life management, and also heat exchanger technology. As this conference followed on from the previous conferences held in Toronto in 1990 and 1994, the emphasis was on recent developments, particularly those of the last 4 years. The conference provided an opportunity to operators, designers and researchers in the field of steam generation associated with electricity generation by nuclear energy to present their findings and exchange ideas. The conference endeavoured to do this over the widest possible range of subject areas, including: general operating experience, life management and fitness for service strategies, maintenance and inspection, thermalhydraulics, vibration, fretting and fatigue, materials, chemistry and corrosion and the regulatory issues

  4. Proceedings of the third international steam generator and heat exchanger conference

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-07-01

    The Third International Steam Generator and Heat Exchanger conference had the objective to present the state of knowledge of steam generator performance and life management, and also heat exchanger technology. As this conference followed on from the previous conferences held in Toronto in 1990 and 1994, the emphasis was on recent developments, particularly those of the last 4 years. The conference provided an opportunity to operators, designers and researchers in the field of steam generation associated with electricity generation by nuclear energy to present their findings and exchange ideas. The conference endeavoured to do this over the widest possible range of subject areas,including: general operating experience, life management and fitness for service strategies, maintenance and inspection, thermalhydraulics, vibration, fretting and fatigue, materials, chemistry and corrosion and the regulatory issues.

  5. Actinide separative chemistry

    International Nuclear Information System (INIS)

    Boullis, B.

    2004-01-01

    Actinide separative chemistry has focused very heavy work during the last decades. The main was nuclear spent fuel reprocessing: solvent extraction processes appeared quickly a suitable, an efficient way to recover major actinides (uranium and plutonium), and an extensive research, concerning both process chemistry and chemical engineering technologies, allowed the industrial development in this field. We can observe for about half a century a succession of Purex plants which, if based on the same initial discovery (i.e. the outstanding properties of a molecule, the famous TBP), present huge improvements at each step, for a large part due to an increased mastery of the mechanisms involved. And actinide separation should still focus R and D in the near future: there is a real, an important need for this, even if reprocessing may appear as a mature industry. We can present three main reasons for this. First, actinide recycling appear as a key-issue for future nuclear fuel cycles, both for waste management optimization and for conservation of natural resource; and the need concerns not only major actinide but also so-called minor ones, thus enlarging the scope of the investigation. Second, extraction processes are not well mastered at microscopic scale: there is a real, great lack in fundamental knowledge, useful or even necessary for process optimization (for instance, how to design the best extracting molecule, taken into account the several notifications and constraints, from selectivity to radiolytic resistivity?); and such a need for a real optimization is to be more accurate with the search of always cheaper, cleaner processes. And then, there is room too for exploratory research, on new concepts-perhaps for processing quite new fuels- which could appear attractive and justify further developments to be properly assessed: pyro-processes first, but also others, like chemistry in 'extreme' or 'unusual' conditions (supercritical solvents, sono-chemistry, could be

  6. Optimization of Water Chemistry to Ensure Reliable Water Reactor Fuel Performance at High Burnup and in Ageing Plant (FUWAC)

    International Nuclear Information System (INIS)

    2011-10-01

    This report presents the results of the Coordinated Research Project (CRP) on Optimization of Water Chemistry to Ensure Reliable Water Reactor Fuel Performance at High Burnup and in Ageing Plants (FUWAC, 2006-2009). It provides an overview of the results of the investigations into the current state of water chemistry practice and concerns in the primary circuit of water cooled power reactors including: corrosion of primary circuit materials; deposit composition and thickness on the fuel; crud induced power shift; fuel oxide growth and thickness; radioactivity buildup in the reactor coolant system (RCS). The FUWAC CRP is a follow-up to the DAWAC CRP (Data Processing Technologies and Diagnostics for Water Chemistry and Corrosion Control in Nuclear Power Plants 2001-2005). The DAWAC project improved the data processing technologies and diagnostics for water chemistry and corrosion control in nuclear power plants (NPPs). With the improved methods for controlling and monitoring water chemistry now available, it was felt that a review of the principles of water chemistry management should be undertaken in the light of new materials, more onerous operating conditions, emergent issues such as CIPS, also known as axial offset anomaly (AOA) and the ageing of operating power plant. In the framework of this CRP, water chemistry specialists from 16 nuclear utilities and research organizations, representing 15 countries, exchanged experimental and operational data, models and insights into water chemistry management. The CD-ROM attached to this IAEA-TECDOC includes the report itself, detailed progress reports of three Research Coordination Meetings (RCMs) (Annexes I-III) and the reports and presentations made during the project by the participants.

  7. Why Teach Environmental Chemistry?

    Science.gov (United States)

    Gardner, Marjorie H.

    1974-01-01

    Discusses the importance of teaching environmental chemistry in secondary school science classes, and outlines five examples of environmental chemistry problems that focus on major concepts of chemistry and have critical implications for human survival and well-being. (JR)

  8. PWR secondary water chemistry diagnostic system

    International Nuclear Information System (INIS)

    Miyazaki, S.; Hattori, T.; Yamauchi, S.; Kato, A.; Suganuma, S.; Yoshikawa, T.

    1989-01-01

    Water chemistry control is one of the most important tasks in order to maintain the reliability of plant equipments and extend operating life of the plant. We developed an advanced water chemistry management system which is able to monitor and diagnose secondary water chemistry. A prototype system had been installed at one plant in Japan since Nov. 1986 in order to evaluate system performance and man-machine interface. The diagnosis system has been successfully tested off line using synthesized plant data for various cases. We are continuing to improve the applicability and develop new technology which make it evaluate steam generator crevice chemistry. (author)

  9. Environmental chemistry. Seventh edition

    Energy Technology Data Exchange (ETDEWEB)

    Manahan, S.E. [Univ. of Missouri, Columbia, MO (United States)

    1999-11-01

    This book presents a basic understanding of environmental chemistry and its applications. In addition to providing updated materials in this field, the book emphasizes the major concepts essential to the practice of environmental chemistry. Topics of discussion include the following: toxicological chemistry; toxicological chemistry of chemical substances; chemical analysis of water and wastewater; chemical analysis of wastes and solids; air and gas analysis; chemical analysis of biological materials and xenobiotics; fundamentals of chemistry; and fundamentals of organic chemistry.

  10. Promotional operation for developing industrial technologies for global environment in fiscal 1998. International research exchange operation; 1998 nendo chikyu kankyo sangyo gijutsu kaihatsu suishin jigyo. Kokusai kenkyu koryu jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    With an objective of creating a new scope of study intended of solving global environment problems and structuring a new technical system, exchanges with overseas researchers and research institutions have been carried out subsequent to those in last year. In fiscal 1998, six researchers from different countries were invited to implement joint researches, and two overseas researchers were invited to an international conference on industrial technologies for global environment. In addition, in order to identify trends of research and development in overseas countries, two researchers were sent to universities in Germany and the U.S.A., and three researchers to international conferences and symposiums on the industrial technologies for global environment. It was intended to exchange technological information between overseas researchers and Japanese researchers who are performing the advanced researches on the industrial technologies for global environment, and to proliferate the latest items of technological information. Therefore, seven international seminars have been held, including the '98 Japan-China Global Environment Protection Symposium, 'substance migration and carbon circulation in coral reefs', 'plant bio-technologies in the 21st century', and the Fourth International Forum for Environmental Catalysts. (NEDO)

  11. Promotional operation for developing industrial technologies for global environment in fiscal 1998. International research exchange operation; 1998 nendo chikyu kankyo sangyo gijutsu kaihatsu suishin jigyo. Kokusai kenkyu koryu jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    With an objective of creating a new scope of study intended of solving global environment problems and structuring a new technical system, exchanges with overseas researchers and research institutions have been carried out subsequent to those in last year. In fiscal 1998, six researchers from different countries were invited to implement joint researches, and two overseas researchers were invited to an international conference on industrial technologies for global environment. In addition, in order to identify trends of research and development in overseas countries, two researchers were sent to universities in Germany and the U.S.A., and three researchers to international conferences and symposiums on the industrial technologies for global environment. It was intended to exchange technological information between overseas researchers and Japanese researchers who are performing the advanced researches on the industrial technologies for global environment, and to proliferate the latest items of technological information. Therefore, seven international seminars have been held, including the '98 Japan-China Global Environment Protection Symposium, 'substance migration and carbon circulation in coral reefs', 'plant bio-technologies in the 21st century', and the Fourth International Forum for Environmental Catalysts. (NEDO)

  12. Exchange Network

    Science.gov (United States)

    The Environmental Information Exchange Network (EN) is an Internet-based system used by state, tribal and territorial partners to securely share environmental and health information with one another and EPA.

  13. Biomolecular Sciences: uniting Biology and Chemistry

    NARCIS (Netherlands)

    Vrieling, Engel

    2017-01-01

    Biomolecular Sciences: uniting Biology and Chemistry www.rug.nl/research/gbb The scientific discoveries in biomolecular sciences have benefitted enormously from technological innovations. At the Groningen Biomolecular Science and Biotechnology Institute (GBB) we now sequence a genome in days,

  14. USSR Report Chemistry

    National Research Council Canada - National Science Library

    1986-01-01

    Contents: Adsorption, Chemistry,Alkaloids, Analytical Chemistry, Catalysis,Chemical Industry,,Coal Gasification, Combustion, Electrochemistry,Explosives and Explosions, Fertilizers, Free Radicals, Inorganic...

  15. Biophysical chemistry

    International Nuclear Information System (INIS)

    Klein, M.P.

    1987-01-01

    Phosphorus-31 NMR spectroscopy is evolving into an important means for determining the in vivo concentrations of phosphorylated metabolites and is now entering the clinical arena. Our previous contributions to this field demonstrated the feasibility of employing implanted radio frequency coils around organs of laboratory animals to permit eliciting the NMR spectra over long periods to establish normative spectra. Using these devices and techniques we have determined phosphorus exchange reactions in rat hearts and kidney, in situ, and have demonstrated that there are pools of metabolic intermediates that are not directly visible in the conventional high resolution NMR spectra. Comparison of the results from NMR spectroscopy with those obtained from radiolabeling studies on chick embryo fibroblasts also showed that there are significant pools of phosphorus not visible in the P-31 NMR spectrum. Both sets of studies suggest that compartmentation occurs. The invisibility of these pools is assumed to result from the immobilization of the molecules by cellular macromolecules or organelles

  16. Where is the future of nuclear chemistry

    International Nuclear Information System (INIS)

    1980-01-01

    The future potentials of nuclear chemistry as a natural science with a strong orientation towards practical applications has been discussed at this meeting of 45 experts coming from research institutes and laboratories working in the fields of radiochemistry, nuclear chemistry, inorganic and applied chemistry, hot-atom chemistry, radiobiology, and nuclear biology, and from the two nuclear research centres at Juelich and Karlsruhe. The discussion centred around the four main aspects of future work, namely 1. basic research leading to an extension of the periodic table, nuclear reactions, the chemistry of superheavy elements, cosmochemistry; 2. radionuclide technology and activation analysis; 3. nuclear fuel cycle and reprocessing processes together with ultimate disposal methods; 4. radiochemistry in the life sciences, including nuclear chemistry and applications. (HK) [de

  17. Water chemistry

    International Nuclear Information System (INIS)

    Hofstetter, K.J.; Baston, V.F.

    1986-01-01

    Prior to the accident, the coolants in the primary and secondary systems were within normal chemistry specifications for an operating pressurized water reactor with once-through steam generators. During and immediately after the accident, additional boric acid and sodium hydroxide were added to the primary coolant for control of criticality and radioiodine solubility. A primary to secondary leak developed contaminating the water in one steam generator. For about 5 years after the accident, the primary coolant was maintained at 3800 +. 100 ppm boron and 1000 +. 100 ppm sodium concentrations. Dissolved oxygen was maintained 7.5, corrosion caused by increased dissolved oxygen levels (up to 8 ppm) and higher chloride ion content (up to 5 ppm) is minimized. Chemical control of dissolved oxygen was discontinued and the coolant was processed. Prior to removal of the reactor vessel head, the boron concentration in the coolant was increased to ≅ 5000 ppm to support future defueling operations. Decontamination of the accident generated water is described in terms of contaminated water management. In addition, the decontamination and chemical lay-up conditions for the secondary system are presented along with an overview of chemical management at TMI-2

  18. Migration chemistry

    International Nuclear Information System (INIS)

    Carlsen, L.

    1992-05-01

    Migration chemistry, the influence of chemical -, biochemical - and physico-chemical reactions on the migration behaviour of pollutants in the environment, is an interplay between the actual natur of the pollutant and the characteristics of the environment, such as pH, redox conditions and organic matter content. The wide selection of possible pollutants in combination with varying geological media, as well as the operation of different chemical -, biochemical - and physico-chemical reactions compleactes the prediction of the influence of these processes on the mobility of pollutants. The report summarizes a wide range of potential pollutants in the terrestrial environment as well as a variety of chemical -, biochemical - and physico-chemical reactions, which can be expected to influence the migration behaviour, comprising diffusion, dispersion, convection, sorption/desorption, precipitation/dissolution, transformations/degradations, biochemical reactions and complex formation. The latter comprises the complexation of metal ions as well as non-polar organics to naturally occurring organic macromolecules. The influence of the single types of processes on the migration process is elucidated based on theoretical studies. The influence of chemical -, biochemical - and physico-chemical reactions on the migration behaviour is unambiguous, as the processes apparently control the transport of pollutants in the terrestrial environment. As the simple, conventional K D concept breaks down, it is suggested that the migration process should be described in terms of the alternative concepts chemical dispersion, average-elution-time and effective retention. (AB) (134 refs.)

  19. Presidential Green Chemistry Challenge: 2004 Greener Reaction Conditions Award

    Science.gov (United States)

    Presidential Green Chemistry Challenge 2004 award winner, Buckman Laboratories International, developed Optimyze technology, which uses an esterase enzyme to remove sticky contaminants from paper products prior to recycling.

  20. Presidential Green Chemistry Challenge: 2007 Greener Reaction Conditions Award

    Science.gov (United States)

    Presidential Green Chemistry Challenge 2007 award winner, Headwaters Technology Innovation, developed a metal nanocatalyst to synthesize hydrogen peroxide directly from hydrogen and oxygen, eliminating hazardous chemicals.

  1. Diverse applications of radiation chemistry

    International Nuclear Information System (INIS)

    Cooper, R.

    1998-01-01

    Radiation chemistry began as early radiotherapists needed a reliable and appropriate dosimeter. The iron sulphate dosimeter, using ferrous iron in sulphuric acid and oxidation by irradiation, was a nasty brew of chemicals but it was sensitive, reliable and conveniently had the same density as human tissue. Water irradiation chemistry studies were driven by the need to understand the fundamental processes in radiotherapy; to control the corrosion problems in the cooling/ heat exchange systems of nuclear reactors and to find stable solvents and reagents for use in spent fuel element processing. The electrical and mechanical stability of materials in high radiation fields stimulated the attention of radiation chemists to the study of defects in solids. The coupled use of radiation and Electron Spin Resonance (ESR) enabled the identity of defect structures to be probed. This research led to the development of the sensitive Thermoluminescent Dosimeters, TLD's and a technique for dating of archaeological pottery artefacts. Radiation chemistry in the area of medicine is very active with fundamental studies of the mechanism of DNA strand breakage and the development of radiation sensitisers and protectors for therapeutic purposes. The major area of polymer radiation chemistry is one which Australia commands great international respect

  2. Abstracts of the 16. Latin-American Congress of Chemistry

    International Nuclear Information System (INIS)

    1984-01-01

    Abstracts of experimental works on analytical chemistry, physical-chemistry, medical chemistry and technology of chemical processes are presented. Those papers dealing with the application of nuclear techniques for the analysis of various substances and also those concerned with the study of materials and/or elements of nuclear interest, are indexed. (C.L.B.) [pt

  3. Humanizing Chemistry Education: From Simple Contextualization to Multifaceted Problematization

    Science.gov (United States)

    Sjöström, Jesper; Talanquer, Vicente

    2014-01-01

    Chemistry teaching has traditionally been weakly connected to everyday life, technology, society, and history and philosophy of science. This article highlights knowledge areas and perspectives needed by the humanistic (and critical-reflexive) chemistry teacher. Different humanistic approaches in chemistry teaching, from simple contextualization…

  4. Medicinal electrochemistry: integration of electrochemistry, medicinal chemistry and computational chemistry.

    Science.gov (United States)

    Almeida, M O; Maltarollo, V G; de Toledo, R A; Shim, H; Santos, M C; Honorio, K M

    2014-01-01

    Over the last centuries, there were many important discoveries in medicine that were crucial for gaining a better understanding of several physiological processes. Molecular modelling techniques are powerful tools that have been successfully used to analyse and interface medicinal chemistry studies with electrochemical experimental results. This special combination can help to comprehend medicinal chemistry problems, such as predicting biological activity and understanding drug action mechanisms. Electrochemistry has provided better comprehension of biological reactions and, as a result of many technological improvements, the combination of electrochemical techniques and biosensors has become an appealing choice for pharmaceutical and biomedical analyses. Therefore, this review will briefly outline the present scope and future advances related to the integration of electrochemical and medicinal chemistry approaches based on various applications from recent studies.

  5. Inorganic ion-exchangers. Their role in chromatographic radionuclide generators for the decade 1993-2002

    International Nuclear Information System (INIS)

    Mushtaq, A.

    2004-01-01

    Ion-exchangers are found not only in water purification processes, the original major application, but also in analytical chemistry for the separation and isolation of elements, hydrometallurgy, inorganic chemistry and biochemistry, in food technology, and of course in many specialized fields related to the utilization of atomic energy. The use of organic ion-exchangers is limited by virtue of their limited stability under harsh conditions, whereas inorganic ion-exchangers possess important properties, which make them very useful for chemical separation and purification in intense radiation fields. The availability of short-lived radionuclides from radionuclide generators provides an inexpensive and convenient alternative to in-house radioisotope production facilities such as accelerators and cyclotrons. Due to their simplicity of operation, chromatographic based generators have been the method of choice, although generators based on solvent extraction and on volatilization and sublimation have also been developed, and are routinely used. In this paper use of inorganic ion-exchangers for the development of radionuclide generators for the decade 1993-2002 has been compiled. (author)

  6. Radionuclide separations in the nuclear fuel cycle development and application of micro and meso porous inorganic ion-exchangers

    International Nuclear Information System (INIS)

    Griffith, C.S.; Luca, V.

    2006-01-01

    Full text: Full text: From the mining of uranium-containing ores to the reprocessing of spent nuclear fuel, separations technologies play a crucial role in determining the efficiency and viability of the nuclear fuel cycle. With respect to proposed Advanced Nuclear Fuel Cycles (ANFC), the integral role of separations is no different with solvent extraction and pyroelectrometalurgical processing dominating efforts to develop a sustainable and publicly acceptable roadmap for nuclear power in the next 100 years. An often forgotten or overlooked separation technology is ion-exchange, more specifically, inorganic ion-exchangers. This is despite the fact that these materials offer the potential advantages of process simplicity; exceptional selectivity against high background concentrations of competing ions; and the possibility of a simple immobilization route for the separated radionculides. ANSTO's principal interest in inorganic ion-exchange materials in recent years has been the development of an inorganic ion-exchanger for the pretreatment of acidic legacy 9 Mo production waste to simultaneously remove radiogenic cesium and strontium. Radiogenic cesium and strontium comprise the majority of activity in such waste and may offer increased ease in the downstream processing to immobilise this waste in a Synroc wasteform. With the reliance on separations technologies in all current ANFC concepts, and the recent admission of ANSTO to the European Commissions EUROPART project, the development of new inorganic ion-exchangers has also expanded within our group. This presentation will provide a background of the fundamentals of inorganic and composite inorganic-organic ion-exchange materials followed by specific discussion of some selected inorganic and composite ion-exchange materials being developed and studied at ANSTO. The detailed structural and ion-exchange chemistry of these materials will be discussed and note made of how such materials could benefit any of the

  7. Electron tunneling in chemistry

    International Nuclear Information System (INIS)

    Zamaraev, K.I.; Khajrutdinov, R.F.; Zhdanov, V.P.; Molin, Yu.N.

    1985-01-01

    Results of experimental and theoretical investigations are outlined systematically on electron tunnelling in chemical reactions. Mechanism of electron transport to great distances is shown to be characteristic to chemical compounds of a wide range. The function of tunnel reactions is discussed for various fields of chemistry, including radiation chemistry, electrochemistry, chemistry of solids, chemistry of surface and catalysis

  8. Progress report, Chemistry and Materials Division, April 1 to June 30, 1977

    International Nuclear Information System (INIS)

    1977-07-01

    Research results are reported in such areas as ion penetration, electron microscopy, metal physics and radiation damage, nuclear methods of analysis, fuel analysis, and general analytical chemistry, electrochemistry, radiation chemistry, hydrogen-deuterium exchange, and surface chemistry of nuclear materials like zirconium base alloys. (E.C.B.)

  9. Progress report, Chemistry and Materials Division, January 1 to March 31, 1977

    International Nuclear Information System (INIS)

    1977-04-01

    Results are described of research on ion penetration, electron microscopy, radiation damage and metal physics, nuclear methods of analysis, computer calculating methods, analytical chemistry, deuterium exchange, radioactivity measurement, electrochemistry, mass spectrometry and fuel analysis, radiation chemistry, surface chemistry, and properties of zirconium base alloys. (E.C.B.)

  10. Asymmetric H-D exchange reactions of fluorinated aromatic ketones

    KAUST Repository

    Zhao, Yujun; Lim, XiaoZhi; Pan, Yuanhang; Zong, Lili; Feng, Wei; Tan, Choonhong; Huang, Kuo-Wei

    2012-01-01

    Chiral bicyclic guanidine catalyzes the asymmetric H-D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction's stereoselectivity. © 2012 The Royal Society of Chemistry.

  11. Asymmetric H-D exchange reactions of fluorinated aromatic ketones

    KAUST Repository

    Zhao, Yujun

    2012-01-01

    Chiral bicyclic guanidine catalyzes the asymmetric H-D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction\\'s stereoselectivity. © 2012 The Royal Society of Chemistry.

  12. Hydrogen exchange

    DEFF Research Database (Denmark)

    Jensen, Pernille Foged; Rand, Kasper Dyrberg

    2016-01-01

    Hydrogen exchange (HX) monitored by mass spectrometry (MS) is a powerful analytical method for investigation of protein conformation and dynamics. HX-MS monitors isotopic exchange of hydrogen in protein backbone amides and thus serves as a sensitive method for probing protein conformation...... and dynamics along the entire protein backbone. This chapter describes the exchange of backbone amide hydrogen which is highly quenchable as it is strongly dependent on the pH and temperature. The HX rates of backbone amide hydrogen are sensitive and very useful probes of protein conformation......, as they are distributed along the polypeptide backbone and form the fundamental hydrogen-bonding networks of basic secondary structure. The effect of pressure on HX in unstructured polypeptides (poly-dl-lysine and oxidatively unfolded ribonuclease A) and native folded proteins (lysozyme and ribonuclease A) was evaluated...

  13. Environmental Science and Technology

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    The Program on Environmental Science and Technology comprehends environmental chemistry (water, soil and atmospheric chemistry), clean technologies (desulfurization of diesel and oil, biodegradable polymers and structural modification of polymers, recycling, pyrolysis of dangerous chemicals by molten salt technology), nanotechnology (magnetic nanoparticles, dendrimers, nano biomarkers, catalyzers) and chemical characterization of nuclear fuel and nuclear fuel cycle waste (chemical and isotopic characterization)

  14. Acidic deposition: State of science and technology. Report 10. Watershed and lake processes affecting surface-water acid-base chemistry. Final report

    International Nuclear Information System (INIS)

    Turner, R.S.; Cook, R.B.; Miegroet, H.V.; Johnson, D.W.; Elwood, J.W.

    1990-09-01

    The acid-base chemistry of surface waters is governed by the amount and chemistry of deposition and by the biogeochemical reactions that generate acidity or acid neutralizing capacity (ANC) along the hydrologic pathways that water follows through watersheds to streams and lakes. The amount of precipitation and it chemical loading depend on the area's climate and physiography, on it proximity to natural or industrial gaseous or particulate sources, and on local or regional air movements. Vegetation interacts with the atmosphere to enhance both wet and dry deposition of chemicals to a greater or lesser extent, depending on vegetation type. Vegetation naturally acidifies the environment in humid regions through processes of excess base cation uptake and generation of organic acids associated with many biological processes. Natural acid production and atmospheric deposition of acidic materials drive the acidification process. The lake or stream NAC represents a balance between the acidity-and ANC-generating processes that occur along different flow paths in the watershed and the relative importance of each flow path

  15. Handbook of hot atom chemistry

    International Nuclear Information System (INIS)

    Adloff, J.P.; Matsuura, Tatsuo; Yoshihara, Kenji

    1992-01-01

    Hot atom chemistry is an increasingly important field, which has contributed significantly to our understanding of many fundamental processes and reactions. Its techniques have become firmly entrenched in numerous disciplines, such as applied physics, biomedical research, and all fields of chemistry. Written by leading experts, this comprehensive handbook encompasses a broad range of topics. Each chapter comprises a collection of stimulating essays, given an in-depth account of the state-of-the-art of the field, and stressing opportunities for future work. An extensive introduction to the whole area, this book provides unique insight into a vast subject, and a clear delineation of its goals, techniques, and recent findings. It also contains detailed discussions of applications in fields as diverse as nuclear medicine, geochemistry, reactor technology, and the chemistry of comets and interstellar grains. (orig.)

  16. Making Decisions by Analytical Chemistry

    DEFF Research Database (Denmark)

    Andersen, Jens Enevold Thaulov

    . These discrepancies are very unfortunate because erroneous conclusions may arise from an otherwise meticulous and dedicated effort of research staff. This may eventually lead to unreliable conclusions thus jeopardizing investigations of environmental monitoring, climate changes, food safety, clinical chemistry......It has been long recognized that results of analytical chemistry are not flawless, owing to the fact that professional laboratories and research laboratories analysing the same type of samples by the same type of instruments are likely to obtain significantly different results. The European......, forensics and other fields of science where analytical chemistry is the key instrument of decision making. In order to elucidate the potential origin of the statistical variations found among laboratories, a major program was undertaken including several analytical technologies where the purpose...

  17. The Department of Chemistry of the Austrian Research Centre Seibersdorf

    International Nuclear Information System (INIS)

    Proksch, E.

    1984-03-01

    The present report describes the R and D work carried out during 1981 to 1983. This work is still almost exclusively devoted to applied research items; a major fraction of the capacity available is devoted to contract research. The main R and D areas are: - applied radiation chemistry - conditioning of wastes - nuclear fuel chemistry and technology - non-nuclear technical chemistry - radioisotopes and labelled compounds - analytical chemistry. (Author) [de

  18. Heat exchanger

    International Nuclear Information System (INIS)

    Drury, C.R.

    1988-01-01

    A heat exchanger having primary and secondary conduits in heat-exchanging relationship is described comprising: at least one serpentine tube having parallel sections connected by reverse bends, the serpentine tube constituting one of the conduits; a group of open-ended tubes disposed adjacent to the parallel sections, the open-ended tubes constituting the other of the conduits, and forming a continuous mass of contacting tubes extending between and surrounding the serpentine tube sections; and means securing the mass of tubes together to form a predetermined cross-section of the entirety of the mass of open-ended tubes and tube sections

  19. Water chemistry and corrosion control of cladding and primary circuit components. Proceedings of a technical committee meeting

    International Nuclear Information System (INIS)

    1999-12-01

    Corrosion is the principal life limiting degradation mechanism in nuclear steam supply systems, especially taking into account the trends to increase fuel burnup, thermal rate and cycle length. Primary circuit components of water cooled power reactors have an impact on Zr-based alloys behaviour due to crud (primary circuit corrosion products) formation, transport and deposition on heat transfer surfaces. Crud deposits influence water chemistry, radiation and thermal hydraulic conditions near cladding surface, and by this way-Zr-based alloy corrosion. During the last decade, significant improvements were achieved in the reduction of the corrosion and dose rates by changing the cladding material for one more resistant to corrosion or by the improvement of water chemistry conditions. However, taking into account the above mentioned tendency for heavier fuel duties, corrosion and water chemistry, control will remain a serious task to work with for nuclear power plant operators and scientists, as well as development of generally accepted corrosion model of Zr-based alloys in a water environment in a new millennium. Upon the recommendation of the International Working Group on Water Reactor Fuel Performance and Technology, water chemistry and corrosion of cladding and primary circuit components are in the focus of the IAEA activities in the area of fuel technology and performance. At present the IAEA performs two co-ordinated research projects (CRPs): on On-line High Temperature Monitoring of Water Chemistry and Corrosion (WACOL) and on Activity Transport in Primary Circuits. Two CRPs deal with hydrogen and hydride degradation of the Zr-based alloys. A state-of-the-art review entitled: 'Waterside Corrosion of Zirconium Alloys in Nuclear Power Plants' was published in 1998. Technical Committee meetings on the subject were held in 1985 (Cadarache, France), 1989 (Portland, USA), 1993 (Rez, Czech Republic). During the last few years extensive exchange of experience in

  20. Progress report 1981-1982. Reactor Chemistry Department

    International Nuclear Information System (INIS)

    1983-08-01

    Review of the activities performed by the Reactor Chemistry Department of the National Atomic Energy Commission of Argentina during 1981-1982. This Department provides services and assistance in all matters related to water chemistry and nuclear reactors chemistry, in all their phases: design, construction, commissioning and decommissioning. During this period, the following tasks were performed: study of the metallic oxide-water interphases; determination of the goethite and magnetite surficial charges; synthesis of the monodispersed nickel ferrites; study of the iron oxides dissolution mechanism in presence of different complexing agents; chemical decontamination of structural metals; thermodynamics of the water-nitrogen system; physico-chemical studies of aqueous solutions at high temperatures; hydrothermal decomposition of ionic exchange resines and study of the equilibria of the anionic exchange for the chemistry of pressurized reactor's primary loops. The appendix includes information on the Reactor Chemistry Department staff, its publications, services, seminars, courses and conferences performed during 1981-1982. (R.J.S.) [es

  1. Heat exchanger

    Science.gov (United States)

    Wolowodiuk, Walter

    1976-01-06

    A heat exchanger of the straight tube type in which different rates of thermal expansion between the straight tubes and the supply pipes furnishing fluid to those tubes do not result in tube failures. The supply pipes each contain a section which is of helical configuration.

  2. Heat exchangers

    International Nuclear Information System (INIS)

    1975-01-01

    The tubes of a heat exchanger tube bank have a portion thereof formed in the shape of a helix, of effective radius equal to the tube radius and the space between two adjacent tubes, to tangentially contact the straight sections of the tubes immediately adjacent thereto and thereby provide support, maintain the spacing and account for differential thermal expansion thereof

  3. Exchange Options

    NARCIS (Netherlands)

    Jamshidian, F.

    2007-01-01

    The contract is described and market examples given. Essential theoretical developments are introduced and cited chronologically. The principles and techniques of hedging and unique pricing are illustrated for the two simplest nontrivial examples: the classical Black-Scholes/Merton/Margrabe exchange

  4. Exchange rates.

    Science.gov (United States)

    Mills, Bev

    2003-09-01

    IN MAY this year, I was lucky enough to go to Larissa in northern Greece as part of Hope Exchange 2003, an annual study tour organised by the European Union's hospital committee and administered by the Institute of Healthcare Management (IHM).

  5. Heat exchanger

    Science.gov (United States)

    Daman, Ernest L.; McCallister, Robert A.

    1979-01-01

    A heat exchanger is provided having first and second fluid chambers for passing primary and secondary fluids. The chambers are spaced apart and have heat pipes extending from inside one chamber to inside the other chamber. A third chamber is provided for passing a purge fluid, and the heat pipe portion between the first and second chambers lies within the third chamber.

  6. Heat exchanger

    International Nuclear Information System (INIS)

    Wolowodiuk, W.

    1976-01-01

    A heat exchanger of the straight tube type is described in which different rates of thermal expansion between the straight tubes and the supply pipes furnishing fluid to those tubes do not result in tube failures. The supply pipes each contain a section which is of helical configuration

  7. Optimization of secondary side water chemistry in TQNPC

    International Nuclear Information System (INIS)

    Fang Lan

    2007-01-01

    This article briefly introduces the types of corrosion that may be happened on steam generator heat exchange tubes in Qinshan CANDU6 nuclear power station and chemical effects on corrosion. The water chemistry optimization on minimzing deposition and corrosion of steam generators are introduced. The article summarizes the experiences of plant chemistry control and morpholine operation, providing guidance for optimizing secondary side water chemistry in the future, giving reference on selection of secondary side alkali agent and setting water chemistry specifications for other nuclear power stations. (authors)

  8. Green chemistry: A tool in Pharmaceutical Chemistry

    OpenAIRE

    Smita Talaviya; Falguni Majumdar

    2012-01-01

    Green chemistry expresses an area of research developing from scientific discoveries about pollution awareness and it utilizes a set of principles that reduces or eliminates the use or generation of hazardous substances in all steps of particular synthesis or process. Chemists and medicinal scientists can greatly reduce the risk to human health and the environment by following all the valuable principles of green chemistry. The most simple and direct way to apply green chemistry in pharmaceut...

  9. From hot atom chemistry to epithermal chemistry

    International Nuclear Information System (INIS)

    Roessler, K.

    2004-01-01

    The rise and fall of hot atom chemistry (HAC) over the years from 1934 to 2004 is reviewed. Several applications are discussed, in particular to astrophysics and the interaction of energetic ions and atoms in space. Epithermal chemistry (ETC) is proposed to substitute the old name, since it better fits the energy range as well as the non-thermal and non-equilibrium character of the reactions. ETC also avoids the strong connexion of HAC to nuclear chemistry and stands for the opening of the field to physical chemistry and astrophysics. (orig.)

  10. 7. Seminar of the IIE-IMP-ININ on technological specialities. Topic 8: Analytical Chemistry; 7. Seminario IIE-IMP-ININ sobre especialidades tecnologicas. Mesa 8: Quimica Analitica

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-12-31

    With the purpose to give continuity to the exchange of experiences and to impel the development of common specialties among IIE-ININ-IMP, the VII Seminary was held in Mexico City on September 7, 1994. In the event were present 163 researchers of the three participant Institutions as well as representative persons of invited institutions. The objective of this Seminary was to relate the researchers of a common branch, with the idea that the specialists made an exchange of experiences, in order to establish cooperation routes. The event was arranged in 11 working tables, with a total of 111 papers: 43 of these papers were from IIE, 42 from IMP, 22 from ININ and 4 from invited entities. During the Seminary, the 11 working tables has sessions simultaneously, and each one of the papers were discussed at the time that possible future cooperating inter institutional actions were examined. The conclusions of the Seminary were exposed in a plenary session, in the presence of the directing boards of the three participant Institutions.

  11. Many-electron approaches in physics, chemistry and mathematics a multidisciplinary view

    CERN Document Server

    Site, Luigi

    2014-01-01

    This book provides a broad description of the development and (computational) application of many-electron approaches from a multidisciplinary perspective. In the context of studying many-electron systems Computer Science, Chemistry, Mathematics and Physics are all intimately interconnected. However, beyond a handful of communities working at the interface between these disciplines, there is still a marked separation of subjects. This book seeks to offer a common platform for possible exchanges between the various fields and to introduce the reader to perspectives for potential further developments across the disciplines. The rapid advances of modern technology will inevitably require substantial improvements in the approaches currently used, which will in turn make exchanges between disciplines indispensable. In essence this book is one of the very first attempts at an interdisciplinary approach to the many-electron problem.

  12. The on-line coupled atmospheric chemistry model system MECO(n) - Part 5: Expanding the Multi-Model-Driver (MMD v2.0) for 2-way data exchange including data interpolation via GRID (v1.0)

    Science.gov (United States)

    Kerkweg, Astrid; Hofmann, Christiane; Jöckel, Patrick; Mertens, Mariano; Pante, Gregor

    2018-03-01

    As part of the Modular Earth Submodel System (MESSy), the Multi-Model-Driver (MMD v1.0) was developed to couple online the regional Consortium for Small-scale Modeling (COSMO) model into a driving model, which can be either the regional COSMO model or the global European Centre Hamburg general circulation model (ECHAM) (see Part 2 of the model documentation). The coupled system is called MECO(n), i.e., MESSy-fied ECHAM and COSMO models nested n times. In this article, which is part of the model documentation of the MECO(n) system, the second generation of MMD is introduced. MMD comprises the message-passing infrastructure required for the parallel execution (multiple programme multiple data, MPMD) of different models and the communication of the individual model instances, i.e. between the driving and the driven models. Initially, the MMD library was developed for a one-way coupling between the global chemistry-climate ECHAM/MESSy atmospheric chemistry (EMAC) model and an arbitrary number of (optionally cascaded) instances of the regional chemistry-climate model COSMO/MESSy. Thus, MMD (v1.0) provided only functions for unidirectional data transfer, i.e. from the larger-scale to the smaller-scale models.Soon, extended applications requiring data transfer from the small-scale model back to the larger-scale model became of interest. For instance, the original fields of the larger-scale model can directly be compared to the upscaled small-scale fields to analyse the improvements gained through the small-scale calculations, after the results are upscaled. Moreover, the fields originating from the two different models might be fed into the same diagnostic tool, e.g. the online calculation of the radiative forcing calculated consistently with the same radiation scheme. Last but not least, enabling the two-way data transfer between two models is the first important step on the way to a fully dynamical and chemical two-way coupling of the various model instances.In MMD (v1

  13. The latest general chemistry

    International Nuclear Information System (INIS)

    Ryu, Geun Bae; Choi, Se Yeong; Kim, Chin Yeong; Yoon, Gil Jung; Lee, Eun Seok; Seo, Moon Gyu

    1995-02-01

    This book deals with the latest general chemistry, which is comprised of twenty-three chapters, the contents of this book are introduction, theory of atoms and molecule, chemical formula and a chemical reaction formula, structure of atoms, nature of atoms and the periodic table, structure of molecule and spectrum, gas, solution, solid, chemical combination, chemical reaction speed, chemical equilibrium, thermal chemistry, oxidation-reduction, electrochemistry, acid-base, complex, aquatic chemistry, air chemistry, nuclear chemistry, metal and nonmetal, organic chemistry and biochemistry. It has exercise in the end of each chapter.

  14. Heat exchanger leakage problem location

    Directory of Open Access Journals (Sweden)

    Jícha Miroslav

    2012-04-01

    Full Text Available Recent compact heat exchangers are very often assembled from numerous parts joined together to separate heat transfer fluids and to form the required heat exchanger arrangement. Therefore, the leak tightness is very important property of the compact heat exchangers. Although, the compact heat exchangers have been produced for many years, there are still technological problems associated with manufacturing of the ideal connection between the individual parts, mainly encountered with special purpose heat exchangers, e.g. gas turbine recuperators. This paper describes a procedure used to identify the leakage location inside the prime surface gas turbine recuperator. For this purpose, an analytical model of the leaky gas turbine recuperator was created to assess its performance. The results obtained are compared with the experimental data which were acquired during the recuperator thermal performance analysis. The differences between these two data sets are used to indicate possible leakage areas.

  15. Micro flow chemistry : new possibilities for synthetic chemists

    NARCIS (Netherlands)

    Noel, T.; Pignataro, B.

    2014-01-01

    The use of microreactor technology for continuous-flow chemistry has received a significant amount of attention in recent years. In this chapter, we discuss the important aspects of this technology and its impact on synthetic organic chemistry. Basic engineering principles, unusual reaction

  16. Progress report, Chemistry and Materials Division, 1 April to 30 June, 1979

    International Nuclear Information System (INIS)

    1979-07-01

    Research results are reported by groups investigating ion penetration, nuclear methods of analysis, accelerator operation, general analytical chemistry, radoactivity measurement, deuterium analysis, electrochemistry, mass spectrometry and fuel analysis, radiation chemistry and laser photochemistry, hydrogen-water exchange, isotope chemistry, surface chemistry, and electron microscopy. Work in an associated laboratory at the University of Toronto on isotopic changes in reaction rates is reported. (L.L.)

  17. Ion exchange equilibrium constants

    CERN Document Server

    Marcus, Y

    2013-01-01

    Ion Exchange Equilibrium Constants focuses on the test-compilation of equilibrium constants for ion exchange reactions. The book first underscores the scope of the compilation, equilibrium constants, symbols used, and arrangement of the table. The manuscript then presents the table of equilibrium constants, including polystyrene sulfonate cation exchanger, polyacrylate cation exchanger, polymethacrylate cation exchanger, polysterene phosphate cation exchanger, and zirconium phosphate cation exchanger. The text highlights zirconium oxide anion exchanger, zeolite type 13Y cation exchanger, and

  18. Heat exchanger

    International Nuclear Information System (INIS)

    Bennett, J.C.

    1975-01-01

    A heat exchanger such as forms, for example, part of a power steam boiler is made up of a number of tubes that may be arranged in many different ways, and it is necessary that the tubes be properly supported. The means by which the tubes are secured must be as simple as possible so as to facilitate construction and must be able to continue to function effectively under the varying operating conditions to which the heat exchanger is subject. The arrangement described is designed to meet these requirements, in an improved way. The tubes are secured to a member extending past several tubes and abutment means are provided. At least some of the abutment means comprise two abutment pieces and a wedge secured to the supporting member, that acts on these pieces to maintain the engagement. (U.K.)

  19. Information Technologies as a Tool for Agricultural Extension and Farmer-to-Farmer Exchange: Mobile-Phone Video Use in Mali and Burkina Faso

    Science.gov (United States)

    Sousa, Fernando; Nicolay, Gian; Home, Robert

    2016-01-01

    Mobile phones are widespread in the rural areas of Mali and Burkina Faso, but their potential as a tool for knowledge transfer by extension services in the region remains largely unexplored. The aim of this contribution is to evaluate the potential of video on mobile phones as a tool for farmer-to-farmer exchange and agricultural extension in…

  20. Power and Thermal Technologies for Air and Space-Scientific Research Program. Delivery Order 0017: Study of Microchip Power Module Materials Using Mini-Channel Heat Exchanger

    Science.gov (United States)

    2009-12-01

    at the mid-point of the channels. In fabricating the heat exchanger, a method of attaching the inlet and exit flow tubes (stainless- steel 625 ) to...and the inlet/exit tubing. The mixing chambers ( Inconel 600) were machined as two pieces which were later welded together to make one chamber. The